Document douglascountywi_gov_doc_95cfda5c5d

Safety Data Sheets Gordon Highway Shop Gordon Highway Shop 11/16/2015 ---PAGE BREAK--- Safety Data Sheet Index Binder: Gordon Highway Shop - Gordon Highway Shop “Freeze Fighter” Anti-Freeze Solution J.C. Whitlam Mfg. Co. 04/22/2015 4 1136 Automatic Transmission Fluid Dexron-VI Lubrication Engineers, Inc. 05/23/2013 10 15W40 Coastal Packaging Inc 03/01/2006 18 1WVL3 - Graphite Dry Film Lubricant 1 Gal Superior Graphite 02/10/2012 20 2 Cycle Oil CHS Inc. 11/15/2013 22 AW HYDRAULIC OIL 46 MOTOR OIL, INC. 06/01/2015 29 BLASTOUT WINDSHIELD WASHER SOLVENT 67-56-1 BLASTOUT, LLC 06/11/1999 36 Castle Thrust Castle Products, Inc. 06/14/2013 38 CITRA CLEAN #443 Waterless Hand Cleaner UNKNOWN 07/30/1990 41 Diesel Fuel 64742-80-9 Total Petrochemicals & Refining USA, Inc. 07/22/2015 43 DIESEL FUEL SUPPLEMENT +CETANE BOOST Power Service Products, Inc. 05/30/2015 44 Dry Moly Lube CRC Industries, Inc. 03/09/2015 57 FVP Bar & Chain Oil Cam2 International, LLC 03/25/2011 64 Gold Band Chain And Bar Oil 64742-52-5 Quaker State Corporation 04/14/1997 74 Health Gards Metered Aerosols - 07913 Odor Neutralizer HOSPECO 05/20/2015 79 Hydraulic AW Phillips 66 Lubricants 05/08/2014 80 KRYLON Industrial QUIK-MARK Water-Based Inverted Marking Paint (Fluorescent) Pink THE SHERWIN-WILLIAMS COMPANY- KRYLON Products Group 03/13/2015 87 MAGNESIUM CHLORIDE, HEXAHYDRATE, BIO-REFINED 7791-18-6 GFS Chemicals, Inc. 06/16/2015 100 Master Brake Parts Cleaner Atlantic Pacific 01/25/2012 106 Microburst 3000 & 9000 Air Neutralizer - All Fragrances Rubbermaid Commercial Products 11/04/2013 110 MOBILGREASE XHP 462 MOLY Exxon Mobil Corporation 03/17/2015 113 POLAR WW SOLVENT 6/1GL Warren Distribution, Inc. 04/02/2015 123 Propane WestAir Gases & Equipment Inc 08/04/2015 130 Product Name CAS Number Manufacturer Version Date Page Page 2 of 156 Page 2 of 156 Page 2 of 156 Page 2 of 156 ---PAGE BREAK--- PX Super “99” Isopropyl Alcohol 67-63-0 Splash Products, Inc. 06/03/2010 135 Shell Motor Oil 30 Shell Oil Company 138 Unleaded Gasoline Total Petrochemicals & Refining USA, Inc. 07/24/2015 140 Xtreme Gleme Claire Manufacturing Company 03/20/2001 152 Product Name CAS Number Manufacturer Version Date Page Page 3 of 156 Page 3 of 156 Page 3 of 156 Page 3 of 156 ---PAGE BREAK--- J.C. Whitlam Freeze Fighter Anti-Freeze Solution Page 1 of 6 Safety Data Sheet SDS ID: Stock Code AF Revision date: April 22, 2015 Section 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product name: “Freeze Fighter” Anti-Freeze Solution Synonyms: None Chemical family: Propylene Glycol mixture Producer: J.C. Whitlam Manufacturing Company 200 West Walnut Street P.O. Box 380 Wadsworth, Ohio 44282-0380 www.jcwhitlam.com Telephone: [PHONE REDACTED] Available during normal business hours Emergency: CHEMTEL [PHONE REDACTED] Available 24 hours Section 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Appearance: blue liquid. May cause adverse reproductive effects based upon animal studies. May cause eye and skin irritation. May cause respiratory tract irritation and digestive tract irritation GHS Classification in accordance with 29 CFR 1910.1200 Reproductive Toxicity (Category 1B), H360 Signal Word and Hazard statements DANGER — May damage fertility or the unborn child DANGER Precautionary Statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P263 Avoid contact during pregnancy/while nursing. P280 Use personal protective equipment as required, (see section 8) P308+313 If exposed or concerned, get medical advice/attention. P405 Store locked up. Inhalation: P260 Do not breathe mist. May cause respiratory tract irritation. Ingestion: P270 Do not eat, drink or smoke when using this product. May cause irritation of the digestive tract. Skin contact: P264 Wash hands thoroughly after handling. May cause irritation from prolonged or repeated contact. Eye contact: May cause eye irritation. Carcinogenic: No ingredients listed by the IARC, NTP, OSHA, or the ACHIH. Page 4 of 156 Page 4 of 156 Page 4 of 156 Page 4 of 156 ---PAGE BREAK--- J.C. Whitlam Freeze Fighter Anti-Freeze Solution Page 2 of 6 Section 3. COMPOSITION / INFORMATION ON INGREDIENTS Material information: Name CAS No. Weight % Sodium tetraborate decahydrate 1303-96-4 <5 Non-hazardous ingredients Not Applicable >95 *Note: The above weight percentages are represented in ranges as estimates. Due to variation among production batches, component percentages may vary. Section 4. FIRST AID MEASURES General Advice: Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of the dangerous area. Inhalation: Move exposed persons to fresh air. If the person is not breathing or breathing is irregular, provide artificial respiration or oxygen by trained personnel. Consult a physician. Skin contact: Remove contaminated clothing and shoes. Wash affected skin with soap and water. Get medical attention if occur. Wash contaminated clothing before reuse. Ingestion: Do not induce vomiting. Never give anything by mouth to an unconscious person. If conscious and alert, rinse the mouth with water. Call a physician or poison control center immediately. Eye contact: Check for and remove any contact lenses, if easy to do so. If eye irritation persists, consult physician after flushing eyes with tepid water for 15 minutes. Section 5. FIREFIGHTING MEASURES Suitable extinguishing media: Use alcohol foam, carbon dioxide, or dry chemical. Specific hazards: Combustion products may include borane/boron oxides. Sodium oxides. Advice for Firefighters: Full protective equipment including self-contained breathing apparatus should be used. Do not allow run-off from fire-fighting to enter drains or water courses. NFPA rating: HMIS rating: Health: 0 1* Flammability: 0 0 Instability/reactivity: 0 0 Other: N/A B (PPE) *Chronic health hazard: Fertility or Unborn child Hazardous FP - Below 73 F Stable N/A FIRE SPECIAL H E A L T H R E A C T I V I T Y 3 2 0 Hazardous FP - above 200 F Stable N/A FIRE SPECIAL H E A L T H R E A C T I V I T Y 0 0 0 Page 5 of 156 Page 5 of 156 Page 5 of 156 Page 5 of 156 ---PAGE BREAK--- J.C. Whitlam Freeze Fighter Anti-Freeze Solution Page 3 of 6 Section 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Large Spill: Avoid mist formation. Immediately contact emergency personnel. Evacuate any potentially affected area and isolate personnel from entry. Personnel must have appropriate training, per Occupational Safety and Health Administration (OSHA) 29 CFR 1910.120. Do not touch damaged containers or spilled material unless wearing appropriate protective equipment (Section Methods for Containment and Clean up Shut off source if possible and if safe. Prevent entry into waterways and sewers. Dyke and/or absorb with vermiculite or other suitable material. Keep absorbed material in closed containers for disposal. Advise applicable authorities if material has entered sewers or water courses. Section 7. HANDLING AND STORAGE Handling: Use with adequate ventilation. Keep containers closed when not in use. Always open containers slowly to allow any excess pressure to vent. Avoid breathing vapors. Avoid contact with eyes, skin, or clothing. Wash thoroughly with soap and water after handling. Launder soiled clothing thoroughly before re-use. Storage: Keep all containers closed when not in use. Do not store with incompatible materials. See Section 10, Stability and Reactivity. Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational Exposure Limits: Name CAS No. ACGIH® TLV® Exposure Limits: Federal OSHA PELs OSHA PELs 1989 C Sodium tetraborate decahydrate 1303-96-4 2 A,D Not Estab. 10 A All exposure limits listed are 8-hour time weighted average (TWA) — except where noted otherwise. A Time Weighted Average (TWA) is an average exposure over the course of an 8-hour work shift. Airborne aerosol (mist) as measured in milligrams (mist) per cubic meter of air. B A Short Term Exposure Limit TWA over the course of 15 minutes. PEL — Permissible Exposure Limit is the maximum 8-hour TWA concentration of a chemical that a worker may be exposed to under Occupational Safety and Health Administration (OSHA) regulations. C Federal OSHA 1989 PELs were vacated but are in use and enforced by many state OSHA plans. D Inhalable aerosol (mist). Engineering measures: Local exhaust ventilation is preferable. General ventilation is acceptable if exposure to materials in this section is maintained below applicable exposure limits. PERSONAL PROTECTIVE EQUIPMENT Respiratory protection: When engineering controls are not sufficient to reduce exposure to levels below applicable exposure limits, seek professional advice prior to respirator selection and use. Wear a properly fitted NIOSH/ MSHA-approved respirator. Skin and body protection: Wear impervious clothing and nitrile rubber gloves to prevent contact. Use the manufacturer’s degradation and permeation data for protective material selection. Eye protection: Wear safety spectacles with unperforated sideshields, or goggles. Page 6 of 156 Page 6 of 156 Page 6 of 156 Page 6 of 156 ---PAGE BREAK--- J.C. Whitlam Freeze Fighter Anti-Freeze Solution Page 4 of 6 Hygiene measures: Avoid repeated or prolonged skin exposure. Wash hands before eating, drinking, smoking, or using toilet facilities. remove contaminated clothing and launder before reuse. Other precautions: Not applicable Section 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Pink liquid Physical state (solid/liquid/gas): Liquid Substance type (pure/mixture): Mixture Color: Pink Odor: Sweet odor Molecular weight: Not available pH: Not Applicable Boiling point/range Not Available Melting point/range: Not Available Decomposition temperature: Not Available Specific gravity: 1.04 Vapor density: (AIR = 1) 2.62 Vapor pressure: 0.22 mm Hg at 68°F Evaporation rate (Butyl acetate= <0.1 Flash point, method used: 211°F; 99.4°C Water solubility: 100% VOC Content: Not Available Auto-ignition temperature: Not Available Flammable limits in air — lower 2.6 Flammable limits in air — upper 12.6 Section 10. STABILITY AND REACTIVITY Reactivity: No data available Stability: Stable under recommended storage conditions. This product is hygroscopic. Possibly hazardous reactions: No data available Conditions to avoid: Never use welding, thermal cutting, or spark- producing equipment near the product because the product, or its residue, can ignite or explode. Incompatible Materials: Oxidizing agents, reducing agents, acid chlorides, acid and chloroformates. Hazardous decomposition products: In a fire with limited oxygen: propionaldehyde, carbon monoxide. Polymerization: Will not occur. Section 11. TOXICOLOGICAL INFORMATION Acute toxicity: Product information: Name CAS No. Inhalation: Dermal: Oral: Sodium tetraborate decahydrate 1303-96-4 No data available. LD50 (Rabbit) 10,000 mg/kg Acute LD50 (Rat):4,500- 5,000 mg/kg Propylene glycol 57-55-6 No data available. LD50 (Rabbit) 20,800 mg/kg No data available. LC50 — the concentration of the chemical in air that kills 50% of the test animals in a given time (usually four hours). Page 7 of 156 Page 7 of 156 Page 7 of 156 Page 7 of 156 ---PAGE BREAK--- J.C. Whitlam Freeze Fighter Anti-Freeze Solution Page 5 of 6 Carcinogenicity: The IARC, NTP, and OSHA: No component of this product, present at levels greater than or equal to 0.1% is identified as probable, possible, or confirmed human carcinogen. Reproductive toxicity: VZ2275000. Sodium tetraborate decahydrate is identified as having fetotoxicity in animals. It is a presumed human reproductive toxicant. Animal feeding studies in rat, mouse, and dog, at high doses, have demonstrated effects on fertility and testes. Studies with the chemically related boric acid in the rat, mouse, and rabbit, at high doses demonstrate developmental effects on the fetus. Sensitization: Not known to cause sensitization in humans. Section 12. ECOLOGICAL INFORMATION Ecotoxicity effects: Sodium tetraborate decahydrate LC50 Carassius auratus (goldfish) 72-hour 178 mg/l. EC50 Daphnia magna (water flea) 48-hour 1,085-1,402 mg/l. Propylene glycol EC50 Water flea 48-hour >10,000 mg/l. Persistence: No data available. Degradability: No data available. Section 13. DISPOSAL CONSIDERATIONS Cleanup considerations: This product is not a hazardous waste as defined under U.S. E.P.A. RCRA 40 CFR 261. Disposal of this material must be done in accordance with federal, state, provincial, and/or local regulations. P501 Dispose of contents/ container to an approved waste disposal plant. The material destined for disposal must be characterized properly and may differ from the product described in this SDS if mixed with other wastes. Section 14. TRANSPORT INFORMATION Please refer to DOT regulation 49 CFR 172.101: Transport information: This material is not regulated under DOT when transported via U.S. commerce routes: and IATA, and IMO via international routes Hazardous Materials Description: (DOT and IATA): UN/identification no.: Not Applicable Proper shipping name: Not Applicable Hazard class: Not Applicable Packing group: Not Applicable DOT reportable quantity (lbs.): Not Applicable Page 8 of 156 Page 8 of 156 Page 8 of 156 Page 8 of 156 ---PAGE BREAK--- J.C. Whitlam Freeze Fighter Anti-Freeze Solution Page 6 of 6 Section 15. REGULATORY INFORMATION U.S. federal regulatory information: U.S. RCRA (40 CFR 261) This product is not a hazardous waste as defined under RCRA 40 CFR 261. State and community right-to-know regulations: The following component(s) of this material are identified on the regulatory lists below: U.S. TSCA Chemical inventory Section 8(b) OSHA — This product is determined to be hazardous as defined in the OSHA Hazard Communications Standard (29 CFR 1910.1200) . CERCLA Sections 102a/103 (40 FR 302.4): No ingredients are listed. Some Components of this product are listed in the following sections of SARA: SARA Title III Section 302 — N/A SARA Title III Section 304 — N/A SARA Title III Section 313 — N/A SARA Title III Sections 311/312 Hazardous Categories (40 CFR 370.21) Acute health hazard: No Chronic health hazard: Yes Fire hazard: No Reactive Hazard: No Pressure Hazard: No California Proposition 65 Components This product does not contain any chemicals known to the State of California to cause cancer, birth defects, or any other reproductive harm. WHMIS (Canada) Class D-2A; D-2B: Material causing other toxic effects. CAS# 1303-96-4 is listed on Canada’s DSL List. CAS# 1303-96-4 is listed on Canada’s Ingredient Disclosure List. NOTE: User must consult with applicable state and local agencies for special specifics, determinations or compliance obligations regarding this product. Section 16. OTHER INFORMATION Standards and Certification Listings: The information and recommendations contained herein are based upon tests, data, and information resources believed to be reliable. However, the J.C. Whitlam Manufacturing Company, Inc., and its related operations or divisions (Whitlam) do not guarantee the accuracy or completeness, nor shall any of this information constitute a warranty, whether expressed or implied, as to the safety of goods, the merchantability of the goods or the fitness of the goods for a particular purpose. Adjustment to conform to actual conditions of usage may be required. Whitlam assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of this data. No warranty against infringement of any patent, copyright or trademark is made or implied. Page 9 of 156 Page 9 of 156 Page 9 of 156 Page 9 of 156 ---PAGE BREAK--- Issuing Date 04-24-2012 Revision Date 05-23-2013 Revision Number 5 SDS: 1136 1136 AUTOMATIC TRANSMISSION FLUID DEXRON®-VI Page 1 / 8 SAFETY DATA SHEET Recommended use of the chemical and restrictions on use Other means of identification Emergency telephone number 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product Name Identified uses CHEMTREC: +1-[PHONE REDACTED] (INTERNATIONAL) 1-[PHONE REDACTED] (NORTH AMERICA) Lubricant Synonyms No information available 1136 AUTOMATIC TRANSMISSION FLUID DEXRON®-VI Product Identifier Details of the supplier of the safety data sheet Version USA Manufacturer Lubrication Engineers Inc. 300 Bailey Avenue Fort Worth, TX 76107 USA (817) 916-3200 Page 10 of 156 Page 10 of 156 Page 10 of 156 Page 10 of 156 ---PAGE BREAK--- Revision Number 5 1136 AUTOMATIC TRANSMISSION FLUID DEXRON®-VI SDS: 1136 Issuing Date 04-24-2012 Page 2 / 8 Revision Date 05-23-2013 Eyes None. Skin None. Emergency Overview Inhalation None. 2. HAZARDS IDENTIFICATION Ingestion None. 3. COMPOSITION/INFORMATION ON INGREDIENTS Fire None. Spill None. Storage None. The producer of "1136" declares that it contains less than 3% DMSO extractable material by IP-346 Classification Disposal None. Label Elements Precautionary Statements - Prevention None. Hazards not otherwise classified (HNOC) Response None. OSHA Regulatory Status This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) None Signal Word None The product contains no substances which at their given concentration, are considered to be hazardous to health Physical state liquid Version USA appearance dark red Odor Hydrocarbon-like Page 11 of 156 Page 11 of 156 Page 11 of 156 Page 11 of 156 ---PAGE BREAK--- SDS: 1136 Issuing Date 04-24-2012 Page 3 / 8 Revision Date 05-23-2013 Revision Number 5 1136 AUTOMATIC TRANSMISSION FLUID DEXRON®-VI Eye Contact Most important and effects, both acute and delayed Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. None known. 4. FIRST AID MEASURES Inhalation Consult a physician. If not breathing, give artificial respiration. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat First Aid Measures Ingestion Drink plenty of water. Do NOT induce vomiting. Skin Contact Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. Consult a physician if necessary. Wear self-contained breathing apparatus and protective suit. Suitable Extinguishing Media Specific Hazards Arising from the Chemical Thermal decomposition can lead to release of irritating gases and vapors. Water spray, Carbon dioxide (CO2), Foam, Dry chemical 215 °C / 420 °F Explosion Data 5. FIRE-FIGHTING MEASURES Sensitivity to Mechanical Impact Not impact sensitive. Unsuitable Extinguishing Media Do not use a solid water stream as it may scatter and spread fire. Sensitivity to Static Discharge May be ignited by friction, heat, sparks or flames. Flash Point Protective Equipment and Precautions for Firefighters Instability 1 Health Hazard 1 Version USA NFPA Flammability 1 Page 12 of 156 Page 12 of 156 Page 12 of 156 Page 12 of 156 ---PAGE BREAK--- SDS: 1136 Issuing Date 04-24-2012 Page 4 / 8 Revision Date 05-23-2013 Revision Number 5 1136 AUTOMATIC TRANSMISSION FLUID DEXRON®-VI Engineering Measures Showers Eyewash stations Ventilation systems. Exposure Guidelines Individual protection measures, such as personal protective equipment This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Eye/Face Protection Eye protection not needed during typical product use conditions. Wear eye protection as appropriate when handling the bulk formulation. Control parameters Appropriate engineering controls 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Do not allow material to contaminate ground water system. Local authorities should be advised if significant spillages cannot be contained. Refer to protective measures listed in Sections 7 and 8. Methods for Cleaning up Use personal protective equipment. Take up mechanically and collect in suitable container for disposal. Clean contaminated surface thoroughly. Conditions for safe storage, including any incompatibilities 6. ACCIDENTAL RELEASE MEASURES Technical measures/Storage conditions Keep containers closed in a dry, cool and well-ventilated place. Incompatible products. Strong oxidizing agents. Strong acids. Strong bases. Methods and material for containment and cleaning up Environmental Precautions Personal precautions, protective equipment and emergency procedures Personal Precautions 7. HANDLING AND STORAGE Methods for Containment Prevent further leakage or spillage if safe to do so. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Do not touch or walk through spilled material. Remove all sources of ignition. Precautions for safe handling Advice on safe handling Version USA Handle in accordance with good industrial hygiene and safety practice. When using, do not eat, drink or smoke. For personal protection see section 8. Environmental Precautions Page 13 of 156 Page 13 of 156 Page 13 of 156 Page 13 of 156 ---PAGE BREAK--- SDS: 1136 Issuing Date 04-24-2012 Page 5 / 8 Revision Date 05-23-2013 Revision Number 5 1136 AUTOMATIC TRANSMISSION FLUID DEXRON®-VI pH 6 - 8 Melting point/freezing point No data available 9.1. Information on basic physical and chemical properties Skin and Body Protection Boiling Point/Range no data available Physical state Flash Point 215 °C / 420 °F liquid Hygiene Measures Vapor pressure No data available Handle in accordance with good industrial hygiene and safety practice. appearance Vapor Density < 1 ( Air = 1 ) dark red Long sleeved clothing. Protective gloves. Specific Gravity 0.86 Odor Water solubility negligible Hydrocarbon-like Partition Coefficient: n-octanol/water 11. TOXICOLOGICAL INFORMATION no data available Respiratory Protection Odor Threshold Autoignition Temperature Information on likely routes of exposure No data available No information available No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. Decomposition Temperature Product Information Product does not present an acute toxicity hazard based on known or supplied information No data available 9. PHYSICAL AND CHEMICAL PROPERTIES Viscosity, kinematic 29 cSt @ 40°C 10. STABILITY AND REACTIVITY Incompatible Materials Strong oxidizing agents. Strong acids. Strong bases. reactivity Possibility of Hazardous Reactions Hazardous Decomposition Products Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke) None under normal processing. No information available Conditions to Avoid Heat, flames and sparks. Contact with other chemicals Version USA Chemical stability Stable under recommended storage conditions. Page 14 of 156 Page 14 of 156 Page 14 of 156 Page 14 of 156 ---PAGE BREAK--- Page 6 / 8 Revision Date 05-23-2013 Revision Number 5 1136 AUTOMATIC TRANSMISSION FLUID DEXRON®-VI SDS: 1136 Issuing Date 04-24-2012 There is no data available for this product. Target Organ Effects Respiratory system, Eyes, Skin. Delayed and immediate effects as well as chronic effects from short and long-term exposure Numerical measures of toxicity - Product Information The producer of "1136" declares that it contains less than 3% DMSO extractable material by IP-346 Component Information No information available Remarks No information available Inhalation Sensitization No information available. Skin Contact May cause irritation. Mutagenic Effects No information available. May cause irritation of respiratory tract. Carcinogenicity No information available. Information on toxicological effects Eye Contact Contact with eyes may cause irritation. Reproductive toxicity No information available. No information available. Ingestion Persistence and Degradability No information available. 12. ECOLOGICAL INFORMATION Other Adverse Effects No information available. Ecotoxicity Bioaccumulation No information available. No information available Version USA Mobility The product is insoluble and floats on water. Page 15 of 156 Page 15 of 156 Page 15 of 156 Page 15 of 156 ---PAGE BREAK--- SDS: 1136 Issuing Date 04-24-2012 Page 7 / 8 Revision Date 05-23-2013 Revision Number 5 1136 AUTOMATIC TRANSMISSION FLUID DEXRON®-VI Complies IECSC Complies KECL Complies 14. TRANSPORT INFORMATION PICCS Complies AICS Complies 15. REGULATORY INFORMATION TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List International Inventories EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances TSCA Complies IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances DSL/NDSL Complies PICCS - Philippines Inventory of Chemicals and Chemical Substances DOT Not regulated AICS - Australian Inventory of Chemical Substances NDSL Not determined U.S. Federal Regulations EINECS Not determined ELINCS Not determined ENCS 13. DISPOSAL CONSIDERATIONS Contaminated Packaging Do not re-use empty containers. Empty containers should be taken to an approved waste handling site for recycling or disposal. Waste Disposal Methods Dispose of in accordance with local regulations. Waste treatment methods Version USA Page 16 of 156 Page 16 of 156 Page 16 of 156 Page 16 of 156 ---PAGE BREAK--- SDS: 1136 Issuing Date 04-24-2012 Page 8 / 8 Revision Date 05-23-2013 Revision Number 5 1136 AUTOMATIC TRANSMISSION FLUID DEXRON®-VI Reactive Hazard No Acute Health Hazard No U.S. State Right-to-Know Regulations This product does not contain any substances regulated by state right-to-know regulations Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). Chronic Health Hazard No SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. 16. OTHER INFORMATION SARA 311/312 Hazard Categories CERCLA This material does not contain any components with a CERCLA RQ. Issuing Date 04-24-2012 Fire Hazard No Revision Date 05-23-2013 Reason for revision No information available Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Sudden Release of Pressure Hazard U.S. State Regulations End of Safety Data Sheet No Version USA California Proposition 65 This product does not contain any Proposition 65 chemicals. Page 17 of 156 Page 17 of 156 Page 17 of 156 Page 17 of 156 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEETS The information contained in this form is based on data from sources considered to be reliable but Coastal Packaging does not guarantee the accuracy or completeness thereof. The information is provided as a service to the persons purchasing or using the material to which it refers and Coastal Packaging Inc. expressly disclaims all liability for loss or damage including consequential loss or for injury to persons including death. The information shall not be reproduced, published or distributed in any manner without prior consent in writing of Coastal Packaging Inc. Page 1 of 2 SECTION 1 - PRODUCT IDENTIFICATION AND USE Product Name: 15W40 Product Class: Lubricant WHMIS Classification: Not Controlled. Supplier Name and Address: Coastal Packaging Inc. Phone: (506) 633-3732 P.O. Box 993 Emergency: (506) 648-3060 Saint John, N.B. E2L 4E3 SECTION 2 - HAZARDOUS INGREDIENTS OF MATERIALS Hazardous Ingredients CAS# wt% ACGIH-TLV LC50 LD50 None 5 mg/m 3 (oil mist) SECTION 3 - PHYSICAL DATA AND CHEMICAL PROPERTIES Form: Liquid Vapour Pressure (mm @ 20 oC): < 0.10 Colour: Brown Volatile 0 Odour: Petroleum Specific Gravity @ 15 oC: 0.86 - 0.90 Solubility: Negligible SECTION 4 - FIRE AND EXPLOSION HAZARD Flammability: ⌧Yes No Conditions: Open flame above flash point. Flash Point : > 210 oC (COC) Upper Flammable Limit: Not established. Lower Flammable Limit: Not established. Auto Ignition Temperature: Not determined. TDG Flammability Classification: Not classified. Sensitivity to Impact: None. Sensitivity to Static Discharge: None. Means of Extinction: Dry chemical, water spray (fog), foam or carbon dioxide. Hazardous Combustion Products: Hydrogen sulphide and oxides of carbon, nitrogen, sulphur and phosphorus. Special Procedures: Water foam may cause frothing. Use water to cool exposed containers. Use self-contained breathing apparatus for fire fighting. SECTION 5 - REACTIVITY DATA Stability: This product is stable. Hazardous Polymerisation: Will not occur. Conditions to avoid: Extremely high temperatures. Incompatibility with other substances: Strong oxidising agents. Hazardous decomposition products: Thermal decomposition from high temperature or combustion will produce hydrogen sulphide and oxides of carbon, nitrogen, sulphur and phosphorus. Page 18 of 156 Page 18 of 156 Page 18 of 156 Page 18 of 156 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEETS The information contained in this form is based on data from sources considered to be reliable but Coastal Packaging does not guarantee the accuracy or completeness thereof. The information is provided as a service to the persons purchasing or using the material to which it refers and Coastal Packaging Inc. expressly disclaims all liability for loss or damage including consequential loss or for injury to persons including death. The information shall not be reproduced, published or distributed in any manner without prior consent in writing of Coastal Packaging Inc. Page 2 of 2 SECTION 6 - TOXICOLOGICAL PROPERTIES Route of Entry: Eye ⌧ Skin Contact Skin Absorption ⌧ Inhalation ⌧ Ingestion Effects of Acute Exposure: Irritation to skin and eyes. Inhalation of hot oil mist or vapours may irritate the upper respiratory tract. Effects of Chronic Exposure: Repeated or prolonged exposure may cause dermatitis and/or oil acne. Long-term intensive exposure to oil mist may cause benign lung fibrosis. No specific toxicity data but extrapolation from similar materials indicates that this product has low oral toxicity. Exposure Limits: 5 mg/m 3 (oil mist) Carcinogenicity: Not determined. Reproductive Toxicity: Not determined. Teratogenicity: Not determined. Irritancy of Product: Slight. Mutagenicity: Not determined. SECTION 7 - PREVENTATIVE AND CORRECTIVE MEASURES Personal Protective Equipment: Gloves: Oil/Chemical resistant. Eye: Chemical safety glasses or full face shield. Respiratory: NOISH respirator if mist levels are high. Footwear: Oil/Chemical resistant. Clothing: Oil/Chemical resistant if repeated exposure to skin and clothing occurs. Other: Engineering Controls: Local exhaust at source of heated vapours. Leak and Spill Procedure: Contain spills with dikes or absorbent material. Eliminate fire hazards. Prevent from entering sewers or water courses. Vacuum liquid or transfer absorbed material into containers. Advise authorities. Waste Disposal: Follow local and governmental regulations. Not regulated as a hazardous waste. Storage Requirements Cool, dry location. Keep containers closed. Special Shipping Information: No special requirements. SECTION 8 - FIRST AID MEASURES Inhalation: Remove to fresh air or give artificial respiration. If breathing is difficult, give oxygen and seek medical attention. Ingestion: Do not induce vomiting, give two glasses of water and seek medical attention. Eye: Flush with water for 15 minutes. Skin: Wash contaminated area with soap and water. Clean contaminated clothing before wearing again. General Advice: High pressure injection under skin can be serious and requires urgent medical attention. SECTION 9 - PREPARATION DATE OF MSDS MSDS Prepared by: Coastal Packaging Inc. Phone: (506) 633-3732 MSDS Date: March 1,2006 Revision 00 Page 19 of 156 Page 19 of 156 Page 19 of 156 Page 19 of 156 ---PAGE BREAK--- Page 20 of 156 Page 20 of 156 Page 20 of 156 Page 20 of 156 ---PAGE BREAK--- Page 21 of 156 Page 21 of 156 Page 21 of 156 Page 21 of 156 ---PAGE BREAK--- Chemical formula Revision date 2 Cycle Oil Blend 2-Cycle Engine Oil. Hydrocarbon. Product name Common name Chemical family Transportation Emergency (CHEMTREC) Section 1. Identification : : : : Chemical name : Lubricating oil. Relevant identified uses of the substance or mixture and uses advised against SAFETY DATA SHEET Lubricant. CHS Inc. P.O. Box 64089 Mail station 525 St. Paul, MN 55164-0089 1-[PHONE REDACTED] SDS no. : 0110-043713 : Technical Information SDS Information : : 1-[PHONE REDACTED] 1-[PHONE REDACTED] : Mixture 11/15/2013 Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 4 CARCINOGENICITY - Category 2 ASPIRATION HAZARD - Category 1 Classification of the substance or mixture : Signal word : Danger Hazard statements : Combustible liquid. Suspected of causing cancer. May be fatal if swallowed and enters airways. Hazard pictograms : Precautionary statements GHS label elements General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Hazardous Material Information System National Fire Protection Association Health : 2 * Flammability : 2 Physical hazards : 0 Health : 0 2 2 Instability : Flammability : Kerosene 10 - 30 8008-20-6 Naphthalene 0.1 - 1 91-20-3 Ingredient name CAS number % There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Chemical name : Lubricating oil. Other means of identification : Blend 2-Cycle Engine Oil. Substance/mixture : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Section 3. Composition/information on ingredients 1/7 Page 22 of 156 Page 22 of 156 Page 22 of 156 Page 22 of 156 ---PAGE BREAK--- 2 Cycle Oil Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention. Flush contaminated skin with plenty of water. Continue to rinse for at least 20 minutes. Get medical attention. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Description of necessary first aid measures Specific treatments : No specific treatment. Most important acute and delayed Inhalation : No known significant effects or critical hazards. May be fatal if swallowed and enters airways. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. : Eye contact Over-exposure Skin contact Ingestion Inhalation No known significant effects or critical hazards. Adverse may include the following: nausea or vomiting No known significant effects or critical hazards. : : : Eye contact : No known significant effects or critical hazards. Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical No specific data. Combustible liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use dry chemical, CO2, water spray (fog) or foam. Extinguishing media : : : Do not use water jet or water-based fire extinguishers. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Methods and materials for containment and cleaning up For non-emergency personnel 2/7 Page 23 of 156 Page 23 of 156 Page 23 of 156 Page 23 of 156 ---PAGE BREAK--- 2 Cycle Oil Spill Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not swallow. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Kerosene NIOSH REL (United States, 6/2009). TWA: 100 mg/m³ 10 hours. ACGIH TLV (United States, 3/2012). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours. Naphthalene ACGIH TLV (United States, 3/2012). Absorbed through skin. STEL: 79 mg/m³ 15 minutes. STEL: 15 ppm 15 minutes. TWA: 52 mg/m³ 8 hours. TWA: 10 ppm 8 hours. NIOSH REL (United States, 6/2009). STEL: 75 mg/m³ 15 minutes. STEL: 15 ppm 15 minutes. TWA: 50 mg/m³ 10 hours. TWA: 10 ppm 10 hours. OSHA PEL (United States, 6/2010). TWA: 50 mg/m³ 8 hours. TWA: 10 ppm 8 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 10 ppm 8 hours. TWA: 50 mg/m³ 8 hours. STEL: 15 ppm 15 minutes. STEL: 75 mg/m³ 15 minutes. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields. Eye/face protection : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Control parameters Individual protection measures Occupational exposure limits Skin protection 3/7 Page 24 of 156 Page 24 of 156 Page 24 of 156 Page 24 of 156 ---PAGE BREAK--- 2 Cycle Oil Hand protection Use a properly fitted, air-purifying or supplied air respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Respiratory protection : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. 0.86 to 0.89 Not available. <0.13 kPa mm Hg)(68oF) Insoluble in the following materials: cold water and hot water. Mild. Odor pH Blue. Color Evaporation rate <1 (Butyl acetate = 1) Auto-ignition temperature Flash point >204.444°C (>400°F) Closed cup: >60°C (>140°F) Not available. Not available. Viscosity Not available. Not available. Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability : Not available. Lower and upper explosive (flammable) limits : Not available. SADT Not available. : Decomposition temperature : Not available. Solubility in water : Insoluble Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability Reactive or incompatible with the following materials: oxidizing materials. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Kerosene LD50 Oral Rat 15 g/kg - Naphthalene LD50 Dermal Rabbit >20 g/kg - LD50 Oral Rat 490 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Kerosene Skin - Severe irritant Rabbit - 500 mg - Skin - Moderate irritant Rabbit - 24 hours 100% - Skin - Moderate irritant Rabbit - 0.5 mL - Naphthalene Skin - Mild irritant Rabbit - 495 mg - Skin - Severe irritant Rabbit - 24 hours 0.05 mL - Product/ingredient name Result Score Exposure Observation Sensitization Species Information on toxicological effects Skin : There is no data available. 4/7 Page 25 of 156 Page 25 of 156 Page 25 of 156 Page 25 of 156 ---PAGE BREAK--- 2 Cycle Oil Carcinogenicity Mutagenicity Teratogenicity Reproductive toxicity Information on the likely routes of exposure Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Name Result Kerosene ASPIRATION HAZARD - Category 1 : Dermal contact. Eye contact. Inhalation. Ingestion. Classification Naphthalene - 2B Reasonably anticipated to be a human carcinogen. Product/ingredient name NTP IARC OSHA Respiratory : There is no data available. There is no data available. There is no data available. There is no data available. There is no data available. There is no data available. There is no data available. Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Naphthalene 3.3 85.11380382 low Toxicity Naphthalene Acute EC50 1600 µg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 2350 µg/l Marine water Crustaceans - Palaemonetes pugio 48 hours Acute LC50 213 µg/l Fresh water Fish - Melanotaenia fluviatilis - Larvae 96 hours Product/ingredient name Species Result Exposure Persistence and degradability Soil/water partition coefficient (KOC) : There is no data available. Mobility in soil There is no data available. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. : Disposal methods 5/7 Page 26 of 156 Page 26 of 156 Page 26 of 156 Page 26 of 156 ---PAGE BREAK--- 2 Cycle Oil Section 14. Transport information COMBUSTIBLE LIQUID, N.O.S. (Kerosene) Combustible liquid. NA1993 DOT IDENTIFICATION NUMBER DOT proper shipping name DOT Hazard Class(es) DOT EMER. RESPONSE GUIDE NO. 128 PG III California Prop. 65 Section 15. Regulatory information U.S. Federal regulations The following components are listed: Kerosene WARNING: This product contains a chemical known to the State of California to cause cancer. Clean Water Act (CWA) 307: Naphthalene Clean Water Act (CWA) 311: Naphthalene; Vinyl acetate Massachusetts : : SARA 313 Product name CAS number % Naphthalene Yes. No. Yes. No. Vinyl acetate Yes. No. No. No. Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level Not applicable. - - Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) : Not listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Not listed New York : The following components are listed: Naphthalene New Jersey : The following components are listed: Distillates (petroleum), solvent-dewaxed heavy paraffinic; Kerosene; Naphthalene; Residual oils (petroleum), solvent-dewaxed : The following components are listed: Kerosene; Naphthalene State regulations TSCA 4(a) final test rules: 2-Butenedioic acid di-C8-18-alkyl esters TSCA 8(a) PAIR: Naphthalene; 2-Butenedioic acid di-C8-18-alkyl esters TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): All components are listed or exempted. SARA 302/304 SARA 304 RQ : Not applicable. Vinyl acetate 0 - 0.1 Yes. - - - - Composition/information on ingredients Name % EHS (lbs) (lbs) (gallons) (gallons) SARA 302 TPQ SARA 304 RQ SARA 311/312 Classification : Fire hazard Delayed (chronic) health hazard Kerosene 10 - 30 Yes. No. No. No. No. Naphthalene 0.1 - 1 No. No. No. Yes. Yes. Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients This product (does/not) contain toxic chemicals subject to the reporting requirements of SARA Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372. : SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. : 6/7 Page 27 of 156 Page 27 of 156 Page 27 of 156 Page 27 of 156 ---PAGE BREAK--- 2 Cycle Oil Prepared by : KMK Regulatory Services Inc. Revised Section(s) : 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16. Section 16. Other information Notice to reader THE INFORMATION CONTAINED IN THIS SDS RELATES ONLY TO THE SPECIFIC MATERIAL IDENTIFIED. IT DOES NOT COVER USE OF THAT MATERIAL IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY PARTICULAR PROCESS. IN COMPLIANCE WITH 29 C.F.R. 1910.1200(g), CHS HAS PREPARED THIS SDS IN SEGMENTS, WITH THE INTENT THAT THOSE SEGMENTS BE READ TOGETHER AS A WHOLE WITHOUT TEXTUAL OMISSIONS OR ALTERATIONS. CHS BELIEVES THE INFORMATION CONTAINED HEREIN TO BE ACCURATE, BUT MAKES NO REPRESENTATION, GUARANTEE, OR WARRANTY, EXPRESS OR IMPLIED, ABOUT THE ACCURACY, RELIABILITY, OR COMPLETENESS OF THE INFORMATION OR ABOUT THE FITNESS OF CONTENTS HEREIN FOR EITHER GENERAL OR PARTICULAR PURPOSES. PERSONS REVIEWING THIS SDS SHOULD MAKE THEIR OWN DETERMINATION AS TO THE MATERIAL’S SUITABILITY AND COMPLETENESS FOR USE IN THEIR PARTICULAR APPLICATIONS. 11/15/2013 Revision date : Supersedes : 05/20/2013 7/7 Page 28 of 156 Page 28 of 156 Page 28 of 156 Page 28 of 156 ---PAGE BREAK--- 1 Revision Number: 1 Revision Date: June 1, 2015 AW Hydraulic Oil 46 SECTION 1 PRODUCT AND COMPANY IDENTIFICATION Product Use: Premium quality anti-wear hydraulic oil Company Identification Motor Oil 2250 Arthur Avenue Elk Grove Village, IL 60007 www.motoroilinc.com Transportation Emergency Response/ Health Emergency (847) 956-7550 Product Information email : [EMAIL REDACTED] Product Information: 1 (847) 956-7550 SECTION 2 HAZARDS IDENTIFICATION Safety Data Sheet AW Hydraulic Oil 46 CLASSIFICATION: Not classified as hazardous according to 29 CFR 1910.1200 (2012). HAZARDS NOT OTHERWISE CLASSIFIED: Not Applicable SECTION 3 COMPOSITION/ INFORMATION ON INGREDIENTS COMPONENTS CAS NUMBER AMOUNT Highly refined mineral oil (C15 - C50) Mixture 70 - 99 %wt/wt SECTION 4 FIRST AID MEASURES Description of first aid measures Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and flush eyes with water. Skin: No specific first aid measures are required. As a precaution, remove clothing and shoes if contaminated. To remove the material from skin, use soap and water. Discard contaminated clothing and shoes or thoroughly clean before reuse. Ingestion: No specific first aid measures are required. Do not induce vomiting. As a precaution, get medical advice. Inhalation: No specific first aid measures are required. If exposed to excessive levels of material in the air, move the exposed person to fresh air. Get medical attention if coughing or respiratory discomfort occurs. Page 29 of 156 Page 29 of 156 Page 29 of 156 Page 29 of 156 ---PAGE BREAK--- 2 Revision Number: 1 Revision Date: June 1, 2015 AW Hydraulic Oil 46 SECTION 5 FIRE FIGHTING MEASURES Most important and effects, both acute and delayed IMMEDIATE AND HEALTH EFFECTS Eye: Not expected to cause prolonged or significant eye irritation. Skin: Contact with the skin is not expected to cause prolonged or significant irritation. Contact with the skin is not expected to cause an allergic skin response. Not expected to be harmful to internal organs if absorbed through the skin. High-Pressure Equipment Information: Accidental high-velocity injection under the skin of materials of this type may result in serious injury. Seek medical attention at once should an accident like this occur. The initial wound at the injection site may not appear to be serious at first; but, if left untreated, could result in disfigurement or amputation of the affected part. Ingestion: Not expected to be harmful if swallowed. Inhalation: Not expected to be harmful if inhaled. Contains a petroleum-based mineral oil. May cause respiratory irritation or other pulmonary effects following prolonged or repeated inhalation of oil mist at airborne levels above the recommended mineral oil mist exposure limit. of respiratory irritation may include coughing and difficulty breathing. DELAYED OR OTHER AND HEALTH EFFECTS: Not classified. Indication of any immediate medical attention and special treatment needed Note to Physicians: In an accident involving high-pressure equipment, this product may be injected under the skin. Such an accident may result in a small, sometimes bloodless, puncture wound. However, because of its driving force, material injected into a fingertip can be deposited into the palm of the hand. Within 24 hours, there is usually a great deal of swelling, discoloration, and intense throbbing pain. Immediate treatment at a surgical emergency center is recommended. Leaks/ruptures in high pressure system using materials of this type can create a fire hazard when in the vicinity of ignition sources (eg. open flame, pilot lights, sparks, or electric arcs). EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. PROTECTION OF FIRE FIGHTERS: Fire Fighting Instructions: This material will burn although it is not easily ignited. See Section 7 for proper handling and storage. For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment, including self-contained breathing apparatus. Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds will be evolved when this material undergoes combustion. SECTION 6 ACCIDENTAL RELEASE MEASURES Protective Measures: Eliminate all sources of ignition in vicinity of spilled material. Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent further contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as applying non-combustible absorbent materials or pumping. Where feasible and appropriate, remove contaminated soil. Place contaminated materials in disposable containers and dispose of in a manner consistent with applicable regulations. Reporting: Report spills to local authorities as appropriate or required. Page 30 of 156 Page 30 of 156 Page 30 of 156 Page 30 of 156 ---PAGE BREAK--- 3 Revision Number: 1 Revision Date: June 1, 2015 AW Hydraulic Oil 46 SECTION 7 HANDLING AND STORAGE SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION GENERAL CONSIDERATIONS: Consider the potential hazards of this material (see Section applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user should read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances. ENGINEERING CONTROLS: Use in a well-ventilated area. PERSONAL PROTECTIVE EQUIPMENT Eye/Face Protection: No special eye protection is normally required. Where splashing is possible, wear safety glasses with side shields as a good safety practice. Skin Protection: No special protective clothing is normally required. Where splashing is possible, select protective clothing depending on operations conducted, physical requirements and other substances in the workplace. Suggested materials for protective gloves include: Nitrile Rubber, Silver Shield, Viton. Respiratory Protection: No respiratory protection is normally required. If user operations generate an oil mist, determine if airborne concentrations are below the occupational exposure limit for mineral oil mist. If not, wear an approved respirator that provides adequate protection from the measured concentrations of this material. For air-purifying respirators use a particulate cartridge. Use a positive pressure air- supplying respirator in circumstances where air-purifying respirators may not provide adequate protection. General Handling Information: Avoid contaminating soil or releasing this material into sewage and drainage systems and bodies of water. Precautionary Measures: DO NOT USE IN HIGH PRESSURE SYSTEMS in the vicinity of flames, sparks and hot surfaces. Use only in well ventilated areas. Keep container closed. Keep out of the reach of children. Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this material. To minimize this hazard, bonding and grounding may be necessary but may not, by themselves, be sufficient. Review all operations which have the potential of generating and accumulating an electrostatic charge and/or a flammable atmosphere (including tank and container filling, splash filling, tank cleaning, sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and use appropriate mitigating procedures. For more information, refer to OSHA Standard 29 CFR 1910.106, 'Flammable and Combustible Liquids', National Fire Protection Association (NFPA 77, 'Recommended Practice on Static Electricity', and/or the American Petroleum Institute (API) Recommended Practice 2003, 'Protection Against Ignitions Arising Out of Static, Lightning, and Stray Currents'. Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid, and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode and cause injury or death. Empty containers should be completely drained, properly closed, and returned to a drum reconditioner or disposed of properly. Occupational Exposure Limits: Component Agency TWA STEL Ceiling Notation Highly refined mineral oil (C15 - C50) OSHA Z-1 5 mg/m3 Highly refined mineral oil (C15 - C50) ACGIH 5 mg/m3 10 mg/m3 Consult local authorities for appropriate values. Page 31 of 156 Page 31 of 156 Page 31 of 156 Page 31 of 156 ---PAGE BREAK--- 4 Revision Number: 1 Revision Date: June 1, 2015 AW Hydraulic Oil 46 SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES SECTION 10 STABILITY AND REACTIVITY Reactivity: May react with strong acids or strong oxidizing agents, such as chlorates, nitrates, peroxides, etc. Chemical Stability: This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. Incompatibility With Other Materials: Not applicable Hazardous Decomposition Products: None known (None expected) Hazardous Polymerization: Hazardous polymerization will not occur. Attention: the data below are typical values and do not constitute a specification. Color: Yellow Physical State: Liquid Odor: Petroleum odor Odor Threshold: No Determined pH: Essentially neutral Vapor Pressure: Not Determined Vapor Density (Air = Greater than 5 Initial Boiling Point: 600°F Solubility: Negligible Freezing Point: Not Applicable Viscosity: 46 cSt @ 40°C Decomposition temperature: No data available Octanol/Water Partition Coefficient: No data available FLAMMABLE PROPERTIES: Flammability (solid, gas): No Data Available Flashpoint: (Cleveland Open Cup) 210 °C Autoignition: Not Determined Flammability (Explosive) Limits by volume in air): Lower: Not Determined Upper: Not Determined SECTION 11 TOXICOLOGICAL INFORMATION Information on toxicological effects Serious Eye Damage/Irritation: The eye irritation hazard is based on evaluation of data for product components. Skin Corrosion/Irritation: The skin irritation hazard is based on evaluation of data for product components. Skin Sensitization: The skin sensitization hazard is based on evaluation of data for product components. Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for product components. Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for product components. Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for product components. Page 32 of 156 Page 32 of 156 Page 32 of 156 Page 32 of 156 ---PAGE BREAK--- 5 Revision Number: 1 Revision Date: June 1, 2015 AW Hydraulic Oil 46 SECTION 12 ECOLOGICAL INFORMATION Acute Toxicity Estimate: Not Determined Germ Cell Mutagenicity: The hazard evaluation is based on data for components or a similar material. Carcinogenicity: The hazard evaluation is based on data for components or a similar material. Reproductive Toxicity: The hazard evaluation is based on data for components or a similar material. Specific Target Organ Toxicity - Single Exposure: The hazard evaluation is based on data for components or a similar material. Specific Target Organ Toxicity - Repeated Exposure: The hazard evaluation is based on data for components or a similar material. ADDITIONAL TOXICOLOGY INFORMATION: This product contains petroleum base oils which may be refined by various processes including severe solvent extraction, severe hydrocracking, or severe hydrotreating. None of the oils requires a cancer warning under the OSHA Hazard Communication Standard (29 CFR 1910.1200). These oils have not been listed in the National Toxicology Program (NTP) Annual Report nor have they been classified by the International Agency for Research on Cancer (IARC) as; carcinogenic to humans (Group probably carcinogenic to humans (Group 2A), or possibly carcinogenic to humans (Group 2B). These oils have not been classified by the American Conference of Governmental Industrial Hygienists (ACGIH) as: confirmed human carcinogen (A1), suspected human carcinogen (A2), or confirmed animal carcinogen with unknown relevance to humans (A3). ECOTOXICITY This material is not expected to be harmful to aquatic organisms. The ecotoxicity hazard is based on an evaluation of data for the components or a similar material. The product has not been tested. The statement has been derived from the properties of the individual components. MOBILITY No data available. PERSISTENCE AND DEGRADABILITY This material is not expected to be readily biodegradable. The biodegradability of this material is based on an evaluation of data for the components or a similar material. The product has not been tested. The statement has been derived from the properties of the individual components. POTENTIAL TO BIOACCUMULATE Bioconcentration Factor: No data available. Octanol/Water Partition Coefficient: No data available SECTION 13 DISPOAL CONSIDERATIONS Use material for its intended purpose or recycle if possible. Oil collection services are available for used oil recycling or disposal. Place contaminated materials in containers and dispose of in a manner consistent with applicable regulations. Contact your sales representative or local environmental or health authorities for approved disposal or recycling methods. Page 33 of 156 Page 33 of 156 Page 33 of 156 Page 33 of 156 ---PAGE BREAK--- 6 Revision Number: 1 Revision Date: June 1, 2015 AW Hydraulic Oil 46 SECTION 14 TRANSPORT INFORMATION SECTION 15 REGULATORY INFORMATION EPCRA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: NO 2. Delayed (Chronic) Health Effects: NO 3. Fire Hazard: NO 4. Sudden Release of Pressure Hazard: NO 5. Reactivity Hazard: NO REGULATORY LISTS SEARCHED: 01-1=IARC Group 1 03=EPCRA 313 01-2A=IARC Group 2A 04=CA Proposition 65 01-2B=IARC Group 2B 05=MA RTK 02=NTP Carcinogen 06=NJ RTK 07=PA RTK No components of this material are found on the regulatory lists above. CHEMICAL INVENTORIES: All components comply with the following chemical inventory requirements: AICS (Australia), DSL (Canada), EINECS (European Union), IECSC (China), KECI (Korea), PICCS (Philippines), TSCA (United States). One or more components does not comply with the following chemical inventory requirements: ENCS (Japan). NEW JERSEY RTK CLASSIFICATION: Under the New Jersey Right-to-Know Act L. 1983 Chapter 315 N.J.S.A. 34:5A-1 et. seq., the product is to be identified as follows: PETROLEUM OIL (Hydraulic oil) The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods Regulations, for additional description requirements technical name) and mode-specific or quantity- specific shipping requirements. DOT Shipping Description: PETROLEUM LUBRICATING OIL, NOT REGULATED AS A HAZARDOUS MATERIAL FOR TRANSPORTATION UNDER 49 CFR IMO/IMDG Shipping Description: PETROLEUM LUBRICATING OIL; NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORT UNDER THE IMDG CODE ICAO/IATA Shipping Description: PETROLEUM LUBRICATING OIL; NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORT UNDER ICAO TI OR IATA DGR Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code: Not applicable SECTION 16 OTHER INFORMATION NFPA RATINGS: Health: 0 Flammability: 1 Reactivity: 0 HMIS RATINGS: Health: 0 Flammability: 1 Reactivity: 0 Page 34 of 156 Page 34 of 156 Page 34 of 156 Page 34 of 156 ---PAGE BREAK--- 7 Revision Number: 1 Revision Date: June 1, 2015 AW Hydraulic Oil 46 (0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index recommendation, Chronic Effect Indicator). These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating Association (for HMIS ratings). LABEL RECOMMENDATION: Label Category : INDUSTRIAL OIL 1 - IND1 REVISION STATEMENT: This revision updates the following sections of this Safety Data Sheet: 1-16 Revision Date: JUNE 1, 2015 ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT: TLV - Threshold Limit Value TWA - Time Weighted Average STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit GHS - Globally Harmonized System CAS - Chemical Abstract Service Number ACGIH - American Conference of Governmental Industrial Hygienists IMO/IMDG - International Maritime Dangerous Goods Code API - American Petroleum Institute SDS - Safety Data Sheet HMIS - Hazardous Materials Information System NFPA - National Fire Protection Association (USA) DOT - Department of Transportation (USA) NTP - National Toxicology Program (USA) IARC - International Agency for Research on Cancer OSHA - Occupational Safety and Health Administration NCEL - New Chemical Exposure Limit EPA - Environmental Protection Agency SCBA - Self-Contained Breathing Apparatus Amended to conform to the United Nations’ Globally Harmonized System of Classifications and Labeling of Chemi- cals (OSHA/GHS). Although the information and recommendations set forth herein are presented in good faith and believed to be correct as of the date hereof, MOTOR OIL makes no representations as to the completeness or accuracy thereof. MOTOR OIL makes no warranty whatsoever, expressed or implied, of MERCHANTABILITY OR FITNESS FOR THE PARTICULAR PURPOSE since the conditions of use are beyond our control. MOTOR OIL assumes no responsibility for injury to recipient or to third persons for any damage to any property and recipient. END OF SAFETY DATA SHEET Page 35 of 156 Page 35 of 156 Page 35 of 156 Page 35 of 156 ---PAGE BREAK--- Page 36 of 156 Page 36 of 156 Page 36 of 156 Page 36 of 156 ---PAGE BREAK--- Page 37 of 156 Page 37 of 156 Page 37 of 156 Page 37 of 156 ---PAGE BREAK--- Thrust Product Code: C2005 Page 1 of 3 SAFETY DATA SHEET SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle® Thrust™ PRODUCT TYPE: Penetrating Oil PRODUCT CODE: C2005 MANUFACTURED FOR: Castle Products, Inc. 424 St. Paul Street Rochester, NY 14605 [PHONE REDACTED] • FAX [PHONE REDACTED] EMERGENCY [PHONE REDACTED] SECTION 2 HAZARD IDENTIFICATION EMERGENCY OVERVIEW: DANGER: Gases Under Pressure, Flammable, Irritant POTENTIAL HEALTH EFFECTS: Eyes: May cause irritation. Skin: May cause irritation. Prolonged exposure may cause fatting dermatitis. Inhalation: May cause irritation. Propellant is a simple Ingestion: May cause headache, nausea, vomiting, and weakness. Effects of chronic exposure: Lifetime skin painting tests indicate that materials of similar composition as kerosene may have produced skin cancer in experimental animals. The relationship of these results to humans has not been fully established. SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % Petroleum Oil Blend (Mixture) 64742-52-5 5 mg/m3 NE NE 30-60% Kerosene (Petroleum) 8008-20-6 5 ppm NE NE 10-30% Propane 74-98-6 1000 ppm NE NE 7-15% Isobutane 75-28-5 1000 ppm NE NE 5-10% Ethyl acetate 141-78-6 400 ppm NE NE 1-5% SECTION 4 FIRST AID MEASURES First Aid Procedures: Eye contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician if irritation persists. Skin contact: For skin contact flush with large amounts of water. Call a physician if irritation persists. Inhalation: Immediately remove from further exposure. Give supplemental oxygen, if breathing is difficult. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by mouth to an unconscious person. Note to physician: If the product is ingested, treat the affected person SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: 25°F LOWER EXPLOSIVE LIMIT: 2.0% UPPER EXPLOSIVE LIMIT: 10.7% [Propellant: ≥-141°F EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate for surrounding fire. UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: Water from fogging nozzles may be used to cool closed containers to prevent pressure build-up if exposed to extreme temperatures. As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area. Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Ventilate spaces before entering. Environmental precautions: Prevent further leakage or spillage if safe to do so. Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Eliminate ignition sources including sources of electrical, static or frictional sparks. Wear appropriate protective equipment and clothing during clean-up. Page 38 of 156 Page 38 of 156 Page 38 of 156 Page 38 of 156 ---PAGE BREAK--- Thrust Product Code: C2005 Page 2 of 3 Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal. Large Spills: Dike far ahead of liquid spill for disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. SECTION 7 HANDLING AND STORAGE Handling: Avoid breathing mist. Avoid contact with skin and eyes. Wear suitable protective clothing. Wash hands after handling. Storage: Keep from freezing. Keep containers closed. Store in a cool, dry place. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established. Engineering controls: Use local exhaust ventilation. Personal protective equipment: General: Eye wash fountain and emergency showers are recommended. Eye/face Protection: Wear safety glasses or goggles. Skin Protection: Wear suitable protective clothing. Wear chemical resistant gloves. Respiratory Protection: When respiratory protection is required, wear a NIOSH/MSHA approved self-contained breathing apparatus with full facepiece operated in a positive-pressure mode. SECTION 9 PHYSICAL and CHEMICAL PROPERTIES BOILING POINT: 168°F (76°C) SPECIFIC GRAVITY (H2O=1): 0.88-0.89 (liquid) 0.75-0.79 (aerosol) VAPOR PRESSURE: 55-65 PERCENT VOLATILE BY VOL >95% VAPOR DENSITY (air=1) >1 EVAPORATION RATE (Butyl Acetate=1): <1 SOLUBILITY IN WATER: Negligible APPEARANCE & ODOR: Dark amber liquid / characteristic pH: NA SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (material to avoid): Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide, Carbon Dioxide, Hydrocarbon fumes and smoke where combustion is incomplete. HAZARDOUS POLYMERIZATION: Will not occur SECTION 11 TOXICOLOGICAL INFORMATION Components Test Results: No information available. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. SECTION 12 ECOLOGICAL INFORMATION Component Test Results: No information available. SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Do not puncture or incinerate containers, even when empty. Dispose according to all applicable Federal, State, and Local regulations. SECTION 14 TRANSPORT INFORMATION D.O.T. Classification: Consumer Commodity, ORM-D T.D.G. Classification: Consumer Commodity (Aerosols, UN1950, Class 2.1) SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations. CERCLA (Superfund) reportable quantity: None SARA (Superfund Amendments and Reauthorization Act of 1986): 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Page 39 of 156 Page 39 of 156 Page 39 of 156 Page 39 of 156 ---PAGE BREAK--- Thrust Product Code: C2005 Page 3 of 3 Section 302 extremely hazardous substance: No Section 311 hazardous chemical: No Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR. SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.) HMIS® ratings Health: 2 Flammability: 4 Physical hazard: 0 NFPA Code 30B: Level 3 Other: NA-Not Applicable, ND-Not Determined, NE-Not Established. Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. PREPARED: 9/25/96 UPDATED: 6/14/13 PRODUCT C2005 Page 40 of 156 Page 40 of 156 Page 40 of 156 Page 40 of 156 ---PAGE BREAK--- Page 41 of 156 Page 41 of 156 Page 41 of 156 Page 41 of 156 ---PAGE BREAK--- Page 42 of 156 Page 42 of 156 Page 42 of 156 Page 42 of 156 ---PAGE BREAK--- There was a PDF conversion failure for - Product Name: Diesel Fuel CAS Number: 64742-80-9 Manufacturer: Total Petrochemicals & Refining USA, Inc. SDS Date: 7/22/2015 To complete your binder, please link a different SDS for this product or print the SDS manually from http://www.msdsonline.com/Legacy/Partners/Show-Document/Default.aspx?ShowId=P74coa%2fh0QI%3d and add to your binder. We are currently researching solutions to this issue. Thank you for your patience. Page 43 of 156 Page 43 of 156 Page 43 of 156 Page 43 of 156 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 1 of 13 POWER SERVICE PRODUCTS, INC. SAFETY DATA SHEET SECTION 1 - IDENTIFICATION PRODUCT NAME: DIESEL FUEL SUPPLEMENT +CETANE BOOST Unless otherwise noted, all sections of this SDS apply to each of the following products and part numbers. PART NUMBERS: 1:400 Treatment Ratio 1016-06, 1016-09, 1025-06, 1025-09, 1025-12, 1080-06, 11016-06, 11016-09, 11025-06, 11025-12, 11080-06 1:1,000 Treatment Ratio 1000, 1128-04, 1060-01 1:1,500 Treatment Ratio 1050-02, 1055-01, 1260-01 COMPANY IDENTIFICATION: Power Service Products, Inc. P.O. Box 1089 Weatherford, TX 76086 Email: [EMAIL REDACTED] Phone: [PHONE REDACTED] or [PHONE REDACTED] Fax: [PHONE REDACTED] Emergency Phone Number: Within USA 1-[PHONE REDACTED]. Outside USA 001-[PHONE REDACTED] (Call Collect). RECOMMENDED USES: Diesel fuel additive SECTION 2 – HAZARD(S) IDENTIFICATION CLASSIFICATION UNDER 29 CFR 1910.1200(d) (NC=product does not meet classification criteria) 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Health Hazard Criteria Category Category Category Acute Toxicity, Oral: NC NC NC Acute Toxicity, Dermal: NC NC NC Acute Toxicity, Inhalation, Vapors: 3 3 3 Page 44 of 156 Page 44 of 156 Page 44 of 156 Page 44 of 156 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 2 of 13 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Health Hazard Criteria Category Category Category Skin Corrosion/Irritation: 2 2 2 Serious Eye Damage/Eye Irritation: 2 2 2 Respiratory Sensitization: NC NC NC Skin Sensitization: NC NC NC Germ Cell Mutagenicity: NC NC NC Carcinogenicity: 2 2 2 Reproductive Toxicity: NC NC NC Specific Target Organ Toxicity, Single Exposure: 3 3 3 Specific Target Organ Toxicity, Repeated or Prolonged Exposure: NC NC NC Aspiration Hazard: 1 1 1 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Physical Properties Criteria Category Category Category Explosives: NC NC NC Flammable Gases: NC NC NC Flammable Aerosols: NC NC NC Oxidizing Gases: NC NC NC Gases Under Pressure: NC NC NC Flammable Liquids: 3 3 3 Flammable Solids: NC NC NC Self-Reactive Chemicals: NC NC NC Pyrophoric Liquids: NC NC NC Pyrophoric Solids: NC NC NC Self-Heating Chemicals: NC NC NC Chemicals Which, in Contact with Water, Emit Flammable Gases: NC NC NC Oxidizing Liquids: NC NC NC Oxidizing Solids: NC NC NC Organic Peroxides: NC NC NC Corrosive to Metals: NC NC NC LABEL SIGNAL WORD, HAZARD STATEMENTS, SYMBOLS AND PRECAUTIONARY STATEMENTS UNDER 29 CFR 1910.1200(f): Please see the Note regarding product labeling in Section 16. Page 45 of 156 Page 45 of 156 Page 45 of 156 Page 45 of 156 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 3 of 13 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Signal Word Danger Danger Danger Hazard Statement(s): Flammable liquid and vapor. Toxic if inhaled. May be fatal if swallowed and enters airways. Harmful if swallowed. Causes skin and serious eye irritation. May cause respiratory irritation and drowsiness or dizziness. Symbols: The following symbols are for all treatment ratios. Precautionary Statement(s): Keep away from sparks and open flames. No smoking. Keep container closed. Use only non-sparking tools. Ground/Bond container and receiving equipment. Use explosion-proof pumps when pumping. Take precautionary measures against static discharge. Avoid breathing vapors. Use only outdoors or in a well-ventilated area. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves and eye protection. Store locked up and in cool, well ventilated place. KEEP OUT OF REACH OF CHILDREN. Hazards Not Otherwise Classified: None SECTION 3 – COMPOSITION / INFORMATION ON INGREDIENTS The specific chemical identity and exact concentration percentage has been withheld as a Trade Secret. Specific chemical information will be made available to health professionals in accordance with 29 CFR 1910.1200. INGREDIENTS CLASSIFIED AS HEALTH HAZARDS TREATMENT RATIO 1:400 Chemical Name Common Name/Synonyms CAS Number Concentration Petroleum Distillates Trade secret Trade secret 50 - 90 Hydroxy alkoxylate Trade secret Trade secret 4 - 10 Alkyl Nitrates Trade secret Trade secret 2 - 6 Naphthalene Not available 91-20-3 0.05 – 0.2 Page 46 of 156 Page 46 of 156 Page 46 of 156 Page 46 of 156 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 4 of 13 TREATMENT RATIO 1:1000 Chemical Name Common Name/Synonyms CAS Number Concentration Petroleum Distillates Trade secret Trade secret 40 - 90 Alkyl Nitrates Trade secret Trade secret 5 - 15 Aromatic Hydrocarbons Trade secret Trade secret 2 - 5 Hexan-1-ol, 2-ethyl Trade secret Trade secret 1 - 4 Naphthalene Not available 91-20-3 0.1 – 0.5 TREATMENT RATIO 1:1500 Chemical Name Common Name/Synonyms CAS Number Concentration Petroleum Distillates Trade secret Trade secret 20 - 55 Alkyl Nitrates Trade secret Trade secret 10 – 20 Aromatic Hydrocarbons Trade secret Trade secret 3 - 8 Hexan-1-ol, 2-ethyl Trade secret Trade secret 2 – 5 Naphthalene Not available 91-20-3 0.2 – 0.9 SECTION 4 - FIRST AID MEASURES As a precaution, exposure to liquids, vapors, mists and fumes should be minimized. EYE CONTACT: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice. SKIN CONTACT: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs get medical advice/attention. INHALATION: Remove person to fresh air and keep comfortable for breathing. Call a doctor. INGESTION: If swallowed, IMMEDIATELY call a doctor. Do NOT induce vomiting. SECTION 5 - FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Use water fog, alcohol-resistant foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPECIFIC HAZARDS: Vapors are heavier than air and may travel along the ground to a distant ignition source and flash back. See Section 10 for Stability and Reactivity. NOTE: EMPTY CONTAINERS CONTAIN COMBUSTIBLE VAPORS THAT CAN CAUSE FLASH FIRES OR EXPLOSIONS. CONTAINERS ARE SINGLE-TRIP CONTAINERS AND SHOULD NOT BE USED FOR ANY REASON AFTER BEING EMPTIED. DO NOT USE CUTTING TORCH Page 47 of 156 Page 47 of 156 Page 47 of 156 Page 47 of 156 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 5 of 13 EQUIPMENT OR ANY OTHER FLAME OR OTHER SOURCES OF IGNITION ON ANY EMPTY CONTAINER. PROTECTIVE EQUIPMENT AND PRECAUTIONS: Use standard protective equipment including self-contained breathing apparatus (SCBA). SECTION 6 - ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, AND EMERGENCY PROCEDURES: Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas. Eliminate all sources of ignition in the vicinity of the spill or released vapor. See Section 2 for Hazards Identification. See Section 4 for First Aid Measures. See Section 5 for Fire Fighting Information. See Section 8 for Personal Protective Equipment. SPILL CONTAINMENT AND CLEAN-UP: Eliminate potential sources of ignition. Stop leak if it can be done without risk. Dike and contain spill. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. Remove with vacuum trucks or pump to storage/salvage vessels. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly. A vapor suppressing foam may be used to reduce vapors. Local, state and federal laws and/or regulations may apply to releases and disposal of this material, as well as those materials and items employed in the clean-up releases. The user/responder will need to determine which local, state and federal laws and/or regulations are applicable. The National Response Center can be reached at 1-[PHONE REDACTED]. SECTION 7 - HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING: Avoid contact with eyes and skin. Use only with adequate ventilation. Use proper bonding and/or grounding procedures. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Keep away from ignition sources such as heat, sparks, and flames. No smoking. CONDITIONS FOR SAFE STORAGE: DO NOT USE OR STORE near heat, sparks, or flame. USE AND STORE ONLY IN A WELL-VENTILATED AREA. Handle containers with care. Keep container closed when not in use. Store locked up. STORAGE TEMPERATURE: Treatment Ratio Part Numbers: Storage Temperature: 1:400 Treatment Ratio 1016-06, 1016-09, 1025-06, 1025-12, 1080-06, 11016-06, 11016-09, 11025-06, 11025-12, 11041-04, 11080-06 -20F to 104F (-29C to 40C) 1:1,000 Treatment Ratio 1000, 1128-04, 1060-01 0F to 104F (-18C to 40C) Page 48 of 156 Page 48 of 156 Page 48 of 156 Page 48 of 156 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 6 of 13 1:1,500 Treatment Ratio 1050-02, 1055-01, 1260-01 10F to 104F (-12C to 40C) EMPTY CONTAINER WARNING: EMPTY CONTAINERS MAY CONTAIN COMBUSTIBLE VAPORS AND CAN BE DANGEROUS. SEE SECTION 5 FOR FIRE AND EXPLOSION HAZARD DATA. SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES: CAS # OSHA ACGIH NIOSH PEL TLV STEL REL STEL IDLH Note 100-41-4 100 ppm 20 ppm not est. 100 ppm 125 ppm 800 ppm (LEL) n/a Naphthalene 91-20-3 10 ppm 10 ppm not est. 10 ppm 15 ppm 250 ppm skin Petroleum Distillates n/a 500 ppm not est. not est. not est. not est. not est. n/a Cumene 98-82-8 50 ppm 50 ppm not est. 50 ppm not est. 900 ppm (LEL) Skin Toluene 108-88-3 100 ppm 20 ppm not est. 100 ppm 150 ppm 500 ppm Skin Hydroxy Alkoxylate Proprietary 50 ppm 20 ppm not est. 5 ppm not est. not est. skin ENGINEERING CONTROLS: The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Local exhaust ventilation is recommended to control exposure. PERSONAL PROTECTIVE EQUIPMENT (PPE): Eyes and Face: Eye protection such as safety glasses or chemical goggles is recommended if contact is likely. Skin: Protective chemical/oil resistant gloves are recommended. Wear additional protective clothing as appropriate. Respiratory: Wear a NIOSH/MSHA approved respirator as necessary. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Practice good housekeeping. NOTE: These precautions are for room temperature handling. Page 49 of 156 Page 49 of 156 Page 49 of 156 Page 49 of 156 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 7 of 13 SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Appearance Liquid, brown Liquid, brown Liquid, brown Odor Aromatic solvent Aromatic solvent Aromatic solvent Odor Threshold Not available Not available Not available pH 7 – 8 basic) 7 – 8 basic) 7 – 8 basic) Melting point/Freezing point Not available Not available Not available Initial Boiling Point and Boiling Range 300F (149C) 300F (149C) 300F (149C) Flash Point 105F (40.5C) 116F (46.6C) 121F (49.4C) Evaporation Rate Not available Not available Not available Flammability Not available Not available Not available Upper / lower Flammability or Explosive Limits Not available Not available Not available Vapor Pressure 0.2 – 0.95 0.2 – 0.95 0.2 – 0.95 Vapor Density >5.0 >5.0 >5.0 Relative Density/Specific Gravity (at 60°F) 0.910 0.912 0.896 Solubility Not available Not available Not available Partition Coefficient; n-octanol / water Not available Not available Not available Auto-ignition Temperature Not available Not available Not available Decomposition temperature Not available Not available Not available Viscosity Not available Not available Not available Pour Point -55F (-13C) -30F (1.1C) -15F (9.4C) SECTION 10 - STABILITY AND REACTIVITY REACTIVITY: see Incompatible Materials below CHEMICAL STABILITY: This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. POSSIBILITY OF HAZARDOUS REACTION: Hazardous polymerization will not occur. CONDITIONS TO AVOID: Flames, high energy ignition sources, and elevated temperatures. INCOMPATIBLE MATERIALS: May react with strong oxidizing agents, such as; chlorates, nitrates, peroxides, nitrogen oxides, sulfur oxides, etc.; alkalis; nitric acid; sulfuric acid; aluminum; brass; copper; reducing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon oxides, products of incomplete combustion. Page 50 of 156 Page 50 of 156 Page 50 of 156 Page 50 of 156 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 8 of 13 SECTION 11 - TOXICOLOGICAL INFORMATION LIKELY ROUTES OF EXPOSURE INGESTION INHALATION SKIN CONTACT EYE CONTACT SKIN ABSORPTION 1:400 Treatment Ratio X X X X 1:1000 Treatment Ratio X X X X 1:1500 Treatment Ratio X X X X RELATED TO PHYSICAL, CHEMICAL AND TOXICOLOGICAL CHARACTERISTICS: Breathing of high vapor concentrations may cause dizziness, light- headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness. The vapor or fumes from this material may cause respiratory irritation. Breathing this material at elevated concentrations causes central nervous system effects. Central nervous system effects may include headache, dizziness, nausea, vomiting, weakness, loss of coordination, blurred vision, drowsiness, confusion or disorientation. At extreme exposures, central nervous system effects may include respiratory depression, tremors, or convulsions, loss of consciousness, coma or death. DELAYED AND IMMEDIATE EFFECTS AND CHRONIC EFFECTS FROM SHORT- AND LONG-TERM EXPOSURE: Repeated skin exposure to a component of this product may cause irritation, even a burn; may cause a more severe response on covered skin, such as under clothing or gloves. Inhalation exposure to a component of this product has caused fetotoxicity in the presence of maternal toxicity in animals. NUMERICAL MEASURES OF TOXICITY Note: the information provided below are estimates; testing of the product is not available. Treatment Ratio Acute Oral Toxicity (ATEmix estimate) Acute Dermal Toxicity (ATEmix estimate) Acute Inhalation (ATEmix estimate) 1:400 Treatment Ratio Does not meet criteria Does not meet criteria 7.10 (vapors) 1:1,000 Treatment Ratio Does not meet criteria Does not meet criteria 8.56 (vapors) 1:1,500 Treatment Ratio Does not meet criteria Does not meet criteria 7.48 (vapors) SENSITIZATION: No information available. MUTAGENICITY: No information available. CARCINOGENICITY LISTINGS – the following chemicals are listed as indicated: Page 51 of 156 Page 51 of 156 Page 51 of 156 Page 51 of 156 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 9 of 13 Chemical List Cumene IARC, NTP IARC Naphthalene IARC, NTP REPODUCTIVE TOXICITY: No information available. TERATOGENICITY/EMBRYOTOXICITY: Hydroxy Alkoxylate has caused fetotoxicity with maternal toxicity. This product contains a component of a complex mixture (Xylenes (1330-20- that has been shown to cause teratogenicity and/or embryotoxicity. SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): Respiratory tract irritation, drowsiness/dizziness. SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): No information available ASPIRATION HAZARD: Aspiration hazard identified. SECTION 12 - ECOLOGICAL INFORMATION ECOTOXICITY: This material is expected to be toxic to aquatic organisms. PERSISTENCE AND DEGRADABILITY: No information available. BIOACCUMULATIVE POTENTIAL: No information available. MOBILITY IN SOIL: No information available. OTHER ADVERSE EFFECTS: No information available. SECTION 13 - DISPOSAL CONSIDERATIONS RCRA Information: Disposal of unused product may be subject to RCRA hazardous waste regulations (40 CFR Part 261). Disposal of the used product may also be regulated as hazardous waste due to resulting mixture characteristics, mixture components or product use. Such changes to the product may result in different and/or additional hazardous waste codes. Potential RCRA waste code based on the product as shipped: D001 IGNITABILITY State or local laws may impose additional regulatory requirements regarding disposal. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. EMPTY CONTAINER WARNING: EMPTY CONTAINERS MAY CONTAIN COMBUSTIBLE VAPORS AND CAN BE DANGEROUS. SEE SECTION 5 FOR FIRE AND EXPLOSION Page 52 of 156 Page 52 of 156 Page 52 of 156 Page 52 of 156 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 10 of 13 HAZARD DATA. Dispose or recycle empty containers appropriately per local, state and federal regulations. SECTION 14 - TRANSPORTATION INFORMATION The following part numbers are not regulated by DOT: 1:400 Treatment Ratio 1016-06, 1016-09, 1025-06, 1025-09, 1025-12, 1080-06, 11016-06, 11016-09, 11025-06, 11025-12, 1080-06 1:1,000 Treatment Ratio 1128-04 1:1,500 Treatment Ratio 1050-02, 1055-01 The following part numbers are regulated by DOT: 1:1,000 Treatment Ratio 1060-01 PROPER SHIPPING NAME: Combustible Liquid, N.O.S., (Petroleum Distillates) Marine Pollutant Nitrate) HAZARD CLASS: Combustible Liquid I.D. NUMBER: NA 1993 PACKING GROUP: III PLACARDING: Combustible Liquid MARINE POLLUTANT: Yes 1:1,000 Treatment Ratio 1000 PROPER SHIPPING NAME: Combustible Liquid, N.O.S., (Petroleum Distillates) Marine Pollutant Nitrate) RQ (Xylene, Naphthalene) HAZARD CLASS: Combustible Liquid I.D. NUMBER: NA 1993 PACKING GROUP: III PLACARDING: Combustible Liquid MARINE POLLUTANT: Yes PRODUCT RQ: 100 lbs. (45.45 kg) – Xylene, Naphthalene 1:1,500 Treatment Ratio 1260-01 PROPER SHIPPING NAME: Combustible Liquid, N.O.S., (Petroleum Distillates) Marine Pollutant Nitrate) HAZARD CLASS: Combustible Liquid I.D. NUMBER: NA 1993 PACKING GROUP: III PLACARDING: Combustible Liquid MARINE POLLUTANT: Yes Page 53 of 156 Page 53 of 156 Page 53 of 156 Page 53 of 156 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 11 of 13 SECTION 15 - REGULATORY INFORMATION §14(a) Consumer Product Safety Act General Certificate of Conformity Power Service Products, Inc. certifies that this product meets the statutory and regulatory requirements of the US Consumer Products Safety Act, the Federal Hazardous Substances Act, and the Poison Prevention Packaging Act of 1970, as applicable. The Power Service products are manufactured in the United States in Weatherford, Texas, unless otherwise indicated on the product label. The product manufacture lot code is stamped on the product container. This Certification is based upon a reasonable testing program conducted by Power Service Products, Inc. which includes a quality control program incorporating, as necessary, confirmation of compliance by component suppliers. Third-party testing is not required to certify compliance. Further details may be obtained by contacting the Power Service Products, Inc. EHS Manager at 1-[PHONE REDACTED]. Contents of this SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. TSCA STATUS: All chemical substances found in this product comply with the Toxic Substances Control Act inventory reporting requirements. EPA SARA TITLE III CHEMICAL LISTINGS: Section 302 Extremely Hazardous Substances: None Sections 311/ 312 Hazard Class: Acute Health Effects: Yes Sudden Release of Pressure Hazard: No Chronic Health Effects: Yes Reactivity Hazard: No Fire Hazard: Yes NFPA (NATIONAL FIRE PROTECTION ASSOCIATION) RATING: HEALTH: 2 FIRE: 2 REACTIVITY: 0 Section 313: Specific chemical information is being withheld as a Trade Secret. The following chemicals subject to the reporting requirements of EPCRA Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (40 CFR Part 372) may be present in this product at a concentration that does not exceed the specified upper weight percentage. Treatment Ratio CAS Number Chemical Name Max % 1:400 Treatment Ratio 100-41-4 24.0 NA Glycol Ether Category 8.0 Page 54 of 156 Page 54 of 156 Page 54 of 156 Page 54 of 156 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 12 of 13 Treatment Ratio CAS Number Chemical Name Max % 91-20-3 Naphthalene 1.0 98-82-8 Cumene 4.0 108-88-3 Toluene 4.0 1:1000 Treatment Ratio 100-41-4 19.0 91-20-3 Naphthalene 1.0 98-82-8 Cumene 3.5 108-88-3 Toluene 3.5 1:1,500 Treatment Ratio 100-41-4 12.0 91-20-3 Naphthalene 1.0 98-82-8 Cumene 2.0 108-88-3 Toluene 2.0 State or local laws may impose additional regulatory requirements for components of this material. It is the responsibility solely of the Employer to maintain compliance with State and Local reporting. This product contains a chemical known to the state of California to cause cancer and/or birth defects or other reproductive harm: toluene, cumene, naphthalene. SECTION 16 – OTHER INFORMATION DATE OF PREPARATION / REVISION: May 30, 2015 NOTE regarding product labeling: The OSHA Hazard Communication Standard applies to hazardous chemicals known to be present in the workplace. However, the labeling and Safety Data Sheet requirements do not apply to consumer products when they are used in the workplace for the purposes intended by the manufacturer and the use results in a duration and frequency of exposure which is not greater than the range of exposures that could reasonably be experienced by consumers when used for the intended purpose. Power Service Products intends for product packaged in 1 gallon or smaller containers to be used by consumers and has labeled those containers as required under the Consumer Product Safety Commission regulations. Power Service Products intends for product packaged in containers larger than 1 gallon to be used in the workplace and has labeled those products as required by the OSHA Hazard Communication Standard. The Consumer Product Safety Commission and OSHA Hazard Communication Standard labeling requirements are different and variations between the consumer and industrial labels may occur. It is the employer’s responsibility to purchase the appropriate product for use in the workplace. The information contained herein is offered in good faith and is believed to be accurate based on the data available to us as of the date of SDS preparation. The information in this document applies to this specific product as supplied. It may not be appropriate for this product if the product is used in combination with other materials. The information in this document is not intended to constitute product performance information. Some of the information presented and conclusions drawn herein are from sources other than direct test data on the product. No statement shall be construed as an endorsement of any product or process. The recommended Page 55 of 156 Page 55 of 156 Page 55 of 156 Page 55 of 156 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 13 of 13 industrial hygiene and safe handling procedures are believed to be valid in the context of the intended use as described in product labeling. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate. You are urged to obtain material safety data sheets for all products you buy, process, use or distribute, and are encouraged to advise those who may come in contact with such products of the information contained therein. Regulatory requirements are subject to change and may differ between locations. It is the buyer’s/user’s responsibility to ensure that his activities comply with all federal, state, provincial or local laws. No warranty or guarantee is expressed or implied with respect to this product, the accuracy and sufficiency of the data or recommendations herein, or the results to be obtained from the use of this product. IN NO EVENT SHALL POWER SERVICE PRODUCTS, INC. BE LIABLE FOR ANY LOSS, CLAIM, DAMAGE OR LIABILITY OF ANY KIND, WHICH MAY ARISE FROM OR IN CONNECTION WITH THE INFORMATION CONTAINED IN THIS DOCUMENT OR FROM THE USE, HANDLING OR STORAGE OF THE PRODUCT BY THE BUYER/USER, WHETHER DIRECT, INDIRECT, OR CONSEQUENTIAL, OR FOR ANY CLAIM BY ANY THIRD PARTY, BEYOND THE PURCHASE PRICE OR REPLACEMENT OF THE PRODUCT IN CONNECTION WITH WHICH SUCH LOSS, CLAIM, DAMAGE OR LIABILITY AROSE. THE FOREGOING LIMITATIONS APPLY REGARDLESS OF THE CAUSES OR CIRCUMSTANCES GIVING RISE TO SUCH LOSS, CLAIM, DAMAGE OR LIABILITY, EVEN IF SUCH LOSS, CLAIM, DAMAGE, OR LIABILITY IS BASED ON NEGLIGENCE OR OTHER TORTS OR BREACH OF CONTRACT. Page 56 of 156 Page 56 of 156 Page 56 of 156 Page 56 of 156 ---PAGE BREAK--- Material Safety Data Sheet Page 1 of 7 Section 1: Product & Company Identification Product Name: Dry Moly Lube Product Number 73084 Product Use: Dry film lubricant Manufacturer / Supplier Contact Information: In United States: In Canada: CRC Industries, Inc. CRC Canada Co. 885 Louis Drive 2-1246 Lorimar Drive Warminster, PA 18974 Mississauga, Ontario L5S 1R2 www.crcindustries.com www.crc-canada.ca 1-[PHONE REDACTED] (General) 1-[PHONE REDACTED] (800) 521-3168 (Technical) (800) 272-4620 (Customer Service) 24-Hr Emergency – CHEMTREC: (800) 424-9300 or (703) 527-3887 Section 2: Hazards Identification Emergency Overview DANGER: Extremely Flammable. Harmful or Fatal if Swallowed. Eye and Skin Irritant. Contents Under Pressure. Appearance & Odor: Dark viscous liquid, solvent odor Potential Health Effects: ACUTE EFFECTS: EYE: May cause eye irritation, including redness, itching or burning sensation. SKIN: Prolonged or repeated exposure may cause irritation. of overexposure include redness, itching and burning of skin. INHALATION: May cause irritation of the upper respiratory system or nervous system depression (headache, dizziness, nausea and loss of coordination). Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Ingestion of aerosol product is not expected during normal use. CHRONIC EFFECTS: Prolonged overexposure may cause adverse effects to the liver and urinary systems. TARGET ORGANS: liver and urinary systems Medical Conditions Aggravated by Exposure: Unknown See Section 11 for toxicology and carcinogenicity information on product ingredients. Page 57 of 156 Page 57 of 156 Page 57 of 156 Page 57 of 156 ---PAGE BREAK--- Product Name: Dry Moly Lube Product Number 73084 Page 2 of 7 Section 3: Composition/Information on Ingredients COMPONENT CAS NUMBER % by Wt. Propane 74-98-6 5 - 15 Butane 106-97-8 15 - 25 Heptane 142-82-5 3 - 8 Mineral Spirits 64742-88-7 1 - 5 2-Propanol 67-63-0 20 - 30 Acetone 67-64-1 30 - 40 Molybdenum Disulfide 1317-33-5 1 - 5 Section 4: First Aid Measures Eye Contact: Immediately flush with plenty of water for 15 minutes. Call a physician if irritation persists. Skin Contact: Remove contaminated clothing and wash affected area with soap and water. Call a physician if irritation persists. Wash contaminated clothing prior to re-use. Inhalation: Remove person to fresh air. Keep person calm. If not breathing, give artificial respiration. If breathing is difficult give oxygen. Call a physician. Ingestion: Do NOT induce vomiting. Get medical attention immediately. Note to Physicians: Treat Section 5: Fire-Fighting Measures Flammable Properties: This product is extremely flammable in accordance with aerosol flammability definitions. Flash Point: < 0°F / -17.8°C Upper Explosive Limit: ND Autoignition Temperature: ND Lower Explosive Limit: ND Fire and Explosion Data: Suitable Extinguishing Media: Carbon dioxide, dry chemical, foam Products of Combustion: Carbon dioxide and carbon monoxide Explosion Hazards: Aerosol containers, when exposed to heat from fire, may build pressure and explode. Vapors may accumulate in a confined space and create a flammable atmosphere. Protection of Fire-Fighters: Firefighters should wear self-contained, NIOSH-approved breathing apparatus for protection against suffocation and possible toxic decomposition products. Proper eye and skin protection should be provided. Use water spray to keep fire-exposed containers cool and to knock down vapors which may result from product decomposition. Section 6: Accidental Release Measures Personal Precautions: Use personal protection recommended in Section 8. Environmental Precautions: Take precautions to prevent contamination of ground and surface waters. Do not flush into Page 58 of 156 Page 58 of 156 Page 58 of 156 Page 58 of 156 ---PAGE BREAK--- Product Name: Dry Moly Lube Product Number 73084 Page 3 of 7 sewers or storm drains. Methods for Containment & Clean-up: Remove all sources of ignition. Dike area to contain spill. Ventilate the area with fresh air. If in confined space or limited air circulation area, clean-up workers should wear appropriate respiratory protection. Recover or absorb spilled material using an absorbent designed for chemical spills. Place used absorbents into proper waste containers. Section 7: Handling and Storage Handling Procedures: Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilate. Do not smoke. Extinguish all flames, pilot lights, and heaters. Turn off stoves, electronic tools and other appliances, and any other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. For product use instructions, please see the product label. Storage Procedures: Store in a cool dry area out of direct sunlight. Aerosol cans must be maintained below 120°F / 48.9°C to prevent cans from rupturing. Store out of reach of children Aerosol Storage Level: III Section 8: Exposure Controls/Personal Protection Exposure Guidelines: OSHA ACGIH OTHER COMPONENT TWA STEL TWA STEL TWA SOURCE UNIT Propane 1000 NE 1000 NE NE ppm Butane 800 NE 1000 NE NE ppm Heptane 500 NE 400 500 NE ppm Mineral Spirits NE NE NE NE NE 2-Propanol 400 NE 200 400 NE ppm Acetone 1000 NE 500 750 NE ppm Molybdenum Disulfide NE NE 10 NE NE mg/m3 N.E. – Not Established – ceiling – skin – vacated Controls and Protection: Engineering Controls: Area should have ventilation to provide fresh air. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at the source, preventing dispersion into the general work area. Use mechanical means if necessary to maintain vapor levels below the exposure guidelines. If working in a confined space, follow applicable OSHA regulations. Respiratory Protection: None required for normal work where adequate ventilation is provided. If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with organic vapor cartridge. Air monitoring is needed to determine actual employee exposure levels. Use a self-contained breathing apparatus in confined spaces and for emergencies. Eye/face Protection: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear splash-proof goggles. Page 59 of 156 Page 59 of 156 Page 59 of 156 Page 59 of 156 ---PAGE BREAK--- Product Name: Dry Moly Lube Product Number 73084 Page 4 of 7 Skin Protection: Use protective gloves such as nitrile or neoprene. Also, use full protective clothing if there is prolonged or repeated contact of liquid with skin. Section 9: Physical and Chemical Properties Physical State: liquid Color: charcoal color Odor: solvent odor Odor Threshold: ND Specific Gravity: 0.71 Initial Boiling Point: ND Freezing Point: ND Vapor Pressure: ND Vapor Density: > 1 (air = 1) Evaporation Rate: fast Solubility: NA Coefficient of water/oil distribution: NA pH: ND Volatile Organic Compounds: wt 61.8 g/L: 438.78 lbs./gal: 3.66 Section 10: Stability and Reactivity Stability: Stable Conditions to Avoid: Sources of ignition; temperature extremes Incompatible Materials: None known Hazardous Decomposition Products: Carbon dioxide and carbon monoxide Possibility of Hazardous Reactions: No Section 11: Toxicological Information Long-term toxicological studies have not been conducted for this product. The following information is available for components of this product. Acute Toxicity: Component Oral LD50 (rat) Dermal LD50 (rabbit) Inhalation LC50 (rat) Propane No data No data No data Butane No data No data 658,000 mg/m3/4H Heptane No data No data 103 g/m3/4H Mineral Spirits > 2000 mg/kg > 2000 mg/kg No data 2-Propanol 5000 mg/kg 12,800 mg/kg 16,000 ppm/8H Acetone 5800 mg/kg No data 50,100 mg/m3/8H Molybdenum Disulfide No data No data > 2820 mg/m3/4H Chronic Toxicity: Component OSHA Carcinogen IARC Carcinogen NTP Carcinogen Irritant Sensitizer Propane No No No No No Butane No No No No No Heptane No No No E (mild) / S (moderate) / R (mild) Unknown Page 60 of 156 Page 60 of 156 Page 60 of 156 Page 60 of 156 ---PAGE BREAK--- Product Name: Dry Moly Lube Product Number 73084 Page 5 of 7 Mineral Spirits No No No E (mild) / S (moderate) / R (mild) Unknown 2-Propanol No No No E (moderate) / S (mild) No Acetone No No No E (moderate) / S (moderate) / R (mild) Yes Molybdenum Disulfide No No No E (mild) / S (mild) / R (mild) Unknown Reproductive Toxicity: No information available Teratogenicity: No information available Mutagenicity: No information available Synergistic Effects: No information available Section 12: Ecological Information Ecological studies have not been conducted for this product. The following information is available for components of this product. Ecotoxicity: Acetone – 48H LC50 Daphnia: 10 mg/l Persistence / Degradability: No information available Bioaccumulation / Accumulation: No information available Mobility in Environment: No information available Section 13: Disposal Considerations Waste Classification: The dispensed liquid product is a hazardous waste for the characteristic of ignitability with a waste code of D001. Empty aerosol containers may be recycled. All disposal activities must comply with federal, state, provincial and local regulations. Local regulations may be more stringent than state, provincial or national requirements. Section 14: Transport Information US DOT (ground): UN1950, Aerosols, flammable, 2.1, Limited Quantity ICAO/IATA (air): UN1950, Aerosols, flammable, 2.1, Limited Quantity IMO/IMDG (water): UN1950, Aerosols, 2.1, Limited Quantity Special Provisions: None Section 15: Regulatory Information U.S. Federal Regulations: Toxic Substances Control Act (TSCA): All ingredients are either listed on the TSCA inventory or are exempt. E – Eye S – Skin R - Respiratory Page 61 of 156 Page 61 of 156 Page 61 of 156 Page 61 of 156 ---PAGE BREAK--- Product Name: Dry Moly Lube Product Number 73084 Page 6 of 7 Comprehensive Environmental Response, Compensation and Liability Act (CERCLA): Reportable Quantities (RQ’s) exist for the following ingredients: Acetone (5,000 lbs) Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center ([PHONE REDACTED]) and to your Local Emergency Planning Committee. Superfund Amendments Reauthorization Act (SARA) Title III: Section 302 Extremely Hazardous Substances (EHS): None Section 311/312 Hazard Categories: Fire Hazard Yes Reactive Hazard No Release of Pressure Yes Acute Health Hazard Yes Chronic Health Hazard No Section 313 Toxic Chemicals: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: None Clean Air Act: Section 112 Hazardous Air Pollutants (HAPs): None Canadian Regulations: Canadian DSL Inventory: All ingredients are either listed on the DSL Inventory or are exempt. WHMIS Hazard Class: A, B5, D2B European Union Regulations: RoHS Compliance: This product is compliant with Directive 2002/95/EC of the European Parliament and of the Council of 27 January 2003. This product does not contain any of the restricted substances as listed in Article 4(1) of the RoHS Directive. Additional Regulatory Information: None Section 16: Other Information HMIS® (II) Health: 2 Flammability: 4 Reactivity: 0 PPE: B Ratings range from 0 (no hazard) to 4 (severe hazard) NFPA Prepared By: Michelle Rudnick CRC 73084 Revision Date: 03/09/2015 Changes since last revision: Revision Date 4 0 2 Page 62 of 156 Page 62 of 156 Page 62 of 156 Page 62 of 156 ---PAGE BREAK--- Product Name: Dry Moly Lube Product Number 73084 Page 7 of 7 The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this MSDS consult your supervisor, a health & safety professional, or CRC Industries. ACGIH: American Conference of Governmental Industrial Hygienists CAS: Chemical Abstract Service CFR: Code of Federal Regulations DOT: Department of Transportation DSL: Domestic Substance List g/L: grams per Liter HMIS: Hazardous Materials Identification System IARC: International Agency for Research on Cancer IATA: International Air Transport Association ICAO: International Civil Aviation Organization IMDG: International Maritime Dangerous Goods IMO: International Maritime Organization lbs./gal: pounds per gallon LC: Lethal Concentration LD: Lethal Dose NA: Not Applicable ND: Not Determined NIOSH: National Institute of Occupational Safety & Health NFPA: National Fire Protection Association NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration PMCC: Pensky-Martens Closed Cup PPE: Personal Protection Equipment ppm: Parts per Million RoHS: Restriction of Hazardous Substances STEL: Short Term Exposure Limit TCC: Tag Closed Cup TWA: Time Weighted Average WHMIS: Workplace Hazardous Materials Information System Page 63 of 156 Page 63 of 156 Page 63 of 156 Page 63 of 156 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET FVP BAR & CHAIN OIL FOR DISCLAIMER OF LIABILITY SEE FINAL PAGE PRODUCT NAME: FVP Bar & Chain Oil SYNONYMS: Petroleum oil; Lube oil; Petroleum hydrocarbon; Lubricant PRODUCT CODE: PRODUCT USE: Bar and Chain Lubricant MANUFACTURER’S NAME: CAM2 International, LLC ADDRESS: P.O. Box 1119 Evergreen, CO 80437 Tel: [PHONE REDACTED] EMERGENCY TELEPHONE NUMBER: UNITED STATES: 1 [PHONE REDACTED] These numbers are for emergency use only. INTERNATIONAL: 1 [PHONE REDACTED] If you desire non-emergency product information, please call phone number listed below. CUSTOMER SERVICE: [PHONE REDACTED] MSDS FORM NUMBER: 174 EMERGENCY OVERVIEW APPEARANCE Amber fluid, petroleum odor CAUTION! HEALTH HAZARDS May be harmful if swallowed. May irritate eyes and skin. POTENTIAL HEALTH EFFECTS INHALATION This product is not likely to present an inhalation hazard at normal temperatures (BREATHING): and pressures. However, when aerosolizing, misting, or heating of this product, high concentrations of generated vapor or mist may irritate the respiratory tract (nose, throat, and lungs). EYES: May cause irritation. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION SECTION 2: HAZARDS IDENTIFICATION Page 64 of 156 Page 64 of 156 Page 64 of 156 Page 64 of 156 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET FVP BAR & CHAIN OIL FOR DISCLAIMER OF LIABILITY SEE FINAL PAGE SKIN: May cause irritation. Not likely to be absorbed through the skin in harmful amounts. INGESTION (SWALLOWING): May be harmful if swallowed. May cause throat irritation, nausea, vomiting, and diarrhea. Breathing product into the lungs during ingestion or vomiting may cause lung injury and possible death. MEDICAL CONDITIONS Individuals with pre-existing respiratory tract (nose, throat, and AGGRAVETED BY lungs) eye and/or skin disorders may have increased susceptibility EXPOSURE: to the effects of exposure. CHRONIC: Prolonged or repeated inhalation of oil mist may cause oil pneumonia, lung tissue inflammation, and/or fibrous tissue formation. Prolonged or repeated eye contact may cause inflammation of the membrane lining the eyelids and covering the eyeball (conjunctivitis). Prolonged or repeated skin contact may cause drying, cracking, redness, itching, and/or swelling (dermatitis). POTENTIAL Harmful to aquatic organisms, may cause long-term adverse effects in the ENVIRONMENTAL aquatic environment. EFFECTS: Wt. Percent Component Synonym CAS # 0 - 100 Highly refined petroleum lubricating oil Lubricating oil base stock Various *1 0 - 35 Mineral oils (C16-C40) Not Available Mixture 0 - 0.2 2,6 Di-tert-butyl-p-cresol Not Available 128-37-0 Component Related Regulatory Information *1Highly refined petroleum lubricating oil contains one or more CAS numbers listed as follows: 64741-88-4, 64742-52-5, 64742-54-7, 64742-55-8, 64742-58-1, 64742-57-0, 64742-01-4, 64742-62-7, 72623-83-7. This product may be regulated, have exposure limits or other information identified as the following: Oil mist, mineral (8012-95-1). INHALATION Remove to fresh air. If not breathing, give artificial respiration. If breathing (BREATHING): is difficult, give oxygen. Oxygen should only be administered by qualified personnel. Someone should stay with victim. Get medical attention if breathing difficulty persists. EYE: If irritation or redness from exposure to vapor develops, move away from exposure into fresh air. Upon contact, immediately flush eyes with plenty of lukewarm water, holding eyelids apart, for 15 minutes. Get medical attention. SKIN: Remove affected clothing and shoes. Wash skin thoroughly with soap and water. Get medical attention if irritation or pain develops or persists. If SECTION 4: FIRST AID MEASURES SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Page 65 of 156 Page 65 of 156 Page 65 of 156 Page 65 of 156 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET FVP BAR & CHAIN OIL FOR DISCLAIMER OF LIABILITY SEE FINAL PAGE product is injected under pressure into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, a physician should immediately evaluate the individual as a medical emergency. INGESTION: Do NOT induce vomiting. Immediately get medical attention. If spontaneous (SWALLOWING) vomiting occurs, keep head below hips to avoid breathing the product into the lungs. Never give anything to an unconscious person by the mouth. NOTE TO Treat and supportively. Treatment may vary with condition PHYSICAINS: of victim and specifics of incident. FLASH POINT (METHOD USED): 293.9oF (145.5oC) (minimum) (COC) FLAMMABLE LIMITS IN AIR: Lower: Not Available Upper: Not Available AUTOIGNITION TEMPERATURE: Not available HAZARDOUS COMBUSTION PRODUCTS: Decomposition and combustion materials may be toxic. Burning may produce sulfur oxides, aldehydes, ketones, carbon monoxide and unidentified organic compounds. CONDITIONS OF Sparks or flame. Products may burn, but does not ignite FLAMMABILITY: readily. EXTINGUISHING MEDIA: Carbon dioxide, regular foam, dry chemical, water spray, or water fog. Water or foam may cause frothing. HAZARD RATING NFPA 704 HAZARD IDENTIFICATION 0= LEAST HEALTH HAZARD (BLUE) 1 1= SLIGHT FIRE HAZARD (RED) 1 2= MODERATE REACTIVITY (YELLOW) 0 3= HIGH SPECIFIC HAZARD (WHITE) 4= EXTREME FIRE FIGHTING INSTRUCTIONS: Keep storage containers cool with water spray. A positive- pressure, self-contained breathing apparatus (SCBA) and full- body protective equipment are required for fire emergencies. FIRE AND EXPLOSION Heated containers may rupture. “Empty” containers may HAZARDS: retain residue and can be dangerous. Products are not sensitive to mechanical impact or static discharge. Remove all ignition sources. Do not touch or walk through spilled product. Stop leak if you can do it without risk. Wear protective equipment and provide engineering controls as specified in Section 8: EXPOSURE CONTROLS/ PERSONAL PROTECTION. Isolate hazard area. Keep unnecessary SECTION 5: FIRE FIGHTING MEASURES SECTION 6: ACCIDENTAL RELEASE MEASURES Page 66 of 156 Page 66 of 156 Page 66 of 156 Page 66 of 156 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET FVP BAR & CHAIN OIL FOR DISCLAIMER OF LIABILITY SEE FINAL PAGE and unprotected personnel from entering. Ventilate area and avoid breathing vapor or mist. Contain spill away from surface water and sewers. Contain spill as a liquid for possible recovery, or sorb with compatible sorbent material and shovel with a clean spark-proof tool into a sealable container for disposal. Additionally, for large spills: Dike far ahead of liquid spill for collection and later disposal. HANDLING: Keep away from sparks or flame. Where flammable mixtures may be present, equipment safe for such locations should be used. Use clean tools. When transferring large volumes of product, metal containers, including trucks and tank cars, should be grounded and bonded. This product has a low vapor pressure and is not expected to present an inhalation hazard under normal temperatures and pressures. However, when aerosolizing, misting, or heating this product, do not breathe vapor or mist. Use in a well ventilated area. Avoid contact with eyes, skin, clothing and shoes. SHIPPING AND Keep container closed when not in use and during transport. Store STORING: containers in a cool, dry place. Do not pressurize, cut, weld, braze, solder, drill, or grind containers. Keep containers away from flame, sparks, static electricity, or other sources of ignition. Empty product containers may retain residue and can be dangerous. EXPOSURE GUIDELINES Component Exposure Limits Highly Refined Petroleum Lubricating Oil ACGIH: 5mg/m3 TWA (sampled by method that does not collect vapor) (related to Oil mist, mineral) 10 mg/m3 STEL (sampled by method that does not collect vapor) (related to Oil mist, mineral) OSHA Final: 5 mg/m3 TWA (related to Oil mist, mineral) OSHA Vacated: 5 mg/m3 TWA (related to Oil mist, mineral) NIOSH: 5 mg/m3 TWA (related to Oil mist, mineral) 10 mg/m3 STEL (related to Oil mist, mineral) Mineral Oil ACGIH: 5mg/m3 TWA (sampled by method that does not collect vapor) (related to Oil mist, mineral) 10 mg/m3 STEL (sampled by method that does not collect vapor) (related to Oil mist, mineral) OSHA Final: 5 mg/m3 TWA (related to Oil mist, mineral) ` 2,6 Di-tert-butyl-p-cresol (128-37-0) ACGIH: 2mg/m3 (inhalable fraction and vapor) OSHA: 10 mg/m3 TWA NIOSH: 10 mg/m3 TWA ENGINEERING Provide general ventilation needed to maintain concentration of vapor or CONTROLS: mist below applicable exposure limits. Where adequate general ventilation is unavailable, use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below applicable exposure limits. SECTION 7: HANDLING AND STORAGE SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Page 67 of 156 Page 67 of 156 Page 67 of 156 Page 67 of 156 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET FVP BAR & CHAIN OIL FOR DISCLAIMER OF LIABILITY SEE FINAL PAGE PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY No respiratory protection is normally required. Use NIOSH-certified P- or R- PROTECTION: series particulate filter and organic vapor cartridges when concentration of vapor or mist exceeds applicable exposure limits. Protection provided by air purifying respirators is limited. Do not use N-rated respirators. Selection and use of respiratory protective equipment should be in accordance in the USA with OSHA General Industry Standard 29 CFR 1910.134; or in Canada with CSA Standard Z94.4. Consult a qualified Industrial Hygienist or Safety Professional for respirator selection guidance. EYE PROTECTION: Where eye contact is likely, wear safety glasses; contact lens use is not recommended. SKIN Where skin contact is likely, wear neoprene, nitrile or equivalent protective PROTECTION: gloves; use of natural rubber or equivalent gloves is not recommended. When product is heated and skin contact is likely, wear heat-insulating gloves, boots, and other protective clothing. To avoid prolonged or repeated contact where spills and splashes are likely, wear appropriate chemical-resistant face shield, boots, apron, coveralls, long sleeve shirts, or other protective clothing. PERSONAL Use good personal hygiene. Wash thoroughly with soap and water after HYGIENE: handling product and before eating, drinking, or using tobacco products. Clean affected clothing, shoes, and protective equipment before reuse. Discard leather articles, such as shoes, saturated with these products. OTHER Where spills and splashes are likely, facilities storing or using these PROTECTIVE products should be equipped with emergency eyewash and shower, EQUIPMENT: both equipped with clean water, in the immediate work area. PHYSICAL STATE, APPEARANCE Amber liquid ODOR: Petroleum odor ODOR THRESHOLD: Not available MOLECULAR WEIGHT: Not applicable SPECIFIC GRAVITY: 0.90 (Estimated) (water=1) (approximately) VAPOR DENSITY: >1 (Air = 1) VAPOR PRESSURE: less than 0.1 mm Hg at 68°F (20°C) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Page 68 of 156 Page 68 of 156 Page 68 of 156 Page 68 of 156 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET FVP BAR & CHAIN OIL FOR DISCLAIMER OF LIABILITY SEE FINAL PAGE RELATIVE DENSITY: 0.90 (15.5°C) INITIAL BOILING POINT: High BOILING RANGE Not available FREEZING/MELTING POINT: Not available pH: Not applicable EVAPORATION RATE: Not available SOLUBILTY IN WATER: Insoluble FLASH POINT: 293.9oF (145.5oC) (minimum) Cleveland Open Cup FLAMMABILITY: Not available FLAMMABLE LIMITS IN AIR: LOWER: Not available UPPER: Not available AUTOIGNITION TEMPERATURE: Not available STABILITY: Stable under normal temperatures and pressures. Avoid sparks, or flame. INCOMPATIBILITY: Avoid oxidizing agents. REACTIVITY: Polymerization is not known to occur under normal temperatures and pressures. Not reactive with water. HAZARDOUS None under normal temperatures and pressures. Also see Section 5: DECOMPOSITION HAZARDOUS COMBUSTION PRODUCTS. PRODUCTS: ROUTES OF EXPOSURE: ACUTE EFFECTS: REPEATED DOSE EFFECTS: Skin, Eyes, Ingestion, and Inhalation. May be harmful if swallowed. May irritate eyes and skin. May cause Throat irritation, nausea, vomiting and diarrhea. Aspiration hazard: breathing product into the lungs during ingestion or vomiting may cause lung injury and possible death. Prolonged or repeated inhalation of oil mist may cause oil pneumonia, lung tissue inflammation, and/or fibrous tissue formation. Prolonged or repeated eye contact may cause inflammation of the membrane lining the eyelids and covering the eyeball (conjunctivitis). Prolonged or repeated skin contact may cause drying, cracking, redness, itching, and/or swelling SECTION 10: STABILITY AND REACTIVITY SECTION 11: TOXICOLOGICAL INFORMATION Page 69 of 156 Page 69 of 156 Page 69 of 156 Page 69 of 156 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET FVP BAR & CHAIN OIL FOR DISCLAIMER OF LIABILITY SEE FINAL PAGE SENSITIZATION: (dermatitis). Based on best current information, there is no known human sensitization associated with this product. MUTAGENICITY: Experimental evidence suggests that this product does not cause mutagenesis. CARCINOGENICITY Based on best current information, there is no known carcinogenicity as regulated by OSHA; as categorized by ACGIH A1 or A2 substances; as categorized by IARC Group 1 Group 2A, or Group 2B agents as either known carcinogens or substances for which there is limited evidence of carcinogenicity in humans or sufficient evidence of carcinogenicity in experimental animals. REPRODUCTIVE Based on best current information, there is no known reproductive TOXICITY: toxicity associated with this product. TERATOGENICITY: Based on best current information, there is no known teratogenicity associated with this product. NEUROTOXICITY: High vapor / aerosol concentrations (attainable only at elevated temperatures) may cause central nervous system effects such as dizziness, drowsiness or headaches. TOXICITY DATA: Component Analysis – LD50/LC50 Mineral Oil Dermal LD50 Rabbit >5000 mg/kg Oral LD50 Rat >5000 mg/kg 2,6-Di-tert-butyl-p-cresol (128-37-0) Oral LD50 Rat: 890 mg/kg ECOTOXICITY: Material expected to be harmful to aquatic organisms. May cause long term adverse effects in the aquatic environment. Component Analysis – Ecotoxicity – Aquatic Toxicity 2,6-Di-tert-butyl-p-cresol (128-37-0) Test & Species 48 Hr LC50 Cryzias latipes 2.5 mg/L 72 Hr EC50 Selenastrum capricomutum 6 mg/L PERSISTENCE/ Not readily biodegradable. DEGRADABILITY: SECTION 12: ECOLOGICAL INFORMATION Page 70 of 156 Page 70 of 156 Page 70 of 156 Page 70 of 156 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET FVP BAR & CHAIN OIL FOR DISCLAIMER OF LIABILITY SEE FINAL PAGE BIOACCUMULATIVE No information available for the product. POTENTIAL: MOBILITY IN Base oil component(s) – Low solubility and floats; expected to ENVIRONMENTAL migrate from water to the land. MEDIA: OTHER ADVERSE Not available. EFFECTS: OCTANOL/WATER Not available. PARTITION COEFFICIENT: VOLATILE ORGANIC Negligible COMPOUNDS: AQUATIC RELEASE: Advise authorities if product has entered or may enter watercourses or sewer drains. DISPOSAL: Dispose in accordance with federal, state, provincial, and local regulations. Regulations may also apply to empty containers. The responsibility for proper waste disposal lies with the owner of the waste. USEPA WASTE This product, if discarded, is not expected to be a characteristic or listed CODES: hazardous waste. If recycled in the USA, it must be managed in accordance with 40 CFR Part 279. Processing, use, or contamination by user may change the waste code(s) applicable to the disposal of these products. LAND (DOT): Not regulated as a hazardous material for Land Transport. (Shipping Name) LAND (TDG): Not regulated as a dangerous good for Land Transport. (Shipping Name) EMERGENCY RESPONSE Not applicable GUIDE NUMBER: Reference North American Emergency Response Guidebook. USA REGULATIONS SARA SECTIONS Based on the ingredients listed in SECTION 3, this product does not SECTION 13: DISPOSAL CONSIDERATIONS SECTION 14: TRANSPORT INFORMATION SECTION 15: REGULATORY INFORMATION Page 71 of 156 Page 71 of 156 Page 71 of 156 Page 71 of 156 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET FVP BAR & CHAIN OIL FOR DISCLAIMER OF LIABILITY SEE FINAL PAGE 302, 304 contain any “extremely hazardous substances” listed pursuant to Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) Section 302 or Section 304 as identified in 40 CFR Part 355, Appendix A and B. SARA SECTIONS This product poses the following health hazard(s) as defined in 40 CFR Part 311 AND 312 370 and is subject to the requirements of sections 311 and 312 of Title III of REPORTING Superfund Amendments and Reauthorization Act of 1986 (SARA): Immediate (Acute) Health Hazard Yes Delayed (Chronic) Health Hazard Yes Physical Fire No Physical Sudden Release of Pressure No Physical Reactive No SARA SECTION This product does not contain chemicals subject to the supplier 313 notification requirements of the SARA 313 Toxic Release Program. CERCLA Based on the ingredients listed in SECTION 3, this product does not contain any “hazardous substances” listed pursuant to the Comprehensive Environmental Response, Compensation and Liability Act of 1980 (CERCLA) in 40 CFR Part 302, Table 302.4. TSCA: All components listed in SECTION 3 are listed on, or are exempted from the requirements. State Regulations The following Ingredients appear on the following state hazardous substances lists: Chemical Name CAS Number STATE REGULATORY LIST CITATION(S) 2,6-Di-tert-butyl –p-cresol 128-37-0 CA, MA, MN, NJ, PA, RI DATE ISSUED: March 25, 2011 SUPERSEDES: February 15, 2011 REVISION NO. 3 REVISION INFORMATION: MSDS review. LABEL/OTHER INFORMATION: Not available. MSDS FORM NUMBER: 174 SECTION 16: OTHER INFORMATION Page 72 of 156 Page 72 of 156 Page 72 of 156 Page 72 of 156 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET FVP BAR & CHAIN OIL FOR DISCLAIMER OF LIABILITY SEE FINAL PAGE The information in this Safety Sheet was obtained from sources which we believe are reliable. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESS OR IMPLIED, REGARDING ITS CORRECTNESS. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH THE HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT. This safety sheet was prepared and is to be used only for this product. If the product is used as a component in another product, this safety sheet information may not be applicable. -END OF DOCUMENT- Page 73 of 156 Page 73 of 156 Page 73 of 156 Page 73 of 156 ---PAGE BREAK--- Material Safety Data Sheet Material Name: Gold Band Chain and Bar Oil ID: GB-020 Page 1 of 5 Issue Date: 04/14/97 Revision: 1.0000 Print Date: 03/04/99 * * * Section 1 - Chemical Product and Company Identification * * * Part Number: 70 2034 (bulk) Manufacturer's Part Number: 3-02-11504; 3-02-11505; 3-09-04005 Chemical Name: NA Product Use: Chain Oil Synonyms: NA Manufacturer Information Specialty Oil Company Phone: [PHONE REDACTED] Division of Quaker State Corporation 2740 Valley View Drive Emergency # [PHONE REDACTED] CHEMTREC Shreveport, LA 71108 General Comments CHEMTREC Emergency telephone number is to be used in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals. All non-emergency questions should be directed to customer service. * * * Section 2 - Composition / Information on Ingredients * * * CAS # Component Percent 64742-52-5 Petroleum Distillates, Hydrotreated Heavy Naphthenic 100 Component Information/Information on Non-Hazardous Components All mineral oils used in this product have been severely hydrotreated and/or solvent refined. This product is considered not hazardous under 29 CFR 1910.1200 (Hazard Communication). * * * Section 3 - Hazards Identification * * * Emergency Overview Product is a non-flammable petroleum distillate mixture. Liquid and vapor may be irritating to the eyes, skin and respiratory system. Irritating and toxic vapors may be released upon combustion of product. Extinguish fire with carbon dioxide, dry chemical, foam or water fog. Hazard Statements No information is available. Potential Health Effects: Eyes This product may cause irritation to the eyes. Potential Health Effects: Skin This product may cause irritation to the skin. Prolonged and/or repeated skin contact with this product may cause irritation / dermatitis. Potential Health Effects: Ingestion Ingestion of this product may cause nausea, vomiting and diarrhea. Small amounts of this product, if aspirated into the lungs, may cause mild to severe pulmonary injury, possibly death. Potential Health Effects: Inhalation Low vapor pressure makes inhalation unlikely at standard temperatures and pressures. Inhalation of oil mists or fumes can cause irritation of the nose, throat and upper respiratory tract. Repeated and prolonged overexposure to oil mists may result in droplet deposition, oil granuloma formation, inflammation and increased incidence of infection. HMIS Ratings: Health: 1 Fire: 1 Reactivity: 0 Pers. Prot.: Safety glasses, gloves Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard * * * Section 4 - First Aid Measures * * * First Aid: Eyes Flush eyes with large amounts of water for 15 minutes. Get medical attention if eye irritation develops or persists. Page 74 of 156 Page 74 of 156 Page 74 of 156 Page 74 of 156 ---PAGE BREAK--- Material Safety Data Sheet Material Name: Gold Band Chain and Bar Oil ID: GB-020 Page 2 of 5 Issue Date: 04/14/97 Revision: 1.0000 Print Date: 03/04/99 First Aid: Skin For skin contact, wash immediately with soap and water. Remove contaminated clothing. Get medical attention if skin disorder develops. Launder contaminated clothing before reuse. First Aid: Ingestion If the material is swallowed, get immediate medical attention or advice Do not induce vomiting. First Aid: Inhalation If affected, remove individual to fresh air. If the affected person is not breathing, apply artificial respiration. Get medical attention if persist. First Aid: Notes to Physician Pulmonary aspiration hazard if swallowed; treat * * * Section 5 - Fire Fighting Measures * * * Flash Point: 425 F (218 C) Method Used: Cleveland Open Cup Upper Flammable Limit (UFL): 7% Lower Flammable Limit (LFL): 0.9% Auto Ignition: Greater than 600 F (316 C) Flammability Classification: Non-Flammable Rate of Burning: Not available General Fire Hazards Product is a non-flammable petroleum distillate mixture. Liquid can burn upon heating to temperatures at or above the flash point. If product is heated above its flash point it will release flammable vapors which can burn in the open or be explosive in confined spaces if exposed to ignition source. Mists or sprays may be flammable below its normal flash point. Hazardous Combustion Products Hazardous combustion product include fumes, smoke, sulfur oxides, aldehydes, carbon monoxide, carbon dioxide and other low molecular weight hydrocarbons. Extinguishing Media Water stream may spread fire. Use water to cool fire-exposed containers and to protect personnel. Direct water spray or foam may cause frothing and spattering. If a leak or spill has not ignited, use water spray to disperse vapors and to flush spills away from exposure. Fire Fighting Equipment/Instructions Firefighters should wear full-face, self contained breathing apparatus and impervious protective clothing. Firefighters should avoid inhaling any combustion products. NFPA Ratings:Health: 1 Fire: 1 Reactivity: 0 Other: Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * * * Section 6 - Accidental Release Measures * * * Containment Procedures Stop the flow of material, if this is without risk. Clean-Up Procedures Absorb with inert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recover using pumps. Scoop up used absorbent into drums or other appropriate container. Evacuation Procedures Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Special Procedures Eliminate all ignition sources including flares, flames and electrical sparks. Wear appropriate protective equipment and clothing during clean-up. Surfaces may become slippery after spillage. Do not allow the spilled product to enter public drainage systems or open water courses. * * * Section 7 - Handling and Storage * * * Handling Procedures Avoid getting this material into contact with your eyes. Avoid prolonged or repeated breathing of this material. Avoid prolonged or repeated skin contact with this material. Use this product with adequate ventilation. Avoid the generation of oil mists. Wash thoroughly after handling. Page 75 of 156 Page 75 of 156 Page 75 of 156 Page 75 of 156 ---PAGE BREAK--- Material Safety Data Sheet Material Name: Gold Band Chain and Bar Oil ID: GB-020 Page 3 of 5 Issue Date: 04/14/97 Revision: 1.0000 Print Date: 03/04/99 Storage Procedures Do not store this material in open or unlabeled containers. Do not store near heat, sparks, open flame or strong oxidizing agents. "Empty" containers retain product residue (liquid and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition; they may explode. * * * Section 8 - Exposure Controls / Personal Protection * * * Exposure Guidelines A: General Product Information If oil mists are generated, observe the OSHA exposure limit of 5 mg/m3; short term exposure limit of 10 mg/m3. B: Component Exposure Limits No information is available. Engineering Controls Use general ventilation and use local exhaust, where possible, in confined or enclosed spaces. Additional area ventilation or local exhaust may be required to maintain air concentrations below recommended exposure limits. PERSONAL PROTECTIVE EQUIPMENT Personal Protective Equipment: Eyes/Face Wear safety glasses with side shields. Wear chemical goggles or faceshield if splash or mist occurs. Personal Protective Equipment: Skin Use impervious gloves for prolonged contact. Wear oil-impervious garments if contact is unavoidable. Personal Protective Equipment: Respiratory If mist is generated (heating, spraying) and engineering controls are not sufficient, wear approved organic vapor respirator suitable for oil mist. Personal Protective Equipment: General Use good hygiene when handling petroleum product. Eye wash fountains are recommended. * * * Section 9 - Physical & Chemical Properties * * * Appearance: Clear to light yellow Odor: Petroleum Physical State: Liquid pH: Not available Vapor Pressure: Not available Vapor Density: Heavier than air Boiling Point: Not available Melting Point: Not applicable Solubility (H2O): Negligible Specific Gravity: 0.93 Freezing Point: Not applicable Viscosity: 145.3 cSt @ 40 C Percent Volatile: Nil Physical Properties: Additional Information Pour Point: -5 F; -21 C * * * Section 10 - Chemical Stability & Reactivity Information * * * Chemical Stability Stable Chemical Stability: Conditions to Avoid Avoid formation of mists. Incompatibility Strong oxidizing agents (peroxides, chlorine, strong acids). Hazardous Decomposition Decomposition products may include oxides of sulfur, aldehydes, carbon monoxide, carbon dioxide and other low molecular weight hydrocarbons. Hazardous Polymerization Hazardous polymerization will not occur. Page 76 of 156 Page 76 of 156 Page 76 of 156 Page 76 of 156 ---PAGE BREAK--- Material Safety Data Sheet Material Name: Gold Band Chain and Bar Oil ID: GB-020 Page 4 of 5 Issue Date: 04/14/97 Revision: 1.0000 Print Date: 03/04/99 * * * Section 11 - Toxicological Information * * * Acute Toxicity A: General Product Information No data available on the product as a whole. Based on similar materials, this product is expected to have a low order of acute oral and dermal toxicity, but minute amounts aspirated into the lungs during ingestion or vomiting may cause mild to severe pulmonary injury and possibly death. B: Component Analysis - LD50 No information is available. Carcinogenicity A: General Product Information No data available on the product as a whole. B: Component Carcinogenicity None of this product's components are listed by ACGIH, IARC, OSHA, NIOSH, or NTP. Epidemiology No data available for product. Neurotoxicity No data available on this product as a whole. Mutagenicity No data available on this product as a whole. Teratogenicity No data available for this product as a whole. Other Toxicological Information No other information available. * * * Section 12 - Ecological Information * * * Ecotoxicity No information is available on ecotoxicity of this product. Environmental Fate No information is available. Keep product out of sewers and waterways. * * * Section 13 - Disposal Considerations * * * US EPA Waste Number & Descriptions A: General Product Information Product as shipped does not meet the definition or characteristics of a hazardous waste. B: Component Waste Numbers No information is available. Disposal Instructions Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations. Material should be recycled if possible. * * * Section 14 - Transportation Information * * * US DOT Information Shipping Name: Not regulated as a hazardous material Hazard Class: Not classified UN/NA Not classified Packing Group: Not classified Required Label(s): None Additional Info.: None International Transportation Regulations Not regulated as dangerous goods. Page 77 of 156 Page 77 of 156 Page 77 of 156 Page 77 of 156 ---PAGE BREAK--- Material Safety Data Sheet Material Name: Gold Band Chain and Bar Oil ID: GB-020 Page 5 of 5 Issue Date: 04/14/97 Revision: 1.0000 Print Date: 03/04/99 * * * Section 15 - Regulatory Information * * * US Federal Regulations A: General Product Information This product may be classified as an oil under Section 311 of the Clean Water Act, and under the Oil Pollution Act. Discharges of spills into or leading to surface waters that cause sheen must be reported to the National Response Center. (1-[PHONE REDACTED]) All known (non-proprietary) components of this product are listed on the US EPA TSCA Inventory. B: Component Analysis None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix SARA Section 313 (40 CFR 372.65), or CERCLA (40 CFR 302.4). State Regulations A: General Product Information Other state regulations may apply. B: Component Analysis - State Component CAS # CA FL MA MN NJ PA No information is available. Other Regulations A: General Product Information No information available for the product. B: Component Analysis - Inventory Component CAS # TSCA DSL EINECS Petroleum Distillates, Hydrotreated Heavy Naphthenic 64742-52-5 Yes Yes Yes C: Component Analysis - WHMIS IDL No information is available. * * * Section 16 - Other Information * * * Other Information This information is, to the best of Quaker State Corporation's knowledge and belief, accurate and reliable. However, no representation, warranty, or guarantee is made to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitableness and completeness of such information for his own particular use. Preparation Information: New MSDS 04/14/1997 Key/Legend N = No; Y = Yes; ppm - parts per million; mg/m3 = milligrams per cubic meter of air; ACGIH = American Conference of Governmental Industrial Hygienists; OSHA = Occupational Safety and Health Administration; TLV = Threshold Limit Value; NIOSH = National Institute of Occupational Safety and Health; NTP = National Toxicology Program; IARC = International Agency for Research on Cancer; EPA = Environmental Protection Agency. Contact: Vince Bernard, Corporate Safety Director Contact Phone: (800) 562-5928 This is the end of MSDS # GB-020 Page 78 of 156 Page 78 of 156 Page 78 of 156 Page 78 of 156 ---PAGE BREAK--- There was a PDF conversion failure for - Product Name: Health Gards Metered Aerosols - 07913 Odor Neutralizer CAS Number: Manufacturer: HOSPECO SDS Date: 5/20/2015 To complete your binder, please link a different SDS for this product or print the SDS manually from and add to your binder. We are currently researching solutions to this issue. Thank you for your patience. Page 79 of 156 Page 79 of 156 Page 79 of 156 Page 79 of 156 ---PAGE BREAK--- Safety Data Sheet According to OSHA HCS 2012 (29 CFR 1910.1200) Section 1: Identification Product Identifier: Hydraulic AW Other means of identification: Hydraulic AW 32 Hydraulic AW 46 Hydraulic AW 68 Hydraulic AW 100 SDS Number: 778830 Intended Use: Hydraulic Fluid Uses Advised Against: All others Emergency Health and Safety Number: CHEMTREC [PHONE REDACTED] (24 Hours) CANUTEC [PHONE REDACTED] CHEMTREC Mexico 01-[PHONE REDACTED] Section 2: Hazards Identification Section 4: First Aid Measures Eye Contact: If irritation or redness develops from exposure, flush eyes with clean water. If persist, seek medical attention. Skin Contact: Remove contaminated shoes and clothing and cleanse affected area(s) thoroughly by washing with mild soap and water or a waterless hand cleaner. If irritation or redness develops and persists, seek medical attention. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician. (see Note to Physician) Inhalation (Breathing): First aid is not normally required. If breathing difficulties develop, move victim away from source of exposure and into fresh air in a position comfortable for breathing. Seek immediate medical attention. Ingestion (Swallowing): First aid is not normally required; however, if swallowed and develop, seek medical attention. Manufacturer: Phillips 66 Lubricants P.O. Box 4428 Houston, TX 77210 SDS Information: Phone: [PHONE REDACTED] Email: [EMAIL REDACTED] URL: www.Phillips66.com Customer Service: U.S.: 1-[PHONE REDACTED] or International: +1-83-2486-3363 Technical Information: 1-[PHONE REDACTED] Classified Hazards Other Hazards This material is not hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200. None Known Label Elements _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Section 3: Composition / Information on Ingredients Chemical Name CASRN Concentration¹ Distillates, petroleum, solvent-dewaxed heavy paraffinic 64742-65-0 0 - 95 Distillates, petroleum, solvent-refined heavy paraffinic 64741-88-4 0 - 75 Distillates, petroleum, hydrotreated heavy paraffinic 64742-54-7 0 - 45 Distillates, petroleum, solvent-dewaxed light paraffinic 64742-56-9 0 - 30 Non-Hazardous Materials VARIOUS <5 ¹ All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. No classified hazards 778830 - Hydraulic AW Page 1/7 Date of Issue: 08-May-2014 Status: FINAL Page 80 of 156 Page 80 of 156 Page 80 of 156 Page 80 of 156 ---PAGE BREAK--- _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 778830 - Hydraulic AW Page 2/7 Date of Issue: 08-May-2014 Status: FINAL Most important and effects, both acute and delayed: Dry skin and possible irritation with repeated or prolonged exposure. Inhalation of oil mists or vapors generated at elevated temperatures may cause respiratory irritation. Accidental ingestion can result in minor irritation of the digestive tract, nausea and diarrhea. Notes to Physician: Acute aspirations of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. When using high-pressure equipment, injection of product under the skin can occur. In this case, the casualty should be sent immediately to the hospital. Do not wait for to develop. High-pressure hydrocarbon injection injuries may produce substantial necrosis of underlying tissue despite an innocuous appearing external wound. These injuries often require extensive emergency surgical debridement and all injuries should be evaluated by a specialist in order to assess the extent of injury. Early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. Section 5: Fire-Fighting Measures NFPA 704 Hazard Class Extinguishing Media: Dry chemical, carbon dioxide, foam, or water spray is recommended. Water or foam may cause frothing of materials heated above 212°F / 100°C. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam. Specific hazards arising from the chemical Unusual Fire & Explosion Hazards: This material may burn, but will not ignite readily. If container is not properly cooled, it can rupture in the heat of a fire. Hazardous Combustion Products: Combustion may yield smoke, carbon monoxide, and other products of incomplete combustion. Oxides of sulfur, nitrogen or phosphorus may also be formed. Special protective actions for firefighters: For fires beyond the initial stage, emergency responders in the immediate hazard area should wear protective clothing. When the potential chemical hazard is unknown, in enclosed or confined spaces, a self contained breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions warrant (see Section Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Cool equipment exposed to fire with water, if it can be done safely. Avoid spreading burning liquid with water used for cooling purposes. See Section 9 for Flammable Properties including Flash Point and Flammable (Explosive) Limits Section 6: Accidental Release Measures Personal precautions, protective equipment and emergency procedures: This material may burn, but will not ignite readily. Keep all sources of ignition away from spill/release. Stay upwind and away from spill/release. Avoid direct contact with material. For large spillages, notify persons down wind of the spill/release, isolate immediate hazard area and keep unauthorized personnel out. Wear appropriate protective equipment, including respiratory protection, as conditions warrant (see Section See Sections 2 and 7 for additional information on hazards and precautionary measures. Environmental Precautions: Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems, and natural waterways. Use water sparingly to minimize environmental contamination and reduce disposal requirements. If spill occurs on water notify appropriate authorities and advise shipping of any hazard. Spills into or upon navigable waters, the contiguous zone, or adjoining shorelines that cause a sheen or discoloration on the surface of the water, may require notification of the National Response Center (phone number [PHONE REDACTED]). Health: 0 Flammability: 1 Instability: 0 0 (Minimal) 1 (Slight) 2 (Moderate) 3 (Serious) 4 (Severe) Page 81 of 156 Page 81 of 156 Page 81 of 156 Page 81 of 156 ---PAGE BREAK--- _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 778830 - Hydraulic AW Page 3/7 Date of Issue: 08-May-2014 Status: FINAL Methods and material for containment and cleaning up: Notify relevant authorities in accordance with all applicable regulations. Immediate cleanup of any spill is recommended. Dike far ahead of spill for later recovery or disposal. Absorb spill with inert material such as sand or vermiculite, and place in suitable container for disposal. If spilled on water remove with appropriate methods (e.g. skimming, booms or absorbents). In case of soil contamination, remove contaminated soil for remediation or disposal, in accordance with local regulations. Recommended measures are based on the most likely spillage scenarios for this material; however local conditions and regulations may influence or limit the choice of appropriate actions to be taken. See Section 13 for information on appropriate disposal. Section 7: Handling and Storage Precautions for safe handling: Keep away from flames and hot surfaces. Wash thoroughly after handling. Use good personal hygiene practices and wear appropriate personal protective equipment (see section Spills will produce very slippery surfaces. High pressure injection of hydrocarbon fuels, hydraulic oils or greases under the skin may have serious consequences even though no or injury may be apparent. This can happen accidentally when using high pressure equipment such as high pressure grease guns, fuel injection apparatus or from pinhole leaks in tubing of high pressure hydraulic oil equipment. Do not enter confined spaces such as tanks or pits without following proper entry procedures such as ASTM D-4276 and 29CFR 1910.146. Do not wear contaminated clothing or shoes. Conditions for safe storage: Storage temperatures above 113°F may lead to thermal decomposition, resulting in the generation of hydrogen sulfide and other sulfur containing gases. Use and store this material in cool, dry, well-ventilated area away from heat and all sources of ignition. Keep container(s) closed and properly labeled. Store only in approved containers. Keep away from any incompatible material (see Section 10). Protect container(s) against physical damage. "Empty" containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury or death. "Empty" drums should be completely drained, properly bunged, and shipped to the supplier or a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. Before working on or in tanks which contain or have contained this material, refer to OSHA regulations, ANSI Z49.1, and other references pertaining to cleaning, repairing, welding, or other contemplated operations. Section 8: Exposure Controls / Personal Protection Chemical Name ACGIH OSHA Other Distillates, petroleum, solvent-dewaxed heavy paraffinic TWA: 5mg/m3 STEL: 10 mg/m3 as Oil Mist, if Generated TWA: 5mg/m3 as Oil Mist, if Generated Distillates, petroleum, solvent-refined heavy paraffinic TWA: 5mg/m3 STEL: 10 mg/m3 as Oil Mist, if Generated TWA: 5mg/m3 as Oil Mist, if Generated Distillates, petroleum, hydrotreated heavy paraffinic TWA: 5mg/m3 STEL: 10 mg/m3 as Oil Mist, if Generated TWA: 5mg/m3 as Oil Mist, if Generated Distillates, petroleum, solvent-dewaxed light paraffinic TWA: 5mg/m3 TWA: 10 mg/m3 as Oil Mist, if Generated TWA: 5mg/m3 as Oil Mist, if Generated Note: State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or similar professional, or your local agencies, for further information. Engineering controls: If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure limits, additional engineering controls may be required. Eye/Face Protection: The use of eye protection that meets or exceeds ANSI Z.87.1 is recommended to protect against potential eye contact, irritation, or injury. Depending on conditions of use, a face shield may be necessary. Skin/Hand Protection: The use of gloves impervious to the specific material handled is advised to prevent skin contact. Users should check with manufacturers to confirm the breakthrough performance of their products. Suggested protective materials: Nitrile Page 82 of 156 Page 82 of 156 Page 82 of 156 Page 82 of 156 ---PAGE BREAK--- _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 778830 - Hydraulic AW Page 4/7 Date of Issue: 08-May-2014 Status: FINAL Respiratory Protection: Where there is potential for airborne exposure above the exposure limit a NIOSH certified air purifying respirator equipped with R or P95 filters may be used. A respiratory protection program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed whenever workplace conditions warrant a respirator's use. Air purifying respirators provide limited protection and cannot be used in atmospheres that exceed the maximum use concentration (as directed by regulation or the manufacturer's instructions), in oxygen deficient (less than 19.5 percent oxygen) situations, or under conditions that are immediately dangerous to life and health (IDLH). Suggestions provided in this section for exposure control and specific types of protective equipment are based on readily available information. Users should consult with the specific manufacturer to confirm the performance of their protective equipment. Specific situations may require consultation with industrial hygiene, safety, or engineering professionals. Section 9: Physical and Chemical Properties Note: Unless otherwise stated, values are determined at 20°C (68°F) and 760 mm Hg (1 atm). Data represent typical values and are not intended to be specifications. Section 10: Stability and Reactivity Reactivity: Not chemically reactive. Chemical stability: Stable under normal ambient and anticipated conditions of use. Possibility of hazardous reactions: Hazardous reactions not anticipated. Conditions to avoid: Extended exposure to high temperatures can cause decomposition. Avoid all possible sources of ignition. Incompatible materials: Avoid contact with strong oxidizing agents and strong reducing agents. Hazardous decomposition products: Not anticipated under normal conditions of use. Section 11: Toxicological Information Information on Toxicological Effects of Substance/Mixture Substance / Mixture Aspiration Hazard: Not expected to be an aspiration hazard. Skin Corrosion/Irritation: Causes mild skin irritation. Repeated exposure may cause skin dryness or cracking. Serious Eye Damage/Irritation: Causes mild eye irritation. Appearance: Amber, Transparent Flash Point: > 420 °F / > 216 °C Physical Form: Liquid Test Method: Cleveland Open Cup (COC), ASTM D92 Odor: Petroleum Initial Boiling Point/Range: No data Odor Threshold: No data Vapor Pressure: <1 mm Hg pH: Not applicable Partition Coefficient (n-octanol/water) (Kow): No data Vapor Density (air=1): >1 Melting/Freezing Point: < 15.8 °F / < -9 °C Upper Explosive Limits (vol % in air): No data Auto-ignition Temperature: No data Lower Explosive Limits (vol % in air): No data Decomposition Temperature: No data Evaporation Rate (nBuAc=1): No data Specific Gravity (water=1): 0.866 - 0.886 @ 60ºF (15.6ºC) Particle Size: Not applicable Bulk Density: 7.2 - 7.4 lbs/gal Percent Volatile: Negligible Viscosity: 5.3 - 10.1 cSt @ 100°C; 32 - 100 cSt @ 40°C Flammability (solid, gas): Not applicable Pour Point: 0 to 14 °F / -17.8 to -10 °C Solubility in Water: Insoluble Acute Toxicity Hazard Additional Information LC50/LD50 Data Inhalation Unlikely to be harmful >5 mg/L (mist, estimated) Dermal Unlikely to be harmful > 2 g/kg (estimated) Oral Unlikely to be harmful > 5 g/kg (estimated) Page 83 of 156 Page 83 of 156 Page 83 of 156 Page 83 of 156 ---PAGE BREAK--- _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 778830 - Hydraulic AW Page 5/7 Date of Issue: 08-May-2014 Status: FINAL Skin Sensitization: No information available on the mixture, however none of the components have been classified for skin sensitization (or are below the concentration threshold for classification). Respiratory Sensitization: No information available. Specific Target Organ Toxicity (Single Exposure): No information available on the mixture, however none of the components have been classified for target organ toxicity (or are below the concentration threshold for classification). Specific Target Organ Toxicity (Repeated Exposure): No information available on the mixture, however none of the components have been classified for target organ toxicity (or are below the concentration threshold for classification). Carcinogenicity: No information available on the mixture, however none of the components have been classified for carcinogenicity (or are below the concentration threshold for classification). Germ Cell Mutagenicity: No information available on the mixture, however none of the components have been classified for germ cell mutagenicity (or are below the concentration threshold for classification). Reproductive Toxicity: No information available on the mixture, however none of the components have been classified for reproductive toxicity (or are below the concentration threshold for classification). Information on Toxicological Effects of Components Lubricant Base Oil (Petroleum) Carcinogenicity: The petroleum base oils contained in this product have been highly refined by a variety of processes including severe hydrocracking/hydroprocessing to reduce aromatics and improve performance characteristics. All of the oils meet the IP-346 criteria of less than 3 percent PAH's and are not considered carcinogens by NTP, IARC, or OSHA. Section 12: Ecological Information Toxicity: All acute aquatic toxicity studies on samples of lubricant base oils show acute toxicity values greater than 100 mg/L for invertebrates, algae and fish. These tests were carried out on water accommodated fractions and the results are consistent with the predicted aquatic toxicity of these substances based on their hydrocarbon compositions. Persistence and Degradability: The hydrocarbons in this material are not readily biodegradable, but since they can be degraded by microorganisms, they are regarded as inherently biodegradable. Bioaccumulative Potential: Log Kow values measured for the hydrocarbon components of this material are greater than 5.3, and therefore regarded as having the potential to bioaccumulate. In practice, metabolic processes may reduce bioconcentration. Mobility in Soil: Volatilization to air is not expected to be a significant fate process due to the low vapor pressure of this material. In water, base oils will float and spread over the surface at a rate dependent upon viscosity. There will be significant removal of hydrocarbons from the water by sediment adsorption. In soil and sediment, hydrocarbon components will show low mobility with adsorption to sediments being the predominant physical process. The main fate process is expected to be slow biodegradation of the hydrocarbon constituents in soil and sediment. Other adverse effects: None anticipated. Section 13: Disposal Considerations The generator of a waste is always responsible for making proper hazardous waste determinations and needs to consider state and local requirements in addition to federal regulations. This material, if discarded as produced, would not be a federally regulated RCRA "listed" hazardous waste and is not believed to exhibit characteristics of hazardous waste. See Sections 7 and 8 for information on handling, storage and personal protection and Section 9 for physical/chemical properties. It is possible that the material as produced contains constituents which are not required to be listed in the SDS but could affect the hazardous waste determination. Additionally, use which results in chemical or physical change of this material could subject it to regulation as a hazardous waste.This material under most intended uses would become "Used Oil" due to contamination by physical or chemical impurities. Whenever possible, Recycle used oil in accordance with applicable federal and state or local regulations. Container contents should be completely used and containers should be emptied prior to discard. GHS Classification: No classified hazards Page 84 of 156 Page 84 of 156 Page 84 of 156 Page 84 of 156 ---PAGE BREAK--- _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 778830 - Hydraulic AW Page 6/7 Date of Issue: 08-May-2014 Status: FINAL Section 14: Transport Information U.S. Department of Transportation (DOT) Shipping Description: Not regulated Note: If shipped by land in a packaging having a capacity of 3,500 gallons or more, the provisions of 49 CFR, Part 130 apply. (Contains oil) International Maritime Dangerous Goods (IMDG) Shipping Description: Not regulated Note: U.S. DOT compliance requirements may apply. See 49 CFR 171.22, 23 & 25. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable International Civil Aviation Org. / International Air Transport Assoc. (ICAO/IATA) UN/ID Not regulated Note: U.S. DOT compliance requirements may apply. See 49 CFR 171.22, 23 & 24. Section 15: Regulatory Information CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs (in pounds): This material does not contain any chemicals subject to the reporting requirements of SARA 302 and 40 CFR 372. CERCLA/SARA - Section 311/312 (Title III Hazard Categories) Acute Health Hazard: No Chronic Health Hazard: No Fire Hazard: No Pressure Hazard: No Reactive Hazard: No CERCLA/SARA - Section 313 and 40 CFR 372: This material does not contain any chemicals subject to the reporting requirements of SARA 313 and 40 CFR 372. EPA (CERCLA) Reportable Quantity (in pounds): This material does not contain any chemicals with CERCLA Reportable Quantities. California Proposition 65: This material does not contain any chemicals which are known to the State of California to cause cancer, birth defects or other reproductive harm at concentrations that trigger the warning requirements of California Proposition 65. International Hazard Classification Canada: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all the information required by the Regulations. WHMIS Hazard Class: none National Chemical Inventories All components are either listed on the US TSCA Inventory, or are not regulated under TSCA. All components are either on the DSL, or are exempt from DSL listing requirements. U.S. Export Control Classification Number: EAR99 Section 16: Other Information LTD. QTY Passenger Aircraft Cargo Aircraft Only Packaging Instruction Max. Net Qty. Per Package: Page 85 of 156 Page 85 of 156 Page 85 of 156 Page 85 of 156 ---PAGE BREAK--- _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 778830 - Hydraulic AW Page 7/7 Date of Issue: 08-May-2014 Status: FINAL Guide to Abbreviations: ACGIH = American Conference of Governmental Industrial Hygienists; CASRN = Chemical Abstracts Service Registry Number; CEILING = Ceiling Limit (15 minutes); CERCLA = The Comprehensive Environmental Response, Compensation, and Liability Act; EPA = Environmental Protection Agency; GHS = Globally Harmonized System; IARC = International Agency for Research on Cancer; INSHT = National Institute for Health and Safety at Work; IOPC = International Oil Pollution Compensation; LEL = Lower Explosive Limit; NE = Not Established; NFPA = National Fire Protection Association; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration; PEL = Permissible Exposure Limit (OSHA); SARA = Superfund Amendments and Reauthorization Act; STEL = Short Term Exposure Limit (15 minutes); TLV = Threshold Limit Value (ACGIH); TWA = Time Weighted Average (8 hours); UEL = Upper Explosive Limit; WHMIS = Worker Hazardous Materials Information System (Canada) Disclaimer of Expressed and implied Warranties: The information presented in this Safety Data Sheet is based on data believed to be accurate as of the date this Safety Data Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. No responsibility is assumed for any damage or injury resulting from abnormal use or from any failure to adhere to recommended practices. The information provided above, and the product, are furnished on the condition that the person receiving them shall make their own determination as to the suitability of the product for their particular purpose and on the condition that they assume the risk of their use. In addition, no authorization is given nor implied to practice any patented invention without a license. Revised Sections or Basis for Revision: Format change; Composition (Section Physical Properties (Section Toxicological (Section 11); Regulatory information (Section 15) Date of Issue: Previous Issue Date: SDS Number: Status: 08-May-2014 13-Jul-2012 778830 FINAL Page 86 of 156 Page 86 of 156 Page 86 of 156 Page 86 of 156 ---PAGE BREAK--- KRYLON® Industrial QUIK-MARK™ Water-Based Inverted Marking Paint (Fluorescent) Pink Not available. Aerosol. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer : THE SHERWIN-WILLIAMS COMPANY KRYLON PRODUCTS GROUP Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Not applicable. 03612 03612 Product code : Product Information Telephone Number : (800) 247-3266 Regulatory Information Telephone Number : (216) 566-2902 Transportation Emergency Telephone Number : (800) 424-9300 Section 2. Hazards identification FLAMMABLE AEROSOLS - Category 1 GASES UNDER PRESSURE - Compressed gas TOXIC TO REPRODUCTION (Unborn child) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation and Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1 Classification of the substance or mixture : Signal word : Danger Hazard pictograms : Precautionary statements GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 24.5% OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Suspected of damaging the unborn child. May be fatal if swallowed and enters airways. May cause respiratory irritation. May cause drowsiness and dizziness. May cause damage to organs through prolonged or repeated exposure. : Hazard statements Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 1/13 Page 87 of 156 Page 87 of 156 Page 87 of 156 Page 87 of 156 ---PAGE BREAK--- Section 2. Hazards identification Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Pressurized container: Do not pierce or burn, even after use. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist. Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 Store in a well-ventilated place. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Hazards not otherwise classified :None known. Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do not discard empty can in trash compactor. Supplemental label elements DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue may spontaneously catch fire if improperly discarded. Immediately place rags, steel wool, other waste soaked with this product, and sanding residue in a sealed, water-filled, metal container. Dispose of in accordance with local fire regulations. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY. Section 3. Composition/information on ingredients Toluene 9.8 108-88-3 Propane 9.5 74-98-6 Med. Aliphatic Hydrocarbon Solvent 8.0 64742-88-7 Butane 4.5 106-97-8 Lt. Aliphatic Hydrocarbon Solvent 1.2 64742-89-8 Ingredient name CAS number % by weight There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification : Not available. Substance/mixture CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 2/13 Page 88 of 156 Page 88 of 156 Page 88 of 156 Page 88 of 156 ---PAGE BREAK--- Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention following exposure or if feeling unwell. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important acute and delayed Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. : Eye contact Over-exposure Skin contact Inhalation Adverse may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse may include the following: reduced fetal weight increase in fetal deaths skeletal malformations : : Eye contact : Adverse may include the following: irritation redness Potential acute health effects Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 3/13 Page 89 of 156 Page 89 of 156 Page 89 of 156 Page 89 of 156 ---PAGE BREAK--- Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Ingestion Adverse may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations : See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 4/13 Page 90 of 156 Page 90 of 156 Page 90 of 156 Page 90 of 156 ---PAGE BREAK--- Section 6. Accidental release measures Environmental precautions Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. : Precautions for safe handling Toluene OSHA PEL Z2 (United States, 2/2013). TWA: 200 ppm 8 hours. CEIL: 300 ppm AMP: 500 ppm 10 minutes. NIOSH REL (United States, 10/2013). TWA: 100 ppm 10 hours. TWA: 375 mg/m³ 10 hours. STEL: 150 ppm 15 minutes. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 5/13 Page 91 of 156 Page 91 of 156 Page 91 of 156 Page 91 of 156 ---PAGE BREAK--- Section 8. Exposure controls/personal protection STEL: 560 mg/m³ 15 minutes. ACGIH TLV (United States, 4/2014). TWA: 20 ppm 8 hours. Propane NIOSH REL (United States, 10/2013). TWA: 1000 ppm 10 hours. TWA: 1800 mg/m³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 1800 mg/m³ 8 hours. Med. Aliphatic Hydrocarbon Solvent OSHA PEL (United States, 2/2013). TWA: 100 ppm 8 hours. TWA: 400 mg/m³ 8 hours. Butane NIOSH REL (United States, 10/2013). TWA: 800 ppm 10 hours. TWA: 1900 mg/m³ 10 hours. ACGIH TLV (United States, 4/2014). STEL: 1000 ppm 15 minutes. Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 6/13 Page 92 of 156 Page 92 of 156 Page 92 of 156 Page 92 of 156 ---PAGE BREAK--- Section 8. Exposure controls/personal protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Respiratory protection : Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. 0.86 1 [Air = 1] 13.5 kPa (101.325 mm Hg) [at 20°C] Not available. Not available. Odor pH Not available. Color Evaporation rate 2 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup] Not available. 7 Viscosity Kinematic (room temperature): <0.07 cm2/s cSt) Kinematic (40°C (104°F)): <0.07 cm2/s cSt) Not available. Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Lower: 0.9% Upper: 9.5% Decomposition temperature : Not available. Type of aerosol : Spray Heat of combustion : 0.0000132 kJ/g Aerosol product Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 7/13 Page 93 of 156 Page 93 of 156 Page 93 of 156 Page 93 of 156 ---PAGE BREAK--- Section 11. Toxicological information Acute toxicity Toluene LC50 Inhalation Vapor Rat 49 g/m³ 4 hours LD50 Oral Rat 636 mg/kg - Butane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours Product/ingredient name Result Species Dose Exposure Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Irritation/Corrosion Toluene Eyes - Mild irritant Rabbit - 0.5 minutes 100 milligrams - Eyes - Mild irritant Rabbit - 870 Micrograms - Eyes - Severe irritant Rabbit - 24 hours 2 milligrams - Skin - Mild irritant Pig - 24 hours 250 microliters - Skin - Mild irritant Rabbit - 435 milligrams - Skin - Moderate irritant Rabbit - 24 hours 20 milligrams - Skin - Moderate irritant Rabbit - 500 milligrams - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Specific target organ toxicity (single exposure) Toluene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Propane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Med. Aliphatic Hydrocarbon Solvent Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Butane Category 3 Not applicable. Respiratory tract Name Category Route of exposure Target organs Information on toxicological effects Classification Toluene - 3 - Product/ingredient name NTP IARC OSHA Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 8/13 Page 94 of 156 Page 94 of 156 Page 94 of 156 Page 94 of 156 ---PAGE BREAK--- Section 11. Toxicological information Specific target organ toxicity (repeated exposure) irritation and Narcotic effects Lt. Aliphatic Hydrocarbon Solvent Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Name Category Toluene Category 2 Not determined Not determined Propane Category 2 Not determined Not determined Med. Aliphatic Hydrocarbon Solvent Category 2 Not determined Not determined Butane Category 2 Not determined Not determined Lt. Aliphatic Hydrocarbon Solvent Category 2 Not determined Not determined Aspiration hazard Name Result Toluene ASPIRATION HAZARD - Category 1 Propane ASPIRATION HAZARD - Category 1 Med. Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1 Butane ASPIRATION HAZARD - Category 1 Lt. Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1 Route of exposure Target organs Information on the likely routes of exposure Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. : Eye contact related to the physical, chemical and toxicological characteristics Skin contact Inhalation Adverse may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse may include the following: reduced fetal weight increase in fetal deaths skeletal malformations : : Eye contact : Adverse may include the following: irritation redness : Not available. Potential acute health effects Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 9/13 Page 95 of 156 Page 95 of 156 Page 95 of 156 Page 95 of 156 ---PAGE BREAK--- Not available. May cause damage to organs through prolonged or repeated exposure. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : Suspected of damaging the unborn child. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Ingestion Adverse may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 4915.1 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Section 12. Ecological information Product/ingredient name Aquatic half-life Photolysis Biodegradability Toluene - - Readily Toxicity Toluene Acute EC50 12500 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 11600 µg/l Fresh water Crustaceans - Gammarus pseudolimnaeus - Adult 48 hours Acute EC50 6000 µg/l Fresh water Daphnia - Daphnia magna - Juvenile (Fledgling, Hatchling, Weanling) 48 hours Acute LC50 5500 µg/l Fresh water Fish - kisutch - Fry 96 hours Chronic NOEC 1000 µg/l Fresh water Daphnia - Daphnia magna 21 days Lt. Aliphatic Hydrocarbon Solvent Acute LC50 >100000 ppm Fresh water Fish - mykiss 96 hours Product/ingredient name Species Result Exposure Persistence and degradability Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 10/13 Page 96 of 156 Page 96 of 156 Page 96 of 156 Page 96 of 156 ---PAGE BREAK--- Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Toluene - 90 low Lt. Aliphatic Hydrocarbon Solvent - 10 to 2500 high Soil/water partition coefficient (KOC) : Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. : Disposal methods Section 14. Transport information AEROSOLS 2.1 - AEROSOLS 2.1 - UN1950 UN1950 Special provisions LIMITED QUANTITY Emergency schedules (EmS) LIMITED QUANTITY, F-D, S-U DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards No. No. TDG Classification UN1950 AEROSOLS 2.1 - No. Special provisions LIMITED QUANTITY Mexico Classification UN1950 AEROSOLS 2.1 - No. Special provisions (ERG#126) IATA UN1950 AEROSOLS, flammable 2.1 - No. Special provisions LIMITED QUANTITY Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 11/13 Page 97 of 156 Page 97 of 156 Page 97 of 156 Page 97 of 156 ---PAGE BREAK--- Section 14. Transport information Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Not available. : Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. Section 15. Regulatory information U.S. Federal regulations : WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 State regulations Section 16. Other information Notice to reader Hazardous Material Information System 2 2 0 Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 12/13 Page 98 of 156 Page 98 of 156 Page 98 of 156 Page 98 of 156 ---PAGE BREAK--- Section 16. Other information It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Date of issue/Date of revision : 3/13/2015. Date of previous issue : No previous validation. Version : 1 13/13 Page 99 of 156 Page 99 of 156 Page 99 of 156 Page 99 of 156 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Product identifier MAGNESIUM CHLORIDE, HEXAHYDRATE, BIO-REFINED ™ Other means of identification Product code 1919 Recommended use professional, scientific and technical activities: other professional, scientific and technical activities Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufacturer GFS Chemicals, Inc. Address P.O. Box 245 Company name Website Telephone Phone [PHONE REDACTED] Toll Free [PHONE REDACTED] Fax [PHONE REDACTED] Emergency phone number Emergency Assistance Chemtrec [PHONE REDACTED] E-mail United States Powell, OH 43065 2. Hazard(s) identification Not classified. Physical hazards Not classified. Health hazards Category 3 Hazardous to the aquatic environment, acute hazard Environmental hazards Category 3 Hazardous to the aquatic environment, long-term hazard Not classified. OSHA defined hazards Label elements None. Hazard symbol Signal word None. Hazard statement Harmful to aquatic life. Harmful to aquatic life with long lasting effects. Precautionary statement Prevention Do not breathe mist or vapor. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Response If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If inhaled: Remove person to fresh air and keep comfortable for breathing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a POISON CENTER or doctor/physician if you feel unwell. If eye irritation persists: Get medical advice/attention. If skin irritation occurs: Get medical advice/attention. Storage Store in a well-ventilated place. Keep container closed. Store locked up. Disposal Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Substances CAS number % Chemical name Common name and synonyms 7791-18-6 MAGNESIUM CHLORIDE 100 Material name: MAGNESIUM CHLORIDE, HEXAHYDRATE, BIO-REFINED ™ Revision date: Issue date: June-16-2015 Version 01 1919 1 / 6 Page 100 of 156 Page 100 of 156 Page 100 of 156 Page 100 of 156 ---PAGE BREAK--- *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a physician if develop or persist. Skin contact Remove and isolate contaminated clothing and shoes. For minor skin contact, avoid spreading material on unaffected skin. Rinse skin with water/shower. Get medical attention if irritation develops and persists. Eye contact Rinse with water. If a contact lens is present, DO NOT delay irrigation or attempt to remove the lens. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Never give anything by mouth to a victim who is unconscious or is having convulsions. If ingestion of a large amount does occur, call a poison control center immediately. Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Get medical attention if occur. Most important acute and delayed Direct contact with eyes may cause temporary irritation. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Use extinguishing agent suitable for type of surrounding fire. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical None known. Special protective equipment and precautions for firefighters Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask. Fire fighting equipment/instructions Use water spray to cool unopened containers. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up This product is miscible in water. Stop the flow of material, if this is without risk. Avoid dust formation. Prevent product from entering drains. Following product recovery, flush area with water. Sweep up or vacuum up spillage and collect in suitable container for disposal. For waste disposal, see section 13 of the SDS. Small Dry Spills: With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. 7. Handling and storage Precautions for safe handling Provide adequate ventilation. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Store in original closed container. Keep container closed and dry. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits No exposure limits noted for ingredient(s). Material name: MAGNESIUM CHLORIDE, HEXAHYDRATE, BIO-REFINED ™ Revision date: Issue date: June-16-2015 Version 01 1919 2 / 6 Page 101 of 156 Page 101 of 156 Page 101 of 156 Page 101 of 156 ---PAGE BREAK--- Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Wear chemical goggles. Skin protection Hand protection Wear appropriate chemical resistant gloves. Other Wear suitable protective clothing. Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. In case of inadequate ventilation or risk of inhalation of dust, use suitable respiratory equipment with particle filter. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Solid. Form Solid. Color White. Odor Odorless. Odor threshold Not available. pH Not available. Melting point/freezing point 212 °F (100 (loses H20) Initial boiling point and boiling range 2573.6 °F (1412 Flash point Not available. Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Not available. Flammability limit - upper Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure Not available. Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) very soluble Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Density 1.56 g/cm3 Molecular formula MgCl2.6H2O Molecular weight 203.3 g/mol g/mol Specific gravity 1.56 Material name: MAGNESIUM CHLORIDE, HEXAHYDRATE, BIO-REFINED ™ Revision date: Issue date: June-16-2015 Version 01 1919 3 / 6 Page 102 of 156 Page 102 of 156 Page 102 of 156 Page 102 of 156 ---PAGE BREAK--- 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid Contact with incompatible materials. The substance is hygroscopic and will absorb water by contact with the moisture in the air. Incompatible materials None known. Hazardous decomposition products Chlorine. Hydrogen chloride. 11. Toxicological information Information on likely routes of exposure Inhalation No adverse effects due to inhalation are expected. Skin contact No adverse effects due to skin contact are expected. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Expected to be a low ingestion hazard. related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity Test Results Product Species MAGNESIUM CHLORIDE (CAS 7791-18-6) LD50 Rat Oral Acute 8100 mg/kg 2800 mg/kg LD50 Mouse Other 1338 mg/kg 14 mg/kg * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation May irritate eyes. Respiratory or skin sensitization Respiratory sensitization Not available. Skin sensitization None known. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not available. 12. Ecological information Ecotoxicity Harmful to aquatic life with long lasting effects. Product Test Results Species MAGNESIUM CHLORIDE (CAS 7791-18-6) Aquatic EC50 Crustacea 95 - 342 mg/l, 48 hours Calanoid copepod (Eudiaptomus padanus padanus) Material name: MAGNESIUM CHLORIDE, HEXAHYDRATE, BIO-REFINED ™ Revision date: Issue date: June-16-2015 Version 01 1919 4 / 6 Page 103 of 156 Page 103 of 156 Page 103 of 156 Page 103 of 156 ---PAGE BREAK--- Product Test Results Species * Estimates for product may be based on additional component data not shown. LC50 Fish 1580 - 2740 mg/l, 96 hours Fathead minnow (Pimephales promelas) Persistence and degradability None known. Bioaccumulative potential No data available. Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Not applicable. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Not regulated. Material name: MAGNESIUM CHLORIDE, HEXAHYDRATE, BIO-REFINED ™ Revision date: Issue date: June-16-2015 Version 01 1919 5 / 6 Page 104 of 156 Page 104 of 156 Page 104 of 156 Page 104 of 156 ---PAGE BREAK--- Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. Food and Drug Administration (FDA) Total food additive Direct food additive GRAS food additive US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. Massachusetts RTK - Substance List Not regulated. US. New Jersey Worker and Community Right-to-Know Act Not listed. US. Worker and Community Right-to-Know Law Not listed. US. Rhode Island RTK Not regulated. US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Yes Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) Yes China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) Yes Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date June-16-2015 Version # 01 Disclaimer GFS Chemicals cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. Revision Information Product and Company Identification: Product Codes Composition / Information on Ingredients: Disclosure Overrides Material name: MAGNESIUM CHLORIDE, HEXAHYDRATE, BIO-REFINED ™ Revision date: Issue date: June-16-2015 Version 01 1919 6 / 6 Page 105 of 156 Page 105 of 156 Page 105 of 156 Page 105 of 156 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Trade Name: Master Brake Parts Cleaner MSDS NO. BC20 Revision Date: 25-01-2012 Date Printed 31-05-2012 Page 1 of 4 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Trade Name: Master Brake Parts Cleaner Synonyms: None Emergency Telephone (24 hr.): CHEMTREC 1-[PHONE REDACTED] Supplier: Atlantic Pacific, Germantown, TN, 38183 2. COMPOSITION/INFORMATION ON INGREDIENTS Component Weight % OSHA TWA OSHA STEL OSHA SKIN Perchloroethylene 127-18-4 85-100 Not Listed Not Listed Not Listed Carbon Dioxide 124-38-9 0-15 Not Listed Not Listed Not Listed Component Weight % OSHA Z PEL OSHA Z TWA OSHA Z Ceiling Perchloroethylene 127-18-4 85-100 Not Listed 100 ppm 170 mg/m 3 25 ppm 200 ppm Carbon Dioxide 124-38-9 0-15 9000 mg/m 3 5000 ppm 18000 mg/m 3 10000 ppm Not Listed Component ACGIH TLV TWA ACGIH TLV STEL ACGIH TLV Ceiling Perchloroethylene 127-18-4 25 ppm 100 ppm Not Listed Carbon Dioxide 124-38-9 5000 ppm 30000 ppm Not Listed 3. HAZARDS IDENTIFICATION Emergency Overview: Content under pressure. DANGER: SUSPECTED CANCER HAZARD Harmful if inhaled. May be fatal if swallowed. Harmful if absorbed through the skin. May cause severe eye irritation. HMIS Classification: Health: *2 Flammability: 0 Physical Hazard: 2 NFPA Rating: Health: 2 Flammability: 0 Reactivity: 0 4. FIRST AID MEASURES Eye Contact: In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing. Ingestion: Get medical attention! If vomiting occurs, keep head lower than hips to prevent aspiration. If swallowed, do NOT induce vomiting. Call a physician immediately. Never give anything by mouth to an unconscious person. Inhalation: If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention. Skin Contact: Remove contaminated clothing and shoes, and launder before reuse. If irritation persists or signs of toxicity occur, seek medical attention. Wash with soap and water for 15 minutes. 5. FIRE FIGHTING MEASURES Flammable Properties Flash Point None (TCC) Flash Point Method: TAG Closed Cup Flammable Limits in Air - Lower Not Determined Flammable Limits in Air - Upper Not Determined Page 106 of 156 Page 106 of 156 Page 106 of 156 Page 106 of 156 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Trade Name: Master Brake Parts Cleaner MSDS NO. BC20 Revision Date: 25-01-2012 Date Printed 31-05-2012 Page 2 of 4 5. FIRE FIGHTING MEASURES Autoignition Temperature None Extinguishing Media: Use extinguishing media appropriate for surrounding fire. Use water spray to keep containers cool that are exposed to heat or flames. Protection Of Fire-Fighters: Special Fire-Fighting Procedures: Wear approved positive-pressure self-contained breathing apparatus and protective clothing. Avoid skin contact. Hazardous Combustion Products: Hydrogen chloride, phosgene, chlorine. Aerosol Comments: NFPA Level 1 Aerosol 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Wear appropriate protective clothing and equipment to prevent skin and eye contact. Avoid breathing vapor. When airborne exposure limits are exceeded use NIOSH approved respiratory protection equipment appropriate to the material and/or its components. Spill Procedures: Contain any liquid from leaking containers. Ventilate spill area. Soak up material with absorbent and place in chemical waste container. Avoid breathing vapors. Action to be taken if material is released or spilled: Wear proper protective equipment as specified in the protective equipment section. Leaking containers should be removed to an isolated, well-ventilated area and transferred to other suitable containers. Do not puncture or incinerate container. Contents under pressure. Environmental Precautions: Do not allow to enter sanitary drains, sewer or surface and subsurface waters. Keep out of lakes, ponds or streams. 7. HANDLING AND STORAGE Handling and Storage: Avoid breathing vapors, if exposed to high vapor concentration, leave area at once. Avoid contact with skin and eyes. Use only in a well ventilated area. Caution: Contents under pressure. Keep away from heat and open flame. Do not puncture, incinerate or store above 120 F. Exposure to high temperatures may cause bursting. DO NOT store in the passenger compartment of an automobile. This material or it's vapors in contact with flames or hot glowing surfaces may form corrosive acid fumes. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls: Local exhaust ventilation as necessary to maintain exposures to within applicable limits. Use in a well ventilated area. Eyes: Chemical goggles; also wear a face shield if splashing hazard exists. Skin Protection: Avoid skin contact. Wear protective clothing and gloves. Respiratory Protection: Use in a well ventilated area. Appropriate respiratory protection shall be worn when applied engineering controls are not adequate to protect against inhalation exposure. Do not breath mist or vapor. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear colorless liquid. Odor: FAINT SWEET pH Value: Not Determined Vapor Pressure: Approx. 13 mm Hg @20C Vapor Density (Air=1): 4.1 Approximate Boiling Point 250 F Melting/Freezing Point: Not determined. Solubility in Water: >65% Bulk Density at 20°C: not determined Molecular Weight: Mixture Specific Gravity (H20=1): 1.62@25/25C Viscosity: Not Determined. Evaporation Rate: Not Determined VOC Content(%): Not determined. Decomposition Temperature: Not Determined 10. STABILITY AND REACTIVITY Chemical Stability: STABLE. Page 107 of 156 Page 107 of 156 Page 107 of 156 Page 107 of 156 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Trade Name: Master Brake Parts Cleaner MSDS NO. BC20 Revision Date: 25-01-2012 Date Printed 31-05-2012 Page 3 of 4 10. STABILITY AND REACTIVITY Conditions to Avoid: Do not expose to heat or store at temperatures above 120 F. Avoid contact with open flame, electric arcs, or other hot surfaces that could cause thermal decomposition. Materials to Avoid: Contact with oxidizing agents. Sulfuric Acid. Nitric acid. Chlorine compounds. Strong acids. Chloroform. Alkalis. Potassium t-butoxide. Strong bases. Hazardous Decomposition Products: Carbon monoxide. The thermal decomposition products of this material are categorized as very toxic by the University of Pittsburgh toxicity of combustion products test method Hazardous Polymerization: WILL NOT OCCUR 11. TOXICOLOGICAL INFORMATION Toxicological Data: Component Route Species Dose Perchloroethylene 127-18-4 Inhalation Rats LC50 34200 mg/m 3/8H Carbon Dioxide 124-38-9 NA NA Not known. Carcinogenicity: Component IARC NTP OSHA Perchloroethylene 127-18-4 Group 2A (Probable carcinogenic to humans) Listed - Suspect Carcinogen Possible Select Carcinogens Carbon Dioxide 124-38-9 Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Remarks: Ecological testing has not been conducted on this product. 13. DISPOSAL CONSIDERATION Waste Classification: Residues and spilled material are hazardous waste due to ignitability. Waste Management: Not determined. Disposal Method: Disposal should be made in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION U.S. DOT: Proper Shipping Name: CONSUMER COMMODITY Hazard Class: ORM-D UN/NA Number: Not Applicable DOT Packing Group: Not Applicable IMDG: Proper Shipping Name: Aerosols Hazard Class: 2.2 Hazard Subclass: Not determined. UN No.: UN1950 Packing Group: Not Applicable Marine Pollutant: Yes 15. REGULATORY INFORMATION US Federal Regulations: Component SARA 313 SARA 302 TPQ RQ Page 108 of 156 Page 108 of 156 Page 108 of 156 Page 108 of 156 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Trade Name: Master Brake Parts Cleaner MSDS NO. BC20 Revision Date: 25-01-2012 Date Printed 31-05-2012 Page 4 of 4 Component SARA 313 SARA 302 TPQ RQ Perchloroethylene 127-18-4 Listed. Not Listed Not Listed Not Listed Carbon Dioxide 124-38-9 Not Listed Not Listed Not Listed Not Listed US OSHA HEALTH CLASSIFICATION: Hazardous per OSHA 29 CFR 1910.1200 SARA 311/312 Hazard Catagories: Acute, Chronic, Pressure State Regulations: Component California Prop. 65 Cancer list California - Prop 65 Developmental Toxicity California Prop. 65 Reproductive Female California Prop. 65 Reproductive Male Perchloroethylene 127-18-4 Listed: April 1, 1988 Carcinogenic. Not Listed Not Listed Not Listed Carbon Dioxide 124-38-9 Not Listed Not Listed Not Listed Not Listed Component New Jersey Right-to-Know List: Perchloroethylene 127-18-4 Substance no. 1810 Carbon Dioxide 124-38-9 Substance no. 0343 U.S. TSCA: The components of this product are listed on the TSCA Inventory. Canadian Inventory: The components of this product are listed on the Canadian DSL or NDSL Inventory. Consumer Product Safety Improvement Act of 2008 General Conformity Certification The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product container. 16. OTHER INFORMATION General Notes: Do not allow undiluted material or large quantities to reach groundwater, bodies of water or sewer system. Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied. Page 109 of 156 Page 109 of 156 Page 109 of 156 Page 109 of 156 ---PAGE BREAK--- Page 110 of 156 Page 110 of 156 Page 110 of 156 Page 110 of 156 ---PAGE BREAK--- Page 111 of 156 Page 111 of 156 Page 111 of 156 Page 111 of 156 ---PAGE BREAK--- Page 112 of 156 Page 112 of 156 Page 112 of 156 Page 112 of 156 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 MOLY Revision Date: 17 Mar 2015 Page 1 of 10 SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: MOBILGREASE XHP 462 MOLY Product Description: Base Oil and Additives Product Code: 2015A0202529, 642546-00, 97AB15 Intended Use: Grease COMPANY IDENTIFICATION Supplier: EXXON MOBIL CORPORATION 22777 Springwoods Village Parkway Spring, TX. 77389 USA 24 Hour Health Emergency [PHONE REDACTED] Transportation Emergency Phone [PHONE REDACTED] or [PHONE REDACTED] CHEMTREC Product Technical Information [PHONE REDACTED] MSDS Internet Address http://www.exxon.com, http://www.mobil.com SECTION 2 HAZARDS IDENTIFICATION This material is not hazardous according to regulatory guidelines (see (M)SDS Section 15). Other hazard information: HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200. PHYSICAL / CHEMICAL HAZARDS No significant hazards. HEALTH HAZARDS High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, or respiratory irritation. ENVIRONMENTAL HAZARDS No significant hazards. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. Page 113 of 156 Page 113 of 156 Page 113 of 156 Page 113 of 156 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 MOLY Revision Date: 17 Mar 2015 Page 2 of 10 SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS This material is defined as a mixture. Hazardous Substance(s) or Complex Substance(s) required for disclosure Name CAS# Concentration* GHS Hazard Codes BENZENAMINE, N-PHENYL-, REACTION PRODUCTS WITH 68411-46-1 1 - < 5% H402, H412 MOLYBDENUM (IV) SULFIDE 1317-33-5 1 - < 5% None ZINC DITHIOPHOSPHATE 68649-42-3 1 - < 2.5% H315, H318, H401, H411 * All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. As per paragraph of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and exact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact percentage composition will be provided to health professionals, employees, or designated representatives in accordance with applicable provisions of paragraph SECTION 4 FIRST AID MEASURES INHALATION Under normal conditions of intended use, this material is not expected to be an inhalation hazard. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, Page 114 of 156 Page 114 of 156 Page 114 of 156 Page 114 of 156 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 MOLY Revision Date: 17 Mar 2015 Page 3 of 10 sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Smoke, Fume, Sulfur oxides, Aldehydes, Oxides of carbon, Incomplete combustion products FLAMMABILITY PROPERTIES Flash Point [Method]: >294°C (561°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802. PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended. SPILL MANAGEMENT Land Spill: Scrape up spilled material with shovels into a suitable container for recycle or disposal. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Skim from surface. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Prevent entry into waterways, sewers, basements or confined areas. Page 115 of 156 Page 115 of 156 Page 115 of 156 Page 115 of 156 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 MOLY Revision Date: 17 Mar 2015 Page 4 of 10 SECTION 7 HANDLING AND STORAGE HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator. STORAGE Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMIT VALUES Exposure limits/standards (Note: Exposure limits are not additive) Substance Name Form Limit / Standard NOTE Source MOLYBDENUM (IV) SULFIDE [as Mo] Total dust. TWA 15 mg/m3 N/A OSHA Z1 MOLYBDENUM (IV) SULFIDE [as Mo] Inhalable fraction. TWA 10 mg/m3 N/A ACGIH MOLYBDENUM (IV) SULFIDE [as Mo] Respirable fraction. TWA 3 mg/m3 N/A ACGIH NOTE: Limits/standards shown for guidance only. Follow applicable regulations. No biological limits allocated. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove Page 116 of 156 Page 116 of 156 Page 116 of 156 Page 116 of 156 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 MOLY Revision Date: 17 Mar 2015 Page 5 of 10 manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Physical State: Solid Form: Semi-fluid Color: Brown Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 0.9 Flammability (Solid, Gas): Flash Point [Method]: >294°C (561°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) [Estimated] Decomposition Temperature: N/D Vapor Density (Air = N/D Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C [Estimated] Evaporation Rate (n-butyl acetate = N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 [Estimated] Solubility in Water: Negligible Viscosity: 460 cSt (460 mm2/sec) at 40 °C Oxidizing Properties: See Hazards Identification Section. Page 117 of 156 Page 117 of 156 Page 117 of 156 Page 117 of 156 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 MOLY Revision Date: 17 Mar 2015 Page 6 of 10 OTHER INFORMATION Freezing Point: N/D Melting Point: N/D DMSO Extract (mineral oil only), IP-346: < 3 %wt NOTE: Most physical properties above are for the oil component in the material. SECTION 10 STABILITY AND REACTIVITY REACTIVITY: See sub-sections below. STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS Hazard Class Conclusion / Remarks Inhalation Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Ingestion Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Corrosion/Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on assessment of the components. Eye Serious Eye Damage/Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components. Sensitization Respiratory Sensitization: No end point data for material. Not expected to be a respiratory sensitizer. Skin Sensitization: No end point data for material. Not expected to be a skin sensitizer. Based on assessment of the components. Aspiration: Data available. Not expected to be an aspiration hazard. Based on physico-chemical properties of the material. Germ Cell Mutagenicity: No end point data for material. Not expected to be a germ cell mutagen. Based on assessment of the components. Page 118 of 156 Page 118 of 156 Page 118 of 156 Page 118 of 156 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 MOLY Revision Date: 17 Mar 2015 Page 7 of 10 Carcinogenicity: No end point data for material. Not expected to cause cancer. Based on assessment of the components. Reproductive Toxicity: No end point data for material. Not expected to be a reproductive toxicant. Based on assessment of the components. Lactation: No end point data for material. Not expected to cause harm to breast-fed children. Specific Target Organ Toxicity (STOT) Single Exposure: No end point data for material. Not expected to cause organ damage from a single exposure. Repeated Exposure: No end point data for material. Not expected to cause organ damage from prolonged or repeated exposure. Based on assessment of the components. OTHER INFORMATION Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Not expected to be harmful to aquatic organisms. MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. Page 119 of 156 Page 119 of 156 Page 119 of 156 Page 119 of 156 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 MOLY Revision Date: 17 Mar 2015 Page 8 of 10 SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (DOT): Not Regulated for Land Transport LAND (TDG): Not Regulated for Land Transport SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code Marine Pollutant: No AIR (IATA): Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with OSHA HazCom 2012, 29 CFR 1910.1200. Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, ENCS, IECSC, Page 120 of 156 Page 120 of 156 Page 120 of 156 Page 120 of 156 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 MOLY Revision Date: 17 Mar 2015 Page 9 of 10 KECI, PICCS, TSCA EPCRA SECTION 302: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: Chemical Name CAS Number Typical Value ZINC DITHIOPHOSPHATE 68649-42-3 1 - < 2.5% The following ingredients are cited on the lists below: Chemical Name CAS Number List Citations MOLYBDENUM (IV) SULFIDE 1317-33-5 1, 4, 13, 16 SOLUTION OF ZINC NAPHTHENATE (10%) IN MINERAL OIL 45011 15 ZINC DITHIOPHOSPHATE 68649-42-3 13, 15, 17, 19 --REGULATORY LISTS SEARCHED-- 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK 5 = TSCA 4 10 = CA P65 CARC 15 = MI 293 Code key: CARC=Carcinogen; REPRO=Reproductive SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only): H315: Causes skin irritation; Skin Corr/Irritation, Cat 2 H318: Causes serious eye damage; Serious Eye Damage/Irr, Cat 1 H401: Toxic to aquatic life; Acute Env Tox, Cat 2 H402: Harmful to aquatic life; Acute Env Tox, Cat 3 H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2 H412: Harmful to aquatic life with long lasting effects; Chronic Env Tox, Cat 3 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Updates made in accordance with implementation of GHS requirements. Page 121 of 156 Page 121 of 156 Page 121 of 156 Page 121 of 156 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 MOLY Revision Date: 17 Mar 2015 Page 10 of 10 The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A DGN: 7049663XUS (1009427) Copyright 2002 Exxon Mobil Corporation, All rights reserved Page 122 of 156 Page 122 of 156 Page 122 of 156 Page 122 of 156 ---PAGE BREAK--- SAFETY DATA SHEET POLAR WW SOLVENT 6/1GL Page 1 of 7 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product Name: POLAR WW SOLVENT 6/1GL Product Code: WW65006P 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended use: Windshield Wash Recommended restrictions: AZ, CA, TX, Atlanta Area 1.3. Details of the supplier of the safety data sheet Manufacturer: Warren Distribution, Inc. 727 S. 13th Street Omaha, NE 68102 Information Phone: +01 (800) 825-1235 +01 (402) 341-9397 E-mail: [EMAIL REDACTED] 1.4. Emergency telephone number Emergency phone number: CHEMTREC: +1 (800) 424-9300 International: +01 (703) 527-3887 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Specific Target Organ Systemic Toxicity (STOT) - Single Exposure Category 1 Flammable Liquid Category 3 2.2. Label elements GHS Hazard Symbols Signal Word Danger Hazard Statements H226 - Flammable liquid and vapor. H370 - Causes damage to organs. Precautionary Statements Prevention P210 - Keep away from heat/sparks/open flames/hot surfaces. – No smoking. P233 - Keep container closed. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting/…/ equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P260 - Do not breathe dust/fume/gas/mist/vapors/spray. P264 - Wash exposed areas thoroughly after handling. P270 - Do no eat, drink or smoke when using this product. P280 - Wear protective gloves/protective clothing/eye protection/face protection. Response P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P307+P311 - IF exposed: Call a POISON CENTER or doctor/physician. P321 - Specific treatment (see section P370+P378 - In case of fire: Use … to extinguish. Storage P233 - Keep container closed. P403+P235 - Store in a well-ventilated place. Keep cool. Page 123 of 156 Page 123 of 156 Page 123 of 156 Page 123 of 156 ---PAGE BREAK--- SAFETY DATA SHEET POLAR WW SOLVENT 6/1GL Page 2 of 7 P405 - Store locked up. Disposal P501- Dispose of contents/container in accordance with local/regional/national/international regulations. 2.3. Other hazards Hazards not otherwise classified: No data available. Unknown acute toxicity (GHS-US) Unknown Acute Toxicity (Gas): 61.197286 % of the mixture consists of ingredient(s) of unknown toxicity. SECTION 3: Composition/information on ingredients Chemical Name % CAS # GHS Classification Methanol 15 - 40 67-56-1 Acute Tox. 3; H311 Acute Tox. 3; H301 Acute Tox. 3; H331 Flam. Liq. 2; H225 STOT SE 1; H370 Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication Standard). SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not breathing, give artificial respiration and have a trained individual administer oxygen. Get medical attention immediately. Eyes Flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Get immediate medical attention. Skin Contact Wash with soap and water. Remove contaminated clothing and launder. Get medical attention if irritation develops or persists. Ingestion Seek medical attention immediately or call the Poison control center. Do not induce vomiting. If patient is fully conscious, give up to two glasses of water. Provide medical care provider with this SDS. 4.2. Most important and effects, both acute and delayed Vomiting, Nausea, Headache, Dizziness, Drowsiness, Coughing, Mental confusion, Systemic effects similar to those resulting from ingestion, Temporary or permanent blindness, Muscle pains, Impaired vision 4.3. Indication of any immediate medical attention and special treatment needed Note to Doctor No additional first aid information available. Page 124 of 156 Page 124 of 156 Page 124 of 156 Page 124 of 156 ---PAGE BREAK--- SAFETY DATA SHEET POLAR WW SOLVENT 6/1GL Page 3 of 7 SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable and Unsuitable Extinguishing Media: Use alcohol resistant foam, carbon dioxide, or dry chemical extinguishing agents. Water may be ineffective but water spray can be used to extinguish a fire if swept across the base of the flames. Water can absorb heat and keep exposed material from being damaged by fire. 5.2. Special hazards arising from the substance or mixture Fire and/or Explosion Hazards Vapors may be ignited by sparks, flames or other sources of ignition if material is above the flash point giving rise to a fire (Class Vapors are heavier than air and may travel to a source of ignition and flash back. 5.3. Advice for firefighters Fire Fighting Methods and Protection Do not enter fire area without proper protection including self-contained breathing apparatus and full protective equipment. Fight fire from a safe distance and a protected location due to the potential for hazardous vapors and decomposition products.Flammable component(s) of this material may be lighter than water and burn while floating on the surface. Hazardous Combustion Products Carbon monoxide, Formaldehyde SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General Measures: Exposure to the spilled material may be severely irritating or toxic. Follow personal protective equipment recommendations found in Section 8 of this SDS. Personal protective equipment needs must be evaluated based on the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Evaporation of volatile substances can lead to the displacement of air creating an environment that can cause 6.2. Environmental precautions Avoid runoff into storm sewers and ditches that lead to waterways. 6.3. Methods and material for containment and cleaning up Methods for cleaning up: Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section 8 at a minimum. Dike with suitable absorbent material like granulated clay. Dispose of according to Federal, State, Local, or Provincial regulations. Used fluid should be disposed of at a recycling center. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. 6.4. Reference to other sections Follow all protective equipment recommendations provided in Section 8. SECTION 7: Handling and storage 7.1. Precautions for safe handling Harmful or irritating material. Avoid contacting and avoid breathing the material. Use only in a well ventilated area. Empty containers may retain product residues/ vapors. Use proper bonding and grounding during bulk product transfer.Use spark-proof tools and explosion-proof equipment 7.2. Conditions for safe storage, including any incompatibilities Store in a cool dry ventilated location. Isolate from incompatible materials and conditions. Keep container(s) closed. Do not expose to extreme temperatures or flames. Incompatible materials See Section 10. 7.3. Specific end use(s) Windshield Wash SECTION 8: Exposure controls/personal protection 8.1. Control parameters Chemical Name Occupational Exposure Limits Value Methyl alcohol OSHA PEL 200 ppm TWA; 260 mg/m3 TWA Methyl alcohol OSHA STEL 250 ppm STEL; 325 mg/m3 STEL Methanol ACGIH TLV-TWA 200 ppm TWA Page 125 of 156 Page 125 of 156 Page 125 of 156 Page 125 of 156 ---PAGE BREAK--- SAFETY DATA SHEET POLAR WW SOLVENT 6/1GL Page 4 of 7 SECTION 8: Exposure controls/personal protection 8.1. Control parameters Chemical Name Occupational Exposure Limits Value Methanol ACGIH STEL 250 ppm STEL Methyl alcohol IDLH 6000 ppm IDLH None. OSHA PEL-Skin Notation Methyl alcohol OSHA STEL-Skin Notation Potential for dermal absorption Methanol ACGIH TLV-Skin Designation Skin - potential significant contribution to overall exposure by the cutaneous route 8.2. Exposure controls Engineering Measures Use local exhaust ventilation or other engineering controls to minimize exposures and maintain operator comfort. Respiratory Protection Respiratory protection may be required to avoid overexposure when handling this product. General or local exhaust ventilation is the preferred means of protection. Use a respirator if general room ventilation is not available or sufficient to eliminate Respirator Type(s) None required where adequate ventilation is provided. If airborne concentrations are above the applicable exposure limits, use NIOSH/MSHA approved respiratory protection. Eye Protection Wear chemically resistant safety glasses with side shields when handling this product. Do not wear contact lenses. An eye wash station must be available where this product is used. Skin Protection Wear protective gloves. Inspect gloves for chemical break-through and replace at regular intervals. Clean protective equipment regularly. Wash hands and other exposed areas with mild soap and water before eating, drinking, and when leaving work. Gloves Butyl rubber, Polyethylene, Polyvinylalcohol SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical State Liquid Color Blue Odor Moderate Odor threshold Not determined pH Not determined Freezing point Not determined Boiling Point Not determined Flash Point 36 Flash Point Method PMCC Evaporation Rate 2-10 (n-Butyl acetate = 1) Upper Flammable/Explosive Limit, % in air 36.5 (air = 1) Lower Flammable/Explosive Limit, % in air 6 (air = 1) Flammability (solid, gas) Not applicable Vapor pressure Not determined Vapor Density Not determined Relative Density 0.82 Solubility in Water Complete; 100% Octanol/Water Partition Coefficient Not determined Autoignition Temperature Not determined Decomposition Temperature Not determined 9.2. Other information Volatiles, % by weight 0.000000 SECTION 10: Stability and reactivity 10.1. Reactivity No data available. Page 126 of 156 Page 126 of 156 Page 126 of 156 Page 126 of 156 ---PAGE BREAK--- SAFETY DATA SHEET POLAR WW SOLVENT 6/1GL Page 5 of 7 SECTION 10: Stability and reactivity 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Sparks, open flame, other ignition sources, and elevated temperatures.Visible light 10.5. Incompatible materials Strong oxidizing agents 10.6. Hazardous decomposition products Carbon monoxide, Formaldehyde SECTION 11: Toxicological information 11.1. Information on toxicological effects Ingestion Toxicity No hazard in normal industrial use.Estimated to be > 5.0 g/kg. Skin Contact This material is likely to be moderately irritating to skin based on animal data.Can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause permanent damage. Absorption Estimated to be > 5.0 g/kg; practically non-toxic Inhalation Toxicity No hazard in normal industrial use. Likely to be practically non-toxic based on animal data. Eye Contact The material is likely to be moderately irritating to eyes based on animal data. Can cause moderate irritation, tearing and reddening, but not likely to permanently injure eye tissue. Sensitization Non-hazardous under Respiratory Sensitization category.No data available to indicate product or components may be a skin sensitizer. Mutagenicity No data available to indicate product or any components present at greater than 0.1% is mutagenic or genotoxic. Carcinogenicity Not a carcinogen according to NTP, IARC, or OSHA. Reproductive and Developmental Toxicity No data available to indicate product or any components present at greater than 0.1% may cause birth defects. Specific target organ toxicity-Single exposure H370 - Causes damage to organs. Specific target organ toxicity-Repeated exposure Non-hazardous under Specific Target Organ Systemic Toxicity Repeated Exposure category. Long-Term (Chronic) Health Effects Drowsiness, Headache, Impaired vision, Circulatory failure, Abdominal pain, Skin rashes Aspiration toxicity Non-hazardous under Aspiration category. Other information No data available. Agents Classified by IARC Monographs Not applicable IARC Group 1 Not applicable IARC Group 2A Not applicable IARC Group 2B National Toxicity Program (NTP) Status Not applicable Known Human Carcinogen Not applicable Reasonably Anticipated To Be A Human Carcinogen SECTION 12: Ecological information 12.1. Toxicity Acute Aquatic ecotoxicity: Non-hazardous under Aquatic Acute Environment category. Chronic Aquatic ecotoxicity: Non-hazardous under Aquatic Chronic Environment category. 12.2. Persistence and degradability Biodegrades quickly. 12.3. Bioaccumulative potential Bioconcentration is not expected to occur. 12.4. Mobility in soil This material is expected to have very high mobility in soil. It does not absorb to most soil types. This material is expected to evaporate quickly from surface soils and/or waters. 12.5. Results of PBT and vPvB assessment Page 127 of 156 Page 127 of 156 Page 127 of 156 Page 127 of 156 ---PAGE BREAK--- SAFETY DATA SHEET POLAR WW SOLVENT 6/1GL Page 6 of 7 SECTION 12: Ecological information No data available. 12.6. Other adverse effects Not determined SECTION 13: Disposal considerations 13.1. Waste treatment methods Disposal Methods Dispose of by incineration following Federal, State, Local, or Provincial regulations. Waste Disposal Code(s) D001 Waste Description for Spent Product Spent or discarded material is a hazardous waste. Contaminated packaging: Containers of this material may be hazardous when emptied. SECTION 14: Transport information DOT Basic Description UN1993, FLAMMABLE LIQUID, N.O.S. (METHANOL), 3, III, LTD QTY IMDG Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S Technical Name: METHANOL UN Number: UN1993 Hazard Class: 3 Packing Group: III Exception: LTD QTY EMS# F-E,S-E IATA Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S Technical Name: METHANOL UN Number: UN1993 Hazard Class: 3 Packing Group: III Exception: LTD QTY SECTION 15: Regulatory information Chemical Inventories TSCA Status All components of this material are on the US TSCA Inventory or are exempt. U.S. State Restrictions: AZ, CA, TX, Atlanta Area WHMIS: B2, D1B, D2A, D2B Chemical Name Regulation CAS # % Methanol CERCLA 67-56-1 15 - 40 Methanol SARA 313 67-56-1 15 - 40 None. SARA EHS None. TSCA 12b U.S. State Regulations Chemical Name Regulation CAS # % None. California Prop 65- Cancer Methanol California Prop 65- Dev. Toxicity 67-56-1 15 - 40 None. California Prop 65- Reprod -fem None. California Prop 65- Reprod-male Page 128 of 156 Page 128 of 156 Page 128 of 156 Page 128 of 156 ---PAGE BREAK--- SAFETY DATA SHEET POLAR WW SOLVENT 6/1GL Page 7 of 7 Chemical Name Regulation CAS # % Methanol Massachusetts RTK List 67-56-1 15 - 40 Methyl alcohol New Jersey RTK List 67-56-1 15 - 40 Methanol RTK List 67-56-1 15 - 40 None. Rhode Island RTK List Methyl alcohol Minnesota Hazardous Substance List 67-56-1 15 - 40 HMIS Ratings: NFPA Ratings: Health: 2 Health: 2 Fire: 3 Fire: 3 Reactivity: 0 Reactivity: 0 PPE: B KEY: 0 - Least 1 - Slight 2 - Moderate 3 - High 4 – Extreme SECTION 16: Other information Revision Date 4/2/2015 11:56:38 AM Supersedes: 4/2/2015 4:47:28 AM References ACGIH: American Conference of Governmental Industrial Hygienists AIHA: American Industrial Hygiene Association CFR: Code of Federal Regulations DOT: United States Department of Transportation GHS: Globally Harmonized System of Classification and Labeling of Chemicals HMIS: Hazardous Materials Identification System IARC: International Agency for Research on Cancer IATA: International Air Transportation Association IDLH: Immediately Dangerous to Life or Health IMDG: International Maritime Dangerous Goods NFPA: National Fire Protection Association NIOSH: National Institute for Occupational Safety and Health NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration PEL: Permissible Exposure Limit RTK: Right-to-Know SARA: Superfund Amendments and Reauthorization Act STEL: Short-term Exposure Limit TLV: Threshold limit value TSCA: Toxic Substances Control Act TWA: Time weighted average UN: United Nations WHMIS: Workplace Hazardous Materials Information System Disclaimer This safety data sheet and the information it contains is offered to you in good faith as accurate. We have reviewed any information contained in the data sheet which we have received from outside sources and we believe the information to be correct, but cannot guarantee its accuracy or completeness. Health and safety precautions in this data sheet may not be adequate for all individuals and/or situations. It is the user's obligation to evaluate and use this product in a safe manner and to comply with all applicable laws and regulations. No statement made in this data sheet shall be construed as permission or recommendation for the use of any product in a manner that might infringe existing patents. No warranty is made, either expressed or implied. Page 129 of 156 Page 129 of 156 Page 129 of 156 Page 129 of 156 ---PAGE BREAK--- WestAir Gases & Equipment Inc page 1 of 5 Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved Generated: 08/04/2015 18:12:43 Safety Data Sheet Propane WestAir Gases & Equipment Inc 2506 Market St San Diego, CA 92102 [PHONE REDACTED] http://westairgases.com Section 1: Product and Company Identification WestAir Gases & Equipment Inc 2506 Market St San Diego, CA 92102 [PHONE REDACTED] http://westairgases.com Product Code: Propane Section 2: Hazards Identification Danger Hazard Classification: Flammable (Category 1) Gases Under Pressure Hazard Statements: Contains gas under pressure; may explode if heated Extremely flammable gas Precautionary Statements Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Response: Eliminate all ignition sources if safe to do so. Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Storage: Protect from sunlight. Store in well-ventilated place. Page 130 of 156 Page 130 of 156 Page 130 of 156 Page 130 of 156 ---PAGE BREAK--- WestAir Gases & Equipment Inc page 2 of 5 Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved Generated: 08/04/2015 18:12:43 Section 3: Composition/Information on Ingredients Chemical Substance Chemical Family Trade Names PROPANE hydrocarbons, aliphatic N-PROPANE; PROPYL HYDRIDE; R-290; LIQUEFIED PETROLEUM GAS; LPG; >96% NATURAL GRADE; >99.9% PURE GRADE; UN 1978; C3H8 Section 4: First Aid Measures Skin Contact Eye Contact Ingestion Inhalation Note to Physicians If frostbite or freezing occur, immediately flush with plenty of lukewarm water (105-115 F; 41-46 DO NOT USE HOT WATER. If warm water is not available, gently wrap affected parts in blankets. Get immediate medical attention. Contact with liquid: Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. If a large amount is swallowed, get medical attention. If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. For inhalation, consider oxygen. Section 5: Fire Fighting Measures Suitable Extinguishing Media Products of Combustion Protection of Firefighters Regular dry chemical, high expansion foam Large fires: Flood with fine water spray. Avoid carbon dioxide. Carbon monoxide, carbon dioxide, water and toxic and irritating fumes  Any self-contained breathing apparatus with a full facepiece.  Any self-contained breathing apparatus with a full facepiece. Section 6: Accidental Release Measures Personal Precautions Environmental Precautions Methods for Containment Keep unnecessary people away, isolate hazard area and deny entry. Ventilate closed spaces before entering. Do not touch spilled material. Avoid heat, flames, sparks and other sources of ignition. Stop leak if possible without personal risk. Reduce vapors with water spray. Remove sources of ignition. Methods for Cleanup Other Information Contact emergency personnel None Section 7: Handling and Storage Handling Storage Store and handle in accordance with all current regulations and standards. Grounding and bonding required. Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. Keep separated from incompatible substances. Section 8: Exposure Controls/Personal Protection Exposure Guidelines CAS # 74-98-6 Page 131 of 156 Page 131 of 156 Page 131 of 156 Page 131 of 156 ---PAGE BREAK--- WestAir Gases & Equipment Inc page 3 of 5 Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved Generated: 08/04/2015 18:12:43 Exposure Guidelines PROPANE: 1000 ppm (1800 mg/m3) OSHA TWA 1000 ppm (1800 mg/m3) NIOSH recommended TWA 10 hour(s) LIQUIFIED PETROLEUM GAS (LPG): 1000 ppm (1800 mg/m3) OSHA TWA 1000 ppm ACGIH TWA 1000 ppm (1800 mg/m3) NIOSH recommended TWA 10 hour(s) ALIPHATIC HYDROCARBON GASES ALKANE (C1-C4): 1000 ppm ACGIH TWA Engineering Controls Handle only in fully enclosed systems. Eye Protection Skin Protection Respiratory Protection For the gas: Eye protection not required, but recommended. For the liquid: Wear splash resistant safety goggles. Contact lenses should not be worn. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. For the gas: Protective clothing is not required. For the liquid: Wear appropriate protective, cold insulating clothing. Any self-contained breathing apparatus with a full facepiece. General Hygiene considerations  Avoid breathing vapor or mist  Avoid contact with eyes and skin  Wash thoroughly after handling and before eating or drinking Section 9: Physical and Chemical Properties Physical State Appearance Color Change in Appearance Physical Form Odor Taste Gas Clear Colorless N/A Gas Gasoline odor N/A Flash Point Flammability Partition Coefficient Autoignition Temperature Upper Explosive Limits Lower Explosive Limits -157 F (-105 C) Not available Not available 842 F (450 C) 0.095 0.021 Boiling Point Freezing Point Vapor Pressure Vapor Density Specific Gravity Water Solubility pH Odor Threshold Evaporation Rate Viscosity -40 F 40 C) -310 F 190 C) 6398 mmHg @ 21.1 C 1.55 (Air=1) 0.5853 @ -45 C Very soluble Not applicable 5000- 20000 ppm Not applicable Not available Molecular Weight Molecular Formula Density Weight per Gallon Volatility by Volume Volatility Solvent Solubility 44.11 C-H3-C-H2-C- H3 0.116 Not available Not available Not applicable Soluble: Absolute alcohol, ether, chloroform, benzene, turpentine Section 10: Stability and Reactivity Stability Conditions to Avoid Incompatible Materials Stable at normal temperatures and pressure. Stable at normal temperatures and pressure. Oxidizing materials, combustible materials, halogen compounds, Hazardous Decomposition Products Possibility of Hazardous Reactions Oxides of carbon Will not polymerize. Section 11: Toxicology Information Acute Effects Oral LD50 Dermal LD50 Inhalation LC50 Inhalation Gas. Rat >800000 ppm 15 minutes Not available Nausea, vomiting, irregular heartbeat, headache, of drunkenness, diorientation, suffocation, convulsions, coma Eye Irritation Skin Irritation Sensitization Liquid: frostbite, blurred vision Liquid: blisters, frostbite Central nervous system depression, difficulty breathing Page 132 of 156 Page 132 of 156 Page 132 of 156 Page 132 of 156 ---PAGE BREAK--- WestAir Gases & Equipment Inc page 4 of 5 Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved Generated: 08/04/2015 18:12:43 Chronic Effects Carcinogenicity Mutagenicity Reproductive Effects Developmental Effects Not available Not available Not available No data Section 12: Ecological Information Fate and Transport Eco toxicity Persistence / Degradability Bioaccumulation / Accumulation Mobility in Environment Fish toxicity: Not available Invertibrate toxicity: Not available Algal toxicity: Not available Phyto toxicity: Not available Other toxicity: Not available Not available Not available Not available Section 13: Disposal Considerations Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. Section 14: Transportation Information U.S. DOT 49 CFR 172.101 Proper Shipping Name ID Number Hazard Class or Division Packing Group Labeling Requirements Passenger Aircraft or Railcar Quantity Limitations Cargo Aircraft Only Quantity Limitations Additional Shipping Description Propane UN1978 2.1 Not applicable 2.1 Forbidden 150 kg N/A Canadian Transportation of Dangerous Goods Shipping Name UN Number Class Packing Group / Risk Group Propane UN1978 2.1 Not applicable Section 15: Regulatory Information U.S. Regulations CERCLA Sections SARA 355.30 SARA 355.40 Not regulated. Not regulated. Not regulated. SARA 370.21 Acute Chronic Fire Reactive Sudden Release Yes No Yes No Yes SARA 372.65 Not regulated. OSHA Process Safety Not regulated. State Regulations CA Proposition 65 Not regulated. Canadian Regulations WHMIS Classification Page 133 of 156 Page 133 of 156 Page 133 of 156 Page 133 of 156 ---PAGE BREAK--- WestAir Gases & Equipment Inc page 5 of 5 Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved Generated: 08/04/2015 18:12:43 A, B1. National Inventory Status US Inventory (TSCA) TSCA 12b Export Notification Canada Inventory (DSL/NDSL) Listed on inventory. Not listed. Listed on inventory. Section 16: Other Information NFPA Rating HEALTH=1 FIRE=4 REACTIVITY=0 0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Page 134 of 156 Page 134 of 156 Page 134 of 156 Page 134 of 156 ---PAGE BREAK--- Page 135 of 156 Page 135 of 156 Page 135 of 156 Page 135 of 156 ---PAGE BREAK--- Page 136 of 156 Page 136 of 156 Page 136 of 156 Page 136 of 156 ---PAGE BREAK--- Page 137 of 156 Page 137 of 156 Page 137 of 156 Page 137 of 156 ---PAGE BREAK--- Page 138 of 156 Page 138 of 156 Page 138 of 156 Page 138 of 156 ---PAGE BREAK--- Page 139 of 156 Page 139 of 156 Page 139 of 156 Page 139 of 156 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Date of issue: 07/24/2015 EN (English US) Page 1 Section 1: Identification 1.1. Product identifier Product form : Mixture Product Identifier(s) : Unleaded Gasoline Grade Gasoline Regular Gasoline, Regular Unleaded Gasoline Mid-Grade Gasoline, Mid-Grade Unleaded Gasoline Premium Gasoline, Premium Unleaded Gasoline CAS No : 86290-81-5 1.2. Recommended use of the chemical and restrictions on use Use of the substance/mixture : Fuel 1.3. Details of the supplier of the safety data sheet Total Petrochemicals & Refining USA, Inc. P O Box 674411 Houston, TX 77267-4411 For non-emergency product information: Phone: [PHONE REDACTED] Email: [EMAIL REDACTED] 1.4. Emergency telephone number Emergency number : CHEMTREC: 1-[PHONE REDACTED] (Toll Free USA & Canada) / [PHONE REDACTED] (Multiple languages) Total Petrochemicals & Refining USA, Inc.: 1-[PHONE REDACTED] (Language: English only) Section 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Flammable liquids Category 1 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Germ cell mutagenicity Category 1B Carcinogenicity Category 1B Reproductive toxicity Category 2 Specific target organ toxicity (single exposure) Category 1 Specific target organ toxicity (single exposure) Category 3 - Respiratory irritation Specific target organ toxicity (single exposure) Category 3 - Narcotic effects Specific target organ toxicity (repeated exposure) Category 1 Aspiration hazard Category 1 Hazardous to the aquatic environment - Chronic Hazard Category 2 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Extremely flammable liquid and vapor May be fatal if swallowed and enters airways Causes skin irritation Causes serious eye irritation May cause respiratory irritation May cause drowsiness or dizziness May cause genetic defects Page 140 of 156 Page 140 of 156 Page 140 of 156 Page 140 of 156 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 2/12 May cause cancer Suspected of damaging fertility or the unborn child Causes damage to organs (lung) Causes damage to organs (blood, hematopoietic system [blood forming], kidneys, peripheral nervous system, brain (neurological), nervous system, visual organ (color vision effects), hearing organ (loss of hearing)) through prolonged or repeated exposure Toxic to aquatic life with long lasting effects Precautionary statements (GHS-US) : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from sparks, open flames, heat, hot surfaces. - No smoking. Keep container closed. Ground/bond container and receiving equipment. Use explosion-proof electrical, lighting, ventilating equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe spray, mist, vapors. Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear flame retardant protective clothing, impermeable protective gloves, eye protection, face protection. If swallowed: Immediately call doctor, poison center. Do NOT induce vomiting. If on skin: Wash with plenty of water. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Specific treatment (see Section 4.1 of SDS or information on this label). If exposed or concerned: Get medical advice/attention. Get medical advice/attention if you feel unwell. Take off contaminated clothing and wash it before reuse. In case of fire: Use Water spray, foam, carbon dioxide (CO2), dry chemical to extinguish. Collect spillage. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. 2.3. Hazards not otherwise classified Other hazards not contributing to the classification : Product can accumulate electrostatic charges that may cause fire by electrical discharges. 2.4. Unknown acute toxicity (GHS-US) 19 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation (Vapours)) 2.5. Additional information No additional information available Section 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Where concentrations in this product are displayed as ranges, it is due to batch-to-batch variability. Name CAS No % Other hydrocarbons ( C4- C14 ) - 5 - 40 Xylene 1330-20-7 1 - 20 Toluene 108-88-3 1 - 20 n-Heptane and Heptane Isomers - 0 - 20 Hexane isomers, excluding n-hexane - 0 - 20 n-Octane and Octane Isomers - 0 - 20 100-41-4 1 - 10 95-63-6 1 - 10 Page 141 of 156 Page 141 of 156 Page 141 of 156 Page 141 of 156 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 3/12 n-pentane 109-66-0 0 - 10 Isopentane 78-78-4 0 - 10 n-Nonane and Nonane Isomers - 0 - 10 n-Hexane 110-54-3 0 - 5 Benzene 71-43-2 0.1 - 2 Cyclohexane 110-82-7 0 - 2 Naphthalene 91-20-3 0.1 - 1 Cumene 98-82-8 0.1 - 1 Section 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center/doctor/physician if you feel unwell. First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if irritation persists. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a poison center or doctor/physician. 4.2. Most important and effects, both acute and delayed : May cause genetic defects. after inhalation : May cause respiratory irritation. May cause drowsiness or dizziness. after skin contact : Causes skin irritation. after ingestion : May be fatal if swallowed and enters airways. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available Section 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the chemical Fire hazard : Extremely flammable liquid and vapor. Explosion hazard : May form flammable/explosive vapor-air mixture. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Section 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Emergency procedures for non-emergency personnel : Evacuate unnecessary personnel. Emergency procedures for emergency responders : Ventilate area. Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. 6.2. Methods and material for containment and cleaning up For containment : Do not contaminate ground and surface water. Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.3. Reference to other sections See section 8. Exposure controls/personal protection. Section 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Page 142 of 156 Page 142 of 156 Page 142 of 156 Page 142 of 156 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 4/12 Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No bare lights. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Eliminate all ignition sources if safe to do so. Use only outdoors or in a well-ventilated area. Do not breathe vapors, mist, spray. Never siphon by mouth. DO NOT fill container while container is in vehicle. Hygiene measures : Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when using this product. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating, lighting equipment. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : flames, heat sources, sparks. Keep in fireproof place. Keep container closed. Incompatible products : Strong bases. Strong acids. Strong oxidizing agents. Strong reducing agents. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. Section 8: Exposure controls/personal protection 8.1. Occupational Exposure Limits Unleaded Gasoline (86290-81-5) USA ACGIH ACGIH TWA (ppm) 300 ppm USA ACGIH ACGIH STEL (ppm) 500 ppm n-Octane and Octane Isomers USA ACGIH ACGIH TWA (ppm) 300 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 2350 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 500 ppm n-Heptane and Heptane Isomers USA ACGIH ACGIH TWA (ppm) 400 ppm USA ACGIH ACGIH STEL (ppm) 500 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 2000 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 500 ppm Hexane isomers, excluding n-hexane USA ACGIH ACGIH TWA (ppm) 50 ppm USA OSHA OSHA PEL (TWA) (ppm) 500 ppm Toluene (108-88-3) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (ppm) 200 ppm USA OSHA OSHA PEL (Ceiling) (ppm) 300 ppm USA OSHA Remark (OSHA) See OSHA Table Z-2. Xylenes p- isomers) (1330-20-7) USA ACGIH ACGIH TWA (ppm) 100 ppm USA ACGIH ACGIH STEL (ppm) 150 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 435 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 100 ppm n-Nonane and Nonane Isomers USA ACGIH ACGIH TWA (ppm) 200 ppm Isopentane (78-78-4) USA ACGIH ACGIH TWA (ppm) 1000 ppm (Pentane, all isomers) USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm (Pentane, all isomers) n-pentane (109-66-0) USA ACGIH ACGIH TWA (ppm) 600 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 2950 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm (100-41-4) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 435 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 100 ppm Page 143 of 156 Page 143 of 156 Page 143 of 156 Page 143 of 156 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 5/12 n-Hexane (110-54-3) USA ACGIH ACGIH TWA (ppm) 50 ppm USA OSHA OSHA PEL (TWA) (ppm) 500 ppm Cyclohexane (110-82-7) USA ACGIH ACGIH TWA (ppm) 100 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 1050 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 300 ppm Benzene (71-43-2) USA ACGIH ACGIH TWA (ppm) 0.5 ppm USA ACGIH ACGIH STEL (ppm) 2.5 ppm USA OSHA OSHA PEL (TWA) (ppm) 1 ppm USA OSHA OSHA PEL (STEL) (ppm) 5 ppm USA OSHA Remark (OSHA) (see 29 CFR 1910.1028) Naphthalene (91-20-3) USA ACGIH ACGIH TWA (ppm) 10 ppm USA ACGIH ACGIH STEL (ppm) 15 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 50 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 10 ppm Cumene (98-82-8) USA ACGIH ACGIH TWA (ppm) 50 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 245 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 50 ppm 8.2. Exposure controls Appropriate engineering controls : Ensure adequate ventilation. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Impermeable protective gloves. Choosing the proper glove is a decision that depends not only on the type of material, but also on other quality features, which differ for each manufacturer. Gloves should be discarded and replaced if there is any indication of degredation or chemical breakthrough. The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear fire/flame resistant/retardant clothing. Respiratory protection : An approved organic vapor respirator/supplied air or self-contained breathing apparatus must be used when vapor concentration exceeds applicable exposure limits. Other information : Do not eat, drink or smoke during use. Section 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : Colorless. Amber or red, if dyed. Odor : Characteristic. Odor threshold : 83 ppm Weighted average pH : Not applicable Relative evaporation rate (butyl acetate=1) : No data available Relative evaporation rate (ether=1) : < 30 Slower than ethyl ether Melting point : < -60 °C Freezing point : No data available Boiling point : 27 (27 - 225) °C Flash point : < -35 °C (closed cup) Auto-ignition temperature : 280 - 470 °C (at 1013 hPa) Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : 500 - 700 mm Hg at 21°C Relative vapor density at 20 °C : 3 - 4 Air = 1 Relative density : 0.75 Page 144 of 156 Page 144 of 156 Page 144 of 156 Page 144 of 156 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 6/12 Solubility : Water: 30 - 100 mg/l (at 20 Log Kow : No data available Viscosity, kinematic : < 1 cSt at 40°C Viscosity, dynamic : No data available Explosive limits : 1.4 - 7.6 vol % 9.2. Other information VOC content : 100 % Section 10: Stability and reactivity 10.1. Reactivity Flammable liquid and vapor. 10.2. Chemical stability The product is stable at normal handling and storage conditions. 10.3. Possibility of hazardous reactions Under normal conditions of storage and use, hazardous polymerization will not occur. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. Sparks. Heat. Overheating. Open flame. 10.5. Incompatible materials Strong acids. Strong bases. Strong oxidizing agents. Strong reducing agents. 10.6. Hazardous decomposition products Hazardous decomposition products formed under fire conditions: carbon monoxide, carbon dioxide, toxic fumes. Section 11: Toxicological information 11.1. Information on toxicological effects Likely routes of exposure : Inhalation. Ingestion. Skin contact. Eye contact. Acute toxicity : Not classified Based on available data, the classification criteria are not met Combustion of hydrocarbon substances, like this product, produces potentially toxic gases which include carbon monoxide, carbon dioxide, oxides of nitrogen and/or sulfur. Exposure to carbon monoxide gas decreases the ability of the blood to carry oxygen to the body and may be potentially fatal. NIOSH lists the Immediately Dangerous to Life or Health Concentration (IDLH) for carbon monoxide gas as1200 ppm. Unleaded Gasoline (86290-81-5) LD50 oral rat > 5000 (5000 - 14000) mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat > 5.2 mg/l/4h Other hydrocarbons ( C4- C14 ) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat > 5 mg/l/4h n-Octane and Octane Isomers LD50 oral rat > 5000 mg/kg Based on Isooctane LD50 dermal rabbit > 2000 mg/kg Based on Isooctane LC50 inhalation rat > 24 mg/l/4h Based on n-Octane n-Heptane and Heptane Isomers LD50 oral rat > 5000 mg/kg Based on iso-octane LD50 dermal rabbit 3000 mg/kg Based on n-heptane LC50 inhalation rat 103 g/m³ Based on n-heptane Hexane isomers, excluding n-hexane LD50 oral rat 15840 mg/kg based on n-hexane LD50 dermal rabbit 3000 mg/kg based on n-hexane LC50 inhalation rat 259 mg/l/4h based on n-hexane LC50 inhalation rat (ppm) 48000 ppm/4h Toluene (108-88-3) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 5000 mg/kg LC50 inhalation rat 28.1 (28.1 - 49) mg/l/4h LC50 inhalation rat (ppm) > 26700 ppm/1h Page 145 of 156 Page 145 of 156 Page 145 of 156 Page 145 of 156 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 7/12 Xylenes p- isomers) (1330-20-7) LD50 oral rat 4300 mg/kg LD50 dermal rabbit > 4200 mg/kg LC50 inhalation rat 21.7 mg/l/4h n-Nonane and Nonane Isomers LD50 oral rat > 5000 mg/kg Based on Iso-Octane LD50 dermal rabbit > 2000 mg/kg Based on Iso-Octane LC50 inhalation rat 17 mg/l/4h Based on nonane LC50 inhalation rat (ppm) 3200 ppm/4h Isopentane (78-78-4) LD50 oral rat > 2000 mg/kg Based on n-pentane LD50 dermal rabbit 3000 mg/kg LC50 inhalation rat 280 mg/l/4h LC50 inhalation rat (ppm) > 4094 ppmV/4h n-pentane (109-66-0) LD50 oral rat > 2000 mg/kg LD50 dermal rabbit 3000 mg/kg LC50 inhalation rat 364 mg/l/4h (95-63-6) LD50 oral rat 5000 mg/kg LD50 dermal rabbit > 3160 mg/kg LC50 inhalation rat 18 mg/l/4h (100-41-4) LD50 oral rat 3500 mg/kg LD50 dermal rabbit 15354 mg/kg LC50 inhalation rat 17.2 mg/l/4h n-Hexane (110-54-3) LD50 oral rat 15840 mg/kg LD50 dermal rabbit 3000 mg/kg LC50 inhalation rat 259 mg/l/4h Cyclohexane (110-82-7) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat 13.9 mg/l/4h Benzene (71-43-2) LD50 oral rat 930 (930 - 6400) mg/kg LD50 dermal rabbit > 8272 mg/kg LC50 inhalation rat 34.4 mg/l/4h Naphthalene (91-20-3) LD50 oral rat 490 mg/kg LD50 dermal rabbit > 20 g/kg LC50 inhalation rat > 340 mg/m³ (Exposure time: 1 h) Cumene (98-82-8) LD50 oral rat 1400 mg/kg LD50 dermal rat 10600 mg/kg LC50 inhalation rat 39 mg/l/4h Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitization : Not classified Germ cell mutagenicity : May cause genetic defects. Carcinogenicity : May cause cancer. Unleaded Gasoline (86290-81-5) IARC group 2B - Possibly carcinogenic to humans Toluene (108-88-3) IARC group 3 - Not classifiable Xylenes p- isomers) (1330-20-7) IARC group 3 - Not classifiable (100-41-4) IARC group 2B - Possibly carcinogenic to humans Benzene (71-43-2) IARC group 1 - Carcinogenic to humans National Toxicology Program (NTP) Status 1 - Known Human Carcinogens OSHA Carcinogen Status In OSHA Specifically Regulated Carcinogen list Additional information Benzene is a known human carcinogen and is known to cause acute myeloid leukemia & (disease that affects the bone marrow and blood) in Page 146 of 156 Page 146 of 156 Page 146 of 156 Page 146 of 156 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 8/12 humans who have been repeatedly exposed to benzene. Naphthalene (91-20-3) IARC group 2B - Possibly carcinogenic to humans National Toxicology Program (NTP) Status 2 - Reasonably anticipated to be Human Carcinogen Cumene (98-82-8) IARC group 2B - Possibly carcinogenic to humans Reproductive toxicity : Suspected of damaging fertility or the unborn child. Specific target organ toxicity (single exposure) : Causes damage to organs (lung). May cause respiratory irritation. May cause drowsiness or dizziness. Specific target organ toxicity (repeated exposure) : Causes damage to organs (blood, hematopoietic system [blood forming], kidneys, peripheral nervous system, brain (neurological), nervous system, visual organ (color vision effects), hearing organ (loss of hearing)) through prolonged or repeated exposure. Aspiration hazard : May be fatal if swallowed and enters airways. Section 12: Ecological information 12.1. Toxicity Ecology - general : Toxic to aquatic life with long lasting effects. 12.2. Persistence and degradability Unleaded Gasoline (86290-81-5) Persistence and degradability Not established. 12.3. Bioaccumulative potential Unleaded Gasoline (86290-81-5) Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Other information : Avoid release to the environment. Section 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents and container in accordance with all local, regional, national and international regulations. Additional information : Handle empty containers with care because residual vapors are flammable. Ecology - waste materials : Avoid release to the environment. Hazardous waste due to toxicity. Section 14: Transport information US Transport (DOT) for Bulk Shipments (Non-Bulk Shipments May Differ) Transport document description : UN1203, Gasoline, 3, PGII UN or NA Number : UN1203 Proper Shipping Name : Gasoline Primary Hazard Class : 3 - Flammable liquid Packing Group : PGII Reportable Quantities (RQ)* *It is the shipper's responsibility to determine whether an RQ must be reported for each individual shipment. : Benzene 10 lbs (4.54 kg), Cumene 5000 lbs (2270 kg), 1000 lbs (454 kg), Hexane 5000 lbs (2270 kg), Toluene 1000 lbs (454 kg), Mixed Xylenes 100 lbs (45.4 kg), Naphthalene 100 lbs (45.4 kg), Cyclohexane 1000 lbs (454 kg) Hazard labels : Emergency Response Guide (ERG) Number : 128 In accordance with the definition in 49 CFR § 171.8, a hazardous substance does not include petroleum, including crude oil or any fraction thereof which is not other specifically listed or designated as such in Appendix A to 49 CFR § 172.101. Therefore, this product does not require a RQ designation. Transport by sea (IMDG) Transport document description : UN1203, GASOLINE, 3, PGII UN Number : UN1203 Page 147 of 156 Page 147 of 156 Page 147 of 156 Page 147 of 156 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 9/12 Proper Shipping Name : GASOLINE Primary Hazard Class : 3 - Flammable liquids Packing Group : PGII Hazard labels (IMDG) : Cargo name listed in 46 CFR 30.25, Table 30.25-1 : Gasolines: Automotive Air transport (IATA) Transport document description : UN1203, Gasoline, 3, PGII UN Number : UN1203 Proper Shipping Name : Gasoline Primary Hazard Class : 3 - Flammable Liquids Packing Group : PGII Hazard labels (IATA) : Section 15: Regulatory information 15.1. US Federal regulations EPA TSCA Status Under TSCA gasoline is a mixture. All components of this mixture are listed on TSCA. SARA Section 313 Supplier Notification This product contains the following toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR 372: CAS number Chemical name Concentration 108-88-3 Toluene 1 - 20% 1330-20-7 Xylenes p- isomers) 1 - 20% 95-63-6 1 - 10% 100-41-4 1 - 10% 110-54-3 n-Hexane 0 - 5% 110-82-7 Cyclohexane 0 - 2% 71-43-2 Benzene 0.1 - 2% 91-20-3 Naphthalene 0.1 - 1% 98-82-8 Cumene 0.1 - 1% This information must be included in all Safety Data Sheets that are copied and distributed for this product. For additional information, see 40 CFR §372.45 Notification About Toxic Chemicals. SARA Section 311/312 Hazard Classes Fire hazard Chronic health hazard Acute health hazard 15.2. International regulations CANADA Unleaded Gasoline (86290-81-5) WHMIS Classification Class B Division 2 - Flammable Liquid Page 148 of 156 Page 148 of 156 Page 148 of 156 Page 148 of 156 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 10/12 National inventories (86290-81-5) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on the Canadian DSL (Domestic Sustances List) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on the Philippines Inventory of Chemicals and Chemical Substances (PICCS) 15.3. US State regulations California Proposition 65 - This product contains a substance or substances known to the state of California to cause cancer and/or reproductive toxicity, not limited to any that may be listed below. Toluene (108-88-3) U.S. - California - Proposition 65 - Carcinogens List No U.S. - California - Proposition 65 - Developmental Toxicity Yes U.S. - California - Proposition 65 - Reproductive Toxicity - Female Yes U.S. - California - Proposition 65 - Reproductive Toxicity - Male No (100-41-4) U.S. - California - Proposition 65 - Carcinogens List Yes U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No Non-significant risk level (NSRL) 54 µg/day (inhalation) Benzene (71-43-2) U.S. - California - Proposition 65 - Carcinogens List Yes U.S. - California - Proposition 65 - Developmental Toxicity Yes U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male Yes Non-significant risk level (NSRL) 6.4 µg/day (oral) Naphthalene (91-20-3) U.S. - California - Proposition 65 - Carcinogens List Yes U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No Non-significant risk level (NSRL) 5.8 µg/day Cumene (98-82-8) U.S. - California - Proposition 65 - Carcinogens List Yes U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No Section 16: Other information Other information : None. NFPA (National Fire Protection Association) NFPA health hazard : 1 NFPA fire hazard : 3 NFPA reactivity : 0 Page 149 of 156 Page 149 of 156 Page 149 of 156 Page 149 of 156 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 11/12 HMIS III Rating Health : 1* Flammability : 3 Physical Hazard : 0 Personal Protection : See section 8 of SDS US OSHA LABEL as specified under 29 CFR §1910.1200 Unleaded Gasoline Total Petrochemicals & Refining USA, Inc. PO Box 674411 Houston, TX 77267-4411 USA Tel. [PHONE REDACTED] or 1-[PHONE REDACTED] Danger Extremely flammable liquid and vapor May be fatal if swallowed and enters airways Causes skin irritation Causes serious eye irritation May cause respiratory irritation May cause drowsiness or dizziness May cause genetic defects May cause cancer Suspected of damaging fertility or the unborn child Causes damage to organs (lung) Causes damage to organs (blood, hematopoietic system [blood forming], kidneys, peripheral nervous system, brain (neurological), nervous system, visual organ (color vision effects), hearing organ (loss of hearing)) through prolonged or repeated exposure Toxic to aquatic life with long lasting effects Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from sparks, open flames, heat, hot surfaces. - No smoking. Keep container closed. Ground/bond container and receiving equipment. Use explosion-proof electrical, lighting, ventilating equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe spray, mist, vapors. Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear flame retardant protective clothing, impermeable protective gloves, eye protection, face protection. If swallowed: Immediately call doctor, poison center. Do NOT induce vomiting. If on skin: Wash with plenty of water. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Specific treatment (see Section 4.1 of SDS or information on this label). If exposed or concerned: Get medical advice/attention. Get medical advice/attention if you feel unwell. Take off contaminated clothing and wash it before reuse. In case of fire: Use Water spray, foam, carbon dioxide (CO2), dry chemical to extinguish. Collect spillage. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. Unknown acute toxicity 19 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation (Vapours)) Supplemental Information Product can accumulate electrostatic charges that may cause fire by electrical discharges. Version : 2.2 Date of issue : July 24, 2015 Page 150 of 156 Page 150 of 156 Page 150 of 156 Page 150 of 156 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 12/12 MSDS ID: UL_GASOLINE SDS REFERENCE NUMBER: RF0029 SDS Template - TOTAL SDS US (GHS HazCom 2012) TPRI Version 4.01 The information contained in this Safety Data Sheet (SDS) is believed by Total Petrochemicals & Refining USA, Inc. (TPRI) to be accurate on the date issued. However, materials may present unknown hazards and should be used with caution. Final determination of suitability and use of any material is the sole responsibility of the user. Neither TPRI nor any of its subsidiaries or affiliated companies assumes any liability whatsoever for the accuracy or completeness of the information contained herein or reliance thereto. If the material is repackaged, the user is responsible and must ensure that proper health, safety and other necessary information is included with the material and/or on the container. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING THE MATERIALS OR THE INFORMATION CONTAINED IN THIS SDS. ALTERATION OF THIS DOCUMENT IS STRICTLY PROHIBITED. Page 151 of 156 Page 151 of 156 Page 151 of 156 Page 151 of 156 ---PAGE BREAK--- Back... Print Page M A T E R I A L S A F E T Y D A T A S H E E T MSDS 700 ITEM NUMBER: 700 - X t r e m e G l e m e VERSION 1 EFFECTIVE DATE: 03/20/01 SUPERCEDES: 00/00/00 PREPARED BY: Ron Cepa IDENTITY (As Used On Label and List): Xtreme Gleme E M E R G E N C Y M E D I C A L Telephone# 1-[PHONE REDACTED] X 009 (24 Hrs) Outside of the U.S.A. Call [PHONE REDACTED] PRODUCT HAZARD RATINGS (HMIS): - Health = Fire = 2, Reactivity = 0, Protective Equipment = B (Rating Legend: - 4 = Extreme, 3 = Serious, 2 = Moderate, 1 = Slight, 0 = Minimal, * = Chronic Hazard) SECTION I Claire Manufacturing TELEPHONE NUMBER FOR INFORMATION : 1-[PHONE REDACTED] 500 Vista Addison DATE PRINTED : 5/18/01 NAME OF PREPARER : Ron Cepa IL 60101 SECTION II - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION Chemical Names CAS # SARA Title III ACGIH OSHA % By Wt. SEC 313 TLV/TWA PEL Ethyl alcohol 64-17-5 No 1000 ppm 1000 ppm 10-20 2-Butoxyethanol 111-76-2 Yes 20 ppm* 25 ppm* 1-5 Page 152 of 156 Page 152 of 156 Page 152 of 156 Page 152 of 156 ---PAGE BREAK--- Liquefied petroleum gas mixture See below No 1-5 Propane 74-98-6 - 1000 ppm NE - n-Butane 106-97-8 - 600 ppm NE - * Skin Balance of ingredients are non-hazardous or below reportable levels. SECTION III - PHYSICAL CHARACTERISTICS Boiling Point: NA Vapor Pressure (psig): 102 @ 130F Specific Gravity (H20=1): <1 Solubility/Water: Predominantly Vapor Density (AIR=1): ND Evaporation Rate (Ether=1): <1 Appearance and Odor: Aerosol spray with characteristic odor. SECTION IV - FIRE AND EXPLOSION HAZARD DATA Aerosol Flammability: Product is not required to be labeled as flammable as described in 16 CFR 1500.3 and 1500.45. Flashpoint: <0F (Propellant); >100F (Concentrate, as established in "Ethyl Alcohol Handbook" by U.S.I.) Flammable Limits - % Volume In Air (Propellant): LEL: 1.9 UEL: 9.5 Extinguishing Media: Carbon dioxide, water spray, foam, or dry chemical. Special Fire Fighting Procedures: Containers should be cooled with water to prevent vapor pressure build up. Use equipment or shielding, as required, to protect personnel from bursting, rupturing or venting containers. Unusual Fire and Explosion Hazards: Fire fighters and others who may be exposed to the products of combustion should be equipped with NIOSH-approved positive pressure self-contained breathing apparatus (SCBA) and full protection clothing. At elevated temperatures (over 54C-130F) containers exposed to direct flame or heat contact should be cooled with water to prevent weakening of container structure. SECTION V - REACTIVITY DATA Stability: Stable Hazardous Polymerization: NA Incompatibility (Materials to Avoid): Oxidizing agents. Page 153 of 156 Page 153 of 156 Page 153 of 156 Page 153 of 156 ---PAGE BREAK--- Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Conditions to Avoid: Keep away from heat, sparks, and flames. Dropping of containers may cause bursting. SECTION VI - HEALTH HAZARD DATA Route(s) of Entry - Inhalation: X Eyes: X Skin: X Ingestion: HAZARDS IDENTIFICATION: EYES: Can cause mild irritation. SKIN: Can cause mild irritation. May cause allergic reactions and sensitization. May be harmful if absorbed through the skin. INHALATION: Irritating to eyes, nose and respiratory tract. Harmful if inhaled. INGESTION: Not hazardous in normal industrial use. Can be fatal if swallowed. CHRONIC EFFECTS/TARGET ORGANS: Nervous system. Liver. Kidneys. Heart and/or circulatory system. EMERGENCY AND FIRST AID PROCEDURES: EYES: Immediately flush with plenty of water for at least 15 minutes. Get prompt medical attention. SKIN: Wash with soap and plenty of water. INHALATION: Remove to fresh air. If develop, seek immediate medical attention. If not breathing, give artificial respiration. INGESTION: Get immediate medical attention. Do NOT induce vomiting unless directed by medical personnel. Never give anything by mouth to an unconscious person. CARCINOGENICITY: No regulated ingredients. TOXICITY INFORMATION: 2-Butoxyethanol: 2-butoxyethanol may affect the liver and kidneys and may increase red blood cell hemolysis. SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND Page 154 of 156 Page 154 of 156 Page 154 of 156 Page 154 of 156 ---PAGE BREAK--- USE Releases or Spills: Remove all sources of ignition and ventilate area. Soak up spill with an inert absorbent and place into a designated disposal container. Consult local regulatory agency for proper disposition of material. Waste Disposal Method: Do not puncture or incinerate containers. When contents are depleted continue to depress button until all gas is expelled. Dispose of container in accordance with local, state, and federal regulations. Handling And Storing: Avoid breathing vapor. Keep away from heat, sparks and flame. Use with adequate ventilation. Do not puncture or incinerate containers. Do not expose to direct sunlight or store at temperatures above 120F (48.9C). Store as Level 1 Aerosol (NFPA 30B). Do not spray into face, eyes or toward other people. Other Precautions: Please read and follow the directions on the product label; they are your best guide to using this product in the most effective way, and give the necessary safety precautions to protect your health. SECTION VIII - EMPLOYEE PROTECTION Respiratory Protection (Type): None required if good ventilation is maintained. If exposure exceeds occupational exposure limits (Sec. II), use a NIOSH approved respirator to prevent overexposure. Ventilation: General ventilation is adequate under normal conditions, mechanical ventilation is optional. Protective Gloves: Chemical resistant gloves are recommended - consult glove manufacturer to determine the proper type for a specific operation. Eye Protection: Safety glasses are recommended. Other Protective Clothing or Equipment: Wear impervious clothing to prevent skin contact. Work/Hygienic Practices: Ensure strict sanitary conditions are conformed to when working around chemicals. Page 155 of 156 Page 155 of 156 Page 155 of 156 Page 155 of 156 ---PAGE BREAK--- Protective clothing and equipment should be in accordance with 29 CFR 1910.132 and CFR 1910.133. SECTION IX - OTHER REGULATORY CONTROLS FEDERAL: Toxic Substance Control Act (TSCA): Ingredients of this product are listed on the EPA/TSCA Inventory of Chemical Substances. SECTION X - TRANSPORTATION REQUIREMENTS (D.O.T. CLASSIFICATION) Shipping Name: Consumer Commodity Hazard Class: ORM-D NG-- Negligible NA-- Not Applicable NE-- Not Established UN-- Unavailable ND-- Not Determined While the information set forth herein is believed to be accurate as of the date hereof, the Company makes no warranty or guarantee, express or implied, and disclaims all liability arising out of the use of this information. EFFECTIVE DATE: 01/15/01 SUPERCEDES: 00/00/00 PREPARED BY: Ron Cepa Page 156 of 156 Page 156 of 156 Page 156 of 156 Page 156 of 156