Document douglascountywi_gov_doc_85f51579fe

Safety Data Sheet Index Binder: Highway Department - Hawthorne Shop - Highway Department - Hawthorne Shop #80 GEL PENETRATING LUBE 1ST AYD CORP 03/12/2015 10 #861 Anti-Seize Lubricant/Sealant Frontier Performance Lubricants, Inc. 06/03/2008 19 066 Multi Purpose Adhesive Sprayway, Inc. 10/25/2007 23 100% Kitchen & Bath Silicone Sealant White DAP Products Inc. 05/18/2015 28 133MA ANTI-SEIZE LUBRICANT 8.5 OZ ITW Permatex 05/28/2015 34 13P441 - Contact Cleaner, Aerosol Can, Aerosol 138495-42-8 CRC Industries, Inc. 07/05/2011 44 14AR THREAD SEALANT W/PTFE 1 OZ ITW Permatex 04/24/2015 47 1BR FORM A GASKET #1 SEALANT 3 OZ. ITW Permatex 04/27/2015 57 2F136 – Grease Dielectric CRC Industries, Inc. 11/06/2006 67 3M Brand Super Trim Adhesive, PN 08090 3M - Automotive Aftermarket 03/27/2015 69 3M BRAND UNDERSEAL RUBBERIZED UNDERCOATING 88161, 88162 (INACTIVE) 3M - CANADA COMPANY 04/22/2015 83 3M General Trim Adhesive, PN 08088 3M - Automotive Aftermarket 04/01/2015 90 3M Scotch-Weld Slip Fit/High Strength Retaining Compound RT80 (formerly sold as Rite-Lok Slip Fit/High Strength Retaining Compound RT80-10, RT80-50, RT80-250, & RT80-1L) 3M - Industrial Adhesives and Tapes 12/10/2012 103 3M Windo-Weld Super Fast Urethane PN 08609 3M - Automotive Aftermarket 02/04/2015 112 4ZF09 – Crease Lithium White CRC Industries, Inc. 01/02/2007 [PHONE REDACTED] NAPA HIGH TACK GASKET SEALANT(PTX80062) 4 FL.OZ ITW Permatex 06/15/2015 127 A1121 Tire Shine Omega Industrial Supply Inc 05/29/2009 136 AeroShell Fluid 4 Shell Canada Products 11/14/2014 137 Aerosol Glass Cleaner - Ammonia Free Malco Products, Inc. 10/24/2014 145 Aerosol Lock Deicer ITW Performance Polymers - QUALCO 10/01/2001 154 Aerosol Spray Paint CARQUEST Canada 11/01/2004 163 AIR BRAKE CONDITIONER 67-56-1 FPPF CHEMICAL CO INC 05/31/2015 165 Product Name CAS Number Manufacturer Version Date Page ---PAGE BREAK--- AIR-TOOL OIL, MYSTERY OIL, 10573 Marvel Oil Company 04/15/1997 175 AMERICA'S CHOICE DIESEL MOTOR OILS – LUBRIZOL BLEND, HD, HD-2, SHD, SHD-M, SHO-M, PLD-3, XHD-7, Includes grades 10W, 10W-30, 15W-40, 30, 40, 50, MIL-PRF-2104G, 2104H, CF, CF-2, CI-4, CI4 Plus, CJ-4 Safety-Kleen Systems, Inc. 04/18/2012 179 AMERICA’S CHOICE MOTOR OIL; Includes Grades 5W-20, 5W-30, 10W-30, 20W-50, SAE 30 Safety-Kleen Systems, Inc. 11/01/2010 191 ARM & HAMMER BAKING SODA 144-55-8 Church & Dwight Co., Inc. 06/23/1986 203 ATC - Air Tool Conditioner(Aerosol) The Blaster Corporation 06/05/2015 205 Balance EC Economy Neutral Floor Cleaner Nyco Products Company 01/30/2015 212 Bar's Leaks Liquid Radiator Stop Leak BAR'S PRODUCTS 05/01/2015 219 Baseboard Stripper & Cleaner Total Solutions 03/12/2004 228 Bonide Wasp & Hornet Killer (Aerosol) Bonide Products, Inc. 05/06/2015 230 Brute Lube ,multi-purpose cutting and tapping 236 Bulldog Adhesion Klean-Strip 238 CARPET AND PLUS CLEANER-- AEROSOL Malco Products, Inc. 12/07/1998 245 Castle Corrosion Off Castle Products, Inc. 06/14/2013 247 Castle Dry Lub Castle Products, Inc. 09/19/2013 250 Castle Long Life Castle Products, Inc. 12/31/2004 253 Castle Plexo Castle Products, Inc. 06/14/2013 254 Castle Tuff Glove Castle Products, Inc. 06/14/2013 257 Castle Zapp Castle Products, Inc. 06/14/2013 260 CAT COMPACTOR OIL Chemtool Incorporated 08/14/2012 263 Cat Coolant Conditioner Element Dober 05/24/2012 275 Citra Clean Total Solutions 08/13/2014 287 Citra-Blaze 535 Cleaner Degreaser Nyco Products Company 12/17/2012 289 Citra-Scrub Kutol 291 cleaner and sealer eliminate grout 296 Clorox Bleach Wipes The Clorox Company 01/05/2015 298 COPPER ANTI-SEIZE LUBRICANT 16 OZ ITW Permatex 05/21/2015 307 Dawn Dishwashing Liquid Soap 64-17-5 Procter & Gamble 01/01/1993 316 Product Name CAS Number Manufacturer Version Date Page Page 2 of 1287 Page 2 of 1287 Page 2 of 1287 Page 2 of 1287 ---PAGE BREAK--- Detail Demon Auto Finish Cleaner/Polish Nyco Products Company 01/06/2011 318 DIELECTRIC TUNE-UP GREASE 3 OZ ITW Permatex 04/07/2015 320 DIESEL FUEL SUPPLEMENT +CETANE BOOST Power Service Products, Inc. 05/30/2015 327 DIESEL STARTING FLUID 142-82-5 QUICK START PRODUCTS LTD 05/01/1991 340 DIESEL/BIODIESEL BLEND Imperial Oil 12/23/2014 343 DIRT FIGHTER Exterior Acrylic Latex Semi- Gloss Finish, White DUTCH BOY 02/02/2012 355 DUPLI-COLOR Brake Caliper Paint, Black DUPLI-COLOR PRODUCTS CO 01/09/2015 359 DUPLI-COLOR Low VOC Truck Bed Coating, Black DUPLI-COLOR PRODUCTS CO 03/05/2015 363 DUPLI-COLOR Truck Bed Coating, Black DUPLI-COLOR PRODUCTS CO 08/04/2014 368 DURATRAN Petro-Canada America Lubricants 02/12/2015 373 DUREX ND SAE 30 Shell Oil Company 01/04/1999 382 ELMERS CARPENTERS WOOD GLUE Elmer's Products, Inc. 03/04/2009 388 ENAMEL REDUCER Axalta Coating Systems, LLC 05/05/2013 395 Epcon Acrylic 7 ITW RED HEAD 08/19/2013 406 Expo White Board Cleaner Newell Rubbermaid 08/05/2015 414 FARM AND INDUSTRY INTERNATIONAL HARVESTOR RED SEYMOUR OF SYCAMORE 01/04/2006 422 Fuel Stabilizer STA-BIL 426 GERMICIDAL CLEANER Claire Manufacturing Company 03/23/2015 433 Glade Super Fresh JohnsonDiversey, Inc. 03/07/2008 442 GLEME GLASS CLEANER Claire Manufacturing Company 05/26/2015 445 GLOSS BLACK SEYMOUR OF SYCAMORE 11/06/2014 455 GLOSS WHITE SEYMOUR OF SYCAMORE 11/05/2014 459 GRAFFITI & SPRAY PAINT REMOVER ITW Professional Brands 11/24/2014 463 GRAFFITI-OFF 20 OZ NW Lawson Products, Inc. 05/24/2011 467 Graphite Lubricant Total Solutions 09/14/2009 471 Great Stuff Dow Chemical Company 04/07/2008 473 GREEN KLEEN MULTI-PURPOSE CLEANER DEGREASER Nyco Products Company 04/06/2012 486 GREEN REBAR EPOXY SEYMOUR OF SYCAMORE 10/13/2014 488 Product Name CAS Number Manufacturer Version Date Page Page 3 of 1287 Page 3 of 1287 Page 3 of 1287 Page 3 of 1287 ---PAGE BREAK--- GS RESTROOM CLEANER Spartan Chemical Company, Inc. 05/04/2015 493 GS Window Cleaner Concentrate Stearns Packaging Corporation 09/23/2014 498 hand soap fair and square 507 INDUSTRIAL UPSIDE DOWN TRAFFIC PAINT 20 oz. PLASTI-KOTE COMPANY, INC. 09/29/2000 514 Injex Pro 2-Cycle Motor Oil Phillips 66 Lubricants 01/09/2015 516 Insect Repellent CRC Industries, Inc. 05/21/2015 524 KEROSENE 64742-81-0 Suncor Energy Inc 06/04/2015 534 KRYLON Battery Protector THE SHERWIN-WILLIAMS COMPANY- KRYLON Products Group 03/06/2015 544 KRYLON Industrial QUIK-MARK Solvent-Based Inverted Marking Paint (Fluorescent), Orange THE SHERWIN-WILLIAMS COMPANY - KRYLON INDUSTRIAL PRODUCTS GROUP 05/04/2015 549 KRYLON Industrial QUIK-MARK Solvent-Based Inverted Marking Paint (Fluorescent), Red Orange THE SHERWIN-WILLIAMS COMPANY - KRYLON INDUSTRIAL PRODUCTS GROUP 05/04/2015 555 KRYLON Industrial QUIK-MARK Water-Based Inverted Marking Paint (APWA), Brilliant Red THE SHERWIN-WILLIAMS COMPANY - KRYLON INDUSTRIAL PRODUCTS GROUP 04/08/2015 561 LECTRA SOL TC (AEROSOL) TRI-CHEM CORPORATION 06/19/2012 565 Lemon Duster Dusting & Cleaning Spray ITW Dymon 04/13/2011 567 LIGHT GRAY PRIMER SEYMOUR OF SYCAMORE 02/16/2015 570 LIQUEFIED PETROLEUM GAS or PROPANE 74-98-6 Lakes Gas Co. 09/01/2004 582 Liquid Hand Soap 1ST AYD CORP 07/01/1999 584 Liquid Wrench Hydraulic Jack Oil RSC Chemical Solutions 05/01/2015 585 Liquid Wrench Penetrating Oil RSC Chemical Solutions 05/06/2015 592 Lock Deicer & Lubricant KAFKO INTERNATIONAL, LTD. 10/01/2006 601 Loctite 598 Black RTV High Performance Silicone Gasket Maker Henkel Corporation 08/28/2014 604 Loctite 7471 Primer T Henkel Corporation 09/10/2014 611 LOCTITE COPPER-BASED ANTI-SEIZE t LUBRICANT Henkel Corporation 09/03/2014 617 Long Term Rust Preventative Lubricant Rawn 623 LPS Cold Galvanize 00516 LPS Laboratories, a division of Illinois Tool Works 02/03/2014 625 Lubrimatic 2-cycle Engine Oil LUBRIMATIC - a division of STANT 04/24/2002 636 Product Name CAS Number Manufacturer Version Date Page Page 4 of 1287 Page 4 of 1287 Page 4 of 1287 Page 4 of 1287 ---PAGE BREAK--- Corporation M06, Mirror Glaze Liquid Cleaner Wax (21- 151A):, M0616, M0664 Meguiar's, Inc. 03/20/2015 640 Marvel Air Tool Oil Marvel Oil Company 03/10/2015 651 Marvel Mystery Oil Marvel Oil Company 03/10/2015 659 MIKE-O-CUT #87 Ashburn Chemical Technologies 09/09/2014 667 Mixed Product Total Petrochemicals & Refining USA, Inc. 07/24/2015 673 MOBIL DELVAC 1300 SUPER 10W-30 Exxon Mobil Corporation 03/16/2015 684 MOBIL DELVAC ATF Exxon Mobil Corporation 04/10/2015 694 MOBIL SHC 630 ExxonMobil Marine Limited 05/19/2015 704 MOBIL TRANS HD 30 Lubes Direct Pty Ltd 11/02/2013 716 MOBILGREASE XHP 462 MOLY Exxon Mobil Corporation 03/17/2015 726 Motor Medic Thrust Starting Fluid RSC Chemical Solutions 05/18/2015 736 MOTORCRAFT MERCON LV AUTOMATIC TRANSMISSION FLUID Ford Motor Company 08/31/2007 746 MOTORCRAFT TRANSFER CASE FLUID Ford Motor Company 05/21/2008 753 MRO DARK GREEN SEYMOUR OF SYCAMORE 09/25/2014 761 MRO FLAT BLACK SEYMOUR OF SYCAMORE 09/25/2014 766 MRO SAFETY BLUE SEYMOUR OF SYCAMORE 11/07/2014 770 Muriatic Acid Crown Chemical Products, Inc. 07/27/2015 775 NAPA Kool 4055, 4056, 4057, 4058; Wix Cool 24055, 24056, 24057, 24058; CARQUEST Cooling Systems Treatment 89055, 89056, 89057, 89058 Wix Filtration Products Division, Affinia Group 03/31/2010 778 NEUTRO-WASH RHOMAR INDUSTRIES INC 03/12/2015 783 NEW EQUIPMENT YELLOW SEYMOUR OF SYCAMORE 10/09/2014 788 NICKEL ANTI-SEIZE LUBRICANT 1LB BB ITW Permatex 12/12/2014 792 NMC EN 12 OZ OMNI-PAK ENAMEL Sprayon Products 12/16/1998 801 NO TOUCH ORIGINAL TIRE CARE 18OZ AE Permatex, Inc. 11/17/2010 805 Oatey Pipe Joint Lubricant OATEY 05/12/2015 808 Oatey PVC Heavy Duty Gray Cement OATEY CO. 05/27/2015 814 OFF! DEEP WOODS INSECT REPELLENT VII S.C. Johnson & Son, Inc. 02/24/2015 824 Office Max Compressed Gas Duster 75-37-6 Falcon Safety Products, Inc 04/28/2015 836 Product Name CAS Number Manufacturer Version Date Page Page 5 of 1287 Page 5 of 1287 Page 5 of 1287 Page 5 of 1287 ---PAGE BREAK--- OMAHA ORANGE SEYMOUR OF SYCAMORE 01/31/2014 844 ORANGE TOUGH 15 Spartan Chemical Company, Inc. 04/24/2015 848 OSHA COLORS- SPRAY PAINT (AEROSOL) TRI-CHEM CORPORATION 06/11/2007 853 PARTS MASTER PREMIUM POWER STEERING FLUID OMNI Specialty Packaging 01/31/2012 855 Peak Cool Extended Life Concentrate Antifreeze & Coolant Old World Industries, LLC 03/10/2015 861 Penetrating Oil HL 25 Miller Industrial Fluids 07/09/2015 870 Pennzoil Platinum Axle 75W-90 Shell Oil Products US 02/05/2014 881 PENRAY AIR BRAKE ANTIFREEZE 5601 Penray Companies, Inc. 05/29/2011 891 Perfect Stop DOT 3 Heavy Duty Brake Fluid Warren Unilube Inc 05/29/2013 896 Permatex Battery Cleaner Loctite Corporation 01/04/1999 901 PERMATEX FAST ORANGE Hand Cleaner (Smooth Lotion) - 15 fl. oz. squeeze bottle Permatex, Inc. 06/30/2012 906 Permatex Rust Treatment Henkel Corporation 08/22/2014 910 PNEUMATIC-HYDRAULIC SEALANT 36 ML ITW Permatex 03/16/2015 916 POLAR WINDSHIELD WASH & DEICER FLUID -30 Degree F Old World Industries, LLC 10/29/2014 924 Power Steering Fluid Smitty's Supply, Inc. 05/16/2015 934 Precision Color (Regal Blue) Raabe Corporation 07/29/2005 941 Propane WORTHINGTON CYLINDER CORPORATION 03/25/2015 949 PROPANE 74-98-6 BERNZOMATIC 06/11/2011 957 Purple Power Windshield Washer Zecol 960 PX Super “99” Isopropyl Alcohol 67-63-0 Splash Products, Inc. 06/03/2010 962 Quaker State Itasca 16:1 2-Cycle Engine Oil Quaker State Corporation 06/05/1998 965 Regulare Clear Cement OATEY CO. 05/28/2015 971 Retinax Grease CMX 2 Shell Oil Products US 02/05/2014 981 RHOMA-SOL RHOMAR INDUSTRIES INC 05/22/2015 991 Rid Ox Tech Spray, Inc. 06/04/2004 996 Ronson Butane 68476-86-8 MYDENT INTERNATIONAL 02/26/2014 1002 ROTOROIL 8000F4 MATTEI COMPRESSORS INC. 05/21/2013 1011 SC JOHNSON PROFESSIONAL GROUT S.C. Johnson & Son, Inc. 09/03/2010 1019 Product Name CAS Number Manufacturer Version Date Page Page 6 of 1287 Page 6 of 1287 Page 6 of 1287 Page 6 of 1287 ---PAGE BREAK--- CLEANER Shell Donax TX Shell Canada Products 02/10/2015 1026 Shell Morlina S4 B 220 Shell Oil Products US 02/05/2014 1033 Shell Rotella T Triple Protection 15W-40 Shell Canada Products 12/18/2014 1042 Shell Spirax S6 AXME 80W-140 Shell Oil Products US 05/21/2015 1049 SHINE PLUS Spartan Chemical Company, Inc. 04/16/2015 1063 SHORELINE MARINE HORNS 811-97-2 A.V.W. Inc./Max Professional 03/10/2010 1068 SLIP PlateNo. 1 Superior Graphite 03/25/2015 1073 Spectracide Wasp & Hornet Killer3 CHEMSICO DIV OF UNITED INDUSTRIES CORP 02/17/2015 1086 Stainless Steel Cleaner Total Solutions 03/23/2004 1092 Stainless Steel Cleaner Wipes Total Solutions 01/09/2013 1094 STATIC GUARD 068783-78-8 Alberto-Culver USA, Inc. 10/20/2000 1096 Straitline Marking Chalk Blue 57455-37-5 Irwin Industrial Tools 06/10/2006 1101 Super Clear Acrylic Gloss Plasti-Kote 1107 SUPER PENETRATING OIL Petra Oil Company 05/01/2011 1112 T42 Threadlocker SAF-T-LOK INTERNATIONAL CORP. 12/11/2012 1117 Tabz Coffee Equipment Cleaning Tablets URNEX BRANDS, INC. 02/03/2015 1121 TDL - The Dry Lube The Blaster Corporation 02/17/2012 1129 Ecoline Contact Cleaner 05/20/2015 1135 The confident solution FVP 1148 THE RIGHT STUFF GASKET MAKER 5 FL.OZ ITW Permatex 04/03/2015 1157 Thrust Castle 1165 Tire Mounting Lubricant AGS COMPANY 01/05/2010 1168 Toner Cartridge -Black Xerox Corporation 05/20/2011 1180 Turtle Wax Oxy Power Out Carpet Cleaner Turtle Wax, Inc. 09/08/2007 1187 UNITED 195 SMELL JEL United Laboratories Inc. 12/22/2012 1192 UNITED 231 VANISHING ACT United Laboratories Inc. 02/24/2015 1194 United 45 FIZZ-FIZZ Mop Soak Tablets United Laboratories Inc. 04/09/2001 1200 Unleaded Gasoline Total Petrochemicals & Refining USA, Inc. 07/24/2015 1202 Victor Mouse Glue Traps WOODSTREAM CORPORATION 01/13/2014 1214 Product Name CAS Number Manufacturer Version Date Page Page 7 of 1287 Page 7 of 1287 Page 7 of 1287 Page 7 of 1287 ---PAGE BREAK--- Wasp and Hornet Spray Spartan Wasp and Hornet Spray 1224 WD-40 MULTI-USE PRODUCT - [Aerosol] WD-40 COMPANY LTD (UK) 08/26/2014 1227 WHITE INVERTED TIP MARKER SEYMOUR OF SYCAMORE 01/04/2007 1240 WHITE LIGHTNING Silicone Rubber All Purpose Sealant (RTV Formula) Sherwin-Williams Company - Consumer Group - Industrial 05/23/2007 1243 White Lithium Grease CRC Industries, Inc. 01/16/2015 1248 White Traffic L/F, Fast Dry Diamond Vogel Paint 12/13/2013 1258 Xtreme Gleme All Weather Surface Degreaser Claire Manufacturing Company 10/03/2012 1263 Yellow Traffic L/F, Fast Dry Diamond Vogel Paint 12/12/2013 1268 Zecol Purple Power Window Wash 67-56-1 ZECOL PRODUCTS COMPANY 05/07/2012 1273 ZRC-221 Cold Galvanizing Compound ZRC Worldwide 02/05/2014 1282 Product Name CAS Number Manufacturer Version Date Page Page 8 of 1287 Page 8 of 1287 Page 8 of 1287 Page 8 of 1287 ---PAGE BREAK--- Page 9 of 1287 Page 9 of 1287 Page 9 of 1287 Page 9 of 1287 ---PAGE BREAK--- Page 10 of 1287 Page 10 of 1287 Page 10 of 1287 Page 10 of 1287 ---PAGE BREAK--- Page 11 of 1287 Page 11 of 1287 Page 11 of 1287 Page 11 of 1287 ---PAGE BREAK--- Page 12 of 1287 Page 12 of 1287 Page 12 of 1287 Page 12 of 1287 ---PAGE BREAK--- Page 13 of 1287 Page 13 of 1287 Page 13 of 1287 Page 13 of 1287 ---PAGE BREAK--- Page 14 of 1287 Page 14 of 1287 Page 14 of 1287 Page 14 of 1287 ---PAGE BREAK--- Page 15 of 1287 Page 15 of 1287 Page 15 of 1287 Page 15 of 1287 ---PAGE BREAK--- Page 16 of 1287 Page 16 of 1287 Page 16 of 1287 Page 16 of 1287 ---PAGE BREAK--- Page 17 of 1287 Page 17 of 1287 Page 17 of 1287 Page 17 of 1287 ---PAGE BREAK--- Material Safety Data Sheet #861 Anti-Seize Lubricant/Sealant Issued 7/14/04 Revised: 6/3/08 MSDS CODE #861 6/3/08 Page 1 of 4 SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Frontier Performance Lubricants, Inc. 24 Hour Emergency Telephone Number PO Box 1777 PERS: [PHONE REDACTED] Lodi, CA 95241 [PHONE REDACTED] PRODUCT DESCRIPTION: Anti-Seize Lubricant/Sealant #861 D.O.T. PROPER SHIPPING NAME: ORM-D CONSUMER COMMODITY SECTION 2: COMPOSITION / INFORMATION ON INGREDIENTS ALIPHATIC HYDROCARBON * PEL: 500 PPM.... CAS 110-54-3 TLV: 50 PPM COPPER COMPOUND PEL: NOT ESTABLISHED CAS 7440-50-8 TLV: NOT ESTABLISHED HYDROCARBON PROPELLANT PEL: 800 PPM CAS 68476-86-8 TLV: 800 PPM If present, IARL, NTP and OSHA carcinogens and chemical subject to this reporting requirements of SARA TITLE III, SECTION 313 are identified SECTION 3: HAZARD IDENTIFICATION GENERAL: This material is an aspiration hazard and defects the skin. Breathing vapors of high concentrations may cause CNS depression. EYE CONTACT: irritating but does not injure eye tissue. SKIN CONTACT: Low order of toxicity. Frequent or prolonged contact may irritate and cause dermatitis. Skin contact may aggravate an existing dermatitis condition. INHALATION: High vapor/aerosol concentrations (greater than approximately 100 ppm) are irritating to the eyes and the respiratory tract, may cause headaches, dizziness, anesthesia, drowsiness, unconsciousness, and other central nervous system effects, including death. INGESTION: Small amounts of this product aspirated into the respiratory system during ingestion or vomiting may cause mild to severe pulmonary injury, possibly minimal toxicity. SECTION 4: FIRST AID MEASURES EYE CONTACT: Flush eyes with large amounts of water until irritation subsides. If irritation persists, get medical attention. SKIN CONTACT: Flush with large amounts of water; use soap if available. Remove grossly contaminated clothing, including shoes, and launder before reuse. INHALATION: Page 18 of 1287 Page 18 of 1287 Page 18 of 1287 Page 18 of 1287 ---PAGE BREAK--- Material Safety Data Sheet #861 Anti-Seize Lubricant/Sealant Issued 7/14/04 Revised: 6/3/08 MSDS CODE #861 6/3/08 Page 2 of 4 Using proper respiratory protection, immediately remove the affected victim from exposure. Administer artificial respiration if breathing is stopped. Keep at rest. Call for prompt medical attention INGESTION: If swallowed, DO NOT induce vomiting. Keep at rest. Get prompt medical attention. SECTION 5: FIRE FIGHTING MEASURES FLASH POINT( EXTREMELY FLAMMABLE EXPLOSIVE LIMIT (PRODUCT): LOWER - N/D UPPER - N/D FIRE & EXPLOSIONS HAZARDS: Keep containers cool. Use equipment or shielding : This product releases Flammable Vapors at well below ambient temperatures and readily forms flammable mixtures with air exposed to an ignition source. It will burn in the open or be explosive in confined spaces. Its vapors are heavier than air and may travel long distances to a point of ignition, and then flash back. Alkaline/chlorine gas mixtures have produced explosions. EXTINGUISHING MEDIA: Dry Chemical. CO2. Halogenated Extinguishing Agent. Stop Gas Flow. SPECIAL FIRE FIGHTING PROCEDURES: Gas fires should not be extinguished unless the gas flow can be stopped immediately. Allow the fire to burn itself out. If the source cannot be shut off immediately, all equipment and surfaces exposed to the fire should be cooled with water to prevent over-heating, flash-backs, or explosions. Control fire until gas supply can be shut off. Use proper protective equipment. Use fresh air respirator when exposure to hazardous concentrations of toxic gases is possible. FIRE FIGHTING: Use water spray to cool fire exposed surfaces and to protect personnel. Isolate "fuel" supply from fire.Use foam, dry chemical, or water spray to extinguish fire. Avoid spraying water directly into storage containers due to danger of boil over. This liquid is volatile and gives off invisible vapors. Either the liquid or vapor may settle in low areas or travel some distance along the ground or surface to ignition sources where they may ignite or explode. SECTION 6: ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: STOP THE SOURCE OF THE LEAK OR RELEASE. CLEAN UP RELEASES AS SOON AS POSSIBLE. CONTAIN LIQUID TO PREVENT FURTHER CONTAMINATION OF SOIL, SURFACE WATER OR GROUND WATER. CLEAN UP SMALL SPILLS USING APPROPRIATE TECHNIQUES SUCH AS SORBENT MATERIALS OR PUMPING. REMOVE ALL SOURCES OF IGNITION. PERSONNEL PROTECTION EQUIPMENT MUST BE WORN (SEE SECTION VIII). VENTILATE SPILL AREA IF IN CONFINED OR POORLY VENTILATED AREA. PICK UP FREE LIQUID FOR RECYCLE AND/OR DISPOSAL. RESIDUAL MATERIAL CAN BE ABSORBED ON INERT MATERIAL. MINIMIZE SKIN CONTACT. KEEP PRODUCT OUT OF SEWERS AND WATERCOURSES BY DIKING OR IMPOUNDING. ADVISE AUTHORITIES IF PRODUCT HAS ENTERED OR MAY ENTER SEWERS, WATERCOURSES, OR EXTENSIVE LAND AREAS. ASSURE CONFORMITY WITH APPLICABLE GOVERNMENTAL REGULATIONS. CONTACT THE COAST GUARD NATIONAL RESPONSE CENTER (800) 424-8802 IF A SPILL OF ANY AMOUNT IS MADE INTO OR UPON U. S. NAVIGABLE WATERS, THE CONTIGUOUS ZONE OR ADJOINING SHORELINES. WASTE DISPOSAL: WASTE DISPOSAL SHOULD BE IN COMPLIANCE WITH ALL FEDERAL, STATE, AND LOCAL LAWS. SECTION 7: HANDLING AND STORAGE STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: STOP THE SOURCE OF THE LEAK OR RELEASE. CLEAN UP RELEASES AS SOON AS POSSIBLE. CONTAIN LIQUID TO PREVENT FURTHER CONTAMINATION OF SOIL, SURFACE WATER OR GROUND WATER. CLEAN UP SMALL SPILLS USING APPROPRIATE TECHNIQUES SUCH AS SORBENT MATERIALS OR PUMPING. REMOVE ALL SOURCES OF IGNITION. PERSONNEL PROTECTION EQUIPMENT MUST BE WORN( SEE SECTION VIII). VENTILATE SPILL AREA IF IN CONFINED OR POORLY VENTILATED AREA. PICK UP FREE LIQUID FOR RECYCLE AND/OR DISPOSAL. RESIDUAL MATERIAL CAN BE ABSORBED ON INERT MATERIAL. MINIMIZE SKIN CONTACT. KEEP Page 19 of 1287 Page 19 of 1287 Page 19 of 1287 Page 19 of 1287 ---PAGE BREAK--- Material Safety Data Sheet #861 Anti-Seize Lubricant/Sealant Issued 7/14/04 Revised: 6/3/08 MSDS CODE #861 6/3/08 Page 3 of 4 PRODUCT OUT OF SEWERS AND WATERCOURSES BY DIKING OR IMPOUNDING. ADVISE AUTHORITIES IF PRODUCT HAS ENTERED OR MAY ENTER SEWERS, WATERCOURSES, OR EXTENSIVE LAND AREAS. ASSURE CONFORMITY WITH APPLICABLE GOVERNMENTAL REGULATIONS. CONTACT THE COAST GUARD NATIONAL RESPONSE CENTER (800) 424-8802 IF A SPILL OF ANY AMOUNT IS MADE INTO OR UPON U. S. NAVIGABLE WATERS, THE CONTIGUOUS ZONE OR ADJOINING SHORELINES. WASTE DISPOSAL: WASTE DISPOSAL SHOULD BE IN COMPLIANCE WITH ALL FEDERAL, STATE, AND LOCAL LAWS. SECTION 8: EXPOSURE CONTROLS - PERSONAL PROTECTION VENTILATION: PROVIDE VENTILATION SUFFICIENT TO PREVENT EXCEEDING RECOMMENDED EXPOSURE LIMIT. USE LOCAL EXHAUST TO CAPTURE VAPOR, MISTS OR FUMES, IF NECESSARY. NO SMOKING, FLAME OR OTHER IGNITION SOURCES. RESPIRATORY PROTECTION: UNDER NORMAL USE CONDITIONS, RESPIRATOR IS NOT USUALLY REQUIRED. USE NIOSH/MSHA APPROVED AIR-PURIFYING RESPIRATOR FOR ORGANIC VAPORS AND PARTICULATES IF THE RECOMMENDED EXPOSURE LIMIT IS EXCEEDED. USE SELF- CONTAINED BREATHING APPARATUS FOR ENTRY INTO CONFINED SPACE, FOR OTHER POORLY VENTILATED AREAS AND FOR LARGE SPILL CLEAN-UP SITE PROTECTIVE GLOVES: USE CHEMICAL RESISTANT GLOVES TO AVOID PROLONGED OR REPEATED SKIN CONTACT. NITRILE GLOVES ARE RECOMMENDED EYE PROTECTION: USE SPLASH GOGGLES OR FACE SHIELD WHEN EYE CONTACT MAY OCCUR OTHER PROTECTIVE EQUIPMENT: USE CHEMICAL RESISTANT BOOTS AND APRONS OR OTHER IMPERVIOUS CLOTHING, IF NEEDED, TO AVOID CONTAMINATING REGULAR CLOTHING. LONG SLEEVE SHIRT IS RECOMMENDED. WORK PRACTICES: KEEP CONTAINERS CLOSED WHEN NOT IN USE. DO NOT STORE NEAR HEAT, SPARKS, FLAME OR STRONG OXIDANTS. PERSONAL HYGIENE: MINIMIZE BREATHING VAPOR, MIST OR FUMES. AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. REMOVE CONTAMINATED CLOTHING; LAUNDER BEFORE REUSE. REMOVE CONTAMINATED SHOES AND THOROUGHLY CLEAN BEFORE RE-USE; DISCARD IF OIL-SOAKED. CLEANSE SKIN THOROUGHLY AFTER CONTACT, BEFORE BREAKS AND MEALS, AND AT END OF WORK PERIOD. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT FOR PRODUCT: 120 F. VAPOR PRESSURE FOR PRODUCT: 45mmHG VAPOR DENSITY FOR PRODUCT: N/D SPECIFIC GRAVITY: 1.394 V.O.C.(GRAMS PER LITER): N/D WATER SOLUBILITY: NEGLIGIBLE APPEARANCE: GRAY LIQUID SECTION 10: STABILITY AND REACTIVITY STABILITY: Stable CONDITIONS TO AVOID: Temperatures above 130 degree F. Page 20 of 1287 Page 20 of 1287 Page 20 of 1287 Page 20 of 1287 ---PAGE BREAK--- Material Safety Data Sheet #861 Anti-Seize Lubricant/Sealant Issued 7/14/04 Revised: 6/3/08 MSDS CODE #861 6/3/08 Page 4 of 4 HAZARDOUS POLYMERIZATION: Will not occur MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: Strong oxidizing agents HAZARDOUS DECOMPOSITION PRODUCTS: None SECTION 11: DISPOSAL CONSIDERATIONS STEPS TO BE TAKEN IN CASE CONTAINER IS PUNTURED AND MATERIAL IS RELEASED: Clean up area by mopping or with absorbent materials and place in closed container for disposal. Consult Federal, State, and local disposal authorities. WASTE DISPOSAL METHOD: Consult local authorities for proper waste disposal procedures. Empty de-pressurized containers can not be reused. Cans that are pressurized or contain liquid must be disposed of in a permitted waste management facility. Consult Federal, State, and local disposal authorities for approved procedures. SECTION 12: OTHER INFORMATION THE INFORMATION AND RECOMMENDATIONS HEREIN ARE, TO THE BEST OF OUR KNOWLEDGE AND BELIEF, ACCURATE AND RELIABLE AS OF THE DATE ISSUED. FRONTIER DOES NOT WARRANT OR GUARANTEE THEIR ACCURACY OR RELIABILITY, AND SHALL NOT BE LIABLE FOR ANY LOSS OR DAMAGE ARISING OUT OF THE USE THEREOF. THE INFORMATION AND RECOMMENDATIONS ARE OFFERED FOR THE USER'S CONSIDERATION AND EXAMINATION, AND IT IS THE USER'S RESPONSIBILITY TO SATISFY ITSELF THAT THEY ARE SUITABLE AND COMPLETE FOR ITS PARTICULAR USE. IF BUYER REPACKAGES THIS PRODUCT, LEGAL COUNSEL SHOULD BE CONSULTED TO INSURE PROPER HEALTH, SAFETY AND OTHER NECESSARY INFORMATION IS INCLUDED ON THE CONTAINER Page 21 of 1287 Page 21 of 1287 Page 21 of 1287 Page 21 of 1287 ---PAGE BREAK--- Flammable properties Containers may explode when heated. Vapor or gas may spread to distant ignition sources and flash back. . 5. Fire Fighting Measures space Suitable extinguishing media Water fog. Foam. Dry chemical. Carbon dioxide (CO2). Do not use water. Extinguishing media space Specific hazards arising from the chemical Fire may produce irritating, corrosive and/or toxic gases. Protection of firefighters space Protective equipment and precautions for firefighters In the event of fire and/or explosion do not breathe fumes. Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask. Containers should be cooled with water to prevent vapor pressure build up. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. space Methods for containment Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. . 6. Accidental Release Measures space Methods for cleaning up Should not be released into the environment. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated surface thoroughly. space Handling Pressurized container: Do not pierce or burn, even after use. Do not handle or store near an open flame, heat or other sources of ignition. Do not use if spray button is missing or defective. Use only with adequate ventilation. Do not get this material in contact with eyes. Do not get this material in contact with skin. Wear personal protective equipment. Avoid prolonged exposure. . 7. Handling and Storage space Storage Level 3 Aerosol. Contents under pressure. Do not puncture, incinerate or crush. The pressure in sealed containers can increase under the influence of heat. Avoid exposure to long periods of sunlight. Keep in an area equipped with sprinklers. Keep out of the reach of children. space Exposure limits ACGIH Components CAS # Cyclohexane 110-82-7 TWA 100 ppm STEL Not established Ceiling Not established n-Butane 106-97-8 1000 ppm Not established Not established Propane 74-98-6 1000 ppm Not established Not established space Isobutane 75-28-5 1000 ppm Not established Not established . 8. Exposure Controls / Personal Protection space OSHA Components CAS # Cyclohexane 110-82-7 TWA 300 ppm STEL Not established Ceiling Not established space Propane 74-98-6 1000 ppm Not established Not established space Eye / face protection Wear chemical goggles. Personal protective equipment space Skin protection Wear appropriate chemical resistant gloves. space Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. space Appearance Compressed liquefied gas. . 9. Physical & Chemical Properties space Boiling point 64.4 °F (17.8 estimated space trade_name Product 066 Revision date: 12-JAN-2009 Print date: 12-JAN-2009 MSDS US 2 / 5 66 Spray Adhesive Page 22 of 1287 Page 22 of 1287 Page 22 of 1287 Page 22 of 1287 ---PAGE BREAK--- Color Tan. space Flammability (HOC) 42.4775 kJ/g estimated space Flash back Yes space Flash point -156 °F (-104.4 estimated space Form Aerosol. space Odor Solvent. space pH Not applicable space Physical state Liquid. space Pressure 55 - 75 psig @ 70F space Solubility None space Specific gravity 0.669 space Chemical stability Risk of ignition. . 10. Chemical Stability & Reactivity Information space Conditions to avoid Heat, flames and sparks. space Hazardous decomposition products May include oxides of oxides of carbon. space Acute effects Acute LD50: 5222 mg/kg estimated, Rat, Dermal Acute LC50: 35 mg/l/4h estimated, Rat, Inhalation . 11. Toxicological Information space Sensitization Not expected to be hazardous by OSHA criteria. space Reproductive effects Not expected to be hazardous by OSHA criteria. space Teratogenicity Not expected to be hazardous by OSHA criteria. space Ecotoxicity LC50 11.98 mg/L estimated, Fish, 96.00 Hours, IC50 1322 mg/L estimated, Algae, 72.00 Hours, . 12. Ecological Information space Waste codes D001: Waste Flammable material with a flash point <140 F . 13. Disposal Considerations space Disposal instructions Contents under pressure. Do not allow this material to drain into sewers/water supplies. If discarded, this product is considered a RCRA ignitable waste, D001. Dispose in accordance with all applicable regulations. space Department of Transportation (DOT) Requirements Consumer commodity ORM-D None Hazard class Subsidiary hazard class Proper shipping name Basic shipping requirements: 156, 306 156, 306 None Packaging exceptions Packaging non bulk Packaging bulk Additional information: . 14. Transport Information space trade_name Product 066 Revision date: 12-JAN-2009 Print date: 12-JAN-2009 MSDS US 3 / 5 66 Spray Adhesive Page 23 of 1287 Page 23 of 1287 Page 23 of 1287 Page 23 of 1287 ---PAGE BREAK--- IMDG AEROSOLS 2.1 1950 Hazard class UN number Proper shipping name Basic shipping requirements: LTD QTY 5F None 2 Packaging exceptions Item Labels required Transport Category Additional information: space IATA Aerosols, flammable 2.1 1950 Hazard class UN number Proper shipping name Basic shipping requirements: LTD QTY 2.1 Packaging exceptions Labels required Additional information: space US federal regulations U.S. - CERCLA/SARA - Section 313 - Emission Reporting 110-82-7 1.0 % de minimis concentration Cyclohexane This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. . 15. Regulatory Information space 29 CFR 1910.1200 hazardous chemical Yes Occupational Safety and Health Administration (OSHA) space Cyclohexane: 1000.0000 CERCLA (Superfund) reportable quantity space Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Superfund Amendments and Reauthorization Act of 1986 (SARA) space Section 302 extremely hazardous substance No space Section 311 hazardous chemical Yes space Inventory status Country(s) or region Inventory name On inventory (yes/no)* No No No No No China Europe Europe Japan Korea Inventory of Existing Chemical Substances in China (IECSC) European Inventory of New and Existing Chemicals (EINECS) European List of Notified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory space State regulations U.S. - - RTK (Right to Know) List 110-82-7 Environmental hazard Cyclohexane 115-10-6 Present Dimethyl Ether 75-28-5 Present Isobutane 106-97-8 Present n-Butane 74-98-6 Present Propane space trade_name Product 066 Revision date: 12-JAN-2009 Print date: 12-JAN-2009 MSDS US 4 / 5 66 Spray Adhesive Page 24 of 1287 Page 24 of 1287 Page 24 of 1287 Page 24 of 1287 ---PAGE BREAK--- HMIS® ratings Health: 1 Flammability: 4 Physical hazard: 0 . 16. Other Information space Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. space MSDS sections updated Hazards Identification: Emergency overview Handling and Storage: Storage Physical & Chemical Properties: Physical & Chemical Properties Physical & Chemical Properties: Appearance Transport Information: Agency Name and Packaging Type/Transport Mode Selection Regulatory Information: United States space trade_name Product 066 Revision date: 12-JAN-2009 Print date: 12-JAN-2009 MSDS US 5 / 5 66 Spray Adhesive Page 25 of 1287 Page 25 of 1287 Page 25 of 1287 Page 25 of 1287 ---PAGE BREAK--- SDS Number: 00008640001 Revision Date: 5/18/2015 24 Hour Emergency Phone Numbers: Medical/Poison Control: In U.S.: Call 1-[PHONE REDACTED] Outside U.S.: Call your local poison control center Transportation/National Response Center: 1-[PHONE REDACTED] 1-[PHONE REDACTED] NOTE: The National ResponseCenter emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals. Safety Data Sheet IMPORTANT: Provide this information to employees, customers, and users of this product. Read this SDS before handling or disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16. 1. Identification This Material Safety Data Sheet is available in American Spanish upon request. Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere. Product Name: 100% Kitchen & Bath Silicone Sealant White Revision Date: 5/18/2015 7/18/2013 Product UPC Number: 08640 Supercedes Date: Product Use/Class: Caulking Compound SDS No: 00008640001 Manufacturer: DAP Products Inc. 2400 Boston Street Suite 200 Baltimore, MD 21224-4723 [PHONE REDACTED] (non-emergency matters) Preparer: Regulatory Department 2. Hazards Identification EMERGENCY OVERVIEW: Under normal use conditions, this product is not expected to cause adverse health effects. High concentration of vapors may cause irritation to eyes and respiratory system. GHS Classification Not a hazardous substance or mixture. Symbol(s) of Product Not a hazardous substance or mixture. Signal Word Not a hazardous substance or mixture. 3. Composition/Information on Ingredients Chemical Name CAS-No. Wt. % GHS Symbols GHS Statements Hydrotreated middle distillate 64742-46-7 10-25 GHS06 H331 Page 1 / 6 Page 26 of 1287 Page 26 of 1287 Page 26 of 1287 Page 26 of 1287 ---PAGE BREAK--- SDS Number: 00008640001 Revision Date: 5/18/2015 Silica, amorphous 7631-86-9 2.5-10 GHS07 H332 Silanetriol, methyl-, triaceta 4253-34-3 2.5-10 GHS07 H302-312-315-319-332 The text for GHS Hazard Statements shown above (if any) is given in the "Other information" Section. 4. First-aid Measures FIRST AID - INHALATION: Material is not likely to present an inhalation hazard at ambient conditions. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical attention immediately. FIRST AID - SKIN CONTACT: Wash skin with soap and water for 15 minutes. Get medical aid if persist. FIRST AID - EYE CONTACT: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until irritation subsides. Get medical attention immediately. FIRST AID - INGESTION: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. 5. Fire-fighting Measures UNUSUAL FIRE AND EXPLOSION HAZARDS: None known. SPECIAL FIREFIGHTING PROCEDURES: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent) and full protective gear. Use water spray to cool exposed surfaces. EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam 6. Accidental Release Measures ENVIRONMENTAL MEASURES: No Information STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations. Scrape up dried material and place into containers. Use personal protective equipment as necessary. In case of spillage, absorb with inert material and dispose of in accordance with applicable regulations. 7. Handling and Storage HANDLING: KEEP OUT OF REACH OF CHILDREN!DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact with eyes, skin and clothing. Use only with adequate ventilation. Ensure fresh air entry during application and drying. Wash thoroughly after handling. Remove contact lenses before using. Do not handle contact lenses until all sealant has been cleaned from fingertips, nails and cuticles. Residual sealant may transfer to contact lenses and cause severe eye irritation. STORAGE: Avoid excessive heat and freezing. Do not store at temperatures above 120 degrees F. Store away from caustics and oxidizers. 8. Exposure Controls/Personal Protection Ingredients with Occupational Exposure Limits Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA OSHA PEL-CEILING Hydrotreated middle distillate N.E. N.E. N.E. N.E. Silica, amorphous N.E. N.E. N.E. N.E. Silanetriol, methyl-, triaceta N.E. N.E. N.E. N.E. Further Advice: MEL = Maximum Exposure Limit OES = Occupational Exposure Standard SUP = Supplier's Recommendation Sk = Skin Sensitizer N.E. = Not Established Page 2 / 6 Page 27 of 1287 Page 27 of 1287 Page 27 of 1287 Page 27 of 1287 ---PAGE BREAK--- SDS Number: 00008640001 Revision Date: 5/18/2015 Personal Protection RESPIRATORY PROTECTION: No personal respiratory protective equipment normally required. SKIN PROTECTION: Wear nitrile or neoprene gloves. EYE PROTECTION: Goggles or safety glasses with side shields. OTHER PROTECTIVE EQUIPMENT: Not required under normal use. HYGIENIC PRACTICES: Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing before re-use. 9. Physical and Chemical Properties Appearance: White Physical State: Paste Odor: Acetic Acid Odor Threshold: Not Established Density, g/cm3: 0.97 - 0.97 pH: Not Established Freeze Point, Not Established Viscosity (mPa.s): Not Established Solubility in Water: Not Established Partition Coeff., n-octanol/water: Not Established Decomposition Temperature, Not Established Explosive Limits, N.I. - N.I. Boiling Range, N.I. - N.I. Auto-Ignition Temperature, °C Not Established Minimum Flash Point, 93.3 Vapor Pressure, mmHg: No Information Evaporation Rate: Slower Than n-Butyl Acetate Flash Method: Seta Closed Cup Vapor Density: Heavier Than Air Combustibility: Does not Support Combustion (See "Other information" Section for abbreviation legend) (If product is an aerosol, the flash point stated above is that of the propellant.) 10. Stability and Reactivity STABILITY: Stable under recommended storage conditions. CONDITIONS TO AVOID: Oxidizing agents. Excessive heat and freezing. INCOMPATIBILITY: Incompatible with strong bases and oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Normal decomposition products, i.e., COx, NOx. 11. Toxicological Information EFFECT OF OVEREXPOSURE - INHALATION: Under normal use conditions, this product is not expected to cause adverse health effects. During application and cure, this product releases methanol. During application and cure, this product releases acetic acid. Inhalation of vapors in high concentration may cause mild irritation of respiratory system (nose, mouth, mucous membranes). EFFECT OF OVEREXPOSURE - SKIN CONTACT: Under normal use conditions, this product is not expected to cause adverse health effects. Prolonged or repeated contact with skin may cause mild irritation. EFFECT OF OVEREXPOSURE - EYE CONTACT: Under normal use conditions, this product is not expected to cause adverse health effects. Direct eye contact may cause irritation. EFFECT OF OVEREXPOSURE - INGESTION: Under normal use conditions, this product is not expected to cause adverse health Page 3 / 6 Page 28 of 1287 Page 28 of 1287 Page 28 of 1287 Page 28 of 1287 ---PAGE BREAK--- SDS Number: 00008640001 Revision Date: 5/18/2015 effects. Single dose oral toxicity is very low. Amounts ingested incidental to industrial handling are not likely to cause injury; however, ingestion of large amounts may cause injury. Ingestion may result in obstruction when material hardens. CARCINOGENICITY: No Information PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Inhalation, Skin Contact Acute Toxicity Values The acute effects of this product have not been tested. Data on individual components are tabulated below CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50 64742-46-7 Hydrotreated middle distillate 7400 mg/kg Rat >2000 mg/kg Rabbit 4.6 mg/L Rat 7631-86-9 Silica, amorphous >3300 mg/kg Rat >5000 mg/kg Rabbit >20 mg/L 4253-34-3 Silanetriol, methyl-, triaceta 1602 mg/kg Rat 1060 mg/kg Rabbit 11.6 mg/L N.I. = No Information 12. Ecological Information ECOLOGICAL INFORMATION: Ecological injuries are not known or expected under normal use. 13. Disposal Information DISPOSAL METHOD: This product does not meet the definition of a hazardous waste according to U.S. EPA Hazardous Waste Management Regulation, 40 CFR Section 261. Dispose as hazardous waste according to all local, state, federal and provincial regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations. Scrape up dried material and place into containers. Use personal protective equipment as necessary. In case of spillage, absorb with inert material and dispose of in accordance with applicable regulations. 14. Transport Information SPECIAL TRANSPORT PRECAUTIONS: No Information DOT Proper Shipping Name: Not Regulated DOT Technical Name: N.A. Hazard SubClass: N.A. DOT Hazard Class: N.A. DOT UN/NA Number: N.A. Packing Group: N.A. 15. Regulatory Information U.S. Federal Regulations: CERCLA - SARA Hazard Category This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Acute Health Hazard, Chronic Health Hazard SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Page 4 / 6 Page 29 of 1287 Page 29 of 1287 Page 29 of 1287 Page 29 of 1287 ---PAGE BREAK--- SDS Number: 00008640001 Revision Date: 5/18/2015 No Sara 313 components exist in this product. TOXIC SUBSTANCES CONTROL ACT: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: No TSCA12(b) components exist in this product in concentrations at or above their thresholds. CALIFORNIA PROPOSITION 65 CARCINOGENS WARNING: This product contains chemicals known to the State of California to cause cancer. CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS This product does not contain any chemicals known to the State of California to cause birth defects or other reproductive harm. International Regulations: As follows - CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings. WHMIS Class Consumer Commodity 16. Other Information Revision Date: 5/18/2015 Supersedes Date: 7/18/2013 Reason for revision: HazCom2012/GHS Conversion Datasheet produced by: Regulatory Department HMIS Ratings: Health: 1 Flammability: 1 Reactivity: 0 Personal Protection: X VOC Less Water Less Exempt, g/L:28.9 VOC, Material, g/L:29 VOC as Defined by California Consumer Product Regulation, Wt/Wt%:3.0 Text for GHS Hazard Statements shown in Section 3 describing each ingredient: H302 Harmful if swallowed. H312 Harmful in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H331 Toxic if inhaled. H332 Harmful if inhaled. Icons for GHS Pictograms shown in Section 3 describing each ingredient: GHS06 GHS07 Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined Page 5 / 6 Page 30 of 1287 Page 30 of 1287 Page 30 of 1287 Page 30 of 1287 ---PAGE BREAK--- SDS Number: 00008640001 Revision Date: 5/18/2015 DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since thisdocument is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to review the recommendations with due consideration for the specific context of the intended use and (ii) determine if they are appropriate. Page 6 / 6 Page 31 of 1287 Page 31 of 1287 Page 31 of 1287 Page 31 of 1287 ---PAGE BREAK--- 1. IDENTIFICATION Product identifier Product Name 133MA ANTI-SEIZE LUBRICANT 8.5 OZ Other means of identification Product Code 81464 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Aerosol Lubricant Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: [PHONE REDACTED] International Emergency: 00+1+ [PHONE REDACTED] Contract Number: MIS0003453 E-mail address [EMAIL REDACTED] 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Specific target organ toxicity (single exposure) Category 3 Aspiration toxicity Category 1 Label elements Emergency Overview Page 1 / 10 Danger Flammable aerosols SAFETY DATA SHEET Causes skin irritation Causes serious eye irritation May cause drowsiness or dizziness May be fatal if swallowed and enters airways Category 1 Version 1 Extremely flammable aerosol Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Revision Date 28-May-2015 Page 32 of 1287 Page 32 of 1287 Page 32 of 1287 Page 32 of 1287 ---PAGE BREAK--- Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. - No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting Precautionary Statements - Storage Store locked up Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Toxic to aquatic life with long lasting effects. The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3 % DMSO extract as measured by IP 346. This note applies only to certain complex oil derived substances in Annex I. Unknown acute toxicity 17.5 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret ACETONE 67-64-1 10 - 30 * HEPTANE 142-82-5 10 - 30 * DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC 64742-52-5 10 - 30 * CALCIUM OXIDE 1305-78-8 7 - 13 * ALUMINIUM POWDER 7429-90-5 5 - 10 * Page 2 / 10 Revision Date 28-May-2015 81464 - 133MA ANTI-SEIZE LUBRICANT 8.5 OZ Odor Solvent Appearance Gray Physical state Liquid Aerosol Page 33 of 1287 Page 33 of 1287 Page 33 of 1287 Page 33 of 1287 ---PAGE BREAK--- GRAPHITE 7782-42-5 3 - 7 * CARBON DIOXIDE 124-38-9 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If persist, call a physician. Ingestion IF SWALLOWED:. Call a physician or poison control center immediately. Do NOT induce vomiting. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important and effects, both acute and delayed See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire. Specific hazards arising from the chemical Extremely flammable. Keep product and empty container away from heat and sources of ignition. Vapors may travel to source of ignition and flash back. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Contents under pressure. Do not puncture or incinerate cans. Environmental precautions Page 3 / 10 81464 - 133MA ANTI-SEIZE LUBRICANT 8.5 OZ Revision Date 28-May-2015 Page 34 of 1287 Page 34 of 1287 Page 34 of 1287 Page 34 of 1287 ---PAGE BREAK--- Environmental precautions See Section 12 for additional ecological information. Do not flush into surface water or sanitary sewer system. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Take precautionary measures against static discharges. Do not puncture or incinerate cans. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Conditions for safe storage, including any incompatibilities Storage Conditions Keep away from heat, sparks, flame and other sources of ignition pilot lights, electric motors and static electricity). Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH ACETONE 67-64-1 STEL: 750 ppm TWA: 500 ppm TWA: 1000 ppm TWA: 2400 mg/m3 (vacated) TWA: 750 ppm (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors (vacated) STEL: 1000 ppm IDLH: 2500 ppm TWA: 250 ppm TWA: 590 mg/m3 HEPTANE 142-82-5 STEL: 500 ppm TWA: 400 ppm TWA: 500 ppm TWA: 2000 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 1600 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 2000 mg/m3 IDLH: 750 ppm Ceiling: 440 ppm 15 min Ceiling: 1800 mg/m3 15 min TWA: 85 ppm TWA: 350 mg/m3 CALCIUM OXIDE 1305-78-8 TWA: 2 mg/m3 TWA: 5 mg/m3 (vacated) TWA: 5 mg/m3 not in effect as a result of reconsideration IDLH: 25 mg/m3 TWA: 2 mg/m3 ALUMINIUM POWDER 7429-90-5 TWA: 1 mg/m3 respirable fraction TWA: 15 mg/m3 total dust TWA: 5 mg/m3 respirable fraction (vacated) TWA: 5 mg/m3 Al Aluminum TWA: 5 mg/m3 Al Page 4 / 10 81464 - 133MA ANTI-SEIZE LUBRICANT 8.5 OZ Revision Date 28-May-2015 Page 35 of 1287 Page 35 of 1287 Page 35 of 1287 Page 35 of 1287 ---PAGE BREAK--- GRAPHITE 7782-42-5 TWA: 2 mg/m3 respirable fraction all forms except graphite fibers TWA: 15 mg/m3 total dust TWA: 5 mg/m3 respirable fraction (vacated) TWA: 2.5 mg/m3 respirable dust natural (vacated) TWA: 10 mg/m3 total dust (vacated) TWA: 5 mg/m3 respirable fraction TWA: 15 natural IDLH: 1250 mg/m3 TWA: 2.5 mg/m3 natural respirable dust CARBON DIOXIDE 124-38-9 STEL: 30000 ppm TWA: 5000 ppm TWA: 5000 ppm TWA: 9000 mg/m3 (vacated) TWA: 10000 ppm (vacated) TWA: 18000 mg/m3 (vacated) STEL: 30000 ppm (vacated) STEL: 54000 mg/m3 IDLH: 40000 ppm TWA: 5000 ppm TWA: 9000 mg/m3 STEL: 30000 ppm STEL: 54000 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid; Aerosol Appearance Gray Odor Solvent Odor threshold No information available Page 5 / 10 Flammability (solid, gas) No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values Lower flammability limit: No information available Vapor pressure No information available Boiling point / boiling range No information available Vapor density >1 Remarks • Method Air = 1 Relative density 0.885-0.905 81464 - 133MA ANTI-SEIZE LUBRICANT 8.5 OZ Flash point Water solubility Insoluble in water < -18 °C / < 0 °F Gives a flame projection at full valve opening or flashback at any degree of valve opening pH No information available Evaporation rate No information available Revision Date 28-May-2015 Page 36 of 1287 Page 36 of 1287 Page 36 of 1287 Page 36 of 1287 ---PAGE BREAK--- Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content 24.5% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides Copper compounds 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. May cause drowsiness or dizziness. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Potential for aspiration if swallowed. Aspiration may cause pulmonary edema and pneumonitis. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 ACETONE 67-64-1 = 5800 mg/kg ( Rat ) - = 50100 mg/m3 ( Rat ) 8 h HEPTANE 142-82-5 - = 3000 mg/kg ( Rabbit ) = 103 g/m3 ( Rat ) 4 h CALCIUM OXIDE 1305-78-8 = 500 mg/kg ( Rat ) - - Information on toxicological effects No information available. Page 6 / 10 Partition coefficient No information available Dynamic viscosity No information available 81464 - 133MA ANTI-SEIZE LUBRICANT 8.5 OZ No data available Solubility in other solvents Autoignition temperature No information available No information available Revision Date 28-May-2015 Decomposition temperature No information available Kinematic viscosity No information available Page 37 of 1287 Page 37 of 1287 Page 37 of 1287 Page 37 of 1287 ---PAGE BREAK--- Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC 64742-52-5 A2 Group 1 - X ACGIH (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Target Organ Effects Central nervous system, Central Vascular System (CVS), Eyes, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 3394 mg/kg ATEmix (dermal) 12375 mg/kg ATEmix (inhalation-dust/mist) 186 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/aquatic plants Fish Crustacea ACETONE 67-64-1 - 4.74 - 6.33: 96 h mykiss mL/L LC50 6210 - 8120: 96 h Pimephales promelas mg/L LC50 static 8300: 96 h Lepomis macrochirus mg/L LC50 10294 - 17704: 48 h Daphnia magna mg/L EC50 Static 12600 - 12700: 48 h Daphnia magna mg/L EC50 HEPTANE 142-82-5 - 375.0: 96 h Cichlid fish mg/L LC50 10: 24 h Daphnia magna mg/L EC50 DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC 64742-52-5 - 5000: 96 h mykiss mg/L LC50 1000: 48 h Daphnia magna mg/L EC50 CALCIUM OXIDE 1305-78-8 - 1070: 96 h Cyprinus carpio mg/L LC50 static - Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient ACETONE 67-64-1 -0.24 HEPTANE 142-82-5 4.66 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Page 7 / 10 81464 - 133MA ANTI-SEIZE LUBRICANT 8.5 OZ Revision Date 28-May-2015 Page 38 of 1287 Page 38 of 1287 Page 38 of 1287 Page 38 of 1287 ---PAGE BREAK--- Waste treatment methods Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not reuse container. US EPA Waste Number D001 Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes ACETONE 67-64-1 - Included in waste stream: F039 - U002 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status ACETONE 67-64-1 Ignitable HEPTANE 142-82-5 Toxic Ignitable CALCIUM OXIDE 1305-78-8 Corrosive ALUMINIUM POWDER 7429-90-5 Ignitable powder 14. TRANSPORT INFORMATION DOT UN/ID no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.1 Emergency Response Guide Number 126 IATA UN/ID no ID 8000 Proper shipping name: Consumer commodity Hazard Class 9 ERG Code 9L IMDG UN/ID no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.1 EmS-No F-D, S-U 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Not Listed. Contains: Natural substance(s) IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory Page 8 / 10 81464 - 133MA ANTI-SEIZE LUBRICANT 8.5 OZ Revision Date 28-May-2015 Page 39 of 1287 Page 39 of 1287 Page 39 of 1287 Page 39 of 1287 ---PAGE BREAK--- DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % ALUMINIUM POWDER - 7429-90-5 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) ACETONE 67-64-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts ACETONE 67-64-1 X X X HEPTANE 142-82-5 X X X CALCIUM OXIDE 1305-78-8 X X X ALUMINIUM POWDER 7429-90-5 X X X GRAPHITE 7782-42-5 X X X CARBON DIOXIDE 124-38-9 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Page 9 / 10 Flammability 4 81464 - 133MA ANTI-SEIZE LUBRICANT 8.5 OZ Physical hazards 0 Personal protection B Health hazards 2 Flammability 4 Revision Date 28-May-2015 Instability 0 - HMIS NFPA Health hazards 2 Page 40 of 1287 Page 40 of 1287 Page 40 of 1287 Page 40 of 1287 ---PAGE BREAK--- Revision Date 28-May-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 10 / 10 81464 - 133MA ANTI-SEIZE LUBRICANT 8.5 OZ Revision Date 28-May-2015 Page 41 of 1287 Page 41 of 1287 Page 41 of 1287 Page 41 of 1287 ---PAGE BREAK--- Page 42 of 1287 Page 42 of 1287 Page 42 of 1287 Page 42 of 1287 ---PAGE BREAK--- Page 43 of 1287 Page 43 of 1287 Page 43 of 1287 Page 43 of 1287 ---PAGE BREAK--- Page 44 of 1287 Page 44 of 1287 Page 44 of 1287 Page 44 of 1287 ---PAGE BREAK--- 1. IDENTIFICATION Product identifier Product Name 14AR THREAD SEALANT W/PTFE 1 OZ. Other means of identification Product Code 80631 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Sealant Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: [PHONE REDACTED] International Emergency: 00+1+ [PHONE REDACTED] Contract Number: MIS0003453 E-mail address [EMAIL REDACTED] 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Category 4 Carcinogenicity Category 2 Specific target organ toxicity (single exposure) Category 1 Label elements Emergency Overview Page 1 / 10 Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Danger Flammable liquids Revision Date 24-Apr-2015 Harmful if swallowed May cause cancer Causes damage to organs Flammable Liquid Category 3 SAFETY DATA SHEET Version 1 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Page 45 of 1287 Page 45 of 1287 Page 45 of 1287 Page 45 of 1287 ---PAGE BREAK--- Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Do not breathe dust/fume/gas/mist/vapors/spray Keep away from heat/sparks/open flames/hot surfaces. — No smoking Keep container closed Take precautionary measures against static discharge Precautionary Statements - Response IF exposed: Call a POISON CENTER or doctor/physician Specific treatment (see supplemental first aid instructions on this label) IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth In case of fire: Use Water spray, fog or regular foam for extinction Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Harmful to aquatic life with long lasting effects. Unknown acute toxicity 65.99515% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret TALC 14807-96-6 15 - 40 * ETHANOL 64-17-5 10 - 30 * CASTOR OIL 8001-79-4 10 - 30 * POLYVINYL RESIN 63148-65-2 5 - 10 * 2-PROPANOL 67-63-0 1 - 5 * TITANIUM DIOXIDE 13463-67-7 1 - 5 * METHANOL 67-56-1 1 - 5 * POLYTETRAFLUOROETHYLENE 9002-84-0 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. Page 2 / 10 Revision Date 24-Apr-2015 80631 - 14AR THREAD SEALANT W/PTFE 1 OZ. Appearance White Physical state Paste Odor Alcoholic Page 46 of 1287 Page 46 of 1287 Page 46 of 1287 Page 46 of 1287 ---PAGE BREAK--- 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash with soap and water. If persist, call a physician. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important and effects, both acute and delayed See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical Flammable. Keep product and empty container away from heat and sources of ignition. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Remove all sources of ignition. Use personal protective equipment as required. Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Page 3 / 10 80631 - 14AR THREAD SEALANT W/PTFE 1 OZ. Revision Date 24-Apr-2015 Page 47 of 1287 Page 47 of 1287 Page 47 of 1287 Page 47 of 1287 ---PAGE BREAK--- Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Conditions for safe storage, including any incompatibilities Storage Conditions Keep away from heat, sparks, flame and other sources of ignition pilot lights, electric motors and static electricity). Store locked up. Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH TALC 14807-96-6 TWA: 2 mg/m3 particulate matter containing no asbestos and silica, respirable fraction (vacated) TWA: 2 mg/m3 respirable dust silica, containing no Asbestos TWA: 20 if 1% Quartz or more, use Quartz limit IDLH: 1000 mg/m3 TWA: 2 mg/m3 containing no Asbestos and Quartz respirable dust ETHANOL 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 2-PROPANOL 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 TITANIUM DIOXIDE 13463-67-7 TWA: 10 mg/m3 TWA: 15 mg/m3 total dust (vacated) TWA: 10 mg/m3 total dust IDLH: 5000 mg/m3 METHANOL 67-56-1 STEL: 250 ppm TWA: 200 ppm S* TWA: 200 ppm TWA: 260 mg/m3 (vacated) TWA: 200 ppm (vacated) TWA: 260 mg/m3 (vacated) STEL: 250 ppm (vacated) STEL: 325 mg/m3 (vacated) S* IDLH: 6000 ppm TWA: 200 ppm TWA: 260 mg/m3 STEL: 250 ppm STEL: 325 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Page 4 / 10 80631 - 14AR THREAD SEALANT W/PTFE 1 OZ. Revision Date 24-Apr-2015 Page 48 of 1287 Page 48 of 1287 Page 48 of 1287 Page 48 of 1287 ---PAGE BREAK--- Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Paste Appearance White Odor Alcoholic Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content 36.7% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Page 5 / 10 Flash point Water solubility Partially soluble 23 °C / 74 °F Solubility in other solvents No information available Tag Closed Cup pH Partition coefficient No information available No information available Evaporation rate < 1 Autoignition temperature No information available 80631 - 14AR THREAD SEALANT W/PTFE 1 OZ. Decomposition temperature No information available Butyl acetate = 1 Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: 12.7% Values Lower flammability limit: 2.3% Revision Date 24-Apr-2015 Vapor pressure 33 mm Hg @ 68°F Boiling point / boiling range 82 °C / 180 °F No data available Vapor density >1 Remarks • Method Air = 1 Relative density 1.06-1.10 Page 49 of 1287 Page 49 of 1287 Page 49 of 1287 Page 49 of 1287 ---PAGE BREAK--- Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides Fluorides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Harmful by inhalation. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion May be harmful if swallowed. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 ETHANOL 64-17-5 = 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h 2-PROPANOL 67-63-0 = 1870 mg/kg ( Rat ) = 4059 mg/kg ( Rabbit ) = 72600 mg/m3 ( Rat ) 4 h TITANIUM DIOXIDE 13463-67-7 > 10000 mg/kg ( Rat ) - - METHANOL 67-56-1 = 6200 mg/kg ( Rat ) = 15800 mg/kg ( Rabbit ) = 22500 ppm ( Rat ) 8 h = 64000 ppm ( Rat ) 4 h Information on toxicological effects No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA TALC 14807-96-6 - Group 3 - - ETHANOL 64-17-5 A3 Group 1 Known X 2-PROPANOL 67-63-0 - Group 1 - X TITANIUM DIOXIDE 13463-67-7 - Group 2B - X POLYTETRAFLUOROETHY LENE 9002-84-0 - Group 3 - - ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 2B - Possibly Carcinogenic to Humans Not classifiable as a human carcinogen NTP (National Toxicology Program) Known - Known Carcinogen Page 6 / 10 80631 - 14AR THREAD SEALANT W/PTFE 1 OZ. Revision Date 24-Apr-2015 Page 50 of 1287 Page 50 of 1287 Page 50 of 1287 Page 50 of 1287 ---PAGE BREAK--- OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Chronic toxicity May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. Contains a known or suspected reproductive toxin. Target Organ Effects Blood, Central nervous system, Central Vascular System (CVS), Eyes, Gastrointestinal tract (GI), Liver, Lungs, Reproductive System, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 1811 mg/kg ATEmix (dermal) 6521 mg/kg ATEmix (inhalation-dust/mist) 11.7 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 35.44605% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea TALC 14807-96-6 - 100: 96 h Brachydanio rerio g/L LC50 semi-static - ETHANOL 64-17-5 - 12.0 - 16.0: 96 h mykiss mL/L LC50 static 100: 96 h Pimephales promelas mg/L LC50 static 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through 9268 - 14221: 48 h Daphnia magna mg/L LC50 2: 48 h Daphnia magna mg/L EC50 Static 10800: 24 h Daphnia magna mg/L EC50 2-PROPANOL 67-63-0 1000: 96 h Desmodesmus subspicatus mg/L EC50 1000: 72 h Desmodesmus subspicatus mg/L EC50 11130: 96 h Pimephales promelas mg/L LC50 static 9640: 96 h Pimephales promelas mg/L LC50 flow-through 1400000: 96 h Lepomis macrochirus µg/L LC50 13299: 48 h Daphnia magna mg/L EC50 METHANOL 67-56-1 - 28200: 96 h Pimephales promelas mg/L LC50 flow-through 100: 96 h Pimephales promelas mg/L LC50 static 19500 - 20700: 96 h mykiss mg/L LC50 flow-through 13500 - 17600: 96 h Lepomis macrochirus mg/L LC50 flow-through 18 - 20: 96 h mykiss mL/L LC50 static - Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient ETHANOL 64-17-5 -0.32 2-PROPANOL 67-63-0 0.05 METHANOL 67-56-1 -0.77 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Page 7 / 10 Revision Date 24-Apr-2015 80631 - 14AR THREAD SEALANT W/PTFE 1 OZ. Page 51 of 1287 Page 51 of 1287 Page 51 of 1287 Page 51 of 1287 ---PAGE BREAK--- Waste treatment methods Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not reuse container. US EPA Waste Number D001 Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes METHANOL 67-56-1 - Included in waste stream: F039 - U154 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status ETHANOL 64-17-5 Toxic Ignitable 2-PROPANOL 67-63-0 Toxic Ignitable METHANOL 67-56-1 Toxic Ignitable 14. TRANSPORT INFORMATION DOT UN/ID no 1133 Proper shipping name: Adhesives, Limited Quantity (LQ) Hazard Class 3 Packing Group III Emergency Response Guide Number 128 IATA UN/ID no ID 8000 Proper shipping name: Consumer commodity Hazard Class 9 ERG Code 9L IMDG UN/ID no 1133 Proper shipping name: Adhesives, Limited Quantity (LQ) Hazard Class 3 Packing Group III EmS-No F-E, S-D 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Not Listed. ENCS Not Listed. IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory Page 8 / 10 80631 - 14AR THREAD SEALANT W/PTFE 1 OZ. Revision Date 24-Apr-2015 Page 52 of 1287 Page 52 of 1287 Page 52 of 1287 Page 52 of 1287 ---PAGE BREAK--- DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % 2-PROPANOL - 67-63-0 1.0 METHANOL - 67-56-1 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) METHANOL 67-56-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 ETHANOL - 64-17-5 Carcinogen Developmental TITANIUM DIOXIDE - 13463-67-7 Carcinogen METHANOL - 67-56-1 Developmental METHYL ISOBUTYL KETONE - 108-10-1 Carcinogen Developmental U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts TALC 14807-96-6 X X X ETHANOL 64-17-5 X X X 2-PROPANOL 67-63-0 X X X TITANIUM DIOXIDE 13463-67-7 X X X WATER 7732-18-5 - - X METHANOL 67-56-1 X X X POLYTETRAFLUOROETHYLENE 9002-84-0 - - X Page 9 / 10 Revision Date 24-Apr-2015 80631 - 14AR THREAD SEALANT W/PTFE 1 OZ. Page 53 of 1287 Page 53 of 1287 Page 53 of 1287 Page 53 of 1287 ---PAGE BREAK--- METHYL ISOBUTYL KETONE 108-10-1 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 24-Apr-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 10 / 10 - Revision Date 24-Apr-2015 HMIS NFPA Health hazards 2 Flammability 3 Physical hazards 0 Personal protection B Health hazards 2 Flammability 3 80631 - 14AR THREAD SEALANT W/PTFE 1 OZ. Instability 0 Page 54 of 1287 Page 54 of 1287 Page 54 of 1287 Page 54 of 1287 ---PAGE BREAK--- 1. IDENTIFICATION Product identifier Product Name 1BR FORM A GASKET #1 SEALANT 3 OZ. Other means of identification Product Code 80008 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Sealant Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: [PHONE REDACTED] International Emergency: 00+1+ [PHONE REDACTED] Contract Number: MIS0003453 E-mail address [EMAIL REDACTED] 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Category 3 Skin sensitization Category 1 Carcinogenicity Category 2 Label elements Emergency Overview Page 1 / 10 Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Revision Date 27-Apr-2015 Toxic if swallowed May cause an allergic skin reaction Suspected of causing cancer SAFETY DATA SHEET Version 1 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Danger Page 55 of 1287 Page 55 of 1287 Page 55 of 1287 Page 55 of 1287 ---PAGE BREAK--- Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention Specific treatment (see supplemental first aid instructions on this label) IF ON SKIN: Wash with plenty of soap and water If skin irritation or rash occurs: Get medical advice/attention Wash contaminated clothing before reuse IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Rinse mouth Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Harmful to aquatic life with long lasting effects. Unknown acute toxicity 58.78% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret KAOLIN 1332-58-7 30 - 60 * ROSIN 8050-09-7 10 - 30 * ETHANOL 64-17-5 7 - 13 * 2-PROPANOL 67-63-0 1 - 5 * TITANIUM DIOXIDE 13463-67-7 0.1 - 1 * SILICA 14808-60-7 0.1 - 1 * METHANOL 67-56-1 0.1 - 1 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Page 2 / 10 80008 - 1BR FORM A GASKET #1 SEALANT 3 OZ. Revision Date 27-Apr-2015 Appearance Reddish golden brown Physical state Paste Odor Alcohol Page 56 of 1287 Page 56 of 1287 Page 56 of 1287 Page 56 of 1287 ---PAGE BREAK--- Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash with soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If persist, call a physician. Ingestion IF SWALLOWED:. Call a physician or poison control center immediately. Rinse mouth. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important and effects, both acute and delayed See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Page 3 / 10 Revision Date 27-Apr-2015 80008 - 1BR FORM A GASKET #1 SEALANT 3 OZ. Page 57 of 1287 Page 57 of 1287 Page 57 of 1287 Page 57 of 1287 ---PAGE BREAK--- Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Store locked up. Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH KAOLIN 1332-58-7 TWA: 2 mg/m3 particulate matter containing no asbestos and silica, respirable fraction TWA: 15 mg/m3 total dust TWA: 5 mg/m3 respirable fraction (vacated) TWA: 10 mg/m3 total dust (vacated) TWA: 5 mg/m3 respirable fraction TWA: 10 mg/m3 total dust TWA: 5 mg/m3 respirable dust ROSIN 8050-09-7 - (vacated) TWA: 0.1 mg/m3 Formaldehyde TWA: 0.1 mg/m3 Formaldehyde ETHANOL 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 2-PROPANOL 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 TITANIUM DIOXIDE 13463-67-7 TWA: 10 mg/m3 TWA: 15 mg/m3 total dust (vacated) TWA: 10 mg/m3 total dust IDLH: 5000 mg/m3 SILICA 14808-60-7 TWA: 0.025 mg/m3 respirable fraction (vacated) TWA: 0.1 mg/m3 respirable dust : (30)/(%SiO2 + 2) mg/m3 TWA total dust : (250)/(%SiO2 + 5) TWA respirable fraction : (10)/(%SiO2 + 2) mg/m3 TWA respirable fraction IDLH: 50 mg/m3 respirable dust TWA: 0.05 mg/m3 respirable dust METHANOL 67-56-1 STEL: 250 ppm TWA: 200 ppm S* TWA: 200 ppm TWA: 260 mg/m3 (vacated) TWA: 200 ppm (vacated) TWA: 260 mg/m3 (vacated) STEL: 250 ppm (vacated) STEL: 325 mg/m3 (vacated) S* IDLH: 6000 ppm TWA: 200 ppm TWA: 260 mg/m3 STEL: 250 ppm STEL: 325 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Page 4 / 10 80008 - 1BR FORM A GASKET #1 SEALANT 3 OZ. Revision Date 27-Apr-2015 Page 58 of 1287 Page 58 of 1287 Page 58 of 1287 Page 58 of 1287 ---PAGE BREAK--- Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Paste Appearance Reddish golden brown Odor Alcohol Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content 13.5% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Page 5 / 10 Remarks • Method Air = 1 Relative density 1.44 Flash point Water solubility Partially soluble Does not apply 80008 - 1BR FORM A GASKET #1 SEALANT 3 OZ. Solubility in other solvents No information available ASTM D 4359 pH Partition coefficient No information available No information available Evaporation rate 7.7 Autoignition temperature No information available Decomposition temperature No information available Butyl acetate = 1 Revision Date 27-Apr-2015 Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values Lower flammability limit: No information available Vapor pressure 33 mmHg @ 68°F Boiling point / boiling range 82 °C / 180 °F Vapor density >1 Page 59 of 1287 Page 59 of 1287 Page 59 of 1287 Page 59 of 1287 ---PAGE BREAK--- Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides Aldehydes Carboxylic acids 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. May cause sensitization by skin contact. Ingestion Toxic if swallowed. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 ROSIN 8050-09-7 = 3 mg/kg ( Rat ) = 7600 mg/kg ( Rat ) > 2500 mg/kg ( Rabbit ) = 1.5 mg/L ( Rat ) 4 h ETHANOL 64-17-5 = 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h 2-PROPANOL 67-63-0 = 1870 mg/kg ( Rat ) = 4059 mg/kg ( Rabbit ) = 72600 mg/m3 ( Rat ) 4 h TITANIUM DIOXIDE 13463-67-7 > 10000 mg/kg ( Rat ) - - SILICA 14808-60-7 = 500 mg/kg ( Rat ) - - METHANOL 67-56-1 = 6200 mg/kg ( Rat ) = 15800 mg/kg ( Rabbit ) = 22500 ppm ( Rat ) 8 h = 64000 ppm ( Rat ) 4 h Information on toxicological effects No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA ETHANOL 64-17-5 A3 Group 1 Known X 2-PROPANOL 67-63-0 - Group 1 - X TITANIUM DIOXIDE 13463-67-7 - Group 2B - X SILICA 14808-60-7 A2 Group 1 Known X Page 6 / 10 80008 - 1BR FORM A GASKET #1 SEALANT 3 OZ. Revision Date 27-Apr-2015 No data available Page 60 of 1287 Page 60 of 1287 Page 60 of 1287 Page 60 of 1287 ---PAGE BREAK--- ACGIH (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 2B - Possibly Carcinogenic to Humans Not classifiable as a human carcinogen NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Chronic toxicity May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. Contains a known or suspected reproductive toxin. Target Organ Effects Blood, Central nervous system, Eyes, Liver, Reproductive System, Respiratory system, Skin, Thyroid. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 5 mg/kg ATEmix (dermal) 3403 mg/kg ATEmix (inhalation-dust/mist) 31 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 60.82% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea ROSIN 8050-09-7 400: 72 h Desmodesmus subspicatus mg/L EC50 - 3.8 - 5.4: 48 h Daphnia magna mg/L EC50 ETHANOL 64-17-5 - 12.0 - 16.0: 96 h mykiss mL/L LC50 static 100: 96 h Pimephales promelas mg/L LC50 static 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through 9268 - 14221: 48 h Daphnia magna mg/L LC50 2: 48 h Daphnia magna mg/L EC50 Static 10800: 24 h Daphnia magna mg/L EC50 2-PROPANOL 67-63-0 1000: 96 h Desmodesmus subspicatus mg/L EC50 1000: 72 h Desmodesmus subspicatus mg/L EC50 11130: 96 h Pimephales promelas mg/L LC50 static 9640: 96 h Pimephales promelas mg/L LC50 flow-through 1400000: 96 h Lepomis macrochirus µg/L LC50 13299: 48 h Daphnia magna mg/L EC50 METHANOL 67-56-1 - 28200: 96 h Pimephales promelas mg/L LC50 flow-through 100: 96 h Pimephales promelas mg/L LC50 static 19500 - 20700: 96 h mykiss mg/L LC50 flow-through 13500 - 17600: 96 h Lepomis macrochirus mg/L LC50 flow-through 18 - 20: 96 h mykiss mL/L LC50 static - Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient ETHANOL 64-17-5 -0.32 2-PROPANOL 67-63-0 0.05 Page 7 / 10 80008 - 1BR FORM A GASKET #1 SEALANT 3 OZ. Revision Date 27-Apr-2015 Page 61 of 1287 Page 61 of 1287 Page 61 of 1287 Page 61 of 1287 ---PAGE BREAK--- METHANOL 67-56-1 -0.77 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes METHANOL 67-56-1 - Included in waste stream: F039 - U154 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status ETHANOL 64-17-5 Toxic Ignitable 2-PROPANOL 67-63-0 Toxic Ignitable METHANOL 67-56-1 Toxic Ignitable 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Not Listed. IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances Page 8 / 10 Revision Date 27-Apr-2015 80008 - 1BR FORM A GASKET #1 SEALANT 3 OZ. Page 62 of 1287 Page 62 of 1287 Page 62 of 1287 Page 62 of 1287 ---PAGE BREAK--- KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % 2-PROPANOL - 67-63-0 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) METHANOL 67-56-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 ETHANOL - 64-17-5 Carcinogen Developmental TITANIUM DIOXIDE - 13463-67-7 Carcinogen SILICA - 14808-60-7 Carcinogen METHANOL - 67-56-1 Developmental METHYL ISOBUTYL KETONE - 108-10-1 Carcinogen Developmental U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts KAOLIN 1332-58-7 X X X ETHANOL 64-17-5 X X X 2-PROPANOL 67-63-0 X X X TITANIUM DIOXIDE 13463-67-7 X X X SILICA 14808-60-7 X X X METHANOL 67-56-1 X X X IRON OXIDE 1309-37-1 X X X METHYL ISOBUTYL KETONE 108-10-1 X X X U.S. EPA Label Information Page 9 / 10 80008 - 1BR FORM A GASKET #1 SEALANT 3 OZ. Revision Date 27-Apr-2015 Page 63 of 1287 Page 63 of 1287 Page 63 of 1287 Page 63 of 1287 ---PAGE BREAK--- EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 27-Apr-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 10 / 10 - HMIS NFPA Health hazards 2 80008 - 1BR FORM A GASKET #1 SEALANT 3 OZ. Flammability 1 Physical hazards 0 Personal protection B Health hazards 2 Revision Date 27-Apr-2015 Flammability 1 Instability 0 Page 64 of 1287 Page 64 of 1287 Page 64 of 1287 Page 64 of 1287 ---PAGE BREAK--- Page 65 of 1287 Page 65 of 1287 Page 65 of 1287 Page 65 of 1287 ---PAGE BREAK--- Page 66 of 1287 Page 66 of 1287 Page 66 of 1287 Page 66 of 1287 ---PAGE BREAK--- 3M™ Brand Super Trim Adhesive, PN 08090 03/27/15 Page 1 of 14 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: the information is copied in full with no changes unless prior written agreement is obtained from 3M, and neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 25-3522-7 Version Number: 5.00 Issue Date: 03/27/15 Supercedes Date: 01/21/13 SECTION 1: Identification 1.1. Product identifier 3M™ Brand Super Trim Adhesive, PN 08090 Product Identification Numbers 60-4550-3687-5, 60-4550-5561-0 1.2. Recommended use and restrictions on use Recommended use Automotive, Adhesive Aerosol 1.3. Supplier’s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-[PHONE REDACTED]) 1.4. Emergency telephone number 1-[PHONE REDACTED] or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Aerosol: Category 1. Serious Eye Damage/Irritation: Category 2B. Reproductive Toxicity: Category 1B. Simple Specific Target Organ Toxicity (central nervous system): Category 3. Specific Target Organ Toxicity (respiratory irritation): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger Page 67 of 1287 Page 67 of 1287 Page 67 of 1287 Page 67 of 1287 ---PAGE BREAK--- 3M™ Brand Super Trim Adhesive, PN 08090 03/27/15 Page 2 of 14 Symbols Flame I Exclamation mark I Health Hazard I Pictograms Hazard Statements Extremely flammable aerosol. Causes eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. May damage fertility or the unborn child. May displace oxygen and cause rapid suffocation. Causes damage to organs through prolonged or repeated exposure: nervous system I sensory organs I Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Call a POISON CENTER or doctor/physician if you feel unwell. Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Keep container closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal. Page 68 of 1287 Page 68 of 1287 Page 68 of 1287 Page 68 of 1287 ---PAGE BREAK--- 3M™ Brand Super Trim Adhesive, PN 08090 03/27/15 Page 3 of 14 34% of the mixture consists of ingredients of unknown acute oral toxicity. 41% of the mixture consists of ingredients of unknown acute dermal toxicity. 47% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Methyl Acetate 79-20-9 30 - 40 Trade Secret * Dimethyl Ether 115-10-6 25 - 35 Trade Secret * Non-hazardous components 04499600-7374) Trade Secret* 10 - 30 Trade Secret * Cyclohexane 110-82-7 10 - 20 Trade Secret * Toluene 108-88-3 3 - 7 Trade Secret * Hydrotreated Heavy Naphtha (Petroleum) 64742-48-9 1 - 5 Trade Secret * Rosin 8050-09-7 < 0.5 Trade Secret * NJTS or New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Wash with soap and water. If develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Page 69 of 1287 Page 69 of 1287 Page 69 of 1287 Page 69 of 1287 ---PAGE BREAK--- 3M™ Brand Super Trim Adhesive, PN 08090 03/27/15 Page 4 of 14 Formaldehyde During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human Page 70 of 1287 Page 70 of 1287 Page 70 of 1287 Page 70 of 1287 ---PAGE BREAK--- 3M™ Brand Super Trim Adhesive, PN 08090 03/27/15 Page 5 of 14 carcin Toluene 108-88-3 CMRG STEL:75 ppm Skin Notation Cyclohexane 110-82-7 OSHA TWA:1050 mg/m3(300 ppm) Cyclohexane 110-82-7 ACGIH TWA:100 ppm Dimethyl Ether 115-10-6 AIHA TWA:1880 mg/m3(1000 ppm) Dimethyl Ether 115-10-6 CMRG TWA:1000 ppm Hydrotreated Heavy Naphtha (Petroleum) 64742-48-9 Manufacturer determined TWA:100 ppm Methyl Acetate 79-20-9 OSHA TWA:610 mg/m3(200 ppm) Methyl Acetate 79-20-9 ACGIH TWA:200 ppm;STEL:250 ppm Rosin 8050-09-7 ACGIH Limit value not established: all exposr-low as possib, Dermal/Respiratory Sensitizer ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Fluoroelastomer Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties Page 71 of 1287 Page 71 of 1287 Page 71 of 1287 Page 71 of 1287 ---PAGE BREAK--- 3M™ Brand Super Trim Adhesive, PN 08090 03/27/15 Page 6 of 14 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Aerosol Odor, Color, Grade: Yellow to amber color, mild solvent smell Odor threshold No Data Available pH Not Applicable Melting point Not Applicable Boiling Point Not Applicable Flash Point -42 ºF Evaporation rate 1.90 [Ref Std: ETHER=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure Not Applicable Vapor Density [Ref Std: AIR=1] Density 0.835 g/ml Specific Gravity 0.835 [Ref Std: WATER=1] Solubility in Water Negligible Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity Not Applicable Hazardous Air Pollutants 0.566 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 53.7 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 448 g/l [Test Method: calculated SCAQMD rule 443.1] Percent volatile 85.7 % weight VOC Less H2O & Exempt Solvents 631 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat Sparks and/or flames 10.5. Incompatible materials Strong acids Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. Page 72 of 1287 Page 72 of 1287 Page 72 of 1287 Page 72 of 1287 ---PAGE BREAK--- 3M™ Brand Super Trim Adhesive, PN 08090 03/27/15 Page 7 of 14 SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Simple may include increased heart rate, rapid respirations, drowsiness, headache, incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal. Respiratory Tract Irritation: may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Mild Skin Irritation: may include localized redness, swelling, itching, and dryness. Eye Contact: Moderate Eye Irritation: may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause target organ effects: Ocular Effects: may include blurred or significantly impaired vision. Auditory Effects: may include hearing impairment, balance dysfunction and ringing in the ears. Olfactory Effects: may include decreased ability to detect odors and/or complete loss of smell. Neurological Effects: may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Page 73 of 1287 Page 73 of 1287 Page 73 of 1287 Page 73 of 1287 ---PAGE BREAK--- 3M™ Brand Super Trim Adhesive, PN 08090 03/27/15 Page 8 of 14 Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE > 5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE 20 - 50 mg/l Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Methyl Acetate Dermal Rat LD50 > 2,000 mg/kg Methyl Acetate Inhalation- Vapor (4 hours) Rat LC50 > 49 mg/l Methyl Acetate Ingestion Rat LD50 > 5,000 mg/kg Dimethyl Ether Inhalation- Gas (4 hours) Rat LC50 164,000 ppm Cyclohexane Dermal Rat LD50 > 2,000 mg/kg Cyclohexane Inhalation- Vapor (4 hours) Rat LC50 > 32.9 mg/l Cyclohexane Ingestion Rat LD50 6,200 mg/kg Toluene Dermal Rat LD50 12,000 mg/kg Toluene Inhalation- Vapor (4 hours) Rat LC50 30 mg/l Toluene Ingestion Rat LD50 5,550 mg/kg Non-hazardous components 04499600-7374) Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Hydrotreated Heavy Naphtha (Petroleum) Inhalation- Vapor LC50 estimated to be 20 - 50 mg/l Hydrotreated Heavy Naphtha (Petroleum) Dermal Rabbit LD50 > 3,000 mg/kg Hydrotreated Heavy Naphtha (Petroleum) Ingestion Rat LD50 > 5,000 mg/kg Rosin Dermal Rabbit LD50 > 2,500 mg/kg Rosin Ingestion Rat LD50 7,600 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Methyl Acetate Rabbit No significant irritation Cyclohexane Rabbit Mild irritant Toluene Rabbit Irritant Hydrotreated Heavy Naphtha (Petroleum) Rabbit Irritant Rosin Rabbit No significant irritation Serious Eye Damage/Irritation Name Species Value Methyl Acetate Rabbit Moderate irritant Cyclohexane Rabbit Mild irritant Toluene Rabbit Moderate irritant Hydrotreated Heavy Naphtha (Petroleum) Rabbit No significant irritation Rosin Rabbit Mild irritant Skin Sensitization Name Species Value Methyl Acetate Human Not sensitizing Toluene Guinea pig Not sensitizing Hydrotreated Heavy Naphtha (Petroleum) Guinea pig Not sensitizing Rosin Guinea pig Sensitizing Page 74 of 1287 Page 74 of 1287 Page 74 of 1287 Page 74 of 1287 ---PAGE BREAK--- 3M™ Brand Super Trim Adhesive, PN 08090 03/27/15 Page 9 of 14 Respiratory Sensitization Name Species Value Rosin Human Some positive data exist, but the data are not sufficient for classification Germ Cell Mutagenicity Name Route Value Methyl Acetate In Vitro Not mutagenic Methyl Acetate In vivo Not mutagenic Dimethyl Ether In Vitro Not mutagenic Dimethyl Ether In vivo Not mutagenic Cyclohexane In Vitro Not mutagenic Cyclohexane In vivo Some positive data exist, but the data are not sufficient for classification Toluene In Vitro Not mutagenic Toluene In vivo Not mutagenic Hydrotreated Heavy Naphtha (Petroleum) In vivo Not mutagenic Hydrotreated Heavy Naphtha (Petroleum) In Vitro Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Dimethyl Ether Inhalation Rat Not carcinogenic Toluene Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Ingestion Rat Some positive data exist, but the data are not sufficient for classification Toluene Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Hydrotreated Heavy Naphtha (Petroleum) Dermal Mouse Some positive data exist, but the data are not sufficient for classification Hydrotreated Heavy Naphtha (Petroleum) Inhalation Human and animal Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Dimethyl Ether Inhalation Not toxic to female reproduction Rat NOAEL 25,000 ppm 2 years Dimethyl Ether Inhalation Not toxic to male reproduction Rat NOAEL 25,000 ppm 2 years Dimethyl Ether Inhalation Not toxic to development Rat NOAEL 40,000 ppm during organogenesi s Cyclohexane Inhalation Not toxic to female reproduction Rat NOAEL 24 mg/l 2 generation Cyclohexane Inhalation Not toxic to male reproduction Rat NOAEL 24 mg/l 2 generation Cyclohexane Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 6.9 mg/l 2 generation Toluene Inhalation Some positive female reproductive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Toluene Inhalation Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 2.3 mg/l 1 generation Toluene Ingestion Toxic to development Rat LOAEL 520 mg/kg/day during gestation Page 75 of 1287 Page 75 of 1287 Page 75 of 1287 Page 75 of 1287 ---PAGE BREAK--- 3M™ Brand Super Trim Adhesive, PN 08090 03/27/15 Page 10 of 14 Toluene Inhalation Toxic to development Human NOAEL Not available poisoning and/or abuse Hydrotreated Heavy Naphtha (Petroleum) Inhalation Not toxic to development Rat NOAEL 2.4 mg/l during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Methyl Acetate Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Methyl Acetate Inhalation respiratory irritation May cause respiratory irritation Human and animal NOAEL Not available Methyl Acetate Inhalation blindness Some positive data exist, but the data are not sufficient for classification NOAEL Not available Methyl Acetate Ingestion central nervous system depression May cause drowsiness or dizziness NOAEL Not available Dimethyl Ether Inhalation central nervous system depression May cause drowsiness or dizziness Rat LOAEL 10,000 ppm 30 minutes Dimethyl Ether Inhalation cardiac sensitization Some positive data exist, but the data are not sufficient for classification Dog NOAEL 100,000 ppm 5 minutes Cyclohexane Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Cyclohexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Toluene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Toluene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Toluene Inhalation immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 0.004 mg/l 3 hours Toluene Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Hydrotreated Heavy Naphtha (Petroleum) Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Hydrotreated Heavy Naphtha (Petroleum) Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Hydrotreated Heavy Naphtha (Petroleum) Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Dog NOAEL 6.5 mg/l 4 hours Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Methyl Acetate Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 28 days Methyl Acetate Inhalation endocrine system I hematopoietic system I liver I immune system I kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 6.1 mg/l 28 days Dimethyl Ether Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for Rat NOAEL 25,000 ppm 2 years Page 76 of 1287 Page 76 of 1287 Page 76 of 1287 Page 76 of 1287 ---PAGE BREAK--- 3M™ Brand Super Trim Adhesive, PN 08090 03/27/15 Page 11 of 14 classification Dimethyl Ether Inhalation liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 20,000 ppm 30 weeks Cyclohexane Inhalation liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 24 mg/l 90 days Cyclohexane Inhalation auditory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.7 mg/l 90 days Cyclohexane Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rabbit NOAEL 2.7 mg/l 10 weeks Cyclohexane Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 24 mg/l 14 weeks Cyclohexane Inhalation peripheral nervous system All data are negative Rat NOAEL 8.6 mg/l 30 weeks Toluene Inhalation auditory system I nervous system I eyes I olfactory system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Toluene Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 2.3 mg/l 15 months Toluene Inhalation heart I liver I kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 11.3 mg/l 15 weeks Toluene Inhalation endocrine system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 4 weeks Toluene Inhalation immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL Not available 20 days Toluene Inhalation bone, teeth, nails, and/or hair Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1.1 mg/l 8 weeks Toluene Inhalation hematopoietic system I vascular system Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Toluene Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 625 mg/kg/day 13 weeks Toluene Ingestion heart Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion liver I kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion hematopoietic system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 600 mg/kg/day 14 days Toluene Ingestion endocrine system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 105 mg/kg/day 28 days Toluene Ingestion immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 105 mg/kg/day 4 weeks Hydrotreated Heavy Naphtha (Petroleum) Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 4.6 mg/l 6 months Hydrotreated Heavy Naphtha (Petroleum) Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat LOAEL 1.9 mg/l 13 weeks Hydrotreated Heavy Naphtha (Petroleum) Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 0.6 mg/l 90 days Hydrotreated Heavy Inhalation bone, teeth, nails, All data are negative Rat NOAEL 5.6 12 weeks Page 77 of 1287 Page 77 of 1287 Page 77 of 1287 Page 77 of 1287 ---PAGE BREAK--- 3M™ Brand Super Trim Adhesive, PN 08090 03/27/15 Page 12 of 14 Naphtha (Petroleum) and/or hair I blood I liver I muscles mg/l Hydrotreated Heavy Naphtha (Petroleum) Inhalation heart All data are negative Multiple animal species NOAEL 1.3 mg/l 90 days Aspiration Hazard Name Value Cyclohexane Aspiration hazard Toluene Aspiration hazard Hydrotreated Heavy Naphtha (Petroleum) Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-[PHONE REDACTED] or [PHONE REDACTED]. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Page 78 of 1287 Page 78 of 1287 Page 78 of 1287 Page 78 of 1287 ---PAGE BREAK--- 3M™ Brand Super Trim Adhesive, PN 08090 03/27/15 Page 13 of 14 Toluene 108-88-3 3 - 7 Cyclohexane 110-82-7 10 - 20 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification Toluene 108-88-3 Female reproductive toxin Toluene 108-88-3 Developmental Toxin WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 4 Instability: 0 Special Hazards: None Aerosol Storage Code: 2 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 25-3522-7 Version Number: 5.00 Issue Date: 03/27/15 Supercedes Date: 01/21/13 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com Page 79 of 1287 Page 79 of 1287 Page 79 of 1287 Page 79 of 1287 ---PAGE BREAK--- 3M™ Brand Super Trim Adhesive, PN 08090 03/27/15 Page 14 of 14 Page 80 of 1287 Page 80 of 1287 Page 80 of 1287 Page 80 of 1287 ---PAGE BREAK--- 3M Canada Company 1840 Oxford Street East, Post Office Box 5757 London, Ontario N6A 4T1 Medical Emergency Telephone: (519) 451‐2500, Ext. 2222 Transportation Emergency Telephone (CANUTEC): (613) 996‐6666 Material Safety Data Sheet Document id : 11‐2200‐1 Issue date : 2015/04/22 Version : 9.00 Supersedes date : 2003/03/06 Copyright, 1997, 3M Canada Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: the information is copied in full with no changes unless prior written agreement is obtained from 3M, and neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Prepared by: Corporate Regulatory Services, 3M Canada Company Telephone: (800) 364‐3577, Fax: (800) 603‐7758, Web Site: www.3M.ca 1 Chemical Product and Company Identification Tradename: 3M BRAND UNDERSEAL RUBBERIZED UNDERCOATING 88161, 88162 (INACTIVE) Product ID: CS‐0406‐1486‐2 CS‐0406‐1543‐0 Intended Use of Product: Coating Division: 3M CANADA COMPANY 2 Hazards Identification Critical Hazards: Combustible liquid and vapour. Moderate Eye Irritation: may include redness, swelling, pain, tearing, and blurred or hazy vision. WARNING: Contains a chemical, Bitumens, which can cause cancer. (CAS 8052‐42‐4) (IARC possible human carcinogen 2B, Calif. Proposition 65) See Sections 7 and 11 for further information. 3M BRAND UNDERSEAL RUBBERIZED UNDERCOATING 88161, Page 2 of 8 88162 (INACTIVE) Page 81 of 1287 Page 81 of 1287 Page 81 of 1287 Page 81 of 1287 ---PAGE BREAK--- 3 Composition/Information on Ingredients Ingredient Name CAS Number Percentage ASPHALT 8052‐42‐4 45 ‐ 55 MINERAL SPIRITS 8052‐41‐3 20 ‐ 30 CLAY 1332‐58‐7 15 ‐ 25 CELLULOSE 65996‐61‐4 1 ‐ 5 WATER 7732‐18‐5 1 ‐ 5 CALCIUM METASILICATE 13983‐17‐0 1 ‐ 5 4 First Aid Measures Instructions for Eye Contact: Immediately flush eyes with large amounts of water. Get immediate medical attention. Instructions for Skin Contact: Flush skin with large amounts of water. If irritation persists, get medical attention. Instructions for Inhalation: Remove person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, get immediate medical attention. Instructions for Ingestion: If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person. 5 Fire Fighting Measures Flash point: Approximately 37.8 C Lower Explosive Limit 0.20 % Upper Explosive Limit 7.00 % Autoignition temperature: Not available Suitable Extinguishing Media: Carbon Dioxide; Dry chemical; Foam; Exposure Hazards during Fire: Closed containers exposed to heat from fire may build pressure and explode. Vapours may travel long distances along the ground or floor to an ignition source and flash back. Combustion Products from Fire: Carbon monoxide and carbon dioxide; Toxic vapours, gases or particulates; Unusual Fire and Explosion Hazards None known. 3M BRAND UNDERSEAL RUBBERIZED UNDERCOATING 88161, Page 3 of 8 88162 (INACTIVE) Fire Fighting Procedures: Wear full protective clothing, including helmet, self‐contained, positive pressure or pressure demand breathing apparatus, bunker Page 82 of 1287 Page 82 of 1287 Page 82 of 1287 Page 82 of 1287 ---PAGE BREAK--- coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. NFPA: Health 2 NFPA: Fire 2 NFPA: Reactivity 0 NFPA: Unusual Reaction Hazard none National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short‐term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. 6 Accidental Release Measures Personal Precautions: Observe precautions from other sections. Call 3M‐ HELPS line (1‐800‐364‐3577) for more information on handling and managing the spill. Environmental Procedures No data available. Methods for cleaning up No data available. Spill Response: Ventilate the area with fresh air. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non‐sparking tools. Cover with absorbent material. Collect as much of the spilled material as possible. Place in an approved metal container. Methods for Disposal: Incinerate in a permitted hazardous waste incinerator in the presence of a combustible material. Dispose of waste product in a facility permitted to accept chemical waste. 3M BRAND UNDERSEAL RUBBERIZED UNDERCOATING 88161, Page 4 of 8 88162 (INACTIVE) 7 Handling and Storage Storage Requirements: Keep container closed when not in use. Incompatible Materials: Not applicable. Ventilation: No data available. Explosion Prevention: Combustible liquid and vapour. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Use Instructions: Keep container closed. Page 83 of 1287 Page 83 of 1287 Page 83 of 1287 Page 83 of 1287 ---PAGE BREAK--- 8 Exposure Controls/Personal Protection Personal Protection Eye Protection: Avoid eye contact. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Indirect vented goggles; Safety glasses with side shields Hand Protection: Wear appropriate gloves when handling this material. The following glove material(s) are recommended: polyethylene/ethylene vinyl alcohol; polyvinyl alcohol; polytetrafluoroethylene fluoroelastomer Skin Protection: Avoid skin contact. Respiratory Protection: Avoid prolonged breathing of vapours. Ingestion (Prevention): Do not ingest. Keep out of the reach of children. Recommended Ventilation: Use in a well‐ventilated area. Provide sufficient ventilation to maintain emissions below recommended exposure limits. Ingredient Exposure Data ASPHALT (8052‐42‐4) LD50 (rat, oral) No data available. LC50 (rat, inhalation/4 hours) No data available. Exposure Limits ACGIH: TWA 0.5 mg/m3 as fume; (Table A4) 0.5 mg/m3 ACGIH: TWA; as benzene solubles, inhalable fraction 0.5 mg/m3 ACGIH: TWA; as benzene solubles, inhalable fraction; 3M BRAND UNDERSEAL RUBBERIZED UNDERCOATING 88161, Page 5 of 8 88162 (INACTIVE) Category: Asphalt MINERAL SPIRITS (8052‐41‐3) LD50 (rat, oral) No data available. LC50 (rat, inhalation/4 hours) No data available. Exposure Limits ACGIH‐TWA: 100 ppm CLAY (1332‐58‐7) Specific Ingredient Data No data available. LD50 (rat, oral) No data available. LC50 (rat, inhalation/4 hours) No data available. Exposure Limits ACGIH: TWA 2 mg/m3 (respirable fraction) CELLULOSE (65996‐61‐4) Specific Ingredient Data No data available. LD50 (rat, oral) No data available. LC50 (rat, inhalation/4 hours) No data available. Exposure Limits Page 84 of 1287 Page 84 of 1287 Page 84 of 1287 Page 84 of 1287 ---PAGE BREAK--- No data available. WATER (7732‐18‐5) LD50 (rat, oral) > 90 ml/kg LC50 (rat, inhalation/4 hours) No data available. Exposure Limits No data available. CALCIUM METASILICATE (13983‐17‐0) Specific Ingredient Data No data available. LD50 (rat, oral) No data available. LC50 (rat, inhalation/4 hours) No data available. Exposure Limits 3M: TWA 10 mg/m3 as dust 9 Physical and Chemical Properties Physical form,Color,Odour: paste; Black; asphalt odour; Odour Threshold: No data available. pH: Not available Boiling point/boiling range: 148.9 ‐ 157.2 C Melting point/melting range: Not available Vapour pressure: 2.0000 mmHg at 20 degrees Celcius (Room Temperature). Water Solubility: Nil Specific gravity: 1.200 Water=1 Vapour density: > 1.00 Air=1 Volatile organic compounds: Not available Evaporation rate: < 1.00 BuOAc=1 Viscosity: Not available 3M BRAND UNDERSEAL RUBBERIZED UNDERCOATING 88161, Page 6 of 8 88162 (INACTIVE) Percent Volatile: No data available. 10 Stability and Reactivity Conditions to Avoid: None known. Materials to Avoid: Not applicable. Hazardous Decomposition: Carbon monoxide and carbon dioxide; Toxic vapours, gases or particulates; Stability and Reactivity: Stable. Hazardous polymerization will not occur. 11 Toxicological Information Effects from Eye Contact: Moderate Eye Irritation: may include redness, swelling, pain, tearing, and blurred or hazy vision. Effects from Skin Contact: Mild Skin Irritation (after prolonged or repeated contact): Page 85 of 1287 Page 85 of 1287 Page 85 of 1287 Page 85 of 1287 ---PAGE BREAK--- can include redness, swelling, and itching. Effects from Inhalation: Central Nervous System Depression: can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. Upper Respiratory Tract Irritation: may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion: Ingestion may cause: Gastrointestinal Irritation: may include abdominal pain, nausea, diarrhea and vomiting. Sensitization Information: No data available. Carcinogenicity: WARNING: Contains a chemical, Bitumens, which can cause cancer. (CAS 8052‐42‐4) (IARC possible human carcinogen 2B, Calif. Proposition 65) Mutagenicity: No data available. Reproductive Effects: No data available. Component Based Information: No data available. Product Based Information: No data available. 3M BRAND UNDERSEAL RUBBERIZED UNDERCOATING 88161, Page 7 of 8 88162 (INACTIVE) 12 Ecological Information Environmental Data: Ecotoxicity Data: No data available. Ecofate Data: Other Effects and Information: Not determined. Since regulations vary, consult applicable regulations or authorities before disposal. 13 Disposal Considerations Product as Sold: No data available. Product Packaging: No data available. Special Instructions: Since regulations vary, consult applicable regulations or authorities before disposal. 14 Transport Information Transportation of Dangerous Goods Page 86 of 1287 Page 86 of 1287 Page 86 of 1287 Page 86 of 1287 ---PAGE BREAK--- TDG Classification: Non‐Regulated Material Special Information: 15 Regulatory Information WHMIS Classification: B3, D2A, D2B NOTE: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. 3M BRAND UNDERSEAL RUBBERIZED UNDERCOATING 88161, Page 8 of 8 88162 (INACTIVE) 16 Other Information Reason for Reissue: The following Sections and topics have been updated or revised: Section 8 ‐ Exposure Controls/Personal Protection The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. Page 87 of 1287 Page 87 of 1287 Page 87 of 1287 Page 87 of 1287 ---PAGE BREAK--- 3M™General Trim Adhesive, PN 08088 04/01/15 Page 1 of 13 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: the information is copied in full with no changes unless prior written agreement is obtained from 3M, and neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 16-6445-7 Version Number: 12.00 Issue Date: 04/01/15 Supercedes Date: 01/10/12 SECTION 1: Identification 1.1. Product identifier 3M™General Trim Adhesive, PN 08088 Product Identification Numbers 60-4550-3005-0, 60-4550-4615-5, 60-4550-4629-6, 60-4550-4837-5, 60-4550-5618-8, 60-9800-4516-9, 60-9801-0537-7 1.2. Recommended use and restrictions on use Recommended use Automotive, Automotive trim adhesive., High strength adhesive for bonding automotive materials (carpeting, fabrics, plastics) to metal and other surfaces. Restrictions on use Not recommended for bonding foam. 1.3. Supplier’s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-[PHONE REDACTED]) 1.4. Emergency telephone number 1-[PHONE REDACTED] or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Aerosol: Category 2. Serious Eye Damage/Irritation: Category 2B. Simple Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (central nervous system): Category 3. Specific Target Organ Toxicity (respiratory irritation): Category 3. 2.2. Label elements Signal word Page 88 of 1287 Page 88 of 1287 Page 88 of 1287 Page 88 of 1287 ---PAGE BREAK--- 3M™General Trim Adhesive, PN 08088 04/01/15 Page 2 of 13 Danger Symbols Flame I Exclamation mark I Health Hazard I Pictograms Hazard Statements Flammable aerosol. Causes eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. May displace oxygen and cause rapid suffocation. Causes damage to organs: cardiovascular system I Precautionary Statements General: Keep out of reach of children. Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Specific treatment (see Notes to Physician on this label). Call a POISON CENTER or doctor/physician if you feel unwell. Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Keep container closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 2.3. Hazards not otherwise classified Page 89 of 1287 Page 89 of 1287 Page 89 of 1287 Page 89 of 1287 ---PAGE BREAK--- 3M™General Trim Adhesive, PN 08088 04/01/15 Page 3 of 13 None. 44% of the mixture consists of ingredients of unknown acute oral toxicity. 54% of the mixture consists of ingredients of unknown acute dermal toxicity. 58% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Dimethyl Ether 115-10-6 30 - 60 Trade Secret * Methyl Acetate 79-20-9 15 - 40 Trade Secret * Non-volatile Components 04499600-7375) Trade Secret* 10 - 20 Trade Secret * Cyclohexane 110-82-7 7 - 13 Trade Secret * 1,1-Difluoroethane 75-37-6 1 - 5 Trade Secret * Hydrotreated Light Petroleum Distillates 64742-47-8 0.5 - 1.5 Trade Secret * Petroleum Distillate 64742-48-9 0.5 - 1.5 Trade Secret * Any remaining components do not contribute to the hazards of this material. NJTS or New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get medical attention. Skin Contact: Wash with soap and water. If develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Page 90 of 1287 Page 90 of 1287 Page 90 of 1287 Page 90 of 1287 ---PAGE BREAK--- 3M™General Trim Adhesive, PN 08088 04/01/15 Page 4 of 13 Substance Condition Aldehydes During Combustion Formaldehyde During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Page 91 of 1287 Page 91 of 1287 Page 91 of 1287 Page 91 of 1287 ---PAGE BREAK--- 3M™General Trim Adhesive, PN 08088 04/01/15 Page 5 of 13 Cyclohexane 110-82-7 ACGIH TWA:100 ppm Cyclohexane 110-82-7 OSHA TWA:1050 mg/m3(300 ppm) Dimethyl Ether 115-10-6 AIHA TWA:1880 mg/m3(1000 ppm) Dimethyl Ether 115-10-6 CMRG TWA:1000 ppm Hydrotreated Light Petroleum Distillates 64742-47-8 CMRG TWA:165 ppm Kerosine (petroleum) 64742-47-8 ACGIH TWA(as total hydrocarbon vapor, non-aerosol):200 mg/m3 A3: Confirmed animal carcin., Skin Notation Naphtha 64742-48-9 OSHA TWA:400 mg/m3(100 ppm) Petroleum Distillate 64742-48-9 Manufacturer determined TWA:100 ppm 1,1-Difluoroethane 75-37-6 AIHA TWA:2700 mg/m3(1000 ppm) 1,1-Difluoroethane 75-37-6 CMRG TWA:1000 ppm Methyl Acetate 79-20-9 ACGIH TWA:200 ppm;STEL:250 ppm Methyl Acetate 79-20-9 OSHA TWA:610 mg/m3(200 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Nitrile Rubber Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece supplied-air respirator For questions about suitability for a specific application, consult with your respirator manufacturer. Page 92 of 1287 Page 92 of 1287 Page 92 of 1287 Page 92 of 1287 ---PAGE BREAK--- 3M™General Trim Adhesive, PN 08088 04/01/15 Page 6 of 13 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Aerosol Odor, Color, Grade: Liquid in aerosol, clear, sweet fruity odor Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point No Data Available Flash Point -40 ºF [Test Method: Tagliabue Closed Cup] Evaporation rate 1.90 [Ref Std: ETHER=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure No Data Available Vapor Density 2.97 [Ref Std: AIR=1] Density 0.781 g/ml [Details: Refers to density of the liquid] Specific Gravity 0.781 [Ref Std: WATER=1] Solubility in Water Nil Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity No Data Available Hazardous Air Pollutants 0.021 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 53.6 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 429 g/l [Test Method: calculated SCAQMD rule 443.1] Percent volatile 86.5 % weight VOC Less H2O & Exempt Solvents 430 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat Sparks and/or flames 10.5. Incompatible materials Strong oxidizing agents Alkali and alkaline earth metals 10.6. Hazardous decomposition products Substance Condition None known. Page 93 of 1287 Page 93 of 1287 Page 93 of 1287 Page 93 of 1287 ---PAGE BREAK--- 3M™General Trim Adhesive, PN 08088 04/01/15 Page 7 of 13 Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Simple may include increased heart rate, rapid respirations, drowsiness, headache, incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal. Respiratory Tract Irritation: may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Mild Skin Irritation: may include localized redness, swelling, itching, and dryness. Eye Contact: Moderate Eye Irritation: may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Cardiac Sensitization: may include irregular heartbeat faintness, chest pain, and may be fatal. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE > 5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE 20 - 50 mg/l Page 94 of 1287 Page 94 of 1287 Page 94 of 1287 Page 94 of 1287 ---PAGE BREAK--- 3M™General Trim Adhesive, PN 08088 04/01/15 Page 8 of 13 Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Dimethyl Ether Inhalation- Gas (4 hours) Rat LC50 164,000 ppm Methyl Acetate Dermal Rat LD50 > 2,000 mg/kg Methyl Acetate Inhalation- Vapor (4 hours) Rat LC50 > 49 mg/l Methyl Acetate Ingestion Rat LD50 > 5,000 mg/kg Cyclohexane Dermal Rat LD50 > 2,000 mg/kg Cyclohexane Inhalation- Vapor (4 hours) Rat LC50 > 32.9 mg/l Cyclohexane Ingestion Rat LD50 6,200 mg/kg Non-volatile Components 04499600-7375) Ingestion Rat LD50 > 34,000 mg/kg 1,1-Difluoroethane Inhalation- Gas (4 hours) Rat LC50 > 437,000 ppm 1,1-Difluoroethane Ingestion Rat LD50 > 1,500 mg/kg Petroleum Distillate Inhalation- Vapor LC50 estimated to be 20 - 50 mg/l Hydrotreated Light Petroleum Distillates Dermal Rabbit LD50 > 3,160 mg/kg Petroleum Distillate Dermal Rabbit LD50 > 3,000 mg/kg Hydrotreated Light Petroleum Distillates Inhalation- Dust/Mist (4 hours) Rat LC50 > 3.0 mg/l Hydrotreated Light Petroleum Distillates Ingestion Rat LD50 > 5,000 mg/kg Petroleum Distillate Ingestion Rat LD50 > 5,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Methyl Acetate Rabbit No significant irritation Cyclohexane Rabbit Mild irritant Hydrotreated Light Petroleum Distillates Rabbit Mild irritant Petroleum Distillate Rabbit Irritant Serious Eye Damage/Irritation Name Species Value Methyl Acetate Rabbit Moderate irritant Cyclohexane Rabbit Mild irritant Hydrotreated Light Petroleum Distillates Rabbit Mild irritant Petroleum Distillate Rabbit No significant irritation Skin Sensitization Name Species Value Methyl Acetate Human Not sensitizing Hydrotreated Light Petroleum Distillates Guinea pig Not sensitizing Petroleum Distillate Guinea pig Not sensitizing Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Dimethyl Ether In Vitro Not mutagenic Dimethyl Ether In vivo Not mutagenic Methyl Acetate In Vitro Not mutagenic Methyl Acetate In vivo Not mutagenic Page 95 of 1287 Page 95 of 1287 Page 95 of 1287 Page 95 of 1287 ---PAGE BREAK--- 3M™General Trim Adhesive, PN 08088 04/01/15 Page 9 of 13 Cyclohexane In Vitro Not mutagenic Cyclohexane In vivo Some positive data exist, but the data are not sufficient for classification 1,1-Difluoroethane In Vitro Some positive data exist, but the data are not sufficient for classification 1,1-Difluoroethane In vivo Some positive data exist, but the data are not sufficient for classification Hydrotreated Light Petroleum Distillates In Vitro Not mutagenic Petroleum Distillate In vivo Not mutagenic Petroleum Distillate In Vitro Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Dimethyl Ether Inhalation Rat Not carcinogenic 1,1-Difluoroethane Inhalation Rat Some positive data exist, but the data are not sufficient for classification Hydrotreated Light Petroleum Distillates Dermal Mouse Some positive data exist, but the data are not sufficient for classification Petroleum Distillate Dermal Mouse Some positive data exist, but the data are not sufficient for classification Petroleum Distillate Inhalation Human and animal Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Dimethyl Ether Inhalation Not toxic to female reproduction Rat NOAEL 25,000 ppm 2 years Dimethyl Ether Inhalation Not toxic to male reproduction Rat NOAEL 25,000 ppm 2 years Dimethyl Ether Inhalation Not toxic to development Rat NOAEL 40,000 ppm during organogenesi s Cyclohexane Inhalation Not toxic to female reproduction Rat NOAEL 24 mg/l 2 generation Cyclohexane Inhalation Not toxic to male reproduction Rat NOAEL 24 mg/l 2 generation Cyclohexane Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 6.9 mg/l 2 generation 1,1-Difluoroethane Inhalation Not toxic to female reproduction Rat NOAEL 25,000 ppm 2 years 1,1-Difluoroethane Inhalation Not toxic to male reproduction Rat NOAEL 25,000 ppm 2 years 1,1-Difluoroethane Inhalation Not toxic to development Rat NOAEL 50,000 ppm during organogenesi s Petroleum Distillate Inhalation Not toxic to development Rat NOAEL 2.4 mg/l during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Dimethyl Ether Inhalation central nervous system depression May cause drowsiness or dizziness Rat LOAEL 10,000 ppm 30 minutes Dimethyl Ether Inhalation cardiac sensitization Some positive data exist, but the data are not sufficient for classification Dog NOAEL 100,000 ppm 5 minutes Page 96 of 1287 Page 96 of 1287 Page 96 of 1287 Page 96 of 1287 ---PAGE BREAK--- 3M™General Trim Adhesive, PN 08088 04/01/15 Page 10 of 13 Methyl Acetate Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Methyl Acetate Inhalation respiratory irritation May cause respiratory irritation Human and animal NOAEL Not available Methyl Acetate Inhalation blindness Some positive data exist, but the data are not sufficient for classification NOAEL Not available Methyl Acetate Ingestion central nervous system depression May cause drowsiness or dizziness NOAEL Not available Cyclohexane Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Cyclohexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available 1,1-Difluoroethane Inhalation cardiac sensitization Causes damage to organs Human and animal NOAEL Not available poisoning and/or abuse 1,1-Difluoroethane Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL 100,000 ppm 1,1-Difluoroethane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Not available NOAEL Not available not available Hydrotreated Light Petroleum Distillates Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Hydrotreated Light Petroleum Distillates Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Petroleum Distillate Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Petroleum Distillate Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Petroleum Distillate Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Dog NOAEL 6.5 mg/l 4 hours Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Dimethyl Ether Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 25,000 ppm 2 years Dimethyl Ether Inhalation liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 20,000 ppm 30 weeks Methyl Acetate Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 28 days Methyl Acetate Inhalation endocrine system I hematopoietic system I liver I immune system I kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 6.1 mg/l 28 days Cyclohexane Inhalation liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 24 mg/l 90 days Cyclohexane Inhalation auditory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.7 mg/l 90 days Cyclohexane Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for Rabbit NOAEL 2.7 mg/l 10 weeks Page 97 of 1287 Page 97 of 1287 Page 97 of 1287 Page 97 of 1287 ---PAGE BREAK--- 3M™General Trim Adhesive, PN 08088 04/01/15 Page 11 of 13 classification Cyclohexane Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 24 mg/l 14 weeks Cyclohexane Inhalation peripheral nervous system All data are negative Rat NOAEL 8.6 mg/l 30 weeks 1,1-Difluoroethane Inhalation hematopoietic system I kidney and/or bladder I respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 25,000 ppm 2 years Petroleum Distillate Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 4.6 mg/l 6 months Petroleum Distillate Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat LOAEL 1.9 mg/l 13 weeks Petroleum Distillate Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 0.6 mg/l 90 days Petroleum Distillate Inhalation bone, teeth, nails, and/or hair I blood I liver I muscles All data are negative Rat NOAEL 5.6 mg/l 12 weeks Petroleum Distillate Inhalation heart All data are negative Multiple animal species NOAEL 1.3 mg/l 90 days Aspiration Hazard Name Value Cyclohexane Aspiration hazard Hydrotreated Light Petroleum Distillates Aspiration hazard Petroleum Distillate Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate uncured product in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information Page 98 of 1287 Page 98 of 1287 Page 98 of 1287 Page 98 of 1287 ---PAGE BREAK--- 3M™General Trim Adhesive, PN 08088 04/01/15 Page 12 of 13 For Transport Information, please visit http://3M.com/Transportinfo or call 1-[PHONE REDACTED] or [PHONE REDACTED]. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Cyclohexane 110-82-7 7 - 13 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 4 Instability: 0 Special Hazards: None Aerosol Storage Code: 2 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 16-6445-7 Version Number: 12.00 Issue Date: 04/01/15 Supercedes Date: 01/10/12 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. Page 99 of 1287 Page 99 of 1287 Page 99 of 1287 Page 99 of 1287 ---PAGE BREAK--- 3M™General Trim Adhesive, PN 08088 04/01/15 Page 13 of 13 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com Page 100 of 1287 Page 100 of 1287 Page 100 of 1287 Page 100 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Slip Fit/High Strength Retaining Compound RT80 (formerly sold as Rite-Lok™Slip Fit/High Strength Retaining Compound RT80-10, RT80-50, RT80-250, & RT80-1L) 12/10/12 Page 1 of 9 Material Safety Data Sheet Copyright, 2012, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: the information is copied in full with no changes unless prior written agreement is obtained from 3M, and neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M(TM) Scotch-Weld(TM) Slip Fit/High Strength Retaining Compound RT80 (formerly sold as Rite-Lok™Slip Fit/High Strength Retaining Compound RT80-10, RT80-50, RT80- 250, & RT80-1L) MANUFACTURER: 3M DIVISION: Industrial Adhesives and Tapes Division ADDRESS: 3M Center, St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-[PHONE REDACTED] or (651) 737-6501 (24 hours) Issue Date: 12/10/12 Supercedes Date: 02/12/10 Document Group: 22-6373-9 Product Use: Specific Use: Anaerobic retaining compound Intended Use: Sealant SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt Bisphenol A bis(2-Hydroxyethyl Ether) Dimethacrylate 24448-20-2 40 - 70 Polyester Resin Trade Secret 10 - 30 Hydroxyalkyl Methacrylate 27813-02-1 10 - 30 Cumene Hydroperoxide 80-15-9 1 - 5 Triethylene Glycol Dimethacrylate 109-16-0 1 - 5 Methyl Alcohol 67-56-1 0.1 - 1 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Odor, Color, Grade: Green liquid with sharp odor. General Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause severe eye irritation. May cause allergic skin reaction. Page 101 of 1287 Page 101 of 1287 Page 101 of 1287 Page 101 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Slip Fit/High Strength Retaining Compound RT80 (formerly sold as Rite-Lok™Slip Fit/High Strength Retaining Compound RT80-10, RT80-50, RT80-250, & RT80-1L) 12/10/12 Page 2 of 9 May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Severe Eye Irritation: may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Vapors released during curing may cause eye irritation. may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Moderate Skin Irritation: may include localized redness, swelling, itching, and dryness. Prolonged or repeated exposure may cause: Allergic Skin Reaction (non-photo induced): may include redness, swelling, blistering, and itching. May be absorbed through skin and cause target organ effects. Inhalation: Respiratory Tract Irritation: may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Prolonged or repeated exposure may cause: Respiratory Effects: may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Prolonged or repeated exposure may cause: Neurological Effects: may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Page 102 of 1287 Page 102 of 1287 Page 102 of 1287 Page 102 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Slip Fit/High Strength Retaining Compound RT80 (formerly sold as Rite-Lok™Slip Fit/High Strength Retaining Compound RT80-10, RT80-50, RT80-250, & RT80-1L) 12/10/12 Page 3 of 9 Inhalation: Remove person to fresh air. If develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point >=200 ºF [Test Method: Closed Cup] Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Water may be used to blanket the fire. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards are anticipated. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Collect the resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Clean-up methods Observe precautions from other sections. Call 3M- HELPS line (1-[PHONE REDACTED]) for more information on handling and managing the spill. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. Page 103 of 1287 Page 103 of 1287 Page 103 of 1287 Page 103 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Slip Fit/High Strength Retaining Compound RT80 (formerly sold as Rite-Lok™Slip Fit/High Strength Retaining Compound RT80-10, RT80-50, RT80-250, & RT80-1L) 12/10/12 Page 4 of 9 SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Avoid eye contact. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid breathing of vapors, mists or spray. Avoid skin contact. Keep out of the reach of children. For industrial or professional use only. Avoid contact with oxidizing agents. 7.2 STORAGE Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Keep container closed. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact. The following eye protection(s) are recommended: Safety Glasses with side shields Indirect Vented Goggles 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Butyl Rubber Neoprene Polyvinyl Chloride . 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors For questions about suitability for a specific application, consult with your respirator manufacturer. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Page 104 of 1287 Page 104 of 1287 Page 104 of 1287 Page 104 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Slip Fit/High Strength Retaining Compound RT80 (formerly sold as Rite-Lok™Slip Fit/High Strength Retaining Compound RT80-10, RT80-50, RT80-250, & RT80-1L) 12/10/12 Page 5 of 9 Ingredient Authority Type Limit Additional Information Cumene Hydroperoxide AIHA TWA 6 mg/m3 Skin Notation* Hydroxyalkyl Methacrylate CMRG CEIL 3 ppm Methyl Alcohol ACGIH TWA 200 ppm Skin Notation* Methyl Alcohol ACGIH STEL 250 ppm Skin Notation* Methyl Alcohol OSHA TWA 260 mg/m3 * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Odor, Color, Grade: Green liquid with sharp odor. General Physical Form: Liquid Autoignition temperature No Data Available Flash Point >=200 ºF [Test Method: Closed Cup] Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Boiling Point >=149 ºC Density 1.12 g/ml Vapor Density No Data Available Vapor Pressure <=10 mmHg 80 ºF] Specific Gravity 1.12 [Ref Std: WATER=1] pH Not Applicable Melting point Not Applicable Solubility in Water Slight (less than 10%) Evaporation rate No Data Available Evaporation rate Negligible Hazardous Air Pollutants 0.55 - 0.75 % weight [Test Method: Calculated] Volatile Organic Compounds < 3 % weight [Test Method: tested per EPA method 24] [Details: EU VOC content] Kow - Oct/Water partition coef No Data Available Percent volatile % weight [Test Method: ACS METHOD] VOC Less H2O & Exempt Solvents < 30 g/l [Test Method: tested per EPA method 24] Viscosity 1300 - 2000 centipoise 73.4 ºF] SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid Page 105 of 1287 Page 105 of 1287 Page 105 of 1287 Page 105 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Slip Fit/High Strength Retaining Compound RT80 (formerly sold as Rite-Lok™Slip Fit/High Strength Retaining Compound RT80-10, RT80-50, RT80-250, & RT80-1L) 12/10/12 Page 6 of 9 Heat Light Sparks and/or flames 10.2 Materials to avoid Reducing agents Strong oxidizing agents Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Formaldehyde During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Irritant Vapors or Gases During Combustion Oxides of Nitrogen During Combustion Oxides of Sulfur During Combustion SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Cure (harden, set, or react) the product according to product instructions. Dispose of completely cured (or polymerized) wastes in a sanitary landfill. As a disposal alternative, incinerate in an industrial or commercial facility in the presence of a combustible material. EPA Hazardous Waste Number (RCRA): Not regulated Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): Page 106 of 1287 Page 106 of 1287 Page 106 of 1287 Page 106 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Slip Fit/High Strength Retaining Compound RT80 (formerly sold as Rite-Lok™Slip Fit/High Strength Retaining Compound RT80-10, RT80-50, RT80-250, & RT80-1L) 12/10/12 Page 7 of 9 62-3437-1050-5, 62-3437-1055-4, 62-3437-3950-4, 62-3437-5050-1, 62-3437-8350-2 Not regulated per U.S. DOT, IATA or IMO. These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M transportation classifications are based on product formulation, packaging, 3M policies and 3M understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory requirements. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Cumene Hydroperoxide 80-15-9 1 - 5 STATE REGULATIONS Contact 3M for more information. CALIFORNIA PROPOSITION 65 Ingredient C.A.S. No. Classification Methyl Alcohol 67-56-1 *Developmental Toxin * WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 2 Flammability: 1 Reactivity: 1 Special Hazards: None Page 107 of 1287 Page 107 of 1287 Page 107 of 1287 Page 107 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Slip Fit/High Strength Retaining Compound RT80 (formerly sold as Rite-Lok™Slip Fit/High Strength Retaining Compound RT80-10, RT80-50, RT80-250, & RT80-1L) 12/10/12 Page 8 of 9 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 1: Product use information was modified. Section 16: Disclaimer (second paragraph) was modified. Section 10: Hazardous decomposition or by-products table was modified. Section 8: Eye/face protection information was modified. Section 8: Skin protection - recommended gloves information was modified. Section 8: Respiratory protection - recommended respirators information was modified. Section 8: Respiratory protection - recommended respirators was modified. Section 14: Transportation legal text was modified. Section 9: Density information was modified. Section 9: Vapor density value was modified. Section 9: Vapor pressure value was modified. Section 9: Boiling point information was modified. Section 5: Flammable limits (UE) information was modified. Section 5: Flammable limits (LEL) information was modified. Section 5: Autoignition temperature information was modified. Section 5: Flash point information was modified. Section 9: Property description for optional properties was modified. Section 9: Specific gravity information was modified. Section 9: pH information was modified. Section 9: Melting point information was modified. Section 9: Solubility in water text was modified. Section 8: Respiratory protection - recommended respirators guide was modified. Section 9: Flash point information was modified. Section 9: Flammable limits (LEL) information was modified. Section 9: Flammable limits (UEL) information was modified. Section 9: Autoignition temperature information was modified. Section 2: Ingredient table was modified. Section 15: EPCRA 313 information was modified. Section 8: Exposure guidelines ingredient information was modified. Section 10: Materials to avoid physical property was modified. Section 10: Conditions to avoid physical property was modified. Section 15: California proposition 65 reproductive harm warning was added. Section 15: California proposition 65 ingredient information was added. Section 15: California proposition 65 heading was added. Section 6: 6.2. Environmental precautions heading was added. Section 6: 6.1. Personal precautions, protective equipment and emergency procedures heading was added. Section 16: Web address was added. Section 1: Address was added. Copyright was added. Company logo was added. Section 6: Clean-up methods heading was added. Telephone header was added. Company Telephone was added. Section 1: Emergency phone information was added. Section 1: Emergency phone information was deleted. Company Logo was deleted. Copyright was deleted. Section 16: Web address heading was deleted. Page 108 of 1287 Page 108 of 1287 Page 108 of 1287 Page 108 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Slip Fit/High Strength Retaining Compound RT80 (formerly sold as Rite-Lok™Slip Fit/High Strength Retaining Compound RT80-10, RT80-50, RT80-250, & RT80-1L) 12/10/12 Page 9 of 9 Section 6: Release measures heading was deleted. Section 1: Address line 1 was deleted. Section 1: Address line 2 was deleted. Section 8: Respiratory protection - recommended respirators punctuation was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M 3M USA are available at www.3M.com Page 109 of 1287 Page 109 of 1287 Page 109 of 1287 Page 109 of 1287 ---PAGE BREAK--- 3M™Windo-Weld™Super Fast Urethane PN 08609 02/04/15 Page 1 of 13 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: the information is copied in full with no changes unless prior written agreement is obtained from 3M, and neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 09-5003-0 Version Number: 12.00 Issue Date: 02/04/15 Supercedes Date: 06/23/14 SECTION 1: Identification 1.1. Product identifier 3M™Windo-Weld™Super Fast Urethane PN 08609 Product Identification Numbers 60-9800-3692-9 1.2. Recommended use and restrictions on use Recommended use Adhesive, Adhesive/Sealant for Windshields 1.3. Supplier’s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-[PHONE REDACTED]) 1.4. Emergency telephone number 1-[PHONE REDACTED] or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Serious Eye Damage/Irritation: Category 2A. Skin Corrosion/Irritation: Category 2. Respiratory Sensitizer: Category 1. Skin Sensitizer: Category 1. Reproductive Toxicity: Category 1B. Carcinogenicity: Category 2. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger Page 110 of 1287 Page 110 of 1287 Page 110 of 1287 Page 110 of 1287 ---PAGE BREAK--- 3M™Windo-Weld™Super Fast Urethane PN 08609 02/04/15 Page 2 of 13 Symbols Health Hazard I Pictograms Hazard Statements Causes serious eye irritation. Causes skin irritation. May cause allergy or asthma or breathing difficulties if inhaled. May cause an allergic skin reaction. May damage fertility or the unborn child. Suspected of causing cancer. Causes damage to organs through prolonged or repeated exposure: nervous system I sensory organs I Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. In case of inadequate ventilation wear respiratory protection. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: If breathing is difficult, remove person to fresh air and keep comfortable for breathing. If experiencing respiratory Call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Get medical advice/attention if you feel unwell. Storage: Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. Page 111 of 1287 Page 111 of 1287 Page 111 of 1287 Page 111 of 1287 ---PAGE BREAK--- 3M™Windo-Weld™Super Fast Urethane PN 08609 02/04/15 Page 3 of 13 42% of the mixture consists of ingredients of unknown acute dermal toxicity. 97% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Urethane Polymer 68130-40-5 30 - 60 Trade Secret * Sulfonic Acids, C10-18-Alkane, Ph Esters 70775-94-9 10 - 30 Trade Secret * Carbon Black 1333-86-4 10 - 30 Trade Secret * Kaolin, Calcined 92704-41-1 10 - 20 Trade Secret * Toluene 108-88-3 1 - 5 Trade Secret * Hydrotreated Light Petroleum Distillates 64742-47-8 1 - 5 Trade Secret * Dibutyltin Dichloride 683-18-1 < 0.1 Trade Secret * P,P'-Methylenebis(phenyl isocyanate) 101-68-8 < 0.2 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media DO NOT USE WATER 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Page 112 of 1287 Page 112 of 1287 Page 112 of 1287 Page 112 of 1287 ---PAGE BREAK--- 3M™Windo-Weld™Super Fast Urethane PN 08609 02/04/15 Page 4 of 13 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Pour isocyanate decontaminant solution (90% water, 8% concentrated ammonia, 2% detergent) on spill and allow to react for 10 minutes. Or pour water on spill and allow to react for more than 30 minutes. Cover with absorbent material. Vacuum or sweep up. WARNING ! A motor could be an ignition source and cause flammable gases or vapors or dust in the spill area to burn or explode. Place in a container approved for transportation by appropriate authorities, but do not seal the container for 48 hours to avoid pressure build-up. Clean up residue. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Keep away from reactive metals (eg. Aluminum, zinc etc.) to avoid the formation of hydrogen gas that could create an explosion hazard. Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Keep container closed to prevent contamination with water or air. If contamination is suspected, do not reseal container. Store away from heat. Store away from acids. Store away from strong bases. Store away from oxidizing agents. Store away from amines. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments P,P'-Methylenebis(phenyl isocyanate) 101-68-8 ACGIH TWA:0.005 ppm FREE ISOCYANATES 101-68-8 Manufacturer determined TWA:0.005 ppm;STEL:0.02 ppm P,P'-Methylenebis(phenyl isocyanate) 101-68-8 OSHA CEIL:0.2 mg/m3(0.02 ppm) Toluene 108-88-3 CMRG STEL:75 ppm Skin Notation Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human Page 113 of 1287 Page 113 of 1287 Page 113 of 1287 Page 113 of 1287 ---PAGE BREAK--- 3M™Windo-Weld™Super Fast Urethane PN 08609 02/04/15 Page 5 of 13 carcin Carbon Black 1333-86-4 CMRG TWA:0.5 mg/m3 Carbon Black 1333-86-4 ACGIH TWA(inhalable fraction):3 mg/m3 A3: Confirmed animal carcin. Carbon Black 1333-86-4 OSHA TWA:3.5 mg/m3 Kerosine (petroleum) 64742-47-8 ACGIH TWA(as total hydrocarbon vapor, non-aerosol):200 mg/m3 A3: Confirmed animal carcin., Skin Notation Hydrotreated Light Petroleum Distillates 64742-47-8 CMRG TWA:165 ppm TIN, ORGANIC COMPOUNDS 683-18-1 OSHA TWA(as Sn):0.1 mg/m3 TIN, ORGANIC COMPOUNDS 683-18-1 ACGIH TWA(as Sn):0.1 mg/m3;STEL(as Sn):0.2 mg/m3 A4: Not class. as human carcin, Skin Notation ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Provide ventilated enclosure for heat curing. Curing enclosures must be exhausted to outdoors or to a suitable emission control device. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Nitrile Rubber If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron – Nitrile Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates Page 114 of 1287 Page 114 of 1287 Page 114 of 1287 Page 114 of 1287 ---PAGE BREAK--- 3M™Windo-Weld™Super Fast Urethane PN 08609 02/04/15 Page 6 of 13 For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Solid Specific Physical Form: Paste Odor, Color, Grade: Neutral odor Black color pH Not Applicable Melting point No Data Available Boiling Point 110 ºC Flash Point No flash point Evaporation rate No Data Available Flammability (solid, gas) Not Classified Flammable Limits(LEL) 1.2 % volume Flammable Limits(UEL) 7.1 % volume Vapor Pressure 29 mbar [Ref Std: AIR=1] Vapor Density 3.14 [Ref Std: AIR=1] Density 1.205 g/cm3 Specific Gravity 1.2 [Ref Std: WATER=1] Solubility in Water Negligible Solubility- non-water No Data Available Autoignition temperature 450 ºC Viscosity No Data Available Hazardous Air Pollutants 0.0590 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 70 g/l [Test Method: calculated SCAQMD rule 443.1] Percent volatile 5.8 % weight VOC Less H2O & Exempt Solvents 70 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat High shear and high temperature conditions Sparks and/or flames Temperatures above the boiling point 10.5. Incompatible materials Amines Alcohols Water Reaction with water, alcohols, and amines is not hazardous if container can vent to the atmosphere to prevent pressure buildup. Accelerators Page 115 of 1287 Page 115 of 1287 Page 115 of 1287 Page 115 of 1287 ---PAGE BREAK--- 3M™Windo-Weld™Super Fast Urethane PN 08609 02/04/15 Page 7 of 13 Al or Mg powder and high/shear temperature conditions Alkali and alkaline earth metals Reactive metals Reducing agents Strong acids Strong bases Strong oxidizing agents Combustibles Finely divided active metals Reaction with water, alcohols, and amines is not hazardous if container can vent to the atmosphere to prevent pressure buildup. 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Respiratory Tract Irritation: may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Allergic Respiratory Reaction: may include difficulty breathing, wheezing, cough, and tightness of chest. May cause additional health effects (see below). Skin Contact: Skin Irritation: may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Allergic Skin Reaction (non-photo induced): may include redness, swelling, blistering, and itching. Eye Contact: Severe Eye Irritation: may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: May be harmful if swallowed. Gastrointestinal Irritation: may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Page 116 of 1287 Page 116 of 1287 Page 116 of 1287 Page 116 of 1287 ---PAGE BREAK--- 3M™Windo-Weld™Super Fast Urethane PN 08609 02/04/15 Page 8 of 13 Additional Health Effects: Prolonged or repeated exposure may cause target organ effects: Ocular Effects: may include blurred or significantly impaired vision. Auditory Effects: may include hearing impairment, balance dysfunction and ringing in the ears. Olfactory Effects: may include decreased ability to detect odors and/or complete loss of smell. Neurological Effects: may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation Carbon Black 1333-86-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Additional Information: Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE > 5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE 20 - 50 mg/l Overall product Ingestion No data available; calculated ATE 2,000 - 5,000 mg/kg Urethane Polymer Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Sulfonic Acids, C10-18-Alkane, Ph Esters Dermal Rat LD50 > 1,000 mg/kg Sulfonic Acids, C10-18-Alkane, Ph Esters Ingestion Rat LD50 > 5,000 mg/kg Carbon Black Dermal Rabbit LD50 > 3,000 mg/kg Carbon Black Ingestion Rat LD50 > 8,000 mg/kg Kaolin, Calcined Ingestion Rat LD50 > 2,000 mg/kg Toluene Dermal Rat LD50 12,000 mg/kg Toluene Inhalation- Vapor (4 hours) Rat LC50 30 mg/l Toluene Ingestion Rat LD50 5,550 mg/kg Hydrotreated Light Petroleum Distillates Dermal Rabbit LD50 > 3,160 mg/kg Hydrotreated Light Petroleum Distillates Inhalation- Dust/Mist (4 hours) Rat LC50 > 3.0 mg/l Hydrotreated Light Petroleum Distillates Ingestion Rat LD50 > 5,000 mg/kg P,P'-Methylenebis(phenyl isocyanate) Inhalation- Vapor LC50 estimated to be 10 - 20 mg/l P,P'-Methylenebis(phenyl isocyanate) Dermal Rabbit LD50 > 5,000 mg/kg P,P'-Methylenebis(phenyl isocyanate) Inhalation- Dust/Mist (4 hours) Rat LC50 0.369 mg/l P,P'-Methylenebis(phenyl isocyanate) Ingestion Rat LD50 31,600 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Page 117 of 1287 Page 117 of 1287 Page 117 of 1287 Page 117 of 1287 ---PAGE BREAK--- 3M™Windo-Weld™Super Fast Urethane PN 08609 02/04/15 Page 9 of 13 Name Species Value Carbon Black Rabbit No significant irritation Toluene Rabbit Irritant Hydrotreated Light Petroleum Distillates Rabbit Mild irritant P,P'-Methylenebis(phenyl isocyanate) official classifica tion Irritant Serious Eye Damage/Irritation Name Species Value Carbon Black Rabbit No significant irritation Toluene Rabbit Moderate irritant Hydrotreated Light Petroleum Distillates Rabbit Mild irritant P,P'-Methylenebis(phenyl isocyanate) official classifica tion Severe irritant Skin Sensitization Name Species Value Toluene Guinea pig Not sensitizing Hydrotreated Light Petroleum Distillates Guinea pig Not sensitizing P,P'-Methylenebis(phenyl isocyanate) official classifica tion Sensitizing Respiratory Sensitization Name Species Value P,P'-Methylenebis(phenyl isocyanate) Human Sensitizing Germ Cell Mutagenicity Name Route Value Carbon Black In Vitro Not mutagenic Carbon Black In vivo Some positive data exist, but the data are not sufficient for classification Toluene In Vitro Not mutagenic Toluene In vivo Not mutagenic Hydrotreated Light Petroleum Distillates In Vitro Not mutagenic P,P'-Methylenebis(phenyl isocyanate) In Vitro Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Carbon Black Dermal Mouse Not carcinogenic Carbon Black Ingestion Mouse Not carcinogenic Carbon Black Inhalation Rat Carcinogenic Toluene Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Ingestion Rat Some positive data exist, but the data are not sufficient for classification Toluene Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Hydrotreated Light Petroleum Distillates Dermal Mouse Some positive data exist, but the data are not sufficient for classification P,P'-Methylenebis(phenyl isocyanate) Inhalation Rat Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Page 118 of 1287 Page 118 of 1287 Page 118 of 1287 Page 118 of 1287 ---PAGE BREAK--- 3M™Windo-Weld™Super Fast Urethane PN 08609 02/04/15 Page 10 of 13 Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Toluene Inhalation Some positive female reproductive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Toluene Inhalation Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 2.3 mg/l 1 generation Toluene Ingestion Toxic to development Rat LOAEL 520 mg/kg/day during gestation Toluene Inhalation Toxic to development Human NOAEL Not available poisoning and/or abuse P,P'-Methylenebis(phenyl isocyanate) Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 0.004 mg/l during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Toluene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Toluene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Toluene Inhalation immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 0.004 mg/l 3 hours Toluene Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Hydrotreated Light Petroleum Distillates Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Hydrotreated Light Petroleum Distillates Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available P,P'-Methylenebis(phenyl isocyanate) Inhalation respiratory irritation May cause respiratory irritation official classifica tion NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Carbon Black Inhalation pneumoconiosis Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Toluene Inhalation auditory system I nervous system I eyes I olfactory system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Toluene Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 2.3 mg/l 15 months Toluene Inhalation heart I liver I kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 11.3 mg/l 15 weeks Toluene Inhalation endocrine system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 4 weeks Toluene Inhalation immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL Not available 20 days Toluene Inhalation bone, teeth, nails, and/or hair Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1.1 mg/l 8 weeks Page 119 of 1287 Page 119 of 1287 Page 119 of 1287 Page 119 of 1287 ---PAGE BREAK--- 3M™Windo-Weld™Super Fast Urethane PN 08609 02/04/15 Page 11 of 13 Toluene Inhalation hematopoietic system I vascular system Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Toluene Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 625 mg/kg/day 13 weeks Toluene Ingestion heart Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion liver I kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion hematopoietic system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 600 mg/kg/day 14 days Toluene Ingestion endocrine system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 105 mg/kg/day 28 days Toluene Ingestion immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 105 mg/kg/day 4 weeks P,P'-Methylenebis(phenyl isocyanate) Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.004 mg/l 13 weeks Aspiration Hazard Name Value Toluene Aspiration hazard Hydrotreated Light Petroleum Distillates Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. If no other disposal options are available, waste product that has been completely cured or polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information Page 120 of 1287 Page 120 of 1287 Page 120 of 1287 Page 120 of 1287 ---PAGE BREAK--- 3M™Windo-Weld™Super Fast Urethane PN 08609 02/04/15 Page 12 of 13 For Transport Information, please visit http://3M.com/Transportinfo or call 1-[PHONE REDACTED] or [PHONE REDACTED]. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - Yes Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Toluene 108-88-3 1 - 5 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification Toluene 108-88-3 Female reproductive toxin Toluene 108-88-3 Developmental Toxin Carbon Black 1333-86-4 Carcinogen WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. WARNING: This product contains a chemical known to the State of California to cause cancer. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 1 Instability: 1 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Page 121 of 1287 Page 121 of 1287 Page 121 of 1287 Page 121 of 1287 ---PAGE BREAK--- 3M™Windo-Weld™Super Fast Urethane PN 08609 02/04/15 Page 13 of 13 Document Group: 09-5003-0 Version Number: 12.00 Issue Date: 02/04/15 Supercedes Date: 06/23/14 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com Page 122 of 1287 Page 122 of 1287 Page 122 of 1287 Page 122 of 1287 ---PAGE BREAK--- Page 123 of 1287 Page 123 of 1287 Page 123 of 1287 Page 123 of 1287 ---PAGE BREAK--- Page 124 of 1287 Page 124 of 1287 Page 124 of 1287 Page 124 of 1287 ---PAGE BREAK--- 1. IDENTIFICATION Product identifier Product Name 765-1221 NAPA HIGH TACK GASKET SEALANT(PTX80062) 4 FL.OZ Other means of identification Product Code 21146 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Sealant Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: [PHONE REDACTED] International Emergency: 00+1+ [PHONE REDACTED] Contract Number: MIS0003453 E-mail address [EMAIL REDACTED] 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Category 3 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Skin sensitization Category 1 Reproductive toxicity Category 2 Specific target organ toxicity (single exposure) Category 3 Specific target organ toxicity (repeated exposure) Category 2 Label elements Emergency Overview Page 1 / 9 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Danger Flammable liquids Category 2 Revision Date 15-Jun-2015 SAFETY DATA SHEET Version 1 Page 125 of 1287 Page 125 of 1287 Page 125 of 1287 Page 125 of 1287 ---PAGE BREAK--- Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Contaminated work clothing should not be allowed out of the workplace Do not breathe dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. — No smoking Keep container closed Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting/equipment Use only non-sparking tools Take precautionary measures against static discharge Keep cool Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention If skin irritation or rash occurs: Get medical advice/attention IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting Rinse mouth In case of fire: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep container closed Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Page 2 / 9 Toxic if swallowed Causes skin irritation Causes serious eye irritation May cause an allergic skin reaction Suspected of damaging fertility or the unborn child May cause drowsiness or dizziness May cause damage to organs through prolonged or repeated exposure Revision Date 15-Jun-2015 Highly flammable liquid and vapor 21146 - 765-1221 NAPA HIGH TACK GASKET SEALANT(PTX80062) 4 FL.OZ Odor Solvent Appearance Red Physical state Liquid Page 126 of 1287 Page 126 of 1287 Page 126 of 1287 Page 126 of 1287 ---PAGE BREAK--- Other Information Toxic to aquatic life with long lasting effects Aspiration hazard: Does not apply Unknown acute toxicity 35.4066 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret ACETONE 67-64-1 15 - 40 * METHYL ESTER OF ROSIN 68186-14-1 10 - 30 * N-HEXANE 110-54-3 10 - 30 * ROSIN 8050-09-7 7 - 13 * ACRYLONITRILE-BUTADIENE POLYMER 9003-18-3 5 - 10 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If persist, call a physician. Ingestion IF SWALLOWED:. Call a physician or poison control center immediately. Do NOT induce vomiting. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important and effects, both acute and delayed See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Page 3 / 9 21146 - 765-1221 NAPA HIGH TACK GASKET SEALANT(PTX80062) 4 FL.OZ Revision Date 15-Jun-2015 Page 127 of 1287 Page 127 of 1287 Page 127 of 1287 Page 127 of 1287 ---PAGE BREAK--- Specific hazards arising from the chemical Extremely flammable. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Remove all sources of ignition. Environmental precautions Environmental precautions See Section 12 for additional ecological information. Do not flush into surface water or sanitary sewer system. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Remove all sources of ignition. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Conditions for safe storage, including any incompatibilities Storage Conditions Keep away from heat, sparks, flame and other sources of ignition pilot lights, electric motors and static electricity). Store locked up. Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Page 4 / 9 21146 - 765-1221 NAPA HIGH TACK GASKET SEALANT(PTX80062) 4 FL.OZ Revision Date 15-Jun-2015 Page 128 of 1287 Page 128 of 1287 Page 128 of 1287 Page 128 of 1287 ---PAGE BREAK--- ACETONE 67-64-1 STEL: 750 ppm TWA: 500 ppm TWA: 1000 ppm TWA: 2400 mg/m3 (vacated) TWA: 750 ppm (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors (vacated) STEL: 1000 ppm IDLH: 2500 ppm TWA: 250 ppm TWA: 590 mg/m3 N-HEXANE 110-54-3 TWA: 50 ppm S* TWA: 500 ppm TWA: 1800 mg/m3 (vacated) TWA: 50 ppm (vacated) TWA: 180 mg/m3 IDLH: 1100 ppm TWA: 50 ppm TWA: 180 mg/m3 ROSIN 8050-09-7 - (vacated) TWA: 0.1 mg/m3 Formaldehyde TWA: 0.1 mg/m3 Formaldehyde NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Red Odor Solvent Odor threshold No information available Page 5 / 9 Ether = 1 Flammability (solid, gas) No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: 13.0% Values Lower flammability limit: 2.0% Vapor pressure 400 mm Hg Boiling point / boiling range 57 °C / 135 °F Vapor density 2.5 Remarks • Method Air = 1 Relative density 0.872 21146 - 765-1221 NAPA HIGH TACK GASKET SEALANT(PTX80062) 4 FL.OZ Flash point Water solubility Partially soluble -18 °C / 0 °F pH No information available Evaporation rate > 1 Revision Date 15-Jun-2015 Page 129 of 1287 Page 129 of 1287 Page 129 of 1287 Page 129 of 1287 ---PAGE BREAK--- Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content 16.6% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May be harmful by inhalation. May cause drowsiness or dizziness. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Toxic if swallowed. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 ACETONE 67-64-1 = 5800 mg/kg ( Rat ) - = 50100 mg/m3 ( Rat ) 8 h N-HEXANE 110-54-3 = 25 g/kg ( Rat ) = 3000 mg/kg ( Rabbit ) = 48000 ppm ( Rat ) 4 h ROSIN 8050-09-7 = 3 mg/kg ( Rat ) = 7600 mg/kg ( Rat ) > 2500 mg/kg ( Rabbit ) = 1.5 mg/L ( Rat ) 4 h Information on toxicological effects No information available. Page 6 / 9 Partition coefficient No information available Dynamic viscosity No information available 21146 - 765-1221 NAPA HIGH TACK GASKET SEALANT(PTX80062) 4 FL.OZ No data available Solubility in other solvents Autoignition temperature No information available No information available Revision Date 15-Jun-2015 Decomposition temperature No information available Kinematic viscosity No information available Page 130 of 1287 Page 130 of 1287 Page 130 of 1287 Page 130 of 1287 ---PAGE BREAK--- Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. IARC (International Agency for Research on Cancer) Not classifiable as a human carcinogen Target Organ Effects Central nervous system, Eyes, Peripheral Nervous System (PNS), Respiratory system, Skin, Thyroid. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 17 mg/kg ATEmix (dermal) 6387 mg/kg ATEmix (inhalation-dust/mist) 178.2 mg/l ATEmix (inhalation-vapor) 186367 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 35.6183 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea ACETONE 67-64-1 - 4.74 - 6.33: 96 h mykiss mL/L LC50 6210 - 8120: 96 h Pimephales promelas mg/L LC50 static 8300: 96 h Lepomis macrochirus mg/L LC50 10294 - 17704: 48 h Daphnia magna mg/L EC50 Static 12600 - 12700: 48 h Daphnia magna mg/L EC50 N-HEXANE 110-54-3 - 2.1 - 2.98: 96 h Pimephales promelas mg/L LC50 flow-through 1000: 24 h Daphnia magna mg/L EC50 ROSIN 8050-09-7 400: 72 h Desmodesmus subspicatus mg/L EC50 - 3.8 - 5.4: 48 h Daphnia magna mg/L EC50 Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient ACETONE 67-64-1 -0.24 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not reuse container. US EPA Waste Number D001 Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes ACETONE 67-64-1 - Included in waste stream: F039 - U002 Page 7 / 9 Revision Date 15-Jun-2015 21146 - 765-1221 NAPA HIGH TACK GASKET SEALANT(PTX80062) 4 FL.OZ Page 131 of 1287 Page 131 of 1287 Page 131 of 1287 Page 131 of 1287 ---PAGE BREAK--- This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status ACETONE 67-64-1 Ignitable N-HEXANE 110-54-3 Toxic Ignitable 14. TRANSPORT INFORMATION DOT UN/ID no 1133 Proper shipping name: Adhesives, Limited Quantity (LQ) Hazard Class 3 Packing Group II Emergency Response Guide Number 128 IATA UN/ID no ID 8000 Proper shipping name: Consumer commodity Hazard Class 9 ERG Code 9L IMDG UN/ID no 1133 Proper shipping name: Adhesives, Limited Quantity (LQ) Hazard Class 3 Packing Group II EmS-No F-E, S-D 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Not Listed. ENCS Not Listed. IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Page 8 / 9 21146 - 765-1221 NAPA HIGH TACK GASKET SEALANT(PTX80062) 4 FL.OZ Revision Date 15-Jun-2015 Page 132 of 1287 Page 132 of 1287 Page 132 of 1287 Page 132 of 1287 ---PAGE BREAK--- Chemical Name SARA 313 - Threshold Values % N-HEXANE - 110-54-3 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) ACETONE 67-64-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ N-HEXANE 110-54-3 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 RHODAMINE - 81-88-9 Carcinogen U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts ACETONE 67-64-1 X X X N-HEXANE 110-54-3 X X X ROSIN 8050-09-7 - - X RHODAMINE 81-88-9 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 15-Jun-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 9 / 9 Instability 0 21146 - 765-1221 NAPA HIGH TACK GASKET SEALANT(PTX80062) 4 FL.OZ - HMIS NFPA Health hazards 2 Revision Date 15-Jun-2015 Flammability 3 Physical hazards 0 Personal protection B Health hazards 2 Flammability 3 Page 133 of 1287 Page 133 of 1287 Page 133 of 1287 Page 133 of 1287 ---PAGE BREAK--- Material Safety Data Sheet May be used to Comply with OSHA’s Hazard Communication Standard, 29 CFR 1910.1200. Standard must be Consulted for specific requirements HMIS HEALTH 1 REACTIVITY 0 FLAMMABILITY 0 PERSONAL PROTECTION B Identity (As Used On Label and List) A1121 Tire Shine Date Prepared 05-29-2009 Section I Manufactured for: OMEGA INDUSTRIAL SUPPLY, INC Emergency Telephone Number: 1-[PHONE REDACTED] Address (Number, Street, Suite/Apt#) 101 Grobric Ct #1 Telephone Number for Information: 1-[PHONE REDACTED] (City, State, and Zip Code) Fairfield, CA 94534 Signature of Prepare (Optional) REGULATORY DEPT. Section II - Ingredients / Identity Information Components (Specific Chemical Identity, Common Name(s)) CAS No. OSHA PEL ACGIH-TLV Polydimethysiloxane 63148-62-9 N/E N/E 05 – 15 Liquefied Petroleum Gas 68476-86-8 1000 ppm 1000 ppm 05 - 15 Section III - Physical Chemical Characteristics Boiling Point > 200°F Specific Gravity (H2O = 1) Concentrate 0.992 Vapor Pressure (can; psig @ 72°F) 50 psi Melting Point - Vapor Density (Air=1) > 1 Evaporation Rate (Butyl Acetate = 1) - Solubility in Water Emulsion pH 7.0 – 8.0 Appearance and Odor— Opaque, white liquid with low to no odor. VOC % 9.15% Section IV – Fire and Explosion Hazard Data Flash Point (Method) None (T.C.C) Flammability (as per CSMA Flame Projection Test): Non-Flammable Spray Extinguishing Media – Foam, CO2, dry media. Unusual Fire and Explosion Hazards – Exposure to temperatures above 120°F may cause bursting. Special Fire Fighting Procedures - Wear self-contained breathing apparatus and protective clothing. Cool fire exposed containers to prevent rupturing. Section V – Reactivity Data Stability: Unstable Stable Conditions to Avoid – Hazardous Polymerization: May Occur Will Not Occur Incompatibility (Materials to Avoid) – Strong oxidizing agents, strong acids, and strong bases. Hazardous Decomposition or Byproducts –Carbon dioxide, carbon monoxide, formaldehyde and possibly low levels of other alcohols, ethers, and organic acids. Section VI – Health Hazard Data Carcinogenicity: NTP? No IARC Monographs? No OSHA Regulated? No Signs and of Exposure: Eyes— May cause mild irritation. May aggravate pre-existing conditions. Skin— Frequent or prolonged contact may cause irritation. Repeated exposure may result in excessive drying and defatting of the skin and possibly dermatitis. May aggravate existing disorders. Inhalation— Inhalation of mist can cause irritation of nasal and respiratory passages. Abusive or excessive inhalation may cause irritation to the upper respiratory tract, headaches, dizziness, drowsiness, nausea, unconsciousness, other central nervous system effects, and possibly even death from depending on time of exposure. Ingestion— Can cause gastrointestinal irritation, nausea, vomiting and diarrhea. Aspiration of material into the lungs can cause pulmonary injury. Repeated ingestion can damage the liver and blood. Emergency and First Aid Procedures. Eyes— Flush with large amounts of cool running water for at least 15 minutes while holding upper and lower lids open. If irritation persists get medical attention immediately. Skin— Wash with soap and water. If irritation persists seek medical attention. Inhalation— Remove to fresh air. Seek medical attention immediately. If breathing stops give artificial respiration. Ingestion— Do not induce vomiting. Seek medical attention immediately. Section VII – Precautions for Safe Handling and Use Steps to be Taken in Case Material is Released or Spilled. Allow propellant to evaporate. Maintain local exhaust and adequate ventilation. No smoking. Keep sparks, heat sources and open flame far away from spill or leak. Cover with absorbent material and sweep up. Wash area to prevent slipping. Dispose of soaked absorbent material in accordance with Federal, State and local laws. Waste Disposal Method – Aerosol can, when emptied and depressurized through normal use, pose no disposal hazard and should be recycled. Consult Federal, State and local authorities for approved procedures. Precautions to be Taken in Handling and Storing – Store in a cool, dry area away from heat or open flame. Do not store at temperatures above 120°F. KEEP OUT OF REACH OF CHILDREN. Section VIII – Control Measures Respiratory Protection (Specify Type) – None needed for proper use in accordance with label directions. Ventilation –Provide local exhaust to keep vapor concentrations of ingredients listed in Section II below acceptable limits. Protective Gloves – Use chemical resistant gloves if hand contact will be made. Eye Protection – Always wear safety glasses or chemical proof goggles when using aerosol products. Other protective Clothing or Equipment – N/A Work/Hygienic Practices – Observe good hygiene. Wash hands thoroughly after product use, eating, drinking, and using restrooms, etc. NOTICE: The information contained on this Material Safety Data Sheet is considered accurate as of the date of publication. It is not necessarily all inclusive nor fully adequate in every circumstance. The suggestions should not be confused with, and or followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, express or implied, of merchantability, fitness, accuracy of data, or the results to be obtained from the use thereof is made. The vendor assumes no responsibility for injury or damages resulting from the inappropriate use of this product. Page 134 of 1287 Page 134 of 1287 Page 134 of 1287 Page 134 of 1287 ---PAGE BREAK--- AeroShell Fluid 4 Version 1.1 Effective Date 2014-11-14 Material Safety Data Sheet According to the Controlled Product Regulations 1/8 Print Date 2014-11-17 000000000807 MSDS_CA 1. MATERIAL AND COMPANY IDENTIFICATION Material Name : AeroShell Fluid 4 Uses : Mineral hydraulic fluid for aircraft. For further details consult the AeroShell Book on www.shell.com/aviation. Product Code : 001A0049 Manufacturer/Supplier : Shell Canada Products 400 - 4th Avenue S.W Calgary AB T2P 0J4 Canada Telephone : [PHONE REDACTED] Fax : [PHONE REDACTED] Emergency Telephone Number : CHEMTREC (24 hr): [PHONE REDACTED] CANUTEC (24 hr): [PHONE REDACTED] 2. COMPOSITION/INFORMATION ON INGREDIENTS Mixture Description: : Highly refined mineral oils and additives. The highly refined mineral oil contains (w/w) DMSO-extract, according to IP346. Refer to Chapter 8 for Occupational Exposure Guidelines. 3. HAZARDS IDENTIFICATION WHMIS Class/Description : THIS PRODUCT IS NOT A WHMIS CONTROLLED SUBSTANCE. Routes of Exposure : Skin and eye contact are the primary routes of exposure although exposure may occur following accidental ingestion. Health Hazards : Not expected to be a health hazard when used under normal conditions. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Aspiration into the lungs when swallowed or vomited may cause chemical pneumonitis which can be fatal. High-pressure injection under the skin may cause serious damage including local necrosis. Used oil may contain harmful impurities. Signs and : If material enters lungs, signs and may include coughing, choking, wheezing, difficulty in breathing, chest congestion, shortness of breath, and/or fever. The onset of respiratory may be delayed for several hours after exposure. Local necrosis is evidenced by delayed onset of pain and tissue damage a few hours following injection. Oil acne/folliculitis signs and may include formation of Page 135 of 1287 Page 135 of 1287 Page 135 of 1287 Page 135 of 1287 ---PAGE BREAK--- AeroShell Fluid 4 Version 1.1 Effective Date 2014-11-14 Material Safety Data Sheet According to the Controlled Product Regulations 2/8 Print Date 2014-11-17 000000000807 MSDS_CA black pustules and spots on the skin of exposed areas. Ingestion may result in nausea, vomiting and/or diarrhoea. Safety Hazards : Not classified as flammable but will burn. Environmental Hazards : Not classified as dangerous for the environment. 4. FIRST AID MEASURES Inhalation : No treatment necessary under normal conditions of use. If persist, obtain medical advice. Skin Contact : Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention. When using high pressure equipment, injection of product under the skin can occur. If high pressure injuries occur, the casualty should be sent immediately to a hospital. Do not wait for to develop. Obtain medical attention even in the absence of apparent wounds. Eye Contact : Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention. Ingestion : If swallowed, do not induce vomiting: transport to nearest medical facility for additional treatment. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. If any of the following delayed signs and appear within the next 6 hours, transport to the nearest medical facility: fever greater than 101° F (38.3°C), shortness of breath, chest congestion or continued coughing or wheezing. Advice to Physician : Treat Potential for chemical pneumonitis. Consider: gastric lavage with protected airway, administration of activated charcoal. High pressure injection injuries require prompt surgical intervention and possibly steroid therapy, to minimise tissue damage and loss of function. Because entry wounds are small and do not reflect the seriousness of the underlying damage, surgical exploration to determine the extent of involvement may be necessary. Local anaesthetics or hot soaks should be avoided because they can contribute to swelling, vasospasm and ischaemia. Prompt surgical decompression, debridement and evacuation of foreign material should be performed under general anaesthetics, and wide exploration is essential. Call a doctor or poison control center for guidance. 5. FIRE FIGHTING MEASURES Clear fire area of all non-emergency personnel. Flash point : Typical 105 °C / 221 °F (PMCC / ASTM D93) Upper / lower Flammability or Explosion limits : Typical 1 - 10 %(V)(based on mineral oil) Auto ignition temperature : > 320 °C / 608 °F Page 136 of 1287 Page 136 of 1287 Page 136 of 1287 Page 136 of 1287 ---PAGE BREAK--- AeroShell Fluid 4 Version 1.1 Effective Date 2014-11-14 Material Safety Data Sheet According to the Controlled Product Regulations 3/8 Print Date 2014-11-17 000000000807 MSDS_CA Hazardous Combustion Products and Specific Hazards : Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Suitable Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media : Do not use water in a jet. Protective Equipment for Firefighters : Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space. 6. ACCIDENTAL RELEASE MEASURES Protective Measures : Avoid contact with skin and eyes. Use appropriate containment to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately. Prevent from spreading by making a barrier with sand, earth or other containment material. Reclaim liquid directly or in an absorbent. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly. Additional Advice : Local authorities should be advised if significant spillages cannot be contained. 7. HANDLING AND STORAGE General Precautions : Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Use the information in this data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling vapour and/or mists. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. Storage : Keep container closed and in a cool, well-ventilated place. Use properly labelled and closeable containers. Store at ambient temperature. Recommended Materials : For containers or container linings, use mild steel or high density polyethylene. Unsuitable Materials : PVC. Additional Information : Polyethylene containers should not be exposed to high temperatures because of possible risk of distortion. Page 137 of 1287 Page 137 of 1287 Page 137 of 1287 Page 137 of 1287 ---PAGE BREAK--- AeroShell Fluid 4 Version 1.1 Effective Date 2014-11-14 Material Safety Data Sheet According to the Controlled Product Regulations 4/8 Print Date 2014-11-17 000000000807 MSDS_CA 8. EXPOSURE CONTROLS/PERSONAL PROTECTION If the American Conference of Governmental Industrial Hygienists (ACGIH) value is provided on this document, it is provided for information only. Occupational Exposure Limits Material Source Type ppm mg/m3 Notation Oil mist, mineral ACGIH TWA(Inhala ble fraction.) 5 mg/m3 Consult local authorities for acceptable exposure limits within their jurisdiction. Exposure Controls : The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Adequate ventilation to control airborne concentrations. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated. Personal Protective Equipment : Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers. Respiratory Protection : No respiratory protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid breathing of material. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. Select a filter suitable for combined particulate/organic gases and vapours [boiling point >65°C(149 Hand Protection : Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection: PVC, neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. Page 138 of 1287 Page 138 of 1287 Page 138 of 1287 Page 138 of 1287 ---PAGE BREAK--- AeroShell Fluid 4 Version 1.1 Effective Date 2014-11-14 Material Safety Data Sheet According to the Controlled Product Regulations 5/8 Print Date 2014-11-17 000000000807 MSDS_CA Eye Protection : Wear safety glasses or full face shield if splashes are likely to occur. Protective Clothing : Skin protection is not required under normal conditions of use. It is good practice to wear chemical resistant gloves. Monitoring Methods : Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate. Environmental Exposure Controls : Minimise release to the environment. An environmental assessment must be made to ensure compliance with local environmental legislation. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Reddish. Liquid at room temperature. Odour : Slight hydrocarbon. Odour threshold : Data not available pH : Not applicable. Initial Boiling Point and Boiling Range : > 280 °C / 536 °F estimated value(s) Pour point : < -60 °C / -76 °F Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s)) Specific gravity : Typical 0.882 at 15 °C / 59 °F Density : Typical 882 kg/m3 at 15 °C / 59 °F Water solubility : Negligible. n-octanol/water partition coefficient (log Pow) : > 6 (based on information on similar products) Kinematic viscosity : Typical 14 mm2/s at 40 °C / 104 °F Vapour density (air=1) : > 1 (estimated value(s)) Evaporation rate (nBuAc=1) : Data not available 10. STABILITY AND REACTIVITY Stability : Stable. Conditions to Avoid : Extremes of temperature and direct sunlight. Materials to Avoid : Strong oxidising agents. Hazardous Decomposition Products : Hazardous decomposition products are not expected to form during normal storage. Hazardous Polymerisation : No Sensitivity to Mechanical Impact : No Sensitivity to Static Discharge : No 11. TOXICOLOGICAL INFORMATION Basis for Assessment : Information given is based on data on the components and the Page 139 of 1287 Page 139 of 1287 Page 139 of 1287 Page 139 of 1287 ---PAGE BREAK--- AeroShell Fluid 4 Version 1.1 Effective Date 2014-11-14 Material Safety Data Sheet According to the Controlled Product Regulations 6/8 Print Date 2014-11-17 000000000807 MSDS_CA toxicology of similar products. Routes of Exposure : Skin and eye contact are the primary routes of exposure although exposure may occur following accidental ingestion. Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat. Aspiration into the lungs may cause chemical pneumonitis which can be fatal. Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit. Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal conditions of use. Skin Irritation : Expected to be irritating. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Eye Irritation : Expected to be irritating. Respiratory Irritation : Inhalation of vapours or mists may cause irritation. Sensitisation : Not expected to be a skin sensitiser. Repeated Dose Toxicity : Not expected to be a hazard. Mutagenicity : Not considered a mutagenic hazard. Carcinogenicity : Product contains mineral oils of types shown to be non- carcinogenic in animal skin-painting studies. Highly refined mineral oils are not classified as carcinogenic by the International Agency for Research on Cancer (IARC). Other components are not known to be associated with carcinogenic effects. Reproductive and Developmental Toxicity : Not expected to be a hazard. Additional Information : Used oils may contain harmful impurities that have accumulated during use. The concentration of such impurities will depend on use and they may present risks to health and the environment on disposal. ALL used oil should be handled with caution and skin contact avoided as far as possible. High pressure injection of product into the skin may lead to local necrosis if the product is not surgically removed. 12. ECOLOGICAL INFORMATION Ecotoxicological data have not been determined specifically for this product. Information given is based on a knowledge of the components and the ecotoxicology of similar products. Acute Toxicity : Poorly soluble mixture.May cause physical fouling of aquatic organisms.Expected to be practically non toxic:LL/EL/IL50 > 100 mg/l(to aquatic organisms)(LL/EL50 expressed as the nominal amount of product required to prepare aqueous test extract).Mineral oil is not expected to cause any chronic effects to aquatic organisms at concentrations less than 1 mg/l. Mobility : Liquid under most environmental conditions. Floats on water. If it enters soil, it will adsorb to soil particles and will not be mobile. Persistence/degradability : Expected to be not readily biodegradable. Major constituents are expected to be inherently biodegradable, but the product Page 140 of 1287 Page 140 of 1287 Page 140 of 1287 Page 140 of 1287 ---PAGE BREAK--- AeroShell Fluid 4 Version 1.1 Effective Date 2014-11-14 Material Safety Data Sheet According to the Controlled Product Regulations 7/8 Print Date 2014-11-17 000000000807 MSDS_CA contains components that may persist in the environment. Bioaccumulation : Contains components with the potential to bioaccumulate. Other Adverse Effects : Product is a mixture of non-volatile components, which are not expected to be released to air in any significant quantities. Not expected to have ozone depletion potential, photochemical ozone creation potential or global warming potential. 13. DISPOSAL CONSIDERATIONS Material Disposal : Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations. Do not dispose into the environment, in drains or in water courses. Container Disposal : Dispose in accordance with prevailing regulations, preferably to a recognised collector or contractor. The competence of the collector or contractor should be established beforehand. Local Legislation : Disposal should be in accordance with applicable regional, national, and local laws and regulations. 14. TRANSPORT INFORMATION Canadian Road and Rail Shipping Classification This product is not regulated under the Canadian Transportation of Dangerous Goods Regulations for transport by road and rail. 15. REGULATORY INFORMATION The regulatory information is not intended to be comprehensive. Other regulations may apply to this material. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Class/Description : THIS PRODUCT IS NOT A WHMIS CONTROLLED SUBSTANCE. Inventory Status DSL : All components listed. EINECS : All components listed or polymer exempt. TSCA : All components listed. Page 141 of 1287 Page 141 of 1287 Page 141 of 1287 Page 141 of 1287 ---PAGE BREAK--- AeroShell Fluid 4 Version 1.1 Effective Date 2014-11-14 Material Safety Data Sheet According to the Controlled Product Regulations 8/8 Print Date 2014-11-17 000000000807 MSDS_CA 16. OTHER INFORMATION MSDS Version Number : 1.0 MSDS Effective Date : 2011-12-09 MSDS Revisions : A vertical bar in the left margin indicates an amendment from the previous version. MSDS Regulation : The content and format of this (M)SDS is in accordance with the Controlled Product Regulations. MSDS Prepared By : Shell Product Stewardship; 1-[PHONE REDACTED] Uses and Restrictions : Not to be used as an engine lubricating oil.This product must not be used in systems incorporating natural rubber.This product must be used, handled and applied in accordance with the requirements of the equipment manufacturer's manuals, bulletins and other documentation. MSDS Distribution : The information in this document should be made available to all who may handle the product. Disclaimer : The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of health, safety and environmental requirements only. No warranty or guarantee is expressed or implied regarding the accuracy of these data or the results to be obtained from the use of the product. Page 142 of 1287 Page 142 of 1287 Page 142 of 1287 Page 142 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Product identifier Aerosol Glass Cleaner - Ammonia Free Version # 03 Issue date 10-22-2014 Revision date 10-24-2014 Supersedes date 10-22-2014 Product Code 1138 Product use Glass Cleaner Malco Products, Inc. 361 Fairview Ave Barberton, OH 44203 United States [EMAIL REDACTED] www.malcopro.com Phone [PHONE REDACTED] Fax [PHONE REDACTED] Phone 1-[PHONE REDACTED] Manufacturer information Supplier Not available. 2. Hazards Identification Emergency overview DANGER Flammable liquid - may release vapors that form flammable mixtures at or above the flash point. CONTENTS UNDER PRESSURE. Aerosol. Pressurized container may explode when exposed to heat or flame. Will be easily ignited by heat, spark or flames. Very toxic. Cancer hazard. Irritating to eyes and skin. Prolonged exposure may cause chronic effects. Potential health effects Routes of exposure Inhalation. Ingestion. Skin contact. Eye contact. Eyes Contact with eyes may cause irritation. Do not get this material in contact with eyes. Skin May be harmful if absorbed through skin. Do not get this material in contact with skin. May cause skin irritation. Inhalation May cause cancer by inhalation. Intentional misuse by concentrating and inhaling the product can be harmful or fatal. May cause irritation of respiratory tract. Prolonged inhalation may be harmful. Avoid breathing dust/fume/gas/mist/vapors/spray. Ingestion Exposure by ingestion of an aerosol is unlikely. Irritating. May cause nausea, stomach pain and vomiting. Do not ingest. Target organs Kidneys. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged and may cause blood damage. These effects have not been observed in humans. Chronic effects May be harmful if absorbed through skin. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Signs and of overexposure may be headache, dizziness, tiredness, nausea and vomiting. are prostration, gasping, pallor, and uncoordinated movements. may include redness, edema, drying, defatting and cracking of the skin. Potential environmental effects May cause long-term adverse effects in the environment. Hazardous components CAS # Percent 3. Composition / Information on Ingredients 111-76-2 5 - 10 Ethylene Glycol Monobutyl Ether Material name: Aerosol Glass Cleaner - Ammonia Free 1122 Version 03 Revision date: 10-24-2014 Issue date: 10-22-2014 MSDS CANADA 1 / 9 Page 143 of 1287 Page 143 of 1287 Page 143 of 1287 Page 143 of 1287 ---PAGE BREAK--- Hazardous components CAS # Percent 106-97-8 1 - 5 Butane 74-98-6 1 - 5 Propane Non-hazardous components CAS # Percent 64-17-5 5 - 10 Ethanol 60 - 100 Other components below reportable levels 4. First Aid Measures First aid procedures Eye contact Flush eyes with water as a precaution. If a contact lens is present, DO NOT delay irrigation or attempt to remove the lens. Call a physician or poison control center immediately. Skin contact Take off immediately all contaminated clothing. Wash off immediately with soap and plenty of water. Call a physician or poison control center immediately. Inhalation Move to fresh air. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a physician or poison control center immediately. Ingestion If ingestion of a large amount does occur, call a poison control center immediately. Notes to physician In case of shortness of breath, give oxygen. may be delayed. General advice In case of shortness of breath, give oxygen. Immediate medical attention is required. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Keep victim under observation. Keep victim warm. 5. Fire Fighting Measures Flammable properties Flammable by WHMIS criteria. Heat may cause the containers to explode. Vapors may travel considerable distance to a source of ignition and flash back. Extinguishing media Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Protection of firefighters Specific hazards arising from the chemical Fire may produce irritating, corrosive and/or toxic gases. Protective equipment for firefighters Firefighters should wear full protective clothing including self contained breathing apparatus. Fire fighting equipment/instructions Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Some of these materials, if spilled, may evaporate leaving a flammable residue. Explosion data Sensitivity to static discharge Not available. Sensitivity to mechanical impact Not available. Hazardous combustion products Not available. 6. Accidental Release Measures Personal precautions Consider initial downwind evacuation for at least 500 meters (1/3 mile). Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. For personal protection, see section 8 of the MSDS. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water. Material name: Aerosol Glass Cleaner - Ammonia Free 1122 Version 03 Revision date: 10-24-2014 Issue date: 10-22-2014 MSDS CANADA 2 / 9 Page 144 of 1287 Page 144 of 1287 Page 144 of 1287 Page 144 of 1287 ---PAGE BREAK--- Methods for containment Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Prevent entry into waterways, sewer, basements or confined areas. Methods for cleaning up Should not be released into the environment. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Clean up in accordance with all applicable regulations. For waste disposal, see section 13 of the MSDS. Other information Clean up in accordance with all applicable regulations. 7. Handling and Storage Handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Do not breathe mist or vapor. Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure. Do not get this material on clothing. When using do not eat or drink. Do not use in areas without adequate ventilation. Wear personal protective equipment. Wash thoroughly after handling. Avoid release to the environment. Storage Level 1 Aerosol. Keep locked up. Contents under pressure. Do not expose to heat or store at temperatures above 120°F/49°C as can may burst. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Store in a well-ventilated place. Refrigeration recommended. Keep away from food, drink and animal feedingstuffs. Keep in an area equipped with sprinklers. Store away from incompatible materials (see Section 10 of the MSDS). 8. Exposure Controls / Personal Protection Occupational exposure limits US. ACGIH Threshold Limit Values Value Components Type STEL 1000 ppm Butane (CAS 106-97-8) STEL 1000 ppm Ethanol (CAS 64-17-5) TWA 20 ppm Ethylene Glycol Monobutyl Ether (CAS 111-76-2) Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) Value Components Type TWA 1000 ppm Butane (CAS 106-97-8) TWA 1880 mg/m3 Ethanol (CAS 64-17-5) 1000 ppm TWA 97 mg/m3 Ethylene Glycol Monobutyl Ether (CAS 111-76-2) 20 ppm TWA 1000 ppm Propane (CAS 74-98-6) Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) Value Components Type STEL 750 ppm Butane (CAS 106-97-8) TWA 600 ppm STEL 1000 ppm Ethanol (CAS 64-17-5) TWA 20 ppm Ethylene Glycol Monobutyl Ether (CAS 111-76-2) Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act) Value Components Type STEL 1000 ppm Butane (CAS 106-97-8) STEL 1000 ppm Ethanol (CAS 64-17-5) Material name: Aerosol Glass Cleaner - Ammonia Free 1122 Version 03 Revision date: 10-24-2014 Issue date: 10-22-2014 MSDS CANADA 3 / 9 Page 145 of 1287 Page 145 of 1287 Page 145 of 1287 Page 145 of 1287 ---PAGE BREAK--- Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act) Value Components Type TWA 20 ppm Ethylene Glycol Monobutyl Ether (CAS 111-76-2) Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) Value Components Type TWA 800 ppm Butane (CAS 106-97-8) STEL 1000 ppm Ethanol (CAS 64-17-5) TWA 20 ppm Ethylene Glycol Monobutyl Ether (CAS 111-76-2) Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) Value Components Type TWA 1900 mg/m3 Butane (CAS 106-97-8) 800 ppm TWA 1880 mg/m3 Ethanol (CAS 64-17-5) 1000 ppm TWA 97 mg/m3 Ethylene Glycol Monobutyl Ether (CAS 111-76-2) 20 ppm TWA 1800 mg/m3 Propane (CAS 74-98-6) 1000 ppm US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Type PEL 1900 mg/m3 Ethanol (CAS 64-17-5) 1000 ppm PEL 240 mg/m3 Ethylene Glycol Monobutyl Ether (CAS 111-76-2) 50 ppm PEL 1800 mg/m3 Propane (CAS 74-98-6) 1000 ppm Biological limit values ACGIH Biological Exposure Indices Value Components Determinant Specimen Sampling Time 200 mg/g Butoxyacetic acid (BAA), with hydrolysis Creatinine in urine * Ethylene Glycol Monobutyl Ether (CAS 111-76-2) * - For sampling details, please see the source document. Engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Ensure adequate ventilation, especially in confined areas. Personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Wear chemical protective equipment that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. Hand protection Wear protective gloves. 9. Physical & Chemical Properties Appearance Clear. Physical state Liquid. Form Aerosol. Color Colourless to light yellow. Odor Solvent. Material name: Aerosol Glass Cleaner - Ammonia Free 1122 Version 03 Revision date: 10-24-2014 Issue date: 10-22-2014 MSDS CANADA 4 / 9 Page 146 of 1287 Page 146 of 1287 Page 146 of 1287 Page 146 of 1287 ---PAGE BREAK--- Odor threshold Not available. pH 10 Vapor pressure 70 - 90 psig Vapor pressure temp. 70 °F (21.11 Vapor density Not available. Boiling point 254.21 °F (123.45 estimated Melting point/Freezing point -138.01 °F (-94.45 estimated Solubility (water) Not available. Specific gravity Not available. Relative density Not available. Flash point -156.0 °F (-104.4 Flammability limits in air, upper, % by volume Not available. Flammability limits in air, lower, % by volume Not available. Auto-ignition temperature 572.7 °F (300.39 estimated VOC 9.7 % by weight Evaporation rate Not available. Partition coefficient (n-octanol/water) Not available. Other data Density 8.00 lbs/gal Heat of combustion (NFPA 30B) 4.92 kJ/g estimated 10. Chemical Stability & Reactivity Information Chemical stability Risk of explosion. Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Do not mix with other chemicals. Hazardous decomposition products Not available. Possibility of hazardous reactions Hazardous polymerization does not occur. 11. Toxicological Information Test Results Components Species Toxicological data Butane (CAS 106-97-8) LC50 Mouse Inhalation Acute 680 mg/l, 2 Hours Rat 658 mg/l, 4 Hours Ethanol (CAS 64-17-5) LC50 Mouse Inhalation Acute 39 mg/l, 4 Hours Rat 20000 ppm, 10 Hours LD50 Dog Oral 5.5 g/kg Guinea pig 5.6 g/kg Mouse 3450 mg/kg Rat 6.2 g/kg Material name: Aerosol Glass Cleaner - Ammonia Free 1122 Version 03 Revision date: 10-24-2014 Issue date: 10-22-2014 MSDS CANADA 5 / 9 Page 147 of 1287 Page 147 of 1287 Page 147 of 1287 Page 147 of 1287 ---PAGE BREAK--- Test Results Components Species LD50 Mouse Other 933 mg/kg Rat 1440 mg/kg Ethylene Glycol Monobutyl Ether (CAS 111-76-2) LD50 Rabbit Dermal Acute 400 mg/kg LC50 Mouse Inhalation 700 ppm, 7 Hours Rat 450 ppm, 4 Hours LD50 Guinea pig Oral 1.2 g/kg Mouse 1.2 g/kg Rabbit 0.32 g/kg Rat 560 mg/kg LD50 Mouse Other 1130 mg/kg Rabbit 280 mg/kg Rat 340 mg/kg Propane (CAS 74-98-6) LC50 Rat Inhalation Acute > 1442.847 mg/l, 15 Minutes Acute effects Sensitization Not available. Chronic effects Hazardous by WHMIS criteria. Prolonged inhalation may be harmful. May be harmful if absorbed through skin. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Prolonged exposure may cause chronic effects. Carcinogenicity Hazardous by WHMIS criteria. Cancer hazard. ACGIH Carcinogens Ethylene Glycol Monobutyl Ether (CAS 111-76-2) A3 Confirmed animal carcinogen with unknown relevance to humans. IARC Monographs. Overall Evaluation of Carcinogenicity Ethylene Glycol Monobutyl Ether (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. Skin corrosion/irritation Not available. Serious eye damage/irritation Not available. Mutagenicity Not available. Reproductive effects Not available. Teratogenicity Not available. Synergistic materials Not available. Material name: Aerosol Glass Cleaner - Ammonia Free 1122 Version 03 Revision date: 10-24-2014 Issue date: 10-22-2014 MSDS CANADA 6 / 9 Page 148 of 1287 Page 148 of 1287 Page 148 of 1287 Page 148 of 1287 ---PAGE BREAK--- 12. Ecological Information Ecotoxicological data Components Test Results Species Ethanol (CAS 64-17-5) Aquatic EC50 Crustacea 7.7 - 11.2 mg/l, 48 hours Water flea (Daphnia magna) LC50 Fish > 100 mg/l, 96 hours Fathead minnow (Pimephales promelas) Ethylene Glycol Monobutyl Ether (CAS 111-76-2) Aquatic LC50 Fish 1250 mg/l, 96 hours Inland silverside (Menidia beryllina) Ecotoxicity Contains a substance which causes risk of hazardous effects to the environment. Environmental effects An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Aquatic toxicity Not available. Persistence and degradability Not available. Partition coefficient Butane 2.89 Ethanol -0.31 Ethylene Glycol Monobutyl Ether 0.83 Propane 2.36 13. Disposal Considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Dispose in accordance with all applicable regulations. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. 14. Transport Information TDG UN1950 UN number AEROSOLS, flammable UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk Not applicable. Packing group D Environmental hazards Read safety instructions, MSDS and emergency procedures before handling. Special precautions for user IATA UN1950 UN number Aerosols, flammable UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk Not applicable. Packing group No. Environmental hazards 10L ERG Code Read safety instructions, MSDS and emergency procedures before handling. Special precautions for user Allowed. Passenger and cargo aircraft Other information Allowed. Cargo aircraft only IMDG UN1950 UN number Material name: Aerosol Glass Cleaner - Ammonia Free 1122 Version 03 Revision date: 10-24-2014 Issue date: 10-22-2014 MSDS CANADA 7 / 9 Page 149 of 1287 Page 149 of 1287 Page 149 of 1287 Page 149 of 1287 ---PAGE BREAK--- AEROSOLS, FLAMMABLE UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk Not applicable. Packing group No. Marine pollutant Environmental hazards Not available. EmS Read safety instructions, MSDS and emergency procedures before handling. Special precautions for user IATA; IMDG; TDG 15. Regulatory Information Canadian regulations This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. WHMIS status Controlled WHMIS classification B2 - Flammable Liquids D1A - Immediate/Serious-VERY TOXIC D2A - Other Toxic Effects-VERY TOXIC D2B - Other Toxic Effects-TOXIC WHMIS labeling International Inventories Country(s) or region Inventory name On inventory (yes/no)* Yes Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) Yes China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) Yes Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other Information HMIS® ratings Health: 2* Flammability: 3 Physical hazard: 0 Material name: Aerosol Glass Cleaner - Ammonia Free 1122 Version 03 Revision date: 10-24-2014 Issue date: 10-22-2014 MSDS CANADA 8 / 9 Page 150 of 1287 Page 150 of 1287 Page 150 of 1287 Page 150 of 1287 ---PAGE BREAK--- NFPA ratings Health: 2 Flammability: 3 Instability: 0 Disclaimer Presta Products cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Prepared by Not available. This data sheet contains changes from the previous version in section(s): Physical & Chemical Properties: Multiple Properties Material name: Aerosol Glass Cleaner - Ammonia Free 1122 Version 03 Revision date: 10-24-2014 Issue date: 10-22-2014 MSDS CANADA 9 / 9 Page 151 of 1287 Page 151 of 1287 Page 151 of 1287 Page 151 of 1287 ---PAGE BREAK--- PANEF CORPORATION 5700 West Douglas Avenue, Milwaukee WI 53218 [PHONE REDACTED] [PHONE REDACTED] FAX [PHONE REDACTED] MATERIAL SAFETY DATA SHEET PRODUCT: LDA-2 & LDA-30 PRODUCT NAME: Aerosol Lock Deicer The attached MSDS for Lock Deicer is provided to Panef Corporation by ITW Performance Polymers - Qualco. This product is filled and labeled by ITW for Panef as the item described above and is sold by Panef Corporation. ® Page 152 of 1287 Page 152 of 1287 Page 152 of 1287 Page 152 of 1287 ---PAGE BREAK--- MANUFACTURER ITW Performance Polymers - QUALCO 2107 West Blue Heron Blvd. Riviera Beach, FL 33404 Emergency telephone number (800) 424-9300 (CHEMTREC): Other Calls: [PHONE REDACTED] EMERGENCY INFORMATION LOCK DE-ICER (00201, 00201-CS, 00201D, 00201S, OO202, 002020) Printed: 10/5/2001 2. COMPOSITION/INFORMATION ON INGREDIENTS "TLV" means the Threshold Limit Value exposure (eight-hour, time-weighted average, unless otherwise noted) established by the American Conference of Governmental Industrial Hygienists. "STEL" indicates a short-term exposure limit. "PEL" indicates the OSHA Permissible Exposure Limit."n/e" indicates that no exposure limit has been established. An asterisk indicates a substance whose identity is a trade secret of our supplier and unknown to us. Last revised: 10/01/01 HAZARDOUS CONSTITUENTS Emergency Overview WARNING! Flammable. Eye, skin and respiratory irritant. May cause central nervous system effects. 3. HAZARDS IDENTIFICATION Appearance, form, odor: Clear liquid with solvent odor. 00201 00201-CS 00201D 00201S 00202 01201S Q00203-PRE This product appears in the following stock number(s): Constituent ACGIH TLV CAS No. Weight percent OSHA PEL Other Limits Abbr. Carbon dioxide 124389 > 10 5000 ppm 5000 ppm n/e Isopropanol 67630 > 50 400 ppm 400 ppm IPA 400 ppm (Canada) Eyes: Severe eye irritant. May cause corneal burns. Inhalation: May cause irritation to the nose, throat and respiratory tract and may result in central nervous system depression (narcotic effect). May cause coughing, shortness of breath, dizziness and intoxication. Potential health effects Skin: May irritate the skin. of acute overexposure: Skin contact Skin absorption Eye contact Inhalation Ingestion Primary routes of exposure: Exposure limits 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Tradename: LOCK DE-ICER (00201, 00201-CS, 00201D, 00201S, OO202, 002020) General use: Chemical family: Alcohol MSDS0619 ITW Performance Polymers - QUALCO Material Safety Data Sheet Page 1 Part No.: Q00201 Page 153 of 1287 Page 153 of 1287 Page 153 of 1287 Page 153 of 1287 ---PAGE BREAK--- Unusual fire and explosion hazards: Heat may build enough pressure to rupture closed containers/ spreading fire/ increasing risk of burns/injuries. When mixed with air and exposed to ignition source, vapors can burn in open or explode if confined. Vapors are heavier than air, travel along floor to ignition source and flash back. Diluting with water may not suffice to raise flash point above ambient temperatures. Burning liquid may float on water. Avoid frothing/steam explosion. Carbon dioxide Dry chemical Foam Alcohol foam Water Extinguishing media: Flash Point 53 Method: TCC Explosive limits in air (percent) Lower: 2 Upper: 12.7 Special firefighting procedures: Clear area of unprotected personnel. Fight fire from safe distance. Do not enter confined fire space without full bunker gear (helmet with face shield, bunker coats, gloves and rubber boots) and positive pressure NIOSH approved self-contained breathing apparatus. Cool fire exposed containers with water spray. 5. FIRE FIGHTING MEASURES General fire and explosion characteristics: Flammable liquid class IB. First aid for skin: Immediately remove contaminated clothing and excess contaminant. Flush skin with water. Wash thoroughly with soap and warm water. Consult a physician if irritation develops. First aid for ingestion: Do NOT induce vomiting. Give two glasses of water if patient is NOT unconscious or drowsy. Keep victims head below hips to prevent aspiration if vomiting. Get medical attention immediately. First aid for inhalation: Remove patient to fresh air. Administer oxygen if breathing is difficult. Get immediate medical attention. Note to physician : Eye: if pain, tears, or rednesscontinue, patient should contact ophthalmologist. Detoxification procedure: administer an aqueous slurry of activated charcoal followed by a cathartic such as magnesium citrate or sorbitol. 4. FIRST AID MEASURES First aid for eyes: Flush eye with clean water for at least 20 minutes while gently holding eyelids open. Get immediate medical attention. Medical conditions which may be aggravated by exposure: Existing eye, skin and respiratory disorders. Effects of chronic overexposure: Repeated or prolonged exposure may irritate mucous membranes. Other effects: May effect mucous tissue or mucous membrane dysfunction. See section 11. OSHA regulated: No ACGIH: No National Toxicology Program: No International Agency for Research on Cancer: No Cancer-suspect constituent(s) : NONE Carcinogenicity Ingestion: Irritating to the gastrointestinal tract, causing abdominal pain and vomitting, sometimes bloody. Ingestion may cause CNS depression, low blood pressure, rapid heart beat and liver damage. MSDS0619 ITW Performance Polymers - QUALCO Material Safety Data Sheet Page 2 Part No.: Q00201 Page 154 of 1287 Page 154 of 1287 Page 154 of 1287 Page 154 of 1287 ---PAGE BREAK--- Hazardous products of combustion: Carbon monoxide and other unknown organic compounds. Containment: Dike, contain and absorb with clay, sand or other suitable material. Cleanup: Wear appropriate respirator and protective clothing. For large spills, blanket with firefighting foam. Pump to storage/salvage vessels. Soak up residue with an absorbent such as clay, sand, or other suitable material and dispose of properly. Flush area with water to remove trace residue. Small spills- take up with an absorbent material and place in appropriate containers for disposal. Special procedures: Contain / collect rapidly to minimize dispersion. Prevent spill from entering drainage/sewer systems, waterways, and surface waters. Use bonding/ grounding lines and non-sparking tools. On water, material is soluble and may float or sink. May biodegrade. Report per regulatory requirements. Storage: Keep in a cool place, without direct exposure to sunlight. Keep containers away from heat, sparks, open flames, and strong oxidizers. Keep container closed and otherwise in accordance with NFPA regulations. Maintain air space in storage containers. Other engineering controls : Keep container closed. Observe label precautions. Have emergency eye wash and safety shower present. Skin protection: Chemical-resistant gloves (Neoprene, nitrile) and other gear as required to prevent skin contact. Respiratory protection: A NIOSH/MSHA air purifying respirator with an organic vapor cartridge may be permissible as exposure levels dictate. Personal protective equipment Eye and face protection: Wear safety glasses. Wear coverall chemical splash goggles and face shield when eye and face contact is possible. Do not wear contacts. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering controls Ventilation : Use ventilation that is adequate to keep employee exposure to airborne concentrations below exposure limits. 7. HANDLING AND STORAGE Handling precautions: Avoid contact with skin, eyes, or clothing. Wash thoroughly with soap and water after using and particularly before eating, drinking, smoking, applying cosmetics, or using toilet facilities. Launder contaminated clothing and protective gear before reuse. Do not breathe vapor or mist. Ground container when pouring. Use non-sparking tools. Handle empty containers with care, vapor residue may be flammable/explosive. Material may attack some forms of plastic, aluminum, rubber, and coatings. Spill control: Avoid personal contact. Eliminate ignition sources. Ventilate area. Equip responders with proper protection. 6. ACCIDENTAL RELEASE MEASURES MSDS0619 ITW Performance Polymers - QUALCO Material Safety Data Sheet Page 3 Part No.: Q00201 Page 155 of 1287 Page 155 of 1287 Page 155 of 1287 Page 155 of 1287 ---PAGE BREAK--- Acute dermal effects: LD50 (rabbit): No data available. Acute inhalation effects: LC50 (rat): No data available. Exposure: hours. 9. PHYSICAL AND CHEMICAL PROPERTIES Melting point - 127 Boiling point 180 Vapor density (air = 2.1 Evaporation rate (butyl acetate = 1.4 Specific gravity: 0.789 Solubility in water: completely pH solution or slurry in water): n/d Percent volatile by volume: 100 VOC (grams/liter): 790 Percent solids by weight: 0 Vapor pressure (mmHg): 33 mm Hg at 68 °F However use a positive pressure air supplied respirator if there is any potential for uncontrolled release, or unknown exposure levels. Hazardous products of decomposition: Oxides of carbon and unidentified organic combustion products. Conditions under which hazardous polymerization may occur: N/A Incompatible materials: Strong oxidizing agents. Aluminum metals, NITROFORM, sulfuric acid. Eye irritation: Severe eye irritant. Subchronic effects: Rat and mouse inhalation toxicity: The subchronic NOAEL was 500 ppm based on clinical signs of CNS depression (both species) and increased body weight and blood effects (rat only) seen at 1500 ppm Carcinogenicity, teratogenicity, and mutagenicity: In response to a TSCA test rule, several studies of IPA have now been completed. The studies and their results are Acute oral effects: LD50 (rat): No data available. 11. TOXICOLOGICAL INFORMATION 10. STABILITY AND REACTIVITY This material is chemically stable. Conditions to avoid : Avoid heat , open flames, temperatures above 120 degrees F and ignition sources, and oxidizing conditions. Hazardous polymerization will not occur. MSDS0619 ITW Performance Polymers - QUALCO Material Safety Data Sheet Page 4 Part No.: Q00201 Page 156 of 1287 Page 156 of 1287 Page 156 of 1287 Page 156 of 1287 ---PAGE BREAK--- Other chronic effects: In rat inhalation neurotoxicity and oral developmental neurotoxicity studies, there was no evidence that IPA caused neurotoxicity in adults (max dose 5000 ppm) or (max dose 1200 ppm). as follows: 1) Both mutagenicity studies, the mouse micronucleus and CHO assays, were negative. 2) Rat and rabbit oral teratogenicity and developmental toxicology: a) there was no evidence that IPA caused teratogenicity in rats or rabbits. b) Developmental toxicity was seen in rats at 1200 mg/kg (evidenced by body weight) while no developmental toxicity was seen in the rabbit study. For rats, the NOAEL was 400 mg/kg; for rabbits 480 mg/kg. This work also identified pregnant rabbits to be approximately eight times more sensitive to IPA's lethal effects than non-pregnant rabbits. Mobility and persistence: No data available. Environmental fate: No data available. 13. DISPOSAL CONSIDERATIONS Waste management recommendations: If this product becomes a waste, it would be a hazardous waste by RCRA criteria (40CFR 261). Dispose of according to applicable federal, state, and local regulations. Please see also Section 15, Regulatory Information. 12 ECOLOGICAL INFORMATION Ecotoxicity: No data available. Constituent Oral LD50 (rat) Dermal LD50 (rabbit) Inhalation LC50 4hr, (rat) Carbon dioxide n/d n/d n/d Isopropanol 5045 mg/kg 12.8 g/kg 22627 ppm Toxicological information on hazardous chemical constituents of this product: 'n/d' = 'not determined' MSDS0619 ITW Performance Polymers - QUALCO Material Safety Data Sheet Page 5 Part No.: Q00201 Page 157 of 1287 Page 157 of 1287 Page 157 of 1287 Page 157 of 1287 ---PAGE BREAK--- For purposes of SARA Section 312 hazardous materials inventory reporting, the following hazard classes apply to this material: - Immediate health hazard Delayed health hazard Fire hazard - 14. TRANSPORT INFORMATION Proper shipping name: Aerosols Technical name : Hazard class : 2.1 UN number: 1950 Packing group: Emergency Response Guide no.: IMDG page number: N/A Other: Domestic US: Consumer Commodity, ORM-D *Depending upon the size and type of container, this material may be reclassified as "Consumer Commodity, ORM-D" for shipments within the United States, or "Limited Quantity" elsewhere. Refer to the appropriate regulation. * : ORM-D : Y Constituent Extremely Hazardous* Toxic Chemical** CERCLA RQ (lbs) TSCA 12B Export Notification Carbon dioxide No No 0.0 Not required Isopropanol No Yes 0.0 Required Regulatory status of hazardous chemical constituents of this product: *Consult the appropriate regulations for emergency planning and release reporting requirements for substances on the SARA Section 301 Extremely Hazardous Substance list. **Substances for which the "Toxic Chemical" column is marked "Yes" are on the SARA Section 313 list of Toxic Chemicals, for which release reporting may be required. For specific requirements, consult the appropriate regulations. 15. REGULATORY INFORMATION U.S. Federal Regulations The following RCRA code(s) applies to this material if it becomes waste: D001 All ingredients of this product are listed, or are exempt from listing, on the TSCA inventory. TSCA : WHMIS hazard class(es) : B2; D2B Canadian regulations All components of this product are on the Domestic Substances List. MSDS0619 ITW Performance Polymers - QUALCO Material Safety Data Sheet Page 6 Part No.: Q00201 Page 158 of 1287 Page 158 of 1287 Page 158 of 1287 Page 158 of 1287 ---PAGE BREAK--- The information and recommendations in this document are based on the best information available to us at the time of preparation, but we make no other warranty, express or implied, as to its correctness or completeness, or as to the results of reliance on this document. Hazardous Materials Identification System (HMIS) ratings: Health 2* Flammability 3 Reactivity 0 16. OTHER INFORMATION MSDS0619 ITW Performance Polymers - QUALCO Material Safety Data Sheet Page 7 Part No.: Q00201 Page 159 of 1287 Page 159 of 1287 Page 159 of 1287 Page 159 of 1287 ---PAGE BREAK--- MSDS0619 ITW Performance Polymers - QUALCO Material Safety Data Sheet Page 8 Part No.: Q00201 Page 160 of 1287 Page 160 of 1287 Page 160 of 1287 Page 160 of 1287 ---PAGE BREAK--- SECTION I - MATERIAL SAFETY DATA SHEET PAGE 1 OF 2 SUPPLIER'S NAME AND ADDRESS: CARQUEST CANADA. 1670 RUE EIFFEL BOUCHERVILLE, QC J4B 7W1 1-[PHONE REDACTED] (24 Hour Emergency Only) [PHONE REDACTED] DATE PREPARED: 11/01/2004 HAZARD RATING HMIS NFPA MATERIAL NAME : AEROSOL SPRAY PAINT 4 = SEVERE HEALTH 1 HEALTH 2 CHEMICAL FORMULA : MIXTURE 3 = SERIOUS FLAMMABILITY 4 FLAMMABILITY 4 INT'L UN NO. : 1950 2 = MODERATE REACTIVITY 0 REACTIVITY 0 NE = NONE ESTABLISHED 1 = SLIGHT PERSONAL - OTHER NA = NONE AVAILABLE 0 = MINIMAL PROTECTION E SECTION II - HAZARDOUS INGREDIENTS PRODUCT NAME : COLOR FLO PROD.# PROD.# PROD.# PROD.# PROD.# PROD.# PRIMERS 14262 14268 14277 ALUM. 14260 14263 14269 14279 14266 TRACTOR & INDUSTRIAL 14261 14265 14270 14280 14267 14272 14282 14273 14284 EXPOSURE LD 50 LC 50 (RAT 14275 INGREDIENT CAS TWA LIMITS (ORAL RAT) INHALATION) NUMBER PPM SOURCE G/Kg P.P.M. % (wt) % (wt) % (wt) % (wt) % (wt) ACETONE 67-64-1 750 ACGIH 9.7 16,000 40-45 33-42 30-40 30-40 15-20 ALIPHATIC HYDROCARBON 64742-89-8 300 RECOMMENDED 25.0 14,000 AROMATIC HYDROCARBON 64742-95-6 NE RECOMMENDED 4.7 3,670 0-5 ETHYL ACETATE 141-78-6 400 ACGIH 5.6 8,000 0-5 ETHYL ALCOHOL 64-17-5 1000 ACGIH 13.7 NA 5-10 5-10 5-10 ETHYL 3-ETHOXY PROPIONATE 763-69-9 50 RECOMMENDED 4.3 1,000 0-5 5-10 5-10 5-10 DI-ISOBUTYL KETONE 108-83-8 25 ACGIH 3.2 1,979 ISOBUTYL ACETATE 110-19-0 150 ACGIH 3.2 - 6.4 NA 0-5 ISOPROPYL ALCOHOL 67-63-0 400 ACGIH NA NA 0-5 METHYL ETHYL KETONE 78-93-3 200 ACGIH 3.4 8,000 0-5 0-5 0-5 0-5 METHYL ISOBUTYL KETONE 108-10-1 50 ACGIH 1.6 - 3.2 2,000-4,000 MINERAL SPIRITS 64742-48-9 100 RECOMMENDED 4.7 3,670 0-5 OXO ALCOHOL ESTER 88230-35-7 50 RECOMMENDED NA NA TOLUENE 108-88-3 100 ACGIH 2.5 8,000 XYLENE 1330-20-7 100 ACGIH 4.3 6,350 5-10 5-10 5-10 5-10 45-50 PROPANE-ISOBUTANE MIXTURE 68476-86-8 1000 RECOMMENDED NE NE 23 23 23 23 SECTION III - PHYSICAL DATA BOILING RANGE: 42 - 195 °C VAPOR DENSITY: (AIR = 1) MORE THAN 1 MELTING POINT: Estimated min. 1500° F % VOLATILE BY VOLUME : 83 - 90 FREEZING POINT: Below 50°C SPECIFIC GRAVITY : (H2O- < 1 VAPOR PRESSURE: (mm Hg, at 20°C) : 0.8 - 186 EVAPORATION RATE: (Butyl Acetate = 1) 0.06 TO 5.7 PHYSICAL STATE: GAS LIQUID SOILD COEFFICIENT OF WATER APPEARANCE AND ODOR: Typical solvent paint /OIL DISTRIBUTION : NOT APPLICABLE ODOR THRESHOLD: NA PH: NOT APPLICABLE SOLUBILITY IN WATER: (20° Slight WEIGHT PER GALLON: 7.9 - 8.0 (PAINT) Continue on page 2 Page 161 of 1287 Page 161 of 1287 Page 161 of 1287 Page 161 of 1287 ---PAGE BREAK--- REVISED 11/01/2004 FOR CANADA PAGE 2 OF 2 SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION: EXTREMELY FLAMMABLE FLASH POINT: (-18° C) TCC NOT SENSITIVE TO MECHANICAL IMPACT. (Propellant = -73° C) LEL 1.0 VEL : 14.0 EXTINGUISHING MEDIA: ALCOHOL FOAM, CO2, DRY CHEMICAL AUTOIGNITION TEMPERATURE : 320°C UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode and/or autoignite when exposed to extreme heat, vapors are heavier than air and may travel along the ground or may be moved by ventilation and ignited by pilot lights, other flames, sparks, heaters, smoking, electric motors or other locations distant from material handling point. SPECIAL FIRE FIGHTING PROCEDURES: Water spray may be ineffective. Water may be used to cool closed containers to prevent pressure build and possible autoignition or explosion when exposed to extreme heat. If water is used, fog nuzzles are preferable use self-contained breathing apparatus with full face piece operated in pressure demand or other positive pressure mode. SECTION V - REACTIVITY DATA STABILITY: YES NO - IF NO UNDER WHICH HAZARDOUS POLYMERIZATION: MAY OCCUR WILL NOT OCCUR INCOMPATIBILITY (Materials to avoid): AVOID CONTACT WITH STRONG OXIDIZING AGENTS AND HEAT. HAZARDOUS DECOMPOSITION PRODUCTS: MAY FORM TOXIC MATERIALS, CARBON DIOXIDE/CARBON MONOXIDE, VARIOUS HYDROCARBONS, NITROGEN COMPOUNDS, ETC., WHEN BURNED. CONDITIONS TO AVOID: HEAT, SPARKS, AND OPEN FLAME. SECTION VI - TOXICOLOGICAL PROPERTIES OF PRODUCT ROUTE(S) OF ENTRY: INHALATION CHRONIC INHALATION ACUTE EYE CONTACT SKIN CONTACT CARCINOGENICITY: REPRODUCTIVE EFFECTS TERATOGENICITY MATAGENICITY SKIN ABSORPTION INGESTION OF OVEREXPOSURE: ACUTE: BREATHING - EXCESSIVE INHALATION OF VAPORS CAN CAUSE NASAL AND RESPIRATORY IRRITATION, DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE, POSSIBLE UNCONSCIOUSNESS AND EVEN EYE CONTACT - CAN CAUSE SEVERE IRRITATION, REDNESS, TEARING, BLURRED VISION. SWALLOWING - CAN CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, DIARRHEA. SKIN CONTACT - CAN CAUSE IRRITATION FOR SOME PERSONS. CHRONIC: REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE, SEVERE OVEREXPOSURE IN LABORATORY ANIMALS HAS ALSO CAUSED LIVER ABNORMALITIES AND DAMAGE TO KIDNEYS, LUNGS, AND SPLEEN, HEART AND ADRENALS. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL. MEDICAL CONDITIONS: Generally Aggravated By Exposure - Can cause respiratory and/or skin reaction. SENSITIZATION TO PRODUCTS: NONE KNOWN SYNERGISTIC MATERIALS : NONE KNOWN SECTION VII - PREVENTIVE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: ELIMINATE ALL IGNITION SOURCES, VENTILATE AREA, ABSORB LIQUID ON PAPER, VERMICULITE, FLOOR ABSORBENT, OR OTHER ABSORBENT MATERIAL AND TRANSFER TO A CLOSED CONTAINER. WASTE DISPOSAL METHOD: MATERIAL COLLECTED ON ABSORBENT MATERIAL MAY BE DEPOSITED IN A POSTED TOXIC SUBSTANCE LANDFILL IN ACCORDANCE WITH LOCAL, PROVINCIAL, AND FEDERAL REGULATIONS. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING : DO NOT PUNCTURE OR INCINERATE. DO NOT STORE IN AREAS ABOVE 50° C, OR IN DIRECT SUNLIGHT, OR NEAR HEAT OR OPEN FLAMES. SPECIAL SHIPPING INFORMATION : KEEP BELOW 50° C OTHER PRECAUTIONS : NONE. RESPIRATORY : USE A CARTRIDGE TYPE RESPIRATOR IF EXPOSURE EXCEEDS LIMITS OR CAUSES DISCOMFORT. ENGINEERING CONTROLS : PROVIDE SUFFICIENT VENTILATION TO MAINTAIN EXPOSURE BELOW TLV'S IN SECTION II. GLOVES : NONE NORMALLY REQUIRED FOOTWEAR: NONE NORMALLY REQUIRED EYE PROTECTION : SAFETY GLASSES. CLOTHING: NONE NORMALLY REQUIRED OTHER : NONE SECTION VIII - FIRST AID MEASURES EMERGENCY PROCEDURES: 1. IF BREATHED - REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. IF BREATHING IS STOPPED, GIVE ARTIFICIAL RESPIRATION AND SEEK MEDICAL HELP. 2. IF IN EYES - FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. 3. IF SWALLOWED - DO NOT INDUCE VOMITING (ASPIRATION OF MATERIAL INTO LUNGS CAN CAUSE PNEUMONTIS, WHICH CAN BE FATAL). KEEP PERSON WARM, QUIET AND GET MEDICAL ATTENTION/POISON CONTROL CENTER. 4. IF ON SKIN - WASH WITH SOAP AND WATER OR VARIOUS HAND CLEANERS, AND WASH CLOTHING . SECTION IX - PREPARATION DATE OF M.S.D.S. PREPARED BY : _____Godfrey PHONE NUMBER : 671-8333_________ DATE : ______11-01-2004 THE INFORMATION CONTAINED ABOVE IS BELIEVED TO BE ACCURATE. BUT IS NOT WARRANTED. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT, APPLICABLE, AND SUITABLE TO CIRCUMSTANCES. Page 162 of 1287 Page 162 of 1287 Page 162 of 1287 Page 162 of 1287 ---PAGE BREAK--- Air Brake Conditioner Page 1 of 10 SDS Preparation Date (mm/dd/yyyy): 05/31/2015 SAFETY DATA SHEET SECTION 1. IDENTIFICATION Product identifier used on the label Air Brake Conditioner : Product Code(s) : US Product Codes: 00157, 90157, 00158, 90158, 00159 Canadian Product Codes: None known. Automotive - Brake System No restrictions on use known. : Recommended use of the chemical and restrictions on use Chemical family : Alcohol Name, address, and telephone number of the manufacturer: Name, address, and telephone number of the supplier: FPPF Chemical Company, Inc. Refer to manufacturer 117 West Tupper Street Buffalo, NY, USA 14201 1-[PHONE REDACTED] : Manufacturer's Telephone # 24 Hr. Emergency Tel # : Chemtrec 1-[PHONE REDACTED] (Within Continental Chemtrec [PHONE REDACTED] (Outside SECTION 2. HAZARDS IDENTIFICATION Classification of the chemical Clear colourless liquid. This material is classified as hazardous under U.S. OSHA regulations (29CFR 1910.1200) (Hazcom 2012) and Canadian WHMIS regulations (Hazardous Products Regulations) (WHMIS 2015). Classification Flammable Liquid - Category 2 Acute toxicity Oral Category 3 Acute toxicity Dermal Category 3 Acute toxicity Inhalation Category 3 Eye Damage/Irritation - Category 2A Reproductive Toxicity - Category 2 Specific Target Organ Toxicity, Single Exposure - Category 1 Label elements Hazard pictogram(s) DANGER! Signal Word Highly flammable liquid and vapour Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes serious eye irritation. Suspected of damaging fertility or the unborn child. Causes damage to the optic nerve and central nervous system. Hazard statement(s) Precautionary statement(s) Page 163 of 1287 Page 163 of 1287 Page 163 of 1287 Page 163 of 1287 ---PAGE BREAK--- Air Brake Conditioner Page 2 of 10 SDS Preparation Date (mm/dd/yyyy): 05/31/2015 SAFETY DATA SHEET Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat, sparks and open flame. - No smoking. Keep container closed. Ground/Bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Use only outdoors or in a well-ventilated area. Wear protective gloves/clothing and eye/face protection. Do not breathe vapours or spray mist. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. In case of fire: Use alcohol-resistant foam, carbon dioxide or dry chemical to extinguish. IF exposed: Call a POISON CENTRE or doctor/physician. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTRE or doctor/physician. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a POISON CENTRE or doctor/physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice/attention. IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician. Rinse mouth. Store in well-ventilated place. Keep cool. Store locked up. Keep container closed. Dispose of contents/container in accordance with local/regional/national/international regulations. Other hazards No OSHA defined hazard classes. Other hazards which do not result in classification: May be sensitive to static discharge. Vapors may cause flash fires. Burning produces obnoxious and toxic fumes. Ingestion can cause gastrointestinal irritation, nausea, and diarrhea. May cause skin irritation. Environmental precautions: Avoid release to the environment. See ECOLOGICAL INFORMATION, Section 12. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS CAS # Chemical name Concentration Common name and synonyms 67-56-1 Methanol 99.0 - 100.0 Carbinol Methyl hydrate Methyl alcohol SECTION 4. FIRST-AID MEASURES Description of first aid measures Immediately call a POISON CENTRE or doctor/physician. Rinse mouth. Do not induce vomiting, unless directed to do so by qualified medical personnel. Never give anything by mouth to an unconscious person. : Ingestion IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTRE or doctor/physician. If breathing has stopped, give artificial respiration. If breathing is difficult, give oxygen by qualified medical personnel only. : Inhalation IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a POISON CENTRE or doctor/physician if exposed or you feel unwell. Skin contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice/attention. Eye contact : Page 164 of 1287 Page 164 of 1287 Page 164 of 1287 Page 164 of 1287 ---PAGE BREAK--- Air Brake Conditioner Page 3 of 10 SDS Preparation Date (mm/dd/yyyy): 05/31/2015 SAFETY DATA SHEET Most important and effects, both acute and delayed If exposed or concerned: Call a POISON CENTER or doctor/physician. Toxic if inhaled. may include coughing, choking and wheezing. Inhalation of methanol vapours may cause substantial visual effects, including irritation, blurred vision, and blindness. May cause irritation to the nose, throat and upper respiratory tract. May cause headache, nausea, dizziness and other of central nervous system depression. May result in unconsciousness and possibly death. Toxic in contact with skin. May be absorbed through the skin, producing similar to ingestion or inhalation. Toxic if swallowed. May be fatal or cause blindness if swallowed in sufficient quantities. may include pain, headache, nausea, vomiting, dizziness, drowsiness and other central nervous system effects. Swallowing methanol is life threatening. May result in unconsciousness and possibly death. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Causes serious eye irritation. may include a burning sensation, pain, watering, and/or changes in vision (blurred vision). Methanol is known to cause appreciable eye irritation, and possible blindness. Suspected of damaging the unborn child. May cause fetotoxic (toxic to the fetus during the latter stages of pregnancy, often through the placenta) and teratogenic effects (causing malformations of the fetus), based on animal information. Causes damage to organs. Causes damage to the optic nerve and central nervous system. Direct skin contact may cause slight or mild, transient irritation. may include changes in organ weight. Prolonged exposure to high vapour concentrations can cause headache, dizziness, nausea, central nervous system depression, and narcosis. Prolonged or repeated contact may cause drying, cracking and defatting of the skin. : Indication of any immediate medical attention and special treatment needed Treat same as methanol poisoning. Immediate medical attention is required. Provide general supportive measures and treat Show this safety data sheet to the doctor in attendance. : SECTION 5. FIRE-FIGHTING MEASURES Extinguishing media : Suitable extinguishing media Dry chemical, foam, carbon dioxide and water fog. : Unsuitable extinguishing media Do not use water jet, as this may spread burning material. Highly flammable liquid and vapour Keep away from heat, sparks, and open flames. Vapours may be heavier than air and may collect in confined and low-lying areas. Vapour can travel considerable distance and flashback to a source of ignition. Product may ignite when exposed to heat, sparks and direct flame. Material will float on water and can be re-ignited at the water’s surface. May be sensitive to static discharge. Closed containers may rupture if exposed to excess heat or flame due to a build-up of internal pressure. : Special hazards arising from the substance or mixture / Conditions of flammability Flammability classification (OSHA 29 CFR 1910.106) : Flammable Liquid - Category 2 Carbon oxides; formaldehyde; irritating fumes and smoke . : Hazardous combustion products Special protective equipment and precautions for firefighters Protective equipment for fire-fighters : Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Firefighters should wear proper protective equipment and self-contained breathing apparatus with full face piece operated in positive pressure mode. : Special fire-fighting procedures Move containers from fire area if safe to do so. Cool closed containers exposed to fire with water spray. Prevent runoff from fire control or dilution from entering sewers, drains, drinking water supply or any natural waterway. Dike for water control. Page 165 of 1287 Page 165 of 1287 Page 165 of 1287 Page 165 of 1287 ---PAGE BREAK--- Air Brake Conditioner Page 4 of 10 SDS Preparation Date (mm/dd/yyyy): 05/31/2015 SAFETY DATA SHEET Immediately evacuate personnel to safe areas. Keep all other personnel upwind and away from the spill/release.All persons dealing with clean-up should wear the appropriate protective equipment including self-contained breathing apparatus. Restrict access to area until completion of clean-up. Refer to protective measures listed in sections 7 and 8. Personal precautions, protective equipment and emergency procedures : SECTION 6. ACCIDENTAL RELEASE MEASURES Ensure spilled product does not enter drains, sewers, waterways, or confined spaces. For large spills, dike the area to prevent spreading. Environmental precautions : Ventilate the area. Remove all sources of ignition. Prevent further leakage or spillage if safe to do so. Dike for water control. Use only non-sparking tools. For spilled liquids: absorb spill with inert, non-combustible material such as sand, then place into suitable containers. Do not use combustible absorbents, such as sawdust. Bond and ground transfer containers and equipment to avoid static accumulation. Pick up and transfer to properly labelled containers. Contaminated absorbent material may pose the same hazards as the spilled product. Contact the proper local authorities. : Methods and material for containment and cleaning up Special spill response procedures : In case of a transportation accident, in the United States contact CHEMTREC at 1-[PHONE REDACTED] or International at 1-[PHONE REDACTED]. If a spill/release in excess of the EPA reportable quantity is made into the environment, immediately notify the national response center in the United States (phone: 1-[PHONE REDACTED]). US CERCLA Reportable quantity (RQ): Methanol (5000 lbs / 2270 kg) Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat, open flames and hot surfaces. - No smoking. Keep container closed. Ground/Bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary measures against static discharges. Use only outdoors or in a well-ventilated area. Do not breathe mist or vapors. Wear protective gloves/clothing and eye/face protection. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Do not ingest. Do not get in eyes, on skin, or on clothing. Avoid contact with incompatible materials. Precautions for safe handling : SECTION 7. HANDLING AND STORAGE : Conditions for safe storage Keep cool. Store in well-ventilated place. Keep container closed. Store locked up. Store away from incompatibles and out of direct sunlight.Storage area should be clearly identified, clear of obstruction and accessible only to trained and authorized personnel. Inspect periodically for damage or leaks. No smoking in the area. : Incompatible materials Strong oxidizing agents; Hydrogen peroxide; Reactive metals ;Acids . SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Limits: Chemical Name STEL PEL STEL TWA ACGIH TLV OSHA PEL Methanol N/Av 200 ppm (260 mg/m³) 250 ppm (skin) 200 ppm (skin) Exposure controls Ventilation and engineering measures : Use only outdoors or in a well-ventilated area. Apply technical measures to comply with the occupational exposure limits. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. Use explosion-proof equipment. In case of insufficient ventilation wear suitable respiratory equipment. Page 166 of 1287 Page 166 of 1287 Page 166 of 1287 Page 166 of 1287 ---PAGE BREAK--- Air Brake Conditioner Page 5 of 10 SDS Preparation Date (mm/dd/yyyy): 05/31/2015 SAFETY DATA SHEET Respiratory protection : If engineering controls and work practices are not effective in controlling exposure to this material, then wear suitable approved respiratory protection. If the TLV is exceeded, a NIOSH/MSHA-approved respirator is advised. Respirators should be selected based on the form and concentration of contaminants in air, and in accordance with OSHA (29 CFR 1910.134) or CSA Z94.4-02. Wear protective gloves/clothing. Where extensive exposure to product is possible, use resistant coveralls, apron and boots to prevent contact. The suitability for a specific workplace should be discussed with the producers of the protective gloves. : Skin protection Wear eye/face protection. Chemical splash goggles are recommended. A full face shield may also be necessary. : Eye / face protection Other protective equipment : Ensure that eyewash stations and safety showers are close to the workstation location. Other equipment may be required depending on workplace standards. General hygiene considerations : Do not breathe mist or vapors. Do not eat, drink or smoke when using this product. Do not get in eyes, on skin, or on clothing. Remove and wash contaminated clothing before re-use. Handle in accordance with good industrial hygiene and safety practice. Clear, colorless liquid. : Appearance SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES : Odour Mild. Alcohol odour. Odour threshold : N/Av : pH N/Av -144.04°F (-97.8°C)estimated : Melting/Freezing point 148.6°F (64.7°C) : Initial boiling point and boiling range Flash point : 12°C / 54°F Tag closed cup Flashpoint (Method) : 3.5 : Evaporation rate (BuAe = 1) Flammability (solid, gas) : N/Ap Lower flammable limit by vol.) : 5.5% 36.5% : Upper flammable limit by vol.) None known. : Oxidizing properties Explosive properties : Not explosive : 96mm Hg Vapour pressure : 1.1 Vapour density : 0.8 Relative density / Specific gravity Solubility in water Complete : Other solubility(ies) : N/Av Partition coefficient: n-octanol/water or Coefficient of water/oil distribution N/Av : 464°F (240°C)estimated : Auto-ignition temperature Decomposition temperature : N/Av 0.75mm²/s at20°C Viscosity : 100%estimated Volatiles by weight) : : Volatile organic Compounds (VOC's) 100%estimated Absolute pressure of container : N/Ap Flame projection length : N/Av None reported by the manufacturer. : Other physical/chemical comments Not normally reactive. SECTION 10. STABILITY AND REACTIVITY : Reactivity Page 167 of 1287 Page 167 of 1287 Page 167 of 1287 Page 167 of 1287 ---PAGE BREAK--- Air Brake Conditioner Page 6 of 10 SDS Preparation Date (mm/dd/yyyy): 05/31/2015 SAFETY DATA SHEET Stable under normal conditions. : Chemical stability Possibility of hazardous reactions : Hazardous polymerization does not occur. May be sensitive to static discharge. : Keep away from heat, sparks and open flame. - No smoking. Keep away from direct sunlight. Do not use in areas without adequate ventilation. Avoid contact with incompatible materials. Conditions to avoid Incompatible materials : Strong oxidizing agents; Hydrogen peroxide; Reactive metals ;Acids . None reported by the manufacturer. Refer also to hazardous combustion products, Section 5. Hazardous decomposition products : : Routes of entry inhalation Information on likely routes of exposure: SECTION 11. TOXICOLOGICAL INFORMATION YES : Routes of entry skin & eye YES : Routes of entry Ingestion YES : Routes of exposure skin absorption YES : Sign and Inhalation Toxic if inhaled. may include coughing, choking and wheezing. Inhalation of methanol vapours may cause substantial visual effects, including irritation, blurred vision, and blindness. May cause irritation to the nose, throat and upper respiratory tract. May result in unconsciousness and possibly death. Potential Health Effects: Signs and of short-term (acute) exposure : Sign and ingestion Toxic if swallowed. May be fatal or cause blindness if swallowed in sufficient quantities. may include pain, headache, nausea, vomiting, dizziness, drowsiness and other central nervous system effects. Swallowing methanol is life threatening. May result in unconsciousness and possibly death. Ingestion can cause gastrointestinal irritation, nausea, and diarrhea. : Sign and skin Toxic in contact with skin. May be absorbed through the skin, producing similar to ingestion or inhalation. : Sign and eyes Causes serious eye irritation. may include a burning sensation, pain, watering, and/or changes in vision (blurred vision). Methanol is known to cause appreciable eye irritation, and possible blindness. Causes central nervous system depression. Inhalation of methanol vapours may cause substantial visual effects, including irritation, blurred vision, and blindness. Causes damage to the optic nerves (eyes) if swallowed. Prolonged or repeated skin contact may cause defatting and drying resulting in irritation and possible dermatitis. : Potential Chronic Health Effects Mutagenicity : Not expected to be mutagenic in humans. Carcinogenicity : No components are listed as carcinogens by ACGIH, IARC, OSHA or NTP. Reproductive effects & Teratogenicity : This material is classified as hazardous under U.S. OSHA regulations (29CFR 1910.1200) (Hazcom 2012) and Canadian WHMIS regulations (Hazardous Products Regulations) (WHMIS 2015). Classification: Reproductive Toxicity - Category 2 Suspected of damaging the unborn child. Methanol has been shown to produce fetotoxicity in the embryo or fetus in laboratory animals. Sensitization to material : Not expected to be a skin or respiratory sensitizer. Page 168 of 1287 Page 168 of 1287 Page 168 of 1287 Page 168 of 1287 ---PAGE BREAK--- Air Brake Conditioner Page 7 of 10 SDS Preparation Date (mm/dd/yyyy): 05/31/2015 SAFETY DATA SHEET Specific target organ effects : Eyes, skin, respiratory system, digestive system, central nervous system. This material is classified as hazardous under U.S. OSHA regulations (29CFR 1910.1200) (Hazcom 2012) and Canadian WHMIS regulations (Hazardous Products Regulations) (WHMIS 2015). Classification: Specific Target Organ Toxicity, Single Exposure - Category 1 Causes damage to the optic nerves (eyes) if swallowed. Inhalation of methanol vapours may cause substantial visual effects, including irritation, blurred vision, and blindness. The substance or mixture is not classified as specific target organ toxicant, repeated exposure. Medical conditions aggravated by overexposure : Pre-existing skin, eye, respiratory and central nervous system disorders. Synergistic materials : Not available. There is no available data for the product itself, only for the ingredients. See below for individual ingredient acute toxicity data. Toxicological data : LD50 LC50(4hr) inh, rat Chemical name (Rabbit, dermal) (Oral, rat) Methanol > 5000 ppm/6H (4.1 mg/L/4H (vapour) The estimated human lethal dose is: 300 - 1000 mg/kg > 393 mg/kg (Monkey) Other important toxicological hazards : None reported by the manufacturer. SECTION 12. ECOLOGICAL INFORMATION No data is available on the product itself. See the following tables for individual ingredient ecotoxicity data. : Ecotoxicity Ecotoxicity data: NOEC / 21 day LC50 / 96h M Factor Toxicity to Fish CAS No Ingredients Methanol 15 400 mg/L (Bluegill sunfish) 67-56-1 N/Av None. CAS No Ingredients Toxicity to Daphnia EC50 / 48h NOEC / 21 day M Factor 67-56-1 None. 208 mg/L (QSAR) > 10 000 mg/L (Daphnia magna) Methanol CAS No Ingredients Toxicity to Algae EC50 / 96h or 72h NOEC / 96h or 72h M Factor 67-56-1 Methanol 22 000 mg/L/96hr (Green algae) N/Av None. No data is available on the product itself. Methanol is readily biodegradable. Persistence and degradability : Bioaccumulation potential : No data is available on the product itself. See the following data for ingredient information. Page 169 of 1287 Page 169 of 1287 Page 169 of 1287 Page 169 of 1287 ---PAGE BREAK--- Air Brake Conditioner Page 8 of 10 SDS Preparation Date (mm/dd/yyyy): 05/31/2015 SAFETY DATA SHEET Components Partition coefficent n-octanol/ater (log Kow) Bioconcentration factor (BCF) Methanol (CAS 67-56-1) -0.74 N/Av : Mobility in soil No data is available on the product itself. The ecological characteristics of this product have not been fully investigated. No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. The product should not be allowed to enter drains or water courses, or be deposited where it can affect ground or surface waters. Other Adverse Environmental effects : SECTION 13. DISPOSAL CONSIDERATIONS Handling for Disposal : Handle in accordance with good industrial hygiene and safety practice. Refer to protective measures listed in sections 7 and 8. Dispose in accordance with all applicable federal, state, provincial and local regulations. : Methods of Disposal : RCRA If this product, as supplied, becomes a waste in the United States, it may meet the criteria of a hazardous waste as defined under RCRA, Title 40 CFR 261. It is the responsibility of the waste generator to determine the proper waste identification and disposal method. For disposal of unused or waste material, check with local, state and federal environmental agencies. SECTION 14. TRANSPORTATION INFORMATION Regulatory Information UN Number UN proper shipping name Packing Group Label Transport hazard class(es) METHANOL 3 TDG UN1230 II Additional information This product does not meet the criteria for an environmentally hazardous mixture, according to the IMDG Code. TDG METHANOL 3 49CFR/DOT UN1230 II Additional information US CERCLA Reportable quantity (RQ): (5000 lbs / 2270 kg) This product does not meet the criteria for an environmentally hazardous mixture, according to the IMDG Code. 49CFR/DOT : Keep away from heat, sparks and open flame. - No smoking. Special precautions for user Environmental hazards : This product does not meet the criteria for an environmentally hazardous mixture, according to the IMDG Code. See ECOLOGICAL INFORMATION, Section 12. Not available. : Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Components listed below are present on the following U.S. Federal chemical lists: US Federal Information: SECTION 15 - REGULATORY INFORMATION Ingredients CAS # TSCA Inventory CERCLA Reportable Quantity(RQ) (40 CFR 117.302): SARA TITLE III: Sec. 302, Extremely Hazardous Substance, 40 CFR 355: SARA TITLE III: Sec. 313, 40 CFR 372, Specific Toxic Chemical Toxic Chemical de minimus Concentration Methanol 67-56-1 5000 lbs / 2270 kg None. 1% Yes Yes Page 170 of 1287 Page 170 of 1287 Page 170 of 1287 Page 170 of 1287 ---PAGE BREAK--- Air Brake Conditioner Page 9 of 10 SDS Preparation Date (mm/dd/yyyy): 05/31/2015 SAFETY DATA SHEET SARA TITLE III: Sec. 311 and 312, MSDS Requirements, 40 CFR 370 Hazard Classes: Fire Hazard; Acute Health Hazard; Chronic Health Hazard Under SARA Sections 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals. The current thresholds are 500 pounds for the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals. . The following chemicals are specifically listed by individual States: US State Right to Know Laws: Ingredients CAS # California Proposition 65 Listed Type of Toxicity State "Right to Know" Lists CA RI MA PA MN NJ 67-56-1 Methanol Yes Yes Yes Yes Yes Yes Yes Developmental All ingredients are present on the DSL. Refer to Section 2 for a WHMIS Classification for this product. Canadian Information: Components listed below are present on the following International Inventory list: International Information: CAS # Ingredients European EINECs Australia AICS Philippines PICCS Japan ENCS Korea KECI/KECL China IECSC NewZealand IOC Methanol 67-56-1 200-659-6 Present Present (2)-201 HSR001186 KE-23193 Present ACGIH: American Conference of Governmental Industrial Hygienists ATE: Acute Toxicity Estimate CA: California CAS: Chemical Abstract Services CERCLA: Comprehensive Environmental Response, Compensation, and Liability Act of 1980 CFR: Code of Federal Regulations CNS: Central Nervous System CSA: Canadian Standards Association DOT: Department of Transportation EC50: Effective Concentration 50%. EINECS: European Inventory of Existing Commercial chemical Substances ENCS: Existing and New Chemical Substances EPA: Environmental Protection Agency HMIS: Hazardous Materials Identification System HSDB: Hazardous Substances Data Bank IARC: International Agency for Research on Cancer IECSC: Inventory of Existing Chemical Substances IMDG: International Maritime Dangerous Goods Inh: Inhalation KECI: Korean Existing Chemicals Inventory KECL: Korean Existing Chemicals List LC: Lethal Concentration LD: Lethal Dose MA: Massachusetts MN: Minnesota MSHA: Mine Safety and Health Administration N/Ap: Not Applicable N/Av: Not Available NFPA: National Fire Protection Association NIOSH: National Institute of Occupational Safety and Health NJ: New Jersey NOEC: No observable effect concentration : Legend SECTION 16. OTHER INFORMATION Page 171 of 1287 Page 171 of 1287 Page 171 of 1287 Page 171 of 1287 ---PAGE BREAK--- Air Brake Conditioner Page 10 of 10 SDS Preparation Date (mm/dd/yyyy): 05/31/2015 SAFETY DATA SHEET NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration PA: PEL: Permissible exposure limit PICCS: Philippine Inventory of Chemicals and Chemical Substances RCRA: Resource Conservation and Recovery Act RI: Rhode Island RTECS: Registry of Toxic Effects of Chemical Substances SARA: Superfund Amendments and Reauthorization Act SDS: Safety Data Sheet STEL: Short Term Exposure Limit TDG: Canadian Transportation of Dangerous Goods Act & Regulations TLV: Threshold Limit Values TPQ: Threshold Planning Quantity TSCA: Toxic Substance Control Act TWA: Time Weighted Average WHMIS: Workplace Hazardous Materials Identification System Information taken from reference works and the literature. Canadian Centre for Occupational Health and Safety (CCOHS), CCInfoWeb databases, 2015 (CHEMINFO, HSDB and RTECS). European Chemicals Agency, Classification Legislation, 2015 OECD- The Global Portal to Information on Chemical Substances - eChemPortal, 2015 National occupational exposure limits Material Safety Data Sheet from manufacturer References : Preparation Date (mm/dd/yyyy) : 05/31/2015 Other special considerations for handling : Provide adequate information, instruction and training for operators. Prepared by: ICC The Compliance Center Inc. Telephone: (888) 442-9628 (888) 977-4834 (Canada) http://www.thecompliancecenter.com Prepared for: FPPF Chemical Company, Inc. 117 West Tupper Street Buffalo, NY, USA 14201 Telephone: 1-[PHONE REDACTED] Please direct all enquiries to FPPF Chemical Company DISCLAIMER This Material Safety Data Sheet was prepared by ICC The Compliance Center Inc using information provided by / obtained from FPPF Chemical Company, Inc and CCOHS’ Web Information Service. The information in the Material Safety Data Sheet is offered for your consideration and guidance when exposed to this product. ICC The Compliance Center Inc and FPPF Chemical Company, Inc expressly disclaim all expressed or implied warranties and assume no responsibilities for the accuracy or completeness of the data contained herein. The data in this MSDS does not apply to use with any other product or in any other process. This Material Safety Data Sheet may not be changed, or altered in any way without the expressed knowledge and permission of ICC The Compliance Center Inc and FPPF Chemical Company, Inc. END OF DOCUMENT Page 172 of 1287 Page 172 of 1287 Page 172 of 1287 Page 172 of 1287 ---PAGE BREAK--- Page 173 of 1287 Page 173 of 1287 Page 173 of 1287 Page 173 of 1287 ---PAGE BREAK--- Page 174 of 1287 Page 174 of 1287 Page 174 of 1287 Page 174 of 1287 ---PAGE BREAK--- Page 175 of 1287 Page 175 of 1287 Page 175 of 1287 Page 175 of 1287 ---PAGE BREAK--- Page 176 of 1287 Page 176 of 1287 Page 176 of 1287 Page 176 of 1287 ---PAGE BREAK--- Revision 04/12; MSDS Form No. 820132 - Page 1 of 12 AMERICA'S CHOICE DIESEL MOTOR OILS – LUBRIZOL BLEND MATERIAL SAFETY DATA SHEET FOR USA AND CANADA SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: AMERICA'S CHOICE DIESEL MOTOR OILS – LUBRIZOL BLEND HD, HD-2, SHD, SHD-M, SHO-M, PLD-3, XHD-7 Includes grades 10W, 10W-30, 15W-40, 30, 40, 50, MIL-PRF-2104G, 2104H, CF, CF-2, CI-4, CI4 Plus, CJ-4 SYNONYMS: Petroleum oil; Lube oil; Petroleum hydrocarbon; Lubricant. PRODUCT CODE: Prefix 22 PRODUCT USE: For lubricating diesel engines. If this product is used in combination with other products, refer to the Material Safety Data Sheet for those products. 24-HOUR EMERGENCY PHONE NUMBER This number is for emergency MEDICAL AND TRANSPORTATION (SPILL): use only. If you desire non-emergency product information, please call a 1-[PHONE REDACTED] phone number listed below. SUPPLIER: Safety-Kleen Systems, Inc. 5360 Legacy Drive Building 2, Suite 100 Plano, Texas 75024 USA 1-[PHONE REDACTED] www.Safety-Kleen.com TECHNICAL INFORMATION: 1-[PHONE REDACTED] Press 1 then 1, then Extension 7500 MSDS FORM NUMBER: 820132 (formerly 82506) ISSUE: April 18, 2012 ORIGINAL ISSUE: June 15, 1989 SUPERSEDES: October 6, 2009 PREPARED BY: Product MSDS Coordinator APPROVED BY: MSDS Task Force Page 177 of 1287 Page 177 of 1287 Page 177 of 1287 Page 177 of 1287 ---PAGE BREAK--- AMERICA'S CHOICE DIESEL MOTOR OILS – LUBRIZOL BLEND MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 04/12; MSDS Form No. 820132- Page 2 of 12 SECTION 2: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW APPEARANCE Amber liquid, petroleum odor. CAUTION! HEALTH HAZARDS May be harmful if swallowed. May irritate eyes and skin. OSHA Regulated Chemicals No information is available. POTENTIAL HEALTH EFFECTS INGESTION (SWALLOWING): May cause throat irritation, nausea, vomiting, and diarrhea. Aspiration hazard: breathing product into the lungs during ingestion or vomiting may cause lung injury and possible death. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Individuals with pre-existing respiratory tract (nose, throat, and lungs), eye, and/or skin disorders may have increased susceptibility to the effects of exposure. CHRONIC: Prolonged or repeated inhalation of oil mist may cause oil pneumonia, lung tissue inflammation, and/or fibrous tissue formation. Prolonged or repeated eye contact may cause inflammation of the membrane lining the eyelids and covering the eyeball (conjunctivitis). Prolonged or repeated skin contact may cause drying, cracking, redness, itching, and/or swelling (dermatitis). CANCER INFORMATION: No known carcinogenicity. For more information, see SECTION 11: MUTAGENICITY and CARCINOGENICITY. Also see SECTION 15: CALIFORNIA. POTENTIAL ENVIRONMENTAL EFFECTS Not available. Also see SECTION 12: ECOLOGICAL INFORMATION. INHALATION (BREATHING): This product is not likely to present an inhalation hazard at normal temperatures and pressures. However, when aerosolizing, misting, or heating this product, high concentrations of generated vapor or mist may irritate the respiratory tract (nose, throat, and lungs). EYES: May cause irritation. SKIN: May cause irritation. Not likely to be absorbed through the skin in harmful amounts. Page 178 of 1287 Page 178 of 1287 Page 178 of 1287 Page 178 of 1287 ---PAGE BREAK--- AMERICA'S CHOICE DIESEL MOTOR OILS – LUBRIZOL BLEND MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 04/12; MSDS Form No. 820132- Page 3 of 12 SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS CAS # Component Synonym Percent 64742-58-1 Lubricating oils, petroleum, hydrotreated spent Hydrotreated paraffinic base oil 0-85* 72623-83-7 Lubricating oils (Petroleum), C>25, hydrotreated Bright Stock 0.1-55* 64742-62-7 Residual oils (petroleum), solvent dewaxed Bright Stock 0.1-55* 64742-57-0 Residual oils (petroleum), hydrotreated Bright Stock 0.1-55* 64742-01-4 Residual oils (petroleum), solvent refined Bright Stock 0-46* Not Available Mineral Oil Not Available 0.1-37.5* Not Available Proprietary Additives Not Available 10-30 64741-88-4 Petroleum distillates, solvent- refined heavy paraffinic Bright Stock 1-15* 122-39-4 Diphenylamine Not Available 1-15* 72623-86-0 Lubricating oils, petroleum, C15-30, hydrotreated neutral oil-based Not Available 0.1-11* Not Available Polyolefin Not Available 0.1-10* 64742-65-0 Distillates (petroleum), solvent dewaxed heavy paraffinic Bright Stock 0.1-6* Not Available Polyolefin amide alkeneamine Not Available 0.1-6* 64742-52-5 Petroleum distillates, hydrotreated heavy naphthenic Bright Stock 0.1-5.5* 178603-65-1 Gas oils, petroleum, vacuum, hydrocracked, hydroisomerized, hydrogenated, C20-40, branched and cyclic, high viscosity index Not Available 0.1-5.5* 178603-64-0 Gas oils, petroleum, vacuum, hydrocracked, hydroisomerized, hydrogenated, C15-30, branched and cyclic, high viscosity index Not Available 0.1-5.5* 64742-46-7 Petroleum distillates, hydrotreated middle Not Available 0.1-5.5* 72623-84-8 Lubricating oils, petroleum, C15-30, hydrotreated neutral oil-based, contg. solvent deasphalted residual oil Not Available 0.1-5.5* 178603-63-9 Gas oils, petroleum, vacuum, hydrocracked, hydroisomerized, hydrogenated, C10-25 Not Available 0.1-5.5* 178603-66-2 Gas oils, petroleum, hydrocracked, hydroisomerized, hydrogenated, C25-55, branched and cyclic, high viscosity index Not Available 0.1-5.5* 72623-87-1 Lubricating Oils, petroleum, C20- 50, hydrotreated neutral oil based Not Available 0.1-5.5* 8042-47-5 White Mineral Oil Not Available 0.1-5.5* Page 179 of 1287 Page 179 of 1287 Page 179 of 1287 Page 179 of 1287 ---PAGE BREAK--- AMERICA'S CHOICE DIESEL MOTOR OILS – LUBRIZOL BLEND MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 04/12; MSDS Form No. 820132- Page 4 of 12 445411-73-4 Gas oils, petroleum, vacuum, hydrocracked, hydroisomerized, hydrogenated, C10-25, branched and cyclic Not Available 0.1-2.5* Calcium sulfonate Not Available 0.1-2.5* Alkylated phenol Not Available 0.1-2* Alkylamine Not Available 0.1-2* 74499-35-7 Phenol, (tetraphenyl) derivatives Not Available 0.5-1.5 68411-46-1 Benzenamine, N-phenyl-, reaction products with 2,4,4- Diphenyamine, diisobutylene reaction product 0.1-1.5* 68649-42-3 Phosphorodithioic acid, O,O-di-C1- 14-alkyl esters, zinc salts Dialkyl (C1-C14) dithiophosphoric acid, zinc salt 0.1-1.5* Calcium phenate Not Available 0.1-1.5* 72623-85-9 Lubricating oils, petroleum, C20-50, hydrotreated neutral oil-based, high viscosity Not Available 0.1-1.5* Component Related Regulatory Information This product may be regulated, have exposure limits or other information identified as the following: Oil mist, mineral (8012-95-1). *Even though the concentration range does not fall under the ranges prescribed by WHMIS, this is the actual range which varies with each batch of the product. **Supplier and/or Safety-Kleen advises that this is a trade secret. SECTION 4: FIRST AID MEASURES INHALATION (BREATHING): Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Oxygen should only be administered by qualified personnel. Someone should stay with victim. Get medical attention if breathing difficulty persists. EYES: If irritation or redness from exposure to vapor develops, move away from exposure into fresh air. Upon contact, immediately flush eyes with plenty of lukewarm water, holding eyelids apart, for 15 minutes. Get medical attention. SKIN: Remove affected clothing and shoes. Wash skin thoroughly with soap and water. Get medical attention if irritation or pain develops or persists. If product is injected under pressure into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, a physician should immediately evaluate the individual as a medical emergency. Wash contaminated clothing before reuse. INGESTION (SWALLOWING): Do NOT induce vomiting. Immediately get medical attention. Call 1-[PHONE REDACTED] for additional information. If spontaneous vomiting occurs, keep head below hips to avoid breathing the product into the lungs. Never give anything by mouth to an unconscious person. NOTE TO PHYSICIANS: Treat and supportively. Treatment may vary with condition of victim and specifics of incident. Call 1-[PHONE REDACTED] for additional information. Page 180 of 1287 Page 180 of 1287 Page 180 of 1287 Page 180 of 1287 ---PAGE BREAK--- AMERICA'S CHOICE DIESEL MOTOR OILS – LUBRIZOL BLEND MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 04/12; MSDS Form No. 820132- Page 5 of 12 SECTION 5: FIRE FIGHTING MEASURES HAZARDOUS COMBUSTION PRODUCTS: Decomposition and combustion materials may be toxic. Burning may produce sulfur oxides, aldehydes, ketones, carbon monoxide and unidentified organic compounds. CONDITIONS OF FLAMMABILITY: Sparks, or flame. Product may burn, but does not ignite readily. PROTECTIVE EQUIPMENT FOR FIREFIGHTERS: A positive-pressure, self-contained breathing apparatus (SCBA) and full- body protective equipment are required for fire emergencies. EXTINGUISHING MEDIA: Carbon dioxide, regular foam, dry chemical, water spray, or water fog. Water or foam may cause frothing. NFPA 704 HAZARD IDENTIFICATION: This information is intended solely for the use by individuals trained in this system. FIRE FIGHTING INSTRUCTIONS: Keep storage containers cool with water spray. FIRE AND EXPLOSION HAZARDS: Heated containers may rupture. "Empty" containers may retain residue and can be dangerous. Product is not sensitive to mechanical impact or static discharge. SECTION 6: ACCIDENTAL RELEASE MEASURES Remove all ignition sources. Do not touch or walk through spilled product. Stop leak if you can do it without risk. Wear protective equipment and provide engineering controls as specified in SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Ventilate area and avoid breathing vapor or mist. Contain spill away from surface water and sewers. Contain spill as a liquid for possible recovery, or absorb with compatible sorbent material and shovel with a clean, spark proof tool into a sealable container for disposal. Additionally, for large spills: Dike far ahead of liquid spill for collection and later disposal. 1 0 1 FIRE HAZARD (RED) REACTIVITY (YELLOW) HEALTH HAZARD (BLUE) SPECIFIC HAZARD (WHITE) Page 181 of 1287 Page 181 of 1287 Page 181 of 1287 Page 181 of 1287 ---PAGE BREAK--- AMERICA'S CHOICE DIESEL MOTOR OILS – LUBRIZOL BLEND MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 04/12; MSDS Form No. 820132- Page 6 of 12 SECTION 7: HANDLING AND STORAGE HANDLING: Keep away from sparks, or flame. Where flammable mixtures may be present, equipment safe for such locations should be used. Use clean tools and explosion-proof equipment. When transferring large volumes of product, metal containers, including trucks and tank cars, should be grounded and bonded. This product has a low vapor pressure and is not expected to present an inhalation hazard under normal temperatures and pressures. However, when aerosolizing, misting, or heating this product, do not breathe vapor or mist. Use in a well ventilated area. Avoid contact with eyes, skin, clothing, and shoes. SHIPPING AND STORING: Keep container closed when not in use and during transport. Store containers in a cool, dry place. Do not pressurize, cut, weld, braze, solder, drill, or grind containers. Keep containers away from flame, sparks, static electricity, or other sources of ignition. Empty product containers may retain product residue and can be dangerous. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE GUIDELINES: Component Exposure Limits Lubricating oils, petroleum, hydrotreated spent (64742-58-1) ACGIH: 5 mg/m3 TWA (sampled by method that does not collect vapor) (related to Oil mist, mineral) 10 mg/m3 STEL (sampled by method that does not collect vapor) (related to Oil mist, mineral) OSHA Final: 5 mg/m3 TWA (related to Oil mist, mineral) OSHA Vacated: 5 mg/m3 TWA (related to Oil mist, mineral) NIOSH: 5 mg/m3 TWA (related to Oil mist, mineral) 10 mg/m3 STEL (related to Oil mist, mineral) Petroleum distillates, solvent-refined heavy paraffinic (64741-88-4) ACGIH: 5 mg/m3 TWA (sampled by method that does not collect vapor) (related to Oil mist, mineral) 10 mg/m3 STEL (sampled by method that does not collect vapor) (related to Oil mist, mineral) OSHA Final: 5 mg/m3 TWA (related to Oil mist, mineral) OSHA Vacated: 5 mg/m3 TWA (related to Oil mist, mineral) NIOSH: 5 mg/m3 TWA (related to Oil mist, mineral) 10 mg/m3 STEL (related to Oil mist, mineral) Diphenylamine (122-39-4) ACGIH: 10 mg/m3 TWA OSHA Vacated: 10 mg/m3 TWA NIOSH: 10 mg/m3 TWA ENGINEERING CONTROLS: Provide general ventilation needed to maintain concentration of vapor or mist below applicable exposure limits. Where adequate general ventilation is unavailable, use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below applicable exposure limits. Page 182 of 1287 Page 182 of 1287 Page 182 of 1287 Page 182 of 1287 ---PAGE BREAK--- AMERICA'S CHOICE DIESEL MOTOR OILS – LUBRIZOL BLEND MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 04/12; MSDS Form No. 820132- Page 7 of 12 PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY PROTECTION: No respiratory protection is normally required. Use NIOSH-certified P- or R- series particulate filter and organic vapor cartridges when concentration of vapor or mist exceeds applicable exposure limits. Protection provided by air purifying respirators is limited. Do not use N-rated respirators. Selection and use of respiratory protective equipment should be in accordance in the USA with OSHA General Industry Standard 29 CFR 1910.134; or in Canada with CSA Standard Z94.4. Consult a qualified Industrial Hygienist or Safety Professional for respirator selection guidance. EYE PROTECTION: Where eye contact is likely, wear safety glasses; contact lens use is not recommended. SKIN PROTECTION: Where skin contact is likely, wear chemical impervious gloves; use of natural rubber or equivalent gloves is not recommended. When product is heated and skin contact is likely, wear heat-resistant gloves, boots, and other protective clothing. To avoid prolonged or repeated contact where spills and splashes are likely, wear appropriate chemical-resistant face shield, boots, apron, coveralls, long sleeve shirts, or other protective clothing. PERSONAL HYGIENE: Use good personal hygiene. Wash thoroughly with soap and water after handling product and before eating, drinking, or using tobacco products. Clean affected clothing, shoes, and protective equipment before reuse. Discard leather articles, such as shoes, saturated with this product. OTHER PROTECTIVE EQUIPMENT: Where spills and splashes are likely, facilities storing or using this product should be equipped with an emergency eyewash and shower, both equipped with clean water, in the immediate work area. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE, APPEARANCE, AND ODOR: Amber liquid, petroleum odor. ODOR THRESHOLD: Not available MOLECULAR WEIGHT: Not applicable SPECIFIC GRAVITY: 0.87 (water (approximately) DENSITY: 7.3 LB/US gal (880 g/l) (approximately) VAPOR DENSITY: Not available VAPOR PRESSURE: less than 0.1 mm Hg at 68°F (20°C) BOILING POINT: 475°F (246°C) (minimum) FREEZING/MELTING POINT: Not available [pour point -22°F (-30°C) (maximum)] pH: Not applicable EVAPORATION RATE: Not available Page 183 of 1287 Page 183 of 1287 Page 183 of 1287 Page 183 of 1287 ---PAGE BREAK--- AMERICA'S CHOICE DIESEL MOTOR OILS – LUBRIZOL BLEND MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 04/12; MSDS Form No. 820132- Page 8 of 12 SOLUBILITY IN WATER: Insoluble FLASH POINT: 421°F (216°C) (minimum) FLAMMABLE LIMITS IN AIR: LOWER: Not available UPPER: Not available AUTOIGNITION TEMPERATURE: Not available SECTION 10: STABILITY AND REACTIVITY STABILITY: Stable under normal temperatures and pressures. CONDITIONS TO AVOID: Avoid sparks or flame. INCOMPATIBILITY: Avoid oxidizing agents. REACTIVITY: Polymerization is not known to occur under normal temperature and pressures. Not reactive with water. HAZARDOUS DECOMPOSITION PRODUCTS: None under normal temperatures and pressures. See also SECTION 5: HAZARDOUS COMBUSTION PRODUCTS. SECTION 11: TOXICOLOGICAL INFORMATION TOXICITY DATA: Component Analysis - LD50/LC50 Lubricating oils, petroleum, hydrotreated spent (64742-58-1) Oral LD50 Rat >2000 mg/kg Dermal LD50 Rat >2000 mg/kg Dermal LD50 Rabbit >4480 mg/kg Residual oils (petroleum), solvent refined (64742-01-4) Inhalation LC50 Rat 2.18 mg/L 4 h Oral LD50 Rat >5000 mg/kg Dermal LD50 Rabbit >2000 mg/kg Petroleum distillates, solvent-refined heavy paraffinic (64741-88-4) Inhalation LC50 Rat 2.18 mg/L 4 h Oral LD50 Rat >5000 mg/kg Dermal LD50 Rabbit >2000 mg/kg Diphenylamine (122-39-4) Oral LD50 Rat 1165 mg/kg Dermal LD50 Rabbit >2000 mg/kg Page 184 of 1287 Page 184 of 1287 Page 184 of 1287 Page 184 of 1287 ---PAGE BREAK--- AMERICA'S CHOICE DIESEL MOTOR OILS – LUBRIZOL BLEND MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 04/12; MSDS Form No. 820132- Page 9 of 12 ACUTE EFFECTS: May be harmful if swallowed. May irritate eyes and skin. May cause throat irritation, nausea, vomiting, and diarrhea. Aspiration hazard: breathing product into the lungs during ingestion or vomiting may cause lung injury and possible death. REPEATED DOSE EFFECTS: Prolonged or repeated inhalation of oil mist may cause oil pneumonia, lung tissue inflammation, and/or fibrous tissue formation. Prolonged or repeated eye contact may cause inflammation of the membrane lining the eyelids and covering the eyeball (conjunctivitis). Prolonged or repeated skin contact may cause drying, cracking, redness, itching, and/or swelling (dermatitis). Based on best current information, there is no known human sensitization associated with this product. Experimental evidence suggests that this product does not cause mutagenesis. Based on best current information, there is no known reproductive toxicity associated with this product. Based on best current information, there is no known teratogenicity associated with this product. CARCINOGENICITY: Based on best current information, for the components listed in SECTION 3, there is no known carcinogenicity as regulated by OSHA; as categorized by ACGIH A1 or A2 substances; as categorized by IARC Group 1, Group 2A, or Group 2B agents; or as listed by NTP as either known carcinogens or substances for which there is limited evidence of carcinogenicity in humans or sufficient evidence of carcinogenicity in experimental animals. Also see SECTION 15: CALIFORNIA. TARGET ORGAN EFFECTS: Prolonged or repeated inhalation of oil mist may cause oil pneumonia, lung tissue inflammation, and/or fibrous tissue formation. Page 185 of 1287 Page 185 of 1287 Page 185 of 1287 Page 185 of 1287 ---PAGE BREAK--- AMERICA'S CHOICE DIESEL MOTOR OILS – LUBRIZOL BLEND MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 04/12; MSDS Form No. 820132- Page 10 of 12 SECTION 12: ECOLOGICAL INFORMATION ECTOXICITY: Component Analysis - Ecotoxicity - Aquatic Toxicity Lubricating oils, petroleum, hydrotreated spent (64742-58-1) Test & Species Results Conditions 96 Hr LC50 Brachydanio rerio 79.6 mg/L semi-static 96 Hr LC50 Pimephales promelas 3.2 mg/L semi-static Residual oils (petroleum), solvent refined (64742-01-4) Test & Species Results Conditions 96 Hr LC50 mykiss >5000 mg/L Petroleum distillates, solvent-refined heavy paraffinic (64741-88-4) Test & Species Results Conditions 96 Hr LC50 mykiss >5000 mg/L Diphenylamine (122-39-4) Test & Species Results Conditions 96 Hr LC50 Pimephales promelas 3.47-4.14 mg/L flow-through 72 Hr EC50 Desmodesmus subspicatus 0.048 mg/L PERSISTENCE/ DEGRADABILITY: No information available for this product. BIOACCUMULATION/ ACCUMULATION: No information available for the product. MOBILITY IN ENVIRONMENTAL MEDIA: No information available for this product. OTHER ADVERSE EFFECTS: Not available. OCTANOL/WATER PARTITION COEFFICIENT: Not available VOLATILE ORGANIC COMPOUNDS: Negligible SECTION 13: DISPOSAL CONSIDERATIONS DISPOSAL: Dispose in accordance with federal, state, provincial, and local regulations. Regulations may also apply to empty containers. The responsibility for proper waste disposal lies with the owner of the waste. Contact Safety-Kleen regarding proper recycling or disposal. USEPA WASTE CODE(S): This product, if discarded, is not expected to be a characteristic or listed hazardous waste. If recycled in the USA, it must be managed in accordance with 40 CFR Part 279. Processing, use, or contamination by the user may change the waste code(s) applicable to the disposal of this product. Page 186 of 1287 Page 186 of 1287 Page 186 of 1287 Page 186 of 1287 ---PAGE BREAK--- AMERICA'S CHOICE DIESEL MOTOR OILS – LUBRIZOL BLEND MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 04/12; MSDS Form No. 820132- Page 11 of 12 SECTION 14: TRANSPORT INFORMATION DOT: Shipping Name: Not regulated as a hazardous material for transportation TDG: Shipping Name: Not regulated as a dangerous good for transportation. EMERGENCY RESPONSE GUIDE NUMBER: Not applicable. Reference North American Emergency Response Guidebook. SECTION 15: REGULATORY INFORMATION USA REGULATIONS OSHA OSHA Regulated Chemicals No information is available. SARA SECTIONS 302 AND 304: Based on the ingredient(s) listed in SECTION 3, this product does not contain any "extremely hazardous substances" listed pursuant to Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) Section 302 or Section 304 as identified in 40 CFR Part 355, Appendix A and B. SARA SECTIONS 311 AND 312: This product poses the following health hazard(s) as defined in 40 CFR Part 370 and is subject to the requirements of sections 311 and 312 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA): Immediate (Acute) Health Hazard Delayed (Chronic) Health Hazard SARA SECTION 313: This product contains "toxic" chemical(s) subject to the requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40 CFR Part 372. Diphenylamine (122-39-4) 1.0 % de minimis concentration CERCLA: Based on the ingredient(s) listed in SECTION 3, this product does not contain any "hazardous substances" listed pursuant to the Comprehensive Environmental Response, Compensation and Liability Act of 1980 (CERCLA) in 40 CFR Part 302, Table 302.4 TSCA: All the components of this product are listed on, or are exempted from the requirement to be listed on, the TSCA Inventory. CALIFORNIA: This product does not contain detectable amounts of any chemical known to the State of California to cause cancer. This product does not contain detectable amounts of any chemical known to the State of California to cause birth defects or other reproductive harm. Page 187 of 1287 Page 187 of 1287 Page 187 of 1287 Page 187 of 1287 ---PAGE BREAK--- AMERICA'S CHOICE DIESEL MOTOR OILS – LUBRIZOL BLEND MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 04/12; MSDS Form No. 820132- Page 12 of 12 CANADIAN REGULATIONS This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by the Controlled Products Regulations. CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA): All the components of these products are listed on, or are automatically included as "substance occurring in nature" on, or are exempted from the requirements to be listed on, the Canadian Domestic Substances List (DSL). SECTION 16. OTHER INFORMATION REVISION INFORMATION: This MSDS has been revised in the following sections: Revision to MSDS name and number. LABEL/OTHER INFORMATION: Not available. User assumes all risks incident to the use of this (these) product(s). To the best of our knowledge, the information contained herein is accurate. However, Safety-Kleen assumes no liability whatsoever for the accuracy or completeness of the information contained herein. No representations or warranties, either express or implied, or merchantability, fitness for a particular purpose or of any other nature are made hereunder with respect to information or the product to which information refers. The data contained on this sheet apply to the product(s) as supplied to the user. Page 188 of 1287 Page 188 of 1287 Page 188 of 1287 Page 188 of 1287 ---PAGE BREAK--- Revision 11/10; MSDS Form No. 82479 - Page 1 of 12 AMERICA’S CHOICE MOTOR OIL MATERIAL SAFETY DATA SHEET FOR USA AND CANADA SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: AMERICA’S CHOICE MOTOR OIL Includes Grades 5W-20, 5W-30, 10W-30, 20W-50, SAE 30 SYNONYMS: Petroleum oil; Lube oil; Petroleum hydrocarbon; Lubricant. PRODUCT CODE: Prefix 21 PRODUCT USE: For lubricating passenger car motors. If these products are used in combination with other products, refer to the Material Safety Data Sheet for those products. 24-HOUR EMERGENCY PHONE NUMBER This number is for emergency MEDICAL AND TRANSPORTATION (SPILL): use only. If you desire non-emergency product information, please call a 1-[PHONE REDACTED] phone number listed below. SUPPLIER: Safety-Kleen Systems, Inc. 5360 Legacy Drive Building 2, Suite 100 Plano, Texas 75024 USA 1-[PHONE REDACTED] www.Safety-Kleen.com TECHNICAL INFORMATION: 1-[PHONE REDACTED] Press 1 then 1, then Extension 7500 MSDS FORM NUMBER: 82479 ISSUE: November 1, 2010 ORIGINAL ISSUE: October 31, 1998 SUPERSEDES: October 30, 2009 PREPARED BY: Product MSDS Coordinator APPROVED BY: MSDS Task Force Page 189 of 1287 Page 189 of 1287 Page 189 of 1287 Page 189 of 1287 ---PAGE BREAK--- AMERICA’S CHOICE MOTOR OIL MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 11/10; MSDS Form No. 82479 - Page 2 of 12 SECTION 2: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW APPEARANCE Liquid, amber, petroleum odor. CAUTION! HEALTH HAZARDS May irritate eyes and skin. May be harmful if swallowed. OSHA Regulated Chemicals No information is available. POTENTIAL HEALTH EFFECTS INGESTION (SWALLOWING): May be harmful if swallowed. May cause throat irritation, nausea, vomiting, and diarrhea. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Individuals with pre-existing respiratory tract (nose, throat, and lungs), eye, and/or skin disorders may have increased susceptibility to the effects of exposure. CHRONIC: Prolonged or repeated inhalation of oil mist may cause oil pneumonia, lung tissue inflammation, and/or fibrous tissue formation. Prolonged or repeated eye contact may cause inflammation of the membrane lining the eyelids and covering the eyeball (conjunctivitis). Prolonged or repeated skin contact may cause drying, cracking, redness, itching, and/or swelling (dermatitis). CANCER INFORMATION: No known carcinogenicity. For more information, see SECTION 11: CARCINOGENICITY. Also see SECTION 15: CALIFORNIA. POTENTIAL ENVIRONMENTAL EFFECTS Not available. Also see SECTION 12: ECOLOGICAL INFORMATION. INHALATION (BREATHING): These products are not likely to present an inhalation hazard at normal temperatures and pressures. However, when aerosolizing, misting, or heating these products, high concentrations of generated vapor or mist may irritate the respiratory tract (nose, throat, and lungs). EYES: May cause irritation. SKIN: May cause irritation. Not likely to be absorbed through the skin in harmful amounts. Page 190 of 1287 Page 190 of 1287 Page 190 of 1287 Page 190 of 1287 ---PAGE BREAK--- AMERICA’S CHOICE MOTOR OIL MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 11/10; MSDS Form No. 82479 - Page 3 of 12 SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS AS # Component Synonym Wt. Percent* 64742-58-1 Lubricating oils, petroleum, hydrotreated spent Hydrotreated paraffinic base oil 56-85 Trade Secret Mineral oil Trade Secret 0-35 64742-01-4 Residual oils (petroleum), solvent Bright Stock 0-25 Mixture** Base oil, mixture Not Available 0-25 64742-62-7 Residual oils (petroleum), solvent dewaxed Bright Stock 0-25 72623-83-7 Lubricating oils, (petroleum), C>25, bright stock Bright Stock 0-25 72623-86-0 Neutral oil Not Available 0-25 Trade Secret Acrylic copolymer Not Available 0-25 64742-54-7 Petroleum distillates, heavy paraffinic, C20-C50 Not Available 0-25 64742-55-8 Petroleum distillates, light paraffinic, C15-C30 Not Available 0-25 68649-42-3 Phosphorodithioc acid, O,O-di-C1- 14-alkyl esters, zinc salts Dialkyl (C1-C14) dithiophosphoric acid, zinc salt 0-6 Component Related Regulatory Information This product may be regulated, have exposure limits or other information identified as the following: Oil mist, mineral (8012-95-1). *Even though the concentration range does not fall under the ranges prescribed by WHMIS, this is the actual range which varies with each batch of the product. **The base oil may be a mixture of the following CAS#s: 8042-47-5, 64742-46-7, 64742-47-8, 64742-52-5, 64742-54-7, 72623-84-8, 72623-85-9, 72623-86-0, 72623-87-1, 178603-64-0, 178603-66-2, 17603-65-1, 445411-73-4 SECTION 4: FIRST AID MEASURES INHALATION (BREATHING): Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Oxygen should only be administered by qualified personnel. Someone should stay with victim. Get medical attention if breathing difficulty persists. EYES: If irritation or redness from exposure to vapor develops, move away from exposure into fresh air. Upon contact, immediately flush eyes with plenty of lukewarm water, holding eyelids apart, for 15 minutes. Get medical attention. SKIN: Remove affected clothing and shoes. Wash skin thoroughly with soap and water. Get medical attention if irritation or pain develops or persists. If product is injected under pressure into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, a physician should immediately evaluate the individual as a medical emergency. INGESTION (SWALLOWING): Do NOT induce vomiting. Immediately get medical attention. Call 1-[PHONE REDACTED] for additional information. If spontaneous vomiting occurs, keep head below hips to avoid breathing the product into the lungs. Never give anything by mouth to an unconscious person. NOTE TO PHYSICIANS: Treat and supportively. Treatment may vary with condition of victim and specifics of incident. Call 1-[PHONE REDACTED] for additional information. Page 191 of 1287 Page 191 of 1287 Page 191 of 1287 Page 191 of 1287 ---PAGE BREAK--- AMERICA’S CHOICE MOTOR OIL MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 11/10; MSDS Form No. 82479 - Page 4 of 12 SECTION 5: FIRE FIGHTING MEASURES HAZARDOUS COMBUSTION PRODUCTS: Decomposition and combustion materials may be toxic. Burning may produce aldehydes, hydrogen sulfide, alkyl mercaptans, sulfides, carbon monoxide, and oxides of sulfur, calcium and zinc and other unidentified organic compounds. CONDITIONS OF FLAMMABILITY: Sparks, or flame. Product may burn, but does not ignite readily. PROTECTIVE EQUIPMENT FOR FIREFIGHTERS: A positive-pressure, self-contained breathing apparatus (SCBA) and full- body protective equipment are required for fire emergencies. EXTINGUISHING MEDIA: Carbon dioxide, regular foam, dry chemical, water spray, or water fog. Water or foam may cause frothing. NFPA 704 HAZARD IDENTIFICATION: This information is intended solely for the use by individuals trained in this system. FIRE FIGHTING INSTRUCTIONS: Keep storage containers cool with water spray. FIRE AND EXPLOSION HAZARDS: Heated containers may rupture. "Empty" containers may retain residue and can be dangerous. Products are not sensitive to mechanical impact or static discharge. SECTION 6: ACCIDENTAL RELEASE MEASURES Remove all ignition sources. Do not touch or walk through spilled product. Stop leak if you can do it without risk. Wear protective equipment and provide engineering controls as specified in SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Ventilate area and avoid breathing vapor or mist. Contain spill away from surface water and sewers. Contain spill as a liquid for possible recovery, or absorb with compatible sorbent material and shovel with a clean, sparkproof tool into a sealable container for disposal. Additionally, for large spills: Dike far ahead of liquid spill for collection and later disposal. 1 0 1 FIRE HAZARD (RED) REACTIVITY (YELLOW) HEALTH HAZARD (BLUE) SPECIFIC HAZARD (WHITE) Page 192 of 1287 Page 192 of 1287 Page 192 of 1287 Page 192 of 1287 ---PAGE BREAK--- AMERICA’S CHOICE MOTOR OIL MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 11/10; MSDS Form No. 82479 - Page 5 of 12 SECTION 7: HANDLING AND STORAGE HANDLING: Keep away from sparks or flame. Where flammable mixtures may be present, equipment safe for such locations should be used. Use clean tools. When transferring large volumes of product, metal containers, including trucks and tank cars, should be grounded and bonded. These products have a low vapor pressure and are not expected to present an inhalation hazard under normal temperatures and pressures. However, when aerosolizing, misting, or heating these products, do not breathe vapor or mist. Use in a well ventilated area. Avoid contact with eyes, skin, clothing, and shoes. SHIPPING AND STORING: Keep container closed when not in use and during transport. Store containers in a cool, dry place. Do not pressurize, cut, weld, braze, solder, drill, or grind containers. Keep containers away from flame, sparks, static electricity, or other sources of ignition. Empty product containers may retain product residue and can be dangerous. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE GUIDELINES: Component Exposure Limits Lubricating oils, petroleum, hydrotreated spent (64742-58-1) ACGIH: 5 mg/m3 TWA (sampled by method that does not collect vapor) (related to Oil mist, mineral) 10 mg/m3 STEL (sampled by method that does not collect vapor) (related to Oil mist, mineral) OSHA Final: 5 mg/m3 TWA (related to Oil mist, mineral) OSHA Vacated: 5 mg/m3 TWA (related to Oil mist, mineral) NIOSH: 5 mg/m3 TWA (related to Oil mist, mineral) 10 mg/m3 STEL (related to Oil mist, mineral) Mineral oil (Not Available) ACGIH: 5 mg/m3 TWA (sampled by method that does not collect vapor) (related to Oil mist, mineral) 10 mg/m3 STEL (sampled by method that does not collect vapor) (related to Oil mist, mineral) OSHA Final: 5 mg/m3 TWA (related to Oil mist, mineral) OSHA Vacated: 5 mg/m3 TWA (related to Oil mist, mineral) NIOSH: 5 mg/m3 TWA (related to Oil mist, mineral) 10 mg/m3 STEL (related to Oil mist, mineral) Lubricating oils, (petroleum), C>25, hydrotreated (72623-83-7) ACGIH: 5 mg/m3 TWA (sampled by method that does not collect vapor) (related to Oil mist, mineral) 10 mg/m3 STEL (related to Oil mist, mineral) Page 193 of 1287 Page 193 of 1287 Page 193 of 1287 Page 193 of 1287 ---PAGE BREAK--- AMERICA’S CHOICE MOTOR OIL MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 11/10; MSDS Form No. 82479 - Page 6 of 12 OSHA: 5 mg/m3 TWA (related to Oil mist, mineral) NIOSH: 5 mg/m3 TWA (related to Oil mist (mineral) 10 mg/m3 STEL (related to Oil mist (mineral) Residual oils (petroleum), hydrotreated (64742-54-7) ACGIH: 5 mg/m3 TWA (sampled by method that does not collect vapor) (related to Oil mist, mineral) 10 mg/m3 STEL (related to Oil mist, mineral) OSHA: 5 mg/m3 TWA (related to Oil mist, mineral) NIOSH: 5 mg/m3 TWA (related to Oil mist (mineral) 10 mg/m3 STEL (related to Oil mist (mineral) Neutral oil (72623-86-0) ACGIH: 5 mg/m3 TWA (sampled by method that does not collect vapor) (related to Oil mist, mineral) 10 mg/m3 STEL (related to Oil mist, mineral) OSHA: 5 mg/m3 TWA (related to Oil mist, mineral) NIOSH: 5 mg/m3 TWA (related to Oil mist (mineral)) 10 mg/m3 STEL (related to Oil mist (mineral) Residual oils (petroleum), solvent dewaxed (64742-62-7) ACGIH: 5 mg/m3 TWA (sampled by method that does not collect vapor) (related to Oil mist, mineral) 10 mg/m3 STEL (related to Oil mist, mineral) OSHA: 5 mg/m3 TWA (related to Oil mist, mineral) NIOSH: 5 mg/m3 TWA (related to Oil mist (mineral)) 10 mg/m3 STEL (related to Oil mist (mineral) ENGINEERING CONTROLS: Provide general ventilation needed to maintain concentration of vapor or mist below applicable exposure limits. Where adequate general ventilation is unavailable, use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below applicable exposure limits. PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY PROTECTION: Not normally needed. Use NIOSH-certified P- or R- series particulate filter and organic vapor cartridges when concentration of vapor or mist exceeds applicable exposure limits. Protection provided by air purifying respirators is limited. Do not use N-rated respirators. Selection and use of respiratory protective equipment should be in accordance in the USA with OSHA General Industry Standard 29 CFR 1910.134; or in Canada with CSA Standard Z94.4. EYE PROTECTION: Where eye contact is likely, wear chemical goggles; contact lens use is not recommended. SKIN PROTECTION: Where skin contact is likely, wear neoprene, nitrile or equivalent protective gloves; use of natural rubber or equivalent gloves is not recommended. When products are heated and skin contact is likely, wear heat-insulating, gloves, boots, and other protective clothing. To avoid prolonged or repeated contact where spills and splashes are likely, wear appropriate chemical-resistant faceshield, boots, apron, coveralls, long sleeve shirts, or other protective clothing. Page 194 of 1287 Page 194 of 1287 Page 194 of 1287 Page 194 of 1287 ---PAGE BREAK--- AMERICA’S CHOICE MOTOR OIL MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 11/10; MSDS Form No. 82479 - Page 7 of 12 PERSONAL HYGIENE: Use good personal hygiene. Wash thoroughly with soap and water after handling product and before eating, drinking, or using tobacco products. Clean affected clothing, shoes, and protective equipment before reuse. Discard leather articles, such as shoes, saturated with these products. OTHER PROTECTIVE EQUIPMENT: Where spills and splashes are likely, facilities storing or using these products should be equipped with an emergency eyewash and shower, both equipped with clean water, in the immediate work area. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE, APPEARANCE, AND ODOR: Liquid, amber, petroleum odor. ODOR THRESHOLD: Not available MOLECULAR WEIGHT: Not applicable SPECIFIC GRAVITY: 0.88 (water = 1) (approximately) DENSITY: 7.3 LB/US gal (880 g/l) (approximately) VAPOR DENSITY: Not available VAPOR PRESSURE: less than 0.1 mmHg at 68ºF (20ºC) BOILING POINT: 475ºF (246ºC) (minimum) FREEZING/MELTING POINT: Not available [pour point 0ºF (-18ºC) (maximum)]. pH: Not available. EVAPORATION RATE: Not available SOLUBILITY IN WATER: Insoluble FLASH POINT: 383ºF (195ºC) (minimum) Cleveland Open Cup FLAMMABLE LIMITS IN AIR: LOWER: Not available UPPER: Not available AUTOIGNITION TEMPERATURE: Not available SECTION 10: STABILITY AND REACTIVITY STABILITY: Stable under normal temperatures and pressures. CONDITIONS TO AVOID: Avoid sparks or flame when not in use. Page 195 of 1287 Page 195 of 1287 Page 195 of 1287 Page 195 of 1287 ---PAGE BREAK--- AMERICA’S CHOICE MOTOR OIL MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 11/10; MSDS Form No. 82479 - Page 8 of 12 INCOMPATIBILITY: Avoid oxidizing agents, acids and reactive halogens. REACTIVITY: Polymerization is not known to occur under normal temperature and pressures. Not reactive with water. HAZARDOUS DECOMPOSITION PRODUCTS: None under normal temperatures and pressures. See also SECTION 5: HAZARDOUS COMBUSTION PRODUCTS. SECTION 11: TOXICOLOGICAL INFORMATION TOXICITY DATA: Component Analysis - LD50/LC50 Lubricating oils, petroleum, hydrotreated spent (64742-58-1) Oral LD50 Rat >2000 mg/kg Dermal LD50 Rat >2000 mg/kg Dermal LD50 Rabbit >4480 mg/kg Residual oils (petroleum), solvent dewaxed (64742-62-7) Inhalation LC50 Rat: 2.18 mg/L/4H Oral LD50 Rat:>5000 mg/kg Dermal LD50 Rabbit:>2000 mg/kg Lubricating oils (petroleum), C>25, hydrotreated bright stock (72623-83-7) Oral LD50 Rat:>5000 mg/kg Residual oils (petroleum), hydrotreated (64742-54-7) Inhalation LC50 Rat: 2.18 mg/L/4H Oral LD50 Rat: >2000 mg/kg Dermal LD50 Rabbit: >2000 mg/kg Lubricating oils, petroleum, C15-30, hydrotreated neutral oil-based (72623-86-0) Inhalation LC50 Rat: 2.18 mg/L/4H Oral LD50 Rat: >5000 mg/kg Dermal LD50 Rabbit: >2000 mg/kg Residual oils (petroleum), solvent refined (64742-01-4) Inhalation LC50 Rat: 2.18 mg/L/4H Oral LD50 Rat:>5000 mg/kg Dermal LD50 Rabbit:>2000 mg/kg Mineral oil (Not Available) Oral LD50 Mouse 22 g/kg (related to Oil mist, mineral) ACUTE EFFECTS: These products are not likely to present an inhalation hazard at normal temperatures and pressures. However, when aerosolizing, misting, or heating these products, high concentrations of generated vapor or mist may irritate the respiratory tract (nose, throat, and lungs). May cause eye and skin irritation. Not likely to be absorbed through the skin in harmful amounts. May be harmful if swallowed. May cause throat irritation, nausea, vomiting, and diarrhea. Page 196 of 1287 Page 196 of 1287 Page 196 of 1287 Page 196 of 1287 ---PAGE BREAK--- AMERICA’S CHOICE MOTOR OIL MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 11/10; MSDS Form No. 82479 - Page 9 of 12 REPEATED DOSE EFFECTS: Prolonged or repeated inhalation of oil mist may cause oil pneumonia, lung tissue inflammation, and/or fibrous tissue formation. Prolonged or repeated eye contact may cause inflammation of the membrane lining the eyelids and covering the eyeball (conjunctivitis). Prolonged or repeated skin contact may cause drying, cracking, redness, itching, and/or swelling (dermatitis). Experimental evidence suggests that these products do not cause mutagenesis. Based on best current information, there is no known sensitization, reproductive toxicity, or teratogenicity associated with these products. CARCINOGENICITY: Based on best current information, there is no known carcinogenicity as categorized by ACGIH A1 or A2 substances; as categorized by IARC Group 1, Group 2A, or Group 2B agents; or as listed by NTP as either known carcinogens or substances for which there is limited evidence of carcinogenicity in humans or sufficient evidence of carcinogenicity in experimental animals. Also see SECTION 15: CALIFORNIA. TARGET ORGAN EFFECTS: Prolonged or repeated inhalation of oil mist may cause oil pneumonia, lung tissue inflammation, and/or fibrous tissue formation. SECTION 12: ECOLOGICAL INFORMATION Page 197 of 1287 Page 197 of 1287 Page 197 of 1287 Page 197 of 1287 ---PAGE BREAK--- AMERICA’S CHOICE MOTOR OIL MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 11/10; MSDS Form No. 82479 - Page 10 of 12 ECOTOXICITY: No information available for the product. Component Analysis - Ecotoxicity - Aquatic Toxicity Lubricating oils, petroleum, hydrotreated spent (64742-58-1) Test & Species Results Conditions 96 Hr LC50 Brachydanio rerio 79.6 mg/L semi-static 96 Hr LC50 Pimephales promelas 3.2 mg/L semi-static Lubricating oils, petroleum, C20-50, hydrotreated neutral oil-based (72623-87-1) Test & Species Results Conditions 96 Hr LC50 mykiss >5000 mg/L Residual oils (petroleum), solvent dewaxed (64742-62-7) Test & Species Results Conditions 96 Hr LC50 Pimephales promelas >5000 mg/L Lubricating oils, petroleum, C>25. hydrotreated bright stock (72623-83-7) Test & Species Conditions 96 Hr LC50 Lepomis macrochirus >10000 mg/L Lubricating oils, petroleum, C15-30, hydrotreated neutral oil-based (72623-86-0) Test & Species Results Conditions 96 Hr LC50 mykill >5000 mg/L Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3) Test & Species Results Conditions 96 Hr LC50 Pimephales promelas 1-5 mg/L static Residual oils (petroleum), solvent refined (64742-01-4) Test & Species Results Conditions 96 Hr LC50 mykiss >5000 mg/L Petroleum distillates, hydrotreated heavy paraffinic (64742-54-7) Test & Species Results Conditions 96 Hr LC50 Pimephales promelas >5000 PERSISTENCE/ DEGRADABILITY: No information available. BIOACCUMULATION/ ACCUMULATION: No information available. MOBILITY IN ENVIRONMENTAL MEDIA: No information available. OTHER ADVERSE EFFECTS: Not available. Page 198 of 1287 Page 198 of 1287 Page 198 of 1287 Page 198 of 1287 ---PAGE BREAK--- AMERICA’S CHOICE MOTOR OIL MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 11/10; MSDS Form No. 82479 - Page 11 of 12 OCTANOL/WATER PARTITION COEFFICIENT: Not available VOLATILE ORGANIC COMPOUNDS: Negligible. SECTION 13: DISPOSAL CONSIDERATIONS DISPOSAL: Dispose in accordance with federal, state, provincial, and local regulations. Regulations may also apply to empty containers. The responsibility for proper waste disposal lies with the owner of the waste. Contact Safety-Kleen regarding proper recycling or disposal. USEPA WASTE CODE(S): These products, if discarded, are not expected to be a characteristic or listed hazardous waste. If recycled in the USA, they must be managed in accordance with 40 CFR Part 279. Processing, use, or contamination by the user may change the waste code(s) applicable to the disposal of these products. SECTION 14: TRANSPORT INFORMATION DOT: Shipping Name: Not regulated TDG: Shipping Name: Not regulated EMERGENCY RESPONSE GUIDE NUMBER: Not applicable. Reference North American Emergency Response Guidebook SECTION 15: REGULATORY INFORMATION USA REGULATIONS OSHA OSHA Regulated Chemicals No information is available. SARA SECTIONS 302 AND 304: Based on the ingredient listed in SECTION 3, this product does not contain any "extremely hazardous substances" listed pursuant to Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) Section 302 or Section 304 as identified in 40 CFR Part 355, Appendix A and B. SARA SECTIONS 311 AND 312: These products pose the following health hazard(s) as defined in 40 CFR Part 370 and are subject to the requirements of sections 311 and 312 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA): Immediate (Acute) Health Hazard Delayed (Chronic) Health Hazard SARA SECTION 313: These products contain "toxic" chemical(s) subject to the requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40 CFR Part 372. Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-4203) 1.0% de minimis concentration (Chemical Category N982)(related to Zinc compounds) Page 199 of 1287 Page 199 of 1287 Page 199 of 1287 Page 199 of 1287 ---PAGE BREAK--- AMERICA’S CHOICE MOTOR OIL MATERIAL SAFETY DATA SHEET FOR USA AND CANADA Revision 11/10; MSDS Form No. 82479 - Page 12 of 12 CERCLA: Based on the ingredient(s) listed in SECTION 3, this product does not contain any "hazardous substances" listed pursuant to the Comprehensive Environmental Response, Compensation and Liability Act of 1980 (CERCLA) in 40 CFR Part 302, Table 302.4. TSCA: All the components of this product are listed on, or are exempted from the requirement to be listed on, the TSCA Inventory. CALIFORNIA: This product does not contain detectable amounts of any chemical known to the State of California to cause cancer. This product does not contain detectable amounts of any chemical known to the state of California to cause birth defects or other reproductive harm. CANADIAN REGULATIONS These products have been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all information required by the CPR. CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA): The components of this product are listed on, or are exempted from the requirements to be listed on, the Canadian Domestic Substances List (DSL). SECTION 16. OTHER INFORMATION REVISION INFORMATION: This MSDS has been revised in the following sections: Section 3 (Composition), Section 8 (Exposure limits), Section 11 (Toxicology fields), Section 12 (Component Ecotoxicity), Section 13 (Regulatory); Section 16 (Revision). LABEL/OTHER INFORMATION: Not available User assumes all risks incident to the use of this (these) product(s). To the best of our knowledge, the information contained herein is accurate. However, Safety-Kleen assumes no liability whatsoever for the accuracy or completeness of the information contained herein. No representations or warranties, either express or implied, or merchantability, fitness for a particular purpose or of any other nature are made hereunder with respect to information or the product to which information refers. The data contained on this sheet apply to the product(s) as supplied to the user. Page 200 of 1287 Page 200 of 1287 Page 200 of 1287 Page 200 of 1287 ---PAGE BREAK--- Page 201 of 1287 Page 201 of 1287 Page 201 of 1287 Page 201 of 1287 ---PAGE BREAK--- Page 202 of 1287 Page 202 of 1287 Page 202 of 1287 Page 202 of 1287 ---PAGE BREAK--- 06/05/2015 EN (English) Page 1 ATC - Air Tool Conditioner (Aerosol) Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. Date of issue: 06/05/2015 Revision date: 06/05/2015 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking Product form : Mixture Product name : ATC - Air Tool Conditioner (Aerosol) Product code : 8-ATC-S, 16-ATC, ATC-TS Use of the substance/mixture : Cleaner / Coating / Lubricant The Blaster Corporation 8500 Sweet Valley Drive 44125 Valley View, Ohio - USA T (216) 901-5800 - F (216) 901-5801 www.blasterproducts.com Emergency number : Chemtrec (800) 424-9300 SECTION 2: Hazards identification GHS-US classification Flammable Aerosol 2 Gases Under Pressure (Dissolved Gas) Skin Irritation 2 Serious eye damage 1 Skin Sensitization 1 Specific target organ toxicity (single exposure) 3 Aspiration hazard 1 GHS-US labelling This product is a consumer product and is labeled in accordance with the US Consumer Product Safety Commission regulations which take precedence over OSHA Hazard Communication labeling. The actual container label will not include the label elements below. The labeling below applies to industrial/professional products. Hazard pictograms (GHS-US) : Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin irritation. Causes serious eye damage. May cause an allergic skin reaction. May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Precautionary statements (GHS-US) : Keep away from heat/sparks/open flames/hot surfaces. -No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing dust/fume/gas/mist/vapors/spray. Wash hands thoroughly after handling. Use only outdoors or in a well-ventilated area. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves/eye protection/face protection If on skin: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation or rash occurs: Get medical advice/attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/ doctor. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. Protect from sunlight. Do not expose to temperatures exceeding 50 ºC/122 ºF. Store in a well-ventilated place. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. No additional information available 15 % of the mixture consists of ingredient(s) of unknown acute toxicity. 2.4. Unknown acute toxicity (GHS-US) 2.3. Other hazards 2.2. Label elements 2.1. Classification of the substance or mixture 1.4. Emergency telephone number 1.3. Details of the supplier of the safety data sheet 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.1. Product identifier Page 203 of 1287 Page 203 of 1287 Page 203 of 1287 Page 203 of 1287 ---PAGE BREAK--- ATC - Air Tool Conditioner (Aerosol) Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/05/2015 EN (English) 2/7 SECTION 3: Composition/information on ingredients Not applicable Name Product identifier % GHS-US classification Distillates, petroleum, hydrotreated heavy naphthenic (CAS No) 64742-52-5 50 - 60 Asp. Tox. 1 Petroleum distillates, hydrotreated light (CAS No) 64742-47-8 20 - 30 Flam. Liq. 3 Asp. Tox. 1 Isopropyl alcohol (CAS No) 67-63-0 10 - 20 Flam. Liq. 2 Eye Irrit. 2A STOT SE 3 Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS No) 68649-42-3 1 - 10 Skin Irrit. 2 Eye Dam. 1 Alcohols, C6-10, ethoxylated propoxylated (CAS No) 68987-81-5 1 - 3 Skin Irrit. 2 Eye Dam. 1 Carbon dioxide (CAS No) 124-38-9 1 - 5 Compressed gas (CAS No) 90-30-2 <0.5 Acute Tox. 4 (Oral) Skin Sens. 1 STOT RE 2 The specific exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph of §1910.1200. SECTION 4: First aid measures First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER/doctor/physician if you feel unwell. First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists. First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. Get medical attention immediately. First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get immediate medical advice/attention. after inhalation : Vapours may cause drowsiness and dizziness. May cause respiratory tract irritation. after skin contact : Causes skin irritation. may include redness, edema, drying, defatting and cracking of the skin. after eye contact : Causes serious eye damage. may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. May cause burns. after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Firefighting measures Suitable extinguishing media : Carbon dioxide, dry chemical, halons, foam. Unsuitable extinguishing media : Do not use a direct stream of water. Product will float and can spread the fire. Fire hazard : Flammable aerosol. Products of combustion may include, and are not limited to: oxides of carbon and oxides of nitrogen. Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. Firefighting instructions : Cool closed containers exposed to fire with water. Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). SECTION 6: Accidental release measures 6.1.1. For non-emergency personnel Protective equipment : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. 6.1. Personal precautions, protective equipment and emergency procedures 5.3. Advice for firefighters 5.2. Special hazards arising from the substance or mixture 5.1. Extinguishing media 4.3. Indication of any immediate medical attention and special treatment needed 4.2. Most important and effects, both acute and delayed 4.1. Description of first aid measures 3.2. Mixture 3.1. Substance Page 204 of 1287 Page 204 of 1287 Page 204 of 1287 Page 204 of 1287 ---PAGE BREAK--- ATC - Air Tool Conditioner (Aerosol) Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/05/2015 EN (English) 3/7 6.1.2. For emergency responders No additional information available For containment : Eliminate sources of ignition. Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Dike to collect large liquid spills. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Vacuum or sweep material and place in a disposal container. Vapours may be heavier than air and may travel along the ground to a distant ignition source and flash back. Provide ventilation. See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal. SECTION 7: Handling and storage Precautions for safe handling : Keep away from sources of ignition. - No smoking. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not swallow. When using do not eat, drink or smoke. Do not spray on an open flame or other ignition source. Use only outdoors or in a well- ventilated area. Pressurized container: Do not pierce or burn, even after use. Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. Contaminated work clothing should not be allowed out of the workplace. Technical measures : Proper grounding procedures to avoid static electricity should be followed. Storage conditions : Keep locked up and out of reach of children. Do not expose to temperatures exceeding 50 122 Store in a cool, dry, well ventilated place away from incompatible materials. Store away from direct sunlight or other heat sources. Not available. SECTION 8: Exposure controls/personal protection Distillates, petroleum, hydrotreated heavy naphthenic (64742-52-5) USA ACGIH ACGIH TWA (mg/m³) 5 mg/m³ (mist) USA OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m³ (mist) Petroleum distillates, hydrotreated light (64742-47-8) USA ACGIH ACGIH TWA (mg/m³) 200 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 100 ppm Isopropyl alcohol (67-63-0) USA ACGIH ACGIH TWA (ppm) 200 ppm USA ACGIH ACGIH STEL (ppm) 400 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 980 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 400 ppm Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3) USA ACGIH ACGIH TWA Not applicable. USA OSHA OSHA PEL (TWA) Not applicable. Alcohols, C6-10, ethoxylated propoxylated (68987-81-5) USA ACGIH ACGIH TWA Not applicable. USA OSHA OSHA PEL (TWA) Not applicable. Carbon dioxide (124-38-9) USA ACGIH ACGIH TWA (ppm) 5000 ppm USA ACGIH ACGIH STEL (ppm) 30000 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 9000 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 5000 ppm (90-30-2) USA ACGIH ACGIH TWA Not applicable. 8.1. Control parameters 7.3. Specific end use(s) 7.2. Conditions for safe storage, including any incompatibilities 7.1. Precautions for safe handling 6.3. Reference to other sections 6.2. Methods and material for containment and cleaning up Page 205 of 1287 Page 205 of 1287 Page 205 of 1287 Page 205 of 1287 ---PAGE BREAK--- ATC - Air Tool Conditioner (Aerosol) Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/05/2015 EN (English) 4/7 (90-30-2) USA OSHA OSHA PEL (TWA) Not applicable. Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Use explosion-proof ventilation equipment. Ensure that eyewash stations and safety showers are close to the workstation location. Hand protection : Wear chemically resistant protective gloves. Eye protection : Wear approved eye protection (properly fitted dust- or splash-proof chemical safety goggles) and face protection (face shield). Skin and body protection : Wear suitable protective clothing. Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Maintain levels below Community environmental protection thresholds. Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. SECTION 9: Physical and chemical properties Physical state : Gas/Pressurized Liquid. Colour : Light red. Odour : No data available. Odour threshold : No data available. pH : No data available. Relative evaporation rate (butylacetate=1) : No data available. Melting point : No data available. Freezing point : No data available. Boiling point : No data available. Flash point : No data available. Self ignition temperature : No data available. Decomposition temperature : No data available. Flammability (solid, gas) : Flammable aerosol. Vapour pressure : No data available. Relative vapour density at 20 °C : No data available. Relative density : No data available. Solubility : Negligible. Log Pow : No data available. Log Kow : No data available. Viscosity, kinematic : No data available. Viscosity, dynamic : No data available. Explosive properties : No data available. Oxidising properties : No data available. Explosive limits : No data available. Flame Projection = 0 cm; Heat of Combustion = 44.6 kJ/g. SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reaction known under conditions of normal use. 10.2. Chemical stability Stable under normal storage conditions. Flammable aerosol. Contents under pressure. Container may explode if heated. Do not puncture. Do not burn. 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 10.4. Conditions to avoid Heat. Incompatible materials. Sources of ignition. 10.5. Incompatible materials Strong oxidizing agents. 9.2. Other information 9.1. Information on basic physical and chemical properties 8.2. Exposure controls Page 206 of 1287 Page 206 of 1287 Page 206 of 1287 Page 206 of 1287 ---PAGE BREAK--- ATC - Air Tool Conditioner (Aerosol) Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/05/2015 EN (English) 5/7 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon, oxides of nitrogen. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified ATC - Air Tool Conditioner (Aerosol) LD50 oral rat > 2000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/l) > 5 mg/l/4h Distillates, petroleum, hydrotreated heavy naphthenic (64742-52-5) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 5000 mg/kg LC50 inhalation rat (mg/l) > 5.0 mg/l/4h Petroleum distillates, hydrotreated light (64742-47-8) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/l) > 5.2 mg/l/4h Isopropyl alcohol (67-63-0) LD50 oral rat 4396 mg/kg LD50 dermal rat 12800 mg/kg LD50 dermal rabbit 12870 mg/kg LC50 inhalation rat (mg/l) 72.6 mg/l/4h (90-30-2) LD50 oral rat 1625 mg/kg LD50 dermal rabbit > 5000 mg/kg Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Causes serious eye damage. Respiratory or skin sensitisation : May cause an allergic skin reaction. Germ cell mutagenicity : Based on available data, the classification criteria are not met. Carcinogenicity : Based on available data, the classification criteria are not met. Isopropyl alcohol (67-63-0) IARC group 3 Reproductive toxicity : Based on available data, the classification criteria are not met. Specific target organ toxicity (single exposure) : May cause drowsiness or dizziness. Specific target organ toxicity (repeated exposure) : Based on available data, the classification criteria are not met. Aspiration hazard : May be fatal if swallowed and enters airways. after inhalation : Vapours may cause drowsiness and dizziness. May cause respiratory tract irritation. after skin contact : Causes skin irritation. may include redness, edema, drying, defatting and cracking of the skin. after eye contact : Causes serious eye damage. may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. May cause burns. after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. SECTION 12: Ecological information 12.1. Toxicity Ecology – general : May cause long-term adverse effects in the aquatic environment. 12.2. Persistence and degradability ATC - Air Tool Conditioner (Aerosol) Persistence and degradability Not established. 12.3. Bioaccumulative potential ATC - Air Tool Conditioner (Aerosol) Bioaccumulative potential Not established. Page 207 of 1287 Page 207 of 1287 Page 207 of 1287 Page 207 of 1287 ---PAGE BREAK--- ATC - Air Tool Conditioner (Aerosol) Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/05/2015 EN (English) 6/7 12.4. Mobility in soil No additional information available 12.5. Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible. Additional information : Flammable vapours may accumulate in the container. Do not incinerate empty containers. Do not cut, weld, drill or grind. SECTION 14: Transport information In accordance with DOT 14.1. UN number UN-No.(DOT) : UN1950 14.2. UN proper shipping name DOT Proper Shipping Name : AEROSOLS, flammable, limited quantities Hazard class (DOT) : 2.1 Packing Group (DOT) : Not applicable. Hazard labels (DOT) : 14.3. Additional information Other information : No supplementary information available. Special transport precautions : Do not handle until all safety precautions have been read and understood. SECTION 15: Regulatory information 15.1. US Federal regulations Isopropyl alcohol (67-63-0) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on SARA Section 313 (Specific toxic chemical listings) EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. SARA Section 313 - Emission Reporting 1.0 % (only if manufactured by the strong acid process, no supplier notification) 15.2. US State regulations ATC - Air Tool Conditioner (Aerosol) State or local regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. (90-30-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory Carbon dioxide (124-38-9) Listed on the United States TSCA (Toxic Substances Control Act) inventory Alcohols, C6-10, ethoxylated propoxylated (68987-81-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3) Listed on the United States TSCA (Toxic Substances Control Act) inventory Petroleum distillates, hydrotreated light (64742-47-8) Listed on the United States TSCA (Toxic Substances Control Act) inventory Distillates, petroleum, hydrotreated heavy naphthenic (64742-52-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory Page 208 of 1287 Page 208 of 1287 Page 208 of 1287 Page 208 of 1287 ---PAGE BREAK--- ATC - Air Tool Conditioner (Aerosol) Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/05/2015 EN (English) 7/7 SOURCE AGENCY CARCINOGEN CLASSIFICATIONS: IARC International Agency for Research on Cancer. 1 - Carcinogenic to humans; 2A - Probably carcinogenic to humans; 2B - Possibly carcinogenic to humans; 3 - Not classifiable; 4 - Probably not carcinogenic to humans. NTP National Toxicology Program. 1 - Evidence of Carcinogenicity; 2 - Known Human Carcinogens; 3 - Reasonably anticipated to be Human Carcinogen; 4 - Substances delisted from report on Carcinogens; 5 - Twelfth Report - Items under consideration. SECTION 16: Other information Indication of changes : None. Date of issue : 06/05/2015 Other information : None. This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product Page 209 of 1287 Page 209 of 1287 Page 209 of 1287 Page 209 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET Issue Date 30-Jan-2015 Revision Date 30-Jan-2015 Version 1 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Product Name Balance EC Economy Neutral Floor Cleaner Other means of identification Product Code N-158 Synonyms None Details of the supplier of the safety data sheet Emergency telephone number Emergency Telephone Chemtrec 1-[PHONE REDACTED] 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Not classified Acute toxicity - Dermal Not classified Skin corrosion/irritation Category 3 Label elements Emergency Overview Precautionary Statements - Response Specific Treatment (See Section 4 on the SDS) Call a POISON CENTER or doctor/physician if you feel unwell If skin irritation occurs: Get medical advice/attention Hazards not otherwise classified (HNOC) Other Information Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity Company Name Page 1 / 7 Nyco Products Company 5332 Dansher Road IL 60525 (708) 579-8100 nycoproducts.com Warning Hazard statements Causes mild skin irritation Appearance Clear Yellow Physical state Liquid Odor Citrus Lemon-Lime Page 210 of 1287 Page 210 of 1287 Page 210 of 1287 Page 210 of 1287 ---PAGE BREAK--- N-158 Balance EC Economy Neutral Floor Cleaner Revision Date 30-Jan-2015 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. Weight-% Trade Secret PROPRIETARY Proprietary 1-5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES First aid measures Skin Contact Wash skin with soap and water. Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Inhalation Remove to fresh air. Ingestion Clean mouth with water and drink afterwards plenty of water. Most important and effects, both acute and delayed Any additional important and effects are described in Section 11: Toxicology Information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media Caution: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical No Information available. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Environmental precautions Environmental precautions See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Page 211 of 1287 Page 211 of 1287 Page 211 of 1287 Page 211 of 1287 ---PAGE BREAK--- N-158 Balance EC Economy Neutral Floor Cleaner Revision Date 30-Jan-2015 Methods for cleaning up Pick up and transfer to properly labeled containers. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers closed in a dry, cool and well-ventilated place. Incompatible materials None known based on information supplied. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Appropriate engineering controls Engineering Controls Showers, Eyewash stations & Ventilation systems. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses if handling large volume. Skin and body protection Wear protective gloves and protective clothing if needed. Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. General Hygiene Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Clear Yellow Color Yellow Odor Citrus Lemon-Lime Odor threshold No Information available Property Values Remarks • Method pH 6.25 - 8.25 Specific Gravity 1.0004 Viscosity < 25 cP @ 25°C Melting point/freezing point No Information available Flash point above 200F Boiling point / boiling range 212 °F Evaporation rate No Information available Flammability (solid, gas) Flammability Limits in Air Upper flammability limit: Not Applicable Lower flammability limit: Not Applicable Vapor pressure No Information available Vapor density No Information available Water solubility Complete Page 212 of 1287 Page 212 of 1287 Page 212 of 1287 Page 212 of 1287 ---PAGE BREAK--- N-158 Balance EC Economy Neutral Floor Cleaner Revision Date 30-Jan-2015 Other Information Density Lbs/Gal 8.33 VOC Content Not Applicable 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Extremes of temperature and direct sunlight. Incompatible materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Harmful by inhalation, ingestion, in contact with eyes and skin. Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system. Eye contact Contact with eyes may cause irritation or burns. Skin Contact Prolonged or repeated contact may dry skin and cause irritation. Ingestion May cause gastro intestinal irritation. Information on toxicological effects No Information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No Information available. Germ cell mutagenicity No Information available. Carcinogenicity No Information available. Reproductive toxicity No Information available. STOT - single exposure No Information available. STOT - repeated exposure No Information available. Aspiration hazard No Information available. Numerical measures of toxicity - Product Information Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document . 12. ECOLOGICAL INFORMATION Partition coefficient No Information available Autoignition temperature No Information available Decomposition temperature No Information available No data available Page 213 of 1287 Page 213 of 1287 Page 213 of 1287 Page 213 of 1287 ---PAGE BREAK--- N-158 Balance EC Economy Neutral Floor Cleaner Revision Date 30-Jan-2015 Ecotoxicity 0.0112% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea Surfactant Blend P194 Yes 32.15: 96 h Rainbow Trout mg/L LC50 Yes Sodium Alpha Olefin Sulfonate 68439-57-6 Yes 1.0 - 10.0: 96 h Brachydanio rerio mg/L LC50 static 12.2: 96 h Brachydanio rerio mg/L LC50 semi-static Yes Sodium Chloride 7647-14-5 Yes 5560 - 6080: 96 h Lepomis macrochirus mg/L LC50 flow-through 12946: 96 h Lepomis macrochirus mg/L LC50 static 6020 - 7070: 96 h Pimephales promelas mg/L LC50 static 7050: 96 h Pimephales promelas mg/L LC50 semi-static 6420 - 6700: 96 h Pimephales promelas mg/L LC50 static 4747 - 7824: 96 h mykiss mg/L LC50 flow-through 1000: 48 h Daphnia magna mg/L EC50 340.7 - 469.2: 48 h Daphnia magna mg/L EC50 Static Sodium Sulfate 7757-82-6 Yes 13500 - 14500: 96 h Pimephales promelas mg/L LC50 6800: 96 h Pimephales promelas mg/L LC50 static 3040 - 4380: 96 h Lepomis macrochirus mg/L LC50 static 13500: 96 h Lepomis macrochirus mg/L LC50 2564: 48 h Daphnia magna mg/L EC50 630: 96 h Daphnia magna mg/L EC50 Methyl Chloro Isothiazolinone 26172-55-4 0.11 - 0.16: 72 h Pseudokirchneriella subcapitata mg/L EC50 static 0.03 - 0.13: 96 h Pseudokirchneriella subcapitata mg/L EC50 static 0.31: 120 h Anabaena flos-aquae mg/L EC50 1.6: 96 h mykiss mg/L LC50 semi-static 4.71: 48 h Daphnia magna mg/L EC50 0.12 - 0.3: 48 h Daphnia magna mg/L EC50 Flow through 0.71 - 0.99: 48 h Daphnia magna mg/L EC50 Static Magnesium Chloride 7786-30-3 2200: 72 h Desmodesmus subspicatus mg/L EC50 1970 - 3880: 96 h Pimephales promelas mg/L LC50 static 4210: 96 h Gambusia affinis mg/L LC50 static 140: 48 h Daphnia magna mg/L EC50 Static 1400: 24 h Daphnia magna mg/L EC50 Persistence and degradability No Information available. Bioaccumulation No Information available. Other adverse effects No Information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. This product contains one or more substances that are listed with the State of California as a hazardous waste. 14. TRANSPORT INFORMATION The basic description below is specific to the container size. This information is provided for at a glance DOT information. Please refer to the container and/or shipping papers for the appropriate shipping description before tendering this material for shipment. For additional information, please contact the distributor listed in section 1 of this SDS. Page 214 of 1287 Page 214 of 1287 Page 214 of 1287 Page 214 of 1287 ---PAGE BREAK--- N-158 Balance EC Economy Neutral Floor Cleaner Revision Date 30-Jan-2015 DOT Not regulated TDG Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard No Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Sodium Sulfate 7757-82-6 Yes X X U.S. EPA Label Information EPA Pesticide Registration Number Not Applicable 16. OTHER INFORMATION Issue Date 30-Jan-2015 Revision Date 30-Jan-2015 Revision Note No Information available NFPA Health hazards 1 Flammability 0 Instability 0 Physical and Chemical Properties Yes HMIS Health hazards 1 Flammability 0 Physical hazards 0 Personal protection B Page 215 of 1287 Page 215 of 1287 Page 215 of 1287 Page 215 of 1287 ---PAGE BREAK--- N-158 Balance EC Economy Neutral Floor Cleaner Revision Date 30-Jan-2015 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 216 of 1287 Page 216 of 1287 Page 216 of 1287 Page 216 of 1287 ---PAGE BREAK--- Page 1 of 9 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 05/01/2015 Reviewed on 05/01/2015 40.1.5 1 Identification · Product identifier · Trade name: Bar's Leaks® Liquid Radiator Stop Leak · Article number: 1194, 1196 · Recommended use and restriction on use · Recommended use: Sealant · Restrictions on use: No further relevant information available. · Details of the supplier of the Safety Data Sheet · Manufacturer/Supplier: · Emergency telephone number: ChemTel Inc. (800)255-3924, +1 (813)248-0585 2 Hazard(s) identification · Classification of the substance or mixture The product is not classified as hazardous according to the Globally Harmonized System (GHS). · Additional information: There are no other hazards not otherwise classified that have been identified. 0 percent of the mixture consists of ingredient(s) of unknown toxicity. · Label elements · GHS label elements The product is not classified as hazardous according to OSHA GHS regulations within the United States. · Hazard pictograms Not Regulated · Signal word Not Regulated · Hazard-determining components of labeling: None. · Hazard statements Not Regulated · Precautionary statements Not Regulated · Hazard description: · WHMIS-symbols: Not hazardous under WHMIS. · Classification system: · NFPA ratings (scale 0 - 4) 0 0 0 Health = 0 Fire = 0 Reactivity = 0 · HMIS-ratings (scale 0 - 4) HEALTH FIRE REACTIVITY 0 0 0 Health = 0 Fire = 0 Reactivity = 0 (Contd. on page 2) Bar's Products P.O. Box 187 Holly, MI 48442 USA Phone: (810) 603-1321 Page 217 of 1287 Page 217 of 1287 Page 217 of 1287 Page 217 of 1287 ---PAGE BREAK--- Page 2 of 9 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 05/01/2015 Reviewed on 05/01/2015 Trade name: Bar's Leaks® Liquid Radiator Stop Leak (Contd. of page 1) 40.1.5 · Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. 3 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Contains no hazardous substances. · Dangerous components: None in reportable quantities. · Additional information: For the listed ingredients, the identity and exact percentages are being withheld as a trade secret. 4 First-aid measures · Description of first aid measures · General information: No special measures required. · After inhalation: Supply fresh air; consult doctor in case of complaints. · After skin contact: Clean with water and soap. If skin irritation is experienced, consult a doctor. · After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If persist, consult a doctor. · After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; immediately call for medical help. · Information for doctor: · Most important and effects, both acute and delayed Slight irritant effect on eyes. Gastric or intestinal disorders Nausea in case of ingestion. · Danger No further relevant information available. · Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: Use fire fighting measures that suit the environment. · For safety reasons unsuitable extinguishing agents: None. · Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. · Advice for firefighters · Protective equipment: Wear self-contained respiratory protective device. (Contd. on page 3) Page 218 of 1287 Page 218 of 1287 Page 218 of 1287 Page 218 of 1287 ---PAGE BREAK--- Page 3 of 9 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 05/01/2015 Reviewed on 05/01/2015 Trade name: Bar's Leaks® Liquid Radiator Stop Leak (Contd. of page 2) 40.1.5 Wear fully protective suit. · Additional information No further relevant information available. 6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. For large spills, wear protective clothing. For large spills, use respiratory protective device against the effects of fumes/dust/aerosol. · Environmental precautions: Do not allow to enter sewers/ surface or ground water. · Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Send for recovery or disposal in suitable receptacles. Dispose contaminated material as waste according to item 13. · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage · Handling: · Precautions for safe handling Prevent formation of aerosols. Avoid splashes or spray in enclosed areas. Use only in well ventilated areas. · Information about protection against explosions and fires: No special measures required. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Provide ventilation for receptacles. Avoid storage near extreme heat, ignition sources or open flame. · Information about storage in one common storage facility: Store away from foodstuffs. Store away from oxidizing agents. · Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. · Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection · Additional information about design of technical systems: No further data; see item 7. · Control parameters · Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. (Contd. on page 4) Page 219 of 1287 Page 219 of 1287 Page 219 of 1287 Page 219 of 1287 ---PAGE BREAK--- Page 4 of 9 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 05/01/2015 Reviewed on 05/01/2015 Trade name: Bar's Leaks® Liquid Radiator Stop Leak (Contd. of page 3) 40.1.5 · Additional information: The lists that were valid during the creation were used as basis. · Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Do not inhale gases / fumes / aerosols. Avoid contact with the eyes and skin. Keep away from foodstuffs, beverages and feed. · Engineering controls: No further relevant information available. · Breathing equipment: Not required under normal conditions of use. Use suitable respiratory protective device when aerosol or mist is formed. For spills, respiratory protection may be advisable. · Protection of hands: Wear protective gloves to handle contents of damaged or leaking units. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Not required under normal conditions of use. Protection may be required for spills. · Limitation and supervision of exposure into the environment No special requirements. · Risk management measures See Section 7 for additional information. 9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Form: Viscous Color: Brown · Odor: Odorless · Odor threshold: Not determined. (Contd. on page 5) Page 220 of 1287 Page 220 of 1287 Page 220 of 1287 Page 220 of 1287 ---PAGE BREAK--- Page 5 of 9 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 05/01/2015 Reviewed on 05/01/2015 Trade name: Bar's Leaks® Liquid Radiator Stop Leak (Contd. of page 4) 40.1.5 · pH-value at 20 °C (68 8.5 - 9.5 · Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: 100 °C (212 · Flash point: Not applicable. · Flammability (solid, gaseous): Product is not flammable. · Auto-ignition temperature: Not determined. · Decomposition temperature: Not determined. · Auto igniting: Product is not self-igniting. · Danger of explosion: Product does not present an explosion hazard. · Explosion limits: Lower: Not determined. Upper: Not determined. · Vapor pressure: Not determined. · Density at 20 °C (68 1 g/cm³ (8.345 lbs/gal) · Relative density Not determined. · Vapour density Not determined. · Evaporation rate Not determined. · Solubility in / Miscibility with Water: Fully miscible. · Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic at 20 °C (68 900 mPas Kinematic: Not determined. · Other information No further relevant information available. 10 Stability and reactivity · Reactivity · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications. · Possibility of hazardous reactions Reacts with strong acids and oxidizing agents. Toxic fumes may be released if heated above the decomposition point. · Conditions to avoid Store away from oxidizing agents. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: Carbon monoxide and carbon dioxide (Contd. on page 6) Page 221 of 1287 Page 221 of 1287 Page 221 of 1287 Page 221 of 1287 ---PAGE BREAK--- Page 6 of 9 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 05/01/2015 Reviewed on 05/01/2015 Trade name: Bar's Leaks® Liquid Radiator Stop Leak (Contd. of page 5) 40.1.5 11 Toxicological information · Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: None. · Primary irritant effect: · on the skin: Slight irritant effect on skin and mucous membranes. · on the eye: Slight irritant effect on eyes. · Sensitization: No sensitizing effects known. · Subacute to chronic toxicity: No further relevant information available. · Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. · Carcinogenic categories · NTP (National Toxicology Program) None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. · Probable Routes of Exposure Inhalation. Eye contact. Skin contact. · Repeated Dose Toxicity: No further relevant information available. 12 Ecological information · Toxicity · Aquatic toxicity: No further relevant information available. · Persistence and degradability No further relevant information available. · Behavior in environmental systems: · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Generally not hazardous for water · Other adverse effects No further relevant information available. 13 Disposal considerations · Waste treatment methods · Recommendation: Smaller quantities can be disposed of with household waste. (Contd. on page 7) Page 222 of 1287 Page 222 of 1287 Page 222 of 1287 Page 222 of 1287 ---PAGE BREAK--- Page 7 of 9 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 05/01/2015 Reviewed on 05/01/2015 Trade name: Bar's Leaks® Liquid Radiator Stop Leak (Contd. of page 6) 40.1.5 Can be burned with household garbage after consulting with the waste disposal facility operator and the pertinent authorities and adhering to the necessary technical regulations. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleansing agent: Water, if necessary with cleansing agents. 14 Transport information · UN-Number · DOT, ADR, ADN, IMDG, IATA Not Regulated · UN proper shipping name · DOT, ADR, ADN, IMDG, IATA Not Regulated · Transport hazard class(es) · DOT, ADR, ADN, IMDG, IATA · Class Not Regulated · Packing group · DOT, ADR, IMDG, IATA Not Regulated · Environmental hazards: · Marine pollutant: No · Special precautions for user Not applicable. · Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · UN "Model Regulation": - 15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture · United States (USA) · SARA · Section 355 (extremely hazardous substances): None of the ingredients is listed. · Section 313 (Specific toxic chemical listings): None of the ingredients are listed. · TSCA (Toxic Substances Control Act): All ingredients are listed. · Proposition 65 (California) · Chemicals known to cause cancer: None of the ingredients are listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. (Contd. on page 8) Page 223 of 1287 Page 223 of 1287 Page 223 of 1287 Page 223 of 1287 ---PAGE BREAK--- Page 8 of 9 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 05/01/2015 Reviewed on 05/01/2015 Trade name: Bar's Leaks® Liquid Radiator Stop Leak (Contd. of page 7) 40.1.5 · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Carcinogenic categories · EPA (Environmental Protection Agency) None of the ingredients is listed. · IARC (International Agency for Research on Cancer) None of the ingredients is listed. · TLV (Threshold Limit Value established by ACGIH) None of the ingredients is listed. · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. · State Right to Know Listings None of the ingredients is listed. · Canadian substance listings: · Canadian Domestic Substances List (DSL) All ingredients are listed. · Canadian Ingredient Disclosure list (limit 0.1%) None of the ingredients is listed. · Canadian Ingredient Disclosure list (limit None of the ingredients is listed. · Other regulations, limitations and prohibitive regulations This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Date of preparation / last revision 05/01/2015 / - · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) WHMIS: Workplace Hazardous Materials Information System (Canada) LC50: Lethal concentration, 50 percent (Contd. on page 9) Page 224 of 1287 Page 224 of 1287 Page 224 of 1287 Page 224 of 1287 ---PAGE BREAK--- Page 9 of 9 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 05/01/2015 Reviewed on 05/01/2015 Trade name: Bar's Leaks® Liquid Radiator Stop Leak (Contd. of page 8) 40.1.5 LD50: Lethal dose, 50 percent · Sources SDS Prepared by: ChemTel Inc. 1305 North Florida Avenue Tampa, Florida USA 33602-2902 Toll Free North America 1-[PHONE REDACTED] Intl. +01 [PHONE REDACTED] Website: www.chemtelinc.com Page 225 of 1287 Page 225 of 1287 Page 225 of 1287 Page 225 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Total Solutions P.O. Box 240014 Milwaukee, WI 53224 GENERAL INFORMATION NUMBER: (414) 354-6417 REVISION DATE: March 12, 2004 CHEMTREC: (800) 424-9300 DATE OF ISSUE: March 23, 2004 I - Product Identification Baseboard Stripper & Cleaner PRODUCT CODE: 8177 CHEMICAL FORMULATION: Pressurized water based alkaline cleaner. NFPA HAZARD IDENTIFICATION SYSTEM: HEALTH: 2 FLAMMABILITY: 4 REACTIVITY: 0 HAZARD RATING: 4 - Extreme; 3 - High; 2 - Moderate; 1 - Slight; 0 - Insignificant II - Hazardous Ingredients Values reported as TWA unless noted. EPA 40 CFR: SUBSTANCE APPROX % OSHA PEL ACGIH TLV 302 355 372 CAS # 2 Butoxyethanol 23.0 25 ppm (skin) 25 ppm (skin) N N Y 111-76-2 Tetrasodium EDTA 0.5-1.0 N/E N/E N N N 64-02-8 Organic Phosphate Ester 1.00-3.00 N/E 1 mg/m3 N N N 51811-79-1 Liquified Petroleum Gas 5.00-10.0 1000 ppm 1000 ppm N N N 68476-85-7 Key: PEL: Permissible Exposure Limit TLV: Threshold Limit Value C: Ceiling level STEL: Short Term Exposure Limit N/A: Not Applicable N/D: Not Determined N/E: Not Established Y: Yes N: No 302: CERCLA List of Hazardous Substances and Reportable Quantities (40 CFR 302.4). 355: SARA TITLE III / List of Extremely Hazardous Substances for Emergency Planning and Notification (40 CFR 355). 372: SARA TITLE III / List of Toxic Chemicals subject to Release Reporting (Community Right to Know) (40 CFR 372). III - Physical Data BOILING POINT N/D SPECIFIC GRAVITY (WATER = < 1.00 VAPOR PRESSURE (mm Hg): 115 ± 5 @ 130F VOC CONTENT by weight): N/D VAPOR DENSITY (AIR = > 1.00 EVAPORATION RATE (WATER = N/D SOLUBILITY IN WATER: Slight pH: N/D APPEARANCE AND ODOR: Semi-stable foaming spray; pine fragrance. IV - Fire and Explosion Hazard Data FLASH POINT (TEST METHOD): FLAME EXTENSION: N/D FLAMMABLE LIMITS IN AIR (VOLUME UPPER: 9.2 LOWER: 1.8 NFPA 30B Rating: 1 EXTINGUISHING MEDIA: Foam, carbon dioxide, dry chemical. SPECIAL FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water fog. Firefighters should be equipped with full protective gear including self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARD: Exposure to temperature above 120°F may cause bursting. Page 226 of 1287 Page 226 of 1287 Page 226 of 1287 Page 226 of 1287 ---PAGE BREAK--- PRODUCT NAME: Baseboard Stripper & Cleaner PRODUCT CODE: 8177 V - Reactivity Data STABILITY: Stable INCOMPATIBILITY: Strong oxidizers and reactive metals. CONDITIONS TO AVOID: Excess heat and open flame. Dropping of container may cause bursting. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may produce oxides of carbon and toxic chemicals may be formed in small amounts. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: None VI - Health Hazard Data ROUTES OF ENTRY INHALATION: X EYE CONTACT: X SKIN CONTACT: X INGESTION: X INGREDIENTS THAT ARE CONSIDERED BY OSHA, NTP, IARC TO BE SUSPECTED HUMAN CARCINOGENS: None EFFECTS OF OVEREXPOSURE IF IN EYES: Burning and irritation. IF ON SKIN: Irritation, chapping and dermatitis, with prolonged or repeated exposure. Possible skin absorption. IF SWALLOWED: Nausea, cramps, diarrhea. If large quantities are ingested red blood cell hemolysis may occur. IF INHALED: Irritation to upper respiratory tract, headache, dizziness and nausea. EMERGENCY AND FIRST AID PROCEDURES IF IN EYES: Flush eyes and under eyelids with plenty of cool water for at least 15 minutes. If irritation persists, obtain medical attention. IF ON SKIN: Remove contaminated clothing and flush skin with water, followed by soap and water. Launder clothing separately before reuse. If irritation persists, obtain medical attention. IF SWALLOWED: Contact physician or poison control center immediately. Rinse mouth with water. Never give anything to an unconscious person. IF INHALED: Remove person to fresh air. If breathing has stopped, administer artificial respiration. Give oxygen if breathing is difficult. VII - Spill or Leak Protection STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Ventilate area and remove all sources of ignition. Contain spill. Soak up spilled material with inert absorbent material and place in a properly marked closed container for proper disposal. WASTE DISPOSAL METHOD: Consult local environmental authorities. Dispose of cans in non-incinerated trash only. VIII - Special Protection Information RESPIRATORY PROTECTION: Use with adequate ventilation. If recommended Exposure Limits are exceeded wear a NIOSH approved respirator, following manufacturer’s recommendations. VENTILATION LOCAL: Recommended MECHANICAL: Not required PROTECTIVE GLOVES: Chemical resistant. EYE PROTECTION: Safety glasses. OTHER PROTECTIVE EQUIPMENT: Impervious clothing. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in a cool, dry place away from heat or open flame. Do not expose to direct sunlight or store at temperatures above 120°F. OTHER PRECAUTIONS: Keep out of reach of children. Do not puncture or incinerate container. IX - Transportation Information (ground transportation only) DOT PROPER SHIPPING NAME: Consumer Commodity DOT CLASS: ORM-D DOT ID NUMBER: None DOT PACKING GROUP: None The shipping information listed above applies only to non-bulk 119 gallons) containers of this product. This product may have more than one proper shipping name depending on packaging, product properties, & mode of shipment. If any alteration of packaging, product, or mode of transportation is further intended, different shipping names and labeling may apply. REVISION DATE: March 12, 2004 Prepared by: PMR DATE OF ISSUE: March 23, 2004 This information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Total Solutions assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material such vendees or users assume all risks associated with the use of this material. Page 227 of 1287 Page 227 of 1287 Page 227 of 1287 Page 227 of 1287 ---PAGE BREAK--- Bonide Wasp & Hornet Killer (Aerosol) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/06/2015 EN (English US) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : Bonide Wasp & Hornet Killer (Aerosol) Product code : 4392 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Bonide Products, Inc. 6301 Sutliff Road Oriskany, NY 13424 T (315) 736-8231 www.bonide.com 1.4. Emergency telephone number Emergency number : CHEMTREC - 1 (800) 262-8200 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Flam. Liq. 3 H226 Muta. 1B H340 Carc. 1B H350 STOT RE 1 H372 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS02 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H226 - Flammable liquid and vapor H340 - May cause genetic defects. H350 - May cause cancer. H372 - Causes damage to organs through prolonged or repeated exposure. Precautionary statements (GHS-US) : P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from ignition sources. - No smoking P233 - Keep container closed P240 - Ground/bond container and receiving equipment P242 - Use only non-sparking tools P243 - Take precautionary measures against static discharge P260 - Do not breathe mist P264 - Wash hands thoroughly after handling P270 - Do not eat, drink or smoke when using this product P280 - Wear protective gloves/eye protection P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P308+P313 - IF exposed or concerned: Get medical advice/attention P314 - Get medical advice and attention if you feel unwell P370+P378 - In case of fire: Use Carbon Dioxide, Dry chemical, Foam, Water for extinction P403+P235 - Store in a well-ventilated place. Keep cool P405 - Store locked up P501 - Dispose of contents/container to in accordance with local/national regulations 2.3. Other hazards No additional information available Page 228 of 1287 Page 228 of 1287 Page 228 of 1287 Page 228 of 1287 ---PAGE BREAK--- Bonide Wasp & Hornet Killer (Aerosol) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/06/2015 EN (English US) 2/6 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients Mixture Name Product identifier % Classification (GHS-US) Mineral Spirits (CAS No) 8052-41-3 96.5 Flam. Liq. 3, H226 Muta. 1B, H340 Carc. 1B, H350 STOT RE 1, H372 Asp. Tox. 1, H304 PIPERONYL BUTOXIDE (CAS No) 51-03-6 0.5 Not classified permethrin (CAS No) 52645-53-1 0.25 Not classified TETRAMETHRIN (CAS No) 7696-12-0 0.1 Not classified SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Assure fresh air breathing. Allow the victim to rest. First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important and effects, both acute and delayed : May cause genetic defects. May cause cancer with prolonged/repested exposure. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Flammable liquid and vapor. Exposures to temperatures above 130 degrees F may cause bursting. Explosion hazard : May form flammable/explosive vapor-air mixture. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. Page 229 of 1287 Page 229 of 1287 Page 229 of 1287 Page 229 of 1287 ---PAGE BREAK--- Bonide Wasp & Hornet Killer (Aerosol) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/06/2015 EN (English US) 3/6 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Take precautionary measures against static discharge. Use only non-sparking tools. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Eliminate all ignition sources if safe to do so. Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Storage conditions : Store in original container. Keep container closed. Incompatible products : Strong bases. strong acids. Incompatible materials : Sources of ignition. Heat sources. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters Mineral Spirits (8052-41-3) USA ACGIH ACGIH TWA (ppm) 100 ppm USA ACGIH ACGIH STEL (ppm) 100 ppm 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Respiratory protection : Wear approved mask. Other information : When using, do not eat, drink or smoke. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : liquid. Color : Colorless. Odor : odorless to faint deodorized kerosene odor. Odor threshold : No data available pH : No data available Relative evaporation rate (butyl acetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : No data available Flash point : 192 °F Self ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : No data available Relative vapor density at 20 °C : No data available Relative density : No data available Solubility : No data available Page 230 of 1287 Page 230 of 1287 Page 230 of 1287 Page 230 of 1287 ---PAGE BREAK--- Bonide Wasp & Hornet Killer (Aerosol) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/06/2015 EN (English US) 4/6 Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Carbon monoxide. Carbon dioxide. May release flammable gases. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified Mineral Spirits (8052-41-3) LD50 oral rat > 5000 mg/kg (Rat) LD50 dermal rabbit > 3000 mg/kg (Rabbit) LC50 inhalation rat (mg/l) > 5.5 mg/l/4h (Rat) permethrin (52645-53-1) LD50 oral rat > 383 mg/kg (Rat) LD50 dermal rat 4000 mg/kg (Rat) LD50 dermal rabbit > 2000 mg/kg (Rabbit) Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : May cause genetic defects. Carcinogenicity : May cause cancer. permethrin (52645-53-1) IARC group 3 - Not Classifiable Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Causes damage to organs through prolonged or repeated exposure. Causes damage to organs through prolonged or repeated exposure Aspiration hazard : Not classified Potential Adverse human health effects and : Based on available data, the classification criteria are not met. Page 231 of 1287 Page 231 of 1287 Page 231 of 1287 Page 231 of 1287 ---PAGE BREAK--- Bonide Wasp & Hornet Killer (Aerosol) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/06/2015 EN (English US) 5/6 SECTION 12: Ecological information 12.1. Toxicity Permethrin (52645-53-1) LC50 fish 1 0.0025 mg/l 96 h; Salmo gairdneri mykiss) EC50 Daphnia 1 0.00043 mg/l (48 h; Daphnia magna; Enzyme effect) LC50 fish 2 0.016 mg/l (96 h; Pimephales promelas) EC50 Daphnia 2 0.290 mg/l (24 h; Lymnaea sp.) 12.2. Persistence and degradability Bonide Wasp & Hornet Killer (Aerosol) Persistence and degradability Not established. 12.3. Bioaccumulative potential Bonide Wasp & Hornet Killer (Aerosol) Bioaccumulative potential Not established. Mineral Spirits (8052-41-3) Log Pow -3.16 - 7.06 Bioaccumulative potential Bioaccumable. Permethrin (52645-53-1) BCF fish 1 560 Salmo gairdneri mykiss) BCF fish 2 480 (Cyprinodon variegatus) BCF other aquatic organisms 1 0.1 mg/l (>24 h; Algae) BCF other aquatic organisms 2 1900 (Ostreidae) Log Pow 3.48 - 6.5 Bioaccumulative potential High potential for bioaccumulation (Log Kow > 12.4. Mobility in soil Mineral Spirits (8052-41-3) Surface tension 0.02 N/m (20 Permethrin (52645-53-1) Ecology - soil Toxic to bees. 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to in accordance with local/national regulations. Additional information : Handle empty containers with care because residual vapors are flammable. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT No dangerous good in sense of transport regulations Additional information Other information : No supplementary information available. ADR Transport document description : Transport by sea No additional information available Air transport No additional information available Page 232 of 1287 Page 232 of 1287 Page 232 of 1287 Page 232 of 1287 ---PAGE BREAK--- Bonide Wasp & Hornet Killer (Aerosol) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/06/2015 EN (English US) 6/6 SECTION 15: Regulatory information This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION: Causes moderate eye irritation. Avoid contact with eyes or clothing. Wash thoroughly with soap and water after handling. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. Remove contaminated clothing and wash clothing before reuse. 15.1. US Federal regulations Bonide Wasp & Hornet Killer (Aerosol) Not listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA No additional information available EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC or 1999/45/EC Not classified 15.2.2. National regulations No additional information available 15.3. US State regulations No additional information available SECTION 16: Other information Other information : None. Full text of H-phrases: see section 16: Asp. Tox. 1 Aspiration hazard Category 1 Carc. 1B Carcinogenicity Category 1B Flam. Liq. 3 Flammable liquids Category 3 Muta. 1B Germ cell mutagenicity Category 1B STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1 H226 Flammable liquid and vapor H304 May be fatal if swallowed and enters airways H340 May cause genetic defects H350 May cause cancer H372 Causes damage to organs through prolonged or repeated exposure SDS US (GHS HazCom 2012) - Pesticides This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. Page 233 of 1287 Page 233 of 1287 Page 233 of 1287 Page 233 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET BruteLube Multi-Purpose Cutting Wax I. PRODUCT AND MANUFACTURER INFORMATION Product name BruteLube Multi-Purpose Cutting Wax Chemical name Synonyms CAS number NE Manufacturer Champion Cutting Tool Corp. 10 Madison Avenue Rockville Centre, NY 11570 Emergency phone number [PHONE REDACTED] Date of last revision 7/9/03 II. HAZARDOUS INGREDIENTS HAZARDOUS COMPONENT CAS NUMBER % Optional OSHA PEL ACGIH TLV CHEMICAL AND/OR COMMON NAME(S) MINERAL OIL (CAS 64742-52-5) 350 PPM 350 PPM III. PHYSICAL AND CHEMICAL CHARACTERISTICS Boiling point @ 760 mm Hg >700 F Vapor pressure at 20 °C <1 Vapor density (air = 1) ND Solubility in water NOT SOLUBLE Appearance and odor YELLOW OPAQUE SOLID Specific gravity (H2O = 1.0) 0.85 Melting point 172 F Evaporation rate (butyl acetate = 1) <1 IV. FIRE AND EXPLOSION HAZARD DATA Combustible/Not combustible NOT COMBUSTIBLE Flammable/Not flammable NOT FLAMMABLE Pyrophoric/Not pyrophoric NOT PYROPHORIC Explosive/Not explosive NOT EXPLOSIVE Flash point (test method) >450 F Flammable limits (in Air % by volume) NA NA NA Extinguishing media FOAM OR DRY CHEMICAL Special fire-fighting procedures or equipment SAME AS FOR PETROLEUM PRODUCTS Unusual fire and explosion hazards NONE V. REACTIVITY DATA Material is stable/unstable STABLE Conditions to avoid AVOID STRONG ACIDS OR BASES Incompatibility (materials to avoid) AVOID STRONG ACIDS OR BASES Hazardous decomposition or by-products NONE KNOWN Hazardous polymerization will/will not occur WILL NOT OCCUR VI. HEALTH HAZARD DATA Threshold limit value NE Primary route(s) of entry Known Hazards Under 29 CFR 1910.1200 Mutagenic (genetic defects) NONE Reproductive NONE Systemic NONE Teratogenic (birth defects) NONE Page 1 Page 234 of 1287 Page 234 of 1287 Page 234 of 1287 Page 234 of 1287 ---PAGE BREAK--- Carcinogen listed in: NTP (National Toxicology Program) NO IARC Monographs NO OSHA NO Signs and of exposure Inhalation NA Skin contact If used as recommended, skin irritation should not occur. Eye contact NA Ingestion Unlikely to occur Emergency first aid procedures Inhalation NA Skin contact Wash with soap and water Eye contact Flush with water for 15 minutes, seek medical attention Ingestion Do not induce vomiting. Call a physician. Medical conditions generally aggravated by exposure NONE KNOWN Notes to physician VII. PRECAUTIONS FOR SAFE HANDLING AND USE Steps to take if released or spilled Flush with water and/or use absorbent material and mop-up Waste disposal method Dispose of in manner consistent with Federal, State and Local regulations. Precautions for handling and storing Launder contaminated clothes before reuse. Other precautions Use as directed Hazard ratings NFPA Health 1 Flammability 1 Reactivity 0 Personal protection VIII. CONTROL MEASURES Protective gloves (type and material) Not normally required under normal working conditions. In situations of overexposure, use chemical resistant gloves. Eye protection If potential for eye contact exists, wear Safety Glasses/Goggles Other protective clothing or equipment Not normally required Respiratory protection (specify type) Not needed under recommended conditions Ventilation and conditions Local Yes Mechanical Recommended Other None Special None Work/hygienic practices Wash hands at end of workday. IX. ADDITIONAL REGULATORY INFORMATION SARA hazard category (Section 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) NONE Toxic chemical(s) subject to the supplier notification requirements of section 313 of the Superfund Amendment and Reauthorization Act of 1986 (SARA) and the requirements of 40 CFR part 372 NONE Ingredient(s) regulated under the Clean Air Act Section 112 hazardous air pollutants and subject to all reporting requirements of CERCLA (Superfund) NONE NA – not applicable NR – not reported ND – not determined NE – not established UN – unknown The information presented in this MSDS has been compiled from sources deemed reliable. This MSDS is presented in good faith and believed to be accurate as of the effective date shown above. No warranty, expressed or implied, is given. Regulatory requirements are subject to change and may differ from one location to another. It is the responsibility of the buyer to insure compliance with federal, state, provincial and local laws and regulations. Page 2 Page 235 of 1287 Page 235 of 1287 Page 235 of 1287 Page 235 of 1287 ---PAGE BREAK--- Page 236 of 1287 Page 236 of 1287 Page 236 of 1287 Page 236 of 1287 ---PAGE BREAK--- Page 237 of 1287 Page 237 of 1287 Page 237 of 1287 Page 237 of 1287 ---PAGE BREAK--- Page 238 of 1287 Page 238 of 1287 Page 238 of 1287 Page 238 of 1287 ---PAGE BREAK--- Page 239 of 1287 Page 239 of 1287 Page 239 of 1287 Page 239 of 1287 ---PAGE BREAK--- Page 240 of 1287 Page 240 of 1287 Page 240 of 1287 Page 240 of 1287 ---PAGE BREAK--- Page 241 of 1287 Page 241 of 1287 Page 241 of 1287 Page 241 of 1287 ---PAGE BREAK--- Page 242 of 1287 Page 242 of 1287 Page 242 of 1287 Page 242 of 1287 ---PAGE BREAK--- to Automotive MSDS Listings product sheet for CARPET AND PLUS CLEANER-- AEROSOL Material Safety Data Sheet - CARPET AND PLUS CLEANER-- AEROSOL Product Identification EDP Number: 110220 Product Name: CARPET AND PLUS CLEANER-- AEROSOL DOT Hazard: CONSUMER COMMODITY DOT ShipName: ORM-D Physical Data Boil Point Freeze Point Gravity Vapor Pressure Vapor Density Evap Rate % Volatile Solubility N./A N/A ~ 1 115@130F N/A N/A ~90 YES Odor and Appearance: YELLOW WITH FLORAL / AMMONIA ODOR Ingedients Material Name Percentage TLV Hazard CAS Number WATER 80-90 N/A N/A 7732-18-5 2-BUTOXY ETHANOL 5-10 25 PPM SKIN IRRITATION 111-76-2 1-2 N/D N/A 9036-19-5 TETRASODIUM EDTA 1-2 N/A N/A 64-02-8 LIQUIFIED PETROLEUM GAS 5-10 N/A FLAMMABLE 68476-85-7 Fire and Explosion Hazard Data Flash Point LEL UEL EXTREMELY FLAMMABLE 1.8 9.2 Extinguishing Media CARBON DIOXIDE, FOAM OR DRY CHEMICAL Unusual Fire & Explosion Hazards VAPORS MAY TRAVEL GREAT DISTANCES TO IGNITION SOURCE. CANS WILL RUPTURE OR BURST IF HEATED ABOVE 130F Health Hazard Data Acute Effects SEE BELOW Swallowing MAY CAUSE GASTROINTESTINAL IRRITATION OR VOMITING Inhalation MAY CAUSE RESPIRATORY SYSTEM IRRITATION AND CENTRAL NERVOUS SYSTEM EFFECTSLIKE HEADACHE, NARCOSIS AND BLURRED VISION Skin Contact MAY CAUSE REDNESS OR IRRITATION Eye Contact MAY CAUSE REDNESS, TEARING OR BLURRED VISION Chronic Effects N/A Other Hazards N/A Emergency First Aid Procedures Swallowing SEEK MEDICAL ATTENTION IMMEDIATELY Inhalation MOVE TO FRESH AIR . GIVE ARTIFICIAL RESPIRATION IF NECESSARY. SEEK MEDICAL HELP IMMEDIATELY SkinContact WASH WITH SOAP AND WATER. Eye Contact RINSE WITH WATER FOR 15 MINUTES. SEEK MEDICAL HELP IMMEDIATELY Primary INHALATION Note to Physician N/A Malco Products MSDS - 110220 - CARPET AND PLUS CLEANER-- AEROSOL (1 of 2) [9/10/2001 1:06:17 AM] Page 243 of 1287 Page 243 of 1287 Page 243 of 1287 Page 243 of 1287 ---PAGE BREAK--- Reactivity Data Stablility YES Conditions to Avoid KEEP AWAY FROM HEAT, DIRECT SUN LIGHT , OPEN FLAMES AND SPARKS. DO NOT STORE ABOVE 130 F. Materails to Avoid STRONG OXIDIZERS, STRONG ACIDS Hazardous Decom Prod CARBON MONOXIDE AND OTHER TOXIC CHEMICALS Hazardous Polymerization NON Additional Cond to Avoid N/A Spill or Leak Procedures Steps if spilled REMOVE ALL SOURCES OF IGNITION. VENTILATE AREA. MOP UP OR SOAK UP WITH ABSORBANTS Waste Disposal Method IN ACCORDANCE WITH LOCAL , STATE AND FEDERAL REGULATIONS Special Protection Information Respiratory Protection NONE IF GOOD VENTILATION IS MAINTAINED Ventilation MECHANICAL EXHAUST Impervious Gloves YES Other PPE SAFETY GOGLES Special Precautions Storage & Handling Precautions N/A Other Precautions N/A HMIS Ratings Health 3 Flammability 2 Reactivity 0 Personal Protective Equipment B Prepared By: JOEL POCHRON TECHNICAL DIRECTOR MALCO PRODUCTS, INC. 36l FAIRVIEW AVE P O BOX 892 BARBERTON OHIO 44203 [PHONE REDACTED] OR [PHONE REDACTED] These numbers are available days, nights, weekends and holidays. Last Updated 12/7/98 THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. VENDOR ASSUMES NO RESPONSIBILITY FOR INJURY TO VENDEE OR THIRD PERSONS PROXIMATELY CAUSED BY THE MATERIALS IF REASONABLE SAFETY PROCEDURES ARE NOT ADHERED TO AS STIPULATED IN THE DATA SHEET. ADDITIONALLY, VENDOR ASSUMES NO RESPONSIBILITY FOR INJURY TO VENDEE OR THIRD PERSONS PROXIMATELY CAUSED BY ABNORMAL USE OF THE MATERIAL, EVEN IF REASONABLE SAFETY PROCEDURES ARE FOLLOWED. FURTHERMORE, VENDEE ASSUMES THE RISK IN HIS USE OF THE MATERIAL. Malco Products MSDS - 110220 - CARPET AND PLUS CLEANER-- AEROSOL (2 of 2) [9/10/2001 1:06:17 AM] Page 244 of 1287 Page 244 of 1287 Page 244 of 1287 Page 244 of 1287 ---PAGE BREAK--- Corrosion Off Product Code: C1614 Page 1 of 3 SAFETY DATA SHEET SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle® Corrosion Off™ PRODUCT TYPE: Battery Cleaner PRODUCT CODE: C1614 MANUFACTURED FOR: Castle Products, Inc. 424 St. Paul Street Rochester, NY 14605 [PHONE REDACTED] • FAX [PHONE REDACTED] EMERGENCY [PHONE REDACTED] SECTION 2 HAZARD IDENTIFICATION EMERGENCY OVERVIEW: DANGER: Gases Under Pressure, Flammable, Irritant POTENTIAL HEALTH EFFECTS: Eyes: Irritating to eyes. Skin: Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis. Inhalation: Irritating to respiratory system. Avoid breathing vapors or mists. of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting, and diarrhea. Potential for aspiration if swallowed. SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % Propane/Isobutane/N-Butane 68476-86-8 NE NE NE 10-30% Triethanolamine 102-71-6 50 ppm 5 mg/m3 NE 1-5% 2-Butoxyethanol 111-76-2 NE NE NE SECTION 4 FIRST AID MEASURES First Aid Procedures: Eye contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician if irritation persists. Skin contact: For skin contact flush with large amounts of water. Call a physician if irritation persists. Inhalation: Immediately remove from further exposure. Give supplemental oxygen, if breathing is difficult. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by mouth to an unconscious person. Note to physician: No information available. SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: ≥ -156°F -104°C) LOWER EXPLOSIVE LIMIT: ND UPPER EXPLOSIVE LIMIT: ND EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate for surrounding fire. UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area. Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Ventilate spaces before entering. Environmental precautions: Prevent further leakage or spillage if safe to do so. Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Eliminate ignition sources including sources of electrical, static or frictional sparks. Wear appropriate protective equipment and clothing during clean-up. Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal. Page 245 of 1287 Page 245 of 1287 Page 245 of 1287 Page 245 of 1287 ---PAGE BREAK--- Corrosion Off Product Code: C1614 Page 2 of 3 Large Spills: Dike far ahead of liquid spill for later disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. SECTION 7 HANDLING AND STORAGE Handling: Propellant is extremely flammable. Do not store near ignition sources. Avoid breathing mist. Avoid contact with skin and eyes. Wear suitable protective clothing. Wash hands after handling. Storage: Keep from freezing. Keep containers closed. Store in a cool, dry place. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established. Engineering controls: Use local exhaust ventilation. Personal protective equipment: Gloves: Not normally required. Eye/Face Protection: Safety glasses or goggles. Skin Protection: Wear clothing suited to the task being performed. Respiratory Protection: Not normally required if good ventilation is maintained. SECTION 9 PHYSICAL and CHEMICAL PROPERTIES BOILING POINT: ND SPECIFIC GRAVITY (H2O=1): ND VAPOR PRESSURE: ND PERCENT VOLATILE BY VOL 18% VAPOR DENSITY (air=1) >1 EVAPORATION RATE (Butyl Acetate=1): ND SOLUBILITY IN WATER: ND APPEARANCE & ODOR: Yellow Liquid / Mild Solvent pH: 9 SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable. INCOMPATIBILITY (material to avoid): Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Oxides, Nitrogen Oxides, fumes. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Components Test Results: Triethanolamine: Oral LD50 (rat) 4190 mg/kg; Dermal LD50 (rabbit) 2000 mg/kg 2-Butoxyethanol: Oral LD50 (rat) 470 mg/kg; Dermal LD50 (rabbit) 220 mg/kg; Inhalation LC50 (rat) 450 ppm (4h) There are no known carcinogenic chemicals in this product. SECTION 12 ECOLOGICAL INFORMATION Component Test Results: None reported. SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Dispose according to all applicable Federal, State, and Local regulations. SECTION 14 TRANSPORT INFORMATION DOT Ground: Consumer Commodity ORM-D, or Limited Quantity. SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations. CERCLA (Superfund) reportable quantity: None SARA (Superfund Amendments and Reauthorization Act of 1986): 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Section 302 extremely hazardous substance: No Section 311 hazardous chemical: Acute Health Hazard: Yes; Chronic Health Hazard: No; Fire Hazard: No; Sudden Release of Pressure Hazard: No. Page 246 of 1287 Page 246 of 1287 Page 246 of 1287 Page 246 of 1287 ---PAGE BREAK--- Corrosion Off Product Code: C1614 Page 3 of 3 Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR. SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.) HMIS® ratings Health: 1 Flammability: 2 Physical hazard: 2 NFPA ratings Health: 1 Flammability: 4 Instability: 0 Other: NA-Not Applicable, ND-Not Determined, NE-Not Established. Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. PREPARED: 7/16/93 UPDATED: 6/14/13 PRODUCT C1614 Page 247 of 1287 Page 247 of 1287 Page 247 of 1287 Page 247 of 1287 ---PAGE BREAK--- Dry Lub Product Code: C2015 Page 1 of 3 SAFETY DATA SHEET SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle® Dry Lub™ PRODUCT TYPE: Dry Lubricant Coating PRODUCT CODE: C2015 MANUFACTURED FOR: Castle Products, Inc. 424 St. Paul Street Rochester, NY 14605 [PHONE REDACTED] • FAX [PHONE REDACTED] EMERGENCY [PHONE REDACTED] SECTION 2 HAZARD IDENTIFICATION EMERGENCY OVERVIEW: DANGER: Gases Under Pressure, Flammable, Irritant POTENTIAL HEALTH EFFECTS: Eyes: Irritating to eyes. Skin: Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis. Inhalation: Irritating to respiratory system. Avoid breathing vapors or mists. of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting, and diarrhea. Potential for aspiration if swallowed. SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % Acetone 67-64-1 1000ppm 750ppm 750ppm 15-40% Toluene 108-88-3 200ppm 20ppm 150ppm 15-40% Propane/Isobutane/N-Butane 68476-86-8 NE NE NE 10-30% Isopropyl Alcohol 67-63-0 400ppm NE 400ppm 5-10% Molybdenum Disulfide 1317-33-5 15 mg/m3(dust) 10 mg/m3 NE 1-5% SECTION 4 FIRST AID MEASURES First Aid Procedures: Eye contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician if irritation persists. Skin contact: For skin contact flush with large amounts of water. Call a physician if irritation persists. Inhalation: Immediately remove from further exposure. Give supplemental oxygen, if breathing is difficult. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by mouth to an unconscious person. Note to physician: No information available. SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: ≥ -141°F LOWER EXPLOSIVE LIMIT: ND UPPER EXPLOSIVE LIMIT: ND EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate for surrounding fire. UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area. Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Ventilate spaces before entering. Environmental precautions: Prevent further leakage or spillage if safe to do so. Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Eliminate ignition sources including sources of electrical, static or frictional sparks. Wear appropriate protective equipment and clothing during clean-up. Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal. Page 248 of 1287 Page 248 of 1287 Page 248 of 1287 Page 248 of 1287 ---PAGE BREAK--- Dry Lub Product Code: C2015 Page 2 of 3 Large Spills: Dike far ahead of liquid spill for later disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. SECTION 7 HANDLING AND STORAGE Handling: Product is extremely flammable. Do not store near ignition sources. Avoid breathing mist. Avoid contact with skin and eyes. Wear suitable protective clothing. Wash hands after handling. Storage: Keep from freezing. Keep containers closed. Store in a cool, dry place. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established. Engineering controls: Use local exhaust ventilation. Personal protective equipment: Gloves: Not normally required. Eye/Face Protection: Eye protection not normally required but recommended. Skin Protection: Wear clothing suited to the task being performed. Respiratory Protection: Not normally required if good ventilation is maintained. SECTION 9 PHYSICAL and CHEMICAL PROPERTIES BOILING POINT: ND SPECIFIC GRAVITY (H2O=1): ND VAPOR PRESSURE: ND PERCENT VOLATILE BY VOL 64.5% VAPOR DENSITY (air=1) >1 EVAPORATION RATE (Butyl Acetate=1): ND SOLUBILITY IN WATER: ND APPEARANCE & ODOR: Black Powder / Solvent pH: NA SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable. INCOMPATIBILITY (material to avoid): Strong oxidizing agents. Strong bases. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide, Carbon Dioxide, Sulfur Oxides. HAZARDOUS POLYMERIZATION: Does not occur. SECTION 11 TOXICOLOGICAL INFORMATION Components Test Results: Acetone: Oral LD50 (rat) 5800 mg/kg Toluene: Oral LD50 (rat) 636 mg/kg; Dermal LD50 (rabbit) 8390 mg/kg; Inhalation LC50 (rat) 12.5 mg/L (4h) ISopropanol: Oral LD50 (rat) 4396 mg/kg; Dermal LD50 (rabbit) 12870 mg/kg; Inhalation LC50 (rat) 72.6 mg/L (4h) Not classified to be a carcinogen to humans. SECTION 12 ECOLOGICAL INFORMATION Component Test Results: None reported. SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Dispose according to all applicable Federal, State, and Local regulations. SECTION 14 TRANSPORT INFORMATION DOT Ground: Consumer Commodity ORM-D, or Limited Quantity. SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations. CERCLA (Superfund) reportable quantity: None SARA (Superfund Amendments and Reauthorization Act of 1986): 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Section 302 extremely hazardous substance: No Page 249 of 1287 Page 249 of 1287 Page 249 of 1287 Page 249 of 1287 ---PAGE BREAK--- Dry Lub Product Code: C2015 Page 3 of 3 Section 311/312 hazardous chemical: Acute Health Hazard: Yes; Chronic Health Hazard: Yes; Fire Hazard: Yes; Sudden Release of Pressure Hazard: No; Reactive Hazard: No.. Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR. SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.) HMIS® ratings Health: 2 Flammability: 4 Physical hazard: 2 NFPA ratings Health: 2 Flammability: 4 Instability: 0 Other: NA-Not Applicable, ND-Not Determined, NE-Not Established. Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. PREPARED: 11/29/93 UPDATED: 9/19/2013 PRODUCT C2015 Page 250 of 1287 Page 250 of 1287 Page 250 of 1287 Page 250 of 1287 ---PAGE BREAK--- MANUFACTURER MATERIAL SAFETY DATA SHEET HAZARD RATING Castle Products, Inc. Hazard: 0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme. Health 2 424 St. Paul Street Protection: A-Goggles, B-Goggles & gloves, Fire 4 Rochester, NY 14605 C-Goggles, gloves, & protective wear. Reactivity 0 1-[PHONE REDACTED] Other: NA-Not Applicable, ND-Not Determined, Protection B EMERGENCY (585) 275-3232 NE-Not Established. SECTION I DESCRIPTION TRADE NAME: Castle® Long Life™ PRODUCT TYPE: Battery Protector SECTION II HAZARDOUS INGREDIENTS INGREDIENT CAS # PEL TLV STEL % Trichloroethylene 79-01-6 50 ppm 50 ppm 100 ppm 50.0 % Propane/Isobutane/n-Butane 68476-86-8 800 ppm 800 ppm NE 30.0 % Mineral Oil Hydrotreated (severe) 64742-52-5 5 mg/m3 5 mg/m3 (skin) 10 mg/m3 20.0 % Metalworking Fluid Additive Mixture 100 ppm 100 ppm NE 5.0 % Stoddard Solvent 8052-41-3 100 ppm 100 ppm NE 5.0 % SECTION III PHYSICAL DATA BOILING POINT: -43°F - 387°F SPECIFIC GRAVITY (H2O=1): 0.8523 VAPOR PRESSURE: 80-90 PERCENT VOLATILE BY VOL % NE VAPOR DENSITY: Heavier than air EVAPORATION RATE (Butyl Acetate=1): Faster than Butyl Acetate SOLUBILITY IN WATER: Negligible APPEARANCE & ODOR Purple / Solvent SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT (method used): -156°F (TCC) LOWER EXPLOSIVE LIMIT: 0.7 % UPPER EXPLOSIVE LIMIT: 10.5 % EXTINGUISHING MEDIA: Alcohol foam, CO2, dry chemical foam, or water fog. UNUSUAL FIRE & EXPLOSION HAZARDS: Avoid all sources of ignition, welding arcs, and open flames. Vapors can travel to source of ignition and flash back. “Empty” cans may retain product residue and can be hazardous. Do not pressurize, cut, weld, braze, solder, drill, or grind cans. Do not expose cans to heat, flame, sparks, static electricity, or other sources of ignition. Heated cans may build up pressure and explode; can cause injury or death. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus (MSHA / NIOSH approved or equivalent) and full protective gear. SECTION V HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: Eye contact, skin contact, inhalation, and ingestion. EFFECTS OF OVEREXPOSURE: Long-term exposure may cause damage to lungs, kidneys, and/or nervous system. • Eyes: may cause irritation, pain, tearing, reddening, swelling, and stinging. • Skin: defatting, drying, irritation, and rash. • Inhalation: difficulty in breathing, headaches, dizziness, nausea, decreased blood pressure, changes in heart rate, and cyanosis. • Ingestion: harmful or fatal. Corrosive: may cause severe, permanent damage to mouth, throat, and stomach. EMERGENCY & FIRST AID PROCEDURES: • Eyes and skin: Flush immediately with plenty of water. Get immediate medical attention. Remove affected clothing and wash separately before reusing. • Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. • Ingestion: Do NOT induce vomiting. Give glass of water or milk. Call physician or poison control immediately. Never give food or drink to an unconscious person. SECTION VI REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (materials to avoid): Strong acids, alkalis, oxidizers, and amines. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon, oxides of nitrogen; may produce forms of chloride, chlorine, and phosgene. SECTION VII SPILL OR LEAK PROCEDURES IF RELEASED OR SPILLED: Absorb spill with inert material (such as dry sand or earth). Dispose in chemical waste container. WASTE DISPOSAL METHOD: Dispose as hazardous waste in accordance with federal, state, and local regulations. SECTION VIII SPECIAL PROTECTION INFORMATION VENTILATION: LOCAL MECHANICAL OTHER RESPIRATORY PROTECTION: If airborne concentrations are expected to exceed exposure limits (listed above), a NIOSH / MSHA approved air-purifying respirator may be permissible. If potential for uncontrolled release, exposure levels are unknown, or if air-purifying respirators may not provide adequate protection, use self-contained, positive pressure air-supplied respirator. EYE PROTECTION: Safety glasses with side shields (or safety goggles) and a face shield. PROTECTIVE GLOVES: Where contact is likely, wear chemical resistant gloves. OTHER PROTECTIVE EQUIPMENT: Where contact is likely, wear chemical suit and rubber boots. Follow standard industrial clothing standards. SECTION IX SPECIAL PRECAUTIONS HANDLING & STORING PRECAUTIONS: Wash thoroughly after handling. Keep away from heat, sparks, or open flame. Store at temperature below 120°F. Keep from freezing. PREPARED: 10/21/93 UPDATED: 12/31/04 PRODUCT C1607 Page 251 of 1287 Page 251 of 1287 Page 251 of 1287 Page 251 of 1287 ---PAGE BREAK--- Plexo Product Code: C2010 Page 1 of 3 SAFETY DATA SHEET SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle® Plexo™ PRODUCT TYPE: Plastic Glass Cleaner PRODUCT CODE: C2010 MANUFACTURED FOR: Castle Products, Inc. 424 St. Paul Street Rochester, NY 14605 [PHONE REDACTED] • FAX [PHONE REDACTED] EMERGENCY [PHONE REDACTED] SECTION 2 HAZARD IDENTIFICATION EMERGENCY OVERVIEW: WARNING: Gases Under Pressure, Irritant POTENTIAL HEALTH EFFECTS: Eyes: Irritating to eyes. Skin: Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis. Inhalation: Irritating to respiratory system. Avoid breathing vapors or mists. of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. Ingestion: Not an expected route of exposure. Potential for aspiration if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting, and diarrhea. SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % Water 7732-18-5 NE NE NE 75-100% Propane/Isobutane/N-Butane 68476-86-8 NE NE NE 3-7% Isopropyl Alcohol 67-63-0 400ppm 200ppm 400ppm 1-5% 2-Butoxyethanol 111-76-2 50ppm 20ppm NE 1-5% SECTION 4 FIRST AID MEASURES First Aid Procedures: Eye contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician if irritation persists. Skin contact: For skin contact flush with large amounts of water. Call a physician if irritation persists. Inhalation: Immediately remove from further exposure. Give supplemental oxygen, if breathing is difficult. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by mouth to an unconscious person. Note to physician: If the product is ingested, treat the affected person SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: -132°F (-91°C) LOWER EXPLOSIVE LIMIT: ND UPPER EXPLOSIVE LIMIT: ND EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate for surrounding fire. UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area. Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Ventilate spaces before entering. Environmental precautions: Prevent further leakage or spillage if safe to do so. Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Eliminate ignition sources including sources of electrical, static or frictional sparks. Wear appropriate protective equipment and clothing during clean-up. Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal. Page 252 of 1287 Page 252 of 1287 Page 252 of 1287 Page 252 of 1287 ---PAGE BREAK--- Plexo Product Code: C2010 Page 2 of 3 Large Spills: Dike far ahead of liquid spill for later disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. SECTION 7 HANDLING AND STORAGE Handling: Propellant is extremely flammable. Store away from heat, sparks, and flames. Avoid breathing mist. Avoid contact with skin and eyes. Wear suitable protective clothing. Wash hands after handling. Storage: Keep from freezing. Keep containers closed. Store in a cool, dry place. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established. Engineering controls: Use local exhaust ventilation. Personal protective equipment: Gloves: Not normally required. Eye/Face Protection: Eye protection not normally required but recommended. Skin Protection: Wear clothing suited to the task being performed. Respiratory Protection: Not normally required if good ventilation is maintained. SECTION 9 PHYSICAL and CHEMICAL PROPERTIES BOILING POINT: ND SPECIFIC GRAVITY (H2O=1): 0.95 VAPOR PRESSURE: ND PERCENT VOLATILE BY VOL 11.73 VAPOR DENSITY (air=1) ND EVAPORATION RATE (Butyl Acetate=1): ND SOLUBILITY IN WATER: Complete APPEARANCE & ODOR: Dark Green Liquid / Solvent pH: 11 SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable under recommended storage conditions. INCOMPATIBILITY (material to avoid): Strong oxidizing agents, strong bases. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon oxides, fumes. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Components Test Results: None reported. Carcinogenicity: ACGIH A3 (animal carcinogen) for Kerosene. Target organ effects: Central nervous system, eyes, respiratory system, skin. SECTION 12 ECOLOGICAL INFORMATION Component Test Results: None reported. SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Dispose according to all applicable Federal, State, and Local regulations. SECTION 14 TRANSPORT INFORMATION DOT ground, Consumer Commodity ORM-D, or Limited Quantity. IATA, UN1950, Aerosols, Flammable, 2.2 LTD QTY. IMDG, UN1950, Aerosols, 2.2, LTD QTY. SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations. CERCLA (Superfund) reportable quantity: None SARA (Superfund Amendments and Reauthorization Act of 1986): 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Section 302 extremely hazardous substance: No Section 311 hazardous chemical: No Page 253 of 1287 Page 253 of 1287 Page 253 of 1287 Page 253 of 1287 ---PAGE BREAK--- Plexo Product Code: C2010 Page 3 of 3 Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR. SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.) HMIS® ratings Health: 1 Flammability: 2 Physical hazard: 2 NFPA ratings Health: 1 Flammability: 4 Instability: 0 Other: NA-Not Applicable, ND-Not Determined, NE-Not Established. Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. PREPARED: 6/9/93 UPDATED: 6/14/13 PRODUCT C2010 Page 254 of 1287 Page 254 of 1287 Page 254 of 1287 Page 254 of 1287 ---PAGE BREAK--- Tuff Glove Product Code: C1643 Page 1 of 3 SAFETY DATA SHEET SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle® Tuff Glove™ PRODUCT TYPE: Skin Protector PRODUCT CODE: C1643 MANUFACTURED FOR: Castle Products, Inc. 424 St. Paul Street Rochester, NY 14605 [PHONE REDACTED] • FAX [PHONE REDACTED] EMERGENCY [PHONE REDACTED] SECTION 2 HAZARD IDENTIFICATION EMERGENCY OVERVIEW: WARNING: Irritant Keep out of reach of children. POTENTIAL HEALTH EFFECTS: Eyes: May be irritating to eyes. Skin: No expected effects. Inhalation: Not a normal route of entry. Ingestion: May cause gastrointestinal discomfort. . SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % Water 7732-18-5 NE NE NE SECTION 4 FIRST AID MEASURES First Aid Procedures: Eye contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician if irritation persists. Skin contact: If product causes irritation, wash with large amounts of water. Call a physician if irritation persists. Inhalation: Immediately remove from further exposure. Give supplemental oxygen, if breathing is difficult. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by mouth to an unconscious person. Note to physician: If the product is ingested, treat the affected person SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: NA LOWER EXPLOSIVE LIMIT: ND UPPER EXPLOSIVE LIMIT: ND EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate for surrounding fire. UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area. Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Ventilate spaces before entering. Environmental precautions: Prevent further leakage or spillage if safe to do so. Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Eliminate ignition sources including sources of electrical, static or frictional sparks. Wear appropriate protective equipment and clothing during clean-up. Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal. Large Spills: Dike far ahead of liquid spill for later disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. Page 255 of 1287 Page 255 of 1287 Page 255 of 1287 Page 255 of 1287 ---PAGE BREAK--- Tuff Glove Product Code: C1643 Page 2 of 3 SECTION 7 HANDLING AND STORAGE Handling: Avoid contact with eyes. Storage: Keep from freezing. Keep containers closed. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established. Engineering controls: Use local exhaust ventilation. Personal protective equipment: Gloves: Not normally required. Eye/Face Protection: Eye protection not normally required but recommended. Skin Protection: Wear clothing suited to the task being performed. Respiratory Protection: Not normally required if good ventilation is maintained. SECTION 9 PHYSICAL and CHEMICAL PROPERTIES BOILING POINT: ND SPECIFIC GRAVITY (H2O=1): 0.95 VAPOR PRESSURE: ND PERCENT VOLATILE BY VOL NE VAPOR DENSITY (air=1): ND EVAPORATION RATE (Butyl Acetate=1): 0.1 SOLUBILITY IN WATER: Complete APPEARANCE & ODOR: White Cream / Almond pH: 5 SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (material to avoid): Strong acids or oxidizing agents, HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide, Carbon Dioxide, and lowmolecular weight hydrocarbons may be produced. HAZARDOUS POLYMERIZATION: Will not occur SECTION 11 TOXICOLOGICAL INFORMATION Components Test Results: No Data Available Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. SECTION 12 ECOLOGICAL INFORMATION Components Information: No Data Available SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Dispose according to all applicable Federal, State, and Local regulations. SECTION 14 TRANSPORT INFORMATION This product is considered Non-Hazardous in all modes of transportation. Therefore, this product does not require classification by DOT, IATA, ICAO or IMDG. SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations. CERCLA (Superfund) reportable quantity: None SARA (Superfund Amendments and Reauthorization Act of 1986): 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Section 302 extremely hazardous substance: No Section 311 hazardous chemical: No Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR. Page 256 of 1287 Page 256 of 1287 Page 256 of 1287 Page 256 of 1287 ---PAGE BREAK--- Tuff Glove Product Code: C1643 Page 3 of 3 SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.) HMIS® ratings Health: 1 Flammability: 0 Physical hazard: 0 NFPA ratings Health: 1 Flammability: 0 Instability: 0 Other: NA-Not Applicable, ND-Not Determined, NE-Not Established. Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. PREPARED: 1/5/95 UPDATED: 6/14/13 PRODUCT C1643 Page 257 of 1287 Page 257 of 1287 Page 257 of 1287 Page 257 of 1287 ---PAGE BREAK--- Zapp Product Code: C1629 Page 1 of 3 SAFETY DATA SHEET SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle® Zapp™ PRODUCT TYPE: Special Electronic Cleaner PRODUCT CODE: C1629 MANUFACTURED FOR: Castle Products, Inc. 418 St. Paul Street Rochester, NY 14605 [PHONE REDACTED] • FAX [PHONE REDACTED] EMERGENCY [PHONE REDACTED] SECTION 2 HAZARD IDENTIFICATION EMERGENCY OVERVIEW: WARNING: Gases Under Pressure, Flammable, Irritant Keep out of reach of children. POTENTIAL HEALTH EFFECTS: Eyes: May be irritating to eyes. Skin: Possible skin irritation. Inhalation: May cause mucous membrane irritation. Ingestion: Harmful if swallowed. May cause gastrointestinal discomfort. . SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % n-Propyl Bromide 106-94-5 10ppm NE NE 60-100% Ethanol 64-17-5 1000ppm NE NE 1-5% Carbon Dioxide 124-38-9 5000ppm NE NE 1-5% SECTION 4 FIRST AID MEASURES First Aid Procedures: Eye contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician if irritation persists. Skin contact: For skin contact flush with large amounts of water. Call a physician if irritation persists. Inhalation: Immediately remove from further exposure. Give supplemental oxygen, if breathing is difficult. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by mouth to an unconscious person. Note to physician: If the product is ingested, treat the affected person SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: 25°F ( -4°C) LOWER EXPLOSIVE LIMIT: 4% UPPER EXPLOSIVE LIMIT: 8% EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate for surrounding fire. UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area. Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Ventilate spaces before entering. Environmental precautions: Prevent further leakage or spillage if safe to do so. Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Eliminate ignition sources including sources of electrical, static or frictional sparks. Wear appropriate protective equipment and clothing during clean-up. Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal. Large Spills: Dike far ahead of liquid spill for later disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. Page 258 of 1287 Page 258 of 1287 Page 258 of 1287 Page 258 of 1287 ---PAGE BREAK--- Zapp Product Code: C1629 Page 2 of 3 SECTION 7 HANDLING AND STORAGE Handling: Avoid breathing mist. Avoid contact with skin and eyes. Wear suitable protective clothing. Wash hands after handling. Storage: Product is flammable. Keep away from heat and sources of ignition. Keep from freezing. Keep containers closed. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established. Engineering controls: Use local exhaust ventilation. Personal protective equipment: Gloves: Not normally required. Eye/Face Protection: Wear safety glasses or goggles. Skin Protection: Wear clothing suited to the task being performed. Respiratory Protection: Not normally required if good ventilation is maintained. SECTION 9 PHYSICAL and CHEMICAL PROPERTIES BOILING POINT: 156F (69C) SPECIFIC GRAVITY (H2O=1): 1.3 VAPOR PRESSURE: 60-70 PERCENT VOLATILE BY VOL 100% VAPOR DENSITY (air=1): >1 EVAPORATION RATE (Butyl Acetate=1): ND SOLUBILITY IN WATER: 2.4g/L APPEARANCE & ODOR: Clear Colorless Liquid / Solvent pH: NA SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (material to avoid): Strong acids or oxidizing agents, HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and low molecular weight hydrocarbons may be produced. HAZARDOUS POLYMERIZATION: Will not occur SECTION 11 TOXICOLOGICAL INFORMATION Components Test Results: No Data Available Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. SECTION 12 ECOLOGICAL INFORMATION Components Information: No Data Available SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Dispose according to all applicable Federal, State, and Local regulations. SECTION 14 TRANSPORT INFORMATION DOT: Consumer Commodity, ORM-D. TDG: Consumer Commodity (Aerosols, UN1950, Class 2.1) SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations. CERCLA (Superfund) reportable quantity: None SARA (Superfund Amendments and Reauthorization Act of 1986): 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Section 302 extremely hazardous substance: No Section 311 hazardous chemical: No Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR. Page 259 of 1287 Page 259 of 1287 Page 259 of 1287 Page 259 of 1287 ---PAGE BREAK--- Zapp Product Code: C1629 Page 3 of 3 SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.) HMIS® ratings Health: 2 Flammability: 2 Physical hazard: 0 NFPA ratings Health: 2 Flammability: 2 Instability: 0 Other: NA-Not Applicable, ND-Not Determined, NE-Not Established. Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. PREPARED: 5/14/99 UPDATED: 6/14/13 PRODUCT C1629 Page 260 of 1287 Page 260 of 1287 Page 260 of 1287 Page 260 of 1287 ---PAGE BREAK--- ,1)275$& 0DWHULDO
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E\  Page 272 of 1287 Page 272 of 1287 Page 272 of 1287 Page 272 of 1287 ---PAGE BREAK--- Cat Coolant Conditioner Element T84746 Corrosion and Scale Inhibitor Material Safety Data Sheet Product name Material uses Code Validation date In case of emergency Product and company identification Prepared by Cat Coolant Conditioner Element : : : : : : 1. 05/24/2012. Atrion International Inc. Supplier/Manufacturer : Chem Tel: 1-[PHONE REDACTED] / 1-[PHONE REDACTED] Dober 11230 Katherine's Crossing Woodridge, IL 60517-5075 Dermal contact. Eye contact. Inhalation. Ingestion. Emergency overview Hazards identification Routes of entry Potential acute health effects Corrosive to eyes. Causes burns. Toxic if swallowed. Corrosive to the digestive tract. Causes burns. Corrosive to the skin. Causes burns. Eyes Skin Inhalation Ingestion Physical state Solid. [Tablet] : : : : : Odor : Mild. 2. Potential chronic health effects Signal word MAY BE FATAL IF INHALED. CAUSES RESPIRATORY TRACT, DIGESTIVE TRACT, EYE AND SKIN BURNS. HARMFUL IF SWALLOWED. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. SUSPECT CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER. POSSIBLE DEVELOPMENTAL HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE ADVERSE DEVELOPMENTAL EFFECTS, BASED ON ANIMAL DATA. REPRODUCTIVE HAZARD. CAN CAUSE HERITABLE GENETIC EFFECTS. Avoid exposure - obtain special instructions before use. Do not breathe dust. Do not ingest. Do not get in eyes or on skin or clothing. Avoid exposure during pregnancy. Use only with adequate ventilation. Keep container closed and sealed until ready for use. Wash thoroughly after handling. : DANGER! Hazard statements : Precautions : : Very toxic by inhalation. Corrosive to the respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Carcinogenicity : Can cause heritable genetic effects. No known significant effects or critical hazards. Contains material which may cause developmental abnormalities, based on animal data. Chronic effects : Can impair fertility. Contains material that may cause target organ damage, based on animal data. Mutagenicity : Teratogenicity : Contains material which may cause cancer. Risk of cancer depends on duration and level of exposure. Color : White to yellowish. OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Developmental effects : Fertility effects : 1/12 North America 05/24/2012. Page 273 of 1287 Page 273 of 1287 Page 273 of 1287 Page 273 of 1287 ---PAGE BREAK--- Cat Coolant Conditioner Element Hazards identification 2. Medical conditions aggravated by over- exposure Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. : Over-exposure Ingestion : Adverse may include the following: stomach pains reduced fetal weight increase in fetal deaths skeletal malformations Skin : Adverse may include the following: pain or irritation redness blistering may occur reduced fetal weight increase in fetal deaths skeletal malformations Eyes : Adverse may include the following: pain watering redness reduced fetal weight increase in fetal deaths skeletal malformations Inhalation : Target organs : Contains material which may cause damage to the following organs: blood, kidneys, lungs, the reproductive system, mucous membranes, gastrointestinal tract, cardiovascular system, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea, nose/sinuses. Adverse may include the following: respiratory tract irritation coughing sodium nitrite 7632-00-0 30-60 disodium trioxosilicate 6834-92-0 10-30 benzotriazole 95-14-7 5-10 disodium tetraborate, 1330-43-4 1-5 Sodium poly acrylate 9003-04-7 1-5 magnesium stearate 557-04-0 1-5 77-09-8 0.1-1 Composition/information on ingredients Name CAS number % sodium nitrite 7632-00-0 30-60 disodium trioxosilicate 6834-92-0 10-30 benzotriazole 95-14-7 5-10 disodium tetraborate, 1330-43-4 1-5 Sodium poly acrylate 9003-04-7 1-5 magnesium stearate 557-04-0 1-5 77-09-8 0.1-1 Name CAS number % United States Canada 3. Mexico 2/12 North America 05/24/2012. Page 274 of 1287 Page 274 of 1287 Page 274 of 1287 Page 274 of 1287 ---PAGE BREAK--- Cat Coolant Conditioner Element Composition/information on ingredients 3. Name CAS number % sodium nitrite 7632-00-0 UN1500 30-60 - 4 0 0 OX disodium trioxosilicate 6834-92-0 UN1759 10-30 - 3 0 1 benzotriazole 95-14-7 Not regulated. 5-10 - 2 1 0 Sodium poly acrylate 9003-04-7 Not regulated. 1-5 - 1 0 0 magnesium stearate 557-04-0 Not regulated. 1-5 - 1 0 0 disodium tetraborate, 1330-43-4 Not regulated. 1-5 - 0 0 0 IDLH H F R Special Classification UN number There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. First aid measures Eye contact Skin contact Ingestion In case of inhalation of decomposition products in a fire, may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Notes to physician : : : : 4. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Use an extinguishing agent suitable for the surrounding fire. Fire-fighting measures Extinguishing media isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. No specific fire or explosion hazard. 5. Special exposure hazards : None known. Suitable : Not suitable : Hazardous thermal decomposition products : Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides metal oxide/oxides Flammability of the product : 3/12 North America 05/24/2012. Page 275 of 1287 Page 275 of 1287 Page 275 of 1287 Page 275 of 1287 ---PAGE BREAK--- Cat Coolant Conditioner Element Fire-fighting measures 5. Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see section 1 for emergency contact information and section 13 for waste disposal. Environmental precautions Accidental release measures : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Personal precautions : Large spill : 6. Move containers from spill area. Avoid allowing the spilled material to get wet or using water to clean up spillages or residues, unless the quantity remaining is very small. Absorb with an inert material and place in an appropriate waste disposal container. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Small spill : Methods for cleaning up Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Put on appropriate personal protective equipment (see Section Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not get in eyes or on skin or clothing. Do not ingest. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Handling and storage Handling Storage : : 7. Exposure controls/personal protection United States 8. Ingredient Exposure limits 4/12 North America 05/24/2012. Page 276 of 1287 Page 276 of 1287 Page 276 of 1287 Page 276 of 1287 ---PAGE BREAK--- Cat Coolant Conditioner Element Exposure controls/personal protection 8. disodium tetraborate, ACGIH TLV (United States, 2/2010). STEL: 6 mg/m³ 15 minute(s). Form: Inhalable fraction TWA: 2 mg/m³ 8 hour(s). Form: Inhalable fraction NIOSH REL (United States, 6/2009). TWA: 1 mg/m³ 10 hour(s). OSHA PEL 1989 (United States, 3/1989). TWA: 10 mg/m³ 8 hour(s). magnesium stearate ACGIH TLV (United States, 2/2010). TWA: 10 mg/m³ 8 hour(s). Form: Total particulate mass Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Personal protection Eyes Respiratory Consult local authorities for acceptable exposure limits. : : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Hands : disodium tetraborate, NOM-010-STPS (Mexico, 9/2000). LMPE-PPT: 1 mg/m³ 8 hour(s). magnesium stearate ACGIH TLV (United States, 2/2010). TWA: 10 mg/m³ 8 hour(s). Form: Total particulate mass Canada Mexico Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking, using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Ingredient Exposure limits Occupational exposure limits Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations disodium tetraborate, US ACGIH 2/2010 - 2 - - 6 - - - - AB 4/2009 - 1 - 3 - - - - - BC 9/2010 - 2 - - 6 - - - - ON 7/2010 - 2 - - 6 - - - - QC 6/2008 - 1 - - - - - - - magnesium stearate US ACGIH 2/2010 - 10 - - - - - - - AB 4/2009 - 10 - - - - - - - BC 9/2010 - 10 - - - - - - - ON 7/2010 - 10 - - - - - - - TWA (8 hours) STEL (15 mins) Ceiling [3]Skin sensitization Form: [a]Inhalable fraction [b]Inhalable [c]Total particulate mass Occupational exposure limits 5/12 North America 05/24/2012. Page 277 of 1287 Page 277 of 1287 Page 277 of 1287 Page 277 of 1287 ---PAGE BREAK--- Cat Coolant Conditioner Element Exposure controls/personal protection 8. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Skin : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Not available. Solid. [Tablet] Not available. Not available. Not available. 55 lb/cu ft Not available. Not available. Partially soluble in the following materials: cold water and hot water. Not available. Not available. Mild. White to yellowish. Boiling/condensation point Melting/freezing point Not available. Not available. Physical and chemical properties Physical state pH Critical temperature Relative density Vapor pressure Vapor density Volatility Odor threshold Evaporation rate Viscosity Solubility Odor Color : : : : : : : : : : : : : : : Flash point : Not available. Not available. : Auto-ignition temperature Flammable limits : Not available. 9. LogKow : Not available. The product is stable. Under normal conditions of storage and use, hazardous decomposition products should not be produced. No specific data. Stability and reactivity Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products : : : : 10. Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactive or incompatible with the following materials: oxidizing materials, reducing materials, metals, acids and moisture. Under normal conditions of storage and use, hazardous polymerization will not occur. 6/12 North America 05/24/2012. Page 278 of 1287 Page 278 of 1287 Page 278 of 1287 Page 278 of 1287 ---PAGE BREAK--- Cat Coolant Conditioner Element Toxicological information 11. Acute toxicity sodium nitrite LC50 Inhalation Dusts and mists Rat 5.5 mg/m³ 4 hours LD50 Oral Rat 85 mg/kg - disodium trioxosilicate LD50 Oral Rat >1000 mg/kg - benzotriazole LD50 Oral Rat 560 mg/kg - disodium tetraborate, LD50 Oral Rat 1200 mg/kg - Sodium poly acrylate LD50 Oral Rat >8250 mg/kg - magnesium stearate LD50 Oral Rat >10000 mg/kg - Product/ingredient name Result Species Dose Exposure Chronic toxicity Not available. Carcinogenicity Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Classification disodium tetraborate, A4 - - - - - magnesium stearate A4 - - - - - - 2B - - Possible - Product/ingredient name ACGIH EPA NIOSH NTP IARC OSHA Irritation/Corrosion Product/ingredient name Result Score Exposure Observation sodium nitrite Eyes - Mild irritant Rabbit - 24 hours 500 milligrams - disodium trioxosilicate Skin - Moderate irritant Guinea pig - - - Skin - Severe irritant Human - - - Skin - Severe irritant Rabbit - - - benzotriazole Eyes - Severe irritant Rabbit - 100 milligrams - Sodium poly acrylate Eyes - Moderate irritant Rabbit - 2 milligrams - Sensitizer Not available. Species Ecological information Ecotoxicity : Water polluting material. May be harmful to the environment if released in large quantities. This material is very toxic to aquatic life. 12. Aquatic ecotoxicity Product/ingredient name Species Result Exposure 7/12 North America 05/24/2012. Page 279 of 1287 Page 279 of 1287 Page 279 of 1287 Page 279 of 1287 ---PAGE BREAK--- Cat Coolant Conditioner Element Ecological information 12. sodium nitrite Acute EC50 >100 mg/l Fresh water Algae 72 hours Acute EC50 15.4 mg/l Fresh water Daphnia 48 hours Acute LC50 0.54 mg/l Fresh water Fish 96 hours disodium trioxosilicate Acute EC50 207 mg/l Algae 72 hours Acute EC50 1700 mg/l Daphnia 48 hours Acute LC50 210 mg/l Fish 96 hours disodium tetraborate, Acute EC50 15.4 mg/L Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Acute LC50 104000 ug/L Fresh water Fish - Gambusia affinis - Adult 96 hours Acute EC50 8.9 mg/l Algae 72 hours Acute EC50 >100 mg/l Daphnia 48 hours Persistence/degradability OECD 301F Ready Biodegradability - Manometric Respirometry Test 76 % - Readily - 28 days - - Product/ingredient name Test Dose Result Inoculum The generation of waste should be avoided or minimized wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal Disposal considerations Disposal should be in accordance with applicable regional, national and local laws and regulations. : 13. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Transport information 8 (6.1) Limited quantity Yes. Packaging instruction Passenger aircraft Quantity limitation: 25 kg Cargo aircraft Quantity limitation: 100 kg Special provisions IB8, IP3, T1 DOT Classification Corrosive solids, toxic, n.o.s. (disodium trioxosilicate, sodium nitrite) III Regulatory information UN number Proper shipping name Classes PG* Label Additional information UN2923 14. 8/12 North America 05/24/2012. Page 280 of 1287 Page 280 of 1287 Page 280 of 1287 Page 280 of 1287 ---PAGE BREAK--- Cat Coolant Conditioner Element Transport information 14. TDG Classification 8 (6.1) UN2923 CORROSIVE SOLID, TOXIC, N.O.S. (disodium trioxosilicate, sodium nitrite) III IMDG Class CORROSIVE SOLID, TOXIC, N.O.S. (disodium trioxosilicate, sodium nitrite). Marine pollutant (sodium nitrite) 8 (6.1) III Corrosive solid, toxic, n.o.s. (disodium trioxosilicate, sodium nitrite). Marine pollutant (sodium nitrite) UN2923 IATA-DGR Class 8 (6.1) III UN2923 Emergency schedules (EmS) F-A, S-B Passenger and Cargo AircraftQuantity limitation: 25 kg Packaging instructions: 860 Cargo Aircraft OnlyQuantity limitation: 100 kg Packaging instructions: 864 Limited Quantities - Passenger AircraftQuantity limitation: 5 kg Packaging instructions: Y845 Explosive Limit and Limited Quantity Index 2 Passenger Carrying Road or Rail Index 25 Special provisions 16 Mexico Classification UN2923 SOLIDO CORROSIVO, TOXICO, N.E.P. (disodium trioxosilicate, sodium nitrite) 8 (6.1) III Special provisions 223, 274 PG* : Packing group Highly toxic material Corrosive material Carcinogen Target organ effects HCS Classification Regulatory information U.S. Federal regulations TSCA 5(a)2 final significant new use rules: sodium nitrite TSCA 8(a) IUR: Not determined United States inventory (TSCA 8b): All components are listed or exempted. TSCA 8(d) H and S data reporting: sodium nitrite TSCA 12(b) annual export notification: sodium nitrite : : United States 15. 9/12 North America 05/24/2012. Page 281 of 1287 Page 281 of 1287 Page 281 of 1287 Page 281 of 1287 ---PAGE BREAK--- Cat Coolant Conditioner Element Regulatory information 15. The following components are listed: SODIUM NITRITE; 1H-BENZOTRIAZOLE; BORON SODIUM OXIDE WARNING: This product contains a chemical known to the State of California to cause cancer. WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm. Clean Water Act (CWA) 311: sodium nitrite Clean Air Act (CAA) 112 accidental release prevention: No products were found. Massachusetts SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: sodium nitrite; disodium trioxosilicate; benzotriazole; disodium tetraborate, SARA 311/312 MSDS distribution - chemical inventory - hazard identification: sodium nitrite: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; disodium trioxosilicate: Immediate (acute) health hazard, Delayed (chronic) health hazard; benzotriazole: Immediate (acute) health hazard; disodium tetraborate, Immediate (acute) health hazard : Product name CAS number Concentration SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. Yes. No. No. No. ethylene oxide Yes. Yes. Yes. Yes. Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level Form R - Reporting requirements Supplier notification California Prop. 65 Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) : Not listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Not listed New York : The following components are listed: Sodium nitrite New Jersey : The following components are listed: SODIUM NITRITE; NITROUS ACID, SODIUM SALT; BORATE COMPOUNDS, Inorganic; 1(3H)- ISOBENZOFURANONE, 3,3-BIS(4-HYDROXYPHENYL)- : The following components are listed: NITROUS ACID, SODIUM SALT; BORON SODIUM OXIDE (B4NA2O7) State regulations sodium nitrite 7632-00-0 30-60 77-09-8 0.1-1 sodium nitrite 7632-00-0 30-60 77-09-8 0.1-1 10/12 North America 05/24/2012. Page 282 of 1287 Page 282 of 1287 Page 282 of 1287 Page 282 of 1287 ---PAGE BREAK--- Cat Coolant Conditioner Element Regulatory information 15. The following components are listed: Sodium nitrite Australia inventory (AICS): Not determined. China inventory (IECSC): Not determined. Japan inventory: Not determined. Korea inventory: Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. WHMIS (Canada) Class D-1A: Material causing immediate and serious toxic effects (Very toxic). Class D-2A: Material causing other toxic effects (Very toxic). Class E: Corrosive material International regulations International lists : : Canada Mexico 0 4 0 Health Flammability Reactivity Special Classification : This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Canadian NPRI : Canada inventory : Not determined. Chemical Weapons Convention List Schedule I Chemicals : Not listed Chemical Weapons Convention List Schedule II Chemicals : Not listed Chemical Weapons Convention List Schedule III Chemicals : Not listed CEPA Toxic substances : None of the components are listed. Canadian lists Other information Hazardous Material Information System Label requirements : : 16. MAY BE FATAL IF INHALED. CAUSES RESPIRATORY TRACT, DIGESTIVE TRACT, EYE AND SKIN BURNS. HARMFUL IF SWALLOWED. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. SUSPECT CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER. POSSIBLE DEVELOPMENTAL HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE ADVERSE DEVELOPMENTAL EFFECTS, BASED ON ANIMAL DATA. REPRODUCTIVE HAZARD. CAN CAUSE HERITABLE GENETIC EFFECTS. Health Flammability Physical hazards 0 * 4 0 11/12 North America 05/24/2012. Page 283 of 1287 Page 283 of 1287 Page 283 of 1287 Page 283 of 1287 ---PAGE BREAK--- Cat Coolant Conditioner Element Other information 16. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue Date of previous issue Version : : : Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Indicates information that has changed from previously issued version. 05/24/2012. No previous validation. 1 Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. National Fire Protection Association : 0 0 4 Health Special Instability Flammability 12/12 North America 05/24/2012. Page 284 of 1287 Page 284 of 1287 Page 284 of 1287 Page 284 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Total Solutions P.O. Box 240014 Milwaukee, WI 53224 GENERAL INFORMATION NUMBER: (414) 354-6417 REVISION DATE: August 13, 2014 CHEMTREC: (800) 424-9300 DATE OF ISSUE: August 13, 2014 I - Product Identification Citra Clean PRODUCT CODE: 0440 CHEMICAL FORMULATION: Citrus based grit hand cleanser NFPA HAZARD IDENTIFICATION SYSTEM: HEALTH: 0 FLAMMABILITY: 1 REACTIVITY: 0 HAZARD RATING: 4 - Extreme; 3 - High; 2 - Moderate; 1 - Slight; 0 - Insignificant II - Hazardous Ingredients Values reported as TWA unless noted. SUBSTANCE APPROX % OSHA PEL ACGIH TLV EPA 40 CFR: CAS # 302 355 372 d-Limonene 1.0 - 10.0 N/E N/E N N N 5989-27-5 Linear Alcohol Ethoxylate 1.0 - 5.0 N/E N/E N N N 34398-01-1 Key: PEL: Permissible Exposure Limit TLV: Threshold Limit Value C: Ceiling level STEL: Short Term Exposure Limit N/A: Not Applicable N/D: Not Determined N/E: Not Established Y: Yes N: No 302: CERCLA List of Hazardous Substances and Reportable Quantities (40 CFR 302.4). 355: SARA TITLE III / List of Extremely Hazardous Substances for Emergency Planning and Notification (40 CFR 355). 372: SARA TITLE III / List of Toxic Chemicals subject to Release Reporting (Community Right to Know) (40 CFR 372). III - Physical Data BOILING POINT N/D SPECIFIC GRAVITY (WATER = 0.998 VAPOR PRESSURE (mm Hg): N/D VOC CONTENT by weight): < 1.0 VAPOR DENSITY (AIR = N/D EVAPORATION RATE (WATER = N/D SOLUBILITY IN WATER: Miscible pH: 6.5 – 7.5 APPEARANCE AND ODOR: Orange, opaque liquid; citrus fragrance. IV - Fire and Explosion Hazard Data FLASH POINT > 200 (TEST METHOD): Closed cup FLAMMABLE LIMITS IN AIR (VOLUME UPPER: N/E LOWER: N/E EXTINGUISHING MEDIA: Foam, carbon dioxide, dry chemical. SPECIAL FIRE FIGHTING PROCEDURES: Firefighters should be equipped with self-contained breathing apparatus and protective clothing. Use water spray to cool fire-exposed containers. UNUSUAL FIRE AND EXPLOSION HAZARD: None. Page 285 of 1287 Page 285 of 1287 Page 285 of 1287 Page 285 of 1287 ---PAGE BREAK--- PRODUCT NAME: Citra Clean PRODUCT CODE: 0440 V - Reactivity Data STABILITY: Stable INCOMPATIBILITY: Strong acids and oxidizing agents. CONDITIONS TO AVOID: None HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may produce oxides of carbons. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: None VI - Health Hazard Data ROUTES OF ENTRY INHALATION: EYE CONTACT: X SKIN CONTACT: X INGESTION: X INGREDIENTS THAT ARE CONSIDERED BY OSHA, NTP, IARC TO BE SUSPECTED HUMAN CARCINOGENS: None. EFFECTS OF OVEREXPOSURE IF IN EYES: Moderate irritation, redness, and tearing. IF ON SKIN: Irritation with repeated or prolonged contact. Contains a possible sensitizer. IF SWALLOWED: Gastrointestinal irritation, nausea, vomiting, and diarrhea. IF INHALED: No hazards under normal use. EMERGENCY AND FIRST AID PROCEDURES IF IN EYES: Flush eyes and under eyelids with plenty of cool water for at least 15 minutes. If irritation persists, obtain medical attention. IF ON SKIN: Wash with water. IF SWALLOWED: Contact physician or poison control center immediately. Do not induce vomiting. Never give anything to an unconscious person. IF INHALED: Remove person to fresh air. VII - Spill or Leak Protection STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Ventilate area and extinguish all sources of ingestion. Soak up on inert absorbent and place in closed container for disposal. WASTE DISPOSAL METHOD: Consult local environmental authorities. VIII - Special Protection Information RESPIRATORY PROTECTION: Use with adequate ventilation. VENTILATION LOCAL: Not required MECHANICAL: Not required PROTECTIVE GLOVES: None. EYE PROTECTION: None. OTHER PROTECTIVE EQUIPMENT: None. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in a cool, dry place, away from heat or open flame. Wash hands thoroughly after handling. Keep container closed when not in use. OTHER PRECAUTIONS: Keep out of reach of children. IX - Transportation Information (ground transportation only) DOT ID NUMBER: None DOT PROPER SHIPPING NAME: None DOT CLASS: None DOT PACKING GROUP: None The shipping information listed above applies only to non-bulk 119 gallons) containers of this product. This product may have more than one proper shipping name depending on packaging, product properties, & mode of shipment. If any alteration of packaging, product, or mode of transportation is further intended, different shipping names and labeling may apply. REVISION DATE: August 13, 2014 Prepared by: Technical Dept. DATE OF ISSUE: August 13, 2014 This information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Total Solutions assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material. Such vendees or users assume all risks associated with the use of this material. Page 286 of 1287 Page 286 of 1287 Page 286 of 1287 Page 286 of 1287 ---PAGE BREAK--- N535 Page 1 of 2 5332 Dansher Road Illinois 60525 MATERIAL SAFETY DATA SHEET Revision Date: 12/17/2012 MSDS No. N535 Supersedes Date: 8/15/2012 Emergency Phones: [PHONE REDACTED] (NYCO) [PHONE REDACTED] (CHEMTREC) PLEASE NOTE: This MSDS is being provided to your company for the purpose of providing current health and safety information to your management and for your employees who work with this material. Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT-TO-KNOW regulations. Also make this information available to any employee who requests it. It is your obligation to comply with these regulations. SECTION I - PRODUCT IDENTITY PRODUCT NAME: Citra-Blaze 535 Cleaner Degreaser Formula: Mixture of terpene solvent, detergent, alkaline builders and water. Chemical Type: As above HMIS RATINGS Health = 1 (Slight) Flammability = 2 (Moderate) Reactivity = 0 (Minimal) Protection = B (Goggles and gloves) SECTION II - HAZARDOUS INGREDIENTS CARCINOGEN PERCENT TLV (OSHA,TP,IARC) None no SECTION III - CHEMICAL AND PHYSICAL Appearance: Orange Liquid Boiling Point: 210OF. Odor: Orange Melting Point: N/A pH: 11.0-11.8 Spec. Gravity (H20 = 1.01 Water Solubility: Complete Vapor Pressure (Mm Hg): N/A Viscosity @ 25oC: < 25 cps (Brookfield) VOC Content: 1.2% SECTION IV - FIRE AND EXPLOSION HAZARDS Flash Point (Method): 133oF. TCC Explosion Limits: Upper: 7 Lower: 1 Extinguishing Media: Water fog, CO2, halon system, foam for alcohols Special Firefighting Procedures and Hazards: Treat as a combustible liquid fire. May be ignited by heat, sparks, flame or other sources of ignition. Minimize prolonged skin and eye contact. Wear breathing, skin and eye protection if exposure is likely. SECTION V - REACTIVITY INFORMATION Stable: Unstable: Precautions: Incompatibility: Oxidizing agents. Hazardous Decomposition Products: If in a fire: CO, CO2, hydrocarbons. Hazardous Polymerization: Occurs: Does Not Occur: Page 287 of 1287 Page 287 of 1287 Page 287 of 1287 Page 287 of 1287 ---PAGE BREAK--- N535 Page 2 of 2 SECTION VI - HEALTH HAZARDS - PROTECTIVE MEASURES - FIRST AID Inhalation: Breathing of mists or vapor causes irritation. Wear approved organic mist respirator if necessary. Provide ventilation in confined spaces. Remove to fresh air. Give artificial respiration or oxygen if needed. Skin: Extended contact may cause irritation and defatting. Wear protective gloves. Flush skin thoroughly with water for 15 minutes. Remove contaminated clothing and wash before wearing again. Eyes: May cause irritation from misting. Flush with water for 15 minutes. If irritation persists consult a doctor. Ingestion: May cause mild gastric disturbances or nausea. Avoid swallowing. Drink lots of water or milk. Do not induce vomiting. If irritation persists get medical attention. Most likely routes of entry: Skin, Eyes. Other Important Medical or Precautionary Information: None SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE Spills and Leaks: Small spills can be flushed into normal drainage or into ground with copious amounts of water, or taken up with absorbent material. Do not drain to sewer without dilution. Larger spills should be contained by diking or other methods and held for disposal or reuse. Storage and Handling: Keep away from heat, sparks and open flames. Check daily for any container leaks. Waste Disposal: May be disposable in sewers if local regulations permit. Otherwise, send to licensed treatment and disposal facility for handling and disposal. Observe label precautions. Empty Containers: Rinse well before handling and disposal. Observe label precautions. Other Precautions: N/A SECTION VIII - REGULATORY INFORMATION Reportable for SARA Title III, S.313 (Form None The information herein has been compiled from sources believed to be reliable and is accurate to the best of our knowledge. However, Nyco Products cannot give any guarantees regarding information from other sources, and expressly does not make any warranties, nor assumes any liability, for its use. Page 288 of 1287 Page 288 of 1287 Page 288 of 1287 Page 288 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET GHS SDS F057 Page 1 of 5 CITRA-SCRUB with SCRUBBERS SECTION 1 – PRODUCT AND COMPANY IDENTIFICATION Product Name : CITRA-SCRUB with SCRUBBERS Product Codes : 5707, 5728, 5753, 5767, 5768 Recommended use : Industrial hand cleaner Product dilution information : Product is sold ready to use. Company : Kutol Products Company 100 Partnership Way Sharonville, Ohio 45241-1571 1-[PHONE REDACTED] Chemtrec Phone : 1-[PHONE REDACTED] Issuing date : 12/10/2014 SECTION 2 – HAZARD(S) IDENTIFICATION GHS Classification : Category 2B Eye irritation GHS Label Element Hazards pictograms : Signal Word : Warning Hazard Statements : Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do so. Continue rinsing. If eye irritation persists: Get medical advice/attention. Other Hazards : None known. SECTION 3 – COMPOSITION / INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration MINERAL SEAL OIL 64742-46-7 5-10 DIPENTENE (D-LIMONENE) 138-86-3 5-10 PROPYLENE GLYCOL 57-55-6 1-5 MINERAL OIL 7 8042-47-5 1-5 COCAMIDE DEA 68603-42-9 1-5 POLYETHYLENE 9002-88-4 1-5 PHENOXYETHANOL 122-99-6 1-5 ACRYSOL 37325-11-4 1-5 TETRASODIUM EDTA 13235-36-4 1-5 TRIETHANOLAMINE 102-71-6 1-5 Page 289 of 1287 Page 289 of 1287 Page 289 of 1287 Page 289 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET GHS SDS F057 Page 2 of 5 CITRA-SCRUB with SCRUBBERS SECTION 4 – FIRST AID MEASURES In case of eye contact : Flush eyes under eyelids with plenty of cool water for at least 15 minutes. If irritation persists, seek medical/advice attention. In case of skin contact : If irritation persists, wash with water. If ingested : Contact a physician or Poison Control Center immediately. Do not induce vomiting never give anything by mouth to an unconscious person. If inhaled : Get medical attention if occur. Protection of first-aiders : No special precautions are necessary. Notes to physicians : Treat SECTION 5 – FIRE-FIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media : None known. Specific hazards during firefighting : No flammable or combustible. Hazardous combustions products : Carbon oxides Special protective equipment for fire-fighters : Use personal protective equipment. Specific extinguishing methods : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. SECTION 6 – ACCIDENTAL RELEASE MEASURES Personal precautions : No special measures required. Environmental precautions : Avoid contact of large amounts of spilled material runoff with soil and surface waterways. Methods of cleaning up : Absorb with inert material. Use a water rinse for final clean-up. SECTION 7 – HANDLING AND STORAGE Handling : Wash hands after handling. Storage : Keep out of reach of children. Keep container closed. Store between 32 to 122 degrees F. SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION Ingredients with workplace control parameters. Ingredients CAS-No. Form of exposure Permissible Concentration Basis MINERAL SEAL OIL 64742-46-7 TWA 5 mg/m3 ACGIH MINERAL SEAL OIL 64742-46-7 TWA 5 mg/m3 OSHA PEL MINERAL SEAL OIL 64742-46-7 TWA 5 mg/m3 NIOSH REL D-LIMONENE 138-86-3 TWA 30 ppm AIHA PROPYLENE GLYCOL 57-55-6 TWA 10 mg/m WEEL Page 290 of 1287 Page 290 of 1287 Page 290 of 1287 Page 290 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET GHS SDS F057 Page 3 of 5 CITRA-SCRUB with SCRUBBERS Engineering measures : Good general ventilation should be sufficient to control workers exposure to airborne contamination. Personal protection Eyes : Eye protection should be used when splashing may occur. Hands : No protective equipment is needed under normal use. Skin : No protective equipment is needed under normal use. Respiratory : No protective equipment is needed under normal use. Consult local authorities for acceptable exposure limits. SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES Appearance: Viscous orange liquid Upper/lower flammability limits: N/A Odor: Citrus fragrance Vapor pressure: N/A Odor Threshold: No data available Vapor density: N/A ph: 6.0 typical Relative density: No data available. Melting point/freezing point: N/A Solubility (ies): No data available. Initial boiling and boiling range: N/A Partition coefficient: n-octanol/water: No data available. Flash point: N/A Auto ignition temperature: N/A Evaporation rate: <1 Decomposition temperature: No data available. Flammability (solid, gas): No data available Viscosity: 50,000 CPS @ 77F; 25C SECTION 10 – STABILITY AND REACTIVITY Stability : The product is stable under normal conditions. Possibility of hazardous reactions : No dangerous reaction is known under conditions of normal use. Conditions to avoid : None known. Incompatible materials : None known. Hazardous decomposition products : Carbon oxides SECTION 11 – TOXICOLOGICAL INFORMATION Information on likely routines of exposure : Inhalation, eye contact, skin contact. Potential Health Effects Eyes : Cause of irritation. Skin : Health injuries are not known or expected under normal use. Ingestion : Health injuries are not known or expected under normal use. Inhalation : Health injuries are not known or expected under normal use. Chronic exposure : Health injuries are not known or expected under normal use. Experience with Human Exposure Eye contact : Redness, irritation. Skin contact : No known or expected. Ingestion : No known or expected. Inhalation : No known or expected. Page 291 of 1287 Page 291 of 1287 Page 291 of 1287 Page 291 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET GHS SDS F057 Page 4 of 5 CITRA-SCRUB with SCRUBBERS Toxicity Acute oral toxicity : Acute toxicity estimate: >5,000 mg/kg Acute inhalation toxicity : No data available Acute dermal toxicity : Acute toxicity estimate: >5,000 mg/kg Skin corrosion/irritation : No data available Serious eye damage/eye irritation : Mild eye irritation. Respiratory or skin sensitization : No data available. Carcinogenicity IARC : No component of this product present at levels greater than or equal to 0.1% is identified as a probable, possible or confirmed human carcinogen by IARC. OSHA : No ingredient of this product presents at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP : No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 12 – ECOLOGICAL INFORMATION Ecological Tests : Data is not available. Environmental Impact : The product ingredients are expected to be safe for the environment at the concentrations predicted under normal use and accidental spill scenarios. Packaging components are compatible with the conventional solid waste management practices. SECTION 13 – DISPOSAL CONSIDERATIONS Disposal methods : The product should not be allowed to enter drains, water courses or the soil. When possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. SECTION 14 – TRANSPORT INFORMATION Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. The shipper / consignor / sender are responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Shipment Identification Number Proper Shipping Name Hazardous Classification Packaging Group US DOT Not dangerous goods N/A N/A None Page 292 of 1287 Page 292 of 1287 Page 292 of 1287 Page 292 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET GHS SDS F057 Page 5 of 5 CITRA-SCRUB with SCRUBBERS IATA (Air) Not dangerous goods N/A N/A None SECTION 15 – REGULATORY INFORMATION U.S. Federal regulations TSCA 8(b) Inventory : All components are listed or exempted. SARA 302/304/311/312 Extremely Hazardous Substances : No listed substance. SARA 302/304 Emergency Planning and Notification : No listed substance. SECTION 16 - OTHER INFORMATION NFPA 704: HMIS III: HEALTH 1 FLAMMABILITY 0 PHYSICAL HAZARDS 0 Issuing date : 12/10/2014 Version : 1.0 Prepared by : Regulatory Compliance The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in conjunction with any other materials or in any process, unless specified in the text. Page 293 of 1287 Page 293 of 1287 Page 293 of 1287 Page 293 of 1287 ---PAGE BREAK--- UNELKO CORPORATION 14641 N. 74th St. Scottsdale, AZ 85260 FAX: (480) 483-7674 Information & Emergency Phone: (480) 991-7272 IN CASE OF TRANSPORTATION EMERGENCY & AFTER HOURS, CONTACT CHEM-TEL, INC. 1-[PHONE REDACTED] MATERIAL SAFETY DATA SHEET PRODUCT INFORMATION TRADE NAME: ELIMINATE® GROUT CLEANER AND SEALER PRODUCT DESCRIPTION: Shower Tub & Tile Cleaner DOT: CONSUMER COMMMODITY, ORM-D (In Containers 32 Fl. Oz. & Under) COMPOUND CLEANING LIQUID, UN/NA 1993 Packing Group II (Containers Over 32 Fl. Oz.) NFPA: HEALTH HAZARD - Hazardous); FLAMMABILITY - 2 ; REACTIVITY - 0 (Stable) CAS NUMBER: PROPRIETARY RCRA HAZARD CLASS:(IF DISCARDED) D001, D002 EPA PRIORITY POLLUTANTS NONE SARA TITLE III (Sec. 313) HAZARDOUS MATERIAL NONE (As determined by the National Toxicology Program [NTP], the International Agency for Research on Cancer [IARC}, or by the Occupational Safety and Health Administration [OSHA]. HAZARDOUS INGREDIENTS MATERIAL or COMPONENT CAS # TLV (UNITS) PEL(TWA) WT % Triethanolamine 102-71-6 0.5ppm TWA 0.1% - 1.0% Diethanolamine 111-42-2 3ppm TWA 3ppm TWA 0.1% - 1.0% Ethylene Glycolmonobutylether 111-76-2 20ppm 25ppm (skin) 1.0% - 5.0% NON-HAZARDOUS INGREDIENTS Glycolic Acid 79-14-1 None established 2.0% - 8.0% Sodium Xylene Sulfonate 1300-72-7 None established 0.1% - 5.0% Cocoamidopropylbetaine 61789-39-7 None established 0.1% - 1.0% Water - - 80% - 95% Fragrance Proprietary - 0.01% - 1.0% 100% (As established by the American Conference of Governmental Industrial Hygienists and/or Standards Promulgated by the Occupational Safety and Health Administration PHYSICAL DATA BOILING POINT, oF 100° C (as water) VAPOR PRESSURE, @ 20oC (mm Hg) Not determined VOLATILES @ BY VOLUME 83% pH 3.4 APPEARANCE @ 25oC Light Amber ODOR Cherry VAPOR DENSITY, (AIR=1) Heavier than air SPECIFIC GRAVITY @ 25oC 1.05 EVAPORATION RATE (BUTYL ACETATE = 1) >1 FREEZE POINT N/A SOLUBILITY IN WATER @ 25oC Complete FIRE AND EXPLOSION HAZARD DATA FLASH POINT: Not determined Page 294 of 1287 Page 294 of 1287 Page 294 of 1287 Page 294 of 1287 ---PAGE BREAK--- FLAMMABLE LIMITS IN AIR, BY VOLUME: LOWER: Undetermined UPPER: Undetermined EXTINGUISHING MEDIA: N/A SPECIAL FIRE FIGHTING PROCEDURES: Use self-contained breathing apparatus and protective clothing. UNUSUAL FIRE & EXPLOSION HAZARDS: None. May form oxides of nitrogen or sulfur on combustion. HEALTH HAZARD DATA THRESHOLD LIMIT VALUE: See HAZARDOUS INGREDIENTS section. EFFECTS OF OVEREXPOSURE: Contact with eyes will cause irritation. Prolonged contact with skin may cause drying. Excessive inhalation of vapors can cause nasal irritation, dizziness, weakness, nausea, headache and a narcotic reaction. If swallowed, may cause stomach cramps, nausea,vomiting and/or diarrhea. EMERGENCY AND FIRST AID PROCEDURES: For eye contact, flush with copious amounts of water. For prolonged skin contact, wash with soap and water and apply skin cream/lubricating ointment. For inhalation, remove to fresh air. If swallowed, drink milk, raw egg white, mucilage, milk of magnesia, or gelatin solution. If these are not available, drink large quantities of water. For any emergency, obtain medical attention. REACTIVITY DATA STABILITY: Stable Unstable ( ) INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizing materials, & bases. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition or burning may produce carbon mono/dioxides and/or oxides of nitrogen and sulfur. HAZARDOUS POLYMERIZATION: May Occur ( ) Will Not Occur CONDITIONS TO AVOID: Excess heat, sparks, flames. SPILL, LEAK AND DISPOSAL PROCEDURES ACTION TO TAKE FOR LEAKS OR SPILLS: (Use appropriate safety equipment). Use absorbent material to collect and contain for disposal. Contain large spills and pump into a suitable tank or vessel. Wash area with detergent solution and rinse thoroughly with water. DISPOSAL METHOD: All local, state and federal regulations concerning health and pollution should be reviewed to determine approved disposal procedures. SPECIAL HANDLING INFORMATION VENTILATION: Provide sufficient ambient or mechanical exhaust ventilation to maintain exposure below TLV. Provide self-contained breathing apparatus when handling drum quantities in an enclosed room. PROTECTIVE CLOTHING: Clean, body-covering clothing. For drum quantities, rubber gloves, boots and apron depending upon the likely exposure or as required by company regulations. EYE PROTECTION: When working with drum or bulk quantities, chemical workers' goggles are recommended. When transferring drum or bulk quantities, a full face shield is recommended. OTHER PROTECTIVE EQUIPMENT: When handling or transferring large quantities of open or bulk material in an enclosed room, eye fountain and safety shower should be available when handling or transferring large quantities of open or bulk material. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Store in well ventilated areas at temperatures below 120oF and away from ignition source. Since emptied containers may retain product residues (vapor, liquid and/or solid), all hazard precautions given in this data sheet must be observed. This data is furnished gratuitously in keeping with prevailing regulations and is independent of any sales of the product. Unelko Corporation urges each customer or recipient of this MSDS to become aware of and understand the hazards associated with the product. The reader should consult references or experts in ventilation, toxicity and fire prevention as necessary to understand and use the data contained herein. While the information is believed to be correct, Unelko Corporation accepts no responsibility for any damages resulting from the publication, use or reliance upon the data contained herein without independent verification. Since the use of this information and the conditions of the use of the product are not within the control of Unelko Corporation, it is the user's obligation to determine and observe the conditions of safe use of the product. Last Revised 07/02/12 BL Page 295 of 1287 Page 295 of 1287 Page 295 of 1287 Page 295 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET Issuing Date January 5, 2015 Revision Date New Revision Number 0 Page 1 / 9 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Clorox® Bleach Wipes Other means of identification EPA Registration Number 67619-12-5813 Recommended use of the chemical and restrictions on use Recommended use Moistened disinfecting bleach wipes Uses advised against No information available Details of the supplier of the safety data sheet Supplier Address The Clorox Company 1221 Broadway Oakland, CA 94612 Phone: 1-[PHONE REDACTED] Emergency telephone number Emergency Phone Numbers For Medical Emergencies call: 1-[PHONE REDACTED] For Transportation Emergencies, call Chemtrec: 1-[PHONE REDACTED] Page 296 of 1287 Page 296 of 1287 Page 296 of 1287 Page 296 of 1287 ---PAGE BREAK--- Clorox® Bleach Wipes Revision Date New Page 2 / 9 2. HAZARDS IDENTIFICATION Classification This product is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). GHS Label elements, including precautionary statements Emergency Overview This product is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Appearance Clear, colorless liquid absorbed into white, non-woven wipes Physical State Thin liquid absorbed into non-woven wipes Odor Fruity, floral, bleach Precautionary Statements - Prevention None Precautionary Statements - Response None Precautionary Statements - Storage None Precautionary Statements - Disposal None Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity 21.8% of the mixture consists of ingredient(s) of unknown toxicity Other information No information available Interactions with Other Chemicals Reacts with other chemicals such as ammonia, toilet bowl cleaners, rust removers or acids to produce hazardous gases, such as chlorine and other chlorinated compounds. 3. COMPOSITION/INFORMATION ON INGREDIENTS This product contains no substances that at their given concentrations are considered to be hazardous to health. Page 297 of 1287 Page 297 of 1287 Page 297 of 1287 Page 297 of 1287 ---PAGE BREAK--- Clorox® Bleach Wipes Revision Date New Page 3 / 9 4. FIRST AID MEASURES First aid measures General Advice Show this safety data sheet to the doctor in attendance. Eye Contact Hold eye open and rinse slowly and gently with water for 15 - 20 minutes. If present, remove contact lenses after the first 5 minutes of rinsing, then continue rinsing eye. Call a poison control center or doctor for further treatment advice. Skin Contact Rinse skin with plenty of water. If irritation persists, call a doctor. Inhalation Move to fresh air. If breathing problems develop, call a doctor. Ingestion Drink a glassful of water. Call a doctor or poison control center. Most important and effects, both acute and delayed Most Important and Effects Liquid may cause eye irritation. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical Hazardous Combustion Products Oxides of carbon. Explosion Data Sensitivity to Mechanical Impact No. Sensitivity to Static Discharge No. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 298 of 1287 Page 298 of 1287 Page 298 of 1287 Page 298 of 1287 ---PAGE BREAK--- Clorox® Bleach Wipes Revision Date New Page 4 / 9 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Avoid contact with eyes. Other Information Refer to protective measures listed in Sections 7 and 8. Environmental precautions Environmental Precautions See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed-down material. 7. HANDLING AND STORAGE Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes, skin, and clothing. Do not eat, drink, or smoke when using this product. Conditions for safe storage, including any incompatibilities Storage Keep containers closed in a dry, cool, and well-ventilated place. Incompatible Products Ammonia, toilet bowl cleaners, rust removers, and acids. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines This product does not contain any ingredients with occupational exposure limits that are at concentrations below their cut-off values/concentrations and that contribute to the hazard classification of the product. Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection No special protective equipment required. Skin and Body Protection No special protective equipment required. Respiratory Protection No protective equipment is needed under normal use conditions. If irritation is experienced, ventilation and evacuation may be required. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Page 299 of 1287 Page 299 of 1287 Page 299 of 1287 Page 299 of 1287 ---PAGE BREAK--- Clorox® Bleach Wipes Revision Date New Page 5 / 9 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Physical State Thin liquid absorbed into non-woven wipes Appearance Clear liquid absorbed into non-woven wipes Odor Fruity, floral, bleach Color Colorless liquid - white non-woven wipes Odor Threshold No information available Property Values Remarks/ Method pH 12 - 12.5 (liquid) None known Melting/freezing point No data available None known Boiling point / boiling range No data available None known Flash Point No data available None known Evaporation rate No data available None known Flammability (solid, gas) No data available None known Flammability Limits in Air Upper flammability limit No data available None known Lower flammability limit No data available None known Vapor pressure No data available None known Vapor density No data available None known Specific Gravity ~1.0 (liquid) None known Water Solubility Complete (liquid) None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/water No data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known Explosive Properties Not explosive Oxidizing Properties No data available Other Information Softening Point No data available VOC Content No data available Particle Size No data available Particle Size Distribution No data available Page 300 of 1287 Page 300 of 1287 Page 300 of 1287 Page 300 of 1287 ---PAGE BREAK--- Clorox® Bleach Wipes Revision Date New Page 6 / 9 10. STABILITY AND REACTIVITY Reactivity Reacts with other chemicals such as ammonia, toilet bowl cleaners, rust removers or acids to produce hazardous gases, such as chlorine and other chlorinated compounds. Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid None known based on information supplied. Incompatible materials Ammonia, toilet bowl cleaners, rust removers, and acids. Hazardous Decomposition Products None known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information . Inhalation Exposure to vapor or mist may irritate respiratory tract. Eye Contact Liquid may cause irritation. Skin Contact Liquid may cause slight irritation. Ingestion Ingestion of liquid may cause slight irritation to mucous membranes and gastrointestinal tract. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Sodium hypochlorite 7681-52-9 8200 mg/kg (Rat) >10000 mg/kg (Rabbit) - Information on toxicological effects Liquid may cause redness and tearing of eyes. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Mutagenic Effects No information available. Page 301 of 1287 Page 301 of 1287 Page 301 of 1287 Page 301 of 1287 ---PAGE BREAK--- Clorox® Bleach Wipes Revision Date New Page 7 / 9 Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA Sodium hypochlorite 7681-52-9 - Group 3 - - IARC (International Agency for Research on Cancer) Group 3 - Not Classifiable as to Carcinogenicity in Humans Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Chronic Toxicity No known effect based on information supplied. Target Organ Effects Respiratory system, eyes, skin, gastrointestinal tract (GI). Aspiration Hazard No information available. Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS document No information available. 12. ECOLOGICAL INFORMATION Ecotoxicity No information available. Persistence and Degradability No information available. Bioaccumulation No information available. Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Disposal methods Dispose of in accordance with all applicable federal, state, and local regulations. Contaminated Packaging Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local regulations. 14. TRANSPORT INFORMATION DOT Not regulated. TDG Not regulated. ICAO Not regulated. IATA Not regulated IMDG/IMO Not regulated Page 302 of 1287 Page 302 of 1287 Page 302 of 1287 Page 302 of 1287 ---PAGE BREAK--- Clorox® Bleach Wipes Revision Date New Page 8 / 9 15. REGULATORY INFORMATION Chemical Inventories TSCA All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt from listing. DSL/NDSL All components are on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Sodium hypochlorite 7681-52-9 100 lb X Sodium hydroxide 1310-73-2 1000 lb X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs RQ Sodium hypochlorite 7681-52-9 100 lb RQ 100 lb final RQ RQ 45.4 kg final RQ Sodium hydroxide 1310-73-2 1000 lb - RQ 1000 lb final RQ RQ 454 kg final RQ EPA Statement This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION: Liquid causes moderate eye irritation. Do not get in eyes or on clothing. Avoid contact with clothing. Wear protective eyewear. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet. For sensitive skin or prolonged use, wear gloves. Page 303 of 1287 Page 303 of 1287 Page 303 of 1287 Page 303 of 1287 ---PAGE BREAK--- Clorox® Bleach Wipes Revision Date New Page 9 / 9 US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Rhode Island Illinois Sodium hypochlorite 7681-52-9 X X X X Sodium hydroxide 1310-73-2 X X X X International Regulations Canada WHMIS Hazard Class Non-controlled 16. OTHER INFORMATION NFPA Health Hazard 1 Flammability 0 Instability 0 Physical and Chemical Hazards - HMIS Health Hazard 1 Flammability 0 Physical Hazard 0 Personal Protection - Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-[PHONE REDACTED] Preparation/Revision Date January 5, 2015 Revision Note Reference New 1047092/153737.001 General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 304 of 1287 Page 304 of 1287 Page 304 of 1287 Page 304 of 1287 ---PAGE BREAK--- 1. IDENTIFICATION Product identifier Product Name COPPER ANTI-SEIZE LUBRICANT 16 OZ. Other means of identification Product Code 31163 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Lubricant Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: [PHONE REDACTED] International Emergency: 00+1+ [PHONE REDACTED] Contract Number: MIS0003453 E-mail address [EMAIL REDACTED] 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Category 4 Label elements Emergency Overview Page 1 / 9 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Harmful if swallowed Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Revision Date 21-May-2015 SAFETY DATA SHEET Warning Version 1 Page 305 of 1287 Page 305 of 1287 Page 305 of 1287 Page 305 of 1287 ---PAGE BREAK--- Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Precautionary Statements - Storage Store in a well-ventilated place. Keep container closed Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Very toxic to aquatic life with long lasting effects. The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3 % DMSO extract as measured by IP 346. This note applies only to certain complex oil derived substances in Annex I. Unknown acute toxicity 31.7415% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC 64742-52-5 30 - 60 * COPPER 7440-50-8 10 - 30 * CALCIUM OXIDE 1305-78-8 10 - 30 * GRAPHITE 7782-42-5 5 - 10 * MINERAL OIL 8042-47-5 5 - 10 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. Page 2 / 9 Revision Date 21-May-2015 31163 - COPPER ANTI-SEIZE LUBRICANT 16 OZ. Odor (Petroleum distillates) Appearance Copper Physical state Paste Page 306 of 1287 Page 306 of 1287 Page 306 of 1287 Page 306 of 1287 ---PAGE BREAK--- Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If persist, call a physician. Ingestion IF SWALLOWED:. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important and effects, both acute and delayed See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Page 3 / 9 Revision Date 21-May-2015 31163 - COPPER ANTI-SEIZE LUBRICANT 16 OZ. Page 307 of 1287 Page 307 of 1287 Page 307 of 1287 Page 307 of 1287 ---PAGE BREAK--- Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers closed in a dry, cool and well-ventilated place. Incompatible materials Strong oxidizing agents, Acids 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH COPPER 7440-50-8 TWA: 1 mg/m3 Cu dust and mist TWA: 0.1 mg/m3 fume TWA: 1 mg/m3 dust and mist (vacated) TWA: 0.1 mg/m3 Cu dust, fume, mist IDLH: 100 mg/m3 Cu dust and mist TWA: 1 mg/m3 Cu dust and mist CALCIUM OXIDE 1305-78-8 TWA: 2 mg/m3 TWA: 5 mg/m3 (vacated) TWA: 5 mg/m3 not in effect as a result of reconsideration IDLH: 25 mg/m3 TWA: 2 mg/m3 GRAPHITE 7782-42-5 TWA: 2 mg/m3 respirable fraction all forms except graphite fibers TWA: 15 mg/m3 total dust TWA: 5 mg/m3 respirable fraction (vacated) TWA: 2.5 mg/m3 respirable dust natural (vacated) TWA: 10 mg/m3 total dust (vacated) TWA: 5 mg/m3 respirable fraction TWA: 15 natural IDLH: 1250 mg/m3 TWA: 2.5 mg/m3 natural respirable dust NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Paste Appearance Copper Odor (Petroleum distillates) Odor threshold No information available Page 4 / 9 31163 - COPPER ANTI-SEIZE LUBRICANT 16 OZ. Revision Date 21-May-2015 Page 308 of 1287 Page 308 of 1287 Page 308 of 1287 Page 308 of 1287 ---PAGE BREAK--- Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content 0 Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Incompatible materials Strong oxidizing agents, Acids Hazardous Decomposition Products Carbon oxides Oxides of sulfur 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Page 5 / 9 Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values Lower flammability limit: No information available 31163 - COPPER ANTI-SEIZE LUBRICANT 16 OZ. Vapor pressure No information available Boiling point / boiling range > 300 °C / 572 °F No data available Vapor density >1 Remarks • Method Air = 1 Relative density 1.31 Flash point Water solubility Negligible 107 °C / 225 °F Revision Date 21-May-2015 Solubility in other solvents No information available pH Partition coefficient No information available No information available Evaporation rate < 1 Autoignition temperature No information available Decomposition temperature No information available Butyl acetate = 1 Page 309 of 1287 Page 309 of 1287 Page 309 of 1287 Page 309 of 1287 ---PAGE BREAK--- Skin contact May cause skin irritation and/or dermatitis. Ingestion Harmful if swallowed. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 CALCIUM OXIDE 1305-78-8 = 500 mg/kg ( Rat ) - - MINERAL OIL 8042-47-5 > 5000 mg/kg ( Rat ) - - Information on toxicological effects No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC 64742-52-5 A2 Group 1 - X ACGIH (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Chronic toxicity May cause adverse liver effects. Target Organ Effects Central Vascular System (CVS), Eyes, kidney, Liver, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 1861 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity 12.2675% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC 64742-52-5 - 5000: 96 h mykiss mg/L LC50 1000: 48 h Daphnia magna mg/L EC50 COPPER 7440-50-8 0.0426 - 0.0535: 72 h Pseudokirchneriella subcapitata mg/L EC50 static 0.031 - 0.054: 96 h Pseudokirchneriella subcapitata mg/L EC50 static 0.2: 96 h Pimephales promelas mg/L LC50 flow-through 0.052: 96 h mykiss mg/L LC50 flow-through 1.25: 96 h Lepomis macrochirus mg/L LC50 static 0.3: 96 h Cyprinus carpio mg/L LC50 semi-static 0.8: 96 h Cyprinus carpio mg/L LC50 static 0.112: 96 h Poecilia reticulata mg/L LC50 flow-through 0.0068 - 0.0156: 96 h Pimephales promelas mg/L LC50 0.3: 96 h Pimephales promelas mg/L LC50 static 0.03: 48 h Daphnia magna mg/L EC50 Static CALCIUM OXIDE 1305-78-8 - 1070: 96 h Cyprinus carpio mg/L LC50 static - MINERAL OIL 8042-47-5 - 10000: 96 h Lepomis macrochirus mg/L LC50 - Page 6 / 9 31163 - COPPER ANTI-SEIZE LUBRICANT 16 OZ. Revision Date 21-May-2015 Page 310 of 1287 Page 310 of 1287 Page 310 of 1287 Page 310 of 1287 ---PAGE BREAK--- Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient MINERAL OIL 8042-47-5 >6 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status COPPER 7440-50-8 Toxic CALCIUM OXIDE 1305-78-8 Corrosive 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Contains: Natural substance(s) Not Listed. IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: Page 7 / 9 Revision Date 21-May-2015 31163 - COPPER ANTI-SEIZE LUBRICANT 16 OZ. Page 311 of 1287 Page 311 of 1287 Page 311 of 1287 Page 311 of 1287 ---PAGE BREAK--- TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % COPPER - 7440-50-8 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances COPPER 7440-50-8 - X X - CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) COPPER 7440-50-8 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts COPPER 7440-50-8 X X X CALCIUM OXIDE 1305-78-8 X X X GRAPHITE 7782-42-5 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Page 8 / 9 Physical hazards 0 Personal protection B Health hazards 1 31163 - COPPER ANTI-SEIZE LUBRICANT 16 OZ. Flammability 1 Instability 0 Revision Date 21-May-2015 - HMIS NFPA Health hazards 1 Flammability 1 Page 312 of 1287 Page 312 of 1287 Page 312 of 1287 Page 312 of 1287 ---PAGE BREAK--- Revision Date 21-May-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 9 / 9 31163 - COPPER ANTI-SEIZE LUBRICANT 16 OZ. Revision Date 21-May-2015 Page 313 of 1287 Page 313 of 1287 Page 313 of 1287 Page 313 of 1287 ---PAGE BREAK--- Page 314 of 1287 Page 314 of 1287 Page 314 of 1287 Page 314 of 1287 ---PAGE BREAK--- Page 315 of 1287 Page 315 of 1287 Page 315 of 1287 Page 315 of 1287 ---PAGE BREAK--- N524 Page 1 5332 Dansher Road Illinois 60525 MATERIAL SAFETY DATA SHEET Revision Date: 1/6/2011 MSDS No. N524 Supersedes Date: 8/8/2005 Emergency Phones: [PHONE REDACTED] (NYCO) [PHONE REDACTED] (CHEMTREC) PLEASE NOTE: This MSDS is being provided to your company for the purpose of providing current health and safety information to your management and for your employees who work with this material. Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT-TO-KNOW regulations. Also make this information available to any employee who requests it. It is your obligation to comply with these regulations. SECTION I - PRODUCT IDENTITY PRODUCT NAME: Detail Demon Auto Finish Cleaner/Polish Formula: Mixture, additives and alcohol in water. Chemical Type: As above HMIS RATINGS Health =1 (Slight) Flammability = 2 (Moderate) Reactivity = 0 (Minimal) Protection = B (Goggles & Gloves) SECTION II - HAZARDOUS INGREDIENTS CARCINOGEN PERCENT TLV (OSHA,TP,IARC) Isopropanol 400 ppm no CAS No. 67-63-0 STEL 500 ppm SECTION III - CHEMICAL AND PHYSICAL Appearance: opaque violet liquid Boiling Point: <212 oF Odor: Tuitti-Fruitti Melting Point: N/A pH: 7.0 - 8.0 Spec. Gravity (H20 = 1.00 Water Solubility: Complete Vapor Pressure (mm Hg): N/A Viscosity @ 25°C: Water Thin (Brookfield) VOC Content: 3% SECTION IV - FIRE AND EXPLOSION HAZARDS Flash Point (Method): 161 oF Cl.Cp. Explosion Limits: Upper: N/A Lower: N/A Extinguishing Media: Water fog, foam, alcohol foam, CO2, dry chemical Special Firefighting Procedures and Hazards: Treat as a combustible liquid. NOTE: This product is Combustible under OSHA criteria, but is not regulated by DOT since it contains less than 24% alcohol and over 50% water, and the other ingredients do not constitute a DOT hazard: see (CFR173.115(b)(2)(i) and (ii). SECTION V - REACTIVITY INFORMATION Stable: Unstable: Precautions: Incompatibility: None known Hazardous Decomposition Products: If in a fire: CO, CO2, hydrocarbons. Hazardous Polymerization: Occurs: Does Not Occur: Page 316 of 1287 Page 316 of 1287 Page 316 of 1287 Page 316 of 1287 ---PAGE BREAK--- N524 Page 2 SECTION VI - HEALTH HAZARDS - PROTECTIVE MEASURES - FIRST AID Inhalation: Breathing of vapors may cause dizziness and shortness of breath. Wear approved vapor respirator if needed. Remove to fresh air. Skin: Extended contact may cause irritation or defatting. Prolonged contact with 2-butoxyethanol may result in the absorption of potentially harmful amounts leading to possible liver and kidney damage. Wear protective gloves if needed. Remove contaminated clothing & wash if necessary before reuse. Flush skin thoroughly with water for 15 minutes. Eyes: Can cause irritation. Wear goggles as needed. Flush immediately with water for 15 minutes. Get prompt medical attention if needed. Ingestion: May cause a mild gastric disturbance. Drink lots of water. Do not induce vomiting. Get medical attention if effects persist. Most likely routes of entry: Skin, Eyes. Other Important Medical or Precautionary Information: None SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE Spills and Leaks: Small spills can be flushed into normal drainage or into ground with copious amounts of water, or taken up with absorbent material. Larger spills should be contained by diking or other methods and held for disposal or reuse. Remove all sources of ignition. Provide strong ventilation. Storage and Handling: Check daily for any leaks from containers, vessels, pumps, and piping. Keep away from sources of ignition. Keep at temperatures below 95°F. Waste Disposal: Collect in closed containers and send to a licensed treatment or disposal facility. Empty Containers: Rinse well before handling and disposal. Observe label precautions. Do not cut, weld or burn. Other Precautions: None SECTION VIII - REGULATORY INFORMATION Reportable for SARA Title III, S.313 (Form None. The information herein has been compiled from sources believed to be reliable and is accurate to the best of our knowledge. However, NYCO Products Company cannot give any guarantees regarding information from other sources, and expressly does not make any warranties, nor assumes any liability, for its use. Page 317 of 1287 Page 317 of 1287 Page 317 of 1287 Page 317 of 1287 ---PAGE BREAK--- 1. IDENTIFICATION Product identifier Product Name DIELECTRIC TUNE-UP GREASE 3 OZ Other means of identification Product Code 22058 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Lubricant Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: [PHONE REDACTED] International Emergency: 00+1+ [PHONE REDACTED] Contract Number: MIS0003453 E-mail address [EMAIL REDACTED] 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label elements Emergency Overview Hazards not otherwise classified (HNOC) Not applicable Other Information Page 1 / 7 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Revision Date 07-Apr-2015 SAFETY DATA SHEET Version 1 The product contains no substances which at their given concentration, are considered to be hazardous to health Odor Mild Appearance White Physical state Grease Page 318 of 1287 Page 318 of 1287 Page 318 of 1287 Page 318 of 1287 ---PAGE BREAK--- Not applicable Unknown acute toxicity 6.52% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret 63148-62-9 60 - 100 * MODIFIED SILICON DIOXIDE 68611-44-9 3 - 7 * OXIRANE, METHYL-, POLYMER 52624-57-4 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If persist, call a physician. Ingestion IF SWALLOWED. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important and effects, both acute and delayed See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 2 / 7 22058 - DIELECTRIC TUNE-UP GREASE 3 OZ Revision Date 07-Apr-2015 Page 319 of 1287 Page 319 of 1287 Page 319 of 1287 Page 319 of 1287 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers closed in a dry, cool and well-ventilated place. Incompatible materials Strong oxidizing agents, Acids, Reducing agent 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection None under normal use conditions. In case of insufficient ventilation, wear suitable respiratory equipment. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 3 / 7 22058 - DIELECTRIC TUNE-UP GREASE 3 OZ Revision Date 07-Apr-2015 Page 320 of 1287 Page 320 of 1287 Page 320 of 1287 Page 320 of 1287 ---PAGE BREAK--- Information on basic physical and chemical properties Physical state Grease Appearance White Odor Mild Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content 0 Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Incompatible materials Strong oxidizing agents, Acids, Reducing agent Hazardous Decomposition Products Carbon oxides Formaldehyde 11. TOXICOLOGICAL INFORMATION Page 4 / 7 Evaporation rate < 1 Autoignition temperature No information available Decomposition temperature No information available Butyl acetate = 1 Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values Lower flammability limit: No information available 22058 - DIELECTRIC TUNE-UP GREASE 3 OZ Vapor pressure No information available Boiling point / boiling range No information available No data available Vapor density >1 Air = 1 Relative density 1.0 Revision Date 07-Apr-2015 Flash point Water solubility Negligible > 93 °C / > 199 °F Solubility in other solvents No information available Tag Closed Cup pH Partition coefficient No information available No information available Page 321 of 1287 Page 321 of 1287 Page 321 of 1287 Page 321 of 1287 ---PAGE BREAK--- Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 63148-62-9 > 17 g/kg ( Rat ) > 2 g/kg ( Rabbit ) - Information on toxicological effects No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity This product contains one or more substances which are classified by IARC as carcinogenic to humans (Group probably carcinogenic to humans (Group 2A) or possibly carcinogenic to humans (Group 2B). IARC (International Agency for Research on Cancer) Group 2A - Probably Carcinogenic to Humans OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 18219 mg/kg ATEmix (dermal) 2143 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity 99.92% of the mixture consists of components(s) of unknown hazards to the aquatic environment Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable Page 5 / 7 22058 - DIELECTRIC TUNE-UP GREASE 3 OZ Revision Date 07-Apr-2015 Page 322 of 1287 Page 322 of 1287 Page 322 of 1287 Page 322 of 1287 ---PAGE BREAK--- 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Not Listed. ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations Page 6 / 7 22058 - DIELECTRIC TUNE-UP GREASE 3 OZ Revision Date 07-Apr-2015 Page 323 of 1287 Page 323 of 1287 Page 323 of 1287 Page 323 of 1287 ---PAGE BREAK--- California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 07-Apr-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 7 / 7 - HMIS NFPA Health hazards 1 22058 - DIELECTRIC TUNE-UP GREASE 3 OZ Flammability 1 Physical hazards 0 Personal protection B Health hazards 1 Revision Date 07-Apr-2015 Flammability 1 Instability 0 Page 324 of 1287 Page 324 of 1287 Page 324 of 1287 Page 324 of 1287 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 1 of 13 POWER SERVICE PRODUCTS, INC. SAFETY DATA SHEET SECTION 1 - IDENTIFICATION PRODUCT NAME: DIESEL FUEL SUPPLEMENT +CETANE BOOST Unless otherwise noted, all sections of this SDS apply to each of the following products and part numbers. PART NUMBERS: 1:400 Treatment Ratio 1016-06, 1016-09, 1025-06, 1025-09, 1025-12, 1080-06, 11016-06, 11016-09, 11025-06, 11025-12, 11080-06 1:1,000 Treatment Ratio 1000, 1128-04, 1060-01 1:1,500 Treatment Ratio 1050-02, 1055-01, 1260-01 COMPANY IDENTIFICATION: Power Service Products, Inc. P.O. Box 1089 Weatherford, TX 76086 Email: [EMAIL REDACTED] Phone: [PHONE REDACTED] or [PHONE REDACTED] Fax: [PHONE REDACTED] Emergency Phone Number: Within USA 1-[PHONE REDACTED]. Outside USA 001-[PHONE REDACTED] (Call Collect). RECOMMENDED USES: Diesel fuel additive SECTION 2 – HAZARD(S) IDENTIFICATION CLASSIFICATION UNDER 29 CFR 1910.1200(d) (NC=product does not meet classification criteria) 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Health Hazard Criteria Category Category Category Acute Toxicity, Oral: NC NC NC Acute Toxicity, Dermal: NC NC NC Acute Toxicity, Inhalation, Vapors: 3 3 3 Page 325 of 1287 Page 325 of 1287 Page 325 of 1287 Page 325 of 1287 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 2 of 13 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Health Hazard Criteria Category Category Category Skin Corrosion/Irritation: 2 2 2 Serious Eye Damage/Eye Irritation: 2 2 2 Respiratory Sensitization: NC NC NC Skin Sensitization: NC NC NC Germ Cell Mutagenicity: NC NC NC Carcinogenicity: 2 2 2 Reproductive Toxicity: NC NC NC Specific Target Organ Toxicity, Single Exposure: 3 3 3 Specific Target Organ Toxicity, Repeated or Prolonged Exposure: NC NC NC Aspiration Hazard: 1 1 1 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Physical Properties Criteria Category Category Category Explosives: NC NC NC Flammable Gases: NC NC NC Flammable Aerosols: NC NC NC Oxidizing Gases: NC NC NC Gases Under Pressure: NC NC NC Flammable Liquids: 3 3 3 Flammable Solids: NC NC NC Self-Reactive Chemicals: NC NC NC Pyrophoric Liquids: NC NC NC Pyrophoric Solids: NC NC NC Self-Heating Chemicals: NC NC NC Chemicals Which, in Contact with Water, Emit Flammable Gases: NC NC NC Oxidizing Liquids: NC NC NC Oxidizing Solids: NC NC NC Organic Peroxides: NC NC NC Corrosive to Metals: NC NC NC LABEL SIGNAL WORD, HAZARD STATEMENTS, SYMBOLS AND PRECAUTIONARY STATEMENTS UNDER 29 CFR 1910.1200(f): Please see the Note regarding product labeling in Section 16. Page 326 of 1287 Page 326 of 1287 Page 326 of 1287 Page 326 of 1287 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 3 of 13 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Signal Word Danger Danger Danger Hazard Statement(s): Flammable liquid and vapor. Toxic if inhaled. May be fatal if swallowed and enters airways. Harmful if swallowed. Causes skin and serious eye irritation. May cause respiratory irritation and drowsiness or dizziness. Symbols: The following symbols are for all treatment ratios. Precautionary Statement(s): Keep away from sparks and open flames. No smoking. Keep container closed. Use only non-sparking tools. Ground/Bond container and receiving equipment. Use explosion-proof pumps when pumping. Take precautionary measures against static discharge. Avoid breathing vapors. Use only outdoors or in a well-ventilated area. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves and eye protection. Store locked up and in cool, well ventilated place. KEEP OUT OF REACH OF CHILDREN. Hazards Not Otherwise Classified: None SECTION 3 – COMPOSITION / INFORMATION ON INGREDIENTS The specific chemical identity and exact concentration percentage has been withheld as a Trade Secret. Specific chemical information will be made available to health professionals in accordance with 29 CFR 1910.1200. INGREDIENTS CLASSIFIED AS HEALTH HAZARDS TREATMENT RATIO 1:400 Chemical Name Common Name/Synonyms CAS Number Concentration Petroleum Distillates Trade secret Trade secret 50 - 90 Hydroxy alkoxylate Trade secret Trade secret 4 - 10 Alkyl Nitrates Trade secret Trade secret 2 - 6 Naphthalene Not available 91-20-3 0.05 – 0.2 Page 327 of 1287 Page 327 of 1287 Page 327 of 1287 Page 327 of 1287 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 4 of 13 TREATMENT RATIO 1:1000 Chemical Name Common Name/Synonyms CAS Number Concentration Petroleum Distillates Trade secret Trade secret 40 - 90 Alkyl Nitrates Trade secret Trade secret 5 - 15 Aromatic Hydrocarbons Trade secret Trade secret 2 - 5 Hexan-1-ol, 2-ethyl Trade secret Trade secret 1 - 4 Naphthalene Not available 91-20-3 0.1 – 0.5 TREATMENT RATIO 1:1500 Chemical Name Common Name/Synonyms CAS Number Concentration Petroleum Distillates Trade secret Trade secret 20 - 55 Alkyl Nitrates Trade secret Trade secret 10 – 20 Aromatic Hydrocarbons Trade secret Trade secret 3 - 8 Hexan-1-ol, 2-ethyl Trade secret Trade secret 2 – 5 Naphthalene Not available 91-20-3 0.2 – 0.9 SECTION 4 - FIRST AID MEASURES As a precaution, exposure to liquids, vapors, mists and fumes should be minimized. EYE CONTACT: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice. SKIN CONTACT: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs get medical advice/attention. INHALATION: Remove person to fresh air and keep comfortable for breathing. Call a doctor. INGESTION: If swallowed, IMMEDIATELY call a doctor. Do NOT induce vomiting. SECTION 5 - FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Use water fog, alcohol-resistant foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPECIFIC HAZARDS: Vapors are heavier than air and may travel along the ground to a distant ignition source and flash back. See Section 10 for Stability and Reactivity. NOTE: EMPTY CONTAINERS CONTAIN COMBUSTIBLE VAPORS THAT CAN CAUSE FLASH FIRES OR EXPLOSIONS. CONTAINERS ARE SINGLE-TRIP CONTAINERS AND SHOULD NOT BE USED FOR ANY REASON AFTER BEING EMPTIED. DO NOT USE CUTTING TORCH Page 328 of 1287 Page 328 of 1287 Page 328 of 1287 Page 328 of 1287 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 5 of 13 EQUIPMENT OR ANY OTHER FLAME OR OTHER SOURCES OF IGNITION ON ANY EMPTY CONTAINER. PROTECTIVE EQUIPMENT AND PRECAUTIONS: Use standard protective equipment including self-contained breathing apparatus (SCBA). SECTION 6 - ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, AND EMERGENCY PROCEDURES: Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas. Eliminate all sources of ignition in the vicinity of the spill or released vapor. See Section 2 for Hazards Identification. See Section 4 for First Aid Measures. See Section 5 for Fire Fighting Information. See Section 8 for Personal Protective Equipment. SPILL CONTAINMENT AND CLEAN-UP: Eliminate potential sources of ignition. Stop leak if it can be done without risk. Dike and contain spill. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. Remove with vacuum trucks or pump to storage/salvage vessels. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly. A vapor suppressing foam may be used to reduce vapors. Local, state and federal laws and/or regulations may apply to releases and disposal of this material, as well as those materials and items employed in the clean-up releases. The user/responder will need to determine which local, state and federal laws and/or regulations are applicable. The National Response Center can be reached at 1-[PHONE REDACTED]. SECTION 7 - HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING: Avoid contact with eyes and skin. Use only with adequate ventilation. Use proper bonding and/or grounding procedures. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Keep away from ignition sources such as heat, sparks, and flames. No smoking. CONDITIONS FOR SAFE STORAGE: DO NOT USE OR STORE near heat, sparks, or flame. USE AND STORE ONLY IN A WELL-VENTILATED AREA. Handle containers with care. Keep container closed when not in use. Store locked up. STORAGE TEMPERATURE: Treatment Ratio Part Numbers: Storage Temperature: 1:400 Treatment Ratio 1016-06, 1016-09, 1025-06, 1025-12, 1080-06, 11016-06, 11016-09, 11025-06, 11025-12, 11041-04, 11080-06 -20F to 104F (-29C to 40C) 1:1,000 Treatment Ratio 1000, 1128-04, 1060-01 0F to 104F (-18C to 40C) Page 329 of 1287 Page 329 of 1287 Page 329 of 1287 Page 329 of 1287 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 6 of 13 1:1,500 Treatment Ratio 1050-02, 1055-01, 1260-01 10F to 104F (-12C to 40C) EMPTY CONTAINER WARNING: EMPTY CONTAINERS MAY CONTAIN COMBUSTIBLE VAPORS AND CAN BE DANGEROUS. SEE SECTION 5 FOR FIRE AND EXPLOSION HAZARD DATA. SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES: CAS # OSHA ACGIH NIOSH PEL TLV STEL REL STEL IDLH Note 100-41-4 100 ppm 20 ppm not est. 100 ppm 125 ppm 800 ppm (LEL) n/a Naphthalene 91-20-3 10 ppm 10 ppm not est. 10 ppm 15 ppm 250 ppm skin Petroleum Distillates n/a 500 ppm not est. not est. not est. not est. not est. n/a Cumene 98-82-8 50 ppm 50 ppm not est. 50 ppm not est. 900 ppm (LEL) Skin Toluene 108-88-3 100 ppm 20 ppm not est. 100 ppm 150 ppm 500 ppm Skin Hydroxy Alkoxylate Proprietary 50 ppm 20 ppm not est. 5 ppm not est. not est. skin ENGINEERING CONTROLS: The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Local exhaust ventilation is recommended to control exposure. PERSONAL PROTECTIVE EQUIPMENT (PPE): Eyes and Face: Eye protection such as safety glasses or chemical goggles is recommended if contact is likely. Skin: Protective chemical/oil resistant gloves are recommended. Wear additional protective clothing as appropriate. Respiratory: Wear a NIOSH/MSHA approved respirator as necessary. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Practice good housekeeping. NOTE: These precautions are for room temperature handling. Page 330 of 1287 Page 330 of 1287 Page 330 of 1287 Page 330 of 1287 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 7 of 13 SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Appearance Liquid, brown Liquid, brown Liquid, brown Odor Aromatic solvent Aromatic solvent Aromatic solvent Odor Threshold Not available Not available Not available pH 7 – 8 basic) 7 – 8 basic) 7 – 8 basic) Melting point/Freezing point Not available Not available Not available Initial Boiling Point and Boiling Range 300F (149C) 300F (149C) 300F (149C) Flash Point 105F (40.5C) 116F (46.6C) 121F (49.4C) Evaporation Rate Not available Not available Not available Flammability Not available Not available Not available Upper / lower Flammability or Explosive Limits Not available Not available Not available Vapor Pressure 0.2 – 0.95 0.2 – 0.95 0.2 – 0.95 Vapor Density >5.0 >5.0 >5.0 Relative Density/Specific Gravity (at 60°F) 0.910 0.912 0.896 Solubility Not available Not available Not available Partition Coefficient; n-octanol / water Not available Not available Not available Auto-ignition Temperature Not available Not available Not available Decomposition temperature Not available Not available Not available Viscosity Not available Not available Not available Pour Point -55F (-13C) -30F (1.1C) -15F (9.4C) SECTION 10 - STABILITY AND REACTIVITY REACTIVITY: see Incompatible Materials below CHEMICAL STABILITY: This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. POSSIBILITY OF HAZARDOUS REACTION: Hazardous polymerization will not occur. CONDITIONS TO AVOID: Flames, high energy ignition sources, and elevated temperatures. INCOMPATIBLE MATERIALS: May react with strong oxidizing agents, such as; chlorates, nitrates, peroxides, nitrogen oxides, sulfur oxides, etc.; alkalis; nitric acid; sulfuric acid; aluminum; brass; copper; reducing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon oxides, products of incomplete combustion. Page 331 of 1287 Page 331 of 1287 Page 331 of 1287 Page 331 of 1287 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 8 of 13 SECTION 11 - TOXICOLOGICAL INFORMATION LIKELY ROUTES OF EXPOSURE INGESTION INHALATION SKIN CONTACT EYE CONTACT SKIN ABSORPTION 1:400 Treatment Ratio X X X X 1:1000 Treatment Ratio X X X X 1:1500 Treatment Ratio X X X X RELATED TO PHYSICAL, CHEMICAL AND TOXICOLOGICAL CHARACTERISTICS: Breathing of high vapor concentrations may cause dizziness, light- headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness. The vapor or fumes from this material may cause respiratory irritation. Breathing this material at elevated concentrations causes central nervous system effects. Central nervous system effects may include headache, dizziness, nausea, vomiting, weakness, loss of coordination, blurred vision, drowsiness, confusion or disorientation. At extreme exposures, central nervous system effects may include respiratory depression, tremors, or convulsions, loss of consciousness, coma or death. DELAYED AND IMMEDIATE EFFECTS AND CHRONIC EFFECTS FROM SHORT- AND LONG-TERM EXPOSURE: Repeated skin exposure to a component of this product may cause irritation, even a burn; may cause a more severe response on covered skin, such as under clothing or gloves. Inhalation exposure to a component of this product has caused fetotoxicity in the presence of maternal toxicity in animals. NUMERICAL MEASURES OF TOXICITY Note: the information provided below are estimates; testing of the product is not available. Treatment Ratio Acute Oral Toxicity (ATEmix estimate) Acute Dermal Toxicity (ATEmix estimate) Acute Inhalation (ATEmix estimate) 1:400 Treatment Ratio Does not meet criteria Does not meet criteria 7.10 (vapors) 1:1,000 Treatment Ratio Does not meet criteria Does not meet criteria 8.56 (vapors) 1:1,500 Treatment Ratio Does not meet criteria Does not meet criteria 7.48 (vapors) SENSITIZATION: No information available. MUTAGENICITY: No information available. CARCINOGENICITY LISTINGS – the following chemicals are listed as indicated: Page 332 of 1287 Page 332 of 1287 Page 332 of 1287 Page 332 of 1287 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 9 of 13 Chemical List Cumene IARC, NTP IARC Naphthalene IARC, NTP REPODUCTIVE TOXICITY: No information available. TERATOGENICITY/EMBRYOTOXICITY: Hydroxy Alkoxylate has caused fetotoxicity with maternal toxicity. This product contains a component of a complex mixture (Xylenes (1330-20- that has been shown to cause teratogenicity and/or embryotoxicity. SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): Respiratory tract irritation, drowsiness/dizziness. SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): No information available ASPIRATION HAZARD: Aspiration hazard identified. SECTION 12 - ECOLOGICAL INFORMATION ECOTOXICITY: This material is expected to be toxic to aquatic organisms. PERSISTENCE AND DEGRADABILITY: No information available. BIOACCUMULATIVE POTENTIAL: No information available. MOBILITY IN SOIL: No information available. OTHER ADVERSE EFFECTS: No information available. SECTION 13 - DISPOSAL CONSIDERATIONS RCRA Information: Disposal of unused product may be subject to RCRA hazardous waste regulations (40 CFR Part 261). Disposal of the used product may also be regulated as hazardous waste due to resulting mixture characteristics, mixture components or product use. Such changes to the product may result in different and/or additional hazardous waste codes. Potential RCRA waste code based on the product as shipped: D001 IGNITABILITY State or local laws may impose additional regulatory requirements regarding disposal. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. EMPTY CONTAINER WARNING: EMPTY CONTAINERS MAY CONTAIN COMBUSTIBLE VAPORS AND CAN BE DANGEROUS. SEE SECTION 5 FOR FIRE AND EXPLOSION Page 333 of 1287 Page 333 of 1287 Page 333 of 1287 Page 333 of 1287 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 10 of 13 HAZARD DATA. Dispose or recycle empty containers appropriately per local, state and federal regulations. SECTION 14 - TRANSPORTATION INFORMATION The following part numbers are not regulated by DOT: 1:400 Treatment Ratio 1016-06, 1016-09, 1025-06, 1025-09, 1025-12, 1080-06, 11016-06, 11016-09, 11025-06, 11025-12, 1080-06 1:1,000 Treatment Ratio 1128-04 1:1,500 Treatment Ratio 1050-02, 1055-01 The following part numbers are regulated by DOT: 1:1,000 Treatment Ratio 1060-01 PROPER SHIPPING NAME: Combustible Liquid, N.O.S., (Petroleum Distillates) Marine Pollutant Nitrate) HAZARD CLASS: Combustible Liquid I.D. NUMBER: NA 1993 PACKING GROUP: III PLACARDING: Combustible Liquid MARINE POLLUTANT: Yes 1:1,000 Treatment Ratio 1000 PROPER SHIPPING NAME: Combustible Liquid, N.O.S., (Petroleum Distillates) Marine Pollutant Nitrate) RQ (Xylene, Naphthalene) HAZARD CLASS: Combustible Liquid I.D. NUMBER: NA 1993 PACKING GROUP: III PLACARDING: Combustible Liquid MARINE POLLUTANT: Yes PRODUCT RQ: 100 lbs. (45.45 kg) – Xylene, Naphthalene 1:1,500 Treatment Ratio 1260-01 PROPER SHIPPING NAME: Combustible Liquid, N.O.S., (Petroleum Distillates) Marine Pollutant Nitrate) HAZARD CLASS: Combustible Liquid I.D. NUMBER: NA 1993 PACKING GROUP: III PLACARDING: Combustible Liquid MARINE POLLUTANT: Yes Page 334 of 1287 Page 334 of 1287 Page 334 of 1287 Page 334 of 1287 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 11 of 13 SECTION 15 - REGULATORY INFORMATION §14(a) Consumer Product Safety Act General Certificate of Conformity Power Service Products, Inc. certifies that this product meets the statutory and regulatory requirements of the US Consumer Products Safety Act, the Federal Hazardous Substances Act, and the Poison Prevention Packaging Act of 1970, as applicable. The Power Service products are manufactured in the United States in Weatherford, Texas, unless otherwise indicated on the product label. The product manufacture lot code is stamped on the product container. This Certification is based upon a reasonable testing program conducted by Power Service Products, Inc. which includes a quality control program incorporating, as necessary, confirmation of compliance by component suppliers. Third-party testing is not required to certify compliance. Further details may be obtained by contacting the Power Service Products, Inc. EHS Manager at 1-[PHONE REDACTED]. Contents of this SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. TSCA STATUS: All chemical substances found in this product comply with the Toxic Substances Control Act inventory reporting requirements. EPA SARA TITLE III CHEMICAL LISTINGS: Section 302 Extremely Hazardous Substances: None Sections 311/ 312 Hazard Class: Acute Health Effects: Yes Sudden Release of Pressure Hazard: No Chronic Health Effects: Yes Reactivity Hazard: No Fire Hazard: Yes NFPA (NATIONAL FIRE PROTECTION ASSOCIATION) RATING: HEALTH: 2 FIRE: 2 REACTIVITY: 0 Section 313: Specific chemical information is being withheld as a Trade Secret. The following chemicals subject to the reporting requirements of EPCRA Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (40 CFR Part 372) may be present in this product at a concentration that does not exceed the specified upper weight percentage. Treatment Ratio CAS Number Chemical Name Max % 1:400 Treatment Ratio 100-41-4 24.0 NA Glycol Ether Category 8.0 Page 335 of 1287 Page 335 of 1287 Page 335 of 1287 Page 335 of 1287 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 12 of 13 Treatment Ratio CAS Number Chemical Name Max % 91-20-3 Naphthalene 1.0 98-82-8 Cumene 4.0 108-88-3 Toluene 4.0 1:1000 Treatment Ratio 100-41-4 19.0 91-20-3 Naphthalene 1.0 98-82-8 Cumene 3.5 108-88-3 Toluene 3.5 1:1,500 Treatment Ratio 100-41-4 12.0 91-20-3 Naphthalene 1.0 98-82-8 Cumene 2.0 108-88-3 Toluene 2.0 State or local laws may impose additional regulatory requirements for components of this material. It is the responsibility solely of the Employer to maintain compliance with State and Local reporting. This product contains a chemical known to the state of California to cause cancer and/or birth defects or other reproductive harm: toluene, cumene, naphthalene. SECTION 16 – OTHER INFORMATION DATE OF PREPARATION / REVISION: May 30, 2015 NOTE regarding product labeling: The OSHA Hazard Communication Standard applies to hazardous chemicals known to be present in the workplace. However, the labeling and Safety Data Sheet requirements do not apply to consumer products when they are used in the workplace for the purposes intended by the manufacturer and the use results in a duration and frequency of exposure which is not greater than the range of exposures that could reasonably be experienced by consumers when used for the intended purpose. Power Service Products intends for product packaged in 1 gallon or smaller containers to be used by consumers and has labeled those containers as required under the Consumer Product Safety Commission regulations. Power Service Products intends for product packaged in containers larger than 1 gallon to be used in the workplace and has labeled those products as required by the OSHA Hazard Communication Standard. The Consumer Product Safety Commission and OSHA Hazard Communication Standard labeling requirements are different and variations between the consumer and industrial labels may occur. It is the employer’s responsibility to purchase the appropriate product for use in the workplace. The information contained herein is offered in good faith and is believed to be accurate based on the data available to us as of the date of SDS preparation. The information in this document applies to this specific product as supplied. It may not be appropriate for this product if the product is used in combination with other materials. The information in this document is not intended to constitute product performance information. Some of the information presented and conclusions drawn herein are from sources other than direct test data on the product. No statement shall be construed as an endorsement of any product or process. The recommended Page 336 of 1287 Page 336 of 1287 Page 336 of 1287 Page 336 of 1287 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 13 of 13 industrial hygiene and safe handling procedures are believed to be valid in the context of the intended use as described in product labeling. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate. You are urged to obtain material safety data sheets for all products you buy, process, use or distribute, and are encouraged to advise those who may come in contact with such products of the information contained therein. Regulatory requirements are subject to change and may differ between locations. It is the buyer’s/user’s responsibility to ensure that his activities comply with all federal, state, provincial or local laws. No warranty or guarantee is expressed or implied with respect to this product, the accuracy and sufficiency of the data or recommendations herein, or the results to be obtained from the use of this product. IN NO EVENT SHALL POWER SERVICE PRODUCTS, INC. BE LIABLE FOR ANY LOSS, CLAIM, DAMAGE OR LIABILITY OF ANY KIND, WHICH MAY ARISE FROM OR IN CONNECTION WITH THE INFORMATION CONTAINED IN THIS DOCUMENT OR FROM THE USE, HANDLING OR STORAGE OF THE PRODUCT BY THE BUYER/USER, WHETHER DIRECT, INDIRECT, OR CONSEQUENTIAL, OR FOR ANY CLAIM BY ANY THIRD PARTY, BEYOND THE PURCHASE PRICE OR REPLACEMENT OF THE PRODUCT IN CONNECTION WITH WHICH SUCH LOSS, CLAIM, DAMAGE OR LIABILITY AROSE. THE FOREGOING LIMITATIONS APPLY REGARDLESS OF THE CAUSES OR CIRCUMSTANCES GIVING RISE TO SUCH LOSS, CLAIM, DAMAGE OR LIABILITY, EVEN IF SUCH LOSS, CLAIM, DAMAGE, OR LIABILITY IS BASED ON NEGLIGENCE OR OTHER TORTS OR BREACH OF CONTRACT. Page 337 of 1287 Page 337 of 1287 Page 337 of 1287 Page 337 of 1287 ---PAGE BREAK--- Page 338 of 1287 Page 338 of 1287 Page 338 of 1287 Page 338 of 1287 ---PAGE BREAK--- Page 339 of 1287 Page 339 of 1287 Page 339 of 1287 Page 339 of 1287 ---PAGE BREAK--- Page 340 of 1287 Page 340 of 1287 Page 340 of 1287 Page 340 of 1287 ---PAGE BREAK--- Product Name: DIESEL/BIODIESEL BLEND Revision Date: 23 Dec 2014 Page 1 of 12 MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: (see Section 16 for Synonyms) DIESEL/BIODIESEL BLEND Product Description: Hydrocarbons and Additives MSDS Number: 20463 Intended Use: Diesel engine fuel COMPANY IDENTIFICATION Supplier: Imperial Oil 240 4th Avenue Calgary, ALBERTA. T2P 3M9 Canada 24 Hour Environmental / Health Emergency Telephone 1-[PHONE REDACTED] Transportation Emergency Phone Number 1-[PHONE REDACTED] Product Technical Information 1-[PHONE REDACTED] Supplier General Contact 1-[PHONE REDACTED] SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# Concentration* Acute Toxicity ALKANES, C10-20 BRANCHED AND LINEAR 928771-01-1 0 - 30% None FUEL OIL NO. 2 68476-30-2 < 100% None KEROSENE, STRAIGHT RUN 8008-20-6 < 100% None LIGHT ATMOSPHERIC GAS OIL 64741-44-2 < 100% None LIGHT HYDROCRACKED DISTILLATE (PETROLEUM) 64741-77-1 < 100% None Hazardous Constituent(s) Contained in Complex Substance(s) Name CAS# Concentration* Acute Toxicity NAPHTHALENE 91-20-3 < 1% Inhalation Lethality: LC50 > 0.4 mg/l (Rat); Oral Lethality: LD50 710 mg/kg (Mouse); Oral Lethality: LD50 533 mg/kg (Mouse) * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. NOTE: Composition may contain up to 0.5% performance additives and / or dyes. SECTION 3 HAZARDS IDENTIFICATION This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). PHYSICAL/CHEMICAL EFFECTS Combustible. Material can release vapours that readily form flammable mixtures. Vapour accumulation could Page 341 of 1287 Page 341 of 1287 Page 341 of 1287 Page 341 of 1287 ---PAGE BREAK--- Product Name: DIESEL/BIODIESEL BLEND Revision Date: 23 Dec 2014 Page 2 of 12 flash and/or explode if ignited. Material can accumulate static charges which may cause an ignition. HEALTH EFFECTS Irritating to skin. May cause cancer. If swallowed, may be aspirated and cause lung damage. Under conditions of poor personal hygiene and prolonged repeated contact, some aromatic compounds (PACs) have been suspected as a cause of skin cancer in humans. May be irritating to the eyes, nose, throat, and lungs. May cause central nervous system depression. High-pressure injection under skin may cause serious damage. NFPA Hazard ID: Health: 1 Flammability: 2 Reactivity: 0 HMIS Hazard ID: Health: 1* Flammability: 2 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Remove contaminated clothing. Dry wipe exposed skin and cleanse with waterless hand cleaner and follow by washing thoroughly with soap and water. For those providing assistance, avoid further skin contact to yourself or others. Wear impervious gloves. Launder contaminated clothing separately before reuse. Discard contaminated articles that cannot be laundered. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION Seek immediate medical attention. Do not induce vomiting. NOTE TO PHYSICIAN If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately. PRE-EXISTING MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSURE Contains hydrocarbon solvent/petroleum hydrocarbons; skin contact may aggravate an existing dermatitis. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Page 342 of 1287 Page 342 of 1287 Page 342 of 1287 Page 342 of 1287 ---PAGE BREAK--- Product Name: DIESEL/BIODIESEL BLEND Revision Date: 23 Dec 2014 Page 3 of 12 Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: FLAMMABLE. Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Vapour is flammable and heavier than air. Vapour may travel across the ground and reach remote ignition sources, causing a flashback fire danger. Hazardous material. Firefighters should consider protective equipment indicated in Section 8. Hazardous Combustion Products: Sulphur oxides, Oxides of carbon, Incomplete combustion products, Aldehydes, Smoke, Fume FLAMMABILITY PROPERTIES Flash Point [Method]: >38°C (100°F) [ASTM D-93] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. PROTECTIVE MEASURES Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required, due to toxicity or flammability of the material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. SPILL MANAGEMENT Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Use clean non-sparking tools to collect absorbed material. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large Spills: Water spray may reduce vapour, but may not prevent ignition in enclosed spaces. Water Spill: Stop leak if you can do so without risk. Eliminate sources of ignition. Warn other shipping. If the Flash Point exceeds the Ambient Temperature by 10 deg C or more, use containment booms and remove from the surface by skimming or with suitable absorbents when conditions permit. If the Flash Point does not exceed the Ambient Air Temperature by at least 10C, use booms as a barrier to protect shorelines and allow material to evaporate. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction Page 343 of 1287 Page 343 of 1287 Page 343 of 1287 Page 343 of 1287 ---PAGE BREAK--- Product Name: DIESEL/BIODIESEL BLEND Revision Date: 23 Dec 2014 Page 4 of 12 and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE HANDLING Avoid all personal contact. Do not siphon by mouth. Place rags, absorbent pads, paper towels etc. contaminated with biodiesel in a container and cover with water. Secure the lid on the container (See Section 5 - Unusual Fire Hazards). Do not use as a cleaning solvent or other non-motor fuel uses. For use as a motor fuel only. It is dangerous and/or unlawful to put petrol into unapproved containers. Do not fill container while it is in or on a vehicle. Static electricity may ignite vapour and cause fire. Place container on ground when filling and keep nozzle in contact with container. Do not use electronic devices (including but not limited to cellular phones, computers, calculators, pagers or other electronic devices etc) in or around any fuelling operation or storage area unless the devices are certified intrinsically safe by an approved national testing agency and to the safety standards required by national and/or local laws and regulations. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. A liquid is typically considered a nonconductive, static accumulator if its conductivity is below 100 pS/m (100x10E-12 Siemens per meter) and is considered a semiconductive, static accumulator if its conductivity is below 10,000 pS/m. Whether a liquid is nonconductive or semiconductive, the precautions are the same. A number of factors, for example liquid temperature, presence of contaminants, anti-static additives and filtration can greatly influence the conductivity of a liquid. STORAGE The container choice, for example storage vessel, may effect static accumulation and dissipation. Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well-ventilated area. Storage containers should be earthed and bonded. Fixed storage containers, transfer containers and associated equipment should be grounded and bonded to prevent accumulation of static charge. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Substance Name Form Limit/Standard Note Source DIESEL/BIODIESEL BLEND Stable Aerosol. TWA 5 mg/m3 Supplier DIESEL/BIODIESEL BLEND Total vapour and aerosol. TWA 500 mg/m3 100 ppm Supplier FUEL OIL NO. 2 Stable Aerosol. TWA 5 mg/m3 Supplier FUEL OIL NO. 2 Vapour. TWA 200 mg/m3 Supplier FUEL OIL NO. 2 [total hydrocarb, Inhalable TWA 100 mg/m3 Skin ACGIH Page 344 of 1287 Page 344 of 1287 Page 344 of 1287 Page 344 of 1287 ---PAGE BREAK--- Product Name: DIESEL/BIODIESEL BLEND Revision Date: 23 Dec 2014 Page 5 of 12 vapor&aerosol] fraction and vapour KEROSENE, STRAIGHT RUN Stable Aerosol. TWA 5 mg/m3 Supplier KEROSENE, STRAIGHT RUN Vapour. TWA 200 mg/m3 Supplier KEROSENE, STRAIGHT RUN [as total hydrocarbon vapor] Non-Aerosol TWA 200 mg/m3 Skin ACGIH LIGHT ATMOSPHERIC GAS OIL Stable Aerosol. TWA 5 mg/m3 Supplier LIGHT ATMOSPHERIC GAS OIL Vapour. TWA 200 mg/m3 Supplier LIGHT HYDROCRACKED DISTILLATE (PETROLEUM) Stable Aerosol. TWA 5 mg/m3 Supplier LIGHT HYDROCRACKED DISTILLATE (PETROLEUM) Vapour. TWA 200 mg/m3 Supplier NAPHTHALENE TWA 10 ppm Skin ACGIH NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: Use explosion-proof ventilation equipment to stay below exposure limits. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: Chemical resistant gloves are recommended. If contact with forearms is likely wear gauntlet style gloves. Eye Protection: If contact with material is likely, chemical goggles are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: Page 345 of 1287 Page 345 of 1287 Page 345 of 1287 Page 345 of 1287 ---PAGE BREAK--- Product Name: DIESEL/BIODIESEL BLEND Revision Date: 23 Dec 2014 Page 6 of 12 Chemical/oil resistant clothing is recommended. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping. ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Petroleum/Solvent Odour Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 0.82 - 0.9 Flash Point [Method]: >38°C (100°F) [ASTM D-93] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D Boiling Point / Range: > 150°C (302°F) Vapour Density (Air = > 2 at 101 kPa Vapour Pressure: 0.067 kPa (0.5 mm Hg) at 20ºC Evaporation Rate (n-butyl acetate = N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): N/D Solubility in Water: Negligible Viscosity: 1.6 cSt (1.6 mm2/sec) at 40ºC - 5 cSt (5 mm2/sec) at 40ºC Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Decomposition Temperature: N/D SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources. MATERIALS TO AVOID: Halogens, Strong Acids, Strong Bases, Strong oxidizers Page 346 of 1287 Page 346 of 1287 Page 346 of 1287 Page 346 of 1287 ---PAGE BREAK--- Product Name: DIESEL/BIODIESEL BLEND Revision Date: 23 Dec 2014 Page 7 of 12 HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation Toxicity (Rat): LC50 > 5000 mg/m3 Minimally Toxic. Based on test data for structurally similar materials. Irritation: Data available. Elevated temperatures or mechanical action may form vapours, mist, or fumes which may be irritating to the eyes, nose, throat, or lungs. Based on test data for structurally similar materials. Ingestion Toxicity (Rat): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Skin Toxicity (Rabbit): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Irritation (Rabbit): Data available. Moderately irritating to skin with prolonged exposure. Based on test data for structurally similar materials. Eye Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials. CHRONIC/OTHER EFFECTS For the product itself: Sensitisation: Non-sensitising to the skin of laboratory animals. Vapour concentrations above recommended exposure levels are irritating to the eyes and the respiratory tract, may cause headaches and dizziness, are anaesthetic and may have other central nervous system effects. Small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema. Diesel fuel: Carcinogenic in animal tests. Caused mutations in-vitro. Repeated dermal exposures to high concentrations in test animals resulted in reduced litter size and litter weight, and increased fetal resorptions at maternally toxic doses. Dermal exposure to high concentrations resulted in severe skin irritation with weight loss and some mortality. Inhalation exposure to high concentrations resulted in respiratory tract irritation, lung changes/infiltration/accumulation, and reduction in lung function. Diesel exhaust fumes: Carcinogenic in animal tests. Inhalation exposures to exhaust for 2 years in test animals resulted in lung tumours and Extract of particulate produced skin tumours in test animals. Caused mutations in-vitro. Contains: KEROSENE: Carcinogenic in animal tests. Lifetime skin painting tests produced tumours, but the mechanism is due to repeated cycles of skin damage and restorative hyperplasia. This mechanism is considered unlikely in humans where such prolonged skin irritation would not be tolerated. Did not cause mutations in-vitro. Inhalation of vapours did not result in reproductive or developmental effects in laboratory animals. Inhalation of high concentrations in animals resulted in respiratory tract irritation, lung changes and some reduction in lung function. Non-sensitizing in animal tests. MIDDLE DISTILLATES WITH CRACKED STOCKS: Carcinogenic in animal tests. Caused mutations in-vitro. Repeated dermal exposures to high concentrations in test animals resulted in reduced litter size and litter weight, and increased fetal resorptions at maternally toxic doses. Dermal exposure to high concentrations resulted in severe skin irritation with weight loss and some mortality. Inhalation exposure to high concentrations resulted in respiratory tract irritation, lung Page 347 of 1287 Page 347 of 1287 Page 347 of 1287 Page 347 of 1287 ---PAGE BREAK--- Product Name: DIESEL/BIODIESEL BLEND Revision Date: 23 Dec 2014 Page 8 of 12 changes/infiltration/accumulation, and reduction in lung function. NAPHTHALENE: Exposure to high concentrations of naphthalene may cause destruction of red blood cells, anemia, and cataracts. Naphthalene caused cancer in laboratory animal studies, but the relevance of these findings to humans is uncertain. CMR Status: Chemical Name CAS Number List Citations FUEL OIL NO. 2 68476-30-2 4 KEROSENE, STRAIGHT RUN 8008-20-6 4 NAPHTHALENE 91-20-3 3, 4 --REGULATORY LISTS SEARCHED-- 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Expected to be toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. MOBILITY More volatile component Highly volatile, will partition rapidly to air. Not expected to partition to sediment and wastewater solids. High molecular wt. component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Material Expected to be inherently biodegradable Atmospheric Oxidation: More volatile component Expected to degrade rapidly in air SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Page 348 of 1287 Page 348 of 1287 Page 348 of 1287 Page 348 of 1287 ---PAGE BREAK--- Product Name: DIESEL/BIODIESEL BLEND Revision Date: 23 Dec 2014 Page 9 of 12 DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (TDG) Proper Shipping Name: FUEL OIL Hazard Class & Division: 3 UN Number: 1202 Packing Group: III LAND (DOT) Proper Shipping Name: DIESEL FUEL Hazard Class & Division: COMBUSTIBLE LIQUID ID Number: NA1993 Packing Group: III ERG Number: 128 Label(s): NONE Transport Document Name: NA1993, DIESEL FUEL, COMBUSTIBLE LIQUID, PG III Footnote: The flash point of this material is greater than 38ºC/100ºF. Regulatory classification of this material varies. DOT: Flammable liquid or combustible liquid. OSHA: Combustible liquid. IATA/IMO: Flammable liquid. This material is not regulated under 49 CFR in a container of 450 litre/119 gallon capacity or less when transported solely by land, as long as the material is not a hazardous waste, a marine pollutant, or specifically listed as a hazardous substance. SEA (IMDG) Proper Shipping Name: GAS OIL Hazard Class & Division: 3 EMS Number: F-E, S-E UN Number: 1202 Packing Group: III Label(s): 3 Transport Document Name: UN1202, GAS OIL, 3, PG III, (38°C c.c.) AIR (IATA) Proper Shipping Name: GAS OIL Hazard Class & Division: 3 UN Number: 1202 Packing Group: III Label(s) / Mark(s): 3 Transport Document Name: UN1202, GAS OIL, 3, PG III Page 349 of 1287 Page 349 of 1287 Page 349 of 1287 Page 349 of 1287 ---PAGE BREAK--- Product Name: DIESEL/BIODIESEL BLEND Revision Date: 23 Dec 2014 Page 10 of 12 SECTION 15 REGULATORY INFORMATION WHMIS Classification: Class B, Division 3: Combustible Liquids Class D, Division 2, Subdivision B: Toxic Material This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Listed or exempt from listing/notification on the following chemical inventories: DSL The Following Ingredients are Cited on the Lists Below: None. --REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: No revision information is available. SYNONYMS: DIESEL LOW SULPHUR 2% biodiesel, DIESEL LOW SULPHUR 20% biodiesel, DIESEL LOW SULPHUR 5% biodiesel, DIESEL LOW SULPHUR DYED 1% biodiesel, DIESEL LOW SULPHUR DYED 10% biodiesel, DIESEL LOW SULPHUR DYED with BIO up to 10%, DIESEL LOW SULPHUR DYED may contain biodiesel, DIESEL LOW SULPHUR may contain biodiesel, FURNACE FUEL DYED may contain biodiesel, DIESEL LOW SULPHUR RAIL may contain biodiesel, DIESEL LOW SULPHUR RAIL DYED may contain biodiesel, DIESEL LOW SULPHUR 1% biodiesel, DIESEL LOW SULPHUR 10% biodiesel, BIODIESEL BLEND B2, BIODIESEL BLEND B5, BIODIESEL BLEND B20, DIESEL LOW SULPHUR with BIO up to 10%, DIESEL LOW SULPHUR DYED 2% biodiesel, DIESEL LOW SULPHUR DYED 20% biodiesel, DIESEL LOW SULPHUR DYED 5% biodiesel, DIESEL LS RAIL 5% biodiesel, DIESEL LS RAIL DYED 5% biodiesel, FURNACE FUEL DYED 5% biodiesel, DIESEL LOW SULPHUR RAIL 5% biodiesel, DIESEL LOW SULPHUR RAIL DYED 5% biodiesel, BIODIESEL BLEND B10 PRECAUTIONARY LABEL TEXT: WHMIS Classification: Class B, Division 3: Combustible Liquids Class D, Division 2, Subdivision B: Toxic Material HEALTH HAZARDS Irritating to skin. May cause cancer. If swallowed, may be aspirated and cause lung damage. PHYSICAL HAZARDS Page 350 of 1287 Page 350 of 1287 Page 350 of 1287 Page 350 of 1287 ---PAGE BREAK--- Product Name: DIESEL/BIODIESEL BLEND Revision Date: 23 Dec 2014 Page 11 of 12 FLAMMABLE. In use, may form flammable/explosive vapour-air mixture. Combustible. Material can accumulate static charges which may cause an ignition. PRECAUTIONS Avoid contact with skin. Do not siphon by mouth. Use proper bonding and/or earthing procedures.However, bonding and earthing may not eliminate the hazard from static accumulation. FIRST AID Eye: Flush thoroughly with water. If irritation occurs, get medical assistance. Oral: Seek immediate medical attention. Do not induce vomiting. Skin: Remove contaminated clothing. Dry wipe exposed skin and cleanse with waterless hand cleaner and follow by washing thoroughly with soap and water. For those providing assistance, avoid further skin contact to yourself or others. Wear impervious gloves. Launder contaminated clothing separately before reuse. Discard contaminated articles that cannot be laundered. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. FIRE FIGHTING MEDIA Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPILL/LEAK Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Water Spill: Stop leak if you can do so without risk. Eliminate sources of ignition. Warn other shipping. If the Flash Point exceeds the Ambient Temperature by 10 deg C or more, use containment booms and remove from the surface by skimming or with suitable absorbents when conditions permit. If the Flash Point does not exceed the Ambient Air Temperature by at least 10C, use booms as a barrier to protect shorelines and allow material to evaporate. Seek the advice of a specialist before using dispersants. The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. DGN: 7093830 (1016263) Copyright 2002 Imperial Oil Limited, All rights reserved Page 351 of 1287 Page 351 of 1287 Page 351 of 1287 Page 351 of 1287 ---PAGE BREAK--- Product Name: DIESEL/BIODIESEL BLEND Revision Date: 23 Dec 2014 Page 12 of 12 Prepared by: Imperial Oil Limited, IH and Product Safety Page 352 of 1287 Page 352 of 1287 Page 352 of 1287 Page 352 of 1287 ---PAGE BREAK--- page 1 of 4 HMIS Codes Health 1* Flammability 0 Reactivity 0 DATE OF PREPARATION Feb 2, 2012 MATERIAL SAFETY DATA SHEET DB19-10 18 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DB19-10 PRODUCT NAME DIRT FIGHTER® Exterior Acrylic Latex Semi-Gloss Finish, White MANUFACTURER'S NAME DUTCH BOY 101 Prospect Avenue N.W. Cleveland, OH 44115 Telephone Numbers and Websites Product Information www.dutchboy.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident) * SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 0.3 14464-46-1 Cristobalite ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.05 mg/m3 as Resp. Dust 13 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 2 1314-13-2 Zinc Oxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. Page 353 of 1287 Page 353 of 1287 Page 353 of 1287 Page 353 of 1287 ---PAGE BREAK--- DB19-10 page 2 of 4 UEL N.A. LEL N.A. FLASH POINT Not Applicable SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 9.73 lb/gal 1166 g/l SPECIFIC GRAVITY 1.17 BOILING POINT 212 - 213 °F 100 - 100 °C MELTING POINT Not Available VOLATILE VOLUME 69% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 9.2 Page 354 of 1287 Page 354 of 1287 Page 354 of 1287 Page 354 of 1287 ---PAGE BREAK--- DB19-10 page 3 of 4 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.32 lb/gal 39 g/l Less Water and Federally Exempt Solvents 0.10 lb/gal 12 g/l Emitted VOC SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." TOXICOLOGY DATA CAS No. Ingredient Name 14464-46-1 Cristobalite LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available 1314-13-2 Zinc Oxide LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. IATA/ICAO Not Regulated for Transportation. Page 355 of 1287 Page 355 of 1287 Page 355 of 1287 Page 355 of 1287 ---PAGE BREAK--- DB19-10 page 4 of 4 SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element Zinc Compound 2 1.6 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 356 of 1287 Page 356 of 1287 Page 356 of 1287 Page 356 of 1287 ---PAGE BREAK--- page 1 of 4 HMIS Codes Health 2* Flammability 3 Reactivity 0 DATE OF PREPARATION Jan 9, 2015 MATERIAL SAFETY DATA SHEET BCP102 07 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER BCP102 PRODUCT NAME DUPLI-COLOR® Brake Caliper Paint, Black MANUFACTURER'S NAME Dupli-Color Products Company Cleveland, OH 44115 Telephone Numbers and Websites Product Information (800) 247-3270 www.dupli-color.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 15 74-98-6 Propane ACGIH TLV 1000 PPM 760 mm OSHA PEL 1000 PPM 14 106-97-8 Butane ACGIH TLV 1000 PPM 760 mm OSHA PEL 800 PPM 21 108-88-3 Toluene ACGIH TLV 20 PPM 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 30 67-64-1 Acetone ACGIH TLV 500 PPM 180 mm ACGIH TLV 750 PPM STEL OSHA PEL 1000 PPM 2 763-69-9 Ethyl 3-Ethoxypropionate ACGIH TLV Not Available 1.11 mm OSHA PEL Not Available 0.9 1333-86-4 Carbon Black ACGIH TLV 3.5 MG/M3 OSHA PEL 3.5 MG/M3 % by Weight Ingredient 0.02 Chromium III (as Cr) SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver Page 357 of 1287 Page 357 of 1287 Page 357 of 1287 Page 357 of 1287 ---PAGE BREAK--- BCP102 page 2 of 4 UEL 12.8 LEL 1.0 FLASH POINT Propellant < 0 °F the urinary system the cardiovascular system the reproductive system SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. Page 358 of 1287 Page 358 of 1287 Page 358 of 1287 Page 358 of 1287 ---PAGE BREAK--- BCP102 page 3 of 4 When sanding, wirebrushing, abrading, burning or welding the dried film, wear a particulate respirator approved by NIOSH/MSHA for protection against non-volatile materials in Section 2. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 6.16 lb/gal 737 g/l SPECIFIC GRAVITY 0.74 BOILING POINT <0 - 342 °F <-18 - 172 °C MELTING POINT Not Available VOLATILE VOLUME 88% EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 52.92% Less Water and Federally Exempt Solvents SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide , Oxides of Metals in Section 2 HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Carbon Black is classified by IARC as possibly carcinogenic to humans (group 2B) based on experimental animal data, however, there is insufficient evidence in humans for its carcinogenicity. TOXICOLOGY DATA CAS No. Ingredient Name 74-98-6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106-97-8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 108-88-3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 67-64-1 Acetone LC50 RAT 4HR Not Available LD50 RAT 5800 mg/kg 763-69-9 Ethyl 3-Ethoxypropionate LC50 RAT 4HR Not Available LD50 RAT Not Available 1333-86-4 Carbon Black LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Page 359 of 1287 Page 359 of 1287 Page 359 of 1287 Page 359 of 1287 ---PAGE BREAK--- BCP102 page 4 of 4 SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability and extractability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U IATA/ICAO UN1950, AEROSOLS, FLAMMABLE, 2.1, LIMITED QUANTITY SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 108-88-3 Toluene 21 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 360 of 1287 Page 360 of 1287 Page 360 of 1287 Page 360 of 1287 ---PAGE BREAK--- page 1 of 5 DATE OF PREPARATION Mar 5, 2015 MATERIAL SAFETY DATA SHEET TR250A 02 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER TR250A PRODUCT NAME DUPLI-COLOR™ Low VOC Truck Bed Coating, Black MANUFACTURER'S NAME Dupli-Color Products Company Cleveland, OH 44115 Telephone Numbers and Websites Product Information (800) 247-3270 www.dupli-color.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 14 74-98-6 Propane ACGIH TLV 1000 PPM 760 mm OSHA PEL 1000 PPM 6 106-97-8 Butane ACGIH TLV 1000 PPM 760 mm OSHA PEL 800 PPM 18 108-88-3 Toluene ACGIH TLV 20 PPM 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 3 29911-28-2 1-(2-Butoxymethylethoxy)-propanol ACGIH TLV Not Available 0.06 mm OSHA PEL Not Available 15 78-93-3 Methyl Ethyl Ketone ACGIH TLV 200 PPM 90.6 mm ACGIH TLV 300 PPM STEL OSHA PEL 200 PPM OSHA PEL 300 PPM STEL 5 79-20-9 Methyl Acetate ACGIH TLV 200 PPM 171 mm ACGIH TLV 250 PPM STEL OSHA PEL 200 PPM OSHA PEL 250 PPM STEL 6 108-65-6 1-Methoxy-2-Propanol Acetate ACGIH TLV Not Available 1.8 mm OSHA PEL Not Available 13 14808-60-7 Quartz ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.1 mg/m3 as Resp. Dust 0.6 1333-86-4 Carbon Black ACGIH TLV 3.5 MG/M3 OSHA PEL 3.5 MG/M3 SECTION 3 — HAZARDS IDENTIFICATION Page 361 of 1287 Page 361 of 1287 Page 361 of 1287 Page 361 of 1287 ---PAGE BREAK--- TR250A page 2 of 5 UEL 20.4 LEL 0.6 FLASH POINT Propellant < 0 °F HMIS Codes Health 2* Flammability 3 Reactivity 0 ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system the hematopoietic (blood-forming) system the cardiovascular system the reproductive system SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. Page 362 of 1287 Page 362 of 1287 Page 362 of 1287 Page 362 of 1287 ---PAGE BREAK--- TR250A page 3 of 5 SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 7.19 lb/gal 861 g/l SPECIFIC GRAVITY 0.87 BOILING POINT <0 - 449 °F <-18 - 231 °C MELTING POINT Not Available VOLATILE VOLUME 80% EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available pH > 2.0, < 11.5 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 63.48% Less Water and Federally Exempt Solvents SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Methyl Ethyl Ketone may increase the nervous system effects of other solvents. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. Carbon Black is classified by IARC as possibly carcinogenic to humans (group 2B) based on experimental animal data, however, there is insufficient evidence in humans for its carcinogenicity. Page 363 of 1287 Page 363 of 1287 Page 363 of 1287 Page 363 of 1287 ---PAGE BREAK--- TR250A page 4 of 5 TOXICOLOGY DATA CAS No. Ingredient Name 74-98-6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106-97-8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 108-88-3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 29911-28-2 1-(2-Butoxymethylethoxy)-propanol LC50 RAT 4HR Not Available LD50 RAT Not Available 78-93-3 Methyl Ethyl Ketone LC50 RAT 4HR Not Available LD50 RAT 2740 mg/kg 79-20-9 Methyl Acetate LC50 RAT 4HR Not Available LD50 RAT Not Available 108-65-6 1-Methoxy-2-Propanol Acetate LC50 RAT 4HR Not Available LD50 RAT 8500 mg/kg 14808-60-7 Quartz LC50 RAT 4HR Not Available LD50 RAT Not Available 1333-86-4 Carbon Black LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U IATA/ICAO UN1950, AEROSOLS, FLAMMABLE, 2.1, LIMITED QUANTITY SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 108-88-3 Toluene 18 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. Page 364 of 1287 Page 364 of 1287 Page 364 of 1287 Page 364 of 1287 ---PAGE BREAK--- TR250A page 5 of 5 TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 365 of 1287 Page 365 of 1287 Page 365 of 1287 Page 365 of 1287 ---PAGE BREAK--- page 1 of 5 HMIS Codes Health 2* Flammability 3 Reactivity 0 DATE OF PREPARATION Aug 4, 2014 MATERIAL SAFETY DATA SHEET TRG252 01 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER TRG252 PRODUCT NAME DUPLI-COLOR™ Truck Bed Coating, Black MANUFACTURER'S NAME Dupli-Color Products Company Cleveland, OH 44115 Telephone Numbers and Websites Product Information (800) 247-3270 www.dupli-color.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 2 64742-88-7 Mineral Spirits 140-Flash ACGIH TLV 100 PPM 0.5 mm OSHA PEL 100 PPM 3 64742-95-6 Light Aromatic Hydrocarbons ACGIH TLV Not Available 3.8 mm OSHA PEL Not Available 1 108-67-8 ACGIH TLV 25 PPM 2 mm OSHA PEL 25 PPM 5 95-63-6 ACGIH TLV 25 PPM 2.03 mm OSHA PEL 25 PPM 16 98-56-6 p-Chlorobenzotrifluoride ACGIH TLV Not Available 5.3 mm OSHA PEL Not Available 36 67-64-1 Acetone ACGIH TLV 500 PPM 180 mm ACGIH TLV 750 PPM STEL OSHA PEL 1000 PPM 14 14808-60-7 Quartz ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.1 mg/m3 as Resp. Dust 1 1333-86-4 Carbon Black ACGIH TLV 3.5 MG/M3 OSHA PEL 3.5 MG/M3 SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. Page 366 of 1287 Page 366 of 1287 Page 366 of 1287 Page 366 of 1287 ---PAGE BREAK--- TRG252 page 2 of 5 UEL 12.8 LEL 0.7 FLASH POINT 10 °F PMCC May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system the reproductive system SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION RED LABEL Extremely Flammable, Flash below 21 °F EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY DOL Storage Class IB PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Contents are EXTREMELY FLAMMABLE. Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper Page 367 of 1287 Page 367 of 1287 Page 367 of 1287 Page 367 of 1287 ---PAGE BREAK--- TRG252 page 3 of 5 containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 8.55 lb/gal 1024 g/l SPECIFIC GRAVITY 1.03 BOILING POINT 132 - 416 °F 55 - 213 °C MELTING POINT Not Available VOLATILE VOLUME 73% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 2.57 lb/gal 309 g/l Less Water and Federally Exempt Solvents 1.07 lb/gal 129 g/l Emitted VOC SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. Carbon Black is classified by IARC as possibly carcinogenic to humans (group 2B) based on experimental animal data, however, there is insufficient evidence in humans for its carcinogenicity. Page 368 of 1287 Page 368 of 1287 Page 368 of 1287 Page 368 of 1287 ---PAGE BREAK--- TRG252 page 4 of 5 TOXICOLOGY DATA CAS No. Ingredient Name 64742-88-7 Mineral Spirits 140-Flash LC50 RAT 4HR Not Available LD50 RAT Not Available 64742-95-6 Light Aromatic Hydrocarbons LC50 RAT 4HR Not Available LD50 RAT Not Available 108-67-8 LC50 RAT 4HR Not Available LD50 RAT Not Available 95-63-6 LC50 RAT 4HR Not Available LD50 RAT Not Available 98-56-6 p-Chlorobenzotrifluoride LC50 RAT 4HR Not Available LD50 RAT Not Available 67-64-1 Acetone LC50 RAT 4HR Not Available LD50 RAT 5800 mg/kg 14808-60-7 Quartz LC50 RAT 4HR Not Available LD50 RAT Not Available 1333-86-4 Carbon Black LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) 5 Liters (1.3 Gallons) and Less may be Classed as LTD. QTY. (PAINT OR RELATED). Larger Containers are Regulated as: UN1263, PAINT, 3, PG II, (ERG#128) DOT (Dept of Transportation) Hazardous Substances & Reportable Quantities Acetone 5000 lb RQ Xylenes (isomers and mixture) 100 lb RQ Bulk Containers may be Shipped as (check reportable quantities): UN1263, PAINT, 3, PG II, (ERG#128) Canada (TDG) UN1263, PAINT, CLASS 3, PG II, LIMITED QUANTITY, (ERG#128) IMO 5 Liters (1.3 Gallons) and Less may be Shipped as Limited Quantity. UN1263, PAINT, CLASS 3, PG II, (-12 C EmS F-E, S-E IATA/ICAO UN1263, PAINT, 3, PG II SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 95-63-6 5 Page 369 of 1287 Page 369 of 1287 Page 369 of 1287 Page 369 of 1287 ---PAGE BREAK--- TRG252 page 5 of 5 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 370 of 1287 Page 370 of 1287 Page 370 of 1287 Page 370 of 1287 ---PAGE BREAK--- Material Safety Data Sheet DURATRAN TM/MC 000003001023 Version 3.0 Revision Date 2015/02/12 Print Date 2015/02/12 Internet: lubricants.petro-canada.ca/msds Page: 1 / 9 Petro-Canada is a Suncor Energy business. TM Trademark of Suncor Energy Inc. Used under licence. SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : DURATRAN TM/MC Product code : DTRANP5R, DTRANP20, DTRANIBC, DTRANDRR, DTRANDRM, DTRANDR1, DTRANDCT, DTRANC16, DTRANC02, DTRAN, DTRANBLK Manufacturer or supplier's details Petro-Canada America Lubricants Inc. 115N Oak Park Avenue #1C Oak Park IL 60301-1366 United States Emergency telephone number Suncor Energy: +1 [PHONE REDACTED]; Poison Control Centre: Consult local telephone directory for emergency number(s). Recommended use of the chemical and restrictions on use Recommended use : Transmission hydraulic fluid (THF) designed to meet the requirements of modern agricultural, construction and mining equipment with a common sump to lubricate multiple systems such as transmissions, hydraulics, wet brakes and PTO gear boxes. Prepared by : Product Safety: +1 [PHONE REDACTED] SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Appearance viscous liquid Colour Yellow/amber. Odour No odour or slight petroleum oil like. GHS Classification Not a hazardous substance or mixture. GHS Label element Not a hazardous substance or mixture. Potential Health Effects Primary Routes of Entry : Eye contact Ingestion Inhalation Skin contact Aggravated Medical : None known. Page 371 of 1287 Page 371 of 1287 Page 371 of 1287 Page 371 of 1287 ---PAGE BREAK--- Material Safety Data Sheet DURATRAN TM/MC 000003001023 Version 3.0 Revision Date 2015/02/12 Print Date 2015/02/12 Internet: lubricants.petro-canada.ca/msds Page: 2 / 9 Petro-Canada is a Suncor Energy business. TM Trademark of Suncor Energy Inc. Used under licence. Condition Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Hazardous components Chemical Name CAS-No. Concentration distillates (petroleum), hydrotreated heavy paraffinic 64742-54-7 70 - 90 % lubricating oils (petroleum), C15-30, hydrotreated neutral oil-based 72623-86-0 30 - 50 % Mineral oil 1 - 5 % distillates (petroleum), hydrotreated light paraffinic 64742-55-8 1 - 5 % Polymer 1 - 5 % zinc bis(dithiophosphate) 4259-15-8 1 - 5 % SECTION 4. FIRST AID MEASURES If inhaled : Move to fresh air. Artificial respiration and/or oxygen may be necessary. Seek medical advice. In case of skin contact : In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Wash clothing before reuse. Seek medical advice. Page 372 of 1287 Page 372 of 1287 Page 372 of 1287 Page 372 of 1287 ---PAGE BREAK--- Material Safety Data Sheet DURATRAN TM/MC 000003001023 Version 3.0 Revision Date 2015/02/12 Print Date 2015/02/12 Internet: lubricants.petro-canada.ca/msds Page: 3 / 9 Petro-Canada is a Suncor Energy business. TM Trademark of Suncor Energy Inc. Used under licence. In case of eye contact : Remove contact lenses. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention. If swallowed : Rinse mouth with water. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. Seek medical advice. Most important and effects, both acute and delayed : First aider needs to protect himself. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media : No information available. Specific hazards during firefighting : Cool closed containers exposed to fire with water spray. Hazardous combustion products : Carbon oxides (CO, CO2), nitrogen oxides (NOx), sulphur oxides (SOx), phosphorus oxides (POx), calcium oxides (CaOx), zinc oxides (ZnOx), smoke and irritating vapours as products of incomplete combustion. Further information : Prevent fire extinguishing water from contaminating surface water or the ground water system. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas. Material can create slippery conditions. Environmental precautions : If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Prevent further leakage or spillage if safe to do so. Remove all sources of ignition. Soak up with inert absorbent material. Non-sparking tools should be used. Ensure adequate ventilation. Contact the proper local authorities. Page 373 of 1287 Page 373 of 1287 Page 373 of 1287 Page 373 of 1287 ---PAGE BREAK--- Material Safety Data Sheet DURATRAN TM/MC 000003001023 Version 3.0 Revision Date 2015/02/12 Print Date 2015/02/12 Internet: lubricants.petro-canada.ca/msds Page: 4 / 9 Petro-Canada is a Suncor Energy business. TM Trademark of Suncor Energy Inc. Used under licence. SECTION 7. HANDLING AND STORAGE Advice on safe handling : For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid contact with skin, eyes and clothing. Do not ingest. Keep away from heat and sources of ignition. Keep container closed when not in use. Conditions for safe storage : Store in original container. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Keep in a dry, cool and well-ventilated place. Keep in properly labelled containers. To maintain product quality, do not store in heat or direct sunlight. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Contains no substances with occupational exposure limit values. Engineering measures : No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Filter type : organic vapour filter Hand protection Material : neoprene, nitrile, polyvinyl alcohol (PVA), Viton(R). Remarks : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Eye protection : Wear face-shield if splashing hazard is likely. Skin and body protection : Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place. Page 374 of 1287 Page 374 of 1287 Page 374 of 1287 Page 374 of 1287 ---PAGE BREAK--- Material Safety Data Sheet DURATRAN TM/MC 000003001023 Version 3.0 Revision Date 2015/02/12 Print Date 2015/02/12 Internet: lubricants.petro-canada.ca/msds Page: 5 / 9 Petro-Canada is a Suncor Energy business. TM Trademark of Suncor Energy Inc. Used under licence. Protective measures : Wash hands and face before breaks and immediately after handling the product. Wash contaminated clothing before re-use. Ensure that eyewash station and safety shower are proximal to the work-station location. Hygiene measures : Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash face, hands and any exposed skin thoroughly after handling. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : viscous liquid Colour : Yellow/amber. Odour : No odour or slight petroleum oil like. Odour Threshold : No data available pH : No data available Pour point : -45 °C (-49 Boiling point/boiling range : No data available Flash point : 239 °C (462 Method: Cleveland open cup Fire Point : 267 °C (513 Auto-Ignition Temperature : No data available Evaporation rate : No data available Flammability : Low fire hazard. This material must be heated before ignition will occur. Upper explosion limit : No data available Lower explosion limit : No data available Vapour pressure : No data available Relative vapour density : No data available Density : 0.8538 kg/l (15 °C / 59 Solubility(ies) Water solubility : insoluble Partition coefficient: n- octanol/water : No data available Viscosity Viscosity, kinematic : 60.09 cSt (40 °C / 104 9.53 cSt (100 °C / 212 Page 375 of 1287 Page 375 of 1287 Page 375 of 1287 Page 375 of 1287 ---PAGE BREAK--- Material Safety Data Sheet DURATRAN TM/MC 000003001023 Version 3.0 Revision Date 2015/02/12 Print Date 2015/02/12 Internet: lubricants.petro-canada.ca/msds Page: 6 / 9 Petro-Canada is a Suncor Energy business. TM Trademark of Suncor Energy Inc. Used under licence. Explosive properties : Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. SECTION 10. STABILITY AND REACTIVITY Possibility of hazardous reactions : Hazardous polymerisation does not occur. Stable under normal conditions. Conditions to avoid : No data available Incompatible materials : Reactive with reducing agents, oxidising agents and acids. Hazardous decomposition products : May release COx, H2S, methacrylate monomers, aldehydes, alkyl mercaptans, sulfides, smoke and irritating vapours when heated to decomposition. SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Eye contact Ingestion Inhalation Skin contact Acute toxicity Product: Acute oral toxicity Remarks: No data available Acute inhalation toxicity Remarks: No data available Acute dermal toxicity Remarks: No data available Components: lubricating oils (petroleum), C15-30, hydrotreated neutral oil-based: Acute oral toxicity LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity LC50 (Rat): > 5.2 mg/l Exposure time: 4 h Test atmosphere: dust/mist Acute dermal toxicity LD50 (Rabbit): > 2,000 mg/kg Skin corrosion/irritation Product: Remarks: No data available Page 376 of 1287 Page 376 of 1287 Page 376 of 1287 Page 376 of 1287 ---PAGE BREAK--- Material Safety Data Sheet DURATRAN TM/MC 000003001023 Version 3.0 Revision Date 2015/02/12 Print Date 2015/02/12 Internet: lubricants.petro-canada.ca/msds Page: 7 / 9 Petro-Canada is a Suncor Energy business. TM Trademark of Suncor Energy Inc. Used under licence. Serious eye damage/eye irritation Product: Remarks: No data available Respiratory or skin sensitisation No data available Germ cell mutagenicity No data available Carcinogenicity No data available Reproductive toxicity No data available STOT - single exposure No data available STOT - repeated exposure No data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Toxicity to fish : Remarks: No data available Toxicity to daphnia and other aquatic invertebrates : Remarks: No data available Toxicity to algae : Remarks: No data available Toxicity to bacteria : Remarks: No data available Persistence and degradability Product: Biodegradability : Remarks: No data available Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available Page 377 of 1287 Page 377 of 1287 Page 377 of 1287 Page 377 of 1287 ---PAGE BREAK--- Material Safety Data Sheet DURATRAN TM/MC 000003001023 Version 3.0 Revision Date 2015/02/12 Print Date 2015/02/12 Internet: lubricants.petro-canada.ca/msds Page: 8 / 9 Petro-Canada is a Suncor Energy business. TM Trademark of Suncor Energy Inc. Used under licence. SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : The product should not be allowed to enter drains, water courses or the soil. Offer surplus and non-recyclable solutions to a licensed disposal company. Waste must be classified and labelled prior to recycling or disposal. Send to a licensed waste management company. Dispose of as hazardous waste in compliance with local and national regulations. Dispose of product residue in accordance with the instructions of the person responsible for waste disposal. SECTION 14. TRANSPORT INFORMATION International Regulation IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. 49 CFR Not regulated as a dangerous good TDG Not regulated as a dangerous good Special precautions for user Not applicable SECTION 15. REGULATORY INFORMATION OSHA Hazards : No OSHA Hazards The components of this product are reported in the following inventories: DSL On the inventory, or in compliance with the inventory TSCA All chemical substances in this product are either listed on the TSCA Inventory or are in compliance with a TSCA Inventory exemption. IECSC On the inventory, or in compliance with the inventory EINECS On the inventory, or in compliance with the inventory SECTION 16. OTHER INFORMATION Page 378 of 1287 Page 378 of 1287 Page 378 of 1287 Page 378 of 1287 ---PAGE BREAK--- Material Safety Data Sheet DURATRAN TM/MC 000003001023 Version 3.0 Revision Date 2015/02/12 Print Date 2015/02/12 Internet: lubricants.petro-canada.ca/msds Page: 9 / 9 Petro-Canada is a Suncor Energy business. TM Trademark of Suncor Energy Inc. Used under licence. Further information NFPA: HMIS III: For Copy of (M)SDS : Internet: lubricants.petro-canada.ca/msds United States, telephone: 1-[PHONE REDACTED]; fax: 1-800-201- 6285 For Product Safety Information: 1 [PHONE REDACTED] Prepared by : Product Safety: +1 [PHONE REDACTED] The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Flammability Health Instability 1 1 0 Special hazard. FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 1 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic PERSONAL PROTECTION B Page 379 of 1287 Page 379 of 1287 Page 379 of 1287 Page 379 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET EQUILON MSDS: 60982E-01 01/04/99 DUREX ND SAE 30 TELEPHONE NUMBER: 24 HOUR EMERGENCY ASSISTANCE GENERAL MSDS ASSISTANCE EQUIVA SERVICES: [PHONE REDACTED] [PHONE REDACTED] CHEMTREC: [PHONE REDACTED] NAME AND ADDRESS EQUILON ENTERPRISES LLC PRODUCT STEWARDSHIP P.O. BOX 674414 HOUSTON, TX 77267-4414 SECTION I NAME PRODUCT: DUREX ND SAE 30 CHEM NAME: MIXTURE (SEE SECTION II-A) CHEM FAMILY: PETROLEUM HYDROCARBON; MOTOR OIL SHELL CODE: 52061 HEALTH HAZARD: 1 FIRE HAZARD: 1 REACTIVITY: 0 SECTION II-A PRODUCT/INGREDIENT NO. COMPOSITION CAS NO. PERCENT P DUREX ND SAE 30 1 SOL. REF., HYDROTREATED, ACID TREATED HEAVY 64742-18-3 60-65 NAPHTHENIC DIST. 2 HYDROTREATED HEAVY PARAFFINIC DISTILLATE 64742-54-7 35-40 3 MINOR ADDITIVES MIXTURE <2 NFPA HAZARD RATING: HEALTH 0 FIRE 1 REACTIVITY 0 SECTION II-B ACUTE TOXICITY DATA NO. ACUTE ORAL LD50 ACUTE DERMAL LD50 ACUTE INHALATION LC50 P NOT AVAILABLE SECTION III HEALTH INFORMATION THE HEALTH EFFECTS NOTED BELOW ARE CONSISTENT WITH REQUIREMENTS UNDER THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). EYE CONTACT: LUBRICATING OILS ARE GENERALLY CONSIDERED NO MORE THAN MINIMALLY IRRITATING TO THE EYES. SKIN CONTACT: LUBRICATING OILS ARE GENERALLY CONSIDERED NO MORE THAN MILDLY IRRITATING TO THE SKIN. PROLONGED AND REPEATED CONTACT MAY RESULT IN VARIOUS SKIN DISORDERS SUCH AS DERMATITIS, FOLLICULITIS OR OIL ACNE. INHALATION: INHALATION OF VAPOR (GENERATED AT HIGH TEMPERATURES ONLY) OR OIL MIST FROM THIS PRODUCT MAY RESULT IN MILD IRRITATION OF THE UPPER RESPIRATORY TRACT. INGESTION: LUBRICATING OILS ARE GENERALLY CONSIDERED NO MORE THAN TOXIC IF SWALLOWED. SIGNS AND IRRITATION AS NOTED ABOVE. AGGRAVATED MEDICAL CONDITIONS: PREEXISTING SKIN AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. OTHER HEALTH EFFECTS: THIS PRODUCT AND ITS COMPONENTS ARE NOT CLASSIFIED AS CARCINOGENS BY INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC), NATIONAL TOXOCOLOGY PROGRAM (NTP) OR OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA). THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER HAS DETERMINED THERE IS Page 380 of 1287 Page 380 of 1287 Page 380 of 1287 Page 380 of 1287 ---PAGE BREAK--- SUFFICIENT EVIDENCE FOR THE CARCINOGENICITY IN EXPERIMENTAL ANIMALS OF USED MOTOR OILS. HANDLING PROCEDURES AND SAFETY PRECAUTIONS IN THE MSDS SHOULD BE FOLLOWED TO MINIMIZE EMPLOYEE'S EXPOSURE TO THE USED PRODUCT. SECTION IV OCCUPATIONAL EXPOSURE LIMITS COMP OSHA ACGIH NO. PEL/TWA PEL/CEILING TLV/TWA TLV/STEL OTHER P 5 MG/M3* NONE 5 MG/M3* 10 MG/M3* *OIL MIST, MINERAL SECTION V EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT: FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN CONTACT: REMOVE CONTAMINATED CLOTHING AND WIPE EXCESS OFF. WASH WITH SOAP AND WATER OR A WATERLESS HAND CLEANER FOLLOWED BY SOAP AND WATER. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. INHALATION: REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. IN GENERAL NO TREATMENT IS NECESSARY UNLESS LARGE QUANTITIES OF PRODUCT ARE INGESTED. HOWEVER, GET MEDICAL ATTENTION. NOTE TO PHYSICIAN: IN GENERAL, EMESIS INDUCTION IS UNNECESSARY IN HIGH VISCOSITY, LOW VOLATILITY PRODUCTS, I.E., MOST OILS AND GREASES. SECTION VI SUPPLEMENTAL HEALTH INFORMATION NONE IDENTIFIED. SECTION VII PHYSICAL DATA BOILING POINT (DEG SPECFIC GRAVITY (H2O = VAPOR PRESSURE (MM HG): NOT AVAILABLE 0.9013 <0.1 MELTING POINT (DEG SOLUBILITY IN WATER: VAPOR DENSITY (AIR = -5 (POUR POINT) NEGLIGIBLE NOT AVAILABLE VISCOSITY: 98-125 (CS @ 104 DEG F) EVAPORATION RATE (NORMAL BUTYL ACETATE = 1):NOT AVAILABLE APPEARANCE AND ODOR:AMBER OIL. SLIGHT HYDROCARBON ODOR. PHYS/CHEM PROPERTIES: SEE ABOVE FOR DETAILS SECTION VIII FIRE AND EXPLOSION HAZARDS FLASH POINT AND METHOD: 370 DEG F (PMCC) FLAMMABLE LIMITS/PERCENT VOLUME IN AIR: LOWER: N/AV HIGHER: N/AV EXTINGUISHING MEDIA: USE WATER FOG, FOAM, DRY CHEMICAL OR CO2. DO NOT USE A DIRECT STREAM OF WATER. PRODUCT WILL FLOAT AND CAN BE REIGNITED ON SURFACE OF WATER. SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS: MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER CONFINED FIRE-SPACE WITHOUT FULL BUNKER GEAR (HELMET WITH FACE SHIELD, BUNKER COATS, GLOVES AND RUBBER BOOTS), INCLUDING A POSITIVE-PRESSURE NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER. UNUSUAL FIRE AND EXPLOSION HAZARDS: NONE IDENTIFIED SECTION IX REACTIVITY STABLITY: STABLE HAZARDOUS POLYMERIZATION WILL NOT OCCUR CONDITIONS AND MATERIALS TO AVOID: Page 381 of 1287 Page 381 of 1287 Page 381 of 1287 Page 381 of 1287 ---PAGE BREAK--- AVOID HEAT, OPEN FLAMES AND OXIDIZING MATERIALS. HAZARDOUS DECOMPOSITION PRODUCTS: THERMAL DECOMPOSITION PRODUCTS ARE HIGHLY DEPENDENT ON THE COMBUSTION CONDITIONS. A COMPLEX MIXTURE OF AIRBORNE SOLID, LIQUID, PARTICULATES AND GASES WILL EVOLVE WHEN THIS MATERIAL UNDERGOES PYROLYSIS OR COMBUSTION. CARBON MONOXIDE, OXIDES OF SULFUR, NITROGEN AND PHOSPHORUS, AND OTHER UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED UPON COMBUSTION. SECTION X EMPLOYEE PROTECTION RESPIRATORY PROTECTION: IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS (SECTION IV) USE A NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134 USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING RESPIRATOR FOR ORGANIC VAPORS AND PARTICULATES. PROTECTIVE CLOTHING WEAR CHEMICAL RESISTANT GLOVES AND OTHER PROTECTIVE CLOTHING AS REQUIRED TO MINIMIZE SKIN CONTACT. WEAR SAFETY GOGGLES TO AVOID EYE CONTACT. TEST DATA FROM PUBLISHED LITERATURE AND/OR GLOVE AND CLOTHING MANUFACTURERS INDICATE THE BEST PROTECTION IS PROVIDED BY NITRILE GLOVES. ADDITIONAL PROTECTIVE MEASURES: NONE IDENTIFIED SECTION XI ENVIRONMENTAL PROTECTION SPILL OR LEAK PROCEDURES: MAY BURN ALTHOUGH NO READILY IGNITABLE. USE CAUTIOUS JUDGMENT WHEN CLEANING UP LARGE SPILLS. LARGE SPILLS WEAR RESPIRATOR AND PROTECTIVE CLOTHING AS APPROPRIATE. SHUT OFF SOURCE OF LEAK IF SAFE TO DO SO. DIKE AND CONTAIN. REMOVE WITH VACUUM TRUCKS OR PUMP TO STORAGE SALVAGE VESSELS. SOAK UP RESIDUE WITH AN ABSORBENT SUCH AS CLAY, SAND, OR OTHER SUITABLE MATERIALS; DISPOSE OF PROPERLY. FLUSH AREA WITH WATER TO REMOVE TRACE RESIDUE. SMALL SPILLS TAKE UP WITH AN ABSORBENT MATERIAL AND DISPOSE OF PROPERLY. SECTION XII SPECIAL PRECAUTIONS MINIMIZE SKIN CONTACT. WASH WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. PROPERLY DISPOSE OF CONTAMINATED LEATHER ARTICLES, INCLUDING SHOES, THAT CANNOT BE DECONTAMINATED. STORE IN A COOL, DRY PLACE WITH ADEQUATE VENTILATION. KEEP AWAY FROM OPEN FLAMES AND HIGH TEMPERATURES. SECTION XIII TRANSPORTATION REQUIREMENTS DEPARTMENT OF TRANSPORTATION CLASSIFICATION: NOT HAZARDOUS BY D.O.T. REGULATIONS DOT PROPER SHIPPING NAME: NOT APPLICABLE OTHER REQUIREMENTS: NOT APPLICABLE SECTION XIV OTHER REGULATORY CONTROLS THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES. PROTECTION OF STRATOSPHERIC OZONE (PURSUANT TO SECTION 611 OF THE CLEAN AIR ACT AMENDMENTS OF 1990): PER 40 CFR PART 82, THIS PRODUCT DOES NOT CONTAIN NOR WAS IT DIRECTLY MANUFACTURED WITH ANY CLASS I OR CLASS II OZONE DEPLETING SUBSTANCES. IN ACCORDANCE WITH SARA TITLE III, SECTION 313, THE ATTACHED ENVIRONMENTAL DATA SHEET (EDS) SHOULD ALWAYS BE COPIED AND SENT WITH THE MSDS. SECTION XV STATE REGULATORY INFORMATION Page 382 of 1287 Page 382 of 1287 Page 382 of 1287 Page 382 of 1287 ---PAGE BREAK--- THE FOLLOWING CHEMICALS ARE SPECIFICALLY LISTED BY INDIVIDUAL STATES; OTHER PROD UCT SPECIFIC HEALTH AND SAFETY DATA IN OTHER SECTIONS OF THE MSDS MAY ALSO BE AP PLICABLE FOR STATE REQUIREMENTS. FOR DETAILS ON YOUR REGULATORY REQUIREMENTS YO U SHOULD CONTACT THE APPROPRIATE AGENCY IN YOUR STATE. STATE LISTED COMPONENT CAS NO PERCENT STATE CODE SOL. REF. HYDROTREATED ACID 64742-18-3 60-65 MA TREATED HEAVY NAPHTHENIC DISTILLATE CA = CALIFORNIA HAZ. SUBST. LIST; CA65C, CA65R, CA65C/R = CALIFORNIA SAFE DRINKING WATER AND TOXICS ENFORCEMENT ACT OF 1986 OR PROPOSITION 65 LIST; CT = CONNECTICUT TOXIC. SUBST. LIST; FL = FLORIDA SUBST. LIST; IL = ILLINOIS TOX. SUBST. LIST; LA = LOUISIANA HAZ. SUBST. LIST; MA = MASSACHUSETTS SUBST. LIST; ME = MAINE HAZ. SUBST. LIST; MN = MINNESOTA HAZ. SUBST. LIST; NJ = NEW JERSEY HAZ. SUBST. LIST; PA = HAZ. SUBST. LIST; RI = RHODE ISLAND HAZ. SUBST. LIST. SECTION XVI SPECIAL NOTES ORIGINAL ISSUE. THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE TO US AT THIS TIME, AND IS BELIEVED TO BE ACCURATE BASED UPON THAT DATA. IT IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT, FOR PURPOSE OF HAZARD COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE PRODUCT PERFORMANCE INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE WITH RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED HEREIN. YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY, PROCESS, USE OR DISTRIBUTE, AND ARE ENCOURAGED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN. TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH MATTERS, OR BE RESPONSIBLE FOR ANY INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. THE UNDERLYING DATA, AND THE INFORMATION PROVIDED HEREIN AS A RESULT OF THAT DATA, IS THE PROPERTY OF EQUIVA SERVICES, LLC AND IS NOT TO BE THE SUBJECT OF SALE OR EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF EQUIVA SERVICES, LLC. ENVIRONMENTAL DATA SHEET EQUILON EDS: 60982E DUREX ND SAE 30 TELEPHONE NUMBER: 24 HOUR EMERGENCY ASSISTANCE GENERAL MSDS ASSISTANCE EQUIVA SERVICES: [PHONE REDACTED] [PHONE REDACTED] CHEMTREC: [PHONE REDACTED] NAME AND ADDRESS EQUILON ENTERPRISES PRODUCT STEWARDSHIP P.O. BOX 674414 HOUSTON, TX 77267-4414 PRODUCT CODE: 52061 SECTION I PRODUCT COMPOSITION NO. COMPOSITION CAS PERCENT P DUREX ND SAE 30 MIXTURE 100 1 SOL. REG., HYDROTREATED, ACID TREATED HE 64742-18-3 60-65 AVY NAPHTHENIC DIST. 2 HYDROTREATED HEAVY PARAFFINIC DISTILLATE 64742-54-7 35-40 3 MINOR ADDITIVES MIXTURE <2 Page 383 of 1287 Page 383 of 1287 Page 383 of 1287 Page 383 of 1287 ---PAGE BREAK--- SECTION II SARA TITLE III INFORMATION NO. EHS RQ EHS TPQ SEC-313 313 CATEGORY 311/312 CATEGORY BASED ON THE DATA AVAILABLE, THIS PRODUCT IS NOT REGULATED BY SARA, TITLE III. *1 = REPORTABLE QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE, SEC 302 *2 = THRESHOLD PLANNING QUANTITY, EXTREMELY HAZARDOUS SUBSTANCE, SEC 302 *3 = TOXIC CHEMICAL, SEC 313 *4 = CATEGORY AS REQUIRED BY SEC 313 (40 CFR 372.65 MUST BE USED ON TOXIC RELEASE INVENTORY FORM *5 = CATEGORY (FOR AGGREGATE REPORTING REQUIREMENTS UNDER SARA 311, 312) HEALTH: H-1 = IMMEDIATE (ACUTE) HEALTH HAZARD H-2 = DELAYED (CHRONIC) HEALTH HAZARD PHYSICAL: P-3 = FIRE HAZARD P-4 = SUDDEN RELEASE OF PRESSURE HAZARD P-5 = REACTIVE HAZARD SECTION III ENVIRONMENTAL RELEASE INFORMATION THIS PRODUCT IS COVERED BY EPA'S COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT (CERCLA) PETROLEUM EXCLUSION. THEREFORE RELEASES TO AIR, LAND, OR WATER ARE NOT REPORTABLE UNDER CERCLA ("SUPERFUND"). HOWEVER UNDER SECTION 311 OF EPA'S CLEAN WATER ACT (CWA), THIS PRODUCT IS CONSIDERED AN OIL. AS SUCH , SPILLS INTO OR LEADING TO SURFACE WATERS THAT CAUSE A SHEEN MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER, [PHONE REDACTED]. THIS PRODUCT IS AN OIL UNDER 49 CFR (DOT) PART 130. IF SHIPPED BY RAIL OR HIGHWAY IN A TANK WITH A CAPACITY OF 3,500 GALLONS OR MORE, IT IS SUBJECT TO THE REQUIREMENTS OF PART 130. MIXTURE SOLUTIONS IN WHICH THIS PRODUCT IS PRESENT AT 10% OR MORE MAY ALSO BE SUBJECT TO THIS RULE. SECTION IV RCRA INFORMATION IF THIS PRODUCT BECOMES A WASTE, IT WOULD NOT BE A HAZARDOUS WASTE BY RCRA CRITERIA (40 CFR 261). PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN COMPLIANCE WITH LOCAL REGULATIONS. THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE TO US AT THIS TIME, AND IS BELIEVED TO BE ACCURATE BASED UPON THAT DATA. IT IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT, FOR PURPOSE OF HAZARD COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE PRODUCT PERFORMANCE INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE WITH RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED HEREIN. YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY, PROCESS, USE OR DISTRIBUTE, AND ARE ENCOURAGED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN. TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH MATTERS, OR BE RESPONSIBLE FOR ANY INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. THE UNDERLYING DATA, AND THE INFORMATION PROVIDED HEREIN AS A RESULT OF THAT DATA, IS THE PROPERTY OF EQUIVA SERVICES, LLC AND IS NOT TO BE THE SUBJECT OF SALE OR EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF EQUIVA SERVICES, LLC. KAREN G. HAYNES EQUIVA SERVICES LLC Page 384 of 1287 Page 384 of 1287 Page 384 of 1287 Page 384 of 1287 ---PAGE BREAK--- P.O. BOX 674414 HOUSTON, TX 77267-4414 FOR ADDITIONAL INFORMATION ON THIS ENVIRONMENTAL DATA PLEASE CALL (877) 276-7285 FOR EMERGENCY ASSISTANCE PLEASE CALL EQUIVA SERVICES LLC: (877) 276-7283 CHEMTREC: (800) 424-9300 } Page 385 of 1287 Page 385 of 1287 Page 385 of 1287 Page 385 of 1287 ---PAGE BREAK--- Material Safety Data Sheet F 1. Chemical Product and Company Identification DESCRIPTION: ELMER'S CARPENTERS WOOD GLUE PRODUCT TYPE: PVAC BASED ADHESIVE APPLICATION: FOR PRODUCT CODES SEE SECTION 16 • Manufacturer/Supplier Information MSDS Prepared by: Elmer's Products, Inc. Emergency Phone Number 1 Easton Oval Poison Control Center Columbus, OH 43219 1-[PHONE REDACTED] For additional health, safety or regulatory information, call 1-[PHONE REDACTED] Call 1-[PHONE REDACTED] to place an order or request additional 2. Composition, Information on Ingredients No hazardous ingredients known to company. 3. Hazards Identification 3.1 Emergency Overview Appearance Light yellow liquid Odor Mild acetic aroma Not an immediate health hazard. • HMIS Rating Page 1 of 7 E700_D ELMER'S CARPENTERS WOOD GLUE Page 386 of 1287 Page 386 of 1287 Page 386 of 1287 Page 386 of 1287 ---PAGE BREAK--- HEALTH = 0 (minimal) FLAMMABILITY = 0 (minimal) REACTIVITY = 0 (minimal) 3.2 Potential Health Effects • Immediate Hazards INGESTION: No hazards known to company. INHALATION: No hazards known to company. SKIN: No hazards known to company. EYES: No hazards known to company. • Delayed Hazards None of the components present in this product at concentrations equal to or greater than 0.1% have been listed by NTP, classified by IARC, nor regulated by OSHA as a carcinogen. 4. First Aid Measures INGESTION: If accidentally swallowed, dilute by drinking large quantities of water. Immediately contact poison control center or hospital emergency room for any other additional treatment directions. EYES: Immediately flush eyes with plenty of water. Call a physician if irritation persists. 5. Fire Fighting Measures Autoignition Temperature Not available Upper/Lower Flammable Limits Not applicable Up/Lower Explosive Limits, % by Vol Not applicable Flash Point Not applicable Will not burn unless water has evaporated. Dried material may burn. In case of fire, water should be used to keep fire-exposed containers cool. 6. Accidental Release Measures Soak up with absorbent material and remove to a chemical disposal Page 2 of 7 E700_D ELMER'S CARPENTERS WOOD GLUE Page 387 of 1287 Page 387 of 1287 Page 387 of 1287 Page 387 of 1287 ---PAGE BREAK--- area. Prevent entry into natural bodies of water. 7. Handling and Storage 7.1 Handling Handle in accordance with good industrial hygiene and safety practices. 7.2 Storage Keep from freezing. Store in a cool, dry place. Keep containers closed. 8. Exposure Controls/Personal Protection 8.1 Exposure Controls No special control measures necessary under normal conditions of use. 8.2 Personal Protection No special protection necessary. 8.3 Exposure Guidelines None established 9. Physical and Chemical Properties Percent Volatiles 54.5 pH @ 25 C 5.0 Specific Gravity 1.08 Appearance Light yellow liquid Autoignition Temperature Not available Page 3 of 7 E700_D ELMER'S CARPENTERS WOOD GLUE Page 388 of 1287 Page 388 of 1287 Page 388 of 1287 Page 388 of 1287 ---PAGE BREAK--- Boiling Point 100°C (212°F) Vapor Density (Air=1) <1 Vapor Pressure, mm Hg @ 20 C 17.5 Evaporation Rate (Butyl Acetate=1) <1 Upper/Lower Flammable Limits Not applicable Up/Lower Explosive Limits, % by Vol Not applicable Flash Point Not applicable Freezing Point 0°C (32°F) Odor Mild acetic aroma Odor Threshold, ppm Not available Solubility in Water Dispersible Coefficient of Water/Oil Distrib. Not available 10. Stability and Reactivity Normally stable as defined in NFPA 704-12(4-3.1). • Incompatibilities: Strong acids and alkaline materials. • Decomposition products may include: CO, CO2. • Hazardous polymerization: Will not occur. • Other Hazards: None known to company. 11. Toxicological Information INGESTION: A similar product was found to be non-toxic orally when tested as described in 16 CFR Part 1500.3(c)(1) and INHALATION: A similar product was found to be non-toxic by inhalation when tested as described in 16 CFR Part 1500.3 and SKIN A similar product was found to be non-toxic dermally ABSORPTION: when tested as described in 16 CFR Part 1500.3 and Page 4 of 7 E700_D ELMER'S CARPENTERS WOOD GLUE Page 389 of 1287 Page 389 of 1287 Page 389 of 1287 Page 389 of 1287 ---PAGE BREAK--- SKIN: A similar product was not an irritant when tested as described in 16 CFR Part 1500.41. EYES: A similar product was not an irritant when tested as described in 16 CFR Part 1500.42. 12. Ecological Information Not determined. 13. Disposal Considerations Recover free liquid. Absorb residue and dispose of according to local, state/provincial, and federal requirements. 14. Transport Information 14.1 U.S. Department of Transportation (DOT) The data provided in this section is for information only and may not be specific to your package size. You will need to apply the appropriate regulations to properly classify your shipment for transportation. Non-Regulated. 14.2 Canadian Transportation of Dangerous Goods (TDG) Non-Regulated. 15. Regulatory Information (Selected Regulations) 15.1 U.S. Federal Regulations • OSHA Hazard Communication Standard 29CFR1910.1200 This material is not a "health hazard" or a "physical hazard" as Page 5 of 7 E700_D ELMER'S CARPENTERS WOOD GLUE Page 390 of 1287 Page 390 of 1287 Page 390 of 1287 Page 390 of 1287 ---PAGE BREAK--- determined when reviewed according to the requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200 "Hazard Communication" Standard. • SARA Title III: Section 311/312 Does not meet any hazard category • SARA Title III Section 313 and 40 CFR Part 372 This product contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and Subpart C-Supplier Notification Requirement of 40 CFR Part 372. None required per SARA TITLE III SECTION 313. • TSCA Section 8(b) Inventory All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications of compliance from our suppliers for chemical substances not manufactured by us. 15.2 Canadian Regulations • Workplace Hazardous Materials Information System (WHMIS) This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR) and the MSDS contains all the information required by the CPR. Not a controlled product • Canadian Environmental Protection Act (CEPA) All reportable chemical substances are listed on the Domestic Substances List (DSL) or otherwise comply with CEPA new substance notification requirements. • National Pollutant Release Inventory (NPRI) This product contains the following chemical(s) subject to the Page 6 of 7 E700_D ELMER'S CARPENTERS WOOD GLUE Page 391 of 1287 Page 391 of 1287 Page 391 of 1287 Page 391 of 1287 ---PAGE BREAK--- reporting requirements of the Canadian Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release Inventory. None required. 16. Other Information AP (Non-Toxic): Products bearing the AP (Non-Toxic) Product Seal of The Art & Creative Materials Institute, Inc. (ACMI) are certified in a program of toxicological evaluation by a medical expert to contain no materials in sufficient quantities to be toxic or injurious to humans or to cause acute or chronic health problems. This program is reviewed by ACMI's Toxicological Advisory Board. These products are certified by ACMI to be labeled in accordance with the chronic hazard labeling standard, ASTM D-4236 and Federal Law, P.L. 100-695. In addition, there is no physical hazard as defined within 29 CFR Part 1910.1200(c). MSDS covers items: U.S.: E614, E700, E701, E702, E704, E705, E706, E970, E980, E1367, E1825, E1850 Canada: 60613, 60614, 60615, 60616, 60617, 60618, 60619, 61367 • User's Responsibility The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace Hazardous Materials Information System (WHMIS) require that the information contained on these sheets be made available to your workers. Educate and train your workers regarding OSHA and WHMIS precautions. Instruct your workers to handle this product properly. Consult with appropriate experts to guard against hazards associated with use of this product and its ingredients. • Disclaimer SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product shall conform to contracted specifications, and that the product does not infringe any valid United States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, negligence or otherwise. CURRENT ISSUE: 04-MAR-09 PREVIOUS ISSUE: 28-FEB-08 Page 7 of 7 E700_D ELMER'S CARPENTERS WOOD GLUE Page 392 of 1287 Page 392 of 1287 Page 392 of 1287 Page 392 of 1287 ---PAGE BREAK--- 3812S AXALTA MATERIAL SAFETY DATA SHEET Page: 1 AXALTA COATING SYSTEMS CANADA COMPANY 05/05/2013 SECTION 1 - Product and Company Identification Supplier: Axalta Coating Systems Canada Company 408 Fairall Street Ajax, ON, L1S 1R6 Manufacturer: Axalta Coating Systems, LLC 1007 Market Street, D-13111 Wilmington, DE, 19898 Telephone: Product Information: (800) 387-2122 Medical Emergency (24 hours): (855) 274-5698 Transportation Emergency (24 hours): (613) 996-6666(CANUTEC) PRODUCT IDENTIFIER: ENAMEL REDUCER PRODUCT CODE: 3812S 081003 Product Use: INDUSTRIAL SOLVENT Prepared by: Regulatory Affairs Chemical Family: Not Available Copyright 2013 Axalta Coating Systems Canada Company. All rights reserved. Copies may be made only for those using Axalta Coating Systems products. SECTION 2 - Composition, Information on Ingredients CAS # Ingredient Exposure Limits** 67-64-1 ACETONE 10- 30 A 750.0 ppm 15 min STEL A 500.0 ppm O 1000.0 ppm D 500.0 ppm 8 & 12 hour TWA 108-88-3 TOLUENE 15- 40 A 20.0 ppm O 300.0 ppm CEIL O 500.0 ppm 10 min TWA O 200.0 ppm D 50.0 ppm 8 & 12 hour TWA Skin 67-63-0 ISOPROPYL ALCOHOL 7- 13 A None O None Page 393 of 1287 Page 393 of 1287 Page 393 of 1287 Page 393 of 1287 ---PAGE BREAK--- 3812S AXALTA MATERIAL SAFETY DATA SHEET Page: 2 AXALTA COATING SYSTEMS CANADA COMPANY 05/05/2013 SECTION 2 - Composition, Information on Ingredients Cont'd 142-82-5 HEPTANE 40- 70 A 500.0 ppm 15 min STEL A 400.0 ppm O 500.0 ppm 100-41-4 1- 5 A 20.0 ppm O 100.0 ppm D 25.0 ppm 8 & 12 hour TWA 1330-20-7 XYLENE 5- 10 A 150.0 ppm 15 min STEL A 100.0 ppm O 100.0 ppm D 100.0 ppm 8 & 12 hour TWA 108-87-2 CYCLOHEXANE, METHYL- 0.5- 1.5 A 400.0 ppm O 400.0 ppm A = ACGIH, O = OSHA, D = Dupont, TWAEV = Ontario, S = Supplier D=Dupont Results obtained from E.I. duPont de Nemours and Company (For additional definition of terms, see section 16) Limits are 8-hour TWA unless otherwise specified. SECTION 3 - Hazards Information Emergency Overview: DANGER! EXPOSURE MAY CAUSE LUNG INJURY AND ALLERGIC RESPIRATORY REACTION. EFFECTS MAY BE PERMANENT. EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPORS AND SPRAY MIST HARMFUL IF INHALED. VAPORS MAY CAUSE FLASH FIRE. MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS SUCH AS DIZZINESS, HEADACHE, OR NAUSEA. MAY CAUSE NOSE, THROAT, EYE AND SKIN IRRITATION. CAN BE ABSORBED THROUGH THE SKIN. Potential Health Effects: Inhalation: If this product mixed with an isocyanate activator/hardener (see MSDS for the activator), the following health effects may apply: Exposure to isocyanates may cause respiratory sensitization. This effect may be permanent. include an asthma-like reaction with shortness of breath, wheezing, cough or permanent lung sensitization. This effect may be delayed for several hours after exposure. Repeated overexposure to isocyanates may cause a decrease in lung function, which may be permanent. Individuals with lung or breathing problems or prior reactions to isocyanates must not be exposed to vapors or spray mist of this product. Page 394 of 1287 Page 394 of 1287 Page 394 of 1287 Page 394 of 1287 ---PAGE BREAK--- 3812S AXALTA MATERIAL SAFETY DATA SHEET Page: 3 AXALTA COATING SYSTEMS CANADA COMPANY 05/05/2013 SECTION 3 - Hazards Information Cont'd May cause nose and throat irritation. May cause nervous system depression characterized by the following progressive steps: headache, dizziness, nausea, staggering gait, confusion, unconsciousness. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Ingestion: May result in gastrointestinal distress. Skin or eye contact: May cause irritation or burning of the eyes. Repeated or prolonged liquid contact may cause skin irritation with discomfort and dermatitis. Other Potential Health Effects in addition to those listed above: ACETONE The following medical conditions may be aggravated by exposure: lung disease eye disease skin disorders Overexposure may cause damage to any of the following organs/systems: blood central nervous system eyes kidneys liver respiratory system skin TOLUENE Increased susceptibility to the effects of this material may be observed in people with preexisting disease of any of the following: central nervous system kidneys liver respiratory system skin Can be absorbed through the skin in harmful amounts. Recurrent overexposure may result in liver and kidney injury. High airborne levels have produced irregular heart beats in animals and occasional palpitations in humans. Rats exposed to very high airborne levels have exhibited high frequency hearing deficits. The significance of this to man is unknown. WARNING: This chemical is known to the State of California to cause birth defects or other reproductive harm. ISOPROPYL ALCOHOL The following medical conditions may be aggravated by exposure: Dermatitis Respiratory Disease Developmental toxicity was seen in rat's at doses that were maternally toxic. Contact may cause skin irritation with discomfort or rash. Can be absorbed through the skin in harmful amounts. Contact will cause moderate to severe redness and swelling, itching, tingling sensation, painful burning. May cause injury to the cornea of the eyes. Prolonged or repeated exposure may cause damage to any of th following organs/systems: liver Ingestion studies on laboratory animals showed that very high oral Page 395 of 1287 Page 395 of 1287 Page 395 of 1287 Page 395 of 1287 ---PAGE BREAK--- 3812S AXALTA MATERIAL SAFETY DATA SHEET Page: 4 AXALTA COATING SYSTEMS CANADA COMPANY 05/05/2013 SECTION 3 - Hazards Information Cont'd doses caused increased liver and kidney weights. Aspiration may occur during swallowing or vomiting, resulting in lung damage. May cause central nervous system depression with headache, stupor, uncoordinated or strange behavior, or unconsciousness. Irritating to the mouth, throat and stomach. May cause irritation of the respiratory tract, experienced as nasal discomfort and discharge, coughing and possibly accompanied by chest pain. Prolonged or repeated contact may cause drying, cracking, or irritation. Ingestion may cause headache, nausea, vomiting, dizziness, and drowsiness. Swallowing significant amounts of substance could cause serious injury, even death. HEPTANE Increased susceptibility to the effects of this material may be observed in people with preexisting disease of any of the following: central nervous system respiratory system skin May cause central nervous system effects such as dizziness, headache, nausea, and loss of conciousness. Laboratory studies with rats have shown that petroleum distillates can cause kidney damage and kidney or liver tumors. These effects were not seen in similar studies with guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown a significant increase of kidney damage or an increase in kidney or liver tumors. Aspiration may occur during swallowing or vomiting, resulting in lung damage. Is an IARC, NTP or OSHA carcinogen. Increased susceptibility to the effects of this material may be observed in people with preexisting disease of any of the following: central nervous system kidneys liver lungs Recurrent overexposure may result in liver and kidney injury. Studies in laboratory animals have shown reproductive, embryotoxic and developmental effects. WARNING: This chemical is known to the State of California to cause cancer. XYLENE Increased susceptibility to the effects of this material may be observed in people with preexisting disease of any of the following: bone marrow cardiovascular system central nervous system kidneys liver lungs Recurrent overexposure may result in liver and kidney injury. High exposures may produce irregular heart beats. Page 396 of 1287 Page 396 of 1287 Page 396 of 1287 Page 396 of 1287 ---PAGE BREAK--- 3812S AXALTA MATERIAL SAFETY DATA SHEET Page: 5 AXALTA COATING SYSTEMS CANADA COMPANY 05/05/2013 SECTION 3 - Hazards Information Cont'd Canada classifies Xylene as a developmental toxin as high exposures to xylenes in some animal studies have been reported to cause health effects on the developing fetus/embryo. These effects were often at levels toxic to the adult animal. The significance of these effects to humans is not known. Repeated or prolonged skin contact may cause: irritation dryness cracking of the skin SECTION 4 - First Aid Measures First Aid Procedures: Inhalation: If affected by inhalation of vapor or spray mist, move to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing difficulty persists, or occurs later, consult a physician. Ingestion: In the unlikely event of ingestion, DO NOT induce vomiting. Call a physician immediately and have names of ingredients available. Skin or eye: In case of contact, immediately flush with plenty of water for at least 15 minutes; call a physician. In case of skin contact, wash thoroughly with soap and water. If irritation occurs, contact a physician. SECTION 5 - Firefighting Measures Flash Point (Method) Below -7 deg C Closed Cup Approx. flammable limits LFL 1.0 % UFL 12.8 % Auto ignition temperature 246.1 - 465.0 Deg C Hazardous Combustion Products: CO, C02, smoke, and oxides of any heavy metals that are reported in "Composition, Information on Ingredients" section. Extinguishing media: Universal aqueous film-forming foam, carbon dioxide, dry chemical. Special fire fighting procedures: Full protective equipment, including self-contained breathing apparatus, is recommended. Water from fog nozzles may be used to prevent pressure build-up. Fire & explosion hazards: Flammable liquid. Vapor/air mixture will burn when an ignition source is present. SECTION 6 - Accidental Release Measures Procedures for cleaning up spills or leaks: Ventilate area. Remove sources of ignition. Prevent skin and eye contact and breathing of vapor. Page 397 of 1287 Page 397 of 1287 Page 397 of 1287 Page 397 of 1287 ---PAGE BREAK--- 3812S AXALTA MATERIAL SAFETY DATA SHEET Page: 6 AXALTA COATING SYSTEMS CANADA COMPANY 05/05/2013 SECTION 6 - Accidental Release Measures Cont'd If the material contains, or is mixed with an isocyanate activator/hardener: Wear a positive-pressure, supplied-air respirator (NIOSH approved TC-19C), eye protection, gloves and protective clothing. Pour liquid decontamination solution over the spill and allow to sit at least 10 minutes. Typical decontamination solutions for isocyanate containing materials are: 20% Surfactant (Tergitol TMN 10) and 80% Water OR 0 -10% Ammonia, 2-5% Detergent and Water (balance) Pressure can be generated. Do not seal waste containers for 48 hours to allow C02 to vent. After 48 hours, material may be sealed and disposed of properly. If material does not contain or is not mixed with an isocyanate activator/hardener: Wear a properly fitted air-purifying respirator with organic vapor cartridges (NIOSH approved TC-23C), eye protection, gloves and protective clothing. Confine, remove with inert absorbent, and dispose of properly. SECTION 7 - Handling and Storage Precautions to be taken in handling and storing: Observe label precautions. Keep away from heat, sparks, flame, static discharge and other sources of ignition. VAPORS MAY IGNITE EXPLOSIVELY. Vapors may spread long distances. Prevent buildup of vapors. Extinguish all pilot lights and turn off heaters, non-explosion proof electrical equipment and other sources of ignition during and after use and until all vapors are gone. Close container after each use. Ground containers when pouring. Wash thoroughly after handling and before eating or smoking. Do not store above 120 deg F. OSHA/NFPA Storage Classification: IB Other precautions: If material is a coating: do not sand, flame cut, braze or weld dry coating without a NIOSH approved air purifying respirator with particulate filters or appropriate ventilation , and gloves. SECTION 8 - Exposure Controls or Personal Protection Engineering controls and work practices: Ventilation: Provide sufficient ventilation in volume and pattern to keep contaminants below applicable exposure limits. Personal Protective Equipment: Recommended PPE: Respiratory: Do not breathe vapors or mists. When this product is used with an isocyanate activator/hardener, wear a positive-pressure, supplied-air respirator (NIOSH approved TC-19C) while mixing activator/hardener with paint, during application and until all vapors and spray mist are exhausted. If product is used without isocyanate activator/hardener, a properly fitted air-purifying respirator with Page 398 of 1287 Page 398 of 1287 Page 398 of 1287 Page 398 of 1287 ---PAGE BREAK--- 3812S AXALTA MATERIAL SAFETY DATA SHEET Page: 7 AXALTA COATING SYSTEMS CANADA COMPANY 05/05/2013 SECTION 8 - Exposure Controls or Personal Protection Cont'd organic vapor cartridges (NIOSH TC-23C) and particulate filter (NIOSH TC-84A) may be used. Follow respirator manufacturer s directions for respirator use. Do not permit anyone without protection in the painting area. Refer to the hardener/activator label instructions and MSDS for further information. Individuals with history of lung or breathing problems or prior reaction to isocyanates should not use or be exposed to this product if mixed with isocyanate activators/hardeners. Protective clothing: Neoprene gloves and coveralls are recommended. Eye protection: Desirable in all industrial situations. Goggles are preferred to prevent eye irritation. If safety glasses are substituted, include splash guard or side shields. SECTION 9 - Physical and Chemical Properties Evaporation Rate Slower than Ether Vapor Pressure of principal solvent 51.30 mmHg @ 20 Deg C Solubility of solvent in water NIL Vapour density (principal solvent) 3.40 Approx. Boiling range (deg C) 55 - 140 DEG Approx. Freezing range (deg C) -94 DEG Gallon weight (lbs/US gal) 6.25 Specific gravity 0.75 Percent volatile by volume 100.00 Percent volatile by weight 100.00 Percent solids by volume 0.00 Percent solids by weight 0.00 Odour Characteristic Solvent Odour Appearance Liquid Thinner Physical state Liquid pH (waterborne systems only) Not Applicable VOC* less exempt (g/l) 744.4 VOC* as packaged (g/l) 670.6 * VOC less exempt (theoretical) and VOC as packaged (theoretical) are based upon the VOC of the packaged material at the point of manufacture. SECTION 10 - Stability and Reactivity Stability: Stable Incompatibility (materials to avoid): None reasonably foreseeable Hazardous decomposition products: CO, C02, smoke, and oxides of any heavy metals that are reported in Page 399 of 1287 Page 399 of 1287 Page 399 of 1287 Page 399 of 1287 ---PAGE BREAK--- 3812S AXALTA MATERIAL SAFETY DATA SHEET Page: 8 AXALTA COATING SYSTEMS CANADA COMPANY 05/05/2013 SECTION 10 - Stability and Reactivity Cont'd "Composition, Information on Ingredients" section. Hazardous polymerization: Will not occur. Sensitivity to static discharge: Solvent vapors in air may explode if static grounding and bonding is not used during transfer of this product. Sensitivity to mechanical impact: None Known SECTION 11 - Toxicological Information ACETONE Oral LD50 5800 mg/kg Rat RTECS Dermal LD50 20 g/kg Rabbit SUPPLIER MSDS Inhalation LC50 50 g/m3 8 h Rat RTECS TOLUENE Oral LD50 3000 mg/kg Rat SUPPLIER MSDS Dermal LD50 4000 mg/kg Rabbit SUPPLIER MSDS Inhalation LC50 5300 ppm Mouse SUPPLIER MSDS ISOPROPYL ALCOHOL Oral LD50 2000 mg/kg Rat SUPPLIER MSDS Dermal LD50 2000 mg/kg Rabbit SUPPLIER MSDS Inhalation LC50 5000 ppm 8 h Rat SUPPLIER MSDS Percutaneous LD50 13000 mg/kg Rabbit SUPPLIER MSDS HEPTANE Oral LD50 5000 mg/kg Mouse MISCELLANEOUS Dermal LD50 2000 mg/kg Rabbit SUPPLIER MSDS Inhalation LC50 103000 mg/m3 4 h Rat SAX DANGEROUS PROP Intravenous LD50 222 mg/kg Mouse SUPPLIER MSDS Oral LD50 3500 mg/kg Rat RTECS Dermal LD50 18 g/kg Rabbit RTECS Inhalation LC50 4000 ppm 4 HR Rat Patty's XYLENE Oral LD50 4300 mg/kg Rat RTECS Dermal LD50 1700 mg/kg Rabbit RTECS Inhalation LC50 5000 ppm 4 h Rat RTECS CYCLOHEXANE, METHYL- Oral LD50 2250 mg/kg Rat SUPPLIER MSDS Dermal LD50 87 g/kg Rat SUPPLIER MSDS For all other ingredients, no information is available. Page 400 of 1287 Page 400 of 1287 Page 400 of 1287 Page 400 of 1287 ---PAGE BREAK--- 3812S AXALTA MATERIAL SAFETY DATA SHEET Page: 9 AXALTA COATING SYSTEMS CANADA COMPANY 05/05/2013 SECTION 11 - Toxicological Information Cont'd Key: RTECHS - Registry of Toxic Effects of Chemical Substances CCOHS - Canadian Center for Occupational Health and Safety Patty's - Patty's Industrial Hygiene and Toxicology, 3rd Edition SECTION 12 - Ecological Information ACETONE 8300 mg/l 4 days Bluegill Sunfish FISH 5540 mg/l 4 days Rainbow Trout FISH 2100 mg/l 1 day Mysid shrimp 10 mg/l 2 days Daphnia INVERTEBRATES 5000 mg/l 1 day Goldfish FISH TOLUENE 60 ppm 4 days Bluegill Sunfish FISH 32 mg/l 4 days Fathead Minnow FISH 100 ppm 1 day Water flea INVERTEBRATES 60 ppm 4 days Goldfish FISH ISOPROPYL ALCOHOL 83 mg/l Fathead Minnow FISH 7550 mg/l 2 days Daphnia INVERTEBRATES HEPTANE 2990 ppm 1 days Bluegill Sunfish FISH 15 ppm 4 days Rainbow Trout FISH 10 mg/l 24 h Daphnia INVERTEBRATES 2 mg/l 48 h INVERTEBRATES 5 mg/l 72 h AQUATIC PLANTS 4 mg/l 96 h FISH XYLENE 22 mg/l 4 days Bluegill Sunfish FISH 21 mg/l 4 days Fathead Minnow FISH 10 mg/l 1 days Water flea INVERTEBRATES 10 mg/l 1 days Daphnia INVERTEBRATES 24 mg/l 4 days Goldfish FISH CYCLOHEXANE, METHYL- 6 mg/l 72 h Daphnia INVERTEBRATES SECTION 13 - Disposal Considerations Provincial Waste Classification: Check appropriate provincial and local waste disposal regulations Page 401 of 1287 Page 401 of 1287 Page 401 of 1287 Page 401 of 1287 ---PAGE BREAK--- 3812S AXALTA MATERIAL SAFETY DATA SHEET Page: 10 AXALTA COATING SYSTEMS CANADA COMPANY 05/05/2013 SECTION 13 - Disposal Considerations Cont'd for proper classifications. Waste disposal method: Do not allow material to contaminate ground water systems. Incinerate or otherwise dispose of waste material in accordance with Federal, State, Provincial, and local requirements. Use only approved waste management contractors. Do not incinerate in closed containers. SECTION 14 - Transportation Information TDG Shipping Name: PAINT RELATED MATERIAL Hazard Class: 3 UN/NA# 1263 Packing Group: II SECTION 15 - Regulatory Information This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. TSCA Status: In compliance with TSCA Inventory requirements for commercial purposes. DSL Status: All components of the mixture are listed on the DSL. OCI: All components of the mixture are listed with the Ontario Inventory. WHMIS Classification: Class B Division 2 Class D Division 2 Subdivision A 53 Class D Division 2 Subdivision A 54 Class D Division 2 Subdivision B 60 WHMIS symbols: Flame Toxic Photochemical Reactivity: Photochemically reactive Other Regulatory Information: EPCRA CERCLA CAS # Ingredient 302 TPQ/RQ 311/312 313 RQ(lbs) HAP 67-64-1 ACETONE N NR A,C,F N 5000 N 108-88-3 TOLUENE N NR A,C,F Y 1000 Y 67-63-0 ISOPROPYL ALCOHOL N NR A,C,F N NR N 142-82-5 HEPTANE N NR A,C,F N NR N Page 402 of 1287 Page 402 of 1287 Page 402 of 1287 Page 402 of 1287 ---PAGE BREAK--- 3812S AXALTA MATERIAL SAFETY DATA SHEET Page: 11 AXALTA COATING SYSTEMS CANADA COMPANY 05/05/2013 SECTION 15 - Regulatory Information Cont'd 100-41-4 N NR A,C,F Y 1000 Y 1330-20-7 XYLENE N NR A,C,F Y 100 Y 108-87-2 CYCLOHEXANE, METHYL- N NR NA N 100 N Key: EPCRA: Emergency Planning and Community Right-to-Know Act (aka Title III, SARA) 302: Extremely hazardous substances 311/312 Categories: F = Fire Hazard A = Acute Hazard R = Reactivity Hazard C = Chronic Hazard P = Pressure Related Hazard 313 Information: Section 313 Supplier Notification - The chemicals listed above with a in the 313 column are subject to reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know act of 1986 and of 40 CFR 372. CERCLA: Comprehensive Emergency Response, Compensation and Liability Act of 1980. HAP = Listed as a Clean Air Act Hazardous Air Pollutant TPQ = Threshold planning quantity RQ = Reportable quantity NA = not available NR = not regulated SECTION 16 - Additional Information HMIS Rating: H: 2 F: 3 R: 0 NFPA Rating: H: F: R: Glossary of Terms: ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer NTP - National Toxicology Program OSHA - Occupational Safety and Health Administration STEL - Short term exposure limit TWA - Time-weighted average PNOR - Particles not otherwise regulated PNOC - Particles not otherwise classified Notice from Axalta Coating Systems The information on this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Approved by: Technical Manager Page 403 of 1287 Page 403 of 1287 Page 403 of 1287 Page 403 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Material name Epcon Acrylic 7 Version # 01 Revision date 08-19-2013 Product Code A7 Product use Concrete anchoring adhesive. Manufacturer/Supplier ITW Red Head 2171 Executive Drive, Suite 100 Addison, IL 60101 US Telephone Number: (630) 350-0370 Contact Person: Andrew Rourke Emergency CHEMTREC: (800) 424-9300 2. Hazards Identification Physical state Liquid. Appearance Paste. Emergency overview DANGER! Highly flammable. Will be easily ignited by heat, spark or flames. Contains an organic peroxide and strong oxidizer. Contact with other materials may cause fire. Heat may cause containers to explode. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. May cause central nervous system effects. Prolonged exposure may cause chronic effects. OSHA regulatory status This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication). Potential health effects Routes of exposure Inhalation. Ingestion. Skin contact. Eye contact. Eyes Irritating to eyes. Contact may cause irritation, redness, tearing, blurred vision and/or burns. Skin Irritating to skin. May cause sensitization by skin contact. Contact may cause irritation, redness and/or drying. Inhalation Vapors may irritate throat and respiratory system and cause coughing. May cause central nervous system effects. Ingestion Irritating to mouth, throat, and stomach. Ingestion may cause vomiting, nausea, diarrhea or other systemic effects. Target organs Eyes. Skin. Respiratory system. Central nervous system. Heart and cardiovascular system. Liver. Kidneys. Reproductive system. Chronic effects Methyl methacrylate vapor has hypotensive properties which may cause cardiac arrest and other cardiovascular effects. Possible reproductive hazard that may cause adverse reproductive effects based on animal data. May cause damage to the liver and kidneys. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Potential environmental effects The product contains a substance which is harmful to aquatic organisms. Components CAS # Percent 3. Composition / Information on Ingredients 80-62-6 10 - 90 Methyl methacrylate 94-36-0 0.1 - 10 Benzoyl peroxide 84-74-2 0.1 - 5 Dibutyl phthalate Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Epcon Acrylic 7 4267 Version 01 Revision date: 08-19-2013 Print date: 08-19-2013 CPH MSDS NA 1 / 8 Page 404 of 1287 Page 404 of 1287 Page 404 of 1287 Page 404 of 1287 ---PAGE BREAK--- 4. First Aid Measures First aid procedures Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention. Skin contact Immediately flush with plenty of water for at least 15 minutes. If skin rash or an allergic skin reaction develops, get medical attention. Wash contaminated clothing before reuse. Destroy or thoroughly clean contaminated shoes. Inhalation Move to fresh air. If breathing is difficult, give oxygen. Get medical attention, if needed. Ingestion Rinse mouth thoroughly. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content does not get into the lungs. Get medical attention immediately. Notes to physician Keep victim under observation. In case of shortness of breath, give oxygen. may be delayed. General advice Take off contaminated clothing and shoes immediately. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before re-use. 5. Fire Fighting Measures Flammable properties Flammable by OSHA criteria. Can be ignited easily and burns vigorously. Strong oxidizer. Contact with combustible material may cause fire. Organic peroxide. Heat may cause the containers to explode. Extinguishing media Suitable extinguishing media Water. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire. Halogenated materials. Protection of firefighters Specific hazards arising from the chemical Vapors may form explosive mixtures with air. Vapors are heavier than air and may travel along the floor and in the bottom of containers. Vapors may be ignited by a spark, a hot surface or an ember. Greatly increases the burning rate of combustible materials. Protective equipment and precautions for firefighters Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Move containers from fire area if you can do so without risk. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. Containers should be cooled with water to prevent vapor pressure build up. Cool containers exposed to flames with water until well after the fire is out. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Some of these materials, if spilled, may evaporate leaving a flammable residue. Special protective equipment for fire-fighters Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask. Specific methods In the event of fire and/or explosion do not breathe fumes. Hazardous combustion products Carbon monoxide. Carbon Dioxide. 6. Accidental Release Measures Personal precautions Keep unnecessary personnel away. Local authorities should be advised if significant spillages cannot be contained. Keep upwind. Keep out of low areas. Ventilate closed spaces before entering them. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. See Section 8 of the MSDS for Personal Protective Equipment. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water. Methods for containment ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. Dike the spilled material, where this is possible. Prevent entry into waterways, sewers, basements or confined areas. Epcon Acrylic 7 4267 Version 01 Revision date: 08-19-2013 Print date: 08-19-2013 CPH MSDS NA 2 / 8 Page 405 of 1287 Page 405 of 1287 Page 405 of 1287 Page 405 of 1287 ---PAGE BREAK--- Methods for cleaning up Keep combustibles (wood, paper, oil, etc.) away from spilled material. Small Spills: Absorb spill with vermiculite or other inert material, then place in a container for chemical waste. Clean surface thoroughly to remove residual contamination. Large Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. This material and its container must be disposed of as hazardous waste. Should not be released into the environment. Prevent product from entering drains. Other information Clean up in accordance with all applicable regulations. 7. Handling and Storage Handling Wear personal protective equipment. Avoid breathing high vapor concentrations. Avoid contact with eyes, skin, and clothing. Do not taste or swallow. Use only with adequate ventilation. Wash thoroughly after handling. DO NOT handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Take precautionary measures against static discharges. When using, do not eat, drink or smoke. Storage Keep away from heat, sparks and open flame. Keep container closed in a cool, well-ventilated place. For maximum shelf life, store between 4.4°C (40°F) to 26.7°C (80°F). Do not store above 43.3°C (110°F). Do not store near combustible materials. Keep away from food, drink and animal feeding stuffs. Keep out of the reach of children. ACGIH 8. Exposure Controls / Personal Protection Occupational exposure limits e u l a V e p y T s t n e n o p m o C 3 m / g m 5 ) 0 - 6 3 - 4 9 ( e dix o r e p ly o z n e B TWA 3 m / g m 5 ) 2 - 4 7 - 4 8 ( e t ala h t h p lyt u bi D TWA m p p 0 0 1 ) 6 - 2 6 - 0 8 ( e t aly r c a h t e m ly h t e M STEL 50 ppm TWA U.S. - OSHA e u l a V e p y T s t n e n o p m o C 3 m / g m 5 ) 0 - 6 3 - 4 9 ( e dix o r e p ly o z n e B PEL 3 m / g m 5 ) 2 - 4 7 - 4 8 ( e t ala h t h p lyt u bi D PEL m p p 0 0 1 ) 6 - 2 6 - 0 8 ( e t aly r c a h t e m ly h t e M PEL 410 mg/m3 Canada - Alberta e u l a V e p y T s t n e n o p m o C 3 m / g m 5 ) 0 - 6 3 - 4 9 ( e dix o r e p ly o z n e B TWA 3 m / g m 5 ) 2 - 4 7 - 4 8 ( e t ala h t h p lyt u bi D TWA m p p 0 0 1 ) 6 - 2 6 - 0 8 ( e t aly r c a h t e m ly h t e M STEL 410 mg/m3 205 mg/m3 TWA 50 ppm Canada - British Columbia e u l a V e p y T s t n e n o p m o C 3 m / g m 5 ) 0 - 6 3 - 4 9 ( e dix o r e p ly o z n e B TWA 3 m / g m 5 ) 2 - 4 7 - 4 8 ( e t ala h t h p lyt u bi D TWA m p p 0 0 1 ) 6 - 2 6 - 0 8 ( e t aly r c a h t e m ly h t e M STEL 50 ppm TWA Canada - Ontario e u l a V e p y T s t n e n o p m o C 3 m / g m 5 ) 0 - 6 3 - 4 9 ( e dix o r e p ly o z n e B TWA 3 m / g m 5 ) 2 - 4 7 - 4 8 ( e t ala h t h p lyt u bi D TWA m p p 0 0 1 ) 6 - 2 6 - 0 8 ( e t aly r c a h t e m ly h t e M STEL 50 ppm TWA Epcon Acrylic 7 4267 Version 01 Revision date: 08-19-2013 Print date: 08-19-2013 CPH MSDS NA 3 / 8 Page 406 of 1287 Page 406 of 1287 Page 406 of 1287 Page 406 of 1287 ---PAGE BREAK--- Canada - Quebec e u l a V e p y T s t n e n o p m o C 3 m / g m 5 ) 0 - 6 3 - 4 9 ( e dix o r e p ly o z n e B TWA 3 m / g m 5 ) 2 - 4 7 - 4 8 ( e t ala h t h p lyt u bi D TWA m p p 0 5 ) 6 - 2 6 - 0 8 ( e t aly r c a h t e m ly h t e M TWA 205 mg/m3 Mexico e u l a V e p y T s t n e n o p m o C 3 m / g m 5 ) 0 - 6 3 - 4 9 ( e dix o r e p ly o z n e B TWA 3 m / g m 0 1 ) 2 - 4 7 - 4 8 ( e t ala h t h p lyt u bi D STEL 5 mg/m3 TWA m p p 5 2 1 ) 6 - 2 6 - 0 8 ( e t aly r c a h t e m ly h t e M STEL 510 mg/m3 410 mg/m3 TWA 100 ppm Engineering controls Use explosion-proof ventilation equipment. Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Personal protective equipment Eye / face protection Wear approved safety goggles. Skin protection Wear chemical-resistant gloves, footwear and protective clothing appropriate for risk of exposure. Contact glove manufacturer for specific information. Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. General hygiene considerations Avoid contact with eyes. Avoid contact with skin. Provide eyewash station and safety shower. When using, do not eat, drink or smoke. Handle in accordance with good industrial hygiene and safety practice. 9. Physical & Chemical Properties Appearance Paste. Color Beige/Gray. Odor Pungent. Odor threshold Not available. Physical state Liquid. Form Liquid. Paste. pH Not available. Melting point Not available. Freezing point Not available. Boiling point > 213 °F 100.6 Flash point 64 °F (17.8 Evaporation rate Not available. Flammability Not available. Flammability limits in air, upper, % by volume 12.5 % Flammability limits in air, lower, % by volume 2.1 % Vapor pressure Not available. Vapor density > 1 Specific gravity 1.6 (25°C) Solubility (water) Insoluble Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. 10. Chemical Stability & Reactivity Information Chemical stability Material is stable under normal conditions. Epcon Acrylic 7 4267 Version 01 Revision date: 08-19-2013 Print date: 08-19-2013 CPH MSDS NA 4 / 8 Page 407 of 1287 Page 407 of 1287 Page 407 of 1287 Page 407 of 1287 ---PAGE BREAK--- Conditions to avoid Heat, flames and sparks. Incompatible materials Strong oxidizing agents. Reducing agents. Strong acids. Combustible material. Polymerization initiators. Hazardous decomposition products Thermal decomposition of this product can generate carbon monoxide and carbon dioxide. Possibility of hazardous reactions Will not occur at normal temperatures, however, exposure to elevated temperatures may cause hazardous polymerization. Toxicological data 11. Toxicological Information s tl u s e R t s e T s t n e n o p m o C Acute Inhalation LC50 Mouse: 18.5 mg/l 2 Hours Methyl methacrylate (80-62-6) Acute Inhalation LC50 Rat: 3750 mg/l 8 Hours Acute Oral LD50 Rabbit: 6000 mg/kg Acute Oral LD50 Rat: 7800 mg/kg Acute Other LD50 Dog: 4500 mg/kg Acute Other LD50 Mouse: 1000 mg/kg Acute Other LD50 Rat: 1328 mg/kg Acute Dermal LD50 Rabbit: 4200 mg/kg Dibutyl phthalate (84-74-2) Acute Inhalation LC50 Rat: 15.68 mg/l 4 Hours Acute Oral LD50 Rat: 8000 mg/kg Acute Oral LD50 Rat: 7710 mg/kg Benzoyl peroxide (94-36-0) Acute Other LD50 Mouse: 206 - 242 mg/kg Local effects Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. Sensitization May cause an allergic skin reaction. ACGIH Sensitizer .r e sitis n e S ) 6 - 2 6 - 0 8 S A C ( e t aly r c a h t e m ly h t e M Chronic effects Prolonged exposure may cause chronic effects. May cause damage to the liver and kidneys. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. ACGIH Carcinogens . n e g o nic r a c n a m u h a s a elb aifis s alc t o N 4 A ) 0 - 6 3 - 4 9 S A C ( e dix o r e p ly o z n e B . n e g o nic r a c n a m u h a s a elb aifis s alc t o N 4 A ) 6 - 2 6 - 0 8 S A C ( e t aly r c a h t e m ly h t e M IARC Monographs. Overall Evaluation of Carcinogenicity .s n a m u h o t yticin e g o nic r a c o t s a elb aifis s alc t o N 3 ) 0 - 6 3 - 4 9 S A C ( e dix o r e p ly o z n e B .s n a m u h o t yticin e g o nic r a c o t s a elb aifis s alc t o N 3 ) 6 - 2 6 - 0 8 S A C ( e t aly r c a h t e m ly h t e M Epidemiology This product is not reported to cause epidemiological effects in humans. Mutagenicity This product is not reported to cause mutagenic effects in humans. Neurological effects Methyl methacrylate vapor has hypotensive properties which may cause cardiac arrest and other cardiovascular effects. Reproductive effects Possible reproductive hazard that may cause adverse reproductive effects based on animal data. Teratogenicity Components in this product have been shown to cause teratogenic effects in laboratory animals. Ecotoxicological data 12. Ecological Information Components Test Results LC50 Fathead minnow (Pimephales promelas): 125.5 - 190.7 mg/l 96 hours Methyl methacrylate (80-62-6) EC50 Water flea (Daphnia magna): 2.99 mg/l 48 hours Dibutyl phthalate (84-74-2) LC50 Yellow perch (Perca flavescens): 0.28 - 0.44 mg/l 96 hours Ecotoxicity Contains a substance which causes risk of hazardous effects to the environment. Environmental effects Harmful to aquatic organisms. An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Epcon Acrylic 7 4267 Version 01 Revision date: 08-19-2013 Print date: 08-19-2013 CPH MSDS NA 5 / 8 Page 408 of 1287 Page 408 of 1287 Page 408 of 1287 Page 408 of 1287 ---PAGE BREAK--- Persistence and degradability Not available. Bioaccumulation / Accumulation No data available. Partition coefficient (n-octanol/water) Not available. Mobility in environmental media No data available. 13. Disposal Considerations Waste codes D001: Waste Flammable material with a flash point <140 °F Disposal instructions Dispose of contents/container in accordance with local/regional/national/international regulations. This material and its container must be disposed of as hazardous waste. Incinerate the material under controlled conditions in an approved incinerator. Do not incinerate sealed containers. If discarded, this product is considered a RCRA ignitable waste, D001. Do not contaminate ponds, waterways or ditches with chemical or used container. 14. Transport Information Product Specific Note: This product meets the limited quantities exception requirements for the below listed transportation agencies. Under DOT and TDG regulations, this product may be reclassified as a Consumer Commodity (ORM-D). Please see the specific regulations for the shipping and packaging requirements. DOT Basic shipping requirements: Consumer commodity Proper shipping name ORM-D Hazard class None Subsidiary hazard class None Labels required Additional information: 156, 306 Packaging exceptions 156, 306 Packaging non bulk None Packaging bulk IATA Basic shipping requirements: 3108 UN number Organic peroxide type E, solid Proper shipping name 5.2 Hazard class IMDG Basic shipping requirements: 3108 UN number ORGANIC PEROXIDE TYPE E, SOLID Proper shipping name 5.2 Hazard class No Marine pollutant Environmental hazards F-J, S-R EmS No. TDG Basic shipping requirements: Consumer commodity Proper shipping name ORM-D Hazard class None Subsidiary hazard class None Labels required Additional information: 156, 306 Packaging exceptions 156, 306 Packaging non bulk None Packaging bulk Epcon Acrylic 7 4267 Version 01 Revision date: 08-19-2013 Print date: 08-19-2013 CPH MSDS NA 6 / 8 Page 409 of 1287 Page 409 of 1287 Page 409 of 1287 Page 409 of 1287 ---PAGE BREAK--- IATA IMDG 15. Regulatory Information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration % 0 . 1 ) 0 - 6 3 - 4 9 S A C ( e dix o r e p ly o z n e B % 0 . 1 ) 2 - 4 7 - 4 8 S A C ( e t ala h t h p lyt u bi D % 0 . 1 ) 6 - 2 6 - 0 8 S A C ( e t aly r c a h t e m ly h t e M US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance . d e tsiL ) 0 - 6 3 - 4 9 S A C ( e dix o r e p ly o z n e B . d e tsiL ) 2 - 4 7 - 4 8 S A C ( e t ala h t h p lyt u bi D . d e tsiL ) 6 - 2 6 - 0 8 S A C ( e t aly r c a h t e m ly h t e M CERCLA (Superfund) reportable quantity (lbs) Methyl methacrylate 1000 Dibutyl phthalate 10 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Section 302 extremely hazardous substance No Section 311 hazardous chemical No Drug Enforcement Agency (DEA) Not controlled Canadian regulations This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. WHMIS status Controlled WHMIS classification B2 - Flammable/Combustible C - Oxidizing D2A - Other Toxic Effects-VERY TOXIC D2B - Other Toxic Effects-TOXIC F - Reactive WHMIS labeling Inventory status Country(s) or region Inventor o n / s e y ( y r o t n e v n i n O e m a n y Yes ) S C I A ( s e c n a ts b u S la ci m e h C f o y r o t n e v n I n aila rts u A aila rts u A Yes ) L S D ( tsiL s e c n a ts b u S cits e m o D a d a n a C No ) L S D N ( tsiL s e c n a ts b u S cits e m o D - n o N a d a n a C Yes ) C S C E I( a nih C ni s e c n a ts b u S la ci m e h C g nitsix E f o y r o t n e v n I a nih C Epcon Acrylic 7 4267 Version 01 Revision date: 08-19-2013 Print date: 08-19-2013 CPH MSDS NA 7 / 8 Page 410 of 1287 Page 410 of 1287 Page 410 of 1287 Page 410 of 1287 ---PAGE BREAK--- Country(s) or region Inventor o n / s e y ( y r o t n e v n i n O e m a n y Yes la ci m e h C laic r e m m o C g nitsix E f o y r o t n e v n I n a e p o r u E e p o r u E Substances (EINECS) No ) S C N I L E ( s e c n a ts b u S la ci m e h C d eifit o N f o tsiL n a e p o r u E e p o r u E Yes ) S C N E ( s e c n a ts b u S la ci m e h C w e N d n a g nitsix E f o y r o t n e v n I n a p a J Yes ) L C E ( tsiL sla ci m e h C g nitsix E a e r o K Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) State regulations WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. US - California Hazardous Substances (Director's): Listed substance . d e tsiL ) 0 - 6 3 - 4 9 S A C ( e dix o r e p ly o z n e B . d e tsiL ) 2 - 4 7 - 4 8 S A C ( e t ala h t h p lyt u bi D . d e tsiL ) 6 - 2 6 - 0 8 S A C ( e t aly r c a h t e m ly h t e M US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance . d e tsiL ) 2 - 4 7 - 4 8 S A C ( e t ala h t h p lyt u bi D US - California Proposition 65 - CRT: Listed date/Developmental toxin . nix o t la t n e m p ole v e D 5 0 0 2 , 2 r e b m e c e D : d e tsiL ) 2 - 4 7 - 4 8 S A C ( e t ala h t h p lyt u bi D US - California Proposition 65 - CRT: Listed date/Female reproductive toxin . nix o t e vitc u d o r p e r ela m e F 5 0 0 2 , 2 r e b m e c e D : d e tsiL ) 2 - 4 7 - 4 8 S A C ( e t ala h t h p lyt u bi D US - California Proposition 65 - CRT: Listed date/Male reproductive toxin . nix o t e vitc u d o r p e r ela M 5 0 0 2 , 2 r e b m e c e D : d e tsiL ) 2 - 4 7 - 4 8 S A C ( e t ala h t h p lyt u bi D US - Massachusetts RTK - Substance: Listed substance . d e tsiL ) 0 - 6 3 - 4 9 S A C ( e dix o r e p ly o z n e B . d e tsiL ) 2 - 4 7 - 4 8 S A C ( e t ala h t h p lyt u bi D . d e tsiL ) 6 - 2 6 - 0 8 S A C ( e t aly r c a h t e m ly h t e M US - New Jersey Community RTK (EHS Survey): Reportable threshold S B L 0 0 5 ) 0 - 6 3 - 4 9 S A C ( e dix o r e p ly o z n e B S B L 0 0 5 ) 2 - 4 7 - 4 8 S A C ( e t ala h t h p lyt u bi D S B L 0 0 5 ) 6 - 2 6 - 0 8 S A C ( e t aly r c a h t e m ly h t e M US - New Jersey RTK - Substances: Listed substance . d e tsiL ) 0 - 6 3 - 4 9 S A C ( e dix o r e p ly o z n e B . d e tsiL ) 2 - 4 7 - 4 8 S A C ( e t ala h t h p lyt u bi D . d e tsiL ) 6 - 2 6 - 0 8 S A C ( e t aly r c a h t e m ly h t e M US - RTK - Hazardous Substances: Listed substance . d e tsiL ) 0 - 6 3 - 4 9 S A C ( e dix o r e p ly o z n e B . d e tsiL ) 2 - 4 7 - 4 8 S A C ( e t ala h t h p lyt u bi D . d e tsiL ) 6 - 2 6 - 0 8 S A C ( e t aly r c a h t e m ly h t e M 16. Other Information Further information HMIS® is a registered trade and service mark of the NPCA. HMIS® ratings Health: 2* Flammability: 3 Physical hazard: 1 NFPA ratings Health: 2 Flammability: 3 Instability: 1 Disclaimer The information in the sheet was written based on the best knowledge and experience currently available. Issue date 08-19-2013 Epcon Acrylic 7 4267 Version 01 Revision date: 08-19-2013 Print date: 08-19-2013 CPH MSDS NA 8 / 8 Page 411 of 1287 Page 411 of 1287 Page 411 of 1287 Page 411 of 1287 ---PAGE BREAK--- Expo White Board Cleaner CHEMTREC (U.S. and Canada) 1-[PHONE REDACTED] SAFETY DATA SHEET Product name Emergency telephone number (with hours of operation) Section 1. Identification : : Manufacturer : Newell Rubbermaid 3500 Lacey Road, 10th Floor Downers Grove, IL 60515 USA [PHONE REDACTED] or [PHONE REDACTED] Material uses : Cleaning solutions. Section 2. Hazards identification Not classified. Classification of the substance or mixture : Signal word : Not applicable Hazard statements : No known significant effects or critical hazards. Precautionary statements Prevention : Not applicable. Response : Not applicable. Storage : Not applicable. Disposal : Not applicable. GHS label elements General : Read label before use. If medical advice is needed, have product container or label at hand. OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product. Hazards not otherwise classified : None known. Section 3. Composition/information on ingredients 3-butoxypropan-2-ol 2 - 5 5131-66-8 Ingredient name CAS number % There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. Substance/mixture : Mixture Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 1/8 Page 412 of 1287 Page 412 of 1287 Page 412 of 1287 Page 412 of 1287 ---PAGE BREAK--- Expo White Board Cleaner Section 3. Composition/information on ingredients Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if occur. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if occur. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if occur. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Description of necessary first aid measures Specific treatments : No specific treatment. Most important acute and delayed Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. : Eye contact Over-exposure Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : No specific data. Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 2/8 Page 413 of 1287 Page 413 of 1287 Page 413 of 1287 Page 413 of 1287 ---PAGE BREAK--- Expo White Board Cleaner Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section : Precautions for safe handling None. Section 8. Exposure controls/personal protection Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Control parameters Individual protection measures Occupational exposure limits Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 3/8 Page 414 of 1287 Page 414 of 1287 Page 414 of 1287 Page 414 of 1287 ---PAGE BREAK--- Expo White Board Cleaner Section 8. Exposure controls/personal protection Hand protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. Not available. Not available. Not available. Not available. Not available. Odor pH Clear. Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Not available. Not available. Not available. Viscosity Not available. Not available. Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Burning rate Not applicable. : Burning time : Not applicable. SADT Not available. : Decomposition temperature : Not available. Solubility in water : Not available. Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 4/8 Page 415 of 1287 Page 415 of 1287 Page 415 of 1287 Page 415 of 1287 ---PAGE BREAK--- Expo White Board Cleaner Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity 3-butoxypropan-2-ol LD50 Dermal Rabbit 3100 mg/kg - Product/ingredient name Result Species Dose Exposure Carcinogenicity No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Reproductive toxicity No known significant effects or critical hazards. Irritation/Corrosion No known significant effects or critical hazards. Sensitization No known significant effects or critical hazards. Information on the likely routes of exposure Delayed and immediate effects and also chronic effects from short and long term exposure Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) No known significant effects or critical hazards. No known significant effects or critical hazards. Aspiration hazard No known significant effects or critical hazards. Information on toxicological effects : Not available. Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 5/8 Page 416 of 1287 Page 416 of 1287 Page 416 of 1287 Page 416 of 1287 ---PAGE BREAK--- Expo White Board Cleaner Section 11. Toxicological information No known significant effects or critical hazards. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Potential chronic health effects Numerical measures of toxicity Dermal 63798.6 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name 3-butoxypropan-2-ol 1.2 - low Toxicity No known significant effects or critical hazards. Persistence and degradability No known significant effects or critical hazards. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. : Disposal methods Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 6/8 Page 417 of 1287 Page 417 of 1287 Page 417 of 1287 Page 417 of 1287 ---PAGE BREAK--- Expo White Board Cleaner Section 14. Transport information - - - - - - - Not regulated. - - Not regulated. Not regulated. - - - DOT Classification IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user No. No. No. Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : TDG Classification Not regulated. - - - No. - Mexico Classification Not regulated. - - - No. - Section 15. Regulatory information U.S. Federal regulations : United States inventory (TSCA 8b): All components are listed or exempted. SARA 311/312 Classification : Not applicable. 3-butoxypropan-2-ol 2 - 5 Yes. No. No. Yes. No. Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients The following components are listed: Propylene glycol butyl ether Not controlled under WHMIS (Canada). None of the components are listed. Canada WHMIS (Canada) Canadian lists Canadian NPRI CEPA Toxic substances : : : Canada inventory : All components are listed or exempted. This product does not contain Chemicals known to State of California to cause cancer, birth defects, or reproductive harm. California Prop. 65 Section 16. Other information History Date of issue/Date of revision Version Prepared by Date of previous issue : : : : 8/5/2015 No previous validation 1 Product Safety. Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 7/8 Page 418 of 1287 Page 418 of 1287 Page 418 of 1287 Page 418 of 1287 ---PAGE BREAK--- Expo White Board Cleaner Section 16. Other information Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our current level of knowledge and on national and community regulations. The mixture must not be used for other uses than those specified in section 1 without having first obtained written handling instructions. It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local regulations. The information in this safety data sheet must be regarded as a description of the safety requirements relating to the mixture and not as a guarantee of the properties thereof. Indicates information that has changed from previously issued version. Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient UN = United Nations Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 8/8 Page 419 of 1287 Page 419 of 1287 Page 419 of 1287 Page 419 of 1287 ---PAGE BREAK--- Page 1/4 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 01/04/2006 Reviewed on 01/04/2006 DR 1 Identification of substance Trade name: FARM AND INDUSTRY INTERNATIONAL HARVESTOR RED Product code: [PHONE REDACTED] Manufacturer/Supplier: SEYMOUR OF SYCAMORE 917 Crosby Avenue Sycamore, IL 60178 (815)-895-9101, www.seymourpaint.com Information department: Health & Safety Department Emergency information: CHEMTEL 1-[PHONE REDACTED], [PHONE REDACTED] if located outside the U.S. 2 Composition/Data on components Chemical Description: This product is a mixture of the substances listed below with nonhazardous additions. Dangerous components: 67-64-1 Acetone 19.1% 74-98-6 propane 15.78% 106-97-8 n-butane 9.26% 7727-43-7 barium sulphate, natural 8.05% 2807-30-9 Glycol Ether EP 5.15% 108-10-1 methyl isobutyl ketone 4.87% 108-65-6 PM acetate 3.22% 107-87-9 Methyl Propyl Ketone 2.98% 1330-20-7 xylene (mix) 2.33% 110-19-0 isobutyl acetate 1.51% 64742-94-5 Solvent naphtha (petroleum), heavy arom. 1.48% Additional information: For the wording of the listed risk phrases refer to section 3. 3 Hazards identification Hazard description: Irritant Extremely flammable Physical dangers: Has a narcotizing effect. Danger! Extremely flammable liquid and vapor in a pressurized container. Vapors may cause flash fire. Keep away from heat, sparks, and flame. Extremely flammable. Irritating to eyes. Vapours may cause drowsiness and dizziness Keep out of the reach of children. Effects of short-term overexposure: Vapors cause irritation to the eyes, nose, throat, skin, and central nervous system. may include dizziness, throat irritation, headache, fatigue,swelling of eyes, and nausea. Effects of chronic overexposure: May cause permanent brain and nervous system damage. Repeated overexposure can also damage kidneys, lungs, liver, heart, and blood. Intentional misuse by deliberately inhaling the contents may be harmful or fatal. NFPA ratings (scale 0 - Health = 1 Fire = 4 Reactivity = 3 HMIS-ratings (scale 0 - Health= 1 Fire= 4 Physical Hazard= 3 4 First aid measures After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Remove contaminated clothing. Wash exposed area with soap and water. After eye contact: Move to fresh air. Rinse opened eye for several minutes under running water. If persist, consult a doctor. After swallowing: Contact physician or poison control center. 5 Fire fighting measures Extinguishing agents: CO2, sand, extinguishing powder, or water spray. Fight larger fires with water spray or alcohol resistant foam. (Contd. on page 2) USA Page 420 of 1287 Page 420 of 1287 Page 420 of 1287 Page 420 of 1287 ---PAGE BREAK--- Page 2/4 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 01/04/2006 Reviewed on 01/04/2006 Trade name: FARM AND INDUSTRY INTERNATIONAL HARVESTOR RED (Contd. of page 1) DR Protective equipment: No special measures required. 6 Accidental release measures Personal safety precautions: Wear protective equipment. Keep unprotected persons away. Environmental safety precautions: Do not allow product to reach sewage systems or ground water. Inform appropriate authorities in case of seepage into water course or sewage system. Measures for cleaning/ collecting: Do not flush with water or aqueous cleansing agents. Use diluted caustic solution. Soak up spills with inert absorbent material. Refer to section 13 for disposal information. 7 Handling and storage Fire/explosion protection: Do not spray on a naked flame or any incandescent material. Do not smoke. Protect from electrostatic charges. Storage requirements: Observe pressurized container storage regulations. Consult with your local authorities. Keep away from sources of heat and direct sunlight. Do not warehouse in subfreezing conditions. 8 Exposure controls and personal protection: Components with limit values that require monitoring at the workplace: 74-98-6 propane PEL REL TLV 1800 mg/m³, 1000 ppm 1800 mg/m³, 1000 ppm (4508) mg/m³, (2500) ppm 106-97-8 n-butane REL TLV 1900 mg/m³, 800 ppm 1900 mg/m³, 800 ppm 7727-43-7 barium sulphate, natural PEL REL TLV 15*; mg/m³ *Total dust **Respirable fraction 10*; mg/m³ *Total dust **Respirable fraction 10 mg/m³ 108-10-1 methyl isobutyl ketone PEL REL TLV 410 mg/m³, 100 ppm Short-term value: 300 mg/m³, 75 ppm Long-term value: 205 mg/m³, 50 ppm Short-term value: 307 mg/m³, 75 ppm Long-term value: 205 mg/m³, 50 ppm BEI 108-65-6 PM acetate WEEL 100 ppm 107-87-9 Methyl Propyl Ketone PEL REL TLV 700 mg/m³, 200 ppm 530 mg/m³, 150 ppm Short-term value: 881 mg/m³, 250 ppm Long-term value: 705 mg/m³, 200 ppm 1330-20-7 xylene (mix) PEL REL TLV 435 mg/m³, 100 ppm Short-term value: 655 mg/m³, 150 ppm Long-term value: 435 mg/m³, 100 ppm & p-isomers) Short-term value: 651 mg/m³, 150 ppm Long-term value: 434 mg/m³, 100 ppm BEI 110-19-0 isobutyl acetate PEL REL TLV 700 mg/m³, 150 ppm 700 mg/m³, 150 ppm 713 mg/m³, 150 ppm (Contd. on page 3) USA Page 421 of 1287 Page 421 of 1287 Page 421 of 1287 Page 421 of 1287 ---PAGE BREAK--- Page 3/4 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 01/04/2006 Reviewed on 01/04/2006 Trade name: FARM AND INDUSTRY INTERNATIONAL HARVESTOR RED (Contd. of page 2) DR Protective hygienic measures: Keep away from foodstuffs and animal feed. Wash hands after use. Breathing equipment: A respirator is generally not necessary when using this product outdoors or in large open areas. In cases of inadequate ventilation, a respiratory protective device should be worn to prevent overexposure. Use suitable respiratory protective device in case of insufficient ventilation. Protection of hands: Protective gloves. The glove material has to be impermeable and resistant to the substance. No glove recommendation can be given. Eye protection: sealed goggles 9 Physical and chemical properties: General Information: Form: Aerosol Color: According to trade name description in section 1. Odor: Solvent Boiling point/Boiling range: -44°C (-47°F) Flash point: -19°C Ignition temperature: 230.0°C (446°F) Auto igniting: Product is not self-igniting. Danger of explosion: Stable at normal temperatures. Can may burst when exposed to temperatures exceeding 120 degrees fahrenheit. In use, may form flammable/explosive vapour-air mixture. Lower Explosion Limit: 1.7 Vol % Upper Explosion Limit: 10.9 Vol % Vapor Pressure: 40 PSI, 2750 hPa Density: Not determined. Specific Gravity: Between 0.77 and 0.90 (Water equals 1.00) VOC content: 466.7 g/l / 3.89 lb/gl VOC in weight percent (less acetone): 46.7 % Solids content: 33.9 % 10 Stability and reactivity: Conditions to be avoided: Do not allow the can to exceed 120 degrees Fahrenheit. Stable at normal temperatures. Possibility of Hazardous Reactions: No dangerous reactions known. 11 Toxicological information: Primary effect on the skin: No irritant effect. Primary effect on the eye: Irritating effect. Sensitization: No sensitizing effects known. 12 Ecological information Other information: This product does not contain any chloroflourocarbons (CFC's),chlorinated solvents, or heavy metals (lead, mercury, cadmium, etc.). No specific ecological data is available for this product. 13 Disposal considerations DISPOSAL METHOD: Dispose of in accordance with local, state, and federal regulations. Do not puncture, incinerate, or compact. Partially empty cans must be disposed of responsibly. Do not heat or cut empty containers with electric or gas torches. Recommendation: Empty cans should be recycled. 14 Transport information: Hazard class: 2.1 Identification number: N/A Label 2.1 ADR/RID class: 2 5TF Gases UN-Number: 1950 IMDG Class: 2 (Contd. on page 4) USA Page 422 of 1287 Page 422 of 1287 Page 422 of 1287 Page 422 of 1287 ---PAGE BREAK--- Page 4/4 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 01/04/2006 Reviewed on 01/04/2006 Trade name: FARM AND INDUSTRY INTERNATIONAL HARVESTOR RED (Contd. of page 3) DR Packaging group: II EMS Number: F-D,S-U Marine pollutant: No ICAO/IATA Class: 2.1 Propper shipping name: Aerosols, Flammable Consumer Commodity ORM-D 15 Regulations SARA Section 355 (extremely hazardous substances): None of the ingredients in this product are listed. SARA Section 313 (Specific toxic chemical listings): 108-10-1 methyl isobutyl ketone 1330-20-7 xylene (mix) TSCA (Toxic Substances Control Act): All ingredients are listed. PROPOSITION 65 Chemicals known to cause cancer: 100-41-4 ethyl benzene Canadian WHMIS: Class A, B5---Flammable Aerosols EPA: A= Known human carcinogen B= Probable human carcinogen C= Possible human carcinogen D= Not classifiable as to human carcinogenicity: Inadequate human and animal evidence of carcinogenicity (or no data is available). 1330-20-7 xylene (mix) D 110-19-0 isobutyl acetate D IARC: Group 2B: The ingredient is possibly carcinogenic to humans. There is limited evidence of carcinogenicity. Group 3: The ingredient is unclassifiable as to its carcinogenicity to humans. 1330-20-7 xylene (mix) 3 ACGIH TLVs: A1-designates a confirmed human carcinogen. A2-designates a suspected human carcinogen. A3-designates an animal carcinogen. A4-designates "not classifiable as a human carcinogen". 1330-20-7 xylene (mix) A4 110-19-0 isobutyl acetate A4 NIOSH: 13463-67-7 titanium dioxide 1333-86-4 Carbon black USDA (United States Department of Agriculture): This product was manufactured to conform to the USDA Food Safety and Inspection Service performance standards. These standards include, but are not limited to, the ability of this product to be safe for use in official meat and poultry establishments, and to perform well under a daily regimen of thorough cleaning, cyclical temperature change, and wet conditions. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Contact: Craig Swafford, Regulatory Affairs. Email: [EMAIL REDACTED] USA Page 423 of 1287 Page 423 of 1287 Page 423 of 1287 Page 423 of 1287 ---PAGE BREAK--- Page 424 of 1287 Page 424 of 1287 Page 424 of 1287 Page 424 of 1287 ---PAGE BREAK--- Page 425 of 1287 Page 425 of 1287 Page 425 of 1287 Page 425 of 1287 ---PAGE BREAK--- Page 426 of 1287 Page 426 of 1287 Page 426 of 1287 Page 426 of 1287 ---PAGE BREAK--- Page 427 of 1287 Page 427 of 1287 Page 427 of 1287 Page 427 of 1287 ---PAGE BREAK--- Page 428 of 1287 Page 428 of 1287 Page 428 of 1287 Page 428 of 1287 ---PAGE BREAK--- Page 429 of 1287 Page 429 of 1287 Page 429 of 1287 Page 429 of 1287 ---PAGE BREAK--- Page 430 of 1287 Page 430 of 1287 Page 430 of 1287 Page 430 of 1287 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 1 / 9 SAFETY DATA SHEET 1. Identification Product number [PHONE REDACTED] Product identifier GERMICIDAL CLEANER Revision date 03-23-2015 Company information Claire Manufacturing Co. 1005 S. Westgate Drive Addison, IL 60101 United States Company phone General Assistance 1-[PHONE REDACTED] Emergency telephone US 1-[PHONE REDACTED] Emergency telephone outside US 1-[PHONE REDACTED] Version # 04 Supersedes date 03-05-2015 Recommended use Cleaner Recommended restrictions None known. 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements Flammable aerosols Serious eye damage/eye irritation Not classified. Not classified. Category 1 Category 2 Signal word Danger Hazard statement Extremely flammable aerosol. Causes serious eye irritation. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash thoroughly after handling. Wear eye/face protection. Response If swallowed: Rinse mouth. Do NOT induce vomiting. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Storage Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Disposal Not available. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % 2-Butoxyethanol Butane EDTA Tertrasodium Salt 111-76-2 106-97-8 64-02-8 2.5 - 10 1 - 2.5 1 - 2.5 Other components below reportable levels 90 - 100 Page 431 of 1287 Page 431 of 1287 Page 431 of 1287 Page 431 of 1287 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 2 / 9 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Call a physician if develop or persist. Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists. Eye contact Rinse with water. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Get medical attention if occur. Most important acute and delayed Indication of immediate medical attention and special treatment needed Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. Provide general supportive measures and treat Keep victim under observation. may be delayed. General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water. Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Do not use water jet as an extinguisher, as this will spread the fire. Contents under pressure. Pressurized container may explode when exposed to heat or flame. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Use water spray to cool unopened containers. In the event of fire and/or explosion do not breathe fumes. General fire hazards Extremely flammable aerosol. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Level 1 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). Page 432 of 1287 Page 432 of 1287 Page 432 of 1287 Page 432 of 1287 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 3 / 9 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value 2-Butoxyethanol (CAS 111-76-2) US. ACGIH Threshold Limit Values PEL 240 mg/m3 50 ppm Components Type Value 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) TWA 20 ppm STEL 1000 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Biological limit values ACGIH Biological Exposure Indices TWA 24 mg/m3 5 ppm TWA 1900 mg/m3 800 ppm Components Value Determinant Specimen Sampling Time 2-Butoxyethanol (CAS 111-76-2) 200 mg/g Butoxyacetic acid (BAA), Creatinine in urine * with hydrolysis * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies 2-Butoxyethanol (CAS 111-76-2) Skin designation applies. US - Tennesse OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Hand protection Wear appropriate chemical resistant gloves. Skin protection Other Wear suitable protective clothing. Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Page 433 of 1287 Page 433 of 1287 Page 433 of 1287 Page 433 of 1287 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 4 / 9 9. Physical and chemical properties Appearance Physical state Gas. Form Aerosol. Color Not available. Odor Not available. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 212 °F (100 estimated Flash point -156.0 °F (-104.4 Propellant estimated Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Flammability limit - upper Not available. Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 55 - 75 psig @70F estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Specific gravity 0.979 estimated 10. Stability and reactivity Reactivity Reacts violently with strong acids. This product may react with oxidizing agents. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid Avoid temperatures exceeding the flash point. Do not mix with other chemicals. Contact with incompatible materials. Incompatible materials Acids. Oxidizing agents. Hazardous decomposition products No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation Prolonged inhalation may be harmful. Skin contact 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Eye contact Causes serious eye irritation. Page 434 of 1287 Page 434 of 1287 Page 434 of 1287 Page 434 of 1287 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 5 / 9 related to the physical, chemical and toxicological characteristics Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. Information on toxicological effects Acute toxicity Harmful if inhaled. Harmful if swallowed. Components Species 2-Butoxyethanol (CAS 111-76-2) Acute Dermal LD50 Guinea pig Test Results 230 ml/kg, 24 Hours 7.3 ml/kg, 4 Days Inhalation Rabbit 450 ml/kg, 24 Hours 435 mg/kg, 24 Hours 0.63 ml/kg Rat > 2000 mg/kg, 24 Hours LC50 Rabbit 400 ppm, 7 Hours Oral Rat 450 ppm, 4 Hours LD100 Rabbit 695 mg/kg LD50 Dog > 695 mg/kg Guinea pig 1200 mg/kg Rat 530 - 2800 mg/kg Butane (CAS 106-97-8) Acute Inhalation LC50 Mouse 1237 mg/l, 120 Minutes 52 120 Minutes Rat 1355 mg/l EDTA Tertrasodium Salt (CAS 64-02-8) Acute Oral LD50 Rat 1658 mg/kg * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Causes skin burns. Serious eye damage/eye irritation Respiratory or skin sensitization Causes eye burns. Risk of serious damage to eyes. Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity 2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Not classified. Page 435 of 1287 Page 435 of 1287 Page 435 of 1287 Page 435 of 1287 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 6 / 9 Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not likely, due to the form of the product. Chronic effects Prolonged inhalation may be harmful. May be harmful if absorbed through skin. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components 2-Butoxyethanol (CAS 111-76-2) Aquatic Species Test Results Fish LC50 Inland silverside (Menidia beryllina) 1250 mg/l, 96 hours EDTA Tertrasodium Salt (CAS 64-02-8) Aquatic Algae Fish IC50 LC50 Algae Bluegill (Lepomis macrochirus) 1.01 mg/L, 72 Hours 472 - 500 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) 2-Butoxyethanol 0.83 Butane 2.89 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. 14. Transport information DOT UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group UN1950 Aerosols 2.2 - 2.2 Not applicable. Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Packaging exceptions Packaging non bulk Packaging bulk 306 None None Page 436 of 1287 Page 436 of 1287 Page 436 of 1287 Page 436 of 1287 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 7 / 9 This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently. IATA UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards ERG Code UN1950 Aerosols, non-flammable 2.2 - 2.2 Not applicable. Yes 2L Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Other information Passenger and cargo aircraft Cargo aircraft only Packaging Exceptions IMDG UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards Marine pollutant EmS Allowed. Allowed. LTD QTY UN1950 AEROSOLS 2.2 - 2.2 Not applicable. Yes Not available. Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Packaging Exceptions Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT IATA; IMDG LTD QTY Not applicable. Page 437 of 1287 Page 437 of 1287 Page 437 of 1287 Page 437 of 1287 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 8 / 9 Marine pollutant 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Chemical name CAS number Reportable quantity Threshold planning quantity Threshold planning quantity, lower value Threshold planning quantity, upper value Ammonia 7664-41-7 100 500 lbs Hydrogen Peroxide 7722-84-1 1000 1000 lbs SARA 311/312 Hazardous No chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Butane (CAS 106-97-8) Safe Drinking Water Act (SDWA) US state regulations Not regulated. US. Massachusetts RTK - Substance List 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) US. New Jersey Worker and Community Right-to-Know Act 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) US. Worker and Community Right-to-Know Law 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) US. Rhode Island RTK Butane (CAS 106-97-8) Page 438 of 1287 Page 438 of 1287 Page 438 of 1287 Page 438 of 1287 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 9 / 9 US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Domestic Substances List (DSL) Canada Non-Domestic Substances List (NDSL) China Inventory of Existing Chemical Substances in China (IECSC) Europe European Inventory of Existing Commercial Chemical Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) Japan Inventory of Existing and New Chemical Substances (ENCS) Korea Existing Chemicals List (ECL) New Zealand New Zealand Inventory Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) No Yes No Yes No No Yes No No No Yes A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 07-28-2014 Revision date 03-23-2015 Version # 04 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Revision Information Product and Company Identification: Alternate Trade Names Page 439 of 1287 Page 439 of 1287 Page 439 of 1287 Page 439 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Glade Super Fresh 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Glade Super Fresh MSDS 126029003 Product Code: 94782 Recommended use: Air care. Emergency telephone number: 1-[PHONE REDACTED] (Prosar); 1-[PHONE REDACTED] (Int'l Prosar); 01-[PHONE REDACTED] (México) 2. HAZARDS IDENTIFICATION Principle routes of exposure: Eye contact. Skin contact. Inhalation. Eye contact: None Skin contact: None known. Inhalation: None known. Ingestion: None known. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous ingredients Ingredient(s) CAS # Weight % LD50 Oral - Rat (mg/kg) LD50 Dermal - Rabbit LC50 Inhalation - Rat Propane 74-98-6 5 - 10% Not available Not available =658 mg ( ) Isobutane 75-28-5 10 - 20% Not available Not available =658 mg/L (4 h) 4. FIRST AID MEASURES Eye contact: Rinse with plenty of water. Skin contact: Rinse with plenty of water. Inhalation: No specific first aid measures are required. Ingestion: No specific first aid measures are required. Aggravated Medical Conditions: None known. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: Dry chemical, water spray, foam, carbon dioxide. Specific hazards: Aerosol product - Containers may rocket or explode in heat of fire. Unusual hazards: None known Specific methods: Aerosol Product - Containers may rocket or expode in heat of fire. Use water spray to keep fire-exposed containers cool. Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: None. HMIS EMERGENCY OVERVIEW CAUTION. CONTENTS UNDER PRESSURE. NFPA Manufacturer, importer, supplier: Consumer Branded Professional Products JohnsonDiversey, Inc. 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249 Version Number: 2 Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] Glade Super Fresh Preparation date: 2008-03-07 1 of 3 Personal protective equipment 0 Fire Hazard None / Aucune / Ninguno 4 0 Health 4 Reactivity 0 0 Page 440 of 1287 Page 440 of 1287 Page 440 of 1287 Page 440 of 1287 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Use personal protective equipment Environmental precautions and clean-up methods: Soak up with inert absorbent material. 7. HANDLING AND STORAGE Handling: Avoid contact with skin and eyes. Use only in well-ventilated areas. CONTENTS UNDER PRESSURE. Do not puncture or incinerate. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Store in a cool, dry, well ventilated area away from heat or open flame. Protect from freezing. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 degrees C or 120 degrees F. Do not pierce or burn, even after use. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: No special ventilation requirements. Personal Protective Equipment Eye protection: No special requirements under normal use conditions Hand protection: No special requirements under normal use conditions Skin and body protection: No special requirements under normal use conditions Respiratory protection: No special requirements under normal use conditions Hygiene measures: Handle in accordance with good industrial hygiene and safety practice Ingredient(s) CAS # ACGIH OSHA Mexico Propane 74-98-6 1000 ppm (TWA) 1000 ppm (TWA) 1800 mg/m3 (TWA) Isobutane 75-28-5 1000 ppm (TWA) 9. PHYSICAL AND CHEMICAL PROPERTIES * - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 10. STABILITY AND REACTIVITY Stability: The product is stable. Polymerization: Hazardous polymerization does not occur. Hazardous decomposition products: None reasonably foreseeable. Conditions to avoid: Do not freeze. Keep away from open flames, hot surfaces and sources of ignition. 11. TOXICOLOGICAL INFORMATION Acute toxicity: Oral LD50 estimated to be greater than 5000 mg/kg Dermal LD50 estimated to be > 2000 mg/kg Component Information: See Section 3 Chronic toxicity: None known Specific effects Carcinogenic effects: None known Mutagenic effects: None known Reproductive toxicity: None known Target organ effects: None known Not determined Dilution pH: Specific gravity: 0.805 No information available. Melting point/range: Not determined Bulk density: Density: 6.72 Appearance: Decomposition temperature: Not determined Aerosol VOC: 25.0% * No information available Autoignition temperature: No information available Vapor density: Flash point: <20°F <-7°C No information available Partition coefficient (n-octanol/water): No information available Liquid Solubility: completely soluble Color: Solubility in other solvents: No information available Colorless Viscosity: No information available pH: Evaporation Rate No information available 7.0 Odor: Characteristic Fresh Glade Super Fresh 2 of 3 Physical State: Boiling point/range: Page 441 of 1287 Page 441 of 1287 Page 441 of 1287 Page 441 of 1287 ---PAGE BREAK--- 12. ECOLOGICAL INFORMATION Environmental Information: No data available 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Use up contents if possible before disposal . If possible, recycle empty aerosol cans to the nearest steel recycling center . 14. TRANSPORT INFORMATION DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the following inventories: New Zealand (NZIoC). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 STATE RIGHT TO KNOW Ingredient(s) CAS # MARTK: PARTK: RIRTK: Propane 74-98-6 X X X X Isobutane 75-28-5 X X X - Water 7732-18-5 - - - - CERCLA/ SARA CAA HAP/CAA ODS/CWA Priority Pollutants: None SARA 311/312 Hazard Categories Canada WHMIS hazard class: A Compressed gases. (Path not found) Ingredient(s) CAS # NPRI Propane 74-98-6 X 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: NFPA 30B Level 1 Aerosol. Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 3 of 3 Glade Super Fresh Page 442 of 1287 Page 442 of 1287 Page 442 of 1287 Page 442 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Product number [PHONE REDACTED] Product identifier GLEME GLASS CLEANER Company information Claire Manufacturing Co. 1005 S. Westgate Drive Addison, IL 60101 United States Company phone General Assistance 1-[PHONE REDACTED] Emergency telephone US 1-[PHONE REDACTED] Emergency telephone outside US 1-[PHONE REDACTED] Version # 01 Recommended use cleaner Recommended restrictions None known. 2. Hazard(s) identification Liquefied gas Gases under pressure Physical hazards Not classified. Health hazards Not classified. Environmental hazards Not classified. OSHA defined hazards Label elements Signal word Warning Hazard statement Contains gas under pressure; may explode if heated. Precautionary statement Prevention Observe good industrial hygiene practices. Response Wash hands after handling. Storage Protect from sunlight. Store in a well-ventilated place. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number % Chemical name Common name and synonyms 111-76-2 2-Butoxyethanol 2.5 - 10 64-17-5 Ethyl Alcohol 2.5 - 10 106-97-8 Butane 1 - 2.5 74-98-6 Propane Other components below reportable levels 90 - 100 1 - 2.5 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Get medical attention if persist. 1 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 443 of 1287 Page 443 of 1287 Page 443 of 1287 Page 443 of 1287 ---PAGE BREAK--- Skin contact Get medical attention if irritation develops and persists. Eye contact Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Most important acute and delayed Direct contact with eyes may cause temporary irritation. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Contents under pressure. During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire-fighting equipment/instructions In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed to heat. Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. See Section 8 of the SDS for Personal Protective Equipment. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into waterways, sewer, basements or confined areas. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Ground and bond containers when transferring material. Do not re-use empty containers. Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Level 1 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. Keep containers closed in a dry, cool and well-ventilated place. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). 2 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 444 of 1287 Page 444 of 1287 Page 444 of 1287 Page 444 of 1287 ---PAGE BREAK--- 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Type PEL 240 mg/m3 2-Butoxyethanol (CAS 111-76-2) 50 ppm PEL 1900 mg/m3 Ethyl Alcohol (CAS 64-17-5) 1000 ppm PEL 1800 mg/m3 Propane (CAS 74-98-6) 1000 ppm US. ACGIH Threshold Limit Values Value Components Type TWA 20 ppm 2-Butoxyethanol (CAS 111-76-2) STEL 1000 ppm Butane (CAS 106-97-8) STEL 1000 ppm Ethyl Alcohol (CAS 64-17-5) US. NIOSH: Pocket Guide to Chemical Hazards Value Components Type TWA 24 mg/m3 2-Butoxyethanol (CAS 111-76-2) 5 ppm TWA 1900 mg/m3 Butane (CAS 106-97-8) 800 ppm TWA 1900 mg/m3 Ethyl Alcohol (CAS 64-17-5) 1000 ppm TWA 1800 mg/m3 Propane (CAS 74-98-6) 1000 ppm Biological limit values ACGIH Biological Exposure Indices Value Components Determinant Specimen Sampling Time 200 mg/g Butoxyacetic acid (BAA), with hydrolysis Creatinine in urine * 2-Butoxyethanol (CAS 111-76-2) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies 2-Butoxyethanol (CAS 111-76-2) Skin designation applies. US - Tennesse OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection If contact is likely, safety glasses with side shields are recommended. Hand protection For prolonged or repeated skin contact use suitable protective gloves. Skin protection Other Wear suitable protective clothing. 3 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 445 of 1287 Page 445 of 1287 Page 445 of 1287 Page 445 of 1287 ---PAGE BREAK--- Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Clear. Physical state Gas. Form Aerosol. Liquefied gas. Color Light yellow. Odor Characteristic. Odor threshold Not available. pH 9.1 - 10.1 estimated Melting point/freezing point Not available. Initial boiling point and boiling range 212 °F (100 estimated Flash point -156.0 °F (-104.4 Propellant estimated Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Not available. Flammability limit - upper Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 80 - 100 psig @70F estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Aerosol spray enclosed space Deflagration density > 2.52 g/cm3 Tested Aerosol spray ignition distance < 15 cm Tested estimated Specific gravity 0.977 - 0.997 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Hazardous polymerization does not occur. Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. 4 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 446 of 1287 Page 446 of 1287 Page 446 of 1287 Page 446 of 1287 ---PAGE BREAK--- Incompatible materials Strong oxidizing agents. Hazardous decomposition products No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation Prolonged inhalation may be harmful. Skin contact No adverse effects due to skin contact are expected. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Eye contact Direct contact with eyes may cause temporary irritation. related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity May be harmful if swallowed. May be harmful in contact with skin. May be harmful if inhaled. Expected to be a low hazard for usual industrial or commercial handling by trained personnel. Test Results Components Species 2-Butoxyethanol (CAS 111-76-2) LD50 Guinea pig Dermal Acute 230 ml/kg, 24 Hours 7.3 ml/kg, 4 Days Rabbit 450 ml/kg, 24 Hours 435 mg/kg, 24 Hours 0.63 ml/kg Rat > 2000 mg/kg, 24 Hours LC50 Rabbit Inhalation 400 ppm, 7 Hours Rat 450 ppm, 4 Hours LD100 Rabbit Oral 695 mg/kg LD50 Dog > 695 mg/kg Guinea pig 1200 mg/kg Rat 530 - 2800 mg/kg Butane (CAS 106-97-8) LC50 Mouse Inhalation Acute 1237 mg/l, 120 Minutes 52 120 Minutes Rat 1355 mg/l Ethyl Alcohol (CAS 64-17-5) LC50 Cat Inhalation Acute 85.41 mg/l, 4.5 Hours 43.68 mg/l, 6 Hours Mouse > 60000 ppm 79.43 mg/l, 134 Minutes Rat > 115.9 mg/l, 4 Hours 5 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 447 of 1287 Page 447 of 1287 Page 447 of 1287 Page 447 of 1287 ---PAGE BREAK--- Test Results Components Species 51.3 mg/l, 6 Hours LD50 Monkey Oral 6000 mg/kg Mouse 10500 ml/kg Rat 1187 - 2769 mg/kg 7800 ml/kg Propane (CAS 74-98-6) LC50 Mouse Inhalation Acute 1237 mg/l, 120 Minutes 52 120 Minutes Rat 1355 mg/l 658 mg/l/4h * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation May be irritating to the skin. Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. May be irritating to eyes. Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity 2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Not likely, due to the form of the product. Chronic effects Prolonged inhalation may be harmful. May be harmful if absorbed through skin. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. 12. Ecological information Ecotoxicity Harmful to aquatic life. Product Test Results Species GLEME GLASS CLEANER (CAS Mixture) Aquatic EC50 Crustacea 13838.1602 mg/l, 48 hours estimated Daphnia Components Test Results Species 2-Butoxyethanol (CAS 111-76-2) Aquatic LC50 Fish 1250 mg/l, 96 hours Inland silverside (Menidia beryllina) 6 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 448 of 1287 Page 448 of 1287 Page 448 of 1287 Page 448 of 1287 ---PAGE BREAK--- Components Test Results Species Ethyl Alcohol (CAS 64-17-5) Aquatic EC50 Crustacea 7700 - 11200 mg/l, 48 hours Water flea (Daphnia magna) * Estimates for product may be based on additional component data not shown. LC50 Fish > 100.1 mg/l, 96 hours Fathead minnow (Pimephales promelas) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) 2-Butoxyethanol 0.83 Butane 2.89 Ethyl Alcohol -0.31 Propane 2.36 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. 14. Transport information DOT UN1950 UN number Aerosols UN proper shipping name 2.2 Class Transport hazard class(es) - Subsidiary risk 2.2 Label(s) Not applicable. Packing group Read safety instructions, SDS and emergency procedures before handling. Special precautions for user 306 Packaging exceptions None Packaging non bulk None Packaging bulk This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently. IATA UN1950 UN number Aerosols, non-flammable UN proper shipping name 2.2 Class Transport hazard class(es) - Subsidiary risk 2.2 Label(s) Not applicable. Packing group No. Environmental hazards 2L ERG Code Read safety instructions, SDS and emergency procedures before handling. Special precautions for user 7 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 449 of 1287 Page 449 of 1287 Page 449 of 1287 Page 449 of 1287 ---PAGE BREAK--- Allowed. Passenger and cargo aircraft Other information Allowed. Cargo aircraft only LTD QTY Packaging Exceptions IMDG UN1950 UN number AEROSOLS UN proper shipping name 2.2 Class Transport hazard class(es) - Subsidiary risk 2.2 Label(s) Not applicable. Packing group No. Marine pollutant Environmental hazards Not available. EmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user LTD QTY Packaging Exceptions Not applicable. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT IATA; IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. 8 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 450 of 1287 Page 450 of 1287 Page 450 of 1287 Page 450 of 1287 ---PAGE BREAK--- Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Butane (CAS 106-97-8) Propane (CAS 74-98-6) Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. Massachusetts RTK - Substance List 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) Propane (CAS 74-98-6) US. New Jersey Worker and Community Right-to-Know Act 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) Propane (CAS 74-98-6) US. Worker and Community Right-to-Know Law 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) Propane (CAS 74-98-6) US. Rhode Island RTK Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Yes Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) Yes China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) No New Zealand New Zealand Inventory No Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) 9 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 451 of 1287 Page 451 of 1287 Page 451 of 1287 Page 451 of 1287 ---PAGE BREAK--- Country(s) or region Inventory name On inventory (yes/no)* Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 05-26-2015 Version # 01 References EPA: AQUIRE database NLM: Hazardous Substances Data Base US. IARC Monographs on Occupational Exposures to Chemical Agents Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 10 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 452 of 1287 Page 452 of 1287 Page 452 of 1287 Page 452 of 1287 ---PAGE BREAK--- Page 1/4 Safety Data Sheet Printing date 11/06/2014 Revised On 11/06/2014 39.6.0 1 Identification of the substance and manufacturer Trade name: GLOSS BLACK Product code: BD12020000 Product category PC9a Paints and coatings. Manufacturer/Supplier: Seymour of Sycamore 917 Crosby Avenue Sycamore, IL 60178 Phone: [PHONE REDACTED] www.seymourpaint.com Emergency telephone number: CHEMTEL 1-[PHONE REDACTED], [PHONE REDACTED] *if located outside the U.S.* 2 Hazard(s) identification Classification of the substance or mixture Flam. Aerosol 1 H222 Extremely flammable aerosol. Press. Gas H280 Contains gas under pressure; may explode if heated. Carc. 2 H351 Suspected of causing cancer. Eye Irrit. 2A H319 Causes serious eye irritation. STOT SE 3 H336 May cause drowsiness or dizziness. GHS Hazard pictograms GHS02 GHS04 GHS07 GHS08 Signal word Danger Hazard statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Suspected of causing cancer. May cause drowsiness or dizziness. Precautionary statements If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. Obtain special instructions before use. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash hands thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapors/spray IF INHALED: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. If eye irritation persists: Get medical advice/attention. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 Store in a well-ventilated place. Keep container closed. Dispose of contents/container in accordance with local/regional/national/international regulations. 3 Composition/information on ingredients Chemical characterization: Mixtures Chemical Description: This product is a mixture of the substances listed below with nonhazardous additions. Dangerous components: 67-64-1 Acetone 22.56% 74-98-6 propane 15.74% 106-97-8 n-butane 9.24% 7727-43-7 barium sulphate, natural 8.51% 108-10-1 methyl isobutyl ketone 5.47% 2807-30-9 Glycol Ether EP 5.45% 107-87-9 Methyl Propyl Ketone 3.06% 1330-20-7 xylene (mix) 2.69% 108-65-6 PM acetate 1.87% 110-19-0 isobutyl acetate 1.41% 4 First-aid measures After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Remove contaminated clothing. Wash exposed area with soap and water. After eye contact: Rinse opened eye for several minutes under running water. If persist, consult a doctor. After swallowing: Rinse out mouth and then drink plenty of water. Rinse mouth with water. Do not induce vomiting. Most important and effects: Dizziness (Contd. on page 2) Page 453 of 1287 Page 453 of 1287 Page 453 of 1287 Page 453 of 1287 ---PAGE BREAK--- Page 2/4 Safety Data Sheet Printing date 11/06/2014 Revised On 11/06/2014 Trade name: GLOSS BLACK (Contd. of page 1) 39.6.0 Indication of any immediate medical attention needed: No further relevant information available. 5 Fire-fighting measures Extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray. Special hazards: Can form explosive gas-air mixtures. Protective equipment for firefighters: A respiratory protective device may be necessary. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures: Use respiratory protective device against the effects of fumes/dust/aerosol. Methods and material for containment and cleaning up: Absorb liquid components with liquid-binding material. 7 Handling and storage Precautions for safe handling Use only in well ventilated areas. Storage requirements: Keep away from sources of heat and direct sunlight. Do not warehouse in subfreezing conditions. Store locked up. 8 Exposure controls/personal protection Components with limit values that require monitoring at the workplace: 67-64-1 Acetone PEL (USA) Long-term value: 2400 mg/m³, 1000 ppm REL (USA) Long-term value: 590 mg/m³, 250 ppm TLV (USA) Short-term value: (1782) NIC-1187 mg/m³, (750) NIC-500 ppm Long-term value: (1188) NIC-594 mg/m³, (500) NIC-250 ppm BEI 74-98-6 propane PEL (USA) Long-term value: 1800 mg/m³, 1000 ppm REL (USA) Long-term value: 1800 mg/m³, 1000 ppm TLV (USA) refer to Appendix F 106-97-8 n-butane REL (USA) Long-term value: 1900 mg/m³, 800 ppm TLV (USA) Short-term value: 2370 mg/m³, 1000 ppm 7727-43-7 barium sulphate, natural PEL (USA) Long-term value: 15* mg/m³ *total dust **respirable fraction REL (USA) Long-term value: 10* mg/m³ *total dust **respirable fraction TLV (USA) Long-term value: 5* mg/m³ *inhalable fraction; E 108-10-1 methyl isobutyl ketone PEL (USA) Long-term value: 410 mg/m³, 100 ppm REL (USA) Short-term value: 300 mg/m³, 75 ppm Long-term value: 205 mg/m³, 50 ppm TLV (USA) Short-term value: 307 mg/m³, 75 ppm Long-term value: 82 mg/m³, 20 ppm BEI 107-87-9 Methyl Propyl Ketone PEL (USA) Long-term value: 700 mg/m³, 200 ppm REL (USA) Long-term value: 530 mg/m³, 150 ppm TLV (USA) Short-term value: 529 mg/m³, 150 ppm 1330-20-7 xylene (mix) PEL (USA) Long-term value: 435 mg/m³, 100 ppm REL (USA) Short-term value: 655 mg/m³, 150 ppm Long-term value: 435 mg/m³, 100 ppm TLV (USA) Short-term value: 651 mg/m³, 150 ppm Long-term value: 434 mg/m³, 100 ppm BEI 108-65-6 PM acetate WEEL (USA) Long-term value: 50 ppm 110-19-0 isobutyl acetate PEL (USA) Long-term value: 700 mg/m³, 150 ppm REL (USA) Long-term value: 700 mg/m³, 150 ppm TLV (USA) Long-term value: 713 mg/m³, 150 ppm (Contd. on page 3) Page 454 of 1287 Page 454 of 1287 Page 454 of 1287 Page 454 of 1287 ---PAGE BREAK--- Page 3/4 Safety Data Sheet Printing date 11/06/2014 Revised On 11/06/2014 Trade name: GLOSS BLACK (Contd. of page 2) 39.6.0 Ingredients with biological limit values: 67-64-1 Acetone BEI (USA) 50 mg/L Medium: urine Time: end of shift Parameter: Acetone (nonspecific) 108-10-1 methyl isobutyl ketone BEI (USA) 1 mg/L Medium: urine Time: end of shift Parameter: MIBK 1330-20-7 xylene (mix) BEI (USA) 1.5 g/g creatinine Medium: urine Time: end of shift Parameter: acids Hygienic protection: Immediately remove all soiled and contaminated clothing. Wash hands after use. Avoid contact with the eyes and skin. Do not eat or drink while working. Breathing equipment: A respirator is generally not necessary when using this product outdoors or in large open areas. In cases where short and/or long term overexposure exists, a charcoal filter respirator should be worn. If you suspect overexposure conditions exist, please consult an authority on chemical hygeine. Hand protection: Protective gloves. The glove material must be impermeable and resistant to the substance. Eye protection: sealed goggles 9 Physical and chemical properties Appearance: Aerosol. Odor: Aromatic Odor threshold: Not determined. pH-value: Not determined. Melting point/Melting range Undetermined. Boiling point: -44 °C (-47 Flash point: -19 °C Flammability (solid, gas): Extremely flammable. Decomposition temperature: Not determined. Auto igniting: Product is not self-igniting. Danger of explosion: In use, may form flammable/explosive vapour-air mixture. Lower Explosion Limit: 1.7 Vol % Upper Explosion Limit: 10.9 Vol % Vapor pressure: Not determined. Relative Density: Between 0.77 and 0.85 (Water equals 1.00) Vapour density Not determined. Evaporation rate Not applicable. Partition coefficient: n-octonal/water: Not determined. Solubility: Not determined. Viscosity: Not determined. VOC content: 496.0 g/l / 4.14 lb/gl VOC content (less exempt solvents): 46.2 % MIR Value: 1.12 Solids content: 30.9 % 10 Stability and reactivity Reactivity: Stable at normal temperatures. Conditions to avoid: Do not allow can to exceed 120 degrees Fahrenheit. Do not warehouse in subfreezing temperatures. Chemical stability: Not fully evaluated. Possibility of hazardous reactions: No dangerous reactions known. Incompatible materials: No further relevant information available. Hazardous decomposition: No dangerous decomposition products known. 11 Toxicological information LD/LC50 values that are relevant for classification: 106-97-8 n-butane Inhalative LC50/4 h 658 mg/l (rat) 108-10-1 methyl isobutyl ketone Oral LD50 2100 mg/kg (rat) Dermal LD50 16000 mg/kg (rab) Inhalative LC50/4 h 8.3-16.6 mg/l (rat) (Contd. on page 4) Page 455 of 1287 Page 455 of 1287 Page 455 of 1287 Page 455 of 1287 ---PAGE BREAK--- Page 4/4 Safety Data Sheet Printing date 11/06/2014 Revised On 11/06/2014 Trade name: GLOSS BLACK (Contd. of page 3) 39.6.0 1330-20-7 xylene (mix) Oral LD50 8700 mg/kg (rat) Dermal LD50 2000 mg/kg (rbt) Inhalative LC50/4 h 6350 mg/l (rat) 108-65-6 PM acetate Oral LD50 8500 mg/kg (rat) Inhalative LC50/4 h 35.7 mg/l (rat) 110-19-0 isobutyl acetate Oral LD50 4763 mg/kg (rbt) Information on toxicological effects: No data available. Sensitization: No sensitizing effects known. Carcinogenic categories IARC (International Agency for Research on Cancer) 108-10-1 methyl isobutyl ketone 2B 1330-20-7 xylene (mix) 3 NTP (National Toxicology Program) None of the ingredients is listed. 12 Ecological information Aquatic toxicity: Hazardous for water, do not empty into drains. Persistence and degradability: The product is degradable after prolonged exposure to natural weathering processes. Bioaccumulative potential: No further relevant information available. Mobility in soil: No further relevant information available. Other adverse effects: No further relevant information available. 13 Disposal considerations Dispose of in accordance with local, state, and federal regulations. Do not puncture, incinerate, or compact. Partially empty cans must be disposed of responsibly. Do not heat or cut empty containers with electric or gas torches. Recommendation: Completely empty cans should be recycled. 14 Transport information UN-Number UN1950 DOT Aerosols, flammable ADR 1950 Aerosols Transport hazard class(es): Class 2.1 Marine pollutant: No Special precautions for user: Warning: Gases EMS Number: F-D,S-U Packaging Group: UN "Model Regulation": UN1950, Aerosols, 2.1 15 Regulatory information SARA Section 355 (extremely hazardous substances): None of the ingredients in this product are listed. SARA Section 313 (Specific toxic chemical listings): 7727-43-7 barium sulphate, natural 108-10-1 methyl isobutyl ketone 1330-20-7 xylene (mix) CPSC: This product complies with 16 CFR 1303 and does not contain more than 90 ppm of lead. California Proposition 65 chemicals known to cause cancer: 108-10-1 methyl isobutyl ketone 1333-86-4 Carbon black 100-41-4 ethyl benzene CANADIAN ENVIRONMENTAL PROTECTION ACT: All hazardous ingredients for this product appear on the Canadian Domestice Substance List. EPA: 67-64-1 Acetone I 7727-43-7 barium sulphate, natural D, CBD(inh), NL(oral) 108-10-1 methyl isobutyl ketone I 1330-20-7 xylene (mix) I 110-19-0 isobutyl acetate D 16 Other information Contact: Regulatory Affairs Date of preparation / last revision 11/06/2014 / - Page 456 of 1287 Page 456 of 1287 Page 456 of 1287 Page 456 of 1287 ---PAGE BREAK--- Page 1/4 Safety Data Sheet Printing date 11/06/2014 Revised On 11/05/2014 39.6.0 1 Identification of the substance and manufacturer Trade name: GLOSS WHITE Product code: BD12050000 Product category PC9a Paints and coatings. Manufacturer/Supplier: Seymour of Sycamore 917 Crosby Avenue Sycamore, IL 60178 Phone: [PHONE REDACTED] www.seymourpaint.com Emergency telephone number: CHEMTEL 1-[PHONE REDACTED], [PHONE REDACTED] *if located outside the U.S.* 2 Hazard(s) identification Classification of the substance or mixture Flam. Aerosol 1 H222 Extremely flammable aerosol. Press. Gas H280 Contains gas under pressure; may explode if heated. Carc. 2 H351 Suspected of causing cancer. Eye Irrit. 2A H319 Causes serious eye irritation. GHS Hazard pictograms GHS02 GHS04 GHS07 GHS08 Signal word Danger Hazard statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Suspected of causing cancer. Precautionary statements If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. Obtain special instructions before use. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash hands thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Do not handle until all safety precautions have been read and understood. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 Store in a well-ventilated place. Dispose of contents/container in accordance with local/regional/national/international regulations. 3 Composition/information on ingredients Chemical characterization: Mixtures Chemical Description: This product is a mixture of the substances listed below with nonhazardous additions. Dangerous components: 67-64-1 Acetone 17.8% 74-98-6 propane 15.76% 13463-67-7 titanium dioxide 11.3% 106-97-8 n-butane 9.26% 108-10-1 methyl isobutyl ketone 5.64% 7727-43-7 barium sulphate, natural 5.0% 2807-30-9 Glycol Ether EP 4.8% 110-19-0 isobutyl acetate 4.56% 107-87-9 Methyl Propyl Ketone 2.94% 1330-20-7 xylene (mix) 2.43% 4 First-aid measures After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Remove contaminated clothing. Wash exposed area with soap and water. After eye contact: Rinse opened eye for several minutes under running water. If persist, consult a doctor. After swallowing: Rinse out mouth and then drink plenty of water. Rinse mouth with water. Do not induce vomiting. Most important and effects: Dizziness Indication of any immediate medical attention needed: No further relevant information available. 5 Fire-fighting measures Extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray. Special hazards: Can form explosive gas-air mixtures. (Contd. on page 2) Page 457 of 1287 Page 457 of 1287 Page 457 of 1287 Page 457 of 1287 ---PAGE BREAK--- Page 2/4 Safety Data Sheet Printing date 11/06/2014 Revised On 11/05/2014 Trade name: GLOSS WHITE (Contd. of page 1) 39.6.0 Protective equipment for firefighters: A respiratory protective device may be necessary. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures: Wear protective equipment. Keep unprotected persons away. Use respiratory protective device against the effects of fumes/dust/aerosol. Methods and material for containment and cleaning up: Ensure adequate ventilation. 7 Handling and storage Precautions for safe handling Use only in well ventilated areas. Storage requirements: Keep away from sources of heat and direct sunlight. Do not warehouse in subfreezing conditions. Store locked up. 8 Exposure controls/personal protection Components with limit values that require monitoring at the workplace: 67-64-1 Acetone PEL (USA) Long-term value: 2400 mg/m³, 1000 ppm REL (USA) Long-term value: 590 mg/m³, 250 ppm TLV (USA) Short-term value: (1782) NIC-1187 mg/m³, (750) NIC-500 ppm Long-term value: (1188) NIC-594 mg/m³, (500) NIC-250 ppm BEI 74-98-6 propane PEL (USA) Long-term value: 1800 mg/m³, 1000 ppm REL (USA) Long-term value: 1800 mg/m³, 1000 ppm TLV (USA) refer to Appendix F 106-97-8 n-butane REL (USA) Long-term value: 1900 mg/m³, 800 ppm TLV (USA) Short-term value: 2370 mg/m³, 1000 ppm 108-10-1 methyl isobutyl ketone PEL (USA) Long-term value: 410 mg/m³, 100 ppm REL (USA) Short-term value: 300 mg/m³, 75 ppm Long-term value: 205 mg/m³, 50 ppm TLV (USA) Short-term value: 307 mg/m³, 75 ppm Long-term value: 82 mg/m³, 20 ppm BEI 7727-43-7 barium sulphate, natural PEL (USA) Long-term value: 15* mg/m³ *total dust **respirable fraction REL (USA) Long-term value: 10* mg/m³ *total dust **respirable fraction TLV (USA) Long-term value: 5* mg/m³ *inhalable fraction; E 110-19-0 isobutyl acetate PEL (USA) Long-term value: 700 mg/m³, 150 ppm REL (USA) Long-term value: 700 mg/m³, 150 ppm TLV (USA) Long-term value: 713 mg/m³, 150 ppm 107-87-9 Methyl Propyl Ketone PEL (USA) Long-term value: 700 mg/m³, 200 ppm REL (USA) Long-term value: 530 mg/m³, 150 ppm TLV (USA) Short-term value: 529 mg/m³, 150 ppm 1330-20-7 xylene (mix) PEL (USA) Long-term value: 435 mg/m³, 100 ppm REL (USA) Short-term value: 655 mg/m³, 150 ppm Long-term value: 435 mg/m³, 100 ppm TLV (USA) Short-term value: 651 mg/m³, 150 ppm Long-term value: 434 mg/m³, 100 ppm BEI Ingredients with biological limit values: 67-64-1 Acetone BEI (USA) 50 mg/L Medium: urine Time: end of shift Parameter: Acetone (nonspecific) 108-10-1 methyl isobutyl ketone BEI (USA) 1 mg/L Medium: urine Time: end of shift Parameter: MIBK (Contd. on page 3) Page 458 of 1287 Page 458 of 1287 Page 458 of 1287 Page 458 of 1287 ---PAGE BREAK--- Page 3/4 Safety Data Sheet Printing date 11/06/2014 Revised On 11/05/2014 Trade name: GLOSS WHITE (Contd. of page 2) 39.6.0 1330-20-7 xylene (mix) BEI (USA) 1.5 g/g creatinine Medium: urine Time: end of shift Parameter: acids Hygienic protection: Keep away from foodstuffs and animal feed. Wash hands after use. Immediately remove all soiled and contaminated clothing. Wash hands after use. Avoid contact with the eyes and skin. Do not eat or drink while working. Breathing equipment: A respirator is generally not necessary when using this product outdoors or in large open areas. In cases where short and/or long term overexposure exists, a charcoal filter respirator should be worn. If you suspect overexposure conditions exist, please consult an authority on chemical hygeine. Hand protection: Protective gloves. The glove material must be impermeable and resistant to the substance. Eye protection: sealed goggles 9 Physical and chemical properties Appearance: Aerosol. Odor: Aromatic Odor threshold: Not determined. pH-value: Not determined. Melting point/Melting range Undetermined. Boiling point: -44 °C (-47 Flash point: -19 °C Flammability (solid, gas): Extremely flammable. Decomposition temperature: Not determined. Auto igniting: Product is not self-igniting. Danger of explosion: In use, may form flammable/explosive vapour-air mixture. Lower Explosion Limit: 1.7 Vol % Upper Explosion Limit: 10.9 Vol % Vapor pressure: Not determined. Relative Density: Between 0.77 and 0.85 (Water equals 1.00) Vapour density Not determined. Evaporation rate Not applicable. Partition coefficient: n-octonal/water: Not determined. Solubility: Not determined. Viscosity: Not determined. VOC content: 497.1 g/l / 4.15 lb/gl VOC content (less exempt solvents): 46.1 % MIR Value: 1.05 Solids content: 35.4 % 10 Stability and reactivity Reactivity: Stable at normal temperatures. Conditions to avoid: Do not allow can to exceed 120 degrees Fahrenheit. Do not warehouse in subfreezing temperatures. Chemical stability: Not fully evaluated. Possibility of hazardous reactions: No dangerous reactions known. Incompatible materials: No further relevant information available. Hazardous decomposition: No dangerous decomposition products known. 11 Toxicological information LD/LC50 values that are relevant for classification: 13463-67-7 titanium dioxide Oral LD50 >20000 mg/kg (rat) Dermal LD50 >10000 mg/kg (rbt) Inhalative LC50/4 h >6.82 mg/l (rat) 106-97-8 n-butane Inhalative LC50/4 h 658 mg/l (rat) 108-10-1 methyl isobutyl ketone Oral LD50 2100 mg/kg (rat) Dermal LD50 16000 mg/kg (rab) Inhalative LC50/4 h 8.3-16.6 mg/l (rat) 110-19-0 isobutyl acetate Oral LD50 4763 mg/kg (rbt) 1330-20-7 xylene (mix) Oral LD50 8700 mg/kg (rat) Dermal LD50 2000 mg/kg (rbt) Inhalative LC50/4 h 6350 mg/l (rat) Information on toxicological effects: No data available. (Contd. on page 4) Page 459 of 1287 Page 459 of 1287 Page 459 of 1287 Page 459 of 1287 ---PAGE BREAK--- Page 4/4 Safety Data Sheet Printing date 11/06/2014 Revised On 11/05/2014 Trade name: GLOSS WHITE (Contd. of page 3) 39.6.0 Sensitization: No sensitizing effects known. Carcinogenic categories IARC (International Agency for Research on Cancer) 13463-67-7 titanium dioxide 2B 108-10-1 methyl isobutyl ketone 2B 1330-20-7 xylene (mix) 3 NTP (National Toxicology Program) None of the ingredients is listed. 12 Ecological information Aquatic toxicity: Hazardous for water, do not empty into drains. Persistence and degradability: The product is degradable after prolonged exposure to natural weathering processes. Bioaccumulative potential: No further relevant information available. Mobility in soil: No further relevant information available. Other adverse effects: No further relevant information available. 13 Disposal considerations Dispose of in accordance with local, state, and federal regulations. Do not puncture, incinerate, or compact. Partially empty cans must be disposed of responsibly. Do not heat or cut empty containers with electric or gas torches. Recommendation: Completely empty cans should be recycled. 14 Transport information UN-Number UN1950 DOT Aerosols, flammable ADR 1950 Aerosols Transport hazard class(es): Class 2.1 Marine pollutant: No Special precautions for user: Warning: Gases EMS Number: F-D,S-U Packaging Group: UN "Model Regulation": UN1950, Aerosols, 2.1 15 Regulatory information SARA Section 355 (extremely hazardous substances): None of the ingredients in this product are listed. SARA Section 313 (Specific toxic chemical listings): 108-10-1 methyl isobutyl ketone 7727-43-7 barium sulphate, natural 1330-20-7 xylene (mix) CPSC: This product complies with 16 CFR 1303 and does not contain more than 90 ppm of lead. California Proposition 65 chemicals known to cause cancer: 13463-67-7 titanium dioxide 108-10-1 methyl isobutyl ketone 100-41-4 ethyl benzene CANADIAN ENVIRONMENTAL PROTECTION ACT: All hazardous ingredients for this product appear on the Canadian Domestice Substance List. EPA: 67-64-1 Acetone I 108-10-1 methyl isobutyl ketone I 7727-43-7 barium sulphate, natural D, CBD(inh), NL(oral) 110-19-0 isobutyl acetate D 1330-20-7 xylene (mix) I 16 Other information Contact: Regulatory Affairs Date of preparation / last revision 11/06/2014 / - Page 460 of 1287 Page 460 of 1287 Page 460 of 1287 Page 460 of 1287 ---PAGE BREAK--- 08/05/2015 Grainger MSDS Lookup 1/4 Common Name: GRAFFITI & SPRAY PAINT REMOVER Manufacturer: ITW PRO BRANDS MSDS Revision Date: 11/24/2014 MSDS Format: GHS-US Grainger Item Number(s): 2DBX9, 3U027, 3WGT3, 6KHD7, 6UAX9 Manufacturer Model Number(s): MSDS Table of Contents Click the desired link below to jump directly to that section in the MSDS. 1 IDENTIFICATION 2 HAZARD(S) IDENTIFICATION 3 COMPOSITION/INFORMATION ON INGREDIENTS 4 FIRST-AID MEASURES 5 FIRE-FIGHTING MEASURES 6 ACCIDENTAL RELEASE MEASURES 7 HANDLING AND STORAGE 8 EXPOSURE CONTROLS/PERSONAL PROTECTION 9 PHYSICAL AND CHEMICAL PROPERTIES 10 STABILITY AND REACTIVITY 11 TOXICOLOGICAL INFORMATION 12 ECOLOGICAL INFORMATION 13 DISPOSAL CONSIDERATIONS 14 TRANSPORT INFORMATION 15 REGULATORY INFORMATION 16 OTHER INFORMATION ITW PRO BRANDS SAFETY DATA SHEET ACC. TO HCS AND GHS PRINTING DATE: 11/24/2014 REVIEWED ON: 11/24/2014 1 IDENTIFICATION PRODUCT IDENTIFIER: TRADE NAME: GRAFFITI & SPRAY PAINT REMOVER ARTICLE NUMBER: 078 APPLICATION OF THE SUBSTANCE / THE MIXTURE: GRAFFITI REMOVER DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET: Page 461 of 1287 Page 461 of 1287 Page 461 of 1287 Page 461 of 1287 ---PAGE BREAK--- 08/05/2015 Grainger MSDS Lookup 2/4 MANUFACTURER/SUPPLIER: ITW PRO BRANDS 805 EAST OLD 56 HIGHWAY OLATHE, KANSAS 66061 PHONE: 1-[PHONE REDACTED] EMERGENCY TELEPHONE NUMBER: INFOTRAC EMERGENCY HOTLINE: 1-[PHONE REDACTED] 2 HAZARD(S) IDENTIFICATION CLASSIFICATION OF THE SUBSTANCE OR MIXTURE: GHS 04: GAS CYLINDER H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED. GHS02: FLAME FLAM. AEROSOL 1: H222-H229: EXTREMELY FLAMMABLE AEROSOL. PRESSURIZED CONTAINER: MAY BURST IF HEATED. GHS08: HEALTH HAZARD REPR. 2: H361 SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD. ROUTE OF EXPOSURE: INHALATIVE. STOT RE 2: H373: MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM THROUGH PROLONGED OR REPEATED EXPOSURE. ROUTE OF EXPOSURE: INHALATIVE. ASP. TOX. 1: H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. GHS07: EXCLAMATION MARK SKIN IRRIT. 2: H315: CAUSES SKIN IRRITATION. STOT SE 3: H336: MAY CAUSE DROWSINESS OR DIZZINESS. LABEL ELEMENTS: GHS LABEL ELEMENTS: THE PRODUCT IS CLASSIFIED AND LABELED ACCORDING TO THE GLOBALLY HARMONIZED SYSTEM (GHS). HAZARD PICTOGRAMS: GHS02: FLAME GHS07: EXCLAMATION MARK GHS08: HEALTH HAZARD Page 462 of 1287 Page 462 of 1287 Page 462 of 1287 Page 462 of 1287 ---PAGE BREAK--- 08/05/2015 Grainger MSDS Lookup 3/4 SIGNAL WORD: DANGER HAZARD-DETERMINING COMPONENTS OF LABELING: TOLUENE HAZARD STATEMENTS: H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED. H222-H229: EXTREMELY FLAMMABLE AEROSOL. PRESSURIZED CONTAINER: MAY BURST IF HEATED. H315: CAUSES SKIN IRRITATION. H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD. ROUTE OF EXPOSURE: INHALATIVE. H336: MAY CAUSE DROWSINESS OR DIZZINESS. H373: MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM THROUGH PROLONGED OR REPEATED EXPOSURE. ROUTE OF EXPOSURE: INHALATIVE. H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. PRECAUTIONARY STATEMENTS: P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. P251: PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE. P260: DO NOT BREATHE MIST/VAPOURS/SPRAY. P211: DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE. P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. P308+P313: IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION. P302+P352: IF ON SKIN: WASH WITH PLENTY OF WATER. P405: STORE LOCKED UP. P410+P412: PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C/122 DEG. F. P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER CLOSED. P501: DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS. ADDITIONAL INFORMATION: PRESSURIZED CONTAINER: MAY BURST IF HEATED. HAZARD DESCRIPTION: Page 463 of 1287 Page 463 of 1287 Page 463 of 1287 Page 463 of 1287 ---PAGE BREAK--- 08/05/2015 Grainger MSDS Lookup 4/4 WHMIS-SYMBOLS: A-COMPRESSED GAS B5- FLAMMABLE AEROSOL D2A - VERY TOXIC MATERIAL CAUSING OTHER TOXIC EFFECTS CLASSIFICATION SYSTEM: NFPA RATINGS (SCALE 0-4): HEALTH 1 FIRE 4 REACTIVITY 0 HMIS-RATINGS (SCALE 0-4): HEALTH 1* FIRE 4 REACTIVITY 0 * - INDICATES A LONG TERM HEALTH HAZARD FROM REPEATED OR PROLONGED EXPOSURES. OTHER HAZARDS: RESULTS OF PBT AND VPVB ASSESSMENT: PBT: NOT APPLICABLE. VPVB: NOT APPLICABLE. 3 COMPOSITION/INFORMATION ON INGREDIENTS CHEMICAL CHARACTERIZATION: MIXTURES DESCRIPTION: MIXTURE OF THE SUBSTANCES LISTED BELOW WITH NONHAZARDOUS ADDITIONS. DANGEROUS COMPONENTS: 108-88-3 TOLUENE 20-40% FLAM. LIQ. 2, H225 REPR. 2, H361 STOT RE 2, H373 ASP. TOX. 1, H304 SKIN IRRIT. 2, H315 STOT SE 3, H336 75-28-5 ISOBUTANE 10-20% FLAM. GAS 1, H220 111-76-2 2-BUTOXYETHANOL 1-5% ACUTE TOX. 4, H302 ACUTE TOX. 4, H312 ACUTE TOX. 4, H332 SKIN IRRIT. 2, H315 EYE IRRIT. 2, H319 FLAM. LIQ. 4 Y H227 74-98-6 PROPANE Page 464 of 1287 Page 464 of 1287 Page 464 of 1287 Page 464 of 1287 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 24-May-2011 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code P91021 Product name GRAFFITI-OFF 20 OZ NW Recommended Use Paint Remover Supplier Lawson Products, Inc. 1666 East Touhy Avenue Des Plaines, IL 60018 (847)-827-9666 Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Eyes. Skin contact. Inhalation. Ingestion. Potential health effects Eyes Contact with eyes may cause irritation. Skin Prolonged skin contact may cause skin irritation. Inhalation Prolonged overexposure may cause. Dizziness. Giddiness. Nausea. Repeated or prolonged exposure may cause the following effects. Respiratory system damage. Central nervous system effects. Liver damage. Kidney damage. Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Ingestion Swallowing substance may cause the following effects:. Irritating to mouth, throat and stomach. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % D-Limonene 5989-27-5 28-32 Acetone 67-64-1 15-20 Propane 74-98-6 15-20 N-Butane 106-97-8 10-15 1-Methyl-2-pyrrolidone 872-50-4 8-12 Alkyl Quanternary Ammonium Montmorillonite 68953-58-2 > 3 4. FIRST AID MEASURES Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If persist, call a physician. Skin contact Wash area thoroughly with soap and water. Remove and wash contaminated clothing before re-use. Ingestion Seek medical advice and bring MSDS or label. Do Not induce vomiting. Drink 1 or 2 glasses of water. Inhalation Remove to fresh air. Provide oxygen if breathing is difficult. Call a physician. 5. FIRE FIGHTING MEASURES Flash point °C -20 Flash point °F -4 Method Tag Closed Cup Autoignition temperature °C Not Applicable Autoignition temperature °F Not Applicable Flammability Limits in Air) Upper 12.8 Lower 2.6 Suitable extinguishing media Water fog. Foam. Dry chemical. Carbon dioxide. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Fire and Explosion Hazards Vapors are volatile and heavier than air. They will tend to collect in low lying areas. Hazardous decomposition products See Section 10. Sensitivity to shock No information available. Sensitivity to static discharge Yes. Take precautionary measures against static discharges. Page 1 / 4 Emergency Overview Flammable. Page 465 of 1287 Page 465 of 1287 Page 465 of 1287 Page 465 of 1287 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Soak up excess with absorbent material. Place in non-leaking, sealed container for proper disposal. 7. HANDLING AND STORAGE Handling Ensure adequate ventilation. Keep away from open flames, hot surfaces and sources of ignition. Do not puncture or incinerate. Avoid breathing vapors or mists. Avoid contact with skin, eyes and clothing. Thoroughly wash hands and exposed skin after handling. Do not take internally. For industrial and institutional use only. Storage Follow all label directions. Store in temperatures below 120 degrees F. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) D-Limonene - - - - Acetone 1000 ppm 2400 mg/m3 - 500 ppm 750 ppm Propane 1000 ppm 1800 mg/m3 - 1000 ppm - N-Butane - - 1000 ppm - 1-Methyl-2- pyrrolidone - - - - Alkyl Quanternary Ammonium Montmorillonit e - - - - Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Mechanical: required. Hygiene measures General industrial hygiene practice. Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment. Hand Protection Solvent resistant gloves. Eye protection Safety glasses. Skin and body protection None necessary under normal conditions 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color White Odor Hydrocarbon-like Odor Threshold Not Applicable pH Not Applicable Specific Gravity 0.7785 Vapor pressure Not Applicable Vapor density >1 (Air = 1) Evaporation Rate > 1 (ether = 1) Water solubility soluble VOC Content 5.34 lbs/gal; 639 g/l; 70% Partition Coefficient (n-octanol/water) No data available Boiling point/range °C > -42 Boiling point/range °F > -44 Melting point/range °C Not Applicable Melting point/range °F Not Applicable Flash point °C -20 Flash point °F -4 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid Avoid heat, sparks, and other sources of ignition. Incompatability None known. Hazardous Decomposition Products Carbon dioxide. Carbon monoxide. Fumes. Hydrocarbons. Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat) LD50 (dermal,rat/rabbi t) LC50 (inhalation,rat) D-Limonene 5989-27-5 4400 mg/kg 2000 mg/kg - Acetone 67-64-1 5800 mg/kg - - Propane 74-98-6 - - 658 mg/L N-Butane 106-97-8 - - 658 mg/L 1-Methyl-2- pyrrolidone 872-50-4 3598 mg/kg 2000 mg/kg 2500 mg/kg 3.1 mg/L Alkyl Quanternary Ammonium Montmorillonite 68953-58-2 5000 mg/kg - 12.6 mg/L Synergistic Products None known Page 2 / 4 Product name GRAFFITI- OFF 20 OZ NW Product code P91021 Page 466 of 1287 Page 466 of 1287 Page 466 of 1287 Page 466 of 1287 ---PAGE BREAK--- Potential health effects Sensitization None known Chronic toxicity None known Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects See Section 2 Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns D-Limonene Not Listed Not Listed Not Listed Not Listed Not Listed Acetone Not Listed Not Listed Not Listed Not Listed Not Listed Propane Not Listed Not Listed Not Listed Not Listed Not Listed N-Butane Not Listed Not Listed Not Listed Not Listed Not Listed 1-Methyl-2- pyrrolidone Not Listed Not Listed Not Listed Not Listed Not Listed Alkyl Quanternary Ammonium Montmorillonit e Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. Do not puncture or incinerate. 14. TRANSPORTATION INFORMATION DOT Consumer commodity, ORM-D TDG UN1950 AEROSOLS, flammable, 2.1 15. REGULATORY INFORMATION US EPA SARA 313 Chemical Name US EPA SARA 313 Emission Reporting 1-Methyl-2- pyrrolidone Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 D-Limonene Not Listed Not Listed Not Listed Acetone Not Listed Not Listed Not Listed Propane Listed Listed Not Listed N-Butane Not Listed Listed Not Listed 1-Methyl-2-pyrrolidone Not Listed Listed Developmental Alkyl Quanternary Ammonium Montmorillonite Not Listed Not Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA D-Limonene X X - X Acetone X X - X Propane X X - X N-Butane X X - X 1-Methyl-2-pyrrolidone X X - X Alkyl Quanternary Ammonium Montmorillonite X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION NFPA Health - 1 Flammability - 4 Reactivity - 0 HMIS Health - 1 Flammability - 4 Physical Hazard - 0 Prepared By H. Buck, Regulatory Affairs Manager Page 3 / 4 Water Flea Data water flea hEC50 48 (0.0039 mg/L) water flea hEC50 48 (12700 mg/L) Daphnia magna hEC50 48 (12600 mg/L) water flea hEC50 48 (0.0039 mg/L) Acetone 1-Methyl-2-pyrrolidone Product code P91021 Water Flea Data water flea hEC50 96 (3135 mg/L) Daphnia magna hEC50 48 (4897 mg/L) Microtox Data Photobacterium phosphoreum EC50=14500 mg/L (15 min) Product name GRAFFITI- OFF 20 OZ NW Page 467 of 1287 Page 467 of 1287 Page 467 of 1287 Page 467 of 1287 ---PAGE BREAK--- The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product code P91021 Product name GRAFFITI- OFF 20 OZ NW Page 468 of 1287 Page 468 of 1287 Page 468 of 1287 Page 468 of 1287 ---PAGE BREAK--- Page 469 of 1287 Page 469 of 1287 Page 469 of 1287 Page 469 of 1287 ---PAGE BREAK--- Page 470 of 1287 Page 470 of 1287 Page 470 of 1287 Page 470 of 1287 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Print Date: 07 Apr 2008 ®(TM)*Trademark of The Dow Chemical Company ("Dow") or an affiliated company of Dow Page 1 of 13 The Dow Chemical Company encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1. Product and Company Identification Product Name GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP COMPANY IDENTIFICATION The Dow Chemical Company 2030 Willard H. Dow Center Midland, MI 48674 USA Customer Information Number: [PHONE REDACTED] EMERGENCY TELEPHONE NUMBER 24-Hour Emergency Contact: [PHONE REDACTED] Local Emergency Contact: [PHONE REDACTED] 2. Hazards Identification Emergency Overview Color: Off-white Physical State: Foam Odor: Characteristic Hazards of product: DANGER! Flammable gas - May cause flash fire. May cause allergic skin reaction. May cause allergic respiratory reaction. May cause eye irritation. May cause skin irritation. Vapor reduces oxygen available for breathing. May cause anesthetic effects. May cause respiratory tract irritation. Vapors may travel a long distance; ignition and/or flash back may occur. Evacuate area. Keep upwind of spill. Stay out of low areas. Aerosol cans exposed to fire can rupture becoming flaming projectiles. Elevated temperatures can cause hazardous polymerization. Toxic fumes may be released in fire situations. Containers are under high pressure. Avoid temperatures above 49 °C (120 OSHA Hazard Communication Standard Material Safety Data Sheet The Dow Chemical Company Page 471 of 1287 Page 471 of 1287 Page 471 of 1287 Page 471 of 1287 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 2 of 13 This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Potential Health Effects Eye Contact: May cause eye irritation. May cause slight temporary corneal injury. Skin Contact: Prolonged contact may cause moderate skin irritation with local redness. Material may stick to skin causing irritation upon removal. May stain skin. Skin Absorption: Prolonged skin contact is unlikely to result in absorption of harmful amounts. Skin Sensitization: Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with isocyanates may play a role in respiratory sensitization. Inhalation: In confined or poorly ventilated areas, vapor can easily accumulate and can cause unconsciousness and death due to displacement of oxygen. Excessive exposure may cause irritation to upper respiratory tract (nose and throat) and lungs. May cause pulmonary edema (fluid in the lungs.) Effects may be delayed. May cause central nervous system depression. of excessive exposure may be anesthetic or narcotic effects; dizziness and drowsiness may be observed. Excessive exposure may increase sensitivity to epinephrine and increase myocardial irritability (irregular heartbeats). Decreased lung function has been associated with overexposure to isocyanates. Respiratory Sensitization: May cause allergic respiratory response. MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in individuals already sensitized. Asthma-like may include coughing, difficult breathing and a feeling of tightness in the chest. Occasionally, breathing difficulties may be life threatening. Ingestion: Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury. Observations in animals include: Gastrointestinal irritation. Effects of Repeated Exposure: Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after repeated excessive exposures to MDI/polymeric MDI aerosols. Contains component(s) which have been reported to cause effects on the following organs in animals: Kidney. Liver. Bone marrow. Contains a component which is reported to be a weak organophosphate-type cholinesterase inhibitor. Excessive exposure may produce organophosphate type cholinesterase inhibition. Signs and of excessive exposure may be headache, dizziness, incoordination, muscle twitching, tremors, nausea, abdominal cramps, diarrhea, sweating, pinpoint pupils, blurred vision, salivation, tearing, tightness in chest, excessive urination, convulsions. Cancer Information: Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory irritation and lung injury. Current exposure guidelines are expected to protect against these effects reported for MDI. Birth Defects/Developmental Effects: In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only at high doses which were toxic to the mother. Component CAS # Amount Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 15.0 - 30.0 % Isocyanic acid, polymethylenepolyphenylene ester, polymer with .alpha.,.alpha.',.alpha.''-1,2,3- propanetriyltris[.omega.-hydroxypoly 57029-46-6 30.0 - 60.0 % Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol coopolymer 53862-89-8 15.0 - 30.0 % Isobutane 75-28-5 7.0 - 13.0 % Paraffin waxes and Hydrocarbon waxes, chlorinated 63449-39-8 5.0 - 10.0 % Tris(1-chloro-2-propyl) phosphate 13674-84-5 5.0 - 10.0 % Propane 74-98-6 1.0 - 5.0 % Methyl ether 115-10-6 1.0 - 5.0 % 4,4' -Methylenediphenyl diisocyanate 101-68-8 5.0 - 10.0 % Note: CAS 101-68-8 is an MDI isomer that is part of CAS 9016-87-9. 3. Composition Information Page 472 of 1287 Page 472 of 1287 Page 472 of 1287 Page 472 of 1287 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 3 of 13 4. First-aid measures Eye Contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5 minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist. Skin Contact: Remove material from skin immediately by washing with soap and plenty of water. Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists. Wash clothing before reuse. An MDI skin decontamination study demonstrated that cleaning very soon after exposure is important, and that a skin cleanser or corn oil may be more effective than soap and water. Discard items which cannot be decontaminated, including leather articles such as shoes, belts and watchbands. Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility. Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel. Notes to Physician: Maintain adequate ventilation and oxygenation of the patient. May cause asthma-like (reactive airways) Bronchodilators, expectorants, antitussives and corticosteroids may be of help. May cause respiratory sensitization or asthma-like Bronchodilators, expectorants and antitussives may be of help. Treat bronchospasm with inhaled beta2 agonist and oral or parenteral corticosteroids. Respiratory including pulmonary edema, may be delayed. Persons receiving significant exposure should be observed 24-48 hours for signs of respiratory distress. Exposure may increase "myocardial irritability". Do not administer sympathomimetic drugs such as epinephrine unless absolutely necessary. If you are sensitized to diisocyanates, consult your physician regarding working with other respiratory irritants or sensitizers. Although cholinesterase depression has been reported with this material, it is not of benefit in determining exposure and need not be considered in the treatment of persons exposed to the material. No specific antidote. Treatment of exposure should be directed at the control of and the clinical condition of the patient. Medical Conditions Aggravated by Exposure: Excessive exposure may aggravate preexisting asthma and other respiratory disorders (e.g. bronchitis, reactive airways dysfunction 5. Fire Fighting Measures Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Do not use direct water stream. Straight or direct water streams may not be effective to extinguish fire. Alcohol resistant foams (ATC type) are preferred. General purpose foams (including AFFF) or protein foams may function, but will be less effective. Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay upwind. Keep out of low areas where gases (fumes) can accumulate. Water may not be effective in extinguishing fire. Do not use direct water stream. May spread fire. Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Eliminate ignition sources. Move container from fire area if this is possible without hazard. Use water spray to cool fire- exposed containers and fire-affected zone until fire is out. Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer to the relevant sections. Unusual Fire and Explosion Hazards: Contains flammable propellant. Aerosol cans exposed to fire can rupture and become flaming projectiles. Propellant release may result in a fireball. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Dense smoke is produced when product burns. Page 473 of 1287 Page 473 of 1287 Page 473 of 1287 Page 473 of 1287 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 4 of 13 Hazardous Combustion Products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Nitrogen oxides. Isocyanates. Hydrogen chloride. Carbon monoxide. Carbon dioxide. 6. Accidental Release Measures Steps to be Taken if Material is Released or Spilled: Contain spilled material if possible. Ground and bond all containers and handling equipment. Isolate area until gas has dispersed. Use non- sparking tools in cleanup operations. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Collect in suitable and properly labeled containers. Absorb with materials such as: Clay. Dirt. Milsorb®. Sand. Sawdust. Vermiculite. See Section 10 for more specific information. See Section 13, Disposal Considerations, for additional information. Personal Precautions: Evacuate area. Only trained and properly protected personnel must be involved in clean-up operations. Keep personnel out of low areas. Keep personnel out of confined or poorly ventilated areas. Keep upwind of spill. Ventilate area of leak or spill. No smoking in area. For large spills, warn public of downwind explosion hazard. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Vapor explosion hazard. Keep out of sewers. See Section 10 for more specific information. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection. Refer to Section 7, Handling, for additional precautionary measures. Environmental Precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. 7. Handling and Storage Handling General Handling: Keep away from heat, sparks and flame. Avoid contact with eyes. Avoid contact with skin and clothing. Avoid prolonged or repeated contact with skin. Avoid breathing vapor. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. Keep out of reach of children. No smoking, open flames or sources of ignition in handling and storage area. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Contents under pressure. Do not puncture or incinerate container. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers. Do not enter confined spaces unless adequately ventilated. Never use air pressure for transferring product. Use of non-sparking or explosion-proof equipment may be necessary, depending upon the type of operation. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION. Storage Minimize sources of ignition, such as static build-up, heat, spark or flame. Store in a dry place. See Section 10 for more specific information. Shelf life: Use within 12 Months 20 - 30 °C 8. Exposure Controls / Personal Protection Exposure Limits Component List Type Value I 4,4' -Methylenediphenyl diisocyanate ACGIH TWA 0.005 ppm Page 474 of 1287 Page 474 of 1287 Page 474 of 1287 Page 474 of 1287 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 5 of 13 OSHA Table Z-1 Ceiling 0.2 mg/m3 0.02 ppm I Methyl ether WEEL TWA 1,880 mg/m3 1,000 ppm I Isobutane ACGIH TWA 1,000 ppm I Propane OSHA Table Z-1 PEL 1,800 mg/m3 1,000 ppm ACGIH TWA 1,000 ppm I Personal Protection Eye/Face Protection: Use safety glasses. Eye wash fountain should be located in immediate work area. Skin Protection: Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task. Remove contaminated clothing immediately, wash skin area with soap and water, and launder clothing before reuse or dispose of properly. Items which cannot be decontaminated, such as shoes, belts and watchbands, should be removed and disposed of properly. Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove barrier materials include: Butyl rubber. Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Examples of acceptable glove barrier materials include: Natural rubber ("latex"). Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Viton. Polyvinyl chloride ("PVC" or "vinyl"). NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier. Respiratory Protection: Atmospheric levels should be maintained below the exposure guideline. When atmospheric levels may exceed the exposure guideline, use an approved air-purifying respirator equipped with an organic vapor sorbent and a particle filter. For situations where the atmospheric levels may exceed the level for which an air-purifying respirator is effective, use a positive-pressure air-supplying respirator (air line or self-contained breathing apparatus). For emergency response or for situations where the atmospheric level is unknown, use an approved positive-pressure self- contained breathing apparatus or positive-pressure air line with auxiliary self-contained air supply. The following should be effective types of air-purifying respirators: Organic vapor cartridge with a particulate pre-filter. Ingestion: Use good personal hygiene. Do not consume or store food in the work area. Wash hands before smoking or eating. Engineering Controls Ventilation: Use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations. Provide general and/or local exhaust ventilation to control airborne levels below the exposure guidelines. Exhaust systems should be designed to move the air away from the source of vapor/aerosol generation and people working at this point. The odor and irritancy of this material are inadequate to warn of excessive exposure. 9. Physical and Chemical Properties Physical State Foam Color Off-white Odor Characteristic Flash Point - Closed Cup -104 °C (-155 Calculated Flammable Limits In Air Lower: No test data available Upper: No test data available Autoignition Temperature No test data available Vapor Pressure 1,151 kPa @ 55 °C Estimated Boiling Point (760 mmHg) Not applicable. Vapor Density (air = 1) No test data available Specific Gravity (H2O = 1) 1.06 Estimated Page 475 of 1287 Page 475 of 1287 Page 475 of 1287 Page 475 of 1287 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 6 of 13 Freezing Point No test data available Melting Point No test data available Solubility in Water (by weight) Insoluble pH Not applicable 10. Stability and Reactivity Stability/Instability Stable under recommended storage conditions. See Storage, Section 7. Unstable at elevated temperatures. Conditions to Avoid: Avoid temperatures above 49 °C (120 Elevated temperatures can cause container to vent and/or rupture. Exposure to elevated temperatures can cause product to decompose. Incompatible Materials: Avoid contact with: Acids. Alcohols. Amines. Ammonia. Bases. Metal compounds. Strong oxidizers. Products based on diisocyanates like TDI and MDI react with many materials to release heat. The reaction rate increases with temperature as well as with increased contact; these reactions can become violent. Contact is increased by stirring or if the other material acts as a solvent. Products based on diisocyanates such as TDI and MDI are not soluble in water and will sink to the bottom, but react slowly at the interface. The reaction forms carbon dioxide gas and a layer of solid polyurea. Reaction with water will generate carbon dioxide and heat. Hazardous Polymerization Can occur. Elevated temperatures can cause hazardous polymerization. Thermal Decomposition Decomposition products depend upon temperature, air supply and the presence of other materials. Toxic gases are released during decomposition. 11. Toxicological Information Acute Toxicity Ingestion Single dose oral LD50 has not been determined. Estimated LD50, Rat > 10,000 mg/kg Skin Absorption The LD50 has not been determined. Estimated LD50, Rabbit > 2,000 mg/kg Inhalation The LC50 has not been determined. Estimated LC50, Aerosol, Rat > 0.5 mg/l Sensitization Skin Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with isocyanates may play a role in respiratory sensitization. Respiratory May cause allergic respiratory response. MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in individuals already sensitized. Asthma-like may include coughing, difficult breathing and a feeling of tightness in the chest. Occasionally, breathing difficulties may be life threatening. Repeated Dose Toxicity Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after repeated excessive exposures to MDI/polymeric MDI aerosols. Contains component(s) which have been reported to cause effects on the following organs in animals: Kidney. Liver. Bone marrow. Contains a component which is reported to be a weak organophosphate-type cholinesterase inhibitor. Excessive exposure may produce organophosphate type cholinesterase inhibition. Signs and of excessive exposure may be headache, dizziness, incoordination, muscle twitching, Page 476 of 1287 Page 476 of 1287 Page 476 of 1287 Page 476 of 1287 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 7 of 13 tremors, nausea, abdominal cramps, diarrhea, sweating, pinpoint pupils, blurred vision, salivation, tearing, tightness in chest, excessive urination, convulsions. Chronic Toxicity and Carcinogenicity Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory irritation and lung injury. Current exposure guidelines are expected to protect against these effects reported for MDI. Developmental Toxicity In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only at high doses which were toxic to the mother. Genetic Toxicology In vitro genetic toxicity studies were negative for component(s) tested. Genetic toxicity data on MDI are inconclusive. MDI was weakly positive in some in vitro studies; other in vitro studies were negative. Animal mutagenicity studies were predominantly negative. 12. Ecological Information CHEMICAL FATE Data for Component: Diphenylmethane Diisocyanate, isomers and homologues Movement & Partitioning In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Persistence and Degradability In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. Data for Component: Isocyanic acid, polymethylenepolyphenylene ester, polymer with .alpha.,.alpha.',.alpha.''-1,2,3-propanetriyltris[.omega.-hydroxypoly Movement & Partitioning In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Persistence and Degradability In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. Data for Component: Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol coopolymer Movement & Partitioning In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Persistence and Degradability In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. Data for Component: Isobutane Movement & Partitioning Bioconcentration potential is low (BCF less than 100 or log Pow less than Potential for mobility in soil is very high (Koc between 0 and 50). Page 477 of 1287 Page 477 of 1287 Page 477 of 1287 Page 477 of 1287 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 8 of 13 Henry's Law Constant 1.19E+00 atm*m3/mole; 25 °C Measured Partition coefficient, n-octanol/water (log Pow): 2.76 Measured Partition coefficient, soil organic carbon/water (Koc): 35 Estimated Distribution in Environment: Mackay Level 1 Fugacity Model: Air Water. Biota Soil Sediment 100 % 0 % 0 % 0 % 0 % Persistence and Degradability Biodegradation may occur under aerobic conditions (in the presence of oxygen). Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 2.44E-12 cm3/s 4.4 d Estimated Theoretical Oxygen Demand: 3.58 mg/mg Data for Component: Paraffin waxes and Hydrocarbon waxes, chlorinated Movement & Partitioning Expected to be relatively immobile in soil (Koc > 5000). Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected to be an important fate process. Henry's Law Constant < 1.0E-07 atm*m3/mole; 25 °C Estimated Partition coefficient, n-octanol/water (log Pow): > 6 Estimated Persistence and Degradability Expected to degrade only slowly in the environment. Data for Component: Tris(1-chloro-2-propyl) phosphate Movement & Partitioning Bioconcentration potential is low (BCF < 100 or Log Pow < Potential for mobility in soil is low (Koc between 500 and 2000). Henry's Law Constant < 1.35E-5 atm*m3/mole; 25 °C Estimated Partition coefficient, n-octanol/water (log Pow): 2.59 Measured Partition coefficient, soil organic carbon/water (Koc): 1,300 Estimated Bioconcentration Factor (BCF): 0.8 - 4.6; common carp (Cyprinus carpio); Measured Persistence and Degradability Material is expected to biodegrade only very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 4.47E-11 cm3/s 0.24 d Estimated OECD Biodegradation Tests: Biodegradation Exposure Time Method 14 % 28 d OECD 301E Test Theoretical Oxygen Demand: 1.17 mg/mg Data for Component: Propane Movement & Partitioning Bioconcentration potential is low (BCF less than 100 or log Pow less than Potential for mobility in soil is very high (Koc between 0 and 50). Henry's Law Constant 7.07E-01 atm*m3/mole; 25 °C Measured Partition coefficient, n-octanol/water (log Pow): 2.36 Measured Partition coefficient, soil organic carbon/water (Koc): 24 - 460 Estimated Distribution in Environment: Mackay Level 1 Fugacity Model: Air Water. Biota Soil Sediment 100 % 0 % 0 % 0 % 0 % Persistence and Degradability No relevant information found. Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 1.27E-12 cm3/s 8.4 d Estimated Page 478 of 1287 Page 478 of 1287 Page 478 of 1287 Page 478 of 1287 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 9 of 13 Theoretical Oxygen Demand: 3.64 mg/mg Data for Component: Methyl ether Movement & Partitioning Bioconcentration potential is low (BCF less than 100 or log Pow less than Potential for mobility in soil is very high (Koc between 0 and 50). Henry's Law Constant 9.78E-4 atm*m3/mole; 25 °C Measured Partition coefficient, n-octanol/water (log Pow): 0.10 Measured Partition coefficient, soil organic carbon/water (Koc): 1.29 - 14 Estimated Persistence and Degradability Material is expected to biodegrade only very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 1.66E-12 cm3/s 6.4 d Estimated OECD Biodegradation Tests: Biodegradation Exposure Time Method 5 % 28 d OECD 301A Test Theoretical Oxygen Demand: 2.08 mg/mg Data for Component: 4,4' -Methylenediphenyl diisocyanate Movement & Partitioning In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Persistence and Degradability In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. ECOTOXICITY Data for Component: Diphenylmethane Diisocyanate, isomers and homologues The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Toxicity to Soil Dwelling Organisms LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg Data for Component: Isocyanic acid, polymethylenepolyphenylene ester, polymer with .alpha.,.alpha.',.alpha.''-1,2,3-propanetriyltris[.omega.-hydroxypoly The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Toxicity to Soil Dwelling Organisms LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg Data for Component: Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol coopolymer The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Toxicity to Soil Dwelling Organisms LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg Data for Component: Isobutane No relevant information found. Data for Component: Paraffin waxes and Hydrocarbon waxes, chlorinated Page 479 of 1287 Page 479 of 1287 Page 479 of 1287 Page 479 of 1287 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 10 of 13 Material is practically non-toxic to fish on an acute basis (LC50 > 100 mg/L). Material is very highly toxic to aquatic invertebrates on an acute basis (LC50/EC50 < 0.1 mg/L). Fish Acute & Prolonged Toxicity LC50, rainbow trout mykiss), static, 96 h: > 100 mg/l Aquatic Invertebrate Acute Toxicity EC50, water flea Daphnia magna, immobilization: 0.037 mg/l Data for Component: Tris(1-chloro-2-propyl) phosphate Material is toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and 100 mg/L in the most sensitive species tested). Fish Acute & Prolonged Toxicity LC50, bluegill (Lepomis macrochirus), 96 h: 84 mg/l Aquatic Invertebrate Acute Toxicity EC50, water flea Daphnia magna, 48 h, immobilization: 63 mg/l Aquatic Plant Toxicity EC50, green alga Selenastrum capricornutum, biomass growth inhibition, 96 h: 47 mg/l EC50, alga Scenedesmus sp., biomass growth inhibition, 72 h: 45 mg/l Toxicity to Micro-organisms EC50, OECD 209 Test; activated sludge, respiration inhibition, 3 h: 784 mg/l Data for Component: Propane No relevant information found. Data for Component: Methyl ether Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Fish Acute & Prolonged Toxicity LC50, guppy (Poecilia reticulata), 96 h: > 4,000 mg/l Aquatic Invertebrate Acute Toxicity LC50, water flea Daphnia magna, 48 h: > 4,000 mg/l Data for Component: 4,4' -Methylenediphenyl diisocyanate The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Toxicity to Soil Dwelling Organisms LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg 13. Disposal Considerations DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. DOW HAS NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed, permitted: Incinerator or other thermal destruction device. As a service to its customers, Dow can provide names of information resources to help identify waste management companies and other facilities which recycle, reprocess or manage chemicals or plastics, and that manage used drums. Telephone Dow's Customer Information Group at 1-[PHONE REDACTED] or 1-989- 832-1556 or 1-[PHONE REDACTED] (Canada) for further details. Page 480 of 1287 Page 480 of 1287 Page 480 of 1287 Page 480 of 1287 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 11 of 13 14. Transport Information DOT Non-Bulk CONSUMER COMMODITY RECLASSIFIED AS ORM-D MATERIAL DOT Bulk NOT AVAILABLE IN BULK CONTAINERS IMDG Proper Shipping Name: AEROSOLS, FLAMMABLE Hazard Class: 2.1 ID Number: UN1950 EMS Number: F-D,S-U LIMITED QUANTITY ICAO/IATA Proper Shipping Name: AEROSOLS, FLAMMABLE Hazard Class: 2.1 ID Number: UN1950Cargo Packing Instruction: 203 Passenger Packing Instruction: 203 LIMITED QUANTITY This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Additional transportation system information can be obtained through an authorized sales or customer service representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material. 15. Regulatory Information OSHA Hazard Communication Standard This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Sections 311 and 312 Immediate (Acute) Health Hazard Yes Delayed (Chronic) Health Hazard Yes Fire Hazard Yes Reactive Hazard No Sudden Release of Pressure Hazard Yes Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Section 313 This product contains the following substances which are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and which are listed in 40 CFR 372. Component CAS # Amount 4,4' -Methylenediphenyl diisocyanate 101-68-8 5.0 - 10.0 % Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 15.0 - 30.0 % (Worker and Community Right-To-Know Act): Hazardous Substances List and/or Environmental Hazardous Substance List: The following product components are cited in the Hazardous Substance List and/or the Environmental Substance List, and are present at levels which require reporting. Page 481 of 1287 Page 481 of 1287 Page 481 of 1287 Page 481 of 1287 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 12 of 13 Component CAS # Amount 4,4' -Methylenediphenyl diisocyanate 101-68-8 5.0 - 10.0 % Methyl ether 115-10-6 1.0 - 5.0 % Propane 74-98-6 1.0 - 5.0 % Isobutane 75-28-5 7.0 - 13.0 % (Worker and Community Right-To-Know Act): Special Hazardous Substances List: To the best of our knowledge, this product does not contain chemicals at levels which require reporting under this statute. California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986) This product contains no listed substances known to the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute. US. Toxic Substances Control Act All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.30 CEPA - Domestic Substances List (DSL) All substances contained in this product are listed on the Canadian Domestic Substances List (DSL) or are not required to be listed. 16. Other Information Recommended Uses and Restrictions Polyurethane foam. Revision Identification Number: 68906 / 1001 / Issue Date 01/31/2008 / Version: 2.0 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. Legend N/A Not available W/W Weight/Weight OEL Occupational Exposure Limit STEL Short Term Exposure Limit TWA Time Weighted Average ACGIH American Conference of Governmental Industrial Hygienists, Inc. DOW IHG Dow Industrial Hygiene Guideline WEEL Workplace Environmental Exposure Level HAZ_DES Hazard Designation Action Level A value set by OSHA that is lower than the PEL which will trigger the need for activities such as exposure monitoring and medical surveillance if exceeded. The Dow Chemical Company urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have Page 482 of 1287 Page 482 of 1287 Page 482 of 1287 Page 482 of 1287 ---PAGE BREAK--- Product Name: GREAT STUFF (TM) Gaps & Cracks Foam Sealant 16oz HC QP Issue Date: 01/31/2008 Page 13 of 13 obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version. Page 483 of 1287 Page 483 of 1287 Page 483 of 1287 Page 483 of 1287 ---PAGE BREAK--- N950 Page 1 of 2 5332 Dansher Road Illinois 60525 MATERIAL SAFETY DATA SHEET Revision Date: 4/6/2012 MSDS No. N950 Supersedes Date: 10/4/2011 Emergency Phones: [PHONE REDACTED] (NYCO) [PHONE REDACTED] (CHEMTREC) PLEASE NOTE: This MSDS is being provided to your company for the purpose of providing current health and safety information to your management and for your employees who work with this material. Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT-TO-KNOW regulations. Also make this information available to any employee who requests it. It is your obligation to comply with these regulations. SECTION I - PRODUCT IDENTITY PRODUCT NAME: GREEN KLEEN MULTI-PURPOSE CLEANER DEGREASER Formula: Mixture of propylene glycol ethers and detergents in water. Chemical Type: Organic compounds in water HMIS RATINGS Health = 0 (Minimal) Flammability = 0 (Minimal) Reactivity = 0 (Minimal) Protection = B (Safety goggles & gloves) SECTION II - HAZARDOUS INGREDIENTS CARCINOGEN PERCENT TLV (OSHA,TP,IARC) Dipropylene glycol methyl ether CAS # 34590-94-8 1-5% TWA – 100 ppm STEL – 150 ppm No SECTION III - CHEMICAL AND PHYSICAL Appearance: Clear Green Liquid Boiling Point: 212OF Odor: Sassafras Melting Point: N/A pH: 10.0-11.5 Spec. Gravity (H20 = 1.01 Water Solubility: Complete Vapor Pressure (Mm Hg): N/A Viscosity @ 25°C.: < 25 cps (Brookfield) VOC Content: 3.5% SECTION IV - FIRE AND EXPLOSION HAZARDS Flash Point (Method): > 200oF. (TCC) Explosion Limits: Upper: N/A Lower: N/A Extinguishing Media: Water fog, CO2, halon system, foam Special Firefighting Procedures and Hazards: Minimize prolonged skin and eye contact. Wear eye protection if exposure to liquid is likely. SECTION V - REACTIVITY INFORMATION Stable: Unstable: Precautions: Incompatibility: None known Hazardous Decomposition Products: If in a fire: CO, CO2, hydrocarbons. Hazardous Polymerization: Occurs: Does Not Occur: Page 484 of 1287 Page 484 of 1287 Page 484 of 1287 Page 484 of 1287 ---PAGE BREAK--- N950 Page 2 of 2 SECTION VI - HEALTH HAZARDS - PROTECTIVE MEASURES - FIRST AID Inhalation: Breathing of mists may cause irritation. Wear an approved mist respirator if exposure is likely. Remove to fresh air. Give artificial respiration or oxygen if needed. Skin: Extended contact may cause irritation and defatting. Wear protective gloves if needed. Wash skin with soap and plenty of water. Remove contaminated clothing and wash before wearing again. Eye: May cause irritation from misting. Wear splash proof goggles as needed. Flush with water for 15 minutes. If irritation persists consult a doctor. Ingestion: May cause mild gastric disturbances, nausea. Avoid swallowing. Drink lots of water or, preferably, milk. Do not induce vomiting. Get medical attention if effects persist. Most likely routes of entry: Skin, Eyes. Other Important Medical or Precautionary Information: None SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE Spills and Leaks: Small spills can be flushed into normal drainage or into ground with copious amounts of water, or taken up with absorbent material. Do not drain to sewer without dilution. Larger spills should be contained by diking or other methods and held for disposal or reuse. Storage and Handling: Check daily for any leaks from containers, vessels, pumps, and piping. Waste Disposal: May be disposable in sewers if local regulations permit. Otherwise, send to licensed treatment and disposal facility. Rinse well before handling and disposal. Observe label precautions. Empty Containers: Rinse well before handling and disposal. Observe label precautions. Other Precautions: N/A SECTION VIII - REGULATORY INFORMATION Reportable for SARA Title III, S.313 (Form None The information herein has been compiled from sources believed to be reliable and is accurate to the best of our knowledge. However, NYCO Products Company cannot give any guarantees regarding information from other sources, and expressly does not make any warranties, nor assumes any liability, for its use. Page 485 of 1287 Page 485 of 1287 Page 485 of 1287 Page 485 of 1287 ---PAGE BREAK--- Page 1/5 Safety Data Sheet acc. to OSHA HCS Printing date 10/13/2014 Revised On 10/13/2014 39.6.0 1 Identification of the substance and manufacturer Trade name: GREEN REBAR EPOXY Product code: [PHONE REDACTED] Product category PC9a Paints and coatings. Manufacturer/Supplier: Seymour of Sycamore 917 Crosby Avenue Sycamore, IL 60178 Phone: [PHONE REDACTED] www.seymourpaint.com Emergency telephone number: CHEMTEL 1-[PHONE REDACTED], [PHONE REDACTED] *if located outside the U.S.* 2 Hazard(s) identification Classification of the substance or mixture Flam. Aerosol 1 H222 Extremely flammable aerosol. Press. Gas H280 Contains gas under pressure; may explode if heated. Carc. 2 H351 Suspected of causing cancer. STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. Eye Irrit. 2A H319 Causes serious eye irritation. STOT SE 3 H336 May cause drowsiness or dizziness. GHS Hazard pictograms GHS02 GHS04 GHS07 GHS08 Signal word Danger Hazard statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Suspected of causing cancer. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure. Precautionary statements If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. Obtain special instructions before use. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash hands thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. IF INHALED: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. If eye irritation persists: Get medical advice/attention. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 Store in a well-ventilated place. Keep container closed. Dispose of contents/container in accordance with local/regional/national/international regulations. 3 Composition/information on ingredients Chemical characterization: Mixtures Chemical Description: This product is a mixture of the substances listed below with nonhazardous additions. Dangerous components: 67-64-1 Acetone 26.43% 74-98-6 propane 15.75% 106-97-8 n-butane 9.25% 1330-20-7 xylene (mix) 8.14% 66402-68-4 Calcium Strontium Zinc Phosphosilicate 6.71% 110-19-0 isobutyl acetate 5.32% 64-17-5 ethyl alcohol 4.14% 64742-89-8 VM&P Naphtha 2.1% 64742-47-8 Mineral Spirits 1.9% 108-65-6 PM acetate 1.86% 13463-67-7 titanium dioxide 1.84% 100-41-4 ethyl benzene 1.79% 4 First-aid measures After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Remove contaminated clothing. Wash exposed area with soap and water. After eye contact: Rinse opened eye for several minutes under running water. If persist, consult a doctor. After swallowing: Rinse mouth with water. Do not induce vomiting. (Contd. on page 2) US4 Page 486 of 1287 Page 486 of 1287 Page 486 of 1287 Page 486 of 1287 ---PAGE BREAK--- Page 2/5 Safety Data Sheet acc. to OSHA HCS Printing date 10/13/2014 Revised On 10/13/2014 Trade name: GREEN REBAR EPOXY (Contd. of page 1) 39.6.0 Most important and effects: Dizziness Indication of any immediate medical attention needed: No further relevant information available. 5 Fire-fighting measures Extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray. Special hazards: Can form explosive gas-air mixtures. Protective equipment for firefighters: A respiratory protective device may be necessary. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures: Use respiratory protective device against the effects of fumes/dust/aerosol. Methods and material for containment and cleaning up: Absorb liquid components with liquid-binding material. 7 Handling and storage Precautions for safe handling Use only in well ventilated areas. Storage requirements: Keep away from sources of heat and direct sunlight. Do not warehouse in subfreezing conditions. Store locked up. 8 Exposure controls/personal protection Components with limit values that require monitoring at the workplace: 67-64-1 Acetone PEL (USA) Long-term value: 2400 mg/m³, 1000 ppm REL (USA) Long-term value: 590 mg/m³, 250 ppm TLV (USA) Short-term value: (1782) NIC-1187 mg/m³, (750) NIC-500 ppm Long-term value: (1188) NIC-594 mg/m³, (500) NIC-250 ppm BEI 74-98-6 propane PEL (USA) Long-term value: 1800 mg/m³, 1000 ppm REL (USA) Long-term value: 1800 mg/m³, 1000 ppm TLV (USA) refer to Appendix F 106-97-8 n-butane REL (USA) Long-term value: 1900 mg/m³, 800 ppm TLV (USA) Short-term value: 2370 mg/m³, 1000 ppm 1330-20-7 xylene (mix) PEL (USA) Long-term value: 435 mg/m³, 100 ppm REL (USA) Short-term value: 655 mg/m³, 150 ppm Long-term value: 435 mg/m³, 100 ppm TLV (USA) Short-term value: 651 mg/m³, 150 ppm Long-term value: 434 mg/m³, 100 ppm BEI 110-19-0 isobutyl acetate PEL (USA) Long-term value: 700 mg/m³, 150 ppm REL (USA) Long-term value: 700 mg/m³, 150 ppm TLV (USA) Long-term value: 713 mg/m³, 150 ppm 64-17-5 ethyl alcohol PEL (USA) Long-term value: 1900 mg/m³, 1000 ppm REL (USA) Long-term value: 1900 mg/m³, 1000 ppm TLV (USA) Short-term value: 1880 mg/m³, 1000 ppm 108-65-6 PM acetate WEEL (USA) Long-term value: 50 ppm 100-41-4 ethyl benzene PEL (USA) Long-term value: 435 mg/m³, 100 ppm REL (USA) Short-term value: 545 mg/m³, 125 ppm Long-term value: 435 mg/m³, 100 ppm TLV (USA) Long-term value: 87 mg/m³, 20 ppm BEI Ingredients with biological limit values: 67-64-1 Acetone BEI (USA) 50 mg/L Medium: urine Time: end of shift Parameter: Acetone (nonspecific) (Contd. on page 3) US4 Page 487 of 1287 Page 487 of 1287 Page 487 of 1287 Page 487 of 1287 ---PAGE BREAK--- Page 3/5 Safety Data Sheet acc. to OSHA HCS Printing date 10/13/2014 Revised On 10/13/2014 Trade name: GREEN REBAR EPOXY (Contd. of page 2) 39.6.0 1330-20-7 xylene (mix) BEI (USA) 1.5 g/g creatinine Medium: urine Time: end of shift Parameter: acids 100-41-4 ethyl benzene BEI (USA) 0.7 g/g creatinine Medium: urine Time: end of shift at end of workweek Parameter: Sum of mandelic acid and acid (nonspecific, semi-quantitative) - Medium: end-exhaled air Time: not critical Parameter: Ethyl benzene (semi-quantitative) Hygienic protection: Immediately remove all soiled and contaminated clothing. Wash hands after use. Avoid contact with the eyes and skin. Do not eat or drink while working. Breathing equipment: A respirator is generally not necessary when using this product outdoors or in large open areas. In cases where short and/or long term overexposure exists, a charcoal filter respirator should be worn. If you suspect overexposure conditions exist, please consult an authority on chemical hygeine. Hand protection: Protective gloves. The glove material must be impermeable and resistant to the substance. Eye protection: sealed goggles 9 Physical and chemical properties Appearance: Aerosol. Odor: Aromatic Odor threshold: Not determined. pH-value: Not determined. Melting point/Melting range Undetermined. Boiling point: -44 °C (-47 Flash point: -19 °C Flammability (solid, gas): Extremely flammable. Decomposition temperature: Not determined. Auto igniting: Product is not self-igniting. Danger of explosion: In use, may form flammable/explosive vapour-air mixture. Lower Explosion Limit: 1.7 Vol % Upper Explosion Limit: 10.9 Vol % Vapor pressure: Not determined. Relative Density: Between 0.77 and 0.85 (Water equals 1.00) Vapour density Not determined. Evaporation rate Not applicable. Partition coefficient: n-octonal/water: Not determined. Solubility: Not determined. Viscosity: Not determined. VOC content: 555.1 g/l / 4.63 lb/gl VOC content (less exempt solvents): 51.0 % MIR Value: 1.22 Solids content: 22.3 % 10 Stability and reactivity Reactivity: Stable at normal temperatures. Conditions to avoid: Do not allow can to exceed 120 degrees Fahrenheit. Do not warehouse in subfreezing temperatures. Chemical stability: Not fully evaluated. Possibility of hazardous reactions: No dangerous reactions known. Incompatible materials: No further relevant information available. Hazardous decomposition: No dangerous decomposition products known. 11 Toxicological information LD/LC50 values that are relevant for classification: 106-97-8 n-butane Inhalative LC50/4 h 658 mg/l (rat) 1330-20-7 xylene (mix) Oral LD50 8700 mg/kg (rat) Dermal LD50 2000 mg/kg (rbt) Inhalative LC50/4 h 6350 mg/l (rat) (Contd. on page 4) US4 Page 488 of 1287 Page 488 of 1287 Page 488 of 1287 Page 488 of 1287 ---PAGE BREAK--- Page 4/5 Safety Data Sheet acc. to OSHA HCS Printing date 10/13/2014 Revised On 10/13/2014 Trade name: GREEN REBAR EPOXY (Contd. of page 3) 39.6.0 110-19-0 isobutyl acetate Oral LD50 4763 mg/kg (rbt) 64-17-5 ethyl alcohol Oral LD50 7060 mg/kg (rat) Inhalative LC50/4 h 20000 mg/l (rat) 108-65-6 PM acetate Oral LD50 8500 mg/kg (rat) Inhalative LC50/4 h 35.7 mg/l (rat) 13463-67-7 titanium dioxide Oral LD50 >20000 mg/kg (rat) Dermal LD50 >10000 mg/kg (rbt) Inhalative LC50/4 h >6.82 mg/l (rat) 100-41-4 ethyl benzene Oral LD50 3500 mg/kg (rat) Dermal LD50 17800 mg/kg (rbt) Information on toxicological effects: No data available. Sensitization: No sensitizing effects known. Carcinogenic categories IARC (International Agency for Research on Cancer) 1330-20-7 xylene (mix) 3 64-17-5 ethyl alcohol 1 13463-67-7 titanium dioxide 2B 100-41-4 ethyl benzene 2B NTP (National Toxicology Program) None of the ingredients is listed. OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. 12 Ecological information Aquatic toxicity: Hazardous for water, do not empty into drains. Persistence and degradability: The product is degradable after prolonged exposure to natural weathering processes. Bioaccumulative potential: No further relevant information available. Mobility in soil: No further relevant information available. Other adverse effects: No further relevant information available. 13 Disposal considerations Dispose of in accordance with local, state, and federal regulations. Do not puncture, incinerate, or compact. Partially empty cans must be disposed of responsibly. Do not heat or cut empty containers with electric or gas torches. Recommendation: Completely empty cans should be recycled. 14 Transport information UN-Number UN1950 DOT Aerosols, flammable ADR 1950 Aerosols Transport hazard class(es): Class 2.1 Marine pollutant: No Special precautions for user: Warning: Gases EMS Number: F-D,S-U Quantity limitations On passenger aircraft/rail: 75 kg On cargo aircraft only: 150 kg ADR Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity IMDG Limited quantities (LQ) 1L Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity Packaging Group: UN "Model Regulation": UN1950, Aerosols, 2.1 15 Regulatory information SARA Section 355 (extremely hazardous substances): None of the ingredients in this product are listed. SARA Section 313 (Specific toxic chemical listings): 1330-20-7 xylene (mix) 100-41-4 ethyl benzene (Contd. on page 5) US4 Page 489 of 1287 Page 489 of 1287 Page 489 of 1287 Page 489 of 1287 ---PAGE BREAK--- Page 5/5 Safety Data Sheet acc. to OSHA HCS Printing date 10/13/2014 Revised On 10/13/2014 Trade name: GREEN REBAR EPOXY (Contd. of page 4) 39.6.0 CPSC: This product complies with 16 CFR 1303 and does not contain more than 90 ppm of lead. California Proposition 65 chemicals known to cause cancer: 13463-67-7 titanium dioxide 100-41-4 ethyl benzene 108-10-1 methyl isobutyl ketone California Proposition 65 chemicals known to cause developmental toxicity: 67-56-1 Methanol Canadian WHMIS: D2A EPA: 67-64-1 Acetone I 1330-20-7 xylene (mix) I 110-19-0 isobutyl acetate D 100-41-4 ethyl benzene D 16 Other information Contact: Regulatory Affairs US4 Page 490 of 1287 Page 490 of 1287 Page 490 of 1287 Page 490 of 1287 ---PAGE BREAK--- Revision Date: 04-May-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: GS RESTROOM CLEANER Product Number: 3503 , 3533 Recommended Use: Disinfectant Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification Serious Eye Damage/Eye Irritation: Category 2A GHS Label Elements Signal Word: Warning Hazard Statements: Causes serious eye irritation Precautionary Statements: Prevention: Wash hands and any exposed skin thoroughly after handling. Wear eye / face protection Response: -Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Not Applicable Disposal: Not Applicable Hazards Not Otherwise Classified: Not Applicable Other Information: • May be harmful if swallowed. • May cause skin irritation. • Inhalation of vapors or mist may cause respiratory irritation. • Keep out of reach of children. Page 1 / 5 0.30298% of the mixture consists of ingredient(s) of unknown toxicity. Symbols: Page 491 of 1287 Page 491 of 1287 Page 491 of 1287 Page 491 of 1287 ---PAGE BREAK--- 3503 - GS RESTROOM CLEANER Revision Date: 04-May-2015 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 60-100 citric acid 77-92-9 5-10 alcohol ethoxylate 68439-46-3 1-5 xanthan gum 11138-66-2 0.1-1 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Product does not support combustion, Use extinguishing agent suitable for type of surrounding fire Specific Hazards Arising from the Chemical: Dried product is capable of burning. Combustion products are toxic. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Cool fire-exposed containers with water spray. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 7. HANDLING AND STORAGE Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Storage Conditions: Keep containers closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep from freezing. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: None established. Engineering Controls: Page 2 / 5 Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Personal Protective Equipment Eye/Face Protection: Wear splash goggles. Page 492 of 1287 Page 492 of 1287 Page 492 of 1287 Page 492 of 1287 ---PAGE BREAK--- 3503 - GS RESTROOM CLEANER Revision Date: 04-May-2015 Skin and Body Protection: Not required with expected use. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Heat, flames and sparks. Incompatible Materials: Strong oxidizing agents. Strong acids. Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Pain, redness, swelling of the conjunctiva and blurred vision. -Skin Contact: Drying of the skin. -Inhalation: Nasal discomfort and coughing. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 29382 mg/kg Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Liquid Color: Clear Odor: Bland pH: 1.5-2.5 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 100 °C / 212 °F Flash Point: > 100 °C / > 212 °F Evaporation Rate: < 1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 1.03 Solubility(ies): Soluble in water Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 3 / 5 Decomposition Temperature: No information available. Viscosity: No information available. Page 493 of 1287 Page 493 of 1287 Page 493 of 1287 Page 493 of 1287 ---PAGE BREAK--- 3503 - GS RESTROOM CLEANER Revision Date: 04-May-2015 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available citric acid 77-92-9 = 3000 mg/kg ( Rat ) Not Available Not Available alcohol ethoxylate 68439-46-3 = 1378 mg/kg ( Rat ) > 2 g/kg ( Rabbit ) Not Available Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Microorganisms Crustacea citric acid 77-92-9 Not Available 1516: 96 h Lepomis macrochirus mg/L LC50 static Not Available 120: 72 h Daphnia magna mg/L EC50 Persistence and Degradability: No information available. Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT: Not Regulated Proper Shipping Name: Non Hazardous Product Special Provisions: Shipping descriptions may vary based on mode of transport, quantities, package size, and/or origin and destination. Check with a trained hazardous materials transportation expert for information specific to your situation. 15. REGULATORY INFORMATION TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product does not contain listed substances above the "de minimus" level SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: No Reactive Hazard: No California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 acetaldehyde - 75-07-0 Carcinogen WARNING: This product contains a chemical known to the State of California to cause cancer. Page 4 / 5 EPA Pesticide Registration Number: 5741-25 Page 494 of 1287 Page 494 of 1287 Page 494 of 1287 Page 494 of 1287 ---PAGE BREAK--- 3503 - GS RESTROOM CLEANER Revision Date: 04-May-2015 EPA Statement: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: EPA Pesticide Label: Caution. Causes moderate eye irritation. May be harmful if swallowed. Avoid contact with eyes, skin or clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, or using the toilet. 16. OTHER INFORMATION Revision Date: 04-May-2015 Reasons for Revision: No information available. Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 1 Flammability: 0 Instability: 0 Special: N/A HMIS Page 5 / 5 Health Hazards: 1 Flammability: 0 Physical Hazards: 0 Page 495 of 1287 Page 495 of 1287 Page 495 of 1287 Page 495 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET GS Window Cleaner Concentrate Date of issue/Date of revision : 09/23/2014 Date of previous issue : 04/01/2014 Version : 1 1/9 Section 1. Identification GHS product identifier : GS Window Cleaner Concentrate Other means of identification : ST-720, ST-840, ST-840E, ST-841, ST-1370 WL35 Product type : Liquid. Relevant identified uses of the substance or mixture and uses advised against Product use : Cleaner for windows, mirrors, and stainless steel surfaces. Area of application : Industrial applications, Professional applications. Product dilution information : 2 oz. (59.14 ml) per 32 ounces (1 liter) of cold water Supplier/Manufacturer : STEARNS PACKAGING CORPORATION 4200 Sycamore Avenue (53714) PO Box 3216 Madison, WI 53704-0216 Telephone no.: [PHONE REDACTED] Fax no.: [PHONE REDACTED] Website: e-mail address of person responsible for this SDS : Emergency telephone number (with hours of operation) : CHEM-TEL : [PHONE REDACTED] Section 2. Hazards identification Product as SOLD Product AT USE DILUTION Physical hazards : Not classified. Not classified. Health hazards : EYE IRRITATION - Category 2B Not classified. Environmental hazards : Not classified. Not classified. OSHA defined hazards : Not classified. Not classified. Label elements Hazard symbol : None Signal word : Warning None Hazard statements : Causes eye irritation. The mixture does not meet the criteria for classification. Precautionary statements General : Keep out of the reach of children. Keep out of the reach of children. Prevention : Wash hands thoroughly after handling. Observe good industrial hygiene practices. Response : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : No storage precautions necessary. No storage precautions necessary. Disposal : Not applicable. Dispose of solution down the drain to municipal sewer. Page 496 of 1287 Page 496 of 1287 Page 496 of 1287 Page 496 of 1287 ---PAGE BREAK--- GS Window Cleaner Concentrate Date of issue/Date of revision : 09/23/2014 Date of previous issue : 04/01/2014 Version : 1 2/9 Section 2. Hazards identification Hazards not otherwise classified : None Not applicable. Supplemental information : Not applicable. Not applicable. Section 3. Composition/information on ingredients Substance/mixture : Mixture Other means of identification : ST-720, ST-840, ST-840E, ST-841, ST-1370 CAS number/other identifiers CAS number : Not applicable. Product code : Not available. Ingredient name Other names % CAS number Videt EGM Not available. 10 - 30 - Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section. Section 4. First aid measures Product as SOLD Product AT USE DILUTION Inhalation : If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a physician if develop or persist. No special measures required. Treat Skin contact : If irritation occurs, flush exposed area with water. Get medical attention if irritation develops and persists. No known effect after skin contact. Eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. No known effect after eye contact. Rinse with water for a few minutes. If irritation persists, get medical attention. Ingestion : Rinse mouth. DO NOT INDUCE VOMITING. If ingestion of a large amount does occur, call a poison control center immediately. Get medical attention if occur. Most important acute and delayed : Direct contact with eyes may cause temporary irritation. No known effects. Indication of immediate medical attention and special treatment needed : Treat Treat General information : Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. No special measures required. Page 497 of 1287 Page 497 of 1287 Page 497 of 1287 Page 497 of 1287 ---PAGE BREAK--- GS Window Cleaner Concentrate Date of issue/Date of revision : 09/23/2014 Date of previous issue : 04/01/2014 Version : 1 3/9 Section 5. Fire-fighting measures Suitable extinguishing media : Treat for surrounding material. Unsuitable extinguishing media : Not available. Specific hazards arising from the chemical : During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters : Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire-fighting equipment/instructions : Move containers from fire area if you can do so without risk. Specific methods : Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards : No unusual fire or explosion hazards noted. Section 6. Accidental release measures Product as SOLD Product AT USE DILUTION Personal precautions, protective equipment and emergency procedures : Keep out of low areas. Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. For personal protection, see section 8 of the SDS. Use personal protective equipment as required. Avoid contact of large amounts of spilled material and run off with soil and surface waterways. Use a water rinse for final clean-up. Methods and materials for containment and cleaning up : This product is miscible in water. Stop the flow of material, if this is without risk. Large Spills: Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Large Spills: Flush area with water. Prevent entry into waterways. Small Spills: Wipe up with absorbent material. Discharge collected material per Section 13 of the SDS. Environmental precautions : Avoid discharge into storm water drains, water courses or onto the ground. Avoid discharge into storm water drains, water courses, or onto the ground. Section 7. Handling and storage Product as SOLD Product AT USE DILUTION Precautions for safe handling : Use care in handling/storage. None required. Conditions for safe storage, including any incompatibilities : Keep out of reach of children. Store in original closed container. Store away from incompatible materials (see Section 10 of the SDS). Keep out of reach of children. Page 498 of 1287 Page 498 of 1287 Page 498 of 1287 Page 498 of 1287 ---PAGE BREAK--- GS Window Cleaner Concentrate Date of issue/Date of revision : 09/23/2014 Date of previous issue : 04/01/2014 Version : 1 4/9 Section 8. Exposure controls/personal protection Product as SOLD Product AT USE DILUTION Occupational exposure limits : No exposure limits noted for ingredient(s). No exposure limits noted for ingredient(s). Biological limit values : No biological exposure limits noted for the ingredient(s). No biological exposure limits noted for the ingredient(s). Appropriate engineering controls : Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Good general ventilation should be used. Individual protection measures, such as personal protective equipment Product as SOLD Product AT USE DILUTION Eye/face protection : Safety glasses if eye contact is possible. Wear protective eyewear if contact is possible. Skin protection Hand protection : Not normally needed. No protective equipment is needed under normal conditions. Other : As required by employer code. No protective equipment is needed under normal conditions. Respiratory protection : No personal respiratory protective equipment normally required. No protective equipment is needed under normal conditions. Thermal hazards : Wear appropriate thermal protective clothing, when necessary. No protective equipment is needed under normal conditions. General hygiene considerations : Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Section 9. Physical and chemical properties Product as SOLD Product AT USE DILUTION Appearance : Clear Clear Physical state : Liquid. Liquid. Form : Liquid. Liquid. Color : Dark blue. Blue. Odor : Odorless.(No fragrance added) Odorless.(No fragrance added) Odor threshold : Not available. Not available. pH : 10.5-11.5 9.5 - 10.5 Melting point : Not available. Not available. Initial boiling point and boiling range : 212 °F (100 212 °F (100 Pour point : Not available. Not available. Page 499 of 1287 Page 499 of 1287 Page 499 of 1287 Page 499 of 1287 ---PAGE BREAK--- GS Window Cleaner Concentrate Date of issue/Date of revision : 09/23/2014 Date of previous issue : 04/01/2014 Version : 1 5/9 Section 9. Physical and chemical properties Specific gravity : Not available. Not available. Flash point : Closed cup: >93.333°C (>200°F) [Pensky-Martens.] Closed cup: >93.333°C (>200°F) [Pensky-Martens.] Evaporation rate : Not available. Not available. Flammability (solid, gas) : Not applicable. Not applicable. Lower and upper explosive (flammable) limits : Not available. Not available. Vapor pressure : <0.013 kPa (<0.1 mm Hg) <0.013 kPa (<0.1 mm Hg) Vapor density : Not available. Not available. Relative density : 1.02 1.00 Solubility : Complete Complete Auto-ignition temperature : Not available. Not available. Decomposition temperature : Not available. Not available. Viscosity : <100 mPa·s (<100 cP) <100 mPa·s (<100 cP) Other information Bulk density : 8.51 lbs/gallon 8.35 lbs/gallon Section 10. Stability and reactivity Product as SOLD Reactivity : None known. Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. Chemical stability : Material is stable under normal conditions. Conditions to avoid : Do not mix with other chemicals. Keep from freezing. Incompatible materials : Strong oxidizing agents. Hazardous decomposition products : No hazardous decomposition products are known. Section 11. Toxicological information Information on the likely routes of exposure Product as SOLD Product AT USE DILUTION Ingestion : Expected to be a low ingestion hazard. Expected to be a low ingestion hazard. Inhalation : No adverse effects due to inhalation are expected. No adverse effects due to inhalation are expected. Skin contact : No adverse effects due to skin contact are expected. No adverse effects due to skin contact are expected. Eye contact : Direct contact with eyes may cause temporary irritation. Direct contact with eyes may cause temporary irritation. related to the physical, chemical and toxicological characteristics : Direct contact with eyes may cause temporary irritation. Direct contact with eyes may cause temporary irritation. Information on toxicological effects Direct contact with eyes may cause temporary irritation. Acute toxicity : Calculated Oral LD50 29,411 mg/kg Non-toxic at use-dilution. Skin corrosion/irritation : Prolonged skin contact may cause temporary irritation. No known significant effects or critical hazards. Exposure minutes : Not available. Not available. Erythema value : Not available. Not available. Oedema value : Not available. Not available. Page 500 of 1287 Page 500 of 1287 Page 500 of 1287 Page 500 of 1287 ---PAGE BREAK--- GS Window Cleaner Concentrate Date of issue/Date of revision : 09/23/2014 Date of previous issue : 04/01/2014 Version : 1 6/9 Section 11. Toxicological information Product as SOLD Product AT USE DILUTION Serious eye damage/eye irritation : Direct contact with eyes may cause temporary irritation. No known significant effects or critical hazards. Corneal opacity value : Not available. Not available. Iris lesion value : Not available. Not available. Conjunctival reddening value : Not available. Not available. Conjunctival oedema value : Not available. Not available. Recover days : Not available. Not available. Respiratory or skin sensitization : Direct contact with eyes may cause temporary irritation. No known significant effects or critical hazards. Respiratory sensitization : Not available. Not available. Skin sensitization : This product is not expected to cause skin sensitization. No known significant effects or critical hazards. Germ cell mutagenicity : No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. No known significant effects or critical hazards. Carcinogenicity : This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. No known significant effects or critical hazards. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) : Not listed. Reproductive toxicity : This product is not expected to cause reproductive or developmental effects. This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity -single exposure : Not classified. Not classified. Specific target organ toxicity -repeated exposure : Not classified. Not classified. Aspiration hazard : Not available. Not available. Chronic effects : Not available. Not available. Further information : This product has no known adverse effect on human health. This product has no known adverse effect on human health. Section 12. Ecological information Ecotoxicity : The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Persistence and degradability : No data is available on the degradability of this product. Bioaccumulative potential : No data available. Mobility in soil : No data available. Mobility in general : Not available. Other adverse effects : No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Page 501 of 1287 Page 501 of 1287 Page 501 of 1287 Page 501 of 1287 ---PAGE BREAK--- GS Window Cleaner Concentrate Date of issue/Date of revision : 09/23/2014 Date of previous issue : 04/01/2014 Version : 1 7/9 Section 13. Disposal considerations Product as SOLD Product AT USE DILUTION Disposal instructions : Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Diluted product can be flushed to sanitary sewer. Discard empty container in trash. Local disposal regulations : Dispose in accordance with all applicable regulations. Hazardous waste code : The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products : Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging : Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Section 14. Transport information Product as SOLD DOT Classification IMDG IATA UN number Not regulated. Not regulated. Not regulated. UN proper shipping name Cleaning Compounds, NOI, liquid - - Transport hazard class(es) - - - Packing group - - - Environmental hazards No. No. No. Additional information - - - Product AT USE DILUTION Not intended for transport Section 15. Regulatory information U.S. Federal regulations Product as SOLD Product AT USE DILUTION TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) : Not regulated. Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) : Not listed. Not listed. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) : Not listed. Not listed. Page 502 of 1287 Page 502 of 1287 Page 502 of 1287 Page 502 of 1287 ---PAGE BREAK--- GS Window Cleaner Concentrate Date of issue/Date of revision : 09/23/2014 Date of previous issue : 04/01/2014 Version : 1 8/9 Section 15. Regulatory information Superfund Amendments and Reauthorization Act of 1986 (SARA) Product as SOLD Product AT USE DILUTION Hazard categories : Immediate Hazard - No Delayed Hazard - No Fire Hazard – No Pressure Hazard - No Reactivity Hazard - No Non-hazardous. SARA 302 Extremely hazardous substance : No Not listed. SARA 311/312 Hazardous chemical : Immediate (acute) health hazard SARA 313 (TRI reporting) : Not regulated. Other federal regulations Product as SOLD Product AT USE DILUTION Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List : Not regulated. Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) : Not regulated. Not regulated. Safe Drinking Water Act (SDWA) : Not regulated. Not regulated. Food and Drug Administration (FDA) : Not regulated. Not regulated. US State regulations US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance : Not listed. Not listed. US. Massachusetts RTK - Substance List : Not regulated. Not regulated. US. RTK - Hazardous Substances : Not regulated. Not regulated. US. Rhode Island RTK : Not regulated. Not regulated. Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s) Page 503 of 1287 Page 503 of 1287 Page 503 of 1287 Page 503 of 1287 ---PAGE BREAK--- GS Window Cleaner Concentrate Date of issue/Date of revision : 09/23/2014 Date of previous issue : 04/01/2014 Version : 1 9/9 Section 16. Other information Product as SOLD Product AT USE DILUTION Hazardous Material Information System Hazardous Material Information System Health 1 Flammability 0 Physical hazards 0 Health 0 Flammability 0 Physical hazards 0 National Fire Protection Association Health Flammability Instability/Reactivity Special Health Flammability Instability/Reactivity Special MSDS File Name : WL35 GS Window Cleaner SDS NSF Certified : A7, C1; 7/8/05; #137216 Green Seal Certified : GS-37 2009 Disclaimer Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. Date of issue/Date of revision : 09/23/2014 Date of previous issue : No previous validation Prepared by : Dell Tech Laboratories, Ltd. Phone: (519) 858-5021 1 0 0 0 0 0 Page 504 of 1287 Page 504 of 1287 Page 504 of 1287 Page 504 of 1287 ---PAGE BREAK---  


 

        



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Page 510 of 1287 Page 510 of 1287 Page 510 of 1287 Page 510 of 1287 ---PAGE BREAK---  Page 511 of 1287 Page 511 of 1287 Page 511 of 1287 Page 511 of 1287 ---PAGE BREAK--- Page 512 of 1287 Page 512 of 1287 Page 512 of 1287 Page 512 of 1287 ---PAGE BREAK--- Page 513 of 1287 Page 513 of 1287 Page 513 of 1287 Page 513 of 1287 ---PAGE BREAK--- Safety Data Sheet According to OSHA HCS 2012 (29 CFR 1910.1200) SECTION 1: Identification Product Identifier: Injex® Pro 2-Cycle Motor Oil Other means of identification: Phillips 66 Injex® Pro 2-Cycle Motor Oil SDS Number: 717910 Relevant identified uses: 2-Cycle Engine Oil Uses Advised Against: All others 24 Hour Emergency Phone Number: CHEMTREC [PHONE REDACTED] (24 Hours) CANUTEC [PHONE REDACTED] CHEMTREC Mexico 01-[PHONE REDACTED] SECTION 2: Hazard identification SECTION 4: First aid measures Eye Contact: If irritation or redness develops from exposure, flush eyes with clean water. If persist, seek medical attention. Manufacturer/Supplier: Phillips 66 Lubricants P.O. Box 4428 Houston, TX 77210 SDS Information: Phone: [PHONE REDACTED] Email: [EMAIL REDACTED] URL: www.Phillips66.com Customer Service: U.S.: [PHONE REDACTED] or International: 1-[PHONE REDACTED] Technical Information: 1-[PHONE REDACTED] Classified Hazards Other Hazards H315 Skin corrosion/irritation Category 2 H336 Specific target organ toxicity (single exposure) Category 3 H411 Hazardous to the aquatic environment, chronic toxicity Category 2 None Known Label Elements _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ SECTION 3: Composition/information on ingredients Chemical Name CASRN Concentration¹ Distillates, petroleum, solvent-refined heavy paraffinic 64741-88-4 >35 Petroleum distillates, hydrotreated light 64742-47-8 >25 Non-Hazardous Materials VARIOUS >30 ¹ All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. WARNING Causes skin irritation May cause drowsiness or dizziness Toxic to aquatic life with long lasting effects 717910 - Injex® Pro 2-Cycle Motor Oil Page 1/8 Date of Issue: 09-Jan-2015 Status: FINAL Avoid breathing dust/fume/gas/mist/vapours/spray; Wash skin thoroughly after handling; Use only outdoors or in a well-ventilated area; Avoid release to the environment; Wear protective gloves/protective clothing and eye/face protection; IF ON SKIN: Wash with plenty of soap and water; If skin irritation occurs: Get medical advice/attention; IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing; Call a POISON CENTER or doctor/physician if you feel unwell; Take off contaminated clothing and wash before reuse; Collect spillage; Store in a well-ventilated place. Keep container closed; Dispose of contents/ container to an approved waste disposal plant Page 514 of 1287 Page 514 of 1287 Page 514 of 1287 Page 514 of 1287 ---PAGE BREAK--- _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 717910 - Injex® Pro 2-Cycle Motor Oil Page 2/8 Date of Issue: 09-Jan-2015 Status: FINAL Skin Contact: Remove contaminated shoes and clothing, and flush affected area(s) with large amounts of water. If skin surface is damaged, apply a clean dressing and seek medical attention. If skin surface is not damaged, cleanse affected area(s) thoroughly by washing with mild soap and water or a waterless hand cleaner. If irritation or redness develops, seek medical attention. Wash contaminated clothing before reuse. Inhalation (Breathing): First aid is not normally required. If breathing difficulties develop, move victim away from source of exposure and into fresh air in a position comfortable for breathing. Seek immediate medical attention. Ingestion (Swallowing): First aid is not normally required; however, if swallowed and develop, seek medical attention. Most important and effects, both acute and delayed: While significant vapor concentrations are not likely, high concentrations can cause minor respiratory irritation, headache, drowsiness, dizziness, loss of coordination, disorientation and fatigue. Ingestion can cause irritation of the digestive tract, nausea, diarrhea, and vomiting, Dry skin and possible irritation with repeated or prolonged exposure. Notes to Physician: Acute aspirations of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. SECTION 5: Firefighting measures NFPA 704 Hazard Class Extinguishing Media: Dry chemical, carbon dioxide, foam, or water spray is recommended. Water or foam may cause frothing of materials heated above 212°F / 100°C. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam. Specific hazards arising from the chemical Unusual Fire & Explosion Hazards: This material may burn, but will not ignite readily. If container is not properly cooled, it can rupture in the heat of a fire. Hazardous Combustion Products: Combustion may yield smoke, carbon monoxide, and other products of incomplete combustion. Oxides of sulfur, nitrogen or phosphorus may also be formed. Special protective actions for firefighters: For fires beyond the initial stage, emergency responders in the immediate hazard area should wear protective clothing. When the potential chemical hazard is unknown, in enclosed or confined spaces, a self contained breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions warrant (see Section Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Cool equipment exposed to fire with water, if it can be done safely. Avoid spreading burning liquid with water used for cooling purposes. See Section 9 for Flammable Properties including Flash Point and Flammable (Explosive) Limits SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures: This material may burn, but will not ignite readily. Keep all sources of ignition away from spill/release. Stay upwind and away from spill/release. Avoid direct contact with material. For large spillages, notify persons down wind of the spill/release, isolate immediate hazard area and keep unauthorized personnel out. Wear appropriate protective equipment, including respiratory protection, as conditions warrant (see Section See Sections 2 and 7 for additional information on hazards and precautionary measures. Health: 1 Flammability: 1 Instability: 0 0 (Minimal) 1 (Slight) 2 (Moderate) 3 (Serious) 4 (Severe) Page 515 of 1287 Page 515 of 1287 Page 515 of 1287 Page 515 of 1287 ---PAGE BREAK--- _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 717910 - Injex® Pro 2-Cycle Motor Oil Page 3/8 Date of Issue: 09-Jan-2015 Status: FINAL Environmental Precautions: Stop and contain spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems, and natural waterways. Use water sparingly to minimize environmental contamination and reduce disposal requirements. If spill occurs on water notify appropriate authorities and advise shipping of any hazard. Spills into or upon navigable waters, the contiguous zone, or adjoining shorelines that cause a sheen or discoloration on the surface of the water, may require notification of the National Response Center (phone number [PHONE REDACTED]). Methods and material for containment and cleaning up: Notify relevant authorities in accordance with all applicable regulations. Immediate cleanup of any spill is recommended. Dike far ahead of spill for later recovery or disposal. Absorb spill with inert material such as sand or vermiculite, and place in suitable container for disposal. If spilled on water remove with appropriate methods (e.g. skimming, booms or absorbents). In case of soil contamination, remove contaminated soil for remediation or disposal, in accordance with local regulations. Recommended measures are based on the most likely spillage scenarios for this material; however local conditions and regulations may influence or limit the choice of appropriate actions to be taken. See Section 13 for information on appropriate disposal. SECTION 7: Handling and storage Precautions for safe handling: Keep away from flames and hot surfaces. Wash thoroughly after handling. Wear protective gloves/clothing and eye/face protection. Use good personal hygiene practices and wear appropriate personal protective equipment (see section Spills will produce very slippery surfaces. Do not enter confined spaces such as tanks or pits without following proper entry procedures such as ASTM D-4276 and 29CFR 1910.146. Used motor oils have been shown to cause skin cancer in mice after repeated application to the skin without washing. Brief or intermittent skin contact with used motor oil is not expected to cause harm if the oil is thoroughly removed by washing with soap and water. Do not wear contaminated clothing or shoes. Conditions for safe storage: Keep container(s) closed and properly labeled. Use and store this material in cool, dry, well-ventilated area away from heat and all sources of ignition. Store only in approved containers. Keep away from any incompatible material (see Section 10). Protect container(s) against physical damage. "Empty" containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury or death. "Empty" drums should be completely drained, properly bunged, and shipped to the supplier or a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. Before working on or in tanks which contain or have contained this material, refer to OSHA regulations, ANSI Z49.1, and other references pertaining to cleaning, repairing, welding, or other contemplated operations. SECTION 8: Exposure controls/personal protection Chemical Name ACGIH OSHA Other Distillates, petroleum, solvent-refined heavy paraffinic TWA: 5mg/m3 STEL: 10 mg/m3 as Oil Mist, if Generated TWA: 5mg/m3 as Oil Mist, if Generated Petroleum distillates, hydrotreated light TWA: 200 mg/m3 Skin based on Kerosene 8008-20-6 Based on Stoddard Solvent Note: State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or similar professional, or your local agencies, for further information. Engineering controls: If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure limits, additional engineering controls may be required. Eye/Face Protection: The use of eye protection that meets or exceeds ANSI Z.87.1 is recommended to protect against potential eye contact, irritation, or injury. Depending on conditions of use, a face shield may be necessary. Skin/Hand Protection: The use of gloves impervious to the specific material handled is advised to prevent skin contact. Users should check with manufacturers to confirm the breakthrough performance of their products. Depending on exposure and use conditions, additional protection may be necessary to prevent skin contact including use of items such as chemical resistant boots, aprons, arm covers, hoods, coveralls, or encapsulated suits. Suggested protective materials: Nitrile Page 516 of 1287 Page 516 of 1287 Page 516 of 1287 Page 516 of 1287 ---PAGE BREAK--- _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 717910 - Injex® Pro 2-Cycle Motor Oil Page 4/8 Date of Issue: 09-Jan-2015 Status: FINAL Respiratory Protection: Where there is potential for airborne exposure above the exposure limit a NIOSH certified air purifying respirator equipped with R or P95 filters may be used. A respiratory protection program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed whenever workplace conditions warrant a respirator's use. Air purifying respirators provide limited protection and cannot be used in atmospheres that exceed the maximum use concentration (as directed by regulation or the manufacturer's instructions), in oxygen deficient (less than 19.5 percent oxygen) situations, or under conditions that are immediately dangerous to life and health (IDLH). Other Protective Equipment: Eye wash and quick-drench shower facilities should be available in the work area. Thoroughly clean shoes and wash contaminated clothing before reuse. Suggestions provided in this section for exposure control and specific types of protective equipment are based on readily available information. Users should consult with the specific manufacturer to confirm the performance of their protective equipment. Specific situations may require consultation with industrial hygiene, safety, or engineering professionals. SECTION 9: Physical and chemical properties Note: Unless otherwise stated, values are determined at 20°C (68°F) and 760 mm Hg (1 atm). Data represent typical values and are not intended to be specifications. SECTION 10: Stability and reactivity Reactivity: Not chemically reactive. Chemical stability: Stable under normal ambient and anticipated conditions of use. Possibility of hazardous reactions: Hazardous reactions not anticipated. Conditions to avoid: Extended exposure to high temperatures can cause decomposition. Avoid all possible sources of ignition. Incompatible materials: Avoid contact with strong oxidizing agents and strong reducing agents. Hazardous decomposition products: Not anticipated under normal conditions of use, During use in engines, contamination of oil with low levels of hazardous fuel combustion by-products may occur. Repeated and prolonged skin contact can cause drying and cracking. SECTION 11: Toxicological information Information on Toxicological Effects of Substance/Mixture Substance / Mixture Appearance: Purple Flash Point: > 199.4 °F / > 93 °C Physical Form: Liquid Test Method: Pensky-Martens Closed Cup (PMCC), ASTM D93, EPA 1010 Odor: Petroleum Initial Boiling Point/Range: No data Odor Threshold: No data Vapor Pressure: <1 mm Hg pH: Not applicable Partition Coefficient (n-octanol/water) (Kow): No data Vapor Density (air=1): >1 Melting/Freezing Point: < -22 °F / < -30 °C Upper Explosive Limits (vol % in air): No data Auto-ignition Temperature: No data Lower Explosive Limits (vol % in air): No data Decomposition Temperature: No data Evaporation Rate (nBuAc=1): No data Specific Gravity (water=1): 0.88 @ 60ºF (15.6ºC) Particle Size: Not applicable Bulk Density: 7.3 lbs/gal Percent Volatile: Negligible Viscosity: 9.7 cSt @ 100°C; 62 cSt @ 40°C Flammability (solid, gas): Not applicable Pour Point: < -22 °F / < -30 °C Solubility in Water: Soluble upon agitation (emusifiable) Acute Toxicity Hazard Additional Information LC50/LD50 Data Inhalation Unlikely to be harmful >5 mg/L (mist, estimated) Dermal Unlikely to be harmful > 2 g/kg (estimated) Oral Unlikely to be harmful > 5 g/kg (estimated) Page 517 of 1287 Page 517 of 1287 Page 517 of 1287 Page 517 of 1287 ---PAGE BREAK--- _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 717910 - Injex® Pro 2-Cycle Motor Oil Page 5/8 Date of Issue: 09-Jan-2015 Status: FINAL Aspiration Hazard: Not expected to be an aspiration hazard. Skin Corrosion/Irritation: Causes skin irritation. Repeated exposure may cause skin dryness or cracking. Serious Eye Damage/Irritation: Causes mild eye irritation. Skin Sensitization: No information available on the mixture, however none of the components have been classified for skin sensitization (or are below the concentration threshold for classification). Respiratory Sensitization: No information available. Specific Target Organ Toxicity (Single Exposure): May cause drowsiness and dizziness. Based on component information Specific Target Organ Toxicity (Repeated Exposure): No information available on the mixture, however none of the components have been classified for target organ toxicity (or are below the concentration threshold for classification). Carcinogenicity: No information available on the mixture, however none of the components have been classified for carcinogenicity (or are below the concentration threshold for classification). Germ Cell Mutagenicity: No information available on the mixture, however none of the components have been classified for germ cell mutagenicity (or are below the concentration threshold for classification). Reproductive Toxicity: No information available on the mixture, however none of the components have been classified for reproductive toxicity (or are below the concentration threshold for classification). Information on Toxicological Effects of Components Distillates, petroleum, solvent-refined heavy paraffinic Carcinogenicity: This oil has been highly refined by a variety of processes to reduce aromatics and improve performance characteristics. It meets the IP-346 criteria of less than 3 percent PAH's and is not considered a carcinogen by the International Agency for Research on Cancer. Petroleum distillates, hydrotreated light Carcinogenicity: Petroleum middle distillates have been shown to cause skin tumors in mice following repeated and prolonged skin contact. Follow-up studies have shown that these tumors are produced through a non-genotoxic mechanism associated with frequent cell damage and repair, and that they are not likely to cause tumors in the absence of prolonged skin irritation. SECTION 12: Ecological information Toxicity: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Persistence and Degradability: The hydrocarbons in this material are not readily biodegradable but are regarded as inherently biodegradable since their hydrocarbon components can be degraded by microorganisms. Bioaccumulative Potential: Hydrocarbon constituents of kerosine show measured or predicted Log Kow values ranging from 3 to 6 and above and therefore would be regarded as having the potential to bioaccumulate. In practice, metabolic processes may reduce bioconcentration. Mobility in Soil: On release to water, hydrocarbons will float on the surface and since they are sparingly soluble, the only significant loss is volatilization to air. It is possible that some of the higher molecular weight hydrocarbons will be adsorbed on sediment. Biodegradation in water is a minor loss process. In air, these hydrocarbons are photodegraded by reaction with hydroxyl radicals with half lives varying from 0.1 to 0.7 days. Other adverse effects: None anticipated. GHS Classification: H411 Hazardous to the aquatic environment, chronic toxicity Category 2 Toxic to aquatic life with long lasting effects. Page 518 of 1287 Page 518 of 1287 Page 518 of 1287 Page 518 of 1287 ---PAGE BREAK--- _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 717910 - Injex® Pro 2-Cycle Motor Oil Page 6/8 Date of Issue: 09-Jan-2015 Status: FINAL SECTION 13: Disposal considerations The generator of a waste is always responsible for making proper hazardous waste determinations and needs to consider state and local requirements in addition to federal regulations. This material, if discarded as produced, would not be a federally regulated RCRA "listed" hazardous waste and is not believed to exhibit characteristics of hazardous waste. See Sections 7 and 8 for information on handling, storage and personal protection and Section 9 for physical/chemical properties. It is possible that the material as produced contains constituents which are not required to be listed in the SDS but could affect the hazardous waste determination. Additionally, use which results in chemical or physical change of this material could subject it to regulation as a hazardous waste.This material under most intended uses would become "Used Oil" due to contamination by physical or chemical impurities. Whenever possible, Recycle used oil in accordance with applicable federal and state or local regulations. Container contents should be completely used and containers should be emptied prior to discard. SECTION 14: Transport information U.S. Department of Transportation (DOT) Shipping Description: Non-Bulk shipments by land are not regulated. ; Not regulated Note: If shipped by land in a packaging having a capacity of 3,500 gallons or more, the provisions of 49 CFR, Part 130 apply. (Contains oil) International Maritime Dangerous Goods (IMDG) Shipping Description: UN3082, Environmentally hazardous substance, liquid, n.o.s., ( Petroleum distillates 9, III Non-Bulk Package Marking: UN3082 , Environmentally hazardous substance, liquid, n.o.s., (Petroleum distillates) Labels: Class 9 Placards/Marking (Bulk): Class 9 / 3082 Packaging - Non-Bulk: P001, LP01 EMS: F-A, S-F Note: U.S. DOT compliance requirements may apply. See 49 CFR 171.22, 23 & 25. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable International Civil Aviation Org. / International Air Transport Assoc. (ICAO/IATA) UN/ID UN3082 Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s. (Petroleum distillates) Hazard Class/Division: 9 Packing Group: III Non-Bulk Package Marking: Environmentally hazardous substance, liquid, n.o.s. (Petroleum distillates), UN3082, [Environmentally Hazardous Substance Mark] (if > 5L container) Labels: Class 9 ERG Code: 9L Note: Note: Environmentally Hazardous Substance Mark not required if container is < 5 L or 5 kg U.S. DOT compliance requirements may apply. See 49 CFR 171.22, 23 & 24. SECTION 15: Regulatory information CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs (in pounds): This material does not contain any chemicals subject to the reporting requirements of SARA 302 and 40 CFR 372. CERCLA/SARA - Section 311/312 (Title III Hazard Categories) Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: No Pressure Hazard: No Reactive Hazard: No LTD. QTY Passenger Aircraft Cargo Aircraft Only Packaging Instruction Y964 964 964 Max. Net Qty. Per Package: 30 kg 450 L 450 L Page 519 of 1287 Page 519 of 1287 Page 519 of 1287 Page 519 of 1287 ---PAGE BREAK--- _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 717910 - Injex® Pro 2-Cycle Motor Oil Page 7/8 Date of Issue: 09-Jan-2015 Status: FINAL CERCLA/SARA - Section 313 and 40 CFR 372: This material does not contain any chemicals subject to the reporting requirements of SARA 313 and 40 CFR 372. EPA (CERCLA) Reportable Quantity (in pounds): This material does not contain any chemicals with CERCLA Reportable Quantities. California Proposition 65: This material does not contain any chemicals which are known to the State of California to cause cancer, birth defects or other reproductive harm at concentrations that trigger the warning requirements of California Proposition 65. International Hazard Classification Canada: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all the information required by the Regulations. WHMIS Hazard Class: D2B - Toxic materials National Chemical Inventories All components are either listed on the US TSCA Inventory, or are not regulated under TSCA. All components are either on the DSL, or are exempt from DSL listing requirements. U.S. Export Control Classification Number: EAR99 SECTION 16: Other information Precautionary Statement(s): P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P264 - Wash skin thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P332 + P313 - If skin irritation occurs: Get medical advice/attention P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P312 - Call a POISON CENTER or doctor if you feel unwell P362 - Take off contaminated clothing and wash before reuse P391 - Collect spillage P403 + P233 - Store in a well-ventilated place. Keep container closed P501 - Dispose of contents/ container to an approved waste disposal plant Guide to Abbreviations: ACGIH = American Conference of Governmental Industrial Hygienists; CASRN = Chemical Abstracts Service Registry Number; CEILING = Ceiling Limit (15 minutes); CERCLA = The Comprehensive Environmental Response, Compensation, and Liability Act; EPA = Environmental Protection Agency; GHS = Globally Harmonized System; IARC = International Agency for Research on Cancer; INSHT = National Institute for Health and Safety at Work; IOPC = International Oil Pollution Compensation; LEL = Lower Explosive Limit; NE = Not Established; NFPA = National Fire Protection Association; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration; PEL = Permissible Exposure Limit (OSHA); SARA = Superfund Amendments and Reauthorization Act; STEL = Short Term Exposure Limit (15 minutes); TLV = Threshold Limit Value (ACGIH); TWA = Time Weighted Average (8 hours); UEL = Upper Explosive Limit; WHMIS = Worker Hazardous Materials Information System (Canada) Revised Sections or Basis for Revision: Composition (Section Exposure limits (Section Toxicological (Section 11) Date of Issue: Previous Issue Date: SDS Number: Status: 09-Jan-2015 01-May-2013 717910 FINAL Page 520 of 1287 Page 520 of 1287 Page 520 of 1287 Page 520 of 1287 ---PAGE BREAK--- _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 717910 - Injex® Pro 2-Cycle Motor Oil Page 8/8 Date of Issue: 09-Jan-2015 Status: FINAL Disclaimer of Expressed and implied Warranties: The information presented in this Safety Data Sheet is based on data believed to be accurate as of the date this Safety Data Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. No responsibility is assumed for any damage or injury resulting from abnormal use or from any failure to adhere to recommended practices. The information provided above, and the product, are furnished on the condition that the person receiving them shall make their own determination as to the suitability of the product for their particular purpose and on the condition that they assume the risk of their use. In addition, no authorization is given nor implied to practice any patented invention without a license. Page 521 of 1287 Page 521 of 1287 Page 521 of 1287 Page 521 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Insect Repellent Product identifier Other means of identification 14011 Product code EPA: 51147-13-55809 Registration number Insect repellent Recommended use None known. Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufactured or sold by: Company name CRC Industries, Inc. Address 885 Louis Dr. Warminster, PA 18974 US Telephone General Information [PHONE REDACTED] Technical Assistance [PHONE REDACTED] Customer Service [PHONE REDACTED] 24-Hour Emergency [PHONE REDACTED] (US) (CHEMTREC) [PHONE REDACTED] (International) Website www.crcindustries.com 2. Hazard(s) identification Category 1 Flammable aerosols Physical hazards Liquefied gas Gases under pressure Category 4 Acute toxicity, oral Health hazards Category 4 Acute toxicity, dermal Category 2 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Sensitization, skin Category 3 narcotic effects Specific target organ toxicity, single exposure Category 2 Hazardous to the aquatic environment, acute hazard Environmental hazards Category 3 Hazardous to the aquatic environment, long-term hazard Not classified. OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause drowsiness or dizziness. Toxic to aquatic life. Harmful to aquatic life with long lasting effects. 1 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 522 of 1287 Page 522 of 1287 Page 522 of 1287 Page 522 of 1287 ---PAGE BREAK--- Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not apply while equipment is energized. Pressurized container: Do not pierce or burn, even after use. Extinguish all flames, pilot lights and heaters. Vapors will accumulate readily and may ignite. Use only with adequate ventilation; maintain ventilation during use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any listed on this label, increase ventilation or leave the area. Avoid breathing mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves/protective clothing. Wear eye/face protection. Avoid release to the environment. Response If swallowed: Call a poison center/doctor if you feel unwell. Rinse mouth. If on skin: Wash with plenty of water. If skin irritation or rash occurs: Get medical attention. Take off contaminated clothing and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Exposure to high temperature may cause can to burst. Disposal Dispose of contents/container in accordance with local/regional/national regulations. Hazard(s) not otherwise classified (HNOC) Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. Supplemental information 32.11% of the mixture consists of component(s) of unknown acute oral toxicity. 32.11% of the mixture consists of component(s) of unknown acute dermal toxicity. 72.39% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment. 3. Composition/information on ingredients Mixtures CAS number % Common name and synonyms Chemical name 67-63-0 Isopropyl alcohol 30 - 40 134-62-3 N,N-Diethyl-m-toluamide (DEET) 25.1 68476-86-8 Liquefied Petroleum Gas 20 - 30 113-48-4 Dicarboximide 5 - 10 136-45-8 Dipropyl isocinchomeronate 2.5 67-64-1 Acetone 1 - 3 57-55-6 Propylene glycol 1 - 3 Specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Inhalation Remove contaminated clothing immediately and wash skin with soap and water. In case of eczema or other skin disorders: Seek medical attention and take along these instructions. Wash contaminated clothing before reuse. Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Eye contact Rinse mouth. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Get medical advice/attention if you feel unwell. Ingestion May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash. Most important acute and delayed Provide general supportive measures and treat Keep victim warm. Keep victim under observation. may be delayed. Indication of immediate medical attention and special treatment needed Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse. General information 2 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 523 of 1287 Page 523 of 1287 Page 523 of 1287 Page 523 of 1287 ---PAGE BREAK--- 5. Fire-fighting measures Alcohol resistant foam. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Unsuitable extinguishing media Contents under pressure. Pressurized container may rupture when exposed to heat or flame. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture when exposed to heat or flame. General fire hazards 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Remove all possible sources of ignition in the surrounding area. Many vapors are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. The product is immiscible with water and will spread on the water surface. Stop the flow of material, if this is without risk. Prevent product from entering drains. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. Use appropriate containment to avoid environmental contamination. Environmental precautions 7. Handling and storage Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Do not taste or swallow. When using, do not eat, drink or smoke. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Avoid release to the environment. Wash contaminated clothing before reuse. For product usage instructions, please see the product label. Precautions for safe handling Level 3 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Avoid spark promoters. These alone may be insufficient to remove static electricity. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 3 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 524 of 1287 Page 524 of 1287 Page 524 of 1287 Page 524 of 1287 ---PAGE BREAK--- 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Type PEL 2400 mg/m3 Acetone (CAS 67-64-1) 1000 ppm PEL 980 mg/m3 Isopropyl alcohol (CAS 67-63-0) 400 ppm US. ACGIH Threshold Limit Values Value Components Type STEL 750 ppm Acetone (CAS 67-64-1) TWA 500 ppm STEL 400 ppm Isopropyl alcohol (CAS 67-63-0) TWA 200 ppm US. NIOSH: Pocket Guide to Chemical Hazards Value Components Type TWA 590 mg/m3 Acetone (CAS 67-64-1) 250 ppm STEL 1225 mg/m3 Isopropyl alcohol (CAS 67-63-0) 500 ppm TWA 980 mg/m3 400 ppm US. AIHA Workplace Environmental Exposure Level (WEEL) Guides Value Components Form Type TWA 10 mg/m3 Aerosol. Propylene glycol (CAS 57-55-6) Biological limit values ACGIH Biological Exposure Indices Value Components Determinant Specimen Sampling Time 50 mg/l Acetone Urine * Acetone (CAS 67-64-1) 40 mg/l Acetone Urine * Isopropyl alcohol (CAS 67-63-0) * - For sampling details, please see the source document. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Appropriate engineering controls Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles). Eye/face protection Skin protection Wear protective gloves such as: Nitrile. Viton®. Hand protection Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended. Other If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels. Respiratory protection Wear appropriate thermal protective clothing, when necessary. Thermal hazards When using do not smoke. Keep away from food and drink. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace. General hygiene considerations 4 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 525 of 1287 Page 525 of 1287 Page 525 of 1287 Page 525 of 1287 ---PAGE BREAK--- 9. Physical and chemical properties Appearance Liquid. Physical state Aerosol. Form Clear. Colorless. Color Mild. Alcoholic. Odor Odor threshold Not available. pH Not available. Melting point/freezing point -138.5 °F (-94.7 estimated Initial boiling point and boiling range 132.9 °F (56.1 estimated Flash point 75 °F (23.9 Tag Closed Cup Evaporation rate Moderate. Not available. Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower 2 % estimated Flammability limit - upper 12.8 % estimated Vapor pressure 1234.3 hPa estimated Vapor density > 1 (air = 1) Relative density 0.8 estimated Solubility (water) Immiscible. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 700 °F (371.1 estimated Decomposition temperature Not available. Viscosity (kinematic) Not available. Percent volatile 67.3 % estimated 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Reactivity Material is stable under normal conditions. Chemical stability No dangerous reaction known under conditions of normal use. Possibility of hazardous reactions Heat, flames and sparks. Contact with incompatible materials. Conditions to avoid Acids. Strong oxidizing agents. Isocyanates. Chlorine. Incompatible materials Carbon oxides. Nitrogen oxides (NOx). Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Skin contact Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Eye contact Causes serious eye irritation. Ingestion Harmful if swallowed. related to the physical, chemical and toxicological characteristics Headache. May cause drowsiness and dizziness. Nausea, vomiting. Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash. Information on toxicological effects Acute toxicity In high concentrations, vapors are anesthetic and may cause headache, fatigue, dizziness and central nervous system effects. Harmful in contact with skin. Harmful if swallowed. Narcotic effects. May cause an allergic skin reaction. 5 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 526 of 1287 Page 526 of 1287 Page 526 of 1287 Page 526 of 1287 ---PAGE BREAK--- Test Results Product Species Insect Repellent Dermal Acute LD50 Rabbit 1380 mg/kg estimated Inhalation LC50 Rat 40990 ppm, 4 hours estimated 12 mg/l, 4 Hours estimated Oral LD50 Rat 1737 mg/kg estimated * Estimates for product may be based on additional component data not shown. TDL0 Human 117 g/kg estimated Causes skin irritation. Skin corrosion/irritation Causes serious eye irritation. Serious eye damage/eye irritation Respiratory sensitization Not a respiratory sensitizer. May cause an allergic skin reaction. Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. This product is not expected to cause reproductive or developmental effects. Reproductive toxicity Specific target organ toxicity - single exposure May cause drowsiness and dizziness. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. 12. Ecological information Toxic to aquatic life. Harmful to aquatic life with long lasting effects. Ecotoxicity Product Test Results Species Insect Repellent Aquatic Acute EC50 Crustacea 171.4605 ppm, 48 hours estimated Daphnia LC50 Fish 218.1529 ppm, 96 hours estimated Fish Components Test Results Species Acetone (CAS 67-64-1) Aquatic EC50 Crustacea 10294 - 17704 mg/l, 48 hours Water flea (Daphnia magna) LC50 Fish 4740 - 6330 mg/l, 96 hours Rainbow trout,donaldson trout mykiss) Isopropyl alcohol (CAS 67-63-0) Aquatic Acute EC50 Crustacea 7550 - 13299 mg/l, 48 hours Water flea (Daphnia magna) LC50 Fish 3200 mg/l, 96 hours Fathead minnow (Pimephales promelas) N,N-Diethyl-m-toluamide (DEET) (CAS 134-62-3) Aquatic LC50 Fish 106 - 114 mg/l, 96 hours Fathead minnow (Pimephales promelas) 6 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 527 of 1287 Page 527 of 1287 Page 527 of 1287 Page 527 of 1287 ---PAGE BREAK--- Components Test Results Species Propylene glycol (CAS 57-55-6) Aquatic LC50 Fish 710 mg/l, 96 hours Fathead minnow (Pimephales promelas) * Estimates for product may be based on additional component data not shown. Acute EC50 Crustacea 4850 - 34000 mg/l, 48 hours Water flea (Daphnia magna) No data is available on the degradability of this product. Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Acetone -0.24 Isopropyl alcohol 0.05 N,N-Diethyl-m-toluamide (DEET) 2.02 Propylene glycol -0.92 No data available. Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Disposal of waste from residues / unused products D001: Waste Flammable material with a flash point <140 F Hazardous waste code Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Contaminated packaging 14. Transport information DOT UN1950 UN number Aerosols, flammable, Limited Quantity UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk 2.1 Label(s) Not applicable. Packing group Read safety instructions, SDS and emergency procedures before handling. Special precautions for user N82 Special provisions 306 Packaging exceptions None Packaging non bulk None Packaging bulk IATA UN1950 UN number Aerosols, flammable, Limited Quantity UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk Not applicable. Packing group No. Environmental hazards 10L ERG Code Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Allowed. Passenger and cargo aircraft Other information Allowed. Cargo aircraft only 7 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 528 of 1287 Page 528 of 1287 Page 528 of 1287 Page 528 of 1287 ---PAGE BREAK--- IMDG UN1950 UN number AEROSOLS, LIMITED QUANTITY UN proper shipping name 2 Class Transport hazard class(es) - Subsidiary risk Not applicable. Packing group No. Marine pollutant Environmental hazards Not available. EmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. SARA 304 Emergency release notification Not regulated. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance Dipropyl isocinchomeronate (CAS 136-45-8) CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1) Listed. CERCLA Hazardous Substances: Reportable quantity Acetone (CAS 67-64-1) 5000 LBS Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center ([PHONE REDACTED]) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated. Safe Drinking Water Act (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1) 6532 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1) 35 %WV DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1) 6532 Not regulated. Food and Drug Administration (FDA) US EPA Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA) This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. FIFRA Information Warning. Signal word Harmful if swallowed. Causes substantial but temporary eye injury. This product is registered in all 50 United States and Puerto Rico. This product is not registered outside of the United States and Puerto Rico. Hazard statement 8 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 529 of 1287 Page 529 of 1287 Page 529 of 1287 Page 529 of 1287 ---PAGE BREAK--- Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Section 311/312 Hazard categories No SARA 302 Extremely hazardous substance US state regulations US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. Acetone (CAS 67-64-1) Dipropyl isocinchomeronate (CAS 136-45-8) Isopropyl alcohol (CAS 67-63-0) Liquefied Petroleum Gas (CAS 68476-86-8) US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. New Jersey Worker and Community Right-to-Know Act Acetone (CAS 67-64-1) Propylene glycol (CAS 57-55-6) Dipropyl isocinchomeronate (CAS 136-45-8) Isopropyl alcohol (CAS 67-63-0) US. Massachusetts RTK - Substance List Acetone (CAS 67-64-1) Isopropyl alcohol (CAS 67-63-0) US. Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Isopropyl alcohol (CAS 67-63-0) Propylene glycol (CAS 57-55-6) US. Rhode Island RTK Acetone (CAS 67-64-1) Dipropyl isocinchomeronate (CAS 136-45-8) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Benzene (CAS 71-43-2) Listed: February 27, 1987 Cumene (CAS 98-82-8) Listed: April 6, 2010 Dipropyl isocinchomeronate (CAS 136-45-8) Listed: May 1, 1996 Ethanal (CAS 75-07-0) Listed: April 1, 1988 US - California Proposition 65 - CRT: Listed date/Developmental toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 Toluene (CAS 108-88-3) Listed: January 1, 1991 US - California Proposition 65 - CRT: Listed date/Female reproductive toxin Toluene (CAS 108-88-3) Listed: August 7, 2009 US - California Proposition 65 - CRT: Listed date/Male reproductive toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 64.9 % Not regulated Consumer products (40 CFR 59, Subpt. C) State This product is regulated as an Insect Repellent. This product is compliant for use in all 50 states. Consumer products VOC content (CA) 64.9 % VOC content (OTC) 64.9 % 9 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 530 of 1287 Page 530 of 1287 Page 530 of 1287 Page 530 of 1287 ---PAGE BREAK--- International Inventories Country(s) or region Inventory name On inventory (yes/no)* Yes Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory No Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 05-21-2015 Issue date Allison Cho Prepared by Version # 01 CRC # 926 Further information Health: 1 Flammability: 3 Physical hazard: 0 Personal protection: B HMIS® ratings Health: 1 Flammability: 3 Instability: 0 NFPA ratings NFPA ratings 0 1 3 The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries. Disclaimer 10 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 531 of 1287 Page 531 of 1287 Page 531 of 1287 Page 531 of 1287 ---PAGE BREAK--- Material Safety Data Sheet KEROSENE 000003000579 Version 1.0 Revision Date 2015/06/04 Print Date 2015/06/04 Internet: www.petro-canada.ca/msds Page: 1 / 10 TM Trademark of Suncor Energy Inc. SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : KEROSENE Synonyms : Low Sulphur Kerosene, Kerosine, KEROSENE (TYPE 1-K) Product code : 101867, 101866 Manufacturer or supplier's details SUNCOR ENERGY INC. P.O. Box 2844, 150 - 6th Avenue South-West Calgary Alberta T2P 3E3 Canada Emergency telephone number Suncor Energy: +1 [PHONE REDACTED]; Poison Control Centre: Consult local telephone directory for emergency number(s). Recommended use of the chemical and restrictions on use Recommended use : Kerosene is a refined petroleum distillate suitable for burning in wick lamps and space heaters designed for kerosene. Prepared by : Product Safety: +1 [PHONE REDACTED] SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Appearance Clear liquid. Colour Clear and bright Odour Hydrocarbon. Hazard Summary Combustible liquid. Irritating to skin. May cause cancer. Potential Health Effects Primary Routes of Entry : Eye contact Ingestion Inhalation Skin contact Skin Absorption Inhalation : May cause respiratory tract irritation. Causes headache, drowsiness or other effects to the central nervous system. Skin : Causes skin irritation. Page 532 of 1287 Page 532 of 1287 Page 532 of 1287 Page 532 of 1287 ---PAGE BREAK--- Material Safety Data Sheet KEROSENE 000003000579 Version 1.0 Revision Date 2015/06/04 Print Date 2015/06/04 Internet: www.petro-canada.ca/msds Page: 2 / 10 TM Trademark of Suncor Energy Inc. Prolonged skin contact may cause skin irritation and/or dermatitis. Eyes : May cause eye irritation. Ingestion : Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea. Aspiration hazard if swallowed - can enter lungs and cause damage. Aggravated Medical Condition : None known. Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical Name CAS-No. Concentration kerosine (petroleum), hydrodesulfurized 64742-81-0 99 - 100 % Aromatic content (Edmonton) 7-25% typical (benzene: nil). SECTION 4. FIRST AID MEASURES If inhaled : Move to fresh air. Artificial respiration and/or oxygen may be necessary. Seek medical advice. In case of skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Wash clothing before reuse. Seek medical advice. In case of eye contact : Remove contact lenses. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Page 533 of 1287 Page 533 of 1287 Page 533 of 1287 Page 533 of 1287 ---PAGE BREAK--- Material Safety Data Sheet KEROSENE 000003000579 Version 1.0 Revision Date 2015/06/04 Print Date 2015/06/04 Internet: www.petro-canada.ca/msds Page: 3 / 10 TM Trademark of Suncor Energy Inc. Obtain medical attention. If swallowed : Rinse mouth with water. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. Seek medical advice. Most important and effects, both acute and delayed : First aider needs to protect himself. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Dry chemical Carbon dioxide (CO2) fog Foam Unsuitable extinguishing media : Do NOT use water jet. Specific hazards during firefighting : Cool closed containers exposed to fire with water spray. Hazardous combustion products : Carbon oxides (CO, CO2), nitrogen oxides (NOx), sulphur oxides (SOx), unidentified organic compounds, smoke and irritating vapours as products of incomplete combustion. Further information : Prevent fire extinguishing water from contaminating surface water or the ground water system. Special protective equipment for firefighters : Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas. Material can create slippery conditions. Environmental precautions : If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Prevent further leakage or spillage if safe to do so. Remove all sources of ignition. Soak up with inert absorbent material. Non-sparking tools should be used. Ensure adequate ventilation. Contact the proper local authorities. Page 534 of 1287 Page 534 of 1287 Page 534 of 1287 Page 534 of 1287 ---PAGE BREAK--- Material Safety Data Sheet KEROSENE 000003000579 Version 1.0 Revision Date 2015/06/04 Print Date 2015/06/04 Internet: www.petro-canada.ca/msds Page: 4 / 10 TM Trademark of Suncor Energy Inc. SECTION 7. HANDLING AND STORAGE Advice on safe handling : For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Use only with adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Ensure all equipment is electrically grounded before beginning transfer operations. Avoid contact with skin, eyes and clothing. Do not ingest. Do not breathe vapours, mist or gas. Keep away from heat and sources of ignition. Keep container closed when not in use. If ingested, seek medical advice immediately and show the container or the label. Never siphon by mouth. Avoid prolonged contact with eyes, skin and clothing. Conditions for safe storage : Store in original container. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Keep in a dry, cool and well-ventilated place. Keep in properly labelled containers. To maintain product quality, do not store in heat or direct sunlight. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis kerosine (petroleum), hydrodesulfurized 64742-81-0 TWA 200 mg/m3 (as total hydrocarbon vapor) ACGIH TWA 200 mg/m3 (as total hydrocarbon vapor) ACGIH Engineering measures : Use only in well-ventilated areas. Personal protective equipment Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Page 535 of 1287 Page 535 of 1287 Page 535 of 1287 Page 535 of 1287 ---PAGE BREAK--- Material Safety Data Sheet KEROSENE 000003000579 Version 1.0 Revision Date 2015/06/04 Print Date 2015/06/04 Internet: www.petro-canada.ca/msds Page: 5 / 10 TM Trademark of Suncor Energy Inc. Filter type : organic vapour cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air-purifying respirators is limited. Use a positive- pressure, air-supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstances where air-purifying respirators may not provide adequate protection. Hand protection Material : polyvinyl alcohol (PVA), Viton(R). Consult your PPE provider for breakthrough times and the specific glove that is best for you based on your use patterns. It should be realized that eventually any material regardless of their imperviousness, will get permeated by chemicals. Therefore, protective gloves should be regularly checked for wear and tear. At the first signs of hardening and cracks, they should be changed. Remarks : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Eye protection : Wear face-shield and protective suit for abnormal processing problems. Skin and body protection : Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place. Protective measures : Wash contaminated clothing before re-use. Hygiene measures : Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash face, hands and any exposed skin thoroughly after handling. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Clear liquid. Colour : Clear and bright Odour : Hydrocarbon. Odour Threshold : No data available pH : No data available Pour point : -51 °C (-60 °F)No data available Boiling point/boiling range : 150 - 300 °C (302 - 572 Flash point : 38 °C (100 Method: Tagliabue. Page 536 of 1287 Page 536 of 1287 Page 536 of 1287 Page 536 of 1287 ---PAGE BREAK--- Material Safety Data Sheet KEROSENE 000003000579 Version 1.0 Revision Date 2015/06/04 Print Date 2015/06/04 Internet: www.petro-canada.ca/msds Page: 6 / 10 TM Trademark of Suncor Energy Inc. Auto-Ignition Temperature : 210 °C (410 Evaporation rate : No data available Flammability : Flammable in presence of open flames, sparks and heat. May accumulate in confined spaces. This product can accumulate static charge and ignite. Vapours are heavier than air and may travel considerable distance to sources of ignition and flash back. Upper explosion limit : 5 Lower explosion limit : 0.7 Vapour pressure : 10.5 mmHg (20 °C / 68 Relative vapour density : 4.5 Relative density : 0.8 - 0.82 Solubility(ies) Water solubility : insoluble Partition coefficient: n- octanol/water : No data available Viscosity Viscosity, kinematic : 1.0 - 2.4 cSt (40 °C / 104 Explosive properties : Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. SECTION 10. STABILITY AND REACTIVITY Possibility of hazardous reactions : Hazardous polymerisation does not occur. Stable under normal conditions. Conditions to avoid : Extremes of temperature and direct sunlight. Incompatible materials : Reactive with oxidising agents. Hazardous decomposition products : May release COx, NOx, SOx, unidentified organic compounds, smoke and irritating vapours when heated to decomposition. SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Eye contact Ingestion Inhalation Skin contact Page 537 of 1287 Page 537 of 1287 Page 537 of 1287 Page 537 of 1287 ---PAGE BREAK--- Material Safety Data Sheet KEROSENE 000003000579 Version 1.0 Revision Date 2015/06/04 Print Date 2015/06/04 Internet: www.petro-canada.ca/msds Page: 7 / 10 TM Trademark of Suncor Energy Inc. Skin Absorption Acute toxicity Product: Acute oral toxicity : Remarks: No data available Acute inhalation toxicity : Remarks: No data available Acute dermal toxicity : Remarks: No data available Components: kerosine (petroleum), hydrodesulfurized: Acute oral toxicity : LD50 Rat: > 5,000 mg/kg, Acute inhalation toxicity : LC50 Rat: > 5.2 mg/l Exposure time: 4 h Acute dermal toxicity : LD50 Rabbit: > 2,000 mg/kg, Skin corrosion/irritation Product: Remarks: No data available Serious eye damage/eye irritation Product: Remarks: No data available Respiratory or skin sensitisation No data available Germ cell mutagenicity No data available Carcinogenicity No data available Reproductive toxicity No data available STOT - single exposure No data available STOT - repeated exposure No data available Aspiration toxicity No data available Page 538 of 1287 Page 538 of 1287 Page 538 of 1287 Page 538 of 1287 ---PAGE BREAK--- Material Safety Data Sheet KEROSENE 000003000579 Version 1.0 Revision Date 2015/06/04 Print Date 2015/06/04 Internet: www.petro-canada.ca/msds Page: 8 / 10 TM Trademark of Suncor Energy Inc. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Toxicity to fish : Remarks: No data available Toxicity to daphnia and other aquatic invertebrates : Remarks: No data available Toxicity to algae : Remarks: No data available Toxicity to bacteria : Remarks: No data available Persistence and degradability Product: Biodegradability : Remarks: No data available Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : The product should not be allowed to enter drains, water courses or the soil. Offer surplus and non-recyclable solutions to a licensed disposal company. Waste must be classified and labelled prior to recycling or disposal. Send to a licensed waste management company. Dispose of as hazardous waste in compliance with local and national regulations. Dispose of product residue in accordance with the instructions of the person responsible for waste disposal. Contaminated packaging : Do not re-use empty containers. SECTION 14. TRANSPORT INFORMATION International Regulation IATA-DGR UN/ID No. : 1223 Page 539 of 1287 Page 539 of 1287 Page 539 of 1287 Page 539 of 1287 ---PAGE BREAK--- Material Safety Data Sheet KEROSENE 000003000579 Version 1.0 Revision Date 2015/06/04 Print Date 2015/06/04 Internet: www.petro-canada.ca/msds Page: 9 / 10 TM Trademark of Suncor Energy Inc. Proper shipping name : Kerosene Class : 3 Packing group : III Labels : 3 Packing instruction (cargo aircraft) : 366 IMDG-Code UN number : 1223 Proper shipping name : KEROSENE Class : 3 Packing group : III Labels : 3 EmS Code : F-E, S-E Marine pollutant : no Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. TDG UN number : 1223 Proper shipping name : KEROSENE Class : 3 Packing group : III Labels : 3 ERG Code : 128 Marine pollutant : no Special precautions for user Not applicable SECTION 15. REGULATORY INFORMATION WHMIS Classification : B3: Combustible Liquid D2A: Very Toxic Material Causing Other Toxic Effects D2B: Toxic Material Causing Other Toxic Effects This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. The components of this product are reported in the following inventories: DSL On the inventory, or in compliance with the inventory TSCA All chemical substances in this product are either listed on the TSCA Inventory or are in compliance with a TSCA Inventory exemption. EINECS On the inventory, or in compliance with the inventory SECTION 16. OTHER INFORMATION For Copy of (M)SDS : Internet: www.petro-canada.ca/msds Canada-wide: telephone: 1-[PHONE REDACTED]; fax: 1-800-837- Page 540 of 1287 Page 540 of 1287 Page 540 of 1287 Page 540 of 1287 ---PAGE BREAK--- Material Safety Data Sheet KEROSENE 000003000579 Version 1.0 Revision Date 2015/06/04 Print Date 2015/06/04 Internet: www.petro-canada.ca/msds Page: 10 / 10 TM Trademark of Suncor Energy Inc. 1228 For Product Safety Information: 1 [PHONE REDACTED] Prepared by : Product Safety: +1 [PHONE REDACTED] The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Page 541 of 1287 Page 541 of 1287 Page 541 of 1287 Page 541 of 1287 ---PAGE BREAK--- page 1 of 5 DATE OF PREPARATION Mar 6, 2015 MATERIAL SAFETY DATA SHEET 1307 10 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER 1307 PRODUCT NAME KRYLON® Battery Protector MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY KRYLON Products Group Cleveland, OH 44115 Telephone Numbers and Websites Product Information (800) 247-3266 Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 15 74-98-6 Propane ACGIH TLV 1000 PPM 760 mm OSHA PEL 1000 PPM 15 106-97-8 Butane ACGIH TLV 1000 PPM 760 mm OSHA PEL 800 PPM 18 64742-89-8 Lt. Aliphatic Hydrocarbon Solvent ACGIH TLV 300 PPM 12 mm OSHA PEL 300 PPM 16 108-88-3 Toluene ACGIH TLV 20 PPM 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 2 100-41-4 ACGIH TLV 20 PPM 7.1 mm OSHA PEL 100 PPM OSHA PEL 125 PPM STEL 13 1330-20-7 Xylene ACGIH TLV 100 PPM 5.9 mm ACGIH TLV 150 PPM STEL OSHA PEL 100 PPM OSHA PEL 150 PPM STEL 2 64742-94-5 Medium Aromatic Hydrocarbons ACGIH TLV Not Available 0.12 mm OSHA PEL Not Available 0.3 91-20-3 Naphthalene ACGIH TLV 10 PPM 1 mm ACGIH TLV 15 PPM STEL OSHA PEL 10 PPM OSHA PEL 15 PPM STEL 11 67-64-1 Acetone ACGIH TLV 500 PPM 180 mm ACGIH TLV 750 PPM STEL OSHA PEL 1000 PPM SECTION 3 — HAZARDS IDENTIFICATION Page 542 of 1287 Page 542 of 1287 Page 542 of 1287 Page 542 of 1287 ---PAGE BREAK--- 1307 page 2 of 5 UEL 12.8 LEL 0.8 FLASH POINT Propellant < 0 °F HMIS Codes Health 2* Flammability 4 Reactivity 0 ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system the cardiovascular system the reproductive system SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Page 543 of 1287 Page 543 of 1287 Page 543 of 1287 Page 543 of 1287 ---PAGE BREAK--- 1307 page 3 of 5 Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 5.93 lb/gal 709 g/l SPECIFIC GRAVITY 0.71 BOILING POINT <0 - 415 °F <-18 - 212 °C MELTING POINT Not Available VOLATILE VOLUME 95% EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available pH > 2.0, < 11.5 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 81.18% Less Water and Federally Exempt Solvents SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Naphthalene is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that causes cancer in humans. Page 544 of 1287 Page 544 of 1287 Page 544 of 1287 Page 544 of 1287 ---PAGE BREAK--- 1307 page 4 of 5 TOXICOLOGY DATA CAS No. Ingredient Name 74-98-6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106-97-8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 64742-89-8 Lt. Aliphatic Hydrocarbon Solvent LC50 RAT 4HR Not Available LD50 RAT Not Available 108-88-3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 100-41-4 LC50 RAT 4HR Not Available LD50 RAT 3500 mg/kg 1330-20-7 Xylene LC50 RAT 4HR 5000 ppm LD50 RAT 4300 mg/kg 64742-94-5 Medium Aromatic Hydrocarbons LC50 RAT 4HR Not Available LD50 RAT Not Available 91-20-3 Naphthalene LC50 RAT 4HR Not Available LD50 RAT Not Available 67-64-1 Acetone LC50 RAT 4HR Not Available LD50 RAT 5800 mg/kg SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U IATA/ICAO UN1950, AEROSOLS, FLAMMABLE, 2.1, LIMITED QUANTITY SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 108-88-3 Toluene 16 100-41-4 2 1330-20-7 Xylene 13 91-20-3 Naphthalene 0.2 Page 545 of 1287 Page 545 of 1287 Page 545 of 1287 Page 545 of 1287 ---PAGE BREAK--- 1307 page 5 of 5 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 546 of 1287 Page 546 of 1287 Page 546 of 1287 Page 546 of 1287 ---PAGE BREAK--- page 1 of 6 DATE OF PREPARATION May 4, 2015 MATERIAL SAFETY DATA SHEET 03702 07 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER 03702 PRODUCT NAME KRYLON® Industrial QUIK-MARK™ Solvent-Based Inverted Marking Paint (Fluorescent), Orange MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY KRYLON INDUSTRIAL PRODUCTS GROUP Cleveland, OH 44115 Telephone Numbers and Websites Product Information (800) 247-3266 www.kpg-industrial.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) Page 547 of 1287 Page 547 of 1287 Page 547 of 1287 Page 547 of 1287 ---PAGE BREAK--- 03702 page 2 of 6 HMIS Codes Health 2* Flammability 3 Reactivity 0 SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 14 74-98-6 Propane ACGIH TLV 1000 PPM 760 mm OSHA PEL 1000 PPM 6 106-97-8 Butane ACGIH TLV 1000 PPM 760 mm OSHA PEL 800 PPM 8 110-54-3 Hexane ACGIH TLV 50 PPM 127 mm OSHA PEL 50 PPM 4 107-83-5 ACGIH TLV Not Available 211 mm OSHA PEL Not Available 1 96-14-0 ACGIH TLV 500 PPM 211 mm OSHA PEL Not Available 1 79-29-8 ACGIH TLV Not Available 230 mm OSHA PEL Not Available 9 142-82-5 Heptane ACGIH TLV 400 PPM 50 mm ACGIH TLV 500 PPM STEL OSHA PEL 400 PPM OSHA PEL 500 PPM STEL 8 64742-89-8 Lt. Aliphatic Hydrocarbon Solvent ACGIH TLV 300 PPM 12 mm OSHA PEL 300 PPM 0.4 100-41-4 ACGIH TLV 20 PPM 7.1 mm OSHA PEL 100 PPM OSHA PEL 125 PPM STEL 2 1330-20-7 Xylene ACGIH TLV 100 PPM 5.9 mm ACGIH TLV 150 PPM STEL OSHA PEL 100 PPM OSHA PEL 150 PPM STEL 0.3 14808-60-7 Quartz ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.1 mg/m3 as Resp. Dust 27 1317-65-3 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system the reproductive system SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Page 548 of 1287 Page 548 of 1287 Page 548 of 1287 Page 548 of 1287 ---PAGE BREAK--- 03702 page 3 of 6 UEL 9.5 LEL 0.9 FLASH POINT Propellant < 0 °F SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Page 549 of 1287 Page 549 of 1287 Page 549 of 1287 Page 549 of 1287 ---PAGE BREAK--- 03702 page 4 of 6 SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 7.37 lb/gal 883 g/l SPECIFIC GRAVITY 0.89 BOILING POINT <0 - 325 °F <-18 - 162 °C MELTING POINT Not Available VOLATILE VOLUME 78% EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available pH > 2.0, < 11.5 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 56.25% Less Water and Federally Exempt Solvents SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Prolonged and repeated exposure to Hexane may cause damage to nerve tissue of the arms and legs (peripheral neuropathy), resulting in muscular weakness and loss of sensation. This effect may be increased by the presence of Methyl Ethyl Ketone. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that causes cancer in humans. Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. Page 550 of 1287 Page 550 of 1287 Page 550 of 1287 Page 550 of 1287 ---PAGE BREAK--- 03702 page 5 of 6 TOXICOLOGY DATA CAS No. Ingredient Name 74-98-6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106-97-8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 110-54-3 Hexane LC50 RAT 4HR Not Available LD50 RAT 28700 mg/kg 107-83-5 LC50 RAT 4HR Not Available LD50 RAT Not Available 96-14-0 LC50 RAT 4HR Not Available LD50 RAT Not Available 79-29-8 LC50 RAT 4HR Not Available LD50 RAT Not Available 142-82-5 Heptane LC50 RAT 4HR Not Available LD50 RAT Not Available 64742-89-8 Lt. Aliphatic Hydrocarbon Solvent LC50 RAT 4HR Not Available LD50 RAT Not Available 100-41-4 LC50 RAT 4HR Not Available LD50 RAT 3500 mg/kg 1330-20-7 Xylene LC50 RAT 4HR 5000 ppm LD50 RAT 4300 mg/kg 14808-60-7 Quartz LC50 RAT 4HR Not Available LD50 RAT Not Available 1317-65-3 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U IATA/ICAO UN1950, AEROSOLS, FLAMMABLE, 2.1, LIMITED QUANTITY Page 551 of 1287 Page 551 of 1287 Page 551 of 1287 Page 551 of 1287 ---PAGE BREAK--- 03702 page 6 of 6 SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 110-54-3 Hexane 8 100-41-4 0.3 1330-20-7 Xylene 2 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 552 of 1287 Page 552 of 1287 Page 552 of 1287 Page 552 of 1287 ---PAGE BREAK--- page 1 of 6 DATE OF PREPARATION May 4, 2015 MATERIAL SAFETY DATA SHEET TT3701 06 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER TT3701 PRODUCT NAME KRYLON® Industrial QUIK-MARK™ Solvent-Based Inverted Marking Paint (Fluorescent), Red Orange MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY KRYLON INDUSTRIAL PRODUCTS GROUP Cleveland, OH 44115 Telephone Numbers and Websites Product Information (800) 247-3266 www.kpg-industrial.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) Page 553 of 1287 Page 553 of 1287 Page 553 of 1287 Page 553 of 1287 ---PAGE BREAK--- TT3701 page 2 of 6 HMIS Codes Health 2* Flammability 3 Reactivity 0 SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 14 74-98-6 Propane ACGIH TLV 1000 PPM 760 mm OSHA PEL 1000 PPM 6 106-97-8 Butane ACGIH TLV 1000 PPM 760 mm OSHA PEL 800 PPM 8 110-54-3 Hexane ACGIH TLV 50 PPM 127 mm OSHA PEL 50 PPM 4 107-83-5 ACGIH TLV Not Available 211 mm OSHA PEL Not Available 1 96-14-0 ACGIH TLV 500 PPM 211 mm OSHA PEL Not Available 1 79-29-8 ACGIH TLV Not Available 230 mm OSHA PEL Not Available 9 142-82-5 Heptane ACGIH TLV 400 PPM 50 mm ACGIH TLV 500 PPM STEL OSHA PEL 400 PPM OSHA PEL 500 PPM STEL 7 64742-89-8 Lt. Aliphatic Hydrocarbon Solvent ACGIH TLV 300 PPM 12 mm OSHA PEL 300 PPM 0.4 100-41-4 ACGIH TLV 20 PPM 7.1 mm OSHA PEL 100 PPM OSHA PEL 125 PPM STEL 2 1330-20-7 Xylene ACGIH TLV 100 PPM 5.9 mm ACGIH TLV 150 PPM STEL OSHA PEL 100 PPM OSHA PEL 150 PPM STEL 0.3 14808-60-7 Quartz ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.1 mg/m3 as Resp. Dust 27 1317-65-3 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system the reproductive system SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Page 554 of 1287 Page 554 of 1287 Page 554 of 1287 Page 554 of 1287 ---PAGE BREAK--- TT3701 page 3 of 6 UEL 9.5 LEL 0.9 FLASH POINT Propellant < 0 °F SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Page 555 of 1287 Page 555 of 1287 Page 555 of 1287 Page 555 of 1287 ---PAGE BREAK--- TT3701 page 4 of 6 SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 7.36 lb/gal 881 g/l SPECIFIC GRAVITY 0.89 BOILING POINT <0 - 325 °F <-18 - 162 °C MELTING POINT Not Available VOLATILE VOLUME 78% EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available pH > 2.0, < 11.5 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 56.41% Less Water and Federally Exempt Solvents SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Prolonged and repeated exposure to Hexane may cause damage to nerve tissue of the arms and legs (peripheral neuropathy), resulting in muscular weakness and loss of sensation. This effect may be increased by the presence of Methyl Ethyl Ketone. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that causes cancer in humans. Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. Page 556 of 1287 Page 556 of 1287 Page 556 of 1287 Page 556 of 1287 ---PAGE BREAK--- TT3701 page 5 of 6 TOXICOLOGY DATA CAS No. Ingredient Name 74-98-6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106-97-8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 110-54-3 Hexane LC50 RAT 4HR Not Available LD50 RAT 28700 mg/kg 107-83-5 LC50 RAT 4HR Not Available LD50 RAT Not Available 96-14-0 LC50 RAT 4HR Not Available LD50 RAT Not Available 79-29-8 LC50 RAT 4HR Not Available LD50 RAT Not Available 142-82-5 Heptane LC50 RAT 4HR Not Available LD50 RAT Not Available 64742-89-8 Lt. Aliphatic Hydrocarbon Solvent LC50 RAT 4HR Not Available LD50 RAT Not Available 100-41-4 LC50 RAT 4HR Not Available LD50 RAT 3500 mg/kg 1330-20-7 Xylene LC50 RAT 4HR 5000 ppm LD50 RAT 4300 mg/kg 14808-60-7 Quartz LC50 RAT 4HR Not Available LD50 RAT Not Available 1317-65-3 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U IATA/ICAO UN1950, AEROSOLS, FLAMMABLE, 2.1, LIMITED QUANTITY Page 557 of 1287 Page 557 of 1287 Page 557 of 1287 Page 557 of 1287 ---PAGE BREAK--- TT3701 page 6 of 6 SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 110-54-3 Hexane 8 100-41-4 0.3 1330-20-7 Xylene 2 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 558 of 1287 Page 558 of 1287 Page 558 of 1287 Page 558 of 1287 ---PAGE BREAK--- page 1 of 4 HMIS Codes Health 2 Flammability 2 Reactivity 0 DATE OF PREPARATION Apr 8, 2015 MATERIAL SAFETY DATA SHEET 03911 01 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER 03911 PRODUCT NAME KRYLON® Industrial QUIK-MARK™ Water-Based Inverted Marking Paint (APWA), Brilliant Red MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY KRYLON INDUSTRIAL PRODUCTS GROUP Cleveland, OH 44115 Telephone Numbers and Websites Product Information (800) 247-3266 www.kpg-industrial.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 10 74-98-6 Propane ACGIH TLV 1000 PPM 760 mm OSHA PEL 1000 PPM 4 106-97-8 Butane ACGIH TLV 1000 PPM 760 mm OSHA PEL 800 PPM 1 64742-89-8 Lt. Aliphatic Hydrocarbon Solvent ACGIH TLV 300 PPM 12 mm OSHA PEL 300 PPM 9 64742-88-7 Med. Aliphatic Hydrocarbon Solvent ACGIH TLV 100 PPM 1.27 mm OSHA PEL 100 PPM 10 108-88-3 Toluene ACGIH TLV 20 PPM 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 1 1317-65-3 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system Page 559 of 1287 Page 559 of 1287 Page 559 of 1287 Page 559 of 1287 ---PAGE BREAK--- 03911 page 2 of 4 UEL 9.5 LEL 0.9 FLASH POINT Propellant < 0 °F the cardiovascular system the reproductive system SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. Page 560 of 1287 Page 560 of 1287 Page 560 of 1287 Page 560 of 1287 ---PAGE BREAK--- 03911 page 3 of 4 When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 7.20 lb/gal 862 g/l SPECIFIC GRAVITY 0.87 BOILING POINT <0 - 395 °F <-18 - 201 °C MELTING POINT Not Available VOLATILE VOLUME 96% EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available pH > 2.0, < 11.5 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 34.49% Less Water and Federally Exempt Solvents SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. TOXICOLOGY DATA CAS No. Ingredient Name 74-98-6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106-97-8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 64742-89-8 Lt. Aliphatic Hydrocarbon Solvent LC50 RAT 4HR Not Available LD50 RAT Not Available 64742-88-7 Med. Aliphatic Hydrocarbon Solvent LC50 RAT 4HR Not Available LD50 RAT Not Available 108-88-3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 1317-65-3 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Page 561 of 1287 Page 561 of 1287 Page 561 of 1287 Page 561 of 1287 ---PAGE BREAK--- 03911 page 4 of 4 SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U IATA/ICAO UN1950, AEROSOLS, FLAMMABLE, 2.1, LIMITED QUANTITY SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 108-88-3 Toluene 10 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 562 of 1287 Page 562 of 1287 Page 562 of 1287 Page 562 of 1287 ---PAGE BREAK--- TRI-CHEM CORPORATION MATERIAL SAFETY DATA SHEET MFG.CODE # SECTION I MANUFACTURER’S NAME TRI-CHEM CORPORATION EMERGENCY TELEPHONE NO. CHEMTREC [PHONE REDACTED] ADDRESS (Street, City, State and Zip Code) P. O. BOX 71550, MADISON HGTS., MI 48071-0550 CHEMICAL NAME AND SYNONYMS N/A TRADE NAME AND SYNONYMS LECTRA SOL TC (AEROSOL) CHEMICAL FAMILY N/A FORMULA N/A SECTION II – HAZARDOUS INGREDIENTS HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES % TLV (UNITS) Trichloroethylene (CAS# 79-01-6) >1 50 ppm Carbon Dioxide (CAS# 124-38-9) >1 5000 ppm This product contains 14 ounces of Trichloroethylene per can of product. Trichloroethylene is a regulated chemical under the Emergency Planning and Right-To-Know Act. You are required to file E.P.A. SARA repots once the threshold of 10,000 pounds of Trichloroethylene has been purchased for one location in each calendar year. All components of this product are listed on the E.P.A./TSCA inventory of chemical substances. SECTION III – PHYSICAL DATA BOILING POINT (ºF) 189° F SPECIFIC GRAVITY (H2O = 1) 1.4 VAPOR PRESSURE (in can PSIG) 95-105 PERCENT VOLATILE BY VOLUME 100 VAPOR DENSITY (AIR = 1) 4 EVAPORATION RATE ( Butyl Acetate faster SOLUBILITY IN WATER insoluble PH N/A APPEARANCE AND ODOR Clear water white liquid with an etherial odor. SECTION IV – FIRE AND EXPLOSION DATA Lel Uel FLASH POINT (Method Used) None FLAMMABLE LIMITS 8.0 52.0 EXTINGUISHING MEDIA Use extinguishing media suitable for fighting surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES Fire fighters should wear full protective clothing including self-contained respiratory equipment operated in a positive mode. Use water spray to keep containers cool. UNUSUAL FIRE AND EXPLOSION HAZARDS Cans may vent, rupture, or burst when exposed to temperatures in excess of 120ºF. (Continued on reverse side) Page 563 of 1287 Page 563 of 1287 Page 563 of 1287 Page 563 of 1287 ---PAGE BREAK--- SECTION V – HEALTH HAZARD DATA THRESHOLD LIMIT VALUE 50 ppm PRIMARY ROUTES OF ENTRY Inhalation x Skin Contact x Other (Specify) EFFECTS OF OVEREXPOSURE Eyes- liquid and vapors may cause irritation. Skin- dry skin, irritation. Inhalation- narcosis, headache, dizziness, carboxyhemoglobinemia. Alcohol consumed before exposure increases effects. EMERGENCY AND FIRST AID PROCEDURE Eyes- flush with copious amounts of water lifting lids and removing contact lenses to ensure complete irrigation- get medical attention. Skin- flush with water and then wash with soap and water, launder contaminated clothing before reuse- get medical if irritation persists. Inhalation- remove to fresh air and assist breathing as necessary- get medical attention. Ingestion- DO NOT INDUCE VOMITING- aspiration of material into lungs may cause chemical pneumonitis which can be fatal- get medical attention. Use gastric lavage. Never use adrenalin. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Persons with pre-existing heart or respiratory disorders Carcinogen: NTP IARC OTHER X California Prop 65 SECTION VI – REACTIVITY DATA UNSTABLE STABILITY STABLE x CONDITIONS TO AVOID Temperatures in excess of 120ºF. INCOMPATABILITY (Conditions to avoid) Strong Oxidizers and Alkalies, reactive metals HAZARDOUS DECOMPOSITION PRODUCTS Oxides of Carbon, Hydrogen Chloride, Phosgene MAY OCCUR HAZARDOUS POLYMERIZATION WILL NOT OCCUR x CONDITIONS TO AVOID None SECTION VII – SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Ventilate spill area. Dike area to contain spill and use absorbent material to soak up spill. Shovel or sweep into for container for disposal. WASTE DISPOSAL METHOD Aerosol cans when emptied and depressurized through normal use pose no disposal hazard and should be recycled. Absorbent materials should be disposed of in accordance with all Local, State, and Federal regulations. SECTION VIII – SPECIAL PROTECTION INFORMATION SPECIAL RESPIRATORY PROTECTION (Specify type) Use NIOSH approved respirator in areas where TLV has been exceeded. LOCAL EXHAUST To control TLV SPECIAL N/A VENTILATION MECHANICAL (General) To control TLV OTHER N/A PROTECTIVE GLOVES Impervious EYE PROTECTION Chemical Goggles OTHER PROTECTIVE EQUIPMENT Eyewash and safety shower. SECTION IX – SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Avoid contact- wear protective clothing and wash thoroughly after using. Avoid inhalation of vapors- do not use in confined, poorly ventilated, or other areas where TLV may be exceeded without proper respiratory protection. Do not take internally. OTHER PRECAUTIONS Do not store in areas where temperatures may exceed 120 degrees F. Keep Out of Reach of Children. HMIS SYMBOL SEVERE 4 SERIOUS 3 MODERATE 2 SLIGHT 1 MINIMAL 0 NAME John Telles SIGNATURE TITLE CHEMIST PREPARATION DATE June 19, 2012 PHONE NUMBER CHEMTREC [PHONE REDACTED] HEALTH 2 FLAMMABILITY 1 REACTIVITY 0 Page 564 of 1287 Page 564 of 1287 Page 564 of 1287 Page 564 of 1287 ---PAGE BREAK--- Page 1 of 3 MATERIAL SAFETY DATA SHEET Prepared: 13 April 2011 Section 1 – Product and Company Identification Product(s): Lemon Duster™ Dusting & Cleaning Spray Formula: A324 Part Number(s): 32420 Company Name & Address: 805 E. Old 56 Hwy. Olathe, KS 66061 [PHONE REDACTED] (8 a.m. – 5 p.m. Weekdays, CDT) Emergency Numbers: IN CASE OF EMERGENCY, CALL Infotrac @ 1-[PHONE REDACTED], 24 hrs. INTERNATIONAL EMERGENCY NUMBER [PHONE REDACTED] Poison Control Center: 1-[PHONE REDACTED] Material Safety Data Sheets: www.dymon.com Section 2 – Hazards Identification DANGER. Contains petroleum distillates – aspiration hazard. Harmful or fatal if swallowed. Can enter lungs and cause damage. May cause eye, skin and respiratory tract irritation. Can cause central nervous system effects if improperly used. Contents under pressure. Potential Health Effects EYES: May cause eye irritation. SKIN: May cause skin irritation. INHALATION: May cause respiratory tract irritation. INGESTION: Aspiration hazard. Harmful or fatal if swallowed. of exposure: Redness, tearing or burning in eyes. Drying, burning or cracking of skin. Nose, throat, and digestive tract irritation. Headaches, nausea, vomiting, drowsiness, dizziness, loss of coordination. Medical conditions generally aggravated by exposure: pre-existing skin disorders may be adversely affected. Follow good chemical hygiene practices to avoid these hazards. HMIS Rating Health – 1 Flammability – 2 Reactivity – 0 Personal Protection – A Section 3 – Composition/Information on Ingredients Ingredient CAS Number Percent Range Water 7732-18-5 60 – 100 Paraffins, Naphthenic Solvent 64742-47-8 5 – 10 Isobutane 75-28-5 5 – 10 Isoparaffinic Hydrocarbon 64742-48-9 3 – 7 White Mineral Oil 8042-47-5 3 – 7 Sorbitan Oleate 1338-43-8 1 – 5 Propane 74-98-6 1 – 5 Isopropyl Myristate 110-27-0 1 – 5 Alcohol Ethoxylate Proprietary 0.5 – 1.5 Any substance listed as hazardous by the states of California, Florida, Illinois, Michigan, New Jersey, Ohio, or Texas is described above if known present in regulated concentrations. Section 4 – First Aid Measures EYES: Flush eyes with large amounts of water for at least 15 minutes while holding eyelids open. Seek medical attention immediately. Page 565 of 1287 Page 565 of 1287 Page 565 of 1287 Page 565 of 1287 ---PAGE BREAK--- Formula: A324 Page 2 of 3 SKIN: Flush with plenty of water for 15 minutes while removing contaminated clothing and shoes. If irritation arises and persists seek medical attention. Launder clothing and shoes before reuse. INHALATION: Move to fresh air. If breathing has stopped, qualified personnel should administer artificial respiration. INGESTION: Do NOT induce vomiting unless directed by a physician. Aspiration hazard. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Section 5 – Fire Fighting Measures Flashpoint (PMCC): 120º F Extinguishing Media: Carbon dioxide, dry chemical, foam, fog or water. Special Fire Fighting Procedures: Keep containers cool and vapors down with water spray. Prevent runoff from entering sewers and public waterways. Wear self-contained breathing apparatus (SCBA) in chemical fires. Hazardous Products of Combustion: Silica, formic acid, oxides of carbon, aldehydes, smoke and soot. Section 6 – Accidental Release Measures Small spill: Wipe up small releases with a dry absorbent cloth or other absorbent material. Large spill: Ventilate area and block traffic. Eliminate all ignition sources. Absorb liquid with vermiculite, absorbent cloth, or other absorbent material. Prevent material from entering sewers and drains. Transfer contaminated material into suitable container for proper disposal. Section 7 – Handling and Storage Handling: Avoid contact with eyes, skin and clothing. Avoid inhaling mists or vapors. Do not smoke while using. Use only with adequate ventilation. Do not swallow. Wash thoroughly after handling. Launder clothing before reuse. Do not deliberately concentrate and inhale vapors. Direct spray away from face. Spray can in upright position only. Follow good chemical hygiene practices when handling this material. Use from original container only and follow label directions carefully. Storage: Keep away from heat, sparks, open flame and direct sunlight. Store in a cool (less than 120° F) well- ventilated area. Keep out of reach of children. Do not contaminate water, food or feed by use or storage. Do not puncture or incinerate container. Replace cap when not in use. Section 8 – Exposure Controls/Personal Protection Engineering controls: Ventilation not usually necessary but should be provided in the event of overexposure. Exposure limits: Paraffins, Naphthenic Solvent (CAS #64742-47-8)=152 ppm TWA Manufacturer’s Recommendation Isobutane (75-28-5)=800 ppm OSHA; 800 ppm ACGIH Isoparaffinic Hydrocarbon (CAS #64742-48-9)=117 ppm TWA, Manufacturer’s Recommendation White Mineral Oil (CAS# 8042-47-5)= 5 mg/m3 OSHA ; 10 mg/m3 STEL ACGIH Propane (CAS# 74-98-6)=1000 ppm OSHA; ACGIH Eye protection: Yes, wear approved safety glasses or goggles if direct contact is possible. Skin protection: Yes, wear impervious gloves if direct contact is possible. Respiratory protection: Not usually necessary. If vapors are present or irritation is experienced, use NIOSH/MSHA approved respirator. Section 9 – Physical and Chemical Properties Appearance and Odor: White creamy liquid with a citrus odor. pH: 9.7 ± 0.5 Boiling Point: 212° F Specific Gravity: 0.921 Vapor Density: >1 Flame Projection: None Solubility in Water: Miscible Pressure: 80 psig Volatile Organic Compounds (VOCs): 14.99 % by weight Section 10 – Stability and Reactivity Hazardous Polymerization: This product will not undergo hazardous polymerization. Hazardous Decomposition or Byproducts: Silica, formic acid, oxides of carbon, aldehydes, smoke and soot. Chemical Stability: Stable Page 566 of 1287 Page 566 of 1287 Page 566 of 1287 Page 566 of 1287 ---PAGE BREAK--- Formula: A324 Page 3 of 3 Incompatible Materials: Strong oxidizers, acids and alkalis. Section 11 – Toxicological Information White Mineral Oil, CAS # 8042-47-5 Dermal LD50 >2000 rabbit, Oral LD50 >5000 rat Isopropyl Myristate, CAS # 110-27-0 Oral LD50>10,000 mg/kg rat; Dermal LD50=5000 mg/kg rabbit Section 12 – Ecological Information No data. Section 13 – Disposal Considerations Dispose of in accordance with all applicable local, state, and federal regulations. Waste information: If this product becomes a waste, it would not be a hazardous waste as defined by RCRA (40CFR261). However the waste should be properly evaluated in case of modification prior to disposal. Section 14 – Transport Information The following transportation information is based on Department of Transportation Regulations found in 49 CFR. If shipping this product by air please refer to International Air Transport Association (IATA) Dangerous Goods Regulations. If shipping this product by ocean please refer to International Maritime Dangerous Goods Regulations (IMDG). To find how to ship this product please refer to the UN# listed below. UN # Proper Shipping Hazard Packing Description Class Group DOT Information None Consumer Commodity ORM-D None Marine Pollutants: None Section 15 – Regulatory Information US Federal Regulations Toxic Substances Control Act (TSCA): All ingredients are on the TSCA inventory or exempt from listing. CERCLA RQ None SARA 313 Components None State and Local Regulations California Proposition 65 None Section 16 – Other Information WARNING! The use of this product is beyond the control of the manufacturer; therefore, no guarantee, expressed or implied, is made as to the effects of such or the results to be obtained if not used in accordance with directions or established safe practice. The user must assume all responsibility, including injury or damage, resulting from its misuse as such, or in combination with other materials. The manufacturer warrants only that this product meets the manufacturer's specifications for such product. THIS WARRANTY IS IN LIEU OF ALL OTHER WARRANTIES, EXPRESS OR IMPLIED, AS TO DESCRIPTION, QUALITY, AND MERCHANTABILITY. FITNESS FOR ANY PARTICULAR PURPOSE, PRODUCTIVENESS OR ANY OTHER MATTER, OF THIS PRODUCT. THE MANUFACTURER SHALL BE IN NO WAY RESPONSIBLE FOR THE IMPROPER USE OF THIS PRODUCT. The sole and exclusive remedy against the manufacturer for breach of warranty shall be reimbursement of the purchase price of the product in the event that a defective condition of the product shall be found to exist. NO OTHER REMEDY (INCLUDING BUT NOT LIMITED TO INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR INJURY TO PERSON OR PROPERTY OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE. Page 567 of 1287 Page 567 of 1287 Page 567 of 1287 Page 567 of 1287 ---PAGE BREAK--- 03/07/2015 Class C Solutions Group, a business of MSC Industrial Supply Co. - LIGHT GRAY PRIMER, BD13510000 1/12 Safety Data Sheet Supply Co. - LIGHT GRAY PRIMER, BD13510000 Document Nbr: 076406 Class C Parts IDs BD1351,BD1351-1 S(R*) SEYMOUR(R*) SAFETY DATA SHEET PRINTING DATE: 02/16/2015 REVISED ON: 02/16/2015 IDENTIFICATION OF THE SUBSTANCE AND MANUFACTURER TRADE NAME: LIGHT GRAY PRIMER PRODUCT CODE: BD13510000 PRODUCT CATEGORY: PC9A: PAINTS AND COATINGS. MANUFACTURER/SUPPLIER: SEYMOUR OF SYCAMORE 917 CROSBY AVENUE SYCAMORE, IL 60178 PHONE: [PHONE REDACTED] WWW.SEYMOURPAINT.COM EMERGENCY TELEPHONE NUMBER: CHEMTEL: 1-[PHONE REDACTED], OR [PHONE REDACTED]. HAZARD(S) IDENTIFICATION CLASSIFICATION OF THE SUBSTANCE OR MIXTURE: FLAM. AEROSOL 1: Page 568 of 1287 Page 568 of 1287 Page 568 of 1287 Page 568 of 1287 ---PAGE BREAK--- 03/07/2015 Class C Solutions Group, a business of MSC Industrial Supply Co. - LIGHT GRAY PRIMER, BD13510000 2/12 H222: EXTREMELY FLAMMABLE AEROSOL. PRESS. GAS: H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED. CARC. 2: H351: SUSPECTED OF CAUSING CANCER. REPR. 2: H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD. STOT RE 2: H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. EYE IRRIT. 2A: H319: CAUSES SERIOUS EYE IRRITATION. STOT SE 3: H336: MAY CAUSE DROWSINESS OR DIZZINESS. GHS HAZARD PICTOGRAMS: GHS02: FLAME GHS04: GAS CYLINDER GHS07: EXCLAMATION MARK GHS08: HEALTH HAZARD SIGNAL WORD: DANGER HAZARD STATEMENTS: EXTREMELY FLAMMABLE AEROSOL. CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED. CAUSES SERIOUS EYE IRRITATION. SUSPECTED OF CAUSING CANCER. SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD. MAY CAUSE DROWSINESS OR DIZZINESS. MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. PRECAUTIONARY STATEMENTS: IF MEDICAL ADVICE IS NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND. KEEP OUT OF REACH OF CHILDREN. READ LABEL BEFORE USE. OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE. PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE. WASH HANDS THOROUGHLY AFTER HANDLING. Page 569 of 1287 Page 569 of 1287 Page 569 of 1287 Page 569 of 1287 ---PAGE BREAK--- 03/07/2015 Class C Solutions Group, a business of MSC Industrial Supply Co. - LIGHT GRAY PRIMER, BD13510000 3/12 USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL. IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION. STORE LOCKED UP. PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C/122 DEG. F. STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER CLOSED. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS. COMPOSITION/INFORMATION ON INGREDIENTS CHEMICAL CHARACTERIZATION: MIXTURES CHEMICAL DESCRIPTION: THIS PRODUCT IS A MIXTURE OF THE SUBSTANCES LISTED BELOW WITH NONHAZARDOUS ADDITIONS. DANGEROUS COMPONENTS: 67-64-1 ACETONE 24.23% 74-98-6 PROPANE 13.87% 106-97-8 N-BUTANE 8.15% 64742-89-8 VM&P NAPHTHA 5.71% 13463-67-7 TITANIUM DIOXIDE 5.13% 108-88-3 TOLUENE 5.07% 14807-96-6 TALC 4.49% Page 570 of 1287 Page 570 of 1287 Page 570 of 1287 Page 570 of 1287 ---PAGE BREAK--- 03/07/2015 Class C Solutions Group, a business of MSC Industrial Supply Co. - LIGHT GRAY PRIMER, BD13510000 4/12 1330-20-7 XYLENE (MIX) 4.08% 64-17-5 ETHYL ALCOHOL 3.98% 123-86-4 N-BUTYL ACETATE 2.78% 64742-47-8 MINERAL SPIRITS 2.55% 110-19-0 ISOBUTYL ACETATE 1.62% FIRST-AID MEASURES AFTER INHALATION: SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF COMPLAINTS. AFTER SKIN CONTACT: REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH SOAP AND WATER. AFTER EYE CONTACT: RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER. IF PERSIST, CONSULT A DOCTOR. AFTER SWALLOWING: RINSE OUT MOUTH AND THEN DRINK PLENTY OF WATER. RINSE MOUTH WITH WATER. DO NOT INDUCE VOMITING. MOST IMPORTANT AND EFFECTS: DIZZINESS INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION NEEDED: NO FURTHER RELEVANT INFORMATION AVAILABLE. FIRE-FIGHTING MEASURES EXTINGUISHING AGENTS: CO2, EXTINGUISHING POWDER OR WATER SPRAY. FIGHT LARGER FIRES WITH WATER SPRAY. SPECIAL HAZARDS: CAN FORM EXPLOSIVE GAS-AIR MIXTURES. PROTECTIVE EQUIPMENT FOR FIREFIGHTERS: A RESPIRATORY PROTECTIVE DEVICE MAY BE NECESSARY. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES: USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF FUMES/DUST/AEROSOL. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP: DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO SECTION 13. Page 571 of 1287 Page 571 of 1287 Page 571 of 1287 Page 571 of 1287 ---PAGE BREAK--- 03/07/2015 Class C Solutions Group, a business of MSC Industrial Supply Co. - LIGHT GRAY PRIMER, BD13510000 5/12 HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING: USE ONLY IN WELL VENTILATED AREAS. STORAGE REQUIREMENTS: KEEP AWAY FROM SOURCES OF HEAT AND DIRECT SUNLIGHT. DO NOT WAREHOUSE IN SUBFREEZING CONDITIONS. STORE LOCKED UP. EXPOSURE CONTROLS/PERSONAL PROTECTION COMPONENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE: 67-64-1 ACETONE: PEL (USA): LONG-TERM VALUE: 2400 MG/M3, 1000 PPM REL (USA): LONG-TERM VALUE: 590 MG/M3, 250 PPM TLV (USA): SHORT-TERM VALUE: (1782) NIC-1187 MG/M3, (750) NIC-500 PPM LONG-TERM VALUE: (1188) NIC-594 MG/M3, (500) NIC-250 PPM BEI 74-98-6 PROPANE: PEL (USA): LONG-TERM VALUE: 1800 MG/M3, 1000 PPM REL (USA): LONG-TERM VALUE: 1800 MG/M3, 1000 PPM TLV (USA): REFER TO APPENDIX F 106-97-8 N-BUTANE: REL (USA): LONG-TERM VALUE: 1900 MG/M3, 800 PPM TLV (USA): SHORT-TERM VALUE: 2370 MG/M3, 1000 PPM 108-88-3 TOLUENE: PEL (USA): LONG-TERM VALUE: 200 PPM CEILING LIMIT VALUE: 300; 500* PPM *10-MIN PEAK PER 8-HR SHIFT Page 572 of 1287 Page 572 of 1287 Page 572 of 1287 Page 572 of 1287 ---PAGE BREAK--- 03/07/2015 Class C Solutions Group, a business of MSC Industrial Supply Co. - LIGHT GRAY PRIMER, BD13510000 6/12 REL (USA): SHORT-TERM VALUE: 560 MG/M3, 150 PPM LONG-TERM VALUE: 375 MG/M3, 100 PPM TLV (USA): LONG-TERM VALUE: 75 MG/M3, 20 PPM BEI 1330-20-7 XYLENE (MIX): PEL (USA): LONG-TERM VALUE: 435 MG/M3, 100 PPM REL (USA): SHORT-TERM VALUE: 655 MG/M3, 150 PPM LONG-TERM VALUE: 435 MG/M3, 100 PPM TLV (USA): SHORT-TERM VALUE: 651 MG/M3, 150 PPM LONG-TERM VALUE: 434 MG/M3, 100 PPM BEI 64-17-5 ETHYL ALCOHOL: PEL (USA): LONG-TERM VALUE: 1900 MG/M3, 1000 PPM REL (USA): LONG-TERM VALUE: 1900 MG/M3, 1000 PPM TLV (USA): SHORT-TERM VALUE: 1880 MG/M3, 1000 PPM 123-86-4 N-BUTYL ACETATE: PEL (USA): LONG-TERM VALUE: 710 MG/M3, 150 PPM REL (USA): SHORT-TERM VALUE: 950 MG/M3, 200 PPM LONG-TERM VALUE: 710 MG/M3, 150 PPM TLV (USA): SHORT-TERM VALUE: 950 MG/M3, 200 PPM LONG-TERM VALUE: 713 MG/M3, 150 PPM 110-19-0 ISOBUTYL ACETATE: PEL (USA): LONG-TERM VALUE: 700 MG/M3, 150 PPM REL (USA): LONG-TERM VALUE: 700 MG/M3, 150 PPM TLV (USA): Page 573 of 1287 Page 573 of 1287 Page 573 of 1287 Page 573 of 1287 ---PAGE BREAK--- 03/07/2015 Class C Solutions Group, a business of MSC Industrial Supply Co. - LIGHT GRAY PRIMER, BD13510000 7/12 LONG-TERM VALUE: 713 MG/M3, 150 PPM INGREDIENTS WITH BIOLOGICAL LIMIT VALUES: 67-64-1 ACETONE: BEI (USA): 50 MG/L MEDIUM: URINE TIME: END OF SHIFT PARAMETER: ACETONE (NONSPECIFIC) 108-88-3 TOLUENE: BEI (USA): 0.02 MG/L MEDIUM: BLOOD TIME: PRIOR TO LAST SHIFT OF WORKWEEK PARAMETER: TOLUENE 0.03 MG/L MEDIUM: URINE TIME: END OF SHIFT PARAMETER: TOLUENE 0.3 MG/G CREATININE MEDIUM: URINE TIME: END OF SHIFT PARAMETER: O-CRESOL WITH HYDROLYSIS (BACKGROUND) 1330-20-7 XYLENE (MIX): BEI (USA): 1.5 G/G CREATININE MEDIUM: URINE TIME: END OF SHIFT PARAMETER: ACIDS HYGIENIC PROTECTION: IMMEDIATELY REMOVE ALL SOILED AND CONTAMINATED CLOTHING. WASH HANDS AFTER USE. AVOID CONTACT WITH THE EYES AND SKIN. DO NOT EAT OR DRINK WHILE WORKING. BREATHING EQUIPMENT: A RESPIRATOR IS GENERALLY NOT NECESSARY WHEN USING THIS PRODUCT OUTDOORS OR IN LARGE OPEN AREAS. IN CASES WHERE SHORT AND/OR LONG TERM OVEREXPOSURE EXISTS, A CHARCOAL FILTER RESPIRATOR SHOULD BE WORN. IF YOU SUSPECT OVEREXPOSURE CONDITIONS EXIST, PLEASE CONSULT AN AUTHORITY ON CHEMICAL HYGIENE. HAND PROTECTION: Page 574 of 1287 Page 574 of 1287 Page 574 of 1287 Page 574 of 1287 ---PAGE BREAK--- 03/07/2015 Class C Solutions Group, a business of MSC Industrial Supply Co. - LIGHT GRAY PRIMER, BD13510000 8/12 PROTECTIVE GLOVES. THE GLOVE MATERIAL MUST BE IMPERMEABLE AND RESISTANT TO THE SUBSTANCE. EYE PROTECTION: SEALED GOGGLES PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: AEROSOL. ODOR: AROMATIC ODOR THRESHOLD: NOT DETERMINED. PH-VALUE: NOT DETERMINED. MELTING POINT/MELTING RANGE: UNDETERMINED. BOILING POINT: -44 DEG. C (-47 DEG. F) FLASH POINT: -19 DEG. C DEG. F) FLAMMABILITY (SOLID, GAS): EXTREMELY FLAMMABLE. DECOMPOSITION TEMPERATURE: NOT DETERMINED. AUTO IGNITING: PRODUCT IS NOT SELF-IGNITING. DANGER OF EXPLOSION: IN USE, MAY FORM FLAMMABLE/EXPLOSIVE VAPOUR-AIR MIXTURE. LOWER EXPLOSION LIMIT: 1.7 VOL % UPPER EXPLOSION LIMIT: 10.9 VOL % VAPOR PRESSURE: NOT DETERMINED. RELATIVE DENSITY: BETWEEN 0.77 AND 0.85 (WATER EQUALS 1.00) VAPOUR DENSITY: NOT DETERMINED. EVAPORATION RATE: NOT APPLICABLE. PARTITION COEFFICIENT N-OCTONAL/WATER: NOT DETERMINED. SOLUBILITY: NOT DETERMINED. VISCOSITY: NOT DETERMINED. VOC CONTENT: 566.1 G/L / 4.72 LB/GL VOC CONTENT (LESS EXEMPT SOLVENTS): 51.6% MIR VALUE: 1.09 Page 575 of 1287 Page 575 of 1287 Page 575 of 1287 Page 575 of 1287 ---PAGE BREAK--- 03/07/2015 Class C Solutions Group, a business of MSC Industrial Supply Co. - LIGHT GRAY PRIMER, BD13510000 9/12 SOLIDS CONTENT: 23.6% STABILITY AND REACTIVITY REACTIVITY: STABLE AT NORMAL TEMPERATURES. CONDITIONS TO AVOID: DO NOT ALLOW CAN TO EXCEED 120 DEGREES FAHRENHEIT. DO NOT WAREHOUSE IN SUBFREEZING TEMPERATURES. CHEMICAL STABILITY: NOT FULLY EVALUATED. POSSIBILITY OF HAZARDOUS REACTIONS: NO DANGEROUS REACTIONS KNOWN. INCOMPATIBLE MATERIALS: NO FURTHER RELEVANT INFORMATION AVAILABLE. HAZARDOUS DECOMPOSITION: NO DANGEROUS DECOMPOSITION PRODUCTS KNOWN. TOXICOLOGICAL INFORMATION LD/LC50 VALUES THAT ARE RELEVANT FOR CLASSIFICATION: 106-97-8 N-BUTANE: INHALATIVE: LC50/4 H: 658 MG/L (RAT) 13463-67-7 TITANIUM DIOXIDE: ORAL: LD50: >20000 MG/KG (RAT) DERMAL: LD50: >10000 MG/KG (RBT) INHALATIVE: LC50/4 H: >6.82 MG/L (RAT) 1330-20-7 XYLENE (MIX): ORAL: LD50: 8700 MG/KG (RAT) DERMAL: LD50: 2000 MG/KG (RBT) INHALATIVE: LC50/4 H: 6350 MG/L (RAT) 64-17-5 ETHYL ALCOHOL: Page 576 of 1287 Page 576 of 1287 Page 576 of 1287 Page 576 of 1287 ---PAGE BREAK--- 03/07/2015 Class C Solutions Group, a business of MSC Industrial Supply Co. - LIGHT GRAY PRIMER, BD13510000 10/12 ORAL: LD50: 7060 MG/KG (RAT) INHALATIVE: LC50/4 H: 20000 MG/L (RAT) 123-86-4 N-BUTYL ACETATE: ORAL: LD50: 14000 MG/KG (RAT) INHALATIVE: LC50/4 H: >21.0 MG/L (RAT) 110-19-0 ISOBUTYL ACETATE: ORAL: LD50: 4763 MG/KG (RBT) INFORMATION ON TOXICOLOGICAL EFFECTS: NO DATA AVAILABLE. SKIN EFFECTS: NO IRRITANT EFFECT. EYE EFFECTS: IRRITATING EFFECT. SENSITIZATION: NO SENSITIZING EFFECTS KNOWN. CARCINOGENIC CATEGORIES: IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER): 13463-67-7 TITANIUM DIOXIDE 2B 108-88-3 TOLUENE 3 14807-96-6 TALC 2B 1330-20-7 XYLENE (MIX) 3 64-17-5 ETHYL ALCOHOL 1 NTP (NATIONAL TOXICOLOGY PROGRAM): NONE OF THE INGREDIENTS IS LISTED. ECOLOGICAL INFORMATION AQUATIC TOXICITY: HAZARDOUS FOR WATER, DO NOT EMPTY INTO DRAINS. PERSISTENCE AND DEGRADABILITY: THE PRODUCT IS DEGRADABLE AFTER PROLONGED EXPOSURE TO NATURAL WEATHERING PROCESSES. Page 577 of 1287 Page 577 of 1287 Page 577 of 1287 Page 577 of 1287 ---PAGE BREAK--- 03/07/2015 Class C Solutions Group, a business of MSC Industrial Supply Co. - LIGHT GRAY PRIMER, BD13510000 11/12 BIOACCUMULATIVE POTENTIAL: NO FURTHER RELEVANT INFORMATION AVAILABLE. MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE. OTHER ADVERSE EFFECTS: NO FURTHER RELEVANT INFORMATION AVAILABLE. DISPOSAL CONSIDERATIONS DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. DO NOT PUNCTURE, INCINERATE, OR COMPACT. PARTIALLY EMPTY CANS MUST BE DISPOSED OF RESPONSIBLY. DO NOT HEAT OR CUT EMPTY CONTAINERS WITH ELECTRIC OR GAS TORCHES. RECOMMENDATION: COMPLETELY EMPTY CANS SHOULD BE RECYCLED. TRANSPORT INFORMATION UN-NUMBER: UN1950 DOT: N/A DOT: CONSUMER COMMODITY AEROSOLS, FLAMMABLE ADR: 1950 AEROSOLS TRANSPORT HAZARD CLASS(ES): CLASS: 2.1 MARINE POLLUTANT: NO SPECIAL PRECAUTIONS FOR USER: WARNING: GASES EMS NUMBER: F-D, S-U PACKAGING GROUP: UN "MODEL REGULATION": UN1950, AEROSOLS, 2.1 REGULATORY INFORMATION SARA SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES): NONE OF THE INGREDIENTS IN THIS PRODUCT ARE LISTED. SARA SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS): 108-88-3 TOLUENE 1330-20-7 XYLENE (MIX) Page 578 of 1287 Page 578 of 1287 Page 578 of 1287 Page 578 of 1287 ---PAGE BREAK--- 03/07/2015 Class C Solutions Group, a business of MSC Industrial Supply Co. - LIGHT GRAY PRIMER, BD13510000 12/12 CPSC: THIS PRODUCT COMPLIES WITH 16 CFR 1303 AND DOES NOT CONTAIN MORE THAN 90 PPM OF LEAD. CALIFORNIA PROPOSITION 65 CHEMICALS KNOWN TO CAUSE CANCER: 13463-67-7 TITANIUM DIOXIDE 100-41-4 ETHYL BENZENE 1333-86-4 CARBON BLACK 108-10-1 METHYL ISOBUTYL KETONE CALIFORNIA PROPOSITION 65 CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY: 108-88-3 TOLUENE 67-56-1 METHANOL CANADIAN ENVIRONMENTAL PROTECTION ACT: ALL HAZARDOUS INGREDIENTS FOR THIS PRODUCT APPEAR ON THE CANADIAN DOMESTICE SUBSTANCE LIST. EPA: 67-64-1 ACETONE I 108-88-3 TOLUENE II 1330-20-7 XYLENE (MIX) I 110-19-0 ISOBUTYL ACETATE D OTHER INFORMATION CONTACT: REGULATORY AFFAIRS DATE OF PREPARATION / LAST REVISION: 02/16/2015 Page 579 of 1287 Page 579 of 1287 Page 579 of 1287 Page 579 of 1287 ---PAGE BREAK--- Page 580 of 1287 Page 580 of 1287 Page 580 of 1287 Page 580 of 1287 ---PAGE BREAK--- Page 581 of 1287 Page 581 of 1287 Page 581 of 1287 Page 581 of 1287 ---PAGE BREAK--- Page 582 of 1287 Page 582 of 1287 Page 582 of 1287 Page 582 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Liquid Wrench Hydraulic Jack Oil Product identifier Other means of identification M3312 SDS number M3334, M3332, M3312 Part No. 2710.19.3040 Tariff code Hydraulic Fluid Recommended use None known. Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufacturer RSC Chemical Solutions Address 600 Radiator Road Company name Website Telephone Customer Service: (704) 821-7643 Technical: (704) 684-1811 Emergency phone number Emergency Telephone: (303) 623-5716 Emergency Contact: ([PHONE REDACTED]) E-mail United States Not available. Indian Trail, NC 28079 2. Hazard(s) identification Not classified. Physical hazards Category 1B Carcinogenicity Health hazards Not classified. Environmental hazards Not classified. OSHA defined hazards Label elements Signal word Danger Hazard statement May cause cancer. Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. Response If exposed or concerned: Get medical advice/attention. Storage Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures 1 / 7 Material name: Liquid Wrench Hydraulic Jack Oil M3334, M3332, M3312 Version 01 Issue date: 05-01-2015 SDS US Page 583 of 1287 Page 583 of 1287 Page 583 of 1287 Page 583 of 1287 ---PAGE BREAK--- CAS number % Common name and synonyms Chemical name Other components below reportable levels 3 - < 5 64742-52-5 Distillates (petroleum), Hydrotreated Heavy Naphthenic 90 - 100 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Move to fresh air. Call a physician if develop or persist. Inhalation Wash off with soap and water. Get medical attention if irritation develops and persists. Skin contact Rinse with water. Get medical attention if irritation develops and persists. Eye contact Rinse mouth. Get medical attention if occur. Ingestion Direct contact with eyes may cause temporary irritation. Most important acute and delayed Provide general supportive measures and treat Keep victim under observation. may be delayed. Indication of immediate medical attention and special treatment needed IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. General information 5. Fire-fighting measures Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Unsuitable extinguishing media During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Special protective equipment and precautions for firefighters Move containers from fire area if you can do so without risk. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Specific methods No unusual fire or explosion hazards noted. General fire hazards 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid discharge into drains, water courses or onto the ground. Environmental precautions 7. Handling and storage Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Provide adequate ventilation. Avoid prolonged exposure. Should be handled in closed systems, if possible. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Precautions for safe handling Store locked up. Store in original closed container. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 2 / 7 Material name: Liquid Wrench Hydraulic Jack Oil M3334, M3332, M3312 Version 01 Issue date: 05-01-2015 SDS US Page 584 of 1287 Page 584 of 1287 Page 584 of 1287 Page 584 of 1287 ---PAGE BREAK--- 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Form Type PEL 5 mg/m3 Mist. Distillates (petroleum), Hydrotreated Heavy Naphthenic (CAS 64742-52-5) 2000 mg/m3 500 ppm US. ACGIH Threshold Limit Values Value Components Form Type TWA 5 mg/m3 Inhalable fraction. Distillates (petroleum), Hydrotreated Heavy Naphthenic (CAS 64742-52-5) US. NIOSH: Pocket Guide to Chemical Hazards Value Components Form Type Ceiling 1800 mg/m3 Distillates (petroleum), Hydrotreated Heavy Naphthenic (CAS 64742-52-5) STEL 10 mg/m3 Mist. No biological exposure limits noted for the ingredient(s). Biological limit values Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Appropriate engineering controls Individual protection measures, such as personal protective equipment Chemical respirator with organic vapor cartridge and full facepiece. Eye/face protection Skin protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Hand protection Use of an impervious apron is recommended. Other Chemical respirator with organic vapor cartridge and full facepiece. Respiratory protection Wear appropriate thermal protective clothing, when necessary. Thermal hazards Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Liquid. Clear. Appearance Liquid. Physical state Liquid. Form Pale yellow Color Naphthenic Odor Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 680 °F (360 estimated Flash point > 205.0 °F 96.1 Cleveland Open Cup Evaporation rate Not available. Not applicable. Flammability (solid, gas) 3 / 7 Material name: Liquid Wrench Hydraulic Jack Oil M3334, M3332, M3312 Version 01 Issue date: 05-01-2015 SDS US Page 585 of 1287 Page 585 of 1287 Page 585 of 1287 Page 585 of 1287 ---PAGE BREAK--- Upper/lower flammability or explosive limits Flammability limit - lower Not available. Flammability limit - upper Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure Not available. Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 500 °F (260 estimated Decomposition temperature Not available. Viscosity Not available. Other information Density 7.51 lbs/gal Not explosive. Explosive properties Flammability class Combustible IIIB estimated Moisture < 0.1 % Not oxidizing. Oxidizing properties Specific gravity 0.9 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Reactivity Material is stable under normal conditions. Chemical stability No dangerous reaction known under conditions of normal use. Possibility of hazardous reactions Avoid temperatures exceeding the flash point. Contact with incompatible materials. Conditions to avoid Strong oxidizing agents. Incompatible materials No hazardous decomposition products are known. Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation Prolonged inhalation may be harmful. Skin contact No adverse effects due to skin contact are expected. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Expected to be a low ingestion hazard. related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity Not available. Prolonged skin contact may cause temporary irritation. Skin corrosion/irritation Direct contact with eyes may cause temporary irritation. Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. This product is not expected to cause skin sensitization. Skin sensitization 4 / 7 Material name: Liquid Wrench Hydraulic Jack Oil M3334, M3332, M3312 Version 01 Issue date: 05-01-2015 SDS US Page 586 of 1287 Page 586 of 1287 Page 586 of 1287 Page 586 of 1287 ---PAGE BREAK--- No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity May cause cancer. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. US. National Toxicology Program (NTP) Report on Carcinogens Distillates (petroleum), Hydrotreated Heavy Naphthenic (CAS 64742-52-5) Known To Be Human Carcinogen. This product is not expected to cause reproductive or developmental effects. Reproductive toxicity Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Ecotoxicity No data is available on the degradability of this product. Persistence and degradability Bioaccumulative potential No data available. Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations. Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Contaminated packaging 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Not established. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. 5 / 7 Material name: Liquid Wrench Hydraulic Jack Oil M3334, M3332, M3312 Version 01 Issue date: 05-01-2015 SDS US Page 587 of 1287 Page 587 of 1287 Page 587 of 1287 Page 587 of 1287 ---PAGE BREAK--- OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - No Delayed Hazard - Yes Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Hazard categories SARA 302 Extremely hazardous substance Not listed. No SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated. Safe Drinking Water Act (SDWA) US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. Distillates (petroleum), Hydrotreated Heavy Naphthenic (CAS 64742-52-5) US. Massachusetts RTK - Substance List Distillates (petroleum), Hydrotreated Heavy Naphthenic (CAS 64742-52-5) US. New Jersey Worker and Community Right-to-Know Act Not listed. US. Worker and Community Right-to-Know Law Not listed. US. Rhode Island RTK Not regulated. US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance NAPHTHALENE (CAS 91-20-3) Listed: April 19, 2002 International Inventories Country(s) or region Inventory name On inventory (yes/no)* No Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) Yes China Inventory of Existing Chemical Substances in China (IECSC) No Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) 6 / 7 Material name: Liquid Wrench Hydraulic Jack Oil M3334, M3332, M3312 Version 01 Issue date: 05-01-2015 SDS US Page 588 of 1287 Page 588 of 1287 Page 588 of 1287 Page 588 of 1287 ---PAGE BREAK--- Country(s) or region Inventory name On inventory (yes/no)* Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 05-01-2015 Issue date Version # 01 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Disclaimer 7 / 7 Material name: Liquid Wrench Hydraulic Jack Oil M3334, M3332, M3312 Version 01 Issue date: 05-01-2015 SDS US Page 589 of 1287 Page 589 of 1287 Page 589 of 1287 Page 589 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Liquid Wrench Penetrating Oil Product identifier Other means of identification L103 SDS number L103 Part No. 3403.19.5000 Tariff code Penetrant Recommended use None known. Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufacturer RSC Chemical Solutions Address 600 Radiator Road Company name Website Telephone Customer Service: (704) 821-7643 Technical: (704) 684-1811 Emergency phone number Emergency Telephone: (303) 623-5716 Emergency Contact: ([PHONE REDACTED]) E-mail United States Not available. Indian Trail, NC 28079 2. Hazard(s) identification Category 2 Flammable aerosols Physical hazards Category 1B Germ cell mutagenicity Health hazards Category 1A Carcinogenicity Category 3 narcotic effects Specific target organ toxicity, single exposure Category 2 Hazardous to the aquatic environment, acute hazard Environmental hazards Category 2 Hazardous to the aquatic environment, long-term hazard Not classified. OSHA defined hazards Label elements Signal word Danger Hazard statement May cause drowsiness or dizziness. May cause genetic defects. May cause cancer. Toxic to aquatic life. Toxic to aquatic life with long lasting effects. Flammable aerosol. Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing mist or vapor. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Response If inhaled: Remove person to fresh air and keep comfortable for breathing. If exposed or concerned: Get medical advice/attention. Call a poison center/doctor if you feel unwell. Collect spillage. 1 / 9 Material name: Liquid Wrench Penetrating Oil L103 Version 01 Issue date: 05-06-2015 SDS US Page 590 of 1287 Page 590 of 1287 Page 590 of 1287 Page 590 of 1287 ---PAGE BREAK--- Storage Store in a well-ventilated place. Keep container closed. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) Combustible. Supplemental information 31.72% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. 31.72% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment. 3. Composition/information on ingredients Mixtures CAS number % Common name and synonyms Chemical name 64742-47-8 Distillates (petroleum), Hydrotreated Light 60 - < 70 68476-86-8 Petroleum Gases, Liquefied, Sweetened; Petroleum Gas; 20 - < 30 Other components below reportable levels 10 - < 20 64741-88-4 Distillates (petroleum), Solvent-refined Heavy Paraffinic < 0.3 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Inhalation Wash off with soap and water. Get medical attention if irritation develops and persists. Skin contact Rinse with water. Get medical attention if irritation develops and persists. Eye contact In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Ingestion May cause drowsiness and dizziness. Headache. Nausea, vomiting. Diarrhea. Most important acute and delayed Provide general supportive measures and treat Keep victim under observation. may be delayed. Indication of immediate medical attention and special treatment needed IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. General information 5. Fire-fighting measures Powder. Alcohol resistant foam. Dry chemicals. Carbon dioxide (CO2). Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Unsuitable extinguishing media Contents under pressure. Pressurized container may explode when exposed to heat or flame. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Special protective equipment and precautions for firefighters Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. Specific methods Combustible. Flammable aerosol. General fire hazards 2 / 9 Material name: Liquid Wrench Penetrating Oil L103 Version 01 Issue date: 05-06-2015 SDS US Page 591 of 1287 Page 591 of 1287 Page 591 of 1287 Page 591 of 1287 ---PAGE BREAK--- 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Refer to attached safety data sheets and/or instructions for use. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Use water spray to reduce vapors or divert vapor cloud drift. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent product from entering drains. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. Environmental precautions 7. Handling and storage Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Avoid breathing mist or vapor. Avoid prolonged or repeated contact with skin. Avoid prolonged exposure. Should be handled in closed systems, if possible. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. Precautions for safe handling Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Keep out of the reach of children. Store away from incompatible materials (see Section 10 of the SDS). Level 3 Aerosol. Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Form Type PEL 5 mg/m3 Mist. Distillates (petroleum), Solvent-refined Heavy Paraffinic (CAS 64741-88-4) 2000 mg/m3 500 ppm US. ACGIH Threshold Limit Values Value Components Form Type TWA 5 mg/m3 Inhalable fraction. Distillates (petroleum), Solvent-refined Heavy Paraffinic (CAS 64741-88-4) US. NIOSH: Pocket Guide to Chemical Hazards Value Components Form Type TWA 100 mg/m3 Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8) Ceiling 1800 mg/m3 Distillates (petroleum), Solvent-refined Heavy Paraffinic (CAS 64741-88-4) STEL 10 mg/m3 Mist. 3 / 9 Material name: Liquid Wrench Penetrating Oil L103 Version 01 Issue date: 05-06-2015 SDS US Page 592 of 1287 Page 592 of 1287 Page 592 of 1287 Page 592 of 1287 ---PAGE BREAK--- No biological exposure limits noted for the ingredient(s). Biological limit values Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Appropriate engineering controls Individual protection measures, such as personal protective equipment Chemical respirator with organic vapor cartridge and full facepiece. Eye/face protection Skin protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Hand protection Use of an impervious apron is recommended. Other Chemical respirator with organic vapor cartridge and full facepiece. Respiratory protection Wear appropriate thermal protective clothing, when necessary. Thermal hazards When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Opaque Liquid. Appearance Liquid. Physical state Aerosol. Form Yellow Color Pleasant. Odor Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 347 °F (175 estimated Flash point > 200.0 °F 93.3 Tag Closed Cup Evaporation rate Not available. Not applicable. Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower 0.7 % estimated Flammability limit - upper 5 % estimated Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 0.57 hPa estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 410 °F (210 estimated Decomposition temperature Not available. Viscosity Not available. Other information Density 7.42 lbs/gal Not explosive. Explosive properties Flame extension > 18 in 4 / 9 Material name: Liquid Wrench Penetrating Oil L103 Version 01 Issue date: 05-06-2015 SDS US Page 593 of 1287 Page 593 of 1287 Page 593 of 1287 Page 593 of 1287 ---PAGE BREAK--- Flammability (flash back) No Flammability class Combustible IIIB estimated Heat of combustion > 36 kJ/g Heat of combustion (NFPA 30B) 27.62 kJ/g estimated Not oxidizing. Oxidizing properties Percent volatile 0.21 % estimated Specific gravity 0.88 estimated VOC (Weight 21.4 % w/w 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Reactivity Material is stable under normal conditions. Chemical stability No dangerous reaction known under conditions of normal use. Possibility of hazardous reactions Avoid temperatures exceeding the flash point. Contact with incompatible materials. Conditions to avoid Strong oxidizing agents. Incompatible materials No hazardous decomposition products are known. Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful. Skin contact No adverse effects due to skin contact are expected. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Expected to be a low ingestion hazard. related to the physical, chemical and toxicological characteristics Headache. May cause drowsiness and dizziness. Nausea, vomiting. Diarrhea. Information on toxicological effects Acute toxicity Narcotic effects. Prolonged skin contact may cause temporary irritation. Skin corrosion/irritation Direct contact with eyes may cause temporary irritation. Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. This product is not expected to cause skin sensitization. Skin sensitization May cause genetic defects. Germ cell mutagenicity Carcinogenicity May cause cancer. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. US. National Toxicology Program (NTP) Report on Carcinogens Distillates (petroleum), Solvent-refined Heavy Paraffinic (CAS 64741-88-4) Known To Be Human Carcinogen. This product is not expected to cause reproductive or developmental effects. Reproductive toxicity Specific target organ toxicity - single exposure May cause drowsiness and dizziness. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Chronic effects Prolonged inhalation may be harmful. 5 / 9 Material name: Liquid Wrench Penetrating Oil L103 Version 01 Issue date: 05-06-2015 SDS US Page 594 of 1287 Page 594 of 1287 Page 594 of 1287 Page 594 of 1287 ---PAGE BREAK--- 12. Ecological information Toxic to aquatic life with long lasting effects. Ecotoxicity Components Test Results Species * Estimates for product may be based on additional component data not shown. Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8) Aquatic LC50 Fish 2.9 mg/l, 96 hours Rainbow trout,donaldson trout mykiss) No data is available on the degradability of this product. Persistence and degradability Bioaccumulative potential No data available. Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations. Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. Contaminated packaging 14. Transport information DOT Not available. UN number Consumer commodity UN proper shipping name ORM-D Class Transport hazard class(es) - Subsidiary risk None Label(s) Not applicable. Packing group Yes Marine pollutant Environmental hazards Read safety instructions, SDS and emergency procedures before handling. Special precautions for user 156, 306 Packaging exceptions 156, 306 Packaging non bulk None Packaging bulk IATA UN1950 UN number Aerosol, flammable UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk III Packing group Yes Environmental hazards 9L ERG Code Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Allowed. Passenger and cargo aircraft Other information 6 / 9 Material name: Liquid Wrench Penetrating Oil L103 Version 01 Issue date: 05-06-2015 SDS US Page 595 of 1287 Page 595 of 1287 Page 595 of 1287 Page 595 of 1287 ---PAGE BREAK--- Allowed. Cargo aircraft only IMDG UN1950 UN number Aerosols UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk III Packing group Yes Marine pollutant Environmental hazards F-D, S-U EmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Not established. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code IATA; IMDG Marine pollutant 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. One or more components are not listed on TSCA. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Hazard categories SARA 302 Extremely hazardous substance Not listed. 7 / 9 Material name: Liquid Wrench Penetrating Oil L103 Version 01 Issue date: 05-06-2015 SDS US Page 596 of 1287 Page 596 of 1287 Page 596 of 1287 Page 596 of 1287 ---PAGE BREAK--- No SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated. Safe Drinking Water Act (SDWA) US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8) Distillates (petroleum), Solvent-refined Heavy Paraffinic (CAS 64741-88-4) Petroleum Gases, Liquefied, Sweetened; Petroleum Gas; (CAS 68476-86-8) US. Massachusetts RTK - Substance List Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8) Distillates (petroleum), Solvent-refined Heavy Paraffinic (CAS 64741-88-4) US. New Jersey Worker and Community Right-to-Know Act Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8) US. Worker and Community Right-to-Know Law Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8) US. Rhode Island RTK Not regulated. US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* No Australia Australian Inventory of Chemical Substances (AICS) No Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) No Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) No New Zealand New Zealand Inventory No Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 05-06-2015 Issue date Version # 01 8 / 9 Material name: Liquid Wrench Penetrating Oil L103 Version 01 Issue date: 05-06-2015 SDS US Page 597 of 1287 Page 597 of 1287 Page 597 of 1287 Page 597 of 1287 ---PAGE BREAK--- The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Disclaimer 9 / 9 Material name: Liquid Wrench Penetrating Oil L103 Version 01 Issue date: 05-06-2015 SDS US Page 598 of 1287 Page 598 of 1287 Page 598 of 1287 Page 598 of 1287 ---PAGE BREAK--- Page 599 of 1287 Page 599 of 1287 Page 599 of 1287 Page 599 of 1287 ---PAGE BREAK--- Page 600 of 1287 Page 600 of 1287 Page 600 of 1287 Page 600 of 1287 ---PAGE BREAK--- Page 601 of 1287 Page 601 of 1287 Page 601 of 1287 Page 601 of 1287 ---PAGE BREAK--- Safety Data Sheet Revision Number: 008.0 Issue date: 08/28/2014 IDH number: 274809 Product name: Loctite(R) 598 Black RTV High Performance Silicone Gasket Maker Page 1 of 7 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Loctite(R) 598 Black RTV High Performance Silicone Gasket Maker IDH number: 274809 Product type: Silicone Item number: 34018 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-[PHONE REDACTED] (toll free) or 1-[PHONE REDACTED] TRANSPORT EMERGENCY Phone: CHEMTREC 1-[PHONE REDACTED] (toll free) or 1-[PHONE REDACTED] Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE IRRITATION. HARMFUL IF INHALED. HAZARD CLASS HAZARD CATEGORY ACUTE TOXICITY INHALATION 4 SKIN IRRITATION 2 EYE IRRITATION 2A SKIN SENSITIZATION 1 PICTOGRAM(S) Precautionary Statements Prevention: Avoid breathing dust or fumes. Wash thoroughly after handling. Use only outdoors or in a well- ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear eye and face protection. Wear protective gloves. Response: IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. Call a poison control center or physician if you feel unwell. If skin irritation or rash occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. Storage: Not prescribed Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. Page 602 of 1287 Page 602 of 1287 Page 602 of 1287 Page 602 of 1287 ---PAGE BREAK--- IDH number: 274809 Product name: Loctite(R) 598 Black RTV High Performance Silicone Gasket Maker Page 2 of 7 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Limestone 1317-65-3 30 - 60 Silicone Resin Proprietary 10 - 30 Oximino silane Proprietary 1 - 5 Butanone oxime 96-29-7 1 - 5 Carbon black 1333-86-4 0.1 - 1 Aluminum 7429-90-5 0.1 - 1 Octadecanoic acid 57-11-4 0.1 - 1 Reactive Silane Proprietary 0.1 - 1 White mineral oil (petroleum), highly refined 8042-47-5 0.1 - 1 Quartz (SiO2) 14808-60-7 0 - 0.1 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Move to fresh air in case of accidental inhalation of vapours or decomposition products. If develop and persist, get medical attention. Skin contact: Wipe off paste with paper towel or cloth. Wash with soap and water. If skin irritation persists, call a physician. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If adverse health effects develop seek medical attention. Ingestion: Do not induce vomiting. In case of adverse health effects seek medical advice. See Section 11. 5. FIRE FIGHTING MEASURES Extinguishing media: Foam, dry chemical or carbon dioxide. Special firefighting procedures: Wear self contained breathing apparatus. Prevent inhalation of fumes and gases. Unusual fire or explosion hazards: None Hazardous combustion products: Oxides of silicon. Oxides of carbon. Formaldehyde. Irritating organic vapours. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Do not allow product to enter sewer or waterways. Clean-up methods: Scrape up as much material as possible. Maintain good ventilation for large spills. Place scrap material in a well ventilated area and allow to cure to rubber. Page 603 of 1287 Page 603 of 1287 Page 603 of 1287 Page 603 of 1287 ---PAGE BREAK--- IDH number: 274809 Product name: Loctite(R) 598 Black RTV High Performance Silicone Gasket Maker Page 3 of 7 7. HANDLING AND STORAGE Handling: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Do not handle contact lenses until all sealant has been removed from hands. Residual sealant may transfer to lenses and cause eye irritation. Storage: For safe storage, store between 0 °C (32°F) and 32 °C (89.6 Store in a dry area below 90° F. Keep container closed. For information on product shelf life contact Henkel Customer Service at (800) 243-4874. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Limestone 10 mg/m3 TWA Total dust. 5 mg/m3 PEL Respirable fraction. 15 mg/m3 PEL Total dust. None None Silicone Resin None None None None Oximino silane None None None None Butanone oxime None None 10 ppm (36 mg/m3) TWA (Skin sensitizer) None Carbon black 3 mg/m3 TWA Inhalable fraction. 3.5 mg/m3 PEL None None Aluminum 1 mg/m3 TWA Respirable fraction. 5 mg/m3 PEL (as Al) Respirable dust. 15 mg/m3 PEL (as Al) Total dust. None None Octadecanoic acid 10 mg/m3 TWA None None None Reactive Silane None None None None White mineral oil (petroleum), highly refined 5 mg/m3 TWA Inhalable fraction. 5 mg/m3 TWA mist 5 mg/m3 PEL Mist. None None Quartz (SiO2) 0.025 mg/m3 TWA Respirable fraction. 2.4 TWA Respirable. 0.1 mg/m3 TWA Respirable. 0.3 mg/m3 TWA Total dust. None None Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Respiratory protection: Use a NIOSH approved air-purifying respirator if the potential to exceed established exposure limits exists. Eye/face protection: Safety goggles or safety glasses with side shields. Safety showers and eye wash stations should be available. Skin protection: Use impermeable gloves and protective clothing as necessary to prevent skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Paste Color: Black Odor: Mild Odor threshold: Not available. pH: Not applicable Vapor pressure: < 5 mm hg (20 °C (68°F)) Boiling point/range: Not applicable Page 604 of 1287 Page 604 of 1287 Page 604 of 1287 Page 604 of 1287 ---PAGE BREAK--- IDH number: 274809 Product name: Loctite(R) 598 Black RTV High Performance Silicone Gasket Maker Page 4 of 7 Melting point/ range: Not available. Specific gravity: 1.3 at 20 °C (68°F) Vapor density: Heavier than air. Flash point: > 93 °C 199.4 Tagliabue closed cup Flammable/Explosive limits - lower: Not applicable Flammable/Explosive limits - upper: Not applicable Autoignition temperature: Not available. Evaporation rate: Not available. Solubility in water: Polymerises in presence of water. Partition coefficient (n-octanol/water): Not available. VOC content: 3.31 40.69 g/l Viscosity: Not available. Decomposition temperature: Not available. 10. STABILITY AND REACTIVITY Stability: Stable at normal conditions. Hazardous reactions: None under normal processing. Hazardous decomposition products: Oxides of carbon. Oxides of silicon. Formaldehyde. Methyl ethyl ketoxime formed during cure. Incompatible materials: Oxidizing agents. Acids and bases. Reactivity: Not available. Conditions to avoid: Exposure to moisture. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes Page 605 of 1287 Page 605 of 1287 Page 605 of 1287 Page 605 of 1287 ---PAGE BREAK--- IDH number: 274809 Product name: Loctite(R) 598 Black RTV High Performance Silicone Gasket Maker Page 5 of 7 Potential Health Inhalation: Inhalation of vapors or mists of the product may be irritating to the respiratory system. When heated to temperatures exceeding 300° F (150° C) in the presence of air, silicones may form formaldehyde vapors. Formaldehyde is a potential cancer hazard and a known skin and respiratory sensitizer. Vapors irritate the eyes, nose and throat. Safe handling conditions may be maintained by keeping formaldehyde vapor concentrations below the OSHA permissible limit. The silane is a skin and eye irritant and prolonged contact may cause eye and skin burns. The low concentration makes such overexposure unlikely and minimizes its affect on health and safety. Harmful if inhaled. Skin contact: Causes skin irritation. May cause allergic skin reaction. Eye contact: Causes serious eye irritation. Ingestion: May be harmful if swallowed. Not expected under normal conditions of use. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Limestone None Nuisance dust Silicone Resin None Irritant Oximino silane None Irritant, Allergen Butanone oxime None Allergen, Blood, Central nervous system, Eyes, Irritant, Some evidence of carcinogenicity Carbon black Oral LD50 (RAT) = > 8,000 mg/kg Respiratory, Some evidence of carcinogenicity Aluminum None Central nervous system, Irritant, Lung Octadecanoic acid Oral LD50 (RAT) = 4.6 g/kg Irritant Reactive Silane None Irritant, Allergen White mineral oil (petroleum), highly refined None Irritant Quartz (SiO2) None Immune system, Lung, Some evidence of carcinogenicity Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Limestone No No No Silicone Resin No No No Oximino silane No No No Butanone oxime No No No Carbon black No Group 2B No Aluminum No No No Octadecanoic acid No No No Reactive Silane No No No White mineral oil (petroleum), highly refined No No No Quartz (SiO2) Known To Be Human Carcinogen. Group 1 No 12. ECOLOGICAL INFORMATION Ecological information: Not available. Page 606 of 1287 Page 606 of 1287 Page 606 of 1287 Page 606 of 1287 ---PAGE BREAK--- IDH number: 274809 Product name: Loctite(R) 598 Black RTV High Performance Silicone Gasket Maker Page 6 of 7 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Cured rubber can be incinerated or landfilled following EPA and local regulations. Hazardous waste number: Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None International Air Transportation (ICAO/IATA) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None Water Transportation (IMO/IMDG) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None Exceptions: None 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 Export Notification: None above reporting de minimis CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Immediate Health, Delayed Health CERCLA/SARA Section 313: None above reporting de minimis California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Prepared by: Lou Fabrizio, Regulatory Affairs Specialist Issue date: 08/28/2014 Page 607 of 1287 Page 607 of 1287 Page 607 of 1287 Page 607 of 1287 ---PAGE BREAK--- IDH number: 274809 Product name: Loctite(R) 598 Black RTV High Performance Silicone Gasket Maker Page 7 of 7 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 608 of 1287 Page 608 of 1287 Page 608 of 1287 Page 608 of 1287 ---PAGE BREAK--- Safety Data Sheet Revision Number: 006.0 Issue date: 09/10/2014 IDH number: 229932 Product name: Loctite(R) 7471 Primer T Page 1 of 6 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Loctite(R) 7471 Primer T IDH number: 229932 Product type: Activator Item number: 19268 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-[PHONE REDACTED] (toll free) or 1-[PHONE REDACTED] TRANSPORT EMERGENCY Phone: CHEMTREC 1-[PHONE REDACTED] (toll free) or 1-[PHONE REDACTED] Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW DANGER: HIGHLY FLAMMABLE LIQUID AND VAPOR. MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. HAZARD CLASS HAZARD CATEGORY FLAMMABLE LIQUID 2 SKIN IRRITATION 2 EYE IRRITATION 2A SKIN SENSITIZATION 1 SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3 ASPIRATION HAZARD 1 PICTOGRAM(S) Precautionary Statements Prevention: Keep away from heat, sparks, open flames, hot surfaces - no smoking. Keep container closed. No release into water. Use explosion-proof equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing vapors, mist, or spray. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves, eye protection, and face protection. Response: IF SWALLOWED: Immediately call a physician or poison control center. If on skin (or hair): Take off immediately all contaminated clothing. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. Call a poison control center or physician if you feel unwell. Do NOT induce vomiting. If skin irritation or rash occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. In case of fire: Use foam, dry chemical or carbon dioxide to extinguish. Page 609 of 1287 Page 609 of 1287 Page 609 of 1287 Page 609 of 1287 ---PAGE BREAK--- IDH number: 229932 Product name: Loctite(R) 7471 Primer T Page 2 of 6 Storage: Store in a well-ventilated place. Keep container closed. Store in a well-ventilated place. Keep cool. Store locked up. Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Acetone 67-64-1 60 - 100 2-Propanol 67-63-0 10 - 30 2-Mercaptobenzothiazole 149-30-4 0.1 - 1 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. Wash clothing before reuse. Get medical attention. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Get medical attention. Never give anything by mouth to an unconscious person. See Section 11. 5. FIRE FIGHTING MEASURES Extinguishing media: Foam, dry chemical or carbon dioxide. Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Unusual fire or explosion hazards: Uncontrolled polymerization may occur at high temperatures resulting in explosions or rupture of storage containers. Hazardous combustion products: Oxides of carbon. Oxides of nitrogen. Oxides of sulfur. Irritating organic vapours. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Do not allow product to enter sewer or waterways. Page 610 of 1287 Page 610 of 1287 Page 610 of 1287 Page 610 of 1287 ---PAGE BREAK--- IDH number: 229932 Product name: Loctite(R) 7471 Primer T Page 3 of 6 Clean-up methods: Remove all sources of ignition. Ensure adequate ventilation. Wear appropriate personal protective equipment. Keep unnecessary personnel away. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Store in a partly filled, closed container until disposal. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up. 7. HANDLING AND STORAGE Handling: During use and until all vapors are gone: Keep area ventilated - do not smoke; extinguish all flames, pilot lights, and heaters; turn off stoves, electrical tools and appliances, and any other sources of ignition. Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Wash thoroughly after handling. Refer to Section 8. Storage: For safe storage, store at or below 49 °C (120.2 Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container closed until ready for use. For information on product shelf life contact Henkel Customer Service at (800) 243-4874. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Acetone 750 ppm STEL 500 ppm TWA 1,000 ppm (2,400 mg/m3) PEL None None 2-Propanol 200 ppm TWA 400 ppm STEL 400 ppm (980 mg/m3) PEL None None 2-Mercaptobenzothiazole None None 5 mg/m3 TWA (SKIN) (Skin sensitizer) None Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available. Skin protection: Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. Neoprene, Butyl-rubber, or nitrile- rubber gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Amber to yellowish Odor: Acetone Odor threshold: Not available. pH: Not available. Vapor pressure: 172 mm hg (20 °C (68°F)) Boiling point/range: 56 °C (132.8 no method Melting point/ range: Not available. Specific gravity: 0.7953 Vapor density: Not available. Flash point: -8 °C (17.6 ; Estimated Flammable/Explosive limits - lower: Not available. Flammable/Explosive limits - upper: Not available. Autoignition temperature: Not available. Page 611 of 1287 Page 611 of 1287 Page 611 of 1287 Page 611 of 1287 ---PAGE BREAK--- IDH number: 229932 Product name: Loctite(R) 7471 Primer T Page 4 of 6 Evaporation rate: Not available. Solubility in water: Not available. Partition coefficient (n-octanol/water): Not available. VOC content: 13.3 106 g/l EPA Method 24 Viscosity: Not available. Decomposition temperature: Not available. 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions of storage and use. Hazardous reactions: None under normal processing. Hazardous decomposition products: Oxides of carbon. Oxides of nitrogen. Oxides of sulfur. Irritating organic vapours. Incompatible materials: Acids. Strong oxidizing agents. Reactivity: Not available. Conditions to avoid: Heat, flames, sparks and other sources of ignition. Store away from incompatible materials. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion Potential Health Inhalation: May cause dizziness, incoordination, headache, nausea, and vomiting. Central nervous system effects. Skin contact: Causes skin irritation. May cause allergic skin reaction. Solvent action can dry and defat the skin, causing the skin to crack, leading to dermatitis. Eye contact: Causes serious eye irritation. Ingestion: This product may be fatal if it is swallowed. May cause an aspiration hazard if swallowed. May cause gastrointestinal tract irritation if swallowed. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Acetone Oral LD50 (RABBIT) = 5,340 mg/kg Oral LD50 (RAT) = 5,800 mg/kg Oral LD50 (RAT) = 9,800 mg/kg Dermal LD50 (RABBIT) = 20,000 mg/kg Inhalation LC50 (RAT, 8 h) = 50.1 mg/l Inhalation LC50 (RAT, 4 h) = 76 mg/l Blood, Central nervous system, Irritant, Reproductive 2-Propanol Oral LD50 (RAT) = 5,045 mg/kg Oral LD50 (RABBIT) = 6,410 mg/kg Oral LD50 (RAT) = 4.7 g/kg Oral LD50 (RABBIT) = 8.0 g/kg Oral LD50 (RABBIT) = 5.03 g/kg Dermal LD50 (RABBIT) = 12,800 mg/kg Allergen, Blood, Brain, Central nervous system, Irritant, Kidney, Liver, Spleen 2-Mercaptobenzothiazole None Allergen, Kidney, Some evidence of carcinogenicity Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Acetone No No No 2-Propanol No No No 2-Mercaptobenzothiazole No No No Page 612 of 1287 Page 612 of 1287 Page 612 of 1287 Page 612 of 1287 ---PAGE BREAK--- IDH number: 229932 Product name: Loctite(R) 7471 Primer T Page 5 of 6 12. ECOLOGICAL INFORMATION Ecological information: Not available. 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. Hazardous waste number: D001: Ignitable. This product contains a component or components identified as hazardous under 40 CFR 261.24. D018: Benzene. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Flammable liquids, n.o.s. (Acetone, Isopropanol) Hazard class or division: 3 Identification number: UN 1993 Packing group: II DOT Hazardous Substance(s): Acetone International Air Transportation (ICAO/IATA) Proper shipping name: Flammable liquid, n.o.s. (Acetone, Isopropanol) Hazard class or division: 3 Identification number: UN 1993 Packing group: II Exceptions: (Not more than 500 ml), May Qualify as Consumer Commodity, ID8000 Water Transportation (IMO/IMDG) Proper shipping name: FLAMMABLE LIQUID, N.O.S. (Acetone, Isopropanol) Hazard class or division: 3 Identification number: UN 1993 Packing group: II Exceptions: Limited quantity (Not more than 1 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 Export Notification: None above reporting de minimis CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Delayed Health, Immediate Health, Fire CERCLA/SARA Section 313: None above reporting de minimis CERCLA Reportable quantity: Acetone (CAS# 67-64-1) 5,000 lbs. (2,270 kg) 2-Propanol (CAS# 67-63-0) 100 lbs. (45.4 kg) California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. Page 613 of 1287 Page 613 of 1287 Page 613 of 1287 Page 613 of 1287 ---PAGE BREAK--- IDH number: 229932 Product name: Loctite(R) 7471 Primer T Page 6 of 6 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Prepared by: Sheila Gines, Regulatory Affairs Specialist Issue date: 09/10/2014 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 614 of 1287 Page 614 of 1287 Page 614 of 1287 Page 614 of 1287 ---PAGE BREAK--- Material Safety Data Sheet Revision Number: 004.4 Issue date: 09/03/2014 IDH number: 234196 Product name: LOCTITE® COPPER-BASED ANTI-SEIZE t LUBRICANT Page 1 of 6 1. PRODUCT AND COMPANY IDENTIFICATION Product name: LOCTITE® COPPER-BASED ANTI- SEIZE t LUBRICANT IDH number: 234196 Item number: 51003 Region: Canada Company address: Contact information: Henkel Corporation 2515 Meadowpine Boulevard Mississauga, Ontario L5N 6C3 Telephone: [PHONE REDACTED] MEDICAL EMERGENCY Phone: Poison Control Center 1-[PHONE REDACTED] (toll free) or 1-[PHONE REDACTED] TRANSPORT EMERGENCY Phone: CHEMTREC 1-[PHONE REDACTED] (toll free) or 1-[PHONE REDACTED] Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Physical state: Aerosol WHMIS hazard class: A, B.5, D.2.B Color: Copper Odor: Solvent DANGER: EXTREMELY FLAMMABLE. CONTENTS UNDER PRESSURE. HARMFUL IF INHALED. MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. Relevant routes of exposure: Skin, Inhalation, Eyes Potential Health Effects Inhalation: May cause irritation to nose and throat. Central nervous system depression, including dizziness, drowsiness, fatigue, nausea, headache, unconsciousness. Extreme overexposure may result in unconsciousness and possibly death. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Inhalation of copper fumes may result in metal fume fever. include metallic taste, discoloration of skin or hair. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Skin contact: May cause irritation due to defatting of the skin. Eye contact: Direct spray or vapors will irritate and may harm eyes. Ingestion: Not expected under normal conditions of use. Existing conditions aggravated by exposure: Eye, skin and respiratory disorders. See Section 11 for additional toxicological information. Page 615 of 1287 Page 615 of 1287 Page 615 of 1287 Page 615 of 1287 ---PAGE BREAK--- IDH number: 234196 Product name: LOCTITE® COPPER-BASED ANTI-SEIZE t LUBRICANT Page 2 of 6 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components CAS NUMBER % n-Heptane 142-82-5 30 - 60 Copper 7440-50-8 5 - 10 Propane 74-98-6 5 - 10 Butane 106-97-8 5 - 10 Graphite 7782-42-5 5 - 10 Distillates (petroleum), hydrotreated heavy naphthenic 64742-52-5 1 - 5 Petroleum distillates, hydrotreated, light naphthenic 64742-53-6 1 - 5 Calcium dihydroxide 1305-62-0 1 - 5 Quartz (SiO2) 14808-60-7 0.1 - 1 4. FIRST AID MEASURES Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Skin contact: Remove contaminated clothing and footwear. Wash with soap and water. If develop and persist, get medical attention. Wash clothing before reuse. Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. Ingestion: Do not induce vomiting. Keep individual calm. Never give anything by mouth to an unconscious person. Get medical attention. 5. FIRE FIGHTING MEASURES Flash point: < -18 °C 0.4 ; Values referring to propellant Flashback: Not evaluated. Autoignition temperature: Not available. Flammable/Explosive limits - lower: Not available. Flammable/Explosive limits - upper: Not available. Extinguishing media: Foam, dry chemical or carbon dioxide. Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Water spray may be ineffective. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. If water is used, fog nozzles are preferable. Unusual fire or explosion hazards: Contents under pressure. Do not handle or store near an open flame, heat or other sources of ignition. Do not puncture or incinerate pressurized containers. Exposure to temperatures above 49°C (120°F) may cause container to burst. Hazardous combustion products: Oxides of carbon. Sensitivity to Mechanical Impact: Not available. Sensitivity to static discharge: Not available. Page 616 of 1287 Page 616 of 1287 Page 616 of 1287 Page 616 of 1287 ---PAGE BREAK--- IDH number: 234196 Product name: LOCTITE® COPPER-BASED ANTI-SEIZE t LUBRICANT Page 3 of 6 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Do not allow product to enter sewer or waterways. Clean-up methods: Ensure adequate ventilation. Remove all sources of ignition. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Store in a closed container until ready for disposal. 7. HANDLING AND STORAGE Handling: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Keep away from heat, spark and flame. Vapors will accumulate readily and may ignite explosively. Refer to Section 8. Storage: Keep in a cool, well ventilated area. Store away from ignition sources. Do not puncture, incinerate, or expose to temperatures above 48.9 °C (120 Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. For information on product shelf life contact Henkel Canada Customer Service at [PHONE REDACTED]. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Page 617 of 1287 Page 617 of 1287 Page 617 of 1287 Page 617 of 1287 ---PAGE BREAK--- IDH number: 234196 Product name: LOCTITE® COPPER-BASED ANTI-SEIZE t LUBRICANT Page 4 of 6 Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER n-Heptane 400 ppm TWA 500 ppm STEL 500 ppm (2,000 mg/m3) PEL None None Copper 0.2 mg/m3 TWA (as Cu) Fume. 1 mg/m3 TWA (as Cu) Dust and mist. 1 mg/m3 PEL (as Cu) Dust and mist. 0.1 mg/m3 PEL (as Cu) Fume. None None Propane Included in the regulation but with no data values. See regulation for further details 1,000 ppm (1,800 mg/m3) PEL None None Butane 1,000 ppm STEL None None None Graphite 2 mg/m3 TWA Respirable fraction. 5 mg/m3 PEL Respirable fraction. 15 mg/m3 PEL Total dust. 15 TWA None None Distillates (petroleum), hydrotreated heavy naphthenic 5 mg/m3 TWA mist 10 mg/m3 STEL mist 5 mg/m3 TWA mist 500 ppm (2,000 mg/m3) PEL 5 mg/m3 PEL Mist. None None Petroleum distillates, hydrotreated, light naphthenic None 500 ppm (2,000 mg/m3) PEL 5 mg/m3 PEL Mist. None None Calcium dihydroxide 5 mg/m3 TWA 5 mg/m3 PEL Respirable fraction. 15 mg/m3 PEL Total dust. None None Quartz (SiO2) 0.025 mg/m3 TWA Respirable fraction. 2.4 TWA Respirable. 0.1 mg/m3 TWA Respirable. 0.3 mg/m3 TWA Total dust. None None Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Respiratory protection: If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH. Observe OSHA regulations for respirator use (29 CFR 1910.134). Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available. Skin protection: Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. Neoprene or oil resistant gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Aerosol Color: Copper Odor: Solvent Odor threshold: Not available. pH: Not available. Vapor pressure: Not available. Boiling point/range: Not available. Melting point/ range: Not available. Specific gravity: Not available. Vapor density: Not available. Flash point: < -18 °C 0.4 ; Values referring to propellant Flashback: Not evaluated. Flammable/Explosive limits - lower: Not available. Flammable/Explosive limits - upper: Not available. Page 618 of 1287 Page 618 of 1287 Page 618 of 1287 Page 618 of 1287 ---PAGE BREAK--- IDH number: 234196 Product name: LOCTITE® COPPER-BASED ANTI-SEIZE t LUBRICANT Page 5 of 6 Autoignition temperature: Not available. Evaporation rate: Not available. Solubility in water: Not available. Partition coefficient (n-octanol/water): Not available. VOC content: 65 650 g/l 10. STABILITY AND REACTIVITY Stability: Stable under recommended storage conditions. Hazardous reactions: Will not occur. Hazardous decomposition products: Oxides of carbon. Incompatible materials: Strong oxidizing agents. Conditions to avoid: Do not puncture, incinerate, or expose to temperatures above 48.9 °C (120 Keep away from heat, ignition sources and incompatible materials. 11. TOXICOLOGICAL INFORMATION Toxicologically synergistic products: Not available. Refer to the following for Irritancy of Product, Sensitization to Product, Carcinogenicity, Reproductive Toxicity, Teratogenicity, and Mutagenicity. Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) ACGIH Carcinogen n-Heptane No No No No Copper No No No No Propane No No No No Butane No No No No Graphite No No No No Distillates (petroleum), hydrotreated heavy naphthenic No No No No Petroleum distillates, hydrotreated, light naphthenic No No No No Calcium dihydroxide No No No No Quartz (SiO2) Known To Be Human Carcinogen. Group 1 No Group A2 Hazardous components LD50s and LC50s Health Effects/Target Organs n-Heptane Inhalation LC50 (RAT, 4 h) = 103 mg/l Central nervous system, Irritant Copper None Allergen, Blood, Central nervous system, Developmental, Gastrointestinal, Immune system, Irritant, Kidney, Liver, Mutagen, Sensory, Skin Propane Inhalation LC50 (RAT, 15 min) = > 1,442.847 mg/l Inhalation LC50 (RAT, 15 min) = > 1,464 mg/l Cardiac, Central nervous system, Irritant Butane Inhalation LC50 (RAT, 4 h) = 658 mg/l Cardiac, Central nervous system, Irritant Graphite None Lung Distillates (petroleum), hydrotreated heavy naphthenic None Irritant Petroleum distillates, hydrotreated, light naphthenic None Irritant Calcium dihydroxide Oral LD50 (RAT) = 7,340 mg/kg Irritant, Corrosive Quartz (SiO2) None Immune system, Lung, Some evidence of carcinogenicity Page 619 of 1287 Page 619 of 1287 Page 619 of 1287 Page 619 of 1287 ---PAGE BREAK--- IDH number: 234196 Product name: LOCTITE® COPPER-BASED ANTI-SEIZE t LUBRICANT Page 6 of 6 12. ECOLOGICAL INFORMATION Ecological information: Not available. 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Do not incinerate. Depressurize cans. Follow all local, state, federal and provincial regulations for disposal. 14. TRANSPORT INFORMATION Canada Transportation of Dangerous Goods - Ground Proper shipping name: AEROSOLS Hazard class or division: 2.1 Identification number: UN 1950 Packing group: None International Air Transportation (ICAO/IATA) Proper shipping name: Aerosols, flammable Hazard class or division: 2.1 Identification number: UN 1950 Packing group: None Water Transportation (IMO/IMDG) Proper shipping name: AEROSOLS (n-Heptane) Hazard class or division: 2.1 Identification number: UN 1950 Packing group: None Marine pollutant: n-Heptane 15. REGULATORY INFORMATION Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. United States Regulatory Information TSCA 8 Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: 4,6,7,8,10,15 This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR), and the MSDS contains all the information required by the CPR. Prepared by: Catherine Bimler, Regulatory Affairs Specialist DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 620 of 1287 Page 620 of 1287 Page 620 of 1287 Page 620 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Cortec, Spray Technologies Division 1300 South River Street Spooner, WI 54801 PHONE: [PHONE REDACTED] TOLL FREE 1-[PHONE REDACTED] FAX: [PHONE REDACTED] EMERGENCY PHONE NO.: (FOR SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT): 1-[PHONE REDACTED] * * * * * * * * * * * * * * * * * RIP-4 37004* * * * * * * * * * * * * * * * SECTION I - PRODUCT IDENTIFICATION PRODUCT NAME: RIP-4 Outdoor Rust Preventative (aerosol) PRODUCT DESCRIPTION: This premier quality hydrocarbon based corrosion preventive product provides a heavy “wax- type” barrier coating for exceptional, long-term protection of outdoor equipment under the most severe of climactic conditions. It is an excellent choice for use in salt water and/or fresh water marine applications as it protects exceptionally well against salt sprays and will outlast all asphalt-type undercoating products. Performs extremely well when used to undercoat auto and truck bodies and is highly desirable when used in all other applications where use of asphalt based undercoating products is objectionable. Extremely flammable – not for use on energized equipment! RESTRICTIONS: Non-restricted. SECTION II - HAZARDOUS INGREDIENTS INGREDIENT NAME(S) CAS# OCCUPATIONAL EXPOSURE LIMITS TLV OR PEL ORAL LD-50 Aliphatic Mineral Spirits Heptane Propane Isobutane 64742-88-7 142-82-5 74-98-6 75-28-5 525 mg/m3 400 ppm 1000 ppm 800 ppm N.E. N.E. N.E. N.E Carcinogenic: OSHA = No NTP = No IARC = No SECTION III - PHYSICAL DATA APPEARANCE: Amber to brown color liquid ODOR: Mild hydrocarbon odor BOILING POINT: 105 Degrees F. (40.5 degrees VAPOR DENSITY (Air = 3 VAPOR PRESSURE: 2070 mmHg SOLUBILITY IN WATER: Nil SPECIFIC GRAVITY: 1.0 EVAPORATION RATE (Ether = 0.5 SECTION IV - FIRE AND EXPLOSION DATA HMIS RATING: Health – 1, Fire – 3, Reactivity - 0 FLASH POINT: 120 degrees F. (49 degrees TCC method FLAMMABLE LIMITS: LEL: N.E. UEL: N.E. EXTINGUISHING MEDIA: Dry chemical, foam CO2, or water fog. UNUSUAL FIRE AND EXPLOSION HAZARDS: Spray is extremely flammable; flammable vapors, heavier than air, may travel considerable distances to ignition sources to flash or explode. SPECIAL FIRE FIGHTING PROCEDURES: Firefighters should wear self-contained breathing apparatus and protective clothing. Cool fire-exposed aerosols with water fog. SECTION V - HEALTH HAZARD DATA EMERGENCY AND FIRST AID PROCEDURES: Eye Contact: Flush eyes with water for at least 15 minutes. Consult a physician. Skin Contact: Wash skin with soap and water. If irritation develops or persists, consult a physician. Inhalation: Remove victim to fresh air, administer oxygen if necessary. If victim has stopped breathing begin CPR. Get immediate medical attention. Ingestion: Consult a physician immediately. DO NOT induce vomiting unless physician directed. If spontaneous vomiting occurs, keep victim’s head below hips to prevent aspiration into the lungs. Get immediate medical attention. Product contains petroleum distillates which are harmful or fatal if swallowed. MEDICAL CONDITIONS PRONE TO AGGRAVATION BY EXPOSURE: Pre-existing skin conditions, liver conditions or kidney conditions. PRIMARY ROUTES OF ENTRY: Inhalation, skin and eye contact. HEALTH HAZARDS (acute and chronic) / EFFECTS OF OVEREXPOSURE: Excessive, acute overexposures by inhalation of vapor concentrations may cause dizziness, weakness, fatigue, nausea, headache, unconsciousness, or in extreme overexposures, Effects of chronic, long-term exposures are not well defined. SECTION VI - REACTIVITY DATA STABILITY: Stable under normal use and storage conditions. HAZARDOUS POLYMERIZATION: Will not occur. HAZARDOUS DECOMPOSITION PRODUCTS (under fire conditions): Oxides of carbon, oxides of sulfur. INCOMPATIBILITY: Avoid strong oxidizing materials and strong alkalies. CONDITIONS TO AVOID: Avoid heat, flame, all potential ignition sources. SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove ignition sources, ventilate area. Take up spill on an inert absorbent material and place into a DOT approved closed-top waste container for disposal. Prevent spilled material from entering sewers or drains. WASTE DISPOSAL: Dispose of waste or unwanted material in accordance with existing Federal, State and Local environmental regulations. May be reclaimed or incinerated by permitted facilities. SECTION VIII - SAFE HANDLING AND USE INFORMATION RESPIRATORY PROTECTION: Not normally required; mechanical (general) ventilation is generally adequate. Wear a NIOSH approved organic respirator for nuisance-level vapors, a positive pressure, air-supplied respirator in high vapor concentrations or oxygen-deficient atmospheres. PROTECTIVE GLOVES: Chemical resistant / oil impervious gloves. EYE PROTECTION: Safety glasses, splash goggles, face shield. OTHER PROTECTIVE EQUIPMENT: Eye wash station. SECTION IX - SPECIAL PRECAUTIONS AND STORAGE DATA PRECAUTIONS TO BE TAKEN IN HANDLING: Avoid eye and skin contact. Avoid excessive inhalation of vapors. Avoid mist formations. Use in a well-ventilated environment. Intentional inhalation of contents is harmful and may be fatal. (continued on page 2) Page 621 of 1287 Page 621 of 1287 Page 621 of 1287 Page 621 of 1287 ---PAGE BREAK--- Page 2 RIP-4 Outdoor Rust Preventative 37004 PRECAUTIONS TO BE TAKEN IN STORING: Store containers below 120ºF (48ºC), away from heat or ignition sources, open flame, out of direct sunlight. SECTION X – SHIPPING DATA U.N. / N.A. NUMBER: UN1950 DOT/IATA SHIPPING NAME: Aerosols, flammable, (each not exceeding 1L capacity) DOT/IATA HAZARD CLASS: 2.1 DOT/IATA REQUIRED LABELS: 2, FLAMMABLE GAS (air shipment only) DOT EXCEPTION: See Code 49 Section 172.101, column (8A). Section 173.306(h) permits “limited quantity” materials (inner packagiongs which do not exceed 1L capacty / 61 cubic inches and for which internal pressures do not exceed 180 psig at 130 degrees meeting Section 171.8 definition of “Consumer commodity” to be renamed “Consumer commodity”, reclassed as ORM-D when shipped via ground mode, domestically. FREIGHT CLASS: NMFC 50234, Sub 2 LTL: 77.5 TL: 35 MW: 36 T.S.C.A. STATUS: All components listed PREPARED BY: Roger Hanson DATE PREPARED: 02-25-00 SUPERCEEDS: 01-10-00 DISCLAIMER: This information is furnished without warranty, expressed, or implied, except that it is accurate to the best knowledge of Cortec, Spray Technologies Division. The data on this sheet relates only to the specific material designated herein. Cortec, Spray Technologies Division assumes no legal responsibility for use or reliance upon this data. N.E. = NOT ESTABLISHED N.A. = NOT APPLICABLE Page 622 of 1287 Page 622 of 1287 Page 622 of 1287 Page 622 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Product identifier LPS® Cold Galvanize Other means of identification Part Number 00516 Recommended use A zinc rich industrial maintenance primer designed for rust and corrosion protection. Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Manufacturer Company name LPS Laboratories, a division of Illinois Tool Works, Inc. Address 4647 Hugh Howell Rd. Tucker, GA 30084 Country Tel: +1 [PHONE REDACTED] In Case of Emergency 1-[PHONE REDACTED] (inside U.S.) +001 [PHONE REDACTED] (outside U.S.) Website www.lpslabs.com E-mail [EMAIL REDACTED] 2. Hazard(s) identification Category 1 Flammable aerosols Physical hazards Category 4 Acute toxicity, dermal Health hazards Category 4 Acute toxicity, inhalation Category 2 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Carcinogenicity Category 3 narcotic effects Specific target organ toxicity, single exposure Not classified. Environmental hazards Not classified. OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause drowsiness or dizziness. Suspected of causing cancer. Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF exposed or concerned: Get medical advice/attention. Call a POISON CENTER or doctor/physician if you feel unwell. Specific measures (see this label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Wash contaminated clothing before reuse. Wash with plenty of soap and water. Storage Keep container closed. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) None known. 1 / 11 Material name: LPS® Cold Galvanize 573 Version 02 Revision date: 02-03-2014 Issue date: 03-07-2013 SDS US Page 623 of 1287 Page 623 of 1287 Page 623 of 1287 Page 623 of 1287 ---PAGE BREAK--- Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number % Chemical name Common name and synonyms 7440-66-6 Metallic Zinc 30 - < 40 68476-86-8 Petroleum Gases, Liquiified, Sweetened 20 - < 30 67-64-1 Acetone 10 - < 20 1330-20-7 Xylene 5 - < 10 100-41-4 1 - < 3 8052-41-3 Mineral Spirits Regular Stoddard Solvent Other components below reportable levels 10 - < 20 1 - < 3 CLP: Regulation No. 1272/2008. DSD: Directive 67/548/EEC. PBT: persistent, bioaccumulative and toxic substance. vPvB: very persistent and very bioaccumulative substance. This substance has been assigned Community workplace exposure limit(s). Composition comments The full text for all R- and H-phrases is displayed in section 16. 4. First-aid measures Inhalation If gas/fume/vapor/dust/mist from the material is inhaled, remove the affected person immediately to fresh air. If not breathing, give artificial respiration. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Get medical attention immediately. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Get medical attention if occur. Eye contact Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Get medical attention immediately. Ingestion Call a physician or poison control center immediately. Only induce vomiting at the instruction of medical personnel. Never give anything by mouth to an unconscious person. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Most important acute and delayed Irritant effects. may include stinging, tearing, redness, swelling, and blurred vision. Defatting of the skin. Rash. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. of overexposure can include shortness of breath, drowsiness, headaches, confusion, decreased coordination, visual disturbances and vomiting, and are reversible if exposure is stopped. Shortness of breath. Discomfort in the chest. Narcosis. Behavioral changes. Decrease in motor functions. Prolonged exposure may cause chronic effects. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat may be delayed. Keep victim under observation. General information In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Powder. Alcohol resistant foam. Dry sand. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical By heating and fire, harmful vapors/gases may be formed. In contact with water releases flammable gases which may ignite spontaneously. Contents under pressure. Container may explode in heat of fire. Special protective equipment and precautions for firefighters Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Firefighters should wear full protective clothing including self contained breathing apparatus. Structural firefighters protective clothing will only provide limited protection. 2 / 11 Material name: LPS® Cold Galvanize 573 Version 02 Revision date: 02-03-2014 Issue date: 03-07-2013 SDS US Page 624 of 1287 Page 624 of 1287 Page 624 of 1287 Page 624 of 1287 ---PAGE BREAK--- Fire-fighting equipment/instructions In case of fire and/or explosion do not breathe fumes. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Use standard firefighting procedures and consider the hazards of other involved materials. If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also consider initial evacuation for 800 meters (1/2 mile) in all directions. ALWAYS stay away from tanks engulfed in flame. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. Use water spray to cool unopened containers. Move containers from fire area if you can do so without risk. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Water runoff can cause environmental damage. Specific methods In the event of fire and/or explosion do not breathe fumes. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Move container from fire area if it can be done without risk. Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards Extremely flammable aerosol. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Local authorities should be advised if significant spillages cannot be contained. Consider initial downwind evacuation for at least 500 meters (1/3 mile). ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Immediately evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire. Ventilate closed spaces before entering them. Avoid inhalation of vapors or mists. Methods and materials for containment and cleaning up ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. The product is immiscible with water and will sediment in water systems. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb spillage with non-combustible, absorbent material. Prevent entry into waterways, sewer, basements or confined areas. Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Clean surface thoroughly to remove residual contamination. Never return spills in original containers for re-use. Environmental precautions Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Avoid release to the environment. Refer to special instructions/safety data sheets. Do not contaminate water. 7. Handling and storage Precautions for safe handling Do not handle until all safety precautions have been read and understood. Vapors may form explosive mixtures with air. May be ignited by open flame. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. DO NOT handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Avoid exposure - obtain special instructions before use. Do not breathe mist or vapor. Do not get this material in contact with eyes. Do not taste or swallow. Avoid contact with skin. Avoid prolonged exposure. Avoid contact with clothing. Use only in area provided with appropriate exhaust ventilation. Wear personal protective equipment. When using, do not eat, drink or smoke. Wash thoroughly after handling. Avoid release to the environment. Do not empty into drains. Use appropriate container to avoid environmental contamination. Conditions for safe storage, including any incompatibilities Level 2 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Avoid exposure - obtain special instructions before use. Store locked up. Do not handle or store near an open flame, heat or other sources of ignition. Store in a cool, dry place out of direct sunlight. Store in a well-ventilated place. Store in a closed container away from incompatible materials. Keep in an area equipped with sprinklers. Keep away from food, drink and animal feedingstuffs. Keep out of the reach of children. Use appropriate container to avoid environmental contamination. 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Type PEL 2400 mg/m3 Acetone (CAS 67-64-1) 3 / 11 Material name: LPS® Cold Galvanize 573 Version 02 Revision date: 02-03-2014 Issue date: 03-07-2013 SDS US Page 625 of 1287 Page 625 of 1287 Page 625 of 1287 Page 625 of 1287 ---PAGE BREAK--- US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Type 1000 ppm PEL 435 mg/m3 (CAS 100-41-4) 100 ppm PEL 2900 mg/m3 Mineral Spirits Regular Stoddard Solvent (CAS 8052-41-3) 500 ppm PEL 435 mg/m3 Xylene (CAS 1330-20-7) 100 ppm US. ACGIH Threshold Limit Values Value Components Type STEL 750 ppm Acetone (CAS 67-64-1) TWA 500 ppm TWA 20 ppm (CAS 100-41-4) TWA 100 ppm Mineral Spirits Regular Stoddard Solvent (CAS 8052-41-3) STEL 150 ppm Xylene (CAS 1330-20-7) TWA 100 ppm US. NIOSH: Pocket Guide to Chemical Hazards Value Components Type TWA 590 mg/m3 Acetone (CAS 67-64-1) 250 ppm STEL 545 mg/m3 (CAS 100-41-4) 125 ppm TWA 435 mg/m3 100 ppm Ceiling 1800 mg/m3 Mineral Spirits Regular Stoddard Solvent (CAS 8052-41-3) TWA 350 mg/m3 Biological limit values ACGIH Biological Exposure Indices Value Components Determinant Specimen Sampling Time 50 mg/l Acetone Urine * Acetone (CAS 67-64-1) 0.7 g/g Sum of mandelic acid and acid Creatinine in urine * (CAS 100-41-4) 1.5 g/g acids Creatinine in urine * Xylene (CAS 1330-20-7) * - For sampling details, please see the source document. Appropriate engineering controls Provide adequate general and local exhaust ventilation. Provide eyewash station. Individual protection measures, such as personal protective equipment Eye/face protection Do not get in eyes. Wear safety glasses with side shields (or goggles). Eye wash fountain is recommended. Skin protection Hand protection Chemical resistant gloves are recommended. Other Avoid contact with the skin. Chemical resistant gloves. Wear appropriate chemical resistant clothing. Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Thermal hazards None known. 4 / 11 Material name: LPS® Cold Galvanize 573 Version 02 Revision date: 02-03-2014 Issue date: 03-07-2013 SDS US Page 626 of 1287 Page 626 of 1287 Page 626 of 1287 Page 626 of 1287 ---PAGE BREAK--- General hygiene considerations When using, do not eat, drink or smoke. Do not get in eyes. Do not get this material on clothing. Avoid contact with skin. Wash hands before breaks and immediately after handling the product. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Appearance Liquid. Physical state Gas. Form Aerosol. Color Light grey. Opaque. Odor Aromatic. Hydrocarbon-like. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range Not available. Flash point < 73.4 °F 23.0 Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Explosive limit - lower 0.9 Explosive limit - upper 10.5 Vapor pressure > 1 kPa @ 25°C Vapor density > 1 (air = 1) Relative density Not available. Solubility(ies) Solubility (water) Insoluble in water Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity 3000 - 4500 cSt Other information Density 14.71 g/cm3 Heat of combustion 20 - 30 kJ/g Percent volatile 55.4 % Specific gravity 1.76 @ 25°C VOC (Weight 0.76 MIR per U.S. State and Federal Aerosol Coating Regulations 10. Stability and reactivity Reactivity Not available. Chemical stability Risk of ignition. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid Heat, flames and sparks. Avoid temperatures exceeding the flash point. Contact with water liberates flammable gas. Incompatible materials Strong oxidizing agents. Hazardous decomposition products Irritating and/or toxic fumes and gases may be emitted upon the products decomposition. 11. Toxicological information Information on likely routes of exposure Ingestion Based on available data, the classification criteria are not met. Inhalation Harmful if inhaled. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Skin contact Harmful in contact with skin. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Eye contact Causes serious eye irritation. 5 / 11 Material name: LPS® Cold Galvanize 573 Version 02 Revision date: 02-03-2014 Issue date: 03-07-2013 SDS US Page 627 of 1287 Page 627 of 1287 Page 627 of 1287 Page 627 of 1287 ---PAGE BREAK--- related to the physical, chemical and toxicological characteristics Discomfort in the chest. Shortness of breath. Narcosis. Coughing. Edema. Liver enlargement. Jaundice. Proteinuria. Behavioral changes. Decrease in motor functions. Irritant effects. Irritation of eyes and mucous membranes. of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Information on toxicological effects Acute toxicity Harmful if inhaled. Harmful in contact with skin. Test Results Components Species Acetone (CAS 67-64-1) LD50 Rabbit Dermal Acute > 15800 mg/kg 20 ml/kg LC50 Rat Inhalation 55700 ppm 76 mg/l, 4 Hours 50.1 mg/l 50.1 mg/l, 8 Hours LD50 Mouse Oral 3000 mg/kg Rabbit 5340 mg/kg Rat 5800 mg/kg 2.2 ml/kg LD50 Mouse Other 1297 mg/kg Rat 5500 mg/kg (CAS 100-41-4) LD50 Rabbit Dermal Acute 17800 mg/kg 17.8 ml/kg LC50 Rat Inhalation 4000 ppm LD50 Rat Oral 3500 mg/kg 3.5 g/kg LD50 Mouse Other 2272 mg/kg Metallic Zinc (CAS 7440-66-6) LC50 Rat Inhalation Acute > 5410 mg/m3 LD50 Rat Oral 630 mg/kg Petroleum Gases, Liquiified, Sweetened (CAS 68476-86-8) LC100 Cat Inhalation Acute 90 % LC50 Mouse 1237 mg/l 52.04 % Rat > 13023 ppm 1355 mg/l 6 / 11 Material name: LPS® Cold Galvanize 573 Version 02 Revision date: 02-03-2014 Issue date: 03-07-2013 SDS US Page 628 of 1287 Page 628 of 1287 Page 628 of 1287 Page 628 of 1287 ---PAGE BREAK--- Test Results Components Species Xylene (CAS 1330-20-7) LD50 Rabbit Dermal Acute > 5000 ml/kg 12126 mg/kg LC50 Mouse Inhalation 3907 mg/l, 6 Hours Rat 6350 mg/l, 4 Hours 5922 ppm LCL0 Rat 8000 mg/l, 4 Hours LD50 Mouse Oral 1590 mg/kg Rat 3523 - 8600 mg/kg 10 ml/kg * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye irritation Causes serious eye irritation. Respiratory or skin sensitization Respiratory sensitization Based on available data, the classification criteria are not met. Skin sensitization Based on available data, the classification criteria are not met. Germ cell mutagenicity Due to lack of data the classification is not possible. Carcinogenicity Suspected of causing cancer. ACGIH Carcinogens Acetone (CAS 67-64-1) Not classifiable as a human carcinogen. A4 (CAS 100-41-4) Confirmed animal carcinogen with unknown relevance to humans. A3 Xylene (CAS 1330-20-7) Not classifiable as a human carcinogen. A4 IARC Monographs. Overall Evaluation of Carcinogenicity (CAS 100-41-4) 2B Possibly carcinogenic to humans. Xylene (CAS 1330-20-7) 3 Not classifiable as to carcinogenicity to humans. Reproductive toxicity Based on available data, the classification criteria are not met. Specific target organ toxicity - single exposure Narcotic effects. Specific target organ toxicity - repeated exposure Based on available data, the classification criteria are not met. Aspiration hazard Based on available data, the classification criteria are not met. Chronic effects Prolonged exposure may cause chronic effects. Further information may be delayed. 12. Ecological information Ecotoxicity Very toxic to aquatic life with long lasting effects. Components Test Results Species Acetone (CAS 67-64-1) Aquatic EC50 Crustacea 10294 - 17704 mg/l, 48 hours Water flea (Daphnia magna) LC50 Fish 4740 - 6330 mg/l, 96 hours Rainbow trout,donaldson trout mykiss) (CAS 100-41-4) Aquatic EC50 Crustacea 1.37 - 4.4 mg/l, 48 hours Water flea (Daphnia magna) LC50 Fish 7.5 - 11 mg/l, 96 hours Fathead minnow (Pimephales promelas) 7 / 11 Material name: LPS® Cold Galvanize 573 Version 02 Revision date: 02-03-2014 Issue date: 03-07-2013 SDS US Page 629 of 1287 Page 629 of 1287 Page 629 of 1287 Page 629 of 1287 ---PAGE BREAK--- Components Test Results Species Metallic Zinc (CAS 7440-66-6) Aquatic EC50 Crustacea 2.8 mg/l, 48 hours Water flea (Daphnia magna) LC50 Fish 0.56 mg/l, 96 hours Rainbow trout,donaldson trout mykiss) Xylene (CAS 1330-20-7) Aquatic LC50 Fish 7.711 - 9.591 mg/l, 96 hours Bluegill (Lepomis macrochirus) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential Not available. Partition coefficient n-octanol / water (log Kow) Acetone -0.24 3.15 Mineral Spirits Regular Stoddard Solvent 3.16 - 7.15 Xylene 3.12 - 3.2 Mobility in soil Not available. Other adverse effects Not available. 13. Disposal considerations Disposal instructions This material and its container must be disposed of as hazardous waste. Incinerate the material under controlled conditions in an approved incinerator. Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities. Do not incinerate sealed containers. Do not discharge into drains, water courses or onto the ground. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. After recovery of solvent dispose of residue as hazardous waste. Dispose of contents/container in accordance with local/regional/national/international regulations. When your own wastewater treatment plant is not available, collect entire waste and then charge to a licensed industrial waste management professional with manifests for industrial waste. Hazardous waste code D001: Waste Flammable material with a flash point <140 F D003: Waste Reactive material Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Avoid discharge into water courses or onto the ground. Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN1950 UN number Aerosols, flammable UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk 2.1 Label(s) Not applicable. Packing group Not available. Special precautions for user N82 Special provisions 306 Packaging exceptions None Packaging non bulk None Packaging bulk IATA UN1950 UN number Aerosols, flammable UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk 2.1 Label(s) Not applicable. Packing group Yes Environmental hazards Not available. Special precautions for user 8 / 11 Material name: LPS® Cold Galvanize 573 Version 02 Revision date: 02-03-2014 Issue date: 03-07-2013 SDS US Page 630 of 1287 Page 630 of 1287 Page 630 of 1287 Page 630 of 1287 ---PAGE BREAK--- Allowed. Passenger and cargo aircraft Other information Allowed. Cargo aircraft only IMDG UN1950 UN number Aerosols, flammable, MARINE POLLUTANT UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk 2.1 Label(s) Not applicable. Packing group Yes Marine pollutant Environmental hazards Not available. EmS Not available. Special precautions for user Not available. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT IATA; IMDG Marine pollutant 15. Regulatory information US federal regulations All components of this product are TSCA inventory listed and/or are exempt. All components of this product are DSL inventory listed and/or are exempt. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1) LISTED (CAS 100-41-4) LISTED Metallic Zinc (CAS 7440-66-6) LISTED Xylene (CAS 1330-20-7) LISTED 9 / 11 Material name: LPS® Cold Galvanize 573 Version 02 Revision date: 02-03-2014 Issue date: 03-07-2013 SDS US Page 631 of 1287 Page 631 of 1287 Page 631 of 1287 Page 631 of 1287 ---PAGE BREAK--- US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. SARA 304 Emergency release notification Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - Yes SARA 302 Extremely hazardous substance No SARA 311/312 Hazardous chemical Yes SARA 313 (TRI reporting) Chemical name CAS number % by wt. Metallic Zinc 7440-66-6 30 - < 40 Xylene 1330-20-7 5 - < 10 100-41-4 1 - < 3 Propylene Oxide 75-56-9 < 0.1 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List (CAS 100-41-4) Xylene (CAS 1330-20-7) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1) 6532 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1) 35 % weight/volumn DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1) 6532 US state regulations WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US. Massachusetts RTK - Substance List Acetone (CAS 67-64-1) (CAS 100-41-4) Metallic Zinc (CAS 7440-66-6) Mineral Spirits Regular Stoddard Solvent (CAS 8052-41-3) Xylene (CAS 1330-20-7) US. New Jersey Worker and Community Right-to-Know Act (CAS 100-41-4) 500 lbs Metallic Zinc (CAS 7440-66-6) 500 lbs Xylene (CAS 1330-20-7) 500 lbs US. RTK - Hazardous Substances Acetone (CAS 67-64-1) (CAS 100-41-4) Metallic Zinc (CAS 7440-66-6) Mineral Spirits Regular Stoddard Solvent (CAS 8052-41-3) Xylene (CAS 1330-20-7) US. Rhode Island RTK Acetone (CAS 67-64-1) (CAS 100-41-4) Metallic Zinc (CAS 7440-66-6) Xylene (CAS 1330-20-7) US. California Proposition 65 US - California Proposition 65 - CRT: Listed date/Carcinogenic substance (CAS 100-41-4) Listed: June 11, 2004 10 / 11 Material name: LPS® Cold Galvanize 573 Version 02 Revision date: 02-03-2014 Issue date: 03-07-2013 SDS US Page 632 of 1287 Page 632 of 1287 Page 632 of 1287 Page 632 of 1287 ---PAGE BREAK--- 16. Other information, including date of preparation or last revision Issue date 03-07-2013 Revision date 02-03-2014 Version # 02 References ACGIH EPA: AQUIRE database NLM: Hazardous Substances Data Base US. IARC Monographs on Occupational Exposures to Chemical Agents Korea. Accidental Release Prevention Substances (Presidential Decree of Toxic Chemical Control Law, Executive Order No. 19203) Korea. Dangerous Substances Threshold Quantity (Presidential Decree of Dangerous Substances Safety Management Act No. 18406, Schedule 1) Korea. Harmful Substances Prohibited from Manufacturing (Presidential Decree on the Industrial Safety and Health Act (No. 13053), Article 29) Korea. Harmful Substances Requiring Permission for Manufacture or Use (Presidential Decree on the Industrial Safety and Health Act (No. 13053), Article 30) Korea. Non-Toxic Chemicals List (National Institute of Environment Research (NIER) Public Notice No. 1997-10, as amended) Korea. Observational Chemicals (Ministerial Decree of TCCL Article 6) Korea. OELs. Regulation for Permitted Concentration of Hazardous Substances (Ministry of Labor (MOL) Public Notice No. 1986-45, as amended) Korea. Prohibited Chemical Substances (TCCL Article 11) Korea. Regulated volatile organic compounds (VOCs) (MOE Notice No. 2001-36, March 8, 2001, as amended) Korea. Restricted Chemical Substances (TCCL Article 11) Korea. Toxic Chemical Control Law (TCCL), Existing Chemicals Inventory (KECI) Korea. Toxic Chemical Control Law (TCCL), pre-1997 List Korea. Toxic Chemicals (TCCL Article 10) Korea. Toxic Release Inventory (TRI) Chemicals (TCCL Article 14) Taiwan. Dangerous Materials (Rules on Hazard Communication of Dangerous Materials and Toxic Materials) Taiwan. Industrial Precursor Chemicals (Categories and Regulations Governing Inspection and Declaration of Industrial Precursor Chemicals, MOEA Decree No. 87, as amended) Taiwan. OELs. (Standards on Workplace Atmosphere of Dangerous and Hazardous Materials) Taiwan. Toxic Chemical Substances (TCS) (List of Toxic Chemical Substances announced by the Environmental Protection Administration) Taiwan. Toxic Materials (Rules on Hazard Communication of Dangerous Materials and Toxic Materials) HSDB® - Hazardous Substances Data Bank IARC Monographs. Overall Evaluation of Carcinogenicity National Toxicology Program (NTP) Report on Carcinogens ACGIH Documentation of the Threshold Limit Values and Biological Exposure Indices Japan Society for Occupational Health, Recommendation of Occupational Exposure Limits GOST 30333-2007 - Chemical production safety passport. General requirements JJIS Z 7250: 2010 Safety data sheet for chemical products-Content and order of sections JIS Z 7251: 2010 Labeling of chemicals based on GHS Disclaimer This safety data sheet was prepared in accordance with the Safety Data Sheet for Chemical Products (JIS Z 7250:2010). Additional information is given in the Material Safety Data Sheet. The information in the sheet was written based on the best knowledge and experience currently available. Revision Information Product and Company Identification: Product and Company Identification Composition / Information on Ingredients: Ingredients Physical & Chemical Properties: Multiple Properties Transport Information: Material Transportation Information Regulatory Information: United States Other information, including date of preparation or last revision: Further information HazReg Data: North America GHS: Classification 11 / 11 Material name: LPS® Cold Galvanize 573 Version 02 Revision date: 02-03-2014 Issue date: 03-07-2013 SDS US Page 633 of 1287 Page 633 of 1287 Page 633 of 1287 Page 633 of 1287 ---PAGE BREAK--- Page 634 of 1287 Page 634 of 1287 Page 634 of 1287 Page 634 of 1287 ---PAGE BREAK--- Page 635 of 1287 Page 635 of 1287 Page 635 of 1287 Page 635 of 1287 ---PAGE BREAK--- Page 636 of 1287 Page 636 of 1287 Page 636 of 1287 Page 636 of 1287 ---PAGE BREAK--- Page 637 of 1287 Page 637 of 1287 Page 637 of 1287 Page 637 of 1287 ---PAGE BREAK--- M06, Mirror Glaze Liquid Cleaner Wax (21-151A):, M0616, M0664 03/20/15 Page 1 of 11 Safety Data Sheet Copyright,2015Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing Meguiar's, Inc. products is allowed provided that: the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 26-6716-0 Version Number: 3.00 Issue Date: 03/20/15 Supercedes Date: 07/02/12 SECTION 1: Identification 1.1. Product identifier M06, Mirror Glaze Liquid Cleaner Wax (21-151A):, M0616, M0664 Product Identification Numbers 14-1000-1159-3, 14-1000-1160-1, 14-1000-1161-9 1.2. Recommended use and restrictions on use Recommended use Automotive, One-step application that cleans, polishes and protects 1.3. Supplier’s details MANUFACTURER: Meguiar's, Inc. DIVISION: Meguiar's ADDRESS: 17991 Mitchell South, Irvine, CA 92614, USA Telephone: [PHONE REDACTED] (Fax: [PHONE REDACTED]) 1.4. Emergency telephone number CHEMTREC 1-[PHONE REDACTED] (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Skin Corrosion/Irritation: Category 2. Specific Target Organ Toxicity (central nervous system): Category 3. 2.2. Label elements Signal word Warning Page 638 of 1287 Page 638 of 1287 Page 638 of 1287 Page 638 of 1287 ---PAGE BREAK--- M06, Mirror Glaze Liquid Cleaner Wax (21-151A):, M0616, M0664 03/20/15 Page 2 of 11 Symbols Exclamation mark I Pictograms Hazard Statements Causes skin irritation. May cause drowsiness or dizziness. Precautionary Statements General: Keep out of reach of children. Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Storage: Store in a well-ventilated place. Keep container closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. 1% of the mixture consists of ingredients of unknown acute oral toxicity. 9% of the mixture consists of ingredients of unknown acute dermal toxicity. 19% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Water 7732-18-5 60 - 90 Trade Secret * Petroleum Distillate 64742-48-9 10 - 30 Trade Secret * Petroleum Distillate 64742-47-8 3 - 7 Trade Secret * Conditioners Trade Secret* < 5 Trade Secret * Calcined Kaolin 92704-41-1 1 - 5 Trade Secret * 63148-62-9 1 - 5 Trade Secret * White Mineral Oil (Petroleum) 8042-47-5 0.1 - 1 Trade Secret * Page 639 of 1287 Page 639 of 1287 Page 639 of 1287 Page 639 of 1287 ---PAGE BREAK--- M06, Mirror Glaze Liquid Cleaner Wax (21-151A):, M0616, M0664 03/20/15 Page 3 of 11 *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Irritant Vapors or Gases During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Page 640 of 1287 Page 640 of 1287 Page 640 of 1287 Page 640 of 1287 ---PAGE BREAK--- M06, Mirror Glaze Liquid Cleaner Wax (21-151A):, M0616, M0664 03/20/15 Page 4 of 11 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with detergent and water. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container closed. Store away from heat. Store away from acids. Store away from strong bases. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Kerosine (petroleum) 64742-47-8 ACGIH TWA(as total hydrocarbon vapor, non-aerosol):200 mg/m3 A3: Confirmed animal carcin., Skin Notation Petroleum Distillate 64742-47-8 CMRG TWA:165 ppm Naphtha 64742-48-9 OSHA TWA:400 mg/m3(100 ppm) Petroleum Distillate 64742-48-9 Manufacturer determined TWA:100 ppm MINERAL OILS, HIGHLY-REFINED OILS 8042-47-5 ACGIH TWA(inhalable fraction):5 mg/m3 A4: Not class. as human carcin Paraffin oil 8042-47-5 OSHA TWA(as mist):5 mg/m3 White Mineral Oil (Petroleum) 8042-47-5 CMRG TWA:5 mg/m3;STEL:10 mg/m3 ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Page 641 of 1287 Page 641 of 1287 Page 641 of 1287 Page 641 of 1287 ---PAGE BREAK--- M06, Mirror Glaze Liquid Cleaner Wax (21-151A):, M0616, M0664 03/20/15 Page 5 of 11 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety Glasses with side shields Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Odor, Color, Grade: Sweet odor; Creamy, ivory liquid Odor threshold No Data Available pH 8.5 - 9.2 Melting point Not Applicable Boiling Point 390 ºF Flash Point 200 ºF [Test Method: Pensky-Martens Closed Cup] [Details: D93-90] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure No Data Available Vapor Density No Data Available Density .96 g/cm3 Specific Gravity 0.96 [Ref Std: WATER=1] Solubility in Water Moderate Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Page 642 of 1287 Page 642 of 1287 Page 642 of 1287 Page 642 of 1287 ---PAGE BREAK--- M06, Mirror Glaze Liquid Cleaner Wax (21-151A):, M0616, M0664 03/20/15 Page 6 of 11 Viscosity 23,000 - 33,000 centipoise Volatile Organic Compounds 14.66 % weight Volatile Organic Compounds 203.14 g/l VOC Less H2O & Exempt Solvents 517.96 g/l SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat 10.5. Incompatible materials Strong acids Strong bases Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Skin Irritation: may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Page 643 of 1287 Page 643 of 1287 Page 643 of 1287 Page 643 of 1287 ---PAGE BREAK--- M06, Mirror Glaze Liquid Cleaner Wax (21-151A):, M0616, M0664 03/20/15 Page 7 of 11 Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Ingestion: Gastrointestinal Irritation: may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE > 5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE > 50 mg/l Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Petroleum Distillate Inhalation- Vapor LC50 estimated to be 20 - 50 mg/l Petroleum Distillate Dermal Rabbit LD50 > 3,000 mg/kg Petroleum Distillate Ingestion Rat LD50 > 5,000 mg/kg Calcined Kaolin Ingestion Rat LD50 > 2,000 mg/kg Petroleum Distillate Dermal Rabbit LD50 > 3,160 mg/kg Petroleum Distillate Inhalation- Dust/Mist (4 hours) Rat LC50 > 3.0 mg/l Petroleum Distillate Ingestion Rat LD50 > 5,000 mg/kg Dermal Rabbit LD50 > 19,400 mg/kg Ingestion Rat LD50 > 17,000 mg/kg White Mineral Oil (Petroleum) Dermal Rabbit LD50 > 2,000 mg/kg White Mineral Oil (Petroleum) Ingestion Rat LD50 > 5,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Petroleum Distillate Rabbit Irritant Petroleum Distillate Rabbit Mild irritant Rabbit No significant irritation White Mineral Oil (Petroleum) Rabbit No significant irritation Serious Eye Damage/Irritation Name Species Value Petroleum Distillate Rabbit No significant irritation Petroleum Distillate Rabbit Mild irritant Rabbit No significant irritation White Mineral Oil (Petroleum) Rabbit Mild irritant Page 644 of 1287 Page 644 of 1287 Page 644 of 1287 Page 644 of 1287 ---PAGE BREAK--- M06, Mirror Glaze Liquid Cleaner Wax (21-151A):, M0616, M0664 03/20/15 Page 8 of 11 Skin Sensitization Name Species Value Petroleum Distillate Guinea pig Not sensitizing Petroleum Distillate Guinea pig Not sensitizing White Mineral Oil (Petroleum) Guinea pig Not sensitizing Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Petroleum Distillate In vivo Not mutagenic Petroleum Distillate In Vitro Some positive data exist, but the data are not sufficient for classification Petroleum Distillate In Vitro Not mutagenic White Mineral Oil (Petroleum) In Vitro Not mutagenic Carcinogenicity Name Route Species Value Petroleum Distillate Dermal Mouse Some positive data exist, but the data are not sufficient for classification Petroleum Distillate Inhalation Human and animal Some positive data exist, but the data are not sufficient for classification Petroleum Distillate Dermal Mouse Some positive data exist, but the data are not sufficient for classification White Mineral Oil (Petroleum) Dermal Mouse Not carcinogenic White Mineral Oil (Petroleum) Inhalation Multiple animal species Not carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Petroleum Distillate Inhalation Not toxic to development Rat NOAEL 2.4 mg/l during organogenesi s White Mineral Oil (Petroleum) Ingestion Not toxic to female reproduction Rat NOAEL 4,350 mg/kg/day 13 weeks White Mineral Oil (Petroleum) Ingestion Not toxic to male reproduction Rat NOAEL 4,350 mg/kg/day 13 weeks White Mineral Oil (Petroleum) Ingestion Not toxic to development Rat NOAEL 4,350 mg/kg/day during gestation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Petroleum Distillate Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Petroleum Distillate Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Page 645 of 1287 Page 645 of 1287 Page 645 of 1287 Page 645 of 1287 ---PAGE BREAK--- M06, Mirror Glaze Liquid Cleaner Wax (21-151A):, M0616, M0664 03/20/15 Page 9 of 11 Petroleum Distillate Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Dog NOAEL 6.5 mg/l 4 hours Petroleum Distillate Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Petroleum Distillate Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Petroleum Distillate Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 4.6 mg/l 6 months Petroleum Distillate Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat LOAEL 1.9 mg/l 13 weeks Petroleum Distillate Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 0.6 mg/l 90 days Petroleum Distillate Inhalation bone, teeth, nails, and/or hair I blood I liver I muscles All data are negative Rat NOAEL 5.6 mg/l 12 weeks Petroleum Distillate Inhalation heart All data are negative Multiple animal species NOAEL 1.3 mg/l 90 days White Mineral Oil (Petroleum) Ingestion hematopoietic system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,381 mg/kg/day 90 days White Mineral Oil (Petroleum) Ingestion liver I immune system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,336 mg/kg/day 90 days Aspiration Hazard Name Value Petroleum Distillate Aspiration hazard Petroleum Distillate Aspiration hazard White Mineral Oil (Petroleum) Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Page 646 of 1287 Page 646 of 1287 Page 646 of 1287 Page 646 of 1287 ---PAGE BREAK--- M06, Mirror Glaze Liquid Cleaner Wax (21-151A):, M0616, M0664 03/20/15 Page 10 of 11 Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information General Transportation Statement This product does not require classification by DOT, IATA, ICAO or IMDG. Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact manufacturer for more information 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No 15.2. State Regulations Contact manufacturer for more information 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact manufacturer for more information 15.4. International Regulations Contact manufacturer for more information This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 2 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 26-6716-0 Version Number: 3.00 Issue Date: 03/20/15 Supercedes Date: 07/02/12 Page 647 of 1287 Page 647 of 1287 Page 647 of 1287 Page 647 of 1287 ---PAGE BREAK--- M06, Mirror Glaze Liquid Cleaner Wax (21-151A):, M0616, M0664 03/20/15 Page 11 of 11 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. Meguiar's, Inc. MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the Meguiar's, Inc. product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a Meguiar's, Inc. product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the Meguiar's, Inc. product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. Meguiar's, Inc. provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, Meguiar's, Inc. makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from Meguiar's, Inc. Meguiar's, Inc. USA SDSs are available at www.Meguiars.com Page 648 of 1287 Page 648 of 1287 Page 648 of 1287 Page 648 of 1287 ---PAGE BREAK--- MARVEL OIL CO., INC. 625 WILLOWBROOK CTR PKWY WILLOWBROOK, IL 60527 SAFETY DATA SHEET 1. Product and Company Identification 1.1 Product Identifier Product Name: Marvel Air Tool Oil Product Code (SKU): MM85R1 (50100), MM080R (50093) - See Section 15 for discontinued SKU’s 1.2 Relevant Identified Uses Of The Substance Product Use: Engine Oil Additive – Fuel additive (EPA Registered) 1.3 Details of the Supplier of the SDS Company Name: Marvel Oil Company, Inc. Street Address: 625 Willowbrook Centre Parkway City, State, Zip Code: Willowbrook, Illinois 60527 1.4 Emergency Telephone Numbers Phone Number: 1(630)455-3700 Fax Number: 1(630)455-3868 Transportation: 1(800)424-9300 (CHEMTREC) Medical Assistance: Call your local Poison Control Center 2. Hazard Identification: 2.1 Classification of the Substance or Mixture Hazard Classification: Flammable liquid 3 Skin irritation 2 Reproductive Toxicity 2 Aspiration toxicity 1 2.2 Label Elements Pictogram: Signal Word: Danger Hazard Statement: Flammable liquid and vapor. Causes skin irritation. Suspected of damaging fertility of the un-born child. May be fatal if swallowed and enters airways. Precautionary Statement: Keep away from heat, sparks, open flames or hot surfaces. Do not smoke. Keep containers closed. Ground all containers and receiving equipment. Use explosion proof electrical, ventilation, and lighting equipment. Use only non- sparking tools. Take precautionary measures against static Page 649 of 1287 Page 649 of 1287 Page 649 of 1287 Page 649 of 1287 ---PAGE BREAK--- discharge. Wear protective gloves, clothing, eye glasses and face shield. Do not handle until all safety precautions have been read and understood. Wash hands thoroughly after handling. If exposed, get medical attention. If on skin or hair, remove immediately all contaminated clothing and launder before re-use. Wash skin with soap and water. If skin irritation occurs, get medical attention. If swallowed, immediately call a poison control center or doctor. Do NOT induce vomiting. Store in a well ventilated place. Dispose of contents and container in accordance with all local, state, national and international regulations. 2.3 Other Hazards Description of additional HNOC: None 3. Information on Ingredients: 3.1 Substance not applicable 3.2 Mixture Component CAS Number Concentration (wt%) Petroleum Distillates (Hydrotreated Heavy 64742-52-5 60-100% Naphthenic) Petroleum Distillates (Stoddard Solvent) 8052-41-3 10-30% Tricresyl Phosphate 1330-78-5 0.1-1.0% Ortho Dichlorobenzene 95-50-1 0.1-1.0% Para Dichlorobenzene 106-46-7 <0.1% 4. First Aid Measures: 4.1 Description of First Aid Measures Inhalation: Remove to fresh air and promote deep breathing. Get medical attention if effects persist or you feel un-well. Skin: In case of skin contact, wash thoroughly with soap and water. Remove contaminated clothing and footwear. Launder clothing before re-use. Call a physician if irritation develops or persists. Eyes: In case of eye contact, immediately flush eyes with plenty of water. Remove contact lenses if worn. If irritation persists, get medical attention Ingestion: If swallowed, do not induce vomiting. Never give anything by mouth to an unconscious person. Immediately call a poison control center or physician. 4.2 Most important and effects – acute and chronic Inhalation: May cause respiratory tract irritation. Vapors may cause drowsiness or dizziness. Skin: Cause skin irritation. may include redness, edema, drying, defatting, and cracking of skin. Eyes: May cause temporary eye irritation. may include discomfort or pain, excess blinking and tearing, with redness and swelling. Ingestion: May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea, and vomiting. Page 650 of 1287 Page 650 of 1287 Page 650 of 1287 Page 650 of 1287 ---PAGE BREAK--- 4.3 Indication of any immediate medical attention and special treatment may not appear immediately. Seek medical attention if effects develop or persist and you feel un-well. 5. Fire Fighting Measures: 5.1 Extinguishing media Carbon dioxide, dry chemical, and alcohol foam 5.2 Special hazards arising from the substance or mixture CO2, CO, and hydrocarbons 5.3 Advice for Fire Fighters Keep up wind of fire. Wear full firefighting turn out gear (full bunker gear) and respiratory protection (SCBA). Cool closed containers exposed to fire with water. See Section 8 for personal protection. 6. Accidental Release Measures: 6.1 Personal precautions, protective equipment, and emergency procedures Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate all source of ignition. 6.2 Methods and materials for containment and clean up For containment: Contain and absorb spill with inert material. Place in suitable container for disposal. Do not flush to sewer or allow to enter waterways. See section 8 for PPE. For clean up: Take up material and place in a suitable container. Vapors may be heavier than air and may travel along the ground to a distant source of ignition. Provide adequate ventilation. 7. Handling and Storage 7.1 Precautions for safe handling Keep away from source of ignition. Do not smoke. Take precaution to eliminate static discharge. Avoid contact with skin and eyes. Avoid breathing vapor or mist. Do not swallow. Do not eat or drink while handling. Wash hands with soap and water after handling. Use only non-sparking tools. 7.2 Conditions for safe storage including incompatibilities Keep out of reach of children. Store in a well ventilated place. Do not store above 49°C (120°F). 7.3 Specific end uses Shelf Life: Shelf life is considered to be 7 – 10 years when properly stored. 8. Exposure Control/Personal Protection: 8.1 Control parameters Page 651 of 1287 Page 651 of 1287 Page 651 of 1287 Page 651 of 1287 ---PAGE BREAK--- Exposure Limits 8 hr TWA: (OSHA PEL) (ACGIH TWA) Petroleum Distillates (Hydrotreated Heavy not applicable not applicable Naphthenic) Petroleum Distillates (Stoddard Solvent) 500 ppm 100 ppm Tricresyl Phosphate not applicable not applicable Ortho Dichlorobenzene 50 ppm 25 ppm Para Dichlorobenzene 75 ppm 10 ppm 8.2 Exposure controls Use adequate ventilation to keep exposure below recommended limits. Ensure that eye wash station and safety shower are close to work station. Hand Protection Equipment: Wear chemical resistant gloves to prevent skin contact. Eye Protection Equipment: Wear safety glasses or splash goggles to prevent eye contact. Skin and Body Protection: Wear suitable protective clothing. Respiration/Ventilation Protection Requirements: Provide good ventilation. Ingestion Protection Requirements: Do not eat, drink or smoke while handling. Wash hands with soap and water after handling. Launder all clothing and foot wear before re-use. 9. Physical And Chemical Properties: 9.1 Information of basic chemical and physical properties Physical Form: thin liquid Color: clear red Odor: typical oily Odor Threshold: not available pH: not applicable – oil based product Melting Point/Freeze Point: -51⁰C (-60⁰F) Initial Boiling Point: not available Flash Point (Seta Closed Cup): 53⁰C (128⁰F) Flammability Limits: Explosive Limits: Upper: not available Lower: not available Evaporation Rate: not available Flammability Solid/Gas: not applicable Vapor Pressure: not available Vapor Density: not available Specific Gravity: 0.876 Solubility in Water: insoluble Auto Ignition Temperature: not available Partition coefficient (n/octonol/water): not available Viscosity (Kinimatic @ 100⁰C): 2.0 – 3.0 cSt 9. 2 Other information % NVM by Weight: 75.0% % VOC Content (California): 24.92% 10. Stability and Reactivity: 10.1 Reactivity Does not react under normal conditions 10.2 Chemical stability Stable Page 652 of 1287 Page 652 of 1287 Page 652 of 1287 Page 652 of 1287 ---PAGE BREAK--- 10.3 Possibility of hazardous reactions Does not react under normal conditions 10.4 Conditions to avoid Heat and incompatible materials 10.5 Incompatible materials Strong oxidizers such as bleach and peroxides 10.6 Hazardous decomposition products CO2, CO and hydrocarbons 11. Toxicological Information: 11.1 Information on Toxicological effects Marvel Mystery Oil LD50 – Oral Rat >2000 mg/Kg LD50 – Dermal Rabbit >2000 mg/Kg LC50 – Inhalation Rat >20 mg/L (4 hr) Petroleum Distillates Hydrotreated Heavy Naphthenic (64742-52-5) LD50 – Oral Rat >5000 mg/Kg LD50 – Dermal Rabbit >5000 mg/Kg LC50 – Inhalation Rat >5 mg/L (4 hr) Tricresyl Phosphate (1330-78-5) LD50 – Oral Rat 3000 mg/Kg o-Dichlorobenzene (95-50-1) LD50 – Oral Rat 500 mg/Kg LD50 – Dermal Rabbit >10000 mg/Kg LC50 – Inhalation Rat 8.15 mg/L (4 hr) p-Dichlorobenzene (106-46-7) LD50 – Oral Rat >2000 mg/Kg LD50 – Dermal Rabbit >2000 mg/Kg Skin corrosion/irritation Causes skin irritation Serious eye damage/irritation Based on available data, classification data are not met Respiratory or skin sensitization Based on available data, classification data are not met Germ cell mutagenicity Based on available data, classification data are not met Carcinogenicity Based on available data, classification data are not met o-Dichlorobenzene (95-50-1) IARC Group 3 – Not Classified p-dichlorobenzene (106-46-7) IARC Group 2B – Possible carcinogen to humans. NTP 1-Evidence of Carcinogenicity 3, Reasonably anticipated to be a human Carcinogen Reproductive toxicity Suspected of damaging fertility of un-born child Specific target organs – single exposure Based on available data, classification data are not met Specific target organs – repeated exposure Based on available data, classification data are not met Page 653 of 1287 Page 653 of 1287 Page 653 of 1287 Page 653 of 1287 ---PAGE BREAK--- Aspiration hazard May be fatal if swallowed and enters air ways. after inhalation May cause respiratory tract irritation. Vapors may cause drowsiness and dizziness. after skin contact Cause skin irritation. may include redness, edema, drying, defatting, and cracking of skin. after eye contact May cause temporary eye irritation. may include discomfort or pain, excess blinking and tearing, with redness and swelling. after ingestion May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea, and vomiting. 12. Ecological Information: 12.1 Toxicity Not recommended for release into aquatic systems without treatment 12.2 Persistence and degradability Not established 12.3 Bioaccumulative potential Not established 12.4 Mobility in soil Not established 12.5 Other adverse effects None known 13. Disposal Considerations: 13.1 Waste treatment methods RCRA Hazardous Waste: Regulated as a hazardous waste (D-001 Ignitable). Waste Disposal Method: Dispose of in accordance with local, state and federal regulations Waste Disposal Vessel: Metal drums are recommended. 14. Transportation Information: 14.1 UN number 1268 14.2 UN Proper shipping name Petroleum Distillate n.o.s. 14.3 Transport Hazard class 3 14.4 Packaging group III 14.5 Marine Pollutant No 14.6 Transportation in Bulk Not applicable Page 654 of 1287 Page 654 of 1287 Page 654 of 1287 Page 654 of 1287 ---PAGE BREAK--- 14.7 Special precautions Use limited quantities 15. Regulatory Information: 15.1 US Federal Regulations TSCA Status: All ingredients are commercially available and listed by the manufacturer under TSCA. 15.2 Foreign Regulations Canadian Status: All materials contained in this product are listed on the Canadian Domestic Substance List (DSL). Consult Turtle Wax, Inc. regarding status of ingredients. European Union: All materials contained in this product are listed on EINECS. AICS: All materials are registered for AICS (Australia) 15.3 State Regulations State Regulatory Information: The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the SDS may also be applicable for state requirements. For details on your regulatory requirements, contact the appropriate agency in your state. California Prop 65: CAS Number Concentration State Code p-Dichlorobenzene (106-46-7) <0.1% Cancer 15.4 HIMS & NFPA Classifications HIMS Classification: Health 2 Flammability 2 Reactivity 0 NFPA Classification: Health 2 Flammability 2 Reactivity 0 15.5 Discontinued SKU’s All discontinued SKU’s used this same formula. MM080, MM085, MM85R, MM086, MM088R, MM089 16. Other Information: Reason For Issue Conversion to OSHA GHS SDS Format Prepared By James Heidel Preparer’s Title Technical Director, R&D SDS Administrator Jean Mayszak - Technical Compliance Manager, R&D Page 655 of 1287 Page 655 of 1287 Page 655 of 1287 Page 655 of 1287 ---PAGE BREAK--- Approval Date March 10, 2015 Supersedes Date December 27, 2012 Revision Number #11 This information is, to the best of Turtle Wax, Inc.’s knowledge and belief, accurate and reliable. However, no representation, warranty, or guarantee is made to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy oneself as to the suitableness and completeness of such information for their own particular use. Page 656 of 1287 Page 656 of 1287 Page 656 of 1287 Page 656 of 1287 ---PAGE BREAK--- MARVEL OIL CO., INC. 625 WILLOWBROOK CTR PKWY WILLOWBROOK, IL 60527 SAFETY DATA SHEET 1. Product and Company Identification 1.1 Product Identifier Product Name: Marvel Mystery Oil Product Code (SKU): MM12R (50094), MM13R (50095), MM13RC (50096) MM14R (50097) – See section 15 for discontinued SKU’s 1.2 Relevant Identified Uses Of The Substance Product Use: Engine Oil Additive – Fuel additive (EPA Registered) 1.3 Details of the Supplier of the SDS Company Name: Marvel Oil Company, Inc. Street Address: 625 Willowbrook Centre Parkway City, State, Zip Code: Willowbrook, Illinois 60527 1.4 Emergency Telephone Numbers Phone Number: 1(630)455-3700 Fax Number: 1(630)455-3868 Transportation: 1(800)424-9300 (CHEMTREC) Medical Assistance: Call your local Poison Control Center 2. Hazard Identification: 2.1 Classification of the Substance or Mixture Hazard Classification: Flammable liquid 3 Skin irritation 2 Reproductive Toxicity 2 Aspiration toxicity 1 2.2 Label Elements Pictogram: Signal Word: Danger Hazard Statement: Flammable liquid and vapor. Causes skin irritation. Suspected of damaging fertility of the un-born child. May be fatal if swallowed and enters airways. Precautionary Statement: Keep away from heat, sparks, open flames or hot surfaces. Do not smoke. Keep containers closed. Ground all containers and receiving equipment. Use explosion proof electrical, ventilation, and lighting equipment. Use only non- sparking tools. Take precautionary measures against static Page 657 of 1287 Page 657 of 1287 Page 657 of 1287 Page 657 of 1287 ---PAGE BREAK--- discharge. Wear protective gloves, clothing, eye glasses and face shield. Do not handle until all safety precautions have been read and understood. Wash hands thoroughly after handling. If exposed, get medical attention. If on skin or hair, remove immediately all contaminated clothing and launder before re-use. Wash skin with soap and water. If skin irritation occurs, get medical attention. If swallowed, immediately call a poison control center or doctor. Do NOT induce vomiting. Store in a well ventilated place. Dispose of contents and container in accordance with all local, state, national and international regulations. 2.3 Other Hazards Description of additional HNOC: None 3. Information on Ingredients: 3.1 Substance not applicable 3.2 Mixture Component CAS Number Concentration (wt%) Petroleum Distillates (Hydrotreated Heavy 64742-52-5 60-100% Naphthenic) Petroleum Distillates (Stoddard Solvent) 8052-41-3 10-30% Tricresyl Phosphate 1330-78-5 0.1-1.0% Ortho Dichlorobenzene 95-50-1 0.1-1.0% Para Dichlorobenzene 106-46-7 <0.1% 4. First Aid Measures: 4.1 Description of First Aid Measures Inhalation: Remove to fresh air and promote deep breathing. Get medical attention if effects persist or you feel un-well. Skin: In case of skin contact, wash thoroughly with soap and water. Remove contaminated clothing and footwear. Launder clothing before re-use. Call a physician if irritation develops or persists. Eyes: In case of eye contact, immediately flush eyes with plenty of water. Remove contact lenses if worn. If irritation persists, get medical attention Ingestion: If swallowed, do not induce vomiting. Never give anything by mouth to an unconscious person. Immediately call a poison control center or physician. 4.2 Most important and effects – acute and chronic Inhalation: May cause respiratory tract irritation. Vapors may cause drowsiness or dizziness. Skin: Cause skin irritation. may include redness, edema, drying, defatting, and cracking of skin. Eyes: May cause temporary eye irritation. may include discomfort or pain, excess blinking and tearing, with redness and swelling. Ingestion: May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea, and vomiting. Page 658 of 1287 Page 658 of 1287 Page 658 of 1287 Page 658 of 1287 ---PAGE BREAK--- 4.3 Indication of any immediate medical attention and special treatment may not appear immediately. Seek medical attention if effects develop or persist and you feel un-well. 5. Fire Fighting Measures: 5.1 Extinguishing media Carbon dioxide, dry chemical, and alcohol foam 5.2 Special hazards arising from the substance or mixture CO2, CO, and hydrocarbons 5.3 Advice for Fire Fighters Keep up wind of fire. Wear full firefighting turn out gear (full bunker gear) and respiratory protection (SCBA). Cool closed containers exposed to fire with water. See Section 8 for personal protection. 6. Accidental Release Measures: 6.1 Personal precautions, protective equipment, and emergency procedures Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate all source of ignition. 6.2 Methods and materials for containment and clean up For containment: Contain and absorb spill with inert material. Place in suitable container for disposal. Do not flush to sewer or allow to enter waterways. See section 8 for PPE. For clean up: Take up material and place in a suitable container. Vapors may be heavier than air and may travel along the ground to a distant source of ignition. Provide adequate ventilation. 7. Handling and Storage 7.1 Precautions for safe handling Keep away from source of ignition. Do not smoke. Take precaution to eliminate static discharge. Avoid contact with skin and eyes. Avoid breathing vapor or mist. Do not swallow. Do not eat or drink while handling. Wash hands with soap and water after handling. Use only non-sparking tools. 7.2 Conditions for safe storage including incompatibilities Keep out of reach of children. Store in a well ventilated place. Do not store above 49°C (120°F). 7.3 Specific end uses Shelf Life: Shelf life is considered to be 7 – 10 years when properly stored. 8. Exposure Control/Personal Protection: 8.1 Control parameters Page 659 of 1287 Page 659 of 1287 Page 659 of 1287 Page 659 of 1287 ---PAGE BREAK--- Exposure Limits 8 hr TWA: (OSHA PEL) (ACGIH TWA) Petroleum Distillates (Hydrotreated Heavy not applicable not applicable Naphthenic) Petroleum Distillates (Stoddard Solvent) 500 ppm 100 ppm Tricresyl Phosphate not applicable not applicable Ortho Dichlorobenzene 50 ppm 25 ppm Para Dichlorobenzene 75 ppm 10 ppm 8.2 Exposure controls Use adequate ventilation to keep exposure below recommended limits. Ensure that eye wash station and safety shower are close to work station. Hand Protection Equipment: Wear chemical resistant gloves to prevent skin contact. Eye Protection Equipment: Wear safety glasses or splash goggles to prevent eye contact. Skin and Body Protection: Wear suitable protective clothing. Respiration/Ventilation Protection Requirements: Provide good ventilation. Ingestion Protection Requirements: Do not eat, drink or smoke while handling. Wash hands with soap and water after handling. Launder all clothing and foot wear before re-use. 9. Physical And Chemical Properties: 9.1 Information of basic chemical and physical properties Physical Form: thin liquid Color: clear red Odor: oil of wintergreen - minty Odor Threshold: not available pH: not applicable – oil based product Melting Point/Freeze Point: -51⁰C (-60⁰F) Initial Boiling Point: not available Flash Point (Seta Closed Cup): 53⁰C (128⁰F) Flammability Limits: Explosive Limits: Upper: not available Lower: not available Evaporation Rate: not available Flammability Solid/Gas: not applicable Vapor Pressure: not available Vapor Density: not available Specific Gravity: 0.876 Solubility in Water: insoluble Auto Ignition Temperature: not available Partition coefficient (n/octonol/water): not available Viscosity (Kinimatic @ 100⁰C): 2.0 – 3.0 cSt 9. 2 Other information % NVM by Weight: 75.0% % VOC Content (California): 24.31% 10. Stability and Reactivity: 10.1 Reactivity Does not react under normal conditions 10.2 Chemical stability Stable Page 660 of 1287 Page 660 of 1287 Page 660 of 1287 Page 660 of 1287 ---PAGE BREAK--- 10.3 Possibility of hazardous reactions Does not react under normal conditions 10.4 Conditions to avoid Heat and incompatible materials 10.5 Incompatible materials Strong oxidizers such as bleach and peroxides 10.6 Hazardous decomposition products CO2, CO and hydrocarbons 11. Toxicological Information: 11.1 Information on Toxicological effects Marvel Mystery Oil LD50 – Oral Rat >2000 mg/Kg LD50 – Dermal Rabbit >2000 mg/Kg LC50 – Inhalation Rat >20 mg/L (4 hr) Petroleum Distillates Hydrotreated Heavy Naphthenic (64742-52-5) LD50 – Oral Rat >5000 mg/Kg LD50 – Dermal Rabbit >5000 mg/Kg LC50 – Inhalation Rat >5 mg/L (4 hr) Tricresyl Phosphate (1330-78-5) LD50 – Oral Rat 3000 mg/Kg o-Dichlorobenzene (95-50-1) LD50 – Oral Rat 500 mg/Kg LD50 – Dermal Rabbit >10000 mg/Kg LC50 – Inhalation Rat 8.15 mg/L (4 hr) p-Dichlorobenzene (106-46-7) LD50 – Oral Rat >2000 mg/Kg LD50 – Dermal Rabbit >2000 mg/Kg Skin corrosion/irritation Cause skin irritation Serious eye damage/irritation Based on available data, classification data are not met Respiratory or skin sensitization Based on available data, classification data are not met Germ cell mutagenicity Based on available data, classification data are not met Carcinogenicity Based on available data, classification data are not met o-Dichlorobenzene (95-50-1) IARC Group 3 – Not Classified p-dichlorobenzene (106-46-7) IARC Group 2B – Possible carcinogen to humans. NTP 1-Evidence of Carcinogenicity 3, Reasonably anticipated to be a human Carcinogen Reproductive toxicity Suspected of damaging fertility of un-born child Specific target organs – single exposure Based on available data, classification data are not met Specific target organs – repeated exposure Based on available data, classification data are not met Aspiration hazard May be fatal if swallowed and enters air ways. Page 661 of 1287 Page 661 of 1287 Page 661 of 1287 Page 661 of 1287 ---PAGE BREAK--- after inhalation May cause respiratory tract irritation. Vapors may cause drowsiness and dizziness. after skin contact Cause skin irritation. may include redness, edema, drying, defatting, and cracking of skin. after eye contact May cause temporary eye irritation. may include discomfort or pain, excess blinking and tearing, with redness and swelling. after ingestion May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea, and vomiting. 12. Ecological Information: 12.1 Toxicity Not recommended for release into aquatic systems without treatment 12.2 Persistence and degradability Not established 12.3 Bioaccumulative potential Not established 12.4 Mobility in soil Not established 12.5 Other adverse effects None known 13. Disposal Considerations: 13.1 Waste treatment methods RCRA Hazardous Waste: Regulated as a hazardous waste (D-001 Ignitable). Waste Disposal Method: Dispose of in accordance with local, state and federal regulations Waste Disposal Vessel: Metal drums are recommended. 14. Transportation Information: 14.1 UN number 1268 14.2 UN Proper shipping name Petroleum Distillate n.o.s. 14.3 Transport Hazard class 3 14.4 Packaging group III 14.5 Marine Pollutant No 14.6 Transportation in Bulk Not applicable Page 662 of 1287 Page 662 of 1287 Page 662 of 1287 Page 662 of 1287 ---PAGE BREAK--- 14.7 Special precautions Use limited quantities 15. Regulatory Information: 15.1 US Federal Regulations TSCA Status: All ingredients are commercially available and listed by the manufacturer under TSCA. 15.2 Foreign Regulations Canadian Status: All materials contained in this product are listed on the Canadian Domestic Substance List (DSL). Consult Turtle Wax, Inc. regarding status of ingredients. European Union: All materials contained in this product are listed on EINECS. AICS: All materials are registered for AICS (Australia) 15.3 State Regulations State Regulatory Information: The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the SDS may also be applicable for state requirements. For details on your regulatory requirements, contact the appropriate agency in your state. California Prop 65: CAS Number Concentration State Code p-Dichlorobenzene (106-46-7) <0.1% Cancer 15.4 HIMS & NFPA Classifications HIMS Classification: Health 2 Flammability 2 Reactivity 0 NFPA Classification: Health 2 Flammability 2 Reactivity 0 15.5 Discontinued SKU’s These all utilized to same formula. MM003, MM007, MM08, MM010, MM011, MM012R, MM013R, MM014R, MM015, MM016, MM017, MM018, MM613, MM005 16. Other Information: Reason For Issue Conversion to OSHA GHS SDS Format Prepared By James Heidel Preparer’s Title Technical Director, R&D Page 663 of 1287 Page 663 of 1287 Page 663 of 1287 Page 663 of 1287 ---PAGE BREAK--- SDS Administrator Jean Mayszak - Technical Compliance Manager, R&D Approval Date March 10, 2015 Supersedes Date December 27, 2012 Revision Number #11 This information is, to the best of Turtle Wax, Inc.’s knowledge and belief, accurate and reliable. However, no representation, warranty, or guarantee is made to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy oneself as to the suitableness and completeness of such information for their own particular use. Page 664 of 1287 Page 664 of 1287 Page 664 of 1287 Page 664 of 1287 ---PAGE BREAK--- Safety Data Sheet Issue Date: 28-Aug-2014 Revision Date: 09-Sep-2014 Version 1 Page 1 / 6 1. IDENTIFICATION Product Identifier Product Name MIKE-O-CUT #87 Other means of identification SDS # Item# D-1330; 1332; 1333 D-1334; 1335 Recommended use of the chemical and restrictions on use Recommended Use Tapping and drilling metal Details of the supplier of the safety data sheet Supplier Address Ashburn Chemical Technologies 7403 Wright Rd Houston, TX 77041 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr) [PHONE REDACTED] INFOTRAC 1-[PHONE REDACTED] (International) 1-[PHONE REDACTED] (North America) 2. HAZARDS IDENTIFICATION Appearance Amber liquid Physical State Liquid Odor Wintergreen Classification This chemical does not meet the hazardous criteria set forth by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). However, this Safety Data Sheet (SDS) contains valuable information critical to the safe handling and proper use of this product. This SDS should be retained and available for employees and other users of this product. 3. COMPOSITION/INFORMATION ON INGREDIENTS This product is not hazardous according to OSHA 29 CFR 1910.1200. Components not listed are not hazardous or are below reportable limits. 4. FIRST-AID MEASURES First Aid Measures General Advice Provide this SDS to medical personnel for treatment. Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin Contact Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. Get medical attention if irritation occurs. Page 665 of 1287 Page 665 of 1287 Page 665 of 1287 Page 665 of 1287 ---PAGE BREAK--- MIKE-O-CUT No. 87 Revision Date: 09-Sep-2014 Page 2 / 6 Inhalation Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. Seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion Do not induce vomiting without medical advice. Seek immediate medical attention/advice. Most important and effects May cause skin and eye irritation. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Hazardous Combustion Products moke, Fume, Incomplete combustion products, Oxides of carbon. Protective equipment and precautions for firefighters Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus(SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Wear protective clothing as described in Section 8 of this safety data sheet. Environmental Precautions Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Absorb or cover with dry earth, sand or other non-combustible material. Methods for Clean-Up Sweep up absorbed material and shovel into suitable containers for disposal. Discard any product, residue, disposable container or liner in full compliance with federal, state, and local regulations. For waste disposal, see section 13 of the SDS. Contain large spills and pump into a suitable tank for disposal. In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800) 424-8802. 7. HANDLING AND STORAGE Page 666 of 1287 Page 666 of 1287 Page 666 of 1287 Page 666 of 1287 ---PAGE BREAK--- MIKE-O-CUT No. 87 Revision Date: 09-Sep-2014 Page 3 / 6 Precautions for safe handling Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing fumes, vapors, mists, spray. Wash face, hands, and any exposed skin thoroughly after handling. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container closed and store in a cool, dry and well-ventilated place. Do not store in open or unlabeled containers. Store away from heat and open flame. Storage temperature > 40 F. Incompatible Materials Oxidizing agents. Strong acids. Strong bases. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines No exposure limits noted for ingredient(s) Appropriate engineering controls Engineering Controls Maintain eye wash fountain and quick-drench facilities in work area. Individual protection measures, such as personal protective equipment Eye/Face Protection If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection If prolonged or repeated contact is likely, chemical, and oil resistant clothing is recommended. Respiratory Protection Ensure adequate ventilation, especially in confined areas. General Hygiene Considerations Avoid contact with skin, eyes and clothing. After handling this product, wash hands before eating, drinking, or smoking. If contact occurs, remove contaminated clothing. If needed, take first aid action shown on section 4 of this SDS. Launder contaminated clothing before reuse. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Liquid Appearance Amber liquid Odor Wintergreen Color Amber Odor Threshold Not determined Property Values Remarks • Method pH Not determined Melting Point/Freezing Point Not determined Boiling Point/Boiling Range > 232.22 °C / > 450 °F (at 760 mm Hg) Flash Point > 212.77 °C / > 415 °F Pensky-Martens Closed Cup (PMCC) Evaporation Rate < 1 Flammability (Solid, Gas) Not determined Upper Flammability Limits Not determined Lower Flammability Limit Not determined Vapor Pressure Not determined Vapor Density < 1.0 (Air=1) Specific Gravity 1.108 Water Solubility Nil Solubility in other solvents Not determined Page 667 of 1287 Page 667 of 1287 Page 667 of 1287 Page 667 of 1287 ---PAGE BREAK--- MIKE-O-CUT No. 87 Revision Date: 09-Sep-2014 Page 4 / 6 Partition Coefficient Not determined Auto-ignition Temperature Not determined Decomposition Temperature Not determined Kinematic Viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined VOC Content 0.36% (3.9/L) 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to Avoid Incompatible Materials. Incompatible Materials Oxidizing agents. Strong acids. Strong bases. Hazardous Decomposition Products Thermal decomposition and combustion are not expected to occur except under extreme conditions. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact May cause temporary irritation on eye contact. Skin Contact Prolonged contact may cause redness and irritation. Inhalation May cause irritation to the mucous membranes and upper respiratory tract. Ingestion May cause gastrointestinal irritation or diarrhea. Component Information Information on physical, chemical and toxicological effects Please see section 4 of this SDS for Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization May cause an allergic skin reaction. Carcinogenicity Carcinogenic potential is unknown. Numerical measures of toxicity Not determined 12. ECOLOGICAL INFORMATION Page 668 of 1287 Page 668 of 1287 Page 668 of 1287 Page 668 of 1287 ---PAGE BREAK--- MIKE-O-CUT No. 87 Revision Date: 09-Sep-2014 Page 5 / 6 Ecotoxicity Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Not determined Other Adverse Effects Not determined 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT Not regulated IATA Not regulated IMDG Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Listed Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 311/312 Hazard Categories This material, as supplied, does not contain any substances subject to the requirements of SARA Sections 311/312 (40 CFR 370) Page 669 of 1287 Page 669 of 1287 Page 669 of 1287 Page 669 of 1287 ---PAGE BREAK--- MIKE-O-CUT No. 87 Revision Date: 09-Sep-2014 Page 6 / 6 SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 US State Regulations U.S. State Right-to-Know Regulations This product does not contain any substances regulated under applicable state right-to-know regulations 16. OTHER INFORMATION NFPA Health Hazards 1 Flammability 0 Instability 0 Special Hazards Not determined HMIS Health Hazards 1 Flammability 0 Physical Hazards 0 Personal Protection Not determined Issue Date: 28-Aug-2014 Revision Date: 09-Sep-2014 Revision Note: New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 670 of 1287 Page 670 of 1287 Page 670 of 1287 Page 670 of 1287 ---PAGE BREAK--- Mixed Product Safety Data Sheet According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Date of issue: 07/24/2015 EN (English US) Page 1 Section 1: Identification 1.1. Product identifier Product form : Mixture Product Identifier(s) : Mixed Product Trans-Mix Slop-Mix Mixed Gasoline Distillate Product 1.2. Recommended use of the chemical and restrictions on use Use of the substance/mixture : Fuel Extraction of chemical component substances. 1.3. Details of the supplier of the safety data sheet Total Petrochemicals & Refining USA, Inc. P O Box 674411 Houston, TX 77267-4411 For non-emergency product information: Phone: [PHONE REDACTED] Email: [EMAIL REDACTED] 1.4. Emergency telephone number Emergency number : CHEMTREC: 1-[PHONE REDACTED] (Toll Free USA & Canada) / [PHONE REDACTED] (Multiple languages) Total Petrochemicals & Refining USA, Inc.: 1-[PHONE REDACTED] (Language: English only) Section 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Flammable liquids Category 1 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2B Germ cell mutagenicity Category 1B Carcinogenicity Category 1A Reproductive toxicity Category 2 Specific target organ toxicity (single exposure) Category 3 - Narcotic effects Specific target organ toxicity (single exposure) Category 3 - Respiratory irritation Specific target organ toxicity (single exposure) Category 1 Specific target organ toxicity (single exposure) Category 2 Specific target organ toxicity (repeated exposure) Category 1 Specific target organ toxicity (repeated exposure) Category 2 Aspiration hazard Category 1 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Extremely flammable liquid and vapor May be fatal if swallowed and enters airways Causes skin irritation Causes eye irritation May cause respiratory irritation May cause drowsiness or dizziness May cause genetic defects Page 671 of 1287 Page 671 of 1287 Page 671 of 1287 Page 671 of 1287 ---PAGE BREAK--- Mixed Product Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 2/11 May cause cancer Suspected of damaging fertility or the unborn child Causes damage to organs (blood, lung) May cause damage to organs (immune system, eye) Causes damage to organs (blood, hematopoietic system [blood forming], kidneys, peripheral nervous system, nervous system, brain (neurological), hearing organ (loss of hearing), visual organ (color vision effects), eye) through prolonged or repeated exposure May cause damage to organs (lung, nose) through prolonged or repeated exposure Precautionary statements (GHS-US) : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from sparks, open flames, heat, hot surfaces. - No smoking. Keep container closed. Ground/bond container and receiving equipment. Use explosion-proof electrical, lighting, ventilating equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe spray, mist, vapors. Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear flame retardant protective clothing, impermeable protective gloves, eye protection. If swallowed: Immediately call doctor, poison center. Do NOT induce vomiting. If on skin: Wash with plenty of water. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Specific treatment (see Section 4.1 of SDS or information on this label). If exposed or concerned: Get medical advice/attention. Get medical advice/attention if you feel unwell. Take off contaminated clothing and wash it before reuse. In case of fire: Use Water spray, foam, carbon dioxide (CO2), dry chemical to extinguish. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. 2.3. Hazards not otherwise classified Other hazards not contributing to the classification : Product can accumulate electrostatic charges that may cause fire by electrical discharges. 2.4. Unknown acute toxicity (GHS-US) 37.62 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation (Vapours)) 2.5. Additional information No additional information available Section 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Where concentrations in this product are displayed as ranges, it is due to batch-to-batch variability. Name CAS No % Gasoline 86290-81-5 0 - 100 Diesel 64742-80-9 0 - 100 Toluene 108-88-3 0 - 25 Xylene 1330-20-7 0 - 15 100-41-4 0 - 5 n-Hexane 110-54-3 0 - 5 Naphthalene 91-20-3 0 - 4 Benzene 71-43-2 0 - 2 Biphenyl 92-52-4 < 1 Page 672 of 1287 Page 672 of 1287 Page 672 of 1287 Page 672 of 1287 ---PAGE BREAK--- Mixed Product Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 3/11 Cumene 98-82-8 < 1 Aromatic Compounds 130498-29-2 < 0.5 Section 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center/doctor/physician if you feel unwell. First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if irritation persists. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a poison center or doctor/physician. 4.2. Most important and effects, both acute and delayed : May cause genetic defects. after inhalation : May cause respiratory irritation. May cause drowsiness or dizziness. after skin contact : Causes skin irritation. after ingestion : May be fatal if swallowed and enters airways. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available Section 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the chemical Fire hazard : Extremely flammable liquid and vapor. Explosion hazard : May form flammable/explosive vapor-air mixture. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Section 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Emergency procedures for non-emergency personnel : Evacuate unnecessary personnel. Emergency procedures for emergency responders : Ventilate area. Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. 6.2. Methods and material for containment and cleaning up For containment : Do not contaminate ground and surface water. Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.3. Reference to other sections See section 8. Exposure controls/personal protection. Section 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No bare lights. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Eliminate all ignition sources if safe to do so. Avoid breathing vapors, mist, spray. Use only outdoors or in a well-ventilated area. Do not breathe vapors, mist, spray. Page 673 of 1287 Page 673 of 1287 Page 673 of 1287 Page 673 of 1287 ---PAGE BREAK--- Mixed Product Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 4/11 Hygiene measures : Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when using this product. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating, lighting equipment. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : flames, heat sources, sparks. Keep in fireproof place. Keep container closed. Incompatible products : Strong bases. Strong acids. Strong oxidizing agents. Strong reducing agents. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. Section 8: Exposure controls/personal protection 8.1. Occupational Exposure Limits Mixed Product USA ACGIH ACGIH TWA (ppm) 300 ppm USA ACGIH ACGIH STEL (ppm) 500 ppm Toluene (108-88-3) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (ppm) 200 ppm USA OSHA OSHA PEL (Ceiling) (ppm) 300 ppm USA OSHA Remark (OSHA) See OSHA Table Z-2. Xylenes p- isomers) (1330-20-7) USA ACGIH ACGIH TWA (ppm) 100 ppm USA ACGIH ACGIH STEL (ppm) 150 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 435 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 100 ppm Gasoline (86290-81-5) USA ACGIH ACGIH TWA (ppm) 300 ppm USA ACGIH ACGIH STEL (ppm) 500 ppm n-Hexane (110-54-3) USA ACGIH ACGIH TWA (ppm) 50 ppm USA OSHA OSHA PEL (TWA) (ppm) 500 ppm (100-41-4) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 435 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 100 ppm Naphthalene (91-20-3) USA ACGIH ACGIH TWA (ppm) 10 ppm USA ACGIH ACGIH STEL (ppm) 15 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 50 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 10 ppm Benzene (71-43-2) USA ACGIH ACGIH TWA (ppm) 0.5 ppm USA ACGIH ACGIH STEL (ppm) 2.5 ppm USA OSHA OSHA PEL (TWA) (ppm) 1 ppm USA OSHA OSHA PEL (STEL) (ppm) 5 ppm USA OSHA Remark (OSHA) (see 29 CFR 1910.1028) Biphenyl (92-52-4) USA ACGIH ACGIH TWA (ppm) 0.2 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 1 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 0.2 ppm Cumene (98-82-8) USA ACGIH ACGIH TWA (ppm) 50 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 245 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 50 ppm 8.2. Exposure controls Appropriate engineering controls : Ensure adequate ventilation. Page 674 of 1287 Page 674 of 1287 Page 674 of 1287 Page 674 of 1287 ---PAGE BREAK--- Mixed Product Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 5/11 Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Impermeable protective gloves. Choosing the proper glove is a decision that depends not only on the type of material, but also on other quality features, which differ for each manufacturer. Gloves should be discarded and replaced if there is any indication of degredation or chemical breakthrough. The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear fire/flame resistant/retardant clothing. Respiratory protection : An approved organic vapor respirator/supplied air or self-contained breathing apparatus must be used when vapor concentration exceeds applicable exposure limits. Other information : Do not eat, drink or smoke during use. Section 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : Colorless. Amber or red, if dyed. Odor : Characteristic. Odor threshold : 83 ppm Weighted average pH : Not applicable Relative evaporation rate (butyl acetate=1) : No data available Relative evaporation rate (ether=1) : < 30 Slower than ethyl ether Melting point : < -60 °C Freezing point : No data available Boiling point : 27 (27 - 225) °C Flash point : < -35 °C (closed cup) Auto-ignition temperature : 280 - 470 °C (at 1013 hPa) Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : 500 - 700 mm Hg at 21°C Relative vapor density at 20 °C : 3 - 4 Air = 1 Relative density : 0.75 Solubility : Water: 30 - 100 mg/l (at 20 Log Kow : No data available Viscosity, kinematic : < 21 cSt at 40°C Viscosity, dynamic : No data available Explosive limits : No data available 9.2. Other information VOC content : 100 % Section 10: Stability and reactivity 10.1. Reactivity Flammable liquid and vapor. 10.2. Chemical stability The product is stable at normal handling and storage conditions. 10.3. Possibility of hazardous reactions Under normal conditions of storage and use, hazardous polymerization will not occur. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. Sparks. Heat. Overheating. Open flame. 10.5. Incompatible materials Strong acids. Strong bases. Strong oxidizing agents. Strong reducing agents. 10.6. Hazardous decomposition products Hazardous decomposition products formed under fire conditions: carbon monoxide, carbon dioxide, toxic fumes. Page 675 of 1287 Page 675 of 1287 Page 675 of 1287 Page 675 of 1287 ---PAGE BREAK--- Mixed Product Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 6/11 Section 11: Toxicological information 11.1. Information on toxicological effects Likely routes of exposure : Inhalation. Ingestion. Skin contact. Eye contact. Acute toxicity : Not classified Based on available data, the classification criteria are not met Combustion of hydrocarbon substances, like this product, produces potentially toxic gases which include carbon monoxide, carbon dioxide, oxides of nitrogen and/or sulfur. Exposure to carbon monoxide gas decreases the ability of the blood to carry oxygen to the body and may be potentially fatal. NIOSH lists the Immediately Dangerous to Life or Health Concentration (IDLH) for carbon monoxide gas as1200 ppm. Toluene (108-88-3) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 5000 mg/kg LC50 inhalation rat 28.1 (28.1 - 49) mg/l/4h LC50 inhalation rat (ppm) > 26700 ppm/1h Xylenes p- isomers) (1330-20-7) LD50 oral rat 4300 mg/kg LD50 dermal rabbit > 4200 mg/kg LC50 inhalation rat 21.7 mg/l/4h Gasoline (86290-81-5) LD50 oral rat 14000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat > 5.2 mg/l/4h Diesel (64742-80-9) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat 4.6 (4.6 - 7.6) mg/l/4h Inhalation form: aerosol (mist) n-Hexane (110-54-3) LD50 oral rat 15840 mg/kg LD50 dermal rabbit 3000 mg/kg LC50 inhalation rat 259 mg/l/4h (100-41-4) LD50 oral rat 3500 mg/kg LD50 dermal rabbit 15354 mg/kg LC50 inhalation rat 17.2 mg/l/4h Naphthalene (91-20-3) LD50 oral rat 490 mg/kg LD50 dermal rabbit > 20 g/kg LC50 inhalation rat > 340 mg/m³ (Exposure time: 1 h) Benzene (71-43-2) LD50 oral rat 930 (930 - 6400) mg/kg LD50 dermal rabbit > 8272 mg/kg LC50 inhalation rat 34.4 mg/l/4h Biphenyl (92-52-4) LD50 oral rat 2140 (2140 - 2400) mg/kg LD50 dermal rabbit > 5010 mg/kg Cumene (98-82-8) LD50 oral rat 1400 mg/kg LD50 dermal rat 10600 mg/kg LC50 inhalation rat 39 mg/l/4h Skin corrosion/irritation : Causes skin irritation. Diesel (64742-80-9) Skin Irritation Data Primary Irritation Index = 4.3-5.6 Serious eye damage/irritation : Causes eye irritation. Based on available data, the classification criteria are not met Mixed Product Eye Corrosion / Irritation Data ECHA Study Report dated: 1986-12-18 Rabbit Cornea Opacity: 0; Overall Irritation Score: ~ 0.2; Conjunctive redness: ~0.06; Cornea edema (chemosis): 0; fully reversible within: 72 hrs ECHA Study Report dated: 1985-04-16 Rabbit Cornea Opacity: 0; Overall Irritation Score: 0.33; Conjunctive redness: ~0.06; Cornea edema (chemosis): ~0.83; fully reversible within: 72 hrs Gasoline (86290-81-5) Eye Corrosion / Irritation Data ECHA Study Report dated: 1986-12-18 Rabbit Cornea Opacity: 0; Overall Irritation Score: ~ Page 676 of 1287 Page 676 of 1287 Page 676 of 1287 Page 676 of 1287 ---PAGE BREAK--- Mixed Product Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 7/11 0.2; Conjunctive redness: ~0.06; Cornea edema (chemosis): 0; fully reversible within: 72 hrs ECHA Study Report dated: 1985-04-16 Rabbit Cornea Opacity: 0; Overall Irritation Score: 0.33; Conjunctive redness: ~0.06; Cornea edema (chemosis): ~0.83; fully reversible within: 72 hrs Diesel (64742-80-9) Eye Corrosion / Irritation Data Overall Irritation Score: 1 Irritation was reversible at 48 hours post exposure. Classification 2B Respiratory or skin sensitization : Not classified Germ cell mutagenicity : May cause genetic defects. Carcinogenicity : May cause cancer. Toluene (108-88-3) IARC group 3 - Not classifiable Xylenes p- isomers) (1330-20-7) IARC group 3 - Not classifiable Gasoline (86290-81-5) IARC group 2B - Possibly carcinogenic to humans (100-41-4) IARC group 2B - Possibly carcinogenic to humans Naphthalene (91-20-3) IARC group 2B - Possibly carcinogenic to humans National Toxicology Program (NTP) Status 2 - Reasonably anticipated to be Human Carcinogen Benzene (71-43-2) IARC group 1 - Carcinogenic to humans National Toxicology Program (NTP) Status 1 - Known Human Carcinogens OSHA Carcinogen Status In OSHA Specifically Regulated Carcinogen list Additional information Benzene is a known human carcinogen and is known to cause acute myeloid leukemia & (disease that affects the bone marrow and blood) in humans who have been repeatedly exposed to benzene. Cumene (98-82-8) IARC group 2B - Possibly carcinogenic to humans Aromatic Compounds (130498-29-2) National Toxicology Program (NTP) Status 2 - Reasonably anticipated to be Human Carcinogen Additional information This product may contain aromatic hydrocarbons, PAHs (also called polynuclear aromatics, PNAs or Aromatic Hydrocarbons, some of which are suspected of causing skin cancer in humans under conditions of poor personal hygiene and prolonged, repeated contact. Wear chemically impervious gloves. Always wash skin with soap and water after skin contact. Reproductive toxicity : Suspected of damaging fertility or the unborn child. Specific target organ toxicity (single exposure) : May cause drowsiness or dizziness. May cause respiratory irritation. Causes damage to organs (blood, lung). May cause damage to organs (immune system, eye). Specific target organ toxicity (repeated exposure) : Causes damage to organs (blood, hematopoietic system [blood forming], kidneys, peripheral nervous system, nervous system, brain (neurological), hearing organ (loss of hearing), visual organ (color vision effects), eye) through prolonged or repeated exposure. May cause damage to organs (lung, nose) through prolonged or repeated exposure. Aspiration hazard : May be fatal if swallowed and enters airways. Section 12: Ecological information 12.1. Toxicity No additional information available 12.2. Persistence and degradability Mixed Product Persistence and degradability Not established. 12.3. Bioaccumulative potential Mixed Product Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Other information : Avoid release to the environment. Page 677 of 1287 Page 677 of 1287 Page 677 of 1287 Page 677 of 1287 ---PAGE BREAK--- Mixed Product Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 8/11 Section 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents and container in accordance with all local, regional, national and international regulations. Additional information : Handle empty containers with care because residual vapors are flammable. Ecology - waste materials : Avoid release to the environment. Hazardous waste due to toxicity. Section 14: Transport information US Transport (DOT) for Bulk Shipments (Non-Bulk Shipments May Differ) Transport document description : UN1203, Gasoline, 3, PGII UN or NA Number : UN1203 Proper Shipping Name : Gasoline Primary Hazard Class : 3 - Flammable liquid Packing Group : PGII Hazard labels : Emergency Response Guide (ERG) Number : 128 In accordance with the definition in 49 CFR § 171.8, a hazardous substance does not include petroleum, including crude oil or any fraction thereof which is not other specifically listed or designated as such in Appendix A to 49 CFR § 172.101. Therefore, this product does not require a RQ designation. Transport by sea (IMDG) Not evaluated. Air transport (IATA) Not evaluated. Section 15: Regulatory information 15.1. US Federal regulations EPA TSCA Status Under TSCA gasoline is a mixture. All components of this mixture are listed on TSCA. SARA Section 313 Supplier Notification This product contains the following toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR 372: CAS number Chemical name Concentration 108-88-3 Toluene 0 - 25% 1330-20-7 Xylenes p- isomers) 0 - 15% 100-41-4 0 - 5% 91-20-3 Naphthalene 0 - 4% 71-43-2 Benzene 0 - 2% 98-82-8 Cumene < 1% 130498-29-2 Aromatic Compounds < 0.5% This information must be included in all Safety Data Sheets that are copied and distributed for this product. For additional information, see 40 CFR §372.45 Notification About Toxic Chemicals. SARA Section 311/312 Hazard Classes Fire hazard Chronic health hazard Acute health hazard Page 678 of 1287 Page 678 of 1287 Page 678 of 1287 Page 678 of 1287 ---PAGE BREAK--- Mixed Product Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 9/11 15.2. International regulations CANADA Mixed Product WHMIS Classification Class B Division 2 - Flammable Liquid National inventories Listed on the AICS (Australian Inventory of Chemical Substances) Listed on the Canadian DSL (Domestic Sustances List) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on the Philippines Inventory of Chemicals and Chemical Substances (PICCS) 15.3. US State regulations Toluene (108-88-3) U.S. - California - Proposition 65 - Carcinogens List No U.S. - California - Proposition 65 - Developmental Toxicity Yes U.S. - California - Proposition 65 - Reproductive Toxicity - Female Yes U.S. - California - Proposition 65 - Reproductive Toxicity - Male No (100-41-4) U.S. - California - Proposition 65 - Carcinogens List Yes U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No Non-significant risk level (NSRL) 54 µg/day (inhalation) Naphthalene (91-20-3) U.S. - California - Proposition 65 - Carcinogens List Yes U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No Non-significant risk level (NSRL) 5.8 µg/day Benzene (71-43-2) U.S. - California - Proposition 65 - Carcinogens List Yes U.S. - California - Proposition 65 - Developmental Toxicity Yes U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male Yes Non-significant risk level (NSRL) 6.4 µg/day (oral) Cumene (98-82-8) U.S. - California - Proposition 65 - Carcinogens List Yes U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No Section 16: Other information Other information : None. NFPA (National Fire Protection Association) NFPA health hazard : 1 NFPA fire hazard : 3 NFPA reactivity : 0 Page 679 of 1287 Page 679 of 1287 Page 679 of 1287 Page 679 of 1287 ---PAGE BREAK--- Mixed Product Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 10/11 HMIS III Rating Health : 1* Flammability : 3 Physical Hazard : 0 Personal Protection : See section 8 of SDS US OSHA LABEL as specified under 29 CFR §1910.1200 Mixed Product Total Petrochemicals & Refining USA, Inc. PO Box 674411 Houston, TX 77267-4411 USA Tel. [PHONE REDACTED] or 1-[PHONE REDACTED] Danger Extremely flammable liquid and vapor May be fatal if swallowed and enters airways Causes skin irritation Causes eye irritation May cause respiratory irritation May cause drowsiness or dizziness May cause genetic defects May cause cancer Suspected of damaging fertility or the unborn child Causes damage to organs (blood, lung) May cause damage to organs (immune system, eye) Causes damage to organs (blood, hematopoietic system [blood forming], kidneys, peripheral nervous system, nervous system, brain (neurological), hearing organ (loss of hearing), visual organ (color vision effects), eye) through prolonged or repeated exposure May cause damage to organs (lung, nose) through prolonged or repeated exposure Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from sparks, open flames, heat, hot surfaces. - No smoking. Keep container closed. Ground/bond container and receiving equipment. Use explosion-proof electrical, lighting, ventilating equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe spray, mist, vapors. Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear flame retardant protective clothing, impermeable protective gloves, eye protection. If swallowed: Immediately call doctor, poison center. Do NOT induce vomiting. If on skin: Wash with plenty of water. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Specific treatment (see Section 4.1 of SDS or information on this label). If exposed or concerned: Get medical advice/attention. Get medical advice/attention if you feel unwell. Take off contaminated clothing and wash it before reuse. In case of fire: Use Water spray, foam, carbon dioxide (CO2), dry chemical to extinguish. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. Unknown acute toxicity 37.62 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation (Vapours)) Supplemental Information Product can accumulate electrostatic charges that may cause fire by electrical discharges. Version : 1.2 Date of issue : July 24, 2015 Page 680 of 1287 Page 680 of 1287 Page 680 of 1287 Page 680 of 1287 ---PAGE BREAK--- Mixed Product Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 11/11 MSDS ID: MIXED_PROD SDS REFERENCE NUMBER: RF0027 SDS Template - TOTAL SDS US (GHS HazCom 2012) TPRI Version 4.01 The information contained in this Safety Data Sheet (SDS) is believed by Total Petrochemicals & Refining USA, Inc. (TPRI) to be accurate on the date issued. However, materials may present unknown hazards and should be used with caution. Final determination of suitability and use of any material is the sole responsibility of the user. Neither TPRI nor any of its subsidiaries or affiliated companies assumes any liability whatsoever for the accuracy or completeness of the information contained herein or reliance thereto. If the material is repackaged, the user is responsible and must ensure that proper health, safety and other necessary information is included with the material and/or on the container. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING THE MATERIALS OR THE INFORMATION CONTAINED IN THIS SDS. ALTERATION OF THIS DOCUMENT IS STRICTLY PROHIBITED. Page 681 of 1287 Page 681 of 1287 Page 681 of 1287 Page 681 of 1287 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 16 Mar 2015 Page 1 of 10 SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Product Description: Base Oil and Additives Product Code: 201520403540, 440461-00, 971601 Intended Use: Engine oil COMPANY IDENTIFICATION Supplier: EXXON MOBIL CORPORATION 22777 Springwoods Village Parkway Spring, TX. 77389 USA 24 Hour Health Emergency [PHONE REDACTED] Transportation Emergency Phone [PHONE REDACTED] or [PHONE REDACTED] CHEMTREC Product Technical Information [PHONE REDACTED] MSDS Internet Address http://www.exxon.com, http://www.mobil.com SECTION 2 HAZARDS IDENTIFICATION This material is not hazardous according to regulatory guidelines (see (M)SDS Section 15). Other hazard information: HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200. PHYSICAL / CHEMICAL HAZARDS No significant hazards. HEALTH HAZARDS High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, or respiratory irritation. ENVIRONMENTAL HAZARDS No significant hazards. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 Page 682 of 1287 Page 682 of 1287 Page 682 of 1287 Page 682 of 1287 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 16 Mar 2015 Page 2 of 10 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS This material is defined as a mixture. Hazardous Substance(s) or Complex Substance(s) required for disclosure Name CAS# Concentration* GHS Hazard Codes ZINC ALKYL DITHIOPHOSPH ATE 113706-15-3 0.1 - < 1% H303, H315, H318, H401, H411 * All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. As per paragraph of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and exact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact percentage composition will be provided to health professionals, employees, or designated representatives in accordance with applicable provisions of paragraph SECTION 4 FIRST AID MEASURES INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Page 683 of 1287 Page 683 of 1287 Page 683 of 1287 Page 683 of 1287 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 16 Mar 2015 Page 3 of 10 Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Oxides of carbon, Sulfur oxides, Aldehydes, Incomplete combustion products, Smoke, Fume FLAMMABILITY PROPERTIES Flash Point [Method]: 215°C (419°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802. PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended. SPILL MANAGEMENT Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and Page 684 of 1287 Page 684 of 1287 Page 684 of 1287 Page 684 of 1287 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 16 Mar 2015 Page 4 of 10 speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE HANDLING Avoid contact with used product. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present during switch-loading operations). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. STORAGE The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols can occur the following are recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction), 5 mg/m³ - OSHA PEL. NOTE: Limits/standards shown for guidance only. Follow applicable regulations. No biological limits allocated. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Page 685 of 1287 Page 685 of 1287 Page 685 of 1287 Page 685 of 1287 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 16 Mar 2015 Page 5 of 10 Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Physical State: Liquid Color: Brown Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 0.875 Flammability (Solid, Gas): N/A Flash Point [Method]: 215°C (419°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Page 686 of 1287 Page 686 of 1287 Page 686 of 1287 Page 686 of 1287 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 16 Mar 2015 Page 6 of 10 Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) [Estimated] Decomposition Temperature: N/D Vapor Density (Air = > 2 at 101 kPa [Estimated] Vapor Pressure: 0.013 kPa (0.1 mm Hg) at 20 °C [Estimated] Evaporation Rate (n-butyl acetate = N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 [Estimated] Solubility in Water: Negligible Viscosity: 74 cSt (74 mm2/sec) at 40 °C I 11.5 cSt (11.5 mm2/sec) at 100°C Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -27°C (-17°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt SECTION 10 STABILITY AND REACTIVITY REACTIVITY: See sub-sections below. STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS Hazard Class Conclusion / Remarks Inhalation Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Ingestion Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Corrosion/Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on assessment of the components. Eye Page 687 of 1287 Page 687 of 1287 Page 687 of 1287 Page 687 of 1287 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 16 Mar 2015 Page 7 of 10 Serious Eye Damage/Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components. Sensitization Respiratory Sensitization: No end point data for material. Not expected to be a respiratory sensitizer. Skin Sensitization: No end point data for material. Not expected to be a skin sensitizer. Based on assessment of the components. Aspiration: Data available. Not expected to be an aspiration hazard. Based on physico-chemical properties of the material. Germ Cell Mutagenicity: No end point data for material. Not expected to be a germ cell mutagen. Based on assessment of the components. Carcinogenicity: No end point data for material. Not expected to cause cancer. Based on assessment of the components. Reproductive Toxicity: No end point data for material. Not expected to be a reproductive toxicant. Based on assessment of the components. Lactation: No end point data for material. Not expected to cause harm to breast-fed children. Specific Target Organ Toxicity (STOT) Single Exposure: No end point data for material. Not expected to cause organ damage from a single exposure. Repeated Exposure: No end point data for material. Not expected to cause organ damage from prolonged or repeated exposure. Based on assessment of the components. OTHER INFORMATION For the product itself: Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Oils that are used in gasoline engines may become hazardous and display the following properties: Carcinogenic in animal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains aromatic compounds (PAC) from combustion products of gasoline and/or thermal degradation products. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION Page 688 of 1287 Page 688 of 1287 Page 688 of 1287 Page 688 of 1287 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 16 Mar 2015 Page 8 of 10 The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Not expected to be harmful to aquatic organisms. MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. Protect the environment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents, brake fluids or coolants. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION Page 689 of 1287 Page 689 of 1287 Page 689 of 1287 Page 689 of 1287 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 16 Mar 2015 Page 9 of 10 LAND (DOT): Not Regulated for Land Transport LAND (TDG): Not Regulated for Land Transport SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code Marine Pollutant: No AIR (IATA): Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with OSHA HazCom 2012, 29 CFR 1910.1200. Listed or exempt from listing/notification on the following chemical inventories: DSL, KECI, TSCA Special Cases: Inventory Status AICS Restrictions Apply EPCRA SECTION 302: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. The following ingredients are cited on the lists below: Chemical Name CAS Number List Citations DIPHENYLAMINE 122-39-4 18 ZINC ALKYL DITHIOPHOSPHATE 113706-15-3 15 --REGULATORY LISTS SEARCHED-- 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK 5 = TSCA 4 10 = CA P65 CARC 15 = MI 293 Page 690 of 1287 Page 690 of 1287 Page 690 of 1287 Page 690 of 1287 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 16 Mar 2015 Page 10 of 10 Code key: CARC=Carcinogen; REPRO=Reproductive SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only): H303: May be harmful if swallowed; Acute Tox Oral, Cat 5 H315: Causes skin irritation; Skin Corr/Irritation, Cat 2 H318: Causes serious eye damage; Serious Eye Damage/Irr, Cat 1 H401: Toxic to aquatic life; Acute Env Tox, Cat 2 H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Updates made in accordance with implementation of GHS requirements. The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re- publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A DGN: 2003209XUS (543097) Copyright 2002 Exxon Mobil Corporation, All rights reserved Page 691 of 1287 Page 691 of 1287 Page 691 of 1287 Page 691 of 1287 ---PAGE BREAK--- Product Name: MOBIL DELVAC ATF Revision Date: 10 Apr 2015 Page 1 of 10 SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: MOBIL DELVAC ATF Product Description: Base Stocks and Additives Product Code: 201530301010, 520361-00, 97Z482 Intended Use: Automatic transmission fluid COMPANY IDENTIFICATION Supplier: EXXON MOBIL CORPORATION 22777 Springwoods Village Parkway Spring, TX. 77389 USA 24 Hour Health Emergency [PHONE REDACTED] Transportation Emergency Phone [PHONE REDACTED] or [PHONE REDACTED] CHEMTREC Product Technical Information [PHONE REDACTED] MSDS Internet Address http://www.exxon.com, http://www.mobil.com SECTION 2 HAZARDS IDENTIFICATION This material is not hazardous according to regulatory guidelines (see (M)SDS Section 15). Other hazard information: HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200. PHYSICAL / CHEMICAL HAZARDS No significant hazards. HEALTH HAZARDS High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, or respiratory irritation. ENVIRONMENTAL HAZARDS No significant hazards. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. Page 692 of 1287 Page 692 of 1287 Page 692 of 1287 Page 692 of 1287 ---PAGE BREAK--- Product Name: MOBIL DELVAC ATF Revision Date: 10 Apr 2015 Page 2 of 10 SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS This material is defined as a mixture. Hazardous Substance(s) or Complex Substance(s) required for disclosure Name CAS# Concentration* GHS Hazard Codes 1-DECENE, HOMOPOLYMER HYDROGENATED 68037-01-4 20 - < 30% H304 2,6-DITERTBUTYL PHENOL 128-39-2 0.1 - < 1% H315, H319(2A), H400(M factor H410(M factor 1) ALKOXYLATED LONG-CHAIN ALKYL AMINE 61791-44-4 0.1 - < 1% H302, H317, H314(1B), H402, H412 POLYALKYL METHACRYLATE CONFIDENTIA L 1 - < 5% H319(2A) * All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. As per paragraph of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and exact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact percentage composition will be provided to health professionals, employees, or designated representatives in accordance with applicable provisions of paragraph SECTION 4 FIRST AID MEASURES INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Page 693 of 1287 Page 693 of 1287 Page 693 of 1287 Page 693 of 1287 ---PAGE BREAK--- Product Name: MOBIL DELVAC ATF Revision Date: 10 Apr 2015 Page 3 of 10 Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Aldehydes, Sulfur oxides, Oxides of carbon, Incomplete combustion products, Smoke, Fume FLAMMABILITY PROPERTIES Flash Point [Method]: 242°C (468°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802. PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. SPILL MANAGEMENT Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. Page 694 of 1287 Page 694 of 1287 Page 694 of 1287 Page 694 of 1287 ---PAGE BREAK--- Product Name: MOBIL DELVAC ATF Revision Date: 10 Apr 2015 Page 4 of 10 SECTION 7 HANDLING AND STORAGE HANDLING Avoid contact with skin. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present during switch-loading operations). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. STORAGE The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMIT VALUES Exposure limits/standards (Note: Exposure limits are not additive) Substance Name Form Limit / Standard NOTE Source 1-DECENE, HOMOPOLYMER HYDROGENATED Aerosols (thoracic fraction) TWA 5 mg/m3 N/A ExxonMobil Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols can occur the following are recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction), 5 mg/m³ - OSHA PEL. NOTE: Limits/standards shown for guidance only. Follow applicable regulations. No biological limits allocated. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a Page 695 of 1287 Page 695 of 1287 Page 695 of 1287 Page 695 of 1287 ---PAGE BREAK--- Product Name: MOBIL DELVAC ATF Revision Date: 10 Apr 2015 Page 5 of 10 level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: Chemical resistant gloves are recommended. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: Chemical/oil resistant clothing is recommended. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Physical State: Liquid Color: Red Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 0.85 [ASTM D4052] Flammability (Solid, Gas): N/A Flash Point [Method]: 242°C (468°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) Decomposition Temperature: N/D Page 696 of 1287 Page 696 of 1287 Page 696 of 1287 Page 696 of 1287 ---PAGE BREAK--- Product Name: MOBIL DELVAC ATF Revision Date: 10 Apr 2015 Page 6 of 10 Vapor Density (Air = > 2 at 101 kPa Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C Evaporation Rate (n-butyl acetate = N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 36 cSt (36 mm2/sec) at 40 °C I 7.2 cSt (7.2 mm2/sec) at 100°C [ASTM D 445] Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -54°C (-65°F) [ASTM D97] SECTION 10 STABILITY AND REACTIVITY REACTIVITY: See sub-sections below. STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS Hazard Class Conclusion / Remarks Inhalation Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components. Ingestion Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Corrosion/Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on assessment of the components. Eye Serious Eye Damage/Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components. Sensitization Respiratory Sensitization: No end point data for material. Not expected to be a respiratory sensitizer. Page 697 of 1287 Page 697 of 1287 Page 697 of 1287 Page 697 of 1287 ---PAGE BREAK--- Product Name: MOBIL DELVAC ATF Revision Date: 10 Apr 2015 Page 7 of 10 Skin Sensitization: No end point data for material. Not expected to be a skin sensitizer. Aspiration: Data available. Not expected to be an aspiration hazard. Based on physico- chemical properties of the material. Germ Cell Mutagenicity: No end point data for material. Not expected to be a germ cell mutagen. Based on assessment of the components. Carcinogenicity: No end point data for material. Not expected to cause cancer. Based on assessment of the components. Reproductive Toxicity: No end point data for material. Not expected to be a reproductive toxicant. Based on assessment of the components. Lactation: No end point data for material. Not expected to cause harm to breast-fed children. Specific Target Organ Toxicity (STOT) Single Exposure: No end point data for material. Not expected to cause organ damage from a single exposure. Repeated Exposure: No end point data for material. Not expected to cause organ damage from prolonged or repeated exposure. Based on assessment of the components. TOXICITY FOR SUBSTANCES NAME ACUTE TOXICITY ALKOXYLATED LONG-CHAIN ALKYL AMINE Oral Lethality: LD50 1350 mg/kg (Rat) OTHER INFORMATION Contains: base oils: Not expected to cause significant health effects under conditions of normal use, based on laboratory studies with the same or similar materials. Not mutagenic or genotoxic. Not sensitizing in test animals and humans. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Not expected to be harmful to aquatic organisms. MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. Page 698 of 1287 Page 698 of 1287 Page 698 of 1287 Page 698 of 1287 ---PAGE BREAK--- Product Name: MOBIL DELVAC ATF Revision Date: 10 Apr 2015 Page 8 of 10 PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (DOT): Not Regulated for Land Transport LAND (TDG): Not Regulated for Land Transport SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code Marine Pollutant: No Page 699 of 1287 Page 699 of 1287 Page 699 of 1287 Page 699 of 1287 ---PAGE BREAK--- Product Name: MOBIL DELVAC ATF Revision Date: 10 Apr 2015 Page 9 of 10 AIR (IATA): Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with OSHA HazCom 2012, 29 CFR 1910.1200. Listed or exempt from listing/notification on the following chemical inventories: DSL, KECI, PICCS, TSCA Special Cases: Inventory Status ENCS Restrictions Apply EPCRA SECTION 302: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK 5 = TSCA 4 10 = CA P65 CARC 15 = MI 293 Code key: CARC=Carcinogen; REPRO=Reproductive SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only): H302: Harmful if swallowed; Acute Tox Oral, Cat 4 H304: May be fatal if swallowed and enters airways; Aspiration, Cat 1 H314(1B): Causes severe skin burns and eye damage; Skin Corr/Irritation, Cat 1B H315: Causes skin irritation; Skin Corr/Irritation, Cat 2 H317: May cause allergic skin reaction; Skin Sensitization, Cat 1 H319(2A): Causes serious eye irritation; Serious Eye Damage/Irr, Cat 2A Page 700 of 1287 Page 700 of 1287 Page 700 of 1287 Page 700 of 1287 ---PAGE BREAK--- Product Name: MOBIL DELVAC ATF Revision Date: 10 Apr 2015 Page 10 of 10 H400: Very toxic to aquatic life; Acute Env Tox, Cat 1 H402: Harmful to aquatic life; Acute Env Tox, Cat 3 H410: Very toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 1 H412: Harmful to aquatic life with long lasting effects; Chronic Env Tox, Cat 3 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Updates made in accordance with implementation of GHS requirements. The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re- publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0 PPEC: C DGN: 7040854XUS (1019277) Copyright 2002 Exxon Mobil Corporation, All rights reserved Page 701 of 1287 Page 701 of 1287 Page 701 of 1287 Page 701 of 1287 ---PAGE BREAK--- Product Name: MOBIL SHC 630 Revision Date: 19 May 2015 Page 1 of 12 SAFETY DATA SHEET SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING As of the revision date above, this (M)SDS meets the regulations in the United Kingdom & Ireland. 1.1. PRODUCT IDENTIFIER Product Name: MOBIL SHC 630 Product Description: Base Stocks and Additives Product Code: 201560500550, 400406, 602953-60 1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST Intended Use: Gear oil Uses advised against: None unless specified elsewhere in this SDS. 1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET Supplier: EXXONMOBIL MARINE LIMITED EXXONMOBIL HOUSE MAILPOINT 31, ERMYN WAY KT22 8UX LEATHERHEAD United Kingdom Supplier General Contact: +44 1372 222 000 E-Mail: [EMAIL REDACTED] 1.4. EMERGENCY TELEPHONE NUMBER 24 Hour Environmental / Health Emergency Telephone: +44 (0)23 80891558 SECTION 2 HAZARDS IDENTIFICATION 2.1. CLASSIFICATION OF SUBSTANCE OR MIXTURE Classification according to Regulation (EC) No 1272/2008 Not Classified Page 702 of 1287 Page 702 of 1287 Page 702 of 1287 Page 702 of 1287 ---PAGE BREAK--- Product Name: MOBIL SHC 630 Revision Date: 19 May 2015 Page 2 of 12 Classification according to EU Directive 67/548/EEC / 1999/45 EC Not Classified 2.2. LABEL ELEMENTS No Label elements according to Regulation (EC) No 1272/2008 2.3. OTHER HAZARDS Physical / Chemical Hazards: No significant hazards. Health Hazards: High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, or respiratory irritation. Environmental Hazards: No significant hazards. Material does not meet the criteria for PBT or vPvB in accordance with REACH Annex XIII. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS 3.1. SUBSTANCES Not Applicable. This material is regulated as a mixture. 3.2. MIXTURES This material is defined as a mixture. Reportable hazardous substance(s) complying with the classification criteria and/or with an exposure limit (OEL) Name CAS# EC# Registration# Concentration* GHS/CLP classification Dec-1-ene, homopolymer, hydrogenated Dec-1-ene, oligomers, hydrogenated 68037-01-4 01-[PHONE REDACTED]- 34 20 - < 30% Asp. Tox. 1 H304 TRIPHENYL PHOSPHATE 115-86-6 204-112-2 NE 0.1 - < 0.25% Aquatic Acute 1 H400 (M factor Aquatic Chronic 1 H410 (M factor 1) Note - any classification in brackets is a GHS building block that was not adopted by the EU in the CLP regulation (No 1272/2008) and therefore is not applicable in the EU or in non-EU countries which have implemented the CLP regulation and is shown for informational purposes only. Name CAS# EC# Registration# Concentration* DSD Symbols/Risk Phrases TRIPHENYL PHOSPHATE 115-86-6 204-112-2 NE 0.1 - < 0.25% N;R50/53 * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Page 703 of 1287 Page 703 of 1287 Page 703 of 1287 Page 703 of 1287 ---PAGE BREAK--- Product Name: MOBIL SHC 630 Revision Date: 19 May 2015 Page 3 of 12 Note: See (M)SDS Section 16 for full text of the R-Phrases. See (M)SDS Section 16 for full text of hazard statements. SECTION 4 FIRST AID MEASURES 4.1. DESCRIPTION OF FIRST AID MEASURES INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. 4.2. MOST IMPORTANT AND EFFECTS, BOTH ACUTE AND DELAYED Local necrosis as evidenced by delayed onset of pain and tissue damage a few hours after injection. 4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED The need to have special means for providing specific and immediate medical treatment available in the workplace is not expected. SECTION 5 FIRE FIGHTING MEASURES 5.1. EXTINGUISHING MEDIA Suitable Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Unsuitable Extinguishing Media: Straight streams of water 5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE Hazardous Combustion Products: Incomplete combustion products, Oxides of carbon, Smoke, Fume, Sulphur oxides, Aldehydes 5.3. ADVICE FOR FIRE FIGHTERS Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering Page 704 of 1287 Page 704 of 1287 Page 704 of 1287 Page 704 of 1287 ---PAGE BREAK--- Product Name: MOBIL SHC 630 Revision Date: 19 May 2015 Page 4 of 12 streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. FLAMMABILITY PROPERTIES Flash Point [Method]: >210°C (410°F) [ASTM D-92] Upper/Lower Flammable Limits (Approximate volume % in air): UEL: 7.0 LEL: 0.9 [Estimated] Autoignition Temperature: No data available SECTION 6 ACCIDENTAL RELEASE MEASURES 6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. 6.2. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. 6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. 6.4. REFERENCES TO OTHER SECTIONS See Sections 8 and 13. SECTION 7 HANDLING AND STORAGE 7.1. PRECAUTIONS FOR SAFE HANDLING Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present during switch-loading Page 705 of 1287 Page 705 of 1287 Page 705 of 1287 Page 705 of 1287 ---PAGE BREAK--- Product Name: MOBIL SHC 630 Revision Date: 19 May 2015 Page 5 of 12 operations). Use proper bonding and/or earthing procedures. However, bonding and earthing may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. 7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store in open or unlabelled containers. 7.3. SPECIFIC END USES: Section 1 informs about identified end-uses. No industrial or sector specific guidance available. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1. CONTROL PARAMETERS EXPOSURE LIMIT VALUES Exposure limits/standards (Note: Exposure limits are not additive) Substance Name Form Limit/Standard Note Source Dec-1-ene, homopolymer, hydrogenated Dec-1-ene, oligomers, hydrogenated Aerosols (thoracic fraction) TWA 5 mg/m3 ExxonMobil TRIPHENYL PHOSPHATE STEL 6 mg/m3 UK EH40 TRIPHENYL PHOSPHATE TWA 3 mg/m3 UK EH40 TRIPHENYL PHOSPHATE TWA 3 mg/m3 ACGIH UK EH40 Workplace Exposure Limits. Exposure limits for use with Control of Substances Hazardous to Health Regulations 2002 (as amended) Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols can occur the following is recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction). Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/institute(s): UK Health and Safety Executive (HSE) Page 706 of 1287 Page 706 of 1287 Page 706 of 1287 Page 706 of 1287 ---PAGE BREAK--- Product Name: MOBIL SHC 630 Revision Date: 19 May 2015 Page 6 of 12 8.2. EXPOSURE CONTROLS ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS Page 707 of 1287 Page 707 of 1287 Page 707 of 1287 Page 707 of 1287 ---PAGE BREAK--- Product Name: MOBIL SHC 630 Revision Date: 19 May 2015 Page 7 of 12 Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. 9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Colour: Orange Odour: Characteristic Odour Threshold: No data available pH: Not technically feasible Melting Point: Not technically feasible Freezing Point: No data available Initial Boiling Point / and Boiling Range: > 316°C (600°F) [Estimated] Flash Point [Method]: >210°C (410°F) [ASTM D-92] Evaporation Rate (n-butyl acetate = No data available Flammability (Solid, Gas): Not technically feasible Upper/Lower Flammable Limits (Approximate volume % in air): UEL: 7.0 LEL: 0.9 [Estimated] Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C [Estimated] Vapour Density (Air = > 2 at 101 kPa [Estimated] Relative Density (at 15 0.854 [ASTM D4052] Solubility(ies): water Negligible Partition coefficient (n-Octanol/Water Partition Coefficient): > 3.5 [Estimated] Autoignition Temperature: No data available Decomposition Temperature: No data available Viscosity: 220 cSt (220 mm2/sec) at 40ºC I 28.5 cSt (28.5 mm2/sec) at 100°C [ASTM D 445] Explosive Properties: None Oxidizing Properties: None 9.2. OTHER INFORMATION Pour Point: -36°C (-33°F) [ASTM D5950] SECTION 10 STABILITY AND REACTIVITY 10.1. REACTIVITY: See sub-sections below. 10.2. CHEMICAL STABILITY: Material is stable under normal conditions. 10.3. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. 10.4. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. Page 708 of 1287 Page 708 of 1287 Page 708 of 1287 Page 708 of 1287 ---PAGE BREAK--- Product Name: MOBIL SHC 630 Revision Date: 19 May 2015 Page 8 of 12 10.5. INCOMPATIBLE MATERIALS: Strong oxidisers 10.6. HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. SECTION 11 TOXICOLOGICAL INFORMATION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS Hazard Class Conclusion / Remarks Inhalation Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Ingestion Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Corrosion/Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on assessment of the components. Eye Serious Eye Damage/Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components. Sensitisation Respiratory Sensitization: No end point data for material. Not expected to be a respiratory sensitizer. Skin Sensitization: No end point data for material. Not expected to be a skin sensitizer. Based on assessment of the components. Aspiration: Data available. Not expected to be an aspiration hazard. Based on physico-chemical properties of the material. Germ Cell Mutagenicity: No end point data for material. Not expected to be a germ cell mutagen. Based on assessment of the components. Carcinogenicity: No end point data for material. Not expected to cause cancer. Based on assessment of the components. Reproductive Toxicity: No end point data for material. Not expected to be a reproductive toxicant. Based on assessment of the components. Lactation: No end point data for material. Not expected to cause harm to breast-fed children. Specific Target Organ Toxicity (STOT) Single Exposure: No end point data for material. Not expected to cause organ damage from a single exposure. Repeated Exposure: No end point data for material. Not expected to cause organ damage from prolonged or repeated exposure. Based on assessment of the components. OTHER INFORMATION Contains: base oils: Not expected to cause significant health effects under conditions of normal use, based on laboratory studies with the same or similar materials. Not mutagenic or genotoxic. Not sensitising in test animals and humans. Page 709 of 1287 Page 709 of 1287 Page 709 of 1287 Page 709 of 1287 ---PAGE BREAK--- Product Name: MOBIL SHC 630 Revision Date: 19 May 2015 Page 9 of 12 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. 12.1. TOXICITY Material Not expected to be harmful to aquatic organisms. Material Not expected to demonstrate chronic toxicity to aquatic organisms 12.2. PERSISTENCE AND DEGRADABILITY Not determined. 12.3. BIOACCUMULATIVE POTENTIAL Not determined. 12.4. MOBILITY IN SOIL Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. 12.5. PERSISTENCE, BIOACCUMULATION AND TOXICITY FOR SUBSTANCE(S) This product is not, or does not contain, a substance that is a PBT or a vPvB. 12.6. OTHER ADVERSE EFFECTS No adverse effects are expected. ECOLOGICAL DATA Ecotoxicity Test Duration Organism Type Test Results Aquatic - Acute Toxicity 96 hour(s) mykiss LL50 1003 mg/l: data for similar materials Aquatic - Chronic Toxicity 21 day(s) Daphnia magna NOELR 1 mg/l: data for similar materials SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. 13.1. WASTE TREATMENT METHODS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. Protect the environment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents, brake fluids or coolants. REGULATORY DISPOSAL INFORMATION Page 710 of 1287 Page 710 of 1287 Page 710 of 1287 Page 710 of 1287 ---PAGE BREAK--- Product Name: MOBIL SHC 630 Revision Date: 19 May 2015 Page 10 of 12 European Waste Code: 13 02 06* NOTE: These codes are assigned based upon the most common uses for this material and may not reflect contaminants resulting from actual use. Waste producers need to assess the actual process used when generating the waste and its contaminants in order to assign the proper waste disposal code(s). This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and subject to the provisions of that Directive unless Article 1(5) of that Directive applies. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (ADR/RID): 14.1-14.6 Not Regulated for Land Transport INLAND WATERWAYS (ADNR/ADN): 14.1-14.6 Not Regulated for Inland Waterways Transport SEA (IMDG): 14.1-14.6 Not Regulated for Sea Transport according to IMDG-Code SEA (MARPOL 73/78 Convention - Annex II): 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not classified according to Annex II AIR (IATA): 14.1-14.6 Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Listed or exempt from listing/notification on the following chemical inventories: IECSC, KECI, TSCA Special Cases: Inventory Status AICS Restrictions Apply NDSL Restrictions Apply Page 711 of 1287 Page 711 of 1287 Page 711 of 1287 Page 711 of 1287 ---PAGE BREAK--- Product Name: MOBIL SHC 630 Revision Date: 19 May 2015 Page 11 of 12 15.1. SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE SUBSTANCE OR MIXTURE Applicable EU Directives and Regulations: 1907/2006 on the Registration, Evaluation, Authorisation and Restriction of Chemicals and amendments thereto] 689/2008/EC [....concerning the export and import of dangerous substances and amendments thereto] 1272/2008 [on classification, labelling and packaging of substances and mixtures.. and amendments thereto] 15.2. CHEMICAL SAFETY ASSESSMENT REACH Information: A Chemical Safety Assessment has been carried out for one or more substances present in the material. SECTION 16 OTHER INFORMATION REFERENCES: Sources of information used in preparing this SDS included one or more of the following: results from in house or supplier toxicology studies, CONCAWE Product Dossiers, publications from other trade associations, such as the EU Hydrocarbon Solvents REACH Consortium, U.S. HPV Program Robust Summaries, the EU IUCLID Data Base, U.S. NTP publications, and other sources, as appropriate. List of abbreviations and acronyms that could be (but not necessarily are) used in this safety data sheet: Acronym Full text N/A Not applicable N/D Not determined NE Not established VOC Volatile Organic Compound AICS Australian Inventory of Chemical Substances AIHA WEEL American Industrial Hygiene Association Workplace Environmental Exposure Limits ASTM ASTM International, originally known as the American Society for Testing and Materials (ASTM) DSL Domestic Substance List (Canada) EINECS European Inventory of Existing Commercial Substances ELINCS European List of Notified Chemical Substances ENCS Existing and new Chemical Substances (Japanese inventory) IECSC Inventory of Existing Chemical Substances in China KECI Korean Existing Chemicals Inventory NDSL Non-Domestic Substances List (Canada) NZIoC New Zealand Inventory of Chemicals Page 712 of 1287 Page 712 of 1287 Page 712 of 1287 Page 712 of 1287 ---PAGE BREAK--- Product Name: MOBIL SHC 630 Revision Date: 19 May 2015 Page 12 of 12 PICCS Philippine Inventory of Chemicals and Chemical Substances TLV Threshold Limit Value (American Conference of Governmental Industrial Hygienists) TSCA Toxic Substances Control Act (U.S. inventory) UVCB Substances of Unknown or Variable composition, Complex reaction products or Biological materials LC Lethal Concentration LD Lethal Dose LL Lethal Loading EC Effective Concentration EL Effective Loading NOEC No Observable Effect Concentration NOELR No Observable Effect Loading Rate KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only): R50/53; Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only): Asp. Tox. 1 H304: May be fatal if swallowed and enters airways; Aspiration, Cat 1 Aquatic Acute 1 H400: Very toxic to aquatic life; Acute Env Tox, Cat 1 Aquatic Chronic 1 H410: Very toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 1 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: No revision information is available. The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A DGN: 2007968QGB (547911) ANNEX Annex not required for this material. Page 713 of 1287 Page 713 of 1287 Page 713 of 1287 Page 713 of 1287 ---PAGE BREAK--- Page 714 of 1287 Page 714 of 1287 Page 714 of 1287 Page 714 of 1287 ---PAGE BREAK--- Page 715 of 1287 Page 715 of 1287 Page 715 of 1287 Page 715 of 1287 ---PAGE BREAK--- Page 716 of 1287 Page 716 of 1287 Page 716 of 1287 Page 716 of 1287 ---PAGE BREAK--- Page 717 of 1287 Page 717 of 1287 Page 717 of 1287 Page 717 of 1287 ---PAGE BREAK--- Page 718 of 1287 Page 718 of 1287 Page 718 of 1287 Page 718 of 1287 ---PAGE BREAK--- Page 719 of 1287 Page 719 of 1287 Page 719 of 1287 Page 719 of 1287 ---PAGE BREAK--- Page 720 of 1287 Page 720 of 1287 Page 720 of 1287 Page 720 of 1287 ---PAGE BREAK--- Page 721 of 1287 Page 721 of 1287 Page 721 of 1287 Page 721 of 1287 ---PAGE BREAK--- Page 722 of 1287 Page 722 of 1287 Page 722 of 1287 Page 722 of 1287 ---PAGE BREAK--- Page 723 of 1287 Page 723 of 1287 Page 723 of 1287 Page 723 of 1287 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 MOLY Revision Date: 17 Mar 2015 Page 1 of 10 SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: MOBILGREASE XHP 462 MOLY Product Description: Base Oil and Additives Product Code: 2015A0202529, 642546-00, 97AB15 Intended Use: Grease COMPANY IDENTIFICATION Supplier: EXXON MOBIL CORPORATION 22777 Springwoods Village Parkway Spring, TX. 77389 USA 24 Hour Health Emergency [PHONE REDACTED] Transportation Emergency Phone [PHONE REDACTED] or [PHONE REDACTED] CHEMTREC Product Technical Information [PHONE REDACTED] MSDS Internet Address http://www.exxon.com, http://www.mobil.com SECTION 2 HAZARDS IDENTIFICATION This material is not hazardous according to regulatory guidelines (see (M)SDS Section 15). Other hazard information: HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200. PHYSICAL / CHEMICAL HAZARDS No significant hazards. HEALTH HAZARDS High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, or respiratory irritation. ENVIRONMENTAL HAZARDS No significant hazards. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. Page 724 of 1287 Page 724 of 1287 Page 724 of 1287 Page 724 of 1287 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 MOLY Revision Date: 17 Mar 2015 Page 2 of 10 SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS This material is defined as a mixture. Hazardous Substance(s) or Complex Substance(s) required for disclosure Name CAS# Concentration* GHS Hazard Codes BENZENAMINE, N-PHENYL-, REACTION PRODUCTS WITH 68411-46-1 1 - < 5% H402, H412 MOLYBDENUM (IV) SULFIDE 1317-33-5 1 - < 5% None ZINC DITHIOPHOSPHATE 68649-42-3 1 - < 2.5% H315, H318, H401, H411 * All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. As per paragraph of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and exact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact percentage composition will be provided to health professionals, employees, or designated representatives in accordance with applicable provisions of paragraph SECTION 4 FIRST AID MEASURES INHALATION Under normal conditions of intended use, this material is not expected to be an inhalation hazard. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, Page 725 of 1287 Page 725 of 1287 Page 725 of 1287 Page 725 of 1287 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 MOLY Revision Date: 17 Mar 2015 Page 3 of 10 sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Smoke, Fume, Sulfur oxides, Aldehydes, Oxides of carbon, Incomplete combustion products FLAMMABILITY PROPERTIES Flash Point [Method]: >294°C (561°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802. PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended. SPILL MANAGEMENT Land Spill: Scrape up spilled material with shovels into a suitable container for recycle or disposal. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Skim from surface. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Prevent entry into waterways, sewers, basements or confined areas. Page 726 of 1287 Page 726 of 1287 Page 726 of 1287 Page 726 of 1287 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 MOLY Revision Date: 17 Mar 2015 Page 4 of 10 SECTION 7 HANDLING AND STORAGE HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator. STORAGE Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMIT VALUES Exposure limits/standards (Note: Exposure limits are not additive) Substance Name Form Limit / Standard NOTE Source MOLYBDENUM (IV) SULFIDE [as Mo] Total dust. TWA 15 mg/m3 N/A OSHA Z1 MOLYBDENUM (IV) SULFIDE [as Mo] Inhalable fraction. TWA 10 mg/m3 N/A ACGIH MOLYBDENUM (IV) SULFIDE [as Mo] Respirable fraction. TWA 3 mg/m3 N/A ACGIH NOTE: Limits/standards shown for guidance only. Follow applicable regulations. No biological limits allocated. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove Page 727 of 1287 Page 727 of 1287 Page 727 of 1287 Page 727 of 1287 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 MOLY Revision Date: 17 Mar 2015 Page 5 of 10 manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Physical State: Solid Form: Semi-fluid Color: Brown Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 0.9 Flammability (Solid, Gas): Flash Point [Method]: >294°C (561°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) [Estimated] Decomposition Temperature: N/D Vapor Density (Air = N/D Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C [Estimated] Evaporation Rate (n-butyl acetate = N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 [Estimated] Solubility in Water: Negligible Viscosity: 460 cSt (460 mm2/sec) at 40 °C Oxidizing Properties: See Hazards Identification Section. Page 728 of 1287 Page 728 of 1287 Page 728 of 1287 Page 728 of 1287 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 MOLY Revision Date: 17 Mar 2015 Page 6 of 10 OTHER INFORMATION Freezing Point: N/D Melting Point: N/D DMSO Extract (mineral oil only), IP-346: < 3 %wt NOTE: Most physical properties above are for the oil component in the material. SECTION 10 STABILITY AND REACTIVITY REACTIVITY: See sub-sections below. STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS Hazard Class Conclusion / Remarks Inhalation Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Ingestion Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Corrosion/Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on assessment of the components. Eye Serious Eye Damage/Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components. Sensitization Respiratory Sensitization: No end point data for material. Not expected to be a respiratory sensitizer. Skin Sensitization: No end point data for material. Not expected to be a skin sensitizer. Based on assessment of the components. Aspiration: Data available. Not expected to be an aspiration hazard. Based on physico-chemical properties of the material. Germ Cell Mutagenicity: No end point data for material. Not expected to be a germ cell mutagen. Based on assessment of the components. Page 729 of 1287 Page 729 of 1287 Page 729 of 1287 Page 729 of 1287 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 MOLY Revision Date: 17 Mar 2015 Page 7 of 10 Carcinogenicity: No end point data for material. Not expected to cause cancer. Based on assessment of the components. Reproductive Toxicity: No end point data for material. Not expected to be a reproductive toxicant. Based on assessment of the components. Lactation: No end point data for material. Not expected to cause harm to breast-fed children. Specific Target Organ Toxicity (STOT) Single Exposure: No end point data for material. Not expected to cause organ damage from a single exposure. Repeated Exposure: No end point data for material. Not expected to cause organ damage from prolonged or repeated exposure. Based on assessment of the components. OTHER INFORMATION Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Not expected to be harmful to aquatic organisms. MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. Page 730 of 1287 Page 730 of 1287 Page 730 of 1287 Page 730 of 1287 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 MOLY Revision Date: 17 Mar 2015 Page 8 of 10 SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (DOT): Not Regulated for Land Transport LAND (TDG): Not Regulated for Land Transport SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code Marine Pollutant: No AIR (IATA): Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with OSHA HazCom 2012, 29 CFR 1910.1200. Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, ENCS, IECSC, Page 731 of 1287 Page 731 of 1287 Page 731 of 1287 Page 731 of 1287 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 MOLY Revision Date: 17 Mar 2015 Page 9 of 10 KECI, PICCS, TSCA EPCRA SECTION 302: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: Chemical Name CAS Number Typical Value ZINC DITHIOPHOSPHATE 68649-42-3 1 - < 2.5% The following ingredients are cited on the lists below: Chemical Name CAS Number List Citations MOLYBDENUM (IV) SULFIDE 1317-33-5 1, 4, 13, 16 SOLUTION OF ZINC NAPHTHENATE (10%) IN MINERAL OIL 45011 15 ZINC DITHIOPHOSPHATE 68649-42-3 13, 15, 17, 19 --REGULATORY LISTS SEARCHED-- 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK 5 = TSCA 4 10 = CA P65 CARC 15 = MI 293 Code key: CARC=Carcinogen; REPRO=Reproductive SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only): H315: Causes skin irritation; Skin Corr/Irritation, Cat 2 H318: Causes serious eye damage; Serious Eye Damage/Irr, Cat 1 H401: Toxic to aquatic life; Acute Env Tox, Cat 2 H402: Harmful to aquatic life; Acute Env Tox, Cat 3 H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2 H412: Harmful to aquatic life with long lasting effects; Chronic Env Tox, Cat 3 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Updates made in accordance with implementation of GHS requirements. Page 732 of 1287 Page 732 of 1287 Page 732 of 1287 Page 732 of 1287 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 462 MOLY Revision Date: 17 Mar 2015 Page 10 of 10 The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A DGN: 7049663XUS (1009427) Copyright 2002 Exxon Mobil Corporation, All rights reserved Page 733 of 1287 Page 733 of 1287 Page 733 of 1287 Page 733 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Motor Medic Thrust Starting Fluid Product identifier Other means of identification M3815 SDS number M3815 Part No. 2909.11.0000 Tariff code Starting Fluid Recommended use None known. Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufacturer RSC Chemical Solutions Address 600 Radiator Road Company name Website Telephone Customer Service: (704) 821-7643 Technical: (704) 684-1811 Emergency phone number Emergency Telephone: (303) 623-5716 Emergency Contact: ([PHONE REDACTED]) E-mail United States Not available. Indian Trail, NC 28079 2. Hazard(s) identification Category 1 Flammable aerosols Physical hazards Category 4 Acute toxicity, oral Health hazards Category 2 Skin corrosion/irritation Category 2B Serious eye damage/eye irritation Category 1B Carcinogenicity Category 3 narcotic effects Specific target organ toxicity, single exposure Category 1 Hazardous to the aquatic environment, acute hazard Environmental hazards Category 1 Hazardous to the aquatic environment, long-term hazard Not classified. OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Harmful if swallowed. Causes skin irritation. Causes eye irritation. May cause drowsiness or dizziness. May cause cancer. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. 1 / 10 Material name: Motor Medic Thrust Starting Fluid M3815 Version 02 Revision date: 05-18-2015 Issue date: 05-07-2015 SDS US Page 734 of 1287 Page 734 of 1287 Page 734 of 1287 Page 734 of 1287 ---PAGE BREAK--- Response If swallowed: Call a poison center/doctor if you feel unwell. If on skin: Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. Call a poison center/doctor if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Collect spillage. Storage Store in a well-ventilated place. Keep container closed. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information 81.4% of the mixture consists of component(s) of unknown acute oral toxicity. 25.6% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. 25.6% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment. 3. Composition/information on ingredients Mixtures CAS number % Common name and synonyms Chemical name 142-82-5 Heptane 70 - < 80 60-29-7 ETHANE, 1,1'-OXYBIS- 10 - < 20 124-38-9 Carbon Dioxide 5 - < 10 64742-52-5 Hydrotreated Heavy Naphthenic Distillate (petroleum) 1 - < 3 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Inhalation Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Eye contact Rinse mouth. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Get medical advice/attention if you feel unwell. Ingestion May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of eyes. Exposed individuals may experience eye tearing, redness, and discomfort. Skin irritation. May cause redness and pain. Most important acute and delayed Provide general supportive measures and treat Keep victim warm. Keep victim under observation. may be delayed. Indication of immediate medical attention and special treatment needed IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. General information 5. Fire-fighting measures Powder. Alcohol resistant foam. Carbon dioxide (CO2). Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Unsuitable extinguishing media Contents under pressure. Pressurized container may explode when exposed to heat or flame. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Special protective equipment and precautions for firefighters Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. Specific methods 2 / 10 Material name: Motor Medic Thrust Starting Fluid M3815 Version 02 Revision date: 05-18-2015 Issue date: 05-07-2015 SDS US Page 735 of 1287 Page 735 of 1287 Page 735 of 1287 Page 735 of 1287 ---PAGE BREAK--- Extremely flammable aerosol. General fire hazards 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Refer to attached safety data sheets and/or instructions for use. Keep combustibles (wood, paper, oil, etc.) away from spilled material. This material is classified as a water pollutant under the Clean Water Act and should be prevented from contaminating soil or from entering sewage and drainage systems which lead to waterways. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. Environmental precautions 7. Handling and storage Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Should be handled in closed systems, if possible. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. Precautions for safe handling Level 3 Aerosol. Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Keep out of the reach of children. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Form Type PEL 9000 mg/m3 Carbon Dioxide (CAS 124-38-9) 5000 ppm PEL 1200 mg/m3 ETHANE, 1,1'-OXYBIS- (CAS 60-29-7) 400 ppm PEL 2000 mg/m3 Heptane (CAS 142-82-5) 500 ppm PEL 5 mg/m3 Mist. Hydrotreated Heavy Naphthenic Distillate (petroleum) (CAS 64742-52-5) 2000 mg/m3 500 ppm US. ACGIH Threshold Limit Values Value Components Form Type STEL 30000 ppm Carbon Dioxide (CAS 124-38-9) 3 / 10 Material name: Motor Medic Thrust Starting Fluid M3815 Version 02 Revision date: 05-18-2015 Issue date: 05-07-2015 SDS US Page 736 of 1287 Page 736 of 1287 Page 736 of 1287 Page 736 of 1287 ---PAGE BREAK--- US. ACGIH Threshold Limit Values Value Components Form Type TWA 5000 ppm STEL 500 ppm ETHANE, 1,1'-OXYBIS- (CAS 60-29-7) TWA 400 ppm STEL 500 ppm Heptane (CAS 142-82-5) TWA 400 ppm TWA 5 mg/m3 Inhalable fraction. Hydrotreated Heavy Naphthenic Distillate (petroleum) (CAS 64742-52-5) US. NIOSH: Pocket Guide to Chemical Hazards Value Components Form Type STEL 54000 mg/m3 Carbon Dioxide (CAS 124-38-9) 30000 ppm TWA 9000 mg/m3 5000 ppm Ceiling 1800 mg/m3 Heptane (CAS 142-82-5) 440 ppm TWA 350 mg/m3 85 ppm Ceiling 1800 mg/m3 Hydrotreated Heavy Naphthenic Distillate (petroleum) (CAS 64742-52-5) STEL 10 mg/m3 Mist. No biological exposure limits noted for the ingredient(s). Biological limit values Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Appropriate engineering controls Individual protection measures, such as personal protective equipment Chemical respirator with organic vapor cartridge and full facepiece. Eye/face protection Skin protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Hand protection Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended. Other Chemical respirator with organic vapor cartridge and full facepiece. Respiratory protection Wear appropriate thermal protective clothing, when necessary. Thermal hazards When using do not smoke. Keep away from food and drink. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Liquid. Clear. Appearance Liquid. Physical state Aerosol. Form Colorless Color Ester-like. Odor Odor threshold Not available. pH Not available. Melting point/freezing point -189.94 °F (-123.3 estimated Initial boiling point and boiling range -109.3 °F (-78.5 estimated 4 / 10 Material name: Motor Medic Thrust Starting Fluid M3815 Version 02 Revision date: 05-18-2015 Issue date: 05-07-2015 SDS US Page 737 of 1287 Page 737 of 1287 Page 737 of 1287 Page 737 of 1287 ---PAGE BREAK--- Flash point -1.0 °F (-18.3 Tag Closed Cup Evaporation rate Not available. Not applicable. Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower 1.9 % estimated Flammability limit - upper 36.5 % estimated Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 4083.55 hPa estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 320 °F (160 estimated Decomposition temperature Not available. Viscosity Not available. Other information Density 5.75 lbs/gal Not explosive. Explosive properties Flammability class Flammable IA estimated Heat of combustion (NFPA 30B) 30.82 kJ/g estimated Not oxidizing. Oxidizing properties Percent volatile 18.6 % estimated Specific gravity 0.69 VOC (Weight 93 % 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Reactivity Material is stable under normal conditions. Chemical stability Hazardous polymerization does not occur. Possibility of hazardous reactions Avoid temperatures exceeding the flash point. Contact with incompatible materials. Conditions to avoid Strong oxidizing agents. Aluminum. Incompatible materials No hazardous decomposition products are known. Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful. Skin contact Causes skin irritation. Eye contact Causes eye irritation. Ingestion Harmful if swallowed. related to the physical, chemical and toxicological characteristics Headache. May cause drowsiness and dizziness. Nausea, vomiting. Irritation of eyes. Exposed individuals may experience eye tearing, redness, and discomfort. Skin irritation. May cause redness and pain. Information on toxicological effects Acute toxicity Harmful if swallowed. Narcotic effects. 5 / 10 Material name: Motor Medic Thrust Starting Fluid M3815 Version 02 Revision date: 05-18-2015 Issue date: 05-07-2015 SDS US Page 738 of 1287 Page 738 of 1287 Page 738 of 1287 Page 738 of 1287 ---PAGE BREAK--- Test Results Components Species ETHANE, 1,1'-OXYBIS- (CAS 60-29-7) Inhalation Acute LC50 Rat 32000 ppm, 4 Hours Oral LD50 Rat 3230 - 3920 mg/kg Heptane (CAS 142-82-5) Inhalation Acute LC50 Rat 103 mg/l, 4 Hours * Estimates for product may be based on additional component data not shown. LD50 Mouse 75 mg/l, 2 Hours Causes skin irritation. Skin corrosion/irritation Causes eye irritation. Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. This product is not expected to cause skin sensitization. Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity May cause cancer. IARC Monographs. Overall Evaluation of Carcinogenicity ETHANE, 1,1'-OXYBIS- (CAS 60-29-7) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. US. National Toxicology Program (NTP) Report on Carcinogens Hydrotreated Heavy Naphthenic Distillate (petroleum) (CAS 64742-52-5) Known To Be Human Carcinogen. This product is not expected to cause reproductive or developmental effects. Reproductive toxicity Specific target organ toxicity - single exposure May cause drowsiness and dizziness. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Very toxic to aquatic life with long lasting effects. Ecotoxicity Components Test Results Species ETHANE, 1,1'-OXYBIS- (CAS 60-29-7) Aquatic LC50 Fish 2560 mg/l, 96 hours Fathead minnow (Pimephales promelas) * Estimates for product may be based on additional component data not shown. Heptane (CAS 142-82-5) Aquatic LC50 Fish 375 mg/l, 96 hours Mozambique tilapia (Tilapia mossambica) No data is available on the degradability of this product. Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) ETHANE, 1,1'-OXYBIS- 0.89 6 / 10 Material name: Motor Medic Thrust Starting Fluid M3815 Version 02 Revision date: 05-18-2015 Issue date: 05-07-2015 SDS US Page 739 of 1287 Page 739 of 1287 Page 739 of 1287 Page 739 of 1287 ---PAGE BREAK--- Partition coefficient n-octanol / water (log Kow) Heptane 4.66 No data available. Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations. Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. Contaminated packaging 14. Transport information DOT Not available. UN number Consumer Commodity UN proper shipping name ORM-D Class Transport hazard class(es) - Subsidiary risk 2.1 Label(s) Not applicable. Packing group Yes Marine pollutant Environmental hazards Read safety instructions, SDS and emergency procedures before handling. Special precautions for user T75, TP5 Special provisions 306 Packaging exceptions 304 Packaging non bulk 314, 315 Packaging bulk IATA UN1950 UN number Aerosols, Flammable (Starting Fluid) UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk III Packing group Yes Environmental hazards 9L ERG Code Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Allowed. Passenger and cargo aircraft Other information Allowed. Cargo aircraft only IMDG UN1950 UN number Aerosols (lLimited QtY) UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk Not applicable. Packing group 7 / 10 Material name: Motor Medic Thrust Starting Fluid M3815 Version 02 Revision date: 05-18-2015 Issue date: 05-07-2015 SDS US Page 740 of 1287 Page 740 of 1287 Page 740 of 1287 Page 740 of 1287 ---PAGE BREAK--- Yes Marine pollutant Environmental hazards F-D, S-U EmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Not established. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code IATA; IMDG Marine pollutant IMDG Regulated Marine Pollutant. DOT Regulated Marine Pollutant. General information 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) ETHANE, 1,1'-OXYBIS- (CAS 60-29-7) Listed. Heptane (CAS 142-82-5) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Hazard categories SARA 302 Extremely hazardous substance Not listed. No SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Not regulated. 8 / 10 Material name: Motor Medic Thrust Starting Fluid M3815 Version 02 Revision date: 05-18-2015 Issue date: 05-07-2015 SDS US Page 741 of 1287 Page 741 of 1287 Page 741 of 1287 Page 741 of 1287 ---PAGE BREAK--- Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) ETHANE, 1,1'-OXYBIS- (CAS 60-29-7) Not regulated. Safe Drinking Water Act (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number ETHANE, 1,1'-OXYBIS- (CAS 60-29-7) 6584 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) ETHANE, 1,1'-OXYBIS- (CAS 60-29-7) 35 %WV DEA Exempt Chemical Mixtures Code Number ETHANE, 1,1'-OXYBIS- (CAS 60-29-7) 6584 US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. Hydrotreated Heavy Naphthenic Distillate (petroleum) (CAS 64742-52-5) US. Massachusetts RTK - Substance List Carbon Dioxide (CAS 124-38-9) ETHANE, 1,1'-OXYBIS- (CAS 60-29-7) Heptane (CAS 142-82-5) Hydrotreated Heavy Naphthenic Distillate (petroleum) (CAS 64742-52-5) US. New Jersey Worker and Community Right-to-Know Act Carbon Dioxide (CAS 124-38-9) ETHANE, 1,1'-OXYBIS- (CAS 60-29-7) Heptane (CAS 142-82-5) US. Worker and Community Right-to-Know Law Carbon Dioxide (CAS 124-38-9) ETHANE, 1,1'-OXYBIS- (CAS 60-29-7) Heptane (CAS 142-82-5) US. Rhode Island RTK ETHANE, 1,1'-OXYBIS- (CAS 60-29-7) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Yes Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) Yes China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) Yes Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 9 / 10 Material name: Motor Medic Thrust Starting Fluid M3815 Version 02 Revision date: 05-18-2015 Issue date: 05-07-2015 SDS US Page 742 of 1287 Page 742 of 1287 Page 742 of 1287 Page 742 of 1287 ---PAGE BREAK--- 16. Other information, including date of preparation or last revision 05-07-2015 Issue date 05-18-2015 Revision date Version # 02 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Disclaimer Physical & Chemical Properties: Multiple Properties Transport Information: Material Transportation Information Revision Information 10 / 10 Material name: Motor Medic Thrust Starting Fluid M3815 Version 02 Revision date: 05-18-2015 Issue date: 05-07-2015 SDS US Page 743 of 1287 Page 743 of 1287 Page 743 of 1287 Page 743 of 1287 ---PAGE BREAK--- Page 744 of 1287 Page 744 of 1287 Page 744 of 1287 Page 744 of 1287 ---PAGE BREAK--- Page 745 of 1287 Page 745 of 1287 Page 745 of 1287 Page 745 of 1287 ---PAGE BREAK--- Page 746 of 1287 Page 746 of 1287 Page 746 of 1287 Page 746 of 1287 ---PAGE BREAK--- Page 747 of 1287 Page 747 of 1287 Page 747 of 1287 Page 747 of 1287 ---PAGE BREAK--- Page 748 of 1287 Page 748 of 1287 Page 748 of 1287 Page 748 of 1287 ---PAGE BREAK--- Page 749 of 1287 Page 749 of 1287 Page 749 of 1287 Page 749 of 1287 ---PAGE BREAK--- Page 750 of 1287 Page 750 of 1287 Page 750 of 1287 Page 750 of 1287 ---PAGE BREAK--- Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 179944 US-US-2 Level: 1 Release Date: 2008-05-21 Page: 1 / FIR No.: 8 1. Product and Company Identification Product Name: Product Code: Application: Supplier: Emergency Telephone: MOTORCRAFT TRANSFER CASE FLUID See Attachment Transfer case fluid Ford Motor Company Attention: MSDS Information, P.O. Box 1899 Dearborn, Michigan 48121 1-[PHONE REDACTED] Poison Control Center: 1-[PHONE REDACTED] CHEMTREC: U.S. and Canada: 1-[PHONE REDACTED] CHEMTREC: International: 1-[PHONE REDACTED] PETROLEUM DISTILLATES HYDROTREATED HEAVY PARAFFINIC LUBRICATING OILS (PETROLEUM) C15-30 HYDROTREATED, NEUTRAL OIL BASED 64742-54-7 72623-86-0 60-100 0.1-1 HAZCOM RSMS_P_SOM HAZCOM RSMS_P_SOM Health: Inhalation: Skin Contact: Eye Contact: Ingestion: This product may cause mild irritation to the eyes and skin. Inhalation of vapors (generated at high temperatures only) may cause mild irritation of the nose, throat, and respiratory tract. Prolonged or repeated contact with this product may dry and/or defat the skin. Prolonged or repeated contact with this product may lead to various skin disorders such as dermatitis or folliculitis. If gas/fume/vapor/dust/mist from the material is inhaled, remove the affected person immediately to fresh air. If irritation persists, get medical attention. Immediately take off all contaminated clothing. Wash skin with soap and water. If irritation persists, get medical attention. In case of contact with eyes, rinse immediately with plenty of water for at least 15 minutes and seek medical attention. If irritation persists, get medical attention. First aid is not normally required; however, if swallowed and develop, seek medical attention. 2. Composition/Information on Ingredients This chemical product is a preparation. 3. Hazards Identification 4. First-Aid Measures Page 751 of 1287 Page 751 of 1287 Page 751 of 1287 Page 751 of 1287 ---PAGE BREAK--- Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 179944 US-US-2 Level: 1 Release Date: 2008-05-21 Page: 2 / FIR No.: 8 Notes to a Physician: Extinguishing Media: Specific Methods: Specific Hazards: Protection of Firefighters: Personal Precautions: Environmental Precautions: Methods for Cleaning Up: Handling: Storage: If the affected person's breathing is difficult, give oxygen. This material, if aspirated into the lungs, may cause chemical pneumonitis; treat the affected person appropriately. Dry chemical, foam, carbon dioxide, water fog. Use water to cool fire-exposed containers, structures, and to protect personnel. Combustion may produce the following products: Oxides of carbon, nitrogen, and phosphorus. Water or foam may cause frothing if the product is heated above 93 degrees C (200 degrees Empty containers may retain product residue including Flammable or Explosive vapors. Do not cut, drill, grind, or weld near full, partially full, or empty product containers. Fire fighters should be equipped with NIOSH-approved, self-contained breathing apparatus (SCBA) and full protective clothing. Avoid inhalation of vapors and contact with skin and eyes. Eliminate all sources of ignition or flammables that may come into contact with a spill of this material. In case of spills, beware of slippery floors and surfaces. Wear appropriate protective equipment and clothing during clean-up. Do not allow the spilled product to enter public drainage system or open water courses. Contain the discharged material. Absorb the spilled material with an inert absorbent (nonflammable) material. Avoid the generation of oil mists. Avoid breathing vapor or mist. Avoid prolonged or repeated skin contact with this material. Do not reuse the empty container. Technical Measures: Precautions and Advice for Safe Handling: Technical Measures: 5. Fire-Fighting Measures 6. Accidental Release Measures 7. Handling and Storage Page 752 of 1287 Page 752 of 1287 Page 752 of 1287 Page 752 of 1287 ---PAGE BREAK--- Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 179944 US-US-2 Level: 1 Release Date: 2008-05-21 Page: 3 / FIR No.: 8 Do not store near heat, spark or open flame. Store this product away from strong oxidizing agents. Store this product in a cool, dry, well-ventilated place. Storage Conditions: Wash thoroughly after handling. Wash contaminated clothing before reuse. Personal Protective Equipment: Hygiene Measures: None required under normal conditions. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the requirements of OSHA Respiratory Protection Standard 29 CFR 1910.134 and/or Canadian Standard CSA Z94.4. Use of impervious gloves is required, such as neoprene or nitrile rubber gloves. Wear safety glasses with side shields. Wear chemical goggles; face shield (if splashing is possible). Light protective clothing is recommended. Respiratory Protection: Hand Protection: Eye Protection: Skin and Body Protection: 8. Exposure Controls/Personal Protection General (mechanical) room ventilation is expected to be satisfactory if handled at low temperatures or in covered equipment. Local ventilation is needed in the presence of airborne mists. If oil mist is generated, observe the OSHA exposure limit of 5 mg/m3. Ford Motor Company recommends an exposure limit of 1.0 mg/m3. Engineering Measures: Control Parameters: Page 753 of 1287 Page 753 of 1287 Page 753 of 1287 Page 753 of 1287 ---PAGE BREAK--- Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 179944 US-US-2 Level: 1 Release Date: 2008-05-21 Page: 4 / FIR No.: 8 9. Physical and Chemical Properties 10. Stability and Reactivity 11. Toxicological Information 0.86-0.87 @15.6°C LIQUID PETROLEUM RED N.AP 157 °C ASTM D93 <1@20°C >1 (AIR=1) NEGLIGIBLE IN WATER 32.5@40°C cSt ASTM D445 <1 (BuAc = 1) This is a stable material. Hazardous polymerization will not occur. This product may react with strong oxidizing agents (bleach--sodium hypochlorite, calcium hypochlorite, hydrogen peroxide, permanganate, nitric acid, concentrated OXYGEN, perchlorates). Decomposition of this product may emit oxides of nitrogen and carbon monoxide. Decomposition of this product may emit oxides of sulfur. Decomposition of this product may yield oxides of phosphorus. The skin sensitization potential of this product has not been fully assessed, assume that contact with the skin may cause allergic contact dermatitis. Risks are higher where prolonged or repeated skin contact with a fluid may occur. Prolonged or repeated contact with this product may dry and/or defat the skin. Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Specific Gravity: Physical State: Odor: Color: pH: Temperature Range During which Changes in Physical State Occur: Flash Point: Explosion Properties: Vapor Pressure: Vapor Density: Solubility: Viscosity: Evaporation Rate: Stability: Conditions and Materials to Avoid: Hazardous Decomposition Products: Skin Contact: Chronic (Long Term) Toxicity: N.AV N.AV UEL: LEL: Page 754 of 1287 Page 754 of 1287 Page 754 of 1287 Page 754 of 1287 ---PAGE BREAK--- Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 179944 US-US-2 Level: 1 Release Date: 2008-05-21 Page: 5 / FIR No.: 8 12. Ecological Information 13. Disposal Considerations No specific aquatic data available for this product. Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulation. No consideration given when disposed of according to local, state, and Federal regulations. Waste from Residues: Contaminated Packaging: Page 755 of 1287 Page 755 of 1287 Page 755 of 1287 Page 755 of 1287 ---PAGE BREAK--- Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 179944 US-US-2 Level: 1 Release Date: 2008-05-21 Page: 6 / FIR No.: 8 14. Transport Information U.S. Department of Transportation (DOT) 49 - CFR 172.101 Canadian Transportation of Dangerous Goods - TDGR Schedule II Secretary of Communication and Transportation (SCT) - NOM-002-SCT2/1994 (Mexico) International and Domestic Air Transportation - ICAO & IATA Section 4.2 International Water Transportation - IMDG Code Amendment 31-02 This product is not regulated as a dangerous good. This product is not regulated as a dangerous good. This product is not regulated as a dangerous good. This product is not regulated as a dangerous good. This product is not regulated as a dangerous good. Don't pollute. Conserve resources. Return used oil to collection centers. This product contains NONE of the substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372 The components of this product are listed on the TSCA Inventory Material contains a chemical which is a Ford Motor Company Material of Concern. Use and release of this material should be minimized to the greatest extent possible. 15. Regulatory Information 16. Other Information Key/Legend: N.AP = Not applicable; N.AV = Not available; ND = Not determined or No data; TLV = Threshold limit value; TWA = Time-weighted average; STEL = Short-term exposure limit; C = Ceiling limit 2 15 The chemical identification and properties for this material were provided by the manufacturer. For Canadian locations, a manufacture's MSDS is available upon request. Health and safety information has been evaluated by the Occupational and Environmental Health Sciences Department, Ford Motor Company, Diagnostic Service Center II, 1800 Fairlane Drive, Allen Park, MI 48101, USA. The following sections contain revisions OR NEW statements. Preparation Information: HMIS and NFPA Hazard Class Information: HMIS Hazard Class: NFPA Hazard Class: Health: 1 (Slight) Flammability: 1 (Slight) Physical Hazard: 0 (Least) Health: 0 (Least) Flammability: 1 (Slight) Instability: 0 (Least) Page 756 of 1287 Page 756 of 1287 Page 756 of 1287 Page 756 of 1287 ---PAGE BREAK--- Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 179944 US-US-2 Level: 1 Release Date: 2008-05-21 Page: 7 / FIR No.: 8 The information on this data sheet represents our current data and is accurate to the best of our knowledge as to the proper handling of this product under normal conditions and in accordance with the application specified on the packaging and/or technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. Disclaimer: Page 757 of 1287 Page 757 of 1287 Page 757 of 1287 Page 757 of 1287 ---PAGE BREAK--- Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 179944 US-US-2 Level: 1 Release Date: 2008-05-21 Page: 8 / FIR No.: 8 Product Code Container Size Part of Kit Kit Product Code XL-12 1 qt. Attachment Page 758 of 1287 Page 758 of 1287 Page 758 of 1287 Page 758 of 1287 ---PAGE BREAK--- Page 1/5 Safety Data Sheet acc. to OSHA HCS Printing date 09/25/2014 Revised On 09/25/2014 39.4.1 1 Identification of the substance and manufacturer Trade name: MRO DARK GREEN Product code: [PHONE REDACTED] Product category PC9a Paints and coatings. Manufacturer/Supplier: Seymour of Sycamore 917 Crosby Avenue Sycamore, IL 60178 Phone: [PHONE REDACTED] www.seymourpaint.com Emergency telephone number: CHEMTEL 1-[PHONE REDACTED], [PHONE REDACTED] *if located outside the U.S.* 2 Hazard(s) identification Classification of the substance or mixture Flam. Aerosol 1 H222 Extremely flammable aerosol. Press. Gas H280 Contains gas under pressure; may explode if heated. Carc. 2 H351 Suspected of causing cancer. STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. Eye Irrit. 2A H319 Causes serious eye irritation. STOT SE 3 H336 May cause drowsiness or dizziness. GHS Hazard pictograms GHS02 GHS04 GHS07 GHS08 Signal word Danger Hazard statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Suspected of causing cancer. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure. Precautionary statements If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. Obtain special instructions before use. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash hands thoroughly after handling. Use only outdoors or in a well-ventilated area. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. Do not breathe dust/fume/gas/mist/vapours/spray. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Get medical advice/attention if you feel unwell. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 Store in a well-ventilated place. Keep container closed. Dispose of contents/container in accordance with local/regional/national/international regulations. 3 Composition/information on ingredients Chemical Description: This product is a mixture of the substances listed below with nonhazardous additions. Dangerous components: 67-64-1 Acetone 20.52% 74-98-6 propane 15.8% 106-97-8 n-butane 9.28% 7727-43-7 barium sulphate, natural 8.65% 108-10-1 methyl isobutyl ketone 5.63% 2807-30-9 Glycol Ether EP 5.54% 107-87-9 Methyl Propyl Ketone 2.87% 108-65-6 PM acetate 2.79% 1330-20-7 xylene (mix) 2.51% 110-19-0 isobutyl acetate 1.67% 4 First-aid measures After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Remove contaminated clothing. Wash exposed area with soap and water. After eye contact: Rinse opened eye for several minutes under running water. If persist, consult a doctor. (Contd. on page 2) US4 Page 759 of 1287 Page 759 of 1287 Page 759 of 1287 Page 759 of 1287 ---PAGE BREAK--- Page 2/5 Safety Data Sheet acc. to OSHA HCS Printing date 09/25/2014 Revised On 09/25/2014 Trade name: MRO DARK GREEN (Contd. of page 1) 39.4.1 After swallowing: Rinse out mouth and then drink plenty of water. Rinse mouth with water. Do not induce vomiting. Most important and effects: Dizziness Indication of any immediate medical attention needed: No further relevant information available. 5 Fire-fighting measures Extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray. Special hazards: Can form explosive gas-air mixtures. Protective equipment for firefighters: A respiratory protective device may be necessary. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures: Wear protective equipment. Keep unprotected persons away. Use respiratory protective device against the effects of fumes/dust/aerosol. Methods and material for containment and cleaning up: Ensure adequate ventilation. 7 Handling and storage Precautions for safe handling Use only in well ventilated areas. Storage requirements: Keep away from sources of heat and direct sunlight. Do not warehouse in subfreezing conditions. Store locked up. 8 Exposure controls/personal protection Components with limit values that require monitoring at the workplace: 67-64-1 Acetone PEL (USA) Long-term value: 2400 mg/m³, 1000 ppm REL (USA) Long-term value: 590 mg/m³, 250 ppm TLV (USA) Short-term value: (1782) NIC-1187 mg/m³, (750) NIC-500 ppm Long-term value: (1188) NIC-594 mg/m³, (500) NIC-250 ppm BEI 74-98-6 propane PEL (USA) Long-term value: 1800 mg/m³, 1000 ppm REL (USA) Long-term value: 1800 mg/m³, 1000 ppm TLV (USA) refer to Appendix F 106-97-8 n-butane REL (USA) Long-term value: 1900 mg/m³, 800 ppm TLV (USA) Short-term value: 2370 mg/m³, 1000 ppm 7727-43-7 barium sulphate, natural PEL (USA) Long-term value: 15* mg/m³ *total dust **respirable fraction REL (USA) Long-term value: 10* mg/m³ *total dust **respirable fraction TLV (USA) Long-term value: 5* mg/m³ *inhalable fraction; E 108-10-1 methyl isobutyl ketone PEL (USA) Long-term value: 410 mg/m³, 100 ppm REL (USA) Short-term value: 300 mg/m³, 75 ppm Long-term value: 205 mg/m³, 50 ppm TLV (USA) Short-term value: 307 mg/m³, 75 ppm Long-term value: 82 mg/m³, 20 ppm BEI 107-87-9 Methyl Propyl Ketone PEL (USA) Long-term value: 700 mg/m³, 200 ppm REL (USA) Long-term value: 530 mg/m³, 150 ppm TLV (USA) Short-term value: 529 mg/m³, 150 ppm 108-65-6 PM acetate WEEL (USA) Long-term value: 50 ppm 1330-20-7 xylene (mix) PEL (USA) Long-term value: 435 mg/m³, 100 ppm (Contd. on page 3) US4 Page 760 of 1287 Page 760 of 1287 Page 760 of 1287 Page 760 of 1287 ---PAGE BREAK--- Page 3/5 Safety Data Sheet acc. to OSHA HCS Printing date 09/25/2014 Revised On 09/25/2014 Trade name: MRO DARK GREEN (Contd. of page 2) 39.4.1 REL (USA) Short-term value: 655 mg/m³, 150 ppm Long-term value: 435 mg/m³, 100 ppm TLV (USA) Short-term value: 651 mg/m³, 150 ppm Long-term value: 434 mg/m³, 100 ppm BEI 110-19-0 isobutyl acetate PEL (USA) Long-term value: 700 mg/m³, 150 ppm REL (USA) Long-term value: 700 mg/m³, 150 ppm TLV (USA) Long-term value: 713 mg/m³, 150 ppm Ingredients with biological limit values: 67-64-1 Acetone BEI (USA) 50 mg/L Medium: urine Time: end of shift Parameter: Acetone (nonspecific) 108-10-1 methyl isobutyl ketone BEI (USA) 1 mg/L Medium: urine Time: end of shift Parameter: MIBK 1330-20-7 xylene (mix) BEI (USA) 1.5 g/g creatinine Medium: urine Time: end of shift Parameter: acids Hygienic protection: Keep away from foodstuffs and animal feed. Wash hands after use. Immediately remove all soiled and contaminated clothing. Wash hands after use. Avoid contact with the eyes and skin. Do not eat or drink while working. Breathing equipment: A respirator is generally not necessary when using this product outdoors or in large open areas. In cases where short and/or long term overexposure exists, a charcoal filter respirator should be worn. If you suspect overexposure conditions exist, please consult an authority on chemical hygeine. Hand protection: Protective gloves. The glove material must be impermeable and resistant to the substance. Eye protection: sealed goggles 9 Physical and chemical properties Appearance: Aerosol. Odor: Aromatic Odor threshold: Not determined. pH-value: Not determined. Melting point/Melting range Undetermined. Boiling point: -44 °C (-47 Flash point: -19 °C Flammability (solid, gas): Extremely flammable. Decomposition temperature: Not determined. Auto igniting: Product is not self-igniting. Danger of explosion: In use, may form flammable/explosive vapour-air mixture. Lower Explosion Limit: 1.7 Vol % Upper Explosion Limit: 10.9 Vol % Vapor pressure: Not determined. Relative Density: Between 0.77 and 0.85 (Water equals 1.00) Vapour density Not determined. Evaporation rate Not applicable. Partition coefficient: n-octonal/water: Not determined. Solubility: Not determined. Viscosity: Not determined. VOC content: 499.5 g/l / 4.17 lb/gl VOC content (less exempt solvents): 47.2 % MIR Value: 1.13 Solids content: 31.8 % 10 Stability and reactivity Reactivity: Stable at normal temperatures. Conditions to avoid: Do not allow can to exceed 120 degrees Fahrenheit. Do not warehouse in subfreezing temperatures. Chemical stability: Not fully evaluated. (Contd. on page 4) US4 Page 761 of 1287 Page 761 of 1287 Page 761 of 1287 Page 761 of 1287 ---PAGE BREAK--- Page 4/5 Safety Data Sheet acc. to OSHA HCS Printing date 09/25/2014 Revised On 09/25/2014 Trade name: MRO DARK GREEN (Contd. of page 3) 39.4.1 Possibility of hazardous reactions: No dangerous reactions known. Incompatible materials: No further relevant information available. Hazardous decomposition: No dangerous decomposition products known. 11 Toxicological information LD/LC50 values that are relevant for classification: 106-97-8 n-butane Inhalative LC50/4 h 658 mg/l (rat) 108-10-1 methyl isobutyl ketone Oral LD50 2100 mg/kg (rat) Dermal LD50 16000 mg/kg (rab) Inhalative LC50/4 h 8.3-16.6 mg/l (rat) 108-65-6 PM acetate Oral LD50 8500 mg/kg (rat) Inhalative LC50/4 h 35.7 mg/l (rat) 1330-20-7 xylene (mix) Oral LD50 8700 mg/kg (rat) Dermal LD50 2000 mg/kg (rbt) Inhalative LC50/4 h 6350 mg/l (rat) 110-19-0 isobutyl acetate Oral LD50 4763 mg/kg (rbt) Information on toxicological effects: No data available. Sensitization: No sensitizing effects known. Carcinogenic categories IARC (International Agency for Research on Cancer) 108-10-1 methyl isobutyl ketone 2B 1330-20-7 xylene (mix) 3 NTP (National Toxicology Program) None of the ingredients is listed. OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. 12 Ecological information Aquatic toxicity: Hazardous for water, do not empty into drains. Persistence and degradability: The product is degradable after prolonged exposure to natural weathering processes. Bioaccumulative potential: No further relevant information available. Mobility in soil: No further relevant information available. Other adverse effects: No further relevant information available. 13 Disposal considerations Dispose of in accordance with local, state, and federal regulations. Do not puncture, incinerate, or compact. Partially empty cans must be disposed of responsibly. Do not heat or cut empty containers with electric or gas torches. Recommendation: Completely empty cans should be recycled. 14 Transport information UN-Number UN1950 DOT Aerosols, flammable ADR 1950 Aerosols Transport hazard class(es): Class 2.1 Marine pollutant: No Special precautions for user: Warning: Gases EMS Number: F-D,S-U Packaging Group: UN "Model Regulation": UN1950, Aerosols, 2.1 15 Regulatory information SARA Section 355 (extremely hazardous substances): None of the ingredients in this product are listed. SARA Section 313 (Specific toxic chemical listings): 7727-43-7 barium sulphate, natural 108-10-1 methyl isobutyl ketone 1330-20-7 xylene (mix) (Contd. on page 5) US4 Page 762 of 1287 Page 762 of 1287 Page 762 of 1287 Page 762 of 1287 ---PAGE BREAK--- Page 5/5 Safety Data Sheet acc. to OSHA HCS Printing date 09/25/2014 Revised On 09/25/2014 Trade name: MRO DARK GREEN (Contd. of page 4) 39.4.1 CPSC: This product complies with 16 CFR 1303 and does not contain more than 90 ppm of lead. California Proposition 65 chemicals known to cause cancer: 108-10-1 methyl isobutyl ketone 13463-67-7 titanium dioxide 100-41-4 ethyl benzene 1333-86-4 Carbon black EPA: 67-64-1 Acetone I 7727-43-7 barium sulphate, natural D, CBD(inh), NL(oral) 108-10-1 methyl isobutyl ketone I 1330-20-7 xylene (mix) I 110-19-0 isobutyl acetate D USDA (United States Department of Agriculture): Category 21: This product was manufactured to conform to the USDA Food Safety and Inspection Service performance standards. These standards include, but are not limited to, the ability of this product to be safe for use in official meat and poultry establishments, and to perform well under a daily regimen of thorough cleaning, cyclical temperature change, and wet conditions. This product may be used where there is a possibility of incidental food contact. 16 Other information Contact: Regulatory Affairs US4 Page 763 of 1287 Page 763 of 1287 Page 763 of 1287 Page 763 of 1287 ---PAGE BREAK--- Page 1/4 Safety Data Sheet acc. to OSHA HCS Printing date 09/25/2014 Revised On 09/25/2014 39.4.1 1 Identification of the substance and manufacturer Trade name: MRO FLAT BLACK Product code: [PHONE REDACTED] Product category PC9a Paints and coatings. Manufacturer/Supplier: Seymour of Sycamore 917 Crosby Avenue Sycamore, IL 60178 Phone: [PHONE REDACTED] www.seymourpaint.com Emergency telephone number: CHEMTEL 1-[PHONE REDACTED], [PHONE REDACTED] *if located outside the U.S.* 2 Hazard(s) identification Classification of the substance or mixture Flam. Aerosol 1 H222 Extremely flammable aerosol. Press. Gas H280 Contains gas under pressure; may explode if heated. Carc. 2 H351 Suspected of causing cancer. STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. Eye Irrit. 2A H319 Causes serious eye irritation. STOT SE 3 H336 May cause drowsiness or dizziness. GHS Hazard pictograms GHS02 GHS04 GHS07 GHS08 Signal word Danger Hazard statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Suspected of causing cancer. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure. Precautionary statements If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. Obtain special instructions before use. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash hands thoroughly after handling. Use only outdoors or in a well-ventilated area. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. Do not breathe dust/fume/gas/mist/vapours/spray. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Get medical advice/attention if you feel unwell. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 Store in a well-ventilated place. Keep container closed. Dispose of contents/container in accordance with local/regional/national/international regulations. 3 Composition/information on ingredients Chemical Description: This product is a mixture of the substances listed below with nonhazardous additions. Dangerous components: 67-64-1 Acetone 21.38% 74-98-6 propane 15.75% 1317-65-3 Calcium Carbonate 13.31% 106-97-8 n-butane 9.25% 108-10-1 methyl isobutyl ketone 7.2% 64742-89-8 VM&P Naphtha 4.63% 108-65-6 PM acetate 4.23% 2807-30-9 Glycol Ether EP 2.58% 110-19-0 isobutyl acetate 2.37% 107-87-9 Methyl Propyl Ketone 1.34% 112926-00-8 Silicon Dioxide 1.14% 4 First-aid measures After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Remove contaminated clothing. Wash exposed area with soap and water. (Contd. on page 2) US4 Page 764 of 1287 Page 764 of 1287 Page 764 of 1287 Page 764 of 1287 ---PAGE BREAK--- Page 2/4 Safety Data Sheet acc. to OSHA HCS Printing date 09/25/2014 Revised On 09/25/2014 Trade name: MRO FLAT BLACK (Contd. of page 1) 39.4.1 After eye contact: Rinse opened eye for several minutes under running water. If persist, consult a doctor. After swallowing: Rinse out mouth and then drink plenty of water. Rinse mouth with water. Do not induce vomiting. Most important and effects: Dizziness Indication of any immediate medical attention needed: No further relevant information available. 5 Fire-fighting measures Extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray. Special hazards: Can form explosive gas-air mixtures. Protective equipment for firefighters: A respiratory protective device may be necessary. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures: Wear protective equipment. Keep unprotected persons away. Use respiratory protective device against the effects of fumes/dust/aerosol. Methods and material for containment and cleaning up: Ensure adequate ventilation. 7 Handling and storage Precautions for safe handling Use only in well ventilated areas. Storage requirements: Keep away from sources of heat and direct sunlight. Do not warehouse in subfreezing conditions. Store locked up. 8 Exposure controls/personal protection Components with limit values that require monitoring at the workplace: 67-64-1 Acetone PEL (USA) Long-term value: 2400 mg/m³, 1000 ppm REL (USA) Long-term value: 590 mg/m³, 250 ppm TLV (USA) Short-term value: (1782) NIC-1187 mg/m³, (750) NIC-500 ppm Long-term value: (1188) NIC-594 mg/m³, (500) NIC-250 ppm BEI 74-98-6 propane PEL (USA) Long-term value: 1800 mg/m³, 1000 ppm REL (USA) Long-term value: 1800 mg/m³, 1000 ppm TLV (USA) refer to Appendix F 106-97-8 n-butane REL (USA) Long-term value: 1900 mg/m³, 800 ppm TLV (USA) Short-term value: 2370 mg/m³, 1000 ppm 108-10-1 methyl isobutyl ketone PEL (USA) Long-term value: 410 mg/m³, 100 ppm REL (USA) Short-term value: 300 mg/m³, 75 ppm Long-term value: 205 mg/m³, 50 ppm TLV (USA) Short-term value: 307 mg/m³, 75 ppm Long-term value: 82 mg/m³, 20 ppm BEI 108-65-6 PM acetate WEEL (USA) Long-term value: 50 ppm 110-19-0 isobutyl acetate PEL (USA) Long-term value: 700 mg/m³, 150 ppm REL (USA) Long-term value: 700 mg/m³, 150 ppm TLV (USA) Long-term value: 713 mg/m³, 150 ppm 107-87-9 Methyl Propyl Ketone PEL (USA) Long-term value: 700 mg/m³, 200 ppm REL (USA) Long-term value: 530 mg/m³, 150 ppm TLV (USA) Short-term value: 529 mg/m³, 150 ppm 112926-00-8 Silicon Dioxide PEL (USA) or 80mg/m3 /%SiO2 REL (USA) Long-term value: 6 mg/m³ See Pocket Guide App. C TLV (USA) TLV withdrawn (Contd. on page 3) US4 Page 765 of 1287 Page 765 of 1287 Page 765 of 1287 Page 765 of 1287 ---PAGE BREAK--- Page 3/4 Safety Data Sheet acc. to OSHA HCS Printing date 09/25/2014 Revised On 09/25/2014 Trade name: MRO FLAT BLACK (Contd. of page 2) 39.4.1 Ingredients with biological limit values: 67-64-1 Acetone BEI (USA) 50 mg/L Medium: urine Time: end of shift Parameter: Acetone (nonspecific) 108-10-1 methyl isobutyl ketone BEI (USA) 1 mg/L Medium: urine Time: end of shift Parameter: MIBK Hygienic protection: Keep away from foodstuffs and animal feed. Wash hands after use. Immediately remove all soiled and contaminated clothing. Wash hands after use. Avoid contact with the eyes and skin. Do not eat or drink while working. Breathing equipment: A respirator is generally not necessary when using this product outdoors or in large open areas. In cases where short and/or long term overexposure exists, a charcoal filter respirator should be worn. If you suspect overexposure conditions exist, please consult an authority on chemical hygeine. Hand protection: Protective gloves. The glove material must be impermeable and resistant to the substance. Eye protection: sealed goggles 9 Physical and chemical properties Appearance: Aerosol. Odor: Aromatic Odor threshold: Not determined. pH-value: Not determined. Melting point/Melting range Undetermined. Boiling point: -44 °C (-47 Flash point: -19 °C Flammability (solid, gas): Extremely flammable. Decomposition temperature: Not determined. Auto igniting: Product is not self-igniting. Danger of explosion: In use, may form flammable/explosive vapour-air mixture. Lower Explosion Limit: 1.7 Vol % Upper Explosion Limit: 10.9 Vol % Vapor pressure: Not determined. Relative Density: Between 0.77 and 0.85 (Water equals 1.00) Vapour density Not determined. Evaporation rate Not applicable. Partition coefficient: n-octonal/water: Not determined. Solubility: Not determined. Viscosity: Not determined. VOC content: 517.2 g/l / 4.32 lb/gl VOC content (less exempt solvents): 48.8 % MIR Value: 0.96 Solids content: 29.6 % 10 Stability and reactivity Reactivity: Stable at normal temperatures. Conditions to avoid: Do not allow can to exceed 120 degrees Fahrenheit. Do not warehouse in subfreezing temperatures. Chemical stability: Not fully evaluated. Possibility of hazardous reactions: No dangerous reactions known. Incompatible materials: No further relevant information available. Hazardous decomposition: No dangerous decomposition products known. 11 Toxicological information LD/LC50 values that are relevant for classification: 106-97-8 n-butane Inhalative LC50/4 h 658 mg/l (rat) 108-10-1 methyl isobutyl ketone Oral LD50 2100 mg/kg (rat) Dermal LD50 16000 mg/kg (rab) Inhalative LC50/4 h 8.3-16.6 mg/l (rat) (Contd. on page 4) US4 Page 766 of 1287 Page 766 of 1287 Page 766 of 1287 Page 766 of 1287 ---PAGE BREAK--- Page 4/4 Safety Data Sheet acc. to OSHA HCS Printing date 09/25/2014 Revised On 09/25/2014 Trade name: MRO FLAT BLACK (Contd. of page 3) 39.4.1 108-65-6 PM acetate Oral LD50 8500 mg/kg (rat) Inhalative LC50/4 h 35.7 mg/l (rat) 110-19-0 isobutyl acetate Oral LD50 4763 mg/kg (rbt) Information on toxicological effects: No data available. Sensitization: No sensitizing effects known. Carcinogenic categories IARC (International Agency for Research on Cancer) 108-10-1 methyl isobutyl ketone 2B NTP (National Toxicology Program) None of the ingredients is listed. OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. 12 Ecological information Aquatic toxicity: Hazardous for water, do not empty into drains. Persistence and degradability: The product is degradable after prolonged exposure to natural weathering processes. Bioaccumulative potential: No further relevant information available. Mobility in soil: No further relevant information available. Other adverse effects: No further relevant information available. 13 Disposal considerations Dispose of in accordance with local, state, and federal regulations. Do not puncture, incinerate, or compact. Partially empty cans must be disposed of responsibly. Do not heat or cut empty containers with electric or gas torches. Recommendation: Completely empty cans should be recycled. 14 Transport information UN-Number UN1950 DOT Aerosols, flammable ADR 1950 Aerosols Transport hazard class(es): Class 2.1 Marine pollutant: No Special precautions for user: Warning: Gases EMS Number: F-D,S-U Packaging Group: UN "Model Regulation": UN1950, Aerosols, 2.1 15 Regulatory information SARA Section 355 (extremely hazardous substances): None of the ingredients in this product are listed. SARA Section 313 (Specific toxic chemical listings): 108-10-1 methyl isobutyl ketone CPSC: This product complies with 16 CFR 1303 and does not contain more than 90 ppm of lead. California Proposition 65 chemicals known to cause cancer: 108-10-1 methyl isobutyl ketone 1333-86-4 Carbon black 100-41-4 ethyl benzene EPA: 67-64-1 Acetone I 108-10-1 methyl isobutyl ketone I 110-19-0 isobutyl acetate D USDA (United States Department of Agriculture): Category 21: This product was manufactured to conform to the USDA Food Safety and Inspection Service performance standards. These standards include, but are not limited to, the ability of this product to be safe for use in official meat and poultry establishments, and to perform well under a daily regimen of thorough cleaning, cyclical temperature change, and wet conditions. This product may be used where there is a possibility of incidental food contact. 16 Other information Contact: Regulatory Affairs US4 Page 767 of 1287 Page 767 of 1287 Page 767 of 1287 Page 767 of 1287 ---PAGE BREAK--- Page 768 of 1287 Page 768 of 1287 Page 768 of 1287 Page 768 of 1287 ---PAGE BREAK--- Page 769 of 1287 Page 769 of 1287 Page 769 of 1287 Page 769 of 1287 ---PAGE BREAK--- Page 770 of 1287 Page 770 of 1287 Page 770 of 1287 Page 770 of 1287 ---PAGE BREAK--- Page 771 of 1287 Page 771 of 1287 Page 771 of 1287 Page 771 of 1287 ---PAGE BREAK--- Page 772 of 1287 Page 772 of 1287 Page 772 of 1287 Page 772 of 1287 ---PAGE BREAK--- SECTION – MATERIAL IDENTIFICATION AND USE Material Name Muriatic Acid Manufacturer Crown Chemical Products Inc Supplier’s Name Street Address 6125 Netherhart Rd Mississauga Ontario L5T 1G5 Suppliers Address Emergency Tel# (905) 5640904 Chemical Name Chemical Family Hydrochloric Acid Molecular Weight Material Use SECTION II – HARZODOUS INGREDIENTS OF MATERIAL Hazardous Ingredients Approximate Concentration % C.A.S. N.A. or U.N. Numbers Exposure Limits LD50/ LC50 Specify Species and Route Hydrochloric Acid 31.5 007647-01-0 LD50 not determined LC50 inhalation, rat) = 3124 ppm for 1 hour. Water Balance 007732-18-5 SECTION III – PHYSICAL DATA FOR MATERIAL Physical Liquid Odour and Appearance Colourless to yellow fuming liquid. Sharp pungent irritating odour. Specific Gravity 1.16 Evaporation Rate No data Boiling Point 81.50C Freezing Point(0C) -40 Vapour pressure 24 mmHG @ 200c Odour Threshold N/AV ph Strong acid less than 1 Vapour Density (g/ml) 11.0 Coefficient of Water/Oil Distribution N/AV SECTION IV – FIRE AND EXPLOSION HAZARD OF MATERIAL Flammability (if yes, under which conditions:) Non-flammable Means of Extinction Non Flammable. Flashpoint (0C) and Method Non flammable UEL By Vol.) N/AP LEL By Vol.) N/AP Auto Ignition Temp. (0C) Non flammable TDG Flammability Classification N/AV Fire or Explosion Hazards Hydrochloric acid itself is non-flammable. There is however, a latent fire or explosion hazard due to hydrogen gas generated when acid is in contact with metals. Fire Fighting Equipment. Full protective equipment including a self contained breathing apparatus should be worn for protection against corrosive liquid and vapour. Explosion Data – Sensitivity to Chemical Impact N/AV Rate of Burning N/AV Explosive Power N/AV Sensitivity to Static Discharge N/AV Flammability Reactivity Health Personal Protection Page 773 of 1287 Page 773 of 1287 Page 773 of 1287 Page 773 of 1287 ---PAGE BREAK--- Material Name Muriatic Acid SECTION V – REACTIVITY DATA Chemical Stability Under Normal Conditions Stable Incompatibility to Other Substances Avoid base and corrosive materials. Avoid contact with most metals. Avoid oxidizing material, can oxidize to chlorine. Under Fire Conditions Toxic and corrosive HCI gas may be released. Hazardous Decomposition Products None SECTION VI – TOXICOLOGICAL PROPERTIES OF PRODUCT Route Of Entry X Skin Absorption X Eye Contact Inhalation Acute X Inhalation Chronic X Ingestion X Skin Contact Effects Of Acute Exposure To Product: Eyes – may cause pain, (tears), and severe irritation with corneal injury which may result in permanent impairment of vision, even blindness. Skin Contact – Short single exposure may cause severe skin burns. Skin Absorption – A single prolonged exposure is not likely to result in the material being absorbed through skin in harmful amounts. The dermal LD50 has not been determined. Ingestion – Ingestion may cause gastrointestinal irritation or ulceration and severe burns of the mouth and throat. Inhalation – Excessive vapour concentrations are readily attainable and may cause serious adverse effects, even death. Excessive exposure may cause severe irritation and injury to upper respiratory tract and lungs. Effects Of Chronic Exposure To Product Irritancy Of Product: N/AV Exposure Limits Of Product: ACGIH TLV – Ceiling : 5ppm Sensitization To Product: N/AV Synergistic Materials: N/AV  Carcinogenicity  Reproductive Effects  Teratogenicity  Mutagenicity Carcinogenicity Data - The ingredients of this product are not listed as carcinogens by NTP (National Toxicology Program), not regulated as carcinogens by OSHA (Occupational Safety and Health Administration) and have not been evaluated by IARC (International Agency for Research on Cancer) or ACGIH (American Conference of Governmental Industrial Hygienists). SECTION VII – PREVENTIVE MEASURES Gloves Neoprene, natural rubber or PVC. Respiratory When airborne exposure guidelines and / or comfort levels may be exceeded, use and approved air-purifying respirator. For emergency and other conditions where the exposure guideline may be greatly exceeded, use an approved positive-pressure self-contained breathing apparatus. Eye Use chemical goggles. If vapour exposure causes eye irritation, use a full-face respirator. Wear a face-shield which allows use of chemical goggles, or a full-face respirator, to protect face and eyes when there is any likelihood of splashes. Eye wash fountain and safety shower must be located in immediate work area. Ventilation Control airborne concentration below the exposure guideline. Use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations. Clothing Use protective clothing impervious to this material. Selection of specific items such as gloves, boots, aprons, or full- body suits will depend on operation. Safety shower should be located in immediate work area. Wash contaminated clothing before reuse. Dispose of contaminated shoes. Footwear Use protective boots and dispose of them after use. Leak And Spill Procedure If spill is significant notify appropriate government environmental authorities. Ventilate and evacuate area. Stop and contain leak or spill. Cover with dry sand , ashes or gravel. Neutralize and dispose of in polyethylene containers. Do not allow to enter waterways. Waste Disposal Disposal of Hydrochloric Acid must meet all federal, provincial and local regulations. Page 774 of 1287 Page 774 of 1287 Page 774 of 1287 Page 774 of 1287 ---PAGE BREAK--- Material Name Muriatic Acid SECTION VII – PREVENTIVE MEASURES (CONTINUED) Handling Procedures And Equipment Suitable materials for equipment and containers include; rubber lined steel, polyethylene, polyester FRP, PVC polypropylene, Teflon or Kynar. Storage Requirements Store in cool, dry well ventilated area in closed containers away from heat sources, metals and oxidizers. SECTION VIII – FIRST AID MEASURES Skin Immediate continued and thorough washing in flowing water for 30 minutes is imperative while removing contaminated clothing. Prompt medical consultation is essential. Eye Immediate and continuous irrigation with flowing water at least 30 minutes is imperative. Prompt medical consultations essential. Ingestion Do not induce vomiting. Give large amounts of water or milk if available and transport to medical facility. Inhalation Remove to fresh air. If not breathing, give mouth-to-mouth resuscitation (CPR). If breathing is difficult, give oxygen. Call a physician. Note To Physician Corrosive. May cause stricture. If lavage is performed, suggest endotracheal and / or esophagoscopic control. If burn is present, treat as any thermal burn, after decontamination. No specific antidote. Supportive care. Treatment based on judgement of the physician in response to reactions of the patient. SECTION IX – PREPARATION DATE OF M.S.D.S. Additional Information/Comments The information herein is given in good faith but no warranty, expressed or implied, is made. Sources Used Prepared By: Crown Chemical Products Inc. Phone Number (905) 564 0904 Date July 27, 2015 Page 775 of 1287 Page 775 of 1287 Page 775 of 1287 Page 775 of 1287 ---PAGE BREAK--- Material Safety Data Sheet Coolant Additives Page 1 of 5 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Product Name: NAPA Kool 4055, 4056, 4057, 4058 WIX Cool 24055, 24056, 24057, 24058 CARQUEST Cooling Systems Treatment 89055, 89056, 89057, 89058 Trade Name and Synonyms: NAPA Kool Coolant Additive Wix Cool Coolant Additive CARQUEST Cooling Systems Treatment Chemical Name and Synonyms: Nitrite-nitrate-borate, sodium hydroxide corrosion inhibitor. Chemical Family: Industrial water treatment Product Use: Vehicle coolant treatment MSDS Date of Preparation: March 31, 2010 Company Identification Manufacturer Telephone Numbers Wix Filtration Products Division, Affinia Group PO Box 1967 Gastonia, NC 28053 Product Information: (704) 869-3700 x2769 Emergency Phone: (800) 424-9300 Chemtrec SECTION 2: HAZARDS IDENTIFICATION Physical Appearance: Red colored liquid. Mild odor. EMERGENCY OVERVIEW Hazards Identification: May cause severe eye and skin irritation or burns. Repeated skin contact may cause allergic skin reaction. Inhalation of mists may cause irritation of the nose, throat and upper respiratory tract. Ingestion may be fatal. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS Number Amount Sodium Borate 1303-96-4 <10% Sodium Nitrate 7632-00-0 Sodium Nitrite 7631-99-4 2-Mercaptobenzothiazole 149-30-4 Sodium Hydroxide 1310-73-2 SECTION 4: FIRST AID MEASURES Eye Contact: Flush eyes thoroughly with running water for at least 15 minutes. Get immediate medical attention. Skin Contact: Flush with water for at least 15 minutes then wash with mild soap and water. Seek medical attention if irritation develops. Inhaled: If mists are inhaled, remove to fresh air. Seek immediate medical attention. Page 776 of 1287 Page 776 of 1287 Page 776 of 1287 Page 776 of 1287 ---PAGE BREAK--- Material Safety Data Sheet Coolant Additives Page 2 of 5 Swallowed: If swallowed, do not induce vomiting. Rinse mouth with water and drink 1-2 glasses of water. Seek immediate medical attention. SECTION 5: FIRE FIGHTING MEASURES Fire and Explosion Hazards: This product contains approximately 80% water and is not flammable or combustible. Dried product (after the water has evaporated) is classified as an oxidizer. Contact of dried residue with flammable or combustible material including clothing may cause fire. Dust clouds from dried product may be explosive. Explosion is possible if residue is heated above 1000°F or when mixed with cyanides. Dried residue will ignite with friction when contaminated with organic materials (grass, sawdust, soils, etc.). Extinguishing Media: Use any media that is appropriate for the surrounding fire. Special Fire Fighting Procedures: Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing. Cool fire exposed containers and structures with water. Hazardous Combustion Products: Carbon oxides, oxides of nitrogen, boron oxides, oxides of sulfur and sodium oxides. SECTION 6: ACCIDENTAL RELEASE MEASURES Use appropriate protective clothing and equipment during clean-up. Absorb small spills with an inert (non-combustible) absorbent and place in a container for disposal. Do NOT use sawdust, rags or any other combustible material. Combustible absorbents may catch fire as they dry in contact with this product. Contain large spills with sand or earth. Do not use combustible materials. Pump liquid into holding tanks. Collect residue with an inert absorbent as described above for small spills. Prevent release to the environment. SECTION 7: HANDLING AND STORAGE Avoid generating and breathing mists and avoid contact with eyes, skin or clothing. Use only with adequate ventilation. Keep product away from heat and all flammable or combustible materials including paper, solvents, fuels, wooden floors and clothing. Wash thoroughly after handling. Remove and launder contaminated clothing before reuse. DO NOT allow product to dry on clothing. Storage: Store in a cool, dry, well-ventilated area away from combustible materials and acids. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Chemical Name Exposure Limits Sodium borate 2 mg/m3 TWA, 6 mg/m3 STEL ACGIH TLV (inhalable) Sodium nitrite None Established Sodium nitrate None Established 2-Mercaptobenzothiazole 5 mg/m3 TWA skin AIHA WEEL Sodium Hydroxide 2 mg/m3 TWA OSHA PEL, 2 mg/m3 Ceiling ACGIH TLV Page 777 of 1287 Page 777 of 1287 Page 777 of 1287 Page 777 of 1287 ---PAGE BREAK--- Material Safety Data Sheet Coolant Additives Page 3 of 5 Ventilation: Use with adequate general or local exhaust ventilation to maintain exposure concentrations below the exposure limits.. Respiratory Protection: For operations where exposures are excessive or irritation is experienced, a NIOSH approved respirator should be used. Respirator selection and use should be based on contaminant type, form and concentration. Follow OSHA 1910.134, ANSI Z88.2 and good Industrial Hygiene practice. Skin Protection: Wear rubber or other impervious gloves. Eye Protection: Chemical safety goggles. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Appearance and Odor: Red-colored liquid with a mild odor Specific Gravity: 1.170 Boiling Point: 102°C (216°F) Water Solubility: Soluble Melting Point: Not determined Vapor Pressure: Same as water Flash Point: None Vapor Density: Same as water Autoignition Point: None pH: 11.3 SECTION 10: STABILITY AND REACTIVITY Stability: This product is stable. Incompatibility/Conditions to Avoid: Avoid extreme heat. Prevent contact with all flammable or combustible materials including paper, solvents, fuels, wooden floors and clothing, strong acids, reducing agents, ammonium compounds, cyanides. Hazardous Decomposition Products: Thermal decomposition will generate carbon oxides, oxides of nitrogen, boron oxides, oxides of sulfur and sodium oxides. Hazardous Polymerization: Will not occur SECTION 11: TOXICOLOGICAL INFORMATION Potential Health Effects: Eye: May cause severe irritation or burns. Skin: May cause irritation. Sodium nitrite and sodium borate may be harmful if absorbed through the skin. Repeated skin contact may cause allergic skin reaction. Inhalation: Mists may cause irritation of the mucous membranes and upper respiratory tract. Absorption may cause effects similar to those described under ingestion. Ingestion: May be fatal if swallowed. May cause burns t the mouth and throat, dizziness, nausea, vomiting, low blood pressure, cyanosis, rapid heart beat, convulsions and collapse. Chronic/Carcinogenicity: Prolonged or repeated exposure may cause nervous system effects, liver damage, kidney damage and effects on the blood. Sodium borate causes adverse reproductive effects in Page 778 of 1287 Page 778 of 1287 Page 778 of 1287 Page 778 of 1287 ---PAGE BREAK--- Material Safety Data Sheet Coolant Additives Page 4 of 5 laboratory animals.. None of the components of this product present at 0.1% or greater are listed as carcinogens by ACGIH, IARC, NTP or OSHA. SECTION 12: ECOLOGICAL INFORMATION No ecotoxicity data is available for the product. 2-Mercaptobenzothiazole is considered toxic to the aquatic environment. Avoid release to the environment. SECTION 13: DISPOSAL INFORMATION Dispose in accordance with all local and national regulations. SECTION 14: TRANSPORT INFORMATION US DOT Shipping Description: Not regulated IMDG Code (Ocean): Not regulated ICAO/IATA (AIR): Not regulated Note: If a package contains 2000 lbs or more, the shipping description is UN3082, Environmentally Hazardous Substance, liquid, n.o.s. (Sodium Nitrite), 9, III RQ SECTION 15: REGULATORY INFORMATION CERCLA 103 Reportable Quantity: This product has a reportable quantity of 2000 lbs based on 5% sodium nitrite with an RQ of 100 lbs. Many states have more stringent reporting requirements. Report releases as required by all federal, state and local authorities. SARA TITLE III: Hazard Category for Section 311/312: Acute health, chronic health Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313 Reporting requirements: Sodium nitrite Sodium nitrate (nitrate compound) 2-Mercaptobenzothiazole Section 302 Extremely Hazardous Substances (TPQ): None EPA Toxic Substances Control Act (TSCA) Status: All of the components of this product are listed on the TSCA inventory. SECTION 16: OTHER INFORMATION NFPA Hazard Rating: Health: 3 Fire: 0 Instability: 0 HMIS Hazard Rating: Health: 3 Fire: 0 Physical Hazard: 0 Page 779 of 1287 Page 779 of 1287 Page 779 of 1287 Page 779 of 1287 ---PAGE BREAK--- Material Safety Data Sheet Coolant Additives Page 5 of 5 The information is believed to be accurate and represents the best information currently available to us. WE MAKE NO WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, WITH RESPECT TO SUCH INFORMATION. We assumes no liability resulting from its use. Users should conduct their own investigations to determine the suitability of the information for their own particular application and purpose.. Page 780 of 1287 Page 780 of 1287 Page 780 of 1287 Page 780 of 1287 ---PAGE BREAK--- NEUTRO-WASH™ Safety Data Sheet Prepared Date: 3/12/2015 Print date: 6/2/2015 Revision: 1 Page 1 of 5 www.rhomar.com SECTION 1: IDENTIFICATION Product Identifier Product Name Product Form Product Code NEUTRO-WASH™ Liquid RH-017 Relevant identified uses of the substance or mixture: Neutralize alkaline surfaces and remove salt as well as calcium and magnesium and brines from equipment. Details of the supplier of the safety data sheet Rhomar Industries, Inc. 2107 E. Rockhurst St. Springfield, MO 65802 USA T [PHONE REDACTED]; F [PHONE REDACTED] [EMAIL REDACTED] Emergency telephone number 1-[PHONE REDACTED] SECTION 2: HAZARDS IDENTIFICATION Classification: Skin Irritation (Category 2) Eye Irritation (Category 2) Acute Aquatic Toxicity (Category 3) Chronic Aquatic Toxicity (Category 3) Specific Target Organ – single exposure (Category central nervous system Hazard Statements: Causes skin irritation. Causes serious eye irritation. Harmful to aquatic life with long lasting effects. May cause drowsiness or dizziness. Precautionary Statements Prevention: Wash skin thoroughly after handling. Avoid release to the environment. Wear protective gloves, eye protection, face protection. Response: Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation occurs. Skin Contact: Wash with plenty of soap and water. Get medical attention if irritation persists. Ingestion: Call a doctor/physician if you feel unwell. Rinse mouth Other: Take off contaminated clothing and wash before reuse. Disposal: Dispose of contents/container to an approved waste treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Signal Word: Warning Page 781 of 1287 Page 781 of 1287 Page 781 of 1287 Page 781 of 1287 ---PAGE BREAK--- Prepared Date: 3/12/2015 NEUTRO‐WASH™ Page 2 of 5 SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Mixture Name CAS # Weight % Sulfamic Acid 5329-14-6 1-5 Sodium Hydroxide 1310-73-2 1-5 Isopropyl Alcohol 67-63-0 1-5 Any concentration shown as a range is to protect confidentiality or is due to process variation. SECTION 4: FIRST-AID MEASURES First Aid Measures Inhalation: Remove to fresh air. If breathing stops, provide artificial respiration. If persist, call physician. Eye Contact: If in eyes, rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation persists. Ingestion: Rinse mouth. Call a Poison Center or doctor/physician if you feel unwell. Skin Contact: Remove contaminated clothing, wash with plenty of soap and water. If skin irritation persists, call a physician. Most Important and Effects, both Acute and Delayed May cause eye irritation with reddening and watering. May cause skin irritation. Indication of any Immediate Medical Attention and Special Treatment Needed No data available. SECTION 5: FIRE-FIGHTING MEASURES Suitable Extinguishing Media Water spray, alcohol resistant foam, dry chemical or carbon dioxide. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Nitrogen oxides, sulphur oxides. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures Personal Precautions Use personal protective equipment as required. Avoid breathing vapor/mist. Ensure adequate ventilation. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and Material for Containment and Cleaning Up Contain spillage and then pick up and arrange for disposal. Do not let product enter the drains. Keep in suitable, closed containers for disposal. Page 782 of 1287 Page 782 of 1287 Page 782 of 1287 Page 782 of 1287 ---PAGE BREAK--- Prepared Date: 3/12/2015 NEUTRO‐WASH™ Page 3 of 5 SECTION 7: HANDLING AND STORAGE Precautions for Safe Handling Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Wash face, hands and any exposed skin thoroughly after handling. Conditions for Safe Storage, Including any Incompatibilities Storage Conditions Keep containers closed in a dry, cool and well-ventilated place. SECTON 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name CAS # ACGIH – TLV OSHA PEL NIOSH Sulfamic Acid 5329-14-6 No limits established No limits established No limits established Sodium Hydroxide 1310-73-2 2 mg/m³ 2 mg/m³ 2 mg/m³ Isopropyl Alcohol 67-63-0 200 ppm 400ppm 980 mg/m³ 500ppm 1225 mg/m³ Appropriate Engineering Controls Engineering Controls: Provide adequate ventilation for dust control. Individual Protection Measures, such as Personal Protective Equipment Eye/Face Protection: Wear NIOSH approved safety goggles or safety glasses with side shields. Skin and Body Protection: Wear suitable protective clothing. Respiratory Protection: Ensure adequate ventilation, especially in confined areas. General Hygiene Considerations: Handle in accordance with good industrial hygiene and safety practice. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Information on Basic Physical and Chemical Properties Physical State Solid Color White pH 3-4 at 68° F Melting Point/Freezing Point No data available Boiling Point/Boiling Range No data available Flash Point No data available Evaporation Rate No data available Flammability (Solid, Gas) No data available Upper Flammable Limits No data available Lower Flammable Limits No data available Vapor Pressure No data available Vapor Density No data available Specific Gravity 1.05 g/cm³ at 77° F Water Solubility Soluble Partition Coefficient No data available Autoignition Temperature No data available Decomposition Temperature No data available Kinematic Viscosity No data available Dynamic Viscosity No data available Explosive Properties No data available Oxidizing Properties No data available Odor No data available Odor Threshold No data available SECTION 10: STABILITY AND REACTIVITY Reactivity No data available Chemical Stability Stable under recommended storage conditions. Page 783 of 1287 Page 783 of 1287 Page 783 of 1287 Page 783 of 1287 ---PAGE BREAK--- Prepared Date: 3/12/2015 NEUTRO‐WASH™ Page 4 of 5 Possibility of Hazardous Reactions No data available Conditions to Avoid No data available Incompatible Materials Strong oxidizing agents, strong bases. Hazardous Decomposition Products Carbon dioxide, carbon monoxide. SECTION 11: TOXICOLOGICAL INFORMATION Information on Likely Routes of Exposure Product Information Inhalation: Avoid breathing fumes/vapors/mist. Eye contact: Causes serious eye irritation Skin Contact: Causes skin irritation. Ingestion: Harmful if swallowed. This product as a whole has not been tested for acute toxicity; the following is based on component data: Chemical Name CAS # Oral LD50 Dermal LD50 Inhalation LC50 Sulfamic Acid 5329-14-6 =3,160 mg/kg (Rat) No data available No data available Sodium Hydroxide 1310-17-2 No data available No data available No data available Isopropyl Alcohol 67-63-0 =5,045 mg/kg (Rat) 12,800 mg/kg(Rabbit) 16,000 ppm (Rat) 8 h Chemical Name Sulfamic Acid Sodium Hydroxide Isopropyl Alcohol Skin corrosion/irritation Moderate skin irritation (Rabbit) Causes severe burns – 24h (Rabbit) Mild irritation (Rabbit) Serious eye damage/irritation Moderate eye irritation (Rabbit) Corrosive – 24h (Rabbit) Eye irritation (Rabbit) -8h Respiratory or skin sensitization No data available Will not occur No data available Mutagenicity No data available No data available No data available Carcinogenicity Not Classifiable Negative Not Classifiable Reproductive toxicity No data available No data available No data available Specific target organ toxicity single exposure No data available No data available Inhalation-Oral may cause drowsiness or dizziness. Specific target organ toxicity repeated exposure No data available No data available No data available Aspiration hazard No data available No data available No data available Delayed and Immediate Effects as well as Chronic Effects from Short and Long-term Exposure Carcinogenicity: This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP or EPA classification. Numerical Measures of Toxicity: Not determined. SECTION 16: OTHER INFORMATION HMIS Ratings: Health: 2 Flammability: 0 Reactivity: 1 Page 784 of 1287 Page 784 of 1287 Page 784 of 1287 Page 784 of 1287 ---PAGE BREAK--- Prepared Date: 3/12/2015 NEUTRO‐WASH™ Page 5 of 5 Indication of changes: Revision-1 Date Sheet Prepared: 03/1/2015 Other Information: Author – EHS Administrator The information herein is presented in good faith and believed to be correct as of the date hereof. However, the manufacturer makes no representation as to the completeness and accuracy thereof. Users must make their own determination as to the suitability of the product for their purposes prior to use. No representations or warranty’s, either express or implied of merchantability, fitness for a particular purpose or of any other nature with respect to the product or to the information herein is made hereunder. The manufacturer shall in no event be responsible for any damages of whatsoever nature directly or indirectly resulting from the publication or use of or reliance upon information contained herein. Page 785 of 1287 Page 785 of 1287 Page 785 of 1287 Page 785 of 1287 ---PAGE BREAK--- Page 1/4 Safety Data Sheet acc. to OSHA HCS Printing date 10/09/2014 Revised On 10/09/2014 39.6.0 1 Identification of the substance and manufacturer Trade name: NEW EQUIPMENT YELLOW Product code: [PHONE REDACTED] Product category PC9a Paints and coatings. Manufacturer/Supplier: Seymour of Sycamore 917 Crosby Avenue Sycamore, IL 60178 Phone: [PHONE REDACTED] www.seymourpaint.com Emergency telephone number: CHEMTEL 1-[PHONE REDACTED], [PHONE REDACTED] *if located outside the U.S.* 2 Hazard(s) identification Classification of the substance or mixture Flam. Aerosol 1 H222 Extremely flammable aerosol. Press. Gas H280 Contains gas under pressure; may explode if heated. Carc. 2 H351 Suspected of causing cancer. Eye Irrit. 2A H319 Causes serious eye irritation. GHS Hazard pictograms GHS02 GHS04 GHS07 GHS08 Signal word Danger Hazard statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Suspected of causing cancer. Precautionary statements If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. Obtain special instructions before use. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash hands thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Do not handle until all safety precautions have been read and understood. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 Store in a well-ventilated place. Dispose of contents/container in accordance with local/regional/national/international regulations. 3 Composition/information on ingredients Chemical characterization: Mixtures Chemical Description: This product is a mixture of the substances listed below with nonhazardous additions. Dangerous components: 67-64-1 Acetone 19.96% 74-98-6 propane 15.73% 106-97-8 n-butane 9.24% 7727-43-7 barium sulphate, natural 8.42% 108-10-1 methyl isobutyl ketone 5.54% 2807-30-9 Glycol Ether EP 5.39% 107-87-9 Methyl Propyl Ketone 2.86% 1330-20-7 xylene (mix) 2.49% 108-65-6 PM acetate 1.89% 110-19-0 isobutyl acetate 1.86% 13463-67-7 titanium dioxide 1.43% 4 First-aid measures After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Remove contaminated clothing. Wash exposed area with soap and water. After eye contact: Rinse opened eye for several minutes under running water. If persist, consult a doctor. After swallowing: Rinse out mouth and then drink plenty of water. Rinse mouth with water. Do not induce vomiting. Most important and effects: Dizziness Indication of any immediate medical attention needed: No further relevant information available. 5 Fire-fighting measures Extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray. (Contd. on page 2) US4 Page 786 of 1287 Page 786 of 1287 Page 786 of 1287 Page 786 of 1287 ---PAGE BREAK--- Page 2/4 Safety Data Sheet acc. to OSHA HCS Printing date 10/09/2014 Revised On 10/09/2014 Trade name: NEW EQUIPMENT YELLOW (Contd. of page 1) 39.6.0 Special hazards: Can form explosive gas-air mixtures. Protective equipment for firefighters: A respiratory protective device may be necessary. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures: Wear protective equipment. Keep unprotected persons away. Use respiratory protective device against the effects of fumes/dust/aerosol. Methods and material for containment and cleaning up: Ensure adequate ventilation. 7 Handling and storage Precautions for safe handling Use only in well ventilated areas. Storage requirements: Keep away from sources of heat and direct sunlight. Do not warehouse in subfreezing conditions. Store locked up. 8 Exposure controls/personal protection Components with limit values that require monitoring at the workplace: 67-64-1 Acetone PEL (USA) Long-term value: 2400 mg/m³, 1000 ppm REL (USA) Long-term value: 590 mg/m³, 250 ppm TLV (USA) Short-term value: (1782) NIC-1187 mg/m³, (750) NIC-500 ppm Long-term value: (1188) NIC-594 mg/m³, (500) NIC-250 ppm BEI 74-98-6 propane PEL (USA) Long-term value: 1800 mg/m³, 1000 ppm REL (USA) Long-term value: 1800 mg/m³, 1000 ppm TLV (USA) refer to Appendix F 106-97-8 n-butane REL (USA) Long-term value: 1900 mg/m³, 800 ppm TLV (USA) Short-term value: 2370 mg/m³, 1000 ppm 7727-43-7 barium sulphate, natural PEL (USA) Long-term value: 15* mg/m³ *total dust **respirable fraction REL (USA) Long-term value: 10* mg/m³ *total dust **respirable fraction TLV (USA) Long-term value: 5* mg/m³ *inhalable fraction; E 108-10-1 methyl isobutyl ketone PEL (USA) Long-term value: 410 mg/m³, 100 ppm REL (USA) Short-term value: 300 mg/m³, 75 ppm Long-term value: 205 mg/m³, 50 ppm TLV (USA) Short-term value: 307 mg/m³, 75 ppm Long-term value: 82 mg/m³, 20 ppm BEI 107-87-9 Methyl Propyl Ketone PEL (USA) Long-term value: 700 mg/m³, 200 ppm REL (USA) Long-term value: 530 mg/m³, 150 ppm TLV (USA) Short-term value: 529 mg/m³, 150 ppm 1330-20-7 xylene (mix) PEL (USA) Long-term value: 435 mg/m³, 100 ppm REL (USA) Short-term value: 655 mg/m³, 150 ppm Long-term value: 435 mg/m³, 100 ppm TLV (USA) Short-term value: 651 mg/m³, 150 ppm Long-term value: 434 mg/m³, 100 ppm BEI 108-65-6 PM acetate WEEL (USA) Long-term value: 50 ppm 110-19-0 isobutyl acetate PEL (USA) Long-term value: 700 mg/m³, 150 ppm REL (USA) Long-term value: 700 mg/m³, 150 ppm TLV (USA) Long-term value: 713 mg/m³, 150 ppm Ingredients with biological limit values: 67-64-1 Acetone BEI (USA) 50 mg/L Medium: urine Time: end of shift Parameter: Acetone (nonspecific) (Contd. on page 3) US4 Page 787 of 1287 Page 787 of 1287 Page 787 of 1287 Page 787 of 1287 ---PAGE BREAK--- Page 3/4 Safety Data Sheet acc. to OSHA HCS Printing date 10/09/2014 Revised On 10/09/2014 Trade name: NEW EQUIPMENT YELLOW (Contd. of page 2) 39.6.0 108-10-1 methyl isobutyl ketone BEI (USA) 1 mg/L Medium: urine Time: end of shift Parameter: MIBK 1330-20-7 xylene (mix) BEI (USA) 1.5 g/g creatinine Medium: urine Time: end of shift Parameter: acids Hygienic protection: Keep away from foodstuffs and animal feed. Wash hands after use. Immediately remove all soiled and contaminated clothing. Wash hands after use. Avoid contact with the eyes and skin. Do not eat or drink while working. Breathing equipment: A respirator is generally not necessary when using this product outdoors or in large open areas. In cases where short and/or long term overexposure exists, a charcoal filter respirator should be worn. If you suspect overexposure conditions exist, please consult an authority on chemical hygeine. Hand protection: Protective gloves. The glove material must be impermeable and resistant to the substance. Eye protection: sealed goggles 9 Physical and chemical properties Appearance: Aerosol. Odor: Aromatic Odor threshold: Not determined. pH-value: Not determined. Melting point/Melting range Undetermined. Boiling point: -44 °C (-47 Flash point: -19 °C Flammability (solid, gas): Extremely flammable. Decomposition temperature: Not determined. Auto igniting: Product is not self-igniting. Danger of explosion: In use, may form flammable/explosive vapour-air mixture. Lower Explosion Limit: 1.7 Vol % Upper Explosion Limit: 10.9 Vol % Vapor pressure: Not determined. Relative Density: Between 0.77 and 0.85 (Water equals 1.00) Vapour density Not determined. Evaporation rate Not applicable. Partition coefficient: n-octonal/water: Not determined. Solubility: Not determined. Viscosity: Not determined. VOC content: 498.8 g/l / 4.16 lb/gl VOC content (less exempt solvents): 46.4 % MIR Value: 1.10 Solids content: 33.2 % 10 Stability and reactivity Reactivity: Stable at normal temperatures. Conditions to avoid: Do not allow can to exceed 120 degrees Fahrenheit. Do not warehouse in subfreezing temperatures. Chemical stability: Not fully evaluated. Possibility of hazardous reactions: No dangerous reactions known. Incompatible materials: No further relevant information available. Hazardous decomposition: No dangerous decomposition products known. 11 Toxicological information LD/LC50 values that are relevant for classification: 106-97-8 n-butane Inhalative LC50/4 h 658 mg/l (rat) 108-10-1 methyl isobutyl ketone Oral LD50 2100 mg/kg (rat) Dermal LD50 16000 mg/kg (rab) Inhalative LC50/4 h 8.3-16.6 mg/l (rat) 1330-20-7 xylene (mix) Oral LD50 8700 mg/kg (rat) Dermal LD50 2000 mg/kg (rbt) Inhalative LC50/4 h 6350 mg/l (rat) (Contd. on page 4) US4 Page 788 of 1287 Page 788 of 1287 Page 788 of 1287 Page 788 of 1287 ---PAGE BREAK--- Page 4/4 Safety Data Sheet acc. to OSHA HCS Printing date 10/09/2014 Revised On 10/09/2014 Trade name: NEW EQUIPMENT YELLOW (Contd. of page 3) 39.6.0 108-65-6 PM acetate Oral LD50 8500 mg/kg (rat) Inhalative LC50/4 h 35.7 mg/l (rat) 110-19-0 isobutyl acetate Oral LD50 4763 mg/kg (rbt) 13463-67-7 titanium dioxide Oral LD50 >20000 mg/kg (rat) Dermal LD50 >10000 mg/kg (rbt) Inhalative LC50/4 h >6.82 mg/l (rat) Information on toxicological effects: No data available. Sensitization: No sensitizing effects known. Carcinogenic categories IARC (International Agency for Research on Cancer) 108-10-1 methyl isobutyl ketone 2B 1330-20-7 xylene (mix) 3 13463-67-7 titanium dioxide 2B NTP (National Toxicology Program) None of the ingredients is listed. OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. 12 Ecological information Aquatic toxicity: Hazardous for water, do not empty into drains. Persistence and degradability: The product is degradable after prolonged exposure to natural weathering processes. Bioaccumulative potential: No further relevant information available. Mobility in soil: No further relevant information available. Other adverse effects: No further relevant information available. 13 Disposal considerations Dispose of in accordance with local, state, and federal regulations. Do not puncture, incinerate, or compact. Partially empty cans must be disposed of responsibly. Do not heat or cut empty containers with electric or gas torches. Recommendation: Completely empty cans should be recycled. 14 Transport information UN-Number UN1950 DOT Aerosols, flammable ADR 1950 Aerosols Transport hazard class(es): Class 2.1 Marine pollutant: No Special precautions for user: Warning: Gases EMS Number: F-D,S-U Packaging Group: UN "Model Regulation": UN1950, Aerosols, 2.1 15 Regulatory information SARA Section 355 (extremely hazardous substances): None of the ingredients in this product are listed. SARA Section 313 (Specific toxic chemical listings): 7727-43-7 barium sulphate, natural 108-10-1 methyl isobutyl ketone 1330-20-7 xylene (mix) CPSC: This product complies with 16 CFR 1303 and does not contain more than 90 ppm of lead. California Proposition 65 chemicals known to cause cancer: 108-10-1 methyl isobutyl ketone 13463-67-7 titanium dioxide 100-41-4 ethyl benzene EPA: 67-64-1 Acetone I 7727-43-7 barium sulphate, natural D, CBD(inh), NL(oral) 108-10-1 methyl isobutyl ketone I 1330-20-7 xylene (mix) I 110-19-0 isobutyl acetate D 16 Other information Contact: Regulatory Affairs US4 Page 789 of 1287 Page 789 of 1287 Page 789 of 1287 Page 789 of 1287 ---PAGE BREAK--- 1. IDENTIFICATION Product identifier Product Name NICKEL ANTI-SEIZE LUBRICANT 1LB BB Other means of identification Product Code 77164 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Lubricant Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: [PHONE REDACTED] International Emergency: 00+1+ [PHONE REDACTED] Contract Number: MIS0003453 E-mail address [EMAIL REDACTED] 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin sensitization Category 1 Carcinogenicity Category 2 Label elements Emergency Overview Page 1 / 9 Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 May cause an allergic skin reaction Suspected of causing cancer Revision Date 12-Dec-2014 SAFETY DATA SHEET Version 1 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Warning Page 790 of 1287 Page 790 of 1287 Page 790 of 1287 Page 790 of 1287 ---PAGE BREAK--- Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Avoid breathing mists or vapors Wear protective gloves Contaminated work clothing should not be allowed out of the workplace Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention Specific treatment (see supplemental first aid instructions on this label) IF ON SKIN: Wash with plenty of soap and water If skin irritation or rash occurs: Get medical advice/attention Wash contaminated clothing before reuse Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Toxic to aquatic life with long lasting effects. The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3 % DMSO extract as measured by IP 346. This note applies only to certain complex oil derived substances in Annex I. No. Respirable dust. Unknown acute toxicity 34.5% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret DISTILLATES (PETROLEUM), SOLVENT-REFINED HEAVY NAPHTHENIC 64741-96-4 30 - 60 * GRAPHITE 7782-42-5 10 - 30 * NICKEL 7440-02-0 5 - 10 * ALUMINIUM POWDER 7429-90-5 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Page 2 / 9 77164 - NICKEL ANTI-SEIZE LUBRICANT 1LB BB Revision Date 12-Dec-2014 Physical state Paste Odor Petroleum odor Appearance Silver Page 791 of 1287 Page 791 of 1287 Page 791 of 1287 Page 791 of 1287 ---PAGE BREAK--- Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash with soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important and effects, both acute and delayed See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media Water. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Page 3 / 9 Revision Date 12-Dec-2014 77164 - NICKEL ANTI-SEIZE LUBRICANT 1LB BB Page 792 of 1287 Page 792 of 1287 Page 792 of 1287 Page 792 of 1287 ---PAGE BREAK--- Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container closed in a dry and well-ventilated place. Store locked up. Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH GRAPHITE 7782-42-5 TWA: 2 mg/m3 respirable fraction all forms except graphite fibers TWA: 15 mg/m3 total dust TWA: 5 mg/m3 respirable fraction (vacated) TWA: 2.5 mg/m3 respirable dust natural (vacated) TWA: 10 mg/m3 total dust (vacated) TWA: 5 mg/m3 respirable fraction TWA: 15 natural IDLH: 1250 mg/m3 TWA: 2.5 mg/m3 natural respirable dust NICKEL 7440-02-0 TWA: 1.5 mg/m3 inhalable fraction TWA: 1 mg/m3 (vacated) TWA: 1 mg/m3 IDLH: 10 mg/m3 Ni TWA: 0.015 mg/m3 except Nickel carbonyl Ni ALUMINIUM POWDER 7429-90-5 TWA: 1 mg/m3 respirable fraction TWA: 15 mg/m3 total dust TWA: 5 mg/m3 respirable fraction (vacated) TWA: 5 mg/m3 Al Aluminum TWA: 5 mg/m3 Al NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 4 / 9 77164 - NICKEL ANTI-SEIZE LUBRICANT 1LB BB Revision Date 12-Dec-2014 Page 793 of 1287 Page 793 of 1287 Page 793 of 1287 Page 793 of 1287 ---PAGE BREAK--- Information on basic physical and chemical properties Physical state Paste Appearance Silver Odor Petroleum odor Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content 0 Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous polymerization Hazardous polymerization does not occur. Conditions to avoid Excessive heat. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides Metal oxides Page 5 / 9 No information available Evaporation rate < 1 Autoignition temperature No information available Revision Date 12-Dec-2014 Decomposition temperature No information available Butyl acetate = 1 Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values Lower flammability limit: No information available Vapor pressure No information available Boiling point / boiling range No information available No data available Vapor density No information available Remarks • Method Relative density 1.12 77164 - NICKEL ANTI-SEIZE LUBRICANT 1LB BB Flash point Water solubility Negligible > 204 °C / > 400 °F Solubility in other solvents No information available pH Partition coefficient No information available Page 794 of 1287 Page 794 of 1287 Page 794 of 1287 Page 794 of 1287 ---PAGE BREAK--- 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 NICKEL 7440-02-0 > 9000 mg/kg ( Rat ) - - Information on toxicological effects No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization May cause sensitization by skin contact. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA DISTILLATES (PETROLEUM), SOLVENT-REFINED HEAVY NAPHTHENIC 64741-96-4 A2 Group 1 - X NICKEL 7440-02-0 - Group 1 Known X ACGIH (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Target Organ Effects Central Vascular System (CVS), Lungs, Nasal Cavities, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 73761 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity 37% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea DISTILLATES (PETROLEUM), SOLVENT-REFINED HEAVY NAPHTHENIC 64741-96-4 - 5000: 96 h mykiss mg/L LC50 1000: 48 h Daphnia magna mg/L EC50 NICKEL 7440-02-0 0.18: 72 h Pseudokirchneriella subcapitata mg/L EC50 0.174 - 0.311: 96 h Pseudokirchneriella subcapitata mg/L EC50 static 100: 96 h Brachydanio rerio mg/L LC50 1.3: 96 h Cyprinus carpio mg/L LC50 semi-static 10.4: 96 h Cyprinus carpio mg/L LC50 static 100: 48 h Daphnia magna mg/L EC50 1: 48 h Daphnia magna mg/L EC50 Static Page 6 / 9 77164 - NICKEL ANTI-SEIZE LUBRICANT 1LB BB Revision Date 12-Dec-2014 Page 795 of 1287 Page 795 of 1287 Page 795 of 1287 Page 795 of 1287 ---PAGE BREAK--- Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes NICKEL 7440-02-0 - Included in waste streams: F006, F039 - - This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status NICKEL 7440-02-0 Toxic powder Ignitable powder ALUMINIUM POWDER 7429-90-5 Ignitable powder 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Not Listed. Contains: Natural substance(s) IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: Page 7 / 9 Revision Date 12-Dec-2014 77164 - NICKEL ANTI-SEIZE LUBRICANT 1LB BB Page 796 of 1287 Page 796 of 1287 Page 796 of 1287 Page 796 of 1287 ---PAGE BREAK--- TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % NICKEL - 7440-02-0 0.1 ALUMINIUM POWDER - 7429-90-5 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances NICKEL 7440-02-0 - X X - CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) NICKEL 7440-02-0 100 lb - RQ 100 lb final RQ RQ 45.4 kg final RQ US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 NICKEL - 7440-02-0 Carcinogen U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts GRAPHITE 7782-42-5 X X X NICKEL 7440-02-0 X X X ALUMINIUM POWDER 7429-90-5 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable Page 8 / 9 HMIS NFPA Health hazards 2 Flammability 1 Physical hazards 0 Personal protection B Health hazards 2 77164 - NICKEL ANTI-SEIZE LUBRICANT 1LB BB Flammability 1 Instability 0 Revision Date 12-Dec-2014 - Page 797 of 1287 Page 797 of 1287 Page 797 of 1287 Page 797 of 1287 ---PAGE BREAK--- NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 12-Dec-2014 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 9 / 9 77164 - NICKEL ANTI-SEIZE LUBRICANT 1LB BB Revision Date 12-Dec-2014 Page 798 of 1287 Page 798 of 1287 Page 798 of 1287 Page 798 of 1287 ---PAGE BREAK--- Page 799 of 1287 Page 799 of 1287 Page 799 of 1287 Page 799 of 1287 ---PAGE BREAK--- Page 800 of 1287 Page 800 of 1287 Page 800 of 1287 Page 800 of 1287 ---PAGE BREAK--- Page 801 of 1287 Page 801 of 1287 Page 801 of 1287 Page 801 of 1287 ---PAGE BREAK--- Page 802 of 1287 Page 802 of 1287 Page 802 of 1287 Page 802 of 1287 ---PAGE BREAK--- Material Safety Data Sheet 1. PRODUCT IDENTIFICATION Product Name: NO TOUCH ORIGINAL TIRE CARE 18OZ AE Item No: NTBP15-6 Product Type: Aerosol coating 2. COMPOSITION/INFORMATION ON INGREDIENTS Component Weight% ACGIH; TLV-TWA OSHA PEL WATER 7732-18-5 >60 Not listed Not listed 63148-62-9 10-30 Not listed Not listed PETROLEUM GASES, LIQUEFIED, SWEETENED 68476-86-8 <5 Not listed Not listed 3. HAZARDS IDENTIFICATION Toxicity: May cause eye, skin and respiratory irritation. Primary Routes of Entry: Eye and skin contact, ingestion, inhalation Signs and of Exposure: May cause redness to eyes and irritation to nasal passages. Excessive accidental exposure may cause headache, dizziness, nausea and mild respiratory irritation. Medical Conditions Recognized as Being Aggravated by Exposure: None known 4. FIRST AID MEASURES Ingestion: If swallowed, DO NOT induce vomiting. Keep individual calm. Obtain medical attention. Inhalation: Move to fresh air in case of accidental inhalation of vapours. If persist, call a physician. Skin Contact: Wash off with soap and water. If skin irritation persists, call a physician. Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists. 5. FIRE FIGHTING MEASURES Flash Point No flame projection Recommended Extinguishing Media: Carbon Dioxide, Dry Chemicals, Foam. Special Fire-Fighting Procedures: Keep containers cool. Use equipment or shielding required to protect against bursting or venting of containers. Water spray may be ineffective on flames but should be used to keep fire-exposed containers cool. Hazardous Products of Combustion: Oxides of carbon Unusual Fire/Explosion Hazards: Exposure to temperatures over 120 degrees F. may cause bursting or venting. Keep containers cool. Use equipment or shielding to protect personnel from bursting containers. Lower Explosive Limit: Not determined Upper Explosive Limit: Not determined 6. ACCIDENTAL RELEASE MEASURES Spill Procedures: Eliminate all sources of ignition. Maintain good ventilation. Take up with an inert absorbent. Store in a closed waste container until disposal. Flush spill or leak area with water. 1 of 3 Permatex, Inc. 10 Columbus Blvd. Hartford, CT 06106 USA Telephone: 1-87-Permatex (877) 376-2839 Emergency: [PHONE REDACTED] (ChemTel) International Emergency: +01-[PHONE REDACTED] Page 803 of 1287 Page 803 of 1287 Page 803 of 1287 Page 803 of 1287 ---PAGE BREAK--- 7. HANDLING AND STORAGE Storage: Store away from heat, sparks or open flame. Do not store at temperatures above 100°F (38°C). Exposure to high temperatures may cause container to burst. Store in accordance with NFPA 30B for Level 1 Aerosols. Handling: Avoid contact with skin and eyes. Use only in a well ventilated area. Wash hands before eating and smoking. Product may cause surfaces to become slippery. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Safety glasses. Skin: Neoprene or nitrile gloves recommended. Ventilation: General; local exhaust ventilation as necessary to control any air contaminants to within their exposure limits (or to the lowest feasible levels when limits have not been established) during the use of this product. Respiratory Protection: Not required under normal use. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: White foam Odor: Pungent Boiling Point: 212°F pH: 9.0-10.0 Solubility in Water: Soluble Specific Gravity: 0.99-1.02 VOC(Wt.%): 5% Vapor Pressure: Not determined Vapor Density (Air=1): >1 Evaporation Rate: <1 (butyl acetate = 1) 10. STABILITY AND REACTIVITY Chemical Stability: Stable at normal conditions Hazardous Polymerization: Will not occur Incompatabilities: Strong oxidizers Conditions to Avoid: Keep away from heat, sparks and open flame. - No smoking. Hazardous Products of Combustion: Oxides of carbon 11. TOXICOLOGICAL INFORMATION See Section 3 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended Method of Disposal: This container may be recycled in aerosol recycling centers. Before offering for recycling, empty the can by using the product according to the label. If recycling is not available, wrap the container and discard in the trash. US EPA Waste Number: D001 as per 40CFR 261.21 14. TRANSPORTATION INFORMATION DOT (49CFR 172) Ground Transport (DOT) DOT Shipping Name: Consumer Commodity Hazard Class: ORM-D UN/ID Number: None IATA Proper Shipping Name: Consumer Commodity (Not more than 1 liter) Class or Division: Class 9 UN/ID Number: ID 8000 IMDG Proper Shipping: Aerosols, Limited Quantity Hazard Class: Class 2.2 UN Number: UN 1950 2 of 3 Product Name: Item No: NTBP15-6 NO TOUCH ORIGINAL TIRE CARE 18OZ AE Page 804 of 1287 Page 804 of 1287 Page 804 of 1287 Page 804 of 1287 ---PAGE BREAK--- Marine Pollutant: None 15. REGULATORY INFORMATION SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical. NONE California Proposition 65: WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm TSCA Inventory Status: All components of this product are listed (or exempt) on the EPA TSCA inventory. 16. OTHER INFORMATION Estimated NFPA Rating: HEALTH 1, FLAMMABILITY 1 , REACTIVITY 0. Estimated HMIS Classification: HEALTH 1, FLAMMABILITY 1, PHYSICAL HAZARD 0 NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. 3 of 3 Company: Permatex. Inc. 10 Columbus Blvd. Hartford, CT USA 06106 Item No: NTBP15-6 Revision Number: 2 Telephone No.: 1-87-Permatex (877) 376-2839 Prepared By: Denise Boyd, Manager-Environmental, Health & Safety NO TOUCH ORIGINAL TIRE CARE 18OZ AE Revision Date: November 17, 2010 Product Name: Page 805 of 1287 Page 805 of 1287 Page 805 of 1287 Page 805 of 1287 ---PAGE BREAK--- Oatey Pipe Joint Lubricant SDS US SDS # Version 01 Revision date: Issue date: 12-May-2015 Page 1 of 6 SAFETY DATA SHEET 1. Identification Product identifier Oatey Pipe Joint Lubricant Other means of identification Product code Synonyms Part Numbers: 30599, 30600, 30601, 30602 Recommended use Lubricant Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Company Name Oatey Inc. Address 4700 West 160th Street Cleveland, OH 44135 Telephone [PHONE REDACTED] E-mail [EMAIL REDACTED] Transport Emergency Chemtrec 1-[PHONE REDACTED] (Outside the US 1-[PHONE REDACTED]) Emergency First Aid 1-[PHONE REDACTED] Contact person MSDS Coordinator 2. Hazard(s) identification Physical hazards Not Classified. Health hazards Skin Irritant Eye Irritation Cat 3 Cat 2B OSHA defined hazards This chemical is considered non-hazardous according to the OSHA Hazard Communication Standard 2012 (29 CFR 1910.1200) Label elements Hazard symbol None. Signal word Warning Hazard statement Causes mild skin irritation. Causes eye irritation. Precautionary statement Prevention Wash skin thoroughly after handling. Response If skin irritation occurs: Get medical advice/attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Storage Not applicable. Disposal Not applicable. Hazard(s) not otherwise classified (HNOC) None. 3. Composition/information on ingredients Mixtures The product contains no substances which at their given concentration, are considered to be hazardous to health. Chemical name CAS number % Mixed sodium and potassium salts of tall oil (soap) 68606-06-4 15 - 25 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if occur. Skin contact Wash off immediately with soap and water. If skin irritation persists, call a physician. Page 806 of 1287 Page 806 of 1287 Page 806 of 1287 Page 806 of 1287 ---PAGE BREAK--- Oatey Pipe Joint Lubricant SDS US SDS # Version 01 Revision date: Issue date: 12-May-2015 Page 2 of 6 Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Ingestion Do NOT induce vomiting. Drink plenty of water. Rinse mouth. Never give anything by mouth to an unconscious person. Call a physician or poison control center immediately Most important acute and delayed Direct contact with eyes may cause temporary irritation. Prolonged or repeated skin contact may cause irritation. Indication of immediate medical attention and special treatment needed. Immediate medical attention is not required. General information Note to physician, treat 5. Fire-fighting measures Suitable extinguishing media Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable extinguishing media Do not use water in a jet. Specific hazards arising from the chemical No information available. Special protective equipment and precautions for firefighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Fire fighting equipment/instructions isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Use water spray to keep fire-exposed containers cool. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Specific methods None General fire hazards None 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Avoid contact with the skin and the eyes. Evacuate personnel to safe areas. Use personal protective equipment. Keep people away from and upwind of spill/leak. Methods and materials for containment and cleaning up Dike to collect large liquid spills. Prevent leakage or spillage if safe to do so. Dam up. Soak up with inert absorbent material Place the bulk of any spilled material into properly labeled containers. Rinse any remaining material to sewage treatment facility. Clean up in accordance with all applicable regulations. Environmental precautions Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Do not flush into surface water or sanitary sewer system. Prevent entry into waterways, sewers, basements or confined areas. See Section 12 for additional Ecological information 7. Handling and storage Precautions for safe handling Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Do not breathe vapors or spray mist. Ensure adequate ventilation. Use only in area provided with appropriate exhaust ventilation. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Do not take internally. Conditions for safe storage, including any incompatibilities Keep containers closed in a dry, cool and well-ventilated place. Keep in properly labeled containers. Keep out of the reach of children. 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values Components Type Value Biological limit values Data Not available. Appropriate engineering controls No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure Page 807 of 1287 Page 807 of 1287 Page 807 of 1287 Page 807 of 1287 ---PAGE BREAK--- Oatey Pipe Joint Lubricant SDS US SDS # Version 01 Revision date: Issue date: 12-May-2015 Page 3 of 6 limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. Individual protection measures, such as personal protective equipment Eye/face protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. Skin protection Hand Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Other Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Thermal hazards None. General hygiene considerations Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. 9. Physical and chemical properties Appearance Physical state Liquid Form Paste Color Off-White Odor Slight Odor threshold Not available. pH 9 Solution) Melting point/freezing point No data available. Initial boiling point and boiling range Not determined Flash point > 220 °F 104°C) Upper/lower flammability or explosive limits Flammability limit – lower Not available Flammability limit – upper Not available Explosive limit - lower Not available Explosive limit - upper Not available Vapor pressure Not applicable Vapor density Not applicable Relative density 1.2 Solubility(ies) Solubility (water) Completely soluble. Partition coefficient (n-octanol/water) Not determined. Auto-ignition temperature Not applicable Decomposition temperature Not available Viscosity, kinematic Not determined/ Other information VOC (Weight < 1% by weight, < 12 g/L 10. Stability and reactivity Reactivity Not reactive under normal conditions Chemical stability The product is stable. Possibility of hazardous reaction Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to avoid Contact with incompatible materials. Incompatible materials Strong Oxidizing Agents. Hazardous decomposition products Carbon oxides. Page 808 of 1287 Page 808 of 1287 Page 808 of 1287 Page 808 of 1287 ---PAGE BREAK--- Oatey Pipe Joint Lubricant SDS US SDS # Version 01 Revision date: Issue date: 12-May-2015 Page 4 of 6 11. Toxicological information Information on likely routes of exposure Inhalation Not a likely route Skin contact May cause mild skin irritation. Eye contact Causes Eye irritation Ingestion No known significant effects or critical hazards. related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Prolonged or repeated contact may dry skin and cause irritation Information on likely routes of exposure Acute Toxicity Components Species Results Skin corrosion/irritation Prolonged exposure may cause skin irritation. Serious eye damage/eye irritation Expected to be irritating. Respiratory or skin sensitization Respiratory sensitization Inhalation of vapors or mists may cause irritation to the respiratory system. Skin sensitization This product is not expected to cause skin irritation. Germ cell mutagenicity Not considered a mutagenic hazard Carcinogenicity No component of this product is identified as a probable, possible, or confirmed carcinogen by IARC, NTP, Monographs, or OSHA. Reproductive toxicity No known significant effects or critical hazards. Specific target organ toxicity Single exposure Repeated exposure Not expected to be a hazard. Not expected to be a hazard. Aspiration Hazard Not expected to be a hazard Chronic effects Not Classified. Further information None Provided. 12. Ecological information Ecotoxicity Product/ingredient name Results Species Exposure Persistence and degradability Not Available. Bio accumulative potential Not Available. Mobility in soil Not determined. Other adverse effects No known significant effects of critical hazards. 13. Disposal considerations Disposal instructions The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Local disposal regulations Not Applicable Hazardous waste code Not Applicable 14. Transportation information Page 809 of 1287 Page 809 of 1287 Page 809 of 1287 Page 809 of 1287 ---PAGE BREAK--- Oatey Pipe Joint Lubricant SDS US SDS # Version 01 Revision date: Issue date: 12-May-2015 Page 5 of 6 DOT Not Regulated UN number UN Proper Shipping Name Transportation Hazard classes Packing group IATA Not Regulated UN number UN Proper Shipping Name Transportation Hazard classes Packing group IMDG Not Regulated UN number UN Proper Shipping Name Transportation Hazard classes Packing group Environmental hazards Marine polluntant 15. Regulatory information U.S. Federal regulations TSCA 12(b) - Chemical export notification: None required. TSCA 5(a)2 - Final significant new use rules: Not listed TSCA 5(a)2 - Proposed significant new use rules: Not listed TSCA 5(e) - Substances consent order: Not listed US Federal Regulations Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42): None known CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): None Known US state regulations California Prop 65 This product does not contain a chemical known to the State of California to cause cancer, birth defects, or other reproductive harm. International regulations Country(s) or region Inventory Name On inventory list (yes/no)* Canada DSL/NDSL Yes United States & Puerto Rico Toxic Substances Control Act (TSCA 8b) Yes Page 810 of 1287 Page 810 of 1287 Page 810 of 1287 Page 810 of 1287 ---PAGE BREAK--- Oatey Pipe Joint Lubricant SDS US SDS # Version 01 Revision date: Issue date: 12-May-2015 Page 6 of 6 16. Other information, including date of preparation or last revision Issue Date 12-May-2015 Revision Date - Version # 01 HMIS Rating Health: 1 Flammability: 0 Physical Hazards: 0 Disclaimer Oatey Inc. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. Page 811 of 1287 Page 811 of 1287 Page 811 of 1287 Page 811 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Oatey PVC Heavy Duty Gray Cement Product identifier Other means of identification 1109E Product code Part Numbers: 31121, 31122, 31123, 31124 Synonyms Joining PVC Pipes Recommended use None known. Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Company Name Oatey Co. Address 4700 West 160th St. Cleveland, OH 44135 Telephone [PHONE REDACTED] E-mail [EMAIL REDACTED] Transport Emergency Chemtrec 1-[PHONE REDACTED] (Outside the US 1-[PHONE REDACTED]) Emergency First Aid 1-[PHONE REDACTED] Contact person MSDS Coordinator 2. Hazard(s) identification Category 2 Flammable liquids Physical hazards Category 4 Acute toxicity, oral Health hazards Category 2 Skin corrosion/irritation Category 2A Serious eye damage/eye irritation Category 3 respiratory tract irritation Specific target organ toxicity, single exposure Category 3 narcotic effects Specific target organ toxicity, single exposure Category 1 Aspiration hazard Not classified. OSHA defined hazards Label elements Signal word Danger Hazard statement Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Response If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use appropriate media to extinguish. Oatey PVC Heavy Duty Gray Cement SDS US 927275 Version 01 Revision date: - Issue date: 05-27-2015 1 / 10 Page 812 of 1287 Page 812 of 1287 Page 812 of 1287 Page 812 of 1287 ---PAGE BREAK--- Storage Store in a well-ventilated place. Keep container closed. Keep cool. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. May form explosive peroxides. Contains a chemical classified by the US EPA as a suspected possible carcinogen. Supplemental information Not applicable. 3. Composition/information on ingredients Mixtures 109-99-9 40-70 Furan, Tetrahydro- CAS number % Chemical name 67-64-1 10-25 Acetone 9002-86-2 10-25 Polyvinyl chloride 108-94-1 5-15 Cyclohexanone 112945-52-5 1-5 Silica, amorphous, fumed *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Inhalation Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Eye contact Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may cause pulmonary edema and pneumonitis. Ingestion Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Skin irritation. May cause redness and pain. Most important acute and delayed Provide general supportive measures and treat Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. may be delayed. Indication of immediate medical attention and special treatment needed Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. General information 5. Fire-fighting measures Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2). Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Unsuitable extinguishing media Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Special protective equipment and precautions for firefighters In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Specific methods Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive organic peroxide when exposed to air or light or with age. General fire hazards Oatey PVC Heavy Duty Gray Cement SDS US 927275 Version 01 Revision date: - Issue date: 05-27-2015 2 / 10 Page 813 of 1287 Page 813 of 1287 Page 813 of 1287 Page 813 of 1287 ---PAGE BREAK--- 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid discharge into drains, water courses or onto the ground. Environmental precautions 7. Handling and storage Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof general and local exhaust ventilation. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Precautions for safe handling Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in a cool, dry place out of direct sunlight. Store in original closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Value Type Components STEL 5 ppm Polyvinyl chloride (CAS 9002-86-2) TWA 1 ppm US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Type Form Components PEL 2400 mg/m3 Acetone (CAS 67-64-1) 1000 ppm PEL 200 mg/m3 Cyclohexanone (CAS 108-94-1) 50 ppm PEL 590 mg/m3 Furan, Tetrahydro- (CAS 109-99-9) 200 ppm PEL 5 mg/m3 Respirable fraction. Polyvinyl chloride (CAS 9002-86-2) 15 mg/m3 Total dust. Oatey PVC Heavy Duty Gray Cement SDS US 927275 Version 01 Revision date: - Issue date: 05-27-2015 3 / 10 Page 814 of 1287 Page 814 of 1287 Page 814 of 1287 Page 814 of 1287 ---PAGE BREAK--- US. OSHA Table Z-3 (29 CFR 1910.1000) Value Type Components TWA 0.8 mg/m3 Silica, amorphous, fumed (CAS 112945-52-5) 20 US. ACGIH Threshold Limit Values Value Type Form Components STEL 750 ppm Acetone (CAS 67-64-1) TWA 500 ppm STEL 50 ppm Cyclohexanone (CAS 108-94-1) TWA 20 ppm STEL 100 ppm Furan, Tetrahydro- (CAS 109-99-9) TWA 50 ppm TWA 1 mg/m3 Respirable fraction. Polyvinyl chloride (CAS 9002-86-2) US. NIOSH: Pocket Guide to Chemical Hazards Value Type Components TWA 590 mg/m3 Acetone (CAS 67-64-1) 250 ppm TWA 100 mg/m3 Cyclohexanone (CAS 108-94-1) 25 ppm STEL 735 mg/m3 Furan, Tetrahydro- (CAS 109-99-9) 250 ppm TWA 590 mg/m3 200 ppm TWA 6 mg/m3 Silica, amorphous, fumed (CAS 112945-52-5) Biological limit values ACGIH Biological Exposure Indices Value Sampling Time Determinant Specimen Components 50 mg/l Acetone Urine * Acetone (CAS 67-64-1) 80 mg/l 1,2-Cyclohexan ediol, with hydrolysis Urine * Cyclohexanone (CAS 108-94-1) 8 mg/l Cyclohexanol, with hydrolysis Urine * 2 mg/l Tetrahydrofura n Urine * Furan, Tetrahydro- (CAS 109-99-9) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies Cyclohexanone (CAS 108-94-1) Skin designation applies. US - Tennessee OELs: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. Furan, Tetrahydro- (CAS 109-99-9) Can be absorbed through the skin. Oatey PVC Heavy Duty Gray Cement SDS US 927275 Version 01 Revision date: - Issue date: 05-27-2015 4 / 10 Page 815 of 1287 Page 815 of 1287 Page 815 of 1287 Page 815 of 1287 ---PAGE BREAK--- US. NIOSH: Pocket Guide to Chemical Hazards Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Appropriate engineering controls Individual protection measures, such as personal protective equipment Face shield is recommended. Wear safety glasses with side shields (or goggles). Eye/face protection Skin protection Wear appropriate chemical resistant gloves. Hand protection Wear appropriate chemical resistant clothing. Other If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Respiratory protection Wear appropriate thermal protective clothing, when necessary. Thermal hazards When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Appearance Liquid. Physical state Translucent liquid. Form Gray. Color Solvent. Odor Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 151 °F (66.11 Flash point 14.0 - 23.0 °F (-10.0 - -5.0 Evaporation rate 5.5 - 8 Not available. Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower 1.8 Flammability limit - upper 11.8 Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 145 mm Hg @ 20 C Vapor density 2.5 Relative density 0.96 0.02 Solubility(ies) Solubility (water) Negligible Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity 1200 - 2500 cP Viscosity temperature 77 °F (25 Oatey PVC Heavy Duty Gray Cement SDS US 927275 Version 01 Revision date: - Issue date: 05-27-2015 5 / 10 Page 816 of 1287 Page 816 of 1287 Page 816 of 1287 Page 816 of 1287 ---PAGE BREAK--- Other information Bulk density 8 lb/gal VOC (Weight 463 g/l SQACMD 1168/M316A 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Reactivity Material is stable under normal conditions. Chemical stability No dangerous reaction known under conditions of normal use. Possibility of hazardous reactions Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Conditions to avoid Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics. Incompatible materials No hazardous decomposition products are known. Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation May be fatal if swallowed and enters airways. Headache. Nausea, vomiting. May cause irritation to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. Skin contact Causes skin irritation. Eye contact Causes serious eye irritation. Ingestion May be fatal if swallowed and enters airways. Harmful if swallowed. Harmful if swallowed. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. related to the physical, chemical and toxicological characteristics Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause redness and pain. of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Information on toxicological effects Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation. Test Results Components Species Acetone (CAS 67-64-1) LD50 Rabbit Dermal Acute 20 ml/kg LC50 Rat Inhalation 50 mg/l, 8 Hours LD50 Rat Oral 5800 mg/kg Cyclohexanone (CAS 108-94-1) LD50 Rabbit Dermal Acute 948 mg/kg LC50 Rat Inhalation 8000 ppm, 4 hours LD50 Rat Oral 1540 mg/kg * Estimates for product may be based on additional component data not shown. Causes skin irritation. Skin corrosion/irritation Causes serious eye irritation. Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not available. Oatey PVC Heavy Duty Gray Cement SDS US 927275 Version 01 Revision date: - Issue date: 05-27-2015 6 / 10 Page 817 of 1287 Page 817 of 1287 Page 817 of 1287 Page 817 of 1287 ---PAGE BREAK--- This product is not expected to cause skin sensitization. Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalation lifetime study on THF conducted by NTP (1998). Male rats developed renal tumors and female mice developed liver tumors while neither the female rats nor the male mice showed similar results. Because the carcinogenic mechanisms could not be identified clearly in either species for either tumor, the EPA determined that the male rat and female mouse findings are relevant to the assessment of carcinogenic potential in humans. Therefore, the IRIS review concludes that these data in aggregate indicate that there is "suggestive evidence of carcinogenic potential" following exposure to THF by all routes of exposure. IARC Monographs. Overall Evaluation of Carcinogenicity Cyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans. Polyvinyl chloride (CAS 9002-86-2) 3 Not classifiable as to carcinogenicity to humans. Silica, amorphous, fumed (CAS 112945-52-5) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Polyvinyl chloride (CAS 9002-86-2) Cancer This product is not expected to cause reproductive or developmental effects. Reproductive toxicity Specific target organ toxicity - single exposure Narcotic effects. May cause drowsiness and dizziness. Respiratory tract irritation. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard May be fatal if swallowed and enters airways. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Ecotoxicity Components Test Results Species Acetone (CAS 67-64-1) Aquatic LC50 Fish > 100 mg/l, 96 hours Fathead minnow (Pimephales promelas) * Estimates for product may be based on additional component data not shown. Cyclohexanone (CAS 108-94-1) Aquatic LC50 Fish 481 - 578 mg/l, 96 hours Fathead minnow (Pimephales promelas) No data is available on the degradability of this product. Persistence and degradability No data available. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Acetone (CAS 67-64-1) -0.24 Cyclohexanone (CAS 108-94-1) 0.81 Furan, Tetrahydro- (CAS 109-99-9) 0.46 No data available. Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations. Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Oatey PVC Heavy Duty Gray Cement SDS US 927275 Version 01 Revision date: - Issue date: 05-27-2015 7 / 10 Page 818 of 1287 Page 818 of 1287 Page 818 of 1287 Page 818 of 1287 ---PAGE BREAK--- Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Contaminated packaging 14. Transport information DOT UN1993 UN number Flammable liquids, n.o.s. (Acetone RQ = 50050 LBS) UN proper shipping name 3 Class Transport hazard class(es) - Subsidiary risk 3 Label(s) II Packing group Read safety instructions, SDS and emergency procedures before handling. Special precautions for user IB2, T7, TP1, TP8, TP28 Special provisions 150 Packaging exceptions 202 Packaging non bulk 242 Packaging bulk IATA UN1993 UN number Flammable liquid, n.o.s. (Acetone) UN proper shipping name 3 Class Transport hazard class(es) - Subsidiary risk II Packing group No. Environmental hazards 3H ERG Code Read safety instructions, SDS and emergency procedures before handling. Special precautions for user IMDG UN1993 UN number FLAMMABLE LIQUID, N.O.S. (Acetone) UN proper shipping name 3 Class Transport hazard class(es) - Subsidiary risk II Packing group No. Marine pollutant Environmental hazards F-E, S-E EmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Not available. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Polyvinyl chloride (CAS 9002-86-2) Cancer Central nervous system Liver Blood Flammability CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1) LISTED Cyclohexanone (CAS 108-94-1) LISTED Oatey PVC Heavy Duty Gray Cement SDS US 927275 Version 01 Revision date: - Issue date: 05-27-2015 8 / 10 Page 819 of 1287 Page 819 of 1287 Page 819 of 1287 Page 819 of 1287 ---PAGE BREAK--- Furan, Tetrahydro- (CAS 109-99-9) LISTED Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Hazard categories SARA 302 Extremely hazardous substance Not listed. No SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated. Safe Drinking Water Act (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1) 6532 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1) 35 %WV DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1) 6532 US state regulations US. Massachusetts RTK - Substance List Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Silica, amorphous, fumed (CAS 112945-52-5) US. New Jersey Worker and Community Right-to-Know Act Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Polyvinyl chloride (CAS 9002-86-2) US. Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Silica, amorphous, fumed (CAS 112945-52-5) US. Rhode Island RTK Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Domestic Substances List (DSL) Yes Canada *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Toxic Substances Control Act (TSCA) Inventory No United States & Puerto Rico Oatey PVC Heavy Duty Gray Cement SDS US 927275 Version 01 Revision date: - Issue date: 05-27-2015 9 / 10 Page 820 of 1287 Page 820 of 1287 Page 820 of 1287 Page 820 of 1287 ---PAGE BREAK--- 16. Other information, including date of preparation or last revision 05-27-2015 Issue date - Revision date Version # 01 Health: 2 Flammability: 3 Physical hazard: 0 HMIS® ratings NFPA ratings 0 2 3 The information in the sheet was written based on the best knowledge and experience currently available. Oatey Co. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. Disclaimer Oatey PVC Heavy Duty Gray Cement SDS US 927275 Version 01 Revision date: - Issue date: 05-27-2015 10 / 10 Page 821 of 1287 Page 821 of 1287 Page 821 of 1287 Page 821 of 1287 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 1/12 1. PRODUCT AND COMPANY IDENTIFICATION Product information Product name : OFF!® DEEP WOODS® INSECT REPELLENT VII Recommended use : Insect Repellent Manufacturer, importer, supplier : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236 Telephone : +18005585252 Emergency telephone number : 24 Hour Medical Emergency Phone: (866)231-5406 24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300 2. HAZARDS IDENTIFICATION Classification of the substance or mixture Globally Harmonized System (GHS) Classification Hazard classification Hazard category Hazards identification Flammable liquids Category 3 Flammable liquid and vapour. Eye irritation Category 2A Causes serious eye irritation. Labelling Hazard symbols Flame Exclamation mark Signal word Warning Hazard statements Flammable liquid and vapour. Causes serious eye irritation. Precautionary statements If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. Page 822 of 1287 Page 822 of 1287 Page 822 of 1287 Page 822 of 1287 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 2/12 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. Store in a well-ventilated place. Keep cool. Dispose of contents/ container to an approved incineration plant. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container closed. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves. Wash hands thoroughly after handling. Use explosion-proof electrical/ ventilating/ lighting/ equipment. Other hazards : None identified 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No. Weight percent Ethyl alcohol 64-17-5 30.00 - 60.00 N,N-Diethyl-m-toluamide 134-62-3 10.00 - 30.00 The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. Skin contact : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If you suspect a reaction to this product, discontinue use and remove contaminated clothing. Inhalation : No special requirements. Ingestion : No special requirements Page 823 of 1287 Page 823 of 1287 Page 823 of 1287 Page 823 of 1287 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 3/12 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during firefighting : Flammable liquid. Vapors are heavier than air and may travel to a source of ignition and flash back. Liquid run-off to sewers may create fire/explosion hazard. Container may melt and leak in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses. Further information : Fight fire from maximum distance or protected area. Cool and use caution when approaching or handling fire-exposed containers. For large quantities of flammable liquids, consider containment to prevent the spread of fire. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Remove all sources of ignition. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Wear personal protective equipment. Wash thoroughly after handling. Environmental precautions : Do not flush into surface water or sanitary sewer system. Use appropriate containment to avoid environmental contamination. Outside of normal use, avoid release to the environment. Methods and materials for containment and cleaning up : Soak up with inert absorbent material. Use only non-sparking equipment. Dike large spills. Clean residue from spill site. Page 824 of 1287 Page 824 of 1287 Page 824 of 1287 Page 824 of 1287 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 4/12 7. HANDLING AND STORAGE Handling Precautions for safe handling : Avoid contact with eyes and lips. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Wash thoroughly after handling. Advice on protection against fire and explosion : Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge. Use only non-sparking tools. Use explosion-proof equipment. Ground/bond container and receiving equipment. Storage Requirements for storage areas and containers : Keep container closed when not in use. Keep away from food, drink and animal feedingstuffs. Keep closed. Store in a well-ventilated place. Keep cool. Other data : Stable under normal conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Non- standard units Basis Ethyl alcohol 64-17-5 1,900 mg/m3 1,000 ppm - OSHA TWA Ethyl alcohol 64-17-5 - 1,000 ppm - ACGIH STEL Personal protective equipment Respiratory protection : Do not spray in enclosed areas. Hand protection : No special requirements. Page 825 of 1287 Page 825 of 1287 Page 825 of 1287 Page 825 of 1287 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 5/12 Eye protection : Safety glasses with side-shields Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : liquid Color : clear Odor : pleasant Odour Threshold : No data available pH : 6.98 at (20 Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Flash point : 84 °F Method: Tag Closed Cup (TCC) Evaporation rate : No data available Flammability (solid, gas) : Sustains combustion Upper/lower flammability or explosive limits : No data available Page 826 of 1287 Page 826 of 1287 Page 826 of 1287 Page 826 of 1287 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 6/12 Vapour pressure : No data available Vapour density : No data available Relative density : 0.93 g/cm3 at 20 °C Solubility(ies) : partly miscible Partition coefficient: n- octanol/water : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity, dynamic : No data available Viscosity, kinematic : Not applicable Oxidizing properties : No data available Volatile Organic Compounds Total VOC (wt. : 34.7 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations Other information : None identified : 10. STABILITY AND REACTIVITY Possibility of hazardous reactions : If accidental mixing occurs and toxic gas is formed, exit area immediately. Do not return until well ventilated. Conditions to avoid : Heat, flames and sparks. Page 827 of 1287 Page 827 of 1287 Page 827 of 1287 Page 827 of 1287 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 7/12 Incompatible materials : Strong oxidizing agents Do not mix with bleach or any other household cleaners. Strong bases Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. 11. TOXICOLOGICAL INFORMATION Emergency Overview : Warning Acute oral toxicity : LD50 4,103 mg/kg GHS Properties Classification Routes of entry Acute toxicity No classification proposed - Skin corrosion/irritation No classification proposed - Eye irritation Category 2A - Skin sensitisation No classification proposed - Respiratory sensitisation No classification proposed - Germ cell mutagenicity No classification proposed - Carcinogenicity No classification proposed - Reproductive toxicity No classification proposed - Specific target organ toxicity - single exposure No classification proposed - Specific target organ toxicity - repeated exposure No classification proposed - Aspiration hazard No classification proposed - Page 828 of 1287 Page 828 of 1287 Page 828 of 1287 Page 828 of 1287 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 8/12 Acute inhalation toxicity : GHS LC50 (dust and mist) > 2.07 mg/l Acute dermal toxicity : LD50 > 5,000 mg/kg Aggravated Medical Condition : Do not apply to cuts or irritated skin. 12. ECOLOGICAL INFORMATION Product : The product itself has not been tested. Toxicity The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions. Toxicity to fish Ethyl alcohol flow- through test LC50 Pimephales promelas (fathead minnow) 14,200 mg/l 96 h N,N-Diethyl-m-toluamide static test LC50 mykiss (rainbow trout) 71.25 mg/l 96 h Toxicity to aquatic invertebrates Ethyl alcohol static test EC50 Daphnia magna (Water flea) 2 mg/l 48 h Components End point Species Value Exposure time Components End point Species Value Exposure time Page 829 of 1287 Page 829 of 1287 Page 829 of 1287 Page 829 of 1287 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 9/12 NOEC Daphnia magna 9.6 mg/l 9 d N,N-Diethyl-m-toluamide No data available Toxicity to aquatic plants Ethyl alcohol Static EC50 Chlorella vulgaris (Fresh water algae) 275 mg/l 72 h N,N-Diethyl-m-toluamide No data available Persistence and degradability Component Biodegradation Exposure time Summary Ethyl alcohol 97 % 28 d Readily biodegradable N,N-Diethyl-m-toluamide No data available Bioaccumulative potential Component Bioconcentration factor (BCF) Partition Coefficient n- Octanol/water (log) Ethyl alcohol 3.2 estimated -0.35 Measured N,N-Diethyl-m-toluamide No data available No data available Mobility Component End point Value Ethyl alcohol No data available N,N-Diethyl-m-toluamide No data available PBT and vPvB assessment Component Results Components End point Species Value Exposure time Page 830 of 1287 Page 830 of 1287 Page 830 of 1287 Page 830 of 1287 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 10/12 Ethyl alcohol Not fulfilling PBT and vPvB criteria N,N-Diethyl-m-toluamide Not fulfilling PBT and vPvB criteria Other adverse effects : None known. 13. DISPOSAL CONSIDERATIONS PESTICIDAL WASTE: For disposal information, please read and follow Disposal instructions on the pesticide label. Consumer may discard empty container in trash, or recycle where facilities exist. 14. TRANSPORT INFORMATION Please refer to the Bill of Lading/receiving documents for up-to-date shipping information. Land transport Sea transport Air transport UN number 1993 1993 1993 UN proper shipping name UN 1993 Flammable liquid, N.O.S. (Ethyl alcohol) UN 1993 Flammable liquid, N.O.S. (Ethyl alcohol) UN 1993 Flammable liquid, N.O.S. (Ethyl alcohol) Transport hazard class(es) 3 3 3 Packing group III III III Environmental hazards - - - Special precautions for user Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. 15. REGULATORY INFORMATION Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Page 831 of 1287 Page 831 of 1287 Page 831 of 1287 Page 831 of 1287 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 11/12 Chemical Substance Inventory. California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65. Registration # / Agency 4822-399/US/EPA 16. OTHER INFORMATION HMIS Ratings Health 2 Flammability 3 Reactivity 0 NFPA Ratings Health 2 Fire 3 Reactivity 0 Special - This information is being provided in accordance with the Occupational Safety and Health Administration (OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use. Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Page 832 of 1287 Page 832 of 1287 Page 832 of 1287 Page 832 of 1287 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 12/12 Prepared by SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 833 of 1287 Page 833 of 1287 Page 833 of 1287 Page 833 of 1287 ---PAGE BREAK--- Safety Data Sheet Office Max Compressed Gas Duster Section 1. Identification Product Identifier Office Max Compressed Gas Duster Synonyms OM96090, OM96091, OM96092, OM04736, OM04737 Manufacturer Stock Numbers N/A Product Cas 75-37-6 Recommended use Dust Removal Uses advised against Use Only as Directed - Read label instructions carefully. Keep out of reach of children. Intentional misuse by deliberately concentrating and/or inhaling contents may be fatal. Manufacturer Contact Address Falcon Safety Products, Inc. 25 ImClone Drive Branchburg, NJ, 08876 USA Phone Emergency Phone Fax (908) 707-4900 (800) 498-7192 N/A Section 2. Hazards Identification Classification FLAMMABLE GASES - Category 2 GASES UNDER PRESSURE - Compressed gas Signal Word Warning Pictogram Hazard Statements Contains gas under pressure; may explode if heated Flammable gas Precautionary Statements Response Eliminate all ignition sources if safe to do so. Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Prevention Do not spray on an open flame or other ignition source. Keep away from heat. Pressurized container: Do not pierce or burn, even after use. Storage Protect from sunlight. Store in a well-ventilated place. Store at temperatures not exceeding 120 degrees F/49 degrees C Disposal N/A Page 1 of 8 Page 834 of 1287 Page 834 of 1287 Page 834 of 1287 Page 834 of 1287 ---PAGE BREAK--- Occupational exposure limits, if available, are listed in Section 8. General Keep out of reach of children Ingredients of unknown toxicity 0% Hazards not Otherwise Classified N/A No Data Available Section 3. Ingredients CAS Ingredient Name Weight % 75-37-6 Ethane, 1,1-difluoro- 100 % Section 4. First-Aid Measures General Advice Never give anything by mouth to an unconscious person. When persist or in all cases of doubt, seek medical advice. Inhalation Remove from exposure, lie down. Move to fresh air. Keep patient warm and at rest. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Skin Take off all contaminated clothing immediately. Flush area with lukewarm water. Do not use hot water. If frostbite has occurred, call a physician. Eye Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical attention. Ingestion Is not considered a potential route of exposure. Most important acute and delayed Anaesthetic effects: light-headedness, irregular heartbeat with a strange sensation in the chest, heart thumping, apprehension, feeling of fainting, dizziness or weakness. Protection of First-aiders If potential for exposure exists refer to Section 8 for specific personal protective equipment. Notes to Physician Because of possible disturbances of cardiac catecholamine drugs, such as epinephrine, which may be used in situations of emergency life support, should be used with special caution. Page 2 of 8 Page 835 of 1287 Page 835 of 1287 Page 835 of 1287 Page 835 of 1287 ---PAGE BREAK--- Section 5. Fire Fighting Measures Suitable Extinguishing Media Water spray, water fog, dry chemical, alcohol resistant foam, carbon dioxide (CO2) Unsuitable Extinguishing Media No applicable data available. Specific Hazards Flammable. This substance's fire decomposition by-products will include hydrofluoric acid and possibly carbonyl flouride. Avoid contact with these materials, which are toxic and irritating. Evacuate personnel immediately in the event of a fire involving this substance. Vapors may form explosive mixtures with air. Vapors are heavier than air and may spread along floors. Vapors or gases may travel considerable distances to ignition source and flash back. Special protective equipment for firefighters Use personal protective equipment. Wear neoprene gloves during cleaning up work after a fire. Exposure to decompositon products may be a hazard to health. Further Information Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Cool containers/tanks with water spray. Section 6. Accidental Release Measures NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. Safeguards (Personnel) Evacuate personnel to safe areas. Ventilate the area. Refer to protective measures listed in sections 7 and 8. Spill Clean-up If this product is spilled and not recovered, or is recovered as a waste for treatment and disposal, the CERCLA Reportable Quantity is 100 lbs. (release of an Unlisted Hazardous Waste with the Characteristic of Ignitability). Evaporates. Ventilate area using forced ventilation, especially low or enclosed places where heavy vapors might collect. Accidental Release Measures Wear self-contained breathing apparatus (SCBA). Section 7. Handling and Storage Handling (Personnel) Avoid breathing vapors or mist. Avoid contact with skin, eyes and clothing. Provide sufficient air exchange and/or exhaust in work rooms. For personal protection see section 8. Handle in accordance with good industrial hygiene and safety practice. Handling (Physical Aspects) Vapors are heavier than air and may spread along floors. Vapors may form flammable mixture with air. The product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropirate standard. No sparking tools should be used. Take measures to prevent the build up of electrostatic charge. Keep away from open flames, hot surfaces and sources of ignition. When using DO NOT SMOKE. Do not use in areas where vapors may accumulate such as paper shredders. Dust Explosion class Not applicable Storage Keep container closed and in a dry, well-ventilated location. Store in original container. The product has an indefinite shelf life when stored properly. Storage Period Recommended shelf life - 10 years provided product is stored in a dry location as directed. Storage Temperature Do not expose to temperatures above 120 degrees F (49 degrees C) as overheating could cause can to burst. DO NOT leave in direct sunlight or enclosed vehicle. Page 3 of 8 Page 836 of 1287 Page 836 of 1287 Page 836 of 1287 Page 836 of 1287 ---PAGE BREAK--- Section 8. Exposure Controls/Personal Protection Occupational Exposure Limits Ingredient Name ACGIH TLV OSHA PEL STEL Ethane, 1,1-difluoro- N/A N/A N/A Personal Protective Equipment N/A Engineering controls Ensure adequate ventilation, especially in confined areas. Use respiratory protection if needed. Eye/Face Protection Wear safety glasses with side shields. Direct contact with liquid may cause frostbite. Respiratory Protection For rescue use self-contained breathing apparatus. Vapors are heavier than air and can cause suffication by reducing oxygen available for breathing. Skin and body protection As required by employer code. If there is risk of skin contact, wear protective clothing, gloves, etc. Direct contact with liquid can cause frostbite. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practices. Page 4 of 8 Page 837 of 1287 Page 837 of 1287 Page 837 of 1287 Page 837 of 1287 ---PAGE BREAK--- Section 9. Physical and Chemical Properties Physical State Gas Color Clear Odor slight, ether- like Odor Threshold No applicable data available Solubility Water - Partition coefficient Water/n-octanol N/A VOC% N/A Viscosity No applicable data available Specific Gravity 0.91 Density lbs/Gal 0.9 Pounds per Cubic Foot N/A Flash Point <-58°F C) FP Method N/A Ph Neutral Melting Point No applicable data available Boiling Point -13 °F (-25 ° C) Boiling Range N/A LEL 3.9 UEL 16.9 Evaporation Rate No applicable data available Flammability Flammable Decomposition Temperature N/A Auto-ignition Temperature No applicable data available Vapor Pressure 5,960 KPa at 77F (25C) Vapor Density 2.4 at 77F (25C) (Air=1) Section 10. Stability and Reactivity Reactivity Stable under recommended storage conditions. Chemical Stability The product is chemically stable under recommended storage conditions. Conditions to Avoid Aerosol containers are unstable at temperatures above 120 degrees F/49 degrees C Incompatible Materials Incompatible products include Alkali metals, Alkaline earth metals, powdered metals, powdered metal salts. Hazardous Decomposition Products Decomposition products are hazardous. This material can be decomposed by high temperatures (open flames, glowing metal surfaces, etc.) forming hydrofluoric acid and possibly carbonyl fluoride. Page 5 of 8 Page 838 of 1287 Page 838 of 1287 Page 838 of 1287 Page 838 of 1287 ---PAGE BREAK--- Section 11. Toxicological Information Component Analysis - LC50 1,1-Difluoroethane - > 64000 ppm rat Component analysis - Oral LD50 1,1-Difluoroethane - 1500 mg/kg rat Effects of Acute Exposure - Eye Contact with liquid may cause frostbite Effects of Acute Exposure - Skin Contact with liquid may cause frostbite Effects of Acute Exposure - Inhalation Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effect (headaches, dizziness). Vapors may cause dizziness or suffocation. Effects of Acute Exposure - Ingestion Not a normal route of exposure Sensitization Non-hazardous by WHMIS/OSHA criteria. Carcinogenicity Not classifiable as a human carcinogen. Animal testing did not show carcinogenic effects. None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC, NTP, or OSHA as a carcinogen. Mutagenicity Animal testing did not show any mutagenic effects. Did not cause genetic damage in cultured bacterial cells. Tests on mammalian cell cultures showed mutagenic effects. Reproductive Toxicity No toxcicity to reproduction. Animal testing showed no reproductive toxicity. Teratogenicity Animal testing showed no developmental toxicity. Further Information Cardiac sensitization threshold limit: 405000 mg/m3 Section 12. Ecological Information Aquatic Toxicity 1,1-Difluoroethane 96 h LC50 : Fish 295.78 mg/l 96 h EC50 : Algae 47.76 mg/l 48 h EC50 : Daphnia (water flea) 146.7 mg/l Section 13. Disposal Waste Disposal Methods Comply with applicable Federal, State/Provincial and Local Regulations. May be a RCRA Hazardous waste due to the ignitability characteristic. Do not puncture or incinerate container. Contaminated Packaging Not Available Page 6 of 8 Page 839 of 1287 Page 839 of 1287 Page 839 of 1287 Page 839 of 1287 ---PAGE BREAK--- Section 14. Transport Information UN Number 1030 UN Proper Shipping Name 1,1-Difluoroethane DOT Classification 2.1 Packing Group N/A Packaging Exceptions Note: Falcon Safety Products has been granted a DOT special permit. A copy of DOT Special Permit SP-11516 can be obtained by calling Falcon Safety Products, Inc. at [PHONE REDACTED]. Transportation of Dangerous Goods (TDG - Canada) Proper Shipping name: 1,1-Difluoroethane Hazard Class: 2.1 UN number: 1030 Packaging Exceptions: Limited quantity (containers up to 125mL) IATA/ICAO (Air) Proper Shipping Name: 1,1-Difuoroethane. Hazard Class: 2.1. UN Number: 1030. Maximum Net Quantity Packaging: Cargo Aircraft only - 150 kg maximum (forbidden on passenger aircraft). Maximum Net Quantity packaging cargo only: 150 kg. IMDG (Marine Transport) Proper Shipping Name: 1,1-DIFLUOROETHANE. Hazard Class: 2.1. UN Number: 1030. Additional Information TDG Canada: Falcon Safety Products has been granted Equivalency Certificate SU 9211 (ren. 1) by the TCSS, TDGD to offer for transport by road, rail and marine. Section 15. Regulatory Information Canadian Federal Regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations. WHMIS Status Controlled WHMIS Classification Class A - Compressed Gas, Class B - Division 1 - Flammable Gas TSCA On the inventory, or in compliance with the inventory. SARA 313 Regulated Chemical(s) This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. US Federal Regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. NJ Right to Know Regulated Chemical(s) Substances on the New Jersey Workplace Hazardous Substance List present at a concentration of 1% or more (0.1% for substances identified as carcinogens, mutagens or teratogens): 1,1-Difluoroethane. California Prop. 65 This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. Canada Domestic Substances List (DSL) This product is listed on the DSL inventory list and complies with the inventory requirements administered by the governing country. Page 7 of 8 Page 840 of 1287 Page 840 of 1287 Page 840 of 1287 Page 840 of 1287 ---PAGE BREAK--- Section 16. Other Information Revision Date 4/28/2015 Disclaimer Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. Prepared By Falcon Safety Products, Inc. [PHONE REDACTED] Page 8 of 8 Page 841 of 1287 Page 841 of 1287 Page 841 of 1287 Page 841 of 1287 ---PAGE BREAK--- Page 1/4 Safety Data Sheet acc. to OSHA HCS Printing date 01/31/2014 Revised On 01/31/2014 38.0 1 Identification of the substance and manufacturer Trade name: OMAHA ORANGE Product code: IM00085077 Manufacturer/Supplier: Seymour of Sycamore 917 Crosby Avenue Sycamore, IL 60178 Phone: [PHONE REDACTED] www.seymourpaint.com Emergency telephone number: CHEMTEL 1-[PHONE REDACTED], [PHONE REDACTED] *if located outside the U.S.* 2 Composition/information on ingredients Chemical Description: This product is a mixture of the substances listed below with nonhazardous additions. Dangerous components: 67-64-1 Acetone 20.87% 74-98-6 propane 15.78% 106-97-8 n-butane 9.26% 7727-43-7 barium sulphate, natural 8.8% 2807-30-9 Glycol Ether EP 5.63% 108-10-1 methyl isobutyl ketone 5.33% 107-87-9 Methyl Propyl Ketone 3.17% 108-65-6 PM acetate 2.64% 1330-20-7 xylene (mix) 2.53% 110-19-0 isobutyl acetate 1.51% 3 Hazard(s) identification Hazard Information for people and the environment: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 i.e. electric lights. Do not pierce or burn, even after use. Extremely flammable liquid and vapor in a pressurized container. Keep away from heat, sparks, and flame. Has narcotizing effect. Risk phrases: Extremely flammable. Irritating to eyes. Vapours may cause drowsiness and dizziness Safety phrases: Keep out of the reach of children. Keep away from sources of ignition - No smoking. Do not breathe gas/fumes/vapour/spray. Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point If swallowed, seek medical advice immediately and show this container or label. Use only in well-ventilated areas. Effects of chronic overexposure: May cause permanent brain and nervous system damage. Repeated overexposure can also damage kidneys, lungs, liver, heart, and blood. Intentional misuse by deliberately inhaling the contents may be harmful or fatal. NFPA ratings (0 - Health = 1 Fire = 4 Reactivity = 3 HMIS-ratings (0 - Health= 1 Fire= 4 Physical Hazard= 3 4 First-aid measures After eye contact: Move to fresh air. Rinse opened eye for several minutes under running water. If persist, consult a doctor. After swallowing: Do not induce vomiting; immediately call for medical help. Rinse out mouth and then drink plenty of water. 5 Fire-fighting measures Extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray. Special hazards: Can form explosive gas-air mixtures. Protective equipment for firefighters: A respiratory protective device may be necessary. Additional information Cool endangered receptacles with water spray. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures: Use respiratory protective device against the effects of fumes/dust/aerosol. Environmental precautions: Do not allow product to reach sewage systems or ground water. (Contd. on page 2) USA Page 842 of 1287 Page 842 of 1287 Page 842 of 1287 Page 842 of 1287 ---PAGE BREAK--- Page 2/4 Safety Data Sheet acc. to OSHA HCS Printing date 01/31/2014 Revised On 01/31/2014 Trade name: OMAHA ORANGE (Contd. of page 1) 38.0 Methods and material for containment and cleaning up: Absorb liquid components with liquid-binding material. 7 Handling and storage Precautions for safe handling No special precautions are necessary if used correctly. Fire/explosion protection: Do not spray on a naked flame or any incandescent material. Do not smoke. Protect from electrostatic discharges. Storage requirements: Observe pressurized container storage regulations. Consult with your local authorities. 8 Exposure controls/personal protection Components with limit values that require monitoring at the workplace: 67-64-1 Acetone PEL Long-term value: 2400 mg/m³, 1000 ppm REL Long-term value: 590 mg/m³, 250 ppm TLV Short-term value: (1782) NIC-1187 mg/m³, (750) NIC-500 ppm Long-term value: (1188) NIC-475 mg/m³, (500) NIC-200 ppm BEI 74-98-6 propane PEL Long-term value: 1800 mg/m³, 1000 ppm REL Long-term value: 1800 mg/m³, 1000 ppm TLV refer to Appendix F: minimal oxygen content 106-97-8 n-butane REL Long-term value: 1900 mg/m³, 800 ppm TLV Short-term value: 2370 mg/m³, 1000 ppm 7727-43-7 barium sulphate, natural PEL Long-term value: 15* mg/m³ *total dust **respirable fraction REL Long-term value: 10* mg/m³ *total dust **respirable fraction TLV Long-term value: (10) NIC-5* mg/m³ *inhalable fraction 108-10-1 methyl isobutyl ketone PEL Long-term value: 410 mg/m³, 100 ppm REL Short-term value: 300 mg/m³, 75 ppm Long-term value: 205 mg/m³, 50 ppm TLV Short-term value: 307 mg/m³, 75 ppm Long-term value: 82 mg/m³, 20 ppm BEI 107-87-9 Methyl Propyl Ketone PEL Long-term value: 700 mg/m³, 200 ppm REL Long-term value: 530 mg/m³, 150 ppm TLV Short-term value: 529 mg/m³, 150 ppm 108-65-6 PM acetate WEEL Long-term value: 50 ppm 1330-20-7 xylene (mix) PEL Long-term value: 435 mg/m³, 100 ppm REL Short-term value: 655 mg/m³, 150 ppm Long-term value: 435 mg/m³, 100 ppm TLV Short-term value: 651 mg/m³, 150 ppm Long-term value: 434 mg/m³, 100 ppm BEI 110-19-0 isobutyl acetate PEL Long-term value: 700 mg/m³, 150 ppm REL Long-term value: 700 mg/m³, 150 ppm TLV Long-term value: 713 mg/m³, 150 ppm Ingredients with biological limit values: 67-64-1 Acetone BEI 50 mg/L Medium: urine Time: end of shift Parameter: Acetone (nonspecific) 108-10-1 methyl isobutyl ketone (Contd. on page 3) USA Page 843 of 1287 Page 843 of 1287 Page 843 of 1287 Page 843 of 1287 ---PAGE BREAK--- Page 3/4 Safety Data Sheet acc. to OSHA HCS Printing date 01/31/2014 Revised On 01/31/2014 Trade name: OMAHA ORANGE (Contd. of page 2) 38.0 BEI 1 mg/L Medium: urine Time: end of shift Parameter: MIBK 1330-20-7 xylene (mix) BEI 1.5 g/g creatinine Medium: urine Time: end of shift Parameter: acids Hygienic protection: Immediately remove all soiled and contaminated clothing. Wash hands after use. Do not eat or drink while working. Breathing equipment: A respirator is generally not necessary when using this product outdoors or in large open areas. In cases where short and/or long term overexposure exists, a charcoal filter respirator should be worn. If you suspect overexposure conditions exist, please consult an authority on chemical hygeine. Hand protection: Protective gloves. The glove material must be impermeable and resistant to the substance. Eye protection: sealed goggles 9 Physical and chemical properties pH-value: Not determined. Boiling point: -44 °C (-47 Flash point: -19 °C Auto igniting: Product is not self-igniting. Danger of explosion: Stable at normal temperatures. Can may burst when exposed to temperatures exceeding 120 degrees fahrenheit. In use, may form flammable/explosive vapour-air mixture. Lower Explosion Limit: 1.7 Vol % Upper Explosion Limit: 10.9 Vol % Vapor Pressure: 40 PSI, 2750 hPa Specific Gravity: Between 0.77 and 0.85 (Water equals 1.00) VOC content: 496.1 g/l / 4.14 lb/gl VOC content (less exempt solvents): 46.8 % MIR Value: 1.12 Solids content: 31.9 % Other information No further relevant information available. 10 Stability and reactivity Conditions to avoid: Do not allow the can to exceed 120 degrees Fahrenheit. Stable at normal temperatures. Hazardous decomposition: No dangerous decomposition products known. 11 Toxicological information Skin effects: No irritant effect. Eye effects: Irritating effect. Sensitization: No sensitizing effects known. Additional toxicological information: Carcinogenic categories IARC (International Agency for Research on Cancer) 108-10-1 methyl isobutyl ketone 2B 1330-20-7 xylene (mix) 3 NTP (National Toxicology Program) None of the ingredients is listed. 12 Ecological information Aquatic toxicity: Hazardous for water, do not empty into drains. Other information: This product does not contain any chlorofluorocarbons (CFC's), hydrochlorofluorocarbons (HCFC's), perfluorocarbons (PFC's), or chlorinated solvents. 13 Disposal considerations Dispose of in accordance with local, state, and federal regulations. Do not puncture, incinerate, or compact. Partially empty cans must be disposed of responsibly. Do not heat or cut empty containers with electric or gas torches. Recommendation: Completely empty cans should be recycled. USA (Contd. on page 4) Page 844 of 1287 Page 844 of 1287 Page 844 of 1287 Page 844 of 1287 ---PAGE BREAK--- Page 4/4 Safety Data Sheet acc. to OSHA HCS Printing date 01/31/2014 Revised On 01/31/2014 Trade name: OMAHA ORANGE (Contd. of page 3) 38.0 14 Transport information UN-Number UN1950 DOT Consumer Commodity ORM-D Aerosols, flammable Class 2.1 Marine pollutant: No EMS Number: F-D,S-U Packaging Group: 15 Regulatory information SARA Section 355 (extremely hazardous substances): None of the ingredients in this product are listed. SARA Section 313 (Specific toxic chemical listings): 108-10-1 methyl isobutyl ketone 1330-20-7 xylene (mix) TSCA: All ingredients are listed. CPSC: This product complies with 16 CFR 1303 and does not contain more than 90 ppm of lead. California Proposition 65 chemicals known to cause cancer: 108-10-1 methyl isobutyl ketone 100-41-4 ethyl benzene EPA: 67-64-1 Acetone I 7727-43-7 barium sulphate, natural D, CBD(inh), NL(oral) 108-10-1 methyl isobutyl ketone I 1330-20-7 xylene (mix) I 110-19-0 isobutyl acetate D ACGIH: 67-64-1 Acetone A4 1330-20-7 xylene (mix) A4 110-19-0 isobutyl acetate A4 NIOSH: The following substances are regulated in the United States with reference to occupational exposure limits: 16 Other information This product was manufactured in the U.S.A. The information on this sheet is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Contact: Regulatory Affairs Abbreviations and acronyms: IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) VOC: Volatile Organic Compounds (USA, EU) EPA: Environmental Protection Agency IARC: International Agency for the Research of Cancer NIOSH: National Institute for Occupational Safety and Health TSCA: Toxic Substances Control Act CPSC: Consumer Product Safety Commission USA Page 845 of 1287 Page 845 of 1287 Page 845 of 1287 Page 845 of 1287 ---PAGE BREAK--- Revision Date: 24-Apr-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: ORANGE TOUGH 15 Product Number: 2215 , 2216 Recommended Use: Cleaning agent Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification Skin Corrosion/Irritation: Category 2 Serious Eye Damage/Eye Irritation: Category 2A Skin Sensitization: Category 1 GHS Label Elements Signal Word: Warning Hazard Statements: Causes skin irritation. Causes serious eye irritation May cause an allergic skin reaction Precautionary Statements: Prevention: Wash hands and any exposed skin thoroughly after handling. Wear eye / face protection Wear protective gloves Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace Response: -Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin IF ON SKIN (or hair): Wash with plenty of soap and water. Take off contaminated clothing and wash before reuse. If skin irritation or rash occurs: Get medical attention. -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Not Applicable Disposal: Page 1 / 5 Dispose of contents and container in accordance with local, state and federal regulations. Symbols: Page 846 of 1287 Page 846 of 1287 Page 846 of 1287 Page 846 of 1287 ---PAGE BREAK--- 2215 - ORANGE TOUGH 15 Revision Date: 24-Apr-2015 Hazards Not Otherwise Classified: Not Applicable Other Information: • Harmful if swallowed • Inhalation of vapors or mist may cause respiratory irritation. • Keep out of reach of children. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 40-70 triethanolamine dodecylbenzene sulfonate 27323-41-7 5-10 dipropylene glycol monobutyl ether 29911-28-2 5-10 triethanolamine 102-71-6 1-5 soybean oil methyl esters 67784-80-9 1-5 d-limonene 5989-27-5 1-5 alcohol ethoxylate 34398-01-1 1-5 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with plenty of soap and water. Take off contaminated clothing and wash before reuse. If skin irritation or rash occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Product does not support combustion, Use extinguishing agent suitable for type of surrounding fire Specific Hazards Arising from the Chemical: Dried product is capable of burning. Combustion products are toxic. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Cool fire-exposed containers with water spray. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 7. HANDLING AND STORAGE Page 2 / 5 Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Page 847 of 1287 Page 847 of 1287 Page 847 of 1287 Page 847 of 1287 ---PAGE BREAK--- 2215 - ORANGE TOUGH 15 Revision Date: 24-Apr-2015 Storage Conditions: Keep containers closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep from freezing. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: None established. Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Personal Protective Equipment Eye/Face Protection: Wear splash goggles. Skin and Body Protection: Wear rubber or other chemical-resistant gloves. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatible Materials: Strong oxidizing agents. Strong acids. Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Pain, redness, swelling of the conjunctiva and blurred vision. -Skin Contact: Pain, redness and cracking of the skin. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Liquid Color: Orange Odor: Orange pH: 8.5-9.0 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 100 °C / 212 °F Flash Point: 99 °C / 210 °F ASTM D56 Evaporation Rate: < 1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 1.00 Solubility(ies): Miscible in water Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 3 / 5 Decomposition Temperature: No information available. Viscosity: No information available. Page 848 of 1287 Page 848 of 1287 Page 848 of 1287 Page 848 of 1287 ---PAGE BREAK--- 2215 - ORANGE TOUGH 15 Revision Date: 24-Apr-2015 -Inhalation: Nasal discomfort and coughing. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 5905 mg/kg ATEmix (dermal): 25721 mg/kg Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available triethanolamine dodecylbenzene sulfonate 27323-41-7 = 2320 mg/kg ( Rat ) > 23220 mg/kg ( Rabbit ) Not Available dipropylene glycol monobutyl ether 29911-28-2 = 1620 µL/kg ( Rat ) = 5860 µL/kg ( Rabbit ) > 2.04 mg/L ( Rat ) 4 h = 42.1 ppm ( Rat ) 4 h d-limonene 5989-27-5 = 4400 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) Not Available Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Microorganisms Crustacea dipropylene glycol monobutyl ether 29911-28-2 Not Available 841: 96 h Poecilia reticulata mg/L LC50 static Not Available Not Available d-limonene 5989-27-5 Not Available 0.619 - 0.796: 96 h Pimephales promelas mg/L LC50 flow-through 35: 96 h mykiss mg/L LC50 Not Available Not Available Persistence and Degradability: No information available. Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT: Not Regulated Proper Shipping Name: Non Hazardous Product Special Provisions: Shipping descriptions may vary based on mode of transport, quantities, package size, and/or origin and destination. Check with a trained hazardous materials transportation expert for information specific to your situation. 15. REGULATORY INFORMATION Page 4 / 5 TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. Page 849 of 1287 Page 849 of 1287 Page 849 of 1287 Page 849 of 1287 ---PAGE BREAK--- 2215 - ORANGE TOUGH 15 Revision Date: 24-Apr-2015 SARA 313 This product does not contain listed substances above the "de minimus" level SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: No Reactive Hazard: No California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 diethanolamine - 111-42-2 Carcinogen WARNING: This product contains a chemical known to the State of California to cause cancer. 16. OTHER INFORMATION Revision Date: 24-Apr-2015 Reasons for Revision: No information available. Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 2 Flammability: 1 Instability: 0 Special: N/A HMIS Page 5 / 5 Health Hazards: 2 Flammability: 1 Physical Hazards: 0 Page 850 of 1287 Page 850 of 1287 Page 850 of 1287 Page 850 of 1287 ---PAGE BREAK--- TRI-CHEM CORPORATION MATERIAL SAFETY DATA SHEET MFG.CODE # AEROSPY SECTION I MANUFACTURER’S NAME TRI-CHEM CORPORATION EMERGENCY TELEPHONE NO. CHEMTREC [PHONE REDACTED] ADDRESS (Street, City, State and Zip Code) P. O. BOX 71550, MADISON HGTS., MI 48071-0550 CHEMICAL NAME AND SYNONYMS N/A TRADE NAME AND SYNONYMS OSHA COLORS- SPRAY PAINT (AEROSOL) CHEMICAL FAMILY N/A FORMULA N/A SECTION II – HAZARDOUS INGREDIENTS HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES % TLV (UNITS) Toluene (CAS# 108-88-3) >1 100 ppm Xylene (CAS# 1330-20-7) >1 100 ppm Acetone (CAS# 67-64-1) >1 750 ppm VM & P Naphtha (CAS# 64742-89-8) >1 300 ppm Light Aromatic Naphtha (CAS# 64742-95-6) >1 50 ppm Propane/n-Butane Propellant Blend (CAS# 74-98-6/106-97-8) >1 800 ppm This product contains 1 ounce of Toluene, 2 ounces of Xylene and 6 ounces of Acetone per can of product. Toluene, Xylene, and Acetone are regulated chemicals under the Emergency Planning and Right- To-Know Act. You are required to file E.P.A. SARA reports once threshold of 10,000 pounds of any of these chemicals has been purchased for one location in each calendar year. All components of this product are listed on the E.P.A./TSCA inventory of chemical substances. SECTION III – PHYSICAL DATA BOILING POINT (ºF) 133 SPECIFIC GRAVITY (H2O = 1) 0.85 VAPOR PRESSURE (mm. Hg.) N/A PERCENT VOLATILE BY VOLUME 70 VAPOR DENSITY (AIR = 1) N/A EVAPORATION RATE ( Butyl Acetate faster SOLUBILITY IN WATER insoluble PH N/A APPEARANCE AND ODOR Colored liquid with paint odor. SECTION IV – FIRE AND EXPLOSION DATA Lel Uel FLASH POINT (Method Used) 40ºF T.O.C. FLAMMABLE LIMITS Flame Projection: 18” with flashback. N/A N/A EXTINGUISHING MEDIA Dry Chemical, Foam, Carbon Dioxide SPECIAL FIRE FIGHTING PROCEDURES Fire fighters should wear full protective clothing including self-contained respiratory equipment operated in a positive mode. Use water spray to keep containers cool. UNUSUAL FIRE AND EXPLOSION HAZARDS Cans may vent, rupture, or burst when exposed to temperatures in excess of 120ºF. (Continued on reverse side) Page 851 of 1287 Page 851 of 1287 Page 851 of 1287 Page 851 of 1287 ---PAGE BREAK--- SECTION V – HEALTH HAZARD DATA (AEROSPY) THRESHOLD LIMIT VALUE 100 ppm PRIMARY ROUTES OF ENTRY Inhalation x Skin Contact x Other (Specify) EFFECTS OF OVEREXPOSURE Eyes- irritation. Skin- prolonged or repeated contact may cause irritation. Inhalation- headache, dizziness, nausea, unconsciousness and even death. Ingestion- nausea, vomiting. EMERGENCY AND FIRST AID PROCEDURE Eyes- flush with copious amounts of water lifting lids and removing contact lenses to ensure complete irrigation- get medical attention. Skin- flush with water and then wash with soap and water, launder contaminated clothing before reuse- get medical attention if irritation persists. Inhalation- remove to fresh air and assist breathing as necessary- get medical attention. Ingestion- Do Not Induce Vomiting- aspiration of material into lungs may be harmful or fatal- get medical attention. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None Known Carcinogen: NTP IARC OTHER No SECTION VI – REACTIVITY DATA UNSTABLE STABILITY STABLE x CONDITIONS TO AVOID Sources of ignition and temperatures in excess of 120ºF. INCOMPATABILITY (Conditions to avoid) Strong Oxidizers HAZARDOUS DECOMPOSITION PRODUCTS Oxides of Carbon MAY OCCUR HAZARDOUS POLYMERIZATION WILL NOT OCCUR x CONDITIONS TO AVOID None SECTION VII – SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Eliminate all sources of ignition and ventilate area. Dike area to contain spill. Use absorbent material to soak up spill. Shovel or sweep into container for disposal. WASTE DISPOSAL METHOD Aerosol cans when emptied and depressurized through normal use pose no disposal hazard and should be recycled. Absorbent materials should be disposed of in accordance with all Local, State, and Federal regulations. SECTION VIII – SPECIAL PROTECTION INFORMATION SPECIAL RESPIRATORY PROTECTION (Specify type) Use NIOSH approved respirators in areas where TLV has been exceeded LOCAL EXHAUST To control TLV SPECIAL N/A VENTILATION MECHANICAL (General) To control TLV OTHER N/A PROTECTIVE GLOVES Impervious EYE PROTECTION Chemical Goggles OTHER PROTECTIVE EQUIPMENT Eyewash and safety shower. SECTION IX – SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Avoid contact- wear protective clothing and wash thoroughly after using. Avoid inhalation of vapors- use only with adequate ventilation. Do not take internally. Avoid use near sources of ignition. Avoid storage in areas where temperatures may exceed OTHER PRECAUTIONS 120ºF. Read and follow label directions before using. Keep Out of Reach of Children.. HMIS SYMBOL HMIS NFPA NFPA SYMBOL SEVERE 4 EXTREME FIRE REACTIVITY SERIOUS 3 HIGH 4 MODERATE 2 MODERATE 2 1 SLIGHT 1 SLIGHT TOXICITY MINIMAL 0 INSIGNIFICANT SPECIAL NAME John Telles SIGNATURE TITLE CHEMIST PREPARATION DATE June 11, 2007 PHONE NUMBER CHEMTREC [PHONE REDACTED] HEALTH 2 FLAMMABILITY 4 REACTIVITY 1 Page 852 of 1287 Page 852 of 1287 Page 852 of 1287 Page 852 of 1287 ---PAGE BREAK--- PARTS MASTER PREMIUM POWER STEERING FLUID Revision Date:18-Jan-2012 Page 1 of 6 Material Safety Data Sheet NFPA HMIS Health Hazard 0 Fire Hazard 1 Reactivity 0 Issuing Date 19-July-2010 Revision Date 18-Jan-2012 Revision Number 2 1. PRODUCT AND COMPANY IDENTIFICATION Product Name PARTS MASTER PREMIUM POWER STEERING FLUID Product Code F-79 Recommended Use Manufactured by: Omni Specialty Packaging 10399 S. Hwy 1 Shreveport, LA 71115 Phone: 1 (318) 524-1100 Emergency Telephone Number CHEMTREC 1 (800) 424-9300 2. HAZARDS IDENTIFICATION Emergency Overview Appearance Clear Liquid Physical State Liquid Odor Mild petroleum odor Potential Health Effects Principal Routes of Exposure Eye contact, Skin contact, Inhalation, Ingestion Acute Toxicity Eyes Eye contact may result in slight irritation and redness.. Skin Minimally irritating upon direct contact. Inhalation Inhalation of oil mist or fumes can cause irritation of the nose, throat and upper respiratory tract Ingestion Do not ingest. May cause nausea, vomiting/diarrhea. Chronic Effects Prolonged exposure may cause chronic effects. 1 0 0 Page 853 of 1287 Page 853 of 1287 Page 853 of 1287 Page 853 of 1287 ---PAGE BREAK--- PARTS MASTER PREMIUM POWER STEERING FLUID Revision Date:18-Jan-2012 Page 2 of 6 Aggravated Medical Conditions Personnel with pre-existing skin disorders should avoid contact with this product. Environmental Hazard See Section 12 for additional Ecological Information. 3. COMPOSITION/INFORMATION ON INGREDIENTS Formula Mixture Chemical Name CAS-No Weight % Solvent-Dewaxed Heavy Paraffinic Distillates (Petroleum) 64742-65-0 85-100 Viscosity Index Improver Lubricant Mixture 5-15 Additive Package N/A 0-10 4. FIRST AID MEASURES Eye Contact Flush with large amounts of water for 15 minutes. Get medical attention if eye irritation develops or persists. If material is hot, treat for thermal burns and take victim to the hospital immediately. Skin Contact Wash off immediately with soap and plenty of water for at least 15 minutes while removing all contaminated clothing and shoes. Get medical attention immediately if skin discoloration occurs. Inhalation If affected, remove individual to fresh air. If not breathing, give mouth-to-mouth resuscitation. Get medical attention if develop or persist. Ingestion CALL PHYSICIAN IMMEDIATELY. Never give anything by mouth to an unconscious person. Don’t induce vomiting except at the instructions of the physician. Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Flammable Properties Not flammable. Flash Point 380°F Suitable Extinguishing Media Water Fog. Carbon dioxide (CO2). Foam. Dry chemical. Unsuitable Extinguishing Media Water stream may spread fire. Hazardous Combustion Products Decomposition and combustion products may include smoke, carbon dioxide, carbon monoxide, and other low molecular weight hydrocarbons. Explosion Data Sensitivity to Mechanical Impact Not sensitive. Sensitivity to Static Discharge Not sensitive. Protective Equipment and Precautions for Firefighters Wear positive pressure self-contained breathing apparatus (SCBA). Use water to cool containers exposed to flames. Structural firefighters’ protective clothing will only provide limited protection. Mist or sprays may be flammable below the product normal flash point. NFPA Health Hazard 0 Flammability 1 Reactivity 0 Physical and Chemical Hazards - Page 854 of 1287 Page 854 of 1287 Page 854 of 1287 Page 854 of 1287 ---PAGE BREAK--- PARTS MASTER PREMIUM POWER STEERING FLUID Revision Date:18-Jan-2012 Page 3 of 6 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Use personal protective equipment. Avoid contact with skin, eyes, and clothing. Ensure adequate ventilation. Methods for Containment Dike far ahead of liquid spill for later disposal. Methods for Cleaning Up Pick up free liquid for recycle and/or disposal. Residual liquid and/or solid can be absorbed on inert material. Evacuation Procedures Large Spill Consider initial downwind evacuate for at least 300 meters (1000 feet). Fire If tank, rail car or tank car is involved in a fire, isolate for 800 meters (1/2 mile) in all directions; also consider initial evacuation for 800 meters (1/2 mile) in all directions. Reporting Requirements Spills that enter a water body must be reported immediately to the USEPA’s National Response Center at (800)424-8802. Check with your local and state regulators regarding their reporting requirements. 7. HANDLING AND STORAGE Handling Do not pressure, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition; they may explode. See NFPA 30 and OSHA 1910.106 – flammable and combustible liquids. Storage Store away from heat, sparks, open flame, or strong oxidizing agents in closed and properly labeled containers. Empty containers retain product residue (liquid, and/or vapor) and can be dangerous 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Solvent-Dewaxed Heavy Paraffinic Distillates (Petroleum) 64742-65-0 5 mg/m³ mist 5 mg/m³ mist None listed Viscosity Index improver Lubricant 5 mg/m³ mist 5 mg/m³ mist None listed Engineering Measures Additional area ventilation or local exhaust may be required to maintain air concentrations below recommended limits. Personal Protective Equipment Eye/Face Protection Safety glasses or face shield where splashing is possible. Full face-shield to be worn during emergencies. Skin and Body Protection As needed to prevent repeated skin contact. Solvent resistant gloves should be used if needed. Respiratory Protection Not normally needed. During emergencies wear respirator. Hygiene Measures Remove and wash contaminated clothing before re-use. Wash hands before breaks and immediately after handling the product. Page 855 of 1287 Page 855 of 1287 Page 855 of 1287 Page 855 of 1287 ---PAGE BREAK--- PARTS MASTER PREMIUM POWER STEERING FLUID Revision Date:18-Jan-2012 Page 4 of 6 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Clear Liquid Odor Mild petroleum odor Physical State Liquid pH N/A Flash Point 380°F Autoignition Temperature 600°F Boiling Point/Range >500°F Freezing Point <-40°C Explosion Limits N/A Flammability Limits in Air N/A Specific Gravity 0.85 Solubility Negligible Evaporation Rate N/A Vapor Pressure N/A Vapor Density Not Determine Density N/A 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions. Incompatible Products Open Flame and strong oxidizing agents. Conditions to Avoid Heat, flames, and sparks. Hazardous Decomposition Products Decomposition and combustion products may include hydrogen sulfide, alkyl mercaptans, sulfides, oxides or sulfur, oxides of : phosphorous, calcium and zinc; aldehydes, carbon monoxide and carbon dioxide. Hazardous Polymerization None under normal processing. 11. TOXICOLOGICAL INFORMATION Acute Toxicity Product Information Test on similar materials show a low order of acute oral and dermal toxicity. Acute Oral Effects Test on similar materials indicates low order of acute toxicity. Acute Inhalation Effects Low acute toxicity expected on inhalation. Skin Effects Practically non-toxic if absorbed. Other similar highly refined products have not shown skin tumors in mouse skin painting studies. Eye Irritation Minimal irritation on contact. Eye irritation or practically non-irritating base on similar products. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Solvent-Dewaxed Heavy Paraffinic Distillates (Petroleum) 64742-65-0 Rat >2000 mg/kg Rabbit >2000 mg/kg Rat > 2.18 mg/L 4 hours Chronic Toxicity Chronic Toxicity Prolonged exposure may cause chronic effects. Carcinogenicity Not considered a potential carcinogen base on IP346 DMSO of less than 3.0 wt% Target Organ Effects Respiratory system, Eyes, Skin, Genotoxicity This product is considered non-mutagenic and has negative potential for tumor development based on from Modified Ames Assay, with Mutagenic Index of less than 1.0. Page 856 of 1287 Page 856 of 1287 Page 856 of 1287 Page 856 of 1287 ---PAGE BREAK--- PARTS MASTER PREMIUM POWER STEERING FLUID Revision Date:18-Jan-2012 Page 5 of 6 12. ECOLOGICAL INFORMATION Ecotoxicity This product is not toxic to fish but may coat gill structures resulting in suffocation if spilled in shallow, running water. Product may be moderately toxic to amphibians by preventing dermal respiration. This product may cause gastrointestinal distress to birds and mammals through ingestion during pelage grooming. 13. DISPOSAL CONSIDERATIONS Waste Disposal Method Dispose of in accordance with local regulations. Keep this product out of sewers and waterways. Contaminated Packaging Dispose of in accordance with local regulations. 14. TRANSPORT INFORMATION DOT Not regulated IATA Not regulated IMDG/IMO Not regulated 15. REGULATORY INFORMATION International Inventories TSCA DSL EINECS/ELINCS ENCS IECSC KECL PICCS AICS Solvent-Dewaxed Heavy Paraffinic Distillates (Petroleum) 64742-65-0 Present X 265-169-7 X X X X X U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act If spilled into navigable waters it is reportable to National Response Center, [PHONE REDACTED]. Reportable Quantity = Oil Sheen present on navigable water surface. (40 CFR 116; 401.15) Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990. CERCLA Page 857 of 1287 Page 857 of 1287 Page 857 of 1287 Page 857 of 1287 ---PAGE BREAK--- PARTS MASTER PREMIUM POWER STEERING FLUID Revision Date:18-Jan-2012 Page 6 of 6 U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. Florida No listed ingredients are present Massachusetts RTK No listed ingredients are present Minnesota RTK No listed ingredients are present New Jersey RTK Lists petroleum oil, but this product does not contain hazardous ingredients. RTK Lists petroleum oil, but this product does not contain hazardous ingredients greater than Illinois DOL TSL No listed ingredients are present International Regulations Mexico – Grade No information available. Canada Not listed on the Canadian Controlled Product Ingredient Disclosure and is compliant with Controlled Products Regulation CONEG Metals Since cadmium, chromium, lead and mercury are not detectable and it does not exceed 100ppm total in this product, it is compliant with CONEG Metals regulation. EEC (Europe) This product is not known to be a dangerous good internationally. R-Phrases R45: May Cause Cancer S-Phrases S53: Avoid Exposure S45 Hazard Label None Danger Symbol None This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class D2B Toxic materials 16. OTHER INFORMATION Prepared By Juan Parker Issuing Date 28-June-2010 Revision Date 31-Jan-2012 Revision Note Not applicable Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of MSDS Page 858 of 1287 Page 858 of 1287 Page 858 of 1287 Page 858 of 1287 ---PAGE BREAK--- Peak Cool Extended Life Concentrate Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/10/2015 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : Peak Cool Extended Life Concentrate Antifreeze & Coolant 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Automotive Engine Antifreeze & Coolant 1.3. Details of the supplier of the safety data sheet Old World Industries, LLC 4065 Commercial Ave. IL 60062 - USA T (847) 559-2000 www.oldworldind.com 1.4. Emergency telephone number Emergency number : (800) 424-9300; (703) 527 3887 (International) Chemtrec SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Acute Tox. 4 (Oral) H302 Repr. 2 H361 STOT RE 2 H373 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS07 GHS08 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H302 - Harmful if swallowed H361 - Suspected of damaging fertility or the unborn child H373 - May cause damage to organs (kidneys) through prolonged or repeated exposure (oral) Precautionary statements (GHS-US) : P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P260 - Do not breathe mist, spray, vapors P264 - Wash affected areas thoroughly after handling P270 - Do not eat, drink or smoke when using this product P280 - Wear personal protective equipment as required P301+P310 - If swallowed: Immediately call doctor/physician or poison center P301+P330+P331 - If swallowed: rinse mouth. Do NOT induce vomiting P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P308+P313 - If exposed or concerned: Get medical advice/attention P405 - Store locked up P501 - Dispose of contents/container, in a safe manner, to appropriate waste disposal facility, in accordance with local/regional/national/international regulations 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) No data available Page 859 of 1287 Page 859 of 1287 Page 859 of 1287 Page 859 of 1287 ---PAGE BREAK--- Peak Cool Extended Life Concentrate Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/10/2015 EN (English) 2/9 SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % by wt GHS-US classification ethylene glycol (CAS No) 107-21-1 90 - 97 Acute Tox. 4 (Oral), H302 diethylene glycol (CAS No) 111-46-6 < 5 Acute Tox. 4 (Oral), H302 STOT RE 2, H373 water (CAS No) 7732-18-5 < 4 Not classified potassium (CAS No) 3164-85-0 < 3 Repr. 2, H361 denatonium benzoate (CAS No) 3734-33-6 30 - 50 ppm Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 STOT SE 3, H335 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Seek immediate medical advice. Allow the victim to rest. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. First-aid measures after skin contact : Remove contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Rinse immediately with plenty of water (for at least 15 minutes). Get medical advice/attention. Specific treatment (see supplemental first aid instructions on this label). First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse immediately with plenty of water for 15 minutes, lifting lower and upper lids. If eye irritation persists: Rinse immediately with plenty of water. Get medical advice/attention. First-aid measures after ingestion : Obtain emergency medical attention. Rinse mouth. If the person is fully conscious, make him/her drink two glasses of water. Never give an unconscious person anything to drink. Do NOT induce vomiting. Call a POISON CENTER/doctor/physician if you feel unwell. If medical advice is delayed, and if the person has swallowed a moderate volume of material (a few ounces), then give three to four ounces of hard liquor, such as whiskey. For children, give proportionally less liquor, according to weight. 4.2. Most important and effects, both acute and delayed : Causes damage to organs (kidneys) (oral). Suspected of damaging fertility or the unborn child. after skin contact : Causes skin irritation. after eye contact : Causes serious eye damage. after ingestion : The lethal dose in humans is estimated to be 100 mL (3 oz). Swallowing a small quantity of this material will result in serious health hazard. 4.3. Indication of any immediate medical attention and special treatment needed A more effective intravenous antidote for physician uses is a potent inhibitor of alcohol dehydrogenases, which effectively blocks the formation of toxic metabolites of ethylene glycol. It has been used to decrease the metabolic consequences of ethylene glycol poisoning before metabolic acidosis coma, seizures, and renal failure have occured. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water fog. Fine water spray. Alcohol-resistant foam. Foam. Carbon dioxide. Dry chemical powder. Sand. Unsuitable extinguishing media : May spread fire. Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Carbon monoxide. Carbon Dioxide. Reactivity : No dangerous reactions known under normal conditions of use. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Page 860 of 1287 Page 860 of 1287 Page 860 of 1287 Page 860 of 1287 ---PAGE BREAK--- Peak Cool Extended Life Concentrate Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/10/2015 EN (English) 3/9 Special protective equipment for fire fighters : Wear positive pressure self-contained breathing apparatus (SCBA). Protective fire fighting clothing (includes fire-fighting helmet, coat, pants, boots and gloves). SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Refer to section 8.2. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Hygiene measures : Do not eat, drink or smoke when using this product. Wash affected areas thoroughly after handling. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Heat sources. Keep container closed when not in use. Product may become solid at temperatures below -18 ºC (0 ºF). Do not store near food, foodstuffs, drugs or potable water supplies. Do not cut, drill, weld, use a blowtorch on, etc. containers even when empty. Incompatible products : Keep away from strong acids, strong bases and oxidizing agents. Incompatible materials : Sources of ignition. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters ethylene glycol (107-21-1) USA ACGIH ACGIH Ceiling (mg/m³) 100.00 mg/m³ USA ACGIH Remark (ACGIH) Upper Respiratory Tract (URT) & Eye irritant 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Gloves. Safety glasses. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Respiratory protection : If exposed to levels above exposure limits wear appropriate respiratory protection. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Page 861 of 1287 Page 861 of 1287 Page 861 of 1287 Page 861 of 1287 ---PAGE BREAK--- Peak Cool Extended Life Concentrate Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/10/2015 EN (English) 4/9 Color : orange Odor : Mild Odor threshold : No data available pH 50% water solution : 8 Relative evaporation rate (butylacetate=1) : Nil Freezing point : -18 °C (0 ºF) Boiling point : 158 °C (317 ºF) Flash point : 116 °C (241 ºF) [100% Ethylene Glycol] ASTM D56 Auto-ignition temperature : 400 °C (752 ºF) [100% Ethylene Glycol] Literature Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : < 0.1 @ 20 ºC Relative vapor density at 20 °C : No data available Specific Gravity : 1.12 Density : 1.12 g/l (9.3 lbs/gal) Solubility : Water: Complete Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : Not applicable. Oxidizing properties : Not applicable. Explosive limits : 3.2 - 15.3 vol % 9.2. Other information VOC content : 0.00 % SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reactions known under normal conditions of use. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Keep away from any flames or sparking source. Extremely high or low temperatures. 10.5. Incompatible materials Keep away from strong acids, strong bases and oxidizing agents. 10.6. Hazardous decomposition products Carbon dioxide. Carbon monoxide. Fume. Alcohols. Aldehydes. Ethers. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Oral: Harmful if swallowed. denatonium benzoate (3734-33-6) LD50 oral rat 584 mg/kg (Rat) LD50 dermal rabbit > 2,000 mg/kg (Rabbit) ATE US (oral) 584 mg/kg bodyweight ethylene glycol (107-21-1) LD50 oral rat > 5,000 mg/kg (Rat) ATE US (oral) 500 mg/kg bodyweight Page 862 of 1287 Page 862 of 1287 Page 862 of 1287 Page 862 of 1287 ---PAGE BREAK--- Peak Cool Extended Life Concentrate Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/10/2015 EN (English) 5/9 diethylene glycol (111-46-6) LD50 oral rat 12,565 mg/kg (Rat) LD50 dermal rabbit 11,890 mg/kg (Rabbit) ATE US (oral) 500 mg/kg bodyweight ATE US (dermal) 11,890 mg/kg bodyweight Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitisation : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Suspected of damaging fertility or the unborn child. Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : May cause damage to organs (kidneys) through prolonged or repeated exposure (oral). Aspiration hazard : Not classified Potential adverse human health effects and : Based on available data, the classification criteria are not met. Harmful if swallowed. after skin contact : Causes skin irritation. after eye contact : Causes serious eye damage. after ingestion : The lethal dose in humans is estimated to be 100 mL (3 oz). Swallowing a small quantity of this material will result in serious health hazard. SECTION 12: Ecological information 12.1. Toxicity denatonium benzoate (3734-33-6) LC50 fish 1 > 1,000 mg/l 96 h; Salmo gairdneri mykiss) EC50 Daphnia 1 13 mg/l (48 h; Daphnia magna) ethylene glycol (107-21-1) LC50 fish 1 53,000 mg/l (96 h; Pimephales promelas; Static system) EC50 Daphnia 1 > 10,000 mg/l (24 h; Daphnia magna) LC50 fish 2 40,761 mg/l (96 h; Salmo gairdneri mykiss); Static system) Threshold limit algae 1 > 10,000 mg/l (168 h; Scenedesmus quadricauda) Threshold limit algae 2 2,000 mg/l (192 h; Microcystis aeruginosa) diethylene glycol (111-46-6) LC50 fish 1 > 5,000 ppm (24 h; Carassius auratus) LC50 other aquatic organisms 1 1,174 mg/l (Xenopus laevis) EC50 Daphnia 1 > 10,000 mg/l (24 h; Daphnia magna) LC50 fish 2 61,072 ppm (168 h; Poecilia reticulata) TLM fish 1 > 32,000 mg/l (96 h; Gambusia affinis) TLM other aquatic organisms 1 > 1,000 ppm (96 h) Threshold limit other aquatic organisms 1 1,174 mg/l (72 h; Xenopus laevis; Toxicity test) Threshold limit other aquatic organisms 2 10,745 mg/l (16 h; Protozoa; Toxicity test) Threshold limit algae 1 2,700 mg/l (168 h; Scenedesmus quadricauda) Threshold limit algae 2 100 mg/l (Selenastrum capricornutum) 12.2. Persistence and degradability denatonium benzoate (3734-33-6) Persistence and degradability Biodegradability in water: no data available. No (test) data on mobility of the substance available. ethylene glycol (107-21-1) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Not established. Biochemical oxygen demand (BOD) 0.47 g O2/g substance Chemical oxygen demand (COD) 1.24 g O2/g substance ThOD 1.29 g O2/g substance BOD of ThOD) 0.36 % ThOD Page 863 of 1287 Page 863 of 1287 Page 863 of 1287 Page 863 of 1287 ---PAGE BREAK--- Peak Cool Extended Life Concentrate Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/10/2015 EN (English) 6/9 diethylene glycol (111-46-6) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Photolysis in the air. Biochemical oxygen demand (BOD) 0.02 g O2/g substance Chemical oxygen demand (COD) 1.51 g O2/g substance ThOD 1.51 g O2/g substance BOD of ThOD) 0.015 % ThOD 12.3. Bioaccumulative potential denatonium benzoate (3734-33-6) Log Pow 1.78 (Estimated value) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < ethylene glycol (107-21-1) BCF fish 1 10 (72 h; Leuciscus idus) BCF other aquatic organisms 1 0.21 - 0.6 (Procambarus sp.; Chronic) BCF other aquatic organisms 2 190 (24 h; Algae) Log Pow -1.34 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established. diethylene glycol (111-46-6) Log Pow -1.98 Bioaccumulative potential Bioaccumulation: not applicable. 12.4. Mobility in soil ethylene glycol (107-21-1) Surface tension 0.048 N/m (20 ºC / 68 ºF) diethylene glycol (111-46-6) Surface tension 0.0485 N/m 12.5. Other adverse effects Effect on ozone layer : No known effect on the ozone layer Effect on global warming : No known ecological damage caused by this product. Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose of contents/container, in a safe manner, to appropriate waste disposal facility, in accordance with local/regional/national/international regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Transport document description : UN3082 Environmentally hazardous substances, liquid, n.o.s., 9, III UN-No.(DOT) : 3082 DOT NA no. : UN3082 Proper Shipping Name (DOT) : Environmentally hazardous substances, liquid, n.o.s. Department of Transportation (DOT) Hazard Classes : 9 - Class 9 - Miscellaneous hazardous material 49 CFR 173.140 Hazard labels (DOT) : 9 - Class 9 (Miscellaneous dangerous materials) DOT Symbols : G - Identifies PSN requiring a technical name Packing group (DOT) : III - Minor Danger DOT Packaging Exceptions (49 CFR 173.xxx) : 155 DOT Packaging Non Bulk (49 CFR 173.xxx) : 203 Page 864 of 1287 Page 864 of 1287 Page 864 of 1287 Page 864 of 1287 ---PAGE BREAK--- Peak Cool Extended Life Concentrate Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/10/2015 EN (English) 7/9 DOT Packaging Bulk (49 CFR 173.xxx) : 241 DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : No limit DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : No limit DOT Vessel Stowage Location : A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel. Other information : Non Bulk: Not regulated by the US D.O.T. (in quantities under 5,000 lbs in any one inner package). ADR No additional information available Transport by sea UN-No. (IMDG) : Not regulated by IMDG (in quantities under 5,000 lbs in any one inner package) Air transport UN-No.(IATA) : Not regulated by IATA (in quantities under 5,000 lbs in any one inner package) SECTION 15: Regulatory information 15.1. US Federal regulations Peak Cool Extended Life Concentrate Antifreeze & Coolant EPA TSCA Regulatory Flag Toxic Substances Control Act (TSCA): The intentional ingredients of this product are listed denatonium benzoate (3734-33-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory ethylene glycol (107-21-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 RQ (Reportable quantity, section 304 of EPA's List of Lists) 5000 lb(s) SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard Ethylene glycol is subject to Tier 1 and/or Tier II annual inventory reporting. SARA Section 313 - Emission Reporting Ethylene glycol is subject to Form R Reporting requirements. diethylene glycol (111-46-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory potassium (3164-85-0) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA Peak Cool Extended Life Concentrate Antifreeze & Coolant WHMIS Classification Class D Division 2 Subdivision A - Very toxic material causing other toxic effects WHMIS Classification Class D Division 2 Subdivision A - Very toxic material causing other toxic effects EU-Regulations No additional information available Page 865 of 1287 Page 865 of 1287 Page 865 of 1287 Page 865 of 1287 ---PAGE BREAK--- Peak Cool Extended Life Concentrate Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/10/2015 EN (English) 8/9 Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified 15.2.2. National regulations Peak Cool Extended Life Concentrate Antifreeze & Coolant DSL (Canada): The intentional ingredients of this product are listed ECL (South Korea): The intentional ingredients of this product are listed. EINECS (Europe): The intentional ingredients of this product are listed ENCS (Japan): The intentional ingredients of this product are listed \ \ \ \ \ 15.3. US State regulations ethylene glycol (107-21-1) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - - RTK (Right to Know) List SECTION 16: Other information Full text of H-phrases: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Eye Irrit. 2A Serious eye damage/eye irritation, Category 2A Repr. 2 Reproductive toxicity, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H302 Harmful if swallowed H315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation H361 Suspected of damaging fertility or the unborn child H373 May cause damage to organs through prolonged or repeated exposure NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health : 2 Moderate Hazard - Temporary or minor injury may occur Flammability : 1 Slight Hazard Physical : 0 Minimal Hazard Personal Protection : B SDS GHS US (GHS HazCom 2012) OWI Old World Industries, LLC makes no warranty, representation or guarantee as to the accuracy, sufficiency or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity and suitability of his own use, handling and disposal of this product. Since actual use by others is beyond our control, no warranty, expressed or implied, is made by Old World Industries, LLC as to the effects of such use, the results to be obtained or the safety and toxicity of this product, nor does Old World Industries, LLC assume liability arising out of the use by others of this product referred to herein. The data in this SDS relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Page 866 of 1287 Page 866 of 1287 Page 866 of 1287 Page 866 of 1287 ---PAGE BREAK--- Peak Cool Extended Life Concentrate Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/10/2015 EN (English) 9/9 Page 867 of 1287 Page 867 of 1287 Page 867 of 1287 Page 867 of 1287 ---PAGE BREAK--- Date of issue/Date of revision : 7/09/2015. 1/11 Penetrating Oil HL 25 Conforms to HazCom 2012 GHS product identifier Other means of ID Recommended use Supplier's details : Penetrating Oil HL 25 : Not available : Penetrating fluid : Miller Industrial Fluids, LLC 1751 W. Raymond Street Indianapolis, IN 46221 Phone: (317) 634-7300 Fax: (317) 636-6761 Emergency telephone number Email: [EMAIL REDACTED] Website: www.millerif.com : CHEMTREC, U.S.: 1-[PHONE REDACTED] International: +1-[PHONE REDACTED] Hours of Operation: 8am 5pm OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the substance or mixture : FLAMMABLE LIQUIDS - Category 4 ACUTE TOXICITY: INHALATION - Category 4 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) [Narcotic effects] - Category 3 ASPIRATION HAZARD - Category 1 GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : Combustible liquid. Harmful if inhaled. Causes skin and eye irritation. May be fatal if swallowed and enters airways. May cause drowsiness and dizziness. Precautionary statements Prevention : Wear protective gloves. Wear eye or face protection. Keep away from flames and hot surfaces. - No smoking. Use only outdoors or in a well-ventilated area. Avoid breathing vapor. Wash hands thoroughly after handling. Response : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Store locked up. Store in a well-ventilated place. Keep cool. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Section 1. Identification Section 2. Hazards identification Page 868 of 1287 Page 868 of 1287 Page 868 of 1287 Page 868 of 1287 ---PAGE BREAK--- Date of issue/Date of revision : 7/09/2015. 2/11 Penetrating Oil HL 25 Section 2. Hazards identification Hazards not otherwise classified : None known. Substance/mixture : Mixture Other means of identification : None CAS number/other identifiers CAS number : None Ingredient name % CAS number 70 - 85 64742-47-8 * = Various = Mixture = Proprietary Any concentration shown as a range is to protect confidentiality or is due to process variation. Occupational exposure limits, if available, are listed in Section 8. Description of necessary first aid measures Eye contact Inhalation Skin contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that gas or vapor is still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Most important acute Potential acute health effects Eye contact : Causes eye irritation. Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. Skin contact : Causes skin irritation. Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach. Over-exposure Section 3. Composition/information on ingredients Section 4. First aid measures Petroleum distillates, hydrotreated light Petroleum distillates, hydrotreated light naphthenic 10 - 20 64742-53-6 Page 869 of 1287 Page 869 of 1287 Page 869 of 1287 Page 869 of 1287 ---PAGE BREAK--- Date of issue/Date of revision : 7/09/2015. 3/11 Penetrating Oil HL 25 Section 4. First aid measures Eye contact : Adverse may include the following: pain or irritation watering redness Inhalation Skin contact Ingestion : Adverse may include the following: nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness : Adverse may include the following: irritation redness : Adverse may include the following: nausea or vomiting Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : If ingested, this material presents a significant aspiration and chemical pneumonitis hazard. Induction of emesis is not recommended. Consider activated charcoal and/or gastric lavage. If patient is obtunded, protect the airway by cuffed endotracheal intubation or by placement of the body in a Trendelenburg and left lateral decubitus position. Specific treatments : Treat and supportively. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that gas or vapor is still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. See toxicological information (Section 11) Specific hazards arising from the chemical : Combustible liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Hazardous thermal decomposition products : Use dry chemical, water spray (fog) or foam. : Do not use water jet. : Decomposition products may include the following materials: carbon dioxide carbon monoxide Special protective actions for fire-fighters Special protective equipment for fire-fighters : isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 5. Fire-fighting measures Page 870 of 1287 Page 870 of 1287 Page 870 of 1287 Page 870 of 1287 ---PAGE BREAK--- Penetrating Oil HL 25 Date of issue/Date of revision : 7/09/2015. 4/11 Personal precautions, protective equipment and emergency procedures For non-emergency personnel : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up Small spill : Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Precautions for safe handling Protective measures : Advice on general : occupational hygiene Put on appropriate personal protective equipment (see Section Do not swallow. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Do not reuse container. Non equilibrium conditions may increase the fire hazard associated with this product. Always bond receiving containers to the fill pipe before and during loading. Always confirm that receiving container is properly grounded. Bonding and grounding alone may be inadequate to eliminate fire and explosion hazards. Carefully review operations that may increase the risks such as tank and container filling, tank cleaning, sampling, gauging, loading, filtering, mixing, agitation, etc. In addition to bonding and grounding, efforts to mitigate the hazards may include, but are not limited to, ventilation, inerting and/or reduction of transfer velocities. Always keep nozzle in contact with the container throughout the loading process. Do NOT fill any portable container in or on a vehicle. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Section 7. Handling and storage Page 871 of 1287 Page 871 of 1287 Page 871 of 1287 Page 871 of 1287 ---PAGE BREAK--- Penetrating Oil HL 25 Date of issue/Date of revision : 7/09/2015. 5/11 Conditions for safe storage, including any incompatibilities : Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Bulk Storage Conditions: Maintain all storage tanks in accordance with applicable regulations. Use necessary controls to monitor tank inventories. Inspect all storage tanks on a periodic basis. Test tanks and associated piping for tightness. Maintain the automatic leak detection devices to assure proper working condition. Control parameters Occupational exposure limits Ingredient name Exposure limits ACGIH TLV (United States). TWA: 400 ppm 8 hours. Appropriate engineering controls Environmental exposure controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, vapor controls, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection Skin protection Hand protection Body protection : Safety glasses equipped with side shields are recommended as minimum protection in industrial settings. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: Splash goggles. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. chemical splash goggles. If inhalation hazards exist, a full-face respirator may be required instead. : Chemical-resistant gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 8. Exposure controls/personal protection Petroleum distillates, hydrotreated light Petroleum distillates, hydrotreated light naphthenic TWA: 5mg/m3 Page 872 of 1287 Page 872 of 1287 Page 872 of 1287 Page 872 of 1287 ---PAGE BREAK--- Penetrating Oil HL 25 Section 8. Exposure controls/personal protection Date of issue/Date of revision : 7/09/2015. 6/11 Respiratory protection : Use a properly fitted, air-purifying or supplied-air respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Physical state Color Odor pH Melting point : Liquid. : Light brown. : Characteristic hydrocarbon solvent odor. : Not available. : -58°C (-72.4°F) Boiling point/boiling range : 175 to 270°C (347 to 518°F) Flash point Evaporation rate Lower and upper explosive (flammable) limits Vapor pressure Vapor density Relative density Density lbs/gal Gravity, °API Solubility Solubility in water Auto-ignition temperature : Closed cup: 80°C (176°F) [Tagliabue (ASTM D-56)] : <1 (n-butyl acetate. = 1) : Lower: 0.6% Upper: 5.5% : 0.03 to 0.06 kPa (0.225 to 0.45 mm Hg) [room temperature] : 4.5 [Air = 1] : 0.81 : 6.79 lbs/gal : Estimated 41 @ 60 F : Very soluble in the following materials: cold water. : 1.5 g/l : 236°C (456.8°F) Reactivity : Not expected to be Explosive, Self-Reactive, Self-Heating, or an Organic Peroxide under US GHS Definition(s). Chemical stability : The product is stable. Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition products should not be produced. Information on toxicological effects Acute toxicity Conclusion/Summary : Petroleum distillates, hydrotreated light: In animal studies utilizing mineral spirits containing up to 22% aromatics indicated that the acute central nervous system effects are reversible. Based on existing animal studies, the potential for persistent effects is not clear. Irritation/Corrosion Section 9. Physical and chemical properties Section 10. Stability and reactivity Section 11. Toxicological information Page 873 of 1287 Page 873 of 1287 Page 873 of 1287 Page 873 of 1287 ---PAGE BREAK--- Date of issue/Date of revision : 7/09/2015. 7/11 Penetrating Oil HL 25 Section 11. Toxicological information Product/ingredient name Result Species Score Exposure Observation Petroleum distillates, hydrotreated light Skin - Mild irritant Rabbit - 24 hours 500 microliters - Skin Eyes Respiratory Sensitization Skin Respiratory Mutagenicity : Primary dermal irritation studies (four hour exposure) in rabbits utilizing mineral spirits containing less than 2% aromatics resulted in slight to moderate skin irritation. In humans, mineral spirits have produced slight to moderate skin irritation particularly with evaporation from the skin is prevented. : No additional information. : Animal studies have demonstrated that mineral spirits produced mild respiratory tract irritation at elevated concentrations. Also, sensory respiratory tract irritation was evident by reduced breathing rates in the test animals in certain studies. : In animal studies utilizing mineral spirits containing up to 18%, aromatics skin sensitization is not evident. : No additional information. Conclusion/Summary : In vivo and in vitro studies on mineral spirits containing up to 22 % aromatics indicate that these products are not genotoxic. Carcinogenicity Conclusion/Summary : The National Toxicology Program (NTP) conducted two-year carcinogenicity studies in rats and mice with Stoddard Solvent IIC (less than 2% aromatics). The studies indicated that there was some evidence of carcinogenic activity in male rats (adrenal medulla neoplasms and renal tubule adenoma) but no evidence of carcinogenic activity in female rats. Further, there was equivocal evidence of carcinogenic activity in female mice (hepatocellular adenoma) but no evidence of carcinogenic activity in male mice. A low carcinogenic potential is suggested by a lack of genotoxic potential identified in in vivo and in vitro genetic toxicity tests (with and without metabolic activation). Reproductive toxicity Conclusion/Summary : There were no treatment-related effects on pregnancy rate, mortality or gross post mortem observations in animal studies utilizing mineral spirits containing less than 2% aromatics. Teratogenicity Conclusion/Summary : There were no treatment-related effects on pregnancy rate, mortality or gross post mortem observations in animal studies utilizing mineral spirits containing less than 2% aromatics. Specific target organ toxicity (single exposure) Name Category Route of exposur Target organs Petroleum distillates, hydrotreated light Category 3 Not applicable. Narcotic effects Specific target organ toxicity (repeated exposure) Not available. Aspiration hazard Name Result Petroleum distillates, hydrotreated light ASPIRATION HAZARD - Category 1 Information on the likely routes of exposure Potential acute health effects : Routes of entry anticipated: Oral, Dermal, Inhalation. Petroleum distillates, hydrotreated light naphthenic ASPIRATION HAZARD - Category 1 Page 874 of 1287 Page 874 of 1287 Page 874 of 1287 Page 874 of 1287 ---PAGE BREAK--- Date of issue/Date of revision : 3/30/2015. 8/11 Penetrating Oil HL 25 Section 11. Toxicological information Eye contact : Causes eye irritation. Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. Skin contact : Causes skin irritation. Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach. related to the physical, chemical and toxicological characteristics Eye contact : Adverse may include the following: pain or irritation watering redness Inhalation Skin contact Ingestion : Adverse may include the following: nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness : Adverse may include the following: irritation redness : Adverse may include the following: nausea or vomiting Potential chronic health effects General : Carcinogenicity : Mutagenicity : Teratogenicity : No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Toxicity Product/ingredient name Result Species Exposure Petroleum distillates, hydrotreated light Acute LC50 2200 µg/l Fresh water Acute LC50 2600 µg/l Fresh water Acute LC50 2900 µg/l Fresh water Fish - Lepomis macrochirus Fish - mykiss Fish - mykiss 4 days 4 days 96 hours Conclusion/Summary : Not available. Persistence and degradability Not available. Conclusion/Summary : Not available. Bioaccumulative potential Product/ingredient name LogPow BCF Potential Petroleum distillates, hydrotreated light 2.8 to 6.5 99 to 5780 high Mobility in soil Section 12. Ecological information Page 875 of 1287 Page 875 of 1287 Page 875 of 1287 Page 875 of 1287 ---PAGE BREAK--- Date of issue/Date of revision : 7/09/2015. 9/11 Rust-Tek 262 Section 12. Ecological information Soil/water partition coefficient (KOC) : Not available. Other adverse effects : No known significant effects or critical hazards. Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. RCRA classification : D018 Section 14. Transport information DOT Classification IMDG IATA UN number NA 1993 Not regulated. Not regulated. UN proper shipping name NA 1993, Combustible Liquid, n. o.s (Naphtha Solvent) Combustible Liquid - - Transport hazard class(es) Combustible liquid. - - Packing group Combustible Liquid - - Environmenta l hazards No. No. No. Additional information Packaging instruction Passenger aircraft Quantity limitation: 60 L Packaging instructions: 203 (non-bulk) Cargo aircraft Quantity limitation: 220 L Packaging instructions: 203 (non-bulk), 241(bulk) - - Special precautions for user : always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Section 13. Disposal considerations Page 876 of 1287 Page 876 of 1287 Page 876 of 1287 Page 876 of 1287 ---PAGE BREAK--- Penetrating Oil HL 25 Section 14. Transport information Date of issue/Date of revision : 7/09/2015. 10/11 U.S. Federal regulations : United States inventory (TSCA 8b): All components are listed or exempted. Clean Water Act (CWA) 307: Naphthalene; Toluene; Benzene Clean Water Act (CWA) 311: Naphthalene; Toluene; Benzene This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the Oil Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters of the United States, their adjoining shorelines, or into conduits leading to surface waters must be reported to the EPA's National Response Center at (800) 424-8802. SARA 302/304 Composition/information on ingredients SARA 304 RQ : Not applicable. SARA 311/312 Classification : Fire hazard Immediate (acute) health hazard Composition/information on ingredients Name Fire Sudden Reactive Immediate Delayed hazard release of (acute) (chronic) pressure health health hazard hazard Petroleum distillates, hydrotreated light Yes. No. No. Yes. No. State regulations Massachusetts : None of the components are listed. New York : None of the components are listed. New Jersey : None of the components are listed. : None of the components are listed. California Prop. 65 WARNING: This product contains less than 0.1% of a chemical known to the State of California to cause cancer. WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm. Ingredient name % Cancer Reproductive No significant risk level Maximum acceptable dosage level Toluene <0.001 No. Yes. No. 7000 µg/day (ingestion) Benzene <0.001 Yes. Yes. 6.4 µg/day 24 µg/day(ingestion) (ingestion) 49 µg/day 13 µg/day (inhalation) (inhalation) Naphthalene <0.0001 Yes. No. Yes. No. <0.0001 Yes. No. 41 µg/day (ingestion) No. 54 µg/day (inhalation) International regulations Section 15. Regulatory information Petroleum distillates, hydrotreated light naphthenic No. No. No. Yes. No. Page 877 of 1287 Page 877 of 1287 Page 877 of 1287 Page 877 of 1287 ---PAGE BREAK--- Penetrating Oil HL 25 Section 15. Regulatory information Date of issue/Date of revision : 7/09/2015. 11/11 International lists : Australia inventory (AICS): All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. Japan inventory: Not determined. Korea inventory: All components are listed or exempted. Malaysia Inventory (EHS Register): All components are listed or exempted. New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted. Philippines inventory (PICCS): All components are listed or exempted. Taiwan inventory (CSNN): Not determined. Canada inventory : All components are listed or exempted. EU Inventory : All components are listed or exempted. WHMIS (Canada) : Class B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). National Fire Protection Association Health 2 Flammability 1 0 Instability/Reactivity Special Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. History Date of issue/Date of revision Key to abbreviations : 7/09/2015. : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations Notice to reader THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED REGARDING ITS CORRECTNESS OR ACCURACY. SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS SDS WAS PREPARED AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER PRODUCT, THIS SDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR PURPOSE OR APPLICATION. THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND/OR DISPOSAL OF THE PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR ANY LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT. Section 16. Other information Page 878 of 1287 Page 878 of 1287 Page 878 of 1287 Page 878 of 1287 ---PAGE BREAK--- Pennzoil Platinum Axle 75W-90 MSDS# 32434DA Version 1.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 1/10 Print Date 07/03/2014 000000038583 MSDS_US 1. MATERIAL AND COMPANY IDENTIFICATION Material Name : Pennzoil Platinum Axle 75W-90 Product Code : 001F1398 Uses : Transmission oil. Manufacturer/Supplier : Shell Oil Products US P.O. Box 4427 Houston TX 77210-4427 USA SDS Request : [PHONE REDACTED] Emergency Telephone Number Spill Information : [PHONE REDACTED] Health Information : [PHONE REDACTED] 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Identity CAS No. Concentration Distillates (petroleum), hydrotreated light paraffinic 64742-55-8 5.00 - 10.00 % Blend of polyolefins and additives. The highly refined mineral oil contains (w/w) DMSO-extract, according to IP346. The highly refined mineral oil is only present as additive diluent. 3. HAZARDS IDENTIFICATION Emergency Overview Appearance and Odour : Amber. Liquid at room temperature. Slight hydrocarbon. Health Hazards : Not classified as dangerous for supply or conveyance. Safety Hazards : Not classified as flammable but will burn. Environmental Hazards : Not classified as dangerous for the environment. Health Hazards : Not expected to be a health hazard when used under normal conditions. Health Hazards Inhalation : Under normal conditions of use, this is not expected to be a primary route of exposure. Skin Contact : Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Eye Contact : May cause slight irritation to eyes. Ingestion : Low toxicity if swallowed. Other Information : Used oil may contain harmful impurities. Signs and : Oil acne/folliculitis signs and may include formation of black pustules and spots on the skin of exposed areas. Page 879 of 1287 Page 879 of 1287 Page 879 of 1287 Page 879 of 1287 ---PAGE BREAK--- Pennzoil Platinum Axle 75W-90 MSDS# 32434DA Version 1.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 2/10 Print Date 07/03/2014 000000038583 MSDS_US Ingestion may result in nausea, vomiting and/or diarrhoea. Aggravated Medical Conditions : Pre-existing medical conditions of the following organ(s) or organ system(s) may be aggravated by exposure to this material: Skin. Environmental Hazards : Not classified as dangerous for the environment. Additional Information : Under normal conditions of use or in a foreseeable emergency, this product does not meet the definition of a hazardous chemical when evaluated according to the OSHA Hazard Communication Standard, 29 CFR 1910.1200. 4. FIRST-AID MEASURES General Information : Not expected to be a health hazard when used under normal conditions. Inhalation : No treatment necessary under normal conditions of use. If persist, obtain medical advice. Skin Contact : Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention. Eye Contact : Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention. Ingestion : In general no treatment is necessary unless large quantities are swallowed, however, get medical advice. Advice to Physician : Treat 5. FIRE-FIGHTING MEASURES Clear fire area of all non-emergency personnel. Flash point : Typical 201 °C / 394 °F Upper / lower Flammability or Explosion limits : Typical 1 - 10 Auto ignition temperature : > 320 °C / 608 °F Specific Hazards : Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide may be evolved if incomplete combustion occurs. Unidentified organic and inorganic compounds. Suitable Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media : Do not use water in a jet. Protective Equipment for Firefighters : Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space. 6. ACCIDENTAL RELEASE MEASURES Avoid contact with spilled or released material. For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on disposal. Observe the relevant local and international regulations. Page 880 of 1287 Page 880 of 1287 Page 880 of 1287 Page 880 of 1287 ---PAGE BREAK--- Pennzoil Platinum Axle 75W-90 MSDS# 32434DA Version 1.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 3/10 Print Date 07/03/2014 000000038583 MSDS_US Protective measures : Avoid contact with skin and eyes. Use appropriate containment to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately. Prevent from spreading by making a barrier with sand, earth or other containment material. Reclaim liquid directly or in an absorbent. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly. Additional Advice : Local authorities should be advised if significant spillages cannot be contained. 7. HANDLING AND STORAGE General Precautions : Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Use the information in this data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling vapour and/or mists. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Storage : Keep container closed and in a cool, well-ventilated place. Use properly labelled and closeable containers. Store at ambient temperature. Product Transfer : This material has the potential to be a static accumulator. Proper grounding and bonding procedures should be used during all bulk transfer operations. Recommended Materials : For containers or container linings, use mild steel or high density polyethylene. Unsuitable Materials : PVC. Additional Information : Polyethylene containers should not be exposed to high temperatures because of possible risk of distortion. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Material Source Type ppm mg/m3 Notation Distillates (petroleum) , hydrotreate d light paraffinic ACGIH TWA(Inhalabl e fraction.) 5 mg/m3 Page 881 of 1287 Page 881 of 1287 Page 881 of 1287 Page 881 of 1287 ---PAGE BREAK--- Pennzoil Platinum Axle 75W-90 MSDS# 32434DA Version 1.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 4/10 Print Date 07/03/2014 000000038583 MSDS_US Distillates (petroleum) , hydrotreate d light paraffinic OSHA Z1 PEL(Mist.) 5 mg/m3 Oil mist, mineral ACGIH TWA(Inhalabl e fraction.) 5 mg/m3 Oil mist, mineral OSHA Z1 PEL(Mist.) 5 mg/m3 Biological Exposure Index (BEI) No biological limit allocated. Exposure Controls : The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Adequate ventilation to control airborne concentrations. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated. Define procedures for safe handling and maintenance of controls. Educate and train workers in the hazards and control measures relevant to normal activities associated with this product. Ensure appropriate selection, testing and maintenance of equipment used to control exposure, e.g. personal protective equipment, local exhaust ventilation. Drain down system prior to equipment break-in or maintenance. Retain drain downs in sealed storage pending disposal or for subsequent recycle. Always observe good personal hygiene measures, such as washing hands after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. Personal Protective Equipment : Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers. Respiratory Protection : No respiratory protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid breathing of material. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where Page 882 of 1287 Page 882 of 1287 Page 882 of 1287 Page 882 of 1287 ---PAGE BREAK--- Pennzoil Platinum Axle 75W-90 MSDS# 32434DA Version 1.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 5/10 Print Date 07/03/2014 000000038583 MSDS_US air-filtering respirators are suitable, select an appropriate combination of mask and filter. Select a filter suitable for combined particulate/organic gases and vapours [boiling point >65°C(149 Hand Protection : Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection: PVC, neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. For continuous contact we recommend gloves with breakthrough time of more than 240 minutes with preference for > 480 minutes where suitable gloves can be identified. For short-term/splash protection we recommend the same, but recognise that suitable gloves offering this level of protection may not be available and in this case a lower breakthrough time may be acceptable so long as appropriate maintenance and replacement regimes are followed. Glove thickness is not a good predictor of glove resistance to a chemical as it is dependent on the exact composition of the glove material. Glove thickness should be typically greater than 0.35 mm depending on the glove make and model. Eye Protection : Wear safety glasses or full face shield if splashes are likely to occur. Protective Clothing : Skin protection not ordinarily required beyond standard issue work clothes. Monitoring Methods : Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate. Validated exposure measurement methods should be applied by a competent person and samples analysed by an accredited laboratory. Examples of sources of recommended exposure measurement methods are given below or contact the supplier. Further national methods may be available. National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods http://www.cdc.gov/niosh/ Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods http://www.osha.gov/ Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances http://www.hse.gov.uk/ Institut für Deutschen Gesetzlichen Page 883 of 1287 Page 883 of 1287 Page 883 of 1287 Page 883 of 1287 ---PAGE BREAK--- Pennzoil Platinum Axle 75W-90 MSDS# 32434DA Version 1.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 6/10 Print Date 07/03/2014 000000038583 MSDS_US Unfallversicherung (IFA), Germany. http://www.dguv.de/inhalt/index.jsp L'Institut National de Recherche et de Securité, (INRS), France http://www.inrs.fr/accueil Environmental Exposure Controls : Take appropriate measures to fulfil the requirements of relevant environmental protection legislation. Avoid contamination of the environment by following advice given in Chapter 6. If necessary, prevent undissolved material from being discharged to waste water. Waste water should be treated in a municipal or industrial waste water treatment plant before discharge to surface water. Local guidelines on emission limits for volatile substances must be observed for the discharge of exhaust air containing vapour. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Amber. Liquid at room temperature. Odour : Slight hydrocarbon. pH : Not applicable. Initial Boiling Point and Boiling Range : > 280 °C / 536 °F estimated value(s) Pour point : Typical -51 °C / -60 °F Flash point : Typical 201 °C / 394 °F Upper / lower Flammability or Explosion limits : Typical 1 - 10 Auto-ignition temperature : > 320 °C / 608 °F Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s)) Density : Typical 875 kg/m3 at 15 °C / 59 °F Water solubility : Negligible. n-octanol/water partition coefficient (log Pow) : > 6 (based on information on similar products) Kinematic viscosity : Typical 110 mm2/s at 40 °C / 104 °F Vapour density (air=1) : > 1 (estimated value(s)) Electrical conductivity : This material is not expected to be a static accumulator. Evaporation rate (nBuAc=1) : Data not available 10. STABILITY AND REACTIVITY Stability : Stable. Conditions to Avoid : Extremes of temperature and direct sunlight. Materials to Avoid : Strong oxidising agents. Hazardous Decomposition Products : Hazardous decomposition products are not expected to form during normal storage. Hazardous Polymerisation : Data not available 11. TOXICOLOGICAL INFORMATION Basis for Assessment : Information given is based on data on the components and the toxicology of similar products. Unless indicated otherwise, the data presented is representative of the product as a whole, rather than for Page 884 of 1287 Page 884 of 1287 Page 884 of 1287 Page 884 of 1287 ---PAGE BREAK--- Pennzoil Platinum Axle 75W-90 MSDS# 32434DA Version 1.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 7/10 Print Date 07/03/2014 000000038583 MSDS_US individual component(s). Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal conditions of use. Skin Irritation : Expected to be irritating. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Eye Irritation : Expected to be irritating. Respiratory Irritation : Inhalation of vapours or mists may cause irritation. Sensitisation : Not expected to be a skin sensitiser. Repeated Dose Toxicity : Not expected to be a hazard. Mutagenicity : Not considered a mutagenic hazard. Carcinogenicity : Not expected to be carcinogenic. Material : Carcinogenicity Classification Highly refined mineral oil (IP346 : ACGIH Group A4: Not classifiable as a human carcinogen. Highly refined mineral oil (IP346 : IARC 3: Not classifiable as to carcinogenicity to humans. Highly refined mineral oil (IP346 : GHS / CLP: No carcinogenicity classification Reproductive and Developmental Toxicity : Not expected to be a hazard. Additional Information : Used oils may contain harmful impurities that have accumulated during use. The concentration of such impurities will depend on use and they may present risks to health and the environment on disposal. ALL used oil should be handled with caution and skin contact avoided as far as possible. 12. ECOLOGICAL INFORMATION Ecotoxicological data have not been determined specifically for this product. Information given is based on a knowledge of the components and the ecotoxicology of similar products. Unless indicated otherwise, the data presented is representative of the product as a whole, rather than for individual component(s). Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic organisms. Expected to be practically non toxic: LL/EL/IL50 > 100 mg/l (to aquatic organisms) LL/EL50 expressed as the nominal amount of product required to prepare aqueous test extract. Mobility : Liquid under most environmental conditions. If it enters soil, it will adsorb to soil particles and will not be mobile. Floats on water. Persistence/degradability : Expected to be not readily biodegradable. Major constituents are expected to be inherently biodegradable, but the product contains components that may persist in the environment. Page 885 of 1287 Page 885 of 1287 Page 885 of 1287 Page 885 of 1287 ---PAGE BREAK--- Pennzoil Platinum Axle 75W-90 MSDS# 32434DA Version 1.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 8/10 Print Date 07/03/2014 000000038583 MSDS_US Bioaccumulation : Contains components with the potential to bioaccumulate. Other Adverse Effects : Product is a mixture of non-volatile components, which are not expected to be released to air in any significant quantities. Not expected to have ozone depletion potential, photochemical ozone creation potential or global warming potential. 13. DISPOSAL CONSIDERATIONS Material Disposal : Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations. Do not dispose into the environment, in drains or in water courses. Container Disposal : Dispose in accordance with prevailing regulations, preferably to a recognised collector or contractor. The competence of the collector or contractor should be established beforehand. Local Legislation : Disposal should be in accordance with applicable regional, national, and local laws and regulations. 14. TRANSPORT INFORMATION US Department of Transportation Classification (49CFR) This material is not subject to DOT regulations under 49 CFR Parts 171-180. IMDG This material is not classified as dangerous under IMDG regulations. IATA (Country variations may apply) This material is either not classified as dangerous under IATA regulations or needs to follow country specific requirements. 15. REGULATORY INFORMATION The regulatory information is not intended to be comprehensive. Other regulations may apply to this material. Federal Regulatory Status Notification Status EINECS All components listed or polymer exempt. TSCA All components listed. Page 886 of 1287 Page 886 of 1287 Page 886 of 1287 Page 886 of 1287 ---PAGE BREAK--- Pennzoil Platinum Axle 75W-90 MSDS# 32434DA Version 1.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 9/10 Print Date 07/03/2014 000000038583 MSDS_US DSL All components listed. Shell classifies this material as an "oil" under the CERCLA Petroleum Exclusion, therefore releases to the environment are not reportable under CERCLA. SARA Hazard Categories (311/312) No SARA 311/312 Hazards. State Regulatory Status California Safe Drinking Water and Toxic Enforcement Act (Proposition 65) This material does not contain any chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. New Jersey Right-To-Know Chemical List Distillates (petroleum), hydrotreated light paraffinic (64742- 55-8) 9.48% Listed. Right-To-Know Chemical List Distillates (petroleum), hydrotreated light paraffinic (64742- 55-8) 9.48% Listed. 16. OTHER INFORMATION NFPA Rating (Health, Fire, Reactivity) : 0, 1, 0 SDS Version Number : 1.1 SDS Effective Date : 02/05/2014 SDS Revisions : A vertical bar in the left margin indicates an amendment from the previous version. SDS Regulation : The content and format of this MSDS is in accordance with the OSHA Hazard Communication Standard, 29 CFR 1910.1200. SDS Distribution : The information in this document should be made available to all who may handle the product. Disclaimer : The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of health, safety and environmental Page 887 of 1287 Page 887 of 1287 Page 887 of 1287 Page 887 of 1287 ---PAGE BREAK--- Pennzoil Platinum Axle 75W-90 MSDS# 32434DA Version 1.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 10/10 Print Date 07/03/2014 000000038583 MSDS_US requirements only. No warranty or guarantee is expressed or implied regarding the accuracy of these data or the results to be obtained from the use of the product. Page 888 of 1287 Page 888 of 1287 Page 888 of 1287 Page 888 of 1287 ---PAGE BREAK--- Page 889 of 1287 Page 889 of 1287 Page 889 of 1287 Page 889 of 1287 ---PAGE BREAK--- Page 890 of 1287 Page 890 of 1287 Page 890 of 1287 Page 890 of 1287 ---PAGE BREAK--- Page 891 of 1287 Page 891 of 1287 Page 891 of 1287 Page 891 of 1287 ---PAGE BREAK--- Page 892 of 1287 Page 892 of 1287 Page 892 of 1287 Page 892 of 1287 ---PAGE BREAK--- Page 893 of 1287 Page 893 of 1287 Page 893 of 1287 Page 893 of 1287 ---PAGE BREAK--- Page 1 of 5 MSDS – PerfectStop Heavy Duty DOT 3 Brake Fluid MATERIAL SAFETY DATA SHEET Warren Unilube, Inc. Address: 915 E. Jefferson Ave. West Memphis, AR 72301 Phone: (800) 428-9284 Chemtrec Number: Domestic: (800) 424-9300 International: (703) 527-3887 SECTION 1 - PRODUCT IDENTIFICATION Trade Name: Perfect Stop DOT 3 Heavy Duty Brake Fluid Date Revised: May 29, 2013 Synonyms: N/A Chemical Name: DOT 3 Brake Fluid DOT Hazard Class: Not Applicable NFPA Codes: Health=1, Flammability=1, Reactivity=0 SECTION 2 - COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS Glycols Trade Secret 0-100 Glycol Ethers Trade Secret 0-100 Corrosion Inhibitor Trade Secret 0-100 OSHA PEL ACGIH TLV NIOSH REL NIOSH Ingredient TWA STEL TWA STEL TWA STEL IDLH Glycols None Estab. None estab. None estab. None estab. None estab. None estab. None estab. Glycol Ethers None Estab. None estab. None estab. None estab. None estab. None estab. None estab. Corr. Inhibitor None Estab. None estab. None estab. None estab. None estab. None estab. None estab. SECTION 3 - HAZARDS INDENTIFICATION DANGER! MAY BE HARMFUL OR FATAL IF SWALLOWED, CAUSE EYE IRRITATION, MAY CAUSE ALLERGIC SKIN REACTION! H M I S H 1 F 1 R 0 ACUTE EFFECTS: Inhalation: Vapors are mildly to markedly irritating to the lungs depending on the exposure level. Eye: Causes severe irritation experienced as discomfort or pain, excess blinking and tear production, with marked excess redness and swelling of the conjunctiva. Skin: No adverse effects expected with exposure to skin. Brief contact may cause slight irritation. Prolonged contact, as with clothing wetted with material, may cause severe irritation and discomfort, seen as local redness and swelling. Ingestion: Ingestion may be fatal. May cause abdominal discomfort, nausea, and vomiting. May produce central nervous system depression and kidney damage. Carcinogenicity: This compound contains no ingredients at concentration of 0.1% or greater that are carcinogens or suspect carcinogens. Medical Conditions Aggravated by Long-Term Exposure: Pre-existing skin, eye, and respiratory disorders may be aggravated Page 894 of 1287 Page 894 of 1287 Page 894 of 1287 Page 894 of 1287 ---PAGE BREAK--- Page 2 of 5 MSDS – PerfectStop Heavy Duty DOT 3 Brake Fluid by exposure to this product. Impaired kidney function from pre-existing disorders may be aggravated by exposure to this product. MSDS - Perfect Stop DOT 3 Heavy Duty Brake Fluid Page 2 of 5 Chronic Effects: Repeated exposure may result in drying of the skin and mucous membranes, causing irritation and dryness. SECTION 4 - EMERGENCY FIRST AID PROCEDURES Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. Skin Contact: Remove any contaminated clothing. Wash skin with soap and water for at least 15 minutes. Get medical attention if irritation develops or persists. Wash clothing before reuse. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: Do not induce vomiting. Never give anything by mouth to an unconscious person. Note to Physicians: There is no specific antidote. Treatment of overexposure should be directed at the control of and the clinical condition of the patient. SECTION 5 - FIRE AND EXPLOSION DATA NFPA Codes: Health=1, Flammability=1, Reactivity=0 Flash Point: >275°F (>135°C) Flash Point Method: CC Burning Rate: Not determined Autoignition Temperature: Not determined LEL: Not determined UEL: Not determined Flammability Classification: Slight to moderate fire hazard when exposed to heat or flames. Extinguishing Media: Water fog, foam, dry chemical, carbon dioxide. Unusual Fire or Explosion Hazards: None known. Hazard Combustion Products: Carbon monoxide, carbon dioxide, and unidentified organic compounds. Fire-Fighting Instructions: Do not release runoff from fire control methods to sewers or waterways. Fire-Fighting Equipment: Wear a self-contained breathing apparatus (SCBA) with a full face-piece operated in pressure-demand or positive-pressure mode. SECTION 6 – ACCIDENTAL RELEASE MEASURES Spill / Leak Procedures: Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal protective equipment. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Use non-sparking tools and equipment. Do not flush to sewer. Small Spills: Contain and recover liquid when possible. Collect liquid in an appropriate container or absorb with an inert material (e.g. vermiculite, dry sand) and place in a chemical waste container. Do not use combustible materials, such as sawdust. Large Spills Containment: Wear respirator and protective clothing as appropriate. Shut off source of leak when safe to do so. For large spills, dike far ahead of liquid spill for later disposal. Do not release into sewers or waterways. Clean-Up: Contain and recover liquid when possible. Collect liquid in appropriate container. Absorb residue with an inert material. Consult with your environmental department for detailed clean-up instructions. Regulatory Requirements: Follow applicable OSHA regulations (29 CFR 1910.120). SECTION 7 – HANDLING AND STORAGE Handling Precautions: May be harmful or fatal if swallowed. Storage Requirements: Store in a cool, dry, ventilated area. Separate from acids, bases, and oxidizing materials. Regulatory Requirements: This product contains the following chemical(s) subject to the reporting requirements of SARA Title III Section 311, 312, and 313: Glycol Ethers. Page 895 of 1287 Page 895 of 1287 Page 895 of 1287 Page 895 of 1287 ---PAGE BREAK--- Page 3 of 5 MSDS – PerfectStop Heavy Duty DOT 3 Brake Fluid SECTION 8 - PERSONAL PROTECTION INFORMATION Engineering Controls: Controls should be such that adequate ventilation is provided. Ventilation: Provide general or local exhaust ventilation systems to maintain airborne concentrations below OSHA PELs (Sec. Local exhaust ventilation is preferred because it prevents contaminant dispersion into the work area by controlling it at its source. Administrative Controls: Normal industrial requirements should be in place. Respiratory Protection: Seek professional advise prior to respirator selection and use. Follow OSHA respirator regulations (29 CFR 1910.134) and, if necessary, wear a MSHA/NIOSH-approved respirator. Select respirator based on its suitability to provide adequate worker protection for given working conditions, level of airborne contamination, and presence of sufficient oxygen. For emergency or non-routine operations (cleaning spills, reactor vessels, or storage tanks), wear an SCBA. Warning! Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. If respirators are used, OSHA requires a written respiratory protection program that includes at least: medical certification, training, fit-testing, periodic environmental monitoring, maintenance, inspection, cleaning, and convenient, sanitary storage areas. Protective Clothing / Equipment: Wear chemically protective gloves, boots, aprons, and gauntlets to prevent prolonged or repeated skin contact. Wear protective eyeglasses or chemical safety goggles, per OSHA eye- and face-protection regulations (29 CFR 1910.133). Contact lenses are not eye protective devices. Appropriate eye protection must be worn instead of, or in conjunction with contact lenses. Safety Stations: Make emergency eyewash stations, safety/quick-drench showers, and washing facilities available in work area. Contaminated Equipment: Separate contaminated work clothes from street clothes. Launder before reuse. Remove this material from your shoes and clean personal protective equipment. Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before eating, drinking, smoking, using the toilet, or applying cosmetics. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Water Solubility: Soluble Appearance and Odor: Yellow to amber liquid with Other Solubilities: Not Available a mild odor Boiling Point: 480°F (248.9°C) Odor Threshold: Not Determined Freezing/Melting Point: Not Determined Vapor Pressure: Not Determined Viscosity: Not Determined Vapor Density (Air=1): >1 Refractive Index: Not Determined Formula Weight: Mixture Surface Tension: Not Determined Density: 8.33 to 9.02 lb/gal % Volatile: Not Determined Specific Gravity (H2O=1, at Evaporation Rate (BuAc=1): <0.01 4°C): 1.000 to 1.070 ph: 10.0 – 11.5 SECTION 10 - REACTIVITY DATA Stability: DOT 3 Brake Fluid is stable at room temperature in closed containers under normal storage and handling conditions. Polymerization: Hazardous polymerization cannot occur. Chemical Incompatibilities: None Known Conditions to Avoid: None Known Hazardous Decomposition Products: Thermal oxidative decomposition of DOT 3 Brake Fluid can produce carbon monoxide, carbon dioxide, and unknown organic compounds. SECTION 11 – TOXICOLOGICAL INFORMATION Eyes: Causes severe irritation experienced as discomfort or pain, excess blinking and tear production, with marked excess redness and swelling of the conjunctiva. Skin: No adverse effects expected with exposure to skin. Brief contact may cause slight irritation. Prolonged contact, as with clothing wetted with material, may cause more severe irritation and discomfort, seen as local redness and swelling. Page 896 of 1287 Page 896 of 1287 Page 896 of 1287 Page 896 of 1287 ---PAGE BREAK--- Page 4 of 5 MSDS – PerfectStop Heavy Duty DOT 3 Brake Fluid Inhalation: Vapors are mildly to markedly irritating to the lungs depending on the exposure level. Ingestion: Ingestion may be fatal. May cause abdominal discomfort, nausea, and vomiting. May produce central nerve system depression and kidney damage. TOXICITY DATA* Acute Inhalation Effects: Human, inhalation, TCLO: Data not available. Acute Oral Effects: Rat, oral, LD50: Data not available Chronic Effects: Data not available Carcinogenicity: Not a listed carcinogen Mutagenicity: Data not available Teratogenicity: Data not available See NIOSH, RTECS for additional toxicity data. SECTION 12 – ECOLOGICAL INFORMATION Ecotoxicity: Data not available Environmental Fate: Data not available Environmental Degradation: Data not available Soil Absorption/Mobility: Data not available SECTION 13 – DISPOSAL CONSIDERATIONS Whatever cannot be saved for recovery or recycling should be disposed of in an approved waste facility in accordance with applicable Federal, State/Provincial and Local requirements. SECTION 14 – TRANSPORT INFORMATION DOT Transportation Data (49 CFR 172.101): Shipping Name: DOT 3 Brake Fluid Hazard Class: Non-Hazardous Liquid ID No.: Not Determined Packing Group: Not Applicable Special Provisions (172.102): Not Applicable Shipping Symbols: Not Applicable Packaging Authorizations: a) Exceptions: Not Applicable b) Non-Bulk Packaging: Not Applicable c) Bulk Packaging: Not Applicable Quantify Limitations: a) Passenger, Aircraft, or Railcar: No Limit b) Cargo Aircraft Only: No limit Vessel Stowage Requirements: a) Vessel Stowage: None b) Other: None SECTION 15 – REGULATORY INFORMATION EPA Regulations: RCRA Hazardous Waste Number: Not listed (40 CFR 261.33) RCRA Hazardous Waste Classification (40 CFR 261): Not classified CERCLA Hazardous Substance (40 CFR 302.4) unlisted specific per RCRA, Sec. 3001; CWA, Sec. 311(b)(4); CWA, Sec. 307(a), CAA, Sec. 112 CERCLA Reportable Quantity (RQ) (40 CFR 302.4): None SARA 311/312 (40 CFR 370): None SARA 313 Toxic Chemical (40 CFR 372.65): glycol ethers SARA 304 EHS (Extremely Hazardous Substance) (40 CFR 355): Not Listed Page 897 of 1287 Page 897 of 1287 Page 897 of 1287 Page 897 of 1287 ---PAGE BREAK--- Page 5 of 5 MSDS – PerfectStop Heavy Duty DOT 3 Brake Fluid OSHA Regulations: Air Contaminant (29 CFR 1910.1000, Table Z-1): Not Listed OSHA Specifically Regulated Substance (29 CFR 1910): Not Listed CALIFORNIA PROPOSITION 65: NONE SECTION 16 – OTHER INFORMATION THIS INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY PROCESS. SUCH INFORMATION IS TO THE BEST OF THIS COMPANY'S KNOWLEDGE AND BELIEVED ACCURATE AND RELIABLE AS OF THE DATE INDICATED. HOWEVER, NO REPRESENTATION, WARRANTY OR GUARANTEE IS MAKE AS TO THE ACCURACY, RELIABILITY OR COMPLETENESS. IT IS THE USER'S RESPONSIBILITY TO SATISFY HIMSELF AS TO THE SUITABLENESS AND COMPLETENESS OF SUCH INFORMATION FOR HIS OWN PARTICULAR USE. Page 898 of 1287 Page 898 of 1287 Page 898 of 1287 Page 898 of 1287 ---PAGE BREAK--- Page 899 of 1287 Page 899 of 1287 Page 899 of 1287 Page 899 of 1287 ---PAGE BREAK--- Page 900 of 1287 Page 900 of 1287 Page 900 of 1287 Page 900 of 1287 ---PAGE BREAK--- Page 901 of 1287 Page 901 of 1287 Page 901 of 1287 Page 901 of 1287 ---PAGE BREAK--- Page 902 of 1287 Page 902 of 1287 Page 902 of 1287 Page 902 of 1287 ---PAGE BREAK--- Page 903 of 1287 Page 903 of 1287 Page 903 of 1287 Page 903 of 1287 ---PAGE BREAK--- SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION Product Name: PERMATEX® FAST ORANGE® Hand Cleaner (Smooth Lotion) - 15 fl. oz. squeeze bottle Product Code: 23116 Stock No.: 23116 Manufacturer Name: Permatex, Inc. Address: 10 Columbus Blvd. Hartford, CT 06106 USA General Phone Number: 1-87-Permatex, (877) 376-2839 Emergency Phone Number: [PHONE REDACTED] CHEMTREC: For emergencies in the US, call CHEMTREC: 800-424- 9300 MSDS Creation Date: August 30, 2010 MSDS Revision Date: June 30, 2012 MSDS Format: According to ANSI Z400.1-2004 NFPA 1 1 0 HMIS Health Hazard 1 Fire Hazard 1 Reactivity 0 Personal Protection X SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS# Ingredient Percent Non hazardous ingredient(s) No Data 60 - 100 by weight d-Limonene 5989-27-5 1 - 10 by weight Ethoxylated C11-C16 Alcohol 127036-24-2 5 - 15 by weight SECTION 3 - HAZARDS IDENTIFICATION Emergency Overview: CAUTION! Irritant. Route of Exposure: Eyes. Skin. Inhalation. Ingestion. Potential Health Effects: Eye: May cause eye irritation. Skin: May cause skin irritation. Inhalation: Prolonged or excessive inhalation may cause respiratory tract irritation. Ingestion: Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea. SECTION 4 - FIRST AID MEASURES Eye Contact: Immediately flush eyes with plenty of water for at least 15 to 20 minutes. Ensure adequate flushing of the eyes by separating the eyelids with fingers. Get immediate medical attention. Skin Contact: Immediately wash skin with plenty of soap and water for 15 to 20 minutes, while removing contaminated clothing and shoes. Get medical attention if irritation develops or persists. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical attention. Ingestion: If swallowed, do NOT induce vomiting. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. SECTION 5 - FIRE FIGHTING MEASURES Flash Point: Not determined. Flash Point Method: Not determined. Auto Ignition Temperature: Not determined. Lower Flammable/Explosive Limit: Not determined. Upper Flammable/Explosive Limit: Not determined. Revision:: 06/30/2012 PERMATEX® FAST ORANGE® Hand Cleaner (Smooth Lotion) - 15 fl. oz. squeeze bottle Stock No. 23116 Page 904 of 1287 Page 904 of 1287 Page 904 of 1287 Page 904 of 1287 ---PAGE BREAK--- Fire Fighting Instructions: Evacuate area of unprotected personnel. Use cold water spray to cool fire exposed containers to minimize risk of rupture. Do not enter confined fire space without full protective gear. If possible, contain fire run-off water. Extinguishing Media: Use carbon dioxide (CO2) or dry chemical when fighting fires involving this material. Protective Equipment: As in any fire, wear Self-Contained Breathing Apparatus (SCBA), MSHA/NIOSH (approved or equivalent) and full protective gear. Unusual Fire Hazards: None. Hazardous Combustion Byproducts: Oxides of carbon and other unknown organic compounds. Irritating fumes and gases may be released upon thermal processing or during combustion. NFPA Ratings: NFPA Health: 1 NFPA Flammability: 1 NFPA Reactivity: 0 NFPA Other: SECTION 6 - ACCIDENTAL RELEASE MEASURES Personnel Precautions: Evacuate area and keep unnecessary and unprotected personnel from entering the spill area. Environmental Precautions: Avoid runoff into storm sewers, ditches, and waterways. Spill Cleanup Measures: Absorb spill with inert material dry sand or earth), then place in a chemical waste container. Provide ventilation. Clean up spills immediately observing precautions in the protective equipment section. After removal, flush spill area with soap and water to remove trace residue. Avoid personal contact and breathing vapors or mists. Ventilate area. Use proper personal protective equipment as listed in section 8. Methods for containment: Wipe or scrape up spill material. Maintain good ventilation for large spills. Place scrap material in a well-ventilated area and allow to cure to rubber. Clean up spills thoroughly as residue is slippery. Methods for cleanup: Wipe or scrape up spill material. Maintain good ventilation for large spills. Place scrap material in a well-ventilated area and allow to cure to rubber. Clean up spills thoroughly as residue is slippery. Other Precautions: Pump or shovel to storage/salvage vessels. Add inhibitor to prevent polymerization. SECTION 7 - HANDLING and STORAGE Handling: Use with adequate ventilation. Avoid breathing vapor, aerosol or mist. Storage: Store in a cool, dry, well ventilated area away from sources of heat and incompatible materials. Keep container closed when not in use. Special Handling Procedures: Provide appropriate ventilation/respiratory protection against decomposition products (see Section 10) during welding/flame cutting operations and to protect against dust during sanding/grinding of cured product. Hygiene Practices: Wash thoroughly after handling. SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION - EXPOSURE GUIDELINES Engineering Controls: Use appropriate engineering control such as process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Good general ventilation should be sufficient to control airborne levels. Where such systems are not effective wear suitable personal protective equipment, which performs satisfactorily and meets OSHA or other recognized standards. Consult with local procedures for selection, training, inspection and maintenance of the personal protective equipment. Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29 CFR 1910.133, OSHA eye and face protection regulation, or the European standard EN 166. Skin Protection Description: Wear appropriate protective gloves and other protective apparel to prevent skin contact. Consult manufacturer's data for permeability data. Respiratory Protection: A NIOSH approved air-purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. Other Protective: Facilities storing or utilizing this material should be equipped with an eyewash and a deluge shower safety station. Revision:: 06/30/2012 PERMATEX® FAST ORANGE® Hand Cleaner (Smooth Lotion) - 15 fl. oz. squeeze bottle Stock No. 23116 Page 905 of 1287 Page 905 of 1287 Page 905 of 1287 Page 905 of 1287 ---PAGE BREAK--- EXPOSURE GUIDELINES Notes : Only established PEL and TLV values for the ingredients are listed. SECTION 9 - PHYSICAL and CHEMICAL PROPERTIES Physical State Appearance: White viscous lotion Color: White Odor: Orange Boiling Point: >390°F (>200°C) Melting Point: Not determined. Specific Gravity: 0.97 Solubility: Soluble Vapor Density: >1 (air=1) Vapor Pressure: Not determined. Evaporation Rate: Not determined. pH: 6 - 8 Molecular Formula: Mixture Molecular Weight: Mixture Flash Point: Not determined. Flash Point Method: Not determined. Auto Ignition Temperature: Not determined. VOC Content: 78.97 g/l SECTION 10 - STABILITY and REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Hazardous Polymerization: Will not occur. Conditions to Avoid: Exposure to moisture Incompatible Materials: Strong oxidizers, Acids SECTION 11 - TOXICOLOGICAL INFORMATION Non hazardous ingredient(s) : RTECS Number: VV7565000 d-Limonene : RTECS Number: GW6360000 Skin: Administration onto the skin - : >5 gm/kg [Details of toxic effects not reported other than lethal dose value] Administration onto the skin - Rabbit : >5000 mg/kg [Details of toxic effects not reported other than lethal dose value] Administration onto the skin - Rabbit : 10 %/24H Administration onto the skin - Rat : 100 %/1H Ingestion: Oral - Rat LD50: 4400 mg/kg [Behavioral - Changes in motor activity (specific assay) Lungs, Thorax, or Respiration - Respiratory depression Skin and Appendages - Hair] Oral - Mouse LD50: 5600 mg/kg [Behavioral - Changes in motor activity (specific assay) Lungs, Thorax, or Respiration - Respiratory depression Skin and Appendages - Hair] SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity: No ecotoxicity data was found for the product. Environmental Fate: No environmental information found for this product. SECTION 13 - DISPOSAL CONSIDERATIONS Waste Disposal: Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the classifications of hazardous waste prior to disposal. Furthermore, consult with your state and local waste requirements or guidelines, if applicable, to ensure compliance. Arrange disposal in accordance to the EPA and/or state and local guidelines. RCRA Number: Not determined. Revision:: 06/30/2012 PERMATEX® FAST ORANGE® Hand Cleaner (Smooth Lotion) - 15 fl. oz. squeeze bottle Stock No. 23116 Page 906 of 1287 Page 906 of 1287 Page 906 of 1287 Page 906 of 1287 ---PAGE BREAK--- SECTION 14 - TRANSPORT INFORMATION DOT Shipping Name: Not Regulated. DOT UN Number: Not applicable. DOT Hazard Class: Not applicable. DOT Packing Group: Not applicable. SECTION 15 - REGULATORY INFORMATION Non hazardous ingredient(s) : TSCA Inventory Status: Listed Massachusetts: Listed Listed Canada DSL: Listed d-Limonene : TSCA Inventory Status: Listed Canada DSL: Listed Ethoxylated C11-C16 Alcohol : TSCA Inventory Status: Listed Canada DSL: Listed Canadian Regulations. WHMIS Hazard Class(es): D2B All components of this product are on the Canadian Domestic Substances List. SECTION 16 - ADDITIONAL INFORMATION HMIS Health Hazard: 1 HMIS Fire Hazard: 1 HMIS Reactivity: 0 HMIS Personal Protection: X MSDS Creation Date: August 30, 2010 MSDS Revision Date: June 30, 2012 MSDS Author: Actio Corporation Disclaimer: This Health and Safety Information is correct to the best of our knowledge and belief at the date of its publication but we cannot accept liability for any loss, injury or damage which may result from its use. The information given in the Data Sheet is designed only as a guidance for safe handling, storage and the use of the substance. It is not a specification nor does it guarantee any specific properties. All chemicals should be handled only by competent personnel, within a controlled environment. Copyright© 1996-2011 Actio Corporation. All Rights Reserved. Revision:: 06/30/2012 PERMATEX® FAST ORANGE® Hand Cleaner (Smooth Lotion) - 15 fl. oz. squeeze bottle Stock No. 23116 Page 907 of 1287 Page 907 of 1287 Page 907 of 1287 Page 907 of 1287 ---PAGE BREAK--- Safety Data Sheet Revision Number: 006.1 Issue date: 08/22/2014 IDH number: 235325 Product name: Permatex(R) Rust Treatment Page 1 of 6 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Permatex(R) Rust Treatment IDH number: 235325 Product type: Rust preventor Item number: 81387 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-[PHONE REDACTED] (toll free) or 1-[PHONE REDACTED] TRANSPORT EMERGENCY Phone: CHEMTREC 1-[PHONE REDACTED] (toll free) or 1-[PHONE REDACTED] Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW DANGER: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. HAZARD CLASS HAZARD CATEGORY SKIN CORROSION 1A SERIOUS EYE DAMAGE 1 PICTOGRAM(S) Precautionary Statements Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe vapors, mist, or spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves, eye protection, and face protection. Use personal protective equipment as required. Response: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. IF exposed or concerned: Get medical attention. Immediately call a poison control center or physician. Wash contaminated clothing before reuse. Storage: Store locked up. Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Page 908 of 1287 Page 908 of 1287 Page 908 of 1287 Page 908 of 1287 ---PAGE BREAK--- IDH number: 235325 Product name: Permatex(R) Rust Treatment Page 2 of 6 Hazardous Component(s) CAS Number Percentage* Barium sulfate 7727-43-7 5 - 10 2-Butoxyethanol 111-76-2 1 - 5 Propane-1,2-diol 57-55-6 1 - 5 Organic acid Proprietary 1 - 5 Silicon dioxide 7631-86-9 1 - 5 Benzene, 1,1'-oxybis-, tetrapropylene derivs., sulfonated, sodium salts 119345-04-9 0.1 - 1 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. Non hazardous components Water 30-50% 4. FIRST AID MEASURES Inhalation: Move to fresh air. If persist, seek medical advice. Skin contact: Immediately flush skin with plenty of water (using soap, if available). If develop and persist, get medical attention. Eye contact: In case of contact with the eyes, rinse immediately with plenty of water for 15 minutes, and seek immediate medical attention. Ingestion: Keep individual calm. Do not induce vomiting. Get medical attention. See Section 11. 5. FIRE FIGHTING MEASURES Extinguishing media: Will not burn. Special firefighting procedures: Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Unusual fire or explosion hazards: None Hazardous combustion products: Oxides of carbon. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Do not allow material to contaminate ground water system. Clean-up methods: Wipe up with adsorbent material (e.g. cloth, fleece). 7. HANDLING AND STORAGE Handling: Avoid skin and eye contact. Do not wear contact lenses. Wash thoroughly after handling. Keep out of the reach of children. Storage: Keep container closed. Store in original container until ready to use. For information on product shelf life contact Henkel Customer Service at (800) 243-4874. Page 909 of 1287 Page 909 of 1287 Page 909 of 1287 Page 909 of 1287 ---PAGE BREAK--- IDH number: 235325 Product name: Permatex(R) Rust Treatment Page 3 of 6 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Barium sulfate 5 mg/m3 TWA Inhalable fraction. 5 mg/m3 PEL Respirable fraction. 15 mg/m3 PEL Total dust. None None 2-Butoxyethanol 20 ppm TWA 50 ppm (240 mg/m3) PEL (SKIN) None None Propane-1,2-diol None None 10 mg/m3 TWA Aerosol. None Organic acid None None None None Silicon dioxide 6 mg/m3 TWA 20 TWA 0.8 mg/m3 TWA None 3 mg/m3 TWA Respirable fraction. Benzene, 1,1'-oxybis-, tetrapropylene derivs., sulfonated, sodium salts None None None None Engineering controls: Ensure adequate ventilation, especially in confined areas. Respiratory protection: Not normally required. Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Eye/face protection: Safety goggles or safety glasses with side shields. Skin protection: Disposable rubber or plastic gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Milky Odor: Mild Odor threshold: Not available. pH: 1.95 Vapor pressure: 24 mm hg (20 °C (68°F)) Boiling point/range: Not available. Melting point/ range: Not available. Specific gravity: 1.202 Vapor density: 1.2 Flash point: Does not flash. Flammable/Explosive limits - lower: Not applicable Flammable/Explosive limits - upper: Not applicable Autoignition temperature: Not applicable Evaporation rate: Not available. Solubility in water: Soluble Partition coefficient (n-octanol/water): Not available. VOC content: 110 g/l of coating Viscosity: Not available. Decomposition temperature: Not available. Page 910 of 1287 Page 910 of 1287 Page 910 of 1287 Page 910 of 1287 ---PAGE BREAK--- IDH number: 235325 Product name: Permatex(R) Rust Treatment Page 4 of 6 10. STABILITY AND REACTIVITY Stability: Stable Hazardous reactions: Will not occur. Hazardous decomposition products: None Incompatible materials: None known Reactivity: Not available. Conditions to avoid: None known 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes Potential Health Inhalation: Mild respiratory tract irritation. Skin contact: Irritating to skin. Eye contact: May cause severe eye irritation. Ingestion: Not expected under normal conditions of use. Gastric disturbances. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Barium sulfate None Lung 2-Butoxyethanol Oral LD50 (RAT) = 560 mg/kg Oral LD50 (RABBIT) = 0.32 g/kg Oral LD50 (RAT) = 1.48 g/kg Dermal LD50 (RABBIT) = 400 mg/kg Inhalation LC50 (RAT, 4 h) = 486 ppm Inhalation LC50 (RAT, 4 h) = 450 ppm Blood, Central nervous system, Irritant, Kidney, Liver Propane-1,2-diol Oral LD50 (RABBIT) = 18 g/kg Oral LD50 (RAT) = 30 g/kg Irritant Organic acid None Blood, Corrosive, Irritant, Kidney, Liver Silicon dioxide Oral LD50 (RAT) = > 22,500 mg/kg Nuisance dust Benzene, 1,1'-oxybis-, tetrapropylene derivs., sulfonated, sodium salts None No Records Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Barium sulfate No No No 2-Butoxyethanol No No No Propane-1,2-diol No No No Organic acid No No No Silicon dioxide No No No Benzene, 1,1'-oxybis-, tetrapropylene derivs., sulfonated, sodium salts No No No 12. ECOLOGICAL INFORMATION Ecological information: Not available. Page 911 of 1287 Page 911 of 1287 Page 911 of 1287 Page 911 of 1287 ---PAGE BREAK--- IDH number: 235325 Product name: Permatex(R) Rust Treatment Page 5 of 6 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. Hazardous waste number: D005. Barium. D002: Corrosive. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None International Air Transportation (ICAO/IATA) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None Water Transportation (IMO/IMDG) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 Export Notification: None above reporting de minimis CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Immediate Health, Delayed Health CERCLA/SARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). 2-Butoxyethanol (CAS# 111-76-2). CERCLA Reportable quantity: Barium sulfate (CAS# 7727-43-7) 1,000 lbs. (454 kg) California Proposition 65: This product contains a chemical known in the State of California to cause cancer. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Prepared by: Lou Fabrizio, Regulatory Affairs Specialist Issue date: 08/22/2014 Page 912 of 1287 Page 912 of 1287 Page 912 of 1287 Page 912 of 1287 ---PAGE BREAK--- IDH number: 235325 Product name: Permatex(R) Rust Treatment Page 6 of 6 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 913 of 1287 Page 913 of 1287 Page 913 of 1287 Page 913 of 1287 ---PAGE BREAK--- 1. IDENTIFICATION Product identifier Product Name PNEUMATIC-HYDRAULIC SEALANT 36 ML Other means of identification Product Code 54540 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Sealant Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: [PHONE REDACTED] International Emergency: 00+1+ [PHONE REDACTED] Contract Number: MIS0003453 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Skin sensitization Category 1 Specific target organ toxicity (repeated exposure) Category 2 Label elements Emergency Overview Page 1 / 8 Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Causes skin irritation Causes serious eye damage May cause an allergic skin reaction May cause damage to organs through prolonged or repeated exposure Revision Date 16-Mar-2015 SAFETY DATA SHEET Version 1 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Danger Page 914 of 1287 Page 914 of 1287 Page 914 of 1287 Page 914 of 1287 ---PAGE BREAK--- Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Contaminated work clothing should not be allowed out of the workplace Do not breathe dust/fume/gas/mist/vapors/spray Precautionary Statements - Response Get medical advice/attention if you feel unwell Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician IF ON SKIN: Wash with plenty of soap and water Take off contaminated clothing and wash before reuse If skin irritation or rash occurs: Get medical advice/attention In case of fire: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store in a well-ventilated place. Keep cool Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Not applicable Unknown acute toxicity 30.69% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance Chemical Name CAS No Weight-% Trade Secret TETRAETHYLENE GLYCOL HEXOATE 18268-70-7 30 - 60 * DIMETHACRYLATE ESTER 25852-47-5 10 - 30 * 2-HYDROXYETHYL METHACRYLATE 868-77-9 10 - 30 * HYDROPEROXIDE 80-15-9 1 - 5 * PROPYLENE GLYCOL 57-55-6 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Page 2 / 8 Revision Date 16-Mar-2015 54540 - PNEUMATIC-HYDRAULIC SEALANT 36 ML Appearance Purple Physical state Liquid Odor Mild Page 915 of 1287 Page 915 of 1287 Page 915 of 1287 Page 915 of 1287 ---PAGE BREAK--- Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If persist, call a physician. Ingestion IF SWALLOWED. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Most important and effects, both acute and delayed See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. Page 3 / 8 Revision Date 16-Mar-2015 54540 - PNEUMATIC-HYDRAULIC SEALANT 36 ML Page 916 of 1287 Page 916 of 1287 Page 916 of 1287 Page 916 of 1287 ---PAGE BREAK--- 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers closed in a dry, cool and well-ventilated place. Incompatible materials Strong oxidizing agents, Amines 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Purple Odor Mild Odor threshold No information available Page 4 / 8 Remarks • Method 54540 - PNEUMATIC-HYDRAULIC SEALANT 36 ML Flash point > 93 °C / > 199 °F Tag Closed Cup pH No information available Evaporation rate <1 Revision Date 16-Mar-2015 Butyl acetate = 1 Flammability (solid, gas) No information available Property Flammability Limit in Air Melting point / freezing point No information available Values Boiling point / boiling range > 149 °C / 300 °F Page 917 of 1287 Page 917 of 1287 Page 917 of 1287 Page 917 of 1287 ---PAGE BREAK--- Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Incompatible materials Strong oxidizing agents, Amines Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Harmful by inhalation. Eye contact Corrosive to the eyes and may cause severe damage including blindness. Skin contact May cause skin irritation and/or dermatitis. May cause sensitization by skin contact. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 TETRAETHYLENE GLYCOL HEXOATE 18268-70-7 = 18 g/kg ( Rat ) > 20 mL/kg ( Rabbit ) - 2-HYDROXYETHYL METHACRYLATE 868-77-9 = 5050 mg/kg ( Rat ) > 3000 mg/kg ( Rabbit ) - Page 5 / 8 No information available Upper flammability limit: No information available Kinematic viscosity No information available Dynamic viscosity No information available Vapor density >1 Revision Date 16-Mar-2015 Air = 1 Relative density 1.00-1.15 Water solubility soluble Lower flammability limit: No information available Solubility in other solvents No information available 54540 - PNEUMATIC-HYDRAULIC SEALANT 36 ML Partition coefficient No information available No data available Autoignition temperature No information available Vapor pressure <5 mm Hg @ 25°C Decomposition temperature Page 918 of 1287 Page 918 of 1287 Page 918 of 1287 Page 918 of 1287 ---PAGE BREAK--- HYDROPEROXIDE 80-15-9 = 382 mg/kg ( Rat ) = 0.126 mL/kg ( Rabbit ) = 220 ppm ( Rat ) 4 h PROPYLENE GLYCOL 57-55-6 = 20000 mg/kg ( Rat ) = 20800 mg/kg ( Rabbit ) - Information on toxicological effects No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. IARC (International Agency for Research on Cancer) Not classifiable as a human carcinogen Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 4652 mg/kg ATEmix (dermal) 5419 mg/kg ATEmix (inhalation-dust/mist) 11.6 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 70.45% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea 2-HYDROXYETHYL METHACRYLATE 868-77-9 - 213 - 242: 96 h Pimephales promelas mg/L LC50 flow-through 227: 96 h Pimephales promelas mg/L LC50 - HYDROPEROXIDE 80-15-9 - 3.9: 96 h mykiss mg/L LC50 static 7: 24 h Daphnia magna mg/L EC50 PROPYLENE GLYCOL 57-55-6 19000: 96 h Pseudokirchneriella subcapitata mg/L EC50 51600: 96 h mykiss mg/L LC50 static 41 - 47: 96 h mykiss mL/L LC50 static 51400: 96 h Pimephales promelas mg/L LC50 static 710: 96 h Pimephales promelas mg/L LC50 1000: 48 h Daphnia magna mg/L EC50 Static 10000: 24 h Daphnia magna mg/L EC50 Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient 2-HYDROXYETHYL METHACRYLATE 868-77-9 0.47 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Page 6 / 8 Revision Date 16-Mar-2015 54540 - PNEUMATIC-HYDRAULIC SEALANT 36 ML Page 919 of 1287 Page 919 of 1287 Page 919 of 1287 Page 919 of 1287 ---PAGE BREAK--- Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes HYDROPEROXIDE 80-15-9 - - - U096 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status HYDROPEROXIDE 80-15-9 Toxic Ignitable 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Does not comply ENCS Complies IECSC Complies KECL Complies PICCS Does not comply AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % Page 7 / 8 54540 - PNEUMATIC-HYDRAULIC SEALANT 36 ML Revision Date 16-Mar-2015 Page 920 of 1287 Page 920 of 1287 Page 920 of 1287 Page 920 of 1287 ---PAGE BREAK--- HYDROPEROXIDE - 80-15-9 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) HYDROPEROXIDE 80-15-9 10 lb - RQ 10 lb final RQ RQ 4.54 kg final RQ US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts HYDROPEROXIDE 80-15-9 X X X PROPYLENE GLYCOL 57-55-6 X - X ACRYLIC ACID 79-10-7 X X X METHACRYLIC ACID 79-41-4 X X X 1,4-NAPHTHOQUINONE 130-15-4 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 16-Mar-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 8 / 8 Revision Date 16-Mar-2015 - HMIS NFPA Health hazards 2 Flammability 1 Physical hazards 0 Personal protection B Health hazards 2 54540 - PNEUMATIC-HYDRAULIC SEALANT 36 ML Flammability 1 Instability 0 Page 921 of 1287 Page 921 of 1287 Page 921 of 1287 Page 921 of 1287 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 1 Initial Preparation Date: 7/19/1999 Last Revision Date: 10/23/2014 Effective Date: 10/29/2014 MATERIAL SAFETY DATA SHEET PRODUCT IDENTITY: POLAR WINDSHIELD WASH & DEICER FLUID -30F 1. CHEMICAL PRODUCT & COMPANY INFORMATION OLD WORLD INDUSTRIES, LLC 4065 COMMERCIAL AVENUE ILLINOIS 60062 PHONE: [PHONE REDACTED] EMERGENCY PHONE: 1-[PHONE REDACTED] (CHEMTREC) 2. COMPOSITION / INFORMATION ON INGREDIENTS 8-Hour Time Weighted Vapor Pressure Material CAS# % by Wt. Avg. (TWA) mm Hg @ Temp Methanol 67-56-1 35 200 ppm (260 Mg/M3) 96.1 20 C Propylene Glycol 57-55-6 <5 Not established 0.8 20 C Additives N/A <1 N/A N/A 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Slight odor. May be fatal if swallowed. Vapors can cause eye irritation. LD50 Rat (Oral): 5,628 mg/kg (Methanol) LD50 Rabbit (Skin): 20 g/kg (Methanol) Carcinogency: No National Toxicology Program: No International Agency for Research on Cancer: No OSHA Regulated: Yes HAZARD RATING SYSTEM HMIS: HEALTH: 2 FLAMMABILITY: 2 REACTIVITY: 0 PERSONAL PROTECTION: A KEY: 0 - Minimal 1 - Slight 2 - Moderate 3 - Serious 4 - Severe A - Safety glasses POTENTIAL HEALTH EFFECTS Health Hazards (Acute and Chronic): Acute: Acute methanol intoxication is manifested initially by signs of narcosis. This is followed by a latent period Page 922 of 1287 Page 922 of 1287 Page 922 of 1287 Page 922 of 1287 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 2 in which formic acid accumulates in the body causing metabolic acidosis. Severe abdominal, leg, and back pain occur and visual degeneration can lead to blindness. 1. Humans – Ingestion of 80 to 150 mL of methanol is usually fatal to humans (HSDB 1994). One worker died from exposure to vapor ranging from 4,000 to 13,000 ppm over 12 hours (ACGIH 1991). The concentration of 4,000 ppm is roughly equivalent to a total of 1,140 mg/kg over the 12-hour period (see end note Poisoning by nonlethal doses can be described in three stages: narcotic stage similar to ethanol; latent period of 10-15 hours; visual disturbances and central nervous system lesions (Rowe and McCollister 1981). Visual disturbances can lead to blindness due to edema of the retina and atrophy of the optic nerve head (HSDB 1994). Third-stage CNS lesions include headache, dizziness, abdominal, back, and leg pain, delirium that can lead to coma, and nausea (HSDB 1994). Formic acid production causes severe metabolic acidosis (Rowe and McCollister 1981). 2. Animals – Oral LD50 values for methanol is animals are 0.4 g/kg in the mouse, 6.2 to 13 g/kg in the rat, 14.4 g/kg in the rabbit, and 2 to 7 g/kg in the monkey (Rowe and McCollister 1981). The LD50 for dermal application to rabbits is 20 mL/kg (approximately 16 g/kg) (Rowe and McCollister 1981). Dose-response data for inhalation vary with species, dose, and duration (8,800 ppm for 8 hours to 152,800 ppm for 94 minutes). of intoxication include incoordination, salivation, lethargy, narcosis, and death (Rowe and McCollister 1981). Sub-chronic/Chronic: Chronic exposure to methanol, either orally or by inhalation, causes headache, insomnia, gastrointestinal problems, and blindness in humans and hepatic and brain alterations in animals. EPA has derived an oral RfD (reference dose) (see end note 3) for methanol of 0.5 mg/kg/day, based on the absence of liver and brain effects in animals exposed by mouth to 500 mg/kg/day. 1. Humans – “Chronic” exposure to methanol vapors (no time or dose given) caused conjunctivitis, headache, giddiness, insomnia, gastric disturbances, and bilateral blindness (ACGIH 1991). Marked vision loss occurred in one worker exposed to 1,200 to 8,000 ppm vapor for 4 years (ACGIH 1991). 2. Animals – No effects were seen in rats given 1% (approximately 140 mg/kg/day) methanol in drinking water for 6 months (Rowe and McCollister 1981). Hepatic abnormalities (proteinic degeneration, altered RNA metabolism) occurred in rhesus monkeys given 3 to 6 g/kg for 3 to 20 weeks and in rats given 10, 100, or 500 mg/kg/day for one month (Rowe and McCollister 1981). Rabbits chronically fed methanol (no dose or time given) had increasing blood levels, brain and eye edema, and myelin thinning (HSDB 1994). Male and female rats were gavaged with 100, 500, or 2,500 mg/kg/day for 90 days (U.S. EPA 1994). Increased levels of SGPT and SAP as well as decreased brain weights were seen in both sexes at the highest dose; a no-observed-adverse effect level (NOAEL) for the study was 500 mg/kg/day. Based on these data, the U.S. EPA (1994) calculated a chronic RfD (see end note 4) for methanol of 0.5 mg/kg/day. No toxic effects were seen in dogs exposed by inhalation to either 10,000 ppm for 3 minutes, 3x/day, for 100 days or to 450 or 500 ppm, 8 hours/day for 379 days (Rowe and McCollister 1981). Ultrastructural changes were observed in the photoreceptor cells of rabbits exposed to 46.6 ppm for 6 months (Rowe and McCollister 1981). Rowe and McCollister (1981) concluded that the effects of combined oral and inhalation exposure appear to be additive. Rats exposed by inhalation to 16.8 ppm, 4 hours/day, for 6 months and administered 0.7 mg/kg/day orally had changes in blood morphology, oxidation-reduction processes, and liver function (Rowe and McCollister 1981). Carcinogenicity: No information was found on the carcinogenicity of methanol in the secondary sources searched. 1. Humans – No information was found in the secondary sources searched concerning the carcinogenicity of methanol to humans. 2. Animals – No information was found in the secondary sources searched concerning the carcinogenicity of methanol to animals. The NTP has assigned a project leader for methanol and the design of the study is in progress (NTP 1994). Page 923 of 1287 Page 923 of 1287 Page 923 of 1287 Page 923 of 1287 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 3 4. FIRST AID MEASURES Ensure physician has access to this MSDS. Routes of Entry: Inhalation, Skin, Ingestion Signs and of Exposure: Eye Contact: May cause eye irritation. Skin Contact: Frequent or prolonged contact may cause skin irritation experienced as burning, drying, cracking and redness. Inhalation: May cause nose and throat irritation. High concentrations may cause acute central nervous system depression characterized by headaches, dizziness, nausea and confusion. Skin Absorption Health Risks and of Exposure: Harmful quantities of Methyl Alcohol may affect eyes and central nervous system. Ingestion Health Risks and of Exposure: May cause nausea, abdominal pain, headache, shortness of breath, visual impairment and blindness. Severe poisoning can cause coma and death. Medical Conditions Generally Aggravated by Exposure: Ingestion of large amounts of Methyl Alcohol has been shown to damage organs including liver, kidney, pancreas, heart, lungs and brain. Although this rarely occurs, survivors of severe intoxication may suffer permanent neurological damage. Overexposure may aggravate pre-existing disorders of the eyes. People have died as a result of drinking large amounts of methanol. Drinking smaller, non-lethal amounts of methanol adversely affects the human nervous system. Effects range from headaches to incoordination similar to that associated with drunkenness. Delayed effects such as severe abdominal, leg, and back pain can follow the inebriation effects of methanol. Loss of vision and even blindness can also occur after exposure to amounts of methanol causing inebriation. These effects are not likely to occur at levels of methanol that are normally found in the environment. Human health effects associated with breathing or otherwise consuming smaller amounts of methanol over long periods of time are not known. Workers repeatedly exposed to methanol have experienced several adverse effects. Effects range from headaches to sleep disorders and gastrointestinal problems to optic nerve damage. Laboratory studies show that repeat exposure to large amounts of methanol in air or in drinking water cause similar adverse effects in animals. TREATMENT Eyes: Flush with large quantities of water for 15 minutes and seek medical attention. Skin: Remove contaminated clothing and wash contaminated skin with large amounts of soap and water. If irritation persists, get medical attention. Launder clothing before reuse. Inhalation: Remove to fresh air. If breathing has stopped, apply artificial respiration. If breathing is difficult, give oxygen provided a qualified operator is available. Get medical attention. Ingestion: If swallowed, Do Not induce vomiting. Drink a large amount of water, milk or sodium bicarbonate to dilute material in stomach. (Never give anything by mouth to an unconscious person.) Call Poison Control Center, hospital emergency room or physician immediately. Page 924 of 1287 Page 924 of 1287 Page 924 of 1287 Page 924 of 1287 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 4 Notes to Physician: This product contains methanol which can cause intoxication and central nervous system depression. Methanol is metabolized to formic acid and formaldehyde. These metabolites can cause metabolic acidosis, visual disturbances and blindness. Since metabolism is required for these toxic their onset may be delayed from 6 to 30 hours following ingestion. Ethanol competes for the same metabolic pathway and has been used to prevent methanol metabolism. Ethanol administration is indicated in patients or at blood hemodialysis. Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material: skin, lung (for example, asthma-like conditions), liver, kidney, central nervous system, pancreas, heart). Exposure to this material may aggravate any preexisting condition sensitive to a decrease in available oxygen, such as chronic lung disease, coronary artery disease or anemias. 5. FIRE FIGHTING MEASURES FIRE & EXPLOSION HAZARD DATA Flammable Properties: Flash Point: 86 F Method Used: ETA 1010 CC Flammability Limits: Percentage of vapor concentration at which methanol can ignite in presence of spark: LEL: 6.0% UEL: 36.0% Hazardous Combustion Products: Methanol Extinguishing Media: Foam, dry chemical, carbon dioxide or any Class B extinguishing agent. Water may be unsuitable as an extinguishing medium but helpful in keeping adjacent containers cool Fire Fighting Instructions: Use water spray to cool fire exposed containers. Water may be ineffective but may be used to cool exposed containers to prevent pressure buildup and possible auto-ignition or explosion when exposed to extreme heat. If water is used, fog nozzles are preferable. Unusual Fire and Explosion Hazards: Handle as flammable liquid. Vapors are heavier than air and may travel along the ground or may be moved by ventilation. Vapors form an explosive mixture in air between the upper and lower explosive limits which can be ignited by many sources, such as pilot lights, open flames, electrical motors and switches. Protective Equipment For Fire Fighters: Wear NIOSH approved self-contained breathing apparatus with full face piece and protective clothing to prevent contact with skin and eyes. 6. ACCIDENTAL RELEASE MEASURES Small Spill: Absorb liquid on vermiculite, floor absorbent or other absorbent material. Large Spill: Eliminate all ignition sources (flares, flames including pilot lights, electrical sparks). Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source. Prevent from entering drains, sewers, streams or other bodies of water. Prevent from spreading. If runoff occurs, notify authorities as required. Pump or vacuum transfer spilled product to clean containers for recovery. Absorb unrecoverable product. Transfer contaminated absorbent, soil and other materials to containers for disposal. Prevent run-off to sewers, streams or other bodies of water. If run-off occurs, notify proper authorities as required, that a spill has occurred. Page 925 of 1287 Page 925 of 1287 Page 925 of 1287 Page 925 of 1287 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 5 7. HANDLING AND STORAGE Do not swallow. Store in closed containers in a cool, dry, well-ventilated area. Keep away from sparks and open flame. Respiratory Protection: Use approved NIOSH respirator when TLV is exceeded. Ventilation: Provide sufficient ventilation to maintain exposure below TLV. Protective Gloves: Wear appropriate impermeable gloves. Eye Protection: Use chemical safety glasses, goggles and face shields for eye protection. Other Protective Clothing or Equipment: Long sleeves and apron are recommended. Work / Hygienic Practices: Avoid prolonged or repeated skin contact. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Eye Protection: Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Consult your safety representative. Skin Protection: Wear resistant gloves (consult your safety equipment supplier). To prevent repeated or prolonged skin contact, wear impervious clothing and boots. Respiratory Protection: If workplace exposure limit(s) of product or any component is exceeded (see exposure guidelines), a NIOSH/MSHA approved air supplied respiratory is advised in absence of proper environmental control. OSHA regulations also permit other NIOSH/MSHA respirators (negative pressure type) under specified conditions (see your industrial hygienist). Engineering or administrative controls should be implemented to reduce exposure. Engineering Controls: Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below TLV(s). Exposure Guidelines: Component: Methyl Alcohol (67-56-1) OSHA VPEL 200.000 ppm – TWA (skin) OSHA VPEL 250.000 ppm – STEL (skin) ACGIH TLV 200.000 ppm – TWA (skin) ACGIH TLV 250.000 ppm – STEL (skin) 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Range: 166 F - 194 F Specific Gravity (Water .94 @ 20 C Vapor Density (Air=1): Heavier than air Water Solubility: Soluble Appearance: Clear purple liquid Odor: Mild alcohol odor Evaporation Rate: Greater than n-butyl acetate Page 926 of 1287 Page 926 of 1287 Page 926 of 1287 Page 926 of 1287 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 6 10. STABILITY & REACTIVITY DATA Stability: Stable Conditions to Avoid: Ignition sources, such as heat, sparks and flames Incompatibility (Materials to Avoid): Strong acids and strong oxidizing agents Hazardous Decomposition Products: Burning can produce carbon monoxide and/or carbon dioxide. Carbon monoxide is highly toxic if inhaled; carbon dioxide in sufficient concentrations an act as an Hazardous Polymerization: Will not occur 11. TOXICOLOGICAL INFORMATION Mutagenicity (The Effects On Genetic Material): Genotoxicity: Methanol was negative for cell transformation in Syrian hamster embryo cells (clonal assay and viral enhanced), sister chromatid exchange in vitro, and for aneuploidy and chromosome aberrations in Neurospora crassa (GENETOX 1992). The micronucleus test and the assay for chromosome aberrations in mammalian were inconclusive (GENETOX 1992). Developmental/Reproductive Toxicity: No information was found on the developmental toxicity of methanol in humans. Methanol can cause adverse effects in the developing in rats at doses that cause overt maternal intoxication. 1. Humans – No information was found in the secondary sources searched regarding the developmental or reproductive toxicity of methanol to humans. However, one of the breakdown products of the artificial sweetener aspartame is methanol. Increased blood methanol levels did not lead to increased formic acid levels in women receiving up to 200 mg/kg aspartame (no other details reported) and no evidence of fetal risk was detected (HSDB 1994). 2. Animals – Rats were exposed by inhalation, 7 hours/day, to 5,000 or 10,000 ppm methanol on gestation days 1-19 or to 20,000 ppm on days 7-15. Maternal intoxication (unsteadiness) occurred at the highest dose and coincided with extra or rudimentary ribs and urinary or cardiovascular defects in the fetuses (ACGIH 1991). Male rats had significantly lowered testosterone levels after inhalation exposure to 200 ppm methanol for 6 weeks; at 10,000 ppm a change in luteinizing hormone was also observed (HSDB 1994). Neurotoxicity: Methanol causes central nervous system depression in humans and animals as well as degenerative changes in the brain and visual system. 1. Humans – Methanol causes narcosis similar to ethanol intoxication and nonlethal doses can lead to blindness. Autopsy of individuals after lethal doses revealed edema and hyperemia of the brain and degeneration of the ganglion cells of the retina (Rowe and McCollister 1981). 2. Animals – Acute methanol intoxication in animals causes CNS depression as observed by narcosis, incoordination, lethargy, drowsiness, and prostration (Rowe and McCollister 1981). Page 927 of 1287 Page 927 of 1287 Page 927 of 1287 Page 927 of 1287 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 7 Significant Data With Possible Relevance To Humans: Pharmacokinetics: 1. Absorption – Methanol is readily absorbed after oral, inhalation, or dermal exposure. Oral doses in humans of 71 to 84 mg/kg resulted in blood levels of 4.7 to 7.6 mg/100 mL of blood within 3 hours (Rowe and McCollister 1981). Inhalation of 500 to 1,000 ppm methanol for 3 to 4 hours gave urine concentrations of 1 to 3 mg methanol/100 mL of urine at the end of exposure (Rowe and McCollister 1981). Based on urinary methanol levels, the rate of absorption of the chemical appears to be proportional to the concentration of vapor inhaled (HSDB 1994). The rate of dermal absorption increased for 35 minutes then decreased over the next 25 minutes (no other details given) (HSDB 1994). 2. Distribution – Methanol distributes rapidly in dogs exposed to 4,000 to 15,000 ppm for 12 hours to 5 days; the highest concentrations of the chemical were found in blood, eye fluid, bile, and urine (HSDB 1994). 3. Metabolism – Methanol is oxidized in the human liver by the enzyme alcohol dehydrogenase (Rowe and McCollister 1981). Metabolic products include formaldehyde and formic acid (HSDB 1994). The rate of metabolism for methanol (25 mg/kg/hr) is much slower than for ethanol (175 mg/kg/hr) and is independent of concentrations in the blood (HSDB 1994). Formic acid is responsible for the toxic effects of methanol (ACGIH 1991). 4. Excretion – Methanol is excreted either as parent compound in the urine or expired air, or as the formic acid metabolite in urine (Rowe and McCollister 1981; HSDB 1994). The amount of formic acid excreted varies greatly with species from 1% in rabbits to 20% in dogs; humans are intermediate (HSDB 1994). In humans, the half-life of methanol elimination in expired air after oral or dermal exposure is 1.5 hours (HSDB 1994). 12. ECOLOGICAL INFORMATION ENVIRONMENTAL FATE Methanol evaporates when exposed to air. It dissolves completely when mixed with water. Most direct releases of methanol to the environment are to air. Methanol also evaporates from water and soil exposed to air. Once in air, it breaks down to other chemicals. Microorganisms that live in water and in soil can also break down methanol. Because it is a liquid that does not bind well to soil, methanol that makes it way into the ground can move through the ground and enter groundwater. Plants and animals are not likely to store methanol. Methanol by itself is not likely to cause environmental harm at levels normally found in the environment. Methanol can contribute to the formation of photochemical smog when it reacts with other volatile organic carbon substances in air. Movement & Partitioning: The miscibility of methanol in water and a low KOC indicate that the chemical will be highly mobile in soil (HSDB 1994). Volatilization half-lives from a model river and an environmental pond were estimated at 4.8 days and 51.7 days, respectively (HSDB 1994). Methanol can be removed from the atmosphere in rain water (HSDB 1994). Degradation & Transformation: 1. Air – Once in the atmosphere, methanol exists in the vapor phase with a half life of 17.8 days (HSDB 1994). The chemical reacts with photochemically produced hydroxyl radicals to produce formaldehyde (HSDB 1994). Methanol can also react with nitrogen dioxide in polluted air to form methyl nitrite (HSDB 1994). 2. Soil – Biodegradation is the major route of removal of methanol from soils. Several species of Page 928 of 1287 Page 928 of 1287 Page 928 of 1287 Page 928 of 1287 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 8 Methylobacterium and Methylomonas isolated from soils are capable of utilizing methanol as a sole carbon source (CHEMFATE 1994). 3. Water – Most methanol is removed from water by biodegradation. The degradation products of methane and carbon dioxide were detected from aqueous cultures of mixed bacteria isolated from sewage sludge (CHEMFATE 1994). Aerobic, Gram-negative bacteria (65 strains) isolated from seawater, sand, mud, and weeks of marine origin utilized methanol as a sole carbon source (CHEMFATE 1994). Aquatic hydrolysis, oxidation, and photolysis are not significant fate processes for methanol (HSDB 1994). 4. Biota – Bioaccumulation of methanol in aquatic organisms is not expected to be significant based on an estimated bioconcentration factor of 0.2 (HSDB 1994). Ecotoxicology: 1. Toxicity to Aquatic Organisms – Methanol has low acute toxicity to aquatic organisms; lethal concentrations are much greater than 100 mg/L. Ninety-six hour LC50 values for fish are 28,100 mg/L for Pimephales promelas (fathead minnow), 20,100 mg/L for mykiss (rainbow trout), and >28,000 mg/L for Alburnus alburnus (bleak) (AQUIRE 1994). Forty-eight hour LC50 values for Cyprinus carpio (common carp) and Carassius auratus (goldfish) are 28,000 mg/L and 1,700 mg/L, respectively (AWQUIRE 1994). Growth inhibition occurred for 4 strains of Anabaena (blue-green algae) over a range of EC50s of 2.57%-3.13% for 10-14 days (AQUIRE 1994). The LC50 for Artemia salina (brine shrimp) is >10,000 mg/L in 24 hours and that for Culex restuans (mosquito) is 20,000 mg/L in 18 hours (AQUIRE 1994). 2. Toxicity to Terrestrial Organisms – No information was found in the secondary sources searched regarding the toxicity of methanol to terrestrial organisms. However, based on the range of oral LD50s, 0.4 to 14.2 g/kg, for monkeys, rats, mice, and rabbits (Rowe and McCollister 1981), it is unlikely that methanol would be toxic to terrestrial animals at environmental levels. 3. Abiotic Effects – Methanol reacts with nitrogen dioxide in polluted atmospheres to produce methyl nitrite (HSDB 1994). According to the definition provided in the Federal Register (1992), methanol is a volatile organic compound (VOC) substance. As a VOC, methanol can contribute to the formation of photochemical smog in the presence of other VOCs. 13. DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION U. S. Department of Transportation: In Inner Packaging No More Than 5.0 L: Proper Shipping Name: Consumer Commodity ORM-D Per 49 CFR Part 173.10 (PG III, inner packaging no more than 5.0L) In Packaging Over 5.0 L: Proper Shipping Name: Flammable Liquid, n.o.s. (Methanol) ID UN 1993 Class: 3 Hazard Label: Flammable Liquid PG: III Page 929 of 1287 Page 929 of 1287 Page 929 of 1287 Page 929 of 1287 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 9 International Air Dangerous Good Regulations (IATA): Proper Shipping Name: Flammable Liquid, n.o.s. (Methanol) ID UN 1993 Class: 3 Hazard Label: Flammable Liquid PG: III Ltd. Qty. Packaging Instruction: Y309 (Max qty. per package 10L) Special Provision: A3 International Maritime Dangerous Goods (IMDG): Proper Shipping Name: Limited Quantities of Class 3 (This must be notated on Shipper's Declaration). 15. REGULATORY INFORMATION THIS PRODUCT CONTAINS COMPONENT(S) CITED ON THE FOLLOWING REGULATIONS: CHEMICAL NAME CAS NUMBER Methanol 67-56-1 U.S. Federal Regulations TSCA (Toxic Substances Control Act) Status – TSCA (UNITED STATES) The intentional ingredients of this product are listed. CERCLA RQ – 40 CFR 302.4(a) Component RQ (lbs) Methyl Alcohol 5,000 SARA 302 Components – 40 CFR 355 Appendix A None Section 311/312 Hazard Class – 40 CFR 370.2 Immediate Delayed Fire Reactive ( ) Sudden Release of Pressure ( ) SARA 313 Components – 40 CFR 372.65 Section 313 Component(s) CAS Number % Methanol 67-56-1 35 International Regulations Inventory Status – DSL (CANADA) The intentional ingredients of this product are listed. WHMIS Information: B2, D1A ECL (SOUTH KOREA) The intentional ingredients of this product are listed. EINECS (EUROPE) The intentional ingredients of this product are listed. ENCS (JAPAN) The intentional ingredients of this product are listed. Page 930 of 1287 Page 930 of 1287 Page 930 of 1287 Page 930 of 1287 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 10 State and Local Regulations California Proposition 65: Methanol is on the California Proposition 65 list as a reproductive toxicant. New Jersey RTK (Right-to-Know) Label Information: Methyl Alcohol (67-56-1) RTK (Right-to-Know) Label Information: Methanol (67-56-1) Atmospheric Standards: The Clean Air Act Amendments of 1990 list methanol as a hazardous air pollutant. 16. OTHER INFORMATION Contact: Tom Cholke Phone: (847) 559-2225 Old World Industries, LLC makes no warranty, representation or guarantee as to the accuracy, sufficiency or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity and suitability of his own use, handling and disposal of this product. Since actual use by others is beyond our control, no warranty, expressed or implied, is made by Old World Industries, LLC as to the effects of such use, the results to be obtained or the safety and toxicity of this product, nor does Old World Industries, LLC assume liability arising out of the use by others of this product referred to herein. The data in this MSDS relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Page 931 of 1287 Page 931 of 1287 Page 931 of 1287 Page 931 of 1287 ---PAGE BREAK--- 05/16/2015 EN (English US) 1/8 SuperS® Power Steering Fluid Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Version: Not Classified Hazard Pictograms (GHS-US) : Signal Word (GHS-US) : Not Hazardous Hazard Statements (GHS-US) : None Required Precautionary Statements (GHS-US) : P273 - Avoid release to the environment. P501 - Dispose of contents/container in accordance with local, regional, national, and international regulations. SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Mixture Product Name: Power Steering Fluid Product Grades: Product Codes: See section 16 Synonyms: Power Steering Fluid 1.2. Intended Use of the Product Power Steering Fluid 1.3. Name, Address, and Telephone of the Responsible Party Company Smitty’s Supply, Inc. PO BOX 530 Roseland, LA 70456 [PHONE REDACTED] www.smittysinc.net 1.4. Emergency Telephone Number Emergency Number : 1-[PHONE REDACTED], CHEMTREC SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Full text of H-phrases: see section 16 2.2. Label Elements GHS-US Labeling None Required 2.3. Other Hazards The mixture consists of substances capable of producing an aspiration hazard. Aspiration may result in chemical pneumonia (fluid in the lungs), severe lung damage, respiratory failure, and even death. 2.4. Unknown Acute Toxicity (GHS-US) 9.73 percent of the mixture consists of ingredient(s) of unknown acute toxicity. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Not applicable Page 932 of 1287 Page 932 of 1287 Page 932 of 1287 Page 932 of 1287 ---PAGE BREAK--- 05/16/2015 EN (English US) 2/8 SuperS® Power Steering Fluid Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Version: 3.2. Mixture Name Product Identifier % (w/w) Classification (GHS-US) Petroleum distillates, solvent dewaxed (CAS No) 64742-65-0 75.75 – 95, 64 - 85 Not Classified heavy paraffinic, Distillates, petroleum, hydrotreated heavy paraffinic (CAS No) 64742-54-7 0 – 11, 10 - 17 Not Classified Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS No) 68649-42-3 0.7 - 2.7 Aquatic Chronic 3, H402 *The specific chemical identity and/or exact percentage of composition have been withheld as a trade secret within the meaning of the OSHA Hazard Communication Standard [29 CFR 1910.1200]. *More than one of the ranges of concentration prescribed by Controlled Products Regulations has been used where necessary, du e to varying composition. Full text of H-phrases: see section 16 SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label if possible). Inhalation: Remove to fresh air and keep at rest in a position comfortable for breathing. Obtain medical attention if breathing difficulty persists. Skin Contact: Remove contaminated clothing. Drench affected area with water or soap and water for at least 15 minutes. Wash contaminated clothing before reuse. Obtain medical attention if irritation develops or persists. Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention. Ingestion: Do NOT induce vomiting. Rinse mouth. Immediately call a POISON CENTER or doctor/physician. 4.2. Most Important and Effects Both Acute and Delayed General: No known significant effects or critical hazards. Inhalation: Overexposure may be irritating to the respiratory system. Skin Contact: Repeated or prolonged skin contact may cause irritation. Eye Contact: Direct contact with the eyes is likely irritating. Ingestion: Ingestion is likely to be harmful or have adverse effects. Chronic No known significant effects or critical hazards. 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed If you feel unwell, seek medical advice (show the label where possible). SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire. Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Not flammable but will support combustion. Explosion Hazard: Product is not explosive. Reactivity: Hazardous reactions will not occur under normal conditions. 5.3. Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Under fire conditions, hazardous fumes will be present. Firefighting Instructions: Use water spray or fog for cooling exposed containers. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Hazardous Combustion Products: Under fire conditions, may produce fumes, smoke, oxides of carbon and hydrocarbons. Page 933 of 1287 Page 933 of 1287 Page 933 of 1287 Page 933 of 1287 ---PAGE BREAK--- 05/16/2015 EN (English US) 3/8 SuperS® Power Steering Fluid Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Version: Other Information: Refer to Section 9 for flammability properties. Reference to Other Sections Refer to section 9 for flammability properties. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Avoid all contact with skin, eyes, or clothing. Avoid breathing (vapor, mist, spray). 6.1.1. For Non-Emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. 6.1.2. For Emergency Personnel Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Stop leak if safe to do so. Eliminate ignition sources. Ventilate area. 6.2. Environmental Precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Spills should be contained with mechanical barriers. Transfer spilled material to a suitable container for disposal. Contact competent authorities after a spill. 6.4. Reference to Other Sections See Heading 8. Exposure controls and personal protection. For further information refer to section 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Any proposed use of this product in elevated-temperature processes should be thoroughly evaluated to assure that safe operating conditions are established and maintained. Practice good housekeeping - spillage can be slippery on smooth surface either wet or dry. Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Comply with applicable regulations. Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Keep/Store away from direct sunlight, extremely high or low temperatures and incompatible materials. Incompatible Materials: Strong acids, strong bases, strong oxidizers. 7.3. Specific End Use(s) Power Steering Fluid. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters For substances listed in section 3 that are not listed here, there are no established Exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), NIOSH (REL), OSHA (PEL), Canadian provincial governments, or the Mexican government. 8.2. Exposure Controls Appropriate Engineering Controls: Ensure adequate ventilation, especially in confined areas. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure all national/local regulations are observed. Page 934 of 1287 Page 934 of 1287 Page 934 of 1287 Page 934 of 1287 ---PAGE BREAK--- 05/16/2015 EN (English US) 4/8 SuperS® Power Steering Fluid Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Version: Personal Protective Equipment: Protective goggles. Gloves. Materials for Protective Clothing: Chemically resistant materials and fabrics. Hand Protection: Wear chemically resistant protective gloves. Eye Protection: Chemical goggles or safety glasses. Skin and Body Protection: Wear suitable protective clothing. Respiratory Protection: Use a NIOSH-approved respirator or self-contained breathing apparatus whenever exposure may exceed established Occupational Exposure Limits. Environmental Exposure Controls: Do not allow the product to be released into the environment. Consumer Exposure Controls: Do not eat, drink or smoke during use. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State : Liquid Appearance : Amber Odor : Slight Hydrocarbon Odor Threshold : Not available pH : Not available Evaporation Rate : Not available Melting Point : Not available Boiling Point : Not available Flash Point : 171C / 340C Auto-ignition Temperature : Not available Decomposition Temperature : Not available Flammability (solid, gas) : Not available Lower Flammable Limit : Not available Upper Flammable Limit : Not available Vapor Pressure : Not available Relative Vapor Density at 20 °C : Not available Relative Density : Not available Specific Gravity : Not available Solubility : Negligible Partition Coefficient: N-Octanol/Water : Not available Viscosity : Not available Viscosity, Kinematic : Not available Explosive Properties : Product is not explosive Explosion Data – Sensitivity to Mechanical Impact : Not expected to present an explosion hazard due to mechanical impact Explosion Data – Sensitivity to Static Discharge : Not expected to present an explosion hazard due to static discharge SECTION 10: STABILITY AND REACTIVITY 10.1. Reactivity: Hazardous reactions will not occur under normal conditions. 10.2. Chemical Stability: Stable under recommended handling and storage conditions (see section Page 935 of 1287 Page 935 of 1287 Page 935 of 1287 Page 935 of 1287 ---PAGE BREAK--- 05/16/2015 EN (English US) 5/8 SuperS® Power Steering Fluid Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Version: 10.3. Possibility of Hazardous Reactions: Hazardous polymerization will not occur. 10.4. Conditions to Avoid: Direct sunlight, extremely high or low temperatures, heat, hot surfaces, sparks, open flames, incompatible materials, and other ignition sources. 10.5. Incompatible Materials: Strong acids, strong bases, strong oxidizers. 10.6. Hazardous Decomposition Products: No decomposition expected under normal use and storage conditions. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects - Product Acute Toxicity: Not classified LD50 and LC50 Data: Not available Skin Corrosion/Irritation: Not classified Eye Damage/Irritation: Not classified Respiratory or Skin Sensitization: Not classified Germ Cell Mutagenicity: Not classified Teratogenicity: Not classified Carcinogenicity: Not classified Specific Target Organ Toxicity (Repeated Exposure): Not classified Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): Not classified Aspiration Hazard: Not classified After Inhalation: Overexposure may be irritating to the respiratory system. After Skin Contact: Repeated or prolonged skin contact may cause irritation. After Eye Contact: Direct contact with the eyes is likely irritating. After Ingestion: Ingestion is likely to be harmful or have adverse gastrointestinal effects. Chronic Not Classified 11.2. Information on Toxicological Effects - Ingredient(s) LD50 and LC50 Data: Heavy paraffinic, Distillates, petroleum, hydrotreated heavy paraffinic (64742-54-7) LD50 Oral Rat > 2000 mg/kg LD50 Dermal Rabbit > 2 g/kg Petroleum distillates, solvent dewaxed (64742-65-0) LD50 Oral Rat > 5000 mg/kg LD50 Dermal Rabbit > 5 g/kg SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecology - General: Toxic to aquatic life. Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3) LC50 Fish 1 1.0 - 5.0 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) EC50 Daphnia 1 1 - 1.5 mg/l (Exposure time: 48 h - Species: Daphnia magna) LC 50 Fish 2 10.0 - 35.0 mg/l (Exposure time: 96 h - Species: Pimephales promelas [semi-static]) Petroleum distillates, solvent dewaxed (64742-65-0) EC50 Daphina 1 > 1000 mg/L (Exposure time: 48 h – Species: Daphnia magna) LC50 Fish 1 > 5000 mg/l (Exposure time: 96 h - Species: mykiss) Distillates, petroleum, hydrotreated heavy paraffinic (64742-54-7) LC50 Fish 1 > 5000 mg/l (Exposure time: 96 h - Species: mykiss) EC50 Daphnia 1 > 1000 mg/l (Exposure time: 48 h - Species: Daphnia magna) 12.2. Persistence and Degradability Not available Page 936 of 1287 Page 936 of 1287 Page 936 of 1287 Page 936 of 1287 ---PAGE BREAK--- 05/16/2015 EN (English US) 6/8 SuperS® Power Steering Fluid Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Version: 12.3. Bioaccumulative Potential Not available 12.4. Mobility in Soil Not available 12.5. Other Adverse Effects Other Information: Avoid release to the environment. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Sewage Disposal Recommendations: Do not empty into drains; dispose of this material and its container in a safe way. Do not empty into drains. Do not dispose of waste into sewer. Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, provincial, territorial and international regulations. SECTION 14: TRANSPORT INFORMATION 14.1. In Accordance with DOT Not regulated for transport 14.2. In Accordance with IMDG Not regulated for transport 14.3. In Accordance with IATA Not regulated for transport 14.4. In Accordance with TDG Not regulated for transport SECTION 15: REGULATORY INFORMATION 15.1. US Federal Regulations SARA Section 311/312 Hazard Classes Not Classified 15.2. US State Regulations None noted 15.3. Canadian Regulations WHMIS Classification Not Classified Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Class D Division 2 Subdivision B - Toxic material causing other toxic effects Petroleum distillates, solvent dewaxed (64742-65-0) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Uncontrolled product according to WHMIS classification criteria Distillates, petroleum, hydrotreated heavy paraffinic (64742-54-7) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Uncontrolled product according to WHMIS classification criteria This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all of the information required by CPR. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision Date : 05/16/2015 Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200. GHS Full Text Phrases: P273 Avoid release into the environment P501 Dispose of contents/container in accordance with local, regional, national, and international regulations. Page 937 of 1287 Page 937 of 1287 Page 937 of 1287 Page 937 of 1287 ---PAGE BREAK--- 05/16/2015 EN (English US) 7/8 SuperS® Power Steering Fluid Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Version: Product Numbers SuperS Power Steering Fluid SUS 29L 12/12 oz. bottles SUS 29-24 24/12 oz. bottles SUS 30 12/1 quart bottles SUS 129-3 3/1 gallon bottles SUS 129-6 6/1 gallon bottles SUS 29Bulk Bulk SuperS Premium Power Steering Fluid SUS 429L 12/12 oz. bottles Party Responsible for the Preparation of This Document Smitty’s Supply, Inc. PO BOX 530 Roseland, LA 70456 [PHONE REDACTED] www.smittysinc.net This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. North America GHS US 2012 & WHMIS 2 Page 938 of 1287 Page 938 of 1287 Page 938 of 1287 Page 938 of 1287 ---PAGE BREAK--- Page 939 of 1287 Page 939 of 1287 Page 939 of 1287 Page 939 of 1287 ---PAGE BREAK--- Page 940 of 1287 Page 940 of 1287 Page 940 of 1287 Page 940 of 1287 ---PAGE BREAK--- Page 941 of 1287 Page 941 of 1287 Page 941 of 1287 Page 941 of 1287 ---PAGE BREAK--- Page 942 of 1287 Page 942 of 1287 Page 942 of 1287 Page 942 of 1287 ---PAGE BREAK--- Page 943 of 1287 Page 943 of 1287 Page 943 of 1287 Page 943 of 1287 ---PAGE BREAK--- Page 944 of 1287 Page 944 of 1287 Page 944 of 1287 Page 944 of 1287 ---PAGE BREAK--- Page 945 of 1287 Page 945 of 1287 Page 945 of 1287 Page 945 of 1287 ---PAGE BREAK--- Page 946 of 1287 Page 946 of 1287 Page 946 of 1287 Page 946 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Product identifier Propane Other means of identification SDS number WC002 Product code UN1075 Recommended use Portable fuel. Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufacturer/Supplier Worthington Cylinder Corporation Address 300 E. Breed St., Chilton, WI 5301 United States Contact person Ann Stiefvater E-mail address [EMAIL REDACTED] Telephone number 1-[PHONE REDACTED] Emergency telephone number 1-[PHONE REDACTED] International / CHEMTREC 1-[PHONE REDACTED] Domestic 2. Hazard(s) identification Category 1 Flammable gases Physical hazards Liquefied gas Gases under pressure Not classified. Health hazards Not classified. OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable gas. Contains gas under pressure; may explode if heated. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Response Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Eliminate all ignition sources if safe to do so. Storage Protect from sunlight. Store in a well-ventilated place. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise classified (HNOC) May displace oxygen and cause rapid suffocation. 3. Composition/information on ingredients Mixtures 74-98-6 87.5-100 Propane CAS number % Chemical name 74-84-0 0-7 Ethane 115-07-1 0-5 Propylene 106-97-8 0-2.5 Butane SDS US Propane 919503 Version 03 Revision date: 25-March-2015 Issue date: 05-May-2014 1 / 8 Page 947 of 1287 Page 947 of 1287 Page 947 of 1287 Page 947 of 1287 ---PAGE BREAK--- Additives CAS number % Chemical name Ethyl Mercaptan 75-08-1 <0.005 Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First-aid measures Inhalation Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Call a physician or poison control center immediately. Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention if irritation develops and persists. If frostbite occurs, immerse involved area in warm water (between 100 F/38 C and 110 F/43 C, not exceeding 112 F/44 Keep immersed for 20 to 40 minutes. Seek medical assistance. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. Ingestion Ingestion is not a typical route of exposure for gases or liquefied gases. Most important acute and delayed Exposure to rapidly expanding gas or vaporizing liquid may cause frostbite ("cold burn"). Very high exposure can cause suffocation from lack of oxygen. May cause drowsiness or dizziness. Indication of immediate medical attention and special treatment needed Exposure may aggravate pre-existing respiratory disorders. Treat General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Dry chemical, CO2, water spray, fog, or foam. Unsuitable extinguishing media None known. Specific hazards arising from the chemical Selection of respiratory protection for firefighting: follow the general fire precautions indicated in the workplace. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire-fighting equipment/instructions Move container from fire area if it can be done without risk. Do not extinguish fires unless gas flow can be stopped safely; explosive re-ignition may occur. isolate the scene by removing all persons from the vicinity of the incident. No action shall be taken involving any personal risk or without suitable training. For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment, including self-contained breathing apparatus. Stop flow of material. Use water to keep fire exposed containers cool and to protect personnel effecting shutoff. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop leak. Prevent runoff from fire control or dilution from entering streams, sewers or drinking water supply. General fire hazards Extremely flammable gas. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Evacuate the area No action shall be taken involving any personal risk or without suitable training. Keep unnecessary personnel away. Ensure adequate ventilation. In case of inadequate ventilation, use respiratory protection. Wear appropriate personal protective equipment (See Section Methods and materials for containment and cleaning up Ventilate well, stop flow of gas or liquid if possible. Immediately contact emergency personnel. Environmental precautions Should not be released into the environment. Prevent further leakage or spillage if safe to do so. Prevent from entering into soil, ditches, sanitary sewers, waterways and/or groundwater. 7. Handling and storage Precautions for safe handling Eliminate all sources of ignition. Wear appropriate personal protective equipment (See Section Eating, drinking, and smoking should be prohibited in areas where this material is handled, stored, and processed. Do not breathe gas. Do not get in eyes, on skin, on clothing. Use only with adequate ventilation. SDS US Propane 919503 Version 03 Revision date: 25-March-2015 Issue date: 05-May-2014 2 / 8 Page 948 of 1287 Page 948 of 1287 Page 948 of 1287 Page 948 of 1287 ---PAGE BREAK--- Conditions for safe storage, including any incompatibilities Store in accordance with local, regional, national, and international regulations. Secure cylinders in an upright position at all times, close all valves when not in use. Store in a cool, dry, well-ventilated place. Keep container closed and sealed until ready for use. Protect cylinders from damage. 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Type Components PEL 1800 mg/m3 Propane (CAS 74-98-6) 1000 ppm Value Type Additives Ceiling 25 mg/m3 Ethyl Mercaptan (CAS 75-08-1) 10 ppm US. ACGIH Threshold Limit Values Value Type Components STEL 1000 ppm Butane (CAS 106-97-8) TWA 500 ppm Propylene (CAS 115-07-1) Value Type Additives TWA 0.5 ppm Ethyl Mercaptan (CAS 75-08-1) US. NIOSH: Pocket Guide to Chemical Hazards Value Type Components TWA 1900 mg/m3 Butane (CAS 106-97-8) 800 ppm TWA 1800 mg/m3 Propane (CAS 74-98-6) 1000 ppm Value Type Additives Ceiling 1.3 mg/m3 Ethyl Mercaptan (CAS 75-08-1) 0.5 ppm Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering controls Provide adequate ventilation and minimize the risk of inhalation of gas. Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Individual protection measures, such as personal protective equipment Eye/face protection Wear approved safety glasses or goggles. Skin protection Hand protection Wear appropriate chemical resistant gloves. Other Wear protective clothing appropriate for the risk of exposure. Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Thermal hazards Contact with liquefied gas might cause frostbites, in some cases with tissue damage. Wear appropriate thermal protective clothing, when necessary. General hygiene considerations Do not eat, drink or smoke when using the product. Wash thoroughly after handling. Provide eyewash station and safety shower. Handle in accordance with good industrial hygiene and safety practices. 9. Physical and chemical properties Appearance Colorless gas. Physical state Gas. Form Compressed liquefied gas. Color Colorless. Odor Rotten egg. SDS US Propane 919503 Version 03 Revision date: 25-March-2015 Issue date: 05-May-2014 3 / 8 Page 949 of 1287 Page 949 of 1287 Page 949 of 1287 Page 949 of 1287 ---PAGE BREAK--- Odor threshold Not available. pH Not applicable. Melting point/freezing point -306.4 °F (-188 Initial boiling point and boiling range -43.6 °F (-42 14.7 psia Flash point -155.2 °F (-104.0 Evaporation rate Not applicable. Flammability (solid, gas) Extremely flammable gas. Upper/lower flammability or explosive limits Explosive limit - lower 2.15 % Explosive limit - upper 9.6 % Vapor pressure 127 psig (21°C / 70°F) Vapor density Not available. Relative density 0.504 (liquid) 1.5 (vapor) (air=1) @ 15°C / 60°F Solubility(ies) Solubility (water) soluble in water. Partition coefficient (n-octanol/water) 1.77 Auto-ignition temperature 809.6 °F (432 Decomposition temperature Not available. Viscosity Not applicable. Other information Molecular weight 45 g/mol Percent volatile 100 % 10. Stability and reactivity Reactivity Reacts violently with strong oxidants, nitrites, inorganic chlorides, chlorites and perchlorates causing fire and explosion hazard. Chemical stability Stable under normal temperature conditions and recommended use. Possibility of hazardous reactions Polymerization will not occur. Conditions to avoid Heat, flames and sparks. Incompatible materials Strong oxidizing agents. Strong acids. Halogens. Hazardous decomposition products Carbon oxides. Hydrocarbons. 11. Toxicological information Information on likely routes of exposure Ingestion Not likely, due to the form of the product. Inhalation High concentrations: Suffocation hazard - if allowed to accumulate to concentrations that reduce oxygen below safe breathing levels. Breathing of high concentrations may cause dizziness, light-headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness. Skin contact Contact with liquefied gas may cause frostbite. Eye contact Contact with liquefied gas may cause frostbite. related to the physical, chemical and toxicological characteristics Exposure to rapidly expanding gas or vaporizing liquid may cause frostbite ("cold burn"). Very high exposure can cause suffocation from lack of oxygen. May cause drowsiness or dizziness. Information on toxicological effects Acute toxicity High concentration: Suffocation hazard - if allowed to accumulate to concentrations that reduce oxygen below safe breathing levels. SDS US Propane 919503 Version 03 Revision date: 25-March-2015 Issue date: 05-May-2014 4 / 8 Page 950 of 1287 Page 950 of 1287 Page 950 of 1287 Page 950 of 1287 ---PAGE BREAK--- Test Results Components Species Butane (CAS 106-97-8) LC50 Mouse Inhalation Acute 680 mg/l, 2 Hours Rat 658 mg/l, 4 Hours Propane (CAS 74-98-6) LC50 Rat Inhalation Acute > 1442 mg/l, 15 Minutes Propylene (CAS 115-07-1) LC50 Mouse Inhalation Acute 680 mg/l, 2 Hours Rat 658 mg/l, 4 Hours Test Results Additives Species Ethyl Mercaptan (CAS 75-08-1) LD50 Rat Dermal Acute > 2000 mg/kg LC50 Mouse Inhalation 4420 mg/l, 4 Hours LD50 Rat Oral 682 mg/kg Skin corrosion/irritation Contact with liquefied gas might cause frostbites, in some cases with tissue damage. Serious eye damage/eye irritation Direct contact with liquefied gas may cause eye damage from frostbite. Respiratory or skin sensitization Respiratory sensitization Not classified. Skin sensitization Not classified. Germ cell mutagenicity Not classified. Carcinogenicity Not classified. IARC Monographs. Overall Evaluation of Carcinogenicity Propylene (CAS 115-07-1) 3 Not classifiable as to carcinogenicity to humans. Reproductive toxicity Not classified. Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not classified. 12. Ecological information Ecotoxicity Not expected to be harmful to aquatic organisms. Persistence and degradability The product is readily biodegradable. Bioaccumulative potential The product is not expected to bioaccumulate. Partition coefficient n-octanol / water (log Kow) Propane (CAS Mixture) 1.77 Butane (CAS 106-97-8) 2.89 Propane (CAS 74-98-6) 2.36 Propylene (CAS 115-07-1) 1.77 Mobility in soil May evaporate quickly. Mobility in general May evaporate quickly. SDS US Propane 919503 Version 03 Revision date: 25-March-2015 Issue date: 05-May-2014 5 / 8 Page 951 of 1287 Page 951 of 1287 Page 951 of 1287 Page 951 of 1287 ---PAGE BREAK--- Other adverse effects None known. 13. Disposal considerations Disposal instructions Use the container until empty. Do not dispose of any non-empty container. Empty containers have residual vapor that is flammable and explosive. Cylinders should be emptied and returned to a hazardous waste collection point. Do not puncture or incinerate even when empty. Dispose in accordance with all applicable regulations. Hazardous waste code D001: Waste Flammable material with a flash point <140 °F Waste from residues / unused products Dispose in accordance with all applicable regulations. Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT 2.1 Class UN number UN1075 UN proper shipping name Petroleum Gases, liquefied Transport hazard class(es) - Subsidiary risk Not applicable. Packing group No Marine pollutant Environmental hazards Read safety instructions, SDS and emergency procedures before handling. Special precautions for user 19, T50 Special provisions 306 Packaging exceptions 304 Packaging non bulk 314, 315 Packaging bulk IATA UN1075 UN number 2.1 Class UN proper shipping name Petroleum Gases, liquefied Transport hazard class(es) - Subsidiary risk 2.1 Label(s) Not applicable. Packing group No Environmental hazards 10L ERG Code Read safety instructions, SDS and emergency procedures before handling. Special precautions for user IMDG 2.1 Class UN number UN1075 UN proper shipping name Petroleum Gases, liquefied Transport hazard class(es) - Subsidiary risk 2.1 Label(s) Not applicable. Packing group No Marine pollutant Environmental hazards F-D, S-U EmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user This product is a compressed or liquefied gas and when transported in bulk is covered under IGC code. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. SDS US Propane 919503 Version 03 Revision date: 25-March-2015 Issue date: 05-May-2014 6 / 8 Page 952 of 1287 Page 952 of 1287 Page 952 of 1287 Page 952 of 1287 ---PAGE BREAK--- TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Butane (CAS 106-97-8) LISTED Ethyl Mercaptan (CAS 75-08-1) LISTED Propane (CAS 74-98-6) LISTED Propylene (CAS 115-07-1) LISTED Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical Yes SARA 313 (TRI reporting) Chemical name CAS number % by wt. Propylene 115-07-1 0-5 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Butane (CAS 106-97-8) Ethyl Mercaptan (CAS 75-08-1) Propane (CAS 74-98-6) Propylene (CAS 115-07-1) Clean Water Act (CWA) Section 112(r) (40 CFR 68.130) Hazardous substance Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. Massachusetts RTK - Substance List Butane (CAS 106-97-8) Ethyl Mercaptan (CAS 75-08-1) Propane (CAS 74-98-6) Propylene (CAS 115-07-1) US. New Jersey Worker and Community Right-to-Know Act Butane (CAS 106-97-8) Ethyl Mercaptan (CAS 75-08-1) Propane (CAS 74-98-6) Propylene (CAS 115-07-1) US. Worker and Community Right-to-Know Law Butane (CAS 106-97-8) Ethyl Mercaptan (CAS 75-08-1) Propane (CAS 74-98-6) Propylene (CAS 115-07-1) US. Rhode Island RTK Butane (CAS 106-97-8) Ethyl Mercaptan (CAS 75-08-1) Propane (CAS 74-98-6) Propylene (CAS 115-07-1) US. California Proposition 65 SDS US Propane 919503 Version 03 Revision date: 25-March-2015 Issue date: 05-May-2014 7 / 8 Page 953 of 1287 Page 953 of 1287 Page 953 of 1287 Page 953 of 1287 ---PAGE BREAK--- US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Not listed. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australian Inventory of Chemical Substances (AICS) Yes Australia Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No Canada Inventory of Existing Chemical Substances in China (IECSC) Yes China European Inventory of Existing Commercial Chemical Substances (EINECS) Yes Europe European List of Notified Chemical Substances (ELINCS) No Europe Inventory of Existing and New Chemical Substances (ENCS) Yes Japan Existing Chemicals List (ECL) Yes Korea New Zealand Inventory Yes New Zealand Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes Philippines *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Toxic Substances Control Act (TSCA) Inventory Yes United States & Puerto Rico 16. Other information, including date of preparation or last revision Issue date Revision date 05-May-2014 25-March-2015 Version # 03 NFPA Ratings 0 4 2 Disclaimer All information in this Material Safety Data Sheet is believed to be accurate and reliable. However, no guarantee or warranty of any kind is made with regard to the accuracy of information or the suitability of the recommendations contained herein. It is the user’s responsibility to assess the safety and toxicity of this product under their own conditions of use and to comply with all applicable laws and regulations. SDS US Propane 919503 Version 03 Revision date: 25-March-2015 Issue date: 05-May-2014 8 / 8 Page 954 of 1287 Page 954 of 1287 Page 954 of 1287 Page 954 of 1287 ---PAGE BREAK--- Page 955 of 1287 Page 955 of 1287 Page 955 of 1287 Page 955 of 1287 ---PAGE BREAK--- Page 956 of 1287 Page 956 of 1287 Page 956 of 1287 Page 956 of 1287 ---PAGE BREAK--- Page 957 of 1287 Page 957 of 1287 Page 957 of 1287 Page 957 of 1287 ---PAGE BREAK--- #93506, 93555 WINDSHIELD WASH - PURPLE POWER The information contained herein is based on current knowledge and experience; no responsibility is accepted that the information is sufficient or correct in all cases. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use and disposal of these materials and the safety and health of employees and customers and the protection of the environment. QUICK IDENTIFIER Common Name: (used on label and list) SECTION 2 - HAZARDOUS INGREDIENTS/IDENTITY 3 - 3 - 0 HEALTH FLAMMABILITY H F R REACTIVITY PERSONAL PROTECTION Style NC-L503R SECTION 1 - GENERAL INFORMATION Address Signature of Person Responsible for Preparation (Optional) City, State, and ZIP Name Emergency Telephone No. Other Information Calls Date Prepared ZECOL PRODUCTS COMPANY MEDINA, MN 55340 4635 WILLOW DRIVE (CHEM-TEL) 1-[PHONE REDACTED] (763) 478-3438 JAN 1, 2002 (REV) SECTION 4 - FIRE & EXPLOSION DATA Hazardous Component(s) [chemical & common name(s)] OSHA PEL ACGIH TLV SKIN STEL CAS ppm ppm ppm mg/m3 mg/m3 NO. *Methanol 200TWA 200TWA 250 260 310 67-56-1 Water ND ND NA NA NA NA Proprietary ingredients ND ND NA NA NA NA Appearance and Odor Solubility in Water Boiling Point SECTION 3 - PHYSICAL & CHEMICAL CHARACTERISTICS 148o F. - 212o F. 100% Purple, non-irritating alcohol odor. Specific Gravity (H2O=1) Auto-Ignition Temperature Flash Point Unusual Fire and Explosion Hazards 84o - 90oF. NA Special Fire Fight- ing Procedure Cool fire-exposed containers with water. Do not enter confined fire space without proper protective equipment including NIOSH-approved self-contained breathing apparatus. None Method Used TCC Extinguisher Media Carbon dioxide, dry chemical, foam. Flammable Limits in Air % by Volume LEL Lower 5.5 UEL Upper 36.5 3 3 0 Evaporation Rate (N-Butyl Acetate=1) Vapor Density (Air=1) Vapor Pressure (mm Hg) .956 @ 60o F. < 1 41 @ 68o F. .9 *This ingredient is subject to the reporting requirements of SARA 313 Title III. May be used to comply with OSHA's Hazard Communication Standard, 29CFR1910.1200. Standard must be consulted for specific requirements. Material Safety Data Sheet ZECOL PRODUCTS COMPANY Page 958 of 1287 Page 958 of 1287 Page 958 of 1287 Page 958 of 1287 ---PAGE BREAK--- Other Precautions Precautions to be Taken in Handling and Storage SECTION 7 - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES Waste Disposal Methods (Consult federal, state, and local regulations) Respiratory Protection (Specify Type) SECTION 5 - PHYSICAL HAZARDS (REACTIVITY DATA) #93506, 93555 WINDSHIELD WASH - PURPLE POWER (cont.) Stability Unstable Stable Conditions to Avoid Incompatability (Materials to Avoid) None known. Hazardous Decomposition Products Carbon monoxide, carbon dioxide, and unidentified organics. Hazardous Polymerization May Occur Will Not Occur Conditions to Avoid SECTION 6 - HEALTH HAZARDS 1. Acute 2. Chronic Signs and of Exposure Medical Conditions Generally Aggravated by Exposure Headache, nausea, narcosis, vomiting, irritated eyes or mucous membranes, blindness, dry or defatted skin. NA Chemical Listed as Carcinogen or Potential Carcinogen Yes No OSHA Yes No I.A.R.C. Monographs Yes No National Toxicology Program ROUTES OF ENTRY 1. Inhalation Remove victim to fresh air. Provide oxygen if breathing is difficult. Give artificial respiration if not breathing. Get medical attention. 2. Eyes Flush eyes with water for at least 15 minutes. Get medical attention. 3. Skin Wash with soap and water. Remove contaminated clothing. If irritation persists, get medical attention. 4. Ingestion Induce vomiting if conscious. Consult a physician immediately. SECTION 8 - SPECIAL PROTECTION INFORMATION/CONTROL MEASURES Steps to be Taken in Case Material is Released or Spilled Keep container closed. Do not store near heat, sparks, flame, or oxidizing materials. Ground all containers when transferring liquid. Use nonsparking tools. Vapors are heavier than air and will collect in low places. Eliminate sources of ignition. Wear appropriate respirator and protective cothing. Large spill - dike and contain. Remove with vacuum trucks or pump to storage/salvage vessel. Small spill - soak up residue with noncombustible absorbent; place in drums for proper disposal. Flush area with water to remove traces of residue. Dispose of flush solutions in drums. Dispose of in an appropriate disposal facility in compliance with regulations. Refer to latest EPA or State Regulations regarding disposal. Keep out of surface waters and any watercourses or sewers entering or leading to surface waters. Protective Gloves Ventilation Other Protective Clothing or Equipment Work/Hygienic Practices Blindness, systemic poisoning. Eye, skin, respiratory and gastrointestinal irritant. Use explosion-proof ventilation to maintain vapor concentrations below the TLV. x x x x x Emergency and First Aid Procedures Use NIOSH-approved respirator if chance of overexposure. Yes Goggles and protective clothing to minimize skin contact and prevent eye contact. Avoid inhalation of vapors, personal contact with the product, and use near flame or heat. Use only DOT- approved containers. None known. T/C/D Page 959 of 1287 Page 959 of 1287 Page 959 of 1287 Page 959 of 1287 ---PAGE BREAK--- Page 960 of 1287 Page 960 of 1287 Page 960 of 1287 Page 960 of 1287 ---PAGE BREAK--- Page 961 of 1287 Page 961 of 1287 Page 961 of 1287 Page 961 of 1287 ---PAGE BREAK--- Page 962 of 1287 Page 962 of 1287 Page 962 of 1287 Page 962 of 1287 ---PAGE BREAK--- Material Safety Data Sheet Material Name: Quaker State Itasca 16:1 2-Cycle Engine Oil ID: ITA-018 Page 1 of 6 Issue Date: 06/05/98 Revision: 2.0001 Print Date: 03/04/99 * * * Section 1 - Chemical Product and Company Identification * * * Product Numbers: 13480 (24/8 OZ) Chemical Name: Complex Mixture Product Use: 2-Cycle Engine Oil Manufacturer Information Quaker State Corporation Phone: (800)562-5928 225 E. John Carpenter Freeway Irving, Texas 75062 Emergency # (800)424-9300 CHEMTREC General Comments CHEMTREC Emergency telephone number is to be used in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals. All non-emergency questions should be directed to customer service. * * * Section 2 - Composition / Information on Ingredients * * * CAS # Component Percent 64742-47-8 Petroleum Distillates, Hydrotreated Light 12 64742-62-7 Residual Oils (petroleum), Solvent Dewaxed < 10 64742-57-0 Residual Oils (petroleum), Hydrotreated < 10 Not Available # 01154100-5013P < 5 Not Available # 01154100-5030P < 5 Not Available # 01154100-5031P < 5 64741-88-4 Petroleum Distillates, Solvent-refined Heavy Paraffinic < 5 64742-65-0 Petroleum Distillates, Solvent Dewaxed Heavy Paraffinic Blend 64742-54-7 Petroleum Distillates, Hydrotreated Heavy Paraffinic Blend Component Information/Information on Non-Hazardous Components The maximum percentage of the petroleum distillate and/or residual oil blend contained in this product is: 78% The manufacturer has claimed one or more ingredients as trade secret under the OSHA Hazard Communication Standard. All mineral oils used in this product have been severely hydrotreated and/or solvent refined. This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication). This product contains trace levels of xylene (1330- 20-7) and ethyl benzene (100-41-4). * * * Section 3 - Hazards Identification * * * Emergency Overview Product is a non-flammable petroleum distillate mixture. Liquid and vapor may be irritating to the eyes, skin and respiratory system. Irritating and toxic vapors may be released upon combustion of product. Extinguish fire with carbon dioxide, dry chemical, foam or water fog. Hazard Statements Not available. Potential Health Effects: Eyes This product is irritating to the eyes. Potential Health Effects: Skin This product may cause irritation to the skin. Prolonged and/or repeated skin contact with this product may cause irritation / dermatitis. Prolonged or repeated contact may result in allergic skin sensitization reactions. Potential Health Effects: Ingestion No significant adverse effects are expected upon ingestion of the product. Ingestion of this product may cause nausea, vomiting and diarrhea. Small amounts of this product, if aspirated into the lungs, may cause mild to severe pulmonary injury, possibly death. Page 963 of 1287 Page 963 of 1287 Page 963 of 1287 Page 963 of 1287 ---PAGE BREAK--- Material Safety Data Sheet Material Name: Quaker State Itasca 16:1 2-Cycle Engine Oil ID: ITA-018 Page 2 of 6 Issue Date: 06/05/98 Revision: 2.0001 Print Date: 03/04/99 Potential Health Effects: Inhalation Low vapor pressure makes inhalation unlikely at standard temperatures and pressures. High vapor/aerosol concentrations are irritating to the eyes and respiratory tract, and may cause headaches, dizziness, anesthesia, drowsiness, unconsciousness, and other central nervous system effects, including death. Repeated and prolonged overexposure to oil mists may result in droplet deposition, oil granuloma formation, inflammation and increased incidence of infection. HMIS Ratings: Health: 1 Fire: 1 Reactivity: 0 Pers. Prot.: safety glasses, gloves Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard * * * Section 4 - First Aid Measures * * * First Aid: Eyes Flush eyes with large amounts of water for 15 minutes. Seek medical attention if eye irritation develops or persists. First Aid: Skin Remove contaminated clothing. For skin contact, wash immediately with soap and water. Get medical attention if skin disorder develops. Launder contaminated clothing before reuse. First Aid: Ingestion Do not induce vomiting. Call your local poison control center or get medical attention. First Aid: Inhalation If affected, remove individual to fresh air. If not breathing, give mouth to mouth resuscitation. Seek medical attention if persist. First Aid: Notes to Physician Pulmonary aspiration hazard if swallowed; treat * * * Section 5 - Fire Fighting Measures * * * Flash Point: 206 F (97 C) Method Used: Cleveland Open Cup (COC) Upper Flammable Limit (UFL): Not available Lower Flammable Limit (LFL): Not available Auto Ignition: Not available Flammability Classification: Non-flammable Rate of Burning: Not available General Fire Hazards Product is a non-flammable petroleum distillate mixture. Liquid can burn upon heating to temperatures at or above the flash point. Mist or sprays may be flammable below the products normal flash point. Hazardous Combustion Products Upon decomposition this product may yield fumes, smoke, sulfur oxides, nitrogen oxides, aldehydes, carbon monoxide, carbon dioxide and other low molecular weight hydrocarbons. Extinguishing Media Use water spray, dry chemical, foam or carbon dioxide to extinguish the fire. Use water to cool fire-exposed containers and to protect personnel. Direct water spray or foam may cause frothing and spattering. If a leak or spill has not ignited, use water spray to disperse vapors and to flush spills away from exposure. Fire Fighting Equipment/Instructions Firefighters should wear full-face, self contained breathing apparatus and impervious protective clothing. Firefighters should avoid inhaling any combustion products. NFPA Ratings: Health: 1 Fire: 1 Reactivity: 0 Other: Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * * * Section 6 - Accidental Release Measures * * * Containment Procedures Stop the flow of material, if this is without risk. Clean-Up Procedures Absorb the spilled material with an inert absorbent (nonflammable) material. Scoop up used absorbent into drums or other appropriate container. Evacuation Procedures Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Page 964 of 1287 Page 964 of 1287 Page 964 of 1287 Page 964 of 1287 ---PAGE BREAK--- Material Safety Data Sheet Material Name: Quaker State Itasca 16:1 2-Cycle Engine Oil ID: ITA-018 Page 3 of 6 Issue Date: 06/05/98 Revision: 2.0001 Print Date: 03/04/99 Special Procedures Eliminate all sources of ignition or flammables that may come into contact with a spill of this material. Surfaces may become slippery after spillage. Wear appropriate protective equipment and clothing during clean-up. Do not allow the spilled product to enter public drainage systems or open water courses. * * * Section 7 - Handling and Storage * * * Handling Procedures Avoid breathing mists or vapors. Avoid prolonged or repeated skin contact with this material. Avoid the generation of oil mists. Wash thoroughly after handling. Use this product with adequate ventilation. Storage Procedures Do not store near heat, sparks, open flame or strong oxidizing agents. Do not store this material in open or unlabeled containers. "Empty" containers retain product residue (liquid and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition; they may explode. * * * Section 8 - Exposure Controls / Personal Protection * * * Exposure Guidelines A: General Product Information If oil mists are generated, observe the OSHA exposure limit of 5 mg/m3; short term exposure limit of 10 mg/m3. B: Component Exposure Limits ACGIH, OSHA, and NIOSH have not developed exposure limits for any of this product's components. Engineering Controls Use general ventilation and use local exhaust, where possible, in confined or enclosed spaces. Additional area ventilation or local exhaust may be required to maintain air concentrations below recommended exposure limits. PERSONAL PROTECTIVE EQUIPMENT Personal Protective Equipment: Eyes/Face Wear safety glasses with side shields. Wear chemical goggles or faceshield if splash or mist occurs. Personal Protective Equipment: Skin Use impervious gloves for prolonged contact. Wear oil-impervious garments if contact is unavoidable. Personal Protective Equipment: Respiratory If mist is generated (heating, spraying) and engineering controls are not sufficient, wear approved organic vapor respirator suitable for oil mist. Personal Protective Equipment: General Use good hygiene when handling petroleum product. Launder contaminated clothing before reuse. Excessive misting may cause slippery floors - wear appropriate footwear. Eye wash fountains are recommended. * * * Section 9 - Physical & Chemical Properties * * * Appearance: Red Odor: Mild petroleum Physical State: Liquid pH: Not available Vapor Pressure: Not available Vapor Density: Not available Boiling Point: Not available Melting Point: Not applicable Solubility (H2O): Negligible Specific Gravity: Not available Freezing Point: Not available Viscosity: 60.4 cSt @ 40 C; 8.70 cSt @ 100 C Percent Volatile: Negligible Physical Properties: Additional Information Pour Point: 10 F; -12 C * * * Section 10 - Chemical Stability & Reactivity Information * * * Chemical Stability Stable Page 965 of 1287 Page 965 of 1287 Page 965 of 1287 Page 965 of 1287 ---PAGE BREAK--- Material Safety Data Sheet Material Name: Quaker State Itasca 16:1 2-Cycle Engine Oil ID: ITA-018 Page 4 of 6 Issue Date: 06/05/98 Revision: 2.0001 Print Date: 03/04/99 Chemical Stability: Conditions to Avoid Avoid formation of mists. Incompatibility This product may react with strong oxidizing agents. Hazardous Decomposition Decomposition may produce sulfur oxides, nitrogen oxides, aldehydes, carbon monoxide, carbon dioxide and other low molecular weight hydrocarbons. Hazardous Polymerization Hazardous polymerization will not occur. * * * Section 11 - Toxicological Information * * * Acute Toxicity A: General Product Information Product may be irritating to the eyes, skin, and respiratory system. Excessive inhalation of mists/fumes may cause central nervous system depression; pulmonary aspiration hazard if swallowed. B: Component Analysis - LD50/LC50 Petroleum Distillates, Hydrotreated Heavy Paraffinic (64742-54-7) RTECS: PY8035500 Oral LD50 Rat: >15 gm/kg Dermal LD50 Rabbit: >5 gm/kg RTECS: PY8035501 Oral LD50 Rat: >15 gm/kg Dermal LD50 Rabbit: >5 gm/kg Carcinogenicity A: General Product Information No data available on the product as a whole. Note that USED oils tend to contain higher amounts of the cancer-causing aromatics, which have been linked to scrotal and lung cancer in humans. B: Component Carcinogenicity None of this product's components are listed by ACGIH, IARC, OSHA, NIOSH, or NTP. Epidemiology No data available for product. Neurotoxicity No data available on this product as a whole. Mutagenicity No data available on this product as a whole. Teratogenicity No data available on this product as a whole. Other Toxicological Information This product contains a blend of petroleum distillates and residual oils, all of which have been solvent refined or severely hydrotreated. The petroleum distillate and residual oil blend consists of one or more of the components identified by CAS Number in Section 2. Since these components vary with the availability of materials their presence is noted as "blend". * * * Section 12 - Ecological Information * * * Ecotoxicity No information is available on ecotoxicity of this product. Environmental Fate No information is available. Keep product out of sewers and waterways. * * * Section 13 - Disposal Considerations * * * US EPA Waste Number & Descriptions A: General Product Information Product as shipped does not meet the definition or characteristics of a hazardous waste. B: Component Waste Numbers No EPA Waste Numbers are applicable for this product's components. Page 966 of 1287 Page 966 of 1287 Page 966 of 1287 Page 966 of 1287 ---PAGE BREAK--- Material Safety Data Sheet Material Name: Quaker State Itasca 16:1 2-Cycle Engine Oil ID: ITA-018 Page 5 of 6 Issue Date: 06/05/98 Revision: 2.0001 Print Date: 03/04/99 Disposal Instructions All wastes must be handled in accordance with local, state and federal regulations. Do not allow this material to drain into sewers/water supplies. Material should be recycled if possible. * * * Section 14 - Transportation Information * * * US DOT Information Shipping Name: Not regulated as a hazardous material. Hazard Class: None UN/NA None Packing Group: None Required Label(s): None Additional Info.: None International Transportation Regulations Not regulated as dangerous goods. * * * Section 15 - Regulatory Information * * * US Federal Regulations A: General Product Information This product may be classified as an oil under Section 311 of the Clean Water Act, and under the Oil Pollution Act. Discharges of spills into or leading to surface waters that cause sheen must be reported to the National Response Center. (1-[PHONE REDACTED]) All components of this product are listed on the U.S. EPA TSCA Inventory. B: Component Analysis None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix SARA Section 313 (40 CFR 372.65), or CERCLA (40 CFR 302.4). State Regulations A: General Product Information Other state regulations may apply. B: Component Analysis - State None of this product's components are listed on the state lists from CA, FL, MA, MN, NJ, or PA. Other Regulations A: General Product Information No other information available. B: Component Analysis - Inventory Component CAS # TSCA DSL EINECS Petroleum Distillates, Hydrotreated Light 64742-47-8 Yes Yes Yes Residual Oils (petroleum), Hydrotreated 64742-57-0 Yes Yes Yes Residual Oils (petroleum), Solvent Dewaxed 64742-62-7 Yes Yes Yes Petroleum Distillates, Solvent-refined Heavy Paraffinic 64741-88-4 Yes Yes Yes Petroleum Distillates, Solvent Dewaxed Heavy Paraffinic 64742-65-0 Yes Yes Yes Petroleum Distillates, Hydrotreated Heavy Paraffinic 64742-54-7 Yes Yes Yes C: Component Analysis - WHMIS IDL No components are listed in the WHMIS IDL. * * * Section 16 - Other Information * * * Other Information This information is, to the best of Quaker State Corporation's knowledge and belief, accurate and reliable. However, no representation, warranty, or guarantee is made to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitableness and completeness of such information for his own particular use. Page 967 of 1287 Page 967 of 1287 Page 967 of 1287 Page 967 of 1287 ---PAGE BREAK--- Material Safety Data Sheet Material Name: Quaker State Itasca 16:1 2-Cycle Engine Oil ID: ITA-018 Page 6 of 6 Issue Date: 06/05/98 Revision: 2.0001 Print Date: 03/04/99 Key/Legend N = No; Y = Yes; ppm - parts per million; mg/m3 = milligrams per cubic meter of air; ACGIH = American Conference of Governmental Industrial Hygienists; OSHA = Occupational Safety and Health Administration; TLV = Threshold Limit Value; NIOSH = National Institute of Occupational Safety and Health; NTP = National Toxicology Program; IARC = International Agency for Research on Cancer. = New Jersey Trade Secret Registry NA = Not Applicable; ND = Not Determined. MSDS History Preparation Information: New MSDS 01/21/1997. Revision 2.0000: 11/19/1997. Revision 2.0000: Section 2 was revised to indicate that the product contains a "blend" of petroleum distillates and/or residual oils. Section 11 revised to the nature of the product blend. Revision (06/05/98): Text correction. Contact: Vince Bernard, Corporate Safety Director Contact Phone: (800) 562-5928 This is the end of MSDS # ITA-018 Page 968 of 1287 Page 968 of 1287 Page 968 of 1287 Page 968 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Regulare Clear Cement Product identifier Other means of identification 1100EB Product code Part Numbers: 31016RB, 31958RB, 31960RB, 31961RB, 31959RB Synonyms Joining PVC Pipes Recommended use None known. Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Company Name Oatey Co. Address 4700 West 160th St. Cleveland, OH 44135 Telephone [PHONE REDACTED] E-mail [EMAIL REDACTED] Transport Emergency Chemtrec 1-[PHONE REDACTED] (Outside the US 1-[PHONE REDACTED]) Emergency First Aid 1-[PHONE REDACTED] Contact person MSDS Coordinator 2. Hazard(s) identification Category 2 Flammable liquids Physical hazards Category 4 Acute toxicity, oral Health hazards Category 2 Skin corrosion/irritation Category 2A Serious eye damage/eye irritation Category 3 respiratory tract irritation Specific target organ toxicity, single exposure Category 3 narcotic effects Specific target organ toxicity, single exposure Category 1 Aspiration hazard Not classified. OSHA defined hazards Label elements Signal word Danger Hazard statement Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Response If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use appropriate media to extinguish. Regulare Clear Cement SDS US 927338 Version 01 Revision date: - Issue date: 05-28-2015 1 / 10 Page 969 of 1287 Page 969 of 1287 Page 969 of 1287 Page 969 of 1287 ---PAGE BREAK--- Storage Store in a well-ventilated place. Keep container closed. Keep cool. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. May form explosive peroxides. Contains a chemical classified by the US EPA as a suspected possible carcinogen. Supplemental information Not applicable. 3. Composition/information on ingredients Mixtures 109-99-9 40-60 Furan, Tetrahydro- CAS number % Chemical name 67-64-1 10-25 Acetone 9002-86-2 12-20 Polyvinyl chloride 108-94-1 5-15 Cyclohexanone 78-93-3 5-15 Methyl ethyl ketone *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Inhalation Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Eye contact Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may cause pulmonary edema and pneumonitis. Ingestion Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Skin irritation. May cause redness and pain. Most important acute and delayed Provide general supportive measures and treat Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. may be delayed. Indication of immediate medical attention and special treatment needed Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. General information 5. Fire-fighting measures Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2). Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Unsuitable extinguishing media Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Special protective equipment and precautions for firefighters In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Specific methods Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive organic peroxide when exposed to air or light or with age. General fire hazards Regulare Clear Cement SDS US 927338 Version 01 Revision date: - Issue date: 05-28-2015 2 / 10 Page 970 of 1287 Page 970 of 1287 Page 970 of 1287 Page 970 of 1287 ---PAGE BREAK--- 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid discharge into drains, water courses or onto the ground. Environmental precautions 7. Handling and storage Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof general and local exhaust ventilation. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Precautions for safe handling Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in a cool, dry place out of direct sunlight. Store in original closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Value Type Components STEL 5 ppm Polyvinyl chloride (CAS 9002-86-2) TWA 1 ppm US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Type Form Components PEL 2400 mg/m3 Acetone (CAS 67-64-1) 1000 ppm PEL 200 mg/m3 Cyclohexanone (CAS 108-94-1) 50 ppm PEL 590 mg/m3 Furan, Tetrahydro- (CAS 109-99-9) 200 ppm PEL 590 mg/m3 Methyl ethyl ketone (CAS 78-93-3) 200 ppm PEL 5 mg/m3 Respirable fraction. Polyvinyl chloride (CAS 9002-86-2) 15 mg/m3 Total dust. Regulare Clear Cement SDS US 927338 Version 01 Revision date: - Issue date: 05-28-2015 3 / 10 Page 971 of 1287 Page 971 of 1287 Page 971 of 1287 Page 971 of 1287 ---PAGE BREAK--- US. ACGIH Threshold Limit Values Value Type Form Components STEL 750 ppm Acetone (CAS 67-64-1) TWA 500 ppm STEL 50 ppm Cyclohexanone (CAS 108-94-1) TWA 20 ppm STEL 100 ppm Furan, Tetrahydro- (CAS 109-99-9) TWA 50 ppm STEL 300 ppm Methyl ethyl ketone (CAS 78-93-3) TWA 200 ppm TWA 1 mg/m3 Respirable fraction. Polyvinyl chloride (CAS 9002-86-2) US. NIOSH: Pocket Guide to Chemical Hazards Value Type Components TWA 590 mg/m3 Acetone (CAS 67-64-1) 250 ppm TWA 100 mg/m3 Cyclohexanone (CAS 108-94-1) 25 ppm STEL 735 mg/m3 Furan, Tetrahydro- (CAS 109-99-9) 250 ppm TWA 590 mg/m3 200 ppm STEL 885 mg/m3 Methyl ethyl ketone (CAS 78-93-3) 300 ppm TWA 590 mg/m3 200 ppm Biological limit values ACGIH Biological Exposure Indices Value Sampling Time Determinant Specimen Components 50 mg/l Acetone Urine * Acetone (CAS 67-64-1) 80 mg/l 1,2-Cyclohexan ediol, with hydrolysis Urine * Cyclohexanone (CAS 108-94-1) 8 mg/l Cyclohexanol, with hydrolysis Urine * 2 mg/l Tetrahydrofura n Urine * Furan, Tetrahydro- (CAS 109-99-9) 2 mg/l MEK Urine * Methyl ethyl ketone (CAS 78-93-3) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies Cyclohexanone (CAS 108-94-1) Skin designation applies. US - Tennessee OELs: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. Furan, Tetrahydro- (CAS 109-99-9) Can be absorbed through the skin. US. NIOSH: Pocket Guide to Chemical Hazards Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. Regulare Clear Cement SDS US 927338 Version 01 Revision date: - Issue date: 05-28-2015 4 / 10 Page 972 of 1287 Page 972 of 1287 Page 972 of 1287 Page 972 of 1287 ---PAGE BREAK--- Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Appropriate engineering controls Individual protection measures, such as personal protective equipment Face shield is recommended. Wear safety glasses with side shields (or goggles). Eye/face protection Skin protection Wear appropriate chemical resistant gloves. Hand protection Wear appropriate chemical resistant clothing. Other If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Respiratory protection Wear appropriate thermal protective clothing, when necessary. Thermal hazards When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Appearance Liquid. Physical state Opaque liquid. Form Gray. Color Solvent. Odor Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 151 °F (66.11 Flash point -4.0 °F (-20.0 Evaporation rate 5.5 - 8 Not available. Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower 1.8 Flammability limit - upper 11.8 Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 145 mm Hg @ 20 C Vapor density 2.5 Relative density 0.9 0.02 Solubility(ies) Solubility (water) Negligible Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity 80 - 500 cP Other information VOC (Weight 488 g/l SCAQMD 1168/M316A 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Reactivity Regulare Clear Cement SDS US 927338 Version 01 Revision date: - Issue date: 05-28-2015 5 / 10 Page 973 of 1287 Page 973 of 1287 Page 973 of 1287 Page 973 of 1287 ---PAGE BREAK--- Material is stable under normal conditions. Chemical stability No dangerous reaction known under conditions of normal use. Possibility of hazardous reactions Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Conditions to avoid Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics. Incompatible materials No hazardous decomposition products are known. Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation May be fatal if swallowed and enters airways. Headache. Nausea, vomiting. May cause irritation to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. Skin contact Causes skin irritation. Eye contact Causes serious eye irritation. Ingestion May be fatal if swallowed and enters airways. Harmful if swallowed. Harmful if swallowed. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. related to the physical, chemical and toxicological characteristics Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause redness and pain. of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Information on toxicological effects Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation. Test Results Components Species Acetone (CAS 67-64-1) LD50 Rabbit Dermal Acute 20 ml/kg LC50 Rat Inhalation 50 mg/l, 8 Hours LD50 Rat Oral 5800 mg/kg Cyclohexanone (CAS 108-94-1) LD50 Rabbit Dermal Acute 948 mg/kg LC50 Rat Inhalation 8000 ppm, 4 hours LD50 Rat Oral 1540 mg/kg * Estimates for product may be based on additional component data not shown. Causes skin irritation. Skin corrosion/irritation Causes serious eye irritation. Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not available. This product is not expected to cause skin sensitization. Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Regulare Clear Cement SDS US 927338 Version 01 Revision date: - Issue date: 05-28-2015 6 / 10 Page 974 of 1287 Page 974 of 1287 Page 974 of 1287 Page 974 of 1287 ---PAGE BREAK--- Carcinogenicity In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalation lifetime study on THF conducted by NTP (1998). Male rats developed renal tumors and female mice developed liver tumors while neither the female rats nor the male mice showed similar results. Because the carcinogenic mechanisms could not be identified clearly in either species for either tumor, the EPA determined that the male rat and female mouse findings are relevant to the assessment of carcinogenic potential in humans. Therefore, the IRIS review concludes that these data in aggregate indicate that there is "suggestive evidence of carcinogenic potential" following exposure to THF by all routes of exposure. IARC Monographs. Overall Evaluation of Carcinogenicity Cyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans. Polyvinyl chloride (CAS 9002-86-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Polyvinyl chloride (CAS 9002-86-2) Cancer This product is not expected to cause reproductive or developmental effects. Reproductive toxicity Specific target organ toxicity - single exposure Narcotic effects. May cause drowsiness and dizziness. Respiratory tract irritation. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard May be fatal if swallowed and enters airways. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Ecotoxicity Components Test Results Species Acetone (CAS 67-64-1) Aquatic LC50 Fish > 100 mg/l, 96 hours Fathead minnow (Pimephales promelas) * Estimates for product may be based on additional component data not shown. Cyclohexanone (CAS 108-94-1) Aquatic LC50 Fish 481 - 578 mg/l, 96 hours Fathead minnow (Pimephales promelas) No data is available on the degradability of this product. Persistence and degradability No data available. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Acetone (CAS 67-64-1) -0.24 Cyclohexanone (CAS 108-94-1) 0.81 Furan, Tetrahydro- (CAS 109-99-9) 0.46 Methyl ethyl ketone (CAS 78-93-3) 0.29 No data available. Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations. Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Contaminated packaging Regulare Clear Cement SDS US 927338 Version 01 Revision date: - Issue date: 05-28-2015 7 / 10 Page 975 of 1287 Page 975 of 1287 Page 975 of 1287 Page 975 of 1287 ---PAGE BREAK--- 14. Transport information DOT UN1993 UN number Flammable liquids, n.o.s. (Methyl ethyl ketone RQ = 37202 LBS, Acetone RQ = 37397 LBS) UN proper shipping name 3 Class Transport hazard class(es) - Subsidiary risk 3 Label(s) II Packing group Read safety instructions, SDS and emergency procedures before handling. Special precautions for user IB2, T7, TP1, TP8, TP28 Special provisions 150 Packaging exceptions 202 Packaging non bulk 242 Packaging bulk IATA UN1993 UN number Flammable liquid, n.o.s. (Methyl ethyl ketone, Acetone) UN proper shipping name 3 Class Transport hazard class(es) - Subsidiary risk II Packing group No. Environmental hazards 3H ERG Code Read safety instructions, SDS and emergency procedures before handling. Special precautions for user IMDG UN1993 UN number FLAMMABLE LIQUID, N.O.S. (Methyl ethyl ketone, Acetone) UN proper shipping name 3 Class Transport hazard class(es) - Subsidiary risk II Packing group No. Marine pollutant Environmental hazards F-E, S-E EmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Not available. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Polyvinyl chloride (CAS 9002-86-2) Cancer Central nervous system Liver Blood Flammability CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1) LISTED Cyclohexanone (CAS 108-94-1) LISTED Furan, Tetrahydro- (CAS 109-99-9) LISTED Methyl ethyl ketone (CAS 78-93-3) LISTED Regulare Clear Cement SDS US 927338 Version 01 Revision date: - Issue date: 05-28-2015 8 / 10 Page 976 of 1287 Page 976 of 1287 Page 976 of 1287 Page 976 of 1287 ---PAGE BREAK--- Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Hazard categories SARA 302 Extremely hazardous substance Not listed. No SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated. Safe Drinking Water Act (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1) 6532 Methyl ethyl ketone (CAS 78-93-3) 6714 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1) 35 %WV Methyl ethyl ketone (CAS 78-93-3) 35 %WV DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1) 6532 Methyl ethyl ketone (CAS 78-93-3) 6714 US state regulations US. Massachusetts RTK - Substance List Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. New Jersey Worker and Community Right-to-Know Act Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) Polyvinyl chloride (CAS 9002-86-2) US. Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. Rhode Island RTK Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Domestic Substances List (DSL) Yes Canada Regulare Clear Cement SDS US 927338 Version 01 Revision date: - Issue date: 05-28-2015 9 / 10 Page 977 of 1287 Page 977 of 1287 Page 977 of 1287 Page 977 of 1287 ---PAGE BREAK--- Country(s) or region Inventory name On inventory (yes/no)* *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Toxic Substances Control Act (TSCA) Inventory No United States & Puerto Rico 16. Other information, including date of preparation or last revision 05-28-2015 Issue date - Revision date Version # 01 Health: 2 Flammability: 3 Physical hazard: 0 HMIS® ratings NFPA ratings 0 2 3 The information in the sheet was written based on the best knowledge and experience currently available. Oatey Co. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. Disclaimer Regulare Clear Cement SDS US 927338 Version 01 Revision date: - Issue date: 05-28-2015 10 / 10 Page 978 of 1287 Page 978 of 1287 Page 978 of 1287 Page 978 of 1287 ---PAGE BREAK--- Retinax Grease CMX 2 MSDS# 400918EDA Version 3.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 1/10 Print Date 07/03/2014 000000003892 MSDS_US 1. MATERIAL AND COMPANY IDENTIFICATION Material Name : Retinax Grease CMX 2 Product Code : 001B1502 Uses : Automotive and industrial grease. Manufacturer/Supplier : Shell Oil Products US P.O. Box 4427 Houston TX 77210-4427 USA SDS Request : [PHONE REDACTED] Emergency Telephone Number Spill Information : [PHONE REDACTED] Health Information : [PHONE REDACTED] 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Identity CAS No. Concentration Molybdenum disulphide 1317-33-5 1.00 - 5.00 % Tris[bis(2- S,S'] antimony 15991-76-1 1.00 - 5.00 % A lubricating grease consisting of highly-refined mineral oil and additives. The highly refined mineral oil contains (w/w) DMSO-extract, according to IP346. 3. HAZARDS IDENTIFICATION Emergency Overview Appearance and Odour : Dark grey. Semi-solid at room temperature. Slight hydrocarbon. Health Hazards : High-pressure injection under the skin may cause serious damage including local necrosis. Safety Hazards : Not classified as flammable but will burn. Environmental Hazards : Not classified as dangerous for the environment. Health Hazards : Not expected to be a health hazard when used under normal conditions. Health Hazards Inhalation : Under normal conditions of use, this is not expected to be a primary route of exposure. Skin Contact : Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Eye Contact : May cause slight irritation to eyes. Ingestion : Low toxicity if swallowed. Page 979 of 1287 Page 979 of 1287 Page 979 of 1287 Page 979 of 1287 ---PAGE BREAK--- Retinax Grease CMX 2 MSDS# 400918EDA Version 3.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 2/10 Print Date 07/03/2014 000000003892 MSDS_US Other Information : High-pressure injection under the skin may cause serious damage including local necrosis. Used grease may contain harmful impurities. Signs and : Local necrosis is evidenced by delayed onset of pain and tissue damage a few hours following injection. Oil acne/folliculitis signs and may include formation of black pustules and spots on the skin of exposed areas. Ingestion may result in nausea, vomiting and/or diarrhoea. Aggravated Medical Conditions : Pre-existing medical conditions of the following organ(s) or organ system(s) may be aggravated by exposure to this material: Skin. Environmental Hazards : Not classified as dangerous for the environment. Additional Information : Under normal conditions of use or in a foreseeable emergency, this product does not meet the definition of a hazardous chemical when evaluated according to the OSHA Hazard Communication Standard, 29 CFR 1910.1200. 4. FIRST-AID MEASURES General Information : Not expected to be a health hazard when used under normal conditions. Inhalation : No treatment necessary under normal conditions of use. If persist, obtain medical advice. Skin Contact : Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention. When using high pressure equipment, injection of product under the skin can occur. If high pressure injuries occur, the casualty should be sent immediately to a hospital. Do not wait for to develop. Obtain medical attention even in the absence of apparent wounds. Eye Contact : Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention. Ingestion : In general no treatment is necessary unless large quantities are swallowed, however, get medical advice. Advice to Physician : Treat High pressure injection injuries require prompt surgical intervention and possibly steroid therapy, to minimise tissue damage and loss of function. Because entry wounds are small and do not reflect the seriousness of the underlying damage, surgical exploration to determine the extent of involvement may be necessary. Local anaesthetics or hot soaks should be avoided because they can contribute to swelling, vasospasm and ischaemia. Prompt surgical decompression, debridement and evacuation of foreign material should be performed under general anaesthetics, and wide exploration is essential. 5. FIRE-FIGHTING MEASURES Clear fire area of all non-emergency personnel. Page 980 of 1287 Page 980 of 1287 Page 980 of 1287 Page 980 of 1287 ---PAGE BREAK--- Retinax Grease CMX 2 MSDS# 400918EDA Version 3.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 3/10 Print Date 07/03/2014 000000003892 MSDS_US Flash point : 260 °C / 500 °F (Cleveland Open Cup) Upper / lower Flammability or Explosion limits : Typical 1 - 10 %(V)(based on mineral oil) Auto ignition temperature : > 320 °C / 608 °F Specific Hazards : Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide may be evolved if incomplete combustion occurs. Unidentified organic and inorganic compounds. Suitable Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media : Do not use water in a jet. Protective Equipment for Firefighters : Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space. 6. ACCIDENTAL RELEASE MEASURES Avoid contact with spilled or released material. For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on disposal. Observe the relevant local and international regulations. Protective measures : Avoid contact with skin and eyes. Use appropriate containment to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Clean Up Methods : Shovel into a suitable clearly marked container for disposal or reclamation in accordance with local regulations. 7. HANDLING AND STORAGE General Precautions : Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Use the information in this data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling vapour and/or mists. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Storage : Keep container closed and in a cool, well-ventilated place. Use properly labelled and closeable containers. Store at ambient temperature. Recommended Materials : For containers or container linings, use mild steel or high density polyethylene. Unsuitable Materials : PVC. Additional Information : Polyethylene containers should not be exposed to high temperatures because of possible risk of distortion. Page 981 of 1287 Page 981 of 1287 Page 981 of 1287 Page 981 of 1287 ---PAGE BREAK--- Retinax Grease CMX 2 MSDS# 400918EDA Version 3.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 4/10 Print Date 07/03/2014 000000003892 MSDS_US 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Material Source Type ppm mg/m3 Notation Molybdenu m disulphide ACGIH TWA(Inhalabl e fraction.) 10 mg/m3 as Mo Molybdenu m disulphide ACGIH TWA(Respira ble fraction.) 3 mg/m3 as Mo Molybdenu m disulphide OSHA Z1 PEL(Total dust.) 15 mg/m3 as Mo Molybdenu m disulphide OSHA Z1 (Total dust.) Listed.as Mo Tris[bis(2- dithiocarba mato-S,S'] antimony ACGIH TWA 0.5 mg/m3 as Sb Tris[bis(2- dithiocarba mato-S,S'] antimony OSHA Z1 PEL 0.5 mg/m3 as Sb Oil mist, mineral ACGIH TWA(Inhalabl e fraction.) 5 mg/m3 Oil mist, mineral OSHA Z1 PEL(Mist.) 5 mg/m3 Additional Information : Due to the product's semi-solid consistency, generation of mists and dusts is unlikely to occur. Biological Exposure Index (BEI) No biological limit allocated. Exposure Controls : The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Adequate ventilation to control airborne concentrations. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated. Define procedures for safe handling and maintenance of Page 982 of 1287 Page 982 of 1287 Page 982 of 1287 Page 982 of 1287 ---PAGE BREAK--- Retinax Grease CMX 2 MSDS# 400918EDA Version 3.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 5/10 Print Date 07/03/2014 000000003892 MSDS_US controls. Educate and train workers in the hazards and control measures relevant to normal activities associated with this product. Ensure appropriate selection, testing and maintenance of equipment used to control exposure, e.g. personal protective equipment, local exhaust ventilation. Drain down system prior to equipment break-in or maintenance. Retain drain downs in sealed storage pending disposal or for subsequent recycle. Always observe good personal hygiene measures, such as washing hands after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. Personal Protective Equipment : Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers. Respiratory Protection : No respiratory protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid breathing of material. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. Select a filter suitable for combined particulate/organic gases and vapours [boiling point >65°C(149 Hand Protection : Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection: PVC, neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. For continuous contact we recommend gloves with breakthrough time of more than 240 minutes with preference for > 480 minutes where suitable gloves can be identified. For short-term/splash protection we recommend the same, but recognise that suitable gloves offering this level of protection may not be available and in this case a lower breakthrough time may be acceptable so long as appropriate maintenance and replacement regimes are followed. Glove thickness is not a good predictor of glove resistance to a chemical as it is dependent on the exact composition of the glove material. Glove thickness should be typically greater than 0.35 mm depending on the glove make and model. Page 983 of 1287 Page 983 of 1287 Page 983 of 1287 Page 983 of 1287 ---PAGE BREAK--- Retinax Grease CMX 2 MSDS# 400918EDA Version 3.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 6/10 Print Date 07/03/2014 000000003892 MSDS_US Eye Protection : Wear safety glasses or full face shield if splashes are likely to occur. Protective Clothing : Skin protection not ordinarily required beyond standard issue work clothes. Monitoring Methods : Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate. Validated exposure measurement methods should be applied by a competent person and samples analysed by an accredited laboratory. Examples of sources of recommended exposure measurement methods are given below or contact the supplier. Further national methods may be available. National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods http://www.cdc.gov/niosh/ Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods http://www.osha.gov/ Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances http://www.hse.gov.uk/ Institut für Deutschen Gesetzlichen Unfallversicherung (IFA), Germany. http://www.dguv.de/inhalt/index.jsp L'Institut National de Recherche et de Securité, (INRS), France http://www.inrs.fr/accueil Environmental Exposure Controls : Take appropriate measures to fulfil the requirements of relevant environmental protection legislation. Avoid contamination of the environment by following advice given in Chapter 6. If necessary, prevent undissolved material from being discharged to waste water. Waste water should be treated in a municipal or industrial waste water treatment plant before discharge to surface water. Local guidelines on emission limits for volatile substances must be observed for the discharge of exhaust air containing vapour. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Dark grey. Semi-solid at room temperature. Odour : Slight hydrocarbon. pH : Not applicable. Initial Boiling Point and Boiling Range : Data not available Dropping point : Typical 220 °C / 428 °F Flash point : 260 °C / 500 °F (Cleveland Open Cup) Upper / lower Flammability or Explosion limits : Typical 1 - 10 (based on mineral oil) Auto-ignition temperature : > 320 °C / 608 °F Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s)) Specific gravity : Typical 0.955 Page 984 of 1287 Page 984 of 1287 Page 984 of 1287 Page 984 of 1287 ---PAGE BREAK--- Retinax Grease CMX 2 MSDS# 400918EDA Version 3.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 7/10 Print Date 07/03/2014 000000003892 MSDS_US Density : Typical 911 g/cm3 Water solubility : Negligible. n-octanol/water partition coefficient (log Pow) : > 6 (based on information on similar products) Kinematic viscosity : Not applicable. Vapour density (air=1) : > 1 (estimated value(s)) Electrical conductivity : This material is not expected to be a static accumulator. Evaporation rate (nBuAc=1) : Data not available 10. STABILITY AND REACTIVITY Stability : Stable. Conditions to Avoid : Extremes of temperature and direct sunlight. Materials to Avoid : Strong oxidising agents. Hazardous Decomposition Products : Hazardous decomposition products are not expected to form during normal storage. 11. TOXICOLOGICAL INFORMATION Basis for Assessment : Information given is based on data on the components and the toxicology of similar products. Unless indicated otherwise, the data presented is representative of the product as a whole, rather than for individual component(s). Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal conditions of use. Skin Irritation : Expected to be irritating. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Eye Irritation : Expected to be irritating. Respiratory Irritation : Inhalation of vapours or mists may cause irritation. Sensitisation : Not expected to be a skin sensitiser. Repeated Dose Toxicity : Not expected to be a hazard. Mutagenicity : Not considered a mutagenic hazard. Carcinogenicity : Not expected to be carcinogenic. Product contains mineral oils of types shown to be non-carcinogenic in animal skin-painting studies. Highly refined mineral oils are not classified as carcinogenic by the International Agency for Research on Cancer (IARC). Distillates (petroleum), hydrotreated heavy paraffinic : GHS / CLP: No carcinogenicity classification Molybdenum disulphide : GHS / CLP: No carcinogenicity classification Hydroxystearic acid : GHS / CLP: No carcinogenicity classification Tris[bis(2- S,S'] antimony : GHS / CLP: No carcinogenicity classification Azelaic acid : GHS / CLP: No carcinogenicity classification Page 985 of 1287 Page 985 of 1287 Page 985 of 1287 Page 985 of 1287 ---PAGE BREAK--- Retinax Grease CMX 2 MSDS# 400918EDA Version 3.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 8/10 Print Date 07/03/2014 000000003892 MSDS_US Lithium hydroxide : GHS / CLP: No carcinogenicity classification Solvent naphtha (petroleum), light aromatic : GHS / CLP: No carcinogenicity classification Reproductive and Developmental Toxicity : Not expected to be a hazard. Additional Information : Used grease may contain harmful impurities that have accumulated during use. The concentration of such harmful impurities will depend on use and they may present risks to health and the environment on disposal. ALL used grease should be handled with caution and skin contact avoided as far as possible. High pressure injection of product into the skin may lead to local necrosis if the product is not surgically removed. 12. ECOLOGICAL INFORMATION Ecotoxicological data have not been determined specifically for this product. Information given is based on a knowledge of the components and the ecotoxicology of similar products. Unless indicated otherwise, the data presented is representative of the product as a whole, rather than for individual component(s). Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic organisms. Expected to be practically non toxic: LL/EL/IL50 > 100 mg/l (to aquatic organisms) LL/EL50 expressed as the nominal amount of product required to prepare aqueous test extract. Mineral oil is not expected to cause any chronic effects to aquatic organisms at concentrations less than 1 mg/l. Mobility : Semi-solid under most environmental conditions. If it enters soil, it will adsorb to soil particles and will not be mobile. Floats on water. Persistence/degradability : Expected to be not readily biodegradable. Major constituents are expected to be inherently biodegradable, but the product contains components that may persist in the environment. Bioaccumulation : Contains components with the potential to bioaccumulate. Other Adverse Effects : Product is a mixture of non-volatile components, which are not expected to be released to air in any significant quantities. Not expected to have ozone depletion potential, photochemical ozone creation potential or global warming potential. 13. DISPOSAL CONSIDERATIONS Material Disposal : Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations. Do not dispose into the environment, in drains or in water courses. Page 986 of 1287 Page 986 of 1287 Page 986 of 1287 Page 986 of 1287 ---PAGE BREAK--- Retinax Grease CMX 2 MSDS# 400918EDA Version 3.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 9/10 Print Date 07/03/2014 000000003892 MSDS_US Container Disposal : Dispose in accordance with prevailing regulations, preferably to a recognised collector or contractor. The competence of the collector or contractor should be established beforehand. Local Legislation : Disposal should be in accordance with applicable regional, national, and local laws and regulations. 14. TRANSPORT INFORMATION US Department of Transportation Classification (49CFR) This material is not subject to DOT regulations under 49 CFR Parts 171-180. IMDG This material is not classified as dangerous under IMDG regulations. IATA (Country variations may apply) This material is either not classified as dangerous under IATA regulations or needs to follow country specific requirements. 15. REGULATORY INFORMATION The regulatory information is not intended to be comprehensive. Other regulations may apply to this material. Federal Regulatory Status Notification Status DSL All components listed. EINECS All components listed. TSCA All components listed. Comprehensive Environmental Release, Compensation & Liability Act (CERCLA) Retinax Grease CMX 2 Reportable quantity: 40 lbs Tris[bis(2- antimony (15991-76-1) SARA Toxic Release Inventory (TRI) (313) Page 987 of 1287 Page 987 of 1287 Page 987 of 1287 Page 987 of 1287 ---PAGE BREAK--- Retinax Grease CMX 2 MSDS# 400918EDA Version 3.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 10/10 Print Date 07/03/2014 000000003892 MSDS_US Tris[bis(2- antimony (15991-76-1) 2.50% State Regulatory Status California Safe Drinking Water and Toxic Enforcement Act (Proposition 65) This material does not contain any chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. New Jersey Right-To-Know Chemical List antimony (15991-76-1) 2.50% Listed. 16. OTHER INFORMATION NFPA Rating (Health, Fire, Reactivity) : 0, 1, 0 SDS Version Number : 3.1 SDS Effective Date : 02/05/2014 SDS Revisions : A vertical bar in the left margin indicates an amendment from the previous version. SDS Regulation : The content and format of this MSDS is in accordance with the OSHA Hazard Communication Standard, 29 CFR 1910.1200. SDS Distribution : The information in this document should be made available to all who may handle the product. Disclaimer : The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of health, safety and environmental requirements only. No warranty or guarantee is expressed or implied regarding the accuracy of these data or the results to be obtained from the use of the product. Page 988 of 1287 Page 988 of 1287 Page 988 of 1287 Page 988 of 1287 ---PAGE BREAK--- RHOMA-SOL™ Safety Data Sheet Prepared Date: 5/22/2015 Print Date: 6/2/2015 Revision: 1 Page 1 of 5 www.rhomar.com SECTION 1: IDENTIFICATION Product Identifier Product Name Product Form Product Code RHOMA-SOL™ Liquid RH-625 Relevant identified uses of the substance or mixture: Specialty cleaner for removing tar, asphalt, graffiti, adhesives, etc. Details of the supplier of the safety data sheet Rhomar Industries, Inc. 2107 E. Rockhurst St. Springfield, MO 65802 USA T [PHONE REDACTED]; F [PHONE REDACTED] [EMAIL REDACTED] Emergency telephone number 1-[PHONE REDACTED] SECTION 2: HAZARDS IDENTIFICATION Classification: Skin Corrosion/Irritation (Category 2) Serious eye damage/eye irritation (Category 2) Hazard Statements: Harmful if swallowed Causes skin irritation Causes severe eye irritation Precautionary Statements Prevention: Wash face, hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Keep container closed. Contaminated clothing should not be allowed out of the workplace. Response: General: If exposed or concerned, get medical advice/attention. Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation occurs. Skin/Hair Contact: If skin irritation occurs, get medical advice/attention. Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Ingestion: Immediately call a Poison Center or doctor/physician. Do not induce vomiting. Rinse mouth. Storage: Store locked up in a cool, dry, well-ventilated place. Keep out of reach of children. Keep unused container closed and in upright position. Disposal: Dispose of contents/container to an approved waste disposal plant. Page 989 of 1287 Page 989 of 1287 Page 989 of 1287 Page 989 of 1287 ---PAGE BREAK--- Prepared Date: 5/22/2015 RHOMA‐SOL™ Page 2 of 5 Other Hazards: Very toxic to aquatic life SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Mixture Name CAS # Weight % D-Limonene 5989-27-5 65-75 2Butoxyethanol 111-76-2 10-20 Citrus Terpenes 68647-72-3 1-10 The balance of ingredients are not classified as hazardous to health or the environment. The specific chemical identity and/or exact percentage has been withheld as a trade secret. SECTION 4: FIRST-AID MEASURES First Aid Measures General Advice: If exposed or concerned, get medical advice/attention. Inhalation: Remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention if irritation occurs. Eye Contact: Immediately flush eyes thoroughly with water for at least 15 minutes. Seek medical attention. Ingestion: Drink 1-2 glasses of water and immediately all poison control center or doctor for treatment advice. Skin Contact: If on skin, wash with plenty of soap and water. Get medical attention if irritation occurs. Most Important and Effects, both Acute and Delayed Harmful if swallowed. May be harmful if absorbed through the skin. Irritation to skin and eyes. Irritation by inhalation. Prolonged or repeated exposure can cause drying, defatting, and dermatitis of skin. Absorption through skin contact may be hazardous. Indication of any Immediate Medical Attention and Special Treatment Needed Note to Physicians, Treat SECTION 5: FIRE-FIGHTING MEASURES Suitable Extinguishing Media Dry chemical, Carbon Dioxide, water spray fog, alcohol resistant foam Unsuitable Extinguishing Media Water spray may be inefficient Specific Hazards Arising from the Chemical Keep away from heat, sparks, and flame. Guard against spontaneous combustion of improperly discarded oily rags. Hazardous Combustion Products: Carbon monoxide, Carbon dioxide (CO2), Thermal decomposition can lead to release of irritation and toxic gasses and vapors. Sensitivity to Static Discharge: Take precautionary measures against static discharge. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved ore equivalent) and full protective gear. Firefighters should wear self-contained breathing apparatus. Smother to exclude air. Do not use water. Handle as an oil fire, Class B fire procedures. Page 990 of 1287 Page 990 of 1287 Page 990 of 1287 Page 990 of 1287 ---PAGE BREAK--- Prepared Date: 5/22/2015 RHOMA‐SOL™ Page 3 of 5 SECTION 6: ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures Personal Precautions Remove all sources of ignition. Evacuate personnel to safe areas. Ensure adequate ventilation, especially in confined areas. Use personal protective equipment as required. Keep people away from up wind of spill/leak. Pay attention to flashback. Take precautionary measures against static discharge. Environmental Precautions Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Do not flush into surface water or sanitary sewers. Methods and Material for Containment and Cleaning Up Prevent further leakage or spillage if safe to do so. Eliminate all ignition sources. Absorb spilled material with inert material such as sand or sawdust and sweep up. Do not hose spills down drains, sewers, or waterways. Keep in suitable, closed containers for disposal. SECTION 7: HANDLING AND STORAGE Precautions for Safe Handling Advice on Safe Handling Ensure adequate ventilation, especially in confined areas. Keep away from heat, sparks, flame and other sources of ignition (i.e. pilot lights, electric motors and static electricity). Take precautionary measures against static discharges. Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when handling this product. Wear protective gloves/protective clothing and eye/face protection. Ground/bond container and receiving equipment. Use non-sparking tools. Use explosion proof equipment. Wash face, hands, and any exposed skin thoroughly after handling. Guard against spontaneous combustion of improperly discarded oily rags. Conditions for Safe Storage, Including any Incompatibilities Storage Conditions Store locked up. Store away from incompatible materials. Store in a well ventilated area at temperature below 70°F. Keep container closed in an upright position. Incompatible Materials Strong oxidizing agents, acidic agents SECTON 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name CAS # ACGIH – TLV OSHA PEL NIOSH IDLH 2-Butoxyethanol 111-76-2 TWA: 20ppm 100mg/m³ TWA: 50ppm TWA: 240 mg/m³ (vacated)TWA: 25ppm (vacated) TWA: 120 mg/m³ (Vacated) S* S* IDLH: 700ppm TWA: 5ppm TWA: 24 mg/m³ Appropriate Engineering Controls Engineering Controls: Good general ventilation (local exhaust) should be sufficient, eyewash stations, showers. Individual Protection Measures, such as Personal Protective Equipment Eye/Face Protection: Splash proof chemical safety goggles. Skin and Body Protection: Oil resistant gloves, oil resistant apron. Respiratory Protection: Under normal circumstances, no protective equipment is needed. If vapor concentration becomes high, use NIOSH approved respirators. Page 991 of 1287 Page 991 of 1287 Page 991 of 1287 Page 991 of 1287 ---PAGE BREAK--- Prepared Date: 5/22/2015 RHOMA‐SOL™ Page 4 of 5 General Hygiene Considerations: Handle in accordance with good industrial hygiene and safety practice. Take off all contaminated clothing and wash it before reuse. Wash face, hands and any exposed skin thoroughly after handling. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Information on Basic Physical and Chemical Properties Physical State Liquid Color Orange pH Not an aqueous solution Melting Point/Freezing Point Not determined Boiling Point/Boiling Range Not determined Flash Point >115°F Evaporation Rate 0.2 (butyl acetate Flammability (Solid, Gas) N/A – Liquid Upper Flammable Limits Not determined Lower Flammable Limits Not determined Vapor Pressure Not determined Vapor Density Not determined Specific Gravity 0.863 Water Solubility Insoluble in water Partition Coefficient Not determined Auto-ignition Temperature Not determined Decomposition Temperature Not determined Kinematic Viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined Odor Citrus Odor Threshold Not determined Solubility in Other Solvents Not determined SECTION 10: STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing Hazardous Polymerization Not determined Conditions to Avoid Excessive heat, sparks and flames. Incompatible materials. Incompatible Materials Strong oxidizing agents, acidic agents. Hazardous Decomposition Products Carbon monoxide, Carbon dioxide (CO2). Smoke may be acrid and fumes irritating. SECTION 11: TOXICOLOGICAL INFORMATION Information on Likely Routes of Exposure Product Information Inhalation: Avoid breathing vapors or mist. Eye Contact: Causes severe eye irritation Skin Contact: Causes skin irritation. May be absorbed through skin contact. Ingestion: Do not taste or swallow. Harmful if swallowed. Page 992 of 1287 Page 992 of 1287 Page 992 of 1287 Page 992 of 1287 ---PAGE BREAK--- Prepared Date: 5/22/2015 RHOMA‐SOL™ Page 5 of 5 Chemical Name CAS # Oral LD50 Dermal LD50 Inhalation LC50 D-Limonene 5989-27-5 4400 mg/kg (Rat) >5 g/kg (Rabbit) 2-Butoxyethanol 111-76-2 745 mg/kg (Rat) 2000 mg/kg 9 (Rat) 1250 mg/kg (Rat) 3500 mg/kg (Mouse) 550ppm (Rat) 4 h 2.5 mg/l (Rat) 4 h Delayed and Immediate Effects as well as Chronic Effects from Short and Long-term Exposure Skin corrosion/Irritation: Causes skin irritation. Serious eye damage/eye irritation: Causes severe eye irritation. Carcinogenicity: This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP or OSHA classification. Aspiration Hazard: May be fatal if swallowed and enters airways. Numerical Measures of Toxicity: Product Information. SECTION 16: OTHER INFORMATION NFPA Ratings: Health: 2 Flammability 1 Instability 0 Special Hazards: Not determined HMIS Ratings: Health: 2 Flammability: 1 Reactivity: 0 Personal Protection: B The information herein is presented in good faith and believed to be correct as of the date hereof. However, the manufacturer makes no representation as to the completeness and accuracy thereof. Users must make their own determination as to the suitability of the product for their purposes prior to use. No representations or warranty’s, either express or implied of merchantability, fitness for a particular purpose or of any other nature with respect to the product or to the information herein is made hereunder. The manufacturer shall in no event be responsible for any damages of whatsoever nature directly or indirectly resulting from the publication or use of or reliance upon information contained herein. Page 993 of 1287 Page 993 of 1287 Page 993 of 1287 Page 993 of 1287 ---PAGE BREAK--- Rid Ox MATERIAL SAFETY DATA SHEET Finished Product Date-Issued: 01/10/2003 MSDS Ref. No: 2112-6S Date-Revised: 06/04/2004 Revision No: 1 Rid Ox 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Rid Ox PRODUCT DESCRIPTION: Connector Protector Enhancer PRODUCT CODE: 2112/CAN/EUR-6S MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS L.P. 1001 N.W. 1st Street P.O. Box 949 Amarillo, TX 79107 Contact: Chemtrec Product Stewardship: 1-[PHONE REDACTED] CHEMTREC CANUTEC: Emergency Phone: (800) 424-9300 (613) 996-6666 1-[PHONE REDACTED] 2. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name Wt.% CAS# EINECS# Distillates, petroleum, hydrotreated light 60 - 80 64742-47- 8 265-149- 8 1,1,1,2-Tetrafluoroethane (HFC-134a) 15 - 25 811-97-2 223770 Nitromethane <1 75-52-5 EEC LABEL SYMBOL AND CLASSIFICATION R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. EEC Harmful - "Xn" 3. HAZARDS IDENTIFICATION file:///CI/Documents%20and%20Settings/ebrown/Desktop/MSDS/80180at4.htm (1 of 6)6/21/2004 10:10:23 AM Page 994 of 1287 Page 994 of 1287 Page 994 of 1287 Page 994 of 1287 ---PAGE BREAK--- Rid Ox EMERGENCY OVERVIEW IMMEDIATE CONCERNS: Flammable liquid and vapor. POTENTIAL HEALTH EFFECTS EYES: Substance causes substantial eye irritation. SKIN: Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). INGESTION: Harmful if swallowed. INHALATION: High concentrations in immediate area can displace oxygen and can cause dizziness, unconsciousness, and possibly death with longer exposure. Keep people away from such vapors without self- contained breathing apparatus. SIGNS AND OF OVEREXPOSURE EYES: of overexposure include: stinging, tearing, redness and pain. INGESTION: For large amounts; abdominal pain, nausea and vomiting. 4. FIRST AID MEASURES EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical attention. SKIN: Wash with soap and water. Get medical attention if irritation develops or persists. INGESTION: Aspiration hazard. If swallowed, vomiting may occur spontaneously, but do not induce. If vomiting occurs, keep head below hips to prevent aspiration into lungs. Call a physician immediately. INHALATION: Remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical attention. 5. FIRE FIGHTING MEASURES FLASHPOINT AND METHOD: 44°C (111°F)TAG CC FLAMMABLE LIMITS: 1.4 to 9.3 GENERAL HAZARD: Flammable Liquid. Can release vapors that form explosive mixtures at temperatures at or above the flash point. EXTINGUISHING MEDIA: Use alcohol foam, carbon dioxide, or water spray when fighting fires involving this material. HAZARDOUS COMBUSTION PRODUCTS: Smoke, fumes and oxides of carbon. EXPLOSION HAZARDS: Vapors may form explosive mixture with air. FIRE FIGHTING EQUIPMENT: As in any fire, wear self-contained breathing apparatus pressure-demand, (MSHA/NIOSH approved or equivalent) and full protective gear. file:///CI/Documents%20and%20Settings/ebrown/Desktop/MSDS/80180at4.htm (2 of 6)6/21/2004 10:10:23 AM Page 995 of 1287 Page 995 of 1287 Page 995 of 1287 Page 995 of 1287 ---PAGE BREAK--- Rid Ox 6. ACCIDENTAL RELEASE MEASURES LARGE SPILL: -Implement cleanup procedures. -If in public area, keep public away and advise authorities. -Recover by pumping (use an explosion proof or hand pump) or with a suitable absorbent. GENERAL PROCEDURES: Dike area to contain spill. Take precautions as necessary to prevent contamination of ground and surface waters. Recover spilled material on adsorbent, such as sawdust or vermiculite, and sweep into closed containers for disposal. After all visible traces, including vapors, have been removed thoroughly wet vacuum the area. Do not flush to sewer. If area of spill is porous, remove as much contaminated earth, gravel, etc. as necessary and place in closed containers for disposal. 7. HANDLING AND STORAGE GENERAL PROCEDURES: Use only in a well ventilated area. STORAGE: Keep away from heat and flame. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES: OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200) EXPOSURE LIMITS OSHA PEL ACGIH TLV Supplier OEL ppm mg/m3 ppm mg/m3 ppm mg/m3 Distillates, petroleum, hydrotreated light TWA NL[1] NL NL NL NL NL STEL NL NL NL NL NL NL 1,1,1,2-Tetrafluoroethane (HFC-134a) TWA NE NE 1,000[2] OSHA TABLE COMMENTS: 1. NL 2. * (AEL)=Acceptable Exposure Limit as established by the manufacture ENGINEERING CONTROLS: Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear splash-proof goggles. SKIN: The glove(s) listed below may provide protection against permeation. Gloves of other chemically resistant materials may not provide adequate protection. Viton, Solvex, Butyl, Buna, Neoprene. file:///CI/Documents%20and%20Settings/ebrown/Desktop/MSDS/80180at4.htm (3 of 6)6/21/2004 10:10:23 AM Page 996 of 1287 Page 996 of 1287 Page 996 of 1287 Page 996 of 1287 ---PAGE BREAK--- Rid Ox RESPIRATORY: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Liquid COLOR: Pink/red. pH: Not Applicable PERCENT VOLATILE: 96 at 20°C (68°F) BOILING POINT: 149°C (300°F) SOLUBILITY IN WATER: Insoluble SPECIFIC GRAVITY: 0.79 (water=1) VISCOSITY: Not Applicable (VOC): 786 g/L (non-exempt VOC) 10. STABILITY AND REACTIVITY STABLE: YES HAZARDOUS POLYMERIZATION: NO CONDITIONS TO AVOID: Heat, flames, ignition sources, and incompatables. STABILITY: Stable. INCOMPATIBLE MATERIALS: Concentrated nitric and sulfuric acid mixtures, chloroform, alkalis, chlorine compounds, acids, potassium t-butoxide. 11. TOXICOLOGICAL INFORMATION EYE EFFECTS: Not Available SKIN EFFECTS: Not Available CARCINOGENICITY: IARC: NOT listed NTP: NOT listed OSHA: NOT listed 12. ECOLOGICAL INFORMATION ENVIRONMENTAL DATA: There is limited information available on the environmental fate and effects of this material. The primary environmental concern for release is the impact on aquatic and terrestrial species. Due care should be taken to avoid the accidental release of this material into the environment. file:///CI/Documents%20and%20Settings/ebrown/Desktop/MSDS/80180at4.htm (4 of 6)6/21/2004 10:10:23 AM Page 997 of 1287 Page 997 of 1287 Page 997 of 1287 Page 997 of 1287 ---PAGE BREAK--- Rid Ox 13. DISPOSAL CONSIDERATIONS GENERAL COMMENTS: Dispose of in a manner consistent with federal, state, and local regulations. 14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: CONSUMER COMMODITY ORM-D PRIMARY HAZARD CLASS/DIVISION: No classification UN/NA NUMBER: NA PACKING GROUP: NA AIR (ICAO/IATA) PROPER SHIPPING NAME: CONSUMER COMMODITY ID8000 PRIMARY HAZARD CLASS/DIVISION: 9 UN/NA NUMBER: ID8000 PACKING GROUP: NA IATA NOTE: Domestic shipments only. When shipping International contact shipping department. VESSEL (IMO/IMDG) PROPER SHIPPING NAME: AEROSOLS IN LIMITED QUANTITIES OF CLASS 2 PRIMARY HAZARD CLASS/DIVISION: 2.1 UN/NA NUMBER: UN1950 PACKING GROUP: NA IMDG NOTE: Page 2102 15. REGULATORY INFORMATION UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) 311/312 HAZARD CATEGORIES: FIRE: YES PRESSURE GENERATING: NO REACTIVITY: NO ACUTE: YES CHRONIC: YES CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT) CERCLA REGULATORY: None of the ingredients are CERCLA/Superfund hazardous chemicals. CERCLA RQ: 1000 Lbs. TSCA (TOXIC SUBSTANCE CONTROL ACT) TSCA STATUS: All components of this product are either listed or exempt from listing in the TSCA inventory. OSHA HAZARD COMM. RULE: Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. CANADA file:///CI/Documents%20and%20Settings/ebrown/Desktop/MSDS/80180at4.htm (5 of 6)6/21/2004 10:10:23 AM Page 998 of 1287 Page 998 of 1287 Page 998 of 1287 Page 998 of 1287 ---PAGE BREAK--- Rid Ox DOMESTIC SUBSTANCE LIST (INVENTORY): All components of this product are listed on the Canadian DSL. EUROPEAN COMMUNITY EEC LABEL SYMBOL AND CLASSIFICATION R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. EEC Harmful - "Xn" 16. OTHER INFORMATION APPROVED BY: Pierce A. Pillon TITLE: Chemist PREPARED BY: Steve Cook REVISION SUMMARY Revision 1 This MSDS replaces the January 10, 2003 MSDS. Any changes in information are as follows: In Section 9 Specific Gravity (Unit) In Section 15 EEC Risk Phrase Codes HMIS RATING HEALTH: 1 FLAMMABILITY: 2 PHYSICAL HAZARD: 0 PERSONAL PROTECTION: NFPA CODES 2 1 0 DATA SOURCES: Code of Federal Regulations (CFR) The Sigma-Aldrich Library of Regulatory and Safety Data OSHA Hazard Communication Standard (29CFR1910.1200) Various Federal, State and Local Regulations MANUFACTURER DISCLAIMER: To the best of our knowledge, the information contained herein is accurate. However, neither Tech Spray, L.P., or any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. file:///CI/Documents%20and%20Settings/ebrown/Desktop/MSDS/80180at4.htm (6 of 6)6/21/2004 10:10:23 AM Page 999 of 1287 Page 999 of 1287 Page 999 of 1287 Page 999 of 1287 ---PAGE BREAK--- Page 1/9 Safety Data Sheet According to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 2/26/2014 Revision: 2/26/2014 1 Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: Ronson Butane · CAS Number: 68476-86-8 · EC number: 270-705-8 · Index number: 649-203-00-1 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · 1.3 Details of the supplier of the Safety Data Sheet · Manufacturer/Supplier: Mydent International 80 Suffolk Court Hauppauge, NY 11788 [PHONE REDACTED] Fax: [PHONE REDACTED] · 1.4 Emergency telephone number: CHEMTREC (800) 424-9300 2 Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 flame Flam. Gas 1 H220 Extremely flammable gas. gas cylinder Press. Gas H280 Contains gas under pressure; may explode if heated. · Classification according to Directive 67/548/EEC or Directive 1999/45/EC Extremely flammable R12: Extremely flammable. Carc. Cat. 1, Muta. Cat. 2 · Information concerning particular hazards for human and environment: Not applicable. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The substance is classified and labelled according to the CLP regulation. (Contd. on page 2) 38.0.16 Page 1000 of 1287 Page 1000 of 1287 Page 1000 of 1287 Page 1000 of 1287 ---PAGE BREAK--- Page 2/9 Safety Data Sheet According to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 2/26/2014 Revision: 2/26/2014 4 0 Trade name: Ronson Butane · Hazard pictograms GHS02 GHS04 · Signal word Danger · Hazard statements H220 Extremely flammable gas. H280 Contains gas under pressure; may explode if heated. · Precautionary statements P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use. P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely. P381 Eliminate all ignition sources if safe to do so. P410+P403 Protect from sunlight. Store in a well-ventilated place. P403 Store in a well-ventilated place. · Hazard description: · WHMIS-symbols: A - Compressed gas B1 - Flammable gas · NFPA ratings (scale 0 - 4) (Contd. of page 1) Health = 0 Fire = 4 Reactivity = 0 · HMIS-ratings (scale 0 - 4) HEALTH FIRE 0 Health = 0 4 Fire = 4 REACTIVITY 0 Reactivity = 0 · HMIS Long Term Health Hazard Substances Substance is listed. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. (Contd. on page 3) 38.0.16 Page 1001 of 1287 Page 1001 of 1287 Page 1001 of 1287 Page 1001 of 1287 ---PAGE BREAK--- Page 3/9 Safety Data Sheet According to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 2/26/2014 Revision: 2/26/2014 Trade name: Ronson Butane (Contd. of page 2) 3 Composition/information on ingredients · 3.1 Substances · CAS No. Description 68476-86-8 Petroleum gases, liquefied, sweetened · Identification number(s) · EC number: 270-705-8 · Index number: 649-203-00-1 4 First aid measures · 4.1 Description of first aid measures · After inhalation: Supply fresh air; consult doctor in case of complaints. · After skin contact: Generally the product does not irritate the skin. Immediately rinse with water. If skin irritation continues, consult a doctor. · After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If persist, consult a doctor. · After swallowing: Unlikely route of exposure. Do not induce vomiting; call for medical help immediately. · 4.2 Most important and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · For safety reasons unsuitable extinguishing agents: W ater with full jet · 5.2 Special hazards arising from the substance or mixture No further relevant information available. · 5.3 Advice for firefighters · Protective equipment: W ear self-contained respiratory protective device. W ear fully protective suit. · Additional information Cool endangered receptacles with water spray. 6 Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures W ear protective equipment. Keep unprotected persons away. (Contd. on page 4) 38.0.16 Page 1002 of 1287 Page 1002 of 1287 Page 1002 of 1287 Page 1002 of 1287 ---PAGE BREAK--- Page 4/9 Safety Data Sheet According to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 2/26/2014 Revision: 2/26/2014 Trade name: Ronson Butane Ensure adequate ventilation Keep away from ignition sources. · 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water. · 6.3 Methods and material for containment and cleaning up: Allow to evaporate. · 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. (Contd. of page 3) 7 Handling and storage · 7.1 Precautions for safe handling Open and handle receptacle with care. · Information about fire - and explosion protection: Keep ignition sources away - Do not smoke. Protect from heat. Protect against electrostatic charges. · 7.2 Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Store in a cool location. · Information about storage in one common storage facility: Store away from oxidizing agents. · Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. Protect from heat and direct sunlight. · 7.3 Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection · Additional information about design of technical facilities: No further data; see item 7. · 8.1 Control parameters · Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of m aterials with critical values that have to be monitored at the workplace. · DNELs No further relevant information available. · PNECs No further relevant information available. · Additional information: The lists valid during the making were used as basis. · 8.2 Exposure controls · Personal protective equipment: · General protective and hygienic measures: W ash hands before breaks and at the end of work. · Respiratory protection: Use suitable respiratory protective device in case of insufficient ventilation. · Protection of hands: Not required. · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. (Contd. on page 5) 38.0.16 Page 1003 of 1287 Page 1003 of 1287 Page 1003 of 1287 Page 1003 of 1287 ---PAGE BREAK--- Page 5/9 Safety Data Sheet According to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 2/26/2014 Revision: 2/26/2014 Trade name: Ronson Butane · Penetration time of glove material (Contd. of page 4) The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Not required. · Body protection: Not required. · Limitation and supervision of exposure into the environment No further relevant information available. · Risk management measures See Section 7 for additional information. No further relevant information available. 9 Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Compressed liquefied gas Colour: Colourless · Odour: Odourless · Odour threshold: Not determined. · pH-value: Not determined. · Change in condition Melting point/Melting range: Not Determined. Boiling point/Boiling range: -24 °C · Flash point: -91 °C · Flammability (solid, gaseous): Not determined. · Auto/Self-ignition temperature: Decomposition temperature: Not determined. · Self-igniting: Not determined. · Danger of explosion: Product is not explosive. However, formation of explosive air/ vapour mixtures are possible. · Explosion limits: Lower: 1,8 Vol % Upper: 9,5 Vol % · Vapour pressure at 21 2814 hPa (2110 mm Hg)(estimado)) · Density at 20 0,56 g/cm³ · Relative density Not determined. · Vapour density at 20 °C 1,7237 (aire-1,0) · Evaporation rate Not applicable. (Contd. on page 6) 38.0.16 Page 1004 of 1287 Page 1004 of 1287 Page 1004 of 1287 Page 1004 of 1287 ---PAGE BREAK--- Page 6/9 Safety Data Sheet According to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 2/26/2014 Revision: 2/26/2014 Trade name: Ronson Butane · Solubility in / Miscibility with water: Not miscible or difficult to mix. · Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Not determined. Kinematic: Not determined. · 9.2 Other information No further relevant information available. (Contd. of page 5) 10 Stability and reactivity · 10.1 Reactivity · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. To avoid thermal decomposition do not overheat. · 10.3 Possibility of hazardous reactions Used empty containers may contain product gases which form explosive mixtures with air. Reacts with strong oxidizing agents. Danger of receptacles bursting because of high vapour pressure when heated. Can form explosive mixtures in air if heated above flash point and/or when sprayed or atomised. · 10.4 Conditions to avoid Keep ignition sources away - Do not smoke. Store away from oxidizing agents. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: Carbon monoxide and carbon dioxide 11 Toxicological information · 11.1 Information on toxicological effects · Acute toxicity: · Primary irritant effect: · on the skin: No irritant effect. · on the eye: No irritating effect. · Sensitization: No sensitizing effects known. 12 Ecological information · 12.1 Toxicity · Aquatic toxicity: No further relevant information available. · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential Does not accumulate in organisms. · 12.4 Mobility in soil No further relevant information available. (Contd. on page 7) 38.0.16 Page 1005 of 1287 Page 1005 of 1287 Page 1005 of 1287 Page 1005 of 1287 ---PAGE BREAK--- Page 7/9 Safety Data Sheet According to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 2/26/2014 Revision: 2/26/2014 Trade name: Ronson Butane · Additional ecological information: · General notes: Negative ecological effects are, according to the current state of knowledge, not expected. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. (Contd. of page 6) 13 Disposal considerations · 13.1 Waste treatment methods · Recommendation Can be burned with household garbage after consulting with the waste disposal facility operator and the pertinent authorities and adhering to the necessary technical regulations. · Uncleaned packaging: · Recommendation: Disposal must be made according to official regulations. · Recommended cleansing agents: W ater, if necessary together with cleansing agents. 14 Transport information · 14.1 UN-Number · DOT, ADR, IMDG, IATA UN1075 · 14.2 UN proper shipping name · DOT, IMDG, IATA PETROLEUM GASES, LIQUEFIED · ADR 1075 PETROLEUM GASES, LIQUEFIED · 14.3 Transport hazard class(es) · DOT · Class 2.1 · Label 2.1 · ADR · Class 2.1 F1 · Label 2.1 (Contd. on page 8) 38.0.16 Page 1006 of 1287 Page 1006 of 1287 Page 1006 of 1287 Page 1006 of 1287 ---PAGE BREAK--- Page 8/9 Safety Data Sheet According to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 2/26/2014 Revision: 2/26/2014 Trade name: Ronson Butane · IMDG, IATA (Contd. of page 7) · Class 2.1 · Label 2.1 · 14.4 Packing group · DOT, ADR, IMDG, IATA II · 14.5 Environmental hazards: · Marine pollutant: No · 14.6 Special precautions for user Not applicable. · 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional information: · ADR · Limited quantities (LQ) 0 · UN "Model Regulation": UN1075, PETROLEUM GASES, LIQUEFIED, 2.1, I 15 Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · United States (USA) · SARA · Section 355 (extremely hazardous substances): Substance is not listed. · Section 313 (Specific toxic chemical listings): Substance is not listed. · TSCA (Toxic Substances Control Act): Substance is listed. · Proposition 65 (California): · Chemicals known to cause cancer: Substance is not listed. · Chemicals known to cause reproductive toxicity for females: Substance is not listed. · Chemicals known to cause reproductive toxicity for males: Substance is not listed. · Chemicals known to cause developmental toxicity: Substance is not listed. (Contd. on page 9) 38.0.16 Page 1007 of 1287 Page 1007 of 1287 Page 1007 of 1287 Page 1007 of 1287 ---PAGE BREAK--- Page 9/9 Safety Data Sheet According to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 2/26/2014 Revision: 2/26/2014 Trade name: Ronson Butane · Carcinogenic Categories (Contd. of page 8) · EPA (Environmental Protection Agency) Substance is not listed. · IARC (International Agency for Research on Cancer) Substance is not listed. · TLV (Threshold Limit Value established by ACGIH) Substance is not listed. · NIOSH-Ca (National Institute for Occupational Safety and Health) Substance is not listed. · OSHA-Ca (Occupational Safety & Health Administration) Substance is not listed. · Canada · Canadian Domestic Substances List (DSL) Substance is listed. · Canadian Ingredient Disclosure list (limit 0.1%) Substance is not listed. · Canadian Ingredient Disclosure list (limit Substance is not listed. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) DNEL: Derived No-Effect Level (REACH) PNEC: Predicted No-Effect Concentration (REACH) Flam. Gas 1: Flammable gases, Hazard Category 1 Press. Gas: Gases under pressure: Compressed gas · Sources SDS Prepared by: Mydent International 80 Suffolk Court Hauppauge, NY 11788 [PHONE REDACTED] Fax: [PHONE REDACTED] 38.0.16 Page 1008 of 1287 Page 1008 of 1287 Page 1008 of 1287 Page 1008 of 1287 ---PAGE BREAK--- Material Safety Data Sheet ROTOROIL 8000F4 Version: 1.1 Revision Date: 05/21/2013 Print Date: 05/21/2013 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name: ROTOROIL 8000F4 Product Use Description: Lubricant Company: Mattei Compressors, Inc. 9635 Liberty Road, Suite E Randallstown, MD 21133 United States of America Telephone: [PHONE REDACTED] SECTION 2. HAZARDS IDENTIFICATION Emergency Overview CAUTION! Form: liquid Color: amber Odor: mild : Hazard Summary May cause eye and skin irritation. : OSHA Hazards THIS MATERIAL IS NOT HAZARDOUS UNDER THE CRITERIA OF THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD 29CFR 1910.1200. Potential Health Effects Primary Routes of Entry : Eye contact Skin contact 산Aggravated Medical : Skin disorders Aggravated Medical : Skin disorders Condition 1 / 8 Page 1009 of 1287 Page 1009 of 1287 Page 1009 of 1287 Page 1009 of 1287 ---PAGE BREAK--- Material Safety Data Sheet ROTOROIL 8000F4 Version: 1.1 Revision Date: 05/21/2013 Print Date: 05/21/2013 Inhalation : May cause respiratory tract irritation. Skin : May cause skin irritation. Prolonged or repeated contact may dry skin and cause irritation. Eyes : May cause eye irritation. Ingestion : May be harmful if swallowed. of Overexposure : No information available. Carcinogenicity: IARC No component of this product presents at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product presents at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP No component of this product presents at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. ACGIH No component of this product presents at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components No ingredients are hazardous according to HCS criteria. SECTION 4. FIRST AID MEASURES First aid procedures Inhalation : If inhaled Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of bluish discoloration (lips, ear lobes, fingernails), give oxygen as quickly as possible. If persist, call a physician. Skin contact : In case of skin contact Wash off with soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing before re-use. Get medical attention if irritation develops and persists. Eye contact : In case of eye contact Rinse thoroughly with plenty of water, also under the eyelids. If eye irritation persists, consult a specialist. Ingestion : If swallowed, DO NOT induces vomiting. Consult a physician if necessary. 2 / 8 Page 1010 of 1287 Page 1010 of 1287 Page 1010 of 1287 Page 1010 of 1287 ---PAGE BREAK--- Material Safety Data Sheet ROTOROIL 8000F4 Version: 1.1 Revision Date: 05/21/2013 Print Date: 05/21/2013 Notes to physician : No information available. Treatment : No information available. SECTION 5. FIRE-FIGHTING MEASURES Flammable properties Flash point : 480 °F (249 Method: Cleveland open cup ASTM D 92 Ignition temperature : Remarks: not determined Lower explosion limit : Remarks: no data available Upper explosion limit : Remarks: no data available Fire fighting Suitable extinguishing media : Carbon dioxide (CO2) Dry powder Foam Alcohol-resistant foam Water mist Unsuitable extinguishing media : Water Further information : In the event of fire, cool tanks with water spray. Protective equipment and precautions for firefighters Specific hazards during fire fighting Special protective equipment for fire-fighters : Burning produces noxious and toxic fumes. : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Use personal protective equipment. Ensure adequate ventilation. Environmental precautions : Should not be released into the environment. Do not contaminate water. Do not flush into surface water or sanitary sewer system. Methods for containment / Methods for cleaning up : Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Additional advice : Forms slippery/greasy layers with water. 3 / 8 Page 1011 of 1287 Page 1011 of 1287 Page 1011 of 1287 Page 1011 of 1287 ---PAGE BREAK--- Material Safety Data Sheet ROTOROIL 8000F4 Version: 1.1 Revision Date: 05/21/2013 Print Date: 05/21/2013 SECTION 7. HANDLING AND STORAGE Handling Handling procedures : Handle in accordance with good industrial hygiene and safety practice. Keep container closed when not in use. Do not use pressure to empty drums. Ensure all equipment is electrically grounded before beginning transfer operations. Storage Requirements for storage areas and containers : Keep container closed in a dry and well-ventilated place. Other data : Stable under recommended storage conditions. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Engineering measures Personal protective equipment Eye protection : Safety glasses with side-shields fitting safety goggles Hand protection : Neoprene gloves Skin and body protection : impervious clothing Respiratory protection : Breathing apparatus needed only when aerosol or mist is formed. In the case of vapor formation use a respirator with an approved filter. Hygiene measures : Avoid contact with skin, eyes and clothing. Provide adequate ventilation. Do not breathe dust or spray mist. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form : liquid Color : amber Odor : mild 4 / 8 Page 1012 of 1287 Page 1012 of 1287 Page 1012 of 1287 Page 1012 of 1287 ---PAGE BREAK--- Material Safety Data Sheet ROTOROIL 8000F4 Version: 1.1 Revision Date: 05/21/2013 Print Date: 05/21/2013 Safety data Flash point : 480 °F (249 Method: Cleveland open cup ASTM D 92 Ignition temperature : Remarks: not determined Lower explosion limit : Note: no data available Upper explosion limit : Note: no data available pH : Note: not applicable Vapor pressure : Note: no data available Density : 0.91 g/cm3 Water solubility : Note: soluble SECTION 10. STABILITY AND REACTIVITY Conditions to avoid : Remarks: Heat. Materials to avoid : Remarks: Strong acids and strong bases Hazardous decomposition products : Note: Carbon oxides Hazardous reactions : Hazardous polymerization does not occur. SECTION 11. TOXICOLOGICAL INFORMATION Acute inhalation toxicity : Remarks: Not classified due to lack of data. Acute dermal toxicity : Remarks: Not classified due to lack of data. Skin irritation : Remarks: Not classified due to lack of data. Eye irritation : Remarks: Not classified due to lack of data. Sensitization : Remarks: Not classified due to lack of data. Toxicology Assessment CMR effects : Carcinogenicity: Not classified due to lack of data. Mutagenicity: 5 / 8 Page 1013 of 1287 Page 1013 of 1287 Page 1013 of 1287 Page 1013 of 1287 ---PAGE BREAK--- Material Safety Data Sheet 6 / 9 SAP 6.0 SDS Number: 400000002039 ROTOROIL 8000F4 Version: 1.1 Revision Date: 05/21/2013 Print Date: 05/21/2013 Not classified due to lack of data. Reproductive toxicity: Not classified due to lack of data. Further information : There is no data available for this product. 12. ECOLOGICAL INFORMATION Eco toxicity effects Toxicity to fish : Remarks: No data available Toxicity to daphnia and other aquatic invertebrates. : Remarks: No data available Toxicity to algae : Remarks: No data available Elimination information (persistence and degradability) Bioaccumulation : Remarks: No data available Mobility : Remarks: No data available Biodegradability : Result: no data available Further information on ecology Ecotoxicology Assessment Results of PBT assessment This substance is not considered to be persistent, bio accumulating nor toxic (PBT). Additional ecological information : There is no data available for this product. SECTION 13. DISPOSAL CONSIDERATIONS Further information : In accordance with local and national regulations. Contaminated packaging : Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION DOT 6 / 8 Page 1014 of 1287 Page 1014 of 1287 Page 1014 of 1287 Page 1014 of 1287 ---PAGE BREAK--- Material Safety Data Sheet 7 / 9 SAP 6.0 SDS Number: 400000002039 ROTOROIL 8000F4 Version: 1.1 Revision Date: 05/21/2013 Print Date: 05/21/2013 Not dangerous goods TDG Not dangerous goods IATA Not dangerous goods IMDG Not dangerous goods RID Not dangerous goods SECTION 15. REGULATORY INFORMATION OSHA Hazards : This material is not hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200. CERCLA Reportable : Quantity SARA 302 Reportable : Quantity SARA 311/312 Hazards : No SARA Hazards EPCRA - EMERGENCY PLANNING COMMUNITY RIGHT - TO - KNOW SARA 304 Components : This material does not contain any components with a section 304 EHS RQ. California Prop. 65 Components : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: US.TSCA On TSCA Inventory DSL This product contains the following components that are not on the Canadian DSL nor NDSL lists. 7 / 8 Page 1015 of 1287 Page 1015 of 1287 Page 1015 of 1287 Page 1015 of 1287 ---PAGE BREAK--- Material Safety Data Sheet 8 / 9 SAP 6.0 SDS Number: 400000002039 ROTOROIL 8000F4 Version: 1.1 Revision Date: 05/21/2013 Print Date: 05/21/2013 AICS Not in compliance with the inventory NZIoC Not in compliance with the inventory ENCS KECI PICCS On the inventory, or in compliance with the inventory On the inventory, or in compliance with the inventory Not in compliance with the inventory IECSC Not in compliance with the inventory SECTION 16. OTHER INFORMATION Further information HMIS Classification : Health hazard: 1 Flammability: 1 Physical hazards: 0 NFPA Classification : Health hazard: 1 1 Fire Hazard: 1 Reactivity Hazard: 0 1 0 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, Transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 8 / 8 Page 1016 of 1287 Page 1016 of 1287 Page 1016 of 1287 Page 1016 of 1287 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON PROFESSIONAL™ GROUT CLEANER Version 1.0 Print Date 09/10/2010 Revision Date 09/03/2010 MSDS Number 350000015677 1/7 1. PRODUCT AND COMPANY IDENTIFICATION Product information Trade name : SC JOHNSON PROFESSIONAL™ GROUT CLEANER Use of the Substance/Mixture : Speciality Cleaner Company : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236 Emergency telephone number : 24 Hour Transport & Medical Emergency Phone (866) 231- 5406 24 Hour International Emergency Phone (952) 852-4647 2. HAZARDS IDENTIFICATION Emergency Overview Appearance / Odor : clear yellow / liquid / Bleach Immediate Concerns : Warning CAUSES EYE IRRITATION. CAUSES SKIN IRRITATION. Avoid contact with skin, eyes and clothing. Do not mix with acids or any other household products. May release dangerous gases (chlorine). Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion. Eyes : Causes: Severe eye irritation May cause permanent eye injury. Skin : Severe skin irritant Inhalation : May cause nose, throat, and lung irritation. Ingestion : May cause irritation to mouth, throat and stomach. May cause abdominal discomfort. Aggravated Medical Condition : Persons with pre-existing skin disorders may be more susceptible to irritating effects. Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, etc. may be more susceptible to irritating effects. Page 1017 of 1287 Page 1017 of 1287 Page 1017 of 1287 Page 1017 of 1287 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON PROFESSIONAL™ GROUT CLEANER Version 1.0 Print Date 09/10/2010 Revision Date 09/03/2010 MSDS Number 350000015677 2/7 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or the Canadian Controlled Products Regulations are listed in this table: Chemical Name CAS-No. Weight percent Sodium hypochlorite 7681-52-9 1.00 - 5.00 Sodium hydroxide 1310-73-2 1.00 - 5.00 For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Eye contact : Remove contact lenses. Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention immediately. Skin contact : Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention immediately. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Inhalation : Remove to fresh air. Ingestion : If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during fire fighting : Container may melt and leak in heat of fire. Further information : Fight fire with normal precautions from a reasonable distance. Standard procedure for chemical fires. Wear full protective clothing and positive pressure self-contained breathing apparatus. Flash point : > 93.4 °C > 200.12 °F Lower explosion limit : Note: no data available Upper explosion limit : Note: no data available Page 1018 of 1287 Page 1018 of 1287 Page 1018 of 1287 Page 1018 of 1287 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON PROFESSIONAL™ GROUT CLEANER Version 1.0 Print Date 09/10/2010 Revision Date 09/03/2010 MSDS Number 350000015677 3/7 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Wear personal protective equipment. Environmental precautions : Outside of normal use, avoid release to the environment. Methods for cleaning up : Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Dike large spills. Clean residue from spill site. 7. HANDLING AND STORAGE Handling Advice on safe handling : Avoid contact with skin, eyes and clothing. Avoid breathing vapors, mist or gas. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Advice on protection against fire and explosion : Normal measures for preventive fire protection. Storage Requirements for storage areas and containers : Keep container closed when not in use. Keep in a dry, cool and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Personal protective equipment Respiratory protection Industrial setting : Use only with adequate ventilation. Household setting : No special requirements. Hand protection : Wear suitable gloves. Eye protection Industrial setting : Wear splash-resistant Chemical goggles. Household setting : No special requirements. Page 1019 of 1287 Page 1019 of 1287 Page 1019 of 1287 Page 1019 of 1287 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON PROFESSIONAL™ GROUT CLEANER Version 1.0 Print Date 09/10/2010 Revision Date 09/03/2010 MSDS Number 350000015677 4/7 Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : liquid Color : clear yellow Odor : Bleach pH : 12.8 Boiling point : no data available Freezing point : no data available Flash point : > 93.4 °C > 200.12 °F Evaporation rate : no data available Autoignition temperature : no data available Lower explosion limit : no data available Upper explosion limit : no data available Density : 1.1 g/cm3 Water solubility : completely soluble 10. STABILITY AND REACTIVITY Conditions to avoid : Direct sources of heat. Materials to avoid : Do not mix with acids or any other household products. May release dangerous gases (chlorine). Avoid contact with: Ammonia compounds. Rust remover. Strong acids Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. Page 1020 of 1287 Page 1020 of 1287 Page 1020 of 1287 Page 1020 of 1287 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON PROFESSIONAL™ GROUT CLEANER Version 1.0 Print Date 09/10/2010 Revision Date 09/03/2010 MSDS Number 350000015677 5/7 Hazardous reactions : If accidental mixing occurs and toxic gas is formed, exit area immediately. Do not return until well ventilated. 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50 estimated > 5,000 mg/kg Acute inhalation toxicity : no data available Acute dermal toxicity : LD50 estimated > 2,000 mg/kg Chronic effects Carcinogenicity : no data available Mutagenicity : no data available Reproductive effects : no data available Teratogenicity : no data available Sensitisation : no data available 12. ECOLOGICAL INFORMATION Ecotoxicity effects : no data available 13. DISPOSAL CONSIDERATIONS Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle where facilities exist. Page 1021 of 1287 Page 1021 of 1287 Page 1021 of 1287 Page 1021 of 1287 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON PROFESSIONAL™ GROUT CLEANER Version 1.0 Print Date 09/10/2010 Revision Date 09/03/2010 MSDS Number 350000015677 6/7 14. TRANSPORT INFORMATION Please refer to the Bill of Lading/receiving documents for up-to-date shipping information. Land transport ƒ U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. Sea transport ƒ IMDG: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. Air transport ƒ ICAO/IATA: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. 15. REGULATORY INFORMATION Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Notification status : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA). California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65. 16. OTHER INFORMATION HMIS Ratings Health 2 Flammability 0 Reactivity 0 NFPA Ratings Page 1022 of 1287 Page 1022 of 1287 Page 1022 of 1287 Page 1022 of 1287 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON PROFESSIONAL™ GROUT CLEANER Version 1.0 Print Date 09/10/2010 Revision Date 09/03/2010 MSDS Number 350000015677 7/7 Health 2 Fire 0 Reactivity 0 Special Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by: SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 1023 of 1287 Page 1023 of 1287 Page 1023 of 1287 Page 1023 of 1287 ---PAGE BREAK--- Shell Donax TX Version 1.2 Effective Date 2015-02-10 Material Safety Data Sheet According to the Controlled Product Regulations 1/7 Print Date 2015-02-10 000000004804 MSDS_CA 1. MATERIAL AND COMPANY IDENTIFICATION Material Name : Shell Donax TX Uses : Transmission oil. Product Code : 001B4421 Manufacturer/Supplier : Shell Canada Products 400 - 4th Avenue S.W Calgary AB T2P 0J4 Canada Telephone : [PHONE REDACTED] Fax : [PHONE REDACTED] Emergency Telephone Number : CHEMTREC (24 hr): [PHONE REDACTED] CANUTEC (24 hr): [PHONE REDACTED] 2. COMPOSITION/INFORMATION ON INGREDIENTS Mixture Description : Highly refined mineral oils and additives. The highly refined mineral oil contains (w/w) DMSO-extract, according to IP346. Refer to Chapter 8 for Occupational Exposure Guidelines. 3. HAZARDS IDENTIFICATION WHMIS Class/Description : THIS PRODUCT IS NOT A WHMIS CONTROLLED SUBSTANCE. Routes of Exposure : Skin and eye contact are the primary routes of exposure although exposure may occur following accidental ingestion. Health Hazards : Not expected to be a health hazard when used under normal conditions. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Used oil may contain harmful impurities. Signs and : Oil acne/folliculitis signs and may include formation of black pustules and spots on the skin of exposed areas. Ingestion may result in nausea, vomiting and/or diarrhoea. Safety Hazards : Not classified as flammable but will burn. Environmental Hazards : Not classified as dangerous for the environment. 4. FIRST AID MEASURES General Information : Not expected to be a health hazard when used under normal conditions. Page 1024 of 1287 Page 1024 of 1287 Page 1024 of 1287 Page 1024 of 1287 ---PAGE BREAK--- Shell Donax TX Version 1.2 Effective Date 2015-02-10 Material Safety Data Sheet According to the Controlled Product Regulations 2/7 Print Date 2015-02-10 000000004804 MSDS_CA Inhalation : No treatment necessary under normal conditions of use. If persist, obtain medical advice. Skin Contact : Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention. Eye Contact : Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention. Ingestion : In general no treatment is necessary unless large quantities are swallowed, however, get medical advice. Advice to Physician : Treat 5. FIRE FIGHTING MEASURES Clear fire area of all non-emergency personnel. Flash point : Typical 205 °C / 401 °F (COC) Upper / lower Flammability or Explosion limits : Typical 1 - 10 %(V)(based on mineral oil) Auto ignition temperature : > 320 °C / 608 °F Hazardous Combustion Products and Specific Hazards : Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Suitable Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media : Do not use water in a jet. Protective Equipment for Firefighters : Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space. 6. ACCIDENTAL RELEASE MEASURES Protective Measures : Avoid contact with skin and eyes. Use appropriate containment to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately. Prevent from spreading by making a barrier with sand, earth or other containment material. Reclaim liquid directly or in an absorbent. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly. Additional Advice : Local authorities should be advised if significant spillages cannot be contained. 7. HANDLING AND STORAGE General Precautions : Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Use the information in this data sheet as input to a risk Page 1025 of 1287 Page 1025 of 1287 Page 1025 of 1287 Page 1025 of 1287 ---PAGE BREAK--- Shell Donax TX Version 1.2 Effective Date 2015-02-10 Material Safety Data Sheet According to the Controlled Product Regulations 3/7 Print Date 2015-02-10 000000004804 MSDS_CA assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling vapour and/or mists. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. Storage : Keep container closed and in a cool, well-ventilated place. Use properly labelled and closeable containers. Store at ambient temperature. Recommended Materials : For containers or container linings, use mild steel or high density polyethylene. Unsuitable Materials : PVC. Additional Information : Polyethylene containers should not be exposed to high temperatures because of possible risk of distortion. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION If the American Conference of Governmental Industrial Hygienists (ACGIH) value is provided on this document, it is provided for information only. Occupational Exposure Limits Material Source Type ppm mg/m3 Notation Oil mist, mineral ACGIH TWA(Inhala ble fraction.) 5 mg/m3 Consult local authorities for acceptable exposure limits within their jurisdiction. Exposure Controls : The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Adequate ventilation to control airborne concentrations. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated. Personal Protective Equipment : Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers. Respiratory Protection : No respiratory protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid breathing of material. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appropriate Page 1026 of 1287 Page 1026 of 1287 Page 1026 of 1287 Page 1026 of 1287 ---PAGE BREAK--- Shell Donax TX Version 1.2 Effective Date 2015-02-10 Material Safety Data Sheet According to the Controlled Product Regulations 4/7 Print Date 2015-02-10 000000004804 MSDS_CA combination of mask and filter. Select a filter suitable for combined particulate/organic gases and vapours [boiling point >65°C(149 Hand Protection : Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection: PVC, neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. Eye Protection : Wear safety glasses or full face shield if splashes are likely to occur. Protective Clothing : Skin protection not ordinarily required beyond standard issue work clothes. Monitoring Methods : Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate. Environmental Exposure Controls : Minimise release to the environment. An environmental assessment must be made to ensure compliance with local environmental legislation. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Amber. Liquid. Odour : Slight hydrocarbon. Odour threshold : Data not available pH : Not applicable. Initial Boiling Point and Boiling Range : > 280 °C / 536 °F estimated value(s) Pour point : Typical -39 °C / -38 °F Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s)) Specific gravity : Typical 0.882 at 15 °C / 59 °F Density : Typical 882 kg/m3 at 15 °C / 59 °F Water solubility : Negligible. n-octanol/water partition coefficient (log Pow) : > 6 (based on information on similar products) Kinematic viscosity : Typical 55.4 mm2/s at 40 °C / 104 °F Vapour density (air=1) : > 1 (estimated value(s)) Evaporation rate (nBuAc=1) : Data not available Page 1027 of 1287 Page 1027 of 1287 Page 1027 of 1287 Page 1027 of 1287 ---PAGE BREAK--- Shell Donax TX Version 1.2 Effective Date 2015-02-10 Material Safety Data Sheet According to the Controlled Product Regulations 5/7 Print Date 2015-02-10 000000004804 MSDS_CA 10. STABILITY AND REACTIVITY Stability : Stable. Conditions to Avoid : Extremes of temperature and direct sunlight. Materials to Avoid : Strong oxidising agents. Hazardous Decomposition Products : Hazardous decomposition products are not expected to form during normal storage. Hazardous Polymerisation : No Sensitivity to Mechanical Impact : No Sensitivity to Static Discharge : No 11. TOXICOLOGICAL INFORMATION Basis for Assessment : Information given is based on data on the components and the toxicology of similar products. Routes of Exposure : Skin and eye contact are the primary routes of exposure although exposure may occur following accidental ingestion. Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat. Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit. Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal conditions of use. Skin Irritation : Expected to be irritating. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Eye Irritation : Expected to be irritating. Respiratory Irritation : Inhalation of vapours or mists may cause irritation. Sensitisation : Not expected to be a skin sensitiser. Repeated Dose Toxicity : Not expected to be a hazard. Mutagenicity : Not considered a mutagenic hazard. Carcinogenicity : Product contains mineral oils of types shown to be non- carcinogenic in animal skin-painting studies. Highly refined mineral oils are not classified as carcinogenic by the International Agency for Research on Cancer (IARC). Other components are not known to be associated with carcinogenic effects. Reproductive and Developmental Toxicity : Not expected to be a hazard. Additional Information : Used oils may contain harmful impurities that have accumulated during use. The concentration of such impurities will depend on use and they may present risks to health and the environment on disposal. ALL used oil should be handled with caution and skin contact avoided as far as possible. Page 1028 of 1287 Page 1028 of 1287 Page 1028 of 1287 Page 1028 of 1287 ---PAGE BREAK--- Shell Donax TX Version 1.2 Effective Date 2015-02-10 Material Safety Data Sheet According to the Controlled Product Regulations 6/7 Print Date 2015-02-10 000000004804 MSDS_CA 12. ECOLOGICAL INFORMATION Ecotoxicological data have not been determined specifically for this product. Information given is based on a knowledge of the components and the ecotoxicology of similar products. Acute Toxicity : Poorly soluble mixture.May cause physical fouling of aquatic organisms.Expected to be practically non toxic:LL/EL/IL50 > 100 mg/l(to aquatic organisms)(LL/EL50 expressed as the nominal amount of product required to prepare aqueous test extract).Mineral oil is not expected to cause any chronic effects to aquatic organisms at concentrations less than 1 mg/l. Mobility : Liquid under most environmental conditions. Floats on water. If it enters soil, it will adsorb to soil particles and will not be mobile. Persistence/degradability : Expected to be not readily biodegradable. Major constituents are expected to be inherently biodegradable, but the product contains components that may persist in the environment. Bioaccumulation : Contains components with the potential to bioaccumulate. Other Adverse Effects : Product is a mixture of non-volatile components, which are not expected to be released to air in any significant quantities. Not expected to have ozone depletion potential, photochemical ozone creation potential or global warming potential. 13. DISPOSAL CONSIDERATIONS Material Disposal : Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations. Do not dispose into the environment, in drains or in water courses. Container Disposal : Dispose in accordance with prevailing regulations, preferably to a recognised collector or contractor. The competence of the collector or contractor should be established beforehand. Local Legislation : Disposal should be in accordance with applicable regional, national, and local laws and regulations. 14. TRANSPORT INFORMATION Canadian Road and Rail Shipping Classification This product is not regulated under the Canadian Transportation of Dangerous Goods Regulations for transport by road and rail. Page 1029 of 1287 Page 1029 of 1287 Page 1029 of 1287 Page 1029 of 1287 ---PAGE BREAK--- Shell Donax TX Version 1.2 Effective Date 2015-02-10 Material Safety Data Sheet According to the Controlled Product Regulations 7/7 Print Date 2015-02-10 000000004804 MSDS_CA 15. REGULATORY INFORMATION The regulatory information is not intended to be comprehensive. Other regulations may apply to this material. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Class/Description : THIS PRODUCT IS NOT A WHMIS CONTROLLED SUBSTANCE. Inventory Status EINECS : All components listed or polymer exempt. TSCA : All components listed. DSL : All components listed. 16. OTHER INFORMATION MSDS Version Number : 1.2 MSDS Effective Date : 2015-02-10 MSDS Revisions : A vertical bar in the left margin indicates an amendment from the previous version. MSDS Regulation : The content and format of this (M)SDS is in accordance with the Controlled Product Regulations. MSDS Prepared By : Shell Product Stewardship; 1-[PHONE REDACTED] MSDS Distribution : The information in this document should be made available to all who may handle the product. Disclaimer : The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of health, safety and environmental requirements only. No warranty or guarantee is expressed or implied regarding the accuracy of these data or the results to be obtained from the use of the product. Page 1030 of 1287 Page 1030 of 1287 Page 1030 of 1287 Page 1030 of 1287 ---PAGE BREAK--- Shell Morlina S4 B 220 MSDS# 18049DA Version 1.4 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 1/9 Print Date 07/03/2014 000000019939 MSDS_US 1. MATERIAL AND COMPANY IDENTIFICATION Material Name : Shell Morlina S4 B 220 Product Code : 001D7827 Uses : Gear lubricant. Manufacturer/Supplier : Shell Oil Products US P.O. Box 4427 Houston TX 77210-4427 USA SDS Request : [PHONE REDACTED] Emergency Telephone Number Spill Information : [PHONE REDACTED] Health Information : [PHONE REDACTED] 2. COMPOSITION/INFORMATION ON INGREDIENTS base oil and additives. Highly refined mineral oil. The highly refined mineral oil contains (w/w) DMSO-extract, according to IP346. Sensitiser not sufficient to classify : Contains 3-(Diisobutoxythiophosphorylsulfonyl)-2- acid. May produce an allergic reaction. 3. HAZARDS IDENTIFICATION Emergency Overview Appearance and Odour : Yellow. Liquid at room temperature. Slight hydrocarbon. Health Hazards : Not classified as dangerous for supply or conveyance. Safety Hazards : Not classified as flammable but will burn. Environmental Hazards : Not classified as dangerous for the environment. Health Hazards : Not expected to be a health hazard when used under normal conditions. Health Hazards Inhalation : Under normal conditions of use, this is not expected to be a primary route of exposure. Skin Contact : Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Eye Contact : May cause slight irritation to eyes. Ingestion : Low toxicity if swallowed. Other Information : Used oil may contain harmful impurities. Signs and : Oil acne/folliculitis signs and may include formation of black pustules and spots on the skin of exposed areas. Page 1031 of 1287 Page 1031 of 1287 Page 1031 of 1287 Page 1031 of 1287 ---PAGE BREAK--- Shell Morlina S4 B 220 MSDS# 18049DA Version 1.4 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 2/9 Print Date 07/03/2014 000000019939 MSDS_US Ingestion may result in nausea, vomiting and/or diarrhoea. Aggravated Medical Conditions : Pre-existing medical conditions of the following organ(s) or organ system(s) may be aggravated by exposure to this material: Skin. Environmental Hazards : Not classified as dangerous for the environment. Additional Information : Under normal conditions of use or in a foreseeable emergency, this product does not meet the definition of a hazardous chemical when evaluated according to the OSHA Hazard Communication Standard, 29 CFR 1910.1200. 4. FIRST-AID MEASURES General Information : Not expected to be a health hazard when used under normal conditions. Inhalation : No treatment necessary under normal conditions of use. If persist, obtain medical advice. Skin Contact : Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention. Eye Contact : Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention. Ingestion : In general no treatment is necessary unless large quantities are swallowed, however, get medical advice. Advice to Physician : Treat 5. FIRE-FIGHTING MEASURES Clear fire area of all non-emergency personnel. Flash point : Typical 240 °C / 464 °F (COC) Upper / lower Flammability or Explosion limits : Typical 1 - 10 Auto ignition temperature : > 320 °C / 608 °F Specific Hazards : Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide may be evolved if incomplete combustion occurs. Unidentified organic and inorganic compounds. Suitable Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media : Do not use water in a jet. Protective Equipment for Firefighters : Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space. 6. ACCIDENTAL RELEASE MEASURES Avoid contact with spilled or released material. For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on disposal. Observe the relevant local and international regulations. Page 1032 of 1287 Page 1032 of 1287 Page 1032 of 1287 Page 1032 of 1287 ---PAGE BREAK--- Shell Morlina S4 B 220 MSDS# 18049DA Version 1.4 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 3/9 Print Date 07/03/2014 000000019939 MSDS_US Protective measures : Avoid contact with skin and eyes. Use appropriate containment to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately. Prevent from spreading by making a barrier with sand, earth or other containment material. Reclaim liquid directly or in an absorbent. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly. Additional Advice : Local authorities should be advised if significant spillages cannot be contained. 7. HANDLING AND STORAGE General Precautions : Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Use the information in this data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling vapour and/or mists. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Storage : Keep container closed and in a cool, well-ventilated place. Use properly labelled and closeable containers. Store at ambient temperature. Recommended Materials : For containers or container linings, use mild steel or high density polyethylene. Unsuitable Materials : PVC. Additional Information : Polyethylene containers should not be exposed to high temperatures because of possible risk of distortion. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Contains no components with occupational exposure limit values. Material Source Type ppm mg/m3 Notation Oil mist, mineral ACGIH TWA(Inhalabl e fraction.) 5 mg/m3 Oil mist, mineral OSHA Z1 PEL(Mist.) 5 mg/m3 Page 1033 of 1287 Page 1033 of 1287 Page 1033 of 1287 Page 1033 of 1287 ---PAGE BREAK--- Shell Morlina S4 B 220 MSDS# 18049DA Version 1.4 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 4/9 Print Date 07/03/2014 000000019939 MSDS_US Biological Exposure Index (BEI) No biological limit allocated. Exposure Controls : The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Adequate ventilation to control airborne concentrations. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated. Define procedures for safe handling and maintenance of controls. Educate and train workers in the hazards and control measures relevant to normal activities associated with this product. Ensure appropriate selection, testing and maintenance of equipment used to control exposure, e.g. personal protective equipment, local exhaust ventilation. Drain down system prior to equipment break-in or maintenance. Retain drain downs in sealed storage pending disposal or for subsequent recycle. Always observe good personal hygiene measures, such as washing hands after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. Personal Protective Equipment : Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers. Respiratory Protection : No respiratory protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid breathing of material. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. Select a filter suitable for combined particulate/organic gases and vapours [boiling point >65°C(149 Hand Protection : Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection: PVC, neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Page 1034 of 1287 Page 1034 of 1287 Page 1034 of 1287 Page 1034 of 1287 ---PAGE BREAK--- Shell Morlina S4 B 220 MSDS# 18049DA Version 1.4 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 5/9 Print Date 07/03/2014 000000019939 MSDS_US Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. For continuous contact we recommend gloves with breakthrough time of more than 240 minutes with preference for > 480 minutes where suitable gloves can be identified. For short-term/splash protection we recommend the same, but recognise that suitable gloves offering this level of protection may not be available and in this case a lower breakthrough time may be acceptable so long as appropriate maintenance and replacement regimes are followed. Glove thickness is not a good predictor of glove resistance to a chemical as it is dependent on the exact composition of the glove material. Glove thickness should be typically greater than 0.35 mm depending on the glove make and model. Eye Protection : Wear safety glasses or full face shield if splashes are likely to occur. Protective Clothing : Skin protection not ordinarily required beyond standard issue work clothes. Monitoring Methods : Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate. Validated exposure measurement methods should be applied by a competent person and samples analysed by an accredited laboratory. Examples of sources of recommended exposure measurement methods are given below or contact the supplier. Further national methods may be available. National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods http://www.cdc.gov/niosh/ Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods http://www.osha.gov/ Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances http://www.hse.gov.uk/ Institut für Deutschen Gesetzlichen Unfallversicherung (IFA), Germany. http://www.dguv.de/inhalt/index.jsp L'Institut National de Recherche et de Securité, (INRS), France http://www.inrs.fr/accueil Environmental Exposure Controls : Take appropriate measures to fulfil the requirements of relevant environmental protection legislation. Avoid contamination of the environment by following advice given in Chapter 6. If necessary, prevent undissolved material from being discharged to waste water. Waste water should be treated in a municipal or industrial waste water treatment plant before discharge to surface water. Local guidelines on emission limits for volatile substances must be observed for the discharge of exhaust air containing vapour. Page 1035 of 1287 Page 1035 of 1287 Page 1035 of 1287 Page 1035 of 1287 ---PAGE BREAK--- Shell Morlina S4 B 220 MSDS# 18049DA Version 1.4 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 6/9 Print Date 07/03/2014 000000019939 MSDS_US 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Yellow. Liquid at room temperature. Odour : Slight hydrocarbon. pH : Not applicable. Initial Boiling Point and Boiling Range : > 280 °C / 536 °F estimated value(s) Pour point : Typical -48 °C / -54 °F Flash point : Typical 240 °C / 464 °F (COC) Upper / lower Flammability or Explosion limits : Typical 1 - 10 Auto-ignition temperature : > 320 °C / 608 °F Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s)) Specific gravity : Typical 0.853 at 15 °C / 59 °F Density : Typical 853 kg/m3 at 15 °C / 59 °F Water solubility : Negligible. n-octanol/water partition coefficient (log Pow) : > 6 (based on information on similar products) Kinematic viscosity : Typical 220 mm2/s at 40 °C / 104 °F Vapour density (air=1) : > 1 (estimated value(s)) Electrical conductivity : This material is not expected to be a static accumulator. Evaporation rate (nBuAc=1) : Data not available 10. STABILITY AND REACTIVITY Stability : Stable. Conditions to Avoid : Extremes of temperature and direct sunlight. Materials to Avoid : Strong oxidising agents. Hazardous Decomposition Products : Hazardous decomposition products are not expected to form during normal storage. 11. TOXICOLOGICAL INFORMATION Basis for Assessment : Information given is based on data on the components and the toxicology of similar products. Unless indicated otherwise, the data presented is representative of the product as a whole, rather than for individual component(s). Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal conditions of use. Skin Irritation : Expected to be irritating. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Eye Irritation : Expected to be irritating. Respiratory Irritation : Inhalation of vapours or mists may cause irritation. Sensitisation : Not expected to be a skin sensitiser. Repeated Dose Toxicity : Not expected to be a hazard. Page 1036 of 1287 Page 1036 of 1287 Page 1036 of 1287 Page 1036 of 1287 ---PAGE BREAK--- Shell Morlina S4 B 220 MSDS# 18049DA Version 1.4 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 7/9 Print Date 07/03/2014 000000019939 MSDS_US Mutagenicity : Not considered a mutagenic hazard. Carcinogenicity : Not expected to be carcinogenic. Material : Carcinogenicity Classification Highly refined mineral oil (IP346 : ACGIH Group A4: Not classifiable as a human carcinogen. Highly refined mineral oil (IP346 : IARC 3: Not classifiable as to carcinogenicity to humans. Highly refined mineral oil (IP346 : GHS / CLP: No carcinogenicity classification Reproductive and Developmental Toxicity : Not expected to be a hazard. Additional Information : Used oils may contain harmful impurities that have accumulated during use. The concentration of such impurities will depend on use and they may present risks to health and the environment on disposal. ALL used oil should be handled with caution and skin contact avoided as far as possible. 12. ECOLOGICAL INFORMATION Ecotoxicological data have not been determined specifically for this product. Information given is based on a knowledge of the components and the ecotoxicology of similar products. Unless indicated otherwise, the data presented is representative of the product as a whole, rather than for individual component(s). Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic organisms. Expected to be practically non toxic: LL/EL/IL50 > 100 mg/l (to aquatic organisms) LL/EL50 expressed as the nominal amount of product required to prepare aqueous test extract. Mobility : Liquid under most environmental conditions. If it enters soil, it will adsorb to soil particles and will not be mobile. Floats on water. Persistence/degradability : Expected to be not readily biodegradable. Major constituents are expected to be inherently biodegradable, but the product contains components that may persist in the environment. Bioaccumulation : Contains components with the potential to bioaccumulate. Other Adverse Effects : Product is a mixture of non-volatile components, which are not expected to be released to air in any significant quantities. Not expected to have ozone depletion potential, photochemical ozone creation potential or global warming potential. 13. DISPOSAL CONSIDERATIONS Material Disposal : Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper Page 1037 of 1287 Page 1037 of 1287 Page 1037 of 1287 Page 1037 of 1287 ---PAGE BREAK--- Shell Morlina S4 B 220 MSDS# 18049DA Version 1.4 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 8/9 Print Date 07/03/2014 000000019939 MSDS_US waste classification and disposal methods in compliance with applicable regulations. Do not dispose into the environment, in drains or in water courses. Container Disposal : Dispose in accordance with prevailing regulations, preferably to a recognised collector or contractor. The competence of the collector or contractor should be established beforehand. Local Legislation : Disposal should be in accordance with applicable regional, national, and local laws and regulations. 14. TRANSPORT INFORMATION US Department of Transportation Classification (49CFR) This material is not subject to DOT regulations under 49 CFR Parts 171-180. IMDG This material is not classified as dangerous under IMDG regulations. IATA (Country variations may apply) This material is either not classified as dangerous under IATA regulations or needs to follow country specific requirements. 15. REGULATORY INFORMATION The regulatory information is not intended to be comprehensive. Other regulations may apply to this material. Federal Regulatory Status Notification Status EINECS All components listed or polymer exempt. TSCA All components listed. DSL All components listed. Shell classifies this material as an "oil" under the CERCLA Petroleum Exclusion, therefore releases to the environment are not reportable under CERCLA. SARA Hazard Categories (311/312) Page 1038 of 1287 Page 1038 of 1287 Page 1038 of 1287 Page 1038 of 1287 ---PAGE BREAK--- Shell Morlina S4 B 220 MSDS# 18049DA Version 1.4 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 9/9 Print Date 07/03/2014 000000019939 MSDS_US No SARA 311/312 Hazards. SARA Toxic Release Inventory (TRI) (313) (95-63-6) 0.00% State Regulatory Status California Safe Drinking Water and Toxic Enforcement Act (Proposition 65) This material does not contain any chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. New Jersey Right-To-Know Chemical List (95-63-6) 0.0001% Listed. Right-To-Know Chemical List (95-63-6) 0.0001% Environmental hazard. Listed. 16. OTHER INFORMATION NFPA Rating (Health, Fire, Reactivity) : 0, 1, 0 SDS Version Number : 1.4 SDS Effective Date : 02/05/2014 SDS Revisions : A vertical bar in the left margin indicates an amendment from the previous version. SDS Regulation : The content and format of this MSDS is in accordance with the OSHA Hazard Communication Standard, 29 CFR 1910.1200. SDS Distribution : The information in this document should be made available to all who may handle the product. Disclaimer : The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of health, safety and environmental requirements only. No warranty or guarantee is expressed or implied regarding the accuracy of these data or the results to be obtained from the use of the product. Page 1039 of 1287 Page 1039 of 1287 Page 1039 of 1287 Page 1039 of 1287 ---PAGE BREAK--- Shell Rotella T Triple Protection 15W-40 Version 1.3 Effective Date 2014-12-18 Material Safety Data Sheet According to the Controlled Product Regulations 1/7 Print Date 2014-12-18 000000014571 MSDS_CA 1. MATERIAL AND COMPANY IDENTIFICATION Material Name : Shell Rotella T Triple Protection 15W-40 Uses : Engine oil. Product Code : 001D5439 Manufacturer/Supplier : Shell Canada Products 400 - 4th Avenue S.W Calgary AB T2P 0J4 Canada Telephone : [PHONE REDACTED] Fax : [PHONE REDACTED] Emergency Telephone Number : CHEMTREC (24 hr): [PHONE REDACTED] CANUTEC (24 hr): [PHONE REDACTED] 2. COMPOSITION/INFORMATION ON INGREDIENTS Mixture Description: : Highly refined mineral oils and additives. The highly refined mineral oil contains (w/w) DMSO-extract, according to IP346. Refer to Chapter 8 for Occupational Exposure Guidelines. 3. HAZARDS IDENTIFICATION WHMIS Class/Description : THIS PRODUCT IS NOT A WHMIS CONTROLLED SUBSTANCE. Routes of Exposure : Skin and eye contact are the primary routes of exposure although exposure may occur following accidental ingestion. Health Hazards : Not expected to be a health hazard when used under normal conditions. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Used oil may contain harmful impurities. Signs and : Oil acne/folliculitis signs and may include formation of black pustules and spots on the skin of exposed areas. Ingestion may result in nausea, vomiting and/or diarrhoea. Safety Hazards : Not classified as flammable but will burn. Environmental Hazards : Not classified as dangerous for the environment. 4. FIRST AID MEASURES General Information : Not expected to be a health hazard when used under normal conditions. Page 1040 of 1287 Page 1040 of 1287 Page 1040 of 1287 Page 1040 of 1287 ---PAGE BREAK--- Shell Rotella T Triple Protection 15W-40 Version 1.3 Effective Date 2014-12-18 Material Safety Data Sheet According to the Controlled Product Regulations 2/7 Print Date 2014-12-18 000000014571 MSDS_CA Inhalation : No treatment necessary under normal conditions of use. If persist, obtain medical advice. Skin Contact : Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention. Eye Contact : Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention. Ingestion : In general no treatment is necessary unless large quantities are swallowed, however, get medical advice. Advice to Physician : Treat 5. FIRE FIGHTING MEASURES Clear fire area of all non-emergency personnel. Flash point : > 230 °C / 446 °F (COC) Upper / lower Flammability or Explosion limits : Typical 1 - 10 %(V)(based on mineral oil) Auto ignition temperature : > 320 °C / 608 °F Hazardous Combustion Products and Specific Hazards : Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Suitable Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media : Do not use water in a jet. Protective Equipment for Firefighters : Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space. 6. ACCIDENTAL RELEASE MEASURES Protective Measures : Avoid contact with skin and eyes. Use appropriate containment to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately. Prevent from spreading by making a barrier with sand, earth or other containment material. Reclaim liquid directly or in an absorbent. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly. Additional Advice : Local authorities should be advised if significant spillages cannot be contained. 7. HANDLING AND STORAGE General Precautions : Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Use the information in this data sheet as input to a risk Page 1041 of 1287 Page 1041 of 1287 Page 1041 of 1287 Page 1041 of 1287 ---PAGE BREAK--- Shell Rotella T Triple Protection 15W-40 Version 1.3 Effective Date 2014-12-18 Material Safety Data Sheet According to the Controlled Product Regulations 3/7 Print Date 2014-12-18 000000014571 MSDS_CA assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling vapour and/or mists. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. Storage : Keep container closed and in a cool, well-ventilated place. Use properly labelled and closeable containers. Store at ambient temperature. Recommended Materials : For containers or container linings, use mild steel or high density polyethylene. Unsuitable Materials : PVC. Additional Information : Polyethylene containers should not be exposed to high temperatures because of possible risk of distortion. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION If the American Conference of Governmental Industrial Hygienists (ACGIH) value is provided on this document, it is provided for information only. Occupational Exposure Limits Material Source Type ppm mg/m3 Notation Oil mist, mineral ACGIH TWA(Inhala ble fraction.) 5 mg/m3 Consult local authorities for acceptable exposure limits within their jurisdiction. Exposure Controls : The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Adequate ventilation to control airborne concentrations. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated. Personal Protective Equipment : Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers. Respiratory Protection : No respiratory protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid breathing of material. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appropriate Page 1042 of 1287 Page 1042 of 1287 Page 1042 of 1287 Page 1042 of 1287 ---PAGE BREAK--- Shell Rotella T Triple Protection 15W-40 Version 1.3 Effective Date 2014-12-18 Material Safety Data Sheet According to the Controlled Product Regulations 4/7 Print Date 2014-12-18 000000014571 MSDS_CA combination of mask and filter. Select a filter suitable for combined particulate/organic gases and vapours [boiling point >65°C(149 Hand Protection : Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection: PVC, neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. Eye Protection : Wear safety glasses or full face shield if splashes are likely to occur. Protective Clothing : Skin protection not ordinarily required beyond standard issue work clothes. Monitoring Methods : Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate. Environmental Exposure Controls : Minimise release to the environment. An environmental assessment must be made to ensure compliance with local environmental legislation. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Amber. Liquid at room temperature. Odour : Slight hydrocarbon. Odour threshold : Data not available pH : Not applicable. Initial Boiling Point and Boiling Range : > 280 °C / 536 °F estimated value(s) Pour point : Typical -34.44 °C / -29.99 °F Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s)) Specific gravity : Density : Typical 879 kg/m3 at 15 °C / 59 °F Water solubility : Negligible. n-octanol/water partition coefficient (log Pow) : > 6 (based on information on similar products) Kinematic viscosity : Typical 120 mm2/s at 40 °C / 104 °F Vapour density (air=1) : > 1 (estimated value(s)) Evaporation rate (nBuAc=1) : Data not available 10. STABILITY AND REACTIVITY Stability : Stable. Page 1043 of 1287 Page 1043 of 1287 Page 1043 of 1287 Page 1043 of 1287 ---PAGE BREAK--- Shell Rotella T Triple Protection 15W-40 Version 1.3 Effective Date 2014-12-18 Material Safety Data Sheet According to the Controlled Product Regulations 5/7 Print Date 2014-12-18 000000014571 MSDS_CA Conditions to Avoid : Extremes of temperature and direct sunlight. Materials to Avoid : Strong oxidising agents. Hazardous Decomposition Products : Hazardous decomposition products are not expected to form during normal storage. Hazardous Polymerisation : No Sensitivity to Mechanical Impact : No Sensitivity to Static Discharge : No 11. TOXICOLOGICAL INFORMATION Basis for Assessment : Information given is based on data on the components and the toxicology of similar products. Routes of Exposure : Skin and eye contact are the primary routes of exposure although exposure may occur following accidental ingestion. Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat. Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit. Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal conditions of use. Skin Irritation : Expected to be irritating. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Eye Irritation : Expected to be irritating. Respiratory Irritation : Inhalation of vapours or mists may cause irritation. Sensitisation : Not expected to be a skin sensitiser. Repeated Dose Toxicity : Not expected to be a hazard. Mutagenicity : Not considered a mutagenic hazard. Carcinogenicity : Product contains mineral oils of types shown to be non- carcinogenic in animal skin-painting studies. Highly refined mineral oils are not classified as carcinogenic by the International Agency for Research on Cancer (IARC). Other components are not known to be associated with carcinogenic effects. Reproductive and Developmental Toxicity : Not expected to be a hazard. Additional Information : Used oils may contain harmful impurities that have accumulated during use. The concentration of such impurities will depend on use and they may present risks to health and the environment on disposal. ALL used oil should be handled with caution and skin contact avoided as far as possible. Continuous contact with used engine oils has caused skin cancer in animal tests. Page 1044 of 1287 Page 1044 of 1287 Page 1044 of 1287 Page 1044 of 1287 ---PAGE BREAK--- Shell Rotella T Triple Protection 15W-40 Version 1.3 Effective Date 2014-12-18 Material Safety Data Sheet According to the Controlled Product Regulations 6/7 Print Date 2014-12-18 000000014571 MSDS_CA 12. ECOLOGICAL INFORMATION Ecotoxicological data have not been determined specifically for this product. Information given is based on a knowledge of the components and the ecotoxicology of similar products. Acute Toxicity : Poorly soluble mixture.May cause physical fouling of aquatic organisms.Expected to be practically non toxic:LL/EL/IL50 > 100 mg/l(to aquatic organisms)(LL/EL50 expressed as the nominal amount of product required to prepare aqueous test extract).Mineral oil is not expected to cause any chronic effects to aquatic organisms at concentrations less than 1 mg/l. Mobility : Liquid under most environmental conditions. Floats on water. If it enters soil, it will adsorb to soil particles and will not be mobile. Persistence/degradability : Expected to be not readily biodegradable. Major constituents are expected to be inherently biodegradable, but the product contains components that may persist in the environment. Bioaccumulation : Contains components with the potential to bioaccumulate. Other Adverse Effects : Product is a mixture of non-volatile components, which are not expected to be released to air in any significant quantities. Not expected to have ozone depletion potential, photochemical ozone creation potential or global warming potential. 13. DISPOSAL CONSIDERATIONS Material Disposal : Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations. Do not dispose into the environment, in drains or in water courses. Container Disposal : Dispose in accordance with prevailing regulations, preferably to a recognised collector or contractor. The competence of the collector or contractor should be established beforehand. Local Legislation : Disposal should be in accordance with applicable regional, national, and local laws and regulations. 14. TRANSPORT INFORMATION Canadian Road and Rail Shipping Classification This product is not regulated under the Canadian Transportation of Dangerous Goods Regulations for transport by road and rail. Page 1045 of 1287 Page 1045 of 1287 Page 1045 of 1287 Page 1045 of 1287 ---PAGE BREAK--- Shell Rotella T Triple Protection 15W-40 Version 1.3 Effective Date 2014-12-18 Material Safety Data Sheet According to the Controlled Product Regulations 7/7 Print Date 2014-12-18 000000014571 MSDS_CA 15. REGULATORY INFORMATION The regulatory information is not intended to be comprehensive. Other regulations may apply to this material. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Class/Description : THIS PRODUCT IS NOT A WHMIS CONTROLLED SUBSTANCE. Inventory Status EINECS : All components listed or polymer exempt. TSCA : All components listed. DSL : All components listed. 16. OTHER INFORMATION MSDS Version Number : 1.3 MSDS Effective Date : 2014-12-18 MSDS Revisions : A vertical bar in the left margin indicates an amendment from the previous version. MSDS Regulation : The content and format of this (M)SDS is in accordance with the Controlled Product Regulations. MSDS Prepared By : Shell Product Stewardship; 1-[PHONE REDACTED] MSDS Distribution : The information in this document should be made available to all who may handle the product. Disclaimer : The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of health, safety and environmental requirements only. No warranty or guarantee is expressed or implied regarding the accuracy of these data or the results to be obtained from the use of the product. Page 1046 of 1287 Page 1046 of 1287 Page 1046 of 1287 Page 1046 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 Version 2.0 Revision Date: 05/21/2015 Print Date: 05/22/2015 1 / 14 800001029741 US SECTION 1. IDENTIFICATION Product name : Shell Spirax S6 AXME 80W-140 Product code : 001D8292 Manufacturer or supplier's details Manufacturer/Supplier : Shell Oil Products US P.O. Box 4427 Houston TX 77210-4427 USA SDS Request : [PHONE REDACTED] Customer Service : Emergency telephone number Spill Information : [PHONE REDACTED] Health Information : [PHONE REDACTED] Recommended use of the chemical and restrictions on use Recommended use : Transmission oil. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Chronic aquatic toxicity : Category 3 GHS Label element Hazard pictograms : No symbol Signal word : No signal word Hazard statements : PHYSICAL HAZARDS: Not classified as a physical hazard under GHS criteria. HEALTH HAZARDS: Not classified as a health hazard under GHS criteria. ENVIRONMENTAL HAZARDS: H412 Harmful to aquatic life with long lasting effects. Precautionary statements : Prevention: P273 Avoid release to the environment. Response: No precautionary phrases. Storage: No precautionary phrases. Disposal: P501 Dispose of contents/ container to an approved waste dis- posal plant. Other hazards which do not result in classification Page 1047 of 1287 Page 1047 of 1287 Page 1047 of 1287 Page 1047 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 Version 2.0 Revision Date: 05/21/2015 Print Date: 05/22/2015 2 / 14 800001029741 US Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin result- ing in disorders such as oil acne/folliculitis. Used oil may contain harmful impurities. Not classified as flammable but will burn. The classification of this material is based on OSHA HCS 2012 criteria. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature : base oil and additives. Hazardous components Chemical Name Synonyms CAS-No. Concentration N-phenyl-1- 90-30-2 0.25 - 0.9 SECTION 4. FIRST-AID MEASURES General advice : Not expected to be a health hazard when used under normal conditions. If inhaled : No treatment necessary under normal conditions of use. If persist, obtain medical advice. In case of skin contact : Remove contaminated clothing. Flush exposed area with wa- ter and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention. In case of eye contact : Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention. If swallowed : In general no treatment is necessary unless large quantities are swallowed, however, get medical advice. Most important and effects, both acute and delayed : Oil acne/folliculitis signs and may include formation of black pustules and spots on the skin of exposed areas. Ingestion may result in nausea, vomiting and/or diarrhoea. Protection of first-aiders : When administering first aid, ensure that you are wearing the appropriate personal protective equipment according to the incident, injury and surroundings. Immediate medical attention, special treatment : Treat SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Foam, water spray or fog. Dry chemical powder, carbon dio- xide, sand or earth may be used for small fires only. Unsuitable extinguishing : Do not use water in a jet. Page 1048 of 1287 Page 1048 of 1287 Page 1048 of 1287 Page 1048 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 Version 2.0 Revision Date: 05/21/2015 Print Date: 05/22/2015 3 / 14 800001029741 US media Specific hazards during fire- fighting : Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide may be evolved if incomplete combustion occurs. Unidentified organic and inorganic compounds. Specific extinguishing me- thods : Use extinguishing measures that are appropriate to local cir- cumstances and the surrounding environment. Special protective equipment for firefighters : Proper protective equipment including chemical resistant gloves are to be worn; chemical resistant suit is indicated if large contact with spilled product is expected. Self-Contained Breathing Apparatus must be worn when approaching a fire in a confined space. Select fire fighter's clothing approved to relevant Standards (e.g. Europe: EN469). SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- tive equipment and emer- gency procedures : Avoid contact with skin and eyes. Environmental precautions : Use appropriate containment to avoid environmental contami- nation. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for containment and cleaning up : Slippery when spilt. Avoid accidents, clean up immediately. Prevent from spreading by making a barrier with sand, earth or other containment material. Reclaim liquid directly or in an absorbent. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly. Additional advice : For guidance on selection of personal protective equipment see Chapter 8 of this Safety Data Sheet. For guidance on disposal of spilled material see Chapter 13 of this Safety Data Sheet. SECTION 7. HANDLING AND STORAGE Technical measures : Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Use the information in this data sheet as input to a risk as- sessment of local circumstances to help determine appropri- ate controls for safe handling, storage and disposal of this Page 1049 of 1287 Page 1049 of 1287 Page 1049 of 1287 Page 1049 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 Version 2.0 Revision Date: 05/21/2015 Print Date: 05/22/2015 4 / 14 800001029741 US material. Precautions for safe handling : Avoid prolonged or repeated contact with skin. Avoid inhaling vapour and/or mists. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. Properly dispose of any contaminated rags or cleaning mate- rials in order to prevent fires. Avoidance of contact : Strong oxidising agents. Product Transfer : This material has the potential to be a static accumulator. Proper grounding and bonding procedures should be used during all bulk transfer operations. Storage Other data : Keep container closed and in a cool, well-ventilated place. Use properly labeled and closable containers. Store at ambient temperature. Packaging material : Suitable material: For containers or container linings, use mild steel or high density polyethylene. Unsuitable material: PVC. Container Advice : Polyethylene containers should not be exposed to high tem- peratures because of possible risk of distortion. SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Components with workplace control parameters Biological occupational exposure limits No biological limit allocated. Monitoring Methods Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure con- trols. For some substances biological monitoring may also be appropriate. Validated exposure measurement methods should be applied by a competent person and sam- ples analysed by an accredited laboratory. Examples of sources of recommended exposure measurement methods are given below or con- tact the supplier. Further national methods may be available. National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods http://www.cdc.gov/niosh/ Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods http://www.osha.gov/ Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances http://www.hse.gov.uk/ Institut für Deutschen Gesetzlichen Unfallversicherung (IFA) , Germany http://www.dguv.de/inhalt/index.jsp L'Institut National de Recherche et de Securité, (INRS), France http://www.inrs.fr/accueil Page 1050 of 1287 Page 1050 of 1287 Page 1050 of 1287 Page 1050 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 Version 2.0 Revision Date: 05/21/2015 Print Date: 05/22/2015 5 / 14 800001029741 US Engineering measures : The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Adequate ventilation to control airborne concentrations. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated. General Information: Define procedures for safe handling and maintenance of controls. Educate and train workers in the hazards and control meas- ures relevant to normal activities associated with this product. Ensure appropriate selection, testing and maintenance of equipment used to control exposure, e.g. personal protective equipment, local exhaust ventilation. Drain down system prior to equipment break-in or mainten- ance. Retain drain downs in sealed storage pending disposal or subsequent recycle. Always observe good personal hygiene measures, such as washing hands after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard con- taminated clothing and footwear that cannot be cleaned. Practice good housekeeping. Personal protective equipment Respiratory protection : No respiratory protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precau- tions should be taken to avoid breathing of material. If engineering controls do not maintain airborne concentra- tions to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the spe- cific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appro- priate combination of mask and filter. Select a filter suitable for the combination of organic gases and vapours [Type A/Type P boiling point >65°C (149°F)]. Hand protection Remarks : Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection. PVC, neoprene or nitrile rubber gloves Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical re- sistance of glove material, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using Page 1051 of 1287 Page 1051 of 1287 Page 1051 of 1287 Page 1051 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 Version 2.0 Revision Date: 05/21/2015 Print Date: 05/22/2015 6 / 14 800001029741 US gloves, hands should be washed and dried thoroughly. Appli- cation of a non-perfumed moisturizer is recommended. For continuous contact we recommend gloves with break- through time of more than 240 minutes with preference for > 480 minutes where suitable gloves can be identified. For short-term/splash protection we recommend the same, but recognize that suitable gloves offering this level of protection may not be available and in this case a lower breakthrough time maybe acceptable so long as appropriate maintenance and replacement regimes are followed. Glove thickness is not a good predictor of glove resistance to a chemical as it is dependent on the exact composition of the glove material. Glove thickness should be typically greater than 0.35 mm depending on the glove make and model. Eye protection : If material is handled such that it could be splashed into eyes, protective eyewear is recommended. Skin and body protection : Skin protection is not ordinarily required beyond standard work clothes. It is good practice to wear chemical resistant gloves. Protective measures : Personal protective equipment (PPE) should meet recom- mended national standards. Check with PPE suppliers. Environmental exposure controls General advice : Take appropriate measures to fulfill the requirements of rele- vant environmental protection legislation. Avoid contamination of the environment by following advice given in Chapter 6. If necessary, prevent undissolved material from being dis- charged to waste water. Waste water should be treated in a municipal or industrial waste water treatment plant before discharge to surface water. Local guidelines on emission limits for volatile substances must be observed for the discharge of exhaust air containing vapour. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Liquid at room temperature. Colour : amber Odour : Slight hydrocarbon Odour Threshold : Data not available pH : Not applicable pour point : -40 °C / -40 °FMethod: ASTM D97 Initial boiling point and boiling range : > 280 °C / 536 °Festimated value(s) Flash point : 201 °C / 394 °F Page 1052 of 1287 Page 1052 of 1287 Page 1052 of 1287 Page 1052 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 Version 2.0 Revision Date: 05/21/2015 Print Date: 05/22/2015 7 / 14 800001029741 US Method: ASTM D92 Evaporation rate : Data not available Flammability (solid, gas) : Data not available Upper explosion limit : Typical 10 Lower explosion limit : Typical 1 Vapour pressure : < 0.5 Pa (20 °C / 68 estimated value(s) Relative vapour density : > 1estimated value(s) Relative density : 0.894 (15.6 °C / 60.1 Density : 894 kg/m3 (15.6 °C / 60.1 Solubility(ies) Water solubility : negligible Solubility in other solvents : Data not available Partition coefficient: n- octanol/water : Pow: > 6(based on information on similar products) Auto-ignition temperature : > 320 °C / 608 °F Viscosity Viscosity, dynamic : Data not available Viscosity, kinematic : 271 mm2/s (40.0 °C / 104.0 Method: ASTM D445 30.5 mm2/s (100 °C / 212 Method: ASTM D445 Conductivity : This material is not expected to be a static accumulator. Decomposition temperature : Data not available SECTION 10. STABILITY AND REACTIVITY Chemical stability : Stable. Possibility of hazardous reac- tions : Reacts with strong oxidising agents. Page 1053 of 1287 Page 1053 of 1287 Page 1053 of 1287 Page 1053 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 Version 2.0 Revision Date: 05/21/2015 Print Date: 05/22/2015 8 / 14 800001029741 US Conditions to avoid : Extremes of temperature and direct sunlight. Incompatible materials : Strong oxidising agents. Hazardous decomposition products : Hazardous decomposition products are not expected to form during normal storage. SECTION 11. TOXICOLOGICAL INFORMATION Basis for assessment : Information given is based on data on the components and the toxicology of similar products.Unless indicated otherwise, the data presented is representative of the product as a whole, rather than for individual component(s). Information on likely routes of exposure Skin and eye contact are the primary routes of exposure although exposure may occur following accidental ingestion. Acute toxicity Product: Acute oral toxicity : LD50 (rat): > 5,000 mg/kg Remarks: Expected to be of low toxicity: Acute inhalation toxicity : Remarks: Not considered to be an inhalation hazard under normal conditions of use. Acute dermal toxicity : LD50 (Rabbit): > 5,000 mg/kg Remarks: Expected to be of low toxicity: Skin corrosion/irritation Product: Remarks: Expected to be irritating., Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Serious eye damage/eye irritation Product: Remarks: Expected to be irritating. Respiratory or skin sensitisation Product: Remarks: Not expected to be a skin sensitiser. Components: Remarks: May cause an allergic skin reaction in sensitive individuals. Remarks: Classified Skin Sensitiser Category 1B. Page 1054 of 1287 Page 1054 of 1287 Page 1054 of 1287 Page 1054 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 Version 2.0 Revision Date: 05/21/2015 Print Date: 05/22/2015 9 / 14 800001029741 US Germ cell mutagenicity Product: : Remarks: Not considered a mutagenic hazard. Carcinogenicity Product: Remarks: Not expected to be carcinogenic. IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by ACGIH. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Product: : Remarks: Not expected to impair fertility., Not expected to be a developmental toxicant. STOT - single exposure Product: Remarks: Not expected to be a hazard. STOT - repeated exposure Product: Remarks: Not expected to be a hazard. Aspiration toxicity Product: Not considered an aspiration hazard. Further information Product: Page 1055 of 1287 Page 1055 of 1287 Page 1055 of 1287 Page 1055 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 Version 2.0 Revision Date: 05/21/2015 Print Date: 05/22/2015 10 / 14 800001029741 US Remarks: Used oils may contain harmful impurities that have accumulated during use. The con- centration of such impurities will depend on use and they may present risks to health and the environment on disposal., ALL used oil should be handled with caution and skin contact avoided as far as possible. Remarks: irritating to respiratory system. SECTION 12. ECOLOGICAL INFORMATION Basis for assessment : Ecotoxicological data have not been determined specifically for this product. Information given is based on a knowledge of the components and the ecotoxicology of similar products. Unless indicated otherwise, the data presented is representa- tive of the product as a whole, rather than for individual com- ponent(s).(LL/EL/IL50 expressed as the nominal amount of product required to prepare aqueous test extract). Ecotoxicity Product: Toxicity to fish (Acute toxic- ity) : Remarks: Expected to be harmful: LL/EL/IL50 10-100 mg/l Toxicity to daphnia and other aquatic invertebrates (Acute toxicity) : Remarks: Expected to be harmful: LL/EL/IL50 10-100 mg/l Toxicity to algae (Acute toxic- ity) : Remarks: Expected to be harmful: LL/EL/IL50 10-100 mg/l Toxicity to fish (Chronic toxic- ity) : Remarks: Data not available Toxicity to daphnia and other aquatic invertebrates (Chron- ic toxicity) : Remarks: Data not available Toxicity to bacteria (Acute toxicity) : Remarks: Data not available Components: M-Factor (Acute aquatic tox- icity) : 1 Persistence and degradability Product: Biodegradability : Remarks: Expected to be not readily biodegradable. Major constituents are expected to be inherently biodegrada- ble, but contains components that may persist in the environ- Page 1056 of 1287 Page 1056 of 1287 Page 1056 of 1287 Page 1056 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 Version 2.0 Revision Date: 05/21/2015 Print Date: 05/22/2015 11 / 14 800001029741 US ment. Bioaccumulative potential Product: Bioaccumulation : Remarks: Contains components with the potential to bioac- cumulate. Mobility in soil Product: Mobility : Remarks: Liquid under most environmental conditions. If it enters soil, it will adsorb to soil particles and will not be mobile. Remarks: Floats on water. Other adverse effects no data available Product: Additional ecological informa- tion : Product is a mixture of non-volatile components, which are not expected to be released to air in any significant quantities. Not expected to have ozone depletion potential, photochemi- cal ozone creation potential or global warming potential. Poorly soluble mixture. May cause physical fouling of aquatic organisms. SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Waste product should not be allowed to contaminate soil or ground water, or be disposed of into the environment. Waste, spills or used product is dangerous waste. Contaminated packaging : Dispose in accordance with prevailing regulations, preferably to a recognized collector or contractor. The competence of the collector or contractor should be established beforehand. Disposal should be in accordance with applicable regional, national, and local laws and regulations. Local legislation Remarks : Disposal should be in accordance with applicable regional, national, and local laws and regulations. SECTION 14. TRANSPORT INFORMATION National Regulations Page 1057 of 1287 Page 1057 of 1287 Page 1057 of 1287 Page 1057 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 Version 2.0 Revision Date: 05/21/2015 Print Date: 05/22/2015 12 / 14 800001029741 US US Department of Transportation Classification (49 CFR Parts 171-180) Not regulated as a dangerous good International Regulation IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Pollution category : Not applicable Ship type : Not applicable Product name : Not applicable Special precautions : Not applicable Special precautions for user Remarks : Special Precautions: Refer to Chapter 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport. Additional Information : MARPOL Annex 1 rules apply for bulk shipments by sea. SECTION 15. REGULATORY INFORMATION OSHA Hazards : No OSHA Hazards EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ., Shell classifies this material as an "oil" under the CERCLA Petroleum Exclusion, therefore releases to the environment are not reportable under CERCLA. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : No SARA Hazards SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Water Act This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other re- productive harm. Page 1058 of 1287 Page 1058 of 1287 Page 1058 of 1287 Page 1058 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 Version 2.0 Revision Date: 05/21/2015 Print Date: 05/22/2015 13 / 14 800001029741 US The components of this product are reported in the following inventories: EINECS : All components listed or polymer exempt. TSCA : All components listed. DSL : All components listed. SECTION 16. OTHER INFORMATION Further information NFPA Rating (Health, Fire, Reac- tivity) 0, 1, 0 Due to the conversion of this product to GHS classification and labelling, there has been a significant change to the nature of the information presented in chapter 2. A vertical bar in the left margin indicates an amendment from the previous version. Abbreviations and Acronyms : The standard abbreviations and acronyms used in this docu- ment can be looked up in reference literature (e.g. scientific dictionaries) and/or websites. ACGIH = American Conference of Governmental Industrial Hygienists ADR = European Agreement concerning the International Carriage of Dangerous Goods by Road AICS = Australian Inventory of Chemical Substances ASTM = American Society for Testing and Materials BEL = Biological exposure limits BTEX = Benzene, Toluene, Xylenes CAS = Chemical Abstracts Service CEFIC = European Chemical Industry Council CLP = Classification Packaging and Labelling COC = Cleveland Open-Cup DIN = Deutsches Institut fur Normung DMEL = Derived Minimal Effect Level DNEL = Derived No Effect Level DSL = Canada Domestic Substance List EC = European Commission EC50 = Effective Concentration fifty ECETOC = European Center on Ecotoxicology and Toxicolo- gy Of Chemicals ECHA = European Chemicals Agency EINECS = The European Inventory of Existing Commercial Chemical Substances EL50 = Effective Loading fifty ENCS = Japanese Existing and New Chemical Substances Inventory EWC = European Waste Code GHS = Globally Harmonised System of Classification and Labelling of Chemicals IARC = International Agency for Research on Cancer IATA = International Air Transport Association IC50 = Inhibitory Concentration fifty IL50 = Inhibitory Level fifty Page 1059 of 1287 Page 1059 of 1287 Page 1059 of 1287 Page 1059 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 Version 2.0 Revision Date: 05/21/2015 Print Date: 05/22/2015 14 / 14 800001029741 US IMDG = International Maritime Dangerous Goods INV = Chinese Chemicals Inventory IP346 = Institute of Petroleum test method N° 346 for the determination of aromatics DMSO-extractables KECI = Korea Existing Chemicals Inventory LC50 = Lethal Concentration fifty LD50 = Lethal Dose fifty per cent. LL/EL/IL = Lethal Loading/Effective Loading/Inhibitory loading LL50 = Lethal Loading fifty MARPOL = International Convention for the Prevention of Pollution From Ships NOEC/NOEL = No Observed Effect Concentration / No Ob- served Effect Level OE_HPV = Occupational Exposure - High Production Volume PBT = Persistent, Bioaccumulative and Toxic PICCS = Philippine Inventory of Chemicals and Chemical Substances PNEC = Predicted No Effect Concentration REACH = Registration Evaluation And Authorisation Of Chemicals RID = Regulations Relating to International Carriage of Dan- gerous Goods by Rail SKIN_DES = Skin Designation STEL = Short term exposure limit TRA = Targeted Risk Assessment TSCA = US Toxic Substances Control Act TWA = Time-Weighted Average vPvB = very Persistent and very Bioaccumulative Revision Date : 05/21/2015 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. Page 1060 of 1287 Page 1060 of 1287 Page 1060 of 1287 Page 1060 of 1287 ---PAGE BREAK--- Revision Date: 16-Apr-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: SHINE PLUS Product Number: 3025 , 3027 Recommended Use: Cleaning agent Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification Reproductive Toxicity: Category 2 GHS Label Elements Signal Word: Warning Hazard Statements: Suspected of damaging fertility or the unborn child Precautionary Statements: Prevention: Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wear eye / face protection Wear protective gloves Response: If exposed or concerned: Get medical attention. -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Store locked up. Disposal: Dispose of contents and container in accordance with local, state and federal regulations. Hazards Not Otherwise Classified: Not Applicable Other Information: • May be harmful if swallowed. • May cause eye irritation. • May cause skin irritation. • Keep out of reach of children. Page 1 / 5 Symbols: Page 1061 of 1287 Page 1061 of 1287 Page 1061 of 1287 Page 1061 of 1287 ---PAGE BREAK--- 3025 - SHINE PLUS Revision Date: 16-Apr-2015 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 40-70 dimethyl siloxane, hydroxyl-terminated 70131-67-8 10-30 aminofunctional siloxane 68554-54-1 1-5 alcohol ethoxylate 84133-50-6 1-5 556-67-2 0.1-1 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Product does not support combustion, Use extinguishing agent suitable for type of surrounding fire Specific Hazards Arising from the Chemical: Dried product is capable of burning. Combustion products are toxic. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Cool fire-exposed containers with water spray. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 7. HANDLING AND STORAGE Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Storage Conditions: Keep containers closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep from freezing. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: None established. Page 2 / 5 Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Page 1062 of 1287 Page 1062 of 1287 Page 1062 of 1287 Page 1062 of 1287 ---PAGE BREAK--- 3025 - SHINE PLUS Revision Date: 16-Apr-2015 Personal Protective Equipment Eye/Face Protection: Wear splash goggles. Skin and Body Protection: Wear rubber or other chemical-resistant gloves. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatible Materials: Strong oxidizing agents. Strong acids. Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Pain and redness. -Skin Contact: Drying of the skin. -Inhalation: Nasal discomfort and coughing. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 65909 mg/kg ATEmix (dermal): 11658 mg/kg 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Liquid Color: White Odor: Floral fragrance pH: 4.8-5.3 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 100 °C / 212 °F Flash Point: > 100 °C / > 212 °F ASTM D56 Evaporation Rate: < 1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 0.992 Solubility(ies): Miscible in water Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 3 / 5 Decomposition Temperature: No information available. Viscosity: No information available. Page 1063 of 1287 Page 1063 of 1287 Page 1063 of 1287 Page 1063 of 1287 ---PAGE BREAK--- 3025 - SHINE PLUS Revision Date: 16-Apr-2015 Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available 556-67-2 = 1540 mg/kg ( Rat ) > 2400 mg/kg ( Rat ) > 4640 mg/kg ( Rabbit ) = 794 µL/kg ( Rabbit ) > 12.7 mg/kg ( Rat ) 4 h > 17.6 mg/L ( Rat ) 1 h Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Microorganisms Crustacea alcohol ethoxylate 84133-50-6 Not Available 3.2: 96 h Pimephales promelas mg/L LC50 Not Available 3.2: 48 h water flea mg/L EC50 556-67-2 Not Available 500: 96 h Brachydanio rerio mg/L LC50 1000: 96 h Lepomis macrochirus mg/L LC50 Not Available 25.2: 24 h Daphnia magna mg/L EC50 Persistence and Degradability: No information available. Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT: Not Regulated Proper Shipping Name: Non Hazardous Product Special Provisions: Shipping descriptions may vary based on mode of transport, quantities, package size, and/or origin and destination. Check with a trained hazardous materials transportation expert for information specific to your situation. 15. REGULATORY INFORMATION TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product does not contain listed substances above the "de minimus" level SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: Yes Fire Hazard: No Sudden release of pressure hazard: No Reactive Hazard: No California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 dioxane - 123-91-1 Carcinogen formaldehyde - 50-00-0 Page 4 / 5 Carcinogen acetaldehyde - 75-07-0 Carcinogen WARNING: This product contains a chemical known to the State of California to cause cancer. Page 1064 of 1287 Page 1064 of 1287 Page 1064 of 1287 Page 1064 of 1287 ---PAGE BREAK--- 3025 - SHINE PLUS Revision Date: 16-Apr-2015 16. OTHER INFORMATION Revision Date: 16-Apr-2015 Reasons for Revision: No information available. Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 1 Flammability: 0 Instability: 0 Special: N/A HMIS Page 5 / 5 Health Hazards: 1* Flammability: 0 Physical Hazards: 0 Page 1065 of 1287 Page 1065 of 1287 Page 1065 of 1287 Page 1065 of 1287 ---PAGE BREAK--- Material Safety Data Sheet 1. Chemical Product and Company Identification Product Trade Name: SHORELINE MARINE HORNS Chemical Family: 1,1,1,2-Tetrafluoroethane Model No: Model No: SL52418 Model No: SL52417 Model No: SL52272 Product Manufacture: A.V.W d.b.a. Max Professional Address: PO Box 9962 Ft Lauderdale, FL 33310 Phone: [PHONE REDACTED] Emergency Telephone: [PHONE REDACTED] 2. Composition / Information on Ingredients Chemical Name Wt % Range TLV Units Tetrafluoroethane 100.0 1000ppm CAS # 811-97-2 All components of this material are listed on the TSCA inventory 3. Hazard Identification Emergency Overview: Nonflammable. A Clear colorless liquefied gas. Liquid acts as a refrigerant and exposure to unprotected skin to liquid can cause frostbite. Keep away from children. Potential Health Effects INHALATION Gross overexposure may cause: Central nervous system depression with dizziness, confusion, in coordination, drowsiness or unconsciousness, Irregular heart beat with a strange sensation in the chest, “heart thumping”, apprehension, lightheadedness, feeling of fainting, dizziness, weakness, sometimes progressing to loss of consciousness and death. Suffocation, if air is displaced by vapors. SKIN CONTACT 1,1,1-2 TETRAFLUORO ETHANE The Immediate effects of overexposure may include: Frostbite, if liquid or escaping vapor contacts the skin. EYE CONTACT 1,1,1,2-TETRAFLUORO ETHANE “Frostbite” effects may occur if the liquid or escaping vapors contact the eyes. ADDITIONAL HEALTH EFFECTS 1,1,1,2-TETRAFLUORO ETHANE Increased susceptibility to the effects of this material may be observed in persons with pre-existing disease of the: central nervous system, cardiovascular system. Carcinogenicity Information None of the components present in this material at concentrations equal to or greater than 0.1 % are listed by IARC, NTP, OSHA or ACGIH as a carcinogen. Medical Conditions Aggravated by Exposure: Page 1066 of 1287 Page 1066 of 1287 Page 1066 of 1287 Page 1066 of 1287 ---PAGE BREAK--- Preexisting disease of the central nervous or cardiovascular system may have increased susceptibility to the toxicity of excessive exposures. 4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician . Skin: In case of contact, immediately flush skin with plenty of warm water for at least 15 minutes, while removing all contaminated clothing. Call a physician. Wash contaminated clothing before reuse. Treat for frostbite if necessary by gently warming affected area. Eyes: Immediately flush with water. Remove any contact lenses and continue flushing for 15 minutes, lifting eyelids occasionally until no evidence of the chemical remains. If irritation develops or persists call a physician. Ingestion: Not considered a potential way of exposure. Treat for any frostbite. Swallowing less than ounce of material is unlikely to cause significant harm. For larger amounts, do not induce vomiting. Call a physician. Note to Attending Physician: Because of the possible disturbances of cardiac catecholamine drugs, such as epinephrine, should be used with special caution and only in situations of emergency life support. Treatment of overexposure should be directed at the control of the and the clinical conditions. There is no specific antidote to over overexposure. Treatment of overexposure should be directed at the control of and the clinical condition of the patient. Immediate medical attention for acute overexposure is required. 5. Firefighting Measures Flash Point: Will not burn. Autoignition Temperature: >750°C Flammable Limits in Air: LEL/UEL: Not applicable. Extinguishing Media: Use dry chemical, “alcohol” foam, CO2 or water. Special Firefighting Procedures: Evacuate personnel. Wear self-contained breathing apparatus (SCBA) and full protective equipment. Keep containers cool. Containers build pressure under fire conditions causing violent bursting and dangerous propelling of container. Contact of welding or soldering torch flame with high concentrations of refrigerant can result in visible changes in the size and color of torch flames. This flame effect will only occur in concentrations of product well above the recommended exposure limit, therefore stop all work and ventilate to disperse refrigerant vapors from the work area before using any open flames. HFC-134a is not flammable in air at temperatures up to 100 deg. C (212 deg. F) at atmospheric pressure. However, mixtures of HFC-134a with high concentrations of air at higher pressure and/or temperature can become combustible in the presence of an ignition source. HFC-134a can also become combustible in oxygen-enriched environment (oxygen concentrations greater than that in air). Whether a mixture containing HFC-134a and air, or HFC-134a in an oxygen enriched atmosphere become combustible depends on the inter-relationship of 1) the temperature 2) the proportion of oxygen in the mixture and 3) the pressure. In HFC-134a should not be allowed to exist with air above atmospheric pressure or at high temperatures; or in an oxygen enriched environment. For example HFC-134a should NOT be mixed with air under pressure for leak testing or other purposes. 6. Accidental Release Measures Spill or Leak: It is very unlikely that a large spill or leak will occur with aerosol containers, in the event of such an occurrence evacuate area. Protected personnel should remove ignition sources and cut off all fire sources. Provide ventilation. Page 1067 of 1287 Page 1067 of 1287 Page 1067 of 1287 Page 1067 of 1287 ---PAGE BREAK--- 7. Handling and Storage Avoid breathing vapors. Keep containers closed. Use only with adequate ventilation. Avoid repeated or prolonged contact with eyes, skin or clothing. Wash thoroughly after handling. Do not store in direct sunlight. Store in cool dry place, away from heat, sparks or flames, which may generate toxic decomposition gases. Vapors are heavy and may concentrate in low poorly ventilated areas. 8. Exposure Controls/Personal Protection Respiratory Protection: Use only with adequate ventilation. Keep container closed. Use approved NIOSH Self-contained or supplied air respirators for emergencies and in situations where air may be displaced by vapors. Eye Protection: Use chemical protective safety glasses. Protective Clothing: Where there is potential for skin contact, use appropriate impervious gloves, apron, pants and jacket. Exposure Guidelines: Applicable Exposure Limits. Tetrafluoroethane: PEL (OSHA) none established TLV (ACGIH) none established AEL (DuPont) 1000 ppm, & 12 hour TWA WEEL (AIHA) 1000 ppm, 8 hour TWA NFPA, NPCA-HIMIS RATING: Health 1 Flammability 0 Reactivity 1 Personal Protection rating to be supplied by user depending on use conditions. 9. Physical and Chemical Properties Physical Form: Liquified Gas Odor: Slight Ethereal Boiling Point: -26.5° C / -15.7°F PH: Not Applicable Solubility in Water: 0.15wt% @ 25° C (77°) @ 14.7 psia. Specific Gravity: 1.208 @ 25°C / 77°F Liquid Density 1.21 g/cm³ @ 25°C (77°F) % Volatile by Weight: 100 Vapor Pressure: 96 psi @ 25° C / 77° Vapor Density [air=1]: 3.6 @ 25° C / 77°F 10. Reactivity Chemical Stability: Material is stable. Conditions to Avoid: Avoid open flames and high temperatures Incompatibilities: Incompatible with alkali or alkaline earth metals – powdered Al, Zn, Be, etc. Decomposition Products: Decomposition products are hazardous. High temperatures (open flames, glowing Page 1068 of 1287 Page 1068 of 1287 Page 1068 of 1287 Page 1068 of 1287 ---PAGE BREAK--- metal parts, etc) will decompose this material forming hydrofluoric acid and possibly carbonyl fluoride. These materials are toxic and irritating. Contact should be avoided. Hazardous Polymerization: Will not occur. 11. Toxicological Information Animal Data 1,1,1,2- TETRAFLUORO ETHANE Eye: A short duration spray of vapor produced very slight eye irritation. Skin: Animal testing indicates this material is slight skin irritant, but not a skin sensitizer. Inhalation: 4 hour, ALC, rat: 567,000 ppm Single exposure caused: Cardiac sensitization: 75,000 ppm. Single exposure caused: Lethargy, Marcarcosis, Increased respiratory rates. These effects were temporary, single exposure to near lethal doses caused: Pulmonary edema. Repeated Exposure caused: Increased adrenals, liver, spleen weight. Decreased uterine, prostate weight. Repeated dosing of higher concentrations caused: the following temporary effects- Tremors, in coordination. CARCINOGENIC, DEVELOPMENTAL, REPRODUCTIVE, MUTAGENETIC EFFECTS: In a two- year inhalation study HFC-134a, at a concentration of 50,000 ppm produced an increase in late-occurring benign testicular tumors, testicular hyperplasia and testicular weight. The no effect level for this study was 10,000 ppm. Animal data shows slight fetotoxicity but only at exposure levels producing other toxic effects in the adult animal. Reproductive data on male mice show: No change in reproductive performance. Tests have shown that this material does not cause genetic damage in bacterial or mammalian cell cultures, or in animals. In animal testing, this material has not caused permanent genetic damage in reproductive cell of mammals (has not produced heritable genetic damage). 12. Ecological Information Aquatic Toxicity: 48 hour EC50- Daphnia magna: 980 mg/L 96 hour LC50- Rainbow Trout: 450 mg/L 13. Disposal Considerations Waste Disposal Remove by distillation or remove to a permitted waste disposal facility, Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial and Local regulations. 14. Transportation Information Transport aerosol Packaging: Ground Transport: Consumer Commodity ORM-D Air Transport: Refrigerant Gas, N.OS. (Tetrafluoroethane), UN3159, Class 2.2, Pkg. Instr.200, Authorization: per DOT-SP-10232 NOTE: Hazard label: Nonflammable Gas 15. Regulatory Information Section 313 Supplier Information: This material contains the following toxic chemicals subject to the emergency reporting requirements of Section 313 of the Emergency Planning and Community Right to Know Act of 1986 and 40 CFR 372: CAS# CHEMICAL NAME %by Weight - None - This information must be included in all that are copied and distributed for this material. Page 1069 of 1287 Page 1069 of 1287 Page 1069 of 1287 Page 1069 of 1287 ---PAGE BREAK--- California V.O.C. Data: This product contains 0 grams total VOC per liter. Title III Hazard Communications Sections 311,312 Acute Yes Chronic Yes Fire No Reactivity No Pressure Yes Hazardous Chemical List SARA Extremely Hazardous Substance: No CERCLA Hazardous Substance No SARA Toxic Chemical No 16. Other Information NFPA, NPCA-HMIS NPCA-HMIS Rating Health: 1 Flammability: 0 Reactivity: 1 WHIMIS- Canada Class A- Compressed Gas CEPA DSL: 1,1,1,2-Tetrafluoroethane Personal Protection rating to be supplied by user depending on use Max Professional Inc. expressly disclaim all express or implied warranties for merchantability and fitness for a particular purpose, with respect to the product or information provided herein. All information appearing herein is based upon data obtained from the manufacturer, While the information is believed to be accurate, Max Professional, Inc. makes no representation as to is accuracy of sufficiency, Conditions of use are beyond Max Professional, Inc. control and therefore users are responsible to verify this data under their own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risk of their use, handling and disposal of the product, or from the publication, or use of, or reliance upon, information contained herein. This information relates only to the product designated here and does not relate to its use in combination with any other material or in any other process. This information is based upon technical information believed to be reliable, it is subject to revision as additional knowledge and experience is gained. Mike Swan Technical Manager 03/10/10 Signature Printed Name Title Revision Date Page 1070 of 1287 Page 1070 of 1287 Page 1070 of 1287 Page 1070 of 1287 ---PAGE BREAK--- SLIP Plate No. 1 Safety Data Sheet Section 1: Identification of the Substance/Mixture and of the Company/Undertaking 1.1 Product identifier Product Name l SLIP Plate No. 1 Product Code l 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified use(s) l Dry film lubricant 1.3 Details of the supplier of the safety data sheet Manufacturer l Superior Graphite 10 S. Riverside Plaza Chicago, IL 60606 United States Telephone (General) l [PHONE REDACTED] - (8-5 CST, M-F) 1.4 Emergency telephone number Manufacturer l 1-[PHONE REDACTED] - For Hazardous Materials [or Dangerous Goods] Incident Spill, Leak, Fire, Exposure, or Accident Call CHEMTREC Day or Night Manufacturer l +1 [PHONE REDACTED] - Outside USA and Canada (collect calls accepted) Section 2: Hazards Identification EU/EEC According to: Regulation (EC) No 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010] According to: EU Directive 67/548/EEC (DSD) or 1999/45/EC (DPD) 2.1 Classification of the substance or mixture CLP l Flammable Liquids 3 - H226 Specific Target Organ Toxicity Repeated Exposure 1 - H372 Aspiration 1 - H304 DSD/DPD l Harmful (Xn) R10, R65 2.2 Label Elements CLP DANGER Hazard statements l H226 - Flammable liquid and vapour H304 - May be fatal if swallowed and enters airways H372 - Causes damage to organs - Central Nervous System (CNS) through prolonged or repeated exposure Preparation Date: 25/March/2015 Format: EU CLP/REACH Language: English (US) Revision Date: 25/March/2015 WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012 Page 1 of 13 Page 1071 of 1287 Page 1071 of 1287 Page 1071 of 1287 Page 1071 of 1287 ---PAGE BREAK--- SLIP Plate No. 1 Precautionary statements Prevention l P210 - Keep away from heat, sparks, open flames and/or hot surfaces. - No smoking. P233 - Keep container closed. P240 - Ground and/or bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting/equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P260 - Do not breathe mist/vapours/spray. P264 - Wash thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P280 - Wear protective gloves/protective clothing/eye protection/face protection. Response l P370+P378 - In case of fire: Use appropriate media for extinction. P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331 - Do NOT induce vomiting. P314 - Get medical advice/attention if you feel unwell. Storage/Disposal l P403+P235 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. DSD/DPD Risk phrases l R10 - Flammable. R65 - Harmful: may cause lung damage if swallowed. Safety phrases l S53 - Avoid exposure - obtain special instructions before use. 2.3 Other Hazards CLP l According to Regulation (EC) No. 1272/2008 (CLP) this material is considered hazardous. DSD/DPD l According to European Directive 1999/45/EC this material is considered dangerous. United States (US) According to: OSHA 29 CFR 1910.1200 HCS 2.1 Classification of the substance or mixture OSHA HCS 2012 l Flammable Liquids 3 Aspiration 1 Eye Irritation 2 Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects Specific Target Organ Toxicity Repeated Exposure 2 2.2 Label elements OSHA HCS 2012 DANGER Hazard statements l Flammable liquid and vapour May be fatal if swallowed and enters airways Causes serious eye irritation May cause drowsiness or dizziness May cause damage to organs through prolonged or repeated exposure. Preparation Date: 25/March/2015 Format: EU CLP/REACH Language: English (US) Revision Date: 25/March/2015 WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012 Page 2 of 13 Page 1072 of 1287 Page 1072 of 1287 Page 1072 of 1287 Page 1072 of 1287 ---PAGE BREAK--- SLIP Plate No. 1 Precautionary statements Prevention l Keep away from heat, sparks, open flames and/or hot surfaces. - No smoking. Keep container closed. Ground and/or bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe mist/vapours/spray. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Response l In case of fire: Use appropriate media for extinction. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. Get medical advice/attention if you feel unwell. Storage/Disposal l Store in a well-ventilated place. Keep container closed. Keep cool. Store locked up. Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. 2.3 Other hazards OSHA HCS 2012 l Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard), this product is considered hazardous. Canada According to: WHMIS 2.1 Classification of the substance or mixture WHMIS l Combustible Liquids - B3 Other Toxic Effects - D2A 2.2 Label elements WHMIS 2.3 Other hazards l Combustible Liquids - B3 Other Toxic Effects - D2A WHMIS l In Canada, the product mentioned above is considered hazardous under the Workplace Hazardous Materials Information System (WHMIS). Section 3 - Composition/Information on Ingredients 3.1 Substances Preparation Date: 25/March/2015 Format: EU CLP/REACH Language: English (US) Revision Date: 25/March/2015 WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012 Page 3 of 13 Page 1073 of 1287 Page 1073 of 1287 Page 1073 of 1287 Page 1073 of 1287 ---PAGE BREAK--- SLIP Plate No. 1 3.2 Mixtures l Material does not meet the criteria of a substance in accordance with Regulation (EC) No 1272/2008. Composition Chemical Name Identifiers % LD50/LC50 Classifications According to Regulation/Directive Comments Stoddard solvent CAS:8052-41-3 < 50% Inhalation-Rat LC50 • >1400 ppm 8 Hour(s) EU DSD/DPD: Annex VI, Table 3.1: Carc. Contains <0.1% benzene therefore mutagen and carcinogen classifications do not apply Cat. 2 R45 Muta. Cat. 2 R46 Xn R48/20-65 EC Number:232- 489-3 EU Index:649- EU CLP: Annex VI, Table 3.1: Carc. 1B, H350; Muta. 1B, H340; STOT RE 1 (CNS), H372 ; Asp. Tox. 1, H304 OSHA HCS 2012: Flam. Liq. 3; Eye Irrit. 2; 345-00-4 STOT RE 2 (Liver, Kidneys); STOT SE 3: Narc.; Asp. Tox. 1 Graphite CAS:7782-42-5 EC Number:231- 955-3 < 40% NDA EU DSD/DPD: Not Classified EU CLP: Not Classified OSHA HCS 2012: Comb. Dust NDA Quartz CAS:14808-60- 7 EC Number:238- 878-4 < 1% NDA EU DSD/DPD: Self Classified: T R48/20 Carc.Cat.1 R49 EU CLP: Self Classified: STOT RE 1 (Lungs, Inhl), H372; Carc. 1A, H350 OSHA HCS 2012: STOT RE 1 (Lungs, Inhl); Carc. 1A NDA Section 4 - First Aid Measures 4.1 Description of first aid measures Inhalation l IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Administer oxygen if breathing is difficult. Give artificial respiration if victim is not breathing. Get medical attention if occur. Skin l In case of contact with substance, immediately flush skin with running water for at least 20 minutes. Wash skin with soap and water. Remove clothing and wash thoroughly before use. Eye l IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion l Do NOT induce vomiting. Get medical attention. 4.2 Most important and effects, both acute and delayed l Refer to Section 11 - Toxicological Information. 4.3 Indication of any immediate medical attention and special treatment needed Notes to Physician l All treatments should be based on observed signs and of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. Section 5 - Firefighting Measures 5.1 Extinguishing media Suitable Extinguishing Media l LARGE FIRES: Water spray, fog or alcohol-resistant foam. SMALL FIRES: Dry chemical, CO2, water spray or alcohol-resistant foam. Preparation Date: 25/March/2015 Format: EU CLP/REACH Language: English (US) Revision Date: 25/March/2015 WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012 Page 4 of 13 Page 1074 of 1287 Page 1074 of 1287 Page 1074 of 1287 Page 1074 of 1287 ---PAGE BREAK--- SLIP Plate No. 1 Unsuitable Extinguishing Media l No data available 5.2 Special hazards arising from the substance or mixture Unusual Fire and Explosion Hazards Hazardous Combustion Products 5.3 Advice for firefighters l Containers may explode when heated. Vapor explosion hazard indoors, outdoors or in sewers. HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Many liquids are lighter than water. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Runoff to sewer may create fire or explosion hazard. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. l No data available l Structural firefighters' protective clothing will only provide limited protection. Wear positive pressure self-contained breathing apparatus (SCBA). Move containers from fire area if you can do it without risk. LARGE FIRES: Cool containers with flooding quantities of water until well after fire is out. Section 6 - Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures Personal Precautions l Ensure adequate ventilation to remove vapors, fumes, dust etc. Do not walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Contaminated clothing may be a fire risk when dry. Emergency Procedures l As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet) ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. 6.2 Environmental precautions l Prevent entry into waterways, sewers, basements or confined areas. 6.3 Methods and material for containment and cleaning up Containment/Clean-up Measures l Stop leak if you can do it without risk. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean non-sparking tools to collect absorbed material. A vapor suppressing foam may be used to reduce vapors. All equipment used when handling the product must be grounded. LARGE SPILLS: Dike far ahead of liquid spill for later disposal. LARGE SPILLS: Water spray may reduce vapor; but may not prevent ignition in closed spaces. Clean up area with absorbent material and place in closed containers for disposal. 6.4 Reference to other sections l Refer to Section 8 - Exposure Controls/Personal Protection and Section 13 - Disposal Considerations. Section 7 - Handling and Storage 7.1 Precautions for safe handling Handling l All equipment used when handling the product must be grounded. Keep away from fire - No Smoking. Keep away from heat and sparks. Do not use sparking tools. Take Preparation Date: 25/March/2015 Format: EU CLP/REACH Language: English (US) Revision Date: 25/March/2015 WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012 Page 5 of 13 Page 1075 of 1287 Page 1075 of 1287 Page 1075 of 1287 Page 1075 of 1287 ---PAGE BREAK--- SLIP Plate No. 1 precautionary measures against static charges. Use only in well ventilated areas. Avoid contact with eyes, skin and clothing. Wear appropriate personal protective equipment, avoid direct contact. Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco. 7.2 Conditions for safe storage, including any incompatibilities Storage l Store in a well-ventilated place. Keep container closed. Do not store above 120 F. Store locked up. 7.3 Specific end use(s) l Refer to Section 1.2 - Relevant identified uses. Section 8 - Exposure Controls/Personal Protection 8.1 Control parameters Exposure Limits/Guidelines Result ACGIH NIOSH OSHA Quartz (14808-60-7) Graphite as TWAs 0.025 mg/m3 TWA (respirable fraction) 0.05 mg/m3 TWA (respirable dust) Not established 15 mg/m3 TWA total Particulates not otherwise classified (PNOC) TWAs 2 mg/m3 TWA (all forms except graphite fibers, respirable fraction) 2.5 mg/m3 TWA (natural, respirable dust) dust); 5 mg/m3 TWA respirable fraction) Stoddard solvent (8052-41-3) TWAs 100 ppm TWA 350 mg/m3 TWA 500 ppm TWA; 2900 mg/m3 TWA Ceilings Not established 1800 mg/m3 Ceiling (15 min) Not established 8.2 Exposure controls Engineering Measures/Controls l Good general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Personal Protective Equipment Respiratory l Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or are experienced. Eye/Face l Wear chemical splash safety goggles. Skin/Body l Wear protective clothing and gloves. Environmental Exposure Controls l Controls should be engineered to prevent release to the environment, including procedures to prevent spills, atmospheric release and release to waterways. Key to abbreviations ACGIH = American Conference of Governmental Industrial Hygiene NIOSH = National Institute of Occupational Safety and Health OSHA = Occupational Safety and Health Administration TWA = Time-Weighted Averages are based on 8h/day, 40h/week exposures Section 9 - Physical and Chemical Properties 9.1 Information on Physical and Chemical Properties Preparation Date: 25/March/2015 Format: EU CLP/REACH Language: English (US) Revision Date: 25/March/2015 WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012 Page 6 of 13 Page 1076 of 1287 Page 1076 of 1287 Page 1076 of 1287 Page 1076 of 1287 ---PAGE BREAK--- SLIP Plate No. 1 Material Description Physical Form Liquid Appearance/Description Black/gray liquid with a petroleum solvent odor. Color Black-gray Odor Petroleum solvent. Odor Threshold Data lacking General Properties Boiling Point 152 to 176 C(305.6 to 348.8 F) Melting Point Data lacking Decomposition Temperature Data lacking pH Data lacking Specific Gravity/Relative Density = 1.08 Water Solubility Negligible Viscosity Data lacking Explosive Properties Data lacking Oxidizing Properties: Data lacking Volatility Vapor Pressure 2 mmHg (torr) @ 20 C(68 F) Vapor Density 4.7 Air=1 Evaporation Rate 0.2 n-Butyl Acetate = 1 Flammability Flash Point 40.6 C(105.08 F) UEL 7 % LEL 0.9 % Autoignition Data lacking Flammability (solid, gas) Not relevant. Environmental Octanol/Water Partition coefficient Data lacking 9.2 Other Information l No additional physical and chemical parameters noted. Section 10: Stability and Reactivity 10.1 Reactivity 10.2 Chemical stability l No dangerous reaction known under conditions of normal use. l Stable under normal temperatures and pressures. 10.3 Possibility of hazardous reactions l Hazardous polymerization will not occur. 10.4 Conditions to avoid lHeat,sparks,openflames.Excessheat.Incompatiblematerials. 10.5 Incompatible materials l Strong oxidizing agents, acids, and alkalis. 10.6 Hazardous decomposition products l On burning may release carbon dioxide and carbon monoxide. Section 11 - Toxicological Information 11.1 Information on toxicological effects Components Quartz 14808- 60-7 Multi-dose Toxicity: Inhalation-Hamster TCLo • 3 mg/m³ 6 Hour(s) 78 Week(s)-Intermittent; Lungs, Thorax, or Respiration:Fibrosis (interstitial); Lungs, Thorax, or Respiration:Changes in lung weight; Inhalation-Rat TCLo • 80 mg/m³ 26 Week(s)-Intermittent; Lungs, Thorax, or Respiration:Fibrosis, focal (pneumoconiosis); Blood:Changes in spleen; Immunological Including Allergic:Decrease in cellular immune response; Preparation Date: 25/March/2015 Format: EU CLP/REACH Language: English (US) Revision Date: 25/March/2015 WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012 Page 7 of 13 Page 1077 of 1287 Page 1077 of 1287 Page 1077 of 1287 Page 1077 of 1287 ---PAGE BREAK--- SLIP Plate No. 1 Stoddard solvent 50%) 8052- 41-3 Tumorigen / Carcinogen: Inhalation-Rat TCLo • 50 mg/m³ 6 Hour(s) 71 Week(s)-Intermittent; Tumorigenic:Carcinogenic by RTECS criteria; Liver:Tumors Acute Toxicity: Inhalation-Rat LC50 • >1400 ppm 8 Hour(s); Irritation: Eye-Rabbit • 500 mg 24 Hour(s) • Moderate irritation; Multi-dose Toxicity: Inhalation-Rat TCLo • 330 ppm 65 Day(s)-Intermittent; Kidney, Ureter, and Bladder:Changes in tubules (including acute renal failure, acute tubular necrosis); Blood:Other changes GHS Properties Classification EU/CLP • Data lacking Acute toxicity Aspiration Hazard Carcinogenicity Germ Cell Mutagenicity Skin corrosion/Irritation Skin sensitization STOT-RE STOT-SE Toxicity for Reproduction Respiratory sensitization Serious eye damage/Irritation Potential Health Effects Inhalation OSHA HCS 2012 • Data lacking EU/CLP • Aspiration 1 OSHA HCS 2012 • Aspiration 1 EU/CLP • Data lacking OSHA HCS 2012 • Data lacking EU/CLP • Data lacking OSHA HCS 2012 • Data lacking EU/CLP • Data lacking OSHA HCS 2012 • Data lacking EU/CLP • Data lacking OSHA HCS 2012 • Data lacking EU/CLP • Specific Target Organ Toxicity Repeated Exposure 1 OSHA HCS 2012 • Specific Target Organ Toxicity Repeated Exposure 2 EU/CLP • Data lacking OSHA HCS 2012 • Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects EU/CLP • Data lacking OSHA HCS 2012 • Data lacking EU/CLP • Data lacking OSHA HCS 2012 • Data lacking EU/CLP • Data lacking OSHA HCS 2012 • Eye Irritation 2 Acute (Immediate) l May affect the central nervous system. may include dizziness, drowsiness, lethargy, coma and death. Chronic (Delayed) l No data available Skin Acute (Immediate) l Under normal conditions of use, no health effects are expected. Chronic (Delayed) l No data available Eye Acute (Immediate) l Causes serious eye irritation. Chronic (Delayed) l No data available Ingestion Acute (Immediate) l May cause gastrointestinal disturbances including diarrhea, nausea, and vomiting. Small amounts aspirated into the respiratory system during ingestion or from vomiting may cause bronchopneumonia or pulmonary edema, a possibly fatal condition. Chronic (Delayed) l No data available Preparation Date: 25/March/2015 Format: EU CLP/REACH Language: English (US) Revision Date: 25/March/2015 WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012 Page 8 of 13 Page 1078 of 1287 Page 1078 of 1287 Page 1078 of 1287 Page 1078 of 1287 ---PAGE BREAK--- SLIP Plate No. 1 Other Chronic (Delayed) l Repeated and prolonged exposure may affect the kidneys. may include but are not limited to weight loss, nausea, swelling of the arms and legs, vomiting, fatigue, headaches, decreased urine or urine that is mostly water, decreased mental sharpness, and muscle cramps and shakes. Repeated and prolonged exposure may affect the liver. may include yellowing of the skin (jaundice), intense fatigue, loss of appetite, nausea, vomiting, and confusion. Repeated and prolonged exposure may affect the central nervous system. Carcinogenic Effects l This product contains silica as quartz. Silica is classified as a Known Carcinogen according to NTP. IARC Monographs on Evaluation of Carcinogenic Risk of Chemicals to Humans (Monograph 68, 1997) concludes that there is sufficient evidence for the carcinogenicity of silica to humans (IARC Group Carcinogenic Effects CAS IARC NTP Quartz 14808-60-7 Group 1-Carcinogenic Known Human Carcinogen Key to abbreviations LC = Lethal Concentration TC = Toxic Concentration Section 12 - Ecological Information 12.1 Toxicity l Material data lacking. 12.2 Persistence and degradability l Material data lacking. 12.3 Bioaccumulative potential l Material data lacking. 12.4 Mobility in Soil l Material data lacking. 12.5 Results of PBT and vPvB assessment l PBT and vPvB assessment has not been conducted for this material. 12.6 Other adverse effects l No studies have been found. Section 13 - Disposal Considerations 13.1 Waste treatment methods Product waste l Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Packaging waste l Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Section 14 - Transport Information Preparation Date: 25/March/2015 Format: EU CLP/REACH Language: English (US) Revision Date: 25/March/2015 WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012 Page 9 of 13 Page 1079 of 1287 Page 1079 of 1287 Page 1079 of 1287 Page 1079 of 1287 ---PAGE BREAK--- SLIP Plate No. 1 14.1 UN number 14.2 UN proper shipping name 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environmental hazards DOT UN1993 Flammable liquid, N.O.S. (Contains mineral spirits) 3 III NDA TDG UN1993 FLAMMABLE LIQUID, N.O.S. (Contains mineral spirits) 3 III Potential Marine Pollutant IMO/IMDG UN1993 FLAMMABLE LIQUID, N.O.S. (Contains mineral spirits) 3 III NDA IATA/ICAO UN1993 Flammable liquid, N.O.S. (Contains mineral spirits) 3 III NDA 14.6 Special precautions for user 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code l None specified. l Data lacking. Section 15 - Regulatory Information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture SARA Hazard Classifications l Acute, Chronic, Fire Inventory Component CAS Canada DSL Canada NDSL EU EINECS EU ELNICS Graphite 7782-42-5 Yes No Yes No Quartz 14808-60-7 Yes No Yes No Stoddard solvent 8052-41-3 Yes No Yes No Canada Labor Canada - WHMIS - Classifications of Substances • Stoddard solvent 8052-41-3 B3, D2B D2A (In certain cases, this classification does not apply. For more information, consult • Quartz 14808-60-7 the section Substance Specific Issues - Silica, encapsulated on Health Canada's WHMIS Division website.) • Graphite 7782-42-5 D2A (natural); D2B Canada - WHMIS - Ingredient Disclosure List • Stoddard solvent 8052-41-3 1 % • Quartz 14808-60-7 1 % • Graphite 7782-42-5 Not Listed Environment Canada - CEPA - Priority Substances List • Stoddard solvent 8052-41-3 Not Listed • Quartz 14808-60-7 Not Listed Preparation Date: 25/March/2015 Format: EU CLP/REACH Language: English (US) Revision Date: 25/March/2015 WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012 Page 10 of 13 Page 1080 of 1287 Page 1080 of 1287 Page 1080 of 1287 Page 1080 of 1287 ---PAGE BREAK--- SLIP Plate No. 1 • Graphite 7782-42-5 Not Listed Europe Other EU - Hazardous Substances Restricted or Prohibited in Electrical Equipment (2011/65/EU) (RoHS) • Stoddard solvent 8052-41-3 Not Listed • Quartz 14808-60-7 Not Listed • Graphite 7782-42-5 Not Listed Japan Environment Inventory - Japan - Industrial Safety and Health Law Substances (ISHL) • Stoddard solvent 8052-41-3 Not Listed • Quartz 14808-60-7 Not Listed • Graphite 7782-42-5 Not Listed Other Japan - Chemical Substance Control Law (CSCL) - Monitoring Chemical Substances • Stoddard solvent 8052-41-3 Not Listed • Quartz 14808-60-7 Not Listed • Graphite 7782-42-5 Not Listed Japan - Poisonous and Deleterious Substances - Substances Not Considered Deleterious • Stoddard solvent 8052-41-3 Not Listed • Quartz 14808-60-7 Not Listed • Graphite 7782-42-5 Not Listed Japan - Poisonous and Deleterious Substances - Substances Not Considered Poisonous • Stoddard solvent 8052-41-3 Not Listed • Quartz 14808-60-7 Not Listed • Graphite 7782-42-5 Not Listed United States Labor U.S. - OSHA - Process Safety Management - Highly Hazardous Chemicals • Stoddard solvent 8052-41-3 Not Listed • Quartz 14808-60-7 Not Listed • Graphite 7782-42-5 Not Listed U.S. - OSHA - Specifically Regulated Chemicals • Stoddard solvent 8052-41-3 Not Listed • Quartz 14808-60-7 Not Listed • Graphite 7782-42-5 Not Listed Environment U.S. - CAA (Clean Air Act) - 1990 Hazardous Air Pollutants • Stoddard solvent 8052-41-3 Not Listed • Quartz 14808-60-7 Not Listed • Graphite 7782-42-5 Not Listed U.S. - CERCLA/SARA - Hazardous Substances and their Reportable Quantities • Stoddard solvent 8052-41-3 Not Listed Preparation Date: 25/March/2015 Format: EU CLP/REACH Language: English (US) Revision Date: 25/March/2015 WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012 Page 11 of 13 Page 1081 of 1287 Page 1081 of 1287 Page 1081 of 1287 Page 1081 of 1287 ---PAGE BREAK--- SLIP Plate No. 1 • Quartz • Graphite 14808-60-7 7782-42-5 Not Listed Not Listed U.S. - CERCLA/SARA - Radionuclides and Their Reportable Quantities • Stoddard solvent 8052-41-3 Not Listed • Quartz 14808-60-7 Not Listed • Graphite 7782-42-5 Not Listed U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances EPCRA RQs • Stoddard solvent 8052-41-3 Not Listed • Quartz 14808-60-7 Not Listed • Graphite 7782-42-5 Not Listed U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances TPQs • Stoddard solvent 8052-41-3 Not Listed • Quartz 14808-60-7 Not Listed • Graphite 7782-42-5 Not Listed U.S. - CERCLA/SARA - Section 313 - Emission Reporting • Stoddard solvent 8052-41-3 Not Listed • Quartz 14808-60-7 Not Listed • Graphite 7782-42-5 Not Listed U.S. - CERCLA/SARA - Section 313 - PBT Chemical Listing • Stoddard solvent 8052-41-3 Not Listed • Quartz 14808-60-7 Not Listed • Graphite 7782-42-5 Not Listed United States - California Environment U.S. - California - Proposition 65 - Carcinogens List • Stoddard solvent 8052-41-3 Not Listed carcinogen, initial date 10/1/88 • Quartz 14808-60-7 (airborne particles of respirable size) • Graphite 7782-42-5 Not Listed U.S. - California - Proposition 65 - Developmental Toxicity • Stoddard solvent 8052-41-3 Not Listed • Quartz 14808-60-7 Not Listed • Graphite 7782-42-5 Not Listed U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL) • Stoddard solvent 8052-41-3 Not Listed • Quartz 14808-60-7 Not Listed • Graphite 7782-42-5 Not Listed U.S. - California - Proposition 65 - No Significant Risk Levels (NSRL) • Stoddard solvent 8052-41-3 Not Listed • Quartz 14808-60-7 Not Listed • Graphite 7782-42-5 Not Listed U.S. - California - Proposition 65 - Reproductive Toxicity - Female • Stoddard solvent 8052-41-3 Not Listed Preparation Date: 25/March/2015 Format: EU CLP/REACH Language: English (US) Revision Date: 25/March/2015 WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012 Page 12 of 13 Page 1082 of 1287 Page 1082 of 1287 Page 1082 of 1287 Page 1082 of 1287 ---PAGE BREAK--- SLIP Plate No. 1 • Quartz • Graphite 14808-60-7 7782-42-5 Not Listed Not Listed U.S. - California - Proposition 65 - Reproductive Toxicity - Male • Stoddard solvent 8052-41-3 Not Listed • Quartz 14808-60-7 Not Listed • Graphite 7782-42-5 Not Listed 15.2 Chemical Safety Assessment l No Chemical Safety Assessment has been carried out. 15.3 Other Information l WARNING: This product contains a chemical known to the State of California to cause cancer. Section 16 - Other Information Relevant Phrases (code & full text) l H340 - May cause genetic defects. H350 - May cause cancer. H372 - Causes damage to organs through prolonged or repeated exposure. R45 - May cause cancer. R46 - May cause heritable genetic damage. R49 - May cause cancer by inhalation. Last Revision Date l 25/March/2015 Preparation Date l 25/March/2015 Disclaimer/Statement of Liability Key to abbreviations NDA = No data available l The information contained herein is based on data available. However, no warranty is expressed or implied regarding the accuracy of the data or the results obtained from the use thereof. Because the information contained herein may be applied under conditions beyond our control, we assume no responsibility for its use. Preparation Date: 25/March/2015 Format: EU CLP/REACH Language: English (US) Revision Date: 25/March/2015 WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012 Page 13 of 13 Page 1083 of 1287 Page 1083 of 1287 Page 1083 of 1287 Page 1083 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET Spectrum Group Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Spectracide Wasp & Hornet Killer3 1-[PHONE REDACTED] HG-75715; HG-95715-3; HG-95865 21-1058, 21-0666, 01-1006 Page 1 SDS Date: 2/17/2015 Product Name: Spectracide Wasp & Hornet Killer3 EPA Reg. No. 9688-190-8845 CAS Aerosol Product Use: Wasp & Hornet Killer Aerosol Manufacturer: Chemsico Div. of United Industries Corp P.O. Box 142642 St. Louis, MO 63114 This product is classified according to the Global Harmonization System (GHS) ROUTES OF EXPOSURE Potential short term health effects: Eye, Skin contact, Ingestion. Eyes: No expected reaction. Skin: May cause irritation. Inhalation: No expected reaction. Ingestion: May cause stomach distress, nausea or vomiting. Target organs: Eyes, Skin, & Respiratory system. Chronic effects: Prolonged or repeated exposure can cause drying, defatting and dermatitis. Signs and may include redness, edema, drying, defatting and cracking of the skin. Composition comments: This product is considered not hazardous under 29 CFR 1910.1200 (Hazard Communication). NOTE: No reportable quantities of hazardous ingredients are present per OSHA 29 CFR 1910.1200. No toxic chemical(s) subject to reporting requirements of Section 313 of Title III and 40 CFR 372 are present. ACTIVE COMPONENT CAS# PERCENTAGE Lambda-cyhalothrin 91465-08-6 0.010% Prallethrin 23031-36-9 0.025% Petroleum Distillates 64742-47-8 3.500% Butyl Propasol 5131-66-8 3.000% Propane 74-98-6 3.500% SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION SECTION 2 - HAZARDS IDENTIFICATION SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS Page 1084 of 1287 Page 1084 of 1287 Page 1084 of 1287 Page 1084 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET Spectrum Group Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Spectracide Wasp & Hornet Killer3 1-[PHONE REDACTED] HG-75715; HG-95715-3; HG-95865 21-1058, 21-0666, 01-1006 Page 2 OTHER COMPONENT CAS# PERCENTAGE Other N/A 89.965 Note: Ingredients not identified are not hazardous FIRST AID PROCEDURES Eye contact: Not required Skin contact: Flush with large amounts of cool water. Wash with soap and water. Remove contaminated clothing and wash before reuse. Obtain medical attention if irritation persists. Inhalation: Not required. Ingestion: Immediately call a Poison Control Center or doctor. Do not induce vomiting unless told to do so by a Poison Control Center. Do not give any liquid to the person. Do not give anything by mouth to an unconscious person. Note to Physician: may be delayed. General advice: If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Keep out of reach of children. Flammable properties: Pressurized Aerosol Container SUITABLE EXTINGUISHING MEDIA Extinguishing media: Water Fog, Foam, CO2, Dry Chemical Unsuitable extinguishing media: Not Available. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL Protection of firefighters: Not Available. Protective equipment for firefighters: Firefighters should wear full protective clothing including self-contained breathing apparatus. Hazardous combustion products: None known. SENSITIVITY TO MECHANICAL IMPACT Explosion data: Not Available. Sensitivity to static discharge: Not Available. Personal precautions: Keep unnecessary personnel away. Do not touch or walk through spilled material. SECTION 4 - FIRST AID MEASURES SECTION 5 - FIRE FIGHTING MEASURES Page 1085 of 1287 Page 1085 of 1287 Page 1085 of 1287 Page 1085 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET Spectrum Group Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Spectracide Wasp & Hornet Killer3 1-[PHONE REDACTED] HG-75715; HG-95715-3; HG-95865 21-1058, 21-0666, 01-1006 Page 3 HMIS Ratings Health Hazard 1 Fire Hazard 2 Reactivity 0 Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with earth, sand or absorbent material swept up and placed in suitable, covered, and labeled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills in original containers for re-use. Handling: Use good industrial hygiene practices in handling this material. Storage: Keep out of reach of children. Store in a closed container away from incompatible materials. Engineering controls: General ventilation normally adequate. EYE / FACE PROTECTION Personal protective equipment: None required Hand protection: None required Skin and body protection: None required Respiratory protection: None required General hygiene considerations: Handle in accordance with good industrial hygiene and safety practice. When using, do not eat or drink. Wash hands before breaks and immediately after handling the product. Appearance: Clear Color: light yellow to water-white Form: Aerosol Odor: Aromatic solvent (slight) Odor threshold: Not Available. Physical state: Pressurized Liquid pH: 5-6 SECTION 6 - ACCIDENTAL RELEASE MEASURES SECTION 7 - HANDLING AND STORAGE SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES Page 1086 of 1287 Page 1086 of 1287 Page 1086 of 1287 Page 1086 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET Spectrum Group Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Spectracide Wasp & Hornet Killer3 1-[PHONE REDACTED] HG-75715; HG-95715-3; HG-95865 21-1058, 21-0666, 01-1006 Page 4 Freezing point: 32°F Boiling point: 212°F Flash point: 1190F (liquid portion) Flame Extension 0” (level 1 aerosol) Flammability limits in air, lower, % by volume: Not Available.. Flammability limits in air, upper, % by volume: Not Available. Vapor pressure: Not Available. Vapor density: Not Available. Specific gravity: 0.973 Octanol/water coefficient: Not Available. Auto-ignition temperature: Not Available. Chemical stability: Stable under recommended storage conditions. Conditions to avoid: Do not mix with other chemicals. Incompatible materials: Avoid strong oxidizers. Hazardous decomposition products: None known. Possibility of hazardous reactions: Hazardous polymerization does not occur. EFFECTS OF ACUTE EXPOSURE Eye: none expected Skin: May cause irritation Inhalation: LC50 > 2mg/L (EPA Tox category IV) Ingestion: LD50 > 5000 mg/kg Sensitization: Not a skin sensitizer Chronic effects/ Carcinogenicity: Not Available. Mutagenicity: Not Available. Reproductive effects: Not Available. Teratogenicity: Not Available. Ecotoxicity: Not Available. Environmental effects: Not Available. Aquatic toxicity: Toxic to aquatic organisms SECTION 10 - CHEMICAL STABILITY & REACTIVITY INFORMATION SECTION 11 - TOXICOLOGICAL INFORMATION SECTION 12 - ECOLOGICAL INFORMATION Page 1087 of 1287 Page 1087 of 1287 Page 1087 of 1287 Page 1087 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET Spectrum Group Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Spectracide Wasp & Hornet Killer3 1-[PHONE REDACTED] HG-75715; HG-95715-3; HG-95865 21-1058, 21-0666, 01-1006 Page 5 Persistence / degradability: Not Available. Bioaccumulation / accumulation: Not Available. Partition coefficient: Not Available. Mobility in environmental media: Not Available. Chemical fate information: Not Available. Waste codes: Not Available. Disposal instructions: Dispose in accordance with all applicable regulations. Waste from residues / unused products: Not Available. Contaminated packaging: Not Available. U.S. Department of Transportation (DOT): Aerosols, Flammable 2.1, UN-1950, Limited Quantity U.S. Federal regulations: This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. IATA: 1950, Aerosols, Flammable, 2.1 IMDG: 1950, Aerosols, Flammable, 2.1,(lambda-cyhlaothrin), Marine Pollutant, Limited Quantity 29 CFR 1910.1200 hazardous chemical Occupational Safety and Health Administration (OSHA): No CERCLA (Superfund) reportable quantity: Not Available. HAZARD CATEGORIES Superfund Amendments and Reauthorization Act of 1986 (SARA): Immediate Hazard No Delayed Hazard No Fire Hazard No Pressure Hazard No Reactivity Hazard No Section 302 extremely hazardous Substance: No Section 311 hazardous chemical: No Clean Air Act (CAA): Not Available. Clean Water Act (CWA): Not Available. SECTION 13 - DISPOSAL CONSIDERATIONS SECTION 14 - TRANSPORTATION INFORMATION SECTION 15 - REGULATORY INFORMATION Page 1088 of 1287 Page 1088 of 1287 Page 1088 of 1287 Page 1088 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET Spectrum Group Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Spectracide Wasp & Hornet Killer3 1-[PHONE REDACTED] HG-75715; HG-95715-3; HG-95865 21-1058, 21-0666, 01-1006 Page 6 State regulations: INVENTORY STATUS Inventory Country(s) or region name on inventory (yes/no)*: N/A, Regulated by EPA Disclaimer: Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. Issue date: 2/17/2015 Prepared by: United Industries Corp. (800) 242 1166 SECTION 16 - OTHER INFORMATION Page 1089 of 1287 Page 1089 of 1287 Page 1089 of 1287 Page 1089 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Total Solutions P.O. Box 240014 Milwaukee, WI 53224 GENERAL INFORMATION NUMBER: (414) 354-6417 REVISION DATE: March 23, 2004 CHEMTREC: (800) 424-9300 DATE OF ISSUE: March 31, 2004 I - Product Identification Stainless Steel Cleaner PRODUCT CODE: 8306 CHEMICAL FORMULATION: Pressurized oil based cleaner. NFPA HAZARD IDENTIFICATION SYSTEM: HEALTH: 2 FLAMMABILITY: 4 REACTIVITY: 0 HAZARD RATING: 4 - Extreme; 3 - High; 2 - Moderate; 1 - Slight; 0 - Insignificant II - Hazardous Ingredients Values reported as TWA unless noted. EPA 40 CFR: SUBSTANCE APPROX % OSHA PEL ACGIH TLV 302 355 372 CAS # Isoparaffinic Solvent 40.0-50.0 N/E N/E N N N 64741-66-8 Mineral Spirits 20.0-30.0 N/E N/E N N N 64741-65-7 Mineral Oil 10.0-20.0 N/E N/E N N N 8042-47-5 Propane (Propellant) 10.0-20.0 1000 ppm 2500 ppm N N N 74-98-6 Key: PEL: Permissible Exposure Limit TLV: Threshold Limit Value C: Ceiling level STEL: Short Term Exposure Limit N/A: Not Applicable N/D: Not Determined N/E: Not Established Y: Yes N: No 302: CERCLA List of Hazardous Substances and Reportable Quantities (40 CFR 302.4). 355: SARA TITLE III / List of Extremely Hazardous Substances for Emergency Planning and Notification (40 CFR 355). 372: SARA TITLE III / List of Toxic Chemicals subject to Release Reporting (Community Right to Know) (40 CFR 372). III - Physical Data BOILING POINT N/D SPECIFIC GRAVITY (WATER = < 1.00 VAPOR PRESSURE (mm Hg): N/D VOC CONTENT by weight): N/D VAPOR DENSITY (AIR = > 1.0 EVAPORATION RATE (WATER = N/D SOLUBILITY IN WATER: Negligible pH: N/A APPEARANCE AND ODOR: Clear liquid; hydrocarbon odor. IV - Fire and Explosion Hazard Data FLASH POINT > 80 (liquid component of aerosol) (TEST METHOD): T.O.C. FLAME EXTENSION: N/D FLAMMABLE LIMITS IN AIR (VOLUME UPPER: 9.5 LOWER: 2.2 EXTINGUISHING MEDIA: Dry chemical, foam, carbon dioxide. NFPA 30B Rating: 3 SPECIAL FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water fog. Firefighters should be equipped with full protective gear including self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARD: Contents under pressure. Exposure to temperatures above 120o F may cause bursting. Page 1090 of 1287 Page 1090 of 1287 Page 1090 of 1287 Page 1090 of 1287 ---PAGE BREAK--- PRODUCT NAME: Stainless Steel Cleaner PRODUCT CODE: 8306 V - Reactivity Data STABILITY: Stable INCOMPATIBILITY: Strong oxidizers. CONDITIONS TO AVOID: Heat, direct sunlight, open flames or sparks. Dropping of containers may cause bursting. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may produce oxides of carbon and additional hazardous chemicals may be formed in small amounts. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: None VI - Health Hazard Data ROUTES OF ENTRY INHALATION: X EYE CONTACT: X SKIN CONTACT: X INGESTION: INGREDIENTS THAT ARE CONSIDERED BY OSHA, NTP, IARC TO BE SUSPECTED HUMAN CARCINOGENS: None EFFECTS OF OVEREXPOSURE IF IN EYES: Moderate irritation and redness. Preexisting eye condition may be aggravated by exposure to this product. IF ON SKIN: Moderate irritation, defatting and dermatitis with prolonged or repeated exposure. Preexisting skin condition may be aggravated by exposure to this product. IF SWALLOWED: May result in vomiting, which could lead to aspiration of product. May be harmful or fatal if swallowed. IF INHALED: CNS depression, headache, giddiness, nausea. EMERGENCY AND FIRST AID PROCEDURES IF IN EYES: Flush eyes and under eyelids with plenty of cool water for at least 15 minutes. If irritation persists, obtain medical attention. IF ON SKIN: Flush skin with water while removing contaminated clothing. Wash skin with soap and water. Launder clothes separately before reuse. If irritation persists, obtain medical attention. IF SWALLOWED: Contact physician or poison control center immediately. Breathing of vomitus into the lungs must be avoided as even small quantities may result in aspiration pneumonitis. IF INHALED: Remove person to fresh air. If breathing has stopped, administer artificial respiration. Give oxygen if breathing is difficult. Obtain medical attention. VII - Spill or Leak Protection STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Ventilate area. Remove all sources of ignition. Soak up material with inert absorbent material and place in a labeled closed container for disposal. WASTE DISPOSAL METHOD: Consult local environmental authorities. Dispose of cans in non-incinerated trash only. VIII - Special Protection Information RESPIRATORY PROTECTION: Use with adequate ventilation. Do not breathe vapors or mists. If recommended Exposure Limits are exceeded, wear a NIOSH approved respirator, following manufacturer’s recommendations. VENTILATION LOCAL: Recommended MECHANICAL: Not required PROTECTIVE GLOVES: Chemical resistant. EYE PROTECTION: Safety glasses. OTHER PROTECTIVE EQUIPMENT: Protective clothing. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in a cool, dry place away from heat, sparks or open flame. Do not expose to direct sunlight or store at temperatures above 120 F. OTHER PRECAUTIONS: Keep out of reach of children. Do not puncture or incinerate container. IX - Transportation Information (ground transportation only) DOT PROPER SHIPPING NAME: Consumer Commodity DOT CLASS: ORM-D DOT ID NUMBER: None DOT PACKING GROUP: None The shipping information listed above applies only to non-bulk 119 gallons) containers of this product. This product may have more than one proper shipping name depending on packaging, product properties, & mode of shipment. If any alteration of packaging, product, or mode of transportation is further intended, different shipping names and labeling may apply. REVISION DATE: March 23, 2004 Prepared by: PMR DATE OF ISSUE: March 31, 2004 This information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Total Solutions assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material such vendees or users assume all risks associated with the use of this material. Page 1091 of 1287 Page 1091 of 1287 Page 1091 of 1287 Page 1091 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Total Solutions P.O. Box 240014 Milwaukee, WI 53224 GENERAL INFORMATION NUMBER: (414) 354-6417 REVISION DATE: January 9, 2013 CHEMTREC: (800) 424-9300 DATE OF ISSUE: February 22, 2013 I - Product Identification Stainless Steel Cleaner Wipes PRODUCT CODE: 1549 CHEMICAL FORMULATION: Premoistened cleaning towel. NFPA HAZARD IDENTIFICATION SYSTEM: HEALTH: 1 FLAMMABILITY: 2 REACTIVITY: 0 HAZARD RATING: 4 - Extreme; 3 - High; 2 - Moderate; 1 - Slight; 0 - Insignificant II - Hazardous Ingredients Values reported as TWA unless noted. SUBSTANCE APPROX % OSHA PEL ACGIH TLV EPA 40 CFR: CAS # 302 355 372 Isoparaffinic Hydrocarbon 50.0-60.0 5 mg/m3 5 mg/m3 N N N 64742-47-8 White Mineral Oil 30.0-40.0 5 mg/m3 5 mg/m3 N N N 8042-47-5 D-limonene < 5.0 N/D N/D N N N 5989-27-5 Key: PEL: Permissible Exposure Limit TLV: Threshold Limit Value C: Ceiling level STEL: Short Term Exposure Limit N/A: Not Applicable N/D: Not Determined N/E: Not Established Y: Yes N: No 302: CERCLA List of Hazardous Substances and Reportable Quantities (40 CFR 302.4). 355: SARA TITLE III / List of Extremely Hazardous Substances for Emergency Planning and Notification (40 CFR 355). 372: SARA TITLE III / List of Toxic Chemicals subject to Release Reporting (Community Right to Know) (40 CFR 372). III - Physical Data BOILING POINT N/D SPECIFIC GRAVITY (WATER = 0.81* VAPOR PRESSURE (mm Hg): N/D VOC CONTENT by weight): < 3.0* VAPOR DENSITY (AIR = N/D EVAPORATION RATE (WATER = N/D SOLUBILITY IN WATER: Insoluble* pH: N/A APPEARANCE AND ODOR: Purple cloth impregnated with a clear, yellow liquid; citrus scent. *Tested using the liquid component of the towelette. IV - Fire and Explosion Hazard Data FLASH POINT 197* (TEST METHOD): Closed cup FLAMMABLE LIMITS IN AIR (VOLUME UPPER: N/D LOWER: N/D EXTINGUISHING MEDIA: Water fog, foam, carbon dioxide, dry chemical. SPECIAL FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water fog. Firefighters should be equipped with full protective gear including self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARD: None *Tested using the liquid component of the towelette. Page 1092 of 1287 Page 1092 of 1287 Page 1092 of 1287 Page 1092 of 1287 ---PAGE BREAK--- PRODUCT NAME: Stainless Steel Cleaner Wipes PRODUCT CODE: 1549 V - Reactivity Data STABILITY: Stable INCOMPATIBILITY: Oxidizers. CONDITIONS TO AVOID: Excess heat and open flame. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may produce oxides of carbon. HAZARDOUS POLYMERIZATION: Will not occur. CONDTIONS TO AVOID: None VI - Health Hazard Data ROUTES OF ENTRY INHALATION: EYE CONTACT: X SKIN CONTACT: X INGESTION: INGREDIENTS THAT ARE CONSIDERED BY OSHA, NTP, IARC TO BE SUSPECTED HUMAN CARCINOGENS: None EFFECTS OF OVEREXPOSURE IF IN EYES: Moderate to severe irritation and redness. IF ON SKIN: Redness, dryness and irritation, with prolonged or repeated exposure. May cause allergic skin reaction. IF SWALLOWED: Not expected to be a route of exposure. Aspiration hazard. Has the potential to be harmful or fatal if the liquid is swallowed. Can enter lungs and cause damage. IF INHALED: No hazard under normal use. Over exposure may cause headache, nausea, nasal and respiratory irritation, drowsiness and fatigue. EMERGENCY AND FIRST AID PROCEDURES IF IN EYES: Flush eyes and under eyelids with plenty of cool water for at least 15 minutes. If irritation persists, obtain medical attention. IF ON SKIN: Wash with soap and water. If irritation persists, obtain medical attention. IF SWALLOWED: Contact physician or poison control center immediately. Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. IF INHALED: Remove person to fresh air. VII - Spill or Leak Protection STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Ventilate area. Remove all sources of ignition. Soak up material with inert absorbent material and place in a labeled closed container for disposal. WASTE DISPOSAL METHOD: Consult local environmental authorities. VIII - Special Protection Information RESPIRATORY PROTECTION: Use with adequate ventilation. If recommended Exposure Limits are exceeded wear a NIOSH approved respirator, following manufacturer’s recommendations. VENTILATION LOCAL: Recommended MECHANICAL: Not required PROTECTIVE GLOVES: Chemical resistant. EYE PROTECTION: Safety glasses. OTHER PROTECTIVE EQUIPMENT: None. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in a cool, dry place away from heat or open flame. Keep container closed when not in use. OTHER PRECAUTIONS: Keep out of reach of children. IX - Transportation Information (ground transportation only) DOT ID NUMBER: None DOT PROPER SHIPPING NAME: None DOT CLASS: None DOT PACKING GROUP: None The shipping information listed above applies only to non-bulk 119 gallons) containers of this product. This product may have more than one proper shipping name depending on packaging, product properties, & mode of shipment. If any alteration of packaging, product, or mode of transportation is further intended, different shipping names and labeling may apply. REVISION DATE: January 9, 2013 Prepared by: Technical Dept. DATE OF ISSUE: February 22, 2013 This information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Total Solutions assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material. Such vendees or users assume all risks associated with the use of this material. Page 1093 of 1287 Page 1093 of 1287 Page 1093 of 1287 Page 1093 of 1287 ---PAGE BREAK--- Page 1 of 5 MATERIAL SAFETY DATA SHEET SECTION I - PRODUCT INFORMATION Trade Name Appearing on Label: STATIC GUARD CATALOG NUMBER: XS-3 & XS-6 Manufacturer: ALBERTO-CULVER COMPANY Emergency Phone: (708) 450-3175 Business Phone: (708) 450-3135 Name of Preparer: ALBERTO-CULVER COMPANY 2525 Armitage Avenue Melrose Park, Illinois 60160 Date Prepared: 15 February 1993 Date Revised: October 20, 2000 SECTION II- INGREDIENTS Chemical Identity CAS Numbers Approx % Exposure Limits in Air TSCA OSHA (PEL) ACGIH (TLV) Listed SD Alcohol 40 000064-17-5 70 1000 ppm 1000ppm Yes Ditallowdimonium Chloride 068783-78-8 <2 Not Avail. Not Avail. Yes Isopropyl Alcohol 000067-63-0 <1 400 ppm 400 ppm Yes Ammonium Acetate 000631-61-8 <1 NotAvail. Not Avail. Yes Isobutane 000075-28-5 15 Not Avail. Not Avail. Yes Propane 000074-98-6 12 1000 ppm Not Avail. Yes Fragrance None Not Avail. Not Avail Yes Chloromethane 000074-87-3 0.0004 Max 50 ppm TWA 50 ppm TWA if present 100 ppm STEL 100 ppm STEL Yes SECTION III - PHYSICAL CHARACTERISTICS Physical Form: Aerosol Anti-Static Spray Specific Gravity: 0.79-0.80 (Concentrate) Boiling Point: 173-181 Degrees F (Aerosol Concentrate-Ethanol) Melting Point: N/A Apparent pH: 7.5-8.5 Water Solubility: Concentrate 100% soluble Vapor Density (air=1): Greater than 1 Appearance: Aerosol Spray-Clear Colorless Liquid Evaporation Rate (Ethyl Alcohol=1): 1 Odor: Characteristic Aerosol Can Pressure: 60 psig HAZARDOUS MATERIAL IDENTIFICATION SYSTEM RATINGS (HMIS) For Total Product - Normal Usage Page 1094 of 1287 Page 1094 of 1287 Page 1094 of 1287 Page 1094 of 1287 ---PAGE BREAK--- Page 2 of 5 Rating Scale for Hazard Determination: 0 Minimal 1 Slight 2 Moderate 3 Serious 4 Severe Product Rating: Health: 1 Flammability: 4 Reactivity: 1 Personal Protection: Safety Glasses (Do Not Spray Product into eyes) SECTION IV - FIRE AND EXPLOSION DATA Flash Point: 56 Degrees F (Aerosol Concentrate-Ethanol) Method used: TCC Auto Ignition Temperature: 685 Degrees F (Ethanol) Flammable Limits in Air, % Volume LEL: 3.3% UEL: 19.0% Concentrate LEL: 1.8% UEL: 9.5% Propellant Extinguishing Media Water Spray _X_Foam _X_Carbon Dioxide Dry Chemical ___Other (specify) Special Fire Fighting Procedures: WARNING. FLAMMABLE LIQUID AND GAS. Clear fire area of unprotected personnel. Do not enter confined fire space without full bunker gear (helmet with face shield, bunker coats, gloves and rubber boots), including a positive pressure NIOSH approved self-contained breathing apparatus. Unusual Fire and Explosion Hazards: Containers exposed to intense heat from fires should be cooled with water to prevent vapor pressure buildup which could result in container explosion and rocketing. Container areas exposed to direct flame contact should be cooled with large quantities of water as needed to prevent explosion and rocketing of aerosol cans. SECTION V - REACTIVITY Stability Stable: Unstable Conditions to Avoid: N/A Incompatibility (materials to avoid): Materials damaged by Ethyl Alcohol Hazardous Decomposition or Byproducts: Carbon Monoxide, Nitrogen compounds, Carbon Dioxide, Hydrogen Chloride and unidentified orgainic compounds may be formed during combustion. Hazardous Polymerization: will not occur. Conditions to Avoid: Ignition sources SECTION VI - HEALTH HAZARDS Route(s) of Entry Inhalation: Skin: Ingestion: Health Hazards: Acute: Product may cause moderate to severe eye irritation. Vapors may cause slight irritation ot mucous membranes. High vapor concentrations may cause CNS depression. Chronic: Studies in laboratory animals involving prolonged and repeated exposures to ethyl alcohol have resulted in such effects as liver damage, embryotoxicity, fetotoxidity, and teratogenicity. A transient mutagenic effect has been reported in rats. Page 1095 of 1287 Page 1095 of 1287 Page 1095 of 1287 Page 1095 of 1287 ---PAGE BREAK--- Page 3 of 5 N/A IARC Monographs: N/A OSHA Registered: N/A Signs and of Exposure: CNS depression may be evidenced by giddiness, headache, dizziness and nausea. Medical Conditions Generally Aggravated by Exposure: Prolonged exposure may aggravate preexisting eye, skin and respiratory disorders. Impaired liver function from preexisting disorders may also be aggravated. EMERGENCY AND FIRST AID TREATMENT Eye Contact: Rinse well with plenty of running water for at least 15 minutes. Seek medical attention if irritation persists. Skin Contact: Product is intended to be left on clothing. No special precautions necessary for incidental contact. Soap and water can be used to remove product from the skin. Inhalation: Move victim to fresh air if necessary. Ingestion: If ingestion occurs seek medical attention. SECTION VII - ENVIRONMENTAL PROTECTION SPILL OR LEAK PROCEDURES WARNING. FLAMMABLE LIQUID AND GAS. ELIMINATE ALL IGNITION SOURCES. Handling equipment must be grounded to prevent sparking. LARGE SPILLS*** Evacuate the hazard area of unprotected personnel. Wear appropriate respirator and protective clothing. Shut off source of leak only if safe to do so. Dike and contain. If vapor cloud forms, water fog may be used to suppress; contain run-off. Remove with vacuum trucks or pump to storage/salvage vessels. Soak up residue with an absorbent such as clay, sand or other suitable material; place in non-leaking containers for appropriate disposal. Flush area with water to remove trace residue; dispose of flush solutions as above. SMALL SPILLS Take up with an absorbent material and place in non-leaking containers; seal for proper disposal. SECTION VII - ENVIRONMENTAL PROTECTION - CONTINUED WASTE DISPOSAL A small number of empty containers can be disposed of in ordinary trash. For disposal of a large number of empty containers or full containers contact a licensed waste hauler. Under EPA-RCRA (40 CFR 261.21), if this product becomes a waste material, it would be ignitible hazardous waste, hazardous waste number D001. Refer to latest EPA or State regulations regarding proper disposal. ENVIRONMENTAL HAZARDS EPA- Comprehensive Environmental Response, Compensation and Liability Act. Under EPA-CERCLA ("superfund") releases to air, land or water may be reportable to the National Response Center, [PHONE REDACTED] Page 1096 of 1287 Page 1096 of 1287 Page 1096 of 1287 Page 1096 of 1287 ---PAGE BREAK--- Page 4 of 5 (circumstances surrounding the release and cleanup determine reportability). SARA TITLE III DATA Section 312 Hazard Categories Fire Ix I Sudden Release of Pressure Ix I Reactivity I I Immediate (Acute) Ix I Delayed (Chronic) I I SECTION 313 TOXIC CHEMICAL NOTIFICATION This proprietary formula contains toxic chemical subject to the reporting requirements of Section 313 of Title III of Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: (Generic) Chemical Name Concentration by weight) (None) (None) SECTION VIII - CONTROL MEASURES Specified Respiratory Protection: None required for normal usage. Ventilation required: Spark proof solvent ventilation may be required if large amounts of product are expelled. Protective Gloves: None required Eye Protection: Keep out of eyes. Other Protective Equipment: N/A Work/Hygenic Practices: N/A SECTION IX - SAFE HANDLING AND STORAGE Precautions to be Taken in Handling and Storage: Cool dry storage away from ignition sources at temperatures below 120 degrees F. Keep out of reach of children. Level 2 Aerosol Other Precautions: N/A SECTION X - TRANSPORTATION REQUIREMENTS US SHIPPING (DOT): FINISHED PRODUCT, CONSUMER COMMODITY PURPOSES ONLY Hazardous materials description and proper shipping name: Consumer Commodity Hazard class: ORM-D Identification number: N/A Labels required: N/A INTERNATIONAL SHIPPING BY AIR (IATA): FINISHED PRODUCT, CONSUMER COMMODITY PURPOSES ONLY Hazardous Materials Description and Proper Shipping Name: Consumer Commodity Hazerd Class: 9 IATA Identification Number: UN8000 IATA Packing Instruction: #910 Labels Required: Miscellaneous INTERNATIONAL SHIPPING BY OCEAN (IMO): FINISHED PRODUCT, CONSUMER COMMODITY (Household Use or Personal Care) PURPOSES ONLY Page 1097 of 1287 Page 1097 of 1287 Page 1097 of 1287 Page 1097 of 1287 ---PAGE BREAK--- Page 5 of 5 Hazardous materials description and proper shipping name: Aerosols Dangerous Goods in Limited Quantity Hazard class: 2 Identification number: UN1950 Packing Group: N/A Labels required: (none required if limited quantities otherwise FLAMMABLE GAS); Package should be marked "Aerosol" For shipping to any destination, appropriate packaging materials must be used. See UPS Guide for Shipping Ground and Air Hazardous Materials, IATA Dangerous Goods Regulations (39th Edition), US Dept. of Transportation Regulations in 49 CFR 172. et seq., IMO and ICAO guidelines. If shipping "Limited Quantities" follow appropriate regulations. Notice: The information presented herein is based on experimental data submitted by the manufacturers of the raw materials and is considered scientifically correct, however, no warranty, expressly implied or otherwise, is made to the accuracy or suitability of this information to the purchaser's intended purpose or for consequences of its use. Use these materials only as directed. For further information concerning product safety and use, call the number listed on the front of the MSDS. Page 1098 of 1287 Page 1098 of 1287 Page 1098 of 1287 Page 1098 of 1287 ---PAGE BREAK--- 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND SUPPLIER Product Name: Straitline Marking Chalk Blue Other Names: Sodium Aluminium Sulfosilicate, Pigment Blue 29, C.I. 77007 Recommended use: Blue pigment for line marking applications. Supplier: Irwin Industrial Tool Company Pty Ltd ABN: 30 005 543 966 Address: 2 National Drive VIC 3975 Australia Telephone: +61 8 9277 5277 (WA) or +61 3 8787 3888 (all other states) Facsimile: +61 8 9277 6277 (WA) or +61 3 8787 3800 (all other states) Emergency Phone: (08) 9277 5277 (WA: 8.30 am – 5 pm) or (03) 8787 3888 (Vic: 8 am – 6 pm) 2. HAZARDS IDENTIFICATION NON-HAZARDOUS SUBSTANCE – NON-DANGEROUS GOOD DG Class: None allocated Subsidiary Risk: None allocated Packing Group: None allocated Risk phrases: None allocated Safety phrases: None allocated 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical identity CAS Number Proportion C.I. Pigment Blue 29 57455-37-5 100 % by weight All components in this product are listed on the Australian Inventory of Chemical Substances (AICS). Material Safety Data Sheet Straitline Marking Chalk Blue Issued: 10.06.2006 Version 1.0 Page 1 of 6 Page 1099 of 1287 Page 1099 of 1287 Page 1099 of 1287 Page 1099 of 1287 ---PAGE BREAK--- 4. FIRST AID MEASURES A low hazard solid. Inhalation of dust may cause slight, temporary breathing difficulties. Swallowed: Not considered a normal route of exposure. Never give anything by mouth to an unconscious person. Do not induce vomiting unless directed to do so by a physician. Adverse effects not anticipated. Eye: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Seek medical advice. Skin: Immediately wash skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and shoes and thoroughly clean before re-use. Seek medical advice. Inhaled: Remove to fresh air immediately. If not breathing, give artificial respiration. If breathing difficulties are experienced, give oxygen. Seek medical advice. Notes to doctor: Treat and supportively. 5. FIRE FIGHTING MEASURES Specific hazards: Non-combustible solid. Will not burn in a fire. Not considered to be a fire hazard. Extinguishing media: Water, dry chemical foam or alcohol-resistant foam. Use extinguishing agents appropriate for surrounding combustible materials. Fire fighting procedures: As with any fire, wear full protective clothing and approved self-contained breathing apparatus with full face-mask. If safe to do so, remove containers from path of fire. Continue to cool fire exposed containers with water until well after flames are extinguished. Hazardous Decomposition Products: Sulfur dioxide gas may be released. Hazchem Code: None allocated 6. ACCIDENTAL RELEASE MEASURES Take precautionary measures against static discharges. Evacuate all personnel from the affected area. Ventilate area well and ensure appropriate personal protective equipment is worn. Refer Section 8. Sweep or scoop up all spills and place in suitable marked containers for re-use or disposal. Advise the appropriate authorities if any material has leaked into drains, waterways, sewer, etc. Material Safety Data Sheet Straitline Marking Chalk Blue Issued: 10.06.2006 Version 1.0 Page 2 of 6 Page 1100 of 1287 Page 1100 of 1287 Page 1100 of 1287 Page 1100 of 1287 ---PAGE BREAK--- 7. HANDLING AND STORAGE Handling: Avoid breathing dust. Avoid contact with skin and eyes. Wash hands and face thoroughly after handling product. Keep container closed. Wear appropriate personal protective equipment as specified in Section 8. Storage: Store in a closed container in a cool, dry location. Ensure storage area is well-ventilated. Keep containers closed at all times – check regularly for leaks. Do not smoke in areas of use or storage. Avoid dust generation. Store away from heat sources, combustible materials and moisture. Incompatibilities: Hydrogen sulfide may be released in contact with acids. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION National occupational exposure standards Substance TWA STEL Carcinogen Category Notices Total dusts - - 10 mg/m3 None allocated None allocated None allocated None allocated As published by National Occupational Health and Safety Commission. Engineering controls: Local exhaust ventilation and/or mechanical (dust) exhaust is recommended, provided these are fitted with flame and explosion proof electrical fittings. Keep containers closed when not in use. Use adequate ventilation to keep airborne concentrations low. Personal Protection Skin: Avoid skin contact by the use of appropriate protective clothing and PVC gloves to prevent skin exposure. Eye: Avoid eye contact by wearing eye protection, e.g. protective safety glasses with side-shields or chemical safety goggles. Respiratory: Wear an approved disposable dust mask with filter class P1 or P2 if dust exposure is likely or expected. Do not smoke while handling product. Ensure adequate ventilation. Ensure eyewash station and safety shower are readily available and tested regularly. Material Safety Data Sheet Straitline Marking Chalk Blue Issued: 10.06.2006 Version 1.0 Page 3 of 6 Page 1101 of 1287 Page 1101 of 1287 Page 1101 of 1287 Page 1101 of 1287 ---PAGE BREAK--- 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: blue solid with no odour Boiling Point: no data available Melting Point: > 1000°C Vapour pressure: not applicable Specific gravity: 2.35 g/cm3 Flash Point: non-flammable pH: 7 – 9 (100 g/L) Flammability Limits: % by volume lower: not applicable % by volume upper: not applicable Autoignition temperature: no data available Solubility in water: insoluble Vapour Density: not applicable 10. STABILITY AND REACTIVITY Chemical stability: Stable under normal temperatures and pressures. Hazardous polymerization: None. Incompatible materials: Hydrogen sulfide may be released into contact with acids. Conditions to avoid: Sulfur dioxide gas is released at temperatures above 400°C. Hazardous decomposition products: Sulfur dioxide, hydrogen sulfide. 11. TOXICOLOGICAL INFORMATION Swallowed: Not considered a likely route of exposure. May cause harmful effects if large amounts are ingested. May also cause gastrointestinal tract irritation with nausea, vomiting and diarrhoea. Eye: Contact with eyes may cause slight, temporary irritation. Skin: Contact with skin may cause slight, temporary irritation. May cause an allergic reaction in certain individuals. Inhaled: Inhalation of dust may result in slight, temporary respiratory irritation. Chronic: Prolonged or repeated exposure may cause severe irritation and dermatitis. Repeated inhalation of product may cause chronic bronchitis. Acute toxicity: LD50/oral/rat: > 10 g/kg Carcinogenicity: Not a human carcinogen Mutagenicity: Not mutagenic Teratogenicity: Not teratogenic Reproductive: Not toxic for reproduction 12. ECOLOGICAL INFORMATION Ecotoxicity: Toxicity to fish (acute): LC50 >32000 mg/L Environmental fate: This material is not expected to biodegrade when released into the soil. This material is not expected to significantly bioaccumulate. Material Safety Data Sheet Straitline Marking Chalk Blue Issued: 10.06.2006 Version 1.0 Page 4 of 6 Page 1102 of 1287 Page 1102 of 1287 Page 1102 of 1287 Page 1102 of 1287 ---PAGE BREAK--- 13. DISPOSAL CONSIDERATIONS Suitable for incineration by approved agent under controlled conditions if permitted by local authorities, otherwise disposal of containers and contents to approved landfill must be in accordance with local waste authority requirements. Product must not be disposed to sewerage systems, drains or waterways. 14. TRANSPORT INFORMATION Road and Rail Transport (Australian Dangerous Goods Code): UN Number: None allocated Proper Shipping Name: None allocated Class: None allocated Hazchem Code: None allocated Packing Group: None allocated Marine Transport (International Maritime Dangerous Goods Code): UN Number: None allocated Proper Shipping Name: None allocated Class: None allocated Packing Group: None allocated Marine Pollutant: No Air Transport (International Air Transport Association Dangerous Goods Regulations): UN Number: None allocated Proper Shipping Name: None allocated Class: None allocated Subsidiary Risk: None allocated Packing Group: None allocated Limitations: None 15. REGULATORY INFORMATION Classification: Not classified as hazardous according to criteria of NOHSC. Not classified as a Dangerous Good according to criteria of the Australian Dangerous Goods Code. Poisons Schedule: Not Scheduled Material Safety Data Sheet Straitline Marking Chalk Blue Issued: 10.06.2006 Version 1.0 Page 5 of 6 Page 1103 of 1287 Page 1103 of 1287 Page 1103 of 1287 Page 1103 of 1287 ---PAGE BREAK--- 16. OTHER INFORMATION This Material Safety Data Sheet has been prepared by Hodson & Associates Pty Ltd on behalf of Irwin Industrial Tool Company Pty Ltd. Contact Point: Hodson & Associates Pty Ltd, MSDS Services Within Australia: Telephone: (03) 9572 1303 Facsimile: (03) 9572 1393 Outside Australia: Telephone: +61 3 9572 1303 Facsimile: +61 3 9572 1393 Issue Date: 10/JUN/06/AH Supercedes Issue Date: 15 March 2004 Reasons for Issue: General update and revision. Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained herein, and assume no responsibility regarding the suitability of this information for the user’s intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purpose(s). Material Safety Data Sheet Straitline Marking Chalk Blue Issued: 10.06.2006 Version 1.0 Page 6 of 6 Page 1104 of 1287 Page 1104 of 1287 Page 1104 of 1287 Page 1104 of 1287 ---PAGE BREAK--- 5 / 1 REVISION DATE 7-1-09 SDS No. 18915 SAFETY DATA SHEET PLASTI-KOTE SUPER CLEAR ACRYLIC GLOSS According to Regulation (EC) No 1907/2006 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING PRODUCT NAME PLASTI-KOTE SUPER CLEAR ACRYLIC GLOSS PRODUCT NO. D66016 BOSTIK INDUSTRIES LTD SUPPLIER NEWTOWN SWORDS CO.DUBLIN +353 1 8624900 +353 1 8402186 [EMAIL REDACTED] 2 HAZARDS IDENTIFICATION Extremely flammable Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. Irritating to eyes. CLASSIFICATION (1999/45) Xi;R36. F+;R12. R66, R67. ENVIRONMENT The product is not expected to be hazardous to the environment. PHYSICAL AND CHEMICAL HAZARDS Aerosol containers can explode when heated, due to excessive pressure build-up. The product is extremely flammable, and explosive vapour/air mixtures may be formed even at normal room temperatures. HUMAN HEALTH In high concentrations, vapours and spray mists are narcotic and may cause headache, fatigue, dizziness and nausea. 3 COMPOSITION/INFORMATION ON INGREDIENTS EC No. Name Classification (67/548/EEC) CAS-No. Content % 200-662-2 ACETONE F;R11 Xi;R36 R66 R67 67-64-1 30-60% 203-448-7 BUTANE F+;R12 106-97-8 5-10% 212-112-9 ETHYL 3-ETHOXY PROPIONATE Xi;R36. 763-69-9 5-10% 202-849-4 F;R11 Xn;R20 100-41-4 1-5% 203-745-1 ISOBUTYL ACETATE F;R11 R66 110-19-0 10-30% 215-535-7 XYLENE R10 Xn;R20/21 Xi;R38 1330-20-7 5-10% The Full Text for all R-Phrases is Displayed in Section 16 4 FIRST-AID MEASURES GENERAL INFORMATION Move the exposed person to fresh air at once. INHALATION Move the exposed person to fresh air at once. Perform artificial respiration if breathing has stopped. Keep the affected person warm and at rest. Get prompt medical attention. Get medical attention. INGESTION Immediately rinse mouth and provide fresh air. Do not induce vomiting. Get medical attention if any discomfort continues. SKIN CONTACT Wash skin with soap and water. Get medical attention if any discomfort continues. EYE CONTACT Immediately rinse with water. Continue to rinse for at least 15 minutes. Make sure to remove any contact lenses from the eyes before rinsing. Get medical attention if occur after washing. 5 FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA Water spray, foam, dry powder or carbon dioxide. Page 1105 of 1287 Page 1105 of 1287 Page 1105 of 1287 Page 1105 of 1287 ---PAGE BREAK--- 5 / 2 REVISION DATE 7-1-09 SDS No. 18915 PLASTI-KOTE SUPER CLEAR ACRYLIC GLOSS SPECIAL FIRE FIGHTING PROCEDURES Use water spray to reduce vapours. Use water to keep fire exposed containers cool and disperse vapours. Cool containers exposed to flames with water until well after the fire is out. UNUSUAL FIRE & EXPLOSION HAZARDS Extremely flammable. Forms explosive mixtures with air. May explode in a fire. Vapours are heavier than air and may spread near ground to sources of ignition. SPECIFIC HAZARDS Aerosol containers can explode when heated, due to excessive pressure build-up. 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS Ensure suitable personal protection (including respiratory protection) during removal of spillages in a confined area. ENVIRONMENTAL PRECAUTIONS Avoid discharge into drains. SPILL CLEAN UP METHODS Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Absorb in vermiculite, dry sand or earth and place into containers. Provide ventilation and confine spill. Do not allow runoff to sewer. 7 HANDLING AND STORAGE USAGE PRECAUTIONS Keep away from heat, sparks and open flame. Read and follow manufacturer's recommendations. Avoid inhalation of vapours and spray mists. Do not incinerate empty containers. Do not handle broken packages without protective equipment. Do not puncture tin even when empty. STORAGE PRECAUTIONS Keep away from heat, sparks and open flame. Aerosol cans: Must not be exposed to direct sunlight or temperatures above 50°C. Do not store near heat sources or expose to high temperatures. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION STD STEL - 15 Min TWA - 8 Hrs Name Notes 500 ppm 1210 mg/m3 WEL 1500 ppm 3620 mg/m3 ACETONE 600 ppm 1450 mg/m3 WEL 750 ppm 1810 mg/m3 BUTANE 100 ppm(Sk) 441 mg/m3(Sk) WEL 125 ppm(Sk) 552 mg/m3(Sk) 150 ppm 724 mg/m3 WEL 187 ppm 903 mg/m3 ISOBUTYL ACETATE 50 ppm(Sk) 220 mg/m3(Sk) WEL 100 ppm(Sk) 441 mg/m3(Sk) XYLENE WEL = Workplace Exposure Limit. RESPIRATORY EQUIPMENT No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit. In case of inadequate ventilation use suitable respirator. HAND PROTECTION For prolonged or repeated skin contact use suitable protective gloves. EYE PROTECTION Wear approved chemical safety goggles where eye exposure is reasonably probable. HYGIENE MEASURES When using do not eat, drink or smoke. Wash if skin becomes wet or contaminated. 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Aerosol. COLOUR Clear ODOUR of solvents PHYSICAL DATA COMMENTS Information given concerns the major ingredient. FLASH POINT <-40 C AUTO IGNITION TEMPERATURE 410-580 C Page 1106 of 1287 Page 1106 of 1287 Page 1106 of 1287 Page 1106 of 1287 ---PAGE BREAK--- 5 / 3 REVISION DATE 7-1-09 SDS No. 18915 PLASTI-KOTE SUPER CLEAR ACRYLIC GLOSS FLAMMABILITY LIMIT - LOWER(%) 1.8 % FLAMMABILITY LIMIT - UPPER(%) 9.5 % 10 STABILITY AND REACTIVITY STABILITY Highly Volatile CONDITIONS TO AVOID Avoid heat, flames and other sources of ignition. Avoid exposure to high temperatures or direct sunlight. 11 TOXICOLOGICAL INFORMATION SKIN CONTACT Skin irritation is not anticipated when used normally. Repeated exposure may cause skin dryness or cracking. EYE CONTACT Irritating to eyes. Spray and vapour in the eyes may cause irritation and smarting. HEALTH WARNINGS In high concentrations, vapours are narcotic and may cause headache, fatigue, dizziness and nausea, (deviation from normal heartbeat). ROUTE OF ENTRY Inhalation. TARGET ORGANS Central nervous system Respiratory system, lungs MEDICAL High concentrations of vapours may irritate respiratory system and lead to headache, fatigue, nausea and vomiting. 12 ECOLOGICAL INFORMATION ECOTOXICITY The product is not expected to be toxic to aquatic organisms. However, contamination of the aquatic or terrestrial environments should be avoided 13 DISPOSAL CONSIDERATIONS DISPOSAL METHODS Make sure containers are empty before discarding (explosion risk). Do not puncture or incinerate even when empty. Dispose of waste and residues in accordance with local authority requirements. 14 TRANSPORT INFORMATION FLAMMABLE GAS 2 PROPER SHIPPING NAME AEROSOLS No. ENVIRONMENTALLY HAZARDOUS SUBSTANCE/MARINE POLLUTANT 1950 UN NO. ROAD 2, 5F ADR CLASS NO. Class 2.1: Flammable gases. ADR CLASS N/A ADR PACK GROUP TUNNEL RESTRICTION CODE 2.1 ADR LABEL NO. 1950 UN NO. SEA 2.1 IMDG CLASS N/A IMDG PACK GR. F-D, S-U EMS Page 1107 of 1287 Page 1107 of 1287 Page 1107 of 1287 Page 1107 of 1287 ---PAGE BREAK--- 5 / 4 REVISION DATE 7-1-09 SDS No. 18915 PLASTI-KOTE SUPER CLEAR ACRYLIC GLOSS 1950 UN NO. AIR 2.1 AIR CLASS N/A AIR PACK GR. 15 REGULATORY INFORMATION LABELLING Irritant Extremely flammable RISK PHRASES R12 Extremely flammable. R36 Irritating to eyes. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. SAFETY PHRASES S2 Keep out of the reach of children. S9 Keep container in a well-ventilated place. S16 Keep away from sources of ignition - No smoking. S23 Do not breathe vapour/spray. S25 Avoid contact with eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 Wear suitable gloves. S51 Use only in well-ventilated areas. S56 Dispose of this material and its container to hazardous or special waste collection point. EU DIRECTIVES Dangerous Preparations Directive 1999/45/EC. Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. STATUTORY INSTRUMENTS Control of Substances Hazardous to Health. 16 OTHER INFORMATION GENERAL INFORMATION This product should be used as directed by Bostik Industries Ltd. For further information consult the product data sheet or contact Technical Services. REVISION DATE 7-1-09 REV. NO./REPL. SDS GENERATED 2 DATE 12-4-10 RISK PHRASES IN FULL Extremely flammable. R12 Flammable. R10 Harmful by inhalation and in contact with skin. R20/21 Harmful by inhalation. R20 Highly flammable R11 Irritating to eyes. R36 Irritating to skin. R38 Repeated exposure may cause skin dryness or cracking. R66 Vapours may cause drowsiness and dizziness. R67 Page 1108 of 1287 Page 1108 of 1287 Page 1108 of 1287 Page 1108 of 1287 ---PAGE BREAK--- 5 / 5 REVISION DATE 7-1-09 SDS No. 18915 PLASTI-KOTE SUPER CLEAR ACRYLIC GLOSS DISCLAIMER This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. Page 1109 of 1287 Page 1109 of 1287 Page 1109 of 1287 Page 1109 of 1287 ---PAGE BREAK--- M S D S Material Safety Data Sheet Petra™ Penetrate P/N 9002 COMPANY AND PRODUCT IDENTIFICATION PRODUCT NAME: SUPER PENETRATING OIL CAS NUMBER: N/A PRODUCT DESCRIPTION: MIXTURE OF SURFACTANTS AND PETROLEUM DISTILLATES CONTACT ADDRESS: Petra Oil Company 5829 W. Sam Houston Pkwy Suite 804 Houston, Texas 77041 INFORMATION (LOCAL) [PHONE REDACTED] EMERGENCY PHONE NUMBER: CHEMTREC: (800) 424-9300 HAZARDOUS INGREDIENTS Name CAS Number Percentage Petroleum distillates 64742-95-6 45 – 90 % Light hydrotreated petroleum distillates 64742-88-7 7 – 30 % Sodium sulfate alkyl ether N/D 1 – 4 % Polyetoxilated stearilic ether 9005-00-9 < 1 % CHEMICAL AND PHYSICAL PROPERTIES APPEARANCE LIQUID COLOR DARK YELLOW SPECIFIC GRAVITY 0.806 g/ml BOILING POINT > 150 ºC VISCOSITY @40 °C 3 cps FLASH POINT 38 °C FREEZING POINT N/D VAPOR PRESSURE (mmHg) N/D WATER SOLUBILITY NOT SOLUBLE HEALTH HAZARD INFORMATION MAIN HAZARDS: - CAN CAUSE EYE AND SKIN IRRITATION. - CONTENTS UNDER PRESSURE, KEEP AWAY FROM HEAT AND FLAMES. - DO NOT INCINERATE, PUNCTURE OR KEEP CONTAINER AT TEMPERATURES HIGHER THAN 50ºC HEALTH HAZARDS EXPOSURE TO THIS PRODUCT CAN OCCUR THROUGH INHALATION, INGESTION, AND SKIN AND EYE CONTACT. Page: 1 / 5 Page 1110 of 1287 Page 1110 of 1287 Page 1110 of 1287 Page 1110 of 1287 ---PAGE BREAK--- M S D S Material Safety Data Sheet POTENTIAL HEALTH EFFECTS, SKIN SIGNIFICANT EFFECTS ARE NOT EXPECTED BECAUSE OF SHORT-TERM EXPOSURE. PROLONGED OR REPEATED CONTACT WITH GREAT QUANTITIES OF THIS PRODUCT MAY RESULT IN REDNESS AND SKIN IRRITATION. POTENTIAL HEALTH EFFECTS, EYES MAY CAUSE MILD IRRITATION AND TEARING. PROLONGED OR REPEATED EXPOSURE MAY CAUSE IRRITATION. POTENTIAL HEALTH EFFECTS, INHALATION INHALATION TOXICITY IS LOW. BREATHING SMALL QUANTITIES DURING HANDLING MAY NOT CAUSE NEGATIVE EFFECTS. BREATHING GREAT QUANTITIES OF MISTS OF VAPORS MAY BE HARMFUL. EXPOSURE TO GREAT QUANTITIES MAY CUASE RESPIRATORY TRACT IRRITATION. POTENTIAL HEALTH EFFECTS, INGESTION IN SMALL DOSES TOXICITY IS LOW. INGESTION OF LARGE QUANTITIES MAY CAUSE GASTROINTESTINAL IRRITATION. FIRST AID EYE CONTACT: IMMEDIATELY WASH EYES WITH PLENTY WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS OR PERSISTS. SKIN CONTACT: IMMEDIATELY WASH SKIN WITH PLENTY OF NEUTRAL SOAP AND WATER FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING SEPARATELY BEFORE REUSE. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS OR PERSISTS. INHALATION: REMOVE PERSON TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. GIVE AT LEAST 3- 4 GLASSES OF WATER. GET IMMEDIATE MEDICAL ATTENTION. NEVER GIVE ANYTHING IN THE MOUTH TO AN UNCONSCIOUS PERSON. FIRE AND EXPLOSION INFORMATION FLAMMABILITY CATEGORY NFPA 30: AEROSOL LEVEL 3 FLAME EXTENSION: > 18” EXTREMELY FLAMMABLE(16 CFR 1500.45) FLASH POINT: N/D FLAMMABILITY LIMITS IN AIR, LOWER, % BY VOLUME: N/D FLAMMABILITY LIMITS IN AIR, UPPER, % BY VOLUME: N/D EXTINGUISHING MEDIA: ALCOHOL FOAM, CO2, DRY CHEMICAL FOAM, WATER FOG. PERSONAL PROTECTION: FIREFIGHTERS MUST WEAR NIOSH APPROVED POSITIVE PRESSURE BREATHING APPARATUS (SCBA) WITH FULL FACE MASK AND FULL PROTECTIVE EQUIPMENT. Page: 2 / 5 Page 1111 of 1287 Page 1111 of 1287 Page 1111 of 1287 Page 1111 of 1287 ---PAGE BREAK--- M S D S Material Safety Data Sheet SPECIAL FIREFIGHTING PROCEDURES: COOL CONTAINERS EXPOSED TO FIRE DURING AND AFTER FIRE TO PREVENT EXPLOSIONS. WATER STREAMS OF WATER WATER RUNOFF CAN CAUSE ENVIRONMENTAL DAMAGE. DIKE AND COLLECT WATER USED TO FIGHT FIRE. WATER HAZARD COMBUSTION PRODUCTS: COX AND OTHER INCOMPLETE COMBUSTION PRODUCTX. ACCIDENTAL SPILLS OR LEAKS PROCEDURE IN CASE OF SPILLS OR LEAKS THE FOLLOWING STEPS SHOULD BE FOLLOWED IN CASE MATERIAL IS RELEASED OR SPILLED: PERSON NOT WEARING PROTECTIVE EQUIPMENT AND CLOTHING SHOULD BE RESTRICTED FROM CONTAMINATED AREAS UNTIL HAS BEEN COMPLETED. 1. DO NOT TOUCH THE SPILLED MATERIAL; STOP THE LEAK IF IT IS POSSIBLE TO DO SO WITHOUT RISK. 2. NOTIFY SAFETY PERSONNEL. 3. REMOVE ALL SOURCES OF HEAT AND IGNITION. 4. VENTILATE POTENTIALLY EXPLOSIVE ATMOSPHERES USING MAXIMALLY EXPLOSION-PROOF EQUIPMENT. 5. USE NONSPARKING TOOLS FOR CLEANUP. 6. WATER SPRAY MAY BE USED TO REDUCE VAPORS, BUT THE SPRAY MAY NOT PREVENT IGNITION IN CLOSED SPACES. 7. FOR SMALL LIQUID SPILLS, TAKE UP WITH SAND OR OTHER NONCOMBUSTIBLE ABSORBENT MATERIAL AND PLACE INTO CLOSED CONTAINERS FOR LATER DISPOSAL. FOR LARGE LIQUID SPILL, BUILD DIKES FAR AHEAD OF THE SPILL TO CONTAIN THE MATERIAL FOR LATER RECLAMATION OR DISPOSAL DISPOSAL CARE MUST BE TAKEN WHEN USING OR DISPOSING OF CHEMICAL MATERIALS AND/OR THEIR CONTAINERS TO PREVENT ENVIRONMENTAL CONTAMINATION. DISPOSAL CAN OCCUR ONLY IN PROPERLY PERMITTED FACILITIES. CHECK STATE AND LOCAL REGULATIONS FOR ANY ADDITIONAL REQUIREMENTS AS THESE MAY BE MORE RESTRICTIVE THAN FEDERAL LAWS AND REGULATIONS. CHEMICAL ADDITIONS, PROCESSING OR OTHERWISE ALTERING THIS MATERIAL MAY MAKE THE WASTE MANAGEMENT INFORMATION PRESENTED IN THIS MSDS INCOMPLETE, INACCURATE OR OTHERWISE INAPPROPRIATE. DISPOSAL OF THIS MATERIAL MUST BE CONDUCTED IN COMPLIANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS. HANDLING AND STORAGE STORAGE PROCEDURES: KEEP MATERIAL AWAY FROM HEAT, ELECTRIC ARCS, STATIC ELECTRICITY AND FIRE. AVOID BREATHING VAPORS. KEEP CONTAINERS CLOSED WHEN NOT IN USE. WASH HANDS AFTER HANDLING. EMPTY CONTAINERS MAY CONTAIN MATERIAL. DO NOT CUT, WELD, PUNCTURE OR EXPOSE CAN TO HEAT, FLAMES OR OTHER IGNITION SOURCES. DO NOT EAT, DRINK OR SMOKE IN STORAGE AREAS. HANDLING: AVOID BREATHING VAPORS OR FUMES, AVOID EYE OR SKIN CONTACT. USE WITH ADEQUATE VENTILATION. WASH HANDS AFTER HANDLING. OBEY LABEL INSTRUCTIONS UNTIL CAN IS DESTROYED. Page: 3 / 5 Page 1112 of 1287 Page 1112 of 1287 Page 1112 of 1287 Page 1112 of 1287 ---PAGE BREAK--- M S D S Material Safety Data Sheet EXPOSURE CONTROL/PERSONAL PROTECTION VENTILATION: USE LOCAL VENTILATION. SKIN PROTECTION: NOT NECESSARY UNDER NORMAL USE. EYE PROTECTION: NOT NECESSARY UNDER NORMAL USE. RESPIRATORY PROTECTION: NOT NECESSARY UNDER NORMAL USE. 10.- REACTIVITY AND STABILITY STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS. INCOMPATIBILITY: AVOID CONTACT WITH STRONG OXIDIZING AGENTS. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS. HAZARDOUS DECOMPOSITION PRODUCTS: COMBUSTION MAY FORM CARBON DIOXIDE, CARBON MONOXIDE, SULFURIC ACID, POSSIBLE TRACES OF PHOSGENE. CONDITIONS TO AVOID: HEAT, SPARKS, OPEN FLAMES, HOT GLOWING SURFACES OR ELECTRICS ARCS. 11.- TOXICITY INFORMATION PETROLEUM DISTILLATES ORAL LD50 RAT 2900 mg/kg LIGHT PETROLEUM DISTILLATES INHALATION LC50 RAT, 450 ppm (4 H) ORAL LD50 RAT 530 mg/kg PIG SKIN LD50 230 mg/Kg SODIUM SULFATE ALKYL ETHER SKIN TOXICITY: IRRITATING ORAL TOXICITY: LD50 >2000 mg/kg, RAT. POLYETOXILATED STEARILIC ETHER SKIN TOXICITY: IRRITATING 12.- EXPOSURE LIMITS PETROLEUM DISTILLATES OSHA 100 PPM-8 HORAS (TWA) ACGIH 100 PPM-10 HORAS (TWA) PETROLEUM DISTILLATES LIGERO NO DETERMINADO SODIUM SULFATE ALKYL ETHER NO DETERMINADO POLYETOXILATED STEARILIC ETHER NO DETERMINADO TWA : Time Weighted Average STEL : Short Term Exposure Limit OSHA: Occupational Safety & Health Administration NIOSH: National Institute for Occupational Safety and Health Page: 4 / 5 Page 1113 of 1287 Page 1113 of 1287 Page 1113 of 1287 Page 1113 of 1287 ---PAGE BREAK--- M S D S Material Safety Data Sheet ACGIH: The American Conference of Governmental Industrial Hygienists 13.- SIGNAL AND LABEL INFORMATION NFPA CODE: HEALTH: 1; FIRE: 4; REACTIVITY: 0. HMIS CODE: HEALTH: 1; FIRE: 4; REACTIVITY: 0. 4 PRECAUTION LABELS 1 0 DANGER - EXTREMELY FLAMMABLE. - CONTENTS UNDER PRESSURE, DO NOT PUNCTURE CONTAINER OR EXPOSE TO HEAT, SPARKS OR FLAMES. - DO NOT STORE AT TEMPERATURES HIGHER THAN 121 ºF. - KEEP OUT OF THE REACH OF CHILDREN. - VAPOR HARMFUL. - HARMFUL OR FATAL IF SWALLOWED. 14.- SHIPPING INFORMATION Secretaria de Comunicaciones y transportes (SCT) – NOM-002-SCT2/1994 (México) Información general para la transportación de embarques. Nombre para transportación: Aerosol inflamable Número ONU: 1950 Clase/División: 2.1 Cantidad Limitada: 1000 ml por bote Se puede transportar como cantidad limitada U.S. Department of Transportation (DOT) 49 – CFR 172 General Transportation Information for Shipments Shipping name: Consumer Commodity, ORM-D UN Number: N/A Class/Division: N/A Packing Group (PG): N/A Label: FLAMMABLE CONTENTS UNDER PRESSURE International Water Transportation – IMDG CODE General Transportation Information for Shipments Shipping name: Aerosol, flammable, n.o.s. UN Number: UN 1950 Class/Division: 2.1 Packing Group (PG): N/A Limited Quantity: 1000 ml per can According to filled quantities, special labeling is not required. (Chapter 3.4 LIMITED QUANTITIES). 15.- ADDITIONAL INFORMATION THE INFORMATION PRESENTED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE TO THE DATE OF PREPARATION OF THIS MATERIAL SAFETY DATA SHEET. HOWEVER, A MSDS MAY NOT BE USED AS A COMMERCIAL SPECIFICATION SHEET OF MANUFACTURER OR SELLER, AND NO WARRANTY OR REPRESTENTATION, EXPRESSED OR IMPLIED, IS MADE AS TO THE ACCURACY OR COMPREHENSIVENESS OF THE FOREGOING DATA AND SAFETY INFORMATION, NOR IS ANY AUTHORIZATION GIVEN OR IMPLIED TO PRACTICE ANY A PATENTED INVENTION WITHOUT A L ICENSE. Last revision: May 2011 Page: 5 / 5 Page 1114 of 1287 Page 1114 of 1287 Page 1114 of 1287 Page 1114 of 1287 ---PAGE BREAK--- SAF-T-LOK Material Safety Data Sheet International Corporation T42 Issue Date: 12/11/12 SECTION I - PRODUCT AND COMPANY INFORMATION Product Name: T42 Threadlocker Product Type: Anaerobic Adhesive/ Sealant Part Numbers: 24202/ 24221 /24231 /24241/ 24243/9S-3263/4C-40330 Hazard Rating: Health: 1 Fire: 1 Reactivity: 0 Company Identification: SAF-T-LOK International Corporation 300 EISENHOWER LANE NORTH LOMBARD, IL 60148 Contact: Helen Champagne Telephone/ Fax: (630) 495-2001 Emergency Phone (24 Hour): (703) 527-3887 Chemtrec (24 Hour): (800) 424-9300 Preparer: Ind. Hygiene Department Internet: www.saftlok.com Product Class: Mixture DOT Hazard Class: N/A Shipping Name: Unrestricted SECTION II - INGREDIENT AND HAZARD INFORMATION Components CAS# Percent dimethacrylate 109-16-0 30 - 60 oleate 9004-96-0 20 - 40 Silica amorphous, fumed, free 112945-52-5 1 - 5 Saccharin 81-07-2 1 - 5 Cumene hydroperoxide 80-15-9 0.1 - 5 SECTION III - HAZARD IDENTIFICATION AND EMERGENCY OVERVIEW EMERGENCY OVERVIEW Physical appearance: Liquid HMIS Physical color: Blue Health: 1 Odor: Mild / Inoffensive Flammability: 1 Reactivity: 0 Personal Protection: B WARNING; MAY CAUSE: EYE IRRITATION SKIN IRRITATION RESPIRATORY TRACT IRRITATION MAY IRRITATE EXISTING ALLERGIC SKIN CONDITIONS Page 1 of 4 Product: T42 Threadlocker Page 1115 of 1287 Page 1115 of 1287 Page 1115 of 1287 Page 1115 of 1287 ---PAGE BREAK--- Relative routes of entry: Skin, Inhalation, Eyes, Ingestion Skin Contact: Usually no effect, however, as with any chemical, prolonged, excessive, or repeated exposure may cause mild to moderate skin irritation, exhibited by redness, drying and cracking of unprotected skin. Eye Contact: May irritate with slight pain and redness. Respiratory/ Inhalation: Usually none, however, as with any chemical product, some irritation may occur. Ingestion: Amounts transferred to mouth by fingers, etc, during normal operation should not cause injury. Medical conditions generally aggravated by exposure: None known, however any chemical product may enhance allergies already present in certain individuals. SECTION IV – FIRST AID INSTRUCTIONS Skin Contact: Remove contaminated clothing. Wash affected area with soap and rinse with plenty of water. Get medical attention if occur. Wash clothing before reuse. Eye Contact: Flush with water for at least 15 minutes holding eyelid open. Get medical attention if persist. Respiratory / Inhalation: Remove to fresh air, if develop get medical attention. Ingestion: Do not induce vomiting. Obtain medical attention if develop. SECTION V – FIRE FIGHTING INSTRUCTIONS Flash Point: 205°F (96°C) Unusual Fire and Explosion Hazards: None Flammable Limits: LEL: N/A, UEL: N/A Extinguishing Media: Carbon Dioxide, Foam, Dry Chemicals Fire Fighting Procedures: Air mask and procedures for fighting chemical fires Hazardous combustion products: Oxides of carbon, sulfur, nitrogen SECTION VI -ACCIDENTAL RELEASE MEASURES Special Precautions: None known. Follow general precautions shown below. Environmental precautions: Prevent material from entering floor drains, sewers, or any bodies of water. Clean up methods: Scoop up into waste container or soak up with absorbent material. Store in a closed container until disposal. SECTION VII - HANDLING AND STORAGE Handling: Avoid contact with eyes, skin, and clothing. Avoid breathing vapors. Wash hands thoroughly at mealtime and end of shift. Storage: Store in a cool location (60-90°F) in a well ventilated area away from sources of heat. Keep container closed when not in use. Personal Protection: Wear personal protective equipment as outlined in Section VIII of this MSDS. Page 2 of 4 Product: T42Threadlocker Page 1116 of 1287 Page 1116 of 1287 Page 1116 of 1287 Page 1116 of 1287 ---PAGE BREAK--- SECTION VIII – EXPOSURE CONTROLS AND PERSONAL PROTECTION Respiratory Protection: No respiratory protection required, but normal good ventilation is recommended. Forced ventilation may be required if concentrations exceed normal use exposure. Skin Protection: Use impermeable gloves (neoprene, butyl rubber, natural rubber), as necessary to avoid skin contact, as well as proper clothing or plastic apron. Wash hands before eating, drinking, or using restroom. Eye Protection: Safety goggles or glasses are recommended. Eye Washes: Eye wash stations should be located within 100 feet or 10 second walk of the work area. SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Blue Odor: Mild Boiling Point: > 300°F (149°C) Specific Gravity: 1.1 Vapor Density (Air = N/A Vapor Pressure (mm Hg.): < 5 @30°F pH: N/A Melting Point: N/A Evaporation Rate: N/A Solubility in Water: Partial V.O.C. Content: < 0.1% SECTION X –STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Hazardous decomposition byproducts: Oxides of carbon, Oxides of nitrogen Incompatibility: Reducing agents. Strong Oxidizers SECTION XI – TOXICOLOGICAL INFORMATION Product Toxicity: Estimated oral LD50 greater than 10,000 mg/kg. Estimated dermal LD50 greater than 5000 mg/kg. Carcinogen Status Ingredients: Health Effect NTP IARC OSHA Dimethacrylate ALG IRR NO NO NO oleate IRR NO NO NO Saccharin N/A NO NO NO Silica, amorphous N/A NO NO NO Cumene Hydroperoxide COR, ALG, IRR NO NO NO Abbreviations: ALG Allergen IRR Irritant COR Corrosive SECTION XII – ECOLOGICAL DATA Water Hazard: Do not allow entry into drains or surface water Page 3 of 4 Product: T42 Threadlocker Page 1117 of 1287 Page 1117 of 1287 Page 1117 of 1287 Page 1117 of 1287 ---PAGE BREAK--- SECTION XIII – DISPOSAL CONSIDERATIONS Recommended method of disposal: Unused product: Dispose of according to Federal, State and local regulations. EPA Hazardous Waste Number; Not an RCRA hazardous waste. SECTION XIV – SHIPPING AND TRANSPORTATION INFORMATION U.S. Department of Transportation Ground (49 CFR) Proper Shipping Name: Unrestricted Hazard Class or Division: None Identification Number: None Packing Group: None International Air Transportation (OCAO/IATA): Proper Shipping Name: Unrestricted Hazard Class or Division: None Identification Number: None Packing Group: None Water Transportation (IMO/IMDG): Proper Shipping Name: Unrestricted Hazard Class or Division: None Identification Number: None Packing Group: None Marine Pollutant: None SECTION XV – REGULATORY INFORMATION United States Regulatory Information TSCA 8 Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. CERCLA/SARA Section 311/312: This product contains the following toxic chemical subject to the reporting requirements of section 313 of the Emergency Planning and Community Right- To-Know Act of 1986 (40 CFR): Cumene hydroperoxide. California Proposition 65: No California Proposition 65 listed chemicals are known to be present. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Domestic Substances List. WHMIS hazard class D.2.B SECTION XVI – OTHER INFORMATION Revision date11/12/2012 By: Human Resource Department DISCLAIMER: The information on this material safety data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user. SAF-T-LOK International Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of SAF-T-LOK International Corporation products. Page 4 of 4 Product: T42 Threadlocker Page 1118 of 1287 Page 1118 of 1287 Page 1118 of 1287 Page 1118 of 1287 ---PAGE BREAK--- Page 1/8 Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date: 03.02.2015 Revision: 03.02.2015 Version No: 6 40.0.6 * SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: Tabz Coffee Equipment Cleaning Tablets · 1.2 Relevant identified uses of the substance or mixture and uses advised against · Application of the substance / the preparation: Coffee/Espresso machine/equipment cleaner · Uses advised against: No further relevant information available. · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: Urnex Brands, Inc. Urnex Brands, Inc. 700 Executive Blvd. 29 Harley Street, London, W1G 9QR Elmsford, NY 10523 USA United Kingdom Phone: +1-[PHONE REDACTED] Tel: +44 (0)20 7927 6881 Fax: +1-[PHONE REDACTED] Email: [EMAIL REDACTED] · Further information obtainable from: Urnex Brands, Inc. 700 Executive Blvd. Elmsford, NY 10523 USA Phone: +1-[PHONE REDACTED] Fax: +1-[PHONE REDACTED] Email: [EMAIL REDACTED] · 1.4 Emergency telephone number: Tel.: [PHONE REDACTED] (USA) Tel.: 001-[PHONE REDACTED] (INTERNATIONAL COLLECT ACCEPTED) * SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2 H319 Causes serious eye irritation. · Classification according to Directive 67/548/EEC or Directive 1999/45/EC Xi; Irritant R36: Irritating to eyes. · Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. · Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms ~  GHS07 · Signal word Warning (Contd. on page 2) GB Page 1119 of 1287 Page 1119 of 1287 Page 1119 of 1287 Page 1119 of 1287 ---PAGE BREAK--- Page 2/8 Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date: 03.02.2015 Revision: 03.02.2015 Version No: 6 Trade name: Tabz Coffee Equipment Cleaning Tablets (Contd. of page 1) 40.0.6 · Hazard statements H315 Causes skin irritation. H319 Causes serious eye irritation. · Precautionary statements P280 Wear protective gloves/protective clothing/eye protection/face protection. P264 Wash thoroughly after handling. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor. P332+P313 If skin irritation occurs: Get medical advice/attention. P302+P352 IF ON SKIN: Wash with plenty of water. P362+P364 Take off contaminated clothing and wash it before reuse. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not determined · vPvB: Not determined * SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Dangerous components: CAS: 497-19-8 EINECS: 207-838-8 Index number: 011-005-00-2 sodium carbonate ? @ G ? @ G Xi R36 ~  Eye Irrit. 2, H319 > 25% CAS: 15630-89-4 EINECS: 239-707-6 disodium carbonate, compound with hydrogenperoxide (2:3) ? @ G ? @ G Xn R22; ? @ G ? @ G Xi R41; ? @ E ? @ E O R8 ~  Ox. Liq. 2, H272; ~  Eye Dam. 1, H318; ~  Acute Tox. 4, H302 < 15% CAS: 25322-68-3 NLP: 500-038-2 Polyethylene glycol ~  STOT SE 3, H335 < 12% CAS: 6834-92-0 EINECS: 229-912-9 Index number: 014-010-00-8 disodium metasilicate ? @ A ? @ A C R34; ? @ G ? @ G Xi R37 ~  Met. Corr.1, H290; Skin Corr. 1B, H314; ~  STOT SE 3, H335 < 3% · Regulation (EC) No 648/2004 on detergents / Labelling for contents phosphates 15 - 30% oxygen-based bleaching agents 5 - 15% · Additional information: For the wording of the listed risk phrases refer to section 16. SECTION 4: First aid measures · 4.1 Description of first aid measures · General information: Take affected persons out of danger area and lay down. Immediately remove any clothing soiled by the product. · After inhalation: Supply fresh air; consult doctor in case of complaints. · After skin contact: Immediately rinse with water. If skin irritation continues, consult a doctor. · After eye contact: Rinse opened eye for several minutes under running water. If persist, consult a doctor. Remove contact lenses, if present and easy to do. Continue rinsing. (Contd. on page 3) GB Page 1120 of 1287 Page 1120 of 1287 Page 1120 of 1287 Page 1120 of 1287 ---PAGE BREAK--- Page 3/8 Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date: 03.02.2015 Revision: 03.02.2015 Version No: 6 Trade name: Tabz Coffee Equipment Cleaning Tablets (Contd. of page 2) 40.0.6 · After swallowing: Rinse out mouth and then drink plenty of water. Seek immediate medical advice. · 4.2 Most important and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. * SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Use fire extinguishing methods suitable to surrounding conditions. · For safety reasons unsuitable extinguishing agents: Water with full jet · 5.2 Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. In case of fire, the following can be released: Carbon monoxide Carbon dioxide · 5.3 Advice for firefighters · Protective equipment: Wear self-contained respiratory protective device. · Additional information Cool endangered receptacles with water spray. Collect contaminated fire fighting water separately. It must not enter the sewage system. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Wear protective clothing. Avoid formation of dust. · 6.2 Environmental precautions: Dilute with plenty of water. Do not allow to enter sewers/ surface or ground water. · 6.3 Methods and material for containment and cleaning up: Pick up mechanically. Ensure adequate ventilation. Dispose of the material collected according to regulations. · 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Any unavoidable deposit of dust must be regularly removed. · Information about fire and explosion protection: Keep respiratory protective device available. · 7.2 Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Store only in the original receptacle. · Information about storage in one common storage facility: Store away from oxidising agents. (Contd. on page 4) GB Page 1121 of 1287 Page 1121 of 1287 Page 1121 of 1287 Page 1121 of 1287 ---PAGE BREAK--- Page 4/8 Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date: 03.02.2015 Revision: 03.02.2015 Version No: 6 Trade name: Tabz Coffee Equipment Cleaning Tablets (Contd. of page 3) 40.0.6 · Further information about storage conditions: Store under lock and key and out of the reach of children. Protect from humidity and water. · 7.3 Specific end use(s) No further relevant information available. SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · 8.2 Exposure controls · Personal protective equipment: · General protective and hygienic measures: Do not inhale dust / smoke / mist. Avoid contact with the eyes and skin. The usual precautionary measures are to be adhered to when handling chemicals. · Respiratory protection: Not necessary if room is well-ventilated. · Protection of hands: ` S Protective gloves Avoid direct contact with the chemical/ the product/ the preparation by organisational measures. To avoid skin problems reduce the wearing of gloves to the required minimum. Check protective gloves prior to each use for their proper condition. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material > 480 min The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · For the permanent contact gloves made of the following materials are suitable: Nitrile rubber, NBR · As protection from splashes gloves made of the following materials are suitable: Natural rubber, NR · Eye protection: Safety glasses · Body protection: Protective work clothing SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Solid Colour: Light blue · Odour: Characteristic · Odour threshold: Not determined. · pH-value (10 g/l) at 20 11.20 - 11.45 (Contd. on page 5) GB Page 1122 of 1287 Page 1122 of 1287 Page 1122 of 1287 Page 1122 of 1287 ---PAGE BREAK--- Page 5/8 Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date: 03.02.2015 Revision: 03.02.2015 Version No: 6 Trade name: Tabz Coffee Equipment Cleaning Tablets (Contd. of page 4) 40.0.6 · Change in condition Melting point/Melting range: Not determined. Boiling point/Boiling range: Not determined. · Flash point: Not determined. · Flammability (solid, gaseous): Not determined. · Ignition temperature: Not determined. · Decomposition temperature: Not determined. · Self-igniting: Product is not selfigniting. · Danger of explosion: Product does not present an explosion hazard. · Explosion limits: Lower: Not determined. Upper: Not determined. · Oxidising properties No · Vapour pressure: Not applicable. · Density: Not determined. · Relative density Not determined. · Vapour density Not applicable. · Evaporation rate Not applicable. · Solubility in / Miscibility with water: Soluble. · Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Not applicable. Kinematic: Not applicable. · 9.2 Other information No further relevant information available. SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability No decomposition if used and stored according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known. · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: Reacts with strong oxidising agents. · 10.6 Hazardous decomposition products: No dangerous decomposition products known. SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity: · LD/LC50 values relevant for classification: 497-19-8 sodium carbonate Oral LD50 4090 mg/kg (Rat) 15630-89-4 disodium carbonate, compound with hydrogenperoxide (2:3) Oral LD50 1034 mg/kg (Rat) (Contd. on page 6) GB Page 1123 of 1287 Page 1123 of 1287 Page 1123 of 1287 Page 1123 of 1287 ---PAGE BREAK--- Page 6/8 Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date: 03.02.2015 Revision: 03.02.2015 Version No: 6 Trade name: Tabz Coffee Equipment Cleaning Tablets (Contd. of page 5) 40.0.6 25322-68-3 Polyethylene glycol Oral LD50 >10000 mg/kg (Rat) Dermal LD50 >20000 mg/kg (Rabbit) 6834-92-0 disodium metasilicate Oral LD50 1153 mg/kg (Rat) · Primary irritant effect: · on the skin: Irritant to skin and mucous membranes. · on the eye: Strong irritant with the danger of severe eye injury. · Sensitisation: No sensitising effects known. · Additional toxicological information: The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: Irritant · Toxicokinetics, metabolism and distribution No further relevant information available. · Acute effects (acute toxicity, irritation and corrosivity) No further relevant information available. · Repeated dose toxicity No further relevant information available. · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) No further relevant information available. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: No further relevant information available. · 12.2 Persistence and degradability Anorganic product, is not eliminable from water by means of biological cleaning processes. The organic portion of the product is biodegradable. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (German Regulation) (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. · 12.5 Results of PBT and vPvB assessment · PBT: Not determined · vPvB: Not determined · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation: Smaller quantities can be disposed of with household waste. · European waste catalogue 20 01 29* detergents containing dangerous substances · Uncleaned packaging · Recommendation: Disposal must be made according to official regulations. (Contd. on page 7) GB Page 1124 of 1287 Page 1124 of 1287 Page 1124 of 1287 Page 1124 of 1287 ---PAGE BREAK--- Page 7/8 Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date: 03.02.2015 Revision: 03.02.2015 Version No: 6 Trade name: Tabz Coffee Equipment Cleaning Tablets (Contd. of page 6) 40.0.6 · Recommended cleansing agents: Water, if necessary together with cleansing agents. SECTION 14: Transport information · 14.1 UN-Number · ADR, ADN, IMDG, IATA Void · 14.2 UN proper shipping name · ADR, ADN, IMDG, IATA Void · 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class Void · 14.4 Packing group · ADR, IMDG, IATA Void · 14.5 Environmental hazards: · Marine pollutant: No · 14.6 Special precautions for user Not applicable. · 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable. · Transport/Additional information: Not dangerous according to the above specifications. · UN "Model Regulation": - SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture No further relevant information available. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H272 May intensify fire; oxidiser. H290 May be corrosive to metals. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage. H319 Causes serious eye irritation. H335 May cause respiratory irritation. R22 Harmful if swallowed. R34 Causes burns. R36 Irritating to eyes. R37 Irritating to respiratory system. R41 Risk of serious damage to eyes. R8 Contact with combustible material may cause fire. (Contd. on page 8) GB Page 1125 of 1287 Page 1125 of 1287 Page 1125 of 1287 Page 1125 of 1287 ---PAGE BREAK--- Page 8/8 Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date: 03.02.2015 Revision: 03.02.2015 Version No: 6 Trade name: Tabz Coffee Equipment Cleaning Tablets (Contd. of page 7) 40.0.6 · Department issuing SDS: Chemservice GmbH 1b D-67550 Worms Tel.: +49 (0)6241-95480-0 Fax: +49 (0)6241-95480-25 Email: [EMAIL REDACTED] · Abbreviations and acronyms: REACH: Registration, Evaluation, Authorisation and Restriction of Chemicals MARPOL: (from Marine Pollutant) International Convention for the Prevention of Marine Pollution from Ships IBC Code: International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk UN: United Nations (also UNO: United Nations Organization) NOEC: No Observed Effect Concentration OECD: Organisation for Economic Co-operation and Development ASTM: American Society for Testing and Materials WAF: Water Accommodated Fraction ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Ox. Liq. 2: Oxidising Liquids, Hazard Category 2 Met. Corr.1: Corrosive to metals, Hazard Category 1 Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Corr. 1B: Skin corrosion/irritation, Hazard Category 1B Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1 Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 · * Data compared to the previous version altered. GB Page 1126 of 1287 Page 1126 of 1287 Page 1126 of 1287 Page 1126 of 1287 ---PAGE BREAK--- PRODUCT AND COMPANY IDENTIFICATION 1 Manufacturer: The Blaster Corporation 8500 Sweet Valley Drive Valley View, Ohio 44125 (216) 901-5800 (216) 901-5801 fax www.blasterproducts.com 24 Hour emergency contact: Chemtrec (800) 424-9300 TDL - The Dry Lube 02/17/12 TDL - aerosol 16-TDL Product Name: Revision Date: MSDS Number: Product Code: COMPOSITION/INFORMATION ON INGREDIENTS 2 Hazardous Ingredients CAS # Percent Exposure Limits Polytetrafluoroethylene 9002-84-0 OSHA (PEL)- 5 mg/m3 dust Heptane 142-82-5 >85% OSHA (TWA)- 500 ppm ACGIH (TWA)- 400 ppm Carbon Dioxide 124-38-9 <3 OSHA (TWA)- 5000 ppm ACGIH (TWA)- 5000 ppm HAZARDS IDENTIFICATION 3 Eyes, skin, inhalation, ingestion Route of Entry: Target Organs: Inhalation of spray mist likely to cause irritation to the respiratory tract. May cause headache, dizziness, nausea, vomiting or narcosis in confined or poorly ventilated areas. Inhalation: Repeated or prolonged contact with skin may cause mild irritation and possibly dermatitis. Skin Contact: Likely to cause immediate or delayed irritaion. Irritation will show as redness and/or swelling of the eyes. Eye Contact: Ingestion may cause irritation to the mouth, esophagus and stomach. May cause abdominal pain, vomiting, dizziness and headaches. Ingestion: May aggravate a pre-existing skin and respiratory disorders. Physical Hazard: Aerosol containers are pressurized (even when empty!) Do not expose to temperatures above 1200 F. Do not puncture or burn can. Failure to observe these precautions may result in rapid and violent decompression of the container producing projectiles and atomization of the liquid contents. TDL - The Dry Lube Material Safety Data Sheet Revision Date: 02/17/12 MSDS Number: TDL - aerosol Page of 1 6 MSDS The Blaster Corporation Page 1127 of 1287 Page 1127 of 1287 Page 1127 of 1287 Page 1127 of 1287 ---PAGE BREAK--- Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. FIRST AID MEASURES 4 Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Continuie to monitor. Get medical attention. Inhalation: Remove contaminated clothing immediately! Wash skin with soap and water. If irritation develops, seek medical attention. Skin Contact: Flush eye(s) with water for 15 minutes. Get medical attention. If eye irritation presists, obtain medical treatment. Eye Contact: Aspiration hazard! Do not induce vomiting or give anything by mouth. This material can enter the lungs and cause lung damage. If victim is drowsy or unconscious and vomiting, place on the left side with head down. Do not leave victime unattended, observe closely for adequacy of breathing. Seek medical attention. Ingestion: FIRE FIGHTING MEASURES 5 Flash point: 15oF ASTM D-56 (TCC) Flammable Limits: Lower Explosion Limit: 1.2% Upper Explosion Limit: 6.7% Auto Ignition Temperature: not determined Extinguishing Media: Dry chemical, carbon dioxide or foam is recommended. Water may be ineffective for extinguishment, but can be useful in minimizing or dispersing vapors, protecting personnel and cooling containers. If containers are not properly cooled they can rupture in the heat of a fire. Avoid spreading burning liquid with water used for cooling purposes. Unusual Fire & Expolsion Hazards: Level 3 Aerosols - Contents Under Pressure! This material is extremely flammable and can be ignitied by heat, sparks, flames, or other sources of ignition (e.g. static electricity, pilot lights, mechanical/electric equipment, and electronic equipment such as cell phones, computers, calculators which have not been certified as intrinsically safe.) Vapors may travel considerable distances to a source of ignition where the can ignite, flash back or explode. May create vapor/air explosion indoors, in confined spaces, outdoors or in sewers. Vapors are heavier than air and can accumulate in low areas. ACCIDENTAL RELEASE MEASURES 6 Eliminate all sources of ignition and ventilate the area. See section 8 for the appropriate personal protection. Aerosol cans should be handled with caution. Sudden release of pressure could produce projectiles and atomized combustible liquid. Leaking aerosol cans should be put into suitable container until the internal pressure has dissipated. Take precautions to prevent contamination of ground and surface waters. Do not flush into sewers or storm drains. Use suitable absorbents to collect liquid product. Consult regulations for the proper disposal of the container, liquid and absorbents. TDL - The Dry Lube Material Safety Data Sheet Revision Date: 02/17/12 MSDS Number: TDL - aerosol Page of 2 6 MSDS The Blaster Corporation Page 1128 of 1287 Page 1128 of 1287 Page 1128 of 1287 Page 1128 of 1287 ---PAGE BREAK--- HANDLING AND STORAGE 7 Use in accordance with good industrial workplace practices. Avoid unnecessary contact. Wash thoroughly after handling. Use with good ventilation. Handling Precautions: Store in a dry place away from excessive heat. Store containers with lids on and properly labeled. Do not store at temperatures above 120 degrees F. Storage Requirements: EXPOSURE CONTROLS/PERSONAL PROTECTION 8 Eye wash stations and emergency showers should be immediately available. Engineering Controls: Eyes and Face: Standard safety glasses with splash shields typically offer adequate protection. Where excessive splashing or spraying is possible, a face shield should be used. Do not wear contacts. Skin and clothing: Excessive contact should be avoided. Nitrile gloves, boots and aprons will provide adequate protection when contact cannot be avoided. Remove and wash any contaminated clothing immediately. Wash thoroughly after handling. Respiratory: Good general ventilation should be sufficient to control airborne levels. Maintain airborne concentrations below OSHA established exposure limits of ingredients in Section 2. Use NIOSH approved respirator if ventilation is not adequate enough to maintain levels below these limits. Protective Equipment: The Blaster Corporation takes no responsibility for determining what measures are required for personal protection in any specific application. This information should be used with discretion. Exposure Guidelines/Other: PHYSICAL AND CHEMICAL PROPERTIES 9 milky white Appearance: aerosol Physical State: strong aromatic Odor: Not Determined pH: 2.3 psia (Reid VP) @ 100°F / 37.8°C Vapor Pressure: 3.5 (air=1) Vapor Density: 195 F Boiling Point: Not Determined Freezing/Melting Pt.: Nil Solubility: 0.697 @ 60ºF (15.6ºC) Spec Grav./Density: Not Determined Not Determined 8.10 (nBuAc=1) 5.81 lbs/gal Not Determined Not Determined Not Appicable Not Appicable Not Determined Not Determined Not Determined Not Determined Heat Value: VOC: Evap. Rate: Bulk Density: Octanol: Molecular Weight: Particle Size: Softening Point: Viscosity: Percent Volatile: Sat. Vap. Concentrat.: Molecular Formula: TDL - The Dry Lube Material Safety Data Sheet Revision Date: 02/17/12 MSDS Number: TDL - aerosol Page of 3 6 MSDS The Blaster Corporation Page 1129 of 1287 Page 1129 of 1287 Page 1129 of 1287 Page 1129 of 1287 ---PAGE BREAK--- STABILITY AND REACTIVITY 10 This product is stable. Stability: Avoid excessive heat, sources of ingition and excessive water. Conditions to avoid: Avoid contact with strong oxidizing agents and strong reducing agents (strong acids or bases.) Avoid mixture with water. Materials to avoid (incompatability): Combustion will product carbon monoxide, carbon dioxide and other oxides. Hazardous Decomposition products: Will not occur. Hazardous Polymerization: TOXICOLOGICAL INFORMATION 11 Acute Toxicity Hazard LC50/LD50 Data Inhalation Unlikely to be harmful > 60 mg/L (Vapor) Skin Absorption Unlikely to be harmful > 2g/kg (estimated) Ingestion Unlikely to be harmful > 5g/kg (estimated) Aspiration Hazard: May be fatal if swallowed and enters airways. Skin Corrosion/Irritation: Causes skin irritation. Repeated exposure may cause skin dryness or cracking. Serious Eye Damage/Irritation: Causes mild eye irritation. Signs and Overexposure to vapors may result in respiratory tract irritation, coughing, nausea, headaches, vomiting, and CNS depression. Skin Sensitization: No information available. Respiratory Sensitization: No information available. Specific Target Organ Toxicity (Single Exposure): May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): Inadequate information available. Carcinogenicity: No information available. Germ Cell Mutagenicity: Inadequate information available. Reproductive Toxicity: Inadequate information available. Other Comments: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage (sometimes referred to as Solvent or Painters' Intentional misuse by deliberately concentrating and inhaling this material may be harmful or fatal. ECOLOGICAL INFORMATION 12 This product's ecological effects have not evaluated. Other Adverse Effects: None anticipated. TDL - The Dry Lube Material Safety Data Sheet Revision Date: 02/17/12 MSDS Number: TDL - aerosol Page of 4 6 MSDS The Blaster Corporation Page 1130 of 1287 Page 1130 of 1287 Page 1130 of 1287 Page 1130 of 1287 ---PAGE BREAK--- DISPOSAL CONSIDERATIONS 13 Used or unused product should be disposed of in accordance with local, state and federal regulations. Some special regulations may exist for the disposal of aerosol containers. Empty containers may contain residual pressure and contents. They should be handled with the same precautions as the product. TRANSPORT INFORMATION 14 Dept. of Transportation (DOT): This product, as it leaves Blaster's facilities, meets the definitions set forth in CFR 49 part 173.150c as a "consumer commodity." Allowing for certain exceptions (173.156) for domestic surface (ground) shipments. Proper shipping name: Consumer Commodity Hazard class: ORM-D International (IMDT-IATA): Proper shipping name: Aerosols, Limited Quantities Hazard class: 2.1 Flammable Compressed Gas UN Number: 1950 REGULATORY INFORMATION 15 SARA Title III Section 313 Reporting requirements: None Section 302 Extremely Hazardous Substances (TPQ): None EPA Toxic Substances Control Act (TSCA) Status: All of the components of this product are listed on the TSCA inventory. California Safe Drinking Water and Toxic Enforcement Act (Proposition 65): This product contains a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. VOC Regulations: This product complies with the consumer product VOC limits of CARB, the US EPA and states adopting the OTC VOC rules. Consumer Product Safety Act General Conformity Certification: This product was evaluated by The Blaster Corporation, and is certified to be in compliance with the provisions of the Consumer Product Safety Act, the Federal Hazardous Substances Act and the Poison Prevention Packaging Act, as applicable. This product was manufactured at the location listed in Section 1 of this MSDS. The date of manufacture is stamped on the product container. No testing is required to certify compliance with the above. TDL - The Dry Lube Material Safety Data Sheet Revision Date: 02/17/12 MSDS Number: TDL - aerosol Page of 5 6 MSDS The Blaster Corporation Page 1131 of 1287 Page 1131 of 1287 Page 1131 of 1287 Page 1131 of 1287 ---PAGE BREAK--- OTHER INFORMATION 16 Manufacturer's Disclaimer: To the best of our knowledge, the information contained herein is accurate. However, neither The Blaster Corporation nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exists. HMIS Ratings Health: 2 Fire: 3 Reactivity 0 END OF MSDS DOCUMENT TDL - The Dry Lube Material Safety Data Sheet Revision Date: 02/17/12 MSDS Number: TDL - aerosol Page of 6 6 MSDS The Blaster Corporation Page 1132 of 1287 Page 1132 of 1287 Page 1132 of 1287 Page 1132 of 1287 ---PAGE BREAK--- Ecoline Contact Cleaner Contact Cleaner Aerosol. Chemtrec - 1-[PHONE REDACTED] CANTUC (Canadian Transportation): (613) 996-6666 Emergency phone: (800) 858-4043 24/7 SAFETY DATA SHEET GHS product identifier Other means of identification Product type Emergency telephone number (with hours of operation) Section 1. Identification : : : : Supplier's details : 8125 Cobb Center Drive Kennesaw, GA 30152 Tel: [PHONE REDACTED] 1 [PHONE REDACTED] Ecoline Contact Cleaner Relevant identified uses of the substance or mixture and uses advised against Not applicable. Section 2. Hazards identification FLAMMABLE AEROSOLS - Category 1 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A GASES UNDER PRESSURE Compressed gas Classification of the substance or mixture : Signal word : Danger Hazard statements : Extremely flammable aerosol. Causes serious eye irritation. Contains gas under pressure; may explode if heated. Hazard pictograms : Precautionary statements Prevention : Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Pressurized container: Do not pierce or burn, even after use. Do not spray on an open flame or other ignition source. Wash hands thoroughly after handling. Response : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 Store in a well-ventilated place. Disposal : Not applicable. GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 25% OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Hazards not otherwise classified : None known. Date of issue/Date of revision : 5/20/2015. Date of previous issue : 5/5/2015. Version : 2 1/13 Page 1133 of 1287 Page 1133 of 1287 Page 1133 of 1287 Page 1133 of 1287 ---PAGE BREAK--- Ecoline Contact Cleaner Section 3. Composition/information on ingredients Ethyl alcohol 10 - 20 64-17-5 Isopropyl alcohol 7 - 15 67-63-0 methanol 1 - 3 67-56-1 Ingredient name CAS number % There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification : Contact Cleaner CAS number : Not applicable. Substance/mixture Product code : 1622-10S CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important acute and delayed Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Irritating to mouth, throat and stomach. : Ingestion Skin contact : May cause skin irritation. Causes serious eye irritation. : Eye contact Over-exposure Potential acute health effects Date of issue/Date of revision : 5/20/2015. Date of previous issue : 5/5/2015. Version : 2 2/13 Page 1134 of 1287 Page 1134 of 1287 Page 1134 of 1287 Page 1134 of 1287 ---PAGE BREAK--- Ecoline Contact Cleaner Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : In case of inhalation of decomposition products in a fire, may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Skin contact Ingestion Inhalation Adverse may include the following: respiratory tract irritation coughing Adverse may include the following: Irritating to mouth, throat and stomach. nausea or vomiting central nervous system depression Adverse may include the following: irritation redness dryness cracking : : : Eye contact : Adverse may include the following: pain or irritation watering redness See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide halogenated compounds carbonyl halides Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Date of issue/Date of revision : 5/20/2015. Date of previous issue : 5/5/2015. Version : 2 3/13 Page 1135 of 1287 Page 1135 of 1287 Page 1135 of 1287 Page 1135 of 1287 ---PAGE BREAK--- Ecoline Contact Cleaner Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. : Precautions for safe handling Date of issue/Date of revision : 5/20/2015. Date of previous issue : 5/5/2015. Version : 2 4/13 Page 1136 of 1287 Page 1136 of 1287 Page 1136 of 1287 Page 1136 of 1287 ---PAGE BREAK--- Ecoline Contact Cleaner Ethyl alcohol ACGIH TLV (United States, 4/2014). STEL: 1000 ppm 15 minutes. NIOSH REL (United States, 10/2013). TWA: 1900 mg/m³ 10 hours. TWA: 1000 ppm 10 hours. OSHA PEL (United States, 2/2013). TWA: 1900 mg/m³ 8 hours. TWA: 1000 ppm 8 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 1900 mg/m³ 8 hours. TWA: 1000 ppm 8 hours. Isopropyl alcohol ACGIH TLV (United States, 4/2014). STEL: 400 ppm 15 minutes. TWA: 200 ppm 8 hours. NIOSH REL (United States, 10/2013). STEL: 1225 mg/m³ 15 minutes. STEL: 500 ppm 15 minutes. TWA: 980 mg/m³ 10 hours. TWA: 400 ppm 10 hours. OSHA PEL (United States, 2/2013). TWA: 980 mg/m³ 8 hours. TWA: 400 ppm 8 hours. OSHA PEL 1989 (United States, 3/1989). STEL: 1225 mg/m³ 15 minutes. STEL: 500 ppm 15 minutes. TWA: 980 mg/m³ 8 hours. TWA: 400 ppm 8 hours. methanol ACGIH TLV (United States, 4/2014). Absorbed through skin. STEL: 328 mg/m³ 15 minutes. STEL: 250 ppm 15 minutes. TWA: 262 mg/m³ 8 hours. TWA: 200 ppm 8 hours. NIOSH REL (United States, 10/2013). Absorbed through skin. STEL: 325 mg/m³ 15 minutes. STEL: 250 ppm 15 minutes. TWA: 260 mg/m³ 10 hours. TWA: 200 ppm 10 hours. OSHA PEL (United States, 2/2013). TWA: 260 mg/m³ 8 hours. TWA: 200 ppm 8 hours. OSHA PEL 1989 (United States, 3/1989). Absorbed through skin. STEL: 325 mg/m³ 15 minutes. STEL: 250 ppm 15 minutes. TWA: 260 mg/m³ 8 hours. TWA: 200 ppm 8 hours. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Appropriate engineering controls : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Control parameters Occupational exposure limits Date of issue/Date of revision : 5/20/2015. Date of previous issue : 5/5/2015. Version : 2 5/13 Page 1137 of 1287 Page 1137 of 1287 Page 1137 of 1287 Page 1137 of 1287 ---PAGE BREAK--- Ecoline Contact Cleaner Section 8. Exposure controls/personal protection Hand protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. [Aerosol.] Not available. Not available. Not available. 7.4 kPa (55.49 mm Hg) [room temperature] Not available. Characteristic. Odor pH Clear. Colorless. Color Evaporation rate >1 (butyl acetate = 1) Flash point Closed cup: -5.5°C (22.1°F) Not available. Not available. Odor threshold : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Lower: 1.1% Upper: 6.7% Date of issue/Date of revision : 5/20/2015. Date of previous issue : 5/5/2015. Version : 2 6/13 Page 1138 of 1287 Page 1138 of 1287 Page 1138 of 1287 Page 1138 of 1287 ---PAGE BREAK--- Ecoline Contact Cleaner Section 9. Physical and chemical properties Auto-ignition temperature Not available. Not available. Viscosity Not available. Partition coefficient: n- octanol/water : : : Decomposition temperature : Not available. Type of aerosol : Spray Heat of combustion : 30.26 kJ/g Aerosol product Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability Reactive or incompatible with the following materials: alkalis Alkaline earth metal salt. Aluminum. zinc : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Ethyl alcohol LC50 Inhalation Vapor Rat 124700 mg/m³ 4 hours LD50 Oral Rat 7 g/kg - Isopropyl alcohol LD50 Dermal Rabbit 12800 mg/kg - LD50 Oral Rat 5000 mg/kg - methanol LC50 Inhalation Gas. Rat 145000 ppm 1 hours LC50 Inhalation Gas. Rat 64000 ppm 4 hours LD50 Dermal Rabbit 15800 mg/kg - LD50 Oral Rat 5600 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Ethyl alcohol Eyes - Mild irritant Rabbit - 24 hours 500 milligrams - Eyes - Moderate irritant Rabbit - 0.066666667 minutes 100 milligrams - Eyes - Moderate irritant Rabbit - 100 microliters - Eyes - Severe irritant Rabbit - 500 milligrams - Skin - Mild irritant Rabbit - 400 milligrams - Skin - Moderate irritant Rabbit - 24 hours 20 milligrams - Isopropyl alcohol Eyes - Moderate irritant Rabbit - 24 hours 100 milligrams - Product/ingredient name Result Score Exposure Observation Species Information on toxicological effects Date of issue/Date of revision : 5/20/2015. Date of previous issue : 5/5/2015. Version : 2 7/13 Page 1139 of 1287 Page 1139 of 1287 Page 1139 of 1287 Page 1139 of 1287 ---PAGE BREAK--- Ecoline Contact Cleaner Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Eyes - Moderate irritant Rabbit - 10 milligrams - Eyes - Severe irritant Rabbit - 100 milligrams - Skin - Mild irritant Rabbit - 500 milligrams - methanol Eyes - Moderate irritant Rabbit - 24 hours 100 milligrams - Eyes - Moderate irritant Rabbit - 40 milligrams - Skin - Moderate irritant Rabbit - 24 hours 20 milligrams - Sensitization Not available. Information on the likely routes of exposure Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Irritating to mouth, throat and stomach. : Ingestion Skin contact : May cause skin irritation. Causes serious eye irritation. : Eye contact related to the physical, chemical and toxicological characteristics Eye contact : Adverse may include the following: pain or irritation watering redness Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Isopropyl alcohol Category 3 Not applicable. Narcotic effects Name Category Not available. Aspiration hazard Not available. Route of exposure Target organs : Not available. Potential acute health effects Classification Ethyl alcohol - 1 - Isopropyl alcohol - 3 - methanol None. - - Product/ingredient name NTP IARC OSHA Date of issue/Date of revision : 5/20/2015. Date of previous issue : 5/5/2015. Version : 2 8/13 Page 1140 of 1287 Page 1140 of 1287 Page 1140 of 1287 Page 1140 of 1287 ---PAGE BREAK--- Ecoline Contact Cleaner Section 11. Toxicological information Not available. No known significant effects or critical hazards. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Skin contact Ingestion Inhalation Adverse may include the following: respiratory tract irritation coughing Adverse may include the following: Irritating to mouth, throat and stomach. nausea or vomiting central nervous system depression Adverse may include the following: irritation redness dryness cracking : : : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 39113.6 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Section 12. Ecological information Toxicity Ethyl alcohol Acute EC50 17.921 mg/l Marine water Algae - Ulva pertusa 96 hours Acute EC50 2000 µg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 25500 µg/l Marine water Crustaceans - Artemia franciscana - Larvae 48 hours Acute LC50 42000 µg/l Fresh water Fish - mykiss 4 days Chronic NOEC 4.995 mg/l Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 0.375 ul/L Fresh water Fish - Gambusia holbrooki - Larvae 12 weeks Isopropyl alcohol Acute LC50 1400000 to 1950000 µg/l Marine water Crustaceans - Crangon crangon 48 hours Acute LC50 1400000 µg/l Fish - Gambusia affinis 96 hours methanol Acute EC50 16.912 mg/l Marine water Algae - Ulva pertusa 96 hours Product/ingredient name Species Result Exposure Date of issue/Date of revision : 5/20/2015. Date of previous issue : 5/5/2015. Version : 2 9/13 Page 1141 of 1287 Page 1141 of 1287 Page 1141 of 1287 Page 1141 of 1287 ---PAGE BREAK--- Ecoline Contact Cleaner Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Ethyl alcohol -0.35 - low Isopropyl alcohol 0.05 - low methanol -0.77 <10 low Acute EC50 10000000 µg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 2500000 µg/l Marine water Crustaceans - Crangon crangon - Adult 48 hours Acute LC50 100 mg/l Fresh water Fish - Pimephales promelas - Juvenile (Fledgling, Hatchling, Weanling) 96 hours Chronic NOEC 9.96 mg/l Marine water Algae - Ulva pertusa 96 hours Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Not available. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. : Disposal methods United States - RCRA Toxic hazardous waste List Methanol Methyl alcohol 67-56-1 Listed U154 Ingredient CAS # Status Reference number Section 14. Transport information Consumer commodity ORM-D AEROSOLS IN LIMITED QUANTITIES OF CLASS 2 2.1 Consumer commodity ID8000 ID8000 9 Not available. 1950 DOT Classification IMDG IATA UN number UN proper shipping name Transport hazard class(es) TDG Classification Not available. Consumer commodity ORM-D ORM-D ADR/RID UN1950 Aerosols, flammable 2 Mexico Classification Not available. Consumer commodity ORM-D ORM-D Date of issue/Date of revision : 5/20/2015. Date of previous issue : 5/5/2015. Version : 2 10/13 Page 1142 of 1287 Page 1142 of 1287 Page 1142 of 1287 Page 1142 of 1287 ---PAGE BREAK--- Ecoline Contact Cleaner Section 14. Transport information - II - - - - Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No. No. No. Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. : - No. - II No. Tunnel code - No. - Section 15. Regulatory information U.S. Federal regulations Clean Air Act (CAA) 112 regulated flammable substances: 1,1-difluoroethane : SARA 313 Clean Air Act Section 112 Hazardous Air Pollutants (HAPs) : Listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Not listed TSCA 8(a) PAIR: heptane TSCA 8(a) CDR Exempt/Partial exemption: Not determined All components are listed or exempted. SARA 302/304 SARA 304 RQ : Not applicable. No products were found. Composition/information on ingredients SARA 311/312 Classification : Fire hazard Immediate (acute) health hazard Ethyl alcohol 10 - 20 Yes. No. No. Yes. No. Isopropyl alcohol 7 - 15 Yes. No. No. Yes. No. methanol 1 - 3 Yes. No. No. Yes. No. Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients Date of issue/Date of revision : 5/20/2015. Date of previous issue : 5/5/2015. Version : 2 11/13 Page 1143 of 1287 Page 1143 of 1287 Page 1143 of 1287 Page 1143 of 1287 ---PAGE BREAK--- Ecoline Contact Cleaner Section 15. Regulatory information The following components are listed: HEPTANE (N-HEPTANE); DIFLUOROETHANE; ETHYL ALCOHOL; ISOPROPYL ALCOHOL; METHANOL WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Massachusetts : Product name CAS number % SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. methanol No. Yes. No. 23000 µg/day (ingestion) 47000 µg/day (inhalation) Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level Isopropyl alcohol 67-63-0 7 - 15 methanol 67-56-1 1 - 3 Isopropyl alcohol 67-63-0 7 - 15 methanol 67-56-1 1 - 3 Form R - Reporting requirements Supplier notification California Prop. 65 New York : The following components are listed: Methanol New Jersey : The following components are listed: n-HEPTANE; HEPTANE; 1,1-DIFLUOROETHANE; ETHANE, 1,1-DIFLUORO-; ETHYL ALCOHOL; ALCOHOL; ISOPROPYL ALCOHOL; 2-PROPANOL; METHYL ALCOHOL; METHANOL : The following components are listed: HEPTANE; DENATURED ALCOHOL; 2-PROPANOL; METHANOL State regulations International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Inform Consent (PIC) Not listed. Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. International lists National inventory Australia : All components are listed or exempted. Canada : All components are listed or exempted. China : All components are listed or exempted. Europe : All components are listed or exempted. Japan : All components are listed or exempted. Republic of Korea : All components are listed or exempted. Malaysia : Not determined. New Zealand : All components are listed or exempted. Philippines : All components are listed or exempted. Date of issue/Date of revision : 5/20/2015. Date of previous issue : 5/5/2015. Version : 2 12/13 Page 1144 of 1287 Page 1144 of 1287 Page 1144 of 1287 Page 1144 of 1287 ---PAGE BREAK--- Ecoline Contact Cleaner Section 15. Regulatory information Taiwan : All components are listed or exempted. Section 16. Other information 5/20/2015. History Date of printing Date of issue/Date of revision Version To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Notice to reader Date of previous issue : : : : Indicates information that has changed from previously issued version. References : Not available. Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 5/20/2015. 5/5/2015. 2 Hazardous Material Information System 1 3 0 0 3 1 National Fire Protection Association Health Special Instability/Reactivity Flammability Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Date of issue/Date of revision : 5/20/2015. Date of previous issue : 5/5/2015. Version : 2 13/13 Page 1145 of 1287 Page 1145 of 1287 Page 1145 of 1287 Page 1145 of 1287 ---PAGE BREAK--- Date of issue/Date of revision : 06/02/2015 Version : 1 1 FVP BLEND 5W20 MOTOR OIL QUART Safety Data Sheet Section 1. Identification GHS product identifier : FVP 5W20 Product code : FVP5W20SB-QT Other means of identification Product type : Not available. : Liquid. Relevant identified uses of the substance or mixture and uses advised against Identified uses Industrial applications: Lubricating Oil Uses advised against Reason Not available. Supplier's details : Factory Motor Parts 1380 Corporate Center Curve, Suite 200 Eagan, MN 55121 1-[PHONE REDACTED] Emergency telephone number (with hours of operation) : 24 hr. CHEMTREC 1-[PHONE REDACTED] / International 1-[PHONE REDACTED] Section 2. Hazards identification OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product. Classification of the substance or mixture : Not classified. Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 2.3% Percentage of the mixture consisting of ingredient(s) of unknown hazards to the aquatic environment: 2.3% GHS label elements Signal word : No signal word. Hazard statements : No known significant effects or critical hazards. Precautionary statements Prevention : Not applicable. Response : Not applicable. Storage : Not applicable. Disposal : Not applicable. Hazards not otherwise classified : None known. Page 1146 of 1287 Page 1146 of 1287 Page 1146 of 1287 Page 1146 of 1287 ---PAGE BREAK--- Date of issue/Date of revision : 06/02/2015 Version : 1 2 Section 3. Composition/information on ingredients Substance/mixture : Mixture Other means of identification : Not available. CAS number/other identifiers CAS number : Not applicable. There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Description of necessary first aid measures Eye contact Inhalation Skin contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if occur. : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if occur. Ingestion : Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if occur. Most important acute and delayed Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards. Over-exposure Eye contact : No specific data. Inhalation Skin contact Ingestion : No specific data. : No specific data. : No specific data. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire. : Do not use water jet. Page 1147 of 1287 Page 1147 of 1287 Page 1147 of 1287 Page 1147 of 1287 ---PAGE BREAK--- Date of issue/Date of revision : 06/02/2015 Version : 1 3 Section 5. Fire-fighting measures Specific hazards arising from the chemical Hazardous thermal decomposition products : In a fire or if heated, a pressure increase will occur and the container may burst. : Decomposition products may include the following materials: carbon dioxide carbon monoxide Special protective actions for fire-fighters Special protective equipment for fire-fighters : isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up Small spill : Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handling Protective measures Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities : Put on appropriate personal protective equipment (see Section : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. : Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Page 1148 of 1287 Page 1148 of 1287 Page 1148 of 1287 Page 1148 of 1287 ---PAGE BREAK--- Date of issue/Date of revision : 06/02/2015 Version : 1 4 Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits None. Appropriate engineering controls Environmental exposure controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection Skin protection Hand protection Body protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Section 9. Physical and chemical properties Appearance Physical state Color Odor Odor threshold pH Melting point : Liquid. : Bright Clear. Pale color. Orange. : Not available. : Not available. : Not available. : Not available. Boiling point : Not available. Flash point Evaporation rate : Open cup: 221°C (429.8°F) : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Vapor pressure Vapor density : Not available. : Not available. Page 1149 of 1287 Page 1149 of 1287 Page 1149 of 1287 Page 1149 of 1287 ---PAGE BREAK--- Date of issue/Date of revision : 06/02/2015 Version : 1 5 Section 9. Physical and chemical properties Relative density Solubility Partition coefficient: n- octanol/water Auto-ignition temperature : 0.863 : Insoluble in the following materials: cold water and hot water. : Not available. : Not available. Decomposition temperature : Not available. Viscosity : Kinematic (40°C (104°F)): 0.43 cm2/s (43 cSt) Section 10. Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to avoid : No specific data. Incompatible materials : No specific data. Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition products should not be produced. Section 11. Toxicological information Information on toxicological effects Acute toxicity Not available. Irritation/Corrosion Not available. Sensitization Not available. Mutagenicity Not available. Carcinogenicity Not available. Reproductive toxicity Not available. Teratogenicity Not available. Specific target organ toxicity (single exposure) Not available. Specific target organ toxicity (repeated exposure) Not available. Aspiration hazard Not available. Page 1150 of 1287 Page 1150 of 1287 Page 1150 of 1287 Page 1150 of 1287 ---PAGE BREAK--- Date of issue/Date of revision : 06/02/2015 Version : 1 6 Section 11. Toxicological information Information on the likely routes of exposure Potential acute health effects : Not available. Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards. related to the physical, chemical and toxicological characteristics Eye contact : No specific data. Inhalation Skin contact Ingestion : No specific data. : No specific data. : No specific data. Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate effects : Not available. Potential delayed effects : Not available. Long term exposure Potential immediate effects : Not available. Potential delayed effects : Not available. Potential chronic health effects Not available. General : Carcinogenicity : Mutagenicity : Teratogenicity : No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Numerical measures of toxicity Acute toxicity estimates Not available. Section 12. Ecological information Toxicity Not available. Persistence and degradability Not available. Bioaccumulative potential Not available. Page 1151 of 1287 Page 1151 of 1287 Page 1151 of 1287 Page 1151 of 1287 ---PAGE BREAK--- Date of issue/Date of revision : 06/02/2015 Version : 1 7 Section 12. Ecological information Mobility in soil Soil/water partition coefficient (KOC) : Not available. Other adverse effects : No known significant effects or critical hazards. Section 13. Disposal considerations Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. RCRA classification : Not Regulated Section 14. Transport information DOT Classification TDG Classification IMDG IATA UN number Not regulated. Not regulated. Not regulated. Not regulated. Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. Section 15. Regulatory information U.S. Federal regulations : TSCA 8(a) PAIR: Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts TSCA 8(a) CDR Exempt/Partial exemption: Not determined All components are listed or exempted. Clean Water Act (CWA) 307: Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts Clean Air Act Section 112 Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances DEA List I Chemicals (Precursor Chemicals) DEA List II Chemicals (Essential Chemicals) SARA 302/304 : Not listed : Not listed : Not listed : Not listed : Not listed Composition/information on ingredients Page 1152 of 1287 Page 1152 of 1287 Page 1152 of 1287 Page 1152 of 1287 ---PAGE BREAK--- Date of issue/Date of revision : 06/02/2015 Version : 1 8 Section 15. Regulatory information No products were found. SARA 304 RQ : Not applicable. SARA 311/312 Classification : Not applicable. Composition/information on ingredients No products were found. State regulations Massachusetts : None of the components are listed. New York : None of the components are listed. New Jersey : The following components are listed: MINERAL OIL (UNTREATED and MILDLY TREATED) : None of the components are listed. California Prop. 65 This product is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International lists National inventory Australia : All components are listed or exempted. Canada : All components are listed or exempted. China : All components are listed or exempted. Europe : All components are listed or exempted. Japan : All components are listed or exempted. Malaysia : Not determined. New Zealand : Not determined. Philippines : Not determined. Republic of Korea : All components are listed or exempted. Taiwan : Not determined. Section 16. Other information Procedure used to derive the classification Classification Justification Not classified. History Date of issue/Date of revision Version : 06/02/2015 : 1 Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations Indicates information that has changed from previously issued version. Notice to reader Page 1153 of 1287 Page 1153 of 1287 Page 1153 of 1287 Page 1153 of 1287 ---PAGE BREAK--- Date of issue/Date of revision : 06/02/2015 Version : 1 9 Section 16. Other information To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Page 1154 of 1287 Page 1154 of 1287 Page 1154 of 1287 Page 1154 of 1287 ---PAGE BREAK--- 1. IDENTIFICATION Product identifier Product Name THE RIGHT STUFF GASKET MAKER 5 FL.OZ Other means of identification Product Code 29208 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Sealant Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: [PHONE REDACTED] International Emergency: 00+1+ [PHONE REDACTED] Contract Number: MIS0003453 E-mail address [EMAIL REDACTED] 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Serious eye damage/eye irritation Category 2A Skin sensitization Category 1 Carcinogenicity Category 2 Label elements Emergency Overview Page 1 / 8 Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Revision Date 03-Apr-2015 Causes serious eye irritation May cause an allergic skin reaction Suspected of causing cancer SAFETY DATA SHEET Version 1 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Warning Page 1155 of 1287 Page 1155 of 1287 Page 1155 of 1287 Page 1155 of 1287 ---PAGE BREAK--- Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water If skin irritation or rash occurs: Get medical advice/attention Wash contaminated clothing before reuse Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Not applicable Unknown acute toxicity 7.294% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret CALCIUM CARBONATE 471-34-1 30 - 60 * POLY HYDROXY TERMINATED 70131-67-8 15 - 40 * VINYL OXIMINOSILANE 2224-33-1 1 - 5 * CARBON BLACK 1333-86-4 1 - 5 * 2-BUTANONE OXIME 96-29-7 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures Page 2 / 8 29208 - THE RIGHT STUFF GASKET MAKER 5 FL.OZ Revision Date 03-Apr-2015 Appearance Black Physical state Paste Odor Mild Page 1156 of 1287 Page 1156 of 1287 Page 1156 of 1287 Page 1156 of 1287 ---PAGE BREAK--- General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash with soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If persist, call a physician. Ingestion IF SWALLOWED. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important and effects, both acute and delayed See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Page 3 / 8 29208 - THE RIGHT STUFF GASKET MAKER 5 FL.OZ Revision Date 03-Apr-2015 Page 1157 of 1287 Page 1157 of 1287 Page 1157 of 1287 Page 1157 of 1287 ---PAGE BREAK--- Methods for cleaning up Ensure adequate ventilation. Flood with water to complete polymerization and scrape off floor. Sweep up and shovel into suitable containers for disposal. Slippery, can cause falls if walked on. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container closed in a dry and well-ventilated place. Protect from moisture. Incompatible materials Strong oxidizing agents, Acids, Water 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH CALCIUM CARBONATE 471-34-1 - - TWA: 10 mg/m3 total dust TWA: 5 mg/m3 respirable dust CARBON BLACK 1333-86-4 TWA: 3 mg/m3 inhalable fraction TWA: 3.5 mg/m3 (vacated) TWA: 3.5 mg/m3 IDLH: 1750 mg/m3 TWA: 3.5 mg/m3 TWA: 0.1 mg/m3 Carbon black in presence of aromatic hydrocarbons PAH NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Paste Appearance Black Page 4 / 8 Revision Date 03-Apr-2015 29208 - THE RIGHT STUFF GASKET MAKER 5 FL.OZ Page 1158 of 1287 Page 1158 of 1287 Page 1158 of 1287 Page 1158 of 1287 ---PAGE BREAK--- Odor Mild Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Incompatible materials Strong oxidizing agents, Acids, Water Hazardous Decomposition Products Carbon oxides Nitrogen oxides (NOx) Formaldehyde May release 2-butanone oxime (ethyl methyl ketoxime) at elevated temperature 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Page 5 / 8 No information available Decomposition temperature No information available 29208 - THE RIGHT STUFF GASKET MAKER 5 FL.OZ Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values Lower flammability limit: No information available Revision Date 03-Apr-2015 Vapor pressure <5 mmHg @ 70°F Boiling point / boiling range Not Applicable No data available Vapor density 3 Remarks • Method Air = 1 Polymerization Relative density 1.34 Flash point Water solubility Not applicable > 93 °C / > 200 °F Polymerization Solubility in other solvents No information available Tag Closed Cup pH Partition coefficient No information available 7-8 Evaporation rate No information available Autoignition temperature Page 1159 of 1287 Page 1159 of 1287 Page 1159 of 1287 Page 1159 of 1287 ---PAGE BREAK--- Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. May cause sensitization by skin contact. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 CALCIUM CARBONATE 471-34-1 = 6450 mg/kg ( Rat ) - - POLY HYDROXY TERMINATED 70131-67-8 - > 16 mL/kg ( Rabbit ) > 8750 mg/m3 ( Rat ) 7 h CARBON BLACK 1333-86-4 > 15400 mg/kg ( Rat ) > 3 g/kg ( Rabbit ) - 2-BUTANONE OXIME 96-29-7 = 930 mg/kg ( Rat ) = 0.2 mg/kg ( Rabbit ) = 20 mg/L ( Rat ) 4 h Information on toxicological effects No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA CARBON BLACK 1333-86-4 A3 Group 2B - X ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Target Organ Effects Eyes, System, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 12217 mg/kg ATEmix (dermal) 10032 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity 99.854% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea CARBON BLACK 1333-86-4 - - 5600: 24 h Daphnia magna mg/L EC50 2-BUTANONE OXIME 96-29-7 83: 72 h Desmodesmus subspicatus mg/L EC50 777 - 914: 96 h Pimephales promelas mg/L LC50 flow-through 320 - 1000: 96 h Leuciscus idus mg/L LC50 static 760: 96 h Poecilia reticulata mg/L LC50 static 750: 48 h Daphnia magna mg/L EC50 Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Page 6 / 8 29208 - THE RIGHT STUFF GASKET MAKER 5 FL.OZ Revision Date 03-Apr-2015 Page 1160 of 1287 Page 1160 of 1287 Page 1160 of 1287 Page 1160 of 1287 ---PAGE BREAK--- Chemical Name Partition coefficient 2-BUTANONE OXIME 96-29-7 0.65 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Not Listed. ENCS Not Listed. IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Page 7 / 8 29208 - THE RIGHT STUFF GASKET MAKER 5 FL.OZ Revision Date 03-Apr-2015 Page 1161 of 1287 Page 1161 of 1287 Page 1161 of 1287 Page 1161 of 1287 ---PAGE BREAK--- SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 CARBON BLACK - 1333-86-4 Carcinogen U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts CARBON BLACK 1333-86-4 X X X ALUMINIUM POWDER 7429-90-5 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 03-Apr-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 8 / 8 29208 - THE RIGHT STUFF GASKET MAKER 5 FL.OZ - HMIS NFPA Health hazards 2 Revision Date 03-Apr-2015 Flammability 1 Physical hazards 0 Personal protection B Health hazards 2 Flammability 1 Instability 0 Page 1162 of 1287 Page 1162 of 1287 Page 1162 of 1287 Page 1162 of 1287 ---PAGE BREAK--- Thrust Product Code: C0805 Page 1 of 3 SAFETY DATA SHEET SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle® Thrust™ PRODUCT TYPE: Penetrating Oil PRODUCT CODE: C0805 MANUFACTURED FOR: Castle Products, Inc. 424 St. Paul Street Rochester, NY 14605 [PHONE REDACTED] • FAX [PHONE REDACTED] EMERGENCY [PHONE REDACTED] SECTION 2 HAZARD IDENTIFICATION EMERGENCY OVERVIEW: DANGER: Gases Under Pressure, Flammable, Irritant POTENTIAL HEALTH EFFECTS: Eyes: Irritating to eyes. Skin: Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis. Inhalation: Irritating to respiratory system. Avoid breathing vapors or mists. of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. Ingestion: Not an expected route of exposure. Potential for aspiration if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting, and diarrhea. SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % Petroleum Oil 64742-52-5 NE NE NE 40-70% Kerosene 8008-20-6 NE 200mg/m3 NE 10-30% Propane/Isobutane/N-Butane 68476-86-8 NE NE NE 10-30% Ethyl Acetic Ester 141-78-6 400ppm 400ppm NE 1-5% SECTION 4 FIRST AID MEASURES First Aid Procedures: Eye contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician if irritation persists. Skin contact: For skin contact flush with large amounts of water. Call a physician if irritation persists. Inhalation: Immediately remove from further exposure. Give supplemental oxygen, if breathing is difficult. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by mouth to an unconscious person. Note to physician: If the product is ingested, treat the affected person SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: -143°F (-97°C) LOWER EXPLOSIVE LIMIT: ND UPPER EXPLOSIVE LIMIT: ND EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate for surrounding fire. UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area. Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Ventilate spaces before entering. Environmental precautions: Prevent further leakage or spillage if safe to do so. Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Eliminate ignition sources including sources of electrical, static or frictional sparks. Wear appropriate protective equipment and clothing during clean-up. Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal. Page 1163 of 1287 Page 1163 of 1287 Page 1163 of 1287 Page 1163 of 1287 ---PAGE BREAK--- Thrust Product Code: C0805 Page 2 of 3 Large Spills: Dike far ahead of liquid spill for later disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. SECTION 7 HANDLING AND STORAGE Handling: Aerosol is extremely flammable. Store away from heat, sparks, and flames. Avoid breathing mist. Avoid contact with skin and eyes. Wear suitable protective clothing. Wash hands after handling. Storage: Keep from freezing. Keep containers closed. Store in a cool, dry place. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established. Engineering controls: Use local exhaust ventilation. Personal protective equipment: Gloves: Not normally required. Eye/Face Protection: Wear Safety Glasses or Goggles. Skin Protection: Wear clothing suited to the task being performed. Respiratory Protection: Not normally required if good ventilation is maintained. SECTION 9 PHYSICAL and CHEMICAL PROPERTIES BOILING POINT: ND SPECIFIC GRAVITY (H2O=1): ND VAPOR PRESSURE: ND PERCENT VOLATILE BY VOL 40% VAPOR DENSITY (air=1) >1 EVAPORATION RATE (Butyl Acetate=1): ND SOLUBILITY IN WATER: ND APPEARANCE & ODOR: Dark Green Liquid / Solvent pH: NA SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable under recommended storage conditions. INCOMPATIBILITY (material to avoid): Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide, Carbon Dioxide, Hydrocarbon fumes and smoke. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Component Test Results: None reported. Carcinogenicity: ACGIH A3 (animal carcinogen) for Kerosene. Target organ effects: Central nervous system, eyes, respiratory system, skin. SECTION 12 ECOLOGICAL INFORMATION Component Test Results: None reported. SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Dispose according to all applicable Federal, State, and Local regulations. SECTION 14 TRANSPORT INFORMATION DOT ground: Consumer Commodity ORM-D, or Limited Quantity. IATA: UN1950, Aerosols, Flammable, 2.1 LTD QTY. IMDG: UN1950, Aerosols, 2.1, LTD QTY. SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations. CERCLA (Superfund) reportable quantity: None SARA (Superfund Amendments and Reauthorization Act of 1986): 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Section 302 extremely hazardous substance: No Section 311 hazardous chemical: No Page 1164 of 1287 Page 1164 of 1287 Page 1164 of 1287 Page 1164 of 1287 ---PAGE BREAK--- Thrust Product Code: C0805 Page 3 of 3 Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR. SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.) HMIS® ratings Health: 2 Flammability: 4 Physical hazard: 2 NFPA ratings Health: 2 Flammability: 4 Instability: 0 Other: NA-Not Applicable, ND-Not Determined, NE-Not Established. Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. PREPARED: 9/25/96 UPDATED: 6/13/13 PRODUCT C0805 Page 1165 of 1287 Page 1165 of 1287 Page 1165 of 1287 Page 1165 of 1287 ---PAGE BREAK--- Page 1166 of 1287 Page 1166 of 1287 Page 1166 of 1287 Page 1166 of 1287 ---PAGE BREAK--- Page 1167 of 1287 Page 1167 of 1287 Page 1167 of 1287 Page 1167 of 1287 ---PAGE BREAK--- Page 1168 of 1287 Page 1168 of 1287 Page 1168 of 1287 Page 1168 of 1287 ---PAGE BREAK--- Page 1169 of 1287 Page 1169 of 1287 Page 1169 of 1287 Page 1169 of 1287 ---PAGE BREAK--- Page 1170 of 1287 Page 1170 of 1287 Page 1170 of 1287 Page 1170 of 1287 ---PAGE BREAK--- Page 1171 of 1287 Page 1171 of 1287 Page 1171 of 1287 Page 1171 of 1287 ---PAGE BREAK--- Page 1172 of 1287 Page 1172 of 1287 Page 1172 of 1287 Page 1172 of 1287 ---PAGE BREAK--- Page 1173 of 1287 Page 1173 of 1287 Page 1173 of 1287 Page 1173 of 1287 ---PAGE BREAK--- Page 1174 of 1287 Page 1174 of 1287 Page 1174 of 1287 Page 1174 of 1287 ---PAGE BREAK--- Page 1175 of 1287 Page 1175 of 1287 Page 1175 of 1287 Page 1175 of 1287 ---PAGE BREAK--- Page 1176 of 1287 Page 1176 of 1287 Page 1176 of 1287 Page 1176 of 1287 ---PAGE BREAK--- Page 1177 of 1287 Page 1177 of 1287 Page 1177 of 1287 Page 1177 of 1287 ---PAGE BREAK--- Material Safety Data Sheet Page 1 / 7 SDS # : A-1030 Issuing Date 2006-04-13 Revision Date 2011-05-20 Version 1 Toner Cartridge -Black Ingestion No known effect Chronic effects Acute toxicity Chronic toxicity No known effects under normal use conditions. Repeated or prolonged inhalation may cause irritation of the respiratory tract as can occur with the inhalation of any non- toxic dust. Minimum respiratory or eye irritation may occur as with exposure to large amounts of any non-toxic dust. Main Overexposure may cause:, mild, respiratory irritation, similar to nuisance dust Eyes Aggravated Medical Conditions None under normal use conditions No known effect 2. HAZARDS IDENTIFICATION Environmental hazard See Section 12 for additional Ecological Information Potential Health Effects Skin No known effect Risk Phrases None required Inhalation No known effect Principle Routes of Exposure Inhalation Emergency Overview The product contains no substances which, in the form utilized and at their given concentrations, are considered to be hazardous to health. Color Black Pure substance/preparation Emergency telephone Safety Information (800)828-6571 Health Emergency (585)422-2177 Chemical Emergency only (Chemtrec) (800)424-9300 or (703)527-3887 (collect outside the US or Canada) Preparation 1. PRODUCT AND COMPANY IDENTIFICATION Part No. 006R00959, 003R99623, 106R02148, 106R02144 Identified uses Xerographic printing for Manufactured by: Odor Faint Xerox Corporation Rochester, NY 14644 Appearance Powder HP LaserJet 4250 Series, HP LaserJet 4350 Series, Q5942X, HP LaserJet 4200 Series, HP LaserJet 4000, HP Laser Jet 4050 Trade Name: Color Black Physical state Solid Toner Page 1178 of 1287 Page 1178 of 1287 Page 1178 of 1287 Page 1178 of 1287 ---PAGE BREAK--- SDS # : A-1030 Toner Cartridge -Black Page 2 / 7 Skin contact Suitable extinguishing media Use water spray or fog; do not use straight streams, Foam Notes to physician Treat Wash skin with soap and water Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire Protection of first-aiders Hazardous combustion products Hazardous decomposition products due to incomplete combustion. Carbon oxides. Nitrogen oxides (NOx). No special protective equipment required. 4. FIRST AID MEASURES Explosion Data Inhalation Move to fresh air Sensitivity to Mechanical Impact Not sensitive. 5. FIRE-FIGHTING MEASURES Eye contact Sensitivity to Static Discharge Fine dust dispersed in air, in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes Specific hazards arising from the chemical Fine dust dispersed in air, in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Flammable properties Not flammable. Will not readily ignite. General advice Protective Equipment and Precautions for Firefighters In the event of fire and/or explosion do not breathe fumes. Wear fire/flame resistant/retardant clothing. Use self-contained pressure-demand breathing apparatus if needed to prevent exposure to smoke or airborne toxins. Ingestion Rinse mouth with water and afterwards drink plenty of water or milk NFPA 704 Flash point not applicable For external use only. When persist or in all cases of doubt seek medical advice. Show this material safety data sheet to the doctor in attendance. 3. COMPOSITION/INFORMATION ON INGREDIENTS Polyester resin 119681-36-6 40-55 Chemical Name Iron oxide 1317-61-9 35-55 CAS-No Weight % Page 1179 of 1287 Page 1179 of 1287 Page 1179 of 1287 Page 1179 of 1287 ---PAGE BREAK--- Page 3 / 7 SDS # : A-1030 Toner Cartridge -Black Methods for containment Prevent dust cloud. Hygiene measures None under normal use condtions Industrial User Do not eat, drink or smoke when using this product Wash hands before eating, drinking, chewing gum, using tobacco, or using toilet Wash hands before breaks and at the end of workday Provide regular cleaning of equipment, work area and clothing Methods for cleaning up Prevent dust cloud. Sweep up or vacuum up spillage and collect in suitable container for disposal. Use non-sparking tools and equipment. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure guidelines Personal Precautions Avoid breathing dust. Product information Other Information See Section 12 for additional information ACGIH TLV TWA 10 mg/m3 (inhalable particles) ACGIH TLV TWA 3 mg/m3 (respirable particles) 7. HANDLING AND STORAGE OSHA PEL TWA 15 mg/m3 (total dust) OSHA PEL TWA 5 mg/m3 (respirable dust) Xerox Exposure Limit 2.5 mg/m3 (total dust) Environmental Precautions Refer to protective measures listed in Sections 7 and 8. Xerox Exposure Limit 0.4 mg/m3 (respirable dust) Advice on safe handling Handle in accordance with good industrial hygiene and safety practice Prevent dust cloud Other Information The results obtained from a Xerox sponsored Chronic Toner Inhalation Study demonstrated no lung changes in rats for the lowest (1mg/m3 ) exposure level (the level most relevant to potential human exposure). A very slight degree of fibrosis was noted in 25% of animals at the middle (4mg/m3 )exposure level, while a slight degree of fibrosis was noted in all the animals at the highest (16mg/m3 ) exposure level. These findings are attributed to "lung overloading", a generic response to excessive amounts of any dust retained in the lungs for a prolonged period. This study was conducted using a special test toner to comply with an EPA testing protocol. Biological standards This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific regulatory bodies Technical measures/Storage conditions Keep container closed in a dry and well-ventilated place Store at room temperature 6. ACCIDENTAL RELEASE MEASURES Special hazard None Flammability 3 Stability 0 Health Hazard 0 Consumer use Stability 0 Health Hazard 0 Flammability 1 Bulk Packaging Special hazard None Page 1180 of 1287 Page 1180 of 1287 Page 1180 of 1287 Page 1180 of 1287 ---PAGE BREAK--- Page 4 / 7 SDS # : A-1030 Toner Cartridge -Black In case of insufficient ventilation: Wear protective eyewear (goggles) Effective dust mask Respiratory protection Flammability Limits in Air not applicable No special protective equipment required. Industrial use 9. PHYSICAL AND CHEMICAL PROPERTIES Avoid dust formation Ensure all equipment is electrically grounded before beginning transfer operations Provide appropriate exhaust ventilation at places where dust is formed Occupational Exposure Controls Explosive properties Fine dust dispersed in air, in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard Eye/Face protection Vapor pressure not applicable No special protective equipment required. Vapor density not applicable Water solubility Negligible Viscosity not applicable Engineering measures None under normal use conditions. Partition coefficient not applicable Evaporation rate not applicable Skin and body protection Melting point/range Not determined No special protective equipment required. Personal Protective Equipment Freezing point not applicable Specific gravity not applicable Consumer use 10. STABILITY AND REACTIVITY Hand protection No special protective equipment required These recommendations apply to the product as supplied Reactivity No dangerous reaction known under conditions of normal use Industrial use 49 - 60 °C / 120 - 140 °F Odor threshold not applicable Appearance Powder Autoignition temperature not applicable Flash point not applicable pH not applicable Odor Faint Boiling point/range not applicable Physical state Solid Color Black Softening point Page 1181 of 1287 Page 1181 of 1287 Page 1181 of 1287 Page 1181 of 1287 ---PAGE BREAK--- Toner Cartridge -Black Page 5 / 7 SDS # : A-1030 Prevent dust cloud, Fine dust dispersed in air, in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard Chronic effects No known effects under normal use conditions. Repeated or prolonged inhalation may cause irritation of the respiratory tract as can occur with the inhalation of any non- toxic dust. Minimum respiratory or eye irritation may occur as with exposure to large amounts of any non-toxic dust. Carcinogenicity See "Other Information" in this section. Hazardous polymerization Hazardous polymerization does not occur Acute toxicity None Other toxic effects Product information Product information Sensitization No sensitization responses were observed Irritation Mutagenic effects Not mutagenic in AMES Test No skin irritation No eye irritation Stability Target organ effects None known. Hazardous reactions LD50 Oral: > 5 g/kg (rat) Other adverse effects None known. None under normal processing. Aspiration Hazard not applicable LD50 Dermal: > 5 g/kg (rabbit) Hazardous Decomposition Products Other information The IARC (International Agency for Research on Cancer) has listed carbon black as "possibly carcinogenic to humans". The classification is based on studies evaluating pure, "free" carbon black. In contrast, toner is a formulation composed of specially prepared polymer and a small amount of carbon black (or other pigment). In the process of making toner, the small amount of carbon black becomes encapsulated within a matrix. Xerox has performed extensive testing of toner, including a chronic bioassay (test for potential carcinogenicity). Exposure to toner did not produce evidence of cancer in exposed animals. The results were submitted to regulatory agencies and published extensively. LC50 Inhalation: > 5 mg/L (rat, 4 hr) 12. ECOLOGICAL INFORMATION None under normal use. Stable under normal conditions Ecotoxicity 11. TOXICOLOGICAL INFORMATION Incompatible products The environmental impact of this product has not been fully investigated. However, this preparation is not expected to present significant adverse environmental effects. Chronic toxicity The toxicity data noted below is based on the test results of similar reprographic materials. Product information Conditions to Avoid Page 1182 of 1287 Page 1182 of 1287 Page 1182 of 1287 Page 1182 of 1287 ---PAGE BREAK--- Page 6 / 7 SDS # : A-1030 Toner Cartridge -Black Fire Hazard No International Inventories U.S. Federal Regulations Sudden Release of Pressure Hazard No Reactive Hazard No 15. REGULATORY INFORMATION SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. Clean Water Act TSCA This product is not regulated as a pollutant pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product is not regulated as a hazardous air pollutant (HAPS) under Section 112 of the Clean Air Act Amendments of 1990. Complies CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. TSCA TSCA 12b does not apply to this product. DSL/NDSL SARA 311/312 Hazard Categories Complies U.S. State Regulations Acute Health Hazard California Proposition 65 Carbon black is regulated under California Proposition 65 only if in the form of "airborne, unbound particles of respirable size". Toner products do not contain carbon black in the form of "airborne, unbound particles of respirable size". Therefore, the requirements of Proposition 65 do not apply to this product. No U.S. State Right-to-Know Regulations Chronic Health Hazard No This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements Contaminated packaging Dispose of in accordance with local regulations. 14. TRANSPORT INFORMATION 13. DISPOSAL CONSIDERATIONS Note This material is not subject to regulation as a hazardous material for shipping. Waste Disposal Methods Page 1183 of 1287 Page 1183 of 1287 Page 1183 of 1287 Page 1183 of 1287 ---PAGE BREAK--- SDS # : A-1030 Toner Cartridge -Black Page 7 / 7 Revision Note Part number 106R02144 added Model HP LaserJet 4000/4050 added Issuing Date 2006-04-13 Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text Although this product contains substances included in some U.S. State Right-to-Know regulations, the particles are bound in a unique matrix and, therefore, the product does not pose any specific hazard. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. end Revision Date 2011-05-20 Canada 16. OTHER INFORMATION WHMIS Hazard Class Not subject to WHMIS classification Page 1184 of 1287 Page 1184 of 1287 Page 1184 of 1287 Page 1184 of 1287 ---PAGE BREAK--- turtle wax, inc 625 Willowbrook Ctr Pkwy Willowbrook, Illinois 60527 Material Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME TURTLE WAX OXY POWER OUT CARPET CLEANER PRODUCT CODE T-244R(C) CHEMICAL FAMILY Carpet & Upholstery Cleaner CHEMICAL NAME Mixture: Water, Surfactant, Silicone, Co-solvent FORMULA Mixture MANUFACTURER EMERGENCY TELEPHONE NUMBERS Turtle Wax, Inc. Transportation: 625 Willowbrook Centre Parkway CHEMTREC: [PHONE REDACTED] Willowbrook, IL 60527 Medical: Phone: [PHONE REDACTED] Contact your local Poison Control Center Fax: [PHONE REDACTED] 2. POSITION/INFORMATION ON INGREDIENTS COMPONENT CAS NUMBER CONCENTRATION (wt Isobutane 75-28-5 1-3% (Liquified Petroleum Gas) Propane 74-98-6 1-3% (Liquified Petroleum Gas) Propylene Glycol Methyl Ether 107-98-2 1-2% (Glycol Ether PM) EXPOSURE LIMITS 8 hrs. TWA(ppm) CARCINOGEN OSHA PEL ACGIH TLV (OSHA,NPT,IARC) Isobutane 1000ppm 1000ppm No (Liquified Petroleum Gas) Propane 1000ppm 1000ppm No (Liquified Petroleum Gas) Propylene Glycol Methyl Ether 100ppm 100ppm No (Glycol Ether PM) 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS INHALATION: Repeated or excessive inhalation of vapor can cause irritation, dizziness, and nausea. Intentional misuse by deliberately concentrating and inhaling vapors, may be harmful or fatal. No chronic effects known. INGESTION: Can cause digestive system upsets and nausea. Avoid sucking into lungs. No chronic effects known. SKIN CONTACT: Can cause irritation. No chronic effects known. EYE CONTACT: Flush with water for 15 minutes. Get medical attention if effects persist. PDF created with pdfFactory trial version www.pdffactory.com Page 1185 of 1287 Page 1185 of 1287 Page 1185 of 1287 Page 1185 of 1287 ---PAGE BREAK--- - 2 - 4. FIRST AID MEASURES EYE: Flush with water for 15 minutes. Get medical attention if effects persist. SKIN: Remove contaminated clothing. Wash effected areas thoroughly with soap and water. Launder clothing before re-use. INHALATION: Remove to fresh air. Use artificial respiration and oxygen if needed. INGESTION: Rinse mouth. Never give anything orally to someone who is unconscious. Give several large glasses of water to drink. Do not induce vomiting. If liquid is sucked into lungs, get prompt medical attention. 5. FIRE FIGHTING MEASURES FLASH POINT: Sprayed vapors can be ignited with a flame. Flame length 14 – 16 inches or less with no flash back to nozzle by CPSC test [16 CFR 1500.3(b)(6)(viii)] is rated non-flammable. NFPA 30: Aerosol Level 1 EXTINGUISHING MEDIA: Water Spray, Alcohol Foam, Carbon Dioxide, Dry Chemical. SPECIAL FIRE FIGHTING PROCEDURES: Aerosol cans, under pressure, can explode when heated above 140ºF (60ºC) and become projectiles. Treat contents as flammable liquid/explosive vapor fire. Keep unignited containers cool with water. Vapors, that are heavier than air, can collect in low areas and may travel to distant source of ignition and flashback. Avoid flow of material to sewers. See Sec. 8 for personal protection. 6. ACCIDENTIAL RELEASE MEASURES SPILL OR LEAK PROCEDURES: Remove all ignition sources. Provide good ventilation. Take up spills and put into closed containers. Avoid flow to sewers. Floors may be slippery. See Section 8 for other protective measures. 7. HANDLING AND STORAGE STORAGE TEMPERATURE (MIN./MAX.): 32º F (0º C)/120º F (49º C) SHELF LIFE: 7 years minimum when the original container is kept closed and properly stored. SPECIAL SENSITIVITY: None. HANDLING AND STORAGE PRECAUTIONS: Store in cool and ventilated places, but avoid freezing. Do not store above 120ºF (49ºC). 8. EXPOSURE CONTROLS/PERSONAL PROTECTION EYE PROTECTION REQUIREMENTS: Wear goggles. Have convenient eye wash stations. SKIN PROTECTION REQUIREMENTS: Wear chemical resistant gloves and other clothing as needed to prevent exposure. RESPIRATOR/VENTILATION REQUIREMENTS: Provide sufficient ventilation to avoid exposure levels above the established TLV. EXPOSURE LIMITS: Not established for product as whole. PDF created with pdfFactory trial version www.pdffactory.com Page 1186 of 1287 Page 1186 of 1287 Page 1186 of 1287 Page 1186 of 1287 ---PAGE BREAK--- - 3 - 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL FORM: Pressurized container COLOR: Clear liquid dispensed as a foam ODOR: typical BOILING POINT: n/av MELT / FREEZE POINT: n/av PH: 9.8 SOLUBILITY IN WATER: Complete SPECIFIC GRAVITY: 1.010 % NON-VOLATILE BY WEIGHT: 8.0% VAPOR PRESSURE: 35 PSIG @ 70ºF VAPOR DENSITY: n/av 10. REACTIVITY STABILITY: Stable HAZARDOUS POLYMERIZATION: Does not occur INCOMPATIBILITIES: DECOMPOSITION PRODUCTS: When burned: CO, CO2, Hydrocarbons 11. TOXICOLOGICAL INFORMATION ACUTE INHALATION: Can cause irritation, dizziness, and nausea CHRONIC INHALATION: None known ACUTE SKIN CONTACT: Can cause irritation, de-fatting, or dermatitis CHRONIC SKIN CONTACT: None known ACUTE EYE CONTACT: Causes irritation 12. ECOLOGICAL INFORMATION No data available. 13. DISPOSAL CONSIDERATIONS RCRA Hazardous Waste: Is not a RCRA hazardous waste. WASTE DISPOSAL METHOD: Dispose of product in accordance with all local, state and federal laws and regulations. PDF created with pdfFactory trial version www.pdffactory.com Page 1187 of 1287 Page 1187 of 1287 Page 1187 of 1287 Page 1187 of 1287 ---PAGE BREAK--- - 4 - 14. TRANSPORT INFORMATION DOT INFORMATION: ORM-D PROPER SHIPPING NAME: Consumer Commodity TECHNICAL SHIPPING NAME: Aerosols (Non-Flammable) HAZARD CLASS: 2.2 (Non Flammable Gas) UN NUMBER: 1950 PRODUCT RQ (lbs): LABEL: Non Bulk ORM-D Bulk Non-Flammable Gas PLACARD: Non Bulk None Bulk Non-Flammable Gas FREIGHT CLASS BULK: n/av FREIGHT CLASS PACKAGE: n/av PRODUCT LABEL None 15. REGULATORY INFORMATION TSCA STATUS: All ingredients are listed under TSCA. CERCLA REPORTABLE QUANTITY: None SARA TITLE III: SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES None SECTION 311/312 HAZARD CATEGORIES Acute Health Yes Chronic Health No Fire No Reactive No Sudden Release of Pressure Yes SECTION 313 CHEMICAL NAME CAS NUMBER CONCENTRATION Propylene Glycol Methyl Ether 107-98-2 1-2% RCRA STATUS: If discarded in its purchased form, this product would be an ignitable waste with an EPA Hazardous Waste Number of D001. However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product should be classified as a hazardous waste. (40CFR261.20-24) CANADIAN STATUS: All materials contained in this product are listed on the Canadian Domestic Substances List. EUROPEAN UNION: All materials contained in this product are listed on EINECS. PDF created with pdfFactory trial version www.pdffactory.com Page 1188 of 1287 Page 1188 of 1287 Page 1188 of 1287 Page 1188 of 1287 ---PAGE BREAK--- - 5 - STATE REGULATORY INFORMATION The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the MSDS may also be applicable for state requirements. For details on your regulatory requirements you should contact the appropriate agency in your state. COMPONENT/ CAS NUMBER CONCENTRATION STATE CODE None CA = Material known to the state of California to cause cancer and/or birth defects. (California Proposition 65). 16. OTHER INFORMATION HMIS CLASSIFICATION Health 1 Flammability 2 Reactivity 0 PPI B NFPA RATING Health 1 Fire 2 Reactivity 0 Special None REASON FOR ISSUE Revised for ANSI format. PREPARED BY James P. Heidel TITLE Technical Director, R&D APPROVAL DATE September 8, 2007 SUPERCEDES DATE March 8, 2007 REVISION NUMBER A - 1 This information is to the best of Turtle Wax, Inc.’s knowledge and belief, accurate and reliable. However, no representation, warranty, or guarantee is made to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to the suitableness and completeness of such information for his own particular use. PDF created with pdfFactory trial version www.pdffactory.com Page 1189 of 1287 Page 1189 of 1287 Page 1189 of 1287 Page 1189 of 1287 ---PAGE BREAK--- - 1 - UNITED 195 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 195 SMELL JEL Jellied Deodorant Spray December 22, 2012 HMIS III HEALTH (0 = Maximum Safety) 0 PHYSICAL HAZARD (0 = Maximum Safety) 0 Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 FLAMMABILITY (0 = Maximum Safety) 1 2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) Isopropyl alcohol 67-63-0 5-10 200 ppm 400 ppm 980 mg/m3 >5045 mg/kg (Rat/oral) 16000 ppm 8 hr (Rat) 1.2-propanediol 57-55-6 5-10 N/A N/A 22000-31000 Mg/kg(Rat/oral) N/A Propane/N-Butane 68476-85-7 10-30 1000 ppm 1800 mg/m3 1000 ppm 1800 mg/m3 N/A N/A 3. HAZARDS IDENTIFICATION Emergency Overview: Aerosol under pressure do not expose to high temperatures 120°F/49°C or store in direct sunlight. Routes of Entry: Eyes, Skin, Ingestion, Inhalation Eyes: May cause irritation. Skin: May cause slight irritation, possible dryness with prolonged contact. Inhalation: Intentional overexposure to mist or vapors may result in dizziness and headache. Ingestion: May cause nausea or gastric discomfort. Chronic Health Hazards: None known. Medical Conditions Generally Aggravated by Exposure: None known. Carcinogenicity (NTP/IARC/OSHA): None 4. FIRST AID MEASURES Eyes: Flush with plenty of water for 15 minutes and call a physician immediately. Skin: Wash with soap and water. If irritation persists, call a physician. If Inhaled: Remove patient to fresh air immediately. Apply artificial respiration if needed and call a physician. If Swallowed: Drink several glasses of water. Call a physician immediately. 5. FIRE FIGHTING MEASURES Flash Point (TCC): 180°F/82.2°C Explosive Limits: Lower (LEL): ND Upper (UEL): ND Flame Projection (Aerosol): Nonflammable per 16 CFR 1500.45 Hazardous Products of Combustion: When strongly heated, as in a fire, this product may produce carbon dioxide and carbon monoxide. Fire and Explosion Hazards: Do not expose aerosols to temperatures above 120°F/49°C or the container may burst, rupture or vent. Extinguishing Media: Water, foam, Carbon dioxide, Dry chemical, Fire Fighting Instructions: Wear self-contained breathing apparatus w/full protective clothing. Containers should be cooled with water to prevent vapor pressure build up. Prevent runoff from entering sewers and public waterways. 6. ACCIDENTAL RELEASE MEASURES Small Spills: Pick up small spills with rag or towel. Clean surface thoroughly to remove residual contamination. Large Spills: Remove sources of ignition and ventilate area. Soak up with an inert absorbent and place in designated disposal container. Prevent material from entering sewers or drains. Wash area thoroughly to remove residual contamination. MATERIAL SAFETY DATA SHEET 320 37th Avenue, St. Charles, Illinois 60174 To Reorder Call: www.unitedlabsinc.com . www.unitedlabsinc.ca [PHONE REDACTED] Always follow Label Directions and Cautions. * Chronic 2 Moderate 4 Severe 1 Slight 3 Serious 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: A Page 1190 of 1287 Page 1190 of 1287 Page 1190 of 1287 Page 1190 of 1287 ---PAGE BREAK--- - 2 - 7. HANDLING AND STORAGE Keep this product properly labeled and store in a cool, well-ventilated area, away from heat or other sources of ignition. Do not expose to direct sunlight or store at temperatures above 120°F/49°C. may cause bursting. Wash hands and face with soap and water after using this product. Keep out of reach of children. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Safety glasses recommended if direct contact is possible. Skin: Chemical resistant gloves recommended only for prolonged or repeated exposure. Respiratory: Not normally needed. If TLV is exceeded, an organic vapor cartridge respirator or SCBA may be needed. Engineering Controls: Ventilation not normally required and local exhaust generally adequate. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 212°F/100°C (Initial-Concentrate) Specific Gravity: 0.99 (Concentrate@77°F) Vapor Pressure: 17.5 77°F Melting Point: ND Vapor Density: >1 Evaporation Rate: <1 Solubility in Water: Soluble pH: 7.6—7.7 VOC (Volatile Organic Compounds): 24.9% Appearance and Odor: White aerosol foam in orange or mulberry scent 10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: When strongly heated, as in a fire, this product may produce carbon dioxide and carbon monoxide. Chemical Stability: Stable Conditions to Avoid (Polymerization): None Incompatibility: Avoid contact with strong oxidizers, alkalies, and acids. 11. TOXICOLOGICAL INFORMATION See section 2 12. ECOLOGICAL INFORMATION N/A 13. DISPOSAL CONSIDERATIONS Consult your local, state, provincial and federal regulations for proper disposal guidelines. Do not puncture or incinerate containers. Wrap container and place in trash collection. Disposal regulations may be different for each state and/or locality. Aerosol cans when vented to atmospheric pressure through normal use pose no disposal hazard. RCRA Hazard Class: Considered non-hazardous under RCA, however product should be fully characterized prior to disposal (40 CFR 261) 14. TRANSPORT INFORMATION US DOT: Consumer Commodity, ORM-D IMDG-Water/Ocean: UN 1950, AEROSOLS IN LIMITED QUANTITIES OF CLASS 2, 2.2, PG None IATA-Air: UN 1950, AEROSOLS IN LIMITED QUANTITIES OF CLASS 2, 2.2 PG None 15. REGULATORY INFORMATION U.S. Federal Regulations: TSCA (Toxic Substances Control Act): All Chemicals are listed or exempt CERCLA (Comprehensive Response Compensation, and Liability Act): None SARA Title III Section 302 EHS: None SARA Title III Section 311/312: None SARA Title III Section 313 Toxic Chemicals: Isopropyl Alcohol – CAS#67-63-0 State Regulations: California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? No Right-to-know acts for Rhode Island, Florida, Minnesota, Massachusetts, New Jersey, Tennessee, Connecticut hazardous material survey. Illinois toxic substances disclosure to employee act. 195WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR. California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? No 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 195 SMELL JEL PREPARED BY: Sandy Kopacz Page 1191 of 1287 Page 1191 of 1287 Page 1191 of 1287 Page 1191 of 1287 ---PAGE BREAK--- Safety Data Sheet Issue Date: 05-Feb-2013 Revision Date: 24-Feb-2015 Version 2 Page 1 / 6 1. IDENTIFICATION Product Identifier Product Name United 231 VANISHING ACT Other means of identification SDS # UNITED-231 Recommended use of the chemical and restrictions on use Recommended Use Industrial Strength Spot and Stain Remover. Uses Advised Against For industrial and institutional use only. Details of the supplier of the safety data sheet Supplier Address United Laboratories, Inc. 320 37th Avenue St. Charles, IL 60174 www.unitedlabsinc.com www.unitedlabsinc.ca Emergency Telephone Number Company Phone Number [PHONE REDACTED] (to reorder) Emergency Telephone (24 hr) INFOTRAC 1-[PHONE REDACTED] (North America) 1-[PHONE REDACTED] (International) 2. HAZARDS IDENTIFICATION Appearance Clear, colorless liquid Physical State Liquid Odor Very faint scent Classification Skin corrosion/irritation Category 1 Serious eye damage/eye irritation Category 1 Signal Word Danger Hazard Statements Causes severe skin burns and eye damage Precautionary Statements - Prevention Do not breathe dust/fume/gas/mist/vapors/spray. Wash face, hands and any exposed skin thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Page 1192 of 1287 Page 1192 of 1287 Page 1192 of 1287 Page 1192 of 1287 ---PAGE BREAK--- UNITED-231 - United 231 VANISHING ACT Revision Date: 24-Feb-2015 Page 2 / 6 Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a poison center or doctor/physician. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Precautionary Statements - Storage Store according to local rules and regulations. Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant . 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Trade Secret Proprietary 1-5 Trade Secret Proprietary 1-5 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** 4. FIRST-AID MEASURES First Aid Measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek immediate medical attention/advice. Skin Contact Wash with soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. Get medical attention if irritation occurs. Inhalation Remove to fresh air. If not breathing, give artificial respiration. Call a physician immediately. Ingestion Rinse mouth. Do not induce vomiting. Get medical attention immediately. Never give anything by mouth to an unconscious person. Dilute by giving a large amount of water. Most important and effects May cause severe burns to skin, eyes and other body tissue. Irritation and corrosive burns to mouth, throat, and stomach. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Water. Dry chemical. Carbon dioxide (CO2). Foam. Unsuitable Extinguishing Media Not determined Specific Hazards Arising from the Chemical Contact with metals may evolve flammable hydrogen gas. Hazardous Combustion Products Carbon oxides. Phosphorus oxides. Page 1193 of 1287 Page 1193 of 1287 Page 1193 of 1287 Page 1193 of 1287 ---PAGE BREAK--- UNITED-231 - United 231 VANISHING ACT Revision Date: 24-Feb-2015 Page 3 / 6 Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Use water spray to keep fire-exposed containers cool. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Small spills may be flushed away with copious amounts of water. Check with local authorities before flushing. Large spills should be picked up with a mop or absorbent material and placed in a suitable container for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Wash thoroughly after handling. Use personal protection recommended in Section 8. Do not breathe dust/fume/gas/mist/vapors/spray. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers closed in a dry, cool and well-ventilated place. Store locked up. Keep out of the reach of children. Incompatible Materials Oxidizers such as bleach. Strong acids. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Trade Secret 2 mg/m 3 2 mg/m 3 - Appropriate engineering controls Engineering Controls Apply technical measures to comply with the occupational exposure limits. Individual protection measures, such as personal protective equipment Eye/Face Protection Safety glasses. Skin and Body Protection Chemical resistant protective gloves. Respiratory Protection Ensure adequate ventilation, especially in confined areas. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Liquid Page 1194 of 1287 Page 1194 of 1287 Page 1194 of 1287 Page 1194 of 1287 ---PAGE BREAK--- UNITED-231 - United 231 VANISHING ACT Revision Date: 24-Feb-2015 Page 4 / 6 Appearance Clear, colorless liquid Odor Very faint scent Color Colorless Odor Threshold Not determined Property Values Remarks • Method pH 12-13 Melting Point/Freezing Point Not determined Boiling Point/Boiling Range 100 °C / 212 °F Flash Point None Evaporation Rate 1 (Water = 1) Flammability (Solid, Gas) n/a-liquid Upper Flammability Limits Not determined Lower Flammability Limit Not determined Vapor Pressure Not determined Vapor Density Not determined Specific Gravity 1.05 (Water = 1) Water Solubility Completely soluble Solubility in other solvents Not determined Partition Coefficient Not determined Auto-ignition Temperature Not determined Decomposition Temperature Not determined Kinematic Viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined VOC Content None 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to Avoid Keep out of reach of children. Incompatible Materials Oxidizers such as bleach. Strong acids. Hazardous Decomposition Products Carbon oxides. Phosphorous oxides. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Page 1195 of 1287 Page 1195 of 1287 Page 1195 of 1287 Page 1195 of 1287 ---PAGE BREAK--- UNITED-231 - United 231 VANISHING ACT Revision Date: 24-Feb-2015 Page 5 / 6 Eye Contact Causes severe eye damage. Skin Contact Causes severe skin burns. Inhalation Avoid breathing vapors or mists. Ingestion Do not taste or swallow. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Trade Secret > 5000 mg/kg ( Rat ) - - Trade Secret - > 4640 mg/kg ( Rabbit ) - Trade Secret = 600 mg/kg ( Rat ) - - Trade Secret = 10 g/kg ( Rat ) - - Information on physical, chemical and toxicological effects Please see section 4 of this SDS for Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Numerical measures of toxicity Not determined 12. ECOLOGICAL INFORMATION Ecotoxicity Not determined. Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Not determined Other Adverse Effects Not determined 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Page 1196 of 1287 Page 1196 of 1287 Page 1196 of 1287 Page 1196 of 1287 ---PAGE BREAK--- UNITED-231 - United 231 VANISHING ACT Revision Date: 24-Feb-2015 Page 6 / 6 14. TRANSPORT INFORMATION DOT Not regulated IATA Not regulated IMDG Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Listed Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. US State Regulations California Proposition 65 This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. U.S. State Right-to-Know Regulations Not determined 16. OTHER INFORMATION NFPA Health Hazards Not determined Flammability Not determined Instability Not determined Special Hazards Not determined HMIS Health Hazards 2 Flammability 0 Physical Hazards 0 Personal Protection B Issue Date: 05-Feb-2013 Revision Date: 24-Feb-2015 Revision Note: New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 1197 of 1287 Page 1197 of 1287 Page 1197 of 1287 Page 1197 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 320 37th Avenue • St. Charles, Illinois 60174 • To Reorder, Call [PHONE REDACTED] PRODUCT IDENTIFICATION USE / DESCRIPTION REVISION DATE FOR MEDICAL AND UNITED 45 Mop Soak Tablets April 9, 2001 TRANSPORTATION EMERGENCIES: INFOTRAC: [PHONE REDACTED] HEALTH (0 = Maximum Safety) REACTIVITY (0 = Maximum Safety) Always follow Label Directions and Cautions. Susceptible to Release of Energy. 4 Extreme. 3 High. 2 Moderate. 1 Slight. 0 Minimal. See Health Hazard Data Section of this M.S.D.S. for more detailed information. FLAMMABILITY (0 = Maximum Safety) Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated to burn. 3 Ignites at normal temperature. 0 Will not burn. 2 Ignites when moderately heated. HAZARDOUS CAS ACGIH ACGIH OSHA OTHER S.A.R.A. TITLE III COMPONENTS NUMBER TWA STEL PEL RECOMMENDED LIMITS QUANTITIES Sodium carbonate 497-19-8 Not Not Not None None established established established BOILING POINT SPECIFIC GRAVITY (H20 = 1) Not determined Not determined VAPOR PRESSURE (mm Hg.) MELTING POINT (At 77° Not determined 145.4° F VAPOR DENSITY (Air = 1) EVAPORATION RATE Not determined Not determined SOLUBILITY IN WATER VOLATILE ORGANIC COMPOUNDS Complete (Pounds Per Gallon Of Product) None APPEARANCE AND ODOR pH: Odorless white tablet Not determined FLASH POINT (Method Used) FLAMMABLE LIMITS LEL UEL None (Tag closed cup) Not applicable Not applicable Not applicable EXTINGUISHING MEDIA Media suitable to surrounding fire SPECIAL FIRE FIGHTING PROCEDURES Firefighters should wear full protective equipment and NIOSH-approved self-contained breathing apparatus. Product is not combustible but may liberate oxygen which supports combustion. UNUSUAL FIRE AND EXPLOSION HAZARDS None known 4 May detonate-vacate area if 2 Violent chemical change Materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. PERSONAL PROTECTION UNITED 45 HAZARDOUS COMPONENTS IDENTITY, EXPOSURE LIMITS AND S.A.R.A. TITLE III INFORMATION PHYSICAL / CHEMICAL CHARACTERISTICS FIRE AND EXPLOSION HAZARD DATA 1 1 0 PAGE (CONTINUED ON REVERSE SIDE) L A B O R A T O R I E S Page 1198 of 1287 Page 1198 of 1287 Page 1198 of 1287 Page 1198 of 1287 ---PAGE BREAK--- STABILITY: STABLE X CONDITIONS TO AVOID UNSTABLE X None known INCOMPATIBILITY (Materials To Avoid) Mixtures containing heavy metal salts and combustible organic materials HAZARDOUS DECOMPOSITION OR BYPRODUCTS None known HAZARDOUS POLYMERIZATION:WILL NOT OCCUR X CONDITIONS TO AVOID MAY OCCUR X None known HEALTH HAZARDS EYES: May cause irritation and burns SKIN: May cause irritation and burns INHALATION: May irritate respiratory system IF SWALLOWED: May irritate or burn the mouth, esophagus and stomach CARCINOGENICITY: NTP? No IARC MONOGRAPHS? No OSHA REGULATED? No This product contains a chemical known to the state of California to cause cancer or reproductive toxicity? No SIGNS AND OF OVEREXPOSURE EYES: Irritation SKIN: Irritation INHALATION: Breathing difficulties IF SWALLOWED: Burning sensation in the mouth, esophagus and stomach MEDICAL CONDITIONS GENERALLY AGGRAVATED BY OVEREXPOSURE None known TARGET ORGANS: Eyes EMERGENCY AND FIRST AID PROCEDURES EYES: Flush with plenty of water for at least 15 minutes. If irritation persists, call a physician or poison center. SKIN: Wash with soap and water. If irritation persists, call a physician or poison center. INHALATION: Remove to fresh air. If irritation persists, call a physician or poison center. IF SWALLOWED: DO NOT induce vomiting. If conscious, give large quantities of milk of magnesia. Call a physician or poison center immediately. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Sweep up or flush to drain if no incompatable materials are present. Do not place with combustible materials. Do not return to original container. WASTE DISPOSAL METHOD Consult local, state and federal authorities for proper disposal guidelines. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Keep containers closed and store in a cool, dry place away from heat sources. RESPIRATORY PROTECTION (Specify Type) Not normally required VENTILATION: MECHANICAL (General) LOCAL EXHAUST Provide adequate ventilation Generally adequate PROTECTIVE GLOVES EYE PROTECTION Rubber gloves Safety glasses recommended OTHER PROTECTIVE CLOTHING OR EQUIPMENT Shirts with long sleeves are recommended. WORK HYGENIC PRACTICES Wash hands and face with soap and water after using this product. REACTIVITY DATA HEALTH HAZARD DATA PRECAUTIONS FOR SAFE HANDLING AND USE CONTROL MEASURES FOR USE WHERE SIGNIFICANT EYE, SKIN OR INHALATION EXPOSURE IS LIKELY PAGE UNITED 45 FIZZ-FIZZ Page 1199 of 1287 Page 1199 of 1287 Page 1199 of 1287 Page 1199 of 1287 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Date of issue: 07/24/2015 EN (English US) Page 1 Section 1: Identification 1.1. Product identifier Product form : Mixture Product Identifier(s) : Unleaded Gasoline Grade Gasoline Regular Gasoline, Regular Unleaded Gasoline Mid-Grade Gasoline, Mid-Grade Unleaded Gasoline Premium Gasoline, Premium Unleaded Gasoline CAS No : 86290-81-5 1.2. Recommended use of the chemical and restrictions on use Use of the substance/mixture : Fuel 1.3. Details of the supplier of the safety data sheet Total Petrochemicals & Refining USA, Inc. P O Box 674411 Houston, TX 77267-4411 For non-emergency product information: Phone: [PHONE REDACTED] Email: [EMAIL REDACTED] 1.4. Emergency telephone number Emergency number : CHEMTREC: 1-[PHONE REDACTED] (Toll Free USA & Canada) / [PHONE REDACTED] (Multiple languages) Total Petrochemicals & Refining USA, Inc.: 1-[PHONE REDACTED] (Language: English only) Section 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Flammable liquids Category 1 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Germ cell mutagenicity Category 1B Carcinogenicity Category 1B Reproductive toxicity Category 2 Specific target organ toxicity (single exposure) Category 1 Specific target organ toxicity (single exposure) Category 3 - Respiratory irritation Specific target organ toxicity (single exposure) Category 3 - Narcotic effects Specific target organ toxicity (repeated exposure) Category 1 Aspiration hazard Category 1 Hazardous to the aquatic environment - Chronic Hazard Category 2 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Extremely flammable liquid and vapor May be fatal if swallowed and enters airways Causes skin irritation Causes serious eye irritation May cause respiratory irritation May cause drowsiness or dizziness May cause genetic defects Page 1200 of 1287 Page 1200 of 1287 Page 1200 of 1287 Page 1200 of 1287 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 2/12 May cause cancer Suspected of damaging fertility or the unborn child Causes damage to organs (lung) Causes damage to organs (blood, hematopoietic system [blood forming], kidneys, peripheral nervous system, brain (neurological), nervous system, visual organ (color vision effects), hearing organ (loss of hearing)) through prolonged or repeated exposure Toxic to aquatic life with long lasting effects Precautionary statements (GHS-US) : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from sparks, open flames, heat, hot surfaces. - No smoking. Keep container closed. Ground/bond container and receiving equipment. Use explosion-proof electrical, lighting, ventilating equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe spray, mist, vapors. Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear flame retardant protective clothing, impermeable protective gloves, eye protection, face protection. If swallowed: Immediately call doctor, poison center. Do NOT induce vomiting. If on skin: Wash with plenty of water. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Specific treatment (see Section 4.1 of SDS or information on this label). If exposed or concerned: Get medical advice/attention. Get medical advice/attention if you feel unwell. Take off contaminated clothing and wash it before reuse. In case of fire: Use Water spray, foam, carbon dioxide (CO2), dry chemical to extinguish. Collect spillage. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. 2.3. Hazards not otherwise classified Other hazards not contributing to the classification : Product can accumulate electrostatic charges that may cause fire by electrical discharges. 2.4. Unknown acute toxicity (GHS-US) 19 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation (Vapours)) 2.5. Additional information No additional information available Section 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Where concentrations in this product are displayed as ranges, it is due to batch-to-batch variability. Name CAS No % Other hydrocarbons ( C4- C14 ) - 5 - 40 Xylene 1330-20-7 1 - 20 Toluene 108-88-3 1 - 20 n-Heptane and Heptane Isomers - 0 - 20 Hexane isomers, excluding n-hexane - 0 - 20 n-Octane and Octane Isomers - 0 - 20 100-41-4 1 - 10 95-63-6 1 - 10 Page 1201 of 1287 Page 1201 of 1287 Page 1201 of 1287 Page 1201 of 1287 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 3/12 n-pentane 109-66-0 0 - 10 Isopentane 78-78-4 0 - 10 n-Nonane and Nonane Isomers - 0 - 10 n-Hexane 110-54-3 0 - 5 Benzene 71-43-2 0.1 - 2 Cyclohexane 110-82-7 0 - 2 Naphthalene 91-20-3 0.1 - 1 Cumene 98-82-8 0.1 - 1 Section 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center/doctor/physician if you feel unwell. First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if irritation persists. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a poison center or doctor/physician. 4.2. Most important and effects, both acute and delayed : May cause genetic defects. after inhalation : May cause respiratory irritation. May cause drowsiness or dizziness. after skin contact : Causes skin irritation. after ingestion : May be fatal if swallowed and enters airways. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available Section 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the chemical Fire hazard : Extremely flammable liquid and vapor. Explosion hazard : May form flammable/explosive vapor-air mixture. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Section 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Emergency procedures for non-emergency personnel : Evacuate unnecessary personnel. Emergency procedures for emergency responders : Ventilate area. Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. 6.2. Methods and material for containment and cleaning up For containment : Do not contaminate ground and surface water. Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.3. Reference to other sections See section 8. Exposure controls/personal protection. Section 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Page 1202 of 1287 Page 1202 of 1287 Page 1202 of 1287 Page 1202 of 1287 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 4/12 Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No bare lights. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Eliminate all ignition sources if safe to do so. Use only outdoors or in a well-ventilated area. Do not breathe vapors, mist, spray. Never siphon by mouth. DO NOT fill container while container is in vehicle. Hygiene measures : Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when using this product. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating, lighting equipment. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : flames, heat sources, sparks. Keep in fireproof place. Keep container closed. Incompatible products : Strong bases. Strong acids. Strong oxidizing agents. Strong reducing agents. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. Section 8: Exposure controls/personal protection 8.1. Occupational Exposure Limits Unleaded Gasoline (86290-81-5) USA ACGIH ACGIH TWA (ppm) 300 ppm USA ACGIH ACGIH STEL (ppm) 500 ppm n-Octane and Octane Isomers USA ACGIH ACGIH TWA (ppm) 300 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 2350 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 500 ppm n-Heptane and Heptane Isomers USA ACGIH ACGIH TWA (ppm) 400 ppm USA ACGIH ACGIH STEL (ppm) 500 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 2000 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 500 ppm Hexane isomers, excluding n-hexane USA ACGIH ACGIH TWA (ppm) 50 ppm USA OSHA OSHA PEL (TWA) (ppm) 500 ppm Toluene (108-88-3) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (ppm) 200 ppm USA OSHA OSHA PEL (Ceiling) (ppm) 300 ppm USA OSHA Remark (OSHA) See OSHA Table Z-2. Xylenes p- isomers) (1330-20-7) USA ACGIH ACGIH TWA (ppm) 100 ppm USA ACGIH ACGIH STEL (ppm) 150 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 435 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 100 ppm n-Nonane and Nonane Isomers USA ACGIH ACGIH TWA (ppm) 200 ppm Isopentane (78-78-4) USA ACGIH ACGIH TWA (ppm) 1000 ppm (Pentane, all isomers) USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm (Pentane, all isomers) n-pentane (109-66-0) USA ACGIH ACGIH TWA (ppm) 600 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 2950 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm (100-41-4) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 435 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 100 ppm Page 1203 of 1287 Page 1203 of 1287 Page 1203 of 1287 Page 1203 of 1287 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 5/12 n-Hexane (110-54-3) USA ACGIH ACGIH TWA (ppm) 50 ppm USA OSHA OSHA PEL (TWA) (ppm) 500 ppm Cyclohexane (110-82-7) USA ACGIH ACGIH TWA (ppm) 100 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 1050 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 300 ppm Benzene (71-43-2) USA ACGIH ACGIH TWA (ppm) 0.5 ppm USA ACGIH ACGIH STEL (ppm) 2.5 ppm USA OSHA OSHA PEL (TWA) (ppm) 1 ppm USA OSHA OSHA PEL (STEL) (ppm) 5 ppm USA OSHA Remark (OSHA) (see 29 CFR 1910.1028) Naphthalene (91-20-3) USA ACGIH ACGIH TWA (ppm) 10 ppm USA ACGIH ACGIH STEL (ppm) 15 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 50 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 10 ppm Cumene (98-82-8) USA ACGIH ACGIH TWA (ppm) 50 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 245 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 50 ppm 8.2. Exposure controls Appropriate engineering controls : Ensure adequate ventilation. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Impermeable protective gloves. Choosing the proper glove is a decision that depends not only on the type of material, but also on other quality features, which differ for each manufacturer. Gloves should be discarded and replaced if there is any indication of degredation or chemical breakthrough. The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear fire/flame resistant/retardant clothing. Respiratory protection : An approved organic vapor respirator/supplied air or self-contained breathing apparatus must be used when vapor concentration exceeds applicable exposure limits. Other information : Do not eat, drink or smoke during use. Section 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : Colorless. Amber or red, if dyed. Odor : Characteristic. Odor threshold : 83 ppm Weighted average pH : Not applicable Relative evaporation rate (butyl acetate=1) : No data available Relative evaporation rate (ether=1) : < 30 Slower than ethyl ether Melting point : < -60 °C Freezing point : No data available Boiling point : 27 (27 - 225) °C Flash point : < -35 °C (closed cup) Auto-ignition temperature : 280 - 470 °C (at 1013 hPa) Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : 500 - 700 mm Hg at 21°C Relative vapor density at 20 °C : 3 - 4 Air = 1 Relative density : 0.75 Page 1204 of 1287 Page 1204 of 1287 Page 1204 of 1287 Page 1204 of 1287 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 6/12 Solubility : Water: 30 - 100 mg/l (at 20 Log Kow : No data available Viscosity, kinematic : < 1 cSt at 40°C Viscosity, dynamic : No data available Explosive limits : 1.4 - 7.6 vol % 9.2. Other information VOC content : 100 % Section 10: Stability and reactivity 10.1. Reactivity Flammable liquid and vapor. 10.2. Chemical stability The product is stable at normal handling and storage conditions. 10.3. Possibility of hazardous reactions Under normal conditions of storage and use, hazardous polymerization will not occur. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. Sparks. Heat. Overheating. Open flame. 10.5. Incompatible materials Strong acids. Strong bases. Strong oxidizing agents. Strong reducing agents. 10.6. Hazardous decomposition products Hazardous decomposition products formed under fire conditions: carbon monoxide, carbon dioxide, toxic fumes. Section 11: Toxicological information 11.1. Information on toxicological effects Likely routes of exposure : Inhalation. Ingestion. Skin contact. Eye contact. Acute toxicity : Not classified Based on available data, the classification criteria are not met Combustion of hydrocarbon substances, like this product, produces potentially toxic gases which include carbon monoxide, carbon dioxide, oxides of nitrogen and/or sulfur. Exposure to carbon monoxide gas decreases the ability of the blood to carry oxygen to the body and may be potentially fatal. NIOSH lists the Immediately Dangerous to Life or Health Concentration (IDLH) for carbon monoxide gas as1200 ppm. Unleaded Gasoline (86290-81-5) LD50 oral rat > 5000 (5000 - 14000) mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat > 5.2 mg/l/4h Other hydrocarbons ( C4- C14 ) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat > 5 mg/l/4h n-Octane and Octane Isomers LD50 oral rat > 5000 mg/kg Based on Isooctane LD50 dermal rabbit > 2000 mg/kg Based on Isooctane LC50 inhalation rat > 24 mg/l/4h Based on n-Octane n-Heptane and Heptane Isomers LD50 oral rat > 5000 mg/kg Based on iso-octane LD50 dermal rabbit 3000 mg/kg Based on n-heptane LC50 inhalation rat 103 g/m³ Based on n-heptane Hexane isomers, excluding n-hexane LD50 oral rat 15840 mg/kg based on n-hexane LD50 dermal rabbit 3000 mg/kg based on n-hexane LC50 inhalation rat 259 mg/l/4h based on n-hexane LC50 inhalation rat (ppm) 48000 ppm/4h Toluene (108-88-3) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 5000 mg/kg LC50 inhalation rat 28.1 (28.1 - 49) mg/l/4h LC50 inhalation rat (ppm) > 26700 ppm/1h Page 1205 of 1287 Page 1205 of 1287 Page 1205 of 1287 Page 1205 of 1287 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 7/12 Xylenes p- isomers) (1330-20-7) LD50 oral rat 4300 mg/kg LD50 dermal rabbit > 4200 mg/kg LC50 inhalation rat 21.7 mg/l/4h n-Nonane and Nonane Isomers LD50 oral rat > 5000 mg/kg Based on Iso-Octane LD50 dermal rabbit > 2000 mg/kg Based on Iso-Octane LC50 inhalation rat 17 mg/l/4h Based on nonane LC50 inhalation rat (ppm) 3200 ppm/4h Isopentane (78-78-4) LD50 oral rat > 2000 mg/kg Based on n-pentane LD50 dermal rabbit 3000 mg/kg LC50 inhalation rat 280 mg/l/4h LC50 inhalation rat (ppm) > 4094 ppmV/4h n-pentane (109-66-0) LD50 oral rat > 2000 mg/kg LD50 dermal rabbit 3000 mg/kg LC50 inhalation rat 364 mg/l/4h (95-63-6) LD50 oral rat 5000 mg/kg LD50 dermal rabbit > 3160 mg/kg LC50 inhalation rat 18 mg/l/4h (100-41-4) LD50 oral rat 3500 mg/kg LD50 dermal rabbit 15354 mg/kg LC50 inhalation rat 17.2 mg/l/4h n-Hexane (110-54-3) LD50 oral rat 15840 mg/kg LD50 dermal rabbit 3000 mg/kg LC50 inhalation rat 259 mg/l/4h Cyclohexane (110-82-7) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat 13.9 mg/l/4h Benzene (71-43-2) LD50 oral rat 930 (930 - 6400) mg/kg LD50 dermal rabbit > 8272 mg/kg LC50 inhalation rat 34.4 mg/l/4h Naphthalene (91-20-3) LD50 oral rat 490 mg/kg LD50 dermal rabbit > 20 g/kg LC50 inhalation rat > 340 mg/m³ (Exposure time: 1 h) Cumene (98-82-8) LD50 oral rat 1400 mg/kg LD50 dermal rat 10600 mg/kg LC50 inhalation rat 39 mg/l/4h Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitization : Not classified Germ cell mutagenicity : May cause genetic defects. Carcinogenicity : May cause cancer. Unleaded Gasoline (86290-81-5) IARC group 2B - Possibly carcinogenic to humans Toluene (108-88-3) IARC group 3 - Not classifiable Xylenes p- isomers) (1330-20-7) IARC group 3 - Not classifiable (100-41-4) IARC group 2B - Possibly carcinogenic to humans Benzene (71-43-2) IARC group 1 - Carcinogenic to humans National Toxicology Program (NTP) Status 1 - Known Human Carcinogens OSHA Carcinogen Status In OSHA Specifically Regulated Carcinogen list Additional information Benzene is a known human carcinogen and is known to cause acute myeloid leukemia & (disease that affects the bone marrow and blood) in Page 1206 of 1287 Page 1206 of 1287 Page 1206 of 1287 Page 1206 of 1287 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 8/12 humans who have been repeatedly exposed to benzene. Naphthalene (91-20-3) IARC group 2B - Possibly carcinogenic to humans National Toxicology Program (NTP) Status 2 - Reasonably anticipated to be Human Carcinogen Cumene (98-82-8) IARC group 2B - Possibly carcinogenic to humans Reproductive toxicity : Suspected of damaging fertility or the unborn child. Specific target organ toxicity (single exposure) : Causes damage to organs (lung). May cause respiratory irritation. May cause drowsiness or dizziness. Specific target organ toxicity (repeated exposure) : Causes damage to organs (blood, hematopoietic system [blood forming], kidneys, peripheral nervous system, brain (neurological), nervous system, visual organ (color vision effects), hearing organ (loss of hearing)) through prolonged or repeated exposure. Aspiration hazard : May be fatal if swallowed and enters airways. Section 12: Ecological information 12.1. Toxicity Ecology - general : Toxic to aquatic life with long lasting effects. 12.2. Persistence and degradability Unleaded Gasoline (86290-81-5) Persistence and degradability Not established. 12.3. Bioaccumulative potential Unleaded Gasoline (86290-81-5) Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Other information : Avoid release to the environment. Section 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents and container in accordance with all local, regional, national and international regulations. Additional information : Handle empty containers with care because residual vapors are flammable. Ecology - waste materials : Avoid release to the environment. Hazardous waste due to toxicity. Section 14: Transport information US Transport (DOT) for Bulk Shipments (Non-Bulk Shipments May Differ) Transport document description : UN1203, Gasoline, 3, PGII UN or NA Number : UN1203 Proper Shipping Name : Gasoline Primary Hazard Class : 3 - Flammable liquid Packing Group : PGII Reportable Quantities (RQ)* *It is the shipper's responsibility to determine whether an RQ must be reported for each individual shipment. : Benzene 10 lbs (4.54 kg), Cumene 5000 lbs (2270 kg), 1000 lbs (454 kg), Hexane 5000 lbs (2270 kg), Toluene 1000 lbs (454 kg), Mixed Xylenes 100 lbs (45.4 kg), Naphthalene 100 lbs (45.4 kg), Cyclohexane 1000 lbs (454 kg) Hazard labels : Emergency Response Guide (ERG) Number : 128 In accordance with the definition in 49 CFR § 171.8, a hazardous substance does not include petroleum, including crude oil or any fraction thereof which is not other specifically listed or designated as such in Appendix A to 49 CFR § 172.101. Therefore, this product does not require a RQ designation. Transport by sea (IMDG) Transport document description : UN1203, GASOLINE, 3, PGII UN Number : UN1203 Page 1207 of 1287 Page 1207 of 1287 Page 1207 of 1287 Page 1207 of 1287 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 9/12 Proper Shipping Name : GASOLINE Primary Hazard Class : 3 - Flammable liquids Packing Group : PGII Hazard labels (IMDG) : Cargo name listed in 46 CFR 30.25, Table 30.25-1 : Gasolines: Automotive Air transport (IATA) Transport document description : UN1203, Gasoline, 3, PGII UN Number : UN1203 Proper Shipping Name : Gasoline Primary Hazard Class : 3 - Flammable Liquids Packing Group : PGII Hazard labels (IATA) : Section 15: Regulatory information 15.1. US Federal regulations EPA TSCA Status Under TSCA gasoline is a mixture. All components of this mixture are listed on TSCA. SARA Section 313 Supplier Notification This product contains the following toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR 372: CAS number Chemical name Concentration 108-88-3 Toluene 1 - 20% 1330-20-7 Xylenes p- isomers) 1 - 20% 95-63-6 1 - 10% 100-41-4 1 - 10% 110-54-3 n-Hexane 0 - 5% 110-82-7 Cyclohexane 0 - 2% 71-43-2 Benzene 0.1 - 2% 91-20-3 Naphthalene 0.1 - 1% 98-82-8 Cumene 0.1 - 1% This information must be included in all Safety Data Sheets that are copied and distributed for this product. For additional information, see 40 CFR §372.45 Notification About Toxic Chemicals. SARA Section 311/312 Hazard Classes Fire hazard Chronic health hazard Acute health hazard 15.2. International regulations CANADA Unleaded Gasoline (86290-81-5) WHMIS Classification Class B Division 2 - Flammable Liquid Page 1208 of 1287 Page 1208 of 1287 Page 1208 of 1287 Page 1208 of 1287 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 10/12 National inventories (86290-81-5) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on the Canadian DSL (Domestic Sustances List) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on the Philippines Inventory of Chemicals and Chemical Substances (PICCS) 15.3. US State regulations California Proposition 65 - This product contains a substance or substances known to the state of California to cause cancer and/or reproductive toxicity, not limited to any that may be listed below. Toluene (108-88-3) U.S. - California - Proposition 65 - Carcinogens List No U.S. - California - Proposition 65 - Developmental Toxicity Yes U.S. - California - Proposition 65 - Reproductive Toxicity - Female Yes U.S. - California - Proposition 65 - Reproductive Toxicity - Male No (100-41-4) U.S. - California - Proposition 65 - Carcinogens List Yes U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No Non-significant risk level (NSRL) 54 µg/day (inhalation) Benzene (71-43-2) U.S. - California - Proposition 65 - Carcinogens List Yes U.S. - California - Proposition 65 - Developmental Toxicity Yes U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male Yes Non-significant risk level (NSRL) 6.4 µg/day (oral) Naphthalene (91-20-3) U.S. - California - Proposition 65 - Carcinogens List Yes U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No Non-significant risk level (NSRL) 5.8 µg/day Cumene (98-82-8) U.S. - California - Proposition 65 - Carcinogens List Yes U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No Section 16: Other information Other information : None. NFPA (National Fire Protection Association) NFPA health hazard : 1 NFPA fire hazard : 3 NFPA reactivity : 0 Page 1209 of 1287 Page 1209 of 1287 Page 1209 of 1287 Page 1209 of 1287 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 11/12 HMIS III Rating Health : 1* Flammability : 3 Physical Hazard : 0 Personal Protection : See section 8 of SDS US OSHA LABEL as specified under 29 CFR §1910.1200 Unleaded Gasoline Total Petrochemicals & Refining USA, Inc. PO Box 674411 Houston, TX 77267-4411 USA Tel. [PHONE REDACTED] or 1-[PHONE REDACTED] Danger Extremely flammable liquid and vapor May be fatal if swallowed and enters airways Causes skin irritation Causes serious eye irritation May cause respiratory irritation May cause drowsiness or dizziness May cause genetic defects May cause cancer Suspected of damaging fertility or the unborn child Causes damage to organs (lung) Causes damage to organs (blood, hematopoietic system [blood forming], kidneys, peripheral nervous system, brain (neurological), nervous system, visual organ (color vision effects), hearing organ (loss of hearing)) through prolonged or repeated exposure Toxic to aquatic life with long lasting effects Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from sparks, open flames, heat, hot surfaces. - No smoking. Keep container closed. Ground/bond container and receiving equipment. Use explosion-proof electrical, lighting, ventilating equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe spray, mist, vapors. Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear flame retardant protective clothing, impermeable protective gloves, eye protection, face protection. If swallowed: Immediately call doctor, poison center. Do NOT induce vomiting. If on skin: Wash with plenty of water. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Specific treatment (see Section 4.1 of SDS or information on this label). If exposed or concerned: Get medical advice/attention. Get medical advice/attention if you feel unwell. Take off contaminated clothing and wash it before reuse. In case of fire: Use Water spray, foam, carbon dioxide (CO2), dry chemical to extinguish. Collect spillage. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. Unknown acute toxicity 19 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation (Vapours)) Supplemental Information Product can accumulate electrostatic charges that may cause fire by electrical discharges. Version : 2.2 Date of issue : July 24, 2015 Page 1210 of 1287 Page 1210 of 1287 Page 1210 of 1287 Page 1210 of 1287 ---PAGE BREAK--- Unleaded Gasoline Safety Data Sheet Date of issue: 07/24/2015 EN (English US) 12/12 MSDS ID: UL_GASOLINE SDS REFERENCE NUMBER: RF0029 SDS Template - TOTAL SDS US (GHS HazCom 2012) TPRI Version 4.01 The information contained in this Safety Data Sheet (SDS) is believed by Total Petrochemicals & Refining USA, Inc. (TPRI) to be accurate on the date issued. However, materials may present unknown hazards and should be used with caution. Final determination of suitability and use of any material is the sole responsibility of the user. Neither TPRI nor any of its subsidiaries or affiliated companies assumes any liability whatsoever for the accuracy or completeness of the information contained herein or reliance thereto. If the material is repackaged, the user is responsible and must ensure that proper health, safety and other necessary information is included with the material and/or on the container. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING THE MATERIALS OR THE INFORMATION CONTAINED IN THIS SDS. ALTERATION OF THIS DOCUMENT IS STRICTLY PROHIBITED. Page 1211 of 1287 Page 1211 of 1287 Page 1211 of 1287 Page 1211 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET Issuing Date 5/01/2015 The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved. 2. HAZARDS IDENTIFICATION Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin sensitization Category 1 GHS Label elements, including precautionary statements Emergency Overview 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Victor V Kills! Mouse Glue Trays M163 Other means of identification Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Trap and/or Bait Station Uses advised against No information available Details of the supplier of the safety data sheet Supplier Name Woodstream Corp. Supplier Address 69 North Locust St. Lititz PA 17543 US Supplier Phone Number Phone:(717) 626-2125 Fax:(717) 626-1912 Contact Phone(717) 626-2125 Supplier Email [EMAIL REDACTED] Emergency telephone number Page 1 / 10 Signal word Warning Page 1212 of 1287 Page 1212 of 1287 Page 1212 of 1287 Page 1212 of 1287 M180 Victor® Mouse Glue Traps Size 1 each Woodstream Corporation Regulatory Licenses None ---PAGE BREAK--- 1126905 - Victor V Kills! Mouse Glue Trays M163 Precautionary Statements - Prevention Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace Wear protective gloves Precautionary Statements - Response Specific treatment (see supplemental first aid instructions on this label) Skin IF ON SKIN: Wash with plenty of soap and water If skin irritation or rash occurs: Get medical advice/attention Wash contaminated clothing before reuse Precautionary Statements - Storage None Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity 70% of the mixture consists of ingredient(s) of unknown toxicity Other information Repeated or prolonged skin contact may cause allergic reactions with susceptible persons Interactions with Other Chemicals No information available. Hazard Statements May cause an allergic skin reaction 3. COMPOSITION/INFORMATION ON INGREDIENTS . Chemical Name CAS No. Weight-% Trade Secret Paraffin oils 8012-95-1 15 - 40 * Rubber 9006-04-6 10 - 30 * *The exact percentage (concentration) of composition has been withheld as a trade secret Appearance Clear to semi-clear Page 2 / 10 Physical State Solid Odor Mild Page 1213 of 1287 Page 1213 of 1287 Page 1213 of 1287 Page 1213 of 1287 M180 Victor® Mouse Glue Traps ---PAGE BREAK--- 1126905 - Victor V Kills! Mouse Glue Trays M163 4. FIRST AID MEASURES First aid measures General Advice Show this safety data sheet to the doctor in attendance. Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. If persist, call a physician. Skin Contact Wash with soap and water. May cause an allergic skin reaction. In the case of skin irritation or allergic reactions see a physician. Inhalation Remove to fresh air. Ingestion Rinse mouth immediately and drink plenty of water. Never give anything by mouth to an unconscious person. Most important and effects, both acute and delayed Most Important and Effects Itching. Rashes. Hives. Indication of any immediate medical attention and special treatment needed Notes to Physician May cause sensitization of susceptible persons. Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical Product is or contains a sensitizer. May cause sensitization by skin contact. Uniform Fire Code Sensitizer: Solid Hazardous Combustion Products Carbon oxides. Explosion Data Sensitivity to Mechanical Impact No. Sensitivity to Static Discharge No. Page 3 / 10 Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 1214 of 1287 Page 1214 of 1287 Page 1214 of 1287 Page 1214 of 1287 M180 Victor® Mouse Glue Traps ---PAGE BREAK--- 1126905 - Victor V Kills! Mouse Glue Trays M163 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Paraffin oils 8012-95-1 TWA: 5 mg/m3 inhalable fraction excluding metal working fluids, highly & severely refined TWA: 5 mg/m3 inhalable fraction excluding metal working fluids TWA: 5 mg/m3 (vacated) TWA: 5 mg/m3 Rubber 9006-04-6 TWA: 0.0001 mg/m3 inhalable allergenic proteins inhalable fraction S* - ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits NIOSH IDLH Immediately Dangerous to Life or Health Other Exposure Guidelines See section 15 for national exposure control parameters 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Other Information Refer to protective measures listed in Sections 7 and 8. Environmental Precautions Environmental Precautions Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage if safe to do so. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. 7. HANDLING AND STORAGE Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash before reuse. Conditions for safe storage, including any incompatibilities Storage Keep containers closed in a dry, cool and well-ventilated place. Store locked up. Keep out of the reach of children. Page 4 / 10 Incompatible Products None known based on information supplied. Page 1215 of 1287 Page 1215 of 1287 Page 1215 of 1287 Page 1215 of 1287 M180 Victor® Mouse Glue Traps ---PAGE BREAK--- 1126905 - Victor V Kills! Mouse Glue Trays M163 Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection No special protective equipment required. Skin and Body Protection Wear protective gloves and protective clothing. Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Take off contaminated clothing and wash before reuse. Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this product. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Physical State Solid Explosive properties No data available Oxidizing Properties No data available Other Information Softening Point No data available VOC Content No data available Particle Size No data available Particle Size Distribution Appearance Clear to semi-clear Odor Mild Color No information available Odor Threshold No information available Property Values Remarks/ Method pH No data available None known Melting / freezing point No data available None known Boiling point / boiling range No data available None known Flash Point No data available None known Evaporation Rate No data available None known Flammability (solid, gas) No data available None known Flammability Limit in Air Upper flammability limit No data available Lower flammability limit No data available Vapor pressure No data available None known Vapor density No data available None known Specific Gravity No data available None known Water Solubility Insoluble None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/waterNo data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity Page 5 / 10 No data available None known Page 1216 of 1287 Page 1216 of 1287 Page 1216 of 1287 Page 1216 of 1287 M180 Victor® Mouse Glue Traps > 400 degrees F 0.875 ---PAGE BREAK--- 1126905 - Victor V Kills! Mouse Glue Trays M163 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information . Inhalation Specific test data for the substance or mixture is not available. Eye Contact Specific test data for the substance or mixture is not available. Skin Contact Specific test data for the substance or mixture is not available. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. (based on components). Ingestion Specific test data for the substance or mixture is not available. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Paraffin oils 8012-95-1 - - = 2062 ppm ( Rat ) 4 h Information on toxicological effects Itching. Rashes. Hives. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization May cause sensitization of susceptible persons. May cause sensitization by skin contact. Mutagenic Effects No information available. 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to avoid None known based on information supplied. Incompatible materials None known based on information supplied. Hazardous Decomposition Products Carbon oxides. Page 6 / 10 No data available. Page 1217 of 1287 Page 1217 of 1287 Page 1217 of 1287 Page 1217 of 1287 M180 Victor® Mouse Glue Traps ---PAGE BREAK--- 1126905 - Victor V Kills! Mouse Glue Trays M163 Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA Paraffin oils 8012-95-1 A2 Group 3 X ACGIH (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen IARC (International Agency for Research on Cancer) Group 3 - Not Classifiable as to Carcinogenicity in Humans OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Chronic Toxicity Repeated contact may cause allergic reactions in very susceptible persons. Target Organ Effects Skin. Aspiration Hazard No information available. Numerical measures of toxicity Product Information The following values are calculated based on chapter 3.1 of the GHS document Not applicable 12. ECOLOGICAL INFORMATION Ecotoxicity The environmental impact of this product has not been fully investigated. Persistence and Degradability No information available. Bioaccumulation No information available Page 7 / 10 Other adverse effects No information available. Page 1218 of 1287 Page 1218 of 1287 Page 1218 of 1287 Page 1218 of 1287 M180 Victor® Mouse Glue Traps ---PAGE BREAK--- 1126905 - Victor V Kills! Mouse Glue Trays M163 14. TRANSPORT INFORMATION DOT NOT REGULATED NOT REGULATED Proper Shipping Name NON REGULATED Hazard Class N/A TDG Not regulated MEX Not regulated ICAO Not regulated IATA Not regulated Proper Shipping Name NON REGULATED Hazard Class N/A IMDG/IMO Not regulated Hazard Class N/A RID Not regulated ADR Not regulated ADN Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL All components are listed either on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List US Federal Regulations 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal methods This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements. Contaminated Packaging Dispose of contents/containers in accordance with local regulations. California Hazardous Waste Codes Page 8 / 10 232 Page 1219 of 1287 Page 1219 of 1287 Page 1219 of 1287 Page 1219 of 1287 M180 Victor® Mouse Glue Traps ---PAGE BREAK--- 1126905 - Victor V Kills! Mouse Glue Trays M163 SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations . Chemical Name New Jersey Massachusetts Rhode Island Illinois Paraffin oils 8012-95-1 X X X International Regulations Mexico National occupational exposure limits Component Carcinogen Status Exposure Limits Paraffin oils 8012-95-1 ( 15 - 40 ) Mexico: TWA 5 mg/m3 Mexico: STEL 10 mg/m3 Mexico - Occupational Exposure Limits - Carcinogens Canada WHMIS Hazard Class D2B - Toxic materials 16. OTHER INFORMATION Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-[PHONE REDACTED] Revision Date 13-Jan-2014 NFPA Health Hazards 2 Flammability 0 Instability 0 Physical and Chemical Hazards - HMIS Health Hazards 2 Flammability 0 Page 9 / 10 Physical Hazard 0 Personal Protection X Page 1220 of 1287 Page 1220 of 1287 Page 1220 of 1287 Page 1220 of 1287 M180 Victor® Mouse Glue Traps This chemical is a pesticide device subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets and for workplace labels of non-pesticide chemicals. ---PAGE BREAK--- 1126905 - Victor V Kills! Mouse Glue Trays M163 Revision Note No information available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of Safety Data Sheet Page 10 / 10 Page 1221 of 1287 Page 1221 of 1287 Page 1221 of 1287 Page 1221 of 1287 M180 Victor® Mouse Glue Traps ---PAGE BREAK--- Spartan Chemical Company, Inc. Material Safety Data Sheet SECTION I: PRODUCT INFORMATION Product Name or Number (as it appears on label): Product Division: WASP & HORNET KILLER (AEROSOL) Product Number: 6820 Janitorial Spartan Chemical Company , Inc. Product/Technical Information: 1-(800)-537-8990 1110 Spartan Drive Medical Emergency: 1-(866)-836-8855 (24 hours) Maumee OH 43537 Chemical Leak/Spill Emergency: CHEMTREC 1-(800) 424-9300 (24 hours) Shipping Description: Limited Quanity NFPA Ratings: HMIS Ratings: Health: 2 - Moderate Health: *2 - Moderate; Chronic Hazard Fire: 4 - Extreme Fire: 4 - Extreme Reactivity: 0 - Minimal Reactivity: 0 - Minimal Pers. Prot. Equip.: See Section VIII SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1% or greater, carcinogens at 0.1% or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. Table Z-1-A Chemical Name(s) %Wt CAS Registry No. TWA mg/m 3 STEL mg/m 3 CEILING mg/m 3 NTP, IARC or OSHA Carcinogen Petroleum distillate Isopropyl alcohol Carbon dioxide *Tetramethrin *Phenothrin 85-95 5-10 1-5 < 1.0 < 1.0 64742-47-8 67-63-0 124-38-9 7696-12-0 26002-80-2 1200 (Exxon) 980 9000 Not Established Not Established Not Established 1225 54000 (ACGIH) Not Established Not Established Not Established Not Established Not Established Not Established Not Established No No No No No Comment: *This substance is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (SARA) and of 40 CFR 372. SECTION III: PHYSICAL DATA Boiling Point: N/A Vapor Pressure: Not Established Vapor Density (AIR = Not Established Solubility in Water: Partial pH: NA Specific Gravity (H2O=1): 0.8136 Evaporation Rate (but.ace.=1): >1 Percent Solid by Weight: Trace Physical State: Pressurized liquid Appearance & Odor: Clear liquid, solvent odor SECTION IV: FIRE & EXPLOSIVE HAZARD DATA Flash Point: [Concentrate] 183°F Method Used: ASTM-D56 Flammable Limits: Not Established Flame Extension: > 18 Inches NFPA 30 B Storage Level 3 Aerosol Extinguishing Media: Water spray or fog, carbon dioxide, dry chemical Special Fire Fighting Procedures: Water fog may be used to cool closed containers to prevent pressure build-up and possible rupture, venting or bursting of containers. Solvent vapors may cause flashback. Use equipment or shielding required to protect personnel against bursting, rupturing or venting containers. Unusual Fire & Explosive Hazards: At elevated temperatures (130°F / 54°C) containers may vent, rupture or burst. Page 1222 of 1287 Page 1222 of 1287 Page 1222 of 1287 Page 1222 of 1287 ---PAGE BREAK--- SECTION V: HEALTH HAZARD DATA Threshold Limit Value: Not Established Primary Routes of Entry: Inhalation, Skin Contact, Eyes and Oral. Effects of Overexposure- Conditions to Avoid: Causes moderate eye irritation : may include pain, redness, swelling and tearing. May cause skin irritation: may include pain, redness and swelling. Harmful if absorbed through the skin. Harmful if swallowed: may include abdominal pain, nausea and diarrhea. Harmful if Inhaled. Inhalation of vapors may cause central nervous system effects including dizziness, weakness, fatigue, nausea, headache, loss of consciousness depending on vapor concentration and duration of exposure. May cause delayed lung damage. The intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Avoid contact with eyes, skin, or clothing. Do not swallow. Avoid breathing product mist. Wash thoroughly with soap and water after handling . Conditions Aggravated by Use: Use of this product may aggravate preexisting skin; eye and respiratory disorders including asthma and dermatitis. Emergency & First Aid Procedures: Eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses; If present after the first 5 minutes; then continue rinsing eye. Call a poison control center or doctor for treatment advice. Skin: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. Ingestion: Immediately call a poison control center or doctor. Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give any liquid to the person. Do not give anything by mouth to an unconscious person. Inhalation: Move person to fresh air. If person is not breathing; call 911 or an ambulance then give artificial respiration; preferably by mouth-to-mouth; if possible. Call a poison control center or doctor for further treatment advice. Note to Physician: Contains petroleum distillate- vomiting may cause aspiration pneumonia. SECTION VI: REACTIVITY DATA Stability: Stable Incompatible Materials: Oxidizers Hazardous Decomposition Products: Carbon dioxide, carbon monoxide and oxides of nitrogen Hazardous Polymerization: Will Not Occur SECTION VII: SPILL OR LEAK PROCEDURES Steps to be Taken in Case Material is Released or Spilled: Remove ignition sources. Avoid breathing vapors or contact with liquid. Soak up with absorbent material and transfer to containers for disposal. Keep spill out of storm sewers and waterways. Waste Disposal Method: Do not incinerate or puncture aerosol container. Dispose of in accordance with federal, state and local regulations. SECTION VIII: SPECIAL PROTECTION INFORMATION Respiratory Protection: Not normally required when good general ventilation is provided. However, if exposure limits (see Section II) are exceeded or respiratory irritation occurs, use of a NIOSH approved respirator suitable for the use-conditions and chemicals in Section II should be considered. Ventilation: Provide good general ventilation. Local exhaust ventilation may be necessary for some operations. Protective Gloves(Specify Type): Rubber or other impervious gloves. Eye Protection(Specify Type): Splash goggles or safety glasses. Other Protective Equipment: See 29 CFR 1910.132-138 for further reference. SECTION IX: SPECIAL PRECAUTIONS Precautions; Handling & Storing: Contents under pressure. Do not puncture or incinerate. Do not contaminate food, feed or seed by storage or disposal. Do not store or use near fires, sparks, or flame. Store in an area inaccessible (preferably locked) to children. Do not store where temperatures could exceed 120°F. Other Precautions: Do not use in commercial food/feed processing; preparation; food/feed storage or serving areas. In the home; food/feed processing surfaces and utensils should be covered during treatment or thoroughly washed before use. Exposed food/feed should be covered or removed. Remove pets; birds and cover fish aquariums before use. Keep out of reach of children. Page 1223 of 1287 Page 1223 of 1287 Page 1223 of 1287 Page 1223 of 1287 ---PAGE BREAK--- © SCC 06/01/2013 Name: Ronald T. Cook Title: Manager, Regulatory Affairs WASP & HORNET KILLER (AEROSOL) Effective Date: 06/01/2013 Supercedes: 06/01/2010 Ref: 29 CFR 1910.1200 (OSHA) Changes: Revise Shipping Description This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. Page 1224 of 1287 Page 1224 of 1287 Page 1224 of 1287 Page 1224 of 1287 ---PAGE BREAK--- Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 26.08.2014 / 0002 Replaces revision of / Version: 30.04.2014 / 0001 Valid from: 26.08.2014 PDF print date: 05.09.2014 WD-40® MULTI-USE PRODUCT - [Aerosol] Safety data sheet according to Regulation (EC) No 1907/2006, Annex II SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier WD-40® MULTI-USE PRODUCT - [Aerosol] 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses of the substance or mixture: Corrosion protection Lubricant Uses advised against: No information available at present. 1.3 Details of the supplier of the safety data sheet WD-40 Company Limited PO Box 440, Kiln Farm, Milton Keynes, MK11 3LF, UK Telephone: +44 1908 555400, Fax: +44 1908 266900 www.wd40.co.uk P.R. Rielly Limited KarKraft House, Kilbarrack Industrial Estate, Kilbarrack, Dublin 5, IE Phone: 01-832 0006, Fax: 01-832 0016 [EMAIL REDACTED] Danka Import Export , 548 St Joseph High Road, M-SVR 1018 St Venera Phone: +356 21233649, Fax: +356 21233501 [EMAIL REDACTED] Qualified person's e-mail address: [EMAIL REDACTED], [EMAIL REDACTED] Please DO NOT use for requesting Safety Data Sheets. 1.4 Emergency telephone Emergency information services / official advisory body: Telephone number of the company in case of emergencies: +49 700 / 24 112 112 (WDC) Emergency information services / official advisory body: Telephone number of the company in case of emergencies: +49 700 / 24 112 112 (WDC) Emergency information services / official advisory body: Medicines & Poisons Info Office - Mater Dei Hospital, Msida MSD 2090, Malta - Tel.: 2545 6504 Emergency Ambulance - Tel.: 112 Telephone number of the company in case of emergencies: +49 700 / 24 112 112 (WDC) SECTION 2: Hazards identification 2.1 Classification of the substance or mixture 2.1.1 Classification according to Regulation (EC) 1272/2008 (CLP) Hazard class Hazard category Hazard statement Page 1 of 13 Page 1225 of 1287 Page 1225 of 1287 Page 1225 of 1287 Page 1225 of 1287 ---PAGE BREAK--- Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 26.08.2014 / 0002 Replaces revision of / Version: 30.04.2014 / 0001 Valid from: 26.08.2014 PDF print date: 05.09.2014 WD-40® MULTI-USE PRODUCT - [Aerosol] STOT SE 3 H336-May cause drowsiness or dizziness. Aerosol 1 H222-Extremely flammable aerosol. Asp. Tox. 1 H304-May be fatal if swallowed and enters airways. Aerosol 1 H229-Pressurised container: May burst if heated. 2.1.2 Classification according to Directives 67/548/EEC and 1999/45/EC (including amendments) F+,Extremely flammable Xn, Harmful, R65 R66 R67 2.2 Label elements 2.2.1 Labeling according to Regulation (EC) 1272/2008 (CLP) Danger H336-May cause drowsiness or dizziness. H222-Extremely flammable aerosol. H229-Pressurised container: May burst if heated. P101-If medical advice is needed, have product container or label at hand. P102-Keep out of reach of children. P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P211-Do not spray on an open flame or other ignition source. P251-Do not pierce or burn, even after use. P261-Avoid breathing vapours or spray. P271- Use only outdoors or in a well-ventilated area. P301+P310+P331-IF SWALLOWED: Immediately call a POISON CENTER/doctor. Do NOT induce vomiting. P312-Call a POISON CENTER/doctor if you feel unwell. P405-Store locked up. P410+P412-Protect from sunlight. Do not expose to temperatures exceeding 50 P501-Dispose of contents/container safely. EUH066-Repeated exposure may cause skin dryness or cracking. Without adequate ventilation, formation of explosive mixtures may be possible. Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics 2.3 Other hazards The mixture does not contain any vPvB substance (vPvB = very persistent, very bioaccumulative) or is not included under XIII of the regulation (EC) 1907/2006. The mixture does not contain any PBT substance (PBT = persistent, bioaccumulative, toxic) or is not included under XIII of the regulation (EC) 1907/2006. Danger of bursting (explosion) when heated Hydrocarbons can be harmful to water. Without adequate ventilation, formation of explosive mixtures may be possible. Product can compose a film on the water surface, which can prevent oxygen exchange. SECTION 3: Composition/information on ingredients Aerosol 3.1 Substance n.a. 3.2 Mixture Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics Registration number (REACH) 01-[PHONE REDACTED]-33-XXXX Index EINECS, ELINCS, NLP 919-857-5 (REACH-IT List-No.) CAS CAS content % 60-80 Page 2 of 13 Page 1226 of 1287 Page 1226 of 1287 Page 1226 of 1287 Page 1226 of 1287 ---PAGE BREAK--- Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 26.08.2014 / 0002 Replaces revision of / Version: 30.04.2014 / 0001 Valid from: 26.08.2014 PDF print date: 05.09.2014 WD-40® MULTI-USE PRODUCT - [Aerosol] Classification according to Directive 67/548/EEC Flammable, R10 Harmful, Xn, R65 R66 R67 Classification according to Regulation (EC) 1272/2008 (CLP) Flam. Liq. 3, H226 Asp. Tox. 1, H304 STOT SE 3, H336 Carbon dioxide Substance for which an EU exposure limit value applies. Registration number (REACH) Index EINECS, ELINCS, NLP 204-696-9 CAS CAS 124-38-9 content % 1-5 Classification according to Directive 67/548/EEC Classification according to Regulation (EC) 1272/2008 (CLP) For the text of the R-phrases / H-phrases and classification codes (GHS/CLP), see Section 16. The substances named in this section are given with their actual, appropriate classification! For substances that are listed in appendix VI, table 3.1/3.2 of the regulation (EC) no. 1272/2008 (CLP regulation) this means that all notes that may be given here for the named classification have been taken into account. SECTION 4: First aid measures 4.1 Description of first aid measures Inhalation Supply person with fresh air. Remove person from danger area. Respiratory arrest - Artificial respiration apparatus necessary. Skin contact Remove polluted, soaked clothing immediately, wash thoroughly with plenty of water and soap, in case of irritation of the skin (flare), consult a doctor. Eye contact Remove contact lenses. Wash thoroughly for several minutes using copious water. Seek medical help if necessary. Ingestion Rinse the mouth thoroughly with water. Consult doctor immediately - keep Data Sheet available. Do not induce vomiting. Danger of aspiration 4.2 Most important and effects, both acute and delayed If applicable delayed and effects can be found in section 11 and the absorption route in section 4.1. The following may occur: Irritation of the eyes Inhalation: Headaches Nausea Dizziness Irritation of the respiratory tract Effects/damages the central nervous system With long-term contact: Dermatitis (skin inflammation) Ingestion: Nausea Vomiting Diarrhoea Danger of aspiration In certain cases, the of poisoning may only appear after an extended period / after several hours. 4.3 Indication of any immediate medical attention and special treatment needed n.c. SECTION 5: Firefighting measures Page 3 of 13 Page 1227 of 1287 Page 1227 of 1287 Page 1227 of 1287 Page 1227 of 1287 ---PAGE BREAK--- Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 26.08.2014 / 0002 Replaces revision of / Version: 30.04.2014 / 0001 Valid from: 26.08.2014 PDF print date: 05.09.2014 WD-40® MULTI-USE PRODUCT - [Aerosol] 5.1 Extinguishing media Suitable extinguishing media Foam CO2 Extinction powder Unsuitable extinguishing media Water 5.2 Special hazards arising from the substance or mixture In case of fire the following can develop: Oxides of carbon Danger of bursting (explosion) when heated Danger of explosion by prolonged heating. Explosive vapour/air mixture 5.3 Advice for firefighters According to size of fire Protective respirator with independent air supply. Cool container at risk with water. Dispose of contaminated extinction water according to official regulations. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Remove possible causes of ignition - do not smoke. Ensure sufficient supply of air. Avoid inhalation, and contact with eyes or skin. Do not carry cleaning cloths soaked in product in trouser pockets. 6.2 Environmental precautions If leakage occurs, dam up. Resolve leaks if this possible without risk. Prevent from entering drainage system. Prevent surface and ground-water infiltration, as well as ground penetration. 6.3 Methods and material for containment and cleaning up If spray or gas escapes, ensure ample fresh air is available. Active substance: Soak up with absorbent material (e.g. universal binding agent, sand, diatomaceous earth) and dispose of according to Section 13. 6.4 Reference to other sections For personal protective equipment see Section 8 and for disposal instructions see Section 13. SECTION 7: Handling and storage In addition to information given in this section, relevant information can also be found in section 8 and 6.1. 7.1 Precautions for safe handling 7.1.1 General recommendations Ensure good ventilation. Keep away from sources of ignition - Do not smoke. Do not use on hot surfaces. Observe directions on label and instructions for use. Use working methods according to operating instructions. Take measures against electrostatic charging, if appropriate. 7.1.2 Notes on general hygiene measures at the workplace General hygiene measures for the handling of chemicals are applicable. Wash hands before breaks and at end of work. Keep away from food, drink and animal feedingstuffs. Remove contaminated clothing and protective equipment before entering areas in which food is consumed. 7.2 Conditions for safe storage, including any incompatibilities Keep out of access to unauthorised individuals. Not to be stored in gangways or stair wells. Observe special regulations for aerosols! Observe special storage conditions (in Germany, e.g., in accordance with the regulations in the "Betriebssicherheitsverordnung"). Keep protected from direct sunlight and temperatures over 50°C. Store in a dry place. Store cool Store in a well ventilated place. Page 4 of 13 Page 1228 of 1287 Page 1228 of 1287 Page 1228 of 1287 Page 1228 of 1287 ---PAGE BREAK--- Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 26.08.2014 / 0002 Replaces revision of / Version: 30.04.2014 / 0001 Valid from: 26.08.2014 PDF print date: 05.09.2014 WD-40® MULTI-USE PRODUCT - [Aerosol] 7.3 Specific end use(s) No information available at present. SECTION 8: Exposure controls/personal protection 8.1 Control parameters Workplace exposure limit (WEL) of the total hydrocarbon solvent content of the mixture (RCP method according to EH40): 800 mg/m3 Chemical Name Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics Content %:60- 80 WEL-TWA: 800 mg/m3 WEL-STEL: BMGV: Other information: (WEL acc. to RCP- method, EH40) Chemical Name Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics Content %:60- 80 OELV-8h: 100 ppm (573 mg/m3) (White Spirit ) OELV-15min: 125 ppm (720 mg/m3) (White Spirit ) BLV: Other information: Chemical Name Carbon dioxide Content %:1-5 WEL-TWA: 5000 ppm (9150 mg/m3) (WEL), 5000 ppm (9000 mg/m3) (EU) WEL-STEL: 15000 ppm (27400 mg/m3) (WEL) BMGV: Other information: Chemical Name Carbon dioxide Content %:1-5 OELV-8h: 5000 ppm (9000 mg/m3) (OELV-8h, EC) OELV-15min: 15000ppm (27000 mg/m3) (OELV- 15min) BLV: Other information: IOELV Chemical Name Carbon dioxide Content %:1-5 OELV-8h: 5000 ppm (9000 mg/m3) (OELV-8h, UE) OELV-ST: BMGV: Other information: Chemical Name Oil mist, mineral Content WEL-TWA: 5 mg/m3 (ACGIH) WEL-STEL: 10 mg/m3 (ACGIH) BMGV: Other information: Chemical Name Oil mist, mineral Content OELV-8h: 0,2 mg/m3 (Mineral oil, used in metal working (inhalable)), 5 mg/m3 (Mineral oil, pure, highly & severely refined (inhalable)) OELV-15min: BLV: Other information: WEL-TWA = Workplace Exposure Limit - Long-term exposure limit (8-hour TWA time weighted average) reference period) EH40. AGW = "Arbeitsplatzgrenzwert" (workplace limit value, Germany). I WEL-STEL = Workplace Exposure Limit - Short-term exposure limit (15-minute reference period). I BMGV = Biological monitoring guidance value EH40. BGW = "Biologischer Grenzwert" (biological limit value, Germany) I Other information: Sen = Capable of causing occupational asthma. Sk = Can be absorbed through skin. Carc = Capable of causing cancer and/or heritable genetic damage. = The exposure limit for this substance is repealed through the TRGS 900 (Germany) of January 2006 with the goal of revision. OELV-8h = Occupational Exposure Limit Value (8-hour reference period). (IFV) = Inhalable Fraction and Vapour. = Inhalable Fraction. = Respirable Fraction. I OELV-15min = Occupational Exposure Limit Value (15-minute reference period). (IFV) = Inhalable Fraction and Vapour. = Inhalable Fraction. = Respirable Fraction. I BLV = Biological limit value I Other information: Carc1A, Carc1B = carcinogenic substance, Cat. 1A or 1B. Muta1A, Muta1B = mutagenic substance, Cat. 1A or 1B. Repr1A, Repr1B = Substances known to be toxic for reproduction, Cat. 1A or 1B. Sk = can be absorbed through skin. Asphx = Sen = Respiratory sensitizer. BOELV = Binding Occupational Exposure Limit Values. IOELV = Indicative Occupational Exposure Limit Values. OELV-8h = Occupational Exposure Limit Value - 8 h (8-hour reference period as a time-weighted average) I OELV-ST = Occupational Exposure Limit Value - Short-term (15-minute reference period) I BMGV = Biological monitoring guidance value EH40. BGW = "Biologischer Grenzwert" (biological limit value, Germany) I Other information: Skin = Possibility of a significant uptake through the skin. Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics Page 5 of 13 Page 1229 of 1287 Page 1229 of 1287 Page 1229 of 1287 Page 1229 of 1287 ---PAGE BREAK--- Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 26.08.2014 / 0002 Replaces revision of / Version: 30.04.2014 / 0001 Valid from: 26.08.2014 PDF print date: 05.09.2014 WD-40® MULTI-USE PRODUCT - [Aerosol] Area of application Exposure route / Environmental compartment Effect on health Descripto r Value Unit Note Workers / employees Human - dermal Long term, systemic effects DNEL 300 mg/kg bw/day Workers / employees Human - inhalation Long term, systemic effects DNEL 1500 mg/m3 Consumer Human - oral Long term, systemic effects DNEL 300 mg/kg bw/day Consumer Human - dermal Long term, systemic effects DNEL 300 mg/kg bw/day Consumer Human - inhalation Long term, systemic effects DNEL 900 mg/m3 8.2 Exposure controls 8.2.1 Appropriate engineering controls Ensure good ventilation. This can be achieved by local suction or general air extraction. If this is insufficient to maintain the concentration under the WEL or AGW values, suitable breathing protection should be worn. Applies only if maximum permissible exposure values are listed here. 8.2.2 Individual protection measures, such as personal protective equipment General hygiene measures for the handling of chemicals are applicable. Wash hands before breaks and at end of work. Keep away from food, drink and animal feedingstuffs. Remove contaminated clothing and protective equipment before entering areas in which food is consumed. Eye/face protection: Tight fitting protective goggles with side protection (EN 166). Skin protection - Hand protection: Protective nitrile gloves (EN 374) Minimum layer thickness in mm: 0,4 Permeation time (penetration time) in minutes: 480 The breakthrough times determined in accordance with EN 374 Part 3 were not obtained under practical conditions. The recommended maximum wearing time is 50% of breakthrough time. Protective hand cream recommended. Skin protection - Other: Protective working garments (e.g. safety shoes EN ISO 20345, long-sleeved protective working garments) Respiratory protection: Normally not necessary. If OES or MEL is exceeded. Filter A P 3 (EN 14387), code colour brown, white Observe wearing time limitations for respiratory protection equipment. Thermal hazards: Not applicable Additional information on hand protection - No tests have been performed. In the case of mixtures, the selection has been made according to the knowledge available and the information about the contents. Selection of materials derived from glove manufacturer's indications. Final selection of glove material must be made taking the breakthrough times, permeation rates and degradation into account. Selection of a suitable glove depends not only on the material but also on other quality characteristics and varies from manufacturer to manufacturer. In the case of mixtures, the resistance of glove materials cannot be predicted and must therefore be tested before use. The exact breakthrough time of the glove material can be requested from the protective glove manufacturer and must be observed. 8.2.3 Environmental exposure controls No information available at present. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Page 6 of 13 Page 1230 of 1287 Page 1230 of 1287 Page 1230 of 1287 Page 1230 of 1287 ---PAGE BREAK--- Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 26.08.2014 / 0002 Replaces revision of / Version: 30.04.2014 / 0001 Valid from: 26.08.2014 PDF print date: 05.09.2014 WD-40® MULTI-USE PRODUCT - [Aerosol] Physical state: Aerosol, Substance: Liquid Colour: Light brown Odour: Characteristic Odour threshold: Not determined pH-value: n.a. Melting point/freezing point: <-66 °C (ASTM D 97, Liquid concentrate ) Initial boiling point and boiling range: 176 °C (Liquid concentrate ) Flash point: 47 °C (Liquid concentrate ) Flash point: Enclosed space ignition test (UN RTDG, Manual of Tests and Criteria, Part III, 31.5): 300 g/m3 (deflagration density) Flash point: Enclosed space ignition test (UN RTDG, Manual of Tests and Criteria, Part III, 31.5): 300 s/m3 (time equivalent) Flash point: Ignition distance test (UN RTDG, Manual of Tests and Criteria, Part III, 31.4): 75 cm Evaporation rate: Not determined Flammability (solid, gas): Yes Lower explosive limit: 0,6 Vol-% ((Particulars of main substances contained) ) Upper explosive limit: 8,0 Vol-% ((Particulars of main substances contained) ) Vapour pressure: 7,2 bar (20°C) Vapour pressure: 9,4 bar (50°C) Vapour density (air = Not determined Density: 0,817 g/ml (Liquid concentrate ) Bulk density: n.a. Solubility(ies): Not determined Water solubility: Insoluble Partition coefficient (n-octanol/water): Not determined Auto-ignition temperature: Not determined Decomposition temperature: Not determined Viscosity: <1 cSt Explosive properties: Not determined Oxidising properties: No 9.2 Other information Miscibility: Not determined Fat solubility / solvent: Not determined Conductivity: Not determined Surface tension: Not determined Solvents content: Not determined SECTION 10: Stability and reactivity 10.1 Reactivity The product has not been tested. 10.2 Chemical stability Stable with proper storage and handling. 10.3 Possibility of hazardous reactions No dangerous reactions are known. 10.4 Conditions to avoid See also section 7. Heating, open flame, ignition sources Pressure increase will result in danger of bursting. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. 10.5 Incompatible materials See also section 7. Avoid contact with strong oxidizing agents. 10.6 Hazardous decomposition products See also Subsection 10.1 to 10.5. See also section 5.2 No decomposition when used as directed. SECTION 11: Toxicological information Possibly more information on health effects, see Section 2.1 (classification). WD-40® MULTI-USE PRODUCT - [Aerosol] Page 7 of 13 Page 1231 of 1287 Page 1231 of 1287 Page 1231 of 1287 Page 1231 of 1287 ---PAGE BREAK--- Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 26.08.2014 / 0002 Replaces revision of / Version: 30.04.2014 / 0001 Valid from: 26.08.2014 PDF print date: 05.09.2014 WD-40® MULTI-USE PRODUCT - [Aerosol] Toxicity/effect Endpoi nt Value Unit Organism Test method Notes Acute toxicity, by oral route: n.d.a. Acute toxicity, by dermal route: n.d.a. Acute toxicity, by inhalation: n.d.a. Skin corrosion/irritation: n.d.a. Serious eye damage/irritation: n.d.a. Respiratory or skin sensitisation: n.d.a. Germ cell mutagenicity: n.d.a. Carcinogenicity: n.d.a. Reproductive toxicity: n.d.a. Specific target organ toxicity - single exposure (STOT-SE): n.d.a. Specific target organ toxicity - repeated exposure (STOT- RE): n.d.a. Aspiration hazard: n.d.a. Respiratory tract irritation: n.d.a. Repeated dose toxicity: n.d.a. n.d.a. Other information: Classification according to calculation procedure. Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics Toxicity/effect Endpoi nt Value Unit Organism Test method Notes Acute toxicity, by oral route: LD50 >5000 mg/kg Rat OECD 401 (Acute Oral Toxicity) Acute toxicity, by dermal route: LD50 >5000 mg/kg Rabbit OECD 402 (Acute Dermal Toxicity) Acute toxicity, by inhalation: LC50 >5000 mg/m3/ 8h Rat OECD 403 (Acute Inhalation Toxicity) Skin corrosion/irritation: Rabbit OECD 404 (Acute Dermal Irritation/Corrosion) Not irritant Repeated exposure may cause skin dryness or cracking. Serious eye damage/irritation: Rabbit OECD 405 (Acute Eye Irritation/Corrosion) Not irritant Respiratory or skin sensitisation: Guinea pig OECD 406 (Skin Sensitisation) No (skin contact) Germ cell mutagenicity: OECD 471 (Bacterial Reverse Mutation Test) Negative, Analogous conclusion Carcinogenicity: OECD 453 (Combined Chronic Toxicity/Carcinogenic ity Studies) Negative, Analogous conclusion Reproductive toxicity: OECD 414 (Prenatal Developmental Toxicity Study) Negative, Analogous conclusion Specific target organ toxicity - single exposure (STOT-SE): May cause drowsiness or dizziness. Aspiration hazard: Yes Repeated dose toxicity: OECD 408 (Repeated Dose 90- Day Oral Toxicity Study in Rodents) Not to be expected unconsciousness, headaches, dizziness, reddening of the skin Carbon dioxide Page 8 of 13 Page 1232 of 1287 Page 1232 of 1287 Page 1232 of 1287 Page 1232 of 1287 ---PAGE BREAK--- Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 26.08.2014 / 0002 Replaces revision of / Version: 30.04.2014 / 0001 Valid from: 26.08.2014 PDF print date: 05.09.2014 WD-40® MULTI-USE PRODUCT - [Aerosol] Toxicity/effect Endpoi nt Value Unit Organism Test method Notes unconsciousness, blisters by skin-contact, vomiting, frostbite, annoyance, palpitations, itching, headaches, cramps, ear noises, dizziness SECTION 12: Ecological information Possibly more information on environmental effects, see Section 2.1 (classification). WD-40® MULTI-USE PRODUCT - [Aerosol] Toxicity/effect Endpoint Time Value Unit Organism Test method Notes Toxicity to fish: n.d.a. Toxicity to daphnia: n.d.a. Toxicity to algae: n.d.a. Persistence and degradability: 28d >20- <60 % OECD 310 (Ready Biodegradability - CO2 in sealed vessels (Headspace Test)) Not readily but inherent biodegradable. Bioaccumulative potential: n.d.a. Mobility in soil: n.d.a. Results of PBT and vPvB assessment n.d.a. Other adverse effects: n.d.a. Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics Toxicity/effect Endpoint Time Value Unit Organism Test method Notes Toxicity to fish: LC50 96h >1000 mg/l mykiss OECD 203 (Fish, Acute Toxicity Test) Toxicity to fish: NOELR 28d 0,13 mg/l mykiss QSAR Toxicity to daphnia: EC50 48h >1000 mg/l Daphnia magna OECD 202 (Daphnia sp. Acute Immobilisation Test) Toxicity to daphnia: NOELR 21d 0,23 mg/l Daphnia magna QSAR Toxicity to algae: ErC50 72h >1000 mg/l Pseudokirchnerie lla subcapitata OECD 201 (Alga, Growth Inhibition Test) Toxicity to algae: EbC50 72h >1000 mg/l Pseudokirchnerie lla subcapitata OECD 201 (Alga, Growth Inhibition Test) Toxicity to algae: NOELR 72h 100 mg/l Raphidocelis subcapitata OECD 201 (Alga, Growth Inhibition Test) Toxicity to algae: NOELR 72h 100 mg/l Raphidocelis subcapitata OECD 201 (Alga, Growth Inhibition Test) groth rate Toxicity to algae: NOELR 72h 3 mg/l Pseudokirchnerie lla subcapitata OECD 201 (Alga, Growth Inhibition Test) Persistence and degradability: 28d 80 % OECD 301 F (Ready Biodegradability - Manometric Respirometry Test) Readily biodegradable Page 9 of 13 Page 1233 of 1287 Page 1233 of 1287 Page 1233 of 1287 Page 1233 of 1287 ---PAGE BREAK--- Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 26.08.2014 / 0002 Replaces revision of / Version: 30.04.2014 / 0001 Valid from: 26.08.2014 PDF print date: 05.09.2014 WD-40® MULTI-USE PRODUCT - [Aerosol] Results of PBT and vPvB assessment No PBT substance, No vPvB substance Carbon dioxide Toxicity/effect Endpoint Time Value Unit Organism Test method Notes Other adverse effects: Greenhouse effect SECTION 13: Disposal considerations 13.1 Waste treatment methods For the substance / mixture / residual amounts EC disposal code no.: The waste codes are recommendations based on the scheduled use of this product. Owing to the user's specific conditions for use and disposal, other waste codes may be allocated under certain circumstances. (2001/118/EC, 2001/119/EC, 2001/573/EC) 16 05 04 gases in pressure containers (including halons) containing dangerous substances Recommendation: Pay attention to local and national official regulations E.g. suitable incineration plant. For contaminated packing material Pay attention to local and national official regulations 15 01 04 metallic packaging 15 01 01 paper and cardboard packaging Dispose using dual system. SECTION 14: Transport information General statements UN number: 1950 Transport by road/by rail (ADR/RID) UN proper shipping name: UN 1950 AEROSOLS Transport hazard class(es): 2.1 Packing group: - Classification code: 5F LQ (ADR 2013): 1 L LQ (ADR 2009): 2 Environmental hazards: Not applicable Tunnel restriction code: D Transport by sea (IMDG-code) UN proper shipping name: AEROSOLS Transport hazard class(es): 2.1 Packing group: - EmS: F-D, S-U Marine Pollutant: n.a Environmental hazards: Not applicable Transport by air (IATA) UN proper shipping name: Aerosols, flammable Transport hazard class(es): 2.1 Packing group: - Environmental hazards: Not applicable Special precautions for user Persons employed in transporting dangerous goods must be trained. All persons involved in transporting must observe safety regulations. Precautions must be taken to prevent damage. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Freighted as packaged goods rather than in bulk, therefore not applicable. Minimum amount regulations have not been taken into account. Danger code and packing code on request. Comply with special provisions. SECTION 15: Regulatory information Page 10 of 13 Page 1234 of 1287 Page 1234 of 1287 Page 1234 of 1287 Page 1234 of 1287 ---PAGE BREAK--- Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 26.08.2014 / 0002 Replaces revision of / Version: 30.04.2014 / 0001 Valid from: 26.08.2014 PDF print date: 05.09.2014 WD-40® MULTI-USE PRODUCT - [Aerosol] 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture For classification and labelling see Section 2. Observe restrictions: Yes Comply with trade association/occupational health regulations. Observe youth employment law (German regulation). Directive 2010/75/EU (VOC): ~ 65,5 % 15.2 Chemical safety assessment A chemical safety assessment is not provided for mixtures. SECTION 16: Other information These details refer to the product as it is delivered. EUF0002 Revised sections: n.a. Classification and processes used to derive the classification of the mixture in accordance with the ordinance (EG) 1272/2008 (CLP): Classification in accordance with regulation (EC) No. 1272/2008 (CLP) Evaluation method used STOT SE 3, H336 Classification according to calculation procedure. Aerosol 1, H222 Classification based on test data. Asp. Tox. 1, H304 Classification according to calculation procedure. Aerosol 1, H229 Classification based on test data. The following phrases represent the posted R phrases / H phrases, Hazard Class and Risk Category Code (GHS/CLP) of the product and the constituents (specified in Section 2 and 10 Flammable. 65 Harmful: may cause lung damage if swallowed. 66 Repeated exposure may cause skin dryness or cracking. 67 Vapours may cause drowsiness and dizziness. H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H336 May cause drowsiness or dizziness. STOT SE — Specific target organ toxicity - single exposure - narcotic effects Aerosol — Aerosols Asp. Tox. — Aspiration hazard Flam. Liq. — Flammable liquid Any abbreviations and acronyms used in this document: AC Article Categories acc., acc. to according, according to ACGIHAmerican Conference of Governmental Industrial Hygienists ADR Accord européen relatif au transport international des marchandises Dangereuses par Route European Agreement concerning the International Carriage of Dangerous Goods by Road) AOEL Acceptable Operator Exposure Level AOX Adsorbable organic halogen compounds approx. approximately Art., Art. no. Article number ATE Acute Toxicity Estimate according to Regulation (EC) 1272/2008 (CLP) BAM Bundesanstalt für Materialforschung und -prüfung (Federal Institute for Materials Research and Testing, Germany) BAuA Bundesanstalt für und Arbeitsmedizin Federal Institute for Occupational Health and Safety, Germany) BCF Bioconcentration factor BGV Berufsgenossenschaftliche Accident Prevention Regulation) BHT 2,6-Di-t-butyl-4-methyl-phenol) BMGV Biological monitoring guidance value (EH40, UK) BOD Biochemical oxygen demand BSEF Bromine Science and Environmental Forum Page 11 of 13 Page 1235 of 1287 Page 1235 of 1287 Page 1235 of 1287 Page 1235 of 1287 ---PAGE BREAK--- Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 26.08.2014 / 0002 Replaces revision of / Version: 30.04.2014 / 0001 Valid from: 26.08.2014 PDF print date: 05.09.2014 WD-40® MULTI-USE PRODUCT - [Aerosol] bw body weight CAS Chemical Abstracts Service CEC Coordinating European Council for the Development of Performance Tests for Fuels, Lubricants and Other Fluids CESIO Comité Européen des Agents de Surface et de leurs Intermédiaires Organiques CIPAC Collaborative International Pesticides Analytical Council CLP Classification, Labelling and Packaging (REGULATION (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures) CMR carcinogenic, mutagenic, reproductive toxic COD Chemical oxygen demand CTFA Cosmetic, Toiletry, and Fragrance Association DMEL Derived Minimum Effect Level DNEL Derived No Effect Level DOC Dissolved organic carbon DT50 Dwell Time - 50% reduction of start concentration DVS Deutscher Verband für Schweißen und verwandte Verfahren e.V. German Association for Welding and Allied Processes) dw dry weight e.g. for example (abbreviation of Latin 'exempli gratia'), for instance EC European Community ECHA European Chemicals Agency EEA European Economic Area EEC European Economic Community EINECS European Inventory of Existing Commercial Chemical Substances ELINCS European List of Notified Chemical Substances EN European Norms EPA United States Environmental Protection Agency (United States of America) ERC Environmental Release Categories ES Exposure scenario etc. et cetera EU European Union EWC European Waste Catalogue Fax. Fax number gen. general GHS Globally Harmonized System of Classification and Labelling of Chemicals GWP Global warming potential HET-CAM Hen's Egg Test - Chorionallantoic Membrane Global Warming Potential IARC International Agency for Research on Cancer IATA International Air Transport Association IBC Intermediate Bulk Container IBC (Code) International Bulk Chemical (Code) IC Inhibitory concentration IMDG-code International Maritime Code for Dangerous Goods incl. including, inclusive IUCLID International Uniform ChemicaL Information Database LC lethal concentration LC50 lethal concentration 50 percent kill LCLo lowest published lethal concentration LD Lethal Dose of a chemical LD50 Lethal Dose, 50% kill LDLo Lethal Dose Low LOAELLowest Observed Adverse Effect Level LOEC Lowest Observed Effect Concentration LOEL Lowest Observed Effect Level LQ Limited Quantities MARPOL International Convention for the Prevention of Marine Pollution from Ships n.a. not applicable n.av. not available n.c. not checked n.d.a. no data available NIOSHNational Institute of Occupational Safety and Health (United States of America) NOAEC No Observed Adverse Effective Concentration NOAEL No Observed Adverse Effect Level NOEC No Observed Effect Concentration NOEL No Observed Effect Level ODP Ozone Depletion Potential OECD Organisation for Economic Co-operation and Development org. organic PAH aromatic hydrocarbon PBT persistent, bioaccumulative and toxic Page 12 of 13 Page 1236 of 1287 Page 1236 of 1287 Page 1236 of 1287 Page 1236 of 1287 ---PAGE BREAK--- Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 26.08.2014 / 0002 Replaces revision of / Version: 30.04.2014 / 0001 Valid from: 26.08.2014 PDF print date: 05.09.2014 WD-40® MULTI-USE PRODUCT - [Aerosol] PC Chemical product category PE Polyethylene PNEC Predicted No Effect Concentration POCP Photochemical ozone creation potential ppm parts per million PROC Process category PTFE Polytetrafluorethylene REACH Registration, Evaluation, Authorisation and Restriction of Chemicals (REGULATION (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals) REACH-IT List-No. 9xx-xxx-x No. is automatically assigned, e.g. to pre-registrations without a CAS No. or other numerical identifier. List Numbers do not have any legal significance, rather they are purely technical identifiers for processing a submission via REACH-IT. RID Règlement concernant le transport International ferroviaire de marchandises Dangereuses Regulation concerning the International Carriage of Dangerous Goods by Rail) SADT Self-Accelerating Decomposition Temperature SAR Structure Activity Relationship SU Sector of use SVHC Substances of Very High Concern Tel. Telephone ThOD Theoretical oxygen demand TOC Total organic carbon TRGS Technische Regeln für Gefahrstoffe (=Technical Regulations for Hazardous Substances) UN RTDG United Nations Recommendations on the Transport of Dangerous Goods VbF Verordnung über brennbare Flüssigkeiten Regulation for flammable liquids (Austria)) VOC Volatile organic compounds vPvB very persistent and very bioaccumulative WEL-TWA, WEL-STEL WEL-TWA = Workplace Exposure Limit - Long-term exposure limit (8-hour TWA time weighted average) reference period), WEL-STEL = Workplace Exposure Limit - Short-term exposure limit (15-minute reference period) (EH40, UK). WHO World Health Organization wwt wet weight The statements made here should describe the product with regard to the necessary safety precautions - they are not meant to guarantee definite characteristics - but they are based on our present up-to-date knowledge. No responsibility. These statements were made by: Chemical Check GmbH, Chemical Check Platz 1-7, D-32839 Steinheim, Tel.: +49 5233 94 17 0, Fax: +49 5233 94 17 90 © by Chemical Check GmbH Gefahrstoffberatung. The copying or changing of this document is forbidden except with consent of the Chemical Check GmbH Gefahrstoffberatung. Page 13 of 13 Page 1237 of 1287 Page 1237 of 1287 Page 1237 of 1287 Page 1237 of 1287 ---PAGE BREAK--- Page 1/3 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 01/04/2007 Reviewed on 01/04/2007 DR 1 Identification of substance Trade name: WHITE INVERTED TIP MARKER Product code: [PHONE REDACTED] Manufacturer/Supplier: SEYMOUR OF SYCAMORE 917 Crosby Avenue Sycamore, IL 60178 (815)-895-9101, www.seymourpaint.com Information department: Health & Safety Department Emergency information: CHEMTEL 1-[PHONE REDACTED], [PHONE REDACTED] if located outside the U.S. 2 Composition/Data on components Chemical Description: This product is a mixture of the substances listed below with nonhazardous additions. Dangerous components: 64742-89-8 VM&P Naptha 15.75% 1317-65-3 Calcium Carbonate 15.29% 106-97-8 n-butane 10.36% 13463-67-7 titanium dioxide 6.33% 64742-47-8 Mineral Spirits 5.46% Additional information: For the wording of the listed risk phrases refer to section 3. 3 Hazards identification Hazard description: Irritant Flammable Physical dangers: Flammable liquid and vapor in a pressurized container. Keep away from heat, sparks, and flame. Flammable. Irritating to eyes and respiratory system. Keep out of the reach of children. Effects of short-term overexposure: Vapors cause irritation to the eyes, nose, throat, skin, and central nervous system. may include dizziness, throat irritation, headache, fatigue,swelling of eyes, and nausea. Effects of chronic overexposure: May cause permanent brain and nervous system damage. Repeated overexposure can also damage kidneys, lungs, liver, heart, and blood. Intentional misuse by deliberately inhaling the contents may be harmful or fatal. NFPA ratings (scale 0 - Health- 1 Flammability- 3 Reactivity- 3 HMIS-ratings (scale 0 - Health- 1 Flammability- 3 Physical Hazard-3 4 First aid measures After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Remove contaminated clothing. Wash exposed area with soap and water. After eye contact: Move to fresh air. Rinse opened eye for several minutes under running water. If persist, consult a doctor. After swallowing: Contact physician or poison control center. 5 Fire fighting measures Extinguishing agents: CO2, sand, extinguishing powder, or water spray. Fight larger fires with water spray or alcohol resistant foam. Protective equipment: No special measures required. 6 Accidental release measures Personal safety precautions: Wear protective equipment. Keep unprotected persons away. Environmental safety precautions: Inform appropriate authorities in case of seepage into water course or sewage system. Do not allow product to reach sewage systems or ground water. (Contd. on page 2) USA City of Moreno Valley Product code 674198 Document 866378 Page 2340 Return to Index Page 1238 of 1287 Page 1238 of 1287 Page 1238 of 1287 Page 1238 of 1287 ---PAGE BREAK--- Page 2/3 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 01/04/2007 Reviewed on 01/04/2007 Trade name: WHITE INVERTED TIP MARKER (Contd. of page 1) DR Measures for cleaning/ collecting: Do not flush with water or aqueous cleansing agents. Use diluted caustic solution. Soak up spills with inert absorbent material. Refer to section 13 for disposal information. 7 Handling and storage Fire/explosion protection: Do not spray on a naked flame or any incandescent material. Do not smoke. Protect from electrostatic charges. Storage requirements: Observe pressurized container storage regulations. Consult with your local authorities. Keep away from sources of heat and direct sunlight. Do not warehouse in subfreezing conditions. 8 Exposure controls and personal protection: Components with limit values that require monitoring at the workplace: 106-97-8 n-butane REL 1900 mg/m³, 800 ppm Protective hygienic measures: Keep away from foodstuffs and animal feed. Wash hands after use. Breathing equipment: Use suitable respiratory protective device in case of insufficient ventilation. A respirator is generally not necessary when using this product outdoors or in large open areas. In cases of inadequate ventilation, a respiratory protective device should be worn to prevent overexposure. Protection of hands: Protective gloves. The glove material has to be impermeable and resistant to the substance. No glove recommendation can be given. Eye protection: sealed goggles 9 Physical and chemical properties: General Information: Form: Aerosol Color: According to trade name description in section 1. Odor: Solvent Boiling point/Boiling range: -44°C (-47°F) Flash point: -19°C Ignition temperature: 210.0°C (410°F) Auto igniting: Product is not self-igniting. Danger of explosion: Stable at normal temperatures. Can may burst when exposed to temperatures exceeding 120 degrees fahrenheit. In use, may form flammable/explosive vapour-air mixture. Lower Explosion Limit: 0.9 Vol % Upper Explosion Limit: 10.9 Vol % Vapor Pressure: 40 PSI, 2750 hPa Density: Not determined. Specific Gravity: Between 0.77 and 0.85 (Water equals 1.00) VOC content: 619.9 g/l / 5.17 lb/gl VOC in weight percent (less acetone): 49.4 % Water: 20.3 % Solids content: 29.1 % 10 Stability and reactivity: Conditions to be avoided: Do not allow the can to exceed 120 degrees Fahrenheit. Stable at normal temperatures. Possibility of Hazardous Reactions: No dangerous reactions known. 11 Toxicological information: Primary effect on the skin: No irritant effect. Primary effect on the eye: Irritating effect. Sensitization: No sensitizing effects known. USA (Contd. on page 3) City of Moreno Valley Product code 674198 Document 866378 Page 2341 Return to Index Page 1239 of 1287 Page 1239 of 1287 Page 1239 of 1287 Page 1239 of 1287 ---PAGE BREAK--- Page 3/3 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 01/04/2007 Reviewed on 01/04/2007 Trade name: WHITE INVERTED TIP MARKER (Contd. of page 2) DR 12 Ecological information Other information: This product does not contain any chloroflourocarbons (CFC's),chlorinated solvents, lead, mercury, cadmium, hexavalent chromium, polybrominated biphenyl (PBB), or polybrominated diphenyl ether (PDBE). No specific ecological data is available for this product. Acquatic toxicity: Harmful to aquatic organisms. Hazardous for water, do not empty into drains. 13 Disposal considerations DISPOSAL METHOD: Dispose of in accordance with local, state, and federal regulations. Do not puncture, incinerate, or compact. Partially empty cans must be disposed of responsibly. Do not heat or cut empty containers with electric or gas torches. Recommendation: Empty cans should be recycled. 14 Transport information: Hazard class: 2.1 Identification number: N/A Label 2.1 ADR/RID class: 2 5F Gases UN-Number: 1950 IMDG Class: 2.1 Packaging group: II EMS Number: F-D,S-U Marine pollutant: No ICAO/IATA Class: 2.1 Propper shipping name: Aerosols, Flammable Consumer Commodity ORM-D 15 Regulations SARA Section 355 (extremely hazardous substances): None of the ingredients in this product are listed. SARA Section 313 (Specific toxic chemical listings): None of the ingredients is listed. TSCA (Toxic Substances Control Act): All ingredients are listed. PROPOSITION 65 Chemicals known to cause cancer: None of the ingredients in this product are listed. Canadian WHMIS: Class A, B5---Flammable Aerosols EPA: A= Known human carcinogen B= Probable human carcinogen C= Possible human carcinogen D= Not classifiable as to human carcinogenicity: Inadequate human and animal evidence of carcinogenicity (or no data is available). IARC: 13463-67-7 titanium dioxide 2B ACGIH TLVs: A1-designates a confirmed human carcinogen. A2-designates a suspected human carcinogen. A3-designates an animal carcinogen. A4-designates "not classifiable as a human carcinogen". 13463-67-7 titanium dioxide A4 NIOSH: 13463-67-7 titanium dioxide 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Contact: Regulatory Affairs USA City of Moreno Valley Product code 674198 Document 866378 Page 2342 Return to Index Page 1240 of 1287 Page 1240 of 1287 Page 1240 of 1287 Page 1240 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SR-AllPurpose/WL 2007 Section 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME & NUMBER HMIS CODES Health 2* WHITE LIGHTNING® Silicone Rubber Flammability 0 All Purpose Sealant (RTV Formula) Reactivity 0 WL09010 WL09023 Clear WL09210 WL09213 White WL09310 Aluminum WL09410 Black WL09510 Bronze MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. THE SHERWIN-WILLIAMS CO. (216) 566-2917 Consumer Group - Industrial Cleveland, OH 44115 DATE OF PREPARATION INFORMATION TELEPHONE NO. 23-MAY-07 (216) 566-2902 Section 2 COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE 3-7 64742-46-7 Middle Petroleum Distillates ACGIH TLV 5 mg/m3 as Mist OSHA PEL 5 mg/m3 as Mist 1-5 17689-77-9 Ethyl Triacetoxysilane ACGIH TLV Not Available OSHA PEL Not Available 1-5 4253-34-3 Methyl Triacetoxysilane ACGIH TLV Not Available OSHA PEL Not Available 7-13 7631-86-9 Amorphous Silica ACGIH TLV 10 mg/m3 as Dust OSHA PEL 6 mg/m3 as Dust 0-1 1333-86-4 Carbon Black ACGIH TLV 3.5 mg/m3 OSHA PEL 3.5 mg/m3 NOTE: These products may evolve trace quantities of Acetic Acid during curing. Exposure limits for Acetic Acid are: <1 64-19-7 Acetic Acid ACGIH TLV 10 ppm 11 mm ACGIH TLV 15 ppm STEL OSHA PEL 10 ppm Continued on page 2 Page 1241 of 1287 Page 1241 of 1287 Page 1241 of 1287 Page 1241 of 1287 ---PAGE BREAK--- SR-AllPurpose/WL page 2 Section 3 HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Section 4 FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. Section 5 FIRE FIGHTING MEASURES FLASH POINT LEL UEL Not Applicable N.A. N.A. FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Continued on page 3 Page 1242 of 1287 Page 1242 of 1287 Page 1242 of 1287 Page 1242 of 1287 ---PAGE BREAK--- SR-AllPurpose/WL page 3 Section 7 HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This product may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. Section 9 PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 8.4 lb/gal 1010 g/l SPECIFIC GRAVITY 1.01 BOILING POINT 244 °F 117 °C MELTING POINT Not Available VOLATILE VOLUME 2 % EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.25 lb/gal 30 g/l Less Water and Federally Exempt Solvents 0.25 lb/gal 30 g/l Emitted VOC Continued on page 4 Page 1243 of 1287 Page 1243 of 1287 Page 1243 of 1287 Page 1243 of 1287 ---PAGE BREAK--- SR-AllPurpose/WL page 4 Section 10 STABILITY AND REACTIVITY STABILITY Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Section 11 TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Carbon Black is classified by IARC as possibly carcinogenic to humans (group 2B) based on experimental animal data, however, there is insufficient evidence in humans for its carcinogenicity. TOXICOLOGY DATA CAS No. Ingredient Name 64742-46-7 Middle Petroleum Distillates LC50 RAT 4HR Not Available LD50 RAT Not Available 64-19-7 Acetic Acid LC50 RAT 4HR Not Available LD50 RAT 3310 mg/kg 17689-77-9 Ethyl Triacetoxysilane LC50 RAT 4HR Not Available LD50 RAT Not Available 4253-34-3 Methyl Triacetoxysilane LC50 RAT 4HR Not Available LD50 RAT Not Available 7631-86-9 Amorphous Silica LC50 RAT 4HR Not Available LD50 RAT Not Available 1333-86-4 Carbon Black LC50 RAT 4HR Not Available LD50 RAT Not Available Section 12 ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Section 13 DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Continued on page 5 Page 1244 of 1287 Page 1244 of 1287 Page 1244 of 1287 Page 1244 of 1287 ---PAGE BREAK--- SR-AllPurpose/WL page 5 Section 14 TRANSPORT INFORMATION US Ground (DOT) Not Regulated Canada (TDG) Not Regulated IMO Not Regulated Section 15 REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Section 16 OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 1245 of 1287 Page 1245 of 1287 Page 1245 of 1287 Page 1245 of 1287 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Product identifier White Lithium Grease Other means of identification Product code 03080 Recommended use Lubricating grease Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufactured or sold by: Company name CRC Industries, Inc. Address 885 Louis Dr. Warminster, PA 18974 US Telephone General Information [PHONE REDACTED] Technical Assistance [PHONE REDACTED] Customer Service [PHONE REDACTED] 24-Hour Emergency [PHONE REDACTED] (US) (CHEMTREC) [PHONE REDACTED] (International) Website www.crcindustries.com 2. Hazard(s) identification Category 1 Flammable aerosols Physical hazards Liquefied gas Gases under pressure Category 2 Skin corrosion/irritation Health hazards Category 2 Carcinogenicity Category 2 Reproductive toxicity (fertility) Category 3 narcotic effects Specific target organ toxicity, single exposure Category 2 Specific target organ toxicity, repeated exposure Category 1 Aspiration hazard Category 3 Hazardous to the aquatic environment, acute hazard Environmental hazards Category 3 Hazardous to the aquatic environment, long-term hazard Not classified. OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal if swallowed and enters airways. Causes skin irritation. May cause drowsiness or dizziness. Suspected of causing cancer. Suspected of damaging fertility. May cause damage to organs (nervous system, upper respiratory tract, skin, eyes) through prolonged or repeated exposure. Harmful to aquatic life. Harmful to aquatic life with long lasting effects. 1 / 10 Material name: White Lithium Grease 03080 Version 01 Issue date: 01-16-2015 SDS US Page 1246 of 1287 Page 1246 of 1287 Page 1246 of 1287 Page 1246 of 1287 ---PAGE BREAK--- Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not apply while equipment is energized. Pressurized container: Do not pierce or burn, even after use. Extinguish all flames, pilot lights and heaters. Vapors will accumulate readily and may ignite. Use only with adequate ventilation; maintain ventilation during use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any listed on this label, increase ventilation or leave the area. Do not breathe dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Avoid release to the environment. Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Wash with plenty of water. If skin irritation occurs: Get medical attention. Take off contaminated clothing and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If exposed or concerned: Get medical attention. Storage Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Exposure to high temperature may cause can to burst. Disposal Dispose of contents/container in accordance with local/regional/national regulations. Hazard(s) not otherwise classified (HNOC) None known. 3. Composition/information on ingredients Mixtures CAS number % Chemical name Common name and synonyms 68476-86-8 Liquefied Petroleum Gas 30 - 40 64742-49-0 Naphtha (petroleum), hydrotreated light 30 - 40 64742-52-5 Distillates (petroleum), hydrotreated heavy naphthenic 10 - 20 107-83-5 5 - 10 110-54-3 n-Hexane 1 - 3 13463-67-7 Titanium dioxide < 1 1314-13-2 Zinc oxide < 1 57855-77-3 Calcium bis(dinonylnaphthalenesulphonate) < 0.2 Specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Remove contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Eye contact Rinse with water. Get medical attention if irritation develops and persists. Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Most important acute and delayed May cause drowsiness and dizziness. Headache. Nausea, vomiting. Aspiration may cause pulmonary edema and pneumonitis. Skin irritation. May cause redness and pain. Prolonged exposure may cause chronic effects. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat Keep victim under observation. may be delayed. General information IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). 2 / 10 Material name: White Lithium Grease 03080 Version 01 Issue date: 01-16-2015 SDS US Page 1247 of 1287 Page 1247 of 1287 Page 1247 of 1287 Page 1247 of 1287 ---PAGE BREAK--- Unsuitable extinguishing media None known. Specific hazards arising from the chemical Contents under pressure. Pressurized container may rupture when exposed to heat or flame. During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Fire-fighting equipment/instructions In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Use water spray to cool unopened containers. General fire hazards Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture when exposed to heat or flame. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Do not breathe dust/fume/gas/mist/vapors/spray. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. The product is immiscible with water and will spread on the water surface. Stop the flow of material, if this is without risk. For waste disposal, see section 13 of the SDS. Prevent entry into waterways, sewer, basements or confined areas. Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. 7. Handling and storage Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. For product usage instructions, please see the product label. Conditions for safe storage, including any incompatibilities Level 3 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Form Type PEL 5 mg/m3 Mist. Distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5) 2000 mg/m3 500 ppm PEL 1800 mg/m3 n-Hexane (CAS 110-54-3) 500 ppm PEL 15 mg/m3 Total dust. Titanium dioxide (CAS 13463-67-7) 3 / 10 Material name: White Lithium Grease 03080 Version 01 Issue date: 01-16-2015 SDS US Page 1248 of 1287 Page 1248 of 1287 Page 1248 of 1287 Page 1248 of 1287 ---PAGE BREAK--- US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Form Type PEL 5 mg/m3 Respirable fraction. Zinc oxide (CAS 1314-13-2) 5 mg/m3 Fume. 15 mg/m3 Total dust. US. ACGIH Threshold Limit Values Value Components Form Type STEL 1000 ppm (CAS 107-83-5) TWA 500 ppm TWA 5 mg/m3 Inhalable fraction. Distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5) TWA 50 ppm n-Hexane (CAS 110-54-3) TWA 10 mg/m3 Titanium dioxide (CAS 13463-67-7) STEL 10 mg/m3 Respirable fraction. Zinc oxide (CAS 1314-13-2) TWA 2 mg/m3 Respirable fraction. US. NIOSH: Pocket Guide to Chemical Hazards Value Components Form Type Ceiling 1800 mg/m3 (CAS 107-83-5) 510 ppm TWA 350 mg/m3 100 ppm Ceiling 1800 mg/m3 Distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5) STEL 10 mg/m3 Mist. TWA 5 mg/m3 Mist. TWA 180 mg/m3 n-Hexane (CAS 110-54-3) 50 ppm Ceiling 15 mg/m3 Dust. Zinc oxide (CAS 1314-13-2) STEL 10 mg/m3 Fume. TWA 5 mg/m3 Fume. 5 mg/m3 Dust. Biological limit values ACGIH Biological Exposure Indices Value Components Determinant Specimen Sampling Time 0.4 mg/l 2,5-Hexanedio n, without hydrolysis Urine * n-Hexane (CAS 110-54-3) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation n-Hexane (CAS 110-54-3) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation n-Hexane (CAS 110-54-3) Can be absorbed through the skin. Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. 4 / 10 Material name: White Lithium Grease 03080 Version 01 Issue date: 01-16-2015 SDS US Page 1249 of 1287 Page 1249 of 1287 Page 1249 of 1287 Page 1249 of 1287 ---PAGE BREAK--- Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear protective gloves such as: Nitrile. Polyvinyl chloride (PVC). Viton®. Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended. Respiratory protection If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Solid. Form Aerosol. Grease. Color Off-white. Odor Solvent. Odor threshold Not available. pH Not available. Melting point/freezing point -244.7 °F (-153.7 estimated Initial boiling point and boiling range 118.4 °F (48 estimated Flash point < 0 °F -17.8 Tag Closed Cup Evaporation rate Fast. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower 1 % estimated Flammability limit - upper 8 % estimated Vapor pressure 2217.9 hPa estimated Vapor density > 1 (air = 1) Relative density 0.64 estimated Solubility (water) Insoluble. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 437 °F (225 estimated Decomposition temperature Not available. Viscosity (kinematic) Not available. Percent volatile 84.9 % estimated 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Conditions to avoid Heat, flames and sparks. Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Chlorine. Hazardous decomposition products Carbon oxides. 5 / 10 Material name: White Lithium Grease 03080 Version 01 Issue date: 01-16-2015 SDS US Page 1250 of 1287 Page 1250 of 1287 Page 1250 of 1287 Page 1250 of 1287 ---PAGE BREAK--- 11. Toxicological information Information on likely routes of exposure Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Inhalation May cause damage to organs through prolonged or repeated exposure by inhalation. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Skin contact Causes skin irritation. Eye contact Direct contact with eyes may cause temporary irritation. related to the physical, chemical and toxicological characteristics May cause drowsiness and dizziness. Headache. Nausea, vomiting. Aspiration may cause pulmonary edema and pneumonitis. Skin irritation. May cause redness and pain. Information on toxicological effects Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects. Test Results Product Species White Lithium Grease LD50 Rabbit Dermal Acute 3913.0442 mg/kg estimated LC50 Rat Inhalation 88578.8594 ppm, 4 hours estimated 82.9611 mg/l, 4 hours estimated LD50 Rat Oral 6327.0615 mg/kg estimated * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity Suspected of causing cancer. IARC Monographs. Overall Evaluation of Carcinogenicity Titanium dioxide (CAS 13463-67-7) 2B Possibly carcinogenic to humans. Reproductive toxicity Suspected of damaging fertility. Specific target organ toxicity - single exposure May cause drowsiness and dizziness. Specific target organ toxicity - repeated exposure May cause damage to organs through prolonged or repeated exposure. Aspiration hazard May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting, may cause chemical pneumonia, pulmonary injury or death. Chronic effects Prolonged exposure may cause chronic effects. May cause damage to organs through prolonged or repeated exposure. 12. Ecological information Ecotoxicity Harmful to aquatic life with long lasting effects. Product Test Results Species White Lithium Grease Aquatic Acute EC50 Crustacea 21.9728 mg/l, 48 hours estimated Daphnia LC50 Fish 246.6337 ppm, 96 hours estimated Fish 6 / 10 Material name: White Lithium Grease 03080 Version 01 Issue date: 01-16-2015 SDS US Page 1251 of 1287 Page 1251 of 1287 Page 1251 of 1287 Page 1251 of 1287 ---PAGE BREAK--- Components Test Results Species Distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5) Aquatic EC50 Crustacea 1000 mg/l, 48 hours Water flea (Daphnia magna) LC50 Fish 5000 mg/l, 96 hours Rainbow trout,donaldson trout mykiss) n-Hexane (CAS 110-54-3) Aquatic LC50 Fish 2.101 - 2.981 mg/l, 96 hours Fathead minnow (Pimephales promelas) Titanium dioxide (CAS 13463-67-7) Acute EC50 Other 5.83 mg/l, 72 hours Pseudokirchnerella subcapitata Chronic NOEC Other 0.984 mg/l, 72 hours Pseudokirchnerella subcapitata Aquatic Acute LC50 Crustacea 3 mg/l, 48 hours Ceriodaphnia dubia 5.5 ppm, 48 hours Water flea (Daphnia magna) LC50 Fish 1000 mg/l, 96 hours Fathead minnow (Pimephales promelas) Zinc oxide (CAS 1314-13-2) Aquatic Acute EC50 Crustacea 0.098 mg/l, 48 hours Water flea (Daphnia magna) * Estimates for product may be based on additional component data not shown. LC50 Fish 1.1 ppm, 96 hours Rainbow trout,donaldson trout mykiss) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) 3.74 n-Hexane 3.9 Bioconcentration factor (BCF) Titanium dioxide 352 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal of waste from residues / unused products If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Hazardous waste code D001: Waste Flammable material with a flash point <140 F Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN1950 UN number Aerosols, flammable, Limited Quantity UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk 7 / 10 Material name: White Lithium Grease 03080 Version 01 Issue date: 01-16-2015 SDS US Page 1252 of 1287 Page 1252 of 1287 Page 1252 of 1287 Page 1252 of 1287 ---PAGE BREAK--- 2.1 Label(s) Not applicable. Packing group Read safety instructions, SDS and emergency procedures before handling. Special precautions for user N82 Special provisions 306 Packaging exceptions None Packaging non bulk None Packaging bulk IATA UN1950 UN number Aerosols, flammable, Limited Quantity UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk Not applicable. Packing group No. Environmental hazards 10L ERG Code Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Allowed. Passenger and cargo aircraft Other information Allowed. Cargo aircraft only IMDG UN1950 UN number AEROSOLS, LIMITED QUANTITY UN proper shipping name 2 Class Transport hazard class(es) - Subsidiary risk Not applicable. Packing group No. Marine pollutant Environmental hazards Not available. EmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. SARA 304 Emergency release notification Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance n-Hexane (CAS 110-54-3) Zinc oxide (CAS 1314-13-2) CERCLA Hazardous Substance List (40 CFR 302.4) n-Hexane (CAS 110-54-3) Zinc oxide (CAS 1314-13-2) CERCLA Hazardous Substances: Reportable quantity n-Hexane (CAS 110-54-3) 5000 LBS Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center ([PHONE REDACTED]) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List n-Hexane (CAS 110-54-3) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. 8 / 10 Material name: White Lithium Grease 03080 Version 01 Issue date: 01-16-2015 SDS US Page 1253 of 1287 Page 1253 of 1287 Page 1253 of 1287 Page 1253 of 1287 ---PAGE BREAK--- Safe Drinking Water Act (SDWA) Not regulated. Food and Drug Administration (FDA) Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) Section 311/312 Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely hazardous substance No US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. New Jersey Worker and Community Right-to-Know Act (CAS 107-83-5) Titanium dioxide (CAS 13463-67-7) n-Hexane (CAS 110-54-3) Zinc oxide (CAS 1314-13-2) US. Massachusetts RTK - Substance List (CAS 107-83-5) n-Hexane (CAS 110-54-3) US. Worker and Community Right-to-Know Law Zinc oxide (CAS 1314-13-2) (CAS 107-83-5) n-Hexane (CAS 110-54-3) Titanium dioxide (CAS 13463-67-7) US. Rhode Island RTK n-Hexane (CAS 110-54-3) Zinc oxide (CAS 1314-13-2) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Titanium dioxide (CAS 13463-67-7) Listed: September 2, 2011 Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 100 % Consumer products (40 CFR 59, Subpt. C) Not regulated State Consumer products Not regulated (semi-solid lubricant) VOC content (CA) 84.7 % VOC content (OTC) 84.7 % International Inventories Country(s) or region Inventory name On inventory (yes/no)* Yes Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) Yes China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) 9 / 10 Material name: White Lithium Grease 03080 Version 01 Issue date: 01-16-2015 SDS US Page 1254 of 1287 Page 1254 of 1287 Page 1254 of 1287 Page 1254 of 1287 ---PAGE BREAK--- Country(s) or region Inventory name On inventory (yes/no)* Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 01-16-2015 Prepared by Allison Cho Version # 01 Further information CRC # 568F/G HMIS® ratings Health: 2* Flammability: 4 Physical hazard: 0 Personal protection: B NFPA ratings Health: 2 Flammability: 4 Instability: 0 NFPA ratings 0 2 4 Disclaimer CRC cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries. 10 / 10 Material name: White Lithium Grease 03080 Version 01 Issue date: 01-16-2015 SDS US Page 1255 of 1287 Page 1255 of 1287 Page 1255 of 1287 Page 1255 of 1287 ---PAGE BREAK--- UC-1509 1 M A T E R I A L S A F E T Y D A T A S H E E T I. IDENTIFICATION . MANUFACTURED BY: Diamond Vogel Paint REVISED: 12/13/2013 1020 Albany Place SE PRINTED: 12/20/2013 Orange City, IA 51041 General Information: 24 Hour Emergency Telephone Mon-Fri 8 AM - 5 PM CHEMTREC 1-[PHONE REDACTED] [PHONE REDACTED] TRADE NAME: White Traffic L/F, Fast Dry MFG. PRODUCT NUMBER: UC-1509 II. HAZARDOUS INGREDIENTS . CAS #13463-67-7 Titanium dioxide WT 5-20 Footnote: ACGIH TLV: 10mg/m3 TWA ACGIH STEL: OSHA PEL: OSHA CEILING: OSHA PEAK: VAPOR PRESSURE: LEL%: CAS #25265-77-4 Texanol WT 1-5 Footnote: ACGIH TLV: N.D. ACGIH STEL: OSHA PEL: OSHA CEILING: OSHA PEAK: VAPOR PRESSURE: .013mbar@20C LEL%: CAS #67-56-1 Methanol WT 1-5 Footnote: ACGIH TLV: 200 ppm ACGIH STEL: 250 ppm OSHA PEL: 200 ppm OSHA CEILING: OSHA PEAK: VAPOR PRESSURE: 92mmHg 20C LEL%: 6.0% CAS #14808-60-7 Silica WT 0.440 Footnote: ACGIH TLV: 0.025 mg/m3 ACGIH STEL: NE OSHA PEL: 10/(%SiO2+2) mg/m3 OSHA CEILING: NE OSHA PEAK: NE VAPOR PRESSURE: NA LEL%: NA WARNING MESSAGES: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Chronic exposure may cause damage to the central nervous system, respiratory system, lung, eye, skin, liver, gastrointestinal tract, spleen, kidneys, and blood. International Agency for Research on Cancer (IARC) Monograph Volume 93 (2010) concludes that Titanium dioxide is "possibly carcinogenic to humans (Group 2B)" based on inadequate evidence in humans and sufficient evidence in experimental animals. International Agency for Research on Cancer (IARC) Monograph Volume 68 (1997) concludes that Silica is "carcinogenic to humans (Group based on sufficient evidence in humans and experimental animals. See Section IX for reportable Hazardous Air Pollutants. III. PHYSICAL DATA . BOILING RANGE: 212° F EVAPORATION RATE: * slower than ether * PERCENT VOLATILE BY VOLUME: 38.38% WEIGHT PER GALLON: 14.13 LBS VAPOR DENSITY: * trace amounts of organic vapors will be heavier than air * Page 1256 of 1287 Page 1256 of 1287 Page 1256 of 1287 Page 1256 of 1287 ---PAGE BREAK--- UC-1509 2 ACTUAL VOC (lb/gal): 0.52 EPA VOC (lb/gal): 0.76 EPA VOC 91.08 IV. FIRE AND EXPLOSION HAZARD DATA . FLASH POINT: 200+° F 93+° C LEL: Refer to Section II FLAMMABILITY CLASSIFICATION: CLASS IIIB HAZARD CLASSIFICATION: *Not Regulated* EXTINGUISHING MEDIA: *carbon dioxide, dry chemical, or fire foam* UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode when exposed to extreme heat. (Due to buildup of steam pressure.) SPECIAL FIRE FIGHTING PROCEDURES: Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. V. HEALTH HAZARD DATA . THRESHOLD LIMIT VALUE: See Section II. EFFECTS OF OVEREXPOSURE Acute- Ingestion of methyl alcohol or inhalation of high levels of methyl alcohol vapor may produce headache, weakness, drowsiness, lightheadedness, nausea, vomiting, drunkenness, irritation of the eyes, and blurred vision. There is usually a latency period during which the acute may disappear, then relapse. during the relapse include nausea, vomiting, dizziness, and headache. Visual disturbances up to and including blindness almost always occur during the relapse. Liver toxicity may also occur. Eye irritation can occur if the liquid or high levels of the vapor get into the eye. Methanol also acts as a defatting agent on the skin, which can result in dermatitis. Chronic- Chronic exposure to methanol can result in headache, dizziness, nausea, vomiting, weakness, vertigo, chills, unsteady gait, dermatitis, edema of the arms, gastric pain, insomnia, blurred vision, constricted visual fields, changes in color perception, double vision and blindness. Methanol Page 1257 of 1287 Page 1257 of 1287 Page 1257 of 1287 Page 1257 of 1287 ---PAGE BREAK--- UC-1509 3 has also been reported to cause shooting pains in the lower extremities and multiple neuritis, characterized by numbness and pricking on the skin, and shooting pain in the back of the hands and forearms. Sleep disturbances and digestive problems may also occur. Methanol is a defatting agent and can cause dermatitis. This product contains silica which may cause delayed repiratory disease (silicosis) if inhaled over a prolonged period of time. Avoid breathing dust. Use a NIOSH/ MSHA approved respirator where TLV for silica may be exceeded. Target Organ Effects- Exposure to lethal concentrations of methanol has been shown to cause damage to organs including liver, kidneys, pancreas, heart, lungs and brain. Although this rarely occurs, survivors of severe intoxication may suffer from permanent neurological damage. Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals, and may aggravate pre-existing disorders of these organs in humans: central nervous system damage. Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans, and may aggravate pre-existing disorders of these organs: visual impairment. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Alcoholism, acute and chronic liver and kidney disease, anemia, coronary disease or disorders of the heart PRIMARY ROUTE(S) OF ENTRY: Eyes, Ingestion, Skin, Inhalation EMERGENCY AND FIRST AID PROCEDURES: Eye Contact: If the chemical contacts the eyes, immediately wash the eyes with large amounts of room temperature water for at least 15 minutes, occasionally lifting the lower and upper lids. Get medical attention immediately. A follow up visit to an ophthalmologist should be made. Contact lenses should not be worn when working with this chemical. Skin Contact: If this chemical contacts the skin, wash the contaminated skin with soap and water for at least 15 minutes. If this chemical penetrates the clothing, remove the clothing and wash the skin with soap and water. Systemic effects may be delayed by 18 to 72 hours, therefore keep individual under observation. Ingestion: IF SWALLOWED, SEEK MEDICAL ATTENTION IMMEDIATELY! Page 1258 of 1287 Page 1258 of 1287 Page 1258 of 1287 Page 1258 of 1287 ---PAGE BREAK--- UC-1509 4 If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Poisonous is swallowed. Can affect the optic nerve resulting inblindness. Inhalation: Remove to fresh air. If not breathing, administer CPR. If breathing is difficult, give oxygen. Call a physician. Note to Physicians: This product contains methanol which can cause intoxication and central nervous system depression. Methanol is metabolized to formic acid and formaldehyde. These metabolites can cause metabolic acidosis, visual disturbances and blindness. Since metabolism is required for these toxic their onset may be delayed from 6 to 30 hours following ingestion. Ethanol competes for the same metabolic pathway and has been used to prevent methanol metabolism. Ethanol administration is indicated in patients or at blood methanol concentrations above 20 ug/dl. Methanol is effectively removed by hemodialysis. VI. REACTIVITY DATA . STABILITY: *stable* HAZARDOUS POLYMERIZATION: *will not occur* INCOMPATIBILITY: Material can react violently with strong oxidizing agents HAZARDOUS DECOMPOSITION PRODUCTS: Fire, burning and welding may generate carbon monoxide. CONDITIONS TO AVOID: Fire, burning, and welding. VII. SPILL OR LEAK PROCEDURES . STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition (flames, hot surfaces and electrical, static or frictional sparks). Avoid breathing vapors. Ventilate area. Use non-sparking tools. Remove with inert absorbant. WASTE DISPOSAL METHOD: Dispose of in accordance with local, state, and federal regulations. VIII. SPECIAL PROTECTION INFORMATION . RESPIRATORY PROTECTION: In confined areas of poor ventilation, use chemical cartridge respirator or self-contained breathing apparatus. VENTILATION: Provide general dilution or local exhaust ventilation in volume and pattern to keep TLV and LEL of most hazardous ingredient in Section II, below acceptable limit. Page 1259 of 1287 Page 1259 of 1287 Page 1259 of 1287 Page 1259 of 1287 ---PAGE BREAK--- UC-1509 5 PROTECTIVE GLOVES: None required except for prolonged contact. EYE PROTECTION: Splash proof eye goggles. In emergency situations, use eye goggles with a full face shield. OTHER PROTECTIVE EQUIPMENT: Where contact is likely, wear rubber apron and boots. Eye wash station and safety shower should be available. HYGIENIC PRACTICES: See Section V IX. SPECIAL PRECAUTIONS . PRECAUTIONS TO BE TAKEN DURING HANDLING AND STORING: Do not store near heat, sparks, flame, strong oxidizing agents or strong acids. This material may cause sensitization. Do not get in eyes, on skin or clothing. Do not allow contaminated clothing to contact skin. Avoid contact with vapors or fumes. OTHER PRECAUTIONS: Prevent eye and skin contact. LIST OF HAZARDOUS AIR POLLUTANTS SUBJECT TO THE PROVISIONS OF THE CLEAN AIR ACT, TITLE I SECTION 112 'National Emission Standards for Hazardous Air Pollutants': Wt% of HAPS Pounds HAPS/ Ingredient CAS # in product Gal product Methanol 67-56-1 2.0 % 0.3 Page 1260 of 1287 Page 1260 of 1287 Page 1260 of 1287 Page 1260 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Product number 700-006 . 1. Product and Company Identification space Product name Xtreme Gleme All Weather Surface Degreaser space Effective date 03-Oct-2012 space Company information Claire Manufacturing Co. 1005 S. Westgate Drive Addison, IL 60101 United States space Company phone General Assistance 1-[PHONE REDACTED] space Emergency telephone US 1-[PHONE REDACTED] space Emergency telephone outside US 1-[PHONE REDACTED] space Version # 09 space Supersedes date 04-Mar-2011 space Product use Degreaser space Emergency overview Aerosol. CONTENTS UNDER PRESSURE. Harmful in contact with eyes. . 2. Hazards Identification space Routes of exposure Eye contact. Skin contact. Ingestion. Potential health effects space Eyes Contact may irritate or burn eyes. space Skin Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. space Inhalation Intentional misuse by concentrating and inhaling the product can be harmful or fatal. space Ingestion Exposure by ingestion of an aerosol is unlikely. Components of the product may be absorbed into the body by ingestion. May cause delayed lung damage. Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea. space Target organs Central nervous system. Lungs. space Chronic effects Unconsciousness. Conjunctiva. Cyanosis (blue tissue condition, nails, lips, and/or skin). May cause central nervous system disorder narcosis involving a loss of coordination, weakness, fatigue, mental confusion and blurred vision) and/or damage. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. May cause delayed lung injury. space Signs and Discomfort in the chest. Narcosis. Cyanosis (blue tissue condition, nails, lips, and/or skin). Coughing. Jaundice. Defatting of the skin. Skin irritation. space CAS # Percent 5 - 8 64-17-5 Components Ethyl Alcohol 3 - 5 112-34-5 Diethylene Glycol Monobutyl Ether 1 - 3 106-97-8 n-Butane 80 - 90 Non-hazardous and other components below reportable levels . 3. Composition / Information on Ingredients space Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. First aid procedures . 4. First Aid Measures space Skin contact Wash off with warm water and soap. Get medical attention if irritation develops and persists. space Inhalation Move to fresh air. Get medical attention if persist. space Ingestion If material is ingested, immediately contact a poison control center. space Product name: Xtreme Gleme All Weather Surface Degreaser Product 700-006 Revision date: 03-OCT-2012 Print date: 03-OCT-2012 MSDS US 1 / 5 Page 1261 of 1287 Page 1261 of 1287 Page 1261 of 1287 Page 1261 of 1287 ---PAGE BREAK--- Notes to physician Keep victim warm. Keep victim under observation. may be delayed. space Flammable properties Vapor or gas may spread to distant ignition sources and flash back. Runoff to sewer may cause fire or explosion hazard. . 5. Fire Fighting Measures space Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Extinguishing media space Protective equipment and precautions for firefighters In case of fire and/or explosion do not breathe fumes. Containers should be cooled with water to prevent vapor pressure build up. Protection of firefighters space Methods for containment Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Stop the flow of material, if this is without risk. . 6. Accidental Release Measures space Methods for cleaning up Should not be released into the environment. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. space Handling Pressurized container: Do not pierce or burn, even after use. Do not smoke while using or until sprayed surface is thoroughly dry. Do not use if spray button is missing or defective. Do not re-use empty containers. Do not get this material in contact with eyes. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with skin. . 7. Handling and Storage space Storage Contents under pressure. Do not puncture, incinerate or crush. The pressure in sealed containers can increase under the influence of heat. Do not handle or store near an open flame, heat or other sources of ignition. Avoid exposure to long periods of sunlight. Store in cool place. Keep container dry. Keep out of the reach of children. Keep away from food, drink and animal feedingstuffs. Level 1 Aerosol (NFPA 30B) space Exposure limits ACGIH Components CAS # Ethyl Alcohol 64-17-5 TWA 1000 ppm STEL 1000 ppm Ceiling Not established Diethylene Glycol Monobutyl Ether 112-34-5 20 ppm Not established Not established space n-Butane 106-97-8 1000 ppm Not established Not established . 8. Exposure Controls / Personal Protection space OSHA Components CAS # Ethyl Alcohol 64-17-5 TWA 1000 ppm STEL Not established Ceiling Not established space Diethylene Glycol Monobutyl Ether 112-34-5 100 ppm Not established Not established space Eye / face protection Do not get in eyes. Chemical goggles are recommended. Personal protective equipment space Skin protection Wear appropriate chemical resistant clothing. Chemical resistant gloves. space Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. space Appearance Cloudy. . 9. Physical & Chemical Properties space Boiling point 215.6 °F (102.2 estimated space Product name: Xtreme Gleme All Weather Surface Degreaser Product 700-006 Revision date: 03-OCT-2012 Print date: 03-OCT-2012 MSDS US 2 / 5 Page 1262 of 1287 Page 1262 of 1287 Page 1262 of 1287 Page 1262 of 1287 ---PAGE BREAK--- Color Not available space Density 0.9597 g/cm3 estimated space Flammability (HOC) 4.6332 kJ/g estimated space Flash back No space Flash point -156 °F (-104.4 Propellant space Form Aerosol. space Freezing point Not available space Odor Characteristic. space pH 9.5 - 10.5 space Physical state Liquid. space Pressure 65 - 70 psig @70F space Solubility Partially space Specific gravity 0.9598 estimated space Chemical stability Risk of ignition. . 10. Chemical Stability & Reactivity Information space Conditions to avoid Heat, flames and sparks. space Hazardous decomposition products Irritants. Toxic gas. space Acute effects Acute LD50: 55663 mg/kg estimated, Rat, Dermal . 11. Toxicological Information space Component analysis - LD50 Toxicology Data - Selected LD50s and LC50s 112-34-5 Oral LD50 Rat 3384 mg/kg; Dermal LD50 Rabbit 2700 mg/kg Diethylene Glycol Monobutyl Ether 64-17-5 Oral LD50 Rat 7060 mg/kg; Inhalation LC50 Rat 124.7 mg/L 4 h Ethyl Alcohol 106-97-8 Inhalation LC50 Rat 658 mg/L 4 h n-Butane space Carcinogenicity IARC - Group 1 (Carcinogenic to Humans) 64-17-5 Monograph 100E [in preparation] (in alcoholic beverages); Monograph 96 [2010] (in alcoholic beverages) Ethyl Alcohol space Ecotoxicity LC50 23777 mg/L, Fish, 96.00 Hours, EC50 23978 mg/L, Daphnia, 48.00 Hours, IC50 5503 mg/L, Algae, 72.00 Hours, Contains a substance which causes risk of hazardous effects to the environment. . 12. Ecological Information space Waste codes D001: Waste Flammable material with a flash point <140 F . 13. Disposal Considerations space Disposal instructions Contents under pressure. Do not puncture, incinerate or crush. Dispose of this material and its container to hazardous or special waste collection point. Do not allow this material to drain into sewers/water supplies. If discarded, this product is considered a RCRA ignitable waste, D001. space Department of Transportation (DOT) Requirements Aerosols 2.1 UN1950 Hazard class UN number Proper shipping name Basic shipping requirements: 153, N82 306 None None Special provisions Packaging exceptions Packaging non bulk Packaging bulk Additional information: . 14. Transport Information space Product name: Xtreme Gleme All Weather Surface Degreaser Product 700-006 Revision date: 03-OCT-2012 Print date: 03-OCT-2012 MSDS US 3 / 5 Page 1263 of 1287 Page 1263 of 1287 Page 1263 of 1287 Page 1263 of 1287 ---PAGE BREAK--- Further information This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2013, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/13 and may be used now in place of the "Consumer Commodity ORM-D" marking but not concurrently. space IMDG AEROSOLS 2.1 1950 Hazard class UN number Proper shipping name Basic shipping requirements: LTD QTY 5F None 2 Packaging exceptions Item Labels required Transport Category Additional information: space IATA Aerosols, flammable 2.1 1950 Hazard class UN number Proper shipping name Basic shipping requirements: LTD QTY 2.1 Packaging exceptions Labels required Additional information: space US federal regulations U.S. - CERCLA/SARA - Section 313 - Emission Reporting 112-34-5 1.0 % de minimis concentration (applies to R-(OCH2CH2)n-OR', where n = 1,2, or 3, R=alkyl C7 or less, or R = phenyl or alkyl substituted phenyl, R' = H or alkyl C7 or less, or OR' consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or sulfonate, Chemical Category N230) Diethylene Glycol Monobutyl Ether This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. . 15. Regulatory Information space 29 CFR 1910.1200 hazardous chemical Yes Occupational Safety and Health Administration (OSHA) space None CERCLA (Superfund) reportable quantity space Section 302 extremely hazardous substance No Superfund Amendments and Reauthorization Act of 1986 (SARA) space Section 311 hazardous chemical Yes space Hazard categories (311/312) Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No space Inventory status Country(s) or region Inventory name On inventory (yes/no)* No Yes No Yes No China Europe Europe Japan Korea Inventory of Existing Chemical Substances in China (IECSC) European Inventory of New and Existing Chemicals (EINECS) European List of Notified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory space Product name: Xtreme Gleme All Weather Surface Degreaser Product 700-006 Revision date: 03-OCT-2012 Print date: 03-OCT-2012 MSDS US 4 / 5 Page 1264 of 1287 Page 1264 of 1287 Page 1264 of 1287 Page 1264 of 1287 ---PAGE BREAK--- State regulations U.S. - - RTK (Right to Know) List 112-34-5 Environmental hazard Diethylene Glycol Monobutyl Ether 64-17-5 Present Ethyl Alcohol 106-97-8 Present n-Butane space Further information HMIS® is a registered trade and service mark of the NPCA. . 16. Other Information space HMIS® ratings Health: 1 Flammability: 2 Physical hazard: 0 space Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. The information in the sheet was written based on the best knowledge and experience currently available. space MSDS sections updated Product and Company Identification: Product and Company Identification Physical & Chemical Properties: Appearance Physical & Chemical Properties: Color Physical & Chemical Properties: Form Transport Information: Product Shipping Name/Packing Group Transport Information: Further information space Prepared by Regulatory Compliance space Product name: Xtreme Gleme All Weather Surface Degreaser Product 700-006 Revision date: 03-OCT-2012 Print date: 03-OCT-2012 MSDS US 5 / 5 Page 1265 of 1287 Page 1265 of 1287 Page 1265 of 1287 Page 1265 of 1287 ---PAGE BREAK--- UC-3584 1 M A T E R I A L S A F E T Y D A T A S H E E T I. IDENTIFICATION . MANUFACTURED BY: Diamond Vogel Paint REVISED: 12/12/2013 1020 Albany Place SE PRINTED: 12/19/2013 Orange City, IA 51041 General Information: 24 Hour Emergency Telephone Mon-Fri 8 AM - 5 PM CHEMTREC 1-[PHONE REDACTED] [PHONE REDACTED] TRADE NAME: Yellow Traffic L/F, Fast Dry MFG. PRODUCT NUMBER: UC-3584 II. HAZARDOUS INGREDIENTS . CAS #13463-67-7 Titanium dioxide WT 1-5 Footnote: ACGIH TLV: 10mg/m3 TWA ACGIH STEL: OSHA PEL: OSHA CEILING: OSHA PEAK: VAPOR PRESSURE: LEL%: CAS #25265-77-4 Texanol WT 1-5 Footnote: ACGIH TLV: N.D. ACGIH STEL: OSHA PEL: OSHA CEILING: OSHA PEAK: VAPOR PRESSURE: .013mbar@20C LEL%: CAS #67-56-1 Methanol WT 1-5 Footnote: ACGIH TLV: 200 ppm ACGIH STEL: 250 ppm OSHA PEL: 200 ppm OSHA CEILING: OSHA PEAK: VAPOR PRESSURE: 92mmHg 20C LEL%: 6.0% CAS #14808-60-7 Silica WT 0.577 Footnote: ACGIH TLV: 0.025 mg/m3 ACGIH STEL: NE OSHA PEL: 10/(%SiO2+2) mg/m3 OSHA CEILING: NE OSHA PEAK: NE VAPOR PRESSURE: NA LEL%: NA WARNING MESSAGES: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Chronic exposure may cause damage to the central nervous system, respiratory system, lung, eye, skin, liver, gastrointestinal tract, spleen, kidneys, and blood. International Agency for Research on Cancer (IARC) Monograph Volume 93 (2010) concludes that Titanium dioxide is "possibly carcinogenic to humans (Group 2B)" based on inadequate evidence in humans and sufficient evidence in experimental animals. International Agency for Research on Cancer (IARC) Monograph Volume 68 (1997) concludes that Silica is "carcinogenic to humans (Group based on sufficient evidence in humans and experimental animals. See Section IX for reportable Hazardous Air Pollutants. III. PHYSICAL DATA . BOILING RANGE: 212° F EVAPORATION RATE: * slower than ether * PERCENT VOLATILE BY VOLUME: 37.80% WEIGHT PER GALLON: 13.80 LBS VAPOR DENSITY: * trace amounts of organic vapors will be heavier than air * Page 1266 of 1287 Page 1266 of 1287 Page 1266 of 1287 Page 1266 of 1287 ---PAGE BREAK--- UC-3584 2 ACTUAL VOC (lb/gal): 0.53 EPA VOC (lb/gal): 0.76 EPA VOC 91.08 IV. FIRE AND EXPLOSION HAZARD DATA . FLASH POINT: 200+° F 93+° C LEL: Refer to Section II FLAMMABILITY CLASSIFICATION: CLASS IIIB HAZARD CLASSIFICATION: *Not Regulated* EXTINGUISHING MEDIA: *carbon dioxide, dry chemical, or fire foam* UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode when exposed to extreme heat. (Due to buildup of steam pressure.) SPECIAL FIRE FIGHTING PROCEDURES: Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. V. HEALTH HAZARD DATA . THRESHOLD LIMIT VALUE: See Section II. EFFECTS OF OVEREXPOSURE Acute- Ingestion of methyl alcohol or inhalation of high levels of methyl alcohol vapor may produce headache, weakness, drowsiness, lightheadedness, nausea, vomiting, drunkenness, irritation of the eyes, and blurred vision. There is usually a latency period during which the acute may disappear, then relapse. during the relapse include nausea, vomiting, dizziness, and headache. Visual disturbances up to and including blindness almost always occur during the relapse. Liver toxicity may also occur. Eye irritation can occur if the liquid or high levels of the vapor get into the eye. Methanol also acts as a defatting agent on the skin, which can result in dermatitis. Chronic- Chronic exposure to methanol can result in headache, dizziness, nausea, vomiting, weakness, vertigo, chills, unsteady gait, dermatitis, edema of the arms, gastric pain, insomnia, blurred vision, constricted visual fields, changes in color perception, double vision and blindness. Methanol Page 1267 of 1287 Page 1267 of 1287 Page 1267 of 1287 Page 1267 of 1287 ---PAGE BREAK--- UC-3584 3 has also been reported to cause shooting pains in the lower extremities and multiple neuritis, characterized by numbness and pricking on the skin, and shooting pain in the back of the hands and forearms. Sleep disturbances and digestive problems may also occur. Methanol is a defatting agent and can cause dermatitis. This product contains silica which may cause delayed repiratory disease (silicosis) if inhaled over a prolonged period of time. Avoid breathing dust. Use a NIOSH/ MSHA approved respirator where TLV for silica may be exceeded. Target Organ Effects- Exposure to lethal concentrations of methanol has been shown to cause damage to organs including liver, kidneys, pancreas, heart, lungs and brain. Although this rarely occurs, survivors of severe intoxication may suffer from permanent neurological damage. Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals, and may aggravate pre-existing disorders of these organs in humans: central nervous system damage. Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans, and may aggravate pre-existing disorders of these organs: visual impairment. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Alcoholism, acute and chronic liver and kidney disease, anemia, coronary disease or disorders of the heart PRIMARY ROUTE(S) OF ENTRY: Eyes, Ingestion, Skin, Inhalation EMERGENCY AND FIRST AID PROCEDURES: Eye Contact: If the chemical contacts the eyes, immediately wash the eyes with large amounts of room temperature water for at least 15 minutes, occasionally lifting the lower and upper lids. Get medical attention immediately. A follow up visit to an ophthalmologist should be made. Contact lenses should not be worn when working with this chemical. Skin Contact: If this chemical contacts the skin, wash the contaminated skin with soap and water for at least 15 minutes. If this chemical penetrates the clothing, remove the clothing and wash the skin with soap and water. Systemic effects may be delayed by 18 to 72 hours, therefore keep individual under observation. Ingestion: IF SWALLOWED, SEEK MEDICAL ATTENTION IMMEDIATELY! Page 1268 of 1287 Page 1268 of 1287 Page 1268 of 1287 Page 1268 of 1287 ---PAGE BREAK--- UC-3584 4 If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Poisonous is swallowed. Can affect the optic nerve resulting inblindness. Inhalation: Remove to fresh air. If not breathing, administer CPR. If breathing is difficult, give oxygen. Call a physician. Note to Physicians: This product contains methanol which can cause intoxication and central nervous system depression. Methanol is metabolized to formic acid and formaldehyde. These metabolites can cause metabolic acidosis, visual disturbances and blindness. Since metabolism is required for these toxic their onset may be delayed from 6 to 30 hours following ingestion. Ethanol competes for the same metabolic pathway and has been used to prevent methanol metabolism. Ethanol administration is indicated in patients or at blood methanol concentrations above 20 ug/dl. Methanol is effectively removed by hemodialysis. VI. REACTIVITY DATA . STABILITY: *stable* HAZARDOUS POLYMERIZATION: *will not occur* INCOMPATIBILITY: Material can react violently with strong oxidizing agents HAZARDOUS DECOMPOSITION PRODUCTS: Fire, burning and welding may generate carbon monoxide. CONDITIONS TO AVOID: Fire, burning, and welding. VII. SPILL OR LEAK PROCEDURES . STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition (flames, hot surfaces and electrical, static or frictional sparks). Avoid breathing vapors. Ventilate area. Use non-sparking tools. Remove with inert absorbant. WASTE DISPOSAL METHOD: Dispose of in accordance with local, state, and federal regulations. VIII. SPECIAL PROTECTION INFORMATION . RESPIRATORY PROTECTION: In confined areas of poor ventilation, use chemical cartridge respirator or self-contained breathing apparatus. VENTILATION: Provide general dilution or local exhaust ventilation in volume and pattern to keep TLV and LEL of most hazardous ingredient in Section II, below acceptable limit. Page 1269 of 1287 Page 1269 of 1287 Page 1269 of 1287 Page 1269 of 1287 ---PAGE BREAK--- UC-3584 5 PROTECTIVE GLOVES: None required except for prolonged contact. EYE PROTECTION: Splash proof eye goggles. In emergency situations, use eye goggles with a full face shield. OTHER PROTECTIVE EQUIPMENT: Where contact is likely, wear rubber apron and boots. Eye wash station and safety shower should be available. HYGIENIC PRACTICES: See Section V IX. SPECIAL PRECAUTIONS . PRECAUTIONS TO BE TAKEN DURING HANDLING AND STORING: Do not store near heat, sparks, flame, strong oxidizing agents or strong acids. This material may cause sensitization. Do not get in eyes, on skin or clothing. Do not allow contaminated clothing to contact skin. Avoid contact with vapors or fumes. OTHER PRECAUTIONS: Prevent eye and skin contact. LIST OF HAZARDOUS AIR POLLUTANTS SUBJECT TO THE PROVISIONS OF THE CLEAN AIR ACT, TITLE I SECTION 112 'National Emission Standards for Hazardous Air Pollutants': Wt% of HAPS Pounds HAPS/ Ingredient CAS # in product Gal product Methanol 67-56-1 2.0 % 0.3 Page 1270 of 1287 Page 1270 of 1287 Page 1270 of 1287 Page 1270 of 1287 ---PAGE BREAK--- Effective Date: May 7, 2012 Product – 93506, 93555 Page 1 of 9 Material Safety Data Sheet 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Zecol Purple Power Window Wash CAS Number: 67-56-1 Recommended Uses: Window Wash Company Identification Manufacturer's Name: ZECOL PRODUCTS COMPANY Address: 4635 Willow Drive, Medina, MN 55340 Telephone – General Information: (763) 478-3438 2. HAZARDS IDENTIFICATION Hazard Classes: Flammable Liquid Category 3 Acute Oral Toxicity Category 3 Acute Dermal (skin) Toxicity Category 3 Acute Inhalation Toxicity Category 3 Toxic to Reproduction Category 1B Specific Target Organ Toxicity (Single Exposure) Category 1 and Category 3 Aspiration Hazard Category 1 Note: Assigned to classification based on human experience with methanol. Signal Word: DANGER Hazard Statements: H226 Flammable Liquid and Vapor. H301 Toxic if Swallowed. H304 May be fatal if swallowed and enters airways. H311 Toxic in Contact with Skin. H331 Toxic if Inhaled. H336 May cause drowsiness or dizziness. H360 May Damage Fertility or the Unborn Child – fetotoxic and teratogenic effects. H370 Causes Damage to the Optic Nerve causing blindness if ingested. Precautionary Statements: P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children, P103 Read label before use. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot surfaces – No smoking. P233 Keep container closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical lighting and equipment. For Emergency Call: CHEM-TEL (800) 255-3924 24 Hour Assistance Page 1271 of 1287 Page 1271 of 1287 Page 1271 of 1287 Page 1271 of 1287 ---PAGE BREAK--- Effective Date: May 7, 2012 Product – 93506, 93555 Page 2 of 9 P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing vapors. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves / protective clothing / eye protection. P301 + P310 If SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331 Do NOT induce vomiting. P330 Rinse mouth. P303 + P361 + P353 If ON SKIN (or hair): Remove/Take of immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P308 + P311 IF exposed or concerned: Call a POISON CENTER or doctor/physician P361 + P378 Take off immediately all contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use dry chemical, CO2, alcohol-resistant foam, and water spray for extinction. P403 + P235 Store in well-ventilated place. Keep cool. P501 Disposal: Dispose of contents/container to a specialized waste disposal plant in accordance with local/regional regulations Hazard Pictograms: 3. COMPOSITION/INFORMATION ON INGREDIENTS Components Typical Weight Percentage CAS Number Methanol 35-38% 67-56-1 Water 62-65% 7732-18-5 4. FIRST AID Eyes: If irritation or redness develops, move victim away from exposure and into fresh air. Flush eyes with clean water. If persist, seek medical attention. Skin: Remove contaminated shoes and clothing and cleanse affected area(s) thoroughly by washing with mild soap and water. If irritation or redness develops, seek medical attention. Inhalation: If respiratory develop or other of exposure develop, move victim away from source of exposure and into fresh air. If persist, seek medical attention. If victim is not breathing, clear airway and immediately begin artificial respiration. If breathing difficulties develop, oxygen should be administered by qualified personnel. Seek immediate medical attention. Page 1272 of 1287 Page 1272 of 1287 Page 1272 of 1287 Page 1272 of 1287 ---PAGE BREAK--- Effective Date: May 7, 2012 Product – 93506, 93555 Page 3 of 9 Ingestion: Aspiration hazard. Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. If victim is drowsy or unconscious and vomiting, place on the left side with the head down. If possible, do not leave victim unattended and observe closely for adequacy of breathing. Seek immediate medical attention. Note to Physicians: Ethanol significantly decreases the toxicity of methanol because it competes for the same metabolic enzymes, and has been used to treat methanol poisoning. Epinephrine and other sympathomimetic drugs may initiate cardiac in persons exposed to high concentrations of hydrocarbon solvents in enclosed spaces or with deliberate abuse). The use of other drugs with less potential should be considered. If sympathomimetic drugs are administered, observe for the development of cardiac Medical Conditions: Exposure to high concentrations of this material may increase the sensitivity of the heart to certain drugs. Persons with pre-existing heart disorders may be more susceptible to this effect (see Note to Physician above). 5. FIRE FIGHTING MEASURES Suitable Extinguishing Media: Dry chemical, CO2, water spray or alcohol-resistant foam. .Water spray is recommended to cool or protect exposed materials or structures. Water may be ineffective for extinguishment, unless used under favorable conditions by experienced fire fighters. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Specific Hazards: This material is flammable and can be ignited by heat, sparks, flames or other sources of ignition static electricity, pilot lights or mechanical/electrical equipment). Flame is invisible in daylight. Vapors may travel considerable distances to a source of ignition where they can ignite, flashback or explode. May create vapor/air explosion hazard indoors, in confined spaces, outdoors or in sewers. If container is not properly cooled, it can rupture in the heat of a fire. Vapors are heavier than area and can accumulate in low areas. Hazardous Combustion Products: Toxic gases and vapors; oxides of carbon and formaldehyde. Special Firefighting Procedures: For fires beyond the initial stage, emergency responders in the immediate hazard area should wear bunker gear. When the potential chemical hazard is unknown, in enclosed or confined spaces, or when explicitly required by DOT, a self-contained breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions warrant (see Section Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Move undamaged containers from immediate hazard area if it can be done with minimal risk. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Cool equipment exposed to fire with water, if it can be done with minimal risk. Avoid spreading burning liquid with water used for cooling purposes. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Flammable. Spilling of liquid product will create a fire hazard and may form an explosive atmosphere. Keep all sources of ignition and hot metal surfaces away from spill/release if safe to do so. The use of explosion-proof equipment is recommended. Stay upwind and away from spill/release. For large spills, notify people down-wind of spill/release, isolate immediate hazard area and keep unauthorized personnel out. Wear appropriate protective equipment including respiratory protection as conditions warrant (see Section See Sections 2 and 7 for additional information on hazards and precautionary measures. Page 1273 of 1287 Page 1273 of 1287 Page 1273 of 1287 Page 1273 of 1287 ---PAGE BREAK--- Effective Date: May 7, 2012 Product – 93506, 93555 Page 4 of 9 Environmental Precautions: Stop spill/release if it can be done with minimal risk. Prevent spilled material from entering sewers, storm drains, other unauthorized treatment drainage systems, and natural waterways. Use foam on spills to minimize vapors. Use water sparingly to minimize environmental contamination and reduce disposal requirements. If spill occurs on water, notify appropriate authorities. Spills into or upon navigable waters, the contiguous zone, or adjoining shorelines that cause a sheen or discoloration on the surface water, may require notification of the National Response Center (phone number [PHONE REDACTED]). Methods for Containment and Clean-Up: Notify relevant authorities in accordance with all applicable regulations. Immediate cleanup of any spill is recommended. Dike far ahead of spill for later recovery or disposal. Absorb spill with inert material such as sand, earth or other non- combustible material, and place in suitable container for disposal. If spilled on water remove with appropriate methods skimming, booms or absorbents). In case of soil contamination, remove contaminated soil for remediation or disposal, in accordance with local regulations. 7. HANDLING AND STORAGE Precautions for Safe Handling: Keep away from ignition sources such as heat/sparks/open flames – No smoking. Take precautionary measures against static discharge. Non-sparking tools should be used. Wear protective gloves/clothing and eye/face protection. Wash thoroughly after handling. Use good personal hygiene practices and wear appropriate personal protective equipment (see Section Flammable. May vaporize easily at ambient temperatures. The vapor is heavier than air and may create an explosive mixture of vapor and air. Beware of accumulation in confined spaces and low lying areas. Open container slowly to relieve any pressure. Electrostatic charge may accumulate and create a hazardous condition when handling or processing this material. To avoid fire or explosion, dissipate static electricity during transfer by bonding and grounding containers and equipment before transferring material. The use of explosion-proof equipment is recommended and may be required (see appropriate fire codes). Refer to NFPA-77 and/or API RP 2003 for specific bonding/grounding requirements. Do not enter confined spaces such as tanks or pits without following proper entry procedures such as ASTM D-4276 and 29CFR 1910.146. Do not wear contaminated clothing or shoes. Keep contaminated clothing away from sources of ignition such as sparks or open flames. Use good personal hygiene practice. Conditions for Safe Storage: Keep container(s) closed. Use and store this material in cool, dry, well-ventilated areas away from heat and all sources of ignition. Post area “No Smoking or Open Flame.” Store only in approved containers. Keep away from any incompatible material (see Section 10). Protect container(s) against physical damage. Outdoor or detached storage is preferred. Indoor storage should meet OSHA standards and appropriate fire codes. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Component ACGIH TLV ACGIH STEL OSHA PEL OSHA STEL Methanol 200 ppm (Skin) 250 ppm (Skin) 200 ppm (Skin) 250 ppm (Skin) Page 1274 of 1287 Page 1274 of 1287 Page 1274 of 1287 Page 1274 of 1287 ---PAGE BREAK--- Effective Date: May 7, 2012 Product – 93506, 93555 Page 5 of 9 Engineering Controls: If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure limits, additional ventilation or exhaust systems may be required. Specific Personal Protective Equipment Eye/Face Protection: The use of eye protection that meets or exceeds ANSI Z.87.1 is recommended to protect against potential eye contact, irritation or injury. Depending on conditions of use, a face shield may be necessary. Skin: The use of gloves impervious to the specific material handled is advised to prevent skin contact. Users should check with manufacturers to confirm the breakthrough performance of their products. Depending on exposure and use conditions, additional protection may be necessary to prevent skin contact including use of items such as chemical resistant boots, aprons, arm covers, hoods, coveralls or encapsulated suits. Suggested protective materials: butyl and nitrile rubbers. Respiratory Protection: Where there is potential for airborne exposure above the exposure limits, a NIOSH approved air purifying respirator with an organic vapor cartridge may be used. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Air- purifying respirators provide limited protection and cannot be used in atmospheres that exceed the maximum use concentration as directed by regulation or the manufacturer’s instructions, in oxygen deficient (less than 19.5% oxygen) situations or under conditions that are immediately dangerous to life and health (IDLH). Use a positive pressure air supplied respirator if there is potential for uncontrolled release, exposure levels are unknown, or any other circumstances where air-purifying respirators may not provide adequate protection. Other Protective Equipment: Eye wash and quick-drench shower facilities should be available in the work area. Thoroughly clean shoes and wash contaminated clothing before reuse. Suggestions provided in this section for exposure control and specific types of protective equipment are based on readily available information. Users should consult with the specific manufacturer to confirm the performance of their protective equipment. Specific situations may require consultation with industrial hygiene, safety, or engineering professionals. 9. PHYSICAL AND CHEMICAL PROPERTIES (approximate values) Appearance: Clear, purple liquid Odor: Mild alcohol Odor threshold: 4.2-596 ppm pH: Not applicable Melting/Freezing Point: -97.8˚C / 208˚F Boiling point (at 1 atm): 64.7˚C / 148 ˚F Flash Point: 29 ˚C / 85 ˚F (Closed Cup) Auto-Ignition Temperature: 470 ˚C / 878 ˚F Evaporation rate (butyl acetate = 4.1 Flammability (solid, gas): Not applicable Explosive Limits: Lower – Upper – 36% Vapor Pressure: 92 mmHg @ 20 ˚C / 68 ˚F Page 1275 of 1287 Page 1275 of 1287 Page 1275 of 1287 Page 1275 of 1287 ---PAGE BREAK--- Effective Date: May 7, 2012 Product – 93506, 93555 Page 6 of 9 Vapor Density (air = 1.1 @ 15 ˚C / 59 ˚F Specific gravity (H20 = 0.79 @ 20˚C / 68 ˚F Solubility in water: Soluble Partition Coefficient: n-octanol/water: Log P = -0.77 Decomposition Temperature: No data Viscosity: 5.81 x 10-7 m2/s @ 40 ˚C / 104 ˚F 10. STABILITY AND REACTIVITY Stability (thermal, light, etc.): Stable under normal conditions of storage and handling. Conditions to Avoid: Avoid all possible sources of ignition (see Sections 5 and Incompatibility (materials to avoid): Avoid contact with strong acids, bases and oxidizers such as liquid chlorine and oxygen. Contact with these materials may cause a violent or explosive reaction. May be corrosive to lead, aluminum, magnesium and platinum. May react with metallic aluminum or magnesium and generate hydrogen gas. May attack some forms of plastic, rubber and coatings. Hazardous Decomposition Products: Thermal decomposition may release carbon monoxide, carbon dioxide, and formaldehyde. Hazardous Polymerization: Will not occur. 11. TOXICOLOGICAL INFORMATION Acute Toxicity: Product/Ingredient Name Result Species Dose Methanol (major ingredient) LD50 Oral LD50 Dermal LC50 Inhalation (vapor) Rat Rabbit Rat >2528 mg/kg 17,100 mg/kg 13.3 mg/l – 6hr Note: Assigned to classification based on human experience and not animal data. Skin Corrosion/Irritation: Causes mild irritation. Repeated exposure may cause dryness or cracking. Serious Eye Damage/Irritation: Causes mild irritation. Signs and High concentrations can cause minor respiratory irritation, headache, drowsiness, dizziness, loss of coordination, disorientation and fatigue. Ingestion can cause irritation of the digestive tract, nausea, abdominal pain, vomiting and visual disturbances ranging from blurred vision to light sensitivity, blindness or death. Skin Sensitization: None reported Respiratory Sensitization: None reported Germ Cell Mutagenicity: There is insufficient information available to conclude that methanol is mutagenic. Carcinogenicity: Methanol did not demonstrate carcinogenic effects in rats and mice treated via whole body inhalation at concentrations > 1.3 mg/l in air. There is insufficient information available to conclude that methanol is carcinogenic. It is not listed by NTP, IARC or OSHA. Page 1276 of 1287 Page 1276 of 1287 Page 1276 of 1287 Page 1276 of 1287 ---PAGE BREAK--- Effective Date: May 7, 2012 Product – 93506, 93555 Page 7 of 9 Reproductive Toxicity: Methanol has produced fetotoxicity in rats and teratogenicity in mice exposed by inhalation to high concentrations of methanol vapors. Specific Target Organ Toxicity (Single Exposure): Methanol ingestion causes damage to the optic nerve causing blindness. May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): There is insufficient information available to conclude that methanol causes target organ effects from repeated exposure. Aspiration Hazard: May be fatal if swallowed and enters airways. 12. ECOLOGICAL INFORMATION Toxicity: Ingredient Name Result Species Exposure Methanol (major ingredient) Acute EC50 = 16.912 mg/L Marine Water Acute LC50 = 2500000 ug/L Marine Water Acute LC50 = 3289 mg/L Fresh Water Acute LC50 > 100000 ug/L Fresh Water Algae Crustacean s Daphnia Fish 96 hours 48 hours 48 hours 96 hours Persistence and Degradability: Methanol biodegrades easily in water and soil. BOD5 = 1.1 COD = 1.05 – 1.55, 99% Bioaccumulative Potential: Risk of bioaccumulation is low (BCF <500 and low log Kow BCF = 0.2 - <10 Log Kow = -0.77 Mobility in Soil: Methanol is highly mobile. Adsorption coefficient (Koc) solid phase/liquid phase = 1 Other Adverse Effects: None known 13. DISPOSAL CONSIDERATIONS The generator of a waste is always responsible for making proper hazardous waste determinations and needs to consider state and local requirements in addition to federal regulations. Recycle wherever possible. Large volumes may be suitable for re-distillation or, if contaminated, incinerated. Can be disposed of in a sewage treatment facility. This material, if discarded as produced, would not be a federally regulated RCRA “listed” hazardous waste. However, it would likely be identified as a federally regulated RCRA hazardous waste for the following characteristic of ignitability (D001). See Sections 7 and 8 for information on handling, storage and personal protection and Section 9 for physical/chemical properties. It is possible that the material as produced contains constituents which are not required to be listed in the MSDS but could affect the hazardous waste determination. Additionally, use which results in chemical or physical change of this material could subject it to regulation as a hazardous waste. 14. TRANSPORT INFORMATION DOT/TDG Proper Shipping Name: Flammable Liquid n.o.s. (Methanol) Page 1277 of 1287 Page 1277 of 1287 Page 1277 of 1287 Page 1277 of 1287 ---PAGE BREAK--- Effective Date: May 7, 2012 Product – 93506, 93555 Page 8 of 9 DOT/TDG Identification Number: UN1993 DOT Hazard Class: 3 / TDG Hazard Class: 3(6.1) DOT/TDG Packing Group: II ERG Guide Number: 131 Marine Pollutant: No 15. REGULATORY INFORMATION TSCA: Methanol is listed on the TSCA inventory. DSL: Methanol is listed on the DSL inventory. OSHA (Occupational Safety and Health Administration): This material is considered to be hazardous as defined by the OSHA Hazard Communication Standard. This material has not been identified as a carcinogen by NTP, IARC or OSHA CERCLA/SARA – Section 302 Extremely Hazardous Substances and TPQ (in pounds): This material does NOT contain chemicals subject to the reporting requirements of SARA 302 and 40 CFR 355 Appendix A and B. EPA (CERCLA) Reportable Quantity (in pounds): This material contains the following chemicals subject to the reporting requirements of 40 CFR 302.4: Component Concentration RQ Methanol 35-38% 5000 lbs CERCLA/SARA - Sections 311/312 (Title III Hazard Categories): Acute: Yes Chronic: Yes Fire: Yes Reactivity: No CERCLA/SARA – Section 313 and 40 CFR 372: This material contains the following chemicals subject to the reporting requirements of SARA 313 and SARA Title III and 40 CFR: Component Concentration de minimis Methanol 35-38% 1% California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material contains detectable chemicals known to the State of California to cause cancer and/or reproductive toxicity. Component Concentration Effect Methanol 35-38% Developmental Canada: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all the information required by the Regulations. WHMIS Hazard Class: B2, D1B, D2A, D2B 16. OTHER INFORMATION Issue Date: May 3, 2012 Previous Issue Date: January 5, 2010 Change: Updated to new GHS compliant HCS 2012 criteria Page 1278 of 1287 Page 1278 of 1287 Page 1278 of 1287 Page 1278 of 1287 ---PAGE BREAK--- Effective Date: May 7, 2012 Product – 93506, 93555 Page 9 of 9 DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES The information in this document is believed to be correct as of the date issued. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THIS INFORMATION, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. This information and product are furnished on the condition that the person receiving them shall make his own determination as to the suitability of the product for this particular purpose and on the condition that he assumes the risk of his use thereof. Page 1279 of 1287 Page 1279 of 1287 Page 1279 of 1287 Page 1279 of 1287 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Product identifier ZRC-221 Cold Galvanizing Compound Version # 01 Issue date 05-February-2014 Revision date - Supersedes date - CAS # Mixture Product code 50002 - 50003 Product use Corrosion protection of iron and steel. Manufacturer Supplier/Manufacturer ZRC Worldwide Address 145 Enterprise Drive, Marshfield, MA 02050 Telephone [PHONE REDACTED] Emergency telephone (CHEMTREC) [PHONE REDACTED] CCN15781 2. Hazards Identification Emergency overview WARNING Combustible liquid. May be ignited by heat, sparks or flames. Prolonged exposure may cause chronic effects. Potential health effects Routes of exposure Inhalation. Ingestion. Skin contact. Eye contact. Eyes Do not get this material in contact with eyes. Direct contact with eyes may cause temporary irritation. Skin Do not get this material in contact with skin. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Inhalation Do not breathe dust/fume/gas/mist/vapors/spray. Prolonged inhalation may be harmful. Ingestion Do not ingest. Harmful if swallowed. Target organs Eyes. Skin. Reproductive system. Signs and Direct contact with eyes may cause temporary irritation. Prolonged skin contact may cause temporary irritation. Swallowing may cause gastrointestinal irritation. Potential environmental effects Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Components CAS # Percent 3. Composition / Information on Ingredients 7440-66-6 75 - 85 Zinc 64742-47-8 2 - 3 Distillates (petroleum), hydrotreated light 64742-88-7 2 - 3 Solvent naphtha (petroleum), medium aliph. 1314-13-2 2 - 3 Zinc oxide 64742-95-6 0.1 - 0.2 Solvent naphtha (petroleum), light aromatic 7.35 Other components below reportable levels 4. First Aid Measures First aid procedures Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. If a contact lens is present, DO NOT delay irrigation or attempt to remove the lens. Continue rinsing. Get medical attention immediately. ZRC-221 Cold Galvanizing Compound MSDS Canada 917618 Version 01 Revision date: - Issue date: 05-February-2014 1 / 7 Page 1280 of 1287 Page 1280 of 1287 Page 1280 of 1287 Page 1280 of 1287 ---PAGE BREAK--- Skin contact Remove and isolate contaminated clothing and shoes. Immediately flush skin with plenty of water. Get medical attention immediately. For minor skin contact, avoid spreading material on unaffected skin. Wash clothing separately before reuse. Inhalation Move to fresh air. Get medical attention if any discomfort continues. Ingestion Get medical attention if any discomfort occurs. Notes to physician Provide general supportive measures and treat General advice In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 5. Fire Fighting Measures Flammable properties Combustible by WHMIS criteria. Heat may cause the containers to explode. Extinguishing media Suitable extinguishing media Dry chemical, CO2, water spray, fog, or foam. Unsuitable extinguishing media Do not use water jet. Protection of firefighters Protective equipment for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. In the event of fire, cool tanks with water spray. Move containers from fire area if you can do so without risk. In case of fire and/or explosion do not breathe fumes. Water runoff can cause environmental damage. Explosion data Sensitivity to static discharge Not sensitive. Sensitivity to mechanical impact Not sensitive. Hazardous combustion products Carbon dioxide. Carbon monoxide. 6. Accidental Release Measures Personal precautions Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Ventilate closed spaces before entering them. For personal protection, see Section 8 of the MSDS. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water. Contact local authorities in case of spillage to drain/aquatic environment. Methods for containment Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Keep out of low areas. Prevent entry into waterways, sewer, basements or confined areas. Methods for cleaning up Extinguish all flames in the vicinity. Should not be released into the environment. Stop the flow of material, if this is without risk. Isolate area until gas has dispersed. Clean up in accordance with all applicable regulations. For waste disposal, see section 13 of the MSDS. Other information Clean up in accordance with all applicable regulations. Prevent product from entering drains. 7. Handling and Storage Handling Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. When using do not smoke. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get this material in contact with eyes. Do not get this material in contact with skin. Avoid prolonged exposure. Do not get this material on clothing. Do not use in areas without adequate ventilation. Wear personal protective equipment. Wash thoroughly after handling. Avoid release to the environment. Storage Do not handle or store near an open flame, heat or other sources of ignition. Keep at temperature not exceeding 49 This material can accumulate static charge which may cause spark and become an ignition source. Store in a closed container away from incompatible materials. Store in a well-ventilated place. Keep container dry. ZRC-221 Cold Galvanizing Compound MSDS Canada 917618 Version 01 Revision date: - Issue date: 05-February-2014 2 / 7 Page 1281 of 1287 Page 1281 of 1287 Page 1281 of 1287 Page 1281 of 1287 ---PAGE BREAK--- 8. Exposure Controls / Personal Protection Occupational exposure limits US. ACGIH Threshold Limit Values Value Type Form Components STEL 10 mg/m3 Respirable fraction. Zinc oxide (CAS 1314-13-2) TWA 2 mg/m3 Respirable fraction. Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) Value Type Form Components TWA 200 mg/m3 Vapor. Distillates (petroleum), hydrotreated light (CAS 64742-47-8) STEL 10 mg/m3 Respirable. Zinc oxide (CAS 1314-13-2) TWA 2 mg/m3 Respirable. Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) Value Type Form Components TWA 200 mg/m3 Non-aerosol. Distillates (petroleum), hydrotreated light (CAS 64742-47-8) STEL 10 mg/m3 Respirable. Zinc oxide (CAS 1314-13-2) TWA 2 mg/m3 Respirable. Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act) Value Type Form Components STEL 10 mg/m3 Respirable fraction. Zinc oxide (CAS 1314-13-2) TWA 2 mg/m3 Respirable fraction. Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) Value Type Form Components STEL 10 mg/m3 Respirable fraction. Zinc oxide (CAS 1314-13-2) TWA 2 mg/m3 Respirable fraction. Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) Value Type Form Components STEL 10 mg/m3 Fume. Zinc oxide (CAS 1314-13-2) TWA 5 mg/m3 Fume. 10 mg/m3 Total dust. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Type Form Components PEL 5 mg/m3 Fume. Zinc oxide (CAS 1314-13-2) 5 mg/m3 Respirable fraction. 15 mg/m3 Total dust. Exposure guidelines Canada - Alberta OELs: Skin designation Distillates (petroleum), hydrotreated light (CAS 64742-47-8) Can be absorbed through the skin. Canada - British Columbia OELs: Skin designation Distillates (petroleum), hydrotreated light (CAS 64742-47-8) Can be absorbed through the skin. Canada - Ontario OELs: Skin designation Distillates (petroleum), hydrotreated light (CAS 64742-47-8) Can be absorbed through the skin. Canada - Saskatchewan OELs: Skin designation Distillates (petroleum), hydrotreated light (CAS 64742-47-8) Can be absorbed through the skin. ZRC-221 Cold Galvanizing Compound MSDS Canada 917618 Version 01 Revision date: - Issue date: 05-February-2014 3 / 7 Page 1282 of 1287 Page 1282 of 1287 Page 1282 of 1287 Page 1282 of 1287 ---PAGE BREAK--- Engineering controls Ensure adequate ventilation, especially in confined areas. Personal protective equipment Eye / face protection Do not get in eyes. If contact is likely, safety glasses with side shields are recommended. Skin protection Wear suitable protective clothing. Use appropriate hand protection. Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. 9. Physical & Chemical Properties Appearance Gray liquid. Physical state Liquid. Form Liquid. Color Gray. Odor Aliphatic. Hydrocarbon. Odor threshold Not available. pH Not available. Vapor pressure Not available. Vapor density > 1 (25°C / 77°F) Boiling point 291.2 - 404.6 °F (144 - 207 Melting point/Freezing point Not available. Solubility (water) soluble in water. Specific gravity Not available. Flash point 109.4 °F (43.0 Setaflash Flammability limits in air, upper, % by volume 7 % Flammability limits in air, lower, % by volume 0.9 % Auto-ignition temperature Not available. VOC 221 g/l (1.8 lb/gal) Evaporation rate < 1 (n-Butyl acetate=1) Viscosity 1800 mPa·s (25°C / 77°F) Bulk density 26 lb/gal 10. Chemical Stability & Reactivity Information Chemical stability Material is stable under normal conditions. Conditions to avoid Avoid temperatures exceeding the flash point. Incompatible materials Strong oxidizing agents. Hazardous decomposition products Carbon oxides. Zinc oxides. 11. Toxicological Information Test Results Toxicological data Components Species Distillates (petroleum), hydrotreated light (CAS 64742-47-8) LD50 Rabbit Dermal Acute > 2000 mg/kg LC50 Rat Inhalation > 5.28 mg/l, 4 hours LD50 Rat Oral > 5000 mg/kg ZRC-221 Cold Galvanizing Compound MSDS Canada 917618 Version 01 Revision date: - Issue date: 05-February-2014 4 / 7 Page 1283 of 1287 Page 1283 of 1287 Page 1283 of 1287 Page 1283 of 1287 ---PAGE BREAK--- Test Results Components Species Solvent naphtha (petroleum), medium aliph. (CAS 64742-88-7) LD50 Rabbit Dermal Acute 3000 mg/kg LD50 Rat Oral > 5000 mg/kg Acute effects Not classified. Sensitization Not classified. Local effects Direct contact with eyes may cause temporary irritation. May cause discomfort if swallowed. Prolonged or repeated contact may dry skin and cause irritation. Chronic effects Prolonged exposure may cause chronic effects. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Not classifiable as to carcinogenicity to humans. Mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Reproductive effects Not classified. and target organs Direct contact with eyes may cause temporary irritation. Prolonged or repeated contact may dry skin and cause irritation. 12. Ecological Information Ecotoxicological data Components Test Results Species Zinc (CAS 7440-66-6) Aquatic LC50 Crustacea 0.068 mg/l, 48 hours Daphnia magna LC50 Fish 0.52 - 3.59 mg/l, 96 hours Bony fish superclass Zinc oxide (CAS 1314-13-2) Aquatic LC50 Crustacea 0.098 mg/l, 48 Hours Water flea (Daphnia magna) Ecotoxicity Components of this product are hazardous to aquatic life. Environmental effects Very toxic to aquatic life with long lasting effects. Persistence and degradability Not available. Bioaccumulation / Accumulation Accumulation in aquatic organisms is expected. 13. Disposal Considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Dispose in accordance with all applicable regulations. Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. Transport Information TDG UN1263 UN number Paint UN proper shipping name 3 Class Transport hazard class(es) - Subsidiary risk III Packing group Yes Environmental hazards Not available. Special precautions for user ZRC-221 Cold Galvanizing Compound MSDS Canada 917618 Version 01 Revision date: - Issue date: 05-February-2014 5 / 7 Page 1284 of 1287 Page 1284 of 1287 Page 1284 of 1287 Page 1284 of 1287 ---PAGE BREAK--- IATA UN1263 UN number Paint UN proper shipping name 3 Class Transport hazard class(es) - Subsidiary risk 3 Label(s) III Packing group Yes Environmental hazards Read safety instructions, MSDS and emergency procedures before handling. Special precautions for user IMDG UN1263 UN number Paint UN proper shipping name 3 Class Transport hazard class(es) - Subsidiary risk III Packing group Yes Marine pollutant Environmental hazards F-E, S-E EmS Read safety instructions, MSDS and emergency procedures before handling. Special precautions for user 15. Regulatory Information Canadian regulations This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. WHMIS status Controlled WHMIS classification B3 - Combustible Liquids D2B - Other Toxic Effects-TOXIC WHMIS labeling Inventory status Country(s) or region Inventory name On inventory (yes/no)* Australian Inventory of Chemical Substances (AICS) Yes Australia Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No Canada Inventory of Existing Chemical Substances in China (IECSC) Yes China European Inventory of Existing Commercial Chemical Substances (EINECS) Yes Europe European List of Notified Chemical Substances (ELINCS) No Europe Inventory of Existing and New Chemical Substances (ENCS) No Japan Existing Chemicals List (ECL) Yes Korea New Zealand Inventory Yes New Zealand Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes Philippines *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Toxic Substances Control Act (TSCA) Inventory Yes United States & Puerto Rico 16. Other Information HMIS® ratings Health: 1 Flammability: 2 Physical hazard: 0 ZRC-221 Cold Galvanizing Compound MSDS Canada 917618 Version 01 Revision date: - Issue date: 05-February-2014 6 / 7 Page 1285 of 1287 Page 1285 of 1287 Page 1285 of 1287 Page 1285 of 1287 ---PAGE BREAK--- NFPA ratings Health: 1 Flammability: 2 Instability: 0 Disclaimer The information in the sheet was written based on the best knowledge and experience currently available. ZRC-221 Cold Galvanizing Compound MSDS Canada 917618 Version 01 Revision date: - Issue date: 05-February-2014 7 / 7 Page 1286 of 1287 Page 1286 of 1287 Page 1286 of 1287 Page 1286 of 1287 ---PAGE BREAK--- Safety Data Sheets Highway Department - Hawthorne Shop Highway Department - Hawthorne Shop 11/16/2015 Page 1287 of 1287 Page 1287 of 1287 Page 1287 of 1287 Page 1287 of 1287