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Safety Data Sheets Gov't Center Building Maintenance Gov't Center 11/16/2015 ---PAGE BREAK--- Safety Data Sheet Index Binder: Maintenance Gov't Center - Gov't Center Building #022 Solvent Based Carpet Seam Sealer Capitol USA, LLC 08/11/2006 8 07961 CATERPILLAR DIESEL ENGINE ANTIFREEZE/COOLANT 107-21-1 TEXACO Lubricants Company, NA 12/05/2000 10 108 LT.OAK OIL-BASED PUTTY COLOR PUTTY CO., INC. 01/01/2011 20 3M Dust Remover AV152A, AV152A-B, AV152B 3M - Stationery & office Supplies 11/18/2014 23 3M Fire Block Sealant FB 136 3M - Industrial Adhesives and Tapes 08/18/2014 32 3X676 - Cylinder Propane Fuel 74-98-6 BERNZ-O-MATIC 02/03/2003 43 42272, 42230, 42210, 42201 Scrubs-in-A- Bucket in a Pack Waterless Hand Cleaner Towel Dymon - ITW 03/01/2004 44 97673 TEF-GEL Lawson Products, Inc. 02/11/2014 50 Adhesivo Bond n Seal Lawson Products, Inc. 07/24/2001 58 AIRLIFT FRESH SCENT (AEROSOL) Spartan Chemical Company, Inc. 05/01/2015 62 AP 2000 Lawson Products, Inc. 10/31/2003 67 Ban-Rust Lawson Products, Inc. 03/11/2013 71 Belt Grip Lawson Products, Inc. 01/04/2014 75 Blow Off Air Duster 152a 75-37-6 A.V.W. Inc. 07/11/2013 79 Blue Marking Chalk Kenson 86 Bostik Never Seez NSBT-8 BOSTIK FINDLEY, INC. 07/19/2005 89 Brr-aker lawson drummond 94 BRRR-Eaker Drummond American, A Lawson Products Company 09/04/2009 104 BRRR-Eaker Drummond, A Lawson Brand 07/19/2012 111 BRRR-Eaker Drummond, A Lawson Brand 07/19/2012 115 C-Thru Glass Cleaner Lawson Products, Inc. 05/02/2014 119 CAT DIESEL ENGINE OIL (DEO) CF SAE 40 Exxon Mobil Corporation 09/29/2008 123 CAT DIESEL ENGINE OIL SAE 10W-30 Imperial Oil Products Division 06/22/2011 131 Clear Out State Chemical Division – State 10/01/2013 140 Product Name CAS Number Manufacturer Version Date Page Page 2 of 871 Page 2 of 871 Page 2 of 871 Page 2 of 871 ---PAGE BREAK--- Industrial Products Clorox Disinfecting Wipes - Fresh Scent Clorox Company of Canada, Ltd. 01/05/2015 142 Cold Pipe Insulation Spray Lawson Products, Inc. 01/14/2008 150 Cold Pipe Insulation Spray Lawson Products, Inc. 02/26/2014 156 Cold Pipe Insulation Spray Lawson Products, Inc. 03/03/2011 159 COLEMAN POWERMATE 10w30 MOTOR OIL CAM2 Oil Products Company 08/25/1998 162 CONTRACTORS Interior Latex Satin Finish, Extra White THE SHERWIN-WILLIAMS COMPANY 07/25/2013 166 Copper Anti-Seize Lawson Products, Inc. 05/02/2005 170 Copper Anti-Seize Tape Lawson Products, Inc. 03/11/2013 173 Covers Up Zinsser Company, Inc. 09/08/2008 176 DAP HOUSEHOLD SILICONE ADHESIVE CLEAR, 698 DAP, INC. 03/25/2004 182 DECAL & LABEL REMOVER Lawson Products, Inc. 03/09/2015 190 Decal Remover Lawson Products, Inc. 03/11/2013 201 DispenseAGasket Black Silicone Sealant Lawson Products, Inc. 05/30/2013 205 EASY SOLUTIONS - Household Adhesive 64-17-5 DAP, INC. 10/16/2000 218 Elmer's China/Glass Cement Elmer's Products, Inc. 01/01/2004 225 ELMER'S GLUE-ALL Elmer's Products, Inc. 05/24/2011 232 Expunge Lawson Products, Inc. 07/29/2014 237 Expunge Lawson Products, Inc. 02/03/2014 241 Fill And Seal 120Z Expanding Foam Sealant Dow Chemical Company 01/31/2008 245 Flexseal Dispense-A-Gasket RTV Black Silicone Drummond, A Lawson Brand 10/30/2014 258 Flush-Off Spray Orange Degreaser Lawson Products, Inc. 10/07/2003 269 FOAMING AC COIL CLEANER ZEP Inc. 07/18/2008 273 Foamy Orange Citrus Degreaser Lawson Products, Inc. 03/14/2014 276 Food Grade Belt Dressing CRC Industries, Inc. 02/12/2014 280 Full Blast Lawson Products, Inc. 07/22/2014 288 GE Silicone I 100% Silicone Rubber Sealant GE Silicones 02/25/2003 291 Gloss UrathaneEnamel Pittsburgh Paints 301 GORILLA GLUE GORILLA GLUE COMPANY 08/01/2005 309 Gorilla Super Glue Gel The Gorilla Glue Company 02/05/2013 313 Product Name CAS Number Manufacturer Version Date Page Page 3 of 871 Page 3 of 871 Page 3 of 871 Page 3 of 871 ---PAGE BREAK--- Gorilla Wood Glue The Gorilla Glue Company 08/26/2014 317 Graffiti Away Towels TRI-CHEM CORPORATION 12/14/2005 322 Great Stuff Dow Chemical Company 04/07/2008 325 Green Envy Driveway Cleaner & Degreaser SUNNYSIDE CORPORATION 08/26/2008 338 GROOVY Drummond American, A Lawson Products Company 07/06/2010 341 Hercules Megaloc HCC Holdings, Inc. 02/05/2015 344 IMPERVEX LATEX HIGH GLOSS METAL & WOOD ENAMEL BENJAMIN MOORE & COMPANY 02/24/2011 351 Industrial Enamel – VOC Complying, Pure White THE SHERWIN WILLIAMS COMPANY 03/02/2010 360 Industrial Enamel B54 Series THE SHERWIN WILLIAMS COMPANY 04/01/2005 364 Industrial Enamel B54W101 Sherwin Williams 369 Interior Wood Finish, Polyurathane Stain Benjamin Moore 373 Interior/Exterior, Acrylic Laytex, Alkali Resistant Primer (WHITE) Pittsburgh Paints (PPG) 383 Iron Clad Quick Dry Industrial Enamel BENJAMIN MOORE & COMPANY 03/28/1994 390 ISOPROPYL ALCOHOL (IPA) 50%, 70%, 91% AND 99% IPA 67-63-0 Cumberland Swan 03/01/2010 393 JOHNSON SHINE-UP (LEMON-AEROSOL) S.C. JOHNSON WAX 09/09/1994 396 Klean-Strip Industrial Maintenance Coating Thinner W. M. Barr 04/13/2015 399 KOPR-SHIELD JET-LUBE, INC. 07/13/2012 408 KRUD KUTTER Concrete Clean and Etch SUPREME CHEMICALS OF GEORGIA, INC. 08/28/2007 417 Kwik Grip Epoxy Lawson Products, Inc. 05/04/2005 425 Kwikee Penetrant with A/T plus Moly Lawson Products, Inc. 12/13/2010 434 Kwikut Lawson 440 LAWSON UNI-SOLV Paint Preparation Solvent Lawson Products, Inc. 09/19/2014 454 Light Oil Lubricant Lawson Products, Inc. 05/28/2013 467 Liquid Anti Static Spray Lawson Products, Inc. 03/16/1993 471 Loctite Power Grab All Purpose Adhesive HENKEL CONSUMER ADHESIVES 02/01/2009 475 Loctite Super Glue Gel 10g HENKEL CONSUMER ADHESIVES 03/18/2010 479 Product Name CAS Number Manufacturer Version Date Page Page 4 of 871 Page 4 of 871 Page 4 of 871 Page 4 of 871 ---PAGE BREAK--- Loxon Masonry Coating System Sherwin Williams 484 LPS ThermaPlex Hi-Load Bearing Grease ITW Professional Brands 02/25/2015 495 Lubri-Temp Lawson Products, Inc. 10/30/2014 501 Lubri-Temp Anti Seize Lawson Products, Inc. 03/25/2014 505 Metal Repair Epoxy Cartridge Part A Lawson Products, Inc. 03/17/2003 508 Metal Repair Epoxy Cartridge Part B Lawson Products, Inc. 03/17/2003 511 Metalastic DTM Sherwin Williams 514 mineral spirits SUNNYSIDE CORPORATION 11/08/2013 518 MINWAX Stainable Wood Filler MINWAX Company 05/21/2015 530 MOBIL RARUS 427 Exxon Mobil Corporation 03/16/2015 539 MOBILGREASE XHP 222 SPECIAL Exxon Mobil Corporation 09/29/2015 549 MOBILGREASE XHP 222 SPECIAL Exxon Mobil Corporation 03/17/2015 559 Mothers Mag & Aluminum Polish MOTHERS-POLISHES-WAXES- CLEANERS 04/03/2007 569 MultiMist Penetrating Thread Locker Henkel Corporation 08/29/2014 577 Nail Hole & Crack Repair Akona Manufacturing, LLC. 07/01/2008 583 OATEY PLUMBERS PUTTY OATEY CO. 06/10/2005 585 Old Ceiling Tile Paint White Lawson Products, Inc. 01/23/2014 589 ONETIME Lightweight Spackling Compound Red Devil Incoporated 593 Orange Buoy State Chemical Division – State Industrial Products 10/01/2014 595 Orange Scrubber Lawson Products, Inc. 10/15/2001 597 Pennzoil Premium Grease Wheel Bearing 707L Red Shell Canada Products 12/10/2014 601 Pipe Coverage, Cold Pipe Insulation Spray Lawson 608 Pitt-Tech Acrylic High Gloss 90-374 PPG 613 Plastic Lead Substitute Genova Industries 01/24/2003 620 PolyShades, Stain and Polyurathane in 1 step Minwax 624 Powr Off Electrical Contact Cleaner Lawson Products, Inc. 09/19/2014 636 Pro Classic Interior Acrylic Latex Sherwin Williams 650 PRO INDUSTRIAL Pre-Catalyzed Waterbased Epoxy Eg-Shel, Extra White THE SHERWIN WILLIAMS COMPANY 04/21/2010 654 ProMal Zone Marking Paint YELLOW Sherwin Williams 658 Product Name CAS Number Manufacturer Version Date Page Page 5 of 871 Page 5 of 871 Page 5 of 871 Page 5 of 871 ---PAGE BREAK--- PROMAR 200 Interior Latex Eg-Shel Enamel, Extra White THE SHERWIN-WILLIAMS COMPANY 04/16/2015 663 PROMAR 400 Interior Latex Gloss Enamel, Extra White THE SHERWIN WILLIAMS COMPANY 03/05/2010 667 Purple Primer Oatey 671 Rapid Repair Epoxy Lawson Products, Inc. 07/10/2012 681 REGAL PREMIUM INTERIOR LATEX MATTE FINISH BENJAMIN MOORE & COMPANY 06/03/2009 685 ROUGH TOUCH SCRUBS-IN-A-BUCKET Dymon - ITW 12/13/2001 693 RTV Silicone L.V. Red Lawson Products, Inc. 10/07/2008 695 Rubber Adhesive Devcon Consumer Products 02/14/2001 701 Rust Oleum Premium Stops Rust Protective Enamel Spray 7721 Fresh Blue Rust-Oleum Corporation 02/07/2007 706 Rustolium Rusty Metal Primer Rustolium 709 SCREEN CLEAN 19 OZ NW Lawson Products, Inc. 05/07/2003 717 Screen Cleaner Rotanium 720 SEALICONE CLEAR 7-1/4 OZ NW Lawson Products, Inc. 02/06/2014 724 Select Deicer Lawson Drummond 728 Sikaflex 15LM (All Colors) SIKA CORPORATION 03/09/2005 732 Silicone Lubricant Lawson Products, Inc. 07/08/2013 737 SILICONE LUBRICANT & MOLD RELEASE ZEP Inc. 11/05/2009 741 Sluff Snowplow Treatment Drummond, A Lawson Brand 09/19/2014 744 Smoke Test CRC Industries, Inc. 11/17/2014 755 Specseal Firestop Sealant ALLIED RUBBER & GASKET COMPANY, INC. 03/29/2010 762 SPECTRUM 2 BLACK 30 CTG FIXED NOZZLESPECTREM 2 BLACK 30 CTG FIXED NOZZLE Tremco Incorporated 09/01/2006 764 SPRAY-ON ACOUSTIC TEXTURE (DRY MIX) Homax Products, Inc. 01/15/2003 770 Stainless Steel Spray Coating Lawson Products, Inc. 04/08/2002 773 STATICIDE General Purpose ACL Incorporated 03/13/2015 777 SUPER SANI CLOTH GERMICIDAL DISPOSABLE WIPE PDI-Professional Disposables, Inc 06/01/2004 784 Tefgel Lawson Products, Inc. 09/17/2014 786 TefGel Penetrating Gel Gear Lubricant with Lawson Products, Inc. 02/11/2014 790 Product Name CAS Number Manufacturer Version Date Page Page 6 of 871 Page 6 of 871 Page 6 of 871 Page 6 of 871 ---PAGE BREAK--- P.T.F.E. Tel-X Plus Chemsearch 798 TG-11 Detector Test Gas CRC Company 802 Three In One Multi Purpose Oil 64742-52-5 WD-40 Company 02/01/2003 809 Turtle Wax Rubbing Compound Heavy Duty Cleaner Turtle Wax, Inc. 05/14/2015 811 UNITED 101 MOISTURE BARRIER United Laboratories Inc. 02/06/2015 817 UNITED 107 AEROSOL SAFETY SOLVENT United Laboratories Inc. 02/21/2012 819 United 190 UP WHITE Acoustical Ceiling Tile Whitener United Laboratories Inc. 03/17/2003 821 UNITED 555 DUO-ZYME United Laboratories Inc. 05/16/2013 823 UVP-500 State Chemical Division – State Industrial Products 03/01/2014 825 Vinylize Lawson 827 Waterplug Thoro 830 WHITE CLEAN METAL PRIMER Rust-Oleum Corporation 06/03/2002 836 WHITE LIGHTENING J.W. ETC, INC. 04/14/1993 844 Windshield De-Icer Lawson Products, Inc. 10/30/2014 848 Wire Kote Lawson Products, Inc. 03/11/2011 852 Xtreme Gleme Claire 856 Zoom Spout Oiler LA-CO INDUSTRIES, INC. 02/13/2013 866 Product Name CAS Number Manufacturer Version Date Page Page 7 of 871 Page 7 of 871 Page 7 of 871 Page 7 of 871 ---PAGE BREAK--- Capitol’s 022 Solvent Based, Flammable Carpet Seam Seal er is specially formulated to prevent edge raveling and seal seams of most commer cial and outdoor carpets. 022 is fast setting and water proof. 022 is compatible with most carpet backings. Do not use for sealing PVC backed products, or products where seam sealers are not required. Excellent for direct glue and double glue applications. Description: Solvent Based Carpet Seam Sealer Flammability: Flammable Clean Up: Safety solvent or mineral spirits. Shelf Life: One year in closed container. Limitations: Do not use for PVC or Vinyl Backed Products. Packaging: • 1 Quart (12/case) • One Half Pint (12/case) For The Installation Of: • ActionBac® • Jute • Latex Unitary • Wovens • Rubber Backed • Urethane (Attached Cushion) Estimated Coverage: • 160 lineal feet per 8 ounce bottle • 2,560 lineal feet per gallon Directions: Remove inner seal before using. Application: Apply an 1/8" bead with dispenser tip at carpet primary backing and immediately butt opposite cut. If carpet edges tend to peak, use board or weights to hold in place until dry. Adhesive may temporarily swell rubber back and cause a “peaking” effect - press down after allowing 30-60 minutes drying time. CLEAN UP: Use a safety solvent or mineral spirits. DO NOT USE ON PVC BACKED CARPETS OR VINYL SHEET GOODS. First Aid: First Aid: Skin- Soap and water. Eyes- Flush with water, lifting upper and lower lids occasionally. Ingestion- Do not induce vomiting. Call physician or transport to an emergency facility. Inhalation- If affected, remove individual to fresh air. Use only in well ventilated areas. Caution: FLAMMABLE! Use only in well ventilated areas. Do not use around sources of ignition such as open flames, pilot lights, etc. Do not store at temperatures above 120° F, or in direct sunlight. Do not incinerate container. Wrap empty container and put in trash collections. KEEP OUT OF REACH OF CHILDREN Capitol USA, LLC 300 Cross Plains Blvd. • PO Box 2023 Dalton, GA 30722 [PHONE REDACTED] • Fax: [PHONE REDACTED] Jim Walker ProSeries TechLine [PHONE REDACTED] Website www.capitolusa.com USA Capitol Capitol the art of innovation ® Specification Specification product Capitol Capitol USA the art of innovation ® #022 Solvent Based Carpet Seam Sealer FLAMMABLE ---PAGE BREAK--- Material Safety Data Sheet Material Safety Data Sheet October 2000 Capitol USA, LLC 300 Cross Plains Blvd. • PO Box 2023 Dalton, GA 30722 [PHONE REDACTED] • Fax: [PHONE REDACTED] Jim Walker ProSeries TechLine [PHONE REDACTED] Website www.capitolusa.com #022 Solvent Based Carpet Seam Sealer SECTION I - PRODUCT IDENTIFICATION Manufacturer’s Name: Capitol USA, LLC Address: 300 Cross Plains Blvd. • Dalton, GA 30720 Telephone 1-[PHONE REDACTED] Emergency Phone: [PHONE REDACTED] Generic ID: Rubber Adhesive in Solvent Sol ution DOT Hazard Classiﬁcation: Class 3 Flammible Liquid, UN1133 Product Identity: #022 Solvent Based Carpet Seam Sealer HMIS: H=1 F=3 R=0 SECTION II - HAZARDOUS COMPONENTS %(weight) PEL TLV Lacolene 62.3 400 ppm 400 ppm (CAS# 64742-89-8) Toluene 10.4 100 ppm 50 ppm (CAS# 108-88-3) SARA TITLE III Reportable: Lacolene, Toluene SECTION III - PHYSICAL DATA Initial Boiling Point: 185°F - 220°F. Vapor Pressure: 38.0 mm Hg @ 68°F. Vapor Density (Air = 1.0 : 3.6). Speciﬁc Gravity: 0.71 @ 60°F. Percent Volatiles: 72.7%. G/L VOC (Calculated): 553.0. SECTION IV - FIRE AND EXPLOSION DATA Flash Point: 20°F - 32°F. Explosive Limit (Product): 1.2%. Extinguishing Media: Foam, CO2, Dry Chemical. HAZARDOUS DECOMPOSITION PRODUCTS: May form toxic materials: carbon dioxide and carbon mon oxide, various hydrocarbons of unknown structure. SPECIAL FIRE FIGHTING PROCEDURES: Water may be used to keep ﬁre-exposed containers cool until ﬁre is out. Wear self-contained breathing apparatus with full facepiece operated in pressure-demand or other positive pressure mode when ﬁghting ﬁres. UNUSU AL FIRE & EXPLOSION HAZARDS: Never use weld ing or cutting torch on or near cans (even empty) be cause resultant pressure could rupture. Empty cans should be incinerated. SECTION V - HEALTH HAZARD DATA Permissible Exposure Level: 400 ppm. Threshold Limit Value: 400 ppm. EFFECTS OF EXPOSURE: Eyes- Can cause irritation, redness, tearing, blurred vision. Skin- Prolonged or repeated contact can cause moderate irri tation, defatting, dermatitis. Breathing- Excessive inha lation of vapors can cause nasal and respiratory irrita tion, dizziness, weakness, fatigue, nausea, headache, and even First Aid: Skin- Soap and wa ter. Eyes- Flush with water , lifting upper and lower lids occasionally. Ingestion- Do not induce vomiting. Call physician or transport to an emergency facility. In halation- If affected, remove individual to fresh air. Use only in well ventilated areas. SECTION VI - REACTIVITY DATA Stability: Stable. Incompatibility: None. Hazardous De composition: None. Hazardous Polymerization: Can not Occur. Conditions To Avoid: Strong Oxidizing Agents, Open Flame, and Excessive Heat SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RE LEASED OR SPILLED: Absorb liquid on paper, ver miculite, ﬂoor absorbent, or other absorbent material and transfer to hood. Allow volatile portion to evapo rate in hood. Allow sufﬁcient time for vapors to com pletely clear hood duct work. Dispose of remaining material in accordance with applicable regulations. SECTION VIII - PROTECTIVE EQUIPMENT VENTILATION: Adequate ventilation is essential to prevent vapor build-up. Open all available windows and entrances to insure good ventilation. RESPIRA TOR PROTECTION: Adequate ventilation is normally sufﬁcient. If eyes begin to water or dizziness or head aches are experienced, increase fresh air supply, wear an NIOSH approved respirator, or leave the area. PRO TECTIVE GLOVES: Wear protective gloves to prevent skin contact. EYE PROTECTION: Wear glasses or pro tective goggles to avoid splashes. OTHER PROTEC TIVE EQUIPMENT: None required. WASH HANDS THOROUGHLY WITH SOAP AND WATER. SECTION IX - SPECIAL PRECAUTIONS Protect from freezing. Use only in applications as stat ed on the label. Do not take internally. Close container after each use. Avoid skin and eye contact. Extinguish any open ﬂames, sparks, or other sources of iginition. Keep away from excessive heat. Ventilation with fresh air, including open doors and windows should be observed during any ﬂooring in stallation. Operate HVAC systems at 100% fresh air in take before, during and after installation to eliminate lingering odors or particulate matter. KEEP OUT OF REACH OF CHILDREN Capitol USA believes the data set forth herein is accu rate as of the date hereof, and makes no warranty with respect thereto and expressly disclaims all liability for reliance thereon. Such data are offered solely for your consideration, investigation and veriﬁcation. ---PAGE BREAK--- Page 10 of 871 Page 10 of 871 Page 10 of 871 Page 10 of 871 ---PAGE BREAK--- Page 11 of 871 Page 11 of 871 Page 11 of 871 Page 11 of 871 ---PAGE BREAK--- Page 12 of 871 Page 12 of 871 Page 12 of 871 Page 12 of 871 ---PAGE BREAK--- Page 13 of 871 Page 13 of 871 Page 13 of 871 Page 13 of 871 ---PAGE BREAK--- Page 14 of 871 Page 14 of 871 Page 14 of 871 Page 14 of 871 ---PAGE BREAK--- Page 15 of 871 Page 15 of 871 Page 15 of 871 Page 15 of 871 ---PAGE BREAK--- Page 16 of 871 Page 16 of 871 Page 16 of 871 Page 16 of 871 ---PAGE BREAK--- Page 17 of 871 Page 17 of 871 Page 17 of 871 Page 17 of 871 ---PAGE BREAK--- Page 18 of 871 Page 18 of 871 Page 18 of 871 Page 18 of 871 ---PAGE BREAK--- Page 19 of 871 Page 19 of 871 Page 19 of 871 Page 19 of 871 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET (INFORMATION SUPPLIED IN ACCORD WITH OSHA FORM 174) COLOR PUTTY CO., INC. Effective Date: 01/01/11 Emergency Telephone Number: [PHONE REDACTED] Technical Information Number: [PHONE REDACTED] SECTION 1 PRODUCT IDENTIFICATION PRODUCT IDENTIFICATION : 108 LT.OAK OIL-BASED PUTTY MANUFACTURER: Color Putty Co., Inc. ADDRESS: 121 W.7th Street Monroe, WI 53566 TELEPHONE NUMBER: [PHONE REDACTED] FAX NUMBER: [PHONE REDACTED] SECTION 2 HAZARDOUS INGREDIENTS/IDENTITY INFORMATION IDENTIFIABLE COMPONENTS: CAS# H.S# OSHA PEL ACGIH TLV None N/A N/A N/A N/A SECTION 3 PHYSICAL/CHEMICAL CHARACTERISTICS BOILING POINT: N/A EVAPORATION RATE: N/A MELTING POINT: N/A (Butyl Acetate=1) SOLUBILITY IN WATER: Insoluble VAPOR PRESSURE: N/A APPEARANCE: Colored putty VAPOR DENSITY: N/A ODOR: Mild SPECIFIC GRAVITY: 2.10 SECTION 4 FIRE AND EXPLOSION HAZARD DATA FLASH POINT: >200F AUTOIGNITION TEMP: N/A LOWER EXPLOSIVE LIMIT: N/A UPPER EXPLOSIVE LIMIT: N/A SPECIAL FIRE & EXPLOSIVE HAZARDS: None SPECIFIC FIREFIGHTING PROCEDURES: None EXTINGUISHING MATERIAL: CO2, Dry chemical, Foam, Water, Fog SECTION 5 REACTIVITY DATA STABILITY: Stable CONDITIONS TO AVOID: N/A INCOMPATIBILITY: None Known HAZARDOUS DECOMPOSITION PRODUCTS: Normal decomposition products ie.,CO x, NO x HAZARDOUS POLYMERIZATION: Will not occur Page 1 of 3 Page 20 of 871 Page 20 of 871 Page 20 of 871 Page 20 of 871 ---PAGE BREAK--- SECTION 6 HEALTH HAZARD DATA POTENTIAL HEALTH EFFECTS FROM OVEREXPOSURE: EYE CONTACT: May cause eye irritation; flush eyes: contact a physician SKIN CONTACT: N/A; Wash with soap & water INHALATION: N/A; Remove to fresh air INGESTION: May irritate mouth, throat & stomach; Do not induce vomiting; Contact a physical PRIMARY ROUTES OF ENTRY: Skin contact; Inhalation; Ingestion MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT: None Known SECTION 7 PRECAUTIONS FOR SAFE HANDLING & USE STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Normal; scoop up product DISPOSAL: Dispose of in accordance with Federal, State, and Local regulations EPA WASTE CODE: None if discarded (40 CFR 261) HANDLING INFORMATION: Keep out of the reach of children; avoid prolonged or repeated skin contact if irritation occurs, avoid eye contact. STORAGE INFORMATION: Keep containers sealed when not in use; store in a cool area. OTHER PRECAUTIONS: None SECTION 8 CONTROL MEASURES ENGINEERING CONTROLS: Good mechanical ventilation and local exhaust RESPIRATORY CONTROLS: None required under normal usage and adequate ventilation EYE PROTECTION: N/A SKIN PROTECTION: Gloves recommended if irritation occurs OTHER PRACTICES & EQUIPMENT: N/A WORK/HYGENIC PRACTICES: Clean hands with soap & water after use. SECTION 9 REGULATORY INFORMATION U.S.FEDERAL REGULATIONS: AS FOLLOWS: OSHA: Hazardous by definition of Hazard Communication Standard (29 CRF 1910.1200) SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. No SARA Section 313 chemicals in this product are to be reported. TOXIC SUBSTANCES CONTROL ACT: This product contains the following chemical substances subject to the reporting requirements of TSCA 12 if exported from the United States: No information is available. Page 2 of 3 Page 21 of 871 Page 21 of 871 Page 21 of 871 Page 21 of 871 ---PAGE BREAK--- NEW JERSEY RIGHT-T0-KNOW: The following materials are non-hazardous, but among the top five components in this product: Chemical Name CAS # Calcium Carbonate Proprietary Ground Limestone Proprietary Soybean Oil Proprietary Naphthienic Proprietary Titanium Dioxide 13463-67-7 CALIFORNIA PROPOSITION 65: WARNING: The chemical(s) noted below and contained in this product are known to the state of California to cause cancer, birth defects or other reproductive harm: No Proposition 65 chemicals are known to exist in this product. RIGHT TO KNOW: The following non-hazardous ingredients are present in the product at greater than Chemical Name CAS # Calcium Carbonate Proprietary Soybean Oil Proprietary Ground Limestone Proprietary HMIS RATING: Health: 0 Flammability: 0 Reactivity: 0 NOTICE: The information herein is presented in good faith and believed to be accurate as of the effective date shown above. However, no warranty, expressed or implied, is given. Regulatory requirements are subject to change and may differ from one location to another. It is the buyer’s responsibility to ensure that its activities comply with numerous federal, state or provincial, and local laws and regulations. Page 3 of 3 Page 22 of 871 Page 22 of 871 Page 22 of 871 Page 22 of 871 ---PAGE BREAK--- 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14 Page 1 of 9 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: the information is copied in full with no changes unless prior written agreement is obtained from 3M, and neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 19-7982-2 Version Number: 6.00 Issue Date: 11/18/14 Supercedes Date: 06/30/09 SECTION 1: Identification 1.1. Product identifier 3M(TM) Dust Remover AV152A, AV152A-B, AV152B Product Identification Numbers 44-0051-5415-6, 70-0050-0173-3, 70-0050-0269-9, 70-0050-1903-2, 70-0050-2436-2, 70-0050-3890-9, 70-0050-4373-5, 70- 0050-4565-6, 70-0050-4715-7, 70-0050-7309-6, 70-0050-7316-1, 70-0050-7986-1, 70-0050-8052-1, 70-0051-0911-4, 70- 0051-1956-8, 70-0051-2011-1, 70-0051-2013-7, 70-0051-2070-7, 70-0051-3321-3, 70-0051-4224-8, 70-0051-4480-6, 70- 0051-4540-7, 70-0051-6293-1, 70-0051-6628-8, 70-0051-6856-5, 70-0713-0457-3, 70-0713-0458-1, 70-0713-2085-0, 70- 0713-2286-4, 70-0713-5096-4, 70-0713-6798-4, 70-0713-7295-0, 70-0713-8144-9, 70-0713-8166-2, 70-0713-9180-2, 70- 0713-9333-7, 70-0713-9390-7, 70-0714-1472-9, 70-0714-1595-7, 70-0714-2146-8, 70-0714-2147-6, 70-0714-2212-8, 70- 0714-2417-3, 70-0714-2418-1, 70-0714-2419-9, 70-0714-7652-0, 70-0714-8282-5, 70-0714-8283-3, 70-0714-8298-1, 70- 0714-8977-0, 70-0714-9081-0, 70-0714-9437-4, 70-0715-0658-1 1.2. Recommended use and restrictions on use Recommended use Compressed gas duster. 1.3. Supplier’s details MANUFACTURER: 3M DIVISION: Stationery and Office Supplies Division ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-[PHONE REDACTED]) 1.4. Emergency telephone number 1-[PHONE REDACTED] or (651) 737-6501 (24 hours) SECTION 2: Hazard identification 2.1. Hazard classification Flammable Aerosol: Category 2. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (central nervous system): Category 3. 2.2. Label elements Signal word Danger Page 23 of 871 Page 23 of 871 Page 23 of 871 Page 23 of 871 ---PAGE BREAK--- 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14 Page 2 of 9 Symbols Flame I Exclamation mark I Health Hazard I Pictograms Hazard Statements Flammable aerosol. May cause drowsiness or dizziness. Causes damage to organs: cardiovascular system I Precautionary Statements Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF exposed: Call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label). Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Keep container closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 2.3. Hazards not otherwise classified May cause frostbite. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt 1,1-DIFLUOROETHANE 75-37-6 > 99.65 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. Page 24 of 871 Page 24 of 871 Page 24 of 871 Page 24 of 871 ---PAGE BREAK--- 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14 Page 3 of 9 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get medical attention. Skin Contact: Thaw frosted skin with lukewarm water. Do not rub affected area. Get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbonyl Fluoride During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Fluoride During Combustion 5.3. Special protective actions for fire-fighters When fire fighting conditions are severe and total thermal decomposition of the product is possible, wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. Page 25 of 871 Page 25 of 871 Page 25 of 871 Page 25 of 871 ---PAGE BREAK--- 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14 Page 4 of 9 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with detergent and water. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not breathe thermal decomposition products. Do not use in a confined area with minimal air exchange. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments 1,1-DIFLUOROETHANE 75-37-6 CMRG TWA:1000 ppm 1,1-DIFLUOROETHANE 75-37-6 AIHA TWA:2700 mg/m3(1000 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection No chemical protective gloves are required. Page 26 of 871 Page 26 of 871 Page 26 of 871 Page 26 of 871 ---PAGE BREAK--- 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14 Page 5 of 9 Respiratory protection Use a positive pressure supplied-air respirator if there is a potential for over exposure from an uncontrolled release, exposure levels are not known, or under any other circumstances where air-purifying respirators may not provide adequate protection. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece supplied-air respirator For questions about suitability for a specific application, consult with your respirator manufacturer. Thermal hazards Wear cold insulating gloves/face shield/eye protection. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Gas Odor, Color, Grade: Clear, colorless with slight ethereal odor. Odor threshold No Data Available pH Not Applicable Melting point Not Applicable Boiling Point -13 ºF Flash Point < -50 ºF [Details: consumer aerosol does not exhibit a flame projection, therefore it is not determined to be flammable as defined in 16 CFR, Section 1500.3(c)(6)(viii).] Evaporation rate Not Applicable Flammability (solid, gas) Flammable Aerosol: Category 2. Flammable Limits(LEL) 3.9 % volume Flammable Limits(UEL) 16.9 % volume Vapor Pressure 87 psia 77 ºF] Vapor Density 2.4 [Ref Std: AIR=1] Density 0.9 g/cm3 [Details: Liquid] Specific Gravity 0.9 [Ref Std: WATER=1] [Details: Liquid] Solubility In Water 0.28 % Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature 849 ºF Decomposition temperature Not Applicable Viscosity Not Applicable SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Page 27 of 871 Page 27 of 871 Page 27 of 871 Page 27 of 871 ---PAGE BREAK--- 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14 Page 6 of 9 Sparks and/or flames 10.5. Incompatible materials Alkali and alkaline earth metals 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. Extreme heat arising from situations such as misuse or equipment failure can generate hydrogen fluoride as a decomposition product. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation. Skin Contact: Frostbite: may include intense pain, discoloration of skin, and tissue destruction. Eye Contact: Frostbite: may include intense pain, clouding of the cornea, redness, swelling, and blindness. Ingestion: No health effects are expected. Target Organ Effects: Single exposure may cause: Central Nervous System (CNS) Depression: may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: may include irregular heartbeat faintness, chest pain, and may be fatal. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or Page 28 of 871 Page 28 of 871 Page 28 of 871 Page 28 of 871 ---PAGE BREAK--- 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14 Page 7 of 9 the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Inhalation- Gas(4 hr) No data available; calculated ATE > 50,000 ppm 1,1-DIFLUOROETHANE Inhalation- Gas (4 hours) Rat LC50 > 437,000 ppm 1,1-DIFLUOROETHANE Ingestion Rat LD50 > 1,500 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Serious Eye Damage/Irritation Name Species Value Skin Sensitization Name Species Value Respiratory Sensitization Name Species Value Germ Cell Mutagenicity Name Route Value 1,1-DIFLUOROETHANE In Vitro Some positive data exist, but the data are not sufficient for classification 1,1-DIFLUOROETHANE In vivo Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value 1,1-DIFLUOROETHANE Inhalation Rat Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration 1,1-DIFLUOROETHANE Inhalation Not toxic to female reproduction Rat NOAEL 25,000 ppm 2 years 1,1-DIFLUOROETHANE Inhalation Not toxic to male reproduction Rat NOAEL 25,000 ppm 2 years 1,1-DIFLUOROETHANE Inhalation Not toxic to development Rat NOAEL 50,000 ppm during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration 1,1-DIFLUOROETHANE Inhalation cardiac sensitization Causes damage to organs Human and animal NOAEL Not available poisoning and/or abuse 1,1-DIFLUOROETHANE Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL 100,000 ppm 1,1-DIFLUOROETHANE Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for Not available NOAEL Not available not available Page 29 of 871 Page 29 of 871 Page 29 of 871 Page 29 of 871 ---PAGE BREAK--- 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14 Page 8 of 9 classification Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration 1,1-DIFLUOROETHANE Inhalation hematopoietic system I kidney and/or bladder I respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 25,000 ppm 2 years Aspiration Hazard Name Value Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of handling halogenated materials. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-[PHONE REDACTED] or [PHONE REDACTED]. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Page 30 of 871 Page 30 of 871 Page 30 of 871 Page 30 of 871 ---PAGE BREAK--- 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14 Page 9 of 9 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 3 Flammability: 4 Instability: 1 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 3 Flammability: 4 Physical Hazard: 1 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS® III) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® III ratings are to be used with a fully implemented HMIS® III program. HMIS® is a registered mark of the American Coatings Association (ACA). Document Group: 19-7982-2 Version Number: 6.00 Issue Date: 11/18/14 Supercedes Date: 06/30/09 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com Page 31 of 871 Page 31 of 871 Page 31 of 871 Page 31 of 871 ---PAGE BREAK--- 3M Fire Block Sealant FB 136 08/18/14 Page 1 of 11 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: the information is copied in full with no changes unless prior written agreement is obtained from 3M, and neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 30-3404-8 Version Number: 2.00 Issue Date: 08/18/14 Supercedes Date: 05/25/12 SECTION 1: Identification 1.1. Product identifier 3M Fire Block Sealant FB 136 Product Identification Numbers 98-0400-5626-3, 98-0400-5627-1, 98-0400-5631-3 1.2. Recommended use and restrictions on use Recommended use Fire Protection 1.3. Supplier’s details MANUFACTURER: 3M DIVISION: Industrial Adhesives and Tapes Division ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-[PHONE REDACTED]) 1.4. Emergency telephone number 1-[PHONE REDACTED] or (651) 737-6501 (24 hours) SECTION 2: Hazard identification 2.1. Hazard classification Serious Eye Damage/Irritation: Category 2B. Skin Corrosion/Irritation: Category 2. Carcinogenicity: Category 1A. Specific Target Organ Toxicity (respiratory irritation): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger Symbols Exclamation mark I Health Hazard I Pictograms Page 32 of 871 Page 32 of 871 Page 32 of 871 Page 32 of 871 ---PAGE BREAK--- 3M Fire Block Sealant FB 136 08/18/14 Page 2 of 11 Hazard Statements Causes eye irritation. Causes skin irritation. May cause respiratory irritation. May cause cancer. Causes damage to organs through prolonged or repeated exposure: respiratory system I Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. IF exposed or concerned: Get medical advice/attention. Storage: Keep container closed. Store locked up in a well-ventilated place. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Water 7732-18-5 40 - 70 Kaolin 1332-58-7 30 - 60 Sodium Silicate 1344-09-8 10 - 30 Titanium Dioxide 13463-67-7 0.5 - 1.5 Page 33 of 871 Page 33 of 871 Page 33 of 871 Page 33 of 871 ---PAGE BREAK--- 3M Fire Block Sealant FB 136 08/18/14 Page 3 of 11 Quartz Silica 14808-60-7 0.1 - 1.0 Carbon Black 1333-86-4 < 0.1 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Page 34 of 871 Page 34 of 871 Page 34 of 871 Page 34 of 871 ---PAGE BREAK--- 3M Fire Block Sealant FB 136 08/18/14 Page 4 of 11 Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container closed. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Ingredient C.A.S. No. Agency Limit type Additional Comments Kaolin 1332-58-7 ACGIH TWA(respirable fraction):2 mg/m3 A4: Not class. as human carcin KAOLIN, TOTAL DUST 1332-58-7 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Carbon Black 1333-86-4 CMRG TWA:0.5 mg/m3 Carbon Black 1333-86-4 OSHA TWA:3.5 mg/m3 Carbon Black 1333-86-4 ACGIH TWA(inhalable fraction):3 mg/m3 A3: Confirmed animal carcin. Titanium Dioxide 13463-67-7 OSHA TWA(as total dust):15 mg/m3 Titanium Dioxide 13463-67-7 ACGIH TWA:10 mg/m3 A4: Not class. as human carcin Titanium Dioxide 13463-67-7 CMRG TWA(as respirable dust):5 mg/m3 Quartz Silica 14808-60-7 OSHA TWA concentration(as total dust):0.3 mg/m3;TWA concentration(respirable):0.1 mg/m3(2.4 millions of particles/cu. ft.) Quartz Silica 14808-60-7 ACGIH TWA(respirable fraction):0.025 mg/m3 A2: Suspected human carcin. ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Page 35 of 871 Page 35 of 871 Page 35 of 871 Page 35 of 871 ---PAGE BREAK--- 3M Fire Block Sealant FB 136 08/18/14 Page 5 of 11 Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Nitrile Rubber Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Solid Specific Physical Form: Paste Odor, Color, Grade: Gray, thixotropic paste, with minimal odor Odor threshold No Data Available pH Not Applicable Melting point Not Applicable Boiling Point Not Applicable Flash Point No flash point Flammability (solid, gas) Not Classified Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Vapor Pressure Not Applicable Vapor Density Not Applicable Specific Gravity 1.8 Solubility in Water Nil [Details: Partly soluble in water until heat cured] Solubility- non-water No Data Available Autoignition temperature Not Applicable Decomposition temperature No Data Available Volatile Organic Compounds < 1 % weight VOC Less H2O & Exempt Solvents 0 g/l SECTION 10: Stability and reactivity 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. Page 36 of 871 Page 36 of 871 Page 36 of 871 Page 36 of 871 ---PAGE BREAK--- 3M Fire Block Sealant FB 136 08/18/14 Page 6 of 11 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials None known. 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation. Skin Contact: Skin Irritation: may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Eye Contact: Moderate Eye Irritation: may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: May be harmful if swallowed. Gastrointestinal Irritation: may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Target Organ Effects: Prolonged or repeated exposure may cause: Pneumoconiosis: may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. Carcinogenicity: Page 37 of 871 Page 37 of 871 Page 37 of 871 Page 37 of 871 ---PAGE BREAK--- 3M Fire Block Sealant FB 136 08/18/14 Page 7 of 11 Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation SILICA, CRYS AIRRESP 14808-60-7 Known human carcinogen National Toxicology Program Carcinogens Carbon Black 1333-86-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Quartz Silica 14808-60-7 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Titanium Dioxide 13463-67-7 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE 2,000 - 5,000 mg/kg Kaolin Dermal LD50 estimated to be > 5,000 mg/kg Kaolin Ingestion Human LD50 > 15,000 mg/kg Sodium Silicate Dermal Rabbit LD50 > 4,640 mg/kg Sodium Silicate Ingestion Rat LD50 500 mg/kg Titanium Dioxide Dermal Rabbit LD50 > 10,000 mg/kg Titanium Dioxide Inhalation- Dust/Mist (4 hours) Rat LC50 > 6.82 mg/l Titanium Dioxide Ingestion Rat LD50 > 10,000 mg/kg Quartz Silica Dermal LD50 estimated to be > 5,000 mg/kg Quartz Silica Ingestion LD50 estimated to be > 5,000 mg/kg Carbon Black Dermal Rabbit LD50 > 3,000 mg/kg Carbon Black Ingestion Rat LD50 > 8,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Kaolin No significant irritation Sodium Silicate Rabbit Corrosive Titanium Dioxide Rabbit No significant irritation Quartz Silica No significant irritation Carbon Black Rabbit No significant irritation Serious Eye Damage/Irritation Name Species Value Kaolin No significant irritation Sodium Silicate Rabbit Corrosive Titanium Dioxide Rabbit No significant irritation Carbon Black Rabbit No significant irritation Skin Sensitization Name Species Value Sodium Silicate Mouse Not sensitizing Titanium Dioxide Human and animal Not sensitizing Respiratory Sensitization Name Species Value Germ Cell Mutagenicity Name Route Value Sodium Silicate In Vitro Not mutagenic Sodium Silicate In vivo Not mutagenic Titanium Dioxide In Vitro Not mutagenic Titanium Dioxide In vivo Not mutagenic Page 38 of 871 Page 38 of 871 Page 38 of 871 Page 38 of 871 ---PAGE BREAK--- 3M Fire Block Sealant FB 136 08/18/14 Page 8 of 11 Quartz Silica In Vitro Some positive data exist, but the data are not sufficient for classification Quartz Silica In vivo Some positive data exist, but the data are not sufficient for classification Carbon Black In Vitro Not mutagenic Carbon Black In vivo Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Kaolin Inhalation Multiple animal species Not carcinogenic Titanium Dioxide Ingestion Multiple animal species Not carcinogenic Titanium Dioxide Inhalation Rat Carcinogenic Quartz Silica Inhalation Human and animal Carcinogenic Carbon Black Dermal Mouse Not carcinogenic Carbon Black Ingestion Mouse Not carcinogenic Carbon Black Inhalation Rat Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Sodium Silicate Ingestion Some positive developmental data exist, but the data are not sufficient for classification Mouse NOAEL 200 mg/kg/day during gestation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Sodium Silicate Inhalation respiratory irritation May cause respiratory irritation official classifica tion NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Kaolin Inhalation pneumoconiosis Causes damage to organs through prolonged or repeated exposure Human NOAEL NA occupational exposure Kaolin Inhalation pulmonary fibrosis Some positive data exist, but the data are not sufficient for classification Rat NOAEL Not available Sodium Silicate Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Dog LOAEL 2,400 mg/kg/day 4 weeks Sodium Silicate Ingestion endocrine system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 804 mg/kg/day 3 months Sodium Silicate Ingestion blood All data are negative Rat NOAEL 804 mg/kg/day 3 months Sodium Silicate Ingestion heart I liver All data are negative Rat NOAEL 1,259 mg/kg/day 8 weeks Titanium Dioxide Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 0.010 mg/l 2 years Page 39 of 871 Page 39 of 871 Page 39 of 871 Page 39 of 871 ---PAGE BREAK--- 3M Fire Block Sealant FB 136 08/18/14 Page 9 of 11 Titanium Dioxide Inhalation pulmonary fibrosis All data are negative Human NOAEL Not available occupational exposure Quartz Silica Inhalation silicosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Carbon Black Inhalation pneumoconiosis Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Aspiration Hazard Name Value Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. If no other disposal options are available, waste product that has been completely cured or polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. EPA Hazardous Waste Number (RCRA): Not regulated SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-[PHONE REDACTED] or [PHONE REDACTED]. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Page 40 of 871 Page 40 of 871 Page 40 of 871 Page 40 of 871 ---PAGE BREAK--- 3M Fire Block Sealant FB 136 08/18/14 Page 10 of 11 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification SILICA, (AIRBORNE PARTICLES OF RESPIRABLE SIZE) None Carcinogen Carbon Black 1333-86-4 Carcinogen Titanium Dioxide 13463-67-7 Carcinogen WARNING: This product contains a chemical known to the State of California to cause cancer. 15.3. Chemical Inventories The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the new substance notification requirements of CEPA. The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the chemical notification requirements of TSCA. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 30-3404-8 Version Number: 2.00 Issue Date: 08/18/14 Supercedes Date: 05/25/12 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness Page 41 of 871 Page 41 of 871 Page 41 of 871 Page 41 of 871 ---PAGE BREAK--- 3M Fire Block Sealant FB 136 08/18/14 Page 11 of 11 or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com Page 42 of 871 Page 42 of 871 Page 42 of 871 Page 42 of 871 ---PAGE BREAK--- Page 43 of 871 Page 43 of 871 Page 43 of 871 Page 43 of 871 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SECTION I - PRODUCT IDENTIFICATION Emergency Phone: 1-[PHONE REDACTED] SECTION II – HAZARDOUS INGREDIENTS Ingredients CAS# Wt% ACGIH-TLV LC50 LD50 None by WHMIS criteria. SECTION III - PHYSICAL DATA Boiling Point 100 Specific Gravity (H2O = 0.982 @ 21.1°C Vapour Pressure (mm Hg): Not available % Volatile (Wt Not available Vapour Density (Air = >1 Evaporation Rate (Ether = Not available Solubility in Water: Dispersible pH (100%): 7.4 Physical State: Liquid Viscosity: Water thin Appearance; Odour: Moist towelettes; citrus Odour Threshold (ppm): Not available SECTION IV - FIRE AND EXPLOSION DATA Flammability: Not flammable by WHMIS criteria. Flash Point ( oC, TCC): >100 LEL: Not applicable UEL: Not applicable Hazardous Combustion Products: May include and are not limited to oxides of carbon. Autoignition Temperature ( oC): Not applicable Means of Extinction: Dry chemical, foam, alcohol foam, carbon dioxide. Special Fire Hazards: Firefighters should wear self-contained breathing apparatus. SECTION V - REACTIVITY DATA Conditions for Chemical Instability: Stable. Incompatible Materials: Acids, oxidizers. Reactivity, and Under What Conditions: Not available. Hazardous Decomposition Products: May include and are not limited to oxides of carbon when heated to decomposition. Product Name: 42272, 42230, 42210, 42201 Scrubs-in-A-Bucket® Product Use: Waterless Hand Cleaner Towels WHMIS Class: Not Controlled TDG Classification: Not Regulated Manufacturer/Supplier : ITW Dymon Address: 805 E Old 56 Highway Olathe, Kansas, 66061 Telephone: 1-[PHONE REDACTED] HEALTH 1 FLAMMABILITY 1 REACTIVITY 0 PERSONAL PROTECTION Page 44 of 871 Page 44 of 871 Page 44 of 871 Page 44 of 871 ---PAGE BREAK--- 42272, 42230, 42210, 42201 Scrubs-in-A-Bucket® SECTION VI - TOXICOLOGICAL PROPERTIES Route of Entry: Eye, Skin contact, EFFECTS OF ACUTE EXPOSURE: Eye: May cause irritation. Skin: May cause irritation. EFFECTS OF CHRONIC EXPOSURE: Skin: Prolonged or repeated exposure can cause drying, defatting and dermatitis. Irritancy: May cause irritation. Respiratory Tract Sensitization: No data available. Carcinogenicity: Non-hazardous by WHMIS criteria. Teratogenicity, Mutagenicity, Reproductive Effects: No data available. Synergistic Materials: Not available. SECTION VII- PREVENTATIVE MEASURES Gloves: Not required. Eye Protection: Not normally required. Respiratory Protection: Not normally required if good ventilation is maintained. Other Protective Equipment: As required by employer code. Engineering Controls: General ventilation normally adequate. Leak and Spill Procedure: Pick up and discard towel. Waste Disposal: Review federal, provincial, and local government requirements prior to disposal. Storage and Handling Requirements: Keep out of reach of children. Store in a closed container away from incompatible materials. SECTION VIII - FIRST AID Eye: Flush with cool water. Remove contact lenses, if applicable, and continue flushing. Obtain medical attention if irritation persists. Skin: Flush with soap and water. In case of skin irritation, discontinue use of product. Inhalation: Not a normal route of exposure. If develop move victim to fresh air. If persist, obtain medical attention. Ingestion: Not a normal route of exposure. Do not induce vomiting. Rinse mouth with water then drink one or two glasses of water. Obtain medical attention. Never give anything by mouth if victim is unconscious, or is convulsing. SECTION IX - PREPARATION INFORMATION Date: 2004/03/01 MSDS Prepared by: Dell Tech Laboratories Telephone: (519) 858-5021 Disclaimer Information for this material safety data sheet was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the mandatory requirements of WHMIS. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this form. If user requires independent information on ingredients in this or any other material, we recommend contact with the Canadian Centre for Occupational Health and Safety (CCOHS) in Hamilton, Ontario (1-[PHONE REDACTED]) or CSST in Montreal, Quebec (514-873- 3990). 2 Page 45 of 871 Page 45 of 871 Page 45 of 871 Page 45 of 871 ---PAGE BREAK--- SANTÉ 1 INFLAMM. 1 RÉACTIVITÉ 0 PROTECTION PERSONNELLE FICHE SIGNALÉTIQUE SECTION I – IDENTIFICATEUR DE LA MATIÈRE Identificateur de la matière: 42272, 42230, 42210, 42201 Scrubs-in-A- Bucket® Usage du produit: Essuie-mains nettoyants "á sec" Classification du SIMDUT: Non contrôlé Appellation réglementaire en vertu du TMD: Non réglementé Fabricant/Fournisseur: ITW Dymon Adresse: 805 E Old 56 Highway Olathe, Kansas, 66061 No. de téléphone: 1-[PHONE REDACTED] Numéro de téléphone d’urgence: 1-[PHONE REDACTED] SECTION II – INGRÉDIENTS DANGEREUX Ingrédients CAS# Pd% ACGIH-TLV CL50 DL50 Aucun d'après les critères du SIMDUT. SECTION III – DONNÉES PHYSIQUES Point d’ébullition 100 Densité spécifique (H2O = 0.982 @ 21.1°C Tension de vapeur (mm Hg): Pas disponible % Volatil (Pd Pas disponible Densité de vapeur (Air = >1 Vitesse d’évaporation (Éther = Pas disponible Solubilité dans l’eau: Dispersible pH (100%): 7.4 État physique: Liquide Viscosité: Comme l'eau Apparence; odeur: Servviettes moite; citrique Seuil de l’odeur (ppm): Pas disponible SECTION IV – DANGERS D’EXPLOSION ET D’INCENDIE Inflammabilité: Ininflammable d'après les critères du SIMDUT. Point d’éclair ( oC, TCC): >100 LIE: Sans objet LSE: Sans objet Produits de combustion dangereux: Ils peuvent comprendre et ne sont pas limités aux oxydes de carbone. Température d’auto-inflammation ( oC): Sans objet Produits extincteurs: Poudre chimique, mousse, mousse anti-alcool, dioxyde de carbone. Dangers d’incendie particuliers: Les pompiers doivent porter un appareil respiratoire autonome. SECTION V – DONNÉES SUR LA RÉACTIVITÉ CHIMIQUE Conditions d’instabilité chimique: Stable. Incompatibilité: Acides, oxydants. Conditions de réactivité: Pas disponible. Produits de décomposition dangereux: Ils peuvent comprendre et ne sont pas limités aux oxydes de carbone quand chauffé jusqu'à décomposition. Page 46 of 871 Page 46 of 871 Page 46 of 871 Page 46 of 871 ---PAGE BREAK--- 42272, 42230, 42210, 42201 Scrubs-in-A-Bucket® SECTION VI – PROPRIÉTÉS TOXICOLOGIQUES Voie d’exposition: Yeux, contact avec la peau EFFETS D’UNE EXPOSITION AIGUË: Yeux: Peut causer une irritation. Peau: Peut causer une irritation. EFFETS D’UNE EXPOSITION CHRONIQUE: Peau: L'exposition prolongée ou répétée peut causer l'assèchement, la délipidation et des dermatites. Irritation: Peut causer une irritation. Sensibilisation des voies respiratoires: Pas de données disponibles. Cancérogénicité: Non dangereux d'après les critères du SIMDUT. Tératogénicité, mutagénicité, effets sur la reproduction: Pas de données disponibles. Matières synergiques: Pas disponible. SECTION VII- MESURES DE PRÉVENTION Gants: Non nécessaire. Protection des yeux: Normalement non nécessaire. Protection des voies respiratoires: Normalement non nécessaire. Autre équipement de protection: Conformément aux directives de votre employeur. Ventilation: Ventilation générale adéquate. Mesures en cas de fuite ou de déversement: Ramasser la serviette et la jeter. Élimination des déchets: Consulter les règlements fédéraux, provinciaux et municipaux avant d'éliminer. Conditions d’entreposage et de manutention: Garder hors de la portée des enfants. Entreposer dans un contenant fermé à l'abri des matières incompatibles. SECTION VIII – PREMIERS SOINS Yeux: Rincer à grande eau froide. Enlever les verres de contact, le cas échéant, et continuer à rincer. Obtenir de l'attention médicale si l'irritation persiste. Peau: Rincer à grande eau et au savon. En cas d'irritation, discontinuer l'emploi du produit. Inhalation: N'est pas une voie d'exposition habituelle. En cas de placer la victime à l'air frais. Si les persistent, obtenir de l'attention médicale. Ingestion: N'est pas une voie d'exposition habituelle. Ne pas tenter de faire vomir. Rincer la bouche à grande eau, puis boire un ou deux verres d'eau. Obtenir de l'attention médicale. Ne jamais rien faire boire ou avaler à une victime inconsciente, en train de perdre rapidement connaissance ou si la victime a des convulsions. SECTION IX – RENSEIGNEMENTS SUR LA PRÉPARATION Date: 2004/03/01 FS préparée par: Dell Tech Laboratories No. de téléphone: (519) 858-5021 Clause d’exonération de responsabilité Les renseignements fournis dans la présente fiche signalétique ont été préparés à partir de différentes sources que nous croyons exactes et fiables du point de vue technique. Nous avons tout mis en oeuvre pour divulguer tous les renseignements sur les dangers. Cependant, dans certains cas, les renseignements ne sont pas disponibles et nous l'avons indiqué. Les conditions d'utilisation du produit étant hors du contrôle du fournisseur, nous assumons que l'utilisateur de la présente matière a reçu la formation obligatoire voulue conformément aux règlements du SIMDUT. Aucune garantie expresse ou implicite n'est émise et le fournisseur ne sera pas responsable en cas de pertes, blessures ou dommages indirects résultant de l'utilisation des présents renseignements. Si l'utilisateur de la présente matière ou d'autres matières souhaite obtenir d'autres renseignements sur les ingrédients, nous lui recommandons de communiquer avec la Commission de la Santé et de la Sécurité du Travail, à Montréal en Québec ([PHONE REDACTED]) ou le Centre Canadien d'Hygiène et de Sécurité au Travail, à Hamilton (1-[PHONE REDACTED]). 2 Page 47 of 871 Page 47 of 871 Page 47 of 871 Page 47 of 871 ---PAGE BREAK--- SALUD 1 INFLAMABILIDAD 1 REACTIVIDAD 0 PROTECCIÓN PERSONAL FICHA DESCRIPTIVA DEL PRODUCTO SECCIÓN I - IDENTIFICACIÓN DEL PRODUCTO Nombre del producto: 42272, 42230, 42210, 42201 Scrubs-in-A-Bucket® Uso del producto: Toallas "secas" para limpiar las manos Clase WHMIS: No controlado Clasificación TDG: No regulado Fabricante/Proveedor : ITW Dymon Dirección: 805 E Old 56 Highway Olathe, Kansas, 66061 Teléfono: 1-[PHONE REDACTED] Teléfono para emergencias: 1-[PHONE REDACTED] SECCIÓN II – PELIGROSOS INGREDIENTES Ingredientes #CAS Peso% ACGIH-TLV CL50 DL50 Ninguno según los criterios de WHMIS. SECCIÓN III - PROPIEDADES FÍSICAS Punto de ebullición ( oC): 100 Peso específico (H2O = 0.982 @ 21.1°C Presión de vapor (mm de Hg): No disponible % Volátil (Peso%): No disponible Densidad de vapor (Aire = >1 Tasa de evaporación (Éter = No disponible Solubilidad en agua: Se dispersa pH (100%): 7.4 Estado físico: Líquido Viscosidad: Como agua Aspecto; olor: Toallas humedecida; cítrico Umbral de olor (ppm): No disponible SECCIÓN IV - MEDIDAS DE LUCHA CONTRA INCENDIO Inflamabilidad: Ininflamable según los criterios de WHMIS. Punto de inflamabilidad ( 0C, Vaso cerrado Tag): >100 LIE: No se aplica LSE: No se aplica Productos de combustión peligrosos: Pueden incluir y no están limitados a óxidos de carbono. Temperatura de autoignición ( 0C): No se aplica Forma de extinción: Polvo químico, espuma, espuma de alcohol, dióxido de carbono. Riesgos de incendio especiales: Los bomberos deben usar aparatos de respiración autónomos. SECCIÓN V - REACTIVIDAD Condiciones para la inestabilidad química: Estable. Materiales incompatibles: Ácidos, oxidantes. Condiciones de reactividad: No disponible. Productos de descomposición peligrosos: Pueden incluir y no están limitados a óxidos de carbono cuando se calienta hasta la descomposición. Page 48 of 871 Page 48 of 871 Page 48 of 871 Page 48 of 871 ---PAGE BREAK--- 42272, 42230, 42210, 42201 Scrubs-in-A-Bucket® SECCIÓN VI - PROPIEDADES TOXICOLÓGICAS Vías de entrada: Ojos, contacto con la piel Efectos debidos a una exposición aguda: Ojos: Puede causar una irritación. Piel: Puede causar una irritación. Efectos debidos a una exposición crónica: Piel: La exposición repetida o prolongada puede causar deshidratación, sequedad y dermatitis. Irritación: Puede causar una irritación. Sensibilización del aparato respiratorio: No hay datos disponibles. Carcinogenesis: No es peligroso según los criterios de WHMIS. Teratogenesis, mutagenesis, efectos sobre la reproducción: No hay datos disponibles. Materiales sinergísticos: No disponible. SECCIÓN VII - MEDIDAS DE PREVENCIÓN Guantes: Normalmente no se requiere. Protección de ojos: Normalmente no se requiere. Protección del aparato respiratorio: Normalmente no se requiere si se mantiene una buena ventilación. Otros equipos de protección: Como sea requerido por las normas del empleador. Controles de ingeniería: La ventilación general es normalmente suficiente. Procedimientos para escapes y derrames: Levantar la toalla y tirarla a la basura. Eliminación de residuos: Consultar los requerimientos de los gobiernos federales, provinciales y municipales antes de la eliminación. Requerimientos de almacenaje y manipulación: Mantener fuera del alcance de los niños. Almacenar en recipientes cerrados lejos de materiales incompatibles. SECCIÓN VIII - PRIMEROS AUXILIOS Ojos: Enjuagar con agua fría. Sacarse los lentes de contacto, si es el caso, y continuar enjuagando. Obtener asistencia médica si la irritación persiste. Piel: Enjuagar con agua y jabón. En caso de irritación de la piel, discontinuar el uso del producto. Inhalación: No es una vía normal de exposición. En caso de síntomas, mover a la víctima a un lugar con aire fresco. Si los síntomas persisten, obtener asistencia médica. Ingestión: No es una vía normal de exposición. No inducir el vómito. Enjuagar la boca con agua y después tomar uno o dos vasos de agua. Obtener asistencia médica. No dar nada por boca si la víctima está inconsciente, o si tiene convulsiones. SECCIÓN IX - INFORMACIÓN SOBRE LA PREPARACIÓN Fecha: 2004/03/01 Ficha preparada por: Dell Tech Laboratories Teléfono: (519) 858-5021 Cláusula de limitación de responsabilidad La información para esta ficha descriptiva fue obtenida de fuentes consideradas técnicamente precisas y confiables. Si bien se ha hecho lo posible para divulgar todos los riesgos del producto, en algunos casos no se dispone de datos y así está indicado. Dado que las condiciones del uso actual del producto están fuera del control del proveedor, se asume que los usuarios de este producto están totalmente entrenados de acuerdo a los requerimientos obligatorios de WHMIS. No se da ninguna garantía expresa, o implícita, y el proveedor no es responsable por ninguna pérdida, heridas o daños indirectos causados como resultado del uso de la información contenida en esta ficha. Si el usuario requiere información independiente sobre los ingredientes de este u otro producto, recomendamos contactar al Centro Canadiense de Seguridad y Salud en el Trabajo (Canadian Centre for Occupational Health and Safety/CCOHS) en Hamilton, Ontario (1-[PHONE REDACTED]) o a la Comisión de la Salud y de la Seguridad en el Trabajo (Commission de la Santé et de la Sécurité du Travail/CSST) en Montreal, Quebec ([PHONE REDACTED]). 2 Page 49 of 871 Page 49 of 871 Page 49 of 871 Page 49 of 871 ---PAGE BREAK--- SAFETY DATA SHEET. Issuing date 11-Feb-2014 Revision Date 11-Feb-2014 Version 1 Page 1 / 8 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product name 97673 TEF-GEL Recommended use of the chemical and restrictions on use Product code 97673 Product Type Extremely flammable aerosol Synonyms Supplier's details Recommended Use Gel Lubricant. Uses advised against Manufactured For: Lawson Products, Inc 8770 W. Bryn Mawr Avenue - Suite 900 Chicago, IL 60631-3515 Emergency telephone number Chemical Emergency Phone Number Chemtrec 1-[PHONE REDACTED] ID 1195 Company Emergency Phone Number [PHONE REDACTED] Page 50 of 871 Page 50 of 871 Page 50 of 871 Page 50 of 871 ---PAGE BREAK--- F00829 97673 TEF-GEL Revision Date 11-Feb-2014 Page 2 / 8 2. HAZARDS IDENTIFICATION Classification Germ Cell Mutagenicity Category 1B Carcinogenicity Category 1A Aspiration toxicity Category 1 Flammable aerosols Category 1 GHS Label elements, including precautionary statements Emergency Overview DANGER Hazard Statements May cause genetic defects May cause cancer May be fatal if swallowed and enters airways Extremely flammable aerosol Appearance Hazy Physical state Aerosol Odor Solvent Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Other information • May be harmful in contact with skin 16.86256% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS CAS # 64742-49-0, COMMERCIAL HEXANES, MAY BE SUBSTITUTED FOR CAS #110-54-3. Synonyms . Page 51 of 871 Page 51 of 871 Page 51 of 871 Page 51 of 871 ---PAGE BREAK--- F00829 97673 TEF-GEL Revision Date 11-Feb-2014 Page 3 / 8 Chemical Name CAS-No Weight % HEXANE 64742-49-0 60 - 70% PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 10 - 20% *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES First aid measures for different exposure routes Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If skin irritation persists, call a physician. Inhalation Move to fresh air. If persist, call a physician. Ingestion Do NOT induce vomiting. If persist, call a physician. Most important acute and delayed Main Not applicable. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Decomposition by contact with water may generate vapors which can be ignited by heat or open flame. Specific hazards arising from the chemical No information available. Explosion Data Sensitivity to Mechanical Impact none. Sensitivity to Static Discharge Yes. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation. Environmental precautions Page 52 of 871 Page 52 of 871 Page 52 of 871 Page 52 of 871 ---PAGE BREAK--- F00829 97673 TEF-GEL Revision Date 11-Feb-2014 Page 4 / 8 Environmental precautions No special environmental precautions required. Methods and materials for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top of can. Conditions for safe storage, including any incompatibilities Technical measures/Storage conditions Keep containers closed in a dry, cool and well-ventilated place. Incompatible products None known based on information supplied. Aerosol Level 3 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . ACGIH: (American Conference of Governmental Industrial Hygienists) OSHA: (Occupational Safety & Health Administration) NIOSH IDLH: Immediately Dangerous to Life or Health Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Exposure controls Engineering Measures Showers Eyewash stations Ventilation systems. Individual protection measures, such as personal protective equipment Eye/Face Protection Safety glasses with side-shields. Skin and body protection Chemical resistant apron. Protective gloves. Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 53 of 871 Page 53 of 871 Page 53 of 871 Page 53 of 871 ---PAGE BREAK--- F00829 97673 TEF-GEL Revision Date 11-Feb-2014 Page 5 / 8 Physical and chemical properties Physical state Aerosol Appearance Hazy Odor Solvent Color amber Odor Threshold No information available Property Values Remarks • Methods pH No information available not applicable Melting/freezing point No information available Boiling point/boiling range No information available Flash Point -96.4 °C / -141 °F Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limits in Air upper flammability limit No information available lower flammability limit No information available Vapor pressure No information available Vapor density No information available Specific Gravity 0.720 Water solubility Practically insoluble Partition coefficient: n-octanol/water No information available Autoignition temperature No information available Not applicable Decomposition temperature No information available Viscosity No information available Explosive properties No information available Other information VOC Content(%) 78.76 10. STABILITY AND REACTIVITY Reactivity No data available Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to Avoid Extremes of temperature and direct sunlight. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Product does not present an acute toxicity hazard based on known information Inhalation There is no data available for this product. Eye contact There is no data available for this product. Page 54 of 871 Page 54 of 871 Page 54 of 871 Page 54 of 871 ---PAGE BREAK--- F00829 97673 TEF-GEL Revision Date 11-Feb-2014 Page 6 / 8 Skin contact There is no data available for this product. Ingestion There is no data available for this product. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation HEXANE 64742-49-0 > 5000 mg/kg ( Rat ) > 3160 mg/kg ( Rabbit ) 73680 ppm ( Rat ) 4 h Information on toxicological effects No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ Cell Mutagenicity No information available. Carcinogenicity There are no known carcinogenic chemicals in this product. This product contains one or more substances which are classified by IARC as carcinogenic to humans (Group probably carcinogenic to humans (Group 2A) or possibly carcinogenic to humans (Group 2B). Reproductive toxicity No information available. Specific target organ systemic toxicity (single exposure) No information available. Specific target organ systemic toxicity (repeated exposure) No information available. Target Organ Effects Central nervous system, Eyes, Peripheral Nervous System (PNS), Respiratory system, Skin. Aspiration hazard No information available. Numerical measures of toxicity - Product Information Unknown Aquatic Toxicty 16.86256% of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 6980 mg/kg ATEmix (dermal) 4702 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphnia and other aquatic invertebrates HEXANE 64742-49-0 2.6: 96 h Chaetogammarus marinus mg/L LC50 Persistence and degradability No information available. Bioaccumulation No information available. Chemical Name log Pow PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 2.8 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Page 55 of 871 Page 55 of 871 Page 55 of 871 Page 55 of 871 ---PAGE BREAK--- F00829 97673 TEF-GEL Revision Date 11-Feb-2014 Page 7 / 8 Waste treatment Waste Disposal Methods This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not re-use empty containers. 14. TRANSPORT INFORMATION DOT Ground CONSUMER COMMODITY ORM-D or LIMITED QUANTITY IATA UN1950, AEROSOLS, FLAMMABLE, 2.1, LTD. QTY. IMDG UN1950, AEROSOLS, 2.1, LTD. QTY. 15. REGULATORY INFORMATION International Inventories Chemical Name TSCA DSL/NDSL EINECS/ELI NCS ENCS IECSC KECL PICCS AICS HEXANE X X X X X Present X X PROPANE/ISOBUTAN E/N-BUTANE X X X Not listed X Present X X TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances CHINA - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard Yes Sudden Release of Pressure Hazard no Reactive Hazard no Page 56 of 871 Page 56 of 871 Page 56 of 871 Page 56 of 871 ---PAGE BREAK--- F00829 97673 TEF-GEL Revision Date 11-Feb-2014 Page 8 / 8 Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): U.S. State Regulations California Proposition 65 This product does not contain any known Proposition 65 chemicals. U.S. State Right-to-Know Regulations Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION NFPA Health Hazard 2 Flammability 4 Instability 0 Physical and chemical hazards - HMIS Health Hazard 2* Flammability 4 Physical Hazard 1 Personal protection B Chronic Hazard Star Legend Chronic Health Hazard; Repeated or prolonged exposure may cause central nervous system damage Prepared By Regulatory Affairs Issuing date 11-Feb-2014 Revision Date 11-Feb-2014 Revision Note No information available Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of Safety Data Sheet Page 57 of 871 Page 57 of 871 Page 57 of 871 Page 57 of 871 ---PAGE BREAK--- 97436 HOJA DE DATOS DE SEGURIDAD DE MATERIALES ESENCIALMENTE SIMILAR A FORMULARIO OSHA 174 -CLASIFICACIONES NFPA HMIS- --PELIGROSIDAD-- ---PROTECCION PERSONAL--- SALUD 3 3 PELIGRO SEVERO 4 A ANTEOJOS INFLAMABILIDAD 0 0 PELIGRO SERIO 3 B ANTEOJOS & GUANTES REACTIVIDAD 1 1 PELIGRO MODERADO 2 C ANTEOJOS, GUANTES & DELANTAL PROTECCION B PELIGRO LIGERO 1 D CARETA PROTECTORA, GUANTES & PERSONAL PELIGRO MINIMO 0 DELANTAL E ANTEOJOS, GUANTES & RESPIRADOR PREPARADO PARA: TELEFONO DE EMERGENCIA: Lawson Products, Inc. Rocky Mountain Poison and Drug Center 1666 East Touhy Avenue (303) 623-5716 Des Plaines, Illinois 60018 FECHA DE REVISION: TELEFONO DE INFORMACION: 07/24/01 (847) 827-9666 I SECCION I - IDENTIFICACION DEL PRODUCTO I PRODUCTO NUMERO 97436 NOMBRE DEL PRODUCTO Adhesivo Bond'n Seal CLASE DEL PRODUCTO Miscel neos I SECCION II - INGREDIENTES PELIGROSOS I TLV MG/ PEL LEL INGREDIENTE NUMERO CAS % PPM M^3 PPM % !@*Tetracloroetileno 127-18-4 72.0 50 670.0 25 N/A * Listado como un Carcinogeno posible. @ Requisitos de notificacion de SARA Titulo III. Mire Seccion IX. ! Requisitos de notificacion de CA Proposition 65. Mire Seccion IX I SECCION III - DATOS FISICOS I PUNTO DE EBULLICION 121.1 DESIDAD DEL VAPOR: Mas pesado que el aire. INDICE DE EVAPORACION: Mas Slower que el eter. PORCENTAJE DE VOLATILIDAD (Por Peso): N/A PESO POR GALON (Kg): N/A OLOR Y APARIENCIA: Olor et,reo. 97436 HOJA DE DATOS DE SEGURIDAD DE MATERIALES ESENCIALMENTE SIMILAR A FORMULARIO OSHA 174 I SECCION IV - DATOS DE PELIGRO DE INCENDIO Y EXPLOSION I CLASIFICACION DE INFLAMABILIDAD CLASIFICACION U.N. file:///JI/shared/MSDS_Content_Building/Content...s/Lawson/1/180a10a0282b9e7486256b66006bbed6.htm (1 of 4) [2/25/2002 8:14:44 PM] Page 58 of 871 Page 58 of 871 Page 58 of 871 Page 58 of 871 ---PAGE BREAK--- OSHA: N/A DOT: ORMD DOT: N/A IMCO: N/A NUMERO DE CLASIFICACION IMCO: CLASIFICACION IATA: N/A N/A PUNTO DE EXPLOSION (C):N/A LEL: N/A UEL: N/A NIVEL DE PROTECCION CONTRA INCENDIOS NFPA: N/A COMPUESTOS ORGANICOS VOLATILES: N/A METHOD: No Aplicable MEDIO DE EXTINCION: ESPUMA CO2 QUIMICO SECO NEBLINA DE AGUA PELIGROS DE INCENDIO Y EXPOSION FUERA DE LO NORMAL: El calor puede causar el aumento de la presi¢n y la posible ruptura del recipiente. PROCEDIMIENTOS DE LUCHA CONTRA INCENDIOS: Al luchar contra incendios que comprometen productos qu¡micos, debe usarse ropa protectora y aparatos aut¢nomos para la respiraci¢n. I SECCION V - DATOS DE PELIGROS PARA LA SALUD I EFFECTOS DE SOBRE EXPOSICION: La sobre exposici¢n al material no curado puede causar n useas y da¤os al sistema respiratorio. Irritante para la piel y los ojos. RUTA(S) PRIMARIA(S) DE ENTRADA: CUTANEA INHALACION CONDICIONES MEDICAS QUE PUEDEN EMPEORAR POR SOBRE EXPOSICION: Los trastornos preexistentes de la piel y los pulmones pueden ser agravados por la exposici¢n excesiva. ORGANOS QUE PUEDEN SER AFECTADOS: Puede causar mareos o narcosis en concentraciones altas de vapor. Causar desgrasamiento de la piel. Los efectos son reversibles. La exposici¢n al vapor a largo plazo (a¤os), puede causar da¤os a los pulmones, al h¡gado, a los ri¤ones. Los disolventes han demostrado tener efecto en el sistema nervioso central. CARCINOGENICIDAD: Este producto contiene material considerado de ser un carcin¢geno por el Programa Toxicol¢gico Nacional, o la Agencia Internacional para la Investigaci¢n del C ncer, o la Administraci¢n de Salud y de Seguridad Ocupacional, "Sospechado en Animales". PROCEDIMIENTOS DE EMERGENCIA Y PRIMEROS AUXILIOS: Mover a la persona al aire fresco, irrigar los ojos, ponerse en con- tacto con el m,dico, si es necesario. 97436 HOJA DE DATOS DE SEGURIDAD DE MATERIALES ESENCIALMENTE SIMILAR A FORMULARIO OSHA 174 I SECCION VI - DATOS DE REACTIVIDAD I ESTABILIDAD: ESTABLE PELIGRO DE POLIMERIZACION: NO DEBE OCURRIR PRODUCTOS PELIGROSOS POR DESCOMPOSICION: La combusti¢n puede producir mon¢xido de carbono y/o di¢xido de car- bono, peque¤as cantidades de fosgeno y cloruro de hidr¢geno. CONDICIONES QUE SE DEBEN EVITAR: Evitar llamas descubiertas, superficies incandecentes, o el arco el,ctrico. file:///JI/shared/MSDS_Content_Building/Content...s/Lawson/1/180a10a0282b9e7486256b66006bbed6.htm (2 of 4) [2/25/2002 8:14:44 PM] Page 59 of 871 Page 59 of 871 Page 59 of 871 Page 59 of 871 ---PAGE BREAK--- INCOMPATIBILIDAD (MATERIALES QUE DEBEN SER EVATADOS): Agentes oxidizantes fuertes, cidos o bases fuertes. I SECCION VII - PROCEDIMIENTOS PARA DERRAMES O FUGAS I PASOS QUE DEBEN SER TOMADOS EN CASO QUE EL MATERIAL SEA DERRAMADO: Eliminar todas las fuentes de ignici¢n, ventilar. Evitar respirar los vapores y quitar con absorbente inerte. METODOS PARA ELIMINAR DESECHOS: Debe ser de acuerdo con leyes y regulaciones aplicables. I SECCION VIII - INFORMACION PARA EL MANEJO Y USO CON SEGURIDAD I PROTECCION RESPIRATORIA: Usar en una rea bien ventilada. VENTILACION: Si las pr cticas de ventilaci¢n corrientes no son adecuadas para man- tener las concentraciones en el aire por debajo de los l¡mites de exposici¢n establecidos, se requerir sistemas adicionales de venti- laci¢n o extracci¢n. GUANTES DE PROTECCION: Se recomienda neopreno. PROTECCION DE LOS OJOS: Usar anteojos de seguridad dise¤ados para proteger contra el salpicado de l¡quidos. OTRO EQUIPO PROTECTOR: Deben haber disponibles una estaci¢n para el lavado de ojos y duchas de seguridad. PRACTICAS HIGIENICAS: Lavar las manos antes de comer o usar el ba¤o. Fumar en AREAS PARA FUMADORES solamente. 97436 HOJA DE DATOS DE SEGURIDAD DE MATERIALES ESENCIALMENTE SIMILAR A FORMULARIO OSHA 174 I SECCION IX - PRECAUCIONES ESPECIALES I PRECAUCIONES A TOMARSE PARA EL MENEJO Y ALMACENAJE: Evitar el contacto con los ojos y el excesivo contacto con la piel. OTRAS PRECAUCIONES: Todos los ingredientes marcados con un son productos qu¡micos t¢xicos est n supeditados a los requisitos de notificaci¢n de la Secci¢n 313 del T¡tulo III del acta Superfund Amendments and Re- authorization Act (SARA) (Ley de Enmiendas y Reautorizaci¢n de Fondos) de 1986 y 40 CFR Parte 372. ADVERTENCIA: Este producto contiene una substancia qu¡mica que el estado de California considera cancer¡gena. Fecha de Preparacion: 09/06/91 PERSONAS RESPONSABLE: file:///JI/shared/MSDS_Content_Building/Content...s/Lawson/1/180a10a0282b9e7486256b66006bbed6.htm (3 of 4) [2/25/2002 8:14:44 PM] Page 60 of 871 Page 60 of 871 Page 60 of 871 Page 60 of 871 ---PAGE BREAK--- Engineering Department Lawson Products, Inc. 1666 East Touhy Avenue Des Plaines, Illinois 60018 (847) 827-9666 "La determinacion final de la conformidad del producto(s) quimico(s) es de la exclusiva responsabilidad del usuario. Los usuarios de cualquier producto quimico deben satisfacerse a si mismos que las condiciones y metodos de su empleo aseguran que el producto quimico es usado con seguridad. NINGUNA REPRESENTACION O GARANTIA, YA SEA EXPRESA O IMPLICITA, DE LA FACILIDAD DE MERCADEO, CAPACIDAD PARA UN PROPOSITO EN PARTICULAR, O DE CUALQUIER OTRO NATURALEZA, SON AQUI HECHAS CON RESPECTO A LA INFORMACION CONTENIDA EN LA PRESENTE, O EN EL PRODUCTO QUIMICO AL CUAL SE REFIERE ESTA INFORMACION." HMIS Sistema de Identificacion de Materiales Peligrosos IARC Agencia Internacional para le Investigacion del Cancer OSHA Administracion de Seguridad y Salubridad Ocupacional IATA Asociacion de Transporte Aereo Internacional IMCO Organizacion de la Comision Maritima Internacional DOT Departamento (Ministrerio) de Transporte N/A No Disponible a la Fecha PEL Nivel Permisible de Exposicion LEL Nivel Bajo Explosivo NTP Programa Toxicologico Nacional PPM Partes Por Millon CAS Servicio Quimico Abstract TLV Valor del Limite del Umbral CNS Sistema Nerviosa Central file:///JI/shared/MSDS_Content_Building/Content...s/Lawson/1/180a10a0282b9e7486256b66006bbed6.htm (4 of 4) [2/25/2002 8:14:44 PM] Page 61 of 871 Page 61 of 871 Page 61 of 871 Page 61 of 871 ---PAGE BREAK--- Revision Date: 01-May-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: AIRLIFT FRESH SCENT (AEROSOL) Product Number: 6095 Recommended Use: Air freshener Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification GHS Label Elements Signal Word: Danger Hazard Statements: Extremely flammable aerosol. Contains gas under pressure; may explode if heated Precautionary Statements: Prevention: Keep away from heat/sparks/open flames/hot surfaces. — No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Response: -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Protect from sunlight. Do not expose to temperatures exceeding 122°F (50°C) Store in a well-ventilated place Disposal: Not Applicable Hazards Not Otherwise Classified: Not Applicable Flammable Aerosols Category 1 Gases Under Pressure Page 1 / 5 Liquefied gas Symbols: Page 62 of 871 Page 62 of 871 Page 62 of 871 Page 62 of 871 ---PAGE BREAK--- 6095 - AIRLIFT FRESH SCENT (AEROSOL) Revision Date: 01-May-2015 Other Information: • May cause skin irritation. • May cause eye irritation. • May be harmful if swallowed. • Inhalation of vapors or mist may cause respiratory irritation. • Keep out of reach of children. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 60-100 N-butane 106-97-8 7-13 petroleum distillates 64742-47-8 5-10 propane 74-98-6 3-7 petroleum distillates 64742-88-7 1-5 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Water spray (fog), Foam Specific Hazards Arising from the Chemical: Extremely flammable aerosol. Exposure to high temperature may cause containers to burst. Bursting aerosol containers may be propelled from fire at high speed. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Water may be used to cool closed containers to prevent pressure build-up and possible auto ignition or explosion when exposed to extreme heat. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 7. HANDLING AND STORAGE Page 2 / 5 Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Wash thoroughly after handling. Page 63 of 871 Page 63 of 871 Page 63 of 871 Page 63 of 871 ---PAGE BREAK--- 6095 - AIRLIFT FRESH SCENT (AEROSOL) Revision Date: 01-May-2015 Storage Conditions: NFPA 30B Level 1 Aerosol. Do not store in direct sunlight or above 122 F° / 50 Exposure to high temperature may cause containers to burst. Keep out of the reach of children. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: . Chemical Name ACGIH TLV OSHA PEL NIOSH N-butane 106-97-8 TWA: 1000 ppm (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 TWA: 800 ppm TWA: 1900 mg/m3 propane 74-98-6 TWA: 1000 ppm TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Personal Protective Equipment Eye/Face Protection: Not required with expected use. Skin and Body Protection: Not required with expected use. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatible Materials: Strong oxidizing agents. Strong acids. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Aerosol Color: Colorless Odor: Fresh pH: 6.0-8.0 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 100 °C / 212 °F (Product without propellant) Flash Point: < -18 °C / < 0 °F (Propellant-estimated) Evaporation Rate: <1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 0.83 (Product without propellant) Solubility(ies): No information available. Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 3 / 5 Decomposition Temperature: No information available. Viscosity: No information available. Page 64 of 871 Page 64 of 871 Page 64 of 871 Page 64 of 871 ---PAGE BREAK--- 6095 - AIRLIFT FRESH SCENT (AEROSOL) Revision Date: 01-May-2015 Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Pain and redness. -Skin Contact: Drying of the skin. -Inhalation: Nasal discomfort and coughing. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Target Organ Effects: Central nervous system. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 49213 mg/kg ATEmix (dermal): 20804 mg/kg ATEmix (inhalation-gas): 1669319 mg/l Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available N-butane 106-97-8 Not Available Not Available = 658 mg/L ( Rat ) 4 h petroleum distillates 64742-47-8 > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5.2 mg/L ( Rat ) 4 h propane 74-98-6 Not Available Not Available = 658 mg/L ( Rat ) 4 h petroleum distillates 64742-88-7 > 5000 mg/kg ( Rat ) = 3000 mg/kg ( Rabbit ) > 5.28 mg/L ( Rat ) 4 h Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Microorganisms Crustacea petroleum distillates 64742-47-8 Not Available 45: 96 h Pimephales promelas mg/L LC50 flow-through 2.2: 96 h Lepomis macrochirus mg/L LC50 static 2.4: 96 h mykiss mg/L LC50 static Not Available 4720: 96 h Den-dronereides heteropoda mg/L LC50 petroleum distillates 64742-88-7 450: 96 h Pseudokirchneriella subcapitata mg/L EC50 800: 96 h Pimephales promelas mg/L LC50 static Not Available 100: 48 h Daphnia magna mg/L EC50 Persistence and Degradability: No information available. Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Page 4 / 5 Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Pressurized container: Do not pierce or burn, even after use. Dispose of in accordance with federal, state and local regulations. Page 65 of 871 Page 65 of 871 Page 65 of 871 Page 65 of 871 ---PAGE BREAK--- 6095 - AIRLIFT FRESH SCENT (AEROSOL) Revision Date: 01-May-2015 14. TRANSPORT INFORMATION DOT: UN/ID No: UN1950 Proper Shipping Name: Aerosols Hazard Class: 2.1 Special Provisions: This product meets the exception requirements of section 49 CFR 173.306 as a limited quantity and may be shipped as a limited quantity. 15. REGULATORY INFORMATION TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product does not contain listed substances above the "de minimus" level SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: Yes Reactive Hazard: No California Proposition 65 This product does not contain any Proposition 65 chemicals 16. OTHER INFORMATION Revision Date: 01-May-2015 Reasons for Revision: No information available. Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 1 Flammability: 1 Instability: 0 Special: N/A HMIS Page 5 / 5 Health Hazards: 1 Flammability: 2 Physical Hazards: 2 Page 66 of 871 Page 66 of 871 Page 66 of 871 Page 66 of 871 ---PAGE BREAK--- Page 1 of 4 Print Date 10/31/2003 MSDS Document Product AP 2000 1. Chemical Product and Company Identification Trade Name of this Product AP 2000 MSDS ID 58338 Manufacturer Lawson Products, Inc. 1666 East Touhy Avenue Des Plaines, IL 60018 Contact Name Corporate Compliance Team Phone Number (847) 827-9666 Emergency Phone (888) 426-4851 Revision Date 01/31/2002 0 2 0 Health: Fire: Reactivity: Specific Health: Fire: Reactivity: Specific 0 2 0 2. Composition and Information on Ingredients Ingredient CAS Number Weight % ACGIH TLV PEL STEL Aliphatic Petroleum Naphtha 50-65 % Oxygenated Hydrocarbon UNKNOWN 15-30 % "Phenol,isopropylated, phosphate 68937-41-7 5-15 % 3. Hazard Identification Synergistic Products N/A EFFECTS OF CHRONIC EXPOSURE TO PRODUCT May be harmful if swallowed. Repeated or prolonged overexposures may cause dermatitis and/or central nervous system effects. Page 67 of 871 Page 67 of 871 Page 67 of 871 Page 67 of 871 ---PAGE BREAK--- Page 2 of 4 Print Date 10/31/2003 MSDS ID 58338 AP 2000 Target Organs Affected Inhalation, skin Medical Conditions Aggravated By Exposure May cause dermatitis on prolonged contact in sensitive individuals. May be harmful or fatal if swallowed. EFFECTS OF OVEREXPOSURE Inhalation:nasal and respiratory irritation, shortness of breath, dizziness, lightheadedness. Eye:irritaiton. Skin:dermatitis. Ingestion:may cause chemical pneumonia if aspirated into lung. Route Of Entry Inhalation Eyes Skin 4. First Aid Information First Aid Procedures Skin/Eye: Flush immediately with cool water and obtain medical aid. Inhalation: Remove to fresh air. Administer oxygen if necessary and consult a physician. Ingestion: Consult a physician immediately. 5. Fire Fighting Measures Flash Point 100 FP Method Tag Closed Cup Extinguishing Media Foam Carbon Dioxide Dry Chemical 6. Accidental Release Measures Material Release Or Spill Remove all sources of ignition, ventilate. Avoid breathing vapors and remove with inert absorbent. 7. Handling and Storage Handling Precautions N/A Storage Store in a cool, dry place away from heat and open flame. Keep out of reach of children Handling Precautions Read Entire Label Before Using. Handling Avoid eye contact and excessive skin contact. Page 68 of 871 Page 68 of 871 Page 68 of 871 Page 68 of 871 ---PAGE BREAK--- Page 3 of 4 Print Date 10/31/2003 MSDS ID 58338 AP 2000 Hygienic Practices Wash hands before eating or using the washroom. Smoke in SMOKING AREAS ONLY. 8. Exposure Controls and Personal Protection Other Protective Equipment Eye wash station and safety showers should be available. Eye Protection Use safety eyewear designed to protect against splash of liquids. Other PPE N/A Protective Gloves Required for prolonged or repeated contact. Ventilation If current ventilation practices are not adequate in maintaining airborne concentrations below the established exposure limits, additional ventilation or exhaust systems may be required. Respiratory Protection Avoid breathing concentrated vapors or particles from all products not specifically designed to be inhaled. 9. Physical and Chemical Properties Physical State Liquid Specific Gravity 0.86 pH N/A Percent Volatile 75.0 ODOR AND APPEARANCE Mild odor, amber color. 10. Stability and Reactivity Incompatibility Avoid contact with strong oxidizing agents. Extended exposure to high temperatures may cause decomposition. CONDITIONS TO AVOID Avoid overheating of product. HAZARDOUS DECOMPOSITION PRODUCTS Oxides of carbon and phosphorus Hazardous Polymerization Will not occur. Page 69 of 871 Page 69 of 871 Page 69 of 871 Page 69 of 871 ---PAGE BREAK--- Page 4 of 4 Print Date 10/31/2003 MSDS ID 58338 AP 2000 11. Toxicological Information Carcinogenicity None of the components in this chemical are listed by IARC, NTP or OSHA as a carcinogen. 12. Ecological Information Ecological Information No information available. 13. Disposal Considerations Waste Disposal Method Must be in accordance with applicable laws and regulations. 14. Transportation Information OSHA CLASS N/A PER DOT N/A DOT Class N/A PER IMCO N/A IMCO Classification Number N/A IATA Classification Number N/A 15. Regulatory Information CPR Certification This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. Other Information Other Precautions No information available. Page 70 of 871 Page 70 of 871 Page 70 of 871 Page 70 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 11-Mar-2013 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 19900 Product name Ban-Rust Recommended Use Coating Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known. Principal Routes of Exposure Skin contact. Skin absorption. Inhalation. Ingestion. Eyes. Potential health effects Eyes May cause the following effects:. Irritation. Pain. Tearing. Reddening. Swelling. Stinging sensation. Feeling like that of fine dust in the eye. Skin Repeated or prolonged exposure may cause skin irritation and dermatitis, due to degreasing properties of the product. Defatting. Chronic exposure causes drying effect on the skin . Inhalation Repeated or prolonged exposure may cause the following effects:. Headaches. Dizziness. Nausea. Decreased blood pressure. Changes in heart rate. Cyanosis. Extreme overexposure may cause. Central nervous system damage. Lung damage. Kidney damage. Harmful by inhalation. Ingestion Harmful or fatal if swallowed. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Stoddard solvent 8052-41-3 15-40 Kerosene 8008-20-6 15-40 Propane/Isobutane/N- Butane 68476-86-8 10-30 2-Butoxyethanol 111-76-2 3-7 4. FIRST AID MEASURES Eye contact Flush eyes immediately with large amounts of water. Seek medical attention if irritation persists. Skin contact Wash off immediately with plenty of water. Remove and wash contaminated clothing before re-use. Seek medical attention. Ingestion Seek medical attention immediately. Do not induce vomiting. Give victim a glass of water or milk. Contact physician or poison control center immediately. Do not give anything by mouth to an unconscious person. Inhalation Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Seek medical attention immediately. 5. FIRE FIGHTING MEASURES Flash point °C -104 Flash point °F -156 Method Closed cup Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 10.6 Lower 0.7 Suitable extinguishing media Alcohol foam. Carbon dioxide (CO2). Dry chemical powder. Foam. Water fog. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 1 / 4 Emergency Overview Vapors irritating to eyes and respiratory tract. Vapors may cause flash fire or explosion. Page 71 of 871 Page 71 of 871 Page 71 of 871 Page 71 of 871 ---PAGE BREAK--- Fire and Explosion Hazards Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Empty containers contain residue and/or vapors. Do not weld, cut, pressurize, braze, solder, drill, grind, or expose such containers to heat, sparks, flame, static electricity, or other sources of ignition. They may explode and cause injury or death. Aerosol containers may vent, rupture or burst when heated to temperatures above 120°F. Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Soak up with noncombustible inert absorbent material. Place in non- leaking, sealed container for proper disposal. 7. HANDLING AND STORAGE Handling Keep in a well-ventilated place. Thoroughly wash hands and exposed skin after handling. Wash hands with soap and water before eating, drinking, smoking, or using toilet facilities. Use only according to label directions. Handle empty containers as if they were full. Avoid breathing vapors. Avoid contact with skin, eyes and clothing. Storage Keep away from heat. Keep away from open flames, hot surfaces and sources of ignition. Do not freeze. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Stoddard solvent 500 ppm 2900 mg/m3 - 100 ppm - Kerosene - - 200 mg/m3 - Propane/Isob utane/N- Butane - - - N/D 2- Butoxyethanol 50 ppm 240 mg/m3 - 20 ppm - Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Hygiene measures Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash hands before eating or using the washroom. Respiratory protection Wear a NIOSH approved air purifying organic cartridge respirator. If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Seek professional advise prior to respirator selection and use. Protection provided by air purifying respirators is limited. Use a positive pressure supplied air respirator. if there is any potential for an uncontrolled release:. where exposure levels are not known. Hand Protection Chemical resistant gloves. Consult glove manufacturer to determine the proper type for a specific operation. Eye protection Use safety eyewear designed to protect against splash of liquids. Wear safety glasses with side shields. Skin and body protection Wear appropriate clothing to minimize skin contact. Rubber or plastic boots. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Amber Odor Citric Odor Threshold No information available pH No data available Specific Gravity 0.7740 Vapor pressure 45-55 Vapor density >Air Evaporation Rate >1 (Butyl Acetate = 1) Water solubility Negligible VOC Content 5.10 Partition Coefficient (n-octanol/water) Not Applicable Boiling point/range °C -41 - 272 Boiling point/range °F -43 - 522 Melting point/range °C 0 Melting point/range °F 32 Flash point °C -104 Flash point °F -156 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions. Conditions to avoid Avoid sources of ignition. Contact with ignition sources, hot-glowing surfaces, electrical arcs, sparks, and open flame. Page 2 / 4 Product name Ban-Rust Product code 19900 Page 72 of 871 Page 72 of 871 Page 72 of 871 Page 72 of 871 ---PAGE BREAK--- Incompatability Strong acids. Oxidizers. Amines. Alkalies. Hazardous Decomposition Products Carbon oxides. Nitrogen oxides (NOx). Chloride. Chlorine. phosgene. Polymerization Hazardous polymerization does not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Stoddard solvent 8052-41-3 - - - Kerosene 8008-20-6 5000 mg/kg 2000 mg/kg 5.28 mg/L Propane/Isobutan e/N-Butane 68476-86-8 - - - 2-Butoxyethanol 111-76-2 470 mg/kg 220 mg/kg 2270 mg/kg 2.21 mg/L 450 ppm Synergistic Products None known Potential health effects Sensitization None known . Chronic toxicity See Section 2 . Mutagenic effects None known . Teratogenic effects None known . Reproductive toxicity None known . Target Organ Effects Central nervous system. Long term exposure to vapor may cause lung damage. Long term exposure to vapor may cause kidney damage. Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Stoddard solvent Not Listed Not Listed Not Listed Not Listed Not Listed Kerosene A3 Not Listed Not Listed Not Listed Not Listed Propane/Isob utane/N- Butane Not Listed Not Listed Not Listed Not Listed Not Listed 2- Butoxyethanol A3 Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT UN1950 Aerosols, flammable, 2.1. Exception: (Compressed Gas not more than 1.0L) Consumer Commodity ORM-D TDG UN1950 AEROSOLS, flammable, 2.1 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting 2-Butoxyethanol Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Stoddard solvent Listed Listed Not Listed Kerosene Listed Listed Not Listed Propane/Isobutane/N- Butane Not Listed Not Listed Not Listed 2-Butoxyethanol Listed Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA Stoddard solvent X X - X Kerosene X X - X Propane/Isobutane/N- Butane X X - X 2-Butoxyethanol X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. OTHER INFORMATION Page 3 / 4 Product code 19900 Water Flea Data Daphnia magna EC501698 - 1940 mg/L (24 h) Daphnia magna EC50>1000 mg/L (48 h) Product name Ban-Rust 2-Butoxyethanol Page 73 of 871 Page 73 of 871 Page 73 of 871 Page 73 of 871 ---PAGE BREAK--- 16. OTHER INFORMATION HMIS Health - 1 Flammability - 4 Physical Hazard - 0 Prepared By H. Buck, Regulatory Affairs Manager The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product code 19900 Product name Ban-Rust Page 74 of 871 Page 74 of 871 Page 74 of 871 Page 74 of 871 ---PAGE BREAK--- Safety Data Sheet Lawson Belt Grip Belt Dressing PAGE 1 of 4 SECTION I - IDENTIFICATION PRODUCT NAME: Belt Grip PRODUCT CODE: 19909 PRODUCT USE: Belt Dressing COMPANY NAME: Lawson Products, Inc COMPANY ADDRESS: 8770 W. Bryn Mawr Ave., Suite 900 Chicago, Il 60631 COMPANY PHONE: [PHONE REDACTED] EMERGENCY PHONE: [PHONE REDACTED] SECTION II – HAZARDS IDENTIFICATION EMERGENCY CLASSIFICATION: Flammable Aerosol: Category 2; Aspiration Hazard HAZARD STATEMENT: DANGER: Extremely Flammable Aerosol Pressurized container: May burst if heated. May be fatal if swallowed and enters airways. SYMBOL: SECTION III – COMPOSITION/HAZARDOUS INGREDIENTS HAZARDOUS INGREDIENT CAS NUMBER PERCENT Aliphatic petroleum distillate 64742-89-8 60-100% Propane/n-Butane 68476-86-8 10-30% Modified Hydrocarbon Resin 68478-07-9 3-7% SECTION IV - FIRST AID MEASURES EYES: Immediately flush with water for 15 - 20 minutes while holding eyelids open. Seek medical attention if irritation persists. INGESTION: If swallowed: Immediately call a poison center or doctor. Do NOT induce vomiting. INHALATION: Move to fresh air. If breathing is difficult or unconscious, administer oxygen. If not breathing administer artificial respiration. Seek medical attention if irritation persists. SKIN: Immediately wash with soap and water for 15 minutes. Seek medical attention if irritation develops. NOTE TO PHYSICIAN: None SECTION V – FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA: Carbon dioxide, foam, and water fog. UNSUITABLE EXTINGUISHING MEDIA: Water spray/stream. SPECIAL FIRE FIGHTING PROCEDURES: Wear NIOSH approved Self Contained Breathing Apparatus with a full face piece operated in a positive pressure demand mode with full body protective clothing when fighting fires. Avoid breathing smoke, fumes, and decomposition products. Cool fire exposed containers with water fog to prevent bursting. UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep away from sparks, open flames, and hot surfaces. No smoking. Do not spray on an open flame or other ignition source. HAZARDOUS COMBUSTION PRODUCTS: Oxides of carbon SECTION VI – ACCIDENTAL RELEASE MEASURES SPILL: Stop leak if you can do so without risk. Move the cylinder/can to a safe and open area if the leak is irreparable. Stop the flow of material, if this is without risk. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Prevent spill from entering sewers, storm drains, and natural waterways. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. WASTE DISPOSAL: Dispose in accordance with local, state and federal laws. Do not reuse, puncture, or incinerate container. Wrap container and place in trash collection Page 75 of 871 Page 75 of 871 Page 75 of 871 Page 75 of 871 ---PAGE BREAK--- Safety Data Sheet Lawson Belt Grip Belt Dressing PAGE 2 of 4 RCRA STATUS: Waste likely considered non-hazardous under RCRA, however product should be fully characterized prior to disposal (40 CFR 261). SECTION VII – HANDLING AND STORAGE HANDLING AND STORAGE: Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Pressurized container: Do not pierce or burn, even after use. OTHER PRECAUTIONS: Keep out of the reach of children. Follow label instructions exactly. SECTION VIII – EXPOSURE CONTROLS/PERSONAL PROTECTION HAZARDOUS INGREDIENT OSHA PEL ACGIH TLV Aliphatic petroleum distillate 500 ppm 300 ppm Propane/n-Butane 1000 ppm 1000 ppm Modified Hydrocarbon Resin 5 mg/m3 5 mg/m3 ENGINEERING CONTROLS / VENTILATION: Ambient ventilation adequate. RESPIRATORY PROTECTION: Not required with normal use. PROTECTIVE CLOTHING: Safety glasses and chemical resistant gloves are recommended. ADDITIONAL MEASURES: Wash hands thoroughly after handling. SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: clear liquid ODOR: Solvent odor ODOR THRESHOLD: Not Known PHYSICAL STATE: Liquid BOILING POINT: Not determined FLASH POINT: Not Tested FLAMMABILITY LOW: Not tested FLAMMABILITY HIGH: Not tested VAPOR PRESSURE (mm Hg): 0.5 @ 77°F (25°C) VAPOR DENSITY (AIR=1): > 1 EVAPORATION RATE: 0.2 SPECIFIC GRAVITY (H2O=1): 0.755 pH: Not Applicable SOLUBILITY IN WATER: 0% SOLIDS 4.8% VOLATILITY INCLUDING WATER 95% VOLATILE ORGANIC COMPOUNDS (VOC): 20% DECOMPOSITION TEMPERATURE: Not determined VISCOCITY: Not tested SECTION X – STABILITY AND REACTIVITY DATA REACTIVITY: Not known. CHEMICAL STABILITY: Stable CONDITIONS TO AVOID: Temperatures greater than 120°F and sources of ignition. INCOMPATIBILITY: Some plastics and painted surfaces, pre-test before using. HAZARDOUS DECOMPOSITION OR BY-PRODUCT: Oxides of carbon HAZARDOUS POLYMERIZATION: Will not occur SECTION XI – TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION: Not Available ROUTES OF ENTRY: Eyes, Ingestion, Inhalation, Skin EYES: May cause irritation. INGESTION: May cause gastric discomfort and nausea. No hazard by this route in normal use. INHALATION: No hazards under normal use due to its low volatility. If vapor is present in high concentrations, irritation to upper respiratory tract may occur. SKIN: May cause irritation, localized defatting, dermatitis, with prolonged or repeated contact. MEDICAL CONDITION AGGRAVATED: None known CHRONIC HEALTH HAZARDS: None known CARCINOGENICITY: OSHA: No ACGIH: No NTP: No IARC: No OTHER: N/A Page 76 of 871 Page 76 of 871 Page 76 of 871 Page 76 of 871 ---PAGE BREAK--- Safety Data Sheet Lawson Belt Grip Belt Dressing PAGE 3 of 4 SECTION XII – ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: Not Available BIODEGRADABILITY: This product is biodegradable. BIOACCUMULATION: This product is not expected to bioaccumulate. SOIL MOBILITY: This product is mobile in soil. SECTION XIII – DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose in accordance with local, state and federal laws. Do not reuse, puncture, or incinerate container. Wrap container and place in trash collection RCRA STATUS: Waste likely considered non-hazardous under RCRA, however product should be fully characterized prior to disposal (40 CFR 261). SECTION XIV - TRANSPORTATION INFORMATION PROPER SHIPPING NAME: ORM-D PACKAGING GROUP: N/A AIR SHIPMENT PROPER SHIPPING NAME: Aerosols, Ltd. Qty. Class 2 HAZARD CLASS/DIVISION: 2.1 UN/NA NUMBER: UN 1950 SHIPPING BY WATER: VESSEL (IMO/IMDG) PROPER SHIPPING NAME: Aerosols, Ltd. Qty. Class 2 HAZARD CLASS/DIVISION: 2.1 UN/NA NUMBER: UN 1950 ENVIRONMENTAL HAZARDS WATER: SECTION XV - REGULATORY INFORMATION TSCA STATUS: All Chemicals are listed or exempt. CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): None SARA 311/312 HAZARD CATEGORIES: None SARA 313 REPORTABLE INGREDIENTS: None STATE REGULATIONS: California Proposition 65: None INTERNATIONAL REGULATIONS: All components are listed or exempted. NFPA HEALTH: 1 HMIS HEALTH: 1 NFPA FLAMMABILITY: 3 HMIS FLAMMABILITY: 3 NFPA REACTIVITY: 0 HMIS REACTIVITY: 0 NFPA OTHER: None HMIS PROTECTION: B SECTION XVI - ADDTIONAL INFORMATION PREPARATION BY: Maureen Ruggeberg, Regulatory Affairs Specialist DATE PREPARED: 01/04/2014 REVISION DATE: 01/04/2014 DISCLAIMER: To the best of our knowledge, information contained herein is accurate. However there is no assumption of liability for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazard which exists. The information contained in this MSDS was obtained from current and reliable sources; however, the data is provided without any warranty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of the manufacturer, the manufacturer will not be Page 77 of 871 Page 77 of 871 Page 77 of 871 Page 77 of 871 ---PAGE BREAK--- Safety Data Sheet Lawson Belt Grip Belt Dressing PAGE 4 of 4 responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. Page 78 of 871 Page 78 of 871 Page 78 of 871 Page 78 of 871 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Essentially Similar to U.S. Department of Labor Form OSHA Revised 07/11/2013 HMIS Health-1 Flammability-4 Physical Hazard -1 Personal Protection x SECTION I-Product Information Manufacturer: A.V.W. Inc. 24 Hour Emergency Phone Number: [PHONE REDACTED] Product Name: Blow Off Air Duster 152a Synonym(s): Blow Off Air Duster Blow Off Auto Duster 3.5oz 8oz Blow Off 152a Duster 3.5oz 8oz 10oz Trade Name: 152a Chemical Name: Ethane, 11,-Difluoro FSPID: Front 152a Model No: Blow Off 3.5 oz, Blow Off 8 oz, Blow Off 10oz. Product Use: Cleaning SECTION II-Hazardous Identification Emergency Overview DANGER Flammable gas. Contents under pressure. Containers may explode when heated. Potential short term health effects Routes of exposure Eye, Skin contact, Inhalation. Eyes Contact with liquid may cause frostbite. Skin Contact with liquid may cause frostbite. Inhalation Excessive intentional inhalation may cause respiratory tract irritation and central Nervous system effects (headache, dizziness). Vapors may cause dizziness or suffocation. Ingestion Not a normal route of exposure. Target organs Eyes. Skin. Respiratory system. Chronic effects Prolonged or repeated exposure can cause drying, defatting and dermatitis. Signs and may include redness, dryness of the skin. Odor, Color, Grade Clear, colorless with slight ethereal odor. General Physical Form Gas Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and explode. May cause frostbite. May cause target organ effects. SECTION III-Composition on Ingredients Component CAS # 75-37-6 % by Wt 100% 1, 1-DIFLUOROETHANE SECTION IV-First Aid Measures Skin: Flush with cool water. Wash affected area with soap and water. If persist, get medical attention. Eye contact: Immediately flush with large amounts of cool water. Remove contact lenses, if applicable, and continue flushing for 15 minutes. Obtain medical attention immediately. Inhalation: If develop, move victim to fresh air. If persist, obtain medical attention. Page 79 of 871 Page 79 of 871 Page 79 of 871 Page 79 of 871 ---PAGE BREAK--- If breathing has stopped, trained personnel should administer CPR immediately. Ingestion: Do not induce vomiting. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention. SECTION V-Firefighting Measures Flammable Properties Flammable by WHMIS/OSHA criteria. Containers may explode when heated. Autoignition temperature 849 °F Flash Point: < 50 °F (Details: consumer aerosol does not exhibit a flame projection, therefore it is not determined to be flammble as defined in 16 CFR, Section 1500.3(c) (viii). Flammable Limits-LEL 3.9% volume Flammable Limits-UEL 16.9% volume Extinguishing media Suitable extinguishing media Small Fires: Dry chemical. Carbon dioxide. Water spray. Fog. Unsuitable extinguishing media: Not available Protection of firefighters specific hazards arising from the chemical Contents under pressure. Pressurized container may explode when exposed to heat or flame. Cool containers with flooding quantities of water until well after fire is out. Protective equipment for firefighters Firefighters should wear full protective clothing including self contained breathing apparatus. Hazardous combustionproducts May include and are not limited to: Oxides of carbon. Fluoride gases. Explosion data Sensitivity to mechanical impact Not available Sensitivity to static discharge Not available SECTION VI-Accidental Release Measures Accidental Release Measures Refer to other sections of this MSDS for information regarding physical and health hazard, respiratory protection, ventilation, and personal protective equipment. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with fresh air. Close cylinder. If the cylinder can’t be closed, place in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors. Dispose of collected material as soon as possible. Personal precautions keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak. Methods for containment Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up Before attempting clean up, refer to hazard data given above. Remove sources of ignition. Page 80 of 871 Page 80 of 871 Page 80 of 871 Page 80 of 871 ---PAGE BREAK--- Although the chance of a significant spill or leak is unlikely in aerosol containers, in the event of such an occurrence, absorb spilled material with a non-flammable absorbent such as sand or vermiculite. SECTON VII-Handling and Storage Handling: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Contents may be under pressure, open carefully. Keep away from heat, sparks, open flam, pilot lights and other sources of ignition. No smoking while handling this material. Avoid eye contact with vapors, mists, or spray. Avoid breathing mists or aerosols of this product. Use good industrial hygiene practices in handling this material. Storage: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep out of reach of children. Do not store at temperatures above 49°C (120.2°F). Keep away from heat, open flames or other sources of ignition. Store away from acids. Keep container in well-ventilated area. SECTION VIII-Exposure Controls/Personal Protection Engineering Controls: Do not use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment Personal protective equipment Respiratory protection: Do not breathe vapors. Use with adequate ventilation. Keep container closed. For emergencies select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half face piece or full face pressure demand self-contained breathing apparatus. Hand protection: If there is constant skin contact, rubber gloves are recommended. Eye/Face protection: Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields. Skin protection: Wear insulated gloves to protect against frostbite. General hygiene considerations: Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. Wash hands and face before breaks and immediately after handling product. SECTION IX-Physical and Chemical Properties Form: Liquefied gas Form: colorless Odor: slight, ethereal Page 81 of 871 Page 81 of 871 Page 81 of 871 Page 81 of 871 ---PAGE BREAK--- Odor threshold: Not available Ph: Not available Physical state: Gas Melting point: Not available Melting point: Freezing point: Boiling point/ Boiling range: -25°C (-13.00 Flash point: -50°C (-58.00 Vapor Pressure: 599.43 kPa @25°C Specific gravity: 0.91 Relative density: 0.9 g/cc @2°C Vapour density: 2.4 @25°C Flammability limits in air, Lower, % by volume 3.9 Flammability limits in air, upper, % by volume 16.9 Octanol.wate coefficient Not available Solubility (H20) Auto-ignition temperature 454 °C (849.20 Percent volatile: 100 SECTION X-Stability and Reactivity Chemical stability: Stable under recommended storage conditions. Conditions to avoid: Stable under recommended storage conditions. Hazardous decomposition Products: May include and are not limited to: Oxides of carbon. Fluoride gases. Possibility of hazardous reactions: Hazardous polymerization does not occur. SECTION XI-Toxicological Information Eye irritation Contact with liquid may cause frostbite. Skin Contact with liquid may cause frostbite. Inhalation Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effects (headache, dizziness). Vapors may cause dizziness or suffocation. Ingestion Not a normal route of exposure. Sensitization Non-hazardous by WHMIS/OSHA criteria Chronic effects Non-hazardous by WHMIS/OSHA criteria Carcinogenicity Non-hazardous by WHMIS/OSHA criteria Mutagenicity Non-hazardous by WHMIS/OSHA criteria Reproductive effects Non-hazardous by WHMIS/OSHA criteria Teratogenicity Non-hazardous by WHMIS/OSHA criteria Synergistic Materials Not Available Page 82 of 871 Page 82 of 871 Page 82 of 871 Page 82 of 871 ---PAGE BREAK--- SECTION X11-Ecological Information Ecotoxicity Not available Environmental effects Product contains no ozone depleting CFCs Aquatic toxicity Not available Persistence / degradability Not available Bioaccumulation / accumulation Not available Partition coefficient Not available Mobility in environmental media Not available Chemical fate information Not available Other adverse effects Not available SECTION X111-Disposal Considerations Waste Code: Not available Disposal instructions Review federal, state/provincial, and local government requirements prior to disposal. Waste from residues/unusedNot available Contaminated packaging Not available SECTION XIV – Transportation Information U.S Department of Transportation (DOT) International Maritime Organization (IMO) Basic shipping requirements: 1, 1-Difluoroethane Transportation of Dangerous Goods (TDG – Canada) Hazard class 2.1 UN number 1030 Additional Information: DOT/IMO Label: FLAMMABLE GAS Special Information: CARGO AIRCRAFT ONLY DOT -2Q DOT-SP11516 IATA/CAO (Air) Basic shipping requirements: Proper shipping name: 1, 1-Difluoroethane Hazard class: 1030 Additional information: Page 83 of 871 Page 83 of 871 Page 83 of 871 Page 83 of 871 ---PAGE BREAK--- Maximum net quantity Cargo aircraft only-150 kg maximum Packaging (Forbidden on passenger aircraft) SECTION XV-Regulatory Information Occupational Safety and Health Administration (OSHA) 29 CFR 1910.1200 hazardous Yes CERCLA (Superfund) reportable quantity None Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard Yes Delayed Hazard No Fire Hazard Yes Pressure Hazard Yes Reactivity Hazard No Section 302 extremely No hazardous substances Section 311 hazardous chemical Yes Clean Air Act (CAA) Not available Clean Water Act (CWA) Not available WHMIS status Controlled WHMIS classification Class A – Compressed Gas, Class B – Division 1 – Flammable Gas State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. Inventory name Country(s) or region Inventory Canada Domestic Substances List (DSL) Canada Non-Domestic Substances List (NDSL) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory SECTION XVI-Other Information NFPA Hazard Classification Health: 1 Flammability: 4 Reactivity: 1 Physical hazard: 0 HMIS Hazard Classification Health: 1 Flammability: 4 Page 84 of 871 Page 84 of 871 Page 84 of 871 Page 84 of 871 ---PAGE BREAK--- Reactivity: 1 Protection: X – See PPE section Page 85 of 871 Page 85 of 871 Page 85 of 871 Page 85 of 871 ---PAGE BREAK--- Keson Industries, Inc. 810 Commerce Street Aurora, IL 60504 Date Prepared: January 1, 2014 Marking Chalk BLUE The information herein is given in good faith but no warranty, expressed or implied, is made 1 MATERIAL SAFETY DATA SHEET SECTION 1 Product Name: Concentrated (color) indicator Marking Chalk-Blue For Information Call: 1-[PHONE REDACTED] SECTION II-Hazardous Ingredients of Mixture Principal Component CAS # OSHA PEL ACGIH, TLV Ultramarine Blue 57455-37-5 NA 10 mg/m3 Calcium Carbonate 471-34-1 15 mg/m3 10 mg/m3 Silicon Dioxide 7631-86-9 6.00 mg/m3 10.00 mg/m3 SECTION III-Physical Data Boiling Point: N/A Specific Gravity (H2O=1) 2.4 Vapor Pressure: N/A Solubility in Water: Negligible % Volatile by weight: N/A Vapor Pressure: N/A Appearance: Odorless Blue Powder pH 5-8 solution) SECTION IV- Fire and Explosion Data Flash Point: Non-Flammable Extinguishing Media: Non-Flammable Special Firefighting Procedures: NIOSH Approved respirator and protective clothing should be worn. Use water spray to cool equipment and containers. Unusual Fire Explosion Hazards: None known. SECTION V-Health Hazard Data Routes of Entry: Skin-Yes, Inhalation-Yes, Ingestion-Yes, Eyes-Yes. Carcinogenicity-Calcium Carbonate contains silica at levels between 0.01-2%. There is some evidence that this material may be carcinogenic. Limit exposure to the lowest limit possible. Effects of Overexposure: Eye Contact- Irritating to eyes Skin Contact- None noted Inhalation- May cause irritation to the nose, throat and respiratory tract. Ingestion- Harmful or fatal if swallowed. Emergency First Aid Procedures: Eye Contact: Flush with warm water, lifting the eyelids periodically for 15 minutes. Consult a physician if condition persists. Skin Contact: Wash affected area with warm soapy water. If irritation occurs, consult a physician. Ingestion: Call a physician immediately. Inhalation: Remove victim from dust area to fresh air. Give artificial respiration if not breathing. Call a physician. Page 86 of 871 Page 86 of 871 Page 86 of 871 Page 86 of 871 ---PAGE BREAK--- Keson Industries, Inc. 810 Commerce Street Aurora, IL 60504 Date Prepared: January 1, 2014 Marking Chalk BLUE The information herein is given in good faith but no warranty, expressed or implied, is made 2 SECTION VI-Reactivity Data Stability: Stable Conditions to avoid: None known. Incompatibility (materials to avoid): Strong acids liberate carbon dioxide. Hazardous Decomposition Products: Combustion will produce toxic oxides of carbon and calcium oxide. Hazardous Polymerization: Will not occur. SECTION VII-Spill or Leak Procedures Vacuum or scoop material into approved containers for reclamation or disposal. If excessive dust is generated, wear NIOSH approved respirator for mineral dust. SECTION VIII-Special Protection Information Respiratory Protection: An approved NIOSH respirator should be worn when TWA limits are exceeded. Ventilation: Use local ventilation to keep dust levels below recommended exposure limits. If exposure limits are exceeded, a NIOSH approved respirator for mineral dust should be worn. Protective Clothing: Employees must wear gloves. Eye Protection: Chemical safety goggles or safety glasses with splash guards. Other Protective equipment: Eye bath and safety shower should be available. SECTION IX- Special Precautions Precautions to be taken in handling and storage: Do not store near acids. Follow normal good housekeeping procedures. Other Precautions: Wash hands thoroughly after handling. Wash contaminated clothing before reuse. SECTION X- Regulatory Status TSCA Inventory Status: This material is a mixture, the ingredients of which are on TSCA inventory. RCRA: This material, when disposed of, is not specifically listed as a hazardous waste according to federal regulations unless it meets the USEPA definitions for being toxic, corrosive, ignitable or reactive, or it is mixed with or comes in contact with a listed hazardous waste. Consult local, state and federal regulations. California Proposition 65: See Section XI SECTION XI-Other Regulatory Information CHEMICAL NAME/ CAS NUMBER CONCENTRATION STATE CODE Arsenic/7440-38-2 <30 ppm * CA, MA Cadmium/7440-43-9 <5 ppm* CA,MA Lead/7439-92-1 <30 ppm * CA * Content of these materials may vary from batch to batch. CA= California Proposition 65 MA= Massachusetts Hazardous Substance List Page 87 of 871 Page 87 of 871 Page 87 of 871 Page 87 of 871 ---PAGE BREAK--- Keson Industries, Inc. 810 Commerce Street Aurora, IL 60504 Date Prepared: January 1, 2014 Marking Chalk BLUE The information herein is given in good faith but no warranty, expressed or implied, is made 3 HMIS CODE: NFPA CODE: Health 1 Health 1 Flammability 0 Flammability 0 Reactivity 0 Reactivity 0 Page 88 of 871 Page 88 of 871 Page 88 of 871 Page 88 of 871 ---PAGE BREAK--- 1HYHU6HH]5HJXODU*UDGH&PSG V FRYHUHG 06'6QDPH 0L[WXUH &$6QXPEHU 0LGGOHWRQ0$ 86$ 0DQXIDFWXUHU V 3HUFHQW &RSSHU3RZGHU =LQFR[LGH &20326,7,21,1)250$7,2121,1*5(',(176 (PHUJHQF\RYHUYLHZ 6.,1&217$&7 6NLQ (\HV ,1+$/$7,21 DQGH\HV ,1*(67,21 6NLQ 7DUJHWRUJDQV 0DWHULDOQDPH 1HYHU6HH]5HJXODU*UDGH&PSG 0DWHULDO,' 9HUVLRQ -8/3ULQWGDWH 06'6 Page 89 of 871 Page 89 of 871 Page 89 of 871 Page 89 of 871 ---PAGE BREAK--- )LUVWDLG 6NLQ E\H[SRVXUH IRJ 1RQH.QRZQ 1RQH.QRZQ 1RQH.QRZQ KD]DUGV 6WRUDJH 6725$*( (;32685(&21752/63(5621$/3527(&7,21 0DWHULDOQDPH 1HYHU6HH]5HJXODU*UDGH&PSG 0DWHULDO,' 9HUVLRQ -8/3ULQWGDWH 06'6 Page 90 of 871 Page 90 of 871 Page 90 of 871 Page 90 of 871 ---PAGE BREAK--- 7/97:$ PHWDOGXVW &RSSHU3RZGHU IXPH &X ILEHUV =LQFR[LGH WRWDOGXVW &RSSHU3RZGHU UHVSLUDEOHGXVW =LQFR[LGH IXPH WRWDOGXVW PLOVRUJUHDWHU 7DUJHWVROLGV &+(0,&$/3523(57,(6 1$ 2GRUWKUHVKROG 1$ *UHDVHOLNH 2GRU 6LOYHU\*UD\ &RORU 3DVWH 1R JO 92& +D]DUGRXV :LOOQRWRFFXU 6WDELOLW\ =LQFR[LGH 2UDO/'0RXVH PJNJ &KURQLFHIIHFWV JO 92& ',6326$/&216,'(5$7,216 0DWHULDOQDPH 1HYHU6HH]5HJXODU*UDGH&PSG 0DWHULDO,' 9HUVLRQ -8/3ULQWGDWH 06'6 Page 91 of 871 Page 91 of 871 Page 91 of 871 Page 91 of 871 ---PAGE BREAK--- '27 75$163257,1)250$7,21 +D]DUGFODVV 81QXPEHU 5(*8/$725<,1)250$7,21 &RSSHU3RZGHU OEILQDO54 ILQDO54 GXVWRUIXPHRQO\ &RSSHU3RZGHU +HDOWK )ODPPDELOLW\ 3K\VLFDOKD]DUG 'HOD\HG+D]DUG1R )LUH+D]DUG1R 3UHVVXUH+D]DUG1R &$7(*25,(6 1RQFRQWUROOHG 'LVFODLPHU 27+(5,1)250$7,21 ,VVXHGDWH 0DWHULDOQDPH 1HYHU6HH]5HJXODU*UDGH&PSG 0DWHULDO,' 9HUVLRQ -8/3ULQWGDWH 06'6 Page 92 of 871 Page 92 of 871 Page 92 of 871 Page 92 of 871 ---PAGE BREAK--- 3UHSDUHGE\ 0DWHULDOQDPH 1HYHU6HH]5HJXODU*UDGH&PSG 0DWHULDO,' 9HUVLRQ -8/3ULQWGDWH 06'6 Page 93 of 871 Page 93 of 871 Page 93 of 871 Page 93 of 871 ---PAGE BREAK--- SAFETY DATA SHEET Version 1.0 Revision Date 05/27/2015 Print Date 06/16/2015 1 / 10 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Material name : BRREAKER Premium Rust Breaking Penetrant Material number : DA8060 Manufacturer or supplier's details Company : Lawson Products, Inc. Address : 8770 W. Bryn Mawr Ave., Suite 900 Chicago, IL 60631 Telephone : 7733045050 Emergency telephone numbers: : 8884264851 SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Appearance Aerosol containing a liquefied gas Colour colourless Odour solvent-like GHS Classification Gases under pressure : Liquefied gas Carcinogenicity : Category 2 GHS Label element Hazard pictograms : Signal word : Warning Hazard statements : H280 Contains gas under pressure; may explode if heated. H351 Suspected of causing cancer. Precautionary statements : Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P281 Use personal protective equipment as required. Response: P308 + P313 IF exposed or concerned: Get medical advice/ attention. Storage: P405 Store locked up. Page 94 of 871 Page 94 of 871 Page 94 of 871 Page 94 of 871 ---PAGE BREAK--- SAFETY DATA SHEET Version 1.0 Revision Date 05/27/2015 Print Date 06/16/2015 2 / 10 P410 + P403 Protect from sunlight. Store in a well-ventilated place. Disposal: P501 Dispose of contents/container in accordance with local regulation. Potential Health Effects Carcinogenicity: IARC Group 2B: Possibly carcinogenic to humans 108-10-1 ACGIH Confirmed animal carcinogen with unknown relevance to humans 108-10-1 OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Chemical Name CAS-No. Concentration 1,1-difluoroethane 75-37-6 70 - < 90 108-10-1 1 - < 5 oleic acid 112-80-1 1 - < 5 SECTION 4. FIRST AID MEASURES General advice : Do not leave the victim unattended. Move out of dangerous area. Show this safety data sheet to the doctor in attendance. If inhaled : If unconscious place in recovery position and seek medical advice. If persist, call a physician. In case of skin contact : If skin irritation persists, call a physician. Wash off immediately with plenty of water for at least 15 minutes. If on clothes, remove clothes. In case of eye contact : Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If in eyes, rinse with water for 15 minutes. If swallowed : Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If persist, call a physician. Page 95 of 871 Page 95 of 871 Page 95 of 871 Page 95 of 871 ---PAGE BREAK--- SAFETY DATA SHEET Version 1.0 Revision Date 05/27/2015 Print Date 06/16/2015 3 / 10 DO NOT induce vomiting unless directed to do so by a physician or poison control center. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Carbon dioxide (CO2) Foam Dry powder Unsuitable extinguishing media : High volume water jet Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : Carbon dioxide (CO2) Carbon monoxide Smoke Fluorine compounds Silicon oxides Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Special protective equipment for firefighters : Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Remove all sources of ignition. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Sweep up or vacuum up spillage and collect in suitable container for disposal. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Page 96 of 871 Page 96 of 871 Page 96 of 871 Page 96 of 871 ---PAGE BREAK--- SAFETY DATA SHEET Version 1.0 Revision Date 05/27/2015 Print Date 06/16/2015 4 / 10 SECTION 7. HANDLING AND STORAGE Advice on safe handling : Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Dispose of rinse water in accordance with local and national regulations. Conditions for safe storage : BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. Keep in a dry place. Observe label precautions. Keep in a well-ventilated place. Electrical installations / working materials must comply with the technological safety standards. Materials to avoid : Oxidizing agents Store and keep away from bases and alkalies. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis 1,1-difluoroethane 75-37-6 TWA 1,000 ppm US WEEL 108-10-1 TWA 20 ppm ACGIH STEL 75 ppm ACGIH TWA 50 ppm 205 mg/m3 NIOSH REL ST 75 ppm 300 mg/m3 NIOSH REL TWA 100 ppm 410 mg/m3 OSHA Z-1 TWA 50 ppm 205 mg/m3 OSHA P0 STEL 75 ppm 300 mg/m3 OSHA P0 Biological occupational exposure limits Component CAS-No. Control parameters Biological specimen Sampling time Permissible concentration Basis ONE 108-10-1 MIBK Urine End of shift (As soon as possible after exposure ceases) 1 mg/l ACGIH BEI Personal protective equipment Page 97 of 871 Page 97 of 871 Page 97 of 871 Page 97 of 871 ---PAGE BREAK--- SAFETY DATA SHEET Version 1.0 Revision Date 05/27/2015 Print Date 06/16/2015 5 / 10 Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Safety glasses Skin and body protection : impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. Hygiene measures : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Aerosol containing a liquefied gas Colour : colourless Odour : solvent-like Odour Threshold : no data available pH : not applicable Melting point/freezing point : no data available Boiling point : no data available Flash point : no data available Evaporation rate : no data available Upper explosion limit : no data available Lower explosion limit : no data available Vapour pressure : no data available Density : 0.91 g/cm3 Solubility(ies) Water solubility : negligible Partition coefficient: n- octanol/water : no data available Auto-ignition temperature : not determined Thermal decomposition : no data available Viscosity Viscosity, kinematic : no data available Heat of combustion : 10.08 kJ/g Page 98 of 871 Page 98 of 871 Page 98 of 871 Page 98 of 871 ---PAGE BREAK--- SAFETY DATA SHEET Version 1.0 Revision Date 05/27/2015 Print Date 06/16/2015 6 / 10 SECTION 10. STABILITY AND REACTIVITY Reactivity : Stable Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : Vapours may form explosive mixture with air. Conditions to avoid : Heat, flames and sparks. Incompatible materials : Oxidizing agents Bases Alkaline earth metals Hazardous decomposition products : Carbon oxides SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Product: Acute inhalation toxicity : Acute toxicity estimate : > 10 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method Components: 1,1-difluoroethane: Acute inhalation toxicity : LC50 mouse: 977,000 mg/l Exposure time: 2 h Skin corrosion/irritation Product: Remarks: May cause skin irritation and/or dermatitis. Components: oleic acid: Species: human skin Exposure time: 72 h Result: Mild skin irritation Serious eye damage/eye irritation Product: Remarks: Vapours may cause irritation to the eyes, respiratory system and the skin. Respiratory or skin sensitisation no data available Germ cell mutagenicity Page 99 of 871 Page 99 of 871 Page 99 of 871 Page 99 of 871 ---PAGE BREAK--- SAFETY DATA SHEET Version 1.0 Revision Date 05/27/2015 Print Date 06/16/2015 7 / 10 no data available Carcinogenicity no data available Reproductive toxicity no data available 1,1-difluoroethane: oleic acid: STOT - single exposure no data available STOT - repeated exposure no data available Aspiration toxicity no data available Further information Product: Remarks: no data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity no data available Persistence and degradability no data available Bioaccumulative potential Product: Partition coefficient: n- octanol/water : Remarks: no data available Mobility in soil no data available Other adverse effects no data available Product: Regulation 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + Page 100 of 871 Page 100 of 871 Page 100 of 871 Page 100 of 871 ---PAGE BREAK--- SAFETY DATA SHEET Version 1.0 Revision Date 05/27/2015 Print Date 06/16/2015 8 / 10 Additional ecological information : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal., Harmful to aquatic life with long lasting effects. SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION Transportation Regulation: 49 CFR (USA): ORM-D, CONSUMER COMMODITY Transportation Regulation: IMDG (Vessel): UN1950, AEROSOLS, NON-FLAMMABLE, 2.2, - Limited quantity Transportation Regulation: IATA (Cargo Air): UN1950, AEROSOLS, NON-FLAMMABLE, 2.2, - Limited quantity Transportation Regulation: IATA (Passenger Air): UN1950, AEROSOLS, NON-FLAMMABLE, 2.2, - Limited quantity Transportation Regulation: TDG (Canada): UN1950, AEROSOLS, NON-FLAMMABLE, 2.2, - Limited quantity SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) 108-10-1 5000 * Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity Page 101 of 871 Page 101 of 871 Page 101 of 871 Page 101 of 871 ---PAGE BREAK--- SAFETY DATA SHEET Version 1.0 Revision Date 05/27/2015 Print Date 06/16/2015 9 / 10 This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Sudden Release of Pressure Hazard Chronic Health Hazard SARA 302 : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : The following components are subject to reporting levels established by SARA Title III, Section 313: 108-10-1 4.776 % California Prop 65 WARNING! This product contains a chemical known to the State of California to cause cancer. 108-10-1 The components of this product are reported in the following inventories: TSCA On TSCA Inventory DSL This product contains one or several components that are not on the Canadian DSL nor NDSL. AICS Not in compliance with the inventory NZIoC Not in compliance with the inventory PICCS Not in compliance with the inventory IECSC Not in compliance with the inventory Inventory Acronym and Validity Area Legend: AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: OSHA GHS Label Information: Flammability Health Instability 3 1 0 Special hazard. FLAMMABILITY PHYSICAL HAZARD HEALTH 0 2 3* 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 102 of 871 Page 102 of 871 Page 102 of 871 Page 102 of 871 ---PAGE BREAK--- SAFETY DATA SHEET Version 1.0 Revision Date 05/27/2015 Print Date 06/16/2015 10 / 10 Hazard pictograms : Signal word : Warning: Hazard statements : Contains gas under pressure; may explode if heated. Suspected of causing cancer. Precautionary statements : Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Response: IF exposed or concerned: Get medical advice/ attention. Storage: Store locked up. Protect from sunlight. Store in a well-ventilated place. Disposal: Dispose of contents/container in accordance with local regulation. Version: 1.0 Revision Date: 05/27/2015 Print Date: 06/16/2015 We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. Users should make their own investigations to determine the suitability and applicability of the information for their particular purposes. This SDS has been prepared by the Compliance Services organization supporting this manufacturer, supplier or distributor. Page 103 of 871 Page 103 of 871 Page 103 of 871 Page 103 of 871 ---PAGE BREAK--- Page 104 of 871 Page 104 of 871 Page 104 of 871 Page 104 of 871 ---PAGE BREAK--- Page 105 of 871 Page 105 of 871 Page 105 of 871 Page 105 of 871 ---PAGE BREAK--- Page 106 of 871 Page 106 of 871 Page 106 of 871 Page 106 of 871 ---PAGE BREAK--- Page 107 of 871 Page 107 of 871 Page 107 of 871 Page 107 of 871 ---PAGE BREAK--- Page 108 of 871 Page 108 of 871 Page 108 of 871 Page 108 of 871 ---PAGE BREAK--- Page 109 of 871 Page 109 of 871 Page 109 of 871 Page 109 of 871 ---PAGE BREAK--- Page 110 of 871 Page 110 of 871 Page 110 of 871 Page 110 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 19-Jul-2012 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code DA8060 Product name BRRR-Eaker Recommended Use Lubricant Supplier Drummond, A Lawson Brand Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions Asthma. Allergies. Principal Routes of Exposure Eyes. Skin contact. Inhalation. Ingestion. Potential health effects Eyes Contact with eyes may cause irritation. Causes burns. Frostbite. Pain. Tearing. Redness. Conjunctivitis. Skin May cause the following effects: . Skin Irritation. Frostbite. Skin burns. Repeated or prolonged exposure may cause:. May cause skin irritation. Exposure can dry the skin. Inhalation Harmful by inhalation. May cause irritation of respiratory tract. Possible May cause the following effects. Drowsiness . Dizziness. Aspiration hazard. Chemical pneumonitis. Ingestion No hazard under normal industrial and institutional use. May be harmful if swallowed. Aspiration hazard. May cause severe lung damage if aspirated into the lungs from ingestion or vomiting. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % 1,1-Difluoroethane 75-37-6 60-100 Methylisobutyl ketone 108-10-1 1-5 Oleic Acid 112-80-1 1-5 4. FIRST AID MEASURES General advice S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Show this safety data sheet to the doctor in attendance. Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Seek medical attention if irritation persists. Skin contact Wash off immediately with plenty of water. Remove contaminated clothing and footwear. Wash contaminated clothing before re-use. Seek medical attention if irritation persists. Ingestion Do Not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to physician of poisoning may not appear for several hours. Keep under medical supervision for at least 48 hours. 5. FIRE FIGHTING MEASURES Flash point °C -58 Flash point °F -72 Method Tag Closed Cup Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper No data available Lower No data available Suitable extinguishing media Dry powder. Foam. Carbon dioxide. Extinguishing media which must NOT be used for safety reasons Do not use water. Do not use a solid water stream as it may scatter and spread fire . Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Special Fire-Fighting Procedures Keep people away from and upwind of spill/leak. Specific hazards Flammable . Page 1 / 4 Emergency Overview Flammable. Harmful by inhalation. May cause eye/skin irritation. Contents under pressure. CONTAINER MAY EXPLODE IF HEATED . Page 111 of 871 Page 111 of 871 Page 111 of 871 Page 111 of 871 ---PAGE BREAK--- Fire and Explosion Hazards CONTAINER MAY EXPLODE IF HEATED . Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Hazardous decomposition products See Section 10. Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective equipment. Keep people away from and upwind of spill/leak. Remove all sources of ignition. Environmental precautions Concentrated vapors of this product are heavier than air and will collect in low areas, pits, storage tanks and other confined spaces. Do not enter those areas. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. Do not flush into surface water or sanitary sewer system. Methods for cleaning up Evacuate area of unprotected and unnecessary personnel. Personnel should wear appropriate protective equipment. Follow all precautions for handling. Please refer to appropriate sections of MSDS for additional information. Eliminate all sources of ignition. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use caution as spill may create a slip hazard. Clean up by sweeping or vacuum. Place in suitable container for disposal as hazardous waste. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. Allow to evaporate. 7. HANDLING AND STORAGE Handling Keep away from open flames, hot surfaces and sources of ignition. Do not smoke. Avoid contact with skin and eyes. Do not swallow. Do not breathe vapors or spray mist. Avoid breathing fumes. Use in a well ventilated area. Handle and open container with care. When using, do not eat, drink or smoke. Wash hands with soap and water before eating, drinking, smoking, or using toilet facilities. Do not puncture or incinerate. Storage Keep out of the reach of children. Keep containers closed in a cool, well-ventilated place. Store in temperatures below 120 degrees F (50 degrees C) . 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) 1,1- Difluoroethan e - - - - Methylisobutyl ketone 100 ppm 410 mg/m3 - 20 ppm 75 ppm Oleic Acid - - - - Ventilation and Environmental Controls Adequate ventilation should be provided to keep exposure levels below current acceptable exposure limits. Hygiene measures General industrial hygiene practice. When using, do not eat, drink or smoke. A safety shower and eye wash station should be available for emergency use. Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment. Hand Protection Protective gloves. Eye protection S39 - Wear eye/face protection. Use safety eyewear designed to protect against splash of liquids. Skin and body protection Wear suitable protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Colorless - Light yellow Odor Characteristic Odor Threshold No information available pH Not Applicable Specific Gravity 0.91 Vapor pressure No data available Vapor density >1 (Air = 1) Evaporation Rate No data available Water solubility Negligible VOC Content 4.8% Partition Coefficient (n-octanol/water) No data available Boiling point/range °C No data available Boiling point/range °F No data available Melting point/range °C No data available Melting point/range °F No data available Flash point °C -58 Flash point °F -72 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Heating may cause an explosion. Conditions to avoid Avoid heat. Do not store or use near incompatible materials. Incompatability Oxidizers. Bases. Alkali metals. Page 2 / 4 Product code DA8060 Product name BRRR-Eaker Page 112 of 871 Page 112 of 871 Page 112 of 871 Page 112 of 871 ---PAGE BREAK--- Hazardous Decomposition Products Carbon oxides. Hydrofluoric acid. Carbonyl Fluoride. Polymerization Stable under normal storage conditions. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) 1,1- Difluoroethane 75-37-6 - - - Methylisobutyl ketone 108-10-1 2080 mg/kg 16000 mg/kg 8.2 mg/L Oleic Acid 112-80-1 25 g/kg - - Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity See Section 2 . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects See Section 2 Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns 1,1- Difluoroethan e Not Listed Not Listed Not Listed Not Listed Not Listed Methylisobutyl ketone A3 Group 2B Not Listed Not Listed Listed Oleic Acid Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Aquatic toxicity Harmful to aquatic organisms Do not let product enter drains 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT UN1950 Aerosols, flammable, 2.1. Exception: (Compressed Gas not more than 1.0L) Consumer Commodity ORM-D TDG UN1950 AEROSOLS, flammable, 2.1 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Methylisobutyl ketone Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 1,1-Difluoroethane Listed Not Listed Not Listed Methylisobutyl ketone Listed Listed Carcinogen Oleic Acid Not Listed Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA 1,1-Difluoroethane X X - X Methylisobutyl ketone X X - X Oleic Acid X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION NFPA Health - 2 Flammability - 3 Reactivity - 0 HMIS Health - 2 Page 3 / 4 Microtox Data Photobacterium phosphoreum EC50=79.6 mg/L (5 min) Product name BRRR-Eaker Water Flea Data Daphnia magna EC50=170 mg/L (48 h) Methylisobutyl ketone Product code DA8060 Page 113 of 871 Page 113 of 871 Page 113 of 871 Page 113 of 871 ---PAGE BREAK--- 16. OTHER INFORMATION Flammability - 3 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product name BRRR-Eaker Product code DA8060 Page 114 of 871 Page 114 of 871 Page 114 of 871 Page 114 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 19-Jul-2012 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code DA8060 Product name BRRR-Eaker Recommended Use Lubricant Supplier Drummond, A Lawson Brand Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions Asthma. Allergies. Principal Routes of Exposure Eyes. Skin contact. Inhalation. Ingestion. Potential health effects Eyes Contact with eyes may cause irritation. Causes burns. Frostbite. Pain. Tearing. Redness. Conjunctivitis. Skin May cause the following effects: . Skin Irritation. Frostbite. Skin burns. Repeated or prolonged exposure may cause:. May cause skin irritation. Exposure can dry the skin. Inhalation Harmful by inhalation. May cause irritation of respiratory tract. Possible May cause the following effects. Drowsiness . Dizziness. Aspiration hazard. Chemical pneumonitis. Ingestion No hazard under normal industrial and institutional use. May be harmful if swallowed. Aspiration hazard. May cause severe lung damage if aspirated into the lungs from ingestion or vomiting. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % 1,1-Difluoroethane 75-37-6 60-100 Methylisobutyl ketone 108-10-1 1-5 Oleic Acid 112-80-1 1-5 4. FIRST AID MEASURES General advice S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Show this safety data sheet to the doctor in attendance. Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Seek medical attention if irritation persists. Skin contact Wash off immediately with plenty of water. Remove contaminated clothing and footwear. Wash contaminated clothing before re-use. Seek medical attention if irritation persists. Ingestion Do Not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to physician of poisoning may not appear for several hours. Keep under medical supervision for at least 48 hours. 5. FIRE FIGHTING MEASURES Flash point °C -58 Flash point °F -72 Method Tag Closed Cup Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper No data available Lower No data available Suitable extinguishing media Dry powder. Foam. Carbon dioxide. Extinguishing media which must NOT be used for safety reasons Do not use water. Do not use a solid water stream as it may scatter and spread fire . Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Special Fire-Fighting Procedures Keep people away from and upwind of spill/leak. Specific hazards Flammable . Page 1 / 4 Emergency Overview Flammable. Harmful by inhalation. May cause eye/skin irritation. Contents under pressure. CONTAINER MAY EXPLODE IF HEATED . Page 115 of 871 Page 115 of 871 Page 115 of 871 Page 115 of 871 ---PAGE BREAK--- Fire and Explosion Hazards CONTAINER MAY EXPLODE IF HEATED . Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Hazardous decomposition products See Section 10. Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective equipment. Keep people away from and upwind of spill/leak. Remove all sources of ignition. Environmental precautions Concentrated vapors of this product are heavier than air and will collect in low areas, pits, storage tanks and other confined spaces. Do not enter those areas. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. Do not flush into surface water or sanitary sewer system. Methods for cleaning up Evacuate area of unprotected and unnecessary personnel. Personnel should wear appropriate protective equipment. Follow all precautions for handling. Please refer to appropriate sections of MSDS for additional information. Eliminate all sources of ignition. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use caution as spill may create a slip hazard. Clean up by sweeping or vacuum. Place in suitable container for disposal as hazardous waste. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. Allow to evaporate. 7. HANDLING AND STORAGE Handling Keep away from open flames, hot surfaces and sources of ignition. Do not smoke. Avoid contact with skin and eyes. Do not swallow. Do not breathe vapors or spray mist. Avoid breathing fumes. Use in a well ventilated area. Handle and open container with care. When using, do not eat, drink or smoke. Wash hands with soap and water before eating, drinking, smoking, or using toilet facilities. Do not puncture or incinerate. Storage Keep out of the reach of children. Keep containers closed in a cool, well-ventilated place. Store in temperatures below 120 degrees F (50 degrees C) . 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) 1,1- Difluoroethan e - - - - Methylisobutyl ketone 100 ppm 410 mg/m3 - 20 ppm 75 ppm Oleic Acid - - - - Ventilation and Environmental Controls Adequate ventilation should be provided to keep exposure levels below current acceptable exposure limits. Hygiene measures General industrial hygiene practice. When using, do not eat, drink or smoke. A safety shower and eye wash station should be available for emergency use. Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment. Hand Protection Protective gloves. Eye protection S39 - Wear eye/face protection. Use safety eyewear designed to protect against splash of liquids. Skin and body protection Wear suitable protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Colorless - Light yellow Odor Characteristic Odor Threshold No information available pH Not Applicable Specific Gravity 0.91 Vapor pressure No data available Vapor density >1 (Air = 1) Evaporation Rate No data available Water solubility Negligible VOC Content 4.8% Partition Coefficient (n-octanol/water) No data available Boiling point/range °C No data available Boiling point/range °F No data available Melting point/range °C No data available Melting point/range °F No data available Flash point °C -58 Flash point °F -72 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Heating may cause an explosion. Conditions to avoid Avoid heat. Do not store or use near incompatible materials. Incompatability Oxidizers. Bases. Alkali metals. Page 2 / 4 Product code DA8060 Product name BRRR-Eaker Page 116 of 871 Page 116 of 871 Page 116 of 871 Page 116 of 871 ---PAGE BREAK--- Hazardous Decomposition Products Carbon oxides. Hydrofluoric acid. Carbonyl Fluoride. Polymerization Stable under normal storage conditions. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) 1,1- Difluoroethane 75-37-6 - - - Methylisobutyl ketone 108-10-1 2080 mg/kg 16000 mg/kg 8.2 mg/L Oleic Acid 112-80-1 25 g/kg - - Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity See Section 2 . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects See Section 2 Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns 1,1- Difluoroethan e Not Listed Not Listed Not Listed Not Listed Not Listed Methylisobutyl ketone A3 Group 2B Not Listed Not Listed Listed Oleic Acid Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Aquatic toxicity Harmful to aquatic organisms Do not let product enter drains 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT UN1950 Aerosols, flammable, 2.1. Exception: (Compressed Gas not more than 1.0L) Consumer Commodity ORM-D TDG UN1950 AEROSOLS, flammable, 2.1 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Methylisobutyl ketone Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 1,1-Difluoroethane Listed Not Listed Not Listed Methylisobutyl ketone Listed Listed Carcinogen Oleic Acid Not Listed Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA 1,1-Difluoroethane X X - X Methylisobutyl ketone X X - X Oleic Acid X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION NFPA Health - 2 Flammability - 3 Reactivity - 0 HMIS Health - 2 Page 3 / 4 Microtox Data Photobacterium phosphoreum EC50=79.6 mg/L (5 min) Product name BRRR-Eaker Water Flea Data Daphnia magna EC50=170 mg/L (48 h) Methylisobutyl ketone Product code DA8060 Page 117 of 871 Page 117 of 871 Page 117 of 871 Page 117 of 871 ---PAGE BREAK--- 16. OTHER INFORMATION Flammability - 3 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product name BRRR-Eaker Product code DA8060 Page 118 of 871 Page 118 of 871 Page 118 of 871 Page 118 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 02-May-2014 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 19951 Product name C-Thru Glass Cleaner Recommended Use Cleaner Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Eyes. Ingestion. Inhalation. Skin absorption. Skin contact. Potential health effects Eyes Contact with eyes may cause irritation. Extreme overexposure may cause. Burn. Frostbite. Skin Direct contact may cause the following effects. Skin Irritation. Dermatitis. Extreme overexposure may cause. Skin burns. Frostbite. Inhalation Extreme overexposure may cause. Shortness of breath. Dizziness. Light headedness. Central nervous system effects. Changes in heart rate. Kidney damage. Liver damage. Respiratory irritation. Decreased blood pressure. Loss of coordination. Coma. Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Ingestion May cause chemical pneumonitis if aspirated into lungs. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Isopropyl Alcohol 67-63-0 2-7 Propane 74-98-6 1-6 Butane 106-97-8 1-6 Propylene Glycol Propyl Ether 1569-01-3 1-6 4. FIRST AID MEASURES Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 20 minutes. Seek medical attention. Skin contact Wash area thoroughly with soap and water. Ingestion If a large quantity of liquid is swallowed, do NOT induce vomiting. Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. Seek medical attention. Inhalation Remove to fresh air. Provide oxygen if breathing is difficult. If not breathing, give artificial respiration. Keep warm and quiet. Seek medical attention. 5. FIRE FIGHTING MEASURES Flash point °C -104 Flash point °F -156 Method No information available Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 12% Lower 1.3% Suitable extinguishing media Alcohol foam. Carbon dioxide (CO2). Dry chemical powder. Foam. Water fog. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fire and Explosion Hazards Material is highly volatile and readily gives off vapors. Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat . Page 1 / 4 Emergency Overview Irritant. May be harmful if swallowed. Page 119 of 871 Page 119 of 871 Page 119 of 871 Page 119 of 871 ---PAGE BREAK--- Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Ensure adequate ventilation. Evacuate personnel to safe areas. Remove all sources of ignition. Clean-up methods - small spill Soak up with inert absorbent material. Dispose of absorbent in accordance with local, state and federal regulations. Clean-up methods - large spill Dike or dam large spills. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. Dispose of absorbent in accordance with local, state and federal regulations. 7. HANDLING AND STORAGE Handling Keep container closed when not in use. Keep away from open flames, hot surfaces and sources of ignition. Storage Keep container closed. Keep away from direct sunlight. Keep away from open flames, hot surfaces and sources of ignition. Store in temperatures below 120 degrees F (50 degrees C) . Containers exposed to extreme heat may burst. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Butane 800 ppm - - 1000 ppm Propane 1000 ppm 1800 mg/m3 - 1000 ppm - Propylene Glycol Propyl Ether - - - - Isopropyl Alcohol 400 ppm 980 mg/m3 - 200 ppm 400 ppm Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. General: as necessary. Use with adequate explosion-proof ventilation to meet the limits in Section 8 . Hygiene measures Remove and wash contaminated clothing before re-use. Other precautions Use personal protective equipment. Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Hand Protection Protective gloves. Eye protection ANSI approved safety glasses or splash goggles with face shield are recommended. Skin and body protection None necessary under normal conditions 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Colorless Odor Characteristic Odor Threshold No information available pH Not Applicable Specific Gravity No data available Vapor pressure No data available Vapor density No data available Evaporation Rate < 1 (ether = 1) Water solubility No data available VOC Content 7.85% Partition Coefficient (n-octanol/water) Not Applicable Boiling point/range °C Not Applicable Boiling point/range °F Not Applicable Melting point/range °C No data available Melting point/range °F No data available Flash point °C -104 Flash point °F -156 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Heat, flames and sparks. Avoid contact with aluminum . Do not store above 120 degrees F. Incompatability Acetaldehyde. Acids. Chlorine. Ethylene oxide. Isocyanates. Strong oxidizing agents. Page 2 / 4 Product name C-Thru Glass Cleaner Product code 19951 Page 120 of 871 Page 120 of 871 Page 120 of 871 Page 120 of 871 ---PAGE BREAK--- Hazardous Decomposition Products Carbon dioxide. Carbon monoxide. Polymerization Hazardous polymerization does not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Butane 106-97-8 - - 658 g/m3 Propane 74-98-6 - - 658 mg/L Propylene Glycol Propyl Ether 1569-01-3 2490 mg/kg 3550 mg/kg - Isopropyl Alcohol 67-63-0 4396 mg/kg 12800 mg/kg 16000 ppm Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity None known Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects See Section 2. Carcinogenic effects See Table Below. Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Butane Not Listed Not Listed Not Listed Not Listed Not Listed Propane Not Listed Not Listed Not Listed Not Listed Not Listed Propylene Glycol Propyl Ether Not Listed Not Listed Not Listed Not Listed Not Listed Isopropyl Alcohol A4 Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Disposal Information Dispose of all product, residues and clean-up materials in accordance with local, state, and federal regulations. Full or partially full containers are considered hazardous waste. 14. TRANSPORTATION INFORMATION DOT Consumer commodity, ORM-D. TDG Consumer commodity, ORM-D. 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Isopropyl Alcohol Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Butane Listed Listed Not Listed Propane Listed Listed Not Listed Propylene Glycol Propyl Ether Not Listed Not Listed Not Listed Isopropyl Alcohol Not Listed Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA Butane X X - X Propane X X - X Propylene Glycol Propyl Ether X X - X Isopropyl Alcohol X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. OTHER INFORMATION NFPA Health - 3 Flammability - 4 Reactivity - 0 Page 3 / 4 Isopropyl Alcohol Product name C-Thru Glass Cleaner Microtox Data Photobacterium phosphoreum EC50=35390 mg/L (5 min) Product code 19951 Water Flea Data Daphnia magna EC50=13299 mg/L (48 h) Page 121 of 871 Page 121 of 871 Page 121 of 871 Page 121 of 871 ---PAGE BREAK--- 16. OTHER INFORMATION HMIS Health - 3 Flammability - 4 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product code 19951 Product name C-Thru Glass Cleaner Page 122 of 871 Page 122 of 871 Page 122 of 871 Page 122 of 871 ---PAGE BREAK--- Page 123 of 871 Page 123 of 871 Page 123 of 871 Page 123 of 871 ---PAGE BREAK--- Page 124 of 871 Page 124 of 871 Page 124 of 871 Page 124 of 871 ---PAGE BREAK--- Page 125 of 871 Page 125 of 871 Page 125 of 871 Page 125 of 871 ---PAGE BREAK--- Page 126 of 871 Page 126 of 871 Page 126 of 871 Page 126 of 871 ---PAGE BREAK--- Page 127 of 871 Page 127 of 871 Page 127 of 871 Page 127 of 871 ---PAGE BREAK--- Page 128 of 871 Page 128 of 871 Page 128 of 871 Page 128 of 871 ---PAGE BREAK--- Page 129 of 871 Page 129 of 871 Page 129 of 871 Page 129 of 871 ---PAGE BREAK--- Page 130 of 871 Page 130 of 871 Page 130 of 871 Page 130 of 871 ---PAGE BREAK--- Product Name: CAT DIESEL ENGINE OIL SAE 10W-30 Revision Date: 22 Jun 2011 Page 1 of 9 MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: CAT DIESEL ENGINE OIL SAE 10W-30 Product Description: Base Oil and Additives MSDS Number: 17711 Intended Use: Engine oil COMPANY IDENTIFICATION Supplier: Imperial Oil Products Division 240 4th Avenue Calgary, ALBERTA. T2P 3M9 Canada 24 Hour Environmental / Health Emergency Telephone 1-[PHONE REDACTED] Transportation Emergency Phone Number 1-[PHONE REDACTED] Product Technical Information 1-[PHONE REDACTED] Supplier General Contact 1-[PHONE REDACTED] SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 3 HAZARDS IDENTIFICATION This material is not considered to be hazardous according to regulatory guidelines see Section 15. HEALTH EFFECTS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES Page 131 of 871 Page 131 of 871 Page 131 of 871 Page 131 of 871 ---PAGE BREAK--- Product Name: CAT DIESEL ENGINE OIL SAE 10W-30 Revision Date: 22 Jun 2011 Page 2 of 9 INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulphur oxides, Incomplete combustion products, Oxides of carbon FLAMMABILITY PROPERTIES Flash Point [Method]: >215C (419F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. Page 132 of 871 Page 132 of 871 Page 132 of 871 Page 132 of 871 ---PAGE BREAK--- Product Name: CAT DIESEL ENGINE OIL SAE 10W-30 Revision Date: 22 Jun 2011 Page 3 of 9 SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE HANDLING Avoid contact with used product. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present during switch-loading operations). Use proper bonding and/or earthing procedures. However, bonding and earthing may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. STORAGE The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols can occur the following is recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction). NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. Page 133 of 871 Page 133 of 871 Page 133 of 871 Page 133 of 871 ---PAGE BREAK--- Product Name: CAT DIESEL ENGINE OIL SAE 10W-30 Revision Date: 22 Jun 2011 Page 4 of 9 PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Physical State: Liquid Form: Clear Colour: Amber Odour: Characteristic Odour Threshold: N/D Page 134 of 871 Page 134 of 871 Page 134 of 871 Page 134 of 871 ---PAGE BREAK--- Product Name: CAT DIESEL ENGINE OIL SAE 10W-30 Revision Date: 22 Jun 2011 Page 5 of 9 IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 0.866 Flash Point [Method]: >215C (419F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapour Density (Air = N/D Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20°C Evaporation Rate (n-butyl acetate = N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 76 cSt (76 mm2/sec) at 40°C I 11.5 cSt (11.5 mm2/sec) at 100C Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -27°C (-17°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation Toxicity (Rat): LC50 > 5000 mg/m3 Minimally Toxic. Based on test data for structurally similar materials. Irritation: No end point data. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components. Ingestion Toxicity (Rat): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Skin Toxicity (Rabbit): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Irritation (Rabbit): Data available. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials. Page 135 of 871 Page 135 of 871 Page 135 of 871 Page 135 of 871 ---PAGE BREAK--- Product Name: CAT DIESEL ENGINE OIL SAE 10W-30 Revision Date: 22 Jun 2011 Page 6 of 9 Eye Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials. CHRONIC/OTHER EFFECTS For the product itself: Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Oils that are used in gasoline engines may become hazardous and display the following properties: Carcinogenic in animal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains aromatic compounds (PAC) from combustion products of gasoline and/or thermal degradation products. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request. CMR Status: None. Chemical Name CAS Number List Citations PHOSPHORUS 7723-14-0 4 --REGULATORY LISTS SEARCHED-- 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Not expected to be harmful to aquatic organisms. MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. Page 136 of 871 Page 136 of 871 Page 136 of 871 Page 136 of 871 ---PAGE BREAK--- Product Name: CAT DIESEL ENGINE OIL SAE 10W-30 Revision Date: 22 Jun 2011 Page 7 of 9 SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (TDG): Not Regulated for Land Transport LAND (DOT): Not Regulated for Land Transport SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code AIR (IATA): Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION WHMIS Classification: Not controlled This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Complies with the following national/regional chemical inventory requirements: AICS, PICCS, ENCS, KECI, TSCA, EINECS, DSL The Following Ingredients are Cited on the Lists Below: None. Page 137 of 871 Page 137 of 871 Page 137 of 871 Page 137 of 871 ---PAGE BREAK--- Product Name: CAT DIESEL ENGINE OIL SAE 10W-30 Revision Date: 22 Jun 2011 Page 8 of 9 Chemical Name CAS Number List Citations PHOSPHORUS 7723-14-0 6 ZINC DITHIOPHOSPHATE 68649-42-3 6 --REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 06: Notification Procedures - Header was modified. Section 11: Acute Toxicity Table Header was modified. Section 09: Phys/Chem Properties Note was modified. Section 11: Ingestion Acute Lethality - Header was modified. Section 11: Inhalation - Header was modified. Section 09: Evaporation Rate - Header was modified. Section 07: Handling and Storage-Handling was modified. Section 07: Handling and Storage-Storage Phrases was modified. Section 11: Dermal Lethality Test Data was modified. Section 11: Oral Lethality Test Data was modified. Section 11: Inhalation Lethality Test Data was modified. Section 05: Hazardous Combustion Products was modified. Section 06: Accidental Release- Spill Management- Water was modified. Section 09: Flash Point C(F) was modified. Section 09 Viscosity was modified. Section 09 Viscosity was modified. Section 14: Sea (IMDG) - Header was modified. Section 14: Air (IATA) - Header was modified. Section 14: LAND (TDG) - Header was modified. Section 14: LAND (DOT) - Header was modified. Section 14: LAND (DOT) - Default was modified. Section 14: LAND (TDG) Default was modified. Section 14: Sea (IMDG) - Default was modified. Section 14: Air (IATA) - Default was modified. Section 15: National Chemical Inventory Listing - Header was modified. Section 15: National Chemical Inventory Listing was modified. Section 08: Exposure limits/standards was modified. Hazard Identification: Hazards Note was modified. Section 16: CA Prepared by - Header was modified. Section 09: Oxidizing Properties was modified. Section 01: Product Identification Product Name was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 11: Tox List Cited Table was modified. Section 09: Form - Header was added. Page 138 of 871 Page 138 of 871 Page 138 of 871 Page 138 of 871 ---PAGE BREAK--- Product Name: CAT DIESEL ENGINE OIL SAE 10W-30 Revision Date: 22 Jun 2011 Page 9 of 9 Section 09: Physical State was added. Section 15: Canadian List Citations Table was added. Section 15: Chemical Name - Header was added. Section 15: CAS Number - Header was added. Section 15: List Citations -Header was added. Section 13: Regulatory Disposal Information - Header was added. Section 13: Regulatory Disposal Information - Header was deleted. Section 09: Form - Header was deleted. Section 09: Physical State was deleted. WHMIS Classification: Not controlled The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. DGN: 5016288 (1010588) Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, IH and Product Safety Page 139 of 871 Page 139 of 871 Page 139 of 871 Page 139 of 871 ---PAGE BREAK--- SAFETY DATA SHEET State Chemical Division – State Industrial Products State Chemical Ltd. 5915 Landerbrook Drive, Mayfield Heights 1745 Meyerside Dr., Unit Mississauga, Ontario L5T 1C6 (905) 670-4669 Ohio 44124-4034 [PHONE REDACTED] 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: CLEAR OUT 24 Hour CHEMTREC Number: [PHONE REDACTED] Product Description: A lemon-scented granular drain opener. MSDS Number: M01303 2. HAZARDS IDENTIFICATION ***EMERGENCY OVERVIEW*** Corrosive - Category 1 Toxicity - Category 4 DANGER Hazard Statements: H314 Causes severe skin burns and eye damage. H332 Harmful if inhaled. H290 May be corrosive to metals H317 May cause an allergic skin reaction. H301 Toxic if swallowed. Precautionary Statements: P260 Avoid breathing fume. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P264 Wash hands thoroughly after handling. P280 Wear protective gloves, protective clothing, and eye protection. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredients CAS Number Weight ACGIH OSHA Sodium Hydroxide 1310-73-2 < 45% 2 mg/m3 2 mg/m3 Aluminum 7429-90-5 < 10% 2 mg/m3 NA Sodium Nitrate 7631-99-4 < 35% NE NE 4. FIRST AID MEASURES P390 Absorb spillage to prevent material damage. P312 Call a POISON CENTER or physician if you feel unwell. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P312+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. P303+P361+P353 IF ON SKIN (or hair): Remove immediately all contaminated clothing. Rinse SKIN with water. P302+P352 IF ON SKIN: wash with plenty of soap and water. P333+P313 IF SKIN irritation or rash occurs: Get medical advice/attention. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or physician. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 Wash contaminated clothing before reuse. 5. FIRE FIGHTING MEASURES Flashpoint: None by TCC or TOC. Lower Explosive Limit(LEL): NA Upper Explosive Limit(UEL): NA Autoignition Temperature: NA Flammable Properties: Contact with flammable liquids, acids and organic halogen compounds may cause fires. Extinguishing Media: Use an extinguishing media appropriate for surrounding fire. Fire Fighting Instructions: Wear a self-contained breathing apparatus with full protective clothing. 6. ACCIDENTAL RELEASE MEASURES Ventilate area. Wear protective goggles and gloves. Sweep the excess powder up and return to container. Flush any residues with plenty of water and follow with a mild hydrochloric acid rinse. Follow All Federal, State and Local Regulations regarding waste disposal. 7. HANDLING AND STORAGE Handling: Wear goggles or face shield and a long-sleeved shirt. Contact lenses should not be worn when working with this product. Wash hands thoroughly after handling. Never mix with any acid or any other chemicals. Do not allow water to get into container. Read and follow all label directions and precautions carefully. Avoid contact with eyes, skin and clothing. Do not take internally. Storage: Keep containers closed when not in use. Do not store below freezing temperatures. Keep out of reach of children. P406 Store in corrosive resistant container with a resistant inner liner. P405 Store locked up. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering Controls: Provide sufficient mechanical ventilation to maintain exposure below TLV limit. Page 140 of 871 Page 140 of 871 Page 140 of 871 Page 140 of 871 ---PAGE BREAK--- Personal Protective Equipment: Respiratory: None normally required. If workplace exposure limit is exceeded, a NIOSH-approved respirator is advised in the absence of environmental control. Eye: Wear approved safety glasses or goggles with unperforated sideshields. Skin: Wear chemically- resistant gloves. Wear long sleeves and long pants. Other: An emergency eyewash station or source of clean potable water should be available in case of accidental eye contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Yellow Odor: Lemon Physical State: Granular powder pH: NA Solubility in Water: Soluble Specific Gravity: NA Boiling Point: NA VOC Content: 0% 10. STABILITY AND REACTIVITY Stability: Stable. Hazardous Polymerization: Will not occur. Conditions to Avoid: Do not allow water to get into containers. Never use this product in an Aluminum container. Never mix with any other chemicals. Incompatibility: Acids, flammable liquids and halogenated materials. May affect some plastics. The heat generated by overuse of this product may distort plastic (PVC) pipes. Hazardous Decomposition Products: Ammonia. 11. TOXICOLOGICAL INFORMATION IARC / NTP / OSHA: This product contains no ingredient at 0.1% or greater that is listed as a human carcinogen. Hazardous Ingredients CAS Number LD50 LC50 Sodium Hydroxide 1310-73-2 500 mg/kg (oral rabbit) 179 mg/l/96 hr (flathead minnow) Aluminum 7429-90-5 NE NE Sodium Nitrate 7631-99-4 180 mg/kg (oral rat) 7.5 ppm/48 hr (mosquito fish) 12. ECOLOGICAL INFORMATION NA 13. DISPOSAL CONSIDERATIONS Dispose of residue in chemical receptacle in a sanitary landfill. Do not reuse empty containers. Follow All Federal, State and Local Regulations regarding waste disposal. P501 Dispose of container to in accordance with all Federal, State and Local Regulations regarding waste disposal. 14. TRANSPORT INFORMATION DOT Shipping Data: For containers 2.2 pounds or less: Consumer Commodity, ORM-D. After 12/31/13: Ship: Limited Quantity For containers greater than 2.2 pounds: Corrosive Solid, Basic, Inorganic, N.O.S., (Sodium Hydroxide), 8, UN3262, II Canadian TDG: For containers 2.2 pounds or less: Shipped in accordance with 49 CFR as part of a transborder shipment authorized under Section 5.2 of the Canadian Transportation of Dangerous Goods. For containers greater than 2.2 pounds: Corrosive Solid, Basic, Inorganic, N.O.S., (Sodium Hydroxide), 8, UN3262, II For International Shipments by Air: Corrosive Solid, Basic, Inorganic, N.O.S., (Sodium Hydroxide), 8, UN3262, II For International Shipments by Vessel: Corrosive Solid, Basic, Inorganic, N.O.S., (Sodium Hydroxide), 8, UN3262, II, Limited Quantity 15. REGULATORY INFORMATION TSCA: All chemicals in this product are listed or exempt from listing on the TSCA inventory. CEPA: All chemicals in this product are listed or exempt from listing on the Canadian DSL/NDSL. Proposition 65: Raw materials used in this product have identified the opportunity for the presence of very low levels of the following Proposition 65 chemicals: Arsenic 7440-38-2 < 0.001 ppm Cadmium Fume 7440-43-9 < 688 ppm Chromium 7440-43-9 < 0.001 ppm Lead 7439-92-1 < 68 ppm Nickel 7440-02-0 < 68 ppm SARA 313: This product contains no toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). HMIS RATING: Health = 3 Flammability = 0 Reactivity = 1 Personal Protection = B WHIMS RATING: Class D, Division 1B; Class E 16. OTHER INFORMATION NA = Not Available or Not Applicable NE = Not Established Read and follow all label directions and precautions before using the product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF THE REACH OF CHILDREN. While we believe that the data contained herein is factual and the opinions expressed are those of qualified experts, the data are not to be taken as a warranty or representation for which the company assumes legal responsibility. They are offered solely for your consideration, investigation, and verification. Any use of these data and information must be determined by the user to be in accordance with applicable Federal, State, and Local Laws and regulations. HEALTH AND SAFETY INFORMATION: (216) 861-7114 Prepared On: October 2013 Replaces: October 2010 Completed By: Regulatory Affairs Specialist Page 141 of 871 Page 141 of 871 Page 141 of 871 Page 141 of 871 ---PAGE BREAK--- SAFETY DATA SHEET Issuing Date January 5, 2015 Revision Date New Revision Number 0 Page 1 / 8 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Clorox Disinfecting Wipes - Fresh Scent Other means of identification Drug Identification Number 02246233 Recommended use of the chemical and restrictions on use Recommended use Moistened disinfecting wipes Uses advised against No information available Details of the supplier of the safety data sheet Supplier Address The Clorox Company of Canada Ltd. 150 Biscayne Crescent Brampton, Ontario L6W 4V3 Phone: 1-[PHONE REDACTED] Emergency telephone number Emergency Phone Numbers For Medical Emergencies call: 1-[PHONE REDACTED] For Transportation Emergencies, call Chemtrec: 1-[PHONE REDACTED] Page 142 of 871 Page 142 of 871 Page 142 of 871 Page 142 of 871 ---PAGE BREAK--- Clorox® Disinfecting Wipes - Fresh Scent Revision Date New Page 2 / 8 2. HAZARDS IDENTIFICATION Classification This product is not considered hazardous under GHS. GHS Label elements, including precautionary statements Emergency Overview This product is not considered hazardous under GHS. Appearance Clear, colourless liquid absorbed into white, non-woven wipes Physical State Thin liquid absorbed into non-woven wipes Odour Fruity, apple, floral Precautionary Statements - Prevention None Precautionary Statements - Response None Precautionary Statements - Storage None Precautionary Statements - Disposal None Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity 21.5% of the mixture consists of ingredient(s) of unknown toxicity Other information No information available Interactions with Other Chemicals No information available. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. Weight % Trade Secret Ethylene glycol monohexyl ether 112-25-4 1 - 5 * n-Alkyl (68% C12, 32% C14) dimethyl ammonium chloride 85409-23-0 0.1 - 0.2 * n-Alkyl C12, 60% C14, 30% C16, 5% C18) dimethyl benzyl ammonium chloride 53516-76-0 0.1 - 0.2 * * The exact percentage (concentration) of composition has been withheld as a trade secret. Page 143 of 871 Page 143 of 871 Page 143 of 871 Page 143 of 871 ---PAGE BREAK--- Clorox® Disinfecting Wipes - Fresh Scent Revision Date New Page 3 / 8 4. FIRST AID MEASURES First aid measures General Advice Show this safety data sheet to the doctor in attendance. Eye Contact Hold eye open and rinse slowly and gently with water for 15 - 20 minutes. If present, remove contact lenses after the first 5 minutes of rinsing, then continue rinsing eye. Call a poison control center or doctor for further treatment advice. Skin Contact Rinse skin with plenty of water. If irritation persists, call a doctor. Inhalation Move to fresh air. If breathing problems develop, call a doctor. Ingestion Drink a glassful of water. Call a doctor or poison control center. Most important and effects, both acute and delayed Most Important and Effects Liquid may cause eye irritation. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical Hazardous Combustion Products Oxides of carbon. Explosion Data Sensitivity to Mechanical Impact No. Sensitivity to Static Discharge No. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 144 of 871 Page 144 of 871 Page 144 of 871 Page 144 of 871 ---PAGE BREAK--- Clorox® Disinfecting Wipes - Fresh Scent Revision Date New Page 4 / 8 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Avoid contact with eyes. Other Information Refer to protective measures listed in Sections 7 and 8. Environmental precautions Environmental Precautions See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up Containerize. Wash residual down to sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed-down material. 7. HANDLING AND STORAGE Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes, skin, and clothing. Do not eat, drink, or smoke when using this product. Conditions for safe storage, including any incompatibilities Storage Keep containers closed in a dry, cool, and well-ventilated place. Incompatible Products None known. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Ethylene glycol monohexyl ether 112-25-4 None None None n-Alkyl (68% C12, 32% C14) dimethyl ammonium chloride 85409-23-0 None None None n-Alkyl C12, 60% C14, 30% C16, 5% C18) dimethyl benzyl ammonium chloride 53516-76-0 None None None ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health. Page 145 of 871 Page 145 of 871 Page 145 of 871 Page 145 of 871 ---PAGE BREAK--- Clorox® Disinfecting Wipes - Fresh Scent Revision Date New Page 5 / 8 Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection No special protective equipment required. Skin and Body Protection No special protective equipment required. Respiratory Protection No protective equipment is needed under normal use conditions. If irritation is experienced, ventilation and evacuation may be required. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Physical State Thin liquid absorbed into non-woven wipes Appearance Clear liquid absorbed into non-woven wipes Odour Fruity, apple, floral Colour Colourless liquid - white non-woven wipes Odour Threshold No information available Property Values Remarks/ Method pH 6 - 9 (liquid) None known Melting/freezing point No data available None known Boiling point / boiling range No data available None known Flash Point No data available None known Evapouration rate No data available None known Flammability (solid, gas) No data available None known Flammability Limits in Air Upper flammability limit No data available None known Lower flammability limit No data available None known Vapour pressure No data available None known Vapour density No data available None known Specific Gravity ~1.0 (liquid) None known Water Solubility Complete (liquid) None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/water No data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known Explosive Properties Not explosive Oxidizing Properties No data available Other Information Softening Point No data available VOC Content No data available Particle Size No data available Particle Size Distribution No data available Page 146 of 871 Page 146 of 871 Page 146 of 871 Page 146 of 871 ---PAGE BREAK--- Clorox® Disinfecting Wipes - Fresh Scent Revision Date New Page 6 / 8 10. STABILITY AND REACTIVITY Reactivity No data available. Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid None known based on information supplied. Incompatible materials None known. Hazardous Decomposition Products None known. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information . Inhalation Exposure to vapour or mist may irritate respiratory tract. Eye Contact Liquid may cause irritation. Skin Contact Liquid may cause slight irritation. Ingestion Ingestion of liquid may cause slight irritation to mucous membranes and gastrointestinal tract. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Ethylene glycol monohexyl ether 112-25-4 739 mg/kg (Rat) 721 mg/kg (Rabbit) >0.5 mg/L (Rat, 4 h) Information on toxicological effects Liquid may cause redness and tearing of eyes. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Mutagenic Effects No information available. Carcinogenicity None of the ingredients in this product are on the IARC, OSHA, or NTP carcinogen lists. Reproductive Toxicity No information available. Page 147 of 871 Page 147 of 871 Page 147 of 871 Page 147 of 871 ---PAGE BREAK--- Clorox® Disinfecting Wipes - Fresh Scent Revision Date New Page 7 / 8 STOT - single exposure No information available. STOT - repeated exposure No information available. Chronic Toxicity No known effect based on information supplied. Target Organ Effects Respiratory system, eyes, skin, gastrointestinal tract (GI). Aspiration Hazard No information available. Numerical measures of toxicity - Product Information ATEmix (oral) 40.1 g/kg ATEmix (dermal) 59.8 g/kg 12. ECOLOGICAL INFORMATION Ecotoxicity No information available. Persistence and Degradability No information available. Bioaccumulation No information available. Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Disposal methods Dispose of in accordance with all existing federal, provincial, and municipal environmental regulations. Contaminated Packaging Do not reuse empty containers. Dispose of in accordance with all existing federal, provincial, and municipal environmental regulations. 14. TRANSPORT INFORMATION DOT Not regulated. TDG Not regulated. ICAO Not regulated. IATA Not regulated IMDG/IMO Not regulated Page 148 of 871 Page 148 of 871 Page 148 of 871 Page 148 of 871 ---PAGE BREAK--- Clorox® Disinfecting Wipes - Fresh Scent Revision Date New Page 8 / 8 15. REGULATORY INFORMATION Chemical Inventories TSCA All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt from listing. DSL/NDSL All components are on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List Canada Regulations WHMIS Hazard Class D2B Toxic materials 16. OTHER INFORMATION NFPA Health Hazard 1 Flammability 0 Instability 0 Physical and Chemical Hazards - HMIS Health Hazard 1 Flammability 0 Physical Hazard 0 Personal Protection A Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-[PHONE REDACTED] Preparation/Revision Date January 5, 2015 Revision Note Reference New 1073291-A/174194.002 General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 149 of 871 Page 149 of 871 Page 149 of 871 Page 149 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 14-Jan-2008 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product code 29569 Product name Cold Pipe Insulation Spray Recommended Use Coating Supplier Lawson Products, Inc. 1666 East Touhy Avenue Des Plaines, IL 60018 (847)-827-9666 Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions Pre-existing heart conditions. Pre-existing lung disorders. Principal Routes of Exposure Eyes. Skin. Inhalation. Ingestion. Potential health effects Eyes Irritation. Skin May cause eye/skin irritation. Inhalation Harmful by inhalation. May cause the following effects. Dizziness. Ingestion May cause the following effects. Nausea. Vomiting. Diarrhea. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Methylene chloride 75-09-2 30-60 Propane/Isobutane/N-Butane 68476-86-8 15-40 4. FIRST AID MEASURES Eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Page 1 / 6 Emergency Overview Flammable. Irritant. May be harmful if swallowed. Harmful by inhalation. Form Aerosol Color White Odor Slight chlorine Solvent Page 150 of 871 Page 150 of 871 Page 150 of 871 Page 150 of 871 ---PAGE BREAK--- Product code 29569 Product name Cold Pipe Insulation Spray Skin contact Wash area thoroughly with soap and water. If skin irritation persists, call a physician. Ingestion Consult a physician. Inhalation Remove to fresh air. If persist, call a physician. 5. FIRE FIGHTING MEASURES Flash point °C < 37 Flash point °F < 99 Method No information available Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper No data available Lower No data available Flame extension >18" Flashback Unknown Suitable extinguishing media Carbon dioxide (CO2). Water. Dry chemical. Foam. Water fog. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Special Fire-Fighting Procedures Firefighters should wear NIOSH/MSHA approved (or equivalent) self-contained pressure-demand breathing apparatus and full protective clothing. Fire and Explosion Hazards Contents under pressure. Aerosol containers may vent, rupture or burst when heated to temperatures above 120°F. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Collect and contain for disposal. Dispose of wiping rags in metal containers with tight lids. Place in suitable container for disposal as hazardous waste. 7. HANDLING AND STORAGE Handling Keep away from open flame. Keep from excessive heat. Storage Keep closed in a dry and cool place. Page 2 / 6 Sensitivity to shock No information available. Sensitivity to static discharge No information available. Page 151 of 871 Page 151 of 871 Page 151 of 871 Page 151 of 871 ---PAGE BREAK--- Product code 29569 Product name Cold Pipe Insulation Spray NFPA Storage Code Store as Level 1 Aerosol (NFPA 30B) 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Methylene chloride - - 50 ppm - Propane/Isobutane/N- Butane - - - - Ventilation and Environmental Controls Local: adequate. Hygiene measures Wash hands before breaks and immediately after handling the product. Personal protective equipment Respiratory protection None required if adequate ventilation is provided. In case of insufficient ventilation wear suitable respiratory equipment. Hand Protection Gloves are recommended to prevent prolonged or repeated contact. Neoprene gloves. Eye protection ANSI approved safety goggles are recommended if exposure is likely. Skin and body protection None necessary under normal conditions 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY Stability Stable. Page 3 / 6 Water solubility 0% Form Partition Coefficient (n-octanol/water) No data available Odor Threshold No information available Boiling point/range °C No data available Aerosol Boiling point/range °F No data available pH Melting point/range °C No data available No data available Melting point/range °F No data available Flash point °C < 37 Specific Gravity Flash point °F < 99 1.20 Color Vapor pressure 355mmHg @25C White Vapor density 1 (air=1) Evaporation Rate <1 (n-Butyl-Acetate = 1) Odor VOC Content 32% Slight chlorine Solvent Page 152 of 871 Page 152 of 871 Page 152 of 871 Page 152 of 871 ---PAGE BREAK--- Product code 29569 Product name Cold Pipe Insulation Spray Conditions to avoid None known. Incompatability Strong acids. Alkalis. Oxidizers. Hazardous Decomposition Products None known. Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat) LD50 (dermal,rat/rabbit) LC50 (inhalation,rat) Methylene chloride 75-09-2 1410 mg/kg 2000 mg/kg - Propane/Isobutane/N-Butane 68476-86-8 - - - Synergistic Products None known Potential health effects Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinogens IARC NTP - Known Carcinogens NTP - Suspected Human Carcinogens OSHA RTK Carcinogens Methylene chloride Listed Group 2B Not Listed Listed Listed Propane/Isobutane/N-Butane Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Page 4 / 6 Sensitization None known Teratogenic effects None known Reproductive toxicity None known Methylene chloride Target Organ Effects None Known Chronic toxicity Repeated and prolonged exposure to solvents may cause brain and nervous system damage. See Section 2 . Mutagenic effects None known Page 153 of 871 Page 153 of 871 Page 153 of 871 Page 153 of 871 ---PAGE BREAK--- Product code 29569 Product name Cold Pipe Insulation Spray 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORT INFORMATION DOT UN1950 Aerosols, poison (Dichloromethane/Propane/n-Butane), Class 2.1(6.1) TDG UN1950 AEROSOLS, POISON (Dichloromethane/Propane/n-Butane), Class 2.1(6.1) IMDG/IMO UN1950 AEROSOLS (Dichloromethane/Propane/n-Butane), Class 2.1(6.1) IATA UN1950 Aerosols, flammable, containing substances in Division 6.1, Packing Group III(Dichloromethane/Propane/n-Butane), Class 2.1(6.1) MEX UN1950 AEROSOLES (Diclorometano/Propano/n-Butano),2.1(6.1) 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Methylene chloride Listed Chemical Name New Jersey - RTK - RTK California Prop. 65 Methylene chloride Listed Listed Carcinogen Propane/Isobutane/N-Butane Not Listed Not Listed Not Listed Chemical Name EINECS DSL NDSL TSCA Methylene chloride X X - X Propane/Isobutane/N-Butane X X - X CPRC This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations Page 5 / 6 Water Flea Data water flea EC50=140 mg/L (48 h) Microtox Data Photobacterium phosphoreum EC50=1000 mg/L (15 min) Page 154 of 871 Page 154 of 871 Page 154 of 871 Page 154 of 871 ---PAGE BREAK--- Product code 29569 Product name Cold Pipe Insulation Spray 16. OTHER INFORMATION Prepared By Michael Katz, Regulatory Affairs Specialist The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 6 / 6 HMIS NFPA - Flammability - Health 2 Health Flammability 3 Reactivity - Physical Hazard 1 Page 155 of 871 Page 155 of 871 Page 155 of 871 Page 155 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 26-Feb-2014 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 29569 Product name Cold Pipe Insulation Spray Recommended Use Coating Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions Pre-existing heart conditions. Pre-existing lung disorders. Principal Routes of Exposure Eyes. Skin. Inhalation. Ingestion. Potential health effects Eyes Irritation. Skin May cause eye/skin irritation. Inhalation Harmful by inhalation. May cause the following effects. Dizziness. Ingestion May cause the following effects. Nausea. Vomiting. Diarrhea. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Methylene chloride 75-09-2 30-60 Propane/Isobutane/N- Butane 68476-86-8 15-40 4. FIRST AID MEASURES Eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Skin contact Wash area thoroughly with soap and water. If skin irritation persists, call a physician. Ingestion Consult a physician. Inhalation Remove to fresh air. If persist, call a physician. 5. FIRE FIGHTING MEASURES Flash point °C < 37 Flash point °F < 99 Method No information available Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper No data available Lower No data available Flame extension >18" Flashback Unknown Suitable extinguishing media Carbon dioxide (CO2). Water. Dry chemical powder. Foam. Water fog. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Special Fire-Fighting Procedures Firefighters should wear NIOSH/MSHA approved (or equivalent) self- contained pressure-demand breathing apparatus and full protective clothing. Fire and Explosion Hazards Contents under pressure. Aerosol containers may vent, rupture or burst when heated to temperatures above 120°F. Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Collect and contain for disposal. Dispose of wiping rags in metal containers with tight lids. Place in suitable container for disposal as hazardous waste. Page 1 / 3 Emergency Overview Flammable. Irritant. May be harmful if swallowed. Harmful by inhalation. Page 156 of 871 Page 156 of 871 Page 156 of 871 Page 156 of 871 ---PAGE BREAK--- 7. HANDLING AND STORAGE Handling Keep away from open flame. Keep from excessive heat. Storage Keep closed in a dry and cool place. NFPA Storage Code Store as Level 1 Aerosol (NFPA 30B) 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Methylene chloride 25 ppm - 50 ppm - Propane/Isob utane/N- Butane - - - - Ventilation and Environmental Controls Local: adequate. Hygiene measures Wash hands before breaks and immediately after handling the product. Respiratory protection None required if adequate ventilation is provided. In case of insufficient ventilation wear suitable respiratory equipment. Hand Protection Gloves are recommended to prevent prolonged or repeated contact. Neoprene gloves. Eye protection ANSI approved safety goggles are recommended if exposure is likely. Skin and body protection None necessary under normal conditions 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color White Odor Slight chlorine Solvent Odor Threshold No information available pH No data available Specific Gravity 1.20 Vapor pressure 355 mmHg @ 25°C Vapor density 1 (air=1) Evaporation Rate <1 (n-Butyl-Acetate = 1) Water solubility 0% VOC Content 32% Partition Coefficient (n-octanol/water) No data available Boiling point/range °C No data available Boiling point/range °F No data available Melting point/range °C No data available Melting point/range °F No data available Flash point °C < 37 Flash point °F < 99 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid None known. Incompatability Strong acids. Alkalies. Oxidizers. Hazardous Decomposition Products None known. Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Methylene chloride 75-09-2 1410 mg/kg - - Propane/Isobutan e/N-Butane 68476-86-8 - - - Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity Repeated and prolonged exposure to solvents may cause brain and nervous system damage. See Section 2 . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects See Section 2 Carcinogenic effects See table below Page 2 / 3 Product code 29569 Product name Cold Pipe Insulation Spray Page 157 of 871 Page 157 of 871 Page 157 of 871 Page 157 of 871 ---PAGE BREAK--- Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Methylene chloride A3 Group 2B, Group 2A Not Listed Reasonabl y Anticipated To Be A Human Carcinoge n Listed Propane/Isob utane/N- Butane Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT UN1950 Aerosols, flammable, containing substances in Class 6.1, 2.1 (6.1) TDG UN1950 AEROSOLS, flammable, containing substances in Class 6.1, 2.1 (6.1) 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Methylene chloride Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Methylene chloride Listed Listed Carcinogen Propane/Isobutane/N- Butane Not Listed Not Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA Methylene chloride X X - X Propane/Isobutane/N- Butane X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION HMIS Health - 2 Flammability - 3 Physical Hazard - 1 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 3 / 3 Product code 29569 Water Flea Data Daphnia magna EC501532 - 1847 mg/L (48 h) Daphnia magna EC50=190 mg/L (48 h) Product name Cold Pipe Insulation Spray Methylene chloride Page 158 of 871 Page 158 of 871 Page 158 of 871 Page 158 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 03-Mar-2011 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 29569 Product name Cold Pipe Insulation Spray Recommended Use Coating Supplier Lawson Products, Inc. 1666 East Touhy Avenue Des Plaines, IL 60018 (847)-827-9666 Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions Pre-existing heart conditions. Pre-existing lung disorders. Principal Routes of Exposure Eyes. Skin. Inhalation. Ingestion. Potential health effects Eyes Irritation. Skin May cause eye/skin irritation. Inhalation Harmful by inhalation. May cause the following effects. Dizziness. Ingestion May cause the following effects. Nausea. Vomiting. Diarrhea. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Methylene chloride 75-09-2 30-60 Propane/Isobutane/N- Butane 68476-86-8 15-40 4. FIRST AID MEASURES Eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Skin contact Wash area thoroughly with soap and water. If skin irritation persists, call a physician. Ingestion Consult a physician. Inhalation Remove to fresh air. If persist, call a physician. 5. FIRE FIGHTING MEASURES Flash point °C < 37 Flash point °F < 99 Method No information available Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper No data available Lower No data available Flame extension >18" Flashback Unknown Suitable extinguishing media Carbon dioxide (CO2). Water. Dry chemical. Foam. Water fog. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Special Fire-Fighting Procedures Firefighters should wear NIOSH/MSHA approved (or equivalent) self- contained pressure-demand breathing apparatus and full protective clothing. Fire and Explosion Hazards Contents under pressure. Aerosol containers may vent, rupture or burst when heated to temperatures above 120°F. Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Collect and contain for disposal. Dispose of wiping rags in metal containers with tight lids. Place in suitable container for disposal as hazardous waste. Page 1 / 3 Emergency Overview Flammable. Irritant. May be harmful if swallowed. Harmful by inhalation. Page 159 of 871 Page 159 of 871 Page 159 of 871 Page 159 of 871 ---PAGE BREAK--- 7. HANDLING AND STORAGE Handling Keep away from open flame. Keep from excessive heat. Storage Keep closed in a dry and cool place. NFPA Storage Code Store as Level 1 Aerosol (NFPA 30B) 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Methylene chloride 25 ppm - 50 ppm - Propane/Isob utane/N- Butane - - - - Ventilation and Environmental Controls Local: adequate. Hygiene measures Wash hands before breaks and immediately after handling the product. Respiratory protection None required if adequate ventilation is provided. In case of insufficient ventilation wear suitable respiratory equipment. Hand Protection Gloves are recommended to prevent prolonged or repeated contact. Neoprene gloves. Eye protection ANSI approved safety goggles are recommended if exposure is likely. Skin and body protection None necessary under normal conditions 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color White Odor Slight chlorine Solvent Odor Threshold No information available pH No data available Specific Gravity 1.20 Vapor pressure 355 mmHg @ 25°C Vapor density 1 (air=1) Evaporation Rate <1 (n-Butyl-Acetate = 1) Water solubility 0% VOC Content 32% Partition Coefficient (n-octanol/water) No data available Boiling point/range °C No data available Boiling point/range °F No data available Melting point/range °C No data available Melting point/range °F No data available Flash point °C < 37 Flash point °F < 99 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid None known. Incompatability Strong acids. Alkalis. Oxidizers. Hazardous Decomposition Products None known. Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat) LD50 (dermal,rat/rabbi t) LC50 (inhalation,rat) Methylene chloride 75-09-2 2000 mg/kg - 76000 mg/m3 Propane/Isobutan e/N-Butane 68476-86-8 - - - Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity Repeated and prolonged exposure to solvents may cause brain and nervous system damage. See Section 2 . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects See Section 2 Carcinogenic effects See table below Page 2 / 3 Product name Cold Pipe Insulation Spray Product code 29569 Page 160 of 871 Page 160 of 871 Page 160 of 871 Page 160 of 871 ---PAGE BREAK--- Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Methylene chloride Listed Group 2B Not Listed Listed Listed Propane/Isob utane/N- Butane Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT UN1950 Aerosols, flammable, containing substances in Class 6.1, 2.1 (6.1) TDG UN1950 AEROSOLS, flammable, containing substances in Class 6.1, 2.1 (6.1) 15. REGULATORY INFORMATION US EPA SARA 313 Chemical Name US EPA SARA 313 Emission Reporting Methylene chloride Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Methylene chloride Listed Listed Carcinogen Propane/Isobutane/N- Butane Not Listed Not Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA Methylene chloride X X - X Propane/Isobutane/N- Butane X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION HMIS Health - 2 Flammability - 3 Physical Hazard - 1 Prepared By H. Buck, Regulatory Affairs Manager The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 3 / 3 Product name Cold Pipe Insulation Spray Water Flea Data water flea hEC50 48 (140 mg/L) Methylene chloride Product code 29569 Microtox Data Nitrosomonas EC50=1 mg/L (24 h) Photobacterium phosphoreum EC50=2.88 mg/L (15 min) Page 161 of 871 Page 161 of 871 Page 161 of 871 Page 161 of 871 ---PAGE BREAK--- ---PAGE BREAK--- ---PAGE BREAK--- ---PAGE BREAK--- ---PAGE BREAK--- Page 166 of 871 Page 166 of 871 Page 166 of 871 Page 166 of 871 ---PAGE BREAK--- Page 167 of 871 Page 167 of 871 Page 167 of 871 Page 167 of 871 ---PAGE BREAK--- Page 168 of 871 Page 168 of 871 Page 168 of 871 Page 168 of 871 ---PAGE BREAK--- Page 169 of 871 Page 169 of 871 Page 169 of 871 Page 169 of 871 ---PAGE BREAK--- Product code 59933 Product name Copper Anti-Seize Material Safety Data Sheet 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 59933 Product name Copper Anti-Seize Recommended Use Lubricant Supplier Lawson Products, Inc. 1666 East Touhy Avenue Des Plaines, IL 60018 (847)-827-9666 Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions No information available Principal Routes of Exposure Skin. Ingestion. Potential health effects Eyes Irritation. Skin Skin Irritation. Inhalation No adverse affects expected. Ingestion Ingestion may cause gastrointestinal irritation. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Copper 7440-50-8 30-40 Grease Trade Secret 30-60 Silicon Dioxide - hydrated 7631-86-9 3-7 Rust Inhibitor 15337-18-5 1-3 4. FIRST AID MEASURES Eye contact Flush with plenty of water for at least 15 minutes. Seek medical attention if irritation persists. Skin contact Wash area thoroughly with soap and water. Keep open wounds covered. Ingestion If a large quantity of liquid is swallowed, do NOT induce vomiting. Call a physician or Poison Control Center immediately. Inhalation Move to fresh air. Get medical attention if allergic response occurs. 5. FIRE FIGHTING MEASURES Flash point °C > 218 Flash point °F > 425 Method Open cup Autoignition temperature Autoignition temperature °C >426 Autoignition temperature °F >800 Flammability Limits in Air) Upper No data available Lower No data available Suitable extinguishing media Foam. Carbon dioxide (CO2). Dry chemical. Extinguishing media which must NOT be used for safety reasons No information available. Special protective equipment for firefighters No information available. Special Fire-Fighting Procedures Firefighters should wear NIOSH/MSHA approved (or equivalent) self- contained pressure-demand breathing apparatus and full protective clothing.. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. . Water spray may be ineffective. If water is used, fog nozzles are preferable. . Keep containers cool. Use shielding to protect against bursting or venting containers.. Hazardous decomposition products See Section 10 Fire and Explosion Hazards Contact with open flame generates corrosive and toxic fumes. Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Page 1 / 3 Emergency Overview Moderately irritating to the eyes. Moderately irritating to the skin. Revision Date 02-May-2005 Page 170 of 871 Page 170 of 871 Page 170 of 871 Page 170 of 871 ---PAGE BREAK--- Product code 59933 Product name Copper Anti-Seize Methods for cleaning up Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. Clean up by scoop or vacuum. Soak up excess with absorbent material. Pick up and transfer to properly labelled containers. 7. HANDLING AND STORAGE Handling Keep from excessive heat. Keep away from open flame. Storage Keep out of the reach of children. Do not store in unlabeled or mislabeled containers. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Grease - - - - Copper 0.1 mg/m³ fume 1 mg/m³ dusts and mists - 0.2 mg/m³ fume 1 mg/m³ dusts and mists, as Cu - Silicon Dioxide - hydrated 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction) 10 ppm 10 mg/m3 (total dust) ND Rust Inhibitor - - - - Ventilation and Environmental Controls Provide local exhaust ventilation. Hygiene measures General industrial hygiene practice. When using, do not eat, drink or smoke. Respiratory protection None necessary under normal conditions. Use NIOSH approved respirator if TLV limit is exceeded. Hand protection The following glove(s) are recommended to prevent prolonged or repeated contact:. Latex gloves. Eye protection ANSI approved safety goggles are recommended if exposure is likely. Skin and body protection No information available 9. PHYSICAL AND CHEMICAL PROPERTIES Form Liquid Color Copper Odor None Odor Threshold No information available pH No data available Specific Gravity 1.05 Boiling point/range °C No data available Boiling point/range °F No data available Melting point/range °C -40 Melting point/range °F -40 Flash point °C > 218 Flash point °F > 425 Vapor pressure No data available Vapor density No data available Evaporation Rate No data available Water solubility No data available Partition Coefficient (n-octanol/water) No data available 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid No information available Materials to avoid Strong oxidizing agents. Bromates. Chlorates. Iodates. Hazardous decomposition products Toxic fumes. Polymerization Will not occur. Synergistic Products No information available. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat) LD50 (dermal,rat/rabbi t) LC50 (inhalation,rat) Grease Trade Secret - - - Copper 7440-50-8 - - - Silicon Dioxide - hydrated 7631-86-9 - - - Rust Inhibitor 15337-18-5 - - - Potential health effects Sensitization No information available. Chronic toxicity No information available. Mutagenic effects No information available. Teratogenic effects No information available Reproductive toxicity No information available Page 2 / 3 Page 171 of 871 Page 171 of 871 Page 171 of 871 Page 171 of 871 ---PAGE BREAK--- Product code 59933 Product name Copper Anti-Seize Target Organ Effects Eyes. Inhalation. Skin. Carcinogenic effects Did not show carcinogenic or teratogenic effects in animal experiments. Chemical Name ACGIH OEL - Carcinog ens IARC NTP - Known Carcinog ens NTP - Suspecte d Human Carcinog ens OSHA RTK Carcinog ens Grease Not Listed Not Listed Not Listed Not Listed Not Listed Copper Not Listed Not Listed Not Listed Not Listed Not Listed Silicon Dioxide - hydrated Not Listed Not Listed Not Listed Not Listed Not Listed Rust Inhibitor Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Aquatic toxicity 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Can be landfilled or incinerated, when in compliance with local regulations. 14. TRANSPORTATION INFORMATION DOT Not Regulated TDG Not Regulated IMDG/IMO Not Regulated IATA Not Regulated MEX Not Regulated 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Copper Listed Listed Rust Inhibitor Listed Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Grease Not Listed Not Listed Not Listed Copper Not Listed Listed Not Listed Silicon Dioxide - hydrated Listed Listed Not Listed Rust Inhibitor Not Listed Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA Grease - - - - Copper X X - X Silicon Dioxide - hydrated X X - X Rust Inhibitor X X X - X CPRC This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION NFPA Health 1 Flammability 2 Reactivity 0 HMIS Health - 1 Flammability - 1 Physical Hazard - 0 Reason for revision No information available. Prepared By T. Heidorn, MSDS Project Lead The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 3 / 3 Water Flea Data water flea LC50=10 µg/L (96 h) water flea LC50=200 µg/L (96 h) Copper Rust Inhibitor Water Flea Data water flea LC50=5 µg/L (72 h) Page 172 of 871 Page 172 of 871 Page 172 of 871 Page 172 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 11-Mar-2013 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 98663 Product name Copper Anti-Seize Tape Recommended Use Adhesive Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Eyes. Inhalation. Potential health effects Eyes Contact with eyes may cause irritation. Skin Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. Rash. Inhalation When thermally decomposed, Teflon may cause polymer fume fever. of polymer fume fever are chills, fever, and flu-like reaction . Chronic overexposure to copper dust may cause tiredness, stuffiness, diarrhea, vomiting, discoloration of the skin and eyes, kidney and liver disorder. Ingestion No adverse affects expected. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Polytetrafluoroethylene 9002-84-0 60-100 Copper 7440-50-8 3-7 Petroleum distillates, hydrotreated light 64742-47-8 1-5 4. FIRST AID MEASURES Eye contact In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Skin contact Wash area thoroughly with soap and water. Remove and wash contaminated clothing before re-use. Seek medical attention if irritation persists. Ingestion Rinse mouth. Drink plenty of water. Seek medical attention. Inhalation Remove from exposure. Keep warm and quiet. Immediately give oxygen if victim turns blue (lips, ears, fingernails). Administer artificial respiration if not breathing. Seek medical attention immediately. 5. FIRE FIGHTING MEASURES Flash point °C Not Applicable Flash point °F Not Applicable Method Not Applicable Autoignition temperature °C Not Applicable Autoignition temperature °F Not Applicable Flammability Limits in Air) Upper No data available Lower No data available Suitable extinguishing media Use extinguishing media appropriate to surrounding fire Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Fire and Explosion Hazards Combustible solid . Combustion ceases when flame is removed . Contact with open flame or hot surfaces may generate toxic fumes. Decomposition on heating above (500F) (260C) results in the emission of toxic fumes . Hazardous decomposition products See Section 10. Sensitivity to shock No information available. Sensitivity to static discharge No information available. Page 1 / 3 Emergency Overview No information available Page 173 of 871 Page 173 of 871 Page 173 of 871 Page 173 of 871 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Sweep up product . 7. HANDLING AND STORAGE Handling Use normal safe handling procedures. Storage Keep away from open flames, hot surfaces and sources of ignition. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Polytetrafluor oethylene - - - - Copper 0.1 mg/m3 - 0.2 mg/m3 1 mg/m3 - Petroleum distillates, hydrotreated light - - - - Ventilation and Environmental Controls Adequate ventilation should be provided to keep exposure levels below current acceptable exposure limits. Hygiene measures General industrial hygiene practice. Respiratory protection Follow OSHA respirator regulations (29 CFR 1910.134) and if necessary, wear a MSHA/NIOSH approved respirator Hand Protection Gloves are not required in normal use Eye protection None necessary under normal use conditions. Skin and body protection None necessary under normal conditions 9. PHYSICAL AND CHEMICAL PROPERTIES Form Solid Color Metallic Odor None Odor Threshold Not Applicable pH Not Applicable Specific Gravity 2.7 Vapor pressure Not Applicable Vapor density Not Applicable Evaporation Rate Not Applicable Water solubility Insoluble Partition Coefficient (n-octanol/water) Not Applicable Boiling point/range °C Not Applicable Boiling point/range °F Not Applicable Melting point/range °C Not Applicable Melting point/range °F Not Applicable Flash point °C Not Applicable Flash point °F Not Applicable 10. STABILITY AND REACTIVITY Stability Stable Conditions to avoid Metal hydrides . Aluminum chloride . Boranes . Avoid temperatures above 500 degrees F. Do not use on oxygen lines. Incompatability Alkali metals. Oxidizers. Fluorine. Chlorine trifluoride . Metal hydrides. Ammonia. Selected amines. Imines. Nitric acid. Hydroxides. Sodium hydroxide. Hazardous Decomposition Products The thermal decomposition vapors of fluorinated polymers may cause polymer fume fever with flu-like in humans, especially when smoking contaminated tobacco. Carbonyl Fluoride. Polymerization Hazardous polymerization does not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Polytetrafluoroeth ylene 9002-84-0 - - - Copper 7440-50-8 - - - Petroleum distillates, hydrotreated light 64742-47-8 5000 mg/kg 2000 mg/kg 5.2 mg/L Synergistic Products None known Specific Hazards of polymer fume fever are chills, fever, and flu-like reaction. Potential health effects Sensitization None known Chronic toxicity See Section 2 . Mutagenic effects None known Page 2 / 3 Product code 98663 Product name Copper Anti- Seize Tape Page 174 of 871 Page 174 of 871 Page 174 of 871 Page 174 of 871 ---PAGE BREAK--- Teratogenic effects None known Reproductive toxicity None known Target Organ Effects See Section 2 Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Polytetrafluor oethylene Not Listed Not Listed Not Listed Not Listed Not Listed Copper Not Listed Not Listed Not Listed Not Listed Not Listed Petroleum distillates, hydrotreated light Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT Not Regulated TDG Not Regulated 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Copper Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Polytetrafluoroethylene Not Listed Listed Not Listed Copper Not Listed Listed Not Listed Petroleum distillates, hydrotreated light Not Listed Not Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA Polytetrafluoroethylene - X - X Copper X X - X Petroleum distillates, hydrotreated light X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 3 / 3 Water Flea Data Den-dronereides heteropoda LC50=4720 mg/L (96 h) Product name Copper Anti- Seize Tape Water Flea Data Daphnia magna EC50=0.03 mg/L (48 h) Product code 98663 Petroleum distillates, hydrotreated light Copper Page 175 of 871 Page 175 of 871 Page 175 of 871 Page 175 of 871 ---PAGE BREAK--- Material Safety Data Sheet N/A: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required Est.: Estimated Covers Up Spray MSDS (09-08-08) Page 1 of 6 pages. Section 1 General Information Manufacturer: HMIS Rating Zinsser Company, Inc. HEALTH: 1 173 Belmont Drive FLAMMABILITY: 3 Somerset, NJ 08875 REACTIVITY: 0 (732) 469-8100 Emergency Telephone: Chemtrec (800) 424-9300 Date: September 8, 2008 Product Name: Covers Up Product Codes: 03688 Section 2 Hazardous Ingredients OSHA ACGIH Hazardous Component CAS# PEL TLV Acetone 67-64-1 1000 ppm 500 ppm Limestone 1317-65-3 15 mg/m3 * (5 mg/m3 10 mg/m3 † (3 mg/m3 Propane 74-98-6 1000 ppm 2500 ppm Titanium dioxide 13463-67-7 15 Mg/m3 * 10 Mg/m3 n-Butane 106-97-8 N/E 1000 ppm * Total Dust Respirable Dust Fraction † Inhalable fraction Section 3 Hazard Identification Emergency Overview: This material is an aerosol spray coating. The container is pressurized and extremely flammable. As packaged, this material has a flashpoint of less than 32° F. Primary Routes of Exposure: Inhalation Skin Contact Eye Contact Potential Acute Health Effects: Eye: May cause eye irritation. Skin: Prolonged contact may cause skin irritation. Page 176 of 871 Page 176 of 871 Page 176 of 871 Page 176 of 871 ---PAGE BREAK--- N/A: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required Est.: Estimated Covers Up Spray MSDS (09-08-08) Page 2 of 6 pages. Ingestion: Although ingestion is not anticipated route of exposure, this material can be harmful if swallowed. It may cause depression of the central nervous system, nausea, and vomiting. Inhalation: May cause headache, drowsiness, dizziness, nausea, and respiratory tract irritation. Potential Chronic Health Effects: None known. (See also Sections 4, 8, and 11 for related information) Section 4 First Aid Measures Eye contact: Flush eyes with water for 15 minutes. Skin contact: Wash affected area thoroughly with soap and water. Ingestion: Call a physician or poison control center. Inhalation: Remove person to fresh air. Contact physician or poison control center if persist. Section 5 Fire Fighting Measures Flash Point (method): < 32° F 0° C) Extinguishing Media: Foam, CO2, dry chemical, water fog. Protection of Firefighters: As in any fire, wear NIOSH approved self-contained breathing apparatus in pressure-demand mode and full protective gear. Fire and Explosion Hazards: Contents under pressure. Containers can build up pressure if exposed to heat (fire). Section 6 Accidental Release Measures Personal Precautions: Use with adequate ventilation. Avoid breathing vapors. Avoid contact with eyes and skin. Do not eat, drink or smoke in areas of use or storage. Clean Up Methods: Dispose of in accordance with federal, state, local, regulations. (See also Section 8 for information on Exposure Controls and Personal Protective Equipment) Page 177 of 871 Page 177 of 871 Page 177 of 871 Page 177 of 871 ---PAGE BREAK--- N/A: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required Est.: Estimated Covers Up Spray MSDS (09-08-08) Page 3 of 6 pages. Section 7 Handling and Storage Handling: Do not use near heat, sparks, or open flame. Keep operating temperatures below ignition temperatures at all times. Use only in a well-ventilated area. Storage: Store at room temperature. Protect against physical damage. Contents under pressure. Do not expose to heat. Keep away from heat, spark, and flame. Do not puncture, incinerate, or store above 120° F. Do not discard empty container in garbage compactor. Exposure to heat or prolonged exposure to sunlight may cause bursting. Section 8 Exposure Controls / Personal Protection Engineering Controls: General dilution ventilation or local exhaust ventilation may be necessary to control vapors below applicable exposure limits. Personal Protective Equipment (PPE): Eye Protection: Wear safety glasses, splash goggles, or full face shield to prevent eye contact. Skin Protection: Wear rubber gloves to prevent skin contact. Respiratory Protection: Use NIOSH approved respirator with organic vapor cartridges if vapor levels exceed applicable workplace exposure limits. General Hygiene Practices: Wash thoroughly after handling. Prevent Eye contact. Avoid prolonged skin or inhalation contact. Section 9 Physical Data Appearance: Off-white colored aerosol Odor: Mild odor. Physical State: Spray mist pH: N/A Boiling Point: N/D Melting Point: N/D Vapor Pressure: N/D Vapor Density: Greater than air Odor Threshold: N/D Viscosity: N/D Solubility in Water: N/D Specific Gravity (water = 0.9 Page 178 of 871 Page 178 of 871 Page 178 of 871 Page 178 of 871 ---PAGE BREAK--- N/A: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required Est.: Estimated Covers Up Spray MSDS (09-08-08) Page 4 of 6 pages. Section 10 Stability and Reactivity Stability: Stable, non-reactive. Hazardous Polymerization: Will not occur. Hazardous Decomposition Products: None known. Conditions to Avoid: Heat, sparks, and open flames. Incompatibilities: Strong oxidizing agents. Section 11 Toxicological Information Carcinocenicity: This material is not considered a carcinogen by IARC or NTP and is not regulated as a carcinogen by OSHA. (See also Section 15 for related information) Section 12 Ecological Information Chemical Fate and Effects: No data available. Section 13 Disposal Considerations RCRA Hazardous Waste: This material, when discarded or disposed of, could be a hazardous waste according to federal regulations (40 CFR 261) due to the characteristic of ignitability (D001). The transportation, storage, treatment, and disposal of this waste must be conducted in compliance with 40 CFR 262, 263, 264, 268, and 270. Disposal can only occur in properly permitted facilities. Check state and local regulations for any additional requirements as these may be more restrictive than federal laws and regulations. Chemical additions, processing or otherwise altering this material may make the waste management information presented in this MSDS incomplete, inaccurate, or otherwise inappropriate. Section 14 Transportation Information Regulated by the DOT: No (ORM-D, Consumer Commodity) Page 179 of 871 Page 179 of 871 Page 179 of 871 Page 179 of 871 ---PAGE BREAK--- N/A: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required Est.: Estimated Covers Up Spray MSDS (09-08-08) Page 5 of 6 pages. Section 15 Regulatory Information CERCLA: The Comprehensive Environmental Response Compensation and Liability Act of 1980 (CERCLA) requires notification to the National Response Center for releases of quantities of Hazardous Substances equal to or greater than the reportable quantities (RQs) in 40 CFR 302.4 (for CERCLA 102). Components present in this product at a level which could require reporting under the statute are: Chemical Name CAS# Maximum Concentration (Wt. None N/A N/A SARA Title III, section 311/312: The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires emergency planning based on Threshold Planning Quantities (TPQs) and release reporting based on Reportable Quantities (RQs) in 40 CFR 355 (used for SARA 302, 304, 311 and 312). Components present in this product at a level which could require reporting under the statute are: Chemical Name CAS# Maximum Concentration (Wt. None N/A N/A SARA Title III, section 313: The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires submission of annual reports of release of toxic chemicals that appear in 40 CFR 372 (for SARA 313). Components present in this product at a level which could require reporting under the statute are: Chemical Name CAS# Maximum Concentration (Wt. None N/A N/A TSCA: The components of this mixture are listed in the Toxic Substance Control Act Inventory of Chemical Substances. This product contains the following chemicals which require export notification under section 12(b) of the TSCA regulation: Chemical Name CAS# TSCA Section None N/A N/A Page 180 of 871 Page 180 of 871 Page 180 of 871 Page 180 of 871 ---PAGE BREAK--- N/A: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required Est.: Estimated Covers Up Spray MSDS (09-08-08) Page 6 of 6 pages. Section 16 Other Information Legend: N/A: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required STEL: Short Term Exposure Limit C: OSHA Ceiling Value cps: Centipoise mg/m3: milligrams per cubic meter million particles per cubic foot of air. PPM: Parts Per Million PPB: Parts Per Billion PEL: Permissible Exposure Limit TLV: Threshold Limit Value TWA: Time Weighted Average ACGIH: American Conference of Governmental Industrial Hygienists CPSC: Consumer Product Safety Commission DOT: US Department of Transportation FHSA: Federal Hazardous Substance Act OSHA: Occupational Safety and Health Administration (US Dept. of Labor) RCRA: Resource Conservation and Recovery Act SARA: Superfund Amendment and Reauthorization Act Skin: This substance has the potential to be absorbed systemically through the skin. TSCA: Toxic Substance Control Act HMIS Key 4 = Severe Hazard 3 = Serious Hazard 2 = Moderate Hazard 1 = Slight Hazard 0 = Minimal Hazard Prepared By: Zinsser Regulatory Compliance Dept. 173 Belmont Drive Somerset, NJ 08875 (732) 469-8100 Disclaimer: Zinsser Company, Inc. believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this material safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials and make no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and data and to comply with all applicable international, federal, state, and local laws and regulations. Page 181 of 871 Page 181 of 871 Page 181 of 871 Page 181 of 871 ---PAGE BREAK--- XIAMETER(R) Hoja de Datos de Seguridad del Material Página: 1 de 8 Versión: 1.1 Fecha de revisión: 2004/03/25 DAP(R) HOUSEHOLD SILICONE ADHESIVE CLEAR, 698 1. IDENTIFICACIÓN DE LA SUSTANCIA Y DE LA COMPAÑÍA Dow Corning de Mexico, S.A. de C.V. Campos Eliseos #345-5 Piso Col. Polanco C.P. 11550 Mexico D.F. MEXICO Teléfono Argentina: Colombia: Puerto Rico: Venezuela: Mexico: Local: 54(11)4814-9600 (571)621-0677 (809)783-8500 58(212)261-2672 (52 55)327-1300 (52 55)227-7979 Dow Corning Corporation South Saginaw Road Midland, Michigan 48686 Teléfono de Emergencia 24 Horas: Información de Producto: (989) 496-5900 (989) 496-6000 MSDS No.: 03301184 Fecha de revisión: 2004/03/25 Descripción Genérica: Elastómero de silicón. Forma Física: Pasta. Color: Incoloro. Olor: Olor a ácido acético. Perfil NFPA: Salud 1 Flamabilidad 1 Inestabilidad / Reactividad 0 Nota: NFPA = National Fire Protection Association - Asociación Nacional de Protección contra Incendios 2. COMPONENTES PELIGROSOS POR OSHA-ASOCIACIÓN DE SALUD Y SEGURIDAD OCUPACIONAL Número CAS % Peso Nombre del Componente 4253-34-3 1.0 - 5.0 Metiltriacetoxisilano 17689-77-9 1.0 - 5.0 Etiltriacetoxisilano Los componentes arriba mencionados son peligrosos de acuerdo a la definición en 29 CFR 1910.1200. 3. EFECTOS PRO SOBREEXPOSICIÓN Efectos agudos Ojos: El contacto directo puede ocasionar una irritación moderada. Piel: Puede causar irritacion moderada. Inhalación: Irrita ligeramente las vias respiratorias Oral: No se esperan efectos significantes por una exposición corta al material. Efectos por Exposición Prolongada / Repetida Page 182 of 871 Page 182 of 871 Page 182 of 871 Page 182 of 871 ---PAGE BREAK--- XIAMETER(R) Hoja de Datos de Seguridad del Material Página: 2 de 8 Versión: 1.1 Fecha de revisión: 2004/03/25 DAP(R) HOUSEHOLD SILICONE ADHESIVE CLEAR, 698 Piel: No hay información aplicable que se conozca. Inhalación: No hay información aplicable que se conozca. Oral: No hay información aplicable que se conozca. Señales y Síntomas de Sobreexposición No hay información aplicable que se conozca. Condiciones Médicas Agravadas por Exposición No hay información aplicable que se conozca. Los efectos potenciales enumerados arriba por sobrexposición se basan en datos actuales, resultados de estudios llevados a cabo en composiciones similares, datos de los componentes o revisiones expertas del producto. Por favor refierase a la Seccion 11 para información toxicológica detallada. 4. PRIMEROS AUXILIOS Ojos: Enjuague inmediatamente con agua durante 15 minutos. Obtenga atención médica. Piel: Remover de la piel y lavar abundantemente con agua y jabón o agua limpia. Obtenga atención médica si persiste, o se desarrolla, irritación u otros malestares. Inhalación: No deberían necesitarse primeros auxilios. Oral: No deberían necesitarse primeros auxilios. Comentarios: Tratar de acuerdo a condiciones específicas de exposición de la persona. 5. MEDIDAS PARA COMBATIR INCENDIOS Punto de inflamación: No aplicable. Temperatura de autoignición: No determinada. Limites de Flamabilidad en Aire: No determinada. Medios de Extinción: Utilice químicos secos, espuma o rocíe agua para fuegos grandes. Utilice dioxido de carbono (CO2), polvo quimico o rocie agua para incendios pequeños. Se puede utilizar agua para enfriar los envases expuestos al fuego. Page 183 of 871 Page 183 of 871 Page 183 of 871 Page 183 of 871 ---PAGE BREAK--- XIAMETER(R) Hoja de Datos de Seguridad del Material Página: 3 de 8 Versión: 1.1 Fecha de revisión: 2004/03/25 DAP(R) HOUSEHOLD SILICONE ADHESIVE CLEAR, 698 Medidas para el Combate de Incendios: Equipos de respiración autónoma y ropa protectora deben ser utilizados cuando se atacan fuegos en que se encuentren productos quimicos presentes. Determinar la necesidad de evacuar o aislar el área de acuerdo con su plan local de emergencia. Ninguno(a). El material no se quema. Peligros inusuales de Incendio: Ninguno/a. Productos Peligrosos de la Descomposición Los siguientes productos peligrosos por la descomposición pueden evolucionar debido a la ruptura térmica de este producto durante un incendio, o condiciones de temperatura muy altas.: Óxidos de carbono y trazas de compuestos de carbono no completamente quemados. Formaldehído. Dióxido de silicio. 6. MEDIDAS QUE DEBAN TOMARSE EN CASO DE VERTIDO ACCIDENTAL Contención / Limpieza: Siga todas las recomendaciones descritas en las secciones 5 y 8 respecto al equipo de protección personal. Junte o Separe para recuperarlo o Destruirlo. Limpie el área como sea apropiado, ya que algunos materiales del silicón, aún en pequeñas cantidades, puede representar un riesgo de resbalar. La limpieza final puede requerir el uso de vapor, solventes o detergentes. Deseche apropiadamente el absorbente saturado, o los materiales de limpieza, ya que puede ocurrir un calentamiento espontáneo. Leyes y reglamentos locales, federales y estatales deben ser verificadas para la disposición del material. asi mismo como los materiales y equipos utilizados en la limpieza para la destrucción. Es necesario determinar cuales leyes y reglamentos deben ser aplicados n las materias arriba mencionadas. Secciones 13 y 15 de MDMS contienen informacion en referencia a los requerimientos federales y estatales. Nota: Vea la Sección 8 para Equipo de Protección Personal para Derrames. 7. MANIPULACION Y ALMACENAMIENTO Utilicese con ventilación adecuada. El producto libera ácido acético (HOAc) cuando se expone al agua o aire húmedo. Proporcione ventilación durante su uso para controlar el HOAc dentro de los lineamientos de exposición (vea la Sección 2) o use protección respiratoria. Evítese el contacto con los ojos. Evítese el contacto con la piel. Use un cuidado razonable, y almacénelo lejos de materiales oxidantes. Manténgase el envase cerrado y almacenarlo lejos del agua o della umedad. 8. CONTROL DE EXPOSICIÓN / PROTECCIÓN INDIVIDUAL Límite de Exposición al Componente Número CAS Nombre del Componente Límites de exposición 4253-34-3 Metiltriacetoxisilano Ver comentarios sobre el acido acético. 17689-77-9 Etiltriacetoxisilano Ver comentarios sobre el acido acético. Page 184 of 871 Page 184 of 871 Page 184 of 871 Page 184 of 871 ---PAGE BREAK--- XIAMETER(R) Hoja de Datos de Seguridad del Material Página: 4 de 8 Versión: 1.1 Fecha de revisión: 2004/03/25 DAP(R) HOUSEHOLD SILICONE ADHESIVE CLEAR, 698 Se forma ácido acético al entrar en contacto con agua o aire humedo. Controles de Ingeniería Ventilación Local: No debe necesitarse alguno(a). Ventilación General: Recomendado(a). Equipo de Protección Personal para la Manipulación Rutinaria Ojos: Use protección apropiada - lentes de seguridad como mínimo. Piel: Lávese antes de los alimentos y al final del turno. Deben retirarse ropas y calzado contaminado tan pronto sea práctico, y limpiarlos exhaustivamente antes de volver a usarse. Se recomienda el uso de guantes protectores contra químicos. Guantes Apropiados: Silver Shield(R). 4H(R). Inhalación: No debe necesitarse protección respiratoria. Respirador Apropiado: No debe necesitarse alguno(a). Equipo de Protección Personal en Caso de Derrames Ojos: Use protección apropiada - lentes de seguridad como mínimo. Piel: Lávese antes de los alimentos y al final del turno. Deben retirarse ropas y calzado contaminado tan pronto sea práctico, y limpiarlos exhaustivamente antes de volver a usarse. Se recomienda el uso de guantes protectores contra químicos. Inhalación/Respirador Apropiado: No debe necesitarse protección respiratoria. Medidas Precautorias: Evítese el contacto con los ojos. Evítese el contacto con la piel. Use con cuidado razonable. Comentarios: El producto libera ácido acético (HOAc) cuando se expone al agua o aire húmedo. Proporcione ventilación durante su uso para controlar el HOAc dentro de los lineamientos de exposición (vea la Sección 2) o use protección respiratoria. El producto puede formar vapores de formaldehído al ser calentado a temperaturas por encima de 150 °C en presencia de aire. El formaldehído es un riesgo potencial de cáncer y un sensibilizador conocido de la piel y sistema respiratorio; es un irritante de los ojos, nariz, piel, garganta y sistema digestivo. Se pueden mantener condiciones de manejo seguras, al controlar las concentraciones de su vapor dentro de los Limites de Exposición Permisibles de OSHA para el formaldehído. Nota: Estas precauciones son para el manejo a temperatura ambiente. El uso de temperatura, o aplicaciones en aerosol/rocío, pueden requerir precauciones adicionales. 9. PROPIEDADES FÍSICAS Y QUÍMICAS Page 185 of 871 Page 185 of 871 Page 185 of 871 Page 185 of 871 ---PAGE BREAK--- XIAMETER(R) Hoja de Datos de Seguridad del Material Página: 5 de 8 Versión: 1.1 Fecha de revisión: 2004/03/25 DAP(R) HOUSEHOLD SILICONE ADHESIVE CLEAR, 698 Forma Física: Pasta. Color: Incoloro. Olor: Olor a ácido acético. Gravedad Específica @ 25°C: 1.024 Viscosidad: No determinada. Punto de Congelamiento / Fusión: No determinada. Punto de Ebullición: No determinada. Presión de Vapor @ 25°C: No determinada. Densidad de Vapor: No determinada. Solubilidad en Agua: No determinada. pH: No determinada. Contenido de Volátiles: No determinada. Nota: La información prevedente no debe ser usada para elaborar especificaciones del producto. 10. ESTABILIDAD Y REACTIVIDAD Estabilidad Química: Estable. Polimerización peligrosa: No ocurrirá polimerización peligrosa. Condiciones que deben evitarse: Ninguno/a. Materiales que deben evitarse: El material oxidante puede causar una reacción. El agua, humedad, o aire húmedo pueden causar la formación de vapores peligrosos, tal como se describe en la Sección 8. 11. INFORMACIÓN TOXICOLÓGICA Información Especial sobre Riesgo en los Componentes No hay información aplicable que se conozca. 12. INFORMACIÓN ECOLÓGICA Destino Ambiental y Distribución Aún no hay información completa disponible. Efectos Ambientales Aún no hay información completa disponible. Destino y Efectos en las Plantas de Tratamiento de Aguas Residuales Aún no hay información completa disponible. Page 186 of 871 Page 186 of 871 Page 186 of 871 Page 186 of 871 ---PAGE BREAK--- XIAMETER(R) Hoja de Datos de Seguridad del Material Página: 6 de 8 Versión: 1.1 Fecha de revisión: 2004/03/25 DAP(R) HOUSEHOLD SILICONE ADHESIVE CLEAR, 698 Criterio de Clasificación de Ecotoxicidad Parámetros de Peligro (CL50 oe CE50) Alto(a) Medio(a) Bajo(a) Toxicidad Acuática Aguda (mg/L) >1 and <=100 >100 Toxicidad Terrestre Aguda <=100 >100 and 2000 >2000 Esta tabla está adaptada de "Evaluación de Riesgo y Toxicología Ambiental", ASTM STP 1179, p.34, 1993. Esta tabla puede usarse para clasificar la ecotoxicidad de este producto o cuando se enumere arriba la ecotoxidad. Por favor lea la otra información presentada en la seccion que concierne a la seguridad ecologica total de este material. 13. CONSIDERACIONES PARA EL DESECHO Clase de Peligro RCRA - Acta de Recuperación y Conservación de Recursos (40 CFR 261) Cuando se toma una decisión de desechar este material, tal cómo se recibió, ¿se clasifica este como residuo peligroso? Las leyes estatales o locales pueden imponer requisitos normativos adicionales respecto al desecho. Consult Section 1 to obtain telephone numbers. 14. INFORMACIÓN RELATIVA AL TRANSPORTE Información sobre Embarque Terreste DOT - Departamento de Transporte (49 CFR 172.101) No esta sujeto(a) al DOT (Departamento de Transportación) Embarque Marítimo (IMDG - Bienes Peligrosos Marítimos Internacionales) No está sujeto al código de IMDG. Embarque Aéreo (ICAO - Organización Internacional de Aviación Civil) No está sujeto a las normas de IATA. 15. INFORMACIÓN REGLAMENTARIA El contenido de esta MSDS cumple con el Estándar de Comunicación de Peligros de OSHA 29 CFR 1910.1200. Estado TSCA - Acta del Control de Sustancias Tóxicas: Toda substancia quimica presente en este producto cumple con los requerimientos reportado en el "act inventory" de control de substancias toxicas, o bien está exento de estos. Listas Químicas Título III EPA SARA - Agencia de Protección Ambiental - Acta de Fondos de Reautorización y Enmiendas Sección 302 Sustancias Extremadamente Peligrosas: Ninguno/a. Sección 304 Sustancias Peligrosas CERCLA - Acta de Responsabilidad, Compensación y Respuesta Ambiental Amplia: Page 187 of 871 Page 187 of 871 Page 187 of 871 Page 187 of 871 ---PAGE BREAK--- XIAMETER(R) Hoja de Datos de Seguridad del Material Página: 7 de 8 Versión: 1.1 Fecha de revisión: 2004/03/25 DAP(R) HOUSEHOLD SILICONE ADHESIVE CLEAR, 698 Ninguno/a. Sección 312 Clase de Peligro: Agudo: Y Crónico: N Fuego: N Presión: N Reactivo: N Sección 313 Químicos Tóxicos: Ninguno(a) presente, o ninguno(a) presente en cantidades reguladas. Información Suplementaria de Cumplimiento Estatal California Advertencia: Este producto contiene el siguiente químico(s) enumerado por el Estado de California bajo el Acta de Aplicación de Agua Potable Segura de 1986 (Proposicion 65), el cual se conoce que causa cancer, defectos en el nacimiento u otros daños reproductivos. Ninguno(a) conocido(a). Massachusets Número CAS % Peso Nombre del Componente 7631-86-9 7.0 - 13.0 Silica, amorfa Nueva Jersey Número CAS % Peso Nombre del Componente 70131-67-8 > 60.0 Dimetil Siloxano, Hidroxi-terminal 7631-86-9 7.0 - 13.0 Silica, amorfa 4253-34-3 1.0 - 5.0 Metiltriacetoxisilano 17689-77-9 1.0 - 5.0 Etiltriacetoxisilano Número CAS % Peso Nombre del Componente 70131-67-8 > 60.0 Dimetil Siloxano, Hidroxi-terminal 7631-86-9 7.0 - 13.0 Silica, amorfa Page 188 of 871 Page 188 of 871 Page 188 of 871 Page 188 of 871 ---PAGE BREAK--- XIAMETER(R) Hoja de Datos de Seguridad del Material Página: 8 de 8 Versión: 1.1 Fecha de revisión: 2004/03/25 DAP(R) HOUSEHOLD SILICONE ADHESIVE CLEAR, 698 16. OTRAS INFORMACIONES Preparado por: Dow Corning Corporation Estos datos se ofrecen de buena voluntad como valores típicos, y no como especificaciones para productos. No se hace aquí una garantía, expresa ni implícita. Se cree que las recomendaciones de higiene industrial y procedimientos para manipulación segura son aplicables en general. Sin embargo, cada usuario debe de revisar estas recomendaciones para determinar si son o no apropiadas dentro del contexto específico del uso pretendido. XIAMETER(R) is a trademark of Dow Corning Corporation http://www.xiameter.com Page 189 of 871 Page 189 of 871 Page 189 of 871 Page 189 of 871 ---PAGE BREAK--- SAFETY DATA SHEET. Issuing date 09-Mar-2015 Revision Date 09-Mar-2015 Version 2.02 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product name DECAL & LABEL REMOVER Recommended use of the chemical and restrictions on use Product code 91757 Product Type Extremely flammable aerosol Synonyms Supplier's details Recommended Use decal and label remover. Uses advised against Emergency telephone number Chemical Emergency Phone Number [PHONE REDACTED] Company Emergency Phone Number 1-[PHONE REDACTED] Page 1 / 11 Manufactured For: Lawson Products, Inc 8770 W. Bryn Mawr Avenue - Suite 900 Chicago, IL 60631-3515 [PHONE REDACTED] Page 190 of 871 Page 190 of 871 Page 190 of 871 Page 190 of 871 ---PAGE BREAK--- 91757 DECAL & LABEL REMOVER Revision Date 09-Mar-2015 2. HAZARDS IDENTIFICATION Classification Acute Toxicity - Dermal Category 4 Acute toxicity - Inhalation (Vapors) Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Carcinogenicity Category 2 Reproductive Toxicity Category 2 Specific target organ toxicity (single exposure) Category 3 Specific target organ toxicity (repeated exposure) Category 2 Aspiration toxicity Category 1 GHS Label elements, including precautionary statements Emergency Overview Precautionary Statements - Prevention Obtain special instructions before use Wear protective gloves/protective clothing/eye protection/face protection Do not handle until all safety precautions have been read and understood Use only outdoors or in a well-ventilated area Wash face, hands and any exposed skin thoroughly after handling Do not breathe dust/fume/gas/mist/vapors/spray Keep away from heat/sparks/open flames/hot surfaces. — No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Precautionary Statements - Response If exposed or concerned: Get medical advice/attention Specific measures (see first aid on this label) Flammable aerosols Category 1 Gases under pressure Compressed Gas DANGER Hazard Statements Harmful in contact with skin Harmful if inhaled Causes skin irritation Causes serious eye irritation Suspected of causing cancer Suspected of damaging fertility or the unborn child May cause respiratory irritation. May cause drowsiness or dizziness May cause damage to organs ( central nervous system , lungs ,and respiratory system) through prolonged or repeated exposure. May be fatal if swallowed and enters airways Extremely flammable aerosol Contains gas under pressure; may explode if heated Appearance Clear Page 2 / 11 Physical state Aerosol Odor Light Vanilla Scent Page 191 of 871 Page 191 of 871 Page 191 of 871 Page 191 of 871 ---PAGE BREAK--- 91757 DECAL & LABEL REMOVER Revision Date 09-Mar-2015 3. COMPOSITION/INFORMATION ON INGREDIENTS CAS # 64742-49-0, COMMERCIAL HEXANES, MAY BE SUBSTITUTED FOR CAS #110-54-3. Synonyms Chemical Name CAS-No Weight HEXANE 64742-49-0 40-50 PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 20-30 PETROLEUM DISTILLATES 64742-47-8 10-20 XYLENE 1330-20-7 10-20 ETHYL BENZENE 100-41-4 1-10 *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES First aid measures for different exposure routes Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin contact Wash off immediately with soap and plenty of water. If skin irritation persists, call a physician. Inhalation Move to fresh air. If persist, call a physician. Ingestion Do NOT induce vomiting. If persist, call a physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or doctor/physician if you feel unwell If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep container closed Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) None Other information • Toxic to aquatic life with long lasting effects 0.79487% of the mixture consists of ingredient(s) of unknown toxicity Page 3 / 11 Page 192 of 871 Page 192 of 871 Page 192 of 871 Page 192 of 871 ---PAGE BREAK--- 91757 DECAL & LABEL REMOVER Revision Date 09-Mar-2015 Most important acute and delayed Main Not applicable. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Decomposition by contact with water may generate vapors which can be ignited by heat or open flame. Specific hazards arising from the chemical No information available. Explosion Data Sensitivity to Mechanical Impact none. Sensitivity to Static Discharge Yes. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation. Environmental precautions Environmental precautions No special environmental precautions required. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Methods and materials for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top of can. Conditions for safe storage, including any incompatibilities Technical measures/Storage conditions Keep containers closed in a dry, cool and well-ventilated place. Incompatible products None known based on information supplied. Aerosol Level Page 4 / 11 3 Page 193 of 871 Page 193 of 871 Page 193 of 871 Page 193 of 871 ---PAGE BREAK--- 91757 DECAL & LABEL REMOVER Revision Date 09-Mar-2015 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH HEXANE 64742-49-0 TWA: 50 ppm Skin - potential significant contribution to overall exposure by the cutaneous route TWA: 500 ppm TWA: 1800 mg/m3 (vacated) TWA: 50 ppm (vacated) TWA: 180 mg/m3 IDLH: 1100 ppm TWA: 50 ppm TWA: 180 mg/m3 PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 74-98-6: TWA: 1000 ppm 106-97-8: STEL: 1000 ppm 75-28-5: STEL: 1000 ppm 74-98-6:TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 106-97-8: (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 74-98-6:IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 106-97-8:TWA: 800 ppm TWA: 1900 mg/m3 75-28-5:TWA: 800 ppm TWA: 1900 mg/m3 XYLENE 1330-20-7 STEL: 150 ppm TWA: 100 ppm TWA: 100 ppm TWA: 435 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 435 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 655 mg/m3 - ETHYL BENZENE 100-41-4 TWA: 20 ppm TWA: 100 ppm TWA: 435 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 435 mg/m3 (vacated) STEL: 125 ppm (vacated) STEL: 545 mg/m3 IDLH: 800 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 125 ppm STEL: 545 mg/m3 ACGIH: (American Conference of Governmental Industrial Hygienists) OSHA: (Occupational Safety & Health Administration) NIOSH IDLH: Immediately Dangerous to Life or Health Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Exposure controls Engineering Measures Showers Eyewash stations Ventilation systems. Individual protection measures, such as personal protective equipment Eye/Face Protection Safety glasses with side-shields. Skin and body protection Chemical resistant apron. Protective gloves. Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and chemical properties Physical state Aerosol Appearance Clear Page 5 / 11 Odor Light Vanilla Scent Page 194 of 871 Page 194 of 871 Page 194 of 871 Page 194 of 871 ---PAGE BREAK--- 91757 DECAL & LABEL REMOVER Revision Date 09-Mar-2015 Explosive properties No information available Other information VOC Content(%) 100 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to Avoid Extremes of temperature and direct sunlight. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Product does not present an acute toxicity hazard based on known information Inhalation Harmful if inhaled. Irritating to respiratory system. May cause drowsiness or dizziness. Avoid breathing vapors or mists. Eye contact causes serious eye damage. Avoid contact with eyes. Skin contact Harmful in contact with skin. Causes skin irritation. Avoid contact with skin. Color clear Odor Threshold Property Values Remarks • Methods pH No information available Melting/freezing point No information available Boiling point/boiling range No information available Flash Point -97 °C / -143 °F Based on propellant Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limits in Air upper flammability limit No information available lower flammability limit No information available Vapor pressure No information available Vapor density No information available Specific Gravity 0.690 Water solubility Practically insoluble Partition coefficient: n-octanol/waterNo information available Autoignition temperature No information available Not applicable Decomposition temperature No information available Viscosity No information available Page 6 / 11 No data available Page 195 of 871 Page 195 of 871 Page 195 of 871 Page 195 of 871 ---PAGE BREAK--- 91757 DECAL & LABEL REMOVER Revision Date 09-Mar-2015 Ingestion Aspiration into the lungs during swallowing may cause serious lung damage which may be fatal. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation HEXANE 64742-49-0 > 5000 mg/kg ( Rat ) > 3160 mg/kg ( Rabbit ) = 73680 ppm ( Rat ) 4 h PETROLEUM DISTILLATES 64742-47-8 > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5.2 mg/L ( Rat ) 4 h XYLENE 1330-20-7 = 3500 mg/kg ( Rat ) > 4350 mg/kg ( Rabbit ) = 29.08 mg/L ( Rat ) 4 h ETHYL BENZENE 100-41-4 = 3500 mg/kg ( Rat ) = 15400 mg/kg ( Rabbit ) = 17.2 mg/L ( Rat ) 4 h Information on toxicological effects of overexposure may be headache, tiredness, nausea, and vomiting. Causes respiratory irritation. Causes skin and eye irritation.Aspiration into the lungs during swallowing may cause serious lung damage which may be fatal. Delayed and immediate effects as well as chronic effects from short and long-term exposure Skin corrosion/irritation Irritating to skin. Eye damage/irritation Irritating to eyes. Sensitization No information available. Germ Cell Mutagenicity None known. Carcinogenicity The table below indicates whether each agency has evaluated a listed ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA XYLENE 1330-20-7 - Group 3 - - ETHYL BENZENE 100-41-4 A3 Group 2B - - ACGIH: (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC: (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans Group 3 - Not Classifiable as to Carcinogenicity in Humans OSHA: (Occupational Safety & Health Administration) X - Present Reproductive toxicity Product is or contains a chemical which is a known or suspected reproductive hazard. Specific target organ systemic toxicity (single exposure) May cause respiratory irritation. May cause drowsiness and dizziness. Specific target organ systemic toxicity (repeated exposure) Causes damage to organs through prolonged or repeated exposure. Chronic toxicity Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Chronic hydrocarbon abuse has been associated with irregular heart and potential cardiac arrest. Target Organ Effects Central nervous system, Eyes, Respiratory system, Skin. Aspiration hazard May be fatal if swallowed and enters airways. Numerical measures of toxicity - Product Information Unknown Acute Toxicity 0.79487% of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 6103 mg/kg ATEmix (dermal) 8595 mg/kg ATEmix (inhalation-dust/mist) 9.5 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity Page 7 / 11 Page 196 of 871 Page 196 of 871 Page 196 of 871 Page 196 of 871 ---PAGE BREAK--- 91757 DECAL & LABEL REMOVER Revision Date 09-Mar-2015 Chemical Name Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphnia and other aquatic invertebrates PROPANE/ISOBUTANE/N- BUTANE 68476-86-8 - - - - PETROLEUM DISTILLATES 64742-47-8 - 2.2 mg/L LC50 Lepomis macrochirus 96h static 2.4 mg/L LC50 mykiss 96h static 45 mg/L LC50 Pimephales promelas 96h flow-through - - XYLENE 1330-20-7 - 13.1 - 16.5 mg/L LC50 Lepomis macrochirus 96h flow-through 13.5 - 17.3 mg/L LC50 mykiss 96h 2.661 - 4.093 mg/L LC50 mykiss 96h static 23.53 - 29.97 mg/L LC50 Pimephales promelas 96h static 30.26 - 40.75 mg/L LC50 Poecilia reticulata 96h static 7.711 - 9.591 mg/L LC50 Lepomis macrochirus 96h static 13.4 mg/L LC50 Pimephales promelas 96h flow-through 19 mg/L LC50 Lepomis macrochirus 96h 780 mg/L LC50 Cyprinus carpio 96h semi-static 780 mg/L LC50 Cyprinus carpio 96h - 0.6 mg/L LC50 Gammarus lacustris 48h 3.82 mg/L EC50 water flea 48h ETHYL BENZENE 100-41-4 4.6 mg/L EC50 Pseudokirchneriella subcapitata 72h 438 mg/L EC50 Pseudokirchneriella subcapitata 96h 2.6 - 11.3 mg/L EC50 Pseudokirchneriella subcapitata 72h static 1.7 - 7.6 mg/L EC50 Pseudokirchneriella subcapitata 96h static 11.0 - 18.0 mg/L LC50 mykiss 96h static 7.55 - 11 mg/L LC50 Pimephales promelas 96h flow-through 9.1 - 15.6 mg/L LC50 Pimephales promelas 96h static 32 mg/L LC50 Lepomis macrochirus 96h static 4.2 mg/L LC50 mykiss 96h semi-static 9.6 mg/L LC50 Poecilia reticulata 96h static - 1.8 - 2.4 mg/L EC50 Daphnia magna 48h Persistence and degradability No information available. Bioaccumulation No information available. Chemical Name log Pow PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 2.8 XYLENE 1330-20-7 3.15 ETHYL BENZENE 100-41-4 3.118 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Page 8 / 11 Waste treatment Page 197 of 871 Page 197 of 871 Page 197 of 871 Page 197 of 871 ---PAGE BREAK--- 91757 DECAL & LABEL REMOVER Revision Date 09-Mar-2015 Waste Disposal Methods It must undergo special treatment, e.g. at suitable disposal site, to comply with local regulations. Contaminated packaging Do not re-use empty containers. 14. TRANSPORT INFORMATION DOT Ground CONSUMER COMMODITY ORM-D or LIMITED QUANTITY IATA UN1950, AEROSOLS, FLAMMABLE, 2.1, LTD. QTY. IMDG UN1950, AEROSOLS, 2.1, LTD. QTY. 15. REGULATORY INFORMATION International Inventories Chemical Name TSCA DSL/NDSL EINECS/ELI NCS ENCS IECSC KECL PICCS AICS HEXANE X X X X X X X X PROPANE/ISOBUTA NE/N-BUTANE X X X Not listed X X X X PETROLEUM DISTILLATES X X X X X X X X XYLENE X X X X X X X X ETHYL BENZENE X X X X X X X X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances CHINA - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name CAS-No Weight SARA 313 - Threshold Values % XYLENE - 1330-20-7 1330-20-7 10-20 1.0 ETHYL BENZENE - 100-41-4 100-41-4 1-10 0.1 SARA 311/312 Hazard Categories Acute Health Hazard Yes Page 9 / 11 Chronic Health Hazard Yes Page 198 of 871 Page 198 of 871 Page 198 of 871 Page 198 of 871 ---PAGE BREAK--- 91757 DECAL & LABEL REMOVER Revision Date 09-Mar-2015 Fire Hazard Yes Sudden Release of Pressure Hazard Yes Reactive Hazard no Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42): Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances XYLENE 1330-20-7 100 lb X ETHYL BENZENE 100-41-4 1000 lb X X X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs RQ XYLENE 1330-20-7 100 lb RQ 100 lb final RQ RQ 45.4 kg final RQ ETHYL BENZENE 100-41-4 1000 lb RQ 1000 lb final RQ RQ 454 kg final RQ U.S. State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals: Chemical Name California Prop. 65 ETHYL BENZENE - 100-41-4 Carcinogen U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts XYLENE 1330-20-7 X X X ETHYL BENZENE 100-41-4 X X X EPA Pesticide Registration Number Not applicable Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Prepared By Regulatory Affairs Issuing date 09-Mar-2015 Revision Date 09-Mar-2015 Revision Note No information available NFPA Health Hazard 2 Flammability 4 Instability 0 Physical and chemical hazards - HMIS Health Hazard 2 Flammability 4 Page 10 / 11 Physical Hazard 1 Personal protection B Page 199 of 871 Page 199 of 871 Page 199 of 871 Page 199 of 871 ---PAGE BREAK--- 91757 DECAL & LABEL REMOVER Revision Date 09-Mar-2015 Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of Safety Data Sheet Page 11 / 11 Page 200 of 871 Page 200 of 871 Page 200 of 871 Page 200 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 11-Mar-2013 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 91757 Product name Decal Remover Recommended Use Adhesive Remover Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known. Principal Routes of Exposure Skin contact. Skin absorption. Inhalation. Ingestion. Eyes. Potential health effects Eyes May cause the following effects:. Irritation. Pain. Tearing. Reddening. Swelling. Stinging sensation. Feeling like that of fine dust in the eye. Skin Repeated or prolonged exposure may cause skin irritation and dermatitis, due to degreasing properties of the product. Defatting. Chronic exposure causes drying effect on the skin . Inhalation Repeated or prolonged exposure may cause the following effects:. Headaches. Dizziness. Nausea. Decreased blood pressure. Changes in heart rate. Cyanosis. Extreme overexposure may cause. Central nervous system damage. Lung damage. Kidney damage. Harmful by inhalation. Ingestion Harmful or fatal if swallowed. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Hexane 110-54-3 30-60 Propane/Isobutane/N- Butane 68476-86-8 15-40 Stoddard solvent 8052-41-3 10-30 1330-20-7 10-30 Ethyl benzene 100-41-4 3-7 4. FIRST AID MEASURES Eye contact Flush eyes immediately with large amounts of water. Seek medical attention if irritation persists. Skin contact Wash off immediately with plenty of water. Remove and wash contaminated clothing before re-use. Seek medical attention. Ingestion Seek medical attention immediately. Do not induce vomiting. Give victim a glass of water or milk. Contact physician or poison control center immediately. Do not give anything by mouth to an unconscious person. Inhalation Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Seek medical attention immediately. 5. FIRE FIGHTING MEASURES Flash point °C -104 Flash point °F -156 Method Pensky-Martens C.C. Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 9.5 Lower 0.7 Suitable extinguishing media Alcohol foam. Carbon dioxide (CO2). Dry chemical powder. Foam. Water fog. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Specific hazards Keep product and empty container away from heat and sources of ignition. Page 1 / 4 Emergency Overview Vapors irritating to eyes and respiratory tract. Vapors may cause flash fire or explosion. Page 201 of 871 Page 201 of 871 Page 201 of 871 Page 201 of 871 ---PAGE BREAK--- Fire and Explosion Hazards Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Empty containers contain residue and/or vapors. Do not weld, cut, pressurize, braze, solder, drill, grind, or expose such containers to heat, sparks, flame, static electricity, or other sources of ignition. They may explode and cause injury or death. Aerosol containers may vent, rupture or burst when heated to temperatures above 120°F. Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Soak up with noncombustible inert absorbent material. Place in non- leaking, sealed container for proper disposal. 7. HANDLING AND STORAGE Handling Keep in a well-ventilated place. Thoroughly wash hands and exposed skin after handling. Wash hands with soap and water before eating, drinking, smoking, or using toilet facilities. Use only according to label directions. Handle empty containers as if they were full. Avoid breathing vapors. Avoid contact with skin, eyes and clothing. Storage Keep away from heat. Keep away from open flames, hot surfaces and sources of ignition. Do not freeze. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Hexane 500 ppm 1800 mg/m3 - 50 ppm N/D Propane/Isob utane/N- Butane - - - - Stoddard solvent 500 ppm 2900 mg/m3 - 100 ppm - ene 100 ppm 435 mg/m3 - 100 ppm 150 ppm Ethyl benzene 100 ppm 435 mg/m3 - 20 ppm - Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Hygiene measures Wash hands before eating or using the washroom. Remove and wash contaminated clothing before re-use. Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Wear a NIOSH approved organic vapor respirator. Use a positive pressure supplied air respirator. if there is any potential for an uncontrolled release:. or other circumstances where an air purifying respirator (P100) may not provide adequate protection . Hand Protection Chemical resistant gloves. Consult glove manufacturer to determine the proper type for a specific operation. Eye protection Safety glasses with side-shields. Face shield is recommended. Skin and body protection Wear appropriate clothing to minimize skin contact. Rubber or plastic boots. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Clear Odor Solvent Odor Threshold No information available pH No data available Specific Gravity 0.6787 Vapor pressure 80-90 Vapor density heavier than air Evaporation Rate >1 (Butyl Acetate = 1) Water solubility Negligible VOC Content 5.58 Partition Coefficient (n-octanol/water) No data available Boiling point/range °C -41 - 197 Boiling point/range °F -43 - 387 Melting point/range °C 0 Melting point/range °F 32 Flash point °C -104 Flash point °F -156 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions. Conditions to avoid Avoid sources of ignition. Contact with ignition sources, hot-glowing surfaces, electrical arcs, sparks, and open flame. Incompatability Strong acids. Oxidizers. Amines. Alkalies. Page 2 / 4 Product name Decal Remover Product code 91757 Page 202 of 871 Page 202 of 871 Page 202 of 871 Page 202 of 871 ---PAGE BREAK--- Hazardous Decomposition Products Carbon oxides. Nitrogen oxides (NOx). Chloride. Chlorine. phosgene. Polymerization Hazardous polymerization does not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Hexane 110-54-3 25 g/kg 3000 mg/kg 48000 ppm Propane/Isobutan e/N-Butane 68476-86-8 - - - Stoddard solvent 8052-41-3 - - - 1330-20-7 4300 mg/kg 1700 mg/kg 47635 mg/L 5000 ppm Ethyl benzene 100-41-4 3500 mg/kg 15354 mg/kg 17.2 mg/L Synergistic Products None known Specific Hazards Hexane has been reported to affect the central nervous system and may damage peripheral nerve tissue. Potential health effects Sensitization None known . Chronic toxicity See Section 2 . Mutagenic effects None known . Teratogenic effects None known . Reproductive toxicity None known . Target Organ Effects Central nervous system. Long term exposure to vapor may cause lung damage. Long term exposure to vapor may cause kidney damage. Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Hexane Not Listed Not Listed Not Listed Not Listed Not Listed Propane/Isob utane/N- Butane Not Listed Not Listed Not Listed Not Listed Not Listed Stoddard solvent Not Listed Not Listed Not Listed Not Listed Not Listed ene A4 Not Listed Not Listed Not Listed Not Listed Ethyl benzene A3 Group 2B Not Listed Not Listed Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT UN1950 Aerosols, flammable, 2.1. Exception: (Compressed Gas not more than 1.0L) Consumer Commodity ORM-D TDG UN1950 AEROSOLS, flammable, 2.1 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Hexane Listed Listed Ethyl benzene Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Hexane Listed Listed Not Listed Propane/Isobutane/N- Butane Not Listed Not Listed Not Listed Stoddard solvent Listed Listed Not Listed Not Listed Listed Not Listed Ethyl benzene Listed Listed Carcinogen Page 3 / 4 Microtox Data Photobacterium phosphoreum EC50=9.68 mg/L (30 min) Nitrosomonas EC50=96 mg/L (24 h) Water Flea Data Daphnia magna EC501.8 - 2.4 mg/L (48 h) Hexane Microtox Data Photobacterium phosphoreum EC50=0.0084 mg/L (24 h) Product code 91757 Water Flea Data water flea hEC50 48 (3.82 mg/L) Gammarus lacustris hLC50 48 (0.6 mg/L) water flea hEC50 48 (3.82 mg/L) Water Flea Data Daphnia magna EC50>1000 mg/L (24 h) Ethyl benzene Product name Decal Remover Page 203 of 871 Page 203 of 871 Page 203 of 871 Page 203 of 871 ---PAGE BREAK--- International Inventories Chemical Name EINECS DSL NDSL TSCA Hexane X X - X Propane/Isobutane/N- Butane X X - X Stoddard solvent X X - X X X - X Ethyl benzene X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. OTHER INFORMATION HMIS Health - 2 Flammability - 4 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product code 91757 Product name Decal Remover Page 204 of 871 Page 204 of 871 Page 204 of 871 Page 204 of 871 ---PAGE BREAK--- Conforms to HazCom 2012/United States, Mexico SAFETY DATA SHEET Section 1. Identification GHS product identifier : DispenseAGasket Black Silicone Sealant Other means of : 93844 identification Relevant identified uses of the substance or mixture and uses advised against Silicone sealant Supplier's details : Lawson Products, Inc. 8770 W. Bryn Mawr Ave, Suite 900 Chicago, IL 60631 Phone: [PHONE REDACTED] Emergency telephone : [PHONE REDACTED] number (with hours of operation) Section 2. Hazards identification OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the : substance or mixture GHS label elements Hazard pictograms : SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2 Signal word : Warning Hazard statements : Causes serious eye irritation. Causes skin irritation. Precautionary statements General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Prevention : Wear protective gloves. Wear eye or face protection. Wash hands thoroughly after handling. Response : IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Not applicable. Disposal : Not applicable. Page 205 of 871 Page 205 of 871 Page 205 of 871 Page 205 of 871 ---PAGE BREAK--- Section 2. Hazards identification Hazards not otherwise : None known. classified Section 3. Composition/information on ingredients Substance/mixture : Mixture Other means of : Not available. identification CAS number/other identifiers CAS number : Not applicable. Product code : Not available. Ingredient name % CAS number 1 - 5 17689-77-9 triacetate 1 - 5 4253-34-3 1,1-Difluoroethane 1 - 5 75-37-6 Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Description of necessary first aid measures Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Flush contaminated skin with plenty of water. Continue to rinse for at least 20 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Most important acute and delayed Potential acute health effects Eye contact : Causes serious eye irritation. Eye contact : Inhalation : Skin contact : Ingestion : Page 206 of 871 Page 206 of 871 Page 206 of 871 Page 206 of 871 ---PAGE BREAK--- Suitable extinguishing media Use an extinguishing agent suitable for the surrounding fire. : Unsuitable extinguishing media : None known. Specific hazards arising from the chemical No specific fire or explosion hazard. : : Decomposition products may include the following materials: carbon dioxide carbon monoxide halogenated compounds carbonyl halides metal oxide/oxides : : No special precaution is required. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 4. First aid measures Inhalation : Skin contact : Ingestion : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Causes skin irritation. Irritating to mouth, throat and stomach. Over-exposure Eye contact : Inhalation : Skin contact : Ingestion : Indication of immediate medical attention and special treatment needed, if necessary In case of inhalation of decomposition products in a fire, may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. No specific treatment. No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : Specific treatments : Protection of first-aiders : See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media Hazardous thermal decomposition products Special protective actions for fire-fighters Special protective equipment for fire-fighters Adverse may include the following: pain or irritation watering redness No known significant effects or critical hazards. Adverse may include the following: irritation redness No known significant effects or critical hazards. Page 207 of 871 Page 207 of 871 Page 207 of 871 Page 207 of 871 ---PAGE BREAK--- Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. Keep personnel unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up Small spill : Large spill : Move containers from spill area. Place spilled material in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Do not dry sweep. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section Do not ingest. Avoid contact with eyes, skin and clothing. Keep in the original container or an approved alternative made from a compatible material, kept closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities : : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits United States None. Mexico Ingredient name Exposure limits Silica NOM-010-STPS (Mexico, 9/2000). LMPE-PPT: 3 mg/m3 8 hours. Form: breathable particulates LMPE-PPT: 10 mg/m3 8 hours. Form: inhalable particulates Page 208 of 871 Page 208 of 871 Page 208 of 871 Page 208 of 871 ---PAGE BREAK--- Section 8. Exposure controls/personal protection Appropriate engineering controls Environmental exposure controls : No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Page 209 of 871 Page 209 of 871 Page 209 of 871 Page 209 of 871 ---PAGE BREAK--- Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Ensure that eyewash stations and safety showers are close to the workstation location. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or gases. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measur based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Section 9. Physical and chemical properties Appearance Physical state : Solid. [Paste.] Color : Depends on specific color ordered Odor : Acetic acid odor. Odor threshold : Not available. pH : Not available. Melting point : Not available. Boiling point : Not available. Flash point : Closed cup: >100°C (>212°F) Burning time : Not available. Burning rate : Not available. Evaporation rate : Not available. Flammability (solid, gas) : Not available. Individual protection measures Hygiene measures : Eye/face protection : Skin protection Hand protection : Page 210 of 871 Page 210 of 871 Page 210 of 871 Page 210 of 871 ---PAGE BREAK--- Section 9. Physical and chemical properties Lower and upper explosive (flammable) limits Vapor pressure Vapor density Relative density Solubility : Not available. Solubility in water : Not available. Partition coefficient: n- octanol/water : There is no data available. Auto-ignition temperature : Not available. Decomposition temperature : Not available. SADT : Not available. Viscosity : Not available. Section 10. Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : No specific data. Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should products not be produced. Section 11. Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure triacetate LD50 Oral Rat 2060 mg/kg - Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation Silica Eyes - Mild irritant Rabbit - 24 hours 25 mg - Sensitization There is no data available. Mutagenicity There is no data available. Carcinogenicity There is no data available. Reproductive toxicity : Not available. : Not available. : Not available. : 1.007 Page 211 of 871 Page 211 of 871 Page 211 of 871 Page 211 of 871 ---PAGE BREAK--- Section 11. Toxicological information There is no data available. Teratogenicity There is no data available. Specific target organ toxicity (single exposure) There is no data available. Specific target organ toxicity (repeated exposure) There is no data available. Aspiration hazard There is no data available. Information on the likely : Dermal contact. Eye contact. Inhalation. Ingestion. routes of exposure Potential acute health effects Eye contact : Inhalation : Skin contact : Ingestion : Causes serious eye irritation. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Causes skin irritation. Irritating to mouth, throat and stomach. related to the physical, chemical and toxicological characteristics Eye contact : Adverse may include the following: pain or irritation watering redness Inhalation : No known significant effects or critical hazards. Skin contact : Adverse may include the following: irritation redness Ingestion : No known significant effects or critical hazards. Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate : No known significant effects or critical hazards. effects Potential delayed effects : No known significant effects or critical hazards. Long term exposure Potential immediate : No known significant effects or critical hazards. effects Potential delayed effects : No known significant effects or critical hazards. Potential chronic health effects General : Carcinogenicity : Mutagenicity : Teratogenicity : No known significant effects or No known significant effects or No known significant effects or No known significant effects or Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. critical hazards. critical hazards. critical hazards. critical hazards. Page 212 of 871 Page 212 of 871 Page 212 of 871 Page 212 of 871 ---PAGE BREAK--- Section 11. Toxicological information Numerical measures of toxicity Acute toxicity estimates There is no data available. Section 12. Ecological information Toxicity There is no data available. Persistence and degradability There is no data available. Bioaccumulative potential There is no data available. Mobility in soil Soil/water partition : There is no data available. coefficient (KOC) Other adverse effects : No known significant effects or critical hazards. Section 13. Disposal considerations Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Section 14. Transport information DOT Classification IMDG IATA UN number ID8000 UN1950 UN1950 UN proper shipping name Consumer commodity Aerosols, [non-flammable, (each not exceeding 1 L capacity)] Aerosols, [non-flammable, (each not exceeding 1 L capacity)] Transport hazard class(es) ORM-D 2.2 2.2 Page 213 of 871 Page 213 of 871 Page 213 of 871 Page 213 of 871 ---PAGE BREAK--- Section 14. Transport information Packing group - - - Environmental hazards No. No. No. Additional information Remarks Remarks Remarks Limited Quantity Exemption Limited Quantity Exemption Limited Quantity Exemption AERG : Not applicable Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. Page 214 of 871 Page 214 of 871 Page 214 of 871 Page 214 of 871 ---PAGE BREAK--- Section 15. Regulatory information U.S. Federal regulations Clean Air Act Section 112 Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances DEA List I Chemicals (Precursor Chemicals) DEA List II Chemicals (Essential Chemicals) SARA 302/304 : TSCA 8(a) PAIR: Siloxanes and Silicones, di-Me, hydroxy-terminated TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): All components are listed or exempted. Clean Air Act (CAA) 112 regulated flammable substances: 1,1-Difluoroethane : Not listed : Not listed : Not listed : Not listed : Not listed Composition/information on ingredients No products were found. SARA 304 RQ : Not applicable. SARA 311/312 Classification : Immediate (acute) health hazard Composition/information on ingredients Name % Fire Sudden Reactive Immediate Delayed hazard release of pressure (acute) health hazard (chronic) health hazard 1 - 5 No. No. No. Yes. No. triacetate 1 - 5 No. No. No. Yes. No. State regulations Page 215 of 871 Page 215 of 871 Page 215 of 871 Page 215 of 871 ---PAGE BREAK--- Section 15. Regulatory information Massachusetts : The following components are listed: Silica; 1,1-Difluoroethane New York : None of the components are listed. New Jersey : The following components are listed: 1,1-Difluoroethane : The following components are listed: Silica California Prop. 65 No products were found. Mexico Classification : International regulations International lists : Australia inventory (AICS): All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. Japan inventory: Not determined. Korea inventory: All components are listed or exempted. Malaysia Inventory (EHS Register): Not determined. New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted. Philippines inventory (PICCS): All components are listed or exempted. Taiwan inventory (CSNN): Not determined. Chemical Weapons Convention List Schedule I Chemicals Chemical Weapons Convention List Schedule II Chemicals Chemical Weapons Convention List Schedule III Chemicals : Not listed : Not listed : Not listed Section 16. Other information History Date of issue mm/dd/yyyy : 05/30/2013 Date of previous issue : 04/15/2013 Version : 1.1 Revised Section(s) : 1, 3, 14, 16 Prepared by : Maureen Ruggeberg Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations Flammability Reactivity Special Health 2 0 1 Page 216 of 871 Page 216 of 871 Page 216 of 871 Page 216 of 871 ---PAGE BREAK--- Section 16. Other information Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Page 217 of 871 Page 217 of 871 Page 217 of 871 Page 217 of 871 ---PAGE BREAK--- I M A T E R I A L S A F E T Y D A T A S H E E T I I SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION I PRODUCT NAME : EASY SOLUTIONS - Household Adhesive UPC NUMBER : [PHONE REDACTED], [PHONE REDACTED] PRODUCT USE/CLASS : Latex Adhesive MANUFACTURER: 24 HOUR EMERGENCY: DAP INC. TRANSPORTATION: 1-[PHONE REDACTED] ([PHONE REDACTED]) 2400 BOSTON STREET MEDICAL : 1-[PHONE REDACTED] ([PHONE REDACTED]) BALTIMORE, MD 21224 PREPARE DATE : 10/16/2000 GENERAL INFORMATION: REVISION NO. : 0 DAP INC. : 1-888-DAP-TIPS (1-[PHONE REDACTED]) REVISION DATE: 10/16/2000 I SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS I WT/WT % ITEM CHEMICAL NAME CAS NUMBER RANGE 01 Ethanol 64-17-5 1.0-5.0 % EXPOSURE LIMITS ACGIH OSHA COMPANY ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN 01 1000 ppm N.E. 1000 ppm N.E. N.E. NO (See Section 16 for abbreviation legend) Remaining ingredients are not considered hazardous per the OSHA Hazard Communication Standard. Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); limits may vary between states. I SECTION 3 - HAZARDS IDENTIFICATION I EMERGENCY OVERVIEW: CAUTION! May irritate eyes, skin, nose, and respiratory tract. (Continued on Page 2) Page 218 of 871 Page 218 of 871 Page 218 of 871 Page 218 of 871 ---PAGE BREAK--- Product Name: EASY SOLUTIONS - Household Adhesive Revision Date: 10/16/2000 Page 2 I SECTION 3 - HAZARDS IDENTIFICATION I POTENTIAL HEALTH EFFECTS: EFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation. EFFECTS OF OVEREXPOSURE - INHALATION: Vapor harmful if inhaled. Vapor may irritate nose and upper respiratory tract. Vapor inhalation may affect the brain or nervous system causing dizziness, headache or nausea. EFFECTS OF OVEREXPOSURE - INGESTION: This material may be harmful or fatal if swallowed. If ingested this product may cause vomiting, diarrhea, and depressed respiration. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated permanent brain and nervous system damage with prolonged and repeated occupational overexposure to solvents. MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT: None known. PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT I SECTION 4 - FIRST AID MEASURES I EYE CONTACT: Flush with large quantities of water until irritation subsides. Contact a physician. SKIN CONTACT: Wash with soap and water. INHALATION: Remove to fresh air. Contact a physician immediately. INGESTION: DO NOT INDUCE VOMITING. Contact a physician or Regional Poison Control Center immediately. COMMENTS: None. I SECTION 5 - FIRE FIGHTING MEASURES I FLASH POINT: >200 F LOWER EXPLOSIVE LIMIT: N.A. (SETAFLASH CLOSED CUP) UPPER EXPLOSIVE LIMIT: N.A. AUTOIGNITION TEMPERATURE: N.E. EXTINGUISHING MEDIA: CO2 DRY CHEMICAL FOAM UNUSUAL FIRE AND EXPLOSION HAZARDS: None known. (Continued on Page 3) Page 219 of 871 Page 219 of 871 Page 219 of 871 Page 219 of 871 ---PAGE BREAK--- Product Name: EASY SOLUTIONS - Household Adhesive Revision Date: 10/16/2000 Page 3 I SECTION 5 - FIRE FIGHTING MEASURES I SPECIAL FIREFIGHTING PROCEDURES: As in any fire, wear self-contained breathing apparatus pressure-demand (MSHA/NIOSH approved or equivalent) and full protective gear. Use water spray to cool exposed surfaces. I SECTION 6 - ACCIDENTAL RELEASE MEASURES I SPILL OR LEAK PROCEDURES: Scrape up dried material and place into containers. I SECTION 7 - HANDLING AND STORAGE I HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. Avoid skin and eye contact. Avoid breathing vapors. Use only in a well ventilated area. STORAGE INFORMATION: Store away from caustics and oxidizers. Keep containers closed when not in use. Keep containers from excessive heat and freezing. Do not store at temperatures above 120 degrees F. OTHER PRECAUTIONS: Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Do not take internally. Use in a well ventilated area. Provide fresh air such that chemical odors cannot be detected during use and while drying. Construction and repair activities can adversely affect indoor air quality. Consult with the occupants or a representative(i.e. maintenance, building manager, industrial hygienist, or safety officer) to determine ways to minimize any impact. I SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION I ENGINEERING CONTROLS: Provide sufficient mechanical ventilation (local or general exhaust) to maintain exposure below PEL and TLV. Vapors are heavier than air and will collect in low areas. Check all low areas (basements, sumps, etc.) for vapor before entering. RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Not required under normal usage and adequate ventilation. EYE PROTECTION: Goggles or safety glasses with side shields. SKIN PROTECTION: Gloves recommended for repeated or prolonged contact with skin. OTHER PROTECTIVE EQUIPMENT: None. (Continued on Page 4) Page 220 of 871 Page 220 of 871 Page 220 of 871 Page 220 of 871 ---PAGE BREAK--- Product Name: EASY SOLUTIONS - Household Adhesive Revision Date: 10/16/2000 Page 4 I SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION I HYGIENIC PRACTICES: Wash contaminated clothing before reuse. I SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES I BOILING RANGE : 210 - 220 F VAPOR DENSITY : Is heavier than air ODOR : Mild Odor APPEARANCE : White Paste EVAPORATION RATE: Is slower than Butyl SOLUBILITY IN H2O : Miscible Acetate SPECIFIC GRAVITY : 1.4115 VAPOR PRESSURE : 17.5 mm Hg @ 68F. PHYSICAL STATE : Paste (See Section 16 for abbreviation legend) I SECTION 10 - STABILITY AND REACTIVITY I CONDITIONS TO AVOID: Excessive heat and freezing. INCOMPATIBILITY: Strong oxidizers and caustics. HAZARDOUS DECOMPOSITION PRODUCTS: Normal decomposition products, i.e. COx, NOx HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. I SECTION 11 - TOXICOLOGICAL PROPERTIES I No product or component toxicological information is available. I SECTION 12 - ECOLOGICAL INFORMATION I No Information. (Continued on Page 5) Page 221 of 871 Page 221 of 871 Page 221 of 871 Page 221 of 871 ---PAGE BREAK--- Product Name: EASY SOLUTIONS - Household Adhesive Revision Date: 10/16/2000 Page 5 I SECTION 13 - DISPOSAL CONSIDERATIONS I WASTE MANAGEMENT/DISPOSAL: Dispose of according to Federal, State, and Local Standards. Do not reuse empty containers. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA WASTE CODE - If discarded (40 CFR 261): None. I SECTION 14 - TRANSPORTATION INFORMATION I DOT PROPER SHIPPING NAME: Not Regulated by D.O.T. DOT HAZARD CLASS: NONE DOT UN/NA NUMBER: NONE PACKING GROUP: NONE I SECTION 15 - REGULATORY INFORMATION I U.S. FEDERAL REGULATIONS: AS FOLLOWS - OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER WT/WT % RANGE No SARA Section 313 components exist in this product. TOXIC SUBSTANCES CONTROL ACT: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: CHEMICAL NAME CAS NUMBER ETHYL ACETATE 141-78-6 METHYL ISOBUTYL KETONE 108-10-1 95-63-6 108-67-8 CUMENE 98-82-8 N-BUTYL ACETATE 123-86-4 ACETONE 67-64-1 (Continued on Page 6) Page 222 of 871 Page 222 of 871 Page 222 of 871 Page 222 of 871 ---PAGE BREAK--- Product Name: EASY SOLUTIONS - Household Adhesive Revision Date: 10/16/2000 Page 6 I SECTION 15 - REGULATORY INFORMATION I NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components in this product: CHEMICAL NAME CAS NUMBER Water 7732-18-5 Vinyl acetate copolymer TSRN-618608-5056P Plasticizer TSRN-618608-5064P Calcium Carbonate 1317-65-3 RIGHT-TO-KNOW: The following non-hazardous ingredients are present in the product at greater than CHEMICAL NAME CAS NUMBER Water 7732-18-5 Vinyl acetate copolymer proprietary Plasticizer proprietary Calcium carbonate 1317-65-3 CALIFORNIA PROPOSITION 65: WARNING: The chemical(s) noted below and contained in this product, are known to the state of California to cause cancer, birth defects or other reproductive harm: CHEMICAL NAME CAS NUMBER No Proposition 65 chemicals exist in this product. INTERNATIONAL REGULATIONS: AS FOLLOWS - CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: No information available. (Continued on Page 7) Page 223 of 871 Page 223 of 871 Page 223 of 871 Page 223 of 871 ---PAGE BREAK--- Product Name: EASY SOLUTIONS - Household Adhesive Revision Date: 10/16/2000 Page 7 I SECTION 16 - OTHER INFORMATION I HMIS RATINGS - HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0 PREVIOUS MSDS REVISION DATE: N/A VOC less water, less exempt solvent: 80-85 gm/L(0.5-1 lb/gal)(5.5-6 wt%VOC) VOC material : 50-55 gm/l(5-6%) LEGEND: ACGIH - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS N.A. - NOT APPLICABLE N.E. - NOT ESTABLISHED PEL - PERMISSIBLE EXPOSURE LIMIT NTP - NATIONAL TOXICOLOGY PROGRAM SARA - SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 STEL - SHORT TERM EXPOSURE LIMIT TLV - THRESHOLD LIMIT VALUE(8 HR. TIME WEIGHTED AVERAGE OR TWA) VOC - VOLATILE ORGANIC COMPOUND - NEW JERSEY RIGHT TO KNOW LAW N.D. - NOT DETERMINED MSDS# 30712 This data is offered in good faith as typical values and not as a product specification. No warranty either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review the recommendations in specific context of the intended use and determine if they are appropriate. < End OF MSDS > Page 224 of 871 Page 224 of 871 Page 224 of 871 Page 224 of 871 ---PAGE BREAK--- Material Safety Data Sheet F 1. Chemical Product and Company Identification DESCRIPTION: ELMER'S CHINA/GLASS CEMENT PRODUCT TYPE: ACRYLIC BASED ADHESIVE APPLICATION: 60817 Manufacturer/Supplier Information G MSDS Prepared by: Elmer's Products, Inc. Emergency Phone Number 1000 Kingsmill Parkway Poison Control Center Columbus, OH 43229 1-[PHONE REDACTED] ext 22 For additional health, safety or regulatory information, call [PHONE REDACTED]. Call 1-[PHONE REDACTED] to place an order or request additional 2. Composition, Information on Ingredients No hazardous ingredients known to company. 3. Hazards Identification 3.1 Emergency Overview Appearance Milky-White liquid Odor Mild ammonia CAUTION! Not a significant fire hazard. 60817CN ELMER'S CHINA/GLASS CEMENT files/m60817cn.htm (1 of 7) [5/25/2006 8:59:19 AM] Page 225 of 871 Page 225 of 871 Page 225 of 871 Page 225 of 871 ---PAGE BREAK--- HMIS Rating G HEALTH = 1 (slight) FLAMMABILITY = 0 (minimal) REACTIVITY = 0 (minimal) 3.2 Potential Health Effects Immediate Hazards G INGESTION: No hazards known to company. INHALATION: No hazards known to company. SKIN: May cause irritation on prolonged or repeated contact. EYES: No hazards known to company. Delayed Hazards G None of the components present in this product at concentrations equal to or greater than 0.1% have been listed by NTP, classified by IARC, nor regulated by OSHA as a carcinogen. 4. First Aid Measures INGESTION: If accidentally swallowed, dilute by drinking large quantities of water. Immediately contact poison control center or hospital emergency room for any other additional treatment directions. SKIN: In case of irritation, flush with water. EYES: Immediately flush eyes with plenty of water. Call a physician if irritation persists. 5. Fire Fighting Measures Autoignition Temperature Not available Upper/Lower Flammable Limits Not applicable Up/Lower Explosive Limits, % by Vol Not applicable Flash Point Not applicable Will not burn unless water has evaporated. Dried material may burn. In case of fire, water should be used to keep fire-exposed containers cool. 6. Accidental Release Measures 60817CN ELMER'S CHINA/GLASS CEMENT files/m60817cn.htm (2 of 7) [5/25/2006 8:59:19 AM] Page 226 of 871 Page 226 of 871 Page 226 of 871 Page 226 of 871 ---PAGE BREAK--- Soak up with absorbent material and remove to a chemical disposal area. Prevent entry into natural bodies of water. 7. Handling and Storage 7.1 Handling Handle in accordance with good industrial hygiene and safety practices. Always use appropriate Personal Protective Equipment (PPE). SKIN: Persons with sensitive skin should avoid prolonged, continuous contact with skin. If irritation develops, discontinue use. 7.2 Storage Keep from freezing. Store in a cool, dry place. Keep containers closed. 8. Exposure Controls/Personal Protection 8.1 Exposure Controls No special control measures necessary under normal conditions of use. 8.2 Personal Protection No special protection necessary. 8.3 Exposure Guidelines None established 60817CN ELMER'S CHINA/GLASS CEMENT files/m60817cn.htm (3 of 7) [5/25/2006 8:59:19 AM] Page 227 of 871 Page 227 of 871 Page 227 of 871 Page 227 of 871 ---PAGE BREAK--- 9. Physical and Chemical Properties Percent Volatiles 56 pH @ 25 C 9.5 Specific Gravity 1.04 Appearance Milky-White liquid Autoignition Temperature Not available Boiling Point 100 deg C Vapor Density (Air=1) < 1 Vapor Pressure, mm Hg @ 20 C 17.5 Evaporation Rate (Butyl Acetate=1) < 1 Upper/Lower Flammable Limits Not applicable Up/Lower Explosive Limits, % by Vol Not applicable Flash Point Not applicable Freezing Point 0 deg C Odor Mild ammonia Odor Threshold, ppm Not available Solubility in Water Dispersible Coefficient of Water/Oil Distrib. Not available 10. Stability and Reactivity Normally stable as defined in NFPA 704-12(4-3.1). Incompatibilities: G Acids. Decomposition products may include: G Oxides of carbon. Hazardous polymerization: G Will not occur. Other Hazards: G None known to company. 11. Toxicological Information INGESTION: Not toxic orally when tested as described in 16 CFR Part 1500.3 and INHALATION: Not toxic by inhalation when tested as described in 16 CFR Part 1500.3 and 60817CN ELMER'S CHINA/GLASS CEMENT files/m60817cn.htm (4 of 7) [5/25/2006 8:59:19 AM] Page 228 of 871 Page 228 of 871 Page 228 of 871 Page 228 of 871 ---PAGE BREAK--- SKIN Not toxic dermally when tested as described in 16 CFR ABSORPTION: Part 1500.3 and EYES: Not an irritant when tested as described in 16 CFR Part 1500.42. 12. Ecological Information Not determined. 13. Disposal Considerations Recover free liquid. Absorb residue and dispose of according to local, state/provincial, and federal requirements. 14. Transport Information 14.1 U.S. Department of Transportation (DOT) The data provided in this section is for information only and may not be specific to your package size. You will need to apply the appropriate regulations to properly classify your shipment for transportation. Non-Regulated. 14.2 Canadian Transportation of Dangerous Goods (TDG) Non-Regulated. 15. Regulatory Information (Selected Regulations) 15.1 U.S. Federal Regulations OSHA Hazard Communication Standard 29CFR1910.1200 G 60817CN ELMER'S CHINA/GLASS CEMENT files/m60817cn.htm (5 of 7) [5/25/2006 8:59:19 AM] Page 229 of 871 Page 229 of 871 Page 229 of 871 Page 229 of 871 ---PAGE BREAK--- This material is not a "health hazard" or a "physical hazard" as determined when reviewed according to the requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200 "Hazard Communication" Standard. SARA Title III: Section 311/312 G Does not meet any hazard category SARA Title III Section 313 and 40 CFR Part 372 G This product contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and Subpart C-Supplier Notification Requirement of 40 CFR Part 372. None required per SARA TITLE III SECTION 313. TSCA Section 8(b) Inventory G All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications of compliance from our suppliers for chemical substances not manufactured by us. 15.2 Canadian Regulations Workplace Hazardous Materials Information System (WHMIS) G This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR) and the MSDS contains all the information required by the CPR. Not a controlled product Canadian Environmental Protection Act (CEPA) G All reportable chemical substances are listed on the Domestic Substances List (DSL) or otherwise comply with CEPA new substance notification requirements. National Pollutant Release Inventory (NPRI) G This product contains the following chemical(s) subject to the reporting requirements of the Canadian Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release Inventory. None required. 60817CN ELMER'S CHINA/GLASS CEMENT files/m60817cn.htm (6 of 7) [5/25/2006 8:59:19 AM] Page 230 of 871 Page 230 of 871 Page 230 of 871 Page 230 of 871 ---PAGE BREAK--- 16. Other Information AP (Non-Toxic): Products bearing the AP (Non-Toxic) Product Seal of The Art & Creative Materials Institute, Inc. (ACMI) are certified in a program of toxicological evaluation by a medical expert to contain no materials in sufficient quantities to be toxic or injurious to humans or to cause acute or chronic health problems. This program is reviewed by ACMI's Toxicological Advisory Board. These products are certified by ACMI to be labeled in accordance with the chronic hazard labeling standard, ASTM D-4236 and Federal Law, P.L. 100-695. In addition, there is no physical hazard as defined within 29 CFR Part 1910.1200(c). MSDS covers items: U.S.: E816 Canada: 60817 User's Responsibility G The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace Hazardous Materials Information System (WHMIS) require that the information contained on these sheets be made available to your workers. Educate and train your workers regarding OSHA and WHMIS precautions. Instruct your workers to handle this product properly. Consult with appropriate experts to guard against hazards associated with use of this product and its ingredients. Disclaimer G SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product shall conform to contracted specifications, and that the product does not infringe any valid United States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, negligence or otherwise. CUR ISSUE 01-JAN-04 PREVIOUS ISSUE: 29-NOV-00 60817CN ELMER'S CHINA/GLASS CEMENT files/m60817cn.htm (7 of 7) [5/25/2006 8:59:19 AM] Page 231 of 871 Page 231 of 871 Page 231 of 871 Page 231 of 871 ---PAGE BREAK--- Page 232 of 871 Page 232 of 871 Page 232 of 871 Page 232 of 871 ---PAGE BREAK--- Page 233 of 871 Page 233 of 871 Page 233 of 871 Page 233 of 871 ---PAGE BREAK--- Page 234 of 871 Page 234 of 871 Page 234 of 871 Page 234 of 871 ---PAGE BREAK--- Page 235 of 871 Page 235 of 871 Page 235 of 871 Page 235 of 871 ---PAGE BREAK--- Page 236 of 871 Page 236 of 871 Page 236 of 871 Page 236 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 29-Jul-2014 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 83570 Product name Expunge Recommended Use Paint Remover Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Skin contact. Inhalation. Eyes. Potential health effects Eyes Exposure to vapors or mists may cause the following effects:. Irritation. Reddening. Burning sensation. Skin Repeated or prolonged exposure may cause:. Skin Irritation. Redness. Itching. Burning sensation. Inhalation Exposure to vapors may cause the following effects. Irritating to respiratory system. Headaches. Dizziness. Nausea. Loss of coordination. Extreme overexposure may cause. Central nervous system depression. Cardiac abnormalities. Liver damage. Reproductive system damage. Possible unconsciousness. Death. Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Ingestion May be harmful if swallowed. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Toluene 108-88-3 30-60 Propane 74-98-6 10-30 Diacetone alcohol 123-42-2 5-10 Butane 106-97-8 5-10 Isopropyl alcohol 67-63-0 1-5 Acetone 67-64-1 1-5 4. FIRST AID MEASURES Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek medical attention. Skin contact Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. Ingestion Do Not induce vomiting. Immediate medical attention is required. Inhalation Remove to fresh air. Restore breathing. Keep warm and quiet. 5. FIRE FIGHTING MEASURES Flash point °C < -17.78 Flash point °F < 0 Method No information available Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 12.8 Lower 1.0 Specific Information for Aerosol Products Flame extension 40" without extension tube Flashback Yes Suitable extinguishing media Carbon dioxide (CO2). Dry chemical. Alcohol foam. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fire and Explosion Hazards Containers may vent or burst under extreme or prolonged fire conditions. Flash back possible over considerable distance. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat . During emergency conditions, overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. Sensitivity to shock No information available. Sensitivity to static discharge Yes. Take precautionary measures against static discharges. Page 1 / 4 Emergency Overview Extremely flammable. Contents under pressure. Irritant. Page 237 of 871 Page 237 of 871 Page 237 of 871 Page 237 of 871 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Eliminate all sources of ignition. Ventilate area to maintain exposure below permissible exposure limits. Soak up with inert absorbent material. Dispose of absorbent in accordance with local, state and federal regulations. 7. HANDLING AND STORAGE Handling Keep away from open flames, hot surfaces and sources of ignition. Vapors may accumulate readily and may ignite explosively. Ensure adequate ventilation. Avoid breathing spray mist. Do not smoke. Turn off other sources of ignition prior to use and until all vapors have dissipated. Do not puncture or incinerate. Do not take internally. Keep out of reach of children. Check to make sure that all equipment is properly grounded and installed to satisfy electrical classification requirements. Standard safety precautions should be observed when handling this material. Storage Containers exposed to extreme heat may burst. Keep away from heat and sources of ignition. Store in temperatures below 120 degrees F (50 degrees C) . Keep away from direct sunlight. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Propane 1000 ppm 1800 mg/m3 - 1000 ppm - Butane 800 ppm - - 1000 ppm Toluene 200 ppm 300 ppm 20 ppm - Isopropyl alcohol 400 ppm 980 mg/m3 - 200 ppm 400 ppm Diacetone alcohol 50 ppm 240 mg/m3 - 50 ppm - Acetone 1000 ppm 2400 mg/m3 - 500 ppm 750 ppm Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Use in a well ventilated area. Consult OSHA standard 1910.94, 1910.107, 1910.108. Hygiene measures Wash hands before eating or using the washroom. Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes and clothing. Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Wear a NIOSH approved organic vapor/particulate respirator. Hand Protection Gloves are not required in normal use. The following gloves are recommended for prolonged or repeated contact: . Chemical resistant gloves. Eye protection Wear safety glasses with side shields. Skin and body protection None necessary under normal conditions Other Protective Equipment An eye wash station should be available. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Colorless Odor No information available Odor Threshold No information available pH 7.0 Specific Gravity 0.80 Vapor pressure No data available Density 6.65 lb/gal; 796 g/l Vapor density >Air Evaporation Rate >1 (Ether Water solubility No data available VOC Content 71.66% Partition Coefficient (n-octanol/water) No data available Boiling point/range °C < -18 - 172 Boiling point/range °F < 0 - 342 Melting point/range °C No data available Melting point/range °F No data available Flash point °C < -17.78 Flash point °F < 0 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid None known. Incompatability None known. Page 2 / 4 Product name Expunge Product code 83570 Page 238 of 871 Page 238 of 871 Page 238 of 871 Page 238 of 871 ---PAGE BREAK--- Hazardous Decomposition Products Carbon dioxide. Carbon monoxide. Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Propane 74-98-6 - - 658 mg/L Butane 106-97-8 - - 658 g/m3 Toluene 108-88-3 636 mg/kg 8390 mg/kg 12.5 mg/L Isopropyl alcohol 67-63-0 4396 mg/kg 12800 mg/kg 16000 ppm Diacetone alcohol 123-42-2 4 g/kg - - Acetone 67-64-1 - - 50100 mg/m3 Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity See Section 2 . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity Possible risk of harm to the unborn fetus. Target Organ Effects See Section 2. Reports have associated prolonged overexposure to solvents with permanent brain and nervous system damage. Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Propane Not Listed Not Listed Not Listed Not Listed Not Listed Butane Not Listed Not Listed Not Listed Not Listed Not Listed Toluene A4 Not Listed Not Listed Not Listed Not Listed Isopropyl alcohol A4 Not Listed Not Listed Not Listed Not Listed Diacetone alcohol Not Listed Not Listed Not Listed Not Listed Not Listed Acetone A4 Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Ecotoxicity effects No information available 13. DISPOSAL CONSIDERATIONS Disposal Information As supplied, this product is a RCRA Hazardous Waste . Waste must be tested for ignitability to determine EPA hazardous waste numbers. Do not puncture or incinerate. Depressurize before disposal. Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT UN1950 Aerosols, flammable, 2.1. Consumer commodity, ORM-D. This product meets the "Limited quantity" exemption TDG UN1950 AEROSOLS, flammable, 2.1 Consumer commodity, ORM-D. This product meets the "limited quantity" exemption 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Isopropyl alcohol Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Propane Listed Listed Not Listed Butane Listed Listed Not Listed Toluene Listed Listed Development al Female Reproductive Isopropyl alcohol Listed Listed Not Listed Diacetone alcohol Listed Listed Not Listed Page 3 / 4 Product name Expunge Microtox Data Photobacterium phosphoreum EC50=35390 mg/L (5 min) Microtox Data Photobacterium phosphoreum EC50=19.7 mg/L (30 min) Water Flea Data Daphnia magna EC50=13299 mg/L (48 h) Acetone Microtox Data Photobacterium phosphoreum EC50=14500 mg/L (15 min) Water Flea Data Daphnia magna EC505.46 - 9.83 mg/L (48 h) Daphnia magna EC50=11.5 mg/L (48 h) Water Flea Data Daphnia magna EC5010294 - 17704 mg/L (48 h) Daphnia magna EC5012600 - 12700 mg/L (48 h) Toluene Isopropyl alcohol Product code 83570 Page 239 of 871 Page 239 of 871 Page 239 of 871 Page 239 of 871 ---PAGE BREAK--- Chemical Name New Jersey - RTK - RTK California Prop. 65 Acetone Not Listed Listed Not Listed Chemical Name Type Toluene - 108-88-3 Female Reproductive WARNING: This product contains a chemical(s) known to the state of California to cause cancer and birth defects or other reproductive harm International Inventories Chemical Name EINECS DSL NDSL TSCA Propane X X - X Butane X X - X Toluene X X - X Isopropyl alcohol X X - X Diacetone alcohol X X - X Acetone X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION HMIS Health - 2 * Flammability - 3 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product name Expunge Product code 83570 Page 240 of 871 Page 240 of 871 Page 240 of 871 Page 240 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 03-Feb-2014 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 83570 Product name Expunge Recommended Use Paint Remover Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Skin contact. Inhalation. Eyes. Potential health effects Eyes Exposure to vapors or mists may cause the following effects:. Irritation. Reddening. Burning sensation. Skin Repeated or prolonged exposure may cause:. Skin Irritation. Redness. Itching. Burning sensation. Inhalation Exposure to vapors may cause the following effects. Irritating to respiratory system. Headaches. Dizziness. Nausea. Loss of coordination. Extreme overexposure may cause. Central nervous system depression. Cardiac abnormalities. Liver damage. Reproductive system damage. Possible unconsciousness. Death. Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Ingestion May be harmful if swallowed. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Toluene 108-88-3 30-60 Propane 74-98-6 10-30 Diacetone alcohol 123-42-2 5-10 Butane 106-97-8 5-10 Isopropyl alcohol 67-63-0 1-5 Acetone 67-64-1 1-5 4. FIRST AID MEASURES Eye contact Flush with plenty of water for at least 15 minutes. Seek medical attention. Skin contact Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. Seek medical attention if irritation persists. Ingestion Do Not induce vomiting. Call a physician or Poison Control Center immediately. Inhalation Remove to fresh air. Restore breathing. Keep warm and quiet. 5. FIRE FIGHTING MEASURES Flash point °C < -17.78 Flash point °F < 0 Method No information available Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 12.8 Lower 1.0 Specific Information for Aerosol Products Flame extension 40" without extension tube Flashback Yes Suitable extinguishing media Carbon dioxide (CO2). Dry chemical. Alcohol foam. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 1 / 4 Emergency Overview Extremely flammable. Contents under pressure. Irritant. Page 241 of 871 Page 241 of 871 Page 241 of 871 Page 241 of 871 ---PAGE BREAK--- Fire and Explosion Hazards Containers may vent or burst under extreme or prolonged fire conditions. Flash back possible over considerable distance. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat . During emergency conditions, overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. Sensitivity to shock No information available. Sensitivity to static discharge Yes. Take precautionary measures against static discharges. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Eliminate all sources of ignition. Ventilate area to maintain exposure below permissible exposure limits. Soak up with inert absorbent material. Dispose of absorbent in accordance with local, state and federal regulations. 7. HANDLING AND STORAGE Handling Keep away from open flames, hot surfaces and sources of ignition. Vapors may accumulate readily and may ignite explosively. Ensure adequate ventilation. Avoid breathing spray mist. Do not smoke. Turn off other sources of ignition prior to use and until all vapors have dissipated. Do not puncture or incinerate. Do not take internally. Keep out of reach of children. Check to make sure that all equipment is properly grounded and installed to satisfy electrical classification requirements. Standard safety precautions should be observed when handling this material. Storage Containers exposed to extreme heat may burst. Keep away from heat and sources of ignition. Store in temperatures below 120 degrees F (50 degrees C) . Keep away from direct sunlight. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Propane 1000 ppm 1800 mg/m3 - 1000 ppm - Butane 800 ppm - - 1000 ppm Toluene 200 ppm 300 ppm 20 ppm - Isopropyl alcohol 400 ppm 980 mg/m3 - 200 ppm 400 ppm Diacetone alcohol 50 ppm 240 mg/m3 - 50 ppm - Acetone 1000 ppm 2400 mg/m3 - 500 ppm 750 ppm Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Use in a well ventilated area. Hygiene measures Wash hands before eating or using the washroom. Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes and clothing. Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Wear a NIOSH approved organic vapor/particulate respirator. Hand Protection Gloves are not required in normal use. The following gloves are recommended for prolonged or repeated contact: . Chemical resistant gloves. Eye protection Wear safety glasses with side shields. Skin and body protection None necessary under normal conditions 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Colorless Odor No information available Odor Threshold No information available pH No data available Specific Gravity 0.80 Vapor pressure No data available Density 6.65 lb/gal; 796 g/l Vapor density >Air Evaporation Rate >1 (Ether Water solubility No data available VOC Content 71.70% Partition Coefficient (n-octanol/water) No data available Boiling point/range °C < -18 - 172 Boiling point/range °F < 0 - 342 Melting point/range °C No data available Melting point/range °F No data available Flash point °C < -17.78 Flash point °F < 0 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid None known. Incompatability None known. Hazardous Decomposition Products Carbon dioxide. Carbon monoxide. Page 2 / 4 Product code 83570 Product name Expunge Page 242 of 871 Page 242 of 871 Page 242 of 871 Page 242 of 871 ---PAGE BREAK--- Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Propane 74-98-6 - - 658 mg/L Butane 106-97-8 - - 658 g/m3 Toluene 108-88-3 636 mg/kg 8390 mg/kg 12.5 mg/L Isopropyl alcohol 67-63-0 4396 mg/kg 12800 mg/kg 16000 ppm Diacetone alcohol 123-42-2 4 g/kg - - Acetone 67-64-1 - - 50100 mg/m3 Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity See Section 2 . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity Possible risk of harm to the unborn fetus. Target Organ Effects See Section 2. Reports have associated prolonged overexposure to solvents with permanent brain and nervous system damage. Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Propane Not Listed Not Listed Not Listed Not Listed Not Listed Butane Not Listed Not Listed Not Listed Not Listed Not Listed Toluene A4 Not Listed Not Listed Not Listed Not Listed Isopropyl alcohol A4 Not Listed Not Listed Not Listed Not Listed Diacetone alcohol Not Listed Not Listed Not Listed Not Listed Not Listed Acetone A4 Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Aquatic toxicity Do not let product enter drains. Harmful to aquatic organisms 13. DISPOSAL CONSIDERATIONS Disposal Information As supplied, this product is a RCRA Hazardous Waste . Waste must be tested for ignitability to determine EPA hazardous waste numbers. Do not puncture or incinerate. Depressurize before disposal. Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT Consumer commodity, ORM-D. TDG Consumer commodity, ORM-D. 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Isopropyl alcohol Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Propane Listed Listed Not Listed Butane Listed Listed Not Listed Toluene Listed Listed Development al Female Reproductive Isopropyl alcohol Listed Listed Not Listed Diacetone alcohol Listed Listed Not Listed Acetone Not Listed Listed Not Listed Chemical Name Type Toluene - 108-88-3 Female Reproductive Page 3 / 4 Acetone Microtox Data Photobacterium phosphoreum EC50=14500 mg/L (15 min) Water Flea Data Daphnia magna EC505.46 - 9.83 mg/L (48 h) Daphnia magna EC50=11.5 mg/L (48 h) Water Flea Data Daphnia magna EC5010294 - 17704 mg/L (48 h) Daphnia magna EC5012600 - 12700 mg/L (48 h) Toluene Isopropyl alcohol Product name Expunge Microtox Data Photobacterium phosphoreum EC50=35390 mg/L (5 min) Microtox Data Photobacterium phosphoreum EC50=19.7 mg/L (30 min) Water Flea Data Daphnia magna EC50=13299 mg/L (48 h) Product code 83570 Page 243 of 871 Page 243 of 871 Page 243 of 871 Page 243 of 871 ---PAGE BREAK--- WARNING: This product contains a chemical(s) known to the state of California to cause cancer and birth defects or other reproductive harm International Inventories Chemical Name EINECS DSL NDSL TSCA Propane X X - X Butane X X - X Toluene X X - X Isopropyl alcohol X X - X Diacetone alcohol X X - X Acetone X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION HMIS Health - 2 Flammability - 3 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product code 83570 Product name Expunge Page 244 of 871 Page 244 of 871 Page 244 of 871 Page 244 of 871 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 120Z Expanding Foam Sealant Issue Date: 01/31/2008 Print Date: 01 Feb 2008 ®(TM)*Trademark of The Dow Chemical Company ("Dow") or an affiliated company of Dow Page 1 of 13 The Dow Chemical Company encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1. Product and Company Identification Product Name FILL AND SEAL (TM) 120Z Expanding Foam Sealant COMPANY IDENTIFICATION The Dow Chemical Company 2030 Willard H. Dow Center Midland, MI 48674 USA Customer Information Number: [PHONE REDACTED] EMERGENCY TELEPHONE NUMBER 24-Hour Emergency Contact: [PHONE REDACTED] Local Emergency Contact: [PHONE REDACTED] 2. Hazards Identification Emergency Overview Color: Yellow Physical State: Foam Odor: Mild Hazards of product: DANGER! Flammable gas - May cause flash fire. May cause allergic skin reaction. May cause allergic respiratory reaction. May cause eye irritation. May cause skin irritation. Vapor reduces oxygen available for breathing. May cause anesthetic effects. May cause respiratory tract irritation. Vapors may travel a long distance; ignition and/or flash back may occur. Evacuate area. Keep upwind of spill. Stay out of low areas. Aerosol cans exposed to fire can rupture becoming flaming projectiles. Elevated temperatures can cause hazardous polymerization. Toxic fumes may be released in fire situations. Containers are under high pressure. Avoid temperatures above 49 °C (120 OSHA Hazard Communication Standard Material Safety Data Sheet The Dow Chemical Company Page 245 of 871 Page 245 of 871 Page 245 of 871 Page 245 of 871 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 120Z Expanding Foam Sealant Issue Date: 01/31/2008 Page 2 of 13 This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Potential Health Effects Eye Contact: May cause eye irritation. May cause slight temporary corneal injury. Skin Contact: Prolonged contact may cause moderate skin irritation with local redness. Material may stick to skin causing irritation upon removal. May stain skin. Skin Absorption: Prolonged skin contact is unlikely to result in absorption of harmful amounts. Skin Sensitization: Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with isocyanates may play a role in respiratory sensitization. Inhalation: In confined or poorly ventilated areas, vapor can easily accumulate and can cause unconsciousness and death due to displacement of oxygen. Excessive exposure may cause irritation to upper respiratory tract (nose and throat) and lungs. May cause pulmonary edema (fluid in the lungs.) Effects may be delayed. May cause central nervous system depression. of excessive exposure may be anesthetic or narcotic effects; dizziness and drowsiness may be observed. Excessive exposure may increase sensitivity to epinephrine and increase myocardial irritability (irregular heartbeats). Decreased lung function has been associated with overexposure to isocyanates. Respiratory Sensitization: May cause allergic respiratory response. MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in individuals already sensitized. Asthma-like may include coughing, difficult breathing and a feeling of tightness in the chest. Occasionally, breathing difficulties may be life threatening. Ingestion: Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury. Observations in animals include: Gastrointestinal irritation. Effects of Repeated Exposure: Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after repeated excessive exposures to MDI/polymeric MDI aerosols. Contains component(s) which have been reported to cause effects on the following organs in animals: Kidney. Liver. Bone marrow. Contains a component which is reported to be a weak organophosphate-type cholinesterase inhibitor. Excessive exposure may produce organophosphate type cholinesterase inhibition. Signs and of excessive exposure may be headache, dizziness, incoordination, muscle twitching, tremors, nausea, abdominal cramps, diarrhea, sweating, pinpoint pupils, blurred vision, salivation, tearing, tightness in chest, excessive urination, convulsions. Cancer Information: Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory irritation and lung injury. Current exposure guidelines are expected to protect against these effects reported for MDI. Birth Defects/Developmental Effects: In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only at high doses which were toxic to the mother. Component CAS # Amount Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 10.0 - 30.0 % Isocyanic acid, polymethylenepolyphenylene ester, polymer with .alpha.,.alpha.',.alpha.''-1,2,3- propanetriyltris[.omega.-hydroxypoly 57029-46-6 30.0 - 60.0 % Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol coopolymer 53862-89-8 10.0 - 30.0 % Tris(1-chloro-2-propyl) phosphate 13674-84-5 5.0 - 10.0 % Paraffin waxes and Hydrocarbon waxes, chlorinated 63449-39-8 5.0 - 10.0 % Isobutane 75-28-5 5.0 - 10.0 % Methyl ether 115-10-6 1.0 - 5.0 % Propane 74-98-6 1.0 - 5.0 % 4,4' -Methylenediphenyl diisocyanate 101-68-8 5.0 - 10.0 % Note: CAS 101-68-8 is an MDI isomer that is part of CAS 9016-87-9. 3. Composition Information Page 246 of 871 Page 246 of 871 Page 246 of 871 Page 246 of 871 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 120Z Expanding Foam Sealant Issue Date: 01/31/2008 Page 3 of 13 4. First-aid measures Eye Contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5 minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist. Skin Contact: Remove material from skin immediately by washing with soap and plenty of water. Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists. Wash clothing before reuse. An MDI skin decontamination study demonstrated that cleaning very soon after exposure is important, and that a skin cleanser or corn oil may be more effective than soap and water. Discard items which cannot be decontaminated, including leather articles such as shoes, belts and watchbands. Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility. Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel. Notes to Physician: Maintain adequate ventilation and oxygenation of the patient. May cause asthma-like (reactive airways) Bronchodilators, expectorants, antitussives and corticosteroids may be of help. May cause respiratory sensitization or asthma-like Bronchodilators, expectorants and antitussives may be of help. Treat bronchospasm with inhaled beta2 agonist and oral or parenteral corticosteroids. Respiratory including pulmonary edema, may be delayed. Persons receiving significant exposure should be observed 24-48 hours for signs of respiratory distress. Exposure may increase "myocardial irritability". Do not administer sympathomimetic drugs such as epinephrine unless absolutely necessary. If you are sensitized to diisocyanates, consult your physician regarding working with other respiratory irritants or sensitizers. Although cholinesterase depression has been reported with this material, it is not of benefit in determining exposure and need not be considered in the treatment of persons exposed to the material. No specific antidote. Treatment of exposure should be directed at the control of and the clinical condition of the patient. Medical Conditions Aggravated by Exposure: Excessive exposure may aggravate preexisting asthma and other respiratory disorders (e.g. bronchitis, reactive airways dysfunction 5. Fire Fighting Measures Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Do not use direct water stream. Straight or direct water streams may not be effective to extinguish fire. Alcohol resistant foams (ATC type) are preferred. General purpose foams (including AFFF) or protein foams may function, but will be less effective. Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay upwind. Keep out of low areas where gases (fumes) can accumulate. Water may not be effective in extinguishing fire. Do not use direct water stream. May spread fire. Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Eliminate ignition sources. Move container from fire area if this is possible without hazard. Use water spray to cool fire- exposed containers and fire-affected zone until fire is out. Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer to the relevant sections. Unusual Fire and Explosion Hazards: Contains flammable propellant. Aerosol cans exposed to fire can rupture and become flaming projectiles. Propellant release may result in a fireball. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Dense smoke is produced when product burns. Page 247 of 871 Page 247 of 871 Page 247 of 871 Page 247 of 871 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 120Z Expanding Foam Sealant Issue Date: 01/31/2008 Page 4 of 13 Hazardous Combustion Products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Nitrogen oxides. Isocyanates. Hydrogen chloride. Carbon monoxide. Carbon dioxide. 6. Accidental Release Measures Steps to be Taken if Material is Released or Spilled: Contain spilled material if possible. Ground and bond all containers and handling equipment. Isolate area until gas has dispersed. Use non- sparking tools in cleanup operations. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Collect in suitable and properly labeled containers. Absorb with materials such as: Clay. Dirt. Milsorb®. Sand. Sawdust. Vermiculite. See Section 10 for more specific information. See Section 13, Disposal Considerations, for additional information. Personal Precautions: Evacuate area. Only trained and properly protected personnel must be involved in clean-up operations. Keep personnel out of low areas. Keep personnel out of confined or poorly ventilated areas. Keep upwind of spill. Ventilate area of leak or spill. No smoking in area. For large spills, warn public of downwind explosion hazard. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Vapor explosion hazard. Keep out of sewers. See Section 10 for more specific information. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection. Refer to Section 7, Handling, for additional precautionary measures. Environmental Precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. 7. Handling and Storage Handling General Handling: Keep away from heat, sparks and flame. Avoid contact with eyes. Avoid contact with skin and clothing. Avoid prolonged or repeated contact with skin. Avoid breathing vapor. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. Keep out of reach of children. No smoking, open flames or sources of ignition in handling and storage area. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Contents under pressure. Do not puncture or incinerate container. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers. Do not enter confined spaces unless adequately ventilated. Never use air pressure for transferring product. Use of non-sparking or explosion-proof equipment may be necessary, depending upon the type of operation. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION. Storage Minimize sources of ignition, such as static build-up, heat, spark or flame. Store in a dry place. See Section 10 for more specific information. Shelf life: Use within 12 Months 20 - 30 °C 8. Exposure Controls / Personal Protection Exposure Limits Component List Type Value I 4,4' -Methylenediphenyl diisocyanate ACGIH TWA 0.005 ppm Page 248 of 871 Page 248 of 871 Page 248 of 871 Page 248 of 871 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 120Z Expanding Foam Sealant Issue Date: 01/31/2008 Page 5 of 13 OSHA Table Z-1 Ceiling 0.2 mg/m3 0.02 ppm I Methyl ether WEEL TWA 1,880 mg/m3 1,000 ppm I Isobutane ACGIH TWA 1,000 ppm I Propane OSHA Table Z-1 PEL 1,800 mg/m3 1,000 ppm ACGIH TWA 1,000 ppm I Personal Protection Eye/Face Protection: Use safety glasses. Eye wash fountain should be located in immediate work area. Skin Protection: Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task. Remove contaminated clothing immediately, wash skin area with soap and water, and launder clothing before reuse or dispose of properly. Items which cannot be decontaminated, such as shoes, belts and watchbands, should be removed and disposed of properly. Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove barrier materials include: Butyl rubber. Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Examples of acceptable glove barrier materials include: Natural rubber ("latex"). Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Viton. Polyvinyl chloride ("PVC" or "vinyl"). NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier. Respiratory Protection: Atmospheric levels should be maintained below the exposure guideline. When atmospheric levels may exceed the exposure guideline, use an approved air-purifying respirator equipped with an organic vapor sorbent and a particle filter. For situations where the atmospheric levels may exceed the level for which an air-purifying respirator is effective, use a positive-pressure air-supplying respirator (air line or self-contained breathing apparatus). For emergency response or for situations where the atmospheric level is unknown, use an approved positive-pressure self- contained breathing apparatus or positive-pressure air line with auxiliary self-contained air supply. The following should be effective types of air-purifying respirators: Organic vapor cartridge with a particulate pre-filter. Ingestion: Use good personal hygiene. Do not consume or store food in the work area. Wash hands before smoking or eating. Engineering Controls Ventilation: Use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations. Provide general and/or local exhaust ventilation to control airborne levels below the exposure guidelines. Exhaust systems should be designed to move the air away from the source of vapor/aerosol generation and people working at this point. The odor and irritancy of this material are inadequate to warn of excessive exposure. 9. Physical and Chemical Properties Physical State Foam Color Yellow Odor Mild Flash Point - Closed Cup -104 °C (-155 Estimated Flammable Limits In Air Lower: No test data available Upper: No test data available Autoignition Temperature No test data available Vapor Pressure 1,151 kPa @ 55 °C Calculated Boiling Point (760 mmHg) Not applicable. Vapor Density (air = 1) No test data available Specific Gravity (H2O = 1) 1.06 Estimated Page 249 of 871 Page 249 of 871 Page 249 of 871 Page 249 of 871 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 120Z Expanding Foam Sealant Issue Date: 01/31/2008 Page 6 of 13 Freezing Point No test data available Melting Point No test data available Solubility in Water (by weight) Insoluble pH Not applicable Kinematic Viscosity Not applicable 10. Stability and Reactivity Stability/Instability Stable under recommended storage conditions. See Storage, Section 7. Unstable at elevated temperatures. Conditions to Avoid: Avoid temperatures above 49 °C (120 Elevated temperatures can cause container to vent and/or rupture. Exposure to elevated temperatures can cause product to decompose. Incompatible Materials: Avoid contact with: Acids. Alcohols. Amines. Ammonia. Bases. Metal compounds. Strong oxidizers. Products based on diisocyanates like TDI and MDI react with many materials to release heat. The reaction rate increases with temperature as well as with increased contact; these reactions can become violent. Contact is increased by stirring or if the other material acts as a solvent. Products based on diisocyanates such as TDI and MDI are not soluble in water and will sink to the bottom, but react slowly at the interface. The reaction forms carbon dioxide gas and a layer of solid polyurea. Reaction with water will generate carbon dioxide and heat. Hazardous Polymerization Can occur. Elevated temperatures can cause hazardous polymerization. Thermal Decomposition Decomposition products depend upon temperature, air supply and the presence of other materials. Toxic gases are released during decomposition. 11. Toxicological Information Acute Toxicity Ingestion Single dose oral LD50 has not been determined. Estimated LD50, Rat > 10,000 mg/kg Skin Absorption The LD50 has not been determined. Estimated LD50, Rabbit > 2,000 mg/kg Inhalation The LC50 has not been determined. Estimated LC50, Aerosol, Rat > 0.5 mg/l Sensitization Skin Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with isocyanates may play a role in respiratory sensitization. Respiratory May cause allergic respiratory response. MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in individuals already sensitized. Asthma-like may include coughing, difficult breathing and a feeling of tightness in the chest. Occasionally, breathing difficulties may be life threatening. Repeated Dose Toxicity Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after repeated excessive exposures to MDI/polymeric MDI aerosols. Contains component(s) which have been reported to cause effects on the following organs in animals: Kidney. Liver. Bone marrow. Contains a component which is reported to be a weak organophosphate-type cholinesterase inhibitor. Excessive exposure may produce organophosphate type cholinesterase inhibition. Signs and of excessive exposure may be headache, dizziness, incoordination, muscle twitching, Page 250 of 871 Page 250 of 871 Page 250 of 871 Page 250 of 871 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 120Z Expanding Foam Sealant Issue Date: 01/31/2008 Page 7 of 13 tremors, nausea, abdominal cramps, diarrhea, sweating, pinpoint pupils, blurred vision, salivation, tearing, tightness in chest, excessive urination, convulsions. Chronic Toxicity and Carcinogenicity Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory irritation and lung injury. Current exposure guidelines are expected to protect against these effects reported for MDI. Developmental Toxicity In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only at high doses which were toxic to the mother. Genetic Toxicology In vitro genetic toxicity studies were negative for component(s) tested. Genetic toxicity data on MDI are inconclusive. MDI was weakly positive in some in vitro studies; other in vitro studies were negative. Animal mutagenicity studies were predominantly negative. 12. Ecological Information CHEMICAL FATE Data for Component: Diphenylmethane Diisocyanate, isomers and homologues Movement & Partitioning In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Persistence and Degradability In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. Data for Component: Isocyanic acid, polymethylenepolyphenylene ester, polymer with .alpha.,.alpha.',.alpha.''-1,2,3-propanetriyltris[.omega.-hydroxypoly Movement & Partitioning In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Persistence and Degradability In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. Data for Component: Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol coopolymer Movement & Partitioning In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Persistence and Degradability In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. Data for Component: Tris(1-chloro-2-propyl) phosphate Movement & Partitioning Bioconcentration potential is low (BCF < 100 or Log Pow < Potential for mobility in soil is low (Koc between 500 and 2000). Page 251 of 871 Page 251 of 871 Page 251 of 871 Page 251 of 871 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 120Z Expanding Foam Sealant Issue Date: 01/31/2008 Page 8 of 13 Henry's Law Constant < 1.35E-5 atm*m3/mole; 25 °C Estimated Partition coefficient, n-octanol/water (log Pow): 2.59 Measured Partition coefficient, soil organic carbon/water (Koc): 1,300 Estimated Bioconcentration Factor (BCF): 0.8 - 4.6; common carp (Cyprinus carpio); Measured Persistence and Degradability Material is expected to biodegrade only very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 4.47E-11 cm3/s 0.24 d Estimated OECD Biodegradation Tests: Biodegradation Exposure Time Method 14 % 28 d OECD 301E Test Theoretical Oxygen Demand: 1.17 mg/mg Data for Component: Paraffin waxes and Hydrocarbon waxes, chlorinated Movement & Partitioning Expected to be relatively immobile in soil (Koc > 5000). Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected to be an important fate process. Henry's Law Constant < 1.0E-07 atm*m3/mole; 25 °C Estimated Partition coefficient, n-octanol/water (log Pow): > 6 Estimated Persistence and Degradability Expected to degrade only slowly in the environment. Data for Component: Isobutane Movement & Partitioning Bioconcentration potential is low (BCF less than 100 or log Pow less than Potential for mobility in soil is very high (Koc between 0 and 50). Henry's Law Constant 1.19E+00 atm*m3/mole; 25 °C Measured Partition coefficient, n-octanol/water (log Pow): 2.76 Measured Partition coefficient, soil organic carbon/water (Koc): 35 Estimated Distribution in Environment: Mackay Level 1 Fugacity Model: Air Water. Biota Soil Sediment 100 % 0 % 0 % 0 % 0 % Persistence and Degradability Biodegradation may occur under aerobic conditions (in the presence of oxygen). Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 2.44E-12 cm3/s 4.4 d Estimated Theoretical Oxygen Demand: 3.58 mg/mg Data for Component: Methyl ether Movement & Partitioning Bioconcentration potential is low (BCF less than 100 or log Pow less than Potential for mobility in soil is very high (Koc between 0 and 50). Henry's Law Constant 9.78E-4 atm*m3/mole; 25 °C Measured Partition coefficient, n-octanol/water (log Pow): 0.10 Measured Partition coefficient, soil organic carbon/water (Koc): 1.29 - 14 Estimated Persistence and Degradability Material is expected to biodegrade only very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 1.66E-12 cm3/s 6.4 d Estimated OECD Biodegradation Tests: Page 252 of 871 Page 252 of 871 Page 252 of 871 Page 252 of 871 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 120Z Expanding Foam Sealant Issue Date: 01/31/2008 Page 9 of 13 Biodegradation Exposure Time Method 5 % 28 d OECD 301A Test Theoretical Oxygen Demand: 2.08 mg/mg Data for Component: Propane Movement & Partitioning Bioconcentration potential is low (BCF less than 100 or log Pow less than Potential for mobility in soil is very high (Koc between 0 and 50). Henry's Law Constant 7.07E-01 atm*m3/mole; 25 °C Measured Partition coefficient, n-octanol/water (log Pow): 2.36 Measured Partition coefficient, soil organic carbon/water (Koc): 24 - 460 Estimated Distribution in Environment: Mackay Level 1 Fugacity Model: Air Water. Biota Soil Sediment 100 % 0 % 0 % 0 % 0 % Persistence and Degradability No relevant information found. Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 1.27E-12 cm3/s 8.4 d Estimated Theoretical Oxygen Demand: 3.64 mg/mg Data for Component: 4,4' -Methylenediphenyl diisocyanate Movement & Partitioning In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Persistence and Degradability In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. ECOTOXICITY Data for Component: Diphenylmethane Diisocyanate, isomers and homologues The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Toxicity to Soil Dwelling Organisms LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg Data for Component: Isocyanic acid, polymethylenepolyphenylene ester, polymer with .alpha.,.alpha.',.alpha.''-1,2,3-propanetriyltris[.omega.-hydroxypoly The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Toxicity to Soil Dwelling Organisms LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg Data for Component: Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol coopolymer The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Toxicity to Soil Dwelling Organisms LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg Data for Component: Tris(1-chloro-2-propyl) phosphate Material is toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and 100 mg/L in the most sensitive species tested). Page 253 of 871 Page 253 of 871 Page 253 of 871 Page 253 of 871 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 120Z Expanding Foam Sealant Issue Date: 01/31/2008 Page 10 of 13 Fish Acute & Prolonged Toxicity LC50, bluegill (Lepomis macrochirus), 96 h: 84 mg/l Aquatic Invertebrate Acute Toxicity EC50, water flea Daphnia magna, 48 h, immobilization: 63 mg/l Aquatic Plant Toxicity EC50, green alga Selenastrum capricornutum, biomass growth inhibition, 96 h: 47 mg/l EC50, alga Scenedesmus sp., biomass growth inhibition, 72 h: 45 mg/l Toxicity to Micro-organisms EC50, OECD 209 Test; activated sludge, respiration inhibition, 3 h: 784 mg/l Data for Component: Paraffin waxes and Hydrocarbon waxes, chlorinated Material is practically non-toxic to fish on an acute basis (LC50 > 100 mg/L). Material is very highly toxic to aquatic invertebrates on an acute basis (LC50/EC50 < 0.1 mg/L). Fish Acute & Prolonged Toxicity LC50, rainbow trout mykiss), static, 96 h: > 100 mg/l Aquatic Invertebrate Acute Toxicity EC50, water flea Daphnia magna, immobilization: 0.037 mg/l Data for Component: Isobutane No relevant information found. Data for Component: Methyl ether Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Fish Acute & Prolonged Toxicity LC50, guppy (Poecilia reticulata), 96 h: > 4,000 mg/l Aquatic Invertebrate Acute Toxicity LC50, water flea Daphnia magna, 48 h: > 4,000 mg/l Data for Component: Propane No relevant information found. Data for Component: 4,4' -Methylenediphenyl diisocyanate The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Toxicity to Soil Dwelling Organisms LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg 13. Disposal Considerations DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. DOW HAS NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed, permitted: Incinerator or other thermal destruction device. As a service to its customers, Dow can provide names of information resources to help identify waste management companies and other facilities which recycle, reprocess or manage chemicals or plastics, and that manage used drums. Telephone Dow's Customer Information Group at 1-[PHONE REDACTED] or 1-989- 832-1556 or 1-[PHONE REDACTED] (Canada) for further details. Page 254 of 871 Page 254 of 871 Page 254 of 871 Page 254 of 871 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 120Z Expanding Foam Sealant Issue Date: 01/31/2008 Page 11 of 13 14. Transport Information DOT Non-Bulk CONSUMER COMMODITY RECLASSIFIED AS ORM-D MATERIAL DOT Bulk NOT AVAILABLE IN BULK CONTAINERS IMDG Proper Shipping Name: AEROSOLS, FLAMMABLE Hazard Class: 2.1 ID Number: UN1950 EMS Number: F-D,S-U LIMITED QUANTITY ICAO/IATA Proper Shipping Name: AEROSOLS, FLAMMABLE Hazard Class: 2.1 ID Number: UN1950Cargo Packing Instruction: 203 Passenger Packing Instruction: 203 LIMITED QUANTITY This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Additional transportation system information can be obtained through an authorized sales or customer service representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material. 15. Regulatory Information OSHA Hazard Communication Standard This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Sections 311 and 312 Immediate (Acute) Health Hazard Yes Delayed (Chronic) Health Hazard Yes Fire Hazard Yes Reactive Hazard No Sudden Release of Pressure Hazard Yes Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Section 313 This product contains the following substances which are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and which are listed in 40 CFR 372. Component CAS # Amount 4,4' -Methylenediphenyl diisocyanate 101-68-8 5.0 - 10.0 % Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 10.0 - 30.0 % (Worker and Community Right-To-Know Act): Hazardous Substances List and/or Environmental Hazardous Substance List: The following product components are cited in the Hazardous Substance List and/or the Environmental Substance List, and are present at levels which require reporting. Page 255 of 871 Page 255 of 871 Page 255 of 871 Page 255 of 871 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 120Z Expanding Foam Sealant Issue Date: 01/31/2008 Page 12 of 13 Component CAS # Amount 4,4' -Methylenediphenyl diisocyanate 101-68-8 5.0 - 10.0 % Methyl ether 115-10-6 1.0 - 5.0 % Propane 74-98-6 1.0 - 5.0 % Isobutane 75-28-5 5.0 - 10.0 % (Worker and Community Right-To-Know Act): Special Hazardous Substances List: To the best of our knowledge, this product does not contain chemicals at levels which require reporting under this statute. California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986) This product contains no listed substances known to the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute. US. Toxic Substances Control Act All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.30 CEPA - Domestic Substances List (DSL) All substances contained in this product are listed on the Canadian Domestic Substances List (DSL) or are not required to be listed. 16. Other Information Recommended Uses and Restrictions Polyurethane foam. Revision Identification Number: 63952 / 0000 / Issue Date 01/31/2008 / Version: 2.0 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. Legend N/A Not available W/W Weight/Weight OEL Occupational Exposure Limit STEL Short Term Exposure Limit TWA Time Weighted Average ACGIH American Conference of Governmental Industrial Hygienists, Inc. DOW IHG Dow Industrial Hygiene Guideline WEEL Workplace Environmental Exposure Level HAZ_DES Hazard Designation Action Level A value set by OSHA that is lower than the PEL which will trigger the need for activities such as exposure monitoring and medical surveillance if exceeded. The Dow Chemical Company urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have Page 256 of 871 Page 256 of 871 Page 256 of 871 Page 256 of 871 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 120Z Expanding Foam Sealant Issue Date: 01/31/2008 Page 13 of 13 obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version. Page 257 of 871 Page 257 of 871 Page 257 of 871 Page 257 of 871 ---PAGE BREAK--- Page 258 of 871 Page 258 of 871 Page 258 of 871 Page 258 of 871 ---PAGE BREAK--- Page 259 of 871 Page 259 of 871 Page 259 of 871 Page 259 of 871 ---PAGE BREAK--- Page 260 of 871 Page 260 of 871 Page 260 of 871 Page 260 of 871 ---PAGE BREAK--- Page 261 of 871 Page 261 of 871 Page 261 of 871 Page 261 of 871 ---PAGE BREAK--- Page 262 of 871 Page 262 of 871 Page 262 of 871 Page 262 of 871 ---PAGE BREAK--- Page 263 of 871 Page 263 of 871 Page 263 of 871 Page 263 of 871 ---PAGE BREAK--- Page 264 of 871 Page 264 of 871 Page 264 of 871 Page 264 of 871 ---PAGE BREAK--- Page 265 of 871 Page 265 of 871 Page 265 of 871 Page 265 of 871 ---PAGE BREAK--- Page 266 of 871 Page 266 of 871 Page 266 of 871 Page 266 of 871 ---PAGE BREAK--- Page 267 of 871 Page 267 of 871 Page 267 of 871 Page 267 of 871 ---PAGE BREAK--- Page 268 of 871 Page 268 of 871 Page 268 of 871 Page 268 of 871 ---PAGE BREAK--- Page 1 of 4 Print Date 10/31/2003 MSDS Document Product Flush-Off Spray Orange Degreaser 1. Chemical Product and Company Identification Trade Name of this Product Flush-Off Spray Orange Degreaser MSDS ID 95660 Manufacturer Lawson Products, Inc. 1666 East Touhy Avenue Des Plaines, IL 60018 Contact Name Corporate Compliance Team Phone Number (847) 827-9666 Emergency Phone (888) 426-4851 Revision Date 10/07/2003 0 0 0 Health: Fire: Reactivity: Specific Health: Fire: Reactivity: Specific 1 3 0 2. Composition and Information on Ingredients Ingredient CAS Number Weight % ACGIH TLV PEL STEL Propellant: CO2 124-38-9 <5.0 % 3. Hazard Identification Effects Of Overexposure Irritates eyes. Prolonged or repeated contact may irritate skin. Nose and throat irritant. Irritancy Of Product Moderate eye irritant. Medical Conditions Aggravated By Exposure May cause dermatitis on prolonged contact in sensitive individuals. May be harmful or fatal if swallowed. Route Of Entry Ingestion Eyes Skin Page 269 of 871 Page 269 of 871 Page 269 of 871 Page 269 of 871 ---PAGE BREAK--- Page 2 of 4 Print Date 10/31/2003 MSDS ID 95660 Flush-Off Spray Orange Degreaser Synergistic Products N/A Target Organs Affected Vapors: Irritating to eyes and respiratory tract. Direct Contact: Irritating to skin and eyes. 4. First Aid Information First Aid Procedures Ingestion: Do not induce vomiting. CALL a physician. Skin and Eyes: Flush with water. 5. Fire Fighting Measures Flash Point 122 FP Method Clev Closed Cup Extinguishing Media Foam Carbon Dioxide Dry Chemical 6. Accidental Release Measures Material Release Or Spill Use absorbent material to collect and contain for salvage or disposal. 7. Handling and Storage Handling Precautions N/A Storage Store in a cool, dry place away from heat and open flame. Keep out of reach of children Other Precautions Wash with soap and water immediately after use. Handling Precautions And Equipment Read and follow contents on product label. Do not store in temperatures above 120 F. Hygienic Practices Wash hands before eating or using the washroom. Smoke in SMOKING AREAS ONLY. 8. Exposure Controls and Personal Protection Other Protective Equipment Eye wash station and safety showers should be available. Eye Protection Use safety eyewear designed to protect against splash of liquids. Page 270 of 871 Page 270 of 871 Page 270 of 871 Page 270 of 871 ---PAGE BREAK--- Page 3 of 4 Print Date 10/31/2003 MSDS ID 95660 Flush-Off Spray Orange Degreaser Clothing Impermeable clothing should be used to prevent excessive skin contact. Other PPE N/A Protective Gloves Required for prolonged or repeated contact. Ventilation If current ventilation practices are not adequate in maintaining airborne concentrations below the established exposure limits, additional ventilation or exhaust systems may be required. Respiratory Protection Avoid breathing concentrated vapors or particles from all products not specifically designed to be inhaled. 9. Physical and Chemical Properties Physical State Liquid Specific Gravity 0.84 pH N/A Boiling/Cond. Point 352.0 Percent Volatile 99.0 Odor And Appearance Mild odor, white color. 10. Stability and Reactivity Incompatibility Avoid contact with strong oxidizing agents. Extended exposure to high temperatures may cause decomposition. Conditions To Avoid Sunlight, open flame & contamination. Hazardous Decomposition Products By open flame: CARBON MONOXIDE, CARBON DIOXIDE. Hazardous Polymerization Will not occur. 11. Toxicological Information Carcinogenicity None of the components in this chemical are listed by IARC, NTP or OSHA as a carcinogen. Page 271 of 871 Page 271 of 871 Page 271 of 871 Page 271 of 871 ---PAGE BREAK--- Page 4 of 4 Print Date 10/31/2003 MSDS ID 95660 Flush-Off Spray Orange Degreaser 12. Ecological Information Ecological Information No information available. 13. Disposal Considerations Waste Disposal Method Dispose of product in accordance with local, county, state, and federal regulations. Do not puncture or incinerate container. Do not reuse container. Wrap container and place in trash collection. 14. Transportation Information OSHA CLASS N/A PER DOT N/A DOT Class N/A PER IMCO N/A IMCO Classification Number N/A IATA Classification Number N/A 15. Regulatory Information CPR Certification This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. Other Information Other Precautions No information available. Page 272 of 871 Page 272 of 871 Page 272 of 871 Page 272 of 871 ---PAGE BREAK--- Material Safety Data Sheet Date of issue 07/18/08 Product name FOAMING AC COIL CLEANER Product code R063 Supersedes Product use Aerosol Cleaner. Emergency Telephone Numbers For MSDS Information: Compliance Services 1-[PHONE REDACTED] For Medical Emergency INFOTRAC: (877) 541-2016 Toll Free - All Calls Recorded For Transportation Emergency CHEMTREC: (800) 424-9300 - All Calls Recorded In the District of Columbia (202) 483-7616 Prepared By Compliance Services 1420 Seaboard Industrial Blvd. Atlanta, GA 30318 Section 1. Chemical Product and Company Identification Zep Inc. 1310 Seaboard Industrial Blvd. Atlanta, GA 30318 1-[PHONE REDACTED] Emergency overview WARNING CAUSES EYE IRRITATION. CONTENTS UNDER PRESSURE. *Hazard Determination System (HDS): Health, Flammability, Reactivity Acute Effects Eyes Skin Inhalation Ingestion Routes of Entry Eye contact. Contact may cause eye irritation. Inflammation of the eye is characterized by redness, watering and itching. Prolonged or repeated contact may dry skin and cause irritation. Skin inflammation is characterized by itching, scaling, or reddening. Over-exposure by inhalation may cause respiratory irritation. Adverse health effects are considered unlikely when the product is administered according to the label instructions. NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse effects are lessened by following all prescribed safety precautions, including the use of proper personal protective equipment. Carcinogenicity Chronic effects There is no known chronic effect after exposure to this product. Additional Information: See Toxicological Information (Section 11) Section 2. Hazards Identification 1 0 0 Name of Hazardous Ingredients CAS number % by Weight DIPROPYLENE GLYCOL N-PROPYL ETHER; 2-propanol, 1-(1-methyl-2-propoxyethoxy) 29911-27-1 1 - 10 HYDROCARBON PROPELLANT; blend of propane & isobutane 75-28-5; 74-98-6 <5 Section 3. Composition/Information on Ingredients Eye Contact Skin Contact Inhalation Ingestion Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Check for and remove any contact lenses. Get medical attention. In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. If irritation persists, get medical attention. If inhaled, remove to fresh air. If irritation persists, get medical attention. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If affected person is conscious, give plenty of water to drink. Get medical attention immediately. Section 4. First Aid Measures Page: 1/3 Page 273 of 871 Page 273 of 871 Page 273 of 871 Page 273 of 871 ---PAGE BREAK--- Material Safety Data Sheet Product Name FOAMING AC COIL CLEANER Product code R063 None. Flash Point Not applicable National Fire Protection Association 1 0 0 Flammable Limits Flammability Fire hazard CONTENTS UNDER PRESSURE. In a fire or if heated, a pressure increase will occur and the container may burst. Bursting aerosol containers may be propelled from a fire at high speed. Non-flammable. (CSMA Method) Fire-Fighting Procedures Cool containers with water jet in order to prevent pressure build-up, auto-ignition or explosion. Do not release runoff from fire to sewers or waterways. Section 5. Fire Fighting Measures Spill Clean up Unlikely in this form. Section 6. Accidental Release Measures Handling Storage Put on appropriate personal protective equipment (see section Avoid contact with eyes. Avoid breathing vapors, spray or mists. Use only with adequate ventilation. Do not ingest. Wash thoroughly after handling. Observe label precautions. CONTENTS UNDER PRESSURE. Store and use away from heat, sparks, open flame or any other ignition source. Do not puncture or incinerate container. Keep away from food, drink and animal feeding stuffs. Keep out of the reach of children. Store below 120°F (49°C). Section 7. Handling and Storage Personal Protective Equipment (PPE) Eyes Body Respiratory Product name Exposure limits HYDROCARBON PROPELLANT; blend of propane & isobutane ACGIH TLV / OSHA PEL (United States). Notes: Propane TWA: 1000 ppm 8 hour(s). Safety glasses. For prolonged or repeated handling, use the following type of gloves: Rubber gloves. Nitrile gloves. Neoprene gloves. Use with adequate ventilation. A respirator is not needed under normal and intended conditions of product use. Section 8. Exposure Controls/Personal Protection Physical State pH Boiling Point Specific Gravity Solubility Liquid. [Aerosol.] Not applicable 100°C (212°F) 1.017 Color Odor Vapor Pressure Vapor Density Evaporation Rate VOC (Consumer) Clear. Colorless. Citrus Not determined. Not determined. 1 (Water = 1) 4.9% 0.41 (lb/gal) 50 Soluble in water Section 9. Physical and Chemical Properties The product is stable. Will not occur. Stability and Reactivity Hazardous Decomposition Products Hazardous Polymerization reactive or incompatible with the following materials: acids and oxidizing agents. Incompatibility carbon oxides and organic chemicals. Section 10. Stability and Reactivity Acute Toxicity Product/ingredient name Result Species Dose Exposure Dipropylene Glycol N-propyl Ether LD50 Dermal Rabbit >2000 mg/kg - LD50 Oral Rat >2000 mg/kg - LD50 Oral Rat >1500 mg/kg - Section 11. Toxicological Information Page: 2/3 Page 274 of 871 Page 274 of 871 Page 274 of 871 Page 274 of 871 ---PAGE BREAK--- Material Safety Data Sheet Product Name FOAMING AC COIL CLEANER Product code R063 Environmental Effects No applicable toxicity data Aquatic Ecotoxicity Not available. Section 12. Ecological Information Waste Information Waste Stream Non-regulated waste Section 13. Disposal Considerations Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or regional authorities for additional information. NOTE: DOT classification applies to most package sizes. For specific container size classifications or for size exceptions, refer to the Bill of Lading with your shipment. PG* : Packing group Regulatory information UN number Proper shipping name Classes PG* Label Consumer commodity ORM-D - Not determined. AEROSOLS (Propellant; Blend of Isobutane, Propane and n-Butane) 2.2 - 2 Section 14. Transport Information DOT Classification IMDG Class None. U.S. Federal Regulations Clean Water Act (CWA) 311: No products were found. Clean Air Act (CAA) 112 regulated toxic substances: No products were found. State Regulations No products were found. California Prop 65 All Components of this product are listed or exempt from listing on TSCA Inventory. Section 15. Regulatory Information Clean Water Act (CWA) 307: No products were found. No products were found. SARA 313 toxic chemical notification and release reporting: To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. *NOTE: Hazard Determination System (HDS) ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although these ratings are not required on under 29 CFR 1910.1200, the preparer may choose to provide them. HDS ratings are to be used with a fully implemented program to relay the meanings of this scale. Section 16. Other Information Page 275 of 871 Page 275 of 871 Page 275 of 871 Page 275 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 14-Mar-2014 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 97936 Product name Foamy Orange Citrus Degreaser Recommended Use Degreaser Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Eyes. Ingestion. Inhalation. Skin contact. Potential health effects Eyes Exposure to vapors or mists may cause the following effects:. Irritation. Pain. Tearing. Reddening. Swelling. Stinging sensation. Feeling like that of fine dust in the eye. Skin Repeated or prolonged exposure may cause:. Defatting. Skin Irritation. Dermatitis. Inhalation Long-term exposure may cause the following effects:. Headaches. Dizziness. Nausea. Decreased blood pressure. Changes in heart rate. Cyanosis. Harmful by inhalation. Ingestion Harmful or fatal if swallowed. Corrosive. If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach. Extreme overexposure may cause. Kidney damage. Liver abnormalities. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Propane/Isobutane/N- Butane 68476-86-8 10-30 D-Limonene 5989-27-5 7-13 Isopropyl Alcohol 67-63-0 3-7 4. FIRST AID MEASURES Eye contact Flush eyes with plenty of water. Seek medical attention if irritation persists. Skin contact Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. Seek medical attention if irritation persists. Ingestion Seek medical attention immediately. Do Not induce vomiting. Give victim a glass of milk. Call a physician or Poison Control Center immediately. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Immediate medical attention is required. 5. FIRE FIGHTING MEASURES Flash point °C -104 Flash point °F -156 Method Pensky-Martens C.C. Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 12.0% Lower 0.7% Suitable extinguishing media Alcohol foam. Carbon dioxide (CO2). Dry chemical. Foam. Water fog. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fire and Explosion Hazards Flash back possible over considerable distance. Empty containers contain residue and/or vapors. Do not weld, cut, pressurize, braze, solder, drill, grind, or expose such containers to heat, sparks, flame, static electricity, or other sources of ignition. They may explode and cause injury or death. Page 1 / 4 Emergency Overview Vapors irritating to eyes and respiratory tract. Vapors may cause flash fire or explosion. Page 276 of 871 Page 276 of 871 Page 276 of 871 Page 276 of 871 ---PAGE BREAK--- Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Place in suitable container for disposal as hazardous waste. 7. HANDLING AND STORAGE Handling Thoroughly wash hands and exposed skin after handling. Remove and wash contaminated clothing before re-use. Ensure adequate ventilation. Use only according to label directions. Empty containers are very hazardous . Containers can contain explosive vapors or residues. Avoid breathing vapors from heated material . Avoid contact with skin, eyes and clothing. Storage Containers exposed to extreme heat may burst. Keep away from heat and sources of ignition. Do not freeze. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) D-Limonene - - - - Propane/Isob utane/N- Butane - - - N/D Isopropyl Alcohol 400 ppm 980 mg/m3 - 200 ppm 400 ppm Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Use in a well ventilated area. Hygiene measures Wash hands before eating or using the washroom. Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes and clothing. Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Protection provided by air purifying respirators is limited. Use a positive pressure supplied air respirator. if there is any potential for an uncontrolled release:. where exposure levels are not known. or other circumstances where an air purifying respirator (P100) may not provide adequate protection . Hand Protection Chemical resistant gloves. Eye protection Use safety eyewear designed to protect against impact. Skin and body protection Lightweight protective clothing. Rubber or plastic boots. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Orange Odor Pleasant Odor Threshold No information available pH 9 Specific Gravity 0.9172 Vapor pressure 40-50 Vapor density >Air Evaporation Rate >1 (Butyl Acetate = 1) Water solubility Soluble in water VOC Content 20.6%; 1.57 lbs/gal, 189 grams/ltr Partition Coefficient (n-octanol/water) Not Applicable Boiling point/range °C -41 - 162 Boiling point/range °F -43 - 325 Melting point/range °C < 0 Melting point/range °F < 32 Flash point °C -104 Flash point °F -156 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions. Conditions to avoid Avoid sources of ignition. Avoid open flames. Do not use near welding arcs. Incompatability Strong acids. Alkalies. Oxidizers. Amines. Page 2 / 4 Product name Foamy Orange Citrus Degreaser Product code 97936 Page 277 of 871 Page 277 of 871 Page 277 of 871 Page 277 of 871 ---PAGE BREAK--- Hazardous Decomposition Products Carbon oxides. Nitrogen oxides (NOx). Chlorides. Chlorine. Phosgene . Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) D-Limonene 5989-27-5 4400 mg/kg 5 g/kg - Propane/Isobutan e/N-Butane 68476-86-8 - - - Isopropyl Alcohol 67-63-0 4396 mg/kg 12800 mg/kg 16000 ppm Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity See Section 2 . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects See Section 2 Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns D-Limonene Not Listed Not Listed Not Listed Not Listed Not Listed Propane/Isob utane/N- Butane Not Listed Not Listed Not Listed Not Listed Not Listed Isopropyl Alcohol A4 Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Disposal Information Discard container or liner in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT UN1950 Aerosols, flammable, 2.1. Exception: (Compressed Gas not more than 1.0L) Consumer Commodity ORM-D TDG UN1950 AEROSOLS, flammable, 2.1 Consumer commodity <1L 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Propane/Isobutan e/N-Butane Listed Isopropyl Alcohol Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 D-Limonene Not Listed Not Listed Not Listed Propane/Isobutane/N- Butane Not Listed Not Listed Not Listed Isopropyl Alcohol Not Listed Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA D-Limonene X X - X Propane/Isobutane/N- Butane X X - X Isopropyl Alcohol X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION HMIS Health - 1 Flammability - 4 Physical Hazard - 0 Page 3 / 4 Isopropyl Alcohol Product code 97936 Microtox Data Photobacterium phosphoreum EC50=35390 mg/L (5 min) Product name Foamy Orange Citrus Degreaser Water Flea Data Daphnia magna EC50=13299 mg/L (48 h) Page 278 of 871 Page 278 of 871 Page 278 of 871 Page 278 of 871 ---PAGE BREAK--- 16. OTHER INFORMATION Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product name Foamy Orange Citrus Degreaser Product code 97936 Page 279 of 871 Page 279 of 871 Page 279 of 871 Page 279 of 871 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Product identifier Food Grade Belt Dressing Other means of identification Product code 03065 Recommended use Belt dressing Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufactured or sold by: Company name CRC Industries, Inc. Address 885 Louis Dr. Warminster, PA 18974 US Telephone General Information [PHONE REDACTED] Technical Assistance [PHONE REDACTED] Customer Service [PHONE REDACTED] 24-Hour Emergency [PHONE REDACTED] (US) (CHEMTREC) [PHONE REDACTED] (International) Website www.crcindustries.com 2. Hazard(s) identification Category 1 Flammable aerosols Physical hazards Liquefied gas Gases under pressure Category 2 Reproductive toxicity (fertility) Health hazards Category 3 narcotic effects Specific target organ toxicity, single exposure Category 2 Specific target organ toxicity, repeated exposure Category 1 Aspiration hazard Category 3 Hazardous to the aquatic environment, long-term hazard Environmental hazards Not classified. OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Suspected of damaging fertility. May cause damage to organs (nervous system, upper respiratory tract, skin, eyes) through prolonged or repeated exposure. Harmful to aquatic life with long lasting effects. Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not apply while equipment is energized. Pressurized container: Do not pierce or burn, even after use. Extinguish all flames, pilot lights and heaters. Vapors will accumulate readily and may ignite. Use only with adequate ventilation; maintain ventilation during use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any listed on this label, increase ventilation or leave the area. Do not breathe gas. Do not breathe mist or vapor. Wear protective gloves/protective clothing/eye protection/face protection. Avoid release to the environment. Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If exposed or concerned: Get medical attention. 1 / 8 Material name: Food Grade Belt Dressing 1741 Version 01 Issue date: 02-12-2014 SDS US Page 280 of 871 Page 280 of 871 Page 280 of 871 Page 280 of 871 ---PAGE BREAK--- Storage Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Exposure to high temperature may cause can to burst. Disposal Dispose of contents/container in accordance with local/regional/national regulations. Hazard(s) not otherwise classified (HNOC) Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. Supplemental information 97.27% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment. 3. Composition/information on ingredients Mixtures CAS number % Chemical name Common name and synonyms 64742-49-0 Naphtha (petroleum), hydrotreated light 40 - 50 68476-86-8 Liquefied Petroleum Gas 20 - 30 107-83-5 10 - 20 9003-29-6 Isobutylene polymer 5 - 10 110-54-3 n-Hexane 1 - 3 Specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Wash off with soap and water. Take off contaminated clothing and wash before reuse. Eye contact Rinse with plenty of water. Ingestion Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may cause pulmonary edema and pneumonitis. Most important acute and delayed Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. May cause drowsiness or dizziness. Prolonged exposure may cause chronic effects. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat General information IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water spray. Water fog. Foam. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Contents under pressure. Pressurized container may explode when exposed to heat or flame. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. Special protective equipment and precautions for firefighters Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Fire-fighting equipment/instructions In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. In the event of fire, cool tanks with water spray. General fire hazards Extremely flammable aerosol. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Remove all possible sources of ignition in the surrounding area. Wear appropriate personal protective equipment. Do not breathe gas. Do not breathe mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 2 / 8 Material name: Food Grade Belt Dressing 1741 Version 01 Issue date: 02-12-2014 SDS US Page 281 of 871 Page 281 of 871 Page 281 of 871 Page 281 of 871 ---PAGE BREAK--- Methods and materials for containment and cleaning up Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Stop the flow of material, if this is without risk. Collect spillage. Dike far ahead of spill for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Prevent entry into waterways, sewer, basements or confined areas. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to avoid environmental contamination. 7. Handling and storage Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Do not breathe mist or vapor. Do not breathe gas. Avoid contact with skin and eyes. Avoid contact during pregnancy/while nursing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. When using, do not eat, drink or smoke. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Avoid release to the environment. Do not empty into drains. For product usage instructions, please see the product label. Conditions for safe storage, including any incompatibilities Level 3 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Avoid spark promoters. These alone may be insufficient to remove static electricity. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Keep out of the reach of children. 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Type PEL 1800 mg/m3 n-Hexane (CAS 110-54-3) 500 ppm US. ACGIH Threshold Limit Values Value Components Type STEL 1000 ppm (CAS 107-83-5) TWA 500 ppm TWA 50 ppm n-Hexane (CAS 110-54-3) US. NIOSH: Pocket Guide to Chemical Hazards Value Components Type Ceiling 1800 mg/m3 (CAS 107-83-5) 510 ppm TWA 350 mg/m3 100 ppm TWA 180 mg/m3 n-Hexane (CAS 110-54-3) 50 ppm Biological limit values ACGIH Biological Exposure Indices Value Components Determinant Specimen Sampling Time 0.4 mg/l 2,5-Hexanedio n, without hydrolysis Urine * n-Hexane (CAS 110-54-3) * - For sampling details, please see the source document. 3 / 8 Material name: Food Grade Belt Dressing 1741 Version 01 Issue date: 02-12-2014 SDS US Page 282 of 871 Page 282 of 871 Page 282 of 871 Page 282 of 871 ---PAGE BREAK--- Exposure guidelines US - California OELs: Skin designation n-Hexane (CAS 110-54-3) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation n-Hexane (CAS 110-54-3) Can be absorbed through the skin. Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear protective gloves such as: Nitrile. Polyvinyl chloride (PVC). Viton®. Other Wear appropriate chemical resistant clothing. Respiratory protection Wear positive pressure self-contained breathing apparatus (SCBA). Air monitoring is needed to determine actual employee exposure levels. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Aerosol. Color Light amber. Odor Mild solvent. Odor threshold Not available. pH Not available. Melting point/freezing point -244.7 °F (-153.7 estimated Initial boiling point and boiling range 118.4 °F (48 estimated Flash point < 0 °F -17.8 Tag Closed Cup Evaporation rate Fast. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower 1 % estimated Flammability limit - upper 8 % estimated Vapor pressure 1682.1 hPa estimated Vapor density > 1 (air = 1) Relative density 0.64 estimated Solubility (water) Negligible. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 489.2 °F (254 estimated Decomposition temperature Not available. Viscosity (kinematic) Not available. Percent volatile 92.8 % estimated 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Conditions to avoid Heat, flames and sparks. Contact with incompatible materials. 4 / 8 Material name: Food Grade Belt Dressing 1741 Version 01 Issue date: 02-12-2014 SDS US Page 283 of 871 Page 283 of 871 Page 283 of 871 Page 283 of 871 ---PAGE BREAK--- Incompatible materials Chlorine. Hazardous decomposition products Carbon oxides. 11. Toxicological information Information on likely routes of exposure Ingestion May be fatal if swallowed and enters airways. Inhalation Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. May cause damage to organs by inhalation. Skin contact Prolonged skin contact may cause temporary irritation. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Eye contact Direct contact with eyes may cause temporary irritation. related to the physical, chemical and toxicological characteristics of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Information on toxicological effects Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects. Test Results Product Species Food Grade Belt Dressing LD50 Rabbit Dermal Acute 3558.8184 mg/kg estimated LC50 Rat Inhalation 11984.4893 ppm, 4 hours estimated 315.9885 mg/l, 4 hours estimated LD50 Rat Oral 23333.2285 mg/kg estimated * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Reproductive toxicity Suspected of damaging fertility. Specific target organ toxicity - single exposure Narcotic effects. Specific target organ toxicity - repeated exposure May cause damage to organs through prolonged or repeated exposure. Aspiration hazard May be fatal if swallowed and enters airways. Chronic effects Prolonged inhalation may be harmful. May cause damage to organs through prolonged or repeated exposure. 12. Ecological information Ecotoxicity Harmful to aquatic life with long lasting effects. Accumulation in aquatic organisms is expected. Product Test Results Species Food Grade Belt Dressing LC50 Fish 1621.4834 mg/l, 96 hours estimated Fish Components Test Results Species Isobutylene polymer (CAS 9003-29-6) Acute EC50 Crustacea > 10000 mg/l, 48 hours Daphnia magna > 1000 mg/l, 48 hours 5 / 8 Material name: Food Grade Belt Dressing 1741 Version 01 Issue date: 02-12-2014 SDS US Page 284 of 871 Page 284 of 871 Page 284 of 871 Page 284 of 871 ---PAGE BREAK--- Components Test Results Species Aquatic Acute LC50 Fish > 1000 mg/l, 96 hours Fathead minnow (Pimephales promelas) > 10000 mg/l, 96 hours Rainbow trout,donaldson trout mykiss) * Estimates for product may be based on additional component data not shown. n-Hexane (CAS 110-54-3) Aquatic LC50 Fish 2.101 - 2.981 mg/l, 96 hours Fathead minnow (Pimephales promelas) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) 3.74 n-Hexane 3.9 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal of waste from residues / unused products This material and its container must be disposed of as hazardous waste. If discarded, this product is considered a RCRA ignitable waste, D001. Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Hazardous waste code D001: Waste Flammable material with a flash point <140 F Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN1950 UN number Aerosols, flammable, Limited Quantity UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk 2.1 Label(s) Not applicable. Packing group Read safety instructions, SDS and emergency procedures before handling. Special precautions for user N82 Special provisions 306 Packaging exceptions None Packaging non bulk None Packaging bulk IATA UN1950 UN number Aerosols, flammable, Limited Quantity UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk Not applicable. Packing group No. Environmental hazards 10L ERG Code Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Allowed. Passenger and cargo aircraft Other information Allowed. Cargo aircraft only IMDG UN1950 UN number AEROSOLS, LIMITED QUANTITY UN proper shipping name 6 / 8 Material name: Food Grade Belt Dressing 1741 Version 01 Issue date: 02-12-2014 SDS US Page 285 of 871 Page 285 of 871 Page 285 of 871 Page 285 of 871 ---PAGE BREAK--- 2 Class Transport hazard class(es) - Subsidiary risk Not applicable. Packing group No. Marine pollutant Environmental hazards Not available. EmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. SARA 304 Emergency release notification Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance n-Hexane (CAS 110-54-3) CERCLA Hazardous Substance List (40 CFR 302.4) n-Hexane (CAS 110-54-3) CERCLA Hazardous Substances: Reportable quantity n-Hexane (CAS 110-54-3) 5000 lbs Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center ([PHONE REDACTED]) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List n-Hexane (CAS 110-54-3) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. Food and Drug Administration (FDA) Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) Section 311/312 Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely hazardous substance No US state regulations US. New Jersey RTK - Substances: Listed substance (CAS 107-83-5) n-Hexane (CAS 110-54-3) US. Massachusetts RTK - Substance List (CAS 107-83-5) n-Hexane (CAS 110-54-3) US. RTK - Hazardous Substances (CAS 107-83-5) n-Hexane (CAS 110-54-3) US. Rhode Island RTK n-Hexane (CAS 110-54-3) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. 7 / 8 Material name: Food Grade Belt Dressing 1741 Version 01 Issue date: 02-12-2014 SDS US Page 286 of 871 Page 286 of 871 Page 286 of 871 Page 286 of 871 ---PAGE BREAK--- Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 100 % Consumer products (40 CFR 59, Subpt. C) Not regulated State Consumer products Not regulated VOC content (CA) 92.8 % VOC content (OTC) 92.8 % International Inventories Country(s) or region Inventory name On inventory (yes/no)* Yes Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) Yes China Inventory of Existing Chemical Substances in China (IECSC) No Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 02-12-2014 Prepared by Allison Cho Version # 01 Further information CRC # 439C/D HMIS® ratings Health: 2* Flammability: 4 Physical hazard: 0 Personal protection: B NFPA ratings Health: 2 Flammability: 4 Instability: 0 Disclaimer The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries. 8 / 8 Material name: Food Grade Belt Dressing 1741 Version 01 Issue date: 02-12-2014 SDS US Page 287 of 871 Page 287 of 871 Page 287 of 871 Page 287 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 22-Jul-2014 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 83571 Product name Full Blast Recommended Use Cleaner Supplier Lawson Products, Inc. 1666 East Touhy Avenue Des Plaines, IL 60018 (847)-827-9666 Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Eyes. Ingestion. Inhalation. Skin absorption. Skin contact. Potential health effects Eyes May cause the following effects:. Irritation. Frostbite. Burn. Skin Substance may cause slight skin irritation. dermatitis. Extreme overexposure may cause. Skin burns. Frostbite. Red blood cell hemolysis. Inhalation Shortness of breath. Dizziness. Light headedness. Headaches. Nausea. Extreme overexposure may cause. Upper respiratory tract irritation. Possible Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Ingestion Extreme overexposure may cause. Nausea. Diarrhea. Vomiting. Can burn mouth, throat, and stomach. May cause chemical pneumonitis if aspirated into lungs. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Butane 106-97-8 1-5 2-Butoxyethanol 111-76-2 1-5 Propane 74-98-6 1-5 Trisodium Phosphate 7601-54-9 1-5 4. FIRST AID MEASURES Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 20 minutes. Seek medical attention. Skin contact Wash area thoroughly with soap and water. Ingestion If a large quantity of liquid is swallowed, do NOT induce vomiting. Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. Call a physician immediately. Inhalation Remove to fresh air. Provide oxygen if breathing is difficult. If not breathing, give artificial respiration. Keep warm and quiet. Seek medical attention. 5. FIRE FIGHTING MEASURES Flash point °C No data available Flash point °F No data available Method Not Applicable Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 9.5% Lower 1.8% Suitable extinguishing media Alcohol foam. Carbon dioxide (CO2). Dry chemical powder. Foam. Water fog. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fire and Explosion Hazards Flammable . Material is highly volatile and readily gives off vapors. Vapors may form explosive mixture in air between upper and lower explosive limits which can be ignited by many sources, such as pilot lights, open flames, electrical motors and switches. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat . Sensitivity to shock No information available. Sensitivity to static discharge Yes. Take precautionary measures against static discharges. 6. ACCIDENTAL RELEASE MEASURES Page 1 / 3 (Bad file name or number) Emergency Overview Extremely flammable. Irritant. May be harmful if inhaled. May be harmful if swallowed. Contents under pressure. Page 288 of 871 Page 288 of 871 Page 288 of 871 Page 288 of 871 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Evacuate area of unprotected and unnecessary personnel. Ventilate area to maintain exposure below permissible exposure limits. Shut off source of leak if safe to do so. Dike or dam large spills. Soak up with inert absorbent material. Dispose of absorbent in accordance with local, state and federal regulations. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. 7. HANDLING AND STORAGE Handling Keep container closed when not in use. Storage Keep container closed. Keep away from direct sunlight. Keep away from open flames, hot surfaces and sources of ignition. Store in temperatures below 120 degrees F (50 degrees C) . 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) 2- Butoxyethanol 50 ppm 240 mg/m3 - 20 ppm - Trisodium Phosphate - - - - Propane 1000 ppm 1800 mg/m3 - 1000 ppm - Butane 800 ppm - - 1000 ppm Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Use with adequate explosion-proof ventilation to meet the limits in Section 8 . Hygiene measures Remove and wash contaminated clothing before re-use. Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Hand Protection Chemical resistant gloves. Eye protection ANSI approved safety glasses or splash goggles with face shield are recommended. Skin and body protection Wear appropriate clothing to minimize skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Colorless Odor Solvent Odor Threshold No information available pH 12.5 Specific Gravity 0.98 @ 70°F calculated Vapor pressure No data available Density No data available Vapor density No data available Evaporation Rate Slower than Ether Water solubility No data available VOC Content 7.85% Partition Coefficient (n-octanol/water) No data available Boiling point/range °C 97.8° (concentrate); -26° (propellant) Boiling point/range °F 208° (concentrate); -14.8° (propellant) Melting point/range °C No data available Melting point/range °F No data available Flash point °C No data available Flash point °F No data available 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Heat, flames and sparks. Do not store above 120 degrees F. Incompatability Strong acids. Halogens. Zinc. Magnesium. Aluminum. Boron. Ethylene oxide. Chlorites. Mercury. Chromium trioxide. Gold. Nitrogen Tetroxide. Oleum (or fuming sulfuric acid). Hazardous Decomposition Products Carbon monoxide. Carbon dioxide. Polymerization Hazardous polymerization does not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) 2-Butoxyethanol 111-76-2 470 mg/kg 220 mg/kg 450 ppm Trisodium Phosphate 7601-54-9 2000 mg/kg 2 mg/kg 2.16 mg/L Propane 74-98-6 - - 658 mg/L Butane 106-97-8 - - 658 g/m3 Synergistic Products None known Potential health effects Sensitization None known . Page 2 / 3 Product code 83571 Product name Full Blast Page 289 of 871 Page 289 of 871 Page 289 of 871 Page 289 of 871 ---PAGE BREAK--- Chronic toxicity None known . Mutagenic effects None known . Teratogenic effects None known . Reproductive toxicity None known . Target Organ Effects Kidney. Liver. Cardiovascular system. Carcinogenic effects See Table Below. Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns 2- Butoxyethanol A3 Not Listed Not Listed Not Listed Not Listed Trisodium Phosphate Not Listed Not Listed Not Listed Not Listed Not Listed Propane Not Listed Not Listed Not Listed Not Listed Not Listed Butane Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Disposal Information Dispose in accordance with federal, state, and local regulations. Full or partially full containers are considered hazardous waste. 14. TRANSPORTATION INFORMATION DOT Consumer commodity, ORM-D. TDG Consumer commodity, ORM-D. 15. REGULATORY INFORMATION US EPA SARA 313 Glycol ethers are listed under the Hazardous Air Pollutants (HAPS) category "glycol ethers" as specified in the Clean Air Act, and here for Clean Air Act reporting purposes Chemical Name US EPA SARA 313 Emission Reporting 2-Butoxyethanol Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 2-Butoxyethanol Listed Listed Not Listed Trisodium Phosphate Not Listed Listed Not Listed Propane Listed Listed Not Listed Butane Listed Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA 2-Butoxyethanol X X - X Trisodium Phosphate X X - X Propane X X - X Butane X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. OTHER INFORMATION NFPA Health - 3 Flammability - 4 Reactivity - 0 Health - 3 Flammability - 4 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 3 / 3 Water Flea Data Daphnia magna EC50>1000 mg/L (48 h) Product code 83571 2-Butoxyethanol Product name Full Blast Page 290 of 871 Page 290 of 871 Page 290 of 871 Page 290 of 871 ---PAGE BREAK--- Page 291 of 871 Page 291 of 871 Page 291 of 871 Page 291 of 871 ---PAGE BREAK--- Page 292 of 871 Page 292 of 871 Page 292 of 871 Page 292 of 871 ---PAGE BREAK--- Page 293 of 871 Page 293 of 871 Page 293 of 871 Page 293 of 871 ---PAGE BREAK--- Page 294 of 871 Page 294 of 871 Page 294 of 871 Page 294 of 871 ---PAGE BREAK--- Page 295 of 871 Page 295 of 871 Page 295 of 871 Page 295 of 871 ---PAGE BREAK--- Page 296 of 871 Page 296 of 871 Page 296 of 871 Page 296 of 871 ---PAGE BREAK--- Page 297 of 871 Page 297 of 871 Page 297 of 871 Page 297 of 871 ---PAGE BREAK--- Page 298 of 871 Page 298 of 871 Page 298 of 871 Page 298 of 871 ---PAGE BREAK--- Page 299 of 871 Page 299 of 871 Page 299 of 871 Page 299 of 871 ---PAGE BREAK--- Page 300 of 871 Page 300 of 871 Page 300 of 871 Page 300 of 871 ---PAGE BREAK--- PITTHANE 35 WHITE TINT BASE COMP A Product name Product and company identification : 1 . 95-8512 PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (514) 645-1320 (Canada) 01-800-00-21-400 (Mexico) Supplier Code Emergency telephone number : : : Technical Phone Number : [PHONE REDACTED] Material Safety Data Sheet Date of issue 9 July 2015 Version 27 Emergency overview Hazards identification Potential acute health effects May be harmful if swallowed. Eyes Skin Inhalation Ingestion See toxicological information (Section 11) WARNING! : : : : : Medical conditions aggravated by over- exposure Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. : 2 . Over-exposure Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeated exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expected from exposure to noise alone. Keep away from flames, such as a pilot light, and any object that sparks, such as an electric motor. Keep away from heat. Do not smoke. Do not swallow. Avoid breathing vapor or mist. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Keep container closed and sealed until ready for use. Wash thoroughly after handling. FLAMMABLE LIQUID AND VAPOR. CAUSES RESPIRATORY TRACT IRRITATION. MAY BE HARMFUL IF INHALED OR SWALLOWED. SANDING AND GRINDING DUSTS MAY BE HARMFUL IF INHALED. MAY CAUSE EYE IRRITATION. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. SUSPECT CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER. May be harmful if inhaled. Irritating to respiratory system. Can irritate eyes, nose, mouth and throat. Moderately irritating to eyes. Moderately irritating to the skin. This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials Information System (WHMIS). Page: 1/8 Canada - Mexico Page 301 of 871 Page 301 of 871 Page 301 of 871 Page 301 of 871 ---PAGE BREAK--- PITTHANE 35 WHITE TINT BASE COMP A Product name 27 Product code Date of issue Version 95-8512 9 July 2015 Composition/information on ingredients 3 . There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. titanium dioxide 13463-67-7 10 - 30 Solvent naphtha (petroleum), light aromatic 64742-95-6 10 - 30 heptan-2-one 110-43-0 7 - 13 95-63-6 3 - 7 barium sulfate 7727-43-7 1 - 5 silicon dioxide 7631-86-9 0.5 - 1.5 xylene 1330-20-7 0.1 - 1 cumene 98-82-8 0.1 - 1 methyl methacrylate 80-62-6 0.1 - 1 Name CAS number % (w/w) First aid measures Eye contact Skin contact Inhalation Ingestion Notes to physician : : : : : 4 . Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting. If ingestion, irritation, any type of overexposure or of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person. No specific treatment. Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Use dry chemical, CO₂, water spray (fog) or foam. Fire-fighting measures Extinguishing media isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : 5 . Special exposure hazards : Do not use water jet. Suitable : Not suitable : Hazardous combustion products : Decomposition products may include the following materials: carbon oxides sulfur oxides metal oxide/oxides Flammability of the product : Page: 2/8 Canada - Mexico Page 302 of 871 Page 302 of 871 Page 302 of 871 Page 302 of 871 ---PAGE BREAK--- PITTHANE 35 WHITE TINT BASE COMP A Product name 27 Product code Date of issue Version 95-8512 9 July 2015 No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section Stop leak if without risk. Move containers from spill area. Approach release from upwind. Use spark-proof tools and explosion-proof equipment. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Environmental precautions Accidental release measures : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions : Large spill : 6 . Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Do not store above the following temperature: 120°F / 49°C. Put on appropriate personal protective equipment (see Section Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Do not swallow. Do not get in eyes or on skin or clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. Vapors are heavier than air and may spread along floors. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. If this material is part of a multiple component system, read the Material Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. Handling and storage Handling Storage : : 7 . Page: 3/8 Canada - Mexico Page 303 of 871 Page 303 of 871 Page 303 of 871 Page 303 of 871 ---PAGE BREAK--- PITTHANE 35 WHITE TINT BASE COMP A Product name 27 Product code Date of issue Version 95-8512 9 July 2015 Exposure controls/personal protection 8 . Acceptable Maximum Peak A = ACGIH = American Conference of Governmental Industrial Hygienists. C = Ceiling Limit Potential skin absorption S SR = Respiratory sensitization = Skin sensitization SS TD = Total dust Key to abbreviations Safety glasses with side shields. Personal protection Eyes Consult local authorities for acceptable exposure limits. : Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. = Threshold Limit Value TLV TWA = Time Weighted Average Fume = F IPEL = Internal Permissible Exposure Limit R = Respirable titanium dioxide TWA 10 mg/m³ 10 mg/m³ TD 10 mg/m³ (as Ti) Not established STEL Not established Not established 20 mg/m³ (as Ti) Not established heptan-2-one TWA 50 ppm 25 ppm 50 ppm Not established STEL Not established Not established 100 ppm Not established TWA 25 ppm 25 ppm 25 ppm Not established STEL Not established Not established 35 ppm Not established barium sulfate TWA 5 mg/m³ 10 mg/m³ TD Not established Not established silicon dioxide TWA Not established Not established 10 mg/m³ Not established 3 mg/m³ R xylene TWA 100 ppm 100 ppm 100 ppm Not established STEL 150 ppm 150 ppm 150 ppm Not established cumene TWA 50 ppm 50 ppm S 50 ppm S Not established STEL Not established Not established 75 ppm S Not established methyl methacrylate TWA 50 ppm SS 50 ppm SS 100 ppm Not established STEL 100 ppm SS 100 ppm SS 125 ppm Not established Name Result ACGIH Ontario Mexico PPG STEL = = Short term Exposure limit values Page: 4/8 Canada - Mexico Page 304 of 871 Page 304 of 871 Page 304 of 871 Page 304 of 871 ---PAGE BREAK--- PITTHANE 35 WHITE TINT BASE COMP A Product name 27 Product code Date of issue Version 95-8512 9 July 2015 Exposure controls/personal protection 8 . If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Skin Respiratory : : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. >37.78°C (>100°F) Liquid. 52% 34.56% (w/w) Not available. Not available. 1.28 Not available. 0.75 kPa (5.6 mm Hg) [room temperature] Soluble in the following materials: cold water. Not available. Not available. Boiling/condensation point Melting/freezing point 0.31 (butyl acetate = 1) Physical and chemical properties Physical state pH Specific gravity Vapor pressure Vapor density Volatility Evaporation rate Solubility Odor Color : : : : : : : : : : : : Flash point : Closed cup: 27.78°C (82°F) Explosion limits : Lower: 0.9% 9 . Partition coefficient: n- octanol/water : Not available. % Solid. (w/w) : 65.44 Density ( lbs / gal ) : 10.68 Yes. : Material supports combustion. Page: 5/8 Canada - Mexico Page 305 of 871 Page 305 of 871 Page 305 of 871 Page 305 of 871 ---PAGE BREAK--- PITTHANE 35 WHITE TINT BASE COMP A Product name 27 Product code Date of issue Version 95-8512 9 July 2015 Stable under recommended storage and handling conditions (see Section Reactive or incompatible with the following materials:,acids,oxidizing materials,strong alkalis Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Stability and reactivity Stability Conditions to avoid Materials to avoid Hazardous decomposition products Hazardous polymerization : : : : : 10 . 11 . Toxicological information Conclusion/Summary : Not available. Chronic toxicity Conclusion/Summary : Not available. Carcinogenicity Classification Carcinogenicity : Contains material which may cause cancer. Risk of cancer depends on duration and level of exposure. Defatting irritant : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis. Target organs : Contains material which causes damage to the following organs: brain, central nervous system (CNS). Contains material which may cause damage to the following organs: blood, lungs, peripheral nervous system, upper respiratory tract, skin, eye, lens or cornea. titanium dioxide LD50 Oral Rat >10 g/kg - Solvent naphtha (petroleum), light aromatic LD50 Oral Rat 8400 mg/kg - LD50 Dermal Rabbit 3.48 g/kg - heptan-2-one LD50 Oral Rat 1.6 g/kg - LD50 Dermal Rabbit 10.206 g/kg - LD50 Oral Rat 5 g/kg - LC50 Inhalation Rat 18000 mg/m3 4 hours xylene LD50 Oral Rat 4.3 g/kg - LD50 Dermal Rabbit >1.7 g/kg - LC50 Inhalation Vapor Rat 5000 ppm 4 hours cumene LD50 Oral Rat 1.4 g/kg - LD50 Dermal Rabbit 12.3 g/kg - LC50 Inhalation Rat 39000 mg/m3 4 hours methyl methacrylate LD50 Oral Rat 7872 mg/kg - LD50 Dermal Rabbit >5 g/kg - LC50 Inhalation Vapor Rat 78000 mg/m3 4 hours Product/ingredient name Result Species Dose Exposure Acute toxicity Product/ingredient name titanium dioxide A4 2B - silicon dioxide - 3 - cumene - 2B Reasonably anticipated to be a human carcinogen. methyl methacrylate A4 3 - ACGIH NTP IARC Page: 6/8 Canada - Mexico Page 306 of 871 Page 306 of 871 Page 306 of 871 Page 306 of 871 ---PAGE BREAK--- PITTHANE 35 WHITE TINT BASE COMP A Product name 27 Product code Date of issue Version 95-8512 9 July 2015 11 . Toxicological information Carcinogen Classification code: Teratogenicity : Contains material which may cause birth defects, based on animal data. ACGIH: A1, A2, A3, A4, A5 IARC: 1, 2A, 2B, 3, 4 NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen Not listed or regulated as a carcinogen: - Ecological information Environmental effects : No known significant effects or critical hazards. 12 . Aquatic ecotoxicity titanium dioxide Acute LC50 >100 mg/l Fresh water Daphnia - Daphnia magna 48 hours Product/ingredient name Species Result Exposure The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal Disposal considerations Disposal should be in accordance with applicable regional, national and local laws and regulations. : 13 . Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures 14. Transport information Additional information None identified. TDG : PAINT 3 III UN1263 Mexico UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No. TDG UN1263 PAINT 3 III No. Marine pollutant substances IMDG UN1263 PAINT 3 III No. Not applicable. Not applicable. Not applicable. Page: 7/8 Canada - Mexico Page 307 of 871 Page 307 of 871 Page 307 of 871 Page 307 of 871 ---PAGE BREAK--- PITTHANE 35 WHITE TINT BASE COMP A Product name 27 Product code Date of issue Version 95-8512 9 July 2015 14. Transport information Special precautions for user Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : None identified. Mexico : IMDG : None identified. 15 . Regulatory information All components are listed or exempted. Canada inventory ( DSL ) : WHMIS (Canada) Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). : Canada Mexico 3 2 0 Health Flammability Reactivity Classification : : : Other information Hazardous Material Information System 3 0 3 National Fire Protection Association Health Instability Flammability Health Flammability Physical hazards Disclaimer The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Date of previous issue 5/29/2015 : 16 . Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Indicates information that has changed from previously issued version. Organization that prepared the MSDS : EHS : : : : : : 2 * 2 0 ( * ) - Chronic effects Page: 8/8 Canada - Mexico Page 308 of 871 Page 308 of 871 Page 308 of 871 Page 308 of 871 ---PAGE BREAK--- Material Safety Data Sheet Data prepared: June 4, 2002 Data revised: August 2005 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY Product Name: Gorilla Glue® Product Type: Polyurethane adhesive for wood and wood substrates Distributor: The Gorilla Glue Company 4550 Red Bank Expressway Cincinnati, OH 45227 Tel: (513) 271-3300 Fax: (513) 527-3742 Emergency: During business hours: The Gorilla Glue Company: (800) 966-3458. Outside business hours: Prosar International Poison Center: (800) 420-7186. 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name CAS No. % content Urethane prepolymer trade secret 60-70 Polymeric MDI* 9016-87-9 30-40 *MDI: 4,4’-Diphenylmethane diisocyanate. Polymeric MDI is a mixture of monomeric MDI, isomeres and homopolymer. 3. HAZARDS IDENTIFICATION Vapors from the product may be irritating to the eyes, respiratory system and skin. MDI in product is a strong sensitiser, resulting in possible allergic reactions. Skin and eye contact may cause irritation and sensitisation. 4. FIRST AID MEASURES Inhalation Move affected individual to fresh air, administer oxygen and artificial respiration as necessary. Call doctor if any problem persists. Eye contact Flush eyes for at least 20 minutes while holding eyelids open. Seek medical attention. Skin contact Remove contaminated clothes immediately, and wash skin thoroughly with soap and warm water. Get medical attention if irritation or sensitization develops or persists. Ingestion Product is not intended to be ingested or eaten. If this product is ingested, severe irritation or blockage of the gastrointestinal tract may occur, and should be treated Call doctor or ambulance. 5. FIRE FIGHTING MEASURES Upper flammable limit (UFL): Not determined Lower flammable limit (LFL): Not determined NFPA: Health – 3, Flammability – 1, Reactivity – 1 HMIS: Health – 3, Flammability – 1, Reactivity – 1 General fire hazards Down-wind personnel must be evacuated. Do not reseal contaminated containers; a chemical reaction generating carbon dioxide gas pressure may occur resulting in rupture of the container. Dense smoke is emitted when product is burned without sufficient oxygen. When using water spray, boil-over may occur when product temperature reaches the boiling point of water, and the reaction forming carbon dioxide will accelerate. MDI vapor and other gases may be generated by thermal decomposition. Page 1 of 4 Page 309 of 871 Page 309 of 871 Page 309 of 871 Page 309 of 871 ---PAGE BREAK--- Special hazards in fire In case of fire, formation of carbon monoxide, carbon dioxide, nitrogen oxide, isocyanate vapor, and traces of hydrogen cyanide is possible. Extinguishing Media Carbon dioxide, dry powder, and foam. In cases of large scale fires, alcohol-resistant foams are preferred. If water is used, it should be used in very large quantities. The reaction between water and isocyanate may be vigorous. Required special protective equipment for fire-fighters Fire fighters should wear full-face, self-contained breathing apparatus and impervious protective clothing. Fire fighters should avoid inhaling any combustion products. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Wear full-protective clothing and respiratory protection as required to maintain exposures during clean-up below the applicable exposure limits. Environmental precautions Do not discharge spillage into drains. Dam remainders with sand, earth, or other suitable absorbent. MDI in contaminated areas can be neutralised with an ammonia/water solution (90% water, 3-8% ammonia, plus 2% detergent. Use 10 parts neutraliser per one part isocyanate.) Clean-up procedures Dispose of spilled material in accordance with federal, state, and local regulations in permitted hazardous waste manage- ment facility. Incineration is the preferred method of disposal. Empty containers must be handled with care due to prod- uct residue. Do not heat or cut empty containers with electric or gas torch. 7. HANDLING AND STORAGE Handling Avoid skin and eye contact. Avoid inhalation of fumes. Smoking, eating and drinking are not allowed in the work-place. Personal protection: see Section 8. Storage Keep product away from sources of alcohols, amines, or other materials that react with dissocyanates. Avoid prolonged heating above 160°C/320°F. Store product in closed containers in a well-ventilated place and in accordance with national regulations. Keep out of reach of children. 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION For exposure controls see Section 15. Component exposure limits Name CAS no. ppm mg/m3 4,4’-Diphenylmethane diisocyanate 101-68-8 0.02 0.2 Personal protection equipment General Wear suitable protective clothing, protective gloves and protective goggles/mask. Suitable materials for Natural rubber/natural latex – NR 0.5 mm) safety gloves – CR 0.5mm) Nitrile rubber – NBR 0.35mm) Butyl rubber – IIR 0.5 mm) Page 2 of 4 Page 310 of 871 Page 310 of 871 Page 310 of 871 Page 310 of 871 ---PAGE BREAK--- Personal protection equipment (continued) Suitable materials Polyethylene/ethylene vinyl alcohol laminate for clothing (PE/VAL) has been reported as an effective material of construction for chemical protective clothing for MDI. Respiratory protection Must be used if concentration above the critical values. Hand protection Use protective lotion or gloves. Eyes protection Chemical goggles or full face shields are recommended. An eyewash fountain and safety shower should be available in the work area. Contact lenses should not be worn when working with this product. Skin protection Wear special gloves and working clothes to avoid skin irritation or sensitization. Depending on operation, chemical resistant boots, overshoes, and apron may also be required. Ventilation If vapor or mist is generated during processing or use, local exhaust ventilation should be provided to maintain exposures below the applicable limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical form. . . . . . . . . . . Liquid Color . . . . . . . . . . . . . . . . . . Dark-brown Odor . . . . . . . . . . . . . . . . . . Mild amine Boiling point . . . . . . . . . . . 368°C (>694°F) Flash point . . . . . . . . . . . . . >250°C (>482°F) Vapour pressure. . . . . . . . < 0,00001 mbar at 20°C (68°F) Specific gravity . . . . . . . . . 1,15 g/cm3 at 20°C (68°F) Viscosity . . . . . . . . . . . . . . . 5,500 – 8,500 mPa.s at 25°C (77°F) Solubility in water . . . . . . Reacts pH. . . . . . . . . . . . . . . . . . . . . Not applicable Percent volatile. . . . . . . . . 0% 10. STABILITY AND REACTIVITY Stability The product is stable under the recommended handling and storage conditions (see Section Hazardous decomposition products By exposure to high temperature, hazardous decomposition products may develop, such as isocyanate vapor and mist, carbon dioxide, carbon monoxide, nitrogen oxide, and traces of hydrogen cyanide. Hazardous reaction Exothermic reaction with amines and alcohols; reacts with water forming heat, CO2, and insoluble polyurea.The combined effect of CO2 and heat can produce enough pressure to rupture a closed container. 11. TOXICOLOGICAL INFORMATION Acute Toxicity LD50 oral, rat: > 5000 mg/kg Carcinogenicity Gorilla Glue, with the exception of unavoidable ubiquitous traces, does not contain any substances currently classified by EU Council Directive 67/548/EEC, its amendments and adaptations to technical progress, as a carcinogen category 1, 2 or 3. Inhalation May cause irritation of the mucous membranes of nose, throat or trachea. Skin contact Prolonged or repeated contact may result in dermatitis, either irritative or allergic. Eye contact May result in conjunctiva irritation and mild corneal opacity. Medical information treatment. Page 3 of 4 Page 311 of 871 Page 311 of 871 Page 311 of 871 Page 311 of 871 ---PAGE BREAK--- 12. ECOLOGICAL INFORMATION The product should not be discharged into drains or streams. Biodegradability 0% after 28 days Acute fish toxicity LC0 = > 1000 mg/l (96 hrs.) Toxicity for daphnia EC 50 = > 1000 mg/l (24 hrs.) Acute bacteria toxicity EC 50 = > 100 mg/l (3 hrs.) 13. DISPOSAL CONSIDERATIONS The product remnants are classified as chemical waste. Dispose of waste according to local, state, federal, and provincial environmental regulations. 14. TRANSPORTATION INFORMATION This product is not classified as hazardous material for transport. UN number - Packaging group - Land transport Transport class - Risk code - Name according to bill of freight - Other information - 15. REGULATION INFORMATION This product and its components are listed on the TSCA 8(b) inventory. Hazard designation Xn – Harmful. Contains 4,4’- Diphenylmethane diisocyanate (MDI), isomere. R-phrases 20 – Harmful by inhalation. 36/37/38 – Irritating to eyes, respiratory system and skin. 42/43 – May cause sensitization by inhalation and skin contact. S-phrases 23 – Do not breathe gas/fumes/vapor/spray. 36/37 – Wear suitable protective clothing and gloves. 45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Any existing national regulations on the handling of isocyanates must be observed. 16. OTHER INFORMATION The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no warranty, expressed or implied, is given. It is the buyer’s responsibility to ensure that its activities comply with federal, state or provincial, and local laws. Date 08/01/2005 Gorilla Glue Safety Data Sheet Sea transport IMDG class - Correct technical name - Other information - Air transport ICAO/IATA class Not restr. Correct technical name - Other information - Page 4 of 4 Page 312 of 871 Page 312 of 871 Page 312 of 871 Page 312 of 871 ---PAGE BREAK--- FOR CHEMICAL EMERGENCY During Business Hours: (800) 966-3458 Outside Business Hours: (800) 420-7186 GORILLA GLUE Gorilla Super Glue Gel MSDS 1. IDENTIFICATION OF SUBSTANCE/PREPARATION/AND THE COMPANY Product name: Gorilla Super Glue Gel Product description: Ethyl Cyanoacrylate adhesive Distributor: The Gorilla Glue Company 4550 Red Bank Expressway Cincinnati, OH 45227 Tel: (513) 271-3300 Fax: (513) 527-3742 2. COMPOSITION AND INFORMATION ON HARMFUL INGREDIENTS Ingredients: CAS No. ACGIH TLV Other limits % Composition Ethyl Cyanoacrylate 7085-85-0 0.2ppm TWA 0.3ppm STEL 60-100 3. HAZARDS IDENTIFICATION Immediate concerns: Causes eye and skin irritation. May cause sensitization. May cause respiratory tract irritation. Rapid polymerization occurs upon contact with water or alkaline substances. As a result, heat is generated. Skin inflammation or burns may occur upon contact during this polymerization. HMIS Health 2 Flammability 2 Physical hazards 1 Label Precautionary Statements: Combustible, Irritant, Bonds Skin Instantly, Keep out of Reach of Children and Animals Potential health effects Eyes: Causes eye irritation. Skin: Bonds skin instantly. May cause sensitization. Ingestion: Note likely route of entry. Substance may be harmful if swallowed. Inhalation: May cause irritation to the nose, throat and respiratory tract. Signs and of overexposure Acute toxicity: of exposure include burning sensation, coughing, wheezing, laryngitis, stomach or intestinal upset, and/or respiratory tract irritation. Target organ statement Eyes. Sensitization: May cause allergic skin reaction. 4. FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes. Do not attempt to pull apart bonded eyelid. Seek medical attention. Skin: Immediately wash skin with soap and plenty of water. Removed contaminated clothing. Get medical attention if occur. Wash clothing before reuse. Ingestion: Do not induce vomiting. Saliva will cause cyanoacrylate to polymerize in mouth. If lips are bonded together, use warm water to gently separate the lips apart. Contact a physician. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Notes to physician: Cured adhesive does not pose a health risk. MATERIALS SAFETY DATA SHEET Date Prepared: February 5, 2013 5th Edition Page 313 of 871 Page 313 of 871 Page 313 of 871 Page 313 of 871 ---PAGE BREAK--- 5. FIRE FIGHTING MEASURES Flash Point: >81ºC (150-200ºF) Extinguishing Media: Water spray, foam, dry chemical or CO2 Special Fire Fighting Procedures: Wear self contained breathing apparatus Unusual Fire/Explosion Hazards: No applicable information found. Hazardous Thermal Decomposition Products: Irritating organic vapors may be formed. 6. ACCIDENTAL RELEASE MEASURES Small spill: Absorb with an inert material and place in an appropriate waste disposal container. Large spill: Extinguish all sources of ignition. Stop spill or leak at source. Dike if necessary. Absorb with an inert material and place in an appropriate waste disposal container. Release notes: Keep spilled material from entering storm drains, sewers or other environmental mediums. Comments: Disposal of clean-up materials may be governmentally regulated. Observe all applicable local, state and Federal waste management regulations. 7. HANDLING AND STORAGE Handling: To avoid fire, eliminate ignition sources. Avoid contact with eyes, skin and clothing. In case of insufficient ventilation, wear suitable respiratory equipment. May react in presence of moisture. May react or be incompatible with alkalies. Wash thoroughly after handling. Storage: Contains moisture sensitive material. Store in a dry, cool, well-ventilated area. Keep away from sources of heat ignition. Keep container closed when not in use. Store between 5-25ºC. Comments: Rapid polymerization occurs upon contact with water or alkaline substances. As a result, heat is generated. Skin inflammation or burns may occur upon contact during this polymerization. 8. EXPOSURE CONTROL AND PERSONAL PROTECTION Eye Protection: Safety goggles / glasses suitable for use with chemicals. Respiratory Protection: Always use appropriate filter mask / respirator. Skin Protection: Nitrile / polyethylene gloves, coveralls, avoid cotton products. Ventilation: Good general or local exhaust ventilation is required for usage. 9. PHYSICA L AND CHEMICAL PROPERTIES Form: Liquid Color: Water white / straw colored Odor: Sharp, irritating Solubility in Water: Immiscible in water Boiling Point: >100ºC Vapor Pressure @ 25ºC: <0.5mm Hg Flash Point: >81ºC (150-200ºF) V.O.C. Content: <20g/l estimated (California SCAQMD Method 316B) FOR CHEMICAL EMERGENCY During Business Hours: (800) 966-3458 Outside Business Hours: (800) 420-7186 GORILLA GLUE Gorilla Super Glue Gel MSDS Page 2 of 12 MATERIALS SAFETY DATA SHEET Date Prepared: February 5, 2013 5th Edition Page 314 of 871 Page 314 of 871 Page 314 of 871 Page 314 of 871 ---PAGE BREAK--- 10. REACTIVITY AND STABILITY Stability: Stable Hazardous Polymerization: No Incompatibility: Reactive with alkalis, oxidizing agents, reducing agents, amines, alcohols and water. Conditions to Avoid: No applicable information found Hazardous Decomposition Products: No applicable information found. 11. TOXICOLOGICAL INFORMATION Estimated Oral LD50: >5000 mg kg Estimated Dermal LD50: >2000 mg kg Estimated Inhalation LC50: >4000 mg kg Causes Severe Irritation. High concentrations are destructive to tissues of the mucous membranes and the upper respiratory tract. Exposure limits: ACGIH TLV: 0.2ppm TWA, OSHA: none 12. ECOLOGICAL INFORMATION No applicable information found. 13. DISPOSAL CONSIDERATIONS Cyanoacrylates must be disposed of in accordance with all national and local regulations. 14. TRANSPORTATION INFORMATION Not considered hazardous for the purpose of transportation. 15. REGULATORY INFORMATION (NOT MEANT TO BE ALL INCLUSIVE) TSCA All ingredients of this product are listed, or are exempt from listing, on the TSCA inventory. SARA CERCLA/SARA Section 302EHS: None above reporting de minimus CERCLA/SARA Section 311/312: Fire, Reactive, Delayed Health, Immediate Health CERCLA/SARA Section 313: None above reporting de minimus Risk Phrases R36/37/38 Irritating to eyes, respiratory system and skin GORILLA GLUE Gorilla Super Glue Gel MSDS Page 3 of 12 FOR CHEMICAL EMERGENCY During Business Hours: (800) 966-3458 Outside Business Hours: (800) 420-7186 MATERIALS SAFETY DATA SHEET Date Prepared: February 5, 2013 5th Edition Page 315 of 871 Page 315 of 871 Page 315 of 871 Page 315 of 871 ---PAGE BREAK--- MATERIALS SAFETY DATA SHEET Date Prepared: February 5, 2013 5th Edition FOR CHEMICAL EMERGENCY During Business Hours: (800) 966-3458 Outside Business Hours: (800) 420-7186 California Proposition 65 No California Proposition 65 listed chemicals are known to be present. Canada DSL All ingredients of this product are listed, or are exempt from listing, on the Canada DSL. Safety Phrases S2 Keep out of reach of children. S23 Do not breathe fumes. S24 Avoid contact with skin S25 Avoid contact with eyes S26 In case of emergency rinse immediately with plenty of water and seek medical advice. S46 If swallowed, seek medical advice immediately and show this container or label. 16. OTHER INFORMATION The information herein is presented in good faith and believed to be accurate as of the effective date given. However no warranty, expressed or implied, is given. It is the buyer’s responsibility to ensure that its activities comply with Federal, State or Provincial, and Local laws. GORILLA GLUE Gorilla Super Glue Gel MSDS Page 4 of 12 Page 316 of 871 Page 316 of 871 Page 316 of 871 Page 316 of 871 ---PAGE BREAK--- Gorilla Wood Glue Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision Date: 08/26/2014 Date of issue: 08/26/2014 Version: 1.0 08/26/2014 EN (English US) 1/5 SECTION 1: IDENTIFICATION Product Identifier Product Name: Gorilla Wood Glue Synonyms: Polyvinyl Acetate Polymer product in water Intended Use of the Product Consumer Adhesives for building, carpentry, or hobby projects using any type of wood. It is water resistant (passes ANSI/HPVA Type II), sandable, and paintable. Name, Address, and Telephone of the Responsible Party Company The Gorilla Glue Company 4550 Red Bank Expressway Cincinnati, Ohio 45227 [PHONE REDACTED] www.gorillatough.com Emergency Telephone Number Emergency number : 1-[PHONE REDACTED] (Prosar) SECTION 2: HAZARDS IDENTIFICATION Classification of the Substance or Mixture Classification (GHS-US) Not classified Label Elements GHS-US Labeling No labelling applicable Other Hazards Not available Unknown Acute Toxicity (GHS-US) Not available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Mixture Name Product identifier % (w/w) Classification (GHS-US) Water (CAS No) 7732-18-5 49 - 52 Not classified Vinyl acetate polymer Trade secret 44 - 46 Not classified Aluminium chloride, hexahydrate (CAS No) 7784-13-6 < 4 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 STOT SE 3, H335 Aquatic Acute 1, H400 Propylene glycol phenyl ether (CAS No) 770-35-4 < 1.5 Eye Irrit. 2A, H319 Full text of H-phrases: see section 16 SECTION 4: FIRST AID MEASURES Description of First Aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label if possible). Inhalation: If inhaled, remove to fresh air and keep at rest in a position comfortable for breathing. If you feel unwell, seek medical advice. Skin Contact: Remove contaminated clothing. Gently wash with plenty of soap and water followed by rinsing with water for at least 15 minutes. Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing for at least 15 minutes. Obtain medical attention if irritation develops. Ingestion: Rinse mouth. Do not induce vomiting. Immediately call a POISON CENTER or doctor/physician. Most Important and Effects Both Acute and Delayed General: May cause irritation. Inhalation: None expected under normal conditions of use. Skin Contact: May cause mild skin irritation. Eye Contact: May cause eye irritation. Page 317 of 871 Page 317 of 871 Page 317 of 871 Page 317 of 871 ---PAGE BREAK--- Gorilla Wood Glue Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/26/2014 EN (English US) 2/5 Ingestion: Ingestion may be harmful or have adverse effects. Chronic Not applicable Indication of Any Immediate Medical Attention and Special Treatment Needed If medical advice is needed, have product container or label at hand. SECTION 5: FIRE-FIGHTING MEASURES Extinguishing Media Special Hazards Arising From the Substance or Mixture Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Firefighting Instructions: Do not allow run-off from fire fighting to enter drains or water courses. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Hazardous Combustion Products: Carbon oxides (CO, CO2). Oxides of aluminum. Reference to Other Sections Refer to section 9 for flammability properties. SECTION 6: ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Do not get in eyes, on skin, or on clothing. Contaminated surfaces will become very slippery. For Non-Emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. For Emergency Personnel Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Ventilate area. Stop leak if safe to do so. Environmental Precautions Prevent entry to sewers and public waters. Methods and Material for Containment and Cleaning Up For Containment: Absorb and/or contain spill with inert material (ie. sand, silica gel, sawdust, universal binder), then place in suitable container. Methods for Cleaning Up: Clear up spills immediately and dispose of waste safely in accordance with local, state, territorial, provincial, and federal regulations. Reference to Other Sections See Section 8 for Exposure Controls and Personal Protection. See Section 13 for Disposal Consideration. SECTION 7: HANDLING AND STORAGE Precautions for Safe Handling Handling Temperature: > 10 °C (50 Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking, or smoking and again when leaving work. Conditions for Safe Storage, Including Any Incompatibilities Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Incompatible Materials: Strong acids, strong bases, strong oxidizers, and materials that react with water. Maximum Storage Period: Varies depending on storage conditions. For best results, protect from frost and do not store in heat or direct sunlight. Keep sealed and between temperatures 10 and 35°C (50 and 95°F). Specific End Use(s) Consumer Adhesives for building, carpentry, or hobby projects using any type of wood. It is water resistant (passes ANSI/HPVA Type II), sandable, and paintable. Suitable Extinguishing Media: The product in solution form does not burn. The product will burn only after the water in it is driven off. For the dry polymer, use alcohol resistant foam, carbon dioxide or dry chemical. Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire. Fire Hazard: Not flammable under stable conditions. Explosion Hazard: Product is not explosive. Reactivity: Hazardous reactions will not occur under normal conditions. Page 318 of 871 Page 318 of 871 Page 318 of 871 Page 318 of 871 ---PAGE BREAK--- Gorilla Wood Glue Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/26/2014 EN (English US) 3/5 SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Control Parameters No Occupational Exposure Limits (OELs) have been established for this product or its chemical components. Exposure Controls Appropriate Engineering Controls: Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation, especially in confined areas. Ensure all national/local regulations are observed. Personal Protective Equipment: Protective clothing. Safety glasses. Gloves. If insufficient ventilation: wear respiratory protection. Materials for Protective Clothing: Chemically resistant materials and fabrics. Hand Protection: Wear chemically resistant protective gloves. Eye Protection: Chemical goggles or safety glasses. Skin and Body Protection: Wear suitable protective clothing. Respiratory Protection: Use a NIOSH-approved respirator or self-contained breathing apparatus when using in a poorly ventilated area. Other Information: When using, do not eat, drink or smoke. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Information on Basic Physical and Chemical Properties Physical State : Liquid Appearance : Light Tan, Milky Odor : Sweet Odor Threshold : Not available pH : 2.5 - 3.5 Relative Evaporation Rate (butylacetate=1) : Not available Melting/Freezing Point : Not available Boiling Point : 100 °C (212 Flash Point : Not available Auto-ignition Temperature : Not available Decomposition Temperature : Not available Flammability (solid, gas) : Not available Upper and Lower Flammable Limits : Not available Vapor Pressure : Not available Relative Vapor Density at 20 °C : Not available Specific Gravity/Relative Density : 1.08 g/cm³ @ 25 °C (77 Solubility : Not available Partition coefficient: n-octanol/water : Not available Viscosity, Dynamic : 4000 - 6000 cP @ 25 °C (77 Explosion Data – Sensitivity to Mechanical Impact : Not expected to present an explosion hazard due to mechanical impact. Explosion Data – Sensitivity to Static Discharge : Not expected to present an explosion hazard due to static discharge. SECTION 10: STABILITY AND REACTIVITY Reactivity: Hazardous reactions will not occur under normal conditions. Chemical Stability: Stable under recommended handling and storage conditions (see section Possibility of Hazardous Reactions: Hazardous polymerization will not occur. Conditions to Avoid: Direct sunlight. Extremely high or low temperatures. Incompatible Materials: Strong acids, strong bases, strong oxidizers, and materials that react with water. Hazardous Decomposition Products: Carbon oxides (CO, CO2). Oxides of aluminum. Page 319 of 871 Page 319 of 871 Page 319 of 871 Page 319 of 871 ---PAGE BREAK--- Gorilla Wood Glue Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/26/2014 EN (English US) 4/5 SECTION 11: TOXICOLOGICAL INFORMATION Information on Toxicological Effects - Product LD50 and LC50 Data: Not available Skin Corrosion/Irritation: Not classified (pH: 2.5 - 3.5) Serious Eye Damage/Irritation: Not classified (pH: 2.5 - 3.5) Respiratory or Skin Sensitization: Not classified Germ Cell Mutagenicity: Not classified Teratogenicity: Not available Carcinogenicity: Not classified Specific Target Organ Toxicity (Repeated Exposure): Not classified Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): Not classified Aspiration Hazard: Not classified Inhalation: None expected under normal conditions of use. Skin Contact: May cause mild skin irritation. Eye Contact: May cause mild eye irritation. Ingestion: Ingestion may be harmful or have adverse effects. Chronic Not applicable Information on Toxicological Effects - Ingredient(s) LD50 and LC50 Data: Propylene glycol phenyl ether (770-35-4) LD50 Oral Rat 2830 mg/kg LD50 Dermal Rat > 2000 Vinyl acetate polymer (Trade Secret) IARC Group 3 SECTION 12: ECOLOGICAL INFORMATION Toxicity Not available Persistence and Degradability Not available Bioaccumulative Potential Not available Mobility in Soil Not available Other Adverse Effects Avoid release to the environment. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, provincial, territorial and international regulations. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Not regulated for transport 14.2 In Accordance with IMDG Not regulated for transport 14.3 In Accordance with IATA Not regulated for transport 14.4 In Accordance with TDG Not regulated for transport 14.5 In Accordance with Mexico Transport Not regulated for transport SECTION 15: REGULATORY INFORMATION US Federal Regulations Water (7732-18-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory Vinyl acetate polymer (Trade Secret) Listed on the United States TSCA (Toxic Substances Control Act) inventory Propylene glycol phenyl ether (770-35-4) Listed on the United States TSCA (Toxic Substances Control Act) inventory Acute Toxicity: Not classified Page 320 of 871 Page 320 of 871 Page 320 of 871 Page 320 of 871 ---PAGE BREAK--- Gorilla Wood Glue Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/26/2014 EN (English US) 5/5 US State Regulations Neither this product nor its chemical components appear on any US state lists. Canadian Regulations WHMIS Classification Uncontrolled product according to WHMIS classification criteria Water (7732-18-5) Listed on the Canadian DSL (Domestic Substances List) inventory. WHMIS Classification Uncontrolled product according to WHMIS classification criteria Vinyl acetate polymer (Trade Secret) Listed on the Canadian DSL (Domestic Substances List) inventory. Aluminium chloride, hexahydrate (7784-13-6) WHMIS Classification Class E - Corrosive Material Propylene glycol phenyl ether (770-35-4) Listed on the Canadian DSL (Domestic Substances List) inventory. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all of the information required by CPR. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date : 08/26/2014 Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200. GHS Full Text Phrases: Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category 1 Eye Irrit. 2A Serious eye damage/eye irritation Category 2A Skin Irrit. 2 Skin corrosion/irritation Category 2 STOT SE 3 Specific target organ toxicity (single exposure) Category 3 H315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation H400 Very toxic to aquatic life Party Responsible for the Preparation of This Document The Gorilla Glue Company +1 [PHONE REDACTED] The information presented in this Safety Data Sheet was prepared by qualified personnel and to the best of our knowledge is true and accurate. The information and recommendations are furnished for this product with the understanding that the purchaser will independently determine the suitability of the product for this purpose. This data does not constitute a warranty, expressed or implied, statutory or otherwise, nor is it representation for which The Gorilla Glue Company assumes legal responsibility. The data is submitted for the user’s information and consideration only. Any use of this product must be determined by the user to be in accordance with applicable federal, state, provincial and local laws and regulations. North America GHS US 2012 & WHMIS Gorilla Wood Glue Page 321 of 871 Page 321 of 871 Page 321 of 871 Page 321 of 871 ---PAGE BREAK--- Page 322 of 871 Page 322 of 871 Page 322 of 871 Page 322 of 871 ---PAGE BREAK--- Page 323 of 871 Page 323 of 871 Page 323 of 871 Page 323 of 871 ---PAGE BREAK--- Page 324 of 871 Page 324 of 871 Page 324 of 871 Page 324 of 871 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Print Date: 07 Apr 2008 ®(TM)*Trademark of The Dow Chemical Company ("Dow") or an affiliated company of Dow Page 1 of 13 The Dow Chemical Company encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1. Product and Company Identification Product Name GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP COMPANY IDENTIFICATION The Dow Chemical Company 2030 Willard H. Dow Center Midland, MI 48674 USA Customer Information Number: [PHONE REDACTED] EMERGENCY TELEPHONE NUMBER 24-Hour Emergency Contact: [PHONE REDACTED] Local Emergency Contact: [PHONE REDACTED] 2. Hazards Identification Emergency Overview Color: Off-white Physical State: Foam Odor: Characteristic Hazards of product: DANGER! Flammable gas - May cause flash fire. May cause allergic skin reaction. May cause allergic respiratory reaction. May cause eye irritation. May cause skin irritation. Vapor reduces oxygen available for breathing. May cause anesthetic effects. May cause respiratory tract irritation. Vapors may travel a long distance; ignition and/or flash back may occur. Evacuate area. Keep upwind of spill. Stay out of low areas. Aerosol cans exposed to fire can rupture becoming flaming projectiles. Elevated temperatures can cause hazardous polymerization. Toxic fumes may be released in fire situations. Containers are under high pressure. Avoid temperatures above 49 °C (120 OSHA Hazard Communication Standard Material Safety Data Sheet The Dow Chemical Company Page 325 of 871 Page 325 of 871 Page 325 of 871 Page 325 of 871 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 2 of 13 This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Potential Health Effects Eye Contact: May cause eye irritation. May cause slight temporary corneal injury. Skin Contact: Prolonged contact may cause moderate skin irritation with local redness. Material may stick to skin causing irritation upon removal. May stain skin. Skin Absorption: Prolonged skin contact is unlikely to result in absorption of harmful amounts. Skin Sensitization: Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with isocyanates may play a role in respiratory sensitization. Inhalation: In confined or poorly ventilated areas, vapor can easily accumulate and can cause unconsciousness and death due to displacement of oxygen. Excessive exposure may cause irritation to upper respiratory tract (nose and throat) and lungs. May cause pulmonary edema (fluid in the lungs.) Effects may be delayed. May cause central nervous system depression. of excessive exposure may be anesthetic or narcotic effects; dizziness and drowsiness may be observed. Excessive exposure may increase sensitivity to epinephrine and increase myocardial irritability (irregular heartbeats). Decreased lung function has been associated with overexposure to isocyanates. Respiratory Sensitization: May cause allergic respiratory response. MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in individuals already sensitized. Asthma-like may include coughing, difficult breathing and a feeling of tightness in the chest. Occasionally, breathing difficulties may be life threatening. Ingestion: Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury. Observations in animals include: Gastrointestinal irritation. Effects of Repeated Exposure: Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after repeated excessive exposures to MDI/polymeric MDI aerosols. Contains component(s) which have been reported to cause effects on the following organs in animals: Kidney. Liver. Bone marrow. Contains a component which is reported to be a weak organophosphate-type cholinesterase inhibitor. Excessive exposure may produce organophosphate type cholinesterase inhibition. Signs and of excessive exposure may be headache, dizziness, incoordination, muscle twitching, tremors, nausea, abdominal cramps, diarrhea, sweating, pinpoint pupils, blurred vision, salivation, tearing, tightness in chest, excessive urination, convulsions. Cancer Information: Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory irritation and lung injury. Current exposure guidelines are expected to protect against these effects reported for MDI. Birth Defects/Developmental Effects: In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only at high doses which were toxic to the mother. Component CAS # Amount Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 15.0 - 30.0 % Isocyanic acid, polymethylenepolyphenylene ester, polymer with .alpha.,.alpha.',.alpha.''-1,2,3- propanetriyltris[.omega.-hydroxypoly 57029-46-6 30.0 - 60.0 % Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol coopolymer 53862-89-8 15.0 - 30.0 % Isobutane 75-28-5 7.0 - 13.0 % Paraffin waxes and Hydrocarbon waxes, chlorinated 63449-39-8 5.0 - 10.0 % Tris(1-chloro-2-propyl) phosphate 13674-84-5 5.0 - 10.0 % Propane 74-98-6 1.0 - 5.0 % Methyl ether 115-10-6 1.0 - 5.0 % 4,4' -Methylenediphenyl diisocyanate 101-68-8 5.0 - 10.0 % Note: CAS 101-68-8 is an MDI isomer that is part of CAS 9016-87-9. 3. Composition Information Page 326 of 871 Page 326 of 871 Page 326 of 871 Page 326 of 871 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 3 of 13 4. First-aid measures Eye Contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5 minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist. Skin Contact: Remove material from skin immediately by washing with soap and plenty of water. Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists. Wash clothing before reuse. An MDI skin decontamination study demonstrated that cleaning very soon after exposure is important, and that a skin cleanser or corn oil may be more effective than soap and water. Discard items which cannot be decontaminated, including leather articles such as shoes, belts and watchbands. Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility. Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel. Notes to Physician: Maintain adequate ventilation and oxygenation of the patient. May cause asthma-like (reactive airways) Bronchodilators, expectorants, antitussives and corticosteroids may be of help. May cause respiratory sensitization or asthma-like Bronchodilators, expectorants and antitussives may be of help. Treat bronchospasm with inhaled beta2 agonist and oral or parenteral corticosteroids. Respiratory including pulmonary edema, may be delayed. Persons receiving significant exposure should be observed 24-48 hours for signs of respiratory distress. Exposure may increase "myocardial irritability". Do not administer sympathomimetic drugs such as epinephrine unless absolutely necessary. If you are sensitized to diisocyanates, consult your physician regarding working with other respiratory irritants or sensitizers. Although cholinesterase depression has been reported with this material, it is not of benefit in determining exposure and need not be considered in the treatment of persons exposed to the material. No specific antidote. Treatment of exposure should be directed at the control of and the clinical condition of the patient. Medical Conditions Aggravated by Exposure: Excessive exposure may aggravate preexisting asthma and other respiratory disorders (e.g. bronchitis, reactive airways dysfunction 5. Fire Fighting Measures Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Do not use direct water stream. Straight or direct water streams may not be effective to extinguish fire. Alcohol resistant foams (ATC type) are preferred. General purpose foams (including AFFF) or protein foams may function, but will be less effective. Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay upwind. Keep out of low areas where gases (fumes) can accumulate. Water may not be effective in extinguishing fire. Do not use direct water stream. May spread fire. Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Eliminate ignition sources. Move container from fire area if this is possible without hazard. Use water spray to cool fire- exposed containers and fire-affected zone until fire is out. Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer to the relevant sections. Unusual Fire and Explosion Hazards: Contains flammable propellant. Aerosol cans exposed to fire can rupture and become flaming projectiles. Propellant release may result in a fireball. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Dense smoke is produced when product burns. Page 327 of 871 Page 327 of 871 Page 327 of 871 Page 327 of 871 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 4 of 13 Hazardous Combustion Products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Nitrogen oxides. Isocyanates. Hydrogen chloride. Carbon monoxide. Carbon dioxide. 6. Accidental Release Measures Steps to be Taken if Material is Released or Spilled: Contain spilled material if possible. Ground and bond all containers and handling equipment. Isolate area until gas has dispersed. Use non- sparking tools in cleanup operations. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Collect in suitable and properly labeled containers. Absorb with materials such as: Clay. Dirt. Milsorb®. Sand. Sawdust. Vermiculite. See Section 10 for more specific information. See Section 13, Disposal Considerations, for additional information. Personal Precautions: Evacuate area. Only trained and properly protected personnel must be involved in clean-up operations. Keep personnel out of low areas. Keep personnel out of confined or poorly ventilated areas. Keep upwind of spill. Ventilate area of leak or spill. No smoking in area. For large spills, warn public of downwind explosion hazard. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Vapor explosion hazard. Keep out of sewers. See Section 10 for more specific information. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection. Refer to Section 7, Handling, for additional precautionary measures. Environmental Precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. 7. Handling and Storage Handling General Handling: Keep away from heat, sparks and flame. Avoid contact with eyes. Avoid contact with skin and clothing. Avoid prolonged or repeated contact with skin. Avoid breathing vapor. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. Keep out of reach of children. No smoking, open flames or sources of ignition in handling and storage area. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Contents under pressure. Do not puncture or incinerate container. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers. Do not enter confined spaces unless adequately ventilated. Never use air pressure for transferring product. Use of non-sparking or explosion-proof equipment may be necessary, depending upon the type of operation. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION. Storage Minimize sources of ignition, such as static build-up, heat, spark or flame. Store in a dry place. See Section 10 for more specific information. Shelf life: Use within 12 Months 20 - 30 °C 8. Exposure Controls / Personal Protection Exposure Limits Component List Type Value I 4,4' -Methylenediphenyl diisocyanate ACGIH TWA 0.005 ppm Page 328 of 871 Page 328 of 871 Page 328 of 871 Page 328 of 871 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 5 of 13 OSHA Table Z-1 Ceiling 0.2 mg/m3 0.02 ppm I Methyl ether WEEL TWA 1,880 mg/m3 1,000 ppm I Isobutane ACGIH TWA 1,000 ppm I Propane OSHA Table Z-1 PEL 1,800 mg/m3 1,000 ppm ACGIH TWA 1,000 ppm I Personal Protection Eye/Face Protection: Use safety glasses. Eye wash fountain should be located in immediate work area. Skin Protection: Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task. Remove contaminated clothing immediately, wash skin area with soap and water, and launder clothing before reuse or dispose of properly. Items which cannot be decontaminated, such as shoes, belts and watchbands, should be removed and disposed of properly. Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove barrier materials include: Butyl rubber. Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Examples of acceptable glove barrier materials include: Natural rubber ("latex"). Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Viton. Polyvinyl chloride ("PVC" or "vinyl"). NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier. Respiratory Protection: Atmospheric levels should be maintained below the exposure guideline. When atmospheric levels may exceed the exposure guideline, use an approved air-purifying respirator equipped with an organic vapor sorbent and a particle filter. For situations where the atmospheric levels may exceed the level for which an air-purifying respirator is effective, use a positive-pressure air-supplying respirator (air line or self-contained breathing apparatus). For emergency response or for situations where the atmospheric level is unknown, use an approved positive-pressure self- contained breathing apparatus or positive-pressure air line with auxiliary self-contained air supply. The following should be effective types of air-purifying respirators: Organic vapor cartridge with a particulate pre-filter. Ingestion: Use good personal hygiene. Do not consume or store food in the work area. Wash hands before smoking or eating. Engineering Controls Ventilation: Use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations. Provide general and/or local exhaust ventilation to control airborne levels below the exposure guidelines. Exhaust systems should be designed to move the air away from the source of vapor/aerosol generation and people working at this point. The odor and irritancy of this material are inadequate to warn of excessive exposure. 9. Physical and Chemical Properties Physical State Foam Color Off-white Odor Characteristic Flash Point - Closed Cup -104 °C (-155 Calculated Flammable Limits In Air Lower: No test data available Upper: No test data available Autoignition Temperature No test data available Vapor Pressure 1,151 kPa @ 55 °C Estimated Boiling Point (760 mmHg) Not applicable. Vapor Density (air = 1) No test data available Specific Gravity (H2O = 1) 1.06 Estimated Page 329 of 871 Page 329 of 871 Page 329 of 871 Page 329 of 871 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 6 of 13 Freezing Point No test data available Melting Point No test data available Solubility in Water (by weight) Insoluble pH Not applicable 10. Stability and Reactivity Stability/Instability Stable under recommended storage conditions. See Storage, Section 7. Unstable at elevated temperatures. Conditions to Avoid: Avoid temperatures above 49 °C (120 Elevated temperatures can cause container to vent and/or rupture. Exposure to elevated temperatures can cause product to decompose. Incompatible Materials: Avoid contact with: Acids. Alcohols. Amines. Ammonia. Bases. Metal compounds. Strong oxidizers. Products based on diisocyanates like TDI and MDI react with many materials to release heat. The reaction rate increases with temperature as well as with increased contact; these reactions can become violent. Contact is increased by stirring or if the other material acts as a solvent. Products based on diisocyanates such as TDI and MDI are not soluble in water and will sink to the bottom, but react slowly at the interface. The reaction forms carbon dioxide gas and a layer of solid polyurea. Reaction with water will generate carbon dioxide and heat. Hazardous Polymerization Can occur. Elevated temperatures can cause hazardous polymerization. Thermal Decomposition Decomposition products depend upon temperature, air supply and the presence of other materials. Toxic gases are released during decomposition. 11. Toxicological Information Acute Toxicity Ingestion Single dose oral LD50 has not been determined. Estimated LD50, Rat > 10,000 mg/kg Skin Absorption The LD50 has not been determined. Estimated LD50, Rabbit > 2,000 mg/kg Inhalation The LC50 has not been determined. Estimated LC50, Aerosol, Rat > 0.5 mg/l Sensitization Skin Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with isocyanates may play a role in respiratory sensitization. Respiratory May cause allergic respiratory response. MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in individuals already sensitized. Asthma-like may include coughing, difficult breathing and a feeling of tightness in the chest. Occasionally, breathing difficulties may be life threatening. Repeated Dose Toxicity Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after repeated excessive exposures to MDI/polymeric MDI aerosols. Contains component(s) which have been reported to cause effects on the following organs in animals: Kidney. Liver. Bone marrow. Contains a component which is reported to be a weak organophosphate-type cholinesterase inhibitor. Excessive exposure may produce organophosphate type cholinesterase inhibition. Signs and of excessive exposure may be headache, dizziness, incoordination, muscle twitching, Page 330 of 871 Page 330 of 871 Page 330 of 871 Page 330 of 871 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 7 of 13 tremors, nausea, abdominal cramps, diarrhea, sweating, pinpoint pupils, blurred vision, salivation, tearing, tightness in chest, excessive urination, convulsions. Chronic Toxicity and Carcinogenicity Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory irritation and lung injury. Current exposure guidelines are expected to protect against these effects reported for MDI. Developmental Toxicity In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only at high doses which were toxic to the mother. Genetic Toxicology In vitro genetic toxicity studies were negative for component(s) tested. Genetic toxicity data on MDI are inconclusive. MDI was weakly positive in some in vitro studies; other in vitro studies were negative. Animal mutagenicity studies were predominantly negative. 12. Ecological Information CHEMICAL FATE Data for Component: Diphenylmethane Diisocyanate, isomers and homologues Movement & Partitioning In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Persistence and Degradability In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. Data for Component: Isocyanic acid, polymethylenepolyphenylene ester, polymer with .alpha.,.alpha.',.alpha.''-1,2,3-propanetriyltris[.omega.-hydroxypoly Movement & Partitioning In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Persistence and Degradability In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. Data for Component: Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol coopolymer Movement & Partitioning In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Persistence and Degradability In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. Data for Component: Isobutane Movement & Partitioning Bioconcentration potential is low (BCF less than 100 or log Pow less than Potential for mobility in soil is very high (Koc between 0 and 50). Page 331 of 871 Page 331 of 871 Page 331 of 871 Page 331 of 871 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 8 of 13 Henry's Law Constant 1.19E+00 atm*m3/mole; 25 °C Measured Partition coefficient, n-octanol/water (log Pow): 2.76 Measured Partition coefficient, soil organic carbon/water (Koc): 35 Estimated Distribution in Environment: Mackay Level 1 Fugacity Model: Air Water. Biota Soil Sediment 100 % 0 % 0 % 0 % 0 % Persistence and Degradability Biodegradation may occur under aerobic conditions (in the presence of oxygen). Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 2.44E-12 cm3/s 4.4 d Estimated Theoretical Oxygen Demand: 3.58 mg/mg Data for Component: Paraffin waxes and Hydrocarbon waxes, chlorinated Movement & Partitioning Expected to be relatively immobile in soil (Koc > 5000). Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected to be an important fate process. Henry's Law Constant < 1.0E-07 atm*m3/mole; 25 °C Estimated Partition coefficient, n-octanol/water (log Pow): > 6 Estimated Persistence and Degradability Expected to degrade only slowly in the environment. Data for Component: Tris(1-chloro-2-propyl) phosphate Movement & Partitioning Bioconcentration potential is low (BCF < 100 or Log Pow < Potential for mobility in soil is low (Koc between 500 and 2000). Henry's Law Constant < 1.35E-5 atm*m3/mole; 25 °C Estimated Partition coefficient, n-octanol/water (log Pow): 2.59 Measured Partition coefficient, soil organic carbon/water (Koc): 1,300 Estimated Bioconcentration Factor (BCF): 0.8 - 4.6; common carp (Cyprinus carpio); Measured Persistence and Degradability Material is expected to biodegrade only very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 4.47E-11 cm3/s 0.24 d Estimated OECD Biodegradation Tests: Biodegradation Exposure Time Method 14 % 28 d OECD 301E Test Theoretical Oxygen Demand: 1.17 mg/mg Data for Component: Propane Movement & Partitioning Bioconcentration potential is low (BCF less than 100 or log Pow less than Potential for mobility in soil is very high (Koc between 0 and 50). Henry's Law Constant 7.07E-01 atm*m3/mole; 25 °C Measured Partition coefficient, n-octanol/water (log Pow): 2.36 Measured Partition coefficient, soil organic carbon/water (Koc): 24 - 460 Estimated Distribution in Environment: Mackay Level 1 Fugacity Model: Air Water. Biota Soil Sediment 100 % 0 % 0 % 0 % 0 % Persistence and Degradability No relevant information found. Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 1.27E-12 cm3/s 8.4 d Estimated Page 332 of 871 Page 332 of 871 Page 332 of 871 Page 332 of 871 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 9 of 13 Theoretical Oxygen Demand: 3.64 mg/mg Data for Component: Methyl ether Movement & Partitioning Bioconcentration potential is low (BCF less than 100 or log Pow less than Potential for mobility in soil is very high (Koc between 0 and 50). Henry's Law Constant 9.78E-4 atm*m3/mole; 25 °C Measured Partition coefficient, n-octanol/water (log Pow): 0.10 Measured Partition coefficient, soil organic carbon/water (Koc): 1.29 - 14 Estimated Persistence and Degradability Material is expected to biodegrade only very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 1.66E-12 cm3/s 6.4 d Estimated OECD Biodegradation Tests: Biodegradation Exposure Time Method 5 % 28 d OECD 301A Test Theoretical Oxygen Demand: 2.08 mg/mg Data for Component: 4,4' -Methylenediphenyl diisocyanate Movement & Partitioning In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Persistence and Degradability In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. ECOTOXICITY Data for Component: Diphenylmethane Diisocyanate, isomers and homologues The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Toxicity to Soil Dwelling Organisms LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg Data for Component: Isocyanic acid, polymethylenepolyphenylene ester, polymer with .alpha.,.alpha.',.alpha.''-1,2,3-propanetriyltris[.omega.-hydroxypoly The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Toxicity to Soil Dwelling Organisms LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg Data for Component: Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol coopolymer The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Toxicity to Soil Dwelling Organisms LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg Data for Component: Isobutane No relevant information found. Data for Component: Paraffin waxes and Hydrocarbon waxes, chlorinated Page 333 of 871 Page 333 of 871 Page 333 of 871 Page 333 of 871 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 10 of 13 Material is practically non-toxic to fish on an acute basis (LC50 > 100 mg/L). Material is very highly toxic to aquatic invertebrates on an acute basis (LC50/EC50 < 0.1 mg/L). Fish Acute & Prolonged Toxicity LC50, rainbow trout mykiss), static, 96 h: > 100 mg/l Aquatic Invertebrate Acute Toxicity EC50, water flea Daphnia magna, immobilization: 0.037 mg/l Data for Component: Tris(1-chloro-2-propyl) phosphate Material is toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and 100 mg/L in the most sensitive species tested). Fish Acute & Prolonged Toxicity LC50, bluegill (Lepomis macrochirus), 96 h: 84 mg/l Aquatic Invertebrate Acute Toxicity EC50, water flea Daphnia magna, 48 h, immobilization: 63 mg/l Aquatic Plant Toxicity EC50, green alga Selenastrum capricornutum, biomass growth inhibition, 96 h: 47 mg/l EC50, alga Scenedesmus sp., biomass growth inhibition, 72 h: 45 mg/l Toxicity to Micro-organisms EC50, OECD 209 Test; activated sludge, respiration inhibition, 3 h: 784 mg/l Data for Component: Propane No relevant information found. Data for Component: Methyl ether Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Fish Acute & Prolonged Toxicity LC50, guppy (Poecilia reticulata), 96 h: > 4,000 mg/l Aquatic Invertebrate Acute Toxicity LC50, water flea Daphnia magna, 48 h: > 4,000 mg/l Data for Component: 4,4' -Methylenediphenyl diisocyanate The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Toxicity to Soil Dwelling Organisms LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg 13. Disposal Considerations DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. DOW HAS NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed, permitted: Incinerator or other thermal destruction device. As a service to its customers, Dow can provide names of information resources to help identify waste management companies and other facilities which recycle, reprocess or manage chemicals or plastics, and that manage used drums. Telephone Dow's Customer Information Group at 1-[PHONE REDACTED] or 1-989- 832-1556 or 1-[PHONE REDACTED] (Canada) for further details. Page 334 of 871 Page 334 of 871 Page 334 of 871 Page 334 of 871 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 11 of 13 14. Transport Information DOT Non-Bulk CONSUMER COMMODITY RECLASSIFIED AS ORM-D MATERIAL DOT Bulk NOT AVAILABLE IN BULK CONTAINERS IMDG Proper Shipping Name: AEROSOLS, FLAMMABLE Hazard Class: 2.1 ID Number: UN1950 EMS Number: F-D,S-U LIMITED QUANTITY ICAO/IATA Proper Shipping Name: AEROSOLS, FLAMMABLE Hazard Class: 2.1 ID Number: UN1950Cargo Packing Instruction: 203 Passenger Packing Instruction: 203 LIMITED QUANTITY This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Additional transportation system information can be obtained through an authorized sales or customer service representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material. 15. Regulatory Information OSHA Hazard Communication Standard This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Sections 311 and 312 Immediate (Acute) Health Hazard Yes Delayed (Chronic) Health Hazard Yes Fire Hazard Yes Reactive Hazard No Sudden Release of Pressure Hazard Yes Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Section 313 This product contains the following substances which are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and which are listed in 40 CFR 372. Component CAS # Amount 4,4' -Methylenediphenyl diisocyanate 101-68-8 5.0 - 10.0 % Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 15.0 - 30.0 % (Worker and Community Right-To-Know Act): Hazardous Substances List and/or Environmental Hazardous Substance List: The following product components are cited in the Hazardous Substance List and/or the Environmental Substance List, and are present at levels which require reporting. Page 335 of 871 Page 335 of 871 Page 335 of 871 Page 335 of 871 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 12 of 13 Component CAS # Amount 4,4' -Methylenediphenyl diisocyanate 101-68-8 5.0 - 10.0 % Methyl ether 115-10-6 1.0 - 5.0 % Propane 74-98-6 1.0 - 5.0 % Isobutane 75-28-5 7.0 - 13.0 % (Worker and Community Right-To-Know Act): Special Hazardous Substances List: To the best of our knowledge, this product does not contain chemicals at levels which require reporting under this statute. California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986) This product contains no listed substances known to the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute. US. Toxic Substances Control Act All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.30 CEPA - Domestic Substances List (DSL) All substances contained in this product are listed on the Canadian Domestic Substances List (DSL) or are not required to be listed. 16. Other Information Recommended Uses and Restrictions Polyurethane foam. Revision Identification Number: 68906 / 1001 / Issue Date 01/31/2008 / Version: 2.0 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. Legend N/A Not available W/W Weight/Weight OEL Occupational Exposure Limit STEL Short Term Exposure Limit TWA Time Weighted Average ACGIH American Conference of Governmental Industrial Hygienists, Inc. DOW IHG Dow Industrial Hygiene Guideline WEEL Workplace Environmental Exposure Level HAZ_DES Hazard Designation Action Level A value set by OSHA that is lower than the PEL which will trigger the need for activities such as exposure monitoring and medical surveillance if exceeded. The Dow Chemical Company urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have Page 336 of 871 Page 336 of 871 Page 336 of 871 Page 336 of 871 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 13 of 13 obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version. Page 337 of 871 Page 337 of 871 Page 337 of 871 Page 337 of 871 ---PAGE BREAK--- Page 338 of 871 Page 338 of 871 Page 338 of 871 Page 338 of 871 ---PAGE BREAK--- Page 339 of 871 Page 339 of 871 Page 339 of 871 Page 339 of 871 ---PAGE BREAK--- Page 340 of 871 Page 340 of 871 Page 340 of 871 Page 340 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 06-Jul-2010 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code DN4760 Product name GROOVY Recommended Use Sealant Supplier Drummond American A Lawson Products Company 600 Corporate Woods Parkway Vernon Hills, IL 60061 (847) 913-9313 Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions Pre-existing respiratory conditions may be aggravated by exposure to this product. Pre-existing skin conditions may be aggravated by exposure to this product. Principal Routes of Exposure Eyes. Skin. Ingestion. Inhalation. Potential health effects Eyes Severe irritation. Redness. Tearing. Blurred vision. Skin Prolonged skin contact may defat the skin and produce dermatitis. Repeated or prolonged exposure may cause:. Skin Irritation. Redness. Sensitization. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. Inhalation Harmful by inhalation. Headaches. Dizziness. Nausea. Fatigue. Vomiting. Central nervous system depression. Narcosis. Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Individuals with lung or breathing problems or prior reaction to isocyanates must not be exposed to vapor or spray mist. . Ingestion Irritating to mouth, throat and stomach. Gastrointestinal irritation. Nausea. Vomiting. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Stoddard solvent 8052-41-3 5-10 Toluene diisocyanate 26471-62-5 5-10 4. FIRST AID MEASURES Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek medical attention. Skin contact Remove and wash contaminated clothing before re-use. Wash area thoroughly with soap and water. Seek medical attention if irritation persists. Ingestion Do not induce vomiting without medical advice. Drink plenty of water. Keep head below hips if vomiting occurs. Never give anything by mouth to an unconscious person. Seek medical attention. Inhalation Remove from exposure. Artificial respiration and/or oxygen may be necessary. Immediate medical attention is required. 5. FIRE FIGHTING MEASURES Flash point °C 62.78 Flash point °F 145 Method Tag Closed Cup Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 9.5 Lower 0.9 Suitable extinguishing media Carbon dioxide (CO2). Dry chemical. Water fog. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Fire and Explosion Hazards Combustible liquid. Vapors may form explosive mixture in air between upper and lower explosive limits which can be ignited by many sources, such as pilot lights, open flames, electrical motors and switches. Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Flash back possible over considerable distance. Empty containers contain residue and/or vapors. Do not weld, cut, pressurize, braze, solder, drill, grind, or expose such containers to heat, sparks, flame, static electricity, or other sources of ignition. They may explode and cause injury or death. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat . Water or foam may cause frothing. Sensitivity to shock No information available. Sensitivity to static discharge No information available. Page 1 / 3 Emergency Overview Combustible material. Irritant. Contains isocyanates . Page 341 of 871 Page 341 of 871 Page 341 of 871 Page 341 of 871 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Personnel should wear appropriate protective equipment. Follow all precautions for handling. Please refer to appropriate sections of MSDS for additional information. Ventilate area to maintain exposure below permissible exposure limits. Eliminate all sources of ignition. Evacuate area of unprotected and unnecessary personnel. Shut off source of leak if safe to do so. Dike or dam large spills. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Pick up and transfer to properly labelled containers. 7. HANDLING AND STORAGE Handling Ensure adequate ventilation. Keep out of reach of children. Take precautionary measures against static discharges. Ground and bond containers when transferring material. Storage Keep containers closed in a dry, cool and well-ventilated place. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Toluene diisocyanate - - 0.005 ppm 0.02 ppm Stoddard solvent 2900 mg/m3 500 ppm - 100 ppm - Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Hygiene measures Avoid contact with skin, eyes and clothing. Wash hands before breaks and at the end of workday. When using, do not eat, drink or smoke. Handle in accordance with good industrial hygiene and safety practice. Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Hand Protection For prolonged or repeated skin contact, use a chemically resistant glove such as nitrile or neoprene. Wash hands with soap and water after removing gloves. Dry hands thoroughly before re-applying gloves. . Eye protection Use safety eyewear designed to protect against splash of liquids. Skin and body protection None necessary under normal conditions Other Protective Equipment Wear appropriate clothing to prevent skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Liquid Color Various Odor Solvent Odor Threshold No information available pH Not Applicable Specific Gravity 1.10 Vapor pressure No data available Vapor density >Air Evaporation Rate <1 (Butyl Acetate = 1) Water solubility soluble VOC Content 104 g/l Partition Coefficient (n-octanol/water) No data available Boiling point/range °C 86.11-251.11 Boiling point/range °F 187-484 Melting point/range °C No data available Melting point/range °F No data available Flash point °C 62.78 Flash point °F 145 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions. Conditions to avoid Avoid extreme heat. Heat, flames and sparks. Incompatability Strong oxidizing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon oxides. Polymerization Hazardous polymerization does not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat) LD50 (dermal,rat/rabbi t) LC50 (inhalation,rat) Toluene diisocyanate 26471-62-5 3360 mg/kg 10000 mg/kg 0.1 mg/L 13.9 ppm 66 ppm Stoddard solvent 8052-41-3 - - - Synergistic Products None known Specific Hazards Reports have associated repeated and prolonged occupational exposure to solvents with permanent brain damage. Potential health effects Page 2 / 3 Product code DN4760 Product name GROOVY Page 342 of 871 Page 342 of 871 Page 342 of 871 Page 342 of 871 ---PAGE BREAK--- Sensitization None known Chronic toxicity See Section 2 . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects Impaired lung function (reduced ventilation capacity) has been associated with overexposure to isocyanates. Long term exposure to vapor may cause kidney damage. Long term exposure to vapor may cause liver damage. Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Toluene diisocyanate Listed Group 2B Not Listed Listed Listed Stoddard solvent Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT Not Regulated TDG Not Regulated IMDG/IMO Not Regulated IATA Not Regulated MEX Not Regulated 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Toluene diisocyanate Listed Chemical Name New Jersey - RTK - RTK California Prop. 65 Toluene diisocyanate Not Listed Listed Carcinogen Stoddard solvent Listed Listed Not Listed Chemical Name EINECS DSL NDSL TSCA Toluene diisocyanate X X - X Stoddard solvent X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION HMIS Health - 2 Flammability - 2 Physical Hazard - 0 Prepared By H. Buck, Regulatory Affairs Manager The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 3 / 3 Product code DN4760 Product name GROOVY Page 343 of 871 Page 343 of 871 Page 343 of 871 Page 343 of 871 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Product identifier Hercules Megaloc Other means of identification Product code 7305E Synonyms Part Numbers: 15802, 15804, 15806, 15808, 15811, 15814, 15816, 15818, 15821 Recommended use Pipe thread sealant. Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Company Name HCC Holdings, Inc. an Oatey Affiliate Address 4700 West 160th Street Cleveland, OH 44135 Telephone [PHONE REDACTED] E-mail [EMAIL REDACTED] Transport Emergency Chemtrec 1-[PHONE REDACTED] (Outside the US 1-[PHONE REDACTED]) Emergency First Aid 1-[PHONE REDACTED] Contact person MSDS Coordinator 2. Hazard(s) identification Not classified. Physical hazards Not classified. Health hazards Not classified. OSHA defined hazards Label elements None. Hazard symbol Signal word None. Hazard statement The mixture does not meet the criteria for classification. Precautionary statement Prevention Observe good industrial hygiene practices. Response Wash hands after handling. Storage Store away from incompatible materials. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise classified (HNOC) Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. The thermal decomposition vapors of fluorinated polymers may cause polymer fume fever. 3. Composition/information on ingredients Mixtures 64741-88-4 30-60 Petroleum-based Lubricating Oil CAS number % Chemical name 1332-58-7 10-30 Kaolin 14807-96-6 10-30 Talc 546-93-0 1-10 Magnesium carbonate 26125-61-1 1-5 Poly (P-phenylenediamine terephthalamide) 13463-67-7 1-5 Titanium Dioxide 112945-52-5 0.5-1.5 Silica, amorphous, fumed Hercules Megaloc SDS US 924536 Version 01 Revision date: - Issue date: 05-February-2015 1 / 7 Page 344 of 871 Page 344 of 871 Page 344 of 871 Page 344 of 871 ---PAGE BREAK--- 14808-60-7 <1 silica (Quartz) *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Call a physician if develop or persist. Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists. Eye contact Rinse with water. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Get medical attention if occur. Most important acute and delayed Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Indication of immediate medical attention and special treatment needed Treat General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire fighting equipment/instructions Move containers from fire area if you can do so without risk. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up This product is miscible in water. Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Avoid prolonged exposure. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Store in original closed container. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Type Form Components PEL 5 mg/m3 Respirable fraction. Kaolin (CAS 1332-58-7) 15 mg/m3 Total dust. Hercules Megaloc SDS US 924536 Version 01 Revision date: - Issue date: 05-February-2015 2 / 7 Page 345 of 871 Page 345 of 871 Page 345 of 871 Page 345 of 871 ---PAGE BREAK--- US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Type Form Components PEL 5 mg/m3 Respirable fraction. Magnesium carbonate (CAS 546-93-0) 15 mg/m3 Total dust. PEL 5 mg/m3 Mist. Petroleum-based Lubricating Oil (CAS 64741-88-4) 2000 mg/m3 500 ppm PEL 15 mg/m3 Total dust. Titanium Dioxide (CAS 13463-67-7) US. OSHA Table Z-3 (29 CFR 1910.1000) Value Type Form Components TWA 0.3 mg/m3 Total dust. silica (Quartz) (CAS 14808-60-7) 0.1 mg/m3 Respirable. TWA 0.3 mg/m3 Total dust. Talc (CAS 14807-96-6) 0.1 mg/m3 Respirable. 20 2.4 Respirable. US. ACGIH Threshold Limit Values Value Type Form Components TWA 0.025 mg/m3 Respirable fraction. silica (Quartz) (CAS 14808-60-7) TWA 2 mg/m3 Respirable fraction. Kaolin (CAS 1332-58-7) TWA 5 mg/m3 Inhalable fraction. Petroleum-based Lubricating Oil (CAS 64741-88-4) TWA 2 mg/m3 Respirable fraction. Talc (CAS 14807-96-6) TWA 10 mg/m3 Titanium Dioxide (CAS 13463-67-7) US. NIOSH: Pocket Guide to Chemical Hazards Value Type Form Components TWA 0.05 mg/m3 Respirable dust. silica (Quartz) (CAS 14808-60-7) TWA 5 mg/m3 Respirable. Kaolin (CAS 1332-58-7) 10 mg/m3 Total TWA 5 mg/m3 Respirable. Magnesium carbonate (CAS 546-93-0) 10 mg/m3 Total STEL 10 mg/m3 Mist. Petroleum-based Lubricating Oil (CAS 64741-88-4) TWA 5 mg/m3 Mist. TWA 2 mg/m3 Respirable. Talc (CAS 14807-96-6) Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear appropriate chemical resistant gloves. Hercules Megaloc SDS US 924536 Version 01 Revision date: - Issue date: 05-February-2015 3 / 7 Page 346 of 871 Page 346 of 871 Page 346 of 871 Page 346 of 871 ---PAGE BREAK--- Other Wear suitable protective clothing. Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Liquid paste. Color Blue. Odor Odorless. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range Not available. Flash point > 212.0 °F 100.0 Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Not available. Flammability limit - upper Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure Not available. Vapor density Not available. Relative density 1.2 g/cm3 Solubility(ies) Solubility (water) Soluble Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity 30000 cP Other information VOC (Weight 4 g/l 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Conditions to avoid Contact with incompatible materials. Incompatible materials Acids. Hazardous decomposition products No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Inhalation Prolonged inhalation may be harmful. Hercules Megaloc SDS US 924536 Version 01 Revision date: - Issue date: 05-February-2015 4 / 7 Page 347 of 871 Page 347 of 871 Page 347 of 871 Page 347 of 871 ---PAGE BREAK--- Skin contact No adverse effects due to skin contact are expected. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Expected to be a low ingestion hazard. related to the physical, chemical and toxicological characteristics Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Information on toxicological effects Acute toxicity Not available. Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity In 1997, IARC (the International Agency for Research on Cancer) concluded that silica inhaled from occupational sources can cause lung cancer in humans. However in making the overall evaluation, IARC noted that "carcinogenicity was not detected in all industrial circumstances studied. Carcinogenicity may be dependent on inherent characteristics of the silica or on external factors affecting its biological activity or distribution of its polymorphs." (IARC Monographs on the evaluation of the carcinogenic risks of chemicals to humans, Silica, silicates dust and organic fibres, 1997, Vol. 68, IARC, Lyon, France.) IARC Monographs. Overall Evaluation of Carcinogenicity silica (Quartz) (CAS 14808-60-7) 1 Carcinogenic to humans. Petroleum-based Lubricating Oil (CAS 64741-88-4) 3 Not classifiable as to carcinogenicity to humans. Titanium Dioxide (CAS 13463-67-7) 2B Possibly carcinogenic to humans. NTP Report on Carcinogens silica (Quartz) (CAS 14808-60-7) Known To Be Human Carcinogen. Petroleum-based Lubricating Oil (CAS 64741-88-4) Known To Be Human Carcinogen. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Chronic effects Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. Further information This product has no known adverse effect on human health. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hercules Megaloc SDS US 924536 Version 01 Revision date: - Issue date: 05-February-2015 5 / 7 Page 348 of 871 Page 348 of 871 Page 348 of 871 Page 348 of 871 ---PAGE BREAK--- Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Not established. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. Massachusetts RTK - Substance List silica (Quartz) (CAS 14808-60-7) Kaolin (CAS 1332-58-7) Magnesium carbonate (CAS 546-93-0) Petroleum-based Lubricating Oil (CAS 64741-88-4) Talc (CAS 14807-96-6) Titanium Dioxide (CAS 13463-67-7) US. New Jersey Worker and Community Right-to-Know Act silica (Quartz) (CAS 14808-60-7) Kaolin (CAS 1332-58-7) Magnesium carbonate (CAS 546-93-0) Hercules Megaloc SDS US 924536 Version 01 Revision date: - Issue date: 05-February-2015 6 / 7 Page 349 of 871 Page 349 of 871 Page 349 of 871 Page 349 of 871 ---PAGE BREAK--- Talc (CAS 14807-96-6) Titanium Dioxide (CAS 13463-67-7) US. Worker and Community Right-to-Know Law silica (Quartz) (CAS 14808-60-7) Kaolin (CAS 1332-58-7) Talc (CAS 14807-96-6) Titanium Dioxide (CAS 13463-67-7) US. Rhode Island RTK Not regulated. US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer. US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance silica (Quartz) (CAS 14808-60-7) Di-''isononyl'' phthalate (CAS 28553-12-0) Titanium Dioxide (CAS 13463-67-7) International Inventories Country(s) or region Inventory name On inventory (yes/no)* Domestic Substances List (DSL) Yes Canada *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Toxic Substances Control Act (TSCA) Inventory Yes United States & Puerto Rico 16. Other information, including date of preparation or last revision Issue date 05-February-2015 Revision date - Version # 01 HMIS® ratings Health: 0 Flammability: 1 Physical hazard: 0 NFPA ratings 0 0 1 Disclaimer HCC Holdings Inc. an Oatey Affiliate cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. Hercules Megaloc SDS US 924536 Version 01 Revision date: - Issue date: 05-February-2015 7 / 7 Page 350 of 871 Page 350 of 871 Page 350 of 871 Page 350 of 871 ---PAGE BREAK--- Material Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION Product Name IMPERVEX LATEX HIGH GLOSS METAL & WOOD ENAMEL Product Code K3093B Product Class WATER THINNED PAINT Color All 2. COMPOSITION INFORMATION ON COMPONENTS Hazardous Components Chemical Name CAS-No Weight % (max) Titanium dioxide 13463-67-7 3 - 7% Ethylene glycol 107-21-1 1 - 5% 3. HAZARDS IDENTIFICATION Potential Health Effects Principal Routes of Exposure Eye contact, skin contact and inhalation. Acute Effects Eyes May cause slight irritation. Skin Substance may cause slight skin irritation. Page 1 / 9 Revision Date: 24-Feb-2011 Emergency Telephone Number(s) CANUTEC: [PHONE REDACTED] Emergency Overview Revision Number: 1 Vapors may be irritating to eyes, nose, throat, and lungs. May cause skin irritation and/or dermatitis. Manufacturer Benjamin Moore & Co. 101 Paragon Drive Montvale, NJ 07645 Phone: [PHONE REDACTED] www.benjaminmoore.com Appearance liquid Odor little or no odor Page 351 of 871 Page 351 of 871 Page 351 of 871 Page 351 of 871 ---PAGE BREAK--- Inhalation May cause irritation of respiratory tract. Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Chronic Effects Repeated contact may cause allergic reactions in very susceptible persons. See Section 11 for additional Toxicological information. Aggravated Medical Conditions None known Note: The PPE rating has intentionally been left blank. Choose appropriate PPE that will protect employees from the hazards the material will present under the actual normal conditions of use. Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings are not required on under 29 CFR 1910.1200, the preparer, has choosen to provide them. HMIS® ratings are to be used only in conjunction with a fully implemented HMIS® program by workers who have received appropriate HMIS® training. HMIS® is a registered trade and service mark of the NPCA. HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. 4. FIRST AID MEASURES General Advice No hazards which require special first aid measures. Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Skin Contact Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. Inhalation Move to fresh air. If persist, call a physician. Ingestion Clean mouth with water and afterwards drink plenty of water. Consult a physician if necessary. Notes To Physician Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Protective Equipment And Precautions For Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 2 / 9 Reactivity: 0 Revision Date: 24-Feb-2011 PPE: - HMIS HMIS Legend 0 - Minimal Hazard 1 - Slight Hazard 2 - Moderate Hazard 3 - Serious Hazard 4 - Severe Hazard * - Chronic Hazard X - Consult your supervisor or S.O.P. for "Special" handling instructions. Health: 1* K3093B - IMPERVEX LATEX HIGH GLOSS METAL & WOOD ENAMEL Flammability: 0 Page 352 of 871 Page 352 of 871 Page 352 of 871 Page 352 of 871 ---PAGE BREAK--- Specific Hazards Arising From The Chemical Closed containers may rupture if exposed to fire or extreme heat. Sensitivity To Mechanical Impact No Sensitivity To Static Discharge No Flash Point Data Flash Point Not applicable Flash Point Not applicable Flash Point Method Not applicable Flammability Limits In Air Upper Explosion Limit Not applicable Lower Explosion Limit Not applicable The ratings assigned are only suggested ratings, the contractor/employer has ultimate responsibilities for NFPA ratings where this system is used. Additional information regarding the NFPA rating system is available from the National Fire Protection Agency (NFPA) at www.nfpa.org. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Environmental Precautions Prevent further leakage or spillage if safe to do so. Methods For Clean-Up Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Other Information None known 7. HANDLING AND STORAGE Handling Avoid contact with skin, eyes and clothing. Avoid breathing vapors, spray mists or sanding dust. In case of insufficient ventilation, wear suitable respiratory equipment. Storage Keep container closed. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Limits Hazardous Components Page 3 / 9 Revision Date: 24-Feb-2011 NFPA Legend 0 - Not Hazardous 1 - 2 - Moderate 3 - High 4 - Severe Health: 1 Flammability: 0 Instability: 0 Special: Not Applicable K3093B - IMPERVEX LATEX HIGH GLOSS METAL & WOOD ENAMEL NFPA Page 353 of 871 Page 353 of 871 Page 353 of 871 Page 353 of 871 ---PAGE BREAK--- Chemical Name ACGIH Alberta British Columbia Ontario Quebec Titanium dioxide 10 mg/m3 - TWA 10 mg/m3 - TWA 10 mg/m3 - TWA 3 mg/m3 - TWA 10 mg/m3 - TWAEV 10 mg/m3 - TWAEV Ethylene glycol 100 mg/m3 - Ceiling 100 mg/m3 - Ceiling 10 mg/m3 - TWA 20 mg/m3 - STEL 100 mg/m3 - Ceiling 50 ppm - Ceiling 100 mg/m3 - CEV 127 mg/m3 - Ceiling 50 ppm - Ceiling Legend ACGIH - American Conference of Governmental Industrial Hygienists Alberta - Alberta Occupational Exposure Limits British Columbia - British Columbia Occupational Exposure Limits Ontario - Ontario Occupational Exposure Limits Quebec - Quebec Occupational Exposure Limits N/E - Not established Engineering Measures Ensure adequate ventilation, especially in confined areas. Personal Protective Equipment Eye/Face Protection Safety glasses with side-shields. Skin Protection Protective gloves and impervious clothing. Respiratory Protection In case of insufficient ventilation wear suitable respiratory equipment. Hygiene Measures Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing before re-use. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance liquid Odor little or no odor Density (lbs/gal) 8.8 - 8.9 Specific Gravity 1.0 - 1.1 pH Not available Viscosity (centistokes) Not available Evaporation Rate Not available Vapor Pressure Not available Vapor Density Not available Wt. % Solids 30 - 40 Vol. % Solids 25 - 35 Wt. % Volatiles 60 - 70 Vol. % Volatiles 65 - 75 VOC Regulatory Limit (g/L) < 250 Boiling Point 212 Boiling Point 100 Freezing Point 32 Freezing Point 0 Flash Point Not applicable Flash Point Not applicable Flash Point Method Not applicable Upper Explosion Limit Not available Lower Explosion Limit Not available Page 4 / 9 K3093B - IMPERVEX LATEX HIGH GLOSS METAL & WOOD ENAMEL Revision Date: 24-Feb-2011 Page 354 of 871 Page 354 of 871 Page 354 of 871 Page 354 of 871 ---PAGE BREAK--- 10. STABILITY AND REACTIVITY Chemical Stability Stable under normal conditions. Conditions To Avoid Prevent from freezing Incompatible Materials No materials to be especially mentioned Hazardous Decomposition Products None under normal use. Possibility Of Hazardous Reactions Hazardous polymerisation will not occur. Page 5 / 9 K3093B - IMPERVEX LATEX HIGH GLOSS METAL & WOOD ENAMEL Revision Date: 24-Feb-2011 Page 355 of 871 Page 355 of 871 Page 355 of 871 Page 355 of 871 ---PAGE BREAK--- 11. TOXICOLOGICAL INFORMATION Acute Toxicity Product No information available Component Chronic Toxicity Carcinogenicity The information below indicates whether each agency has listed any ingredient as a carcinogen: Chemical Name ACGIH IARC NTP OSHA Carcinogen Titanium dioxide 2B - Possible Human Carcinogen Listed • Although IARC has classified titanium dioxide as possibly carcinogenic to humans (2B), their summary concludes: "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium dioxide is bound to other materials, such as paint." Legend ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer NTP - National Toxicity Program OSHA - Occupational Safety & Health Administration 12. ECOLOGICAL INFORMATION Ecotoxicity Effects Product Acute Toxicity to Fish No information available Acute Toxicity to Aquatic Invertebrates No information available Page 6 / 9 LC50 Inhalation (Dust): > 6.82 mg/L (Rat, 4 hr.) Ethylene glycol LD50 Oral: > 24000 mg/kg (Rat) LD50 Oral: 4700 mg/kg (Rat) K3093B - IMPERVEX LATEX HIGH GLOSS METAL & WOOD ENAMEL Revision Date: 24-Feb-2011 LD50 Dermal: 9530 µg/L (Rabbit) LD50 Dermal: > 10000 mg/m³ (Rabbit) Titanium dioxide Page 356 of 871 Page 356 of 871 Page 356 of 871 Page 356 of 871 ---PAGE BREAK--- 12. ECOLOGICAL INFORMATION Acute Toxicity to Aquatic Plants No information available Component Acute Toxicity to Fish Acute Toxicity to Aquatic Invertebrates No information available Acute Toxicity to Aquatic Plants No information available 13. DISPOSAL CONSIDERATIONS Waste Disposal Method Dispose of in accordance with federal, state, provincial, and local regulations. Dry, empty containers may be recycled in a can recycling program. Local requirements may vary, consult your sanitation department or state-designated environmental protection agency for more disposal options. 14. TRANSPORT INFORMATION TDG Not regulated ICAO / IATA Not regulated IMDG / IMO Not regulated 15. REGULATORY INFORMATION International Inventories United States TSCA Yes - All components are listed or exempt. Canada DSL Yes - All components are listed or exempt. National Pollutant Release Inventory (NPRI) NPRI Parts 1- 4 This product contains the following Parts 1-4 NPRI chemicals: Page 7 / 9 K3093B - IMPERVEX LATEX HIGH GLOSS METAL & WOOD ENAMEL Ethylene glycol Titanium dioxide LC50: 8050 mg/L (Fathead Minnow - 96 hr.) Revision Date: 24-Feb-2011 LC50: >1000 mg/L (Fathead Minnow - 96 hr.) Page 357 of 871 Page 357 of 871 Page 357 of 871 Page 357 of 871 ---PAGE BREAK--- 15. REGULATORY INFORMATION This product may contain trace amounts of (other) NPRI Parts I-4 reportable chemicals. Contact the preparer for further information. NPRI Part 5 This product contains the following NPRI Part 5 Chemicals: This product may contain trace amounts of (other) NPRI Part 5 reportable chemicals. Contact the preparer for further information. WHMIS Regulatory Status This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class D2A Very toxic materials 16. OTHER INFORMATION WARNING! If you scrape, sand, or remove old paint, you may release lead dust. LEAD IS TOXIC. EXPOSURE TO LEAD DUST CAN CAUSE SERIOUS ILLNESS, SUCH AS BRAIN DAMAGE, ESPECIALLY IN CHILDREN. PREGNANT WOMEN SHOULD ALSO AVOID EXPOSURE. Wear a NIOSH approved respirator to control lead exposure. Clean up carefully with a HEPA vacuum and a wet mop. Before you start, find out how to protect yourself and your family by logging onto Health Canada @ http://www.hc-sc.gc.ca/iyh-vsv/prod/paint-peinture_e.html. Prepared By Product Stewardship Department Benjamin Moore & Co. 360 Route 206 - P.O. Box 4000 Flanders, NJ 07836 [PHONE REDACTED] Revision Date: 24-Feb-2011 Revision Summary No information available Page 8 / 9 Ethylene glycol 107-21-1 1 - 5% Revision Date: 24-Feb-2011 K3093B - IMPERVEX LATEX HIGH GLOSS METAL & WOOD ENAMEL Chemical Name CAS-No Weight % (max) Page 358 of 871 Page 358 of 871 Page 358 of 871 Page 358 of 871 ---PAGE BREAK--- Disclaimer The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, provincial, and local laws and regulations. K3093B End of MSDS Page 9 / 9 K3093B - IMPERVEX LATEX HIGH GLOSS METAL & WOOD ENAMEL Revision Date: 24-Feb-2011 Page 359 of 871 Page 359 of 871 Page 359 of 871 Page 359 of 871 ---PAGE BREAK--- Page 360 of 871 Page 360 of 871 Page 360 of 871 Page 360 of 871 ---PAGE BREAK--- Page 361 of 871 Page 361 of 871 Page 361 of 871 Page 361 of 871 ---PAGE BREAK--- Page 362 of 871 Page 362 of 871 Page 362 of 871 Page 362 of 871 ---PAGE BREAK--- Page 363 of 871 Page 363 of 871 Page 363 of 871 Page 363 of 871 ---PAGE BREAK--- Page 364 of 871 Page 364 of 871 Page 364 of 871 Page 364 of 871 ---PAGE BREAK--- Page 365 of 871 Page 365 of 871 Page 365 of 871 Page 365 of 871 ---PAGE BREAK--- Page 366 of 871 Page 366 of 871 Page 366 of 871 Page 366 of 871 ---PAGE BREAK--- Page 367 of 871 Page 367 of 871 Page 367 of 871 Page 367 of 871 ---PAGE BREAK--- Page 368 of 871 Page 368 of 871 Page 368 of 871 Page 368 of 871 ---PAGE BREAK--- page 1 of 4 HMIS Codes Health 2* Flammability 2 Reactivity 0 DATE OF PREPARATION Jul 17, 2015 MATERIAL SAFETY DATA SHEET B54W101 47 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER B54W101 PRODUCT NAME Industrial Enamel, Pure White MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 Telephone Numbers and Websites Product Information (800) 524-5979 www.sherwin-williams.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 40 64742-88-7 Med. Aliphatic Hydrocarbon Solvent ACGIH TLV 100 PPM 1.27 mm OSHA PEL 100 PPM 0.1 100-41-4 ACGIH TLV 20 PPM 7.1 mm OSHA PEL 100 PPM OSHA PEL 125 PPM STEL 6 14807-96-6 Talc ACGIH TLV 2 mg/m3 as Resp. Dust OSHA PEL 2 mg/m3 as Resp. Dust 14 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Page 369 of 871 Page 369 of 871 Page 369 of 871 Page 369 of 871 ---PAGE BREAK--- B54W101 page 2 of 4 UEL 6.0 LEL 1.0 FLASH POINT 101 °F PMCC SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION Combustible, Flash above 99 and below 200 °F EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY DOL Storage Class II PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Contents are COMBUSTIBLE. Keep away from heat and open flame. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Page 370 of 871 Page 370 of 871 Page 370 of 871 Page 370 of 871 ---PAGE BREAK--- B54W101 page 3 of 4 SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 8.78 lb/gal 1051 g/l SPECIFIC GRAVITY 1.06 BOILING POINT 300 - 395 °F 148 - 201 °C MELTING POINT Not Available VOLATILE VOLUME 57% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 3.68 lb/gal 441 g/l Less Water and Federally Exempt Solvents 3.68 lb/gal 441 g/l Emitted VOC SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that causes cancer in humans. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." TOXICOLOGY DATA CAS No. Ingredient Name 64742-88-7 Med. Aliphatic Hydrocarbon Solvent LC50 RAT 4HR Not Available LD50 RAT Not Available 100-41-4 LC50 RAT 4HR Not Available LD50 RAT 3500 mg/kg 14807-96-6 Talc LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Page 371 of 871 Page 371 of 871 Page 371 of 871 Page 371 of 871 ---PAGE BREAK--- B54W101 page 4 of 4 SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) May be Classed as a Combustible Liquid for U.S. Ground. UN1263, PAINT, 3, PG III, (ERG#128) DOT (Dept of Transportation) Hazardous Substances & Reportable Quantities Xylenes (isomers and mixture) 100 lb RQ Bulk Containers may be Shipped as (check reportable quantities): UN1263, PAINT, COMBUSTIBLE LIQUID, PG III, (ERG#128) Canada (TDG) May be Classed as a Combustible Liquid for Canadian Ground. UN1263, PAINT, 3, PG III, (ERG#128) IMO 5 Liters (1.3 Gallons) and Less may be Shipped as Limited Quantity. UN1263, PAINT, 3, PG III, (38 C EmS F-E, S-E IMO 5 Liters (1.3 Gallons) and Less may be Shipped as Limited Quantity. UN1263, PAINT, 3, PG III, (38 C EmS F-E, S-E IATA/ICAO UN1263, PAINT, 3, PG III SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 100-41-4 0.1 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 372 of 871 Page 372 of 871 Page 372 of 871 Page 372 of 871 ---PAGE BREAK--- Material Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION Product Name BENWOOD INT WOOD FINISH POLYURETHANE FLAT Product Code N42400 Color All 2. COMPOSITION INFORMATION ON COMPONENTS Hazardous Components Chemical Name CAS-No Weight % (max) Stoddard solvent 8052-41-3 25 Silicon dioxide, wax coated 112926-00-8 10 95-63-6 5 Solvent naphtha, petroleum, light aromatic 64742-95-6 5 Xylene 1330-20-7 5 Ethyl benzene 100-41-4 5 108-67-8 5 Cumene 98-82-8 5 3. HAZARDS IDENTIFICATION OSHA Regulatory Status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Page 1 / 10 Emergency Telephone Number(s) CHEMTREC: [PHONE REDACTED] Emergency Overview DANGER Revision Date: 11-Jul-2007 Vapors may be irritating to eyes, nose, throat, and lungs. May cause skin irritation and/or dermatitis. Combustible material. Rags, steel wool or waste soaked with this product may spontaneously catch fire if improperly discarded. Manufacturer Benjamin Moore & Co. 101 Paragon Drive Montvale, NJ 07645 Phone: [PHONE REDACTED] www.benjaminmoore.com Revision Number: 1 Appearance milky amber liquid Odor mild Page 373 of 871 Page 373 of 871 Page 373 of 871 Page 373 of 871 ---PAGE BREAK--- Potential Health Effects Principal Routes of Exposure Eye contact, skin contact and inhalation. Acute Effects Eyes Contact with eyes may cause irritation. Skin May cause skin irritation and/or dermatitis. Inhalation High vapor / aerosol concentrations are irritating to the eyes, nose, throat and lungs and may cause headaches, dizziness, drowsiness, unconsciousness, and other central nervous system effects. Ingestion Ingestion may cause irritation to mucous membranes. Small amounts of this product aspirated into the respiratory system during ingestion or vomiting may cause mild to severe pulmonary injury, possibly progressing to death. Chronic Effects Avoid repeated exposure See Section 11 for additional Toxicological information. Aggravated Medical Conditions None known Note: The PPE rating has intentionally been left blank. Choose appropriate PPE that will protect employees from the hazards the material will present under the actual normal conditions of use. Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings are not required on under 29 CFR 1910.1200, Benjamin Moore & Co., has choosen to provide them. HMIS® ratings are to be used only in conjunction with a fully implemented HMIS® program by workers who have received appropriate HMIS® training. HMIS® is a registered trade and service mark of the NPCA. HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. 4. FIRST AID MEASURES General Advice If persist, call a physician. Show this safety data sheet to the doctor in attendance. Eye Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Keep eye wide open while rinsing. If persist, call a physician. Skin Contact Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. If skin irritation persists, call a physician. Inhalation Move to fresh air. If persist, call a physician. If not breathing, give artificial respiration. Call a physician immediately. Page 2 / 10 Flammability: 2 N42400 - BENWOOD INT WOOD FINISH POLYURETHANE FLAT Reactivity: 0 PPE: - Revision Date: 11-Jul-2007 HMIS HMIS Legend 0 - Minimal Hazard 1 - Slight Hazard 2 - Moderate Hazard 3 - Serious Hazard 4 - Severe Hazard * - Chronic Hazard X - Consult your supervisor or S.O.P. for "Special" handling instructions. Health: 2* Page 374 of 871 Page 374 of 871 Page 374 of 871 Page 374 of 871 ---PAGE BREAK--- Ingestion Clean mouth with water and afterwards drink plenty of water. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Consult a physician. Notes To Physician Treat Protection Of First-Aiders Use personal protective equipment 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Foam, dry powder or water. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Protective Equipment And Precautions For Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Specific Hazards Arising From The Chemical Combustible material. Closed containers may rupture if exposed to fire or extreme heat. Keep product and empty container away from heat and sources of ignition. Thermal decomposition can lead to release of irritating gases and vapors. Sensitivity To Mechanical Impact No Sensitivity To Static Discharge Yes Flash Point Data Flash Point 104 Flash Point 40 Flash Point Method PMCC Flammability Limits In Air Lower Explosion Limit Not available Upper Explosion Limit Not available The ratings assigned by Benjamin Moore & Co. are only suggested ratings, the contractor/employer has ultimate responsibilities for NFPA ratings where this system is used. Additional information regarding the NFPA rating system is available from the National Fire Protection Agency (NFPA) at www.nfpa.org. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Use personal protective equipment. Remove all sources of ignition. Page 3 / 10 Revision Date: 11-Jul-2007 NFPA NFPA Legend 0 - Not Hazardous 1 - 2 - Moderate 3 - High 4 - Severe Health: 2 Flammability: 2 N42400 - BENWOOD INT WOOD FINISH POLYURETHANE FLAT Instability: 0 Special: Not Applicable Page 375 of 871 Page 375 of 871 Page 375 of 871 Page 375 of 871 ---PAGE BREAK--- Environmental Precautions Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system. Prevent product from entering drains. Do not flush into surface water or sanitary sewer system. Local authorities should be advised if significant spillages cannot be contained. Methods For Clean-Up Dam up. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. Clean contaminated surface thoroughly. Other Information None known 7. HANDLING AND STORAGE Handling Use only in area provided with appropriate exhaust ventilation. Do not breathe vapors or spray mist. Wear personal protective equipment. Take precautionary measures against static discharges. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Keep away from open flames, hot surfaces and sources of ignition. Storage Keep containers closed in a dry, cool and well-ventilated place. Keep away from heat. Keep in properly labeled containers. DANGER - Rags, steel wool or waste soaked with this product may spontaneously catch fire if improperly discarded. Immediately after use, place rags, steel wool or waste in a sealed water-filled metal container. 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Exposure Limits Hazardous Components Chemical Name ACGIH OSHA Stoddard solvent TWA 100 ppm PEL 2900 mg/m3 / 500 ppm Silicon dioxide, wax coated N/E N/E TWA 25 ppm N/E Solvent naphtha, petroleum, light aromatic N/E N/E Xylene TWA 100 ppm STEL: 150 ppm PEL 435 mg/m3 / 100 ppm Ethyl benzene TWA 100 ppm STEL: 125 ppm PEL 435 mg/m3 / 100 ppm TWA 25 ppm N/E Cumene TWA 50 ppm PEL 245 mg/m3 / 50 ppm Can be absorbed through the skin. Legend ACGIH - American Conference of Governmental Industrial Hygienists Exposure Limits OSHA - Occupational Safety & Health Administration Exposure Limits N/E - Not Established Engineering Measures Ensure adequate ventilation, especially in confined areas. Personal Protective Equipment Page 4 / 10 Revision Date: 11-Jul-2007 N42400 - BENWOOD INT WOOD FINISH POLYURETHANE FLAT Page 376 of 871 Page 376 of 871 Page 376 of 871 Page 376 of 871 ---PAGE BREAK--- Eye/Face Protection Safety glasses with side-shields. Skin Protection Long sleeved clothing. Protective gloves. Respiratory Protection In case of insufficient ventilation wear suitable respiratory equipment. When spraying the product or applying in confined areas, wear a NIOSH approved respirator specified for paint spray or organic vapors. Hygiene Measures Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing before re-use. Wash thoroughly after handling. When using do not eat, drink or smoke. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance milky amber liquid Odor mild Density (lbs/gal) 7.8 Specific Gravity 0.895 pH Not available Viscosity (centistokes) Not available Evaporation Rate Not available Vapor Pressure Not available Vapor Density Not available Wt. % Solids > 60 Vol. % Solids Not available Wt. % Volatiles < 40 Vol. % Volatiles Not available VOC (g/L) < 350 Boiling Point 312 - 385 Boiling Point 155 - 196 Freezing Point Not available Freezing Point Not available Flash Point 104 Flash Point 40 Flash Point Method PMCC Upper Explosion Limit Not available Lower Explosion Limit Not available 10. STABILITY AND REACTIVITY Chemical Stability Stable under normal conditions. Hazardous polymerisation does not occur. Conditions To Avoid Keep away from open flames, hot surfaces, static electricity and sources of ignition. Incompatible Materials Incompatible with strong acids and bases and strong oxidizing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapors. Possibility Of Hazardous Reactions None under normal conditions of use. Page 5 / 10 Revision Date: 11-Jul-2007 N42400 - BENWOOD INT WOOD FINISH POLYURETHANE FLAT Page 377 of 871 Page 377 of 871 Page 377 of 871 Page 377 of 871 ---PAGE BREAK--- 11. TOXICOLOGICAL INFORMATION Acute Toxicity Product Repeated or prolonged exposure to organic solvents may lead to permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Component No information available Chronic Toxicity Carcinogenicity The information below indicates whether each agency has listed any ingredient as a carcinogen: Chemical Name ACGIH IARC NTP OSHA Carcinogen Page 6 / 10 Stoddard solvent LD50 Oral: 5,000 mg/kg (Rat) LD50 Oral: 8400 mg/kg (Rat) LC50 Inhalation (Vapor): 24,000 mg/m3 (Rat, 4 hr.) LC50 Inhalation (Vapor): > 6.1 mg/L (Rat) Cumene Xylene LD50 Oral: 1400 - 2900 mg/kg (Rat) N42400 - BENWOOD INT WOOD FINISH POLYURETHANE FLAT LD50 Dermal: 12300 µL/kg (Rabbit) LD50 Oral: 4300 mg/kg (Rat) LC50 Inhalation (Vapor): 39000mg/kg (Rat) LD50 Dermal: > 1700 mg/kg (Rabbit) LD50 Oral: > 5,000 mg/kg (Rat) LC50 Inhalation (Vapor): 5000 ppm (Rat, 4 hr.) LD50 Oral: 5000 mg/kg (Rat) Ethyl benzene Revision Date: 11-Jul-2007 LD50 Oral: 3500 mg/kg (Rat) LC50 Inhalation (Vapor): 18000 mg/m3 (Rat, 4 hr.) LD50 Dermal: 17800 µg/L (Rabbit) LD50 Dermal: > 3160 mg/kg (Rabbit) LC50 Inhalation (Vapor): 55000 mg/m3 (Rat, 2 hr.) Solvent naphtha, petroleum, light aromatic Page 378 of 871 Page 378 of 871 Page 378 of 871 Page 378 of 871 ---PAGE BREAK--- Chemical Name ACGIH IARC NTP OSHA Carcinogen Stoddard solvent 3 Classification not possible from current data. Silicon dioxide, wax coated 3 Classification not possible from current data. Xylene 3 Classification not possible from current data. Ethyl benzene 2B Possible carcinogen. Legend ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer NTP - National Toxicity Program OSHA - Occupational Safety & Health Administration 12. ECOLOGICAL INFORMATION Ecotoxicity Effects Product Acute Toxicity to Fish No information available Acute Toxicity to Aquatic Invertebrates No information available Acute Toxicity to Aquatic Plants No information available Component Acute Toxicity to Fish No information available Acute Toxicity to Aquatic Invertebrates No information available Acute Toxicity to Aquatic Plants No information available 13. DISPOSAL CONSIDERATIONS Page 7 / 10 Revision Date: 11-Jul-2007 N42400 - BENWOOD INT WOOD FINISH POLYURETHANE FLAT Page 379 of 871 Page 379 of 871 Page 379 of 871 Page 379 of 871 ---PAGE BREAK--- 13. DISPOSAL CONSIDERATIONS Waste Disposal Method Dispose of in accordance with federal, state, and local regulations. Dry, empty containers may be recycled in a can recycling program. Local requirements may vary, consult your sanitation department or state-designated environmental protection agency for more disposal options. 14. TRANSPORT INFORMATION DOT Not regulated ICAO / IATA Contact Benjamin Moore & Co. for further information. IMDG / IMO Contact Benjamin Moore & Co. for further information. 15. REGULATORY INFORMATION International Inventories United States TSCA Yes - All components are listed or exempt. Canada DSL Yes - All components are listed or exempt. Federal Regulations SARA 311/312 hazardous categorization Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard Yes Sudden Release of Pressure Hazard No Reactive Hazard No SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product contains the following HAPs: Page 8 / 10 Xylene 1330-20-7 5 Ethyl benzene 100-41-4 5 Cumene 98-82-8 5 This product may contain trace amounts of (other) SARA reportable chemicals. Contact Benjamin Moore & Co. for further information. Revision Date: 11-Jul-2007 N42400 - BENWOOD INT WOOD FINISH POLYURETHANE FLAT Chemical Name CAS-No Weight % (max) 95-63-6 5 Page 380 of 871 Page 380 of 871 Page 380 of 871 Page 380 of 871 ---PAGE BREAK--- State Regulations California Proposition 65 This product may contain small amounts of materials known to the state of California to cause cancer or reproductive harm. State Right-to-Know Chemical Name Massachusetts New Jersey Louisiana Rhode Island Stoddard solvent X X X X Silicon dioxide, wax coated X X X X X X X Xylene X X X X Ethyl benzene X X X X X X X X Cumene X X X X Legend X - Listed 16. OTHER INFORMATION WARNING! If you scrape, sand, or remove old paint, you may release lead dust. LEAD IS TOXIC. EXPOSURE TO LEAD DUST CAN CAUSE SERIOUS ILLNESS, SUCH AS BRAIN DAMAGE, ESPECIALLY IN CHILDREN. PREGNANT WOMEN SHOULD ALSO AVOID EXPOSURE. Wear a NIOSH approved respirator to control lead exposure. Clean up carefully with a HEPA vacuum and a wet mop. Before you start, find out how to protect yourself and your family by contacting the National Lead Information Hotline at 1-800-424-LEAD or log on to www.epa.gov/lead. Prepared By Product Stewardship Department Benjamin Moore & Co. 360 Route 206 - P.O. Box 4000 Flanders, NJ 07836 [PHONE REDACTED] Revision Date: 11-Jul-2007 Revision Summary Not available Page 9 / 10 Ethyl benzene 100-41-4 5 Cumene 98-82-8 5 This product may contain trace amounts of (other) HAPs chemicals. Contact Benjamin Moore & Co. for further information. N42400 - BENWOOD INT WOOD FINISH POLYURETHANE FLAT Revision Date: 11-Jul-2007 Chemical Name CAS-No Weight % (max) Xylene 1330-20-7 5 Page 381 of 871 Page 381 of 871 Page 381 of 871 Page 381 of 871 ---PAGE BREAK--- Disclaimer The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, provincial, and local laws and regulations. End of MSDS Page 10 / 10 N42400 - BENWOOD INT WOOD FINISH POLYURETHANE FLAT Revision Date: 11-Jul-2007 Page 382 of 871 Page 382 of 871 Page 382 of 871 Page 382 of 871 ---PAGE BREAK--- Perma-Crete Int/Ext Alkali Resistant Primer Product name Product and company identification : 1 . 4-603 PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (514) 645-1320 (Canada) 01-800-00-21-400 (Mexico) Supplier Code Emergency telephone number : : : Technical Phone Number : 1-[PHONE REDACTED] (8:00 am to 5:00 pm EST) Material Safety Data Sheet Date of issue 30 January 2015 Version 31 Emergency overview Hazards identification Potential acute health effects May be harmful if swallowed. Eyes Skin Inhalation Ingestion See toxicological information (Section 11) WARNING! : : : : : Medical conditions aggravated by over- exposure Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. : 2 . Over-exposure This product contains silica which can cause lung cancer or silicosis. The risk of cancer depends on the duration and level of exposure to dust from sanding surfaces or mist from spray applications. Avoid breathing vapor or mist. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Keep container closed and sealed until ready for use. Wash thoroughly after handling. CAUSES RESPIRATORY TRACT AND EYE IRRITATION. MAY BE HARMFUL IF INHALED OR SWALLOWED. SANDING AND GRINDING DUSTS MAY BE HARMFUL IF INHALED. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. CANCER HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE CANCER. May be harmful if inhaled. Irritating to respiratory system. Can irritate eyes, nose, mouth and throat. Irritating to eyes. May cause skin dryness and irritation. This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials Information System (WHMIS). Composition/information on ingredients 3 . titanium dioxide 13463-67-7 7 - 13 Mica-group minerals 12001-26-2 1 - 5 ethanediol 107-21-1 1 - 5 zinc oxide 1314-13-2 0.5 - 1.5 silica, respirable powder (<10 microns) 14808-60-7 0.1 - 1 Name CAS number % (w/w) Page: 1/7 Canada - Mexico Page 383 of 871 Page 383 of 871 Page 383 of 871 Page 383 of 871 ---PAGE BREAK--- Perma-Crete Int/Ext Alkali Resistant Primer Product name 31 Product code Date of issue Version 4-603 30 January 2015 Composition/information on ingredients 3 . There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. First aid measures Eye contact Skin contact Inhalation Ingestion Notes to physician : : : : : 4 . Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting. If ingestion, irritation, any type of overexposure or of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person. No specific treatment. Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Use an extinguishing agent suitable for the surrounding fire. Fire-fighting measures Extinguishing media isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. In a fire or if heated, a pressure increase will occur and the container may burst. Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : 5 . Special exposure hazards : None known. Suitable : Not suitable : Hazardous combustion products : Decomposition products may include the following materials: carbon oxides metal oxide/oxides Flammability of the product : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Environmental precautions Accidental release measures : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions : Large spill : 6 . Page: 2/7 Canada - Mexico Page 384 of 871 Page 384 of 871 Page 384 of 871 Page 384 of 871 ---PAGE BREAK--- Perma-Crete Int/Ext Alkali Resistant Primer Product name 31 Product code Date of issue Version 4-603 30 January 2015 Accidental release measures 6 . Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Do not store below the following temperature: 32F / 0C. Put on appropriate personal protective equipment (see Section Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Do not swallow. Do not get in eyes or on skin or clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. If this material is part of a multiple component system, read the Material Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. Handling and storage Handling Storage : : 7 . Exposure controls/personal protection 8 . Acceptable Maximum Peak A = ACGIH = American Conference of Governmental Industrial Hygienists. C = Ceiling Limit Potential skin absorption S SR = Respiratory sensitization = Skin sensitization SS TD = Total dust Key to abbreviations Consult local authorities for acceptable exposure limits. = Threshold Limit Value TLV TWA = Time Weighted Average Fume = F IPEL = Internal Permissible Exposure Limit R = Respirable titanium dioxide TWA 10 mg/m³ 10 mg/m³ TD 10 mg/m³ (as Ti) Not established STEL Not established Not established 20 mg/m³ (as Ti) Not established Mica-group minerals TWA 3 mg/m³ R 3 mg/m³ R 3 mg/m³ Not established ethanediol STEL 100 mg/m³ C 100 mg/m³ C 100 mg/m³ C Not established zinc oxide TWA 2 mg/m³ R 2 mg/m³ R 10 mg/m³ Not established 5 mg/m³ STEL 10 mg/m³ R 10 mg/m³ R 10 mg/m³ Not established silica, respirable powder (<10 microns) TWA 0.025 mg/m³ R 0.1 mg/m³ R 0.1 mg/m³ R Not established Name Result ACGIH Ontario Mexico PPG STEL = = Short term Exposure limit values Page: 3/7 Canada - Mexico Page 385 of 871 Page 385 of 871 Page 385 of 871 Page 385 of 871 ---PAGE BREAK--- Perma-Crete Int/Ext Alkali Resistant Primer Product name 31 Product code Date of issue Version 4-603 30 January 2015 Exposure controls/personal protection 8 . If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety glasses with side shields. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Personal protection Eyes Skin Respiratory : : : Engineering measures : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. >37.78°C (>100°F) Liquid. 61% 51.63% (w/w) Not available. Not available. 1.18 Not available. 2.3 kPa (17.3 mm Hg) [room temperature] Not available. Not available. Boiling/condensation point Melting/freezing point 0.34 (butyl acetate = 1) Physical and chemical properties Physical state pH Specific gravity Vapor pressure Vapor density Volatility Evaporation rate Odor Color : : : : : : : : : : : Flash point : Closed cup: >93.33°C (>200°F) 9 . Density ( lbs / gal ) : 9.85 Yes. : Material supports combustion. Page: 4/7 Canada - Mexico Page 386 of 871 Page 386 of 871 Page 386 of 871 Page 386 of 871 ---PAGE BREAK--- Perma-Crete Int/Ext Alkali Resistant Primer Product name 31 Product code Date of issue Version 4-603 30 January 2015 Physical and chemical properties 9 . Insoluble in the following materials: cold water. Solubility : Partition coefficient: n- octanol/water : Not available. % Solid. (w/w) : 48.37 Stable under recommended storage and handling conditions (see Section Reactive or incompatible with the following materials:,water,acids,oxidizing materials, strong alkalis Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. No specific data. Stability and reactivity Stability Conditions to avoid Materials to avoid Hazardous decomposition products Hazardous polymerization : : : : : 10 . 11 . Toxicological information Conclusion/Summary : Not available. Chronic toxicity Conclusion/Summary : Not available. Carcinogenicity Classification Carcinogenicity : Contains material which can cause cancer. Risk of cancer depends on duration and level of exposure. Defatting irritant : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis. Target organs : Contains material which may cause damage to the following organs: kidneys, lungs, heart, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea. titanium dioxide LD50 Oral Rat >10 g/kg - ethanediol LD50 Oral Rat 4700 mg/kg - LD50 Dermal Rabbit 9.53 g/kg - Product/ingredient name Result Species Dose Exposure Acute toxicity Product/ingredient name titanium dioxide A4 2B - ethanediol A4 - - silica, respirable powder (<10 microns) A2 1 Known to be a human carcinogen. ACGIH NTP IARC Carcinogen Classification code: Teratogenicity : Contains material which may cause birth defects, based on animal data. ACGIH: A1, A2, A3, A4, A5 IARC: 1, 2A, 2B, 3, 4 NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen Not listed or regulated as a carcinogen: - Page: 5/7 Canada - Mexico Page 387 of 871 Page 387 of 871 Page 387 of 871 Page 387 of 871 ---PAGE BREAK--- Perma-Crete Int/Ext Alkali Resistant Primer Product name 31 Product code Date of issue Version 4-603 30 January 2015 Ecological information Environmental effects : No known significant effects or critical hazards. 12 . Aquatic ecotoxicity titanium dioxide Acute LC50 >100 mg/l Fresh water Daphnia - Daphnia magna 48 hours zinc oxide Acute EC50 0.481 mg/L Fresh water Daphnia - Water flea - Daphnia magna 48 hours Product/ingredient name Species Result Exposure The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal Disposal considerations Disposal should be in accordance with applicable regional, national and local laws and regulations. : 13 . Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures 14. Transport information Special precautions for user Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Additional information None identified. None identified. TDG Mexico : : - - - Not regulated. Mexico UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No. TDG Not regulated. - - - No. Marine pollutant substances IMDG : None identified. IMDG Not regulated. - - - No. Not applicable. Not applicable. Not applicable. Page: 6/7 Canada - Mexico Page 388 of 871 Page 388 of 871 Page 388 of 871 Page 388 of 871 ---PAGE BREAK--- Perma-Crete Int/Ext Alkali Resistant Primer Product name 31 Product code Date of issue Version 4-603 30 January 2015 15 . Regulatory information All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. At least one component is not listed. At least one component is not listed. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. United States inventory (TSCA 8b) : Australia inventory (AICS) Canada inventory ( DSL ) : China inventory (IECSC) : Japan inventory (ENCS) : Korea inventory (KECI) : New Zealand ( NZIoC ) : Philippines inventory (PICCS) : : Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this material. WHMIS (Canada) Class D-1B: Material causing immediate and serious toxic effects (Toxic). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). : Canada Mexico 1 2 0 Health Flammability Reactivity Classification : : : Other information Hazardous Material Information System 1 0 1 National Fire Protection Association Health Instability Flammability Health Flammability Physical hazards Disclaimer The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Date of previous issue 12/3/2014. : 16 . Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Indicates information that has changed from previously issued version. Organization that prepared the MSDS : EHS : : : : : : 2 * 2 0 ( * ) - Chronic effects Page: 7/7 Canada - Mexico Page 389 of 871 Page 389 of 871 Page 389 of 871 Page 389 of 871 ---PAGE BREAK--- ---PAGE BREAK--- ---PAGE BREAK--- ---PAGE BREAK--- Material Safety Data Sheet SECTION 1:Chemical Product and Company Identification Manufacturer: Cumberland Swan Date: March 2000 One Swan Drive TN 37167 Product: Isopropyl Alcohol (IPA) 50%, 70%, 91% and 99% IPA Telephone: (615) 459-8900 24hr Emergency: (615) 459-8900 ext. 5270 SECTION 2: Composition/Information on Ingredients Name: Isopropanol, IPA, 2-Propanol, Dimethyl Carbinol CAS#: 67-63-0 SECTION 3: Hazards Identification Colorless, volatile liquid with the odor of rubbing alcohol. Isopropyl Alcohol is a dangerous fire risk. Prolonged exposure to elevated concentrations of vapors may result in irritation of the eyes, nose, and throat and central nervous system (CNS) depression. Prolonged dermal exposure can result in dry, cracking skin. Potential Routes of Exposure: Ingestion, inhalation, dermal contact, eye contact Target Organs: Eyes, skin, respiratory system of Overexposure: Inhalation: Mild irritation of eyes, nose and throat. Ingestion: Drowsiness, headache Dermal Contact: Dry, cracking skin Acute Effects: Irritation of skin and/or upper respiratory tract as noted above. Acute CNS depression may be manifested as giddiness, headache, dizziness and/or nausea. Chronic Effects: Chronic exposure can result in skin irritation and contact dermititus Pre-existing disorders of the skin, eyes, and respiratory tract may be exacerbated by exposure to isopropyl alcohol. HMIS: H=1, F=3, R=0 See Section 8 for PPE information SECTION 4: First Aid Measures Eye: Flush eyes with copious amount of water for at least 15 minutes Skin: Flush with water. If irritation persists, seek medical attention. Ingestion: Do not induce vomiting if victim is unconscious or drowsy. Seek medical attention or contact the poison control center. Inhalation: Remove victim to fresh air and provided oxygen if breathing is difficult. Seek Medical attention if breathing continues to be difficult. Isopropyl Alcohol MSDS Page 1 of 3 Page 393 of 871 Page 393 of 871 Page 393 of 871 Page 393 of 871 ---PAGE BREAK--- SECTION 5: Fire Fighting Measures Extinguishing Media: Use water fog, alcohol foam, dry chemical or CO2 Unusual Fire or Containers exposed to intense heat from fires should be Explosion Hazards: cooled with large amounts of water to prevent buildup of internal pressure due to vapor generation which could result in container rupture. Recommendations: Clear area of unprotected personnel. Wear complete turnout gear. Cool containers exposed to fire with water. SECTION 6: Accidental Release Measures Large Spills: Eliminate all ignition sources. Equipment must be grounded to prevent sparking. Evacuate the area of unprotected personnel. Contain source of spill. Dike or otherwise confine spilled product. Uncontrolled releases to air, land, or water may be reportable to the National Response Center (1-[PHONE REDACTED]). Small Spills: Take up with absorbent material and place in non-leaking container; seal Dispose of absorbent (see section 13) SECTION 7: Handling and Storage Storage Requirements: Store in closed containers in a cool, dry area away from heat and other possible ignition sources. Handling precautions: Use non-sparking tools to open containers. Maintain appropriate class of fire extinguishers nearby in case of fire. SECTION 8: Exposure Controls / Personal Protection OSHA PEL=400ppm OSHA STEL=500ppm IDLH=12,000ppm Recommended Engineering Controls: Use explosion-proof ventilation equipment as necessary to maintain airborne concentrations below the PEL. Ground all containers to prevent static sparks during fluid transfers. Recommended Admin Controls: Train employees on the hazards of Isopropyl Alcohol PPE: Goggles, gloves, NIOSH approved respiratory protection required when above PEL/TWA Recommended Hygiene Practices: Clean PPE and work clothing contaminated prior to reuse. After working with this product, be sure to wash before eating, smoking, drinking, or applying cosmetics. SECTION 9: Physical and Chemical Properties Appearance: Colorless Liquid UEL: 12% LEL: 2% Odor: Mild Rubbing Alcohol Odor Threshold: 43ppm Water solubility: Miscible 50% IPA 70%IPA 91%IPA 99%IPA Vapor Pressure 680F) approx. 29mm 23mm 33mm 33mm Specific Gravity .929 .878 .790 .790 Boiling Point 176 0 F 176 0 F 180 0 F 181 0 F Flash Point (TAG Open Cup) 74.5 0 F 70.5 0 F 54 0 F 53 0 F Freezing Point -32--50 0 C -32--50 0 C -32--50 0 C -127 0 F Molecular Weight 47.5 47.5 47.5 60.1 Auto Ignition Temperature No Data No Data No Data 750 0 F Isopropyl Alcohol MSDS Page 2 of 3 Page 394 of 871 Page 394 of 871 Page 394 of 871 Page 394 of 871 ---PAGE BREAK--- SECTION 10: Stability and Reactivity Stability: Stable Polymerization: Will not occur Incompatible Chem: Strong oxidizers, acetaldehyde, chlorine, ethylene oxide, acids, isocyanates Conditions to avoid: Heat, sparks, and open flame. Do Not store in aluminum > 120 0 F Hazardous Products: CO and unidentified organic compounds may be formed of Decomposition SECTION 11: Toxicological Information LD50: 5,840 mg/kg (acute oral - rat); 13,000 mg/kg (acute dermal - rabbit) LD50: 16,000 ppm/8hr (inhalation - rat) Mutagenicity: Not Indicated LDlo : 5,000 mg/kg (oral - rabbit) Reproductive Effects: Not Indicated Carcinogenicity: Not identified as a carcinogen by OSHO, IARC, or NTP SECTION 12: Ecological Information Ecotoxicity: N/A Environmental Fate: N/A Soil Absorption/Mobility: Highly Mobile Environmental Degradation: Should be removed readily from soils and water by volatilization and biodegradation. SECTION 13: Disposal Considerations Disposal: Contact your supplier or a licensed contractor for detailed recommendations. Disposal regulatory Requirements: Follow applicable Federal, state, and local regulations. Consider fuels blending as an alternative to incineration. SECTION 14: Transport Information DOT Shipping Name: Isopropanol DOT Packing Group: II DOT Hazard Class: 3 DOT Label: Flammable Liquid UN ID#: UN 1219 SECTION 15: Regulatory Information RCRA Hazardous Waste Number/ Classification:D001 CERCLA Substance: N/A HAZARDOUS AIR POLUTANT (CAA): No SARA 311/312 Codes: N/A SARA Toxic Chemical: Yes, (Strong manufacturing only) CERCLA Reportable Quantity: 10,000 lbs (Default) SECTION 16: Other Information Prepared by: Cumberland Swan Sources of Information: 29 CFR1910.1000; NIOSH Pocket Guide to Chemical Hazards (1993); Occupational Health Guidelines for Chemical Hazards; NFPA Guide to Hazardous Materials - 10th Edition. Disclaimer: While reasonable care has been taken to ensure the accuracy and completeness of the information regarding the material described herein, it is the purchaser’s responsibility to ensure the suitability of such information as it applies to the purchaser’s intended use of the material. Isopropyl Alcohol MSDS Page 3 of 3 Page 395 of 871 Page 395 of 871 Page 395 of 871 Page 395 of 871 ---PAGE BREAK--- Page 396 of 871 Page 396 of 871 Page 396 of 871 Page 396 of 871 ---PAGE BREAK--- Page 397 of 871 Page 397 of 871 Page 397 of 871 Page 397 of 871 ---PAGE BREAK--- Page 398 of 871 Page 398 of 871 Page 398 of 871 Page 398 of 871 ---PAGE BREAK--- 04/13/2015 Revision: 04/13/2015 Printed: Page: 1 Klean-Strip Industrial Maintenance Coating Thinner SAFETY DATA SHEET 01/02/2015 Supersedes Revision: Klean-Strip Industrial Maintenance Coating Thinner Product Name: W. M. Barr Company Name: 2105 Channel Avenue Memphis, TN 38113 3E 24 Hour Emergency Contact Emergency Contact: (800)451-8346 W.M. Barr Customer Service Information: (800)398-3892 (901)775-0100 Phone Number: Paint, stain, and varnish thinning. Intended Use: www.wmbarr.com Web site address: CKIM14630, GKIM24630, QKIM34630 Synonyms: 1. PRODUCT AND COMPANY IDENTIFICATION This product is regulated by the United States Consumer Product Safety Commission and is subject to certain labeling requirements under the Federal Hazardous Substances Act. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS). The product label also includes other important information, including directions for use, and should always be read in its entirety prior to using the product. Additional Information 2. HAZARDS IDENTIFICATION P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P233: Keep container closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P261: Avoid breathing gas/mist/vapors/spray. P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear protective gloves/protective clothing/eye protection/face protection. P281: Use personal protective equipment as required. P235: Keep cool. GHS Precaution Phrases: P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302+352: IF ON SKIN: Wash with plenty of soap and water. GHS Response Phrases: H225: Highly flammable liquid and vapor. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation. H340: May cause genetic defects. GHS Hazard Phrases: Flammable Liquids, Category 2 Skin Corrosion/Irritation, Category 2 Serious Eye Damage/Eye Irritation, Category 2 Germ Cell Mutagenicity, Category 1B Specific Target Organ Toxicity (single exposure), Category 3 Aspiration Toxicity, Category 1 Danger GHS Signal Word: Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 399 of 871 Page 399 of 871 Page 399 of 871 Page 399 of 871 ---PAGE BREAK--- 04/13/2015 Revision: 04/13/2015 Printed: Page: 2 Klean-Strip Industrial Maintenance Coating Thinner SAFETY DATA SHEET 01/02/2015 Supersedes Revision: P303+361+353: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+313: IF exposed or concerned: Get medical attention/advice. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment see label. P331: Do NOT induce vomiting. P332+313: If skin irritation occurs, get medical advice/attention. P337+313: If eye irritation persists, get medical advice/attention. P362: Take off contaminated clothing and wash before re-use. P370+378: In case of fire, use dry chemical powder to extinguish. P403+233: Store container closed in well-ventilated place. P405: Store locked up. P501: Dispose of contents/container according to local, state and federal regulations. GHS Storage and Disposal Phrases: Hazard Rating System: Instability Special Hazard Health Flammability HEALTH FLAMMABILITY PPE PHYSICAL 1 0 3 * X 1 3 0 NFPA: HMIS: This material is classified as hazardous under OSHA regulations. OSHA Regulatory Status: Inhalation Acute Exposure Effects: High vapor concentrations may cause dizziness, headache, anaesthesia, drowsiness, fatigue, and other central nervous system effects, including death. Intentional misuse of this product by deliberately concentrating and inhaling vapors can be harmful or fatal. Skin Contact Acute Exposure Effects: This product is a skin irritant. It may be absorbed through the skin. It may cause irritation, dermatitis, drying of skin, redness, itching, and burning of the skin. Repeated or prolonged skin contact can produce moderate irritation (dermatitis). Skin contact may aggravate an existing dermatitis condition. Eye Contact Acute Exposure Effects: This material is an eye irritant. It may cause irritation, redness, stinging, tearing, and swelling. High vapor concentrations are irritating to the eyes and the respiratory tract. Ingestion Acute Exposure Effects: Harmful or fatal if swallowed. May cause nausea, vomiting, gastrointestinal irritation, or diarrhea. If swallowed, this material may irritate the mucous membranes of the mouth, throat, and esophagus. It can be readily absorbed by the stomach and intestinal tract. include a burning sensation of the mouth and esophagus, nausea, vomiting, dizziness, staggering gait, drowsiness, loss of consciousness, and delirium, as well as additional central nervous system effects. There is a danger of aspiration into the lungs during vomiting. Aspiration can result in severe lung damage or death. Chronic Exposure Effects: Reports have associated repeated and prolonged overexposure to solvents with irreversible brain and nervous system damage. Prolonged or repeated contact may cause dermatitis. Potential Health Effects (Acute and Chronic): Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 400 of 871 Page 400 of 871 Page 400 of 871 Page 400 of 871 ---PAGE BREAK--- 04/13/2015 Revision: 04/13/2015 Printed: Page: 3 Klean-Strip Industrial Maintenance Coating Thinner SAFETY DATA SHEET 01/02/2015 Supersedes Revision: Skin, Respiratory System, Liver, Kidneys, Central Nervous System Medical Conditions Generally Aggravated By Exposure: Chronic effects of ingestion and subsequent aspiration into the lungs may cause pneumatocele (lung cavity) formation and chronic lung dysfunction. TARGET ORGANS: kidneys, lungs, liver, mucous membranes, upper respiratory tract, skin, eyes, central nervous system CAS # Hazardous Components (Chemical Name) 3. COMPOSITION/INFORMATION ON INGREDIENTS Concentration RTECS # 64742-89-8 Light aliphatic solvent naphtha (petroleum) 15.0 -40.0 % NA 141-78-6 Acetic acid, ethyl ester {Ethyl acetate} 15.0 -40.0 % AH5425000 64742-95-6 Petroleum Hydrocarbons 10.0 -30.0 % WF3400000 95-63-6 {Pseudocumene} 7.0 -13.0 % DC3325000 1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} 1.0 -5.0 % ZE2100000 Specific percentage of composition is being withheld as a trade secret. Additional Chemical Information 4. FIRST AID MEASURES Skin: Immediately begin washing the skin thoroughly with large amounts of water and mild soap, if available, while removing contaminated clothing. Seek medical attention if irritation persists. Eyes: Immediately begin to flush eyes with water, remove any contact lens. Continue to flush the eyes for at least 15 minutes. Seek medical attention. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Ingestion: If swallowed, do NOT induce vomiting. Seek immediate medical attention. Call a physician, hospital emergency room, or poison control center immediately. Never give anything by mouth to an unconscious person. Emergency and First Aid Procedures: See Potential Health Effects. Signs and Of Exposure: Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 401 of 871 Page 401 of 871 Page 401 of 871 Page 401 of 871 ---PAGE BREAK--- 04/13/2015 Revision: 04/13/2015 Printed: Page: 4 Klean-Strip Industrial Maintenance Coating Thinner SAFETY DATA SHEET 01/02/2015 Supersedes Revision: 5. FIRE FIGHTING MEASURES Flash Pt: 35.00 F Method Used: Setaflash Closed Cup (Rapid Setaflash) Self-contained respiratory protection should be provided for fire fighters fighting fires in buildings or confined areas. Storage containers exposed to fire should be kept cool with water spay to prevent pressure build-up. Stay away from heads of containers that have been exposed to intense heat or flame. Fire Fighting Instructions: Material can accumulate static charges which can cause an incendiary electrical disharge. Flammable Properties and Hazards: Autoignition Pt: No data. Explosive Limits: LEL: 0.9 % UEL: ~6.0 % Flammability Classification: NFPA Class IB Use carbon dioxide, dry powder, water spray, or alcohol-resistant foam. Suitable Extinguishing Media: None known. Unsuitable Extinguishing Media: 6. ACCIDENTAL RELEASE MEASURES Vapors may cause flash fire or ignite explosively. Clean up: Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, out of low areas, and ventilate closed spaces before entering. Shut off ignition sources; keep flares, smoking or flames out of hazard area. Use non-sparking tools. Use proper bonding and grounding methods for all equipment and processes. Keep out of waterways and bodies of water. Be cautious of vapors collecting in small enclosed spaces, sewers, low lying areas, confined spaces, etc. Small spills: Take up with sand, earth or other noncombustible absorbent material and place in a plastic container where applicable. Large spills: Dike far ahead of spill for later disposal. Waste Disposal: Dispose in accordance with applicable local, state and federal regulations. Steps To Be Taken In Case Material Is Released Or Spilled: 7. HANDLING AND STORAGE Read carefully all cautions and directions on product label before use. Since empty container retains residue, follow all label warnings even after container is empty. Dispose of empty container according to all regulations. Do not reuse this container. Do not use this product near any source of heat or open flame, furnace areas, pilot lights, stoves, etc. Do not use in small enclosed spaces, such as basements and bathrooms. Vapors can accumulate and explode if ignited. Precautions To Be Taken in Handling: Keep container closed when not in use. Store in a cool, dry place. Do not store near flames or at elevated temperatures. Precautions To Be Taken in Storing: Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 402 of 871 Page 402 of 871 Page 402 of 871 Page 402 of 871 ---PAGE BREAK--- 04/13/2015 Revision: 04/13/2015 Printed: Page: 5 Klean-Strip Industrial Maintenance Coating Thinner SAFETY DATA SHEET 01/02/2015 Supersedes Revision: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OSHA TWA ACGIH TWA CAS # Partial Chemical Name Other Limits PEL: 100 ppm STEL: 500 ppm/(10min) CEIL: 300 ppm TLV: 300 ppm STEL: 150 ppm 64742-89-8 Light aliphatic solvent naphtha (petroleum) No data. PEL: 400 ppm TLV: 400 ppm 141-78-6 Acetic acid, ethyl ester {Ethyl acetate} No data. No data. No data. 64742-95-6 Petroleum Hydrocarbons No data. No data. No data. 95-63-6 {Pseudocumene} No data. PEL: 100 ppm TLV: 100 ppm STEL: 150 ppm 1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} No data. For use in areas with inadequate ventilation or fresh air, wear a properly maintained and properly fitted NIOSH approved respirator for organic solvent vapors. For OSHA controlled work places and other regular users - Use only with adequate ventilation under engineered air control systems designed to prevent exceeding the appropriate TLV. A dust mask does not provide protection against vapors. Respiratory Equipment (Specify Type): Chemical splash goggles or face shields are recommended to safeguard against potential eye contact, irritation, or injury. Eye Protection: Wear gloves with as much resistance to the chemical ingredients as possible. Glove materials such as nitrile rubber may provide protection. Glove selection should be based on chemicals being used and conditions of use. Consult your glove supplier for additional information. Gloves contaminated with product should be discarded and not reused. Protective Gloves: Various application methods can dictate the use of additional protective safety equipment, such as impermeable aprons, etc., to minimize exposure. Other Protective Clothing: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use only with adequate ventilation to prevent buildup of vapors. Do not use in areas where vapors can accumulate and concentrate, such as basements, bathrooms or small enclosed areas. Whenever possible, use outdoors in an open air area. If using indoors open all windows and doors and maintain a cross ventilation of moving fresh air across the work area. If strong odor is noticed or you experience slight dizziness, headache, nausea or eye-watering STOP ventilation is inadequate. Leave area immediately and move to fresh air. Engineering Controls (Ventilation etc.): A source of clean water should be available in the work area for flushing eyes and skin. Do not eat, drink, or smoke in the work area. Wash hands thoroughly after use. Before reuse, thoroughly clean any clothing or protective equipment that has been contaminated by prior use. Discard any clothing or other protective equipment that cannot be decontaminated, such as gloves or shoes. Work/Hygienic/Maintenance Practices: Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 403 of 871 Page 403 of 871 Page 403 of 871 Page 403 of 871 ---PAGE BREAK--- 04/13/2015 Revision: 04/13/2015 Printed: Page: 6 Klean-Strip Industrial Maintenance Coating Thinner SAFETY DATA SHEET 01/02/2015 Supersedes Revision: 9. PHYSICAL AND CHEMICAL PROPERTIES Physical States: [ ] Gas [ X ] Liquid [ ] Solid Melting Point: No data. Boiling Point: No data. Autoignition Pt: No data. Flash Pt: 35.00 F Method Used: Setaflash Closed Cup (Rapid Setaflash) Explosive Limits: LEL: 0.9 % UEL: ~6.0 % Specific Gravity (Water = 0.833 Density: 6.95 LB/GL Free and clear, water white. Appearance and Odor: Vapor Pressure (vs. Air or mm Hg): 47.6 MM HG at 68.0 F Vapor Density (vs. Air = > 1 Evaporation Rate: > 1 Solubility in Water: none Percent Volatile: 100.0 % by weight. VOC / Volume: 833.0000 G/L Viscosity: water thin 10. STABILITY AND REACTIVITY No data available. Conditions To Avoid - Instability: Unstable [ ] Stable [ X ] Stability: Incompatible with strong oxidizing agents, acids, and alkalies. Incompatibility - Materials To Avoid: Decomposition may produce carbon monoxide and carbon dioxide. Hazardous Decomposition Or Byproducts: Will occur [ ] Will not occur [ X ] Possibility of Hazardous Reactions: No data available. Conditions To Avoid - Hazardous Reactions: Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 404 of 871 Page 404 of 871 Page 404 of 871 Page 404 of 871 ---PAGE BREAK--- 04/13/2015 Revision: 04/13/2015 Printed: Page: 7 Klean-Strip Industrial Maintenance Coating Thinner SAFETY DATA SHEET 01/02/2015 Supersedes Revision: CAS # Hazardous Components (Chemical Name) NTP 11. TOXICOLOGICAL INFORMATION This product has not been tested as a whole. Refer to section 2 for acute and chronic effects. Toxicological Information: ACGIH A4 - Not Classifiable as a Human Carcinogen. Carcinogenicity/Other Information: IARC ACGIH OSHA CAS# 141-78-6: Standard Draize Test, Eyes, Human, 400.0 PPM. Result: Liver: Hepatitis (hepatocellular necrosis), zonal. - Journal of Industrial Hygiene and Toxicology, Vol/p/yr: 25,282, 1943 CAS# 64742-95-6: Acute toxicity, LD50, Oral, Rat, 8400. MG/KG. Result: Behavioral: Somnolence (general depressed activity). Behavioral: Tremor. Lungs, Thorax, or Respiration:Other changes. - National Technical Information Service, Vol/p/yr: OTS0534799, Standard Draize Test, Eyes, Species: Rabbit, 100.0 UL, 24 H, Mild. Result: Brain and Coverings: Changes in surface EEG. Blood:Changes in serum composition (e.g. Related to Chronic Data - changes in testicular weight. - National Technical Information Service, Vol/p/yr: OTS0534779, CAS# 1330-20-7: Acute toxicity, LC50, Inhalation, Rat, 5000. PPM, 4 H. Result: Behavioral: Muscle contraction or spasticity. Lungs, Thorax, or Respiration:Other changes. - Raw Material Data Handbook, Vol.1: Organic Solvents, 1974., National Assoc. of Printing Ink Research Institute, Francis McDonald Sinclair Memorial Labor, Lehigh Univ., Bethlehem, PA 18015, Vol/p/yr: 1,123, 1974 Standard Draize Test, Eyes, Species: Rabbit, 5.000 MG, 24 H, Severe. Result: Behavioral: General anesthetic. Behavioral: Somnolence (general depressed activity). Behavioral: Irritability. - "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," , Institut Pro Vychovu Vedoucicn P, Marhold, J.V., Institut Pro Vychovu Vedoucicn, Pracovniku Chemickeho, Prumyclu Praha Czechoslovakia, Vol/p/yr: -,24, 1972 Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 405 of 871 Page 405 of 871 Page 405 of 871 Page 405 of 871 ---PAGE BREAK--- 04/13/2015 Revision: 04/13/2015 Printed: Page: 8 Klean-Strip Industrial Maintenance Coating Thinner SAFETY DATA SHEET 01/02/2015 Supersedes Revision: 64742-89-8 Light aliphatic solvent naphtha (petroleum) n.a. n.a. n.a. n.a. 141-78-6 Acetic acid, ethyl ester {Ethyl acetate} n.a. n.a. n.a. n.a. 64742-95-6 Petroleum Hydrocarbons n.a. n.a. n.a. n.a. 95-63-6 {Pseudocumene} n.a. n.a. n.a. n.a. 1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} n.a. 3 A4 n.a. This product has not been tested as a whole. General Ecological Information: 12. ECOLOGICAL INFORMATION Dispose in accordance with local, state, and federal regulations. Waste Disposal Method: 13. DISPOSAL CONSIDERATIONS 14. TRANSPORT INFORMATION Paint Related Material DOT Proper Shipping Name: 3 FLAMMABLE LIQUID DOT Hazard Class: UN1263 UN/NA Number: II Packing Group: LAND TRANSPORT (US DOT): The shipper/supplier may apply one of the following exceptions: Combustible Liquid, Consumer Commodity, Limited Quantity, Viscous Liquid, Does Not Sustain Combustion, or others, as allowed under 49CFR Hazmat Regulations. Please consult 49CFR Subchapter C to ensure that subsequent shipments comply with these exceptions. Additional Transport Information: CAS # Hazardous Components (Chemical Name) 15. REGULATORY INFORMATION S. 302 (EHS) S. 304 RQ S. 313 (TRI) EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists 64742-89-8 Light aliphatic solvent naphtha (petroleum) No No No 141-78-6 Acetic acid, ethyl ester {Ethyl acetate} No Yes 5000 LB No 64742-95-6 Petroleum Hydrocarbons No No No 95-63-6 {Pseudocumene} No No Yes 1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} No Yes 100 LB Yes Yes [ ] No Acute (immediate) Health Hazard Yes [ ] No Chronic (delayed) Health Hazard Yes [ ] No Fire Hazard [ ] Yes No Sudden Release of Pressure Hazard [ ] Yes No Reactive Hazard This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated: CAS # Hazardous Components (Chemical Name) Other US EPA or State Lists 64742-89-8 Light aliphatic solvent naphtha (petroleum) CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No 141-78-6 Acetic acid, ethyl ester {Ethyl acetate} CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory, 4 Test; CA PROP.65: No 64742-95-6 Petroleum Hydrocarbons CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No 95-63-6 {Pseudocumene} CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 406 of 871 Page 406 of 871 Page 406 of 871 Page 406 of 871 ---PAGE BREAK--- 04/13/2015 Revision: 04/13/2015 Printed: Page: 9 Klean-Strip Industrial Maintenance Coating Thinner SAFETY DATA SHEET 01/02/2015 Supersedes Revision: Inventory; CA PROP.65: No 1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} CAA HAP,ODC: HAP; CWA NPDES: Yes; TSCA: Yes - Inventory; CA PROP.65: No 16. OTHER INFORMATION No data available. Additional Information About This Product: The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, state and local laws and regulations. Company Policy or Disclaimer: 04/13/2015 Revision Date: W.M. Barr EHS Department (901)775-0100 Preparer Name: Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 407 of 871 Page 407 of 871 Page 407 of 871 Page 407 of 871 ---PAGE BREAK--- Page 1 / 9 Material Safety Data Sheet Issuing Date 13-Jul-2012 Revision Date 1. PRODUCT AND COMPANY IDENTIFICATION Revision Number 0 Product Name KOPR-SHIELD® Product Code(s) CP-4, CP-8, CP-16, CP-128, CP12B, NDS20131879, 20131879, 201318791, A7297-1 UN-Number UN3082 Recommended Use Lubricants, Greases and Release Products, CONDUCTOR TERMINATION COMPOUND Synonyms THOMAS & BETTS KOPR-SHIELD® Manufacturer Address Jet-Lube, Inc. 4849 Homestead Rd. Suite 232 Houston, TX 77379 TEL: [PHONE REDACTED] Emergency Telephone Number EU: 44 1628-631913 North America: [PHONE REDACTED] 2. HAZARDS IDENTIFICATION CAUTION! Emergency Overview The product contains no substances which at their given concentration are considered to be hazardous to health Appearance Copper Physical State Semi-fluid (gel). Odor Petroleum like Potential Health Effects Acute Toxicity Eyes May cause slight irritation. Skin Prolonged or repeated contact may cause skin dryness or cracking. Inhalation No known effect based on information supplied. Ingestion Not an expected route of exposure. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Chronic Effects No known effect based on information supplied. Aggravated Medical Conditions None known. Environmental Hazard Very toxic to aquatic organisms. See Section 12 for additional Ecological Information. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Page 408 of 871 Page 408 of 871 Page 408 of 871 Page 408 of 871 ---PAGE BREAK--- Page 2 / 9 WPS-JLI-040NA - KOPR-SHIELD® Revision Date Lubricating greases A complex combination of hydrocarbons having carbon numbers predominantly in the range of C12 through C50. may contain organic salts of alkali metals, alkaline earth metals, etc. 74869-21-9 65-70 Copper 7440-50-8 25-30 4. FIRST AID MEASURES Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Skin Contact Wash skin with soap and water. Inhalation Move to fresh air. Ingestion Clean mouth with water and afterwards drink plenty of water. Consult a physician. Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Flammable Properties Not flammable. Flash Point > 310°C Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Water spray jet Explosion Data Sensitivity to Mechanical Impact None Sensitivity to Static Discharge None Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health Hazard 0 Flammability 1 Instability 0 Physical and Chemical Hazards - HMIS Health Hazard 0 Flammability 1 Physical Hazard 0 Personal Protection X 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Use personal protective equipment. Avoid contact with the skin and the eyes. Environmental Precautions Do not allow material to contaminate ground water system. Local authorities should be advised if significant spillages cannot be contained. Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up Use personal protective equipment. Take up mechanically and collect in suitable container for disposal. Clean contaminated surface thoroughly. 7. HANDLING AND STORAGE Handling Wear personal protective equipment. Avoid contact with skin and eyes. Wash thoroughly after handling. Storage Keep containers closed in a dry, cool and well-ventilated place. Page 409 of 871 Page 409 of 871 Page 409 of 871 Page 409 of 871 ---PAGE BREAK--- Page 3 / 9 WPS-JLI-040NA - KOPR-SHIELD® Revision Date 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Copper 7440-50-8 TWA: 0.2 mg/m3fume TWA: 0.1 mg/m3fume TWA: 1 mg/m3dust and mist (vacated) TWA: 0.1 mg/m3 Cu dust, fume, mist IDLH: 100 mg/m3dust, fume and mist TWA: 1 mg/m3 dust and mist TWA: 0.1 mg/m3 fume OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. NIOSH IDLH: Immediately Dangerous to Life or Health. Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Engineering Measures Showers Eyewash stations Ventilation systems Personal Protective Equipment Eye/Face Protection Safety glasses with side-shields. Skin and Body Protection Protective gloves. Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Hygiene Measures Wash hands before breaks and at the end of workday. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Copper. Odor Petroleum like. Odor Threshold No information available Physical State Semi-fluid (gel) pH Neutral Flash Point > 310°C Decomposition Temperature No information available. Melting Point/Range NONE Flammability Limits in Air No information available. Autoignition Temperature No information available. Boiling Point/Boiling Range >315°C Specific Gravity 1.20 Solubility Largely Water Solubility Insoluble in water. Evaporation Rate No information available Vapor Pressure No data available. Vapor Density No data available. 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions. Decomposes in contact with water. Incompatible Products Strong oxidizing agents. Acids. Water. Conditions to Avoid None known based on information supplied. Hazardous Decomposition Products None known based on information supplied. Hazardous Polymerization Hazardous polymerization does not occur. Page 410 of 871 Page 410 of 871 Page 410 of 871 Page 410 of 871 ---PAGE BREAK--- Page 4 / 9 WPS-JLI-040NA - KOPR-SHIELD® Revision Date 11. TOXICOLOGICAL INFORMATION Acute Toxicity Product Information Product does not present an acute toxicity hazard based on known or supplied information. Inhalation None under normal use condtions Eye Contact Contact with eyes may cause irritation. Skin Contact Non-irritating during normal use Prolonged or repeated contact may dry skin and cause irritation. Ingestion Not an expected route of exposure. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Lubricating greases A complex combination of hydrocarbons having carbon numbers predominantly in the range of C12 through C50. may contain organic salts of alkali metals, alkaline earth metals, etc. = 2280 mg/kg ( Rat ) Chronic Toxicity Sensitization None known. Mutagenic Effects None known. Reproductive Toxicity None known. Developmental Toxicity None known. Target Organ Effects None known. Page 411 of 871 Page 411 of 871 Page 411 of 871 Page 411 of 871 ---PAGE BREAK--- Page 5 / 9 WPS-JLI-040NA - KOPR-SHIELD® Revision Date 12. ECOLOGICAL INFORMATION This product contains a chemical which is listed as a severe marine pollutant according to DOT. Ecotoxicity Very toxic to aquatic organisms. Ecotoxicity effects of component substances. Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Microorganisms Daphnia Magna (Water Flea) Lubricating greases A complex combination of hydrocarbons having carbon numbers predominantly in the range of C12 through C50. may contain organic salts of alkali metals, alkaline earth metals, etc. LC50 96 h: > 2000 mg/L (Salmo gairdneri) Copper EC50 96 h: 0.031 - 0.054 mg/L static (Pseudokirchneriella subcapitata) EC50 72 h: 0.0426 - 0.0535 mg/L static (Pseudokirchneriella subcapitata) LC50 96 h: 0.0068 - 0.0156 mg/L (Pimephales promelas) LC50 96 h: < 0.3 mg/L static (Pimephales promelas) LC50 96 h: = 0.052 mg/L flow-through mykiss) LC50 96 h: = 0.112 mg/L flow-through (Poecilia reticulata) LC50 96 h: = 0.2 mg/L flow- through (Pimephales promelas) LC50 96 h: = 0.3 mg/L semi- static (Cyprinus carpio) LC50 96 h: = 0.8 mg/L static (Cyprinus carpio) LC50 96 h: = 1.25 mg/L static (Lepomis macrochirus) - EC50 48 h: = 0.03 mg/L Static (Daphnia magna) Persistence and Degradability Not readily biodegradable. 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated Packaging Do not re-use empty containers. This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Copper Toxic Page 412 of 871 Page 412 of 871 Page 412 of 871 Page 412 of 871 ---PAGE BREAK--- Page 6 / 9 WPS-JLI-040NA - KOPR-SHIELD® Revision Date 14. TRANSPORT INFORMATION DOT UN-Number UN3082 Proper shipping name Environmentally hazardous substances, liquid, n.o.s. Hazard Class 9 Subsidiary Class Packing Group III Marine Pollutant This product contains a chemical which is listed as a severe marine pollutant according to DOT. Description UN3082, Environmentally hazardous substances, liquid, n.o.s.(Copper), 9, , III,Marine Pollutant Emergency Response Guide Number 171 TDG UN-Number UN3082 Proper Shipping Name Environmentally hazardous substance, liquid, n.o.s. Hazard Class 9 Packing Group III Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(Copper), 9, III,Marine Pollutant MEX UN-Number UN3082 Proper Shipping Name Environmentally hazardous substances, liquid, n.o.s. Hazard Class 9 Packing Group III Description UN3082 Environmentally hazardous substances, liquid, n.o.s.(Copper), 9, III ICAO UN-Number UN3082 Proper shipping name Environmentally hazardous substance, liquid, n.o.s. Hazard Class 9 Packing Group III Description UN3082, Environmentally hazardous substance, liquid, n.o.s.(Copper), 9, III IATA UN-Number UN3082 Proper Shipping Name Environmentally hazardous substance, liquid, n.o.s. Hazard Class 9 Packing Group III ERG Code 9L Description UN3082, Environmentally hazardous substance, liquid, n.o.s.(Copper), 9, III IMDG/IMO UN-Number UN3082 Proper Shipping Name Environmentally hazardous substance, liquid, n.o.s. Hazard Class 9 Packing Group III EmS No. F-A, S-F Marine Pollutant Product is a marine pollutant according to the criteria set by IMDG/IMO Description UN3082, Environmentally hazardous substance, liquid, n.o.s.(Copper), 9, III,Marine Pollutant RID UN-Number UN3082 Proper Shipping Name Environmentally hazardous substance, liquid, n.o.s. Hazard Class 9 Page 413 of 871 Page 413 of 871 Page 413 of 871 Page 413 of 871 ---PAGE BREAK--- Page 7 / 9 WPS-JLI-040NA - KOPR-SHIELD® Revision Date Packing Group III Classification Code M6 Description UN3082 Environmentally hazardous substance, liquid, n.o.s.(Copper), 9, III ADR UN-Number UN3082 Proper Shipping Name Environmentally hazardous substance, liquid, n.o.s. Hazard Class 9 Packing Group III Classification Code M6 Description UN3082 Environmentally hazardous substance, liquid, n.o.s.(Copper), 9, III(E) ADN UN-No UN3082 Proper Shipping Name Environmentally hazardous substance, liquid, n.o.s. Hazard Class 9 Packing Group III Classification Code M6 Special Provisions 274, 335, 601 Description UN3082 Environmentally hazardous substance, liquid, n.o.s.(Copper), 9, III Hazard Labels 9 Limited Quantity LQ7 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL Complies EINECS Complies ENCS Not determined IECSC Not determined KECL Not determined PICCS Not determined AICS Not determined Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List U.S. Federal Regulations Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name CAS-No Weight % SARA 313 - Threshold Values % Copper 7440-50-8 29.8 1.0 SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42): Page 414 of 871 Page 414 of 871 Page 414 of 871 Page 414 of 871 ---PAGE BREAK--- Page 8 / 9 WPS-JLI-040NA - KOPR-SHIELD® Revision Date Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Copper X X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs RQ Copper 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Illinois Rhode Island Copper X X X X X International Regulations Mexico - Grade Slight risk, Grade 1 Chemical Name Carcinogen Status Exposure Limits Copper Mexico: TWA= 1 mg/m3 Mexico: TWA= 0.2 mg/m3 Mexico: STEL= 2 mg/m3 Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class Non-controlled Page 415 of 871 Page 415 of 871 Page 415 of 871 Page 415 of 871 ---PAGE BREAK--- Page 9 / 9 WPS-JLI-040NA - KOPR-SHIELD® Revision Date 16. OTHER INFORMATION Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-[PHONE REDACTED] Issuing Date 13-Jul-2012 Revision Date Revision Note Initial Release General Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of Safety Data Sheet Page 416 of 871 Page 416 of 871 Page 416 of 871 Page 416 of 871 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 MATERIAL SAFETY DATA SHEET 1 PRODUCT AND COMPANY IDENTIFICATION Product Name: KRUD KUTTER® Concrete Clean and Etch Synonyms: Not applicable Molecular Formula: Not applicable Molecular Weight: Not applicable Supplier: Supreme Chemicals of Georgia, Inc. 1535 Oak Industrial Lane, Suite B Cumming, GA 30041 USA Emergency Telephone: (CHEMTREC) [PHONE REDACTED] (Non-emergency Telephone) 800- 466-7126 Intended Use: Cleaning agent 2 HAZARDS IDENTIFICATION Emergency Overview Physical State: Liquid Color: Translucent orange Odor: Bland WARNING! Causes skin and eye irritation. Mist or vapors irritating to eyes and respiratory tract. Potential Health Effects Inhalation: Mist or vapor irritating to eyes and respiratory tract. Exposure may cause coughing, asthmatic breathing and irritation. Eye Contact: Causes eye irritation. Exposure may cause eye tearing, redness and discomfort. Skin Contact: Causes skin irritation. Exposure may cause redness, itching and inflammation. Ingestion: Not expected to be an ingestion hazard for intended use. Exposure may cause gastrointestinal irritation, nausea, vomiting, diarrhea and other systemic effects. Chronic Health Effects: None known Target Organ(s): Eye, skin, respiratory tract OSHA Regulatory Status: Hazardous; consumer product use is exempt. North America MSDS 1/8 Page 417 of 871 Page 417 of 871 Page 417 of 871 Page 417 of 871 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 3 COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No. Weight % phosphoric acid 7664-38-2 < 40 % Components not listed are not hazardous or are below reportable limits 4 FIRST AID MEASURES Inhalation: If inhaled, remove to fresh air. Get medical attention if persist. Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. Get medical attention. Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Ingestion: If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. If vomiting occurs, keep head lower than the hips to help prevent aspiration. Never give anything by mouth to an unconscious person. Get medical attention. 5 FIRE-FIGHTING MEASURES Extinguishing Media: Water spray, carbon dioxide, dry chemical or alcohol foam Unsuitable Extinguishing Media: None known Special Fire Fighting Procedures: Wear self-contained breathing apparatus and protective clothing. Unusual Fire & Explosion Hazards: None known Hazardous Combustion Products: Carbon oxides, phosphorous oxides 6 ACCIDENTAL RELEASE MEASURES Personal Precautions: Wear appropriate personal protective equipment. See Section 8. Spill Cleanup Methods: Small Liquid Spills: Wipe up or use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Large Spillages: Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use water spray to reduce vapors or divert vapor cloud drift. Isolate and stay upwind. Ventilate enclosed areas. Keep unauthorized personnel away. Prevent entry into waterways, sewer, basements or confined areas. 7 HANDLING AND STORAGE Handling: Avoid breathing mist or vapors. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Wash thoroughly after handling. North America MSDS 2/8 Page 418 of 871 Page 418 of 871 Page 418 of 871 Page 418 of 871 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 Prevention of Fire and Explosion: None Storage: Keep container closed. Store in original container. Keep out of reach of children. 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Industrial Exposures: Exposure Limits: Chemical Name Source Type Exposure Limits Notes phosphoric acid NIOSH REL 1 mg/m³ phosphoric acid NIOSH STEL 3 mg/m³ phosphoric acid NIOSH IDLH 1000 mg/m³ phosphoric acid ACGIH TWA 1 mg/m³ Upper respiratory tract eye & skin irritant phosphoric acid ACGIH STEL 3 mg/m³ Upper respiratory tract eye & skin irritant phosphoric acid OSHA Z-1 PEL 1 mg/m³ phosphoric acid California TWA 1 mg/m³ phosphoric acid California STEL 3 mg/m³ phosphoric acid Alberta, Canada TWA 1 mg/m³ Irritation phosphoric acid Alberta, Canada STEL 3 mg/m³ Irritation phosphoric acid British Columbia, Canada TWA 1 mg/m³ phosphoric acid British Columbia, Canada STEL 3 mg/m³ phosphoric acid Ontario, Canada TWA 1 mg/m³ phosphoric acid Ontario, Canada STEL 3 mg/m³ phosphoric acid Quebec, Canada TWA 1 mg/m³ phosphoric acid Quebec, Canada STEL 3 mg/m³ phosphoric acid Mexico TWA 1 mg/m³ phosphoric acid Mexico STEL 3 mg/m³ Engineering Controls: Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. Respiratory Protection: If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. In the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA Standard 63 FR 1152, January 8, 1998. Respirator type: Air-purifying respirator with an appropriate, government approved (where applicable), air-purifying filter, cartridge or canister. Contact health and safety professional or manufacturer for specific information. North America MSDS 3/8 Page 419 of 871 Page 419 of 871 Page 419 of 871 Page 419 of 871 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 Eye Protection: Wear splash goggles and a face shield or safety glasses with side shields. Hand Protection: Wear chemical resistant gloves. Skin Protection: Wear protective clothing appropriate for the risk of exposure. Hygiene Measures: Eye wash, washing facilities, safety shower 9 PHYSICAL AND CHEMICAL PROPERTIES Color: Translucent orange Odor: Bland Physical State: Liquid pH: No data available Boiling Point: 218º C (424.4º F) Melting Point: < -1.1° C (30° F) Flash Point: None Evaporation Rate: < 1 (Water = 1) Flammability: None Flammability Limit – Upper Not applicable Flammability Limit – Lower Not applicable Vapor Pressure: 17 mm Hg 20 ºC) (68° F) Vapor Density (Air=1): 3.2 Specific Gravity: 1.1 – 1.3 Solubility in Water: Complete Partition Coefficient (n-Octanol/water): No data available Autoignition Temperature: Not applicable Decomposition Temperature: No data available Volatile Organic Compounds (VOC): No data available Viscosity: No data available Percent Volatile: No data available 10 STABILITY AND REACTIVITY Stability: Stable Conditions to Avoid: None known Incompatible Materials: Strong oxidizing agents, alkalis Hazardous Decomposition Products: Carbon oxides, phosphorous oxides Possibility of Hazardous Reactions: Will not occur. 11 TOXICOLOGICAL INFORMATION Information available upon request. Listed Carcinogens: None North America MSDS 4/8 Page 420 of 871 Page 420 of 871 Page 420 of 871 Page 420 of 871 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 12 ECOLOGICAL INFORMATION Krud Kutter® Concrete Clean and Etch is biodegradable. 13 DISPOSAL CONSIDERATIONS General Information: Dispose in accordance with applicable federal, state, and local regulations. Disposal Methods: No specific disposal method required. Container: Since emptied containers retain product residue, follow label warnings even after container is emptied. 14 TRANSPORT INFORMATION DOT: ORM-D Proper Shipping Name: Consumer Commodity Packaging Requirements: Inner packagings not over 5.0 Liters (1.3 Gallons) net capacity each for liquids, and packed in strong outer packagings. Packages over 5.0 Liters (1.3 Gallons): UN-Number: 1805 Proper Shipping Name: Phosphoric Acid Solution Class: 8 Packaging Group: III Emergency Response Guide Number: 154 TDG: UN-Number: 1805 Proper Shipping Name: Phosphoric Acid Solution Class: 8 Packaging Group: III Emergency Response Guide Number: 154 IATA: For Limited Quantities of liquids of Class 8 Packing Group III: Passenger & Cargo Aircraft Packing Instructions: Y819 Passenger & Cargo Aircraft Limited Quantity Maximum Quantity Package: 1 Liter Single packagings are not permitted. The inner packagings must be packed in one of the following outer packagings with sufficient cushioning/absorbent material so as to prevent movement/leakage. The maximum quantity must not exceeded. Inner packagings: glass earthenware, plastic, metal (not aluminum), or glass ampoule. Outer Packaging: Steel packagings must be corrosion-resistant or with protection against corrosion. Glass or earthenware inner packagings and glass ampoules must be packaged with absorbent material in closed metal or rigid plastic receptacles in outer packagings. Glass or earthenware inner packagings and glass ampoules are permitted if this item is free from hydrofluoric acid. Outer Packaging: Drums: Steel, aluminum, plywood, fiber, plastic. Jerricans: Steel, aluminum, plastic Boxes: UN Certified Box, steel, aluminum, wood, plywood, reconstituted wood, fiber board and plastic North America MSDS 5/8 Page 421 of 871 Page 421 of 871 Page 421 of 871 Page 421 of 871 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 Passenger & Cargo Aircraft Packing Instructions: 819 Passenger & Cargo Aircraft Maximum Quantity/Package: 5 Liters Single packagings are not permitted. The inner packagings must be packed in one of the following outer packagings with sufficient cushioning/absorbent material so as to prevent movement/leakage. The maximum quantity must not exceeded. Inner packagings: glass earthenware, plastic, metal (not aluminum), or glass ampoule. Outer Packaging: Steel packagings must be corrosion-resistant or with protection against corrosion. Glass or earthenware inner packagings and glass ampoules must be packaged with absorbent material in closed metal or rigid plastic receptacles in outer packagings. Glass or earthenware inner packagings and glass ampoules are permitted if this item is free from hydrofluoric acid. Outer Packaging: Drums: Steel (1A2), aluminum (1B2), plywood (1D), fiber (1G), plastic (1H2). Jerricans: Steel (4A), Aluminum (4B), Plastic (3H2); Boxes: UN Certified Box, Steel (4A), aluminum (3B2), wood (4C1,4C2), plywood (4D), reconstituted wood (5F), fiber board (4G) and plastic (4H1, 4H2). Cargo Aircraft Only Package Instruction: 821 Cargo Aircraft Only Maximum Quantity/Package: 60 Liters Combination and single packagings are permitted. The inner packagings must be packed in one of the following outer packagings with sufficient cushioning/absorbent material so as to prevent movement/leakage. Combination packagings: inner packagings: Glass or earthenware, plastic, metal (not aluminum) or glass ampoule. Outer packaging: Drums: Steel (1A2), aluminum (1B2), plywood (1D), fiber (1G), plastic (1H2). Jerricans: Steel (3A2), aluminum (3B2), plastic (1H2); Boxes: UN Certified Box, steel(4A), aluminum (4B), wood (4C1,4C2), plywood (4D), reconstituted wood (4F), fiber board (4G) and plastic (4H1, 4H2). Special Provisions: A3 ERG Code: 8L Packages over 5.0 Liters (1.3 Gallons): UN-Number: 1805 Proper Shipping Name: Phosphoric Acid Solution Class: 8 Packaging Group: III Emergency Response Guide Number: 154 IMDG: Limited Quantities Exception: Dangerous Goods in limited quantities of Class 8. Limited quantities must be packed in combination packaging. The inner packaging must be within the quantity limit specified in the Dangerous Goods List (DGL) for the substance being prepared for shipment and be packaged in suitable outer packaging (i.e. UN certified box). The gross mass of the package must not exceed 30 kilograms (66 pounds). For over 30 kilograms (66 pounds): UN-Number: 1805 Proper Shipping Name: Phosphoric Acid Solution Class: 8 Packaging Group: III EMS No: F-A, S-B Special Provision: 223 Packing Instructions: P001, LP01 North America MSDS 6/8 Page 422 of 871 Page 422 of 871 Page 422 of 871 Page 422 of 871 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 IBC 03 Portable tanks and bulk containers: IMO Tank Instructions: T3 UN Tank Instructions: T4 Provisions: TP1 Stowage and Segregation: Category A 15 REGULATORY INFORMATION Canadian Controlled Products Regulations: This product has been classified according to the hazard criteria of the Canadian Controlled Products Regulations, Section 33, and the MSDS contains all required information. WHMIS Classification: D2B Mexico: Hazard Identification Guidance List: Phosphoric Acid: 3-0-0 PPE: F Inventory Status This product or all components are listed on the following inventory: TSCA DSL Inventory: No information available US Regulations CERCLA Hazardous Substance List (40 CFR 302.4): Component Reportable Quantity phosphoric acid 5,000 lbs SARA Title III Section 302Extremely Hazardous Substance (40 CFR 355, Appendix None Section 311/312 (40 CFR 370): X Acute (Immediate) Chronic (Delayed) Fire Reactive Pressure Generating Section 313 Toxic Release Inventory (40 CFR 372): None Clean Air Act (CCA) Section 112, 1990 Amendments, Statutory Hazardous Air Pollutants: None Clean Air Act (CAA) Section 112(i) High-Risk Hazardous Air Pollutants (40 CFR 63.74): None Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): None Clean Water Act Section 307 Toxic Pollutants (40 CFR 401.15): None Clean Water Act Section 311 Hazardous Chemical (40 CFR 116.4): Phosphoric acid Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3): Component Reportable Quantity phosphoric acid 5,000 lbs North America MSDS 7/8 Page 423 of 871 Page 423 of 871 Page 423 of 871 Page 423 of 871 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 Drug Enforcement Act: None TSCA: None . State Regulations California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): None Massachusetts Right-To-Know List: Phosphoric Acid Minnesota Hazardous Substances List: Phosphoric Acid New Jersey Right-To-Know List: Phosphoric Acid Right-To-Know Substances: Phosphoric Acid 16 OTHER INFORMATION Hazard Ratings Health Hazard Fire Hazard Reactivity Hazard Special Hazard NFPA 2 0 0 N/A Health Hazard Fire Hazard Reactivity Hazard HMIS 2 0 0 0 – Minimal; 1 – Slight; 2 – Moderate; 3 – Serious; 4 – Severe; Chronic health effect Revision Information: New Prepared by: Supreme Chemicals of Georgia, Inc. Issue Date: 8/28/2007 Disclaimer: To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. North America MSDS 8/8 Page 424 of 871 Page 424 of 871 Page 424 of 871 Page 424 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 04-May-2005 1.CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product code 84782 Product name Kwik Grip Epoxy Recommended Use Repair Material Supplier Lawson Products, Inc. 1666 East Touhy Avenue Des Plaines, IL 60018 (847)-827-9666 Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions Pre-existing skin, eye, or respiratory conditions may be aggravated by exposure to this product. Principal Routes of Exposure Eyes. Skin. Inhalation. Ingestion. Potential health effects Eyes Irritation. Skin Skin Irritation. Allergic reaction. Inhalation May cause irritation of the nose and throat. Ingestion Repeated or prolonged exposure may cause:. Gastrointestinal irritation. Central nervous system effects. Reproductive system damage. 3. COMPOSITION/INFORMATION ON INGREDIENTS Page 1 / 9 Emergency Overview Irritant. Form Solid Color Black & White Odor Unpleasant Page 425 of 871 Page 425 of 871 Page 425 of 871 Page 425 of 871 ---PAGE BREAK--- Product code 84782 Product name Kwik Grip Epoxy Chemical Name CAS-No Weight % Aluminum Oxide 1344-28-1 40-70 Bisphenol A - Epichlorohydrin polymer 25068-38-6 10-30 Distillates, petroleum, heavy thermal cracked 64741-81-7 1-5 2,4,6-Tri(dimethylaminomethyl)phenol 90-72-2 1.5 Styrene 100-42-5 3-7 Fumed Silica 112945-52-5 1-5 Ethylene glycol 107-21-1 1-5 Benz[a]anthracene 56-55-3 0.1-1.0 Polymercaptan 101359-87-9 10-30 Titanium dioxide 13463-67-7 1-5 4. FIRST AID MEASURES Eye contact Flush with plenty of water for at least 15 minutes. Seek medical attention if irritation persists. Skin contact Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. Seek medical attention if irritation persists. Ingestion Do not induce vomiting. Give victim a glass of water or milk. Seek medical attention immediately. Inhalation Remove to fresh air. Provide oxygen or artificial respiration if necessary. Seek medical attention. 5. FIRE FIGHTING MEASURES Flash point °C > 93 Flash point °F > 200 Method Tag closed cup Autoignition temperature °C No data available Autoignition temperature °F Flammability Limits in Air) Upper 12 Lower 2 Suitable extinguishing media Carbon dioxide. Dry chemical. Foam. Extinguishing media which must NOT be used for safety reasons No information available. Special Fire-Fighting Procedures Firefighters should wear NIOSH/MSHA approved (or equivalent) self-contained pressure-demand breathing apparatus and full protective clothing. 6. ACCIDENTAL RELEASE MEASURES Page 2 / 9 Sensitivity to static discharge No information available. Sensitivity to shock No information available. Page 426 of 871 Page 426 of 871 Page 426 of 871 Page 426 of 871 ---PAGE BREAK--- Product code 84782 Product name Kwik Grip Epoxy Methods for cleaning up Eliminate all sources of ignition. Ventilate area to maintain exposure below permissible exposure limits. Soak up with inert absorbent material. Collect and contain for disposal. 7. HANDLING AND STORAGE Handling Avoid prolonged inhalation of vapor or mist. Storage Store in temperatures below 100 degrees F. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Aluminum Oxide 15 mg/m³ total dust 5 mg/m³ respirable fraction - 10 mg/m³ particulate matter containing no asbestos and < 1% silica - Bisphenol A - Epichlorohydrin polymer - - - - Polymercaptan - - - - Styrene 100 ppm 200 ppm 20 ppm 40 ppm Distillates, petroleum, heavy thermal cracked - - - - 2,4,6- Tri(dimethylaminomethy l)phenol - - - - Fumed Silica - - - - Titanium dioxide 15 mg/m³ total dust - 10 mg/m³ - Ethylene glycol - - - - Benz[a]anthracene - - - - Ventilation and Environmental Controls Adequate ventilation should be provided to keep exposure levels below current acceptable exposure limits. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Personal protective equipment Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment. Hand protection Rubber gloves. Plastic gloves. Eye protection Safety glasses. Skin and body protection No information available Page 3 / 9 Page 427 of 871 Page 427 of 871 Page 427 of 871 Page 427 of 871 ---PAGE BREAK--- Product code 84782 Product name Kwik Grip Epoxy 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Avoid heat. Materials to avoid Strong oxidizers. Hazardous decomposition products Irritating organic vapors. Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat) LD50 (dermal,rat/rabbit) LC50 (inhalation,rat) Aluminum Oxide 1344-28-1 - - - Bisphenol A - Epichlorohydrin polymer 25068-38-6 11400 mg/kg - - Polymercaptan 101359-87-9 - - - Styrene 100-42-5 2650 mg/kg - 12 g/m3 Distillates, petroleum, heavy thermal cracked 64741-81-7 - - - Page 4 / 9 Vapor density No data available Evaporation Rate No data available Odor Water solubility No data available Unpleasant Partition Coefficient (n-octanol/water) No data available Synergistic Products No information available. Form Odor Threshold No information available Solid Boiling point/range °C No data available pH Boiling point/range °F No data available No data available Melting point/range °C No data available Melting point/range °F No data available Specific Gravity Flash point °C > 93 1.4 - 1.68 Flash point °F > 200 Color Vapor pressure No data available Black & White Page 428 of 871 Page 428 of 871 Page 428 of 871 Page 428 of 871 ---PAGE BREAK--- Product code 84782 Product name Kwik Grip Epoxy 2,4,6- Tri(dimethylaminomethyl)p henol 90-72-2 1200 mg/kg - - Fumed Silica 112945-52-5 3160 mg/kg - - Titanium dioxide 13463-67-7 - - - Ethylene glycol 107-21-1 4700 mg/kg 9530 µL/kg - Benz[a]anthracene 56-55-3 - - - Potential health effects Target Organ Effects No information available Carcinogenic effects See table below Page 5 / 9 Chronic toxicity No information available. Mutagenic effects No information available. Sensitization No information available. Teratogenic effects No information available Reproductive toxicity No information available Page 429 of 871 Page 429 of 871 Page 429 of 871 Page 429 of 871 ---PAGE BREAK--- Product code 84782 Product name Kwik Grip Epoxy Chemical Name ACGIH OEL - Carcinogens IARC NTP - Known Carcinogens NTP - Suspected Human Carcinogens OSHA RTK Carcinogens Aluminum Oxide A4 - Not Classifiable as a Human Carcinogen Not Listed Not Listed Not Listed Not Listed Bisphenol A - Epichlorohydrin polymer Not Listed Not Listed Not Listed Not Listed Not Listed Polymercaptan Not Listed Not Listed Not Listed Not Listed Not Listed Styrene A4 - Not Classifiable as a Human Carcinogen Group 2B Not Listed Not Listed Listed Distillates, petroleum, heavy thermal cracked Not Listed Not Listed Not Listed Not Listed Not Listed 2,4,6- Tri(dimethylaminomethyl)phe nol Not Listed Not Listed Not Listed Not Listed Not Listed Fumed Silica Not Listed Not Listed Not Listed Not Listed Not Listed Titanium dioxide A4 - Not Classifiable as a Human Carcinogen Not Listed Not Listed Not Listed Not Listed Ethylene glycol A4 - Not Classifiable as a Human Carcinogen (aerosol) Not Listed Not Listed Not Listed Not Listed Benz[a]anthracene A2 - Suspected Human Carcinogen Group 2A Not Listed Suspect Listed 12. ECOLOGICAL INFORMATION Aquatic toxicity Page 6 / 9 Water Flea Data water flea LC50=46300 mg/L (48 h) Styrene Benz[a]anthracene Water Flea Data water flea EC50=23.0 mg/L (48 h) Microtox Data Photobacterium phosphoreum EC50=0.26 mg/L (15 min) Ethylene glycol Microtox Data Photobacterium phosphoreum EC50=620.0 mg/L (30 min) Microtox Data Photobacterium phosphoreum EC50=5.4 mg/L (5 min) Page 430 of 871 Page 430 of 871 Page 430 of 871 Page 430 of 871 ---PAGE BREAK--- Product code 84782 Product name Kwik Grip Epoxy 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORT INFORMATION DOT Not Regulated TDG Not Regulated IMDG/IMO Not Regulated IATA Not Regulated MEX Not Regulated 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Aluminum Oxide Listed Styrene Listed Ethylene glycol Listed Benz[a]anthracene Listed Listed State Regulations Page 7 / 9 Water Flea Data water flea EC50=0.01 mg/L (96 h) Page 431 of 871 Page 431 of 871 Page 431 of 871 Page 431 of 871 ---PAGE BREAK--- Product code 84782 Product name Kwik Grip Epoxy Chemical Name New Jersey - RTK - RTK California Prop. 65 Aluminum Oxide Not Listed Listed Not Listed Bisphenol A - Epichlorohydrin polymer Not Listed Not Listed Not Listed Polymercaptan Not Listed Not Listed Not Listed Styrene Listed Listed Not Listed Distillates, petroleum, heavy thermal cracked Not Listed Not Listed Not Listed 2,4,6- Tri(dimethylaminomethyl)phe nol Not Listed Not Listed Not Listed Fumed Silica Not Listed Not Listed Not Listed Titanium dioxide Not Listed Listed Not Listed Ethylene glycol Listed Listed Not Listed Benz[a]anthracene Listed Listed Carcinogen International Inventories Chemical Name EINECS DSL NDSL TSCA Aluminum Oxide X X - X Bisphenol A - Epichlorohydrin polymer - X - X Polymercaptan - - - - Styrene X X - X Distillates, petroleum, heavy thermal cracked X X - X 2,4,6-Tri(dimethylaminomethyl)phenol X X - X Fumed Silica - X - - Titanium dioxide X X X X - X Ethylene glycol X X - X Benz[a]anthracene X - X X CPRC This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations Page 8 / 9 Page 432 of 871 Page 432 of 871 Page 432 of 871 Page 432 of 871 ---PAGE BREAK--- Product code 84782 Product name Kwik Grip Epoxy 16. OTHER INFORMATION Reason for revision No information available. Prepared By T. Heidorn, MSDS Project Lead The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 9 / 9 HMIS NFPA Health 1 Health Flammability 1 Reactivity 1 Physical Hazard 0 1 Flammability 1 Page 433 of 871 Page 433 of 871 Page 433 of 871 Page 433 of 871 ---PAGE BREAK--- 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product code 83603 Product name Kwikee Penetrant with A/T plus Moly Recommended Use Penetrant Supplier Lawson Products, Inc. 1666 East Touhy Avenue Des Plaines, IL 60018 (847)-827-9666 Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known. Principal Routes of Exposure Skin. Ingestion. Inhalation. Potential health effects Eyes Contact with eyes may cause irritation. Severity depends on degree of exposure. Skin May cause the following effects: . Mild irritation. Defatting. Inhalation May cause the following effects. Dizziness. Prolonged overexposure may cause. Possible unconsciousness. Ingestion May cause the following effects. Headache. Nausea. Drowsiness . Unconsciousness. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % 2-Butoxyethanol 111-76-2 5-10 Toluene 108-88-3 0-5 Isopropyl alcohol 67-63-0 5-15 Mineral Spirits 64742-47-8 30-60 Mineral Seal Oil 64741-44-2 35-45 Page 1 / 6 Emergency Overview Irritant. Combustible material. Revision Date 13-Dec-2010 Material Safety Data Sheet Form Liquid Color Black Odor Mild Solvent Page 434 of 871 Page 434 of 871 Page 434 of 871 Page 434 of 871 ---PAGE BREAK--- 4. FIRST AID MEASURES Eye contact Flush with plenty of water for at least 15 minutes. Skin contact Wash off immediately with soap and plenty of water. If skin irritation persists, call a physician. Ingestion Call a physician or Poison Control Center immediately. Inhalation Remove to fresh air. 5. FIRE FIGHTING MEASURES Flash point °C > 85 Flash point °F > 185 Method Tag Closed Cup Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 6.0 Lower 1.0 Suitable extinguishing media Carbon dioxide (CO2). Foam. Water fog. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Fire and Explosion Hazards Combustible liquid. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Absorb with fire resistant absorbent. Pick up and transfer to properly labelled containers. 7. HANDLING AND STORAGE Handling Keep away from open flames, hot surfaces and sources of ignition. Keep container sealed. Storage Keep closed in a dry and cool place. Store at room temperature. Page 2 / 6 Product code 83603 Sensitivity to static discharge No information available. Product name Kwikee Penetrant with A/T plus Moly Sensitivity to shock No information available. Page 435 of 871 Page 435 of 871 Page 435 of 871 Page 435 of 871 ---PAGE BREAK--- 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Mineral Seal Oil - - - - Mineral Spirits - - - - Isopropyl alcohol 400 ppm 980 mg/m3 - 200 ppm 400 ppm 2-Butoxyethanol 240 mg/m3 50 ppm - 20 ppm - Toluene 200 ppm 300 ppm 20 ppm - Ventilation and Environmental Controls Adequate ventilation should be provided to keep exposure levels below current acceptable exposure limits. Hygiene measures Wash hands after handling the product. Personal protective equipment Respiratory protection Use NIOSH approved respirator if TLV limit is exceeded. Hand Protection Gloves are not required in normal use. Eye protection ANSI approved safety goggles are recommended to prevent accidental eye contact. Skin and body protection None necessary under normal conditions 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY Stability Stable. Page 3 / 6 Odor Water solubility 0% Mild Solvent Partition Coefficient (n-octanol/water) No data available Odor Threshold No information available Boiling point/range °C 82 Form Boiling point/range °F 180 pH Melting point/range °C Not Applicable No data available Melting point/range °F Not Applicable Liquid Flash point °C > 85 Specific Gravity Flash point °F > 185 0.78 Product code 83603 Vapor pressure 8 + mmHg @ 25°C Color Vapor density > 1 (Air=1) Black Evaporation Rate <1 (Butyl Acetate = 1) Product name Kwikee Penetrant with A/T plus Moly VOC Content 19.3 % Page 436 of 871 Page 436 of 871 Page 436 of 871 Page 436 of 871 ---PAGE BREAK--- Conditions to avoid Heat, flames and sparks. Incompatability Some plastics. Hazardous Decomposition Products None known. Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat) LD50 (dermal,rat/rabbit) LC50 (inhalation,rat) Mineral Seal Oil 64741-44-2 5000 mg/kg 2000 mg/kg 1.72 mg/L Mineral Spirits 64742-47-8 5000 mg/kg 2000 mg/kg 5.2 mg/L Isopropyl alcohol 67-63-0 4396 mg/kg 12800 mg/kg 12870 mg/kg 72.6 mg/L 2-Butoxyethanol 111-76-2 470 mg/kg 220 mg/kg 2270 mg/kg 2.21 mg/L 450 ppm Toluene 108-88-3 636 mg/kg 12124 mg/kg 8390 mg/kg 12.5 mg/L 26700 ppm Synergistic Products None known Potential health effects Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinogens IARC NTP - Known Carcinogens NTP - Suspected Human Carcinogens OSHA RTK Carcinogens Mineral Seal Oil Not Listed Not Listed Not Listed Not Listed Not Listed Mineral Spirits Not Listed Not Listed Not Listed Not Listed Not Listed Isopropyl alcohol Listed Not Listed Not Listed Not Listed Not Listed 2-Butoxyethanol Listed Not Listed Not Listed Not Listed Not Listed Toluene Listed Not Listed Not Listed Not Listed Not Listed Page 4 / 6 Teratogenic effects None known Sensitization None known Reproductive toxicity None known Product code 83603 Target Organ Effects See Section 2 Chronic toxicity None known Product name Kwikee Penetrant with A/T plus Moly Mutagenic effects None known Page 437 of 871 Page 437 of 871 Page 437 of 871 Page 437 of 871 ---PAGE BREAK--- 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose of all product, residues and clean-up materials in accordance with local, state, and federal regulations. Do not puncture or incinerate. Do not reuse container. Wrap container and place in trash collection. 14. TRANSPORT INFORMATION DOT Not Regulated TDG Not Regulated 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Isopropyl alcohol Listed Page 5 / 6 Water Flea Data Daphnia magna hEC50 48 (13299 mg/L) Water Flea Data Den-dronereides heteropoda hLC50 96 (4720 mg/L) 2-Butoxyethanol Product name Kwikee Penetrant with A/T plus Moly Water Flea Data water flea hEC50 24 (1720 mg/L) Daphnia magna hLC50 24 (1698 - 1940 mg/L) Isopropyl alcohol Toluene Mineral Spirits Microtox Data Photobacterium phosphoreum EC50=19.7 mg/L (30 min) Water Flea Data water flea hEC50 48 (11.3 mg/L) water flea hEC50 48 (310 mg/L) Daphnia magna hEC50 48 (11.3 mg/L) water flea hEC50 48 (11.3 mg/L) Microtox Data Photobacterium phosphoreum EC50=35390 mg/L (5 min) Product code 83603 Page 438 of 871 Page 438 of 871 Page 438 of 871 Page 438 of 871 ---PAGE BREAK--- 15. REGULATORY INFORMATION Toluene Listed Chemical Name New Jersey - RTK - RTK California Prop. 65 Mineral Seal Oil Not Listed Not Listed Not Listed Mineral Spirits Not Listed Not Listed Not Listed Isopropyl alcohol Listed Listed Not Listed 2-Butoxyethanol Listed Listed Not Listed Toluene Listed Listed Developmental WARNING: This product contains a chemical(s) known to the state of California to cause birth defects or other reproductive harm Chemical Name EINECS DSL NDSL TSCA Mineral Seal Oil X X - X Mineral Spirits X X - X Isopropyl alcohol X X - X 2-Butoxyethanol X X - X Toluene X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION Prepared By J. Cameron, Regulatory Affairs Coordinator The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 6 / 6 NFPA Product name Kwikee Penetrant with A/T plus Moly HMIS Product code 83603 - Flammability - Health 1 Health Flammability 2 Reactivity - Physical Hazard 1 Page 439 of 871 Page 439 of 871 Page 439 of 871 Page 439 of 871 ---PAGE BREAK--- LAWSON KWIKUT Cutting Oil Not available. Aerosol. (888) 426-4851 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer : Lawson Products, Inc. 8770 W. Bryn Mawr, Suite 900 Chicago, IL 60631-3515 7733045050 Relevant identified uses of the substance or mixture and uses advised against Not applicable. 82288 82288 Product code : Section 2. Hazards identification FLAMMABLE AEROSOLS - Category 1 GASES UNDER PRESSURE - Compressed gas SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A TOXIC TO REPRODUCTION (Unborn child) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation and Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1 Classification of the substance or mixture : Signal word : Danger Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 51.8% OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Causes skin irritation. Suspected of damaging the unborn child. May be fatal if swallowed and enters airways. May cause respiratory irritation. May cause drowsiness and dizziness. : Hazard statements Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version : 1 1/14 Page 440 of 871 Page 440 of 871 Page 440 of 871 Page 440 of 871 ---PAGE BREAK--- Section 2. Hazards identification Precautionary statements Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Pressurized container: Do not pierce or burn, even after use. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist. Wash hands thoroughly after handling. Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 Store in a well-ventilated place. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Hazards not otherwise classified :None known. May cause damage to organs through prolonged or repeated exposure. Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do not discard empty can in trash compactor. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY. Section 3. Composition/information on ingredients Heptane, Branched, Cyclic, Linear 40.0 426260-76-6 Heptane 18.0 142-82-5 Heavy Naphthenic Petroleum Oil 13.8 64742-52-5 Heavy Paraffinic Oil 13.5 64742-65-0 Propane 10.0 74-98-6 Toluene 2.0 108-88-3 Ingredient name CAS number % by weight There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification : Not available. Substance/mixture CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version : 1 2/14 Page 441 of 871 Page 441 of 871 Page 441 of 871 Page 441 of 871 ---PAGE BREAK--- Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important acute and delayed Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach. : Ingestion Skin contact : Causes skin irritation. Causes serious eye irritation. : Eye contact Over-exposure Skin contact Inhalation Adverse may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : Eye contact : Adverse may include the following: pain or irritation watering redness Potential acute health effects Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version : 1 3/14 Page 442 of 871 Page 442 of 871 Page 442 of 871 Page 442 of 871 ---PAGE BREAK--- Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Ingestion Adverse may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations : See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For non-emergency personnel Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version : 1 4/14 Page 443 of 871 Page 443 of 871 Page 443 of 871 Page 443 of 871 ---PAGE BREAK--- Section 6. Accidental release measures Environmental precautions Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid breathing gas. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. : Precautions for safe handling Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version : 1 5/14 Page 444 of 871 Page 444 of 871 Page 444 of 871 Page 444 of 871 ---PAGE BREAK--- Section 8. Exposure controls/personal protection Heptane, Branched, Cyclic, Linear ACGIH TLV (United States, 4/2014). TWA: 400 ppm 8 hours. TWA: 1640 mg/m³ 8 hours. STEL: 500 ppm 15 minutes. STEL: 2050 mg/m³ 15 minutes. Heptane ACGIH TLV (United States, 4/2014). TWA: 400 ppm 8 hours. TWA: 1640 mg/m³ 8 hours. STEL: 500 ppm 15 minutes. STEL: 2050 mg/m³ 15 minutes. NIOSH REL (United States, 10/2013). TWA: 85 ppm 10 hours. TWA: 350 mg/m³ 10 hours. CEIL: 440 ppm 15 minutes. CEIL: 1800 mg/m³ 15 minutes. OSHA PEL (United States, 2/2013). TWA: 500 ppm 8 hours. TWA: 2000 mg/m³ 8 hours. Heavy Naphthenic Petroleum Oil ACGIH TLV (United States, 4/2014). TWA: 5 mg/m³ 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2013). TWA: 5 mg/m³ 10 hours. Form: Mist STEL: 10 mg/m³ 15 minutes. Form: Mist OSHA PEL (United States, 2/2013). TWA: 5 mg/m³ 8 hours. Heavy Paraffinic Oil ACGIH TLV (United States, 4/2014). TWA: 5 mg/m³ 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2013). TWA: 5 mg/m³ 10 hours. Form: Mist STEL: 10 mg/m³ 15 minutes. Form: Mist OSHA PEL (United States, 2/2013). TWA: 5 mg/m³ 8 hours. Propane NIOSH REL (United States, 10/2013). TWA: 1000 ppm 10 hours. TWA: 1800 mg/m³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 1800 mg/m³ 8 hours. Toluene OSHA PEL Z2 (United States, 2/2013). TWA: 200 ppm 8 hours. CEIL: 300 ppm AMP: 500 ppm 10 minutes. NIOSH REL (United States, 10/2013). TWA: 100 ppm 10 hours. TWA: 375 mg/m³ 10 hours. STEL: 150 ppm 15 minutes. STEL: 560 mg/m³ 15 minutes. ACGIH TLV (United States, 4/2014). TWA: 20 ppm 8 hours. Ingredient name Exposure limits Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version : 1 6/14 Page 445 of 871 Page 445 of 871 Page 445 of 871 Page 445 of 871 ---PAGE BREAK--- Section 8. Exposure controls/personal protection Hand protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Liquid. Not available. 0.71 1.55 [Air = 1] 13.5 kPa (101.325 mm Hg) [at 20°C] Not available. Odor pH Not available. Color Evaporation rate 2 (butyl acetate = 1) Flash point Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup] Not available. Not available. Odor threshold : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Lower: 1% Upper: 9.5% Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version : 1 7/14 Page 446 of 871 Page 446 of 871 Page 446 of 871 Page 446 of 871 ---PAGE BREAK--- Section 9. Physical and chemical properties Solubility Not available. Auto-ignition temperature Not available. Not available. Viscosity Kinematic (room temperature): <0.07 cm2/s cSt) Kinematic (40°C (104°F)): <0.07 cm2/s cSt) Partition coefficient: n- octanol/water : : : : Decomposition temperature : Not available. Type of aerosol : Spray Heat of combustion : 0.0000376 kJ/g Aerosol product Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Heptane LC50 Inhalation Gas. Rat 48000 ppm 4 hours LC50 Inhalation Vapor Rat 103 g/m³ 4 hours Heavy Naphthenic Petroleum Oil LD50 Oral Rat >5000 mg/kg - Heavy Paraffinic Oil LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat >5000 mg/kg - Toluene LC50 Inhalation Vapor Rat 49 g/m³ 4 hours LD50 Oral Rat 636 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Heavy Naphthenic Petroleum Oil Skin - Severe irritant Rabbit - 500 milligrams - Toluene Eyes - Mild irritant Rabbit - 0.5 minutes 100 milligrams - Eyes - Mild irritant Rabbit - 870 Micrograms - Eyes - Severe irritant Rabbit - 24 hours 2 milligrams - Skin - Mild irritant Pig - 24 hours 250 microliters - Product/ingredient name Result Score Exposure Observation Species Information on toxicological effects Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version : 1 8/14 Page 447 of 871 Page 447 of 871 Page 447 of 871 Page 447 of 871 ---PAGE BREAK--- Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Skin - Mild irritant Rabbit - 435 milligrams - Skin - Moderate irritant Rabbit - 24 hours 20 milligrams - Skin - Moderate irritant Rabbit - 500 milligrams - Sensitization Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Heptane, Branched, Cyclic, Linear Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Heptane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Heavy Naphthenic Petroleum Oil Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Heavy Paraffinic Oil Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Propane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Toluene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Name Category Name Category Heptane, Branched, Cyclic, Linear Category 2 Not determined Not determined Heptane Category 2 Not determined Not determined Heavy Naphthenic Petroleum Oil Category 2 Not determined Not determined Heavy Paraffinic Oil Category 2 Not determined Not determined Propane Category 2 Not determined Not determined Toluene Category 2 Not determined Not determined Aspiration hazard Route of exposure Target organs Route of exposure Target organs Classification Toluene - 3 - Product/ingredient name NTP IARC OSHA Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version : 1 9/14 Page 448 of 871 Page 448 of 871 Page 448 of 871 Page 448 of 871 ---PAGE BREAK--- Section 11. Toxicological information Name Result Heptane ASPIRATION HAZARD - Category 1 Propane ASPIRATION HAZARD - Category 1 Toluene ASPIRATION HAZARD - Category 1 Information on the likely routes of exposure Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach. : Ingestion Skin contact : Causes skin irritation. Causes serious eye irritation. : Eye contact related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : Adverse may include the following: pain or irritation watering redness Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure : Not available. Potential acute health effects Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version : 1 10/14 Page 449 of 871 Page 449 of 871 Page 449 of 871 Page 449 of 871 ---PAGE BREAK--- Not available. May cause damage to organs through prolonged or repeated exposure. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : Suspected of damaging the unborn child. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Numerical measures of toxicity Oral 15476 mg/kg Route ATE value Acute toxicity estimates Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Heptane - 552 high Toluene - 90 low Product/ingredient name Aquatic half-life Photolysis Biodegradability Toluene - - Readily Toxicity Heptane Acute LC50 375000 µg/l Fresh water Fish - Oreochromis mossambicus 96 hours Toluene Acute EC50 12500 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 11600 µg/l Fresh water Crustaceans - Gammarus pseudolimnaeus - Adult 48 hours Acute EC50 6000 µg/l Fresh water Daphnia - Daphnia magna - Juvenile (Fledgling, Hatchling, Weanling) 48 hours Acute LC50 5500 µg/l Fresh water Fish - kisutch - Fry 96 hours Chronic NOEC 1000 µg/l Fresh water Daphnia - Daphnia magna 21 days Product/ingredient name Species Result Exposure Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version : 1 11/14 Page 450 of 871 Page 450 of 871 Page 450 of 871 Page 450 of 871 ---PAGE BREAK--- Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. : Disposal methods Section 14. Transport information AEROSOLS 2.1 - AEROSOLS 2.1 - UN1950 UN1950 Special provisions LIMITED QUANTITY Emergency schedules (EmS) LIMITED QUANTITY, F-D, S-U DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No. No. : Not available. : TDG Classification UN1950 AEROSOLS 2.1 - No. Special provisions LIMITED QUANTITY Mexico Classification UN1950 AEROSOLS 2.1 - No. Special provisions (ERG#126) Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. IATA UN1950 AEROSOLS, flammable 2.1 - No. Special provisions LIMITED QUANTITY Section 15. Regulatory information U.S. Federal regulations : Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version : 1 12/14 Page 451 of 871 Page 451 of 871 Page 451 of 871 Page 451 of 871 ---PAGE BREAK--- WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 State regulations Section 16. Other information It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Notice to reader Hazardous Material Information System 2 4 0 Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). The customer is responsible for determining the PPE code for this material. Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version : 1 13/14 Page 452 of 871 Page 452 of 871 Page 452 of 871 Page 452 of 871 ---PAGE BREAK--- Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version : 1 14/14 Page 453 of 871 Page 453 of 871 Page 453 of 871 Page 453 of 871 ---PAGE BREAK--- LAWSON UNI-SOLV Paint Preparation Solvent Not available. Aerosol. (888) 426-4851 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer : Lawson Products, Inc. 8770 W. Bryan Mawr, Suite 900 Chicago, IL 60631-3515 Relevant identified uses of the substance or mixture and uses advised against Not applicable. 56160 56160 Product code : Section 2. Hazards identification FLAMMABLE AEROSOLS - Category 1 GASES UNDER PRESSURE - Compressed gas ACUTE TOXICITY (inhalation) - Category 4 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A CARCINOGENICITY - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation and Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1 Classification of the substance or mixture : Signal word : Danger Hazard pictograms : Precautionary statements GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 68.8% General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Harmful if inhaled. Causes serious eye irritation. Causes skin irritation. Suspected of causing cancer. May be fatal if swallowed and enters airways. May cause respiratory irritation. May cause drowsiness and dizziness. May cause damage to organs through prolonged or repeated exposure. : Hazard statements Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.08 1/13 Page 454 of 871 Page 454 of 871 Page 454 of 871 Page 454 of 871 ---PAGE BREAK--- Section 2. Hazards identification Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Pressurized container: Do not pierce or burn, even after use. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist. Wash hands thoroughly after handling. Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 Store in a well-ventilated place. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified :None known. Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do not discard empty can in trash compactor. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY. Section 3. Composition/information on ingredients Lt. Aliphatic Hydrocarbon Solvent 56.0 64742-89-8 Xylene 16.1 1330-20-7 Propane 12.8 74-98-6 Butane 12.3 106-97-8 2.9 100-41-4 Ingredient name CAS number % by weight There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification : Not available. Substance/mixture CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.08 2/13 Page 455 of 871 Page 455 of 871 Page 455 of 871 Page 455 of 871 ---PAGE BREAK--- Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important acute and delayed Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach. : Ingestion Skin contact : Causes skin irritation. Causes serious eye irritation. : Eye contact Over-exposure Skin contact Ingestion Inhalation Adverse may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness Adverse may include the following: nausea or vomiting Adverse may include the following: irritation redness : : : Eye contact : Adverse may include the following: pain or irritation watering redness Potential acute health effects Indication of immediate medical attention and special treatment needed, if necessary Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.08 3/13 Page 456 of 871 Page 456 of 871 Page 456 of 871 Page 456 of 871 ---PAGE BREAK--- Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. See toxicological information (Section 11) Section 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.08 4/13 Page 457 of 871 Page 457 of 871 Page 457 of 871 Page 457 of 871 ---PAGE BREAK--- Section 6. Accidental release measures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. : Precautions for safe handling Xylene ACGIH TLV (United States, 6/2013). TWA: 100 ppm 8 hours. TWA: 434 mg/m³ 8 hours. STEL: 150 ppm 15 minutes. STEL: 651 mg/m³ 15 minutes. OSHA PEL (United States, 2/2013). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours. Propane NIOSH REL (United States, 10/2013). TWA: 1000 ppm 10 hours. TWA: 1800 mg/m³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 1800 mg/m³ 8 hours. Butane NIOSH REL (United States, 10/2013). Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.08 5/13 Page 458 of 871 Page 458 of 871 Page 458 of 871 Page 458 of 871 ---PAGE BREAK--- Section 8. Exposure controls/personal protection TWA: 800 ppm 10 hours. TWA: 1900 mg/m³ 10 hours. ACGIH TLV (United States, 6/2013). STEL: 1000 ppm 15 minutes. ACGIH TLV (United States, 6/2013). TWA: 20 ppm 8 hours. NIOSH REL (United States, 10/2013). TWA: 100 ppm 10 hours. TWA: 435 mg/m³ 10 hours. STEL: 125 ppm 15 minutes. STEL: 545 mg/m³ 15 minutes. OSHA PEL (United States, 2/2013). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours. Hand protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.08 6/13 Page 459 of 871 Page 459 of 871 Page 459 of 871 Page 459 of 871 ---PAGE BREAK--- Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. 0.69 1.55 [Air = 1] 13.5 kPa (101.325 mm Hg) [at 20°C] Not available. Not available. Odor pH Not available. Color Evaporation rate 4 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup] Not available. Not available. Viscosity Kinematic (40°C (104°F)): <0.07 cm2/s cSt) Not available. Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Lower: 1% Upper: 9.5% Decomposition temperature : Not available. Type of aerosol : Spray Heat of combustion : 40.51 kJ/g Aerosol product Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.08 7/13 Page 460 of 871 Page 460 of 871 Page 460 of 871 Page 460 of 871 ---PAGE BREAK--- Section 11. Toxicological information Acute toxicity Xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours LD50 Oral Rat 4300 mg/kg - Butane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat 3500 mg/kg - Product/ingredient name Result Species Dose Exposure Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Irritation/Corrosion Xylene Eyes - Mild irritant Rabbit - 87 milligrams - Eyes - Severe irritant Rabbit - 24 hours 5 milligrams - Skin - Mild irritant Rat - 8 hours 60 microliters - Skin - Moderate irritant Rabbit - 24 hours 500 milligrams - Skin - Moderate irritant Rabbit - 100 Percent - Eyes - Severe irritant Rabbit - 500 milligrams - Skin - Mild irritant Rabbit - 24 hours 15 milligrams - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Specific target organ toxicity (single exposure) Lt. Aliphatic Hydrocarbon Solvent Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Xylene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Propane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Butane Category 3 Not applicable. Respiratory tract Name Category Route of exposure Target organs Information on toxicological effects Classification Xylene - 3 - - 2B - Product/ingredient name NTP IARC OSHA Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.08 8/13 Page 461 of 871 Page 461 of 871 Page 461 of 871 Page 461 of 871 ---PAGE BREAK--- Section 11. Toxicological information Specific target organ toxicity (repeated exposure) irritation and Narcotic effects Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Name Category Lt. Aliphatic Hydrocarbon Solvent Category 2 Not determined Not determined Xylene Category 2 Not determined Not determined Propane Category 2 Not determined Not determined Butane Category 2 Not determined Not determined Category 2 Not determined Not determined Aspiration hazard Name Result Lt. Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1 ASPIRATION HAZARD - Category 1 Route of exposure Target organs Information on the likely routes of exposure Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach. : Ingestion Skin contact : Causes skin irritation. Causes serious eye irritation. : Eye contact related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness Adverse may include the following: nausea or vomiting Adverse may include the following: irritation redness : : : Eye contact : Adverse may include the following: pain or irritation watering redness Delayed and immediate effects and also chronic effects from short and long term exposure : Not available. Potential acute health effects Potential immediate effects : Not available. Short term exposure Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.08 9/13 Page 462 of 871 Page 462 of 871 Page 462 of 871 Page 462 of 871 ---PAGE BREAK--- Not available. May cause damage to organs through prolonged or repeated exposure. General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Potential chronic health effects Numerical measures of toxicity Oral 6847.2 mg/kg Inhalation (gases) 9690.9 ppm Route ATE value Acute toxicity estimates Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Product/ingredient name Lt. Aliphatic Hydrocarbon Solvent - 10 to 2500 high Xylene - 8.1 to 25.9 low Toxicity Lt. Aliphatic Hydrocarbon Solvent Acute LC50 100000 ppm Fresh water Fish - mykiss 96 hours Xylene Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes pugio 48 hours Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours Acute EC50 4600 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 3600 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Acute EC50 2930 µg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 5200 µg/l Marine water Crustaceans - Americamysis bahia 48 hours Acute LC50 4200 µg/l Fresh water Fish - mykiss 96 hours Chronic NOEC 1000 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Product/ingredient name Species Result Exposure Persistence and degradability Not available. Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.08 10/13 Page 463 of 871 Page 463 of 871 Page 463 of 871 Page 463 of 871 ---PAGE BREAK--- Section 12. Ecological information Other adverse effects : No known significant effects or critical hazards. Soil/water partition coefficient (KOC) : Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. : Disposal methods Section 14. Transport information AEROSOLS 2.1 - AEROSOLS 2.1 - UN1950 UN1950 Special provisions LIMITED QUANTITY Emergency schedules (EmS) LIMITED QUANTITY, F-D, S-U DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No. No. : Not available. : TDG Classification UN1950 AEROSOLS 2.1 - No. Special provisions LIMITED QUANTITY Mexico Classification UN1950 AEROSOLS 2.1 - No. Special provisions (ERG#126) Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. IATA UN1950 AEROSOLS, flammable 2.1 - No. Special provisions LIMITED QUANTITY Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.08 11/13 Page 464 of 871 Page 464 of 871 Page 464 of 871 Page 464 of 871 ---PAGE BREAK--- Section 15. Regulatory information U.S. Federal regulations : SARA 313 SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 State regulations Section 16. Other information It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Notice to reader Hazardous Material Information System 2 4 0 * Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.08 12/13 Page 465 of 871 Page 465 of 871 Page 465 of 871 Page 465 of 871 ---PAGE BREAK--- Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.08 13/13 Page 466 of 871 Page 466 of 871 Page 466 of 871 Page 466 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 28-May-2013 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 19907 Product name Light Oil Lubricant Recommended Use Lubricant Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Eyes. Ingestion. Inhalation. Skin contact. Skin absorption. Potential health effects Eyes Exposure to vapors or mists may cause the following effects:. Irritation. Pain. Tearing. Reddening. Swelling. Stinging sensation. Feeling like that of fine dust in the eye. Skin Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. Chronic exposure causes drying effect on the skin . Inhalation Harmful by inhalation. Repeated or prolonged exposure may cause the following effects:. Headaches. Dizziness. Nausea. Decreased blood pressure. Changes in heart rate. Cyanosis. Chronic overexposure can cause: . Lung damage. Ingestion Harmful or fatal if swallowed. If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach. Extreme overexposure may cause. Kidney damage. Liver abnormalities. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % VM&P Naphtha 8032-32-4 10-30 Propane/Isobutane/N- Butane 68476-86-8 10-30 Paraffinic Mineral Oil 8042-47-5 3-7 4. FIRST AID MEASURES Eye contact Flush eyes with plenty of water. Seek medical attention if irritation persists. Skin contact Flush skin with water. Remove and wash contaminated clothing before re-use. Seek medical attention immediately. Ingestion Seek medical attention immediately. Do not induce vomiting. Give victim a glass of water or milk. Call a physician or Poison Control Center immediately. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Immediate medical attention is required. 5. FIRE FIGHTING MEASURES Flash point °C -104 Flash point °F -156 Method Pensky-Martens C.C. Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 9.5 Lower 1.1 Suitable extinguishing media Alcohol foam. Carbon dioxide. Dry chemical powder. Foam. Water fog. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Page 1 / 4 Emergency Overview Vapors extremely irritating to eyes and respiratory tract. Vapors may cause flash fire or explosion. Page 467 of 871 Page 467 of 871 Page 467 of 871 Page 467 of 871 ---PAGE BREAK--- Fire and Explosion Hazards Flash back possible over considerable distance. Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Empty containers contain residue and/or vapors. Do not weld, cut, pressurize, braze, solder, drill, grind, or expose such containers to heat, sparks, flame, static electricity, or other sources of ignition. They may explode and cause injury or death. Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Place in suitable container for disposal as hazardous waste. 7. HANDLING AND STORAGE Handling Thoroughly wash hands and exposed skin after handling. Remove and wash contaminated clothing before re-use. Ensure adequate ventilation. Use only according to label directions. Avoid contact with skin, eyes and clothing. Avoid breathing vapors from heated material . Storage Keep away from heat and sources of ignition. Do not freeze. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) VM&P Naphtha - - - - Propane/Isob utane/N- Butane - - - - Paraffinic Mineral Oil - - - - Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Hygiene measures Wash hands before breaks and immediately after handling the product. Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes and clothing. Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Protection provided by air purifying respirators is limited. Use a positive pressure supplied air respirator. if there is any potential for an uncontrolled release:. where exposure levels are not known. or other circumstances where an air purifying respirator (P100) may not provide adequate protection . Hand Protection Chemical resistant gloves. Eye protection Use safety eyewear designed to protect against impact. Skin and body protection None necessary under normal conditions Other Protective Equipment Wear appropriate clothing to prevent skin contact. Rubber boots. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Clear Odor Solvent Odor Threshold No information available pH Not Applicable Specific Gravity 0.8428 Vapor pressure 80-90 Vapor density >Air Evaporation Rate >1 (Butyl Acetate = 1) Water solubility Negligible VOC Content 2.04 lbs/gal; 244 g/l Partition Coefficient (n-octanol/water) No data available Boiling point/range °C -41 - 142 Boiling point/range °F -43 - 287 Melting point/range °C 0 Melting point/range °F 32 Flash point °C -104 Flash point °F -156 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Do not use near other sources of ignition. Do not use near welding arcs. Avoid open flames. Page 2 / 4 Product code 19907 Product name Light Oil Lubricant Page 468 of 871 Page 468 of 871 Page 468 of 871 Page 468 of 871 ---PAGE BREAK--- Incompatability Strong acids. Alkalies. Oxidizers. Amines. Hazardous Decomposition Products Sulphur oxides. Carbon oxides. Nitrogen oxides (NOx). Chlorides. Chlorine. Phosgene . Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) VM&P Naphtha 8032-32-4 - - 3400 ppm Propane/Isobutan e/N-Butane 68476-86-8 - - - Paraffinic Mineral Oil 8042-47-5 5000 mg/kg - - Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity None known Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects May cause damage to liver. May cause damage to kidneys. Central nervous system. Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns VM&P Naphtha Not Listed Not Listed Not Listed Not Listed Not Listed Propane/Isob utane/N- Butane Not Listed Not Listed Not Listed Not Listed Not Listed Paraffinic Mineral Oil Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT UN1950 Aerosols, flammable, 2.1. Exception: (Compressed Gas not more than 1.0L) Consumer Commodity ORM-D TDG UN1950 AEROSOLS, flammable, 2.1 Consumer commodity <1L 15. REGULATORY INFORMATION State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 VM&P Naphtha Not Listed Listed Not Listed Propane/Isobutane/N- Butane Not Listed Not Listed Not Listed Paraffinic Mineral Oil Not Listed Not Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA VM&P Naphtha X X - X Propane/Isobutane/N- Butane X X - X Paraffinic Mineral Oil X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. OTHER INFORMATION HMIS Health - 1 Flammability - 4 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer Page 3 / 4 Product code 19907 Product name Light Oil Lubricant Page 469 of 871 Page 469 of 871 Page 469 of 871 Page 469 of 871 ---PAGE BREAK--- The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product code 19907 Product name Light Oil Lubricant Page 470 of 871 Page 470 of 871 Page 470 of 871 Page 470 of 871 ---PAGE BREAK--- Page 1 of 4 Print Date 08/02/2004 MSDS Document Product Liquid Anti Static Spray 1. Chemical Product and Company Identification Trade Name of this Product Liquid Anti Static Spray MSDS ID 95048 Manufacturer Lawson Products, Inc. 1666 East Touhy Avenue Des Plaines, IL 60018 Contact Name Corporate Compliance Team Phone Number (847) 827-9666 Emergency Phone (888) 426-4851 Revision Date 03/16/1993 Health: Fire: Reactivity: Specific 1 4 0 2. Composition and Information on Ingredients Ingredient CAS Number Weight % ACGIH TLV PEL STEL Isopropyl Alcohol 67-63-0 67-63 % 400 ppm 400 ppm 500 ppm 3. Hazard Identification Route Of Entry Ingestion Eyes Synergistic Products N/A Target Organs Affected Not Available. EFFECTS OF OVEREXPOSURE Possible eye irritant. Inhalation of ethylene glycol gives initial CNS stimulation followed by depression. Moderately toxic by ingestion and inhalation. Page 471 of 871 Page 471 of 871 Page 471 of 871 Page 471 of 871 ---PAGE BREAK--- Page 2 of 4 Print Date 08/02/2004 MSDS ID 95048 Liquid Anti Static Spray 4. First Aid Information EMERGENCY AND FIRST AID PROCEDURES Wash contacted areas with soap and water. For eye contact, flush with plenty of water. Call physician. If swallowed, administer large quantities of water if person is conscious, and get medical atten- tion immediately. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, consult physician. 5. Fire Fighting Measures Extinguishing Media Foam Carbon Dioxide Sand 6. Accidental Release Measures STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Flush with large quantities of water. Ventilate area. 7. Handling and Storage Handling Precautions N/A N/A Read Entire Label Before Using. Hygienic Practices Wash hands before eating or using the washroom. Smoke in SMOKING AREAS ONLY. 8. Exposure Controls and Personal Protection Other Protective Equipment Not required. Eye Protection Use safety eyewear designed to protect against splash of liquids. Other PPE N/A Protective Gloves Required for prolonged or repeated contact. Ventilation If current ventilation practices are not adequate in maintaining airborne concentrations below the established exposure limits, additional ventilation or exhaust systems may be required. Respiratory Protection None Required. Page 472 of 871 Page 472 of 871 Page 472 of 871 Page 472 of 871 ---PAGE BREAK--- Page 3 of 4 Print Date 08/02/2004 MSDS ID 95048 Liquid Anti Static Spray 9. Physical and Chemical Properties Physical State Liquid Specific Gravity 0.99 pH 7.1+1 Boiling/Cond. Point 199.0 VOC % 80.00 ODOR AND APPEARANCE Mild odor, yellow color. 10. Stability and Reactivity Incompatibility N/A Conditions to avoid Avoid contact with any source of ignition. Hazardous Decomposition Products None listed. Hazardous Polymerization Will not occur. 11. Toxicological Information CARCINOGENICITY Not Applicable. 12. Ecological Information Ecological Information No information available. 13. Disposal Considerations WASTE DISPOSAL METHOD Consult local regulations. Flush with water, controlled burning. 14. Transportation Information OSHA CLASS N/A PER DOT N/A DOT Class N/A PER IMCO N/A IMCO Classification Number N/A IATA Classification Number N/A 15. Regulatory Information CPR Certification This product has been classified in accordance with the hazard criteria of the Controlled Page 473 of 871 Page 473 of 871 Page 473 of 871 Page 473 of 871 ---PAGE BREAK--- Page 4 of 4 Print Date 08/02/2004 MSDS ID 95048 Liquid Anti Static Spray Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. Other Information Other Precautions No information available. Page 474 of 871 Page 474 of 871 Page 474 of 871 Page 474 of 871 ---PAGE BREAK--- Page 475 of 871 Page 475 of 871 Page 475 of 871 Page 475 of 871 ---PAGE BREAK--- Page 476 of 871 Page 476 of 871 Page 476 of 871 Page 476 of 871 ---PAGE BREAK--- Page 477 of 871 Page 477 of 871 Page 477 of 871 Page 477 of 871 ---PAGE BREAK--- Page 478 of 871 Page 478 of 871 Page 478 of 871 Page 478 of 871 ---PAGE BREAK--- CONSUMER MATERIAL SAFETY DATA SHEET NAME OF PRODUCT: Loctite Super Glue Gel Professional MSDS DATE: 03/18/2010 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Loctite Super Glue Gel 10g SUPPLIER: Henkel Corporation ADDRESS: 32150 Just Imagine Drive Avon, Ohio 44011 DOMESTIC EMERGENCY PHONE: Chemtrec 1-[PHONE REDACTED] In Canada Canutec [PHONE REDACTED] OTHER CALLS: Regulatory Affairs [PHONE REDACTED] FAX PHONE: Regulatory Affairs [PHONE REDACTED] CHEMICAL FAMILY: Cyanoacrylates PRODUCT USE: Consumer Product; Super Glue PREPARED BY: Regulatory MSDS PREPARATION DATE: 03/18/2010 SECTION 1 NOTES: Household Super Glue SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENT: % CAS NO. OSHA PEL ACGIH TLV Ethyl cyanoacrylate 60-100 7085-85-0 None 0.2ppm TWA SECTION 3: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: BONDS SKIN IN SECONDS MAY CAUSE EYE AND RESPIRATORY IRRITATION COMBUSTIBLE LIQUID AND VAPOR ROUTES OF ENTRY: oral, dermal, inhalation POTENTIAL HEALTH EFFECTS EYES: Irritating to the eyes. Causes excessive tearing. Eyelids may bond. SKIN: Bonds skin in seconds. May cause skin irritation. Cyanoacrylates have been reported to cause allergic reaction but due to rapid polymerization at the skin surface, an allergic reaction is rare. Cyanoacrylates generate heat on solidification. In rare circumstances, a large drop will burn the skin. Cured adhesive does not present a health hazard even if bonded to the skin. INGESTION: Not expected to be harmful by ingestion. Rapidly polymerizes (solidifies) and bonds in mouth. It is almost impossible to swallow. INHALATION: Exposure to vapors above established exposure limit results in respiratory irritation which may lead to difficulty in breathing and tightness in the chest. Page 479 of 871 Page 479 of 871 Page 479 of 871 Page 479 of 871 ---PAGE BREAK--- SECTION 4: FIRST AID MEASURES EYES: Immediately flush with plenty of water for at least 15 minutes. Get medical attention. If eyelids are bonded closed, release eyelashes with warm water by covering with a wet pad. Do not force eye open. Cyanoacrylate will bond to eye protein and will cause a effect, which will help to debond the adhesive. Keep eye covered until debonding is complete, usually within 1-3 days. Medical attention should be sought in case solid particles of polymerized cyanoacrylate trapped behind the eyelid cause abrasive damage. SKIN: Do not pull bonded skin apart. Soak in warm soapy water. Gently peel apart using a blunt instrument. If skin is burned due to the rapid generation of heat by a large drop, seek medical attention. If lips are bonded, apply warm water to the lips and encourage wetting and pressure from saliva in mouth. Peel or roll lips apart. Do not pull lips apart with direct opposing force. INGESTION: Ensure breathing passages are not obstructed. The product will polymerize rapidly and bond to the mouth making it almost impossible to swallow. Saliva will separate any solidified product in several hours. Prevent the patient from swallowing by separating mass. INHALATION: Remove to fresh air. If discomfort persists seek medical attention. SECTION 5: FIRE-FIGHTING MEASURES NFPA HAZARD CLASSIFICATION HEALTH: FLAMMABILITY: REACTIVITY: <2,2,1> EXTINGUISHING MEDIA: Foam, CO2, Dry chemical (B-C) FLAMMABLE LIMITS IN AIR: Not determined FLASHPOINT: 65C-93.4C (150F-200F) UNUSUAL FIRE AND EXPLOSION HAZARDS: None SPECIAL FIREFIGHTING PROCEDURES: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA). HAZARDOUS DECOMPOSITION PRODUCTS: Trace amount of toxic or irritating fumes may be released and the use of breathing apparatus is recommended. SECTION 6: ACCIDENTAL RELEASE MEASURES ACCIDENTAL RELEASE MEASURES: Ventilate area. Prevent product from entering the drains. Do not use cloth for mopping up. Flood with water to complete polymerization and scrape off the floor. Cured materials can be disposed of as non-hazardous wastes. SECTION 7: HANDLING AND STORAGE HANDLING AND STORAGE: Avoid contact with eyes, skin and clothing. Avoid breathing vapor and mist. Wash thoroughly after handling. Avoid contact with fabric or paper goods. Contact with these materials may cause rapid polymerization which can generate smoke and strong irritating vapors and cause thermal burns. See label on product for use directions. Page 480 of 871 Page 480 of 871 Page 480 of 871 Page 480 of 871 ---PAGE BREAK--- SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Use positive downdraft exhaust ventilation if general ventilation is insufficient to maintain vapor concentration below established exposure limits. RESPIRATORY PROTECTION: Use NIOSH approved respirator if there is potential to exceed exposure limits.. EYE PROTECTION: Chemical splash goggles or safety glasses with side shields. SKIN PROTECTION: Use nitrile gloves and aprons as necessary to prevent contact. Do not use PVC, nylon or cotton. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Colorless gel. ODOR: Sharp, irritating. PHYSICAL STATE: Gel pH AS SUPPLIED: Not applicable. SPECIFIC GRAVITY (H2O = 1.1 SOLUBILITY IN WATER: Polymerizes in presence of water. EVAPORATION RATE: Not available BOILING POINT: > 149C (300F) VAPOR PRESSURE: <0.2mm Hg % VOC 20g/L (California SCAQMD Method 316B (estimated)) SECTION 10: STABILITY AND REACTIVITY STABILITY: Stable under recommended storage conditions. CONDITIONS TO AVOID: Spontaneous polymerization. HAZARDOUS POLYMERIZATION: Rapid exothermic polymerization will occur in the presence of water, amines, alkalis and alcohols. INCOMPATIBILITY: Water, amines, alkalis and alcohols. SECTION 11: TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION: Acute oral LD50 >5000mg/kg, rat (estimated). LD50 >2000mg/kg, rabbit (estimated). See also Section 3 Hazard Identifications. SECTION 11 NOTES: Contact Regulatory Affairs if further information is required. SECTION 12: ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: No data available. Page 481 of 871 Page 481 of 871 Page 481 of 871 Page 481 of 871 ---PAGE BREAK--- SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: Dispose in accordance with federal, state or local regulations. SECTION 14: TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION PROPER SHIPPING NAME: Combustible liquids N.O.S (Cyanoacrylate ester) HAZARD CLASS: 3 UN NUMBER: NA 1993 PACKING GROUP: III EXCEPTIONS: (Not more than 450L) Unrestricted MARINE POLLUTANT: None NOTE: This product classifies as a Consumer Commodity due to its size and intended use. ORM-D INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA) PROPER SHIPPING NAME: Aviation regulated liquids N.O.S (Cyanoacrylate ester) HAZARD CLASS: 9 UN NUMBER: UN3334 PACKING GROUP: III EXCEPTIONS: (Not more than 500ml). Unrestricted. WATER TRANSPORATION (IMO/IMDG) PROPER SHIPPING NAME: Unrestricted. SECTION 15: REGULATORY INFORMATION U.S. FEDERAL REGULATIONS This product has been labeled according to the Federal Hazardous Substances Act and the associated Consumer Product Safety Regulations. SECTION 16: OTHER INFORMATION OTHER INFORMATION: Information provided in this MSDS is intended to provide supplementary information for consumer uses of this product. This product is not intended for industrial uses. Contact Regulatory Affairs for additional information DISCLAIMER: The information appearing herein is furnished without express or implied warranty and is based upon tests and data believed to be accurate to the best knowledge of Henkel Consumer Page 482 of 871 Page 482 of 871 Page 482 of 871 Page 482 of 871 ---PAGE BREAK--- Adhesives Inc. It is the user’s responsibility to ensure that the product is handled safely and that the instructions for use are properly communicated and followed. Henkel Corporation assumes no legal responsibility or liability for any use not in accordance with the use described in this MSDS or in the product labeling. Page 483 of 871 Page 483 of 871 Page 483 of 871 Page 483 of 871 ---PAGE BREAK--- LOXON® Concrete & Masonry Primer, Interior/Exterior Latex White Not available. Liquid. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer : THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Not applicable. A24W8300 A24W8300 Product code : Product Information Telephone Number : Not available. Regulatory Information Telephone Number : (216) 566-2902 Transportation Emergency Telephone Number : (800) 424-9300 Section 2. Hazards identification CARCINOGENICITY - Category 1A Classification of the substance or mixture : Signal word : Danger Hazard pictograms : Precautionary statements Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Response : IF exposed or concerned: Get medical attention. Storage : Store locked up. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 31.1% General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). May cause cancer. : Hazard statements Date of issue/Date of revision : 6/18/2015. Date of previous issue : 5/22/2015. Version : 1.03 1/11 Page 484 of 871 Page 484 of 871 Page 484 of 871 Page 484 of 871 ---PAGE BREAK--- Section 2. Hazards identification Hazards not otherwise classified :None known. Please refer to the SDS for additional information. Do not transfer contents to other containers for storage. Supplemental label elements WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. Adequate ventilation required when sanding or abrading the dried film. If Adequate ventilation cannot be provided wear an approved particulate respirator (NIOSH approved). Follow respirator manufacturer's directions for respirator use. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film may release Silica which has been shown to cause lung damage and cancer under long term exposure. Section 3. Composition/information on ingredients Titanium Dioxide 11.4 13463-67-7 Quartz 7.8 14808-60-7 zinc oxide 1.4 1314-13-2 Ingredient name CAS number % by weight There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification : Not available. Substance/mixture CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important acute and delayed Potential acute health effects Date of issue/Date of revision : 6/18/2015. Date of previous issue : 5/22/2015. Version : 1.03 2/11 Page 485 of 871 Page 485 of 871 Page 485 of 871 Page 485 of 871 ---PAGE BREAK--- Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. : Eye contact Over-exposure Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : No specific data. See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: metal oxide/oxides In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision : 6/18/2015. Date of previous issue : 5/22/2015. Version : 1.03 3/11 Page 486 of 871 Page 486 of 871 Page 486 of 871 Page 486 of 871 ---PAGE BREAK--- Section 6. Accidental release measures Environmental precautions Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Titanium Dioxide ACGIH TLV (United States, 4/2014). TWA: 10 mg/m³ 8 hours. OSHA PEL (United States, 2/2013). TWA: 15 mg/m³ 8 hours. Form: Total dust Quartz OSHA PEL Z3 (United States, 2/2013). TWA: 250 / (%SiO2+5) 8 hours. Form: Respirable TWA: 10 MG/M3 / (%SiO2+2) 8 hours. Form: Respirable ACGIH TLV (United States, 4/2014). Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits Date of issue/Date of revision : 6/18/2015. Date of previous issue : 5/22/2015. Version : 1.03 4/11 Page 487 of 871 Page 487 of 871 Page 487 of 871 Page 487 of 871 ---PAGE BREAK--- Section 8. Exposure controls/personal protection TWA: 0.025 mg/m³ 8 hours. Form: Respirable fraction NIOSH REL (United States, 10/2013). TWA: 0.05 mg/m³ 10 hours. Form: respirable dust zinc oxide NIOSH REL (United States, 10/2013). CEIL: 15 mg/m³ Form: Dust TWA: 5 mg/m³ 10 hours. Form: Dust and fumes STEL: 10 mg/m³ 15 minutes. Form: Fume OSHA PEL (United States, 2/2013). TWA: 5 mg/m³ 8 hours. Form: Fume TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 15 mg/m³ 8 hours. Form: Total dust ACGIH TLV (United States, 4/2014). TWA: 2 mg/m³ 8 hours. Form: Respirable fraction STEL: 10 mg/m³ 15 minutes. Form: Respirable fraction Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Date of issue/Date of revision : 6/18/2015. Date of previous issue : 5/22/2015. Version : 1.03 5/11 Page 488 of 871 Page 488 of 871 Page 488 of 871 Page 488 of 871 ---PAGE BREAK--- Section 8. Exposure controls/personal protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Respiratory protection : Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. 1.31 1 [Air = 1] 0.31 kPa (2.333 mm Hg) [at 20°C] Not available. Not available. Odor pH Not available. Color Evaporation rate 0.09 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: >93.3°C (>199.9°F) Not available. 9.5 Viscosity Kinematic (room temperature): >0.205 cm2/s (>20.5 cSt) Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt) Not available. Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : 100°C (212°F) Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Decomposition temperature : Not available. Heat of combustion : 0.000001393 kJ/g Aerosol product Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Date of issue/Date of revision : 6/18/2015. Date of previous issue : 5/22/2015. Version : 1.03 6/11 Page 489 of 871 Page 489 of 871 Page 489 of 871 Page 489 of 871 ---PAGE BREAK--- Section 11. Toxicological information Acute toxicity Not available. Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Irritation/Corrosion Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent - zinc oxide Eyes - Mild irritant Rabbit - 24 hours 500 milligrams - Skin - Mild irritant Rabbit - 24 hours 500 milligrams - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Not available. Not available. Aspiration hazard Not available. Information on toxicological effects Classification Titanium Dioxide - 2B - Quartz - 1 Known to be a human carcinogen. Product/ingredient name NTP IARC OSHA Information on the likely routes of exposure Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. : Eye contact related to the physical, chemical and toxicological characteristics Inhalation No specific data. : Eye contact : No specific data. : Not available. Potential acute health effects Date of issue/Date of revision : 6/18/2015. Date of previous issue : 5/22/2015. Version : 1.03 7/11 Page 490 of 871 Page 490 of 871 Page 490 of 871 Page 490 of 871 ---PAGE BREAK--- Not available. No known significant effects or critical hazards. General : May cause cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Skin contact Ingestion No specific data. No specific data. : : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Not available. Acute toxicity estimates Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Product/ingredient name Titanium Dioxide - 352 low zinc oxide - 60960 high Toxicity Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours zinc oxide Acute IC50 1.85 mg/l Marine water Algae - Skeletonema costatum 96 hours Acute IC50 46 µg/l Fresh water Algae - Pseudokirchneriella subcapitata - Exponential growth phase 72 hours Acute LC50 98 µg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 1.1 ppm Fresh water Fish - mykiss 96 hours Product/ingredient name Species Result Exposure Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Not available. Date of issue/Date of revision : 6/18/2015. Date of previous issue : 5/22/2015. Version : 1.03 8/11 Page 491 of 871 Page 491 of 871 Page 491 of 871 Page 491 of 871 ---PAGE BREAK--- Section 12. Ecological information Other adverse effects : No known significant effects or critical hazards. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. : Disposal methods Section 14. Transport information - - - - - - Not regulated. Not regulated. Special provisions Not Applicable Emergency schedules (EmS) Not Applicable DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No. No. : Not available. : TDG Classification Not regulated. - - - No. Special provisions Not Applicable Mexico Classification Not regulated. - - - No. Special provisions Not Applicable Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. IATA Not regulated. - - - No. Special provisions Not Applicable Date of issue/Date of revision : 6/18/2015. Date of previous issue : 5/22/2015. Version : 1.03 9/11 Page 492 of 871 Page 492 of 871 Page 492 of 871 Page 492 of 871 ---PAGE BREAK--- Section 15. Regulatory information U.S. Federal regulations : WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 State regulations Section 16. Other information It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Notice to reader Hazardous Material Information System 1 0 0 * Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Date of issue/Date of revision : 6/18/2015. Date of previous issue : 5/22/2015. Version : 1.03 10/11 Page 493 of 871 Page 493 of 871 Page 493 of 871 Page 493 of 871 ---PAGE BREAK--- Date of issue/Date of revision : 6/18/2015. Date of previous issue : 5/22/2015. Version : 1.03 11/11 Page 494 of 871 Page 494 of 871 Page 494 of 871 Page 494 of 871 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Product identifier LPS® ThermaPlex® Hi-Load Bearing Grease Other means of identification Part Number 70414, 70406, 70435, 70455 Recommended use A lubricating grease intended for bearings in industrial applications involving extreme loads. Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Manufacturer Company name ITW Pro Brands Address 4647 Hugh Howell Rd. Tucker, GA 30084 Country Tel: +1 [PHONE REDACTED] In Case of Emergency 1-[PHONE REDACTED] (inside U.S.) +001 [PHONE REDACTED] (outside U.S.) Website www.lpslabs.com E-mail 2. Hazard(s) identification Not classified. Physical hazards Not classified. Health hazards Not classified. Environmental hazards Not classified. OSHA defined hazards Label elements None. Hazard symbol Signal word None. Hazard statement The mixture does not meet the criteria for classification. Precautionary statement Prevention Observe good industrial hygiene practices. Response Wash hands after handling. Storage Store away from incompatible materials. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures The manufacturer lists no ingredients as hazardous according to OSHA 29 CFR 1910.1200. 4. First-aid measures Inhalation Move to fresh air. Call a physician if develop or persist. Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists. Eye contact Rinse with water. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Get medical attention if occur. Most important acute and delayed Direct contact with eyes may cause temporary irritation. 1 / 6 Material name: LPS® ThermaPlex® Hi-Load Bearing Grease 70414, 70406, 70435, 70455 Version 01 Issue date: 02-25-2015 SDS US Page 495 of 871 Page 495 of 871 Page 495 of 871 Page 495 of 871 ---PAGE BREAK--- Indication of immediate medical attention and special treatment needed Treat General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire fighting equipment/instructions Use water spray to cool unopened containers. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Use personal protection recommended in Section 8 of the SDS. Methods and materials for containment and cleaning up Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Store in original closed container. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits No exposure limits noted for ingredient(s). Biological limit values No biological exposure limits noted for the ingredient(s). Exposure guidelines Occupational Exposure Limits are not relevant to the current physical form of the product. Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Not normally needed. Skin protection Hand protection Wear appropriate chemical resistant gloves. Other Wear suitable protective clothing. Respiratory protection No personal respiratory protective equipment normally required. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Solid. Form Paste. Color Grey. Black. Odor Hydrocarbon-like. 2 / 6 Material name: LPS® ThermaPlex® Hi-Load Bearing Grease 70414, 70406, 70435, 70455 Version 01 Issue date: 02-25-2015 SDS US Page 496 of 871 Page 496 of 871 Page 496 of 871 Page 496 of 871 ---PAGE BREAK--- Odor threshold Not available. pH Not applicable. Melting point/freezing point Not available. Initial boiling point and boiling range Not available. Flash point 400.0 °F (204.4 Cleveland Open Cup Evaporation rate Not available. Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower Not available. Flammability limit - upper Not available. Explosive limit - lower Not applicable. Explosive limit - upper Not applicable. Vapor pressure < 0.13 kPa Vapor density < 1 (air = 1) Relative density 0.87, 7.506 (lbs/gal) @ 15°C Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information VOC (Weight 1 % w/w ASTM D-972 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid Heat, flames and sparks. Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Hazardous decomposition products Carbon oxides. 11. Toxicological information Information on likely routes of exposure Inhalation No adverse effects due to inhalation are expected. Skin contact Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion May cause discomfort if swallowed. However, ingestion is not likely to be a primary route of occupational exposure. related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Exposure may cause temporary irritation, redness, or discomfort. Information on toxicological effects Acute toxicity Expected to be a low hazard for usual industrial or commercial handling by trained personnel. Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. 3 / 6 Material name: LPS® ThermaPlex® Hi-Load Bearing Grease 70414, 70406, 70435, 70455 Version 01 Issue date: 02-25-2015 SDS US Page 497 of 871 Page 497 of 871 Page 497 of 871 Page 497 of 871 ---PAGE BREAK--- Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not likely, due to the form of the product. Chronic effects None known. Further information This product has no known adverse effect on human health. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) > 1 Mobility in soil No data available. Other adverse effects None known. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Not applicable. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. 4 / 6 Material name: LPS® ThermaPlex® Hi-Load Bearing Grease 70414, 70406, 70435, 70455 Version 01 Issue date: 02-25-2015 SDS US Page 498 of 871 Page 498 of 871 Page 498 of 871 Page 498 of 871 ---PAGE BREAK--- CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. Massachusetts RTK - Substance List Not regulated. US. New Jersey Worker and Community Right-to-Know Act Not listed. US. Worker and Community Right-to-Know Law Not listed. US. Rhode Island RTK Not regulated. US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Yes Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) Yes China Inventory of Existing Chemical Substances in China (IECSC) No Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) 5 / 6 Material name: LPS® ThermaPlex® Hi-Load Bearing Grease 70414, 70406, 70435, 70455 Version 01 Issue date: 02-25-2015 SDS US Page 499 of 871 Page 499 of 871 Page 499 of 871 Page 499 of 871 ---PAGE BREAK--- Country(s) or region Inventory name On inventory (yes/no)* Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 02-25-2015 Version # 01 Disclaimer Not available. 6 / 6 Material name: LPS® ThermaPlex® Hi-Load Bearing Grease 70414, 70406, 70435, 70455 Version 01 Issue date: 02-25-2015 SDS US Page 500 of 871 Page 500 of 871 Page 500 of 871 Page 500 of 871 ---PAGE BREAK--- Safety Data Sheet Lubri-Temp PAGE 1 of 4 SECTION I - IDENTIFICATION PRODUCT NAME: Lubri-Temp PRODUCT CODE: 19923 PRODUCT USE: Lubricant COMPANY NAME: Lawson Products, Inc. COMPANY ADDRESS: 8770 W. Bryn Mawr Suite 900, Chicago, Il 60631 COMPANY PHONE: [PHONE REDACTED] EMERGENCY PHONE: [PHONE REDACTED] SECTION II – HAZARDS IDENTIFICATION CLASSIFICATION: Does not present a hazard according to OSHA (29CFR 1910.1200) HAZARD STATEMENT(S): N/A This product contains the following percentage of chemicals of unknown toxicity: 0% PRECAUTIONARY STATEMENTS: N/A SYMBOL: N/A HAZARDS NOT OTHERWISE CLASSIFIED: N/A SECTION III – COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS INGREDIENT CAS NUMBER PERCENT N/A N/A N/A SECTION IV - FIRST AID MEASURES EYES: Immediately flush with water for 15 - 20 minutes while holding eyelids open. Seek medical attention if irritation persists. INGESTION: Rinse mouth with water. Do not induce vomiting unless directed by medical authority. Seek medical attention if irritation persists. INHALATION: Move to fresh air. Avoid breathing oil mists. If breathing is difficult, administer oxygen. If not breathing administer artificial respiration. Seek immediate medical attention. SKIN: Immediately wash with soap and water for 15 minutes. Seek medical attention if irritation develops. ACUTE HEALTH HAZARDS: None Known CHRONIC HEALTH HAZARDS: None known NOTE TO PHYSICIAN: There is no specific treatment regimen. Treatment of overexposure should be directed at the control of and the clinical condition of the patient. SECTION V – FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA: Dry chemical or suitable for surrounding materials. UNSUITABLE EXTINGUISHING MEDIA: Water spray/stream. SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing and NIOSH approved SCBA with full facepiece operated in positive pressure or pressure demand. Use water mist to keep material cool in fire situations. UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep away from oxygen generating materials. HAZARDOUS COMBUSTION PRODUCTS: N/A SECTION VI – ACCIDENTAL RELEASE MEASURES PERSONAL PROTECTIVE EQUIPMENT: Refer to section VIII for proper Personal Protective Equipment. SPILL: Clean up using cloth or absorbent material. dispose of product-containing wiping cloth or absorbent paper in suitable manner. place waste in proper containers for waste disposal. WASTE DISPOSAL: Dispose of in accordance with federal, state, and local regulations. Do not reuse container and recycle or place in trash collection. Drums and pails should be offered for recycling. RCRA STATUS: Product should be fully characterized prior to disposal (40 CFR 261). Page 501 of 871 Page 501 of 871 Page 501 of 871 Page 501 of 871 ---PAGE BREAK--- Safety Data Sheet Lubri-Temp PAGE 2 of 4 SECTION VII – HANDLING AND STORAGE HANDLING AND STORAGE: Store in a cool, dry area. Do not use or store near heat or open flames. Keep container closed when not in use. OTHER PRECAUTIONS: Keep out of the reach of children. INCOMPATIBILITY: None Known SECTION VIII – EXPOSURE CONTROLS/PERSONAL PROTECTION HAZARDOUS INGREDIENT OSHA PEL ACGIH TLV N/A N/A N/A ENGINEERING CONTROLS / VENTILATION: Ambient ventilation adequate. RESPIRATORY PROTECTION: Not required with normal use. PERSONAL PROTECTIVE EQUIPMENT: Safety glasses and chemical resistant gloves ADDITIONAL MEASURES: Wash hands thoroughly with soap and water after use. SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Grey-Aluminum paste ODOR: Bland odor ODOR THRESHOLD: N/D BOILING POINT: Decomposes FREEZING POINT: N/D FLAMMABILITY: Not considered a flammable liquid by OSHA (29CFR 1910.1200) FLASH POINT: N/D AUTOIGNITION TEMPERATURE: N/D LOWER FLAMMABILITY LIMIT: N/D UPPER FLAMMABILITY LIMIT: N/D VAPOR PRESSURE (mm Hg): N/A VAPOR DENSITY (AIR=1): N/A EVAPORATION RATE: < 1 SPECIFIC GRAVITY (H2O=1): 0.950 SOLIDS N/A SOLUBILITY IN WATER: 0% PARTITION COEFFICIENT: n-OCTANOL/WATER (KOW): N/D VOLATILITY INCLUDING WATER VOLATILE ORGANIC COMPOUNDS (VOC): 0% DIELECTRIC STRENGTH (Volts): N/D DECOMPOSITION TEMPERATURE: N/D VISCOSITY: N/D SECTION X – STABILITY AND REACTIVITY DATA REACTIVITY: None Known CHEMICAL STABILITY: Stable CONDITIONS TO AVOID: Excessive heat. Sources of ignition. INCOMPATIBILITY: None Known HAZARDOUS DECOMPOSITION OR BY-PRODUCT: None Known POSSIBLE HAZARDOUS REACTIONS: None Known SECTION XI – TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION: Not Established ROUTES OF ENTRY: Eyes, Ingestion,Skin EYES: May cause irritation with prolonged exposure. INGESTION: Causes gastrointestinal irritation, nausea, diarrhea, vomiting. Page 502 of 871 Page 502 of 871 Page 502 of 871 Page 502 of 871 ---PAGE BREAK--- Safety Data Sheet Lubri-Temp PAGE 3 of 4 INHALATION: Unlikely due to low vapor pressure. Mist may cause irritation to the respiratory tract, headache. SKIN: Causes irritation with prolonged contact. MEDICAL CONDITION AGGRAVATED: None known ACUTE HEALTH HAZARDS: None Known CHRONIC HEALTH HAZARDS: None known CARCINOGENICITY: OSHA: No ACGIH: No NTP: No IARC: No OTHER: N/A SECTION XII – ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: Not Established BIODEGRADABILITY: Component or components of this product are not biodegradable. BIOACCUMULATION: Components in this mixture can bioaccumulate in aquatic organisms. SOIL MOBILITY: This product is not mobile in soil OTHER ECOLOGICAL HAZARDS: None Known SECTION XIII – DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with federal, state, and local regulations. Do not reuse container and recycle or place in trash collection. Drums and pails should be offered for recycling. RCRA STATUS: Product should be fully characterized prior to disposal (40 CFR 261). SECTION XIV - TRANSPORTATION INFORMATION PROPER SHIPPING NAME: Lubricating Oil Petroleum Base HAZARD CLASS/DIVISION: Not Regulated UN/NA NUMBER: N/A PACKAGING GROUP: None AIR SHIPMENT PROPER SHIPPING NAME: Lubricating Oil Petroleum Base HAZARD CLASS/DIVISION: Not Regulated UN/NA NUMBER: N/A SHIPPING BY WATER: VESSEL (IMO/IMDG) PROPER SHIPPING NAME: Lubricating Oil Petroleum Base HAZARD CLASS/DIVISION: Not Regulated UN/NA NUMBER: N/A ENVIRONMENTAL HAZARDS WATER: N/A SECTION XV - REGULATORY INFORMATION TSCA STATUS: All Chemicals are listed or exempt. CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): None SARA 311/312 HAZARD CATEGORIES: None SARA 313 REPORTABLE INGREDIENTS: None STATE REGULATIONS: California Proposition 65: None INTERNATIONAL REGULATIONS: All components are listed or exempted. NFPA HEALTH: 1 HMIS HEALTH: 1 NFPA FLAMMABILITY: 1 HMIS FLAMMABILITY: 1 NFPA REACTIVITY: 1 HMIS REACTIVITY: 1 NFPA OTHER: None HMIS PROTECTION: A SECTION XVI - ADDTIONAL INFORMATION PREPARATION BY: Maureen Ruggeberg, Regulatory Affairs Specialist DATE PREPARED: 12/4/2012 Page 503 of 871 Page 503 of 871 Page 503 of 871 Page 503 of 871 ---PAGE BREAK--- Safety Data Sheet Lubri-Temp PAGE 4 of 4 REVISION DATE: 10/30/2014 N/A = Not Applicable; N/D = Not Determined DISCLAIMER: To the best of our knowledge, information contained herein is accurate. However there is no assumption of liability for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazard which exists. The information contained in this SDS was obtained from current and reliable sources; however, the data is provided without any warranty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of the manufacturer, the manufacturer will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this SDS shall be created or inferred by any statement in this SDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this SDS. The user is responsible for full compliance. Page 504 of 871 Page 504 of 871 Page 504 of 871 Page 504 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 25-Mar-2014 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 19923 Product name Lubri-Temp Anti Seize Recommended Use Lubricant Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known. Principal Routes of Exposure Skin. Ingestion. Eyes. Potential health effects Eyes Irritating to eyes. Burning sensation. Redness. Tearing. Skin Prolonged skin contact may cause skin irritation. Inhalation May cause irritation of respiratory tract. Headaches. Ingestion Gastrointestinal irritation. Nausea. Diarrhea. Vomiting. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Polybutene 9003-29-6 60-100 Fumed Silica 112945-52-5 5-10 Aluminum 7429-90-5 5-10 Graphite 7782-42-5 5-10 Petroleum distillates, hydrotreated heavy naphthenic 64742-52-5 1-5 Antimony N/A 1-5 4. FIRST AID MEASURES Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek medical attention if irritation persists. Skin contact Wash off immediately with plenty of water for at least 15 minutes. Seek medical attention if irritation persists. Ingestion Rinse mouth. Do Not induce vomiting without medical advice. Seek medical attention if irritation persists. Inhalation Move to fresh air. Avoid breathing spray mist. If breathing is difficult, give oxygen. Administer artificial respiration if not breathing. Seek medical attention immediately. 5. FIRE FIGHTING MEASURES Flash point °C No data available Flash point °F No data available Method No information available Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper No data available Lower No data available Suitable extinguishing media Dry chemical. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Fire and Explosion Hazards Oil and grease on torches can cause a violent reaction in the presence of oxygen. Sensitivity to shock No information available. Sensitivity to static discharge No information available. Page 1 / 3 Emergency Overview Irritating to eyes. Page 505 of 871 Page 505 of 871 Page 505 of 871 Page 505 of 871 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Soak up excess with absorbent material. Collect and contain for disposal. Flush area with water. 7. HANDLING AND STORAGE Handling Keep away from open flame. Keep from excessive heat. Keep out of reach of children. Storage Keep closed in a dry and cool place. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Polybutene - - - - Petroleum distillates, hydrotreated heavy naphthenic - - - - Fumed Silica - - - - Aluminum 15 mg/m3 - 1 mg/m3 - Graphite 15 mg/m3 - 2 mg/m3 - Antimony rbamate - - - - Ventilation and Environmental Controls Normal ventilation is adequate. Hygiene measures Wash hands after handling the product. Respiratory protection None necessary under normal conditions. Hand Protection Chemical resistant gloves. Eye protection ANSI approved safety glasses are recommended to prevent accidental eye contact. Skin and body protection None necessary under normal conditions Other Protective Equipment An eye wash station should be available. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Solid Color Silver Gray Odor None Odor Threshold Not Applicable pH Not Applicable Specific Gravity 0.950 Vapor pressure Not Applicable Vapor density Not Applicable Evaporation Rate <1 (air = 1) Water solubility 0% VOC Content 0 Partition Coefficient (n-octanol/water) No data available Boiling point/range °C No data available Boiling point/range °F No data available Melting point/range °C No data available Melting point/range °F No data available Flash point °F No data available 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid Do not use on oxygen lines. Heat, flames and sparks. Avoid extreme heat. Avoid heat, sparks, and other sources of ignition. Avoid sources of ignition. Incompatability Oxygen. Hazardous Decomposition Products Carbon monoxide. Polymerization Hazardous polymerization does not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Polybutene 9003-29-6 - - - Petroleum distillates, hydrotreated heavy naphthenic 64742-52-5 28710 mg/kg - - Fumed Silica 112945-52-5 - - - Aluminum 7429-90-5 - - - Graphite 7782-42-5 - - - Antimony mate N/A - - - Page 2 / 3 Product name Lubri-Temp Anti Seize Product code 19923 Page 506 of 871 Page 506 of 871 Page 506 of 871 Page 506 of 871 ---PAGE BREAK--- Synergistic Products None known . Potential health effects Sensitization None known . Chronic toxicity None known . Mutagenic effects None known . Teratogenic effects None known . Reproductive toxicity None known . Target Organ Effects None Known. Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Polybutene Not Listed Not Listed Not Listed Not Listed Not Listed Petroleum distillates, hydrotreated heavy naphthenic Not Listed Not Listed Not Listed Not Listed Not Listed Fumed Silica Not Listed Not Listed Not Listed Not Listed Not Listed Aluminum A4 Not Listed Not Listed Not Listed Not Listed Graphite Not Listed Not Listed Not Listed Not Listed Not Listed Antimony rbamate Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Disposal Information Do not puncture or incinerate. Do not reuse container. Wrap container and place in trash collection. Drums should be offered for recycling. 14. TRANSPORTATION INFORMATION DOT Not Regulated TDG Not Regulated 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Aluminum Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Polybutene Not Listed Not Listed Not Listed Petroleum distillates, hydrotreated heavy naphthenic Not Listed Not Listed Not Listed Fumed Silica Not Listed Not Listed Not Listed Aluminum Listed Listed Not Listed Graphite Not Listed Listed Not Listed Antimony Not Listed Not Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA Polybutene - X - X Petroleum distillates, hydrotreated heavy naphthenic X X - X Fumed Silica - X - - Aluminum X X - X Graphite X X - X Antimony - - - - CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION NFPA NFPA Health - 1 Flammability - 1 Reactivity - 1 HMIS Health - 1 Flammability - 1 Physical Hazard - 1 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 3 / 3 Water Flea Data Daphnia magna EC50>1000 mg/L (48 h) Product code 19923 Product name Lubri-Temp Anti Seize Petroleum distillates, hydrotreated heavy naphthenic Page 507 of 871 Page 507 of 871 Page 507 of 871 Page 507 of 871 ---PAGE BREAK--- Page 1 of 3 Print Date 03/09/2004 MSDS Document Product Metal Repair Epoxy Cartridge Part A 1. Chemical Product and Company Identification Trade Name of this Product Metal Repair Epoxy Cartridge Part A MSDS ID 55375A Manufacturer Lawson Products, Inc. 1666 East Touhy Avenue Des Plaines, IL 60018 Contact Name Corporate Compliance Team Phone Number (847) 827-9666 Emergency Phone (888) 426-4851 Revision Date 03/17/2003 1 1 0 Health: Fire: Reactivity: Specific Health: Fire: Reactivity: Specific 1 1 0 2. Composition and Information on Ingredients Ingredient CAS Number Weight % ACGIH TLV PEL STEL Epoxy Resin 67989-52-0 54.0 % ND ND ND Cresyl Glycidyl Ether 26447-14-3 23.0 % 3. Hazard Identification Synergistic Products N/A Target Organs Affected Eyes, Gastrointestinal Tract, Skin. Effects Of Overexposure Irritates eyes. Prolonged or repeated contact may irritate skin. Nose and throat irritant. Route Of Entry Skin Eyes Ingestion 4. First Aid Information EMERGENCY AND FIRST AID PROCEDURES Eyes- Flush with water for 15 minutes. Ingestion- Induce vomiting. Call Physician. 5. Fire Fighting Measures Extinguishing Media Foam Carbon Dioxide Dry Chemical Water Fog Page 508 of 871 Page 508 of 871 Page 508 of 871 Page 508 of 871 ---PAGE BREAK--- Page 2 of 3 Print Date 03/09/2004 MSDS ID 55375A Metal Repair Epoxy Cartridge Part A 6. Accidental Release Measures Material Release or Spill N/A. 7. Handling and Storage Handling Precautions N/A Storage Store in a cool, dry place away from heat and open flame. Keep out of reach of children Handling Precautions Read Entire Label Before Using. Handling Avoid eye contact and excessive skin contact. Hygienic Practices Wash hands before eating or using the washroom. Smoke in SMOKING AREAS ONLY. 8. Exposure Controls and Personal Protection Other Protective Equipment Not required. Eye Protection Safety Glasses. Other PPE N/A Protective Gloves Required for prolonged or repeated contact. Ventilation As required. Respiratory Protection None Required. 9. Physical and Chemical Properties Physical State Solid Specific Gravity 1.361 pH N/A ODOR AND APPEARANCE Putty appearance. 10. Stability and Reactivity Incompatibility N/A HAZARDOUS DECOMPOSITION PRODUCTS Thermal decomposition in the presence of air may yield major ac- counts of oxides of carbon and minor amounts of oxides of sulfur and nitrogen. Hazardous Polymerization Will not occur. Page 509 of 871 Page 509 of 871 Page 509 of 871 Page 509 of 871 ---PAGE BREAK--- Page 3 of 3 Print Date 03/09/2004 MSDS ID 55375A Metal Repair Epoxy Cartridge Part A 11. Toxicological Information Carcinogenicity None of the components in this chemical are listed by IARC, NTP or OSHA as a carcinogen. 12. Ecological Information Ecological Information No information available. 13. Disposal Considerations Waste Disposal Method Must be in accordance with applicable laws and regulations. 14. Transportation Information OSHA CLASS N/A PER DOT N/A DOT Class N/A PER IMCO N/A IMCO Classification Number N/A IATA Classification Number N/A 15. Regulatory Information CPR Certification This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. Other Information Other Precautions No information available. Page 510 of 871 Page 510 of 871 Page 510 of 871 Page 510 of 871 ---PAGE BREAK--- Page 1 of 3 Print Date 03/09/2004 MSDS Document Product Metal Repair Epoxy Cartridge Part B 1. Chemical Product and Company Identification Trade Name of this Product Metal Repair Epoxy Cartridge Part B MSDS ID 55375B Manufacturer Lawson Products, Inc. 1666 East Touhy Avenue Des Plaines, IL 60018 Contact Name Corporate Compliance Team Phone Number (847) 827-9666 Emergency Phone (888) 426-4851 Revision Date 03/17/2003 3 1 0 Health: Fire: Reactivity: Specific Health: Fire: Reactivity: Specific 3 1 0 2. Composition and Information on Ingredients Ingredient CAS Number Weight % ACGIH TLV PEL STEL 140-31-8 29.0 % 25154-52-3 28.0 % 3. Hazard Identification Synergistic Products N/A Irritancy Of Product Moderate eye irritant. Target Organs Affected Eyes, Gastrointestinal Tract, Skin. EFFECTS OF OVEREXPOSURE Eyes: Irritation, Redness, Tearing, blurred vision. Skin: Moderate irritation, dermatitis. Breathing: Nasal and respiratory irritation, dizziness, headache, nausea, possible unconsciousness, and even Swallowing: Gastro-intestinal irritation, nausea, vomiting, diarrhea. Route Of Entry Skin Eyes Inhalation Ingestion 4. First Aid Information First Aid Procedures Give oxygen. Do not induce vomiting. Gastric lavage- Wash eyes and skin with water. Page 511 of 871 Page 511 of 871 Page 511 of 871 Page 511 of 871 ---PAGE BREAK--- Page 2 of 3 Print Date 03/09/2004 MSDS ID 55375B Metal Repair Epoxy Cartridge Part B 5. Fire Fighting Measures Flash Point 250 Extinguishing Media Alcohol Foam Carbon Dioxide Dry Chemical Water Fog 6. Accidental Release Measures STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Contain to prevent spreading. Keep away from groundwater. Collect run-off water and dispose. Cover minor spills with sodium bisulfate to neutralize. Place in metal containers. 7. Handling and Storage Handling Precautions N/A Storage Store in a cool, dry place away from heat and open flame. Keep out of reach of children Handling Precautions Read Entire Label Before Using. Handling Avoid eye contact and excessive skin contact. Hygienic Practices Wash hands before eating or using the washroom. Smoke in SMOKING AREAS ONLY. 8. Exposure Controls and Personal Protection Other Protective Equipment Eye wash station and safety showers should be available. Eye Protection Safety Glasses. Clothing Impermeable clothing should be used to prevent excessive skin contact. Other PPE N/A Protective Gloves Required for prolonged or repeated contact. Ventilation If current ventilation practices are not adequate in maintaining airborne concentrations below the established exposure limits, additional ventilation or exhaust systems may be required. RESPIRATORY PROTECTION Use in a well ventilated area. 9. Physical and Chemical Properties Physical State Liquid Specific Gravity 1.289 pH N/A Boiling/Cond. Point 450.0 ODOR AND APPEARANCE Paste. Page 512 of 871 Page 512 of 871 Page 512 of 871 Page 512 of 871 ---PAGE BREAK--- Page 3 of 3 Print Date 03/09/2004 MSDS ID 55375B Metal Repair Epoxy Cartridge Part B 10. Stability and Reactivity Incompatibility Strong oxidizing agents, strong acids or bases. N/A HAZARDOUS DECOMPOSITION PRODUCTS Oxides of nitrogen; Carbon monoxide. Hazardous Polymerization Will not occur. 11. Toxicological Information Carcinogenicity None of the components in this chemical are listed by IARC, NTP or OSHA as a carcinogen. 12. Ecological Information Ecological Information No information available. 13. Disposal Considerations Waste Disposal Method Must be in accordance with applicable laws and regulations. 14. Transportation Information OSHA CLASS N/A PER DOT N/A DOT Class N/A PER IMCO N/A IMCO Classification Number N/A IATA Classification Number N/A 15. Regulatory Information CPR Certification This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. Other Information Other Precautions No information available. Page 513 of 871 Page 513 of 871 Page 513 of 871 Page 513 of 871 ---PAGE BREAK--- page 1 of 4 HMIS Codes Health 2* Flammability 2 Reactivity 0 DATE OF PREPARATION Jul 17, 2015 MATERIAL SAFETY DATA SHEET B55WZ611 25 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER B55WZ611 PRODUCT NAME METALASTIC® DTM Acrylic Modified Enamel, Extra White MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 Telephone Numbers and Websites Product Information (800) 524-5979 www.sherwin-williams.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 14 64742-88-7 Mineral Spirits 140-Flash ACGIH TLV 100 PPM 0.5 mm OSHA PEL 100 PPM 0.7 100-41-4 ACGIH TLV 20 PPM 7.1 mm OSHA PEL 100 PPM OSHA PEL 125 PPM STEL 4 1330-20-7 Xylene ACGIH TLV 100 PPM 5.9 mm ACGIH TLV 150 PPM STEL OSHA PEL 100 PPM OSHA PEL 150 PPM STEL 4 14807-96-6 Talc ACGIH TLV 2 mg/m3 as Resp. Dust OSHA PEL 2 mg/m3 as Resp. Dust 14 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system the reproductive system Page 514 of 871 Page 514 of 871 Page 514 of 871 Page 514 of 871 ---PAGE BREAK--- B55WZ611 page 2 of 4 UEL 7.0 LEL 0.9 FLASH POINT 123 °F PMCC SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION Combustible, Flash above 99 and below 200 °F EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY DOL Storage Class II PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Contents are COMBUSTIBLE. Keep away from heat and open flame. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. Page 515 of 871 Page 515 of 871 Page 515 of 871 Page 515 of 871 ---PAGE BREAK--- B55WZ611 page 3 of 4 EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 12.19 lb/gal 1460 g/l SPECIFIC GRAVITY 1.47 BOILING POINT 281 - 416 °F 138 - 213 °C MELTING POINT Not Available VOLATILE VOLUME 38% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 2.60 lb/gal 311 g/l Less Water and Federally Exempt Solvents 2.60 lb/gal 311 g/l Emitted VOC SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that causes cancer in humans. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." TOXICOLOGY DATA CAS No. Ingredient Name 64742-88-7 Mineral Spirits 140-Flash LC50 RAT 4HR Not Available LD50 RAT Not Available 100-41-4 LC50 RAT 4HR Not Available LD50 RAT 3500 mg/kg 1330-20-7 Xylene LC50 RAT 4HR 5000 ppm LD50 RAT 4300 mg/kg 14807-96-6 Talc LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Page 516 of 871 Page 516 of 871 Page 516 of 871 Page 516 of 871 ---PAGE BREAK--- B55WZ611 page 4 of 4 SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) May be Classed as a Combustible Liquid for U.S. Ground. UN1263, PAINT, 3, PG III, (ERG#128) DOT (Dept of Transportation) Hazardous Substances & Reportable Quantities Xylenes (isomers and mixture) 100 lb RQ Bulk Containers may be Shipped as (check reportable quantities): RQ, UN1263, PAINT, 3, PG III, (XYLENES (ISOMERS AND MIXTURE)), (ERG#128) Canada (TDG) May be Classed as a Combustible Liquid for Canadian Ground. UN1263, PAINT, 3, PG III, (ERG#128) IMO 5 Liters (1.3 Gallons) and Less may be Shipped as Limited Quantity. UN1263, PAINT, 3, PG III, (51 C EmS F-E, S-E IMO 5 Liters (1.3 Gallons) and Less may be Shipped as Limited Quantity. UN1263, PAINT, 3, PG III, (51 C EmS F-E, S-E IATA/ICAO UN1263, PAINT, 3, PG III SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 100-41-4 0.6 1330-20-7 Xylene 4 Zinc Compound 3 1.3 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 517 of 871 Page 517 of 871 Page 517 of 871 Page 517 of 871 ---PAGE BREAK--- SAFETY DATA SHEET Issuing Date No data available Revision Date 08-Nov-2013 Revision Number 1 The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved. Page 1 / 12 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Mineral Spirits Other means of identification Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Paint Thinner (*Note Future CARB requirements: 2013 - 3 wt%) Uses advised against No information available Details of the supplier of the safety data sheet Supplier Name Sunnyside Corporation Supplier Address 225 Carpenter Avenue Wheeling IL 60090 Supplier Phone Number Supplier Email US Phone:[PHONE REDACTED] Fax:[PHONE REDACTED] [EMAIL REDACTED] Chem Trec [PHONE REDACTED] Emergency telephone number 2. HAZARDS IDENTIFICATION Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Aspiration toxicity Category 1 Flammable liquids Category 3 Product Number 803 Page 518 of 871 Page 518 of 871 Page 518 of 871 Page 518 of 871 ---PAGE BREAK--- 1119374 - Mineral Spirits Revision Date 08-Nov-2013 Page 2 / 12 GHS Label elements, including precautionary statements Emergency Overview Signal word Warning Hazard Statements May be fatal if swallowed and enters airways Flammable liquid and vapor Appearance Clear Physical State Liquid Odor Petroleum distillates Precautionary Statements - Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep container closed Ground/bond container and receiving equipment Use explosion-proof electrical/ ventilating/ lighting/ equipment Use only non-sparking tools Take precautionary measures against static discharge Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response None Skin IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Ingestion IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting Fire In case of fire: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep cool Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity Page 519 of 871 Page 519 of 871 Page 519 of 871 Page 519 of 871 ---PAGE BREAK--- 1119374 - Mineral Spirits Revision Date 08-Nov-2013 Page 3 / 12 Other information No information available Interactions with Other Chemicals No information available. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Trade Secret Solvent naphtha (petroleum), medium aliphatic 64742-88-7 60 - 100 * *The exact percentage (concentration) of composition has been withheld as a trade secret 4. FIRST AID MEASURES First aid measures General Advice Show this safety data sheet to the doctor in attendance. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye irritation persists: Get medical advice/attention. Skin Contact Wash skin with soap and water. Get medical attention if irritation develops and persists. Take off contaminated clothing and wash before reuse. Inhalation If persist, call a physician. Ingestion Rinse mouth. Do NOT induce vomiting. Call a physician or poison control center immediately. Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. Most important and effects, both acute and delayed Most Important and Effects Difficulty in breathing. Dizziness. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat Because of the danger of aspiration, emesis or gastric lavage should not be employed unless the risk is justified by the presence of additional toxic substances. Page 520 of 871 Page 520 of 871 Page 520 of 871 Page 520 of 871 ---PAGE BREAK--- 1119374 - Mineral Spirits Revision Date 08-Nov-2013 Page 4 / 12 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use:. Dry chemical, CO2, water spray or regular foam. Unsuitable Extinguishing Media CAUTION: All these products have a very low flash point. Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical Vapors can form explosive mixtures with air. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). Vapors may travel to source of ignition and flash back. Uniform Fire Code Combustible Liquid: II Hazardous Combustion Products Carbon oxides. Explosion Data Sensitivity to Mechanical Impact No. Sensitivity to Static Discharge Yes. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Pay attention to flashback. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Other Information Water spray may reduce vapor; but may not prevent ignition in closed spaces. Environmental Precautions Environmental Precautions Prevent entry into waterways, sewers, basements or confined areas. Methods and material for containment and cleaning up Methods for Containment A vapor suppressing foam may be used to reduce vapors. Methods for cleaning up Dam up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Use clean non-sparking tools to collect absorbed material. Clean up by sweeping or vacuum. Keep in suitable, closed containers for disposal. Page 521 of 871 Page 521 of 871 Page 521 of 871 Page 521 of 871 ---PAGE BREAK--- 1119374 - Mineral Spirits Revision Date 08-Nov-2013 Page 5 / 12 7. HANDLING AND STORAGE Precautions for safe handling Handling Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use grounding and bonding connection when transferring this material to prevent static discharge, fire or explosion. Use according to package label instructions. Use personal protection equipment. Use with local exhaust ventilation. Use spark-proof tools and explosion-proof equipment. Avoid contact with skin, eyes or clothing. Avoid breathing vapors or mists. Conditions for safe storage, including any incompatibilities Storage Keep containers closed in a dry, cool and well-ventilated place. Protect from moisture. Store locked up. Keep out of the reach of children. Store away from other materials. Keep away from heat, sparks, flame and other sources of ignition pilot lights, electric motors and static electricity). Keep in properly labeled containers. Do not store near combustible materials. Keep in an area equipped with sprinklers. Store in accordance with the particular national regulations. Store in accordance with local regulations. Incompatible Products Strong oxidizing agents. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection Tight sealing safety goggles. Skin and Body Protection Wear protective gloves and protective clothing. Long sleeved clothing. Chemical resistant apron. Impervious gloves. Antistatic boots. Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is recommended. Wash hands before breaks and immediately after handling the product. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 522 of 871 Page 522 of 871 Page 522 of 871 Page 522 of 871 ---PAGE BREAK--- 1119374 - Mineral Spirits Revision Date 08-Nov-2013 Page 6 / 12 Physical and Chemical Properties Physical State Liquid Appearance Clear Odor Petroleum distillates Color No information available Odor Threshold No information available Property Values Remarks/ Method pH UNKNOWN None known Melting / freezing point No data available None known Boiling point / boiling range 157 °C / 315 °F None known Flash Point 42 C / 108 F None known Evaporation Rate No data available None known Flammability (solid, gas) No data available None known Flammability Limit in Air Upper flammability limit No data available Lower flammability limit No data available Vapor pressure No data available None known Vapor density No data available None known Specific Gravity No data available None known Water Solubility Insoluble in water None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/water No data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known Explosive properties No data available Oxidizing Properties No data available Other Information Softening Point No data available VOC Content No data available Particle Size No data available Particle Size Distribution Page 523 of 871 Page 523 of 871 Page 523 of 871 Page 523 of 871 ---PAGE BREAK--- 1119374 - Mineral Spirits Revision Date 08-Nov-2013 Page 7 / 12 10. STABILITY AND REACTIVITY Reactivity No data available. Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to avoid Heat, flames and sparks. Incompatible materials Strong oxidizing agents. Hazardous Decomposition Products Carbon oxides. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Product does not present an acute toxicity hazard based on known or supplied information. . Inhalation Specific test data for the substance or mixture is not available. May cause drowsiness and dizziness. Eye Contact Specific test data for the substance or mixture is not available. Skin Contact Specific test data for the substance or mixture is not available. Ingestion Specific test data for the substance or mixture is not available. Potential for aspiration if swallowed. May be fatal if swallowed and enters airways. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Solvent naphtha (petroleum), medium aliphatic 64742-88-7 > 5000 mg/kg ( Rat ) = 3000 mg/kg ( Rabbit ) > 5.28 mg/L ( Rat ) 4 h Information on toxicological effects Difficulty in breathing. Vapors may cause drowsiness and dizziness. Page 524 of 871 Page 524 of 871 Page 524 of 871 Page 524 of 871 ---PAGE BREAK--- 1119374 - Mineral Spirits Revision Date 08-Nov-2013 Page 8 / 12 Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Mutagenic Effects No information available. Carcinogenicity Contains no ingredient listed as a carcinogen. Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Target Organ Effects Respiratory system. Aspiration Hazard No information available. Numerical measures of toxicity Product Information The following values are calculated based on chapter 3.1 of the GHS document ATEmix (dermal) 3,000.00 mg/kg (ATE) 12. ECOLOGICAL INFORMATION Ecotoxicity The environmental impact of this product has not been fully investigated. Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Microorganisms Daphnia Magna (Water Flea) Solvent naphtha (petroleum), medium aliphatic 64742-88-7 96h EC50: = 450 mg/L (Pseudokirchneriella subcapitata) 96h LC50: = 800 mg/L (Pimephales promelas) 48h EC50: > 100 mg/L Persistence and Degradability No information available. Bioaccumulation No information available Other adverse effects No information available. Page 525 of 871 Page 525 of 871 Page 525 of 871 Page 525 of 871 ---PAGE BREAK--- 1119374 - Mineral Spirits Revision Date 08-Nov-2013 Page 9 / 12 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal methods This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated Packaging Dispose of contents/containers in accordance with local regulations. US EPA Waste Number D001 California Hazardous Waste Codes 213 14. TRANSPORT INFORMATION DOT NOT REGULATED (If shipped in NON BULK packaging by ground transport) Proper Shipping Name NON-REGULATED Hazard Class N/A Emergency Response Guide Number 128 TDG UN-No. UN1268 Proper Shipping Name PETROLEUM DISTILLATES, N.O.S. Hazard Class 3 Packing Group III MEX UN-No. UN1268 Proper Shipping Name Petroleum distillates, n.o.s. Hazard Class 3 Packing Group III Description UN1268 Petroleum distillates, n.o.s.,3,III ICAO UN-No. UN1268 Proper Shipping Name Petroleum distillates, n.o.s. Hazard Class 3 Packing Group III Description 1268,Petroleum distillates, n.o.s.,3,PG III IATA UN-No. 1268 Proper Shipping Name PETROLEUM DISTILLATES, N.O.S. Hazard Class 3 Packing Group III Description UN1268,Petroleum distillates, n.o.s.,3,PG III IMDG/IMO UN-No. 1268 Page 526 of 871 Page 526 of 871 Page 526 of 871 Page 526 of 871 ---PAGE BREAK--- 1119374 - Mineral Spirits Revision Date 08-Nov-2013 Page 10 / 12 Proper Shipping Name Petroleum distillates, n.o.s. Hazard Class 3 Packing Group III EmS No. F-E, S-E Description 1268, Petroleum distillates, n.o.s.,3,PG III, FP 42C RID UN-No. 1268 Proper Shipping Name Petroleum distillates, n.o.s. Hazard Class 3 Packing Group III Classification code F1 Description 1268 Petroleum distillates, n.o.s.,3,III ADR UN-No. UN1268 Proper Shipping Name Petroleum distillates, n.o.s. Hazard Class 3 Packing Group III Classification code F1 Description UN1268 Petroleum distillates, n.o.s.,3,III ADN UN-No. UN1268 Proper Shipping Name Petroleum distillates, n.o.s. Hazard Class 3 Packing Group III Classification code F1 Description UN1268 Petroleum distillates, n.o.s.,3,III Hazard Labels 3 Limited Quantity LQ7 Ventilation VE01 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL All components are listed either on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard Yes Sudden release of pressure hazard No Reactive Hazard No Page 527 of 871 Page 527 of 871 Page 527 of 871 Page 527 of 871 ---PAGE BREAK--- 1119374 - Mineral Spirits Revision Date 08-Nov-2013 Page 11 / 12 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations . Chemical Name New Jersey Massachusetts Rhode Island Illinois Solvent naphtha (petroleum), medium aliphatic 64742-88-7 X International Regulations Canada WHMIS Hazard Class B3 - Combustible liquid 16. OTHER INFORMATION NFPA Health Hazards 1 Flammability 2 Instability 0 Physical and Chemical Hazards - HMIS Health Hazards 1 Flammability 2 Physical Hazard 0 Personal Protection X Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-[PHONE REDACTED] Revision Date 08-Nov-2013 Revision Note No information available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text Page 528 of 871 Page 528 of 871 Page 528 of 871 Page 528 of 871 ---PAGE BREAK--- 1119374 - Mineral Spirits Revision Date 08-Nov-2013 Page 12 / 12 End of Safety Data Sheet Page 529 of 871 Page 529 of 871 Page 529 of 871 Page 529 of 871 ---PAGE BREAK--- MINWAX® Stainable Wood Filler Not available. Liquid. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer : MINWAX Company 10 Mountainview Road Upper Saddle River, NJ 07458 Relevant identified uses of the substance or mixture and uses advised against Not applicable. 4285- 4285- Product code : Product Information Telephone Number : (800) 523-9299 Regulatory Information Telephone Number : (216) 566-2902 Transportation Emergency Telephone Number : (800) 424-9300 Section 2. Hazards identification Not classified. Classification of the substance or mixture : Signal word : No signal word. Precautionary statements Prevention : Not applicable. Response : Not applicable. Storage : Not applicable. Disposal Not applicable. GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 20% General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product. Hazards not otherwise classified :None known. No known significant effects or critical hazards. : Hazard statements Please refer to the SDS for additional information. Do not transfer contents to other containers for storage. Supplemental label elements WARNING: This product contains a chemical known to the State of California to cause cancer. Date of issue/Date of revision : 5/21/2015. Date of previous issue : No previous validation. Version : 1 1/9 Page 530 of 871 Page 530 of 871 Page 530 of 871 Page 530 of 871 ---PAGE BREAK--- Section 3. Composition/information on ingredients There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification : Not available. Substance/mixture CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if occur. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if occur. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if occur. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Description of necessary first aid measures Specific treatments : No specific treatment. Most important acute and delayed Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. : Eye contact Over-exposure Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : No specific data. Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Date of issue/Date of revision : 5/21/2015. Date of previous issue : No previous validation. Version : 1 2/9 Page 531 of 871 Page 531 of 871 Page 531 of 871 Page 531 of 871 ---PAGE BREAK--- Section 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Protective measures Put on appropriate personal protective equipment (see Section : Precautions for safe handling Date of issue/Date of revision : 5/21/2015. Date of previous issue : No previous validation. Version : 1 3/9 Page 532 of 871 Page 532 of 871 Page 532 of 871 Page 532 of 871 ---PAGE BREAK--- Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : : None. Section 8. Exposure controls/personal protection Hand protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Control parameters Individual protection measures Occupational exposure limits Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Date of issue/Date of revision : 5/21/2015. Date of previous issue : No previous validation. Version : 1 4/9 Page 533 of 871 Page 533 of 871 Page 533 of 871 Page 533 of 871 ---PAGE BREAK--- Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. 0.83 1 [Air = 1] 0.31 kPa (2.333 mm Hg) [at 20°C] Not available. Not available. Odor pH Not available. Color Evaporation rate 0.09 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Not available. Not available. 9.3 Viscosity Kinematic (room temperature): >0.205 cm2/s (>20.5 cSt) Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt) Not available. Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : 100°C (212°F) Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Decomposition temperature : Not available. Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Not available. Irritation/Corrosion Not available. Sensitization Not available. Information on toxicological effects Date of issue/Date of revision : 5/21/2015. Date of previous issue : No previous validation. Version : 1 5/9 Page 534 of 871 Page 534 of 871 Page 534 of 871 Page 534 of 871 ---PAGE BREAK--- Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Not available. Not available. Aspiration hazard Not available. Not available. Information on the likely routes of exposure Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. : Eye contact No known significant effects or critical hazards. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : No specific data. Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure : Not available. Potential acute health effects Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Date of issue/Date of revision : 5/21/2015. Date of previous issue : No previous validation. Version : 1 6/9 Page 535 of 871 Page 535 of 871 Page 535 of 871 Page 535 of 871 ---PAGE BREAK--- Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Numerical measures of toxicity Not available. Acute toxicity estimates Section 12. Ecological information Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Not available. Toxicity Not available. Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Not available. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. : Disposal methods Section 14. Transport information - - - - - - Not regulated. Not regulated. DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group TDG Classification Not regulated. - - - Mexico Classification Not regulated. - - - IATA Not regulated. - - - Date of issue/Date of revision : 5/21/2015. Date of previous issue : No previous validation. Version : 1 7/9 Page 536 of 871 Page 536 of 871 Page 536 of 871 Page 536 of 871 ---PAGE BREAK--- Section 14. Transport information Special provisions Not Applicable Emergency schedules (EmS) Not Applicable Additional information Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No. No. : Not available. : No. Special provisions Not Applicable No. Special provisions Not Applicable Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. No. Special provisions Not Applicable Section 15. Regulatory information U.S. Federal regulations : WARNING: This product contains a chemical known to the State of California to cause cancer. California Prop. 65 State regulations Section 16. Other information Hazardous Material Information System 1 0 0 Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Date of issue/Date of revision : 5/21/2015. Date of previous issue : No previous validation. Version : 1 8/9 Page 537 of 871 Page 537 of 871 Page 537 of 871 Page 537 of 871 ---PAGE BREAK--- Section 16. Other information It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Notice to reader Date of issue/Date of revision : 5/21/2015. Date of previous issue : No previous validation. Version : 1 9/9 Page 538 of 871 Page 538 of 871 Page 538 of 871 Page 538 of 871 ---PAGE BREAK--- Product Name: MOBIL RARUS 427 Revision Date: 16 Mar 2015 Page 1 of 10 SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: MOBIL RARUS 427 Product Description: Base Oil and Additives Product Code: 201560202040, 606202-00, 970996 Intended Use: Compressor oil COMPANY IDENTIFICATION Supplier: EXXON MOBIL CORPORATION 22777 Springwoods Village Parkway Spring, TX. 77389 USA 24 Hour Health Emergency [PHONE REDACTED] Transportation Emergency Phone [PHONE REDACTED] or [PHONE REDACTED] CHEMTREC Product Technical Information [PHONE REDACTED] MSDS Internet Address http://www.exxon.com, http://www.mobil.com SECTION 2 HAZARDS IDENTIFICATION This material is not hazardous according to regulatory guidelines (see (M)SDS Section 15). Other hazard information: HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200. PHYSICAL / CHEMICAL HAZARDS No significant hazards. HEALTH HAZARDS High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, or respiratory irritation. ENVIRONMENTAL HAZARDS No significant hazards. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. Page 539 of 871 Page 539 of 871 Page 539 of 871 Page 539 of 871 ---PAGE BREAK--- Product Name: MOBIL RARUS 427 Revision Date: 16 Mar 2015 Page 2 of 10 SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS This material is defined as a mixture. Hazardous Substance(s) or Complex Substance(s) required for disclosure Name CAS# Concentration* GHS Hazard Codes OXA DITHIA PHOSPHATETRADECANOIC ACID ESTER 83547-95-9 0.1 - < 1% H315, H317, H401, H411 * All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. As per paragraph of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and exact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact percentage composition will be provided to health professionals, employees, or designated representatives in accordance with applicable provisions of paragraph SECTION 4 FIRST AID MEASURES INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, Page 540 of 871 Page 540 of 871 Page 540 of 871 Page 540 of 871 ---PAGE BREAK--- Product Name: MOBIL RARUS 427 Revision Date: 16 Mar 2015 Page 3 of 10 sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Smoke, Fume, Aldehydes, Oxides of carbon, Sulfur oxides, Incomplete combustion products FLAMMABILITY PROPERTIES Flash Point [Method]: >210°C (410°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802. PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended. SPILL MANAGEMENT Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. Page 541 of 871 Page 541 of 871 Page 541 of 871 Page 541 of 871 ---PAGE BREAK--- Product Name: MOBIL RARUS 427 Revision Date: 16 Mar 2015 Page 4 of 10 SECTION 7 HANDLING AND STORAGE HANDLING This material is not intended for use in air compressors for breathing applications. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present during switch-loading operations). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. STORAGE The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store in open or unlabelled containers. Keep away from incompatible materials. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols can occur the following are recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction), 5 mg/m³ - OSHA PEL. NOTE: Limits/standards shown for guidance only. Follow applicable regulations. No biological limits allocated. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. Page 542 of 871 Page 542 of 871 Page 542 of 871 Page 542 of 871 ---PAGE BREAK--- Product Name: MOBIL RARUS 427 Revision Date: 16 Mar 2015 Page 5 of 10 For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Physical State: Liquid Color: Amber Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 0.879 Flammability (Solid, Gas): N/A Flash Point [Method]: >210°C (410°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) Decomposition Temperature: N/D Vapor Density (Air = > 2 at 101 kPa Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C Evaporation Rate (n-butyl acetate = N/D pH: N/A Page 543 of 871 Page 543 of 871 Page 543 of 871 Page 543 of 871 ---PAGE BREAK--- Product Name: MOBIL RARUS 427 Revision Date: 16 Mar 2015 Page 6 of 10 Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 100 cSt (100 mm2/sec) at 40 °C Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -9°C (16°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt SECTION 10 STABILITY AND REACTIVITY REACTIVITY: See sub-sections below. STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS Hazard Class Conclusion / Remarks Inhalation Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Ingestion Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Corrosion/Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on assessment of the components. Eye Serious Eye Damage/Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components. Sensitization Respiratory Sensitization: No end point data for material. Not expected to be a respiratory sensitizer. Skin Sensitization: No end point data for material. Not expected to be a skin sensitizer. Based on assessment of the components. Aspiration: Data available. Not expected to be an aspiration hazard. Based on physico- chemical properties of the material. Page 544 of 871 Page 544 of 871 Page 544 of 871 Page 544 of 871 ---PAGE BREAK--- Product Name: MOBIL RARUS 427 Revision Date: 16 Mar 2015 Page 7 of 10 Germ Cell Mutagenicity: No end point data for material. Not expected to be a germ cell mutagen. Based on assessment of the components. Carcinogenicity: No end point data for material. Not expected to cause cancer. Based on assessment of the components. Reproductive Toxicity: No end point data for material. Not expected to be a reproductive toxicant. Based on assessment of the components. Lactation: No end point data for material. Not expected to cause harm to breast-fed children. Specific Target Organ Toxicity (STOT) Single Exposure: No end point data for material. Not expected to cause organ damage from a single exposure. Repeated Exposure: No end point data for material. Not expected to cause organ damage from prolonged or repeated exposure. Based on assessment of the components. OTHER INFORMATION For the product itself: Component concentrations in this formulation would not be expected to cause skin sensitization, based on tests of the components or similar formulations. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Not expected to be harmful to aquatic organisms. MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may Page 545 of 871 Page 545 of 871 Page 545 of 871 Page 545 of 871 ---PAGE BREAK--- Product Name: MOBIL RARUS 427 Revision Date: 16 Mar 2015 Page 8 of 10 reduce the bioconcentration or limit bioavailability. SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. Protect the environment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents, brake fluids or coolants. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (DOT): Not Regulated for Land Transport LAND (TDG): Not Regulated for Land Transport SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code Marine Pollutant: No AIR (IATA): Not Regulated for Air Transport Page 546 of 871 Page 546 of 871 Page 546 of 871 Page 546 of 871 ---PAGE BREAK--- Product Name: MOBIL RARUS 427 Revision Date: 16 Mar 2015 Page 9 of 10 SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with OSHA HazCom 2012, 29 CFR 1910.1200. Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, IECSC, KECI, TSCA Special Cases: Inventory Status ENCS Restrictions Apply EPCRA SECTION 302: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK 5 = TSCA 4 10 = CA P65 CARC 15 = MI 293 Code key: CARC=Carcinogen; REPRO=Reproductive SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only): H315: Causes skin irritation; Skin Corr/Irritation, Cat 2 H317: May cause allergic skin reaction; Skin Sensitization, Cat 1 H401: Toxic to aquatic life; Acute Env Tox, Cat 2 H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Updates made in accordance with implementation of GHS requirements. Page 547 of 871 Page 547 of 871 Page 547 of 871 Page 547 of 871 ---PAGE BREAK--- Product Name: MOBIL RARUS 427 Revision Date: 16 Mar 2015 Page 10 of 10 The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re- publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A DGN: 2008423XUS (1013559) Copyright 2002 Exxon Mobil Corporation, All rights reserved Page 548 of 871 Page 548 of 871 Page 548 of 871 Page 548 of 871 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 29 Sep 2015 Page 1 of 10 SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: MOBILGREASE XHP 222 SPECIAL Product Description: Base Oil and Additives Product Code: 2015A0202531, 530550-00, 97G870 Intended Use: Grease COMPANY IDENTIFICATION Supplier: EXXON MOBIL CORPORATION 22777 Springwoods Village Parkway Spring, TX. 77253 USA 24 Hour Health Emergency [PHONE REDACTED] Transportation Emergency Phone [PHONE REDACTED] or [PHONE REDACTED] CHEMTREC Product Technical Information [PHONE REDACTED] MSDS Internet Address http://www.exxon.com, http://www.mobil.com SECTION 2 HAZARDS IDENTIFICATION This material is not hazardous according to regulatory guidelines (see (M)SDS Section 15). Other hazard information: HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200. PHYSICAL / CHEMICAL HAZARDS No significant hazards. HEALTH HAZARDS High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, or respiratory irritation. ENVIRONMENTAL HAZARDS No significant hazards. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary Page 549 of 871 Page 549 of 871 Page 549 of 871 Page 549 of 871 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 29 Sep 2015 Page 2 of 10 from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS This material is defined as a mixture. Hazardous Substance(s) or Complex Substance(s) required for disclosure Name CAS# Concentration* GHS Hazard Codes BENZENAMINE, N-PHENYL-, REACTION PRODUCTS WITH 68411-46-1 1 - < 5% H402, H412 ZINC DITHIOPHOSPHATE 68649-42-3 1 - < 2.5% H315, H318, H401, H411 * All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. As per paragraph of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and exact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact percentage composition will be provided to health professionals, employees, or designated representatives in accordance with applicable provisions of paragraph SECTION 4 FIRST AID MEASURES INHALATION Under normal conditions of intended use, this material is not expected to be an inhalation hazard. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, Page 550 of 871 Page 550 of 871 Page 550 of 871 Page 550 of 871 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 29 Sep 2015 Page 3 of 10 sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Aldehydes, Incomplete combustion products, Oxides of carbon, Smoke, Fume, Sulfur oxides FLAMMABILITY PROPERTIES Flash Point [Method]: >204°C (400°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802. PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended. SPILL MANAGEMENT Land Spill: Scrape up spilled material with shovels into a suitable container for recycle or disposal. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Skim from surface. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Prevent entry into waterways, sewers, basements or confined areas. Page 551 of 871 Page 551 of 871 Page 551 of 871 Page 551 of 871 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 29 Sep 2015 Page 4 of 10 SECTION 7 HANDLING AND STORAGE HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator. STORAGE Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION NOTE: Limits/standards shown for guidance only. Follow applicable regulations. No biological limits allocated. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Page 552 of 871 Page 552 of 871 Page 552 of 871 Page 552 of 871 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 29 Sep 2015 Page 5 of 10 Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Physical State: Solid Form: Semi-fluid Color: Dark Gray Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 0.914 Flammability (Solid, Gas): N/A Flash Point [Method]: >204°C (400°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) [Estimated] Decomposition Temperature: N/D Vapor Density (Air = N/D Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C [Estimated] Evaporation Rate (n-butyl acetate = N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 [Estimated] Solubility in Water: Negligible Viscosity: 220 cSt (220 mm2/sec) at 40 °C I >16 cSt (16 mm2/sec) at 100°C Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: >260°C (500°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt NOTE: Most physical properties above are for the oil component in the material. Page 553 of 871 Page 553 of 871 Page 553 of 871 Page 553 of 871 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 29 Sep 2015 Page 6 of 10 SECTION 10 STABILITY AND REACTIVITY REACTIVITY: See sub-sections below. STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS Hazard Class Conclusion / Remarks Inhalation Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Ingestion Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Corrosion/Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on assessment of the components. Eye Serious Eye Damage/Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components. Sensitization Respiratory Sensitization: No end point data for material. Not expected to be a respiratory sensitizer. Skin Sensitization: No end point data for material. Not expected to be a skin sensitizer. Based on assessment of the components. Aspiration: Data available. Not expected to be an aspiration hazard. Based on physico-chemical properties of the material. Germ Cell Mutagenicity: No end point data for material. Not expected to be a germ cell mutagen. Based on assessment of the components. Carcinogenicity: No end point data for material. Not expected to cause cancer. Based on assessment of the components. Reproductive Toxicity: No end point data for material. Not expected to be a reproductive toxicant. Based on assessment of the components. Lactation: No end point data for material. Not expected to cause harm to breast-fed children. Specific Target Organ Toxicity (STOT) Single Exposure: No end point data for material. Not expected to cause organ damage from a single exposure. Repeated Exposure: No end point data for Not expected to cause organ damage from prolonged or repeated Page 554 of 871 Page 554 of 871 Page 554 of 871 Page 554 of 871 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 29 Sep 2015 Page 7 of 10 material. exposure. Based on assessment of the components. OTHER INFORMATION Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. Middle distillates: Carcinogenic in animal tests. Lifetime skin painting tests produced tumors, but the mechanism is due to repeated cycles of skin damage and restorative hyperplasia. This mechanism is considered unlikely in humans where such prolonged skin irritation would not be tolerated. Did not cause mutations In Vitro. Inhalation of vapors did not result in reproductive or developmental effects in laboratory animals. Inhalation of high concentrations in animals resulted in respiratory tract irritation, lung changes and some reduction in lung function. Non-sensitizing in test animals. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Not expected to be harmful to aquatic organisms. MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. Page 555 of 871 Page 555 of 871 Page 555 of 871 Page 555 of 871 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 29 Sep 2015 Page 8 of 10 SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (DOT): Not Regulated for Land Transport LAND (TDG): Not Regulated for Land Transport SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code Marine Pollutant: No AIR (IATA): Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with OSHA HazCom 2012, 29 CFR 1910.1200. Listed or exempt from listing/notification on the following chemical inventories: AICS, ENCS, IECSC, KECI, PICCS, TSCA Special Cases: Inventory Status Page 556 of 871 Page 556 of 871 Page 556 of 871 Page 556 of 871 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 29 Sep 2015 Page 9 of 10 NDSL Restrictions Apply EPCRA SECTION 302: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: Chemical Name CAS Number Typical Value ZINC DITHIOPHOSPHATE 68649-42-3 1 - < 2.5% The following ingredients are cited on the lists below: Chemical Name CAS Number List Citations NAPHTHENIC ACIDS, ZINC SALTS 12001-85-3 15 ZINC DITHIOPHOSPHATE 68649-42-3 13, 15, 17, 19 ZINC NEODECANOATE 27253-29-8 15 --REGULATORY LISTS SEARCHED-- 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK 5 = TSCA 4 10 = CA P65 CARC 15 = MI 293 Code key: CARC=Carcinogen; REPRO=Reproductive SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only): H315: Causes skin irritation; Skin Corr/Irritation, Cat 2 H318: Causes serious eye damage; Serious Eye Damage/Irr, Cat 1 H401: Toxic to aquatic life; Acute Env Tox, Cat 2 H402: Harmful to aquatic life; Acute Env Tox, Cat 3 H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2 H412: Harmful to aquatic life with long lasting effects; Chronic Env Tox, Cat 3 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 01: Company Mailing Address information was modified. Section 05: Hazardous Combustion Products information was modified. Page 557 of 871 Page 557 of 871 Page 557 of 871 Page 557 of 871 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 29 Sep 2015 Page 10 of 10 Section 14: Marine Pollutant information was modified. Section 09: Flammability (Solid, Gas) information was added. Section 16: Revision Information - Implementation of GHS requirements phrase. information was deleted. The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A DGN: 2006163XUS (550276) Copyright 2002 Exxon Mobil Corporation, All rights reserved Page 558 of 871 Page 558 of 871 Page 558 of 871 Page 558 of 871 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 17 Mar 2015 Page 1 of 10 SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: MOBILGREASE XHP 222 SPECIAL Product Description: Base Oil and Additives Product Code: 2015A0202531, 530550-00, 97G870 Intended Use: Grease COMPANY IDENTIFICATION Supplier: EXXON MOBIL CORPORATION 22777 Springwoods Village Parkway Spring, TX. 77389 USA 24 Hour Health Emergency [PHONE REDACTED] Transportation Emergency Phone [PHONE REDACTED] or [PHONE REDACTED] CHEMTREC Product Technical Information [PHONE REDACTED] MSDS Internet Address http://www.exxon.com, http://www.mobil.com SECTION 2 HAZARDS IDENTIFICATION This material is not hazardous according to regulatory guidelines (see (M)SDS Section 15). Other hazard information: HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200. PHYSICAL / CHEMICAL HAZARDS No significant hazards. HEALTH HAZARDS High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, or respiratory irritation. ENVIRONMENTAL HAZARDS No significant hazards. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. Page 559 of 871 Page 559 of 871 Page 559 of 871 Page 559 of 871 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 17 Mar 2015 Page 2 of 10 SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS This material is defined as a mixture. Hazardous Substance(s) or Complex Substance(s) required for disclosure Name CAS# Concentration* GHS Hazard Codes BENZENAMINE, N-PHENYL-, REACTION PRODUCTS WITH 68411-46-1 1 - < 5% H402, H412 ZINC DITHIOPHOSPHATE 68649-42-3 1 - < 2.5% H315, H318, H401, H411 * All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. As per paragraph of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and exact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact percentage composition will be provided to health professionals, employees, or designated representatives in accordance with applicable provisions of paragraph SECTION 4 FIRST AID MEASURES INHALATION Under normal conditions of intended use, this material is not expected to be an inhalation hazard. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed Page 560 of 871 Page 560 of 871 Page 560 of 871 Page 560 of 871 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 17 Mar 2015 Page 3 of 10 spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Aldehydes, Oxides of carbon, Smoke, Fume, Sulfur oxides, Incomplete combustion products FLAMMABILITY PROPERTIES Flash Point [Method]: >204°C (400°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802. PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended. SPILL MANAGEMENT Land Spill: Scrape up spilled material with shovels into a suitable container for recycle or disposal. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Skim from surface. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE Page 561 of 871 Page 561 of 871 Page 561 of 871 Page 561 of 871 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 17 Mar 2015 Page 4 of 10 HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator. STORAGE Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION NOTE: Limits/standards shown for guidance only. Follow applicable regulations. No biological limits allocated. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or Page 562 of 871 Page 562 of 871 Page 562 of 871 Page 562 of 871 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 17 Mar 2015 Page 5 of 10 manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Physical State: Solid Form: Semi-fluid Color: Dark Gray Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 0.914 Flammability (Solid, Gas): Flash Point [Method]: >204°C (400°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) [Estimated] Decomposition Temperature: N/D Vapor Density (Air = N/D Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C [Estimated] Evaporation Rate (n-butyl acetate = N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 [Estimated] Solubility in Water: Negligible Viscosity: 220 cSt (220 mm2/sec) at 40 °C I >16 cSt (16 mm2/sec) at 100°C Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: >260°C (500°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt NOTE: Most physical properties above are for the oil component in the material. Page 563 of 871 Page 563 of 871 Page 563 of 871 Page 563 of 871 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 17 Mar 2015 Page 6 of 10 SECTION 10 STABILITY AND REACTIVITY REACTIVITY: See sub-sections below. STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS Hazard Class Conclusion / Remarks Inhalation Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Ingestion Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Corrosion/Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on assessment of the components. Eye Serious Eye Damage/Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components. Sensitization Respiratory Sensitization: No end point data for material. Not expected to be a respiratory sensitizer. Skin Sensitization: No end point data for material. Not expected to be a skin sensitizer. Based on assessment of the components. Aspiration: Data available. Not expected to be an aspiration hazard. Based on physico-chemical properties of the material. Germ Cell Mutagenicity: No end point data for material. Not expected to be a germ cell mutagen. Based on assessment of the components. Carcinogenicity: No end point data for material. Not expected to cause cancer. Based on assessment of the components. Reproductive Toxicity: No end point data for material. Not expected to be a reproductive toxicant. Based on assessment of the components. Lactation: No end point data for material. Not expected to cause harm to breast-fed children. Specific Target Organ Toxicity (STOT) Single Exposure: No end point data for material. Not expected to cause organ damage from a single exposure. Repeated Exposure: No end point data for material. Not expected to cause organ damage from prolonged or repeated exposure. Based on assessment of the components. Page 564 of 871 Page 564 of 871 Page 564 of 871 Page 564 of 871 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 17 Mar 2015 Page 7 of 10 OTHER INFORMATION Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. Middle distillates: Carcinogenic in animal tests. Lifetime skin painting tests produced tumors, but the mechanism is due to repeated cycles of skin damage and restorative hyperplasia. This mechanism is considered unlikely in humans where such prolonged skin irritation would not be tolerated. Did not cause mutations In Vitro. Inhalation of vapors did not result in reproductive or developmental effects in laboratory animals. Inhalation of high concentrations in animals resulted in respiratory tract irritation, lung changes and some reduction in lung function. Non-sensitizing in test animals. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Not expected to be harmful to aquatic organisms. MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. SECTION 13 DISPOSAL CONSIDERATIONS Page 565 of 871 Page 565 of 871 Page 565 of 871 Page 565 of 871 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 17 Mar 2015 Page 8 of 10 Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (DOT): Not Regulated for Land Transport LAND (TDG): Not Regulated for Land Transport SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code Marine Pollutant: No AIR (IATA): Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with OSHA HazCom 2012, 29 CFR 1910.1200. Listed or exempt from listing/notification on the following chemical inventories: AICS, ENCS, IECSC, KECI, PICCS, TSCA Special Cases: Inventory Status Page 566 of 871 Page 566 of 871 Page 566 of 871 Page 566 of 871 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 17 Mar 2015 Page 9 of 10 NDSL Restrictions Apply EPCRA SECTION 302: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: Chemical Name CAS Number Typical Value ZINC DITHIOPHOSPHATE 68649-42-3 1 - < 2.5% The following ingredients are cited on the lists below: Chemical Name CAS Number List Citations NAPHTHENIC ACIDS, ZINC SALTS 12001-85-3 15 ZINC DITHIOPHOSPHATE 68649-42-3 13, 15, 17, 19 ZINC NEODECANOATE 27253-29-8 15 --REGULATORY LISTS SEARCHED-- 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK 5 = TSCA 4 10 = CA P65 CARC 15 = MI 293 Code key: CARC=Carcinogen; REPRO=Reproductive SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only): H315: Causes skin irritation; Skin Corr/Irritation, Cat 2 H318: Causes serious eye damage; Serious Eye Damage/Irr, Cat 1 H401: Toxic to aquatic life; Acute Env Tox, Cat 2 H402: Harmful to aquatic life; Acute Env Tox, Cat 3 H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2 H412: Harmful to aquatic life with long lasting effects; Chronic Env Tox, Cat 3 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Updates made in accordance with implementation of GHS requirements. Page 567 of 871 Page 567 of 871 Page 567 of 871 Page 567 of 871 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 17 Mar 2015 Page 10 of 10 The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A DGN: 2006163XUS (550276) Copyright 2002 Exxon Mobil Corporation, All rights reserved Page 568 of 871 Page 568 of 871 Page 568 of 871 Page 568 of 871 ---PAGE BREAK--- 1. PRODUCT AND COMPANY IDENTIFICATION Product Name Mothers Mag & Aluminum Polish Product Code(s) 05100, 05101, 05102, 05155 2. HAZARDS IDENTIFICATION Potential Health Effects Acute Toxicity Eyes May cause irritation. Skin May cause irritation. May cause sensitization by skin contact. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. Inhalation May cause central nervous system depression with nausea, headache, dizziness, vomiting, and incoordination. Page 1 / 8 Emergency Overview May cause skin irritation and/or dermatitis May produce an allergic reaction May cause sensitization by skin contact May cause drowsiness and dizziness. PPE Transport Symbol NFPA Supplier Address MOTHERS POLISHES WAXES CLEANERS 5456 Industrial Drive Huntington Beach, CA 92649 TEL: [PHONE REDACTED] FAX: [PHONE REDACTED] Material Safety Data Sheet HMIS Issuing Date 03-Apr-2007 Revision Date WARNING! Revision Number 0 Odor Pine Appearance White Physical State Paste. Page 569 of 871 Page 569 of 871 Page 569 of 871 Page 569 of 871 ---PAGE BREAK--- Ingestion May be harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. May cause additional affects as listed under "Inhalation". Potential for aspiration if swallowed. Chronic Effects Avoid repeated exposure. Repeated contact may cause allergic reactions in very susceptible persons. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Aggravated Medical Conditions Allergies. Skin disorders. Respiratory disorders. Central nervous system. Preexisting eye disorders. Interactions with Other Chemicals Irritants. Sensitizers. Epoxies. Use of alcoholic beverages may enhance toxic effects. Environmental Hazard See Section 12 for additional Ecological information 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Solvent naphtha (petroleum), medium aliphatic 64742-88-7 10-30 Petroleum distillates, hydrotreated light 64742-47-8 5-10 Triethanolamine 102-71-6 1-5 Hexylene glycol 107-41-5 1-5 Diethylene glycol monoethyl ether 111-90-0 0.1-1 5-Chloro-2-methyl-3-isothiazolone 26172-55-4 0.1-1 Alcohols, C9-11-iso-, C10-rich, ethoxylated 78330-20-8 0.1-1 Sodium hydroxide 1310-73-2 0.1-1 4. FIRST AID MEASURES General Advice If persist, call a physician. Eye Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Keep eye wide open while rinsing. If persist, call a physician. Skin Contact Wash off with warm water and soap. If skin irritation persists, call a physician. Inhalation Move to fresh air. If persist, call a physician. If breathing is irregular or stopped, administer artificial respiration. Call a physician immediately. Ingestion Rinse mouth. Drink plenty of water. Never give anything by mouth to an unconscious person. Do not induce vomiting. Consult a physician. Notes to Physician May cause sensitization of susceptible persons. Use of epinephrine may be indicated. 5. FIRE-FIGHTING MEASURES Flammable Properties Not flammable Flash Point Not applicable Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment Page 2 / 8 Revision Date WPS-MPWC-05100 - Mothers Mag & Aluminum Polish Page 570 of 871 Page 570 of 871 Page 570 of 871 Page 570 of 871 ---PAGE BREAK--- Explosion Data Sensitivity to mechanical impact None Sensitivity to static discharge None Specific Hazards Arising from the Chemical Thermal decomposition can lead to release of irritating gases and vapors. In the event of fire and/or explosion do not breathe fumes. May cause sensitization by inhalation and skin contact. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Use personal protective equipment. Avoid contact with the skin and the eyes. Methods for Containment Prevent further leakage or spillage if safe to do so Methods for Cleaning Up Cover liquid spill with sand, earth or other noncombustible absorbent material. Cover powder spill with plastic sheet or tarp to minimize spreading. Pick up and transfer to properly labeled containers. 7. HANDLING AND STORAGE Handling Handle in accordance with good industrial hygiene and safety practice. Wear personal protective equipment. Avoid breathing vapors or mists. Avoid contact with skin and eyes. Storage Keep container closed in a dry and well-ventilated place. Keep out of the reach of children. Keep containers closed in a cool, well-ventilated place. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Triethanolamine TWA: 5 mg/m3 Hexylene glycol Ceiling: 25 ppm Ceiling: 25 ppm Ceiling: 125 mg/m3 Sodium hydroxide Ceiling: 2 mg/m3 Ceiling: 2 mg/m3 TWA: 2 mg/m3 10 mg/m3 NIOSH IDLH: Immediately Dangerous to Life or Health Engineering Measures Showers Eyewash stations Ventilation systems Personal Protective Equipment Eye/Face Protection fitting safety goggles. Skin and Body protection Lightweight protective clothing. Page 3 / 8 Stability 0 WPS-MPWC-05100 - Mothers Mag & Aluminum Polish Physical and Chemical Hazards - HMIS NFPA Health Hazard 2 Revision Date Flammability 0 Stability 0 Personal Precautions - Health Hazard 2 Flammability 0 Page 571 of 871 Page 571 of 871 Page 571 of 871 Page 571 of 871 ---PAGE BREAK--- Respiratory Protection None required under normal usage. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions Conditions to Avoid None known based on information supplied Incompatible Products None known based on information supplied Hazardous Decomposition Products None under normal use, Thermal decomposition can lead to release of irritating gases and vapors. Hazardous Polymerization Hazardous polymerization does not occur 11. TOXICOLOGICAL INFORMATION Acute Toxicity Product Information No acute toxicity information is available for this product. Component Information Page 4 / 8 Not applicable Partition Coefficient octanol/water) No data available Odor Pine Autoignition Temperature Not applicable Decomposition Temperature No data available Revision Date Boiling Point/Range No data available Odor Threshold No information available Melting Point/Range No data available Flammability Limits in Air No data available Physical State Paste Explosion Limits No data available Appearance Specific Gravity No data available pH Solubility No data available 7.0-7.6 Evaporation Rate No data available White Vapor Pressure No data available WPS-MPWC-05100 - Mothers Mag & Aluminum Polish Vapor Density No data available VOC Content <30% Flash Point Page 572 of 871 Page 572 of 871 Page 572 of 871 Page 572 of 871 ---PAGE BREAK--- Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Solvent naphtha (petroleum), medium aliphatic 5000 mg/kg ( Rat ) 3000 mg/kg ( Rabbit ) 5.28 mg/L ( Rat ) 4 h Petroleum distillates, hydrotreated light 5000 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) 5.2 mg/L ( Rat ) 4 h Triethanolamine 4190 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) Hexylene glycol 3692 mg/kg ( Rat ) 8560 µL/kg ( Rabbit ) 310 mg/m3 ( Rat ) 1 h Diethylene glycol monoethyl ether 1920 mg/kg ( Rat ) 4200 µL/kg ( Rabbit ) 5-Chloro-2-methyl-3-isothiazolone 481 mg/kg ( Rat ) 1008 mg/kg ( Rat ) 1.23 mg/L ( Rat ) 4 h Sodium hydroxide 1350 mg/kg ( Rabbit ) Subchronic Toxicity (28 days) Chronic Toxicity Chronic Toxicity Avoid repeated exposure. Repeated contact may cause allergic reactions in very susceptible persons. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Carcinogenicity There are no known carcinogenic chemicals in this product Mutagenicity Reproductive Toxicity This product does not contain any known or suspected reproductive hazards Target Organ Effects Central nervous system (CNS), Eyes, Respiratory system, Skin. Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors 12. ECOLOGICAL INFORMATION Ecotoxicity Ecotoxicity effects. Chemical Name Toxicity to Algae Toxicity to Fish Microtox Daphnia Magna (Water Flea) Solvent naphtha (petroleum), medium aliphatic EC50 = 450 mg/L 96 h EC50 > 100 mg/L 48 h Petroleum distillates, hydrotreated light LC50 = 4720 mg/L 96 h Triethanolamine EC50 = 169 mg/L 96 h EC50 = 216 mg/L 72 h EC50 > 10000 mg/L 30 min EC50 = 1386 mg/L 24 h Hexylene glycol EC50 = 3038 mg/L 5 min EC50 = 3200 mg/L 48 h Diethylene glycol monoethyl ether LC50 3940 - 4670 mg/L 48 h EC50 = 4026 mg/L 48 h 5-Chloro-2-methyl-3- isothiazolone EC50 = 0.31 mg/L 120 h EC50 = 5.7 mg/L 16 h EC50 = 4.71 mg/L 48 h Chemical Name Log Pow Triethanolamine -2.53 Hexylene glycol 0.14 Diethylene glycol monoethyl ether -0.8 13. DISPOSAL CONSIDERATIONS Waste Disposal Method This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). Page 5 / 8 Revision Date WPS-MPWC-05100 - Mothers Mag & Aluminum Polish Page 573 of 871 Page 573 of 871 Page 573 of 871 Page 573 of 871 ---PAGE BREAK--- Contaminated Packaging Dispose of in accordance with local regulations Chemical Name California Hazardous Waste Status Sodium hydroxide Toxic; Corrosive 14. TRANSPORT INFORMATION DOT Not regulated TDG Not regulated MEX Not regulated ICAO Not regulated IATA Not regulated IMDG/IMO Not regulated RID Not regulated ADR Not regulated ADN Not regulated 15. REGULATORY INFORMATION International Inventories DSL Complies EINECS/ELINCS Does not Comply ENCS Does not Comply CHINA Complies KECL Complies PICCS Complies AICS Complies U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name CAS-No Weight % SARA 313 - Threshold Values Diethylene glycol monoethyl ether 111-90-0 0.1-1 1.0 Page 6 / 8 WPS-MPWC-05100 - Mothers Mag & Aluminum Polish Revision Date Page 574 of 871 Page 574 of 871 Page 574 of 871 Page 574 of 871 ---PAGE BREAK--- SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Sodium hydroxide 1000 lb X CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs Sodium hydroxide 1000 lb U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name Massachusetts New Jersey Illinois Rhode Island Sodium hydroxide X X X X Hexylene glycol X X X X Diethylene glycol monoethyl ether X X X International Regulations Chemical Name Carcinogen Status Exposure Limits Sodium hydroxide Mexico: Ceiling= 2 mg/m3 Hexylene glycol Mexico: Ceiling= 25 ppm Mexico: Ceiling= 125 mg/m3 Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class D2B Toxic materials Page 7 / 8 WPS-MPWC-05100 - Mothers Mag & Aluminum Polish Revision Date Page 575 of 871 Page 575 of 871 Page 575 of 871 Page 575 of 871 ---PAGE BREAK--- 16. OTHER INFORMATION Issuing Date 03-Apr-2007 Revision Date Revision Note No information available Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of MSDS Page 8 / 8 Revision Date WPS-MPWC-05100 - Mothers Mag & Aluminum Polish Page 576 of 871 Page 576 of 871 Page 576 of 871 Page 576 of 871 ---PAGE BREAK--- Safety Data Sheet Revision Number: 007.0 Issue date: 08/29/2014 IDH number: 241237 Product name: MultiMist(TM) Penetrating Thread Locker Page 1 of 6 1. PRODUCT AND COMPANY IDENTIFICATION Product name: MultiMist(TM) Penetrating Thread Locker IDH number: 241237 Product type: PrimerAnaerobic Sealant Item number: 32905 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-[PHONE REDACTED] (toll free) or 1-[PHONE REDACTED] TRANSPORT EMERGENCY Phone: CHEMTREC 1-[PHONE REDACTED] (toll free) or 1-[PHONE REDACTED] Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING: CAUSES SKIN AND EYE IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. HAZARD CLASS HAZARD CATEGORY SKIN IRRITATION 2 EYE IRRITATION 2B SKIN SENSITIZATION 1 PICTOGRAM(S) Precautionary Statements Prevention: Avoid breathing vapors, mist, or spray. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves. Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. If skin irritation or rash occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. Storage: Not prescribed Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* dimethacrylate Proprietary 60 - 100 Page 577 of 871 Page 577 of 871 Page 577 of 871 Page 577 of 871 ---PAGE BREAK--- IDH number: 241237 Product name: MultiMist(TM) Penetrating Thread Locker Page 2 of 6 Cumene hydroperoxide 80-15-9 1 - 5 Saccharin 81-07-2 1 - 5 Cumene 98-82-8 0.1 - 1 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention. Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. Wash clothing before reuse. Get medical attention. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention. See Section 11. 5. FIRE FIGHTING MEASURES Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide. Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. In case of fire, keep containers cool with water spray. Unusual fire or explosion hazards: Uncontrolled polymerization may occur at high temperatures resulting in explosions or rupture of storage containers. Hazardous combustion products: Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic vapours. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Do not allow product to enter sewer or waterways. Clean-up methods: Remove all sources of ignition. Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean- up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Scrape up as much material as possible. Store in a partly filled, closed container until disposal. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up. Page 578 of 871 Page 578 of 871 Page 578 of 871 Page 578 of 871 ---PAGE BREAK--- IDH number: 241237 Product name: MultiMist(TM) Penetrating Thread Locker Page 3 of 6 7. HANDLING AND STORAGE Handling: Use only with adequate ventilation. Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Keep container closed. Refer to Section 8. Storage: For safe storage, store at or below 38 °C (100.4 Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container closed until ready for use. For information on product shelf life contact Henkel Customer Service at (800) 243-4874. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER dimethacrylate None None None None Cumene hydroperoxide None None 1 ppm (6 mg/m3) TWA (SKIN) None Saccharin None None None None Cumene 50 ppm TWA 50 ppm (245 mg/m3) PEL (SKIN) None None Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available. Skin protection: Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. Neoprene gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Green Odor: Mild Odor threshold: Not available. pH: Not applicable Vapor pressure: < 5 mm hg (27.0 °C (80.6 Boiling point/range: > 149.0 °C 300.2 Melting point/ range: Not available. Specific gravity: 1.07 at 26.70 °C (80.06 Vapor density: Not available. Flash point: > 93.3 °C 199.94 Tagliabue closed cup Flammable/Explosive limits - lower: Not available. Flammable/Explosive limits - upper: Not available. Autoignition temperature: Not available. Evaporation rate: Not available. Solubility in water: Slight Partition coefficient (n-octanol/water): Not available. VOC content: 2.27 22.1 g/l Viscosity: Not available. Decomposition temperature: Not available. Page 579 of 871 Page 579 of 871 Page 579 of 871 Page 579 of 871 ---PAGE BREAK--- IDH number: 241237 Product name: MultiMist(TM) Penetrating Thread Locker Page 4 of 6 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions of storage and use. Hazardous reactions: None under normal processing. Polymerization may occur at elevated temperature or in the presence of incompatible materials. Hazardous decomposition products: Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic vapours. Phenolics. Incompatible materials: Copper. Iron. Rust. Aluminum. Zinc. Strong oxidizing agents. Reducing agents. Oxygen scavengers. Strong acids. Strong alkalis. Reactivity: Not available. Conditions to avoid: Elevated temperatures. Heat, flames, sparks and other sources of ignition. Store away from incompatible materials. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion Potential Health Inhalation: Inhalation of vapors or mists of the product may be irritating to the respiratory system. Skin contact: Causes skin irritation. May cause allergic skin reaction. Eye contact: Causes eye irritation. Ingestion: May cause gastrointestinal tract irritation if swallowed. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects dimethacrylate None Allergen, Irritant Cumene hydroperoxide None Allergen, Central nervous system, Corrosive, Irritant, Mutagen Saccharin None No Target Organs Cumene Oral LD50 (RAT) = 2.91 g/kg Oral LD50 (RAT) = 1,400 mg/kg Inhalation LC50 (RAT, 4 h) = 8000 ppm Central nervous system, Irritant, Lung Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) dimethacrylate No No No Cumene hydroperoxide No No No Saccharin No No No Cumene No Group 2B No 12. ECOLOGICAL INFORMATION Ecological information: Not available. Page 580 of 871 Page 580 of 871 Page 580 of 871 Page 580 of 871 ---PAGE BREAK--- IDH number: 241237 Product name: MultiMist(TM) Penetrating Thread Locker Page 5 of 6 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. Hazardous waste number: Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: RQ, Environmentally hazardous substances, liquid, n.o.s. Hazard class or division: 9 Identification number: UN 3082 Packing group: III DOT Hazardous Substance(s): International Air Transportation (ICAO/IATA) Proper shipping name: Environmentally hazardous substance, liquid, n.o.s. Hazard class or division: 9 Identification number: UN 3082 Packing group: III Water Transportation (IMO/IMDG) Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard class or division: 9 Identification number: UN 3082 Packing group: III 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 Export Notification: None above reporting de minimis CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Immediate Health, Delayed Health CERCLA/SARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Cumene hydroperoxide (CAS# 80-15-9). Saccharin (CAS# 81-07-2). CERCLA Reportable quantity: Cumene hydroperoxide (CAS# 80-15-9) 10 lbs. (4.54 kg) California Proposition 65: This product contains a chemical known in the State of California to cause cancer. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Prepared by: Sheila Gines, Regulatory Affairs Specialist Issue date: 08/29/2014 Page 581 of 871 Page 581 of 871 Page 581 of 871 Page 581 of 871 ---PAGE BREAK--- IDH number: 241237 Product name: MultiMist(TM) Penetrating Thread Locker Page 6 of 6 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 582 of 871 Page 582 of 871 Page 582 of 871 Page 582 of 871 ---PAGE BREAK--- Material Safety Data Sheet Nail Hole & Crack Repair ©AKONA MANUFACTURING LLC • June 2008 Version 1.0 2025 Centre Point Blvd, Suite 300, Mendota Heights, MN 55120 I P [PHONE REDACTED] I F [PHONE REDACTED] I www.akonallc.com 1 Product Types: Liquid Ready-Mixed Repair Products AKONA Product Name: Nail Hole & Crack Repair Hazardous Components CAS No. Typical Concentration Propylene Glycol 57-55-6 Less than 2% Calcium Carbonate 47t-34-1 Less than 20% Glass Bubbles 65997-17-3 Less than 15% Appearance and Odor: White Paste Boiling Point: 212° F Vapor Pressure: 17.5mm Vapor Density: Lighter than air Solubility in Water: 68% Flash Point: NA Flammable Limits: Non-Flammable Fire Extinguishing Media: NA Special Fire Fighting Procedures: NA Unusual Fire and Explosion Hazards: NA Stability: Stable. Incompatibility: None. Hazardous Polymerization: None. SECTION I: PRODUCT IDENTIFICATION Akona Manufacturing, LLC. 2025 Centre Pointe Boulevard, Suite 300 Mendota Heights, MN 55120-1221 Emergency Telephone Number: [PHONE REDACTED] Information Telephone Number: [PHONE REDACTED] SECTION II: HAZARDOUS INGREDIENTS/IDENTITY INFORMATION SECTION III: PHYSICAL/CHEMICAL CHARACTERISTICS SECTION IV: FIRE AND EXPLOSION HAZARD DATA Revision Date: July 2008 SECTION V: REACTIVITY DATA Page 583 of 871 Page 583 of 871 Page 583 of 871 Page 583 of 871 ---PAGE BREAK--- Material Safety Data Sheet Nail Hole & Crack Repair ©AKONA MANUFACTURING LLC • June 2008 Version 1.0 2025 Centre Point Blvd, Suite 300, Mendota Heights, MN 55120 I P [PHONE REDACTED] I F [PHONE REDACTED] I www.akonallc.com 2 Route(s) of Entry: Inhalation? Yes Skin? Yes Ingestion? Yes HEALTH EFFECTS FROM OVEREXPOSURE Inhalation of vapor or mist can cause the following: headache - nausea - irritation of nose, throat, and lungs Carcinogenicity: t classified as a carcinogen NTP? no IARC Monographs? no OSHA Regulated? no Eye Contact: Direct contact with material can cause irritation and possible corneal injury. Skin Contact: Prolonged or repeated skin contact can cause slight irritation. FIRST AID Skin: Thoroughly wash affected area with soap and water. Remove contaminated clothing. Eye Contact: Flush with large amounts of water, lifting the upper and lower lids occasionally. Get medical atten- tion. Ingestion: If swallowed, give two glasses of water. If large amounts are ingested, induce vomiting with Ipecac syrup or by placing finger at the back of the throat. Never give anything by mouth to an unconscious person. Get medical attention. Inhalation: Remove to fresh air if effects occur. Consult physician. AVOID SKIN AND EYE CONTACT AND AVOID BREATHING VAPORS. Steps To Be Taken In Case Material Is Released or Spilled: Contain spills immediately with inert material (sand, earth, absorbent pigment). Transfer liquid and solid diking to separate containers for recovery or disposal. WASTE DISPOSAL: In accordance with Federal, State and Local regulations PERSONAL PROTECTIVE EQUIPMENT Eye protection: Use chemical splash goggles (ANSI Z87.1 or approved equivalent) Hand protection: Neoprene gloves are recommended. Gloves of other chemically resistant materials may not pro- vide adequate protection. Respiratory Protection: Use NIOSH approve respirator. WASTE DISPOSAL: Local Exhaust: yes Mechanical: yes Special Protection: Clean protective clothing. Impervious gloves. NOTE: The information and recommendations contained herein are based upon data believed to be correct. How- ever, no guarantee or warranty of any kind, express or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by expo- sure to silica contained in our products. Before using any product, read its label. SECTION VI: HEALTH HAZARD DATA SECTION VII: PRECAUTIONS FOR SAFE HANDLING AND USE SECTION VIII: CONTROL MEASURES Page 584 of 871 Page 584 of 871 Page 584 of 871 Page 584 of 871 ---PAGE BREAK--- MSDS No: OTH050E5 Issue Date: 10 June 2005 Page: 1 of 4 MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION Trade Name: OATEY PLUMBER’S PUTTY Product Use: Stainless fixture setting compound. Formula: See SECTION 2 Synonyms: Putty. Firm Name & OATEY CO. 4700 West 160th Street P.O. Box 35906 Cleveland, Mailing Address: Ohio 44135, U.S.A. http://www.oatey.com Oatey Phone Number: (216) 267-7100 or (800) 321-9532 Emergency Phone For Emergency First Aid call 1-[PHONE REDACTED] COLLECT. For Numbers: chemical transportation emergencies ONLY, call Chemtrec at 1-[PHONE REDACTED]. Outside the US: 1-[PHONE REDACTED]. Prepared By: Corporate Director – Safety and Environmental Compliance Preparation Date: June 10, 2005 SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENTS: %wt/wt: CAS NUMBER: ACGIH TLV TWA: OSHA PEL TWA: OTHER: Limestone 60 - 90% 1317-65-3 10 mg/M3 15 mg/M3 None (Total dust) Hydrocarbon oil 10 - 30% 64742-52-5 5 mg/M3 5 mg/M3 None Talc 1 - 5% 14807-96-6 2 mg/M3 2 mg/M3 None Clay 1 – 5% 68953-58-2 10 mg/M3 10 mg/M3 None O SHA Hazard Classification: Not hazardous SECTION 3 HAZARDS IDENTIFICATION Emergency Overview: White putty with a mild petroleum odor. May cause mechanical irritation of the eyes. SECTION 4 FIRST AID MEASURES CALL 1-[PHONE REDACTED] COLLECT Skin: Wash all exposed areas with soap and water. Eyes: As with most foreign materials, should eye contact occur, flush eyes with water until foreign matter is removed. If irritation develops, seek medical attention. Inhalation: Not a likely route of entry. Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water. Call a physician. SECTION 5 FIRE FIGHTING MEASURES Flashpoint / Method: Not applicable Flammability: LEL = Not determined, UEL = Not determined Extinguishing Use dry chemical, CO2, or foam to extinguish fire. Cool fire Media: exposed container with water. Water may be ineffective as an extinguishing agent. Special Fire As appropriate for surrounding fire. Fighting Procedure: Unusual Fire and None Explosion Hazards: Hazardous Combustion will produce toxic and irritating vapors including Decomposition carbon monoxide and carbon dioxide. Products: Page 585 of 871 Page 585 of 871 Page 585 of 871 Page 585 of 871 ---PAGE BREAK--- MSDS No: OTH050E5 Issue Date: 10 June 2005 Page: 2 of 4 SECTION 6 ACCIDENTAL RELEASE MEASURES Spill or Sweep up dried material and dispose of with ordinary trash. Leak Procedures: SECTION 7 HANDLING AND STORAGE Handling: No special handling required. Wash thoroughly after handling. Use good hygiene practices. Storage: Store in a cool, dry area. Other: None. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation: Use with adequate ventilation. Respiratory If putty dries and becomes dusty, wear a dust respirator Protection: during clean-up. Skin Gloves are not normally required. Protection: Eye Safety glasses with side shields are recommended. Protection: Other: Eye wash should be available. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: Not applicable Melting Point: Not applicable Vapor Pressure: Not determined Vapor Density: Not determined Volatile Components: Not determined Solubility In Water: Negligible. pH: Not applicable Specific Gravity: 2.0 @ 20 Degrees C Evaporation Rate: Not applicable Appearance: White Putty Odor: Petroleum odor Will Dissolve In: Not determined Material Is: Putty SECTION 10 STABILITY AND REACTIVITY Stability: Stable. Conditions To Avoid: Avoid heat, flames and other sources of ignition. Hazardous Combustion will produce toxic and irritating vapors Decomposition including carbon monoxide and carbon dioxide. Products: Incompatibility/ Strong oxidizing agents. Materials To Avoid: Hazardous Will not occur. Polymerization: Page 586 of 871 Page 586 of 871 Page 586 of 871 Page 586 of 871 ---PAGE BREAK--- MSDS No: OTH050E5 Issue Date: 10 June 2005 Page: 3 of 4 SECTION 11 TOXICOLOGICAL INFORMATION Inhalation: Not a likely route of entry. Skin: May cause mild irritation. Prolonged and repeated contact may cause dermatitis. Eye: Contact may cause irritation. Ingestion: Swallowing may cause a laxative effect including cramps and diarrhea. Chronic Prolonged or repeated overexposure cause dermatitis. Toxicity: Toxicity Data: Not available Sensitization: None of the components are known to cause sensitization. Carcinogenicity: None of the components are listed as a carcinogen or suspect carcinogen by NTP, IARC or OSHA. Mutagenicity: None of the components are known to be mutagenic. Reproductive None of the components are known to be toxic to reproduction. Toxicity: Medical None known. Conditions Aggravated By Exposure: SECTION 12 ECOLOGICAL INFORMATION No ecotoxicological information known. VOC This product has very low VOC level. Information: SECTION 13 DISPOSAL CONSIDERATIONS Waste Disposal: Dispose in accordance with current local, state and federal regulations. RCRA Hazardous Waste Number: Not a hazardous waste. EPA Hazardous Waste ID Number: Not a hazardous waste. EPA Hazard Waste Class: Not a hazardous waste. SECTION 14 TRANSPORT INFORMATION DOT Less than 1 Liter (0.3 gal) Greater than 1 Liter (0.3 gal) Proper Shipping Name: Not regulated. Not regulated. Hazard Class/Packing Group: None None UN/NA Number: None None Hazard Labels: None None IMDG Proper Shipping Name: Not regulated Hazard Class/Packing Group: None UN Number: None Label: None 2004 North American Emergency Response Guidebook Number: None Page 587 of 871 Page 587 of 871 Page 587 of 871 Page 587 of 871 ---PAGE BREAK--- MSDS No: OTH050E5 Issue Date: 10 June 2005 Page: 4 of 4 SECTION 15 REGULATORY INFORMATION Hazard Category for Section Not hazardous. Section 302 Extremely This product does not contain chemicals regulated Hazardous Substances (TPQ): under SARA Section 302. Section 313 Toxic Chemicals: This product does not contain any chemicals regulated under SARA Title III Section 313. CERCLA 103 Reportable This product does not contain any chemicals regulated Quantity: under CERCLA. California Proposition 65: This product does not contain any chemicals subject To California Proposition 65 regulation. TSCA Inventory: All of the components of this product are listed on the TSCA inventory. Canadian WHIMS Classification: Not a controlled product. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. SECTION 16 OTHER INFORMATION NFPA and HMIS: NFPA Hazard Signal: Health: 0 Flammability: 0 Reactivity: 0 Special: None HMIS Hazard Signal: Health: 0 Flammability: 0 Reactivity: 0 PPE: A Disclaimer: The information herein has been compiled from sources believed to be reliable, up- to-date, and is accurate to the best of our knowledge. However, Oatey cannot give any guarantees regarding information from other sources, and expressly does not make warranties, nor assumes any liability for its use. Page 588 of 871 Page 588 of 871 Page 588 of 871 Page 588 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 23-Jan-2014 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 96215 Product name Old Ceiling Tile Paint White Recommended Use Coating Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known. Principal Routes of Exposure Eyes. Inhalation. Potential health effects Eyes No adverse affects expected. Skin No adverse affects expected. Inhalation Harmful by inhalation. Narcosis. Dizziness. Extreme overexposure may cause. Kidney damage. Lung damage. Liver damage. Cardiac abnormalities. Damage to blood . Repeated and prolonged exposure to solvents may cause brain and nervous system damage. Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Ingestion May be harmful if swallowed. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Propane 74-98-6 10-30 Toluene 108-88-3 10-30 N-Butane 106-97-8 7-13 Light Aliphatic Naptha Solvent 64742-89-8 3-7 Acetone 67-64-1 3-7 Xylene (mix) 1330-20-7 1-5 Mineral Spirits 64742-47-8 1-5 Carbon Black 1333-86-4 0.1-1 Titanium dioxide 13463-67-7 0.1-1 Ethyl benzene 100-41-4 0.1-1 4. FIRST AID MEASURES Eye contact Remove to fresh air. Rinse thoroughly with plenty of water, also under the eyelids. Seek medical attention if irritation persists. Skin contact Remove and wash contaminated clothing before re-use. Wash area thoroughly with soap and water. Ingestion Call a physician or Poison Control Center immediately. Inhalation Move to fresh air. If persist, call a physician. 5. FIRE FIGHTING MEASURES Flash point °C -19 Flash point °F -2 Method Pensky-Martens C.C. Autoignition temperature °C Product is not self-igniting Autoignition temperature °F Flammability Limits in Air) Upper 10.9% Lower 1.5% Suitable extinguishing media Carbon dioxide (CO2). Water spray. Dry powder. Sand. Alcohol-resistant foam . Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Fire and Explosion Hazards Aerosol containers may vent, rupture or burst when heated to temperatures above 120°F. Vapors may form explosive mixture in air between upper and lower explosive limits which can be ignited by many sources, such as pilot lights, open flames, electrical motors and switches. Sensitivity to shock No information available. Page 1 / 4 Emergency Overview Extremely flammable. Harmful by inhalation. Contents under pressure. Page 589 of 871 Page 589 of 871 Page 589 of 871 Page 589 of 871 ---PAGE BREAK--- Sensitivity to static discharge Yes. Take precautionary measures against static discharges. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Personnel should wear appropriate protective equipment. Follow all precautions for handling. Please refer to appropriate sections of MSDS for additional information. Evacuate area of unprotected and unnecessary personnel. Ventilate area to maintain exposure below permissible exposure limits. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. 7. HANDLING AND STORAGE Handling Do not spray on a naked flame or any other incandescent material. Do not smoke. Protect against electrostatic charges. Storage Keep away from open flames, hot surfaces and sources of ignition. Observe pressurized container storage regulations. Consult with local authorities.. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Toluene 200 ppm 300 ppm 20 ppm - N-Butane - - - 1000 ppm Acetone 1000 ppm 2400 mg/m3 - 500 ppm 750 ppm Propane 1000 ppm 1800 mg/m3 - 1000 ppm - Light Aliphatic Naptha Solvent - - - - Mineral Spirits - - - - Ethyl benzene 100 ppm 435 mg/m3 - 20 ppm - Xylene (mix) 100 ppm 435 mg/m3 - 100 ppm 150 ppm Ventilation and Environmental Controls Adequate ventilation should be provided to keep exposure levels below current acceptable exposure limits. Hygiene measures Keep away from food, drink and animal feeding stuffs. Wash hands before breaks and immediately after handling the product. Respiratory protection None necessary under normal conditions. Use NIOSH approved respirator if TLV limit is exceeded. Hand Protection Chemical resistant gloves. Consult glove manufacturer to determine the proper type for a specific operation. Eye protection fitting safety goggles. Skin and body protection None necessary under normal conditions 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color White Odor Aromatic Odor Threshold No information available pH No data available Specific Gravity 0.77-0.85 Vapor pressure 40 PSI @ 70 F Density 0.82 g/cm³ @ 20°C (68°F) Vapor density No data available Evaporation Rate No data available Water solubility No data available VOC Content 53.8%; 561.8 g/L; 4.69 lb/gl Solids content 21.5% MIR value 1.11 Partition Coefficient (n-octanol/water) No data available Boiling point/range °C -44 Boiling point/range °F -47 Melting point/range °C No data available Melting point/range °F No data available Flash point °C -19 Flash point °F -2 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Do not store in temperatures above 120 degrees F. Incompatability None known. Hazardous Decomposition Products None known. Page 2 / 4 Product code 96215 Product name Old Ceiling Tile Paint White Page 590 of 871 Page 590 of 871 Page 590 of 871 Page 590 of 871 ---PAGE BREAK--- Polymerization Hazardous polymerization does not occur 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Toluene 108-88-3 636 mg/kg 8390 mg/kg 12.5 mg/L N-Butane 106-97-8 - - 658 g/m3 Acetone 67-64-1 - - 50100 mg/m3 Propane 74-98-6 - - 658 mg/L Light Aliphatic Naptha Solvent 64742-89-8 - 3000 mg/kg - Mineral Spirits 64742-47-8 5000 mg/kg 2000 mg/kg 5.2 mg/L Ethyl benzene 100-41-4 3500 mg/kg 15354 mg/kg 17.2 mg/L Xylene (mix) 1330-20-7 4300 mg/kg - 47635 mg/L Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity None known Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects Reports have associated prolonged overexposure to solvents with permanent brain and nervous system damage. Prolonged or repeated occupational overexposure may affect the following:. Kidney. Lungs. Liver. Heart. Blood. Other adverse effects Possible risk of harm to the unborn fetus . Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Toluene A4 Not Listed Not Listed Not Listed Not Listed N-Butane Not Listed Not Listed Not Listed Not Listed Not Listed Acetone A4 Not Listed Not Listed Not Listed Not Listed Propane Not Listed Not Listed Not Listed Not Listed Not Listed Light Aliphatic Naptha Solvent Not Listed Not Listed Not Listed Not Listed Not Listed Mineral Spirits Not Listed Not Listed Not Listed Not Listed Not Listed Ethyl benzene A3 Group 2B Not Listed Not Listed Listed Xylene (mix) A4 Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Aquatic toxicity Harmful to aquatic organisms Do not let product enter drains. 13. DISPOSAL CONSIDERATIONS Disposal Information Dispose in accordance with federal, state, and local regulations. Do not puncture or incinerate. Do not heat or cut empty containers with electric or gas torches . Please recycle empty container whenever possible. 14. TRANSPORTATION INFORMATION DOT Consumer commodity, ORM-D. TDG Consumer commodity, ORM-D. 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Ethyl benzene Listed Page 3 / 4 Water Flea Data Gammarus lacustris LC50=0.6 mg/L (48 h) water flea EC50=3.82 mg/L (48 h) Toluene Ethyl benzene Acetone Product code 96215 Microtox Data Photobacterium phosphoreum EC50=9.68 mg/L (30 min) Nitrosomonas EC50=96 mg/L (24 h) Product name Old Ceiling Tile Paint White Water Flea Data Daphnia magna EC501.8 - 2.4 mg/L (48 h) Microtox Data Photobacterium phosphoreum EC50=14500 mg/L (15 min) Microtox Data Photobacterium phosphoreum EC50=19.7 mg/L (30 min) Water Flea Data Daphnia magna EC5010294 - 17704 mg/L (48 h) Daphnia magna EC5012600 - 12700 mg/L (48 h) Xylene (mix) Microtox Data Photobacterium phosphoreum EC50=0.0084 mg/L (24 h) Water Flea Data Daphnia magna EC505.46 - 9.83 mg/L (48 h) Daphnia magna EC50=11.5 mg/L (48 h) Page 591 of 871 Page 591 of 871 Page 591 of 871 Page 591 of 871 ---PAGE BREAK--- 15. REGULATORY INFORMATION Xylene (mix) Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Toluene Listed Listed Development al Female Reproductive N-Butane Not Listed Listed Not Listed Acetone Not Listed Listed Not Listed Propane Listed Listed Not Listed Light Aliphatic Naptha Solvent Not Listed Not Listed Not Listed Mineral Spirits Not Listed Not Listed Not Listed Ethyl benzene Listed Listed Carcinogen Xylene (mix) Not Listed Listed Not Listed Chemical Name Type Toluene - 108-88-3 Female Reproductive WARNING: This product contains a chemical(s) known to the state of California to cause cancer and birth defects or other reproductive harm International Inventories Chemical Name EINECS DSL NDSL TSCA Toluene X X - X N-Butane X X - X Acetone X X - X Propane X X - X Light Aliphatic Naptha Solvent X X - X Mineral Spirits X X - X Ethyl benzene X X - X Xylene (mix) X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION NFPA Health - 1 Flammability - 3 Reactivity - 3 HMIS Health - 1 Flammability - 3 Physical Hazard - 3 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product code 96215 Product name Old Ceiling Tile Paint White Page 592 of 871 Page 592 of 871 Page 592 of 871 Page 592 of 871 ---PAGE BREAK--- Material Safety Data Sheet (MSDS) Series: #0541, #0542, #0544, #0545, #0548, #0549 Kit (All Labels) MSDS # 0037 Revision 4 NFPA Rating: HMIS Rating: 1-0-0 1-0-0-B SECTION I EMERGENCY TELEPHONE NO. TRADE NAME (IF NONE, PUT CHEMICAL) ONETIME® Lightweight Spackling Compound (918) 825-5744 (24 Hrs.) MANUFACTURER'S NAME AND TELEPHONE NO. Red Devil, Incorporated (918) 825-5744 ADDRESS (Number, Street, City, State, Zip Code) 4175 Webb Street, Pryor, Oklahoma 74361 SECTION II - HAZARDOUS INGREDIENTS % TLV PEL UNITS PRODUCT CONSISTS OF: Acrylic & Vinyl Acrylic Emulsion Blend (Mixture) Mineral Oil Based Anti-Foam (Mixture) <70 <0.25 NE NE NE NE Ethoxylate [9036-19-5] Non-hazardous ingredients* <0.75 <10 NE NA NE NA Soda Lime Borosilicate (65997-17-3) <25 NE NE *Unlisted ingredients are not considered hazardous under the OSHA Hazard Communication Standard (29 CFR 1910.1200). Specific chemical identities withheld as trade secret pursuant to OSHA Haz. Com. Stand. 29 CFR 1910.1200 VOC: 4%/wt. CARB Compliance: YES. Prop 65 Ingredients: NONE SECTION III - PHYSICAL DATA BOILING POINT NE SPECIFIC GRAVITY (H20=1) 0.36 – 0.38 VAPOR PRESSURE (MM Hg.) NE PERCENT VOLATILES BY VOLUME <5 VAPOR DENSITY (AIR=1) <1 pH 9-9.5 SOLUBILITY IN WATER Appreciable EVAPORATION RATE <0.4 (BuAc = 1) APPEARANCE AND ODOR White paste; mild acrylic/ammonia odor SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method used) > 200F (TOC) FLAMMABLE LIMITS LEL NA UEL NA EXTINGUISHING MEDIA Use media suitable for adjacent materials. SPECIAL FIRE FIGHTING PROCEDURES No special procedures are required. UNUSUAL FIRE AND EXPLOSION HAZARDS None known. NA - Not Applicable NE - Not Established UN - Unavailable Page 593 of 871 Page 593 of 871 Page 593 of 871 Page 593 of 871 ---PAGE BREAK--- SECTION V - HEALTH HAZARD INFORMATION OR OVEREXPOSURE Inhalation of dust generated from dried product may cause respiratory irritation. Prolonged or repeated contact may cause mild skin and eye irritation. FIRST AID EYES Immediately flush with large amounts of water, holding eyelids open. Get medical attention if irritation persists. SKIN Wipe material from skin with cloth or paper towel, then wash exposed area with soap and water. Get medical help if irritation persists. INHALATION Move to fresh air. Treat with artificial respiration if needed. Seek medical attention if irritation persists. INGESTION Contact local poison control center or physician IMMEDIATELY!! SECTION VI - REACTIVITY DATA STABILITY Stable INCOMPATIBLE MATERIALS None known HAZARDOUS DECOMPOSITION PRODUCTS Carbon monoxide, carbon dioxide, acrylic acid SECTION VII - SPILL OR LEAK PROCEDURES PROCEDURES Wipe up spilled material. Wash area with detergent. WASTE DISPOSAL METHOD Dispose of in accordance with Local, State and Federal regulations. SECTION VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY Not normally required. EYEWEAR Wear safety glasses. CLOTHING/GLOVES Not normally required; For extended contact, neoprene or other chemical resistant gloves recommended. VENTILATION Provide adequate general dilution ventilation. SECTION IX - SPECIAL PRECAUTIONS Store in a closed container in cool dry area. Protect from freezing & excessive heat. DOT Proper Shipping Name: Not Regulated by DOT. DOT Hazard Class: None. DOT UN/NA Number: None. PACKING GROUP: None. Reviewed By: Larry G. Brandon VP Technology & General Manager June 24, 2004 NAME TITLE DATE The information contained herein has been developed based upon current available scientific data. New information may be developed from time to time which may render the conclusions of this report obsolete. Therefore, no warranty is extended as to the applicability of this information to the user's intended purpose or for the consequences of its use or misuse. Page 594 of 871 Page 594 of 871 Page 594 of 871 Page 594 of 871 ---PAGE BREAK--- SAFETY DATA SHEET State Chemical Division – State Industrial Products State Chemical Ltd. 5915 Landerbrook Drive, Mayfield Heights 1745 Meyerside Dr., Unit Mississauga, Ontario L5T 1C6 (905) 670-4669 Ohio 44124-4034 [PHONE REDACTED] 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: ORANGE BUOY 24 Hour Emergency CHEMTREC Number: [PHONE REDACTED] Product Description: A formulated lift station and grease trap cleaner. MSDS Number: M00447 2. HAZARDS IDENTIFICATION ***EMERGENCY OVERVIEW*** Flammable Liquid - Category 3 Aspiration Hazard - Category 1 DANGER Hazard Statements: H304 May be fatal if swallowed and enters airways H315 Causes skin irritation. H317 May cause an allergic skin reaction. Precautionary Statements: P261 Avoid breathing fume. P210 Keep away from heat, sparks and open flames. — No smoking. P202 Do not handle until all safety precautions have been read and understood. P271 Use only outdoors or in a well-ventilated area. P281 Use personal protective equipment as required. P264 Wash hands thoroughly after handling. P280 Wear protective gloves, protective clothing, and eye protection. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredients CAS Number Weight ACGIH OSHA Orange Terpenes 68647-72-3 < 100% NE NE 4. FIRST AID MEASURES P312 Call a POISON CENTER or physician if you feel unwell. P308+P313 IF exposed or concerned: Get medical attention. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P312+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. P302+P352 IF ON SKIN: wash with plenty of soap and water. P332+P313 IF SKIN irritation occurs: Get medical attention. P362 Take off contaminated clothing and wash before reuse. 5. FIRE FIGHTING MEASURES Flashpoint(Method): 120ºF; 49ºC (TCC) Lower Explosive Limit(LEL): NA Upper Explosive Limit(UEL): NA Autoignition Temperature: NA Flammable Properties: Combustible liquid. Unusual Fire & Explosion Hazards: Improper handling of solvent soaked rags can cause spontaneous combustion. Before disposal, wash rags with soap and water and dry in well-ventilated area or store in a fireproof container with no other flammable or combustible materials present. Extinguishing Media: Carbon Dioxide, dry chemical, foam. Fire Fighting Instructions: Wear self-contained breathing apparatus and full protective clothing. Contains oil, water is not effective in fire fighting. 6. ACCIDENTAL RELEASE MEASURES Small Spills: Use absorbent to pick up residue and dispose of properly. Avoid discharge to natural waters. Large Spills: Halt spill at source, dike and contain spill. Use absorbent to pick up residue and transfer to a proper container. Dispose of in accordance with Federal, State and local regulations. 7. HANDLING AND STORAGE Handling:: This product is for industrial use only. Use with adequate ventilation. Wash thoroughly after handling. Do not take internally. Harmful if swallowed. Do not reuse empty containers. Empty product containers may contain product residue. Avoid contact with skin, eyes and clothing. Do not mix with other chemicals. Storage: Keep out of reach of children. Keep containers closed when not in use. Store in a well-ventilated area. Do not store with strong oxidizers. P403+P233 Store in a well-ventilated place. Keep container closed. P405 Store locked up. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering Controls: Use of general or local ventilation is recommended whenever this product is used in confined spaces or above ambient temperature. Personal Protective Equipment: Page 595 of 871 Page 595 of 871 Page 595 of 871 Page 595 of 871 ---PAGE BREAK--- Respiratory: If personal exposure cannot be controlled below applicable limits by ventilation, wear a NIOSH approved, properly fitted respirator. Eye: Safety glasses or goggles with unperforated sideshields are recommended. Skin: Wear chemically impervious gloves. Other: An emergency eyewash station or source of clean potable water should be available in case of accidental eye contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear orange Odor: Citrus Physical State: Liquid pH: NA Boiling Point: 221ºF; 105ºC Freezing/Melting Point: NA Solubility in Water: Insoluble Specific Gravity: 0.845 10. STABILITY AND REACTIVITY Stability: Stable. Hazardous Polymerization: Will not occur. Conditions to Avoid: Heat, sparks or open flame. Incompatibility: Oxidizing agents. Hazardous Decomposition Products: Carbon Dioxide, Carbon Monoxide, various Hydrocarbons. 11. TOXICOLOGICAL INFORMATION This product contains no IARC, NTP or OSHA listed carcinogens. Hazardous Ingredients CAS Number LD50 LC50 Orange Terpenes 68647-72-3 5.6-6.6 g/kg (mouse oral) NE 12. ECOLOGICAL INFORMATION NA 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with the Federal, State, and Local regulations regarding pollution. Avoid discharge to natural waters. P501 Dispose of container to in accordance with all Federal, State and Local Regulations regarding waste disposal. 14. TRANSPORT INFORMATION DOT Shipping Data: Combustible Liquid. Ships as non-hazardous due to limited quantity exemption. Canadian TDG: Shipped in accordance with 49 CFR as part of a transborder shipment authorized under Section 5.2 of the Canadian Transportation of Dangerous Goods. 15. REGULATORY INFORMATION TSCA: All ingredients in this product are listed or exempt from listing on the TSCA Chemical Inventory. CEPA: All ingredients in this product are listed or exempt from listing on the Canadian DSL/NDSL. Proposition 65: This product contains no chemicals known to the state of California to cause cancer, birth defects or other reproductive harm. SARA 313: This product contains no toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40CFR372). HMIS RATING: HEALTH = 1 FLAMMABILITY = 2 REACTIVITY = 0 PPE = B WHMIS RATING: Class B, Division 3; Class D, Division 2B 16. OTHER INFORMATION NA = Not Available or Not Applicable NE = Not Established Read and follow all label directions and precautions before using the product. This product is intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF THE REACH OF CHILDREN. While we believe that the data contained herein is factual and the opinions expressed are those of qualified experts, the data are not to be taken as a warranty or representation for which the company assumes legal responsibility. They are offered solely for your consideration, investigation, and verification. Any use of these data and information must be determined by the user to be in accordance with applicable Federal, State, and Local Laws and regulations. HEALTH AND SAFETY INFORMATION: (216) 861-7114 Prepared On: October 2014 Replaces: October 2011 Completed By: Regulatory Affairs Page 596 of 871 Page 596 of 871 Page 596 of 871 Page 596 of 871 ---PAGE BREAK--- 98277 MATERIAL SAFETY DATA SHEET ESSENTIALLY SIMILAR TO OSHA FORM 174 RATINGS HMIS NFPA HAZARD INDEX PERSONAL PROTECTION HEALTH 1 1 SEVERE HAZARD 4 A GLASSES FLAMMABILITY 2 2 SERIOUS HAZARD 3 B GLASSES & GLOVES REACTIVITY 0 0 MODERATE HAZARD 2 C GLASSES,GLOVES & APRON PERSONAL PROTECTION B SLIGHT HAZARD 1 D FACE SHIELD,GLOVES & APRON MINIMAL HAZARD 0 E GLASSES, GLOVES & RESP. MANUFACTURED FOR: EMERGENCY TELEPHONE NUMBER: Lawson Products, Inc. Rocky Mountain Poison and Drug Center 1666 East Touhy Avenue (303) 623-5716 Des Plaines, Illinois 60018 REVISION DATE: INFORMATION TELEPHONE NUMBER: 10/15/01 (847) 827-9666 SECTION I - PRODUCT IDENTIFICATION PRODUCT NUMBER 98277 PRODUCT NAME Orange Scrubber PRODUCT CLASS Cleaners SECTION II - HAZARDOUS INGREDIENTS ACGIH OSHA OSHA OSHA TLV PEL PEL TLV TWA STEL INGREDIENT CAS NUMBER % PPM PPM MG/M^3 MG/M^3 Pumice 1332-09-8 5-10 NONE NONE NONE NONE Triethanolamine I 102-71-6 0.1-1 NONE NONE NONE N/A Terpenes 68956-56-9 5-10 N/A N/A N/A N/A D-Limonene 5989-27-5 N/A N/A N/A N/A N/A SECTION III - PHYSICAL DATA BOILING POINT (degrees N/A VAPOR DENSITY: N/A EVAPORATION RATE: N/A PERCENT VOLATILE (By Volume): N/A WEIGHT PER GALLON (LBS): N/A ODOR AND APPEARANCE: Citrus odor, hazy liquid. SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION: U.N. CLASSIFICATION: OSHA CLASS NONE PER DOT NONE DOT CLASS NONE PER IMCO NONE IMCO CLASSIFICATION NUMBER: IATA CLASSIFICATION: NONE NONE FLASH POINT (Degrees 193 METHOD: Tag Closed Cup LEL: N/A UEL: N/A file:///JI/shared/MSDS_Content_Building/Content_...ts/Lawson/1/d0274b4344d6ca0e86256b66006a2134.htm (1 of 4) [2/27/2002 1:46:48 AM] Page 597 of 871 Page 597 of 871 Page 597 of 871 Page 597 of 871 ---PAGE BREAK--- NFPA FIRE PROTECTION LEVEL:N/A VOLATILE ORGANIC COMPOUNDS: 9.20% EXTINGUISHING MEDIA: CO2 DRY CHEMICAL UNUSUAL FIRE AND EXPLOSION HAZARDS: None Known. SPECIAL FIREFIGHTING PROCEDURES: None Known. SECTION V - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE: None Known. PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT INHALATION INGESTION MEDICAL CONDITIONS PRONE TO OVEREXPOSURE: N/A TARGET ORGANS AFFECTED: N/A CARCINOGENICITY: This product contains material suspected to be a carcinogen by the National Toxicolgy Program, or the International Agency for Research on Cancer, or the Occupational Safety & Health Administration, "Suspected in Animals" EMERGENCY AND FIRST AID PROCEDURES: Ingestion: Do not induce vomiting. CALL a physician. Skin and Eyes: Flush with water. SECTION VI - REACTIVITY DATA STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR HAZARDOUS DECOMPOSITION PRODUCTS: Irritating organic vapors upon combustion. CONDITIONS TO AVOID: N/A INCOMPATIBILITY (MATERIALS TO AVOID): None Known. SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Use absorbent material to collect and contain for salvage or disposal. Flush area with water. WASTE DISPOSAL METHOD: Must be in accordance with applicable laws and regulations. SECTION VIII - SAFE HANDLING AND USE INFORMATION RESPIRATORY PROTECTION: None Required. file:///JI/shared/MSDS_Content_Building/Content_...ts/Lawson/1/d0274b4344d6ca0e86256b66006a2134.htm (2 of 4) [2/27/2002 1:46:48 AM] Page 598 of 871 Page 598 of 871 Page 598 of 871 Page 598 of 871 ---PAGE BREAK--- VENTILATION: As required. PROTECTIVE GLOVES: Not required. EYE PROTECTION: Not required. OTHER PROTECTIVE EQUIPMENT: Eye wash station and safety showers should be available. HYGENIC PRACTICES: Not applicable. SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep in area above 40 degrees F and below 120 degrees F. OTHER PRECAUTIONS: FOR INDUSTRIAL USE ONLY. DO NOT TAKE INTERNALLY. Date of Preparation 03/27/91 RESPONSIBLE PARTY: Engineering Department Lawson Products, Inc. 1666 East Touhy Avenue Des Plaines, Illinois 60018 (847) 827-9666 "Final determination of suitability of the chemical(s) is the sole responsibility of the user. Users of any chemical should satisfy themselves that the conditions and methods of use assure that the chemical is used safely. NO REPRESENTATIONS OR WARRANTEES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO THE INFORMATION CONTAINED HEREIN OR THE CHEMICAL TO WHICH THE INFORMATION REFERS." PPM Parts Per Million CAS Chemical Abstract Service CNS Central Nervous System DOT Department of Transportation TLV Threshold Limit Value UEL Upper Explosive Level LEL Lower Explosive Level MG/M^3 Milligrams per Cubic Meter N/A Not Currently Available NFPA National Fire Protection Agency NTP National Toxicolgy Program PEL Permissible Exposure Levels STEL Short Term Exposure Limit TWA Time Weighted Average HMIS Hazardous Materials Identification System file:///JI/shared/MSDS_Content_Building/Content_...ts/Lawson/1/d0274b4344d6ca0e86256b66006a2134.htm (3 of 4) [2/27/2002 1:46:48 AM] Page 599 of 871 Page 599 of 871 Page 599 of 871 Page 599 of 871 ---PAGE BREAK--- IATA International Air Transport Association OSHA Occupational Safety & Health Administration IARC International Agency for Research on Cancer IMCO International Maritime Commission Oraganization ACGIH Am. Conference of Governmental Indust. Hygieniests file:///JI/shared/MSDS_Content_Building/Content_...ts/Lawson/1/d0274b4344d6ca0e86256b66006a2134.htm (4 of 4) [2/27/2002 1:46:48 AM] Page 600 of 871 Page 600 of 871 Page 600 of 871 Page 600 of 871 ---PAGE BREAK--- Pennzoil Premium Grease Wheel Bearing 707L Red Version 2.2 Effective Date 2014-12-10 Material Safety Data Sheet According to the Controlled Product Regulations 1/7 Print Date 2014-12-10 MSDS_CA 1. MATERIAL AND COMPANY IDENTIFICATION Material Name : Pennzoil Premium Grease Wheel Bearing 707L Red Uses : Automotive and industrial grease. Product Code : 001B1160 Manufacturer/Supplier : Shell Canada Products 400 - 4th Avenue S.W Calgary AB T2P 0J4 Canada Telephone : [PHONE REDACTED] Fax : [PHONE REDACTED] Emergency Telephone Number CHEMTREC (24 hr) : CHEMTREC (24 hr): [PHONE REDACTED] Canutec (24 hr) : CANUTEC (24 hr): [PHONE REDACTED] 2. COMPOSITION/INFORMATION ON INGREDIENTS Preparation description : A lubricating grease containing highly-refined mineral oils and additives. The highly refined mineral oil contains (w/w) DMSO-extract, according to IP346. Refer to Chapter 8 for Occupational Exposure Guidelines. 3. HAZARDS IDENTIFICATION WHMIS Class/Description : THIS PRODUCT IS NOT A WHMIS CONTROLLED SUBSTANCE. Physical Description : A lubricating grease containing highly-refined mineral oils and additives. Routes of Exposure : Skin and eye contact are the primary routes of exposure although exposure may occur following accidental ingestion. Health Hazards : Not expected to be a health hazard when used under normal conditions. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. High-pressure injection under the skin may cause serious damage including local necrosis. Used grease may contain harmful impurities. Signs and : Local necrosis is evidenced by delayed onset of pain and tissue damage a few hours following injection. Oil acne/folliculitis signs and may include formation of black pustules and spots on the skin of exposed areas. Ingestion may result in nausea, vomiting and/or diarrhoea. Safety Hazards : Not classified as flammable but will burn. Environmental Hazards : Not classified as dangerous for the environment. Page 601 of 871 Page 601 of 871 Page 601 of 871 Page 601 of 871 ---PAGE BREAK--- Pennzoil Premium Grease Wheel Bearing 707L Red Version 2.2 Effective Date 2014-12-10 Material Safety Data Sheet According to the Controlled Product Regulations 2/7 Print Date 2014-12-10 MSDS_CA 4. FIRST AID MEASURES General Information : Not expected to be a health hazard when used under normal conditions. Inhalation : No treatment necessary under normal conditions of use. If persist, obtain medical advice. Skin Contact : Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention. When using high pressure equipment, injection of product under the skin can occur. If high pressure injuries occur, the casualty should be sent immediately to a hospital. Do not wait for to develop. Obtain medical attention even in the absence of apparent wounds. Eye Contact : Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention. Ingestion : In general no treatment is necessary unless large quantities are swallowed, however, get medical advice. Advice to Physician : Treat High pressure injection injuries require prompt surgical intervention and possibly steroid therapy, to minimise tissue damage and loss of function. Because entry wounds are small and do not reflect the seriousness of the underlying damage, surgical exploration to determine the extent of involvement may be necessary. Local anaesthetics or hot soaks should be avoided because they can contribute to swelling, vasospasm and ischaemia. Prompt surgical decompression, debridement and evacuation of foreign material should be performed under general anaesthetics, and wide exploration is essential. 5. FIRE FIGHTING MEASURES Clear fire area of all non-emergency personnel. Flash point : Typical 274 °C / 525 °F (COC) Upper / lower Flammability or Explosion limits : Typical 1 - 10 %(V)(based on mineral oil) Auto ignition temperature : > 320 °C / 608 °F Hazardous Combustion Products and Specific Hazards : Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Suitable Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media : Do not use water in a jet. Protective Equipment for Firefighters : Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space. 6. ACCIDENTAL RELEASE MEASURES Page 602 of 871 Page 602 of 871 Page 602 of 871 Page 602 of 871 ---PAGE BREAK--- Pennzoil Premium Grease Wheel Bearing 707L Red Version 2.2 Effective Date 2014-12-10 Material Safety Data Sheet According to the Controlled Product Regulations 3/7 Print Date 2014-12-10 MSDS_CA Protective Measures : Avoid contact with skin and eyes. Use appropriate containment to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Clean Up Methods : Shovel into a suitable clearly marked container for disposal or reclamation in accordance with local regulations. 7. HANDLING AND STORAGE General Precautions : Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Use the information in this data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling vapour and/or mists. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. Storage : Keep container closed and in a cool, well-ventilated place. Use properly labelled and closeable containers. Storage Temperature: 0 - 50 °C / 32 - 122 °F Recommended Materials : For containers or container linings, use mild steel or high density polyethylene. Unsuitable Materials : PVC. Additional Information : Polyethylene containers should not be exposed to high temperatures because of possible risk of distortion. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Oil mist, mineral ACGIH TWA 5 mg/m3 ACGIH STEL 10 mg/m3 Consult local authorities for acceptable exposure limits within their jurisdiction. Additional Information : Due to the product's semi-solid consistency, generation of mists and dusts is unlikely to occur. Exposure Controls : The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Adequate ventilation to control airborne concentrations. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated. Personal Protective Equipment : Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers. Page 603 of 871 Page 603 of 871 Page 603 of 871 Page 603 of 871 ---PAGE BREAK--- Pennzoil Premium Grease Wheel Bearing 707L Red Version 2.2 Effective Date 2014-12-10 Material Safety Data Sheet According to the Controlled Product Regulations 4/7 Print Date 2014-12-10 MSDS_CA Respiratory Protection : No respiratory protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid breathing of material. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. Select a filter suitable for combined particulate/organic gases and vapours [boiling point >65 °C (149 Hand Protection : Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection: PVC, neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. Eye Protection : Wear safety glasses or full face shield if splashes are likely to occur. Protective Clothing : Skin protection not ordinarily required beyond standard issue work clothes. Monitoring Methods : Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate. Environmental Exposure Controls : Minimise release to the environment. An environmental assessment must be made to ensure compliance with local environmental legislation. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Red. Liquid at room temperature. Odour : Slight hydrocarbon. Odour threshold : Data not available pH : Not applicable. Initial Boiling Point and Boiling Range : Data not available Dropping point : Data not available Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s)) Specific gravity : Typical 0.905 at 15 °C / 59 °F Density : Typical 890 kg/m3 at 15 °C / 59 °F Water solubility : Negligible. n-octanol/water partition coefficient (log Pow) : > 6 (based on information on similar products) Page 604 of 871 Page 604 of 871 Page 604 of 871 Page 604 of 871 ---PAGE BREAK--- Pennzoil Premium Grease Wheel Bearing 707L Red Version 2.2 Effective Date 2014-12-10 Material Safety Data Sheet According to the Controlled Product Regulations 5/7 Print Date 2014-12-10 MSDS_CA Kinematic viscosity : Typical 107 mm2/s at 40 °C / 104 °F Vapour density (air=1) : > 1 (estimated value(s)) Evaporation rate (nBuAc=1) : Data not available 10. STABILITY AND REACTIVITY Stability : Stable. Conditions to Avoid : Extremes of temperature and direct sunlight. Materials to Avoid : Strong oxidising agents. Hazardous Decomposition Products : Hazardous decomposition products are not expected to form during normal storage. Hazardous Polymerisation : Data not available Sensitivity to Mechanical Impact : Data not available Sensitivity to Static Discharge : Data not available 11. TOXICOLOGICAL INFORMATION Basis for Assessment : Information given is based on data on the components and the toxicology of similar products. Routes of Exposure : Skin and eye contact are the primary routes of exposure although exposure may occur following accidental ingestion. Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal conditions of use. Skin Irritation : Expected to be irritating. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Eye Irritation : Expected to be irritating. Respiratory Irritation : Inhalation of vapours or mists may cause irritation. Sensitisation : Not expected to be a skin sensitiser. Repeated Dose Toxicity : Not expected to be a hazard. Mutagenicity : Not considered a mutagenic hazard. Carcinogenicity : Product contains mineral oils of types shown to be non- carcinogenic in animal skin-painting studies. Highly refined mineral oils are not classified as carcinogenic by the International Agency for Research on Cancer (IARC). Other components are not known to be associated with carcinogenic effects. Reproductive and Developmental Toxicity : Not expected to be a hazard. Additional Information : Used grease may contain harmful impurities that have accumulated during use. The concentration of such harmful impurities will depend on use and they may present risks to health and the environment on disposal. ALL used grease should be handled with caution and skin contact avoided as far as possible. Page 605 of 871 Page 605 of 871 Page 605 of 871 Page 605 of 871 ---PAGE BREAK--- Pennzoil Premium Grease Wheel Bearing 707L Red Version 2.2 Effective Date 2014-12-10 Material Safety Data Sheet According to the Controlled Product Regulations 6/7 Print Date 2014-12-10 MSDS_CA High pressure injection of product into the skin may lead to local necrosis if the product is not surgically removed. 12. ECOLOGICAL INFORMATION Ecotoxicological data have not been determined specifically for this product. Information given is based on a knowledge of the components and the ecotoxicology of similar products. Acute Toxicity : Poorly soluble mixture.May cause physical fouling of aquatic organisms.Expected to be practically non toxic:LL/EL/IL50 > 100 mg/l(to aquatic organisms)(LL/EL50 expressed as the nominal amount of product required to prepare aqueous test extract).Mineral oil is not expected to cause any chronic effects to aquatic organisms at concentrations less than 1 mg/l. Mobility : Semi-solid under most environmental conditions. Floats on water. If it enters soil, it will adsorb to soil particles and will not be mobile. Persistence/degradability : Expected to be not readily biodegradable. Major constituents are expected to be inherently biodegradable, but the product contains components that may persist in the environment. Bioaccumulation : Contains components with the potential to bioaccumulate. Other Adverse Effects : Product is a mixture of non-volatile components, which are not expected to be released to air in any significant quantities. Not expected to have ozone depletion potential, photochemical ozone creation potential or global warming potential. 13. DISPOSAL CONSIDERATIONS Material Disposal : Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations. Do not dispose into the environment, in drains or in water courses. Container Disposal : Dispose in accordance with prevailing regulations, preferably to a recognised collector or contractor. The competence of the collector or contractor should be established beforehand. Local Legislation : Disposal should be in accordance with applicable regional, national, and local laws and regulations. 14. TRANSPORT INFORMATION Canadian Road and Rail Shipping Classification This product is not regulated under the Canadian Transportation of Dangerous Goods Regulations for transport by road and rail. Page 606 of 871 Page 606 of 871 Page 606 of 871 Page 606 of 871 ---PAGE BREAK--- Pennzoil Premium Grease Wheel Bearing 707L Red Version 2.2 Effective Date 2014-12-10 Material Safety Data Sheet According to the Controlled Product Regulations 7/7 Print Date 2014-12-10 MSDS_CA 15. REGULATORY INFORMATION The regulatory information is not intended to be comprehensive. Other regulations may apply to this material. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Class/Description : THIS PRODUCT IS NOT A WHMIS CONTROLLED SUBSTANCE. Inventory Status EINECS : All components listed. TSCA : All components listed. DSL : All components listed. 16. OTHER INFORMATION MSDS Version Number : 2.2 MSDS Effective Date : 2014-12-10 MSDS Revisions : A vertical bar in the left margin indicates an amendment from the previous version. MSDS Regulation : The content and format of this (M)SDS is in accordance with the Controlled Product Regulations. MSDS Distribution : The information in this document should be made available to all who may handle the product. Disclaimer : The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of health, safety and environmental requirements only. No warranty or guarantee is expressed or implied regarding the accuracy of these data or the results to be obtained from the use of the product. Page 607 of 871 Page 607 of 871 Page 607 of 871 Page 607 of 871 ---PAGE BREAK--- Safety Data Sheet Cold Pipe Insulation PAGE 1 of 5 SECTION I - IDENTIFICATION PRODUCT NAME: Cold Pipe Insulation PRODUCT CODE: 29569 PRODUCT USE: Cold Pipe Insulation Spray COMPANY NAME: Lawson Products, Inc. COMPANY ADDRESS: 8770 W. Bryn Mawr Ave., Suite 900 Chicago, Il 60631 COMPANY PHONE: [PHONE REDACTED] EMERGENCY PHONE: [PHONE REDACTED] SECTION II – HAZARDS IDENTIFICATION CLASSIFICATION: Flammable Aerosol: Category 2 Liquefied Gas Skin Irritant: Category 2 Eye Irritant: Category 2b Carcinogenicity: Category 2 HAZARD STATEMENT(S): WARNING: Flammable Aerosol Contains gas under pressure; May explode if heated. Causes eye and skin irritation. Suspected of causing cancer. This product contains the following percentage of chemicals of unknown toxicity: 7.5% PRECAUTIONARY STATEMENTS: Keep away from heat, sparks, open flames, and hot surfaces. -No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Wash hands thoroughly after handling. If on skin: Wash with plenty of water. If skin irritation occurs: Get medical attention. Take off contaminated clothing and wash before reuse. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves and eye protection. If exposed or concerned: Get medical advice or attention. Store locked up. Dispose of contents and container in accordance with local, state, and national regulations. SYMBOL: HAZARDS NOT OTHERWISE CLASSIFIED: N/A SECTION III – COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS INGREDIENT CAS NUMBER PERCENT Methylene Chloride 75-09-2 30-60% Hexadecanoic Acid 57-10-3 1-5% Propane/n-Butane 68476-86-8 15-40% Octadecanoic Acid 57-11-4 1-5% SECTION IV - FIRST AID MEASURES EYES: Remove contact lenses. Flush with water for at least 15 minutes. See a physician if irritation persists. INGESTION: Rinse mouth with water. Do not induce vomiting unless directed by medical authority. Seek medical attention if irritation persists. INHALATION: If inhaled: Remove person to fresh air and keep comfortable for breathing. SKIN: Wash thoroughly with soap and water. Seek medical attention if irritation develops. ACUTE HEALTH HAZARDS: Eyes: redness, tearing, blurred vision Skin: defatting and dermatitis Inhalation: Irritation Oral: abdominal irritation, nausea, vomiting, and diarrhea CHRONIC HEALTH HAZARDS: Possible cancer causing agent and overexposure may also include damage to skin, kidneys, liver, dizziness, headache, nausea, mental confusion, visual disturbances, lungs, blood, or central nervous system. NOTE TO PHYSICIAN: Do not administer adrenaline or epinephrine to a victim of chlorinated solvent poisoning. This product contains ingredients that may be anticipated to be a carcinogen. Page 608 of 871 Page 608 of 871 Page 608 of 871 Page 608 of 871 ---PAGE BREAK--- Safety Data Sheet Cold Pipe Insulation PAGE 2 of 5 SECTION V – FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA: Carbon dioxide, foam, and water fog. UNSUITABLE EXTINGUISHING MEDIA: Water spray/stream. SPECIAL FIRE FIGHTING PROCEDURES: Wear NIOSH approved Self Contained Breathing Apparatus with a full face piece operated in a positive pressure demand mode with full body protective clothing when fighting fires. Avoid breathing smoke, fumes, and decomposition products. Cool fire exposed containers with water fog to prevent bursting. UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep away from sparks, open flames, and hot surfaces. No smoking. Do not spray on an open flame or other ignition source. HAZARDOUS COMBUSTION PRODUCTS: Oxides of carbon, Hydrogen Chloride, Phosgene. SECTION VI – ACCIDENTAL RELEASE MEASURES PERSONAL PROTECTIVE EQUIPMENT: Refer to section VIII for proper Personal Protective Equipment. SPILL: Remove sources of ignition such as pilot lights. Material is heavier than air and can settle in low lying areas in Flammable concentrations, ventilate area. Product will undergo rapid evaporation. Use absorbent on spill sweep to clean. WASTE DISPOSAL: Dispose of in accordance with federal, state, and local regulations. Do not flame cut, braze, or weld. Empty container very hazardous! RCRA STATUS: Waste solvent likely considered F001 , hazardous, under RCRA, however product should be fully characterized prior to disposal (40 CFR 261). SECTION VII – HANDLING AND STORAGE HANDLING AND STORAGE: Protect from sunlight. Store in a well-ventilated place. Do not expose to temperatures exceeding 50°C/122°F. Store locked up. Pressurized container: Do not pierce or burn, even after use. OTHER PRECAUTIONS: Keep out of the reach of children. Follow label directions exactly. Vapors may collect in low lying areas. INCOMPATIBILITY: May attack certain plastics, rubber, & coatings. Incompatible w/ strong oxidizers & caustics, chemically active metal, such as Aluminum, magnesium powder, sodium, potassium, and lithium. SECTION VIII – EXPOSURE CONTROLS/PERSONAL PROTECTION HAZARDOUS INGREDIENT OSHA PEL ACGIH TLV Methylene Chloride 25 ppm 50 ppm Hexadecanoic Acid Not Established Not Established Propane/n-Butane 1000 ppm 1000 ppm Octadecanoic Acid Not Established Not Established ENGINEERING CONTROLS / VENTILATION: Use only outdoors or in a well-ventilated area. RESPIRATORY PROTECTION: N/A PERSONAL PROTECTIVE EQUIPMENT: Safety glasses and chemical resistant gloves ADDITIONAL MEASURES: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear Liquid ODOR: Chlorinated solvent odor ODOR THRESHOLD: 21mg/m3 (Methylene Chloride) BOILING POINT: > 140°F FREEZING POINT: N/D FLAMMABILITY: Flammable Aerosol FLASH POINT: N/D AUTOIGNITION TEMPERATURE: N/D LOWER FLAMMABILITY LIMIT: N/D UPPER FLAMMABILITY LIMIT: N/D VAPOR PRESSURE (mm Hg): >100 Page 609 of 871 Page 609 of 871 Page 609 of 871 Page 609 of 871 ---PAGE BREAK--- Safety Data Sheet Cold Pipe Insulation PAGE 3 of 5 VAPOR DENSITY (AIR=1): >2 EVAPORATION RATE: >2 SPECIFIC GRAVITY (H2O=1): 1.2 pH: N/A SOLIDS 26% SOLUBILITY IN WATER: 0% PARTITION COEFFICIENT: n-OCTANOL/WATER (KOW): N/D VOLATILITY INCLUDING WATER 82% VOLATILE ORGANIC COMPOUNDS (VOC): 32% DIELECTRIC STRENGTH (Volts): N/D DECOMPOSITION TEMPERATURE: N/D VISCOSITY: N/D SECTION X – STABILITY AND REACTIVITY DATA REACTIVITY: None Known CHEMICAL STABILITY: Stable CONDITIONS TO AVOID: Excessive heat. Sources of ignition. INCOMPATIBILITY: May attack certain plastics, rubber, & coatings. Incompatible w/ strong oxidizers & caustics, chemically active metal, such as Aluminum, magnesium powder, sodium, potassium, and lithium. HAZARDOUS DECOMPOSITION OR BY-PRODUCT: Oxides of carbon, Hydrogen Chloride gas, and Phosgene. POSSIBLE HAZARDOUS REACTIONS: None Known SECTION XI – TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION: Methylene Chloride (75-09-2) LD50 (Oral, Rat) 1600 mg/kg; LC50 (Inhalation, Rat) 52 gm/m3 ROUTES OF ENTRY: Eyes, Ingestion, Inhalation, Skin EYES: Causes irritation, redness, temporary eye damage. INGESTION: Nausea, vomiting, headaches, abdominal pain, diarrhea, dizziness, pulmonary edems, unconsciousness or death INHALATION: May cause irritation to the respiratory tract, headaches, nausea, vomiting, lungs, and may cause fatigue. Excessive or prolonged exposure may cause dizziness and unconsciousness. SKIN: Causes mild irritation, dryness, localize defatting. MEDICAL CONDITION AGGRAVATED: Excessive exposure will aggravate pre-exsiting skin disorders, respiratory, liver, kidney, cardiovascular or pulmonary illnesses. ACUTE HEALTH HAZARDS: Eyes: redness, tearing, blurred vision Skin: defatting and dermatitis Inhalation: Irritation Oral: abdominal irritation, nausea, vomiting, and diarrhea CHRONIC HEALTH HAZARDS: Possible cancer causing agent and overexposure may also include damage to skin, kidneys, liver, dizziness, headache, nausea, mental confusion, visual disturbances, lungs, blood, or central nervous system. CARCINOGENICITY: OSHA: Yes ACGIH: A3 - Animal Carcinogen NTP: Suspected IARC: 2B - Possible OTHER: CA Prop 65 SECTION XII – ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: Do not let residue come in contact with waterways in the United States. Methylene Chloride - This material may leach into groundwater. Will quickly evaporate in the soil and water and may biodegrade to a moderate extent in the water. Will not significantly bioaccumulate. Released in the air this material is expected to have a half-life greater than 30 days. ENVIRONMENTAL TOXICITY: LC50/96hr for fish - >100mg/l. Not expected to be toxic to aquatic life. BIODEGRADABILITY: Component or components of this product are not biodegradable. BIOACCUMULATION: This product is not expected to bioaccumulate. SOIL MOBILITY: This product is mobile in soil. OTHER ECOLOGICAL HAZARDS: This material is toxic to aquatic life. SECTION XIII – DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with federal, state, and local regulations. Do not flame cut, braze, or weld. Empty container very hazardous! Page 610 of 871 Page 610 of 871 Page 610 of 871 Page 610 of 871 ---PAGE BREAK--- Safety Data Sheet Cold Pipe Insulation PAGE 4 of 5 RCRA STATUS: Waste solvent likely considered F001 , hazardous, under RCRA, however product should be fully characterized prior to disposal (40 CFR 261). SECTION XIV - TRANSPORTATION INFORMATION PROPER SHIPPING NAME: Aerosols, Ltd. Qty. HAZARD CLASS/DIVISION: 2.1 (6.1) UN/NA NUMBER: UN 1950 PACKAGING GROUP: N/A AIR SHIPMENT PROPER SHIPPING NAME: Forbidden by USDOT Regulations HAZARD CLASS/DIVISION: N/A UN/NA NUMBER: N/A PACKAGING GROUP: N/A SHIPPING BY WATER: VESSEL (IMO/IMDG) PROPER SHIPPING NAME: Aerosols, Ltd. Qty. HAZARD CLASS/DIVISION: 2.1 (6.1) UN/NA NUMBER: UN 1950 PACKAGING GROUP: N/A ENVIRONMENTAL HAZARDS WATER: Marine Pollutant SECTION XV - REGULATORY INFORMATION TSCA STATUS: All Chemicals are listed or exempt. CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): Methylene Chloride (75-09-2) Reportable Quantity = 1,000 lbs SARA 311/312 HAZARD CATEGORIES: Acute Health, Chronic Health SARA 313 REPORTABLE INGREDIENTS: Methylene Chloride - 75-09-2 STATE REGULATIONS: This product contains chemical(s) METHYLENE CHLORIDE - 75-09-2 known to the state of California Proposition 65 to cause birth defects or other reproductive harm and cancer. Right to Know: METHYLENE CHLORIDE - 75-09-2; Massachusetts Right to Know: METHYLENE CHLORIDE - 75-09- 2 INTERNATIONAL REGULATIONS: All components are listed or exempted. NFPA HEALTH: 2 HMIS HEALTH: 2 NFPA FLAMMABILITY: 2 HMIS FLAMMABILITY: 2 NFPA REACTIVITY: 0 HMIS REACTIVITY: 0 NFPA OTHER: None HMIS PROTECTION: B SECTION XVI - ADDTIONAL INFORMATION PREPARATION BY: Maureen Ruggeberg, Regulatory Affairs Specialist DATE PREPARED: 07/26/2013 REVISION DATE: 10/30/2014 N/A = Not Applicable; N/D = Not Determined DISCLAIMER: To the best of our knowledge, information contained herein is accurate. However there is no assumption of liability for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazard which exists. The information contained in this SDS was obtained from current and reliable sources; however, the data is provided without any warranty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of the manufacturer, the manufacturer will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this SDS shall be created or inferred by any statement in this SDS. Various government agencies may have specific regulations Page 611 of 871 Page 611 of 871 Page 611 of 871 Page 611 of 871 ---PAGE BREAK--- Safety Data Sheet Cold Pipe Insulation PAGE 5 of 5 regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this SDS. The user is responsible for full compliance. Page 612 of 871 Page 612 of 871 Page 612 of 871 Page 612 of 871 ---PAGE BREAK--- PITT-TECH GLOSS WHITE Product name Product and company identification : 1 . 90-374 PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (514) 645-1320 (Canada) 01-800-00-21-400 (Mexico) Supplier Code Emergency telephone number : : : Technical Phone Number : [PHONE REDACTED] Material Safety Data Sheet Date of issue 29 May 2015 Version 53 Emergency overview Hazards identification Potential acute health effects May be harmful if swallowed. Eyes Skin Inhalation Ingestion See toxicological information (Section 11) WARNING! : : : : : Medical conditions aggravated by over- exposure Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. : 2 . Over-exposure Ingestion : Skin : Eyes : Inhalation : Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Keep container closed and sealed until ready for use. Wash thoroughly after handling. HARMFUL IF ABSORBED THROUGH SKIN. CAUSES EYE IRRITATION. MAY BE HARMFUL IF INHALED OR SWALLOWED. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. May be harmful if inhaled. Irritating to eyes. Toxic in contact with skin. This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials Information System (WHMIS). No specific data. No specific data. No specific data. Adverse may include the following: pain or irritation watering redness Page: 1/7 Canada - Mexico Page 613 of 871 Page 613 of 871 Page 613 of 871 Page 613 of 871 ---PAGE BREAK--- PITT-TECH GLOSS WHITE Product name 53 Product code Date of issue Version 90-374 29 May 2015 Composition/information on ingredients 3 . There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. titanium dioxide 13463-67-7 10 - 30 1-(2-butoxy-1-methylethoxy)propan-2-ol 29911-28-2 1 - 5 2-(2-butoxyethoxy)ethanol 112-34-5 1 - 5 2-(2-methoxyethoxy)ethanol 111-77-3 0.5 - 1.5 Name CAS number % (w/w) First aid measures Eye contact Skin contact Inhalation Ingestion Notes to physician : : : : : 4 . Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting. If ingestion, irritation, any type of overexposure or of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person. No specific treatment. Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Use an extinguishing agent suitable for the surrounding fire. Fire-fighting measures Extinguishing media isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. In a fire or if heated, a pressure increase will occur and the container may burst. Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : 5 . Special exposure hazards : None known. Suitable : Not suitable : Hazardous combustion products : Decomposition products may include the following materials: carbon oxides metal oxide/oxides Flammability of the product : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section Environmental precautions Accidental release measures : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions : 6 . Page: 2/7 Canada - Mexico Page 614 of 871 Page 614 of 871 Page 614 of 871 Page 614 of 871 ---PAGE BREAK--- PITT-TECH GLOSS WHITE Product name 53 Product code Date of issue Version 90-374 29 May 2015 Accidental release measures 6 . Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Do not store below the following temperature: 32F / 0C. Put on appropriate personal protective equipment (see Section Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Do not swallow. Do not get in eyes or on skin or clothing. Avoid breathing vapor or mist. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. If this material is part of a multiple component system, read the Material Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. Handling and storage Handling Storage : : 7 . Exposure controls/personal protection 8 . Acceptable Maximum Peak A = ACGIH = American Conference of Governmental Industrial Hygienists. C = Ceiling Limit Potential skin absorption S SR = Respiratory sensitization = Skin sensitization SS TD = Total dust Key to abbreviations Consult local authorities for acceptable exposure limits. = Threshold Limit Value TLV TWA = Time Weighted Average Fume = F IPEL = Internal Permissible Exposure Limit R = Respirable titanium dioxide TWA 10 mg/m³ 10 mg/m³ TD 10 mg/m³ (as Ti) Not established STEL Not established Not established 20 mg/m³ (as Ti) Not established 2-(2-butoxyethoxy)ethanol TWA 10 ppm Not established Not established Not established 2-(2-methoxyethoxy)ethanol TWA Not established Not established Not established 30 ppm Name Result ACGIH Ontario Mexico PPG STEL = = Short term Exposure limit values Page: 3/7 Canada - Mexico Page 615 of 871 Page 615 of 871 Page 615 of 871 Page 615 of 871 ---PAGE BREAK--- PITT-TECH GLOSS WHITE Product name 53 Product code Date of issue Version 90-374 29 May 2015 Exposure controls/personal protection 8 . If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety glasses with side shields. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Personal protection Eyes Skin Respiratory : : : Engineering measures : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. >37.78°C (>100°F) Liquid. 64% 53.51% (w/w) Not available. Not available. 1.18 Not available. 2.5 kPa (18.6 mm Hg) [room temperature] Not available. Not available. Boiling/condensation point Melting/freezing point 0.36 (butyl acetate = 1) Physical and chemical properties Physical state pH Specific gravity Vapor pressure Vapor density Volatility Evaporation rate Odor Color : : : : : : : : : : : Flash point : Closed cup: >93.33°C (>200°F) Explosion limits : Lower: 9.9% 9 . Density ( lbs / gal ) : 9.85 Yes. : Material supports combustion. Page: 4/7 Canada - Mexico Page 616 of 871 Page 616 of 871 Page 616 of 871 Page 616 of 871 ---PAGE BREAK--- PITT-TECH GLOSS WHITE Product name 53 Product code Date of issue Version 90-374 29 May 2015 Physical and chemical properties 9 . Soluble in the following materials: cold water. Solubility : Partition coefficient: n- octanol/water : Not available. % Solid. (w/w) : 46.49 Stable under recommended storage and handling conditions (see Section Reactive or incompatible with the following materials:,acids,oxidizing materials,strong alkalis Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. No specific data. Stability and reactivity Stability Conditions to avoid Materials to avoid Hazardous decomposition products Hazardous polymerization : : : : : 10 . 11 . Toxicological information Conclusion/Summary : Not available. Chronic toxicity Conclusion/Summary : Not available. Carcinogenicity Classification Carcinogenicity : Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Target organs : Contains material which may cause damage to the following organs: blood, lungs, liver, upper respiratory tract, skin, central nervous system (CNS). titanium dioxide LD50 Oral Rat >10 g/kg - 1-(2-butoxy-1-methylethoxy)propan-2-ol LD50 Oral Rat 4.05 g/kg - LD50 Dermal Rabbit 5860 uL/kg - 2-(2-butoxyethoxy)ethanol LD50 Oral Rat 4500 mg/kg - LD50 Dermal Rabbit 2700 mg/kg - 2-(2-methoxyethoxy)ethanol LD50 Oral Rat 4 mL/kg - LD50 Dermal Rabbit 0.65 g/kg - Product/ingredient name Result Species Dose Exposure Acute toxicity Product/ingredient name titanium dioxide A4 2B - ACGIH NTP IARC Carcinogen Classification code: Mutagenicity : Contains material which may cause heritable genetic effects, based on animal data. Teratogenicity : Contains material which may cause birth defects, based on animal data. ACGIH: A1, A2, A3, A4, A5 IARC: 1, 2A, 2B, 3, 4 NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen Not listed or regulated as a carcinogen: - Developmental effects : Contains material which may cause developmental abnormalities, based on animal data. Page: 5/7 Canada - Mexico Page 617 of 871 Page 617 of 871 Page 617 of 871 Page 617 of 871 ---PAGE BREAK--- PITT-TECH GLOSS WHITE Product name 53 Product code Date of issue Version 90-374 29 May 2015 Ecological information Environmental effects : No known significant effects or critical hazards. 12 . Aquatic ecotoxicity titanium dioxide Acute LC50 >100 mg/l Fresh water Daphnia - Daphnia magna 48 hours Product/ingredient name Species Result Exposure The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal Disposal considerations Disposal should be in accordance with applicable regional, national and local laws and regulations. : 13 . Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures 14. Transport information Special precautions for user Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Additional information None identified. None identified. TDG Mexico : : - - - Not regulated. Mexico UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No. TDG Not regulated. - - - No. Marine pollutant substances IMDG : None identified. IMDG Not regulated. - - - No. Not applicable. Not applicable. Not applicable. Page: 6/7 Canada - Mexico Page 618 of 871 Page 618 of 871 Page 618 of 871 Page 618 of 871 ---PAGE BREAK--- PITT-TECH GLOSS WHITE Product name 53 Product code Date of issue Version 90-374 29 May 2015 15 . Regulatory information All components are listed or exempted. Canada inventory ( DSL ) : WHMIS (Canada) Class D-1B: Material causing immediate and serious toxic effects (Toxic). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). : Canada Mexico 1 3 0 Health Flammability Reactivity Classification : : : Other information Hazardous Material Information System 1 0 1 National Fire Protection Association Health Instability Flammability Health Flammability Physical hazards Disclaimer The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Date of previous issue 2/1/2015. : 16 . Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Indicates information that has changed from previously issued version. Organization that prepared the MSDS : EHS : : : : : : 3 * 3 0 ( * ) - Chronic effects Page: 7/7 Canada - Mexico Page 619 of 871 Page 619 of 871 Page 619 of 871 Page 619 of 871 ---PAGE BREAK--- Product Name: Plastic Lead Substitute MSDS No.: 379638 Page: 1 of 4 Date Printed: 01/23/2004 MSDS - Material Safety Data Sheet Part Numbers Covered: 015815 14210 I. Basic Information: Manufacturer: Address: City, ST Zip: Genova Industries 7034 East Court Street Davison, MI 48423 Last Update: 01/24/2003 Chemical State: Solid Gas Liquid X Chemical Type: Mixture Pure X 0 1 0 ALK 1 0 0 E II. Ingredients: CAS No. Chemical Name % Range EHS NTP IARC SUB Z SARA OSHA PEL ACGIH Other TLV Limits [PHONE REDACTED] Calcium carbonate NI NI NI NI 7778189 Calcium sulfate NI 1332587 CLAY 10 NI 10 MG/M3 1305788 Lime, unslaked NI NI NI NI 65997151 PORTLAND CEMENT 10 NI 50MPPC 7631869 SILICA 10 NI NI III. Hazardous Identification: Hazard Category: Acute Chronic Fire Pressure Reactive Hazardous Identification Information: PLEASE SEE 1ST AID MEASURES FOR HEALTH RELATED INQUIRIES X X Inhalation, ingestion Route(s) of Entry: IV. First Aid Measures: Acute: Lung and eye irritation, Skin irritation Chronic: No long term effects from exposure known. Health Hazards (Acute and Chronic): Signs and Page 620 of 871 Page 620 of 871 Page 620 of 871 Page 620 of 871 ---PAGE BREAK--- Product Name: Plastic Lead Substitute MSDS No.: 379638 Page: 2 of 4 Date Printed: 01/23/2004 MSDS - Material Safety Data Sheet EYES: MAY CAUSE EYE IRRITATION. INHALATION: POSSIBLE COUGHING AND BURNING OF THE LUNGS NI Medical Conditions Generally Aggravated by Exposure: EMERGENCY FIRST AID CALL: 1-[PHONE REDACTED] COLLECT REMOVE VICTIM TO FRESH AIR, SEEK MEDICAL ATTENTION IF CONDITION PERSISTS. Emergency and First Aid Procedures: Other Health Warnings: NI CO2, FOAM AND DRY CHEMICAL Fire Extinguishing Media: NI NI Not Determ Upper Explosive Limit: Lower Explosive Limit: Flash Point: V. Fire Fighting Measures: USE WATER SPRAY TO COOL FIRE EXPOSED TO MATERIAL AND TO PROTECT PERSONNEL. Special Fire Fighting Procedures: Unusual Fire and Explosion: NI VI. Accidental Release Measures: Steps to be Taken in Case Material is Released or Spilled: NO SPECIAL PRECAUTIONS - SCOOP UP SPILLED MATERIAL, IT CAN BE REUSED IF IT IS NOT DIRTY OR CONTAMINATED. KEEP CONTAINER CLOSED AFTER USE. Precautions to be Taken: VII. Handling and Storage: Other Precautions: KEEP OUT OF REACH OF CHILDREN AND PETS OPEN AREA IS SUFFICIENT Ventilitation Requirements: VIII. Exposure Controls/Personal Protection: Personal Protective Equipment: NO PROTECTIVE CLOTHING OR EQUIPMENT IS REQUIRED. USE NORMAL GOOD HYGIENIC PRACTICES. Page 621 of 871 Page 621 of 871 Page 621 of 871 Page 621 of 871 ---PAGE BREAK--- Product Name: Plastic Lead Substitute MSDS No.: 379638 Page: 3 of 4 Date Printed: 01/23/2004 MSDS - Material Safety Data Sheet IX. Physical and Chemical Properties: Boiling Point: Melting Point: Evaporation Rate: Vapor Pressure (mm Hg.): Vapor Density (AIR = NI NI NI NI NI Solubility In Water: Apprearance and Odor: Other Information: White powder NONE KNOWN NEGLIGIBLE STABLE Stability: X. Stability and Reactivity: Store away from acids and strong oxidizers. Incompatibility (Materials to Avoid): None known Decomposition/By Products: Hazardous Polymerization: WILL NOT OCCUR XI. Toxicological Information: Avoid breathing dusts. Silicates inhaled into the lungs can lead to Silicosis and other repiratory diseases. XII. Ecological Information: NDA XIII. Disposal Considerations: PLACE IN TRASH CONTAINER AND DISPOSE OF ACCORDING TO FEDERAL, STATE, AND LOCAL REGULATIONS. XIV. Transport Information: TRANSPORATION INFORMATION: DOT PROPER SHIPPING NAME: N/A DOT LABEL: N/A DOT NUMBER: N/A UN NUMBER: N/A IMCO CLASS: N/A DOT HAZARD CLASSIFICATION: N/A XV. Regulatory Information: NDA Page 622 of 871 Page 622 of 871 Page 622 of 871 Page 622 of 871 ---PAGE BREAK--- Product Name: Plastic Lead Substitute MSDS No.: 379638 Page: 4 of 4 Date Printed: 01/23/2004 MSDS - Material Safety Data Sheet XVI. Other Information: NDA ABBREVIATIONS: N/A = NOT APPLICABLE N/I = NONE INDICATED NDA = NO DATA AVAILABLE N/E = NOT ESTABLISHED C = CELSIUS DEGREES F = FAHRENHEIT DEGREES DISCLAIMER: THE INFORMATION HEREIN HAS BEEN COMPILED FROM SOURCES BELEIVED TO BE RELIABLE, UP-TO-DATE, AND IS ACCURATE TO THE BEST OF OUR KNOWLEDGE. HOWEVER, GENOVA PRODUCTS CANNOT GIVE ANY GUARANTEES REGARDING INFORMATION FROM OTHER SOURCES, AND EXPRESSLY DOES NOT MAKE WARRANTIES, NOR ASSUMES ANY LIABILITY FOR ITS USES. Page 623 of 871 Page 623 of 871 Page 623 of 871 Page 623 of 871 ---PAGE BREAK--- MINWAX® POLYSHADES® Interior Stain & Polyurethane Gloss Finish American Chestnut Not available. Liquid. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer : MINWAX Company 10 Mountainview Road Upper Saddle River, NJ 07458 Relevant identified uses of the substance or mixture and uses advised against Not applicable. 475 475 Product code : Product Information Telephone Number : (800) 523-9299 Regulatory Information Telephone Number : (216) 566-2902 Transportation Emergency Telephone Number : (800) 424-9300 Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 3 SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION (Fertility) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation and Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1 Classification of the substance or mixture : Signal word : Danger Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 52.7% OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Flammable liquid and vapor. May cause an allergic skin reaction. Suspected of damaging fertility. Suspected of causing cancer. May be fatal if swallowed and enters airways. May cause respiratory irritation. May cause drowsiness and dizziness. May cause damage to organs through prolonged or repeated exposure. : Hazard statements Date of issue/Date of revision : 6/3/2015. Date of previous issue : 4/6/2015. Version : 1.01 1/12 Page 624 of 871 Page 624 of 871 Page 624 of 871 Page 624 of 871 ---PAGE BREAK--- Section 2. Hazards identification Precautionary statements Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non- sparking tools. Take precautionary measures against static discharge. Keep container closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Contaminated work clothing should not be allowed out of the workplace. Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical attention. Storage : Store locked up. Store in a well-ventilated place. Keep cool. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Hazards not otherwise classified :None known. Please refer to the SDS for additional information. Do not transfer contents to other containers for storage. Supplemental label elements DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue may spontaneously catch fire if improperly discarded. Immediately place rags, steel wool, other waste soaked with this product, and sanding residue in a sealed, water-filled, metal container. Dispose of in accordance with local fire regulations. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. Section 3. Composition/information on ingredients Mineral Spirits (Odorless) 28.7 64742-47-8 Med. Aliphatic Hydrocarbon Solvent 14.8 64742-88-7 Aliphatic Solvent 3.3 64742-47-8 Cobalt Naphthenate 0.2 61789-51-3 Cobalt 0.1 136-52-7 Ingredient name CAS number % by weight There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification : Not available. Substance/mixture CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Date of issue/Date of revision : 6/3/2015. Date of previous issue : 4/6/2015. Version : 1.01 2/12 Page 625 of 871 Page 625 of 871 Page 625 of 871 Page 625 of 871 ---PAGE BREAK--- Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important acute and delayed Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. : Ingestion Skin contact : May cause an allergic skin reaction. No known significant effects or critical hazards. : Eye contact Over-exposure Skin contact Inhalation Adverse may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : Eye contact : No specific data. Potential acute health effects Date of issue/Date of revision : 6/3/2015. Date of previous issue : 4/6/2015. Version : 1.01 3/12 Page 626 of 871 Page 626 of 871 Page 626 of 871 Page 626 of 871 ---PAGE BREAK--- Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Ingestion Adverse may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations : See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use dry chemical, CO₂, water spray (fog) or foam. Extinguishing media : : : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision : 6/3/2015. Date of previous issue : 4/6/2015. Version : 1.01 4/12 Page 627 of 871 Page 627 of 871 Page 627 of 871 Page 627 of 871 ---PAGE BREAK--- Section 6. Accidental release measures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Date of issue/Date of revision : 6/3/2015. Date of previous issue : 4/6/2015. Version : 1.01 5/12 Page 628 of 871 Page 628 of 871 Page 628 of 871 Page 628 of 871 ---PAGE BREAK--- Mineral Spirits (Odorless) ACGIH TLV (United States, 4/2014). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours. Med. Aliphatic Hydrocarbon Solvent OSHA PEL (United States, 2/2013). TWA: 100 ppm 8 hours. TWA: 400 mg/m³ 8 hours. Aliphatic Solvent ACGIH TLV (United States, 4/2014). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours. Cobalt Naphthenate ACGIH TLV (United States, 4/2014). TWA: 0.02 mg/m³, (as Co) 8 hours. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Control parameters Individual protection measures Occupational exposure limits Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Date of issue/Date of revision : 6/3/2015. Date of previous issue : 4/6/2015. Version : 1.01 6/12 Page 629 of 871 Page 629 of 871 Page 629 of 871 Page 629 of 871 ---PAGE BREAK--- Section 8. Exposure controls/personal protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Respiratory protection : Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. 0.92 5 [Air = 1] 0.023 kPa (0.169 mm Hg) [at 20°C] Not available. Not available. Odor pH Not available. Color Evaporation rate 0.13 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: 41°C (105.8°F) [Pensky-Martens Closed Cup] Not available. Not available. Viscosity Kinematic (room temperature): <0.205 cm2/s (<20.5 cSt) Kinematic (40°C (104°F)): <0.205 cm2/s (<20.5 cSt) Not available. Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : 148°C (298.4°F) Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Lower: 1% Upper: 8.8% Decomposition temperature : Not available. Heat of combustion : 0.00002111 kJ/g Aerosol product Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Date of issue/Date of revision : 6/3/2015. Date of previous issue : 4/6/2015. Version : 1.01 7/12 Page 630 of 871 Page 630 of 871 Page 630 of 871 Page 630 of 871 ---PAGE BREAK--- Section 11. Toxicological information Acute toxicity Cobalt Naphthenate LD50 Oral Rat 3900 mg/kg - Cobalt LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat 1.22 g/kg - Product/ingredient name Result Species Dose Exposure Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Irritation/Corrosion Cobalt Naphthenate Eyes - Mild irritant Rabbit - 24 hours 10 milligrams - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Mineral Spirits (Odorless) Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Med. Aliphatic Hydrocarbon Solvent Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Aliphatic Solvent Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Name Category Name Category Mineral Spirits (Odorless) Category 2 Not determined Not determined Med. Aliphatic Hydrocarbon Solvent Category 2 Not determined Not determined Aliphatic Solvent Category 2 Not determined Not determined Aspiration hazard Name Result Med. Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1 Route of exposure Target organs Route of exposure Target organs Information on toxicological effects Classification Cobalt Naphthenate - 2B - Product/ingredient name NTP IARC OSHA Date of issue/Date of revision : 6/3/2015. Date of previous issue : 4/6/2015. Version : 1.01 8/12 Page 631 of 871 Page 631 of 871 Page 631 of 871 Page 631 of 871 ---PAGE BREAK--- Not available. Information on the likely routes of exposure Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. : Ingestion Skin contact : May cause an allergic skin reaction. No known significant effects or critical hazards. : Eye contact May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : No specific data. Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure : Not available. Potential acute health effects Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Date of issue/Date of revision : 6/3/2015. Date of previous issue : 4/6/2015. Version : 1.01 9/12 Page 632 of 871 Page 632 of 871 Page 632 of 871 Page 632 of 871 ---PAGE BREAK--- Developmental effects : No known significant effects or critical hazards. Fertility effects : Suspected of damaging fertility. Numerical measures of toxicity Not available. Acute toxicity estimates Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Cobalt Naphthenate - 15600 high Cobalt - 15600 high Toxicity Mineral Spirits (Odorless) Acute LC50 2200 µg/l Fresh water Fish - Lepomis macrochirus 4 days Aliphatic Solvent Acute LC50 2200 µg/l Fresh water Fish - Lepomis macrochirus 4 days Product/ingredient name Species Result Exposure Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Not available. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. : Disposal methods Section 14. Transport information Date of issue/Date of revision : 6/3/2015. Date of previous issue : 4/6/2015. Version : 1.01 10/12 Page 633 of 871 Page 633 of 871 Page 633 of 871 Page 633 of 871 ---PAGE BREAK--- Section 14. Transport information - - - PAINT 3 III Not regulated. UN1263 Special provisions Not Applicable Emergency schedules (EmS) F-E, S-E DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No. No. : Not available. : TDG Classification Not regulated. - - - No. Special provisions Not Applicable Mexico Classification UN1263 PAINT 3 III No. Special provisions (ERG#128) Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. IATA UN1263 PAINT 3 III No. Special provisions Not Applicable Section 15. Regulatory information U.S. Federal regulations : WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 State regulations Section 16. Other information Hazardous Material Information System 2 2 0 * Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Date of issue/Date of revision : 6/3/2015. Date of previous issue : 4/6/2015. Version : 1.01 11/12 Page 634 of 871 Page 634 of 871 Page 634 of 871 Page 634 of 871 ---PAGE BREAK--- Section 16. Other information It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Notice to reader Date of issue/Date of revision : 6/3/2015. Date of previous issue : 4/6/2015. Version : 1.01 12/12 Page 635 of 871 Page 635 of 871 Page 635 of 871 Page 635 of 871 ---PAGE BREAK--- Powr Off Electrical Contact Cleaner Not available. Aerosol. (888) 426-4851 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer : Lawson Products, Inc. 8770 W. Bryan Mawr, Suite 900 Chicago, IL 60631-3515 7733045050 Relevant identified uses of the substance or mixture and uses advised against Not applicable. 52812 52812 Product code : Section 2. Hazards identification FLAMMABLE AEROSOLS - Category 1 GASES UNDER PRESSURE - Compressed gas SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A TOXIC TO REPRODUCTION (Unborn child) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation and Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1 Classification of the substance or mixture : Signal word : Danger Hazard pictograms : Precautionary statements GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 70.3% General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Causes skin irritation. Suspected of damaging the unborn child. May be fatal if swallowed and enters airways. May cause respiratory irritation. May cause drowsiness and dizziness. May cause damage to organs through prolonged or repeated exposure. : Hazard statements Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.09 1/14 Page 636 of 871 Page 636 of 871 Page 636 of 871 Page 636 of 871 ---PAGE BREAK--- Section 2. Hazards identification Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Pressurized container: Do not pierce or burn, even after use. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist. Wash hands thoroughly after handling. Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 Store in a well-ventilated place. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified :None known. Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do not discard empty can in trash compactor. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY. Section 3. Composition/information on ingredients Heptane 50.3 64742-49-0 Propane 20.0 74-98-6 2-Propanol 10.0 67-63-0 Ethanol 10.0 64-17-5 Cyclohexane 8.0 110-82-7 Toluene 1.7 108-88-3 Ingredient name CAS number % by weight There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification : Not available. Substance/mixture CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.09 2/14 Page 637 of 871 Page 637 of 871 Page 637 of 871 Page 637 of 871 ---PAGE BREAK--- Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important acute and delayed Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach. : Ingestion Skin contact : Causes skin irritation. Causes serious eye irritation. : Eye contact Over-exposure Skin contact Inhalation Adverse may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : Eye contact : Adverse may include the following: pain or irritation watering redness Potential acute health effects Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.09 3/14 Page 638 of 871 Page 638 of 871 Page 638 of 871 Page 638 of 871 ---PAGE BREAK--- Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Ingestion Adverse may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations : See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.09 4/14 Page 639 of 871 Page 639 of 871 Page 639 of 871 Page 639 of 871 ---PAGE BREAK--- Section 6. Accidental release measures Environmental precautions Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. : Precautions for safe handling Propane NIOSH REL (United States, 10/2013). TWA: 1000 ppm 10 hours. TWA: 1800 mg/m³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 1800 mg/m³ 8 hours. 2-Propanol ACGIH TLV (United States, 6/2013). TWA: 200 ppm 8 hours. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.09 5/14 Page 640 of 871 Page 640 of 871 Page 640 of 871 Page 640 of 871 ---PAGE BREAK--- Section 8. Exposure controls/personal protection STEL: 400 ppm 15 minutes. NIOSH REL (United States, 10/2013). TWA: 400 ppm 10 hours. TWA: 980 mg/m³ 10 hours. STEL: 500 ppm 15 minutes. STEL: 1225 mg/m³ 15 minutes. OSHA PEL (United States, 2/2013). TWA: 400 ppm 8 hours. TWA: 980 mg/m³ 8 hours. Ethanol ACGIH TLV (United States, 6/2013). STEL: 1000 ppm 15 minutes. NIOSH REL (United States, 10/2013). TWA: 1000 ppm 10 hours. TWA: 1900 mg/m³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 1900 mg/m³ 8 hours. Cyclohexane ACGIH TLV (United States, 6/2013). TWA: 100 ppm 8 hours. NIOSH REL (United States, 10/2013). TWA: 300 ppm 10 hours. TWA: 1050 mg/m³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 300 ppm 8 hours. TWA: 1050 mg/m³ 8 hours. Toluene OSHA PEL Z2 (United States, 2/2013). TWA: 200 ppm 8 hours. CEIL: 300 ppm AMP: 500 ppm 10 minutes. NIOSH REL (United States, 10/2013). TWA: 100 ppm 10 hours. TWA: 375 mg/m³ 10 hours. STEL: 150 ppm 15 minutes. STEL: 560 mg/m³ 15 minutes. ACGIH TLV (United States, 6/2013). TWA: 20 ppm 8 hours. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.09 6/14 Page 641 of 871 Page 641 of 871 Page 641 of 871 Page 641 of 871 ---PAGE BREAK--- Section 8. Exposure controls/personal protection Hand protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Respiratory protection : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. 0.66 1.5 [Air = 1] 13.5 kPa (101.325 mm Hg) [at 20°C] Not available. Not available. Odor pH Not available. Color Evaporation rate 6.1 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup] Not available. Not available. Viscosity Kinematic (40°C (104°F)): <0.07 cm2/s cSt) Not available. Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Lower: 1% Upper: 19% Decomposition temperature : Not available. Type of aerosol : Spray Heat of combustion : 38.84 kJ/g Aerosol product Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.09 7/14 Page 642 of 871 Page 642 of 871 Page 642 of 871 Page 642 of 871 ---PAGE BREAK--- Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity 2-Propanol LD50 Dermal Rabbit 12800 mg/kg - LD50 Oral Rat 5000 mg/kg - Ethanol LC50 Inhalation Vapor Rat 124700 mg/m³ 4 hours LD50 Oral Rat 7 g/kg - Cyclohexane LD50 Oral Rat 6240 mg/kg - Toluene LC50 Inhalation Vapor Rat 49 g/m³ 4 hours LD50 Oral Rat 636 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion 2-Propanol Eyes - Moderate irritant Rabbit - 24 hours 100 milligrams - Eyes - Moderate irritant Rabbit - 10 milligrams - Eyes - Severe irritant Rabbit - 100 milligrams - Skin - Mild irritant Rabbit - 500 milligrams - Ethanol Eyes - Mild irritant Rabbit - 24 hours 500 milligrams - Eyes - Moderate irritant Rabbit - 0.066666667 minutes 100 milligrams - Eyes - Moderate irritant Rabbit - 100 microliters - Eyes - Severe irritant Rabbit - 500 milligrams - Skin - Mild irritant Rabbit - 400 milligrams - Skin - Moderate irritant Rabbit - 24 hours 20 milligrams - Toluene Eyes - Mild irritant Rabbit - 0.5 minutes 100 milligrams - Eyes - Mild irritant Rabbit - 870 Micrograms - Eyes - Severe irritant Rabbit - 24 hours 2 milligrams - Product/ingredient name Result Score Exposure Observation Species Information on toxicological effects Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.09 8/14 Page 643 of 871 Page 643 of 871 Page 643 of 871 Page 643 of 871 ---PAGE BREAK--- Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Skin - Mild irritant Pig - 24 hours 250 microliters - Skin - Mild irritant Rabbit - 435 milligrams - Skin - Moderate irritant Rabbit - 24 hours 20 milligrams - Skin - Moderate irritant Rabbit - 500 milligrams - Sensitization Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Heptane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Propane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects 2-Propanol Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Ethanol Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Cyclohexane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Toluene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Name Category Route of exposure Target organs Classification 2-Propanol - 3 - Toluene - 3 - Product/ingredient name NTP IARC OSHA Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.09 9/14 Page 644 of 871 Page 644 of 871 Page 644 of 871 Page 644 of 871 ---PAGE BREAK--- Section 11. Toxicological information Name Category Heptane Category 2 Not determined Not determined Propane Category 2 Not determined Not determined 2-Propanol Category 2 Not determined Not determined Ethanol Category 2 Not determined Not determined Cyclohexane Category 2 Not determined Not determined Toluene Category 2 Not determined Not determined Aspiration hazard Name Result Heptane ASPIRATION HAZARD - Category 1 Route of exposure Target organs Information on the likely routes of exposure Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach. : Ingestion Skin contact : Causes skin irritation. Causes serious eye irritation. : Eye contact related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : Adverse may include the following: pain or irritation watering redness Delayed and immediate effects and also chronic effects from short and long term exposure : Not available. Potential acute health effects Short term exposure Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.09 10/14 Page 645 of 871 Page 645 of 871 Page 645 of 871 Page 645 of 871 ---PAGE BREAK--- Not available. May cause damage to organs through prolonged or repeated exposure. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : Suspected of damaging the unborn child. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Potential chronic health effects Numerical measures of toxicity Oral 6325.1 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Section 12. Ecological information Toxicity 2-Propanol Acute LC50 1400000 µg/l Marine water Crustaceans - Crangon crangon 48 hours Acute LC50 1400000 µg/l Fish - Gambusia affinis 96 hours Ethanol Acute EC50 17.921 mg/l Marine water Algae - Ulva pertusa 96 hours Acute EC50 2000 µg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 25500 µg/l Marine water Crustaceans - Artemia franciscana - Larvae 48 hours Acute LC50 42000 µg/l Fresh water Fish - mykiss 4 days Chronic NOEC 4.995 mg/l Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 0.375 ul/L Fresh water Fish - Gambusia holbrooki - Larvae 12 weeks Cyclohexane Acute LC50 4530 µg/l Fresh water Fish - Pimephales promelas 96 hours Toluene Acute EC50 433 ppm Marine water Algae - Skeletonema costatum 96 hours Acute EC50 12500 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 11600 µg/l Fresh water Crustaceans - Gammarus pseudolimnaeus - Adult 48 hours Acute EC50 6000 µg/l Fresh water Daphnia - Daphnia magna - Juvenile (Fledgling, Hatchling, Weanling) 48 hours Acute LC50 5500 µg/l Fresh water Fish - kisutch - Fry 96 hours Chronic NOEC 500000 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Chronic NOEC 1000 µg/l Fresh water Daphnia - Daphnia magna 21 days Product/ingredient name Species Result Exposure Persistence and degradability Not available. Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.09 11/14 Page 646 of 871 Page 646 of 871 Page 646 of 871 Page 646 of 871 ---PAGE BREAK--- Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Heptane - 10 to 2500 high Cyclohexane - 167 low Toluene - 90 low Soil/water partition coefficient (KOC) : Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. : Disposal methods Section 14. Transport information AEROSOLS 2.1 - AEROSOLS 2.1 - UN1950 UN1950 Special provisions LIMITED QUANTITY Emergency schedules (EmS) LIMITED QUANTITY, F-D, S-U DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards No. No. TDG Classification UN1950 AEROSOLS 2.1 - No. Special provisions LIMITED QUANTITY Mexico Classification UN1950 AEROSOLS 2.1 - No. Special provisions (ERG#126) IATA UN1950 AEROSOLS, flammable 2.1 - No. Special provisions LIMITED QUANTITY Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.09 12/14 Page 647 of 871 Page 647 of 871 Page 647 of 871 Page 647 of 871 ---PAGE BREAK--- Section 14. Transport information Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Not available. : Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. Section 15. Regulatory information U.S. Federal regulations : SARA 313 SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 State regulations Section 16. Other information Notice to reader Hazardous Material Information System 2 4 0 Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). The customer is responsible for determining the PPE code for this material. Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.09 13/14 Page 648 of 871 Page 648 of 871 Page 648 of 871 Page 648 of 871 ---PAGE BREAK--- Section 16. Other information It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.09 14/14 Page 649 of 871 Page 649 of 871 Page 649 of 871 Page 649 of 871 ---PAGE BREAK--- page 1 of 4 HMIS Codes Health 1* Flammability 0 Reactivity 0 DATE OF PREPARATION Jun 27, 2015 MATERIAL SAFETY DATA SHEET B20W1151 14 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER B20W1151 PRODUCT NAME ProClassic® Waterborne Interior Acrylic Satin Finish, Extra White MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 Telephone Numbers and Websites Product Information www.sherwin-williams.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 6 14808-60-7 Quartz ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.1 mg/m3 as Resp. Dust 0.1 14464-46-1 Cristobalite ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.05 mg/m3 as Resp. Dust 21 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. Page 650 of 871 Page 650 of 871 Page 650 of 871 Page 650 of 871 ---PAGE BREAK--- B20W1151 page 2 of 4 UEL Not Applicable LEL Not Applicable FLASH POINT Not Applicable SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Required for long or repeated contact. EYE PROTECTION Wear safety spectacles with unperforated sideshields. Page 651 of 871 Page 651 of 871 Page 651 of 871 Page 651 of 871 ---PAGE BREAK--- B20W1151 page 3 of 4 SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 10.52 lb/gal 1260 g/l SPECIFIC GRAVITY 1.27 BOILING POINT 212 - 213 °F 100 - 100 °C MELTING POINT Not Available VOLATILE VOLUME 69% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available pH > 2.0, < 11.5 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.27 lb/gal 32 g/l Less Water and Federally Exempt Solvents 0.08 lb/gal 10 g/l Emitted VOC SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." TOXICOLOGY DATA CAS No. Ingredient Name 14808-60-7 Quartz LC50 RAT 4HR Not Available LD50 RAT Not Available 14464-46-1 Cristobalite LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Page 652 of 871 Page 652 of 871 Page 652 of 871 Page 652 of 871 ---PAGE BREAK--- B20W1151 page 4 of 4 SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. IMO Not Regulated for Transportation. IATA/ICAO Not Regulated for Transportation. SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 653 of 871 Page 653 of 871 Page 653 of 871 Page 653 of 871 ---PAGE BREAK--- Page 654 of 871 Page 654 of 871 Page 654 of 871 Page 654 of 871 ---PAGE BREAK--- Page 655 of 871 Page 655 of 871 Page 655 of 871 Page 655 of 871 ---PAGE BREAK--- Page 656 of 871 Page 656 of 871 Page 656 of 871 Page 656 of 871 ---PAGE BREAK--- Page 657 of 871 Page 657 of 871 Page 657 of 871 Page 657 of 871 ---PAGE BREAK--- page 1 of 5 HMIS Codes Health 2* Flammability 3 Reactivity 0 DATE OF PREPARATION Feb 10, 2015 MATERIAL SAFETY DATA SHEET TM5495 14 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER TM5495 PRODUCT NAME PROMAR® Zone Marking Paint (Conventional Alkyd), Lead Free Yellow MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 Telephone Numbers and Websites Product Information (800) 524-5979 www.sherwin-williams.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 19 64742-89-8 Lt. Aliphatic Hydrocarbon Solvent ACGIH TLV 300 PPM 12 mm OSHA PEL 300 PPM 5 108-88-3 Toluene ACGIH TLV 20 PPM 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 0.2 100-41-4 ACGIH TLV 20 PPM 7.1 mm OSHA PEL 100 PPM OSHA PEL 125 PPM STEL 1 1330-20-7 Xylene ACGIH TLV 100 PPM 5.9 mm ACGIH TLV 150 PPM STEL OSHA PEL 100 PPM OSHA PEL 150 PPM STEL 0.1 14808-60-7 Quartz ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.1 mg/m3 as Resp. Dust 1 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Page 658 of 871 Page 658 of 871 Page 658 of 871 Page 658 of 871 ---PAGE BREAK--- TM5495 page 2 of 5 UEL 7.0 LEL 0.9 FLASH POINT 16 °F PMCC Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system the cardiovascular system the reproductive system SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION RED LABEL Extremely Flammable, Flash below 21 °F EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY DOL Storage Class IB PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Contents are EXTREMELY FLAMMABLE. Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. Page 659 of 871 Page 659 of 871 Page 659 of 871 Page 659 of 871 ---PAGE BREAK--- TM5495 page 3 of 5 RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 11.79 lb/gal 1413 g/l SPECIFIC GRAVITY 1.42 BOILING POINT 222 - 325 °F 105 - 162 °C MELTING POINT Not Available VOLATILE VOLUME 46% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 2.97 lb/gal 356 g/l Less Water and Federally Exempt Solvents 2.97 lb/gal 356 g/l Emitted VOC SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that causes cancer in humans. Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." Page 660 of 871 Page 660 of 871 Page 660 of 871 Page 660 of 871 ---PAGE BREAK--- TM5495 page 4 of 5 TOXICOLOGY DATA CAS No. Ingredient Name 64742-89-8 Lt. Aliphatic Hydrocarbon Solvent LC50 RAT 4HR Not Available LD50 RAT Not Available 108-88-3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 100-41-4 LC50 RAT 4HR Not Available LD50 RAT 3500 mg/kg 1330-20-7 Xylene LC50 RAT 4HR 5000 ppm LD50 RAT 4300 mg/kg 14808-60-7 Quartz LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) 5 Liters (1.3 Gallons) and Less may be Classed as LTD. QTY. (PAINT OR RELATED)., DO NOT FREEZE Larger Containers are Regulated as: UN1263, PAINT, 3, PG II, (ERG#128), DO NOT FREEZE DOT (Dept of Transportation) Hazardous Substances & Reportable Quantities Toluene 1000 lb RQ Xylenes (isomers and mixture) 100 lb RQ Bulk Containers may be Shipped as (check reportable quantities): UN1263, PAINT, 3, PG II, (ERG#128), DO NOT FREEZE Canada (TDG) UN1263, PAINT, CLASS 3, PG II, LIMITED QUANTITY, (ERG#128), DO NOT FREEZE IMO 5 Liters (1.3 Gallons) and Less may be Shipped as Limited Quantity. UN1263, PAINT, CLASS 3, PG II, C EmS F-E, , DO NOT S-E FREEZE IMO 5 Liters (1.3 Gallons) and Less may be Shipped as Limited Quantity. UN1263, PAINT, CLASS 3, PG II, C EmS F-E, , DO NOT S-E FREEZE IATA/ICAO UN1263, PAINT, 3, PG II, DO NOT FREEZE Page 661 of 871 Page 661 of 871 Page 661 of 871 Page 661 of 871 ---PAGE BREAK--- TM5495 page 5 of 5 SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 108-88-3 Toluene 5 100-41-4 0.1 1330-20-7 Xylene 1 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 662 of 871 Page 662 of 871 Page 662 of 871 Page 662 of 871 ---PAGE BREAK--- page 1 of 4 HMIS Codes Health 2* Flammability 0 Reactivity 0 DATE OF PREPARATION Apr 16, 2015 MATERIAL SAFETY DATA SHEET B20W2251 25 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER B20W2251 PRODUCT NAME PROMAR® 200 Interior Latex Eg-Shel Enamel, Extra White MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 Telephone Numbers and Websites Product Information www.sherwin-williams.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 2 107-21-1 Ethylene Glycol ACGIH TLV 100 MG/M3 CEILING (aerosol) 0.12 mm OSHA PEL 50 PPM CEILING 0.1 14464-46-1 Cristobalite ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.05 mg/m3 as Resp. Dust 15 1317-65-3 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 13 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Page 663 of 871 Page 663 of 871 Page 663 of 871 Page 663 of 871 ---PAGE BREAK--- B20W2251 page 2 of 4 UEL Not Applicable LEL Not Applicable FLASH POINT Not Applicable SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. Page 664 of 871 Page 664 of 871 Page 664 of 871 Page 664 of 871 ---PAGE BREAK--- B20W2251 page 3 of 4 SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 10.77 lb/gal 1290 g/l SPECIFIC GRAVITY 1.30 BOILING POINT 212 - 388 °F 100 - 197 °C MELTING POINT Not Available VOLATILE VOLUME 58% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available pH > 2.0, < 11.5 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.78 lb/gal 93 g/l Less Water and Federally Exempt Solvents 0.35 lb/gal 42 g/l Emitted VOC SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." Ethylene Glycol is considered an animal teratogen. It has been shown to cause birth defects in rats and mice at high doses when given in drinking water or by gavage. There is no evidence to indicate it causes birth defects in humans. TOXICOLOGY DATA CAS No. Ingredient Name 107-21-1 Ethylene Glycol LC50 RAT 4HR Not Available LD50 RAT 4700 mg/kg 14464-46-1 Cristobalite LC50 RAT 4HR Not Available LD50 RAT Not Available 1317-65-3 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Page 665 of 871 Page 665 of 871 Page 665 of 871 Page 665 of 871 ---PAGE BREAK--- B20W2251 page 4 of 4 SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. IMO Not Regulated for Transportation. IATA/ICAO Not Regulated for Transportation. SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 107-21-1 Ethylene Glycol 2 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 666 of 871 Page 666 of 871 Page 666 of 871 Page 666 of 871 ---PAGE BREAK--- Page 667 of 871 Page 667 of 871 Page 667 of 871 Page 667 of 871 ---PAGE BREAK--- Page 668 of 871 Page 668 of 871 Page 668 of 871 Page 668 of 871 ---PAGE BREAK--- Page 669 of 871 Page 669 of 871 Page 669 of 871 Page 669 of 871 ---PAGE BREAK--- Page 670 of 871 Page 670 of 871 Page 670 of 871 Page 670 of 871 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Oatey Purple Primer- NSF Listed for PVC and CPVC Product identifier Other means of identification 1402E Product code Part Numbers: 30755(TV), 30756(TV), 30757(TV), 30758, 30759, 30927 Synonyms Joining PVC Pipes Recommended use None known. Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Company Name Oatey Co. Address 4700 West 160th St. Cleveland, OH 44135 Telephone [PHONE REDACTED] E-mail [EMAIL REDACTED] Transport Emergency Chemtrec 1-[PHONE REDACTED] (Outside the US 1-[PHONE REDACTED]) Emergency First Aid 1-[PHONE REDACTED] Contact person MSDS Coordinator 2. Hazard(s) identification Category 2 Flammable liquids Physical hazards Category 4 Acute toxicity, oral Health hazards Category 2 Skin corrosion/irritation Category 2A Serious eye damage/eye irritation Category 3 respiratory tract irritation Specific target organ toxicity, single exposure Category 3 narcotic effects Specific target organ toxicity, single exposure Category 1 Aspiration hazard Not classified. OSHA defined hazards Label elements Signal word Danger Hazard statement Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Response If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use appropriate media to extinguish. Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US 926733 Version 01 Revision date: - Issue date: 27-May-2015 1 / 10 Page 671 of 871 Page 671 of 871 Page 671 of 871 Page 671 of 871 ---PAGE BREAK--- Storage Store in a well-ventilated place. Keep container closed. Keep cool. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. May form explosive peroxides. Contains a chemical classified by the US EPA as a suspected possible carcinogen. Supplemental information Not applicable. 3. Composition/information on ingredients Mixtures 67-64-1 25-40 Acetone CAS number % Chemical name 108-94-1 25-40 Cyclohexanone 109-99-9 15-30 Furan, Tetrahydro- 78-93-3 15-30 Methyl ethyl ketone *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Inhalation Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Eye contact Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may cause pulmonary edema and pneumonitis. Ingestion Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Skin irritation. May cause redness and pain. Most important acute and delayed Provide general supportive measures and treat Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. may be delayed. Indication of immediate medical attention and special treatment needed Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. General information 5. Fire-fighting measures Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2). Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Unsuitable extinguishing media Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Special protective equipment and precautions for firefighters In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Specific methods Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive organic peroxide when exposed to air or light or with age. General fire hazards Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US 926733 Version 01 Revision date: - Issue date: 27-May-2015 2 / 10 Page 672 of 871 Page 672 of 871 Page 672 of 871 Page 672 of 871 ---PAGE BREAK--- 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid discharge into drains, water courses or onto the ground. Environmental precautions 7. Handling and storage Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof general and local exhaust ventilation. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Precautions for safe handling Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in a cool, dry place out of direct sunlight. Store in original closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Type Components PEL 2400 mg/m3 Acetone (CAS 67-64-1) 1000 ppm PEL 200 mg/m3 Cyclohexanone (CAS 108-94-1) 50 ppm PEL 590 mg/m3 Furan, Tetrahydro- (CAS 109-99-9) 200 ppm PEL 590 mg/m3 Methyl ethyl ketone (CAS 78-93-3) 200 ppm US. ACGIH Threshold Limit Values Value Type Components STEL 750 ppm Acetone (CAS 67-64-1) TWA 500 ppm STEL 50 ppm Cyclohexanone (CAS 108-94-1) TWA 20 ppm STEL 100 ppm Furan, Tetrahydro- (CAS 109-99-9) Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US 926733 Version 01 Revision date: - Issue date: 27-May-2015 3 / 10 Page 673 of 871 Page 673 of 871 Page 673 of 871 Page 673 of 871 ---PAGE BREAK--- US. ACGIH Threshold Limit Values Value Type Components TWA 50 ppm STEL 300 ppm Methyl ethyl ketone (CAS 78-93-3) TWA 200 ppm US. NIOSH: Pocket Guide to Chemical Hazards Value Type Components TWA 590 mg/m3 Acetone (CAS 67-64-1) 250 ppm TWA 100 mg/m3 Cyclohexanone (CAS 108-94-1) 25 ppm STEL 735 mg/m3 Furan, Tetrahydro- (CAS 109-99-9) 250 ppm TWA 590 mg/m3 200 ppm STEL 885 mg/m3 Methyl ethyl ketone (CAS 78-93-3) 300 ppm TWA 590 mg/m3 200 ppm Biological limit values ACGIH Biological Exposure Indices Value Sampling Time Determinant Specimen Components 50 mg/l Acetone Urine * Acetone (CAS 67-64-1) 80 mg/l 1,2-Cyclohexan ediol, with hydrolysis Urine * Cyclohexanone (CAS 108-94-1) 8 mg/l Cyclohexanol, with hydrolysis Urine * 2 mg/l Tetrahydrofura n Urine * Furan, Tetrahydro- (CAS 109-99-9) 2 mg/l MEK Urine * Methyl ethyl ketone (CAS 78-93-3) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies Cyclohexanone (CAS 108-94-1) Skin designation applies. US - Tennessee OELs: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. Furan, Tetrahydro- (CAS 109-99-9) Can be absorbed through the skin. US. NIOSH: Pocket Guide to Chemical Hazards Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Appropriate engineering controls Individual protection measures, such as personal protective equipment Face shield is recommended. Wear safety glasses with side shields (or goggles). Eye/face protection Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US 926733 Version 01 Revision date: - Issue date: 27-May-2015 4 / 10 Page 674 of 871 Page 674 of 871 Page 674 of 871 Page 674 of 871 ---PAGE BREAK--- Skin protection Wear appropriate chemical resistant gloves. Hand protection Wear appropriate chemical resistant clothing. Other If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Respiratory protection Wear appropriate thermal protective clothing, when necessary. Thermal hazards When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Appearance Liquid. Physical state Translucent liquid. Form Purple Color Solvent. Odor Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 151 °F (66.11 Flash point 14.0 - 23.0 °F (-10.0 - -5.0 Evaporation rate 5.5 - 8 Not available. Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower 1.8 Flammability limit - upper 11.8 Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 145 mm Hg @ 20 C Vapor density 2.5 Relative density 0.84 0.02 @20°C Solubility(ies) Solubility (water) Negligible Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Bulk density 7 lb/gal VOC (Weight 505 g/l SQACMD Method 24 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Reactivity Material is stable under normal conditions. Chemical stability No dangerous reaction known under conditions of normal use. Possibility of hazardous reactions Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Conditions to avoid Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics. Incompatible materials Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US 926733 Version 01 Revision date: - Issue date: 27-May-2015 5 / 10 Page 675 of 871 Page 675 of 871 Page 675 of 871 Page 675 of 871 ---PAGE BREAK--- No hazardous decomposition products are known. Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation May be fatal if swallowed and enters airways. Headache. Nausea, vomiting. May cause irritation to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. Skin contact Causes skin irritation. Eye contact Causes serious eye irritation. Ingestion May be fatal if swallowed and enters airways. Harmful if swallowed. Harmful if swallowed. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. related to the physical, chemical and toxicological characteristics Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause redness and pain. of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Information on toxicological effects Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation. Test Results Components Species Acetone (CAS 67-64-1) LD50 Rabbit Dermal Acute 20 ml/kg LC50 Rat Inhalation 50 mg/l, 8 Hours LD50 Rat Oral 5800 mg/kg Cyclohexanone (CAS 108-94-1) LD50 Rabbit Dermal Acute 948 mg/kg LC50 Rat Inhalation 8000 ppm, 4 hours LD50 Rat Oral 1540 mg/kg * Estimates for product may be based on additional component data not shown. Causes skin irritation. Skin corrosion/irritation Causes serious eye irritation. Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not available. This product is not expected to cause skin sensitization. Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalation lifetime study on THF conducted by NTP (1998). Male rats developed renal tumors and female mice developed liver tumors while neither the female rats nor the male mice showed similar results. Because the carcinogenic mechanisms could not be identified clearly in either species for either tumor, the EPA determined that the male rat and female mouse findings are relevant to the assessment of carcinogenic potential in humans. Therefore, the IRIS review concludes that these data in aggregate indicate that there is "suggestive evidence of carcinogenic potential" following exposure to THF by all routes of exposure. IARC Monographs. Overall Evaluation of Carcinogenicity Cyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans. Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US 926733 Version 01 Revision date: - Issue date: 27-May-2015 6 / 10 Page 676 of 871 Page 676 of 871 Page 676 of 871 Page 676 of 871 ---PAGE BREAK--- OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. This product is not expected to cause reproductive or developmental effects. Reproductive toxicity Specific target organ toxicity - single exposure Narcotic effects. May cause drowsiness and dizziness. Respiratory tract irritation. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard May be fatal if swallowed and enters airways. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Ecotoxicity Components Test Results Species Acetone (CAS 67-64-1) Aquatic LC50 Fish > 100 mg/l, 96 hours Fathead minnow (Pimephales promelas) * Estimates for product may be based on additional component data not shown. Cyclohexanone (CAS 108-94-1) Aquatic LC50 Fish 481 - 578 mg/l, 96 hours Fathead minnow (Pimephales promelas) No data is available on the degradability of this product. Persistence and degradability No data available. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Acetone (CAS 67-64-1) -0.24 Cyclohexanone (CAS 108-94-1) 0.81 Furan, Tetrahydro- (CAS 109-99-9) 0.46 Methyl ethyl ketone (CAS 78-93-3) 0.29 No data available. Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations. Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Contaminated packaging 14. Transport information DOT UN1993 UN number Flammable liquids, n.o.s. (Methyl ethyl ketone RQ = 26274 LBS, Acetone RQ = 13130 LBS) UN proper shipping name 3 Class Transport hazard class(es) - Subsidiary risk 3 Label(s) II Packing group Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US 926733 Version 01 Revision date: - Issue date: 27-May-2015 7 / 10 Page 677 of 871 Page 677 of 871 Page 677 of 871 Page 677 of 871 ---PAGE BREAK--- Read safety instructions, SDS and emergency procedures before handling. Special precautions for user IB2, T7, TP1, TP8, TP28 Special provisions 150 Packaging exceptions 202 Packaging non bulk 242 Packaging bulk IATA UN1993 UN number Flammable liquid, n.o.s. (Methyl ethyl ketone, Acetone) UN proper shipping name 3 Class Transport hazard class(es) - Subsidiary risk II Packing group No. Environmental hazards 3H ERG Code Read safety instructions, SDS and emergency procedures before handling. Special precautions for user IMDG UN1993 UN number FLAMMABLE LIQUID, N.O.S. (Methyl ethyl ketone, Acetone) UN proper shipping name 3 Class Transport hazard class(es) - Subsidiary risk II Packing group No. Marine pollutant Environmental hazards F-E, S-E EmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Not available. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1) LISTED Cyclohexanone (CAS 108-94-1) LISTED Furan, Tetrahydro- (CAS 109-99-9) LISTED Methyl ethyl ketone (CAS 78-93-3) LISTED Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Hazard categories SARA 302 Extremely hazardous substance Not listed. No SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Not regulated. Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US 926733 Version 01 Revision date: - Issue date: 27-May-2015 8 / 10 Page 678 of 871 Page 678 of 871 Page 678 of 871 Page 678 of 871 ---PAGE BREAK--- Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated. Safe Drinking Water Act (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1) 6532 Methyl ethyl ketone (CAS 78-93-3) 6714 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1) 35 %WV Methyl ethyl ketone (CAS 78-93-3) 35 %WV DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1) 6532 Methyl ethyl ketone (CAS 78-93-3) 6714 US state regulations US. Massachusetts RTK - Substance List Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. New Jersey Worker and Community Right-to-Know Act Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. Rhode Island RTK Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Domestic Substances List (DSL) Yes Canada *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Toxic Substances Control Act (TSCA) Inventory Yes United States & Puerto Rico 16. Other information, including date of preparation or last revision 27-May-2015 Issue date - Revision date Version # 01 Health: 2 Flammability: 3 Physical hazard: 0 HMIS® ratings Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US 926733 Version 01 Revision date: - Issue date: 27-May-2015 9 / 10 Page 679 of 871 Page 679 of 871 Page 679 of 871 Page 679 of 871 ---PAGE BREAK--- NFPA ratings 0 2 3 The information in the sheet was written based on the best knowledge and experience currently available. Oatey Co. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. Disclaimer Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US 926733 Version 01 Revision date: - Issue date: 27-May-2015 10 / 10 Page 680 of 871 Page 680 of 871 Page 680 of 871 Page 680 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 10-Jul-2012 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 88800 Product name Rapid Repair Epoxy Recommended Use Repair Material Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Inhalation. Skin contact. Eyes. Ingestion. Potential health effects Eyes Direct contact will cause the following effects:. Moderately irritating to the eyes. Skin Prolonged skin contact may cause skin irritation. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. Sensitization. Inhalation May cause irritation of respiratory tract. Coughing. Ingestion Irritation of the gastrointestinal system. Discomfort. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Zinc Sulfide 1314-98-3 Talc (Mg3H2(SiO3)4) 14807-96-6 Quartz Silica) 14808-60-7 Epoxy Resin 25036-25-3 Bisphenol A - Epichlorohydrin polymer 25068-38-6 2,4,6- Tri(dimethylaminomethyl)phe nol 90-72-2 4. FIRST AID MEASURES Eye contact Flush with plenty of water for at least 15 minutes. If effects occur, consult a physician, preferably an ophthalmologist. Skin contact Wash off immediately with soap and plenty of water. Seek medical attention if irritation persists. Ingestion Do Not induce vomiting. If effects occur, seek medical attention immediately. Inhalation Remove to fresh air. Get medical attention if cough or respiratory develop. Seek medical attention immediately. Notes to physician Treat 5. FIRE FIGHTING MEASURES Flash point °C > 93 Flash point °F > 200 Method Seta closed cup Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper No data available Lower No data available Suitable extinguishing media Foam. Alcohol foam. Carbon dioxide (CO2). Dry chemical powder. Water fog. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Special Fire-Fighting Procedures Extinguish preferably with waterspray. Cool containers / tanks with water spray . Sensitivity to shock No information available. Page 1 / 4 Emergency Overview May cause eye/skin irritation. May cause irritation of respiratory tract. Page 681 of 871 Page 681 of 871 Page 681 of 871 Page 681 of 871 ---PAGE BREAK--- Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Environmental precautions Should not be released into the environment. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. Methods for cleaning up Personnel should wear appropriate protective equipment. Follow all precautions for handling. Please refer to appropriate sections of MSDS for additional information. Evacuate area of unprotected and unnecessary personnel. Ventilate area to maintain exposure below permissible exposure limits. Sweep up and shovel into suitable containers for disposal. Use caution as spill may create a slip hazard. Dispose in accordance with local, state and federal regulations. 7. HANDLING AND STORAGE Handling Wear personal protective equipment. In case of insufficient ventilation, wear suitable respiratory equipment. Observe all precautions even after container is emptied. Avoid contact with skin, eyes and clothing. Do not reuse containers. Must not come in contact with food. Keep out of reach of pets and domestic animals. Storage Keep containers closed in a cool, well-ventilated place. Keep container away from heat, sparks and flame . Keep away from heat and sources of ignition. Prevent moist air from entering storage tanks or containers. Store in original container. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Bisphenol A - Epichlorohydri n polymer - - - - Epoxy Resin - - - - 2,4,6- Tri(dimethyla minomethyl)p henol - - - - Zinc Sulfide - - - - Quartz Silica) - - 0.025 mg/m3 - Talc (Mg3H2(SiO3 - - 2 mg/m3 - Ventilation and Environmental Controls Provide local exhaust ventilation. Ensure adequate ventilation, especially in confined areas. Adequate ventilation should be provided to keep exposure levels below current acceptable exposure limits. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. A safety shower and eye wash station should be available for emergency use. Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. Wear a NIOSH approved organic vapor respirator. P100 filter. For emergency or non-routine operations (cleaning spills, reactor vessel, or storage tanks), wear self- contained breathing apparatus . Use a positive pressure supplied air respirator. Hand Protection Chemical resistant gloves. Eye protection Wear safety glasses with side shields. Goggles. Skin and body protection Wear suitable protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Paste / Solid Color Black / White Odor Pungent / Sulfur Odor Threshold No information available pH Not Applicable Specific Gravity 1.92 Vapor pressure No data available Density 15.97 lb/gal Vapor density No data available Evaporation Rate No data available Water solubility Insoluble in water Partition Coefficient (n-octanol/water) No data available Boiling point/range °C No data available Boiling point/range °F No data available Melting point/range °C No data available Melting point/range °F No data available Flash point °C > 93 Flash point °F > 200 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid None known. Incompatability Strong oxidizers. Acids. Bases. Page 2 / 4 Product code 88800 Product name Rapid Repair Epoxy Page 682 of 871 Page 682 of 871 Page 682 of 871 Page 682 of 871 ---PAGE BREAK--- Hazardous Decomposition Products Carbon dioxide. Aldehydes. Acids. Nitrogen oxides (NOx). Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Bisphenol A - Epichlorohydrin polymer 25068-38-6 11400 mg/kg - - Epoxy Resin 25036-25-3 - - - 2,4,6- Tri(dimethylamino methyl)phenol 90-72-2 1000 mg/kg 1280 mg/kg - Zinc Sulfide 1314-98-3 2 g/kg 2 g/kg 5040 mg/m3 Quartz Silica) 14808-60-7 500 mg/kg - - Talc (Mg3H2(SiO3)4) 14807-96-6 - - - Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity Chronic respiratory disease has been observed in workers exposed to up to 3.0 mg/m3 of airborne talc ore free of asbestos and silica. Early of silicosis include cough, mucous production and shortness of breath upon exertion. Product is a non respirable form. Silica Quartz CAS 14808-60-7: Toxic effects (Humans) - fibrosis, pneumoconiosis, cough, difficult breathing. Mutagenic effects Silica Quartz CAS 14808-60-7: Mutagenic effects have occurred in humans. Teratogenic effects None known Reproductive toxicity None known Target Organ Effects See Section 2 Carcinogenic effects Silica, Quartz CAS 14808-60-7: ACGIH, A2 - Suspected Human Carcinogen, IARC, Group 1 - Carcinogenic to Humans, Monograph 100C, Monograph 68. Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Bisphenol A - Epichlorohydri n polymer Not Listed Not Listed Not Listed Not Listed Not Listed Epoxy Resin Not Listed Not Listed Not Listed Not Listed Not Listed 2,4,6- Tri(dimethyla minomethyl)p henol Not Listed Not Listed Not Listed Not Listed Not Listed Zinc Sulfide Not Listed Not Listed Not Listed Not Listed Not Listed Quartz Silica) A2 Group 1 Known Human Carcinoge n Not Listed Listed Talc (Mg3H2(SiO3 A4 Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Ecotoxicity effects No ozone depleting chemical(s) are present in this product 13. DISPOSAL CONSIDERATIONS Disposal Information Dispose in accordance with federal, state, and local regulations. The following US EPA Hazardous Waste Numbers are applicable to the unadulterated product if it enters the "waste stream": None. 14. TRANSPORTATION INFORMATION DOT Not Regulated. TDG Not Regulated 15. REGULATORY INFORMATION US EPA SARA 313 This product contains no listed chemicals subject to reporting Chemical Name US EPA SARA 313 Emission Reporting Zinc Sulfide Listed Page 3 / 4 Product code 88800 Product name Rapid Repair Epoxy Page 683 of 871 Page 683 of 871 Page 683 of 871 Page 683 of 871 ---PAGE BREAK--- State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Bisphenol A - Epichlorohydrin polymer Not Listed Not Listed Not Listed Epoxy Resin Not Listed Not Listed Not Listed 2,4,6- Tri(dimethylaminomethyl)phe nol Not Listed Not Listed Not Listed Zinc Sulfide Not Listed Not Listed Not Listed Quartz Silica) Not Listed Listed Carcinogen Talc (Mg3H2(SiO3)4) Not Listed Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA Bisphenol A - Epichlorohydrin polymer - X - X Epoxy Resin - X - X 2,4,6- Tri(dimethylaminomethyl)phe nol X X - X Zinc Sulfide X X - X Quartz Silica) X X - X Talc (Mg3H2(SiO3)4) X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION HMIS Health - 1 Flammability - 0 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product code 88800 Product name Rapid Repair Epoxy Page 684 of 871 Page 684 of 871 Page 684 of 871 Page 684 of 871 ---PAGE BREAK--- Material Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION Product Name REGAL PREMIUM INTERIOR LATEX MATTE FINISH Product Code N221 Product Class WATER THINNED PAINT Color All 2. COMPOSITION INFORMATION ON COMPONENTS Hazardous Components Chemical Name CAS-No Weight % (max) Titanium dioxide 13463-67-7 25 Nepheline syenite 37244-96-5 20 Limestone 1317-65-3 10 Kaolin, calcined 66402-68-4 5 Diatomaceous earth 61790-53-2 5 Silica, amorphous 7631-86-9 5 3. HAZARDS IDENTIFICATION Potential Health Effects Principal Routes of Exposure Eye contact, skin contact and inhalation. Acute Effects Eyes May cause slight irritation. Skin Substance may cause slight skin irritation. Inhalation May cause irritation of respiratory tract. Page 1 / 8 Emergency Telephone Number(s) CHEMTREC: [PHONE REDACTED] Emergency Overview Revision Number: 3 Vapors may be irritating to eyes, nose, throat, and lungs. May cause skin irritation and/or dermatitis. Manufacturer Benjamin Moore & Co. 101 Paragon Drive Montvale, NJ 07645 Phone: [PHONE REDACTED] www.benjaminmoore.com Revision Date: 03-Jun-2009 Appearance liquid Odor little or no odor Page 685 of 871 Page 685 of 871 Page 685 of 871 Page 685 of 871 ---PAGE BREAK--- Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Chronic Effects Repeated contact may cause allergic reactions in very susceptible persons. See Section 11 for additional Toxicological information. Aggravated Medical Conditions None known Note: The PPE rating has intentionally been left blank. Choose appropriate PPE that will protect employees from the hazards the material will present under the actual normal conditions of use. Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings are not required on under 29 CFR 1910.1200, Benjamin Moore & Co., has choosen to provide them. HMIS® ratings are to be used only in conjunction with a fully implemented HMIS® program by workers who have received appropriate HMIS® training. HMIS® is a registered trade and service mark of the NPCA. HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. 4. FIRST AID MEASURES General Advice No hazards which require special first aid measures. Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Skin Contact Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. Inhalation Move to fresh air. If persist, call a physician. Ingestion Clean mouth with water and afterwards drink plenty of water. Consult a physician if necessary. Notes To Physician Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Protective Equipment And Precautions For Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 2 / 8 PPE: - HMIS HMIS Legend 0 - Minimal Hazard 1 - Slight Hazard 2 - Moderate Hazard 3 - Serious Hazard 4 - Severe Hazard * - Chronic Hazard X - Consult your supervisor or S.O.P. for "Special" handling instructions. N221 - REGAL PREMIUM INTERIOR LATEX MATTE FINISH Health: 1* Flammability: 0 Revision Date: 03-Jun-2009 Reactivity: 0 Page 686 of 871 Page 686 of 871 Page 686 of 871 Page 686 of 871 ---PAGE BREAK--- Specific Hazards Arising From The Chemical Closed containers may rupture if exposed to fire or extreme heat. Sensitivity To Mechanical Impact No Sensitivity To Static Discharge No Flash Point Data Flash Point Not applicable Flash Point Not applicable Flash Point Method Not applicable Flammability Limits In Air Lower Explosion Limit Not applicable Upper Explosion Limit Not applicable The ratings assigned by Benjamin Moore & Co. are only suggested ratings, the contractor/employer has ultimate responsibilities for NFPA ratings where this system is used. Additional information regarding the NFPA rating system is available from the National Fire Protection Agency (NFPA) at www.nfpa.org. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Environmental Precautions Prevent further leakage or spillage if safe to do so. Methods For Clean-Up Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Other Information None known 7. HANDLING AND STORAGE Handling Avoid contact with skin, eyes and clothing. Avoid breathing vapors, spray mists or sanding dust. In case of insufficient ventilation, wear suitable respiratory equipment. Storage Keep container closed. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Limits Page 3 / 8 N221 - REGAL PREMIUM INTERIOR LATEX MATTE FINISH NFPA Revision Date: 03-Jun-2009 NFPA Legend 0 - Not Hazardous 1 - 2 - Moderate 3 - High 4 - Severe Health: 1 Flammability: 0 Instability: 0 Special: Not Applicable Page 687 of 871 Page 687 of 871 Page 687 of 871 Page 687 of 871 ---PAGE BREAK--- Hazardous Components Chemical Name ACGIH OSHA Titanium dioxide 10 mg/m3 - TWA 15 mg/m3 - TWA total Nepheline syenite N/E 5 mg/m3 - TWA (nuisance dust) Limestone N/E 15 mg/m3 - TWA total 5 mg/m3 - TWA Kaolin, calcined N/E 5 mg/m3 - TWA Diatomaceous earth N/E - SiO2) mg/m3 TWA 20 - TWA Silica, amorphous N/E - SiO2) mg/m3 TWA 20 - TWA Legend ACGIH - American Conference of Governmental Industrial Hygienists Exposure Limits OSHA - Occupational Safety & Health Administration Exposure Limits N/E - Not Established Engineering Measures Ensure adequate ventilation, especially in confined areas. Personal Protective Equipment Eye/Face Protection Safety glasses with side-shields. Skin Protection Protective gloves and impervious clothing. Respiratory Protection In case of insufficient ventilation wear suitable respiratory equipment. Hygiene Measures Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing before re-use. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance liquid Odor little or no odor Density (lbs/gal) 10.06 - 12.07 Specific Gravity 1.20 - 1.44 pH Not available Viscosity (centistokes) Not available Evaporation Rate Not available Vapor Pressure Not available Vapor Density Not available Wt. % Solids 40 - 60 Vol. % Solids 25 - 45 Wt. % Volatiles 40 - 60 Vol. % Volatiles 55 - 75 VOC (g/L) < 100 Boiling Point 212 Boiling Point 100 Freezing Point 32 Freezing Point 0 Flash Point Not applicable Flash Point Not applicable Flash Point Method Not applicable Upper Explosion Limit Not applicable Lower Explosion Limit Not applicable Page 4 / 8 N221 - REGAL PREMIUM INTERIOR LATEX MATTE FINISH Revision Date: 03-Jun-2009 Page 688 of 871 Page 688 of 871 Page 688 of 871 Page 688 of 871 ---PAGE BREAK--- 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY Chemical Stability Stable under normal conditions. Conditions To Avoid Prevent from freezing Incompatible Materials No materials to be especially mentioned. Hazardous Decomposition Products None under normal use. Possibility Of Hazardous Reactions None under normal conditions of use. 11. TOXICOLOGICAL INFORMATION Acute Toxicity Product No information available Component Chronic Toxicity Carcinogenicity The information below indicates whether each agency has listed any ingredient as a carcinogen: Page 5 / 8 LD50 Oral: > 10000 mg/kg (Rat) Nepheline syenite LD50 Dermal: 2,000 mg/kg (Rabbit) LD50 Oral: > 24000 mg/kg (Rat) LC50 Inhalation (Dust): > 2 mg/L Sensitization: No sensitizing effects known. N221 - REGAL PREMIUM INTERIOR LATEX MATTE FINISH Limestone LD50 Dermal: > 10000 mg/m³ (Rabbit) LD50 Oral: 6,450 mg/kg (Rat) vendor data Titanium dioxide Sensitization: No sensitizing effects known. LC50 Inhalation (Dust): > 6.82 mg/L (Rat, 4 hr.) Silica, amorphous Revision Date: 03-Jun-2009 Page 689 of 871 Page 689 of 871 Page 689 of 871 Page 689 of 871 ---PAGE BREAK--- Chemical Name ACGIH IARC NTP OSHA Carcinogen Titanium dioxide 2B - Possible Human Carcinogen Listed Kaolin, calcined 2B - Possible Human Carcinogen Although IARC has classified titanium dioxide as possibly carcinogenic to humans (2B), their summary concludes: "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium dioxide is bound to other materials, such as paint." Legend ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer NTP - National Toxicity Program OSHA - Occupational Safety & Health Administration 12. ECOLOGICAL INFORMATION Ecotoxicity Effects Product Acute Toxicity to Fish No information available Acute Toxicity to Aquatic Invertebrates No information available Acute Toxicity to Aquatic Plants No information available Component Acute Toxicity to Fish Acute Toxicity to Aquatic Invertebrates No information available Acute Toxicity to Aquatic Plants No information available 13. DISPOSAL CONSIDERATIONS Page 6 / 8 LC50: >1000 mg/L (Fathead Minnow - 96 hr.) Revision Date: 03-Jun-2009 Titanium dioxide N221 - REGAL PREMIUM INTERIOR LATEX MATTE FINISH Page 690 of 871 Page 690 of 871 Page 690 of 871 Page 690 of 871 ---PAGE BREAK--- 13. DISPOSAL CONSIDERATIONS Waste Disposal Method Dispose of in accordance with federal, state, and local regulations. Dry, empty containers may be recycled in a can recycling program. Local requirements may vary, consult your sanitation department or state-designated environmental protection agency for more disposal options. 14. TRANSPORT INFORMATION DOT Not regulated ICAO / IATA Not regulated IMDG / IMO Not regulated 15. REGULATORY INFORMATION International Inventories United States TSCA Yes - All components are listed or exempt. Canada DSL Yes - All components are listed or exempt. Federal Regulations SARA 311/312 hazardous categorization Acute Health Hazard No Chronic Health Hazard Yes Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product contains the following HAPs: State Regulations California Proposition 65 Page 7 / 8 N221 - REGAL PREMIUM INTERIOR LATEX MATTE FINISH This product may contain trace amounts of (other) SARA reportable chemicals. Contact Benjamin Moore & Co. for further information. This product may contain trace amounts of (other) HAPs chemicals. Contact Benjamin Moore & Co. for further information. Revision Date: 03-Jun-2009 Page 691 of 871 Page 691 of 871 Page 691 of 871 Page 691 of 871 ---PAGE BREAK--- This product may contain small amounts of materials known to the state of California to cause cancer or reproductive harm. State Right-to-Know Chemical Name Massachusetts New Jersey Louisiana Rhode Island Titanium dioxide X X X X Limestone X X X Diatomaceous earth X X Silica, amorphous X X X Legend X - Listed 16. OTHER INFORMATION WARNING! If you scrape, sand, or remove old paint, you may release lead dust. LEAD IS TOXIC. EXPOSURE TO LEAD DUST CAN CAUSE SERIOUS ILLNESS, SUCH AS BRAIN DAMAGE, ESPECIALLY IN CHILDREN. PREGNANT WOMEN SHOULD ALSO AVOID EXPOSURE. Wear a NIOSH approved respirator to control lead exposure. Clean up carefully with a HEPA vacuum and a wet mop. Before you start, find out how to protect yourself and your family by contacting the National Lead Information Hotline at 1-800-424-LEAD or log on to www.epa.gov/lead. Prepared By Product Stewardship Department Benjamin Moore & Co. 360 Route 206 - P.O. Box 4000 Flanders, NJ 07836 [PHONE REDACTED] Revision Date: 03-Jun-2009 Revision Summary Not available Disclaimer The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, provincial, and local laws and regulations. End of MSDS Page 8 / 8 N221 - REGAL PREMIUM INTERIOR LATEX MATTE FINISH Revision Date: 03-Jun-2009 Page 692 of 871 Page 692 of 871 Page 692 of 871 Page 692 of 871 ---PAGE BREAK--- Material Safety Data Sheet 42272 HMIS May be used to comply with OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Standard must be consulted for specific requirements. HEALTH FLAMMABILITY 1 1 REACTIVITY PERSONAL PROTECTION 0 None Identity (As Used on Label and List) 4 2 2 0 1 , 4 2 2 1 0 , 4 2 2 3 0 , 4 2 2 3 6 , 4 2 2 7 2 Rough Touch® Scrubs in - a - Bucket® Note: Blank spaces are not permitted. If any item is not applicable, or no information is available, the space must be marked to indicate that. SECTION I Manufacturer's Name ITW Dymon Emergency Telephone Number 1-[PHONE REDACTED] Address (Number, Street, City, State, and ZIP Code) 805 East Old 56 Highway Telephone Number for Information 1-[PHONE REDACTED] Olathe, Kansas 66061 Date Prepared December 13, 2001 Signature of Preparer (Optional) Regulatory Dept. SECTION II - Hazardous Ingredients/Identity Information Hazardous Components (Specific Other Limits Chemical Identity, Common Name(s)) CAS No. OSHA PEL ACGIH- TLV Recommended % (Opt.) This product is not known to contain any compound in concentrations requiring reporting under SARA Title III Section 313. TSCA: All ingredients are on the TSCA inventory or are not required to be listed on the TSCA inventory. Any substance listed as hazardous by the States of California, Florida, Illinois, Michigan, New Jersey, Ohio, or Texas is described above if known present in regulated concentrations. SECTION III Physical/Chemical Characteristics Boiling Point Initial >200 o F Specific Gravity (H2O = 1) @70o F 0.982 Vapor Pressure (mm-Hg @ 70o F) No Data Melting Point No Data Vapor Density (AIR = 1) Greater than one Evaporation Rate (Butyl Acetate = 1) No Data Solubility in Water Dispersible pH 7.4 + 0.5 Appearance and Odor - Opaque white liquid with a fresh citrus scent saturated onto towels. SECTION IV - Fire and Explosion Hazard Data Flash Point (Method Used) None to boiling (TCC) Solution on Towel Flammable Limits No Data LEL No Data UEL No Data Extinguishing Media - Use carbon dioxide, dry chemical, foam, fog or water spray. Special Fire Fighting Procedures - Keep containers cool and vapors down with water spray. Prevent runoff from entering sewers and public waterways. Wear SCBA in chemical fires. Unusual Fire and Explosion Hazards - None known. Page 693 of 871 Page 693 of 871 Page 693 of 871 Page 693 of 871 ---PAGE BREAK--- 4 2 2 0 1 , 4 2 2 1 0 , 4 2 2 3 0 , 4 2 2 3 6 , 4 2 2 7 2 December 13, 2001 SECTION V - Reactivity Data Stability Unstable Conditions to Avoid - None known Stable X Incompatibility (Materials to Avoid) - Strong oxidizers and acids. Hazardous Decomposition or Byproducts - Carbon dioxide, carbon monoxide, hydrogen sulfide, sulfur dioxide, smoke and soot. Hazardous May Occur Conditions to Avoid - None known Polymerization Will Not Occur X SECTION VI - Health Hazard Data Route(s) of Entry Eyes? Yes Inhalation? No Skin? No Ingestion? Yes Health Hazards (Acute and Chronic) - Caution. Towel may cause eye irritation. Carcinogenicity: None known NTP? No IARC Monographs? No OSHA Regulated? No Signs and of Exposure - Redness, tearing or burning in eyes. Irritation of the throat or stomach, nausea, vomiting, and diarrhea if swallowed. Medical Conditions Generally Aggravated by Exposure - Pre-existing skin conditions such as dermatitis may be adversely affected by this and other oil and grease effective cleaners. Emergency and First Aid Procedures: Eyes - Flush with plenty of water for at least 15 minutes lifting eyelids to insure complete removal. See a physician immediately. Ingestion - Not a likely exposure route. If a large quantity of liquid is swallowed, do not induce vomiting, call a physician or poison control center immediately. Inhalation - Unlikely route as liquid is impregnated on a towel, minimizing exposure via this route. Skin - None usually required. Material is designed for skin cleansing. SECTION VII - Precautions for Safe Handling and Use Steps to be Taken in Case Material is Released or Spilled - Caution, slip hazard. Wipe up small releases with a dry absorbent cloth. For large releases, prevent material from entering sewers or drains. Ventilate area and block traffic. Pick up and put in suitable container for proper disposal. Waste Disposal Method - Consult local, state, and federal regulations. Discard empty container or offer for recycling or reuse. Precautions to be Taken in Handling and Storing - Do not allow towel contact with eyes. For external use only. Not for use around the mouth or eyes for an extended period of time. Do not smoke while using. Do not contaminate water, food or feed by use or storage. Other Precautions - Follow label directions carefully. Keep away from heat sources. Keep out of reach of children. Keep container sealed when not in use. SECTION VIII - Control Measures Respiratory Protection (Specify Type) Not usually necessary. Use with adequate ventilation. Use NIOSH/MSHA approved respirator if PELs or TLVs are exceeded. Ventilation Local Exhaust Not usually needed Special None Mechanical (General) Acceptable Other None Protective Gloves - Not necessary Eye Protection - Not necessary Other Protective Clothing or Equipment - Not usually necessary. Work/Hygienic Practices - Normal. Use to wash hands before eating, drinking, smoking, using restrooms, etc. WARNING! The use of this product is beyond the control of the manufacturer; therefore, no guarantee, expressed or implied, is made as to the effects of such or the results to be obtained if not used in accordance with directions or established safe practice. The user must assume all responsibility, including injury or damage, resulting from its misuse as such, or in combination with other materials. The manufacturer warrants only that this product meets the manufacturer's specifications for such product. THIS WARRANTY IS IN LIEU OF ALL OTHER WARRANTIES, EXPRESS OR IMPLIED, AS TO DESCRIPTION , QUALITY, MERCHANTABILITY. FITNESS FOR ANY PARTICULAR PURPOSE, PRODUCTIVENESS, OR ANY OTHER MATTER, OF THIS PRODUCT. THE MANUFACTURER SHALL BE IN NO WAY RESPONSIBLE FOR THE IMPROPER USE OF THIS PRODUCT. The sole and exclusive remedy against the manufacturer for breach of warranty shall be reimbursement of the purchase price of the product in the event that a defective condition of the product shall be found to exist. NO OTHER REMEDY (INCLUDING BUT NOT LIMITED TO INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR INJURY TO PERSON OR PROPERTY OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE. Page 694 of 871 Page 694 of 871 Page 694 of 871 Page 694 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 07-Oct-2008 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product code 93206 Product name RTV Silicone L.V. Red Recommended Use Sealant Supplier Lawson Products, Inc. 1666 East Touhy Avenue Des Plaines, IL 60018 (847)-827-9666 Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known. Principal Routes of Exposure Eyes. Inhalation. Potential health effects Eyes Moderately irritating to the eyes. Redness. Swelling. Severity depends on degree of exposure. Skin Repeated or prolonged exposure may cause:. Moderate irritation. Inhalation May cause irritation of respiratory tract. Ingestion May cause the following effects. Stomach distress. Irritation of lips, gums and tongue. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % 4253-34-3 1-5 Silicon Dioxide - hydrated 7631-86-9 7-13 17689-77-9 1-5 Dimethyl Siloxane Hydroxy Terminated 70131-67-8 60-100 4. FIRST AID MEASURES Page 1 / 6 Color Red Odor Slight Form Liquid Page 695 of 871 Page 695 of 871 Page 695 of 871 Page 695 of 871 ---PAGE BREAK--- Product code 93206 Product name RTV Silicone L.V. Red 4. FIRST AID MEASURES Eye contact Flush with plenty of water for at least 15 minutes. Seek medical attention if irritation persists. Skin contact Wipe off with a towel. Flush skin with water and follow by washing skin with soap and water. Ingestion Call a physician or Poison Control Center immediately. Inhalation Remove to fresh air. 5. FIRE FIGHTING MEASURES Flash point °C No data available Flash point °F No data available Method Open cup Autoignition temperature °C No data available Autoignition temperature °F Flammability Limits in Air) Upper No data available Lower No data available Suitable extinguishing media Carbon dioxide (CO2). Water. Water fog. Dry chemical. Foam. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Special Fire-Fighting Procedures Firefighters should wear NIOSH/MSHA approved (or equivalent) self-contained pressure-demand breathing apparatus and full protective clothing. Fire and Explosion Hazards None known. Hazardous decomposition products See Section 10 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Wipe or scrape up and dispose of spill. Place in non-leaking, sealed container for proper disposal. Use caution as spill may create a slip hazard. 7. HANDLING AND STORAGE Page 2 / 6 Sensitivity to static discharge No information available. Sensitivity to shock No information available. Page 696 of 871 Page 696 of 871 Page 696 of 871 Page 696 of 871 ---PAGE BREAK--- Product code 93206 Product name RTV Silicone L.V. Red 7. HANDLING AND STORAGE Handling Avoid contact with skin and eyes. Do not handle contact lenses until all sealant has been cleaned from the fingertips, nails, and cuticles. Wash hands with soap and water before eating, drinking, smoking, or using toilet facilities. Storage Store in a well ventilated area. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Dimethyl Siloxane Hydroxy Terminated - - - - Silicon Dioxide - hydrated 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction) 10 ppm 10 mg/m3 (total dust) ND - 10 mg/m3 (dust) - 15 ppm - ND - ND Ventilation and Environmental Controls Use in a well ventilated area. Provide adequate ventilation to keep exposure limits below TLV. Hygiene measures Wash hands before breaks and immediately after handling the product. Personal protective equipment Respiratory protection None necessary under normal conditions. Hand Protection Cotton gloves. Eye protection ANSI approved safety glasses are recommended to prevent accidental eye contact. Skin and body protection None necessary under normal conditions Other Protective Equipment An eye wash station should be available. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 3 / 6 Specific Gravity 1.032 @ 77F (25C) Color Vapor pressure No data available Red Vapor density No data available Evaporation Rate Not Applicable Odor VOC Content 0 gm/liter Slight Water solubility No data available Form Partition Coefficient (n-octanol/water) No data available Odor Threshold No information available Liquid pH Not Applicable Page 697 of 871 Page 697 of 871 Page 697 of 871 Page 697 of 871 ---PAGE BREAK--- Product code 93206 Product name RTV Silicone L.V. Red 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY Stability No information available. Conditions to avoid No information available. Incompatability No information available. Hazardous Decomposition Products Sulfur oxides. Carbon oxides. Incompletely burned carbon products. Silicone dioxide. Iodine compounds. Formaldehyde. Polymerization No information available. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat) LD50 (dermal,rat/rabbit) LC50 (inhalation,rat) Dimethyl Siloxane Hydroxy Terminated 70131-67-8 - - - Silicon Dioxide - hydrated 7631-86-9 2000 mg/kg 5000 mg/kg 2000 mg/kg 5000 mg/kg 2000 mg/kg 5000 mg/kg 17689-77-9 - - - 4253-34-3 2060 mg/kg 2060 mg/kg 2060 mg/kg Synergistic Products None known Potential health effects Page 4 / 6 Melting point/range °C No data available Melting point/range °F No data available Flash point °C No data available Flash point °F No data available Boiling point/range °C Not Applicable Boiling point/range °F Not Applicable Page 698 of 871 Page 698 of 871 Page 698 of 871 Page 698 of 871 ---PAGE BREAK--- Product code 93206 Product name RTV Silicone L.V. Red Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinogens IARC NTP - Known Carcinogens NTP - Suspected Human Carcinogens OSHA RTK Carcinogens Dimethyl Siloxane Hydroxy Terminated Not Listed Not Listed Not Listed Not Listed Not Listed Silicon Dioxide - hydrated Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION No Information Available 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORT INFORMATION DOT Not Regulated TDG Not Regulated IMDG/IMO Not Regulated IATA Not Regulated Page 5 / 6 Teratogenic effects None known Silicon Dioxide - hydrated Reproductive toxicity None known Water Flea Data Ceriodaphnia dubia EC50=7600 mg/L (48 h) Target Organ Effects See Section 2 Chronic toxicity None known Mutagenic effects None known Sensitization None known Page 699 of 871 Page 699 of 871 Page 699 of 871 Page 699 of 871 ---PAGE BREAK--- Product code 93206 Product name RTV Silicone L.V. Red 14. TRANSPORT INFORMATION MEX Not Regulated 15. REGULATORY INFORMATION Chemical Name New Jersey - RTK - RTK California Prop. 65 Dimethyl Siloxane Hydroxy Terminated Not Listed Not Listed Not Listed Silicon Dioxide - hydrated Listed Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Chemical Name EINECS DSL NDSL TSCA Dimethyl Siloxane Hydroxy Terminated - X - X Silicon Dioxide - hydrated X X - X X X - X X X - X CPRC This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION Prepared By Michael Katz, Regulatory Affairs Specialist The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 6 / 6 HMIS NFPA 1 Flammability 1 Health 1 Health Flammability 1 Reactivity 0 Physical Hazard 0 Page 700 of 871 Page 700 of 871 Page 700 of 871 Page 700 of 871 ---PAGE BREAK--- Page 701 of 871 Page 701 of 871 Page 701 of 871 Page 701 of 871 ---PAGE BREAK--- Page 702 of 871 Page 702 of 871 Page 702 of 871 Page 702 of 871 ---PAGE BREAK--- Page 703 of 871 Page 703 of 871 Page 703 of 871 Page 703 of 871 ---PAGE BREAK--- Page 704 of 871 Page 704 of 871 Page 704 of 871 Page 704 of 871 ---PAGE BREAK--- Page 705 of 871 Page 705 of 871 Page 705 of 871 Page 705 of 871 ---PAGE BREAK--- Page 706 of 871 Page 706 of 871 Page 706 of 871 Page 706 of 871 ---PAGE BREAK--- Page 707 of 871 Page 707 of 871 Page 707 of 871 Page 707 of 871 ---PAGE BREAK--- Page 708 of 871 Page 708 of 871 Page 708 of 871 Page 708 of 871 ---PAGE BREAK--- Date Printed: 5/15/2015 Safety Data Sheet * Trusted Quality Since 1921 * www.rustoleum.com 1. Identification Product Name: STRUST +SSPR 6PK FLAT RUSTY METAL PRIMER Revision Date: 5/15/2015 Product Identifier: 7769830 Supercedes Date: 4/24/2015 Product Use/Class: Primer/Aerosols Supplier: Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA Manufacturer: Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA Preparer: Regulatory Department 24 Hour Hotline: [PHONE REDACTED] Emergency Telephone: 2. Hazard Identification EMERGENCY OVERVIEW: Extremely flammable liquid and vapor. Vapors may cause flash fire or explosion. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. Contents Under Pressure. May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if inhaled. Harmful if swallowed. Causes eye irritation. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Vapor Harmful. Causes Eye, Skin, Nose, and Throat Irritation. Classification Symbol(s) of Product Signal Word Danger Possible Hazards 74% of the mixture consists of ingredient(s) of unknown acute toxicity GHS HAZARD STATEMENTS Flammable Aerosol, category 1 H222 Extremely flammable aerosol. Flammable Liquid, category 1 H224 Extremely flammable liquid and vapor. Acute Toxicity, Oral, category 5 H303 May be harmful if swallowed. Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin. Skin Irritation, category 2 H315 Causes skin irritation. Eye Irritation, category 2 H319 Causes serious eye irritation. Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled. STOT, single exposure, category 3, RTI H335 May cause respiratory irritation. STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness. Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways. Eye Irritation, category 2B H320 Causes eye irritation. Flammable Aerosol, category 1 H280 Contains gas under pressure; may explode if heated. Page 1 / 8 Page 709 of 871 Page 709 of 871 Page 709 of 871 Page 709 of 871 ---PAGE BREAK--- Date Printed: 5/15/2015 Germ Cell Mutagenicity, category 1B H340 May cause genetic defects. Classified as mutagenic Category 1 if one ingredient is present at or above 0.1%. Applies to liquids, solids (w/w units) and gases The substance may also have its own exposure limit. Routes of exposure are dependent on ingredient form. Carcinogenicity, category 1B H350 May cause cancer. Classified as carcinogenic Category 1 on the basis of epidemiological and/or animal data. Mixtures are classified as carcinogenic when at least 1 ingredient has been classified as carcinogenic and is present at 0.1% or above Routes of exposure are dependant on ingredient form. STOT, repeated exposure, category 2 H373 May cause damage to organs through prolonged or repeated exposure . GHS LABEL PRECAUTIONARY STATEMENTS P211 Do not spray on an open flame or other ignition source. P251 Pressurized container: Do not pierce or burn, even after use. P375 Fight fire remotely due to the risk of explosion. P102 Keep out of reach of children. P103 Read label before use. P234 Keep only in original container. P260 Do not breathe dust/fume/gas/mist/vapors/spray. P262 Do not get in eyes, on skin, or on clothing. P264 Wash … thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. P285 In case of inadequate ventilation wear respiratory protection. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P374 Fight fire with normal precautions from a reasonable distance. P402 Store in a dry place. P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C / 122°F. P403+P235 Store in a well-ventilated place. Keep cool. P362 Take off contaminated clothing and wash before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. P403+P233 Store in a well-ventilated place. Keep container closed. P201 Obtain special instructions before use. P308+P313 IF exposed or concerned: Get medical advice/attention. P350 Gently wash with plenty of soap and water. P302+P352 IF ON SKIN: Wash with plenty of soap and water. 3. Composition/Information On Ingredients HAZARDOUS SUBSTANCES Chemical Name CAS-No. Wt.% Range GHS Symbols GHS Statements Propane 10-25 74-98-6 Medium Oil Alkyd 10-25 Proprietary Aliphatic Hydrocarbon 2.5-10 GHS08 H340-350 64742-89-8 n-Butane 2.5-10 106-97-8 Iron Oxide 2.5-10 1309-37-1 Hydrous Magnesium Silicate 2.5-10 14807-96-6 Acetone 2.5-10 GHS02-GHS07 H225-336-319 67-64-1 Mineral Spirits 2.5-10 GHS06-GHS08 H331-372 64742-88-7 Xylene (mixed isomers) 2.5-10 GHS02-GHS07 H226-312-[PHONE REDACTED]-20-7 Page 2 / 8 Page 710 of 871 Page 710 of 871 Page 710 of 871 Page 710 of 871 ---PAGE BREAK--- Date Printed: 5/15/2015 Limestone 2.5-10 1317-65-3 n-Butyl Acetate 2.5-10 GHS02-GHS07 H225-336 123-86-4 1.0-2.5 GHS02-GHS07 H225-332 100-41-4 Barium Sulfate 1.0-2.5 7727-43-7 Silica / Quartz 0.1-1.0 GHS07 H302 14808-60-7 The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section. 4. First-aid Measures FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed. FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists. FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately. FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention. 5. Fire-fighting Measures EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20°F. EXTREMELY FLAMMABLE LIQUID AND VAPOR!Water spray may be ineffective. Closed containers may explode when exposed to extreme heat due to buildup of steam. Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a source of ignition and flash back. Isolate from heat, electrical equipment, sparks and open flame. Perforation of the pressurized container may cause bursting of the can. No unusual fire or explosion hazards noted. Keep containers closed. SPECIAL FIREFIGHTING PROCEDURES: Full protective equipment including self-contained breathing apparatus should be used. Evacuate area and fight fire from a safe distance. Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Use water spray to keep fire-exposed containers cool. Containers may explode when heated. 6. Accidental Release Measures STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Ventilate area, isolate spilled material, and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations. 7. Handling and Storage HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing. STORAGE: Keep containers closed. Isolate from heat, electrical equipment, sparks and open flame. Contents under pressure. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of NFPA Class I flammable liquids. Product should be stored in sealed containers and protected from heat, moisture, and foreign materials. Store in a dry, well ventilated place. Keep container closed when not in use. Keep away from heat, sparks, flame and sources of ignition. Avoid excess heat. 8. Exposure Controls/Personal Protection Chemical Name CAS-No. Weight % Less Than ACGIH TLV- TWA ACGIH TLV- STEL OSHA PEL-TWA OSHA PEL- CEILING Propane 74-98-6 20.0 1000 ppm N.E. 1000 ppm N.E. Medium Oil Alkyd Proprietary 15.0 N.E. N.E. N.E. N.E. Aliphatic Hydrocarbon 64742-89-8 10.0 350 ppm N.E. 500 ppm N.E. n-Butane 106-97-8 10.0 1000 ppm 1000 ppm N.E. N.E. Page 3 / 8 Page 711 of 871 Page 711 of 871 Page 711 of 871 Page 711 of 871 ---PAGE BREAK--- Date Printed: 5/15/2015 Iron Oxide 1309-37-1 10.0 5 mg/m3 (Respirable Dust, OSHA) N.E. 15 mg/m3 (Total Dust) N.E. Hydrous Magnesium Silicate 14807-96-6 10.0 2 mg/m3 (Respirable Dust) N.E. 20 (Mineral Dust Quartz) N.E. Acetone 67-64-1 10.0 500 ppm 750 ppm 1000 ppm N.E. Mineral Spirits 64742-88-7 10.0 100 ppm N.E. 100 ppm N.E. Xylene (mixed isomers) 1330-20-7 10.0 100 ppm 150 ppm 100 ppm N.E. Limestone 1317-65-3 5.0 15 mg/m3 (Total Dust, OSHA) N.E. 5 mg/m3 (Respirable Dust) N.E. n-Butyl Acetate 123-86-4 5.0 150 ppm 200 ppm 150 ppm N.E. 100-41-4 5.0 20 ppm 125 ppm 100 ppm N.E. Barium Sulfate 7727-43-7 5.0 5 mg/m3 (Inhlalable fraction w/o asbestos and N.E. 15 mg/m3 [Total Dust] N.E. Silica / Quartz 14808-60-7 1.0 0.025 mg/m3 [Respirable Dust] N.E. 0.1 mg/m3 [Respirable Dust] N.E. PERSONAL PROTECTION ENGINEERING CONTROLS: Use explosion-proof ventilation equipment. Provide general dilution of local exhaust ventilation in volume and pattern to keep TLV of hazardous ingredients below acceptable limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation. Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin protection. EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids. OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications. HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse. 9. Physical and Chemical Properties Appearance: Aerosolized Mist Physical State: Liquid Odor: Solvent Like Odor Threshold: N.E. Relative Density: 0.852 pH: N.A. Freeze Point, N.D. Viscosity: N.D. Solubility in Water: Slight Partition Coefficient, n- octanol/water: No Information Decompostion Temp., No Information Boiling Range, -11 - 498 Explosive Limits, vol%: 0.7 - 13.1 Flammability: Does not Support Combustion Flash Point, -105 Evaporation Rate: Faster than Ether Auto-ignition Temp., No Information Vapor Density: Heavier than Air Vapor Pressure: N.D. (See "Other information" Section for abbreviation legend) 10. Stability and Reactivity CONDITIONS TO AVOID: Avoid temperatures above 120 ° F. Avoid contact with strong acid and strong bases. Avoid all possible sources of ignition. INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies. HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. Page 4 / 8 Page 712 of 871 Page 712 of 871 Page 712 of 871 Page 712 of 871 ---PAGE BREAK--- Date Printed: 5/15/2015 11. Toxicological information EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation. Allergic reactions are possible. EFFECTS OF OVEREXPOSURE - INHALATION: High gas, vapor, mist or dust concentrations may be harmful if inhaled. High vapor concentrations are irritating to the eyes, nose, throat and lungs. Harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. Prolonged or excessive inhalation may cause respiratory tract irritation. EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: IARC lists as a possible human carcinogen (group 2B). Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. May cause central nervous system disorder narcosis involving a loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage. PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact ACUTE TOXICITY VALUES The acute effects of this product have not been tested. Data on individual components are tabulated below: CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50 74-98-6 Propane N.I. N.I. 658 mg/L Rat 64742-89-8 Aliphatic Hydrocarbon N.I. 3000 mg/kg Rabbit N.I. 1309-37-1 Iron Oxide >10000 mg/kg Rat N.I. N.I. 64742-88-7 Mineral Spirits >5000 mg/kg Rat 3000 mg/kg Rabbit >5.28 mg/L Rat 1330-20-7 Xylene (mixed isomers) 4300 mg/kg Rat N.I. 47635 mg/L Rat 123-86-4 n-Butyl Acetate N.I. >17600 mg/kg Rabbit N.I. 100-41-4 3500 mg/kg Rat 15354 mg/kg Rabbit 17.2 mg/L Rat 14808-60-7 Silica / Quartz 500 mg/kg Rat N.I. N.I. N.I. - No Information 12. Ecological Information ECOLOGICAL INFORMATION: Product is a mixture of listed components. 13. Disposal Information DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow to enter waterways, wastewater, soil, storm drains or sewer systems. 14. Transport Information Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada) UN Number: N.A. 1950 1950 N.A. Proper Shipping Name: Paint Products in Limited Quantities Aerosols Aerosols Paint Products in Limited Quantities Hazard Class: N.A. 2.1 2.1 N.A. Packing Group: N.A. N.A. N.A. N.A. Limited Quantity: Yes Yes Yes Yes 15. Regulatory Information Page 5 / 8 Page 713 of 871 Page 713 of 871 Page 713 of 871 Page 713 of 871 ---PAGE BREAK--- Date Printed: 5/15/2015 U.S. Federal Regulations: CERCLA - SARA Hazard Category This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Fire Hazard, Pressure Hazard, Acute Health Hazard, Chronic Health Hazard Sara Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name CAS-No. Xylene (mixed isomers) 1330-20-7 100-41-4 Toxic Substances Control Act: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported from the United States: Chemical Name CAS-No. Phthalic 85-44-9 CALIFORNIA PROPOSITION 65: WARNING: This product contains a substance known to the State of California to cause cancer. Chemical Name CAS-No. 100-41-4 Silica / Quartz 14808-60-7 Benzene 71-43-2 Cadmium Compounds 7440-43-9 Lead Compounds 7439-92-1 CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS WARNING: This product contains a substance known to the State of California to cause birth defects or other reproductive harm. Chemical Name CAS-No. Toluene 108-88-3 Benzene 71-43-2 Lead Compounds 7439-92-1 Cadmium Compounds 7440-43-9 International Regulations: CANADIAN WHMIS: This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings. Page 6 / 8 Page 714 of 871 Page 714 of 871 Page 714 of 871 Page 714 of 871 ---PAGE BREAK--- Date Printed: 5/15/2015 16. Other Information HMIS RATINGS Health: 2* Flammability: 4 Physical Hazard: 0 Personal Protection: X CANADIAN WHMIS CLASS: AB5 D2A NFPA RATINGS Health: 2 Flammability: 4 Instability 0 VOLATILE ORGANIC COMPOUNDS, g/L: 532 MSDS REVISION DATE: 5/15/2015 REASON FOR REVISION: No Information Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined Text for GHS Hazard Statements shown in Section 3 describing each ingredient: H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H302 Harmful if swallowed. H312 Harmful in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H331 Toxic if inhaled. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness. H340 May cause genetic defects . H350 May cause cancer . H372 Causes damage to organs through prolonged or repeated exposure . Icons for GHS Pictograms shown in Section 3 describing each ingredient: GHS02 GHS06 GHS07 GHS08 Page 7 / 8 Page 715 of 871 Page 715 of 871 Page 715 of 871 Page 715 of 871 ---PAGE BREAK--- Date Printed: 5/15/2015 Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations. Page 8 / 8 Page 716 of 871 Page 716 of 871 Page 716 of 871 Page 716 of 871 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Page 1 MSDS ID: 93160 Revised 5/07/03 CRT CLEANER 19 OZ NW *NONE Replaces 5/25/99 Lawson Products Inc. Emergency/Information Telephone: 1666 East Touhy Avenue Des Plaines, Illinois 60018 [PHONE REDACTED] Formula: 43989 MSDS Effective: 01/04/99 Section I - Product Identification Part Number: 93160 Product Name: SCREEN CLEAN 19 OZ NW Trade Name/Synonyms: SCREEN CLEAN Chemical Family: AEROSOL CLEANER Section II - Hazardous Ingredients Ingredient CAS No. WT % Pel TLV Stel Units LC50,PPM LD50,MG/KG 2-BUTOXYETHANOL #00111-76-2 6 25S 25S N/A PPM RAT 450 RAT I 470 . RAB A 220 BUTANE 00106-97-8 1-5 800 800 N/A PPM RAT277374 N/A PROPANE 00074-98-6 1-5 1000 N/A N/A PPM MLO 10000 N/A WATER 07732-18-5 80-90 Section III - Physical Data Boiling Pt Deg F/C: N/A Specific Gravity:0.96 Vapor Pressure(MM HG):N/A %Volatile Volume:99 Vapor Density(Air=1):HEAVIER THAN AIR Evaporation Rate:FASTER THAN ETHER Solubility In Water: N/A Water/Oil Dist Coeff:N/A Physical State: AEROSOL PH: 7.0 Freeze PT Deg F/C: N/A Threshold Odor,PPM: N/A Appearance And Odor: CLEAR LIQUID, AMMONIA ODOR Voc:Lbs/Gal=0.84; Grams/Liter=100 ; Grams Voc/Gram Solid=N/A ; % Voc 10.6 Section IV - Fire and Explosion Hazard Data Classification: AEROSOL NFPA Rating: 2,4,0 HMIS: 2,4,0 Combustion Products: N/A Flash Point Deg F/C: 23F/-5C T.C.C. Lel%:1.1 Uel%:10.6 Extinguishing Media: FOAM, CO2, DRY CHEMICAL Auto Ign. Temp Deg F/C: N/A Special Fire Fighting Procedures: FIREFIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING EQUIPMENT. Unusual Fire And Explosion Hazards: EXPOSURE TO FIRE, HEAT OR PROLONGED SUNLIGHT MAY CAUSE BURSTING. IF USED IN CONFINED SPACE, HAZARDOUS VAPORS MAY SPREAD, BURN OR BUILD UP IN LOW AREAS. CONTACT WITH FLAME OR HOT SURFACES MAY PRODUCE TOXIC GASES. Explosive Power: HIGH Impact Sensitive: No Burning Rate: HIGH Static Sensitive: No Section V - Health Hazard Data Routes Of Entry: SKIN CONTACT,EYE,INHALATION Effects Of Overexposure: MAY CAUSE EYE & SKIN IRRIATION. EXCESS INHALATION MAY CAUSE DIZZINESS, GIDDINESS & NAUSEA. PROLONGED & REPEATED INHALATION MAY BE HARMFUL TO RES- Page 717 of 871 Page 717 of 871 Page 717 of 871 Page 717 of 871 ---PAGE BREAK--- PIRAOTORY SYSTEM, LIVER, KIDNEYS & BLOOD. EXTREME OVEREXPOSURE MAY RESULT IN UNCONSCIOUSNESS & POSSIBLE DEATH. MISUSE OR DELIBERATE INHALATION MAY BE HARMFUL OR FATAL. INGESTION CAUSES NAUSEA, CRAMPS, VOMITING, DIARRHEA. Any suspected carcinogen = or > No Emergency and First Aid Procedures: EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MIN. & CALL PHYSICIAN. SKIN: WASH THOROUGHLY WITH PLENTY OF SOAP & WATER. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. INHALATION: IF AFFECTED, REMOVE TO FRESH AIR, ADMIN- ISTER OXYGEN & CALL PHYSICIAN. INGESTION: CALL PHYSICIAN IMMEDIATELY. Section VI - Reactivity Data Stable: Yes Conditions to Avoid: Incompatibility(Materials to Avoid): No Hazardous Decomposition Products: Yes CO, CO2 Hazardous Polymerization: No Section VII - Spill or Leak Procedures Listed In: SARA Title III; #302: No #304,Cercla: No #313: Yes Steps to be Taken in Case Material is Released or Spilled: REMOVE ALL SOURCES OF IGNITION. VENTILATE THE AREA. CLEAN UP WITH ABSORBENT MATERIAL. Disposal Method: DO NOT PUNCTURE, INCINERATE OR BURN CONTAINERS. DISPOSE OF WASTES IN ACCORDANCE WITH FEDERAL, STATE & LOCAL REGULATIONS. Section VIII - Safe Handling and Protection Information Ventilation-Local: RECOMMENDED Special:N/A Mechanical: REQUIRED Other: N/A Protective Gloves: SEE BELOW Eye Protection:SAFETY GLASSES Precautions in Use: IF VENTILATION IS INADEQUATE, WEAR APPROVED RESPIRATORY EQUIPMENT. DO NOT SPRAY NEAR SPARKS, FLAME OR HEATED SURFACES. GLOVES: NONE REQUIRED UNDER NORMAL APPLICATION WHERE SKIN CONTACT IS MINIMAL. Estimated LD50, MG/KG: No Estimated LC50, PPM: No Sensitization: No Irritant: No Synergistic Agents: No Section IX - Special Precautions Precautions to be Taken in Handling and Storing: KEEP AWAY FROM HEAT, SPARKS, FLAME OR SOURCES OF IGNITION. DO NOT PUNCTURE, INCINERATE, BURN OR STORE CONTAINERS ABOVE 120F(47C). USE ONLY IN WELL VEN- TILATED AREAS. DO NOT BREATHE VAPOR OR SPRAY MIST. AVOID CONTACT WITH EYES, SKIN & CLOTHING. WASH THOROUGHLY AFTER USING. DO NOT TAKE INTERNALLY. IN CASE OF ACCIDENT OR ILLNESS,SEEK PHYSICIAN IMMEDIATELY, SHOW LABEL OR MSDS. Other Precautions: KEEP OUT OF REACH OF CHILDREN. ALWAYS READ & FOLLOW DIRECTIONS ON PRODUCT LABEL. ADDITIONAL TECHNICAL DATA SHEETS AND/OR MATERIAL SAFETY DATA SHEETS (MSDS) ARE AVAILABLE UPON REQUEST. FOR PROFESSIONAL & INDUSTRIAL USE ONLY. Symbols, Abbreviations and Notations: #=Listed in SARA Title III Section 313; @=Non-hazardous ingredient among the Normal product usage should not result in respirable dust that would be hazardous to the respiratory system; N/A=Not available or applicable; *=If found as dust, mist or fume; C=Ceiling limit; S=Skin designation; M=Human; RAB=Rabbits; GPG=Guinea Pigs; MIC=Mice; I=Ingestion; A=Skin absorption; LO=Little observable effect; NO=No effect; Pel=OSHA permissible exposure limit; TLV=ACGIH threshold limit value; Stel=Short term exposure limit. Final determination of suitability of the chemical(s) is the sole responsibility of the user. Users of any chemicals should satisfy themselves that the conditions and methods of use assure that the chemical is used safely.NO REPRESENTATIONS OR WARRANTIES, EITHER Page 718 of 871 Page 718 of 871 Page 718 of 871 Page 718 of 871 ---PAGE BREAK--- EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO THE INFORMATION CONTAINED HEREIN OR THE CHEMICAL TO WHICH THE INFORMATION REFERS. Page 719 of 871 Page 719 of 871 Page 719 of 871 Page 719 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 08-Jul-2013 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code P93160 Product name Screen Clean Recommended Use Cleaner Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Skin contact. Skin absorption. Inhalation. Eyes. Potential health effects Eyes Contact with eyes may cause irritation. Severity depends on degree of exposure. Skin Repeated or prolonged exposure may cause:. Skin Irritation. Inhalation Long-term exposure may cause the following effects:. Headaches. Dizziness. Irritating to respiratory system. Ingestion Toxic if swallowed. Swallowing large amounts may be harmful. Central nervous system effects. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Isopropyl alcohol 67-63-0 1-10 Propane/Isobutane/N- Butane 68476-86-8 1-10 2-Butoxyethanol 111-76-2 1-5 4. FIRST AID MEASURES Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Skin contact Wash area thoroughly with soap and water. Remove and wash contaminated clothing before re-use. Seek medical attention if irritation persists. Ingestion Call a physician or Poison Control Center immediately. Do Not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Immediate medical attention is required. 5. FIRE FIGHTING MEASURES Flash point °C -104 Flash point °F -156 Method Pensky-Martens C.C. Autoignition temperature °C Not Applicable Autoignition temperature °F Not Applicable Flammability Limits in Air) Upper 12.0 Lower 1.1 Suitable extinguishing media Water fog. Dry chemical. Carbon dioxide (CO2). Foam. Alcohol foam. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fire and Explosion Hazards Vapors may form explosive mixture in air between upper and lower explosive limits which can be ignited by many sources, such as pilot lights, open flames, electrical motors and switches. Empty containers contain residue and/or vapors. Do not weld, cut, pressurize, braze, solder, drill, grind, or expose such containers to heat, sparks, flame, static electricity, or other sources of ignition. They may explode and cause injury or death. Sensitivity to shock No information available. Page 1 / 4 Emergency Overview Contents under pressure. May cause eye/skin irritation. Harmful by inhalation. Page 720 of 871 Page 720 of 871 Page 720 of 871 Page 720 of 871 ---PAGE BREAK--- Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Personnel should wear appropriate protective equipment. Follow all precautions for handling. Please refer to appropriate sections of MSDS for additional information. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. Collect and contain for disposal. 7. HANDLING AND STORAGE Handling Thoroughly wash hands and exposed skin after handling. Keep in a well- ventilated place. Use only according to label directions. Ground and bond containers when transferring material. Containers can contain residues. Do not puncture or incinerate. Avoid using sparking tools. Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing before re-use. Keep container closed when not in use. Storage Do not freeze. Keep container closed. Do not store or use in containers made of tin, aluminum, zinc, or alloys of these metals. Store in temperatures below 120 degrees F (50 degrees C) . Keep away from heat and sources of ignition. Keep away from direct sunlight. NFPA Storage Code Store as Level 1 Aerosol (NFPA 30B) 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Isopropyl alcohol 400 ppm 980 mg/m3 - 200 ppm 400 ppm Propane/Isob utane/N- Butane - - - N/D 2- Butoxyethanol 50 ppm 240 mg/m3 - 20 ppm - Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Use in a well ventilated area. Hygiene measures Wash hands before eating or using the washroom. Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes and clothing. Respiratory protection Follow OSHA respirator regulations (29 CFR 1910.134) and if necessary, wear a MSHA/NIOSH approved respirator. Hand Protection Chemical resistant gloves. Eye protection Use safety eyewear designed to protect against splash of liquids. ANSI approved safety glasses or splash goggles with face shield are recommended. Skin and body protection Rubber or plastic boots. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Colorless Odor Lemon / Citric Odor Threshold Not Applicable pH 10 Specific Gravity 0.9399 Vapor pressure No data available Vapor density >Air Evaporation Rate >1 (Butyl Acetate = 1) Water solubility Miscible VOC Content 11.98%; 112 g/L; 0.94 lbs/gal Partition Coefficient (n-octanol/water) Not Applicable Boiling point/range °C -24 - 171 Boiling point/range °F -12 - 340 Melting point/range °C No data available Melting point/range °F No data available Flash point °C -104 Flash point °F -156 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Exposure to open flame. Avoid open flames. Avoid extreme temperatures. Do not puncture, incinerate or expose to temperatures above 120 degrees F. Incompatability Strong acids. Strong mineral acids. Strong oxidizing agents. Halogens. Hazardous Decomposition Products Carbon oxides. Aldehydes. Hydrocarbons. Carbon monoxide. Carbon dioxide. smoke. Fumes. ketones. organic acids . Page 2 / 4 Product name Screen Clean Product code P93160 Page 721 of 871 Page 721 of 871 Page 721 of 871 Page 721 of 871 ---PAGE BREAK--- Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Isopropyl alcohol 67-63-0 4396 mg/kg 12800 mg/kg 16000 ppm Propane/Isobutan e/N-Butane 68476-86-8 - - - 2-Butoxyethanol 111-76-2 470 mg/kg 220 mg/kg 450 ppm Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity See Section 2 . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects See Section 2 Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Isopropyl alcohol A4 Not Listed Not Listed Not Listed Not Listed Propane/Isob utane/N- Butane Not Listed Not Listed Not Listed Not Listed Not Listed 2- Butoxyethanol A3 Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT Consumer commodity, ORM-D. TDG Consumer commodity, ORM-D. 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Isopropyl alcohol Listed 2-Butoxyethanol Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Isopropyl alcohol Listed Listed Not Listed Propane/Isobutane/N- Butane Not Listed Not Listed Not Listed 2-Butoxyethanol Listed Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA Isopropyl alcohol X X - X Propane/Isobutane/N- Butane X X - X 2-Butoxyethanol X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION HMIS Health - 2 Flammability - 2 Physical Hazard - 0 Prepared By J. Cameron, Regulatory Affairs Coordinator Page 3 / 4 Water Flea Data Daphnia magna EC501698 - 1940 mg/L (24 h) Daphnia magna EC50>1000 mg/L (48 h) Microtox Data Photobacterium phosphoreum EC50=35390 mg/L (5 min) Product code P93160 Water Flea Data Daphnia magna EC50=13299 mg/L (48 h) Isopropyl alcohol 2-Butoxyethanol Product name Screen Clean Page 722 of 871 Page 722 of 871 Page 722 of 871 Page 722 of 871 ---PAGE BREAK--- The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product code P93160 Product name Screen Clean Page 723 of 871 Page 723 of 871 Page 723 of 871 Page 723 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 06-Feb-2014 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code P92385 Product name SEALICONE CLEAR 7-1/4 OZ NW Recommended Use Sealant Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known. Principal Routes of Exposure Eyes. Inhalation. Potential health effects Eyes Uncured product contact irritates eyes. Skin May produce the following results in the uncured state: . Irritation of lips, gums and tongue. Inhalation May cause the following effects. Respiratory irritation. Ingestion May cause gastric distress.. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Dimethyl Siloxane Hydroxy Terminated 70131-67-8 60-100 Silicon Dioxide - hydrated 7631-86-9 7-13 Silane 22984-54-9 3-7 1,1-Difluoroethane 75-37-6 1-5 4. FIRST AID MEASURES Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek medical attention. Skin contact To clean from skin, remove completely with a dry cloth or paper towel before washing with detergent and water. Get medical attention if irritation develops.. Ingestion No first aid should be needed.. Inhalation Remove to fresh air. 5. FIRE FIGHTING MEASURES Flash point °C Not Applicable Flash point °F Not Applicable Method Not Applicable Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper No data available Lower No data available Suitable extinguishing media Carbon dioxide (CO2). Water. Water fog. Dry chemical powder. Foam. Water spray. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fire and Explosion Hazards Contact with open flame or hot surfaces may generate toxic fumes. Hazardous decomposition products See Section 10. Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Page 1 / 4 Emergency Overview Contents under pressure. Irritating to eyes. Page 724 of 871 Page 724 of 871 Page 724 of 871 Page 724 of 871 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Personnel should wear appropriate protective equipment. Follow all precautions for handling. Please refer to appropriate sections of MSDS for additional information. Soak up with inert absorbent material. Place in non-leaking, sealed container for proper disposal. Use caution as spill may create a slip hazard. 7. HANDLING AND STORAGE Handling Avoid contact with skin and eyes. Do not handle contact lenses until all sealant has been cleaned from the fingertips, nails, and cuticles. Wash hands with soap and water before eating, drinking, smoking, or using toilet facilities. If container is an aerosol product: Propellant remains in can during and after normal use and is not expelled with product. DO NOT remove rubber plug from bottom of container.. Storage Store in a well ventilated area. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Dimethyl Siloxane Hydroxy Terminated - - - - Silicon Dioxide - hydrated 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction) 10 ppm 10 mg/m3 (total dust) ND etoxime) Silane - - - - 1,1- Difluoroethan e - - - - Ventilation and Environmental Controls Provide adequate ventilation to keep exposure limits below applicable limits. Hygiene measures Wash hands before breaks and immediately after handling the product. Respiratory protection None required if adequate ventilation is provided. Hand Protection Cotton gloves. Eye protection Safety glasses. Skin and body protection None necessary under normal conditions Other Protective Equipment An eye wash station should be available. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Paste Color Clear Odor Mild Odor Threshold No information available pH No data available Specific Gravity 1.04 @ 77F (25C) Vapor pressure No data available Vapor density No data available Evaporation Rate No data available Water solubility No data available VOC Content Partition Coefficient (n-octanol/water) No data available Boiling point/range °C No data available Boiling point/range °F No data available Melting point/range °C Not Applicable Melting point/range °F Not Applicable Flash point °C Not Applicable Flash point °F Not Applicable 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid Oxidizing material can cause a reaction. Water, moisture, or humid air can cause hazardous vapors to form.. Incompatability Water. Moisture. Humid air. Oxidizers. Hazardous Decomposition Products Sulphur oxides. Carbon dioxide. Silicone dioxide. Iodine compounds. formaldehyde. Page 2 / 4 Product name SEALICONE CLEAR 7-1/4 OZ NW Product code P92385 Page 725 of 871 Page 725 of 871 Page 725 of 871 Page 725 of 871 ---PAGE BREAK--- Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Dimethyl Siloxane Hydroxy Terminated 70131-67-8 - 16 mL/kg 8750 mg/m3 Silicon Dioxide - hydrated 7631-86-9 5000 mg/kg 2000 mg/kg 2.2 mg/L ime) Silane 22984-54-9 - - - 1,1- Difluoroethane 75-37-6 - - - Synergistic Products None known Potential health effects Sensitization None known . Chronic toxicity None known . Mutagenic effects None known . Teratogenic effects None known . Reproductive toxicity None known . Target Organ Effects None Known. Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Dimethyl Siloxane Hydroxy Terminated Not Listed Not Listed Not Listed Not Listed Not Listed Silicon Dioxide - hydrated Not Listed Not Listed Not Listed Not Listed Not Listed etoxime) Silane Not Listed Not Listed Not Listed Not Listed Not Listed 1,1- Difluoroethan e Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT Not Regulated TDG Not Regulated 15. REGULATORY INFORMATION US EPA SARA 313 This product contains no listed chemicals subject to reporting State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Dimethyl Siloxane Hydroxy Terminated Not Listed Not Listed Not Listed Silicon Dioxide - hydrated Listed Listed Not Listed Silane Not Listed Not Listed Not Listed 1,1-Difluoroethane Listed Not Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA Dimethyl Siloxane Hydroxy Terminated - X - X Silicon Dioxide - hydrated X X - X Silane X X - X 1,1-Difluoroethane X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. OTHER INFORMATION Page 3 / 4 Water Flea Data Ceriodaphnia dubia EC50=7600 mg/L (48 h) Product name SEALICONE CLEAR 7-1/4 OZ NW Silicon Dioxide - hydrated Product code P92385 Page 726 of 871 Page 726 of 871 Page 726 of 871 Page 726 of 871 ---PAGE BREAK--- 16. OTHER INFORMATION NFPA Health - 2 Flammability - 1 Reactivity - 0 HMIS Health - 2 Flammability - 1 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product code P92385 Product name SEALICONE CLEAR 7-1/4 OZ NW Page 727 of 871 Page 727 of 871 Page 727 of 871 Page 727 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 10-Feb-2014 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code DA6120 Product name Sleet Recommended Use Winter Products Supplier Drummond, A Lawson Brand Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Skin contact. Ingestion. Potential health effects Eyes May cause irritation. Conjunctivitis. Skin Repeated or prolonged exposure may cause:. Skin Irritation. Prolonged skin contact may defat the skin and produce dermatitis. Exposure can dry the skin. Inhalation Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Prolonged inhalation may be harmful . Chest discomfort. Narcosis. Coughing. Causes delayed lung injury. Central nervous system damage. Loss of coordination. Weakness. Fatigue. Confusion. Blurred vision. Ingestion Exposure by ingestion of an aerosol is unlikely. Components of the product may be absorbed into the body by ingestion.. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Ethyl Alcohol 64-17-5 30-60 Isopropyl alcohol 67-63-0 30-60 Carbon Dioxide 124-38-9 1-5 4. FIRST AID MEASURES Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses. Continue rinsing. Seek medical attention if irritation persists. Skin contact Remove contaminated clothing. Flush skin with water and follow by washing skin with soap and water. Seek medical attention if irritation persists. For minor skin contact, avoid spreading material on unaffected skin.. Ingestion If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not induce vomiting without advice from poison control center. Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one- way valve or other proper respiratory medical device. If ingestion of a large amount does occur, call a poison control center immediately.. Inhalation Move to fresh air. If breathing is difficult, give oxygen. Administer artificial respiration if not breathing. Seek medical attention. Notes to physician may be delayed. 5. FIRE FIGHTING MEASURES Flash point °C 16.1C Flash point °F 60.8F Method No information available Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper No data available Lower No data available Specific Information for Aerosol Products Flashback Unknown Suitable extinguishing media Foam. Carbon dioxide (CO2). Dry powder. Page 1 / 4 Emergency Overview Extremely Flammable Aerosol. Contents under pressure. Harmful in contact with eyes.. Prolonged exposure may cause chronic effects.. Page 728 of 871 Page 728 of 871 Page 728 of 871 Page 728 of 871 ---PAGE BREAK--- Special protective equipment for firefighters In the event of fire and/or explosion do not breathe fumes . Special Fire-Fighting Procedures Water should be used to cool closed containers to prevent pressure build- up and possible autoignition or explosion when exposed to extreme heat. Keep containers cool. Use shielding to protect against bursting or venting containers. Water from fogging nozzles may be used to cool closed containers to prevent build-up if exposed to extreme temperatures.. Specific hazards Runoff to sewer may cause fire or explosion hazard.. Fire and Explosion Hazards Aerosol containers may vent, rupture or burst when heated to temperatures above 120°F. Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Clean-up methods - small spill Soak up excess with absorbent material. Clean contaminated surface thoroughly. 7. HANDLING AND STORAGE Handling Pressurized container: Do not pierce or burn, even after use. Do not smoke while using or until sprayed surface is thoroughly dry. Do not use if spray button is missing or defective. Do not re-use empty containers. Do not get this material in contact with eyes. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with skin. . Storage Do not puncture, incinerate or crush. The pressure in sealed containers can increase under the influence of heat. Avoid exposure to long periods of sunlight. Store in cool place. Keep away from food, drink and animal feedingstuffs.. NFPA Storage Code Store as Level 2 Aerosol (NFPA 30B) 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Ethyl Alcohol 1000 ppm 1900 mg/m3 - - 1000 ppm Isopropyl alcohol 400 ppm 980 mg/m3 - 200 ppm 400 ppm Carbon Dioxide 5000 ppm 9000 mg/m3 - 5000 ppm 30000 ppm Ventilation and Environmental Controls Provide local exhaust ventilation. Mechanical: optional. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Respiratory protection None required if adequate ventilation is provided. Use NIOSH approved respirator if TLV limit is exceeded. Hand Protection Chemical resistant gloves. Eye protection Goggles. Safety glasses with side-shields. Skin and body protection Impervious clothing. Other Protective Equipment An eye wash station should be available. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Colorless Odor Alcoholic Odor Threshold Not Applicable pH No data available Specific Gravity 0.7769 estimated Vapor pressure psig @72F: 85 Density 0.7768 Vapor density > 1 (Air=1) Evaporation Rate < 1 (ether = 1) Water solubility Soluble in water VOC Content 92% Partition Coefficient (n-octanol/water) Not Applicable Boiling point/range °C 86.1C Boiling point/range °F 186.8F Melting point/range °C No data available Melting point/range °F No data available Flash point °C 16.1C Flash point °F 60.8F 10. STABILITY AND REACTIVITY Stability Risk of ignition. Conditions to avoid Aerosol containers are unstable at temperatures above 49C. Avoid high temperatures.. Incompatability No information available Hazardous Decomposition Products No information available Polymerization Hazardous polymerization does not occur Page 2 / 4 Product name Sleet Product code DA6120 Page 729 of 871 Page 729 of 871 Page 729 of 871 Page 729 of 871 ---PAGE BREAK--- 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Ethyl Alcohol 64-17-5 - - 124.7 mg/L Isopropyl alcohol 67-63-0 4396 mg/kg 12800 mg/kg 16000 ppm Carbon Dioxide 124-38-9 - - - Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity None known Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects Central nervous system. Lungs. Other adverse effects Pregnant women or women of child- bearing age should not be exposed to this product.. Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Ethyl Alcohol A3 Group 1 Not Listed Not Listed Listed Isopropyl alcohol A4 Not Listed Not Listed Not Listed Not Listed Carbon Dioxide Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Ecotoxicity effects Contains a substance which causes risk of hazardous effects to the environment 13. DISPOSAL CONSIDERATIONS Disposal Information Dispose in accordance with federal, state, and local regulations. Please recycle empty container whenever possible. As supplied, this product is a RCRA Hazardous Waste . Do not incinerate. 14. TRANSPORTATION INFORMATION DOT UN1950 Aerosols, flammable, 2.1. This product meets the "Limited quantity" exemption TDG UN1950 AEROSOLS, flammable, 2.1 This product meets the "Limited quantity" exemption. 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Isopropyl alcohol Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Ethyl Alcohol Not Listed Listed not listed Isopropyl alcohol Listed Listed Not Listed Carbon Dioxide Not Listed Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA Ethyl Alcohol X X - X Isopropyl alcohol X X - X Carbon Dioxide X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION HMIS Health - 1 Flammability - 3 Physical Hazard - 0 Page 3 / 4 Microtox Data Photobacterium phosphoreum EC50=35390 mg/L (5 min) Microtox Data Photobacterium phosphoreum EC50=34634 mg/L (30 min) Photobacterium phosphoreum EC50=35470 mg/L (5 min) Water Flea Data Daphnia magna EC50=13299 mg/L (48 h) Product code DA6120 Product name Sleet Water Flea Data Daphnia magna LC509268 - 14221 mg/L (48 h) Daphnia magna EC50=2 mg/L (48 h) Ethyl Alcohol Isopropyl alcohol Page 730 of 871 Page 730 of 871 Page 730 of 871 Page 730 of 871 ---PAGE BREAK--- 16. OTHER INFORMATION Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product code DA6120 Product name Sleet Page 731 of 871 Page 731 of 871 Page 731 of 871 Page 731 of 871 ---PAGE BREAK--- M A T E R I A L S A F E T Y D A T A S H E E T Page 1 of 5 Sikaflex® 15LM (All Colors) HMIS HEALTH *2 FLAMMABILITY 1 REACTIVITY 0 PERSONAL PROTECTION C 1. Product And Company Identification Supplier Manufacturer Sika Corporation Sika Corporation 201 Polito Ave 201 Polito Ave NJ 07071 NJ 07071 Company Contact: EHS Department Company Contact: EHS Department Telephone Number: [PHONE REDACTED] Telephone Number: [PHONE REDACTED] FAX Number: [PHONE REDACTED] FAX Number: [PHONE REDACTED] Web Site: www.sikausa.com Web Site: www.sikausa.com Supplier Emergency Contacts & Phone Number Manufacturer Emergency Contacts & Phone Number CHEMTREC: [PHONE REDACTED] CHEMTREC: [PHONE REDACTED] INTERNATIONAL: [PHONE REDACTED] INTERNATIONAL: [PHONE REDACTED] Issue Date: 03/09/2005 Product Name: Sikaflex® 15LM (All Colors) Chemical Family: Polyurethane Chemical Formula: RMF-2817 MSDS Number: 3500 Product Code: 0440545 2. Composition/Information On Ingredients Ingredient CAS Percent Of Name Number Total Weight POLYISOCYANATE PREPOLYMER Trade Secret XYLENE (MIXED ISOMERS) 1330-20-7 < 4 3. Hazards Identification Eye Hazards Causes eye irritation. Skin Hazards May cause skin irritation. Prolonged and/or repeated skin contact may cause an allergic reaction/sensitization. Ingestion Hazards May be harmful if swallowed. Inhalation Hazards May cause respiratory tract irritation. May cause nose, throat, and lung irritation. May cause an allergic respiratory reaction / sensitization after prolonged or repeated contact. Reports have associated repeated and prolonged exposure to some of the chemicals in this product with permanent brain, liver, kidney, and Central Nervous Page 732 of 871 Page 732 of 871 Page 732 of 871 Page 732 of 871 ---PAGE BREAK--- M A T E R I A L S A F E T Y D A T A S H E E T Page 2 of 5 Sikaflex® 15LM (All Colors) 3. Hazards Identification - Continued Inhalation Hazards - Continued System damage. Headaches and dizziness may result. 4. First Aid Measures Eye In case of contact, hold eyelids apart and immediately flush eyes with plenty of tepid water for at least 15 minutes. Get medical attention immediately if irritation develops and persists. Skin In case of contact, immediately flush skin with soap and plenty of tepid water for at least 15 minutes. Get medical attention immediately if irritation (redness, rash, blistering) develops and persists. Ingestion If swallowed, do not induce vomiting unless directed to do so by medical personnel. Inhalation Remove to fresh air. If not breathing, give artificial respiration and seek medical attention. 5. Fire Fighting Measures Flash Point: 143 °F Autoignition Point: N/AV °F Fire And Explosion Hazards During a fire, irritating and/or toxic gases and aerosols from the decomposition/combustion products may be present. Extinguishing Media In case of fire, use water spray (fog) foam, dry chemical, or CO2. Fire Fighting Instructions In the event of a fire, firefighters should wear full protective clothing and NIOSH-approved self-contained breathing apparatus with a full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Avoid release to the environment. Use appropriate Personal Protective Equipment (PPE). Contain spill and collect with absorbent material and transfer into suitable containers. Do not flush to sewer or allow to enter waterways. Ventilate enclosed area. 7. Handling And Storage Handling And Storage Precautions Keep out of reach of children. Store in a cool, dry, well ventilated area. Keep containers closed. Store at 40-95F. Condition to 65-85F before using. If closed container is exposed to heat, pressure can build up. If moisture enters container, pressure may build up due to reaction. Store in cool dry area in closed containers, away from sparks of open flames. Work/Hygienic Practices Wash thoroughly with soap and water after handling. 8. Exposure Controls/Personal Protection Engineering Controls Use of a system of local and/or general exhaust is recommended to keep employee below applicable expsoure limits. Refer to the current edition of "Industrial Ventilation: A Manual of Recommended Practice" published by the American Conference of Governmental Industrial Hygienists for information on the design, installation, use, and maintenance of exhaust systems. Page 733 of 871 Page 733 of 871 Page 733 of 871 Page 733 of 871 ---PAGE BREAK--- M A T E R I A L S A F E T Y D A T A S H E E T Page 3 of 5 Sikaflex® 15LM (All Colors) 8. Exposure Controls/Personal Protection - Continued Eye/Face Protection Safety glasses with side shields or goggles. Skin Protection Chemical-resistant gloves. Lab coat or other work clothing. Launder before reuse. Respiratory Protection A respirator protection program that meets 29 CFR 1910.134 requirement must be followed whenever workplace conditions warrant a respirator's use. In areas where the Permissible Expsosure Limits are exceeded, use a properly fitted NIOSH-approved respirator. Other/General Protection Wash thoroughly after handling. Ingredient(s) - Exposure Limits XYLENE (MIXED ISOMERS) ACGIH TLV-STEL 150 ppm ACGIH TLV-TWA 100 ppm OSHA PEL-TWA 100 ppm 9. Physical And Chemical Properties Appearance Paste (various colors) Odor Aromatic Odor Chemical Type: Mixture Physical State: Solid Melting Point: N/AV °F Boiling Point: N/AV °F Specific Gravity: 1.19 Percent Volatiles: < 4% Percent VOCs: < 4% Packing Density: 10 pounds/gallon Vapor Pressure: N/AV Vapor Density: > AIR S o l u b i l i t y : N/AV Evaporation Rate: Slower than ether VOC Content: 47.9 grams / liter 10. Stability And Reactivity S t a b i l i t y : Stable Hazardous Polymerization: Will not occur Conditions To Avoid (Stability) Open flame, heat Incompatible Materials Water, Alcohols, and Amines. Hazardous Decomposition Products CO, CO2, Oxides of Nitrogen, Smoke, Fumes Page 734 of 871 Page 734 of 871 Page 734 of 871 Page 734 of 871 ---PAGE BREAK--- M A T E R I A L S A F E T Y D A T A S H E E T Page 4 of 5 Sikaflex® 15LM (All Colors) 11. Toxicological Information No Data Available... 12. Ecological Information No Data Available... 13. Disposal Considerations Dispose in accordance with applicable federal, state and local government regulations. Waste generators must determine whether a discarded material is classified as a hazardous waste. USEPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. 14. Transport Information Proper Shipping Name Not regulated by the USDOT. 15. Regulatory Information U.S. Regulatory Information All ingredients of this product are listed or are excluded from listing under the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. SARA Hazard Classes Acute Health Hazard Chronic Health Hazard SARA Title III - Section 313 Supplier Notification This product contains the following toxic chemicals that are subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372. XYLENE (MIXED ISOMERS) (1330-20-7) <4 % This information must be included on all that are copied and distributed for this material. Ingredient(s) - U.S. Regulatory Information XYLENE (MIXED ISOMERS) SARA Title III - Section 313 Form "R"/TRI Reportable Chemical Ingredient(s) - State Regulations XYLENE (MIXED ISOMERS) New Jersey - Workplace Hazard New Jersey - Environmental Hazard New Jersey - Special Hazard - Workplace Hazard - Environmental Hazard Massachusetts - Hazardous Substance New York City - Hazardous Substance 16. Other Information HMIS Rating H e a l t h : *2 F i r e : 1 R e a c t i v i t y : 0 P P E : C Page 735 of 871 Page 735 of 871 Page 735 of 871 Page 735 of 871 ---PAGE BREAK--- M A T E R I A L S A F E T Y D A T A S H E E T Page 5 of 5 Sikaflex® 15LM (All Colors) 16. Other Information - Continued Revision/Preparer Information MSDS Preparer: EHS Department MSDS Preparer Phone Number: [PHONE REDACTED] This MSDS Supercedes A Previous MSDS Dated: 02/24/2005 Disclaimer The data in this Material Safety Data Sheet relates only to the specific material herein and does not relate to use in combination with any other material or in any process. The information set forth herein is based on technical data that Sika believes to be reliable as of the date hereof. Since conditions of use are outside our control, we make no warranties, express or implied and assume no liability in connection with any use of this information. Nothing herein is to be taken as a license to operate under or a recommendation to infringe any patents. SIKA CORPORATION Printed Using MSDS Generator™ 2000 Page 736 of 871 Page 736 of 871 Page 736 of 871 Page 736 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 08-Jul-2013 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 19902 Product name Silicone Lubricant Recommended Use Lubricant Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Eyes. Skin contact. Inhalation. Ingestion. Skin absorption. Potential health effects Eyes Contact with eyes may cause irritation. Skin May cause the following effects: . Skin Irritation. Dermatitis. Repeated or prolonged exposure may cause:. Redness. Frostbite. Possible burns to tissue. May be absorbed through the skin in harmful amounts. Inhalation May cause the following effects. Shortness of breath. Dizziness. Light headedness. Extreme overexposure may cause. Liver damage. Kidney damage. Possible Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Ingestion May be harmful if swallowed. Gastrointestinal irritation. Aspiration hazard. May cause severe lung damage if aspirated into the lungs from ingestion or vomiting. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Petroleum distillates, hydrotreated light 64742-47-8 39-44 Propane 74-98-6 22-27 Butane 106-97-8 17-22 Hexane 110-54-3 15-20 4. FIRST AID MEASURES Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 20 minutes. Seek medical attention. Skin contact Wash area thoroughly with soap and water. Ingestion If a large quantity of liquid is swallowed, do NOT induce vomiting. Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. Seek medical attention. Inhalation Remove to fresh air. Provide oxygen if breathing is difficult. If not breathing, give artificial respiration. Keep warm and quiet. Seek medical attention. 5. FIRE FIGHTING MEASURES Flash point °C -104 Flash point °F -156 Method No information available Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 9.5% Lower 1.2% Suitable extinguishing media Water fog. Carbon dioxide (CO2). Dry chemical powder. Foam. Alcohol foam. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 1 / 4 Emergency Overview Flammable. Irritant. Page 737 of 871 Page 737 of 871 Page 737 of 871 Page 737 of 871 ---PAGE BREAK--- Fire and Explosion Hazards Flammable . Evacuate area of unprotected and unnecessary personnel. Material is highly volatile and readily gives off vapors. Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat . Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Shut off source of leak if safe to do so. Evacuate area of unprotected and unnecessary personnel. Ventilate area to maintain exposure below permissible exposure limits. Dike or dam large spills. Soak up excess with absorbent material. Dispose of absorbent in accordance with local, state and federal regulations. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. 7. HANDLING AND STORAGE Handling Keep container closed when not in use. Storage Keep container closed. Keep away from direct sunlight. Keep away from open flames, hot surfaces and sources of ignition. Store in temperatures below 120 degrees F (50 degrees C) . Containers exposed to extreme heat may burst. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Petroleum distillates, hydrotreated light - - - - Hexane 500 ppm 1800 mg/m3 - 50 ppm N/D Butane 800 ppm - - 1000 ppm Propane 1000 ppm 1800 mg/m3 - 1000 ppm - Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. If current ventilation practices are not adequate in maintaining airborne concentrations below the established exposure limits, additional ventilation or exhaust systems may be required. Use with adequate explosion-proof ventilation to meet the limits in Section 8 . Hygiene measures Remove and wash contaminated clothing before re-use. Other precautions Use personal protective equipment. Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Hand Protection Gloves are recommended to prevent prolonged or repeated contact. Protective gloves. Eye protection Safety glasses with side-shields. Skin and body protection None necessary under normal conditions 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Clear Odor Solvent Odor Threshold No information available pH Not Applicable Specific Gravity No data available Vapor pressure No data available Vapor density No data available Evaporation Rate <1 (ether = 1) Water solubility No data available VOC Content 58% by weight Partition Coefficient (n-octanol/water) No data available Boiling point/range °C No data available Boiling point/range °F No data available Melting point/range °C No data available Melting point/range °F No data available Flash point °C -104 Flash point °F -156 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Heat, flames and sparks. Incompatability Strong oxidizing agents. Page 2 / 4 Product code 19902 Product name Silicone Lubricant Page 738 of 871 Page 738 of 871 Page 738 of 871 Page 738 of 871 ---PAGE BREAK--- Hazardous Decomposition Products Carbon dioxide. Carbon monoxide. Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Petroleum distillates, hydrotreated light 64742-47-8 5000 mg/kg 2000 mg/kg 5.2 mg/L Hexane 110-54-3 - 3000 mg/kg 48000 ppm Butane 106-97-8 - - 658 g/m3 Propane 74-98-6 - - 658 mg/L Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity None known Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects Kidney. Liver. Central nervous system. Carcinogenic effects See Table Below. Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Petroleum distillates, hydrotreated light Not Listed Not Listed Not Listed Not Listed Not Listed Hexane Not Listed Not Listed Not Listed Not Listed Not Listed Butane Not Listed Not Listed Not Listed Not Listed Not Listed Propane Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Disposal Information Full or partially full containers are considered hazardous waste. Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT Consumer commodity, ORM-D. TDG Consumer commodity, ORM-D. 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Hexane Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Petroleum distillates, hydrotreated light Not Listed Not Listed Not Listed Hexane Listed Listed Not Listed Butane Listed Listed Not Listed Propane Listed Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA Petroleum distillates, hydrotreated light X X - X Hexane X X - X Butane X X - X Propane X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. OTHER INFORMATION NFPA Page 3 / 4 Water Flea Data Daphnia magna EC50>1000 mg/L (24 h) Product name Silicone Lubricant Water Flea Data Den-dronereides heteropoda LC50=4720 mg/L (96 h) Product code 19902 Hexane Petroleum distillates, hydrotreated light Page 739 of 871 Page 739 of 871 Page 739 of 871 Page 739 of 871 ---PAGE BREAK--- 16. OTHER INFORMATION Health - 2 Flammability - 4 Reactivity - 0 HMIS Health - 2 Flammability - 4 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product code 19902 Product name Silicone Lubricant Page 740 of 871 Page 740 of 871 Page 740 of 871 Page 740 of 871 ---PAGE BREAK--- Material Safety Data Sheet Date of issue 11/05/09 Product name SILICONE LUBRICANT & MOLD RELEASE Product code R257 Supersedes Product use Silicone Lubricant Emergency Telephone Numbers For MSDS Information: Compliance Services 1-[PHONE REDACTED] For Medical Emergency (877) 541-2016 Toll Free - All Calls Recorded For Transportation Emergency CHEMTREC: (800) 424-9300 - All Calls Recorded In the District of Columbia (202) 483-7616 Prepared By Compliance Services 1420 Seaboard Industrial Blvd. Atlanta, GA 30318 Section 1. Chemical Product and Company Identification Zep Inc. 1310 Seaboard Industrial Blvd. Atlanta, GA 30318 1-[PHONE REDACTED] Emergency overview DANGER ! CAUSES EYE IRRITATION. MAY CAUSE SKIN IRRITATION. HARMFUL OR FATAL IF SWALLOWED. COMBUSTIBLE. *Hazard Determination System (HDS): Health, Flammability, Reactivity Acute Effects Eyes Skin Inhalation Ingestion Routes of Entry Dermal contact. Eye contact. Inhalation. Causes eye irritation. Inflammation of the eye is characterized by redness, watering and itching. May cause skin irritation. Skin inflammation is characterized by itching, scaling, or reddening. Inhalation of oil mist or vapors at elevated temperatures may cause respiratory irritation. Can cause central nervous system (CNS) depression. May be fatal if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage. NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse effects are lessened by following all prescribed safety precautions, including the use of proper personal protective equipment. Carcinogenicity Chronic effects No known significant effects or critical hazards. Prolonged or repeated contact may dry skin and cause irritation. Contains material which may cause damage to the following organs: central nervous system (CNS). Additional Information: See Toxicological Information (Section 11) Section 2. Hazards Identification 2 2 0 Product/ingredient name Not available. Name of Hazardous Ingredients CAS number % by Weight ODORLESS ALIPHATIC NAPHTHA; heavy alkylate petroleum naphtha; odorless mineral spirits 64741-65-7 50 - 60 ISOPARAFFINIC SOLVENT; hydrotreated light distillate (petroleum) 64741-73-7 25 - 35 Section 3. Composition/Information on Ingredients Eye Contact Skin Contact Inhalation Ingestion Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention immediately. Flush affected skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Get medical attention if irritation develops. Move exposed person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. If affected person is conscious, give plenty of water to drink. Never give anything by mouth to an unconscious person. Get medical attention immediately. Section 4. First Aid Measures Page: 1/3 Page 741 of 871 Page 741 of 871 Page 741 of 871 Page 741 of 871 ---PAGE BREAK--- Material Safety Data Sheet Product Name SILICONE LUBRICANT & MOLD RELEASE Product code R257 Closed cup: 51.6°C (125°F) (Tagliabue.) Flash Point Not available. National Fire Protection Association 2 2 0 Flammable Limits Flammability Fire hazard COMBUSTIBLE. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Combustible. Fire-Fighting Procedures Use dry chemical, CO2, water spray (fog) or foam. Section 5. Fire Fighting Measures Spill Clean up Eliminate all ignition sources. Put on appropriate personal protective equipment (see section Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion- proof equipment. Dispose of via a licensed waste disposal contractor. Section 6. Accidental Release Measures Handling Storage Put on appropriate personal protective equipment (see section Store and use away from heat, sparks, open flame or any other ignition source. Avoid contact with eyes, skin and clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wash thoroughly after handling. Do not reuse container. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Keep container closed and sealed until ready for use. Keep away from heat, sparks and flame. Keep out of the reach of children. Section 7. Handling and Storage Personal Protective Equipment (PPE) Eyes Body Respiratory Product name Exposure limits ODORLESS ALIPHATIC NAPHTHA; heavy alkylate petroleum naphtha; odorless mineral spirits OSHA PEL (United States). TWA: 500 ppm 8 hour(s). ACGIH TLV (United States). TWA: 100 ppm 8 hour(s). ISOPARAFFINIC SOLVENT; hydrotreated light distillate (petroleum) NIOSH REL (United States). TWA: 1200 mg/m³ Form: Vapor Safety glasses. Wear appropriate protective clothing to prevent skin contact. Recommended: Neoprene gloves. Nitrile gloves. Rubber gloves. Use with adequate ventilation. Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective occupational exposure limits. Wear appropriate respirator when ventilation is inadequate. Section 8. Exposure Controls/Personal Protection Physical State pH Boiling Point Specific Gravity Solubility Thin liquid Not applicable 179.44°C (355°F) 0.8 Color Odor Vapor Pressure Vapor Density Evaporation Rate VOC (Consumer) Clear. Colorless to light yellow. Hydrocarbon. [Slight] Not determined. >1 [Air = 1] <1 (butyl acetate = 1) 475.98 3.97 lbs/gal 59.60% Insoluble in the following materials: cold water and hot water. Section 9. Physical and Chemical Properties The product is stable. Will not occur. Stability and Reactivity Hazardous Decomposition Products Hazardous Polymerization Keep away from heat, sparks and flame. Reactive or incompatible with the following materials: oxidizing materials. Incompatibility carbon oxides (CO, CO2) Section 10. Stability and Reactivity Page: 2/3 Page 742 of 871 Page 742 of 871 Page 742 of 871 Page 742 of 871 ---PAGE BREAK--- Material Safety Data Sheet Product Name SILICONE LUBRICANT & MOLD RELEASE Product code R257 Acute Toxicity Product/ingredient name Result Species Dose Exposure Odorless Aliphatic Naphtha LD50 Oral Rat >18800 mg/kg - LC50 Inhalation Vapor Rat >5900 mg/m³ 4 hours Isoparaffinic Solvent; Hydrotreated light distillate (petroleum) LD50 Dermal Rabbit >2000 mg/kg - LD50 Oral Rat >2000 mg/kg - Section 11. Toxicological Information Environmental Effects No known significant effects or critical hazards. Aquatic Ecotoxicity Not available. Section 12. Ecological Information Waste Information Waste Stream Code: D001 Classification: - [Hazardous waste.] Origin: - [RCRA waste.] Section 13. Disposal Considerations Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or regional authorities for additional information. NOTE: DOT classification applies to most package sizes. For specific container size classifications or for size exceptions, refer to the Bill of Lading with your shipment. PG* : Packing group Regulatory information UN number Proper shipping name Classes PG* Label Not a DOT controlled material (United States). - - Not determined. Section 14. Transport Information DOT Classification IMDG Class Not regulated. U.S. Federal Regulations Clean Water Act (CWA) 311: No products were found. Clean Air Act (CAA) 112 regulated toxic substances: No products were found. State Regulations No products were found. California Prop 65 All Components of this product are listed or exempt from listing on TSCA Inventory. Section 15. Regulatory Information Clean Water Act (CWA) 307: No products were found. No products were found. SARA 313 toxic chemical notification and release reporting: To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. *NOTE: Hazard Determination System (HDS) ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although these ratings are not required on under 29 CFR 1910.1200, the preparer may choose to provide them. HDS ratings are to be used with a fully implemented program to relay the meanings of this scale. Section 16. Other Information Page 743 of 871 Page 743 of 871 Page 743 of 871 Page 743 of 871 ---PAGE BREAK--- Sluff Snowplow Treatment Not available. Aerosol. (888) 426-4851 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer : Drummond, A Lawson Brand Lawson Products, Inc. 8770 W. Bryn Mawr, Suite 900 Chicago, IL 60631-3515 7733045050 Relevant identified uses of the substance or mixture and uses advised against Not applicable. DA7940 DA7940 Product code : Section 2. Hazards identification FLAMMABLE AEROSOLS - Category 1 GASES UNDER PRESSURE - Compressed gas SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation and Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Classification of the substance or mixture : Signal word : Danger Hazard pictograms : Precautionary statements Prevention : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Pressurized container: Do not pierce or burn, even after use. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist. Response : Get medical attention if you feel unwell. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 62.3% General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May cause respiratory irritation. May cause drowsiness and dizziness. May cause damage to organs through prolonged or repeated exposure. : Hazard statements Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.06 1/11 Page 744 of 871 Page 744 of 871 Page 744 of 871 Page 744 of 871 ---PAGE BREAK--- Section 2. Hazards identification Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 Store in a well-ventilated place. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified :None known. Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do not discard empty can in trash compactor. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. FOR INDUSTRIAL USE ONLY. Section 3. Composition/information on ingredients Aliphatic Solvent 38.4 64742-47-8 Butane 37.7 106-97-8 Propane 17.3 74-98-6 6.6 63148-62-9 Ingredient name CAS number % by weight There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification : Not available. Substance/mixture CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention following exposure or if feeling unwell. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention following exposure or if feeling unwell. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.06 2/11 Page 745 of 871 Page 745 of 871 Page 745 of 871 Page 745 of 871 ---PAGE BREAK--- Section 4. First aid measures immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Most important acute and delayed Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. : Eye contact Over-exposure Skin contact Ingestion Inhalation Adverse may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness No specific data. No specific data. : : : Eye contact : Adverse may include the following: irritation redness Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.06 3/11 Page 746 of 871 Page 746 of 871 Page 746 of 871 Page 746 of 871 ---PAGE BREAK--- Section 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. : Protective measures Put on appropriate personal protective equipment (see Section Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not breathe vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. : Precautions for safe handling Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.06 4/11 Page 747 of 871 Page 747 of 871 Page 747 of 871 Page 747 of 871 ---PAGE BREAK--- Section 7. Handling and storage Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. : Aliphatic Solvent ACGIH TLV (United States, 6/2013). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours. Butane NIOSH REL (United States, 10/2013). TWA: 800 ppm 10 hours. TWA: 1900 mg/m³ 10 hours. ACGIH TLV (United States, 6/2013). STEL: 1000 ppm 15 minutes. Propane NIOSH REL (United States, 10/2013). TWA: 1000 ppm 10 hours. TWA: 1800 mg/m³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 1800 mg/m³ 8 hours. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection : : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Control parameters Individual protection measures Occupational exposure limits Skin protection Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.06 5/11 Page 748 of 871 Page 748 of 871 Page 748 of 871 Page 748 of 871 ---PAGE BREAK--- Section 8. Exposure controls/personal protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Respiratory protection : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. 0.65 1.55 [Air = 1] 13.5 kPa (101.325 mm Hg) [at 20°C] Not available. Not available. Odor pH Not available. Color Evaporation rate 0.009 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup] Not available. 7 Viscosity Kinematic (40°C (104°F)): <0.07 cm2/s cSt) Not available. Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Lower: 1.3% Upper: 9.5% Decomposition temperature : Not available. Type of aerosol : Spray Heat of combustion : 39.76 kJ/g Aerosol product Section 10. Stability and reactivity Conditions to avoid Avoid all possible sources of ignition (spark or flame). The product is stable. Chemical stability : : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.06 6/11 Page 749 of 871 Page 749 of 871 Page 749 of 871 Page 749 of 871 ---PAGE BREAK--- Section 10. Stability and reactivity Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. No specific data. : Incompatible materials : Section 11. Toxicological information Acute toxicity Butane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours Product/ingredient name Result Species Dose Exposure Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Irritation/Corrosion Eyes - Mild irritant Rabbit - 1 hours 100 milligrams - Eyes - Mild irritant Rabbit - 24 hours 100 microliters - Eyes - Moderate irritant Rabbit - 24 hours 100 microliters - Skin - Mild irritant Rabbit - 24 hours 500 microliters - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aliphatic Solvent Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Butane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Propane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Name Category Name Category Aliphatic Solvent Category 2 Not determined Not determined Butane Category 2 Not determined Not determined Propane Category 2 Not determined Not determined Route of exposure Target organs Route of exposure Target organs Information on toxicological effects Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.06 7/11 Page 750 of 871 Page 750 of 871 Page 750 of 871 Page 750 of 871 ---PAGE BREAK--- Section 11. Toxicological information Aspiration hazard Not available. Not available. Information on the likely routes of exposure Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. : Eye contact May cause damage to organs through prolonged or repeated exposure. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness No specific data. No specific data. : : : Eye contact : Adverse may include the following: irritation redness Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Not available. Acute toxicity estimates : Not available. Potential acute health effects Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.06 8/11 Page 751 of 871 Page 751 of 871 Page 751 of 871 Page 751 of 871 ---PAGE BREAK--- Section 12. Ecological information Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Not available. Toxicity Aliphatic Solvent Acute LC50 2200 µg/l Fresh water Fish - Lepomis macrochirus 4 days Acute LC50 44.5 ppm Fresh water Daphnia - Daphnia magna - Instar 48 hours Acute LC50 3160 µg/l Fresh water Fish - Ictalurus punctatus 96 hours Product/ingredient name Species Result Exposure Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Not available. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. : Disposal methods Section 14. Transport information AEROSOLS 2.1 - AEROSOLS 2.1 - UN1950 UN1950 DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No. No. TDG Classification UN1950 AEROSOLS 2.1 - No. Mexico Classification UN1950 AEROSOLS 2.1 - No. IATA UN1950 AEROSOLS, flammable 2.1 - No. Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.06 9/11 Page 752 of 871 Page 752 of 871 Page 752 of 871 Page 752 of 871 ---PAGE BREAK--- Section 14. Transport information Special provisions LIMITED QUANTITY Emergency schedules (EmS) LIMITED QUANTITY, F-D, S-U Additional information Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Not available. : Special provisions LIMITED QUANTITY Special provisions (ERG#126) Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. Special provisions LIMITED QUANTITY Section 15. Regulatory information U.S. Federal regulations : State regulations Section 16. Other information Notice to reader Hazardous Material Information System 2 4 0 Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). The customer is responsible for determining the PPE code for this material. Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.06 10/11 Page 753 of 871 Page 753 of 871 Page 753 of 871 Page 753 of 871 ---PAGE BREAK--- Section 16. Other information It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Date of issue/Date of revision : 9/19/2014. Date of previous issue : 9/19/2014. Version : 1.06 11/11 Page 754 of 871 Page 754 of 871 Page 754 of 871 Page 754 of 871 ---PAGE BREAK--- Material Safety Data Sheet Page 1 of 7 Section 1: Product & Company Identification Product Name: Smoke Test® Product Number 72105 Product Use: Smoke Detector Tester Manufacturer / Supplier Contact Information: In United States: In Canada: CRC Industries, Inc. CRC Canada Co. 885 Louis Drive 2-1246 Lorimar Drive Warminster, PA 18974 Mississauga, Ontario L5S 1R2 www.crcindustries.com www.crc-canada.ca 1-[PHONE REDACTED] (General) 1-[PHONE REDACTED] (800) 521-3168 (Technical) (800) 272-4620 (Customer Service) 24-Hr Emergency – CHEMTREC: (800) 424-9300 or (703) 527-3887 Section 2: Hazards Identification Emergency Overview DANGER: Extremely Flammable. Contents Under Pressure. Appearance & Odor: Packaged product is a clear, water-white liquid; dispensed product is a smoky mist; alcohol odor Potential Health Effects: ACUTE EFFECTS: EYE: Liquid contact can cause severe irritation, redness, tearing, blurred vision and possible freeze burns. The effects of eye contact with the spray mist are likely to be less severe. SKIN: Contact with evaporating liquid can cause frostbite. Contact with spray mist is not likely to produce health effects. INHALATION: Inhalation of vapor may produce anesthetic effects, irritation of nose and throat, and feeling of euphoria. Prolonged overexposure can cause rapid breathing, headache, dizziness, narcosis, central nervous system depression, unconsciousness or death from depending on concentration and duration of exposure. INGESTION: May cause gastrointestinal irritation, including nausea and vomiting. Ingestion of ethanol can cause drunkenness and central nervous system depression. CHRONIC EFFECTS: Ethanol is a developmental toxin and various effects have been associated with ethanol abuse, including physical dependence, cardiac myopathy, amnesia, and hepatotoxicity. TARGET ORGANS: Liver Medical Conditions Aggravated by Exposure: Pre-existing liver or nervous system conditions See Section 11 for toxicology and carcinogenicity information on product ingredients. Page 755 of 871 Page 755 of 871 Page 755 of 871 Page 755 of 871 ---PAGE BREAK--- Product Name: Smoke Test® Product Number 72105 Page 2 of 7 Section 3: Composition/Information on Ingredients COMPONENT CAS NUMBER % by Wt. Ethanol 64-17-5 25 – 35 1,2,3-Propanetriol 56-81-5 2 – 5 Liquefied petroleum gas 68476-86-8 65 - 75 Section 4: First Aid Measures Eye Contact: Immediately flush with plenty of water for 15 minutes. Call a physician if irritation persists. Skin Contact: Remove contaminated clothing and wash affected area with soap and water. Call a physician if irritation persists. Wash contaminated clothing prior to re-use. Inhalation: Remove person to fresh air. Keep person calm. If not breathing, give artificial respiration. If breathing is difficult give oxygen. Call a physician. Ingestion: Do not induce vomiting. If victim is completely conscious and alert, have them drink water. Contact a physician for further treatment. Note to Physicians: Treatment of overexposure should be directed at the control of and the clinical condition of the patient. Section 5: Fire-Fighting Measures Flammable Properties: This product is extremely flammable in accordance with aerosol flammability definitions. Use with caution around energized equipment. Flash Point: 56°F / 13°C (TCC) Upper Explosive Limit: 19.0 Autoignition Temperature: 363°F / 183.9°C Lower Explosive Limit: 3.3 Fire and Explosion Data: Suitable Extinguishing Media: Use Class B extinguishing agents such as dry chemical, CO2, water spray or alcohol- resistant foam. Products of Combustion: oxides of carbon, volatile hydrocarbon vapors Explosion Hazards: Aerosol containers, when exposed to heat from fire, may build pressure and explode. Vapors can accumulate and create a flammable atmosphere. Protection of Fire-Fighters: Firefighters should wear self-contained, NIOSH-approved breathing apparatus for protection against suffocation and possible toxic decomposition products. Proper eye and skin protection should be provided. Use water spray to keep fire-exposed containers cool and to knock down vapors which may result from product decomposition. Section 6: Accidental Release Measures Personal Precautions: Use personal protection recommended in Section 8. Environmental Precautions: Take precautions to prevent contamination of ground and surface waters. Do not flush into sewers or storm drains. Methods for Containment & Clean-up: Eliminate all sources of ignition. Dike area to contain spill. Ventilate the area Page 756 of 871 Page 756 of 871 Page 756 of 871 Page 756 of 871 ---PAGE BREAK--- Product Name: Smoke Test® Product Number 72105 Page 3 of 7 with fresh air. If in confined space or limited air circulation area, clean-up workers should wear appropriate respiratory protection. Recover or absorb spilled material using an absorbent designed for chemical spills. Place used absorbents into proper waste containers. Section 7: Handling and Storage Handling Procedures: Do not use this product near sources of ignition. Liquid contents are flammable. Dispensed mist can create flammable atmosphere. Use in ventilated areas only. Avoid inhaling vapors. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. For product use instructions, please see the product label. Storage Procedures: Store in a cool dry area out of direct sunlight. Aerosol cans must be maintained below 120°F / 49°C to prevent cans from rupturing. Store out of reach of children Aerosol Storage Level: III Section 8: Exposure Controls/Personal Protection Exposure Guidelines: OSHA ACGIH OTHER COMPONENT TWA STEL TWA STEL TWA SOURCE UNIT Ethanol 1000 NE NE 1000 NE ppm 1,2,3-Propanetriol 15 NE 10 NE NE mg/m3 Liquefied petroleum gas 1000 NE 1000 NE NE ppm N.E. – Not Established – ceiling – skin – vacated Controls and Protection: Engineering Controls: Area should have ventilation to provide fresh air. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at the source, preventing dispersion into the general work area. Use mechanical means if necessary to maintain vapor levels below the exposure guidelines. If working in a confined space, follow applicable OSHA regulations. Respiratory Protection: None required for normal work where adequate ventilation is provided. If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with organic vapor cartridge. Air monitoring is needed to determine actual employee exposure levels. Use a self-contained breathing apparatus in confined spaces and for emergencies. Eye/face Protection: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear splash-proof goggles. Skin Protection: Use protective gloves such as rubber, neoprene or vinyl. Also, use full protective clothing if there is prolonged or repeated contact of liquid with skin. Section 9: Physical and Chemical Properties Physical State: liquid (dispensed product is a mist) Color: colorless (dispensed product has smoky haze) Odor: alcohol Odor Threshold: ND Page 757 of 871 Page 757 of 871 Page 757 of 871 Page 757 of 871 ---PAGE BREAK--- Product Name: Smoke Test® Product Number 72105 Page 4 of 7 Specific Gravity: 0.817 Initial Boiling Point: 172.9°F / 78.3°C Freezing Point: - 173.4°F / -114.1°C Vapor Pressure: ~44.6 mmHg @ 68°F / 20°C Vapor Density: > 1 (air = 1) Evaporation Rate: very fast Solubility: complete Coefficient of water/oil distribution: ND pH: NA Volatile Organic Compounds: wt 97.5 g/L: 796.6 lbs./gal: 6.64 Section 10: Stability and Reactivity Stability: Stable Conditions to Avoid: excessive heat, sparks, open flame or other sources of ignition Incompatible Materials: acetyl chloride, or other strong oxidizing agents or strong acids Hazardous Decomposition Products: oxides of carbon; thermal decomposition may release acrolein Possibility of Hazardous Reactions: No Section 11: Toxicological Information Long-term toxicological studies have not been conducted for this product. The following information is available for components of this product. Acute Toxicity: Component Oral LD50 (rat) Dermal LD50 (rabbit) Inhalation LC50 (rat) Ethanol 760 mg/kg No data 20,000 ppm/10H 1,2,3-Propanetriol 12,600 mg/kg No data No data Liquefied petroleum gas No data No data No data Chronic Toxicity: Component OSHA Carcinogen IARC Carcinogen NTP Carcinogen Irritant Sensitizer Ethanol No No No Eye Unknown 1,2,3-Propanetriol No No No None Unknown Liquefied petroleum gas No No No None No Reproductive Toxicity: Ethanol: Developmental Toxin Teratogenicity: No information available Mutagenicity: No information available Synergistic Effects: No information available Section 12: Ecological Information Ecological studies have not been conducted for this product. The following information is available for components of this product. Ecotoxicity: Ethanol - 48 Hr EC50 Daphnia magna: 9268 mg/L 5 min EC50 Photobacterium phosphoreum: 35470 mg/L Page 758 of 871 Page 758 of 871 Page 758 of 871 Page 758 of 871 ---PAGE BREAK--- Product Name: Smoke Test® Product Number 72105 Page 5 of 7 Persistence / Degradability: Ethanol and 1,2,3-propanetriol are expected to be biodegradable. Bioaccumulation / Accumulation: Ethanol is not expected to bioaccumulate. Mobility in Environment: No information available Section 13: Disposal Considerations Waste Classification: Any liquid product would be a RCRA hazardous waste for the characteristic of ignitability with a waste code of D001. Empty aerosol containers may be recycled. All disposal activities must comply with federal, state, provincial and local regulations. Local regulations may be more stringent than state, provincial or national requirements. Section 14: Transport Information US DOT (ground): UN1950, Aerosol, flammable, 2.1, Limited Quantity ICAO/IATA (air): UN1950, Aerosol, flammable, 2.1, Limited Quantity IMO/IMDG (water): UN1950, Aerosols, 2.1, Limited Quantity Special Provisions: None Section 15: Regulatory Information U.S. Federal Regulations: Toxic Substances Control Act (TSCA): All ingredients are either listed on the TSCA inventory or are exempt. Comprehensive Environmental Response, Compensation and Liability Act (CERCLA): Reportable Quantities (RQ’s) exist for the following ingredients: None Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center ([PHONE REDACTED]) and to your Local Emergency Planning Committee. Superfund Amendments Reauthorization Act (SARA) Title III: Section 302 Extremely Hazardous Substances (EHS): None Section 311/312 Hazard Categories: Fire Hazard Yes Reactive Hazard No Release of Pressure Yes Acute Health Hazard Yes Chronic Health Hazard No Section 313 Toxic Chemicals: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: None Clean Air Act: Section 112 Hazardous Air Pollutants (HAPs): None Page 759 of 871 Page 759 of 871 Page 759 of 871 Page 759 of 871 ---PAGE BREAK--- Product Name: Smoke Test® Product Number 72105 Page 6 of 7 Canadian Regulations: Controlled Products Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. WHMIS Hazard Class: A, B5, D2B Canadian DSL Inventory: All ingredients are either listed on the DSL Inventory or are exempt. European Union Regulations: RoHS Compliance: This product is compliant with Directive 2002/95/EC of the European Parliament and of the Council of 27 January 2003. This product does not contain any of the restricted substances as listed in Article 4(1) of the RoHS Directive. Additional Regulatory Information: None Section 16: Other Information HMIS® (II) Health: 1 Flammability: 4 Reactivity: 0 PPE: B Ratings range from 0 (no hazard) to 4 (severe hazard) NFPA Prepared By: Michelle Rudnick CRC 418 Revision Date: 11/17/2014 Changes since last revision: removed product number The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this MSDS consult your supervisor, a health & safety professional, or CRC Industries. ACGIH: American Conference of Governmental Industrial Hygienists CAS: Chemical Abstract Service CFR: Code of Federal Regulations DOT: Department of Transportation DSL: Domestic Substance List g/L: grams per Liter HMIS: Hazardous Materials Identification System IARC: International Agency for Research on Cancer IATA: International Air Transport Association ICAO: International Civil Aviation Organization IMDG: International Maritime Dangerous Goods IMO: International Maritime Organization lbs./gal: pounds per gallon LC: Lethal Concentration LD: Lethal Dose NA: Not Applicable ND: Not Determined NIOSH: National Institute of Occupational Safety & Health NFPA: National Fire Protection Association NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration PMCC: Pensky-Martens Closed Cup PPE: Personal Protection Equipment ppm: Parts per Million 4 0 1 Page 760 of 871 Page 760 of 871 Page 760 of 871 Page 760 of 871 ---PAGE BREAK--- Product Name: Smoke Test® Product Number 72105 Page 7 of 7 RoHS: Restriction of Hazardous Substances STEL: Short Term Exposure Limit TCC: Tag Closed Cup TWA: Time Weighted Average WHMIS: Workplace Hazardous Materials Information System Page 761 of 871 Page 761 of 871 Page 761 of 871 Page 761 of 871 ---PAGE BREAK--- 1 MATERIAL SAFETY DATA SHEET Specseal Firestop Sealant SECTION I – PRODUCT INFORMATION Distributor’s name: Allied Rubber and Gasket Company, Inc. – ARGCO 2610 Commerce Way Vista, Ca 92081 In case of emergency: Contact Your local Poison Control Center For information, call: [PHONE REDACTED] Date prepared: 3/29/2010 Product name: Specseal Firestop Sealant SECTION II – HAZARDOUS INGREDIENTS INFORMATION CHEMICAL NAME: C.A.S. No % By Wgt ACGIH TLV OSHA PEL NONE ABOVE DEMINIMIS CONCENTRATIONS SECTION III – PHYSICAL & CHEMICAL DATA Physical State: Paste Appearance Odor: Red Paste with minimal odor Boiling Point: 212 Degree F Specific Gravity: 1.24 Evaporation Tate: >1 Percent Volatile: 22% Solubility in Water: Infinitely dilutable Vapor Pressure: N/A Percent Solids (by weight): 78% Melting Point: N/A SECTION IV – FIRE & EXPLOSION HAZARD DATA Flash Point: Not Applicable –water based compound Flammable Limits: LEL: N/A UEL: N/A Proper Extinguishing Media: Foam, water, or carbon dioxide Recommended Fire: Treat as a class fire. Limit fire fighting to those trained to do so. Minimize breathing gasses, vapor. Fighting Procedures:Fumes, or decomposition products. Use supplied-air breathing equipment for enclosed or confined spaces or as otherwise needed. Unusual Fire & Explosion Hazard: None Known SECTION V – HEALTH & HAZARD DATA Medical Conditions: Preexisting eye, skin and pulmonary disorders may be aggravated by this products Aggravated by Exposure: Primary Route of Entry: Skin – Yes Ingest – Not likely Inhale – No Eye Contact – Yes Page 762 of 871 Page 762 of 871 Page 762 of 871 Page 762 of 871 ---PAGE BREAK--- 2 SIGNS & OF EXPOSURE: Skin Contact: Can cause irritation and redness Inhalation: May be irritating to eyes, skin, mucous membranes, respiratory tract, and my produce of nausea in poorly ventilated areas. Ingestion: N/A Eye Contact: Can cause irritation redness, tearing, blurred vision. EMERGENCY & FIRST AID PROCEDURES: On Skin: Wash with soap and water, get medical attention if irritation persists. Inhalation: N/A Ingestion: N/A In Eyes: Treat as a foreign object in the eye. Flush with large amounts of water frequently flushing under the lids. Get medical attention if irritation persists. ACUTE EFFECTS OF OVEREXPOSURE: Irritation, Redness CHRONIC EFFECTS: (Include all potential carcinogens present at 0.1% or greater) Prolonged or repeated contact with skin can cause moderate irritation. NTP: Yes IARC: Yes OSHA: No Disclaimer The information contained herein is accurate and reliable as of the date issued to the best of the manufacturer’s knowledge. ARGCO doesn’t warrant or guarantee its accuracy or reliability and shall not be liable for any loss or damage arising from the use thereof. It is the user’s responsibility to satisfy itself that the information offered for its consideration is suitable for its particular use. END OF MATERIAL SAFETY DATA SHEET Page 763 of 871 Page 763 of 871 Page 763 of 871 Page 763 of 871 ---PAGE BREAK--- Page 764 of 871 Page 764 of 871 Page 764 of 871 Page 764 of 871 ---PAGE BREAK--- Page 765 of 871 Page 765 of 871 Page 765 of 871 Page 765 of 871 ---PAGE BREAK--- Page 766 of 871 Page 766 of 871 Page 766 of 871 Page 766 of 871 ---PAGE BREAK--- Page 767 of 871 Page 767 of 871 Page 767 of 871 Page 767 of 871 ---PAGE BREAK--- Page 768 of 871 Page 768 of 871 Page 768 of 871 Page 768 of 871 ---PAGE BREAK--- Page 769 of 871 Page 769 of 871 Page 769 of 871 Page 769 of 871 ---PAGE BREAK--- 1 PRODUCT TRADE NAME: HOMAX PRODUCTS, INC. SPRAY-ON ACOUSTIC TEXTURE (DRY MIX) ITEM #8525 SECTION I - MANUFACTURER IDENTIFICATION MANUFACTURER'S NAME: 24 HOUR EMERGENCY PHONE NUMBER: HOMAX PRODUCTS, INC. CHEMTREC 1-[PHONE REDACTED] 468 WEST HORTON ROAD BELLINGHAM,WA 98226 INFORMATION PHONE NUMBER: 1-[PHONE REDACTED] DATE OF PREPARATION: 01/15/03 SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION CAS NUMBER DESCRIPTION PEL TLV % 1317-65-3 CALCIUM CARBONATE 15mg/m3** 10mg/m3** N/A 5mg/m3* 12001-26-2 MICA 3mg/m3** 3mg/m3** N/A 13463-67-7 TITANIUM DIOXIDE 10mg/m3** 10mg/m3** N/A 5mg/m3* 14808-60-7 SILICA QUARTZ*** 10mg/m3* 0.1mg/m3* N/A * RESPIRABLE DUST TOTAL DUST PRESENT AS A NATURAL OCCURING CONTAMINANT, IRAC STATED THERE IS LITTLE EVIDENCE THAT SILICA (QUARTZ) CAUSES CANCER IN HUMANS. NTP HAS OF 1991 LISTS RESPIRABLE SILICA WHICH MAY REASONABLEY BE ANTICIPATED TO BE A CARCINOGEN. SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS APPEARANCE AND ODOR: WHITE POWDER, NO ODOR BOILING POINT: N/A EVAPORATION RATE: N/A VAPOR PRESSURE: N/A WATER SOLUBILITY VAPOR DINSITY (AIR = 1) N/A SPECIFIC GRAVITY (WATER = 1) 1 - 2.3 MELTING POINT: N/A % VOLATILITY BY VOLUME: N/A SECTION IV – FIRE AND EXPLOSION DATA FLASH POINT (METHOD USED): N/A LEL: N/A UEL: N/A FLAMMABLE LIMITS: N/A Page 770 of 871 Page 770 of 871 Page 770 of 871 Page 770 of 871 ---PAGE BREAK--- 2 EXTINGUISHING MEDIA: USE ANY APPROPRIATE MEDIUM FOR EXTINGUISHING SURROUNDING FIRE. SPECIAL FIRE FIGHTING PROCEDURES: FIREFIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS IF DUSTY CONDITIONS ARE PRESENT. UNUSUAL FIRE AND EXPLOSION HAZARDS: NO HAZARD SECTION V – REACTIVITY DATA STABILITY: MATERIAL IS STABLE. HAZARDOUS POLYMERIZATION WILL NOT OCCUR. INCOMPATIBILITY (MATERIALS TO AVOID): ACIDS CONDITIONS TO AVOID: N/A SECTION VI – HEALTH HAZARD DATA ROUTES OF ENTRY: INHALATION – YES SKIN – YES INGESTION – YES HEALTH HAZARDS (ACUTE AND CHRONIC): INHALATION OVER LONG PERIODS OF HIGH AMOUNTS OF ANY NUISANCE DUST MAY OVERLOAD LUNG MECHANISIMS AND MAKE LUNGS MORE VULNERABLE TO RESPIRATORY DISEASE. CARCINOGENICITY: (RESPIRABLE SILICA) NTP – YES IARC MONOGRAPHS – YES OSHA REGULATED – YES SIGNS AND OF EXPOSURE INHALATION: BREATHING DUST MAY IRRITATE THE NOSE, THROAT, AND RESPIRATORY TRACT, CAUSE SNEEZING AND COUGHING EYE CONTACT: DUSTS MAY IRRITATE THE EYES SKIN CONTACT: PROLONGED OR REPEATED CONTACT WITH THE DUST MAY IRRITATE THE SKIN INGESTION: NONE CURRENTLY KNOWN. CONTACT PHYSICIAN MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: PREEXISTING EYE, SKIN OR RESPIRATORY DISORDERS MAY BE AGGRAVATED EMERGENCY AND FIRST AID PROCEDURES IF INHALED: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. GET IMMEDIATE MEDICAL ATTENTION EYE CONTACT: IMMEDIATELY FLUSH EYES WITH LOTS OF RUNNING WATER FOR 15 MINUTES, LIFTING UPPER AND LOWER LIDS OCCASIONALLY. CALL PHYSICIAN SKIN CONTACT: IMMEDIATELY WASH SKIN WITH LOTS OF SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH BEFORE REUSE. GET MEDICAL ATTENTION IF IRRITATION PERSISTS AFTER WASHING. INGESTION: DO NOT INDUCE VOMITING. CALL PHYSICIAN Page 771 of 871 Page 771 of 871 Page 771 of 871 Page 771 of 871 ---PAGE BREAK--- 3 NOTES TO HPYSICIAN: NONE WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. SECTION VII – PRECAUTIONS FOR SAFE HANDLING AND USE STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SCOOP MATERIAL INTO WASTE CONTAINER FOR DISPOSAL. COMPLY WITH ALL APPLICABLE GOVERNMENTAL REGULATIONS ON SPILL REPORTING AND HANDLING AND DISPOSAL OF WASTE. WASTE DISPOSAL METHOD: DISPOSE OF CONTAMINATED PRODUCT AND MATERIALS USED IN CLEANING UP SPILLS AND LEAKS IN A MANNER APPROVED FOR THIS MATERIAL. CONSULT APPROPRIATE FEDERAL, STATE AND LOCAL REGULATORY AGENCIES TO ASCERTAIN PROPER PROCEDURES. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: STORE IN COOL, DRY PLACE. KEEP BAGS AND CONTAINERS DRY AT ALL TIMES. WASH THOROUGHLY AFTER HANDLING. DO NOT GET IN EYES, ON SKIN OR CLOTHING. OTHER PRECAUTIONS: CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, WILL RETAIN PRODUCT RESIDUE. ALWAYS OBEY HAZARD WARNIGS AND HANDLE EMPTY CONTAINER AS IF THEY WERE FULL. SECTION VIII – CONTROL MEASURES RESPIRATORY PROTECTION: NIOSH-APPROVED DUST RESPIRATOR OR MASK IN THE ABSENCE OF ADEQUATE ENVIRONMENTAL CONTROLS AT POINT OF USE. THERE IS LITTLE EVIDENCE THAT SILICA CAUSES CANCER IN HUMANS. VENTILATION: USE LOCAL EXHAUST CAPABLE OF MINIMIZING DUST EMISSIONS AT POINT OF USE. PROTECTIVE GLOVES: NOT NORMALLY REQUIRED, USE IF DESIRED. EYE PROTECTION: NIOSH-APPROVED DUST GOGGLES. OTHER PROTECTIVE CLOTHING OR EQUIPMENT: LONG-SLEEVED SHIRT, TROUSERS, SAFETY SHOES AND GLOVES. WORK/HYGIENIC PRACTICES: WASH THOROUGHLY AFTER HANKLING AND BEFORE EATING, DRINKING OR SMOKING. AN EYEWASH AND SAFETY SHOWER SHOULD BE NEARBY AND READY FOR USE. SECTION XI - DISCLAIMER TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HERE IN IS ACCURATE, OBTAINED FROM SOURCES BELIEVED BY HOMAX CORPORATION TO BE ACCURATE. SINCE THE CONDITIONS AND METHODS OF USE OF OUR PRODUCTS ARE BEYOND OUR CONTROL, WE DESCLAIM ANY AND ALL LIABILITY ARISING OUT OF THE IMPROPER USE OF THESE PRODUCTS OR THE INFORMATION PROVIDED HEREWITH. Page 772 of 871 Page 772 of 871 Page 772 of 871 Page 772 of 871 ---PAGE BREAK--- Page 1 of 4 Print Date 10/31/2003 MSDS Document Product Stainless Steel Spray Coating 1. Chemical Product and Company Identification Trade Name of this Product Stainless Steel Spray Coating MSDS ID 95545 Manufacturer Lawson Products, Inc. 1666 East Touhy Avenue Des Plaines, IL 60018 Contact Name Corporate Compliance Team Phone Number (847) 827-9666 Emergency Phone (888) 426-4851 Revision Date 04/08/2002 2 4 1 Health: Fire: Reactivity: Specific Health: Fire: Reactivity: Specific 2 4 1 2. Composition and Information on Ingredients Ingredient CAS Number Weight % ACGIH TLV PEL STEL Toluene 108-88-3 15-20 % Medium aliphatic solvent naphtha 64742-88-7 N/A % Acetone 67-64-1 N/A % Propellant: Propane 74-98-6 N/A % Propellant: n-Butane 106-97-8 N/A % Nickel 7440-02-0 N/A % 3. Hazard Identification Synergistic Products N/A Page 773 of 871 Page 773 of 871 Page 773 of 871 Page 773 of 871 ---PAGE BREAK--- Page 2 of 4 Print Date 10/31/2003 MSDS ID 95545 Stainless Steel Spray Coating Irritancy Of Product Moderate eye irritant. Target Organs Affected Vapors: Irritating to eyes and respiratory tract. Direct Contact: Irritating to skin and eyes. MEDICAL CONDITIONS PRONE TO AGGRAVATION BY EXPOSURE Pre-existing skin, respiratory, liver, and kidney disorders. EFFECTS OF OVEREXPOSURE Possible eye or skin irritation with repeated or prolonged contact. Ingestion: irritation, nausea or diarrhea. Route Of Entry Ingestion Inhalation Eyes Skin 4. First Aid Information EMERGENCY AND FIRST AID PROCEDURES Eyes: Flush with water. Consult a physician. Skin: Wash area with soap and water. Consult physician if irritation persists. Inhalation: Move to fresh air and consult a physician. 5. Fire Fighting Measures Extinguishing Media Foam Carbon Dioxide Dry Chemical Water Fog 6. Accidental Release Measures Material Release Or Spill Remove all sources of ignition, ventilate. Avoid breathing vapors and remove with inert absorbent. 7. Handling and Storage Handling Precautions N/A Storage Store in a cool, dry place away from heat and open flame. Keep out of reach of children Other Precautions All ingredients marked with an symbol are toxic chemicals subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40CFRPart372. Handling Store in cool, dry, ventilated areas. Keep container closed when not in use. Keep all food and beverages away. Eating, drinking, and smoking should be prohibited where there is Page 774 of 871 Page 774 of 871 Page 774 of 871 Page 774 of 871 ---PAGE BREAK--- Page 3 of 4 Print Date 10/31/2003 MSDS ID 95545 Stainless Steel Spray Coating potential exposure to toxic material. Hygienic Practices Wash hands before eating or using the washroom. Smoke in SMOKING AREAS ONLY. 8. Exposure Controls and Personal Protection Ventilation If current ventilation practices are not adequate in maintaining airborne concentrations below the established exposure limits, additional ventilation or exhaust systems may be required. Respiratory Protection If airborne concentrations exceed recommended exposure limits, a suitable NIOSH respirator should be worn. Other Protective Equipment Eye wash station and safety showers should be available. Eye Protection Use safety eyewear designed to protect against splash of liquids. Clothing Impermeable clothing should be used to prevent excessive skin contact. Other PPE N/A PROTECTIVE GLOVES Wear resistant gloves such as rubber, neoprene or plastic. 9. Physical and Chemical Properties Physical State Liquid Specific Gravity 0.88 pH N/A Boiling/Cond. Point 133.0 VOC % 53.32 ODOR AND APPEARANCE Solvent odor, aluminum color. 10. Stability and Reactivity Incompatibility Avoid contact with strong oxidizing agents. Extended exposure to high temperatures may cause decomposition. Conditions To Avoid Sunlight, open flame & contamination. Page 775 of 871 Page 775 of 871 Page 775 of 871 Page 775 of 871 ---PAGE BREAK--- Page 4 of 4 Print Date 10/31/2003 MSDS ID 95545 Stainless Steel Spray Coating Hazardous Decomposition Products By open flame: CARBON MONOXIDE, CARBON DIOXIDE. Hazardous Polymerization Will not occur. 11. Toxicological Information Carcinogenicity This product contains material considered to be a carcinogen by the National Toxicology Program, or the International Agency for Research on cancer, or the Occupational Safety and Health Administration, Suspected in Animals. 12. Ecological Information Ecological Information No information available. 13. Disposal Considerations Waste Disposal Method Dispose of product in accordance with local, county, state, and federal regulations. Do not puncture or incinerate container. Do not reuse container. Wrap container and place in trash collection. 14. Transportation Information OSHA CLASS 1A PER DOT ORMD DOT Class UN1950 PER IMCO N/A IMCO Classification Number N/A IATA Classification Number N/A 15. Regulatory Information CPR Certification This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. Other Information Other Precautions No information available. Page 776 of 871 Page 776 of 871 Page 776 of 871 Page 776 of 871 ---PAGE BREAK--- SDS# 2001, 2003 Staticide General Purpose Page 1 of 7 Rev. March 13, 2015 Page 1 of 7 Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Section 1. CHEMICAL PRODUCT SECTION Identification: Product Name: STATICIDE® General Purpose Product Number: #2001, #2003, #530, #2001-5 & #2001-2 Recommend use: Anti-static topical for hard surfaces Synonym: Water with surfactants Manufacturer: ACL Incorporated 840 W. 49th Place Chicago, IL 60609 PH: (01) [PHONE REDACTED] FAX: (01) [PHONE REDACTED] Emergency telephone: INFOTRAC: (01) [PHONE REDACTED] (day or night) Section 2. HAZARDOUS IDENTIFICATION 2.1 Classification of the substance or mixture Product definition: Mixture GHS-US classification Physical: Not Classified Health: Eye irritation / category 2B Environmental: Not Classified 2.2 Label Elements Hazard Pictograms: None Signal Word: Warning Hazard Statement: Causes eye irritation (H320) Precautionary Statements: General: If medical advice is needed, have container or label at hand (P101) Keep out of reach of children (P102) Read label before use (P103) Prevention: Wash hands thoroughly after handling (P264) Response: IF IN EYES, Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing (P305 +P351 + P338) If eye irritation persists, get medical attention or advice (P337 + P313) IF ON SKIN, wash with plenty of water. (P302 + P352) Unknown Acute Toxicity: No data available Page 777 of 871 Page 777 of 871 Page 777 of 871 Page 777 of 871 ---PAGE BREAK--- SDS# 2001, 2003 Staticide General Purpose Page 2 of 7 Rev. March 13, 2015 Page 2 of 7 Section 3. COMPOSITION / INFORMATION ON INGREDIENTS CHEMICAL CAS CLASSIFICATION WEIGHT Deionized Water 7732-18-5 Not classified 95 – 99.5 Quaternary ammonium compounds, coco (hydroxyethyl)methyl, nitrates 71487-00-8 Acute Tox. 4; H302 Skin Corr. 1B; H314 Eye Dam. 1; H318 Aquatic Acute 1; H400 Aquatic Chronic 1; H410 M-Factor (Acute): 1 < 0.5 Isopropanol 67-63-0 Flam. Liq. 2; H225 Eye Irrit. 2A; H319 STOT SE 3; H336 < 0.5 Section 4. FIRST AID MEASURES PRIMARY ROUTE(S) OF EXPOSURE / ENTRY: Inhalation, Skin Contact. General Advice: If exposed or concerned: Get medical advice/attention. Inhalation: Move to fresh air and contact a physician if persist. Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin Contact: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/ attention. Ingestion: Clean mouth with water and drink afterwards plenty of water. . Section 5. FIRE FIGHTING MEASURES Suitable Extinguishing Media: Alcohol resistant foam, carbon dioxide (CO2). Dry chemical. Unsuitable Extinguishing Media: Not determined. Specific Hazards Arising from the Chemical: Not determined. Hazardous Combustion Products: Not determined. Protective equipment and precautions for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Section 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions: Use personal protective equipment as required Methods and material for containment and cleaning up Methods for Containment: Prevent further leakage or spillage if safe to do so Methods for Clean-Up: Halt spill at source and contain or dike spill with inert absorbent material. Transfer liquid to containers for recovery or disposal. Shovel absorbent into drums for disposal in accordance with local, state and federal regulations Page 778 of 871 Page 778 of 871 Page 778 of 871 Page 778 of 871 ---PAGE BREAK--- SDS# 2001, 2003 Staticide General Purpose Page 3 of 7 Rev. March 13, 2015 Page 3 of 7 Section 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Wash face, hands, and any exposed skin thoroughly after handling. Wear eye/face protection. Conditions for safe storage, including any incompatibilities Storage Conditions: Ambient (40° - 90° F) Incompatible Materials: None known based on information supplied. Section 8. EXPOSURE CONTROL / PERSONAL PROTECTION Exposure Guidelines OSHA PEL ACGIH TLV Chemical Name ppm Mg/m3 ppm Mg/m3 2- Propanol TWA 400 ppm 980 Mg/m3 400 ppm 983 Mg/m3 STEL 500 ppm 1225 Mg/m3 500 ppm 1230 Mg/m3 Appropriate engineering controls Engineering Controls: Eyewash stations. Ventilation systems. Individual protection measures, such as personal protective equipment Respirator: None required in well ventilated areas. Skin and Body Protection: Wear rubber gloves. Wear protective work clothing Eye Protection: Wear approved safety goggles. Section 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Clear pale yellow liquid Odor Pleasant pH 7.5 Melting point/freezing point NE / Less than 0C Initial boiling point and boiling range 100C (212F) Flash point and method None Evaporation rate (H2O 1 estimate Flammability (solid, gas, liquid) NA Upper/lower flammability or explosive limits NA Vapor pressure NE Vapor density (air=1) Less than air Relative density .99 Solubility(ies). Miscible Partition coefficient: n-octanol/water NE Autoignition temperature NA Decomposition temperature NE Viscosity NE Volatile by weight >90% VOC (g/l) < 3.6 Page 779 of 871 Page 779 of 871 Page 779 of 871 Page 779 of 871 ---PAGE BREAK--- SDS# 2001, 2003 Staticide General Purpose Page 4 of 7 Rev. March 13, 2015 Page 4 of 7 Section 10. STABILITY AND REACTIVITY Reactivity: Stable under recommended storage conditions Chemical Reactivity: Stable under recommended storage conditions Possibility of Hazardous Reactions: None under normal procession Hazardous Polymerization: Under normal conditions of storage and use, will not occur Conditions to Avoid: Keep away from heat, flames, and sparks. Incompatible Materials: None known based on information supplied Hazardous Decomposition: Not determined Section 11. TOXICOLOGY INFORMATION Acute toxicity Product/ingredient name Result Species Dose Exposure Quaternary ammonium compounds, coco (hydroxyethyl)methyl, nitrates (salts) LD50 Oral Rat 400 mg/kg - propan-2-ol LC50 Inhalation Vapor LD50 Dermal LD50 Oral Rat – Male Rabbit Rat 66100 mg/m³ 12800 mg/kg 5000 mg/kg 4 hours - - Conclusion/Summary: Not available Irritation/Corrosion Product/ingredient name Result Species Exposure propan-2-ol Eyes - Moderate irritant Eyes - Moderate irritant Eyes - Severe irritant Skin - Mild irritant Rabbit Rabbit Rabbit Rabbit 24 hours 100 milligrams 10 milligrams 100 milligrams 500 milligrams Conclusion/Summary: Not available Sensitization Conclusion/Summary: Not available. Mutagenicity Conclusion/Summary: Not available. Carcinogenicity Conclusion/Summary: Not available. Reproductive toxicity Conclusion/Summary: Not available. Teratogenicity Conclusion/Summary: Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure): Not available. Aspiration hazard: Not available. Information on the likely routes of exposure: Not available. Potential acute health effects Eye Contact: Causes eye irritation Skin Contact: May cause skin irritation or dryness Inhalation: Do not inhale Ingestion: Do not ingest related to the physical, chemical and toxicological characteristics Eye contact: Adverse may include the following: Pain, watering, redness Inhalation: Adverse may include the following: nausea or vomiting, headache, drowsiness/fatigue, dizziness/vertigo, unconsciousness Product/ingredient name Category Route of exposure Target organs propan-2-ol Category 3 Not applicable. Narcotic effects Page 780 of 871 Page 780 of 871 Page 780 of 871 Page 780 of 871 ---PAGE BREAK--- SDS# 2001, 2003 Staticide General Purpose Page 5 of 7 Rev. March 13, 2015 Page 5 of 7 Skin contact: Adverse may include the following: pain or irritation, redness, blistering may occur Ingestion: Adverse may include the following: stomach pains Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate effects: Not available. Potential delayed effects: Not available. Long term exposure Potential immediate effects: Not available. Potential delayed effects: Not available. Potential chronic health effects: Not available. Conclusion/Summary: Not available. General: No known significant effects or critical hazards. Carcinogenicity: No known significant effects or critical hazards. Mutagenicity: No known significant effects or critical hazards. Teratogenicity: No known significant effects or critical hazards. Developmental effects: No known significant effects or critical hazards. Fertility effects: No known significant effects or critical hazards. Other information: No known significant effects or critical hazards. Section 12. ECOLOGICAL INFORMATION 12.1 Toxicity Product/ingredient name Result Species Exposure propan-2-ol Acute LC50 1400000 to 1950000 μg/l Marine water Acute LC50 4200000 μg/l Fresh water Crustaceans - Crangon crangon Fish - Rasbora heteromorpha 48 hours 96 hours Quaternary ammonium compounds, benzyl- chlorides Acute LC50 0.31 mg/l Fish 96 hours Conclusion/Summary : Not available. 12.2 Persistence and degradability Product/ingredient name Test Result Dose Inoculum Quaternary ammonium compounds, coco (hydroxyethyl)methyl, nitrates (salts) - 20 % - 42 days - - propan-2-ol 301E Ready Biodegradability - Modified OECD Screening Test 95 % - 21 days - - Conclusion/Summary : Not available. Product/ingredient name Aquatic half-life Photolysis Biodegradability propan-2-ol - - Readily 12.3 Bioaccumulative potential Product/ingredient name LogPow BCF Potential propan-2-ol 0.05 - low 12.4 Mobility in soil Soil/water partition coefficient (KOC): Not available. Page 781 of 871 Page 781 of 871 Page 781 of 871 Page 781 of 871 ---PAGE BREAK--- SDS# 2001, 2003 Staticide General Purpose Page 6 of 7 Rev. March 13, 2015 Page 6 of 7 Mobility: Not available. 12.5 Results of PBT and vPvB assessment PBT: Not available. vPvB: Not available. 12.6 Other adverse effects: No known significant effects or critical hazards. Section 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes: Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging: Disposal should be in accordance with applicable regional, national and local laws and regulations Section 14. TRANSPORTATION INFORMATION U.S. DOT Information: Basic Description: NON HAZARDOUS MATERIAL IATA: Proper Shipping Name: NON HAZARDOUS MATERIAL Section 15. REGULATORY INFORMATION United States Federal Regulations: MSDS complies with the OSHA Hazard Communication Rule, 29 CFR 1910.1200. CERCLA/Superfund, 40 CFR 117, 302: None of the chemicals are Section 302 hazards SARA Superfund and Reauthorization Act of 1986 Title III sections 302, 311,312 and 313: Section 302 – Extremely hazardous substances (40 CFR 355): ---None of the chemicals are Section 302 hazards Section 311/312 – Material Safety Data Sheet Requirements (40 CFR 370): By our hazard evaluation, this product is non-hazardous. Section 313 – List of Toxic Chemicals (40CFC 372): ---None of the chemicals are 313 Toxic Chemicals Toxic Substance Control Act (TSCA): All substances are TSCA listed. Resource Conservation and Recovery Act (RCRA 40 CFR 261) Subpart C & D: Refer to Section 13 for RCRA classification. Federal Water Pollution Control Act, Clean Water Act, 40 CFR 401.15 (formerly section 307) 40 CFR 116 (formerly section 311) ---None of the chemicals are listed Clean Air Act: No Information STATE REGULATIONS: California Proposition 65: None of the chemicals are on the Proposition 65 list--- INTERNATIONAL REGULATIONS: Canada WHMIS: 904 (1050 FR) Isopropanol is listed on Ingredient Disclosure List (SOR/88-64) To the best of our ability, this MSDS is written in accordance to REACH Directive EC1907/2006 Annex II and GHS requirements. This product is not subject to REACH restrictions. It does not contain any candidates on the SvHC. Page 782 of 871 Page 782 of 871 Page 782 of 871 Page 782 of 871 ---PAGE BREAK--- SDS# 2001, 2003 Staticide General Purpose Page 7 of 7 Rev. March 13, 2015 Page 7 of 7 Sections 16. OTHER INFORMATION NFPA Health: Can cause significant irritation NFPA Fire: Will not burn NFPA Instability: Stable NFPA Reactivity: None HMIS Health: Slight Hazard. Irritation or minor reversible injury possible. HMIS Flammability: Minimal Hazard. Will not burn unless heated. HMIS Reactivity: Minimal Hazard. Stable HMIS Personal Protection: B. Safety glasses and protective gloves should be worn when handling this material. LABEL INFORMATION: For Shipping Label information refer to section 14 Product label warnings are as follows (Comparable CHIP Safety & Risk phrases are noted):  Keep out of the reach of children (S2) REVISION DATES, SECTIONS, REVISED BY: 15-FEB-92, Original release date 02-APR-01, Reviewed 18-Feb-04, New Format, mkb 31-Jan-07 Section 11 & 12, mkb 28-Aug-09 New address, Reach format, mkb 22-Aug-11 Section 9, VOC, mkb 08-May-12 GHS, mkb 29-Apr-14 SDS, mkb 31-Jul-14 Section 3, mkb 25-Nov-14 Section 2, mkb 10-Dec-14 Section 2, mkb 13-Mar-15 Reviewed, mkb ABBREVIATIONS USED: NE – Not Established, NA – Not Applicable, NIF – No Information Found ABRIDGED LIST OF REFERENCES: Code of Federal Regulations (CFR) The Sigma-Aldrich Library of Regulatory and Safety Data Chemical Guide and OSHA Hazardous Communication Standard The Environmental Protection Agency (www.epa.gov) American National Standards Institute To the best of our knowledge, the information contained herein is accurate. However, neither ACL STATICIDE nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Page 783 of 871 Page 783 of 871 Page 783 of 871 Page 783 of 871 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 1 PROFESSIONAL DISPOSABLES INC. THE HEALTHCARE DIVISION OF NP/PDI ISO 9001 CERTIFIED NICE-PAK PRODUCTS, INC. TWO NICE PAK PARK ORANGEBURG, NY 10962-1376 [PHONE REDACTED] REVISION DATE: 6/04 I. PRODUCT IDENTIFICATION PRODUCT/TRADE NAME SUPER SANI CLOTH GERMICIDAL DISPOSABLE WIPE - Q55172, Q43472, H04082, U87295, Q86984 HAZARD RATING(NFPA) HEALTH: 1 FLAMMABILITY: 3 REACTIVITY: 0 SPECIFIC: NONE EMERGENCY OR INFORMATION TELEPHONE NO: [PHONE REDACTED] (M-F DAYTIME) AT OTHER TIMES, CONTACT THE LOCAL POISON CONTROL CENTER CHEMICAL NAME: PROPRIETARY MIXTURE II. HAZARDOUS INGREDIENTS PER 29 CFR 1910.1200 Hazardous Ingredients % ACGIH TLV CAS NUMBER ISOPROPYL ALCOHOL 55 400 ppm 67-63-0 QUATERNARY AMMONIUM CMPD <1 N/A 68391-01-5/68956-79-6 III. PHYSICAL/CHEMICAL CHARACTERISTICS COLOR/ODOR/APPEARANCE: APPLICATOR SATURATED WITH CLEAR LIQUID WITH ALCOHOL ODOR BOILING POINT: 181° F FLASH POINT: 74° F VAPOR DENSITY N/A EVAPORATION RATE: N/A SOLUBILITY IN WATER: COMPLETE SPECIFIC GRAVITY (H2O = 0.892 IV. FIRE & EXPLOSION HAZARD DATA FLASH POINT(Method Used): 74° F TAG CLOSED CUP : LEL: N/A UEL:N/A EXTINGUISHING MEDIA: WATER, FOAM SPECIAL FIRE FIGHTING PROCEDURES: TREAT PRODUCT AS FLAMMABLE UNUSUAL FIRE AND EXPLOSION HAZARDS: NONE V. REACTIVITY DATA STABILITY: STABLE CONDITIONS TO AVOID : NONE INCOMPATIBILITY: ANIONIC SURFACTANT, SOAPS HAZARDOUS DECOMPOSITION OR BYPRODUCTS: NONE KNOWN POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: NONE KNOWN PRODUCT DOES NOT REACT WITH FORMALDEHYDE Page 784 of 871 Page 784 of 871 Page 784 of 871 Page 784 of 871 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 2 SUPER SANI CLOTH VI. HEALTH HAZARD DATA EFFECTS OF OVER EXPOSURE: SKIN : MAY CAUSE SKIN IRRITATION EYES : MAY CAUSE IRRITATION INHALATION: NOT NORMAL ROUTE OF ENTRY INGESTION: NOT NORMAL ROUTE OF ENTRY EMERGENCY AND FIRST AID PROCEDURES: SKIN CONTACT: IF RASH OR IRRITATION DEVELOPS, DISCONTINUE USE EYE CONTACT: FLUSH WITH COOL WATER FOR 15 MINUTES INHALATION: REMOVE TO FRESH AIR INGESTION: CONSULT PHYSICIAN TARGET ORGANS; NONE KNOWN KNOWN CARCINOGEN: NONE KNOWN VII. SPILL AND DISPOSAL PROCEDURE SPILL CONTROL: PICK UP WITH ABSORBENT WASTE DISPOSAL METHOD: TREAT AS FLAMMABLE LIQUID. OBEY LOCAL, STATE AND FEDERAL REGULATIONS HANDLING AND STORAGE: AVOID HIGH HEAT AND SOURCES OF IGNITION VIII. CONTROL MEASURES/PROTECTION RESPIRATION: USE NIOSH APPROVED RESPIRATOR WHEN HANDLING BULK LIQUID IF EXPOSURE LEVEL IS EXCEEDED VENTILATION: RECOMMENDED PROTECTIVE GLOVES: RECOMMENDED EYE PROTECTION: IF SPLASHING MAY OCCUR HYGIENIC PRACTICES: FOLLOW GOOD HOUSEKEEPING PRACTICES OTHER: NONE IX. TRANSPORT/SHIPPING DOT SHIPPING NAME: CONSUMER COMMODITY TECHNICAL SHIPPING NAME: N/A DOT SHIPPING CLASSIFICATION: ORM-D DOT ID NO.: N/A DOT LABEL REQUIREMENTS: UN/NA NUMBER REGULATIONS: N/A REPORTABLE QUANTITY: N/A X. DISCLAIMER THE INFORMATION FURNISHED HEREIN IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST DATA CURRENTLY AVAILABLE TO US. NO WARRANTY, EXPRESSED OR IMPLIED IS MADE AND NICE-PAK PRODUCTS, INC. ASSUMES NO LEGAL RESPONSIBILITY OR LIABILITY RESULTING FROM ITS USE. ALL COMPONENTS OF THIS PRODUCT ARE LISTED UNDER T.S.C.A. INVENTORY. Page 785 of 871 Page 785 of 871 Page 785 of 871 Page 785 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 17-Sep-2014 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 97673 Product name Tefgel Recommended Use Lubricant Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Eyes. Skin contact. Skin absorption. Inhalation. Ingestion. Potential health effects Eyes May cause the following effects:. Irritation. Skin Skin Irritation. Repeated or prolonged exposure may cause skin irritation and dermatitis, due to degreasing properties of the product. Defatting. Repeated exposure may cause skin dryness or cracking. Inhalation Irritating to respiratory system. Avoid breathing vapors or mists. of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. Ingestion Not likely to occur. May be harmful if swallowed. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Hexane 110-54-3 40-70 Olefin Polymer Proprietary 10-30 Propane 74-98-6 10-30 Paraffinic Mineral Oil 8042-47-5 3-7 4. FIRST AID MEASURES General advice Show this safety data sheet to the doctor in attendance. Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Seek medical attention. Skin contact Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. If skin irritation persists, call a physician. Ingestion Do not induce vomiting. Contact physician or poison control center immediately. Inhalation Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Seek medical attention immediately. 5. FIRE FIGHTING MEASURES Flash point °C -104°C Flash point °F -156°F Method Pensky-Martens C.C. Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 9.5 Lower 1.2 Suitable extinguishing media Carbon dioxide (CO2). Dry chemical powder. Foam. Water fog. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Special Fire-Fighting Procedures Water spray may be ineffective. If water is used, fog nozzles are preferable . Fire and Explosion Hazards Containers can build up pressure if exposed to heat (fire). Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat . Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Hazardous decomposition products See Section 10. Sensitivity to shock No information available. Page 1 / 4 Emergency Overview Extremely flammable. Vapors may cause flash fire or explosion. Contents under pressure. May cause eye/skin irritation. May cause irritation of respiratory tract. Page 786 of 871 Page 786 of 871 Page 786 of 871 Page 786 of 871 ---PAGE BREAK--- Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Avoid breathing of vapors. Ensure adequate ventilation. Use personal protective equipment. Remove all sources of ignition. Environmental precautions Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Methods for cleaning up Soak up with noncombustible inert absorbent material. Place in non- leaking, sealed container for proper disposal. 7. HANDLING AND STORAGE Handling Avoid contact with skin, eyes and clothing. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate. Do not stick pin, nail, or any other sharp object into opening on top of can. Thoroughly wash hands and exposed skin after handling. Wash hands with soap and water before eating, drinking, smoking, or using toilet facilities. Use only according to label directions. Handle empty containers as if they were full. Storage Keep out of the reach of children. Keep away from heat. Keep away from open flames, hot surfaces and sources of ignition. Store in temperatures below 120 degrees F (50 degrees C) . NFPA Storage Code Store as Level 3 Aerosol (NFPA 30B) 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Hexane 500 ppm 1800 mg/m3 - 50 ppm N/D Paraffinic Mineral Oil - - - - Propane 1000 ppm 1800 mg/m3 - 1000 ppm - Olefin Polymer - - - - Ventilation and Environmental Controls Adequate ventilation should be provided to keep exposure levels below current acceptable exposure limits. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes and clothing. Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Seek professional advise prior to respirator selection and use. Hand Protection Chemical resistant gloves. Eye protection Safety glasses with side-shields. Skin and body protection Wear appropriate clothing to prevent skin contact. Impervious clothing. Rubber or plastic boots. Apron. Coveralls. Other Protective Equipment A safety shower and eye wash station should be available for emergency use. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Amber Odor Solvent Odor Threshold No information available pH No data available Specific Gravity 0.67 Vapor pressure 80-90 Vapor density heavier than air Evaporation Rate >1 (Butyl Acetate = 1) Water solubility Negligible VOC Content 79% Partition Coefficient (n-octanol/water) No data available Boiling point/range °C No data available Boiling point/range °F -44°F - 611°F Melting point/range °C No data available Melting point/range °F No data available Flash point °C -104°C Flash point °F -156°F 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions. Conditions to avoid Avoid sources of ignition. Incompatability Strong oxidizing agents. Strong bases. Hazardous Decomposition Products Carbon oxides. Fumes. Page 2 / 4 Product name Tefgel Product code 97673 Page 787 of 871 Page 787 of 871 Page 787 of 871 Page 787 of 871 ---PAGE BREAK--- Polymerization Hazardous polymerization does not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Hexane 110-54-3 - 3000 mg/kg 48000 ppm Paraffinic Mineral Oil 8042-47-5 5000 mg/kg - - Propane 74-98-6 - - 658 mg/L Olefin Polymer Proprietary - - - Synergistic Products None known Specific Hazards Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Potential health effects Sensitization None known Chronic toxicity See Section 2 . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects Central nervous system. Eyes. Peripheral nervous system. Respiratory system. Skin. Carcinogenic effects None known . Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Hexane Not Listed Not Listed Not Listed Not Listed Not Listed Paraffinic Mineral Oil Not Listed Not Listed Not Listed Not Listed Not Listed Propane Not Listed Not Listed Not Listed Not Listed Not Listed Olefin Polymer Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Disposal Information Full or partially full containers are considered hazardous waste. Emptied container retains product residue. Do not reuse container. Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT May be classed as Consumer Commodity, ORM-D, UN1950, AEROSOLS, 2.1 LIMITED QUANTITY TDG May be classed as Consumer Commodity, ORM-D, UN1950, AEROSOLS, 2.1 LIMITED QUANTITY 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Hexane Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Hexane Listed Listed Not Listed Paraffinic Mineral Oil Not Listed Not Listed Not Listed Propane Listed Listed Not Listed Olefin Polymer Not Listed Not Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA Hexane X X - X Paraffinic Mineral Oil X X - X Propane X X - X Olefin Polymer - - - - CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. OTHER INFORMATION HMIS Health - 1 Flammability - 4 Physical Hazard - 0 Page 3 / 4 Product code 97673 Product name Tefgel Page 788 of 871 Page 788 of 871 Page 788 of 871 Page 788 of 871 ---PAGE BREAK--- 16. OTHER INFORMATION Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product name Tefgel Product code 97673 Page 789 of 871 Page 789 of 871 Page 789 of 871 Page 789 of 871 ---PAGE BREAK--- SAFETY DATA SHEET. Issuing date 11-Feb-2014 Revision Date 11-Feb-2014 Version 1 Page 1 / 8 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product name TefGel Penetrating Gel Gear Lubricant with P.T.F.E. Recommended use of the chemical and restrictions on use Product code 97673 Product Type Extremely flammable aerosol Synonyms Supplier's details Recommended Use Gel Lubricant. Uses advised against Manufactured For: Lawson Products, Inc 8770 W. Bryn Mawr Avenue - Suite 900 Chicago, IL 60631-3515 Emergency telephone number Company Emergency Phone Number [PHONE REDACTED] Page 790 of 871 Page 790 of 871 Page 790 of 871 Page 790 of 871 ---PAGE BREAK--- 97673 TefGel Penetrating Gel Gear Lubricant with P.T.F.E. Revision Date 11-Feb-2014 Page 2 / 8 2. HAZARDS IDENTIFICATION Classification Germ Cell Mutagenicity Category 1B Carcinogenicity Category 1A Aspiration toxicity Category 1 Flammable aerosols Category 1 GHS Label elements, including precautionary statements Emergency Overview DANGER Hazard Statements May cause genetic defects May cause cancer May be fatal if swallowed and enters airways Extremely flammable aerosol Appearance Hazy Physical state Aerosol Odor Solvent Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Other information • May be harmful in contact with skin 16.86256% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS CAS # 64742-49-0, COMMERCIAL HEXANES, MAY BE SUBSTITUTED FOR CAS #110-54-3. Synonyms . Page 791 of 871 Page 791 of 871 Page 791 of 871 Page 791 of 871 ---PAGE BREAK--- 97673 TefGel Penetrating Gel Gear Lubricant with P.T.F.E. Revision Date 11-Feb-2014 Page 3 / 8 Chemical Name CAS-No Weight % HEXANE 64742-49-0 60 - 70% PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 10 - 20% *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES First aid measures for different exposure routes Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If skin irritation persists, call a physician. Inhalation Move to fresh air. If persist, call a physician. Ingestion Do NOT induce vomiting. If persist, call a physician. Most important acute and delayed Main Not applicable. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Decomposition by contact with water may generate vapors which can be ignited by heat or open flame. Specific hazards arising from the chemical No information available. Explosion Data Sensitivity to Mechanical Impact none. Sensitivity to Static Discharge Yes. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation. Environmental precautions Page 792 of 871 Page 792 of 871 Page 792 of 871 Page 792 of 871 ---PAGE BREAK--- 97673 TefGel Penetrating Gel Gear Lubricant with P.T.F.E. Revision Date 11-Feb-2014 Page 4 / 8 Environmental precautions No special environmental precautions required. Methods and materials for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top of can. Conditions for safe storage, including any incompatibilities Technical measures/Storage conditions Keep containers closed in a dry, cool and well-ventilated place. Incompatible products None known based on information supplied. Aerosol Level 3 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . ACGIH: (American Conference of Governmental Industrial Hygienists) OSHA: (Occupational Safety & Health Administration) NIOSH IDLH: Immediately Dangerous to Life or Health Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Exposure controls Engineering Measures Showers Eyewash stations Ventilation systems. Individual protection measures, such as personal protective equipment Eye/Face Protection Safety glasses with side-shields. Skin and body protection Chemical resistant apron. Protective gloves. Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 793 of 871 Page 793 of 871 Page 793 of 871 Page 793 of 871 ---PAGE BREAK--- 97673 TefGel Penetrating Gel Gear Lubricant with P.T.F.E. Revision Date 11-Feb-2014 Page 5 / 8 Physical and chemical properties Physical state Aerosol Appearance Hazy Odor Solvent Color amber Odor Threshold No information available Property Values Remarks • Methods pH No information available not applicable Melting/freezing point No information available Boiling point/boiling range No information available Flash Point -96.4 °C / -141 °F Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limits in Air upper flammability limit No information available lower flammability limit No information available Vapor pressure No information available Vapor density No information available Specific Gravity 0.720 Water solubility Practically insoluble Partition coefficient: n-octanol/water No information available Autoignition temperature No information available Not applicable Decomposition temperature No information available Viscosity No information available Explosive properties No information available Other information VOC Content(%) 78.76 10. STABILITY AND REACTIVITY Reactivity No data available Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to Avoid Extremes of temperature and direct sunlight. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Product does not present an acute toxicity hazard based on known information Inhalation There is no data available for this product. Eye contact There is no data available for this product. Page 794 of 871 Page 794 of 871 Page 794 of 871 Page 794 of 871 ---PAGE BREAK--- 97673 TefGel Penetrating Gel Gear Lubricant with P.T.F.E. Revision Date 11-Feb-2014 Page 6 / 8 Skin contact There is no data available for this product. Ingestion There is no data available for this product. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation HEXANE 64742-49-0 > 5000 mg/kg ( Rat ) > 3160 mg/kg ( Rabbit ) 73680 ppm ( Rat ) 4 h Information on toxicological effects No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ Cell Mutagenicity No information available. Carcinogenicity There are no known carcinogenic chemicals in this product. This product contains one or more substances which are classified by IARC as carcinogenic to humans (Group probably carcinogenic to humans (Group 2A) or possibly carcinogenic to humans (Group 2B). Reproductive toxicity No information available. Specific target organ systemic toxicity (single exposure) No information available. Specific target organ systemic toxicity (repeated exposure) No information available. Target Organ Effects Central nervous system, Eyes, Peripheral Nervous System (PNS), Respiratory system, Skin. Aspiration hazard No information available. Numerical measures of toxicity - Product Information Unknown Aquatic Toxicty 16.86256% of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 6980 mg/kg ATEmix (dermal) 4702 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphnia and other aquatic invertebrates HEXANE 64742-49-0 2.6: 96 h Chaetogammarus marinus mg/L LC50 Persistence and degradability No information available. Bioaccumulation No information available. Chemical Name log Pow PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 2.8 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Page 795 of 871 Page 795 of 871 Page 795 of 871 Page 795 of 871 ---PAGE BREAK--- 97673 TefGel Penetrating Gel Gear Lubricant with P.T.F.E. Revision Date 11-Feb-2014 Page 7 / 8 Waste treatment Waste Disposal Methods This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not re-use empty containers. 14. TRANSPORT INFORMATION DOT Ground CONSUMER COMMODITY ORM-D or LIMITED QUANTITY IATA UN1950, AEROSOLS, FLAMMABLE, 2.1, LTD. QTY. IMDG UN1950, AEROSOLS, 2.1, LTD. QTY. 15. REGULATORY INFORMATION International Inventories Chemical Name TSCA DSL/NDSL EINECS/ELI NCS ENCS IECSC KECL PICCS AICS HEXANE X X X X X Present X X PROPANE/ISOBUTAN E/N-BUTANE X X X Not listed X Present X X TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances CHINA - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard Yes Sudden Release of Pressure Hazard no Reactive Hazard no Page 796 of 871 Page 796 of 871 Page 796 of 871 Page 796 of 871 ---PAGE BREAK--- 97673 TefGel Penetrating Gel Gear Lubricant with P.T.F.E. Revision Date 11-Feb-2014 Page 8 / 8 Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): U.S. State Regulations California Proposition 65 This product does not contain any known Proposition 65 chemicals. U.S. State Right-to-Know Regulations Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION NFPA Health Hazard 2 Flammability 4 Instability 0 Physical and chemical hazards - HMIS Health Hazard 2* Flammability 4 Physical Hazard 1 Personal protection B Chronic Hazard Star Legend Chronic Health Hazard; Repeated or prolonged exposure may cause central nervous system damage Prepared By Maureen Ruggeberg, Regulatory Affairs Specialist Issuing date 11-Feb-2014 Revision Date 11-Feb-2014 Revision Note No information available Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of Safety Data Sheet Page 797 of 871 Page 797 of 871 Page 797 of 871 Page 797 of 871 ---PAGE BREAK--- Material Safety Data Sheet: TEL-X PLUS AEROSOL Supercedes Date 11/12/2008 Issuing Date 04/01/2011 1. PRODUCT AND COMPANY IDENTIFICATION Product Name TEL-X PLUS AEROSOL Product Code 5496 Recommended use Lubricant Chemical nature Resins in solution Information on Manufacturer Emergency Telephone Number CHEMSEARCH DIV. OF NCH CORP. CHEMTREC 1-[PHONE REDACTED] BOX 152170 IRVING, TX 75015 2. HAZARDS IDENTIFICATION Emergency Overview DANGER! Extremely flammable May cause skin irritation Causes eye irritation May be harmful if inhaled May be harmful if swallowed Color white Physical State Liquid Odor Rubbing alcohol Potential Health Effects Principle Route of Exposure Inhalation, Skin contact, Eye contact. Primary Routes of Entry Inhalation Acute Effects Eyes Causes eye irritation. Skin May cause skin irritation. Inhalation May cause irritation of respiratory tract. Inhalation may cause central nervous system effects. May cause central nervous system depression. and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. May be fatal if inhaled in large quantities. Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Chronic Toxicity May cause polymer fume fever, a temporary flu-like illness accompanied by chills, fever, and a cough. This can last up to 24 hours in duration . Prolonged or repeated exposure increases the risk. Liver and kidney injuries may occur. Target Organ Effects Eyes, Skin, Respiratory system, Central nervous system, Liver, Kidney. Aggravated Medical Conditions Skin disorders, Respiratory disorders, Neurological disorders, Liver disorders, Kidney disorders. Potential Environmental Effects See Section 12 for additional Ecological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Component CAS-No Isopropyl alcohol 67-63-0 Butane 106-97-8 Propane 74-98-6 Polytetrafluoroethylene 9002-84-0 4. FIRST AID MEASURES General Advice Avoid contact with skin, eyes and clothing. Avoid breathing vapors or mists. Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. Get medical attention if irritation develops and persists. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention if irritation develops and persists. Wash contaminated clothing before re-use. Inhalation If inhaled, remove to fresh air. Get medical attention if occur. Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention if occur. Never give anything by mouth to an unconscious person. Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Flash Point 53 °F / 12 °C Method Seta closed cup Autoignition Temperature No information available. Flammability Limits in Air % . Upper 12.7 Lower 1.8 Suitable Extinguishing Media Foam. Alcohol-resistant foam. Dry chemical. Water spray. Carbon dioxide (CO2). Unsuitable Extinguishing Media None known. Specific hazards arising from the chemical Solvent vapors are heavier than air and may spread along floors. Vapors may ignite and explode. Flame extension: 30 inches / 75 cm and Burnback: 0 inches / 0 cm. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Aerosol Level (NFPA 30B) - 3 NFPA Health 2 Flammability 4 Instability 0 Page 1 / 4 Page 798 of 871 Page 798 of 871 Page 798 of 871 Page 798 of 871 ---PAGE BREAK--- HMIS Health 2 Flammability 4 Instability 0 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Use personal protective equipment. Remove all sources of ignition. Ensure adequate ventilation. Prevent further leakage or spillage if safe to do so. Material can create slippery conditions. Environmental Precautions Do not flush into surface water or sanitary sewer system. Methods for Containment Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Methods for Cleaning Up Use clean non-sparking tools to collect absorbed material. Pick up and transfer to properly labeled containers. Neutralizing Agent Not applicable. 7. HANDLING AND STORAGE Handling Keep away from open flames, hot surfaces and sources of ignition. Avoid contact with skin, eyes and clothing. Avoid breathing vapors, mist or gas. Storage Keep away from heat and sources of ignition. Storage Temperature Minimum 35 °F / 2 °C Maximum 120 °F / 49 °C Storage Conditions Indoor X Outdoor Heated Refrigerated 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH Isopropyl alcohol TWA: 200 ppm STEL: 400 ppm TWA: 400 ppm TWA: 980 mg/m3 IDLH: 2000 ppm STEL 500 ppm STEL 1225 mg/m3 TWA: 400 ppm TWA: 980 mg/m3 Butane TWA: 1000 ppm No data available TWA: 800 ppm TWA: 1900 mg/m3 Propane TWA: 1000 ppm TWA: 1000 ppm TWA: 1800 mg/m3 IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 Polytetrafluoroethylene No data available No data available No data available Engineering Measures Ensure adequate ventilation, especially in confined areas. Handle only in a place equipped with local exhaust (or other appropriate exhaust). Personal Protective Equipment Eye/Face Protection Safety glasses with side-shields. Skin Protection For prolonged or repeated contact, use protective gloves Respiratory Protection In case of insufficient ventilation wear suitable respiratory equipment. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. General Hygiene Considerations Ensure that eyewash stations and safety showers are close to the workstation location. Remove and wash contaminated clothing before re-use. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Viscosity Slight Viscous Color white Odor Rubbing alcohol Appearance Cloudy pH Not applicable Specific Gravity 0.69 Evaporation Rate 51.6 Percent Volatile (Volume) 99.7 VOC Content 99.0 VOC Photoreactive (Y/N) Yes Vapor Pressure 1301 mmHg @ 70°F Vapor Density 1.9 Solubility Moderately soluble Boiling Point/Range 180 °F / 82 °C 10. STABILITY AND REACTIVITY Chemical Stability Stable. Hazardous polymerization does not occur. Conditions to Avoid Keep away from open flames, hot surfaces, and sources of ignition Incompatible Products Strong oxidizing agents, Strong acids. Hazardous Decomposition Products Carbon oxides, Hydrogen fluoride, Fluorinated hydrocarbons. Possibility of Hazardous Reactions None under normal processing 11. TOXICOLOGICAL INFORMATION Product Information No information available. Component Information Acute Toxicity No information available Component LD50 Oral LD50 Dermal LC50 Inhalation Draize Test Other Isopropyl alcohol = 4396 mg/kg ( Rat ) = 12800 mg/kg ( Rat ) = 12870 mg/kg ( Rabbit ) = 72.6 mg/L ( Rat ) 4 h no data available no data available Butane no data available no data available = 658 mg/L ( Rat ) 4 h no data available no data available 5496 - TEL-X PLUS AEROSOL 5496 - TEL-X PLUS AEROSOL 5496 - TEL-X PLUS AEROSOL 5496 - TEL-X PLUS AEROSOL Issuing Date 01-Apr-2011 Issuing Date 01-Apr-2011 Issuing Date 01-Apr-2011 Issuing Date 01-Apr-2011 Page 2 / 4 Page 799 of 871 Page 799 of 871 Page 799 of 871 Page 799 of 871 ---PAGE BREAK--- Propane no data available no data available = 658 mg/L ( Rat ) 4 h no data available no data available Polytetrafluoroethylene no data available no data available = 45 mg/m3 ( Rat ) 30 min no data available no data available Chronic Toxicity Component Mutagenicity Sensitization Developmental Toxicity Reproductive Toxicity Target Organ Effects Isopropyl alcohol no data available no data available no data available no data available eyes, respiratory system, skin, liver, kidney, CNS Butane no data available no data available no data available no data available CNS Propane no data available no data available no data available no data available CNS Polytetrafluoroethylene no data available no data available no data available no data available no data available Carcinogenicity There are no known carcinogenic chemicals in this product. Component ACGIH IARC NTP OSHA Other Isopropyl alcohol not applicable not applicable not applicable not applicable not applicable Butane not applicable not applicable not applicable not applicable not applicable Propane not applicable not applicable not applicable not applicable not applicable Polytetrafluoroethylene not applicable not applicable not applicable not applicable not applicable 12. ECOLOGICAL INFORMATION Product Information No information available. Component Information Component Toxicity to Algae Toxicity to Fish Microtox Water Flea log Pow Isopropyl alcohol EC50 > 1000 mg/L Desmodesmus subspicatus 72 h EC50 > 1000 mg/L Desmodesmus subspicatus 96 h LC50 = 11130 mg/L Pimephales promelas 96 h LC50 = 9640 mg/L Pimephales promelas 96 h LC50 > 1400000 µg/L Lepomis macrochirus 96 h EC50 = 35390 mg/L 5 min = 13299 mg/L 48 h 0.05 Butane no data available no data available no data available no data available 2.89 Propane no data available no data available no data available no data available 2.3 Polytetrafluoroethylene no data available no data available no data available no data available N/A Persistence and Degradability No information available. Bioaccumulation No information available. Mobility No information available. 13. DISPOSAL CONSIDERATIONS Product Disposal Dispose of in accordance with local regulations. Container Disposal Warning! Container under pressure. Do not puncture. Empty remaining contents. 14. TRANSPORT INFORMATION DOT Proper Shipping Name Consumer commodity Hazard Class ORM-D Description Consumer commodity ,ORM-D, TDG Proper shipping name Aerosols Hazard Class 2.1 UN-No UN1950 Description AEROSOLS,2.1,UN1950 LTD. QTY. ICAO UN-No UN1950 Proper Shipping Name Aerosols Hazard Class 2.1 Shipping Description Aerosols,UN1950 LTD. QTY. IATA UN-No UN1950 Proper Shipping Name Aerosols, flammable Hazard Class 2.1 ERG Code 10L Shipping Description UN1950,Aerosols, flammable,2.1 LTD. QTY. IMDG/IMO Proper Shipping Name Aerosols Hazard Class 2.1 UN-No UN1950 EmS No. F-D, S-U 5496 - TEL-X PLUS AEROSOL 5496 - TEL-X PLUS AEROSOL 5496 - TEL-X PLUS AEROSOL 5496 - TEL-X PLUS AEROSOL Issuing Date 01-Apr-2011 Issuing Date 01-Apr-2011 Issuing Date 01-Apr-2011 Issuing Date 01-Apr-2011 Page 3 / 4 Page 800 of 871 Page 800 of 871 Page 800 of 871 Page 800 of 871 ---PAGE BREAK--- Shipping Description UN1950, Aerosols,2.1 LIMITED QUANTITIES 15. REGULATORY INFORMATION Inventories TSCA Complies DSL Complies U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part 372. Component CAS-No Weight % SARA 313 - Threshold Values Isopropyl alcohol 67-63-0 40-70 1.0 % de minimis concentration (only if manufactured by the strong acid process, no supplier notification) SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard Yes Sudden Release of Pressure Hazard Yes Reactive Hazard No CERCLA Component Hazardous Substances RQs CERCLA EHS RQs Isopropyl alcohol Not applicable Not applicable Butane Not applicable Not applicable Propane Not applicable Not applicable Polytetrafluoroethylene Not applicable Not applicable Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class A Compressed gases, B5 Flammable aerosol, D2B Toxic materials. 16. OTHER INFORMATION Prepared By Mike McDowell Supercedes Date 11/12/2008 Issuing Date 03/31/2011 Reason for Revision No information available. Glossary No information available. List of References. No information available. CHEMSEARCH DIV. OF NCH CORP. assumes no responsibility for personal injury or property damage caused by the use, storage, or disposal of the product in a manner not recommended on the product label. Users assume all risks associated with such unrecommended use, storage or disposal of the product. The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. 5496 - TEL-X PLUS AEROSOL 5496 - TEL-X PLUS AEROSOL 5496 - TEL-X PLUS AEROSOL 5496 - TEL-X PLUS AEROSOL Issuing Date 01-Apr-2011 Issuing Date 01-Apr-2011 Issuing Date 01-Apr-2011 Issuing Date 01-Apr-2011 Page 4 / 4 Page 801 of 871 Page 801 of 871 Page 801 of 871 Page 801 of 871 ---PAGE BREAK--- Material Safety Data Sheet Material Safety Data Sheet Material Safety Data Sheet Material Safety Data Sheet Page 1 of 7 Section 1: Product & Company Identification Product Name: Smoke Test® Product Number 02105, 72105 Product Use: Smoke Detector Tester Manufacturer / Supplier Contact Information: In United States: In Canada: In Mexico: CRC Industries, Inc. CRC Canada Co. CRC Industries Mexico 885 Louis Drive 2-1246 Lorimar Drive Av. Benito Juárez 4055 G Warminster, PA 18974 Mississauga, Ontario L5S 1R2 Colonia Orquídea www.crcindustries.com www.crc-canada.ca San Luís Potosí, SLP CP 78394 1-[PHONE REDACTED] (General) 1-[PHONE REDACTED] www.crc-mexico.com (800) 521-3168 (Technical) 52-[PHONE REDACTED] (800) 272-4620 (Customer Service) 24-Hr Emergency – CHEMTREC: (800) 424-9300 or (703) 527-3887 Section 2: Hazards Identification Emergency Overview DANGER: Extremely Flammable. Contents Under Pressure. As defined by OSHA’s Hazard Communication Standard, this product is hazardous. Appearance & Odor: Packaged product is a clear, water-white liquid; dispensed product is a smoky mist; alcohol odor Potential Health Effects: ACUTE EFFECTS: EYE: Liquid contact can cause severe irritation, redness, tearing, blurred vision and possible freeze burns. The effects of eye contact with the spray mist are likely to be less severe. SKIN: Contact with evaporating liquid can cause frostbite. Contact with spray mist is not likely to produce health effects. INHALATION: Inhalation of vapor may produce anesthetic effects, irritation of nose and throat, and feeling of euphoria. Prolonged overexposure can cause rapid breathing, headache, dizziness, narcosis, central nervous system depression, unconsciousness or death from depending on concentration and duration of exposure. INGESTION: May cause gastrointestinal irritation, including nausea and vomiting. Ingestion of ethanol can cause drunkenness and central nervous system depression. CHRONIC EFFECTS: Ethanol is a developmental toxin and various effects have been associated with ethanol abuse, including physical dependence, cardiac myopathy, amnesia, and hepatotoxicity. TARGET ORGANS: Liver Medical Conditions Aggravated by Exposure: Pre-existing liver or nervous system conditions See Section 11 for toxicology and carcinogenicity information on product ingredients. Page 802 of 871 Page 802 of 871 Page 802 of 871 Page 802 of 871 ---PAGE BREAK--- Product Name: Smoke Test® Product Number 02105, 72105 Page 2 of 7 Section 3: Composition/Information on Ingredients COMPONENT CAS NUMBER % by Wt. Ethanol 64-17-5 25 – 35 1,2,3-Propanetriol 56-81-5 2 – 5 Liquefied petroleum gas 68476-86-8 65 - 75 Section 4: First Aid Measures Eye Contact: Immediately flush with plenty of water for 15 minutes. Call a physician if irritation persists. Skin Contact: Remove contaminated clothing and wash affected area with soap and water. Call a physician if irritation persists. Wash contaminated clothing prior to re-use. Inhalation: Remove person to fresh air. Keep person calm. If not breathing, give artificial respiration. If breathing is difficult give oxygen. Call a physician. Ingestion: Do not induce vomiting. If victim is completely conscious and alert, have them drink water. Contact a physician for further treatment. Note to Physicians: Treatment of overexposure should be directed at the control of and the clinical condition of the patient. Section 5: Fire-Fighting Measures Flammable Properties: This product is extremely flammable in accordance with aerosol flammability definitions. (See 16 CFR 1500.3(c)(6) ) Use with caution around energized equipment. Flash Point: 56°F (TCC) Upper Explosive Limit: 19.0 Autoignition Temperature: 685.4°F Lower Explosive Limit: 1.9 Fire and Explosion Data: Suitable Extinguishing Media: Use Class B extinguishing agents such as dry chemical, CO2, water spray or alcohol- resistant foam. Products of Combustion: oxides of carbon, volatile hydrocarbon vapors Explosion Hazards: Aerosol containers, when exposed to heat from fire, may build pressure and explode. Vapors can accumulate and create a flammable atmosphere. Protection of Fire-Fighters: Firefighters should wear self-contained, NIOSH-approved breathing apparatus for protection against suffocation and possible toxic decomposition products. Proper eye and skin protection should be provided. Use water spray to keep fire-exposed containers cool and to knock down vapors which may result from product decomposition. Section 6: Accidental Release Measures Personal Precautions: Use personal protection recommended in Section 8. Environmental Precautions: Take precautions to prevent contamination of ground and surface waters. Do not flush into sewers or storm drains. Methods for Containment & Clean-up: Eliminate all sources of ignition. Dike area to contain spill. Ventilate the area Page 803 of 871 Page 803 of 871 Page 803 of 871 Page 803 of 871 ---PAGE BREAK--- Product Name: Smoke Test® Product Number 02105, 72105 Page 3 of 7 with fresh air. If in confined space or limited air circulation area, clean-up workers should wear appropriate respiratory protection. Recover or absorb spilled material using an absorbent designed for chemical spills. Place used absorbents into proper waste containers. Section 7: Handling and Storage Handling Procedures: Do not use this product near sources of ignition. Liquid contents are flammable. Dispensed mist can create flammable atmosphere. Use in ventilated areas only. Avoid inhaling vapors. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. For product use instructions, please see the product label. Storage Procedures: Store in a cool dry area out of direct sunlight. Aerosol cans must be maintained below 120 F to prevent cans from rupturing. Store out of reach of children Aerosol Storage Level: III Section 8: Exposure Controls/Personal Protection Exposure Guidelines: OSHA ACGIH OTHER COMPONENT TWA STEL TWA STEL TWA SOURCE UNIT Ethanol 1000 NE 1000 NE NE ppm 1,2,3-Propanetriol 15 NE 10 NE NE mg/m3 Liquefied petroleum gas 1000 NE 1000 NE NE ppm N.E. – Not Established – ceiling – skin – vacated Controls and Protection: Engineering Controls: Area should have ventilation to provide fresh air. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at the source, preventing dispersion into the general work area. Use mechanical means if necessary to maintain vapor levels below the exposure guidelines. If working in a confined space, follow applicable OSHA regulations. Respiratory Protection: None required for normal work where adequate ventilation is provided. If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with organic vapor cartridge. Air monitoring is needed to determine actual employee exposure levels. Use a self-contained breathing apparatus in confined spaces and for emergencies. Eye/face Protection: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear splash-proof goggles. Skin Protection: Use protective gloves such as rubber, neoprene or vinyl. Also, use full protective clothing if there is prolonged or repeated contact of liquid with skin. Section 9: Physical and Chemical Properties Physical State: liquid (dispensed product is a mist) Color: colorless (dispensed product has smoky haze) Odor: alcohol Odor Threshold: ND Page 804 of 871 Page 804 of 871 Page 804 of 871 Page 804 of 871 ---PAGE BREAK--- Product Name: Smoke Test® Product Number 02105, 72105 Page 4 of 7 Specific Gravity: 0.817 Initial Boiling Point: 173°F Freezing Point: - 227.2°F Vapor Pressure: ~44.6 mmHg @ 68°F Vapor Density: > 1 (air = 1) Evaporation Rate: very fast Solubility: complete Coefficient of water/oil distribution: ND pH: NA Volatile Organic Compounds: wt 97.5 g/L: 796.6 lbs./gal: 6.64 Section 10: Stability and Reactivity Stability: Stable Conditions to Avoid: excessive heat, sparks, open flame or other sources of ignition Incompatible Materials: acetyl chloride, or other strong oxidizing agents or strong acids Hazardous Decomposition Products: oxides of carbon; thermal decomposition may release acrolein Possibility of Hazardous Reactions: No Section 11: Toxicological Information Long-term toxicological studies have not been conducted for this product. The following information is available for components of this product. Acute Toxicity: Component Oral LD50 (rat) Dermal LD50 (rabbit) Inhalation LC50 (rat) Ethanol 760 mg/kg No data 20,000 ppm/10H 1,2,3-Propanetriol 12,600 mg/kg No data No data Liquefied petroleum gas No data No data No data Chronic Toxicity: Component OSHA Carcinogen IARC Carcinogen NTP Carcinogen Irritant Sensitizer Ethanol No No No E (mild) / S (moderate) Unknown 1,2,3-Propanetriol No No No No Unknown Liquefied petroleum gas No No No No No Reproductive Toxicity: Ethanol: Developmental Toxin Teratogenicity: No information available Mutagenicity: No information available Synergistic Effects: No information available Section 12: Ecological Information Ecological studies have not been conducted for this product. The following information is available for components of this product. Ecotoxicity: Ethanol - 48 Hr EC50 Daphnia magna: 9268 mg/L E – Eye S – Skin R - Respiratory Page 805 of 871 Page 805 of 871 Page 805 of 871 Page 805 of 871 ---PAGE BREAK--- Product Name: Smoke Test® Product Number 02105, 72105 Page 5 of 7 5 min EC50 Photobacterium phosphoreum: 35470 mg/L Persistence / Degradability: Ethanol and 1,2,3-propanetriol are expected to be biodegradable. Bioaccumulation / Accumulation: Ethanol is not expected to bioaccumulate. Mobility in Environment: No information available Section 13: Disposal Considerations Waste Classification: Any liquid product would be a RCRA hazardous waste for the characteristic of ignitability with a waste code of D001. Pressurized containers are a D003 reactive waste. (See 40 CFR Part 261.20 – 261.33) Empty aerosol containers may be recycled. All disposal activities must comply with federal, state, provincial and local regulations. Local regulations may be more stringent than state, provincial or national requirements. Section 14: Transport Information US DOT (ground): Consumer Commodity, ORM-D ICAO/IATA (air): Consumer Commodity, ID8000, 9 IMO/IMDG (water): Aerosols, UN1950, 2.1, Limited Quantity Special Provisions: None Section 15: Regulatory Information U.S. Federal Regulations: Toxic Substances Control Act (TSCA): All ingredients are either listed on the TSCA inventory or are exempt. Comprehensive Environmental Response, Compensation and Liability Act (CERCLA): Reportable Quantities (RQ’s) exist for the following ingredients: None Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center ([PHONE REDACTED]) and to your Local Emergency Planning Committee. Superfund Amendments Reauthorization Act (SARA) Title III: Section 302 Extremely Hazardous Substances (EHS): None Section 311/312 Hazard Categories: Fire Hazard Yes Reactive Hazard No Release of Pressure Yes Acute Health Hazard Yes Chronic Health Hazard Yes Section 313 Toxic Chemicals: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: None Clean Air Act: Section 112 Hazardous Air Pollutants (HAPs): None U.S. State Regulations: Page 806 of 871 Page 806 of 871 Page 806 of 871 Page 806 of 871 ---PAGE BREAK--- Product Name: Smoke Test® Product Number 02105, 72105 Page 6 of 7 California Safe Drinking Water and Toxic Enforcement Act (Prop 65): This product may contain the following chemicals known to the state of California to cause cancer, birth defects or other reproductive harm: None Consumer Products VOC Regulations: This product is not regulated. State Right to Know: New Jersey: 64-17-5 56-81-5, 64-17-5 Massachusetts: 56-81-5, 64-17-5 Rhode Island : 56-81-5, 64-17-5 Canadian Regulations: Canadian DSL Inventory: All ingredients are either listed on the DSL Inventory or are exempt. WHMIS Hazard Class: A, B5, D2B European Union Regulations: RoHS Compliance: This product is compliant with Directive 2002/95/EC of the European Parliament and of the Council of 27 January 2003. This product does not contain any of the restricted substances as listed in Article 4(1) of the RoHS Directive. Additional Regulatory Information: None Section 16: Other Information HMIS® (II) Health: 1 Flammability: 4 Reactivity: 0 PPE: B Ratings range from 0 (no hazard) to 4 (severe hazard) NFPA Prepared By: Michelle Rudnick CRC 418 Revision Date: 08/07/2008 Changes since last revision: MSDS reformatted to meet the requirements of the Canadian Controlled Products Regulations. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this MSDS consult your supervisor, a health & safety professional, or CRC Industries. 4 0 1 Page 807 of 871 Page 807 of 871 Page 807 of 871 Page 807 of 871 ---PAGE BREAK--- Product Name: Smoke Test® Product Number 02105, 72105 Page 7 of 7 ACGIH: American Conference of Governmental Industrial Hygienists CAS: Chemical Abstract Service CFR: Code of Federal Regulations DOT: Department of Transportation DSL: Domestic Substance List g/L: grams per Liter HMIS: Hazardous Materials Identification System IARC: International Agency for Research on Cancer IATA: International Air Transport Association ICAO: International Civil Aviation Organization IMDG: International Maritime Dangerous Goods IMO: International Maritime Organization lbs./gal: pounds per gallon LC: Lethal Concentration LD: Lethal Dose NA: Not Applicable ND: Not Determined NIOSH: National Institute of Occupational Safety & Health NFPA: National Fire Protection Association NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration PMCC: Pensky-Martens Closed Cup PPE: Personal Protection Equipment ppm: Parts per Million RoHS: Restriction of Hazardous Substances STEL: Short Term Exposure Limit TCC: Tag Closed Cup TWA: Time Weighted Average WHMIS: Workplace Hazardous Materials Information System Page 808 of 871 Page 808 of 871 Page 808 of 871 Page 808 of 871 ---PAGE BREAK--- Page 809 of 871 Page 809 of 871 Page 809 of 871 Page 809 of 871 ---PAGE BREAK--- Page 810 of 871 Page 810 of 871 Page 810 of 871 Page 810 of 871 ---PAGE BREAK--- TURTLE WAX, INC. 625 WILLOWBROOK CTR PKWY WILLOWBROOK, IL 60527 SAFETY DATA SHEET 1. Product and Company Identification 1.1 Product Identifier Product Name: Turtle Wax Rubbing Compound Heavy Duty Cleaner Product Code (SKU): T230A (50191), T230AC (50192), T230AS (50193) 1.2 Relevant Identified Uses Of The Substance Product Use: Automotive Rubbing and Polishing Compound 1.3 Details of the Supplier of the SDS Company Name: Turtle Wax, Inc. Street Address: 625 Willowbrook Centre Parkway City, State, Zip Code: Willowbrook, Illinois 60527 1.4 Emergency Telephone Numbers Phone Number: 1(630)455-3700 Fax Number: 1(630)455-3868 Transportation: 1(800)424-9300 (CHEMTREC) Medical Assistance: Call your local Poison Control Center 2. Hazard Identification: 2.1 Classification of the Substance or Mixture Hazard Classification: not classified 2.2 Label Elements Pictogram: not required Signal Word: none Hazard Statement: none Precautionary Statement: none 2.3 Other Hazards Description of additional HNOC: none 3. Information on Ingredients: 3.1 Substance not applicable 3.2 Mixture Component CAS Number Concentration (wt%) Water 7732-18-5 >65% Kaolin Clay 66402-68-4 7 – 13% White Mineral Oil 8042-47-5 1 – 3% Page 811 of 871 Page 811 of 871 Page 811 of 871 Page 811 of 871 ---PAGE BREAK--- 4. First Aid Measures: 4.1 Description of First Aid Measures Inhalation: Remove to fresh air and promote deep breathing. Get medical attention if effects persist. Skin: In case of skin contact, wash thoroughly with soap and water. If irritation persists, get medical attention. Eyes: In case of eye contact, immediately flush eyes with plenty of water. Remove contact lenses if worn. If irritation persists, get medical attention Ingestion: If swallowed, do not induce vomiting. Never give anything by mouth to an unconscious person. Give water to drink if conscious. Get medical attention if effects persist. 4.2 Most important and effects – acute and chronic Inhalation: May cause respiratory tract irritation. Skin: May cause skin irritation. May cause drying, cracking, or mild dermatitis. Eyes: May cause temporary eye irritation. Ingestion: May cause stomach distress, nausea, and vomiting. 4.3 Indication of any immediate medical attention and special treatment may not appear immediately. Seek medical attention if effects persist and you feel un- well. 5. Fire Fighting Measures: 5.1 Extinguishing media Water spray, carbon dioxide, dry chemical, and alcohol foam 5.2 Special hazards arising from the substance or mixture CO2, CO, and hydrocarbons 5.3 Advice for Fire Fighters Keep up wind of fire. Wear full firefighting turn out gear (full bunker gear) and respiratory protection (SCBA). See Section 8 for personal protection. 6. Accidental Release Measures: 6.1 Personal precautions, protective equipment, and emergency procedures Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. 6.2 Methods and materials for containment and clean up For containment: Contain and absorb spill with inert material. Place in suitable container for disposal. Spilled material may be slippery. For clean up: Take up material and place in a suitable container. Provide adequate ventilation. Spilled material may be slippery. 7. Handling and Storage Page 812 of 871 Page 812 of 871 Page 812 of 871 Page 812 of 871 ---PAGE BREAK--- 7.1 Precautions for safe handling Avoid contact with skin and eyes. Do not swallow. Do not eat, drink or smoke while handling. Wash hands with soap and water after handling. Launder all clothing and foot wear before re- use. 7.2 Conditions for safe storage including incompatibilities Keep out of reach of children. Keep container closed. Store in a well ventilated place. Do not store above 49°C (120°F). 7.3 Specific end uses Shelf Life: Shelf life is considered to be 7 – 10 years when properly stored and kept closed. 8. Exposure Control/Personal Protection: 8.1 Control parameters Exposure Limits 8 hr TWA: (OSHA PEL) (ACGIH TWA) Kaolin Clay 15 mg/m3 (total dust) 2 mg/m3 5 mg/m3 (Respirable fraction) White Mineral Oil not applicable not applicable 8.2 Exposure controls Use adequate ventilation to keep exposure below recommended limits. Ensure that eye wash station and safety shower are close to work station. Hand Protection Equipment: Wear chemical resistant gloves and clothing to prevent skin contact. Eye Protection Equipment: Wear safety glasses or splash goggles to prevent eye contact. Skin and Body Protection: Wear suitable protective clothing. Respiration/Ventilation Protection Requirements: Provide good ventilation. Ingestion Protection Requirements: Do not eat, drink or smoke while handling. Wash hands with soap and water after handling. Launder all clothing and foot wear before re-use. 9. Physical And Chemical Properties: 9.1 Information of basic chemical and physical properties Physical Form: Cream semi-hard paste Color: Dark reddish-brown Odor: Typical Odor Threshold: not available pH: 9.4 (1:1 with soft water) Melting Point/Freeze Point: 0°C (32°F) – Based on Water Initial Boiling Point: 100°C (212°F) – Based on Water Flash Point (Seta Closed Cup): >93°C (200°F) Flammability Limits: Explosive Limits: Upper: not available Lower: not available Evaporation Rate: not available Flammability Solid/Gas: not applicable Vapor Pressure: not available Vapor Density: not available Specific Gravity: 1.061 Solubility in Water: Dispersible Auto Ignition Temperature: not available Partition coefficient (n/octonol/water): not available Viscosity: n/av Page 813 of 871 Page 813 of 871 Page 813 of 871 Page 813 of 871 ---PAGE BREAK--- 9. 2 Other information %NVM by Weight: 18.0% %VOC Content (California): 0.0% 10. Stability and Reactivity: 10.1 Reactivity Does not react under normal conditions 10.2 Chemical stability Stable 10.3 Possibility of hazardous reactions Does not react under normal conditions 10.4 Conditions to avoid Heat and incompatible materials 10.5 Incompatible materials Strong oxidizers such as bleach and peroxides 10.6 Hazardous decomposition products CO2, CO and hydrocarbons 11. Toxicological Information: 11.1 Information on Toxicological effects Turtle Wax Rubbing Compound Heavy Duty Cleaner LD50 – Oral Rat >2000 mg/Kg LD50 – Dermal Rat >2000 mg/Kg LC50 – Inhalation Rat >20 mg/L (4 hr) Skin corrosion/irritation Based on available data, classification data are not met Serious eye damage/irritation Based on available data, classification data are not met Respiratory or skin sensitization Based on available data, classification data are not met Germ cell mutagenicity Based on available data, classification data are not met Carcinogenicity Based on available data, classification data are not met Reproductive toxicity Based on available data, classification data are not met Specific target organs – single exposure Based on available data, classification data are not met Specific target organs – repeated exposure Based on available data, classification data are not met Aspiration hazard Based on available data, classification data are not met after inhalation May cause respiratory tract irritation after skin contact May cause skin irritation. May cause drying, cracking, or mild dermatitis. after eye contact May cause temporary eye irritation. after ingestion May cause stomach distress, nausea, and vomiting. 12. Ecological Information: 12.1 Toxicity Not recommended for release into aquatic systems without treatment 12.2 Persistence and degradability Not established Page 814 of 871 Page 814 of 871 Page 814 of 871 Page 814 of 871 ---PAGE BREAK--- 12.3 Bioaccumulative potential Not established 12.4 Mobility in soil Not established 12.5 Other adverse effects None known 13. Disposal Considerations: 13.1 Waste treatment methods RCRA Hazardous Waste: Not regulated as a hazardous waste Waste Disposal Method: Dispose of in accordance with local, state and federal regulations Waste Disposal Vessel: Plastic or metal drums. 14. Transportation Information: 14.1 UN number None - not regulated as a hazardous material 14.2 UN Proper shipping name None 14.3 Transport Hazard class Not applicable 14.4 Packaging group Not applicable 14.5 Marine Pollutant No 14.6 Transportation in Bulk Not applicable 14.7 Special precautions None 15. Regulatory Information: 15.1 US Federal Regulations TSCA Status: All ingredients are commercially available and listed by the manufacturer under TSCA. 15.2 Foreign Regulations Canadian Status: All materials contained in this product are listed on the Canadian Domestic Substance List (DSL). Consult Turtle Wax, Inc. regarding status of ingredients. European Union: All materials contained in this product are listed on EINECS. AICS: All materials are registered for AICS (Australia) 15.3 State Regulations Page 815 of 871 Page 815 of 871 Page 815 of 871 Page 815 of 871 ---PAGE BREAK--- State Regulatory Information: The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the SDS may also be applicable for state requirements. For details on your regulatory requirements, contact the appropriate agency in your state. California Prop 65: CAS Number Concentration State Code None 15.4 HIMS & NFPA Classifications HIMS Classification: Health 1 Flammability 1 Reactivity 0 NFPA Classification: Health 1 Flammability 1 Reactivity 0 16. Other Information: Reason For Issue Conversion to OSHA GHS SDS Format Prepared By Jean Mayszak Preparer’s Title Technical Compliance Manager, R&D SDS Administrator Jean Mayszak - Technical Compliance Manager, R&D Approval Date May 14, 2015 Supersedes Date September 1, 2013 Revision Number A – 4 This information is, to the best of Turtle Wax, Inc.’s knowledge and belief, accurate and reliable. However, no representation, warranty, or guarantee is made to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy oneself as to the suitableness and completeness of such information for their own particular use. Page 816 of 871 Page 816 of 871 Page 816 of 871 Page 816 of 871 ---PAGE BREAK--- - 1 - UNITED 101 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 101 MOISTURE BARRIER Moisture Barrier and Electrical Lubricant February 6, 2015 HMIS III HEALTH (0 = Maximum Safety) 1 PHYSICAL HAZARD (0 = Maximum Safety) 0 Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 FLAMMABILITY (0 = Maximum Safety) 1 2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) Food grade mineral oil 8042-47-5 40-70 5 mg/m3 5 mg/m3 NE NE 556-67-2 1-5 10 ppm* NE NE NE Dipropylene glycol monomethyl ether 34590-94-8 1-5 100 ppm (Skin) 100 ppm (Skin) NE NE 541-02-6 1-5 10 ppm* NE NE NE Carbon dioxide 124-38-9 1-5 5000 ppm 5000 ppm NE NE * Manufacturer’s recommended TWA exposure limit. 3. HAZARDS IDENTIFICATION Eyes: May cause slight irritation; does not injure eye tissue. Skin: Prolonged or repeated contact may cause moderate irritation. Inhalation: Exposure to massive amount of vapors may cause dizziness, drowsiness, throat irritation, unconsciousness and CNS effects. Ingestion: May cause upset stomach, nausea, vomiting, and diarrhea. Possible aspiration hazard may cause inflammation of the lungs. 4. FIRST AID MEASURES Eyes: Flush with large amounts of cool running water for at least 15 minutes while holding upper and lower lids open. If irritation persists call a physician. Skin: Wash with soap and water. If irritation persists call a physician. Inhalation: Remove to fresh air immediately. Apply artificial respiration if needed. Call a physician immediately. Ingestion: DO NOT induce vomiting. Call a physician immediately. Aspiration may cause chemical pneumonitis. 5. FIRE FIGHTING MEASURES Flash Point (TOC) : >200°F/93.3°C Explosive Limits: Lower (LEL): NE Upper (UEL): NE Flame Projection (Aerosol): Non- flammable per 16 CFR 1500.3 and 1500.45. Hazardous Products of Combustion: When strongly heated, as in a fire, this product may produce oxides of carbon. Fire and Explosion Hazards: Aerosol container (pressurized) may burst if heated over 120°F/48°C. Extinguishing Media: Foam, Dry chemical, Carbon dioxide. Fire Fighting Instructions: Wear self-contained breathing apparatus w/full protective clothing in chemical fires. Cool fire exposed containers with water to prevent pressure build up. MATERIAL SAFETY DATA SHEET 320 37th Avenue, St. Charles, Illinois 60174 To Reorder Call: www.unitedlabsinc.com . www.unitedlabsinc.com [PHONE REDACTED] Always follow Label Directions and Cautions. * Chronic 2 Moderate 4 Severe 1 Slight 3 Serious 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: B Page 817 of 871 Page 817 of 871 Page 817 of 871 Page 817 of 871 ---PAGE BREAK--- - 2 - 6. ACCIDENTAL RELEASE MEASURES Small Spills: Soak up with an inert absorbent and place in designated disposal container. Wash area thoroughly. Large Spills: Remove sources of ignition and ventilate area. Soak up with an inert absorbent and place in designated disposal container. Wash area thoroughly. 7. HANDLING AND STORAGE Keep away from heat, sparks, and flame. Use with adequate ventilation. Do not puncture or incinerate containers. Store as NFPA Code 30B Rating: Level 1 Aerosol. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Safety glasses or chemical splash goggles are recommended. Skin: Chemical resistant gloves are recommended. Respiratory: Not normally required. If vapor concentration exceeds TLV, use a NIOSH or MSHA approved respirator. Engineering Controls: Mechanical ventilation recommended when handling in enclosed/tight spaces. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 500°F/260°C Specific Gravity: 0.840 (H2O=1) Vapor Pressure: 68 psig Melting Point: ND Vapor Density: > 1 (air=1) Evaporation Rate: ND Solubility in Water: Slight pH: N/A Appearance and Odor: Aerosol; Brown liquid with solvent scent. 10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: When strongly heated, as in a fire, this product may produce oxides of carbon. Chemical Stability: Stable Incompatibility: Oxidizing agents such as bleach. 11. TOXICOLOGICAL INFORMATION Carcinogenicity (NTP/IARC/OSHA): None California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? None 12. ECOLOGICAL INFORMATION ND 13. DISPOSAL CONSIDERATIONS Consult your local, state, provincial and federal regulations for proper disposal guidelines. Do not puncture or incinerate containers. Disposal regulations may be different for each state and/or locality. 14. TRANSPORT INFORMATION DOT: Available upon request TDG: Available upon request UN: Availabale upon request 15. REGULATORY INFORMATION VOC (Volatile Organic Compounds): 3.34% TSCA (Toxic Substances Control Act): Listed SARA Title III Section 302 EHS: None SARA Title III Section 311/312: ND SARA Title III Section 313 Toxic Chemicals: None WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 101 MOISTURE BARRIER PREPARED BY: TechDept.AD Page 818 of 871 Page 818 of 871 Page 818 of 871 Page 818 of 871 ---PAGE BREAK--- - 1 - UNITED 107 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 107 AEROSOL SAFETY SOLVENT Multi Purpose Cleaner February 21, 2012 HMIS III HEALTH (0 = Maximum Safety) *2 PHYSICAL HAZARD (0 = Maximum Safety) 0 Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 FLAMMABILITY (0 = Maximum Safety) 2 2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) Trichloroethylene 79-01-6 > 90 10 ppm 100 ppm NE NE Carbon Dioxide 124-38-9 3 - 5 5,000 ppm 5,000 ppm NE NE ACGIH (STEL) Trichloroethylene CAS#79-01-6 25 ppm, Carbon Dioxide CAS #124-38-9 30,000 ppm 3. HAZARDS IDENTIFICATION Eyes: May cause slight irritation. Skin: May cause irritation. Prolonged or repeated contact can result in defatting and drying of the skin, irritation and dermatitis. Inhalation: Intentional misuse by inhaling the product can be harmful or fatal. High concentrations or prolonged exposure to lower concentrations may be irritating to mucous membranes. Ingestion: Exposure by ingestion of an aerosol is unlikely. May cause delayed lung damage. Components of the product may be absorbed into the body by ingestion. Chronic Effects: May cause central nervous system disorder and/or damage. May cause delayed lung damage. Prolonged skin contact may defat the skin and produce dermatitis. 4. FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops or persists. Skin: Wash off with warm water and soap. Get medical attention if irritation develops or persists. Inhalation: Move to fresh air. Oxgen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled to substance. Call a physician if develop or persist. Ingestion: If material is ingested, immediately contact a poison control center. Rinse mouth. Do not induce vomiting without advice from poiso control center. If vomiting occurs naturally, have vixtim lean forward to reduce risk of aspiration. 5. FIRE FIGHTING MEASURES Flash Point (TCC): Not flammable & not combustible by OSHA Explosive Limits: Lower (LEL): 7.3 Upper (UEL): 36.0 Flame Projection (Aerosol): Non-flammable per 16 CFR 1500.3 and 1500.45. Hazardous Products of Combustion: Material decomposed by fire may produce irritating, corrosive and/or toxic gases. Fire and Explosion Hazards: Exposure to temperature above 130°F/ 54.4°C may cause container to burst, rupture, or vent. Containers should be cooled with water to prevent vapor pressure build up. Runoff to sewer may cause fire or explosion hazard. Extinguishing Media: Water, Water fog, Foam, Dry chemical, Carbon dioxide. Fire Fighting Instructions: Wear self-contained breathing apparatus and protective clothing. Cool fire exposed containers to prevent rupturing. MATERIAL SAFETY DATA SHEET 320 37th Avenue, St. Charles, Illinois 60174 To Reorder Call: www.unitedlabsinc.com . www.unitedlabsinc.ca [PHONE REDACTED] Always follow Label Directions and Cautions. * Chronic 2 Moderate 4 Severe 1 Slight 3 Serious 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: X Consult Supervisor Page 819 of 871 Page 819 of 871 Page 819 of 871 Page 819 of 871 ---PAGE BREAK--- - 2 - 6. ACCIDENTAL RELEASE MEASURES Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated surface thoroughly. After removal flush contaminated area thoroughly with water. Large Spills: Ventilate area and remove all sources of ignition. Cover with absorbent material like vermiculite, sand or earth to soak up product and place in a disposal container. Clean contaminated surface thoroughly. Prevent entry into waterways, sewers or confined spaces. 7. HANDLING AND STORAGE Store in a cool, dry place away from heat, sparks or open flame. Do not store at temperatures above 49°C/ 120°F. Keep out of sunlight. Contents under pressure. Do not puncture, incinerate or crush. For Industrial and Institutional use only. NFPA Code 30B Rating: Level 1 Aerosol. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Chemical safety googles are recommended. Skin: Chemical resistant gloves are recommended. Wear appropriate chemical resistant clothing. Respiratory: None needed for proper use in accordance with label directions. If recommended exposure limits are exceeded wear a NIOSH approved respirator with mechanical filter/organic vapor cartridge. Engineering Controls: Insure adequate ventilation, especially in confined areas. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 186.8°F/ 86.1°C Specific Gravity: 1.47 (H2O=1) Vapor Pressure: 72-91 psig@70°F Melting Point: Concentrate -86°C Vapor Density: > 1 Evaporation Rate: ND Solubility in Water: Negligible pH: NA Appearance and Odor: Aerosol, clear, colorless, liquid with ether-like odor. 10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: Material decomposed by fire may produce irritating and/or toxic gases. Chemical Stability: Stable Incompatibility: Oxidizing agents, heat, flames and sparks. 11. TOXICOLOGICAL INFORMATION Carcinogenicity (NTP/IARC/OSHA): Trichloroethylene CAS# 79-01-6 California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? Yes – Trichloroethylene CAS# 79-01--6 12. ECOLOGICAL INFORMATION Components of this product are hazardous to aquatic life. 13. DISPOSAL CONSIDERATIONS Consult your local, state and federal regulations for proper disposal guidelines. Do not puncture or incinerate containers. Disposal regulations may be different for each state and/or locality. Waste codes: D040: Waste Trichloroethylene 14. TRANSPORT INFORMATION DOT: Available upon request TDG: Available upon request UN: Availabale upon request 15. REGULATORY INFORMATION VOC (Volatile Organic Compounds): 96.60 % TSCA (Toxic Substances Control Act): Listed SARA Title III Section 302 EHS: No SARA Title III Section 311/312: Yes SARA Title III Section 313 Toxic Chemicals: Trichloroethylene CAS# 79-01-6 (0.97 lb.)* * Pounds of reportable material per can of UNITED product. WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 107 AEROSOL SAFETY SOLVENT PREPARED BY: Sandy Kopacz Page 820 of 871 Page 820 of 871 Page 820 of 871 Page 820 of 871 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 320 37th Avenue • St. Charles, Illinois 60174 • To Reorder, Call [PHONE REDACTED] PRODUCT IDENTIFICATION USE / DESCRIPTION REVISION DATE FOR MEDICAL AND UNITED 190 Acoustical Ceiling Tile Whitener March 17, 2003 TRANSPORTATION EMERGENCIES: UP WHITE INFOTRAC: [PHONE REDACTED] HEALTH (0 = Maximum Safety) REACTIVITY (0 = Maximum Safety) Always follow Label Directions and Cautions. Susceptible to Release of Energy. 4 Extreme. 3 High. 2 Moderate. 1 Slight. 0 Minimal. See Health Hazard Data Section of this M.S.D.S. for more detailed information. FLAMMABILITY (0 = Maximum Safety) Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated to burn. 3 Ignites at normal temperature. 0 Will not burn. 2 Ignites when moderately heated. HAZARDOUS CAS ACGIH ACGIH OSHA OTHER S.A.R.A. TITLE III COMPONENTS NUMBER TWA STEL PEL RECOMMENDED LIMITS QUANTITIES Isopropanol 67-63-0 400 ppm 500 ppm 400 ppm NIOSH TWA 400 ppm None 983 mg/m3 1,230 mg/m3 980 mg/m3 980 mg/m3 Propane 74-98-6 2,500 ppm Not 1,000 ppm NIOSH TWA 1,000 ppm None 4,508 mg/m3 established 1,800 mg/m3 1,800 mg/m3 Isobutane 75-28-5 Not Not Not NIOSH TWA 800 ppm None established established established 1,900 mg/m3 Trichloroethylene 79-01-6 50 ppm 100 ppm 100 ppm NIOSH TWA 25 ppm 0.263* 269 mg/m3 537 mg/m Acetone 67-64-1 500 ppm 750 ppm 1,000 ppm NIOSH TWA 250 ppm None 1,188 mg/m3 1,782 mg/m3 590 mg/m3 Paraffinic Naphthenic 64742-47-8 Not Not Not None None Solvent established established established * Pounds of reportable material per can of UNITED product. BOILING POINT SPECIFIC GRAVITY (H20 = 1) Not determined 1.123 VAPOR PRESSURE (PSIg) MELTING POINT (At 25° C) 55 Not determined VAPOR DENSITY (Air = 1) EVAPORATION RATE Greater than 1.0. (Butyl Acetate = 1) Less than 1.0 SOLUBILITY IN WATER VOLATILE ORGANIC COMPOUNDS Insoluble (Pounds Per Can Of Product) 0.43 APPEARANCE AND ODOR pH: Spray with sweet etheral odor. Not applicable FLASH POINT (Method Used) FLAMMABLE LIMITS LEL UEL Flame projection: Flammable (Greater than 18 inches) Not determined Not determined Not determined EXTINGUISHING MEDIA Carbon dioxide, foam, dry chemical, Halon. SPECIAL FIRE FIGHTING PROCEDURES Keep containers cool with water spray. Do not allow runoff to enter lakes, ponds, sewers or public water courses. Use equipment or shielding required to protect personnel against rupturing, bursting or venting containers. Firefighters should wear full protective equipment and NIOSH approved self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS Exposure to temperatures over 120°F may cause bursting or venting. Heat or fire may cause hazardous fumes: Carbon Monoxide, Phosgene, Chlorine and Hydrogen Chloride. 4 May detonate-vacate area if 2 Violent chemical change Materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. PERSONAL PROTECTION UNITED 190 HAZARDOUS COMPONENTS IDENTITY, EXPOSURE LIMITS AND S.A.R.A. TITLE III INFORMATION PHYSICAL / CHEMICAL CHARACTERISTICS FIRE AND EXPLOSION HAZARD DATA 0 2 3 PAGE (CONTINUED ON REVERSE SIDE) L A B O R A T O R I E S Page 821 of 871 Page 821 of 871 Page 821 of 871 Page 821 of 871 ---PAGE BREAK--- STABILITY: STABLE X CONDITIONS TO AVOID UNSTABLE X Temperatures above 120°F. INCOMPATIBILITY (Materials To Avoid) Oxidizing materials. HAZARDOUS DECOMPOSITION OR BY PRODUCTS Open flames can cause thermal degradation with the evolution of carbon monoxide, hydrogen chloride, phosgene and chlorine. HAZARDOUS POLYMERIZATION:WILL NOT OCCUR X CONDITIONS TO AVOID MAY OCCUR X Avoid sources of heat. HEALTH HAZARDS EYES: May cause pain, irritation, redness, slight corneal injury SKIN: May cause drying or flaking, irritation, burning sensation INHALATION: Prolonged exposure may cause dizziness, nausea, headache, upper respiratory discomfort. IF SWALLOWED: May cause upset stomach, nausea, vomiting, headache, diarrhea. CARCINOGENICITY: Trichloroethylene NTP? No IARC MONOGRAPHS? Yes OSHA REGULATED? No This product contains a chemical known to the state of California to cause cancer or reproductive toxicity? Yes SIGNS AND OF OVEREXPOSURE EYES: Pain, irritation, redness SKIN: Burning sensation INHALATION: Dizziness, nausea, headache, respiratory discomfort, irregular heartbeat IF SWALLOWED: Upset stomach, vomiting, nausea, headache, diarrhea TARGET ORGANS: Central nervous system, heart, liver, skin, eyes MEDICAL CONDITIONS GENERALLY AGGRAVATED BY OVEREXPOSURE Skin sensitivity, chemical allergies, heart condition EMERGENCY AND FIRST AID PROCEDURES EYES: Flush with plenty of cool water for at least 15 minutes while holding eyelids open.. Call a physician or poison center. SKIN: Wash with soap and water. If irritation persists, call a physician or poison center. Remove contaminated clothing. INHALATION: Remove to fresh air. Apply CPR as needed. Call a physician or poison center immediately. IF SWALLOWED: DO NOT induce vomiting. Call a physician or poison center immediately. Note to Physician: If lavage is performed, suggest endotracheal and/or esophageal control. Do not administer sympathomimetic drugs unless absolutely necessary. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Small spills: Mop up, soak up immediately. Remove to out of doors. Large spills: Evacuate area. Remove all sources of ignition. Contain liquid; transfer to closed metal containers. Keep out of water supply. WASTE DISPOSAL METHOD Consult local, state, and federal authorities for proper disposal guidelines. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Store in cool, dry, well ventilated area away from heat, sparks or open flame. Exposure to temperatures above 120°F may cause bursting. Keep out of reach of children. NFPA 30B Storage Level: I RESPIRATORY PROTECTION (Specify Type) If TLV is exceeded, use NIOSH approved respirator. VENTILATION: MECHANICAL (General) LOCAL EXHAUST Provide adequate ventilation Provide adequate ventilation PROTECTIVE GLOVES EYE PROTECTION Rubber gloves Safety glasses OTHER PROTECTIVE CLOTHING OR EQUIPMENT Long sleeves WORK HYGENIC PRACTICES Wash hands and face with soap and water after using this product. REACTIVITY DATA HEALTH HAZARD DATA PRECAUTIONS FOR SAFE HANDLING AND USE CONTROL MEASURES FOR USE WHERE SIGNIFICANT EYE, SKIN OR INHALATION EXPOSURE IS LIKELY PAGE UNITED 190 UP WHITE Page 822 of 871 Page 822 of 871 Page 822 of 871 Page 822 of 871 ---PAGE BREAK--- - 1 - UNITED 555 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 555 DUO-ZYME™ Earth Smart® Enzyme Treatment for Drain System May 16, 2013 Maintenance and All-Purpose Cleaning HMIS III HEALTH (0 = Maximum Safety) 0 PHYSICAL HAZARD (0 = Maximum Safety) 0 Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 FLAMMABILITY (0 = Maximum Safety) 0 2. COMPOSITION/INFORMATION ON INGREDIENTS In accordance with Federal Regulation 29 CFR 1910.1200, all materials in this product are considered non-hazardous. 3. HAZARDS IDENTIFICATION Eyes: May cause irritation. Skin: Prolonged or repeated contact may cause irritation. Inhalation: No affect from routine use. When heated, mists of this product may irritate nasal passages. Ingestion: Large quantities (more than a few ounces) may cause upset stomach, diarrhea, nausea, and vomiting. 4. FIRST AID MEASURES Eyes: Immediately flush with plenty of water for at least 15 minutes. If develop, seek medical attention. Skin: Wash with soap and plenty of water. If develop, seek medical attention. Inhalation: Remove patient to fresh air. If develop, seek medical attention. If not breathing, give artificial respiration. Ingestion: DO NOT induce vomiting. Immediately rinse mouth and drink plenty of water. Get medical attention immediately. 5. FIRE FIGHTING MEASURES Flash Point (TCC): None Explosive Limits: Lower (LEL): ND Upper (UEL): ND Flame Projection (Aerosol): NA Hazardous Products of Combustion: When strongly heated, as in a fire, this product may produce oxides of nitrogen and carbon. Fire and Explosion Hazards: None known. Extinguishing Media: Use any means for extinguishing surrounding fires. Dry chemical, Dry foam, Carbon dioxide, Water. Fire Fighting Instructions: Wear self-contained breathing apparatus w/full protective clothing. 6. ACCIDENTAL RELEASE MEASURES Small Spills: This product is biodegradable. Flush to sewage drain. This product may cause slippery conditions; rinse thoroughly. Large Spills: This product is biodegradable. Flush to sewage drain. This product may cause slippery conditions; rinse thoroughly. MATERIAL SAFETY DATA SHEET 320 37th Avenue, St. Charles, Illinois 60174 To Reorder Call: www.unitedlabsinc.com . www.unitedlabsinc.ca [PHONE REDACTED] Always follow Label Directions and Cautions. * Chronic 2 Moderate 4 Severe 1 Slight 3 Serious 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Susceptibility of Material to Burning. 4 Extremely flammable 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: B Page 823 of 871 Page 823 of 871 Page 823 of 871 Page 823 of 871 ---PAGE BREAK--- - 2 - 7. HANDLING AND STORAGE Keep this product in a properly labeled, closed container. Store in a cool, dry, ventilated area away from sources of heat and incompatibilities. Do not allow this product to freeze. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Safety glasses are recommended. Skin: Chemical resistant gloves are recommended for prolonged exposure. Respiratory: Normally not required. Engineering Controls: Mechanical ventilation recommended when handling in enclosed/tight spaces. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 212°F/100°C Specific Gravity: 0.990 (H2O=1) Vapor Pressure: 17.5 mmHg Melting Point: ND Vapor Density: ND Evaporation Rate: 1 (Water=1) Solubility in Water: Soluble pH: 7-8 Appearance and Odor: Light green color liquid with light Cimarron (cinnamon-like) scent or Newberry scent. 10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: When strongly heated, as in a fire, this product may produce oxides of nitrogen and carbon. Chemical Stability: Stable Incompatibility: Oxidizers such as bleach. 11. TOXICOLOGICAL INFORMATION Carcinogenicity (NTP/IARC/OSHA): None California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? None 12. ECOLOGICAL INFORMATION ND 13. DISPOSAL CONSIDERATIONS This product is biodegradable. Consult your local, state, provincial and federal regulations for proper disposal guidelines. Disposal regulations may be different for each state and/or locality. 14. TRANSPORT INFORMATION DOT: For Ground shipping within the US: Nonhazardous - Cleaning, scouring or washing compounds, or soaps. TDG: Ocean shipping: Nonhazardous - Cleaning, scouring or washing compounds, or soaps. UN: Availabale upon request 15. REGULATORY INFORMATION VOC (Volatile Organic Compounds): None TSCA (Toxic Substances Control Act): Listed SARA Title III Section 302 EHS: None SARA Title III Section 311/312: No SARA Title III Section 313 Toxic Chemicals: None WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/WHMIS) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 555 DUO-ZYME™ PREPARED BY: Sandy Kopacz Page 824 of 871 Page 824 of 871 Page 824 of 871 Page 824 of 871 ---PAGE BREAK--- SAFETY DATA SHEET State Chemical Division – State Industrial Products 5915 Landerbrook Drive, Mayfield Heights, Ohio 44124-4034 – (866) 747-2229 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: UVP-500 24 Hour Emergency CHEMTREC Number: [PHONE REDACTED] Product Description: Repair material. MSDS Number: 119937 2. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredients CAS Number Weight ACGIH OSHA Syrene Monomer 100-42-5 < 22% 20 ppm 100 ppm 3. HAZARDS IDENTIFICATION ***EMERGENCY OVERVIEW*** May cause eye and skin irritation. May be harmful if swallowed. POTENTIAL HEALTH EFFECTS Eye Contact: May cause eye irritation, blurred vision, tearing and redness. Skin Contact: May cause skin irritation. Inhalation: May cause respiratory tract irritation, headache, dizziness, difficulty in breathing. Ingestion: May be harmful if swallowed. May cause nausea, vomiting, diarrhea, mucous membrane irritation. 4. FIRST AID MEASURES Eye Contact: flush with a large amount of water for at least 15 minutes. If irritation persists, consult a physician. Skin Contact: wash with soap and water and rinse thoroughly. Remove contaminated clothing and launder before reuse. If irritation persists, consult a physician. Inhalation: Remove to fresh air. If irritation persists, consult a physician. Ingestion: Give two glasses of water. Do not induce vomiting. Never give anything to an unconscious person. Contact a physician immediately. 5. FIRE FIGHTING MEASURES Flashpoint: 150ºF [65.6ºC] PMCC Lower Explosive Limit(LEL): 0.9 Upper Explosive Limit(UEL): 6.8 Autoignition Temperature: 410ºF [210ºC] Flammable Properties: Flammable liquid and vapor. May accumulate static electricity. Contact with strong oxidizers may cause fire. Sealed containers may rupture when heated. Above the flashpoint explosive vapor-air mixtures may be formed. Vapors can flow along surfaces to distant ignition source and flash back. Sensitive to static discharge. Extinguishing Media: Carbon Dioxide, dry chemical, alcohol foam. Fire Fighting Instructions: Wear self-contained breathing apparatus and full protective clothing. Material floats on water and may travel back to an ignition source and spread fire. Water spray may be used to keep fire exposed containers cool. Do not allow water runoff to enter sewers or waterways. 6. ACCIDENTAL RELEASE MEASURES Ventilate area. Use absorbent to pick up residue and dispose of properly. Avoid discharge to natural waters. Dispose of in accordance with Federal, State and Local Regulations regarding waste disposal. 7. HANDLING AND STORAGE Handling: This product is for industrial use only. Use with adequate ventilation. Wash thoroughly after handling. Do not take internally. Harmful if swallowed. Empty product containers may contain product residue. Avoid contact with skin, eyes and clothing. Do not mix with other chemicals. Storage: Keep out of reach of children. Keep containers closed when not in use. Store in a well-ventilated area away from all sunlight and ultra violet irradiation. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering Controls: Use general or local ventilation to keep exposure levels below exposure limits. Personal Protective Equipment: Respiratory: Local or general exhaust is adequate. Eye: Wear approved safety glasses or goggles with unperforated sideshields. Skin: Wear chemically impervious gloves for prolonged or repeated contact. Other: An emergency eyewash station or source of clean potable water should be available in case of accidental eye contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Sticky resin. Odor: Styrene Physical State: Sheet. pH: NA Boiling Point: NA Freezing/Melting Point: NA Solubility in Water: Insoluble. Specific Gravity: ~1800 Kg/m3 VOC Content: 100 – 200 g/L Vapor Pressure @ 72 ºF [ 22 ºC 5 mm Hg 10. STABILITY AND REACTIVITY Stability: This material will harden irreversibly on exposure to ultra violet irradiation and this reaction is exothermic. Hazardous Polymerization: May occur under fire conditions or if contaminated. Conditions to Avoid: Keep away from sources of ignition. Incompatibility: Strong oxidizers. Hazardous Decomposition Products: Carbon Dioxide, Carbon Monoxide. Page 825 of 871 Page 825 of 871 Page 825 of 871 Page 825 of 871 ---PAGE BREAK--- 11. TOXICOLOGICAL INFORMATION IARC / NTP / OSHA: Styrene is classified as an IARC 2B Possible Carcinogen. Hazardous Ingredients CAS Number LD50 LC50 Syrene Monomer 100-42-5 5000 mg/kg (oral rat) 2770 ppm/4 hr (rat) 12. ECOLOGICAL INFORMATION NA 13. DISPOSAL CONSIDERATIONS Do not reuse empty containers. Dispose of in accordance with the Federal, State, and Local regulations regarding pollution and waste disposal. 14. TRANSPORT INFORMATION DOT Shipping Data: Not regulated. Canadian TDG: Not available for sale in Canada. 15. REGULATORY INFORMATION TSCA: All ingredients in this product are listed or exempt from listing on the TSCA Chemical Inventory. CEPA: All ingredients in this product are listed or exempt from listing on the Canadian DSL/NDSL. Proposition 65: This product contains no chemicals known to the state of California to cause cancer, birth defects or other reproductive harm. SARA 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40CFR372): Syrene Monomer 100-42-5 < 22% HMIS Rating: HEALTH = 2 FLAMMABILITY = 1 REACTIVITY = 1 PPE = B WHMIS Rating: Not available for sale in Canada. 16. OTHER INFORMATION NA = Not Available or Not Applicable NE = Not Established Read and follow all label directions and precautions before using the product. This product is intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF THE REACH OF CHILDREN. While we believe that the data contained herein is factual and the opinions expressed are those of qualified experts, the data are not to be taken as a warranty or representation for which the company assumes legal responsibility. They are offered solely for your consideration, investigation, and verification. Any use of these data and information must be determined by the user to be in accordance with applicable Federal, State, and Local Laws and regulations. HEALTH AND SAFETY INFORMATION: (216) 861-7114 Prepared On: March 2014 Replaces: March 2011 Completed By: Regulatory Affairs Page 826 of 871 Page 826 of 871 Page 826 of 871 Page 826 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 11-Mar-2013 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 83840 Product name Vinylize Recommended Use Cleaner Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Skin contact. Skin absorption. Inhalation. Eyes. Potential health effects Eyes Exposure to vapors or mists may cause the following effects:. Irritation. Pain. Tearing. Reddening. Swelling. Stinging sensation. Feeling like that of fine dust in the eye. Skin Repeated or prolonged exposure may cause:. Defatting. Skin Irritation. Dermatitis. Chronic exposure causes drying effect on the skin . Inhalation Long-term exposure may cause the following effects:. Headaches. Dizziness. Nausea. Decreased blood pressure. Changes in heart rate. Cyanosis. Harmful by inhalation. Ingestion Harmful or fatal if swallowed. Can burn mouth, throat, and stomach. Severe tissue damage. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Propane/Isobutane/N- Butane 68476-86-8 7-13 1-Butoxy-2-propanol 5131-66-8 3-7 4. FIRST AID MEASURES Eye contact Flush eyes with plenty of water. Seek medical attention if irritation persists. Skin contact Wash area thoroughly with soap and water. Remove and wash contaminated clothing before re-use. Seek medical attention immediately. Ingestion Seek medical attention immediately. Do Not induce vomiting. Give victim a glass of water or milk. Call a physician or Poison Control Center immediately. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Immediate medical attention is required. 5. FIRE FIGHTING MEASURES Flash point °C -104 Flash point °F -156 Method Pensky-Martens C.C. Autoignition temperature °C Not Applicable Autoignition temperature °F Not Applicable Flammability Limits in Air) Upper 9.5 Lower 1.1 Suitable extinguishing media Water fog. Dry chemical. Carbon dioxide (CO2). Foam. Alcohol foam. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fire and Explosion Hazards Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Empty containers contain residue and/or vapors. Do not weld, cut, pressurize, braze, solder, drill, grind, or expose such containers to heat, sparks, flame, static electricity, or other sources of ignition. They may explode and cause injury or death. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat . Page 1 / 3 Emergency Overview May cause irritation of respiratory tract. Irritating to eyes. Vapors may cause flash fire or explosion. Page 827 of 871 Page 827 of 871 Page 827 of 871 Page 827 of 871 ---PAGE BREAK--- Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Place in suitable container for disposal as hazardous waste. 7. HANDLING AND STORAGE Handling Thoroughly wash hands and exposed skin after handling. Remove and wash contaminated clothing before re-use. Keep in a well-ventilated place. Use only according to label directions. Avoid contact with skin, eyes and clothing. Avoid breathing vapors from heated material . Storage Containers exposed to extreme heat may burst. Keep away from heat and sources of ignition. Do not freeze. NFPA Storage Code Store as Level 1 Aerosol (NFPA 30B) 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) 1-Butoxy-2- propanol - - - - Propane/Isob utane/N- Butane - - - N/D Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Use in a well ventilated area. Hygiene measures Wash hands before eating or using the washroom. Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes and clothing. Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Protection provided by air purifying respirators is limited. Use a positive pressure supplied air respirator. if there is any potential for an uncontrolled release:. where exposure levels are not known. or other circumstances where an air purifying respirator (P100) may not provide adequate protection . Hand Protection For prolonged or repeated skin contact, use a chemically resistant glove such as nitrile or neoprene. Wash hands with soap and water after removing gloves. Dry hands thoroughly before re-applying gloves. . Eye protection Use safety eyewear designed to protect against splash of liquids. Safety glasses with side-shields. Skin and body protection Rubber or plastic boots. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Clear / Light yellow Odor Mint-like Odor Threshold No information available pH 11 Specific Gravity 0.9624 Vapor pressure 214 kPa Vapor density >Air Evaporation Rate >1 (Butyl Acetate = 1) Water solubility Soluble in water VOC Content 6.98%; 68 gm/liter; 0.56 lbs/gal Partition Coefficient (n-octanol/water) Not Applicable Boiling point/range °C -41 - 170 Boiling point/range °F -43 - 338 Melting point/range °C 0 Melting point/range °F 32 Flash point °C -104 Flash point °F -156 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions. Conditions to avoid Avoid sources of ignition. Avoid open flames. Do not use near welding arcs. Incompatability Strong acids. Alkalies. Oxidizers. Amines. Page 2 / 3 Product code 83840 Product name Vinylize Page 828 of 871 Page 828 of 871 Page 828 of 871 Page 828 of 871 ---PAGE BREAK--- Hazardous Decomposition Products Carbon oxides. Nitrogen oxides (NOx). Chlorides. Chlorine. phosgene. Polymerization Hazardous polymerization does not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) 1-Butoxy-2- propanol 5131-66-8 5660 µL/kg 3100 mg/kg - Propane/Isobutan e/N-Butane 68476-86-8 - - - Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity See Section 2 . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects See Section 2 Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns 1-Butoxy-2- propanol Not Listed Not Listed Not Listed Not Listed Not Listed Propane/Isob utane/N- Butane Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT UN1950 Aerosols, flammable, 2.1. Exception: (Compressed Gas not more than 1.0L) Consumer Commodity ORM-D TDG UN1950 AEROSOLS, flammable, 2.1 15. REGULATORY INFORMATION State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 1-Butoxy-2-propanol Not Listed Not Listed Not Listed Propane/Isobutane/N- Butane Not Listed Not Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA 1-Butoxy-2-propanol X X - X Propane/Isobutane/N- Butane X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION HMIS Health - 1 Flammability - 4 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 3 / 3 Product code 83840 Product name Vinylize Page 829 of 871 Page 829 of 871 Page 829 of 871 Page 829 of 871 ---PAGE BREAK--- Waterplug® 1. Product and Company Information Company: Thoro Consumer Products BASF Construction Chemicals, LLC 23700 Chagrin Blvd. Cleveland, Ohio 44122 Telephone: (216) 839-7171 or (866) 518-7171 Emergency telephone: (800) 424-9300 (703) 527-3887 (Outside continental U.S.) Product name: Waterplug® 2. Hazardous Ingredients 3. Hazards Identiﬁ cation Chemical CAS Number TLV STEL PEL CEIL Weight % Alumina cement 65997-16-2 N.E. N.E. N.E. N.E. 30.00-60.00 % Portland cement 65997-15-1 10 mg/m3 N.E. 5 mg/m3 N.E. 15.00-40.00 % Silica, quartz 14808-60-7 .05 mg/m3 N.E. .1 mg/m3 N.E. 10.00-30.00 % Iron oxide 1309-37-1 5 mg/m3 N.E. 10 mg/m3 N.E. 0.00-5.00 % Calcium hydroxide 1305-62-0 5 mg/m3 N.E. 5 mg/m3 N.E. 1.00-5.00 % Limestone, calcium 471-34-1 5 mg/m3 N.E. 5 mg/m3 N.E. 0.00-5.00 % carbonate Limestone 1317-65-3 5 mg/m3 N.E. 5 mg/m3 N.E. 0.00-5.00 % 7778-18-9 10 mg/m3 N.E. 5 mg/m3 N.E. 0.00-5.00 % HMIS® rating: Health Flammability Reactivity 2* 0 1 WHMIS class: D2B E Primary routes of entry: Inhalation Eye contact Skin contact Effects of Overexposure Inhalation: Inhalation of dust can cause coughing and labored breathing and possible temporary but reversible irritation on mucous membranes and respiratory tract. Skin: Can cause slight to moderate irritation due to abrasive action. In combination with water, repeated or prolonged dermal exposure can cause moderate to severe alkali burns. Material Data Safety Sheet July 2007 page 1 of 6 Page 830 of 871 Page 830 of 871 Page 830 of 871 Page 830 of 871 ---PAGE BREAK--- Waterplug® Eyes: Can cause severe irritation, redness, tearing and blurred vision. Prolonged or repeated contact can cause burns and possibly corneal injury. Ingestion: Irritating to mouth, throat, and stomach. Chronic Exposure: This product contains (quartz) silica which has been listed as a human carcinogen by NTP (Group 1) and IARC (Human Carcinogen) and a Suspected Human Carcinogen by ACGIH (category A2). Repeated or prolonged overexposure to free respirable silica can cause silicosis or other delayed and serious lung injury. Repeated or prolonged overexposure to free respirable silica can cause silicosis or other delayed and serious lung injury. Carcinogenicity ACGIH IARC NTP OSHA Alumina cement N.E. N.E. N.E. N.E. Portland cement N.E. N.E. N.E. N.E. Silica, quartz Suspected human carcinogen Human carcinogen Known carcinogen N.E. Iron oxide Not classiﬁ able as Classiﬁ cation not N.E. N.E. human carcinogen possible from current data Calcium hydroxide N.E. N.E. N.E. N.E. Limestone, calcium carbonate N.E. N.E. N.E. N.E. Limestone N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. 4. First Aid Measures Eye contact: Flush eyes with water, lifting upper and lower lids occasionally for 15 minutes. Seek medical attention. Skin contact: Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Seek medical advice. Ingestion: Do not induce vomiting without medical advice. If conscious, drink plenty of water. Call a physician immediately. Never give anything by mouth to an unconscious person. If a person vomits, place him/her in the recovery position. Inhalation: Remove victim from exposure. If difﬁ culty breathing, administer oxygen. If breathing has stopped, administer artiﬁ cial respiration, preferably mouth-to-mouth. Seek immediate medical attention. 5. Fire-Fighting Measures Flash point: Not combustible. Autoignition temperature: Not combustible Lower explosion limit: Not applicable. Suitable extinguishing media: Water fog Carbon dioxide (CO2) Upper explosion limit: Not applicable. Dry chemical Alcohol-resistant foam Fire and explosion hazards: This product is alkaline and releases considerable heat on contact with small amounts of water. Avoid contact between resulting hot alkaline paste and metallic aluminum. Such contact could generate hydrogen gas. Special ﬁ re-ﬁ ghting procedures: As in any ﬁ re, wear self-contained breathing apparatus pressure-demand (MSHA/NIOSH approved or equivalent) and full protective gear. Material Data Safety Sheet July 2007 page 2 of 6 Page 831 of 871 Page 831 of 871 Page 831 of 871 Page 831 of 871 ---PAGE BREAK--- Waterplug® 6. Accidental Release Measures Methods for cleaning up: Clean up by sweeping or vacuum. Clean thoroughly. After cleaning, ﬂ ush away traces with water. Keep in suitable, closed containers for disposal. Wear personal protective equipment. 7. Handling and Storage Handling: Use only in area provided with appropriate ventilation. Keep out of reach of children. Avoid exceeding of the given occupational exposure limits (see section Avoid formation of respirable particles. Storage: Keep container closed. 8. Exposure Controls / Personal Protection Eye protection: Wear as appropriate - Safety glasses with side-shields Face-shield Goggles Hand protection: Wear as appropriate - Impervious gloves Body protection: Wear as appropriate - Preventive skin protection Impervious clothing Respiratory protection: In case of insufﬁ cient ventilation, wear suitable respiratory equipment. When workers are facing concentrations above the exposure limit, they must use appropriate certiﬁ ed respirators. Hygienic practices: Avoid contact with skin, eyes and clothing. Ensure adequate ventilation, especially in conﬁ ned areas. Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. When using, do not eat, drink or smoke. Engineering controls: Local exhaust ventilation can be necessary to control any air contaminants to within their TLVs during the use of this product. 9. Physical and Chemical Properties Color: Gray Physical state: Powder Odor: None pH (at 100%): Not applicable Odor threshold: No data available Vapor pressure: Not applicable Vapor density: Not applicable Boiling point/range: No data available Freeze point: No data available Water solubility: soluble Speciﬁ c gravity: No data available Viscosity: No data available Evaporation rate: No data available Partition coefﬁ cient: No data available (n-octanol water) VOC Concentration as applied (less water and exempt solvents): 0 g/l Material Data Safety Sheet July 2007 page 3 of 6 Page 832 of 871 Page 832 of 871 Page 832 of 871 Page 832 of 871 ---PAGE BREAK--- Waterplug® 10. Stability and Reactivity Stability: Stable under recommended storage conditions. Conditions to avoid: No data available. Materials to avoid: Strong acids and strong bases Strong oxidizing agents Hazardous decomposition products: No data available. Hazardous polymerization: Will not occur under normal conditions. 11. Toxicological Information Type Value Species Exposure Time Acute inhalation toxicity Product LC50 No data available Component Alumina cement LC50 No data available Portland cement LC50 No data available Silica, quartz LC50 No data available Iron oxide LC50 0.96 mg/l 4 h Calcium hydroxide LC50 No data available Limestone, calcium carbonate LC50 No data available Limestone LC50 No data available LC50 No data available Acute oral toxicity Product LD50 (Oral) No data available Component Alumina cement LD50 (Oral) 2,255 mg/kg Portland cement LD50 (Oral) 2,000 mg/kg Silica, quartz LD50 (Oral) 1,300 mg/kg Iron oxide LD50 (Oral) 3,700 mg/kg Calcium hydroxide LD50 (Oral) 7,340 mg/kg rat Limestone, calcium carbonate LD50 (Oral) No data available Limestone LD50 (Oral) 6,450 mg/kg rat LD50 (Oral) No data available Acute dermal toxicity Product LD50 (Dermal) No data available Component Alumina cement LD50 (Dermal) No data available Portland cement LD50 (Dermal) No data available Silica, quartz LD50 (Dermal) No data available Iron oxide LD50 (Dermal) 3,100 mg/kg Calcium hydroxide LD50 (Dermal) 2,520 mg/kg Limestone, calcium carbonate LD50 (Dermal) No data available Limestone LD50 (Dermal) No data available LD50 (Dermal) No data available Material Data Safety Sheet July 2007 page 4 of 6 Page 833 of 871 Page 833 of 871 Page 833 of 871 Page 833 of 871 ---PAGE BREAK--- Waterplug® 12. Ecological Information Ecotoxicological Information: There is no data available for this product. 13. Disposal Considerations Recommendations: Use excess product in an alternate beneﬁ cial application. Handle disposal of waste material in manner which complies with local, state, province and federal regulation. 14. Transportation Information DOT: Proper shipping name Not regulated IATA: Proper shipping name Not regulated 15. Regulatory Information SARA 311/312 (RTK) This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable deﬁ nitions, to meet the following categories: Immediate Health Hazard Delayed (Chronic) Health Hazard SARA 313 This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and the Reauthorization Act of 1986 and 40 CFR Part 372: Weight % CAS Number Chemical Name This product contains no chemicals subject to the SARA 313 supplier notiﬁ cation requirements. CERCLA CERCLA section 103(a) speciﬁ cally requires the person in charge of a vessel or facility to report immediately to the National Response Center (NRC) a release of hazardous substances whose amount equals or exceeds the assigned RQ. The following hazardous substances are contained in this product: RQ CAS Number Chemical Name No CERCLA chemicals exist in this product above reportable concentrations. TSCA Section 12(b) Export Notiﬁ cation This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported from the United States: CAS Number Chemical Name There are no TSCA 12(b) chemicals in this product. California Proposition 65 The chemical(s) noted below and contained in this product are known to the state of California to cause cancer, birth de- fects or other reproductive harm. Unless otherwise speciﬁ ed in Section 2 of this MSDS, these chemicals are present at CAS Number Chemical Name 14808-60-7 Silica, quartz 7439-92-1 Inorganic lead 7440-38-2 Arsenic 7439-97-6 Mercury Material Data Safety Sheet July 2007 page 5 of 6 Page 834 of 871 Page 834 of 871 Page 834 of 871 Page 834 of 871 ---PAGE BREAK--- Waterplug® 16. Other Information Legend: N.E. - Not established TLV - Threshold limit value STEL - Short term exposure limit PEL - Permissible exposure limit CEIL - Ceiling Prepared by: Environment, Health and Safety Department This information is furnished without warranty, representation, or license of any kind, except that this information is accu- rate to the best of the manufacturer’s knowledge, or is obtained from sources believed by the manufacturer to be accurate and is not intended to be all inclusive. No warranty is expressed or implied regarding the accuracy of this information or the results to be obtained from its use thereof. The manufacturer assumes no responsibility for injuries proximately caused by use of the Material if reasonable safety procedures are not followed as stipulated in this Data Sheet. Additionally, the manufacturer assumes no responsibility for injuries proximately caused by abnormal use of the Material even if reason- able safety procedures are followed. Buyer assumes the risk in its use of the Material. End of MSDS. Material Data Safety Sheet July 2007 page 6 of 6 Page 835 of 871 Page 835 of 871 Page 835 of 871 Page 835 of 871 ---PAGE BREAK--- Page 836 of 871 Page 836 of 871 Page 836 of 871 Page 836 of 871 ---PAGE BREAK--- Page 837 of 871 Page 837 of 871 Page 837 of 871 Page 837 of 871 ---PAGE BREAK--- Page 838 of 871 Page 838 of 871 Page 838 of 871 Page 838 of 871 ---PAGE BREAK--- Page 839 of 871 Page 839 of 871 Page 839 of 871 Page 839 of 871 ---PAGE BREAK--- Page 840 of 871 Page 840 of 871 Page 840 of 871 Page 840 of 871 ---PAGE BREAK--- Page 841 of 871 Page 841 of 871 Page 841 of 871 Page 841 of 871 ---PAGE BREAK--- Page 842 of 871 Page 842 of 871 Page 842 of 871 Page 842 of 871 ---PAGE BREAK--- Page 843 of 871 Page 843 of 871 Page 843 of 871 Page 843 of 871 ---PAGE BREAK--- Page 844 of 871 Page 844 of 871 Page 844 of 871 Page 844 of 871 ---PAGE BREAK--- Page 845 of 871 Page 845 of 871 Page 845 of 871 Page 845 of 871 ---PAGE BREAK--- Page 846 of 871 Page 846 of 871 Page 846 of 871 Page 846 of 871 ---PAGE BREAK--- Page 847 of 871 Page 847 of 871 Page 847 of 871 Page 847 of 871 ---PAGE BREAK--- Safety Data Sheet Windshield De-Icer PAGE 1 of 4 SECTION I - IDENTIFICATION PRODUCT NAME: Windshield De-Icer PRODUCT CODE: 95101 PRODUCT USE: Ice removal COMPANY NAME: Lawson Products, Inc. COMPANY ADDRESS: 8770 W. Bryn Mawr Suite 900, Chicago, Il 60631 COMPANY PHONE: [PHONE REDACTED] EMERGENCY PHONE: [PHONE REDACTED] SECTION II – HAZARDS IDENTIFICATION CLASSIFICATION: Flammable Aerosol: Category 1 Dissolved Gas Actue Toxicity (Oral / Inhalation / Dermal): Category 3 Skin Irritant: Category 2 Eye Irritant: Category 2b Specific Target Organ Toxicity (Single Exposure): Category 1 HAZARD STATEMENT(S): DANGER: Extremely Flammable Aerosol Contains gas under pressure; May explode if heated. Toxic if swallowed, in contact with skin, and if inhaled. Causes eye and skin irritation. Causes damage to Eyes and Central nervous system. This product contains the following percentage of chemicals of unknown toxicity: 0% PRECAUTIONARY STATEMENTS: Keep away from heat, sparks, open flames, and hot surfaces. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Protect from sunlight. Store in a well-ventilated place. Do not expose to temperatures exceeding 50°C/122°F. Wash hands thoroughly after handling. Do not eat, drink, or smoke when using this product. Wear safety glasses and protective gloves. Do not breathe mist, vapors, or spray. If on skin: Wash with plenty of water. If skin irritation occurs: Get medical advice or attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. Take off immediately all contaminated clothing and wash before reuse. If swallowed: Immediately call a poison center or doctor. Rinse Mouth. Call a poison center or doctor if exposed or you feel unwell. Use only outdoors or in a well-ventilated area. Store locked up. Dispose of contents and container in accordance with local, state, and national regulations. If in eyes: rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: get medical attention. SYMBOL: HAZARDS NOT OTHERWISE CLASSIFIED: N/A SECTION III – COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS INGREDIENT CAS NUMBER PERCENT Carbon Dioxide 124-38-9 3-7% Ethylene Glycol 107-21-1 5-10% Isopropyl Alcohol 67-63-0 1-5% Methyl Alchol 67-56-1 60-100% SECTION IV - FIRST AID MEASURES EYES: Immediately flush with water for 15 minutes while holding eyelids open. Seek immediate medical attention. INGESTION: Seek immediate medical attention. INHALATION: Move to fresh air. If breathing is difficult, administer oxygen. If not breathing administer artificial respiration or at any sign of loss of consciousness seek immediate medical attention. SKIN: Immediately wash with soap and water for 15 minutes. ACUTE HEALTH HAZARDS: Eyes: Redness and tearing Skin: Absor\pbtion of large amounts of product causes Eye and Central nervous system damage, and possibly death. Inhalation: Anesthetic, irritation, prolonged exposure may lead to unconsciousness and death. Page 848 of 871 Page 848 of 871 Page 848 of 871 Page 848 of 871 ---PAGE BREAK--- Safety Data Sheet Windshield De-Icer PAGE 2 of 4 Oral: abdominal irritation, nausea, vomiting, and diarrhea, consumption of large quantities causes Eye, Central Nervous System damage, and death CHRONIC HEALTH HAZARDS: May cause damage to the following organs: blood, kidneys, liver, mucous membranes, bone marrow, central nervous system (CNS). NOTE TO PHYSICIAN: There is no specific treatment regimen. Treatment of overexposure should be directed at the control of and the clinical condition of the patient. SECTION V – FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA: Carbon dioxide, standard chemical fire extinguisher, and water fog. UNSUITABLE EXTINGUISHING MEDIA: Water spray/stream. SPECIAL FIRE FIGHTING PROCEDURES: Wear NIOSH approved Self Contained Breathing Apparatus with a full face piece operated in a positive pressure demand mode with full body protective clothing when fighting fires. Avoid contact with skin and breathing smoke, fumes, and decomposition products. Cool fire exposed containers with water fog to prevent bursting. UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep away from sparks, open flames, and hot surfaces. No smoking. Do not spray on an open flame or other ignition source. HAZARDOUS COMBUSTION PRODUCTS: Oxides of carbon SECTION VI – ACCIDENTAL RELEASE MEASURES PERSONAL PROTECTIVE EQUIPMENT: Refer to section VIII for proper Personal Protective Equipment. SPILL: Absorb with non-combustible material like vermiculite, sand or earth and rinse with small amount of soapy water. Do not allow to drain into sewers or storm drains. Dispose of in accordance with local, state and federal regulations. WASTE DISPOSAL: Dispose of in accordance with local, state and federal regulations. RCRA STATUS: Product should be fully characterized prior to disposal (40 CFR 261). SECTION VII – HANDLING AND STORAGE HANDLING AND STORAGE: Protect from sunlight. Store in a well-ventilated place. Do not expose to temperatures exceeding 50°C/122°F. Pressurized container: Do not pierce or burn, even after use. OTHER PRECAUTIONS: Keep out of the reach of children. INCOMPATIBILITY: Strong oxidizing agents. SECTION VIII – EXPOSURE CONTROLS/PERSONAL PROTECTION HAZARDOUS INGREDIENT OSHA PEL ACGIH TLV Carbon Dioxide 5000 ppm 5000 ppm Ethylene Glycol 125 mg/m3 100 mg/m3 Isopropyl Alcohol 400 ppm 200 ppm Methyl Alchol 200 ppm 200 ppm ENGINEERING CONTROLS / VENTILATION: General ventilation and local exhaust should be adequate. RESPIRATORY PROTECTION: Wear NIOSH/MSHA approved respiratory protection if used in confined, poorly ventilated areas. PERSONAL PROTECTIVE EQUIPMENT: Safety glasses ADDITIONAL MEASURES: Wash hands thoroughly after handling. Do not breathe vapors. Do not eat, drink, or smoke while using product. Get medical attention if you feel unwell. SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear, Colorless Aerosol ODOR: Alcohol Odor ODOR THRESHOLD: N/D BOILING POINT: > 148°F (64.4°C) FREEZING POINT: N/D FLAMMABILITY: Extremely Flammable Aerosol FLASH POINT: 65°F (18°C) AUTOIGNITION TEMPERATURE: N/D Page 849 of 871 Page 849 of 871 Page 849 of 871 Page 849 of 871 ---PAGE BREAK--- Safety Data Sheet Windshield De-Icer PAGE 3 of 4 LOWER FLAMMABILITY LIMIT: N/D UPPER FLAMMABILITY LIMIT: N/D VAPOR PRESSURE (mm Hg): 89 mmHg VAPOR DENSITY (AIR=1): > 1 EVAPORATION RATE: > 1 SPECIFIC GRAVITY (H2O=1): 0.815 @ 77° F (25° C) pH: N/A SOLIDS N/D SOLUBILITY IN WATER: 100% PARTITION COEFFICIENT: n-OCTANOL/WATER (KOW): N/D VOLATILITY INCLUDING WATER 100% VOLATILE ORGANIC COMPOUNDS (VOC): 96% DIELECTRIC STRENGTH (Volts): N/A DECOMPOSITION TEMPERATURE: N/D VISCOSITY: N/D SECTION X – STABILITY AND REACTIVITY DATA REACTIVITY: None Known CHEMICAL STABILITY: Stable CONDITIONS TO AVOID: Temperatures greater than 120°F may cause bursting. INCOMPATIBILITY: Strong oxidizing agents. HAZARDOUS DECOMPOSITION OR BY-PRODUCT: Oxides of carbon POSSIBLE HAZARDOUS REACTIONS: None Known SECTION XI – TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION: Isopropyl Alcohol (67-63-0) LD50 (Oral,Rat) 5045 mg/kg; LD50 (Oral, Rabbit) 5045 mg/kg; LD50 (Dermal, Rabbit) 12,800 mg/kg; LC50 (Inhalation, Rat, 8hr) 16,000 ppm Methyl Alcohol (67-56-1) LD50 (Oral, Man) 5628 mg/kg; LD50 (Dermal, Rabbit) 20,000 mg/kg Ethylene Glycol (107-21-1) LD50 (Oral, Rat) 4700 mg/kg; LC50 (Rat, 4 hrs) > 200 mg/m3 ROUTES OF ENTRY: Eyes, Ingestion, Inhalation, Skin EYES: Causes severe irritation, redness, tearing. INGESTION: Not a likely route of exposure under normal product handling conditions. INHALATION: Acute exposure may cause nausea, vomiting, coughing and pulmonary irritation. SKIN: Causes localized defatting, irritation. MEDICAL CONDITION AGGRAVATED: Pre-existing disorders of the skin, respiratory system, and eyes will be aggravated by over exposure. ACUTE HEALTH HAZARDS: Eyes: Redness and tearing Skin: Absor\pbtion of large amounts of product causes Eye and Central nervous system damage, and possibly death. Inhalation: Anesthetic, irritation, prolonged exposure may lead to unconsciousness and death. Oral: abdominal irritation, nausea, vomiting, and diarrhea, consumption of large quantities causes Eye, Central Nervous System damage, and death CHRONIC HEALTH HAZARDS: May cause damage to the following organs: blood, kidneys, liver, mucous membranes, bone marrow, central nervous system (CNS). CARCINOGENICITY: OSHA: No ACGIH: No NTP: No IARC: No OTHER: N/A SECTION XII – ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: Isopropyl Alcohol (67-63-0) LC50 (Fathead Minnow, 96 hrs) 100,000 mg/L Methyl Alcohol (67- 56-1) LC50 (Fathead Minnow, 96hrs) 29400 mg/L The half-life of methanol in surface water ranges from 24 - 168 hrs. Ethylene Glycol (107-21-1) LC50 (Trout, 96 hrs) 41,000 mg/L; (Water Flea, 48 hrs) 46,300 mg/L; (Bluegill Fish, 96 hrs) 34,250 mg/L; (Goldfish, 72 hrs) 34,250 mg/L BIODEGRADABILITY: This product is biodegradable. BIOACCUMULATION: This product is not expected to bioaccumulate. SOIL MOBILITY: This product is mobile in soil. OTHER ECOLOGICAL HAZARDS: None Known Page 850 of 871 Page 850 of 871 Page 850 of 871 Page 850 of 871 ---PAGE BREAK--- Safety Data Sheet Windshield De-Icer PAGE 4 of 4 SECTION XIII – DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with local, state and federal regulations. RCRA STATUS: Product should be fully characterized prior to disposal (40 CFR 261). SECTION XIV - TRANSPORTATION INFORMATION PROPER SHIPPING NAME: Aerosols, Ltd. Qty. HAZARD CLASS/DIVISION: 2.1 UN/NA NUMBER: UN 1950 PACKAGING GROUP: N/A AIR SHIPMENT PROPER SHIPPING NAME: Aerosols, Ltd. Qty. HAZARD CLASS/DIVISION: 2.1 UN/NA NUMBER: UN 1950 SHIPPING BY WATER: VESSEL (IMO/IMDG) PROPER SHIPPING NAME: Aerosols, Ltd. Qty. HAZARD CLASS/DIVISION: 2.1 UN/NA NUMBER: UN 1950 ENVIRONMENTAL HAZARDS WATER: N/A SECTION XV - REGULATORY INFORMATION TSCA STATUS: All Chemicals are listed or exempt. CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): Methanol (67-56-1) Reportable Quantity = 5,000 lbs Ethylene Glycol (107-21-1) Reportable Quantity = 5,000 lbs SARA 311/312 HAZARD CATEGORIES: Fire Hazard SARA 313 REPORTABLE INGREDIENTS: Methanol (67-56-1), Ethylene Glycol (107-21-1) CLEAN WATER ACT: None STATE REGULATIONS: Isopropyl Alcohol (67-63-0) Right-to-Know acts for Rhode Island, Florida, Minnesota, Massachusetts, New Jersey, Tennesee Connecticut hazardous material survey. Isopropyl alcohol Illinois toxic substances disclosure to employee act INTERNATIONAL REGULATIONS: All components are listed or exempted. NFPA HEALTH: 3 HMIS HEALTH: 3 NFPA FLAMMABILITY: 3 HMIS FLAMMABILITY: 3 NFPA REACTIVITY: 1 HMIS REACTIVITY: 1 NFPA OTHER: None HMIS PROTECTION: B SECTION XVI - ADDTIONAL INFORMATION PREPARATION BY: Maureen Ruggeberg, Regulatory Affairs Specialist DATE PREPARED: 01/16/2014 REVISION DATE: 10/30/2014 N/A = Not Applicable; N/D = Not Determined DISCLAIMER: To the best of our knowledge, information contained herein is accurate. However there is no assumption of liability for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazard which exists. The information contained in this SDS was obtained from current and reliable sources; however, the data is provided without any warranty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of the manufacturer, the manufacturer will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this SDS shall be created or inferred by any statement in this SDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this SDS. The user is responsible for full compliance. Page 851 of 871 Page 851 of 871 Page 851 of 871 Page 851 of 871 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 11-Mar-2011 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 80924 Product name Wire Kote Recommended Use Coating Supplier Lawson Products, Inc. 1666 East Touhy Avenue Des Plaines, IL 60018 (847)-827-9666 Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known. Principal Routes of Exposure Inhalation. Eyes. Skin contact. Potential health effects Eyes May cause the following effects:. Irritation. Redness. Itching. Burning sensation. Skin Repeated or prolonged exposure may cause:. Skin Irritation. Redness. Itching. Burning sensation. Inhalation Repeated or prolonged exposure may cause the following effects. Headaches. Dizziness. Nausea. Upper respiratory tract irritation. Central nervous system effects. Loss of coordination. Extreme overexposure may cause. Possible unconsciousness. Death. Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Ingestion May be harmful if swallowed. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Propane 74-98-6 10-30 Butane 106-97-8 10-30 Toluene 108-88-3 30-60 Acetone 67-64-1 10-30 Ethyl 3-Ethoxypropionate 763-69-9 1-5 4. FIRST AID MEASURES Eye contact Flush with plenty of water for at least 15 minutes. Seek medical attention. Skin contact Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. Ingestion Do not induce vomiting. Immediate medical attention is required. Inhalation Remove from exposure. Restore breathing. Keep warm and quiet. Contact physician if breathing difficulty develops. 5. FIRE FIGHTING MEASURES Flash point °C < -17 Flash point °F < 0 Method No information available Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 12.8 Lower 1.0 Suitable extinguishing media Carbon dioxide (CO2). Dry chemical. Foam. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fire and Explosion Hazards Keep product and empty container away from heat and sources of ignition. Containers may vent or burst under extreme or prolonged fire conditions. In the event of fire and/or explosion do not breathe fumes. Contact with open flame or hot surfaces may generate toxic fumes. During emergency conditions, overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat . Page 1 / 4 Emergency Overview Flammable. Irritant. May be harmful if swallowed. Page 852 of 871 Page 852 of 871 Page 852 of 871 Page 852 of 871 ---PAGE BREAK--- Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective equipment. Methods for cleaning up Eliminate all sources of ignition. Ventilate area to maintain exposure below permissible exposure limits. Soak up with inert absorbent material. 7. HANDLING AND STORAGE Handling Ensure adequate ventilation. Turn off other sources of ignition prior to use and until all vapors have dissipated. Vapors may accumulate readily and may ignite explosively. Remove all sources of ignition. Keep away from open flame. Avoid contact with skin and eyes. Do not smoke. Check to make sure that all equipment is properly grounded and installed to satisfy electrical classification requirements. Contents under pressure. Do not puncture or incinerate. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of reach of children. Storage Store in temperatures below 120 degrees F. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Toluene 200 ppm 300 ppm 20 ppm - Acetone 1000 ppm 2400 mg/m3 - 500 ppm 750 ppm Propane 1000 ppm 1800 mg/m3 - 1000 ppm - Butane 800 ppm - 1000 ppm - Ethyl 3- Ethoxypropion ate - - - - Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. General: as necessary. Hygiene measures Wash hands before breaks and immediately after handling the product. Other precautions Avoid contact with the skin and the eyes. Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Hand Protection Gloves are not required in normal use. The following glove(s) are recommended to prevent prolonged or repeated contact:. Chemical resistant gloves. Eye protection Avoid contact with eyes. Wear safety glasses with side shields. Skin and body protection None necessary under normal conditions 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Colorless Odor None Odor Threshold No information available pH No data available Specific Gravity 0.73 Vapor pressure No data available Density 6.09 lb/gal; 729 g/l Vapor density >1 (air=1) Evaporation Rate >1 (ether = 1) Water solubility No data available VOC Content 70.54% Partition Coefficient (n-octanol/water) No data available Boiling point/range °C < -18 - 172 Boiling point/range °F < 0 - 342 Melting point/range °C No data available Melting point/range °F No data available Flash point °C < -17 Flash point °F < 0 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid None known. Incompatability None. Hazardous Decomposition Products Carbon dioxide. Carbon monoxide. Page 2 / 4 Product name Wire Kote Product code 80924 Page 853 of 871 Page 853 of 871 Page 853 of 871 Page 853 of 871 ---PAGE BREAK--- Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat) LD50 (dermal,rat/rabbi t) LC50 (inhalation,rat) Toluene 108-88-3 636 mg/kg 12124 mg/kg 8390 mg/kg 12.5 mg/L 26700 ppm Acetone 67-64-1 5800 mg/kg - - Propane 74-98-6 - - 658 mg/L Butane 106-97-8 - - 658 mg/L Ethyl 3- Ethoxypropionate 763-69-9 3200 mg/kg 10 mL/kg - Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity None known Mutagenic effects None known Teratogenic effects None known Reproductive toxicity May cause adverse reproductive effects - such as birth defect, miscarriages, or infertility. Target Organ Effects Long term exposure to vapor may cause liver damage. Urinary system. Cardiovascular system. Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Toluene Listed Not Listed Not Listed Not Listed Not Listed Acetone Not Listed Not Listed Not Listed Not Listed Not Listed Propane Not Listed Not Listed Not Listed Not Listed Not Listed Butane Not Listed Not Listed Not Listed Not Listed Not Listed Ethyl 3- Ethoxypropion ate Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Page 3 / 4 Product code 80924 Microtox Data Photobacterium phosphoreum EC50=19.7 mg/L (30 min) Product name Wire Kote Water Flea Data water flea hEC50 48 (11.3 mg/L) water flea hEC50 48 (310 mg/L) Daphnia magna hEC50 48 (11.3 mg/L) water flea hEC50 48 (11.3 mg/L) Toluene Page 854 of 871 Page 854 of 871 Page 854 of 871 Page 854 of 871 ---PAGE BREAK--- 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Disposal Information As supplied, this product is a RCRA Hazardous Waste . Waste must be tested for ignitability to determine EPA hazardous waste numbers. Do not puncture or incinerate. Depressurize before disposal. Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT Consumer commodity, ORM-D TDG UN1950 AEROSOLS, flammable, 2.1 15. REGULATORY INFORMATION US EPA SARA 313 Chemical Name US EPA SARA 313 Emission Reporting Toluene Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Toluene Listed Listed Development al Acetone Not Listed Not Listed Not Listed Propane Listed Listed Not Listed Butane Listed Listed Not Listed Ethyl 3-Ethoxypropionate Not Listed Not Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA Toluene X X - X Acetone X X - X Propane X X - X Butane X X - X Ethyl 3-Ethoxypropionate X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION HMIS Health - 2 Flammability - 4 Physical Hazard - 0 Prepared By H. Buck, Regulatory Affairs Manager The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Water Flea Data water flea hEC50 48 (0.0039 mg/L) water flea hEC50 48 (12700 mg/L) Daphnia magna hEC50 48 (12600 mg/L) water flea hEC50 48 (0.0039 mg/L) Acetone Ethyl 3-Ethoxypropionate Product code 80924 Product name Wire Kote Water Flea Data Daphnia magna hEC50 48 (970 mg/L) Microtox Data Photobacterium phosphoreum EC50=14500 mg/L (15 min) Page 855 of 871 Page 855 of 871 Page 855 of 871 Page 855 of 871 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Product number [PHONE REDACTED] Product identifier XTREME GLEME Company information Claire Manufacturing Co. 1005 S. Westgate Drive Addison, IL 60101 United States Company phone General Assistance 1-[PHONE REDACTED] Emergency telephone US 1-[PHONE REDACTED] Emergency telephone outside US 1-[PHONE REDACTED] Version # 01 Recommended use CLEANER Recommended restrictions None known. 2. Hazard(s) identification Category 1 Flammable aerosols Physical hazards Not classified. Health hazards Not classified. Environmental hazards Not classified. OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Response Wash hands after handling. Storage Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Disposal Not available. Hazard(s) not otherwise classified (HNOC) Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number % Chemical name Common name and synonyms 112-34-5 Diethylene Glycol Monobutyl Ether 2.5 - 10 64-17-5 Ethyl Alcohol 2.5 - 10 106-97-8 Butane 1 - 2.5 7632-00-0 Sodium Nitrite Other components below reportable levels 80 - 90 0.1 - 1 This substance has workplace exposure limit(s). *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 1 / 10 Product name: XTREME GLEME Product [PHONE REDACTED] Version 01 Issue date: 05-25-2015 SDS US Page 856 of 871 Page 856 of 871 Page 856 of 871 Page 856 of 871 ---PAGE BREAK--- 4. First-aid measures Inhalation If develop move victim to fresh air. Get medical attention if persist. Skin contact Rinse skin with water/shower. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Ingestion In the unlikely event of swallowing contact a physician or poison control center. Most important acute and delayed Direct contact with eyes may cause temporary irritation. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat General information Take off all contaminated clothing immediately. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Contents under pressure. Pressurized container may explode when exposed to heat or flame. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. To reduce potential for static discharge, use proper bonding and grounding procedures. This liquid may accumulate static electricity when filling properly grounded containers. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. Special protective equipment and precautions for firefighters Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Fire-fighting equipment/instructions Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. General fire hazards Extremely flammable aerosol. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Transfer by mechanical means such as vacuum truck to a salvage tank or other suitable container for recovery or safe disposal. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to avoid environmental contamination. 2 / 10 Product name: XTREME GLEME Product [PHONE REDACTED] Version 01 Issue date: 05-25-2015 SDS US Page 857 of 871 Page 857 of 871 Page 857 of 871 Page 857 of 871 ---PAGE BREAK--- 7. Handling and storage Precautions for safe handling Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Do not re-use empty containers. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. For additional information on equipment bonding and grounding, refer to the Canadian Electrical Code in Canada, (CSA C22.1), or the American Petroleum Institute (API) Recommended Practice 2003, "Protection Against Ignitions Arising out of Static, Lightning, and Stray Currents" or National Fire Protection Association (NFPA) 77, "Recommended Practice on Static Electricity" or National Fire Protection Association (NFPA) 70, "National Electrical Code". Conditions for safe storage, including any incompatibilities Level 1 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Avoid spark promoters. Ground/bond container and equipment. These alone may be insufficient to remove static electricity. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Type PEL 1900 mg/m3 Ethyl Alcohol (CAS 64-17-5) 1000 ppm US. ACGIH Threshold Limit Values Value Components Form Type STEL 1000 ppm Butane (CAS 106-97-8) TWA 10 ppm Inhalable fraction and vapor. Diethylene Glycol Monobutyl Ether (CAS 112-34-5) STEL 1000 ppm Ethyl Alcohol (CAS 64-17-5) US. NIOSH: Pocket Guide to Chemical Hazards Value Components Type TWA 1900 mg/m3 Butane (CAS 106-97-8) 800 ppm TWA 1900 mg/m3 Ethyl Alcohol (CAS 64-17-5) 1000 ppm Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering controls Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Hand protection Wear appropriate chemical resistant gloves. Skin protection Other Not available. 3 / 10 Product name: XTREME GLEME Product [PHONE REDACTED] Version 01 Issue date: 05-25-2015 SDS US Page 858 of 871 Page 858 of 871 Page 858 of 871 Page 858 of 871 ---PAGE BREAK--- Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Gas. Form Aerosol. Color Not available. Odor Not available. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 209.39 °F (98.55 estimated Flash point -156.0 °F (-104.4 Propellant estimated Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower 2.6 % estimated Flammability limit - upper 12.8 % estimated Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 34.12 psig @70F estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 856.4 °F (458 estimated Decomposition temperature Not available. Viscosity Not available. Other information Specific gravity 0.974 estimated 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Hazardous decomposition products No hazardous decomposition products are known. 4 / 10 Product name: XTREME GLEME Product [PHONE REDACTED] Version 01 Issue date: 05-25-2015 SDS US Page 859 of 871 Page 859 of 871 Page 859 of 871 Page 859 of 871 ---PAGE BREAK--- 11. Toxicological information Information on likely routes of exposure Ingestion Not available. Inhalation Prolonged inhalation may be harmful. Skin contact Not available. Eye contact Direct contact with eyes may cause temporary irritation. related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity Expected to be a low hazard for usual industrial or commercial handling by trained personnel. Test Results Product Species XTREME GLEME (CAS Mixture) LD50 Rat Dermal Acute 47608 mg/kg LC50 Rat Inhalation 976 mg/l/4h Test Results Components Species Butane (CAS 106-97-8) LC50 Mouse Inhalation Acute 1237 mg/l, 120 Minutes 52 120 Minutes Rat 1355 mg/l Diethylene Glycol Monobutyl Ether (CAS 112-34-5) LD50 Guinea pig Dermal Acute 2 ml/kg, 2 Days Rabbit 2764 mg/kg, 24 Hours LD100 Rabbit Oral 4000 mg/kg LD50 Guinea pig 2000 mg/kg Mouse 2410 mg/kg Rabbit 2500 - 3000 mg/kg Rat 3306 mg/kg Ethyl Alcohol (CAS 64-17-5) LC50 Cat Inhalation Acute 85.41 mg/l, 4.5 Hours 43.68 mg/l, 6 Hours Mouse > 60000 ppm 79.43 mg/l, 134 Minutes Rat > 115.9 mg/l, 4 Hours 51.3 mg/l, 6 Hours LD50 Monkey Oral 6000 mg/kg Mouse 10500 ml/kg Rat 1187 - 2769 mg/kg 5 / 10 Product name: XTREME GLEME Product [PHONE REDACTED] Version 01 Issue date: 05-25-2015 SDS US Page 860 of 871 Page 860 of 871 Page 860 of 871 Page 860 of 871 ---PAGE BREAK--- Test Results Components Species 7800 ml/kg Sodium Nitrite (CAS 7632-00-0) LC50 Rat Inhalation Acute 5.5 mg/kg, 4 hours supplier LD50 Rat Oral 88 mg/kg supplier * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity Not available. Specific target organ toxicity - single exposure Not available. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not available. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity Harmful to aquatic life with long lasting effects. Product Test Results Species XTREME GLEME (CAS Mixture) Aquatic EC50 Crustacea 32900 mg/L, 48 Hours Daphnia LC50 Fish 4404 mg/L, 96 Hours Fish Components Test Results Species Diethylene Glycol Monobutyl Ether (CAS 112-34-5) Aquatic LC50 Fish 1300 mg/l, 96 hours Bluegill (Lepomis macrochirus) Ethyl Alcohol (CAS 64-17-5) Aquatic EC50 Crustacea 7700 - 11200 mg/l, 48 hours Water flea (Daphnia magna) LC50 Fish > 100.1 mg/l, 96 hours Fathead minnow (Pimephales promelas) Sodium Nitrite (CAS 7632-00-0) Aquatic EC50 Crustacea 16.14 - 26.61 mg/l, 48 hours Greasyback shrimp (Metapenaeus ensis) * Estimates for product may be based on additional component data not shown. LC50 Fish 0.15 - 0.25 mg/l, 96 hours Rainbow trout,donaldson trout mykiss) Persistence and degradability No data is available on the degradability of this product. 6 / 10 Product name: XTREME GLEME Product [PHONE REDACTED] Version 01 Issue date: 05-25-2015 SDS US Page 861 of 871 Page 861 of 871 Page 861 of 871 Page 861 of 871 ---PAGE BREAK--- Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) Butane 2.89 Diethylene Glycol Monobutyl Ether 0.56 Ethyl Alcohol -0.31 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. 14. Transport information DOT UN1950 UN number Aerosols, flammable, (each not exceeding 1 L capacity) UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk 2.1 Label(s) Not applicable. Packing group Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling. Special precautions for user N82 Special provisions 306 Packaging exceptions None Packaging non bulk None Packaging bulk This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently. IATA UN1950 UN number Aerosols, flammable UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk 2.1 Label(s) Not applicable. Packing group No. Environmental hazards 10L ERG Code Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Allowed. Passenger and cargo aircraft Other information Allowed. Cargo aircraft only LTD QTY Packaging Exceptions IMDG UN1950 UN number 7 / 10 Product name: XTREME GLEME Product [PHONE REDACTED] Version 01 Issue date: 05-25-2015 SDS US Page 862 of 871 Page 862 of 871 Page 862 of 871 Page 862 of 871 ---PAGE BREAK--- AEROSOLS UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk 2.1 Label(s) Not applicable. Packing group No. Marine pollutant Environmental hazards F-D, S-U EmS Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling. Special precautions for user LTD QTY Packaging Exceptions Not applicable. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT IATA; IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Sodium Nitrite (CAS 7632-00-0) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No 8 / 10 Product name: XTREME GLEME Product [PHONE REDACTED] Version 01 Issue date: 05-25-2015 SDS US Page 863 of 871 Page 863 of 871 Page 863 of 871 Page 863 of 871 ---PAGE BREAK--- SARA 302 Extremely hazardous substance Chemical name CAS number Reportable quantity Threshold planning quantity Threshold planning quantity, lower value Threshold planning quantity, upper value Ammonia 7664-41-7 100 500 lbs SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Chemical name CAS number % by wt. Sodium Nitrite 7632-00-0 0.1 - 1 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Butane (CAS 106-97-8) Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. Massachusetts RTK - Substance List Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) Sodium Nitrite (CAS 7632-00-0) US. New Jersey Worker and Community Right-to-Know Act Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) Sodium Nitrite (CAS 7632-00-0) US. Worker and Community Right-to-Know Law Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) Sodium Nitrite (CAS 7632-00-0) US. Rhode Island RTK Butane (CAS 106-97-8) Sodium Nitrite (CAS 7632-00-0) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Yes Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) Yes China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) Yes Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) No New Zealand New Zealand Inventory No Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 05-25-2015 9 / 10 Product name: XTREME GLEME Product [PHONE REDACTED] Version 01 Issue date: 05-25-2015 SDS US Page 864 of 871 Page 864 of 871 Page 864 of 871 Page 864 of 871 ---PAGE BREAK--- Version # 01 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 10 / 10 Product name: XTREME GLEME Product [PHONE REDACTED] Version 01 Issue date: 05-25-2015 SDS US Page 865 of 871 Page 865 of 871 Page 865 of 871 Page 865 of 871 ---PAGE BREAK--- r & I Section 1 SAFETY DATA SHEET Product Name: Zoom Spout® Oiler Revision Date: February 13. 2013 Page 1 of 6 Product and Company Identification Product Name: Product Code: Product Use: Supplier Phone Number Fax: 24-hour Emergency: Zoom Spout® Oiler 79704 Lubricating oil for general applications. LA-CO Industries, Inc. 1201 Pratt Boulevard Elk Grove village, IL 60007-5746 E-mail Contact: [EMAIL REDACTED] (847) 956-7600 (847) 956-9885 CHEMTREC: (800) 424-9300 Section 2: Hazards Identification 2.1 Classification of the substance or mixture according to GHS Classifications (UNECE 3 Revised Edition): Not classified as a hazardous chemical. 2.2 Label elements: No hazard classifications. 2.3 Other hazards: Maycause an allergic skin reaction in some individuals. 2.4 Other hazard classifications: USA: This material is not considered a hazardous chemical by the OSHA Hazard Communication Standard 29 CFR 1910.1200(2012). Canada: This is not a controlled product under WHMIS. European Union (EU): This product is not classified as hazardous according to CLP Regulation (EC) No 1272/2006. I Section 3: Composition / Information on Ingredients ChemlcalName• x • CAS No. Wt.% GHS Classifications" -according to UNECE 3rd Revised Edition Lubricating base oil and proprietary additives. No hazardous/dangerous ingredients by OSHA and WHMIS criteria. Not available 100 Not classified I Section 4: First Aid Measures 4.1 Description of first aid measures: Inhalation: are experienced, remove source of contamination or have victimmove to fresh air. Obtain medical advice. Eye Contact: Immediately flush the contaminated eye(s) withlukewarm, gently flowing water for 5 minutes whileholding the eyelids open. Ifirritation persists, obtain medical attention. Skin Contact: Ifirritation does occur flush with lukewarm, gently flowing water for 5 minutes. Ifirritation persists, obtain medical advice. Ingestion: Ifswallowed, do not induce vomiting. Ifvomitingoccurs naturally, have victim lean forward to reduce the risk of aspiration. Obtain medical advice or call a POISON CENTER or doctor/physician. \ 4.2 Most important and effects, both acute and delayed: Skin Contact: Acomponent of this material may cause an allergicskin reaction. may include redness and a burning sensation. Ingestion: Not an expected route of exposure withnormal use of the product. Acute oral toxicity of the component substances is low. Ingestion of large amounts of the product may cause nausea, vomiting and diarrhea. jfp\ Page 866 of 871 Page 866 of 871 Page 866 of 871 Page 866 of 871 ---PAGE BREAK--- SAFETY DATA SHEET Product Name: Zoom Spout® Oiler Revision Date: February 13,2013 Page 2 of 6 Section 5: Fire Fighting Measures 5.1 Extinguishing media: For small fires, usedry chemicals, carbon dioxide, appropriate foam, orinert gas (nitrogen). For large fires, useappropriate foam, water fog, orwater spray. Water canbeused tocool fire-exposed containers. Do not use water jet; may spread the fire. 5.2 Special hazards arising from the substance: Notclassified as a flammable or combustible liquid. Product will burn ifinvolved in a fire. Flashpoint: >150°C (>302°F) ASTM D93. 5.3 Advice for firefighters: If involved in a fire, combustion may produce toxic and irritating fumes and gases including carbon dioxide, carbon monoxide, nitrogen oxides, sulfur oxides, smoke, fumes, and/or unburned hydrocarbons. As for any fire, evacuate the area and fight the fire from a safe distance. Firefighters must wear full protective clothing and positive pressure self-contained breathing apparatus. I Section 6: Accidental Release Measures 6.1 Personalprecautions, protective equipment and Shutoff orextinguish all sources ofignition. Avoid contact with skin and eyes. Ventilate thearea. 6.2 Environmental precautions: Prevent the spilled liquid from entering sewersorwaterways. 6.3 Methods and materialfor containment and cleaning up: Stop the spill if it is safe to do so. p^ Absorb thespilled liquid using dry earth, sand ornon-combustible absorbent material and transfer toappropriate, covered and labeled waste containers. 6.4 Additional Information: See Section 8 for information onselection ofpersonal protective equipment See Section 13 forinformation on disposal ofspilled productand contaminated absorbents. Section 7: Handling andStorage 7.1 Precautions for safe handling: Keep outofreach ofchildren. Avoid contact with skin and eyes. Do not use near hot surfaces or flames. No smoking. 7.2 Conditions for safe storage, including any incompatibilities: Store in a well ventilated place. Keep cool. Keep containers closed when notin use. Section 8: Exposure Controls/Personal Protection 8.1 Control parameters: Occupational Exposure Limits: Consultlocalauthorities foracceptable exposure limits. Component Lubricant Base Oil (Petroleum) ACGIH TLV (8-hr. TWA) (mg/ms) Not available U.S. OSHA PEL 18-hr. TWA) (mg/m3) 5 mg/m as Oil Mist, ifgenerated British Columbia (Canada! TWA(mg/m0) Not available ID Page 867 of 871 Page 867 of 871 Page 867 of 871 Page 867 of 871 ---PAGE BREAK--- SAFETY DATA SHEET [Section 8: Exposure Controls/Personal Protection, continued Product Name: Zoom Spout® Oiler Revision Date: February 13,2013 Page 3 of 6 8.2 Exposure controls: Engineering Controls: General ventilation is normally adequate. Personal Protection: Workers must comply withthe Personal Protective Equipment requirements of the workplace in which this product is handled. Eye/Face Protection: Not required for normal use. Safety glasses equipped with side shields are recommended as minimum protection in industrial settings. Skin Protection: Not required for normal use. Wear heavy duty gloves made of nitrile when needed to prevent repeated or prolonged skin contact Respiratory Protection: Ifventilationand other engineering controls and work practices are not effective in controllingexposure to mists/aerosols of this material, then wear suitable personal protective equipment including approved respiratory protective equipment (RPE). Inworkplaces where respiratory protection is required, institutea complete respiratory protection program including selection, fittesting, training, maintenance and inspection. Consult with respirator manufacturer to determine respirator selection, use and limitations. Other Protection: If product comes in contact with clothing, immediately remove soaked clothing. remove and discard contaminated leather goods (e.g. watchbands, belts). 1Section 9: Physical and Chemical Properties 1 9.1 Information on basic physical and chemical properties: I Appearance: Liquid, clear, colorless. Odor Petroleum Odor threshold: Not applicable pH: Not applicable Melting point/freezing point: < -188C (0.4°F) Initial boiling point and boiling range: Not available Flash point: >150°C (>302"F) ASTM D93 Flammability Will burn but does not ignite readily. Auto-ignition temperature: Not available Upper/lower flammability or explosive limits: Not available Explosive properties: Not available Oxidizing properties: Not available Sensitivity to mechanical impact: Not available Sensitivity to static discharge: Not available Vapor pressure: <1 mm Hg Evaporation rate: <1 (n-butyl acetate = 1) Vapor density: <1 Relative density: 0.86-0.87 (water Solubility (is): Insoluble in water. Partition coefficient (n-octane/water): Not available Decomposition temperature: Not available Viscosity: 30-110@30°C 5 -11 cSt ® 100"C ASTM D445 1Section 10: Stability and Reactivity 1 10.1 Reactivity: Not classified for reactivity hazards. 10.2 Chemical Stability: Stable at normal ambient and anticipated storage and handling conditions of temperature and pressure. 10.3 Possibility of Hazardous Reactions: None known 10.4 Conditions to Avoid: Do not use in conditions of heat or near open flames and sparks. Page 868 of 871 Page 868 of 871 Page 868 of 871 Page 868 of 871 ---PAGE BREAK--- SAFETY DATA SHEET Product Name: Zoom Spout® Oiler Revision Date: February 13,2013 Page 4 of 6 Section 10: Stability and Reactivity, continued 10.5 Incompatible Materials: Incompatible with strong oxidizers, such as chlorine and oxygen, and strong reducing agents. 10.6 Hazardous Decomposition Products: Not available. Combustion may produce irritating and/or toxic gases. Section 11: Toxicological Information 11.1 Information on toxicological effects: Acute Health Effects: Inhalation: This product does not easily form a vapor, inhalation exposure is unlikely to occur, unless this material is heated or misted. Exposures to high vapor or mist concentrations may cause respiratory tract irritation. Ingestion: Not an expected route of exposure with normal use of the product. Skin: Contact with the skin may cause irritation. may include redness and a burning sensation. Eye: Direct contact with the liquid may cause irritation. Acute Toxicity Data:: /pP^v Component Substance LDsoOral (mg/kg) LDso Dermal (mg/kg) LCso Inhalation (4 hrs.) Lubricant oil >5 000 (species not available) >2 000 Not available Chronic Health Effects: Data are not available. Sensitization: Data are not available for the product. Contains a substance wt/wt) which may cause an allergic skin reaction. Neurological Effects: Data are not available. Genetic Effects: Data are not available. Reproductive Effects: Data are not available. Developmental Effects: Data are not available. Target Organ Effects: Data are not available. Carcinogenicity: The petroleum base oils contained inthis product have been highly refined by a variety of processes including severe hydrocracking/hydroprocessing to reduce aromatics and improve performance characteristics. All of the oils meet the IP-346 criteria of less than 3 percent PAH's and are not considered carcinogens by NTP, IARC, or OSHA. Medical Conditions Aggravated by Exposure: Repeated skin contact may aggravate an existing dermatitis. Interactions With Other Chemicals: Data are not available. Page 869 of 871 Page 869 of 871 Page 869 of 871 Page 869 of 871 ---PAGE BREAK--- SAFETY DATA SHEET Product Name: Zoom Spout® Oiler Revision Date: February 13,2013 Page 5 of 6 Section 12: Ecological Information 12.1 Toxicity: Assays have demonstrated acute aquatic toxicity values greater than 1000 mg/L. 12.2 Persistence and degradability: Volatilization to air is notexpected to be a significant fate process due to the low vapor pressure ofthis material. Inwater, base oils will float and spread over the surface. Not readily biodegradable. 12.3 Bioaccumulative potential: Log Kow values measured forthe hydrocarbon components ofthismaterial range from 4 to 6. 12.4 Mobility in soil: Not available I Section 13: Disposal Considerations Zl /0&A 13.1 Waste treatment methods: Do NOTdiscard into any sewers, on the ground or intoany body of water. Store material for disposal as indicated in Section 7 Handling and Storage. Dispose of in accordance with beat, state/provincial and federal laws and regulations. The conditionsof use. storage and disposal of this productare beyond our control and may be beyond our knowledge. For this and other reasons, LA-COIndustries, Inc. does not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of this product. I Section 14: Transport Information: Transport Regulations: U.S. Hazardous Materials Regulation (DOT 49CFR): Canadian Transportation of Dangerous Goods (TDG): IMO Classification: ICAO/IATA Classification: Section 15: Regulatory Information Not regulated. If shipped by land in a packaging having a capacity of 3,500 gallons or more, the provisions of 49 CFR, Part 130 apply. (Contains oil) Not regulated as a dangerous good for transport. Not regulated as a dangerous good for transport Not regulated as a dangerous good for transport 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture: USA OSHA: Non-Hazardous Chemical according to OSHA Hazard Communication Standard 29 CFR 1910.120 (2012). SARA Title III Sec. 302/304: None Sec: 311/312: Not applicable Sec. 313: None CERCLA RQ: None California Prop 65: Not applicable Page 870 of 871 Page 870 of 871 Page 870 of 871 Page 870 of 871 ---PAGE BREAK--- SAFETY DATA SHEET Product Name: Zoom Spojt® Oiler RevisionDale: February 13, 2013 Page 6 of 6 Section 15: Regulatory Information, continued Canada Europe This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and tne 3DS contains all tne information required by the Controlled Products Regulations. WHMIS Classification: Not controlled DSL Status: AH component substances listed on the DSL (Domestic Substances List). NPRI Substances: Not applicable OSHA: This product is notclassified as hazardousaccording to CLP Regulation (EC) No 1272/2008. Section 16: Other Information Preparation Information: Revision date: February 13, 2013 References and sources for data: CCOHS-Chemlnfo Legend to abbreviations: ACGIH - American Conference of Governmental Industrial Hygienists GHS-Globally Harmonised System forClassification and Labeling IARC - International Agency for Research on Cancer LD50- Median lethal dose; the dose causing 50 % lethality LEV- Local exhaust ventilation OSHA - United States. Occupational Safety and Health Administration STEL - Short term exposure limit TWA - Time weighted average TLV - Threshold Limit Value NTP - National Toxicology Program WHMIS - Canada, Workplace Hazardous Materials Information System Supplier Note: The information contained herein is based on data available to us and is accurate and reliable to the best of our knowledge and belief. However, LA-CO Industries, Inc. makes no representations as to its completeness or accuracy. Information is supplied on condition that persons receiving such information will make their own determination as to its suitability for their purposes prior to use. In no event will LA-CO Industries, Inc. be responsible for damages of any nature whatsoever resulting from the use of or reliance upon the information contained herein. Prepared by: LEHDER Environmental Services Limited (519)336-4101 www.lehder.com While LEHDER Environmental Services Limited believes that the data set forth herein is accurate, as of the date hereof, LEHDER makes no warranty with respect thereto and expressly disclaims all liability for reliance thereon. Such data is offered solely for your consideration, investigation and verification. Page 871 of 871 Page 871 of 871 Page 871 of 871 Page 871 of 871

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