Document douglascountywi_gov_doc_de9cea04f5

Safety Data Sheets HHS 3rd Floor HHS 3rd Floor 02/29/2016 ---PAGE BREAK--- Safety Data Sheet Index Binder: HHS 3rd Floor - HHS 3rd Floor 3M BRAND DESK AND OFFICE CLEANER 573 3M - Stationery & office Supplies 02/10/2015 4 ALPET D2 Surface Sanitizer Wipes Best Sanitizers Inc 01/15/2015 14 Bromocresol Purple - Bromothymol Blue Mixed Indicator, 1% / 0.2% (w/v) in Methanol 67-56-1 Ricca Chemical Company 05/01/2015 23 BRUSH KLEAN (aerosol) TRI-CHEM CORPORATION 07/12/2007 34 CEB31600 CORPORATE EXPRESS HAND CLEANING WIPES TUB 100 Sourcing Partner Inc 04/07/2008 36 CLOROX CLEAN UP CLEANER WITH BLEACH The Clorox Company 04/01/2002 39 CLOROX COMMERCIAL SOLUTIONS ULTRA CLOROX DISINFECTING BLEACH Clorox Company of Canada, Ltd. 07/19/2013 40 CONSERVE Ecolab - Food & Beverage 11/16/2000 42 CRITERION 90 SRM VESUVIUS USA 06/12/2015 44 GS NEUTRAL DISINFECTANT CLEANER Spartan Chemical Company, Inc. 08/14/2015 52 Gunk Glass Cleaner - Streak Free RSC Chemical Solutions 08/10/2015 57 KRUD KUTTER Driveway Cleaner & Degreaser Krud Kutter, Inc. 12/11/2013 66 Lemon Scent Professional Lysol Brand II Disinfectant Deodorizing Cleaner Reckitt Benckiser - Morris Corporate Center IV 04/01/2015 72 Liquid Had Dishwashing Detergents and Antibacterial Hand Soaps Procter & Gamble 08/01/2007 84 LOTIONIZED LIQUID HAND CLEANER Spartan Chemical Company, Inc. 07/28/2015 89 Potassium Hydrogen Phthalate Solutions 877-24-7 GE Analytical Instruments 04/16/2015 94 Reagent Alcohol Fisher Scientific International 08/27/2015 100 Reference Electrodo Filling Solution 900001 Thermo Electric Company 11/11/2003 109 Sodium Bicarbonate 144-55-8 EK Industries, Inc. 08/04/2015 110 Sodium Hydroxide, Pellets Avantor Performance Materials, Inc 04/14/2015 114 Sodium Phosphate Monobasic Monohydrate (Certified ACS) 10049-21-5 Fisher Scientific International 08/25/2015 124 SODIUM THISOULFATE 7772-98-7 Mineral Masters 08/21/2014 131 Soy Broth BD DIAGNOSTIC SYSTEMS 03/24/2014 136 Product Name CAS Number Manufacturer Version Date Page Page 2 of 136 Page 2 of 136 Page 2 of 136 Page 2 of 136 ---PAGE BREAK--- Product Name CAS Number Manufacturer Version Date Page Page 3 of 136 Page 3 of 136 Page 3 of 136 Page 3 of 136 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 1 of 10 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: the information is copied in full with no changes unless prior written agreement is obtained from 3M, and neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 10-0157-7 Version Number: 27.00 Issue Date: 02/10/15 Supercedes Date: 02/12/13 SECTION 1: Identification 1.1. Product identifier 3M BRAND DESK AND OFFICE CLEANER 573 Product Identification Numbers 70-0061-3328-7, 70-0160-6830-9, 70-0701-7945-5, 70-0704-0450-7, 70-0709-0857-2, 70-0711-2910-3 1.2. Recommended use and restrictions on use Recommended use Aerosol Cleaner for Office Surfaces, AEROSOL FOAM CLEANER FOR OFFICE SURFACES 1.3. Supplier’s details MANUFACTURER: 3M DIVISION: Stationery and Office Supplies Division ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-[PHONE REDACTED]) 1.4. Emergency telephone number 1-[PHONE REDACTED] or (651) 737-6501 (24 hours) SECTION 2: Hazard identification 2.1. Hazard classification Flammable Aerosol: Category 1. Specific Target Organ Toxicity (single exposure): Category 1. 2.2. Label elements Signal word Danger Symbols Flame I Health Hazard I Pictograms Page 4 of 136 Page 4 of 136 Page 4 of 136 Page 4 of 136 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 2 of 10 Hazard Statements Extremely flammable aerosol. Causes damage to organs: cardiovascular system I Precautionary Statements Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF exposed: Call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label). Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 2.3. Hazards not otherwise classified Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal. 2% of the mixture consists of ingredients of unknown acute oral toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt WATER 7732-18-5 86 - 92 ISOBUTANE PROPELLANT 75-28-5 1 - 8 Trade Secret * ISOPROPYL ALCOHOL 67-63-0 3 - 5 Trade Secret * ETHOXYLATED TALL-OIL FATTY ACIDS 61791-00-2 1 - 3 Trade Secret * SODIUM CARBONATE 497-19-8 < 1 ETHANOLAMINE 141-43-5 < 0.5 *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. Page 5 of 136 Page 5 of 136 Page 5 of 136 Page 5 of 136 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 3 of 10 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get medical attention. Skin Contact: Wash with soap and water. If you feel unwell, get medical attention. Eye Contact: No need for first aid is anticipated. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Hydrocarbons During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that Page 6 of 136 Page 6 of 136 Page 6 of 136 Page 6 of 136 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 4 of 10 can dissolve in water. An AR - AFFF type foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with water. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments ETHANOLAMINE 141-43-5 OSHA TWA:6 mg/m3(3 ppm) ETHANOLAMINE 141-43-5 ACGIH TWA:3 ppm;STEL:6 ppm ISOPROPYL ALCOHOL 67-63-0 OSHA TWA:980 mg/m3(400 ppm) ISOPROPYL ALCOHOL 67-63-0 ACGIH TWA:200 ppm;STEL:400 ppm A4: Not class. as human carcin ISOBUTANE PROPELLANT 75-28-5 ACGIH STEL:1000 ppm ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Page 7 of 136 Page 7 of 136 Page 7 of 136 Page 7 of 136 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 5 of 10 Skin/hand protection No chemical protective gloves are required. Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates Half facepiece or full facepiece supplied-air respirator Organic vapor respirators may have short service life. For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Foam Odor, Color, Grade: White foam, Lemon odor Odor threshold No Data Available Melting point Not Applicable Boiling Point Not Applicable Flash Point 30 ºF [Test Method: Open Cup] [Details: specific method: D92] Evaporation rate >=1.00 [Ref Std: WATER=1] [Details: product as applied (without propellant)] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) 1.80 % Flammable Limits(UEL) 8.40 % [Details: for isobutane.] Vapor Pressure 31 - 43 psi 70 ºF] [Details: (aerosol can pressure)] Vapor Density No Data Available Density 1 g/ml Specific Gravity Approximately 1 [Ref Std: WATER=1] Solubility In Water 100.00 % Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity Not Applicable Volatile Organic Compounds 55 - 115 g/l Percent volatile 96 - 98 % weight VOC Less H2O & Exempt Solvents 702 - 831 g/l SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. Page 8 of 136 Page 8 of 136 Page 8 of 136 Page 8 of 136 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 6 of 10 10.4. Conditions to avoid Heat Sparks and/or flames 10.5. Incompatible materials Not determined 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Contact with the skin during product use is not expected to result in significant irritation. Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Ingestion: Gastrointestinal Irritation: may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Additional Health Effects: Single exposure may cause target organ effects: Cardiac Sensitization: may include irregular heartbeat faintness, chest pain, and may be fatal. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Page 9 of 136 Page 9 of 136 Page 9 of 136 Page 9 of 136 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 7 of 10 Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg ISOBUTANE PROPELLANT Inhalation- Gas (4 hours) Rat LC50 276,000 ppm ISOPROPYL ALCOHOL Dermal Rabbit LD50 12,870 mg/kg ISOPROPYL ALCOHOL Inhalation- Vapor (4 hours) Rat LC50 72.6 mg/l ISOPROPYL ALCOHOL Ingestion Rat LD50 4,710 mg/kg SODIUM CARBONATE Dermal Rabbit LD50 > 2,000 mg/kg SODIUM CARBONATE Ingestion Rat LD50 2,800 mg/kg ETHANOLAMINE Inhalation- Vapor official classifica tion LC50 estimated to be 10 - 20 mg/l ETHANOLAMINE Dermal Rabbit LD50 1,000 mg/kg ETHANOLAMINE Ingestion Rat LD50 1,720 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value ISOBUTANE PROPELLANT Professio nal judgeme nt No significant irritation ISOPROPYL ALCOHOL Multiple animal species No significant irritation SODIUM CARBONATE Rabbit No significant irritation ETHANOLAMINE Rabbit Corrosive Serious Eye Damage/Irritation Name Species Value ISOBUTANE PROPELLANT Professio nal judgeme nt No significant irritation ISOPROPYL ALCOHOL Rabbit Severe irritant SODIUM CARBONATE Rabbit Corrosive ETHANOLAMINE Rabbit Corrosive Skin Sensitization Name Species Value ISOPROPYL ALCOHOL Guinea pig Not sensitizing ETHANOLAMINE Guinea pig Some positive data exist, but the data are not sufficient for classification Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value ISOBUTANE PROPELLANT In Vitro Not mutagenic ISOPROPYL ALCOHOL In Vitro Not mutagenic ISOPROPYL ALCOHOL In vivo Not mutagenic SODIUM CARBONATE In Vitro Not mutagenic ETHANOLAMINE In Vitro Not mutagenic ETHANOLAMINE In vivo Not mutagenic Carcinogenicity Name Route Species Value Page 10 of 136 Page 10 of 136 Page 10 of 136 Page 10 of 136 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 8 of 10 ISOPROPYL ALCOHOL Inhalation Rat Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration ISOPROPYL ALCOHOL Ingestion Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 400 mg/kg/day during organogenesi s ISOPROPYL ALCOHOL Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat LOAEL 9 mg/l during gestation SODIUM CARBONATE Ingestion Not toxic to development Mouse NOAEL 340 mg/kg/day during organogenesi s ETHANOLAMINE Dermal Not toxic to development Rat NOAEL 225 mg/kg/day during organogenesi s ETHANOLAMINE Ingestion Not toxic to development Rat NOAEL 616 mg/kg/day during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration ISOBUTANE PROPELLANT Inhalation cardiac sensitization Causes damage to organs Multiple animal species NOAEL Not available ISOBUTANE PROPELLANT Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available ISOBUTANE PROPELLANT Inhalation respiratory irritation All data are negative Mouse NOAEL Not available ISOPROPYL ALCOHOL Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available ISOPROPYL ALCOHOL Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available ISOPROPYL ALCOHOL Inhalation auditory system Some positive data exist, but the data are not sufficient for classification Guinea pig NOAEL 13.4 mg/l 24 hours ISOPROPYL ALCOHOL Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse ETHANOLAMINE Inhalation respiratory irritation May cause respiratory irritation Human and animal NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration ISOBUTANE PROPELLANT Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 4,500 ppm 13 weeks ISOPROPYL ALCOHOL Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 12.3 mg/l 24 months ISOPROPYL ALCOHOL Inhalation nervous system All data are negative Rat NOAEL 12 mg/l 13 weeks ISOPROPYL ALCOHOL Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 400 mg/kg/day 12 weeks SODIUM CARBONATE Inhalation respiratory system Some positive data exist, but the Rat LOAEL 0.07 3 months Page 11 of 136 Page 11 of 136 Page 11 of 136 Page 11 of 136 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 9 of 10 data are not sufficient for classification mg/l ETHANOLAMINE Inhalation liver I kidney and/or bladder I respiratory system Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 0.656 mg/l 5 weeks ETHANOLAMINE Ingestion hematopoietic system I liver I kidney and/or bladder I respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL Not available Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Facility must be capable of handling aerosol cans. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-[PHONE REDACTED] or [PHONE REDACTED]. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No Page 12 of 136 Page 12 of 136 Page 12 of 136 Page 12 of 136 ---PAGE BREAK--- 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 Page 10 of 10 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 1 Flammability: 3 Instability: 1 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 1 Flammability: 3 Physical Hazard: 1 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS® III) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® III ratings are to be used with a fully implemented HMIS® III program. HMIS® is a registered mark of the American Coatings Association (ACA). Document Group: 10-0157-7 Version Number: 27.00 Issue Date: 02/10/15 Supercedes Date: 02/12/13 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com Page 13 of 136 Page 13 of 136 Page 13 of 136 Page 13 of 136 ---PAGE BREAK--- Section 1 Product Description Safety Data Sheet Alpet D2 Surface Sanitizer Wipes Product Name: Recommended Uses: Synonyms: Distributor: Chemical Information Emergency: Alpet D2 Surface Sanitizer Wipes RTU Surface Sanitizer Sanitizer Wipes Best Sanitizers, Inc. PO Box 1360 Penn Valley, CA 95946 Chemtrec 1.[PHONE REDACTED] OSHA Regulatory Status--This chemical is considered hazardous by the 2012 OSHA Hazard Communication, 29 CFR §1910.1200: This material is an EPA Registered Disinfectant for industrial, institutional and consumer use that is safe for consumers with intended and reasonable foreseeable use. Please follow label directions. NOTE: Warnings below are for exposure to large quantities of the product. Normal usage should not create hazardous conditions. Flammable liquids Category 3 Danger Hazard Statements Causes serious eye irritation. Flammable liquid and vapor. Maybe be harmful if swallowed. Precautionary Statements—Prevention Appearance—Aqueous solution Physical state—Liquid Odor— Alcohol Odor Keep away from heat/sparks/open flames/hot surfaces-----No Smoking. Do not use in eyes. Keep container closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/protective clothing/eye protection/face protection. Precautionary Statements—Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin (hair) with water/shower. In case of fire: Use CO2, dry chemical, or foam for extinction. Precautionary Statements—Storage Stored in a well-ventilated place. Keep Cool. Section 2 Hazard Identification Page 14 of 136 Page 14 of 136 Page 14 of 136 Page 14 of 136 ---PAGE BREAK--- Safety Data Sheet Precautionary Statements—Disposal Dispose of contents/container to an approved waste disposal plant. Hazards not otherwise classified (HNOC) Not Applicable Other Information Unknown Acute Toxicity Ingredients considered hazardous as defined by OSHA, 29 CFR 1910.1200, WHMIS under the HPA (Canada), Chemical Name CAS No. Weight-% Isopropyl Alcohol 67-63-0 55-75 First Aid Measures Eye Contact Skin Contact Hold eye(s) open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after first 5 minutes, then continue rinsing eye(s). If eye irritation persists: Get medical advice/attention. For accidental exposure to large quantities, wash off immediatelywith soap and plenty of water while removing all contaminated clothes and shoes. Get medical attention if irritation develops. Inhalation Remove to fresh air. Immediate medical attention is not required. Ingestion Do NOT induce vomiting. Ingestion of large amounts can cause drowsiness, unconsciousness or cramps. Drink plenty of water. Never give anything by mouth to an unconscious person. Call physician. Most important and effects, both acute and delayed See Section 11 for information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat Suitable Extinguishing Media Dry Chemical, Waterspray (fog), Carbon dioxide (CO2), Foam. Unsuitable Extinguishing Media No Information available. Specific hazards arising from the chemical Flammable. Vapors may travel to source of ignition and flash back. Hazardous combustion products Explosion Data Sensitivityto Mechanical Impact Sensitivityto Static Discharge Carbon Monoxide. Carbon Dioxide (CO2). None May be ignited by friction, heat, sparks or flames. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective Section 5 Fire-Fighting Measures Remaining ingredients are non-hazardous and/or present at amounts below reportable limits and considered confidential. Section 4 First Aid Measures Section 3 Composition/Information on Ingredients Page 15 of 136 Page 15 of 136 Page 15 of 136 Page 15 of 136 ---PAGE BREAK--- Safety Data Sheet gear. Cool containers with flooding quantities of water until well after fire is out. Personal Precautions, Protective Equipment and Emergency Procedures Personal Precautions Use personal protection recommended in Section 8. Ensure adequate ventilation, especially in confined areas. For emergency responders Isolate area. Keep unnecessary personnel away. Environment Precautions Environmental Precautions Prevent entry into waterways, sewers, basements or confined areas. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local/national regulations (See Section 13). Methods for cleaning up Use clean non-sparking tools to collect absorbed material. May be ignited by friction, heat, sparks or flames. Collect spillage. Soak up with inert absorbent material,. Sweep up and shovel into suitable containers for disposal. Following product recovery, flush area with water. Precautions for Safe Handling Advice on Safe Handling Keep away from heat sparks, flame and other sources of ignition pilot lights, electric motors and static electricity). Take precautionary measures against static discharges. Do not eat, drink or smoke when using this product. Use personal protection recommended in Section 8. Avoid contact with skin, eyes or clothing. Use only in well-ventilated areas. Avoid breathing vapors or mists. Wash thoroughly after handling. Handle in accordance with good industrial hygiene and safety practice. Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible materials Keep Containers closed in a dry, cool and well-ventilated place. Keep from freezing. Keep away from heat, sparks, flame and other sources of ignition(i.e., pilot lights, electric motors and static electricity). Store between 40 to 100˚F. Heat, sparks, open flame, other ignition sources. Reacts violently with strong oxidants such as nitric acid and silver nitrate causing fire and explosion hazard. Reacts slowly with calcium hypochlorite and ammonia causing fire and explosion hazard. Section 7 Handling and Storage Section 6 Accidental Release Measures Page 16 of 136 Page 16 of 136 Page 16 of 136 Page 16 of 136 ---PAGE BREAK--- Safety Data Sheet Exposure Guidelines Chemical Name ACGIHTLV OSHA PEL NIOSH IDLH Isopropyl alcohol 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 ppm (vacated)STEL: 500 ppm (vacated) STEL: 1225 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 Appropriate Engineering Controls Engineering Controls Showers, eyewash stations, ventilation system. Individual Protection Measures, such as personal protective equipment Eye/Face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective NeopreneTM gloves. Rubbergloves. Normal work clothing (long sleeved shirt and long pants is recommended). Apron is recommended. Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. General Hygiene Considerations Wash face, hands and any exposed skin thoroughly after handling. Wash contaminated clothing and shoes before reuse. Do not Eat, Drink or Smoke when using this product. Information on basic physical and chemical properties Formula: Odor: See Section 3 Alcohol Smell Physical State: Appearance: Liquid Aqueous solution Odor Threshold: Property pH Melting Point/Freezing Point Boiling Point/ Boiling Range Flash Point Evaporation rate Flammability (solid, gas) No Information Available Color: Values 5.0-7.0 No Information 180˚F 21.49 ˚C / 70.68˚F No information available No information available Clear Remarks— Method ±1 @21˚C Section 9 Physical and Chemical Properties Section 8 Protection Information Page 17 of 136 Page 17 of 136 Page 17 of 136 Page 17 of 136 ---PAGE BREAK--- Safety DataSheet Flammability Limit in Air Upper flammability limit: 12.7% Lower flammability limit: Vapor pressure: Vapor density: Specific Gravity Water solubility Partition coefficient Autoignition temperature Decomposition temperature Kinematic viscosity Dynamic viscosity Explosive properties Oxidizing properties 2.0% 30mm Hg @ 20 ˚C No information available 0.89 Soluble in water No information available No information available No information available No information available No information available No information available No information available Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to avoid Incompatible materials Hazardous Decomposition Products No data available. Stable under recommended storage conditions. None under normal processing. Heat, flames and sparks, extreme temperature conditions Heat, sparks, open flame, other ignition sources. Carbon monoxide. Carbon dioxide (CO2). Nitrogen. Information on likely routes of exposure Product Information Inhalation Eye Contact Skin Contact Ingestion Inhalation of vapors in high concentration maycause irritation of respiratory system. Irritating to eyes. No irritant under normal use. May be harmful if swallowed. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Water, 7732-18-5 > 90 mL/kg (Rat) - - Isopropyl alcohol 67-63-0 = 4396 mg/kg (Rat) = 12800 mg/kg (Rabbit) = 16000 ppm (Rat) 8 h Section 11 Toxicity Data Section 10 Stability and Reactivity Data Page 18 of 136 Page 18 of 136 Page 18 of 136 Page 18 of 136 ---PAGE BREAK--- Safety Data Sheet Information on toxicological effects No Information Available Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No Information Available Germ cell mutagenicity No Information Available Carcinogenicity IARC: Group 3 (Not classifiable as to its carcinogenicity to humans). Reproductive toxicity No Information Available STOT single exposure No Information Available STOT repeated exposure No Information Available Aspiration hazard No Information Available Numerical measures of toxicity –Product Information Unknown Acute Toxicity <0.5% of the mixture consists of direct food additives and 150 ppm of material of unknown toxicity. The following values are calculated based on Chapter 3.1 of the GHS document ATE mix (dermal) ATE mix(inhalation-vapor 21843mg/kg mg/l NA (Isopropanol Inhalation LC 50 = 16,000 ppm Rat 8 hours) Ecotoxicity <0.5% of the mixture consists of components(s) of unknow hazards to the aquatic environment. Chemical Name Algae/Aquatic Plants Fish Crustacea Isopropyl alcohol 67-63-0 1000: 96 h Desmodesmussubspicatus mg/L EC50 1000: 72 h Desmodesmussubspicatus mg/L EC50 9640: 96 h Pimephales promelas mg/L LC50 flow-through 11130: 96 h Pimephales promelas mg/L LC50 static 1400000: 96 h Lepomis macrochirus µg/L LC50 13299: 48 h Daphnia magna mg/L EC50 Section 12 Ecological Data Page 19 of 136 Page 19 of 136 Page 19 of 136 Page 19 of 136 ---PAGE BREAK--- Safety Data Sheet Persistence and degradability No Information Available. Bioaccumulation Chemical Name Partition Coefficient Isopropyl alcohol 67-63-0 0.05 Mobility No information available. Other adverse effects No information available Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Dispose of in accordance with federal, state and local regulations. Chemical Name California Hazardous Waste Status Isopropyl alcohol 67-63-0 Toxic Ignitable DOT UN/ID No. Proper shipping name Hazard Class Packing Group 1219 Isopropanol Flammable liquids 3 II Limited Quantities for packages under 1 Liter Exempt DOT-SP 9275 for packages under 1 gallon Section 14 Transport Information Section 13 Disposal Information Page 20 of 136 Page 20 of 136 Page 20 of 136 Page 20 of 136 ---PAGE BREAK--- Safety DataSheet Section 15 Regulatory Information International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies Legend: TSCA—United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL— Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS—European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. Note: Isopropyl alcohol only needs to be reported if it is being manufactured by the strong acid process. Facilities that process or otherwise use isopropyl alcohol are NOT covered and should NOT file a report. SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard Yes Sudden Release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substance regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substance regulated as a hazardous substance under the Comprehensive Environment Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local regional or state level pertaining to releases of this material. US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Isopropyl alcohol 67-63-0 X X X U.S. EPA Label Information EPA Pesticide Registration Number 73232-2 This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The pesticide label includes other important information, including directions for use. Page 21 of 136 Page 21 of 136 Page 21 of 136 Page 21 of 136 ---PAGE BREAK--- Safety DataSheet NFPA Health Hazards Flammability Instability Physical and Chemical Properties 2 3 0 None HMIS Health Hazards Flammability Physical Hazards Personal protection 2 3 0 B (safety glasses, gloves) Prepared by: Technical Department Revision Date January 15, 2015 Version 0 Revision Note No information available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the d ate of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet LS 104-222-00.004 Section 16 Additional Information Page 22 of 136 Page 22 of 136 Page 22 of 136 Page 22 of 136 ---PAGE BREAK--- Safety Data Sheet 1.1. Product Identifier Trade Name or Designation: Product Number: Other Identifying Product Numbers: Bromocresol Purple - Bromothymol Blue Mixed Indicator, 1% / 0.2% (w/v) in Methanol 1315 1315-4 1.2. Recommended Use and Restrictions on Use General Laboratory Reagent 1.3. Details of the Supplier of the Safety Data Sheet Ricca Chemical Company 448 West Fork Drive Arlington, TX 76012 USA [PHONE REDACTED] Company: Address: Telephone: 1.4. Emergency Telephone Number (24 hr) CHEMTREC (USA) CHEMTREC (International) [PHONE REDACTED] 1+ [PHONE REDACTED] SECTION 1: Identification Product Number: 1315 Page 1 of 11 Page 23 of 136 Page 23 of 136 Page 23 of 136 Page 23 of 136 ---PAGE BREAK--- Safety Data Sheet Hazard Class Category Hazard Statement Precautionary Statements P264, P270, P301+P310, P321, P330, P405, P501 H301 Category 3 Acute Toxicity - Oral P280, P302+P352, P312, P321, P361, P405, P501 H311 Category 3 Acute Toxicity - Dermal P261, P271, P304+P340, P311, P321, P403+P233, P405, P501 H331 Category 3 Acute Toxicity - Inhalation P264, P280, P305+P351+P338, P337+P313 H319 Category 2A Eye Damage / Irritation P201, P202, P280, P308+P313, P405, P501 H360 Category 1 Reproductive Toxicity P260, P264, P270, P307+P311, P321, P405, P501 H370 Category 1 Specific Target Organs/Systemic Toxicity Following Single Exposure P260, P264, P270, P314, P501 H372 Category 1 Specific Target Organs/Systemic Toxicity Following Repeated Exposure P210, P233, P240, P241, P242, P243, P280, P303+P361+P353, P370+P378, P403+P235, P501 H225 Category 2 Flammable Liquids For the full text of the Hazard and Precautionary Statements listed below, see Section 16. 2.1. Classification of the Substance or Mixture (in accordance with OSHA HCS 29 CFR 1910.1200) SECTION 2: Hazard(s) Identification 2.2. GHS Label Elements Pictograms: Signal Word: Danger Hazard Statements: Hazard Number Hazard Statement H225 Highly flammable liquid and vapor. H301 Toxic if swallowed. H311 Toxic in contact with skin. H319 Causes serious eye irritation. H331 Toxic if inhaled. H360 May damage fertility or the unborn child. H370 Causes damage to organs. H372 Causes damage to organs through prolonged or repeated exposure. Product Number: 1315 Page 2 of 11 Page 24 of 136 Page 24 of 136 Page 24 of 136 Page 24 of 136 ---PAGE BREAK--- Safety Data Sheet Precautionary Statements: Precautionary Statement Precautionary Number P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, sparks and open flame. No smoking. P233 Keep container closed. P240 Ground container and receiving equipment. P241 Use explosion-proof equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe dust, fumes or mist. P261 Avoid breathing dust, fumes or mist. P264 Wash arms, hands and face thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves and eye protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or physician. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P307+P311 IF exposed: Call a POISON CENTER or physician. P308+P313 IF exposed or concerned: Get medical attention. P311 Call a POISON CENTER or physician. P312 Call a POISON CENTER or physician if you feel unwell. P314 Get medical attention if you feel unwell. P321 Specific treatment (Wash areas of contact with water). P330 Rinse mouth. P337+P313 If eye irritation persists: Get medical attention. P361 Take off immediately all contaminated clothing and wash it before reuse. P403+P233 Store in a well-ventilated place. Keep container closed. P405 Store locked up. P501 Dispose of contents in accordance with local, state, federal and international regulations. 2.3. WHMIS Classification WHMIS classification is not included based on the recommended option (Option 4) found in the Canada Gazette Part II, Vol. 149, No.3, page 458 Product Number: 1315 Page 3 of 11 Page 25 of 136 Page 25 of 136 Page 25 of 136 Page 25 of 136 ---PAGE BREAK--- Safety Data Sheet 2.4. Hazards not Otherwise Classified or Covered by GHS Data not available. SECTION 3: Composition / Information on Ingredients 3.1. Components of Substance or Mixture Chemical Name Formula Molecular Weight CAS Number Weight% Methyl Alcohol CH₃OH 32.04 g/mol 67-56-1 98.50% Bromocresol Purple C₂₁H₁₆Br₂O₅S 540.22 g/mol 115-40-2 1.25% Bromothymol Blue C₂₇H₂₈Br₂O₅S 624.38 g/mol 76-59-5 0.25% Eye Contact: SECTION 4: First-Aid Measures 4.1. General First Aid Information IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. May cause irritation with burning and stinging with possible damage to the cornea and conjunctiva. Inhalation: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Skin Contact: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Results in drying and cracking which can lead to secondary infections and dermatitis. Dermal absorption causes many of the of inhalation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or physician. Dilute immediately with water or milk. Induce vomiting. Call a physician. 4.2. Most Important and Effects, Acute and Delayed Flammable liquid. Primarily toxic by ingestion. Cannot be made non-poisonous. If ingested, give large quantity of water and induce vomiting. Call a physician. Contact may cause dryness and cracking of the skin. May cause irritation to the eyes. Wash areas of contact with water. May cause irritation of the respiratory system. EYE CONTACT: May cause irritation with burning and stinging with possible damage to the cornea and conjunctiva. SKIN CONTACT: Results in drying and cracking which can lead to secondary infections and dermatitis. Dermal absorption causes many of the of inhalation. 4.3. Medical Attention or Special Treatment Needed Specific treatment (Wash areas of contact with water). 5.1. Extinguishing Media Use water spray, dry chemical, alcohol foam, or carbon dioxide for extinguishing the surrounding fire. Water spray can be used to dilute spills to non-flammable mixtures. SECTION 5: Fire-Fighting Measures 5.2. Specific Hazards Arising from the Substance or Mixture Highly flammable liquid and vapor. Moderate explosion hazard and dangerous fire hazard when exposed to heat, sparks and open flames. Above flash point, vapor-air mixtures are explosive within flammable limits noted above. Sensitive to static discharge. Product Number: 1315 Page 4 of 11 Page 26 of 136 Page 26 of 136 Page 26 of 136 Page 26 of 136 ---PAGE BREAK--- Safety Data Sheet 5.3. Special Protective Equipment for Firefighters Wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6.1. Personal Precautions, Protective Equipment and Emergency Procedures Ground container and receiving equipment. Use explosion-proof equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves and eye protection. SECTION 6: Accidental Release Measures 6.2. Cleanup and Containment Methods and Materials Remove all sources of ignition. Contain spill. Do not flush to sewer. Absorb with suitable inert material (vermiculite, dry sand, etc) and place in a chemical waste container for proper disposal in an approved waste disposal facility. Ventilate area of spill. Have extinguishing agent available in case of fire. Use non-sparking tools and equipment. Dispose of in accordance with local regulations. 7.1. Precautions for Safe Handling and Storage Conditions Store locked up. As with all chemicals, wash hands thoroughly after handling. Avoid contact with eyes and skin. Protect from freezing and physical damage. Store in secure, flammable storage area away from all sources of ignition. Empty containers may be hazardous since they retain product residues. SECTION 7: Handling and Storage 8.1. Control Parameters Chemical Name Country Exposure Limit Limit Type Information Source TWA USA U.S. - OSHA - Final PELs - Time Weighted Averages (TWAs) Methyl Alcohol (67-56-1) 200 ppm TWA 260 mg/m³ TWA TLV-STEL USA ACGIH - Threshold Limit Values - Short Term Exposure Limits (TLV-STEL) Methyl Alcohol (67-56-1) 250 ppm STEL TLV-TWA USA ACGIH - Threshold Limit Values - Time Weighted Averages (TLV-TWA) Methyl Alcohol (67-56-1) 200 ppm TWA SECTION 8: Exposure Controls / Personal Protection 8.2. Exposure Controls Engineering Controls: Use only outdoors or in a well-ventilated area. A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limit. Respiratory Protection: If engineering controls do not maintain airborne concentrations below recommended exposure limits, an approved atmosphere supplied respirator must be worn. Skin Protection: Wear protective gloves and eye protection. Chemical resistant gloves. Eye Protection: Wear protective gloves and eye protection. Safety glasses or goggles. 8.3. Personal Protective Equipment Wear protective gloves and eye protection. If engineering controls do not maintain airborne concentrations below recommended exposure limits, an approved atmosphere supplied respirator must be worn. Chemical resistant gloves. Safety glasses or goggles. Product Number: 1315 Page 5 of 11 Page 27 of 136 Page 27 of 136 Page 27 of 136 Page 27 of 136 ---PAGE BREAK--- Safety Data Sheet Data not available. Data not available. Data not available. Data not available. Data not available. -0.77 Miscible at 20°C 0.8 1.1 128 hPa at 20°C Data not available. Data not available. 2.1 (butyl acetate = 1) 11°C Approximately 64.5°C - Approximately 64.5°C -98°C Data not available. Data not available. Slight, alcohol-like Liquid Reddish-orange liquid Appearance: Physical State: Odor: Odor Threshold: pH: Melting/Freezing Point: Initial Boiling Point /Range: Flash Point: Evaporation Rate: Flammability: Flammability/Explosive Limits: Vapor Pressure: Vapor Density: Relative Density: Solubility: Partition Coeffieient (n-Octanol/Water): Auto-Ignition Temperature: Decomposition Temperature: Viscosity: ExplosiveProperties: Oxidizing Properties: 9.1. Basic Physical and Chemical Properties SECTION 9: Physical and Chemical Properties 10.1. Reactivity and Chemical Stability Stable under normal conditions of use and storage. SECTION 10: Stability and Reactivity 10.2. Possibility of Hazardous Reactions Data not available. 10.3. Conditions to Avoid and Incompatible Materials Keep away from heat, sparks and open flame. No smoking. Keep container closed. Strong oxidizing agents such as Nitrates, Perchlorates or 10.4. Hazardous Decomposition Products Will not occur. Product Number: 1315 Page 6 of 11 Page 28 of 136 Page 28 of 136 Page 28 of 136 Page 28 of 136 ---PAGE BREAK--- Safety Data Sheet Acute Toxicity - Oral Exposure: Toxic if swallowed. Wash arms, hands and face thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Immediately call a POISON CENTER or physician. Specific treatment (Wash areas of contact with water). Rinse mouth. Store locked up. Dispose of contents in accordance with local, state, federal and international regulations. 11.1. Information on Toxicological Effects SECTION 11: Toxicological Information Acute Toxicity - Dermal Exposure: Toxic in contact with skin. Wear protective gloves and eye protection. IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell. Specific treatment (Wash areas of contact with water). Take off immediately all contaminated clothing and wash it before reuse. Store locked up. Dispose of contents in accordance with local, state, federal and international regulations. Acute Toxicity - Inhalation Exposure: Toxic if inhaled. Avoid breathing dust, fumes or mist. Use only outdoors or in a well-ventilated area. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician. Specific treatment (Wash areas of contact with water). Store in a well-ventilated place. Keep container closed. Store locked up. Dispose of contents in accordance with local, state, federal and international regulations. Acute Toxicity - Other Information: LD50, Oral, Rat: (Methanol) 5628 mg/kg, details of toxic effects not reported other than lethal dose value. Skin Corrosion and Irritation: Not applicable. Serious Eye Damage and Irritation: Causes serious eye irritation. Wash arms, hands and face thoroughly after handling. Wear protective gloves and eye protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Respiratory Sensitization: Not applicable. Skin Sensitization: Not applicable. Germ Cell Mutagenicity: Not applicable. Carcinogenicity: Not applicable. Reproductive Toxicity: May damage fertility or the unborn child. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves and eye protection. IF exposed or concerned: Get medical attention. Store locked up. Dispose of contents in accordance with local, state, federal and international regulations. Specific Target Organ Toxicity from Single Exposure: Causes damage to organs. Do not breathe dust, fumes or mist. Wash arms, hands and face thoroughly after handling. Do not eat, drink or smoke when using this product. IF exposed: Call a POISON CENTER or physician. Specific treatment (Wash areas of contact with water). Store locked up. Dispose of contents in accordance with local, state, federal and international regulations. Product Number: 1315 Page 7 of 11 Page 29 of 136 Page 29 of 136 Page 29 of 136 Page 29 of 136 ---PAGE BREAK--- Safety Data Sheet Specific Target Organ Toxicity from Repeated Exposure: Causes damage to organs through prolonged or repeated exposure. Do not breathe dust, fumes or mist. Wash arms, hands and face thoroughly after handling. Do not eat, drink or smoke when using this product. Get medical attention if you feel unwell. Dispose of contents in accordance with local, state, federal and international regulations. Aspiration Hazard: Not applicable. Additional Toxicology Information: Data not available. 12.1. Ecotoxicity Not applicable. SECTION 12: Ecological Information 12.2. Persistence and Degradability Data not available. 12.3. Bioaccumulative Potential Data not available. 12.4. Mobility in Soil Data not available. 12.5. Other Adverse Ecological Effects Data not available. 13.1. Waste Treatment Methods Data not available. SECTION 13: Disposal Considerations II 3 Methanol Solution UN1230 UN Number: Proper Shipping Name: Hazard Class: Packing Group: Hazard Placard Labels: 14.1. Transportation by Land - Department of Transportation (DOT, United States of America) SECTION 14: Transportation Information Product Number: 1315 Page 8 of 11 Page 30 of 136 Page 30 of 136 Page 30 of 136 Page 30 of 136 ---PAGE BREAK--- Safety Data Sheet II 3 Methanol Solution UN1230 UN Number: Proper Shipping Name: Hazard Class: Packing Group: Hazard Placard Labels: 14.2. Transportation by Air - International Air Transport Association (IATA) 15.1. Occupational Safety and Health Administration (OSHA) Hazards Not listed. SECTION 15: Regulatory Information 15.2. Superfund Amendments and Reauthorization Act (SARA) 302 Extremely Hazardous Substances Not listed. 15.3. Superfund Amendments and Reauthorization Act (SARA) 311/312 Hazardous Chemicals Methyl Alcohol (CAS # 67-56-1): 5000 lb final RQ; 2270 kg final RQ 15.4. Superfund Amendments and Reauthorization Act (SARA) 313 Toxic Release Inventory (TRI) Methyl Alcohol (CAS # 67-56-1): 1.0 % de minimis concentration 15.5. Massachusetts Right-to-Know Substance List Methyl Alcohol (CAS # 67-56-1): Present 15.6. Right-to-Know Hazardous Substances Methyl Alcohol (CAS # 67-56-1): Environmental hazard Methyl Alcohol (CAS # 67-56-1): Present 15.7. New Jersey Worker and Community Right-to-Know Components Methyl Alcohol (CAS # 67-56-1): flammable - third degree; teratogen Methyl Alcohol (CAS # 67-56-1): sn 1222 Methyl Alcohol (CAS # 67-56-1): SN 1222 TPQ: 500 lb 15.8. California Proposition 65 Methyl Alcohol (CAS # 67-56-1): developmental toxicity, initial date 3/16/12 15.9. Canada Domestic Substances List / Non-Domestic Substances List (DSL/NDSL) Bromocresol Purple (CAS # 115-40-2): Present Methyl Alcohol (CAS # 67-56-1): Present Bromothymol Blue (CAS # 76-59-5): Present Product Number: 1315 Page 9 of 11 Page 31 of 136 Page 31 of 136 Page 31 of 136 Page 31 of 136 ---PAGE BREAK--- Safety Data Sheet 15.10. United States of America Toxic Substances Control Act (TSCA) List Bromocresol Purple (CAS # 115-40-2): Present Methyl Alcohol (CAS # 67-56-1): Present Bromothymol Blue (CAS # 76-59-5): Present 15.11. European Inventory of Existing Commercial Chemical Substances (EINECS), European List of Notified Chemical Substances (ELINCS), and No Longer Polymers (NLP) Not listed. SECTION 16: Other Information 16.1. Full Text of Hazard Statements and Precautionary Statements Highly flammable liquid and vapor. Toxic if swallowed. Toxic in contact with skin. Causes serious eye irritation. Toxic if inhaled. May damage fertility or the unborn child. Causes damage to organs. Causes damage to organs through prolonged or repeated exposure. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat, sparks and open flame. No smoking. Ground container and receiving equipment. Use explosion-proof equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust, fumes or mist. Wash arms, hands and face thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye protection. IF SWALLOWED: Immediately call a POISON CENTER or physician. IF ON SKIN: Wash with plenty of soap and water. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed: Call a POISON CENTER or physician. Get medical attention if you feel unwell. Specific treatment (Wash areas of contact with water). Rinse mouth. If eye irritation persists: Get medical attention. In case of fire: Use dry chemical, foam or carbon dioxide to extinguish. Store in a well-ventilated place. Keep container closed. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents in accordance with local, state, federal and international regulations. 16.2. Miscellaneous Hazard Classes Not Applicable. Not Applicable. Not Applicable. Not Applicable. Canadian Carcinogenicity Hazard Class: Physical Hazards Not Otherwise Classified (PHNOC): Health Hazards Not Otherwise Classified (HHNOC): Product Number: 1315 Page 10 of 11 Page 32 of 136 Page 32 of 136 Page 32 of 136 Page 32 of 136 ---PAGE BREAK--- Safety Data Sheet 16.3. National Fire Protection Association (NFPA) Rating 1 0 3 0 3 1 Health: Flammability: Reactivity: Special Hazard: 16.4. Document Revision Last Revision Date: 5/1/2015 DISCLAIMER When handled properly by qualified personnel, the product described herein does not present a significant health or safety hazard. Alteration of its characteristics by concentration, evaporation, addition of other substances, or other means may present hazards not specifically addressed herein and which must be evaluated by the user. The information furnished herein is believed to be accurate and represents the best data currently available to us. No warranty, expressed or implied, is made and RICCA CHEMICAL COMPANY assumes no legal responsibility or liability whatsoever resulting from its use. Product Number: 1315 Page 11 of 11 Page 33 of 136 Page 33 of 136 Page 33 of 136 Page 33 of 136 ---PAGE BREAK--- TRI-CHEM CORPORATION MATERIAL SAFETY DATA SHEET MFG.CODE # HR24200 SECTION I MANUFACTURER’S NAME TRI-CHEM CORPORATION EMERGENCY TELEPHONE NO. Chemtrec: [PHONE REDACTED] ADDRESS (Street, City, State and Zip Code) P. O. BOX 71550, MADISON HGTS., MI 48071-0550 CHEMICAL NAME AND SYNONYMS N/A TRADE NAME AND SYNONYMS BRUSH KLEAN (aerosol) CHEMICAL FAMILY N/A FORMULA N/A SECTION II – HAZARDOUS INGREDIENTS HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES % TLV (UNITS) Sodium Metasilicate CAS #6834-92-0 >1 N/ Citrus Terpene CAS #5989-27-5 >1 Polyethoxylate CAS #9002-93-7 >1 Liquified Petroleum Gas CAS #68476-85-7 >1 1000 ppm All components of this product are listed on the E.P.A./TSCA inventory of chemical substances. SECTION III – PHYSICAL DATA BOILING POINT (ºF) 212°F SPECIFIC GRAVITY (H2O = 1) 0.99 VAPOR PRESSURE (mm. Hg.) 63 PERCENT VOLATILE BY VOLUME 85 VAPOR DENSITY (AIR = 1) heavier EVAPORATION RATE ( Water 1 SOLUBILITY IN WATER complete PH 7 APPEARANCE AND ODOR SECTION IV – FIRE AND EXPLOSION DATA Lel Uel FLASH POINT (Method Used) None T.O.C. FLAMMABLE LIMITS N/A N/A EXTINGUISHING MEDIA Foam, Dry chemical, Carbon dioxide SPECIAL FIRE FIGHTING PROCEDURES fighters should wear full protective clothing including self-contained respiratory equipment operated in a positive mode. Use water spray to keep containers cool. UNUSUAL FIRE AND EXPLOSION HAZARDS Cans may vent, rupture, or burst when exposed to temperatures in excess of 120° F. (Continued on reverse side) Page 34 of 136 Page 34 of 136 Page 34 of 136 Page 34 of 136 ---PAGE BREAK--- SECTION V – HEALTH HAZARD DATA THRESHOLD LIMIT VALUE 1000 ppm PRIMARY ROUTES OF ENTRY Inhalation Skin Contact Other (Specify) EFFECTS OF OVEREXPOSURE Eyes – slight irritation. Skin – prolonged contact may cause irritation. Inhalation – nasal and respiratory irritation, dizziness, nausea, CNS effects. Ingestion – irritation, nausea, diarrhea EMERGENCY AND FIRST AID PROCEDURE Eyes – flush with copious amounts of water lifting lids and removing contact lenses to ensure complete irrigation – get medical attention. Skin – flush with water and then wash with soap and water, launder contaminated clothing before reuse. Inhalation – remove to fresh air and assist breathing as necessary – get medical attention. Ingestion – DO NOT INDUCE VOMITING – aspiration of material into lungs will be harmful or fatal - get immediate medical attention. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None Known Carcinogen: NTP IARC OTHER No SECTION VI – REACTIVITY DATA UNSTABLE STABILITY STABLE X CONDITIONS TO AVOID Temperatures in excess of 120° F INCOMPATABILITY (Conditions to avoid) Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS Oxides of Carbon MAY OCCUR HAZARDOUS POLYMERIZATION WILL NOT OCCUR X CONDITIONS TO AVOID None SECTION VII – SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Eliminate all sources of ignition and ventilate area. Use absorbent material to soak up spill. Shovel or sweep into container for disposal WASTE DISPOSAL METHOD In accordance with all local, state and federal regulations. SECTION VIII – SPECIAL PROTECTION INFORMATION SPECIAL RESPIRATORY PROTECTION (Specify type) None needed for proper use in accordance with label directions. LOCAL EXHAUST Normal ventilation adequate SPECIAL N/A VENTILATION MECHANICAL (General) Normal ventilation adequate OTHER N/A PROTECTIVE GLOVES Impervious EYE PROTECTION Chemical goggles OTHER PROTECTIVE EQUIPMENT Eyewash and safety shower SECTION IX – SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Avoid contact – wear protective clothing and wash thoroughly after using. Avoid inhalation of vapors – use only with adequate ventilation. Do not take internally. Do not store in areas where temperatures may exceed 120° F. Read and follow label directions. OTHER PRECAUTIONS Keep Out of Reach of Children HMIS SYMBOL HMIS NFPA NFPA SYMBOL SEVERE 4 EXTREME FIRE REACTIVITY SERIOUS 3 HIGH 0 MODERATE 2 MODERATE 1 1 SLIGHT 1 SLIGHT TOXICITY MINIMAL 0 INSIGNIFICANT SPECIAL NAME John Telles SIGNATURE TITLE CHEMIST PREPARATION DATE July 12, 2007 PHONE NUMBER Chemtrec: [PHONE REDACTED] HEALTH 1 FLAMMABILITY 0 REACTIVITY 1 Page 35 of 136 Page 35 of 136 Page 35 of 136 Page 35 of 136 ---PAGE BREAK--- SAFEW DATA SHEET CEB31600 CORPOMTE EXPRESS HAND CLEANING WIPES TUB 1OO Page 1 lssued: 04/07/2008 Revision No: 1 1 . IDENTIFICATION OF THE SUBSTANCE T PREPARATION AND OF THE COMPANY I UNDERTAKING Product name: Product code: Synonyms: Gompany name: CEB31600 CORPOMTE EXPRESS HAND CLEANING WIPES TUB 1OO cE831600 OTHER PRODUCT REFERENCES: 327-50-007 Sourcing Partner Inc 1400 Lavon Drive Suite 200 McKinney TX75069 USA Tel: 001 [PHONE REDACTED] Fax:001 [PHONE REDACTED] 2, HAZARDS IDENTIFICATION Main hazards: No significant hazard. 3. COMPOSITION / INFORMATION ON INGREDIENTS Contains: Propane-1 ,2-DIOL 0.75o/o Cas Nr: 57-55-6 Einecs 200-338-0 No significant hazardous 4. FIRST AID MEASURES Skin contact: Eye contact: Ingestion: Inhalation: No There may be irritation and redness There may be initation of the throat. No 4. FIRST ArD MEASURES (ACTTON) Eye contact: Bathe the eye with running water for 15 minutes. Ingestion: lf conscious, give half a litre of water to drink immediately. 5. FIRE.FIGHTING.MEASURES Extinguishing media: Protection of fire-f i ghters: Suitable extinguishing media for the surrounding fire should be used. Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin ano eyes. 6. ACGIDENTALRELEASE MEASURES Personal precautions: Environmental precautions: Clean-up procedures: Refer to section 8 of SDS for personal protection details. Turn leaking containers leak-side up to prevent the escape of liquid. Do not discharge into drains or rivers. Contain the spillage using bunding. Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. lcont...l Page 36 of 136 Page 36 of 136 Page 36 of 136 Page 36 of 136 ---PAGE BREAK--- lssued: 04/07/2008 SAFETY DATA SHEET CEB31600 CORPOMTE EXPRESS HAND CLEANING WIPES TUB 1OO Page 2 7. HANDLINGANDSTORAGE Storage conditions: Store in cool, well ventilated area. Keep container closed. Do not allow to freeze Suitable packaging: Must only be kept in original packaging. 8. EXPOSURE CONTROLS I PERSONAL.PROTECTION Workplace exposure limits WEL (15 min STEL): Respirable dust WEL (8 hrTWA): WEL (15 min STEL): Respiratory protection: Eye protection: 10 150 474 Respiratory protection not required. Ensure eye bath is to hand. 9. PHYSICALAND CHEMICAL PROPERTIES State: Colour: Odour: Solubility in water: Boiling poinUrange'C: Relative density: pH: Liquid Colourless Characteristic odour Soluble >1 00 1.00 - 1.10 5.3 - 5.7 10. STABILIW AND REACTIVIW Stability: Stable under normal conditions. Conditions to avoid: Do NOT freeze Materials to avold: Strong oxidising agents. Strong acids. 1 1. TOXICOLOGICAL INFORMATION Chronic toxicity: May cause irritation to the eyes Routes of exposure: Refer to section 4 of SDS for routes of exposure and corresponding 1 2. ECOLOGICAL INFORMATION Mobility: Persistence and degradability: Bioaccumulative potential : Other adverse effects: Readily absorbed into soil Biodegradable. No data available. No data available. 1 3, DISPOSAL. CONSIDERATIONS NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal. lcont...l Page 37 of 136 Page 37 of 136 Page 37 of 136 Page 37 of 136 ---PAGE BREAK--- lssued: 04/07/2008 SAFETY DATA SHEET CEB31600 CORPORATE EXPRESS HAND CLEANING WIPES TUB 1OO Page 3 14. INFORMATION ADR / RID UN no: Not Classified IMDG / IMO UN no: Not Classified. IATA/ ICAO UN no: Not Classified 1 5. REGULATORY INFORMATION Hazard symbols: Safety phrases: Note: No significant hazard. 52: Keeo out of the reach of children. The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the safety data sheet. The user's attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all applicable national, international and local regulations or provisions. 16. OTHER INFORMATION Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product. [final page] Page 38 of 136 Page 38 of 136 Page 38 of 136 Page 38 of 136 ---PAGE BREAK--- Page 39 of 136 Page 39 of 136 Page 39 of 136 Page 39 of 136 ---PAGE BREAK--- The Clorox Company of Canada, Ltd. Material Safety 150 Biscayne Crescent Data Sheet Brampton, Ontario L6W 4V3 SECTION 1 - PRODUCT IDENTIFICATION AND USE PRODUCT NAME: CLOROX® COMMERCIAL SOLUTIONS™ ULTRA CLOROX® DISINFECTING BLEACH - DIN 02333007 PRODUCT IDENTIFICATION NUMBER: Not applicable. PRODUCT USE: Hard surface disinfecting bleach MANUFACTURER SUPPLIER The Clorox Company of Canada, Ltd. 150 Biscayne Crescent Brampton, Ontario L6W 4V3 EMERGENCY PHONE NO.: 1-[PHONE REDACTED] The Clorox Company of Canada, Ltd. 150 Biscayne Crescent Brampton, Ontario L6W 4V3 EMERGENCY PHONE NO.: 1-[PHONE REDACTED] SECTION 2 - HAZARDOUS INGREDIENTS Hazardous Ingredient % (w/w) CAS Number LD50 of Material (Specify Species & Route) LC50 of Material (Specify Species) Sodium hypochlorite 5 - 8 7681-52-9 13 g/kg (5.25% NaOCl, rat, oral) Not available. SECTION 3 - PHYSICAL DATA Physical State: Liquid Odour & Appearance: Clear, lime-yellow, thin liquid with characteristic bleach odour. Odour Threshold: Not available. Specific Gravity: 1.1 at 20°C Vapour Pressure: Not available. Vapour Density: N. Av. Evaporation Rate: N. Av. Boiling Point: N. Av. Freezing Point: N. Av. % Volatile (by volume): 85 - 90 Solubility in Water: Complete. pH: 11 - 12 Coeff. of Water/Oil Dist.: Not available. SECTION 4 - FIRE AND EXPLOSION DATA Flammability: Yes: No: X If yes, under which conditions? Means of Extinction: Not flammable. Special Procedures: In a fire, cool containers to prevent rupture and release of sodium chlorate. Flashpoint & Method: Not applicable. Upper Flammable Limit by volume): Not applicable. Lower Flammable Limit by volume): Not applicable. Autoignition Temperature: N. Ap. Hazardous Combustion Products: Not applicable. Explosion Data - Sensitivity to Impact: Not applicable. Explosion Data - Sensitivity to Static Discharge: Not applicable. SECTION 5 - REACTIVITY DATA Chemical Stability: Yes: X No: If no, under which conditions? Incompatibility with other substances: Yes: X No: If so, which ones? Reacts with other chemicals such as toilet bowl cleaners, rust removers, acids, and ammonia-containing products to produce hazardous gases, such as chlorine and other chlorinated compounds. Avoid contact with metals, reducing agents, and other oxidizing agents. Reactivity, if any, and under what conditions? See above. Hazardous decomposition products? Exposure to extreme heat may release sodium chlorate. Clorox® Commercial Solutions™ Ultra Clorox® Disinfecting Bleach, Page 1 of 2 Page 40 of 136 Page 40 of 136 Page 40 of 136 Page 40 of 136 ---PAGE BREAK--- SECTION 6 - TOXICOLOGICAL PROPERTIES Route of Entry? Skin Contact: X Skin Absorption: Eye Contact: X Inhalation Acute: X Inhalation Chronic: Ingestion: X . Effects of Acute Exposure to Material: May cause severe irritation or damage (burns) to eyes, skin, gastrointestinal tract, and respiratory tract. Harmful if swallowed. Exposure to high concentrations of vapour or mist may aggravate the following medical conditions: heart conditions or chronic respiratory problems such as asthma, chronic bronchitis, or obstructive lung disease. Effects of Chronic Exposure to Material: See Sensitization section below. Exposure Limits (TLV, ACGIH): Not applicable. Irritancy of Material: Corrosive to eyes. Severely irritating or corrosive to skin, nose, lungs, throat, and gastrointestinal tract. Sensitization Property of Material: Some clinical reports suggest a low potential for skin sensitization upon exaggerated exposure to sodium hypochlorite if skin damage occurs during exposure. Carcinogenicity of Material: Not a carcinogen. Teratogenicity/Embryotoxicity: Not teratogenic or embryotoxic. Reproductive Toxicity: Not a reproductive toxicant. Mutagenicity: Not mutagenic. Synergistic Materials: None known. SECTION 7 - PREVENTATIVE MEASURES Personal Protective Equipment: Gloves (specify): Wear nitrile, neoprene, butyl rubber, or other protective gloves. Respirator (specify): In situations where high concentrations of vapour or mist may be generated, a NIOSH-approved respirator is advised. Eye (specify): Safety glasses. Footwear (specify): Not applicable. Clothing (specify): Not applicable. Other (specify): Not applicable. Engineering Controls (specify, e.g. ventilation, enclosed process): Use general ventilation to minimize exposure to product vapour or mist. Leak and Spill Procedure: Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed-down material. For spills of multiple products, responders should evaluate the MSDS’s of the products for incompatibility with sodium hypochlorite. Breathing protection should be worn in enclosed and/or poorly-ventilated areas until hazard assessment is complete. Waste Disposal: Dispose of in accordance with existing federal, provincial, and municipal environmental regulations. Handling Procedures & Equipment: Wash hands after direct contact. Do not wear product-contaminated clothing for prolonged periods. Do not reuse empty container. Rinse container and replace cap before recycling or discarding. Storage Requirements: STORE AWAY FROM CHILDREN. Reclose cap after each use. Store this product upright in a cool, dry area away from direct sunlight and heat to avoid deterioration. Special Shipping Information: Not restricted per TDG regulations. SECTION 8 - FIRST AID MEASURES Eye Contact: If in eyes, rinse with water for 15 minutes. Call a doctor immediately. Skin Contact: If on skin, rinse well with water. If on clothes, remove clothes. If irritation persists, call a doctor. Ingestion: If swallowed, call a poison control centre or doctor immediately. Do not induce vomiting. Inhalation: If breathed in, move person to fresh air. If breathing problems develop, call a doctor. SECTION 9 - PREPARATION DATE OF MSDS Prepared by (group, department, etc.) Phone Number: Date: Clorox Services Company 1-[PHONE REDACTED] July 19, 2013 V1 This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of The Clorox Company of Canada, Ltd. The data on these sheets relates only to the specific material designated herein. The Clorox Company of Canada, Ltd. assumes no legal responsibility for use or reliance upon this data. The CLOROX name and logo are registered trademarks of The Clorox Company. N. Av. = Not available. N. Ap. = Not applicable. © 1996 The Clorox Company Clorox® Commercial Solutions™ Ultra Clorox® Disinfecting Bleach, Page 2 of 2 Page 41 of 136 Page 41 of 136 Page 41 of 136 Page 41 of 136 ---PAGE BREAK--- 922433 MATERIAL SAFETY DATA SHEET MEDICAL EMERGENCIES ONLY (24 Hour Service): 1-[PHONE REDACTED] Medical Calls from Outside of the USA: 1-[PHONE REDACTED] ECOLAB FOOD & BEVERAGE DIVN. Ecolab Center St. Paul MN 55102 Product Information: 1-[PHONE REDACTED] Issue Date: November 16, 2000 1.0 IDENTIFICATION / 1.1 Product Name: CONSERVE 1.2 Product Type: Liquid High Chelant Alkaline Cleaner 1.3 Hazard Rating: Health: 2 Fire: 0 Reactivity: 0 Substances Subject to SARA 313 Reporting Are Indicated by 2.0 HAZARDOUS COMPONENTS / (in mg/m3) CAS No. % PEL TWA 2.1 Chelating agents mixture 20-50 No No 2.2 Triethanolamine 102-71-6 1-5 No 5 2.3 Nonionic surfactant proprietary 1-5 No No PEL = OSHA 8 Hour Average in Air TWA = ACGIH 8 Hour Average in Air 3.0 PHYSICAL DATA / 3.1 Appearance: Clear, light amber liquid 3.2 Solubility in Water: Mixes with water in all proportions 3.3 pH: 9.5 3.4 Initial Boiling Point: > 212 deg F / 100 deg C 3.5 Specific Gravity: 1.195 @ 68 deg F / 20 deg C 4.0 FIRE AND EXPLOSION DATA / 4.1 Special Fire Hazards: None, does not support combustion. 4.2 Fire Fighting Methods: Use method appropriate for surrounding fire. 5.0 REACTIVITY DATA / 5.1 Stability: Stable under normal conditions of use and handling. 5.2 Conditions to Avoid: No special requirements; use standard industrial practices. Use as directed. 6.0 SPILL OR LEAK PROCEDURES / USE PROPER PROTECTIVE EQUIPMENT 6.1 Cleanup: Dike or dam large spills. Pump to containers or soak up on inert absorbent. Flush residue to sanitary sewer. 6.2 Waste Disposal: Consult state/local authorities for limits on chemical waste disposal. 7.0 HEALTH HAZARD DATA / WARNING 7.1 Effects of Overexposure to Concentrate: Eyes: Causes minor to moderate irritation. Skin: Prolonged or repeated exposure may cause minor irritation. If Swallowed: May cause stomach distress, nausea or vomiting. 8.0 FIRST AID / 8.1 Eyes: Flush with cool running water. Remove contact lenses and continue flushing for 15 minutes. 8.2 Skin: Flush skin with water; wash with soap and water. Remove and wash contaminated clothing before reuse. Page 1 of 2 Material Safety Data Sheet - Product #46641 2007-03-17 Created with novaPDF Printer (www.novaPDF.com). Please register to remove this message. Page 42 of 136 Page 42 of 136 Page 42 of 136 Page 42 of 136 ---PAGE BREAK--- 8.3 If Swallowed: Rinse mouth; then drink 1 or 2 large glasses of water. DO NOT induce vomiting. NEVER give anything by mouth to an unconscious person. IF IRRITATION OR DISCOMFORT PERSISTS, CALL A PHYSICIAN. 9.0 PROTECTIVE MEASURES / 9.1 FOR CONCENTRATE: Eyes: Wear chemical splash goggles. Skin: Wear any impervious glove. 10.0 ADDITIONAL INFORMATION / 10.1 Purpose of 11/16/2000 issue: Minor formula change; associated edits. QC and editorial update. Replaces August 27, 1997 issue. KEEP OUT OF REACH OF CHILDREN The above information is believed to be correct with respect to the formula used to manufacture the product. As data, standards and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION. Page 2 of 2 Material Safety Data Sheet - Product #46641 2007-03-17 Created with novaPDF Printer (www.novaPDF.com). Please register to remove this message. Page 43 of 136 Page 43 of 136 Page 43 of 136 Page 43 of 136 ---PAGE BREAK--- SDS for CRITERION® 90 SRM 1 of 8 Vesuvius USA 495 Emma Street, Bettsville, Ohio 44815 Safety Data Sheet CRITERION® 90 SRM SDS Number SDS-30567 Revision: 1 Legacy Number: LEB31741 Preparation Information: Site: All Contact Deb Cook @ (419) 986-5126 for further product information or medical emergency during normal business hours. Section 1: Product and Company Identification Product Name: CRITERION® 90 SRM Chemical Name: Mixture Formula: N/A CAS Number: N/A Product Use: Advanced Refractories Supplier Information: Supplier Name: Vesuvius USA Supplier Phone: (419) 986-5126 Supplier Address: 495 Emma Street Bettsville, OH 44815 Manufacturer Information: Manufacturer Name: Vesuvius USA Manufacturer Phone: (419) 986-5126 Manufacturer Address: 495 Emma Street Bettsville, OH 44815 Emergency Contact Information: CHEMTREC (800) 424-9300 (USA) CANUTEC (613) 996-6666 (CANADA) Page 44 of 136 Page 44 of 136 Page 44 of 136 Page 44 of 136 ---PAGE BREAK--- SDS for CRITERION® 90 SRM 2 of 8 Section 2: Hazard(s) Identification Hazard Classification: Skin Corrosion/Irritation - Category 2 Serious Eye Damage/Eye Irritation - Category 2 Specific Target Organ Toxicity, Repeated or Prolonged Exposure - Category 2 Signal Word: Warning Hazard Statement(s): Causes mild skin irritation Causes eye irritation May cause respiratory irritation Pictograms: Precautionary Statement(s): Prevention Do not eat, drink, or smoke when using this product. Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. Wash thoroughly after handling. Response If eye irritation persists, remove contact lenses if necessary and rinse eyes with water. Seek medical attention if needed. If skin is irritated, wash with plenty of soap and water. Seek medical attention if needed. If breathing is difficult, remove victim to fresh air and keep at rest in comfortable position, seek medical advice/attention. Storage Product contains chemicals, which will upon exposure to moisture result in product consolidation. Store in a dry place. Disposal This product, as manufactured, does not exhibit any characteristics of a hazardous waste. It is suitable for landfill disposal. However, debris generated during installation, maintenance or tear-out procedures may be contaminated with other hazardous materials. Therefore, appropriate waste analysis may be necessary to determine proper disposal. A qualified environmental professional in accordance with applicable federal, state, and local regulations should determine waste characterisation and disposal/treatment methods. Hazards not Otherwise Classified: N/A Percentage of the mixture consisting of ingredients of unknown toxicity: N/A Section 3: Composition/Information on Ingredients Ingredient: CAS No. / Other Identifiers: % Weight: Aluminum Oxide, non-fibrous 1344-28-1 85-95 Calcium Aluminate 12042-68-1 3-7 Magnesium Oxide 1309-48-4 3-7 Page 45 of 136 Page 45 of 136 Page 45 of 136 Page 45 of 136 ---PAGE BREAK--- SDS for CRITERION® 90 SRM 3 of 8 Section 4: First Aid Measures Emergency Overview: Product is only an issue at tear-out when dust can occur. Potential Health Effects: Respiratory irritation can occur at tear-out when dust can occur. Chronic Health Hazards: Prolonged inhalation of product dust may cause lung damage. Medical Conditions Generally Aggravated by Exposure: Pre-existing skin and respiratory ailments. Routes of Entry: Eyes? Yes Skin? Yes Inhalation? Yes Ingestion? No Other? Carcinogenicity: NTP? No IARC? No OSHA? No WHMIS? No Other? Details: Dust from mixture can cause respiratory irritation. Calcium aluminate, when wet, can be a skin and eye irritant. Eye Contact: Immediately flush with water for a t least 15 minutes. If irritations persists, consult physician. Skin Contact: Immediately wash with cold water. If irritations persists, consult physician. Inhalation: Remove person to fresh air. If problems persist, consult physician. Ingestion: N/A Section 5: Fire-Fighting Measures Flash Point: N/A Auto-Ignition: N/A LEL: N/A UEL: N/A NFPA Hazard Classification: Health: 1 Flammable: 0 Reactivity: 0 Special Hazard: N/A HMIS Hazard Classification: Health: 1 Flammable: 0 Reactivity: 0 PPE: B Extinguishing Media: No special instructions or conditions. Special Fire Fighting Procedures: No special instructions other than use of approved respirators. Page 46 of 136 Page 46 of 136 Page 46 of 136 Page 46 of 136 ---PAGE BREAK--- SDS for CRITERION® 90 SRM 4 of 8 Product is not combustable. No hazardous decomposition products. Unusual Fire and Explosion Hazards: SENSITIVITY TO MECHANICAL IMPACT: N/A SENSITIVITY TO STATIC DISCHARGE: N/A OTHER: N/A Section 6: Accidental Release Measures Sweep or pick up with vacuum cleaner. Minimize dust levels and wear dust mask. Section 7: Handling and Storage Store in dry place to minimize exposure to moisture. Section 8: Exposure Controls/Personal Protection Exposure Limits Ingredient PEL-OSHA TLV-ACGIH Other Calcium Aluminate 5 mg/M3 (respirable) 5 mg/M3 (respirable) N/A Aluminum Oxide, non-fibrous 5 mg/M3 (respirable) 1 mg/M3 (respirable) N/A Magnesium Oxide 15 mg/M3 10 mg/M3 (inhalable) N/A Details: N/A Respiratory Protection: If PEL/TLV is exceeded, use NIOSH approved mask/respriator for above listed ingredients. Ventilation LOCAL: N/A SPECIAL: N/A MECHANICAL: As required to maintain levels below the listed PEL/TLVs. ENGINEERING CONTROLS: N/A Protective Equipment: GLOVES: anti slip gloves EYE: safety glasses CLOTHING: long sleeves Personnel Sampling Procedure: N/A PPE Symbols Displayed: Page 47 of 136 Page 47 of 136 Page 47 of 136 Page 47 of 136 ---PAGE BREAK--- SDS for CRITERION® 90 SRM 5 of 8 Section 9: Physical and Chemical Properties Chemical Properties Appearance (physical state, color, etc.): A dry gray mixture of fine materials. Odor: N/A Odor threshold: N/A pH: N/A Melting point/freezing point: N/A Initial boiling point and boiling range: N/A Flash point: N/A Evaporation rate: N/A Flammability (solid, gas): N/A Upper/lower flammability or explosive limits: N/A Vapor pressure: N/A Vapor density: N/A Relative density: N/A Solubility(ies): N/A Partition coefficient: n-octanol/water: N/A Auto ignition temperature: N/A Decomposition temperature: N/A Viscosity: N/A Other Relevant Properties: N/A Section 10: Stability and Reactivity Stability: Stable Avoid: N/A Reactivity: N/ANone Avoid: N/A Other: N/A Incompatibility: None Hazardous Decomposition of By-products None Polymerization: Will not occur Avoid: N/A Page 48 of 136 Page 48 of 136 Page 48 of 136 Page 48 of 136 ---PAGE BREAK--- SDS for CRITERION® 90 SRM 6 of 8 Section 11: Toxicological Information Chemical Name % Wt. LD50 LC50 Route of Exposure: Short / Long Term Exposure Effects: Known Carcinogen: N/A Other Studies: Section 12: Ecological Information Ecotoxicity: N/AV Environmental Fate: N/AV Section 13: Disposal Considerations Dispose of in accordance with local, state and federal regulations. Section 14: Transport Information International N/A United States N/A Canada SHIPPING NAME: N/A P.I.N/UN: N/A PRIMARY CLASS: N/A SUBSIDIARY CLASS: N/A PACKING GROUP: N/A European Community N/A Section 15: Regulatory Information US Federal Regulations TSCA All components of this product are included on the EPA TSCA Chemical Substance Inventory. SARA 311 and 312 Hazard Categories: Immediate (Acute) Health Hazard: Yes Delayed (Chronic) Health Hazard: No Fire Hazard: No Reactivity: No Page 49 of 136 Page 49 of 136 Page 49 of 136 Page 49 of 136 ---PAGE BREAK--- SDS for CRITERION® 90 SRM 7 of 8 Sudden Release of Pressure: No SARA Section 313 Notification: This product contains no toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372, based upon our knowledge of the raw materials comprising this product. Ozone Depleting Substances: N/A Volatile Organic Compounds (VOC): N/A US State Regulation: N/A Canadian Regulation: WHMIS CLASSIFICATION: E This Product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. European Regulation: N/A Other Regulation: N/A MITI: N/A N/A is Not Applicable N/K is Not Known N/AV is Not Available Section 16: Other Information The product is a fired refractory brick/shape available in various sizes and shapes. It is composed of the mineral phases in Section 3, some of which may be present in dust generated by sawing, cutting, or crushing during installation or tear-out. Document Revision History: Revision: 1 Date Created: 06/12/2015 Date of Last Revision: 06/12/2015 Last Approval Date: 06/12/2015 Document Author: Deb Cook SDS Status: Page 50 of 136 Page 50 of 136 Page 50 of 136 Page 50 of 136 ---PAGE BREAK--- SDS for CRITERION® 90 SRM 8 of 8 Disclaimer Information contained within this safety data sheet is based on the current state of knowledge and relates to such products, their intended usage and the required safety precautions. Although every effort has been made to ensure that this information is correct and gives adequate safety margins in line with current knowledge, it does not constitute a specification and no information for other purposes, particularly information regarding properties of the delivered materials, may be inferred. Determination of the technical suitability of each material and complying with any guidance relating to safe usage remain the sole responsibility of the user. Consequently, beyond any separately agreed contractual arrangements, the aforementioned manufacturer and its subsidiaries exclude any and all liability resulting from the use of the product. Unknown hazards may be inherent in all materials; therefore these materials shall be treated with caution. Although certain hazards are described herein, we are unable to guarantee that these are the only hazards. Page 51 of 136 Page 51 of 136 Page 51 of 136 Page 51 of 136 ---PAGE BREAK--- Revision Date: 14-Aug-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: GS NEUTRAL DISINFECTANT CLEANER Product Number: 3502 , 3513 Recommended Use: Disinfectant Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification Acute Toxicity - Oral: Category 4 Skin Corrosion/Irritation: Category 1 Serious Eye Damage/Eye Irritation: Category 1 GHS Label Elements Signal Word: Danger Hazard Statements: Harmful if swallowed. Causes severe skin burns and serious eye damage. Precautionary Statements: Prevention: Wash hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product Do not breathe mist, vapors or spray. Wear protective gloves. Wear eye / face protection. Wear protective clothing. Response: IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. -Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. -Skin IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Wash contaminated clothing before reuse. -Inhalation: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. -Ingestion: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Store locked up. Page 1 / 5 Disposal: Dispose of contents and container in accordance with local, state and federal regulations. Symbols: Page 52 of 136 Page 52 of 136 Page 52 of 136 Page 52 of 136 ---PAGE BREAK--- 3502 - GS NEUTRAL DISINFECTANT CLEANER Revision Date: 14-Aug-2015 Hazards Not Otherwise Classified: Not Applicable Other Information: • Corrosive. • Inhalation of vapors or mist may cause respiratory irritation. • Keep out of reach of children. • NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. 0.134% of the mixture consists of ingredient(s) of unknown toxicity. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 60-100 dialkyl dimethyl ammonium chloride 68424-95-3 1-5 alkyl dimethyl benzyl ammonium chloride 68424-85-1 1-5 ethanol 64-17-5 1-5 tetrasodium ethylenediaminetetraacetate 64-02-8 0.1-1 alcohol ethoxylate 68439-46-3 0.1-1 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. -Skin Contact: Take off immediately all contaminated clothing and shoes. Rinse with water or shower for at least 15 minutes. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. Wash contaminated clothing before reuse. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. -Ingestion: Rinse mouth. Do NOT induce vomiting. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. Never give anything by mouth to an unconscious person. Note to Physicians: NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Product does not support combustion, Use extinguishing agent suitable for type of surrounding fire Specific Hazards Arising from the Chemical: Dried product is capable of burning. Combustion products are toxic. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Cool fire-exposed containers with water spray. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). Page 2 / 5 7. HANDLING AND STORAGE Page 53 of 136 Page 53 of 136 Page 53 of 136 Page 53 of 136 ---PAGE BREAK--- 3502 - GS NEUTRAL DISINFECTANT CLEANER Revision Date: 14-Aug-2015 Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Storage Conditions: Keep containers closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep from freezing. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: . Chemical Name ACGIH TLV OSHA PEL NIOSH ethanol 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Eye wash stations and shower facilities should be readily accessible in areas where the product is handled. Personal Protective Equipment Eye/Face Protection: Wear splash goggles. Skin and Body Protection: Wear rubber or other chemical-resistant gloves. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Liquid Color: Clear Odor: Mild pH: 6.0-7.0 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 100 °C / 212 °F Flash Point: > 100 °C / > 212 °F ASTM D56 Evaporation Rate: < 1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 1.0 Solubility(ies): Soluble in water Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 3 / 5 Decomposition Temperature: No information available. Viscosity: No information available. Page 54 of 136 Page 54 of 136 Page 54 of 136 Page 54 of 136 ---PAGE BREAK--- 3502 - GS NEUTRAL DISINFECTANT CLEANER Revision Date: 14-Aug-2015 Incompatible Materials: Strong oxidizing agents. Strong acids. Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Pain, redness, swelling of the conjunctiva and tissue damage. Eye contact may cause permanent damage. -Skin Contact: Pain, redness, blistering and possible chemical burn. -Inhalation: Nasal discomfort and coughing. -Ingestion: Damage or chemical burns to mouth, throat and stomach. Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 1837 mg/kg ATEmix (dermal): 5528 mg/kg ATEmix (inhalation-dust/mist): 23 mg/l Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available alkyl dimethyl benzyl ammonium chloride 68424-85-1 = 426 mg/kg ( Rat ) Not Available Not Available ethanol 64-17-5 = 7060 mg/kg ( Rat ) Not Available = 124.7 mg/L ( Rat ) 4 h tetrasodium ethylenediaminetetraacetate 64-02-8 = 10 g/kg ( Rat ) Not Available Not Available alcohol ethoxylate 68439-46-3 = 1378 mg/kg ( Rat ) > 2 g/kg ( Rabbit ) Not Available Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Microorganisms Crustacea ethanol 64-17-5 Not Available 12.0 - 16.0: 96 h mykiss mL/L LC50 static 100: 96 h Pimephales promelas mg/L LC50 static 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through Not Available 9268 - 14221: 48 h Daphnia magna mg/L LC50 10800: 24 h Daphnia magna mg/L EC50 2: 48 h Daphnia magna mg/L EC50 Static tetrasodium ethylenediaminetetraacetate 64-02-8 1.01: 72 h Desmodesmus subspicatus mg/L EC50 41: 96 h Lepomis macrochirus mg/L LC50 static 59.8: 96 h Pimephales promelas mg/L LC50 static Not Available 610: 24 h Daphnia magna mg/L EC50 Persistence and Degradability: No information available. Bioaccumulation: No information available. Page 4 / 5 Other Adverse Effects: No information available. Page 55 of 136 Page 55 of 136 Page 55 of 136 Page 55 of 136 ---PAGE BREAK--- 3502 - GS NEUTRAL DISINFECTANT CLEANER Revision Date: 14-Aug-2015 13. DISPOSAL CONSIDERATIONS Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT: Not Regulated Proper Shipping Name: Non-Hazardous Product Special Provisions: Shipping descriptions may vary based on mode of transport, quantities, package size, and/or origin and destination. Check with a trained hazardous materials transportation expert for information specific to your situation. IMDG: Not Regulated Proper Shipping Name: Non-Hazardous Product 15. REGULATORY INFORMATION TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product does not contain listed substances above the "de minimus" level SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: No Reactive Hazard: No California Proposition 65 This product is not subject to warning requirements under California Proposition 65. EPA Pesticide Registration Number: 1839-169-5741 EPA Statement: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: EPA Pesticide Label: Danger. Keep out of reach of children. Corrosive. Causes irreversible eye damage and skin burns. Do not get in eyes, on skin or on clothing. May be fatal if absorbed through the skin. Harmful if swallowed. Wear goggles or face shield, rubber gloves, and protective clothing. Remove contaminated clothing and wash before reuse. Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco. 16. OTHER INFORMATION Revision Date: 14-Aug-2015 Reasons for Revision: Section 11 Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 3 Flammability: 0 Instability: 0 Special: N/A HMIS Page 5 / 5 Health Hazards: 3 Flammability: 0 Physical Hazards: 0 Page 56 of 136 Page 56 of 136 Page 56 of 136 Page 56 of 136 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Gunk Glass Cleaner - Streak Free Product identifier Other means of identification GC1 SDS number GC1 Part No. 3402.90.5030 Tariff code Glass Cleaner Recommended use None known. Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufacturer RSC Chemical Solutions Address 600 Radiator Road Company name Website Telephone Customer Service: (704) 821-7643 Technical: (704) 684-1811 Emergency phone number Emergency Telephone: (303) 623-5716 Emergency Contact: ([PHONE REDACTED]) E-mail United States Indian Trail, NC 28079 2. Hazard(s) identification Category 1 Flammable aerosols Physical hazards Category 4 Acute toxicity, inhalation Health hazards Category 3 Hazardous to the aquatic environment, acute hazard Environmental hazards Not classified. OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Harmful if inhaled. Harmful to aquatic life. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing vapors. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Response If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. Storage Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information 6.07% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. 3. Composition/information on ingredients Mixtures 1 / 9 Material name: Gunk Glass Cleaner - Streak Free GC1 Version 02 Revision date: 08-10-2015 Issue date: 05-08-2015 SDS US Page 57 of 136 Page 57 of 136 Page 57 of 136 Page 57 of 136 ---PAGE BREAK--- CAS number % Common name and synonyms Chemical name 75-28-5 Isobutane 3 - < 5 67-63-0 Isopropyl Alcohol 1 - < 3 1336-21-6 AMMONIUM HYDROXIDE < 1 Other components below reportable levels 90 - 100 7632-00-0 SODIUM NITRITE < 0.2 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Call a POISON CENTER or doctor/physician if you feel unwell. Inhalation Wash off with soap and water. Get medical attention if irritation develops and persists. Skin contact Rinse with water. Get medical attention if irritation develops and persists. Eye contact In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth. Ingestion Direct contact with eyes may cause temporary irritation. Most important acute and delayed Provide general supportive measures and treat Keep victim warm. Keep victim under observation. may be delayed. Indication of immediate medical attention and special treatment needed Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. General information 5. Fire-fighting measures Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Unsuitable extinguishing media Contents under pressure. Pressurized container may explode when exposed to heat or flame. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Special protective equipment and precautions for firefighters Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. Specific methods Extremely flammable aerosol. General fire hazards 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation of vapors and spray mists. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Refer to attached safety data sheets and/or instructions for use. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent product from entering drains. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. Environmental precautions 2 / 9 Material name: Gunk Glass Cleaner - Streak Free GC1 Version 02 Revision date: 08-10-2015 Issue date: 05-08-2015 SDS US Page 58 of 136 Page 58 of 136 Page 58 of 136 Page 58 of 136 ---PAGE BREAK--- 7. Handling and storage Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Avoid inhalation of vapors and spray mists. Avoid prolonged exposure. Use only outdoors or in a well-ventilated area. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. Precautions for safe handling Level 1 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Store in a well-ventilated place. Keep out of the reach of children. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Type PEL 35 mg/m3 AMMONIUM HYDROXIDE (CAS 1336-21-6) 50 ppm PEL 980 mg/m3 Isopropyl Alcohol (CAS 67-63-0) 400 ppm US. ACGIH Threshold Limit Values Value Components Type STEL 35 ppm AMMONIUM HYDROXIDE (CAS 1336-21-6) TWA 25 ppm STEL 1000 ppm Isobutane (CAS 75-28-5) STEL 400 ppm Isopropyl Alcohol (CAS 67-63-0) TWA 200 ppm US. NIOSH: Pocket Guide to Chemical Hazards Value Components Type STEL 27 mg/m3 AMMONIUM HYDROXIDE (CAS 1336-21-6) 35 ppm TWA 18 mg/m3 25 ppm TWA 1900 mg/m3 Isobutane (CAS 75-28-5) 800 ppm STEL 1225 mg/m3 Isopropyl Alcohol (CAS 67-63-0) 500 ppm TWA 980 mg/m3 400 ppm Biological limit values ACGIH Biological Exposure Indices Value Components Determinant Specimen Sampling Time 40 mg/l Acetone Urine * Isopropyl Alcohol (CAS 67-63-0) * - For sampling details, please see the source document. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Appropriate engineering controls 3 / 9 Material name: Gunk Glass Cleaner - Streak Free GC1 Version 02 Revision date: 08-10-2015 Issue date: 05-08-2015 SDS US Page 59 of 136 Page 59 of 136 Page 59 of 136 Page 59 of 136 ---PAGE BREAK--- Individual protection measures, such as personal protective equipment Chemical respirator with organic vapor cartridge and full facepiece. Eye/face protection Skin protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Hand protection Wear suitable protective clothing. Other Chemical respirator with organic vapor cartridge and full facepiece. Respiratory protection Wear appropriate thermal protective clothing, when necessary. Thermal hazards When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Clear. Liquid. Appearance Liquid. Physical state Aerosol. Form Colorless Color Ammonia Odor Odor threshold Not available. pH 10.5 - 11.5 Melting point/freezing point Not available. Initial boiling point and boiling range Not available. Flash point None Evaporation rate Not available. Not applicable. Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower Not available. Flammability limit - upper Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 0.00001 hPa estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Density 8.17 lbs/gal estimated Not explosive. Explosive properties Flame extension No Extension Flammability (flash back) No Heat of combustion (NFPA 30B) 2.09 kJ/g estimated Not oxidizing. Oxidizing properties Percent volatile 94.15 % estimated 4 / 9 Material name: Gunk Glass Cleaner - Streak Free GC1 Version 02 Revision date: 08-10-2015 Issue date: 05-08-2015 SDS US Page 60 of 136 Page 60 of 136 Page 60 of 136 Page 60 of 136 ---PAGE BREAK--- Specific gravity 0.98 - 1 VOC (Weight 5.94 % w/w 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Reactivity Material is stable under normal conditions. Chemical stability No dangerous reaction known under conditions of normal use. Possibility of hazardous reactions Contact with incompatible materials. Conditions to avoid Strong oxidizing agents. Incompatible materials No hazardous decomposition products are known. Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation Harmful if inhaled. Skin contact No adverse effects due to skin contact are expected. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Expected to be a low ingestion hazard. related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity Harmful if inhaled. Test Results Components Species AMMONIUM HYDROXIDE (CAS 1336-21-6) Oral Acute LD50 Rat 350 mg/kg Isobutane (CAS 75-28-5) Inhalation Acute LC50 Mouse 52 mg/l, 1 Hours Isopropyl Alcohol (CAS 67-63-0) Dermal Acute LD50 Rabbit 12800 mg/kg Oral LD50 Dog 4797 mg/kg Mouse 3600 mg/kg Rabbit 5.03 g/kg Rat 4.7 g/kg SODIUM NITRITE (CAS 7632-00-0) Inhalation Acute LC50 Rat 5.5 mg/l, 4 Hours Oral LD50 Mouse 175 mg/kg Rabbit 186 mg/kg * Estimates for product may be based on additional component data not shown. Rat 85 mg/kg 5 / 9 Material name: Gunk Glass Cleaner - Streak Free GC1 Version 02 Revision date: 08-10-2015 Issue date: 05-08-2015 SDS US Page 61 of 136 Page 61 of 136 Page 61 of 136 Page 61 of 136 ---PAGE BREAK--- Prolonged skin contact may cause temporary irritation. Skin corrosion/irritation Direct contact with eyes may cause temporary irritation. Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. This product is not expected to cause skin sensitization. Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. This product is not expected to cause reproductive or developmental effects. Reproductive toxicity Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Harmful to aquatic life. Ecotoxicity Components Test Results Species AMMONIUM HYDROXIDE (CAS 1336-21-6) Aquatic LC50 Fish 15 mg/l, 96 hours Western mosquitofish (Gambusia affinis) Isopropyl Alcohol (CAS 67-63-0) Aquatic LC50 Fish > 1400 mg/l, 96 hours Bluegill (Lepomis macrochirus) SODIUM NITRITE (CAS 7632-00-0) Aquatic EC50 Crustacea 16.14 - 26.61 mg/l, 48 hours Greasyback shrimp (Metapenaeus ensis) * Estimates for product may be based on additional component data not shown. LC50 Fish 0.15 - 0.25 mg/l, 96 hours Rainbow trout,donaldson trout mykiss) No data is available on the degradability of this product. Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Isobutane 2.76 Isopropyl Alcohol 0.05 No data available. Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations. Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code 6 / 9 Material name: Gunk Glass Cleaner - Streak Free GC1 Version 02 Revision date: 08-10-2015 Issue date: 05-08-2015 SDS US Page 62 of 136 Page 62 of 136 Page 62 of 136 Page 62 of 136 ---PAGE BREAK--- Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. Contaminated packaging 14. Transport information DOT Not available. UN number Consumer Commodity UN proper shipping name ORM-D Class Transport hazard class(es) - Subsidiary risk 2.1 Label(s) Not applicable. Packing group Read safety instructions, SDS and emergency procedures before handling. Special precautions for user 19, T50 Special provisions 306 Packaging exceptions 304 Packaging non bulk 314, 315 Packaging bulk IATA Not regulated as dangerous goods. IMDG UN1950 UN number AEROSOLS UN proper shipping name 2 Class Transport hazard class(es) - Subsidiary risk Not applicable. Packing group No. Marine pollutant Environmental hazards F-D, S-U EmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Not established. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code IMDG 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) SODIUM NITRITE (CAS 7632-00-0) 1.0 % One-Time Export Notification only. CERCLA Hazardous Substance List (40 CFR 302.4) AMMONIUM HYDROXIDE (CAS 1336-21-6) Listed. Isobutane (CAS 75-28-5) Listed. Isopropyl Alcohol (CAS 67-63-0) Listed. SODIUM NITRITE (CAS 7632-00-0) Listed. SARA 304 Emergency release notification Not regulated. 7 / 9 Material name: Gunk Glass Cleaner - Streak Free GC1 Version 02 Revision date: 08-10-2015 Issue date: 05-08-2015 SDS US Page 63 of 136 Page 63 of 136 Page 63 of 136 Page 63 of 136 ---PAGE BREAK--- OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Hazard categories SARA 302 Extremely hazardous substance Not listed. No SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Chemical name CAS number % by wt. Isopropyl Alcohol 67-63-0 1 - < 3 AMMONIUM HYDROXIDE 1336-21-6 < 1 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Isobutane (CAS 75-28-5) Not regulated. Safe Drinking Water Act (SDWA) US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. Isobutane (CAS 75-28-5) Isopropyl Alcohol (CAS 67-63-0) US. Massachusetts RTK - Substance List AMMONIUM HYDROXIDE (CAS 1336-21-6) Isobutane (CAS 75-28-5) Isopropyl Alcohol (CAS 67-63-0) SODIUM NITRITE (CAS 7632-00-0) US. New Jersey Worker and Community Right-to-Know Act AMMONIUM HYDROXIDE (CAS 1336-21-6) Isobutane (CAS 75-28-5) Isopropyl Alcohol (CAS 67-63-0) SODIUM NITRITE (CAS 7632-00-0) US. Worker and Community Right-to-Know Law AMMONIUM HYDROXIDE (CAS 1336-21-6) Isobutane (CAS 75-28-5) Isopropyl Alcohol (CAS 67-63-0) SODIUM NITRITE (CAS 7632-00-0) US. Rhode Island RTK AMMONIUM HYDROXIDE (CAS 1336-21-6) Isobutane (CAS 75-28-5) Isopropyl Alcohol (CAS 67-63-0) SODIUM NITRITE (CAS 7632-00-0) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Yes Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) 8 / 9 Material name: Gunk Glass Cleaner - Streak Free GC1 Version 02 Revision date: 08-10-2015 Issue date: 05-08-2015 SDS US Page 64 of 136 Page 64 of 136 Page 64 of 136 Page 64 of 136 ---PAGE BREAK--- Country(s) or region Inventory name On inventory (yes/no)* Yes China Inventory of Existing Chemical Substances in China (IECSC) No Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 05-08-2015 Issue date 08-10-2015 Revision date Version # 02 Health: 2 Flammability: 4 Physical hazard: 0 HMIS® ratings Health: 2 Flammability: 4 Instability: 0 NFPA ratings NFPA ratings 0 2 4 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Disclaimer Physical & Chemical Properties: Multiple Properties Physical and chemical properties: Odor Stability and reactivity: Possibility of hazardous reactions Transport Information: Material Transportation Information GHS: Classification Revision Information 9 / 9 Material name: Gunk Glass Cleaner - Streak Free GC1 Version 02 Revision date: 08-10-2015 Issue date: 05-08-2015 SDS US Page 65 of 136 Page 65 of 136 Page 65 of 136 Page 65 of 136 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Krud Kutter, Inc. Page 1 of 6 Prepared to U.S. OSHA, CMA, ANSI, Canadian WHMIS Standards, Australian WorkSafe, Japanese Industrial Standard JIS Z 7250:2000, and European Directives 1. PRODUCT IDENTIFICATION TRADE NAME (AS LABELED): KRUD KUTTER® Driveway Cleaner & Degreaser SYNONYMS: Not Applicable CHEMICAL SHIPPING NAME/CLASS: NON-REGULATED MATERIAL U.N. NUMBER: NA MANUFACTURER'S NAME: Krud Kutter,Inc.(Formerly Supreme Chemicals of Georgia, Inc.) ADDRESS: 1535 Oak Industrial Lane, Suite B, Cumming, GA 30041 USA EMERGENCY PHONE: (800) 424-9300 (CHEMTREC - US) (703) 527-3887 (Outside USA) BUSINESS PHONE: (800) 466-7126 DATE OF PREPARATION: December 11, 2013 DATE OF REVISION: December 11, 2013 2. HAZARD IDENTIFICATION EMERGENCY OVERVIEW: Warning! Product Description: This product is a clear liquid with a mild odor. Health Hazards: May cause eye and/or skin irritation. The product is expected to be a low inhalation hazard. Flammability Hazards: Non-Flammable Reactivity Hazards: This product is not reactive. Environmental Hazards: Release of this product is not expected to cause significant adverse effects to the aquatic environment. Emergency Recommendations: Emergency responders must have personal protective equipment and fire protection appropriate for the situation to which they are responding. EU LABELING AND CLASSIFICATION: This product meets the definition of a hazardous substance or preparation according to EU Regulations (EC) No 1272/2008. INDEX NUMBER: EC# 229-912-9Annex I – Index# 014-010-00-8 GHS CLASSIFICATIONS: Skin Corrosive Category 2 SIGNAL WORD : Warning! HAZARD STATEMENT: H315 Causes skin irritation PREVENTION STATEMENT : P264 Wash hands thoroughly after handling P271 Use in well ventilated areas P280 Wear protective gloves/protective clothing/eye protection/ face protection HEALTH HAZARD FLAMMABILITY HAZARD REACTIVITY PROTECTIVE EQUIPMENT 1 EYES RESPIRATORY HANDS BODY (BLUE) (RED) For Routine Industrial Use and Handling Applications SEE SECTION 8 HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (YELLOW) 0 0 SEE SECTION 8 Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard HEALTH FLAMMABILITY REACTIVITY OTHER 1 0 0 Page 66 of 136 Page 66 of 136 Page 66 of 136 Page 66 of 136 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Krud Kutter, Inc. Page 2 of 6 RESPONSE STATEMENT: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 IF IN EYES : Rinse cautionously with water for several minutes P333 + P313 IF skin irritation or rash occurs : Get medical advice/attention HEALTH EFFECTS OR RISKS FROM EXPOSURE: ACUTE: INHALATION: Mist or vapor not expected to cause irritation to the respiratory tract. SKIN: Prolonged contact may cause skin irritation. Exposure can cause redness, itching and inflammation. EYES: Contact causes eye irritation. Exposure may cause tearing, redness and discomfort. INGESTION: Not expected to be an ingestion hazard for intended use. Exposure may cause nausea, vomiting, diarrhea and other systemic effects. CHRONIC: None known 3. COMPOSITION AND INFORMATION ON INGREDIENTS Hazardous Ingredients: WT% CAS# EINECS # Hazard Classification Risk Phrases Sodium Metasilicate Pentahydrate 6834-92-0 229-912-9 Corrosive R34 Alcohol Ethoxylate Proprietary Proprietary [Xi] Irritant R36/38 Balance of other ingredients is less than 1% in concentration (or 0.1% for carcinogens, reproductive toxins, or respiratory sensitizers). None NOTE: ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-2004 format. This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR, EU Directives and the Japanese Industrial Standard JIS Z 7250: 2000. 4. FIRST-AID MEASURES SKIN EXPOSURE: If this product contaminates the skin, wash with soap and water. Remove exposed or contaminated clothing, taking care not to contaminate eyes. The contaminated individual should seek medical attention if any adverse effect occurs. EYE EXPOSURE: If this product enter the eyes, open contaminated individual's eyes while under gently running water. Use sufficient force to open eyelids. Remove contact lenses if worn. Have contaminated individual "roll" eyes. Minimum flushing is for 15 minutes. Contaminated individual must seek medical attention if irritation develops or persists or if visual changes occur. INHALATION: If vapors/mists generated by this product are inhaled, or individual has difficulty breathing remove contaminated individual to fresh air. If necessary, use artificial respiration to support vital functions. SEEK IMMEDIATE MEDICAL ATTENTION. INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. DO NOT induce vomiting; if vomiting occurs spontaneously, keep head below hips to prevent aspiration of liquid into lungs. Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or unable to swallow. SEEK IMMEDIATE MEDICAL ATTENTION. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Individuals with pre-existing skin may be more susceptible to effects of this material. RECOMMENDATIONS TO PHYSICIANS: Treat and eliminate overexposure. 5. FIRE-FIGHTING MEASURES FLASH POINT: Not Applicable AUTOIGNITION TEMPERATURE: Not Applicable FLAMMABLE LIMITS (in air by volume, Lower NA Upper NA FIRE EXTINGUISHING MATERIALS: Use fire extinguishing methods listed below: Water Spray: Yes Carbon Dioxide: Yes Foam: Yes Dry Chemical: Yes Halon: Yes Other: Any Class Page 67 of 136 Page 67 of 136 Page 67 of 136 Page 67 of 136 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Krud Kutter, Inc. Page 3 of 6 UNUSUAL FIRE AND EXPLOSION HAZARDS: None known Explosion Sensitivity to Mechanical Impact: No Explosion Sensitivity to Static Discharge: No SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment. Isolate materials not yet involved in the fire and protect personnel. Move containers from fire area if this can be done without risk; otherwise, cool with carefully applied water spray. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas. 6. ACCIDENTAL RELEASE MEASURES SPILL AND LEAK RESPONSE: Evacuate unprotected personnel from the area. Maintain adequate ventilation. Follow personal protective equipment recommendations found in section 8. Contain and recover if possible. Cover or absorb spilled liquid with sand, earth or other inert material. Clean up spill immediately and place in appropriate containers. U.S. Regulations (CERCLA) requires reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802. Dispose of in accordance with U.S. Federal, State, and local hazardous waste disposal regulations and those of Canada and its Provinces, those of Australia, Japan and EU Member States (see Section 13, Disposal Considerations). 7. HANDLING and STORAGE WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash thoroughly after handling this product. Do not eat, drink, smoke, or apply cosmetics while handling this product. Avoid breathing vapors/mists/dusts generated by this product. Use in a well-ventilated location. Remove contaminated clothing immediately. STORAGE AND HANDLING PRACTICES: Protect against physical damage. Store in a cool, dry well-ventilated location. Keep containers closed. Keep out of the reach of children. Observe all warnings and precautions listed for the product. 8. EXPOSURE CONTROLS - PERSONAL PROTECTION Chemical Name CAS# ACGIH TLV OSHA TWA Sodium Metasilicate Pentahydrate 6834-92-0 Not Listed Not Listed Alcohol Ethoxylate Proprietary Not Listed Not Listed VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained below the limits provided below. Use a chemical fume hood or local exhaust ventilation, and process enclosure if necessary, to control airborne dust. Ensure eyewash/safety shower stations are available near areas where this product is used. The following information on appropriate Personal Protective Equipment is provided to assist employers in complying with OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132) or equivalent standard of Canada, or standards of EU member states (including EN 149 for respiratory PPE, and EN 166 for face/eye protection), and those of Japan. Please reference applicable regulations and standards for relevant details. RESPIRATORY PROTECTION: Maintain airborne contaminant concentrations below guidelines listed above, if applicable. If necessary, use only respiratory protection authorized in the U.S. Federal OSHA Respiratory Protection Standard (29 CFR 1910.134), equivalent U.S. State standards, Canadian CSA Standard Z94.4-93, the European Standard EN149, or EU member states. EYE PROTECTION: Use chemical safety goggles and/or a full face shield where dusting or splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area. If necessary, refer to U.S. OSHA 29 CFR 1910.133, Canadian Standards, and the European Standard EN166, Australian Standards, or relevant Japanese Standards. HAND PROTECTION: Use chemically-resistant gloves when handling this product. If necessary, refer to U.S. OSHA 29 CFR 1910.138, the European Standard DIN EN 374, the appropriate Standards of Canada, Australian Standards, or relevant Japanese Standards. BODY PROTECTION: Use body protection appropriate for task (e.g. lab coat, overalls). If necessary, refer to appropriate Standards of Canada, or appropriate Standards of the EU, Australian Standards, or relevant Japanese Standards. If a Page 68 of 136 Page 68 of 136 Page 68 of 136 Page 68 of 136 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Krud Kutter, Inc. Page 4 of 6 hazard of injury to the feet exists due to falling objects, rolling objects, where objects may pierce the soles of the feet or where employee’s feet may be exposed to electrical hazards, use foot protection, as described in U.S. OSHA 29 CFR 1910.136. 9. PHYSICAL and CHEMICAL PROPERTIES VAPOR DENSITY: >1 EVAPORATION RATE (n-BuAc=1): <1 % VOLATILE: 1% MELTING/FREEZING POINT: 0°C (32°F) SOLUBILITY IN WATER: Complete BOILING POINT: 100°C (212°F) VAPOR PRESSURE: 17 mm Hg @ 20°C (68°F) pH: <12 ODOR: Mild Odor SPECIFIC GRAVITY: 1.0 APPEARANCE and COLOR: This product is a clear liquid with a mild odor. 10. STABILITY and REACTIVITY STABILITY: Stable under conditions of normal storage and use. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition produces carbon oxides, silicon oxides and sodium oxides. MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Strong oxidizing agents, strong acids. POSSIBILITY OF HAZARDOUS REACTIONS: Will not occur. CONDITIONS TO AVOID: Incompatible materials. 11. TOXICOLOGICAL INFORMATION TOXICITY DATA: No Data Available for this product. CARCINOGENS None of the components of this product are listed as a carcinogen or suspected carcinogen or is considered a reproductive hazard. /ON 12. ECOLOGICAL INFORMATION ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION. ENVIRONMENTAL STABILITY: No data are available on the adverse effects of this material on the environment. This product is biodegradable. None of the ingredients in this mixture are classified as a Marine Pollutant. CHEMICAL EFFECT ON PLANTS, ANIMALS AND AQUATIC LIFE: This product is non-toxic and biodegradable. 13. DISPOSAL CONSIDERATIONS PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate U.S. Federal, State, and local regulations, those of Canada, Australia, EU Member States and Japan. 14. TRANSPORTATION INFORMATION US DOT, IATA, IMO, ADR: U.S. DEPARTMENT OF TRANSPORTATION (DOT) SHIPPING REGULATIONS: This product is classified (per 49 CFR 172.101) by the U.S. Department of Transportation, as follows. PROPER SHIPPING NAME: NON-REGULATED MATERIAL HAZARD CLASS NUMBER and DESCRIPTION: NA UN IDENTIFICATION NUMBER: NA PACKING GROUP: NA DOT LABEL(S) REQUIRED: NA Page 69 of 136 Page 69 of 136 Page 69 of 136 Page 69 of 136 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Krud Kutter, Inc. Page 5 of 6 NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER: NA RQ QUANTITY: NA MARINE POLLUTANT: The components of this product are not designated by the Department of Transportation to be Marine Pollutants (49 CFR 172.101, Appendix INTERNATIONAL AIR TRANSPORT ASSOCIATION SHIPPING INFORMATION (IATA): This product is not considered as dangerous goods. INTERNATIONAL MARITIME ORGANIZATION SHIPPING INFORMATION (IMO): This product is notconsidered as dangerous goods. EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD (ADR): This product is not considered by the United Nations Economic Commission for Europe to be dangerous goods. 15. REGULATORY INFORMATION UNITED STATES REGULATIONS: U.S. SARA REPORTING REQUIREMENTS: The components of this product are not subject to the reporting requirements of Sections 302, 304, and 313 of Title III of the Superfund Amendments and Reauthorization Act. Section 313 Toxic Release Inventory (40 CFR 372): None U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for the components of this product. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lbs (4,540 kg) therefore applies, per 40 CFR 370.20. U.S. CERCLA REPORTABLE QUANTITY (RQ): None U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory or are exempted form listing. OTHER U.S. FEDERAL REGULATIONS: None STATE REGULATIONS: STATE RIGHT TO KNOW LISTS: None CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): Ingredients within this product are not on the Proposition 65 Lists. CANADIAN REGULATIONS: CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are on the DSL Inventory, or are exempted from listing. OTHER CANADIAN REGULATIONS: Not applicable. CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: CANADIAN WHMIS CLASSIFICATION and SYMBOLS: Class E Corrosive EUROPEAN ECONOMIC COMMUNITY INFORMATION: EU LABELING AND CLASSIFICATION: This product meets the definition of the following hazard class as defined by the European Economic Community Guidelines. EU CLASSIFICATION: Corrosive EU RISK PHRASES: R34: Causes burns; R36/38: Irritating to eyes and skin. EU SAFETY PHRASES: S20/21: When using do not eat, drink or smoke; S24/25: Avoid contact with skin and eyes; S36/37: Wear suitable protective clothing and gloves; S39: Wear suitable eye/face protection. AUSTRALIAN INFORMATION FOR PRODUCT: The components of this product are not listed on the International Chemical Inventory list. Page 70 of 136 Page 70 of 136 Page 70 of 136 Page 70 of 136 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Krud Kutter, Inc. Page 6 of 6 JAPANESE INFORMATION FOR PRODUCT: JAPANESE MINISTER OF INTERNATIONAL TRADE AND INDUSTRY (MITI) STATUS: The components of this product are not listed as Class I Specified Chemical Substances, Class II Specified Chemical Substances, or Designated Chemical Substances by the Japanese MITI. JAPANESE ENCS INVENTORY: The components of this product are on the ENCS Inventory as indicated in the section on International Chemical Inventories, below. POISONOUS AND DELETERIOUS SUBSTANCES CONTROL LAW: No component of this product is a listed Specified Poisonous Substance under the Poisonous and Deleterious Substances Control Law. INTERNATIONAL CHEMICAL INVENTORIES: Listing of the components on individual country Chemical Inventories is as follows: Asia-Pac: Not Listed Australian Inventory of Chemical Substances (AICS): Listed Korean Existing Chemicals List (ECL): Listed Japanese Existing National Inventory of Chemical Substances (ENCS): Listed Philippines Inventory if Chemicals and Chemical Substances (PICCS): Listed Swiss Giftliste List of Toxic Substances: Listed U.S. TSCA: Listed 16. OTHER INFORMATION PREPARED BY: Paul Eigbrett – (GHS MSDS Compliance PLUS) DATE OF PRINTING: December 11, 2013 The information contained herein is believed to be accurate but is not warranted to be so. Data and calculations are based on information furnished by the manufacturer of the product and manufacturers of the components of the product. Users are advised to confirm in advance of the need that information is current, applicable and suited to the circumstances of use. Krud Kutter, Inc. assumes no responsibility for injury to vendee or third party person proximately caused by the material if reasonable safety procedures are no adhered to as stipulated in the data sheet. Furthermore, Krud Kutter, Inc. assumes no responsibility for injury caused by abnormal use of this material even if reasonable safety procedures are followed. END OF MSDS SHEET Page 71 of 136 Page 71 of 136 Page 71 of 136 Page 71 of 136 ---PAGE BREAK--- Lemon Scent Professional Lysol Brand II Disinfectant Deodorizing Cleaner Hard Surface Disinfectant. Professional use SAFETY DATA SHEET Product name Distributed by Product use 1. Product and company identification : : : D0060203 v3.0 : SDS # EPA ID No. 777-82-675 Formulation : 1201-147 (374055 v2.0) UPC Code / Sizes : 36241 76334 01 (128 fl. oz.) : Lemon Scent Professional Lysol Brand II Disinfectant Deodorizing Cleaner : Website: http://www.rbnainfo.com Emergency telephone number (Medical) Emergency telephone number (Transport) : 1-[PHONE REDACTED] 1-[PHONE REDACTED] (U.S. & Canada) CHEMTREC Outside U.S. and Canada (North America), call Chemtrec:[PHONE REDACTED] : This SDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is greater potential for large-scale or prolonged exposure, in accordance with the requirements of USDOL Occupational Safety and Health Administration. This SDS is not applicable for consumer use of our products. For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulations, and shown in Section 15 of this SDS. Reckitt Benckiser LLC. Morris Corporate Center IV 399 Interpace Parkway (P.O. Box 225) Parsippany, New Jersey 07054-0225 +1 [PHONE REDACTED] Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 2. Hazards identification Classification of the substance or mixture SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A : Signal word : Warning Hazard statements : Causes serious eye irritation. Hazard pictograms : GHS label elements General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Precautionary statements 1/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 72 of 136 Page 72 of 136 Page 72 of 136 Page 72 of 136 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 2. Hazards identification Supplemental label elements : None known. Hazards not otherwise classified : None known. Prevention : Wear eye or face protection. Wash hands thoroughly after handling. Response : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Not applicable. Disposal : Not applicable. 3. Composition/information on ingredients Mixture : Substance/mixture Alcohols, C12-15, ethoxylated 5 - 10 68131-39-5 2-(2-butoxyethoxy)ethanol 2.5 - 5 112-34-5 1,2,3-Propanetricarboxylic acid, 2-hydroxy-, sodium salt, hydrate (1:3:2) < 2.5 6132-04-3 Quaternary ammonium compounds, chlorides 0.1 - 1 68424-85-1 Ingredient name CAS number % There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Any concentration shown as a range is to protect confidentiality or is due to batch variation. 4. First aid measures Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures 2/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 73 of 136 Page 73 of 136 Page 73 of 136 Page 73 of 136 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : In case of inhalation of decomposition products in a fire, may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Most important acute and delayed Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Irritating to mouth, throat and stomach. : Ingestion Skin contact : No known significant effects or critical hazards. Causes serious eye irritation. : Eye contact Over-exposure Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : Adverse may include the following: pain or irritation watering redness Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides metal oxide/oxides In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : 3/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 74 of 136 Page 74 of 136 Page 74 of 136 Page 74 of 136 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". 7. Handling and storage Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : Protective measures Put on appropriate personal protective equipment (see Section Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in the original container or an approved alternative made from a compatible material, kept closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling 8. Exposure controls/personal protection Control Occupational exposure limits 4/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 75 of 136 Page 75 of 136 Page 75 of 136 Page 75 of 136 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 8. Exposure controls/personal protection 2-(2-butoxyethoxy)ethanol ACGIH TLV (United States, 6/2013). TWA: 10 ppm 8 hours. Form: Inhalable fraction and vapor Ingredient name Exposure limits Hand protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. 9. Physical and chemical properties Physical state Melting point Liquid. [Clear.] Not available. Citrus Lemon-like. Odor pH Green-Yellow Color 10.7 to 11.8 [Conc. w/w): 100%] Not available. Odor threshold : : : : : : Appearance Boiling point : Not available. 5/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 76 of 136 Page 76 of 136 Page 76 of 136 Page 76 of 136 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 9. Physical and chemical properties Vapor pressure Relative density Vapor density Solubility 1.008 to 1.018 Not available. Not available. Easily soluble in the following materials: cold water and hot water. Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Closed cup: >93.3°C (>199.9°F) Not available. Viscosity Not available. Partition coefficient: n- octanol/water : : : : : : : : : Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Decomposition temperature : Not available. 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. 11. Toxicological information Acute toxicity Product/ingredient name Result Species Dose Exposure Conclusion/Summary : Not classified Harmful. *Information is based on toxicity test result of a similar product. Irritation/Corrosion Information on toxicological effects Quaternary ammonium compounds, benzyl- chlorides LD50 Oral Rat 344 mg/kg - 2-(2-butoxyethoxy)ethanol LD50 Dermal Rabbit 2700 mg/kg - LD50 Oral Rat 4500 mg/kg - *Lemon Scent Professional Lysol Brand II Disinfectant Deodorizing Cleaner LD50 Dermal Rabbit >2000 mg/kg - LD50 Oral Rabbit >5000 mg/kg - 6/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 77 of 136 Page 77 of 136 Page 77 of 136 Page 77 of 136 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 11. Toxicological information Quaternary ammonium compounds, benzyl- chlorides Skin - Severe irritant Rabbit - 25 milligrams - 2-(2-butoxyethoxy)ethanol Eyes - Moderate irritant Rabbit - 24 hours 20 milligrams - Eyes - Severe irritant Rabbit - 20 milligrams - *Lemon Scent Professional Lysol Brand II Disinfectant Deodorizing Cleaner Eyes - Cornea opacity Rat 1 - - Skin - Erythema/Eschar Rat 0 - 24 hours Product/ingredient name Result Score Exposure Observation Conclusion/Summary Skin : Non-irritant to skin. *Information is based on toxicity test result of a similar product. Eyes : Irritating to eyes. *Information is based on toxicity test result of a similar product. Species Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Sensitization *Lemon Scent Professional Lysol Brand II Disinfectant Deodorizing Cleaner skin In vitro Not sensitizing Product/ingredient name Route of exposure Species Result Conclusion/Summary Skin : Non-sensitizer to skin. *Information is based on toxicity test result of a similar product. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Not available. Not available. Aspiration hazard Not available. Information on the likely routes of exposure Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Causes serious eye irritation. : Eye contact : Not available. Potential acute health effects 7/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 78 of 136 Page 78 of 136 Page 78 of 136 Page 78 of 136 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 11. Toxicological information Not available. Irritating to mouth, throat and stomach. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : Adverse may include the following: pain or irritation watering redness Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 90000 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. 12. Ecological information Toxicity 8/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 79 of 136 Page 79 of 136 Page 79 of 136 Page 79 of 136 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 12. Ecological information Quaternary ammonium compounds, benzyl- chlorides Acute EC50 0.016 mg/l Daphnia 48 hours Acute LC50 64 ppb Fresh water Fish - mykiss 96 hours 2-(2-butoxyethoxy)ethanol Acute LC50 1300000 µg/l Fresh water Fish - Lepomis macrochirus 96 hours Product/ingredient name Species Result Exposure LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name 2-(2-butoxyethoxy)ethanol 1 - low Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Not available. 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. : Disposal methods 14. Transport information Not a DOT controlled material (United States). Not a TDG-controlled material. This preparation is not classified as dangerous according to international transport regulations (ADR/RID, IMDG or ICAO/IATA). 15. Regulatory information U.S. Federal regulations TSCA 4(a) proposed test rules: Quaternary ammonium compounds, benzyl- chlorides Clean Water Act (CWA) 311: sodium hydroxide; ammonia, : TSCA 8(a) PAIR: decanal; nonanal; octanal; α-hexylcinnamaldehyde; 2-methylundecanal TSCA 8(a) CDR Exempt/Partial exemption: Not determined Commerce control list precursor: 2,2',2''-nitrilotriethanol United States inventory (TSCA 8b): All components are listed or exempted. 9/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 80 of 136 Page 80 of 136 Page 80 of 136 Page 80 of 136 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 15. Regulatory information WARNING Signal word: : Label elements Clean Air Act Section 112 Hazardous Air Pollutants (HAPs) : Listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Not listed The following components are listed: TRIETHANOLAMINE Massachusetts : SARA 313 Product name CAS number % SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. 2-(2-butoxyethoxy)ethanol 112-34-5 5 2-(2-butoxyethoxy)ethanol 112-34-5 5 Form R - Reporting requirements Supplier notification New York : None of the components are listed. New Jersey : The following components are listed: GLYCOL ETHERS; TRIETHANOLAMINE; ETHANOL, 2,2',2"-NITRILOTRIS-; ETHYL ALCOHOL; ALCOHOL : The following components are listed: GLYCOL ETHERS; ETHANOL, NITRILOTRIS-; DENATURED ALCOHOL State regulations SARA 302/304 SARA 304 RQ : 200000000 lbs / 90800000 kg [23678995.4 gal / 89634748.3 L] Ammonia < 0.01 Yes. 500 - 100 - Composition/information on ingredients Name % EHS (lbs) (lbs) (gallons) (gallons) SARA 302 TPQ SARA 304 RQ SARA 311/312 Classification : Immediate (acute) health hazard 2-(2-butoxyethoxy)ethanol 2.5 - 5 Yes. No. No. Yes. No. Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients 10/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 81 of 136 Page 81 of 136 Page 81 of 136 Page 81 of 136 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 15. Regulatory information Hazard statements Causes substantial but temporary eye injury Keep out of reach of children. Do not get in eyes, on skin, or on clothing. Use safety eyewear designed to protect against splash of liquids. After handling, always wash hands thoroughly with soap and water. Remove contaminated clothing and wash it before reuse. Precautionary measures : : 16. Other information Hazardous Material Information System 1 0 0 0 0 1 National Fire Protection Association Health Special Instability/Reactivity Flammability Health Flammability Physical hazards Date of issue Date of previous issue : : : : Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. 01/04/2015. 15/04/2011. Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Personal protection A Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 11/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 82 of 136 Page 82 of 136 Page 82 of 136 Page 82 of 136 ---PAGE BREAK--- D0060203 v3.0 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM 16. Other information Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Version : Indicates information that has changed from previously issued version. 3 Prepared by : Reckitt Benckiser LLC. Product Safety Department 1 Philips Parkway Montvale, New Jersey 07646-1810 USA. FAX: [PHONE REDACTED] Revision comments : Update as per US GHS. RB is a member of the CSPA Product Care Product Stewardship Program. 12/12 01/04/2015. Date of issue : SDS # FF374055 (D0060203) : Code # D0060203 v3.0 : Page 83 of 136 Page 83 of 136 Page 83 of 136 Page 83 of 136 ---PAGE BREAK--- Page 84 of 136 Page 84 of 136 Page 84 of 136 Page 84 of 136 ---PAGE BREAK--- Page 85 of 136 Page 85 of 136 Page 85 of 136 Page 85 of 136 ---PAGE BREAK--- Page 86 of 136 Page 86 of 136 Page 86 of 136 Page 86 of 136 ---PAGE BREAK--- Page 87 of 136 Page 87 of 136 Page 87 of 136 Page 87 of 136 ---PAGE BREAK--- Page 88 of 136 Page 88 of 136 Page 88 of 136 Page 88 of 136 ---PAGE BREAK--- Revision Date: 28-Jul-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: LOTIONIZED LIQUID HAND CLEANER Product Number: 3003 , 3006 Recommended Use: Hand cleaner Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification Not Classified Not dangerous according to the Globally Harmonized System (GHS) GHS Label Elements Signal Word: No signal word Hazard Statements: No hazard statements Precautionary Statements: Prevention: Not Applicable Response: -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Not Applicable Disposal: Not Applicable Hazards Not Otherwise Classified: Not Applicable Other Information: • May be harmful if swallowed. • May cause eye irritation. 5.07657% of the mixture consists of ingredient(s) of unknown toxicity. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 60-100 cocamide DIPA 68855-69-6 1-5 sodium lauryl sulfate 151-21-3 1-5 Page 1 / 5 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. Symbols: No symbols Page 89 of 136 Page 89 of 136 Page 89 of 136 Page 89 of 136 ---PAGE BREAK--- 3003 - LOTIONIZED LIQUID HAND CLEANER Revision Date: 28-Jul-2015 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Product does not support combustion, Use extinguishing agent suitable for type of surrounding fire Specific Hazards Arising from the Chemical: Dried product is capable of burning. Combustion products are toxic. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Cool fire-exposed containers with water spray. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 7. HANDLING AND STORAGE Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Storage Conditions: Keep containers closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep from freezing. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: None established. Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Personal Protective Equipment Eye/Face Protection: Not required with expected use. Skin and Body Protection: Not required with expected use. Respiratory Protection: Page 2 / 5 Not required with expected use. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. Page 90 of 136 Page 90 of 136 Page 90 of 136 Page 90 of 136 ---PAGE BREAK--- 3003 - LOTIONIZED LIQUID HAND CLEANER Revision Date: 28-Jul-2015 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatible Materials: Strong oxidizing agents. Strong acids. Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Pain and redness. -Skin Contact: No known hazard in contact with skin -Inhalation: No known effect. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 42706 mg/kg ATEmix (dermal): 19231 mg/kg ATEmix (inhalation-dust/mist): 49.7 mg/l Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available sodium lauryl sulfate 151-21-3 = 1288 mg/kg ( Rat ) = 580 mg/kg ( Rabbit ) > 3900 mg/m3 ( Rat ) 1 h Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Liquid Color: Pink Odor: Floral fragrance pH: 7.0-8.0 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 100 °C / 212 °F Flash Point: > 100 °C / > 212 °F ASTM D56 Evaporation Rate: < 1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 1.01 Solubility(ies): Soluble in water Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 3 / 5 Decomposition Temperature: No information available. Viscosity: No information available. Page 91 of 136 Page 91 of 136 Page 91 of 136 Page 91 of 136 ---PAGE BREAK--- 3003 - LOTIONIZED LIQUID HAND CLEANER Revision Date: 28-Jul-2015 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Microorganisms Crustacea sodium lauryl sulfate 151-21-3 53: 72 h Desmodesmus subspicatus mg/L EC50 30 - 100: 96 h Desmodesmus subspicatus mg/L EC50 117: 96 h Pseudokirchneriella subcapitata mg/L EC50 3.59 - 15.6: 96 h Pseudokirchneriella subcapitata mg/L EC50 static 8 - 12.5: 96 h Pimephales promelas mg/L LC50 static 15 - 18.9: 96 h Pimephales promelas mg/L LC50 static 22.1 - 22.8: 96 h Pimephales promelas mg/L LC50 static 4.3 - 8.5: 96 h mykiss mg/L LC50 static 4.62: 96 h mykiss mg/L LC50 flow-through 4.2: 96 h mykiss mg/L LC50 7.97: 96 h Brachydanio rerio mg/L LC50 flow-through 9.9 - 20.1: 96 h Brachydanio rerio mg/L LC50 semi-static 4.06 - 5.75: 96 h Lepomis macrochirus mg/L LC50 static 4.2 - 4.8: 96 h Lepomis macrochirus mg/L LC50 flow-through 4.5: 96 h Lepomis macrochirus mg/L LC50 5.8 - 7.5: 96 h Pimephales promelas mg/L LC50 static 10.2 - 22.5: 96 h Pimephales promelas mg/L LC50 semi-static 6.2 - 9.6: 96 h Pimephales promelas mg/L LC50 13.5 - 18.3: 96 h Poecilia reticulata mg/L LC50 semi-static 10.8 - 16.6: 96 h Poecilia reticulata mg/L LC50 static 1.31: 96 h Cyprinus carpio mg/L LC50 semi-static Not Available 1.8: 48 h Daphnia magna mg/L EC50 Persistence and Degradability: No information available. Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT: Not Regulated Proper Shipping Name: Non Hazardous Product Special Provisions: Shipping descriptions may vary based on mode of transport, quantities, package size, and/or origin and destination. Check with a trained hazardous materials transportation expert for information specific to your situation. IMDG: Not Regulated Proper Shipping Name: Page 4 / 5 Non Hazardous Product 15. REGULATORY INFORMATION Page 92 of 136 Page 92 of 136 Page 92 of 136 Page 92 of 136 ---PAGE BREAK--- 3003 - LOTIONIZED LIQUID HAND CLEANER Revision Date: 28-Jul-2015 TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product does not contain listed substances above the "de minimus" level SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: No Reactive Hazard: No California Proposition 65 This product is not subject to warning requirements under California Proposition 65. 16. OTHER INFORMATION Revision Date: 28-Jul-2015 Reasons for Revision: Section 14 and 15 Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 1 Flammability: 0 Instability: 0 Special: N/A HMIS Page 5 / 5 Health Hazards: 1 Flammability: 0 Physical Hazards: 0 Page 93 of 136 Page 93 of 136 Page 93 of 136 Page 93 of 136 ---PAGE BREAK--- Version: 2.0 Effective Date: Apr-16-2015 Previous Date: Apr-10-2015 SAFETY DATA SHEET Potassium Hydrogen Phthalate Solutions 1. Identification Product identifier Potassium Hydrogen Phthalate Solutions Other means of identification None. Product application This SDS provides health and safety information for any (unacidified) KHP component of the following vials or kits. GE Analytical Instruments part number Product name STD 62025, STD 68110, STD 68210, STD 68225, STD 68250, STD 68310, STD 68350, STD68410, STD68450, STD68520, STD 77250, STD 90056 , 91200, STD 91300, STD 91400, STD 91500, STD 91600, STD 93100 - GE Analytical Instruments kit number STD 68020, 77000, 77014, 77200 , 90000, 90001, 90002, 90003, 90004, 90005, 90014, 90016, 90017, 90018, 90019, 90020, 90021, 90023, 90025, 90026, 90028, 90031, 90036, 96000, 99001 Recommended use Calibration Standard Recommended restrictions None known. GE Analytical Instruments Inc 6060 Spine Road Boulder, CO 80301 T [PHONE REDACTED] Emergency telephone 1-[PHONE REDACTED] INFOTRAC (North America) Outside of N.A., call collect: 1-[PHONE REDACTED] GE (800) 877-1940 Company/undertaking identification 2. Hazard(s) identification Not classified. Physical hazards Not classified. Health hazards Not classified. OSHA defined hazards Label elements None. Hazard symbol Signal word None. Hazard statement The mixture does not meet the criteria for classification. Precautionary statement Prevention Observe good industrial hygiene practices. Response Wash hands after handling. Storage Store away from incompatible materials. Disposal Dispose of waste and residues in accordance with local authority requirements. Page: 1 / 6 Page 94 of 136 Page 94 of 136 Page 94 of 136 Page 94 of 136 ---PAGE BREAK--- Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number % Chemical name Common name and synonyms 7732-18-5 Water > 95.5 877-24-7 Potassium hydrogen phthalate < 4.5 Composition comments Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this SDS for our assessment of the potential hazards of this formulation. 4. First-aid measures Inhalation No treatment required. Skin contact Wash off with soap and water. Eye contact Flush eyes with water as a precaution. Ingestion Do not give anything to eat or drink. Most important acute and delayed None known. 5. Fire-fighting measures Suitable extinguishing media This product does not represent a fire hazard since it contains a high amount of water. Unsuitable extinguishing media None known. Specific hazards arising from the chemical None known. Special protective equipment and precautions for firefighters No special protective equipment required. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures See Section 8 of the SDS for Personal Protective Equipment. Methods and materials for containment and cleaning up Spills of the product are very slippery. Contain and recover by physical means. Remove small spills with plenty of water. Environmental precautions No special environmental precautions required. 7. Handling and storage Precautions for safe handling Handle in accordance with good industrial hygiene and safety procedures. Conditions for safe storage, including any incompatibilities Reasonable and safe chemical storage. 8. Exposure controls/personal protection Occupational exposure limits No exposure limits noted for ingredient(s). Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering controls Adequate ventilation. Individual protection measures, such as personal protective equipment Eye/face protection Safety goggles. Skin protection Hand protection None required. Other No special protective equipment required. Respiratory protection Not required. Thermal hazards Not applicable. Page: 2 / 6 Version number: 2.0 Material name: Potassium Hydrogen Phthalate Solutions Page 95 of 136 Page 95 of 136 Page 95 of 136 Page 95 of 136 ---PAGE BREAK--- 9. Physical and chemical properties Appearance Color Colorless Physical state Liquid Odor None Odor threshold None pH (concentrated product) 6.5 Melting point/freezing point 32 °F (0 Initial boiling point and boiling range 212 °F (100 Flash point > 212 °F 100 Pensky Martens (CC) Evaporation rate 1 (Water = 1) Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Not available. Flammability limit - upper Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 18 mm Hg at 21°C Vapor density 1 (Air = 1) Relative density 1 Solubility(ies) Solubility (water) 100 % Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Specific gravity 1 @ 4°C VOC (Weight None 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid None known. Incompatible materials None known. Hazardous decomposition products None known. 11. Toxicological information Information on likely routes of exposure Inhalation None known. Skin contact None known. Eye contact None known. Ingestion None known. related to the physical, chemical and toxicological characteristics Not available. Page: 3 / 6 Version number: 2.0 Material name: Potassium Hydrogen Phthalate Solutions Page 96 of 136 Page 96 of 136 Page 96 of 136 Page 96 of 136 ---PAGE BREAK--- Information on toxicological effects Acute toxicity Not classified. Test Results Product Species Potassium Hydrogen Phthalate Solutions (CAS Mixture) LD50 Rat Oral Acute > 5000 mg/kg, (Calculated according to GHS additivity formula) Skin corrosion/irritation Not classified. Serious eye damage/eye irritation Not classified. Respiratory or skin sensitization Respiratory sensitization Not classified. Skin sensitization Not classified. Germ cell mutagenicity Not classified. Carcinogenicity Not classified. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity Not classified. Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not classified. 12. Ecological information Ecotoxicity No ecotoxicity data noted for the ingredient(s). Bioaccumulative potential Not available. Mobility in soil Not available. Other adverse effects Not available. Persistence and degradability No data available 13. Disposal considerations Disposal instructions Dispose of contents/container in accordance with local/regional/national/international regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner. Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. 15. Regulatory information US federal regulations All components of this product are included on or are in compliance with the U.S. TSCA regulations. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. Page: 4 / 6 Version number: 2.0 Material name: Potassium Hydrogen Phthalate Solutions Page 97 of 136 Page 97 of 136 Page 97 of 136 Page 97 of 136 ---PAGE BREAK--- CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. Inventory status Country(s) or region Inventory name On inventory (yes/no)* Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). US state regulations US - Massachusetts RTK - Substance List Not regulated. US - RTK - Hazardous Substances Not regulated. US - Rhode Island RTK Not regulated. US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. New Jersey Worker and Community Right-to-Know Act Not listed. US. Worker and Community Right-to-Know Law Not listed. US. California Proposition 65 US - California Proposition 65 - CRT: Listed date/Carcinogenic substance No ingredient listed. US - California Proposition 65 - CRT: Listed date/Developmental toxin No ingredient listed. US - California Proposition 65 - CRT: Listed date/Female reproductive toxin No ingredient listed. US - California Proposition 65 - CRT: Listed date/Male reproductive toxin No ingredient listed. Page: 5 / 6 Version number: 2.0 Material name: Potassium Hydrogen Phthalate Solutions Page 98 of 136 Page 98 of 136 Page 98 of 136 Page 98 of 136 ---PAGE BREAK--- 16. Other information, including date of preparation or last revision Issue date Mar-18-2015 Revision date Apr-16-2015 Version # 2.0 List of abbreviations CAS: Chemical Abstract Service Registration Number NFPA: National Fire Protection Association ACGIH: American Conference of Governmental Industrial Hygienists TWA: Time Weighted Average STEL: Short Term Exposure Limit LD50: Lethal Dose, 50% LC50: Lethal Concentration, 50% EC50: Effect Concentration, 50% NOEL: No Observed Effect Level COD: Chemical Oxygen Demand BOD: Biochemical Oxygen Demand TOC: Total Organic Carbon TLV: Threshold Limit Value IATA: International Air Transport Association IMDG: International Maritime Dangerous Goods Code References: No data available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Prepared by This SDS has been prepared by GE Water & Process Technologies Regulatory Department (1-[PHONE REDACTED]). Page: 6 / 6 Version number: 2.0 Material name: Potassium Hydrogen Phthalate Solutions Page 99 of 136 Page 99 of 136 Page 99 of 136 Page 99 of 136 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Product Name Reagent Alcohol Cat No. : A962-4; A962-200; A962F-1GAL; A962P-4; A962RB-200; A962S-4; A9624-4LC; A995-4; A995RS-19; A995RS-50; A995RS-200; A995SS-28; A9954-LC; A995SS-50; A995SS-115; A995SS-200 Synonyms Denatured Alcohol; Denatured Ethanol (Histological/HPLC) Recommended Use Laboratory chemicals. Uses advised against No Information available Details of the supplier of the safety data sheet 2. Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label Elements Signal Word Danger Hazard Statements Highly flammable liquid and vapor Harmful if swallowed Harmful if inhaled Page 1 / 9 Aspiration Toxicity Category 1 Revision Date 27-Aug-2015 Acute oral toxicity Category 4 Emergency Telephone Number CHEMTRECÒ, Inside the USA: [PHONE REDACTED] CHEMTRECÒ, Outside the USA: 001-[PHONE REDACTED] Acute dermal toxicity Category 4 Revision Number 2 Acute Inhalation Toxicity - Vapors Category 4 Creation Date 24-Feb-2010 Specific target organ toxicity (single exposure) Category 1 Company Fisher Scientific One Reagent Lane Fair Lawn, NJ 07410 Tel: (201) 796-7100 Target Organs - Central nervous system (CNS), Optic nerve. Specific target organ toxicity - (repeated exposure) Category 1 Target Organs - Kidney, Liver, spleen, Blood. Flammable liquids Category 2 Page 100 of 136 Page 100 of 136 Page 100 of 136 Page 100 of 136 ---PAGE BREAK--- Harmful in contact with skin May cause drowsiness or dizziness May be harmful if swallowed and enters airways Causes damage to organs Causes damage to organs through prolonged or repeated exposure Precautionary Statements Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Use only outdoors or in a well-ventilated area Do not breathe dust/fume/gas/mist/vapors/spray Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep container closed Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting/equipment Use only non-sparking tools Take precautionary measures against static discharge Wear protective gloves/protective clothing/eye protection/face protection Keep cool Response IF exposed: Call a POISON CENTER or doctor/physician Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell Skin IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower Ingestion IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Do NOT induce vomiting Fire In case of fire: Use CO2, dry chemical, or foam for extinction Storage Store locked up Store in a well-ventilated place. Keep container closed Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) None identified Other hazards Poison, may be fatal or cause blindness if swallowed. Vapor harmful. Cannot be made non-poisonous. WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm. 3. Composition / information on ingredients Component CAS-No Weight % Ethyl alcohol 64-17-5 90.0 Methyl alcohol 67-56-1 5.0 Isopropyl alcohol 67-63-0 5.0 Page 2 / 9 Reagent Alcohol Revision Date 27-Aug-2015 Page 101 of 136 Page 101 of 136 Page 101 of 136 Page 101 of 136 ---PAGE BREAK--- 4. First-aid measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical attention is required. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required. Inhalation Move to fresh air. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with a respiratory medical device. Immediate medical attention is required. Ingestion Do not induce vomiting. Call a physician or Poison Control Center immediately. Most important Breathing difficulties. Inhalation of high vapor concentrations may cause like headache, dizziness, tiredness, nausea and vomiting Notes to Physician Treat 5. Fire-fighting measures Suitable Extinguishing Media CO 2, dry chemical, dry sand, alcohol-resistant foam. Use water spray to cool unopened containers. Unsuitable Extinguishing Media Water may be ineffective Flash Point 12.8 - 14.4 °C / 55 - 57.9 °F Method - No information available Autoignition Temperature 362.8 °C / 685 °F Explosion Limits Upper 19 vol % Lower 3.3 vol % Sensitivity to Mechanical Impact No information available Sensitivity to Static Discharge No information available Specific Hazards Arising from the Chemical Flammable. Risk of ignition. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Containers may explode when heated. Hazardous Combustion Products Carbon monoxide (CO) Carbon dioxide (CO2) Thermal decomposition can lead to release of irritating gases and vapors Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors. NFPA 6. Accidental release measures Personal Precautions Remove all sources of ignition. Use personal protective equipment. Take precautionary measures against static discharges. Do not get in eyes, on skin, or on clothing. Environmental Precautions Should not be released into the environment. See Section 12 for additional ecological information. Methods for Containment and Clean Up Remove all sources of ignition. Soak up with inert absorbent material. Take precautionary measures against static discharges. Keep in suitable, closed containers for disposal. Page 3 / 9 Flammability 3 Instability 0 Physical hazards N/A Reagent Alcohol Health 2 Revision Date 27-Aug-2015 Page 102 of 136 Page 102 of 136 Page 102 of 136 Page 102 of 136 ---PAGE BREAK--- 7. Handling and storage Handling Use only under a chemical fume hood. Wear personal protective equipment. Use explosion-proof equipment. Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharges. Do not breathe vapors or spray mist. Do not get in eyes, on skin, or on clothing. Storage Keep containers closed in a dry, cool and well-ventilated place. Keep away from heat and sources of ignition. Flammables area. 8. Exposure controls / personal protection Exposure Guidelines Page 4 / 9 OSHA PEL NIOSH IDLH ACGIH - American Conference of Governmental Industrial Hygienists Ethyl alcohol STEL: 1000 ppm OSHA - Occupational Safety and Health Administration (Vacated) TWA: 1000 ppm (Vacated) TWA: 1900 mg/m3 TWA: 1000 ppm TWA: 1900 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 NIOSH IDLH: The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health Methyl alcohol TWA: 200 ppm STEL: 250 ppm Skin (Vacated) TWA: 200 ppm (Vacated) TWA: 260 mg/m3 (Vacated) STEL: 250 ppm (Vacated) STEL: 325 mg/m3 Skin TWA: 200 ppm TWA: 260 mg/m3 IDLH: 6000 ppm TWA: 200 ppm TWA: 260 mg/m3 STEL: 250 ppm STEL: 325 mg/m3 Isopropyl alcohol TWA: 200 ppm STEL: 400 ppm Engineering Measures Use only under a chemical fume hood. Use explosion-proof electrical/ventilating/lighting/equipment. Ensure that eyewash stations and safety showers are close to the workstation location. (Vacated) TWA: 400 ppm (Vacated) TWA: 980 mg/m3 (Vacated) STEL: 500 ppm (Vacated) STEL: 1225 mg/m3 TWA: 400 ppm TWA: 980 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 Reagent Alcohol Personal Protective Equipment Revision Date 27-Aug-2015 Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Component Quebec Mexico OEL (TWA) Ontario TWAEV Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure. Ethyl alcohol TWA: 1000 ppm TWA: 1880 mg/m3 TWA: 1000 ppm TWA: 1900 mg/m3 STEL: 1000 ppm Methyl alcohol TWA: 200 ppm TWA: 262 mg/m3 STEL: 250 ppm STEL: 328 mg/m3 Skin TWA: 200 ppm TWA: 260 mg/m3 STEL: 250 ppm STEL: 310 mg/m3 TWA: 200 ppm STEL: 250 ppm Skin Isopropyl alcohol TWA: 400 ppm TWA: 985 mg/m3 STEL: 500 ppm STEL: 1230 mg/m3 TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 TWA: 200 ppm STEL: 400 ppm Component ACGIH TLV Legend Page 103 of 136 Page 103 of 136 Page 103 of 136 Page 103 of 136 ---PAGE BREAK--- 9. Physical and chemical properties Physical State Liquid Appearance Clear Odor aromatic Odor Threshold No information available pH No information available Melting Point/Range -114.1 °C / -173.4 °F Boiling Point/Range 78.5 °C / 173.3 °F Flash Point 12.8 - 14.4 °C / 55 - 57.9 °F Evaporation Rate No information available Flammability (solid,gas) No information available Flammability or explosive limits Upper 19 vol % Lower 3.3 vol % Vapor Pressure 44 mmHg Vapor Density 1.24 Specific Gravity 0.8 Solubility Soluble in water Partition coefficient; n-octanol/water No data available Autoignition Temperature 362.8 °C / 685 °F Decomposition Temperature No information available Viscosity No information available 10. Stability and reactivity Reactive Hazard None known, based on information available Stability Stable under normal conditions. Conditions to Avoid Incompatible products. Heat, flames and sparks. Incompatible Materials Strong oxidizing agents, Strong acids, Strong bases, Metals, Acid Acid chlorides Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2), Thermal decomposition can lead to release of irritating gases and vapors Hazardous Polymerization Hazardous polymerization does not occur. Hazardous Reactions None under normal processing. 11. Toxicological information Acute Toxicity Oral LD50 Category 4. ATE = 300 - 2000 mg/kg. Dermal LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg. Vapor LC50 Category 4. ATE = 10 - 20 mg/l. Component Information Component LD50 Oral LD50 Dermal LC50 Inhalation Ethyl alcohol LD50 = 7060 mg/kg ( Rat ) Not listed 20000 ppm/10H ( Rat ) Methyl alcohol LD50 = 6200 mg/kg ( Rat ) LD50 = 15800 mg/kg ( Rabbit ) 64000 ppm ( Rat ) 4 h 83.2 mg/L ( Rat ) 4 h Page 5 / 9 Revision Date 27-Aug-2015 Reagent Alcohol Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other are experienced. Page 104 of 136 Page 104 of 136 Page 104 of 136 Page 104 of 136 ---PAGE BREAK--- Isopropyl alcohol 5840 mg/kg ( Rat ) 13900 mg/kg ( Rat ) 12870 mg/kg ( Rabbit ) 72.6 mg/L ( Rat ) 4 h Toxicologically Synergistic Products No information available Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Irritating to eyes and skin Sensitization No information available Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS-No IARC NTP ACGIH OSHA Mexico Ethyl alcohol 64-17-5 Group 1 Known A3 X Not listed Methyl alcohol 67-56-1 Not listed Not listed Not listed Not listed Not listed Isopropyl alcohol 67-63-0 Not listed Not listed Not listed Not listed Not listed IARC: (International Agency for Research on Cancer) IARC: (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 2A - Probably Carcinogenic to Humans Group 2B - Possibly Carcinogenic to Humans Mutagenic Effects Mutagenic effects have occurred in humans. Reproductive Effects Adverse reproductive effects have occurred in humans. Developmental Effects Substances known to cause developmental toxicity in humans. Component substance is listed on California Proposition 65 as a developmental hazard. Teratogenicity Teratogenic effects have occurred in humans. STOT - single exposure Central nervous system (CNS) Optic nerve STOT - repeated exposure Kidney Liver spleen Blood Aspiration hazard No information available / effects,both acute and delayed Inhalation of high vapor concentrations may cause like headache, dizziness, tiredness, nausea and vomiting Endocrine Disruptor Information No information available Other Adverse Effects See actual entry in RTECS for complete information. 12. Ecological information Ecotoxicity . Component Freshwater Algae Freshwater Fish Microtox Water Flea Ethyl alcohol EC50 (72h) = 275 mg/l (Chlorella vulgaris) Fathead minnow (Pimephales promelas) LC50 = 14200 mg/l/96h Photobacterium phosphoreum:EC50 = 34634 mg/L/30 min Photobacterium phosphoreum:EC50 = 35470 mg/L/5 min EC50 = 9268 mg/L/48h EC50 = 10800 mg/L/24h Methyl alcohol Not listed Pimephales promelas: LC50 > 10000 mg/L 96h EC50 = 39000 mg/L 25 min EC50 = 40000 mg/L 15 min EC50 = 43000 mg/L 5 min EC50 > 10000 mg/L 24h Isopropyl alcohol EC50: > 1000 mg/L, 72h (Desmodesmus subspicatus) EC50: > 1000 mg/L, 96h (Desmodesmus subspicatus) LC50: > 1400000 µg/L, 96h (Lepomis macrochirus) LC50: = 11130 mg/L, 96h static (Pimephales promelas) LC50: = 9640 mg/L, 96h flow-through (Pimephales promelas) = 35390 mg/L EC50 Photobacterium phosphoreum 5 min 13299 mg/L EC50 = 48 h 9714 mg/L EC50 = 24 h Page 6 / 9 Reagent Alcohol Revision Date 27-Aug-2015 Page 105 of 136 Page 105 of 136 Page 105 of 136 Page 105 of 136 ---PAGE BREAK--- Persistence and Degradability No information available Bioaccumulation/ Accumulation No information available. Mobility . Component log Pow Ethyl alcohol -0.32 Methyl alcohol -0.74 Isopropyl alcohol 0.05 13. Disposal considerations Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. Component RCRA - U Series Wastes RCRA - P Series Wastes Methyl alcohol - 67-56-1 U154 - 14. Transport information DOT UN-No UN1987 Proper Shipping Name ALCOHOLS, N.O.S. Proper technical name (Ethanol, Methanol, Isopropanol) Hazard Class 3 Packing Group II TDG UN-No UN1987 Proper Shipping Name ALCOHOLS, N.O.S. Hazard Class 3 Packing Group II IATA UN-No UN1987 Proper Shipping Name ALCOHOLS, N.O.S. Hazard Class 3 Packing Group II IMDG/IMO UN-No UN1987 Proper Shipping Name ALCOHOLS, N.O.S. Hazard Class 3 Packing Group II 15. Regulatory information International Inventories Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL Ethyl alcohol X X - 200-578-6 - X X X X X Methyl alcohol X X - 200-659-6 - X X X X X Isopropyl alcohol X X - 200-661-7 - X X X X X Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Page 7 / 9 Revision Date 27-Aug-2015 Reagent Alcohol Page 106 of 136 Page 106 of 136 Page 106 of 136 Page 106 of 136 ---PAGE BREAK--- Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S. Federal Regulations TSCA 12(b) Not applicable SARA 313 Component CAS-No Weight % SARA 313 - Threshold Values % Methyl alcohol 67-56-1 5.0 1.0 Isopropyl alcohol 67-63-0 5.0 1.0 SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard Yes Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act Not applicable Clean Air Act Component HAPS Data Class 1 Ozone Depletors Class 2 Ozone Depletors Methyl alcohol X - OSHA Occupational Safety and Health Administration Not applicable CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Component Hazardous Substances RQs CERCLA EHS RQs Methyl alcohol 5000 lb - California Proposition 65 This product contains the following Proposition 65 chemicals: Ethyl alcohol is only a considered a Proposition 65 developmental hazard when it is ingested as an alcoholic beverage Component CAS-No California Prop. 65 Prop 65 NSRL Category Ethyl alcohol 64-17-5 Development (alcoholic beverages only) - Developmental Carcinogen Methyl alcohol 67-56-1 Developmental - Developmental State Right-to-Know Component Massachusetts New Jersey Illinois Rhode Island Ethyl alcohol X X X X X Methyl alcohol X X X X X Isopropyl alcohol X X X - X U.S. Department of Transportation Reportable Quantity (RQ): Y DOT Marine Pollutant N DOT Severe Marine Pollutant N U.S. Department of Homeland Security This product does not contain any DHS chemicals. Page 8 / 9 Reagent Alcohol Revision Date 27-Aug-2015 Page 107 of 136 Page 107 of 136 Page 107 of 136 Page 107 of 136 ---PAGE BREAK--- Other International Regulations Mexico - Grade Serious risk, Grade 3 Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR WHMIS Hazard Class B2 Flammable liquid D1B Toxic materials D2A Very toxic materials D2B Toxic materials 16. Other information Prepared By Regulatory Affairs Thermo Fisher Scientific Email: [EMAIL REDACTED] Creation Date 24-Feb-2010 Revision Date 27-Aug-2015 Print Date 27-Aug-2015 Revision Summary This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR 1910.1200 to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of SDS Page 9 / 9 Reagent Alcohol Revision Date 27-Aug-2015 Page 108 of 136 Page 108 of 136 Page 108 of 136 Page 108 of 136 ---PAGE BREAK--- Page 109 of 136 Page 109 of 136 Page 109 of 136 Page 109 of 136 ---PAGE BREAK--- 1. IDENTIFICATION Product Name Sodium Bicarbonate Product Code 7941 CAS No. 144-55-8 Chemical Formula NaHCO3 Recommended Use For laboratory, scientific, R&D or manufacturing use. Emergency Telephone Call CHEMTREC 1-[PHONE REDACTED] (EKI CCN 7453) 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label elements Although this product does not normally require specific hazard precautions, chemical users should always take care to minimize personnel exposure and workplace contamination. Store closed at 15-30C. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. Weight-% Sodium bicarbonate 144-55-8 >97 4. FIRST AID MEASURES Description of first aid measures General advice This chemical is not expected to produce any significant adverse health effects. Eye contact Flush eyes with plenty of water, removing contact lenses if present. Get medical attention if irritation develops. Skin contact Wash thoroughly with soap and water while removing contaminated garments. Get medical attention if irritation develops. Inhalation Remove to fresh air. Get medical attention for any breathing difficulty. Ingestion Rinse mouth and drink several glasses of water. Contact a physician or poison control center if develop. 5. FIRE-FIGHTING MEASURES Page 1 / 4 Version 1 SAFETY DATA SHEET Revision Date 04-Aug-2015 Company E K Industries, Inc. 1403 Herkimer St. Joliet, IL 60432 Tel. (800) 283-4244 Page 110 of 136 Page 110 of 136 Page 110 of 136 Page 110 of 136 ---PAGE BREAK--- Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment Specific hazards arising from the chemical No information available. Hazardous combustion productsCarbon oxides. Sodium oxides. Protective equipment and precautions for firefighters Firefighters should wear self-contained breathing apparatus with full facepiece operated in pressure-demand or other positive pressure mode. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment as required. Ensure adequate ventilation, especially in confined areas. For emergency responders Remove all sources of ignition. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. 7. HANDLING AND STORAGE Precautions for safe handling Use personal protective equipment as required Handle in accordance with good industrial hygiene and safety practice. Storage Conditions Keep containers closed in a dry, cool and well-ventilated place. Incompatible materials Acids. Strong oxidizing agents. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies Appropriate engineering controls Engineering Controls Emergency showers, eyewash stations, ventilation systems. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Solid Appearance White powder Odor odorless Odor threshold No information available Page 2 / 4 No information available 7941 - Sodium Bicarbonate pH 8.3 Revision Date 04-Aug-2015 Melting point / freezing point Page 111 of 136 Page 111 of 136 Page 111 of 136 Page 111 of 136 ---PAGE BREAK--- 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions No information available. Conditions to avoid Exposure to air or moisture over prolonged periods. Extremes of temperature and direct sunlight. Incompatible materials Acids. Strong oxidizing agents. Hazardous Decomposition Products Carbon oxides. Sodium oxide. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Component Oral LD50 Dermal LD50 Inhalation LC50 Sodium bicarbonate 144-55-8 ( >97 ) = 4220 mg/kg ( Rat ) - - No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Skin corrosion/irritation No information available. Serious eye damage/eye irritation No information available. Irritation May cause eye irritation. Inhalation of dust in high concentration may cause irritation of respiratory system. Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity This chemical does not contain any carcinogens or potential carcinogens as listed by ACGIH, OSHA, IARC or NTP . 12. ECOLOGICAL INFORMATION Ecotoxicity No information available Persistence and degradability Page 3 / 4 Evaporation rate No information available Vapor density No information available No information available Relative density No information available Revision Date 04-Aug-2015 Water solubility Soluble in water Flammability (solid, gas) No information available Solubility in other solvents No information available Partition coefficient No information available Flammability Limit in Air Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Flash point No information available Upper flammability limit: No information available 7941 - Sodium Bicarbonate Lower flammability limit: No information available Boiling point / boiling range Vapor pressure No information available Page 112 of 136 Page 112 of 136 Page 112 of 136 Page 112 of 136 ---PAGE BREAK--- No information available. Bioaccumulation No information available. 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. 14. TRANSPORT INFORMATION Note: Transportation information is provided as a general reference only and may not be applicable in all situations. This information applies to non-bulk shipments only. Per 49 CFR §173.22, it is the shipper’s responsibility to ensure that all materials are properly packaged, classified and labeled prior to shipment. DOT Not regulated IATA Not regulated 15. REGULATORY INFORMATION No information available. 16. OTHER INFORMATION Prepared By EKI Regulatory Affairs (Email: [EMAIL REDACTED]) Revision Date 04-Aug-2015 Disclaimer E K Industries, Inc. makes no representation as to the comprehensiveness or accuracy of this document. Individuals using this information, or the product to which it refers, must exercise their independent judgment in determining all appropriateness for a particular purpose. Accordingly, E K Industries, Inc. will not be responsible for damages of any kind or nature resulting from the use of this information or the corresponding product. No representations or warranties of any kind or nature, including but not limited to: express warranties, implied warranties or merchantability, or warranties of fitness for a particular purpose, are made hereunder with respect to the information set forth herein or to the product to which the information refers. End of Safety Data Sheet Page 4 / 4 7941 - Sodium Bicarbonate Revision Date 04-Aug-2015 Page 113 of 136 Page 113 of 136 Page 113 of 136 Page 113 of 136 ---PAGE BREAK--- Version: 2.1 Revision Date: 04-14-2015 SDS_US - SDS000000947 1/10 SAFETY DATA SHEET 1. Identification Product identifier: Sodium Hydroxide, Pellets Other means of identification Product No.: 3115, 3718, 3722, 3723, 3728, 5045, 5565, 7001, 7680, 7708, 7772 Recommended use and restriction on use Recommended use: Not available. Restrictions on use: Not known. Details of the supplier of the safety data sheet Manufacturer Company Name: Avantor Performance Materials, Inc. Address: 3477 Corporate Parkway, Suite 200 Center Valley, PA 18034 Telephone: Customer Service: [PHONE REDACTED] Fax: [PHONE REDACTED] Contact Person: Environmental Health & Safety E-mail: [EMAIL REDACTED] Emergency telephone number: 24 Hour Emergency: [PHONE REDACTED] Chemtrec: [PHONE REDACTED] 2. Hazard(s) identification Hazard Classification Physical Hazards Corrosive to metals Category 1 Health Hazards Skin Corrosion/Irritation Category 1 Serious Eye Damage/Eye Irritation Category 1 Unknown toxicity - Health Acute toxicity, inhalation, dust or mist 100 % Unknown toxicity - Environment Chronic hazards to the aquatic environment 100 % Hazard Symbol: Label Elements Page 114 of 136 Page 114 of 136 Page 114 of 136 Page 114 of 136 ---PAGE BREAK--- Version: 2.1 Revision Date: 04-14-2015 SDS_US - SDS000000947 2/10 Signal Word: Danger Hazard Statement: May be corrosive to metals. Causes severe skin burns and eye damage. Precautionary Statement Prevention: Do not breathe dust/fume/gas/mist/vapors/spray. Wear protective gloves/protective clothing/eye protection/face protection. Keep only in original container. Wash hands thoroughly after handling. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Absorb spillage to prevent material damage. Storage: Store locked up. Store in corrosive resistant container with a resistant inner liner. Store in a well-ventilated place. Keep container closed. Disposal: Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Other hazards which do not result in GHS classification: None. 3. Composition/information on ingredients Substances Chemical Identity Common name and synonyms CAS number Content in percent SODIUM HYDROXIDE 1310-73-2 90 - 100% * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First-aid measures General information: Get medical advice/attention if you feel unwell. Show this safety data sheet to the doctor in attendance. Ingestion: Call a physician or poison control center immediately. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Inhalation: Move to fresh air. Call a physician or poison control center immediately. Apply artificial respiration if victim is not breathing If breathing is difficult, give oxygen. Page 115 of 136 Page 115 of 136 Page 115 of 136 Page 115 of 136 ---PAGE BREAK--- Version: 2.1 Revision Date: 04-14-2015 SDS_US - SDS000000947 3/10 Skin Contact: Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician or poison control center immediately. Wash contaminated clothing before reuse. Destroy or thoroughly clean contaminated shoes. Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Call a physician or poison control center immediately. Most important acute and delayed Corrosive to skin and eyes. Indication of immediate medical attention and special treatment needed Treatment: Treat may be delayed. 5. Fire-fighting measures General Fire Hazards: Move containers from fire area if you can do so without risk. Use water spray to keep fire-exposed containers cool. Cool containers exposed to flames with water until well after the fire is out. Suitable (and unsuitable) extinguishing media Suitable extinguishing media: Use fire-extinguishing media appropriate for surrounding materials. Unsuitable extinguishing media: The product reacts with water and will generate heat. Specific hazards arising from the chemical: Fire may produce irritating, corrosive and/or toxic gases. Special protective equipment and precautions for firefighters Special fire fighting procedures: No unusual fire or explosion hazards noted. Special protective equipment for fire-fighters: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures: Keep unauthorized personnel away. Ventilate closed spaces before entering them. Use personal protective equipment. See Section 8 of the SDS for Personal Protective Equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Methods and material for containment and cleaning up: Sweep up and place in a clearly labeled container for chemical waste. Clean surface thoroughly to remove residual contamination. Neutralize spill area and washings with dilute acetic acid. Notification Procedures: Prevent entry into waterways, sewer, basements or confined areas. Stop the flow of material, if this is without risk. Inform authorities if large amounts are involved. Environmental Precautions: Do not contaminate water sources or sewer. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Page 116 of 136 Page 116 of 136 Page 116 of 136 Page 116 of 136 ---PAGE BREAK--- Version: 2.1 Revision Date: 04-14-2015 SDS_US - SDS000000947 4/10 7. Handling and storage Precautions for safe handling: Do not get in eyes, on skin, on clothing. Do not eat, drink or smoke when using the product. Do not taste or swallow. Avoid breathing dust or vapor. Use personal protective equipment as required. Wash hands thoroughly after handling. Conditions for safe storage, including any incompatibilities: Do not store in metal containers. Keep container closed. Store in a well-ventilated place. Store in a dry place. 8. Exposure controls/personal protection Control Parameters Occupational Exposure Limits Chemical Identity type Exposure Limit Values Source SODIUM HYDROXIDE Ceiling 2 mg/m3 US. ACGIH Threshold Limit Values (2011) Ceil_Time 2 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010) PEL 2 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) Ceiling 2 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) Appropriate Engineering Controls No data available. Individual protection measures, such as personal protective equipment General information: Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. An eye wash and safety shower must be available in the immediate work area. Eye/face protection: Wear safety glasses with side shields (or goggles) and a face shield. Skin Protection Hand Protection: Chemical resistant gloves Other: Wear suitable protective clothing. Respiratory Protection: In case of inadequate ventilation use suitable respirator. Air-purifying respirator with a high efficiency particulate filter. Hygiene measures: Provide eyewash station and safety shower. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing to remove contaminants. Discard contaminated footwear that cannot be cleaned. 9. Physical and chemical properties Appearance Physical state: solid Form: Pellets Color: White Odor: Odorless Page 117 of 136 Page 117 of 136 Page 117 of 136 Page 117 of 136 ---PAGE BREAK--- Version: 2.1 Revision Date: 04-14-2015 SDS_US - SDS000000947 5/10 Odor threshold: No data available. pH: 13 (0.5% aqueous solution) Melting point/freezing point: 323 °C Initial boiling point and boiling range: 1,388 °C Flash Point: not applicable Evaporation rate: No data available. Flammability (solid, gas): No data available. Upper/lower limit on flammability or explosive limits Flammability limit - upper No data available. Flammability limit - lower No data available. Explosive limit - upper No data available. Explosive limit - lower No data available. Vapor pressure: No data available. Vapor density: No data available. Relative density: 2.13 (25 Solubility(ies) Solubility in water: 1,110 g/l Solubility (other): No data available. Partition coefficient (n-octanol/water): No data available. Auto-ignition temperature: No data available. Decomposition temperature: No data available. Viscosity: No data available. Other information Molecular weight: 40 g/mol (HNaO) 10. Stability and reactivity Reactivity: Reacts violently with strong acids. Chemical Stability: Material is stable under normal conditions. Possibility of Hazardous Reactions: Hazardous polymerization does not occur. The substance is hygroscopic and will absorb water by contact with the moisture in the air. Conditions to Avoid: Avoid dust formation. Heat. Moisture. Incompatible Materials: Oxidizing agents. Acids. Flammable liquid. Contact with metals may evolve flammable hydrogen gas. Hazardous Decomposition Products: Sodium oxides 11. Toxicological information Information on likely routes of exposure Ingestion: May cause burns of the gastrointestinal tract if swallowed. Inhalation: May cause damage to mucous membranes in nose, throat, lungs and bronchial system. Skin Contact: Causes severe skin burns. Eye contact: Causes serious eye damage. Page 118 of 136 Page 118 of 136 Page 118 of 136 Page 118 of 136 ---PAGE BREAK--- Version: 2.1 Revision Date: 04-14-2015 SDS_US - SDS000000947 6/10 Information on toxicological effects Acute toxicity (list all possible routes of exposure) Oral Product: LD 50 (Rat): 130 - 340 mg/kg Dermal Product: LD 50 (Rabbit): 1,350 mg/kg Inhalation Product: No data available. Repeated dose toxicity Product: No data available. Skin Corrosion/Irritation Product: Causes severe skin burns. Serious Eye Damage/Eye Irritation Product: Causes serious eye damage. Respiratory or Skin Sensitization Product: Not a skin sensitizer. Carcinogenicity Product: This substance has no evidence of carcinogenic properties. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: No carcinogenic components identified US. National Toxicology Program (NTP) Report on Carcinogens: No carcinogenic components identified US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): No carcinogenic components identified Germ Cell Mutagenicity In vitro Product: No mutagenic components identified In vivo Product: No data available. Reproductive toxicity Product: No components toxic to reproduction Specific Target Organ Toxicity - Single Exposure Product: None known. Specific Target Organ Toxicity - Repeated Exposure Product: None known. Aspiration Hazard Product: Not classified Other effects: None known. Page 119 of 136 Page 119 of 136 Page 119 of 136 Page 119 of 136 ---PAGE BREAK--- Version: 2.1 Revision Date: 04-14-2015 SDS_US - SDS000000947 7/10 12. Ecological information Ecotoxicity: Acute hazards to the aquatic environment: Fish Product: No data available. Specified substance(s): SODIUM HYDROXIDE LC 50 (Western mosquitofish (Gambusia affinis), 96 125 mg/l Mortality Aquatic Invertebrates Product: No data available. Specified substance(s): SODIUM HYDROXIDE EC 50 (Water flea (Ceriodaphnia dubia), 48 34.59 - 47.13 mg/l Intoxication Chronic hazards to the aquatic environment: Fish Product: No data available. Aquatic Invertebrates Product: No data available. Toxicity to Aquatic Plants Product: No data available. Persistence and Degradability Biodegradation Product: Expected to be readily biodegradable. BOD/COD Ratio Product: No data available. Bioaccumulative Potential Bioconcentration Factor (BCF) Product: No data available on bioaccumulation. Partition Coefficient n-octanol / water (log Kow) Product: No data available. Mobility in Soil: The product is water soluble and may spread in water systems. Other Adverse Effects: Harmful to aquatic organisms. The product may affect the acidity (pH-factor) in water with risk of harmful effects to aquatic organisms. 13. Disposal considerations Disposal instructions: Discharge, treatment, or disposal may be subject to national, state, or local laws. Contaminated Packaging: Since emptied containers retain product residue, follow label warnings even after container is emptied. Page 120 of 136 Page 120 of 136 Page 120 of 136 Page 120 of 136 ---PAGE BREAK--- Version: 2.1 Revision Date: 04-14-2015 SDS_US - SDS000000947 8/10 14. Transport information DOT UN Number: UN 1823 UN Proper Shipping Name: Sodium hydroxide, solid Transport Hazard Class(es) Class(es): 8 Label(s): 8 Packing Group: II Marine Pollutant: Not a Marine Pollutant Special precautions for user: – IMDG UN Number: UN 1823 UN Proper Shipping Name: SODIUM HYDROXIDE, SOLID Transport Hazard Class(es) Class(es): 8 Label(s): 8 EmS No.: F-A, S-B Packing Group: II Marine Pollutant: Not a Marine Pollutant Special precautions for user: – IATA UN Number: UN 1823 Proper Shipping Name: Sodium hydroxide, solid Transport Hazard Class(es): Class(es): 8 Label(s): 8 Marine Pollutant: Not a Marine Pollutant Packing Group: II Special precautions for user: – 15. Regulatory information US Federal Regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) None present or none present in regulated quantities. CERCLA Hazardous Substance List (40 CFR 302.4): Chemical Identity Reportable quantity SODIUM HYDROXIDE 1000 lbs. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Acute (Immediate) SARA 302 Extremely Hazardous Substance None present or none present in regulated quantities. SARA 304 Emergency Release Notification Chemical Identity Reportable quantity SODIUM HYDROXIDE 1000 lbs. Page 121 of 136 Page 121 of 136 Page 121 of 136 Page 121 of 136 ---PAGE BREAK--- Version: 2.1 Revision Date: 04-14-2015 SDS_US - SDS000000947 9/10 SARA 311/312 Hazardous Chemical Chemical Identity Threshold Planning Quantity SODIUM HYDROXIDE 10000 lbs SARA 313 (TRI Reporting) None present or none present in regulated quantities. Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3) Chemical Identity Reportable quantity SODIUM HYDROXIDE Reportable quantity: 1000 lbs. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): None present or none present in regulated quantities. US State Regulations US. California Proposition 65 No ingredient regulated by CA Prop 65 present. US. New Jersey Worker and Community Right-to-Know Act Chemical Identity SODIUM HYDROXIDE US. Massachusetts RTK - Substance List Chemical Identity SODIUM HYDROXIDE US. RTK - Hazardous Substances Chemical Identity SODIUM HYDROXIDE US. Rhode Island RTK Chemical Identity SODIUM HYDROXIDE Inventory Status: Australia AICS: On or in compliance with the inventory Canada DSL Inventory List: On or in compliance with the inventory EINECS, ELINCS or NLP: On or in compliance with the inventory Japan (ENCS) List: On or in compliance with the inventory China Inv. Existing Chemical Substances: Not in compliance with the inventory. Korea Existing Chemicals Inv. (KECI): On or in compliance with the inventory Canada NDSL Inventory: Not in compliance with the inventory. Philippines PICCS: On or in compliance with the inventory US TSCA Inventory: On or in compliance with the inventory New Zealand Inventory of Chemicals: On or in compliance with the inventory Japan ISHL Listing: On or in compliance with the inventory Japan Pharmacopoeia Listing: Not in compliance with the inventory. 16.Other information, including date of preparation or last revision NFPA Hazard ID Flammability Health Reactivity Special hazard. 0 1 3 Page 122 of 136 Page 122 of 136 Page 122 of 136 Page 122 of 136 ---PAGE BREAK--- Version: 2.1 Revision Date: 04-14-2015 SDS_US - SDS000000947 10/10 Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe; RNP - Rating not possible Issue Date: 04-14-2015 Revision Date: No data available. Version 2.1 Further Information: No data available. Disclaimer: THE INFORMATION PRESENTED IN THIS MATERIAL SAFETY DATA SHEET (MSDS/SDS) WAS PREPARED BY TECHNICAL PERSONNEL BASED ON DATA THAT THEY BELIEVE IN THEIR GOOD FAITH JUDGMENT IS ACCURATE. HOWEVER, THE INFORMATION PROVIDED HEREIN IS PROVIDED “AS IS,” AND AVANTOR PERFORMANCE MATERIALS MAKES AND GIVES NO REPRESENTATIONS OR WARRANTIES WHATSOEVER, AND EXPRESSLY DISCLAIMS ALL WARRANTIES REGARDING SUCH INFORMATION AND THE PRODUCT TO WHICH IT RELATES, WHETHER EXPRESS, IMPLIED, OR STATUTORY, INCLUDING WITHOUT LIMITATION, WARRANTIES OF ACCURACY, COMPLETENESS, MERCHANTABILITY, NON- INFRINGEMENT, PERFORMANCE, SAFETY, SUITABILITY, STABILITY, AND FITNESS FOR A PARTICULAR PURPOSE, AND ANY WARRANTIES ARISING FROM COURSE OF DEALING, COURSE OF PERFORMANCE, OR USAGE OF TRADE. THIS MSDS/SDS IS INTENDED ONLY AS A GUIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE MATERIAL BY A PROPERLY TRAINED PERSON USING THIS PRODUCT, AND IS NOT INTENDED TO BE COMPREHENSIVE AS TO THE MANNER AND CONDITIONS OF USE, HANDLING, STORAGE, OR DISPOSAL OF THE PRODUCT. INDIVIDUALS RECEIVING THIS MSDS/SDS MUST ALWAYS EXERCISE THEIR OWN INDEPENDENT JUDGMENT IN DETERMINING THE APPROPRIATENESS OF SUCH ISSUES. ACCORDINGLY, AVANTOR PERFORMANCE MATERIALS ASSUMES NO LIABILITY WHATSOEVER FOR THE USE OF OR RELIANCE UPON THIS INFORMATION. NO SUGGESTIONS FOR USE ARE INTENDED AS, AND NOTHING HEREIN SHALL BE CONSTRUED AS, A RECOMMENDATION TO INFRINGE ANY EXISTING PATENTS OR TO VIOLATE ANY FEDERAL, STATE, LOCAL, OR FOREIGN LAWS. AVANTOR PERFORMANCE MATERIALS REMINDS YOU THAT IT IS YOUR LEGAL DUTY TO MAKE ALL INFORMATION IN THIS MSDS/SDS AVAILABLE TO YOUR EMPLOYEES. Page 123 of 136 Page 123 of 136 Page 123 of 136 Page 123 of 136 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Product Name Sodium Phosphate Monobasic Monohydrate (Certified ACS) Cat No. : S369-1; S369-3; S369-50; S369-250LB; S369-500 Synonyms Sodium dihydrogen phosphate monohydrate; Dihydrogen sodium phosphate monohydrate Recommended Use Laboratory chemicals. Uses advised against No Information available Details of the supplier of the safety data sheet 2. Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label Elements Signal Word Warning Hazard Statements Causes eye irritation May cause respiratory irritation Precautionary Statements Prevention Page 1 / 7 Emergency Telephone Number CHEMTRECÒ, Inside the USA: [PHONE REDACTED] CHEMTRECÒ, Outside the USA: 001-[PHONE REDACTED] Target Organs - Respiratory system. Revision Number 2 Creation Date 14-Oct-2009 Company Fisher Scientific One Reagent Lane Fair Lawn, NJ 07410 Tel: (201) 796-7100 Serious Eye Damage/Eye Irritation Category 2B Revision Date 25-Aug-2015 Specific target organ toxicity (single exposure) Category 3 Page 124 of 136 Page 124 of 136 Page 124 of 136 Page 124 of 136 ---PAGE BREAK--- Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell Storage Store in a well-ventilated place. Keep container closed Store locked up Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) None identified 3. Composition / information on ingredients Component CAS-No Weight % Phosphoric acid, monosodium salt, monohydrate 10049-21-5 >95 Sodium phosphate, monobasic 7558-80-7 - 4. First-aid measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Get medical attention if occur. Inhalation Move to fresh air. If breathing is difficult, give oxygen. Get medical attention if occur. Ingestion Do not induce vomiting. Obtain medical attention. Most important No information available. Notes to Physician Treat 5. Fire-fighting measures Suitable Extinguishing Media Substance is nonflammable; use agent most appropriate to extinguish surrounding fire. Unsuitable Extinguishing Media No information available Flash Point No information available Method - No information available Autoignition Temperature No information available Explosion Limits Upper No data available Lower No data available Sensitivity to Mechanical Impact No information available Sensitivity to Static Discharge No information available Specific Hazards Arising from the Chemical Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Hazardous Combustion Products Sodium oxides Oxides of phosphorus Page 2 / 7 Sodium Phosphate Monobasic Monohydrate (Certified ACS) Revision Date 25-Aug-2015 Page 125 of 136 Page 125 of 136 Page 125 of 136 Page 125 of 136 ---PAGE BREAK--- Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors. NFPA 6. Accidental release measures Personal Precautions Ensure adequate ventilation. Use personal protective equipment. Avoid dust formation. Environmental Precautions Should not be released into the environment. See Section 12 for additional ecological information. Methods for Containment and Clean Up Sweep up or vacuum up spillage and collect in suitable container for disposal. Avoid dust formation. 7. Handling and storage Handling Wear personal protective equipment. Ensure adequate ventilation. Avoid contact with skin and eyes. Avoid ingestion and inhalation. Avoid dust formation. Storage Keep containers closed in a dry, cool and well-ventilated place. 8. Exposure controls / personal protection Exposure Guidelines This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. 9. Physical and chemical properties Physical State Solid Appearance White Odor Odorless Odor Threshold No information available pH 4.1-4.5 @ 20°C 5% aq.solution Melting Point/Range 100 °C Boiling Point/Range No information available Flash Point No information available Evaporation Rate Not applicable Flammability (solid,gas) No information available Flammability or explosive limits Page 3 / 7 Flammability 0 Sodium Phosphate Monobasic Monohydrate (Certified ACS) Personal Protective Equipment Instability 1 Physical hazards N/A Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Revision Date 25-Aug-2015 Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure. Health 1 Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other are experienced. Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Page 126 of 136 Page 126 of 136 Page 126 of 136 Page 126 of 136 ---PAGE BREAK--- Upper No data available Lower No data available Vapor Pressure negligible Vapor Density Not applicable Specific Gravity No information available Solubility Soluble in water Partition coefficient; n-octanol/water No data available Autoignition Temperature No information available Decomposition Temperature > 100°C Viscosity Not applicable Molecular Formula H2 Na O4 P . H2 O Molecular Weight 137.99 10. Stability and reactivity Reactive Hazard None known, based on information available Stability Hygroscopic. Conditions to Avoid Incompatible products. Excess heat. Avoid dust formation. Exposure to moist air or water. Incompatible Materials Strong oxidizing agents Hazardous Decomposition Products Sodium oxides, Oxides of phosphorus Hazardous Polymerization Hazardous polymerization does not occur. Hazardous Reactions None under normal processing. 11. Toxicological information Acute Toxicity Product Information Oral LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg. Dermal LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg. Mist LC50 Based on ATE data, the classification criteria are not met. ATE > 5 mg/l. Component Information Component LD50 Oral LD50 Dermal LC50 Inhalation Sodium phosphate, monobasic LD50 = 8290 mg/kg ( Rat ) LD50 > 7940 mg/kg ( Rabbit ) Not listed Toxicologically Synergistic Products No information available Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Moderately irritating to the eyes Sensitization No information available Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS-No IARC NTP ACGIH OSHA Mexico Phosphoric acid, monosodium salt, monohydrate 10049-21-5 Not listed Not listed Not listed Not listed Not listed Sodium phosphate, monobasic 7558-80-7 Not listed Not listed Not listed Not listed Not listed Mutagenic Effects No information available Reproductive Effects No information available. Page 4 / 7 Sodium Phosphate Monobasic Monohydrate (Certified ACS) Revision Date 25-Aug-2015 Page 127 of 136 Page 127 of 136 Page 127 of 136 Page 127 of 136 ---PAGE BREAK--- Developmental Effects No information available. Teratogenicity No information available. STOT - single exposure Respiratory system STOT - repeated exposure None known Aspiration hazard No information available / effects,both acute and delayed No information available Endocrine Disruptor Information No information available Other Adverse Effects The toxicological properties have not been fully investigated. See actual entry in RTECS for complete information. 12. Ecological information Ecotoxicity No information available. Persistence and Degradability Soluble in water Persistence is unlikely based on information available. Bioaccumulation/ Accumulation No information available. Mobility Will likely be mobile in the environment due to its water solubility. 13. Disposal considerations Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. 14. Transport information DOT Not regulated TDG Not regulated IATA Not regulated IMDG/IMO Not regulated 15. Regulatory information International Inventories Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL Phosphoric acid, monosodium salt, monohydrate - - - - - X - X X - Sodium phosphate, monobasic X X - 231-449-2 - X X X X X Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Page 5 / 7 Sodium Phosphate Monobasic Monohydrate (Certified ACS) Revision Date 25-Aug-2015 Page 128 of 136 Page 128 of 136 Page 128 of 136 Page 128 of 136 ---PAGE BREAK--- Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S. Federal Regulations TSCA 12(b) Not applicable SARA 313 Not applicable SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act Not applicable Clean Air Act Not applicable OSHA Occupational Safety and Health Administration Not applicable CERCLA Not applicable California Proposition 65 This product does not contain any Proposition 65 chemicals State Right-to-Know Not applicable U.S. Department of Transportation Reportable Quantity (RQ): N DOT Marine Pollutant N DOT Severe Marine Pollutant N U.S. Department of Homeland Security This product does not contain any DHS chemicals. Component DHS Chemical Facility Anti-Terrorism Standard Sodium phosphate, monobasic 2000 lb STQ Other International Regulations Mexico - Grade No information available Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR WHMIS Hazard Class D2B Toxic materials Page 6 / 7 Sodium Phosphate Monobasic Monohydrate (Certified ACS) Revision Date 25-Aug-2015 Page 129 of 136 Page 129 of 136 Page 129 of 136 Page 129 of 136 ---PAGE BREAK--- 16. Other information Prepared By Regulatory Affairs Thermo Fisher Scientific Email: [EMAIL REDACTED] Creation Date 14-Oct-2009 Revision Date 25-Aug-2015 Print Date 25-Aug-2015 Revision Summary This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR 1910.1200 to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of SDS Page 7 / 7 Sodium Phosphate Monobasic Monohydrate (Certified ACS) Revision Date 25-Aug-2015 Page 130 of 136 Page 130 of 136 Page 130 of 136 Page 130 of 136 ---PAGE BREAK--- ISO 9001:2008 CERTIFIED 130 W. GRAND LAKE BLVD., WEST CHICAGO, IL. 50185 [PHONE REDACTED] OFFICE [PHONE REDACTED] FAX FOR CHEMICAL EMERGENCY. SPILL, LEAK, EXPOSURE, OR ACCIDENT, CALL CHEMTREC, 1-[PHONE REDACTED] Revised 8-21-14 SAFETY DATA SHEET 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: SODIUM THISOULFATE 2. COMPOSITION/INFORMATION ON INGREDIENTS CHEMICAL FORMULA: Na2S203 Cas# 7772-98-7 100% TLV: Not established by ACGIH: ACGIH (sulfur Dioxide) TWA 2 ppm (5.2 m (S)2(/m3; STEl 5 pppm (13 mg (S02)/m3) Toxicity values of the Hazardous ingredients Sodium Thiosulfate Intraperitoneal (ld50): Acute 5200 mg/kg (Mouse) 3. HAZARDS IDENTIFICATION POTENTIONAL HEALTH EFFECTS SIGNAL WORD: DANGER EYE CAN CAUSE SEVERE EYE IRRITATION. INCLUDE STINGING, TEARING, REDNESS AND SWELLIN OF THE EYES. CAN INJURE EYE TISSUE. SKIN CAN CAUSE SKIN IRRITATION. MAY INCLUDE REDNESS AND BURNING OF THE SKIN, AND OTHER SKIN DAMAGE. THE FEELING OF IRRITATION OR PAIN MAY NOT OCCUR UNTIL SEVERAL HOURS AFTER THE EXPOSURE. ADDITIONAL OF SKIN CONTACT MAY INCLUDE, HAIR LOSS, PASSAGE OF THIS MATERIAL INTO THE BODY THROUGH THE SKIN IS POSSIBLEM BUT IS UNLIKELY THAT THIS WOULD RESULT IN HARMFUL EFFECTS DURING SAFE HANDLING AND USE. SWALLOWING SWALLOWING THIS MATERIAL MAY BE HARMFUL OR FATAL. MAY INCLUDE SEERE STOMACH AND INESTINAL IRRITATION (NAUSEA, VOMITING, DIARRHEA), ABDOMINAL PAIN, AND VOMITING OF BLOOD. SWALLOWING THIS MATERIAL MAY CAYSE BURNS AND DESTROY TISSUE IN THE MOIUTH, THROAT AND DIGESTIVE TRACT. LOW BLOOD PRESSURE AND SHOCK MAY OCCUR AS A RESULT OF SEVERE TISSUE INJURY. INHALATION IT IS POSSIBLE TO BREATHE THIS MATERIAL UNDER DERTAIN CONDITIONS OF HANDLING AND USE FOR EXAMPLE (DURING HEATIN, SPRAYING OR STIRRING). BREATHING SMALL AMOUNTS OF THIS MATERIAL DURING NORMAL HANDLING IS NOT LIKELY TO CAUSE HARMFUL EFFECTS. BREATHING LARGE AMOUNTS MAY BE HARMFUL. USUALLY OCCUR AT AIR CONCENTRATIONS HIGHER THAN THE RECOMMENDED EXPOSURE LIMITS (SEE SECTION 8) OF EXPOSURE SIGNS AND OF EXPOSURE TO THIS MATERIAL THROUGH BREATHING, SWALOWING, AND OR PASSAGE OF THE MATERIAL THROUGH THE SKIN MAY INCLUDE STOMACH, OR INTENSTINAL UPSET (NAUSEA, VOMITING, DIARRHEA), IRRITATION (NOSE, THROAT, AIRWAYS) COUGH DIFFICULT BREATHING, LUNG EDEMA, (FLUID BUILD UP IN THE LUNG TISSUE) LUNG DAMAGE, DAMAGE TO THE MOUTH, THROAT AND OR AIRWAYS, SCHOCK. TARGET ORGANS N//A DEVELOPMENTAL INFORMATION THIS MATERIAL (OR A COMPONENT) HAS BEEN SHOWN TO CAUSE BIRTH DEFECTS IN LAB ANIMAL STUDIES. HARM TO THE FETUS OCCURS ONLY AT EXPOSURE LEELS THAT HARM THE PREGNANT AMIMAL. THE RELEVENACE OF THESE FINDINGS TO HUMANS IS UNCERTAIN. Page 131 of 136 Page 131 of 136 Page 131 of 136 Page 131 of 136 ---PAGE BREAK--- CANCER INFORMATION THIS MATERIAL IS NOT LISTED AS A CARCINOGEN BY THE INTERNATIONAL AGENCY FOR RESEARCH FOR CANCER, THE NATIONAL TOXICOLOGY PROGRAM FOR THE OCCUPATIONAL SAFETY AND HEALTH ADMINSTRATION OTHER HEALTH EFFECTS: NO DATA PRIMARY ROUTE OF ENTRY INHALATION, SKIN ABSORPTION, SIN CONTACT, EYE CONTACT, INGESTION 4. FIRST AID MEASURES INHALATION IF DEVELOP, MOVE INDIVIDUAL AWSAY FROM EXPOSURE AND INTO RESH AIR. IF PERSIS, SEEK MEDICAL ATTENTION. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. EEP PERSON WARM AND QUIET, SEEK IMMEDIATE MEDICAL ATTENTION. EYES IF DEVELOP, IMMEDIATELY MOVE INDIVIUAL AWAY FRM EXPOSURE AND INTO FRESH AIR. FLUSH EYS GENTLY WITH WATER FOR AT LEAST 15 MINUTES WHILE HOLDING EYELIDS APART, SEEK IMMEDIATE MEDICAL ATTENTION. SKIN IMMEDIATELY FLUSH SKIN WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMVING CONTAMINATED CLOTHING AND SHOES. SEEK MEDICAL ATTENTION. LAUNDER CLOTHING BEFORE REUSE AND DISCARD CONTAMINATED SHOES. SWALLOWING SEEK MEDICAL ATTENTION. IF INDIVIDUAL IS DROWSY OR UNCONSCIOUS DO NOT GIVE ANYTHING MY MOUTH, PLACE INDIVIUAL ON THE LEFT SIDE WITH HEAD DOWN. CONTACT A PHYSICIAN, MEDICAL FACILITYOR POSION CONTROL CENTER FOR ADVICE ABOUT WHETHER TO INDUCE VOMITING. IF POSSIBLE, DO NOT LEAVE INDIVDUAL UNATTENDED. NOTE TO PHYSICIAN PRE EXISTING DISORDERS OF THE FOLLOWINF ORFANS (OR ORGAN SYSTEMS) MAY BE AGGRAVATED BY EXPOSURE TO THIS MATERIAL. SKIN, LUNG (FOR I.E. ASTHMA LIKE CONDITIONS) 5. FIRE FIGHTING MEASURES FLASH LIMIT: N/A EXPLOSIVE LIMIT: N/A AUTOIGNITION TEMPERATURE; NO DATA HAZARDOUS PRODUCTS OF COMBUSTION: MAY FORM CARBON DIOXIDE AND CARBON MONOXIDE, VARIOUS HYDROCARBONS. FIRE & EXPLOSION HAZARDS NO SPECIAL FIRE HAZARDS ARE KNOWN TO BE ASSOCIATED WITH THIS PRODUCT EXTINGUISHING MEDIA USE AN EXTUINGUISHING MEDIA APPOPRIATE FOR SURROUNDING FIRE FIRE FIGHTING INSTRUCTIONS USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS AND STRUCTURES UNTIL FIRE IS OUT IF IT CAN BE DONE WITH MINIMAL RISK. AVOID BRATHING BURNING LIQUID WITH WATER USED FOR COOLING PURPOSES. WEAR FULL FIRE FIGHTING TURN OUT EAR (FULL BUNKER GEAR) , AND RESPIRATORY PROTECTION (SCBA). NFPA RATING HEALTH = 3 FLAMMABILITY = 1 REACTIVITY=0 6. ACCIDENTAL RELEASE MEASURES SMALL SPILL ABSORB LIQUID ON VERMICULITE, FLOOR ABSORBENT OR OTHER ABSORBENT MATERIAL. SCOOP OR SCRAPE UP. PUT IN CONTAINER FOR RECOVERY OR DISPOSAL. LARGE SPILL PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AEA OF SPILL UNTIL CEAN UP HAS BEEN COMPLETED. STOP SPILL AT SOURCE, DIKE AREA OF SPILL TO PREVENT SPREADING, PUMP LIQUID TO SALVAGE TANK. REMAINING LIQUID MAY BE TAKEN UP ON SAND, CLAY, EARTH, FLOOR ABSORBENT OR OTHER ABSORBENT MATERIAL AND SHOVELED INTO CONTAINERS. 7. HANDLING AND STORAGE HANDLING CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONAINERS RETAIN PRODUCT RESIDUES, (VAPOR, LIQUID AND OR SOLID) ALL HAZARD PRECAUTIONS GIVEN IN THE DATA SHEET MUST BE OBSERVED. EMERGENCY EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE Page 132 of 136 Page 132 of 136 Page 132 of 136 Page 132 of 136 ---PAGE BREAK--- IMMEDIATE VICINITY OF OF POTENTIAL EXPOSURE. USE GOOD PERSONAL HYGIENE PRACTIVES. WASH HANDS BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. REMOVE SOILED CLOTHING AND WASH BEFORE REUSE. SHOWER AFTER WORK USING PLENTY OF SOAP AND WATER. STORAGE PRODUCT SOLUTIONS ARE CORROSIVE TO MANY COMMONLY USED MATERIALS OF CONSTRUCTION SUCH AS STEEL, GALVANIZED IRON, ALUMINUM, IN AND ZINC. THESE SOLUTIONS CAN BE STORED AND HANDLED IN BAKED PHENOLIC-LINED STEEL, POLYETHYLENE, STAINLESS STEEL OR REINFORECED EPOXY PLASTIC EQUIPMENT. STORE IN CLOSED CONTAINERS IN A DRY WELL VENTILATED AREA, 8. EXPOSURE CONTROLS/PERSONAL PROTECTION EYE PROTECTION CHEMICAL SPLASH GOGGLES IN COMPLIANCE WITH OSHA REGULATIONS ARE ADVISED, HOWEVER, OSHA REGULATIONS ALSO PERMIT OTHER TYPE SAFETY GLASSES. CONSULT YOUR SAFETY REPRESENTATIVE SKIN PROTECTION WEAR IMERVIOUS GLOVE (CONSULT YOUR SAFETY EQUIPMENT SUPPLIER) TO PREVENT SKIN CONTACT, WEAR IMPERVIOUS CLOTHING AND BOOTS RESPIRATORY PROTECTION IF WORKPLACE EXPOSURE LIMIT(S) OF PRODUCT OR ANY COMPONENT IS EXCEEDED 9SEE EXPOSURE GUIDELINES ) A NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPERT ENVIRONMENTAL CONTRO OSHA REGULATIONS ALSO PERMIT OTHER NIOSH/MSHA RESPIRATORS (NEGATIVE PRESSURE TYPE) UNDER SPECIFIED CONDITIONS (SEE YOUR INDUSTRIAL HYGIENIEST). ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUC EXPOSURE. ENGINEERING CONTROLS PROVIDE SUFFICIENT MECHANICAL (GENERAL AND OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW LEVEL OF OVER EXPOSURE (FROM KNOWN, SUSPECTED OR APARENT ADVERSE EFFECTS) EXPOSURE GUIDELINES ORGANIC SALT – NO EXPOSURE LIMITS ESTABLISHED. SODIUM HYDROXIDE (1310-73-2) OSHA PEL – 2.00 MG/M3 –TWA OSHA VPEL 2.00 MG/M3 – CEILING ACGIH TLV 2.00 MG/M3 - CEILING 9. PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT: (FOR PRODUCT) 219.0 F (103.8 C) @ 760 MMHG VAPOR PRESSURE: (FOR PRODUCT ) < 17.500 MM/HG @ 68.00 F SPECIFIC VAPOR DENSITY: .6000 @AIR = 1 SPECIFIC GRAVITY: 1.260 @ 77.00 F LIQUID DENSITY 10.480 LBS/GAL @ 77.00 F 1.260 KG/L @ 25.00 C PERCENT VOLATILES: >60. % EVAPORATION RATE: SLOWER THAN ETHYL ETHER APPEARANCE: CLEAR LIQUID STATE: LIQUID PHYSICAL FORM: HOMOGENEOUS SOLUTION COLOR: CLEAR PALE YELLOW ODOR: SLIGHT AMINE ODOR ph: 10.5 -12.0 @ 1% AQUEUS SOLUTION FREEZING POINT: <-8.0 F (-22.2 C) MOLECULAR WEIGHT : 380.0 10. STABILITY AND REACTIVITY HAZARDOUS POLYMERIXATION PRODUCT WILL NOT UNDERGO HAZARDOUS POLYMERIZATION Page 133 of 136 Page 133 of 136 Page 133 of 136 Page 133 of 136 ---PAGE BREAK--- HAZARDOUS DECOMPOSITION MAY FORM: CARBON OXIDES, NITROEN OXIDES, TOXIC FUME CHEMICAL STABILITY STABLE INCOMPATBILITY AVOID CONTACT WITH: REACTIVE METALS SUCH AS ALUMINUM AND MANESIUM, STEEL, STRONG MINERAL ACIDS, STRONG OXIDZING AGENTS. REACTS WITH ACTIVE METALS (POTASSIUM , SODIUM, ALUMINUM ETC) TO PRODUCT FLAMMABLE HYDROGEN GAS. 11. TOXICOLOGICAL INFORMATION LD 50 AND LC 50 DATA SODIUM HYDROXIDE (CAS# 1310-73-2) ORAL LDLO (RABBIT): 500 MG/KG DERMAL LD50 (RABBIT) 1350 MG/KG INHALATION LC50: N/A ETHYLENEDIAMINEERAACETATE, SODIUM SALT (CAS#64-02-8) ORAL LD50 (MALE RATE: 3030 MG/KG DERMAL LD50 (RABBIT):>5000 MG/KG INHALATION LC50: N/A 12. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION 96 HR LC50 RAINBOW TROUT (STATIC CONDITIONS: 884 MG/L* 96 HR LC50 FATHEAD MINNOW (STATIC CONDITIONS: 707 MG/L* 48 HR LC50 CERIODAPHNIA DUBIA (STATIC CONDITIONS: 536 MG/L* 48 HR LC50 CERIODAPHNIA DBIA (STATIC CONDITIONS: 574 MG/L* *BASED ON SIMILAR FORMULATION CHEMICAL FATE INFORMATION BOD5:<2000 MG/L* COD: 329,800 MG/L* *BASED ON SIMILAR PRODUCT 13. DISPOSAL CONSIDERATIONS WASTE MANAGEMENT INFORMATION DISPOSE OF IN ACCORDANCW WITH ALL APPLICABLE LOCA, SATE AND FEDERAL REGULATINS. FOR ASISTANCE WITH YOUR WASTE MANAGEMENT NEEDS – INCLUDING DISPOSAL, RECYCLING AND WASTE STREAM REDUCTIONS, CONTACT MINERAL MASTERS [PHONE REDACTED] 14. TRANSPORT INFORMATION DOT INFORMATION – 249 CFR 172.101 D.O.T. Description: UN3267, CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S., 8, PG III CONTAINER MODE: 55 GAL DRUM/TRUCK PACKAGE NOS COMPONENT: ETHYLENEDIAMINE TETRAACETIC ACID NA SALT RQ (REPORTABLE QUANTITY ) 49 CFR 172.101: N/A OTHER TRANSPORTATION THE TRANSPORTATION INFORMATON MAY VARY WITH THE CONTAINER AND MODE OF SHIPMENT Page 134 of 136 Page 134 of 136 Page 134 of 136 Page 134 of 136 ---PAGE BREAK--- 15. REGULATORY INFORMATION US FEDERAL REGULATIONS TSCA (TOXIC SUBSTANCES CONTROL ACT ) STATUS TSCA (UNITED SATES) THE INTENTIONAL INGREDIENTS OF THIS PRODUCT ARE LISTED. CERCLA RQ – 40 CFR 302.4 COMPONENT RQ (LBS) SODIUM HYDROXIDE 1000 CERCLA RQ – 40 CFR 355 APPENDIX NONE Sara 311/312 Hazard Class – 40 CFR 370.2 Immediate Delayed ( ) Fire Reactive Sudden Release of Pressure Sara 313 Components – 40 CFR 372.65 None OSHA Process Safety Mgmt. – 29 CFR 1910 None Listed EPA Accidental Release Prevention 40 CFR 68 None Listed International Regulations – Inventory Status AICS (Australia) The intentional ingredients of this product are listed. DSL (Canada) The Intentional ingredients of this product are listed ECL (South Korea) The Intentional ingredients of this product are listed EINECS (Europe) The Intentional ingredients of this product are listed ENC (Japan) The Intentional ingredients of this product are listed IECSC (China) The Intentional ingredients of this product are listed PICCS (Philippines) The Intentional ingredients of this product are listed State and Local Regulations California Prop. 65 None NEW JERSEY RTK LABEL INFORMATION SODIUM HYDROXIDE 1310-73-2 RTK LABEL INFORMATION SODIUM HYDROXIDE (NAOH) 1310-73-2 The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirtm in advance or need that the information is current applicable and suitable to their circumstances. SECTION 16. OTHER INFORMATION IMPORTANT: The information presented herein, while not guaranteed, was prepared by competent technical personnel and it is true and accurate to the best of our knowledge. NO WARRANTY OR MERCHANTABILITY OR FITNESS FOR PURPOSE, OR OF ANY OTHER KIND, EXPRESSED OR IMPLIED, IS MADE REGARDING PERFORMANCE, STABILITY OR OTHERWISE. This information is not intended to be all inclusive as to the manner and conditions of use, handling, and storage. Other factors may involve other or additional safety or performance considerations. While or technical personnel will be happy to respond to questions, safe handling and use remains the responsibility of the customer. No suggestions for use are intended as and nothing herein shall be construed as a recommendation to infringe any existing patents or violate any federal, state, local laws, rules regulations or ordinances. Page 135 of 136 Page 135 of 136 Page 135 of 136 Page 135 of 136 ---PAGE BREAK--- There was a PDF conversion failure for - Product Name: Soy Broth CAS Number: Manufacturer: BD DIAGNOSTIC SYSTEMS SDS Date: 3/24/2014 To complete your binder, please link a different SDS for this product or print the SDS manually from http://www.msdsonline.com/Legacy/Partners/Show-Document/Default.aspx?ShowId=24aw3Js6NwA%3d and add to your binder. We are currently researching solutions to this issue. Thank you for your patience. Page 136 of 136 Page 136 of 136 Page 136 of 136 Page 136 of 136