Document douglascountywi_gov_doc_7fa6e1d564

Safety Data Sheets Court House & Government Center Buildings & Grounds 02/29/2016 ---PAGE BREAK--- Safety Data Sheet Index Binder: Buildings & Grounds - Court House & Government Center #530, 531 EMERGENCY TIRE INFLATOR ZECOL PRODUCTS COMPANY 05/01/2007 10 106 MoorGard 100% Acrylic Latex House Paint BENJAMIN MOORE & COMPANY 05/04/1998 12 137 Moore¹s Weatherproof Aluminum Paint BENJAMIN MOORE & COMPANY 12/15/1997 16 3M Desk & Office Cleaner - Aerosol 3M 03/12/1998 20 3M Super 77 Multipurpose Adhesive (Aerosol) 3M - Construction and Home Improvement Products 04/06/2009 25 3UM47 - Lubricant Wd 40 16 Oz WD-40 Company 03/11/2010 34 41770 OATLEY REGULAR CLEAR PVC SOLVENT CEMENT Oatey Company 03/10/1992 36 5H901 - Spray Paint Gloss Bright Red 150z Rust-Oleum Corporation - Industrial Coatings 04/05/2006 40 6KP02 - Paint Marking Rust-Oleum Corporation 01/25/2006 43 AERO INSTANT FOAMING HAND SANITIZER Deb SBS Inc. 05/30/2006 45 AIRLIFT FRESH SCENT AIR FRESHENER (AEROSOL) Spartan Chemical Company, Inc. 08/06/2011 47 AIRLIFT LEMON SCENT AIR FRESHENER (AEROSOL) Spartan Chemical Company, Inc. 06/08/2011 50 ALKYD/OIL STAINS/NWF PPG Industries, Inc. 01/26/2006 53 All Purpose Spotter Essential Industries, Inc. 07/14/2009 58 ALL PURPOSE SPOTTER Essential Industries, Inc. 01/22/2008 60 ANTI-STAT 68607-27-2 Clausen Carpet Solutions 01/01/2008 61 AOUASCENT (Apple-Pear) F-Matic of America 01/01/2005 62 AquaScent (Apple-Pear) F-MATIC, INC. 09/26/2011 64 Astro Dalco Industries, Ltd. 01/01/2002 68 B66 - DTM Acrilic Semi Gloss Enamel Sherwin-Williams Company 05/18/1998 69 Benjamin Moore Collection Latex High Gloss Enamel BENJAMIN MOORE & COMPANY 12/01/2005 71 Benzomatic Propane Cylinder BERNZOMATIC CORPORATION 74 BERRY BLAST (12X12 OZ) CHEMSEARCH - A DIVISION OF NCH CORPORATION 07/18/2007 76 Product Name CAS Number Manufacturer Version Date Page Page 2 of 878 Page 2 of 878 Page 2 of 878 Page 2 of 878 ---PAGE BREAK--- BERRY BLAST (12X12 OZ) CHEMSEARCH DIV. OF NCH CORP. 07/19/2010 79 BLAST OFF 16A Dalco Enterprises 01/16/2007 83 Blow Off Air Duster 68476-86-8 A.V.W. Inc. 01/20/2012 85 BRAVO HEAVY DUTY LOW ODOR STRIPPER Johnson Wax Professional 01/29/2003 86 BRRR-Eaker Drummond, A Lawson Brand 07/19/2012 90 CaviCide Metrex Research 12/15/2014 94 CaviCide Metrex Research 07/14/2015 104 CHEWING GUM REMOVER Spartan Chemical Company, Inc. 09/16/2014 110 CHEWING GUM REMOVER Freeze Action 68476-85-7 Dalco 09/01/2005 115 CLASSIC 99 Interior Flat Latex Wall Paint, Extra White THE SHERWIN-WILLIAMS COMPANY 06/28/2014 117 CLASSIC ONE Interior Latex Flat Finish, Ultra White Dutch Boy Group 02/28/2008 121 CLOROX REGULAR BLEACH The Clorox Company 08/01/2009 126 CLR MOLD & MILDEW STAIN REMOVER Jelmar, LLC 02/12/2015 127 CLR- CALCIUM LIME & RUST REMOVER JELMAR 03/01/2009 134 CONQ-R-DUST Dust Mop / Dust Cloth Treatment (Aerosol) Diversey, Inc. 07/14/2010 139 CONQ-R-DUST PRESSURIZED JohnsonDiversey 01/13/2004 143 Cool It Lawson Products, Inc. 05/01/1972 151 Crew Bathroom & Scale Remover Johnson Wax Professional 10/04/2007 153 Dal-Pro #14 Orbit Dalco 07/01/2010 156 Dalco Defoamer 78-51-3 Dalco Industries, Ltd. 01/15/1989 157 DAP 2000 Construction Adhesive DAP, INC. 02/14/2000 159 DAP BEATS THE NAIL All Purpose Construction Adhesive DAP, INC. 02/03/1999 166 DAP MULTIPURPOSE CERAMIC TILE ADHESIVE DAP, INC. 02/10/2002 173 Deep Creep Sea Foam SEA FOAM SALES CO 05/01/2005 180 Defoamer Spartan Chemical Company 09/22/2008 182 Distilled White Vinegar 8028-52-2 H.J. HEINZ CO. 08/22/2011 186 Dura Clean Satin Interior Latex Wall & Trim Paint, Base A Dutch Boy Group 11/02/2009 188 Product Name CAS Number Manufacturer Version Date Page Page 3 of 878 Page 3 of 878 Page 3 of 878 Page 3 of 878 ---PAGE BREAK--- Elmers Carpenters Ext, Wood Filler Elmer's Products, Inc. 09/14/2001 192 Elmers Glue-All Elmer's Products, Inc. 11/16/2006 199 END BAC II DISINFECTANT SPRAY JohnsonDiversey 06/22/2005 206 EPOXYS SSPR 6PK ANTI-SLIP AEROSOL Rust-Oleum Corporation 05/15/2015 209 EXTRACTION CLEANER Johnson Wax Professional 04/29/2005 216 EYE GLASS CLEANER JohnsonDiversey 02/02/2004 219 FACILIPRO MILD FOAMING HAND SOAP Ecolab Inc. 10/17/2014 222 FACILIPRO WATERLESS FOAM HAND SANITIZER Ecolab Inc. Institutional Division 10/04/2013 229 FASTRIP Floor Stripper Diversey, Inc. 03/12/2010 235 FILL AND SEAL 20oz Expanding Foam Sealant The Dow Chemical Company 01/31/2008 239 Fireball Dalco Enterprises 252 FLORCRAFT PREMIUM CARPET ADHESIVE CHICAGO ADHESIVE PRODUCTS COMPANY - CHAPCO 05/18/2004 254 FlorCraft Vinyl Composition Tile Adhesive Tile Perfect, Inc. 05/18/2004 258 FOAMY Q&A Spartan Chemical Company 03/25/2008 262 Formula 100 Ice Remover State Industrial 265 Formula 340 Multi-Clean 04/01/2012 271 FORMULA 409 ALL PURPOSE CLEANER The Clorox Company 03/01/2010 272 Gasoila 100 Thread Sealant FEDERAL PROCESS COMPANY 03/29/2006 273 GLANCE NA Johnson Wax Professional 07/25/2007 276 Glance SC (Super Concentrate) Johnson Wax Professional 05/15/2006 279 GOJO E1 Foam Handwash GOJO Industries, Inc. 10/06/2009 283 GOLDEN HARVEST STICK-EASE SEAM AND TOUCH-UP ADHESIVE; 209452, 209454, 209455 Roman Adhesives, Inc. 06/28/1996 285 GOO GONE PAINTER'S PAL MAGIC AMERICAN PRODUCTS, INC. 04/29/2003 288 GOOD RIDDANCE CHEMSEARCH - A DIVISION OF NCH CORPORATION 02/05/2009 289 Goop Liquid Orange Hand Cleaner CRITZAS INDUSTRIES, INC. 10/29/2014 293 Gorilla Epoxy (Gray Package)- Hardener The Gorilla Glue Company 06/12/2012 297 Gorilla Epoxy (Gray Package)- Resin The Gorilla Glue Company 06/12/2012 302 GP Forward (1:64 Use Solution) JohnsonDiversey - Canada, Inc. 10/25/2006 307 Product Name CAS Number Manufacturer Version Date Page Page 4 of 878 Page 4 of 878 Page 4 of 878 Page 4 of 878 ---PAGE BREAK--- GRAFFITI AWAY TOWELS TRI-CHEM CORPORATION 05/24/2007 310 Grainger Premiere Pro Ice Melter CP INDUSTRIES 01/03/2006 312 Great Stuff Gaps & Cracks Dow Chemical Company 09/17/2002 313 GREAT STUFF Pro Gun Cleaner The Dow Chemical Company 09/27/2013 321 Green Envy Driveway Cleaner & Degreaser SUNNYSIDE CORPORATION 08/26/2008 331 Gum Remover Johnson Wax Professional 03/07/2008 334 Heavy Duty Carpet Cleaner Rubbermaid Commercial Products 06/09/2003 337 Heavy Duty Chain Lubricant Lawson Products, Inc. 05/02/2012 339 Home Armor Mildew Stain Remover Plus Blocker W. M. Barr 04/17/2015 343 Industrial Blue SCOTWOOD INDUSTRIES, INC. 10/21/2014 350 Instant FOAM Hand Sanitiser DEB Australia 02/12/2009 356 Interior/ Exterior Traffic Marking Paint Acrylic, Striping Yellow CONCO PAINT CO 04/20/2005 360 Interior/Exterior DTM 100% Acrylic Gloss Industrial Enamel, Accent Base CONCO PAINT CO 11/28/2010 365 Interior/Exterior DTM Alkyd Gloss Industrial Enamel, Safety Yellow CONCO PAINT CO 04/19/2010 368 Kimberly-Clark Professional Waterless Hand Wipes, Kimberly-Clark Professional Heavy Duty Hand Cleaning Wipes, WYPALL Waterless Hand Wipes Kimberly-Clark Corporation 06/09/2007 373 Klean Strip Aircraft Paint Remover W. M. Barr 04/13/2012 379 KLEAN-STRIP ACETONE W.M. BARR & COMPANY 05/18/2005 390 KRUD KUTTER Concrete Clean and Etch SUPREME CHEMICALS OF GEORGIA, INC. 08/28/2007 395 KRYLON LINE-UP Striping Paint (Solvent Based), Handicap Blue THE SHERWIN-WILLIAMS COMPANY- KRYLON Products Group 07/05/2012 403 KRYLON LINE-UP Striping Paint (Solvent Based), Handicap Blue THE SHERWIN-WILLIAMS COMPANY- KRYLON Products Group 08/14/2013 408 KRYLON LINE-UP Striping Paint (Solvent Based), Handicap Blue THE SHERWIN-WILLIAMS COMPANY- KRYLON Products Group 06/18/2013 413 KRYLON LINE-UP Striping Paint (Solvent Based), Handicap Blue THE SHERWIN-WILLIAMS COMPANY- KRYLON Products Group 09/23/2011 418 Lano-Vera Foaming Hand Soap Dalco Enterprises 06/01/2004 423 Product Name CAS Number Manufacturer Version Date Page Page 5 of 878 Page 5 of 878 Page 5 of 878 Page 5 of 878 ---PAGE BREAK--- LECTRA SOL TC (AEROSOL) TRI-CHEM CORPORATION 06/19/2012 424 Light Oil Lubricant Lawson Products, Inc. 05/28/2013 426 Liquid Hand Dishwashing Detergents Procter & Gamble - P&G Household Care 08/28/2014 430 Liquid Ice-Chek Activator State Industrial Products 434 LIQUID WRENCH SUPER LUBRICANT Radiator Specialty Company 02/12/1991 440 Lock- Lube Lawson Products, Inc. 03/10/2014 444 Loctite Contact Adhesive HENKEL LOCTITE CORPORATION 08/20/2014 447 Loctite PL375 Heavy Duty Construction Adhesive Henkel Corporation 06/18/2010 454 Loctite Polyseamseal Tub & Tile Ultra Sealant Henkel Corporation 12/15/2014 460 Lubri-Temp Anti-Seize Lawson Products, Inc. 01/30/2008 465 Marvel Lubricating Oil Marvel Oil Company 11/07/2000 471 Mildew Stain Remover Plus Blocker W. M. Barr 03/14/2013 475 mineral spirits SUNNYSIDE CORPORATION 05/20/2005 481 Minwax Polyshades Interior Stain MINWAX Company 09/29/2007 484 MINWAX WOOD FINISH Stain Marker MINWAX Company 03/19/2003 490 MINWAX WOOD PUTTY MINWAX Company 02/11/2009 495 Misty Surface Disinfectant AMREP, Inc. 05/31/2015 499 Mobil Rarus 427 Exxon Mobil Corporation 06/14/2012 511 Natural Magic Odor Blaster Liquid Osmegen Inc 03/25/1998 520 Natural Magic Odor Blaster Liquid Osmegen Inc 03/25/1998 522 OLD ENGLISH OIL (LEMON OIL, RED OIL & ORANGE OIL) Reckitt Benckiser, Inc. 08/05/2004 524 ORANGE GOOP LIQUID, ORANGE GOOP LIQUID WITH PUMICE CRITZAS INDUSTRIES, INC. 01/01/2009 528 ORANGE TOUGH 40 Spartan Chemical Company, Inc. 06/01/2015 531 Orbit Extraction Rinse Dalco Enterprises 533 ORTHO Weed-B-Gon LawnGaurd Formula Concentrate The ORTHO Group 02/27/2004 535 Oxivir Tb Johnson Wax Professional 03/02/2006 539 Oxivir Tb Wipes JohnsonDiversey 12/06/2007 542 P.O.G. Spotter Gel JohnsonDiversey, Inc. 08/28/2008 545 Product Name CAS Number Manufacturer Version Date Page Page 6 of 878 Page 6 of 878 Page 6 of 878 Page 6 of 878 ---PAGE BREAK--- P.O.G. Spotter Gel Diversey, Inc. 05/21/2014 548 PEAK ANTIFREEZE & COOLANT Old World Industries, Inc. 10/11/2011 552 PEAK ANTIFREEZE & COOLANT Old World Industries, Inc. 10/21/2010 564 Pearl Soft Lotion Hand Cleaner Dalco Enterprises 01/01/2002 576 PINE SOL CLEANER CLOROX CO. 08/09/1994 577 Polyurethane Gloss Porch & Floor Enamel, White DUTCH BOY 06/07/2009 582 Pourable Gray Concrete Crack Filter; Concrete Repair; Mortar Repair; Pre-Mixed Stucco Patch; Pre-Mixed Concrete Patch Akona Manufacturing, LLC. 06/01/2008 586 PowerOff Contact Clenaer Lawson Products, Inc. 06/07/2006 588 PowrOff Contact Cleaner Lawson Products, Inc. 06/07/2006 595 PREMIUM INTERIOR EGGSHELL ULTRA WHITE / BS 1 PPG Industries, Inc. - Coatings & Resins Group 11/07/2000 602 PROTEIN SPOTTER S. C. Johnson & Son, Inc. 04/19/2000 607 PROVON Enriched Lotion Cleanser GOJO Industries, Inc. 02/10/2015 610 PVC PRIMER PURPLE 16 OZ Oatey Corp 01/05/1999 621 Quaker State Advanced Durability SAE 5W-30 Motor Oil SOPUS Products 04/18/2011 625 Quaker State Advanced Durability SAE 5W-30 Motor Oil SOPUS Products 03/13/2013 633 RAID ANT & ROACH KILLER (AEROSOL) S.C. Johnson & Son, Inc. 06/12/1995 642 Roadrunner Ice Melting Compound SCOTWOOD INDUSTRIES, INC. 05/01/1999 646 Roundup Weed & Grass Killer Concentrate Plus Monsanto Company, Lawn & Garden Products 05/13/2015 648 Roundup Weed Grass Killer Ready-To-Use Plus Monsanto Company, Lawn & Garden Products 05/28/2004 658 Rust Oleum American Accents Decorative Paint Pens Rust-Oleum Corporation 08/30/2007 667 Rust-Oleum Professional Inverted Marking Paint Aerosol Rust-Oleum Corporation 03/27/2009 673 Rustoleum spray paint 745 Rust-Oleum Corporation - Industrial Coatings 12/16/2004 679 Safe Step Ice Melter Compass Minerals Group 10/30/2008 685 SCOTCHGARD TILE AND GROUT PROTECTOR 3M Building & Commercial Services Division 08/03/2011 691 SCOTCHGARD TILE AND GROUT PROTECTOR 3M - Building & Commercial Services Division 08/03/2011 699 Product Name CAS Number Manufacturer Version Date Page Page 7 of 878 Page 7 of 878 Page 7 of 878 Page 7 of 878 ---PAGE BREAK--- SEA FOAM Akzo Nobel - Awlgrip North America 09/23/2004 707 Sea Foam Motor Treatment SEA FOAM SALES CO 01/26/2006 711 SHEETROCK All Purpose Joint Compound USG INTERIORS, INC. 03/27/1998 713 SHINE-UP (LEMON - AEROSOL) S. C. Johnson & Son, Inc. 04/17/1997 717 SIGN OFF Spartan Chemical Company 03/25/2008 723 Simple Green Industrial Cleaner & Degreaser Sunshine Makers, Inc. 07/31/2015 726 Sonolastic NP1 BASF Construction Chemicals Australia 11/22/2006 730 SPARCLING Spartan Chemical Company 06/01/2013 734 Stainless Steel Polish Dalco 11/01/2012 737 STATIC GUARD ANTISTATIC SPRAY Alberto-Culver USA, Inc. 03/03/2010 738 STERIPHENE II BRAND DISINFECTANT DEODORANT Spartan Chemical Company 09/22/2008 743 Stride Citrus HC 3 Neutral Cleaner Diversey, Inc. 08/19/2014 747 STRIDE CITRUS SC NEUTRAL CLEANER Johnson Wax Professional 08/02/2001 752 STRIDE FLORAL SC (SUPER CONCENTRATE) JohnsonDiversey 04/27/2009 756 SUN BRITE BLEACH Sunburst Chemical, Inc. 07/19/2007 759 SUPER IRON OUT IRON OUT, INC. 08/22/2008 761 SUPERIOR HIGH SHINE STAINLESS STEEL CLEANER & POLISH (AEROSOL) Spartan Chemical Company 06/08/2009 768 TANNIN STAIN REMOVER S. C. Johnson & Son, Inc. 01/17/2001 772 TECH STAIN REMOVER TECH ENTERPRISES INC 12/12/2014 776 TECH STAIN REMOVER TECH ENTERPRISES INC 01/01/2013 778 TECH STAIN REMOVER TECH ENTERPRISES INC 01/01/2010 780 Terro Multi-Purpose Insect Bait SENORET CHEMICAL CO INC 09/04/2012 782 TFE Paste William H. Harvey Company 01/08/2010 785 TFE Paste William H. Harvey Company 01/08/2010 790 Thread Guard BALMAR LLC 06/28/2007 795 THRUST SULFURIC ACID DRAIN OPENER 7664-93-9 RICMAR INDUSTRIES 07/01/1996 796 TNT FOAMING DISINFECTANT CLEANER Spartan Chemical Company 06/01/2007 797 TOMCAT BAIT STATIONS Motomco LTD 04/09/2008 799 Top Down Aerosol, O/G CERTIFIED LABS - DIVISION OF 01/29/2008 801 Product Name CAS Number Manufacturer Version Date Page Page 8 of 878 Page 8 of 878 Page 8 of 878 Page 8 of 878 ---PAGE BREAK--- NCH CORPORATION TOP DOWN AEROSOL, O/G CHEMSEARCH - A DIVISION OF NCH CORPORATION 09/28/2001 805 TOUCH OF SCENT AIR FRESHENER (All Fragrances) SCOTTS LIQUID GOLD INC 03/11/2004 809 TRIAD II DISINFECTANT CLEANER Johnson Wax Professional 03/01/2006 811 Triad III JohnsonDiversey 06/07/2007 814 Ultra Dawn Power Plus, Ultra Dawn Plus Hand Care, Ultra Dawn Oxi, Ultra Dawn with Bleach Alternative (Mountain Spring, Fresh Rapids), Dawn Complete (Original Scent, Apple Blossom, Floral Scent, Antibacterial Hand Soap) Procter & Gamble - Household Care 09/02/2006 815 UNITED 101 MOISTURE BARRIER United Laboratories Inc. 02/06/2015 819 UNITED 107 AEROSOL SAFETY SOLVENT United Laboratories Inc. 06/03/2015 821 UNITED 107 AEROSOL SAFETY SOLVENT United Laboratories Inc. 02/21/2012 822 UNITED 125 ALL STIK United Laboratories Inc. 02/06/2015 824 UNITED 125 ALL STIK United Laboratories Inc. 06/26/2015 826 United 231 VANISHING ACT Industrial Strength Spot and Stain Remover United Laboratories Inc. 09/10/2003 827 UNITED 50 PINK MARVEL United Laboratories Inc. 02/16/2012 829 UNITED 50 PINK MARVEL United Laboratories Inc. 04/03/2015 831 Valvoline Super HPO SAE 40 API SL 8012-95-1 Raloy Lubricantes, SA de CV 12/18/2007 832 Varathane Wood Filler Tubes Rust-Oleum Corporation 02/04/2005 837 Victor Lock De-icer Ultramotive Corporation 08/20/2007 842 Vinyl Spackling Compound Red Devil, Inc. 03/06/2012 854 Water Wash Brush Cleaner WILSON IMPERIAL CO 10/13/1993 857 WET TASK Wiping Products - EXEMPT LETTER Kimberly-Clark Corporation 10/02/2001 861 WHITE LIGHTNING 3006 ULTRA All Purpose Elastomeric Sealant, Almond Sherwin-Williams Company 03/12/2009 862 WHITE LIGHTNING FLAME BUSTER Intumescent Silicone Sealant Sherwin-Williams Company - Consumer Group - Industrial 03/20/2015 866 Windshield De-Icer Lawson Products, Inc. 10/30/2014 870 Woolite Heavy Traffic Carpet Cleaner - with FibraPure PLAYTEX PRODUCTS INC 01/29/2002 874 Xtra Duty Stripper Dalco 02/01/2003 878 Product Name CAS Number Manufacturer Version Date Page Page 9 of 878 Page 9 of 878 Page 9 of 878 Page 9 of 878 ---PAGE BREAK--- Page 10 of 878 Page 10 of 878 Page 10 of 878 Page 10 of 878 ---PAGE BREAK--- Page 11 of 878 Page 11 of 878 Page 11 of 878 Page 11 of 878 ---PAGE BREAK--- MSDS for 106 MoorGard 100% Acrylic Low Lustre Latex House Paint Page 1 of 4 http://www.benjaminmoore.com/msds/MSDS/106.html 12/31/98 M A T E R I A L S A F E T Y D A T A S H E E T Rev 10600.01B For Coating, Resins, and Related Materials NPCA 1-84 MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. BENJAMIN MOORE & Co. [PHONE REDACTED] (CHEMTREC) 51 CHESTNUT RIDGE RD. MONTVALE, NJ 07645 DATE OF PREPARATION INFORMATION TELEPHONE 04-MAY-98 [PHONE REDACTED] SECTION I - PRODUCT ID HMIS CODE SARA TITLE 312 PRODUCT CODE: 106 I I I Acute: NO I CLASS: WATER THINNED PAINT I Health: 1* I I Chronic: YES I NAME: MOORGARD 100% ACRYLIC LATEX I Flammability: 0 I I Fire: NO I HOUSE PAINT I Reactivity: 0 I I Pressure: NO I COLOR: ALL I Personal Prot.: I I React: NO I For a complete description of HMIS and an explanation of the PERSONAL PROT: code, see Section XX. SECTION II - HAZARDOUS INGREDIENTS INGREDIENT MAX PCT CAS NO. TLV PEL STEL CEIL MM Hg TEMP Zinc Oxide (f*3n) 2.5 1314132 10mg/m3 10mg/m3 N/E N/E N/A Titanium Dioxide (f*n) 18.3 13463677 10mg/m3 10mg/m3 N/E N/E N/A Silica, 13.9 14808607 (f*n) .1mg/m3 .1mg/m3 N/E N/E N/A Silica, Amorphous 5.7 7631869 (f*n) 10mg/m3 6mg/m3 N/E N/E N/A Diatomaceous Earth (f*n) 1.2 61790532 10mg/m3 5mg/m3 N/E N/E N/A f Federal Hazard List * Hazardous only as dust when product is sanded. 3 Sect. 313 of the Emergency Planning & Community Right-To-Know Act of 1986 and of 40 CFR 37 n New Jersey Label Law hazardous chemical This product may contain small amounts of materials known to the State of California to cause cancer and reproductive harm. SECTION III - PHYSICAL DATA BOILING RANGE: N/A VAPOR DENSITY: HEAVIER THAN AIR WEIGHT PER GAL: 9.7 - 10.8 EVAPORATION RATE: SLOWER THAN ETHER % VOLATILE VOLUME: 64.4 - 68.3 Page 12 of 878 Page 12 of 878 Page 12 of 878 Page 12 of 878 ---PAGE BREAK--- MSDS for 106 MoorGard 100% Acrylic Low Lustre Latex House Paint Page 2 of 4 http://www.benjaminmoore.com/msds/MSDS/106.html 12/31/98 SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION: NOT REGULATED FLASH PT.: >250 F PMCC LEL: Not Applicable EXTINGUISHING MEDIA: FOAM CO2 DRY CHEMICAL WATER FOG UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may burst if exposed to extreme heat or fire. Toxic gases may form when product burns. SPECIAL FIREFIGHTING PROCEDURES: Cool exposed containers with water. Use self-contained breathing apparatus. SECTION V - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE - ACUTE: Inhalation - Causes nose and throat irritation. Inhalation - Causes lung irritation. Skin and Eye Contact - Primary irritation. Contact - Causes skin irritation. Ingestion of large amounts could cause serious injury. EFFECTS OF OVEREXPOSURE - CHRONIC: Skin Contact - Prolonged or repeated exposure may cause dermatitis. Chronic lung conditions may be aggravated by exposure to high dust levels. Inhalation statement: Sanding dust inhalation may cause lung damage. Contains - Silica which has been determined to be carcinogenic to humans by IARC when in respirable form. Risk of cancer depends on duration and level of inhalation exposure to dust from sanding the dried paint or spray mist. MEDICAL CONDITIONS PRONE TO AGGRAVATION BY EXPOSURE: None expected when used in accordance with Safe Handling and Use Information (Section VIII). PRIMARY ROUTE(S) OF ENTRY: DERMAL INHALATION INGESTION EMERGENCY AND FIRST AID PROCEDURES: Inhalation - Remove to fresh air. Get medical help for any breathing difficulty. Eye Contact - Flush thoroughly with water. Call physician. Skin Contact - Wash with soap and water. Ingestion - Drink 1 or 2 glasses of water to dilute. Do NOT induce vomiting. Call physician. SECTION VI - REACTIVITY DATA STABILITY: STABLE HAZARDOUS POLYMERIZATION WILL NOT OCCUR CONDITIONS TO AVOID: Elevated Temperatures HAZARDOUS DECOMPOSITION PRODUCTS: Burning may produce carbon dioxide and carbon monoxide. INCOMPATIBILITY (MATERIALS TO AVOID): None reasonably foreseeable. SECTION VII - SPILL OR LEAK PROCEDURES Page 13 of 878 Page 13 of 878 Page 13 of 878 Page 13 of 878 ---PAGE BREAK--- MSDS for 106 MoorGard 100% Acrylic Low Lustre Latex House Paint Page 3 of 4 http://www.benjaminmoore.com/msds/MSDS/106.html 12/31/98 STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Flush with water. Absorb with sawdust or rags. WASTE DISPOSAL METHOD: Conventional procedures in compliance with local, state and federal regulations. Do not incinerate sealed containers. SECTION VIII - SAFE HANDLING AND USE INFORMATION RESPIRATORY PROTECTION: Use NIOSH approved respirator specified for protection against paint spray mist and sanding dust in restricted or confined areas. VENTILATION: Adequate to maintain working atmosphere below T.L.V. and L.E.L. (See Sect. II for ingredient data and concentrations). Mechanical exhaust may be required in confined areas. PROTECTIVE GLOVES: Waterproof during repeated contact. EYE PROTECTION: Splash goggles or safety glasses with side shields. OTHER PROTECTIVE EQUIPMENT: Clothing adequate to protect skin. HYGIENIC PRACTICES: Remove and wash clothing before reuse. Wash hands before eating, smoking or using the washroom. SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Do not throw or drop containers. OTHER PRECAUTIONS: Avoid contact with eyes and prolonged contact with skin or breathing of spray mist or sanding dust. Close container after each use. Keep out of reach of children. Do not take internally. SECTION XX HMIS (Hazardous Materials Identification System) NPCA HMIS is a recognized workplace Hazard Communications System as required by OSHA (40 CFR 1910. 1200). Information on establishing a compliant hazardous communication program using HMIS is available from: American Labelmark Co., Inc., Labelmaster Division 5724 N. Pulaski Rd., Chicago, IL 60646 1-[PHONE REDACTED] The ratings assigned by Benjamin Moore & Co. are only suggested ratings; the contractor/employer has ultimate responsibility for HMIS rating where this system is used. PERSONAL PROTECTION: This code is left blank on Benjamin Moore & Co. MSDS's as it depends on application technique and the workplace ventilation. Please read Sections II through IX of this MSDS before deciding on appropriate Page 14 of 878 Page 14 of 878 Page 14 of 878 Page 14 of 878 ---PAGE BREAK--- MSDS for 106 MoorGard 100% Acrylic Low Lustre Latex House Paint Page 4 of 4 http://www.benjaminmoore.com/msds/MSDS/106.html 12/31/98 protective equipment and beginning work. There are codes available for this section which can be obtained from Labelmaster. This product contains at least one toxic chemical listed in Section II that is subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To- Know Act of 1986 and 40 CR 372. Page 15 of 878 Page 15 of 878 Page 15 of 878 Page 15 of 878 ---PAGE BREAK--- MSDS for 137 Moore¹s Weatherproof Aluminum Paint Page 1 of 4 http://www.benjaminmoore.com/msds/MSDS/137.html 12/31/98 M A T E R I A L S A F E T Y D A T A S H E E T Rev 13700.03B For Coating, Resins, and Related Materials NPCA 1-84 MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. BENJAMIN MOORE & Co. [PHONE REDACTED] (CHEMTREC) 51 CHESTNUT RIDGE RD. MONTVALE, NJ 07645 DATE OF PREPARATION INFORMATION TELEPHONE 15-DEC-97 (Sup. 01-SEP-90) [PHONE REDACTED] SECTION I - PRODUCT ID HMIS CODE SARA TITLE 312 PRODUCT CODE: 137,C137 I I I Acute: YES I CLASS: SOLVENT THINNED PAINT I Health: 2* I I Chronic: YES I NAME: WEATHERPROOF ALUMINUM PAINT I Flammability: 2 I I Fire: YES I COLOR: ALL I Reactivity: 1 I I Pressure: NO I I Personal Prot.: I I React: NO I For a complete explanation of HMIS and a description of the PERSONAL PROT: code, see Section XX. SECTION II - HAZARDOUS INGREDIENTS INGREDIENT MAX PCT CAS NO. TLV PEL STEL CEIL MM Hg TEMP Aluminum (f3n) 13.4 7429905 10mg/m3 15mg/m3 N/E N/E N/A Stoddard Solvent (fn) 57.8 8052413 100ppm 100ppm N/E N/E 2.0 @ 20 C Coumarone Indene Resin 10.4 63393895 10mg/m3 10mg/m3 N/E N/E N/A 1,2,4 1.0 95636 (f3n) 25ppm 25ppm N/E N/E N/A f Federal Hazard List * Hazardous only as dust when product is sanded. 3 Sect. 313 of the Emergency Planning & Community Right-To-Know Act of 1986 and of 40 CFR 37 n New Jersey Label Law hazardous chemical This product may contain small amounts of materials known to the State of California to cause cancer and reproductive harm. SECTION III - PHYSICAL DATA BOILING RANGE: 315- 395 F VAPOR DENSITY: HEAVIER THAN AIR WEIGHT PER GAL: 7.7 - 7.9 EVAPORATION RATE: SLOWER THAN ETHER % VOLATILE VOLUME: 65.0 - 72.8 Page 16 of 878 Page 16 of 878 Page 16 of 878 Page 16 of 878 ---PAGE BREAK--- MSDS for 137 Moore¹s Weatherproof Aluminum Paint Page 2 of 4 http://www.benjaminmoore.com/msds/MSDS/137.html 12/31/98 SECTION IV - FIRE AND EXPLOSION HAZARD DATA D.O.T. FLAMMABILITY CLASSIFICATION: COMBUSTIBLE FLASH PT.: 107 F PMCC LEL: 1.0% EXTINGUISHING MEDIA: FOAM CO2 DRY CHEMICAL WATER FOG UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may burst if exposed to extreme heat or fire. Toxic gases may form when product burns. SPECIAL FIREFIGHTING PROCEDURES: Do not use water stream on burning liquid. Cool exposed containers with water. Use self-contained breathing apparatus. SECTION V - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE - ACUTE: Inhalation - Harmful if inhaled. May affect the brain or nervous system, causing dizziness, headache or nausea. Contact - Causes eye irritation. Contact - Causes skin irritation. Skin Absorption - Hazardous ingredients contained in this product have the capacity to be absorbed in sufficient quantities to cause systemic toxicity. See Safe Handling and Use Information (Section VIII). Ingestion - Irritation of the digestive tract and nervous system depression (drowsiness, dizziness, loss of coordination and fatigue). Aspiration Hazard - This material can enter lungs during swallowing or vomiting and cause lung inflammation and damage. Hazard - This material can enter lungs during swallowing or vomiting and cause lung inflammation and damage. EFFECTS OF OVEREXPOSURE - CHRONIC: Skin Contact - Prolonged or repeated exposure may cause dermatitis. NOTICE: Reports have associated permanent brain and nervous system damage with repeated, prolonged overexposure to solvents among persons engaged in the painting trade. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. MEDICAL CONDITIONS PRONE TO AGGRAVATION BY EXPOSURE: None expected when used in accordance with Safe Handling and Use Information (Section VIII). PRIMARY ROUTE(S) OF ENTRY: DERMAL INHALATION INGESTION EMERGENCY AND FIRST AID PROCEDURES: Inhalation - Remove from hazard area, maintain breathing, call physician. Skin Contact - Remove with soap and water. Eye Contact - Flush immediately with large amounts of water. Call physician. Ingestion - Drink 1 or 2 glasses of water to dilute. Do NOT induce vomiting. Call physician. SECTION VI - REACTIVITY DATA STABILITY: STABLE HAZARDOUS POLYMERIZATION WILL NOT OCCUR HAZARDOUS DECOMPOSITION PRODUCTS: Burning may produce carbon dioxide and carbon monoxide. CONDITIONS TO AVOID: Elevated temperatures and build up of vapors. INCOMPATIBILITY (MATERIALS TO AVOID): None reasonably foreseeable. Page 17 of 878 Page 17 of 878 Page 17 of 878 Page 17 of 878 ---PAGE BREAK--- MSDS for 137 Moore¹s Weatherproof Aluminum Paint Page 3 of 4 http://www.benjaminmoore.com/msds/MSDS/137.html 12/31/98 SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition. Avoid breathing vapors. Use non-sparking tools to return materials to container. Absorb residue with Fuller's earth. WASTE DISPOSAL METHOD: Conventional procedures in compliance with local, state and federal regulations. Do not incinerate sealed containers. SECTION VIII - SAFE HANDLING AND USE INFORMATION RESPIRATORY PROTECTION: Wear a properly fitted vapor/particulate approved by NIOSH/MSHA for use with paints (TC-23C) during application or sanding and until all vapors and spry mist are exhausted. In confined spaces or in situations where continuous spray operations are typical, or if proper respirator fit is not possible, wear a positive-pressure, supplied air respirator (NIOSH/MSHA TC-19C). VENTILATION: Adequate to maintain working atmosphere below T.L.V. and L.E.L. (See Sect. II for ingredient data and concentrations). Mechanical exhaust may be required in confined areas. Discharge exhaust only in area away from ignition sources. PROTECTIVE GLOVES: Solvent impermeable gloves are required during repeated contact. EYE PROTECTION: Splash goggles or safety glasses with side shields. OTHER PROTECTIVE EQUIPMENT: Clothing adequate to protect skin. HYGIENIC PRACTICES: Remove and wash clothing before reuse. Wash hands before eating, smoking or using the washroom. SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Combustible - Keep away from heat and flame. OTHER PRECAUTIONS: Use only with adequate ventilation. Avoid prolonged contact with skin and breathing of vapor spray mist or sanding dust. Close container after each use. Keep out of reach of children. Do not take internally. SECTION XX HMIS (Hazardous Materials Identification System) NPCA HMIS is a recognized workplace Hazard Communications System as required by OSHA (40 CFR 1910.1200). Information on establishing a compliant hazardous communication program using HMIS is available from: American Lablemark Co., Inc., Labelmaster Division 5724 N. Pulaski Rd., Chicago, IL 60646 1-[PHONE REDACTED] Page 18 of 878 Page 18 of 878 Page 18 of 878 Page 18 of 878 ---PAGE BREAK--- MSDS for 137 Moore¹s Weatherproof Aluminum Paint Page 4 of 4 http://www.benjaminmoore.com/msds/MSDS/137.html 12/31/98 The ratings assigned by Benjamin Moore & Co. are only suggested ratings; the contractor/ employee has ultimate responsibility for HMIS rating where this system is used. PERSONAL PROTECTION: This code is left blank on Benjamin Moore & Co. MSDS's as it depends on application technique and the workplace ventilation. Please read Sections II through IX of this MSDS before deciding on appropriate protective equipment and beginning work. There are codes available for this section which can be obtained from Labelmaster. Note: There are no SARA reportable materials in this product. Page 19 of 878 Page 19 of 878 Page 19 of 878 Page 19 of 878 ---PAGE BREAK--- Page 20 of 878 Page 20 of 878 Page 20 of 878 Page 20 of 878 ---PAGE BREAK--- Page 21 of 878 Page 21 of 878 Page 21 of 878 Page 21 of 878 ---PAGE BREAK--- Page 22 of 878 Page 22 of 878 Page 22 of 878 Page 22 of 878 ---PAGE BREAK--- Page 23 of 878 Page 23 of 878 Page 23 of 878 Page 23 of 878 ---PAGE BREAK--- Page 24 of 878 Page 24 of 878 Page 24 of 878 Page 24 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 04/06/09 Page 1 of 9 Material Safety Data Sheet Copyright, 2009, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: the information is copied in full with no changes unless prior written agreement is obtained from 3M, and neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) MANUFACTURER: 3M DIVISION: Construction and Home Improvement Markets ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-[PHONE REDACTED] or (651) 737-6501 (24 hours) Issue Date: 04/06/09 Supercedes Date: 06/11/08 Document Group: 22-4025-7 Product Use: Intended Use: Adhesive aerosol Specific Use: General Purpose Aerosol adhesive SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt NON-VOLATILE COMPONENTS (NJ TRADE SECRET # 04499600-6433P) Trade Secret 20 - 30 ACETONE 67-64-1 20 - 30 PROPANE 74-98-6 15 - 25 107-83-5 10 - 20 96-14-0 3 - 7 CYCLOHEXANE 110-82-7 3 - 7 75-83-2 1 - 3 79-29-8 1 - 3 HEXANE 110-54-3 < 0.8 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Aerosol Odor, Color, Grade: clear, sweet fruity odor Page 25 of 878 Page 25 of 878 Page 25 of 878 Page 25 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 04/06/09 Page 2 of 9 General Physical Form: Gas aerosol Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains flammable material under pressure. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Moderate Eye Irritation: may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Prolonged or repeated exposure may cause: Mild Skin Irritation: may include localized redness, swelling, and itching. Inhalation: Intentional concentration and inhalation may be harmful or fatal. Respiratory Tract Irritation: may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Peripheral Neuropathy: may include tingling or numbness of the extremities, incoordination, weakness of the hands and feet, tremors and muscle atrophy. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. SECTION 4: FIRST AID MEASURES Page 26 of 878 Page 26 of 878 Page 26 of 878 Page 26 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 04/06/09 Page 3 of 9 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If persist, get medical attention. Skin Contact: Wash affected area with soap and water. If develop, get medical attention. Inhalation: Remove person to fresh air. If develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point -42.00 ºF [Test Method: Tagliabue Closed Cup] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available OSHA Flammability Classification: Class IA Flammable Liquid 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains flammable material under pressure. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-[PHONE REDACTED]) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non- sparking tools. Ventilate the area with fresh air. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate organic solvent. Read and follow safety precautions on the solvent label and MSDS. Place in a metal container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. Page 27 of 878 Page 27 of 878 Page 27 of 878 Page 27 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 04/06/09 Page 4 of 9 SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Do not pierce or burn container, even after use. No smoking while handling this material. Do not spray near flames or sources of ignition. Avoid breathing of vapors, mists or spray. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Vapors may ignite explosively. May cause flash fire. Prevent build-up of vapors - open all windows and doors. Maintain vapor concentrations below recommended exposure limits. Use only with cross- ventilation. Without adequate ventilation, vapors may settle in low-lying areas. Keep away from heat, sparks, and open flame. Do not smoke or ignite matches, lighters, etc. 7.2 STORAGE Store away from acids. Store away from heat. Store out of direct sunlight. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Use in an enclosed process area is recommended. Use with functioning spray booth or local exhaust. Use in a well-ventilated area. If exhaust ventilation is not available, use appropriate respiratory protection. Do not use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. Do not use in a confined area or areas with little or no air movement. If exhaust ventilation is not adequate, use appropriate respiratory protection. Provide ventilation adequate to control vapor concentrations below recommended exposure limits and/or control spray or mist. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields. 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Polyethylene/Ethylene Vinyl Alcohol. 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges. Consult the current 3M Respiratory Selection Guide for additional information or call 1-[PHONE REDACTED] for 3M technical assistance. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information Page 28 of 878 Page 28 of 878 Page 28 of 878 Page 28 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 04/06/09 Page 5 of 9 ACETONE ACGIH TWA 500 ppm Table A4 ACETONE ACGIH STEL 750 ppm Table A4 ACETONE OSHA TWA, Vacated 750 ppm ACETONE OSHA TWA 1000 ppm Table Z-1 ACETONE OSHA STEL, Vacated 1000 ppm CYCLOHEXANE ACGIH TWA 100 ppm CYCLOHEXANE OSHA TWA 300 ppm Table Z-1 HEXANE ACGIH TWA 50 ppm Skin Notation* HEXANE OSHA TWA, Vacated 50 ppm Table Z-1A HEXANE OSHA TWA 500 ppm Table Z-1A HEXANE (ISOMERS OTHER THAN N- HEXANE) ACGIH TWA 500 ppm HEXANE (ISOMERS OTHER THAN N- HEXANE) ACGIH STEL 1000 ppm PROPANE ACGIH TWA 1000 ppm PROPANE OSHA TWA 1000 ppm Table Z-1 * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local regulatory agency. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Aerosol Odor, Color, Grade: clear, sweet fruity odor General Physical Form: Gas aerosol Autoignition temperature No Data Available Flash Point -42.00 ºF [Test Method: Tagliabue Closed Cup] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available Boiling point Not Applicable Vapor Density 2.97 [Ref Std: AIR=1] Specific Gravity 0.726 [Ref Std: WATER=1] pH No Data Available Melting point No Data Available Solubility in Water Nil Evaporation rate 1.90 [Ref Std: ETHER=1] Hazardous Air Pollutants 0.4 % weight [Test Method: Calculated] Hazardous Air Pollutants 0.016 lb HAPS/lb solids Hazardous Air Pollutants 0.02 lb HAPS/gal [Test Method: Calculated] Volatile Organic Compounds Approximately 51 % [Test Method: calculated SCAQMD rule 443.1] Page 29 of 878 Page 29 of 878 Page 29 of 878 Page 29 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 04/06/09 Page 6 of 9 Percent volatile <=75 % weight VOC Less H2O & Exempt Solvents 468 g/l Viscosity Not Applicable SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: Heat Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Aldehydes During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate uncured product in a permitted hazardous waste incinerator. Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. The facility should be equipped to handle gaseous waste. Facility must be capable of handling aerosol cans. Dispose of empty product containers in a sanitary landfill. RECYCLE EMPTY AEROSOL CONTAINERS WHERE AVAILABLE. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) Since regulations vary, consult applicable regulations or authorities before disposal. Page 30 of 878 Page 30 of 878 Page 30 of 878 Page 30 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 04/06/09 Page 7 of 9 SECTION 14:TRANSPORT INFORMATION ID Number(s): LN-A100-0323-8, LN-A100-0323-9, LN-A100-0324-0, 62-4977-4030-8, 62-4977-4920-0, 62-4977-4926-7, 62-4977-4977-0, 70- 0714-1653-4, 70-0714-1654-2, 70-0714-1656-7, 70-0714-7444-2, 70-0714-7572-0, 70-0714-7640-5, 70-0714-7930-0, 70-0714-8259- 3, 70-0714-8947-3 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt CYCLOHEXANE 110-82-7 3 - 7 STATE REGULATIONS Contact 3M for more information. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. INTERNATIONAL REGULATIONS This material contains one or more ingredients that may be regulated by the International Traffic in Arms Regulation (ITAR), an export control of US military technology and chemicals. Prior to export of this material or any product containing this material, Page 31 of 878 Page 31 of 878 Page 31 of 878 Page 31 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 04/06/09 Page 8 of 9 determine whether a proper license from the Department of State must be obtained. See 22CFR 120-130 for any specific requirements. Contact 3M for more information. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 2 Flammability: 4 Reactivity: 0 Special Hazards: None Aerosol Storage Code: 3 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 2 Flammability: 4 Reactivity: 0 Protection: X - See PPE section. Hazardous Material Identification System (HMIS(r)) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mark of the National Paint and Coatings Association (NPCA). Revision Changes: Section 1: Division name was modified. Copyright was modified. Section 2: Ingredient table was modified. Section 15: TSCA section 12[b] text was deleted. Section 15: TSCA section 12[b] information was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M are available at www.3M.com Page 32 of 878 Page 32 of 878 Page 32 of 878 Page 32 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 04/06/09 Page 9 of 9 Page 33 of 878 Page 33 of 878 Page 33 of 878 Page 33 of 878 ---PAGE BREAK--- Page 34 of 878 Page 34 of 878 Page 34 of 878 Page 34 of 878 ---PAGE BREAK--- Page 35 of 878 Page 35 of 878 Page 35 of 878 Page 35 of 878 ---PAGE BREAK--- Page 36 of 878 Page 36 of 878 Page 36 of 878 Page 36 of 878 ---PAGE BREAK--- Page 37 of 878 Page 37 of 878 Page 37 of 878 Page 37 of 878 ---PAGE BREAK--- Page 38 of 878 Page 38 of 878 Page 38 of 878 Page 38 of 878 ---PAGE BREAK--- Page 39 of 878 Page 39 of 878 Page 39 of 878 Page 39 of 878 ---PAGE BREAK--- Page 40 of 878 Page 40 of 878 Page 40 of 878 Page 40 of 878 ---PAGE BREAK--- Page 41 of 878 Page 41 of 878 Page 41 of 878 Page 41 of 878 ---PAGE BREAK--- Page 42 of 878 Page 42 of 878 Page 42 of 878 Page 42 of 878 ---PAGE BREAK--- Page 43 of 878 Page 43 of 878 Page 43 of 878 Page 43 of 878 ---PAGE BREAK--- Page 44 of 878 Page 44 of 878 Page 44 of 878 Page 44 of 878 ---PAGE BREAK--- No flash to 212°F LEL NA UEL NA Water spray (fog), foam, dry chemical, carbon dioxide Blanket fire with extinguishing medium Water or foam may cause frothing Undetermined SECTION II - INGREDIENTS FORMULA COMPLETED BY TITLE DATE SECTION I MANUFACTURED BY PHONE NUMBER PRODUCT NAME AERO® INSTANT FOAMING HAND SANITIZER THIS PRODUCT IS MANUFACTURED AND LABELED IN COMPLIANCE WITH THE FEDERAL FOOD, DRUG, AND COSMETIC ACT, AND IS EXEMPT FROM THE LABELING REQUIREMENTS OF THE OSHA HAZARD COMMUNICATION STANDARD. ALL PRODUCT INGREDIENTS ARE LISTED BELOW. SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS SECTION IV - FIRE AND EXPLOSION DATA BOILING POINT VAPOR PRESSURE (mmHg) VAPOR DENSITY (Air = 1) SOLUBILITY IN WATER APPEARANCE & ODOR FLASH POINT (Method Used) FLAMMABLE LIMITS EXTINGUISHING MEDIA SPECIAL FIRE FIGHTING PROCEDURES UNUSUAL FIRE AND EXPLOSION HAZARDS 56111 DEB SBS, INC. CHEMIST May 30, 2006 DEB SBS INC. 1100 HIGHWAY 27 SOUTH STANLEY, NC 28164 (704) 263-4240 SPECIFIC GRAVITY (H 0 = 1) MELTING POINT EVAPORATION RATE (Butyl Acetate = 1) pH 2 1.003 NA NA 6.5-7.5 212°F NA NA Complete Light purple, thin liquid with pleasant odor MATERIAL SAFETY DATA SHEET (Essentially Similar to Form OSHA-174) While the information and recommendations set forth herein are believed to be accurate as of the date hereof, DEB SBS Inc. makes no warranty with respect thereto and disclaims all liability from reliance thereon. ACTIVE INGREDIENTS CAS NUMBER WEIGHT, % Alkyl Dimethyl Benzyl Ammonium Chloride 68424-85-1 0.24 OTHER INGREDIENTS Water, D.I. 7732-18-5 Cocamidopropyl Betaine 61789-40-0 Propylene Glycol 57-55-6 Amine Oxide 68155-09-9 Tetrasodium EDTA 64-02-8 Citric Acid 77-92-9 Aloe Vera 8001-97-6 26172-55-4 Methylisothiazolinone 2682-20-4 FD&C Blue #1 3844-45-9 FD&C Red #33 3567-66-6 Fragrance Page 45 of 878 Page 45 of 878 Page 45 of 878 Page 45 of 878 ---PAGE BREAK--- UNSTABLE STABLE X Oxidizing Agents Undetermined MAY OCCUR WILL NOT OCCUR X STABILITY INCOMPATIBILITY (Materials to Avoid) HAZARDOUS DECOMPOSITION OR BY-PRODUCTS HAZARDOUS POLYMERIZATION SECTION V - REACTIVITY DATA SECTION VI - HEALTH HAZARD DATA CONDITIONS TO AVOID CONDITIONS TO AVOID None known None known Routes of Entry: Skin, Ingestion Health Hazards: Skin: Excessive contact may cause temporary dryness. Eyes: Temporary irritation. Ingestion: If digested in large quantity, product may cause diarrhea. Emergency and first aid procedures: Skin: Apply moisturizing cream. Eyes: Immediately flush eyes with clean water while holding eyelids apart. Continue flushing for at least 15 minutes or until irritation subsides. Contact doctor. Ingestion: Do not induce vomiting. Give large amount of water. Get medical attention. MATERIAL SAFETY DATA SHEET - AERO® INSTANT , side 2 SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED WASTE DISPOSAL METHOD SPECIAL PRECAUTIONS FOR HANDLING AND STORAGE SECTION VIII - CONTROL MEASURES SPECIAL RESPIRATORY PROTECTION SPECIAL SKIN PROTECTION SPECIAL EYE PROTECTION Wipe up Discard with ordinary liquid wastes. Comply with all government waste disposal regulations. None required None required None required None required Page 46 of 878 Page 46 of 878 Page 46 of 878 Page 46 of 878 ---PAGE BREAK--- Spartan Chemical Company, Inc. Material Safety Data Sheet SECTION I: PRODUCT INFORMATION Product Name or Number (as it appears on label): Product Division: AIRLIFT FRESH SCENT AIR FRESHENER (AEROSOL) Product Number: 6095 Janitorial Spartan Chemical Company , Inc. Product/Technical Information: 1-(800)-537-8990 1110 Spartan Drive Medical Emergency: 1-(888)-314-6171 (24 hours) Maumee, OH 43537 Chemical Leak/Spill Emergency: CHEMTREC 1-(800) 424-9300 (24 hours) Shipping Description: ORM-D, Consumer Commodity NFPA Ratings: HMIS Ratings: Health: 1- Slight Health: *1 - Slight; Chronic Hazard Fire: 1- Slight Fire: 1- Slight Reactivity: 0 - Minimal Reactivity: 0 - Minimal Pers. Prot. Equip.: See Section VIII SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1% or greater, carcinogens at 0.1% or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. Table Z-1-A Chemical Name(s) %Wt CAS Registry No. TWA mg/m 3 STEL mg/m 3 CEILING mg/m 3 NTP, IARC or OSHA Carcinogen Liquified petroleum gas Petroleum distillates Petroleum distillates 15-20 5-10 1-5 68476-85-7 64742-47-8 64741-65-7 1800 1200 (Exxon) *2900 *525 (ACGIH) Not Established Not Established Not Established Not Established Not Established *1800 (NIOSH) No No No Comment: * Limits for Stoddard Solvent - to be used as a guide only. SECTION III: PHYSICAL DATA Boiling Point: N/A Vapor Pressure: Unknown Vapor Density (AIR = Heavier than air. Solubility in Water: Emulsifiable pH: 6.0-8.0 Specific Gravity (H2O=1): Unknown Evaporation Rate (but.ace.=1): <1 Percent Solid by Weight: Unknown Physical State: Aerosol can (pressurized liquid) Appearance & Odor: "Fresh" fragrance SECTION IV: FIRE & EXPLOSIVE HAZARD DATA Flash Point: None Method Used: Estimate Flammable Limits: Not Established Explosive Limits: Lower: 1.0% Upper: 9.5% Flame Extension: 0 Inches NFPA 30B Level 1 Aerosol Extinguishing Media: Carbon dioxide, Dry chemical, Water fog, Foam Special Fire Fighting Procedures: Water may be used to cool closed containers to prevent pressure build-up and possible venting or rupturing when exposed to extreme heat. Wear NIOSH approved self-contained breathing apparatus and protective clothing. Unusual Fire & Explosive Hazards: Material gives off vapors which may travel along the ground and be ignited by pilot lights or other sources of ignition. At elevated temperatures (over 120°F/ 49°C ) containers may vent, rupture or burst. Page 47 of 878 Page 47 of 878 Page 47 of 878 Page 47 of 878 ---PAGE BREAK--- SECTION V: HEALTH HAZARD DATA Threshold Limit Value: Not Established Primary Routes of Entry: Inhalation, Skin Contact, Eyes & Oral Effects of Overexposure- Conditions to Avoid: May Cause Eye Irritation : may include pain, redness, and swelling. May Cause Skin Irritation . may include redness, pain and swelling. May Cause Respiratory Irritation . Inhalation of vapors may cause respiratory irritation and dizziness, nausea or headache. Prolonged exposure above the OSHA permissible exposure limits may result in kidney and liver damage. May be Harmful if Swallowed . Small amounts of this product aspirated into the respiratory system during ingestion or vomiting may cause pulmonary injury. Avoid contact with eyes and skin . Avoid breathing product vapors or mist . Do not swallow. Wash thoroughly after handling . Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Conditions Aggravated by Use: Use of this product may aggravate preexisting skin; eye and respiratory disorders including asthma and dermatitis. Emergency & First Aid Procedures: Eyes: Flush eyes with water for at least 15 minutes. Remove contact lenses. Get medical attention if irritation persists. Skin: Wash thoroughly with soap and water. Get medical attention if irritation persists. Ingestion: Do not induce vomiting. Drink one or two glasses of water to dilute. Get medical attention. Never give anything by mouth to an unconscious person. Inhalation: Move person to fresh air. Get medical attention if irritation persists. Note to Physician: Contains Petroleum distillates. Aspiration hazard. SECTION VI: REACTIVITY DATA Stability: Stable Incompatible Materials: Avoid contact with strong oxidizing agents; strong alkalis and strong mineral acids. Hazardous Decomposition Products: Burning can produce carbon monoxide, carbon dioxide and phosgene gas Hazardous Polymerization: Will Not Occur SECTION VII: SPILL OR LEAK PROCEDURES Steps to be Taken in Case Material is Released or Spilled: Ventilate area. Remove all sources of ignition. Clean up with inert materials and dispose of in accordance with all local, state and federal regulations. Waste Disposal Method: Do not puncture or incinerate aerosol containers. Empty containers may be disposed of through normal channels. Full or partially filled containers are considered hazardous waste. SECTION VIII: SPECIAL PROTECTION INFORMATION Respiratory Protection: Not normally required when good general ventilation is provided. However, if exposure limits (see Section II) are exceeded or respiratory irritation occurs, use of a NIOSH approved respirator suitable for the use-conditions and chemicals in Section II should be considered. Ventilation: Provide good general ventilation. Local exhaust ventilation may be necessary for some operations. Protective Gloves(Specify Type): Wear rubber or other impervious gloves for prolonged or repeated contact. Eye Protection(Specify Type): None required. Other Protective Equipment: See 29 CFR 1910.132-138 for further reference. SECTION IX: SPECIAL PRECAUTIONS Precautions; Handling & Storing: Do not puncture or incinerate container. Do not use or store product near heat, sparks or open flame. Do not store in direct sunlight or above 120 F. High temperatures may cause container to burst. Wash thoroughly after handling. Other Precautions: Keep out of reach of children. © SCC 06/08/2011 Name: Ronald T. Cook Title: Manager, Regulatory Affairs AIRLIFT FRESH SCENT AIR FRESHENER (AEROSOL) Effective Date: 06/08/2011 Supercedes: 03/25/2008 Ref: 29 CFR 1910.1200 (OSHA) Changes: General Review This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as Page 48 of 878 Page 48 of 878 Page 48 of 878 Page 48 of 878 ---PAGE BREAK--- to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. Page 49 of 878 Page 49 of 878 Page 49 of 878 Page 49 of 878 ---PAGE BREAK--- Spartan Chemical Company, Inc. Material Safety Data Sheet SECTION I: PRODUCT INFORMATION Product Name or Number (as it appears on label): Product Division: AIRLIFT LEMON SCENT AIR FRESHENER (AEROSOL) Product Number: 6085 Janitorial Spartan Chemical Company , Inc. Product/Technical Information: 1-(800)-537-8990 1110 Spartan Drive Medical Emergency: 1-(888)-314-6171 (24 hours) Maumee, OH 43537 Chemical Leak/Spill Emergency: CHEMTREC 1-(800) 424-9300 (24 hours) Shipping Description: ORM-D, Consumer Commodity NFPA Ratings: HMIS Ratings: Health: 1- Slight Health: *1 - Slight; Chronic Hazard Fire: 1- Slight Fire: 1- Slight Reactivity: 0 - Minimal Reactivity: 0 - Minimal Pers. Prot. Equip.: See Section VIII SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1% or greater, carcinogens at 0.1% or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. Table Z-1-A Chemical Name(s) %Wt CAS Registry No. TWA mg/m 3 STEL mg/m 3 CEILING mg/m 3 NTP, IARC or OSHA Carcinogen Liquified petroleum gas Petroleum distillates Petroleum distillates 15-20 5-10 1-5 68476-85-7 64742-47-8 64741-65-7 1800 1200 (Exxon) *2900 *525 (ACGIH) Not Established Not Established Not Established Not Established Not Established *1800 (NIOSH) No No No Comment: * Limits for Stoddard Solvent - to be used as a guide only. SECTION III: PHYSICAL DATA Boiling Point: N/A Vapor Pressure: Unknown Vapor Density (AIR = Heavier than air. Solubility in Water: Emulsifiable pH: 6.0-8.0 Specific Gravity (H2O=1): Unknown Evaporation Rate (but.ace.=1): <1 Percent Solid by Weight: Unknown Physical State: Aerosol can (pressurized liquid) Appearance & Odor: Lemon fragrance SECTION IV: FIRE & EXPLOSIVE HAZARD DATA Flash Point: None Method Used: Estimate Flammable Limits: Not Established Explosive Limits: Lower: 1.0% Upper: 9.5% Flame Extension: 0 Inches NFPA 30B Level 1 Aerosol Extinguishing Media: Carbon dioxide, Dry chemical, Water fog, Foam Special Fire Fighting Procedures: Water may be used to cool closed containers to prevent pressure build-up and possible venting or rupturing when exposed to extreme heat. Wear NIOSH approved self-contained breathing apparatus and protective clothing. Unusual Fire & Explosive Hazards: Material gives off vapors which may travel along the ground and be ignited by pilot lights or other sources of ignition. At elevated temperatures (over 120°F/ 49°C ) containers may vent, rupture or burst. Page 50 of 878 Page 50 of 878 Page 50 of 878 Page 50 of 878 ---PAGE BREAK--- SECTION V: HEALTH HAZARD DATA Threshold Limit Value: Not Established Primary Routes of Entry: Inhalation, Skin Contact, Eyes & Oral Effects of Overexposure- Conditions to Avoid: May Cause Eye Irritation : may include pain, redness, and swelling. May Cause Skin Irritation . may include redness, pain and swelling. May Cause Respiratory Irritation . Inhalation of vapors may cause respiratory irritation and dizziness, nausea or headache. Prolonged exposure above the OSHA permissible exposure limits may result in kidney and liver damage. May be Harmful if Swallowed . Small amounts of this product aspirated into the respiratory system during ingestion or vomiting may cause pulmonary injury. Avoid contact with eyes and skin . Avoid breathing product vapors or mist . Do not swallow. Wash thoroughly after handling . Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Conditions Aggravated by Use: Use of this product may aggravate preexisting skin; eye and respiratory disorders including asthma and dermatitis. Emergency & First Aid Procedures: Eyes: Flush eyes with water for at least 15 minutes. Remove contact lenses. Get medical attention if irritation persists. Skin: Wash thoroughly with soap and water. Get medical attention if irritation persists. Ingestion: Do not induce vomiting. Drink one or two glasses of water to dilute. Get medical attention. Never give anything by mouth to an unconscious person. Inhalation: Move person to fresh air. Get medical attention if irritation persists. Note to Physician: Contains Petroleum distillates. Aspiration hazard. SECTION VI: REACTIVITY DATA Stability: Stable Incompatible Materials: Avoid contact with strong oxidizing agents; strong alkalis and strong mineral acids. Hazardous Decomposition Products: Burning can produce carbon monoxide, carbon dioxide and phosgene gas Hazardous Polymerization: Will Not Occur SECTION VII: SPILL OR LEAK PROCEDURES Steps to be Taken in Case Material is Released or Spilled: Ventilate area. Remove all sources of ignition. Clean up with inert materials and dispose of in accordance with all local, state and federal regulations. Waste Disposal Method: Do not puncture or incinerate aerosol containers. Empty containers may be disposed of through normal channels. Full or partially filled containers are considered hazardous waste. SECTION VIII: SPECIAL PROTECTION INFORMATION Respiratory Protection: Not normally required when good general ventilation is provided. However, if exposure limits (see Section II) are exceeded or respiratory irritation occurs, use of a NIOSH approved respirator suitable for the use-conditions and chemicals in Section II should be considered. Ventilation: Provide good general ventilation. Local exhaust ventilation may be necessary for some operations. Protective Gloves(Specify Type): Wear rubber or other impervious gloves for prolonged or repeated contact. Eye Protection(Specify Type): None required. Other Protective Equipment: See 29 CFR 1910.132-138 for further reference. SECTION IX: SPECIAL PRECAUTIONS Precautions; Handling & Storing: Do not puncture or incinerate container. Do not use or store product near heat, sparks or open flame. Do not store in direct sunlight or above 120 F. High temperatures may cause container to burst. Wash thoroughly after handling. Other Precautions: Keep out of reach of children. © SCC 06/08/2011 Name: Ronald T. Cook Title: Manager, Regulatory Affairs AIRLIFT LEMON SCENT AIR FRESHENER (AEROSOL) Effective Date: 06/08/2011 Supercedes: 03/25/2008 Ref: 29 CFR 1910.1200 (OSHA) Changes: General Review This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as Page 51 of 878 Page 51 of 878 Page 51 of 878 Page 51 of 878 ---PAGE BREAK--- to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. Page 52 of 878 Page 52 of 878 Page 52 of 878 Page 52 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SECTION 1 - PRODUCT AND COMPANY INFORMATION PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 TECHNICAL INFORMATION: (412) 492-5200 (ALLISON PARK, PA) 8:00 a.m. - 5:00 p.m. EST PRODUCT SAFETY/MSDS INFORMATION: (412) 492-5555 7:00 a.m. - 4:30 p.m. EST Product ID: 77J (0809) PRODUCT NAME: ALKYD/OIL STAINS/NWF SYNONYMS: None ISSUE DATE: 01/26/2006 EDITION NO.: 2 CHEMICAL FAMILY: ALKYD EMERGENCY OVERVIEW: Combustible. Keep away from heat, sparks, flames, and other sources of ignition. Do not smoke.CAUSES EYE IRRITATION.MAY CAUSE SLIGHT SKIN IRRITATION.VAPOR AND/OR SPRAY MIST MAY BE HARMFUL IF INHALED. VAPOR IRRITATES EYES, NOSE, AND THROAT. SANDING AND GRINDING DUSTS MAY BE HARMFUL IF INHALED.HARMFUL IF SWALLOWED. SECTION 2 - COMPOSITION INFORMATION The following ingredient(s) marked with an are considered hazardous under applicable U.S. OSHA and/or Canadian WHMIS regulations. If no ingredients are listed, then there are no U.S. OSHA and/or Canadian WHMIS hazardous ingredients in this product. Material/ CAS Number Percent Hazardous NAPHTHA 8052-41-3 60- 100 X NAPHTHA 64742-48-9 40 - 70 X QUARTZ 14808-60-7 10 - 30 X TITANIUM DIOXIDE 13463-67-7 10 - 30 X SILICA CRISTOBALLITE 14464-46-1 5 - 10 X CALCIUM CARBONATE 1317-65-3 1 - 5 X DIATOMACEOUS EARTH 68855-54-9 1 - 5 X XYLENES 1330-20-7 1 - 5 X AROMATIC NAPHTHA 64742-95-6 0.5-1.5 X RED IRON OXIDE 1309-37-1 0.5-1.5 X PARAFFIN WAXES AND HYDROCARBON WAXES 8002-74-2 0.5-1.5 X DIETHYLENE GLYCOL MONOMETHYL ETHER 111-77-3 0.1-1.0 X ETHYL BENZENE 100-41-4 0.1-1.0 X CARBON BLACK 1333-86-4 0.1-1.0 X MANGANESE DRIER 27253-32-3 0.1-1.0 X (As Manganese 27253-32-3 * X See Sections 8 and 15 for information. SECTION 3 - HAZARDS IDENTIFICATION ACUTE OVEREXPOSURE EFFECTS EYE CONTACT: Causes eye irritation. Redness, itching, burning sensation and visual disturbances may indicate excessive eye contact. SKIN CONTACT: May cause slight skin irritation. Dryness, itching, cracking, burning, redness, and swelling are conditions associated with excessive skin contact. SKIN ABSORPTION: Skin absorption not expected to occur. INHALATION: Vapor and/or spray mist may be harmful if inhaled. Vapor irritates eyes, nose, and throat. Sanding and grinding dusts may be harmful if inhaled. INGESTION: Harmful if swallowed. SIGNS & OF OVEREXPOSURE: Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Eye watering, headaches, nausea, dizziness and loss of coordination are indications that solvent levels are too high. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Dryness, itching, cracking, burning, redness, and swelling are conditions associated with excessive skin contact. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Not applicable. CHRONIC OVEREXPOSURE EFFECTS Avoid long-term and repeated contact. Page 1 of 5 01-800-00-21-400 (Mexico) 0532-83889090 (China) EMERGENCY PHONE NUMBERS (24 hours/day): (514) 645-1320 (Canada) (412) 434-4515 Page 53 of 878 Page 53 of 878 Page 53 of 878 Page 53 of 878 ---PAGE BREAK--- PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 Product ID: 77J (0809) PRODUCT NAME: ALKYD/OIL STAINS/NWF Repeated exposure to vapors above recommended exposure limits (see Section 8) may cause irritation of the respiratory system and permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. This product contains silica which has been classified as a human carcinogen by IARC. Long-term exposures may also lead to a disabling lung condition known as silicosis. The risk depends on the duration and level of exposure to dust from sanding surfaces or mist from spray applications. Use of appropriate personal protective equipment and/or engineering controls should be employed whenever these types of operations are being performed. This product either contains formaldehyde or is capable of releasing formaldehyde above 0.5 ppm under certain conditions. If this product contains free formaldehyde, formaldehyde will be listed as an ingredient in Section 2 and 11 of this MSDS; if formaldehyde is not specifically listed, this product contains ingredients capable of releasing formaldehyde under certain conditions. Formaldehyde is a known cancer hazard, a skin sensitizer and a respiratory sensitizer. Manganese dust overexposure affects the central nervous system and may also cause blood and lung changes. These effects have mostly been observed in miners and steel mill workers. High exposures to xylenes in some animal studies have been reported to cause health effects on the developing embryo and fetus. These effects were often at levels toxic to the mother. The effects of long-term, low level exposures to this product have not been determined. Safe handling of this material on a long-term basis should emphasize the prevention of all contact with this material to avoid any effects from repetitive acute exposures. See Section 11, of this MSDS for a detailed list of chronic health effects information available on individual ingredients in this product. SECTION 4 - FIRST AID MEASURES If ingestion, irritation, any type of overexposure or of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material Safety Data Sheet information available. EYE CONTACT: Remove contact lens and pour a gentle stream of warm water through the affected eye for at least 15 minutes. If irritation persists, contact a poison control center, emergency room, or physician as further treatment may be necessary. SKIN CONTACT: Run a gentle stream of water over the affected area for 15 minutes. A mild soap may be used if available. If any persist, contact a poison control center, emergency room, or physician as further treatment may be necessary. INHALATION: Remove from area to fresh air. If contact a poison control center, emergency room or physician for treatment information. INGESTION: Gently wipe or rinse the inside of the mouth with water. Sips of water may be given. Never give anything by mouth to an unconscious person. Contact a poison control center, emergency room or physician right away as further treatment may be necessary. SECTION 5 - FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES FLASHPOINT: 105 Degrees F ( 41 Degrees C) FLASHPOINT TEST METHOD: Pensky-Martens Closed Cup UEL: Not Available. LEL: 1.5 AUTOIGNITION TEMPERATURE: Not Available. EXTINGUISHING MEDIA: Use National Fire Protection Association (NFPA) Class B extinguishers (carbon dioxide, dry chemical, or universal aqueous film forming foam) designed to extinguish NFPA Class II combustible liquid fires. Water spray may be ineffective. Water spray may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. PROTECTION OF FIREFIGHTERS: Fire-fighters should wear self-contained breathing apparatus and full protective clothing. UNUSUAL FIRE AND EXPLOSION HAZARDS: When this product is used, the overspray and other combustible materials such as paint booth filters, rags, masking materials, etc., contaminated by coating material are subject to spontaneous combustion. Wetting the contaminated materials and not packing them together in refuse containers will minimize the potential for this to occur. Keep this product away from heat, sparks, flame, and other sources of ignition pilot lights, electric motors, static electricity). Invisible vapors can travel to a source of ignition and flash back. Do not smoke while using this product. Keep containers closed when not in use. Closed containers may explode when overheated. Do not apply to hot surfaces. Toxic gases may form when this product comes in contact with extreme heat. May produce hazardous decomposition products when exposed to extreme heat. Extreme heat includes, but is not limited to, flame cutting, brazing, and welding. SECTION 6 - ACCIDENTAL RELEASE MEASURE STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Provide maximum ventilation. Only personnel equipped with proper respiratory, skin, and eye protection should be permitted in the area. Remove all sources of ignition. Take up spilled material with sand, vermiculite, or other noncombustible absorbent material and place in clean, empty containers for disposal. Only the spilled material and the absorbant should be placed in this container. SECTION 7 - HANDLING AND STORAGE PRECAUTIONS TO BE TAKEN DURING HANDLING AND STORAGE: Vapors may collect in low areas. If this material is part of a multiple component system, read the Material Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. Containers should be grounded when pouring. Avoid free fall of liquids in excess of a few inches. STORAGE: Do not store above 120 degrees F.(48 degrees Store large quantities in buildings designed and protected for storage of NFPA Class II combustible liquids. SECTION 8 - EXPOSURE CONTROLS & PERSONAL PROTECTION ENGINEERING CONTROLS: Provide general dilution or local exhaust ventilation in volume and pattern to keep the concentration of ingredients listed in Section 8 below the lowest suggested exposure limits, the LEL below the stated limit, and to remove decomposition products during welding or flame cutting. PERSONAL PROTECTIVE EQUIPMENT EYES: Wear chemical-type splash goggles when possibility exists for eye contact due to splashing or spraying liquid, airborne particles, or vapors. SKIN/GLOVES: Wear protective clothing. Gloves should be constructed of: neoprene rubber or nitrile rubber. No specific permeation/degradation testing have been done on protective clothing for this product. Recommendations for skin protection are based on infrequent contact with this product. For frequent contact or total immersion, contact a manufacturer of protective clothing for appropriate chemical impervious equipment. Clean contaminated clothing and shoes. Page 2 of 5 Page 54 of 878 Page 54 of 878 Page 54 of 878 Page 54 of 878 ---PAGE BREAK--- PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 Product ID: 77J (0809) PRODUCT NAME: ALKYD/OIL STAINS/NWF RESPIRATOR: Overexposure to vapors may be prevented by ensuring proper ventilation controls, vapor exhaust or fresh air entry. A NIOSH- approved air purifying respirator with the appropriate chemical cartridges or a positive- pressure, air-supplied respirator may also reduce exposure. Read the respirator manufacturer's instructions and literature carefully to determine the type of airborne contaminants against which the respirator is effective, its limitations, and how it is to be properly fitted and used. Provide general dilution or local exhaust ventilation in volume and pattern to keep the concentration of ingredients listed in Section 2 below the lowest suggested exposure limits, the LEL below the stated limit, and to remove decomposition products during welding or flame cutting. GENERAL HYGIENE - ESTABLISHED EXPOSURE LIMITS If Threshold Limit Values (TLVs) have been established by ACGIH, OSHA, Ontario or PPG, they will be listed below. These limits are intended for use in the practice of industrial hygiene as guidelines or recommendations in the control of potential workplace health hazards. These limits are not a relative index of toxicity and should not be used by anyone without industrial hygiene training. Material/ CAS Number Percent ACGIH TLV ACGIH STEL OSHA PEL OSHA STEL NAPHTHA 8052-41-3 60- 100 100 ppm Not established 100 ppm Not established QUARTZ 14808-60-7 10 - 30 R- 0.05 MG/m3 Not established R- 0.1 mg/m3 Not established TITANIUM DIOXIDE 13463-67-7 10 - 30 10 mg/m3 Not established 10 mg/m3 Not established SILICA CRISTOBALLITE 14464-46-1 5 - 10 R- 0.05 mg/m3 Not established R- 0.05 mg/m3 Not established CALCIUM CARBONATE 1317-65-3 1 - 5 Not established Not established R- 5 mg/m3 Not established XYLENES 1330-20-7 1 - 5 100 ppm 150 ppm 100 ppm 150 ppm RED IRON OXIDE 1309-37-1 0.5-1.5 5 mg/m3 Not established 10 mg/m3 Not established PARAFFIN WAXES AND HYDROCARBON WAXES 8002-74-2 0.5-1.5 2 mg/m3 Not established 2 mg/m3 Not established ETHYL BENZENE 100-41-4 0.1-1.0 100 ppm 125 ppm 100 ppm 125 ppm CARBON BLACK 1333-86-4 0.1-1.0 3.5 mg/m3 Not established 3.5 mg/m3 Not established (As Manganese 27253-32-3 * Not established Not established C- 5 MG/m3 Not established Material/ CAS Number Percent Ontario TWA Ontario STEL PPG IPEL PPG STEL NAPHTHA 8052-41-3 60- 100 525 MG/m3 Not established Not established Not established QUARTZ 14808-60-7 10 - 30 0.10 MG/m3 Not established Not established Not established TITANIUM DIOXIDE 13463-67-7 10 - 30 10 mg/m3 Not established Not established Not established SILICA CRISTOBALLITE 14464-46-1 5 - 10 0.05 MG/m3 Not established Not established Not established CALCIUM CARBONATE 1317-65-3 1 - 5 10 MG/m3 Not established Not established Not established XYLENES 1330-20-7 1 - 5 100 ppm 150 ppm Not established Not established RED IRON OXIDE 1309-37-1 0.5-1.5 5 MG/m3 Not established Not established Not established PARAFFIN WAXES AND HYDROCARBON WAXES 8002-74-2 0.5-1.5 2 MG/m3 Not established Not established Not established DIETHYLENE GLYCOL MONOMETHYL ETHER 111-77-3 0.1-1.0 Not established Not established 25 ppm 50 ppm ETHYL BENZENE 100-41-4 0.1-1.0 100 ppm 125 ppm Not established Not established CARBON BLACK 1333-86-4 0.1-1.0 3.5 mg/m3 Not established Not established Not established (As Manganese 27253-32-3 * 5 mg/m3 Not established Not established Not established Key: ACGIH=American Conference of Governmental Industrial Hygienists; OSHA=Occupational Safety and Health Administration; TLV=Threshold Limit Value; TWA=Time Weighted Average; PEL=Permissible Exposure Limit; IPEL=Internal Permissible Exposure Limit; Ceiling=TLV or PEL Ceiling Limit; STEL=TLV or PEL Short-Term Exposure Limit; Skin= Skin Absorption Designation. Ceiling Limit; S- Potential Skin Aborption; R-Respirable Dust] Additional Information Not applicable. SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES (FORMULA VALUES, NOT SALES SPECIFICATIONS) SPECIFIC GRAVITY: .932 PHYSICAL STATE: Liquid Percent Solids: 31-70 Percent Volatile by Volume: 43-74 pH: Not available. ODOR THRESHOLD: Not available. Vapour Pressure: <20.0 mmHg ODOR/APPEARANCE: Viscous liquid with an odor characteristic of the solvents listed in Section 2. VAPOR DENSITY: HEAVIER THAN AIR Evaporation Rate: <70 BOILING POINT OR RANGE: 172- 468Degrees F Freezing Point or Range: Not Applicable. Melting Point or Range(°C): Not Applicable. Partition coefficient octanol/water): Not Applicable. WEIGHT PER GALLON: 7.77 / 9.3 (IMPERIAL) SECTION 10 - STABILITY AND REACTIVITY STABILITY: This product is normally stable and will not undergo hazardous reactions. Page 3 of 5 Page 55 of 878 Page 55 of 878 Page 55 of 878 Page 55 of 878 ---PAGE BREAK--- PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 Product ID: 77J (0809) PRODUCT NAME: ALKYD/OIL STAINS/NWF CONDITIONS TO AVOID: None Known. INCOMPATIBLE MATERIALS: Avoid contact with strong alkalies, strong mineral acids, or strong oxidizing agents. HAZARDOUS POLYMERIZATION: None Known. HAZARDOUS DECOMPOSITION PRODUCTS: - Carbon monoxide - Carbon dioxide - Iron oxides - Oxides of aluminum - Lower molecular weight polymer fractions - Oxides of nitrogen SECTION 11 - TOXICOLOGICAL INFORMATION ACUTE TOXICITY Material/ CAS Number Percent ORAL LD50 (g/kg) DERMAL LD50 (g/kg) INHALATION LC50 (mg/l) NAPHTHA 8052-41-3 60- 100 5.00 g/kg Not Available 5.50 g/L. 4 hr. TITANIUM DIOXIDE 13463-67-7 10 - 30 10.00 g/kg Not Available Not Available XYLENES 1330-20-7 1 - 5 4.30 g/kg 1.70 g/kg 21.88 g/L. 4 hr. AROMATIC NAPHTHA 64742-95-6 0.5-1.5 8.40 g/kg 3.48 g/kg 5.20 g/L. 4 hr. RED IRON OXIDE 1309-37-1 0.5-1.5 10.00 g/kg Not Available Not Available DIETHYLENE GLYCOL MONOMETHYL ETHER 111-77-3 0.1-1.0 9.20 g/kg .65 g/kg Not Available ETHYL BENZENE 100-41-4 0.1-1.0 3.50 g/kg 17.80 g/kg Not Available CARBON BLACK 1333-86-4 0.1-1.0 15.40 g/kg 3.00 g/kg Not Available CHRONIC TOXICITY Ingredient Target Organ/Chronic Effects: - Bone marrow and blood tissues - Kidney - Liver - Embryotoxin - Carcinogen - Blood - Neurotoxin - Brain - Central nervous system - Lung Mutagenicity Toxicity: This has not been tested for this product. Reproductive Toxicity: This has not been tested for this product. SUPPLEMENTAL HEALTH INFORMATION: Material/ CAS Number Percent Ingredient Specific Animal Data: TITANIUM DIOXIDE 13463-67-7 10 - 30 This product contains titanium dioxide. Animals inhaling massive quantities of titanium dioxide dust in a long-term study developed lung tumors. Studies with humans involved in manufacture of this pigment indicate no increased risk of cancer from exposure. DIETHYLE NE GLYCOL MONOMET HYL ETHER 111-77-3 0.1-1.0 This product contains an ethylene series glycol ether and/or acetate which has been shown to cause adverse effects on the kidneys, liver, blood and/or blood-forming tissue. ETHYL BENZENE 100-41-4 0.1-1.0 has been reported by NTP to cause cancer in laboratory animals following a chronic (2 year) inhalation exposure. Dose levels of 75, 250 and 750 ppm were used, with evidence of carcinogenicity found in the kidneys of rats and the lung and liver of mice at 750 ppm. The No Observed Effect Level (NOEL) was 75 ppm. The relevance of these findings to humans is uncertain, but appropriate safeguards should be employed to reduce or eliminate inhalation exposure to CARBON BLACK 1333-86-4 0.1-1.0 This product contains carbon black which has been rated an IARC 2B carcinogen due to animal data. SECTION 12 - ECOLOGICAL INFORMATION POTENTIAL ENVIRONMENTAL EFFECTS Ecotoxicity: No Information Available. ENVIRONMENTAL FATE Mobility: No information available. Biodegradation: No information available. Bioaccumulation: No Information Available. PHYSICAL/CHEMICAL Hydrolysis: No information available. Photolysis: No information available. SECTION 13 - DISPOSAL CONSIDERATIONS Provide maximum ventilation, only personnel equipped with proper respiratory and skin and eye protection should be permitted in the area. Take up spilled material with sawdust, vermiculite, or other absorbent material and place in containers for disposal. Waste material must be disposed of in accordance with federal, state, provincial and local environmental control regulations. Empty containers should be recycled by an appropriately licensed reconditioner/salvager or disposed of through a permitted waste management facility. Additional disposal information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative. SECTION 14 - TRANSPORTATION INFORMATION Proper Shipping Name: NOT AVAILABLE NOS Technical Name: NOT AVAILABLE Hazard Class: N.A. Subsidiary Class(es): N.A. UN Number: N.A. Packing Group: N.A. USA - RQ Hazardous Substances: NOT AVAILABLE USA-RQ Hazardous Substance Threshold Ship Weight: NOT AVAILABLE Marine Pollutant Name: NOT AVAILABLE Page 4 of 5 Page 56 of 878 Page 56 of 878 Page 56 of 878 Page 56 of 878 ---PAGE BREAK--- PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 Product ID: 77J (0809) PRODUCT NAME: ALKYD/OIL STAINS/NWF SECTION 15 - REGULATORY INFORMATION INVENTORY STATUS U.S. TSCA: This product and/or all of its components are listed on the U.S. TSCA Inventory or is otherwise exempt from TSCA Inventory reporting requirements. FEDERAL REGULATIONS US Regulations Material/ CAS Number Percent CERCLA HS - RQ (LBS) SARA EHS- TPQ (LBS) SARA 313 NAPHTHA 8052-41-3 60- 100 Not Listed Not Listed Not Listed NAPHTHA 64742-48-9 40 - 70 Not Listed Not Listed Not Listed QUARTZ 14808-60-7 10 - 30 Not Listed Not Listed Not Listed TITANIUM DIOXIDE 13463-67-7 10 - 30 Not Listed Not Listed Not Listed SILICA CRISTOBALLITE 14464-46-1 5 - 10 Not Listed Not Listed Not Listed CALCIUM CARBONATE 1317-65-3 1 - 5 Not Listed Not Listed Not Listed DIATOMACEOUS EARTH 68855-54-9 1 - 5 Not Listed Not Listed Not Listed XYLENES 1330-20-7 1 - 5 100 lbs Not Listed Listed AROMATIC NAPHTHA 64742-95-6 0.5-1.5 Not Listed Not Listed Not Listed RED IRON OXIDE 1309-37-1 0.5-1.5 Not Listed Not Listed Not Listed PARAFFIN WAXES AND HYDROCARBON WAXES 8002-74-2 0.5-1.5 Not Listed Not Listed Not Listed DIETHYLENE GLYCOL MONOMETHYL ETHER 111-77-3 0.1-1.0 Not Listed Not Listed Not Listed ETHYL BENZENE 100-41-4 0.1-1.0 1000 lbs Not Listed Listed CARBON BLACK 1333-86-4 0.1-1.0 Not Listed Not Listed Not Listed MANGANESE DRIER 27253-32-3 0.1-1.0 Not Listed Not Listed Not Listed (As Manganese 27253-32-3 * Not Listed Not Listed Listed SARA 311/312 Health (acute): Yes Health (chronic): Yes Fire (flammable): Yes Pressure: No Reactivity: No WHMIS HAZARD CLASS: - Class B, Division 6 - Class D, Division 2, Subdivision A STATE/PROVINCIAL REGULATIONS CALIFORNIA PROP. 65: WARNING: This product contains a chemical known to the State of California to cause cancer. Additional Information Material/ CAS Number Percent IARC Group 1(Kno wn Human Carc.) IARC Group 2A (Proba ble Carc.) IARC 2B ( Suspec ted Carc.) ACGIH Carc. NTP Known Carc. OSHA Carc. QUARTZ 14808-60-7 10 - 30 Y N N Y N Y SILICA CRISTOBALLITE 14464-46-1 5 - 10 Y N N N N N ETHYL BENZENE 100-41-4 0.1-1.0 N N Y N N Y CARBON BLACK 1333-86-4 0.1-1.0 N N Y N N Y Key: IARC- International Agency on the Research of Cancer; ACGIH- American Conference of Governmental Industrial Hygienists; NTP- National Toxicology Program *Denotes chemical as NTP Known Carcinogen; + Denotes NTP Possible Carcinogen; OSHA- Occupational Safety and Health Administration. SECTION 16 - OTHER INFORMATION Hazard Rating Systems NFPA Rating: 2 20 HMIS Rating: 2*20 Rating System: 0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe, *=Chronic Effects. HMIS=Hazardous Materials Identification System; NFPA=National Fire Protection Association; Safe handling of this product requires that all of the information on the MSDS be evaluated for specific work environments and conditions of use. PREPARED BY: Product Safety Department REASON FOR REVISION: Date. Edition. Updated MSDS format. This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200), the supplier notification requirements of SARA Title III, Section 313 and other applicable right-to-know regulations. Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative. 77J 000000 (00253850.001)(02/03/03) 030124, 000, 0809 END OF MSDS Page 5 of 5 Page 57 of 878 Page 57 of 878 Page 57 of 878 Page 57 of 878 ---PAGE BREAK--- ALL PURPOSE SPOTTER 327CC Water-Based Stain Remover 1-[PHONE REDACTED] Essential Industries, Inc. P.O. Box 12 Merton, WI 53056-0012 Phone: [PHONE REDACTED] 7/14/2009. Material Safety Data Sheet Product name Material uses Manufacturer Code Validation date Print date In case of emergency Product and company identification Responsible name Regulatory Affairs Department ALL PURPOSE SPOTTER 1 . 7/14/2009. Health Physical hazards 0 1 Hazardous Material Information System Personal protection B HAZARD RATING 4 = Extreme 3 = High 2 = Moderate 1 = Slight 0 = Insignificant A = Goggles B = Goggles & Gloves C = Goggles, Gloves & Apron Flammability 0 Emergency overview Hazards identification Potential acute health effects due to overexposure No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Eyes Skin Inhalation Ingestion See toxicological information (section 8) NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHEN THE RECOMMENDED INSTRUCTIONS FOR USE ARE FOLLOWED. No known significant effects or critical hazards. Avoid prolonged contact with eyes, skin and clothing. 2 . Potential chronic health effects due to overexposure Carcinogenicity No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Developmental effects No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Composition/information on ingredients 3 . There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention if occur. Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention if occur. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention if occur. Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if occur. First aid measures Eye contact Skin contact Inhalation Ingestion No specific treatment. Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Notes to physician 4 . Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. Use an extinguishing agent suitable for the surrounding fire. Fire-fighting measures Extinguishing media isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. In a fire or if heated, a pressure increase will occur and the container may burst. 5 . Special exposure hazards Suitable Flammability of the product Page 58 of 878 Page 58 of 878 Page 58 of 878 Page 58 of 878 ---PAGE BREAK--- Fire-fighting measures 5 . Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Hazardous thermal decomposition products Decomposition products may include the following materials: carbon dioxide carbon monoxide sulfur oxides metal oxide/oxides Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Control and preventive measures Storage 6. Personal protection Respiratory Hands Eyes Skin Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Methods for cleaning up Small spill Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Waste disposal The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. 100°C (212°F) Liquid 8.8 to 9.4 0°C (32°F) <1 [Air = 1] <4 kPa (<30 mm Hg) Varied Colorless Boiling/condensation point Melting/freezing point Physical and chemical properties Physical state pH Vapor pressure Vapor density Odor Color 7.5% VOC 7. 1% pH: 7.0 Specific Gravity: 1.00 gm/ml Weight per Gallon: 8.38 lbs./gal. Toxicological information 8. Acute toxicity Conclusion/Summary Not available Chronic toxicity Conclusion/Summary Not available Transport information - - DOT Classification - - Regulatory information UN number Proper shipping name Classes PG* Label Additional information Not regulated 9. PG* : Packing group Page 59 of 878 Page 59 of 878 Page 59 of 878 Page 59 of 878 ---PAGE BREAK--- SECTION 9 - PREPARATION INFORMATION SECTION 8 - EMERGENCY FIRST AID PROCEDURES SECTION 7 - PREVENTATIVE AND CONTROL MEASURES SECTION 6 - TOXICOLOGICAL PROPERTIES SECTION 5 - REACTIVITY DATA SECTION 4 - FIRE AND EXPLOSION HAZARD DATA SECTION 3 - PHYSICAL DATA SECTION 2 - HAZARDOUS INGREDIENTS INFORMATION SECTION 1. PRODUCT/MANUFACTURER'S IDENTITY Water 7732-18-5 60-100 N.E. N.E. N.D. N.D. 2-Butoxyethanol 111-76-2 8 25ppm 25ppm 470mg/kg 700ppm 7hr Sodium hydroxymethane sulfite 149-44-0 1-5 15mg/m3 10mg/m3 >1g/kg N.D. Sodium xylene sulfonate 1300-72-7 1-5 N.E. N.E. N.D. N.D. MATERIAL SAFETY DATA SHEET PRODUCT NAME: PRODUCT NUMBER: ALL PURPOSE SPOTTER PRODUCT USE: Water-based stain remover PRODUCT I.D. NUMBER (PIN): N.A. 1 0 0 B HEALTH FIRE REACTIVITY MAXIMUM PERSONAL PROTECTION H.M.I.S. A = Goggles B = Goggles & Gloves C = Goggles, Gloves & Apron COMPANY: Essential Industries, Inc. P.O. Box 12 Merton, WI 53056-0012 EMERGENCY PHONE: [PHONE REDACTED] HAZARD RATING 4 = Extreme 3 = High 2 = Moderate 1 = Slight 0 = Insignificant WHMIS CLASS: D2B N.A. DOT HAZARD CLASS: DOT SHIPPING NAME: ABBREVIATION KEY: N.A. - Not Applicable N.E. = Not Established N.D. = Not Determined HAZARDOUS CHEMICAL IDENTITY CAS NO. % PEL LD50 LC50 This mixture contains 8% 2-Butoxyethanol which is subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR, Part 372. Color: Colorless Varied Liquid Physical State: Odor Threshold: N.E. 100°C (212°F) Boiling Point: <30 mm of Hg Vapor Pressure: Vapor Density (Air=1):<1 pH: 8.8 - 9.4 Evaporation Rate (Water=1):N.E. Water/Oil Distribution:N.E. Freezing Point: 0°C (32°F) Solubility in Water: Complete Specific Gravity: 1.00 gm/ml Flash Point and Method: N.A. Flammable Limits: N.A. Autoignition Temperature:N.A. Extinguishing Media: Hazardous Combustion Products:N.A. Use dry chemical or CO2. Special Fire Fighting Procedures: None. Unusual Fire and Explosion Hazards:None. Chemical Stability: Stable. Incompatibility (Materials to Avoid): None known. Hazardous decomposition of By-Products: None known. Will not occur. Hazardous Polymerization: Routes of Entry: Ingestion. Inhalation. Skin contact. Eye contact. Sensitization: Toxicologically Synergistic Products: None known. None known. Medical Conditions Aggravated by Exposure: EFFECTS OF OVEREXPOSURE (Acute and/or Chronic): Eyes: Direct contact may cause irritation. May cause gastrointestinal irritation, nausea, diarrhea. Prolonged or repeated contact may cause irritation. May be absorbed through skin with prolonged or repeated contact. Inhalation: Ingestion: Skin: NO mutagenic effect. Regulatory Affairs Department Remove to fresh air and rest. Inhalation: Ingestion: Give 2-3 large glasses of water. Seek medical attention. Eyes: Skin: Wash with mild soap and water. Flush with a large amount of water for 15 minutes holding eyelids open. FIRST AID - NOTES TO PHYSICIAN: Waste Disposal: Dispose of as permitted by all federal, provincial, state and local regulatory authorities. Collect and reuse if possible. Flush to sewer with large quantities of water if permitted by regulatory authorities or absorb on inert material (sand, clay, etc.) and place into container for proper disposal. Do not allow runoff into public waterways. Steps to be Taken if Material is Spilled or Released: Storage Requirements: Store in cool, dry area. Follow good housekeeping practices. None normally required with adequate ventilation. Respiratory Protection: Ventilation: Other Requirements:Keep out of reach of children. Reproductive Toxicity: Non-Regulated N.A. LEL: No. Local Exhaust: Acceptable Mechanical: Recommended TLV 00327CC UEL: N.A. NO teratogenic effect. NO reproductive toxicity effect. NO carcinogenic effect. Prolonged exposure in poorly ventilated area may cause respiratory irritation. Carcinogenic Effects: Mutagenic Effects: Rubber for prolonged exposure. As needed to prevent wetting of skin. Safety glasses if splashing is likely. After handling, always wash hands thoroughly with soap and water. Work and Hygienic Practices: Protective Gloves: Protective Clothing and Equipment: Eye Protection: [PHONE REDACTED] No additional information. VOC Content: 7.5% Odor: 1% pH: 7.0 Weight per Gallon: 8.38 lbs./gal. Note to Physician: Date of Preparation: Prepared By: Phone: Teratogenic Effects: Flash Point and Method: Color: 1/22/2008. Page 60 of 878 Page 60 of 878 Page 60 of 878 Page 60 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) NTP IARC OSHA NONE X X X x None to Boiling SECTION 1 - PRODUCT IDENTIFICATION Distributor Emergency Phone Clausen Carpet Solutions [PHONE REDACTED] Address P.O. Box 37 Folcroft, PA 19032 Trade Name Product Type Carpet Antistat ANTI-STAT SECTION 2 - HAZARDOUS INGREDIENTS CHEMICAL NAME/COMMON NAME CAS NO. PERCENT(optional) TLV(Source) ammonium chloride 68607-27-2 Not Established Other ingredients in this product are : Less than 1% by weight or less than 0.1% for carcinogens Not hazardous Declared to be Trade Secret SECTION 3 - PHYSICAL DATA Boiling point(°F.) Specific Gravity(H2O=1.0) 0.005) pH 0.5) 7.0 Near 212 1.000 Vapor Pressure(mm Hg) Vapor Density(Air=1) Unknown Unknown X Solubility in water Complete Insoluble Emulsifiable (or Dispersible) Slight (or Partial) X Evaporation Rate(vs. H2O) Faster Slower About the Same Appearance and Odor Liquid, pleasant odor SECTION 4 - FIRE AND EXPLOSION HAZARD DATA Lower Upper Flammable Limits Unknown Unknown Extinguishing Media CO2, dry chemical, foam, water spray. Special Firefighting Procedures Do not enter confined fire-spaces without protective clothing and self-contained air supply. Unusual Fire and Explosion Hazards None known. SECTION 5 - REACTIVITY DATA Incompatibility Stability Stable Strong oxidizers Hazardous Decomposition Products Carbon monoxide and other unidentified organic gases may occur during incomplete combustion. SECTION 6 - HEALTH HAZARDS X X X Primary Routes of Exposure Eye Skin Oral Inhalation Other Signs Eyes: Stinging. Skin:Redness or itching if left on exposed skin. Swallowing: Possible mucosal damage,possible respiratory depression, possible convulsions. Signs and of Overexposure(Chronic)None known Medical Conditions None known Carcinogen/Suspect Carcinogen Ingredients X SECTION 7 - EMERGENCY AND FIRST AID PROCEDURES Eyes Flush immediately with water for at least 15 minutes. If persistent irritation occurs, call a physician. Skin Wash thoroughly with soap and water. Ingestion Drink milk,egg whites, gelatin solution or if these are not available, drink large quantities of water. Call a physician. Inhalation Remove exposed person to fresh air. Treat SECTION 8 - SPECIAL PROTECTION INFORMATION Respiratory Protection Not needed under normal conditions of use. X Ventilation Requirements Local Exhaust Mechanical Protective Gloves Other Protective Clothing Eye Protection Rubber Safety glasses/goggles Not required for normal use SECTION 9 - SPILL OR LEAK PROCEDURES Steps to be Taken Absorb with suitable absorbent. For large spills, collect for disposal. if Released or Spilled Waste Disposal Methods Dispose of in accordance with applicable Federal, State and Local ordinances. SECTION 10 - STORAGE AND HANDLING INFORMATION Avoid contact with skin, eyes and clothing. Wash thoroughly after handling. Use with adequate ventilation. Do not contaminate food or water by storage or disposal. Precautions to be Taken in Handling and Storage and of Overexposure (Acute) Aggravated by Overexposure Flash Point(T.C.C.) Room Ventilation Is Adequate The health hazards given on the Material Safety Data Sheet apply to this product in its concentrated form (as supplied) and may differ significantly at use dilution. The signs and of over exposure apply only to negligence in handling or misuse of the concentrated product and not to the routine exposure to the product, under normal conditions of use. 1/1/2008 DATE PREPARED Page 61 of 878 Page 61 of 878 Page 61 of 878 Page 61 of 878 ---PAGE BREAK--- Page 62 of 878 Page 62 of 878 Page 62 of 878 Page 62 of 878 ---PAGE BREAK--- Page 63 of 878 Page 63 of 878 Page 63 of 878 Page 63 of 878 ---PAGE BREAK--- Material Safety Data Sheet Material Name: AquaScent (Apple-Pear) Page 1 of 4 Issue Date: 09/26/11 Revision: 1.0000 Print Date: 09/26/11 * * * Section 1 - Chemical Product and Company Identification * * * Manufactured for F-MATIC Inc. Phone: [PHONE REDACTED] 299 S Millpond Dr Fax: [PHONE REDACTED] Lehi, UT 84043 * * * Section 2 - Hazards Identification * * * Emergency Overview May cause skin and eye irritation. Potential Health Effects: Eyes May cause eye irritation. Potential Health Effects: Skin May cause irritation. Potential Health Effects: Ingestion Not a likely route of exposure under normal product use conditions. May cause gastrointestinal irritation if swallowed. Potential Health Effects: Inhalation None anticipated under normal product use conditions. May cause dizziness and nausea from prolonged inhalation. HMIS Ratings: Health: 1 Fire: 1 HMIS Reactivity 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard * * * Section 3 - Composition / Information on Ingredients * * * CAS # Component 51229-78-8 3,5,7-Triaza-1-azoniatricyclo[3.3.1.13, ]decane, 1-(3-chloro-2-propenyl)-, chloride, 8050-81-5 Simethicone 1934-21-0 FD&C yellow No. 5 2353-45-9 Fast green Trade Secret Fragrance 7732-18-5 Water * * * Section 4 - First Aid Measures * * * First Aid: Eyes Immediately flush eyes with plenty of water for at least 15 minutes. If irritation persists get medical attention. First Aid: Skin For skin contact, wash immediately with soap and water. First Aid: Ingestion If the material is swallowed, get immediate medical attention or advice Do not induce vomiting. First Aid: Inhalation Move person to non-contaminated air. If the affected person is not breathing, apply artificial respiration. * * * Section 5 - Fire Fighting Measures * * * General Fire Hazards See Section 9 for Flammability Properties. None Hazardous Combustion Products Not Determined. Extinguishing Media Use extinguishing media appropriate for surrounding fire. Fire Fighting Equipment/Instructions Firefighters should wear full protective gear. Page 64 of 878 Page 64 of 878 Page 64 of 878 Page 64 of 878 ---PAGE BREAK--- Material Safety Data Sheet Material Name: AquaScent (Apple-Pear) Page 2 of 4 Issue Date: 09/26/11 Revision: 1.0000 Print Date: 09/26/11 NFPA Ratings: Health: 1 Fire: 1 Reactivity: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * * * Section 6 - Accidental Release Measures * * * Containment Procedures Contain the discharged material. Clean-Up Procedures Contain spilled material with a suitable absorbent material. Evacuation Procedures Isolate area. Keep unnecessary personnel away. Special Procedures Follow all Local, State, Federal and Provincial regulations for disposal. * * * Section 7 - Handling and Storage * * * Handling Procedures No special handling procedures necessary. Storage Procedures Keep this material in a cool, well-ventilated place. * * * Section 8 - Exposure Controls / Personal Protection * * * A: Component Exposure Limits ACGIH, OSHA, and NIOSH have not developed exposure limits for any of this product's components. Engineering Controls Local exhaust is suggested for use, where possible, in enclosed or confined spaces. PERSONAL PROTECTIVE EQUIPMENT Personal Protective Equipment: Eyes/Face Wear safety glasses with side shields. Personal Protective Equipment: Skin None necessary. Personal Protective Equipment: Respiratory Not normally needed. Personal Protective Equipment: General Eye wash fountain is recommended. * * * Section 9 - Physical & Chemical Properties * * * Appearance: Light Green Odor: Apple-Pear Physical State: Liquid pH: ND Vapor Pressure: ND Vapor Density: ND Boiling Point: >100°C Melting Point: ND Solubility (H2O): Complete Specific Gravity: 1.028@25°C Octanol/H2O Coeff.: ND Flash Point: NA Flash Point Method: ND Upper Flammability Limit (UFL): NA Lower Flammability Limit (LFL): NA Burning Rate: NA Auto Ignition: NA * * * Section 10 - Chemical Stability & Reactivity Information * * * Chemical Stability This is a stable material. Chemical Stability: Conditions to Avoid None Incompatibility None Hazardous Decomposition Not Determined Page 65 of 878 Page 65 of 878 Page 65 of 878 Page 65 of 878 ---PAGE BREAK--- Material Safety Data Sheet Material Name: AquaScent (Apple-Pear) Page 3 of 4 Issue Date: 09/26/11 Revision: 1.0000 Print Date: 09/26/11 Possibility of Hazardous Reactions Will not occur. * * * Section 11 - Toxicological Information * * * Acute Dose Effects A: General Product Information No information available for the product. B: Component Analysis - LD50/LC50 FD&C yellow No. 5 (1934-21-0) Oral LD50 Mouse: 12750 mg/kg Fast green (2353-45-9) Oral LD50 Rat: >2 g/kg Water (7732-18-5) Oral LD50 Rat: >90 mL/kg Carcinogenicity A: General Product Information No information available for the product. B: Component Carcinogenicity Fast green (2353-45-9) IARC: Supplement 7 [1987], Monograph 16 [1978] (Group 3 (not classifiable)) * * * Section 12 - Ecological Information * * * Ecotoxicity A: General Product Information No information available for the product. B: Component Analysis - Ecotoxicity - Aquatic Toxicity No ecotoxicity data are available for this product's components. * * * Section 13 - Disposal Considerations * * * US EPA Waste Number & Descriptions Component Waste Numbers No EPA Waste Numbers are applicable for this product's components. Disposal Instructions All wastes must be handled in accordance with local, state and federal regulations. See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations. * * * Section 14 - Transportation Information * * * US DOT Information Shipping Name: Not Regulated * * * Section 15 - Regulatory Information * * * US Federal Regulations Component Analysis None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix SARA Section 313 (40 CFR 372.65), or CERCLA (40 CFR 302.4). State Regulations Page 66 of 878 Page 66 of 878 Page 66 of 878 Page 66 of 878 ---PAGE BREAK--- Material Safety Data Sheet Material Name: AquaScent (Apple-Pear) Page 4 of 4 Issue Date: 09/26/11 Revision: 1.0000 Print Date: 09/26/11 Component Analysis - State The following components appear on one or more of the following state hazardous substances lists: Component CAS CA MA MN NJ PA RI Fast green 2353-45-9 Yes No No No No No Component Analysis - WHMIS IDL No components are listed in the WHMIS IDL. Additional Regulatory Information Component Analysis - Inventory Component CAS # TSCA CAN EEC FD&C yellow No. 5 1934-21-0 Yes DSL EINECS Fast green 2353-45-9 Yes DSL EINECS 3,5,7-Triaza-1-azoniatricyclo[3.3.1.13, ]decane, 1-(3- chloro-2-propenyl)-, chloride, 51229-78-8 No DSL ELINCS Water 7732-18-5 Yes DSL EINECS Simethicone 8050-81-5 No DSL No * * * Section 16 - Other Information * * * Other Information The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or provincial, and local laws. Key/Legend EPA = Environmental Protection Agency; TSCA = Toxic Substance Control Act; ACGIH = American Conference of Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NIOSH = National Institute for Occupational Safety and Health; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration., = New Jersey Trade Secret Registry. Page 67 of 878 Page 67 of 878 Page 67 of 878 Page 67 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET (COMPLIES WITH 29CFR 1910.1200) SECTION I - CHEMICAL PRODUCT & COMPANY IDENTIFICATION Identity (As Used on Label and List): Astro Product Class: Silicone oil emulsion Emergency Telephone Number: [PHONE REDACTED] Telephone Number for Information: [PHONE REDACTED] Distributed By: Dalco 300 5th Ave NW New Brighton, Minnesota 55112 SECTION II - COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Components (Specific Chemical Identity): Chemical Common Name(s) % A Emulsified silicone oil 1 - 5 (proprietary) B Water 60 - 100 CAS #7732-18-5 SECTION III - HAZARDS IDENTIFICATION Emergency Overview Appearance and Odor: Opaque/white liquid, mild aroma. Primary Hazards: Non-hazardous in normal use. Potential Health Hazards Route(s) of Entry: Skin Absorption: Ingestion: X Inhalation: Eye: No hazards known. Skin: No hazards known. Ingestion: No hazards known. Inhalation: No hazards known. Signs and of Exposure: No effects expected. Carcinogenicity: NTP? No IARC Monographs? No OSHA Regulated? No Target Organ No additional data Medical Conditions Generally Aggravated by Exposure: N. Av. Health Hazards, Chronic: N. Av. SECTION IV - FIRST AID MEASURES Emergency and First Aid Procedures: If Swallowed: Drink water in large amounts and call a physician immediately. Never give anything by mouth to an unconscious person. Eye Contact: Flush eyes with running water for at least 15 minutes. If irritation persists, obtain medical attention. Skin Contact: Flush thoroughly with cool water. Remove and wash contaminated clothing before reuse. Sources Used: Raw material data, general toxicology from the trade for similar products. SECTION V - FIRE FIGHTING MEASURES Flammability: No Autoignition Temperature: N. Ap. Flash Point (method used): None Flammable Limits: N. Ap. LEL UEL Extinguishing Media N. Ap. Water? Foam? Water Fog? Alcohol Foam? CO2? Dry Chemical? Vaporizing Liquid? Other? Special Fire Fighting Procedures: N. Ap. Unusual Fire and Explosion Hazards: N. Av. TDG Flammability Classification: Non-flammable Sensitivity to Mechanical Impact: None Sensitivity to Static Discharge: None SECTION VI - ACCIDENTAL RELEASE MEASURES Steps to be Taken in Case Material is Released or Spilled: Dike and contain spill with inert material (sand, earth, etc). Collect spill with mop, absorbent material (example: floor-dri) or vacuum. Thoroughly rinse affected area with water. SECTION VII - HANDLING AND STORAGE Precautions to be Taken in Handling and Storing: Normal care in handling and storage. Other Precautions: Keep out of reach of children. Keep from freezing. SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION Respiratory Protection (Specify Types): Not required Ventilation: Local Exhaust: Not required Special: Not required Mechanical (General): Normal good ventilation sufficient. Other: Not required Protective Gloves: Natural rubber or Eye Protection: Approved safety goggles or glasses. Footwear: Not required Other Protective Clothing or Equipment: Not required Work/Hygienic Practices: Do not contaminate food or beverages with cleaning chemicals. SECTION IX - PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: Approximately 212°F (100°C) pH: 8 - 9 Specific Gravity (H20) = 1: 1.00 % Volatile: > 90 Vapor Density (Air = N. Av. Odor Threshold: N. Av. Evaporation Rate (Butyl Acetate = N. Av. Oil/Water Distribution Solubility in Water: Complete Coefficient: N. Av. Vapor Pressure (MM HG): N. Av. Melting Point: N. Ap. SECTION X - STABILITY AND REACTIVITY Stability: Unstable: Stable: X Conditions to Avoid: N. Ap. Incompatibility (materials to avoid): N. Av. Hazardous Decomposition or By-products: N. Av. Hazardous Polymerization: May occur: Will not occur: X Conditions to Avoid: N. Ap. SECTION XI - TOXICOLOGICAL INFORMATION Chemical OSHA PEL ACGIH TLV Recom. LD50 LC50 A None None N. Av. N. Av. N. Av. B None None N. Av. N. Av. N. Av. Teratogen, Mutagen, Reproductive Toxin Status: No Toxicologically Synergistic Products: N. Av. SECTION XII - ECOLOGICAL INFORMATION Biodegradation Properties: N. Av. Ecotoxicological Information: N. Av. Chemical Fate Information: N. Av. SECTION XIII - DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose of spilled material in accordance with local, state and federal regulations. Waste from normal cleaning procedures may be sewered, depending on the materials and/or contaminates being cleaned as well as state, federal and local sewer commission regulations. RCRA Hazard Class: None SECTION XIV - TRANSPORT INFORMATION Shipping Classification: Compound, cleaning liquid, N.O.I. UN Number: N. Ap. Packing Group: N. Ap. SECTION XV - PREPARATION DATA Prepared By: James Tracy Telephone Number: [PHONE REDACTED] Date: 1/02 SECTION XVI - REGULATORY INFORMATION US Federal Regulations TSCA Status: All ingredients listed. CERCLA Reportable Quality: None SARA Title III Section 302 Extremely Hazardous Chemicals: None Section 311/312 Hazard Category: None Section 313 Toxic Chemicals: None State Regulations NOTICE STATE OF CALIFORNIA Warning: This product may contain chemicals known to the State of California to cause cancer or reproductive defects as trace impurities in the standard industrial materials used in the manufacture of this product. International Regulations WHMIS Controlled Product Hazard Class: N. Ap. SECTION XVII - OTHER INFORMATION None N. Ap. - Not Applicable; N.Av. - Not Available NFPA SYSTEM A. Health Hazard A. Fire Hazard A. Reactivity Hazard THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE, HOWEVER NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. MINUTEMAN INTERNATIONAL, INC. ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE TO VENDEES, USERS OR THIRD PARTIES CAUSED BY THE MATERIAL. SUCH VENDEES OR USERS ASSUME ALL RISKS ASSOCIATED WITH THE USE OF THE MATERIAL. Page 68 of 878 Page 68 of 878 Page 68 of 878 Page 68 of 878 ---PAGE BREAK--- èèè MSDS Text Page Follows èèè 159 Material Safety Data Sheet 98 The Sherwin-Williams Co. Emergency telephone number (216) 566-2917 101 Prospect Ave. N.W. Information telephone number (216) 566-2902 Cleveland, OH 44115 Date of preparation May 18, 1998 ©1998, The Sherwin-Williams Co. — Section 1 — Product Identification 111-77-3 2-(2-Methoxyethoxy)-ethanol Not Established 1.0 3 3 3 3 3 111-76-2 2-Butoxyethanol 25 25 PPM (Skin) 0.6 2 112-34-5 2-(2-Butoxyethoxy)-ethanol Not Established 0.1 3 3 3 1 1 1 107-21-1 Ethylene Glycol. C 50 50 PPM 0.1 2 - 4 1 - 3 1 - 3 1 - 3 2 108419-35-8 Oxo-Tridecyl Acetate. Not Established 0.0 2 2 2 1 2 14808-60-7 Quartz 0.1 0.1 Mg/M3 11 112926-00-8 Amorphous Precipitated Silica 10 6 MG/M3 as Dust 1 14464-46-1 Cristobalite 0.05 0.05 Mg/M3 0.1 0.1 0.1 0.2 0.1 14807-96-6 Talc 2 2 Mg/M3 10 12001-26-2 Mica 3 3 Mg/M3 4 471-34-1 Calcium Carbonate. 10 15[5] 11 26 27 13463-67-7 Titanium Dioxide. 10 10[5] 17 12 11 23 9 9 9 1314-13-2 Zinc Oxide 10 10[5] 1 1333-86-4 Carbon Black. 3.5 3.5 Mg/M3 0 - 1 0 - 1 0 - 1 0 - 1 Zinc Compound. Zinc] 2 [1.4] 2 [1.1] 3 [1.6] Barium Compound. Barium] 5 [2.6] Weight per Gallon (lbs.) 10.21 9.68 9.58 8.80 10.67 11.19 11.46 11.45 9.24 Solids by Weight 49.7 45.7 44.8 38.4 52.7 57.7 61.2 61.2 29.0 Solids by Volume 38.3 36.6 36.2 34.6 39.3 43.0 46.2 46.3 20.6 Percent Water 42.2 45.1 46.7 53.3 39.0 40.7 33.4 33.1 67.8 VOC (Volatile Organic Compounds) Total - lbs./gal. 0.80 0.86 0.78 0.71 0.86 0.16 0.60 0.64 0.28 VOC Less Water & Federally Exempt Solvents - lbs./gal. 1.66 1.81 1.69 1.63 1.72 0.35 1.12 1.18 1.16 Photochemically Reactive No No No No No No No No No Flash Point NAp NAp NAp NAp NAp NAp NAp NAp NAp HMIS (NFPA) Rating (health - flammability - reactivity) 2* - 0 - 0 2* - 0 - 0 2* - 0 - 0 2* - 0 - 0 2* - 0 - 0 1* - 0 - 0 2 - 0 - 0 2 - 0 - 0 2 - 0 - 0 Ingredient subject to the reporting requirements of the Superfund Amendments and Reauthorization Act (SARA) Section 313, 40 CFR 372.65 C § § § § as Resp. Dust as Resp. Dust as Resp. Dust as Resp. Dust Mg/M3 as Dust [Resp. Fraction] Mg/M3 as Dust [Resp. Fraction] Mg/M3 as Dust [Resp. Fraction] § § § — Section 2 — Pure Midtone Deeptone Ultradeep Ultra Off Primer Barium Free Wash (percent by weight) White Base Base Base White White White Primer White Primer ACGIH OSHA Vapor B66W201 B66W202 B66W203 B66T204 B66W200 B66A50 B66W1 B66WW10 B71Y1 CAS No. Hazardous Ingredients TLV PEL Units Pressure (mm Hg) DTM Acrylic Semi-Gloss Enamel B66/2 P E R C E N T B Y W E I G H T Page 69 of 878 Page 69 of 878 Page 69 of 878 Page 69 of 878 ---PAGE BREAK--- 160 Section 7 — Spill Or Leak Procedures STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate and remove with inert absorbent. WASTE DISPOSAL METHOD Waste from B66W1 may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for extractability to determine the applicable EPA hazardous waste numbers. Waste from other products is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate all products in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State, and Local regulations regarding pollution. Section 8 — Protection Information PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid breathing vapor and spray mist. Avoid contact with skin and eyes. Wash hands after using. These coatings may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg./m3 (total dust), 3 mg./m3 (respirable fraction), OSHA PEL 15 mg./m3 (total dust), 5 mg./m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding, wirebrushing, abrading, burning or welding the dried film, wear a particulate respirator approved by NIOSH/MSHA for protection against non-volatile materials in Section 2. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. Section 9 — Precautions DOL STORAGE CATEGORY - Not applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Section 10 — Other Regulatory Information CALIFORNIA PROPOSITION 65 WARNING: B66E39, B66T204, B66W200, B66W201, B66W202, B66W203 and B66Y37 contain a chemical known to the State of California to cause cancer. B66A50, B66W1, B66WW10 and B71Y1 contain chemicals known to the State of California to cause cancer. TSCA CERTIFICATION All chemicals in these products are listed, or are exempt from listing, on the TSCA Inventory. This Material Safety Data Sheet conforms to the Hazard Communication standard, 29 CFR 1910.1200(g)(4), for similar complex mixtures. The above information pertains to these products as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to these products may substantially alter the composition and hazards of the products. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Section 3 — Physical Data PRODUCT WEIGHT See TABLE EVAPORATION RATE Slower than Ether SPECIFIC GRAVITY 1.03-1.38 VAPOR DENSITY Heavier than Air BOILING RANGE 212-545 °F MELTING POINT N.A. VOLATILE VOLUME 53-79 % SOLUBILITY IN WATER N.A. pH 8.5-9.5 Section 4 — Fire And Explosion Hazard Data FLAMMABILITY CLASSIFICATION FLASH POINT See TABLE LEL N.Ap. UEL N.Ap. Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 5 — Health Hazard Data ROUTES OF EXPOSURE Exposure may be by INHALATION and/or SKIN or EYE contact, depending on conditions of use. To minimize exposure, follow recommendations for proper use, ventilation, and personal protective equipment. ACUTE Health Hazards EFFECTS OF OVEREXPOSURE Irritation of eyes, skin and upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. EMERGENCY AND FIRST AID PROCEDURES If INHALED: If affected, remove from exposure. Restore breathing. Keep warm and quiet. If on SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If in EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. If SWALLOWED: Get medical attention. CHRONIC Health Hazards Carbon Black is classified by IARC as possibly carcinogenic to humans (group 2B) based on experimental animal data, however, there is insufficient evidence in humans for its carcinoge- nicity. Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. Ethylene Glycol is considered an animal teratogen. It has been shown to cause birth defects in rats and mice at high doses when given in drinking water or by gavage. There is no evidence to indicate it causes birth defects in humans. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary and blood forming systems. Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung cancer, however, such exposure levels are not attainable in the workplace. Section 6 — Reactivity Data STABILITY — Stable CONDITIONS TO AVOID — None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide, Oxides of Metals in Section 2 HAZARDOUS POLYMERIZATION — Will Not Occur DTM Acrylic Enamel B66 covers MSDS pages B66/1 and B66/2 Page 70 of 878 Page 70 of 878 Page 70 of 878 Page 70 of 878 ---PAGE BREAK--- M A T E R I A L S A F E T Y D A T A S H E E T Manufacturer's Name 24 Hour Emergency Telephone No. BENJAMIN MOORE & CO. LIMITED [PHONE REDACTED] (CANUTEC) 139 MULOCK AVENUE TORONTO, ONTARIO M6N 1G9 SECTION I - PRODUCT IDENTIFICATION TRADE NAME: Benjamin Moore Collection Latex High Gloss Enamel PLANT CODE: 309-01 SYNONYMS: Not applicable CHEMICAL NAME: Mixture MOL. FORMULA: Mixture C.A.S. NUMBER: Mixture GENERIC NAME: Latex paint PRODUCT USE: Finish coat TRANSPORT OF DANGEROUS GOODS: Not Regulated in small containers SHIPPING NAME: n/a CLASSIFICATION: n/a UN n/a PACKING GROUP: n/a WHMIS CLASSIFICATION: D2B, Other Toxic Effects SECTION II - HAZARDOUS INGREDIENTS INGREDIENT CAS NUMBER %WT TLV LD50/LC50 Titanium Dioxide 13463-67-7 10 – 30 10 mg/m3 not established Propylene Glycol 57-55-6 1 – 5 not oral, rat established 20 g/kg SECTION III - PHYSICAL DATA The following physical data are approximate only and do not represent specification values. They should only be used in the context of this Material Safety Data Sheet. BOILING RANGE ~ 100 SPECIFIC GRAVITY (20 1.10 - 1.30 VAPOUR PRESSURE (kPa): 2.3 @ 20 °C VAPOUR DENSITY (air = > 1 WATER SOLUBILITY: Soluble VOLATILITY by vol): 60 - 70 FREEZING POINT < 0 ODOUR THRESHOLD: Not known OIL/WATER DISTRIBUTION COEFFICIENT: Not known pH: 8 - 9.5 EVAPORATION RATE (butyl acetate = < 1 PHYSICAL STATE: Liquid APPEARANCE & ODOUR: Thick white liquid with mild odour SECTION IV - FIRE & EXPLOSION HAZARDS FLASH POINT n/a METHOD: n/a FLAMMABLE LIMITS in air); LOWER: n/a UPPER: n/a AUTOIGNITION TEMPERATURE Not known FLAMMABILITY CLASSIFICATION: Non-combustible aqueous based liquid CONDITIONS OF FLAMMABILITY: Not applicable EXTINGUSHING MEDIA: Not applicable FIRE FIGHTING PROCEDURES: Sealed containers may explode if they become overheated in a fire. Cool containers with a water mist or fog. FIRE & EXPLOSION HAZARD: Page 71 of 878 Page 71 of 878 Page 71 of 878 Page 71 of 878 ---PAGE BREAK--- Not sensitive to static discharge or mechanical impact. HAZARDOUS COMBUSTION PRODUCTS: Hazardous combustion products may include oxides of carbon and nitrogen and smoke. SECTION V - REACTIVITY LEVEL OF STABILITY: Stable CONDITIONS TO AVOID: None. INCOMPATIBILITY: Avoid oxidizing agents, strong acids and strong bases. HAZARDOUS DECOMPOSITION PRODUCTS: May produce oxides of carbon and nitrogen. HAZARDOUS POLYMERIZATION: Will not occur. POLYMERIZING AGENTS TO AVOID: None. SECTION VI - TOXICOLOGICAL PROPERTIES THRESHOLD LIMIT VALUE: Not established EFFECTS OF EXPOSURE: Exposure to vapour and mist is unlikely to cause health effects. Vapour concentrations are normally too low at room temperature to cause observable health effects. When spraying avoid breathing mist or back-spray. In contact with the eyes the product may cause mild irritation but is not expected to cause tissue damage. May cause irritation in prolonged contact with skin. Ingestion of the product may cause irritation of the lining of the stomach. It may also cause nausea, discomfort, CN depression and vomiting. Always use proper safety and hygiene practices as described below. TOXICOLOGICALLY SYNERGISTIC PRODUCTS: None known. OTHER HEALTH HAZARDS: None of the ingredients are listed as sensitizers, carcinogens, reproductive toxins, teratogens or mutagens. AQUATIC TOXICITY: Not available SECTION VII - EMERGENCY FIRST AID In case of inhalation, remove victim to fresh air and administer artificial respiration if breathing has stopped. Obtain medical assistance immediately. In case of contact with eyes, flush with large amounts of water until irritation subsides. If irritation persists, obtain medical attention. For contact with skin, flush with large amounts of cold water. Use soap if available. Remove contaminated clothing after flushing has begun. Wash contaminated clothing before reuse. If ingested, do NOT induce vomiting. Keep at rest and obtain medical assistance immediately. If victim is conscious have victim drink 240 to 300 mL of water to dilute. SECTION VIII - PREVENTIVE MEASURES PERSONAL PROTECTIVE EQUIPMENT: Use NIOSH approved respirator specified for protection against paint spray mist and organic vapours in restricted and confined areas. Wear coverall chemical goggles to protect against splashes. Wear solvent resistant gloves to protect hands. Page 72 of 878 Page 72 of 878 Page 72 of 878 Page 72 of 878 ---PAGE BREAK--- STEPS TO BE TAKEN IF MATERIAL IS SPILLED OR RELEASED: Dike Spill. Do NOT flush into sewers. As a general precaution, remove all sources of ignition and only use non-sparking tools. Absorb with inert material. WASTE DISPOSAL METHODS: Dispose of in accordance with local regulations. STORAGE AND HANDLING: Keep container closed when not using product. Store in cool, well-ventilated area, away from all sources of ignition. Keep from freezing. SPECIAL ENGINEERING CONTROLS: None. SECTION IX - PREPARATION INFORMATION REGULATORY AFFAIRS DEPARTMENT BENJAMIN MOORE & COMPANY LIMITED December 2005 (201) 573-9600 n/e = not established n/a = not available SECTION X - NOTICE OF DISCLAIMER The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, provincial, and local laws and regulations. Page 73 of 878 Page 73 of 878 Page 73 of 878 Page 73 of 878 ---PAGE BREAK--- ---PAGE BREAK--- ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET: BERRY BLAST (12X12 OZ) Section I - General Information (000000-000000- - 5774) Date of Issue: 7/18/2007 12:00:00 AM Supercedes: 4/30/2007 12:00:00 AM Chemical Name & Synonyms: N/A Trade Name & Synonyms: BERRY BLAST (12X12 OZ) Chemical Family: ESTER AND HYDROCARBON MIXTURE Formula is a mixture: Manufacturer Name: CHEMSEARCH DIV. OF NCH CORP. Manufacturer Address: BOX 152170 IRVING, TX 75015 Prepared By: E LEVI/CHEMIST Product Code Number: 5774 Emergency Phone Number: [PHONE REDACTED] Section II - Hazardous Ingredients THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS Chemical Name (Ingredients) Hazard TLV PEL STEL CAS # AMYL ACETATE IRR/COMB 50 ppm $1 100 ppm 3 100 ppm $1 628-63-7 N-BUTYL ACETATE IRRITANT 150 ppm 1 150 ppm 3 200 ppm 1 123-86-4 ETHYL BUTYRATE IRR/COMB N/E 1 N/E 1 N/E 105-54-4 D-LIMONENE COMB/SENS N/E 1 5 mg/m3*2 N/E 5989-27-5 ISOPARAFFINIC HYDROCARBON IRR/COMB 5 mg/m3 #1 5 mg/m3 #2 10 mg/m3#1 64742-47-8 $ PENTYL ACETATE, ALL ISOMERS # OIL MIST VALUES * VEGETABLE OIL VALUE Section III - Physical Data Boiling Point (°F):415 Specific Gravity (H20=1):0.8 Vapor Pressure (mm Hg):0.3 Color:Yellow Vapor Density (Air=1):5.5 Odor:Mulberry pH @ 100% :N/A Clarity:Transparent % Volatile by Volume:99 Evaporation Rate (BuAc=1):0.02 H20 Solubility:Negligible Viscosity:Non-Viscous Section IV - Fire and Explosion Hazard Flash Point: 160°F Method Used: SetaFlash Flammable Limits: PRODUCT MIXTURE UEL: 8.8% LEL: 0.7% Aerosol Level (NFPA 30B): N/A Extinguishing Media: Foam [ ] Alcohol Foam CO2 Dry Chemical Water Spray [ ] Other NFPA 704 Hazard Rating: 4-Extreme 3-High 2-Moderate 1-Slight 0-Insignificant Health: 1 Flammability: 2 Instability: 0 Special: Special Fire Fighting Procedures: Firefighters should wear a self-contained breathing apparatus and full protective gear. Cool fire-exposed containers with water spray to prevent bursting. Unusual Fire and Explosion Hazards: The use of water spray (fog), while effective, may cause frothing and foaming. Never use a water jet as this will just spread the fire. Product may produce a floating fire hazard as liquid floats on water. Vapors are heavier than air and may travel to distant and/or low-lying sources of ignition and flashback. Use care as spills may be slippery. Section V - Health and Hazard Data Threshold Limit Value: Not Established for Mixture. See Section II. Effects of Overexposure: Acute: (Short Term Exposure) EYE CONTACT: Causes irritation seen as redness, stinging, tearing, and blurred vision. SKIN CONTACT: Causes irritation seen as itching and redness. Prolonged or repeated contact may cause drying, defatting, and cracking of the skin. May cause allergic skin reactions seen as delayed skin rash which may be followed by blistering, scaling, and other skin effects. INHALATION: Vapors or mists may cause respiratory irritation seen as coughing and sneezing. At low vapor concentrations, no harmful effects are expected. At high vapor concentrations, inhalation may cause central nervous system effects such as headache, dizziness, drowsiness, weakness, unconciousness, possible anesthetic effects from central nervous system depression, and may be fatal. INGESTION: May cause irritation with possible nausea, vomiting, and diarrhea. Ingestion and subsequent vomiting of this product can lead to aspiration of the product into the lungs which can cause damage and may be fatal. Chronic: (Long Term Exposure) May cause skin and respiratory sensitization in some individuals. On rare occasions, prolonged and repeated exposure to hydrocarbon mist poses a risk of chronic lung inflammation. This condition is usually as a result of repeated small aspirations. Shortness of breath and coughing are the most common Aspiration may lead to pulmonary edema and hemorrhage and may be fatal. Signs of lung involvement include increased respiration and heart rates as well as a bluish discoloration of the skin. Chronic skin contact may promote dermatitis and oil acne. In rarer cases, an increased senstivity to sunlight (photosensitivity) may occur. Medical conditions aggravated by exposure are pre-existing respiratory and skin conditions such as asthma, and dermatitis. TARGET ORGANS: Blood-Forming Organs, Central Nervous System, Liver, and Lungs. The primary routes of exposure are skin and eye contact. Primary Routes of Entry Inhalation [ ] Ingestion Absorption Emergency First Aid Procedures: 1 of 3 Page 76 of 878 Page 76 of 878 Page 76 of 878 Page 76 of 878 ---PAGE BREAK--- Inhalation: Remove from the area to fresh air. Seek medical attention if respiratory irritation develops or if breathing becomes difficult. Eye Contact: Rinse the eyes with water. Remove any contact lenses and continue flushing with plenty of water for several minutes. Seek medical attention if irritation develops. Skin Contact: Wash affected areas with large amounts of soap and water for 15 minutes. Remove contaminated clothing and shoes. Seek medical attention if irritation persists. Wash clothing and clean shoes before re-use. Ingestion: Give 3 to 4 glasses of water, but DO NOT induce vomiting. If vomiting occurs, give fluids again. Get immediate medical attention. Do not give anything by mouth to an unconscious or convulsing person. Notes to Physician: Ingestion and subsequent vomiting of this product can lead to aspiration of the product into the lungs which can cause damage and may be fatal. Depending on the amount ingested and retained as well as the toxicity of the product, gastric lavage should be considered. Keep patient's head below hips to prevent pulmonary aspiration. If comatose, a cuffed endotrachael tube will prevent aspiration. In the event of injection in underlying tissue, immediate treatment should include extensive incision, debridement and saline irrigation. Inadequate treatment can result in ischemia and gangrene. Early may be minimal. Section VI - Toxicity Information Product Contains Chemicals Listed as Carcinogen or Potential Carcinogen By: [ ] IARC [ ] NTP [ ] OSHA [ ] ACGIH [ ] Other VOC Content: 100% by weight; 100% by volume; 800 g/L AMYL ACETATE EYE-HMN SDT: 300 ppm 4. IHL-HMN TCLo: 5,000 mg/m3/30m 4. ORL-RAT LD50: >1,600 mg/kg 4. Overexposure to this material has been suggested as a cause of liver damage in laboratory animals. N-BUTYL ACETATE IHL-RAT LC50: 390 ppm/4h 4. ORL-RAT LD50: 10,768 mg/kg 4. SKN-RBT LD50: >17,600 mg/kg 4. SKN-RBT SDT: 500 mg/24h Moderate 4. EYE-RBT SDT: 100 mg Moderate 4. EYE-HMN SDT: 300 ppm 4. ETHYL BUTYRATE ORL-RAT LD50: 13 gm/kg 4. ORL-RBT LD50: 5,228 mg/kg 4. SKN-RBT LD50: >2 gm/kg 4. SKN-RBT SDT: 500 mg/24h Moderate 4. D-LIMONENE IPT-RAT LD50: 3600 mg/kg 4. ORL-RAT LD50: 4,400 mg/kg 4. SKN-RBT LD50: >5 gm/kg 4. SKN-RBT SDT: 10%/24h Mild 4. SKN-RAT SDT: 100%/1h 4. ISOPARAFFINIC HYDROCARBON DMSO EXTRACTABLES) IHL-RAT LC50: >290 ppm 3. ORL-RAT LD50: >10 g/kg 3. SKN-RBT LD50: >3 g/kg 3. SKN SENSITIZER: No 3. SKN IRRITATION: Slight 3. EYE IRRITATION: Slight 3. This hydrocarbon was administered orally 5 days/week to male and female rats at 100, 500 or 1000 mg/kg for 13 weeks. An additional group was dosed with 100 mg/kg for 13 weeks followed by a 4-week recovery period. No mortalities or clinical effects were observed. Liver and kidney weights for the 500 and 1000 mg/kg exposure groups were significantly increased. After the 4-week recovery period, there were no differences in organ weights. 3. Hydrocarbon mists derived from petroleum distillates are reported to have low acute and sub-acute toxicities in animals. Effects from single and short-term repeated exposures to high concentrations well above applicable workplace exposure levels include lung inflammatory reaction, lipoid granuloma formation, and lipoid pneumonia. In acute and sub-acute studies involving exposures to lower concentrations at or near current work place exposure levels produced no significant toxicological effects. In long term studies (up to two years) no carcinogenic effects have been reported in any animal species tested. These petroleum distillates are severely hydrotreated, severely solvent extracted, and/or processed by mild hydrotreatment and extraction. For this reason, they are not classified as cancer hazards. 3. Section VII - Reactivity Data Stability Stable [ ] Unstable Conditions to Avoid: Avoid heat, hot surfaces, sparks, and open flames. Hazardous Polymerization Will not occur [ ] May occur Conditions to Avoid: N/A Incompatibility (Materials to Avoid): Strong oxidizing agents such as Chlorine bleach and concentrated Hydrogen Peroxide. Hazardous Decomposition Products: Oxides of Carbon. Section VIII - Spill Or Leak Procedures Steps to be Taken if Material is Released or Spilled: MATERIAL SAFETY DATA SHEET: BERRY BLAST (12X12 OZ) MATERIAL SAFETY DATA SHEET: BERRY BLAST (12X12 OZ) MATERIAL SAFETY DATA SHEET: BERRY BLAST (12X12 OZ) MATERIAL SAFETY DATA SHEET: BERRY BLAST (12X12 OZ) 2 of 3 Page 77 of 878 Page 77 of 878 Page 77 of 878 Page 77 of 878 ---PAGE BREAK--- ©2008 NCH Corporation All rights reserved. Wear appropriate protective clothing. Eliminate all sources of ignition and ventilate the area. Use only non-sparking equipment. Use care as spills may be slippery. Shut off source of leak. Dike and contain spill. Absorb with an inert material and transfer all material into a properly labeled container for disposal. Prevent product from contaminating soil or from entering sewage and drainage systems and bodies of water. Flush area with water. Waste Disposal Method(s): Dispose of in accordance with all Federal, state, and local regulations. Neutralizing Agent: N/A Section IX - Special Protection Information Required Ventilation: Local ventilation is recommended to control exposure from operations that can generate excessive levels of mists or vapors. Local ventilation is preferred, because it prevents dispersion into work areas by controlling it at its source. Respiratory Protection: Respirators should be selected by and used under the direction of a trained health and safety professional following requirements found in OSHA's respirator standard (29 CFR 1910.134) and ANSI's standard for respiratory protection (Z88.2-1992). For concentrations above the TLV and/or PEL but less than 10 times these limits, a NIOSH approved half-facepiece respirator equipped with appropriate chemical cartridges may be used. For concentrations greater than 10 times the TLV and/or PEL, consult the NIOSH respirator decision logic found in publication No. 87-116 or ANSI Z88.2-1992. Glove Protection: Neoprene or nitrile rubber gloves if repeated or prolonged skin contact is likely. Ensure compliance with OSHA's personal protective equipment (PPE) standard for hand protection, 29 CFR 1910.138. Eye Protection: Safety glasses with side shields if the method of application presents the likelihood of eye contact. Ensure compliance with OSHA's Personal Protective Equipment (PPE) standard for eye and face protection, 29 CFR 1910.133. Other Protection: Wear protective clothing when handling. A safety shower and an eyewash station should be available. Section X - Storage and Handling Information Storage Temperature Max: 120°F Min: 35°F Storage Conditions Indoors [ ] Outdoors [ ] Heated [ ] Refrigerated Precautions to be Taken in Handling and Storing: Always store material in its original container. Keep the container closed when not in use. Use with caution around heat, sparks, pilot lights, static electricity, and open flame. Empty containers may contain product residues which may exhibit the hazards of the product. To avoid possible explosion, do not pressurize, cut, weld, solder, drill, grind, or expose empty containers to heat, hot surfaces, sparks, or open flames. Ground and bond container when handling near flammable vapors and all sources of ignition. Other Precautions: Keep out of reach of children. Read the entire label before using the product. Follow the label directions. Section XI - Regulatory Information Chemical Name CAS Number Upper % Limit None. Those Ingredients listed above are subject to the reporting requirements of 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372. Please call 1-[PHONE REDACTED] for additional information if you are a California customer. This MSDS is not intended for users in the state of California. Section XII - References 1. Threshold Limit Values for chemical substances and physical agents and biological exposure indices, ACGIH, 2007. 2. OSHA PEL. 3. Vendor's MSDS. 4. Registry of toxic effects of chemical substances, CCINFOWeb, 2007. 5. European Chemical Substances Information System (ESIS), International Uniform Chemical Information Database (IUCLID) Chemical Data Sheets. All the components of this product are in compliance with the Toxic Substances Control Act (TSCA) and are either listed on the TSCA inventory or otherwise exempted from listing. IRR: Irritant, OSHA: Occupational Safety & Health Administration, IARC: International Agency for the Research on Cancer, TOX: Toxic, NFPA: National Fire Protection Association, ppm: Parts Per Million, UEL: Upper Explosion Limit, STEL: Short-term Exposure Limit, SKN: Skin, IHL: Inhalation, COMB: Combustible, CORR: Corrosive, MUT: Mutagenic, CARC: Carcinogenic, N/A: Not Applicable, TLV: Threshold Limit Value, N/E: Not Established, ORL: Oral, FLAM: Flammable, C.O.C.: Cleveland Open Cup, PNOR: Particles Not Otherwise Regulated, LEL: Lower Explosion Limit, mg/L: Milligrams per Liter, PNOS: Particles Not Otherwise Specified, g/L: Grams per Liter, PMCC: Pensky-Martin Closed Cup, NTP: National Toxicology Program, µg/L: Micrograms per Liter, TCC: Tagliabue Closed Cup, SEV: Severe, RBT: Rabbit, INV: Intravenous, ACGIH: American Conference of Governmental Industrial Hygienists, PEL: Permissible Exposure Limit, MOD: Moderate, IPT: Intraperitoneal, gm/kg: Grams per Kilogram, C.C.C.: Cleveland Closed Cup, HMN: Human, mg/m3: Milligrams per Cubic Meter, mg/kg: Milligrams per Kilogram, VOC: Volatile Organic Compound, SDT: Standard Draize Test, MSE: Mouse, GPG: Guinea Pig. THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE IN LIGHT OF CURRENT FORMULATION. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. CHEMSEARCH DIV. OF NCH CORP. assumes no responsibility for personal injury or property damage caused by the use, storage, or disposal of the product in a manner not recommended on the product label. Users assume all risks associated with such unrecommended use, storage, or disposal of the product. MATERIAL SAFETY DATA SHEET: BERRY BLAST (12X12 OZ) MATERIAL SAFETY DATA SHEET: BERRY BLAST (12X12 OZ) MATERIAL SAFETY DATA SHEET: BERRY BLAST (12X12 OZ) MATERIAL SAFETY DATA SHEET: BERRY BLAST (12X12 OZ) 3 of 3 Page 78 of 878 Page 78 of 878 Page 78 of 878 Page 78 of 878 ---PAGE BREAK--- Material Safety Data Sheet: BERRY BLAST (12X12 OZ) Supercedes Date 07/18/2007 Issuing Date 07/19/2010 1. PRODUCT AND COMPANY IDENTIFICATION Product Name BERRY BLAST (12X12 OZ) Product Code 5774 Recommended Use Fragrance Chemical Nature Petroleum distillates Information on Manufacturer Emergency Telephone Number CHEMSEARCH DIV. OF NCH CORP. CHEMTREC ® [PHONE REDACTED] BOX 152170 IRVING, TX 75015 2. HAZARDS IDENTIFICATION Emergency Overview WARNING Combustible liquid and vapor Causes skin irritation Causes eye irritation May cause allergic skin reaction May be harmful if inhaled May cause allergic respiratory reaction May be harmful if swallowed Color Yellow Physical State Liquid Odor Fruity Potential Health Effects Principle Route of Exposure Skin contact, Eye contact, Inhalation. Primary Routes of Entry Inhalation, Skin Absorption. Acute Effects Eyes Causes eye irritation. Skin Causes skin irritation. May cause allergic skin reaction. Inhalation May cause irritation of respiratory tract. Inhalation may cause central nervous system effects. May cause central nervous system depression. and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. May cause allergic respiratory reaction. Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Aspiration hazard if swallowed - can enter lungs and cause damage. May be fatal if swallowed and enters airways. Chronic Toxicity May cause sensitization by skin contact, May cause sensitization by inhalation, Liver and kidney injuries may occur. Target Organ Effects Central nervous system, Cardiovascular system, Respiratory system, Liver, Kidney, Lungs, Bone Marrow. Aggravated Medical Conditions Respiratory disorders, Skin disorders, Liver disorders, Kidney disorders, Neurological disorders. Potential Environmental Effects See Section 12 for additional Ecological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Component CAS-No Ethyl Butyrate 105-54-4 n-Butyl acetate 123-86-4 D-Limonene 5989-27-5 n-Amyl acetate 628-63-7 Petroleum distillates, hydrotreated light 64742-47-8 4. FIRST AID MEASURES General Advice Avoid contact with skin, eyes and clothing. Avoid breathing vapors or mists. Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. Get medical attention if irritation develops and persists. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention if irritation develops and persists. Wash contaminated clothing before re-use. Inhalation If inhaled, remove to fresh air. Get medical attention if occur. Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately. Never give anything by mouth to an unconscious person. Notes to Physician May cause sensitization of susceptible persons. Aspiration hazard if swallowed - can enter lungs and cause damage. 5. FIRE-FIGHTING MEASURES Flash Point 160°F/71°C Method Seta closed cup Autoignition Temperature No information available. Flammability Limits in Air % Mixture. Upper 8.8 Lower 0.6 Suitable Extinguishing Media Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Specific hazards arising from the chemical Combustible Liquid. Solvent vapors are heavier than air and may spread along floors. Vapors may ignite and explode. Material can create slippery conditions. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 1 Flammability 2 Instability 0 HMIS Health 1 Flammability 2 Instability 0 Page 1 / 4 Page 79 of 878 Page 79 of 878 Page 79 of 878 Page 79 of 878 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Use personal protective equipment. Remove all sources of ignition. Ensure adequate ventilation. Prevent further leakage or spillage if safe to do so. Material can create slippery conditions. Environmental Precautions Do not flush into surface water or sanitary sewer system. Methods for Containment Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Methods for Cleaning Up Use clean non-sparking tools to collect absorbed material. Pick up and transfer to properly labeled containers. Neutralizing Agent Not applicable. 7. HANDLING AND STORAGE Handling Keep away from open flames, hot surfaces and sources of ignition. Avoid contact with skin, eyes and clothing. Avoid breathing vapors or mists. Storage Keep away from heat and sources of ignition. Store in original container. Keep containers closed in a dry, cool and well- ventilated place. Storage Temperature Minimum 35°F/2°C Maximum 120°F/49°C Storage Conditions Indoor X Outdoor Heated Refrigerated 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH Ethyl Butyrate No data available No data available No data available n-Butyl acetate 200 ppm STEL : 150 ppm TWA 150 ppm TWA; 710 mg/m3 TWA 1700 ppm IDLH (10% LEL) : 150 ppm TWA; 710 mg/m3 TWA 200 ppm STEL; 950 mg/m3 STEL D-Limonene No data available No data available No data available n-Amyl acetate 100 ppm STEL : 50 ppm TWA 100 ppm TWA; 525 mg/m3 TWA 1000 ppm IDLH : 100 ppm TWA; 525 mg/m3 TWA Petroleum distillates, hydrotreated light 5 mg/m3 as oil mist 10 mg/m3 as oil mist No data available Engineering Measures Ensure adequate ventilation, especially in confined areas. Personal Protective Equipment Eye/Face Protection Safety glasses with side-shields. Skin Protection Wear suitable protective clothing, Impervious gloves. Respiratory Protection In case of inadequate ventilation wear respiratory protection. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. General Hygiene Considerations Ensure that eyewash stations and safety showers are close to the workstation location. Remove and wash contaminated clothing before re-use. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Viscosity Non viscous Color Yellow Odor Fruity Appearance Transparent pH Not applicable Specific Gravity 0.80 Evaporation Rate 0.01 (Butyl acetate=1) Percent Volatile (Volume) 99 VOC Content 100 VOC Content (g/L) 100 Vapor Pressure No information available Vapor Density No information available Solubility Insoluble Boiling Point/Range 415°F/213°C 10. STABILITY AND REACTIVITY Chemical Stability Stable. Hazardous polymerization does not occur. Conditions to Avoid Heat, flames, and sparks Incompatible Products Strong oxidizing agents Hazardous Decomposition Products Carbon oxides Possibility of Hazardous Reactions None under normal processing. 11. TOXICOLOGICAL INFORMATION Product Information No information available. Component Information Acute toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Draize Test Other Ethyl Butyrate 13 g/kg ( Rat ) 2 g/kg ( Rabbit ) no data available no data available no data available n-Butyl acetate 10768 mg/kg ( Rat ) 17600 mg/kg ( Rabbit ) 390 ppm ( Rat ) 4 h no data available no data available D-Limonene 4400 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) no data available no data available no data available n-Amyl acetate 1600 mg/kg ( Rat ) no data available no data available no data available no data available Petroleum distillates, hydrotreated light 5000 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) 5.2 mg/L ( Rat ) 4 h no data available no data available Chronic Toxicity Component Mutagenicity Sensitization Developmental Toxicity Reproductive Toxicity Target Organ Effects Ethyl Butyrate no data available no data available no data available no data available no data available n-Butyl acetate no data available no data available no data available no data available eyes, CNS, respiratory system, skin D-Limonene no data available Skin sensitization, Respiratory no data available no data available CNS, bone marrow, lungs, liver, 5774 - BERRY BLAST (12X12 OZ) 5774 - BERRY BLAST (12X12 OZ) 5774 - BERRY BLAST (12X12 OZ) 5774 - BERRY BLAST (12X12 OZ) Issuing Date 19-Jul-2010 Issuing Date 19-Jul-2010 Issuing Date 19-Jul-2010 Issuing Date 19-Jul-2010 Page 2 / 4 Page 80 of 878 Page 80 of 878 Page 80 of 878 Page 80 of 878 ---PAGE BREAK--- sensitization kidneys n-Amyl acetate no data available no data available no data available no data available eyes, CNS, respiratory system, skin Petroleum distillates, hydrotreated light no data available no data available no data available no data available CNS, cardiovascular system, respiratory system Carcinogenicity There are no known carcinogenic chemicals in this product. Component ACGIH IARC NTP OSHA Other Ethyl Butyrate not applicable not applicable not applicable not applicable not applicable n-Butyl acetate not applicable not applicable not applicable not applicable not applicable D-Limonene not applicable not applicable not applicable not applicable not applicable n-Amyl acetate not applicable not applicable not applicable not applicable not applicable Petroleum distillates, hydrotreated light not applicable not applicable not applicable not applicable not applicable 12. ECOLOGICAL INFORMATION Product Information No information available. Component Information Component Toxicity to Algae Toxicity to Fish Microtox Water Flea log Pow Ethyl Butyrate no data available no data available no data available no data available N/A n-Butyl acetate EC50= 674.7 mg/L Desmodesmus subspicatus 72 h LC50 17-19 mg/L Pimephales promelas 96 h LC50= 100 mg/L Lepomis macrochirus 96 h LC50= 62 mg/L Leuciscus idus 96 h EC50 = 70.0 mg/L 5 min EC50 = 82.2 mg/L 15 min EC50 = 959 mg/L 18 h EC50 = 98.9 mg/L 30 min EC50 = 72.8 mg/L 24 h 1.81 at 23 °C D-Limonene no data available LC50 0.619-0.796 mg/L Pimephales promelas 96 h LC50= 35 mg/L mykiss 96 h no data available no data available N/A n-Amyl acetate no data available LC50= 650 mg/L Lepomis macrochirus 96 h no data available no data available N/A Petroleum distillates, hydrotreated light no data available LC50= 2.2 mg/L Lepomis macrochirus 96 h LC50= 2.4 mg/L mykiss 96 h LC50= 45 mg/L Pimephales promelas 96 h no data available LC50 = 4720 mg/L 96 h N/A Persistence and Degradability No information available. Bioaccumulation No information available. Mobility No information available. 13. DISPOSAL CONSIDERATIONS Product Disposal Dispose of in accordance with local regulations. Container Disposal Empty containers should be taken for local recycling, recovery, or waste disposal. 14. TRANSPORT INFORMATION DOT Proper Shipping Name <119 gals = NOT REGULATED (DOT Combustible exception 173.150(f)) >119 gals = Petroleum Distillates, N.O.S. Hazard Class 3 UN-No UN1268 Packing Group III Description UN1268, Petroleum distillates, N.O.S.,3,III TDG Proper shipping name <119 gals = NOT REGULATED >119 gals = Petroleum Distillates, N.O.S.,3,III Hazard Class 3 UN-No UN1268 Packing Group III Description UN1268, Petroleum Distillates, N.O.S.,3,III ICAO Not regulated IATA Not regulated IMDG/IMO Not regulated 15. REGULATORY INFORMATION Inventories TSCA Complies DSL Complies U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part 372. SARA 311/312 Hazardous Categorization 5774 - BERRY BLAST (12X12 OZ) 5774 - BERRY BLAST (12X12 OZ) 5774 - BERRY BLAST (12X12 OZ) 5774 - BERRY BLAST (12X12 OZ) Issuing Date 19-Jul-2010 Issuing Date 19-Jul-2010 Issuing Date 19-Jul-2010 Issuing Date 19-Jul-2010 Page 3 / 4 Page 81 of 878 Page 81 of 878 Page 81 of 878 Page 81 of 878 ---PAGE BREAK--- Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard Yes Sudden Release of Pressure Hazard No Reactive Hazard No CERCLA Component Hazardous Substances RQs CERCLA EHS RQs Ethyl Butyrate Not applicable Not applicable n-Butyl acetate Not applicable Not applicable D-Limonene Not applicable Not applicable n-Amyl acetate Not applicable Not applicable Petroleum distillates, hydrotreated light Not applicable Not applicable Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class B3 Combustible liquid, D2A Very toxic materials, D2B Toxic materials. 16. OTHER INFORMATION Prepared By Dan Hollas Supercedes Date 07/18/2007 Issuing Date 07/19/2010 Reason for Revision No information available. Glossary No information available. List of References. No information available. CHEMSEARCH DIV. OF NCH CORP. assumes no responsibility for personal injury or property damage caused by the use, storage, or disposal of the product in a manner not recommended on the product label. Users assume all risks associated with such unrecommended use, storage or disposal of the product. The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. 5774 - BERRY BLAST (12X12 OZ) 5774 - BERRY BLAST (12X12 OZ) 5774 - BERRY BLAST (12X12 OZ) 5774 - BERRY BLAST (12X12 OZ) Issuing Date 19-Jul-2010 Issuing Date 19-Jul-2010 Issuing Date 19-Jul-2010 Issuing Date 19-Jul-2010 Page 4 / 4 Page 82 of 878 Page 82 of 878 Page 82 of 878 Page 82 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET (SUBSTITUTES FOR OSHA FORM 174): May be used to comply with OSHA's Hazard Communication Standard, 29 CFR 1910.1200. PRODUCT NUMBER: 014281 IDENTITY: BLAST OFF 16A Revision Date: 01/16/2007 Section I Manufacturer's Name:DALCO ENTERPRISES, INC Telephone Numbers: Address: 300 5TH AVENUE NW Emergency: 800/255-3924 NEW BRIGHTON Information: State: MN Zip Code:55112 651/604-2966 HMIS CODES: REACTIVITY: 1 FLAMMABILITY: 0 HEALTH: 1 PERSONAL PROTECT: A Section II: HAZARDOUS INGREDIENTS/IDENTITY INFORMATION (All of the ingredients contained in this product are listed on the TSCA inventory.) Name Cas No. OSHA PEL ACGIH TLV OTHER LIM % 2-BUTOXY ETHANOL * 111-76-2 50 PPM 20 PPM N/A ISOPROPYL ALCOHOL 67-63-0 400 PPM 200 PPM N/A PROPANE/N-BUTANE 68476-86-8 1000 PPM 600 PPM N/A Comment: THIS PRODUCT CONTAINS THE TOXIC CHEMICALS MARKED WITH AN * SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986 AND OF 40CFR372. Section III: PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: 212 Specific Gravity (water=1) 1.00 Vapor Pressure(mm Hg) 17.5 Melting Point: N/A Vapor Density(AIR=1) 1 Evaporation Rate: .1 Solubility in Water: 100% (Butyl Acetate=1) Appearance and Odor: CLEAR SPRAY, FRUITY BUTYL ODOR Section IV: FIRE AND EXPLOSION HAZARD DATA Flash Point(Method Used):NONE Flammable Limits: LEL:N/A UEL: N/A Extinguishing Media: STANDARD CHEMICAL FIRE EXTINGUISHER Special Fire Fighting Procedures: WEAR SELF CONTAINED BREATHING APPARATUS WHEN INDICATED Unusual Fire and Explosion Hazards: CONTENTS UNDER PRESSURE. EXPOSURE TO TEMPERATURES ABOVE 120 MAY CAUSE BURSTING. Page 83 of 878 Page 83 of 878 Page 83 of 878 Page 83 of 878 ---PAGE BREAK--- Section V: REACTIVITY DATA PRODUCT NUMBER: 014281 Stability: Unstable: Conditions to avoid: Stable: X TEMPERATURES ABOVE 120 F Incompatability (Materials to Avoid): NONE Hazardous Decomposition or Byproducts: NONE Hazardous Polymerization: May Occur: Will Not Occur: X Conditions to Avoid: NONE Section VI: HEALTH HAZARD DATA Routes of Entry: Inhalation: YES Skin: YES Ingestion:YES Health Hazards(Acute and Chronic): INHALATION: EXPOSURE TO EXCESSIVE FUMES MAY CAUSE DIZZINESS. EYES: SEVERE IRRITATION, BURNING, CAN CAUSE MILD CORNEAL DAMAGE. SKIN: MAY CAUSE LOCALIZED DEFATTING. INGESTION: MAY CAUSE NAUSEA OR VOMITING. Carcinogenicity: NTP:NO IARC Monographs:NO OSHA Reg:NO Signs and of Exposure: SEE HEALTH HAZARDS ABOVE Medical Conditions Generally Aggravated by Exposure: NONE Emergency and First Aid Procedures: INHALATION: REMOVE TO FRESH AIR. INGESTION: INDUCE VOMITING-SEE PHYSICIAN. SKIN: WASH WITH SOAP AND WATER - IF IRRITATION PERSISTS, SEE PHYSICIAN. EYES: RINSE THOROUGHLY WITH WATER FOR 15 MINUTES - IF IRRITATION PERSISTS - SEE PHYSICIAN. Section VII: PRECAUTIONS FOR SAFE HANDLING AND USE Steps to be Taken in Case Material is Released or Spilled: WIPE UP WITH RAG OR USE SOME ABSORBENT CLAY MATERIAL. Waste Disposal Method: DISPOSE OF RESIDUE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL GUIDELINES. WRAP CONTAINER AND PLACE IN TRASH COLLECTION Precautions to be Taken in Handling and Storing: KEEP AWAY FROM CHILDREN STORE IN A COOL DRY AREA. KEEP AWAY FROM HEAT, SPARKS OR OPEN FLAME. CONTENTS UNDER PRESSURE. Other Precautions: EXPOSURE TO TEMPERATURES >120F MAY CAUSE BURSTING. Section VIII: CONTROL MEASURES Respiratory Protection: USE WITH ADEQUATE VENTILATION. Ventilation: Local Exhaust:ADEQUATE Mechanical: N/A Special: N/A Other: N/A Protective Gloves:N/A Eye Protection: SAFETY GLASSES ARE RECOMMENDED WHEN USING CHEMICAL PRODUCTS Other Protective Clothing or Equipment: N/A Work/Hygienic Practices: WASH HANDS AFTER USE • Page 84 of 878 Page 84 of 878 Page 84 of 878 Page 84 of 878 ---PAGE BREAK--- Page 85 of 878 Page 85 of 878 Page 85 of 878 Page 85 of 878 ---PAGE BREAK--- BRAVO HEAVY DUTY LOW ODOR STRIPPER 4576 & 4583 & 4588 Industrial/Institutional: Floor care. This product is intended to be diluted prior to use. 1/29/2003 1/29/2003 Material Safety Data Sheet Product Name Product Use Validation Date Print Date In Case of Emergency Section 1. Chemical Product and Company Identification Supersedes 4/5/2002. Health 3 0 0 Fire Hazard Reactivity Specific Hazard Health Fire Hazard Reactivity Protective Clothing 0 0 3 (800) 851-7145 Johnson Wax Professional 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249 MSDS Internet Address: www.jwp.com U.S. Headquarters Johnson Wax Professional 100 Matheson Blvd. East, Suite 203 Mississauga, Ontario L4Z 2G7 Phone: (905) 755-0913 or (888) 746-5971 Hazardous Material Information System (HMIS) National Fire Protection Association (NFPA) Code MSDS# 114585005 455721 Canadian Headquarters Clear Liquid. See Section 9. DANGER. CORROSIVE. CAUSES EYE AND SKIN BURNS. HARMFUL OR FATAL IF SWALLOWED. Emergency Overview PMS# BRAVO HEAVY DUTY LOW ODOR STRIPPER Monoethanolamine 141-43-5 1-5 OSHA (United States). TWA: 8 mg/m3 STEL: 15 mg/m3 ACGIH (United States). TWA: 7.5 mg/m3 STEL: 15 mg/m3 ORAL (LD50): Acute: 1720 mg/kg [Rat]. DERMAL (LD50): Acute: 1018 mg/kg [Rabbit]. Sodium Hydroxide 1310-73-2 5-10 OSHA (United States). CEIL: 2 mg/m3 ACGIH (United States). STEL: 2 mg/m3 Not available. Water 7732-18-5 60-100 Not available. Not available. Section 2. Composition and Information on Ingredients Ingredients CAS # % by Weight Exposure Limits LC50/LD50 Inhalation. Skin contact. Eye contact. Medical Conditions Aggravated by Overexposure: Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, etc., may be more susceptible to irritating effects. Section 3. Hazards Identification Routes of Entry Potential Acute Health Effects May cause irritation and corrosive effects to nose, throat and respiratory tract. Corrosive. May cause permanent damage including blindness. Corrosive. May cause burns to mouth, throat, and stomach. Corrosive. May cause permanent damage. Eyes Skin Inhalation Ingestion See Toxicological Information (section 11) Continued on Next Page Page: 1/4 Page 86 of 878 Page 86 of 878 Page 86 of 878 Page 86 of 878 ---PAGE BREAK--- Material Safety Data Sheet BRAVO HEAVY DUTY LOW ODOR STRIPPER Do not induce vomiting. Immediately drink one cupful of water or milk. Never give anything by mouth to an unconscious person. Get medical attention immediately. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Get medical attention immediately. Flush immediately with plenty of water for at least 15 minutes. Get medical attention immediately. If breathing is difficult: Remove to fresh air. Get medical attention immediately. Section 4. First Aid Measures Eye Contact Skin Contact Inhalation Ingestion None known. None known. None known. Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire fighting procedure may be used. Corrosive material (See sections 8 and 10). Section 5. Fire Fighting Measures Flammability of the Product Flash Points Products of Combustion Put on appropriate personal protective equipment (see Section Fire Fighting Media and Instructions Protective Clothing (Fire) Special Remarks on Fire and Explosion Hazards In the event of major spillage: Use appropriate containment to avoid environmental contamination. Sweep or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a water rinse for final clean-up. Put on appropriate personal protective equipment (see Section Section 6. Accidental Release Measures Personal Precautions Environmental Precautions and Clean-up Methods Keep container closed. Protect from freezing. Store in a dry, cool and well-ventilated area. KEEP OUT OF REACH OF CHILDREN. Avoid contact with eyes, skin and clothing. Do not taste or swallow. Avoid breathing vapors or spray mists. Use only with adequate ventilation. Remove and wash contaminated clothing and footwear before re-use. Wash thoroughly after handling. Product residue may remain on/in empty containers. All precautions for handling the product must be used in handling the empty container and residue. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Section 7. Handling and Storage Handling Storage Good general ventilation should be sufficient to control airborne levels. Respiratory protection is not required if good ventilation is maintained. Section 8. Exposure Controls/Personal Protection Engineering Controls If mists/vapors are not adequately controlled by ventilation, use appropriate respiratory protection to avoid over exposure. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Chemical splash goggles. If major exposure is possible, wear suitable protective clothing and footwear. Chemical resistant gloves. Includes: Neoprene gloves. Rubber gloves. Protective footwear. Personal Protection Eyes Hands Respiratory Feet Body Continued on Next Page Page: 2/4 Page 87 of 878 Page 87 of 878 Page 87 of 878 Page 87 of 878 ---PAGE BREAK--- Material Safety Data Sheet BRAVO HEAVY DUTY LOW ODOR STRIPPER Liquid. 13.4 [Basic.] (Undiluted.) 1.1 Bland. Clear Section 9. Physical and Chemical Properties Physical State and Appearance pH Specific Gravity Solubility in water Odor Color Complete. The product is stable. Reactive with oxidizing agents, acids. Will not occur. When exposed to fire: Produces normal products of combustion. None known. Section 10. Stability and Reactivity Stability and Reactivity Conditions of Instability Incompatibility with Various Substances Hazardous Decomposition Products Hazardous Polymerization Section 11. Toxicological Information Effects of Chronic Exposure Other Toxic Effects None known. Acute oral toxicity (LD50): Estimated to be 860 mg/kg. Corrosive. Acute toxicity None known. Section 12. Ecological Information Not available. Undiluted product is regulated under environmental and transportation laws as a corrosive waste. Dispose of according to all federal, state and local regulations. Waste Information Section 13. Disposal Considerations Please refer to the Bill of Lading/receiving documents for up to date shipping information. Section 14. Transport Information DOT Classification DOT Proper Shipping Name TDG Classification TDG Proper Shipping Name TDG Class Please refer to the Bill of Lading/receiving documents for up to date shipping information. Section 15. Regulatory Information Federal Reporting in this section is based on ingredients disclosed in Section 2 Clean Water Act (CWA) 311: Sodium hydroxide CERCLA: Hazardous substances.: Sodium hydroxide US Regulations Continued on Next Page Page: 3/4 Page 88 of 878 Page 88 of 878 Page 88 of 878 Page 88 of 878 ---PAGE BREAK--- Material Safety Data Sheet BRAVO HEAVY DUTY LOW ODOR STRIPPER State Chemical Inventory Status Canadian Regulations CLASS E: Corrosive liquid. All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Registered Product Information WHMIS Classification WHMIS Icon New Jersey spill list: Sodium hydroxide New Jersey: Monoethanolamine, Sodium hydroxide Massachusetts spill list: Monoethanolamine, Sodium hydroxide Massachusetts RTK: Monoethanolamine, Sodium hydroxide RTK: Monoethanolamine, Sodium hydroxide Registered Product Information Not applicable. Not applicable. This product is not subject to the reporting requirements under California's Proposition 65. Not available. Section 16. Other Information Other Special Considerations Notice to Reader This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Version 1.03 Page 89 of 878 Page 89 of 878 Page 89 of 878 Page 89 of 878 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 19-Jul-2012 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code DA8060 Product name BRRR-Eaker Recommended Use Lubricant Supplier Drummond, A Lawson Brand Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions Asthma. Allergies. Principal Routes of Exposure Eyes. Skin contact. Inhalation. Ingestion. Potential health effects Eyes Contact with eyes may cause irritation. Causes burns. Frostbite. Pain. Tearing. Redness. Conjunctivitis. Skin May cause the following effects: . Skin Irritation. Frostbite. Skin burns. Repeated or prolonged exposure may cause:. May cause skin irritation. Exposure can dry the skin. Inhalation Harmful by inhalation. May cause irritation of respiratory tract. Possible May cause the following effects. Drowsiness . Dizziness. Aspiration hazard. Chemical pneumonitis. Ingestion No hazard under normal industrial and institutional use. May be harmful if swallowed. Aspiration hazard. May cause severe lung damage if aspirated into the lungs from ingestion or vomiting. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % 1,1-Difluoroethane 75-37-6 60-100 Methylisobutyl ketone 108-10-1 1-5 Oleic Acid 112-80-1 1-5 4. FIRST AID MEASURES General advice S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Show this safety data sheet to the doctor in attendance. Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Seek medical attention if irritation persists. Skin contact Wash off immediately with plenty of water. Remove contaminated clothing and footwear. Wash contaminated clothing before re-use. Seek medical attention if irritation persists. Ingestion Do Not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to physician of poisoning may not appear for several hours. Keep under medical supervision for at least 48 hours. 5. FIRE FIGHTING MEASURES Flash point °C -58 Flash point °F -72 Method Tag Closed Cup Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper No data available Lower No data available Suitable extinguishing media Dry powder. Foam. Carbon dioxide. Extinguishing media which must NOT be used for safety reasons Do not use water. Do not use a solid water stream as it may scatter and spread fire . Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Special Fire-Fighting Procedures Keep people away from and upwind of spill/leak. Specific hazards Flammable . Page 1 / 4 Emergency Overview Flammable. Harmful by inhalation. May cause eye/skin irritation. Contents under pressure. CONTAINER MAY EXPLODE IF HEATED . Page 90 of 878 Page 90 of 878 Page 90 of 878 Page 90 of 878 ---PAGE BREAK--- Fire and Explosion Hazards CONTAINER MAY EXPLODE IF HEATED . Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Hazardous decomposition products See Section 10. Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective equipment. Keep people away from and upwind of spill/leak. Remove all sources of ignition. Environmental precautions Concentrated vapors of this product are heavier than air and will collect in low areas, pits, storage tanks and other confined spaces. Do not enter those areas. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. Do not flush into surface water or sanitary sewer system. Methods for cleaning up Evacuate area of unprotected and unnecessary personnel. Personnel should wear appropriate protective equipment. Follow all precautions for handling. Please refer to appropriate sections of MSDS for additional information. Eliminate all sources of ignition. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use caution as spill may create a slip hazard. Clean up by sweeping or vacuum. Place in suitable container for disposal as hazardous waste. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. Allow to evaporate. 7. HANDLING AND STORAGE Handling Keep away from open flames, hot surfaces and sources of ignition. Do not smoke. Avoid contact with skin and eyes. Do not swallow. Do not breathe vapors or spray mist. Avoid breathing fumes. Use in a well ventilated area. Handle and open container with care. When using, do not eat, drink or smoke. Wash hands with soap and water before eating, drinking, smoking, or using toilet facilities. Do not puncture or incinerate. Storage Keep out of the reach of children. Keep containers closed in a cool, well-ventilated place. Store in temperatures below 120 degrees F (50 degrees C) . 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) 1,1- Difluoroethan e - - - - Methylisobutyl ketone 100 ppm 410 mg/m3 - 20 ppm 75 ppm Oleic Acid - - - - Ventilation and Environmental Controls Adequate ventilation should be provided to keep exposure levels below current acceptable exposure limits. Hygiene measures General industrial hygiene practice. When using, do not eat, drink or smoke. A safety shower and eye wash station should be available for emergency use. Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment. Hand Protection Protective gloves. Eye protection S39 - Wear eye/face protection. Use safety eyewear designed to protect against splash of liquids. Skin and body protection Wear suitable protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Colorless - Light yellow Odor Characteristic Odor Threshold No information available pH Not Applicable Specific Gravity 0.91 Vapor pressure No data available Vapor density >1 (Air = 1) Evaporation Rate No data available Water solubility Negligible VOC Content 4.8% Partition Coefficient (n-octanol/water) No data available Boiling point/range °C No data available Boiling point/range °F No data available Melting point/range °C No data available Melting point/range °F No data available Flash point °C -58 Flash point °F -72 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Heating may cause an explosion. Conditions to avoid Avoid heat. Do not store or use near incompatible materials. Incompatability Oxidizers. Bases. Alkali metals. Page 2 / 4 Product code DA8060 Product name BRRR-Eaker Page 91 of 878 Page 91 of 878 Page 91 of 878 Page 91 of 878 ---PAGE BREAK--- Hazardous Decomposition Products Carbon oxides. Hydrofluoric acid. Carbonyl Fluoride. Polymerization Stable under normal storage conditions. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) 1,1- Difluoroethane 75-37-6 - - - Methylisobutyl ketone 108-10-1 2080 mg/kg 16000 mg/kg 8.2 mg/L Oleic Acid 112-80-1 25 g/kg - - Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity See Section 2 . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects See Section 2 Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns 1,1- Difluoroethan e Not Listed Not Listed Not Listed Not Listed Not Listed Methylisobutyl ketone A3 Group 2B Not Listed Not Listed Listed Oleic Acid Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Aquatic toxicity Harmful to aquatic organisms Do not let product enter drains 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT UN1950 Aerosols, flammable, 2.1. Exception: (Compressed Gas not more than 1.0L) Consumer Commodity ORM-D TDG UN1950 AEROSOLS, flammable, 2.1 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Methylisobutyl ketone Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 1,1-Difluoroethane Listed Not Listed Not Listed Methylisobutyl ketone Listed Listed Carcinogen Oleic Acid Not Listed Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA 1,1-Difluoroethane X X - X Methylisobutyl ketone X X - X Oleic Acid X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION NFPA Health - 2 Flammability - 3 Reactivity - 0 HMIS Health - 2 Page 3 / 4 Microtox Data Photobacterium phosphoreum EC50=79.6 mg/L (5 min) Product name BRRR-Eaker Water Flea Data Daphnia magna EC50=170 mg/L (48 h) Methylisobutyl ketone Product code DA8060 Page 92 of 878 Page 92 of 878 Page 92 of 878 Page 92 of 878 ---PAGE BREAK--- 16. OTHER INFORMATION Flammability - 3 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product name BRRR-Eaker Product code DA8060 Page 93 of 878 Page 93 of 878 Page 93 of 878 Page 93 of 878 ---PAGE BREAK--- CaviCide™ Date Prepared: 12/15/14 Page 1 of 10 SAFETY DATA SHEET Section 1: Chemical Product and Company Information 1.1 Product Identifier Product Name: CaviCide™ 1.2 Relevant Identified Uses of the Substance or Mixture and Uses Advised Against Product Use: Hard surface cleaner and disinfectant. 1.3 Details of the Supplier of the Substance or Mixture Manufacturer: METREX™ RESEARCH 28210 Wick Rd Romulus, MI 48174 U.S.A. 1.4 Emergency Telephone Number (Chemical Spills, Leaks, Fire, Exposure or Accident only): CHEMTREC: 1-[PHONE REDACTED] (in the US) 1-[PHONE REDACTED] (Outside the US) Information Phone Number: 1-[PHONE REDACTED] (Customer Service) SDS Date Of Preparation/Revision: December 15, 2014 Section 2. Hazards Identification 2.1 Classification of the Substance or Mixture Flammable Liquid Category 3 Eye Irritation Category 2 (2A US) Specific Target Organ Toxicity Single Exposure Category 3 (Narcotic effects) 2.2 Label Elements WARNING! Hazard Phrases H226 Flammable liquid and vapor. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. Precautionary Phrases P210 Keep away from heat, sparks, open flames, hot surfaces – No smoking. P233 Keep container closed. P241 Use explosion-proof electrical, ventilating and light equipment. P243 Take precautionary measures against static discharge. Page 94 of 878 Page 94 of 878 Page 94 of 878 Page 94 of 878 ---PAGE BREAK--- CaviCide™ Date Prepared: 12/15/14 Page 2 of 10 P261 Avoid breathing vapors. P264 Wash thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear eye protection. P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312: Call a POISON CENTER or physician if you feel unwell. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing. P337+P313 If eye irritation persists get medical attention. P370+P378 In case of fire: Use water spray or fog, alcohol-resistant foam, carbon dioxide or dry chemical to extinguish. P403+P235 Store in a well-ventilated place. Keep cool. P501 Dispose of contents and container in accordance with local and national regulations. 2.3 Other Hazards: None identified Section 3. Composition/Information On Ingredients Component CAS No. Amount GHS Classification Isopropanol 67-63-0 17.2% Flam Liquid 2 (H226) Eye Irrit. 2 (H319) STOT SE 3 (H336) Ethylene Glycol Monobutyl Ether (2-Butoxyethanol) 111-76-2 1-5% Acute Tox 4 (H302), Acute Tox 3 (H311), Acute Tox. 3 (H331), Skin Irrit. 2 (H315), Eye Irrit. 2 (H319) chloride 121-54-0 0.28% Acute Tox 3 (H301) Skin Corr 1A (H314) Eye Dam 1 (H318) STOT SE 3 (H335) Aquatic Chronic 2 (H411) Water 7732-18-5 70-80% Not classified as hazardous Section 4. First Aid Measures 4.1 Description of First Aid Measures Inhalation: Move to fresh air if effects occur and seek medical attention if effects persist. Skin Contact: Remove contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for further treatment advice. Eye Contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. Call a poison control center or doctor for treatment advice. Page 95 of 878 Page 95 of 878 Page 95 of 878 Page 95 of 878 ---PAGE BREAK--- CaviCide™ Date Prepared: 12/15/14 Page 3 of 10 Ingestion: If swallowed, get medical advice by calling a Poison Control Center or hospital emergency room. If advice is not available, take victim and product container to the nearest emergency treatment center or hospital. Do not attempt to give anything by mouth to an unconscious person. 4.2 Most Important and effects, both acute and delayed: Causes serious eye irritation. Inhalation of concentrated vapors may cause irritation of the eyes, nose and throat and dizziness and drowsiness. 4.3 Indication of any immediate medical attention and special treatment needed: Immediate medical attention is generally not required. Section 5. Fire Fighting Measures 5.1 Extinguishing Media: Use water spray or fog, alcohol-resistant foam, carbon dioxide or dry chemical. Cool fire exposed containers with water. 5.2 Special Hazards Arising from the Substance or Mixture: Flammable liquid and vapor. May form explosive mixtures in air at temperatures at or above the flashpoint. Flammable vapors may collect in confined areas. Vapors are heavier than air and may travel along surfaces to remote ignition sources and flashback. Fire exposed containers may rupture explosively. 5.3 Advice for Fire-Fighters: Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing for fires in areas where chemicals are used or stored. Section 6: Accidental Release Measures 6.1 Personal Precautions, Protective Equipment and Emergency Procedures: Wear appropriate protective clothing and equipment. 6.2 Environmental Precautions: Avoid release to the environment 6.3 Methods and Material for Containment and Cleaning Up: Eliminate all ignition sources. Ventilate area. Use explosion-proof equipment if large amounts are released. Stop leak if it is safe to do so and move containers from the spill area. Collect material with an inert absorbent material and place in appropriate, labeled container for disposal. Section 7. Handling and Storage 7.1 Precautions for Safe Handling: Do not get in eyes or on clothing. Wear appropriate eye protection when handling. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet. Remove and wash contaminated clothing before reuse. Flammable liquid and vapor. Keep away from heat, sparks, open flames and all other sources of ignition. Do not smoke in storage or use areas. Keep containers closed when not in use. Do not reuse empty containers. 7.2 Conditions for Safe Storage, Including any Incompatibilities: Store in a cool, well-ventilated area away from heat, oxidizers and all sources of ignition. Do not contaminate water, food or feed by storage. Page 96 of 878 Page 96 of 878 Page 96 of 878 Page 96 of 878 ---PAGE BREAK--- CaviCide™ Date Prepared: 12/15/14 Page 4 of 10 Empty containers retain product residues and may be hazardous. Do not flame cut, drill, weld, etc. on or near empty containers, even empty. 7.3 Specific end use(s): Hard surface cleaner and disinfectant. Section 8. Exposure Controls / Personal Protection 8.1 Control Parameters: Chemical Korean Exposure Limit Isopropanol 200 ppm 8 hr Exposure Limit 400 ppm Short Term Exposure Ethylene Glycol Monobutyl Ether Butoxyethanol) 20 ppm 8 hr Exposure Limit benzylammonium chloride None Established Water None Established 8.2 Exposure Controls: Recommended Monitoring Procedures: Collection on charcoal and analysis by gas chromatography. Appropriate Engineering Controls: General ventilation should be adequate for normal use. For operations where the exposure limits may be exceeded, mechanical ventilation such as local exhaust may be needed to minimize exposure. Use explosion proof electrical equipment and wiring where required. Personal Protective Measurers Respiratory Protection: None under normal use conditions with adequate ventilation. For operations where the occupational exposure limits are exceeded, an approved respirator with an organic vapor cartridge or supplied air respirator is recommended. Equipment selection depends on contaminant type and concentration. Select in accordance with applicable regulations and good industrial hygiene practice. For firefighting, use self-contained breathing apparatus. Eye Protection: Splash proof goggles, face shield, or safety glasses are recommended to prevent eye contact. Skin Protection: Impervious gloves such as butyl rubber or nitrile are recommended for operations which may result in prolonged or repeated skin contact. Other protection: Wear protective clothing if needed to avoid prolonged/ repeated skin contact. Suitable washing and eye flushing facilities should be available in the work area. Contaminated clothing should be removed and laundered before re-use. Page 97 of 878 Page 97 of 878 Page 97 of 878 Page 97 of 878 ---PAGE BREAK--- CaviCide™ Date Prepared: 12/15/14 Page 5 of 10 Section 9. Physical and Chemical Properties 9.1 Information on basic Physical and Chemical Properties: Appearance Clear liquid. Vapor Pressure 43.3 mmHg @ 20°C (isopropanol) Odor Alcohol Vapor Density: 2.1 (isopropanol) Odor Threshold 0.001 ppm (ethylene glycol monobutyl ether) Relative Density /Specific Gravity: 0.972 pH 11.0-12.49 Solubility in Water: Complete Melting/Freezing Point Not determined Partition Coefficient octanol/water Not determined Boiling Point: Not determined Auto-ignition Temperature Not determined Flash Point: 28.3°C (83°F) Decomposition Temperature Not determined Evaporation Rate Not determined Viscosity Not determined Flammability (solid/gas) Not applicable Explosive Properties Vapors may explode if confined. Flammable/ Explosive Limits LEL: 2% UEL: 12.7% Oxidizing Properties None Percent Volatile >95% Section 10. Stability and Reactivity 10.1 Reactivity: Not reactive at ambient temperatures. 10.2 Chemical Stability: Stable 10.3 Possibility of Hazardous Reactions: Not reactive. 10.4 Conditions to Avoid: Heat, sparks, flames and all other sources of ignition. 10.5 Incompatible Materials: Strong oxidizing agents, acids and strong reducing agents. 10.6 Hazardous Decomposition Products: Thermal decomposition will produce carbon monoxide, carbon dioxide, nitrogen oxides, amines, chlorine and hydrogen chloride. 11. Toxicological Information 11.1 Information on Toxicological Effects: Potential Health Effects: Inhalation: May cause irritation of the nose, throat and upper respiratory tract. High vapor concentrations may produce nausea, vomiting, headache, dizziness, drowsiness, weakness, fatigue, narcosis and possible unconsciousness. Skin Contact: Prolonged or repeated exposure may cause mild irritation. Eye Contact: May cause irritation with tearing, redness and pain. Ingestion: Ingestion may cause gastrointestinal disturbances and central nervous system effects such as headache, dizziness, drowsiness and nausea. Page 98 of 878 Page 98 of 878 Page 98 of 878 Page 98 of 878 ---PAGE BREAK--- CaviCide™ Date Prepared: 12/15/14 Page 6 of 10 Acute Toxicity Values: Product LD50 Oral Rat >5000 mg/kg LD50 Dermal Rabbit >2000 mg/kg LC50 inhalation LC50 rat >2.08 mg/L Skin corrosion/irritation: Product: Non-irritating in a primary irritation study with rabbits. No signs of toxicity or irritation were observed in a dermal toxicity study in rabbits. Eye damage/ irritation: Product: Moderately irritating in an eye irritation study with rabbits. Effects reversed in 7 days. Skin Sensitization: Product: Negative in a skin sensitization study with guinea pigs. Respiratory Sensitization: No data available on the product or components. Not expected to cause respiratory sensitization. Germ Cell Mutagenicity: Ethylene Glycol Monobutyl Ether: Tested negative in the AMES test, in an in vitro mammalian chromosome aberration assay and in an in vivo mammalian micronucleus test. Isopropanol: Tested negative in the AMES test, in an In vitro mammalian cell gene mutation test and in an in vivo mammalian micronucleus test. chloride: Negative in AMES test with or without metabolic activation. Carcinogenicity: None of the components is listed as a carcinogen or potential carcinogen by IARC, NTP, ACGIH, or OSHA. Ethylene glycol monobutyl ether: The US National Toxicology Program (NTP) conducted a 2-year inhalation chronic toxicity and carcinogenicity study with ethylene glycol monobutyl ether in rats and mice. A significant increase in the incidence of liver hemangiosarcomas was seen in male mice and forestomach tumors in female mice. Based on the mode of action data available, there was no significant hazard for human carcinogenicity. Developmental / Reproductive Toxicity: Ethylene glycol monobutyl ether: In a14 week reproductive study, mice were orally administered 720, 1340 and 2050 mg/kg/day. Effects were seen on fertility only at doses which were severely toxic to the animals (1340 and 2050 mg/kg). A NOAEL -720 mg/kg. benzylammonium chloride: In a teratology study, rats were given up to 35.6 mg/kg/day from day 6-15 of gestation. Adverse maternal effects were seen at the highest dose. Specific Target Organ Toxicity (Single Exposure): In an acute toxicity study with rat, Cavicide has been shown to cause respiratory irritation. Specific Target Organ Toxicity (Repeated Exposure): Ethylene Glycol Monobutyl Ether: Ethylene Glycol Monobutyl Ether: was administered dermally to male and female rabbits at doses up to 150mg/kg/day for 90 days. The maximum dose tested was the maximum that could be tolerated. No clinical, haematological, clinical chemistry or pathological changes were observed that could be attributed to treatment. NOEAL 150 mg/kg. Isopropanol: In a 104 week inhalation study, rats were exposed to 500, 2500, 5000 ppm for 6hr/day. There no adverse exposure related effects seen at any dose. NOAEL of 5000 ppm. Page 99 of 878 Page 99 of 878 Page 99 of 878 Page 99 of 878 ---PAGE BREAK--- CaviCide™ Date Prepared: 12/15/14 Page 7 of 10 Section 12. Ecological Information 12.1 Toxicity: Isopropanol: LC50 fathead minnows 11,130 mg/L/48 hr; LC50 brown shrimp 1400 mg/L/48 hr chloride: LC50 pimephales promelas 1.6 mg/L/96 hr, LC50 lepomis macrochirus 1.4 mg/L/96 hr. 12.2 Persistence and degradability: Isopropanol and 2-butoxyethanol are readily biodegradable in screening tests. chloride is not readily biodegradable. 12.3 Bioaccumulative Potential: Isopropanol has an estimated BCF of 3 suggesting that the potential for bioaccumulation is low. 12.4 Mobility in Soil: Isopropanol is expected to have very high mobility in soil. 12.5 Results of PVT and vPvB assessment: None required. 12.6 Other Adverse Effects: None known. 13. Disposal Considerations 13.1 Waste Treatment Methods: Do not contaminate water, food, or feed by storage and disposal. Pesticide Disposal: Unused product or wastes resulting from the use of this product may be disposed of according to applicable Federal, State, or local procedures. Container Disposal: Nonrefillable container. Do not reuse or refill this container. Offer for recycling, if available. Section 14. Transport Information 14.1 UN Number 14.2 UN Proper Shipping Name 14.3 Hazard Class(s) 14.4 Packing Group 14.5 Environmental Hazards US DOT None Not Regulated per alcohol exception (49CFR 173.150(e)) None None None EU ADR/RID UN1987 Alcohols, n.o.s. (Isopropanol) 3 III None IMDG UN1987 Alcohols, n.o.s. (Isopropanol) 3 III None IATA/ICAO UN1987 Alcohols, n.o.s. (Isopropanol) 3 III None DOT MARINE POLLUTANTS: This product does not contain Marine Pollutants as defined in 49 CFR 171.8. 14.6 Special Precautions for User: None identified 14.7 Transport in Bulk According to Annex III MARPOL 73/78 and the IBC Code: None known. Page 100 of 878 Page 100 of 878 Page 100 of 878 Page 100 of 878 ---PAGE BREAK--- CaviCide™ Date Prepared: 12/15/14 Page 8 of 10 Section 15. Regulatory Information 15.1 Safety, Health and Environmental Regulations/Legislation Specific for the Substance or Mixture US Regulations EPA SARA 311/312 Hazard Classification: Fire Hazard, Acute Health, Chronic Health EPA SARA 313: This Product Contains the Following Chemicals Subject to Annual Release Reporting Requirements Under SARA Title III, Section 313 (40 CFR 372): Ethylene Glycol Monobutyl Ether (Glycol Ether) 1-5% Protection Of Stratospheric Ozone: This product is not known to contain or to have been manufactured with ozone depleting substances as defined in 40 CFR Part 82, Appendix A to Subpart A. CERCLA SECTION 103: This product is not subject to CERCLA reporting requirements; however, many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. US EPA Registered Pesticide: This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. CAUTION! Harmful if absorbed through the skin. Causes moderate eye irritation. Keep out of reach of children. California Prop 65: This product may contain a chemical known to the State of California to cause cancer or birth defects or other reproductive harm. Korean Regulations: Industrial Safety and Health Act: Isopropanol and ethylene glycol monobutyl ether are regulated under the Korean Industrial Safety and Health Act. Toxic Chemical Control Act: None of the components are regulated or are below the threshold for reporting under the Toxic Chemical Control Act. Dangerous Material Safety Control Act: Isopropanol is regulated under the Dangerous Material Safety Control Act as a Class 4 Alcohol. Ethylene glycol monobutyl ether is regulated under the Dangerous Material Safety Control Act as a Class 4 No. 2 Petroleum. Wastes Management Act: Not sold as a designated waste. Page 101 of 878 Page 101 of 878 Page 101 of 878 Page 101 of 878 ---PAGE BREAK--- CaviCide™ Date Prepared: 12/15/14 Page 9 of 10 International Inventories US EPA TSCA Inventory: All of the components of this product are listed on the Toxic Substances Control Act (TSCA) Chemical Substances Inventory or exempt. Canadian Environmental Protection Act: All of the components in this product are listed on the Domestic Substances List (DSL) or exempt. European Union: All the components in this product are listed on the EINECS inventory or exempt. Australia: All of the components in this product are listed on the Australian Inventory of Chemical Substances (AICS) or exempt. China: All of the components in this product are listed on the Inventory of Existing Chemical Substances in China (IECSC) or exempt. Japan: All of the components in this product are listed on the Japanese Existing and New Chemical Substances (ENCS) inventory or exempt. Korea: All of the components in this product are listed on the Korean Existing Chemicals List (KECL) or exempt. Philippines: All of the components of this product are listed on the Philippines Inventory of Chemicals and Chemical Substances (PICCS) or exempt. 16. Other Information NFPA Rating: Fire: 3 Health: 2 Instability: 0 GHS Classification for Reference (See Sections 2 and Flam. Liq. 2 Flammable Liquid Category 2 Eye Dam 1 Eye Damage Category 1 Eye Irrit. 2 Eye Irritation Category 2 Skin Corr 1A Skin Corrosion Category 1A Skin Irrit. 2 Skin Irritation Category 2 Acute Tox 3 Acute Toxicity Category 3 Acute Tox 4 Acute Toxicity Category 4 STOT SE 3 Specific Target Organ Toxicity Single Exposure Category 3 Aquatic Chronic 2 Aquatic Chronic Toxicity Category 2 H226 Flammable liquid and vapor. H301 Toxic if swallowed. H302 Harmful if swallowed. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H318 Causes serious eye damage. H319 Causes serious eye irritation. H331 Toxic if inhaled. H335 May cause respiratory irritation. Page 102 of 878 Page 102 of 878 Page 102 of 878 Page 102 of 878 ---PAGE BREAK--- CaviCide™ Date Prepared: 12/15/14 Page 10 of 10 H336 May cause drowsiness or dizziness. H411 Toxic to aquatic life with long lasting effects. Effective Date: 12/15/14 Supersedes Date: New SDS Revision Summary: New SDS The information and recommendations set forth herein are taken from sources believed to be accurate as of the date of preparation, however, METREX™ RESEARCH makes no warranty with respect to the accuracy or suitability of the recommendations, and assumes no liability to any use thereof. Page 103 of 878 Page 103 of 878 Page 103 of 878 Page 103 of 878 ---PAGE BREAK--- CaviCide™ Date Prepared: 7/14/2015 Page 1 of 6 MATERIAL SAFETY DATA SHEET 1. Product And Company Identification Product Name: CaviCide™ Manufacturer: METREX™ RESEARCH 1717 W. Collins Ave. Orange, CA 92867 U.S.A. Imported by: Sybron Canada LP Brampton, Ontario L6W 4T5 Information Phone Number: 1-[PHONE REDACTED] (Customer Service) Chemical Emergency Phone Number (Chemical Spills, Leaks, Fire, Exposure or Accident only): CHEMTREC 1-[PHONE REDACTED] (in the US) 1-[PHONE REDACTED] (Outside the US) MSDS Date Of Preparation/Revision: 7/14/2015 Product Use: Hard surface cleaner and disinfectant. DIN: 02161656 2. Hazards Identification Clear liquid with an alcohol odor. EMERGENCY OVERVIEW Flammable liquid and vapor. Causes moderate eye irritation. May cause mild skin irritation. Harmful if absorbed through the skin. Inhalation of concentrated vapors may cause irritation of the eyes, nose and throat and dizziness and drowsiness. Prolonged overexposure to ethylene glycol monobutyl ether may affect liver, kidneys, blood, system or central nervous system. 3. Composition/Information On Ingredients Component CAS No. Amount Isopropanol 67-63-0 17.2% Ethylene Glycol Monobutyl Ether Butoxyethanol) 111-76-2 1-5% dimethyl benzyl ammonium chloride 121-54-0 0.28% Water 7732-18-5 70-80% 4. First Aid Measures Inhalation: Move to fresh air if effects occur and seek medical attention if effects persist. Skin Contact: Remove contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for further treatment advice. Page 104 of 878 Page 104 of 878 Page 104 of 878 Page 104 of 878 ---PAGE BREAK--- CaviCide™ Date Prepared: 7/14/2015 Page 2 of 6 Eye Contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. Call a poison control center or doctor for treatment advice. Ingestion: If swallowed, get medical advice by calling a Poison Control Center or hospital emergency room. If advice is not available, take victim and product container to the nearest emergency treatment center or hospital. Do not attempt to give anything by mouth to an unconscious person. 5. Fire Fighting Measures Extinguishing Media: Use water spray or fog, alcohol-resistant foam, carbon dioxide or dry chemical. Cool fire exposed containers with water. Special Fire Fighting Procedures: Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing for fires in areas where chemicals are used or stored. Unusual Fire Hazards: Flammable liquid and vapor. May form explosive mixtures in air at temperatures at or above the flashpoint. Flammable vapors may collect in confined areas. Vapors are heavier than air and may travel along surfaces to remote ignition sources and flashback. Fire exposed containers may rupture explosively. Hazardous Combustion Products: Burning may produce carbon monoxide, carbon dioxide, nitrogen oxides, amines, chlorine and hydrogen chloride. 6: Accidental Release Measures Eliminate all ignition sources. Ventilate area. Use explosion-proof equipment if large amounts are released. Stop leak if it is safe to do so and move containers from the spill area. Wear appropriate protective clothing and equipment (See Section Collect material with an inert absorbent material and place in appropriate, labeled container for disposal. Refer to Section 13 for disposal advice. 7. Handling and Storage Do not get in eyes or on clothing. Wear appropriate eye protection when handling (see Section Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet. Remove and wash contaminated clothing before reuse. Flammable liquid and vapor. Keep away from heat, sparks, open flames and all other sources of ignition. Do not smoke in storage or use areas. Keep containers closed when not in use. Do not reuse empty containers. Store in a cool, well-ventilated area away from heat, oxidizers and all sources of ignition. Do not contaminate water, food or feed by storage. Empty containers retain product residues and may be hazardous. Do not flame cut, drill, weld, etc. on or near empty containers, even empty. Page 105 of 878 Page 105 of 878 Page 105 of 878 Page 105 of 878 ---PAGE BREAK--- CaviCide™ Date Prepared: 7/14/2015 Page 3 of 6 8. Exposure Controls / Personal Protection Exposure Limits Chemical Exposure Limit Isopropanol 200 ppm TWA, 400 ppm STEL (Alberta, British Columbia, Manitoba, New Brunswick, Newfoundland, Labrador, Nova Scotia, Prince Edward Island, Saskatchewan, Ontario 400 ppm TWA, 500 ppm STEL skin Nunavut, Northwest Territories, Yukon, Quebec Ethylene Glycol Monobutyl Ether Butoxyethanol) 20 ppm TWA (Alberta, British Columbia, Manitoba, New Brunswick, Newfoundland, Labrador, Nova Scotia, Prince Edward Island, Ontario, Quebec 20 ppm TWA, 30 ppm STEL Saskatchewan 25 ppm TWA, 75 ppm STEL Nunavut, Northwest Territories 50 ppm TWA, 150 ppm STEL skin Yukon dimethyl benzyl ammonium chloride None Established Ventilation: General ventilation should be adequate for normal use. For operations where the exposure limits may be exceeded, mechanical ventilation such as local exhaust may be needed to minimize exposure. Respiratory Protection: None under normal use conditions with adequate ventilation. For operations where the occupational exposure limits are exceeded, a NIOSH/MSHA approved respirator with an organic vapor cartridges or supplied air respirator is recommended. Equipment selection depends on contaminant type and concentration. Select in accordance with applicable regulations and good industrial hygiene practice. For firefighting, use self-contained breathing apparatus. Gloves: Impervious gloves such as butyl rubber or nitrile are recommended for operations which may result in prolonged or repeated skin contact. Eye Protection: Splash proof goggles, face shield, or safety glasses are recommended to prevent eye contact. Other Protective Equipment/Clothing: Wear protective clothing if needed to avoid prolonged/ repeated skin contact. Suitable washing and eye flushing facilities should be available in the work area. Contaminated clothing should be removed and laundered before re-use. Page 106 of 878 Page 106 of 878 Page 106 of 878 Page 106 of 878 ---PAGE BREAK--- CaviCide™ Date Prepared: 7/14/2015 Page 4 of 6 9. Physical and Chemical Properties Appearance And Odor: Clear liquid with an alcohol odor. Boiling Point: Not Determined Specific Gravity: 0.972 Solubility in Water: Complete pH: 11.0 -12.49 Vapor Pressure: 43.3 mmHg @ 20°C (isopropanol) Vapor Density: 2.1 (isopropanol) Percent Volatile: >95% Melting/Freezing Point: Not Determined Coefficient of Water/Oil Distribution: Not Determined Flash Point: 28.3°C (83°F) Flammable Limits: LEL: 2% UEL: 12.7% 10. Stability and Reactivity Stability: Stable Conditions To Avoid: Heat, sparks, flames and all other sources of ignition. Incompatibility: Strong oxidizing agents, acids and strong reducing agents. Hazardous Decomposition Products: Thermal decomposition will produce carbon monoxide, carbon dioxide, nitrogen oxides, amines, chlorine and hydrogen chloride. Hazardous Polymerization: Will not occur. 11. Toxicological Information Potential Health Effects: Acute Hazards: Inhalation: May cause irritation of the nose, throat and upper respiratory tract. High vapor concentrations may produce nausea, vomiting, headache, dizziness, drowsiness, weakness, fatigue, narcosis and possible unconsciousness. Not acutely toxic in rats. Skin Contact: Prolonged or repeated exposure may cause mild irritation. No signs of toxicity or irritation were observed in a dermal toxicity study in rabbits. Non-irritating in a primary irritation study with rabbits. Negative in a skin sensitization study with guinea pigs. Eye Contact: May cause irritation with tearing, redness and pain. Moderate irritant in an eye irritation study with rabbits. Effects reversed in 7 days. Ingestion: Ingestion may cause gastrointestinal disturbances and central nervous system effects such as headache, dizziness, drowsiness and nausea. Not acutely toxic in rats. Chronic Hazards: Prolonged overexposure to ethylene glycol monobutyl ether may affect liver, kidneys, blood, system or central nervous system. Medical Conditions Aggravated By Exposure: Due to its defatting properties, isopropyl alcohol may aggravate an existing skin condition. Page 107 of 878 Page 107 of 878 Page 107 of 878 Page 107 of 878 ---PAGE BREAK--- CaviCide™ Date Prepared: 7/14/2015 Page 5 of 6 Carcinogen: None of the components is listed as a carcinogen or potential carcinogen by IARC, NTP, ACGIH, or OSHA. Acute Toxicity Values for CaviCide: LD50 Oral Rat >5000 mg/kg LD50 Dermal Rabbit >2000 mg/kg LC50 inhalation LC50 rat >2.08 mg/L 12. Ecological Information This product is not classified as aquatically toxic based on the GHS criteria for aquatic toxicity. Toxicity: Isopropanol: LC50 fathead minnows 11,130 mg/L/48 hr; LC50 brown shrimp 1400 mg/L/48 hr dimethyl benzyl ammonium chloride: LC50 pimephales promelas 1.6 mg/L/96 hr, LC50 lepomis macrochirus 1.4 mg/L/96 hr. Persistence and degradability: Isopropanol and 2-butoxyethanol are readily biodegradable in screening tests. dimethyl benzyl ammonium chloride is not readily biodegradable. Bioaccumulative Potential: Isopropanol has an estimated BCF of 3 suggesting that the potential for bioaccumulation is low. Mobility in Soil: Isopropanol is expected to have very high mobility in soil. 13. Disposal Considerations Do not contaminate water, food, or feed by storage and disposal. Solution Disposal: Dilute with water. Dispose of in ordinary sanitary sewer. CONTAINER DISPOSAL: Triple rinse. Offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or incineration, or, if allowed by provincial and local authorities, by burning. If burned, keep out of smoke. 14. Transport Information U.S. DOT Hazard Classification Proper Shipping Name: Not Regulated per alcohol exception (49CFR 173.150(e)) Technical Name: N/A UN Number: N/A Hazard Class/Packing Group: N/A Labels Required: N/A DOT MARINE POLLUTANTS: This product does not contain Marine Pollutants as defined in 49 CFR 171.8. Page 108 of 878 Page 108 of 878 Page 108 of 878 Page 108 of 878 ---PAGE BREAK--- CaviCide™ Date Prepared: 7/14/2015 Page 6 of 6 Canada TDG Proper Shipping Name: Not regulated per aqueous solution of alcohol exception (1.36) Technical Name: N/A UN Number: N/A Hazard Class/Packing Group: N/A Labels Required: N/A IMDG Code Shipping Classification Proper Shipping Name: Alcohols, n.o.s. (Isopropanol) UN Number: UN1987 Hazard Class: 3 Packing Group: III Labels Required: Flammable Liquid (Class 3) Placards Required: Class 3 Not classified as a marine pollutant ICAO Air Transport Classification Proper Shipping Name: Alcohols, n.o.s. (Isopropanol) ID Number: UN1987 Hazard Class: 3 Packing Group: III Labels Required: Class 3 15. Regulatory Information National Pollutant Release Inventory (NPRI): This Product Contains the Following Chemicals Subject to Annual Release Reporting Requirements NPRI: Isopropanol 17.2% Ethylene Glycol Monobutyl Ether 1-5% CEPA Chemical Inventory: All of the components of this material are listed on the DSL or exempt. WHMIS Classification: Class B-2, Class D-2-B This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. 16. Other Information NFPA Rating: Fire: 3 Health: 2 Instability: 0 The information and recommendations set forth herein are taken from sources believed to be accurate as of the date of preparation, however, METREX™ RESEARCH makes no warranty with respect to the accuracy or suitability of the recommendations, and assumes no liability to any use thereof. Page 109 of 878 Page 109 of 878 Page 109 of 878 Page 109 of 878 ---PAGE BREAK--- Revision Date: 16-Sep-2014 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: CHEWING GUM REMOVER Product Number: 6445 Recommended Use: Chewing gum remover Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification GHS Label Elements Signal Word: Danger Hazard Statements: Extremely flammable aerosol. Contains gas under pressure; may explode if heated Precautionary Statements: Prevention: Keep away from heat/sparks/open flames/hot surfaces. — No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Response: -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F Protect from sunlight. Store in a well-ventilated place Disposal: Not Applicable Hazards Not Otherwise Classified: Not Applicable Flammable Aerosols Category 1 Gases Under Pressure Page 1 / 5 Liquefied gas Symbols: Page 110 of 878 Page 110 of 878 Page 110 of 878 Page 110 of 878 ---PAGE BREAK--- 6445 - CHEWING GUM REMOVER Revision Date: 16-Sep-2014 Other Information: • May cause frostbite if sprayed on skin or in eyes. • May be harmful if inhaled • Keep out of reach of children. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% propane 74-98-6 30-60 N-butane 106-97-8 30-60 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with lukewarm water. Clothing frozen to the skin should be thawed before being removed If skin irritation occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Water spray (fog) Foam Specific Hazards Arising from the Chemical: Extremely flammable aerosol. Exposure to high temperature may cause containers to burst. Bursting aerosol containers may be propelled from fire at high speed. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Water may be used to cool closed containers to prevent pressure build-up and possible auto ignition or explosion when exposed to extreme heat. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 7. HANDLING AND STORAGE Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Wash thoroughly after handling. Storage Conditions: NFPA 30B Level 3 Aerosol. Do not store in direct sunlight or above 122 F° / 50 Exposure to high temperature may cause containers to burst. Keep out of the reach of children. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Page 2 / 5 Occupational Exposure Limits: . Page 111 of 878 Page 111 of 878 Page 111 of 878 Page 111 of 878 ---PAGE BREAK--- 6445 - CHEWING GUM REMOVER Revision Date: 16-Sep-2014 Chemical Name ACGIH TLV OSHA PEL NIOSH propane 74-98-6 TWA: 1000 ppm TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 N-butane 106-97-8 TWA: 1000 ppm (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 TWA: 800 ppm TWA: 1900 mg/m3 Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Personal Protective Equipment Eye/Face Protection: Not required with expected use. Skin and Body Protection: Not required with expected use. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatible Materials: Strong oxidizing agents. Strong acids. Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Contact with product may cause frostbite 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Aerosol Color: Colorless Odor: Odorless pH: Not applicable Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: < -18 °C / 0 °F Flash Point: < -18 °C / < 0 °F (Propellant-estimated) Evaporation Rate: > 1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 0.543 Solubility(ies): No information available. Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 3 / 5 Decomposition Temperature: No information available. Viscosity: No information available. Page 112 of 878 Page 112 of 878 Page 112 of 878 Page 112 of 878 ---PAGE BREAK--- 6445 - CHEWING GUM REMOVER Revision Date: 16-Sep-2014 -Skin Contact: Contact with product may cause frostbite -Inhalation: Nasal discomfort and coughing. May cause central nervous system depression with nausea, headache, dizziness, vomiting, and incoordination -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Target Organ Effects: Central nervous system. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. Data not available or insufficient for classification. Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 propane 74-98-6 Not Available Not Available = 658 mg/L ( Rat ) 4 h N-butane 106-97-8 Not Available Not Available = 658 mg/L ( Rat ) 4 h Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence and Degradability: No information available. Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Pressurized container: Do not pierce or burn, even after use. Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT: UN/ID No: UN1954 Proper Shipping Name: Compressed gases, flammable, n.o.s Hazard Class: 2.1 This product meets the exception requirements of section 49 CFR 173.306 as a limited quantity and may be shipped as a limited quantity. 15. REGULATORY INFORMATION TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product does not contain listed substances above the "de minimus" level SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: Yes Sudden release of pressure hazard: Yes Page 4 / 5 Reactive Hazard: No Page 113 of 878 Page 113 of 878 Page 113 of 878 Page 113 of 878 ---PAGE BREAK--- 6445 - CHEWING GUM REMOVER Revision Date: 16-Sep-2014 California Proposition 65 This product does not contain any Proposition 65 chemicals 16. OTHER INFORMATION Revision Date: 16-Sep-2014 Reasons for Revision: No information available. Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 1 Flammability: 4 Instability: 0 Special: N/A HMIS Page 5 / 5 Health Hazards: 1 Flammability: 4 Physical Hazards: 2 Page 114 of 878 Page 114 of 878 Page 114 of 878 Page 114 of 878 ---PAGE BREAK--- M A T E R I A L S A F E T Y D A T A S H E E T MSDS 726 Page 1 MSDS ITEM NUMBER: 726 VERSION 2 EFFECTIVE DATE: 09/01/05 SUPERCEDES: 07/02/98 PREPARED BY: Regulatory Compliance Section(s) Revised: HMIS, II, III, IV, VI, IX, X IDENTITY (As Used On Label and List): CHEWING GUM REMOVER Freeze Action E M E R G E N C Y M E D I C A L Telephone# 1-[PHONE REDACTED] (24 Hrs) Outside of the U.S.A. Call [PHONE REDACTED] PRODUCT HAZARD RATINGS (HMIS®): Health = 1, Fire = 4, Reactivity = 0, Protective Equipment = B (Rating Legend: 4 = Extreme, 3 = Serious, 2 = Moderate, 1 = Slight, 0 = Minimal) SECTION I Dalco TELEPHONE NUMBER FOR INFORMATION: 1-[PHONE REDACTED] 300 5th Ave NW New Brighton, MN 55112 DATE PRINTED: September 1, 2005 NAME OF PREPARER: Regulatory Compliance SECTION II - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION Chemical Names SARA Title III ACGIH OSHA % By Wt. SEC 313 TLV-TWA/STEL PEL/STEL Liquefied Petroleum Gas Mixture (CAS#68476-85-7) No See below ingredient data 100% Propane (74-98-6) No 1000 ppm/ NE 1000 ppm/ NE (48-55) n-Butane (106-97-8) No 1000 ppm/ NE NE / NE (45-49) Isobutane (75-28-5) No 1000 ppm/ NE NE / NE (0.5-2.0) Unidentified ingredients are not considered hazardous under the Federal Hazard Communication Standard. Components Listed As A Suspected Carcinogen: None SECTION III - PHYSICAL CHARACTERISTICS Boiling Point: NA Vapor Pressure (psig): 175+/- 3 @130F Specific Gravity (H20=1): <1.0 Solubility/Water: Negligible Vapor Density (AIR=1): ND Evaporation Rate (Ether=1): ND Appearance and Odor: Clear, Odorless Gas SECTION IV - FIRE AND EXPLOSION HAZARD DATA Aerosol Flammability: This product is considered to be Flammable as described in 16CFR 1500.45. Flashpoint: <0°F (Propellant); NA (Concentrate) Flammable Limits - % Volume In Air (Propellant): LEL: 1.8 UEL: 9.2 Extinguishing Media: Carbon dioxide, foam and/or dry chemical may be used. Special Fire Fighting Procedures: Containers should be cooled with water to prevent vapor pressure build up. Use equipment or shielding, as required, to protect personnel from bursting, rupturing or venting containers. Unusual Fire and Explosion Hazards: At elevated temperatures (over 54C-130F) containers exposed to direct flame or heat contact should be cooled with water to prevent weakening of container structure. SECTION V - REACTIVITY DATA Stability: Stable Hazardous Polymerization: NA Incompatibility (Materials to Avoid): Oxygen and strong oxidizing agents Hazardous Decomposition Products: Oxides of carbon and additional toxic chemicals may be formed in small amounts. Conditions to Avoid: Do not store above 54C-130F. Keep away from heat, direct sunlight, open flames or sparks. Dropping of containers may cause bursting. Page 115 of 878 Page 115 of 878 Page 115 of 878 Page 115 of 878 ---PAGE BREAK--- M A T E R I A L S A F E T Y D A T A S H E E T MSDS 726 Page 2 SECTION VI - HEALTH HAZARD DATA Route(s) of Entry: Inhalation: X Eyes: X Skin: X Ingestion: X Signs and of Exposure: Inhalation: Simple May cause dizziness, disorientation, headaches and central nervous system depression. Liquified gas may cause freeze burns to skin and eyes. Ingestion: possible frostbite to mucous membranes and central nervous system. Medical Conditions Generally Aggravated by Exposure: Preexisting skin or eye disorders may be aggravated by exposure to this product. Emergency and First Aid Procedures: Inhalation: Remove from exposure, if breathing administer artifical respiration. Seek medical attention. Eye Contact: Vapor may cause mild irritation. Flush eyes with plenty of water for 15 minutes while holding eyelids open. For freeze burns seek medical attention. Skin : Flush affected area with water for 15 minutes. For freeze burns, seek medical attention. If irritation persists obtain medical attention. Ingestion: Seek medical attention. CARCINOGENICITY: No regulated ingredients. SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE Releases or Spilled: Remove all sources of ignition and ventilate area. Soak up spill with an inert absorbent and place into a designated disposal container. Consult local regulatory agency for proper disposition of material. Waste Disposal Method: Do not puncture or incinerate containers. When contents are depleted continue to depress button until all gas is expelled. Dispose of container in accordance with local, state, and federal regulations. Handling And Storing: Avoid breathing vapor. Keep away from heat and flame. Use with adequate ventilation. Do not puncture or incinerate containers. Do not expose to direct sunlight or store at temperatures above 130F (54C). Store as Level 3 Aerosol (NFPA 30B). Other Precautions: Please read and follow the directions on the product label; they are your best guide to using this product in the most effective way, and give the necessary safety precautions to protect your health. SECTION VIII - EMPLOYEE PROTECTION Respiratory Protection (Type): None required if good ventilation is maintained. If exposure exceeds occupational exposure limits (Sec. II), use a NIOSH approved respirator to prevent overexposure. Ventilation: Local exhaust is adequate under normal conditions, mechanical ventilation is optional. Protective Gloves: Chemical resistant gloves*. Eye Protection: Chemical safety glasses are recommended*. Other Protective Clothing or Equipment: Wear impervious clothing to prevent skin contact. Work/Hygienic Practices: Ensure strict sanitary conditions are conformed to when working around chemicals. Protective clothing and equipment should be in accordance with 29 CFR 1910.132 and CFR 1910.133. SECTION IX - OTHER REGULATORY CONTROLS FEDERAL: Toxic Substance Control Act (TSCA): Ingredients of this product are listed on the EPA/TSCA Inventory of Chemical Substances. STATE RIGHT-TO-KNOW: Jersey Right-To-Know (Chemical and CAS No.): Refer to Section II. SECTION X - TRANSPORTATION REQUIREMENTS (D.O.T. CLASSIFICATION) Shipping Name: Aerosols Hazard Class: 3 UN Number: 1950 Packing Group: NA NG-- Negligible NA-- Not Applicable NE-- Not Established UN-- Unavailable ND-- Not Determined While the information set forth herein is believed to be accurate as of the date hereof, the Company makes no warranty or guarantee, express or implied, and disclaims all liability arising out of the use of this information. Page 116 of 878 Page 116 of 878 Page 116 of 878 Page 116 of 878 ---PAGE BREAK--- Page 117 of 878 Page 117 of 878 Page 117 of 878 Page 117 of 878 ---PAGE BREAK--- Page 118 of 878 Page 118 of 878 Page 118 of 878 Page 118 of 878 ---PAGE BREAK--- Page 119 of 878 Page 119 of 878 Page 119 of 878 Page 119 of 878 ---PAGE BREAK--- Page 120 of 878 Page 120 of 878 Page 120 of 878 Page 120 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 472-07 16 00 Section 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DATE OF PREPARATION HMIS CODES Health 1* 472-07 28-FEB-08 Flammability 0 Reactivity 0 PRODUCT NAME CLASSIC ONE™ Interior Latex Flat Finish, Ultra White MANUFACTURER'S NAME DUTCH BOY 101 Prospect Avenue N.W. Cleveland, OH 44115 TELEPHONE NUMBERS and WEBSITES Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency for Chemical Emergency ONLY (spill, leak, (800) 424-9300 fire, exposure, or accident) Section 2 COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE 0.2 14808-60-7 Quartz ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.1 mg/m3 as Resp. Dust 2 14464-46-1 Cristobalite ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.05 mg/m3 as Resp. Dust 17 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction Section 3 HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. Continued on page 2 Page 121 of 878 Page 121 of 878 Page 121 of 878 Page 121 of 878 ---PAGE BREAK--- 472-07 page 2 MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE May cause allergic skin reaction in susceptible persons or skin sensitization. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Section 4 FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. Section 5 FIRE FIGHTING MEASURES FLASH POINT LEL UEL Not Applicable N.A. N.A. FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Section 7 HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Continued on page 3 Page 122 of 878 Page 122 of 878 Page 122 of 878 Page 122 of 878 ---PAGE BREAK--- 472-07 page 3 Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. Section 9 PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 10.67 lb/gal 1278 g/l SPECIFIC GRAVITY 1.28 BOILING POINT 212 - 500 F 100 - 260 C MELTING POINT Not Available VOLATILE VOLUME 73 % EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 9.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.76 lb/gal 91 g/l Less Water and Federally Exempt Solvents 0.22 lb/gal 26 g/l Emitted VOC Continued on page 4 Page 123 of 878 Page 123 of 878 Page 123 of 878 Page 123 of 878 ---PAGE BREAK--- 472-07 page 4 Section 10 STABILITY AND REACTIVITY STABILITY Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Section 11 TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." TOXICOLOGY DATA CAS No. Ingredient Name 14808-60-7 Quartz LC50 RAT 4HR Not Available LD50 RAT Not Available 14464-46-1 Cristobalite LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available Section 12 ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Section 13 DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Continued on page 5 Page 124 of 878 Page 124 of 878 Page 124 of 878 Page 124 of 878 ---PAGE BREAK--- 472-07 page 5 Section 14 TRANSPORT INFORMATION US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. Section 15 REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Section 16 OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 125 of 878 Page 125 of 878 Page 125 of 878 Page 125 of 878 ---PAGE BREAK--- Page 126 of 878 Page 126 of 878 Page 126 of 878 Page 126 of 878 ---PAGE BREAK--- SAFETY DATA SHEET 760215 Page 1 of 7 Date issued 12-February-2015 1 - PRODUCT AND COMPANY IDENTIFICATION Product Name CLR MOLD & MILDEW STAIN REMOVER Restrictions on Use Incompatible with strong oxidizing agents, acids, bases, bleach, and lime. Product Use Aqueous Cleaner for Removal of Mold and Mildew Stains on Painted Walls, Ceramic Tile, Hardwood Floors and Baseboards, Fabrics, Glass, Metal, Concrete, Brick, Marble, Laminated Countertops, Fully Cured and Oil-based Painted Surfaces, Hard Plastics, Automobile Tires, Vinyl Tops, Wood, Glass, and Fiberglass. Retail Package: [32 fl. oz. (946 ml)] Manufacturer: Jelmar, LLC Address: 5550 W. Touhy Ave. Skokie, IL 60077 USA 1(847) 675-8400 Emergency Phone Number: 1(800) 323-5497 (USA) 8:30 A.M. – 4:30 P.M. CST Monday – Friday Emergency 24 hour Contact: Chemtrec 1(800) 424-9300 2 – HAZARDS IDENTIFICATION COMPLIES WITH 29CFR 1900.1200 DATED MAY 2012 WARNING ACUTE EYE IRRITATION (Category 2A) ACUTE DERMAL IRRATION (Category 3) HAZARD NOT OTHERWISE CLASSIFIED ((HNOC) Not applicable OTHER INFORMATION No information available DO NOT get in eyes, on skin or clothing. DO NOT mix with bleach or other household chemicals harmful; fumes may result. DO NOT ingest. DO NOT breathe vapor or mist. Use in well ventilated areas. Keep container closed when not in use. KEEP OUT OF REACH OF CHILDREN Page 127 of 878 Page 127 of 878 Page 127 of 878 Page 127 of 878 ---PAGE BREAK--- SAFETY DATA SHEET 760215 Page 2 of 7 Date issued 12-February-2015 Hazard statement(s) Causes eye irritation. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice. May cause mild skin irritation. Precautionary statement Wash skin thorough after handling. If skin irritation or rash occurs: Get medical advice/attention. Do not eat, drink or smoke when handling this product. Wear protective gloves. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. Avoid breathing fumes. SECTION 3 - COMPOSITION /INFORMATION ON INGREDIENTS Component CAS# OSHA HAZARD % by Weight 1. Alcohols, C9-11, ethoxylated 68439-46-3 YES 1.00-8.00 2. Lauramine Oxide 1643-20-5 YES 1.00-5.00 3. Potassium Bicarbonate 298-14-6 YES 0.25-3.00 The exact percentages (concentration) of mixture has been withheld as a trade secret in accordance to paragraph of §1910.1200. SECTION 4 – FIRST AID MEASURES EYE CONTACT: In case of eye contact, immediately rinse eye thoroughly with plenty of water. Remove contact lenses, and continue rinsing for at least 15 minutes. If irritation persists, get medical attention. SKIN CONTACT: Can be irritating to skin, prolonged contact can be more severe, no adverse effects during normal usage. In case of skin contact, rinse area for at least 15 minutes. Remove contaminated clothing and shoes, wash thoroughly before reuse. If irritation persists get medical attention. INHALATION: Not a significant route of exposure. Remove to fresh air. If breathing is difficult, GET MEDICAL ATTENTION IMMEDIATELY. INGESTION: DO NOT induce vomiting. If fully conscious, drink 16 ounces of water. CALL A OR POISON CONTROL CENTER IMMEDIATELY. NEVER give an unconscious person anything to ingest. SECTION 5 – FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Not flammable. Use appropriate media for area. Use water spray, dry chemical, alcohol-resistant foam or carbon dioxide. HAZARDOUS COMBUSTION PRODUCTS: Carbon Monoxide. Thermal decomposition can lead to irritating gases and vapors. FIRE FIGHTING METHODS: Evacuate area of personnel. Wear protective NIOSH-approved self- contained breathing apparatus. Remain upwind of fire to avoid hazardous vapors and decomposition products. Use water spray to cool fire-exposed containers. Run-off of large quantities of product from fire control may cause pollution. Contact appropriate agencies. FIRE AND EXPLOSION HAZARDS: None known. Page 128 of 878 Page 128 of 878 Page 128 of 878 Page 128 of 878 ---PAGE BREAK--- SAFETY DATA SHEET 760215 Page 3 of 7 Date issued 12-February-2015 SECTION 6 – ACCIDENTAL RELEASES MEASURES Steps to be taken in Case Material is Released or Spilled: Avoid contact with skin and eyes Small Spill: No special clean-up procedure is necessary for small (less than 1 gallon) spills. Flush spill area with water. Wear rubber gloves. Large Spill: Use personal protection recommended in Section 8. Isolate area, and deny entry to unnecessary and unprotected personnel. Dam spill, and absorb with earth, sand or similar material. Place in non-leaking containers. Dispose of collected material according to local, state, and federal regulations. Flush residue with large amount of water. Avoid direct discharge to sewers and surface waters. SECTION 7- HANDLING AND STORAGE HANDLING and STORAGE: Avoid contact with eyes, skin or clothing. May be harmful if swallowed. Use with adequate ventilation. Avoid breathing vapors or mist. Do not eat, drink, or smoke in work area. Wash hands thoroughly after use. Consumer size container (32 fluid ounces), should be rinsed and recycled. Store in cool, well-ventilated area away from heat. Keep containers closed. Avoid contact with strong oxidizing agents, acids, bases, bleach, and lime. DO NOT MIX WITH BLEACH, OR ANY OTHER PRODUCTS AS TOXIC FUMES MAY RESULT. KEEP OUT OF REACH OF CHILDREN. SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES: OSHA ACGIH COMPONENT PEL STEL/C TWA STEL/C 1. Alcohols, C9-11, ethoxylated N.E N.E. N.E. N.E. 2. Lauramine Oxide N.E. N.E. N.E. N.E. 3. Potassium Bicarbonate N.A. N.A. N.A. N.A. VENTILATION REQUIREMENT: Avoid prolonged breathing mists or dusts of this product. Use with adequate ventilation. Do not use in closed or confined spaces. RESPIRATORY PROTECTION: None required during normal household use. Emergency responders should wear self-contained breathing apparatus (SCBA) to avoid inhalation of product. EYE PROTECTION: Not required during normal household usage. Emergency responders should wear full eye and face protection. SKIN PROTECTION: Rubber gloves with protective cuff. Emergency responders should wear impermeable gloves. OTHER PROTECTION: Emergency responders should wear chemical type (impermeable) protective clothing and footwear where direct contact with chemicals in this product is possible. WORK/HYGIENIC PRACTICES: Wash thoroughly with soap and water after use or handling. SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES Appearance: clear, water white liquid Flammability: Not Flammable Odor: Surfactant Upper/Lower Flammability N.A. Odor Threshold: N.D. Vapor Pressure: N.D pH: @20ºC 9.10-9.70 Vapor Density (mm Hg): N.D. Melting Point: N.D. Relative Density @20ºC: 1.010 – 1.030 Freezing Point: N.D Solubility in water: 100% Boiling Point: 97.4ºC / 207ºF Partition Coefficient; N.D. Page 129 of 878 Page 129 of 878 Page 129 of 878 Page 129 of 878 ---PAGE BREAK--- SAFETY DATA SHEET 760215 Page 4 of 7 Date issued 12-February-2015 Boiling Point Range: N.A. n-octanol/water Flash Point: None Auto Ignition Temperature: N.A. Evaporation Rate: N.D Decomposition Temperature: N.A. Viscosity: N.D. SECTION 10 – STABILITY AND REACTIVITY REACTIVITY: N.A. CHEMICAL STABILITY: Stable under normal storage conditions. POSSIBILITY OF HAZARDOUS REACTIONS: N. D. CONDITIONS TO AVOID: Avoid elevated temperatures. INCOMPATIBLE MATERIALS: Strong oxidizing agents, acids, bases, bleach, and lime. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition can lead to release of irritating gases, vapors and carbon oxides. In the event of fire: see Section 5. SECTION 11 – TOXICOLOGICAL INFORMATION Routes of Exposure Eyes, Skin, Inhalation, Ingestion. Eyes Irritant: avoid eye contact. Effects may vary depending on length of exposure, solution concentration Skin Mild Irritant. Prolonged contact may cause dermatitis, and itching. Inhalation No adverse effects expected under typical use conditions. Ingestion Vomiting and gastrointestinal disturbance. LD50 ACUTE EYE IRRITATION: GHS Toxicity Category 2A - Irritant LD50 ACUTE DERMAL IRRATION - RABBITS: GHS Category 3 – Mild Skin Irritation. LD50 ACUTE ORAL TOXICITY – RATS: GHS Category 5 >5,000 mg/kg - Not Toxic LD50 ACUTE DERMAL TOXICITY - RABBITTS: GHS Category 5 >5,000 mg/kg – Not Toxic LD50 ACUTE INHALATION TOXICITY – RATS: GHS Category 5 - Not toxic by inhalation. This product does not contain any substances that are considered carcinogenic by the National Toxicology Program (NTP) Report on Carcinogens and have not been found to be potential carcinogens in the International Agency for Research on Cancer (IARC) Monographs or found to be potential carcinogens by OSHA. Reproductive Toxicity: N.A. Specific Target Organ Toxicity – Single Exposure N.A. Specific Organ Toxicity – Repeated Dose: N. A. SECTION 12- ECOLOGICAL INFORMATION ALCOHOLS, C9-11, ETHOXYLATED: Ecotoxicity Page 130 of 878 Page 130 of 878 Page 130 of 878 Page 130 of 878 ---PAGE BREAK--- SAFETY DATA SHEET 760215 Page 5 of 7 Date issued 12-February-2015 No data on product itself Toxicity to fish – Components Alcohol, C9-11, ethoxylated LC50 (96 hr.): 8.5 mg/l Species: Fathead minnow (Pimephales promelas). Toxicity to daphnia – Components Alcohol, C9-11, ethoxylated EC50 (48 hr.): 5.3 mg/l Species: Daphnia Toxicity to other organisms: No data available. Persistence / degradability: Biodegradability: Readily biodegradable, as defined by OECD, substance that degrades >60-70% within a 10 day window over 28 days. Mobility: No data available Bioaccumulation: No data on the product itself. LAURAMINE OXIDE: Ecotoxicity Acute Aquatic Toxicity Reviewed Category ≤1 mg/L Algae IC50 0.01 mg/L Invertebrate EC50 1.01 mg/L Fish LC50 2.6 mg/L Persistence / degradabilityy Biodegradation: % degraded in 28 days ≥60% ThOD/ThCO2 (≥70% DOC) POTASSIUM BICARBONATE: Ecotoxicity Fish Toxicity:1500 mg/L 96 hour(s) LC50 Bluegill sunfish (practically nontoxic); 1300 mg/L 96 hour(s) LC50 Rainbow trout (practically nontoxic) Invertebrate Toxicity: 1200 mg/L 48 hour(s) EC50 Daphnia magna (practically nontoxic) FATE AND TRANSPORT: Page 131 of 878 Page 131 of 878 Page 131 of 878 Page 131 of 878 ---PAGE BREAK--- SAFETY DATA SHEET 760215 Page 6 of 7 Date issued 12-February-2015 BIODEGRADATION: This material is inorganic and not subject to biodegradation. PERSISTENCE: This material is believed not to persist in the environment. BIOCONCENTRATION: This material is believed not to bioaccumulate. MOBILITY IN SOIL: No data available. SECTION 13 – DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Rinse empty bottles and recycle. Dispose of unused product in a permitted hazardous waste management facility following all local, state, and federal regulations. Follow label warnings, since containers may retain some reside of the product. Processing, use or contamination of this product may change the waste management options. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. State and local disposal regulations may differ from federal disposal regulations. SECTION 14 - TRANSPORTATION INFORMATION UN Number: N.A. UN Proper Shipping Name: N.A. DOT (Department of Transportation Proper Shipping Name): Not regulated by DOT. Packaging Group: N.A. Environmental Hazard: Marine - NO TDG Classification: Not Regulated IMDG Classification: Not Regulated IATA Classification: Passenger – Not Regulated WHIMS (Canada): This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all the information required by CPR. SECTION 15 – REGULATORY INFORMATION FEDERAL REGULATIONS: TSCA INVENTORY STATUS: All components of this product are listed on the TSCA Inventory or are exempt from TSCA Inventory requirements. SARA TITTLE III SECTION 311/312 CATEGORY: IMMEDIATE (ACUTE) HEALTH HAZARARD: YES DELAYED (CHRONIC) HEALTH HAZARD: NO FIRE HAZARD: NO SUDDEN RELEASE OF PRESSURE: NO REACTIVE HAZARD: NO SARA SECTIONS 302/304/313/HAP: NO INTERNATIONAL CHEMICAL INVENTORY STATUS: EUROPEAN UNION (EINECS) YES JAPAN (METI) YES Page 132 of 878 Page 132 of 878 Page 132 of 878 Page 132 of 878 ---PAGE BREAK--- SAFETY DATA SHEET 760215 Page 7 of 7 Date issued 12-February-2015 AUSTRALIA (ACIS) YES KOREA (KECL) YES CANADA (DSL) YES CANADA (NDSL) NO PHILIPPINES YES STATES RIGHT TO KNOW: California, New Jersey, Minnesota, Massachusetts, and Wisconsin. Complies with listed States Right to Know Acts. The following statement is made in order to comply with the California State Drinking Water Act. California Proposition 65: This product does not contain any chemicals known to the State of California to cause cancer and/or to cause birth defects and other reproductive harm. CTION 16 – OTHER INFORMATION Precautions to be taken in Handling and Storing: Avoid exposure to excess heat, and prevent from freezing. NFPA: 1, 0, 0. None Total VOC (wt. 0.09% - does not include any CARB applicable exemptions (Volatile Organic Compounds)/California Air Resources Board CLR MOLD & MILDEW STAIN REMOVER CHEMICAL FATE INFORMATION: 28-day biodegradation. The matter is readily biodegradable. OECD 301D Other Precautions: None required. SDS ABBREVIATIONS: N. Not Applicable N. Not Determined N.E.: Not Established C: Ceiling Limit HAP: Hazardous Air Pollutant VOC: Volatile Organic Compound Revision: GHS Format; Additional information – Sections 3, 8, 12 R. A. Gaudreault Although the information and recommendations set forth herein are presented in good faith and believed to be correct as of the date hereof, JELMAR offers no representations as to the completeness or accuracy thereof. Information is provided upon the condition that the persons receiving same will make their own determination as to its suitability for their purposes prior to use. In no event will JELMAR be responsible for damages of any nature whatsoever resulting from use of or reliance upon said information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH INFORMATION HEREIN REFERS. Page 133 of 878 Page 133 of 878 Page 133 of 878 Page 133 of 878 ---PAGE BREAK--- MSDS ID: 03C0309 03/09 JELMAR MATERIAL SAFETY DATA SHEET CLR CALCIUM LIME & RUST REMOVER ENHANCED FORMULA Page 1 of 5 SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Jelmar LLC Emergency Phone Number: 1(800) 323-5497 (USA) Address: 5550 W. Touhy Ave. Monday – Friday 8:30 A.M. – 4:30 P.M. CST Skokie, IL 60077 Emergency Contact: Chemtrec 1(800) 424-9300 Product Name: CLR- Calcium Lime & Rust Remover (Enhanced Formula) MSDS ID: 03C0309 Chemical Family: Aqueous Acidic Cleaner Formula: Proprietary Mixture SECTION 2 – HAZARDS IDENTIFICATION PHYSICAL STATE: Liquid COLOR: clear, lime green ODOR: sour WARNING OVERVIEW: Irritating to eyes, respiratory tract and mucous membranes. Use with adequate ventilation. Avoid breathing mist or dust. Keep container closed when not in use. POTENTIAL HEALTH EFFECTS ROUTES OF EXPOSURE: Eyes. Skin. Inhalation. Ingestion. TARGET ORGANS: No data. EYE CONTACT: Irritation and blurred vision. Effects may vary depending on length of exposure, solution concentration, and first aid measures. Prolonged contact may cause permanent damage. SKIN CONTACT: Prolonged contact may cause dermatitis, and itching. INHALATION: Irritation, breathing difficulties, headaches, dizziness. INGESTION: Oral burns, vomiting, and gastrointestinal disturbance. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE TO PRODUCT: Eye, skin, and respiratory disorders. CANCER INFORMATION: This product does not contain >0.10% of the known potential carcinogens listed in NTP, IRAC, or OSHA. DO NOT MIX WITH BLEACH, OR ANY OTHER PRODUCT AS TOXIC FUMES MAY RESULT. KEEP OUT OF REACH OF CHILDREN. SECTION 3 - COMPOSITION /INFORMATION ON INGREDIENTS Component CAS# OSHA HAZARD % by Weight 1. Water 7732-18-5 NO 70-81 2. Lactic Acid 79-33-4 YES 15-20 3. Gluconic Acid 526-95-4 N0 2-4 4. Lauryldimethyl Hydroxysultaine 13197-76-7 N0 1-4 5. Propylene Glycol Normal Butyl Ether 5131-66-8 YES 1-2 SECTION 4 – FIRST AID MEASURES EYE CONTACT: In case of eye contact, immediately rinse eye thoroughly with plenty of water. Remove contact lenses, and continue rinsing for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: Can be irritating to skin, prolonged contact can be more severe, no adverse effects during normal usage. In case of skin contact, rinse area for at least 15 minutes. Remove contaminated clothing and shoes, wash thoroughly before reuse. Get immediate medical attention if irritation persists. Page 134 of 878 Page 134 of 878 Page 134 of 878 Page 134 of 878 ---PAGE BREAK--- MSDS ID: 03C0309 03/09 JELMAR MATERIAL SAFETY DATA SHEET CLR CALCIUM LIME & RUST REMOVER ENHANCED FORMULA Page 2 of 5 INHALATION: Not a significant route of exposure. Remove to fresh air. If breathing is difficult, GET MEDICAL ATTENTION IMMEDIATELY. INGESTION: DO NOT induce vomiting. If fully conscious, drink 16 ounces of water. CALL A OR POISON CONTROL CENTER IMMEDIATELY. NEVER give an unconscious person anything to ingest. SECTION 5 – FIRE FIGHTING MEASURES FLAMMABILTY: Not flammable FLASH POINT: None (100º Method: TOC EXPLOSIVE LIMITS IN AIR: Not available EXTINGUISHING MEDIA: Not flammable. Use appropriate media for area. Water spray, dry chemical, alcohol foam or carbon dioxide. FIRE FIGHTING METHODS: Evacuate area of personnel. Wear protective NIOSH-approved self- contained breathing apparatus. Remain upwind of fire to avoid hazardous vapors and decomposition products. Use water spray to cool fire-exposed containers. Run-off of large quantities of product from fire control may cause pollution. Contact appropriate agencies. HAZARDOUS COMBUSTION PRODUCTS: Carbon Monoxide. Thermal decomposition can lead to irritating gases and vapors. FIRE AND EXPLOSION HAZARDS: None known. SECTION 6 – ACCIDENTAL RELEASES MEASURES Steps to be taken in Case Material is Released or Spilled: Avoid contact with skin and eyes Small Spill: No special clean-up procedure is necessary for small (less than 1 gallon) spills. Flush spill area with water. Wear rubber gloves. Large Spill: Use personal protection recommended in Section 8. Isolate area, and deny entry to unnecessary and unprotected personnel. Dam spill, and absorb with earth, sand or similar material. Place in non-leaking containers. Dispose of collected material according to local, state, and federal regulations. Flush residue with large amount of water. Avoid direct discharge to sewers and surface waters. SECTION 7- HANDLING AND STORAGE STORAGE: Store in cool, well-ventilated area, away from heat. Keep containers closed. Avoid contact with combustible materials, wood, and organic materials. Store in original container in a secure area away from children and pets. HANDLING: Avoid contact with eyes, skin or clothing. May be harmful or fatal if swallowed. Use with adequate ventilation. Avoid breathing vapors or mist. Do not eat, drink, or smoke in work area. Wash hand thoroughly after use. Consumer size containers (14, 28, and 42 fluid ounces and gallon containers), should be rinsed and recycled. Empty 5gallon containers and 55gallon drums, may contain product residue in form of vapor, dried product, or liquid, and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE THESE CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY. DO NOT MIX WITH BLEACH, OR ANY OTHER PRODUCTS AS TOXIC FUMES MAY RESULT. KEEP OUT OF REACH OF CHILDREN. Page 135 of 878 Page 135 of 878 Page 135 of 878 Page 135 of 878 ---PAGE BREAK--- MSDS ID: 03C0309 03/09 JELMAR MATERIAL SAFETY DATA SHEET CLR CALCIUM LIME & RUST REMOVER ENHANCED FORMULA Page 3 of 5 SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION VENTILATION REQUIREMENT: Avoid prolonged breathing mists or dusts of this product. Use with adequate ventilation. Do not use in closed or confined spaces. RESPIRATORY PROTECTION: None required during normal household use. If product is used in an industrial setting, respiratory protection must be worn if ventilation does not eliminate or keep levels below recommended exposure limits. If mist or dust is present, wear NIOSH-Approved respirator for dusts and mists, NIOSH-Approved self-contained breathing apparatus, NIOSH-Approved full-face piece positive-pressure, air-supplied respirator. DO NOT exceed limits established by respirator manufacturer. Emergency responders should wear self-contained breathing apparatus (SCBA) to avoid inhalation of product. EYE PROTECTION: Not required during normal household usage. Industrial users wear safety goggles. Do not wear contact lenses. Emergency responders should wear full eye and face protection. SKIN PROTECTION: Rubber gloves with protective cuff. Emergency responders should wear impermeable gloves. OTHER PROTECTION: Emergency responders should wear chemical type (impermeable) protective clothing and footwear where direct contact with chemicals in this product is possible. WORK/HYGIENIC PRACTICES: Wash thoroughly with soap and water after use or handling. EXPOSURE GUIDELINES: OSHA ACGIH COMPONENT PEL STEL/C TWA STEL/C 1. Water N.E. N.E. N.E. N.E. 2. Lactic Acid N.E N.E. N.E. N.E. 3. Gluconic Acid N.E. N.E. N.E. N.E. 4. Lauryldimethyl Hydroxysultaine N.E. N.E. N.E. N.E. 5. Propylene Glycol Normal Butyl Ether N.E. N.E. N.E. N.E. SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES Boiling point: 100º C / 212º F Specific Gravity: 1.05 – 1.06 Vapor Pressure: N.D. Percent Volatiles: ~78.6% (Calculated) Freezing Point: N.D. Evaporation Rate: N.D. (nBuAc=1) Melting Point: N.D. VOC <1.5 (Calculated) Vapor Density (mm Hg): N.D. VOC (LBS/GAL): <0.13 (Calculated) pH: @20ºC ~2 Solubility in Water: 100% SECTION 10 – STABILITY AND REACTIVITY STABILITY: Stable under normal conditions. CONDITIONS TO AVOID: Avoid elevated temperatures. INCOMPATIBLE MATERIALS: Strong oxidizing agents, metals, acids, and bases. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition can lead to release of irritating gases and vapors and carbon oxides. POSSIBILITY OF HAZARDOUS REACTIONS: No data. SECTION 11 – TOXICOLOGICAL INFORMATION ACUTE ORAL EFFECTS: A dose of 5 ml/kg was given to 5 male and 5 female rats and no mortality occurred in 14 days. The acute oral LD50 was found to be > 5 ml/kg. The product is not toxic by oral ingestion in accordance with FHSA / CPSC Guidelines. SKIN: Not a primary dermal irritant in accordance with FHSA / CPSC Guidelines. EYE: Irritant in accordance with FHSA / CPSC Guidelines. Page 136 of 878 Page 136 of 878 Page 136 of 878 Page 136 of 878 ---PAGE BREAK--- MSDS ID: 03C0309 03/09 JELMAR MATERIAL SAFETY DATA SHEET CLR CALCIUM LIME & RUST REMOVER ENHANCED FORMULA Page 4 of 5 SECTION 12- ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION: No data available. CHEMICAL FATE INFORMATION: 28-day biodegradation <60%. The matter is biodegradable. SECTION 13 – DISPOSAL CONSIDERATIONS HAZARDOUS WASTE NUMBER: D002 DISPOSAL METHOD: Dispose of in a permitted hazardous waste management facility following all local, state, and federal regulations. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. Follow label warnings, since containers may retain some reside of the product. Processing, use or contamination of this product may change the waste management options. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. State and local disposal regulations may differ from federal disposal regulations. SECTION 14 - TRANSPORTATION INFORMATION DOT (Department of Transportation Proper Shipping Name): Not regulated by DOT. Identification Number: N.A. Packaging Group: N.A. UN Number: N.A. TDG Classification: Not Regulated IMDG Classification: Not Regulated IATA Classification: Passenger – Not Regulated WHIMS (Canada): This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by CPR. SECTION 15 – REGULATORY INFORMATION FEDERAL REGULATIONS: TSCA INVENTORY STATUS: All components of this product are listed on the TSCA Inventory or are exempt from TSCA Inventory requirements. SARA TITTLE III SECTION 311/312 CATEGORY: IMMEDIATE (ACUTE) HEALTH HAZARARD: YES DELAYED (CHRONIC) HEALTH HAZARD: YES FIRE HAZARD: NO SUDDEN RELEASE OF PRESSURE: NO REACTIVE HAZARD: NO SARA SECTIONS 302/304/313/HAP: COMPENT RQ (LBS) RQ (LBS) TPQ (LBS) SEC 313 HAP Water N.A. N.A. N.A. NO NO Lactic Acid N.A. N.A. N.A. NO NO Gluconic Acid N.A. N.A. N.A. NO NO Lauryldimethyl Hydroxysultaine N.A. N.A. N.A. NO NO Propylene Glycol Normal Butyl Ether N.A. N.A. N.A. NO NO Page 137 of 878 Page 137 of 878 Page 137 of 878 Page 137 of 878 ---PAGE BREAK--- MSDS ID: 03C0309 03/09 JELMAR MATERIAL SAFETY DATA SHEET CLR CALCIUM LIME & RUST REMOVER ENHANCED FORMULA Page 5 of 5 CERCLA Reportable Quantity SARA Reportable Quantity SARA EHS Threshold Planning Quantity SARA 313 Toxic Chemical / Category U. S. EPA Hazardous Air Pollutant INTERNATIONAL CHEMICAL INVENTORY STATUS: EUROPEAN UNION (EINECS) YES JAPAN (METI) YES AUSTRALIA (ACIS) NO* KOREA (KECL) YES CANADA (DSL) YES CANADA (NDSL ) NO PHILIPPINES YES STATES RIGHT TO KNOW: California, New Jersey, Minnesota, Massachusetts, and Wisconsin. None. The following statement is made in order to comply with the California State Drinking Water Act. California Proposition 65: This product does not contain any chemicals known to the State of California to cause cancer and/or to cause birth defects and other reproductive harm. SECTION 16 – OTHER INFORMATION NFPA Rating System: Health-1 / Flammability-0 / Reactivity-0 / Special Hazard - None Precautions to be taken in Handling and Storing: Avoid exposure to excess heat, and prevent from freezing. Other Precautions: None required. MSDS ABBREVIATIONS: N. Not Applicable N. Not Determined N.E.: Not Established C: Ceiling Limit HAP: Hazardous Air Pollutant VOC: Volatile Organic Compound Revision: Section 11 March 2009 R. A. Gaudreault Although the information and recommendations set forth herein are presented in good faith and believed to be correct as of the date hereof, JELMAR LLC offers no representations as to the completeness or accuracy thereof. Information is provided upon the condition that the persons receiving same will make their own determination as to its suitability for their purposes prior to use. In no event will JELMAR LLC be responsible for damages of any nature whatsoever resulting from use of or reliance upon said information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH INFORMATION HEREIN REFERS. Page 138 of 878 Page 138 of 878 Page 138 of 878 Page 138 of 878 ---PAGE BREAK--- 1. PRODUCT AND COMPANY IDENTIFICATION Product name: CONQ-R-DUST Dust Mop / Dust Cloth Treatment (Aerosol) MSDS 114750005 Product Code: 04751 Recommended use: Cleaning product. Emergency telephone number: 1-[PHONE REDACTED] 1-[PHONE REDACTED] (Int'l) 2. HAZARDS IDENTIFICATION Principal routes of exposure: None Eye contact: None Skin contact: None Inhalation: None Ingestion: None 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient(s) CAS # Weight % LD50 Oral - Rat (mg/kg) LD50 Dermal - Rabbit LC50 Inhalation - Rat Isobutane 75-28-5 5 - 10% Not available Not available =658 mg/L (4 h) Propane 74-98-6 1 - 5% Not available Not available =658 mg/L (4 h) 4. FIRST AID MEASURES Aggravated Medical Conditions: Persons with pre-existing skin disorders may be more susceptable to irritating effects 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: Dry chemical, water spray, foam. Specific hazards: Aerosol product - Containers may rocket or explode in heat of fire. Keep product and empty container away from heat and sources of ignition. NFPA 30B Level 1 Aerosol . Unusual hazards: None known Specific methods: No special methods required MATERIAL SAFETY DATA SHEET Canadian Headquarters Diversey, Inc. - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] EMERGENCY OVERVIEW The product contains no substances which at their given concentration, are considered to be hazardous to health CONQ-R-DUST Dust Mop / Dust Cloth Treatment (Aerosol) 1 of 4 Manufacturer, importer, supplier: US Headquarters Diversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-1964 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.diversey.com HMIS CONQ-R-DUST Dust Mop / Dust Cloth Treatment (Aerosol) NFPA Personal protective equipment 4 None / Aucune / Ninguno Health 1 Version Number: 1 Reactivity 0 4 Preparation date:2010-07-14 1 0 Fire Hazard Page 139 of 878 Page 139 of 878 Page 139 of 878 Page 139 of 878 ---PAGE BREAK--- Special protective equipment for firefighters:As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons:No information available 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Use personal protective equipment Environmental precautions and clean-up methods: No information available 7. HANDLING AND STORAGE FOR COMMERCIAL AND INDUSTRIAL USE ONLY. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: None known Personal Protective Equipment Eye protection: No special requirements under normal use conditions Hand protection: No special requirements under normal use conditions Skin and body protection: No special requirements under normal use conditions Respiratory protection: No special requirements under normal use conditions Hygiene measures: Handle in accordance with good industrial hygiene and safety practice Ingredient(s) CAS # ACGIH OSHA Mexico Isobutane 75-28-5 1000 ppm (TWA) Propane 74-98-6 1000 ppm (TWA) 1000 ppm (TWA) 1800 mg/m3 (TWA) 9. PHYSICAL AND CHEMICAL PROPERTIES Explosion limits:- upper:Not determined- lower:Not determined * - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 10. STABILITY AND REACTIVITY Stability: The product is stable Polymerization: Hazardous polymerization does not occur Hazardous decomposition products: None reasonably foreseeable. 11. TOXICOLOGICAL INFORMATION Acute toxicity: Oral LD50 estimated to be greater than 5000 mg/kg Dermal LD50 estimated to be > 2000 mg/kg Component Information: See Section 3 Chronic toxicity: None known Melting point/range:Not determined Bulk density:No information available Decomposition temperature:Not determined Specific gravity:0.9 Autoignition temperature:No information available Solubility:Dispersible Density:7.5lbs/gal0.9Kg/L Color:Yellow Solubility in other solvents:No information available Appearance:Aerosol Flash point:<20°F<-7°C Vapor density:No information available Partition coefficient (n-octanol/water):No information available Viscosity:No information available Physical State:Aerosol Elemental Phosphorus:0% by wt. Odor:Solvent VOC:19.4% * pH:No information available Boiling point/range:Not determined Dilution pH:No information available. Evaporation RateNo information available CONQ-R-DUST Dust Mop / Dust Cloth Treatment (Aerosol) 2 of 4 Page 140 of 878 Page 140 of 878 Page 140 of 878 Page 140 of 878 ---PAGE BREAK--- Specific effects Carcinogenic effects: None known Mutagenic effects: None known Reproductive toxicity: None known Target organ effects: None known 12. ECOLOGICAL INFORMATION Environmental Information: No data available 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Dispose of according to all federal, state and local applicable regulations 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the following inventories:U.S.A. (TSCA), Canada (DSL/NDSL). U.S. Regulations California Proposition 65:This product is not subject to the reporting requirements under California's Proposition 65 RIGHT TO KNOW (RTK) Ingredient(s) CAS # MARTK: PARTK: RIRTK: Water 7732-18-5 - - - - Petroleum hydrocarbon 64741-44-2 - - - - Isoparaffinic hydrocarbon solvent 64742-48-9 - - - - Isobutane 75-28-5 X X X - Propane 74-98-6 X X X X CERCLA/ SARA SARA 311/312 Hazard Categories Immediate: - Delayed: - Fire: X Reactivity: - Sudden Release of Pressure: - Canada WHMIS hazard class:A Compressed gases Ingredient(s) CAS # NPRI Isoparaffinic hydrocarbon solvent 64742-48-9 X Propane 74-98-6 X 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: None DOT/TDG:Please refer to the Bill of Lading/receiving documents for up to date shipping information CONQ-R-DUST Dust Mop / Dust Cloth Treatment (Aerosol) 14. TRANSPORT INFORMATION 3 of 4 Page 141 of 878 Page 141 of 878 Page 141 of 878 Page 141 of 878 ---PAGE BREAK--- Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 4 of 4 CONQ-R-DUST Dust Mop / Dust Cloth Treatment (Aerosol) Page 142 of 878 Page 142 of 878 Page 142 of 878 Page 142 of 878 ---PAGE BREAK--- JOHNSON DIVERSEY CONQ-R-DUST PRESSURIZED Revised: 1/13/2004 MSDS Contents SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION SECTION 2. COMPOSITION AND INFORMATION ON INGREDIENTS SECTION 3. HAZARDS IDENTIFICATION SECTION 4. FIRST AID MEASURES SECTION 5. FIRE FIGHTING MEASURES SECTION 6. ACCIDENTAL RELEASE MEASURES SECTION 7. HANDLING AND STORAGE SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES SECTION 10. STABILITY AND REACTIVITY SECTION 11. TOXICOLOGICAL INFORMATION SECTION 12. ECOLOGICAL INFORMATION SECTION 13. DISPOSAL CONSIDERATIONS SECTION 14. TRANSPORT INFORMATION SECTION 15. REGULATORY INFORMATION SECTION 16. OTHER INFORMATION Item Number: 3VB33 Mfg. Model Number: 5231 JOHNSON WAX PROFESSIONAL MATERIAL SAFETY DATA SHEET CONQ-R-DUST PRESSURIZED NATIONAL FIRE PROTECTION ASSOCIATION (NFPA): HEALTH 1 FIRE HAZARD 4 REACTIVITY 0 SPECIFIC HAZARD HAZARDOUS MATERIAL INFORMATION SYSTEM (HMIS): HEALTH 1 FIRE HAZARD 4 REACTIVITY 0 PROTECTIVE CLOTHING: NONE REQUIRED. EMERGENCY OVERVIEW: CLEAR YELLOW. AEROSOL. SEE SECTION 9. CAUTION: CONTENTS UNDER PRESSURE. MAY BE MILDLY IRRITATING TO EYES. SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: CONQ-R-DUST PRESSURIZED Page 143 of 878 Page 143 of 878 Page 143 of 878 Page 143 of 878 ---PAGE BREAK--- PRODUCT USE: INDUSTRIAL/INSTITUTIONAL: CLEANING PRODUCT. CODE: 4751 PMS#: 433114 MSDS#: 114750005 U.S. HEADQUARTERS: JOHNSONDIVERSEY, INC. 8310 16TH STREET STURTEVANT, WISCONSIN 53177-0902 PHONE: (888) 352-2249 MSDS INTERNET ADDRESS: WWW.JOHNSONDIVERSEY.COM CANADIAN HEADQUARTERS: JOHNSONDIVERSEY - CANADA, INC. 2401 BRISTOL CIRCLE OAKVILLE, ONTARIO L6H 6P1 PHONE: 1-[PHONE REDACTED] IN CASE OF EMERGENCY: (800) 851-7145 VALIDATION DATE: 1/13/2004 PRINT DATE: 1/13/2004 SUPERSEDES: NO PREVIOUS VALIDATION. SECTION 2. COMPOSITION AND INFORMATION ON INGREDIENTS INGREDIENTS CAS # % BY EXPOSURE LIMITS WEIGHT SORBITAN MONOOLEATE 1338-43-8 1-5 NOT AVAILABLE. PROPANE 74-98-6 1-5 OSHA (UNITED STATES). TWA: 1800 MG/M3 ACGIH (UNITED STATES). TWA: 4508 MG/M3 OSHA PEL (UNITED STATES, 1993). NOTES: TWA: 1800 MG/M3 8 HOUR(S). TWA: 1000 PPM 8 HOUR(S) ISOBUTANE 75-28-5 5-10 Page 144 of 878 Page 144 of 878 Page 144 of 878 Page 144 of 878 ---PAGE BREAK--- LIGHT NAPHTHENIC DISTILLATE 64741-44-2 10-30 NOT AVAILABLE. ISOPARAFFINIC HYDROCARBON 64742-48-9 5-10 NOT AVAILABLE. SOLVENT WATER 7732-18-5 60-100 NOT AVAILABLE. INGREDIENTS LC50/LD50 SORBITAN MONOOLEATE NOT AVAILABLE. PROPANE NOT AVAILABLE. ISOBUTANE VAPOR (LC50): ACUTE: 0.0057 PPM 0.25 HOUR(S) (RAT). LIGHT NAPHTHENIC DISTILLATE NOT AVAILABLE. ISOPARAFFINIC HYDROCARBON NOT AVAILABLE. SOLVENT WATER NOT AVAILABLE. SECTION 3. HAZARDS IDENTIFICATION ROUTES OF ENTRY: INHALATION. SKIN CONTACT. EYE CONTACT. POTENTIAL ACUTE HEALTH EFFECTS: EYES: MAY BE MILDLY IRRITATING TO EYES. SKIN: PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. INHALATION: MAY BE IRRITATING TO NOSE, THROAT, AND RESPIRATORY TRACT. INGESTION: MAY BE HARMFUL IF SWALLOWED. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: NONE KNOWN. SEE TOXICOLOGICAL INFORMATION (SECTION 11) SECTION 4. FIRST AID MEASURES EYE CONTACT: FLUSH IMMEDIATELY WITH PLENTY OF WATER. GET MEDICAL ATTENTION IF IRRITATION OCCURS. Page 145 of 878 Page 145 of 878 Page 145 of 878 Page 145 of 878 ---PAGE BREAK--- SKIN CONTACT: RINSE WITH PLENTY OF RUNNING WATER. INHALATION: IF BREATHING IS DIFFICULT: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION. INGESTION: IMMEDIATELY DRINK PLENTY OF WATER. DO NOT INDUCE VOMITING UNLESS TOLD TO DO SO BY A POISON CONTROL CENTER OR DOCTOR. SECTION 5. FIRE FIGHTING MEASURES FLAMMABILITY OF THE PRODUCT: NFPA 30B LEVEL 2 AEROSOL. FLASH POINTS: CLOSED CUP: < -7 DEG. C (19.4 DEG. F).(PROPELLANT) PRODUCTS OF COMBUSTION: NONE KNOWN. FIRE FIGHTING MEDIA AND INSTRUCTIONS: USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL. DRY CHEMICAL, CARBON DIOXIDE. FIGHT FIRE FROM PROTECTED LOCATION OR MAXIMUM POSSIBLE DISTANCE. IN CASE OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES.. PROTECTIVE CLOTHING (FIRE): PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION SPECIAL REMARKS ON FIRE AND EXPLOSION HAZARDS: AEROSOL PRODUCT - CONTAINERS MAY ROCKET OR EXPLODE IN HEAT OF FIRE. VAPORS MAY ACCUMULATE IN LOW OR CONFINED AREAS. SECTION 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION ENVIRONMENTAL PRECAUTIONS AND CLEAN-UP METHODS: ELIMINATE ALL IGNITION SOURCES. IN THE EVENT OF MAJOR SPILLAGE: USE APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION. TAKE UP WITH SAND OR OTHER NON-COMBUSTIBLE MATERIAL. PLACE IN SUITABLE CLEAN, DRY CONTAINERS FOR DISPOSAL BY APPROVED METHODS. Page 146 of 878 Page 146 of 878 Page 146 of 878 Page 146 of 878 ---PAGE BREAK--- SECTION 7. HANDLING AND STORAGE HANDLING: AVOID CONTACT WITH EYES. AVOID BREATHING VAPORS OR SPRAY MISTS. USE APPROPRIATE HYGIENE MEASURES WHEN HANDLING PRODUCT. USE ONLY IN WELL-VENTILATED AREAS. DO NOT PUNCTURE OR INCINERATE. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. STORAGE: STORE IN A DRY, COOL AND WELL-VENTILATED AREA. PROTECT FROM FREEZING. KEEP AWAY FROM HEAT, SPARKS AND FLAME. PRESSURIZED CONTAINER: PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURE EXCEEDING 50 DEG. C. DO NOT PIERCE OR BURN, EVEN AFTER USE. KEEP OUT OF REACH OF CHILDREN. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: NO SPECIAL VENTILATION REQUIREMENTS. GENERAL ROOM VENTILATION IS ADEQUATE. PERSONAL PROTECTION: EYES: NO SPECIAL REQUIREMENTS UNDER NORMAL USE CONDITIONS. HANDS: NO SPECIAL REQUIREMENTS UNDER NORMAL USE CONDITIONS. RESPIRATORY: NO SPECIAL REQUIREMENTS UNDER NORMAL USE CONDITIONS. FEET: NO SPECIAL REQUIREMENTS UNDER NORMAL USE CONDITIONS. BODY: NO SPECIAL PROTECTIVE CLOTHING IS REQUIRED. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE AND APPEARANCE: LIQUID. (AEROSOL.) ODOR: MILD. COLOR: CLEAR YELLOW. SPECIFIC GRAVITY: 0.9 SOLUBILITY IN WATER: NEGLIGIBLE. Page 147 of 878 Page 147 of 878 Page 147 of 878 Page 147 of 878 ---PAGE BREAK--- SECTION 10. STABILITY AND REACTIVITY STABILITY AND REACTIVITY: THE PRODUCT IS STABLE. CONDITIONS OF INSTABILITY: EXCESSIVE HEAT. INCOMPATIBILITY WITH VARIOUS SUBSTANCES: NONE KNOWN. HAZARDOUS DECOMPOSITION PRODUCTS: WHEN EXPOSED TO FIRE: PRODUCES NORMAL PRODUCTS OF COMBUSTION. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. SECTION 11. TOXICOLOGICAL INFORMATION ACUTE TOXICITY: ORAL (LD50): GREATER THAN 5000 MG/KG (RAT). EFFECTS OF CHRONIC EXPOSURE: NONE KNOWN. OTHER TOXIC EFFECTS: NONE KNOWN. SECTION 12. ECOLOGICAL INFORMATION NOT AVAILABLE. SECTION 13. DISPOSAL CONSIDERATIONS WASTE INFORMATION: IF POSSIBLE, RECYCLE EMPTY AEROSOL CANS TO THE NEAREST STEEL RECYCLING CENTER. USE UP PACKAGE OR GIVE TO SOMEONE WHO CAN. DISPOSE OF ACCORDING TO ALL FEDERAL, STATE AND LOCAL REGULATIONS. Page 148 of 878 Page 148 of 878 Page 148 of 878 Page 148 of 878 ---PAGE BREAK--- SECTION 14. TRANSPORT INFORMATION DOT CLASSIFICATION: DOT PROPER SHIPPING NAME: PLEASE REFER TO THE BILL OF LADING/RECEIVING DOCUMENTS FOR UP TO DATE SHIPPING INFORMATION. TDG CLASSIFICATION: TDG PROPER SHIPPING NAME: PLEASE REFER TO THE BILL OF LADING/RECEIVING DOCUMENTS FOR UP TO DATE SHIPPING INFORMATION. TDG CLASS: SECTION 15. REGULATORY INFORMATION REPORTING IN THIS SECTION IS BASED ON INGREDIENTS DISCLOSED IN SECTION 2 US REGULATIONS: FEDERAL: SARA 302/304/311/312 HAZARDOUS CHEMICALS: PROPANE, ISOBUTANE SARA 311/312 MSDS DISTRIBUTION - CHEMICAL INVENTORY - HAZARD IDENTIFICATION: PROPANE, ISOBUTANE CLEAN AIR ACT (CAA) 112 ACCIDENTAL RELEASE PREVENTION: PROPANE, ISOBUTANE CLEAN AIR ACT (CAA) 112 REGULATED FLAMMABLE SUBSTANCES: PROPANE, ISOBUTANE CERCLA: HAZARDOUS SUBSTANCES.: PROPANE, ISOBUTANE STATE: NEW JERSEY: LIGHT NAPHTHENIC DISTILLATE, PROPANE, ISOBUTANE, LIGHT NAPHTHENIC DISTILLATE MASSACHUSETTS SPILL LIST: PROPANE, ISOBUTANE MASSACHUSETTS RTK: PROPANE, ISOBUTANE Page 149 of 878 Page 149 of 878 Page 149 of 878 Page 149 of 878 ---PAGE BREAK--- RTK: PROPANE, ISOBUTANE THIS PRODUCT IS NOT SUBJECT TO THE REPORTING REQUIREMENTS UNDER CALIFORNIA'S PROPOSITION 65. REGISTERED PRODUCT INFORMATION: NOT APPLICABLE. CANADIAN REGULATIONS: WHMIS CLASSIFICATION: NOT CONTROLLED UNDER WHMIS (CANADA). WHMIS ICON: NOT CONTROLLED UNDER WHMIS. REGISTERED PRODUCT INFORMATION: NOT APPLICABLE. CHEMICAL INVENTORY STATUS: ALL INGREDIENTS OF THIS PRODUCT ARE LISTED OR ARE EXCLUDED FROM LISTING ON THE U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL SUBSTANCE INVENTORY. SECTION 16. OTHER INFORMATION OTHER SPECIAL CONSIDERATIONS: NOT AVAILABLE. VERSION: 1.02 NOTICE TO READER: THIS DOCUMENT HAS BEEN PREPARED USING DATA FROM SOURCES CONSIDERED TECHNICALLY RELIABLE. IT DOES NOT CONSTITUTE A WARRANTY, EXPRESS OR IMPLIED, AS TO THE ACCURACY OF THE INFORMATION CONTAINED WITHIN. ACTUAL CONDITIONS OF USE AND HANDLING ARE BEYOND SELLER'S CONTROL. USER IS RESPONSIBLE TO EVALUATE ALL AVAILABLE INFORMATION WHEN USING PRODUCT FOR ANY PARTICULAR USE AND TO COMPLY WITH ALL FEDERAL, STATE, PROVINCIAL AND LOCAL LAWS AND REGULATIONS. Page 150 of 878 Page 150 of 878 Page 150 of 878 Page 150 of 878 ---PAGE BREAK--- 81765 U.S. DEPARTMENT OF LABOR f orrn Auprovra OMB NO. 44-R1387 Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915. 1916, 191 7) I SECTION 1 MANUFACTURE d for: ( EMERGENCY TELEPHONE NO. LAWSON PROD~ICTS, INC. 1 (31 2) 827-9666 AOORESS Srrerr. City, Stare. and ZIP Codr! SECTION II - HAZARDOUS INGREDIENTS PAINTS, PRESERVATIVES, i SOLVENTS I x 1 1 ALLOYS AND METALl.,Ic co*TINCs TLV niu , I % IUniol 1 u c i T Finn1 8 - - - PIGMENTS 1 BALE M E T A L I ) . . CHE MlCAL NAME A N I CATALYST 1 I ( ALLOYS I ! I TRADE NAME AND SYNONYMS T METALLIC COATINGS CHEMICAL FAMILY Cool I t I I ADDITIVES 1 I / OTHERS 1 I I I I HAZARDOUS MIXTURES OF OTHER LIQUIDS. SOLIDS. OR GASES Lubricating O i l CAS. NO. None-Proprietary B l end SOLVENTS 1 ,I ,I , Trichloroethane CAS. NO. 71-55-6 - FILLER METAL PLUS COATING OR CORE FLUX - - - SECTION I I1 - PHYSICAL DATA BOILING POINT (OF.) 1 7 1 6 S ° F I ~ P E C I F I C G R ~ V I T Y ( ~ ~ O - I ) (7 1 I SOLUBILITY IN WATER 1 I 1 1 (mm Aeros01@700F VAPOR DENSITY (AIR-1) 1 APPEARANCE AND ODOR Amber, Chlorinated Odor I I SECTION IV - FIRE fIi4D EXPLOSION HAZARD DATA I 90+ 5 7 1 - . . FLASH POINT (MmthoQ u-I NA FLAMMABLE LIMITS NA I b l I U.1 PERCENT. VOLATILE ! BY VOLUME :t 90% EVAPORATION RATE 1 = I ) 17 'I I 1 MEOlA Carbon Di o x i de , Foam PROCEDURES None UNUSUAL FIRE AND EXPLOSION HAZARDS Treat as aerosol containers: Cylinders of compressed PAGE 11) (Continued on reverse side) Form OSHA-20 7 2 / q c Page 151 of 878 Page 151 of 878 Page 151 of 878 Page 151 of 878 ---PAGE BREAK--- SECTION V - HEALTH HAZARD DATA - -WRESUOLD LIMIT VALUE ~ = F E C T S OF OVEREXPOSURE Hazards frorr. vzpor are chiefly those o f an anesthetic. Remove , i rom contaminated area. If breathing has stopped administer a r t i f i c f a l respiration. E b l E 9 5 E N C y AND FIRST AID PROCEDURES S K I N T A C T : Waqh w i t h scaD and water. EYES: Wash with - - / I dater. I f i r r i t a t i o n persists, c a l l a physician. L - 1 I SECTION VI - REACTIVITY DATA I I a ~ ~ r o ~ r i a t e container. I -4 4 1 T, ' o~spOsALMrT*oo Dispose o f container i n a safe fashion using land f i l l or other -opriate methods-in accordance with Federal, State o r local regulations. CONDITIONS Heat, e l e c t r i c a l sparks, and open STAB:LITY SECTION VII - SPILL OR LEAK PROCEDURES STEPS T O BE TAKEN IN CASE M A T E R I A L IS RELEASED OR SPILLED Use dry absorbent and place i n UNSTABLE I , . i 1 STABLE SECTION Vlll - SPECIAL PROTECTION INFORMATION 1 RESPIRATORY PRO?ECTlON (Spcc~fy type) X X 1 flames. V E N T I U T I O N ' INCOMPATASI LITY (Ma~eriaIs to ovoid; A1 umi num ' HAZARDOUS OECOMPOS~?~ON PRODUCTS Hydrochloric acid and t o x i c materi a1 s i n small amounts. LOCAL EXHAUST xxx MECHAN 1 C A L {General) SPECIAL OTHER PROTECTIVE GLOVES N A. HAZARDOUS POLVMERIZATION EYE p ~ o ~ ~ c ~ l o ~ ~ a f e t y g l asses o r face s h i e l d ' 3 f XXX MAY OCCUR WILL N O T OCCUR f SECTION IX - SPECIAL PRECAUTIONS .'RECAUTIONS T O BE T A K E N I N H A N O L I N G AND STORING Keep away from heat sources and where tern- perature 'COUI d exceed 120oF. 3THER PRECAUTIONS Read directions on can 1 abel p r i o r t o using material . CONOITIONS T O A V O I D Page 152 of 878 Page 152 of 878 Page 152 of 878 Page 152 of 878 ---PAGE BREAK--- Page 153 of 878 Page 153 of 878 Page 153 of 878 Page 153 of 878 ---PAGE BREAK--- Page 154 of 878 Page 154 of 878 Page 154 of 878 Page 154 of 878 ---PAGE BREAK--- Page 155 of 878 Page 155 of 878 Page 155 of 878 Page 155 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Section 1 - Chemical Product & Company Identification Identity (As Used on Label and List): Dal-Pro #14 Orbit Product Class: Water-based carpet and hard surface cleaner. Emergency Telephone Number: [PHONE REDACTED] Telephone Number for Information: [PHONE REDACTED] Distributed By: Dalco 300 5th Ave NW New Brighton, Minnesota 55112 Section 2 - Composition/Information On Ingredients Hazardous Components (Specific Chemical Identity): Chemical Common Name(s) % A Citric Acid 5 - 15 CAS #77-92-9 B Phosphoric Acid 1 - 5 CAS #7664-38-2 C Sodium Alkyl Napthalene Sulfonate 1 - 5 CAS # (Mixture) D Water 60 - 100 CAS #7732-18-5 Section 3 - Hazards Identification Emergency Overview Appearance and Odor: Orange liquid, citrus/floral fragrance. Primary Hazards: Corrosive Potential Health Hazards Route(s) of Entry: Skin Absorption: Ingestion: X Inhalation: Eye: May cause burns on contact. Skin: May cause burns on contact. Ingestion: Harmful if swallowed. Inhalation: No hazardous vapors. Signs and of Exposure: Irritation on direct contact. Carcinogenicity: NTP? No IARC Monographs? No OSHA Regulated? No Target Organ No additional data Medical Conditions Generally Aggravated by Exposure: N. Av. Health Hazards, Chronic: N. Av. Section 4 - First Aid Measures Emergency and First Aid Procedures: If Swallowed: Do not induce vomiting. If a person can swallow, give several glasses of water. Obtain immediate medical attention. Eye Contact: Flush eyes with running water for at least 15 minutes. Obtain immediate medical attention. Skin Contact: Flush with cool water. Remove and wash contaminated clothing before reuse. For Inhalation: Remove to fresh air. If irritation persists, get medical attention. Sources Used: Raw material data, general toxicology from the trade for similar products. Section 5 - Fire Fighting Measures Flammability: No Autoignition Temperature: N. Ap. Flash Point (method used): None Flammable Limits: N. Ap. LEL UEL Extinguishing Media N. Ap. Water? Foam? Water Fog? Alcohol Foam? CO2? Dry Chemical? Vaporizing Liquid? Other? Special Fire Fighting Procedures: N. Ap. Unusual Fire and Explosion Hazards: N. Av. TDG Flammability Classification: Non-flammable Sensitivity to Mechanical Impact: None Sensitivity to Static Discharge: None Section 6 - Accidental Release Measures Steps to be Taken in Case Material is Released or Spilled: Dike and contain spill with inert material (sand, earth, etc). Collect spill with mop, absorbent material (example: floor-dri) or vacuum. Thoroughly rinse affected area with water. Section 7 - Handling And Storage Precautions to be Taken in Handling and Storing: Normal care in handling and storage. Other Precautions: Keep out of reach of children. Keep from freezing. Section 8 - Exposure Controls/Personal Protection Respiratory Protection (Specify Types): Not required Ventilation: Local Exhaust: Not required Special: Not required Mechanical (General): Normal good ventilation sufficient. Other: Not required Protective Gloves: Natural rubber or Eye Protection: Approved safety goggles or glasses. Footwear: Not required Other Protective Clothing or Equipment: Not required Work/Hygienic Practices: Do not contaminate food or beverages with cleaning chemicals. Section 9 - Physical/Chemical Characteristics Boiling Point: Approximately 212°F pH: 2-3 solution) Specific Gravity (H20) = 1: 1.07 % Volatile: >80% Vapor Density (Air = < 1 Odor Threshold: N. Av. Evaporation Rate (Butyl Acetate = N. Av. Oil/Water Distribution Solubility in Water: Complete Coefficient: N. Av. Vapor Pressure (MM HG): N. Av. Melting Point: N. Ap. Section 10 - Stability And Reactivity Stability: Unstable: Stable: X Conditions to Avoid: Do not mix with any other chemicals, especially alkaline, bleach or ammonia cleaners. Avoid contact with alkaline materials & reactive metals. Incompatibility (materials to avoid): Mild steel and aluminum may react to produce hydrogen gas that can produce an explosive in confined vessels. Do not use on marble, terrazzo or natural stone. Hazardous Decomposition or By-products: N. Av. Hazardous Polymerization: May occur: Will not occur: X Conditions to Avoid: N. Ap. Section 11 - Toxicological Information Chemical OSHA PEL ACGIH TLV Recom. LD50 LC50 A None None N. Av. 11.7 gm/kg N. Av. (rat, oral) B 1 mg/m3 1 mg/m3 N. Ap. 4,400 mg/kg 7.7 mg/L (rat, oral) (rat, 4 hrs.) C None None N. Av. 3,400 mg/kg N. Av. (rat, oral) D None None N. Av. N. Av. N. Av. Teratogen, Mutagen, Reproductive Toxin Status: No Toxicologically Synergistic Products: N. Av. Section 12 - Ecological Information Ecotoxicological Information: N. Av. Chemical Fate Information: N. Av. Section 13 - Disposal Considerations Waste Disposal Method: Neutralize and dispose of spilled material in accordance with local, state and federal regulations. Waste from normal cleaning procedures may be sewered, depending on the materials and/or contaminates being cleaned as well as state, federal and local sewer commission regulations. RCRA Hazard Class: None Section 14 - Transport Information Shipping Classification: Corrosive Liquid, Acidic Inorganic, N.O.S. (Containing Phosphoric Acid), Class 8 UN Number: UN3264 Packing Group: II Section 15 - Preparation Data Prepared By: Mike Elms Telephone Number: [PHONE REDACTED] Date: 7-10 Section 16 - Regulatory Information US Federal Regulations TSCA Status: All ingredients listed. CERCLA Reportable Quality: 5,000 Pounds (Phosphoric Acid) SARA Title III Section 302 Extremely Hazardous Chemicals: None Section 311/312 Hazard Category: Immediate health hazard Section 313 Toxic Chemicals: Phosphoric Acid State Regulations NOTICE STATE OF CALIFORNIA Warning: This product may contain chemicals known to the State of California to cause cancer or reproductive defects as trace impurities in the standard industrial materials used in the manufacture of this product. International Regulations WHMIS Controlled Product Hazard Class: E Section 17 - Other Information None N. Ap. - Not Applicable; N.Av. - Not Available NFPA SYSTEM A. Health Hazard A. Fire Hazard A. Reactivity Hazard THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE, HOWEVER NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. MINUTEMAN INTERNATIONAL, INC. ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE TO VENDEES, USERS OR THIRD PARTIES CAUSED BY THE MATERIAL. SUCH VENDEES OR USERS ASSUME ALL RISKS ASSOCIATED WITH THE USE OF THE MATERIAL. (Complies with 29CFR 1910.1200) Page 156 of 878 Page 156 of 878 Page 156 of 878 Page 156 of 878 ---PAGE BREAK--- Page 157 of 878 Page 157 of 878 Page 157 of 878 Page 157 of 878 ---PAGE BREAK--- Page 158 of 878 Page 158 of 878 Page 158 of 878 Page 158 of 878 ---PAGE BREAK--- I M A T E R I A L S A F E T Y D A T A S H E E T I I SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION I PRODUCT NAME : 2000 CONSTRUCTION ADHESIVE UPC NUMBER : [PHONE REDACTED], 70709825013, [PHONE REDACTED], [PHONE REDACTED], [PHONE REDACTED] PRODUCT USE/CLASS : Construction Adhesive MANUFACTURER: 24 HOUR EMERGENCY: DAP INC. TRANSPORTATION: 1-[PHONE REDACTED] ([PHONE REDACTED]) 2400 BOSTON ST. MEDICAL : 1-[PHONE REDACTED] ([PHONE REDACTED]) BALTIMORE, MD 21224 PREPARE DATE : 02/03/1999 GENERAL INFORMATION: REVISION NO. : 6 DAP INC.: 1-800-DAP-TIPS (1-[PHONE REDACTED]) REVISION DATE: 02/14/2000 I SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS I WT/WT % ITEM CHEMICAL NAME CAS NUMBER RANGE 01 N-Hexane 110-54-3 5.0-10.0 % 02 Aliphatic Petroleum Distillate 64742-89-8 15.0-20.0 % 03 2-Methyl Pentane 107-83-5 5.0-10.0 % 04 3-Methyl Pentane 96-14-0 5.0-10.0 % EXPOSURE LIMITS ACGIH OSHA COMPANY ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN 01 50 ppm N.E. 50 ppm N.E. N.E. NO 02 400 ppm N.E. 400 ppm N.E. N.E. NO 03 N.E. N.E. N.E. N.E. N.E. NO 04 N.E. N.E. N.E. N.E. N.E. NO (See Section 16 for abbreviation legend) Remaining ingredients are not considered hazardous per the OSHA Hazard Communication Standard. Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); limits may vary between states. (Continued on Page 2) Page 159 of 878 Page 159 of 878 Page 159 of 878 Page 159 of 878 ---PAGE BREAK--- Product Name: 2000 CONSTRUCTION ADHESIVE Revision Date: 02/14/2000 Page 2 I SECTION 3 - HAZARDS IDENTIFICATION I EMERGENCY OVERVIEW: DANGER! Extremely flammable liquid and vapor. Vapor harmful. Harmful or fatal if swallowed. Vapors may cause flash fire or explosion. Aspiration hazard if swallowed - can enter lungs and cause damage. Harmful if inhaled. POTENTIAL HEALTH EFFECTS: EFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May irritate skin. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). EFFECTS OF OVEREXPOSURE - INHALATION: Vapor harmful if inhaled. Vapor may irritate nose and upper respiratory tract. Vapor inhalation may affect the brain or nervous system causing dizziness, headache or nausea. EFFECTS OF OVEREXPOSURE - INGESTION: This material may be harmful or fatal if swallowed. Aspiration of material into the lungs due to vomiting can cause chemical pneumonitis which can be fatal. If ingested, this product may cause vomiting, diarrhea, and depressed respiration. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated permanent brain and nervous system damage with prolonged and repeated occupational overexposure to solvents. Hexane exposure may cause damage to the arms and legs which may be permanent. include: loss of memory, loss of intellectual ability, and loss of coordination. MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT: None known. PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT INHALATION I SECTION 4 - FIRST AID MEASURES I EYE CONTACT: Flush with large quantities of water until irritation subsides. Contact a physician. SKIN CONTACT: Wash with soap and water. INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Contact a physician immediately. Note: Only trained personnel should give artificial respiration or administer oxygen. (Continued on Page 3) Page 160 of 878 Page 160 of 878 Page 160 of 878 Page 160 of 878 ---PAGE BREAK--- Product Name: 2000 CONSTRUCTION ADHESIVE Revision Date: 02/14/2000 Page 3 I SECTION 4 - FIRST AID MEASURES I INGESTION: DO NOT INDUCE VOMITING. If irritation or complications arise, contact a physician or Regional Poison Control Center immediately. COMMENTS: None. I SECTION 5 - FIRE FIGHTING MEASURES I FLASH POINT: -30 F LOWER EXPLOSIVE LIMIT: N.A. (SETAFLASH CLOSED CUP) UPPER EXPLOSIVE LIMIT: N.A. AUTOIGNITION TEMPERATURE: N.E. EXTINGUISHING MEDIA: CO2 DRY CHEMICAL FOAM UNUSUAL FIRE AND EXPLOSION HAZARDS: Extremely flammable. Material will readily ignite at room temperature. Vapors may form an explosive mixture with air. Vapors can travel long distances to a source of ignition and flashback. Containers may explode if exposed to extreme heat. Eliminate sources of ignition: heat, electrical equipment, sparks, and flames. Do not put in contact with oxidizing or caustic materials. SPECIAL FIREFIGHTING PROCEDURES: Full protective equipment, including self-contained breathing apparatus, is recommended to protect from combustion products. Cool exposed containers with water. I SECTION 6 - ACCIDENTAL RELEASE MEASURES I SPILL OR LEAK PROCEDURES: Dike spill area. Immediately eliminate sources of ignition. Use absorbent material or scrape up dried material and place into containers. I SECTION 7 - HANDLING AND STORAGE I HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. Avoid skin and eye contact. Avoid breathing vapors. Use only in a well ventilated area. STORAGE INFORMATION: Store away from caustics and oxidizers. Keep away from heat, spark, and flame. Keep containers closed when not in use. Keep containers from excessive heat and freezing. Do not store at temperatures above 120 degrees F. (Continued on Page 4) Page 161 of 878 Page 161 of 878 Page 161 of 878 Page 161 of 878 ---PAGE BREAK--- Product Name: 2000 CONSTRUCTION ADHESIVE Revision Date: 02/14/2000 Page 4 I SECTION 7 - HANDLING AND STORAGE I OTHER PRECAUTIONS: Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Do not take internally. Construction and repair activities can adversely affect indoor air quality. Consult with the occupants or a representative (i.e. maintenance, building manager, industrial hygienist, or safety officer) to determine ways to minimize any impact. I SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION I ENGINEERING CONTROLS: Provide sufficient mechanical ventilation (local or general exhaust) to maintain exposure below PEL and TLV. Vapors are heavier than air and will collect in low areas. Check all low areas (basements, sumps, etc.) for vapors before entering. RESPIRATORY PROTECTION: If 8 hour exposure limit or value is exceeded for any component, use an approved NIOSH/OSHA respirator. Consult your safety equipment supplier and the OSHA regulation, 29 CFR 1910.134 for respirator requirements. A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. EYE PROTECTION: Goggles or safety glasses with side shields. SKIN PROTECTION: Solvent impervious gloves. OTHER PROTECTIVE EQUIPMENT: Provide eyewash and solvent impervious apron if body contact may occur. HYGIENIC PRACTICES: Remove contaminated clothing and wash before reuse. I SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES I BOILING RANGE : 150 - 160 F VAPOR DENSITY : Is heavier than air ODOR : Gasoline-like APPEARANCE : Gray color paste EVAPORATION RATE: Is faster than Butyl SOLUBILITY IN H2O : Negligible Acetate SPECIFIC GRAVITY : 1.3058 VAPOR PRESSURE : 125 mm Hg @ 68F PHYSICAL STATE : Paste (See Section 16 for abbreviation legend) (Continued on Page 5) Page 162 of 878 Page 162 of 878 Page 162 of 878 Page 162 of 878 ---PAGE BREAK--- Product Name: 2000 CONSTRUCTION ADHESIVE Revision Date: 02/14/2000 Page 5 I SECTION 10 - STABILITY AND REACTIVITY I CONDITIONS TO AVOID: Excessive heat and freezing. INCOMPATIBILITY: Strong oxidizers and caustics. HAZARDOUS DECOMPOSITION PRODUCTS: Normal decomposition products, i.e. COx, NOx HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. I SECTION 11 - TOXICOLOGICAL PROPERTIES I No product or component toxicological information is available. I SECTION 12 - ECOLOGICAL INFORMATION I No Information. I SECTION 13 - DISPOSAL CONSIDERATIONS I WASTE MANAGEMENT/DISPOSAL: Dispose of according to Federal, State, and Local Standards. Discarded material should be incinerated at a permitted facility. Liquids cannot be disposed of in a landfill. Do not reuse empty container. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA WASTE CODE - If discarded (40 CFR 261): None, yields no liquid component when evaluated by EPA method 1311 (TCLP) I SECTION 14 - TRANSPORTATION INFORMATION I DOT PROPER SHIPPING NAME: Adhesive(Consumer Commodity*) DOT HAZARD CLASS: 3(ORM-D*) DOT UN/NA NUMBER: UN 1133(NONE*) PACKING GROUP: III(NONE*) * For containers of 1 gallon or less. Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may apply if shipped via other modes of transportation and/or to non-domestic destinations. (Continued on Page 6) Page 163 of 878 Page 163 of 878 Page 163 of 878 Page 163 of 878 ---PAGE BREAK--- Product Name: 2000 CONSTRUCTION ADHESIVE Revision Date: 02/14/2000 Page 6 I SECTION 15 - REGULATORY INFORMATION I U.S. FEDERAL REGULATIONS: AS FOLLOWS - OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER WT/WT % RANGE N-Hexane 110-54-3 5.0-10.0% TOXIC SUBSTANCES CONTROL ACT: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: CHEMICAL NAME CAS NUMBER No information is available. All ingredients are listed on the TSCA inventory NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components in this product: CHEMICAL NAME CAS NUMBER Hydrocarbon resin TSRN-1223370035031P Magnesium Carbonate 546-93-0 SB Rubber TSRN-618608-5085P Calcium Carbonate 1317-65-3 RIGHT-TO-KNOW: The following non-hazardous ingredients are present in the product at greater than CHEMICAL NAME CAS NUMBER Hydrocarbon resin proprietary Magnesium Carbonate 546-93-0 SB Rubber proprietary Calcium Carbonate 1317-65-3 CALIFORNIA PROPOSITION 65: WARNING: The chemical(s) noted below and contained in this product, are known to the state of California to cause cancer, birth defects or other reproductive harm: CHEMICAL NAME CAS NUMBER No Proposition 65 chemicals are present in this product. (Continued on Page 7) Page 164 of 878 Page 164 of 878 Page 164 of 878 Page 164 of 878 ---PAGE BREAK--- Product Name: 2000 CONSTRUCTION ADHESIVE Revision Date: 02/14/2000 Page 7 I SECTION 15 - REGULATORY INFORMATION I INTERNATIONAL REGULATIONS: AS FOLLOWS - CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: No information available. I SECTION 16 - OTHER INFORMATION I HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 3 REACTIVITY: 1 PREVIOUS MSDS REVISION DATE: 07/17/1999 REASON FOR REVISION: SECTION 1: New Emergency Contact Phone Numbers VOC less water, less exempt solvent: 330-340 gm/l(25-26%) VOC material: 330-340 gm/l LEGEND: ACGIH - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS N.A. - NOT APPLICABLE N.E. - NOT ESTABLISHED PEL - PERMISSIBLE EXPOSURE LIMIT NTP - NATIONAL TOXICOLOGY PROGRAM SARA - SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 STEL - SHORT TERM EXPOSURE LIMIT TLV - THRESHOLD LIMIT VALUE(8 HR. TIME WEIGHTED AVERAGE OR TWA) VOC - VOLATILE ORGANIC COMPOUND - NEW JERSEY RIGHT TO KNOW LAW N.D. - NOT DETERMINED MSDS# 10302 This data is offered in good faith as typical values and not as a product specification. No warranty either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review the recommendations in specific context of the intended use and determine if they are appropriate. < End OF MSDS > Page 165 of 878 Page 165 of 878 Page 165 of 878 Page 165 of 878 ---PAGE BREAK--- I M A T E R I A L S A F E T Y D A T A S H E E T I I SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION I THIS MATERIAL SAFETY DATA SHEET IS AVAILABLE IN SPANISH UPON REQUEST. LOS DATOS DE SEGURIDAD DEL PRODUCTO PEUDEN OBTERNERSE EN ESPANOL SI LO REQUIERE. PRODUCT NAME : BEATS THE NAIL UPC NUMBER : [PHONE REDACTED], [PHONE REDACTED], [PHONE REDACTED], [PHONE REDACTED] [PHONE REDACTED], [PHONE REDACTED] PRODUCT USE/CLASS : Construction Adhesive MANUFACTURER: 24 HOUR EMERGENCY: DAP INC. TRANSPORTATION: 1-[PHONE REDACTED] 2400 BOSTON ST. MEDICAL : 1-[PHONE REDACTED] BALTIMORE, MD 21224 PREPARE DATE : 02/03/1999 GENERAL INFORMATION: REVISION NO. : 6 DAP INC.: 1-[PHONE REDACTED] REVISION DATE: 02/03/1999 I SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS I WT/WT % ITEM CHEMICAL NAME CAS NUMBER RANGE 01 N-Hexane 110-54-3 5.0-10.0 % 02 Aliphatic Petroleum Distillate 64742-89-8 15.0-20.0 % 03 2-Methyl Pentane 107-83-5 5.0-10.0 % 04 3-Methyl Pentane 96-14-0 5.0-10.0 % EXPOSURE LIMITS ACGIH OSHA COMPANY ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN 01 50 ppm N.E. 50 ppm N.E. N.E. NO 02 400 ppm N.E. 400 ppm N.E. N.E. NO 03 N.E. N.E. N.E. N.E. N.E. NO 04 N.E. N.E. N.E. N.E. N.E. NO (See Section 16 for abbreviation legend) Remaining ingredients are not considered hazardous per the OSHA Hazard Communication Standard. Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); limits may vary between states. (Continued on Page 2) Page 166 of 878 Page 166 of 878 Page 166 of 878 Page 166 of 878 ---PAGE BREAK--- Product Name: BEATS THE NAIL Revision Date: 02/03/1999 Page 2 I SECTION 3 - HAZARDS IDENTIFICATION I EMERGENCY OVERVIEW: DANGER! Extremely flammable liquid and vapor. Vapor harmful. Harmful or fatal if swallowed. Vapors may cause flash fire or explosion. Harmful if inhaled. POTENTIAL HEALTH EFFECTS: EFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May irritate skin. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). EFFECTS OF OVEREXPOSURE - INHALATION: Vapor harmful if inhaled. Vapor may irritate nose and upper respiratory tract. Vapor inhalation may affect the brain or nervous system causing dizziness, headache or nausea. EFFECTS OF OVEREXPOSURE - INGESTION: This material may be harmful or fatal if swallowed. If ingested, this product may cause vomiting, diarrhea, and depressed respiration. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated permanent brain and nervous system damage with prolonged and repeated occupational overexposure to solvents. Hexane exposure may cause damage to the arms and legs which may be permanent. include: loss of memory, loss of intellectual ability, and loss of coordination. MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT: None known. PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT INHALATION I SECTION 4 - FIRST AID MEASURES I EYE CONTACT: Flush with large quantities of water until irritation subsides. Contact a physician. SKIN CONTACT: Wash with soap and water. INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Contact a physician immediately. Note: Only trained personnel should give artificial respiration or administer oxygen. (Continued on Page 3) Page 167 of 878 Page 167 of 878 Page 167 of 878 Page 167 of 878 ---PAGE BREAK--- Product Name: BEATS THE NAIL Revision Date: 02/03/1999 Page 3 I SECTION 4 - FIRST AID MEASURES I INGESTION: DO NOT INDUCE VOMITING. If irritation or complications arise, contact a physician or Regional Poison Control Center immediately. COMMENTS: None. I SECTION 5 - FIRE FIGHTING MEASURES I FLASH POINT: -30 F LOWER EXPLOSIVE LIMIT: N.A. (SETAFLASH CLOSED CUP) UPPER EXPLOSIVE LIMIT: N.A. AUTOIGNITION TEMPERATURE: N.E. EXTINGUISHING MEDIA: CO2 DRY CHEMICAL FOAM UNUSUAL FIRE AND EXPLOSION HAZARDS: Extremely flammable. Material will readily ignite at room temperature. Vapors may form an explosive mixture with air. Vapors can travel long distances to a source of ignition and flashback. Containers may explode if exposed to extreme heat. Eliminate sources of ignition: heat, electrical equipment, sparks, and flames. Do not put in contact with oxidizing or caustic materials. SPECIAL FIREFIGHTING PROCEDURES: Full protective equipment, including self-contained breathing apparatus, is recommended to protect from combustion products. Cool exposed containers with water. I SECTION 6 - ACCIDENTAL RELEASE MEASURES I SPILL OR LEAK PROCEDURES: Dike spill area. Immediately eliminate sources of ignition. Use absorbent material or scrape up dried material and place into containers. I SECTION 7 - HANDLING AND STORAGE I HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. Avoid skin and eye contact. Avoid breathing vapors. Use only in a well ventilated area. STORAGE INFORMATION: Store away from caustics and oxidizers. Keep away from heat, spark, and flame. Keep containers closed when not in use. Keep containers from excessive heat and freezing. Do not store at temperatures above 120 degrees F. (Continued on Page 4) Page 168 of 878 Page 168 of 878 Page 168 of 878 Page 168 of 878 ---PAGE BREAK--- Product Name: BEATS THE NAIL Revision Date: 02/03/1999 Page 4 I SECTION 7 - HANDLING AND STORAGE I OTHER PRECAUTIONS: Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Do not take internally. Construction and repair activities can adversely affect indoor air quality. Consult with the occupants or other appropriate representative (i.e. maintenance, building manager, industrial hygienist, or safety officer) to determine ways to minimize any impact. I SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION I ENGINEERING CONTROLS: Provide sufficient mechanical ventilation (local or general exhaust) to maintain exposure below PEL and TLV. Vapors are heavier than air and will collect in low areas. Check all low areas (basements, sumps, etc.) for vapors before entering. RESPIRATORY PROTECTION: If 8 hour exposure limit or value is exceeded for any component, use an approved NIOSH/OSHA respirator. Consult your safety equipment supplier and the OSHA regulation, 29 CFR 1910.134 for respirator requirements. A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. EYE PROTECTION: Goggles or safety glasses with side shields. SKIN PROTECTION: Solvent impervious gloves. OTHER PROTECTIVE EQUIPMENT: Provide eyewash and solvent impervious apron if body contact may occur. HYGIENIC PRACTICES: Remove contaminated clothing and wash before reuse. I SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES I BOILING RANGE : N.E. VAPOR DENSITY : Is heavier than air ODOR : Gasoline-like APPEARANCE : Gray color paste EVAPORATION RATE: Is faster than Butyl SOLUBILITY IN H2O : Negligible Acetate SPECIFIC GRAVITY : 1.3058 VAPOR PRESSURE : 125 mm Hg @ 68F PHYSICAL STATE : Paste (See Section 16 for abbreviation legend) (Continued on Page 5) Page 169 of 878 Page 169 of 878 Page 169 of 878 Page 169 of 878 ---PAGE BREAK--- Product Name: BEATS THE NAIL Revision Date: 02/03/1999 Page 5 I SECTION 10 - STABILITY AND REACTIVITY I CONDITIONS TO AVOID: Excessive heat and freezing. INCOMPATIBILITY: Strong oxidizers and caustics. HAZARDOUS DECOMPOSITION PRODUCTS: Normal decomposition products, i.e. COx, NOx HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. I SECTION 11 - TOXICOLOGICAL PROPERTIES I No product or component toxicological information is available. I SECTION 12 - ECOLOGICAL INFORMATION I No Information. I SECTION 13 - DISPOSAL CONSIDERATIONS I WASTE MANAGEMENT/DISPOSAL: Dispose of according to Federal, State, and Local Standards. Discarded material should be incinerated at a permitted facility. Liquids cannot be disposed of in a landfill. Do not reuse empty container. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA WASTE CODE - If discarded (40 CFR 261): None, yields no liquid component when evaluated by EPA method 1311 (TCLP) I SECTION 14 - TRANSPORTATION INFORMATION I DOT PROPER SHIPPING NAME: Adhesive(Consumer Commodity*) DOT HAZARD CLASS: 3(ORM-D*) DOT UN/NA NUMBER: UN 1133(NONE*) PACKING GROUP: III(NONE*) * For containers of 1 gallon or less. Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may apply is shipped via other modes of transportation and/or to non-domestic destinations. (Continued on Page 6) Page 170 of 878 Page 170 of 878 Page 170 of 878 Page 170 of 878 ---PAGE BREAK--- Product Name: BEATS THE NAIL Revision Date: 02/03/1999 Page 6 I SECTION 15 - REGULATORY INFORMATION I U.S. FEDERAL REGULATIONS: AS FOLLOWS - OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER WT/WT % RANGE N-Hexane 110-54-3 5.0-10.0% TOXIC SUBSTANCES CONTROL ACT: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: CHEMICAL NAME CAS NUMBER No information is available. All ingredients are listed on the TSCA inventory NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components in this product: CHEMICAL NAME CAS NUMBER Hydrocarbon resin TSRN-1223370035031P Magnesium Carbonate 546-93-0 SB Rubber TSRN-618608-5085P Calcium Carbonate 1317-65-3 RIGHT-TO-KNOW: The following non-hazardous ingredients are present in the product at greater than CHEMICAL NAME CAS NUMBER Hydrocarbon resin proprietary Magnesium Carbonate 546-93-0 SB Rubber proprietary Calcium Carbonate 1317-65-3 CALIFORNIA PROPOSITION 65: WARNING: The chemical(s) noted below and contained in this product, are known to the state of California to cause cancer, birth defects or other reproductive harm: CHEMICAL NAME CAS NUMBER No Proposition 65 chemicals are present in this product. (Continued on Page 7) Page 171 of 878 Page 171 of 878 Page 171 of 878 Page 171 of 878 ---PAGE BREAK--- Product Name: BEATS THE NAIL Revision Date: 02/03/1999 Page 7 I SECTION 15 - REGULATORY INFORMATION I INTERNATIONAL REGULATIONS: AS FOLLOWS - CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: No information available. I SECTION 16 - OTHER INFORMATION I HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 3 REACTIVITY: 1 PREVIOUS MSDS REVISION DATE: 02/01/1997 REASON FOR REVISION: FORMULA CHANGE MSDS 77084 VOC less water, less exempt solvent: 330-340 gm/l(25-26%) VOC material: 330-340 gm/l LEGEND: ACGIH - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS N.A. - NOT APPLICABLE N.E. - NOT ESTABLISHED PEL - PERMISSIBLE EXPOSURE LIMIT NTP - NATIONAL TOXICOLOGY PROGRAM SARA - SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 STEL - SHORT TERM EXPOSURE LIMIT TLV - THRESHOLD LIMIT VALUE(8 HR. TIME WEIGHTED AVERAGE OR TWA) VOC - VOLATILE ORGANIC COMPOUND - NEW JERSEY RIGHT TO KNOW LAW N.D. - NOT DETERMINED Supersedes MSDS 77084 This data is offered in good faith as typical values and not as a product specification. No warranty either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review the recommendations in specific context of the intended use and determine if they are appropriate. < End OF MSDS > Page 172 of 878 Page 172 of 878 Page 172 of 878 Page 172 of 878 ---PAGE BREAK--- I M A T E R I A L S A F E T Y D A T A S H E E T I I SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION I THIS MSDS IS OFFERED IN CANADIAN-FRENCH UPON REQUEST. ON PEUT DEMANDER CETTE MSDS A LA LANGUE FRANCAISE-CANADIENNE. PRODUCT NAME : DAP MULTIPURPOSE CERAMIC TILE ADHESIVE UPC NUMBER: : [PHONE REDACTED], [PHONE REDACTED] PRODUCT USE/CLASS : Adhesive MANUFACTURER: 24 HOUR EMERGENCY: DAP CANADA CORP. TRANSPORTATION: 1-[PHONE REDACTED] 475 FINCHDENE SQUARE UNITE 5 MEDICAL: 1-[PHONE REDACTED] SCARBOROUGH, ONTARIO M1X 1B7 PREPARE DATE: 02/02/1999 GENERAL INFORMATION: REVISION NO. : 6 DAP INC.: 1-[PHONE REDACTED] REVISION DATE: 02/10/2002 I SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS I WT/WT % ITEM CHEMICAL NAME CAS NUMBER RANGE 01 Mineral spirits 8052-41-3 1.0-5.0 % 02 Ethylene glycol 107-21-1 1.0-5.0 % EXPOSURE LIMITS ACGIH OSHA COMPANY ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN 01 100 ppm N.E. 100 ppm N.E. N.E. NO 02 N.E. 50 ppm* N.E. 50 ppm N.E. NO (See Section 16 for abbreviation legend), * - TLV-Ceiling Value Remaining ingredients are not considered hazardous per the OSHA Hazard Communication Standard. Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); limits may vary between states. I SECTION 3 - HAZARDS IDENTIFICATION I EMERGENCY OVERVIEW: CAUTION! Harmful or fatal if swallowed. May cause eye or skin irritation. POTENTIAL HEALTH EFFECTS: (Continued on Page 2) Page 173 of 878 Page 173 of 878 Page 173 of 878 Page 173 of 878 ---PAGE BREAK--- Product Name: DAP MULTIPURPOSE CERAMIC TILE ADHESIVE Revision Date: 02/10/2002 Page 2 I SECTION 3 - HAZARDS IDENTIFICATION I EFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Prolonged or repeated contact with skin may cause irritation. EFFECTS OF OVEREXPOSURE - INHALATION: Vapor may irritate nose and upper respiratory tract. Vapor inhalation may affect the brain or nervous system causing dizziness, headache or nausea. May irritate eyes, skin, nose and respiratory tract. EFFECTS OF OVEREXPOSURE - INGESTION: Ingestion of ethylene glycol in excess may lead to respiratory cardiac failure as well as kidney and liver damage. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Ingestion of Ethylene Glycol in excess may lead to respiratory and cardiac failure, and kidney and liver damage. Prolonged or repeated contact with skin may cause irritation. MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT: None known. PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT INGESTION I SECTION 4 - FIRST AID MEASURES I EYE CONTACT: Flush with large quantities of water until irritation subside SKIN CONTACT: Wash with soap and water. INHALATION: Remove to fresh air. INGESTION: DO NOT INDUCE VOMITING. Contact a physician or Regional Poison Control Center immediately. COMMENTS: Call 1-[PHONE REDACTED] if irritation or complications arise from any of the above exposures. I SECTION 5 - FIRE FIGHTING MEASURES I FLASH POINT:>200 F LOWER EXPLOSIVE LIMIT: N.A. (SETAFLASH CLOSED CUP) UPPER EXPLOSIVE LIMIT: N.A. EXTINGUISHING MEDIA: CO2 DRY CHEMICAL FOAM WATER FOG UNUSUAL FIRE AND EXPLOSION HAZARDS: None known. (Continued on Page 3) Page 174 of 878 Page 174 of 878 Page 174 of 878 Page 174 of 878 ---PAGE BREAK--- Product Name: DAP MULTIPURPOSE CERAMIC TILE ADHESIVE Revision Date: 02/10/2002 Page 3 I SECTION 5 - FIRE FIGHTING MEASURES I SPECIAL FIREFIGHTING PROCEDURES: As in any fire, wear self-contained breathing apparatus pressure-demand (MSHA/NIOSH approved or equivalent) and full protective gear. Use water spray to cool exposed surfaces. I SECTION 6 - ACCIDENTAL RELEASE MEASURES I SPILL OR LEAK PROCEDURES: Use absorbent material or scrape up dried material and place into containers. I SECTION 7 - HANDLING AND STORAGE I HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. Avoid prolonged or repeated contact with skin. Avoid contact with eyes. STORAGE INFORMATION: Store away from caustics and oxidizers. Keep containers closed when not in use. Keep containers from excessive heat and freezing. Do not store at temperatures above 120 degrees F. OTHER PRECAUTIONS: Use in a well ventilated area. Provide fresh air such that chemical odors cannot be detected during use and while drying. Construction and repair activities can adversely affect indoor air quality. Consult with the occupants or a representative(i.e. maintenance, building manager, industrial hygienist, or safety officer) to determine ways to minimize any impact. I SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION I ENGINEERING CONTROLS: Good mechanical ventilation and local exhaust. RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Not required under normal usage and adequate ventilation. EYE PROTECTION: Safety glasses with side shields recommended. SKIN PROTECTION: Gloves recommended for repeated or prolonged contact with skin. OTHER PROTECTIVE EQUIPMENT: None. (Continued on Page 4) Page 175 of 878 Page 175 of 878 Page 175 of 878 Page 175 of 878 ---PAGE BREAK--- Product Name: DAP MULTIPURPOSE CERAMIC TILE ADHESIVE Revision Date: 02/10/2002 Page 4 I SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION I HYGIENIC PRACTICES: Although this product is not considered an eye irritant, inhalation hazard, or a skin contact hazard under normal conditions, it is advisable that personnel minimize skin contact, inhalation of vapors, and eye contact. Remove contaminated clothing and wash before reuse. I SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES I BOILING RANGE : 210 - 220 F VAPOR DENSITY : Is heavier than air ODOR : Sweet Odor APPEARANCE : Off white color EVAPORATION RATE: Is slower than Butyl SOLUBILITY IN H2O : N.E. Acetate SPECIFIC GRAVITY : 1.5950 VAPOR PRESSURE : 17.5 mm Hg@68F. PHYSICAL STATE : Paste VISCOSITY : 278,800-304,400 (See Section 16 for abbreviation legend) I SECTION 10 - STABILITY AND REACTIVITY I CONDITIONS TO AVOID: Excessive heat and freezing. INCOMPATIBILITY: Strong oxidizers and caustics. HAZARDOUS DECOMPOSITION PRODUCTS: Normal decomposition products, i.e. COx, NOx HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. I SECTION 11 - TOXICOLOGICAL PROPERTIES I No product or component toxicological information is available. The toxicological properties of this material are unknown, however, based on the toxicity of its constituents, it is expected to have relatively low toxicity. I SECTION 12 - ECOLOGICAL INFORMATION I No Information. (Continued on Page 5) Page 176 of 878 Page 176 of 878 Page 176 of 878 Page 176 of 878 ---PAGE BREAK--- Product Name: DAP MULTIPURPOSE CERAMIC TILE ADHESIVE Revision Date: 02/10/2002 Page 5 I SECTION 13 - DISPOSAL CONSIDERATIONS I WASTE MANAGEMENT/DISPOSAL: Dispose of according to Federal, State, and Local Standards. This product does not meet the definition of a hazardous waste according to U.S. EPA Hazardous Waste Management Regulations, 40 CFR Section 261. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA WASTE CODE - If discarded (40 CFR 261): None I SECTION 14 - TRANSPORTATION INFORMATION I DOT PROPER SHIPPING NAME: Not Regulated by D.O.T. DOT HAZARD CLASS: NONE DOT UN/NA NUMBER: NONE PACKING GROUP: NONE Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may apply is shipped via other mo of transportation and/or to non-domestic destinations. I SECTION 15 - REGULATORY INFORMATION I U.S. FEDERAL REGULATIONS: AS FOLLOWS - OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER WT/WT % RANGE Ethylene glycol 107-21-1 1.0-5.0 % TOXIC SUBSTANCES CONTROL ACT: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: CHEMICAL NAME CAS NUMBER No information available. All ingredients are listed on the TSCA inventory NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components in this product: CHEMICAL NAME CAS NUMBER Water 7732-18-5 Proprietary acid polymer TSRN618608-5144P (Continued on Page 6) Page 177 of 878 Page 177 of 878 Page 177 of 878 Page 177 of 878 ---PAGE BREAK--- Product Name: DAP MULTIPURPOSE CERAMIC TILE ADHESIVE Revision Date: 02/10/2002 Page 6 I SECTION 15 - REGULATORY INFORMATION I RIGHT-TO-KNOW: The following non-hazardous ingredients are present in the product at greater than CHEMICAL NAME CAS NUMBER Water 7732-18-5 Proprietary acid polymer Proprietary CALIFORNIA PROPOSITION 65: WARNING: The chemical(s) noted below and contained in this product, are known to the state of California to cause cancer, birth defects or other reproductive harm: CHEMICAL NAME CAS NUMBER No proposition 65 chemicals are known to exist in this product. INTERNATIONAL REGULATIONS: AS FOLLOWS - CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: No information available. (Continued on Page 7) Page 178 of 878 Page 178 of 878 Page 178 of 878 Page 178 of 878 ---PAGE BREAK--- Product Name: DAP MULTIPURPOSE CERAMIC TILE ADHESIVE Revision Date: 02/10/2002 Page 7 I SECTION 16 - OTHER INFORMATION I HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0 PREVIOUS MSDS REVISION DATE: 02/15/1999 REASON FOR REVISION: FORMULA CHANGE MSDS 17042 VOC Material 80-90 g/l VOC less water less exempt 80-90 g/l LEGEND: ACGIH - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS N.A. - NOT APPLICABLE N.E. - NOT ESTABLISHED PEL - PERMISSIBLE EXPOSURE LIMIT NTP - NATIONAL TOXICOLOGY PROGRAM SARA - SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 STEL - SHORT TERM EXPOSURE LIMIT TLV - THRESHOLD LIMIT VALUE(8 HR. TIME WEIGHTED AVERAGE OR TWA) VOC - VOLATILE ORGANIC COMPOUND - NEW JERSEY RIGHT TO KNOW LAW N.D. - NOT DETERMINED This data is offered in good faith as typical values and not as a product specification. No warranty either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review the recommendations in specific context of the intended use and determine if they are appropriate. < End OF MSDS > Page 179 of 878 Page 179 of 878 Page 179 of 878 Page 179 of 878 ---PAGE BREAK--- Sea Foam Sales Company P.O. Box 5178 Hopkins, MN 55343-1178 Phone (952)938-4811 MATERIAL SAFETY DATA INFORMATION FOR SEA FOAM DEEP CREEP Part No. DC-14 SECTION I - IDENTIFICATION Deep Creep Sea Foam Formula: Proprietary Blend Date Prepared 5-1-2005 EMERGENCY PHONE : (708)598-7100 Mfg. Code ID: L-12749 SECTION II - HAZARDOUS INGREDIENTS/SARA III INFORMATION VAPOR PRESSURE WEIGHT REPORTABLE COMPONENTS mm Hg @ TEMP PERCENT PALE OIL .01 68 40-60% NAPHTHA 10 68 25-35% IPA 33 68 10-20% CARBON DIOXIDE 38650 60 3-5% No toxic chemical(s) subject to the reporting requirements of section 313 of Title III and of 40 CFR 372 are present. SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS BOILING RANGE: 177 deg F - 500 deg F SPECIFIC GRAVITY (H2O=1): 0.85 VAPOR DENSITY: HEAVIER THAN AIR EVAPORATION RATE: SLOWER THAN ETHER SOLUBILITY IN WATER: NIL APPEARANCE AND ODOR: AEROSOL PRODUCT SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT: 55 deg F METHOD USED: TCC FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER: 1 UPPER: 12 EXTINGUISHING MEDIA: FOAM, CO2, DRY CHEMICAL, WATER FOG SPECIAL FIREFIGHTING PROCEDURES WATER SPRAY MAY BE INEFFECTIVE. WATER MAY BE USED TO COOL CONTAINERS TO PREVENT PRESSURE BUILD-UP AND EXPLOSION WHEN EXPOSED TO EXTREME HEAT. IF WATER IS USED, FOG NOZZLES PREFERRED. WEAR GOGGLES AND SELF-CONTAINED BREATHING APPARATUS. UNUSUAL FIRE AND EXPLOSION HAZARDS CLOSED CONTAINERS MAY EXPLODE FROM INTERNAL PRESSURE BUILD-UP WHEN EXPOSED TO EXTREME HEAT AND DISCHARGE CONTENTS. VAPOR ACCUMULATION CAN FLASH OR EXPLODE IF IGNITED. OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. MAY NOT BE READILY APPARENT. OBTAIN MEDICAL ATTENTION. SECTION V - REACTIVITY DATA STABILITY: STABLE CONDITIONS TO AVOID APPLICATION TO HOT SURFACES. STORAGE ABOVE 120 DEG F. EXPOSURE TO OPEN FLAME. INCOMPATIBILITY (MATERIALS TO AVOID) STRONG OXIDIZING AGENTS. HAZARDOUS DECOMPOSITION OR BYPRODUCTS MAY PRODUCE FUMES WHEN HEATED TO DECOMPOSITION. FUMES MAY CONTAIN CARBON MONOXIDE. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR Page 180 of 878 Page 180 of 878 Page 180 of 878 Page 180 of 878 ---PAGE BREAK--- SECTION VI - HEALTH HAZARD DATA INHALATION HEALTH RISKS AND OF EXPOSURE RESPIRATORY IRRITATION, HEADACHE, NAUSEA, FATIGUE, DROWSINESS, IMPAIRED CO-ORDINATION. SKIN AND EYE CONTACT HEALTH RISKS AND OF EXPOSURE SKIN: CONTACT MAY DRY THE SKIN; PROLONGED CONTACT MAY CAUSE MODERATE IRRITATION. EYES: LIQUID OR VAPOR CAN CAUSE MODERATE TO SEVERE IRRITATION. SKIN ABSORPTION HEALTH RISKS AND OF EXPOSURE NOT EASILY ABSORBED. SOLVENT ACTION CAN DRY AND DEFAT THE SKIN CAUSING THE SKIN TO CRACK, LEADING TO DERMATITIS. INGESTION HEALTH RISKS AND OF EXPOSURE NOT A LIKELY ROUTE OF EXPOSURE. IF SWALLOWED, DO NOT INDUCE VOMITING. SEEK IMMEDIATE MEDICAL ADVICE AND/OR ATTENTION. HEALTH HAZARDS (ACUTE AND CHRONIC) ACUTE: EYE IRRITANT. POSSIBLE SKIN IRRITANT. CHRONIC: NONE KNOWN. CARCINOGENICITY: NTP CARCINOGEN: No IARC MONOGRAPHS: No OSHA REGULATED: No MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE KNOWN. EMERGENCY AND FIRST AID PROCEDURES INHALATION: REMOVE TO FRESH AIR. ADMINISTER OXYGEN IF NEEDED. APPLY ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. GET MEDICAL ATTENTION. SKIN: WIPE OFF WITH TOWEL. WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. EYES: WASH IMMEDIATELY WITH LARGE VOLUMES OF FRESH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED AVOID BREATHING VAPORS. VENTILATE AREA. REMOVE ALL SOURCES OF IGNITION. CLEAN UP AREA WITH ABSORBENT MATERIAL AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL. WASTE DISPOSAL METHOD DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. BEFORE ATTEMPTING CLEAN UP, REFER TO OTHER SECTIONS OF THIS MSDS FOR HAZARD CAUTION INFORMATION. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING STORE AND USE IN COOL, DRY, WELL-VENTILATED AREAS. DO NOT STORE ABOVE 120 DEG F. DO NOT PUNCTURE OR INCINERATE (BURN) CANS. DO NOT STICK PIN, NAIL OR ANY OTHER SHARP OBJECT INTO OPENING ON TOP OF CAN. DO NOT SPRAY IN EYES. DO NOT TAKE INTERNALLY. SEE PRODUCT LABEL FOR ADDITIONAL INFORMATION. OTHER PRECAUTIONS SMALL PRESSURIZED CONTAINERS OF FLAMMABLE PRODUCTS MAY BE STORED IN AREAS SUITABLE FOR ORDINARY COMBUSTIBLES WITH RESPECT TO CONSTRUCTION, DRAINAGE, CONTROL OF IGNITION SOURCES, AND VENTILATION EXCEPT THAT THEY SHOULD NOT BE STORED IN BASEMENTS. SECTION VIII - CONTROL MEASURES RESPIRATORY PROTECTION NONE UNDER NORMAL USE. AVOID BREATHING VAPORS. IN RESTRICTED AREAS, USE APPROVED CHEMICAL/MECHANICAL FILTERS DESIGNED TO REMOVE A COMBINATION OF PARTICLES AND VAPOR. IN CONFINED AREAS, USE APPROVED AIR LINE TYPE RESPIRATOR OR HOOD. SELF-CONTAINED BREATHING APPARATUS IS REQUIRED FOR VAPOR CONCENTRATIONS ABOVE PEL/TLV LIMITS. VENTILATION SUFFICIENT TO PREVENT INHALATION OF SOLVENT VAPORS. GENERAL DILUTION AND/OR LOCAL EXHAUST VENTILATION IN VOLUME OR PATTERN TO KEEP PEL/TLV OF MOST HAZARDOUS INGREDIENT BELOW ACCEPTABLE LIMIT AND LEL BELOW STATED LIMIT. PROTECTIVE GLOVES NONE UNDER NORMAL USE. SOLVENT RESISTANT REQUIRED FOR PROLONGED OR REPEATED CONTACT. EYE PROTECTION NONE UNDER NORMAL USE; HOWEVER, USE OF SAFETY GLASSES WITH SPLASH GUARDS OR FULL FACE SHIELD IS RECOMMENDED. OTHER PROTECTIVE CLOTHING OR EQUIPMENT NONE UNDER NORMAL USE; HOWEVER, USE OF SOLVENT RESISTANT APRONS OR OTHER CLOTHING IS RECOMMENDED. WORK/HYGIENIC PRACTICES EYE WASHES AND SAFETY SHOWERS IN THE WORKPLACE ARE RECOMMENDED. SECTION IX - DISCLAIMER THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. BECAUSE THE INFORMATION CONTAINED HEREIN MAY BE APPLIED UNDER CONDITIONS BEYOND OUR CONTROL, WE ASSUME NO RESPONSIBILITY FOR ITS USE. Page 181 of 878 Page 181 of 878 Page 181 of 878 Page 181 of 878 ---PAGE BREAK--- Spartan Chemical Company, Inc. Material Safety Data Sheet SECTION I: PRODUCT INFORMATION Product Name or Number (as it appears on label): Product Division: DEFOAMER Product Number: 3024; 3042 Janitorial Spartan Chemical Company, Inc. Product/Technical Information:1-(800)-537-8990 1110 Spartan Drive Medical Emergency:1-(888)-314-6171 (24 hours) Maumee OH 43537 Chemical Leak/Spil Emergency:CHEMTREC 1-(800) 424-9300 (24 hours) Shipping Description: Cleaning compounds, liquid, n.o.s. NFPA Ratings: HMIS Ratings: Health: 1- Slight Health: 1- Slight Fire: 0 - Minimal Fire: 0 - Minimal Reactivity: 0 - Minimal Reactivity: 0 - Minimal Pers. Prot. Equip.: See Section VIII SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1% or greater, carcinogens at 0.1% or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. Chemical Name(s) % W CAS Registry No. Table Z- 1 - A NTP, IARC or OSHA Carcinogen TWA mg/m3 STEL mg/m 3 CELING mg/m3 emulsion 1-5 Proprietary Not Established Not Established Not Established No SECTION III: PHYSICAL DATA Boiling Point: 212 °F Vapor Pressure: Not determined Vapor Density (AIR = Unknown Solubility in Water: Emulsifiable pH: 9.0-10.0 Specific Gravity (H2O=1): 1.00 Evaporation Rate (but.ace.=1): <1 Percent Solid by Weight: 1-5 Physical State: Liquid Appearance & Odor: Milky white liquid, bland odor Page 182 of 878 Page 182 of 878 Page 182 of 878 Page 182 of 878 ---PAGE BREAK--- SECTION IV: FIRE & EXPLOSIVE HAZARD DATA Flash Point: > 212°F Method Used: ASTM-D56 Flammable Limits: Not Established Flame Extension: N/A Extinguishing Media: Product does not support combustion. Use extinguishing media appropriate for surrounding fire. Special Fire Fighting Procedures: Wear NIOSH approved self-contained breathing apparatus and protective clothing. Cool fire-exposed containers with water spray. Unusual Fire & Explosive Hazards: Combustion products are toxic. SECTION V: HEALTH HAZARD DATA Threshold Limit Value: Not Established Primary Routes of Entry: Inhalation, Skin Contact, Eyes and Oral Effects of Overexposure- Conditions to Avoid: May cause mild eye and skin irritation. May be harmful if swallowed. Inhalation of product mist may cause respiratory irritation. Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Do not swallow. Avoid breathing product mist. Wash thoroughly after handling. Conditions Aggravated by Use: Use of this product may aggravate preexisting skin; eye and respiratory disorders including asthma and dermatitis. Emergency & First Aid Procedures: Eyes: Flush eyes with plenty of water for at least 15 minutes. Remove contact lenses. Get medical attention. Skin: Wash skin thoroughly with soap and water. Get medical attention if irritation persists. Wash contaminated clothing before reuse. Ingestion: Do not induce vomiting. Drink one or two glasses of water to dilute product. Get medical attention. Do not give anything by mouth to an unconscious person. Inhalation: In case of respiratory irritation; move person to fresh air. Get medical attention if irritation persists. SECTION VI: REACTIVITY DATA Stability: Stable Incompatible Materials: Strong oxidizers Hazardous Decomposition Products: CO, CO2 Hazardous Polymerization: Will Not Occur SECTION VII: SPILL OR LEAK PROCEDURES Steps to be Taken in Case Material is Released or Spilled: Small spills of one gallon or less may be flushed with plenty of water to sanitary sewer system (If permitted by local sewer regulations). Dike and contain large spills with inert material and transfer liquid to containers for disposal. Keep spill out of storm sewers and waterways. Waste Disposal Method: Dispose of in compliance with all federal, state and local laws and regulations. SECTION VIII: SPECIAL PROTECTION INFORMATION Page 183 of 878 Page 183 of 878 Page 183 of 878 Page 183 of 878 ---PAGE BREAK--- Respiratory Protection: None required Ventilation: Provide good general ventilation. Local exhaust ventilation may be necessary for some operations. Protective Gloves(Specify Type): Not required. Impervious gloves may be worn if desired. Eye Protection(Specify Type): Not required. Splash goggles may be worn if desired. Other Protective Equipment: See 29 CFR 1910.132-138 for further guidance. Page 184 of 878 Page 184 of 878 Page 184 of 878 Page 184 of 878 ---PAGE BREAK--- SECTION IX: SPECIAL PRECAUTIONS Precautions; Handling & Storing: Keep from freezing. Other Precautions: Keep out of reach of children. © SCC 09/22/2008 Name: Ronald T. Cook Title: Manager, Regulatory Affairs DEFOAMER Effective Date: 09/22/2008 Supercedes: 07/07/2005 Ref: 29 CFR 1910.1200 (OSHA) Changes: Review This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. Page 185 of 878 Page 185 of 878 Page 185 of 878 Page 185 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Date Issued: Revised 8/22/2011 Trade Name: Distilled White Vinegar Chemical Name: Dilute Acetic Acid (CH 3COOH) C.A.S. - 8028-52-2 Definition Product made by the acetous fermentation of Ethyl Alcohol to contain 4–10% acetic acid (or 40–100 grain vinegar) Manufacturer’s Name H. J. Heinz Co. And Address: Heinz 57 Center 357 6th Avenue Pittsburgh, Pa 15222-2530 Contact: Customer & Consumer Resource Center Phone Number: 1-[PHONE REDACTED] HEALTH HAZARD DATA INHALATION Threshold Limit Value: 10 ppm Short Term Exposure: 15 ppm for 15 minutes Odor Threshold: 1.0 ppm Prolonged inhalation of vapors can cause irritation to respiration tract. EYES Will cause eye irritation – smarting and reddening of the eye. Page 186 of 878 Page 186 of 878 Page 186 of 878 Page 186 of 878 ---PAGE BREAK--- MSDS: Distilled White Vinegar Page 2. EMERGENCY AND FIRST – AID PROCEDURES In case of eye contact, flush immediately and thoroughly with water for 15–20 minutes (timed by a clock). Call a physician. If swallowed in large amounts, water should be consumed to dilute. Do not induce vomiting. Do not give emetics of baking soda. Call a physician. Stability – GOOD HAZARDOUS POLYMERIZATION WILL NOT OCCUR. SPILL OR LEAK PROCEDURES If vinegar is spilled, water may be used to dilute. PHYSICAL DATA Appearance and Odor Clear liquid, odor of vinegar. Boiling Point: 244 oF Vapor Pressure (MM Hg): 11 MM Vapor Density (Air = 2.1 Solubility in Water: Complete Specific Gravity: 1.01 pH: 2.2 @ 100 Grain Questions? Contact: Ms. Karen White, Senior Manager Government & Regulatory Affairs and Customer & Consumer Resource Center Heinz North America P.O. Box 57 Pittsburgh, PA. 15230 Page 187 of 878 Page 187 of 878 Page 187 of 878 Page 187 of 878 ---PAGE BREAK--- page 1 of 4 HMIS Codes Health 1* Flammability 0 Reactivity 0 DATE OF PREPARATION Nov 2, 2009 MATERIAL SAFETY DATA SHEET DB120-03 19 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DB120-03 PRODUCT NAME DURA CLEAN™ Satin Interior Latex Wall & Trim Paint, Base A MANUFACTURER'S NAME DUTCH BOY 101 Prospect Avenue N.W. Cleveland, OH 44115 Telephone Numbers and Websites Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident) * SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 0.1 14464-46-1 Cristobalite ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.05 mg/m3 as Resp. Dust 17 471-34-1 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 15 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 18 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. Page 188 of 878 Page 188 of 878 Page 188 of 878 Page 188 of 878 ---PAGE BREAK--- DB120-03 page 2 of 4 UEL N.A. LEL N.A. FLASH POINT Not Applicable SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 11.33 lb/gal 1357 g/l SPECIFIC GRAVITY 1.36 BOILING POINT 212 - 213 °F 100 - 100 °C MELTING POINT Not Available VOLATILE VOLUME 63% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 9.0 Page 189 of 878 Page 189 of 878 Page 189 of 878 Page 189 of 878 ---PAGE BREAK--- DB120-03 page 3 of 4 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.35lb/gal 43g/l Less Water and Federally Exempt Solvents 0.13lb/gal 16g/l Emitted VOC SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." TOXICOLOGY DATA CAS No. Ingredient Name 14464-46-1 Cristobalite LC50 RAT 4HR Not Available LD50 RAT Not Available 471-34-1 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Page 190 of 878 Page 190 of 878 Page 190 of 878 Page 190 of 878 ---PAGE BREAK--- DB120-03 page 4 of 4 SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 191 of 878 Page 191 of 878 Page 191 of 878 Page 191 of 878 ---PAGE BREAK--- Page 192 of 878 Page 192 of 878 Page 192 of 878 Page 192 of 878 ---PAGE BREAK--- Page 193 of 878 Page 193 of 878 Page 193 of 878 Page 193 of 878 ---PAGE BREAK--- Page 194 of 878 Page 194 of 878 Page 194 of 878 Page 194 of 878 ---PAGE BREAK--- Page 195 of 878 Page 195 of 878 Page 195 of 878 Page 195 of 878 ---PAGE BREAK--- Page 196 of 878 Page 196 of 878 Page 196 of 878 Page 196 of 878 ---PAGE BREAK--- Page 197 of 878 Page 197 of 878 Page 197 of 878 Page 197 of 878 ---PAGE BREAK--- Page 198 of 878 Page 198 of 878 Page 198 of 878 Page 198 of 878 ---PAGE BREAK--- 1 of 7 Material Safety Data Sheet F 1. Chemical Product and Company Identification DESCRIPTION: ELMER'S GLUE-ALL PRODUCT TYPE: PVAC BASED ADHESIVE APPLICATION: FOR PRODUCT CODES SEE SECTION 16 · Manufacturer/Supplier Information MSDS Prepared by: Elmer's Products, Inc. Emergency Phone Number 1 Easton Oval Poison Control Center Columbus, OH 43219 [PHONE REDACTED] For additional health, safety or regulatory information, call [PHONE REDACTED]. Call 1-[PHONE REDACTED] to place an order or request additional 2. Composition, Information on Ingredients No hazardous ingredients known to company. 3. Hazards Identification 3.1 Emergency Overview Appearance Milky white liquid Odor Mild acetic aroma CAUTION! Not a significant fire hazard. May cause eye irritation · HMIS Rating HEALTH = 1 (slight) FLAMMABILITY = 0 (minimal) REACTIVITY = 0 (minimal) 3.2 Potential Health Effects Page 199 of 878 Page 199 of 878 Page 199 of 878 Page 199 of 878 ---PAGE BREAK--- 2 of 7 · Immediate Hazards INGESTION: Not expected to be harmful under normal conditions of use. INHALATION: Not expected to be harmful under normal conditions of use. However, if allowed to become airborne, may cause irritation of nose, throat and lungs. SKIN: May cause irritation on prolonged or repeated contact. EYES: May cause irritation on prolonged or repeated contact. · Delayed Hazards None of the components present in this product at concentrations equal to or greater than 0.1% have been listed by NTP, classified by IARC, nor regulated by OSHA as a carcinogen. 4. First Aid Measures INGESTION: If accidentally swallowed, dilute by drinking large quantities of water. Immediately contact poison control center or hospital emergency room for any other additional treatment directions. INHALATION: Remove to fresh air. SKIN: In case of irritation, flush with water. EYES: Immediately flush eyes with plenty of water. Call a physician if irritation persists. 5. Fire Fighting Measures Autoignition Temperature Not available Upper/Lower Flammable Limits Not applicable Up/Lower Explosive Limits, % by Vol Not applicable Flash Point Not applicable Will not burn unless water has evaporated. Dried material may burn. In case of fire, water should be used to keep fire-exposed containers cool. 6. Accidental Release Measures Soak up with absorbent material and remove to a chemical disposal area. Prevent entry into natural bodies of water. 7. Handling and Storage 7.1 Handling Handle in accordance with good industrial hygiene and safety practices. Always use appropriate Personal Protective Equipment (PPE). INHALATION: Avoid prolonged or repeated breathing of vapor. Page 200 of 878 Page 200 of 878 Page 200 of 878 Page 200 of 878 ---PAGE BREAK--- 3 of 7 SKIN: Avoid prolonged or repeated contact with skin and clothing. EYES: Avoid prolonged or repeated contact with eyes. 7.2 Storage Keep from freezing. Store in a cool, dry place. Keep containers closed. 8. Exposure Controls/Personal Protection 8.1 Exposure Controls If airborne contaminants are generated when the material is heated or handled, sufficient ventilation in volume and air flow patterns should be provided to keep air contaminant concentration levels below acceptable criteria. 8.2 Personal Protection Where air contaminants can exceed acceptable criteria, use NIOSH/MSHA approved respiratory protection equipment. Respirators should be selected based on the form and concentration of contaminants in air in accordance with OSHA laws and regulations or other applicable standards or guidelines, including ANSI standards regarding respiratory protection. Use goggles if contact is likely. Wear impervious gloves as required to prevent skin contact. 8.3 Exposure Guidelines None established 9. Physical and Chemical Properties Percent Volatiles 63 pH @ 25 C 5 Specific Gravity 1.07 Appearance Milky white liquid Autoignition Temperature Not available Boiling Point 100 deg C Vapor Density (Air=1) < 1 Vapor Pressure, mm Hg @ 20 C 17.5 Evaporation Rate (Butyl Acetate=1) < 1 Upper/Lower Flammable Limits Not applicable Up/Lower Explosive Limits, % by Vol Not applicable Flash Point Not applicable Freezing Point 0 deg C Odor Mild acetic aroma Odor Threshold, ppm Not available Solubility in Water Dispersible Coefficient of Water/Oil Distrib. Not available Page 201 of 878 Page 201 of 878 Page 201 of 878 Page 201 of 878 ---PAGE BREAK--- 4 of 7 10. Stability and Reactivity Normally stable as defined in NFPA 704-12(4-3.1). · Conditions to Avoid: Exposure to heat, flame and incompatibles. · Incompatibilities: Strong acids and alkaline materials. · Decomposition products may include: CO, CO2. · Hazardous polymerization: Will not occur. · Other Hazards: None known to company. 11. Toxicological Information See Section 3 Hazards Identification information. 12. Ecological Information Not determined. 13. Disposal Considerations Recover free liquid. Absorb residue and dispose of according to local, state/provincial, and federal requirements. 14. Transport Information 14.1 U.S. Department of Transportation (DOT) The data provided in this section is for information only and may not be specific to your package size. You will need to apply the Page 202 of 878 Page 202 of 878 Page 202 of 878 Page 202 of 878 ---PAGE BREAK--- 5 of 7 appropriate regulations to properly classify your shipment for transportation. Non-Regulated. 14.2 Canadian Transportation of Dangerous Goods (TDG) Non-Regulated. 15. Regulatory Information (Selected Regulations) 15.1 U.S. Federal Regulations · OSHA Hazard Communication Standard 29CFR1910.1200 This material is not a "health hazard" or a "physical hazard" as determined when reviewed according to the requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200 "Hazard Communication" Standard. · SARA Title III: Section 311/312 Does not meet any hazard category · SARA Title III Section 313 and 40 CFR Part 372 This product contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and Subpart C-Supplier Notification Requirement of 40 CFR Part 372. None required per SARA TITLE III SECTION 313. · TSCA Section 8(b) Inventory All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications of compliance from our suppliers for chemical substances not manufactured by us. 15.2 Canadian Regulations · Workplace Hazardous Materials Information System (WHMIS) This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR) and the MSDS contains all the information required by the CPR. Page 203 of 878 Page 203 of 878 Page 203 of 878 Page 203 of 878 ---PAGE BREAK--- 6 of 7 Not a controlled product · Canadian Environmental Protection Act (CEPA) All reportable chemical substances are listed on the Domestic Substances List (DSL) or otherwise comply with CEPA new substance notification requirements. · National Pollutant Release Inventory (NPRI) This product contains the following chemical(s) subject to the reporting requirements of the Canadian Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release Inventory. None required. 16. Other Information CP (Non-Toxic): Products bearing the CP Certified Product Seal of The Art & Creative Materials Institute, Inc. (ACMI) are certified in a program of toxicological evaluation by a medical expert to contain no materials in sufficient quantities to be toxic or injurious to humans or to cause acute or chronic health problems. This program is reviewed by ACMI's Toxicological Advisory Board. These products are certified by ACMI to be labeled in accordance with the chronic hazard labeling standard, ASTM D-4236 and Federal law, P.L. 100-695. In addition, there is no physical hazard as defined within 29 CFR Part 1910.1200(c). Additionally, products bearing the CP Seal meet the specific requirements of material, workmanship, working qualities and color described in the appropriate product standard issued by ACMI or other recognized standards organization. MSDS covers items: U.S.: E371, E372, E375, E379, E381, E382, E383, E384, E385, E386, E393, E395, E61 E1366, E1462, E1501 Canada: 60345, 60352, 60355, 60359, 60375, 60385, 60395, 65120 · User's Responsibility The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace Hazardous Materials Information System (WHMIS) require that the information contained on these sheets be made available to your workers. Educate and train your workers regarding OSHA and WHMIS precautions. Instruct your workers to handle this product properly. Consult with appropriate experts to guard against hazards associated with use of this product and its ingredients. · Disclaimer SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product shall conform to contracted specifications, and that the product does not infringe any valid United States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of the quantity of Page 204 of 878 Page 204 of 878 Page 204 of 878 Page 204 of 878 ---PAGE BREAK--- 7 of 7 product in respect of which damages are claimed. In no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, negligence or otherwise. CURRENT ISSUE: 16-NOV-06 PREVIOUS ISSUE: 15-MAR-06 Page 205 of 878 Page 205 of 878 Page 205 of 878 Page 205 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET END BAC II DISINFECTANT SPRAY 1. PRODUCT AND COMPANY IDENTIFICATION Product name: END BAC II DISINFECTANT SPRAY MSDS 124740001 Product code: 54746 Recommended use: Disinfectant. Emergency telephone number: 1-[PHONE REDACTED] (Prosar); 1-[PHONE REDACTED] (Int'l Prosar); 01-[PHONE REDACTED] (México) 2. HAZARDS IDENTIFICATION Principle routes of exposure: Skin contact. Eye contact. Inhalation. Ingestion. Skin contact: May be mildly irritating to skin. Eye contact: May be mildly irritating to eyes. Inhalation: May be irritating to nose, throat, and respiratory tract. Ingestion: May be irritating to mouth, throat and stomach. 3. COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS COMPONENTS Ingredient CAS # Weight % LD50 Oral LD50 Dermal LC50 Inhalation Ethyl alcohol 64-17-5 40 - 50% 7060 mg/kg (rat) Not available 20 g/kg/10H (rat) Propane 74-98-6 5 - 10% Not available Not available Not available Isobutane 75-28-5 30 - 40% Not available Not available Not available 4. FIRST AID MEASURES Eye contact: Flush immediately with plenty of water. Get medical attention if irritation occurs. Skin contact: Rinse with plenty of water. Get medical attention if irritation occurs. Inhalation: If breathing is affected, remove to fresh air. Get medical attention. Ingestion: Immediately drink one cupful of water or milk. Never give anything by mouth to an unconscious person. Call medical attendant, medical doctor, or poison control center . Aggravated Medical Conditions: Persons with pre-existing skin disorders may be more susceptable to irritating effects 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: Dry chemical, water spray, foam, carbon dioxide. Specific hazards: Aerosol product - Containers may rocket or explode in heat of fire. Unusual hazards: None known Specific methods: Use water spray to keep fire-exposed containers cool. Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: None. Version Number: 2 Preparation date: 2005-06-22 EMERGENCY OVERVIEW CAUTION. CONTENTS UNDER PRESSURE. MAY CAUSE EYE AND SKIN IRRITATION. Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-0902 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.johnsondiversey.com END BAC II DISINFECTANT SPRAY Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] 1 of 3 NFPA Personal protective equipment HMIS Health 4 Reactivity 0 0 1 Fire Hazard 4 1 Page 206 of 878 Page 206 of 878 Page 206 of 878 Page 206 of 878 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Remove all sources of ignition. Environmental precautions and clean-up methods: Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. 7. HANDLING AND STORAGE Handling: Avoid contact with skin and eyes. Wash thoroughly after handling. Avoid breathing vapors or mists. Keep away from open flames, hot surfaces and sources of ignition. CONTENTS UNDER PRESSURE. Do not puncture or incinerate. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Keep closed in a dry, cool and well-ventilated place. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 degrees C or 120 degrees F. Do not pierce or burn, even after use. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: No special ventilation requirements. General room ventilation is adequate. Personal Protective Equipment Eye protection: No special requirements under normal use conditions Hand protection: No special requirements under normal use conditions Skin and body protection: No special requirements under normal use conditions Respiratory protection: No special requirements under normal use conditions Hygiene measures: Handle in accordance with good industrial hygiene and safety practice Ingredient CAS # ACGIH OSHA Mexico Ethyl alcohol 64-17-5 1000 ppm (TWA) 1900 mg/m3 1000 ppm 1900 mg/m3 (TWA) Propane 74-98-6 1000 ppm (TWA) 1800 mg/m3 1000 ppm Isobutane 75-28-5 1000 ppm (TWA) 9. PHYSICAL AND CHEMICAL PROPERTIES Partition coefficient (n-octanol/water): No information available 10. STABILITY AND REACTIVITY Stability: The product is stable Polymerization: Hazardous polymerisation does not occur Hazardous decomposition products: None reasonably foreseeable Conditions to avoid: Keep away from open flames, hot surfaces and sources of ignition. 11. TOXICOLOGICAL INFORMATION Component Information: See Section 3 Chronic toxicity: None known Specific effects Carcinogenic effects: None known Mutagenic effects: None known Reproductive toxicity: None known Target organ effects: None known Physical State: Density: No information available Boiling point/range: Not determined Bulk density: No information available Decomposition temperature: Not determined Appearance: Vapor density: No information available Odor: Characteristic Autoignition temperature: No information available Aerosol Evaporation rate: No information available Solubility: No information available Melting point/range: Not determined Solubility in other solvents: No information available Aerosol VOC: No information available Specific gravity: Viscosity: No information available 0.72 Flash point: <20 Color: pH: 9.0 - 10.0 END BAC II DISINFECTANT SPRAY Colourless 2 of 3 Dilution pH: No information available Page 207 of 878 Page 207 of 878 Page 207 of 878 Page 207 of 878 ---PAGE BREAK--- HAZARDOUS COMPONENTS Ingredient CAS # NTP IARC OSHA Ethyl alcohol 64-17-5 Listed. 12. ECOLOGICAL INFORMATION Environmental Information: When used for its intended purpose this product should not cause adverse effects in the environment 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: PESTICIDAL WASTE - Observe all applicable Federal/Provincial/State regulations and Local/Municipal ordinances regarding disposal of pesticide wastes . 14. TRANSPORT INFORMATION DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 STATE RIGHT TO KNOW Ingredient CAS # MARTK: PARTK: RIRTK: ILRTK: Ethyl alcohol 64-17-5 Listed Listed Listed Listed Listed Listed Water 7732-18-5 - - - - - - Propane 74-98-6 Listed Listed Listed Listed Listed Listed Isobutane 75-28-5 Listed Listed Listed - Listed Listed CERCLA / SARA Ingredient CAS # Weight % CERCLA/SARA RQ (lbs) Section 302 TPQ (lbs) Section 313 Ethyl alcohol 64-17-5 40 - 50% 100 Propane 74-98-6 5 - 10% 100 Isobutane 75-28-5 30 - 40% 100 CAA HAP/CAA ODS/CWA Priority Pollutants: None Canada WHMIS hazard class: Non-controlled. DIN No. : 02244932 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: None Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 3 of 3 END BAC II DISINFECTANT SPRAY Page 208 of 878 Page 208 of 878 Page 208 of 878 Page 208 of 878 ---PAGE BREAK--- Date Printed: 5/15/2015 Safety Data Sheet * Trusted Quality Since 1921 * www.rustoleum.com 1. Identification Product Name: EPOXYS SSPR 6PK ANTI-SLIP AEROSOL Revision Date: 5/15/2015 Product Identifier: 268652 Supercedes Date: 4/30/2015 Product Use/Class: Anti Slip Coating/Aerosols Supplier: Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA Manufacturer: Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA Preparer: Regulatory Department 24 Hour Hotline: [PHONE REDACTED] Emergency Telephone: 2. Hazard Identification EMERGENCY OVERVIEW: Harmful if swallowed. Extremely flammable liquid and vapor. Vapors may cause flash fire or explosion. Contents Under Pressure. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if inhaled. Causes eye irritation. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Vapor Harmful. Causes Eye, Skin, Nose, and Throat Irritation. Classification Symbol(s) of Product Signal Word Danger Possible Hazards 61% of the mixture consists of ingredient(s) of unknown acute toxicity GHS HAZARD STATEMENTS Flammable Aerosol, category 1 H222 Extremely flammable aerosol. Flammable Liquid, category 1 H224 Extremely flammable liquid and vapour. Acute Toxicity, Oral, category 5 H303 May be harmful if swallowed. Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin. Skin Irritation, category 2 H315 Causes skin irritation. Eye Irritation, category 2 H319 Causes serious eye irritation. Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled. STOT, single exposure, category 3, RTI H335 May cause respiratory irritation. STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness. Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways Eye Irritation, category 2B H320 Causes eye irritation Flammable Aerosol, category 1 H280 Contains gas under pressure; may explode if heated. Page 1 / 7 Page 209 of 878 Page 209 of 878 Page 209 of 878 Page 209 of 878 ---PAGE BREAK--- Date Printed: 5/15/2015 GHS LABEL PRECAUTIONARY STATEMENTS P211 Do not spray on an open flame or other ignition source. P251 Do not pierce or burn, even after use. P375 Fight fire remotely due to the risk of explosion. P102 Keep out of reach of children. P103 Read label before use. P202 Do not handle until all safety precautions have been read and understood. P234 Keep only in original container. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P262 Do not get in eyes, on skin, or on clothing. P264 Wash … thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. P285 In case of inadequate ventilation wear respiratory protection. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P350 Gently wash with plenty of soap and water. P374 Fight fire with normal precautions from a reasonable distance. P402 Store in a dry place. P410+P412 Protect from sunlight. Do no expose to temperatures exceeding 50°C/ 122°F. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P403+P235 Store in a well-ventilated place. Keep cool. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P362 Take off contaminated clothing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. P403+P233 Store in a well-ventilated place. Keep container closed. 3. Composition/Information On Ingredients HAZARDOUS SUBSTANCES Chemical Name CAS-No. Wt.% Range GHS Symbols GHS Statements Acetone 10-25 GHS02-GHS07 H225-336-319 67-64-1 Propane 10-25 74-98-6 Xylene (mixed isomers) 10-25 GHS02-GHS07 H226-312-[PHONE REDACTED]-20-7 n-Butyl Acetate 10-25 GHS02-GHS07 H225-336 123-86-4 n-Butane 2.5-10 106-97-8 2.5-10 GHS02-GHS07 H225-332 100-41-4 Aromatic Petroleum Distillates 1.0-2.5 GHS06 H227-310 64742-94-5 The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section. 4. First-aid Measures FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed. FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists. FIRST AID - INHALATION: If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately. Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. Page 2 / 7 Page 210 of 878 Page 210 of 878 Page 210 of 878 Page 210 of 878 ---PAGE BREAK--- Date Printed: 5/15/2015 FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention. 5. Fire-fighting Measures EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20°F. EXTREMELY FLAMMABLE LIQUID AND VAPOR!Water spray may be ineffective. Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a source of ignition and flash back. Keep containers closed. Isolate from heat, electrical equipment, sparks and open flame. Perforation of the pressurized container may cause bursting of the can. Closed containers may explode when exposed to extreme heat due to buildup of steam. No unusual fire or explosion hazards noted. SPECIAL FIREFIGHTING PROCEDURES: Evacuate area and fight fire from a safe distance. Full protective equipment including self-contained breathing apparatus should be used. Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Use water spray to keep fire-exposed containers cool. Containers may explode when heated. 6. Accidental Release Measures STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Remove all sources of ignition, ventilate area and remove with inert absorbent and non- sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Ventilate area, isolate spilled material, and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations. 7. Handling and Storage HANDLING: Wash thoroughly after handling. Wash hands before eating. Use only in a well-ventilated area. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Avoid contact with eyes, skin and clothing. STORAGE: Keep containers closed. Isolate from heat, electrical equipment, sparks and open flame. Contents under pressure. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of NFPA Class I flammable liquids. Contents under pressure. Do not expose to heat or store above 120 ° F. Product should be stored in sealed containers and protected from heat, moisture, and foreign materials. Store in a dry, well ventilated place. Keep container closed when not in use. Keep away from heat, sparks, flame and sources of ignition. Avoid excess heat. 8. Exposure Controls/Personal Protection Chemical Name CAS-No. Weight % Less Than ACGIH TLV- TWA ACGIH TLV- STEL OSHA PEL-TWA OSHA PEL- CEILING Acetone 67-64-1 25.0 500 ppm 750 ppm 1000 ppm N.E. Propane 74-98-6 20.0 1000 ppm N.E. 1000 ppm N.E. Xylene (mixed isomers) 1330-20-7 15.0 100 ppm 150 ppm 100 ppm N.E. n-Butyl Acetate 123-86-4 15.0 150 ppm 200 ppm 150 ppm N.E. n-Butane 106-97-8 10.0 1000 ppm 1000 ppm N.E. N.E. 100-41-4 5.0 20 ppm 125 ppm 100 ppm N.E. Aromatic Petroleum Distillates 64742-94-5 5.0 N.E. N.E. N.E. N.E. PERSONAL PROTECTION ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use explosion-proof ventilation equipment. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation. Provide general dilution of local exhaust ventilation in volume and pattern to keep TLV of hazardous ingredients below acceptable limits. RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection. Use gloves to prevent prolonged skin contact. EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids. Page 3 / 7 Page 211 of 878 Page 211 of 878 Page 211 of 878 Page 211 of 878 ---PAGE BREAK--- Date Printed: 5/15/2015 OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application. Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications. HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse. 9. Physical and Chemical Properties Appearance: Aerosolized Mist Physical State: Liquid Odor: Solvent Like Odor Threshold: N.E. Relative Density: 0.756 pH: N.A. Freeze Point, N.D. Viscosity: N.D. Solubility in Water: Slight Partition Coefficient, n- octanol/water: No Information Decompostion Temp., No Information Boiling Range, -11 - 397 Explosive Limits, vol%: 0.7 - 13.0 Flammability: Does not Support Combustion Flash Point, -105 Evaporation Rate: Faster than Ether Auto-ignition Temp., No Information Vapor Density: Heavier than Air Vapor Pressure: N.D. (See "Other information" Section for abbreviation legend) 10. Stability and Reactivity CONDITIONS TO AVOID: Avoid temperatures above 120 ° F. Avoid all possible sources of ignition. Avoid contact with strong acid and strong bases. INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies. HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. 11. Toxicological information EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin irritation. Prolonged or repeated contact may cause skin irritation. May cause skin irritation. Allergic reactions are possible. EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and lungs. Prolonged or excessive inhalation may cause respiratory tract irritation. EFFECTS OF OVEREXPOSURE - INGESTION: Aspiration hazard if swallowed; can enter lungs and cause damage. Harmful if swallowed. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: IARC lists as a possible human carcinogen (group 2B). Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. May cause central nervous system disorder narcosis involving a loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage. PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact ACUTE TOXICITY VALUES The acute effects of this product have not been tested. Data on individual components are tabulated below: CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50 74-98-6 Propane N.I. N.I. 658 mg/L Rat 1330-20-7 Xylene (mixed isomers) 4300 mg/kg Rat N.I. 47635 mg/L Rat 123-86-4 n-Butyl Acetate N.I. >17600 mg/kg Rabbit N.I. 100-41-4 3500 mg/kg Rat 15354 mg/kg Rabbit 17.2 mg/L Rat 64742-94-5 Aromatic Petroleum Distillates >5000 mg/kg Rat >2 mL/kg Rabbit N.I. Page 4 / 7 Page 212 of 878 Page 212 of 878 Page 212 of 878 Page 212 of 878 ---PAGE BREAK--- Date Printed: 5/15/2015 N.I. - No Information 12. Ecological Information ECOLOGICAL INFORMATION: Product is a mixture of listed components. Product is a mixture of listed components. 13. Disposal Information DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow to enter waterways, wastewater, soil, storm drains or sewer systems. 14. Transport Information Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada) UN Number: N.A. 1950 1950 N.A. Proper Shipping Name: Paint Products in Limited Quantities Aerosols Aerosols Paint Products in Limited Quantities Hazard Class: N.A. 2.1 2.1 N.A. Packing Group: N.A. N.A. N.A. N.A. Limited Quantity: Yes Yes Yes Yes 15. Regulatory Information U.S. Federal Regulations: CERCLA - SARA Hazard Category This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Fire Hazard, Pressure Hazard, Acute Health Hazard, Chronic Health Hazard Sara Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name CAS-No. Xylene (mixed isomers) 1330-20-7 100-41-4 Toxic Substances Control Act: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported from the United States: No TSCA 12(b) components exist in this product. CALIFORNIA PROPOSITION 65: WARNING: This product contains a substance known to the State of California to cause cancer. Chemical Name CAS-No. 100-41-4 Naphthalene 91-20-3 Benzene 71-43-2 Page 5 / 7 Page 213 of 878 Page 213 of 878 Page 213 of 878 Page 213 of 878 ---PAGE BREAK--- Date Printed: 5/15/2015 CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS WARNING: This product contains a substance known to the State of California to cause birth defects or other reproductive harm. Chemical Name CAS-No. Toluene 108-88-3 Benzene 71-43-2 International Regulations: CANADIAN WHMIS: This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings. 16. Other Information HMIS RATINGS Health: 2* Flammability: 4 Physical Hazard: 0 Personal Protection: X CANADIAN WHMIS CLASS: AB5 D2A NFPA RATINGS Health: 2 Flammability: 4 Instability 0 VOLATILE ORGANIC COMPOUNDS, g/L: 571 MSDS REVISION DATE: 5/15/2015 REASON FOR REVISION: No Information Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined Text for GHS Hazard Statements shown in Section 3 describing each ingredient: H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H227 Combustible liquid H310 Fatal in contact with skin. H312 Harmful in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness. Icons for GHS Pictograms shown in Section 3 describing each ingredient: GHS02 GHS06 Page 6 / 7 Page 214 of 878 Page 214 of 878 Page 214 of 878 Page 214 of 878 ---PAGE BREAK--- Date Printed: 5/15/2015 GHS07 Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations. Page 7 / 7 Page 215 of 878 Page 215 of 878 Page 215 of 878 Page 215 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET EXTRACTION CLEANER 1. PRODUCT AND COMPANY IDENTIFICATION Product name: EXTRACTION CLEANER MSDS 2264126354004 Product code: 03844 Recommended use: Carpet Care . Emergency telephone number: 1-[PHONE REDACTED] (Prosar); 1-[PHONE REDACTED] (Int'l Prosar); 01-[PHONE REDACTED] (México) 2. HAZARDS IDENTIFICATION Principle routes of exposure: Eyes. Skin. Inhalation. Skin contact: May be mildly irritating to skin. Eye contact: Moderately irritating to the eyes. Inhalation: May be irritating to nose, throat, and respiratory tract. Ingestion: May be irritating to mouth, throat and stomach. 3. COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS COMPONENTS Ingredient CAS # Weight % LD50 Oral LD50 Dermal LC50 Inhalation Alcohol ethoxylates 34398-01-1 1 - 5% Not available Not available Not available 4. FIRST AID MEASURES Eye contact: Flush immediately with plenty of water. If irritation persists, get medical attention. Skin contact: Flush immediately with plenty of water. If irritation persists, get medical attention. Inhalation: If breathing is affected, remove to fresh air. Get medical attention. Ingestion: Immediately drink one cupful of water or milk. Never give anything by mouth to an unconscious person. Get medical attention. Aggravated Medical Conditions: Persons with pre-existing skin disorders may be more susceptable to irritating effects 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: Not applicable Specific hazards: Not applicable Unusual hazards: None known Specific methods: No special methods required EMERGENCY OVERVIEW CAUTION. CONCENTRATE. MAY CAUSE EYE IRRITATION. Mild skin irritation. Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-0902 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.johnsondiversey.com Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] Version Number: 1 EXTRACTION CLEANER 1 of 3 Preparation date: 2005-04-29 Personal protective equipment HMIS NFPA 0 Reactivity 0 0 2 Fire Hazard 0 2 Health Page 216 of 878 Page 216 of 878 Page 216 of 878 Page 216 of 878 ---PAGE BREAK--- Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: No information available 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Not relevant for the product itself. Environmental precautions and clean-up methods: No information available 7. HANDLING AND STORAGE Handling: Avoid contact with skin, eyes and clothing. Wash thoroughly after handling. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing . Keep closed in a dry, cool and well-ventilated place. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: No special ventilation requirements. General room ventilation is adequate. Personal Protective Equipment Eye protection: Safety glasses are not normally required. However, their use is recommended in those cases where handling the undiluted product involves a risk of splashing. Hand protection: No special requirements under normal use conditions. Skin and body protection: If major exposure is possible, wear suitable protective clothing and footwear. Respiratory protection: No special requirements under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice 9. PHYSICAL AND CHEMICAL PROPERTIES Partition coefficient (n-octanol/water): No information available 10. STABILITY AND REACTIVITY Stability: Stable. Polymerization: Hazardous polymerisation does not occur. Hazardous decomposition products: None reasonably foreseeable Materials to avoid: Strong oxidising agents. Conditions to avoid: No special storage conditions required. 11. TOXICOLOGICAL INFORMATION Acute toxicity Oral, LD50 estimated to be greater than 5000 mg/kg, Dermal, LD50 estimated to be > 2000 mg/kg. Component Information: See Section 3 Chronic toxicity: None known Specific effects Carcinogenic effects: None known Mutagenic effects: None known Reproductive toxicity: None known Target organ effects: None known 12. ECOLOGICAL INFORMATION Environmental Information: no data available. Appearance: Vapor density: No information available Odor: Apple Autoignition temperature: No information available Aqueous solution Evaporation rate: No information available Solubility: Soluble Melting point/range: Not determined Solubility in other solvents: No information available Liquid VOC: 0 Specific gravity: Viscosity: No information available 1.015 Flash point: >200 >93 Color: pH: 9.75 Colourless Dilution pH: No information available Physical State: Density: 8.47 Boiling point/range: Not determined Bulk density: No information available EXTRACTION CLEANER 2 of 3 Decomposition temperature: Not determined Page 217 of 878 Page 217 of 878 Page 217 of 878 Page 217 of 878 ---PAGE BREAK--- 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Dispose of according to all federal, state and local applicable regulations 14. TRANSPORT INFORMATION DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 STATE RIGHT TO KNOW Ingredient CAS # MARTK: PARTK: RIRTK: ILRTK: Water 7732-18-5 - - - - - - Tetrasodium salt of EDTA 64-02-8 - - - - - - Alcohol ethoxylates 34398-01-1 - - - - - - CERCLA / SARA SARA 311/312 Hazard Categories Immediate: Y Delayed: N Fire: N Reactivity: N Sudden Release of Pressure: N Canada WHMIS hazard class: D2B Toxic materials . 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: None Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 3 of 3 EXTRACTION CLEANER Page 218 of 878 Page 218 of 878 Page 218 of 878 Page 218 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Page 1 of 3 Revised 2/02/04 EYE GLASS CLEANER EYE GLASS CLEANER Replaces 8/12/03 Printed 2/03/04 MSDS ID: 02082 MSDS ID: 02082 I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Product Discriptor: MANUFACTURER: JOHNSONDIVERSEY, INC. EMERGENCY PHONE NUMBER:(800)851-7145 3630 E. KEMPER ROAD CINCINNATI, OH. 45241 II. HAZARDOUS COMPONENTS II. HAZARDOUS COMPONENTS Component Name CAS Number % Exposure Limits Units EYE GLASS CLEANER >30% None established III. HAZARDS IDENTIFICATION III. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: SIGNS AND OF OVEREXPOSURE ACUTE: IRRITATES EYES; CAUSES SKIN DRYNESS CHRONIC: SAME AS ACUTE MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Sensitive skin IV. FIRST AID MEASURES IV. FIRST AID MEASURES V. FIRE FIGHTING MEASURES V. FIRE FIGHTING MEASURES FLASH POINT (degrees 96 FLAME EXTENSION: N/A FLAMMABLE LIMITS IN AIR BY VOLUME: LEL: N/A UEL: N/A EXTINGUISHING MEDIA: C02, FOAM, DRY CHEMICALS FIRE FIGHTING INSTRUCTIONS: Wear full protective gear and positive pressure breathing apparatus (SCBA) in fire area. VI. ACCIDENTAL RELEASE MEASURES VI. ACCIDENTAL RELEASE MEASURES IF MATERIAL IS RELEASED OR SPILLED: ELIMINATE SOURCES OF IGNITION. ABSORB LIQUID ON PAPER, VERMICULITE FLOOR ABSORBENT OR OTHER ABOSRBNET MATERIAL AND TRANSFER TO HOOD. This product does not contain a reportable quantity (RQ) under CERCLA. VII. HANDLING AND STORAGE VII. HANDLING AND STORAGE HANDLING AND STORAGE PRECAUTIONS: KEEP CONTAINER CLOSED. STORE AWAY FROM HEAT, FLAME AND SPARKING EQUIPMENT. IF FROZEN, THAW AND MIX TO MAKE USABLE. Industrial Page 219 of 878 Page 219 of 878 Page 219 of 878 Page 219 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Page 2 of 3 Revised 2/02/04 EYE GLASS CLEANER EYE GLASS CLEANER Replaces 8/12/03 Printed 2/03/04 MSDS ID: 02082 MSDS ID: 02082 VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION EYE/FACE PROTECTION: SAFETY GLASSES PROTECTIVE GLOVES: IMPERVIOUS OTHER PROTECTIVE CLOTHING/EQUIPMENT: NONE ENGINEERING CONTROLS: MECHANICAL VENTILATION: PROVIDE NORMAL AIR DILUTION LOCAL VENTILATION: NO IX. PHYSICAL AND CHEMICAL PROPERTIES IX. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE AND ODOR: BOILING POINT (DEG 212 FREEZING POINT: Not determined SPECIFIC GRAVITY/BULK DENSITY: pH: pH 1% SOLUTION: Not Determined VOLATILE BY VOLUME: 100% VAPOR PRESSURE(mmHg): 17.5 at 20 C VAPOR DENSITY: >1 X. STABILITY AND REACTIVITY X. STABILITY AND REACTIVITY CHEMICAL STABILITY: STABLE INCOMPATIBILITY WITH OTHER MATERIALS: OXIDES OF CARBON HAZARDOUS DECOMPOSITION PRODUCTS: None known. HAZARDOUS POLYMERIZATION: NONE KNOWN XI. TOXICOLOGICAL INFORMATION XI. TOXICOLOGICAL INFORMATION No data available. TOXICITY TEST DATA: No data available. XII. ECOLOGICAL INFORMATION XII. ECOLOGICAL INFORMATION ECOTOXICITY TEST DATA: No data available. ENVIRONMENTAL FATE: No data available. XIII. DISPOSAL CONSIDERATIONS XIII. DISPOSAL CONSIDERATIONS RCRA REGULATED: Not Regulated. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. XIV. TRANSPORT INFORMATION XIV. TRANSPORT INFORMATION Please refer to the Bill of Lading/receiving documents for up to date shipping information. Industrial Page 220 of 878 Page 220 of 878 Page 220 of 878 Page 220 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Page 3 of 3 Revised 2/02/04 EYE GLASS CLEANER EYE GLASS CLEANER Replaces 8/12/03 Printed 2/03/04 MSDS ID: 02082 MSDS ID: 02082 XV. REGULATORY INFORMATION XV. REGULATORY INFORMATION U.S. Federal Regulations: TSCA: All ingredients in this product are on TSCA inventory. HAPS: Contains no hazardous air pollutants. VOC CONTENT (EPA Method 24A): % VOC: Lb/Gal VOC: CERCLA/EPCRA: Section 313 Toxic Chemicals: None SARA Section 311/312: ACUTE:NO CHRONIC:NO FIRE:NO REACTIVITY:NO SUDDEN RELEASE OF PRESSURE:NO LISTED CARCINOGEN: NONE NTP: NO IARC: NO OSHA: NO HMIS RATINGS: HEALTH: 1 FIRE: 3 REACTIVITY: 0 PERSONAL PROTECTIVE EQUIPMENT: A NFPA RATING: HEALTH: FIRE: REACTIVITY: SPECIAL: STATE RIGHT-TO-KNOW INFORMATION: WATER - CAS #7732-18-5 ISOPROPANOL - CAS #67-63-0 CALIFORNIA PROPOSITION 65: None of the ingredients are on the California proposition 65 list. XVI. OTHER INFORMATION XVI. OTHER INFORMATION DISCLAIMER: The information contained in this material safety data sheet is based on the knowledge of this specific product and current national legisla- tion. It applies to the product as sold, use dilutions may be less hazardous. It may not be valid for this material if used in combination with any other materials or in a process. It is the user's responsibility to evaluate the handling, and use. Industrial Page 221 of 878 Page 221 of 878 Page 221 of 878 Page 221 of 878 ---PAGE BREAK--- SAFETY DATA SHEET FACILIPRO MILD FOAMING HAND SOAP 901411-03 1 / 7 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : FACILIPRO MILD FOAMING HAND SOAP Other means of identification : Not applicable Recommended use : Skin-care Restrictions on use : Reserved for industrial and professional use. Product dilution information : Product is sold ready to use. Company : Ecolab Inc. 370 N. Wabasha Street St. Paul, Minnesota USA 55102 1-[PHONE REDACTED] Emergency telephone : 1-[PHONE REDACTED] (US/Canada), 1-[PHONE REDACTED] (outside US) Issuing date : 10/17/2014 SECTION 2. HAZARDS IDENTIFICATION GHS Classification Eye irritation : Category 2B GHS Label element Signal Word : Warning Hazard Statements : Causes eye irritation. Precautionary Statements : Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. Other hazards : None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration sulfuric acid, mono-c10-16-alkyl esters, sodium salts 68585-47-7 1 - 5 110615-47-9 1 - 5 citric acid 77-92-9 0 - 0.1 Fragrance Proprietary Ingredient 0 - 1 SECTION 4. FIRST AID MEASURES In case of eye contact : Rinse with water. In case of skin contact : Rinse with water. If swallowed : Rinse mouth. Get medical attention if occur. Page 222 of 878 Page 222 of 878 Page 222 of 878 Page 222 of 878 ---PAGE BREAK--- SAFETY DATA SHEET FACILIPRO MILD FOAMING HAND SOAP 901411-03 2 / 7 If inhaled : Get medical attention if occur. Protection of first-aiders : No special precautions are necessary for first aid responders. Notes to physician : Treat See toxicological information (Section 11) SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media : None known. Specific hazards during fire fighting : Not flammable or combustible. Hazardous combustion products : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus Special protective equipment for fire-fighters : Use personal protective equipment. Specific extinguishing methods : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Refer to protective measures listed in sections 7 and 8. Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up : Stop leak if safe to do so. Contain spillage, and then collect with non- combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. SECTION 7. HANDLING AND STORAGE Advice on safe handling : No special handling advice required. Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers. Storage temperature : 5 °C to 50 °C SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Page 223 of 878 Page 223 of 878 Page 223 of 878 Page 223 of 878 ---PAGE BREAK--- SAFETY DATA SHEET FACILIPRO MILD FOAMING HAND SOAP 901411-03 3 / 7 Ingredients with workplace control parameters Contains no substances with occupational exposure limit values. Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection : No special protective equipment required. Hand protection : No special protective equipment required. Skin protection : No special protective equipment required. Respiratory protection : No personal respiratory protective equipment normally required. Hygiene measures : No specific measures identified. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Color : yellow Odor : sweet pH : 6.35, 100 % Flash point : Not applicable Odor Threshold : No data available Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Evaporation rate : No data available Flammability (solid, gas) : No data available Upper explosion limit : No data available Lower explosion limit : No data available Vapor pressure : No data available Relative vapor density : No data available Relative density : 1.014 Water solubility : No data available Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Autoignition temperature : No data available Thermal decomposition : No data available Viscosity, kinematic : No data available Explosive properties : No data available Oxidizing properties : No data available Molecular weight : No data available Page 224 of 878 Page 224 of 878 Page 224 of 878 Page 224 of 878 ---PAGE BREAK--- SAFETY DATA SHEET FACILIPRO MILD FOAMING HAND SOAP 901411-03 4 / 7 VOC : No data available SECTION 10. STABILITY AND REACTIVITY Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. Conditions to avoid : None known. Incompatible materials : None known. Hazardous decomposition products : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Eyes : Causes eye irritation. Skin : Health injuries are not known or expected under normal use. Ingestion : Health injuries are not known or expected under normal use. Inhalation : Health injuries are not known or expected under normal use. Chronic Exposure : Health injuries are not known or expected under normal use. Experience with human exposure Eye contact : Redness, Irritation Skin contact : No known or expected. Ingestion : No known or expected. Inhalation : No known or expected. Toxicity Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Acute inhalation toxicity : No data available Acute dermal toxicity : Acute toxicity estimate : > 5,000 mg/kg Skin corrosion/irritation : No data available Page 225 of 878 Page 225 of 878 Page 225 of 878 Page 225 of 878 ---PAGE BREAK--- SAFETY DATA SHEET FACILIPRO MILD FOAMING HAND SOAP 901411-03 5 / 7 Serious eye damage/eye irritation : Mild eye irritation Respiratory or skin sensitization : No data available Carcinogenicity : No data available Reproductive effects : No data available Germ cell mutagenicity : No data available Teratogenicity : No data available STOT-single exposure : No data available STOT-repeated exposure : No data available Aspiration toxicity : No data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects : Harmful to aquatic life. Product Toxicity to fish : No data available Toxicity to daphnia and other aquatic invertebrates : No data available Toxicity to algae : No data available Ingredients Toxicity to fish : 96 h LC50 Fish: 5 mg/l citric acid 96 h LC50 Fish: > 100 mg/l Ingredients Toxicity to daphnia and other aquatic invertebrates : sulfuric acid, mono-c10-16-alkyl esters, sodium salts 48 h EC50 Daphnia : 1.37 mg/l Persistence and degradability No data available Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods : The product should not be allowed to enter drains, water courses or the soil. Where possible recycling is preferred to disposal or Page 226 of 878 Page 226 of 878 Page 226 of 878 Page 226 of 878 ---PAGE BREAK--- SAFETY DATA SHEET FACILIPRO MILD FOAMING HAND SOAP 901411-03 6 / 7 incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re- use empty containers. SECTION 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (DOT) Not dangerous goods Sea transport (IMDG/IMO) Not dangerous goods SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Acute Health Hazard SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: Switzerland. New notified substances and declared preparations : not determined United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : This product contains one or several components listed in the Canadian NDSL. Australia Inventory of Chemical Substances (AICS) : On the inventory, or in compliance with the inventory Page 227 of 878 Page 227 of 878 Page 227 of 878 Page 227 of 878 ---PAGE BREAK--- SAFETY DATA SHEET FACILIPRO MILD FOAMING HAND SOAP 901411-03 7 / 7 New Zealand. Inventory of Chemical Substances : On the inventory, or in compliance with the inventory Japan. ENCS - Existing and New Chemical Substances Inventory : not determined Japan. ISHL - Inventory of Chemical Substances (METI) : not determined Korea. Korean Existing Chemicals Inventory (KECI) : not determined Philippines Inventory of Chemicals and Chemical Substances (PICCS) : not determined China. Inventory of Existing Chemical Substances in China (IECSC) : not determined SECTION 16. OTHER INFORMATION NFPA: HMIS III: Issuing date : 10/17/2014 Version : 1.6 Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Flammability Health Instability 1 0 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 0 0 1 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 228 of 878 Page 228 of 878 Page 228 of 878 Page 228 of 878 ---PAGE BREAK--- FACILIPRO WATERLESS FOAM HAND SANITIZER Skin antiseptic SAFETY DATA SHEET Product name Recommended use and restrictions : Supplier's information : FACILIPRO WATERLESS FOAM HAND SANITIZER Use only for the purpose on the product label. : Section 1. Chemical product and company identification Product dilution information : Not applicable Ecolab Inc. Institutional Division 370 N. Wabasha Street St. Paul, MN 55102 1-[PHONE REDACTED] EMERGENCY HEALTH INFORMATION: 1-[PHONE REDACTED] Outside United States and Canada CALL 1-[PHONE REDACTED] (in USA) Code Date of issue : : 04 Oct 2013 908598-03 GHS Classification : Signal word : Hazard statements : Symbol : Precautionary statements Prevention : Response : Storage : Disposal : Other hazards : Section 2. Hazards identification GHS label elements Product AS SOLD Product AT USE DILUTION Store in a well-ventilated place. Keep cool. FLAMMABLE LIQUIDS - Category 3 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B Warning Flammable liquid and vapor. Causes eye irritation. Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Keep container closed. No special protection is required. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. See section 13 for waste disposal information. None known. Product is sold ready to use. Page: 1/6 Page 229 of 878 Page 229 of 878 Page 229 of 878 Page 229 of 878 ---PAGE BREAK--- FACILIPRO WATERLESS FOAM HAND SANITIZER 04 Oct 2013 Mixture Section 3. Composition/information on ingredients Substance/mixture : Hazardous ingredients CAS number Concentration Range Product is sold ready to use. Hazardous ingredients CAS number Concentration Range Product AS SOLD Product AT USE DILUTION ALCOHOL >50 64-17-5 FARNESOL <1.0 4602-84-0 Eye contact Skin contact Inhalation Ingestion : : : : Protection of first- aiders : Notes to physician : See toxicological information (section 11) Section 4. First aid measures Product AS SOLD Product AT USE DILUTION Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse with water for a few minutes. Product is sold ready to use. Get medical attention if appear. No special measures required. Treat Get medical attention if occur. No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Hazardous thermal decomposition products Specific hazards arising from the chemical Special protective equipment for fire-fighters : : : Suitable fire extinguishing media : Specific fire-fighting methods : Section 5. Fire-fighting measures Product AS SOLD Use dry chemical, CO₂, water spray (fog) or foam. Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. Decomposition products may include the following materials: carbon dioxide carbon monoxide isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Page: 2/6 Page 230 of 878 Page 230 of 878 Page 230 of 878 Page 230 of 878 ---PAGE BREAK--- FACILIPRO WATERLESS FOAM HAND SANITIZER 04 Oct 2013 Environmental precautions Personal precautions : : Methods for cleaning up : Section 6. Accidental release measures Product AS SOLD Product AT USE DILUTION Eliminate all ignition sources. No special measures required. Product is sold ready to use. Avoid contact of large amounts of spilled material and runoff with soil and surface waterways. Absorb with an inert material. Use a water rinse for final clean-up. Handling Storage : : Section 7. Handling and storage Product AS SOLD Product AT USE DILUTION Store between the following temperatures: 0 and 30°C Keep away from heat, sparks and flame. To avoid fire, eliminate ignition sources. Wash hands after handling. Product is sold ready to use. Keep out of reach of children. Keep container closed. Keep container closed and sealed until ready for use. Keep container in a cool, well-ventilated area. Avoid all possible sources of ignition (spark or flame). Store in a segregated and approved area. Hand protection Eye protection Respiratory protection : : : Skin protection : Appropriate engineering controls : Hygiene measures : Control parameters Personal protection Section 8. Exposure controls/personal protection Product AS SOLD Product AT USE DILUTION ALCOHOL ACGIH TLV (United States, 3/2012). STEL: 1000 ppm 15 minutes. OSHA PEL (United States, 6/2010). TWA: 1900 mg/m³ 8 hours. TWA: 1000 ppm 8 hours. NIOSH REL (United States, 6/2009). TWA: 1000 ppm 10 hours. TWA: 1900 mg/m³ 10 hours. Ingredient name Exposure limits No special ventilation requirements. Product is sold ready to use. No special protection is required. No special measures required. No special protection is required. No special protection is required. No special protection is required. Page: 3/6 Page 231 of 878 Page 231 of 878 Page 231 of 878 Page 231 of 878 ---PAGE BREAK--- FACILIPRO WATERLESS FOAM HAND SANITIZER 04 Oct 2013 Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. 0.858 to 0.883 (Water = 1) Not available. Not available. Easily soluble in the following materials: cold water and hot water. Alcohol-like Odor pH Colorless Color Evaporation rate (butyl acetate = 1) Not available. Auto-ignition temperature Flash point Not available. 26 °C (Closed cup) Not available. 6 to 9 (100%) Viscosity Not available. Partition coefficient: n-octanol/water : : : : : : : : : : : : : : Boiling point : Not available. Flammability (solid, gas) : Not available. Explosion limits : Not available. Section 9. Physical and chemical properties Product AS SOLD Product AT USE DILUTION Product is sold ready to use. Decomposition temperature Odor threshold : : Not available. Not available. Hazardous decomposition products Conditions to avoid Stability Not available. : : : Materials to avoid : Possibility of hazardous reactions : Section 10. Stability and reactivity Product AS SOLD The product is stable. Under normal conditions of storage and use, hazardous reactions will not occur. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Route of exposure : Skin contact, Eye contact, Inhalation, Ingestion Section 11. Toxicological information Skin contact Ingestion Inhalation : : : Eye contact : Product AS SOLD Product AT USE DILUTION Adverse may include the following: irritation watering redness Product is sold ready to use. No specific data. No specific data. No specific data. Page: 4/6 Page 232 of 878 Page 232 of 878 Page 232 of 878 Page 232 of 878 ---PAGE BREAK--- FACILIPRO WATERLESS FOAM HAND SANITIZER 04 Oct 2013 Section 11. Toxicological information Toxicity data Product/ingredient name Carcinogenicity : Mutagenicity : Teratogenicity : Developmental effects : Fertility effects : Chronic toxicity Acute toxicity Inhalation : : Ingestion Skin contact : : Eye contact Causes eye irritation. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. ethanol LC50 Inhalation Vapor Rat 117 mg/l LD50 Dermal Rabbit 15800 mg/kg LD50 Oral Rat 10470 mg/kg No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Other adverse effects : Aquatic and terrestrial toxicity Product/ingredient name Species Result Exposure Ecotoxicity : No known significant effects or critical hazards. Section 12. Ecological information Product AS SOLD ethanol Acute LC50 11000 mg/l Fish 96 hours 2,6,10-dodecatrien-1-ol, 3,7,11-trimethyl- Acute EC50 2.2 mg/l Daphnia 48 hours Acute LC50 1.8 mg/l Fish 96 hours No known significant effects or critical hazards. : Disposal methods Section 13. Disposal considerations Product AS SOLD Product AT USE DILUTION Avoid disposal. Attempt to use product completely in accordance with intended use. Disposal should be in accordance with applicable regional, national and local laws and regulations. Product is sold ready to use. RCRA classification : Unused product is D001 (Ignitable) Section 14. Transport information Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. DOT DOT Classification DOT Proper shipping name Class Packing group IMO/IMDG IMO/IMDG Classification IMO/IMDG Proper shipping name UN1170 Ethanol solutions 3 III UN1170 ETHANOL SOLUTION Page: 5/6 Page 233 of 878 Page 233 of 878 Page 233 of 878 Page 233 of 878 ---PAGE BREAK--- FACILIPRO WATERLESS FOAM HAND SANITIZER 04 Oct 2013 Section 14. Transport information Product AT USE DILUTION Not intended for transport. Class Packing group 3 III For transport in bulk, see shipping documents for specific transportation information. Section 15. Regulatory information U.S. Federal regulations : TSCA 8(b) inventory All components are listed or exempted. Product AS SOLD SARA 302/304/311/312 extremely hazardous substances: No listed substance No listed substance SARA 302/304 emergency planning and notification: No listed substance SARA 313 Product name CAS number Concentration No listed substance Form R - Reporting requirements : California Prop. 65 : Date of issue The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION. Notice to reader : Section 16. Other information Prepared by : Regulatory Affairs 04 Oct 2013 Product AS SOLD Hazardous Material Information System 0 3 1 National Fire Protection Association Health Special Instability/Reactivity Flammability Health Flammability Physical hazards : : 1 0 3 * 1-[PHONE REDACTED] Page: 6/6 Page 234 of 878 Page 234 of 878 Page 234 of 878 Page 234 of 878 ---PAGE BREAK--- 1. PRODUCT AND COMPANY IDENTIFICATION Product name: FASTRIP Floor Stripper MSDS MS0300443 Product Code: 4122398, 4122401, 4362447 Recommended use: Industrial/Institutional. Floor stripper. This product is intended to be diluted prior to use. Emergency telephone number: 1-[PHONE REDACTED] 1-[PHONE REDACTED] (Int'l) 2. HAZARDS IDENTIFICATION Principle routes of exposure: Eye contact. Skin contact. Inhalation. Eye contact: Corrosive. Causes permanent eye damage, including blindness. Skin contact: Corrosive. Causes permanent damage. Inhalation: May cause irritation and corrosive effects to nose, throat and respiratory tract. Ingestion: Corrosive. Causes burns to mouth, throat and stomach. 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient(s) CAS # Weight % LD50 Oral - Rat (mg/kg) LD50 Dermal - Rabbit LC50 Inhalation - Rat Benzyl alcohol 100-51-6 20 - 30% 1230 2000 mg/kg 8.8 mg/L (4 h) Potassium hydroxide 1310-58-3 5 - 10% 273 Not available Not available Monoethanolamine 141-43-5 10 - 20% 1720 1 mL/kg Not available Glycerin 56-81-5 1 - 5% 10000 Not available >570 mg/m3 (1 h) 4. FIRST AID MEASURES Eye contact: Immediately flush eyes with running water for 15-20 minutes, keeping eyelids open. Get medical attention immediately. Skin contact: Immediately flush with plenty of water for 15-20 minutes . Get medical attention immediately. Inhalation: If breathing is affected, remove to fresh air. Get medical attention immediately. Ingestion: If swallowed, rinse mouth. Give a cupful of water or milk . THEN IMMEDIATELY CONTACT A PHYSICIAN OR POISON CENTER. DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Aggravated Medical Conditions: Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, etc., may be more susceptible to irritating effects FASTRIP Floor Stripper Manufacturer, importer, supplier: US Headquarters Diversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-1964 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.diversey.com Canadian Headquarters Diversey, Inc. - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] FASTRIP Floor Stripper MATERIAL SAFETY DATA SHEET EMERGENCY OVERVIEW DANGER. CORROSIVE. CAUSES SKIN AND EYE BURNS. HARMFUL OR FATAL IF SWALLOWED. HMIS NFPA Personal protective equipment 1 of 4 0 Health Health 3 Version Number: 1 Reactivity 0 Flammability Preparation date: 2010-03-12 0 3 Instability 0 Fire Hazard Page 235 of 878 Page 235 of 878 Page 235 of 878 Page 235 of 878 ---PAGE BREAK--- 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: The product is not flammable. Extinguish fire using agent suitable for surrounding fire. Specific hazards: Not applicable. Unusual hazards: Corrosive material (See sections 8 and 10). Specific methods: No special methods required. Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Extinguishing media which must not be used for safety reasons: No information available. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Put on appropriate personal protective equipment (see Section Environmental precautions and clean-up methods: Use appropriate containment to avoid environmental contamination. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Keep in suitable and closed containers for disposal. Use a water rinse for final clean-up. 7. HANDLING AND STORAGE Handling: Avoid contact with skin, eyes and clothing. Do not taste or swallow. Avoid breathing vapors or mists. Use only with adequate ventilation. Remove and wash contaminated clothing and footwear before re-use. Wash thoroughly after handling. Product residue may remain on/in empty containers. All precautions for handling the product must be used in handling the empty container and residue. . FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: Good general ventilation should be sufficient to control airborne levels Respiratory protection is not required if good ventilation is maintained Personal Protective Equipment Eye protection: Chemical-splash goggles. Hand protection: Chemical-resistant gloves Skin and body protection: Protective footwear. If major exposure is possible, wear suitable protective clothing and footwear. Respiratory protection: In case of insufficient ventilation wear suitable respiratory equipment. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Ingredient(s) CAS # ACGIH OSHA Mexico Potassium hydroxide 1310-58-3 2 mg/m3 (Ceiling) Monoethanolamine 141-43-5 6 ppm (STEL) 3 ppm (TWA) 3 ppm (TWA) 6 mg/m3 (TWA) 6 ppm (STEL) 15 mg/m3 (STEL) 8 mg/m3 (TWA) 3 ppm (TWA) Glycerin 56-81-5 10 mg/m3 (TWA) 5 mg/m3 (TWA) 15 mg/m3 (TWA) 10 mg/m3 (TWA) 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Clear Yellow Odor: Solvent Density: 9.01 lbs/gal 1.08 Kg/L Flash point: > 200 °F > 93.4 °C FASTRIP Floor Stripper Autoignition temperature: No information available Specific gravity: 1.08 Solubility: Completely Soluble Appearance: Liquid Solubility in other solvents: No information available Vapor density: No information available Viscosity: No information available Partition coefficient (n-octanol/water): No information available Elemental Phosphorus: 0 % by wt. Boiling point/range: Not determined VOC: 17.6 % * Evaporation Rate No information available Melting point/range: Not determined Bulk density: No information available Decomposition temperature: Not determined 2 of 4 Page 236 of 878 Page 236 of 878 Page 236 of 878 Page 236 of 878 ---PAGE BREAK--- Dilution pH: 12.7 @ (1:6) Explosion limits: - upper: Not determined - lower: Not determined * - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 10. STABILITY AND REACTIVITY Stability: The product is stable Polymerization: Hazardous polymerization does not occur. Hazardous decomposition products: None reasonably foreseeable. Materials to avoid: Acids. Strong oxidising agents. Conditions to avoid: Do not mix with any other product or chemical . 11. TOXICOLOGICAL INFORMATION Acute toxicity: Corrosive Oral LD50 estimated to be between 1000 - 2000 mg/kg Dermal LD50 estimated to be > 2000 mg/kg Component Information: See Section 3. Chronic toxicity: None known Specific effects Carcinogenic effects: None known Mutagenic effects: None known Reproductive toxicity: None known Target organ effects: None known 12. ECOLOGICAL INFORMATION Environmental Information: No data available. 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Undiluted product is regulated under environmental and transportation laws as a corrosive waste. Dispose of in compliance with all Federal, state, provincial, and local laws and regulations. 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65. RIGHT TO KNOW (RTK) Ingredient(s) CAS # MARTK: PARTK: RIRTK: Benzyl alcohol 100-51-6 X X X - Hexyloxyethanol 112-25-4 - X - - Potassium hydroxide 1310-58-3 X X X X Monoethanolamine 141-43-5 X X X X Glycerin 56-81-5 X - X X Potassium tallate 61790-44-1 - - - - Water 7732-18-5 - - - - CERCLA/ SARA FASTRIP Floor Stripper DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information . pH: 14 3 of 4 14. TRANSPORT INFORMATION Page 237 of 878 Page 237 of 878 Page 237 of 878 Page 237 of 878 ---PAGE BREAK--- Ingredient(s) CAS # Weight % CERCLA/SARA RQ (lbs) Section 302 TPQ (lbs) Section 313 Hexyloxyethanol 112-25-4 10 - 20% X Potassium hydroxide 1310-58-3 5 - 10% 1000 Ingredient(s) CAA HAP CAA ODS CWA Priority Pollutants Hexyloxyethanol X SARA 311/312 Hazard Categories Immediate: X Delayed: - Fire: - Reactivity: - Sudden Release of Pressure: - Canada WHMIS hazard class: E Corrosive material Ingredient(s) CAS # NPRI Glycerin 56-81-5 X 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: None. Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. FASTRIP Floor Stripper 4 of 4 Page 238 of 878 Page 238 of 878 Page 238 of 878 Page 238 of 878 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 20oz Expanding Foam Sealant Issue Date: 01/31/2008 Print Date: 01 Feb 2008 ®(TM)*Trademark of The Dow Chemical Company ("Dow") or an affiliated company of Dow Page 1 of 13 The Dow Chemical Company encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1. Product and Company Identification Product Name FILL AND SEAL (TM) 20oz Expanding Foam Sealant COMPANY IDENTIFICATION The Dow Chemical Company 2030 Willard H. Dow Center Midland, MI 48674 USA Customer Information Number: [PHONE REDACTED] EMERGENCY TELEPHONE NUMBER 24-Hour Emergency Contact: [PHONE REDACTED] Local Emergency Contact: [PHONE REDACTED] 2. Hazards Identification Emergency Overview Color: Yellow Physical State: Foam Odor: Mild Hazards of product: DANGER! Flammable gas - May cause flash fire. May cause allergic skin reaction. May cause allergic respiratory reaction. May cause eye irritation. May cause skin irritation. Vapor reduces oxygen available for breathing. May cause anesthetic effects. May cause respiratory tract irritation. Vapors may travel a long distance; ignition and/or flash back may occur. Evacuate area. Keep upwind of spill. Stay out of low areas. Aerosol cans exposed to fire can rupture becoming flaming projectiles. Elevated temperatures can cause hazardous polymerization. Toxic fumes may be released in fire situations. Containers are under high pressure. Avoid temperatures above 49 °C (120 OSHA Hazard Communication Standard Material Safety Data Sheet The Dow Chemical Company Page 239 of 878 Page 239 of 878 Page 239 of 878 Page 239 of 878 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 20oz Expanding Foam Sealant Issue Date: 01/31/2008 Page 2 of 13 This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Potential Health Effects Eye Contact: May cause eye irritation. May cause slight temporary corneal injury. Skin Contact: Prolonged contact may cause moderate skin irritation with local redness. Material may stick to skin causing irritation upon removal. May stain skin. Skin Absorption: Prolonged skin contact is unlikely to result in absorption of harmful amounts. Skin Sensitization: Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with isocyanates may play a role in respiratory sensitization. Inhalation: In confined or poorly ventilated areas, vapor can easily accumulate and can cause unconsciousness and death due to displacement of oxygen. Excessive exposure may cause irritation to upper respiratory tract (nose and throat) and lungs. May cause pulmonary edema (fluid in the lungs.) Effects may be delayed. May cause central nervous system depression. of excessive exposure may be anesthetic or narcotic effects; dizziness and drowsiness may be observed. Excessive exposure may increase sensitivity to epinephrine and increase myocardial irritability (irregular heartbeats). Decreased lung function has been associated with overexposure to isocyanates. Respiratory Sensitization: May cause allergic respiratory response. MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in individuals already sensitized. Asthma-like may include coughing, difficult breathing and a feeling of tightness in the chest. Occasionally, breathing difficulties may be life threatening. Ingestion: Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury. Observations in animals include: Gastrointestinal irritation. Effects of Repeated Exposure: Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after repeated excessive exposures to MDI/polymeric MDI aerosols. Contains component(s) which have been reported to cause effects on the following organs in animals: Kidney. Liver. Bone marrow. Contains a component which is reported to be a weak organophosphate-type cholinesterase inhibitor. Excessive exposure may produce organophosphate type cholinesterase inhibition. Signs and of excessive exposure may be headache, dizziness, incoordination, muscle twitching, tremors, nausea, abdominal cramps, diarrhea, sweating, pinpoint pupils, blurred vision, salivation, tearing, tightness in chest, excessive urination, convulsions. Cancer Information: Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory irritation and lung injury. Current exposure guidelines are expected to protect against these effects reported for MDI. Birth Defects/Developmental Effects: In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only at high doses which were toxic to the mother. Component CAS # Amount Isocyanic acid, polymethylenepolyphenylene ester, polymer with .alpha.,.alpha.',.alpha.''-1,2,3- propanetriyltris[.omega.-hydroxypoly 57029-46-6 30.0 - 60.0 % Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol coopolymer 53862-89-8 10.0 - 30.0 % Paraffin waxes and Hydrocarbon waxes, chlorinated 63449-39-8 5.0 - 10.0 % Isobutane 75-28-5 5.0 - 10.0 % Methyl ether 115-10-6 1.0 - 5.0 % Propane 74-98-6 1.0 - 5.0 % Tris(1-chloro-2-propyl) phosphate 13674-84-5 5.0 - 10.0 % Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 10.0 - 30.0 % 4,4' -Methylenediphenyl diisocyanate 101-68-8 5.0 - 10.0 % Note: CAS 101-68-8 is an MDI isomer that is part of CAS 9016-87-9. 3. Composition Information Page 240 of 878 Page 240 of 878 Page 240 of 878 Page 240 of 878 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 20oz Expanding Foam Sealant Issue Date: 01/31/2008 Page 3 of 13 4. First-aid measures Eye Contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5 minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist. Skin Contact: Remove material from skin immediately by washing with soap and plenty of water. Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists. Wash clothing before reuse. An MDI skin decontamination study demonstrated that cleaning very soon after exposure is important, and that a skin cleanser or corn oil may be more effective than soap and water. Discard items which cannot be decontaminated, including leather articles such as shoes, belts and watchbands. Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility. Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel. Notes to Physician: Maintain adequate ventilation and oxygenation of the patient. May cause asthma-like (reactive airways) Bronchodilators, expectorants, antitussives and corticosteroids may be of help. May cause respiratory sensitization or asthma-like Bronchodilators, expectorants and antitussives may be of help. Treat bronchospasm with inhaled beta2 agonist and oral or parenteral corticosteroids. Respiratory including pulmonary edema, may be delayed. Persons receiving significant exposure should be observed 24-48 hours for signs of respiratory distress. Exposure may increase "myocardial irritability". Do not administer sympathomimetic drugs such as epinephrine unless absolutely necessary. If you are sensitized to diisocyanates, consult your physician regarding working with other respiratory irritants or sensitizers. Although cholinesterase depression has been reported with this material, it is not of benefit in determining exposure and need not be considered in the treatment of persons exposed to the material. No specific antidote. Treatment of exposure should be directed at the control of and the clinical condition of the patient. Medical Conditions Aggravated by Exposure: Excessive exposure may aggravate preexisting asthma and other respiratory disorders (e.g. bronchitis, reactive airways dysfunction 5. Fire Fighting Measures Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Do not use direct water stream. Straight or direct water streams may not be effective to extinguish fire. Alcohol resistant foams (ATC type) are preferred. General purpose foams (including AFFF) or protein foams may function, but will be less effective. Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay upwind. Keep out of low areas where gases (fumes) can accumulate. Water may not be effective in extinguishing fire. Do not use direct water stream. May spread fire. Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Eliminate ignition sources. Move container from fire area if this is possible without hazard. Use water spray to cool fire- exposed containers and fire-affected zone until fire is out. Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer to the relevant sections. Unusual Fire and Explosion Hazards: Contains flammable propellant. Aerosol cans exposed to fire can rupture and become flaming projectiles. Propellant release may result in a fireball. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Dense smoke is produced when product burns. Page 241 of 878 Page 241 of 878 Page 241 of 878 Page 241 of 878 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 20oz Expanding Foam Sealant Issue Date: 01/31/2008 Page 4 of 13 Hazardous Combustion Products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Nitrogen oxides. Isocyanates. Hydrogen chloride. Carbon monoxide. Carbon dioxide. 6. Accidental Release Measures Steps to be Taken if Material is Released or Spilled: Contain spilled material if possible. Ground and bond all containers and handling equipment. Isolate area until gas has dispersed. Use non- sparking tools in cleanup operations. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Collect in suitable and properly labeled containers. Absorb with materials such as: Clay. Dirt. Milsorb®. Sand. Sawdust. Vermiculite. See Section 10 for more specific information. See Section 13, Disposal Considerations, for additional information. Personal Precautions: Evacuate area. Only trained and properly protected personnel must be involved in clean-up operations. Keep personnel out of low areas. Keep personnel out of confined or poorly ventilated areas. Keep upwind of spill. Ventilate area of leak or spill. No smoking in area. For large spills, warn public of downwind explosion hazard. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Vapor explosion hazard. Keep out of sewers. See Section 10 for more specific information. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection. Refer to Section 7, Handling, for additional precautionary measures. Environmental Precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. 7. Handling and Storage Handling General Handling: Keep away from heat, sparks and flame. Avoid contact with eyes. Avoid contact with skin and clothing. Avoid prolonged or repeated contact with skin. Avoid breathing vapor. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. Keep out of reach of children. No smoking, open flames or sources of ignition in handling and storage area. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Contents under pressure. Do not puncture or incinerate container. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers. Do not enter confined spaces unless adequately ventilated. Never use air pressure for transferring product. Use of non-sparking or explosion-proof equipment may be necessary, depending upon the type of operation. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION. Storage Minimize sources of ignition, such as static build-up, heat, spark or flame. Store in a dry place. See Section 10 for more specific information. Shelf life: Use within 12 Months 20 - 30 °C 8. Exposure Controls / Personal Protection Exposure Limits Component List Type Value I 4,4' -Methylenediphenyl diisocyanate ACGIH TWA 0.005 ppm Page 242 of 878 Page 242 of 878 Page 242 of 878 Page 242 of 878 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 20oz Expanding Foam Sealant Issue Date: 01/31/2008 Page 5 of 13 OSHA Table Z-1 Ceiling 0.2 mg/m3 0.02 ppm I Methyl ether WEEL TWA 1,880 mg/m3 1,000 ppm I Isobutane ACGIH TWA 1,000 ppm I Propane OSHA Table Z-1 PEL 1,800 mg/m3 1,000 ppm ACGIH TWA 1,000 ppm I Personal Protection Eye/Face Protection: Use safety glasses. Eye wash fountain should be located in immediate work area. Skin Protection: Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task. Remove contaminated clothing immediately, wash skin area with soap and water, and launder clothing before reuse or dispose of properly. Items which cannot be decontaminated, such as shoes, belts and watchbands, should be removed and disposed of properly. Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove barrier materials include: Butyl rubber. Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Examples of acceptable glove barrier materials include: Natural rubber ("latex"). Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Viton. Polyvinyl chloride ("PVC" or "vinyl"). NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier. Respiratory Protection: Atmospheric levels should be maintained below the exposure guideline. When atmospheric levels may exceed the exposure guideline, use an approved air-purifying respirator equipped with an organic vapor sorbent and a particle filter. For situations where the atmospheric levels may exceed the level for which an air-purifying respirator is effective, use a positive-pressure air-supplying respirator (air line or self-contained breathing apparatus). For emergency response or for situations where the atmospheric level is unknown, use an approved positive-pressure self- contained breathing apparatus or positive-pressure air line with auxiliary self-contained air supply. The following should be effective types of air-purifying respirators: Organic vapor cartridge with a particulate pre-filter. Ingestion: Use good personal hygiene. Do not consume or store food in the work area. Wash hands before smoking or eating. Engineering Controls Ventilation: Use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations. Provide general and/or local exhaust ventilation to control airborne levels below the exposure guidelines. Exhaust systems should be designed to move the air away from the source of vapor/aerosol generation and people working at this point. The odor and irritancy of this material are inadequate to warn of excessive exposure. 9. Physical and Chemical Properties Physical State Foam Color Yellow Odor Mild Flash Point - Closed Cup -104 °C (-155 Estimated Flammable Limits In Air Lower: No test data available Upper: No test data available Autoignition Temperature No test data available Vapor Pressure 1,151 kPa @ 55 °C Estimated Boiling Point (760 mmHg) Not applicable. Vapor Density (air = 1) No test data available Specific Gravity (H2O = 1) 1.06 Calculated Page 243 of 878 Page 243 of 878 Page 243 of 878 Page 243 of 878 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 20oz Expanding Foam Sealant Issue Date: 01/31/2008 Page 6 of 13 Freezing Point No test data available Melting Point No test data available Solubility in Water (by weight) Insoluble pH Not applicable Kinematic Viscosity Not applicable 10. Stability and Reactivity Stability/Instability Stable under recommended storage conditions. See Storage, Section 7. Unstable at elevated temperatures. Conditions to Avoid: Avoid temperatures above 49 °C (120 Elevated temperatures can cause container to vent and/or rupture. Exposure to elevated temperatures can cause product to decompose. Incompatible Materials: Avoid contact with: Acids. Alcohols. Amines. Ammonia. Bases. Metal compounds. Strong oxidizers. Products based on diisocyanates like TDI and MDI react with many materials to release heat. The reaction rate increases with temperature as well as with increased contact; these reactions can become violent. Contact is increased by stirring or if the other material acts as a solvent. Products based on diisocyanates such as TDI and MDI are not soluble in water and will sink to the bottom, but react slowly at the interface. The reaction forms carbon dioxide gas and a layer of solid polyurea. Reaction with water will generate carbon dioxide and heat. Hazardous Polymerization Can occur. Elevated temperatures can cause hazardous polymerization. Thermal Decomposition Decomposition products depend upon temperature, air supply and the presence of other materials. Toxic gases are released during decomposition. 11. Toxicological Information Acute Toxicity Ingestion Single dose oral LD50 has not been determined. Estimated LD50, Rat > 10,000 mg/kg Skin Absorption The LD50 has not been determined. Estimated LD50, Rabbit > 2,000 mg/kg Inhalation The LC50 has not been determined. Estimated LC50, Aerosol, Rat > 0.5 mg/l Sensitization Skin Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with isocyanates may play a role in respiratory sensitization. Respiratory May cause allergic respiratory response. MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in individuals already sensitized. Asthma-like may include coughing, difficult breathing and a feeling of tightness in the chest. Occasionally, breathing difficulties may be life threatening. Repeated Dose Toxicity Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after repeated excessive exposures to MDI/polymeric MDI aerosols. Contains component(s) which have been reported to cause effects on the following organs in animals: Kidney. Liver. Bone marrow. Contains a component which is reported to be a weak organophosphate-type cholinesterase inhibitor. Excessive exposure may produce organophosphate type cholinesterase inhibition. Signs and of excessive exposure may be headache, dizziness, incoordination, muscle twitching, Page 244 of 878 Page 244 of 878 Page 244 of 878 Page 244 of 878 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 20oz Expanding Foam Sealant Issue Date: 01/31/2008 Page 7 of 13 tremors, nausea, abdominal cramps, diarrhea, sweating, pinpoint pupils, blurred vision, salivation, tearing, tightness in chest, excessive urination, convulsions. Chronic Toxicity and Carcinogenicity Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory irritation and lung injury. Current exposure guidelines are expected to protect against these effects reported for MDI. Developmental Toxicity In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only at high doses which were toxic to the mother. Genetic Toxicology In vitro genetic toxicity studies were negative for component(s) tested. Genetic toxicity data on MDI are inconclusive. MDI was weakly positive in some in vitro studies; other in vitro studies were negative. Animal mutagenicity studies were predominantly negative. 12. Ecological Information CHEMICAL FATE Data for Component: Isocyanic acid, polymethylenepolyphenylene ester, polymer with .alpha.,.alpha.',.alpha.''-1,2,3-propanetriyltris[.omega.-hydroxypoly Movement & Partitioning In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Persistence and Degradability In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. Data for Component: Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol coopolymer Movement & Partitioning In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Persistence and Degradability In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. Data for Component: Paraffin waxes and Hydrocarbon waxes, chlorinated Movement & Partitioning Expected to be relatively immobile in soil (Koc > 5000). Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected to be an important fate process. Henry's Law Constant < 1.0E-07 atm*m3/mole; 25 °C Estimated Partition coefficient, n-octanol/water (log Pow): > 6 Estimated Persistence and Degradability Expected to degrade only slowly in the environment. Data for Component: Isobutane Movement & Partitioning Bioconcentration potential is low (BCF less than 100 or log Pow less than Potential for mobility in soil is very high (Koc between 0 and 50). Page 245 of 878 Page 245 of 878 Page 245 of 878 Page 245 of 878 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 20oz Expanding Foam Sealant Issue Date: 01/31/2008 Page 8 of 13 Henry's Law Constant 1.19E+00 atm*m3/mole; 25 °C Measured Partition coefficient, n-octanol/water (log Pow): 2.76 Measured Partition coefficient, soil organic carbon/water (Koc): 35 Estimated Distribution in Environment: Mackay Level 1 Fugacity Model: Air Water. Biota Soil Sediment 100 % 0 % 0 % 0 % 0 % Persistence and Degradability Biodegradation may occur under aerobic conditions (in the presence of oxygen). Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 2.44E-12 cm3/s 4.4 d Estimated Theoretical Oxygen Demand: 3.58 mg/mg Data for Component: Methyl ether Movement & Partitioning Bioconcentration potential is low (BCF less than 100 or log Pow less than Potential for mobility in soil is very high (Koc between 0 and 50). Henry's Law Constant 9.78E-4 atm*m3/mole; 25 °C Measured Partition coefficient, n-octanol/water (log Pow): 0.10 Measured Partition coefficient, soil organic carbon/water (Koc): 1.29 - 14 Estimated Persistence and Degradability Material is expected to biodegrade only very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 1.66E-12 cm3/s 6.4 d Estimated OECD Biodegradation Tests: Biodegradation Exposure Time Method 5 % 28 d OECD 301A Test Theoretical Oxygen Demand: 2.08 mg/mg Data for Component: Propane Movement & Partitioning Bioconcentration potential is low (BCF less than 100 or log Pow less than Potential for mobility in soil is very high (Koc between 0 and 50). Henry's Law Constant 7.07E-01 atm*m3/mole; 25 °C Measured Partition coefficient, n-octanol/water (log Pow): 2.36 Measured Partition coefficient, soil organic carbon/water (Koc): 24 - 460 Estimated Distribution in Environment: Mackay Level 1 Fugacity Model: Air Water. Biota Soil Sediment 100 % 0 % 0 % 0 % 0 % Persistence and Degradability No relevant information found. Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 1.27E-12 cm3/s 8.4 d Estimated Theoretical Oxygen Demand: 3.64 mg/mg Data for Component: Tris(1-chloro-2-propyl) phosphate Movement & Partitioning Bioconcentration potential is low (BCF < 100 or Log Pow < Potential for mobility in soil is low (Koc between 500 and 2000). Henry's Law Constant < 1.35E-5 atm*m3/mole; 25 °C Estimated Partition coefficient, n-octanol/water (log Pow): 2.59 Measured Partition coefficient, soil organic carbon/water (Koc): 1,300 Estimated Bioconcentration Factor (BCF): 0.8 - 4.6; common carp (Cyprinus carpio); Measured Page 246 of 878 Page 246 of 878 Page 246 of 878 Page 246 of 878 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 20oz Expanding Foam Sealant Issue Date: 01/31/2008 Page 9 of 13 Persistence and Degradability Material is expected to biodegrade only very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 4.47E-11 cm3/s 0.24 d Estimated OECD Biodegradation Tests: Biodegradation Exposure Time Method 14 % 28 d OECD 301E Test Theoretical Oxygen Demand: 1.17 mg/mg Data for Component: Diphenylmethane Diisocyanate, isomers and homologues Movement & Partitioning In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Persistence and Degradability In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. Data for Component: 4,4' -Methylenediphenyl diisocyanate Movement & Partitioning In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Persistence and Degradability In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. ECOTOXICITY Data for Component: Isocyanic acid, polymethylenepolyphenylene ester, polymer with .alpha.,.alpha.',.alpha.''-1,2,3-propanetriyltris[.omega.-hydroxypoly The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Toxicity to Soil Dwelling Organisms LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg Data for Component: Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol coopolymer The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Toxicity to Soil Dwelling Organisms LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg Data for Component: Paraffin waxes and Hydrocarbon waxes, chlorinated Material is practically non-toxic to fish on an acute basis (LC50 > 100 mg/L). Material is very highly toxic to aquatic invertebrates on an acute basis (LC50/EC50 < 0.1 mg/L). Fish Acute & Prolonged Toxicity LC50, rainbow trout mykiss), static, 96 h: > 100 mg/l Aquatic Invertebrate Acute Toxicity EC50, water flea Daphnia magna, immobilization: 0.037 mg/l Data for Component: Isobutane Page 247 of 878 Page 247 of 878 Page 247 of 878 Page 247 of 878 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 20oz Expanding Foam Sealant Issue Date: 01/31/2008 Page 10 of 13 No relevant information found. Data for Component: Methyl ether Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Fish Acute & Prolonged Toxicity LC50, guppy (Poecilia reticulata), 96 h: > 4,000 mg/l Aquatic Invertebrate Acute Toxicity LC50, water flea Daphnia magna, 48 h: > 4,000 mg/l Data for Component: Propane No relevant information found. Data for Component: Tris(1-chloro-2-propyl) phosphate Material is toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and 100 mg/L in the most sensitive species tested). Fish Acute & Prolonged Toxicity LC50, bluegill (Lepomis macrochirus), 96 h: 84 mg/l Aquatic Invertebrate Acute Toxicity EC50, water flea Daphnia magna, 48 h, immobilization: 63 mg/l Aquatic Plant Toxicity EC50, green alga Selenastrum capricornutum, biomass growth inhibition, 96 h: 47 mg/l EC50, alga Scenedesmus sp., biomass growth inhibition, 72 h: 45 mg/l Toxicity to Micro-organisms EC50, OECD 209 Test; activated sludge, respiration inhibition, 3 h: 784 mg/l Data for Component: Diphenylmethane Diisocyanate, isomers and homologues The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Toxicity to Soil Dwelling Organisms LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg Data for Component: 4,4' -Methylenediphenyl diisocyanate The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in the most sensitive species tested). Toxicity to Soil Dwelling Organisms LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg 13. Disposal Considerations DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. DOW HAS NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed, permitted: Incinerator or other thermal destruction device. As a service to its customers, Dow can provide names of information resources to help identify waste management companies and other facilities which recycle, reprocess or manage chemicals or plastics, and that manage used drums. Telephone Dow's Customer Information Group at 1-[PHONE REDACTED] or 1-989- 832-1556 or 1-[PHONE REDACTED] (Canada) for further details. Page 248 of 878 Page 248 of 878 Page 248 of 878 Page 248 of 878 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 20oz Expanding Foam Sealant Issue Date: 01/31/2008 Page 11 of 13 14. Transport Information DOT Non-Bulk CONSUMER COMMODITY RECLASSIFIED AS ORM-D MATERIAL DOT Bulk NOT AVAILABLE IN BULK CONTAINERS IMDG Proper Shipping Name: AEROSOLS, FLAMMABLE Hazard Class: 2.1 ID Number: UN1950 EMS Number: F-D,S-U LIMITED QUANTITY ICAO/IATA Proper Shipping Name: AEROSOLS, FLAMMABLE Hazard Class: 2.1 ID Number: UN1950Cargo Packing Instruction: 203 Passenger Packing Instruction: 203 LIMITED QUANTITY This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Additional transportation system information can be obtained through an authorized sales or customer service representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material. 15. Regulatory Information OSHA Hazard Communication Standard This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Sections 311 and 312 Immediate (Acute) Health Hazard Yes Delayed (Chronic) Health Hazard Yes Fire Hazard Yes Reactive Hazard No Sudden Release of Pressure Hazard Yes Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Section 313 This product contains the following substances which are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and which are listed in 40 CFR 372. Component CAS # Amount 4,4' -Methylenediphenyl diisocyanate 101-68-8 5.0 - 10.0 % Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 10.0 - 30.0 % (Worker and Community Right-To-Know Act): Hazardous Substances List and/or Environmental Hazardous Substance List: The following product components are cited in the Hazardous Substance List and/or the Environmental Substance List, and are present at levels which require reporting. Page 249 of 878 Page 249 of 878 Page 249 of 878 Page 249 of 878 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 20oz Expanding Foam Sealant Issue Date: 01/31/2008 Page 12 of 13 Component CAS # Amount 4,4' -Methylenediphenyl diisocyanate 101-68-8 5.0 - 10.0 % Methyl ether 115-10-6 1.0 - 5.0 % Propane 74-98-6 1.0 - 5.0 % Isobutane 75-28-5 5.0 - 10.0 % (Worker and Community Right-To-Know Act): Special Hazardous Substances List: To the best of our knowledge, this product does not contain chemicals at levels which require reporting under this statute. California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986) This product contains no listed substances known to the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute. US. Toxic Substances Control Act All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.30 CEPA - Domestic Substances List (DSL) All substances contained in this product are listed on the Canadian Domestic Substances List (DSL) or are not required to be listed. 16. Other Information Recommended Uses and Restrictions Polyurethane foam. Revision Identification Number: 63951 / 0000 / Issue Date 01/31/2008 / Version: 2.0 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. Legend N/A Not available W/W Weight/Weight OEL Occupational Exposure Limit STEL Short Term Exposure Limit TWA Time Weighted Average ACGIH American Conference of Governmental Industrial Hygienists, Inc. DOW IHG Dow Industrial Hygiene Guideline WEEL Workplace Environmental Exposure Level HAZ_DES Hazard Designation Action Level A value set by OSHA that is lower than the PEL which will trigger the need for activities such as exposure monitoring and medical surveillance if exceeded. The Dow Chemical Company urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have Page 250 of 878 Page 250 of 878 Page 250 of 878 Page 250 of 878 ---PAGE BREAK--- Product Name: FILL AND SEAL (TM) 20oz Expanding Foam Sealant Issue Date: 01/31/2008 Page 13 of 13 obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version. Page 251 of 878 Page 251 of 878 Page 251 of 878 Page 251 of 878 ---PAGE BREAK--- Powerful - Multi Purpose This concentrated, heavy-duty degreaser floats away grease, oil, dirt, dye, ink, soap scum, light carbon and other industrial grime. It is specifically formulated to attack, suspend and rinse away the heaviest industrial grit. It can be sprayed or wiped onto any surface not harmed by water. SPECIFICATIONS FOR FIREBALL Type Butyl Degreaser Clear Liquid Odor Pine Detergent Type Purple Weight per 8.73 lbs. pH 8.5 - 9.5 pH 1% 9.4 Storage Min. 1 Year Freeze/Thaw Passes 3 Cycles Foam Height Medium High Flash Point None Actives >15% Phosphate 0.9 Features • Variable Dilution Rate – From 1 - 12 Ounces per Gallon • Pine Fragrance • All-Purpose – Use Wherever Heavy Soil is Found • Classified Non-Hazardous by DOT • USDA A1 Authorized Twin Cities Duluth Rochester LaCrosse Reorder no. 3803 Distributed by: 300 5th Ave NW New Brighton, MN 51122 www.dalcoonline.com 1-[PHONE REDACTED] Fireball High Powered Degreaser Page 252 of 878 Page 252 of 878 Page 252 of 878 Page 252 of 878 ---PAGE BREAK--- Page 253 of 878 Page 253 of 878 Page 253 of 878 Page 253 of 878 ---PAGE BREAK--- Page 254 of 878 Page 254 of 878 Page 254 of 878 Page 254 of 878 ---PAGE BREAK--- Page 255 of 878 Page 255 of 878 Page 255 of 878 Page 255 of 878 ---PAGE BREAK--- Page 256 of 878 Page 256 of 878 Page 256 of 878 Page 256 of 878 ---PAGE BREAK--- Page 257 of 878 Page 257 of 878 Page 257 of 878 Page 257 of 878 ---PAGE BREAK--- Safe Set 7 Clear Spread Adhesive M A T E R I A L S A F E T Y D A T A S H E E T Page: 1 PRODUCT NAME: FlorCraft Vinyl Composition Tile Adhesive HMIS CODES: H F R P PRODUCT CODE: SS7D 1 0 0 B SECTION I - MANUFACTURER IDENTIFICATION MANUFACTURER'S NAME: TILE PERFECT ADDRESS: 1105 SOUTH FRONTENAC ST. AURORA, IL. 60504 EMERGENCY PHONE: [PHONE REDACTED] DATE REVISED: 05/18/2004 DATE PRINTED: 09/29/2005 INFORMATION PHONE: [PHONE REDACTED] NAME OF PREPARER: Michelle Kascak SECTION II - HAZARDOUS INGREDIENTS/SARA III INFORMATION VAPOR PRESSURE WEIGHT COMPONENTS CAS NUMBER MM HG @ TEMP PERCENT No toxic chemical(s) subject to the reporting requirements of section 313 of Title III and of 40 CFR 372 are present. Hazardous ingredients must be reported when present at 1.0% or greater.*** SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS BOILING POINT: 212 Degrees F. SPECIFIC GRAVITY (H2O=1): 1.11 VAPOR DENSITY: Heavier than air. EVAPORATION RATE: Slower than Ether. SOLUBILITY IN WATER: Soluble. APPEARANCE AND ODOR: Off-White paste - Mild sweet odor. SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT: NA METHOD USED: NA FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER: NA UPPER: NA EXTINGUISHING MEDIA: Will not support combustion. SPECIAL FIRE FIGHTING PROCEDURES: None UNUSUAL FIRE AND EXPLOSION HAZARDS: None SECTION V - REACTIVITY DATA STABILITY: Stable CONDITIONS TO AVOID: NA INCOMPATIBILITY (MATERIALS TO AVOID): Oxidizing agents and caustics HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Oxides of carbon if co-burned with flammable material HAZARDOUS POLYMERIZATION: Will not occur Deleted: 08/25/2005 Page 258 of 878 Page 258 of 878 Page 258 of 878 Page 258 of 878 ---PAGE BREAK--- Safe Set 7 Clear Spread Adhesive M A T E R I A L S A F E T Y D A T A S H E E T Page: 2 CONDITIONS TO AVOID: None Known SECTION VI - HEALTH HAZARD DATA ROUTES OF ENTRY: Inhalation and skin contact are expected to be the primary routes of occupational exposure with this product. This material is not expected to cause adverse effects when good industrial hygiene and safety practices are followed. HEALTH HAZARDS: None known SIGNS & OF EXPOSURE: None ACUTE EFFECTS OF OVEREXPOSURE: None known to occur CHRONIC EFFECTS OF OVER EXPOSURE: None known to occur CARCINOGENICITY: NTP: No known effect IARC MONOGRAPHS: No OSHA REGULATED: No MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: None known EMERGENCY AND FIRST AID PROCEDURES: Eyes - Flush with water for 15 minutes, lifting eyelids occasionally. Skin - Wash with soap and water; Ingestion - Do not induce vomiting. CALL PHYSICIAN IMMEDIATELY. Inhalation - Should inhalation problems occur, move victim to fresh air and aid in breathing if necessary. **IF IRRITATION SHOULD DEVELOP OR PERSIST FROM THE ABOVE EXPOSURES, CALL PHYSICIAN IMMEDIATELY.*** SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Scrape up excess and place in D.O.T. approved container. Clean with soapy water. HAZARDOUS SUBSTANCE SUPERFUND: NA WASTE DISPOSAL METHOD: Dispose of as per local, state and federal regulations. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed and store in cool dry place. OTHER PRECAUTIONS: NA SECTION VIII - CONTROL MEASURES RESPIRATORY PROTECTION: None required Page 259 of 878 Page 259 of 878 Page 259 of 878 Page 259 of 878 ---PAGE BREAK--- Safe Set 7 Clear Spread Adhesive M A T E R I A L S A F E T Y D A T A S H E E T Page: 3 VENTILATION: Local exhaust; Use with adequate ventilation. Open doors and windows to create cross ventilation during use and until adhesive dries. PROTECTIVE CLOTHES/GLOVES: Impervious gloves EYE PROTECTION: Safety goggles required OTHER PROTECTIVE CLOTHING OR EQUIPMENT: None required WORK/HYGENIC PRACTICES: Thorough washing of skin with soap and water before eating, or drinking. SECTION IX - SHIPPING INFORMATION D.O.T. PROPER SHIPPING NAME: Adhesives HAZARDOUS SUBSTANCE 49CFR CERCLA: NA HAZARD CODE: NA D.O.T. HAZARD CLASS: Not Regulated D.O.T. LABELS REQUIRED: NA D.O.T. PLACARDS REQUIRED: NA POISON CONSTITUENT: NA BILL OF LADING DESCRIPTION: Adhesives CC NO: NA UN/NA CODE: NA CHEMICAL EMERGENCY: CHEMTREC 24 HOURS: 1-[PHONE REDACTED] SECTION XI - OTHER REGULATORY INFOMATION TSCA INVENTORY STATUS: Listed on Inventory: Yes PROPOSITION 65: If your business resides in the state of California or if you supply products directly or indirectly into California, we are providing this information to you pursuant to the California Safe Drinking Water and Toxic Act of 1986 (commonly known as proposition 65). This law requires, in part, that "no person in the course of doing business shall knowingly and intentionally expose any individual to chemicals known to the state to cause cancer or reproductive toxicity without first exempt from the warning requirements "an exposure for which the person responsible can show that the exposure poses no significant risk..." (Section 25249.10). There may be small, perhaps undetectable amounts, of other naturally occuring chemicals that are known to the State of California to cause cancer, birth defects or other reporductive harm. This warning is provided in the absence of definitive testing to prove that these risks do not exist. These amounts are typical quantities and may be below the Proposition 65 level of concern, or could even be zero. Page 260 of 878 Page 260 of 878 Page 260 of 878 Page 260 of 878 ---PAGE BREAK--- Safe Set 7 Clear Spread Adhesive M A T E R I A L S A F E T Y D A T A S H E E T Page: 4 OSHA Standard 29CFR 1910.1200 requires that information be provided to employees regarding the hazards of chemicals by means of a hazard communication program including labeling, material safety data sheets, training and access to written records. We request that you and it is your legal duty to, make all information in this material safety data sheet available to your employees. The Following ingredients are considered to be classified as per OSHA hazardCommunication Standard (29CFR1910.1200): NA SECTION X - DISCLAIMER INFOMATION ***THE CRITERIA FOR LISTING COMPONENTS IN THE HAZARDOUS INGREDIENTS SECTIONS IS AS FOLLOWS: CARCINOGENS ARE LISTED WHEN PRESENT AT 0.1% OR GREATER; COMPONENTS WHICH ARE OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN PRESENT AT 1.0% OR GREATED. While this information and recommendations set forth herein are believed to be accurate as of the date hereof, TILE PERFECT MAKES NO WARRANTY WITH RESPECT HERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE THEREON. The information contained within the MSDS is considered propriety and is a trade secret. Unauthorized distribution or duplication of this information is prohibited. Page 261 of 878 Page 261 of 878 Page 261 of 878 Page 261 of 878 ---PAGE BREAK--- SECTION I: PRODUCT INFORMATION SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1% or greater, carcinogens at 0.1% or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. Comment: *This substance is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (SARA) and of 40 CFR 372. Spartan Chemical Company, Inc. Material Safety Data Sheet Product Name or Number (as it appears on label): Product Division: FOAMY Q&A Product Number: 3200; 3202 Janitorial Spartan Chemical Company, Inc. Product/Technical Information:1-(800)-537-8990 1110 Spartan Drive Medical Emergency:1-(888)-314-6171 (24 hours) Maumee OH 43537 Chemical Leak/Spil Emergency:CHEMTREC 1-(800) 424-9300 (24 hours) Shipping Description: Disinfectants, liquid, n.o.s. NFPA Ratings: HMIS Ratings: Health: 3 - Serious Health: *3 - Serious; Chronic Hazard Fire: 0 - Minimal Fire: 0 - Minimal Reactivity: 0 - Minimal Reactivity: 0 - Minimal Pers. Prot. Equip.: See Section VIII Chemical Name(s) % W CAS Registry No. Table Z- 1 - A NTP, IARC or OSHA Carcinogen TWA mg/m3 STEL mg/m 3 CELING mg/m3 Phosphoric acid 10-15 7664-38-2 1 3 (NIOSH) Not Established No Hydroxyacetic acid 1-5 79-14-1 Not Established Not Established Not Established No *2-Butoxyethanol 1-5 111-76-2 240 [skin] 96 Not Established Not Established No Alcohol ethoxylate 1-5 68439-46-3 Not Established Not Established Not Established No Cocoamidopropyl hydroxysultaine 1-5 70851-08-0 Not Established Not Established Not Established No Alkyl dimethyl benzyl ammonium chloride < 1 68424-85-1 Not Established Not Established Not Established No Page 262 of 878 Page 262 of 878 Page 262 of 878 Page 262 of 878 MSDS #3092 ---PAGE BREAK--- SECTION III: PHYSICAL DATA SECTION IV: FIRE & EXPLOSIVE HAZARD DATA SECTION V: HEALTH HAZARD DATA Emergency & First Aid Procedures: Boiling Point: 200-210 °F Vapor Pressure: Undetermined Vapor Density (AIR = Unknown Solubility in Water: Complete pH: < 2 Specific Gravity (H2O=1): 1.09 Evaporation Rate (but.ace.=1): <1 Percent Solid by Weight: 15-25 Physical State: Liquid Appearance & Odor: Purple liquid, Citrus/floral fragrance Flash Point: > 200°F Method Used: ASTM-D56 Flammable Limits: Not Established Flame Extension: N/A Extinguishing Media: Product does not support combustion. Use extinguishing media appropriate for surrounding fire. Special Fire Fighting Procedures: Wear NIOSH approved self-contained breathing apparatus and protective clothing. Cool fire- exposed containers with water spray. Unusual Fire & Explosive Hazards: Combustion products are toxic. Threshold Limit Value: Not Established Primary Routes of Entry: Inhalation, Skin Contact, Eyes & Oral Effects of Overexposure- Conditions to Avoid: CORROSIVE. CAUSES IRREVERSIBLE EYE DAMAGE AND SKIN BURNS: may include pain, redness, swelling and tissue damage. Harmful if absorbed through the skin. MAY BE FATAL IF SWALLOWED. may include nausea, vomiting, pain and diarrhea. INHALATION OF SPRAY MIST MAY CAUSE RESPIRATORY IRRITATION. Breathing spray mist may cause coughing and difficulty breathing. Contains 2-butoxyethanol which may cause central nervous system depression with such as headache; dizziness; nausea and drowsiness. Exposure to 2- butoxyethanol may cause blood cell; liver and kidney damage based on animal data. Do not get in eyes on skin or clothing. Do not swallow. Avoid breathing product mist. Wash thoroughly with soap and water after handling. Conditions Aggravated by Use: Use of this product may aggravate preexisting skin; eye and respiratory disorders including asthma and dermatitis. Eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses after the first 5 minutes then continue rinsing eye. Call a poison control center or doctor for treatment advice. Skin: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. Wash contaminated clothing before reuse. Ingestion: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Inhalation: In case of respiratory irritation; move person to fresh air. Get medical attention if irritation persists. Page 263 of 878 Page 263 of 878 Page 263 of 878 Page 263 of 878 ---PAGE BREAK--- SECTION VI: REACTIVITY DATA SECTION VII: SPILL OR LEAK PROCEDURES SECTION VIII: SPECIAL PROTECTION INFORMATION SECTION IX: SPECIAL PRECAUTIONS Stability: Stable Incompatible Materials: Strong alkalis; hypochlorites (bleach) ammonia; cyanides. Hazardous Decomposition Products: Heating to decomposition yields toxic fumes of phosphorus pentoxide. CO, CO2 H Hazardous Polymerization: Will Not Occur Steps to be Taken in Case Material is Released or Spilled: Small spills of one gallon or less may be flushed with plenty of water to sanitary sewer system (If permitted by local sewer regulations). Dike and contain large spills with inert material and transfer liquid to containers for recovery or disposal. Waste Disposal Method: Dispose of in compliance with all federal, state and local laws and regulations. Respiratory Protection: Not normally required when good general ventilation is provided. However, if exposure limits (see Section II) are exceeded or respiratory irritation occurs, use of a NIOSH approved respirator suitable for the use-conditions and chemicals in Section II should be considered. Ventilation: Provide good general ventilation. Local exhaust ventilation may be necessary for some operations. Protective Gloves(Specify Type): Rubber or neoprene gloves are recommended. Eye Protection(Specify Type): Splash goggles are recommended to prevent eye contact. Other Protective Equipment: Acid resistant aprons and boots are recommended where body or foot contact is likely. Eye wash stations and washing facilities should be readily accessible. See 29 CFR 1910.132-138. Precautions; Handling & Storing: Do not contaminate water, food or feed by storage or disposal. Keep from freezing. Other Precautions: Keep out of reach of children. © SCC 03/25/2008 Name: Ronald T. Cook Title: Manager, Regulatory Affairs FOAMY Q&A Effective Date: 03/25/2008 Supercedes: 06/01/2007 Ref: 29 CFR 1910.1200 (OSHA) Changes: Formula Revision This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. Page 264 of 878 Page 264 of 878 Page 264 of 878 Page 264 of 878 ---PAGE BREAK--- SAFETY DATA SHEET 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Formula 100 Ice-Remover 24 Hour Emergency CHEMTREC Number: [PHONE REDACTED] Product Description: A formulated ice removing compound. MSDS Number: M00364 EPA Registration Number: NA EPA Establishment Number: NA 2. HAZARDS IDENTIFICATION ***EMERGENCY OVERVIEW*** FIFRA Hazard Classification: Not Applicable Acute toxicity; oral: Category 4 Skin corrosion/irritation: Category 3 Serious eye damage/eye irritation: Category 2B Exclamation Mark WARNING Hazard Statements: H302 Harmful if swallowed. H316 Causes mild skin irritation. H320 Causes eye irritation. Precautionary Statements: P270 Do not eat, drink or smoke when using this product. P264 Wash hands thoroughly after handling. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredients CAS Number Weight ACGIH OSHA Calcium Chloride 10043-52-4 94-97% NE NE Sodium Chloride 7647-14-5 NE NE Potassium Chloride 7747-40-7 NE NE Strontium Chloride 10476-85-4 NE NE Water 7732-18-5 NE NE 4. FIRST AID MEASURES P337+P313 IF eye irritation persists: Get medical advice. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332+P313 IF SKIN irritation occurs: Get medical attention. P301+P312 IF SWALLOWED: call a POISON CENTER or physician if you feel unwell. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. 5. FIRE FIGHTING MEASURES Flashpoint(Method): None to boiling point Lower Explosive Limit(LEL): NA Upper Explosive Limit(UEL): NA Autoignition Temperature: NA Flammable Properties: None Expected Extinguishing Media: Carbon Dioxide, dry chemical, foam. Fire Fighting Instructions: Wear self-contained breathing apparatus and full protective clothing. Contains oil, water is not effective in fire fighting. 6. ACCIDENTAL RELEASE MEASURES Ventilate area. Halt spill at source, dike and contain spill. Flush with plenty of water to drain. Dispose of in accordance with Federal, State and Local Regulations regarding waste disposal. 7. HANDLING AND STORAGE P402 Store in dry place. P405 Store locked up. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering Controls: Use general or local ventilation to keep exposure levels below exposure limits. Personal Protective Equipment: Personal Protective Equipment: Respiratory: Use respirable fume respirator or air supplied respirator when soldering in confined space or where local exhaust or ventilation does not keep exposure Respiratory: Normal room ventilation is adequate. Use a NIOSH/MHSA approved respirator if exposure limits are exceeded. Eye: Wear approved safety glasses or goggles with unperforated eyeshields where splashing may occur. Skin: For repeated or prolonged contact, wear chemically impervious gloves such as Nitrile. Other: An emergency eyewash station or source of clean potable water should be available in case of accidental eye contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 265 of 878 Page 265 of 878 Page 265 of 878 Page 265 of 878 ---PAGE BREAK--- Appearance: White Odor: No Fragrance added Physical State: Solid pH: NA Solubility in Water: 100% Diluted pH: NA Boiling Point: NA Specific Gravity: NA Freezing Point: NA VOC Content: NA Melting Point: NA 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur. Conditions to Avoid: None expected Incompatibility: Do not mix with cationic disinfectant or sanitizers. Hazardous Decomposition Products: Carbon Dioxide, Carbon Monoxide 11. TOXICOLOGICAL INFORMATION This product contains no ingredient at 0.1% or greater that is listed as a human carcinogen. Hazardous Ingredients CAS Number LD50 LC50 Calcium Chloride 10043-52-4 NE NE Sodium Chloride 7647-14-5 3000 mg/kg (oral rat) NE Potassium Chloride 7747-40-7 NE NE Strontium Chloride 10476-85-4 NE NE Water 7732-18-5 NE NE 12. ECOLOGICAL INFORMATION This product is toxic to fish. 13. DISPOSAL CONSIDERATIONS P501 Dispose of container in accordance with all Federal, State and Local Regulations regarding waste disposal. 14. TRANSPORT INFORMATION DOT Shipping Data: Not Regulated Canadian TDG: Not Regulated For International Shipments by Air: NA For International Shipments by Vessel: NA 15. REGULATORY INFORMATION TSCA: All ingredients in this product are listed or exempt from listing on the TSCA Chemical Inventory. CEPA: All ingredients in this product are listed or exempt from listing on the Canadian DSL/NDSL. Proposition 65: This product contains no listed substances known to the State of California to cause cancer, birth defects or reproductive harm, at reportable levels under the statute. SARA 313: This product contains no toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To- Know Act of1986 (40CFR372). VOC: NA HMIS RATING: HEALTH = 1 FLAMMABILITY = 0 REACTIVITY = 0 PPE = B WHMIS RATING: Class D, Division 2B 16. OTHER INFORMATION NA = Not Available or Not Applicable NE = Not Established Read and follow all label directions and precautions before using the product. This product is intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF THE REACH OF CHILDREN. While we believe that the data contained herein is factual and the opinions expressed are those of qualified experts, the data are not to be taken as a warranty or representation for which the company assumes legal responsibility. They are offered solely for your consideration, investigation, and verification. Any use of these data and information must be determined by the user to be in accordance with applicable Federal, State, and Local Laws and regulations. Prepared On: 08/11/2015 Replaces: 12/01/2011 Page 266 of 878 Page 266 of 878 Page 266 of 878 Page 266 of 878 ---PAGE BREAK--- FICHE SIGNALÉTIQUE DE SÉCURITÉ 1. IDENTIFICATION DU PRODUIT CHIMIQUE ET DE LA SOCIÉTÉ Nom du produit : Formula 100 Ice-Remover Numéro d’urgence CHEMTREC 24 h/24 : [PHONE REDACTED] Description du produit : Produit dégivrant Numéro de la fiche signalétique de produit : M00364 EPA Registration Number : NA EPA Establishment Number : NA 2. IDENTIFICATION DES DANGERS ***VUE GÉNÉRALE D’URGENCE*** Point d’exclamation AVERTISSEMENT Mention de danger: H302 Nocif en cas d’ingestion. H316 Provoque une légère irritation de la peau. H320 Provoque une irritation des yeux/Lésions oculaires/irritation des yeux graves. Conseils de prudence: P270 Ne pas manger, boire ou fumer en manipulant ce produit. P264 Se laver soigneusement la peau après manutention. 3. COMPOSITION/INFORMATION SUR LES INGRÉDIENTS Ingrédients dangereux Numéro CAS Poids ACGIH OSHA Chlorure de calcium 10043-52-4 94-97% NE NE Chlorure de sodium 7647-14-5 NE NE Potassium Chloride 7747-40-7 NE NE Strontium Chloride 10476-85-4 NE NE Eau 7732-18-5 NE NE 4. PREMIERS SOINS P337+P313 Si l’irritation oculaire persiste: consulter un médecin. P305+P351+P338 EN CAS DE CONTACT AVEC LES YEUX: rincer avec précaution à l’eau pendant plusieurs minutes. Enlever les lentilles de contact si la victime en porte et si elles peuvent être facilement enlevées. Continuer à rincer. P332+P313 En cas d’irritation cutanée: consulter un médecin. P301+P312 EN CAS D’INGESTION : Appeler un CENTRE ANTIPOISON ou un médecin en cas de malaise. P301+P330+P331 EN CAS D’INGESTION : Rincer la bouche. NE PAS faire vomir. 5. EN CAS D’INCENDIE Point d’éclair : Aucun jusqu’au point d’ébullition. Limite d’explosivité inférieure (LIE) : NA Limite d’explosivité supérieure (LSE) : NA Température d’auto-inflammation : NA Propriétés d’inflammabilité : aucune présumée Moyens d’extinction : Dioxyde de carbone, poudre chimique, mousse extinctrice. Lutte contre l’incendie : Porter un appareil respiratoire autonome et une tenue protectrice intégrale. Contient de l’huile, l’eau n’est pas un moyen d’extinction efficace. 6. ÉMISSIONS ACCIDENTELLES Ventiler la zone. Interrompre le déversement à la source, l’endiguer et le contenir. Évacuer à grande eau. Éliminer conformément aux réglementations fédérale, provinciale et locale en vigueuren matière d’élimination des déchets 7. MANIPULATION ET CONSERVATION P402 Stocker dans un endroit sec. P405 Entreposer dans un endroit verrouillé. 8. EXPOSITION/PROTECTION INDIVIDUELLE Moyens techniques : Assurer une ventilation forcée adéquate pour maintenir l’exposition en deçà de la valeur limite d’exposition. Équipement de protection individuelle : Équipement de protection individuelle : Équipement de protection individuelle : respiratoire : Utiliser un appareil respiratoire pour vapeurs inahalables ou un appareil respiratoire à adduction d’air pour souder dans les espaces fermés ou dans les endroits où l’aspiration ou la ventilation locales ne suffisent pas à maintenir l’exposition en dessous de son seuil limite admissible. Respiratoire : La ventilation normale est suffisante. Si les limites d’exposition sont dépassées, utiliser un appareil respiratoire agréé NIOSH/MSHA. Oculaire : Porter des lunettes de protection homologuées munies d’écrans latéraux non perforés. Cutanée : En cas de contact répété ou prolongé, porter des gants de protection chimique. Autre : Un bassin oculaire d’urgence ou une source d’eau potable propre devrait être prêt à être utilisé en cas de contact oculaire accidentel. 9. PROPRIÉTÉS PHYSIQUES ET CH IMIQUES Aspect : Blanc Odeur : Pas de parfum ajouté État de la matière : Solide Concentrer pH : NA Solubilité dans l’eau : 100% Dilué pH : NA Page 267 of 878 Page 267 of 878 Page 267 of 878 Page 267 of 878 ---PAGE BREAK--- Contenu de VOC : NA Densité : NA Point de congélation/fusion : NA / NA 10. STABILITÉ ET RÉACTIVITÉ Stabilité : Stable Polymérisation dangereuse : Ne se produira pas. Conditions à éviter : Aucune connue Incompatibilité : Ne pas mélanger avec des produits assainissants ou désinfectants cationiques. Produits de décomposition dangereuse : Monoxyde de carbone, dioxyde de carbone. 11. INFORMATIONS TOXICOLOGIQUES Ce produit ne contient aucun ingrédient déclaré cancérogène humain à des teneurs supérieures ou égales à 0,1 Ingrédients dangereux Numéro CAS LD50 LC50 Chlorure de calcium 10043-52-4 NE NE Chlorure de sodium 7647-14-5 3000 mg/kg (oral rat) NE Potassium Chloride 7747-40-7 NE NE Strontium Chloride 10476-85-4 NE NE Eau 7732-18-5 NE NE 12. INFORMATIONS ÉCOLOGIQUES Ce produit est toxique pour les poissons. 13. DESTRUCTION P501 Éliminer le contenant conformément à tous les règlements fédéraux, d’État et locales en matière d’élimination des déchets. 14. TRANSPORT INFORMATION DE TRANSPORT D.O.T. : non réglementé. TMD AU CANADA : non réglementé. Pour les expéditions internationales par Air : NA Pour les expéditions internationales par Vessel : NA 15. INFORMATIONs RÉGLEMENTAIRES TSCA : Tous les ingrédients contenus dans ce produit figurent ou sont exempts de figurer sur l’inventaire du TSCA. CEPA : Tous les ingrédients contenus dans ce produit figurent ou sont exempts de figurer sur la LIS et la LES (Canada). Proposition 65 : Ce produit ne contient aucune substance chimique reconnus dans l’État de Californie pour causer le cancer, des malformations congénitales ou d’autres problèmesde reproduction. SARA 313 : Ne produit ne contient aucune substance chimique toxique devant être déclarée aux termes de la section 313 de la loi Emergency Planning andCommunity Right-To-Know Act de 1986 (40 CFR 372.65C). CLASSIFICATION HMIS : SANTÉ = 1 INFLAMMABILITÉ = 0 RÉACTIVITÉ = 0 EPS = B CLASSIFICATION SIMDUT : Classe D, Division 2B 16. AUTRES INFORMATIONS néant = Non disponible ou sans objet n.e. = Non établi Lire et suivre toutes les instructions et les précautions d’emploi figurant sur l’étiquette avant d’utiliser le produit. Ces produits sont réservés uniquement à l’usage industriel et par les collectivités. CES PRODUITS NE SONT PAS DESTINÉS À L’USAGE DOMESTIQUE OU À LA REVENTE. GARDER HORS DE LA PORTÉE DES ENFANTS. Bien qu’à notre avis les informations énoncées ci-dessus soient réelles et que le jugement exprimé soit celui d’experts qualifiés, elles ne doivent pas être considérées comme une garantie ou une déclaration pour lesquelles la société assume une responsabilité légale. Ces informations sont données uniquement pour examen, investigation et vérification. L’utilisation des ces informations doit être déterminée par l’utilisateur conformément à la réglementation et à la loi fédérales, d’État et régionales applicables. INFORMATIONS SUR LA SANTÉ ET LA SÉCURITÉ : (216) 861-7114 Date de Préparation: 08/11/2015 Remplace : 12/01/2011 Page 268 of 878 Page 268 of 878 Page 268 of 878 Page 268 of 878 ---PAGE BREAK--- PLANILLA DE DATOS DE SEGURIDAD 1. PRODUCTO QUÍMICO Y DATOS DE LA COMPAÑÍA Nombre del producto: Formula 100 Ice-Remover Núm. CHEMTREC las 24 horas: [PHONE REDACTED] Descripción del producto: Compuesto para eliminar hielo. Número MSDS: M00364 EPA Registration Number: NA EPA Establishment Number: NA 2. ENUMERACIÓN DE PELIGROS ***DESCRIPCIÓN GENERAL DE LAS SITUACIONES DE EMERGENCIA*** Signo de exclamación ADVERTENCIA H302 Nocivo en caso de ingestión. H316 Causa leve corrosión/irritación en la piel. H320 Causa irritacion en los ojos/Serio daño en los ojos/irritación en los ojos. P270 No comer, beber ni fumar durante su utilización. P264 Lavar la piel meticulosamente después de la manipulación. 3. COMPOSICIÓN/INFORMACIÓN SOBRE LOS COMPONENTES Componentes peligrosos Número CAS Peso ACGIH OSHA Cloruro de calico 10043-52-4 94-97% NE NE Cloruro de sodio 7647-14-5 NE NE Potassium Chloride 7747-40-7 NE NE Strontium Chloride 10476-85-4 NE NE Agua 7732-18-5 NE NE 4. MEDIDAS DE PRIMEROS AUXILIOS P337+P313 Si persiste la irritación ocular: Consultar a un médico. P305+P351+P338 EN CASO DE CONTACTO CON LOS OJOS: Aclarar cuidadosamente con agua durante varios minutos. Quitar las lentes de contacto, si lleva y resulta fácil. Seguir aclarando. P332+P313 En caso de irritación cutánea: Consultar a un médico. P301+P312 EN CASO DE INGESTIÓN: llamar a un CENTRO DE TOXICOLOGÍA o médico SI se siente indispuesto. P301+P330+P331 EN CASO DE INGESTIÓN: Limpie la boca. NO provoque el vómito. 5. MEDIDAS PARA COMBATIR INCENDIOS Pto. inflamabilidad: Ninguno para el punto de ebullición Límite explosivo inferior (LEL): NA Límite explosivo superior (UEL): NA Temperatura de autoignición: NA Inflamabilidad: No se espera ninguna. Medio extinguidor: Dióxido de carbono, productos químicos en polvo, espuma. Instrucciones para combatir el fuego: Use un aparato autónomo para respirar e indumentaria de protección. Por contener aceite, el agua no resultará eficaz para combatir incendios. 6. MEDIDAS EN CASO DE DERRAME ACCIDENTAL Ventile el área. Coloque una barrera física y contenga el derrame en el propio sitio de origen. Limpie el derrame con agua en abundancia y vierta todo por el drenaje. Obedezca todos losreglamentos federales, estatales y locales relativos a la disposición final de residuos. 7. MANIPULACIÓN Y ALMACENAMIENTO P402 Almacenar en un lugar seco. P405 Almacenar bajo llave. 8. CONTROL DE EXPOSICIÓN/PROTECCIÓN PERSONAL Controles de ingeniería: Proveer suficiente ventilación mecánica para mantener la exposición por debajo del límite de concentración máxima (Threshold Limit Value, TLV). Equipo de protección personal: Equipo de protección personal: Equipo de protección personal: Respiratorio: Cuando suelde en recintos pequeños o cuando la ventilación local no mantenga la exposición por debajo del TLV, utilice una mascarilla que proteja contra las emanaciones o un respirador con suministro de oxígeno. Respiratorio: Si el límite de exposición en el lugar de trabajo es excedido, se aconseja el uso de un respirador de aire ante la ausencia de control ambiental. Ojos: Use gafas protectoras o gafas con protección lateral sin perforaciones aprobadas. Piel: Si el contacto fuera prolongado o repetido, use guantes resistentes a productos químicos. Otros: Una estación de lavaojos de emergencia o una fuente de agua potable limpia debe estar disponible en caso de contacto accidental con los ojos. 9. PROPIEDADES FÍSICAS Y QUÍMICAS Aspecto: Blanco Olor: Sin olor adicional Estado de agregación: Sólido Concentrarse pH: NA Solubilidad en agua: 100% Diluido pH: NA Contenido de VOC: NA Peso específico: NA Punto de congelación/fusión: NA / NA Page 269 of 878 Page 269 of 878 Page 269 of 878 Page 269 of 878 ---PAGE BREAK--- 10. ESTABILIDAD Y REACTIVIDAD Estabilidad: Estable Polimerización peligrosa: No ocurrirá. Condiciones a evitar: Agentes oxidantes. Incompatibilidad: No mezcle con desinfectantes o productos de limpieza catiónicos. Productos de descomposición peligrosos: Monóxido de carbono, Dióxido de carbono. 11. INFORMACIÓN TOXICOLÓGICA Este producto no contiene ningún componente en 0.1% o más del que se señale como un carcinógeno humano. Componentes peligrosos Número CAS LD50 LC50 Cloruro de calico 10043-52-4 NE NE Cloruro de sodio 7647-14-5 3000 mg/kg (oral rat) NE Potassium Chloride 7747-40-7 NE NE Strontium Chloride 10476-85-4 NE NE Agua 7732-18-5 NE NE 12. INFORMACIÓN ECOLÓGICA Este producto es tóxico para los peces. 13. SUGERENCIAS PARA SU DISPOSICIÓN FINAL P501 Elimine el recipiente en conformidad con todas las regulaciones federales, estatales y locales relacionadas con la eliminación de residuos. 14. INFORMACIÓN SOBRE TRANSPORTE DATOS DE EMBARQUE SEGÚN EL DOT (Ministerio de Transporte de los EE.UU.): No se ha regulado. TDG CANADIENSE: Producto no regulado. No se ha regulado. Para los envíos internacionales de Air: NA Para los envíos internacionales de Vessel: NA 15. INFORMACIÓN SOBRE REGLAMENTOS TSCA: Todos los químicos de este producto están catalogados o están exentos de ser catalogados en el inventario químico de la Ley de Control de Sustancias Tóxicas(Toxic Substances Control Act, TSCA). CEPA: Todos los químicos de este producto están catalogados o están exentos de ser catalogados en el DSL/NDSL canadiense. Propuesta 65: Este producto no contiene sustancias registradas en el Estado de California como causante de cáncer, defectos de nacimiento u otros daños reproductivos. SARA 313: Este producto no contiene sustancias tóxicas sujetas a los requisitos de información del Artículo 313 de la ley de 1986 (40 CFR 372.65) de Planeamiento anteemergencias y Derecho a Estar Informado de la Comunidad. CLASIFICACIÓN HMIS: SALUD = 1 INFLAMABILIDAD = 0 REACTIVIDAD = 0 EQUIPO DE PROTECCIÓN PERSONAL= B CLASIFICACIÓN WHMIS: Clase D, División 2B 16. OTRA INFORMACIÓN NA = No disponible o No se aplica NE = No se ha establecido Antes de utilizar este producto, lea y obedezca todas las instrucciones y precauciones. Este producto fue formulado para utilizarse únicamente en el ámbito industrial e institucional. NO ES PARA REVENTA NI PARA USO EN EL ÁMBITO HOGAREÑO. MANTENGA FUERA DEL ALCANCE DE LOS NIÑOS. Si bien se considera que los datos contenidos en esta planilla son correctos y las opiniones expresadas son las de calificados expertos, los datos no deberán considerarse como garantía ni como declaración por las que la compañía asume responsabilidad legal alguna. Estos datos se brindan sólo para evaluación, investigación y verificación por parte del cliente. El usuario es quien deberá determinar si cualquier uso que se dé a estos datos e información está de acuerdo con las leyes y reglamentos federales, estatales y locales aplicables. INFORMACIÓN DE SEGURIDAD Y SALUD: (216) 861-7114 Preparado Encendido: 08/11/2015 Reemplaza: 12/01/2011 Page 270 of 878 Page 270 of 878 Page 270 of 878 Page 270 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET (COMPLIES WITH 29CFR 1910.1200) SECTION I - CHEMICAL PRODUCT & COMPANY IDENTIFICATION Identity (As Used on Label and List): Formula 340 Product Class: General purpose water-based cleaner/degreaser Emergency Telephone Number: [PHONE REDACTED] Telephone Number for Information: [PHONE REDACTED] Manufacturer's Name and Address: Multi-Clean® 600 Cardigan Road Shoreview, MN 55126 SECTION II - COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Components (Specific Chemical Identity): Chemical Common Name(s) % A Sodium Metasilicate Pentahydrate 1 - 5 CAS #6834-92-0 B Alcohol Ethoxylates 1 - 5 CAS #34398-01-1 C Sodium Xylene Sulfonate 1 - 5 CAS #1300-72-7 D Water 60 - 100 CAS #7732-18-5 SECTION III - HAZARDS IDENTIFICATION Emergency Overview Appearance and Odor: Orange liquid, mild odor. Primary Hazards: Corrosive Potential Health Hazards Route(s) of Entry: Skin Absorption: Ingestion: X Inhalation: Eye: May cause chemical burns on contact. Skin: May cause chemical burns on contact. Ingestion: May be harmful if swallowed. Inhalation: No hazardous vapors. Signs and of Exposure: Eye Contact: Possible burning, tearing, redness and corneal damage. Skin Contact: Possible slippery feeling, redness, swelling and burns. may be delayed. Carcinogenicity: NTP? No IARC Monographs? No OSHA Regulated? No Target Organ Skin and eyes. Medical Conditions Generally Aggravated by Exposure: N. Av. Health Hazards, Chronic: N. Av. SECTION IV - FIRST AID MEASURES Emergency and First Aid Procedures: If Swallowed: Do not induce vomiting. If person can swallow, give several glasses of water. Obtain immediate medical attention. Eye Contact: Flush eyes with running water for at least 15 minutes. If irritation persists, obtain medical attention. Skin Contact: Flush thoroughly with cool water. Remove and wash contaminated clothing before reuse. Sources Used: Raw material data, general toxicology from the trade for similar products. SECTION V - FIRE FIGHTING MEASURES Flammability: No Autoignition Temperature: N. Ap. Flash Point (method used): None Flammable Limits: N. Ap. LEL UEL Extinguishing Media N. Ap. Water? Foam? Water Fog? Alcohol Foam? CO2? Dry Chemical? Vaporizing Liquid? Other? Special Fire Fighting Procedures: N. Ap. Unusual Fire and Explosion Hazards: N. Av. TDG Flammability Classification: Non-flammable Sensitivity to Mechanical Impact: None Sensitivity to Static Discharge: None SECTION VI - ACCIDENTAL RELEASE MEASURES Steps to be Taken in Case Material is Released or Spilled: Dike and contain spill with inert material (sand, earth, etc). Collect spill with mop, absorbent material (example: floor-dri) or vacuum. Thoroughly rinse affected area with water. SECTION VII - HANDLING AND STORAGE Precautions to be Taken in Handling and Storing: Normal care in handling and storage. Other Precautions: Keep out of reach of children. Keep from freezing. SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION Respiratory Protection (Specify Types): Not required Ventilation: Local Exhaust: Not required Special: Not required Mechanical (General): Normal good ventilation sufficient. Other: Not required Protective Gloves: Natural rubber or Eye Protection: Approved safety goggles or glasses. Footwear: Not required Other Protective Clothing or Equipment: Not required Work/Hygienic Practices: Do not contaminate food or beverages with cleaning chemicals. SECTION IX - PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: Approximately 212°F pH: > 13 Specific Gravity (H20) = 1: 1.06 Odor Threshold: N. Av. Vapor Density (Air = < 1 % Volatile: 60 - 100 Evaporation Rate (Butyl Acetate = N. Av. Oil/Water Distribution Solubility in Water: Complete Coefficient: N. Av. Vapor Pressure (MM HG): N. Av. Melting Point: N. Ap. SECTION X - STABILITY AND REACTIVITY Stability: Unstable: Stable: X Conditions to Avoid: N. Ap. Incompatibility (materials to avoid): N. Av. Hazardous Decomposition or By-products: N. Av. Hazardous Polymerization: May occur: Will not occur: X Conditions to Avoid: N. Ap. SECTION XI - TOXICOLOGICAL INFORMATION Chemical OSHA PEL ACGIH TLV Recom. LD50 LC50 A N. Ap. N. Ap. 2 mg/M3 800 mg/kg N. Av. B None None N. Av. 0.7 – 1.7 gm/kg N. Av. (rat, oral) C None None N. Av. 4,000 mg/kg N. Av. (rat, oral) D None None N. Av. N. Av. N. Av Teratogen, Mutagen, Reproductive Toxin Status: No Toxicologically Synergistic Products: N. Av. SECTION XII - ECOLOGICAL INFORMATION Ecotoxicological Information: N. Av. Biodegradation Properties: N. Av. SECTION XIII - DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose of spilled material in accordance with local, state and federal regulations. Waste from normal cleaning procedures may be sewered, depending on the materials and/or contaminates being cleaned as well as state, federal and local sewer commission regulations. RCRA Hazard Class: DOO2, characteristic corrosive. SECTION XIV - TRANSPORT INFORMATION Shipping Classification: Corrosive liquid, basic inorganic, N.O.S. (Containing sodium metasilicate), Class 8 UN Number: 3266 Packing Group: II SECTION XV - PREPARATION DATA Prepared By: Ron Camp Telephone Number: [PHONE REDACTED] Date: 4-12 SECTION XVI - REGULATORY INFORMATION US Federal Regulations TSCA Status: All ingredients listed. CERCLA Reportable Quality: N. Av. SARA Title III Section 302 Extremely Hazardous Chemicals: None Section 311/312 Hazard Category: Immediate health hazard Section 313 Toxic Chemicals: None State Regulations International Regulations WHMIS Controlled Product Hazard Class: E SECTION XVII - OTHER INFORMATION None N. Ap. - Not Applicable; N.Av. - Not Available NFPA SYSTEM A. Health Hazard A. Fire Hazard A. Reactivity Hazard THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE, HOWEVER NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. MINUTEMAN INTERNATIONAL, INC. ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE TO VENDEES, USERS OR THIRD PARTIES CAUSED BY THE MATERIAL. SUCH VENDEES OR USERS ASSUME ALL RISKS ASSOCIATED WITH THE USE OF THE MATERIAL. Page 271 of 878 Page 271 of 878 Page 271 of 878 Page 271 of 878 ---PAGE BREAK--- The Clorox Company 1221 Broadway Oakland, CA 94612 Tel. (510) 271-7000 Material Safety Data Sheet I Product: FORMULA 409 ALL PURPOSE CLEANER Description: GREEN LIQUID Other Designations Distributor Emergency Telephone Nos. All Purpose Cleaner Misty Breeze Fragrance Lemon Fresh Fragrance Clorox Sales Company 1221 Broadway Oakland, CA 94612 For Medical Emergencies call: (800) 446-1014 For Transportation Emergencies Chemtrac (800) 424-9300 II Health Hazard Data III Hazardous Ingredients CAUTION: EYE IRRITANT. Avoid eye and prolonged skin contact. Do Not ingest FIRST AID: EYE CONTACT: Immediately flush eyes with plenty of water. If irritation persists, see a doctor. SKIN CONTACT: Wash with water. Seek medical attention if irritation develops or persists. INGESTION: Drink a glass full of water. Call Physician. Do not induce vomiting. Do not give anything by mouth to an unconscious or convulsing person. INHALATION: If breathing problems develop remove to fresh air. Seek medical attention if respiratory irritation develops or breathing becomes difficult. KEEP OUT OF REACH OF CHILDREN Ingredients Concentration Worker Exposure Limit Alkyl (C1240%; C1450% 0.3% Not Established C1610%) dimethyl benzyl Ammonium chloride CAS# 68424-85-1 Ethylene Glycol 0.5-5% 25 ppm TLV-TWA Monobutyl Ether 25 ppm PEL CAS # 111-76-2 Substance can be absorbed through the skin and may contribute to overall exposure. None of the ingredients in this product are on the IARC, NTP or OSHA carcinogen lists. TLV - TWA - Threshold Limit Value - Time Weighted Average. Source: ACGIH 1985-86. PEL - Permissible Exposure Limit. Source: OSHA IV Special Protection and Precautions V Transportation and Regulatory Data Hygienic Practices: Wear safety glasses. With repeated or prolonged use, wear gloves. Engineering Controls: Use general ventilation to minimize exposure to vapor or mist. Work Practices: Minimize skin contact and inhalation of vapor or mist. Not recommended for use on soft vinyl, varnishes or aluminum. If sprayed on these surfaces, rinse and wipe dry immediately. U.S. DOT Hazard Class: Not restricted U.S. DOT Proper Shipping Name:.Not restricted. EPA - SARA Title III/CERCLA: Bottled product is not reportable under Sections 311/312; contains chemicals regulated under Section 313 (ethylene oxide = trace, glycol ethers < and contains chemicals (glycol ethers < ethylenediaminetetracetic acid < 1.0%, ethylene oxide = trace, and sodium hydroxide < 0.5%) which are regulated under Section 304/CERCLA. TSCA Status: All components of this product are on the TSCA Inventory VOC Content: 48 g/L (EPA Method 24) VI Spill Procedures/Waste Disposal VII Reactivity Data Spill Procedures: Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed-down material. Waste Disposal: Dispose of in accordance with all applicable federal, state, and local regulations. Stable under normal use and storage conditions. VIII Fire and Explosion Data IX Physical Data Flash Point: >200F Fire Extinguishing Agents: Foam, Dry Chemical, Water, CO2 Unusual Fire and Explosion Hazards: Products of combustion are toxic Solubility in complete Specific Gravity 1963, 1991 THE CLOROX COMPANY DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH DATE PREPARED 3/01 Page 272 of 878 Page 272 of 878 Page 272 of 878 Page 272 of 878 ---PAGE BREAK--- Page 273 of 878 Page 273 of 878 Page 273 of 878 Page 273 of 878 ---PAGE BREAK--- Page 274 of 878 Page 274 of 878 Page 274 of 878 Page 274 of 878 ---PAGE BREAK--- Page 275 of 878 Page 275 of 878 Page 275 of 878 Page 275 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Glance NA Version Number: 2 Preparation date: 2007-07-25 Personal protective equipment NFPA HMIS Reactivity 0 None / Aucune / Ninguno Health Fire Hazard 1 0 0 1 0 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Glance NA MSDS MS0200011 Product Code: 3361936, 3172641 Recommended use: Cleaning product. This product is intended to be diluted prior to use. Emergency telephone number: 1-[PHONE REDACTED] (Prosar); 1-[PHONE REDACTED] (Int'l Prosar); 01-[PHONE REDACTED] (México) 2. HAZARDS IDENTIFICATION Principle routes of exposure: Eye contact. Skin contact. Inhalation. Eye contact: May be mildly irritating to eyes. Skin contact: May be mildly irritating to skin. Inhalation: None known. Ingestion: None known. 3. COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS COMPONENTS Ingredient(s) CAS # Weight % LD50 Oral - Rat LD50 Dermal - Rabbit LC50 Inhalation - Rat Sodium lauryl sulfate 151-21-3 1 - 5% Not available Not available Not available Ethyl alcohol 64-17-5 0.1 - 1.5% Not available Not available Not available 4. FIRST AID MEASURES Eye contact: Flush immediately with plenty of water. Get medical attention if irritation occurs. Skin contact: Flush immediately with plenty of water. Get medical attention if irritation occurs. Inhalation: No specific first aid measures are required. Ingestion: No specific first aid measures are required. Aggravated Medical Conditions: None known. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: The product is not flammable. Extinguish fire using agent suitable for surrounding fire. Specific hazards: None known. Unusual hazards: None known. Specific methods: No special methods required Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: No information available Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-0902 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.johnsondiversey.com Glance NA Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] 1 of 3 EMERGENCY OVERVIEW CAUTION. MAY BE MILDLY IRRITATING TO EYES. MAY BE MILDLY IRRITATING TO SKIN. Page 276 of 878 Page 276 of 878 Page 276 of 878 Page 276 of 878 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Use personal protective equipment Environmental precautions and clean-up methods: Clean up affected area with water. 7. HANDLING AND STORAGE Handling: Avoid contact with skin and eyes. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep closed in a dry, cool and well-ventilated place. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: No special ventilation requirements. General room ventilation is adequate. Personal Protective Equipment Eye protection: No special requirements under normal use conditions. Hand protection: No special requirements under normal use conditions Skin and body protection: No special requirements under normal use conditions. Respiratory protection: No special requirements under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Ingredient(s) CAS # ACGIH OSHA Mexico Ethyl alcohol 64-17-5 1000 ppm (TWA) 1000 ppm (TWA) 1900 mg/m3 (TWA) 1000 ppm (TWA) 1900 mg/m3 (TWA) 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY Stability: The product is stable Polymerization: Hazardous polymerization does not occur Hazardous decomposition products: None reasonably foreseeable. Materials to avoid: None known. Conditions to avoid: Do not freeze. 11. TOXICOLOGICAL INFORMATION Acute toxicity: Oral LD50 estimated to be greater than 5000 mg/kg Dermal LD50 estimated to be > 2000 mg/kg Component Information: See Section 3 Chronic toxicity: None known Specific effects Carcinogenic effects: None known Mutagenic effects: None known Reproductive toxicity: None known Target organ effects: None known HAZARDOUS COMPONENTS Ingredient(s) CAS # NTP IARC OSHA Ethyl alcohol 64-17-5 X 1 X Bulk density: Density: 8.35 Appearance: Decomposition temperature: Not determined Aqueous solution VOC: 0.25 No information available Autoignition temperature: No information available Vapor density: Flash point: >200°F >93.3°C No information available Partition coefficient (n-octanol/water): No information available Liquid Solubility: Soluble Color: Solubility in other solvents: No information available Blue Viscosity: No information available pH: Elemental Phosphorus: 0.0 %P Evaporation Rate No information available >7.0 7.0 Odor: Characteristic Physical State: Boiling point/range: Not determined Dilution pH: Specific gravity: .999 No information available. Glance NA 2 of 3 Melting point/range: Not determined Page 277 of 878 Page 277 of 878 Page 277 of 878 Page 277 of 878 ---PAGE BREAK--- 12. ECOLOGICAL INFORMATION Environmental Information: No data available 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Dispose of according to all federal, state and local applicable regulations 14. TRANSPORT INFORMATION DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), Australia (AICS), Korea (ECL), Japan (ENCS), Philippines (PICCS), China (IECSC). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 STATE RIGHT TO KNOW Ingredient(s) CAS # MARTK: PARTK: RIRTK: Water 7732-18-5 - - - - Sodium lauryl sulfate 151-21-3 - - - - Alcohol ethoxylates 68439-46-3 - - - - Ethyl alcohol 64-17-5 X X X X Sodium lauryl ether sulfate 9004-82-4 - - - - CERCLA/ SARA CAA HAP/CAA ODS/CWA Priority Pollutants: None SARA 311/312 Hazard Categories Immediate: X Delayed: - Fire: - Reactivity: - Sudden Release of Pressure: - Canada WHMIS hazard class: Non-controlled. Ingredient(s) CAS # NPRI Ethyl alcohol 64-17-5 X 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: None Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 3 of 3 Glance NA Page 278 of 878 Page 278 of 878 Page 278 of 878 Page 278 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET GLANCE SC (SUPER CONCENTRATE) Version Number: 1 Preparation date: 2006-05-15 Personal protective equipment NFPA HMIS Reactivity 0 Health Fire Hazard 3 0 0 3 0 1. PRODUCT AND COMPANY IDENTIFICATION Product name: GLANCE SC (SUPER CONCENTRATE) MSDS 114700004 Product code: 114700X, 114700004, 04701, 04305, 04459 Recommended use: Cleaning product. This product is intended to be diluted prior to use. Emergency telephone number: 1-[PHONE REDACTED] (Prosar); 1-[PHONE REDACTED] (Int'l Prosar); 01-[PHONE REDACTED] (México) 2. HAZARDS IDENTIFICATION Principle routes of exposure: Eye contact. Skin contact. Inhalation. Eye contact: Corrosive. Causes permanent eye damage, including blindness. Skin contact: Corrosive. Causes permanent damage . Inhalation: May cause irritation and corrosive effects to nose, throat and respiratory tract. Ingestion: Corrosive. Causes burns to mouth, throat and stomach. 3. COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS COMPONENTS Ingredient(s) CAS # Weight % LD50 Oral - Rat LD50 Dermal - Rabbit LC50 Inhalation - Rat Sodium lauryl sulfate 151-21-3 1 - 5% = 1288 mg/kg Not available > 3900 mg/m3 (1h) Ammonium hydroxide 1336-21-6 1 - 5% = 350 mg/kg Not available Not available 2-butoxyethanol 111-76-2 20 - 30% = 470 mg/kg = 220 mg/kg = 2.21 mg/L (4h) = 450 ppm (4h) 4. FIRST AID MEASURES Eye contact: Immediately flush eyes with running water for at least 15-20 minutes, keeping eyelids open. Get medical attention immediately. Skin contact: Flush immediately with plenty of water for at least 15-20 minutes. Get medical attention immediately. Inhalation: If breathing is affected, remove to fresh air. Get medical attention immediately. Ingestion: If swallowed, give a cupful of water or milk. THEN IMMEDIATELY CONTACT A PHYSICIAN OR POISON CENTER. DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Aggravated Medical Conditions: Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, etc., may be more susceptible to irritating effects. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: The product is not flammable. Extinguish fire using agent suitable for surrounding fire . Specific hazards: None known. Unusual hazards: Corrosive material (See sections 8 and 10). Specific methods: No special methods required EMERGENCY OVERVIEW DANGER. CORROSIVE. CAUSES SKIN AND EYE BURNS. HARMFUL OR FATAL IF SWALLOWED. Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-0902 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.johnsondiversey.com GLANCE SC (SUPER CONCENTRATE) Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] 1 of 4 Page 279 of 878 Page 279 of 878 Page 279 of 878 Page 279 of 878 ---PAGE BREAK--- 5. FIRE-FIGHTING MEASURES Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: No information available 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Put on appropriate personal protective equipment (see Section Environmental precautions and clean-up methods: Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use a water rinse for final clean-up. 7. HANDLING AND STORAGE Handling: Avoid contact with skin, eyes and clothing. Do not taste or swallow. Avoid breathing vapors or mists. Use only with adequate ventilation. Remove and wash contaminated clothing and footwear before re-use. Wash thoroughly after handling. Product residue may remain on/in empty containers. All precautions for handling the product must be used in handling the empty container and residue. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep closed in a dry, cool and well-ventilated place. KEEP OUT OF THE REACH OF CHILDREN. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: Good general ventilation should be sufficient to control airborne levels. Respiratory protection is not required if good ventilation is maintained. Personal Protective Equipment Eye protection: Chemical splash goggles. Hand protection: Chemical resistant gloves Skin and body protection: Protective footwear. If major exposure is possible, wear suitable protective clothing and footwear. Respiratory protection: In case of insufficient ventilation wear suitable respiratory equipment. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice Ingredient(s) CAS # ACGIH OSHA Mexico 2-butoxyethanol 111-76-2 20 ppm (TWA) Skin 240 mg/m3 (TWA) 50 ppm (TWA) 75 ppm (STEL) 360 mg/m3 (STEL) 120 mg/m3 (TWA) 26 ppm (TWA) 9. PHYSICAL AND CHEMICAL PROPERTIES * - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 10. STABILITY AND REACTIVITY Stability: The product is stable. Polymerization: Hazardous polymerization does not occur. Hazardous decomposition products: None reasonably foreseeable. Materials to avoid: Strong oxidising agents. Do not mix with any other product or chemical. Conditions to avoid: Do not freeze. 11. TOXICOLOGICAL INFORMATION Acute toxicity Oral LD50 estimated to be between 500 - 5000 mg/kg Component Information: See Section 3 Color: Solubility in other solvents: No information available Blue Viscosity: No information available pH: Elemental Phosphorous: 0 %P Evaporation Rate No information available 11.5 Odor: Ammoniacal Physical State: Boiling point/range: Not determined Dilution pH: Specific gravity: 0.995 No information available. Melting point/range: Not determined Bulk density: Density: 8.3 lbs/gal Appearance: Decomposition temperature: Not determined Aqueous solution VOC: 20.0% * No information available Autoignition temperature: No information available Vapor density: Flash point: >200 >93.3 No information available Partition coefficient (n-octanol/water): No information available GLANCE SC (SUPER CONCENTRATE) Liquid 2 of 4 Solubility: Soluble Page 280 of 878 Page 280 of 878 Page 280 of 878 Page 280 of 878 ---PAGE BREAK--- 11. TOXICOLOGICAL INFORMATION Chronic toxicity: None known Specific effects Carcinogenic effects: None known Mutagenic effects: None known Reproductive toxicity: None known Target organ effects: None known 12. ECOLOGICAL INFORMATION Environmental Information: No data available 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Dispose of according to all federal, state and local applicable regulations 14. TRANSPORT INFORMATION DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 STATE RIGHT TO KNOW Ingredient(s) CAS # MARTK: PARTK: RIRTK: Sodium lauryl sulfate 151-21-3 - - - - Sodium xylene sulfonate 1300-72-7 - - - - Ammonium hydroxide 1336-21-6 X X - - 2-butoxyethanol 111-76-2 X X X X Water 7732-18-5 - - - - CERCLA/ SARA Ingredient(s) CAS # Weight % CERCLA/SARA RQ (lbs) Section 302 TPQ (lbs) Section 313 Ammonium hydroxide 1336-21-6 1 - 5% 1000 2-butoxyethanol 111-76-2 20 - 30% X Ingredient(s) CAA HAP CAA ODS CWA Priority Pollutants 2-butoxyethanol X SARA 311/312 Hazard Categories Immediate: Y Delayed: N Fire: N Reactivity: N Sudden Release of Pressure: N Canada WHMIS hazard class: E Corrosive material . Ingredient(s) CAS # NPRI 2-butoxyethanol 111-76-2 X 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC 3 of 4 GLANCE SC (SUPER CONCENTRATE) Page 281 of 878 Page 281 of 878 Page 281 of 878 Page 281 of 878 ---PAGE BREAK--- 16. OTHER INFORMATION Additional advice: None Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 4 of 4 GLANCE SC (SUPER CONCENTRATE) Page 282 of 878 Page 282 of 878 Page 282 of 878 Page 282 of 878 ---PAGE BREAK--- Date: 6 October 2009 Supercedes: 19 December 2007 MATERIAL SAFETY DATA SHEET IN CASE OF EMERGENCY CALL CHEMTREC AT 1-[PHONE REDACTED] 1. PRODUCT IDENTIFICATION AND COMPANY IDENTIFICATION: Product Name: GOJO® E1 Foam Handwash Company Name & Address: GOJO Industries, Inc. One GOJO Plaza, Suite 500 Akron, OH 44311 Emergency Phone: 1-[PHONE REDACTED] CHEMTREC Non-Emergency Phone: (330) 255-6000 MSDS Request Phone: (330) 255-6000 x8804 2. INFORMATION ON INGREDIENTS: HAZARDOUS INGREDIENTS CAS NUMBER OSHA PEL ACGIH TLV % RANGE None Other ingredient(s) with notification requirements: CAS NUMBER List None 3. HAZARDS IDENTIFICATION: EMERGENCY OVERVIEW When used according to instructions, the product applicable to this MSDS is safe and presents no immediate or long-term health hazard. However, abnormal entry routes, such as gross ingestion, may require immediate medical attention. Potential Health Effects: HMIS: Health 1 Flammability 0 Reactivity 0 Personal Protection None Eye Contact: May cause eye irritation. Skin Contact: No irritation or reaction expected. Inhalation: Not applicable. Ingestion: May cause upset stomach, nausea (Abnormal entry route). Carcinogenicity: Not listed as a carcinogen by NTP, IARC, OSHA or ACGIH. 4. FIRST AID MEASURES: Eye Contact: Do not rub eyes. Flush eyes thoroughly with water for 15 minutes. If condition worsens or irritation persists, contact physician. Skin Contact: Not applicable. Inhalation: Not applicable. Ingestion: Do not induce vomiting. Contact a physician or Poison Control Center. Page 283 of 878 Page 283 of 878 Page 283 of 878 Page 283 of 878 ---PAGE BREAK--- GOJO® E1 FOAM HANDWASH Page 2 of 2 Document#: 5200-506 5. FIRE FIGHTING MEASURES: NFPA: Health 1 Fire 0 Reactivity 0 Flashpoint °F/°C (PMCC method): Not applicable. Unusual Fire and Explosion Hazards: None known. Special Fire Fighting Procedures: None known. Extinguishing Media: X Water Fog X Alcohol Foam X CO2 X Dry Chemical Other 6. ACCIDENTAL RELEASE MEASURES: No special requirements. Water clean up and rinse. CAUTION – WILL CAUSE SLIPPERY SURFACES. 7. HANDLING AND STORAGE: Store at normal room temperature away from reach of small children. Keep containers sealed. Use older containers first. Avoid freezing conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION: Eye Protection: None required under normal conditions. Skin Protection: None required under normal conditions. Respiratory Protection: None required under normal conditions. Ventilation: None required under normal conditions. Protective Equipment or Clothing: None required under normal conditions. 9. PHYSICAL AND CHEMICAL PROPERTIES: Appearance and Odor Colorless to yellow liquid, fragrance free pH (undiluted): 4.8 - 7.5 VOC , <0.5% 10. STABILITY AND REACTIVITY: Stable/Non reactive product. 11. TOXICOLOGICAL INFORMATION: No acute or chronic toxic effects expected when used according to directions. 12. ECOLOGICAL CONSIDERATIONS: No ecological or special considerations when used according to directions. Not considered environmentally harmful from normal dilution, expected usage and typical drainage to sewers, septic systems and treatment plants. 13. DISPOSAL CONSIDERATIONS: No special considerations when disposed according to local, state and Federal regulations. 14. TRANSPORT INFORMATION: Not classified as a hazardous material. 15. REGULATORY AND OTHER INFORMATION: TSCA: All ingredients are listed or exempt per reference 15 USC 2602 Complies with current FDA regulations for cosmetic and/or over-the-counter drug products. WHMIS: Not Controlled Notice: The information herein is based on data considered to be accurate as of the date of preparation of this material safety data sheet. However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and safety information. The user assumes all liability for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices or from any hazards inherent in the nature of the product. Page 284 of 878 Page 284 of 878 Page 284 of 878 Page 284 of 878 ---PAGE BREAK--- Page 285 of 878 Page 285 of 878 Page 285 of 878 Page 285 of 878 ---PAGE BREAK--- Page 286 of 878 Page 286 of 878 Page 286 of 878 Page 286 of 878 ---PAGE BREAK--- Page 287 of 878 Page 287 of 878 Page 287 of 878 Page 287 of 878 ---PAGE BREAK--- MSDS-PPS14 Date Prepared:4/29/03 MATERIAL SAFETY DATA SHEET/COMPLIES WITH OSHA’S HAZARD COMMUNICATION STANDARD (29CFR 1910.1200) SECTION I – PRODUCT IDENTIFICATION GOO GONE PAINTER’S PAL CONTAINER SIZE: 14 fl oz, 55 gallon STOCK NO.: PPS14, PPS14DO, PPS14BM SUPPLIER’S NAME: MAGIC AMERICAN PRODUCTS, INC. ADDRESS: 23700 MERCANTILE ROAD; CLEVELAND, OH 44122 24 Hour Emergency Phone: CHEMTEL 1-[PHONE REDACTED] Information Phone: MAGIC AMERICAN PRODUCTS, INC. M-F, 9-5 EST 1-[PHONE REDACTED] DOT SHIPPING INFORMATION HAZARDS RATING INFORMATION DOT SHIPPING NAME: Not regulated DOT HAZARD CLASS: None DOT LABEL: None DOT PACKING GROUP: None Health Flammability Reactivity Personal Protection NFPA 1 0 0 N/A NPCA(HMIS) 2 0 0 C 0-Minimal 1-Slight 2-Moderate 3-Serious 4-Extreme C-Glasses, gloves, apron SECTION II - INGREDIENTS CHEMICAL NAME CAS NO. 313/CHEMICAL PEL TWA/TLV CARCINOGEN Proprietary Mixture None No ingredients are regulated N/A N/A No (Alkaline Water-based Surfactant and 2-Butoxyethanol Solution) All ingredients used in this proprietary mixture are listed on the TSCA Inventory List and none is listed as carcinogenic by OSHA, IARC or NTP. SECTION III – PHYSICAL DATA SECTION IV – FIRE AND EXPLOSION DATA Boiling Point: 207°F (97°C) Vapor Pressure: 24.2 mm Hg (25°C) Solubility in Water: Complete pH: 8.3 – 8.8 Specific Gravity: 1.03 g/ml Evaporation Rate: Similar to Water Appearance/Odor: Translucent Orange with Citrus, Orange-like Fragrance VOC Content: 25% VOC by CARB Flash Point: Greater than 200°F (93°C) Explosive Hazard: Not an explosive. Extinguishing Media: Use extinguishing media suitable for other combustible materials in area. Special Fire Fighting Procedures: None; material is not combustible. Unusual Fire and Explosion Hazards: None. SECTION V – REACTIVITY DATA SECTION VI – STORAGE AND HANDLING Stability: Stable Hazardous Polymerization: Will not occur. Hazardous Decomposition Products: None known. Incompatibility: None known. KEEP OUT OF THE REACH OF CHILDREN Store in a cool, dry area away from heat or open flame. Do not store at temperatures above 120ºF. SECTION VII – HEALTH EFFECTS AND FIRST AID PRIMARY ROUTES OF ENTRY AND EFFECTS OF OVEREXPOSURE FIRST AID PROCEDURES EYES: According to the Federal Hazardous Substance Act testing protocol 16CFR 1500.42, this product was shown to be an eye irritant in laboratory tests. Therefore, this material is labeled an eye irritant. EYES: Remove any contact lenses and flush both eyes with cool running water for at least 15 minutes. Seek medical attention if irritation persists. SKIN: Irritant. According to the Federal Hazardous Substance Act testing protocol 16CFR 1500.41, this product was shown not to be a primary skin irritant in laboratory tests. Therefore, this product is not considered a skin irritant. SKIN: Wash with soap and water. With extended periods of use, a skin emollient should be applied after use to prevent drying. INHALATION: Not expected to be an inhalation hazard. INHALATION: Remove person to fresh air. INGESTION: According to the Federal Hazardous Substance Act testing protocol 16CFR 1500.3(c)(2)(i), this product was shown to be non-toxic by the oral route of exposure. This material is not considered an ingestion hazard. INGESTION: Rinse mouth and then drink a large glass of water and seek immediate medical attention. LONG TERM EFFECTS: No long term effects expected. SECTION VIII – SPECIAL PROTECTION DATA SECTION IX – SPILL OR LEAK PRECAUTIONS STEPS TO BE TAKEN IN CASE OF SPILLAGE OR LEAKAGE: Ventilate area. Spilled material can be picked up with sorbant material. Use caution where surfaces may become slippery from spilled material. WASTE DISPOSAL METHOD: Sweep up and place in empty container and close. Dispose of according to local, state and federal regulations. RESPIRATORY PROTECTION: Not needed. VENTILATION: Not needed. PROTECTIVE GLOVES: Chemically resistant gloves (neoprene) are recommended for prolonged use. EYE PROTECTION: Recommended if splashing during transfer is possible. WASTE DISPOSAL CAUTION: Hazardous substances cleaned with this product may create hazardous waste that must be properly characterized and disposed of in accordance with RCRA, state and local regulations. N/A = NOT APPLICABLE N/E = NOT ESTABLISHED N/D = NOT DETERMINED < = LESS THAN > = MORE THAN NOTICE: The information contained on this Material Safety Data Sheet is for Industrial and Institutional use only and considered accurate as of the date of publication. It is not necessarily all inclusive or fully adequate in every circumstance. The suggestions should not be confused with or followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, express or implied, of merchantability, fitness, accuracy of data, or the results to be obtained from the use thereof is made. The vendor assumes no responsibility for injury or damages resulting from the inappropriate use of this product. Magic American assumes no responsibility for any product information placed on the Internet by individuals who are not affiliated with Magic American. Page 288 of 878 Page 288 of 878 Page 288 of 878 Page 288 of 878 ---PAGE BREAK--- Material Safety Data Sheet: GOOD RIDDANCE Supercedes Date 04/12/2006 Issuing Date 02/05/2009 1. PRODUCT AND COMPANY IDENTIFICATION Product Name GOOD RIDDANCE Recommended Use cleaning agent Product Code 0677 Chemical Nature Mixture Information on Manufacturer Emergency Telephone Number CHEMSEARCH DIV. OF NCH CORP. CHEMTREC ® [PHONE REDACTED] BOX 152170 IRVING, TX 75015 2. HAZARDS IDENTIFICATION Emergency Overview Warning May cause skin irritation Causes eye irritation May cause allergic skin reaction May cause allergic respiratory reaction May cause respiratory tract irritation May be harmful if swallowed Color Colorless Physical State Liquid Odor Fresh Potential Health Effects Principle Route of Exposure Skin contact, Eye contact. Primary Routes of Entry Inhalation, Ingestion, Skin Absorption. Acute Effects Eyes Causes eye irritation. Skin May cause skin irritation. May cause allergic skin reaction. Inhalation May cause irritation of respiratory tract. May cause allergic respiratory reaction. Ingestion Irritating to mucous membranes. May produce an allergic reaction. Chronic Effects May cause sensitization of susceptible persons. Target Organ Effects Skin, Eyes, Respiratory system, Bone Marrow. Aggravated Medical Conditions Skin disorders. Respiratory disorders. Potential Environmental Effects See Section 12 for additional Ecological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Component CAS-No Sodium thiosulfate pentahydrate 10102-17-7 Sodium lauryl sulfate 151-21-3 Tetrasodium Ethylenediaminetetraacetate 64-02-8 Sulfuric acid, mono-c12-16-alkyl esters, sodium salts 73296-89-6 Sodium metabisulfite 7681-57-4 4. FIRST AID MEASURES General Advice Avoid contact with skin, eyes and clothing. Avoid breathing vapors, mist or gas. Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. Get medical attention if irritation develops and persists. Skin Contact Wash off immediately with soap and plenty of water. Remove contaminated clothing and shoes. Get medical attention if irritation develops and persists. Wash contaminated clothing before re-use. Inhalation If inhaled, remove to fresh air. Get medical attention if occur. Ingestion Drink 1 or 2 glasses of water. Do not induce vomiting. Get medical attention immediately. Never give anything by mouth to an unconscious person. Notes to Physician No information available. 5. FIRE-FIGHTING MEASURES Flash Point Not combustible Method Not applicable Autoignition Temperature No information available Flammability Limits in Air % Not applicable Suitable Extinguishing Media Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Specific Hazards Arising from the Chemical Material can create slippery conditions. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 2 Flammability 1 Instability 0 HMIS Health 2 Flammability 1 Instability 0 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Use personal protective equipment. Prevent further leakage or spillage if safe to do so. Material can create slippery conditions. Environmental Precautions Do not flush into surface water or sanitary sewer system. Methods for Containment Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13) Methods for Cleaning Up Pick up and transfer to properly labeled containers . Neutralizing Agent Not applicable Page 1 / 4 Page 289 of 878 Page 289 of 878 Page 289 of 878 Page 289 of 878 ---PAGE BREAK--- 7. HANDLING AND STORAGE Handling Avoid contact with skin, eyes and clothing. Avoid breathing vapors or mists. Storage Keep container closed. Keep out of the reach of children. Keep containers closed in a cool, well-ventilated place. Storage Temperature Minimum 35°F / 2°C Maximum 120°F / 49°C Storage Conditions Indoor X Outdoor Heated Refrigerated 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH Sodium thiosulfate pentahydrate No data available no data available no data available Sodium lauryl sulfate No data available no data available no data available Tetrasodium Ethylenediaminetetraacetate No data available no data available no data available Sulfuric acid, mono-c12-16-alkyl esters, sodium salts No data available no data available no data available Sodium metabisulfite TWA: 5 mg/m3 no data available TWA: 5 mg/m3 Engineering Measures Use with local exhaust ventilation. Personal Protective Equipment Eye/Face Protection Safety glasses with side-shields. Skin Protection Impervious gloves. Respiratory Protection Use NIOSH approved respiratory protection. General Hygiene Considerations Ensure that eyewash stations and safety showers are close to the workstation location. Wear protective gloves/clothing. Remove and wash contaminated clothing before re-use. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Viscosity Non viscous Color Colorless Odor Fresh Appearance Transparent pH 5.8 Specific Gravity 1.037 Bulk Density No information available Evaporation Rate 0.45 (Butyl acetate=1) Percent Volatile (Volume) 91 VOC Content 0.1 VOC Content (g/l) 0 Vapor Pressure 16.7 mmHg @ 70 °F Vapor Density 0.6 Solubility Soluble Boiling Point/Range 212°F / 100°C 10. STABILITY AND REACTIVITY Chemical Stability Stable under normal conditions. Conditions to Avoid None known. Incompatible Products Strong oxidizing agents. Acids. Halogenated hydrocarbon. Powdered metals. Metal nitrates . Hazardous Decomposition Products Carbon oxides. Sulfur oxides . Sodium oxides. Hydrogen sulfide and smoke . Possibility of Hazardous Reactions None under normal processing 11. TOXICOLOGICAL INFORMATION Product Information No information available Component Information Acute toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Draize Test Other Sodium thiosulfate pentahydrate 5000 mg/kg ( Rat ) no data available no data available no data available no data available Sodium lauryl sulfate 1288 mg/kg ( Rat ) 580 mg/kg ( Rabbit ) 3900 mg/m3 ( Rat ) 1 h no data available no data available Tetrasodium Ethylenediaminetetraacetate 10 g/kg ( Rat ) no data available no data available no data available no data available Sulfuric acid, mono-c12-16-alkyl esters, sodium salts 1783 mg/kg ( Rat ) no data available no data available no data available no data available Sodium metabisulfite 1131 mg/kg ( Rat ) 2 g/kg ( Rat ) no data available no data available no data available Chronic Toxicity Component Mutagenicity Sensitization Developmental Toxicity Reproductive Toxicity Target Organ Effects Sodium thiosulfate pentahydrate no data available no data available no data available no data available no data available Sodium lauryl sulfate no data available Skin sensitization no data available no data available Bone marrow Tetrasodium Ethylenediaminetetraacetate no data available no data available no data available no data available no data available Sulfuric acid, mono-c12-16-alkyl esters, sodium salts no data available no data available no data available no data available no data available Sodium metabisulfite no data available Skin sensitization no data available no data available eyes, skin, respiratory system, bone marrow Carcinogenicity There are no known carcinogenic chemicals in this product Component ACGIH IARC NTP OSHA Other Sodium thiosulfate pentahydrate not applicable not applicable not applicable not applicable not applicable Sodium lauryl sulfate not applicable not applicable not applicable not applicable not applicable Tetrasodium Ethylenediaminetetraacetate not applicable not applicable not applicable not applicable not applicable Sulfuric acid, mono-c12-16-alkyl esters, sodium salts not applicable not applicable not applicable not applicable not applicable Sodium metabisulfite not applicable not applicable not applicable not applicable not applicable 12. ECOLOGICAL INFORMATION Product Information No information available 0677 - GOOD RIDDANCE 0677 - GOOD RIDDANCE 0677 - GOOD RIDDANCE 0677 - GOOD RIDDANCE Issuing Date 05-Feb-2009 Issuing Date 05-Feb-2009 Issuing Date 05-Feb-2009 Issuing Date 05-Feb-2009 Page 2 / 4 Page 290 of 878 Page 290 of 878 Page 290 of 878 Page 290 of 878 ---PAGE BREAK--- Component Information Component Toxicity to Algae Toxicity to Fish Microtox Water Flea log Pow Sodium thiosulfate pentahydrate no data available LC50= 24000 mg/L Gambusia affinis 96 h no data available no data available N/A Sodium lauryl sulfate EC50 30 - 100 mg/L Scenedesmus subspicatus 96 h EC50= 117 mg/L Selenastrum capricornutum 96 h EC50= 53 mg/L Scenedesmus subspicatus 72 h LC50 13.5 - 18.3 mg/L Poecilia reticulata 96 h LC50 4.06 - 5.75 mg/L Lepomis macrochirus 96 h LC50 6.6 - 8.5 mg/L Pimephales promelas 96 h LC50= 10.2 mg/L Pimephales promelas 96 h LC50= 17 mg/L Pimephales promelas 96 h LC50= 22.5 mg/L Pimephales promelas 96 h LC50= 4.6 mg/L mykiss 96 h LC50= 7.97 mg/L Brachydanio rerio 96 h EC50 = 0.46 mg/L 30 min EC50 = 0.72 mg/L 15 min EC50 = 1.19 mg/L 5 min EC50 = 1.8 mg/L 48 h 1.6 Tetrasodium Ethylenediaminetetraacetate EC50= 1.01 mg/L Scenedesmus subspicatus 72 h LC50= 41 mg/L Lepomis macrochirus 96 h LC50= 59.8 mg/L Pimephales promelas 96 h no data available EC50 = 610 mg/L 24 h N/A Sulfuric acid, mono-c12-16-alkyl esters, sodium salts EC50= 42 mg/L Scenedesmus subspicatus 96 h LC50= 4.1 mg/L Leuciscus idus 48 h no data available EC50 = 21.2 mg/L 24 h N/A Sodium metabisulfite EC50= 40 mg/L Scenedesmus subspicatus 96 h EC50= 48 mg/L Scenedesmus subspicatus 72 h LC50= 32 mg/L Lepomis macrochirus 96 h EC50 = 56 mg/L 17 h EC50 = 89 mg/L 24 h -3.7 Persistence and Degradability No information available Bioaccumulation No information available Mobility No information available 13. DISPOSAL CONSIDERATIONS Product Disposal Dispose of in accordance with local regulations Container Disposal Do not re-use empty containers. 14. TRANSPORT INFORMATION DOT Not regulated TDG Not regulated ICAO Not regulated IATA Not regulated IMDG/IMO Not regulated 15. REGULATORY INFORMATION Inventories TSCA Complies DSL Complies U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part 372. SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No CERCLA Component Hazardous Substances RQs CERCLA EHS RQs Sodium thiosulfate pentahydrate Not applicable Not applicable Sodium lauryl sulfate Not applicable Not applicable Tetrasodium Ethylenediaminetetraacetate Not applicable Not applicable Sulfuric acid, mono-c12-16-alkyl esters, sodium salts Not applicable Not applicable Sodium metabisulfite Not applicable Not applicable Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class D2B Toxic materials . 16. OTHER INFORMATION Prepared By Dan Hollas Supercedes Date 04/12/2006 Issuing Date 02/05/2009 Reason for Revision No information available Glossary No information available List of References No information available CHEMSEARCH DIV. OF NCH CORP. assumes no responsibility for personal injury or property damage caused by the use, storage, or disposal of the product in a manner not recommended on the product label. Users assume all risks associated with such unrecommended use, storage or disposal of the product. The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, 0677 - GOOD RIDDANCE 0677 - GOOD RIDDANCE 0677 - GOOD RIDDANCE 0677 - GOOD RIDDANCE Issuing Date 05-Feb-2009 Issuing Date 05-Feb-2009 Issuing Date 05-Feb-2009 Issuing Date 05-Feb-2009 Page 3 / 4 Page 291 of 878 Page 291 of 878 Page 291 of 878 Page 291 of 878 ---PAGE BREAK--- processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. 0677 - GOOD RIDDANCE 0677 - GOOD RIDDANCE 0677 - GOOD RIDDANCE 0677 - GOOD RIDDANCE Issuing Date 05-Feb-2009 Issuing Date 05-Feb-2009 Issuing Date 05-Feb-2009 Issuing Date 05-Feb-2009 Page 4 / 4 Page 292 of 878 Page 292 of 878 Page 292 of 878 Page 292 of 878 ---PAGE BREAK--- SAFETY DATA SHEET Goop Hand Cleaner Product Name: Goop Liquid Orange Hand Cleaner Page 1 of 4 Product ID: #44, 440 Product Name: Goop Liquid Orange Hand Cleaner Product Use: Bathroom/Industrial hand cleaner / Kitchen Revision Date: 10-29-2014 Product ID: #44, #440 Company Information: Critzas Industries Inc. 4041 Park Avenue St. Louis, MO 63110, United States Phone: [PHONE REDACTED] Fax: [PHONE REDACTED] Email: [EMAIL REDACTED] Emergency Contact Information: For Chemical Emergency [PHONE REDACTED] Goop Liquid Orange Hand Cleaner Item #38, #47 EMERGENCY OVERVIEW The product within this SDS, when used in accordance with the instructions, presents no immediate or long term health hazard. Abnormal entry may, such as gross ingestion, may require medical attention. Class: Prevention: POSSIBLE EYE IRRITANT Do not eat or drink while using this product Response If swallowed: Call a doctor if you feel unwell Rinse mouth Rinse eyes thoroughly with clean water If irritation persists, contact a medical physician WARNING Storage HARMFUL IF SWALLOWED Store above 32o F and below 100o F IRRITATION TO EYES Disposal None specified Components CAS # Concentration Water 7732-18-5 Q.S. 100% C9-11 Pareth-8 68439-46-3 5-8% D-Limonene 5989-27-5 2% Triethanolamine 102-71-6 1-2% Glycerin 56-81-5 1-3% Paraffinum Liquidum 8042-47-5 2-4% PEG-75 Lanolin 61790-81-6 Polyacrylate Crosspolymer Proprietary DMDM Hydantoin 6440-58-0 .20% CI 15985 Spangler Orange 2783-94-0 1: Product and company identification 2: Hazards Identification 3: Composition / Information on ingredients Page 293 of 878 Page 293 of 878 Page 293 of 878 Page 293 of 878 ---PAGE BREAK--- SAFETY DATA SHEET Goop Hand Cleaner Product Name: Goop Liquid Orange Hand Cleaner Page 2 of 4 Product ID: #44, 440 Eye Contact: Flush eyes with thoroughly with plenty of water. Tilt head to avoid contaminating unaffected eye. If irritation occurs seek medical attention. Skin Contact: No hazard expected under normal use. If irritation occurs seek medical attention. Ingestion: No hazard expected under normal use. Do not induce vomiting. Seek medical attention if occur. Inhalation: No hazard expected under normal use. Remove to fresh air if occur. Seek medical attention if persist. Note to Physicians: There is no specific antidote. Treatment of overexposure should be directed at the control of and the clinical condition of the patient. Extinguishing Media: For fires in area use appropriate media, i.e. dry chemical, carbon dioxide, water fog, alcohol foam. Fire Fighting Methods: Will not burn. No special instruction available. Use fire fighting methods appropriated for surrounding materials. Fire and Explosion: None known. Hazardous Combustion Products: None known. Spill Clean-Up Procedures: Follow personal protective equipment recommendations found in Section 8. Soak up residue with inert absorbent material. Place in non-leaking containers for disposal. Flush remaining residue in area with water and dispose of properly. Avoid direct discharge to sewers and surface waters in large amounts. Notify authorities if entry occurs. Handling: Avoid eye contact. Do not swallow. Do not eat, drink or smoke in work area. Avoid breathing mists or dusts. Exposure Guide Lines: None established by OSHA Engineering Controls: None expected to be needed under normal use. Use local exhaust ventilation if in confined spaces. Avoid creating mist. Eye/Face Protection: None needed under normal use. Safety glasses or goggles recommended if eye contact is eminent. Skin Protection: Material is not considered a skin contact hazard. Respiratory Protection: None required under normal use. Other Protective Equipment: Eye-wash station. General Hygiene Conditions: Wash with soap and water before meal times and at the end of each work shift. 4: First Aid Measures 5: Fire Fighting Measures 7: Handling and Storage 8: Exposure Control / Personal Protection 6: Accidental Release Measures Page 294 of 878 Page 294 of 878 Page 294 of 878 Page 294 of 878 ---PAGE BREAK--- SAFETY DATA SHEET Goop Hand Cleaner Product Name: Goop Liquid Orange Hand Cleaner Page 3 of 4 Product ID: #44, 440 Physical State: Viscous Liquid Color: Orange Odor: Sweet Boiling Point: N.D. Freezing Point: N.D. Melting Point: N.D. Evaporation Point: >1.0 Vapor Pressure: N.D. Vapor Density: <1.0 (Air=1) Viscosity: N.D. Solubility: Soluble in Water pH: Range 7-8 Specific Gravity: .95g/ml @25oC (Water=1) VOC .94% VOC 9.4g/L VOC Method EPA Method 24 Flash Point: N.A. Flash Point Method: N.A. Auto Ignition Temp.: N.D. Stability: Stable under normal conditions Conditions to Avoid: Avoid all forms of contamination, Heat over 150oF/Below -10oF Incompatible Materials: Avoid strong oxidizing agents, sources of ignition. Hazardous Decomposition Products: None known. Hazardous Polymerization: None known. LD50 Oral: No Data LD50 Skin: No Data LD50 Inhalation: No Data Ecotoxicity: No data available. Environmental Fate: Product is biodegradable. Hazardous Waste Number: N.A. Disposal Method: Dispose of in accordance with all local, state, and federal regulations. Disposal methods identified are for the product as sold. For disposal of used material, an assessment must be completed to determine proper disposal methods for your location. 9: Physical Data 10. Stability and Reactivity 11: Toxicological Information 12: Ecological Information 13: Disposal Considerations Page 295 of 878 Page 295 of 878 Page 295 of 878 Page 295 of 878 ---PAGE BREAK--- SAFETY DATA SHEET Goop Hand Cleaner Product Name: Goop Liquid Orange Hand Cleaner Page 4 of 4 Product ID: #44, 440 Department of Transportation: Not regulated by the Department of Transportation. Harmonized System Code: 3401.20.0000 U.S. Federal Regulations: TSCA: All components of this product are in compliance with or exempt. (15USC 2602 Environmental Protection Agency (EPA) All components of this product are in compliance with regulations set forth by the EPA. (USEPA sec 183e) U.S. State Regulations: California California Air Resources Board (CARB): All components of this product are in compliance with regulations set forth by CARB. (CARB art. 94509) Southern California Air Quality Management District (SCAQMD): All components of this product are in compliance with regulations set forth by SCAQMD. (SCAQMD rule 1113) California Proposition 65 Statement This product does not contain chemicals known to the state of California to cause cancer, birth defects or cause reproductive harm. NFPA Hazard Ratings: Health: 0 Flammability: 0 Reactivity: 0 Special Hazard: None MSDS Abbreviations N.A. = Not Applicable N.D. = Not Determined VOC = Volatile Organic Material MSDS Prepared by: LH Completed: 10/29/14 Disclaimer: This material safety data sheet relates to the specific material designated and does not relate to its use in combination with any other material. The date contained is believed to be correct. However, since conditions of use are outside our control is should be taken as warranty or representation for which Critzas Industries Inc. assumes legal responsibility. This information is provided solely for your consideration, investigation, and verification. 14: Transportation Information 15: Regulatory Information 16: Additional Information Page 296 of 878 Page 296 of 878 Page 296 of 878 Page 296 of 878 ---PAGE BREAK--- FOR CHEMICAL EMERGENCY During Business Hours: (800) 966-3458 Outside Business Hours: (800) 420-7186 GORILLA EPOXY HARDENER MSDS Page 1 of 4 1. IDENTIFICATION OF THE PRODUCT PRODUCT NAME: Gorilla Epoxy (Gray Package)- Hardener SYNONYMS: Epoxy Hardener DISTRIBUTOR: The Gorilla Glue Company 4550 Red Bank Expressway Cincinnati, OH 45227 Tel: (513) 271-3300 Fax: (513) 527-3742 2. HAZARDS IDENTIFICATION Physical State Liquid Color Amber OSHA/HCS status This material is considered hazardous by OSHA Hazard Communication Standard (29 CFR 1910.1200) Emergency Overview DANGER! CAUSES EYE AND SKIN BURNS. CAUSES RESPIRATORY TRACT IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. MAY BE HARMFUL IF ABSORBED THROUGH SKIN OR SWALLOWED. CAN ENTER LUNGS AND CAUSE DAMAGE. Do not breathe vapor. Do not get on skin. Avoid contact with eyes. Do not ingest. Wash thoroughly after handling. Use only with adequate ventilation. See toxicological information (section 11) 3. COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENTS WGT% CAS # Mercaptan-terminated polymer 60-100% Isophorone 7-13 % 2855-13-2 4. FIRST AID MEASURES Eye contact Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Inhalation Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. MATERIALS SAFETY DATA SHEET Date Revised June 12, 2012 4th Edition Page 297 of 878 Page 297 of 878 Page 297 of 878 Page 297 of 878 ---PAGE BREAK--- FOR CHEMICAL EMERGENCY During Business Hours: (800) 966-3458 Outside Business Hours: (800) 420-7186 GORILLA EPOXY HARDENER MSDS Page 2 of 5 4. FIRST AID MEASURES Ingestion Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Notes to physician No specific treatment. Treat Call medical doctor or poison control center immediately if large quantities have been ingested. . 5. FIRE- FIGHTING MEASURES Flash point Closed cup: >93oC (>199.4oF) Hazardous thermal Decomposition products may include the following: decomposition products carbon dioxide carbon monoxide nitrogen oxides Extinguishing media Suitable : Use an extinguishing agent suitable for the surrounding fire. Not suitable : None known Special exposure hazards isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Use personal protection in Section 8. Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Methods for cleaning up : Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Note: see section 1 for emergency contact information and section 13 for waste disposal. MATERIALS SAFETY DATA SHEET Date Revised June 12, 2012 4th Edition Page 298 of 878 Page 298 of 878 Page 298 of 878 Page 298 of 878 ---PAGE BREAK--- FOR CHEMICAL EMERGENCY During Business Hours: (800) 966-3458 Outside Business Hours: (800) 420-7186 GORILLA EPOXY HARDENER MSDS Page 3 of 5 7. HANDLING AND STORAGE Handling Put on appropriate personal protective equipment (see Section Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Keep closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Storage Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Keep container closed and sealed until ready for use. Do not store in unlabeled containers. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering controls: Use local exhaust ventilation if the potential for airborne exposure exists. Respiratory: In case of inadequate ventilation wear respiratory protection. Hands: Chemical resistant, impermeable gloves Eyes: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary. 9. PHYSICAL AND CHEMICAL PROPERTIES FLASH POINT: >200°F/ 93°C Closed cup LOWER FLAMMABLE LIMIT Not available UPPER FLAMMABLE LIMIT Not available APPEARANCE: Amber viscous liquid SPECIFIC GRAVITY: 1.11 VAPOR PRESSURE (mmHg): < 1 BOILING POINT: N/AV VAPOR DENSITY: Heavier than air EVAPORATION RATE (Ethyl Ether = Not available VOLATILES BY WEIGHT: Nil SOLUBILITY IN WATER: Nil VOC: 1.2% (11 g/L) 10. STABILITY AND REACTIVITY STABILITY: Stable CONDITIONS TO AVOID: Open flames, sparks, heat, electrical and static discharge. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Dioxide, Carbon Monoxide, and Carbon. HAZARDOUS POLYMERIZATION: Under normal conditions of storage and use, hazardous reactions will not occur. MATERIALS SAFETY DATA SHEET Date Revised June 12, 2012 4th Edition Page 299 of 878 Page 299 of 878 Page 299 of 878 Page 299 of 878 ---PAGE BREAK--- FOR CHEMICAL EMERGENCY During Business Hours: (800) 966-3458 Outside Business Hours: (800) 420-7186 GORILLA EPOXY HARDENER MSDS Page 4 of 5 11. TOXICOLOGICAL INFORMATION Potential Acute Health Effects: Inhalation Causes irritation to the respiratory system Ingestion Harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage. May cause burns to mouth, throat and stomach. Skin Corrosive to skin. Can cause burns. May cause sensitization by skin contact. Eyes Corrosive to eye. Can cause burns. Product/Ingredient name Result Species Dose Exposure Isophorone diamine LD50 Oral Rat 1030mg/kg - Sensitizer Guinea Pig Skin Mercaptan-terminated polymer LC50 Inhalation Rat >20 mg/L 4 hours Chronic Effects: Overexposure to this material has apparently been known to cause the following effects in lab animals: skin sensitization, respiratory system irritation. CARCINOGEN: YES NO X TERATOGEN: YES NO X MUTAGEN: YES NO X 12. ECOLOGICAL INFORMATION Environmental effects No known significant effects or critical hazards. 13. DISPOSAL CONSIDERATIONS Waste Disposal: Dispose of in accordance with local, state, and federal regulations. 14. TRANSPORT INFORMATION Proper shipping name DOT : ISOPHORONEDIAMINE MIXTURE UN2289 TDG : ISOPHORONEDIAMINE MIXTURE UN2289 IMDG : ISOPHORONEDIAMINE MIXTURE UN2289 IATA : ISOPHORONEDIAMINE MIXTURE UN2289 Cargo aircraft qty limit 60L, packaging instructions 856 15. REGULATORY INFORMATION U.S. Federal Regulations HCS Classification Corrosive material Sensitizing material U.S. Federal regulations United States Inventory (TSCA 8b): All components are listed or exempted. SARA 302/304/311/312/313 Extremely hazardous substances: No ingredient listed MATERIALS SAFETY DATA SHEET Date Revised June 12, 2012 4th Edition Page 300 of 878 Page 300 of 878 Page 300 of 878 Page 300 of 878 ---PAGE BREAK--- 15. REGULATORY INFORMATION SARA 311/312 Hazard identification: Immediate acute health hazard, Delayed chronic health hazard Clean Air Act Section 112(b) No ingredients listed CERCLA Hazardous substances No ingredients listed State Regulations: – RTK: Proponal, Oxybis- California Prop 65: This product contains no listed substances known to the state of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute. Canada WHMIS Class D-2B: Material causing other toxic effects. Class E: Corrosive Material CEPA DSL All components are listed or exempted. International lists : Australia inventory (AICS): At least one component is not listed. China inventory (IECSC): All components are listed or exempted. Japan inventory: At least one component is not listed. Korea inventory: Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): At least one component is not listed. 16. OTHER INFORMATION HMIS RATING: Health 3 4 = Extreme Fire 1 3 = High Reactivity 1 2 = Moderate 1 = Slight 0 = Insignificant Personal Protection - See Section 8 The information presented in this Material Safety Data Sheet was prepared by qualified personnel and to the best of our knowledge is true and accurate. The information and recommendations are furnished for this product with the understanding that the purchaser will independently determine the suitability of the product for this purpose. This data does not constitute a warranty, expressed or implied, statutory or otherwise, nor is it representation for which The Gorilla Glue Company assumes legal responsibility. The data is submitted for the user’s information and consideration only. Any use of this product must be determined by the user to be in accordance with applicable federal, state, provincial and local laws and regulations. MATERIALS SAFETY DATA SHEET Date Revised June 12, 2012 4th Edition FOR CHEMICAL EMERGENCY During Business Hours: (800) 966-3458 Outside Business Hours: (800) 420-7186 Page 5 of 5 GORILLA EPOXY HARDENER MSDS Page 301 of 878 Page 301 of 878 Page 301 of 878 Page 301 of 878 ---PAGE BREAK--- FOR CHEMICAL EMERGENCY During Business Hours: (800) 966-3458 Outside Business Hours: (800) 420-7186 GORILLA EPOXY RESIN MSDS Page 1 of 5 1. IDENTIFICATION OF THE PRODUCT PRODUCT NAME: Gorilla Epoxy (Gray Package)- Resin SYNONYMS: Epoxy Resin DISTRIBUTOR: The Gorilla Glue Company 4550 Red Bank Expressway Cincinnati, OH 45227 Tel: (513) 271-3300 Fax: (513) 527-3742 2. HAZARDS IDENTIFICATION Physical State Liquid Color Translucent, clear OSHA/HCS status This material is considered hazardous by OSHA Hazard Communication Standard (29 CFR 1910.1200 Emergency Overview WARNING! MAY CAUSE EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. Do not breathe vapor or mist. Do not get on skin or clothing. Avoid contact with eyes. Wash thoroughly after handling. See toxicological information (section 11) 3. COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENTS WGT% CAS # Bisphenol A Epoxy Resin 60-100% 25068-38-6 4. FIRST AID MEASURES Eye contact Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention. Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. If develop or persist, get medical attention. Inhalation Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. If develop or persist, get medical attention. Ingestion Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. MATERIALS SAFETY DATA SHEET Date Revised June 12, 2012 4th Edition Page 302 of 878 Page 302 of 878 Page 302 of 878 Page 302 of 878 ---PAGE BREAK--- FOR CHEMICAL EMERGENCY During Business Hours: (800) 966-3458 Outside Business Hours: (800) 420-7186 GORILLA EPOXY RESIN MSDS Page 2 of 5 4. FIRST AID MEASURES Notes to physician No specific treatment. Treat Call medical doctor or poison control center immediately if large quantities have been ingested. 5. FIRE- FIGHTING MEASURES Flash point Closed cup: >93oC (>199.4oF) Hazardous thermal No specific data decomposition products Extinguishing media Suitable : Use an extinguishing agent suitable for the surrounding fire. Not suitable : None known Special exposure hazards isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Use personal protection in Section 8. Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Methods for cleaning up : Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Note: see section 1 for emergency contact information and section 13 for waste disposal. 7. HANDLING AND STORAGE Handling Do not breathe gas/fumes/vapors/spray. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Keep container closed. Do not reuse container. Storage Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Keep container closed and sealed until ready for use. Do not store in unlabeled containers. MATERIALS SAFETY DATA SHEET Date Revised June 12, 2012 4th Edition Page 303 of 878 Page 303 of 878 Page 303 of 878 Page 303 of 878 ---PAGE BREAK--- FOR CHEMICAL EMERGENCY During Business Hours: (800) 966-3458 Outside Business Hours: (800) 420-7186 GORILLA EPOXY RESIN MSDS Page 3 of 5 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering controls: Use local exhaust ventilation if the potential for airborne exposure exists. Respiratory: In case of inadequate ventilation wear respiratory protection. Hands: Chemical resistant, impermeable gloves Eyes: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary. Other PPE: Wear other protective clothing as needed tp prevent skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES FLASH POINT: Closed cup >93oC (>199.4oF) LOWER FLAMMABLE LIMIT N/E UPPER FLAMMABLE LIMIT N/E APPEARANCE: Clear viscous liquid SPECIFIC GRAVITY: 1.16 VAPOR PRESSURE (mmHg): < 1 BOILING POINT: N/AV VAPOR DENSITY: Heavier than air EVAPORATION RATE (Ethyl Ether = Not available VOLATILES BY WEIGHT: Nil SOLUBILITY IN WATER: Nil VOC: Grams/Liter = Nil Lbs/Gallon = Nil 10. STABILITY AND REACTIVITY STABILITY: Stable CONDITIONS TO AVOID: Open flames, sparks, heat, electrical and static discharge. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Dioxide, Carbon Monoxide, and Carbon. HAZARDOUS POLYMERIZATION: Under normal conditions of storage and use, hazardous reactions will not occur. 11. TOXICOLOGICAL INFORMATION POTENTIAL ACUTE HEALTH EFFECTS Inhalation No significant effects or critical hazards Ingestion No significant effects or critical hazards Skin Irritating to skin. May cause sensitization by skin contact. Eyes Irritating to eye MATERIALS SAFETY DATA SHEET Date Revised June 12, 2012 4th Edition Page 304 of 878 Page 304 of 878 Page 304 of 878 Page 304 of 878 ---PAGE BREAK--- FOR CHEMICAL EMERGENCY During Business Hours: (800) 966-3458 Outside Business Hours: (800) 420-7186 GORILLA EPOXY RESIN MSDS Page 4 of 5 11. TOXICOLOGICAL INFORMATION CHRONIC EFFECTS: Overexposure to this material has apparently been known to cause the following effects in lab animals: skin sensitization, respiratory system irritation. Pre-existing skin disorders may be aggravated by over-exposure to this product. CARCINOGEN: YES NO X TERATOGEN: YES NO X MUTAGEN: YES NO X 12. ECOLOGICAL INFORMATION Toxic to aquatic organisms. Marine Pollutant 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with local, state, and federal regulations. 14. TRANSPORT INFORMATION Proper shipping name DOT : Environmentally hazardous substance, liquid, n.o.s. (BISPHENOL A EPOXY RESIN) Marine pollutant UN3082 Class 9 PG* III TDG :Environmentally hazardous substance, liquid, n.o.s. (BISPHENOL A EPOXY RESIN) Marine pollutant UN3082 Class 9 PG* III IMDG :ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BISPHENOL A EPOXY RESIN) Marine pollutant UN3082 Class 9 PG* III IATA :ENVIRON MENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BISPHENOL A EPOXY RESIN) Marine pollutant UN3082 Class 9 PG* III 15. REGULATORY INFORMATION U.S. Federal Regulations HCS Classification Irritating material Sensitizing material U.S. Federal regulations United States Inventory (TSCA 8b): All components are listed or exempted. SARA 302/304/311/312/313 No ingredient listed Clean Air Act Section 112(b) No ingredients listed CERCLA Hazardous substances No ingredients listed MATERIALS SAFETY DATA SHEET Date Revised June 12, 2012 4th Edition Page 305 of 878 Page 305 of 878 Page 305 of 878 Page 305 of 878 ---PAGE BREAK--- 15. REGULATORY INFORMATION State Regulations – RTK: None of the components are listed California Prop 65: This product contains no listed substances known to the state of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute. Canada WHMIS Class D-2B: Material causing other toxic effects. CEPA DSL All components are listed or exempted. International lists : Australia inventory (AICS): All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. Japan inventory: At least one component is not listed. Korea inventory: All components are listed or exempted. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): All components are listed or exempted. 16. OTHER INFORMATION HMIS RATING: Health 2 4 = Extreme Fire 1 3 = High Reactivity 0 2 = Moderate 1 = Slight 0 = Insignificant Personal Protection - See Section 8 The information presented in this Material Safety Data Sheet was prepared by qualified personnel and to the best of our knowledge is true and accurate. The information and recommendations are furnished for this product with the understanding that the purchaser will independently determine the suitability of the product for this purpose. This data does not constitute a warranty, expressed or implied, statutory or otherwise, nor is it representation for which The Gorilla Glue Company assumes legal responsibility. The data is submitted for the user’s information and consideration only. Any use of this product must be determined by the user to be in accordance with applicable federal, state, provincial and local laws and regulations. MATERIALS SAFETY DATA SHEET Date Revised June 12, 2012 4th Edition FOR CHEMICAL EMERGENCY During Business Hours: (800) 966-3458 Outside Business Hours: (800) 420-7186 GORILLA EPOXY RESIN MSDS Page 5 of 5 Page 306 of 878 Page 306 of 878 Page 306 of 878 Page 306 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET GP Forward (1:64 use solution) Version Number: 1 Preparation date: 2006-10-25 Personal protective equipment NFPA HMIS Reactivity 0 None / Aucune / Ninguno Health Fire Hazard 1 0 0 1 0 1. PRODUCT AND COMPANY IDENTIFICATION Product name: GP Forward (1:64 use solution) MSDS MS0200044D Product Code: MS0200044D Recommended use: Industrial/Institutional. Cleaning product. This product is intended to be diluted prior to use. Emergency telephone number: 1-[PHONE REDACTED] (Prosar); 1-[PHONE REDACTED] (Int'l Prosar); 01-[PHONE REDACTED] (México) 2. HAZARDS IDENTIFICATION Principle routes of exposure: Eye contact. Skin contact. Inhalation. Eye contact: May be mildly irritating to eyes. Skin contact: None known. Inhalation: None known. Ingestion: None known. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components None 4. FIRST AID MEASURES Eye contact: Flush immediately with plenty of water. If irritation develops, get medical attention. Skin contact: Rinse with plenty of water. Inhalation: No specific first aid measures are required. Ingestion: No specific first aid measures are required. Aggravated Medical Conditions: None known. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: The product is not flammable. Extinguish fire using agent suitable for surrounding fire. Specific hazards: None known. Unusual hazards: None known. Specific methods: No special methods required Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: None. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Use personal protective equipment Environmental precautions and clean-up methods: Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use a water rinse for final clean-up. Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] EMERGENCY OVERVIEW CAUTION. MAY BE MILDLY IRRITATING TO EYES. GP Forward (1:64 use solution) 1 of 3 Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-0902 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.johnsondiversey.com Page 307 of 878 Page 307 of 878 Page 307 of 878 Page 307 of 878 ---PAGE BREAK--- 7. HANDLING AND STORAGE Handling: Avoid contact with eyes. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: No special ventilation requirements. General room ventilation is adequate. Personal Protective Equipment Eye protection: No special requirements under normal use conditions. Hand protection: No special requirements under normal use conditions Skin and body protection: No special requirements under normal use conditions. Respiratory protection: No special requirements under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES * - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 10. STABILITY AND REACTIVITY Stability: The product is stable Polymerization: Hazardous polymerization does not occur. Hazardous decomposition products: None reasonably foreseeable. Conditions to avoid: Do not freeze. 11. TOXICOLOGICAL INFORMATION Acute toxicity: Oral LD50 estimated to be greater than 5000 mg/kg. Dermal LD50 estimated to be > 2000 mg/kg Component Information: See Section 3 Chronic toxicity: None known Specific effects Carcinogenic effects: None known Mutagenic effects: None known Reproductive toxicity: None known Target organ effects: None known 12. ECOLOGICAL INFORMATION Environmental Information: No data available 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Dispose of according to all federal, state and local applicable regulations Appearance: Decomposition temperature: Not determined Aqueous solution VOC: 0.0% * No information available Autoignition temperature: No information available Vapor density: Flash point: >200°F >93.3°C No information available Partition coefficient (n-octanol/water): No information available Liquid Solubility: completely soluble Color: Solubility in other solvents: No information available Green Viscosity: No information available pH: Elemental Phosphorus: 0 %P Evaporation Rate No information available 10 Odor: Fresh Minty Physical State: Boiling point/range: Not determined Dilution pH: Specific gravity: 1.026 No information available. Melting point/range: Not determined GP Forward (1:64 use solution) Bulk density: 2 of 3 Density: 8.56 lbs/gal Page 308 of 878 Page 308 of 878 Page 308 of 878 Page 308 of 878 ---PAGE BREAK--- 14. TRANSPORT INFORMATION DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), Australia (AICS), Korea (ECL), Philippines (PICCS), China (IECSC). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 STATE RIGHT TO KNOW Ingredient(s) CAS # MARTK: PARTK: RIRTK: Water 7732-18-5 - - - - CERCLA/ SARA None CAA HAP/CAA ODS/CWA Priority Pollutants: None SARA 311/312 Hazard Categories Immediate: - Delayed: - Fire: - Reactivity: - Sudden Release of Pressure: - Canada WHMIS hazard class: Non-controlled. 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: None Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 3 of 3 GP Forward (1:64 use solution) Page 309 of 878 Page 309 of 878 Page 309 of 878 Page 309 of 878 ---PAGE BREAK--- TRI-CHEM CORPORATION MATERIAL SAFETY DATA SHEET MFG.CODE # 162 SECTION I MANUFACTURER’S NAME TRI-CHEM CORPORATION EMERGENCY TELEPHONE NO. CHEMTREC [PHONE REDACTED] ADDRESS (Street, City, State and Zip Code) P.O. BOX 71550 MADISON HGTS., MI 48071-0550 CHEMICAL NAME AND SYNONYMS N/A TRADE NAME AND SYNONYMS GRAFFITI AWAY TOWELS CHEMICAL FAMILY Premoistened Towels FORMULA N/A SECTION II – HAZARDOUS INGREDIENTS HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES % TLV (UNITS) Dimethyl Glutarate (CAS# 1119-40-0) >1 N/A n-Methyl Pyrrolidine (CAS# 872-50-4) >1 not est. Dimethyl Succinate (CAS# 106-65-0) >1 N/A Dimethyl Adipate (CAS# 627-93-0) >1 N/A All components of this product are listed on the E.P.A./TSCA inventory of chemical substances. SECTION III – PHYSICAL DATA BOILING POINT °F N/A SPECIFIC GRAVITY (H2O = 1) 1.08 VAPOR PRESSURE (mm. Hg.) 0.1 PERCENT VOLATILE BY VOLUME 90 VAPOR DENSITY (AIR = 1) 1.1 EVAPORATION RATE ( n-Butyl Acetate N/A SOLUBILITY IN WATER soluble PH N/A APPEARANCE AND ODOR Light green cloth impregnated with a clear, water white liquid- no odor. SECTION IV – FIRE AND EXPLOSION DATA Lel Uel FLASH POINT (Method Used) 200+ºF T.O.C. FLAMMABLE LIMITS N/A N/A EXTINGUISHING MEDIA Dry Chemical, Carbon Dioxide, Foam, Water SPECIAL FIRE FIGHTING PROCEDURES Fire fighters should wear full protective clothing including self-contained respiratory equipment operated in a positive mode. UNUSUAL FIRE AND EXPLOSION HAZARDS None (Continued on reverse side) n-Methyl Pyrrolidine is listed as “Developmental” on the California Prop 65 Chemicals List. No conclusive detrimental data has been found to date. All other components are California Prop 65 Compliant. Page 310 of 878 Page 310 of 878 Page 310 of 878 Page 310 of 878 ---PAGE BREAK--- SECTION V – HEALTH HAZARD DATA THRESHOLD LIMIT VALUE not established PRIMARY ROUTES OF ENTRY Inhalation X Skin Contact X Other (Specify) EFFECTS OF OVEREXPOSURE Eyes- irritation. Skin- irritation. Inhalation- irritation to upper respiratory tract, dizziness, headache. Ingestion- irritation to digestive tract, nausea, cramps, vomiting. EMERGENCY AND FIRST AID PROCEDURE Eyes- flush with copious amoutns of water lifting lids and removing contact lenses to ensure complete irrigation- get medical attention. Skin- wash with soap and water, launder contaminated clothing before reuse- get medical attention if irritation persists. Inhalation- remove to fresh air and assist breathing as necessary- get medical attention. Ingestion- DO NOT INDUCE VOMITING- give water if conscious- get medical attention immediately. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None Known CARCINOGEN: No NTP IARC OTHER SECTION VI – REACTIVITY DATA UNSTABLE STABILITY STABLE X CONDITIONS TO AVOID Excessive heat, open flames INCOMPATIBILITY (Materials to avoid) Strong Oxidizers, Acids, Alkalies HAZARDOUS DECOMPOSITION PRODUCTS Oxides of Carbon and Nitrogen MAY OCCUR HAZARDOUS POLYMERIZATION WILL NOT OCCUR X CONDITIONS TO AVOID None SECTION VII – SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Pickup and place in conatiner for disposal. Flush area with water. WASTE DISPOSAL METHOD In accordance with all local, state, and federal regulations. SECTION VIII – SPECIAL PROTECTION INFORMATION SPECIAL RESPIRATORY PROTECTION (Specify type) Not required LOCAL EXHAUST normal ventilation adequate SPECIAL N/A VENTILATION MECHANICAL (General) normal ventilation adequate OTHER N/A PROTECTIVE GLOVES Impervious EYE PROTECTION Safety Glasses OTHER PROTECTIVE EQUIPMENT Eyewash and safety shower SECTION IX – SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Avoid contact- wear protective clothing and wash thoroughly after using. Avoid inhalation of vapors- use only with adequate ventilation. Do not take internally. Do not store in areas of excessive heat. Do not use near sources of ignition. OTHER PRECAUTIONS Keep container closed when not in use. Keep Out of Reach of Children. HMIS SYMBOL NAME John Telles SIGNATURE TITLE CHEMIST PREPARATION DATE May 24, 2007 PHONE NUMBER CHEMTREC [PHONE REDACTED] PAGE TWO: GRAFFITI AWAY TOWELS HEALTH 1 FLAMMABILITY 1 REACTIVITY 0 HMIS NFPA SEVERE 4 EXTREME 1 SERIOUS 3 HIGH 1 0 MODERATE 2 MODERATE SLIGHT 1 SLIGHT MINIMAL 0 INSIGNIFICANT NFPA SYMBOL TOXICITY FIRE REACTIVITY SPECIAL Page 311 of 878 Page 311 of 878 Page 311 of 878 Page 311 of 878 ---PAGE BREAK--- CP Industries 560 North 500 West Salt Lake City, Utah 84116 (801) 521-0313 (800) 453-4931 (801) 539-0510 FAX Product name: Grainger Premiere Pro Ice Melter Date prepared: January 3, 2006 Hazardous ingredients: No substances defined as hazardous present. Other ingredients: Sodium chloride CAS 7647-14-5 Calcium magnesium acetate (CMA) CAS 76123-46-1 Sodium silicates CAS 1344-09-8 Urea CAS 57-13-6 Ethanol amines CAS 102-71-6 Magnesium Chloride Hexahydrate CAS 7791-18-6 Potassium Acetate CAS 127-08-2 Physical/ chemical characteristics: Solubility in water: soluble Appearance and odor: pink solid Fire and Explosion Hazard: Product is not flammable. Not considered a fire hazard. Reactivity data: Hazardous polymerization: cannot occur Stability: stable Incompatibility: avoid contact with strong oxidizing agents. Health hazard data: Eye irritant. May irritate sensitive skin. May be harmful if swallowed, especially in large amounts because of presence of a small quantities of alkaline material. First aid procedures: Eyes: flush with water. If irritation or redness are severe or persist, consult physician. Skin: wash off with water. Ingestion: drink liquids to dilute and consult physician. Spill or leak procedures: Small spills: may be flushed away with water or swept up. Large spills: sweep or scoop up for reuse or disposal. Waste disposal methods: Small spills: may be sewered. Large spills: should be disposed of in landfill according to regulations. Protective equipment to be used: While this product is considered non-hazardous, good industrial practice suggest the use of proper eye protection and the use of gloves. Special precautions or other comments: Containers of this material may be hazardous when emptied since emptied containers retain product residues (vapor, liquid and/ or solid). All hazard precautions given in the data sheet must be observed. Note: The information accumulated herein is believed to be efficacious and accurate; however, no warranty is made with respect thereto. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Prepared to comply with OSHA hazard communication standard (29CFR 1910.1200 MATERIAL SAFETY DATA SHEET SUMSD Page 312 of 878 Page 312 of 878 Page 312 of 878 Page 312 of 878 ---PAGE BREAK--- Page 313 of 878 Page 313 of 878 Page 313 of 878 Page 313 of 878 ---PAGE BREAK--- Page 314 of 878 Page 314 of 878 Page 314 of 878 Page 314 of 878 ---PAGE BREAK--- Page 315 of 878 Page 315 of 878 Page 315 of 878 Page 315 of 878 ---PAGE BREAK--- Page 316 of 878 Page 316 of 878 Page 316 of 878 Page 316 of 878 ---PAGE BREAK--- Page 317 of 878 Page 317 of 878 Page 317 of 878 Page 317 of 878 ---PAGE BREAK--- Page 318 of 878 Page 318 of 878 Page 318 of 878 Page 318 of 878 ---PAGE BREAK--- Page 319 of 878 Page 319 of 878 Page 319 of 878 Page 319 of 878 ---PAGE BREAK--- Page 320 of 878 Page 320 of 878 Page 320 of 878 Page 320 of 878 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Pro Gun Cleaner Issue Date: 2013.09.27 Print Date: 30 Sep 2013 ®(TM)*Trademark Page 1 of 10 The Dow Chemical Company encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1. Product and Company Identification Product Name GREAT STUFF(TM) Pro Gun Cleaner COMPANY IDENTIFICATION The Dow Chemical Company 2030 Willard H. Dow Center Midland, MI 48674 United States For MSDS updates and Product Information: [PHONE REDACTED] Prepared By: Prepared for use in Canada by EH&S, Hazard Communications. Revision 2013.09.27 Print Date: 9/30/2013 Customer Information Number: [PHONE REDACTED] EMERGENCY TELEPHONE NUMBER 24-Hour Emergency Contact: [PHONE REDACTED] Local Emergency Contact: [PHONE REDACTED] 2. Hazards Identification Emergency Overview Color: Colorless Physical State: Liquid. Odor: Mild Hazards of product: WARNING! Causes eye irritation. May cause central nervous system effects; can cause death if too much is breathed. Vapor reduces oxygen available for breathing. May cause anesthetic effects. May cause respiratory tract irritation. Aspiration hazard. Can enter lungs and cause damage. Vapor explosion hazard. Isolate area. Keep upwind of spill. Warn public of downwind explosion hazard. Aerosol cans exposed to fire can rupture becoming flaming projectiles. Eliminate ignition sources. Contents under pressure. Material Safety Data Sheet The Dow Chemical Company Page 321 of 878 Page 321 of 878 Page 321 of 878 Page 321 of 878 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Pro Gun Cleaner Issue Date: 2013.09.27 Page 2 of 10 Potential Health Effects Eye Contact: May cause severe eye irritation. May cause slight corneal injury. Effects may be slow to heal. Vapor may cause eye irritation experienced as mild discomfort and redness. Skin Contact: Essentially nonirritating to skin. May cause drying and flaking of the skin. Skin Absorption: Prolonged skin contact is unlikely to result in absorption of harmful amounts. Inhalation: In confined or poorly ventilated areas, vapor can easily accumulate and can cause unconsciousness and death due to displacement of oxygen. Excessive exposure may increase sensitivity to epinephrine and increase myocardial irritability (irregular heartbeats). May cause respiratory irritation and central nervous system depression. At air concentrations <1000 ppm, propane exerts very little physiological action; at 100,000 ppm and above it may produce dizziness or other central nervous system effects. Excessive exposure may cause headache, dizziness, anesthesia, drowsiness, unconsciousness and other central nervous system effects, including death. Ingestion: Very low toxicity if swallowed. Harmful effects not anticipated from swallowing small amounts. Aspiration hazard: Aspiration into the lungs may occur during ingestion or vomiting, causing lung damage or even death due to chemical pneumonia. Effects of Repeated Exposure: Contains component(s) which have been reported to cause effects on the following organs in animals: Blood. Kidney. Liver. Development of cataracts has been reported in laboratory animals after prolonged repeated skin exposure to acetone. Birth Defects/Developmental Effects: Contains component(s) which, in laboratory animals, have been toxic to the fetus only at doses toxic to the mother. Component CAS # Amount W/W Acetone 67-64-1 60.0 - 100.0 % Propane 74-98-6 10.0 - 30.0 % Amounts are presented as percentages by weight. 4. First-aid measures Description of first aid measures General advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specific personal protective equipment. Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility. Skin Contact: Wash skin with plenty of water. Eye Contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5 minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately available. Ingestion: Do not induce vomiting. Call a physician and/or transport to emergency facility immediately. Most important and effects, both acute and delayed Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), no additional and effects are anticipated. 3. Composition/information on ingredients Page 322 of 878 Page 322 of 878 Page 322 of 878 Page 322 of 878 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Pro Gun Cleaner Issue Date: 2013.09.27 Page 3 of 10 Indication of immediate medical attention and special treatment needed Maintain adequate ventilation and oxygenation of the patient. Exposure may increase "myocardial irritability". Do not administer sympathomimetic drugs such as epinephrine unless absolutely necessary. The decision of whether to induce vomiting or not should be made by a physician. If lavage is performed, suggest endotracheal and/or esophageal control. Danger from lung aspiration must be weighed against toxicity when considering emptying the stomach. No specific antidote. Treatment of exposure should be directed at the control of and the clinical condition of the patient. Skin contact may aggravate preexisting dermatitis. 5. Fire Fighting Measures Suitable extinguishing media Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose foams (including AFFF) or protein foams may function, but will be less effective. Extinguishing Media to Avoid: Do not use direct water stream. Straight or direct water streams may not be effective to extinguish fire. Special hazards arising from the substance or mixture Hazardous Combustion Products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Carbon monoxide. Carbon dioxide. Unusual Fire and Explosion Hazards: Contains flammable propellant. Aerosol cans exposed to fire can rupture and become flaming projectiles. Propellant release may result in a fireball. Container may vent and/or rupture due to fire. Electrically ground and bond all equipment. Flammable mixtures of this product are readily ignited even by static discharge. Vaporizes quickly at room temperature. Advice for firefighters Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Water may not be effective in extinguishing fire. Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed. Immediately withdraw all personnel from the area in case of rising sound from venting safety device or discoloration of the container. Do not use direct water stream. May spread fire. Eliminate ignition sources. Move container from fire area if this is possible without hazard. Warning - flashback potential. Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). If protective equipment is not available or not used, fight fire from a protected location or safe distance. See Section 9 for related Physical Properties 6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures: Isolate area. Keep unnecessary and unprotected personnel from entering the area. Keep personnel out of confined or poorly ventilated areas. Keep upwind of spill. Spilled material may cause a slipping hazard. Ventilate area of leak or spill. Confined space entry procedures must be followed before entering the area. For large spills, warn public of downwind explosion hazard. Vapor explosion hazard. Keep out of sewers. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Refer to Section 7, Handling, for additional precautionary measures. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection. Page 323 of 878 Page 323 of 878 Page 323 of 878 Page 323 of 878 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Pro Gun Cleaner Issue Date: 2013.09.27 Page 4 of 10 Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. Methods and materials for containment and cleaning up: Contain spilled material if possible. Absorb with materials such as: Dirt. Sand. Sawdust. Pump with explosion-proof equipment. If available, use foam to smother or suppress. Collect in suitable and properly labeled containers. Wash the spill site with water. See Section 13, Disposal Considerations, for additional information. 7. Handling and Storage Handling General Handling: Avoid contact with eyes. Wash thoroughly after handling. Do not swallow. Avoid breathing vapor. Use only with adequate ventilation. Keep container closed. No smoking, open flames or sources of ignition in handling and storage area. Ignition sources can include and are not limited to pilot lights, flames, smoking, sparks, heaters, electrical equipment, and static discharges. Electrically bond and ground all containers and equipment before transfer or use of material. Contents under pressure. Do not puncture or incinerate container. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers. Use of non-sparking or explosion-proof equipment may be necessary, depending upon the type of operation. Do not enter confined spaces unless adequately ventilated. This material is hygroscopic in nature. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION. Other Precautions: Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition temperatures possibly resulting in spontaneous combustion. Storage Protect from atmospheric moisture. Store in a dry place. Avoid prolonged exposure to heat and air. Store in the following material(s): Carbon steel. Stainless steel. Polypropylene. Polyethylene-lined container. Teflon. Glass-lined container. Aluminum. Plasite 3066 lined container. Plasite 3070 lined container. 316 stainless steel. Store away from direct sunlight. Keep away from sources of ignition. Store in a cool, dry place. Keep container closed. Minimize sources of ignition, such as static build- up, heat, spark or flame. See Section 10 for more specific information. Storage Period: 36 Months 8. Exposure Controls / Personal Protection Exposure Limits Component List Type Value I Acetone CAD AB OEL TWA 1,200 mg/m3 500 ppm CAD AB OEL STEL 1,800 mg/m3 750 ppm CAD BC OEL TWA 250 ppm CAD BC OEL STEL 500 ppm CAD ON OEL TWAEV 500 ppm CAD ON OEL STEV 750 ppm ACGIH TWA 500 ppm BEI ACGIH STEL 750 ppm BEI OEL (QUE) TWA 1,190 mg/m3 500 ppm OEL (QUE) STEL 2,380 mg/m3 1,000 ppm I Propane OEL (QUE) TWA 1,800 mg/m3 1,000 ppm CAD AB OEL TWA 1,000 ppm CAD ON OEL TWAEV 1,000 ppm Page 324 of 878 Page 324 of 878 Page 324 of 878 Page 324 of 878 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Pro Gun Cleaner Issue Date: 2013.09.27 Page 5 of 10 CAD BC OEL TWA 1,000 ppm ACGIH Consult local authorities for recommended exposure limits. A BEI notation following the exposure guideline refers to a guidance value for assessing biological monitoring results as an indicator of the uptake of a substance from all routes of exposures. Personal Protection Eye/Face Protection: Use chemical goggles. If exposure causes eye discomfort, use a full-face respirator. Skin Protection: Wear clean, body-covering clothing. Hand protection: Use gloves chemically resistant to this material when prolonged or frequently repeated contact could occur. Examples of preferred glove barrier materials include: Natural rubber ("latex"). Neoprene. Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Examples of acceptable glove barrier materials include: Butyl rubber. Chlorinated polyethylene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Polyvinyl alcohol Polyvinyl chloride ("PVC" or "vinyl"). Viton. NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier. Respiratory Protection: Atmospheric levels should be maintained below the exposure guideline. Ingestion: Avoid ingestion of even very small amounts; do not consume or store food or tobacco in the work area; wash hands and face before smoking or eating. Engineering Controls Ventilation: Use engineering controls to maintain airborne level below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use only in enclosed systems or with local exhaust ventilation. Exhaust systems should be designed to move the air away from the source of vapor/aerosol generation and people working at this point. Lethal concentrations may exist in areas with poor ventilation. 9. Physical and Chemical Properties Appearance Physical State Liquid. Color Colorless Odor Mild Odor Threshold No test data available pH No test data available Melting Point No test data available Freezing Point No test data available Boiling Point (760 mmHg) No test data available. Flash Point - Closed Cup flammable Evaporation Rate (Butyl Acetate = 1) No test data available Flammability (solid, gas) Not applicable to liquids Flammable Limits In Air Lower: 2.1 Vendor Upper: 8.5 Vendor (propane) Vapor Pressure 4,482 hPa Vendor Vapor Density (air = 1) greater than air Specific Gravity (H2O = 1) 0.87 20 °C/20 °C Vendor Solubility in water (by weight) Complete Partition coefficient, n- octanol/water (log Pow) No data available for this product. See Section 12 for individual component data. Autoignition Temperature 450 °C Estimated. Decomposition Temperature No test data available Page 325 of 878 Page 325 of 878 Page 325 of 878 Page 325 of 878 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Pro Gun Cleaner Issue Date: 2013.09.27 Page 6 of 10 Kinematic Viscosity No test data available Explosive properties Not explosive Oxidizing properties No Volatile Organic Compounds 50.8 g/l 10 Wt% Supplier 10. Stability and Reactivity Reactivity No dangerous reaction known under conditions of normal use. Chemical stability Thermally stable at typical use temperatures. Possibility of hazardous reactions Polymerization will not occur. Conditions to Avoid: Elevated temperatures can cause container to vent and/or rupture. Avoid static discharge. Incompatible Materials: Avoid contact with: Acids. Bases. Oxidizers. Hazardous decomposition products Decomposition products depend upon temperature, air supply and the presence of other materials. 11. Toxicological Information Acute Toxicity Ingestion As product: Single dose oral LD50 has not been determined. Estimated. LD50, rat > 5,000 mg/kg Dermal As product: The dermal LD50 has not been determined. Estimated. LD50, rabbit > 2,000 mg/kg Inhalation As product: The LC50 has not been determined. Eye damage/eye irritation May cause severe eye irritation. May cause slight corneal injury. Effects may be slow to heal. Vapor may cause eye irritation experienced as mild discomfort and redness. Skin corrosion/irritation Essentially nonirritating to skin. May cause drying and flaking of the skin. Sensitization Skin No relevant data found. Respiratory No relevant data found. Repeated Dose Toxicity Contains component(s) which have been reported to cause effects on the following organs in animals: Blood. Kidney. Liver. Development of cataracts has been reported in laboratory animals after prolonged repeated skin exposure to acetone. Chronic Toxicity and Carcinogenicity No relevant data found. Developmental Toxicity Contains component(s) which, in laboratory animals, have been toxic to the fetus only at doses toxic to the mother. Reproductive Toxicity For the major component(s): In animal studies, did not interfere with reproduction. Page 326 of 878 Page 326 of 878 Page 326 of 878 Page 326 of 878 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Pro Gun Cleaner Issue Date: 2013.09.27 Page 7 of 10 Genetic Toxicology Genetic toxicity studies on tested components were predominantly negative. Component Toxicology - Acetone Inhalation LC50, 4 h, Vapor, rat 76 mg/l Component Toxicology - Propane Inhalation LC50, 4 h, Vapor, rat, male and female > 425,000 ppm 12. Ecological Information Toxicity Data for Component: Acetone Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested). Fish Acute & Prolonged Toxicity LC50, mykiss (rainbow trout), 96 h: 5,500 - 6,100 mg/l Aquatic Invertebrate Acute Toxicity EC50, Daphnia magna (Water flea), 48 h, immobilization: 6,084 mg/l LC50, Ceriodaphnia Dubia (water flea), 48 h: 8,098 mg/l Aquatic Plant Toxicity EC50, Skeletonema costatum, biomass growth inhibition, 5 d: 11,800 - 14,400 mg/l Toxicity to Micro-organisms EC50, activated sludge test (OECD 209), Respiration inhibition, 3 h: > 1,000 mg/l Data for Component: Propane No relevant data found. Persistence and Degradability Data for Component: Acetone Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. OECD Biodegradation Tests: Biodegradation Exposure Time Method 10 Day Window 91 % 28 d OECD 301B Test pass Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 2.04E-13 cm3/s 52 d Estimated. Theoretical Oxygen Demand: 2.20 mg/mg Data for Component: Propane No relevant data found. Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 1.27E-12 cm3/s 8.4 d Estimated. Theoretical Oxygen Demand: 3.64 mg/mg Bioaccumulative potential Data for Component: Acetone Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < Partition coefficient, n-octanol/water (log Pow): -0.24 Measured Bioconcentration Factor (BCF): 0.69; Fish; Measured Data for Component: Propane Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < Partition coefficient, n-octanol/water (log Pow): 2.36 Measured Page 327 of 878 Page 327 of 878 Page 327 of 878 Page 327 of 878 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Pro Gun Cleaner Issue Date: 2013.09.27 Page 8 of 10 Mobility in soil Data for Component: Acetone Mobility in soil: Potential for mobility in soil is very high (Koc between 0 and 50). Partition coefficient, soil organic carbon/water (Koc): 0.37 - 2.0 Estimated. Henry's Law Constant 1.38E-05 atm*m3/mole; 25 °C Estimated. Distribution in Environment: Mackay Level 1 Fugacity Model: Air Water. Biota Soil Sediment 44.3 % 55.6 % < 0.1 % < 0.1 % < 0.1 % Data for Component: Propane Mobility in soil: Potential for mobility in soil is very high (Koc between 0 and 50). Partition coefficient, soil organic carbon/water (Koc): 24 - 460 Estimated. Henry's Law Constant 7.07E-01 atm*m3/mole; 25 °C Measured Distribution in Environment: Mackay Level 1 Fugacity Model: Air Water. Biota Soil Sediment 100 % 0 % 0 % 0 % 0 % 13. Disposal Considerations DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed, permitted: Recycler. Reclaimer. Incinerator or other thermal destruction device. For additional information, refer to: Handling & Storage Information, MSDS Section 7 Stability & Reactivity Information, MSDS Section 10 Regulatory Information, MSDS Section 15 14. Transport Information TDG Small container Proper Shipping Name: AEROSOLS Hazard Class: 2.1 ID Number: UN1950 LIMITED QUANTITY TDG Large container Proper Shipping Name: AEROSOLS Hazard Class: 2.1 ID Number: UN1950 IMDG Proper Shipping Name: AEROSOLS Hazard Class: 2 ID Number: UN1950 EMS Number: F-D,S-U Marine pollutant.: No LIMITED QUANTITY ICAO/IATA Proper Shipping Name: AEROSOLS, FLAMMABLE Hazard Class: 2.1 ID Number: UN1950Cargo Packing Instruction: 203 Page 328 of 878 Page 328 of 878 Page 328 of 878 Page 328 of 878 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Pro Gun Cleaner Issue Date: 2013.09.27 Page 9 of 10 Passenger Packing Instruction: 203 LIMITED QUANTITY HAZCHEM CODE: 2YE 15. Regulatory Information US. Toxic Substances Control Act All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.30 CEPA - Domestic Substances List (DSL) All substances contained in this product are listed on the Canadian Domestic Substances List (DSL) or are not required to be listed. Hazardous Products Act Information: CPR Compliance This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. Hazardous Products Act Information: WHMIS Classification A Compressed Gas B1 Flammable Gas D2B Eye or Skin Irritant Hazardous Products Act Information: Hazardous Ingredients This product contains the following ingredients which are Controlled Products and/or are on the Ingredient Disclosure List (Canadian HPA Section 13 and 14). Component CAS # Amount W/W Acetone 67-64-1 60.0 - 100.0 % Propane 74-98-6 10.0 - 30.0 % 16. Other Information Recommended Uses and Restrictions Identified uses Cleaner. We recommend that you use this product in a manner consistent with the listed use. If your intended use is not consistent with the stated use, please contact your sales or technical service representative. Revision Identification Number: 64097 / 0000 / Issue Date 2013.09.27 / Version: 3.0 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. Legend N/A Not available W/W Weight/Weight OEL Occupational Exposure Limit STEL Short Term Exposure Limit TWA Time Weighted Average ACGIH American Conference of Governmental Industrial Hygienists, Inc. DOW IHG Dow Industrial Hygiene Guideline Page 329 of 878 Page 329 of 878 Page 329 of 878 Page 329 of 878 ---PAGE BREAK--- Product Name: GREAT STUFF(TM) Pro Gun Cleaner Issue Date: 2013.09.27 Page 10 of 10 WEEL Workplace Environmental Exposure Level HAZ_DES Hazard Designation VOL/VOL Volume/Volume The Dow Chemical Company urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version. Page 330 of 878 Page 330 of 878 Page 330 of 878 Page 330 of 878 ---PAGE BREAK--- 748 M A T E R I A L S A F E T Y D A T A S H E E T Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 Date of Prep: 8/26/08 SECTION 1 SUNNYSIDE CORPORATION FOR INFORMATION: (847) 541-5700 225 CARPENTER AVENUE WHEELING, ILLINOIS 60090 (847) 541-5700 - SUNNYSIDE CORPORATION EMERGENCY TELEPHONE (800) 424-9300 - CHEM TREC Product Class: Surfactants Manufacturer's Code: 748 Trade Name: Green Envy Driveway Cleaner & Degreaser NPCA HMIS: Health: 2 Flammability: 0 Reactivity: 0 Product Appearance and Odor: Clear liquid; mild odor. SECTION 2 HAZARDOUS INGREDIENTS OCCUPATIONAL EXPOSURE LIMITS ACGIH ACGIH OSHA OSHA INGREDIENT CAS # PERCENT TLV TLV PEL PEL VAPOR PRESSURE (TWA) (STEL) (TWA) (STEL) Alcohols, Ethyoxylated, C9- C11 68439-46-3 Not Est. Not Est. Not Est. Not Est. Not Available Monosodium Salt of Alkyl Iminoacid Not available Not Est. Not Est. Not Est. Not Est. Not Available Methyl Dihydroxyethyl- Isotridecyloxypropyl Ammonium Chloride 68610-19-5 Not Est. Not Est. Not Est. Not Est. Not Available Sodium Metasilicate Pentahydrate 6834-92-0 Not Est. Not Est. Not Est. Not Est. Not Applicable SECTION 3 EMERGENCY AND FIRST AID PROCEDURES Inhalation: Remove to fresh air. If breathing is difficult, have trained person administer oxygen. If respiration stops, give mouth-to-mouth resuscitation. Get medical attention immediately. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes forcibly holding lids apart to ensure complete irrigation of all eye and lid tissue. Washing eyes within one minute is essential to achieve maximum effectiveness. Seek medical attention immediately, preferably from an ophthalmologist. Skin Contact: Remove contaminated clothing and shoes immediately. Wash affected area with large amounts of cool water and soap for at least 15 to20 minutes. Obtain medical attention if irritation persists. Discard non-rubber shoes. Wash clothing before reuse. Ingestion: Get medical attention as soon as possible. If swallowed, do not induce vomiting. If patient is fully conscious, give large quantities of water. If vomiting occurs spontaneously, keep airway clear. SECTION 4 PHYSICAL DATA The following data represent approximate or typical values. They do not constitute product specifications. Boiling Range: 212° F. Vapor Density: Heavier than air Evaporation Rate: Slower than ether % Volatile By Volume: Not determined Weight Per Gallon: 8.50 lbs. Solubility in Water: Negligible PH: 12.5 Page 331 of 878 Page 331 of 878 Page 331 of 878 Page 331 of 878 ---PAGE BREAK--- Trade Name: GREEN ENVY DRIVEWAY CLEANER & DEGREASER Page 2 of 3 SECTION 5 FIRE AND EXPLOSION DATA Flammability Classification: Non-flammable. Flash Point: Not applicable Lower Explosive Limit: Not applicable Extinguishing Media: Use water spray, dry chemical, fog, carbon dioxide, foam or other agents as appropriate for surrounding fire. Unusual Fire and Explosion Hazards: Do not store or mix with strong oxidants. Special Fire Fighting Procedures: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Use water spray to keep fire-exposed containers cool. SECTION 6 HEALTH HAZARD DATA THRESHOLD LIMIT VALUE: See Section 2. EFFECTS OF OVEREXPOSURE Eye Contact: Will cause tissue destruction and eye damage if not treated. Skin Contact: May cause itching and redness; prolonged contact may cause dermatitis. Ingestion: Causes severe irritation and possible tissue damage to mucous membranes of the mouth, throat, esophagus and stomach. Inhalation: Vapors are unlikely due to physical properties. Carcinogenicity: Components of this product have not been identified as carcinogens by NTP, IARC, or OSHA. SECTION 7 REACTIVITY DATA Stability: Stable Conditions to Avoid: Prolonged excessive heat may cause product decomposition. Incompatibility (Materials to Avoid): This product is alkaline – avoid contact with acidic materials and strong oxidizing agents. Prolonged contact with metals such as aluminum, tin, lead and zinc may produce flammable hydrogen gas. Hazardous Decomposition Products: Thermal decomposition may yield carbon dioxide and carbon monoxide. Hazardous Polymerization: Will not occur. SECTION 8 SPILL OR LEAK PROCEDURES Steps to be taken in case material is spilled or released: Wear eye and skin protection. Floor may be slippery; use care to avoid falling. Leaks should be stopped. Spills should be contained and scooped up immediately with inert materials (e.g. sand, earth) and placed in approved containers for disposal. Flush spill area with water. Waste disposal method: Consult local, state and federal regulations before disposing of this material.. SECTION 9 SAFE HANDLING AND USE INFORMATION Respiratory Protection: Not required under normal use, but if vapor concentration become high, use self-contained air mask. Ventilation: Use adequate ventilation. Protective Gloves: Chemically resistant gloves. Eye Protection: Safety glasses should be warn. Other Protective Equipment: Eye wash and safety shower in work areas. Handling and Storage Precautions: Do not store in aluminum container as flammable hydrogen gas can be generated. Do not use aluminum fittings or transfer lines. Avoid contact with acids. Page 332 of 878 Page 332 of 878 Page 332 of 878 Page 332 of 878 ---PAGE BREAK--- Trade Name: GREEN ENVY DRIVEWAY CLEANER & DEGREASER Page 3 of 3 SECTION 10 SPECIAL PRECAUTIONS Dept. of Labor Storage Category: Non-flammable. Keep containers closed when not in use. Avoid eye contact. Avoid prolonged or repeated contact with skin. Wash skin with soap and water after contact. Empty Container Warning: “Empty” containers retain residue (liquid and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind or expose such containers to heat, flame, sparks or other sources of ignition. They may explode and cause injury or death. Do not attempt to clean since residue is difficult to remove. “Empty” drums should be completely drained, properly bunged and returned to supplier or disposed of in an environmentally safe manner and in accordance with governmental regulations. SECTION 11 ADDITIONAL INFORMATION This product contains the following toxic chemical(s) which are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: TOXIC CHEMICAL C AS # A PPROXIMATE % BY WEIGHT N ot Applicable N ot Applicable N ot Applicable S ARA Title III Hazard Categories: Immediate (Acute) Health Hazard C ommon Names: W ater based cleaner/degreaser TRANSPORTATION Not regulated by the U.S. D.O.T. as a hazardous material. Page 333 of 878 Page 333 of 878 Page 333 of 878 Page 333 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET GUM REMOVER 1. PRODUCT AND COMPANY IDENTIFICATION Product name: GUM REMOVER MSDS 126330001 Product Code: 05257, 04198 Recommended use: Carpet Care. Emergency telephone number: 1-[PHONE REDACTED] (Prosar); 1-[PHONE REDACTED] (Int'l Prosar); 01-[PHONE REDACTED] (México) 2. HAZARDS IDENTIFICATION Principle routes of exposure: Eye contact. Skin contact. Inhalation. Eye contact: May be mildly irritating to eyes. Skin contact: May be mildly irritating to skin. Inhalation: None Ingestion: None known. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous ingredients Ingredient(s) CAS # Weight % LD50 Oral - Rat (mg/kg) LD50 Dermal - Rabbit LC50 Inhalation - Rat 1,1,1,2-tetrafluoroethane 811-97-2 90 - 100% Not available Not available Not available Pentane 109-66-0 10 - 20% Not available =3000 mg/kg =364 g/m3 (4 h) 4. FIRST AID MEASURES Eye contact: Flush immediately with plenty of water. If irritation develops, get medical attention. Skin contact: Flush immediately with plenty of water. If irritation develops, get medical attention. Inhalation: No specific first aid measures are required. Ingestion: No specific first aid measures are required. Aggravated Medical Conditions: None known. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: The product is not flammable. Extinguish fire using agent suitable for surrounding fire. Specific hazards: Aerosol product - Containers may rocket or explode in heat of fire. Unusual hazards: None known Specific methods: Aerosol Product - Containers may rocket or expode in heat of fire. Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: No information available HMIS EMERGENCY OVERVIEW CAUTION. MAY BE MILDLY IRRITATING TO EYES. MAY BE MILDLY IRRITATING TO SKIN. NFPA Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-0902 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.johnsondiversey.com Version Number: 1 Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] GUM REMOVER Preparation date: 2008-03-07 1 of 3 Personal protective equipment 1 Fire Hazard None / Aucune / Ninguno 0 1 Health 0 Reactivity 0 0 Page 334 of 878 Page 334 of 878 Page 334 of 878 Page 334 of 878 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Use personal protective equipment Environmental precautions and clean-up methods: Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use a water rinse for final clean-up. 7. HANDLING AND STORAGE Handling: Avoid contact with skin and eyes. Do not spray towards face . CONTENTS UNDER PRESSURE. Do not puncture or incinerate. Use only in well- ventilated areas. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 degrees C or 120 degrees F. Do not pierce or burn, even after use. Do not pierce or burn, even after use . KEEP OUT OF REACH OF CHILDREN. NFPA 30B Level 1 Aerosol . 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: No special ventilation requirements. General room ventilation is adequate. Personal Protective Equipment Eye protection: No special requirements under normal use conditions. Hand protection: No special requirements under normal use conditions Skin and body protection: No special requirements under normal use conditions. Respiratory protection: No special requirements under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Ingredient(s) CAS # ACGIH OSHA Mexico Pentane 109-66-0 600 ppm (TWA) 1000 ppm (TWA) 2950 mg/m3 (TWA) 760 ppm (STEL) 2250 mg/m3 (STEL) 600 ppm (TWA) 1800 mg/m3 (TWA) 9. PHYSICAL AND CHEMICAL PROPERTIES * - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 10. STABILITY AND REACTIVITY Stability: The product is stable Polymerization: Hazardous polymerization does not occur Hazardous decomposition products: None reasonably foreseeable. Materials to avoid: direct sunlight . Conditions to avoid: Strong sunlight for prolonged periods.. 11. TOXICOLOGICAL INFORMATION Acute toxicity: Oral LD50 estimated to be greater than 5000 mg/kg Dermal LD50 estimated to be > 2000 mg/kg Component Information: See Section 3 Chronic toxicity: None known Specific effects Carcinogenic effects: None known Mutagenic effects: None known Reproductive toxicity: None known Target organ effects: None known Not determined Dilution pH: Specific gravity: 1.11 Not applicable Melting point/range: Not determined Bulk density: Density: 9.30 lbs/gal Appearance: Decomposition temperature: Not determined Aerosol VOC: 10% * No information available Autoignition temperature: No information available Vapor density: Flash point: >200°F >93.3°C No information available Partition coefficient (n-octanol/water): No information available Aerosol Solubility: Insoluble Color: Solubility in other solvents: No information available Clear Colorless Viscosity: No information available pH: Elemental Phosphorus: 0 %P Evaporation Rate No information available Not applicable Odor: Hydrocarbon GUM REMOVER 2 of 3 Physical State: Boiling point/range: Page 335 of 878 Page 335 of 878 Page 335 of 878 Page 335 of 878 ---PAGE BREAK--- 12. ECOLOGICAL INFORMATION Environmental Information: No data available 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Dispose of according to all federal, state and local applicable regulations 14. TRANSPORT INFORMATION DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), New Zealand (NZIoC), China (IECSC). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 STATE RIGHT TO KNOW Ingredient(s) CAS # MARTK: PARTK: RIRTK: Pentane 109-66-0 X X X X 1,1,1,2-tetrafluoroethane 811-97-2 - X - - CERCLA/ SARA SARA 311/312 Hazard Categories Immediate: - Delayed: - Fire: - Reactivity: - Sudden Release of Pressure: X Canada WHMIS hazard class: A Compressed gases. 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: None Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 3 of 3 GUM REMOVER Page 336 of 878 Page 336 of 878 Page 336 of 878 Page 336 of 878 ---PAGE BREAK--- Page 337 of 878 Page 337 of 878 Page 337 of 878 Page 337 of 878 ---PAGE BREAK--- Page 338 of 878 Page 338 of 878 Page 338 of 878 Page 338 of 878 ---PAGE BREAK--- Page 339 of 878 Page 339 of 878 Page 339 of 878 Page 339 of 878 ---PAGE BREAK--- Page 340 of 878 Page 340 of 878 Page 340 of 878 Page 340 of 878 ---PAGE BREAK--- Page 341 of 878 Page 341 of 878 Page 341 of 878 Page 341 of 878 ---PAGE BREAK--- Page 342 of 878 Page 342 of 878 Page 342 of 878 Page 342 of 878 ---PAGE BREAK--- Page 343 of 878 Page 343 of 878 Page 343 of 878 Page 343 of 878 ---PAGE BREAK--- Page 344 of 878 Page 344 of 878 Page 344 of 878 Page 344 of 878 ---PAGE BREAK--- Page 345 of 878 Page 345 of 878 Page 345 of 878 Page 345 of 878 ---PAGE BREAK--- Page 346 of 878 Page 346 of 878 Page 346 of 878 Page 346 of 878 ---PAGE BREAK--- Page 347 of 878 Page 347 of 878 Page 347 of 878 Page 347 of 878 ---PAGE BREAK--- Page 348 of 878 Page 348 of 878 Page 348 of 878 Page 348 of 878 ---PAGE BREAK--- Page 349 of 878 Page 349 of 878 Page 349 of 878 Page 349 of 878 ---PAGE BREAK--- Industrial Blue Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision Date: 10/21/2014 Version: 1.0 10/21/2014 EN (English US) 1/6 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Mixture Product Name: Industrial Blue Synonyms: Industrial Blue Premium Blended Ice Melting Compound contains a proprietary combination of Sodium Chloride, Calcium Chloride, liquid Magnesium Chloride with Corrosion Inhibitor & blue dye pigment 1.2. Intended Use of the Product Melting Ice 1.3. Name, Address, and Telephone of the Responsible Party Company Scotwood Industries, Inc. 12980 Metcalf Ave. STE 240 Overland Park, Kansas 66213 Office: (913) 851-3500 Toll Free: (800) 844-2022 Fax: (913) 851-3377 1.4. Emergency Telephone Number Emergency Number : (800)-424-9300 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Eye Irrit. 2A H319 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) : GHS07 Signal Word (GHS-US) : Warning Hazard Statements (GHS-US) : H319 - Causes serious eye irritation. Precautionary Statements (GHS-US) : P264 - Wash hands, forearms, and other exposed areas thoroughly after handling. P280 - Wear protective gloves, protective clothing, eye protection, face protection, respiratory protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical advice/attention. 2.3. Other Hazards Other Hazards: Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions. When heated to decomposition, emits irritating fumes. Corrosive to metals upon prolonged contact. Contact with water causes an exothermic heat reaction, which may cause significant temperature rise. 2.4. Unknown Acute Toxicity (GHS-US) No data available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification (GHS-US) Sodium chloride (CAS No) 7647-14-5 Proprietary Not classified Magnesium chloride (CAS No) 7786-30-3 Proprietary Not classified Calcium chloride (CAS No) 10043-52-4 Proprietary Acute Tox. 4 (Oral), H302 Eye Irrit. 2A, H319 Page 350 of 878 Page 350 of 878 Page 350 of 878 Page 350 of 878 ---PAGE BREAK--- Industrial Blue Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/21/2014 EN (English US) 2/6 Potassium chloride (CAS No) 7447-40-7 Proprietary Aquatic Acute 3, H402 The specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. Full text of H-phrases: see section 16 SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid Measures After Inhalation: When occur: go into open air and ventilate suspected area. Remove to fresh air and keep at rest in a position comfortable for breathing. Obtain medical attention if breathing difficulty persists. First-aid Measures After Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 15 minutes. Obtain medical attention if irritation persists. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if irritation develops or persists. First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. 4.2. Most important and effects, both acute and delayed Causes eye irritation. After Inhalation: May cause respiratory irritation. After Skin Contact: Skin contact with large amounts of dust may cause mechanical irritation. After Eye Contact: Causes eye irritation. After Ingestion: Ingestion is likely to be harmful or have adverse effects. 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned, get medical advice and attention. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire. Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Not considered flammable but may burn at high temperatures. Explosion Hazard: Product is not explosive. Reactivity: When heated to decomposition, emits irritating fumes. 5.3. Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Firefighting Instructions: Use water spray or fog for cooling exposed containers. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Other information: Do not allow run-off from fire fighting to enter drains or water courses. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Avoid breathing (dust, fumes). Avoid all contact with skin, eyes, or clothing. 6.1.1. For Non-emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. 6.1.2. For Emergency Responders Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Ventilate area. 6.2. Environmental Precautions Prevent entry to sewers and public waters. Avoid release to the environment. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Contain and collect as any solid. Methods for Cleaning Up: Clear up spills immediately and dispose of waste safely. Recover the product by vacuuming, shoveling or sweeping. Contact competent authorities after a spill. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. Page 351 of 878 Page 351 of 878 Page 351 of 878 Page 351 of 878 ---PAGE BREAK--- Industrial Blue Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/21/2014 EN (English US) 3/6 SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: When heated to decomposition, emits irritating fumes. Contact with water causes an exothermic heat reaction, which may cause significant temperature rise. Precautions for Safe Handling: Do not breathe vapors, mist, spray. Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking, or smoking and again when leaving work. Do no eat, drink or smoke when using this product. Wash hands and forearms thoroughly after handling. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Comply with applicable regulations. Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Keep/Store away from extremely high or low temperatures, direct sunlight, heat, ignition sources, incompatible materials. Incompatible Products: Strong acids. Strong bases. Strong oxidizers. reactive metals. Special Rules on Packaging: Keep only in original container. Packaging materials: Store in corrosive resistant container with a resistant inner liner. 7.3. Specific End Use(s) Melting ice. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters No additional information available. 8.2. Exposure Controls Appropriate Engineering Controls : Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure all national/local regulations are observed. Ensure adequate ventilation, especially in confined areas. Personal Protective Equipment : Protective goggles. Protective clothing. Gloves. Materials for Protective Clothing : Chemically resistant materials and fabrics. Corrosionproof clothing. Hand Protection : Wear chemically resistant protective gloves. Eye Protection : Chemical goggles or face shield. Skin and Body Protection : Wear suitable protective clothing. Respiratory Protection : Not required under normal conditions of use. Other Information : When using, do not eat, drink or smoke. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State : Solid Appearance : Light blue and light grey dry granules, white and light blue flake. Odor : Minimal Odor Odor Threshold : No data available pH : No data available Evaporation rate : No data available Melting Point : No data available Freezing Point : No data available Boiling Point : No data available Flash Point : No data available Auto-ignition Temperature : No data available Decomposition Temperature : No data available Flammability (solid, gas) : No data available Vapor Pressure : No data available Relative Vapor Density at 20 °C : No data available Relative Density : No data available Specific Gravity : 2.076 Page 352 of 878 Page 352 of 878 Page 352 of 878 Page 352 of 878 ---PAGE BREAK--- Industrial Blue Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/21/2014 EN (English US) 4/6 Solubility : 317 gpl @ 0° C (32°F) Partition coefficient: n-octanol/water : No data available Viscosity : No data available 9.2. Other Information No additional information available SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity: When heated to decomposition, emits irritating fumes. 10.2 Chemical Stability: Stable under normal conditions. 10.3 Possibility of Hazardous Reactions: Hazardous polymerization will not occur. 10.4 Conditions to Avoid: Direct sunlight. Extremely high or low temperatures. Incompatible materials. 10.5 Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Reactive metals. 10.6 Hazardous Decomposition Products: Hydrogen chloride. Chlorine. Sodium oxides. Oxides of magnesium. Oxides of calcium. Potassium oxides. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information On Toxicological Effects Acute Toxicity: Not classified Sodium chloride (7647-14-5) LD50 Oral Rat 3 g/kg LC50 Inhalation Rat > 42 g/m³ (Exposure time: 1 h) Magnesium chloride (7786-30-3) LD50 Oral Rat 2800 mg/kg LD50 Dermal Rat > 2000 mg/kg Calcium chloride (10043-52-4) LD50 Oral Rat 1000 mg/kg LD50 Dermal Rat 2630 mg/kg ATE (Oral) 1,000.00 mg/kg body weight Potassium chloride (7447-40-7) LD50 Oral Rat 2600 mg/kg ATE (Oral) 2,600.00 mg/kg body weight Skin Corrosion/Irritation: Not classified Serious Eye Damage/Irritation: Causes serious eye irritation. Respiratory or Skin Sensitization: Not classified Germ Cell Mutagenicity: Not classified Carcinogenicity: Not classified Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): Not classified Specific Target Organ Toxicity (Repeated Exposure): Not classified Aspiration Hazard: Not classified After Inhalation: May cause respiratory irritation. After Skin Contact: Skin contact with large amounts of dust may cause mechanical irritation. After Eye Contact: Causes eye irritation. After Ingestion: Ingestion is likely to be harmful or have adverse effects. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Sodium chloride (7647-14-5) LC50 Fish 1 5560 (5560 - 6080) mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [flow- through]) EC50 Daphnia 1 1000 mg/l (Exposure time: 48 h - Species: Daphnia magna) LC 50 Fish 2 12946 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) EC50 Daphnia 2 340.7 (340.7 - 469.2) mg/l (Exposure time: 48 h - Species: Daphnia magna [Static]) Magnesium chloride (7786-30-3) LC50 Fish 1 1970 - 3880 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) EC50 Daphnia 1 140 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static]) Page 353 of 878 Page 353 of 878 Page 353 of 878 Page 353 of 878 ---PAGE BREAK--- Industrial Blue Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/21/2014 EN (English US) 5/6 Calcium chloride (10043-52-4) LC50 Fish 1 10650 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) EC50 Daphnia 1 2400 mg/l (Exposure time: 48 h - Species: Daphnia magna) Potassium chloride (7447-40-7) LC50 Fish 1 1060 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) EC50 Daphnia 1 825 mg/l (Exposure time: 48 h - Species: Daphnia magna) LC 50 Fish 2 750 - 1020 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) EC50 Daphnia 2 83 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static]) 12.2. Persistence and Degradability No additional information available 12.3. Bioaccumulative Potential Industrial Blue Bioaccumulative Potential Not established. Sodium chloride (7647-14-5) BCF fish 1 (no bioaccumulation) Calcium chloride (10043-52-4) BCF fish 1 (no bioaccumulation) 12.4. Mobility in Soil No additional information available 12.5. Other Adverse Effects Other Information : Avoid release to the environment. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, and international regulations. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Not regulated for transport 14.2 In Accordance with IMDG Not regulated for transport 14.3 In Accordance with IATA Not regulated for transport SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations Industrial Blue SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Sodium chloride (7647-14-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory Magnesium chloride (7786-30-3) Listed on the United States TSCA (Toxic Substances Control Act) inventory Calcium chloride (10043-52-4) Listed on the United States TSCA (Toxic Substances Control Act) inventory Potassium chloride (7447-40-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2 US State Regulations Sodium chloride (7647-14-5) U.S. - Texas - Effects Screening Levels - Long Term U.S. - Texas - Effects Screening Levels - Short Term Magnesium chloride (7786-30-3) U.S. - Texas - Effects Screening Levels - Long Term U.S. - Texas - Effects Screening Levels - Short Term Calcium chloride (10043-52-4) U.S. - Texas - Effects Screening Levels - Long Term U.S. - Texas - Effects Screening Levels - Short Term Potassium chloride (7447-40-7) U.S. - Texas - Effects Screening Levels - Long Term Page 354 of 878 Page 354 of 878 Page 354 of 878 Page 354 of 878 ---PAGE BREAK--- Industrial Blue Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10/21/2014 EN (English US) 6/6 U.S. - Texas - Effects Screening Levels - Short Term SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date : 10/21/2014 Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200. The specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. GHS Full Text Phrases: Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4 Aquatic Acute 3 Hazardous to the aquatic environment - Acute Hazard Category 3 Eye Irrit. 2A Serious eye damage/eye irritation Category 2A H302 Harmful if swallowed H319 Causes serious eye irritation H402 Harmful to aquatic life This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. SDS US (GHS HazCom) - US Page 355 of 878 Page 355 of 878 Page 355 of 878 Page 355 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Instant FOAM Hand Sanitiser Page: 1 of 4 Issued: 12/02/2009 Revision No: 2 IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING Product name: Instant FOAM Hand Sanitiser Use / description of product: Skin Sanitiser. Manufacturer’s Product Code: Code dependant on pack size. Company name: DEB Australia Pty Ltd 73 Alfred Road Chipping Norton NSW 2170 Tel: 1800 090 330 Fax: 1800 090 340 Email: www.deb.com.au or [EMAIL REDACTED] A.B.N. 79 003 964 681 1. COMPOSITION / INFORMATION ON INGREDIENTS Contains: Ethyl alcohol Aqua n-Propanol Coco-glucoside Glyceryl Oleate PEG-7 Glyceryl Cocoate PEG-200 Hydrogenated Glyceryl Palmate PEG-5 Linoleammonium Chloride Behentrimonium Chloride Bis-PEG-12 Dimethicone Isopropyl Alcohol 2. HAZARDS IDENTIFICATION Main hazards: Classified as hazardous according to criteria of Worksafe Australia. Highly Flammable 3. FIRST AID MEASURES Skin contact: Not applicable. Eye contact: There may be irritation, redness and inflammation. Ingestion: Inhalation of the fumes from the stomach may cause similar to direct inhalation. Inhalation: Fumes or vapour may cause irritation, nausea or drowsiness. 4. FIRST AID MEASURES (ACTION) Skin contact: Not applicable. Eye contact: Irrigate with copious quantities of water for 15 minutes. If soreness or irritation persists seek medical attention. Ingestion: Give plenty of liquid to drink. Do not induce vomiting. If vomiting occurs, give further liquid and seek medical attention. Inhalation: Remove to fresh air and seek medical advice if persist. Page 356 of 878 Page 356 of 878 Page 356 of 878 Page 356 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Instant FOAM Hand Sanitiser Page: 2 of 4 Issued: 12/02/2009 Revision No: 2 5. FIRE FIGHTING MEASURES Extinguishing media: Carbon dioxide. Alcohol resistant foam. Dry chemical powder. Do not use water. Protection of fire fighters: Wear self contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Refer to section 8 of the MSDS for personal protection details. Clean-up procedures: In the event of spillage mop up bulk and dilute remainder to foul drain with water. Treat large spillages as industrial waste. 7. HANDLING AND STORAGE Handling requirements: Do not mix with any other material other than water, as directed. If the product is to be used for any other purpose other than that stated on the label, contact Technical Services (02) 9794 7720, to check suitability. Storage conditions: Store in a cool dry area. Protect from extremes of temperature. Suitable packaging: Must only be kept in original packaging. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Respiratory protection: Not applicable. Hand protection: Not applicable. Eye protection: Not applicable. Skin protection: Not applicable. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Colourless liquid. Odour: Alcoholic. Solubility in water: Soluble. Flash Point: 21˚C. pH: 5.0 to 7.5 Viscosity: Non-Viscous. 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions. Conditions to avoid: Sources of ignition. Avoid extremes of temperature. Page 357 of 878 Page 357 of 878 Page 357 of 878 Page 357 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Instant FOAM Hand Sanitiser Page: 3 of 4 Issued: 12/02/2009 Revision No: 2 11. TOXOCOLOGICAL INFORMATION Routes of Exposure: Eye contact may cause irritation. Inhalation – Excessive exposure may cause drowsiness or dizziness. Ingestion – may cause nausea, irritation to the digestive system may occur. 12. ECOLOGICAL INFORMATION Persistence and degradability: Major ingredients are biodegradable and will not accumulate in soil or water or cause long term problems. 13. DISPOSAL CONSIDERATIONS Disposal of packaging: Drain well. Recycle containers if possible, consult manufacturer for recycling options or dispose of in an authorised landfill. Consult State Land Waste Management Authority for disposal. 14. TRANSPORT INFORMATION UN no: 1987 Dangerous Goods Class: 3 Flammable Liquid Packing Group: II Shipping Name: ALCOHOLS, N.O.S. (ETHANOL, PROPYL ALCOHOL) Hazchem code: 3[Y]E 15. REGULATORY INFORMATION Hazard symbols: Highly flammable. Risk phrases: R11: Highly flammable. Safety phrases: S25: Avoid contact with eyes. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S46: If swallowed, seek medical advice and show this container or label. Contact 131126 NSW POISONS INFORMATION CENTRE Note: The regulatory information above only indicates the principal regulations specifically applicable to the product described in the material safety data sheet. The user’s attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all applicable national, international and local regulations or provisions. Page 358 of 878 Page 358 of 878 Page 358 of 878 Page 358 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Instant FOAM Hand Sanitiser Page: 4 of 4 Issued: 12/02/2009 Revision No: 2 16. ADDITIONAL INFORMATION Contact Point: Deb Australia Pty Ltd. – (02) 9794 7700 Legal Disclaimer: This Material Safety Data Sheet summarises at the date of issue, our best knowledge of the health and safety hazard information of the product and in particular, how to safely handle and use the product in the workplace. Since Deb Australia Pty. Ltd. cannot anticipate or control the conditions under which the product is used, each user must prior to usage, review this Material Safety Data Sheet in context of how the user intends to handle and use the product in the workplace. Page 359 of 878 Page 359 of 878 Page 359 of 878 Page 359 of 878 ---PAGE BREAK--- Page 360 of 878 Page 360 of 878 Page 360 of 878 Page 360 of 878 ---PAGE BREAK--- Page 361 of 878 Page 361 of 878 Page 361 of 878 Page 361 of 878 ---PAGE BREAK--- Page 362 of 878 Page 362 of 878 Page 362 of 878 Page 362 of 878 ---PAGE BREAK--- Page 363 of 878 Page 363 of 878 Page 363 of 878 Page 363 of 878 ---PAGE BREAK--- Page 364 of 878 Page 364 of 878 Page 364 of 878 Page 364 of 878 ---PAGE BREAK--- page 1 of 3 UEL N.A. LEL N.A. FLASH POINT Not Applicable HMIS Codes Health 2 Flammability 0 Reactivity 0 DATE OF PREPARATION Nov 28, 2010 MATERIAL SAFETY DATA SHEET 8000(40) 23 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER 8000(40) PRODUCT NAME Interior/Exterior DTM 100% Acrylic Gloss Industrial Enamel, Accent Base MANUFACTURER'S NAME Conco Paints 101 Prospect Avenue N.W. Cleveland, OH 44115 Telephone Numbers and Websites Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident) * SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 5 111-77-3 2-(2-Methoxyethoxy)-ethanol ACGIH TLV Not Available 1 mm OSHA PEL Not Available SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam Page 365 of 878 Page 365 of 878 Page 365 of 878 Page 365 of 878 ---PAGE BREAK--- 8000(40) page 2 of 3 UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 8.52 lb/gal 1021 g/l SPECIFIC GRAVITY 1.03 BOILING POINT 212 - 500 °F 100 - 260 °C MELTING POINT Not Available VOLATILE VOLUME 66% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 9.5 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 1.69 lb/gal 203 g/l Less Water and Federally Exempt Solvents 0.72 lb/gal 86 g/l Emitted VOC Page 366 of 878 Page 366 of 878 Page 366 of 878 Page 366 of 878 ---PAGE BREAK--- 8000(40) page 3 of 3 SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. TOXICOLOGY DATA CAS No. Ingredient Name 111-77-3 2-(2-Methoxyethoxy)-ethanol LC50 RAT 4HR Not Available LD50 RAT 5500 mg/kg SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element Glycol Ethers 5 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 367 of 878 Page 367 of 878 Page 367 of 878 Page 367 of 878 ---PAGE BREAK--- page 1 of 5 HMIS Codes Health 2* Flammability 3 Reactivity 0 DATE OF PREPARATION Apr 19, 2010 MATERIAL SAFETY DATA SHEET 8500(73) 11 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER 8500(73) PRODUCT NAME Interior/Exterior DTM Alkyd Gloss Industrial Enamel, Safety Yellow MANUFACTURER'S NAME Conco Paints 101 Prospect Avenue N.W. Cleveland, OH 44115 Telephone Numbers and Websites Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident) * SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 16 64742-88-7 Mineral Spirits ACGIH TLV 100 PPM 2 mm OSHA PEL 100 PPM 0.8 100-41-4 ACGIH TLV 100 PPM 7.1 mm ACGIH TLV 125 PPM STEL OSHA PEL 100 PPM OSHA PEL 125 PPM STEL 5 1330-20-7 Xylene ACGIH TLV 100 PPM 5.9 mm ACGIH TLV 150 PPM STEL OSHA PEL 100 PPM OSHA PEL 150 PPM STEL 1 95-63-6 ACGIH TLV 25 PPM 2.03 mm OSHA PEL 25 PPM 1 2807-30-9 2-Propoxyethanol ACGIH TLV Not Available 1.3 mm OSHA PEL Not Available 16 471-34-1 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 15 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 11 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. Page 368 of 878 Page 368 of 878 Page 368 of 878 Page 368 of 878 ---PAGE BREAK--- 8500(73) page 2 of 5 UEL 15.8 LEL 1.0 FLASH POINT 95 °F PMCC May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system the reproductive system SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION RED LABEL Flammable, Flash below 100 °F (38 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY DOL Storage Class IC PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Contents are FLAMMABLE. Keep away from heat, sparks, and open flame. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other Page 369 of 878 Page 369 of 878 Page 369 of 878 Page 369 of 878 ---PAGE BREAK--- 8500(73) page 3 of 5 hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 10.04 lb/gal 1203 g/l SPECIFIC GRAVITY 1.21 BOILING POINT 281 - 395 °F 138 - 201 °C MELTING POINT Not Available VOLATILE VOLUME 40% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 2.74 lb/gal 328 g/l Less Water and Federally Exempt Solvents 2.74 lb/gal 328 g/l Emitted VOC SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that causes cancer in humans. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." Page 370 of 878 Page 370 of 878 Page 370 of 878 Page 370 of 878 ---PAGE BREAK--- 8500(73) page 4 of 5 TOXICOLOGY DATA CAS No. Ingredient Name 64742-88-7 Mineral Spirits LC50 RAT 4HR Not Available LD50 RAT Not Available 100-41-4 LC50 RAT 4HR Not Available LD50 RAT 3500 mg/kg 1330-20-7 Xylene LC50 RAT 4HR 5000 ppm LD50 RAT 4300 mg/kg 95-63-6 LC50 RAT 4HR Not Available LD50 RAT Not Available 2807-30-9 2-Propoxyethanol LC50 RAT 4HR Not Available LD50 RAT 3090 mg/kg 471-34-1 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION US Ground (DOT) 1 Gallon and Less may be Classed as CONSUMER COMMODITY, ORM-D Larger Containers are Regulated as: UN1263, PAINT, 3, PG III, (ERG#128) DOT (Dept of Transportation) Hazardous Substances & Reportable Quantities Xylenes (isomers and mixture) 100 lb RQ Bulk Containers may be Shipped as (check reportable quantities): RQ, UN1263, PAINT, 3, PG III, (XYLENES (ISOMERS AND MIXTURE)), (ERG#128) Canada (TDG) UN1263, PAINT, CLASS 3, PG III, LIMITED QUANTITY, (ERG#128) IMO UN1263, PAINT, CLASS 3, PG III, (35 C EmS F-E, S-E, ADR (D/E) SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 100-41-4 0.7 1330-20-7 Xylene 5 95-63-6 1 Glycol Ethers 1 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Page 371 of 878 Page 371 of 878 Page 371 of 878 Page 371 of 878 ---PAGE BREAK--- 8500(73) page 5 of 5 SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 372 of 878 Page 372 of 878 Page 372 of 878 Page 372 of 878 ---PAGE BREAK--- 1 SAFETY DATA SHEET Kimberly-Clark® Professional Waterless Hand Wipes; Kimberly-Clark® Professional Heavy Duty Hand Cleaning Wipes; WYPALL® Waterless Hand Wipes 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING Product Name: Kimberly-Clark® Professional Waterless Hand Wipes; Kimberly-Clark® Professional Heavy Duty Hand Cleaning Wipes; WYPALL® Waterless Hand Wipes Product Number: 58310, 91054, 91341, 91367, 91371, 91391 Date Prepared: 6/9/2007 Manufacturer: Kimberly-Clark Corporation 1400 Holcomb Bridge Road Roswell, GA 30076-2199 United States of America Telephone: MEDICAL EMERGENCY TRANSPORTATION EMERGENCY INFORMATION 1-[PHONE REDACTED] Chemtrec 1-[PHONE REDACTED] 1-[PHONE REDACTED] Product Use: Skin/personal cleansing For additional information contact [EMAIL REDACTED]. 2. HAZARDS IDENTIFICATION White liquid with a citrus odor on a polypropylene towel. Emergency Overview: CAUTION: Slip Hazard. May cause eye irritation. Keep away from heat and sources of ignition. Do not smoke while using this product or near surfaces wetted with this product. EU Classification (1999/45/EC): Not classified as a dangerous substance or preparation. Medicinal and cosmetic products in the finished form, intended for the final user are not subject the Directive relating to the classification, packaging and labelling of dangerous preparations (1999/45/EC). US OSHA Classification (29CFR1910.1200): Not Hazardous Canadian WHMIS Classification: Not a controlled product. Page 373 of 878 Page 373 of 878 Page 373 of 878 Page 373 of 878 ---PAGE BREAK--- 2 SAFETY DATA SHEET Kimberly-Clark® Professional Waterless Hand Wipes; Kimberly-Clark® Professional Heavy Duty Hand Cleaning Wipes; WYPALL® Waterless Hand Wipes 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No./ EINECS- No % EU Classification (67/548/EEC): Terpenes and Terpenoids (orange) 68917-57-7 0-8% Xi N R10, R36, R43 Glycerin 56-81-5/200-289-5 0-3% Not applicable Non-Hazardous Ingredients Proprietary 89-100% Not applicable See Section 16 for further information on EU Classification. 4. FIRST AID MEASURES Inhalation: Move to fresh air. Seek medical advice if cough, shortness of breath or other respiratory problems occur. Skin contact: This product is intended for use on the skin. Seek medical advice if redness, swelling, itching or burning occurs. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention if irritation persists. Ingestion: Call a physician or Poison Control Centre immediately. If victim is conscious, rinse mouth with a small amount of water. Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Water, water fog, foam, carbon dioxide, dry chemical. Special Fire Fighting Procedures: Wear self-contained breathing apparatus and protective suit. Unusual Fire and Explosion Hazards: No unusual hazards expected. Hazardous Combustion Products: Carbon monoxide, carbon dioxide. 6. ACCIDENTAL RELEASE MEASURES CAUTION: Slip Hazard. Remove all sources of ignition. Ventilate the area. Pick up and place in a suitable container for use or disposal. Comply with all federal, state and local regulations. Page 374 of 878 Page 374 of 878 Page 374 of 878 Page 374 of 878 ---PAGE BREAK--- 3 SAFETY DATA SHEET Kimberly-Clark® Professional Waterless Hand Wipes; Kimberly-Clark® Professional Heavy Duty Hand Cleaning Wipes; WYPALL® Waterless Hand Wipes 7. HANDLING AND STORAGE Avoid contact with eyes. Avoid sparks, flame and excessive heat. Do not smoke while using this product or near surfaces wetted with this product. Recommended storage temperature 40ºF - 100ºF (5ºC - 37ºC). 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name Exposure limit(s) Terpenes and Terpenoids (orange) None established Glycerin 15 mg/m3 PEL-TWA (total particulate) 10 mg/m3 TLV-TWA (inhalable particulate) as mist Ventilation: No special ventilation normally required. Respiratory Protection: No personal respiratory protective equipment normally required. Protective Gloves: Not required. This product is intended for use as a hand cleanser and is expected to contact the skin. Eye Protection: None required for normal use. For bulk processing, regular hand washing along with general body-covering clothing, safety goggles and gloves are recommended as good industrial hygiene practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance and Odor White liquid with a citrus odor on a polypropylene towel. Boiling point/range 200-220ºF (93.3-104.4ºC) Melting point/range Not applicable Specific Gravity (water=1) 0.97-0.98 Vapor pressure Not available Vapor density (air=1) >1 Solubility Complete pH ~6 Partition coefficient (n-octanol/water): Not available Evaporation Rate (Butyl acetate=1) Not available Percent Volatile by Volume Not available Volatile Organic Carbon Compounds (VOC) (g/L) Page 375 of 878 Page 375 of 878 Page 375 of 878 Page 375 of 878 ---PAGE BREAK--- 4 SAFETY DATA SHEET Kimberly-Clark® Professional Waterless Hand Wipes; Kimberly-Clark® Professional Heavy Duty Hand Cleaning Wipes; WYPALL® Waterless Hand Wipes Flashpoint: 127ºF (53ºC)(liquid only) This product was tested in accordance with the UN Manual of Tests and Criteria, Test N.1. It passes the Preliminary Screening Test and therefore does not meet the definition of a readily combustible solid of Division 4.1. Flammable Limits in Air % by Volume: LEL (Lower):0.7%(Terpenes and Terpenoids (orange)) UEL (Upper): 6.1% ( Terpenes and Terpenoids (orange) ) 10. STABILITY AND REACTIVITY Stability: Stable Conditions to Avoid: Avoid sparks, flame and excessive heat. Materials to avoid: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Does not occur. 11. TOXICOLOGICAL INFORMATION of Overexposure: Inhalation: None expected. Skin contact: Prolonged skin contact may cause mild irritation in sensitive individuals. Patch testing does not indicate a potential for sensitization in humans. Patch testing does not indicate a potential for dermal irritation in humans. Eye contact: Contact with eyes may cause irritation. Ingestion: Not a likely route of exposure. May cause mucous membrane and gastrointestinal irritation and other adverse effects. Chronic toxicity: Prolonged skin contact may cause mild irritation in sensitive individuals. Medical Conditions Aggravated by Exposure: None currently known. May possibly aggravate dermatitis, psoriasis and other skin conditions. Carcinogenicity Data: None of the components of this product is listed as a carcinogen by IARC, NTP, US OSHA or the European Directive (67/48/EEC). Reproductive Toxicity: No adverse effects on reproduction are known. Acute Toxicity Values: Product: Oral LD50 (rat) >5000 mg/kg Based on an assessment of the ingredients. Page 376 of 878 Page 376 of 878 Page 376 of 878 Page 376 of 878 ---PAGE BREAK--- 5 SAFETY DATA SHEET Kimberly-Clark® Professional Waterless Hand Wipes; Kimberly-Clark® Professional Heavy Duty Hand Cleaning Wipes; WYPALL® Waterless Hand Wipes 12. ECOLOGICAL INFORMATION No data is currently available. 13. DISPOSAL CONSIDERATIONS Dispose in accordance with all state, local and federal regulations. 14. TRANSPORT INFORMATION US DOT Shipping Description: Not regulated IATA Shipping Description (Air): Not regulated IMDG Shipping Description (Vessel): Not regulated 15. REGULATORY INFORMATION US Regulations EPA Toxic Substances Control Act (TSCA): All of the components of this product are listed on the TSCA Inventory or exempted from TSCA. SARA 302 Listed Chemicals: None. SARA 311/312 Hazard Categories: None. SARA 313 This Product Contains the Following Chemicals Subject to Annual Release Reporting Requirements Under the SARA Section 313 (40 CFR 372): None. California Proposition 65: This product does not contain chemicals listed per the Safe Drinking Water and Toxic Enforcement Act of 1986. International Regulations Canadian CEPA: All of the components are either listed on or exempted from the Domestic Substances List (DSL). Canadian WHMIS Classification: Drugs and cosmetics are not subject to the Hazardous Products Act (WHMIS). EU Labeling: Medicinal and cosmetic products in the finished form, intended for the final user are not subject the Directive relating to the classification, packaging and labelling of dangerous preparations (1999/45/EC). 16. OTHER INFORMATION HMIS Rating: Health 1 Fire 1 Reactivity 0 Revision Summary: Revision to section(s) 1,2,3,5,9. EU Classes and Risk Phrases for Reference (See Sections 2 and Xi - Irritant Page 377 of 878 Page 377 of 878 Page 377 of 878 Page 377 of 878 ---PAGE BREAK--- 6 SAFETY DATA SHEET Kimberly-Clark® Professional Waterless Hand Wipes; Kimberly-Clark® Professional Heavy Duty Hand Cleaning Wipes; WYPALL® Waterless Hand Wipes R10 - Flammable. R36 - Irritating to eyes. R43 - May cause sensitization by skin contact. The information contained herein is true and correct to the best of Kimberly-Clark's knowledge. However, no warranty, express or implied, is made. Nothing herein should be interpreted as a recommendation to infringe existing patents or violate any laws or regulations. Final determination of the suitability of the material is the sole responsibility of the user. Page 378 of 878 Page 378 of 878 Page 378 of 878 Page 378 of 878 ---PAGE BREAK--- 1 Page: Klean Strip Aircraft Paint Remover SAFETY DATA SHEET 2 4 0 04/13/2012 01/30/2009 Revision: Supercedes Revision: 07/31/2012 Printed: X * 2 0 4 Instability Special Hazard Health Flammability HEALTH FLAMMABILITY PHYSICAL PPE 1. Product and Company Identification A3900.2 Product Code: Klean Strip Aircraft Paint Remover Product Name: Manufacturer Information W. M. Barr Company Name: 2105 Channel Avenue Memphis, TN 38113 (901)775-0100 Phone Number: 3E 24 Hour Emergency Contact (800)451-8346 Emergency Contact: W.M. Barr Customer Service (800)398-3892 Information: www.wmbarr.com Web site address: W.M. Barr EHS Dept (901)775-0100 Preparer Name: Synonyms EAR322 2. Hazards Identification GHS Hazard Phrases No data available. GHS Precaution Phrases No data available. GHS Response Phrases No data available. GHS Storage and Disposal Phrases No data available. Potential Health Effects (Acute and Chronic) INHALATION ACUTE EXPOSURE EFFECTS: Vapor harmful. May cause upper respiratory tract irritation and central nervous system depression with such as confusion, lightheadedness, nausea, vomiting, headache, and fatigue. Causes formation of carbon monoxide in blood which may affect the cardiovascular system and central nervous system. Elevated carboxyhemoglobin levels can be additive to the increase caused by smoking and other carbon monoxide sources. Continued exposure may cause unconsciousness and even death. Intentional misuse of this product by deliberately concentrating and inhaling the vapors can be harmful or fatal. The propellant used in this product is a simple SKIN CONTACT ACUTE EXPOSURE EFFECTS: May cause effects ranging from mild irritation to severe pain, and possibly burns, depending on the intensity of contact. May dry the skin. may include redness, burning, drying and cracking of the skin. Skin absorption may occur. Passage of the material into the body through the skin is possible, and may add to toxic effects from breathing or swallowing. EYE CONTACT ACUTE EXPOSURE EFFECTS: Licensed to W.M. Barr and Company Multi-region format Page 379 of 878 Page 379 of 878 Page 379 of 878 Page 379 of 878 ---PAGE BREAK--- 04/13/2012 Revision: 07/31/2012 Printed: 2 Page: Klean Strip Aircraft Paint Remover SAFETY DATA SHEET 01/30/2009 Supercedes Revision: Vapors may cause eye irritation. Contact may cause tearing, redness, a stinging or burning feeling, swelling, blurred vision, and corneal injury. INGESTION ACUTE EXPOSURE EFFECTS: Harmful if swallowed. May cause nausea, vomiting, or diarrhea. If vomiting results in aspiration, chemical pneumonia could occur. Absorption through the gastrointestinal tract may produce central nervous system depression. May cause irritation to the mouth, throat and stomach. May affect the central nervous system (CNS) causing loss of coordination, dizziness, drowsiness, weakness, fatigue, and CNS depression. May cause leg cramps, pain the abdomen and lower back, blurred vision, shortness of breath, cyanosis, visual impairment (including blindness), coma, and death. CHRONIC EXPOSURE EFFECTS: Reports have associated repeated and prolonged overexposure to solvents with neurological and other physiological damage. Prolonged or repeated contact may cause dermatitis. Methanol has caused birth defects in laboratory animals, but only when inhaled at extremely high vapor concentrations. The relevance of this finding to humans is uncertain. Methylene Chloride (MC) overexposure may cause liver damage. May cause cancer based on animal data. Alcohol may enhance the toxic effects. May cross the placenta. May be excreted in breast milk. Concurrent exposure to carbon monoxide, smoking, or physical activity may increase the level of carboxyhemoglobin in the blood resulting in additive effects. The best evidence that MC causes cancer is from laboratory studies in which rats, mice and hamsters inhaled MC 6 hours per day, 5 days per week for 2 years. MC exposure produced lung and liver tumors in mice and mammary tumors in rats. No carcinogenic effects of MC were found in hamsters. There are also some human epidemiological studies which show an association between occupational exposure to MC and increases in biliary (bile duct) cancer and a type of brain cancer. Other epidemiological studies have not observed a relationship between MC exposure and cancer. OSHA interprets these results to mean that there is suggestive (but not absolute) evidence that MC is a human carcinogen. Ethoxylate is in a family of chemicals that has shown possible toxicity to the fetus in lab animals at doses toxic to the mother. TARGET ORGANS: Blood, central nervous system, liver, skin, cardiovascular system, heart, eyes, kidneys, pancreas, lungs, and brain. Signs and Of Exposure See Potential Health Effects. Medical Conditions Generally Aggravated By Exposure Diseases of the blood, skin, eyes, liver, kidneys, lungs, nervous system, respiratory system, cardiovascular system and respiratory system; alcoholism and disorders of the heart. Licensed to W.M. Barr and Company Multi-region format Page 380 of 878 Page 380 of 878 Page 380 of 878 Page 380 of 878 ---PAGE BREAK--- 04/13/2012 Revision: 07/31/2012 Printed: 3 Page: Klean Strip Aircraft Paint Remover SAFETY DATA SHEET 01/30/2009 Supercedes Revision: OSHA Regulatory Status: This material is classified as hazardous under OSHA regulations. 3. Composition/Information on Ingredients Hazardous Components (Chemical Name) Dichloromethane {Methylene chloride; R-30; Freon 30} 75-09-2 CAS # 60.0 -100.0 % Concentration 1. Methanol {Methyl alcohol; Carbinol; Wood alcohol} 67-56-1 1.0 -5.0 % 2. Poly(oxy-1,2-ethanediyl), Ethoxylate} 9016-45-9 1.0 -5.0 % 3. Liquified petroleum gas, sweetened {propane, isobutane, n-butane} 68476-86-8 ~15.0 % 4. Additional Chemical Information The concentration range values for the liquid ingredients do not reflect the dilution of the propellant in the container. The concentration values are for the liquid concentrate only. 4. First Aid Measures Emergency and First Aid Procedures INHALATION: If user experiences breathing difficulty, move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. SKIN CONTACT: Wash with soap and water. Get medical attention if irritation from contact persists. EYE CONTACT: Immediately flush eyes with water, remove any contact lens, continue flushing with water for at least 15 minutes. Get medical attention. INGESTION: Call your poison control center, hospital emergency room, or physician immediately for instructions. Note to Physician This product contains methylene chloride and methanol (less than This product contains methanol which can cause intoxication and central nervous system depression. Methanol is metabolized to formic acid and formaldehyde. These metabolites can cause metabolic acidosis, visual disturbances and blindness. Since metabolism is required for these toxic their onset may be delayed from 6 to 30 hours following ingestion. Ethanol competes for the same metabolic pathway and has been used to prevent methanol metabolism. Ethanol administration is indicated in patients or at blood methanol concentrations above 20 ug/dl. Methanol is effectively removed by hemodialysis. Adrenalin should never be given to a person overexposed to methylene chloride. Methylene Chloride is an aspiration hazard. Risk of aspiration must be weighed against possible toxicity of the material when determining whether to induce emesis or to perform gastric lavage. This material sensitizes the heart to the effects of sympathomimetic amines. Epinephrine and other sympathomimetic drugs may initiate cardiac in individuals exposed to this material. This material is metabolized to carbon monoxide. Consequently, elevations in carboxyhemoglobin as high as 50% have been reported, and levels may continue to rise for several hours after exposure has ceased. Data in experimental animals suggest there is a narrow margin between concentrations causing anesthesia and death. Licensed to W.M. Barr and Company Multi-region format Page 381 of 878 Page 381 of 878 Page 381 of 878 Page 381 of 878 ---PAGE BREAK--- 04/13/2012 Revision: 07/31/2012 Printed: 4 Page: Klean Strip Aircraft Paint Remover SAFETY DATA SHEET 01/30/2009 Supercedes Revision: 5. Fire Fighting Measures Flammable Aerosol Level 1 Flammability Classification: -140 F (-96.9 C) Method Used: Closed Cup Flash Pt: LEL: 1.8 UEL: 9.5 Explosive Limits: No data available. Autoignition Pt: Fire Fighting Instructions Self-contained respiratory protection should be provided for fire fighters fighting fires in buildings or confined areas. Storage containers exposed to fire should be kept cool with water spray to prevent pressure build-up. Stay away from heads of containers that have been exposed to intense heat or flame. Flammable Properties and Hazards Aerosol Flammability Classification according to ASTM D-3065-77 and FHSA 1500.45. CPSC FLAMMABILITY: Flammable Aerosol - Level 1 Contents under pressure. Do not puncture, incinerate or store above 120 degrees F. Exposure to heat or prolonged exposure to sun may cause bursting. Contact of liquid or vapor with flame or hot surfaces will produce toxic gases and a corrosive residue that will cause deterioration of metal. Flashpoint of propellant: -142.50 degrees F (closed cup) Flashoint of liquid only: No flash to boiling Hazardous Combustion Products Combustion may produce carbon monoxide and carbon dioxide. Suitable Extinguishing Media Use carbon dioxide, dry powder, or foam. Unsuitable Extinguishing Media None known. 6. Accidental Release Measures Steps To Be Taken In Case Material Is Released Or Spilled Isolate the immediate area. Prevent unauthorized entry. Eliminate all sources of ignition in area and downwind of the spill area. Stay upwind, out of low areas, and ventilate closed spaces before entering. All equipment used when handling this product must be grounded or non-sparking. Do not touch or walk through spilled material. Stop leak if you can do so without risk. Prevent entry into waterways, sewers, or confined areas. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand, or other non-combustible material and transfer to compatible containers. For large spills, dike ahead of the spill. 7. Handling and Storage Precautions To Be Taken in Handling Read carefully all cautions and directions on product label before use. Since empty container retains residue, follow all label warnings even after container is empty. Dispose of empty container according to all regulations. Do not reuse this container. Wear protective clothing and take precautions to prevent all skin and eye contact. Precautions To Be Taken in Storing Store in a cool place and protect from sunlight. Exposure to high temperatures or prolonged exposure to sun may cause can to leak or swell. Do not store near flames or at elevated temperatures. Replace overcap on container after each use. Licensed to W.M. Barr and Company Multi-region format Page 382 of 878 Page 382 of 878 Page 382 of 878 Page 382 of 878 ---PAGE BREAK--- 04/13/2012 Revision: 07/31/2012 Printed: 5 Page: Klean Strip Aircraft Paint Remover SAFETY DATA SHEET 01/30/2009 Supercedes Revision: 8. Exposure Controls/Personal Protection TLV: 50 ppm PEL: 25 ppm STEL: 125 ppm (15 min) No data. Hazardous Components (Chemical Name) ACGIH TWA Dichloromethane {Methylene chloride; R-30; Freon 30} 75-09-2 CAS # OSHA TWA Other Limits 1. TLV: 200 ppm STEL: 250 ppm PEL: 200 ppm No data. Methanol {Methyl alcohol; Carbinol; Wood alcohol} 67-56-1 2. TLV: 200 ppm STEL: 400 ppm PEL: 400 ppm No data. Poly(oxy-1,2-ethanediyl), Ethoxylate} 9016-45-9 3. TLV: (1000 ppm) STEL: ppm PEL: 1000 ppm No data. Liquified petroleum gas, sweetened {propane, isobutane, n-butane} 68476-86-8 4. Respiratory Equipment (Specify Type) For occasional consumer use - Use with adequate ventilation to prevent a build-up of vapors in confined areas. Open windows or position fans to provide cross ventilation. If a mild to strong odor is noticeable, ventilation is not adequate. For OSHA controlled workplace and other regular users - Use only with adequate ventilation under engineered air control systems designed to prevent exceeding appropriate TLVs. For occasional use, where engineered air control is not feasible, use properly maintained and properly fitted NIOSH approved self-contained breathing apparatus for chlorinated solvent vapors. A dust mask does not provide protection against vapors. Eye Protection Safety glasses, chemical goggles, or face shields are recommended to safeguard against potential eye contact, irritation, or injury. Chemical goggles or face shields are recommended when splashing or spraying of chemical is possible. A faceshield provides more protection to help reduce chemical contact to the face and eyes. Protective Gloves Wear gloves with as much resistance to the chemical ingredients as possible. Laminate film gloves offer the best protection. Other glove materials will be degraded by methylene chloride, but may provide protection for some amount of time, based on the type of glove and the conditions of use. Consult your glove supplier for additional information. Gloves contaminated with product should be discarded and not reused. Other Protective Clothing Various application methods can dictate use of additional protective safety equipment, such as impermeable aprons, etc., to minimize exposure. Engineering Controls (Ventilation etc.) Use only with adequate ventilation to prevent buildup of vapors. Do not use in areas where vapors can accumulate and concentrate, such as basements, bathrooms or small enclosed areas. Whenever possible, use outdoors in an open air area. If using indoors open all windows and doors and maintain a cross ventilation of moving fresh air across the work area. If strong odor is noticed or you experience slight dizziness, headache, nausea or eye-watering STOP ventilation is inadequate. Leave area immediately and move to fresh air. Work/Hygienic/Maintenance Practices A source of clean water should be available in the work area for flushing of the eyes and skin. Wash hands thoroughly after use. Do not eat, drink, or smoke in the work area. Before reuse, thoroughly clean any clothing or protective equipment that has been contaminated by prior use. Discard any clothing or other protective equipment that cannot be decontaminated, such as gloves or shoes. Licensed to W.M. Barr and Company Multi-region format Page 383 of 878 Page 383 of 878 Page 383 of 878 Page 383 of 878 ---PAGE BREAK--- 04/13/2012 Revision: 07/31/2012 Printed: 6 Page: Klean Strip Aircraft Paint Remover SAFETY DATA SHEET 01/30/2009 Supercedes Revision: 9. Physical and Chemical Properties [ X ] Gas [ X ] Liquid [ ] Solid Physical States: No data. Melting Point: 100 F (40.0 C) - 150 F (65.6 C) Boiling Point: No data. Autoignition Pt: -140 F (-96.9 C) Method Used: Closed Cup Flash Pt: LEL: 1.8 UEL: 9.5 Explosive Limits: No data. Specific Gravity (Water = 10.5 - (of liquid) LB/GL at 75 F (23.9 C) Density: No data. Vapor Pressure (vs. Air or mm Hg): > 1 Vapor Density (vs. Air = < 1 Evaporation Rate: Slight Solubility in Water: 96 % by weight. Percent Volatile: 18 % WT VOC / Volume: Appearance and Odor Yellow to orange clinging liquid. 10. Stability and Reactivity Unstable [ ] Stable [ X ] Stability: Conditions To Avoid - Instability No data available. Incompatibility - Materials To Avoid Incompatible with strong oxidizing agents; strong caustics; strong alkalis; oxygen; nitrogen peroxide; chemically active metals such as aluminum and magnesium; sodium; potassium; and nitric acid. Hazardous Decomposition Or Byproducts Thermal decomposition may produce carbon monoxide and carbon dioxide, hydrogen chloride, chlorine gas, and small quantities of phosgene. Will occur [ ] Will not occur [ X ] Possibility of Hazardous Reactions: Conditions To Avoid - Hazardous Reactions No data available. 11. Toxicological Information Toxicological Information This product has not been tested as a whole. Information below will be for individual ingredients. Methylene Chloride: ACUTE TOXICITY: LC50 Rat inhalation 52 mg/L 4 hrs LD50 Rat oral 985-1600 mg/kg SKIN CORROSION / IRRITATION: 810 mg/24 hr skin rabbit - severe 100 mg/24 hr skin rabbit - moderate SERIOUS EYE DAMAGE / IRRITATION: 162 mg eyes rabbit - moderate 10 mg eyes rabbit - mild 500 mg/24 hr eyes rabbit - mild RESPIRATORY OR SKIN SENSITIZATION: Not a respiratory or skin sensitizer. Licensed to W.M. Barr and Company Multi-region format Page 384 of 878 Page 384 of 878 Page 384 of 878 Page 384 of 878 ---PAGE BREAK--- 04/13/2012 Revision: 07/31/2012 Printed: 7 Page: Klean Strip Aircraft Paint Remover SAFETY DATA SHEET 01/30/2009 Supercedes Revision: ASPIRATION HAZARD: Methylene chloride does present an aspiration hazard. MUTAGENIC DATA: Positive results have been observed in the Ames test. In mammalian systems, responses have generally been negative. IMMUNOTOXICITY: A study found there was no evidence of harm to the immune system of laboratory animals or reduced ability to combat disease. NEUROTOXICITY: Tests in rats indicate no significant neurotoxic effects after exposure to concentrations up to 2,000 ppm for 90 days. No neurotoxic effects have been observed in humans at typical occupational exposure levels. DEVELOPMENTAL/REPRODUCTIVE: No significant developmental effects were observed in female rats and mice exposed to 1,250 ppm during gestation. A similar result was observed in rats exposed to 4,500 ppm before and during gestation. A two-generation inhalation study showed no adverse reproductive effects in rats exposed to as much as 1,500 ppm for 14 weeks. CARCINOGEN STATUS: Methylene chloride is carcinogenic in experimental animals at a relatively high dose, by route(s) of administration, at site(s), of histologic type(s), or by mechanism(s) that are not considered relevant to worker exposure. Available epidemiological studies do not confirm an increased risk of cancer in humans. Available evidence suggests that this material is not likely to cause cancer in humans except under uncommon or unlikely routes or levels of exposure. Methanol: ACUTE TOXICITY: LD50 Rat oral 5628 mg/kg LC50 Rat inhalation 64000 ppm/4 hr LC50 Rat inhalation 87.5 mg/L/6 hr LD50 Mouse oral 7300 mg/kg SKIN CORROSION / IRRITATION: LD50 Rabbit dermal 15,800 mg/kg bw SERIOUS EYE DAMAGE / IRRITATION: Methanol is a mild to moderate eye irritant. RESPIRATORY OR SKIN SENSITIZATION: Not a respiratory or skin sensitizer. ASPIRATION HAZARD: Methanol presents an aspiration hazard. MUTAGENIC DATA: No data. IMMUNOTOXICITY: No data. NEUROTOXICITY: Overexposure to methanol has been suggested as causing central nervous system damage in laboratory animals. DEVELOPMENTAL/REPRODUCTIVE: The inhalation of methanol by pregnant rodents throughout the period of embryogenesis induces a wide range of concentration-dependent teratogenic and embryolethal effects. Methanol has caused birth defects in laboratory animals, but only when inhaled at extremely high vapor concentrations. The relevance of this finding to humans is uncertain. CARCINOGEN STATUS: There is no evidence from animal studies to suggest methanol is a carcinogen. Ethoxylate: LD50 Rat Oral 2590 ul/kg LD50 Rabbit Skin 2830 ul kg Chronic Toxicological Effects No data. Licensed to W.M. Barr and Company Multi-region format Page 385 of 878 Page 385 of 878 Page 385 of 878 Page 385 of 878 ---PAGE BREAK--- 04/13/2012 Revision: 07/31/2012 Printed: 8 Page: Klean Strip Aircraft Paint Remover SAFETY DATA SHEET 01/30/2009 Supercedes Revision: Carcinogenicity/Other Information IARC 2B - Possibly Carcinogenic to Humans ACGIH A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans A3 2B Yes Hazardous Components (Chemical Name) Dichloromethane {Methylene chloride; R-30; Freon 30} 75-09-2 CAS # Possible NTP IARC ACGIH OSHA 1. n.a. n.a. n.a. Methanol {Methyl alcohol; Carbinol; Wood alcohol} 67-56-1 n.a. 2. n.a. n.a. n.a. Poly(oxy-1,2-ethanediyl), Ethoxylate} 9016-45-9 n.a. 3. n.a. n.a. n.a. Liquified petroleum gas, sweetened {propane, isobutane, n-butane} 68476-86-8 n.a. 4. 12. Ecological Information General Ecological Information This product has not been tested as a whole. Information below will be for individual ingredients. Methylene Chloride: TOXICITY: LC50 310 mg/L 96 hrs (static) Fathead Minnow; LC50 220 mg/L 96 hrs (static) Bluegill Sunfish; LC50 256 mg/L 96 hrs Mysid Shrimp PERSISTENCE AND DEGRADABILITY: If released to air, a vapor pressure of 435 mm Hg at 25 deg C indicates dichloromethane will exist solely as a vapor in the ambient atmosphere. This material released to the atmosphere will degrade by reaction with hydroxyl radicals with a half-life of several months. It is not subject to direct photooxidation. On land is expected to evaporate rapidly into the atmosphere due to its high vapor pressure. it is poorly adsorbed to soil and can leach into the groundwater. Calculated Adsorption Coefficient (log KOC) is 1. This material is subject to rapid evaporation, with estimated evaporative half-lives ranging from 3 to 5.6 hours under moderate mixing conditions. This material has a negligible rate of hydrolysis. Biodegredation may occur in groundwater, but will be very slow compared with evaporation. BIOACCUMULATIVE POTENTIAL: Bioconcentration potential in aquatic organisms is low with BCF of 2. MOBILITY IN SOIL: If released to soil, dichloromethane is expected to have very high mobility based upon an estimated Koc of 24. OTHER ADVERSE EFFECTS: No data. Methanol: TOXICITY: Methanol is of low toxicity to aquatic organisms. LC50 Pimephales promelas (fathead minnows) 29.4 g/L/96 hr, (28-29 days old), confidence limit= 28.5-30.4; Test conditions: Water temp= 25 deg C, dissolved oxygen= 7.3 mg/L, water hardness= 43.5 mg/l calcium carbonate, alkalinity= 46.6 calcium carbonate, tank volume= 6.3 L, additions= 5.71 V/D, pH= 7.66 (0.03). PERSISTENCE AND DEGRADABILITY: If released to the atmosphere, a vapor pressure of 127 mm Hg at 25 deg C indicates that methanol will exist solely in the vapor phase. Vapor phase methanol is degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals; the half-life for this reaction in air is estimated to be 17 days. Volatilization from moist soil surfaces is expected to be an important fate process based upon a Henry's Law constant of 4.55X10-6 atm-cu m/mole. Methanol may also volatilize from dry soils based upon it vapor pressure. Biodegradation of methanol in soils is expected to occur rapidly based on half-lives in a sandy silt loam from Texas and a sandy loam from Mississippi of 1 and 3.2 days, respectively. If released into water, methanol is not expected to adsorb to suspended solids and sediment based upon the estimated Koc. Volatilization from water surfaces is expected to be an important fate process based upon this compound's Henry's Law constant. Estimated volatilization half-lives for a model river and model lake are 3 and 35 days, respectively. Biodegradation is expected to occur in natural waters since methanol is degraded quickly in soils and was biodegraded rapidly in various aqueous screening tests using sewage seed or activated sludge. Licensed to W.M. Barr and Company Multi-region format Page 386 of 878 Page 386 of 878 Page 386 of 878 Page 386 of 878 ---PAGE BREAK--- 04/13/2012 Revision: 07/31/2012 Printed: 9 Page: Klean Strip Aircraft Paint Remover SAFETY DATA SHEET 01/30/2009 Supercedes Revision: Hydrolysis of methanol and photolysis in sunlit surface waters are not expected since methanol lacks functional groups that are susceptible to hydrolysis or photolysis under environmental conditions. BIOACCUMULATIVE POTENTIAL: BCF values of less than 10, measured in fish suggests bioconcentration in aquatic organisms is low. MOBILITY IN SOIL: If released to soil, methanol is expected to have very high mobility based upon an estimated Koc of 1. Ethoxylate: Material is moderately toxic to aquatic organisms on an acute basis (LC50/EC50) between 1 and 10 mg/L in most sensitive species tested. 13. Disposal Considerations Waste Disposal Method Dispose in accordance with applicable local, state, and federal regulations. 14. Transport Information LAND TRANSPORT (US DOT) Aerosols, flammable, Ltd. Qty. Level 1 Aerosol DOT Proper Shipping Name 2.1 DOT Hazard Class: FLAMMABLE GAS DOT Hazard Label: UN1950 UN/NA Number: LAND TRANSPORT (Canadian TDG) 1950 UN Number: 2.1 - FLAMMABLE GAS Hazard Class: AIR TRANSPORT (ICAO/IATA) UN1950, AEROSOLS, flammable, 2.1, LTD. QTY Level 1 Aerosol ICAO/IATA Shipping Name 1950 UN Number: 2.1 - FLAMMABLE GAS Hazard Class: MARINE TRANSPORT (IMDG/IMO) UN1950, AEROSOLS, flammable, 2.1, LTD. QTY Level 1 Aerosol IMDG/IMO Shipping Name 1950 UN Number: 2.1 - FLAMMABLE GAS Hazard Class: Licensed to W.M. Barr and Company Multi-region format Page 387 of 878 Page 387 of 878 Page 387 of 878 Page 387 of 878 ---PAGE BREAK--- 04/13/2012 Revision: 07/31/2012 Printed: 10 Page: Klean Strip Aircraft Paint Remover SAFETY DATA SHEET 01/30/2009 Supercedes Revision: Additional Transport Information For D.O.T. information, contact W.M. Barr Technical Services at 1-[PHONE REDACTED]. The shipper / supplier may apply one of the following exceptions: Combustible Liquid, Consumer Commodity, Limited Quantity, Viscous Liquid, Does Not Sustain Combustion, or others, as allowed under 49CFR Hazmat Regulations. Please consult 49CFR Subchapter C to ensure that subsequent shipments comply with these exceptions. 15. Regulatory Information Canadian Chemical Lists Yes Hazardous Components (Chemical Name) Dichloromethane {Methylene chloride; R-30; Freon 30} 75-09-2 CAS # Yes Canadian NPRI Canadian IDL 1. Yes Methanol {Methyl alcohol; Carbinol; Wood alcohol} 67-56-1 Yes 2. No Poly(oxy-1,2-ethanediyl), Ethoxylate} 9016-45-9 Yes 3. No Liquified petroleum gas, sweetened {propane, isobutane, n-butane} 68476-86-8 No 4. Canadian WHMIS Classification No data available. US EPA SARA Title III Yes Yes 1000 LB Yes Hazardous Components (Chemical Name) Dichloromethane {Methylene chloride; R-30; Freon 30} 75-09-2 CAS # No Sec.302 (EHS) Sec.304 RQ Sec.313 (TRI) Sec.110 1. Yes Yes 5000 LB No Methanol {Methyl alcohol; Carbinol; Wood alcohol} 67-56-1 No 2. No No No Poly(oxy-1,2-ethanediyl), Ethoxylate} 9016-45-9 No 3. No No No Liquified petroleum gas, sweetened {propane, isobutane, n-butane} 68476-86-8 No 4. US EPA CAA, CWA, TSCA Inventory, 4 Test, 8A CAIR Yes Yes Hazardous Components (Chemical Name) Dichloromethane {Methylene chloride; R-30; Freon 30} 75-09-2 CAS # HAP, ODC EPA CAA EPA CWA NPDES EPA TSCA CA PROP 65 1. Inventory No Yes Methanol {Methyl alcohol; Carbinol; Wood alcohol} 67-56-1 HAP, ODC 2. Inventory, 8A PAIR No No Poly(oxy-1,2-ethanediyl), Ethoxylate} 9016-45-9 HAP, ODC 3. Inventory No No Liquified petroleum gas, sweetened {propane, isobutane, n-butane} 68476-86-8 HAP, ODC 4. International Regulatory Lists EPA Hazard Categories: This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated: Yes [ ] No Acute (immediate) Health Hazard Yes [ ] No Chronic (delayed) Health Hazard Yes [ ] No Fire Hazard Licensed to W.M. Barr and Company Multi-region format Page 388 of 878 Page 388 of 878 Page 388 of 878 Page 388 of 878 ---PAGE BREAK--- 04/13/2012 Revision: 07/31/2012 Printed: 11 Page: Klean Strip Aircraft Paint Remover SAFETY DATA SHEET 01/30/2009 Supercedes Revision: Yes [ ] No Sudden Release of Pressure Hazard [ ] Yes No Reactive Hazard 16. Other Information Company Policy or Disclaimer The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, state and local laws and regulations. Licensed to W.M. Barr and Company Multi-region format Page 389 of 878 Page 389 of 878 Page 389 of 878 Page 389 of 878 ---PAGE BREAK--- 1 Page: Klean-Strip Acetone MATERIAL SAFETY DATA SHEET 1 3 0 Special Health Flammability Instability 05/18/2005 05/18/2005 Date Created: Revision: 12/12/2005 Printed: FLAMMABILITY PPE PHYSICAL HAZ. G HEALTH 2 2 3 1. Product and Company Identification Product Code: GAC18 Product Name: Klean-Strip Acetone Reference 1640 Manufacturer Information Company Name: W. M. Barr 2105 Channel Avenue Memphis, TN 38113 Phone Number: (901)775-0100 Emergency Contact: 3E 24 Hour Emergency Contact (800)451-8346 Information: W.M. Barr Customer Service (800)398-3892 Web site address: www.wmbarr.com Preparer Name: W.M. Barr EHS Department (901)775-0100 2. Composition/Information on Ingredients Acetone Hazardous Components (Chemical Name) 67-64-1 CAS # 100.0 -95.0 % Percentage 1000 ppm OSHA PEL 500 ppm ACGIH TWA No data. Other Limits 1. Acetone Hazardous Components (Chemical Name) AL3150000 RTECS # No data. OSHA STEL No data. OSHA CEIL 750 ppm ACGIH STEL No data. ACGIH CEIL 1. 3. Hazards Identification Danger! Extremely Flammable. Keep away from heat, sparks, flame and all other sources of ignition. Vapors may cause flash fire or ignite explosively. Vapors may travel long distances to other areas and rooms away from the work site. Do not smoke. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and all other sources of ignition anywhere in the structure, dwelling, or building during use and until all vapors are gone from the work site. Keep away from electrical outlets and switches. Beware of static electricity that may be generated by clothing and other sources. Emergency Overview OSHA Regulatory Status: This material is classified as hazardous under OSHA regulations. Inhalation Acute Exposure Effects: Vapor harmful. May cause dizziness, headache, watering of eyes, irritation of respiratory tract, drowsiness, nausea, and numbness in fingers, arms and legs. Skin Contact Acute Exposure Effects: May cause drying of skin, and numbness in fingers and arms. Liquid is absorbed readily. Eye Contact Acute Exposure Effects: This material is an eye irritant. Ingestion Acute Exposure Effects: Harmful if swallowed. May cause dizziness, headache, nausea, and irritation of the mouth, throat, and stomach. Chronic Exposure Effects: Reports have associated repeated and prolonged overexposure to solvents with neurological and other physiological damage. May cause weakness, fatigue, skin irritation, and numbness in hands and feet. Potential Health Effects (Acute and Chronic) Licensed to W.M. Barr and Company ANSI Z400.1 Format Page 390 of 878 Page 390 of 878 Page 390 of 878 Page 390 of 878 ---PAGE BREAK--- 05/18/2005 Revision: 12/12/2005 Printed: 2 Page: Klean-Strip Acetone MATERIAL SAFETY DATA SHEET Primary Routes of Exposure: Inhalation, ingestion, and dermal. Signs and Of Exposure None known. Medical Conditions Generally Aggravated By Exposure HEALTH HAZARDS : N/E PHYSICAL HAZARDS : N/E TARGET ORGANS & EFFECTS: N/E OSHA Hazard Classes: 4. First Aid Measures Inhalation: If user experiences breathing difficulty, move to air free of vapors. Administer oxygen or artificial respiration until medical assistance can be reached. Skin Contact: Wash with soap and water. Eye Contact: Flush with large quantities of water for at least 15 minutes and seek immediate medical attention. Ingestion: Call your poison control center, hospital emergency room, or physician immediately for instructions. Emergency and First Aid Procedures Call your local poison control center for further instructions. Note to Physician 5. Fire Fighting Measures Flammability Classification: Class IB Flash Pt: -4.00 F Method Used: TCC Explosive Limits: LEL: 2.60 UEL: No data. Autoignition Pt: No data. Self-contained respiratory protection should be provided for fire fighters fighting fires in buildings or confined areas. Storage containers exposed to fire should be kept cool with water spray to prevent pressure build-up. Stay away from heads of containers that have been exposed to intense heat or flame. Fire Fighting Instructions No data available. Flammable Properties and Hazards Use carbon dioxide, dry powder, or foam. Extinguishing Media No data available. Unsuitable Extinguishing Media 6. Accidental Release Measures Clean Up: Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, out of low areas, and ventilate closed spaces before entering. Shut off ignition sources; keep flares, smoking or flames out of hazard area. For small spills, take up liquid with sand, earth, or other noncombustible absorbent material and place in a container for disposal. For large spills, dike far ahead of spill and use sand, earth, or other noncombustible absorbent material and then place material in a container for disposal. Steps To Be Taken In Case Material Is Released Or Spilled Licensed to W.M. Barr and Company ANSI Z400.1 Format Page 391 of 878 Page 391 of 878 Page 391 of 878 Page 391 of 878 ---PAGE BREAK--- 05/18/2005 Revision: 12/12/2005 Printed: 3 Page: Klean-Strip Acetone MATERIAL SAFETY DATA SHEET Waste Disposal: Dispose in accordance with applicable local, state, and federal regulations. 7. Handling and Storage Read carefully all cautions and directions on product label before use. Since empty container retains residue, follow all label warnings even after container is empty. Dispose of empty container according to all regulations. Do not reuse the container. Precautions To Be Taken in Handling Keep container closed when not in use. Store in a cool, dry place. Do not store near flames or at elevated temperatures. Precautions To Be Taken in Storing 8. Exposure Controls/Personal Protection For OSHA controlled work place and other regular users. Use only with adequate ventilation under engineered air control systems designed to prevent exceeding appropriate TLV. For occasional use, where engineered air control is not feasible, use properly maintained and properly fitted NIOSH approved respirator for organic solvent vapors. A dust mask does not provide protection against vapors. Respiratory Equipment (Specify Type) Safety glasses, chemical goggles or face shields are recommended to safeguard against potential eye contact, irritation, or injury. Contact lenses should not be worn while working with chemicals. Eye Protection Wear impermeable gloves. Gloves contaminated with product should be discarded. remove clothing that becomes soiled with product. Protective Gloves Various application methods can dictate use of additional protective safety equipment, such as impermeable aprons, etc., to minimize exposure. A source of clean water should be available in the work area for flushing eyes and skin. Do not eat, drink, or smoke in the work area. Wash hands thoroughly after use. Before reuse, thoroughly clean any clothing or protective equipment that has been contaminated by prior use. Discard any clothing or other protective equipment that cannot be decontaminated, such as gloves or shoes. Other Protective Clothing Use only with adequate ventilation to prevent build-up of vapors. Open all windows and doors. Use only with a cross ventilation of moving fresh air across the work area. If strong odor is noticed or your experience slight dizziness, headache, nausea, or eye-watering - STOP - ventilation is inadequate. Leave area immediately. Engineering Controls (Ventilation etc.) 9. Physical and Chemical Properties Physical States: [ ] Gas [ X ] Liquid [ ] Solid Melting Point: No data. Boiling Point: > 133.00 F Autoignition Pt: No data. Flash Pt: -4.00 F Method: TCC Explosive Limits: LEL: 2.60 UEL: No data. Specific Gravity (Water = No data. Bulk Density: 6.572 LB/GA Vapor Pressure (vs. Air or mm Hg): No data. Vapor Density (vs. Air = No data. Evaporation Rate (vs Butyl Acetate=1): No data. Licensed to W.M. Barr and Company ANSI Z400.1 Format Page 392 of 878 Page 392 of 878 Page 392 of 878 Page 392 of 878 ---PAGE BREAK--- 05/18/2005 Revision: 12/12/2005 Printed: 4 Page: Klean-Strip Acetone MATERIAL SAFETY DATA SHEET Solubility in Water: No data. Percent Volatile: 100.0 % by weight. Corrosion Rate: No data. pH: No data. No data available. Appearance and Odor 10. Stability and Reactivity Stability: Unstable [ ] Stable [ X ] No data available. Conditions To Avoid - Instability Incompatible with strong oxidizing agents and hydrogen peroxide. Incompatibility - Materials To Avoid Decomposition may produce carbon monoxide and carbon dioxide. Hazardous Decomposition Or Byproducts Hazardous Polymerization: Will occur [ ] Will not occur [ X ] No data available. Conditions To Avoid - Hazardous Polymerization 11. Toxicological Information No data available. Toxicological Information No data available. Carcinogenicity/Other Information Carcinogenicity: NTP? No IARC Monographs? No OSHA Regulated? No 12. Ecological Information No data available. Ecological Information 13. Disposal Considerations Dispose in accordance with applicable local, state and federal regulations. Waste Disposal Method RCRA Waste ID Code: D001 14. Transport Information LAND TRANSPORT (US DOT) No data available. DOT Proper Shipping Name 15. Regulatory Information US EPA SARA Title III Acetone Hazardous Components (Chemical Name) 67-64-1 CAS # No Sec.302 (EHS) Yes 5000 LB Sec.304 RQ No Sec.313 (TRI) Yes Sec.110 1. US EPA CAA, CWA, TSCA Acetone Hazardous Components (Chemical Name) 67-64-1 CAS # No EPA CAA No EPA CWA NPDES No EPA TSCA No CA PROP 65 1. SARA (Superfund Amendments and Reauthorization Act of 1986) Lists: Sec.302: EPA SARA Title III Section 302 Extremely Hazardous Chemical with TPQ. * indicates 10000 LB TPQ if not volatile. Licensed to W.M. Barr and Company ANSI Z400.1 Format Page 393 of 878 Page 393 of 878 Page 393 of 878 Page 393 of 878 ---PAGE BREAK--- 05/18/2005 Revision: 12/12/2005 Printed: 5 Page: Klean-Strip Acetone MATERIAL SAFETY DATA SHEET Sec.304: EPA SARA Title III Section 304: CERCLA Reportable + Sec.302 with Reportable Quantity. indicates statutory RQ. Sec.313: EPA SARA Title III Section 313 Toxic Release Inventory. Note: -Cat indicates a member of a chemical category. Sec.110: EPA SARA 110 Superfund Site Priority Contaminant List TSCA (Toxic Substances Control Act) Lists: 5A(2): Chemical Subject to Significant New Rules (SNURS) 6A: Commercial Chemical Control Rules 8A: Toxic Substances Subject To Information Rules on Production 8A CAIR: Comprehensive Assessment Information Rules - (CAIR) 8A PAIR: Preliminary Assessment Information Rules - (PAIR) 8C: Records of Allegations of Significant Adverse Reactions 8D: Health and Safety Data Reporting Rules 8D TERM: Health and Safety Data Reporting Rule Terminations Other Important Lists: CWA NPDES: EPA Clean Water Act NPDES Permit Chemical CAA HAP: EPA Clean Air Act Hazardous Air Pollutant CAA ODC: EPA Clean Air Act Ozone Depleting Chemical (1=CFC, 2=HCFC) CA PROP 65: California Proposition 65 This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated: EPA Hazard Categories: [ ] Yes No Acute (immediate) Health Hazard [ ] Yes No Chronic (delayed) Health Hazard [ ] Yes No Fire Hazard [ ] Yes No Reactive Hazard [ ] Yes No Sudden Release of Pressure Hazard 16. Other Information The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, state and local laws and regulations. Company Policy or Disclaimer Licensed to W.M. Barr and Company ANSI Z400.1 Format Page 394 of 878 Page 394 of 878 Page 394 of 878 Page 394 of 878 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 MATERIAL SAFETY DATA SHEET 1 PRODUCT AND COMPANY IDENTIFICATION Product Name: KRUD KUTTER® Concrete Clean and Etch Synonyms: Not applicable Molecular Formula: Not applicable Molecular Weight: Not applicable Supplier: Supreme Chemicals of Georgia, Inc. 1535 Oak Industrial Lane, Suite B Cumming, GA 30041 USA Emergency Telephone: (CHEMTREC) [PHONE REDACTED] (Non-emergency Telephone) 800- 466-7126 Intended Use: Cleaning agent 2 HAZARDS IDENTIFICATION Emergency Overview Physical State: Liquid Color: Translucent orange Odor: Bland WARNING! Causes skin and eye irritation. Mist or vapors irritating to eyes and respiratory tract. Potential Health Effects Inhalation: Mist or vapor irritating to eyes and respiratory tract. Exposure may cause coughing, asthmatic breathing and irritation. Eye Contact: Causes eye irritation. Exposure may cause eye tearing, redness and discomfort. Skin Contact: Causes skin irritation. Exposure may cause redness, itching and inflammation. Ingestion: Not expected to be an ingestion hazard for intended use. Exposure may cause gastrointestinal irritation, nausea, vomiting, diarrhea and other systemic effects. Chronic Health Effects: None known Target Organ(s): Eye, skin, respiratory tract OSHA Regulatory Status: Hazardous; consumer product use is exempt. North America MSDS 1/8 Page 395 of 878 Page 395 of 878 Page 395 of 878 Page 395 of 878 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 3 COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No. Weight % phosphoric acid 7664-38-2 < 40 % Components not listed are not hazardous or are below reportable limits 4 FIRST AID MEASURES Inhalation: If inhaled, remove to fresh air. Get medical attention if persist. Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. Get medical attention. Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Ingestion: If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. If vomiting occurs, keep head lower than the hips to help prevent aspiration. Never give anything by mouth to an unconscious person. Get medical attention. 5 FIRE-FIGHTING MEASURES Extinguishing Media: Water spray, carbon dioxide, dry chemical or alcohol foam Unsuitable Extinguishing Media: None known Special Fire Fighting Procedures: Wear self-contained breathing apparatus and protective clothing. Unusual Fire & Explosion Hazards: None known Hazardous Combustion Products: Carbon oxides, phosphorous oxides 6 ACCIDENTAL RELEASE MEASURES Personal Precautions: Wear appropriate personal protective equipment. See Section 8. Spill Cleanup Methods: Small Liquid Spills: Wipe up or use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Large Spillages: Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use water spray to reduce vapors or divert vapor cloud drift. Isolate and stay upwind. Ventilate enclosed areas. Keep unauthorized personnel away. Prevent entry into waterways, sewer, basements or confined areas. 7 HANDLING AND STORAGE Handling: Avoid breathing mist or vapors. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Wash thoroughly after handling. North America MSDS 2/8 Page 396 of 878 Page 396 of 878 Page 396 of 878 Page 396 of 878 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 Prevention of Fire and Explosion: None Storage: Keep container closed. Store in original container. Keep out of reach of children. 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Industrial Exposures: Exposure Limits: Chemical Name Source Type Exposure Limits Notes phosphoric acid NIOSH REL 1 mg/m³ phosphoric acid NIOSH STEL 3 mg/m³ phosphoric acid NIOSH IDLH 1000 mg/m³ phosphoric acid ACGIH TWA 1 mg/m³ Upper respiratory tract eye & skin irritant phosphoric acid ACGIH STEL 3 mg/m³ Upper respiratory tract eye & skin irritant phosphoric acid OSHA Z-1 PEL 1 mg/m³ phosphoric acid California TWA 1 mg/m³ phosphoric acid California STEL 3 mg/m³ phosphoric acid Alberta, Canada TWA 1 mg/m³ Irritation phosphoric acid Alberta, Canada STEL 3 mg/m³ Irritation phosphoric acid British Columbia, Canada TWA 1 mg/m³ phosphoric acid British Columbia, Canada STEL 3 mg/m³ phosphoric acid Ontario, Canada TWA 1 mg/m³ phosphoric acid Ontario, Canada STEL 3 mg/m³ phosphoric acid Quebec, Canada TWA 1 mg/m³ phosphoric acid Quebec, Canada STEL 3 mg/m³ phosphoric acid Mexico TWA 1 mg/m³ phosphoric acid Mexico STEL 3 mg/m³ Engineering Controls: Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. Respiratory Protection: If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. In the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA Standard 63 FR 1152, January 8, 1998. Respirator type: Air-purifying respirator with an appropriate, government approved (where applicable), air-purifying filter, cartridge or canister. Contact health and safety professional or manufacturer for specific information. North America MSDS 3/8 Page 397 of 878 Page 397 of 878 Page 397 of 878 Page 397 of 878 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 Eye Protection: Wear splash goggles and a face shield or safety glasses with side shields. Hand Protection: Wear chemical resistant gloves. Skin Protection: Wear protective clothing appropriate for the risk of exposure. Hygiene Measures: Eye wash, washing facilities, safety shower 9 PHYSICAL AND CHEMICAL PROPERTIES Color: Translucent orange Odor: Bland Physical State: Liquid pH: No data available Boiling Point: 218º C (424.4º F) Melting Point: < -1.1° C (30° F) Flash Point: None Evaporation Rate: < 1 (Water = 1) Flammability: None Flammability Limit – Upper Not applicable Flammability Limit – Lower Not applicable Vapor Pressure: 17 mm Hg 20 ºC) (68° F) Vapor Density (Air=1): 3.2 Specific Gravity: 1.1 – 1.3 Solubility in Water: Complete Partition Coefficient (n-Octanol/water): No data available Autoignition Temperature: Not applicable Decomposition Temperature: No data available Volatile Organic Compounds (VOC): No data available Viscosity: No data available Percent Volatile: No data available 10 STABILITY AND REACTIVITY Stability: Stable Conditions to Avoid: None known Incompatible Materials: Strong oxidizing agents, alkalis Hazardous Decomposition Products: Carbon oxides, phosphorous oxides Possibility of Hazardous Reactions: Will not occur. 11 TOXICOLOGICAL INFORMATION Information available upon request. Listed Carcinogens: None North America MSDS 4/8 Page 398 of 878 Page 398 of 878 Page 398 of 878 Page 398 of 878 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 12 ECOLOGICAL INFORMATION Krud Kutter® Concrete Clean and Etch is biodegradable. 13 DISPOSAL CONSIDERATIONS General Information: Dispose in accordance with applicable federal, state, and local regulations. Disposal Methods: No specific disposal method required. Container: Since emptied containers retain product residue, follow label warnings even after container is emptied. 14 TRANSPORT INFORMATION DOT: ORM-D Proper Shipping Name: Consumer Commodity Packaging Requirements: Inner packagings not over 5.0 Liters (1.3 Gallons) net capacity each for liquids, and packed in strong outer packagings. Packages over 5.0 Liters (1.3 Gallons): UN-Number: 1805 Proper Shipping Name: Phosphoric Acid Solution Class: 8 Packaging Group: III Emergency Response Guide Number: 154 TDG: UN-Number: 1805 Proper Shipping Name: Phosphoric Acid Solution Class: 8 Packaging Group: III Emergency Response Guide Number: 154 IATA: For Limited Quantities of liquids of Class 8 Packing Group III: Passenger & Cargo Aircraft Packing Instructions: Y819 Passenger & Cargo Aircraft Limited Quantity Maximum Quantity Package: 1 Liter Single packagings are not permitted. The inner packagings must be packed in one of the following outer packagings with sufficient cushioning/absorbent material so as to prevent movement/leakage. The maximum quantity must not exceeded. Inner packagings: glass earthenware, plastic, metal (not aluminum), or glass ampoule. Outer Packaging: Steel packagings must be corrosion-resistant or with protection against corrosion. Glass or earthenware inner packagings and glass ampoules must be packaged with absorbent material in closed metal or rigid plastic receptacles in outer packagings. Glass or earthenware inner packagings and glass ampoules are permitted if this item is free from hydrofluoric acid. Outer Packaging: Drums: Steel, aluminum, plywood, fiber, plastic. Jerricans: Steel, aluminum, plastic Boxes: UN Certified Box, steel, aluminum, wood, plywood, reconstituted wood, fiber board and plastic North America MSDS 5/8 Page 399 of 878 Page 399 of 878 Page 399 of 878 Page 399 of 878 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 Passenger & Cargo Aircraft Packing Instructions: 819 Passenger & Cargo Aircraft Maximum Quantity/Package: 5 Liters Single packagings are not permitted. The inner packagings must be packed in one of the following outer packagings with sufficient cushioning/absorbent material so as to prevent movement/leakage. The maximum quantity must not exceeded. Inner packagings: glass earthenware, plastic, metal (not aluminum), or glass ampoule. Outer Packaging: Steel packagings must be corrosion-resistant or with protection against corrosion. Glass or earthenware inner packagings and glass ampoules must be packaged with absorbent material in closed metal or rigid plastic receptacles in outer packagings. Glass or earthenware inner packagings and glass ampoules are permitted if this item is free from hydrofluoric acid. Outer Packaging: Drums: Steel (1A2), aluminum (1B2), plywood (1D), fiber (1G), plastic (1H2). Jerricans: Steel (4A), Aluminum (4B), Plastic (3H2); Boxes: UN Certified Box, Steel (4A), aluminum (3B2), wood (4C1,4C2), plywood (4D), reconstituted wood (5F), fiber board (4G) and plastic (4H1, 4H2). Cargo Aircraft Only Package Instruction: 821 Cargo Aircraft Only Maximum Quantity/Package: 60 Liters Combination and single packagings are permitted. The inner packagings must be packed in one of the following outer packagings with sufficient cushioning/absorbent material so as to prevent movement/leakage. Combination packagings: inner packagings: Glass or earthenware, plastic, metal (not aluminum) or glass ampoule. Outer packaging: Drums: Steel (1A2), aluminum (1B2), plywood (1D), fiber (1G), plastic (1H2). Jerricans: Steel (3A2), aluminum (3B2), plastic (1H2); Boxes: UN Certified Box, steel(4A), aluminum (4B), wood (4C1,4C2), plywood (4D), reconstituted wood (4F), fiber board (4G) and plastic (4H1, 4H2). Special Provisions: A3 ERG Code: 8L Packages over 5.0 Liters (1.3 Gallons): UN-Number: 1805 Proper Shipping Name: Phosphoric Acid Solution Class: 8 Packaging Group: III Emergency Response Guide Number: 154 IMDG: Limited Quantities Exception: Dangerous Goods in limited quantities of Class 8. Limited quantities must be packed in combination packaging. The inner packaging must be within the quantity limit specified in the Dangerous Goods List (DGL) for the substance being prepared for shipment and be packaged in suitable outer packaging (i.e. UN certified box). The gross mass of the package must not exceed 30 kilograms (66 pounds). For over 30 kilograms (66 pounds): UN-Number: 1805 Proper Shipping Name: Phosphoric Acid Solution Class: 8 Packaging Group: III EMS No: F-A, S-B Special Provision: 223 Packing Instructions: P001, LP01 North America MSDS 6/8 Page 400 of 878 Page 400 of 878 Page 400 of 878 Page 400 of 878 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 IBC 03 Portable tanks and bulk containers: IMO Tank Instructions: T3 UN Tank Instructions: T4 Provisions: TP1 Stowage and Segregation: Category A 15 REGULATORY INFORMATION Canadian Controlled Products Regulations: This product has been classified according to the hazard criteria of the Canadian Controlled Products Regulations, Section 33, and the MSDS contains all required information. WHMIS Classification: D2B Mexico: Hazard Identification Guidance List: Phosphoric Acid: 3-0-0 PPE: F Inventory Status This product or all components are listed on the following inventory: TSCA DSL Inventory: No information available US Regulations CERCLA Hazardous Substance List (40 CFR 302.4): Component Reportable Quantity phosphoric acid 5,000 lbs SARA Title III Section 302Extremely Hazardous Substance (40 CFR 355, Appendix None Section 311/312 (40 CFR 370): X Acute (Immediate) Chronic (Delayed) Fire Reactive Pressure Generating Section 313 Toxic Release Inventory (40 CFR 372): None Clean Air Act (CCA) Section 112, 1990 Amendments, Statutory Hazardous Air Pollutants: None Clean Air Act (CAA) Section 112(i) High-Risk Hazardous Air Pollutants (40 CFR 63.74): None Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): None Clean Water Act Section 307 Toxic Pollutants (40 CFR 401.15): None Clean Water Act Section 311 Hazardous Chemical (40 CFR 116.4): Phosphoric acid Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3): Component Reportable Quantity phosphoric acid 5,000 lbs North America MSDS 7/8 Page 401 of 878 Page 401 of 878 Page 401 of 878 Page 401 of 878 ---PAGE BREAK--- Krud Kutter® Concrete Clean and Etch 8/28/07 Drug Enforcement Act: None TSCA: None . State Regulations California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): None Massachusetts Right-To-Know List: Phosphoric Acid Minnesota Hazardous Substances List: Phosphoric Acid New Jersey Right-To-Know List: Phosphoric Acid Right-To-Know Substances: Phosphoric Acid 16 OTHER INFORMATION Hazard Ratings Health Hazard Fire Hazard Reactivity Hazard Special Hazard NFPA 2 0 0 N/A Health Hazard Fire Hazard Reactivity Hazard HMIS 2 0 0 0 – Minimal; 1 – Slight; 2 – Moderate; 3 – Serious; 4 – Severe; Chronic health effect Revision Information: New Prepared by: Supreme Chemicals of Georgia, Inc. Issue Date: 8/28/2007 Disclaimer: To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. North America MSDS 8/8 Page 402 of 878 Page 402 of 878 Page 402 of 878 Page 402 of 878 ---PAGE BREAK--- page 1 of 5 DATE OF PREPARATION Jul 5, 2012 MATERIAL SAFETY DATA SHEET K08302 02 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER K08302 PRODUCT NAME KRYLON® LINE-UP™ Striping Paint (Solvent Based), Handicap Blue MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY KRYLON PRODUCTS GROUP Cleveland, OH 44115 Telephone Numbers and Websites Product Information (800) 247-3266 www.kpg-industrial.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 13 74-98-6 Propane ACGIH TLV 2500 PPM 760 mm OSHA PEL 1000 PPM 12 106-97-8 Butane ACGIH TLV 800 PPM 760 mm OSHA PEL 800 PPM 7 64742-89-8 V. M. & P. Naphtha ACGIH TLV 300 PPM 12 mm OSHA PEL 300 PPM OSHA PEL 400 PPM STEL 2 100-41-4 ACGIH TLV 20 PPM 7.1 mm OSHA PEL 100 PPM OSHA PEL 125 PPM STEL 9 1330-20-7 Xylene ACGIH TLV 100 PPM 5.9 mm ACGIH TLV 150 PPM STEL OSHA PEL 100 PPM OSHA PEL 150 PPM STEL 23 67-64-1 Acetone ACGIH TLV 500 PPM 180 mm ACGIH TLV 750 PPM STEL OSHA PEL 1000 PPM 24 471-34-1 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 15 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 3 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION Page 403 of 878 Page 403 of 878 Page 403 of 878 Page 403 of 878 ---PAGE BREAK--- K08302 page 2 of 5 UEL 12.8 LEL 0.9 FLASH POINT Propellant < 0 °F HMIS Codes Health 2* Flammability 3 Reactivity 0 ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system the reproductive system SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. Page 404 of 878 Page 404 of 878 Page 404 of 878 Page 404 of 878 ---PAGE BREAK--- K08302 page 3 of 5 This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 7.30 lb/gal 875 g/l SPECIFIC GRAVITY 0.88 BOILING POINT <0 - 325 °F <-18 - 162 °C MELTING POINT Not Available VOLATILE VOLUME 85% EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 42.75% Less Water and Federally Exempt Solvents SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that causes cancer in humans. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." Page 405 of 878 Page 405 of 878 Page 405 of 878 Page 405 of 878 ---PAGE BREAK--- K08302 page 4 of 5 TOXICOLOGY DATA CAS No. Ingredient Name 74-98-6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106-97-8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 64742-89-8 V. M. & P. Naphtha LC50 RAT 4HR Not Available LD50 RAT Not Available 100-41-4 LC50 RAT 4HR Not Available LD50 RAT 3500 mg/kg 1330-20-7 Xylene LC50 RAT 4HR 5000 ppm LD50 RAT 4300 mg/kg 67-64-1 Acetone LC50 RAT 4HR Not Available LD50 RAT 5800 mg/kg 471-34-1 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U, ADR IATA/ICAO UN1950, AEROSOLS, FLAMMABLE, 2.1, LIMITED QUANTITY SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 100-41-4 2 1330-20-7 Xylene 9 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Page 406 of 878 Page 406 of 878 Page 406 of 878 Page 406 of 878 ---PAGE BREAK--- K08302 page 5 of 5 SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 407 of 878 Page 407 of 878 Page 407 of 878 Page 407 of 878 ---PAGE BREAK--- page 1 of 5 HMIS Codes Health 2* Flammability 3 Reactivity 0 DATE OF PREPARATION Aug 14, 2013 MATERIAL SAFETY DATA SHEET K08302 02 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER K08302 PRODUCT NAME KRYLON® LINE-UP® Striping Paint (Solvent Based), Handicap Blue MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY KRYLON PRODUCTS GROUP Cleveland, OH 44115 Telephone Numbers and Websites Product Information (800) 247-3266 www.kpg-industrial.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 12 74-98-6 Propane ACGIH TLV 1000 PPM 760 mm OSHA PEL 1000 PPM 6 106-97-8 Butane ACGIH TLV 1000 PPM 760 mm OSHA PEL 800 PPM 2 64742-89-8 V. M. & P. Naphtha ACGIH TLV 300 PPM 12 mm OSHA PEL 300 PPM OSHA PEL 400 PPM STEL 21 108-88-3 Toluene ACGIH TLV 20 PPM 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 16 616-38-6 Dimethyl Carbonate ACGIH TLV Not Available 53 mm OSHA PEL Not Available 1 14807-96-6 Talc ACGIH TLV 2 mg/m3 as Resp. Dust OSHA PEL 2 mg/m3 as Resp. Dust 2 471-34-1 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 15 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 1 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. Page 408 of 878 Page 408 of 878 Page 408 of 878 Page 408 of 878 ---PAGE BREAK--- K08302 page 2 of 5 UEL 12.8 LEL 0.9 FLASH POINT Propellant < 0 °F EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system the cardiovascular system the reproductive system SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Page 409 of 878 Page 409 of 878 Page 409 of 878 Page 409 of 878 ---PAGE BREAK--- K08302 page 3 of 5 VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 7.19 lb/gal 861 g/l SPECIFIC GRAVITY 0.87 BOILING POINT <0 - 325 °F <-18 - 162 °C MELTING POINT Not Available VOLATILE VOLUME 95% EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 40.89% Less Water and Federally Exempt Solvents SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." Page 410 of 878 Page 410 of 878 Page 410 of 878 Page 410 of 878 ---PAGE BREAK--- K08302 page 4 of 5 TOXICOLOGY DATA CAS No. Ingredient Name 74-98-6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106-97-8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 64742-89-8 V. M. & P. Naphtha LC50 RAT 4HR Not Available LD50 RAT Not Available 108-88-3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 616-38-6 Dimethyl Carbonate LC50 RAT 4HR Not Available LD50 RAT 13000 mg/kg 14807-96-6 Talc LC50 RAT 4HR Not Available LD50 RAT Not Available 471-34-1 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U IATA/ICAO UN1950, AEROSOLS, FLAMMABLE, 2.1, LIMITED QUANTITY SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 108-88-3 Toluene 21 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Page 411 of 878 Page 411 of 878 Page 411 of 878 Page 411 of 878 ---PAGE BREAK--- K08302 page 5 of 5 SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 412 of 878 Page 412 of 878 Page 412 of 878 Page 412 of 878 ---PAGE BREAK--- page 1 of 5 HMIS Codes Health 2* Flammability 3 Reactivity 0 DATE OF PREPARATION Jun 18, 2013 MATERIAL SAFETY DATA SHEET K08302 02 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER K08302 PRODUCT NAME KRYLON® LINE-UP® Striping Paint (Solvent Based), Handicap Blue MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY KRYLON PRODUCTS GROUP Cleveland, OH 44115 Telephone Numbers and Websites Product Information (800) 247-3266 www.kpg-industrial.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 12 74-98-6 Propane ACGIH TLV 1000 PPM 760 mm OSHA PEL 1000 PPM 6 106-97-8 Butane ACGIH TLV 1000 PPM 760 mm OSHA PEL 800 PPM 2 64742-89-8 V. M. & P. Naphtha ACGIH TLV 300 PPM 12 mm OSHA PEL 300 PPM OSHA PEL 400 PPM STEL 21 108-88-3 Toluene ACGIH TLV 20 PPM 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 16 616-38-6 Dimethyl Carbonate ACGIH TLV Not Available 53 mm OSHA PEL Not Available 1 14807-96-6 Talc ACGIH TLV 2 mg/m3 as Resp. Dust OSHA PEL 2 mg/m3 as Resp. Dust 2 471-34-1 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 15 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 1 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. Page 413 of 878 Page 413 of 878 Page 413 of 878 Page 413 of 878 ---PAGE BREAK--- K08302 page 2 of 5 UEL 12.8 LEL 0.9 FLASH POINT Propellant < 0 °F EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system the cardiovascular system the reproductive system SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Page 414 of 878 Page 414 of 878 Page 414 of 878 Page 414 of 878 ---PAGE BREAK--- K08302 page 3 of 5 VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 7.19 lb/gal 861 g/l SPECIFIC GRAVITY 0.87 BOILING POINT <0 - 325 °F <-18 - 162 °C MELTING POINT Not Available VOLATILE VOLUME 95% EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 40.89% Less Water and Federally Exempt Solvents SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." Page 415 of 878 Page 415 of 878 Page 415 of 878 Page 415 of 878 ---PAGE BREAK--- K08302 page 4 of 5 TOXICOLOGY DATA CAS No. Ingredient Name 74-98-6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106-97-8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 64742-89-8 V. M. & P. Naphtha LC50 RAT 4HR Not Available LD50 RAT Not Available 108-88-3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 616-38-6 Dimethyl Carbonate LC50 RAT 4HR Not Available LD50 RAT 13000 mg/kg 14807-96-6 Talc LC50 RAT 4HR Not Available LD50 RAT Not Available 471-34-1 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U, ADR IATA/ICAO UN1950, AEROSOLS, FLAMMABLE, 2.1, LIMITED QUANTITY SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 108-88-3 Toluene 21 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Page 416 of 878 Page 416 of 878 Page 416 of 878 Page 416 of 878 ---PAGE BREAK--- K08302 page 5 of 5 SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 417 of 878 Page 417 of 878 Page 417 of 878 Page 417 of 878 ---PAGE BREAK--- page 1 of 5 DATE OF PREPARATION Sep 23, 2011 MATERIAL SAFETY DATA SHEET K08302 02 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER K08302 PRODUCT NAME KRYLON® LINE-UP™ Striping Paint (Solvent Based), Handicap Blue MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY KRYLON PRODUCTS GROUP Cleveland, OH 44115 Telephone Numbers and Websites Product Information (800) 247-3266 www.kpg-industrial.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident) * SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 13 74-98-6 Propane ACGIH TLV 2500 PPM 760 mm OSHA PEL 1000 PPM 12 106-97-8 Butane ACGIH TLV 800 PPM 760 mm OSHA PEL 800 PPM 7 64742-89-8 V. M. & P. Naphtha ACGIH TLV 300 PPM 12 mm OSHA PEL 300 PPM OSHA PEL 400 PPM STEL 2 100-41-4 ACGIH TLV 100 PPM 7.1 mm ACGIH TLV 125 PPM STEL OSHA PEL 100 PPM OSHA PEL 125 PPM STEL 9 1330-20-7 Xylene ACGIH TLV 100 PPM 5.9 mm ACGIH TLV 150 PPM STEL OSHA PEL 100 PPM OSHA PEL 150 PPM STEL 23 67-64-1 Acetone ACGIH TLV 500 PPM 180 mm ACGIH TLV 750 PPM STEL OSHA PEL 1000 PPM 24 471-34-1 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 15 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 3 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION Page 418 of 878 Page 418 of 878 Page 418 of 878 Page 418 of 878 ---PAGE BREAK--- K08302 page 2 of 5 UEL 12.8 LEL 0.9 FLASH POINT Propellant < 0 °F HMIS Codes Health 2* Flammability 3 Reactivity 0 ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system the reproductive system SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. Page 419 of 878 Page 419 of 878 Page 419 of 878 Page 419 of 878 ---PAGE BREAK--- K08302 page 3 of 5 This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 7.30 lb/gal 875 g/l SPECIFIC GRAVITY 0.88 BOILING POINT <0 - 325 °F <-18 - 162 °C MELTING POINT Not Available VOLATILE VOLUME 85% EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 42.75% Less Water and Federally Exempt Solvents SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that causes cancer in humans. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." Page 420 of 878 Page 420 of 878 Page 420 of 878 Page 420 of 878 ---PAGE BREAK--- K08302 page 4 of 5 TOXICOLOGY DATA CAS No. Ingredient Name 74-98-6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106-97-8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 64742-89-8 V. M. & P. Naphtha LC50 RAT 4HR Not Available LD50 RAT Not Available 100-41-4 LC50 RAT 4HR Not Available LD50 RAT 3500 mg/kg 1330-20-7 Xylene LC50 RAT 4HR 5000 ppm LD50 RAT 4300 mg/kg 67-64-1 Acetone LC50 RAT 4HR Not Available LD50 RAT 5800 mg/kg 471-34-1 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U, ADR IATA/ICAO UN1950, AEROSOLS, FLAMMABLE, 2.1, LIMITED QUANTITY SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 100-41-4 2 1330-20-7 Xylene 9 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Page 421 of 878 Page 421 of 878 Page 421 of 878 Page 421 of 878 ---PAGE BREAK--- K08302 page 5 of 5 SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 422 of 878 Page 422 of 878 Page 422 of 878 Page 422 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET (COMPLIES WITH 29CFR 1910.1200) SECTION I - CHEMICAL PRODUCT & COMPANY IDENTIFICATION Identity (As Used on Label and List): Lano-Vera Foaming Hand Soap Product Class: Soap Solution Emergency Telephone Number: [PHONE REDACTED] Telephone Number for Information: 1-[PHONE REDACTED] Distributed by: Dalco 300 5th Ave. NW New Brighton, MN 55112 SECTION II - COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Components (Specific Chemical Identity): Chemical Common Name(s) % A Sodium Laureth Sulfate & 2 - 8 Alkyl (Blend) B Sodium Lauryl Sulfate 1 - 5 CAS #68585-47-7 C Cocamidopropyl Betaine 1 - 5 CAS #61789-400 D Lauramide DEA 0.1 - 1 Cas # (mixture) E Water 75 - 100 CAS #7732-18-5 SECTION III - HAZARDS IDENTIFICATION Emergency Overview Appearance and Odor: Pink liquid, citus/floral fragrance. Primary Hazards: No effects expected. Potential Health Hazards Route(s) of Entry: Skin Absorption: Ingestion: X Inhalation: Eye: May cause eye irritation on contact. Skin: No effects expected. Ingestion: May be harmful if swallowed. Inhalation: No hazardous vapors. Signs and of Exposure: May cause irritation to eyes on direct contact. Carcinogenicity: NTP? No IARC Monographs? No OSHA Regulated? No Target Organ No additional data Medical Conditions Generally Aggravated by Exposure: Dermatitis Health Hazards, Chronic: N. Av. SECTION IV - FIRST AID MEASURES Emergency and First Aid Procedures: If Swallowed: If the person can swallow, give several glasses of water. Obtain medical attention. Eye Contact: Flush eyes with running water for at least 15 minutes. If irritation persists, obtain medical attention. Skin Contact: If irritation develops, discontinue Use. Rinse with cool water. Sources Used: Raw material data, general toxicology from the trade for similar products. SECTION V - FIRE FIGHTING MEASURES Flammability: No Autoignition Temperature: N. Ap. Flash Point (method used): None Flammable Limits: N. Ap. LEL UEL Extinguishing Media N. Ap. Water? Foam? Water Fog? Alcohol Foam? CO2? Dry Chemical? Vaporizing Liquid? Other? Special Fire Fighting Procedures: N. Ap. Unusual Fire and Explosion Hazards: N. Av. TDG Flammability Classification: Non-flammable Sensitivity to Mechanical Impact: None Sensitivity to Static Discharge: None SECTION VI - ACCIDENTAL RELEASE MEASURES Steps to be Taken in Case Material is Released or Spilled: Dike and contain spill with inert material (sand, earth, etc). Collect spill with mop, absorbent material (example: floor-dri) or vacuum. Thoroughly rinse affected area with water. SECTION VII - HANDLING AND STORAGE Precautions to be Taken in Handling and Storing: Normal care in handling and storage. Other Precautions: Keep out of reach of children. Keep from freezing. SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION Respiratory Protection (Specify Types): Not required Ventilation: Local Exhaust: Not required Special: Not required Mechanical (General): Not required Other: Not required Protective Gloves: Not required Eye Protection: Approved safety goggles or glasses. Footwear: Not required Other Protective Clothing or Equipment: Not required Work/Hygienic Practices: Do not contaminate food or beverages with cleaning chemicals. SECTION IX - PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: Approximately 212°F pH: 7-8 Specific Gravity (H20) = 1: 1.01 Volatile: > 85 Vapor Density (Air = N. Av. Odor Threshold: N. Av. Evaporation Rate (Butyl Acetate = N. Av. Oil/Water Distribution Solubility in Water: Complete Coefficient: N. Av. Vapor Pressure (MM HG): N. Av. Melting Point: N. Ap. SECTION X - STABILITY AND REACTIVITY Stability: Unstable: Stable: X Conditions to Avoid: N. Ap. Incompatibility (materials to avoid): N. Av. Hazardous Decomposition or By-products: N. Av. Hazardous Polymerization: May occur: Will not occur: X Conditions to Avoid: N. Ap. SECTION XI - TOXICOLOGICAL INFORMATION Chemical OSHA PEL ACGIH TLV Recom. LD50 LC50 A N. Ap. N. Ap. N. Av. N. Av. N. Av. B N. Ap. N. Ap. N. Av. <5 ml/kg N. Av. (rat, oral) C N. Ap. N. Ap. N. Av. N. Av. N. Av. D N. Ap. N. Ap. N. Av. N. Av. N. Av. E N. Ap. N. Ap. N. Av. N. Av. N. Av Teratogen, Mutagen, Reproductive Toxin Status: No Toxicologically Synergistic Products: N. Av. SECTION XII - ECOLOGICAL INFORMATION Ecotoxicological Information: N. Av. Chemical Fate Information: N. Av. SECTION XIII - DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose of spilled material in accordance with local, state and federal regulations. Waste from normal cleaning procedures may be sewered, depending on the materials and/or contaminates being cleaned as well as state, federal and local sewer commission regulations. RCRA Hazard Class: None SECTION XIV - TRANSPORT INFORMATION Shipping Classification: Compound, cleaning liquid, N.O.I. UN Number: N. Ap. Packing Group: N. Ap. SECTION XV - PREPARATION DATA Prepared By: Mike Elms Telephone Number: [PHONE REDACTED] Date: 6/04 SECTION XVI - REGULATORY INFORMATION US Federal Regulations TSCA Status: All ingredients listed. CERCLA Reportable Quality: None SARA Title III Section 302 Extremely Hazardous Chemicals: None Section 311/312 Hazard Category: None Section 313 Toxic Chemicals: Diethanolamine (DEA) State Regulations NOTICE STATE OF CALIFORNIA Warning: This product may contain chemicals known to the State of California to cause cancer or reproductive defects as trace impurities in the standard industrial materials used in the manufacture of this product. International Regulations WHMIS Controlled Product Hazard Class: N. Ap. SECTION XVII - OTHER INFORMATION None N. Ap. - Not Applicable; N.Av. - Not Available NFPA SYSTEM A. Health Hazard A. Fire Hazard A. Reactivity Hazard THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE, HOWEVER NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. MINUTEMAN INTERNATIONAL, INC. ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE TO VENDEES, USERS OR THIRD PARTIES CAUSED BY THE MATERIAL. SUCH VENDEES OR USERS ASSUME ALL RISKS ASSOCIATED WITH THE USE OF THE MATERIAL. Page 423 of 878 Page 423 of 878 Page 423 of 878 Page 423 of 878 ---PAGE BREAK--- TRI-CHEM CORPORATION MATERIAL SAFETY DATA SHEET MFG.CODE # SECTION I MANUFACTURER’S NAME TRI-CHEM CORPORATION EMERGENCY TELEPHONE NO. CHEMTREC [PHONE REDACTED] ADDRESS (Street, City, State and Zip Code) P. O. BOX 71550, MADISON HGTS., MI 48071-0550 CHEMICAL NAME AND SYNONYMS N/A TRADE NAME AND SYNONYMS LECTRA SOL TC (AEROSOL) CHEMICAL FAMILY N/A FORMULA N/A SECTION II – HAZARDOUS INGREDIENTS HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES % TLV (UNITS) Trichloroethylene (CAS# 79-01-6) >1 50 ppm Carbon Dioxide (CAS# 124-38-9) >1 5000 ppm This product contains 14 ounces of Trichloroethylene per can of product. Trichloroethylene is a regulated chemical under the Emergency Planning and Right-To-Know Act. You are required to file E.P.A. SARA repots once the threshold of 10,000 pounds of Trichloroethylene has been purchased for one location in each calendar year. All components of this product are listed on the E.P.A./TSCA inventory of chemical substances. SECTION III – PHYSICAL DATA BOILING POINT (ºF) 189° F SPECIFIC GRAVITY (H2O = 1) 1.4 VAPOR PRESSURE (in can PSIG) 95-105 PERCENT VOLATILE BY VOLUME 100 VAPOR DENSITY (AIR = 1) 4 EVAPORATION RATE ( Butyl Acetate faster SOLUBILITY IN WATER insoluble PH N/A APPEARANCE AND ODOR Clear water white liquid with an etherial odor. SECTION IV – FIRE AND EXPLOSION DATA Lel Uel FLASH POINT (Method Used) None FLAMMABLE LIMITS 8.0 52.0 EXTINGUISHING MEDIA Use extinguishing media suitable for fighting surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES Fire fighters should wear full protective clothing including self-contained respiratory equipment operated in a positive mode. Use water spray to keep containers cool. UNUSUAL FIRE AND EXPLOSION HAZARDS Cans may vent, rupture, or burst when exposed to temperatures in excess of 120ºF. (Continued on reverse side) Page 424 of 878 Page 424 of 878 Page 424 of 878 Page 424 of 878 ---PAGE BREAK--- SECTION V – HEALTH HAZARD DATA THRESHOLD LIMIT VALUE 50 ppm PRIMARY ROUTES OF ENTRY Inhalation x Skin Contact x Other (Specify) EFFECTS OF OVEREXPOSURE Eyes- liquid and vapors may cause irritation. Skin- dry skin, irritation. Inhalation- narcosis, headache, dizziness, carboxyhemoglobinemia. Alcohol consumed before exposure increases effects. EMERGENCY AND FIRST AID PROCEDURE Eyes- flush with copious amounts of water lifting lids and removing contact lenses to ensure complete irrigation- get medical attention. Skin- flush with water and then wash with soap and water, launder contaminated clothing before reuse- get medical if irritation persists. Inhalation- remove to fresh air and assist breathing as necessary- get medical attention. Ingestion- DO NOT INDUCE VOMITING- aspiration of material into lungs may cause chemical pneumonitis which can be fatal- get medical attention. Use gastric lavage. Never use adrenalin. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Persons with pre-existing heart or respiratory disorders Carcinogen: NTP IARC OTHER X California Prop 65 SECTION VI – REACTIVITY DATA UNSTABLE STABILITY STABLE x CONDITIONS TO AVOID Temperatures in excess of 120ºF. INCOMPATABILITY (Conditions to avoid) Strong Oxidizers and Alkalies, reactive metals HAZARDOUS DECOMPOSITION PRODUCTS Oxides of Carbon, Hydrogen Chloride, Phosgene MAY OCCUR HAZARDOUS POLYMERIZATION WILL NOT OCCUR x CONDITIONS TO AVOID None SECTION VII – SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Ventilate spill area. Dike area to contain spill and use absorbent material to soak up spill. Shovel or sweep into for container for disposal. WASTE DISPOSAL METHOD Aerosol cans when emptied and depressurized through normal use pose no disposal hazard and should be recycled. Absorbent materials should be disposed of in accordance with all Local, State, and Federal regulations. SECTION VIII – SPECIAL PROTECTION INFORMATION SPECIAL RESPIRATORY PROTECTION (Specify type) Use NIOSH approved respirator in areas where TLV has been exceeded. LOCAL EXHAUST To control TLV SPECIAL N/A VENTILATION MECHANICAL (General) To control TLV OTHER N/A PROTECTIVE GLOVES Impervious EYE PROTECTION Chemical Goggles OTHER PROTECTIVE EQUIPMENT Eyewash and safety shower. SECTION IX – SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Avoid contact- wear protective clothing and wash thoroughly after using. Avoid inhalation of vapors- do not use in confined, poorly ventilated, or other areas where TLV may be exceeded without proper respiratory protection. Do not take internally. OTHER PRECAUTIONS Do not store in areas where temperatures may exceed 120 degrees F. Keep Out of Reach of Children. HMIS SYMBOL SEVERE 4 SERIOUS 3 MODERATE 2 SLIGHT 1 MINIMAL 0 NAME John Telles SIGNATURE TITLE CHEMIST PREPARATION DATE June 19, 2012 PHONE NUMBER CHEMTREC [PHONE REDACTED] HEALTH 2 FLAMMABILITY 1 REACTIVITY 0 Page 425 of 878 Page 425 of 878 Page 425 of 878 Page 425 of 878 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 28-May-2013 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 19907 Product name Light Oil Lubricant Recommended Use Lubricant Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Eyes. Ingestion. Inhalation. Skin contact. Skin absorption. Potential health effects Eyes Exposure to vapors or mists may cause the following effects:. Irritation. Pain. Tearing. Reddening. Swelling. Stinging sensation. Feeling like that of fine dust in the eye. Skin Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. Chronic exposure causes drying effect on the skin . Inhalation Harmful by inhalation. Repeated or prolonged exposure may cause the following effects:. Headaches. Dizziness. Nausea. Decreased blood pressure. Changes in heart rate. Cyanosis. Chronic overexposure can cause: . Lung damage. Ingestion Harmful or fatal if swallowed. If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach. Extreme overexposure may cause. Kidney damage. Liver abnormalities. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % VM&P Naphtha 8032-32-4 10-30 Propane/Isobutane/N- Butane 68476-86-8 10-30 Paraffinic Mineral Oil 8042-47-5 3-7 4. FIRST AID MEASURES Eye contact Flush eyes with plenty of water. Seek medical attention if irritation persists. Skin contact Flush skin with water. Remove and wash contaminated clothing before re-use. Seek medical attention immediately. Ingestion Seek medical attention immediately. Do not induce vomiting. Give victim a glass of water or milk. Call a physician or Poison Control Center immediately. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Immediate medical attention is required. 5. FIRE FIGHTING MEASURES Flash point °C -104 Flash point °F -156 Method Pensky-Martens C.C. Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 9.5 Lower 1.1 Suitable extinguishing media Alcohol foam. Carbon dioxide. Dry chemical powder. Foam. Water fog. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Page 1 / 4 Emergency Overview Vapors extremely irritating to eyes and respiratory tract. Vapors may cause flash fire or explosion. Page 426 of 878 Page 426 of 878 Page 426 of 878 Page 426 of 878 ---PAGE BREAK--- Fire and Explosion Hazards Flash back possible over considerable distance. Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Empty containers contain residue and/or vapors. Do not weld, cut, pressurize, braze, solder, drill, grind, or expose such containers to heat, sparks, flame, static electricity, or other sources of ignition. They may explode and cause injury or death. Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Place in suitable container for disposal as hazardous waste. 7. HANDLING AND STORAGE Handling Thoroughly wash hands and exposed skin after handling. Remove and wash contaminated clothing before re-use. Ensure adequate ventilation. Use only according to label directions. Avoid contact with skin, eyes and clothing. Avoid breathing vapors from heated material . Storage Keep away from heat and sources of ignition. Do not freeze. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) VM&P Naphtha - - - - Propane/Isob utane/N- Butane - - - - Paraffinic Mineral Oil - - - - Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Hygiene measures Wash hands before breaks and immediately after handling the product. Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes and clothing. Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Protection provided by air purifying respirators is limited. Use a positive pressure supplied air respirator. if there is any potential for an uncontrolled release:. where exposure levels are not known. or other circumstances where an air purifying respirator (P100) may not provide adequate protection . Hand Protection Chemical resistant gloves. Eye protection Use safety eyewear designed to protect against impact. Skin and body protection None necessary under normal conditions Other Protective Equipment Wear appropriate clothing to prevent skin contact. Rubber boots. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Clear Odor Solvent Odor Threshold No information available pH Not Applicable Specific Gravity 0.8428 Vapor pressure 80-90 Vapor density >Air Evaporation Rate >1 (Butyl Acetate = 1) Water solubility Negligible VOC Content 2.04 lbs/gal; 244 g/l Partition Coefficient (n-octanol/water) No data available Boiling point/range °C -41 - 142 Boiling point/range °F -43 - 287 Melting point/range °C 0 Melting point/range °F 32 Flash point °C -104 Flash point °F -156 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Do not use near other sources of ignition. Do not use near welding arcs. Avoid open flames. Page 2 / 4 Product code 19907 Product name Light Oil Lubricant Page 427 of 878 Page 427 of 878 Page 427 of 878 Page 427 of 878 ---PAGE BREAK--- Incompatability Strong acids. Alkalies. Oxidizers. Amines. Hazardous Decomposition Products Sulphur oxides. Carbon oxides. Nitrogen oxides (NOx). Chlorides. Chlorine. Phosgene . Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) VM&P Naphtha 8032-32-4 - - 3400 ppm Propane/Isobutan e/N-Butane 68476-86-8 - - - Paraffinic Mineral Oil 8042-47-5 5000 mg/kg - - Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity None known Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects May cause damage to liver. May cause damage to kidneys. Central nervous system. Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns VM&P Naphtha Not Listed Not Listed Not Listed Not Listed Not Listed Propane/Isob utane/N- Butane Not Listed Not Listed Not Listed Not Listed Not Listed Paraffinic Mineral Oil Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT UN1950 Aerosols, flammable, 2.1. Exception: (Compressed Gas not more than 1.0L) Consumer Commodity ORM-D TDG UN1950 AEROSOLS, flammable, 2.1 Consumer commodity <1L 15. REGULATORY INFORMATION State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 VM&P Naphtha Not Listed Listed Not Listed Propane/Isobutane/N- Butane Not Listed Not Listed Not Listed Paraffinic Mineral Oil Not Listed Not Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA VM&P Naphtha X X - X Propane/Isobutane/N- Butane X X - X Paraffinic Mineral Oil X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. OTHER INFORMATION HMIS Health - 1 Flammability - 4 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer Page 3 / 4 Product code 19907 Product name Light Oil Lubricant Page 428 of 878 Page 428 of 878 Page 428 of 878 Page 428 of 878 ---PAGE BREAK--- The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product code 19907 Product name Light Oil Lubricant Page 429 of 878 Page 429 of 878 Page 429 of 878 Page 429 of 878 ---PAGE BREAK--- Gain Hand Dishwashing Liquid and Antibacterial Hand Soap Page 1 of 4 The Procter & Gamble Company P&G Household Care Fabric & Home Care Innovation Center 5299 Spring Grove Avenue Cincinnati, OH 45217-1087 MATERIAL SAFETY DATA SHEET MSDS RQ1400299/ RQ1402524/RQ1402799 Issue Date: 08/28/2014 Supersedes: RQ1212667 / RQ1309635 / RQ1310079 Issue Date: 06/11/2014 SECTION I - PRODUCT IDENTIFICATION Identity: Liquid Hand Dishwashing Detergents Brand: GAIN Finished Products Covered: Ultra Gain Original Fresh [96664093] Ultra Gain Apple Berry Twist [96664091] Ultra Gain Spring Lavender [96664082] Ultra Gain Island Fresh [96664100] Ultra Gain Bleach Alternative Honey Berry Hula [96708849] Fresh Arapids [96708850] Ultra Gain Lemon Zest Dishwashing Liquid/Antibacterial Hand Soap [96664044] GAIN Ultra Hawaiian Aloha [96664158] Ultra Gain Moonlight Breeze [96866930] P&G Telephone Number: 1-[PHONE REDACTED] or call Local Poison Control Center or your physician. SECTION II - HAZARDS IDENTIFICATION Potential Health Hazards (Acute and Chronic): (See Section 11 for more information) Ingestion: Ingestion may cause transient gastrointestinal irritation. Eye Contact: May cause mild, transient irritation. Skin: Transient irritation with prolonged exposure to concentrated material. Inhalation: N/A Signs and of Exposure: Ingestion: May result in nausea, vomiting, and/or diarrhea. Eye Contact: May cause stinging, tearing, itching, swelling, and/or redness. Skin: Prolonged contact with concentrated material may be drying or transiently irritating to skin. Inhalation: N/A Potential Environmental Effects: (See Section 12 for more information) SECTION III - COMPOSITION AND INGREDIENTS Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200. and/or WHMIS under the HPA: CHEMICAL NAME COMMON NAME CAS RN COMPOSITION RANGE LD50/LC50 Ethyl alcohol Ethanol 64-17-5 0.1 – 1% LD50(oral, rat) – 7.06 g/kg These substances are listed because in their pure bulk form they meet the OSHA and/or WHMIS definition of hazardous. Any hazards associated with this finished product are listed in Section II of this MSDS. Page 430 of 878 Page 430 of 878 Page 430 of 878 Page 430 of 878 ---PAGE BREAK--- Gain Hand Dishwashing Liquid and Antibacterial Hand Soap Page 2 of 4 SECTION IV – FIRST AID INFORMATION First Aid Procedures: Ingestion: Drink 1 or 2 glasses of water. Eye Contact: Flush thoroughly with water for 15 minutes. Skin: If prolonged contact occurs, rinse thoroughly with water. If spilled on clothing, change clothes. If persist or recur, seek medical attention. Inhalation: N/A Other: Consumer product package has the following precautionary statement on the back label: “For external use only. Keep out of the reach of children. If Dawn gets in eyes, rinse thoroughly with water. If swallowed, drink a glass of water to dilute.” SECTION V - FIRE FIGHTING INFORMATION Flammable Properties: The liquid hand dishwashing detergents have a flashpoint of 115-135°F (46.1-57.2°C) Pensky-Martens (Closed cup). However, the detergents do not sustain combustion according to ASTM D4206. Flammable Properties: Upper Flammable Limit: N/A Lower Flammable Limit: N/A Explosive Limits: UEL: N/A LEL: N/A Auto-ignition Temperature: N/A Hazardous Combustion Products: N/A Explosion Data (Sensitivity to Mechanical Impact): N/A Explosion Data (Sensitivity to Static Discharge): N/A Extinguishing Media: Suitable: CO2, water or dry chemical may be used. Unsuitable: N/K Protection of Firefighters: Specific Hazards Arising from the Material: None. SECTION VI - ACCIDENTAL RELEASE MEASURES Personal Precautions: None Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS. Solutions of the detergents may be allowed to be flushed down sewer - First check with your local water treatment plant. Recycling is recommended for undiluted scrap product. Do not landfill. Steps To Be Taken in Case Material is Released or Spilled: Prevent spills from reaching a waterway. Sorbents may be used. Read “Waste Disposal Method” below for further information. SECTION VII – HANDLING AND STORAGE Precautions To Be Taken in Handling: No special precautions necessary. Precautions To Be Taken in Storage: No special precautions necessary. SECTION VIII - EXPOSURE CONTROLS / PERSONAL PROTECTION Recommended Exposure Guidelines: N/A Engineering Controls: N/A Personal Protective Equipment (PPE): N/A Eye/Face Protection: None required with normal household use. Industrial Setting: For splash protection, use chemical goggles. Eye wash fountain is recommended. Skin Protection: None required with normal household use. Industrial Setting: Protective gloves (rubber, neoprene) should be used for prolonged direct contact. Respiratory Protection: No special precautions for casual exposure. Page 431 of 878 Page 431 of 878 Page 431 of 878 Page 431 of 878 ---PAGE BREAK--- Gain Hand Dishwashing Liquid and Antibacterial Hand Soap Page 3 of 4 Ventilation Local Exhaust: None required with normal consumer use. Special: None Industrial (General): Normal/general dilution ventilation is acceptable. Other: None SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES Appearance (color, physical form, shape): Clear, opaque or colored liquids. Flash Point (Method Used): 115-135°F (46.1-57.2°C) Pensky-Martens (Closed cup) but do not sustain combustion according to ASTM D4206. Odor: Perfumed Reserve Alkalinity: N/A Odor Threshold: N/A Solubility in Water: Complete Physical State: Liquid hand dishwashing solution Decomposition Temperature: N/K Vapor Pressure (mm Hg): N/K Evaporation Rate (nBuOAc=1): N/K Vapor Density (Air=1): N/K Specific Gravity/Density: ca. 1 Boiling Point: N/K Melting/Freezing Point: ~ 30 °F Partition Coefficient (n-octanol/water): N/K pH (10% solution): 9 Volatile Organic Compound (VOC): Not applicable - Product not regulated for VOC Content at State or Federal level SECTION X - STABILITY AND REACTIVITY Chemical Stability: Stable Conditions to Avoid: None known Incompatible Materials: None Hazardous Decomposition Products: None known Possibility of Hazardous Reactions: None known SECTION XI - TOXICOLOGICAL INFORMATION Liquid hand dishwashing detergents have a relatively low order of toxicity, may cause transient irritation and are expected to be emetic. Chronic Effects: No chronic health effects reported. Target Organs: No target organs reported. Carcinogenicity: This finished product is not carcinogenic. NTP: No IARC: No OSHA: No SECTION XII - ECOLOGICAL INFORMATION All surfactants are readily biodegradable. SECTION XIII - DISPOSAL CONSIDERATIONS Waste Disposal Method: DISPOSAL SHOULD BE IN ACCORDANCE WITH FEDERAL, STATE/PROVINCIAL AND LOCAL REGULATIONS Non Household Setting: Products covered by this MSDS, in their original form, when disposed as waste, are considered non hazardous waste according to Federal RCRA regulations (40 CFR 261). Disposal should be in accordance with local, state and federal regulations. Solutions of diluted detergent in the course of use, may be allowed to be flushed down sewer. First check with your local water treatment plant. Recycling is recommended for undiluted scrap product. Do not landfill. California Hazardous Waste: Not hazardous, in accordance with 22 CCR 66261.20 through 22 CCR 66261.24 Household Use: Household product is safe for disposal down the drain during detergent use or in the trash. Dispose of empty bottle in the trash or recyle where facilities exist. SECTION XIV - TRANSPORT INFORMATION Products covered by this MSDS, in their original form, are not regulated for transportation. Page 432 of 878 Page 432 of 878 Page 432 of 878 Page 432 of 878 ---PAGE BREAK--- Gain Hand Dishwashing Liquid and Antibacterial Hand Soap Page 4 of 4 Ground Transport (US DOT): Not regulated Air Transport (IATA): Not regulated Marine/Water Transport (IMDG): Not regulated SECTION XV - REGULATORY INFORMATION United States All intentionally-added components of this product are listed on the US TSCA Inventory. This product is not subject to warning labeling under California Proposition 65. EPA Reg. No.: Not Applicable This product contains the following SARA 313/302/304/311/312 chemicals: None This product contains the following CERCLA chemicals: Ethanol 64-17-5 1.0% Chemical Name CAS Number Max Range in Product State Right-to-Know: The following ingredients present in the finished product are listed on state right-to-know lists or state worker exposure lists: INGREDIENT CAS RN MAX LEVEL STATE IL MA NJ PA RI Ethanol 64-17-5 1.0 % X X X X X Perfumes contained within the products covered by this MSDS comply with appropriate IFRA guidance Canada All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and this MSDS contains all information required by the Controlled Products Regulations. SECTION XVI - OTHER INFORMATION Perfumes contained within the products covered by this MSDS comply with appropriate IFRA guidance. P&G Hazard Rating: Health: 1 4=EXTREME Flammability: 1 3=HIGH Reactivity: 0 2=MODERATE 1=SLIGHT 0=NOT SIGNIFICANT *N/A. - Not Applicable *N/K. - Not Known Data supplied is for use only in connection with occupational safety and health. DISCLAIMER: This MSDS is intended to provide a brief summary of our knowledge and guidance regarding the use of this material. The information contained here has been compiled from sources considered by Procter & Gamble to be dependable and is accurate to the best of the Company’s knowledge. It is not meant to be an all- inclusive document on worldwide hazard communication regulations. This information is offered in good faith. Each user of this material needs to evaluate the conditions of use and design the appropriate protective mechanisms to prevent employee exposures, property damage or release to the environment. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, or for any damage to any property resulting from misuse of the product. Page 433 of 878 Page 433 of 878 Page 433 of 878 Page 433 of 878 ---PAGE BREAK--- SAFETY DATA SHEET 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: LIQUID ICE-CHEK ACTIVATOR F.185 24 Hour Emergency CHEMTREC Number: [PHONE REDACTED] Product Description: De-icing, anti-icing formula. MSDS Number: M00403 EPA Registration Number: NA EPA Establishment Number: NA 2. HAZARDS IDENTIFICATION ***EMERGENCY OVERVIEW*** FIFRA Hazard Classification: Not Applicable Skin corrosion/irritation: Category 3 Serious eye damage/eye irritation: Category 2B Acute toxicity; oral: Category 4 Exclamation Mark WARNING Hazard Statements: H316 Causes mild skin irritation. H320 Causes eye irritation. H302 Harmful if swallowed. Precautionary Statements: P270 Do not eat, drink or smoke when using this product. P264 Wash hands thoroughly after handling. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredients CAS Number Weight ACGIH OSHA Ethylene Glycol 107-21-1 <80% NE 50 ppm 4. FIRST AID MEASURES P337+P313 IF eye irritation persists: Get medical advice. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332+P313 IF SKIN irritation occurs: Get medical attention. P301+P312 IF SWALLOWED: call a POISON CENTER or physician if you feel unwell. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. 5. FIRE FIGHTING MEASURES Flashpoint(Method): >275°F [COC] Lower Explosive Limit(LEL): NA Upper Explosive Limit(UEL): NA Autoignition Temperature: NA Flammable Properties: None Expected Extinguishing Media: Carbon Dioxide, dry chemical, foam. Fire Fighting Instructions: Wear self-contained breathing apparatus and full protective clothing. Contains oil, water is not effective in fire fighting. Water may be used to coolclosed containers to prevent possible explosive when exposed to extreme heat. 6. ACCIDENTAL RELEASE MEASURES Ventilate area. Halt spill at source, dike and contain spill. Flush with plenty of water to drain. Dispose of in accordance with Federal, State and Local Regulations regarding waste disposal. 7. HANDLING AND STORAGE P402 Store in dry place. P405 Store locked up. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering Controls: Use general or local ventilation to keep exposure levels below exposure limits. Personal Protective Equipment: Personal Protective Equipment: Respiratory: Use respirable fume respirator or air supplied respirator when soldering in confined space or where local exhaust or ventilation does not keep exposure Respiratory: Normal room ventilation is adequate. Use a NIOSH/MHSA approved respirator if exposure limits are exceeded. Eye: Wear approved safety glasses or goggles with unperforated eyeshields where splashing may occur. Skin: For repeated or prolonged contact, wear chemically impervious gloves such as Nitrile. Other: An emergency eyewash station or source of clean potable water should be available in case of accidental eye contact. Page 434 of 878 Page 434 of 878 Page 434 of 878 Page 434 of 878 ---PAGE BREAK--- 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Orange Odor: Mild. Physical State: Liquid. pH: NA Solubility in Water: 100% Diluted pH: NA Boiling Point: NA Specific Gravity: 1.147 Freezing Point: NA VOC Content: NA Melting Point: NA 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur. Conditions to Avoid: Strong oxidizers, acids, active metals, aluminum, zinc, tin and alloys. Incompatibility: Solvents, caustics, acids or oxidizers Hazardous Decomposition Products: Carbon Dioxide, Carbon Monoxide,Oxides of Nitrogen. 11. TOXICOLOGICAL INFORMATION This product contains no ingredient at 0.1% or greater that is listed as a human carcinogen. Hazardous Ingredients CAS Number LD50 LC50 Ethylene Glycol 107-21-1 8.57 g/kg (oral rat) > 10000 mg/l/96 hr (flathead minnow) 12. ECOLOGICAL INFORMATION Do not discharge to natural waters. Advise authorities if product has entered or may enter sewers, watercourses or extensive land areas. 13. DISPOSAL CONSIDERATIONS P501 Dispose of container in accordance with all Federal, State and Local Regulations regarding waste disposal. 14. TRANSPORT INFORMATION DOT Shipping Data: Not Regulated Canadian TDG: Not Regulated For International Shipments by Air: NA For International Shipments by Vessel: NA 15. REGULATORY INFORMATION TSCA: All ingredients in this product are listed or exempt from listing on the TSCA Chemical Inventory. CEPA: All ingredients in this product are listed or exempt from listing on the Canadian DSL/NDSL. Proposition 65: This product may contain trace amounts of the following chemicals that are known to the state of California to cause cancer, birth defects or other reproductive harm: D&C Red No. 19 81-88-9 1 ppm, Acetaldehyde 75-07-0 < 8 ppm, 1,4 Dioxane 123-91-1 < 0.20 ppm SARA 313: This product contains the following toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40CFR372): Glycol Ethers VOC: NA HMIS RATING: HEALTH = 2 FLAMMABILITY = 0 REACTIVITY = 0 PPE = B WHMIS RATING: Class D, Division 2B 16. OTHER INFORMATION NA = Not Available or Not Applicable NE = Not Established Read and follow all label directions and precautions before using the product. This product is intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF THE REACH OF CHILDREN. While we believe that the data contained herein is factual and the opinions expressed are those of qualified experts, the data are not to be taken as a warranty or representation for which the company assumes legal responsibility. They are offered solely for your consideration, investigation, and verification. Any use of these data and information must be determined by the user to be in accordance with applicable Federal, State, and Local Laws and regulations. Prepared On: 08/11/2015 Replaces: 09/01/2012 Page 435 of 878 Page 435 of 878 Page 435 of 878 Page 435 of 878 ---PAGE BREAK--- FICHE SIGNALÉTIQUE DE SÉCURITÉ 1. IDENTIFICATION DU PRODUIT CHIMIQUE ET DE LA SOCIÉTÉ Nom du produit : LIQUID ICE-CHEK ACTIVATOR F.185 Numéro d’urgence CHEMTREC 24 h/24 : [PHONE REDACTED] Description du produit : solution dégivrante et antigel Numéro de la fiche signalétique de produit : M00403 EPA Registration Number : NA EPA Establishment Number : NA 2. IDENTIFICATION DES DANGERS ***VUE GÉNÉRALE D’URGENCE*** Point d’exclamation AVERTISSEMENT Mention de danger: H316 Provoque une légère irritation de la peau. H320 Provoque une irritation des yeux/Lésions oculaires/irritation des yeux graves. H302 Nocif en cas d’ingestion. Conseils de prudence: P270 Ne pas manger, boire ou fumer en manipulant ce produit. P264 Se laver soigneusement la peau après manutention. 3. COMPOSITION/INFORMATION SUR LES INGRÉDIENTS Ingrédients dangereux Numéro CAS Poids ACGIH OSHA éthylène glycol 107-21-1 <80% NE 50 ppm 4. PREMIERS SOINS P337+P313 Si l’irritation oculaire persiste: consulter un médecin. P305+P351+P338 EN CAS DE CONTACT AVEC LES YEUX: rincer avec précaution à l’eau pendant plusieurs minutes. Enlever les lentilles de contact si la victime en porte et si elles peuvent être facilement enlevées. Continuer à rincer. P332+P313 En cas d’irritation cutanée: consulter un médecin. P301+P312 EN CAS D’INGESTION : Appeler un CENTRE ANTIPOISON ou un médecin en cas de malaise. P301+P330+P331 EN CAS D’INGESTION : Rincer la bouche. NE PAS faire vomir. 5. EN CAS D’INCENDIE Point d’éclair : >275°F [COC] Limite d’explosivité inférieure (LIE) : NA Limite d’explosivité supérieure (LSE) : NA Température d’auto-inflammation : NA Propriétés d’inflammabilité : aucune présumée Moyens d’extinction : Dioxyde de carbone, poudre chimique, mousse extinctrice. Lutte contre l’incendie : Porter un appareil respiratoire autonome et une tenue protectrice intégrale. Contient de l’huile, l’eau n’est pas un moyen d’extinction efficace. Utiliser de l’eau pour rafraîchir les récipients hermétiques exposés à une chaleur extrême pour écarter les risques d’explosion. 6. ÉMISSIONS ACCIDENTELLES Ventiler la zone. Interrompre le déversement à la source, l’endiguer et le contenir. Évacuer à grande eau. Éliminer conformément aux réglementations fédérale, provinciale et locale en vigueuren matière d’élimination des déchets 7. MANIPULATION ET CONSERVATION P402 Stocker dans un endroit sec. P405 Entreposer dans un endroit verrouillé. 8. EXPOSITION/PROTECTION INDIVIDUELLE Moyens techniques : Assurer une ventilation forcée adéquate pour maintenir l’exposition en deçà de la valeur limite d’exposition. Équipement de protection individuelle : Équipement de protection individuelle : Équipement de protection individuelle : respiratoire : Utiliser un appareil respiratoire pour vapeurs inahalables ou un appareil respiratoire à adduction d’air pour souder dans les espaces fermés ou dans les endroits où l’aspiration ou la ventilation locales ne suffisent pas à maintenir l’exposition en dessous de son seuil limite admissible. Respiratoire : La ventilation normale est suffisante. Si les limites d’exposition sont dépassées, utiliser un appareil respiratoire agréé NIOSH/MSHA. Oculaire : Porter des lunettes de protection homologuées munies d’écrans latéraux non perforés. Cutanée : En cas de contact répété ou prolongé, porter des gants de protection chimique. Autre : Un bassin oculaire d’urgence ou une source d’eau potable propre devrait être prêt à être utilisé en cas de contact oculaire accidentel. 9. PROPRIÉTÉS PHYSIQUES ET CH IMIQUES Aspect : Orange Odeur : Doux État de la matière : Liquide Concentrer pH : NA Page 436 of 878 Page 436 of 878 Page 436 of 878 Page 436 of 878 ---PAGE BREAK--- Solubilité dans l’eau : 100% Dilué pH : NA Contenu de VOC : NA Densité : NA Point de congélation/fusion : NA / NA 10. STABILITÉ ET RÉACTIVITÉ Stabilité : Stable Polymérisation dangereuse : Ne se produira pas. Conditions à éviter : Oxydants forts, acides, métaux actifs, l’aluminium, le zinc, l’étain et alliages. Incompatibilité : Les solvants, les produits caustiques, acides ou oxydants Produits de décomposition dangereuse : Dioxyde de carbone, monoxyde de carbone, oxydes d’azote. 11. INFORMATIONS TOXICOLOGIQUES Ce produit ne contient aucun ingrédient déclaré cancérogène humain à des teneurs supérieures ou égales à 0,1 Ingrédients dangereux Numéro CAS LD50 LC50 éthylène glycol 107-21-1 8.57 g/kg (oral rat) > 10000 mg/l/96 hr (flathead minnow) 12. INFORMATIONS ÉCOLOGIQUES Ne pas vidanger dans les eaux naturelles. Aviser les autorités si le produit a pénétré ou peut pénétrer des égouts, des cours d’eau ou des zones de terrains étendus. 13. DESTRUCTION P501 Éliminer le contenant conformément à tous les règlements fédéraux, d’État et locales en matière d’élimination des déchets. 14. TRANSPORT INFORMATION DE TRANSPORT D.O.T. : non réglementé. TMD AU CANADA : non réglementé. Pour les expéditions internationales par Air : NA Pour les expéditions internationales par Vessel : NA 15. INFORMATIONs RÉGLEMENTAIRES TSCA : Tous les ingrédients contenus dans ce produit figurent ou sont exempts de figurer sur l’inventaire du TSCA. CEPA : Tous les ingrédients contenus dans ce produit figurent ou sont exempts de figurer sur la LIS et la LES (Canada). Proposition 65 : Ce produit peut contenir des traces de ce qui suit des produits chimiques qui sont connus de l’état de Californie pour causer le cancer, des malformations congénitales ou d’autres anomalies de la reproduction: D & C Red No. 19 81-88-9 1 75-07-0 ppm, Acetaldehyde <8 ppm1, 4 dioxane 123-91-1 <0,20 ppm SARA 313 : Ce produit contient les substances chimiques suivantes devant être déclarées aux termes de la section 313 de la loi Emergency Planning and Community Right-To-Know Act de 1986 (40CFR372) :Éthers glycoliques < 0,50 % CLASSIFICATION HMIS : SANTÉ = 2 INFLAMMABILITÉ = 0 RÉACTIVITÉ = 0 EPS = B CLASSIFICATION SIMDUT : Classe D, Division 2B 16. AUTRES INFORMATIONS néant = Non disponible ou sans objet n.e. = Non établi Lire et suivre toutes les instructions et les précautions d’emploi figurant sur l’étiquette avant d’utiliser le produit. Ces produits sont réservés uniquement à l’usage industriel et par les collectivités. CES PRODUITS NE SONT PAS DESTINÉS À L’USAGE DOMESTIQUE OU À LA REVENTE. GARDER HORS DE LA PORTÉE DES ENFANTS. Bien qu’à notre avis les informations énoncées ci-dessus soient réelles et que le jugement exprimé soit celui d’experts qualifiés, elles ne doivent pas être considérées comme une garantie ou une déclaration pour lesquelles la société assume une responsabilité légale. Ces informations sont données uniquement pour examen, investigation et vérification. L’utilisation des ces informations doit être déterminée par l’utilisateur conformément à la réglementation et à la loi fédérales, d’État et régionales applicables. INFORMATIONS SUR LA SANTÉ ET LA SÉCURITÉ : (216) 861-7114 Date de Préparation: 08/11/2015 Remplace : 09/01/2012 Page 437 of 878 Page 437 of 878 Page 437 of 878 Page 437 of 878 ---PAGE BREAK--- PLANILLA DE DATOS DE SEGURIDAD 1. PRODUCTO QUÍMICO Y DATOS DE LA COMPAÑÍA Nombre del producto: LIQUID ICE-CHEK ACTIVATOR F.185 Núm. CHEMTREC las 24 horas: [PHONE REDACTED] Descripción del producto: Fórmula descongelante y anticongelante. Número MSDS: M00403 EPA Registration Number: NA EPA Establishment Number: NA 2. ENUMERACIÓN DE PELIGROS ***DESCRIPCIÓN GENERAL DE LAS SITUACIONES DE EMERGENCIA*** Signo de exclamación ADVERTENCIA H316 Causa leve corrosión/irritación en la piel. H320 Causa irritacion en los ojos/Serio daño en los ojos/irritación en los ojos. H302 Nocivo en caso de ingestión. P270 No comer, beber ni fumar durante su utilización. P264 Lavar la piel meticulosamente después de la manipulación. 3. COMPOSICIÓN/INFORMACIÓN SOBRE LOS COMPONENTES Componentes peligrosos Número CAS Peso ACGIH OSHA glicol etileno 107-21-1 <80% NE 50 ppm 4. MEDIDAS DE PRIMEROS AUXILIOS P337+P313 Si persiste la irritación ocular: Consultar a un médico. P305+P351+P338 EN CASO DE CONTACTO CON LOS OJOS: Aclarar cuidadosamente con agua durante varios minutos. Quitar las lentes de contacto, si lleva y resulta fácil. Seguir aclarando. P332+P313 En caso de irritación cutánea: Consultar a un médico. P301+P312 EN CASO DE INGESTIÓN: llamar a un CENTRO DE TOXICOLOGÍA o médico SI se siente indispuesto. P301+P330+P331 EN CASO DE INGESTIÓN: Limpie la boca. NO provoque el vómito. 5. MEDIDAS PARA COMBATIR INCENDIOS Pto. inflamabilidad: >275°F [COC] Límite explosivo inferior (LEL): NA Límite explosivo superior (UEL): NA Temperatura de autoignición: NA Inflamabilidad: No se espera ninguna. Medio extinguidor: Dióxido de carbono, productos químicos en polvo, espuma. Instrucciones para combatir el fuego: Use un aparato autónomo para respirar e indumentaria de protección. Por contener aceite, el agua no resultará eficaz para combatir incendios.Puede usarse agua para enfriar los recipientes cerrados y evitar una posible explosión si éstos estuvieran expuestos a calor extremo. 6. MEDIDAS EN CASO DE DERRAME ACCIDENTAL Ventile el área. Coloque una barrera física y contenga el derrame en el propio sitio de origen. Limpie el derrame con agua en abundancia y vierta todo por el drenaje. Obedezca todos losreglamentos federales, estatales y locales relativos a la disposición final de residuos. 7. MANIPULACIÓN Y ALMACENAMIENTO P402 Almacenar en un lugar seco. P405 Almacenar bajo llave. 8. CONTROL DE EXPOSICIÓN/PROTECCIÓN PERSONAL Controles de ingeniería: Proveer suficiente ventilación mecánica para mantener la exposición por debajo del límite de concentración máxima (Threshold Limit Value, TLV). Equipo de protección personal: Equipo de protección personal: Equipo de protección personal: Respiratorio: Cuando suelde en recintos pequeños o cuando la ventilación local no mantenga la exposición por debajo del TLV, utilice una mascarilla que proteja contra las emanaciones o un respirador con suministro de oxígeno. Respiratorio: Si el límite de exposición en el lugar de trabajo es excedido, se aconseja el uso de un respirador de aire ante la ausencia de control ambiental. Ojos: Use gafas protectoras o gafas con protección lateral sin perforaciones aprobadas. Piel: Si el contacto fuera prolongado o repetido, use guantes resistentes a productos químicos. Otros: Una estación de lavaojos de emergencia o una fuente de agua potable limpia debe estar disponible en caso de contacto accidental con los ojos. 9. PROPIEDADES FÍSICAS Y QUÍMICAS Aspecto: Naranja Olor: Leve Estado de agregación: Líquido Concentrarse pH: NA Solubilidad en agua: 100% Diluido pH: NA Contenido de VOC: NA Peso específico: 1.147 Punto de congelación/fusión: NA / NA Page 438 of 878 Page 438 of 878 Page 438 of 878 Page 438 of 878 ---PAGE BREAK--- 10. ESTABILIDAD Y REACTIVIDAD Estabilidad: Estable Polimerización peligrosa: No ocurrirá. Condiciones a evitar: Oxidantes fuertes, ácidos, metales activos, aluminio, zinc, estaño y sus aleaciones. Incompatibilidad: Disolventes, productos cáusticos, ácidos u oxidantes Productos de descomposición peligrosos: Dióxido de carbono, monóxido de carbono, óxidos de nitrógeno. 11. INFORMACIÓN TOXICOLÓGICA Este producto no contiene ningún componente en 0.1% o más del que se señale como un carcinógeno humano. Componentes peligrosos Número CAS LD50 LC50 glicol etileno 107-21-1 8.57 g/kg (oral rat) > 10000 mg/l/96 hr (flathead minnow) 12. INFORMACIÓN ECOLÓGICA No vertir en fuentes de agua naturales. Avise a las autoridades si el producto se cuela en el alcantarillado, en corrientes de agua o en grandes terrenos. 13. SUGERENCIAS PARA SU DISPOSICIÓN FINAL P501 Elimine el recipiente en conformidad con todas las regulaciones federales, estatales y locales relacionadas con la eliminación de residuos. 14. INFORMACIÓN SOBRE TRANSPORTE DATOS DE EMBARQUE SEGÚN EL DOT (Ministerio de Transporte de los EE.UU.): No se ha regulado. TDG CANADIENSE: Producto no regulado. No se ha regulado. Para los envíos internacionales de Air: NA Para los envíos internacionales de Vessel: NA 15. INFORMACIÓN SOBRE REGLAMENTOS TSCA: Todos los químicos de este producto están catalogados o están exentos de ser catalogados en el inventario químico de la Ley de Control de Sustancias Tóxicas(Toxic Substances Control Act, TSCA). CEPA: Todos los químicos de este producto están catalogados o están exentos de ser catalogados en el DSL/NDSL canadiense. Propuesta 65: Este producto Peut trazas de las sustancias químicas que, tras se sabe que el estado de California debido a un cáncer, defectos de nacimiento y otros daños reproductivos: D & C Rojo No. 19 81-88-9 1 75-07-0 ppm, Acetaldehyde <8 ppm1, 4 dioxano 123-91-1 <0,20 ppm SARA 313: Este producto contiene las siguientes sustancias tóxicas sujetas a los requisitos de presentación de informes de la sección 313 de la Ley de Planificación deEmergencias y Derecho a Saber de la Comunidad de 1986 (sección 372 del Título 40 del Código de Reglamentos Federales):Éteres de glicol < 0.50% CLASIFICACIÓN HMIS: SALUD = 2 INFLAMABILIDAD = 0 REACTIVIDAD = 0 EQUIPO DE PROTECCIÓN PERSONAL= B CLASIFICACIÓN WHMIS: Clase D, División 2B 16. OTRA INFORMACIÓN NA = No disponible o No se aplica NE = No se ha establecido Antes de utilizar este producto, lea y obedezca todas las instrucciones y precauciones. Este producto fue formulado para utilizarse únicamente en el ámbito industrial e institucional. NO ES PARA REVENTA NI PARA USO EN EL ÁMBITO HOGAREÑO. MANTENGA FUERA DEL ALCANCE DE LOS NIÑOS. Si bien se considera que los datos contenidos en esta planilla son correctos y las opiniones expresadas son las de calificados expertos, los datos no deberán considerarse como garantía ni como declaración por las que la compañía asume responsabilidad legal alguna. Estos datos se brindan sólo para evaluación, investigación y verificación por parte del cliente. El usuario es quien deberá determinar si cualquier uso que se dé a estos datos e información está de acuerdo con las leyes y reglamentos federales, estatales y locales aplicables. INFORMACIÓN DE SEGURIDAD Y SALUD: (216) 861-7114 Preparado Encendido: 08/11/2015 Reemplaza: 09/01/2012 Page 439 of 878 Page 439 of 878 Page 439 of 878 Page 439 of 878 ---PAGE BREAK--- LIQUID WRENCH SUPER LUBRICANT Page 1 of 4 OSU COLLEGE OF BIOLOGICAL SCIENCES MSDS FILE ~ RADIATOR SPECIALTY L2-4 LIQUID WRENCH SUPER LUBRICANT PETROLEUM SOLVENTS, RUST INHIBITOR MATERIAL SAFETY DATA SHEET FSC: 9150 NUN: 00FO14159 Manufacturer's CAGE: 77628 Part No. Indicator: A Part Number/Trade Name: L2-4 LIQUID WRENCH SUPER LUBRICANT 4,-34 L2-- L2- General Information Item Name: PETROLEUM SOLVENTS, RUST INHIBITOR Company's Name:.RADIATOR SPECIALTY COMPANY Company'sStreet:1400W.INDEPENDENCEBLVD Company's City: CHARLOTTE Company's State: NC Company's Zip Code: 28208 Company's Emerg Ph (704) 377-6555 Company's Info Ph (704) 377-6555 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 Date MSDS Prepared: 01SEP85 Safety Data Review Date: 12FEB91 Preparer's Company: RADIATOR SPECIALTY COMPANY Preparer's St Or P. O. Box: 1400 W. INDEPENDENCEBLVD Preparer's City: CHARLOTTE Preparer's State: NC Preparer's Zip Code: 28208 MSDS Serial Number: Ingredients/Identity Information Proprietary: NO Ingredient: ALIPHATIC PETROLEUM DISTILLATE Ingredient Sequence Number: 01 Percent: >70% NIOSH (RTECS) Number: 1004498AP CAS Number: 64742-38-7 ACGIH TLV: 300 PPM Proprietary: NO Ingredient: NAPHTHENIC PETROLEUM OIL, NAPHTHENIC OIL Ingredient Sequence Number: 02 Percent: http://www.biosci.ohio-state.edu/~jsmith/MSDS/LIQUID%20WRENCH%20SUPER%20LUl... 7/26/02 Page 440 of 878 Page 440 of 878 Page 440 of 878 Page 440 of 878 ---PAGE BREAK--- , LIQUID WRENCH SUPER LUBRICANT Page 2 of 4 ~ NIOSH (RTECS) Number: 1000661NO CAS Number: 64741-53-3 ACGIH TLV: 5 MG/CUM Proprietary: NO Ingredient: 2-BUTOXYETHANOL Ingredient Sequence Number: 03 Percent: 1-5% NIOSH (RTECS) Number: KJ8575000 CAS Number: 111-76-2 OSHA PEL: S, 50 PPM ACGIH TLV: S, 25 PPM; 9293 Other Recommended Limit: 25 PPM (SKIN) Proprietary: NO Ingredient: ALKYL AMINE DERIVATIVE Ingredient Sequence Number: 04 Percent: 0.5-5% NIOSH (RTECS) Number: 1004556AA Physical/Chemical Characteristics Appearance And Odor: DARK LIQUID W/PETROLEUM ODOR. Boiling Point: >300F Specific Gravity: 0.8 Solubility In Water: INSOLUBLE Percent Volatiles By Volume: >80% pH: >7 Fire and Explosion Hazard Data Flash Point: >1OOF Extinguishing Media: FOAM, CO2, DRY CHEMICAL Special Fire Fighting Proc: WEAR SELF-CONTAINEDBREATHING APPARATUS & FULL PROTECTIVE CLOTHING. Reactivity Data Stability: YES Cond To Avoid (Stability): HIGH TEMPERATURES, IGNITION SOURCES Materials To Avoid: ACIDS, OXIDIZING AGENTS Hazardous Decomp Products: CO2, CO, SMOKE & NITROGEN OXIDES Hazardous Poly Occur: NO http://www.biosci.ohio-state.edul~jsmith/MSDS/LIQUID%20WRENCH%20SUPER%20LU1.. 7/26/02 Page 441 of 878 Page 441 of 878 Page 441 of 878 Page 441 of 878 ---PAGE BREAK--- LIQUID WRENCH SUPER LUBRICANT Page 3 of 4 Health Hazard Data ~ RouteOfEntry- Inhalation:YES RouteOfEntry- Skin:YES RouteOf Entry- Ingestion:YES Health Haz Acute And Chronic: EYE: IRRITANT. SKIN: IRRITANT/MAY BE ABSORBED. INGESTION: HARMFUL. INHALATION: HEADACHE, DIZZINESS, NAUSEA. Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Explanation Carcinogenicity: NONE OfOverexp: EYE: IRRITANT. SKIN: IRRITANT/ABSORBED. INHALATION: HEADACHE, DIZZINESS, NAUSEA. INGESTION: HARMFUL. Emergency/First Aid Proc: EYE: FLUSH W/WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. IF IRRITATED, USE EMOLLIENT CREAM. INHALATION: MOVE TO FRESH AIR. INGESION: DON'T INDUCE VOMITING. CONSULT PHYSICIAN IN ALL CASES. Precautions for Safe Handling and Use Steps IfMatl Released/Spill: WIPE UP W/RAGES. OBSERVING HEALTH HAZARDS DESCRIBED ABOVE, CONFINE SPILL & TRANSFER TO WASTE DURM. Waste Disposal Method: DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. Precautions-Handling/Storing: STORE AWAY FROM IGNITION SOURCES & OXIDIZING AGENTS. KEEP AWAY FROM CHILDREN. WEAR CONTACT LENSES IS INADVISABLE. Control Measures Respiratory Protection: IF TLV IS EXCEEDED, USE NIOSH APPROVED RESPIRATOR. Ventilation: USE MECHANICAL W/ADEQUATE VENTILATION Protective Gloves: OIL-RESISTANT Eye Protection: GOGGLES Transportation Data Disposal Data LabelData http://www.biosci.ohio-state.edu/~jsmith/MSDS/LIQUID%20WRENCH%20SUPER%20LUJ... 7/26/02 Page 442 of 878 Page 442 of 878 Page 442 of 878 Page 442 of 878 ---PAGE BREAK--- LIQUID WRENCH SUPER LUBRICANT Page4of4 Label Required: YES Label Status: G Common Name: L2-4 LIQUID WRENCH SUPER LUBRICANT 4,-34 Special Hazard Precautions: EYE: IRRITANT. SKIN: IRRITANTIMAYBE ABSORBED. INGESTION: HARMFUL. INHALATION: HEADACHE, DIZZINESS, NAUSEA. EYE: IRRITANT. SKIN: IRRITANT/ ABSORBED. INHALATION: HEADACHE, DIZZINESS, NAUSEA. INGESTION: HARMFUL. Label Name: RADIATOR SPECIALTY COMPANY Label Street: 1400 W. INDEPENDENCE BLVD Label City: CHARLOTTE Label State: NC Label Zip Code: 28208 Label Emergency Number: (704) 377-6555 L2- URL for this msds http://hazard.com. If you wish to change, add to, or delete information in this archive please sent updates to [EMAIL REDACTED]. http://www.biosci.ohio-state.edu/~jsmith/MSDS/LIQUID%20WRENCH%20SUPER%20LUl... 7/26/02 Page 443 of 878 Page 443 of 878 Page 443 of 878 Page 443 of 878 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 10-Mar-2014 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 58570 Product name Lock- Lube Recommended Use Lubricant Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Eyes. Skin. Inhalation. Ingestion. Potential health effects Eyes Prolonged or repeated exposure may cause . Slight irritation. Skin Prolonged skin contact may cause skin irritation and/or dermatitis. Inhalation Headaches. Dizziness. Nausea. Decreased blood pressure. Changes in heart rate. Cyanosis. Extreme overexposure may cause. Lung damage. Central nervous system damage. Kidney damage. Ingestion Harmful or fatal if swallowed. Can burn mouth, throat, and stomach. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Stoddard solvent 8052-41-3 60-100 Petroleum distillates, hydrotreated heavy naphthenic 64742-52-5 10-30 Dripless Base Compound Mixture 3-7 4. FIRST AID MEASURES Eye contact Flush with plenty of water for at least 15 minutes. Seek medical attention if irritation persists. Skin contact Wash off immediately with soap and plenty of water. If skin irritation persists, call a physician. Ingestion Seek medical attention immediately. Do Not induce vomiting. Give victim a glass of water or milk. Call a physician or Poison Control Center immediately. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Immediate medical attention is required. 5. FIRE FIGHTING MEASURES Flash point °C 37 Flash point °F 100 Method Tag Closed Cup Autoignition temperature °C No data available Autoignition temperature °F Flammability Limits in Air) Upper 6% Lower 0.7% Suitable extinguishing media Foam. Water fog. Alcohol foam. Carbon dioxide (CO2). Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Special Fire-Fighting Procedures Firefighters should wear NIOSH/MSHA approved (or equivalent) self- contained pressure-demand breathing apparatus and full protective clothing. Fire and Explosion Hazards Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Empty containers contain residue and/or vapors. Do not weld, cut, pressurize, braze, solder, drill, grind, or expose such containers to heat, sparks, flame, static electricity, or other sources of ignition. They may explode and cause injury or death. Page 1 / 3 Emergency Overview Irritant. Vapors may cause flash fire or explosion. Page 444 of 878 Page 444 of 878 Page 444 of 878 Page 444 of 878 ---PAGE BREAK--- Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Soak up with inert absorbent material. Place in suitable container for disposal as hazardous waste. 7. HANDLING AND STORAGE Handling Thoroughly wash hands and exposed skin after handling. Storage Keep closed in a dry and cool place. Keep away from open flames, hot surfaces and sources of ignition. Do not freeze. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Stoddard solvent 500 ppm 2900 mg/m3 - 100 ppm - Petroleum distillates, hydrotreated heavy naphthenic - - - - Dripless Base Compound - - - - Ventilation and Environmental Controls Provide local exhaust ventilation. Hygiene measures Wash hands before eating or using the washroom. Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes and clothing. Respiratory protection Use NIOSH approved respirator if TLV limit is exceeded. Hand Protection Chemical resistant gloves. Eye protection ANSI approved safety glasses or splash goggles with face shield are recommended. Skin and body protection Lightweight protective clothing. Other Protective Equipment Wear appropriate clothing to prevent skin contact. Rubber boots. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Liquid Color Black Odor Solvent Odor Threshold No information available pH No data available Specific Gravity No data available Vapor pressure 1-5 Vapor density > 1 (Air=1) Evaporation Rate < 1 (ether = 1) Water solubility Negligible VOC Content 5.74 Partition Coefficient (n-octanol/water) No data available Boiling point/range °C 155-197 Boiling point/range °F No data available Melting point/range °C 0 Melting point/range °F 32 Flash point °C 37 Flash point °F 100 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Avoid sources of ignition. Do not use near welding arcs. Avoid open flames. Incompatability Oxidizers. Strong acids. Alkalies. Amines. Hazardous Decomposition Products Carbon oxides. Nitrogen oxides (NOx). Chlorine. Chloride. phosgene. Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Stoddard solvent 8052-41-3 - - - Petroleum distillates, hydrotreated heavy naphthenic 64742-52-5 28710 mg/kg - - Dripless Base Compound Mixture - - - Synergistic Products None known Page 2 / 3 Product code 58570 Product name Lock- Lube Page 445 of 878 Page 445 of 878 Page 445 of 878 Page 445 of 878 ---PAGE BREAK--- Potential health effects Sensitization None known Chronic toxicity None known Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects See Section 2 Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Stoddard solvent Not Listed Not Listed Not Listed Not Listed Not Listed Petroleum distillates, hydrotreated heavy naphthenic Not Listed Not Listed Not Listed Not Listed Not Listed Dripless Base Compound Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT Consumer commodity, ORM-D. TDG 15. REGULATORY INFORMATION State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Stoddard solvent Listed Listed Not Listed Petroleum distillates, hydrotreated heavy naphthenic Not Listed Not Listed Not Listed Dripless Base Compound Not Listed Not Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA Stoddard solvent X X - X Petroleum distillates, hydrotreated heavy naphthenic X X - X Dripless Base Compound - - - - CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. OTHER INFORMATION Health - 0 Flammability - 2 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 3 / 3 Water Flea Data Daphnia magna EC50>1000 mg/L (48 h) Product name Lock- Lube Petroleum distillates, hydrotreated heavy naphthenic Product code 58570 Page 446 of 878 Page 446 of 878 Page 446 of 878 Page 446 of 878 ---PAGE BREAK--- Safety Data Sheet Revision Number: 003.0 Issue date: 08/20/2014 IDH number: 234923 Product name: Loctite(R) Contact Adhesive Page 1 of 7 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Loctite(R) Contact Adhesive IDH number: 234923 Product type: Adhesive Item number: 30537 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-[PHONE REDACTED] (toll free) or 1-[PHONE REDACTED] TRANSPORT EMERGENCY Phone: CHEMTREC 1-[PHONE REDACTED] (toll free) or 1-[PHONE REDACTED] Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW DANGER: HIGHLY FLAMMABLE LIQUID AND VAPOR. MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. HAZARD CLASS HAZARD CATEGORY FLAMMABLE LIQUID 2 SKIN IRRITATION 2 EYE IRRITATION 2A SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3 ASPIRATION HAZARD 1 PICTOGRAM(S) Precautionary Statements Prevention: Keep away from heat, sparks, open flames, hot surfaces - no smoking. Keep container closed. No release into water. Use explosion-proof equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing vapors, mist, or spray. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves, eye protection, and face protection. Response: IF SWALLOWED: Immediately call a physician or poison control center. If on skin (or hair): Take off immediately all contaminated clothing. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. Call a poison control center or physician if you feel unwell. Do NOT induce vomiting. If skin irritation occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. In case of fire: Use foam, dry chemical or carbon dioxide to extinguish. Storage: Store in a well-ventilated place. Keep container closed. Store in a well-ventilated place. Keep cool. Store locked up. Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Page 447 of 878 Page 447 of 878 Page 447 of 878 Page 447 of 878 ---PAGE BREAK--- IDH number: 234923 Product name: Loctite(R) Contact Adhesive Page 2 of 7 Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Methyl ethyl ketone 78-93-3 10 - 30 Acetone 67-64-1 10 - 30 Toluene 108-88-3 10 - 30 n-Hexane 110-54-3 10 - 30 Magnesium oxide 1309-48-4 1 - 5 Silica, amorphous, fumed, 112945-52-5 1 - 5 Resin Proprietary 1 - 5 C.I. Solvent Yellow 3 97-56-3 0.1 - 1 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. Wash clothing before reuse. Get medical attention. Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Aspiration may cause pulmonary edema and pneumonitis. Never give anything by mouth to an unconscious person. Get medical attention. See Section 11. 5. FIRE FIGHTING MEASURES Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide. Special firefighting procedures: Never use welding or cutting torch on or near drum (even empty) because product (even just residue) can ignite explosively. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. In case of fire, keep containers cool with water spray. Unusual fire or explosion hazards: Hydrocarbon solvents are basically non-conductors of electricity and can become electrostatically charged during mixing, filtering or pumping at high flow rates. If this charge reaches a significantly high level, sparks can form that may ignite vapors of flammable liquids. Sudden release of hot organic chemical vapors or mist from process equipment operated at elevated temperatures and pressures or sudden ingress of air into vacuum equipment may result in ignitions without the presence of obvious ignition sources. Page 448 of 878 Page 448 of 878 Page 448 of 878 Page 448 of 878 ---PAGE BREAK--- IDH number: 234923 Product name: Loctite(R) Contact Adhesive Page 3 of 7 Hazardous combustion products: Oxides of carbon. Irritating organic vapours. Hydrocarbons. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Do not allow product to enter sewer or waterways. Clean-up methods: Remove all sources of ignition. Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean- up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Scrape up as much material as possible. Store in a partly filled, closed container until disposal. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up. 7. HANDLING AND STORAGE Handling: Use only with adequate ventilation. Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Do not taste or swallow. DO NOT heat or spray. Refer to Section 8. Storage: For safe storage, store between 0 °C (32°F) and 49 °C (120.2 Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container closed until ready for use. Ground and bond metal containers for liquid transfer to avoid static sparks. For information on product shelf life contact Henkel Customer Service at (800) 243-4874. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Methyl ethyl ketone 200 ppm TWA 300 ppm STEL 200 ppm (590 mg/m3) PEL None None Acetone 750 ppm STEL 500 ppm TWA 1,000 ppm (2,400 mg/m3) PEL None None Toluene 20 ppm TWA 200 ppm TWA 300 ppm Ceiling 500 ppm MAX. CONC 10 minutes None None n-Hexane 50 ppm TWA (SKIN) 500 ppm (1,800 mg/m3) PEL None None Magnesium oxide 10 mg/m3 TWA Inhalable fraction. 15 mg/m3 PEL Total particulate. None None Silica, amorphous, fumed, 10 mg/m3 TWA Inhalable dust. 3 mg/m3 TWA Respirable fraction. 20 TWA 0.8 mg/m3 TWA None None Resin None None None None C.I. Solvent Yellow 3 None None None None Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Respiratory protection: Use a NIOSH approved supplied air respirator if the potential to exceed established exposure limits exists. If this material is handled at elevated temperatures or under mist forming conditions, without engineering controls, a NIOSH approved respirator must be used. Page 449 of 878 Page 449 of 878 Page 449 of 878 Page 449 of 878 ---PAGE BREAK--- IDH number: 234923 Product name: Loctite(R) Contact Adhesive Page 4 of 7 Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available. Skin protection: Because a variety of protective gloves exist, consult manufacturer to determine the proper type for a specific operation. Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Yellow Odor: Solvent Odor threshold: Not available. pH: Not applicable Vapor pressure: 181 mm hg (20 °C (68°F)) Boiling point/range: 56 °C (132.8 Melting point/ range: Not available. Specific gravity: 0.91 Vapor density: 2.68 Flash point: -24 °C (-11.2 Tagliabue closed cup Flammable/Explosive limits - lower: 1 % Flammable/Explosive limits - upper: 12.6 % Autoignition temperature: Not available. Evaporation rate: 14.4 (Butyl acetate = 1) Solubility in water: Negligible Partition coefficient (n-octanol/water): Not available. VOC content: 47.4 430 g/l Viscosity: Not available. Decomposition temperature: Not available. 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions of storage and use. Hazardous reactions: Will not occur. Hazardous decomposition products: Oxides of carbon. Irritating organic vapours. Hydrocarbons. Incompatible materials: Oxidizing agents. Acids. Reactivity: Not available. Conditions to avoid: Elevated temperatures. Heat, flames, sparks and other sources of ignition. Store away from incompatible materials. 11. TOXICOLOGICAL INFORMATION Product toxicity data: This material has been shown to cause harm to the fetus in laboratory animal studies. Harm to the fetus occurs only at exposure levels that harm the pregnant animals. The relevance to these findings to humans is uncertain. Relevant routes of exposure: Skin, Lungs, Ingestion, Eye contact Page 450 of 878 Page 450 of 878 Page 450 of 878 Page 450 of 878 ---PAGE BREAK--- IDH number: 234923 Product name: Loctite(R) Contact Adhesive Page 5 of 7 Potential Health Inhalation: are typically seen at air concentrations exceeding the recommended exposure limits. Harmful if inhaled. Skin contact: Causes skin irritation. Skin absorption is possible, but harmful effects are not expected from this route of exposure under normal conditions of handling and use. Pre-existing skin disorders may be aggravated by exposure to this material. Repeated or prolonged contact can result in drying of skin. may include redness, burning, drying, cracking and skin burns. Eye contact: Causes serious eye irritation. Burning sensation. Redness. Excess tearing. Stinging. Blurred vision. Ingestion: Principal hazard of ingestion is aspiration into the lungs and subsequent pneumonitis. can include sore throat, abdominal pain, nausea, vomiting and diarrhea. Harmful or fatal if swallowed. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Methyl ethyl ketone Oral LD50 (RAT) = 2,300 - 3,500 mg/kg Oral LD50 (RAT) = 4,500 - 6,800 mg/kg Dermal LD50 (RABBIT) = > 8,000 mg/kg Inhalation LC50 (RAT, 4 h) = 11700 ppm Irritant, Central nervous system Acetone Oral LD50 (RABBIT) = 5,340 mg/kg Oral LD50 (RAT) = 5,800 mg/kg Oral LD50 (RAT) = 9,800 mg/kg Dermal LD50 (RABBIT) = 20,000 mg/kg Inhalation LC50 (RAT, 8 h) = 50.1 mg/l Inhalation LC50 (RAT, 4 h) = 76 mg/l Blood, Central nervous system, Irritant, Reproductive Toluene Oral LD50 (RAT) = 2.6 g/kg Oral LD50 (RAT) = 5,000 mg/kg Dermal LD50 (RABBIT) = 12,124 mg/kg Inhalation LC50 (RAT, 1 h) = 26700 ppm Inhalation LC50 (RAT, 2 h) = 12200 ppm Inhalation LC50 (RAT, 4 h) = 8000 ppm Behavioral, Cardiac, Central nervous system, Developmental, Ear, Irritant n-Hexane Oral LD50 (RAT) = 24 mg/kg Oral LD50 (RAT) = 43.5 mg/kg Oral LD50 (RAT) = 28,710 mg/kg Dermal LD50 (RABBIT) = > 2,000 mg/kg Inhalation LC50 (RAT, 4 h) = 73860 ppm Developmental, Irritant, Lung, Nervous System, Reproductive Magnesium oxide None Blood, Central nervous system, Immune system, Irritant Silica, amorphous, fumed, None Nuisance dust Resin None Irritant, Allergen C.I. Solvent Yellow 3 None Mutagen, Some evidence of carcinogenicity Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Methyl ethyl ketone No No No Acetone No No No Toluene No No No n-Hexane No No No Magnesium oxide No No No Silica, amorphous, fumed, No No No Resin No No No C.I. Solvent Yellow 3 Reasonably Anticipated to be a Human Carcinogen. Group 2B No 12. ECOLOGICAL INFORMATION Ecological information: Not available. Page 451 of 878 Page 451 of 878 Page 451 of 878 Page 451 of 878 ---PAGE BREAK--- IDH number: 234923 Product name: Loctite(R) Contact Adhesive Page 6 of 7 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. Hazardous waste number: D001: Ignitable. D035: Methyl Ethyl Ketone. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Adhesives Hazard class or division: 3 Identification number: UN 1133 Packing group: II DOT Hazardous Substance(s): Toluene, Methyl ethyl ketone International Air Transportation (ICAO/IATA) Proper shipping name: Adhesives Hazard class or division: 3 Identification number: UN 1133 Packing group: II Exceptions: (Not more than 500 ml), May Qualify as Consumer Commodity, ID8000 Water Transportation (IMO/IMDG) Proper shipping name: ADHESIVES Hazard class or division: 3 Identification number: UN 1133 Packing group: II 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 Export Notification: None above reporting de minimis CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Fire, Immediate Health, Delayed Health CERCLA/SARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Methyl ethyl ketone (CAS# 78-93-3). Toluene (CAS# 108-88-3). n-Hexane (CAS# 110-54-3). C.I. Solvent Yellow 3 (CAS# 97-56-3). CERCLA Reportable quantity: Methyl ethyl ketone (CAS# 78-93-3) 5,000 lbs. (2,270 kg) Acetone (CAS# 67-64-1) 5,000 lbs. (2,270 kg) Toluene (CAS# 108-88-3) 1,000 lbs. (454 kg) n-Hexane (CAS# 110-54-3) 5,000 lbs. (2,270 kg) California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. Page 452 of 878 Page 452 of 878 Page 452 of 878 Page 452 of 878 ---PAGE BREAK--- IDH number: 234923 Product name: Loctite(R) Contact Adhesive Page 7 of 7 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Prepared by: Catherine Bimler, Regulatory Affairs Specialist Issue date: 08/20/2014 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 453 of 878 Page 453 of 878 Page 453 of 878 Page 453 of 878 ---PAGE BREAK--- Material Safety Data Sheet Revision Number: 000.0 Issue date: 06/18/2010 IDH number: 1410944 1432215 Product name: Loctite PL375 Heavy Duty Construction Adhesive Page 1 of 6 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Loctite PL375 Heavy Duty Construction Adhesive IDH number: 1410944 1432215 Product type: Assembly adhesive, solvent Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 Telephone: [PHONE REDACTED] Transportation Emergency Telephone: [PHONE REDACTED] 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW HMIS: Physical state: pasty HEALTH: 2 Color: beige FLAMMABILITY: 3 Odor: mineral-oil-like PHYSICAL HAZARD: 0 Personal Protection: See MSDS Section 8 DANGER: EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPOR MAY CAUSE FLASH FIRE. HARMFUL IF SWALLOWED OR INHALED. MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. Relevant routes of exposure: Inhalation, Skin contact Potential Health Effects Inhalation: Irritates the nose, throat and respiratory system. Exposure to high doses may cause central nervous system depression. Such doses may also cause adverse effects in the liver, kidneys, and lungs. Overexposure to hexane may result in peripheral and central nervous system damage, which may be permanent. Abrasion of cured material such as by sanding or grinding could release respirable particles of silica quartz, a cancer hazard by inhalation. Normal use of this product causes no such release. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Skin contact: Prolonged and/or repeated skin contact with this product may cause irritation/dermatitis. Eye contact: Contact with eyes can cause eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. Ingestion: Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea. Existing conditions aggravated by exposure: Eye, skin and respiratory disorders. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). See Section 11 for additional toxicological information. Page 454 of 878 Page 454 of 878 Page 454 of 878 Page 454 of 878 ---PAGE BREAK--- IDH number: 1410944 1432215 Product name: Loctite PL375 Heavy Duty Construction Adhesive Page 2 of 6 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components CAS NUMBER % Distillates, petroleum, steam-cracked, polymd. 68131-77-1 10 - 30 Naphtha (petroleum), solvent-refined light 64741-84-0 10 - 30 Toluene 108-88-3 5 - 10 n-Hexane 110-54-3 5 - 10 Ethanol 64-17-5 1 - 5 Distillates (petroleum), hydrotreated heavy naphthenic 64742-52-5 1 - 5 Titanium dioxide 13463-67-7 0.1 - 1 Quartz (SiO2) 14808-60-7 0.1 - 1 4. FIRST AID MEASURES Inhalation: If inhaled, immediately remove the affected person to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. If develop and persist, get medical attention. Skin contact: Rinse with running water and soap. Apply replenishing cream. Change all contaminated clothing. Eye contact: In case of contact with the eyes, rinse immediately with plenty of water for 15 minutes, and seek immediate medical attention. Ingestion: Do not induce vomiting, seek medical advice immediately. 5. FIRE FIGHTING MEASURES Flash point: 0 °F (-17.78 no method Autoignition temperature: Not available Flammable/Explosive limits - lower: 1 % Flammable/Explosive limits - upper: 15 % Extinguishing media: Foam, dry chemical or carbon dioxide. In case of fire, keep containers cool with water spray. Special firefighting procedures: Wear a self-contained breathing apparatus with a full face piece operated in pressure-demand or other positive pressure mode. Wear full protective clothing. Unusual fire or explosion hazards: Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors are heavier than air and may travel along floor to an ignition source. Hazardous combustion products: Carbon dioxide. Carbon monoxide. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Eliminate all sources of ignition or flammables that may come into contact with a spill of this material. Ventilate area. Clean-up methods: Absorb spill with inert material. Shovel material into appropriate container for disposal. Wear suitable protective clothing, gloves and eye/face protection. Page 455 of 878 Page 455 of 878 Page 455 of 878 Page 455 of 878 ---PAGE BREAK--- IDH number: 1410944 1432215 Product name: Loctite PL375 Heavy Duty Construction Adhesive Page 3 of 6 7. HANDLING AND STORAGE Handling: Do not pressurize, cut, heat or weld containers. Empty product containers may contain product residue. Do not reuse empty containers. Use only in well-ventilated areas. Keep out of the reach of children. Storage: Keep away from heat, spark and flame. Store in a cool, dry, well-ventilated area. Keep containers closed when not in use. For information on product shelf life, please review labels on container or check the Technical Data Sheet. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER Distillates, petroleum, steam-cracked, polymd. None None None None Naphtha (petroleum), solvent-refined light None None None None Toluene 20 ppm TWA 200 ppm TWA 300 ppm Ceiling1 500 ppm MAX. CONC 10 minutes None None n-Hexane (SKIN) 50 ppm TWA 500 ppm (1,800 mg/m3) TWA None None Ethanol 1,000 ppm STEL 1,000 ppm (1,900 mg/m3) TWA None None Distillates (petroleum), hydrotreated heavy naphthenic 5 mg/m3 TWA mist 10 mg/m3 STEL mist 5 mg/m3 TWA mist None None Titanium dioxide 10 mg/m3 TWA 15 mg/m3 TWA Total dust. None None Quartz (SiO2) 0.025 mg/m3 TWA Respirable fraction. 2.4 TWA Respirable. 0.1 mg/m3 TWA Respirable. 0.3 mg/m3 TWA Total dust. None None Engineering controls: Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination below occupational exposure limits. Respiratory protection: Use a NIOSH approved air-purifying respirator if the potential to exceed established exposure limits exists. When workplace hazards warrant the use of a respirator, appropriate respirators must be used, and a program that follows 29 CFR 1910.134 must be followed. Eye/face protection: Safety goggles or safety glasses with side shields. Skin protection: Suitable protective clothing 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: pasty Color: beige Odor: mineral-oil-like Odor threshold: Not available pH: not applicable Vapor pressure: 155 mm hg (20 °C (68°F)) Boiling point/range: 65 - 110 °C (149°F - 230°F) no method Melting point/ range: Not available Specific gravity: 1.1210 Vapor density: Heavier than air Flash point: 0 °F (-17.78 no method Page 456 of 878 Page 456 of 878 Page 456 of 878 Page 456 of 878 ---PAGE BREAK--- IDH number: 1410944 1432215 Product name: Loctite PL375 Heavy Duty Construction Adhesive Page 4 of 6 Flammable/Explosive limits - lower: 1 % Flammable/Explosive limits - upper: 15 % Autoignition temperature: Not available Evaporation rate: 4.8 (Butyl acetate = 1) Solubility in water: partially soluble Partition coefficient (n-octanol/water): Not available VOC content: 33 380 g/l (calculated) Viscosity: 200,000 - 400,000 mPa.s 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions of storage and use. Hazardous reactions: Will not occur. Hazardous decomposition products: Carbon dioxide, carbon monoxide and irritating and/or toxic gases and particulate may be generated by thermal decomposition or combustion. Incompatible materials: Strong oxidizing agents. Conditions to avoid: Heat, flames, sparks and other sources of ignition. 11. TOXICOLOGICAL INFORMATION Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Distillates, petroleum, steam-cracked, polymd. No No No Naphtha (petroleum), solvent-refined light No No No Toluene No No No n-Hexane No No No Ethanol No No No Distillates (petroleum), hydrotreated heavy naphthenic No No No Titanium dioxide No Group 2B No Quartz (SiO2) Known carcinogen. Group 1 No Hazardous components Health Effects/Target Organs Distillates, petroleum, steam-cracked, polymd. Irritant Naphtha (petroleum), solvent-refined light Irritant Toluene Behavioral, Cardiac, Central nervous system, Developmental, Ear, Irritant n-Hexane Developmental, Irritant, Lung, Nervous System, Reproductive Ethanol Irritant, Central nervous system Distillates (petroleum), hydrotreated heavy naphthenic Irritant Titanium dioxide Irritant, Respiratory, Some evidence of carcinogenicity Quartz (SiO2) Immune system, Lung, Some evidence of carcinogenicity 12. ECOLOGICAL INFORMATION Ecological information: Not available Page 457 of 878 Page 457 of 878 Page 457 of 878 Page 457 of 878 ---PAGE BREAK--- IDH number: 1410944 1432215 Product name: Loctite PL375 Heavy Duty Construction Adhesive Page 5 of 6 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations. Hazardous waste number: It is the responsibility of the user to determine if an item is hazardous as defined in the Resource Conservation and Recovery Act (RCRA) at the time of disposal. Product uses, transformations, mixtures, processes, etc., may render the resulting material hazardous, under the criteria of ignitability, corrosivity, reactivity and toxicity characteristics of the Toxicity Characteristics Leaching Procedure (TCLP) 40 CFR 261.20-24. 14. TRANSPORT INFORMATION The shipping classifications in this sections are for non-bulk packaging only (unless otherwise specified). Shipping classification may be different for bulk packaging. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Adhesives Hazard class or division: 3 Identification number: UN 1133 Packing group: II DOT Reportable quantity: Toluene Exceptions: Consumer Commodity ORM-D (Not more than 5 L) International Air Transportation (ICAO/IATA) Proper shipping name: Adhesives Hazard class or division: 3 Identification number: UN 1133 Packing group: II Exceptions: Consumer Commodity, ID 8000, Class 9, (Not more than 5 L) Water Transportation (IMO/IMDG) Proper shipping name: ADHESIVES Hazard class or division: 3 Identification number: UN 1133 Packing group: II Exceptions: Limited quantity (Not more than 5 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12(b) Export Notification: None above reporting de minimus CERCLA/SARA Section 302 EHS: None above reporting de minimus CERCLA/SARA Section 311/312: Immediate Health, Delayed Health, Fire CERCLA/SARA 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Toluene (CAS# 108-88-3). n-Hexane (CAS# 110-54-3). California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. Page 458 of 878 Page 458 of 878 Page 458 of 878 Page 458 of 878 ---PAGE BREAK--- IDH number: 1410944 1432215 Product name: Loctite PL375 Heavy Duty Construction Adhesive Page 6 of 6 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet format. Prepared by: Mary Ellen Roddy, Sr. Regulatory Affairs Specialist DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 459 of 878 Page 459 of 878 Page 459 of 878 Page 459 of 878 ---PAGE BREAK--- Safety Data Sheet Revision Number: 001.1 Issue date: 12/15/2014 IDH number: 1509357 Product name: Loctite Polyseamseal Tub & Tile Ultra Sealant Page 1 of 5 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Loctite Polyseamseal Tub & Tile Ultra Sealant IDH number: 1509357 Product type: Sealant Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 Telephone: +1 (800) 624-7767 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671- 4608 (toll free) or 1-[PHONE REDACTED] TRANSPORT EMERGENCY Phone: CHEMTREC 1-[PHONE REDACTED] (toll free) or 1-[PHONE REDACTED] 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW NOT CLASSIFIED. READ ENTIRE SAFETY DATA SHEET. HAZARD CLASS HAZARD CATEGORY None None PICTOGRAM(S) None Precautionary Statements Prevention: Not prescribed Response: Not prescribed Storage: Not prescribed Disposal: Not prescribed Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Titanium dioxide 13463-67-7 1 - 5 Talc 14807-96-6 0.1 - 1 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Move to fresh air, consult doctor if complaint persists. Skin contact: Wash with soap and water. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Page 460 of 878 Page 460 of 878 Page 460 of 878 Page 460 of 878 ---PAGE BREAK--- IDH number: 1509357 Product name: Loctite Polyseamseal Tub & Tile Ultra Sealant Page 2 of 5 Ingestion: Rinse the mouth. Drink 1-2 glasses of water. See Section 11. 5. FIRE FIGHTING MEASURES Extinguishing media: Use dry chemical, water spray or carbon dioxide. Special firefighting procedures: None Unusual fire or explosion hazards: Closed containers may explode when exposed to extreme heat. Hazardous combustion products: Oxides of carbon. Oxides of nitrogen. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Absorb spill with inert material. Shovel material into appropriate container for disposal. Wear appropriate protective equipment and clothing during clean-up. Clean-up methods: Follow all local, state, federal and provincial regulations for disposal. 7. HANDLING AND STORAGE Handling: Keep container closed. Avoid skin and eye contact. Keep out of the reach of children. Keep from freezing. Avoid extreme temperatures. Storage: Keep closed in a cool, dry area. For information on product shelf life, please review labels on container or check the Technical Data Sheet. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Titanium dioxide 10 mg/m3 TWA 15 mg/m3 PEL Total dust. None None Talc 2 mg/m3 TWA Respirable fraction. 20 TWA 2.4 TWA Respirable. 0.1 mg/m3 TWA Respirable. 0.3 mg/m3 TWA Total dust. None 50 ppm Engineering controls: No particular measures required. Respiratory protection: No personal respiratory protective equipment normally required. Eye/face protection: Wear protective glasses. Skin protection: Wear suitable protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: pasty Color: white Odor: characteristic Odor threshold: Not available. Page 461 of 878 Page 461 of 878 Page 461 of 878 Page 461 of 878 ---PAGE BREAK--- IDH number: 1509357 Product name: Loctite Polyseamseal Tub & Tile Ultra Sealant Page 3 of 5 pH: 7.5 - 8.8 Vapor pressure: 15 mbar (20 °C (68°F)) Boiling point/range: 100.0 °C (212°F) Melting point/ range: Not available. Specific gravity: 1.2570 Vapor density: Heavier than air, (Air = 1) Flash point: > 93.33 °C 199.99 Pensky Martens closed cup Flammable/Explosive limits - lower: Not available. Flammable/Explosive limits - upper: Not available. Autoignition temperature: Not available. Evaporation rate: Slower than butyl acetate., (Butyl acetate = 1) Solubility in water: Soluble Partition coefficient (n-octanol/water): Not available. VOC content: < 1.00 < 4.00 g/l (Calculated, as packaged) Viscosity: 400,000 - 560,000 cp Decomposition temperature: Not available. 10. STABILITY AND REACTIVITY Stability: Not available. Hazardous reactions: Will not occur. Hazardous decomposition products: Oxides of carbon. Oxides of nitrogen. Incompatible materials: None known Reactivity: Not available. Conditions to avoid: Freezing conditions. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin Potential Health Inhalation: Not a hazard under normal conditions of use. Skin contact: May cause irritation. Eye contact: May cause irritation. Ingestion: Ingestion of this product may cause nausea, vomiting and diarrhea. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Titanium dioxide None Irritant, Respiratory, Some evidence of carcinogenicity Talc None Irritant, Lung, Some evidence of carcinogenicity Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Titanium dioxide No Group 2B No Talc No Group 2B No 12. ECOLOGICAL INFORMATION Ecological information: Not available. Page 462 of 878 Page 462 of 878 Page 462 of 878 Page 462 of 878 ---PAGE BREAK--- IDH number: 1509357 Product name: Loctite Polyseamseal Tub & Tile Ultra Sealant Page 4 of 5 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. Hazardous waste number: It is the responsibility of the user to determine if an item is hazardous as defined in the Resource Conservation and Recovery Act (RCRA) at the time of disposal. Product uses, transformations, mixtures, processes, etc., may render the resulting material hazardous, under the criteria of ignitability, corrosivity, reactivity and toxicity characteristics of the Toxicity Characteristics Leaching Procedure (TCLP) 40 CFR 261.20-24. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None International Air Transportation (ICAO/IATA) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None Water Transportation (IMO/IMDG) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 Export Notification: None above reporting de minimis CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Delayed Health CERCLA/SARA Section 313: None above reporting de minimis California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Page 463 of 878 Page 463 of 878 Page 463 of 878 Page 463 of 878 ---PAGE BREAK--- IDH number: 1509357 Product name: Loctite Polyseamseal Tub & Tile Ultra Sealant Page 5 of 5 Prepared by: Mary Ellen Roddy, Sr. Regulatory Affairs Specialist Issue date: 12/15/2014 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 464 of 878 Page 464 of 878 Page 464 of 878 Page 464 of 878 ---PAGE BREAK--- Page 465 of 878 Page 465 of 878 Page 465 of 878 Page 465 of 878 ---PAGE BREAK--- Page 466 of 878 Page 466 of 878 Page 466 of 878 Page 466 of 878 ---PAGE BREAK--- Page 467 of 878 Page 467 of 878 Page 467 of 878 Page 467 of 878 ---PAGE BREAK--- Page 468 of 878 Page 468 of 878 Page 468 of 878 Page 468 of 878 ---PAGE BREAK--- Page 469 of 878 Page 469 of 878 Page 469 of 878 Page 469 of 878 ---PAGE BREAK--- Page 470 of 878 Page 470 of 878 Page 470 of 878 Page 470 of 878 ---PAGE BREAK--- Page 471 of 878 Page 471 of 878 Page 471 of 878 Page 471 of 878 ---PAGE BREAK--- Page 472 of 878 Page 472 of 878 Page 472 of 878 Page 472 of 878 ---PAGE BREAK--- Page 473 of 878 Page 473 of 878 Page 473 of 878 Page 473 of 878 ---PAGE BREAK--- Page 474 of 878 Page 474 of 878 Page 474 of 878 Page 474 of 878 ---PAGE BREAK--- 1 Page: Mildew Stain Remover Plus Blocker MATERIAL SAFETY DATA SHEET 1 0 0 03/14/2013 01/29/2013 Revision: Supercedes Revision: 03/15/2013 Printed: X * 1 0 0 Instability Special Hazard Health Flammability HEALTH FLAMMABILITY PHYSICAL PPE 1. Product and Company Identification BSNX109.4 Product Code: Mildew Stain Remover Plus Blocker Product Name: Manufacturer Information W. M. Barr Company Name: 2105 Channel Avenue Memphis, TN 38113 (901)775-0100 Phone Number: 3E 24 Hour Emergency Contact (800)451-8346 Emergency Contact: W.M. Barr Customer Service (800)398-3892 Information: www.wmbarr.com Web site address: W.M. Barr EHS Dept (901)775-0100 Preparer Name: Synonyms FG523, FG533, FG301 03/14/2013 Revision Date: 2. Hazards Identification Emergency Overview Caution: Harmful if swallowed. May cause eye irritation. Potential Health Effects (Acute and Chronic) This product has not been tested as a whole to determine health effects. The health effects listed below are associated with the individual ingredients. EYES: Contact may cause severe irritation. May cause discomfort, pain, blinking, tear production, redness, swelling, and chemical burns of the eye. SKIN: May cause skin irritation. Prolonged skin contact may cause mild to moderate local redness and swelling. INHALATION: Vapor may cause headache, nausea, and dizziness. May cause irritation of the upper respiratory tract. INGESTION: May produce signs of intoxication characterized by incoordination, dizziness, drowsiness, headache, nausea, mental confusion, possibly slurred speech, and stupor, depending on the quantity of material ingested. May result in burns of the mouth and throat. CHRONIC OVEREXPOSURE EFFECTS: Diethylene Glycol Monobutyl Ether: In animals, effects have been reported on blood (hemolysis) and secondary effects on the kidney and liver. Humans appear to be resistant to this effect. EDTA and its sodium salts have been reported to cause birth defects in laboratory animals only at exaggerated doses that were toxic to the mother. These effects are likely associated with zinc deficiency due to chelation. TARGET ORGANS: skin, respiratory system, eyes Licensed to W.M. Barr and Company ANSI Z400.1-2004 Page 475 of 878 Page 475 of 878 Page 475 of 878 Page 475 of 878 ---PAGE BREAK--- 03/14/2013 Revision: 03/15/2013 Printed: 2 Page: Mildew Stain Remover Plus Blocker MATERIAL SAFETY DATA SHEET 01/29/2013 Supercedes Revision: Signs and Of Exposure No data available. Medical Conditions Generally Aggravated By Exposure No data available. OSHA Regulatory Status: This material is classified as hazardous under OSHA regulations. 3. Composition/Information on Ingredients Hazardous Components (Chemical Name) Ethylenediamine tetraacetic acid, tetrasodium salt 64-02-8 CAS # 1.0 -5.0 % Concentration 1. Alcohol ethoxylate (Alcohols, C9-11, Ethoxylated) 68439-46-3 1.0 -5.0 % 2. Diethylene glycol monobutyl ether {2-(2-Butoxyethoxy)ethanol glycol ether)} 112-34-5 1.0 -5.0 % 3. 4. First Aid Measures Emergency and First Aid Procedures Skin: Immediately begin washing the skin thoroughly with large amounts of water and mild soap, if available, while removing contaminated clothing. Seek medical attention if irritation persists. Eyes: Immediately begin to flush eyes with water, remove any contact lens. Continue to flush the eyes for at least 15 minutes, then seek immediate medical attention. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Ingestion: If swallowed, do NOT induce vomiting. Seek immediate medical attention. Call a physician, hospital emergency room, or poison control center immediately. Never give anything by mouth to an unconscious person. If spontaneous vomiting is about to occur, place victim's head below knees. If victim is drowsy or unconscious, place on the left side with head down. Note to Physician Treatment of overexposure should be directed at the control of and the clinical condition of the patient. 5. Fire Fighting Measures No data. Flash Pt: LEL: No data. UEL: No data. Explosive Limits: No data available. Autoignition Pt: Fire Fighting Instructions Self-contained respiratory protection should be provided for fire fighters fighting fires in buildings or confined areas. Storage containers exposed to fire should be kept cool with water spray to prevent pressure build-up. Stay away from heads of containers that have been exposed to intense heat or flame. Flammable Properties and Hazards Flashpoint: No flash to boiling. Hazardous Combustion Products Carbon monoxide, carbon dioxide Licensed to W.M. Barr and Company ANSI Z400.1-2004 Page 476 of 878 Page 476 of 878 Page 476 of 878 Page 476 of 878 ---PAGE BREAK--- 03/14/2013 Revision: 03/15/2013 Printed: 3 Page: Mildew Stain Remover Plus Blocker MATERIAL SAFETY DATA SHEET 01/29/2013 Supercedes Revision: Suitable Extinguishing Media Non-combustible liquid - use extinguishing media for underlying cause of fire. Unsuitable Extinguishing Media None known. 6. Accidental Release Measures Steps To Be Taken In Case Material Is Released Or Spilled For small spills: Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. For large spills: Wear appropriate PPE and keep all unecessary personnel out of the area. Stop spill at the source, dike ahead of the spill if possible, and contain the spill. Recover as much as possible and use absorbent material to collect the remaining liquid. Prevent runoff from entering drains, sewers, or bodies of water. Dispose of according to all applicable local, state, and federal regulations. 7. Handling and Storage Precautions To Be Taken in Handling Avoid contact with eyes, skin, and clothing. Do not reuse this container. Precautions To Be Taken in Storing Keep from freezing. Store in a cool dry place. 8. Exposure Controls/Personal Protection No data. No data. No data. Hazardous Components (Chemical Name) ACGIH TLV Ethylenediamine tetraacetic acid, tetrasodium salt 64-02-8 CAS # OSHA PEL Other Limits 1. No data. No data. No data. Alcohol ethoxylate (Alcohols, C9-11, Ethoxylated) 68439-46-3 2. No data. No data. No data. Diethylene glycol monobutyl ether {2-(2-Butoxyethoxy)ethanol glycol ether)} 112-34-5 3. Respiratory Equipment (Specify Type) When used as directed, respiratory equipment should not be needed. Wear NIOSH approved respiratory protective equipment when vapor or mists may exceed applicable concentration limits. Eye Protection Safety glasses should be worn during normal handling of this material. Where contact with the eyes or face is likely, a faceshield or chemical splash goggles should be worn to prevent eye contact. Protective Gloves Wear gloves with as much resistance to the chemical ingredients as possible. Glove materials such as nitrile rubber and latex will provide protection. Glove selection should be based on chemicals being used and conditions of use. Consult your glove supplier for additional information. Other Protective Clothing Various application methods can dictate use of additional protective safety equipment, such as impermeable aprons, etc., to minimize exposure. Engineering Controls (Ventilation etc.) Ventilation is normally not required when handling or using this product to keep exposure to airborne contaminants below the exposure limit. Work/Hygienic/Maintenance Practices Wash hands thoroughly after use and before eating, drinking, smoking, or using the restroom. Do not eat, drink, or smoke in the work area. Licensed to W.M. Barr and Company ANSI Z400.1-2004 Page 477 of 878 Page 477 of 878 Page 477 of 878 Page 477 of 878 ---PAGE BREAK--- 03/14/2013 Revision: 03/15/2013 Printed: 4 Page: Mildew Stain Remover Plus Blocker MATERIAL SAFETY DATA SHEET 01/29/2013 Supercedes Revision: Discard any clothing or other protective equipment that cannot be decontaminated. Facilities storing or handling this material should be equipped with an emergency eyewash and safety shower. 9. Physical and Chemical Properties [ ] Gas [ X ] Liquid [ ] Solid Physical States: No data. Melting Point: 210 F Boiling Point: No data. Autoignition Pt: No data. Flash Pt: 0.998 - 1.002 Specific Gravity (Water = 8.47 Density: < 0.1 MM HG at 68 F Vapor Pressure (vs. Air or mm Hg): No data. Vapor Density (vs. Air = No data. Evaporation Rate: complete Solubility in Water: N.D. Percent Volatile: 8 - 10 pH: Appearance and Odor Free and clear, colorless. 10. Stability and Reactivity Unstable [ ] Stable [ X ] Stability: Conditions To Avoid - Instability No data available. Incompatibility - Materials To Avoid Oxidizers, reactive metals, materials reactive with hydroxyl compounds, amines, strong acids Hazardous Decomposition Or Byproducts Carbon monoxide, carbon dioxide, ammonia, nitrogen oxides, aldehydes Will occur [ ] Will not occur [ X ] Possibility of Hazardous Reactions: Conditions To Avoid - Hazardous Reactions No data available. 11. Toxicological Information Toxicological Information CAS# 112-34-5: Acute toxicity, LD50, Oral, Rat, 5660. MG/KG. Result: Brain and Coverings: Other degenerative changes. Biochemical:Metabolism (intermediary): Other. - Dow Chemical Company Reports., Dow Chemical USA, Health and Environment Research, Toxicology Research Lab, Midland, MI 48640, Vol/p/yr: MSD-41, Standard Draize Test, Eyes, Species: Rabbit, 20.00 MG, Severe. Result: Behavioral: Anticonvulsant. - American Journal of Ophthalmology., Ophthalmic Pub. Co., 435 N. Michigan Ave., Suite 1415, Chicago, IL 60611, Vol/p/yr: 29,1363, 1946 Licensed to W.M. Barr and Company ANSI Z400.1-2004 Page 478 of 878 Page 478 of 878 Page 478 of 878 Page 478 of 878 ---PAGE BREAK--- 03/14/2013 Revision: 03/15/2013 Printed: 5 Page: Mildew Stain Remover Plus Blocker MATERIAL SAFETY DATA SHEET 01/29/2013 Supercedes Revision: Standard Draize Test, Eyes, Species: Rabbit, 20.00 MG, 24 H, Moderate. Result: Behavioral: Abuse. Endocrine: Differential effect of sex or castration on observed toxicity. - Prehled Prumyslove Toxikologie, Marhold, Organicke Latky, Prague Czechoslovakia, Vol/p/yr: -,635, 1986 Chronic Toxicological Effects No data available. n.a. n.a. n.a. Hazardous Components (Chemical Name) Ethylenediamine tetraacetic acid, tetrasodium salt 64-02-8 CAS # n.a. NTP IARC ACGIH OSHA 1. n.a. n.a. n.a. Alcohol ethoxylate (Alcohols, C9-11, Ethoxylated) 68439-46-3 n.a. 2. n.a. n.a. n.a. Diethylene glycol monobutyl ether {2-(2-Butoxyethoxy)ethanol glycol ether)} 112-34-5 n.a. 3. 12. Ecological Information General Ecological Information Not tested. Results of PBT and vPvB assessment CAS# 68439-46-3: LC50, Fathead Minnow (Pimephales promelas), 11000. UG/L, 96 H, Mortality, Water temperature: 22 C C. Result: Sex Effects. - Acute Toxicity and Structure-Activity Relationships of Nine Alcohol Ethoxylate Surfactants to Fathead Minnow and Daphnia magna, Wong, D.C.L., P.B. Dorn, and E.Y. Chai, 1997 LC50, Fathead Minnow (Pimephales promelas), embryo(s), 4.870 MG/L, 28 D, Mortality, Water temperature: 21 C - 25 C C, pH: 7.60, Hardness: 10.00 MG/L. Result: Age Effects. - Effects of a Homologous Series of Linear Alcohol Ethoxylate Surfactants on Fathead Minnow Early Life Stages, Lizotte, R.E.,Jr., D.C.L. Wong, P.B. Dorn, and J.H.,Jr. Rodgers, 1999 Effective concentration to % of test organisms, Fathead Minnow (Pimephales promelas), embryo(s), 10.27 MG/L, 16 - 19 D, Mortality, Water temperature: 21 C - 25 C C, pH: 7.60, Hardness: 10.00 MG/L. Result: Age Effects. - Effects of a Homologous Series of Linear Alcohol Ethoxylate Surfactants on Fathead Minnow Early Life Stages, Lizotte, R.E.,Jr., D.C.L. Wong, P.B. Dorn, and J.H.,Jr. Rodgers, 1999 CAS# 112-34-5: LC50, Water Flea (Daphnia magna), 2850. MG/L, 24 H, Intoxication,, Water temperature: 20 C - 22 C C, pH: 7.70, Hardness: 16.00 dH. Result: Sex Effects. - Results of the Damaging Effect of Water Pollutants on Daphnia magna (Befunde der Schadwirkung Wassergefahrdender Stoffe Gegen Daphnia magna), Bringmann, and R. Kuhn, 1977 Licensed to W.M. Barr and Company ANSI Z400.1-2004 Page 479 of 878 Page 479 of 878 Page 479 of 878 Page 479 of 878 ---PAGE BREAK--- 03/14/2013 Revision: 03/15/2013 Printed: 6 Page: Mildew Stain Remover Plus Blocker MATERIAL SAFETY DATA SHEET 01/29/2013 Supercedes Revision: 13. Disposal Considerations Waste Disposal Method Dispose in accordance with applicable local, state and federal regulations. 14. Transport Information LAND TRANSPORT (US DOT) Not regulated by D.O.T. DOT Proper Shipping Name Additional Transport Information For D.O.T. information, contact W.M. Barr Technical Services at 1-[PHONE REDACTED]. 15. Regulatory Information US EPA SARA Title III No No No Hazardous Components (Chemical Name) Ethylenediamine tetraacetic acid, tetrasodium salt 64-02-8 CAS # No Sec.302 (EHS) Sec.304 RQ Sec.313 (TRI) Sec.110 1. No No No Alcohol ethoxylate (Alcohols, C9-11, Ethoxylated) 68439-46-3 No 2. Yes-Cat. N230 No No Diethylene glycol monobutyl ether {2-(2-Butoxyethoxy)ethanol glycol ether)} 112-34-5 No 3. Other US EPA or State Lists Inventory No No Hazardous Components (Chemical Name) Ethylenediamine tetraacetic acid, tetrasodium salt 64-02-8 CAS # No CAA HAP,ODC CWA NPDES TSCA CA PROP.65 1. Inventory No No Alcohol ethoxylate (Alcohols, C9-11, Ethoxylated) 68439-46-3 No 2. Inventory, 4 Test No No Diethylene glycol monobutyl ether {2-(2-Butoxyethoxy)ethanol glycol ether)} 112-34-5 HAP 3. EPA Hazard Categories: This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated: Yes [ ] No Acute (immediate) Health Hazard Yes [ ] No Chronic (delayed) Health Hazard [ ] Yes No Fire Hazard [ ] Yes No Sudden Release of Pressure Hazard [ ] Yes No Reactive Hazard Regulatory Information Statement All components of this material are listed on the TSCA Inventory or are exempt. 16. Other Information Company Policy or Disclaimer The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, state and local laws and regulations. Licensed to W.M. Barr and Company ANSI Z400.1-2004 Page 480 of 878 Page 480 of 878 Page 480 of 878 Page 480 of 878 ---PAGE BREAK--- 803 M A T E R I A L S A F E T Y D A T A S H E E T Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 Date of Prep: 05/20/05 SECTION 1 SUNNYSIDE CORPORATION FOR INFORMATION: (847) 541-5700 225 CARPENTER AVENUE WHEELING, ILLINOIS 60090 (847) 541-5700 - SUNNYSIDE CORPORATION EMERGENCY TELEPHONE (800) 424-9300 - CHEM TREC Product Class: Petroleum Hydrocarbon Manufacturer's Code: 803 Trade Name: MINERAL SPIRITS NPCA HMIS: Health: 1 Fire: 2 Reactivity: 0 Product Appearance and Odor: Clear, water-white liquid; petroleum odor. SECTION 2 HAZARDOUS INGREDIENTS OCCUPATIONAL EXPOSURE LIMITS ACGIH ACGIH OSHA OSHA INGREDIENT CAS # PERCENT TLV TLV PEL PEL VAPOR PRESSURE (TWA) (STEL) (TWA) (STEL) Mineral Spirits 64742-88-7 100 PPM 100 PPM 2.0 MM Hg @ 20O C. (For Stoddard Solvent - CAS #8052- 41-3) SECTION 3 EMERGENCY AND FIRST AID PROCEDURES Eye Contact: Flush eyes with plenty of water for 15 minutes while holding eyelids open. Get medical attention. Skin Contact: Remove contaminated clothing/shoes. Flush skin with water. Follow by washing with soap and water. If irritation occurs, get medical attention. Do not reuse clothing until cleaned. Inhalation: Remove victim to fresh air and if breathing is difficult, oxygen should be provided by qualified personnel. Give artificial respiration if not breathing. Get medical attention. Ingestion: Do not induce vomiting. If vomiting occurs spontaneously, keep head below hips to prevent aspiration of liquid into the lungs. Get medical attention. SECTION 4 PHYSICAL DATA The following data represent approximate or typical values. They do not constitute product specifications. Boiling Range: 315-395O Vapor Density: Heavier than air Evaporation Rate: Slower than ether % Volatile By Volume: Approx. 100% Weight Per Gallon: 6.43 lbs. Solubility in Water: Negligible; less than 0.1% SECTION 5 FIRE AND EXPLOSION DATA Flammability Classification: Combustible Liquid - Class II. Flash Point: 102O(F) Tag. Closed cup Autoignition Temperature: 445OF Lower Explosive Limit: 0.7% Extinguishing Media: Carbon dioxide, foam, dry chemical, water spray. Do not use direct water stream; it will spread fire. Unusual Fire and Explosion Hazards: Do not store or mix with strong oxidants. Special Fire Fighting Procedures: Use air-supplied rescue equipment for enclosed areas. Cool exposed containers with water. Page 481 of 878 Page 481 of 878 Page 481 of 878 Page 481 of 878 3190K751,752,753,754 ---PAGE BREAK--- Trade Name: MINERAL SPIRITS Page 2 of 3 SECTION 6 HEALTH HAZARD DATA THRESHOLD LIMIT VALUE: See Section 2. EFFECTS OF OVEREXPOSURE Acute Eye Contact: May cause irritation, discomfort, redness and swelling of the eye. Skin Contact: Liquid is irritating to the skin. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis. Inhalation: Vapors may cause irritation to nose, throat and respiratory tract. Breathing of high vapor concentrations may result in headaches, dizziness and other signs of nervous system depression. These effects have been observed after misuse or abuse of this product. When used in a reasonable and foreseeable manner, no adverse effects are anticipated from exposure to this product. Ingestion: Ingestion may result in vomiting, aspiration (breathing) of vomitus into the lungs must be avoided as even small quantities may result in aspiration pneumonitis. Chronic: Repeated skin contact may aggravate an existing dermatitis (skin condition). Carcinogenicity: This product has not been identified as a carcinogen by NTP, IARC, or OSHA. Medical Conditions Aggravated by Exposure: Conditions aggravated by exposure may include skin disorders and respiratory (asthma-like) disorders. SECTION 7 REACTIVITY DATA Stability: Stable Conditions to Avoid: Heat, sparks and flame. Incompatibility (Materials to Avoid): Strong oxidizing agents like liquid chlorine or concentrated oxygen. Hazardous Decomposition Products: Thermal decomposition may yield carbon dioxide and carbon monoxide. Hazardous Polymerization: Will not occur. SECTION 8 SPILL OR LEAK PROCEDURES Steps to be taken in case material is spilled or released: Remove ignition sources, evacuate area, avoid breathing vapor or contact with liquid. Recover free liquid or stop leak if possible. Dike large spills and use absorbent material for small spills. Keep spilled material out of sewers, ditches and bodies of water. Waste disposal method: Incinerate under safe conditions; dispose of in accordance with local, state and federal regulations. SECTION 9 SAFE HANDLING AND USE INFORMATION Respiratory Protection: Appropriate vapor canister, self-contained breathing apparatus or supplied-air hose mask, if needed. Ventilation: Sufficient, in volume and pattern, to keep workroom concentration below current applicable OSHA safety and health requirements. See Section 2. Use explosion-proof equipment. No smoking. Protective Gloves: Rubber or neoprene. Eye Protection: Chemical safety goggles. Other Protective Equipment: Impervious clothing or boots, if needed. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Page 482 of 878 Page 482 of 878 Page 482 of 878 Page 482 of 878 ---PAGE BREAK--- Trade Name: MINERAL SPIRITS Page 3 of 3 SECTION 10 SPECIAL PRECAUTIONS Dept. of Labor Storage Category: Combustible Liquid - Class II Hygienic Practices: Keep away from heat, sparks and open flame. Keep containers closed when not in use. Avoid eye contact. Avoid prolonged or repeated contact with skin. Wash skin with soap and water after contact. Additional Precautions: Ground containers when transferring liquid to prevent static accumulation and discharge. Additional information regarding safe handling of products with static accumulation potential can be ordered by contacting the American Petroleum Institute (API) for API Recommended Practice 2003, entitled "Protection Against Ignitions Arising Out of Static, Lighting, and Stray Currents" (American Petroleum Institute, 1720 L Street Northwest, Washington, DC 20005), or the National Fire Protection Association (NFPA) for NFPA 77 entitled "Static Electricity" (National Fire Protection Association, 1 Batterymarch Park, P.O. Box 9101, Quincy, MA 02269-9101). Empty Container Warning: "Empty" containers retain residue (liquid and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind or expose such containers to heat, flame, sparks or other sources of ignition; they may explode and cause injury or death. Do not attempt to clean since residue is difficult to remove. "Empty" drums should be completely drained, properly bunged and returned to supplier or disposed of in an environmentally safe manner and in accordance with governmental regulations. SECTION 11 ADDITIONAL INFORMATION This product contains the following toxic chemical(s) which are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: APPROXIMATE TOXIC CHEMICAL CAS # % BY WEIGHT NONE NONE NONE SARA Title III Hazard Categories: Fire Hazard, immediate (Acute) and Delayed (Chronic) Health Hazard Common Names: Solvent Naphtha (Petroleum), Aliphatic Hydrocarbon, Petroleum Distillate California Proposition 65: This product may contain trace amounts of Benzene, Ethyl Benzene and Toluene- which are known to the State of California to cause cancer, birth defects or other reproductive harm, and may be subject to the requirements of California Proposition 65. TRANSPORTATION U.S. D.O.T. Proper Shipping Name: Petroleum Distillates, N.O.S. U.S. D.O.T. Hazard Class & Packing Group: Combustible Liquid, III U.S. D.O.T. Identification Number: UN 1268 R fer to 49 CFR for possible exceptions and exemptions. e Page 483 of 878 Page 483 of 878 Page 483 of 878 Page 483 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 490A 04 00 Section 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DATE OF PREPARATION HMIS CODES Health 2 490A 29-SEP-07 Flammability 2 Reactivity 0 PRODUCT NAME MINWAX® POLYSHADES® Interior Stain & Polyurethane Gloss Finish, Natural Cherry MANUFACTURER'S NAME MINWAX Company 10 Mountainview Road Upper Saddle River, NJ 07458 TELEPHONE NUMBERS and WEBSITES Product Information (800) 523-9299 Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency for Chemical Emergency ONLY (spill, leak, (800) 424-9300 fire, exposure, or accident) Section 2 COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE 6 64742-88-7 Med. Aliphatic Hydrocarbon Solvent ACGIH TLV Not Available 2 mm OSHA PEL Not Available 14 64742-88-7 Mineral Spirits ACGIH TLV 100 ppm 2 mm OSHA PEL 100 ppm 6 64741-65-7 Mineral Spirits (Odorless) ACGIH TLV 100 ppm 1 mm OSHA PEL 100 ppm Section 3 HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver and urinary systems. Continued on page 2 Page 484 of 878 Page 484 of 878 Page 484 of 878 Page 484 of 878 ---PAGE BREAK--- 490A page 2 SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Section 4 FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. Section 5 FIRE FIGHTING MEASURES FLASH POINT LEL UEL 121 F PMCC 1.0 7.0 FLAMMABILITY CLASSIFICATION Combustible, Flash above 99 and below 200 F EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Continued on page 3 Page 485 of 878 Page 485 of 878 Page 485 of 878 Page 485 of 878 ---PAGE BREAK--- 490A page 3 Section 7 HANDLING AND STORAGE STORAGE CATEGORY DOL Storage Class II PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Contents are COMBUSTIBLE. Keep away from heat and open flame. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. To minimize the possibility of spontaneous combustion: control the accumulation of overspray; soak wiping rags and waste immediately after use in a water-filled, closed metal container; air dry filters outside, far from any combustible material and separated by bricks or other non-combustible spacers; dispose of all contaminated materials and waste properly. Consult OSHA 29 CFR 1910.107(b)(5) and NFPA 33, Chapter 8 (8-9) for the proper procedures. Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. Continued on page 4 Page 486 of 878 Page 486 of 878 Page 486 of 878 Page 486 of 878 ---PAGE BREAK--- 490A page 4 OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Section 9 PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 7.87 lb/gal 943 g/l SPECIFIC GRAVITY 0.95 BOILING POINT 300 - 425 F 148 - 218 C MELTING POINT Not Available VOLATILE VOLUME 33 % EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 2.17 lb/gal 260 g/l Less Water and Federally Exempt Solvents 2.17 lb/gal 260 g/l Emitted VOC Section 10 STABILITY AND REACTIVITY STABILITY Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Section 11 TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. TOXICOLOGY DATA CAS No. Ingredient Name 64742-88-7 Med. Aliphatic Hydrocarbon Solvent LC50 RAT 4HR Not Available LD50 RAT Not Available 64742-88-7 Mineral Spirits LC50 RAT 4HR Not Available LD50 RAT Not Available 64741-65-7 Mineral Spirits (Odorless) LC50 RAT 4HR Not Available LD50 RAT Not Available Continued on page 5 Page 487 of 878 Page 487 of 878 Page 487 of 878 Page 487 of 878 ---PAGE BREAK--- 490A page 5 Section 12 ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Section 13 DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Section 14 TRANSPORT INFORMATION US Ground (DOT) May be Classed as a Combustible Liquid for U.S. Ground. UN1263, PAINT, 3, PG III, (ERG#128) Bulk Containers may be Shipped as: UN1263, PAINT, COMBUSTIBLE LIQUID, PG III, (ERG#128) Canada (TDG) May be Classed as a Combustible Liquid for Canadian Ground. UN1263, PAINT, CLASS 3, PG III, (ERG#128) IMO UN1263, PAINT, CLASS 3, PG III, (49 C EmS F-E, S-E Section 15 REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Continued on page 6 Page 488 of 878 Page 488 of 878 Page 488 of 878 Page 488 of 878 ---PAGE BREAK--- 490A page 6 Section 16 OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 489 of 878 Page 489 of 878 Page 489 of 878 Page 489 of 878 ---PAGE BREAK--- Page 490 of 878 Page 490 of 878 Page 490 of 878 Page 490 of 878 ---PAGE BREAK--- Page 491 of 878 Page 491 of 878 Page 491 of 878 Page 491 of 878 ---PAGE BREAK--- Page 492 of 878 Page 492 of 878 Page 492 of 878 Page 492 of 878 ---PAGE BREAK--- Page 493 of 878 Page 493 of 878 Page 493 of 878 Page 493 of 878 ---PAGE BREAK--- Page 494 of 878 Page 494 of 878 Page 494 of 878 Page 494 of 878 ---PAGE BREAK--- Page 495 of 878 Page 495 of 878 Page 495 of 878 Page 495 of 878 ---PAGE BREAK--- Page 496 of 878 Page 496 of 878 Page 496 of 878 Page 496 of 878 ---PAGE BREAK--- Page 497 of 878 Page 497 of 878 Page 497 of 878 Page 497 of 878 ---PAGE BREAK--- Page 498 of 878 Page 498 of 878 Page 498 of 878 Page 498 of 878 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 1 / 12 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Material name : Misty(R) Surface Disinfectant EPA ID Number: 33176-5-10807 Material number : 000000000001001788 Manufacturer or supplier's details Company : Amrep, Inc. Address : 990 Industrial Park Drive Marietta, GA 30062 Telephone : [PHONE REDACTED] Emergency telephone numbers For SDS Information : Compliance Services 1-[PHONE REDACTED] For a Medical Emergency : [PHONE REDACTED] Toll Free - All Calls Recorded For a Transportation Emergency : CHEMTREC: [PHONE REDACTED] - All Calls Recorded. In the District of Columbia [PHONE REDACTED] SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Appearance Aerosol containing a liquefied gas Colour clear, colourless Odour odourized GHS Classification Flammable aerosols : Category 2 Gases under pressure : Liquefied gas Eye irritation : Category 2A GHS Label element Hazard pictograms : Signal word : Warning Hazard statements : H223 Flammable aerosol. H280 Contains gas under pressure; may explode if heated. H319 Causes serious eye irritation. Precautionary statements : Prevention: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P211 Do not spray on an open flame or other ignition source. P251 Pressurized container: Do not pierce or burn, even after Page 499 of 878 Page 499 of 878 Page 499 of 878 Page 499 of 878 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 2 / 12 use. P264 Wash skin thoroughly after handling. P280 Wear eye protection/ face protection. Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. Storage: P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 122 Disposal: P501 Dispose of contents/container in accordance with local regulation. Potential Health Effects Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical Name CAS-No. Concentration ethanol 64-17-5 30 - < 50 butane 106-97-8 10 - < 20 propane 74-98-6 1 - < 5 propan-2-ol 67-63-0 1 - < 5 sodium nitrite 7632-00-0 0.1 - < 1 SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : If unconscious place in recovery position and seek medical advice. Page 500 of 878 Page 500 of 878 Page 500 of 878 Page 500 of 878 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 3 / 12 If persist, call a physician. In case of skin contact : If on clothes, remove clothes. If persist, call a physician. Call a physician if irritation persists. Wash off immediately with plenty of water for at least 15 minutes. In case of eye contact : If in eyes, rinse with water for 15 minutes. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. If persist, call a physician. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Water spray jet Unsuitable extinguishing media : High volume water jet Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : Carbon dioxide (CO2) Carbon monoxide Smoke Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. For safety reasons in case of fire, cans should be stored separately in closed containments. Use a water spray to cool fully closed containers. Special protective equipment for firefighters : Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and : Use personal protective equipment. Ensure adequate ventilation. Page 501 of 878 Page 501 of 878 Page 501 of 878 Page 501 of 878 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 4 / 12 emergency procedures Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Sweep up or vacuum up spillage and collect in suitable container for disposal. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). SECTION 7. HANDLING AND STORAGE Advice on safe handling : Do not breathe vapours or spray mist. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Open drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations. Always replace cap after use. Conditions for safe storage : BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. No smoking. Keep in a dry, cool and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. Materials to avoid : Oxidizing agents SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis ethanol 64-17-5 TWA 1,000 ppm ACGIH TWA 1,000 ppm NIOSH REL Page 502 of 878 Page 502 of 878 Page 502 of 878 Page 502 of 878 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 5 / 12 1,900 mg/m3 TWA 1,000 ppm 1,900 mg/m3 OSHA Z-1 TWA 1,000 ppm 1,900 mg/m3 OSHA P0 butane 106-97-8 TWA 800 ppm 1,900 mg/m3 NIOSH REL TWA 800 ppm 1,900 mg/m3 OSHA P0 propane 74-98-6 TWA 1,000 ppm ACGIH TWA 1,000 ppm 1,800 mg/m3 NIOSH REL TWA 1,000 ppm 1,800 mg/m3 OSHA Z-1 TWA 1,000 ppm 1,800 mg/m3 OSHA P0 propan-2-ol 67-63-0 TWA 200 ppm ACGIH STEL 400 ppm ACGIH TWA 400 ppm 980 mg/m3 NIOSH REL ST 500 ppm 1,225 mg/m3 NIOSH REL TWA 400 ppm 980 mg/m3 OSHA Z-1 TWA 400 ppm 980 mg/m3 OSHA P0 STEL 500 ppm 1,225 mg/m3 OSHA P0 Biological occupational exposure limits Component CAS-No. Control parameters Biological specimen Sampling time Permissible concentration Basis PROPAN-2-OL 67-63-0 Acetone Urine End of shift at end of workwee k 40 mg/l ACGIH BEI Personal protective equipment Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Ensure that eyewash stations and safety showers are close to the workstation location. fitting safety goggles Skin and body protection : impervious clothing Choose body protection according to the amount and Page 503 of 878 Page 503 of 878 Page 503 of 878 Page 503 of 878 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 6 / 12 concentration of the dangerous substance at the work place. Hygiene measures : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Aerosol containing a liquefied gas Colour : clear, colourless Odour : odourized Odour Threshold : no data available pH : no data available Melting point/freezing point : no data available Boiling point : not applicable Flash point : not applicable Evaporation rate : no data available Flammability (solid, gas) : Flammable aerosol. Upper explosion limit : no data available Lower explosion limit : no data available Vapour pressure : not applicable Density : no data available Solubility(ies) Water solubility : soluble Partition coefficient: n- octanol/water : no data available Auto-ignition temperature : not determined Thermal decomposition : no data available Viscosity Viscosity, kinematic : no data available Heat of combustion : 24.21 kJ/g SECTION 10. STABILITY AND REACTIVITY Reactivity : Stable Chemical stability : Stable under normal conditions. Page 504 of 878 Page 504 of 878 Page 504 of 878 Page 504 of 878 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 7 / 12 Possibility of hazardous reactions : No decomposition if stored and applied as directed. Vapours may form explosive mixture with air. Conditions to avoid : Heat, flames and sparks. Extremes of temperature and direct sunlight. Incompatible materials : Oxidizing agents Ammonium salts Reducing agents Hazardous decomposition products : Carbon oxides SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Product: Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Components: ethanol: Acute oral toxicity : LD50 Oral rat: 7,060 mg/kg Acute inhalation toxicity : LC50 rat: 124.7 mg/l Exposure time: 4 h butane: Acute inhalation toxicity : LC50 mouse: 1,237 mg/l Exposure time: 2 h LC50 rat: 1,355 mg/l propane: Acute inhalation toxicity : LC50 mouse: 1,237 mg/l Exposure time: 2 h LC50 rat: 658 mg/l Exposure time: 4 h LC50 rat: 1,355 mg/l propan-2-ol: Acute oral toxicity : LD50 Oral rat: 4,396 mg/kg Method: Calculation method Skin corrosion/irritation Product: Page 505 of 878 Page 505 of 878 Page 505 of 878 Page 505 of 878 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 8 / 12 Remarks: May cause skin irritation in susceptible persons. Serious eye damage/eye irritation Product: Remarks: Severe eye irritation Respiratory or skin sensitisation no data available Germ cell mutagenicity no data available Carcinogenicity no data available Reproductive toxicity no data available ethanol: butane: propane: propan-2-ol: sodium nitrite: STOT - single exposure no data available STOT - repeated exposure no data available Aspiration toxicity no data available Further information Product: Remarks: no data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity no data available Persistence and degradability no data available Bioaccumulative potential Product: Partition coefficient: n- : Remarks: no data available Page 506 of 878 Page 506 of 878 Page 506 of 878 Page 506 of 878 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 9 / 12 octanol/water Components: butane : Partition coefficient: n- octanol/water : Pow: 2.89 Mobility in soil no data available Other adverse effects no data available Product: Regulation 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + Additional ecological information : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal., Harmful to aquatic life. SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of in accordance with local regulations. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION Transportation Regulation: 49 CFR (USA): ORM-D, CONSUMER COMMODITY Transportation Regulation: IMDG (Vessel): UN1950, AEROSOLS, 2.1, - Limited quantity Transportation Regulation: IATA (Cargo Air): UN1950, Aerosols, flammable, 2.1, - Limited quantity Page 507 of 878 Page 507 of 878 Page 507 of 878 Page 507 of 878 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 10 / 12 Transportation Regulation: IATA (Passenger Air): UN1950, Aerosols, flammable, 2.1, - Limited quantity Transportation Regulation: TDG (Canada): UN1950, AEROSOLS, 2.1, - Limited quantity SECTION 15. REGULATORY INFORMATION This product is regulated under the United States Federal Insecticide, Fungicide and Rodenticide Act (FIFRA). Pesticide Labeling Information Required Under U.S. FIFRA Regulations This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION Harmful if inhaled. Causes moderate eye irritation. EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) sodium nitrite 7632-00-0 100 * Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) ammonia, 7664-41-7 100 * Calculated RQ exceeds reasonably attainable upper limit. SARA 311/312 Hazards : Fire Hazard Sudden Release of Pressure Hazard Acute Health Hazard SARA 302 : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 WARNING! This product contains a chemical known to the State of California to cause cancer. biphenyl-2-ol 90-43-7 The components of this product are reported in the following inventories: Page 508 of 878 Page 508 of 878 Page 508 of 878 Page 508 of 878 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 11 / 12 TSCA On TSCA Inventory DSL This product contains one or several components that are not on the Canadian DSL nor NDSL. AICS Not in compliance with the inventory NZIoC Not in compliance with the inventory PICCS Not in compliance with the inventory IECSC Not in compliance with the inventory Inventory Acronym and Validity Area Legend: AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: OSHA GHS Label Information: Hazard pictograms : Signal w ord : Warning: Hazard statements : Flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Precautionary statements : Prevention: Keep aw ay from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash skin thoroughly after handling. Wear eye protection/ face protection. Response: IF IN EYES: Rinse cautiously w ith water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. Storage: Protect from sunlight. Do not expose to temperatures exceeding 50 122 Disposal: Dispose of contents/container in accordance with local regulation. Version: 1.1 Revision Date: 05/31/2015 Flammability Health Instability 3 3 0 Special hazard. FLAMMABILITY PHYSICAL HAZARD HEALTH 3 2 3 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 509 of 878 Page 509 of 878 Page 509 of 878 Page 509 of 878 ---PAGE BREAK--- SAFETY DATA SHEET Misty(R) Surface Disinfectant Version 1.1 Revision Date 05/31/2015 Print Date 06/09/2015 12 / 12 Print Date: 06/09/2015 We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. Users should make their own investigations to determine the suitability and applicability of the information for their particular purposes. This SDS has been prepared by the Compliance Services organization supporting this manufacturer, supplier or distributor. Zep Inc. markets products under well recognized and established brand names such as Zep®, Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®, Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands. Page 510 of 878 Page 510 of 878 Page 510 of 878 Page 510 of 878 ---PAGE BREAK--- Product Name: MOBIL RARUS 427 Revision Date: 14 Jun 2012 Page 1 of 9 MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: MOBIL RARUS 427 Product Description: Base Oil and Additives Product Code: 606202-00, 970996 Intended Use: Compressor oil COMPANY IDENTIFICATION Supplier: EXXON MOBIL CORPORATION 3225 GALLOWS RD. FAIRFAX, VA. 22037 USA 24 Hour Health Emergency [PHONE REDACTED] Transportation Emergency Phone [PHONE REDACTED] ExxonMobil Transportation No. [PHONE REDACTED] Product Technical Information [PHONE REDACTED], [PHONE REDACTED] MSDS Internet Address http://www.exxon.com, http://www.mobil.com SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 3 HAZARDS IDENTIFICATION This material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). POTENTIAL HEALTH EFFECTS Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use Page 511 of 878 Page 511 of 878 Page 511 of 878 Page 511 of 878 ---PAGE BREAK--- Product Name: MOBIL RARUS 427 Revision Date: 14 Jun 2012 Page 2 of 9 adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulfur oxides, Incomplete combustion products, Oxides of carbon FLAMMABILITY PROPERTIES Flash Point [Method]: >210°C (410°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802. Page 512 of 878 Page 512 of 878 Page 512 of 878 Page 512 of 878 ---PAGE BREAK--- Product Name: MOBIL RARUS 427 Revision Date: 14 Jun 2012 Page 3 of 9 PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended. SPILL MANAGEMENT Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE HANDLING This material is not intended for use in air compressors for breathing applications. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present during switch-loading operations). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. STORAGE The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store in open or unlabelled containers. Keep away from incompatible materials. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Page 513 of 878 Page 513 of 878 Page 513 of 878 Page 513 of 878 ---PAGE BREAK--- Product Name: MOBIL RARUS 427 Revision Date: 14 Jun 2012 Page 4 of 9 Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols can occur the following are recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction), 5 mg/m³ - OSHA PEL. NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. Page 514 of 878 Page 514 of 878 Page 514 of 878 Page 514 of 878 ---PAGE BREAK--- Product Name: MOBIL RARUS 427 Revision Date: 14 Jun 2012 Page 5 of 9 ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Physical State: Liquid Color: Amber Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 0.879 Flash Point [Method]: >210°C (410°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) Vapor Density (Air = > 2 at 101 kPa Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C Evaporation Rate (n-butyl acetate = N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 100 cSt (100 mm2/sec) at 40 °C Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -9°C (16°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Page 515 of 878 Page 515 of 878 Page 515 of 878 Page 515 of 878 ---PAGE BREAK--- Product Name: MOBIL RARUS 427 Revision Date: 14 Jun 2012 Page 6 of 9 ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components. Ingestion Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on assessment of the components. Eye Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components. CHRONIC/OTHER EFFECTS Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. Additional information is available by request. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Not expected to be harmful to aquatic organisms. MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable Page 516 of 878 Page 516 of 878 Page 516 of 878 Page 516 of 878 ---PAGE BREAK--- Product Name: MOBIL RARUS 427 Revision Date: 14 Jun 2012 Page 7 of 9 BIOACCUMULATION POTENTIAL Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. Protect the environment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents, brake fluids or coolants. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (DOT): Not Regulated for Land Transport LAND (TDG): Not Regulated for Land Transport SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code AIR (IATA): Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not Page 517 of 878 Page 517 of 878 Page 517 of 878 Page 517 of 878 ---PAGE BREAK--- Product Name: MOBIL RARUS 427 Revision Date: 14 Jun 2012 Page 8 of 9 classified as hazardous in accordance with OSHA 29 CFR 1910.1200. Complies with the following national/regional chemical inventory requirements:: AICS, DSL, IECSC, KECI, TSCA Special Cases: Inventory Status ENCS Restrictions Apply **EPCRA SECTION 302**: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK 5 = TSCA 4 10 = CA P65 CARC 15 = MI 293 Code key: CARC=Carcinogen; REPRO=Reproductive SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 09: Boiling Point C(F) was modified. Section 08: Comply with applicable regulations phrase was modified. Section 09: Vapor Pressure was modified. Hazard Identification: Health Hazards was modified. Section 11: Dermal Lethality Test Data was modified. Section 11: Dermal Lethality Test Comment was modified. Section 11: Oral Lethality Test Data was modified. Section 11: Inhalation Lethality Test Data was modified. Section 11: Dermal Irritation Test Data was modified. Section 11: Eye Irritation Test Data was modified. Section 11: Oral Lethality Test Comment was modified. Section 11: Inhalation Lethality Test Comment was modified. Section 11: Dermal Irritation Test Comment was modified. Page 518 of 878 Page 518 of 878 Page 518 of 878 Page 518 of 878 ---PAGE BREAK--- Product Name: MOBIL RARUS 427 Revision Date: 14 Jun 2012 Page 9 of 9 Section 11: Eye Irritation Test Comment was modified. Section 11: Inhalation Irritation Test Data was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Viscosity was modified. Section 15: National Chemical Inventory Listing was modified. Section 16: Code to MHCs was modified. Section 15: Community RTK - Header was modified. The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A DGN: 2008423XUS (1013559) Copyright 2002 Exxon Mobil Corporation, All rights reserved Page 519 of 878 Page 519 of 878 Page 519 of 878 Page 519 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET U.S. Department of Labor May be used to comply with OSHA’s Occupational Safety and Health Administration Hazard Communication Standard (Non-Mandatory Form) 29 CFR1910.1200. Standard must be Form approved OMB. No. 1218-0072 consulted for specific requirements. IDENTITY (As used on label and list) Natural Magic Odor Blaster Liquid Note: Blank spaces are not permitted. If any item is not applicable or information is not available, the space must be marked to indicate that. Section l Bar Code: 781748 06010 4 #6010 781748 06000 5 #6000 781748 06080 7 #6080 781748 06040 1 #6040 Manufacturer’s name: Osmegen Incorporated Emergency Telephone Number: Poison Control [PHONE REDACTED] Address: P.O. Box 20426 Telephone Number for information: [PHONE REDACTED] or [PHONE REDACTED] Lehigh Valley, PA 18002 Date Prepared: 3/25/98 Section ll – Hazardous Ingredients/Identity Information Hazardous Components (Specific Chemical Identity: Common Name(s)), OSHA PEL, ACGIH TLV, Other Limits Proprietary Formula All components used to make this product are considered to be safe, through normal use of such product. Section lll – Physical/Chemical Characteristics Boiling Point, Degrees F: 212 Freezing Point, Degrees F: 32 Specific Gravity (water = 1.005 pH: 8.0 – 8.5 Water Solubility, 100% Vapor Density (Air = N/A Evaporation Rate (Water = N/A Appearance and Odor: Natural Section lV – Fire and Explosion Hazard Flash Point: Non-Flammable Flammable Limits Vol) LEL: N/A UEL: N/A Extinguishing Media: N/A Special Fire Fighting Procedures: N/A Unusual Fire and Explosion Hazards: N/A Page 520 of 878 Page 520 of 878 Page 520 of 878 Page 520 of 878 ---PAGE BREAK--- Section V – Reactivity Data Stability: Stable Conditions to Avoid: N/A Incompatibility (Materials to Avoid): None Known Hazardous Decomposition or Byproducts: N/A Hazardous Polymerization: Will not Occur Conditions to Avoid: N/A Section Vl – Health Hazard Data Route(s) of Entry: Inhalation? No Hazard Skin? Remove with water Ingestion? None Health Hazards (Acute and Chronic): N/A Carcinogenicity: None known NTF? None IARC Monographs? None OSHA Regulated? No Signs and of Exposure: None currently known for Inhalation, Eye contact, skin contact, or ingestion. Medical Conditions Generally Aggravated by Exposure: Available information and professional opinion suggest that it is unlikely to aggravate existing medical conditions. Emergency and First Aid Procedures: N/A Section Vll – Precautions for Safe Handling and Use Steps to be Taken In Case Material is Spilled or Released: A routine clean up with water Waste Disposal Method: Any accepted state, federal or local method to transfer to waste disposal. Handling and Storage Precautions: None Other precautions: None Section Vlll – Control Measures Respiratory Protection (Specify Type): None required Local Exhaust: N/A Ventilation (when product is in melted state) Mechanical (General): N/A Special (melted state): N/A Protective Gloves: None Eye Protection: None Other Protective Clothing or Equipment: None Work/Hygienic Practices: If irritation occurs, discontinue use of product. Page 521 of 878 Page 521 of 878 Page 521 of 878 Page 521 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET U.S. Department of Labor May be used to comply with OSHA’s Occupational Safety and Health Administration Hazard Communication Standard (Non-Mandatory Form) 29 CFR1910.1200. Standard must be Form approved OMB. No. 1218-0072 consulted for specific requirements. IDENTITY (As used on label and list) Natural Magic Odor Blaster Liquid Note: Blank spaces are not permitted. If any item is not applicable or information is not available, the space must be marked to indicate that. Section l Bar Code: 781748 06010 4 #6010 781748 06000 5 #6000 781748 06080 7 #6080 781748 06040 1 #6040 Manufacturer’s name: Osmegen Incorporated Emergency Telephone Number: Poison Control [PHONE REDACTED] Address: P.O. Box 20426 Telephone Number for information: [PHONE REDACTED] or [PHONE REDACTED] Lehigh Valley, PA 18002 Date Prepared: 3/25/98 Section ll – Hazardous Ingredients/Identity Information Hazardous Components (Specific Chemical Identity: Common Name(s)), OSHA PEL, ACGIH TLV, Other Limits Proprietary Formula All components used to make this product are considered to be safe, through normal use of such product. Section lll – Physical/Chemical Characteristics Boiling Point, Degrees F: 212 Freezing Point, Degrees F: 32 Specific Gravity (water = 1.005 pH: 8.0 – 8.5 Water Solubility, 100% Vapor Density (Air = N/A Evaporation Rate (Water = N/A Appearance and Odor: Natural Section lV – Fire and Explosion Hazard Flash Point: Non-Flammable Flammable Limits Vol) LEL: N/A UEL: N/A Extinguishing Media: N/A Special Fire Fighting Procedures: N/A Unusual Fire and Explosion Hazards: N/A Page 522 of 878 Page 522 of 878 Page 522 of 878 Page 522 of 878 ---PAGE BREAK--- Section V – Reactivity Data Stability: Stable Conditions to Avoid: N/A Incompatibility (Materials to Avoid): None Known Hazardous Decomposition or Byproducts: N/A Hazardous Polymerization: Will not Occur Conditions to Avoid: N/A Section Vl – Health Hazard Data Route(s) of Entry: Inhalation? No Hazard Skin? Remove with water Ingestion? None Health Hazards (Acute and Chronic): N/A Carcinogenicity: None known NTF? None IARC Monographs? None OSHA Regulated? No Signs and of Exposure: None currently known for Inhalation, Eye contact, skin contact, or ingestion. Medical Conditions Generally Aggravated by Exposure: Available information and professional opinion suggest that it is unlikely to aggravate existing medical conditions. Emergency and First Aid Procedures: N/A Section Vll – Precautions for Safe Handling and Use Steps to be Taken In Case Material is Spilled or Released: A routine clean up with water Waste Disposal Method: Any accepted state, federal or local method to transfer to waste disposal. Handling and Storage Precautions: None Other precautions: None Section Vlll – Control Measures Respiratory Protection (Specify Type): None required Local Exhaust: N/A Ventilation (when product is in melted state) Mechanical (General): N/A Special (melted state): N/A Protective Gloves: None Eye Protection: None Other Protective Clothing or Equipment: None Work/Hygienic Practices: If irritation occurs, discontinue use of product. Page 523 of 878 Page 523 of 878 Page 523 of 878 Page 523 of 878 ---PAGE BREAK--- Page 524 of 878 Page 524 of 878 Page 524 of 878 Page 524 of 878 ---PAGE BREAK--- Page 525 of 878 Page 525 of 878 Page 525 of 878 Page 525 of 878 ---PAGE BREAK--- Page 526 of 878 Page 526 of 878 Page 526 of 878 Page 526 of 878 ---PAGE BREAK--- Page 527 of 878 Page 527 of 878 Page 527 of 878 Page 527 of 878 ---PAGE BREAK--- Page 1 of 3 MATERIAL SAFETY DATA SHEET SECTION I: PRODUCT IDENTIFICATION: #44, #440, #549, #548, #46, #550 TRADE NAME: ORANGE GOOP LIQUID, ORANGE GOOP LIQUID WITH PUMICE MANUFACTURER'S NAME: Critzas Industries, Inc., 4041 Park Avenue, St. Louis, MO 63110 PHONE NUMBER FOR ADDITIONAL INFORMATION: [PHONE REDACTED] FAX NUMBER FOR ADDITIONAL INFORMATION: [PHONE REDACTED] EMERGENCY INFORMATION: For chemical emergency 911 DATE PREPARED OR REVISED: January 1, 2009 PREPARED BY (optional): SECTION II: HAZARDOUS INGREDIENTS EXPOSURE LIMITS Chemical Names CAS Numbers % ACGIH TLV OSHA PEL OTHER Notification Requirements D- Limonene 5939-27-5 5 NONE NONE CN 1 HMIS RATING: Health: 1 Fire: 1 Reactivity: 0 Personal protection: NONE SECTION III: PHYSICAL PROPERTIES VAPOR DENSITY (AIR = <1 MELTING POINT/RANGE: N/A SPECIFIC GRAVITY: (Water=1):0.90 g/cc BOILING POINT/RANGE: 212° F SOLUBILITY IN WATER: Completely Dispersable EVAPORATION RATE (BuAc = >1 VAPOR PRESSURE, mm Hg @ 20 degrees C: APPEARANCE AND ODOR: Creamy orange, citrus scent This product contains less than 5 % VOC by formulation. VOC CONTENT DETERMINATION USING ARB METHOD 310 This product is not photochemically reactive. SECTION IV: FIRE AND EXPLOSION FLASH POINT, 200° F AUTO-IGNITION TEMPERATURE, >213° F FLAMMABLE LIMITS IN AIR (VOLUME LOWER N/A UPPER N/A FIRE EXTINGUISHING MATERIALS: WATER SPRAY: YES FOAM: YES CARBON DIOXIDE: YES DRY CHEMICAL: YES OTHER: N/A SPECIAL FIRE FIGHTING PROCEDURES: NO SPECIAL EQUIPMENT NECESSARY UNUSUAL FIRE AND EXPLOSION HAZARDS: NONE This form complies with and is essentially similar to OSHA Form 174 as specified in 29CFR 1910.1200 (Federal OSHA Hazard Communication Standard) and complies with requirements of CAL/OSHA. Page 528 of 878 Page 528 of 878 Page 528 of 878 Page 528 of 878 ---PAGE BREAK--- 2 Page 2 of 3 MATERIAL SAFETY DATA SHEET SECTION V: HEALTH HAZARD INFORMATION OF OVEREXPOSURE FOR EACH POTENTIAL ROUTE OF EXPOSURE INHALED: N/A CONTACT WITH SKIN OR EYES: WASH SKIN WITH WATER, FLUSH EYES WITH WATER ABSORBED THROUGH SKIN: NONE SWALLOWED: DO NOT INDUCE VOMITING. Seek medical attention immediately. Give large quantities of water. If available, give several glasses of milk or acidic beverages (tomato or orange juice, carbonated soft drinks). Never give anything by mouth to an unconscious person. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. HEALTH EFFECTS OR RISKS FROM EXPOSURE (Explain in lay terms) N/A ACUTE: N/A CHRONIC: N/A FIRST AID EMERGENCY PROCEDURES EYE CONTACT: Flush eyes for at least 15 minutes with running water, periodically lifting upper and lower lids to ensure washing of entire surface. If irritation persists get medical attention. SKIN CONTACT: Remove contaminated clothing. Wash affected area with soap and water. Seek medical attention if irritation persists. Do not wear contaminated clothing until properly laundered. INHALED: N/A SUSPECTED CANCER AGENT? X NO. THIS PRODUCT'S INGREDIENTS ARE NOT FOUND IN THE LISTS BELOW. YES. FEDERAL OSHA NTP IARC California employers using CAL/OSHA regulated carcinogens must register with CAL/OSHA. The CAL/OSHA and Federal OSHA carcinogen lists are similar. CALIFORNIA PROP. 65 STATEMENT This product does not contain chemicals known to the state of California to cause cancer, birth defects or cause reproductive harm. PRE-EXISTING MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: N/A SECTION VI: REACTIVITY DATA PRODUCT IS ( X ) STABLE UNSTABLE CONDITIONS TO AVOID: Avoid contact with heat, sparks and open flame. INCOMPATIBILITY (materials to avoid): Strong oxidizing agents, sources of ignition. HAZARDOUS DECOMPOSITION PRODUCTS, INCLUDING COMBUSTION: Carbon monoxide, carbon dioxide and unburned hydrocarbons. HAZARDOUS POLYMERIZATION MAY OCCUR ( X ) WILL NOT OCCUR. CONDITIONS TO AVOID: Heat over 140 ° F / cold under –10 ° F Page 529 of 878 Page 529 of 878 Page 529 of 878 Page 529 of 878 ---PAGE BREAK--- 3 Page 3 of 3 MATERIAL SAFETY DATA SHEET SECTION VII: SPILL, LEAK AND DISPOSAL PROCEDURES SPILL RESPONSE PROCEDURES, INCLUDING EMPLOYEE PROTECTION: Flush spill with water. May be necessary to wash with a detergent and flush again with water to ensure surface is no longer slick. PREPARING WASTES FOR DISPOSAL (containers, neutralization, etc.): N/A NOTE: DISPOSE OF ALL WASTES IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. SECTION VIII: SPECIAL HANDLING INFORMATION VENTILATION AND ENGINEERING CONTROLS: N/A RESPIRATORY PROTECTION (TYPE): N/A EYE PROTECTION (TYPE): N/A GLOVES (SPECIFY MATERIAL): N/A OTHER CLOTHING AND EQUIPMENT: N/A WORK PRACTICES, HYGIENIC PRACTICES: Wash hands thoroughly after use and before eating, drinking, smoking or using the toilet. OTHER HANDLING AND STORAGE REQUIREMENTS: Keep containers closed when not in use. Do not use near sources of ignition. PROTECTIVE MEASURES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: N/A SECTION IX: SHIPPING INFORMATION FULL DOT SHIPPING NAME: Cleaning Compounds OT Granular, Liquid or Powder, NOI NMFC#048581 DOT HAZARD CLASS: N/A PACKING GROUP: N/A UN/NA NUMBER: N/A SECTION X: ENVIRONMENTAL STATEMENT THIS PRODUCT IS / IS NOT SUBJECT TO REPORTING ACCORDING TO SARA, TITLE III (SUPERFUND AMENDMENT). Information contained in this safety data sheet is drawn from recognized sources and is believed to be accurate and correct as of the date of issue. It is presented for your evaluation of the suitability of the product and for compliance with federal and state regulations. No claims are made for the accuracy, completeness and reliability of the information contained herein. Page 530 of 878 Page 530 of 878 Page 530 of 878 Page 530 of 878 ---PAGE BREAK--- SPARTAN CHEMICAL COMPANY, INC. WHMIS MATERIAL SAFETY DATA SHEET SECTION I: PRODUCT INFORMATION PRODUCT IDENTIFIER ORANGE TOUGH 40 PRODUCT USE: Water-Dilutable, Water Rinsable, Multipurpose Degreaser MANUFACTURER’S NAME & ADDRESS MEDICAL EMERGENCY TELEPHONE Spartan Chemical Company, Inc. 888/314-6171 (24 Hours) 1110 Spartan Drive, Maumee, OH 43537 USA PRODUCT INFORMATION 800/537-8990 SECTION II: HAZARDOUS INGREDIENTS CAS TLV REGISTRY % W CHEMICAL NAME(S) TWA STEL Ceiling LD50 LC50 NO. mg/m3 mg/m3 mg/m3 5989-27-5 35-45 d-Limonene Not Established Not available Not available 127087-87-0 10-15 ethoxylate Not Established Not available Not available 27323-41-7 5-10 Triethanolamine dodecylbenzenesulfonate Not Established Not available Not available 102-71-6 5-10 Triethanolamine 5 (ACGIH) Not available Not available 107-41-5 1-5 Hexylene glycol 121 (ACGIH) Not available Not available 66375-37-9 1-5 Dicarboxylic fatty acid, dipotassium salt Not Established Not available Not available 64-02-8 1-5 Tetrasodium ethylenediaminetetraacetate Not Established Not available Not available SECTION III: PHYSICAL DATA BOILING POINT SPECIFIC GRAVITY (H20 = 1) PERCENT SOLID BY WEIGHT > 100 °C (212°F) 0.96 20-25 VAPOUR PRESSURE EVAPORATION RATE (butyl acetate = 1) FREEZING POINT Not established < 1 Not available VAPOUR DENSITY (AIR = 1) SOLUBILITY IN WATER Not established Complete pH APPEARANCE AND ODOUR ODOUR THRESHOLD 9.0 Orange liquid, orange odor Not available COEFFICIENT OF WATER/OIL DISTRIBUTION PHYSICAL STATE Not available GAS LIQUID X SOLID SECTION IV: FIRE & EXPLOSION DATA FLASH POINT METHOD USED FLAMMABLE LIMITS 51 °C (124°F) ASTM - D56 Not established EXTINGUISHING MEDIA CONDITIONS OF FLAMMABILITY AUTO-IGNITION TEMPERATURE Foam, dry chemical, CO2, Not applicable Not applicable water fog or spray. HAZARDOUS COMBUSTION PRODUCTS EXPLOSION DATA Not established Not applicable SPECIAL FIRE FIGHTING PROCEDURES Use self-contained breathing apparatus for maximum respiratory protection. Cool fire-exposed containers with water spray. UNUSUAL FIRE AND EXPLOSION HAZARDS Combustible liquid and vapor. Keep away from heat, sparks or flame. Combustion products are toxic. Page 531 of 878 Page 531 of 878 Page 531 of 878 Page 531 of 878 ---PAGE BREAK--- SECTION V: REACTIVITY DATA STABILITY: STABLE X CONDITIONS OF INSTABILITY CONDITIONS OF REACTIVITY Not established Not established INCOMPATIBILITY (MATERIALS TO AVOID) Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS Carbon dioxide, carbon monoxide SECTION VI: TOXICOLOGICAL PROPERTIES PRIMARY ROUTES OF ENTRY: Eye Contact, Skin Contact, Ingestion, Inhalation EXPOSURE LIMIT Not established for mixture. EFFECTS OF ACUTE EXPOSURE: EYE CONTACT: Causes eye irritation with such as pain, redness and swelling of the conjunctiva. INGESTION: Harmful if swallowed. may include pain, nausea and diarrhea. SKIN CONTACT: Causes skin irritation with such as redness, pain and swelling. INHALATION: Breathing vapors or mist may cause respiratory irritation. may include nasal discomfort and coughing. EFFECTS OF CHRONIC EXPOSURE Repeated over exposure to triethanolamine may cause liver and kidney damage. IRRITANCY OF PRODUCT SENSITIZATION TO PRODUCT CARCINOGENICITY Causes skin and eye irritation Contains d-limonene, hexylene glycol No and triethanolamine which may cause skin sensitization with repeated contact. REPRODUCTIVE TOXICITY TERATOGENICITY MUTAGENICITY SYNERGISTIC PRODUCTS Not available Not available Not available Not available SECTION VII: PREVENTIVE MEASURE PERSONAL PROTECTIVE EQUIPMENT / ENGINEERING CONTROLS: Wear rubber or other impervious gloves and splash goggles. Provide good general ventilation. Local exhaust ventilation may be necessary for some operations. If exposure limits (see Section II) can not be maintained by ventilation, use of a NIOSH approved respirator suitable for the conditions of use and chemicals in Section II should be considered. LEAK AND SPILL PROCEDURE: Dike and contain spill with inert material (sand, earth, commercial absorbent, etc.) and transfer to containers for disposal. Keep spill out of storm sewers and waterways. WASTE DISPOSAL METHOD: Assure conformance with applicable regulations. HANDLING PROCEDURES: Avoid contact with eyes, skin and clothing. Avoid breathing product vapors or mist. Do not swallow. Use with adequate ventilation. Wash thoroughly after handling. STORAGE REQUIREMENTS: Combustible liquid and vapors. Flash point 82 °C (179°F). Keep away from heat, sparks or open flame. Keep container closed when not in use. Do not freeze. Do not store above 49°C (120°F). Keep out of reach of children. SPECIAL SHIPPING INFORMATION: Flammable liquids, n.o.s.,3,UN 1993, III (contains d-limonene) SECTION VIII: FIRST AID MEASURES EYES: Flush eyes with water for at least 15 minutes. Remove contact lenses. Get medical attention. SKIN: Remove contaminated clothing. Flush skin with water for at least 15 minutes. Get medical attention if irritation persists. Wash contaminated clothing before reuse. INGESTION: Do not induce vomiting. Drink one or two glasses of water to dilute product. Get medical attention. Do not give anything by mouth to an unconscious person. INHALATION: In case of respiratory irritation move person to fresh air. Get medical attention if irritation persists. SECTION IX: PREPARATION INFORMATION ORANGE TOUGH 40 DATE OF PREPARATION: June 1, 2015 SUPERCEDES: June 8, 2012 PREPARED BY Ronald T. Cook / Manager, Regulatory Affairs / Spartan Chemical Company, Inc. TELEPHONE NUMBER 800/537-8990 Page 532 of 878 Page 532 of 878 Page 532 of 878 Page 532 of 878 ---PAGE BREAK--- Page 533 of 878 Page 533 of 878 Page 533 of 878 Page 533 of 878 ---PAGE BREAK--- Page 534 of 878 Page 534 of 878 Page 534 of 878 Page 534 of 878 ---PAGE BREAK--- ---PAGE BREAK--- ---PAGE BREAK--- ---PAGE BREAK--- ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Oxivir Tb Version Number: 1 Preparation date: 2006-03-02 Personal protective equipment NFPA HMIS Reactivity 0 None / Aucune / Ninguno Health Fire Hazard 0 0 0 0 0 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Oxivir Tb MSDS MS0200014 Product code: 4277285, 4277293 Recommended use: Disinfectant / Deodorizer / Sanitizer. Emergency telephone number: 1-[PHONE REDACTED] (Prosar); 1-[PHONE REDACTED] (Int'l Prosar); 01-[PHONE REDACTED] (México) 2. HAZARDS IDENTIFICATION Principle routes of exposure: Eye contact. Skin contact. Inhalation. Ingestion. Eye contact: None known. Skin contact: None known. Inhalation: None known. Ingestion: None known. 3. COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS COMPONENTS Ingredient(s) CAS # Weight % LD50 Oral - Rat LD50 Dermal - Rabbit LC50 Inhalation - Rat Hydrogen peroxide 7722-84-1 0.1 - 1.5% =801 mg/kg =2000 mg/kg =2 mg/L (4 h) Benzyl alcohol 100-51-6 1 - 5% =1230 mg/kg =2000 mg/kg =8.8 mg/L (4 h) 4. FIRST AID MEASURES Eye contact: Rinse with plenty of water. Skin contact: Rinse with plenty of water. Inhalation: No specific first aid measures are required. Ingestion: No specific first aid measures are required. Aggravated Medical Conditions: None known. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: Dry chemical, water spray, foam, carbon dioxide. Specific hazards: Not applicable Unusual hazards: None known Specific methods: No special methods required Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: No information available Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-0902 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.johnsondiversey.com Oxivir Tb Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] 1 of 3 EMERGENCY OVERVIEW The product contains no substances which at their given concentration, are considered to be hazardous to health. Page 539 of 878 Page 539 of 878 Page 539 of 878 Page 539 of 878 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Not applicable. Environmental precautions and clean-up methods: Use appropriate containment to avoid environmental contamination. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Keep in suitable and closed containers for disposal. Use a water rinse for final clean-up. 7. HANDLING AND STORAGE Handling: Handle in accordance with good industrial hygiene and safety practice. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep closed in a dry, cool and well-ventilated place. KEEP OUT OF THE REACH OF CHILDREN. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: No special ventilation requirements. Personal Protective Equipment Eye protection: No special requirements under normal use conditions. Hand protection: No special requirements under normal use conditions Skin and body protection: No special requirements under normal use conditions. Respiratory protection: No special requirements under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Ingredient(s) CAS # ACGIH OSHA Mexico Hydrogen peroxide 7722-84-1 1 ppm (TWA) 1 ppm (TWA) 1.4 mg/m3 (TWA) 2 ppm (STEL) 3 mg/m3 (STEL) 1 ppm (TWA) 1.5 mg/m3 (TWA) 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY Stability: The product is stable Polymerization: Hazardous polymerization does not occur Hazardous decomposition products: None reasonably foreseeable. 11. TOXICOLOGICAL INFORMATION Acute toxicity Oral, Dermal LD50 estimated to be greater than 5000 mg/kg. Component Information: See Section 3 Chronic toxicity: None known Specific effects Carcinogenic effects: None known Mutagenic effects: None known Reproductive toxicity: None known Target organ effects: None known HAZARDOUS COMPONENTS Ingredient(s) CAS # NTP IARC OSHA Hydrogen peroxide 7722-84-1 3 Melting point/range: Not determined Bulk density: Density: 8.41 Appearance: Decomposition temperature: Not determined Aqueous solution VOC: No information available No information available Autoignition temperature: No information available Vapor density: Flash point: 200 93.3 No information available Partition coefficient (n-octanol/water): No information available Liquid Solubility: Easily soluble Color: Solubility in other solvents: No information available Colourless Viscosity: No information available pH: Evaporation Rate No information available 3 Odor: Characteristic Physical State: Boiling point/range: Not determined Dilution pH: Oxivir Tb Specific gravity: 1.01 2 of 3 No information available. Page 540 of 878 Page 540 of 878 Page 540 of 878 Page 540 of 878 ---PAGE BREAK--- 12. ECOLOGICAL INFORMATION Environmental Information: No data available 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: PESTICIDAL WASTE - Observe all applicable Federal/Provincial/State regulations and Local/Municipal ordinances regarding disposal of pesticide wastes. 14. TRANSPORT INFORMATION DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the following inventories: U.S.A. (TSCA). U.S. Regulations EPA Reg. No. : 70627-56 California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 STATE RIGHT TO KNOW Ingredient(s) CAS # MARTK: PARTK: RIRTK: Water 7732-18-5 - - - - Hydrogen peroxide 7722-84-1 X X X X Benzyl alcohol 100-51-6 X - X - CERCLA/ SARA Ingredient(s) CAS # Weight % CERCLA/SARA RQ (lbs) Section 302 TPQ (lbs) Section 313 Hydrogen peroxide 7722-84-1 0.1 - 1.5% 1000 SARA 311/312 Hazard Categories Immediate: N Delayed: N Fire: N Reactivity: N Sudden Release of Pressure: N Canada WHMIS hazard class: Non-controlled. Ingredient(s) CAS # NPRI Benzyl alcohol 100-51-6 X DIN No. : 02283522 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: None Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 3 of 3 Oxivir Tb Page 541 of 878 Page 541 of 878 Page 541 of 878 Page 541 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Oxivir Tb Wipes NFPA HMIS Personal protective equipment Version Number: 1 Preparation date: 2007-12-06 0 Reactivity 0 None / Aucune / Ninguno Health Fire Hazard 0 0 0 0 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Oxivir Tb Wipes MSDS MS0200097 Product Code: 4599516 Recommended use: Disinfectant / Deodorizer / Sanitizer. Emergency telephone number: 1-[PHONE REDACTED] (Prosar); 1-[PHONE REDACTED] (Int'l Prosar); 01-[PHONE REDACTED] (México) 2. HAZARDS IDENTIFICATION Principle routes of exposure: Eye contact. Skin contact. Inhalation. Ingestion. Eye contact: None known. Skin contact: None known. Inhalation: None known. Ingestion: None known. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components None 4. FIRST AID MEASURES Eye contact: Rinse with plenty of water. Skin contact: Rinse with plenty of water. Inhalation: No specific first aid measures are required. Ingestion: Do not induce vomiting. Call medical attendant, medical doctor, or poison control center . Aggravated Medical Conditions: None known. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: Dry chemical, water spray, foam, carbon dioxide. Specific hazards: Not applicable Unusual hazards: None known Specific methods: No special methods required Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: No information available 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Not relevant for the product itself. Environmental precautions and clean-up methods: Use appropriate containment to avoid environmental contamination. EMERGENCY OVERVIEW The product contains no substances which at their given concentration, are considered to be hazardous to health. Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-0902 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.johnsondiversey.com Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] Oxivir Tb Wipes 1 of 3 Page 542 of 878 Page 542 of 878 Page 542 of 878 Page 542 of 878 ---PAGE BREAK--- 7. HANDLING AND STORAGE Handling: Handle in accordance with good industrial hygiene and safety practice. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: No special ventilation requirements. Personal Protective Equipment Eye protection: No special requirements under normal use conditions. Hand protection: No special requirements under normal use conditions Skin and body protection: No special requirements under normal use conditions. Respiratory protection: No special requirements under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES * - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 10. STABILITY AND REACTIVITY Stability: The product is stable Polymerization: Hazardous polymerization does not occur Hazardous decomposition products: None reasonably foreseeable. Materials to avoid: None known. Conditions to avoid: None known. 11. TOXICOLOGICAL INFORMATION Acute toxicity: Oral LD50 estimated to be greater than 5000 mg/kg. Dermal LD50 estimated to be > 2000 mg/kg Component Information: See Section 3 Chronic toxicity: None known Specific effects Carcinogenic effects: None known Mutagenic effects: None known Reproductive toxicity: None known Target organ effects: None known 12. ECOLOGICAL INFORMATION Environmental Information: No data available 13. DISPOSAL CONSIDERATIONS Do not contaminate water, food, or feed by storage or disposal Waste from residues / unused products: PESTICIDAL WASTE - Observe all applicable Federal/Provincial/State regulations and Local/Municipal ordinances regarding disposal of pesticide wastes. VOC: 0% * No information available Autoignition temperature: No information available Vapor density: Flash point: 200°F 93.3°C No information available Partition coefficient (n-octanol/water): No information available Solid Solubility: completely soluble Color: Solubility in other solvents: No information available Colorless Viscosity: No information available pH: Elemental Phosphorus: 0 %P Evaporation Rate No information available 3 Odor: Characteristic Physical State: Boiling point/range: Not determined Dilution pH: Specific gravity: 1.01 No information available. Melting point/range: Not determined Bulk density: Density: 8.41 Appearance: Oxivir Tb Wipes Decomposition temperature: Not determined 2 of 3 Moistened Towelette Page 543 of 878 Page 543 of 878 Page 543 of 878 Page 543 of 878 ---PAGE BREAK--- Pesticide Storage: Store in original container in areas inaccessible to children. Open dumping is prohibited. Do not reuse empty container Pesticide Disposal: Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal Law Container Disposal: Triple rinse (or equivalent). Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or incinerate, or, if allowed by State and local authorities burn. If burned, stay out of smoke 14. TRANSPORT INFORMATION DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL), Australia (AICS), Korea (ECL), Philippines (PICCS), China (IECSC). U.S. Regulations EPA Reg. No. : 70627-60 California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 CERCLA/ SARA None SARA 311/312 Hazard Categories Immediate: N Delayed: N Fire: N Reactivity: N Sudden Release of Pressure: N 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: None Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 3 of 3 Oxivir Tb Wipes Page 544 of 878 Page 544 of 878 Page 544 of 878 Page 544 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET P.O.G. Spotter Gel 1. PRODUCT AND COMPANY IDENTIFICATION Product name: P.O.G. Spotter Gel MSDS MS0300125 Product Code: 13888, 5045267 Recommended use: Industrial/Institutional. Carpet Care. Emergency telephone number: 1-[PHONE REDACTED] 1-[PHONE REDACTED] (Int'l) 2. HAZARDS IDENTIFICATION Principle routes of exposure: Eye contact. Skin contact. Inhalation. Eye contact: May be mildly irritating to eyes. Skin contact: May be mildly irritating to skin. Inhalation: None know n. Ingestion: None know n. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous ingredients Ingredient(s) CAS # Weight % LD50 Oral - Rat (mg/kg) LD50 Dermal - Rabbit LC50 Inhalation - Rat Diethylene glycol butyl ether 112-34-5 20 - 30% 3384 = 2700 mg/kg Not available Triethanolamine 102-71-6 0.1 - 1.5% 8000 >2000 mg/kg Not available Amorphous silica 7631-86-9 1 - 5% 5000 >2000 mg/kg Not available 4. FIRST AID MEASURES Eye contact: Flush immediately w ith plenty of w ater. If irritation develops, get medical attention. Skin contact: Flush immediately w ith plenty of w ater. If irritation develops, get medical attention. Inhalation: No specific first aid measures are required. Ingestion: No specific first aid measures are required. Aggravated Medical Conditions: None know n. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: Use dry chemical, CO2, w ater spray or "alcohol" foam. Specific hazards: Not applicable Unusual hazards: None know n Specific methods: No special methods required Special protective equipment for firefighters: As in any fire, w ear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: No information available 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Use personal protective equipment EMERGENCY OVERVIEW CAUTION. MAY BE MILDLY IRRITATING TO EYES. MAY BE MILDLY IRRITATING TO SKIN. COMBUSTIBLE LIQUID AND VAPOR. NFPA Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-1964 Phone: 1-[PHONE REDACTED] MSDS Internet Address: w w w .johnsondiversey.com Version Number: 1 Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] Preparation date: 2008-08-28 Personal protective equipment P.O.G. Spotter Gel HMIS 1 of 3 0 0 1 Fire Hazard None / Aucune / Ninguno 2 1 Health 2 Reactivity Page 545 of 878 Page 545 of 878 Page 545 of 878 Page 545 of 878 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Environmental precautions and clean-up methods: Soak up w ith inert absorbent material. Sw eep up and shovel into suitable containers for disposal. Use a w ater rinse for final clean-up. 7. HANDLING AND STORAGE Handling: Avoid contact w ith skin and eyes. COMBUSTIBLE LIQUID AND VAPOR . Keep aw ay from open flames, hot surfaces and sources of ignition. Use only in w ell-ventilated areas. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep closed in a dry, cool and w ell-ventilated place. KEEP OUT OF REACH OF CHILDREN. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: No special ventilation requirements. General room ventilation is adequate. Personal Protective Equipment Eye protection: No special requirements under normal use conditions. Hand protection: No special requirements under normal use conditions Skin and body protection: No special requirements under normal use conditions. Respiratory protection: No special requirements under normal use conditions. Hygiene measures: Handle in accordance w ith good industrial hygiene and safety practice. Ingredient(s) CAS # ACGIH OSHA Mexico Triethanolamine 102-71-6 5 mg/m3 (TWA) 9. PHYSICAL AND CHEMICAL PROPERTIES * - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 10. STABILITY AND REACTIVITY Stability: The product is stable Polymerization: Hazardous polymerization does not occur Hazardous decomposition products: None reasonably foreseeable. Conditions to avoid: Keep aw ay from heat. Do not freeze. 11. TOXICOLOGICAL INFORMATION Acute toxicity: Oral LD50 estimated to be greater than 5000 mg/kg Dermal LD50 estimated to be > 2000 mg/kg Component Information: See Section 3 Chronic toxicity: None know n Specific effects Carcinogenic effects: None know n Mutagenic effects: None know n Reproductive toxicity: None know n Target organ effects: None know n Hazardous ingredients Ingredient(s) CAS # NTP IARC OSHA Triethanolamine 102-71-6 3 Amorphous silica 7631-86-9 3 12. ECOLOGICAL INFORMATION Environmental Information: No data available Autoignition temperature: No information available Vapor density: Flash point: 186°F 85.5°C No information available Partition coefficient (n-octanol/water): No information available Gel Solubility: Dispersible Color: Solubility in other solvents: No information available Translucent Colorless Viscosity: No information available pH: Elemental Phosphorus: 0% by w t. Evaporation Rate No information available NA Odor: Fruity Physical State: Boiling point/range: Not determined Dilution pH: Specific gravity: 0.84 No information available. Melting point/range: Not determined Bulk density: Density: 7.07 lbs/gal Kg/L Appearance: Decomposition temperature: Not determined Viscous liquid VOC: P.O.G. Spotter Gel 0% 2 of 3 No information available Page 546 of 878 Page 546 of 878 Page 546 of 878 Page 546 of 878 ---PAGE BREAK--- 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Dispose of according to all federal, state and local applicable regulations 14. TRANSPORT INFORMATION DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the follow ing inventories: U.S.A. (TSCA), Canada (DSL/NDSL). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 STATE RIGHT TO KNOW Ingredient(s) CAS # MARTK: PARTK: RIRTK: Aliphatic hydrocarbons 64742-47-8 - - - - Alcohol ethoxylate 68002-97-1 - - - - Diethylene glycol butyl ether 112-34-5 - - - - Triethanolamine 102-71-6 X - X X Amorphous silica 7631-86-9 X X X - CERCLA/ SARA Ingredient(s) CAS # Weight % CERCLA/SARA RQ (lbs) Section 302 TPQ (lbs) Section 313 Diethylene glycol butyl ether 112-34-5 20 - 30% X Ingredient(s) CAA HAP CAA ODS CWA Priority Pollutants Diethylene glycol butyl ether X SARA 311/312 Hazard Categories Canada WHMIS hazard class: B3 Combustible liquid . Ingredient(s) CAS # NPRI Aliphatic hydrocarbons 64742-47-8 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: None Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 3 of 3 P.O.G. Spotter Gel Page 547 of 878 Page 547 of 878 Page 547 of 878 Page 547 of 878 ---PAGE BREAK--- Page 548 of 878 Page 548 of 878 Page 548 of 878 Page 548 of 878 ---PAGE BREAK--- Page 549 of 878 Page 549 of 878 Page 549 of 878 Page 549 of 878 ---PAGE BREAK--- Page 550 of 878 Page 550 of 878 Page 550 of 878 Page 550 of 878 ---PAGE BREAK--- Page 551 of 878 Page 551 of 878 Page 551 of 878 Page 551 of 878 ---PAGE BREAK--- Page 552 of 878 Page 552 of 878 Page 552 of 878 Page 552 of 878 ---PAGE BREAK--- Page 553 of 878 Page 553 of 878 Page 553 of 878 Page 553 of 878 ---PAGE BREAK--- Page 554 of 878 Page 554 of 878 Page 554 of 878 Page 554 of 878 ---PAGE BREAK--- Page 555 of 878 Page 555 of 878 Page 555 of 878 Page 555 of 878 ---PAGE BREAK--- Page 556 of 878 Page 556 of 878 Page 556 of 878 Page 556 of 878 ---PAGE BREAK--- Page 557 of 878 Page 557 of 878 Page 557 of 878 Page 557 of 878 ---PAGE BREAK--- Page 558 of 878 Page 558 of 878 Page 558 of 878 Page 558 of 878 ---PAGE BREAK--- Page 559 of 878 Page 559 of 878 Page 559 of 878 Page 559 of 878 ---PAGE BREAK--- Page 560 of 878 Page 560 of 878 Page 560 of 878 Page 560 of 878 ---PAGE BREAK--- Page 561 of 878 Page 561 of 878 Page 561 of 878 Page 561 of 878 ---PAGE BREAK--- Page 562 of 878 Page 562 of 878 Page 562 of 878 Page 562 of 878 ---PAGE BREAK--- Page 563 of 878 Page 563 of 878 Page 563 of 878 Page 563 of 878 ---PAGE BREAK--- PEAK Antifreeze 1 Initial Preparation Date: 10/9/1990 Last Revision Date: 4/19/2010 Effective Date: 10/21/2010 MATERIAL SAFETY DATA SHEET PRODUCT IDENTITY: PEAK ANTIFREEZE & COOLANT 1. CHEMICAL PRODUCT & COMPANY INFORMATION OLD WORLD INDUSTRIES, INC. 4065 COMMERCIAL AVENUE ILLINOIS 60062 PHONE: [PHONE REDACTED] EMERGENCY PHONE: 1-[PHONE REDACTED] (CHEMTREC) 2. COMPOSITION/INFORMATION ON INGREDIENTS Material CAS# % by Wt PEL (OSHA) TLV (ACGIH) Ethylene Glycol 107-21-1 90 - 95 50 ppm 50 ppm Diethylene Glycol 111-46-6 0 - 5 None None Dipotassium Phosphate 7758-11-4 1 - 2 None None 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Slight odor. May be fatal if swallowed. Vapors can cause eye irritation. Lowest Known LD50 (Oral) 107-21-1 5840 mg/kg (Rats) Lowest Known LD50 (Skin) 107-21-1 9530 mg/kg (Rabbits) HAZARD RATING SYSTEM NFPA: HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0 HMIS: HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0 KEY: 0 – Minimal 1 – Slight 2 - Moderate 3 - Serious 4 - Severe Page 564 of 878 Page 564 of 878 Page 564 of 878 Page 564 of 878 ---PAGE BREAK--- PEAK Antifreeze 2 POTENTIAL HEALTH EFFECTS Routes of Exposure: Inhalation, Ingestion, Skin Contact/Absorption, Eye Contact Eye: May cause slight transient (temporary) eye irritation. Corneal injury is unlikely. Vapors or mists may cause eye irritation. Skin: Prolonged or repeated exposure not likely to cause significant skin irritation. A single prolonged exposure is not likely to result in the material being absorbed through skin in harmful amounts. Repeated skin exposure may result in absorption of harmful amounts. Massive contact with damaged skin or of material sufficiently hot to burn skin may result in absorption of potential lethal amounts. Ingestion: Single dose oral toxicity is considered to be moderate. Excessive exposure may cause central nervous system effects, cardiopulmonary effects (metabolic acidosis), and kidney failure. Small amounts swallowed incidental to normal handling operations are not likely to cause injury; however, swallowing amounts larger than that may cause serious injury, even death. Inhalation: At room temperature, exposures to vapors are minimal due to physical properties; higher temperatures may generate vapor levels sufficient to cause adverse effects. Systemic (Other Target Organ) Effects: Repeated excessive exposures may cause severe kidney and also liver and gastrointestinal effects. Signs and of excessive exposure may be central nervous system effects. Signs and of excessive exposure may be nausea and/or vomiting. Signs and of excessive exposure may be anesthetic or narcotic effects. Observations in animals include formation of bladder stones after repeated oral doses of ethylene glycol. Reports of kidney failure and death in burn patients suggest the ethylene glycol may have been a factor. The use of topical applications containing this material may not be appropriate in severely burned patients or individuals with impaired renal function. Cancer Information: Based on data from long-term animal studies, ethylene glycol is not believed to pose a carcinogenic risk to man. Teratology (Birth Defects): Exposure to ethylene glycol has caused birth defects in laboratory animals only at doses toxic to the mother. Reproductive Effects: Ethylene glycol has not interfered with reproduction in animal studies except at very high doses. CHRONIC, PROLONGED OR REPEATED OVEREXPOSURE Effects of Repeated Overexposure: Repeated inhalation of ethylene glycol mist may produce signs of central nervous system involvement, particularly dizziness and nystagmus. Other Effects of Overexposure: repeated skin contact with ethylene glycol may, in a very small proportion of cases, cause sensitization with the development of allergic contact dermatitis. The incidence is significantly less than 1% with the undiluted material. Page 565 of 878 Page 565 of 878 Page 565 of 878 Page 565 of 878 ---PAGE BREAK--- PEAK Antifreeze 3 4. FIRST AID MEASURES Ensure physician has access to this MSDS. TREATMENT Eyes: Immediately flush eyes with large amounts of water for 15 minutes, lifting lower and upper lids. Get medical attention as soon as possible. Contact lenses should never be worn when working with this chemical. Skin: Flush area of skin contact immediately with large amounts of water for at least 15 minutes while removing contaminated clothing. If irritation persists after flushing, get medical attention Wash clothing before re- use. Inhalation: If inhaled, immediately remove victim to fresh air and call emergency medical care. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Ingestion: Obtain medical attention immediately. If patient is fully conscious, give two glasses of water. Do not induce vomiting. If medical advice is delayed, and if the person has swallowed a moderate volume of material (a few ounces), then give three to four ounces of hard liquor, such as whisky. For children, give proportionally less liquor, according to weight. Notes to Physician: It is estimated that the lethal oral dose to adults is of the order of 1.0 ml/kg. Ethylene glycol is metabolized by alcohol dehydrogenate to various metabolites including glyceraldehydes, glycolic acid and oxalic acid which cause an elevated anion-gap metabolic acidosis and renal tubular injury. The signs and in ethylene glycol poisoning are those of metabolic acidosis, CNS depression, and kidney injury. Urinalysis may show albuminuria, hematuria and oxaluria. Clinical chemistry may reveal anion-gap metabolic acidosis and uremia. The currently recommended medical management of ethylene glycol poisoning includes elimination of ethylene glycol and metabolites, correction of metabolic acidosis and prevention of kidney injury. It is essential to have immediate and follow up urinalysis and clinical chemistry. There should be particular emphasis on acid-base balance and renal function tests. A continuous infusion of 5% sodium bicarbonate with frequent monitoring of electrolytes and fluid balance is used to achieve correction of metabolic acidosis and forced diuresis. As a competitive substrate for alcohol dehydrogenase, ethanol is antidotal. Given in the early stages of intoxication, it blocks the formulation of nephrotoxic metabolites. A therapeutically effective blood concentration of ethanol is in the range 100-150 mg/dl, and should be achieved by a rapid loading dose and maintained by intravenous infusion. For severe and/or deteriorating cases, hemodialysis may be required. Dialysis should be considered for patients who are have severe metabolic acidosis, a blood ethylene glycol concentration greater than 25 md/dl, or compromise of renal functions. A more effective intravenous antidote for physician use is a potent inhibitor of alcohol dehydrogenases, which effectively blocks the formation of toxic metabolites of ethylene glycol. It has been used to decrease the metabolic consequences of ethylene glycol poisoning before metabolic acidosis coma, seizures, and renal failure have occurred. A generally recommended protocol is a loading dose of 15 mg/kg followed by 10 mg/kg every 12 hours for 4 doses and then 15 mg/kg every 12 hours until ethylene glycol concentrations are below 20 mg/100 ml. Slow intravenous infusion is required. Since is dialyzable, increased dosage may be necessary during hemodialysis. Additional therapeutic measures may include the administration of cofactors involved in the metabolism of ethylene glycol. Thiamine (100 mg) and pyridoxine (50 mg) should be given every six hours. Page 566 of 878 Page 566 of 878 Page 566 of 878 Page 566 of 878 ---PAGE BREAK--- PEAK Antifreeze 4 Pulmonary edema with hypoxemia has been described in a number of patients following poisoning with ethylene glycol. The mechanism of production has not been elucidated, but it appears to be non-cardiogenic in origin in several cases. Respiratory support with mechanical ventilation and positive end expiratory pressure may be required. There may be cranial nerve involvement in the late stages of toxicity from swallowed ethylene glycol. In particular, effects have been reported involving the seventh, eighth and ninth cranial nerves, presenting with bilateral facial paralysis, diminished hearing and 5. FIRE FIGHTING MEASURES Flammable Properties Flash Point: 119°C (247°F) Method Used: Setaflash Autoignition Temperature: Autoignition temperature for ethylene glycol is 398°C (748°F). Flammability Limits - % of vapor concentration at which product can ignite in presence of spark. Lower Flammability Limit: 3.2% Upper Flammability Limit: 15.3% Hazardous Combustion Products: Hazardous combustion products may include and are not limited to carbon monoxide, carbon dioxide and trace amounts of aldehydes and organic acids. When available oxygen is limited, as in a fire or when heated to very high temperatures by a hot wire or plate, carbon monoxide and other hazardous compounds such as aldehydes might be generated. Extinguishing Media: Water fog or fine spray. Alcohol resistant foams (ATC type) are preferred if available. General purpose foams (including AFFF) or protein foams may function, but much less effectively. Carbon dioxide. Dry chemical. Do not use direct water stream. May spread fire. Fire Fighting Instructions: No fire and explosion hazards expected under normal storage and handling conditions (i.e. ambient temperatures). However, ethylene glycol or solutions of ethylene glycol and water can form flammable vapors with air if heated sufficiently. Keep people away. Isolate fire area and deny unnecessary entry. Protective Equipment for Fire Fighters: Wear positive-pressure, self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire-fighting helmet, coat, pants, boots and gloves). 6. ACCIDENTAL RELEASE MEASURES Protect People: Material is moderately toxic when ingested. Take adequate precautions to keep people, especially children away from spill site. PVC-coated rubber gloves and monogoggles or face shield can be used during cleanup of spill site. Product on surfaces can cause slippery conditions. Practice reasonable care and cleanliness. Avoid breathing spray mists if generated. Keep out of reach of children. Product may become a solid at temperatures below -18oC (0oF). Do not store near food, foodstuffs, drugs or potable water supplies. Protect the Environment: Do not dump used product or diluted material into sewers, on the ground, or into any body of water. Cleanup: Small spills: Soak up with absorbent material. Large spills: Dike and pump into suitable containers for disposal. Ensure compliance with all applicable statues that require notification of appropriate government officials. Page 567 of 878 Page 567 of 878 Page 567 of 878 Page 567 of 878 ---PAGE BREAK--- PEAK Antifreeze 5 7. HANDLING AND STORAGE Steps to be Taken in Case Material is Released or Spilled: Eliminate all sources of ignition in vicinity of the spilled or released fluid. Other Precautions: Use normal precautions in handling any combustible liquid. Keep container closed when not in use. Store away from heat or open flame. Product on surfaces can cause slippery conditions. Practice reasonable care and cleanliness. Avoid breathing spray mists if generated. Keep out of reach of children. Product may become a solid at temperatures below -18 oC (0 oF). Do not store near food, foodstuffs, drugs or potable water supplies. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Respiratory Protection: Respiratory protection is required if airborne concentration exceeds TLV. At any detectable concentration any self-contained breathing apparatus with a full face piece and operated in a pressure- demand or other positive pressure mode or any supplied-air respirator with a full face piece and operated in a pressure-demand or other positive pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive pressure mode. Escape: Any air-purifying full face piece respirator (gas mask) with a chin-style or front- or back-mounted organic vapor canister or any appropriate escape-type self-contained breathing apparatus. Skin Protection: Protective gloves recommended when prolonged skin contact cannot be avoided. Polyethylene; Neoprene; Nitrile; Polyvinyl alcohol; Natural Rubber, Butyl Rubber. Safety shower should be available. Eye Protection: Safety goggles and face shield. Emergency eyewash should be available. Contact lenses should not be worn when working with this chemical. Engineering Controls: Use general or local exhaust ventilation to meet TLV requirements. EXPOSURE LIMITS Component Exposure Limits Skin Form Ethylene glycol 100 mg/m3 CEILING ACGIH Aerosol Ethylene glycol 125 mg/m3 CEILING OSHA-vacated 50 ppm CEILING OSHA – vacated 100 mg/m3 CEILING UCC Aerosol and Vapor Diethylene glycol 50 ppm TWA8 AIHA WEEL Aerosol and Vapor Diethylene glycol 10 mg/m3 TWA8 AIHA WEEL Aerosol In the Exposure Limits Chart above, if there is no specific qualifier Aerosol) listed in the Form Column for a particular limit, the listed limit includes all airborne forms of the substance that can be inhaled. A “blank” in the Skin column indicates that exposure by the cutaneous (skin) route is not a potential significant contributor to overall exposure. Page 568 of 878 Page 568 of 878 Page 568 of 878 Page 568 of 878 ---PAGE BREAK--- PEAK Antifreeze 6 9. PHYSICAL / CHEMICAL PROPERTIES Boiling Range: 171 - 175oC (339 - 348oF) Freeze Point: -18oC (0oF) Specific Gravity (Water 1.12 Pounds/Gallons: 9.3 Vapor Pressure (mm of Hg) @ 20C: <0.1 Vapor Density (air=1): 2.1 Water Solubility: Complete Evaporation Rate (BuAc = Nil % Volatile By Volume: 97.0 Appearance: Green Odor: Mild pH (50% Water Solution): 10.5-11.0 10. STABILITY & REACTIVITY DATA Stability: Stable Conditions to Avoid: Keep away from flame Incompatibility (Materials to Avoid): Strong acid or oxidizing agents Hazardous Decomposition Products: Incomplete combustion may produce CO gas Hazardous Polymerization: Will not occur 11. TOXICOLOGICAL INFORMATION Skin: The dermal LD50 has not been determined. Ingestion: The lethal dose in humans is estimated to be 100 ml (3 ozs.). The oral LD50 for rats is in the 6000- 13,000-mg/kg range. Mutagenicity (The Effects on Genetic Material): In vitro mutagenicity studies were negative. Animal mutagenicity studies were negative. Significant Data with Possible Relevance to Humans: Ethylene glycol has been shown to produce dose-related teratogenic effects in rats and mice when given by gavage or in drinking water at high concentrations or doses. The no-effect doses for developmental toxicity for ethylene glycol given by gavage over the period of organogenesis has been shown to be 150 mg/kg/day for the mouse and 500 mg/kg/day for the rat. Also, in a preliminary study to asses the effects of exposure of pregnant rats and made to aerosis at concentrations of 150, 1000 and 25000 mg/m3 for 6 hours a day throughout the period of organogenesis, teratogenic effects were produced at the highest concentration, but only in mice. The conditions of these latter experiments did not allow a conclusion as to whether the developmental toxicity was mediated by inhalation of aerosol percutaneous absorption of ethylene glycol from contaminated skin, or swallowing ethylene glycol as a result of grooming the wetted coat. In a further study, comparing effects from high aerosol concentration by whole-body or nose-only exposure, it was shown that nose- only exposure resulted in maternal toxicity (1000 and 25000 mg/m3) and developmental toxicity with minimal evidence of teratogenicity (2500 mg/m3). The no-effects concentration (based on maternal toxicity) was 500 mg/m3. In a further study in mice, no teratogenic effects could be produced when ethylene glycol was applied to skin of pregnant mice over the period of organogenesis. The above observations suggest that ethylene glycol is to be regarded as an animal teratogen. There is currently no available information to suggest that ethylene glycol has caused birth defects in humans. Cutaneous application of ethylene glycol is ineffective in producing developmental Page 569 of 878 Page 569 of 878 Page 569 of 878 Page 569 of 878 ---PAGE BREAK--- PEAK Antifreeze 7 toxicity. Exposure to high aerosol concentrations is only minimally effective in producing developmental toxicity. The major route for producing developmental toxicity is perorally. Two chronic feeding studies, using rats and mice, have not produced any evidence that ethylene glycol causes dose-related increases in tumor incidence or a different pattern of tumors compared with untreated controls. The absence of carcinogenic potential for ethylene glycol has been supported by numerous in vitro genotoxicity studies showing that it does not produce mutagenic or clastogenic effects. A chronic dietary feeding study of diethylene glycol with rats showed mild kidney injury at while concentrations of 2% and 4% caused more marked kidney injury. In addition, at 2% and 4% of diethylene glycol in the diet, some rats developed benign papillary tumors in the urinary bladder. These have been attributed to the presence of urinary bladder calcium oxalate stones. No evidence for carcinogenicity was found with a chronic skin- painting study with diethylene glycol in mice. The absence of a direct chemical carcinogenic effect addords with the results in vitro genotoxicity studies that show that it does not produce mutagenic or clastogenic effects. A feeding study employing up to 5.0% diethylene glycol in the diet failed to produce any teratogenic effects. In a mouse continuous breeding study with large doses of diethylene glycol in drinking water, there was evidence for reproductive toxicity at 3.5% (equivalent to 6.1 g/kg/day) as reduced number of litter, live pups per litter and live pup weight. No such effects were seen at 1.75% (approximately 3.05 g/kg/day). The relevance of these very high dosages to human health is uncertain. Pregnant rats receiving undiluted diethylene glycol by gavage over the period of organogenesis had toxic effects at 4.0 and 8.0 ml/kg/day as mortality, decreased body weight, decreased food consumption increased water consumption and increased liver and kidney weights. Fetotoxicity was seen only at these maternally toxic dosages. Decreased fetal body weight occurred at 8.0 ml/kg/day, and increased skeletal variants at 4.0 and 8.0 ml/kg/day. No embryotixic or teratogenic effects were seen. Neither maternal toxicity nor fetotoxicity occurred at 1.0 ml/kg/day. In a study with mice also receiving undiluted diethylene glycol over the period of organogenesis, maternal toxicity occurred at 2.5 and 10.0 ml/kg/day, but not at 0.5 ml/kg/day. Definitive developmental toxicity was not seen in this species. ACUTE TOXICITY Peroral: The lethal dose in humans is estimated to be 3 oz. or 100 ml. Rat: LD50 (6000 – 13000) mg/kg Percutaneous: Rabbit: LD50 = >22270 mg/kg; 24 h occluded Inhalation: Rat: 8-hour exposure, substantially saturated vapor studies, dynamic generation method Mortality: 0/6 Inhalation: Mist/vapor study, rat, at 170°C, 8-hour exposure = 2.2 mg/l Mortality: 0/6 Inhalation: Rat: 8-hour exposure, fog = 10000 ppm; 65° - 70°C Mortality: 0/6 Page 570 of 878 Page 570 of 878 Page 570 of 878 Page 570 of 878 ---PAGE BREAK--- PEAK Antifreeze 8 IRRITATION Skin: Rabbit: 24-hour occluded contact, 0.5 ml Results: Minor erythema and edema Skin: Human: Primary irritation patch test, 48-hour occluded, 0.2 ml Results: Evidence of irritation Eye: Rabbit: 0.1 ml Results: Minor transient iritis, conjunctival irritation with discharge REPEATED EXPOSURE In a 7-day dietary study with rats, a significant increase in kidney weights in females was observed at 5.0 gm/kg. The NOEL was 2.5 gm/kg. In a 24-month dietary study with rats, increased mortality in males was observed at the highest dose, 1.0 gm/kg/day. There were multiple signs: mineralization of several organs, including the cardiac vessels, cardiac muscle, vas deferens, stomach and pulmonary vessels; cellular hyperplasia of the parathyroids, hemosiderosis of the spleen, myocardial fibrosis, portal fibrosis of the liver, bile duct hyperplasia and hydronephrosis and oxylate nephrosis of the kidneys. Ethylene glycol was not oncogenic. In a 90-day dietary study with dogs, repeated exposures to 2.5 gm/kg resulted in acute renal failure and deaths. The NOAEL was 1.0 gm/kg. SENSITIZATION (ANIMAL AND HUMAN STUDIES) Repeated skin contact with ethylene glycol may, in a very small proportion of cases, cause sensitization with the development of allergic contact dermatitis. The incidence is significantly less than 1% with the undiluted material. REPRODUCTIVE TOXICITY A three-generation study indicated that ethylene glycol did not affect reproductive parameters at dietary concentrations up to 1.0 gm/kg/day in any generation. CHRONIC TOXICITY AND CARCINOGENICITY Two chronic feeding studies, using rats and mice, have not produced any evidence that ethylene glycol causes dose- related increases in tumor incidence or a different pattern of tumors compared with untreated controls. The absence of a carcinogenic potential for ethylene glycol has been supported by numerous in vitro genotoxicity studies showing that it does not produce mutagenic or clastogenic effects. GENETIC TOXICOLOGY In Vitro: Ethylene glycol was devoid of genotoxic activity in an Ames test, forward gene mutation and sister chromatid exchange (SCE) studies in Chinese Hamster Ovary (CHO) cells and an in vitro cytogenetics study. Page 571 of 878 Page 571 of 878 Page 571 of 878 Page 571 of 878 ---PAGE BREAK--- PEAK Antifreeze 9 In Vivo: Ethylene glycol by three different routes (intravenous, peroral and percutaneous) demonstrates apparent first-order pharmacokinetic behavior for the disposition in and the elimination from the plasma. Dose-dependent changes occur for the elimination of metabolites in the urine and as 14CO2 after single doses for the intravenous and peroral, but not the percutaneous route. The hypothesis from literature sources exists that developmental toxicity is caused by a metabolite of ethylene glycol, called glycolic acid, and not parent ethylene glycol. Under most conditions of ethylene glycol exposure, the glycolic acid metabolite is present in the blood in very low levels. However, it can become the major metabolite following large doses of ethylene glycol due to saturation of glycolic acid oxidation and/or elimination. When levels of this acidic metabolite exceed the capacity of maternal blood buffers to neutralize it, a maternal metabolic acidosis ensues, which has been hypothesized to be the true agent responsible for ethylene glycol induced developmental toxicity. Research suggests that ethylene glycol developmental toxicity is due to a dose-rate dependent toxicokinetic shift leading to glycolate accumulation and metabolic acidosis. ADDITIONAL STUDIES Ethylene glycol has been shown to produce dose-related teratogenic effects in rats and mice when given by gavage or in drinking water at high concentrations or doses. The no-effect doses for developmental toxicity for ethylene glycol given by gavage over the period of organogenesis has been shown to be 150 mg/kg/day for the mouse and 500 mg/kg/day for the rat. Also, in a preliminary study to assess the effects of exposure of pregnant rats and mice to aerosols at concentrations of 150, 1000 and 2500 mg/m3 for 6 hours a day throughout the period of organogenesis, teratogenic effects were produced at the highest concentration, but only in mice. The conditions of these latter experiments did not allow a conclusion as to whether the developmental toxicity was mediated by inhalation of aerosol, percutaneous absorption of ethylene glycol from contaminated skin, or swallowing of ethylene glycol as a result of grooming the wetted coat. In a further study, comparing effects from high aerosol concentration by whole-body or nose-only exposure, it was shown that nose-only exposure resulted in maternal toxicity (1000 and 2500 mg/m3) and developmental toxicity with minimal evidence of teratogenicity (2500 mg/m3). The no-effects concentration (based on maternal toxicity) was 500 mg/m3. In a further study in mice, no teratogenic effects could be produced when ethylene glycol was applied to the skin of pregnant mice over the period of organogenesis. The above observations suggest that ethylene glycol is to be regarded as an animal teratogen. There is currently no available information to suggest that ethylene glycol has caused birth defects in humans. Cutaneous application of ethylene glycol is ineffective in producing developmental toxicity. Exposure to high aerosol concentrations is only minimally effective in producing developmental toxicity. 12. ECOLOGICAL INFORMATION ENVIRONMENTAL FATE Movement & Partitioning: Bioconcentration potential is low (BCF less than 100 or Log Kow less than Log octanol/water partition coefficient (log Kow) is -1.36. Henry's Law Constant is 6.0E-08 atm-m3/mol. Bioconcentration factor (BCF) is 10 in golden orfe. Degradation & Transformation: Biodegradation under aerobic static laboratory conditions is high (BOD20 or BOD28/ThOD greater than 40%). 5-Day biochemical oxygen demand (BOD5) is 0.78 p/p. 10-Day biochemical oxygen demand (BOD10) is 1.06 p/p. 20-Day biochemical oxygen demand (BOD20) is 1.15 p/p. Theoretical oxygen demand (THOD) is calculated to be 1.29 p/p. Biodegradation may occur under both aerobic and anaerobic conditions (in either the presence or absence of oxygen). Inhibitory concentration (IC50) in OECD "Activated Sludge, Respiration Inhibition Test" (Guideline # 209) is < 1000 mg/L. Degradation is expected in the atmospheric environment within days to weeks. Page 572 of 878 Page 572 of 878 Page 572 of 878 Page 572 of 878 ---PAGE BREAK--- PEAK Antifreeze 10 Ecotoxicology: Material is practically non-toxic to aquatic organisms on an acute basis (LC50 greater than 100 mg/L in most sensitive species). Acute LC50 for fathead minnow (Pimephales promelas) is 51000 mg/L. Acute LC50 for bluegill (Lepomis macrochirus) is 27549 mg/L. Acute LC50 for rainbow trout mykiss) is about 18000-46000 mg/L. Acute LC50 for guppy (Poecilia reticulata) is 49300 mg/L. Acute LC50 for water flea (Daphnia magna) is 46300-51100 mg/L. Acute LC50 for the cladoceran Ceriodaphnia dubia is 10000-25800 mg/L. Acute LC50 for crayfish is 91430 mg/L. Acute LC50 for brine shrimp (Artemia salina) is 20000 mg/L. Acute LC50 for golden orfe (Leuciscus idus) is greater than 10000 mg/L. Acute LC50 for goldfish (Carassius auratus) is greater than 5000 mg/L. Growth inhibition EC50 for green alga Selenastrum capricornutum is 9500-13000 mg/L. BOD Oxygen Consumption): Day 5 Day 10 Day 15 Day 20 Day 30 51% 80% 97% ECOTOXICITY Toxicity to Micro-organisms: Bacterial / NA: 16 h; IC50 Result Value: >10000 mg/l Toxicity to Aquatic Invertebrates: Daphnia: 48 h; LC50 Result Value: >100000 mg/l Toxicity to Fish Fathead Minnow: 94 h; LC50 Result Value: 70000 mg/l FURTHER INFORMATION Chemical Oxygen Demand (COD) – Measured: 1.29 mg/mg Theoretical Oxygen Demand (THOD) – Calculated: 1.30 mg/mg Octanol/Water Partition Coefficient – Measured: -1.36 13. DISPOSAL CONSIDERATIONS DO NOT discharge to sewer. Wear appropriate personal protection. Take up with sand, vermiculite, or similar inert material. Dispose in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION Non-Bulk Not regulated by the US D.O.T. (in quantities under 5,000 lbs in any one inner package) Page 573 of 878 Page 573 of 878 Page 573 of 878 Page 573 of 878 ---PAGE BREAK--- PEAK Antifreeze 11 Bulk Proper Shipping Name: Environmentally Hazardous Substance, LIQUID N.O.S. (ETHYLENE GLYCOL) Technical Name: ETHYLENE GLYCOL ID Number: UN 3082 Hazard Class: 9 Packing Group: PG III Reportable Quantity: 5,000 lb. IATA Non-Bulk Not Regulated by IATA IMDG Non-Bulk Not regulated by IMDG (in quantities under 5,000 lbs in any one inner package) 15. REGULATORY INFORMATION THIS PRODUCT CONTAINS COMPONENT(S) CITED ON THE FOLLOWING REGULATIONS. Chemical Name Cas Number Ethylene Glycol 107-21-1 United States - TSCA Inventory: Listed Water Standards: No data available Atmospheric Standards: Clean Air Act (1990) - List of Hazardous Air Contaminants: listed CERCLA: Reportable Quantity (RQ): 5,000 pounds (532 gallons) OSHA Hazard Communication Standard: This product is a “hazardous chemical” as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. SARA Title III: Section 311/312 - Categories: Acute hazard; chronic hazard Section 312 - Inventory Reporting: Ethylene glycol is subject to Tier I and/or Tier II annual inventory reporting. Section 313 - Emission Reporting: Ethylene glycol is subject to Form R reporting requirements. Section 302 - Extremely Hazardous Substances: Ethylene glycol is not listed. Page 574 of 878 Page 574 of 878 Page 574 of 878 Page 574 of 878 ---PAGE BREAK--- PEAK Antifreeze 12 State Right-To-Know: California - Exposure Limits - Ceilings: vapor-50 ppm ceiling; 125 mg/m3 ceiling Director's List of Hazardous Substances: listed Florida - Hazardous Substances List: listed Massachusetts - Right-to-Know List: listed Minnesota - Haz. Subs. List: listed (particulate and vapor) New Jersey - Right-to-Know List (Total): Present greater than 1.0% Right-to-Know List: environmental hazard Canadian Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required. WHMIS Information: D2A - material has potential toxic effects. Refer elsewhere in the MSDS for specific warnings and safe handling information. Refer to the employer's workplace education program. California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986): The normal consumer use of this product does not result in exposure to chemicals known to the state of California to cause Cancer and/or reproductive harm above the significant risk level for carcinogens or the maximum allowable dose levels for reproductive toxins. Warnings are not required for consumer packaging. However, industrial or other occupational use of this product at higher frequency and using larger quantities of this product may result in exposures exceeding these levels and are labeled accordingly. California SCAQMD Rule 443.1 (South Coast Air Quality Management District Rule 443.1, Labeling of Materials Containing Organic Solvents): VOC: Vapor pressure 0.06 mmHg at 20°C 1113.38 g/l 16. OTHER INFORMATION Contact: Thomas Cholke Phone: (847) 559-2225 Old World Industries, Inc. makes no warranty, representation or guarantee as to the accuracy, sufficiency or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity and suitability of his own use, handling and disposal of this product. Since actual use by others is beyond our control, no warranty, expressed or implied, is made by Old World Industries, Inc. as to the effects of such use, the results to be obtained or the safety and toxicity of this product, nor does Old World Industries, Inc. assume liability arising out of the use by others of this product referred to herein. The data in this MSDS relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Page 575 of 878 Page 575 of 878 Page 575 of 878 Page 575 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET (COMPLIES WITH 29CFR 1910.1200) SECTION I - CHEMICAL PRODUCT & COMPANY IDENTIFICATION Identity (As Used on Label and List): Pearl Soft Lotion Hand Cleaner Product Class: Soap solution Emergency Telephone Number: [PHONE REDACTED] Telephone Number for Information: [PHONE REDACTED] Distributed By: Dalco 300 5th Ave NW New Brighton, Minnesota 55112 SECTION II - COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Components (Specific Chemical Identity): Chemical Common Name(s) % A Sodium Laureth Sulfate & 2 - 8 Alkyl Blend B Sodium Lauryl Sulfate 2 - 8 CAS #68585-47-7 C Lauramide DEA (mixture) .5 - 2 D Cocamidopropyl Betaine .5 - 2 CAS #61789-400 E Sodium Chloride 1 - 5 CAS #7647-14-5 C Water 75 - 100 CAS #7732-18-5 SECTION III - HAZARDS IDENTIFICATION Emergency Overview Appearance and Odor: Pink, opaque liquid,coconut fragrance. Primary Hazards: No effects expected. Potential Health Hazards Route(s) of Entry: Skin Absorption: Ingestion: X Inhalation: Eye: May cause eye irritation on contact. Skin: No effects expected. Ingestion: May be harmful if swallowed. Inhalation: No hazardous vapors. Signs and of Exposure: May cause irritation to eyes on direct contact. Carcinogenicity: NTP? No IARC Monographs? No OSHA Regulated? No Target Organ No additional data Medical Conditions Generally Aggravated by Exposure: Dermatitis Health Hazards, Chronic: N. Av. SECTION IV - FIRST AID MEASURES Emergency and First Aid Procedures: If Swallowed: If a person can swallow, give several glasses of water. Obtain immediate medical attention. Eye Contact: Flush eyes with running water for at least 15 minutes. If irritation persists, obtain medical attention. Skin Contact: If irritation develops, discontinue use. For Inhalation: Remove to fresh air. If irritation persists, get medical attention. Sources Used: Raw material data, general toxicology from the trade for similar products. SECTION V - FIRE FIGHTING MEASURES Flammability: No Autoignition Temperature: N. Ap. Flash Point (method used): None Flammable Limits: N. Ap. LEL UEL Extinguishing Media N. Ap. Water? Foam? Water Fog? Alcohol Foam? CO2? Dry Chemical? Vaporizing Liquid? Other? Special Fire Fighting Procedures: N. Ap. Unusual Fire and Explosion Hazards: N. Av. TDG Flammability Classification: Non-flammable Sensitivity to Mechanical Impact: None Sensitivity to Static Discharge: None SECTION VI - ACCIDENTAL RELEASE MEASURES Steps to be Taken in Case Material is Released or Spilled: Dike and contain spill with inert material (sand, earth, etc). Collect spill with mop, absorbent material (example: floor-dri) or vacuum. Thoroughly rinse affected area with water. SECTION VII - HANDLING AND STORAGE Precautions to be Taken in Handling and Storing: Normal care in handling and storage. Other Precautions: Keep out of reach of children. Keep from freezing. SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION Respiratory Protection (Specify Types): Not required Ventilation: Local Exhaust: Not required Special: Not required Mechanical (General): Not required Other: Not required Protective Gloves: Not required Eye Protection: Approved safety goggles or glasses. Footwear: Not required Other Protective Clothing or Equipment: Not required Work/Hygienic Practices: Do not contaminate food or beverages with cleaning chemicals. SECTION IX - PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: Approximately 212°F pH: 7 - 8 Specific Gravity (H20) = 1: 1.027 Volatile: > 85 Vapor Density (Air = N. Av. Odor Threshold: N. Av. Evaporation Rate (Butyl Acetate = N. Av. Oil/Water Distribution Solubility in Water: Complete Coefficient: N. Av. Vapor Pressure (MM HG): N. Av. Melting Point: N. Ap. SECTION X - STABILITY AND REACTIVITY Stability: Unstable: Stable: X Conditions to Avoid: N. Ap. Incompatibility (materials to avoid): N. Av. Hazardous Decomposition or By-products: N. Av. Hazardous Polymerization: May occur: Will not occur: X Conditions to Avoid: N. Ap. SECTION XI - TOXICOLOGICAL INFORMATION Chemical OSHA PEL ACGIH TLV Recom. LD50 LC50 A N. Ap. N. Ap. N. Av. N. Av. N. Av. B N. Ap. N. Ap. N. Av. <5 ml/kg N. Av. (rat, oral) C N. Ap. N. Ap. N. Av. N. Av. N. Av. D N. Ap. N. Ap. N. Av. N. Av. N. Av. E N. Ap. N. Ap. N. Av. N. Av. N. Av. F N. Ap. N. Ap. N. Ap. N. Ap. N. Ap. Teratogen, Mutagen, Reproductive Toxin Status: No Toxicologically Synergistic Products: N. Av. SECTION XII - ECOLOGICAL INFORMATION Ecotoxicological Information: N. Av. Chemical Fate Information: N. Av. SECTION XIII - DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose of spilled material in accordance with local, state and federal regulations. Waste from normal cleaning procedures may be sewered, depending on the materials and/or contaminates being cleaned as well as state, federal and local sewer commission regulations. RCRA Hazard Class: None SECTION XIV - TRANSPORT INFORMATION Shipping Classification: Compound, cleaning liquid, N.O.I. UN Number: N. Ap. Packing Group: N. Ap. SECTION XV - PREPARATION DATA Prepared By: Mike Elms Telephone Number: [PHONE REDACTED] Date: 1/02 SECTION XVI - REGULATORY INFORMATION US Federal Regulations TSCA Status: All ingredients listed. CERCLA Reportable Quality: None SARA Title III Section 302 Extremely Hazardous Chemicals: None Section 311/312 Hazard Category: None Section 313 Toxic Chemicals: Diethanolamine State Regulations NOTICE STATE OF CALIFORNIA Warning: This product may contain chemicals known to the State of California to cause cancer or reproductive defects as trace impurities in the standard industrial materials used in the manufacture of this product. International Regulations WHMIS Controlled Product Hazard Class: N. Ap. SECTION XVII - OTHER INFORMATION None N. Ap. - Not Applicable; N.Av. - Not Available NFPA SYSTEM A. Health Hazard A. Fire Hazard A. Reactivity Hazard THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE, HOWEVER NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. MINUTEMAN INTERNATIONAL, INC. ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE TO VENDEES, USERS OR THIRD PARTIES CAUSED BY THE MATERIAL. SUCH VENDEES OR USERS ASSUME ALL RISKS ASSOCIATED WITH THE USE OF THE MATERIAL. 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CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product code 52812 Product name PowrOff Contact Cleaner Recommended Use Cleaner Supplier Lawson Products, Inc. 1666 East Touhy Avenue Des Plaines, IL 60018 (847)-827-9666 Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known. Principal Routes of Exposure Inhalation. Eyes. Skin contact. Potential health effects Eyes Irritation. Redness. Itching. Burning sensation. Skin Repeated or prolonged exposure may cause:. Skin Irritation. Redness. Itching. Burning sensation. Inhalation Repeated or prolonged exposure may cause the following effects. Headaches. Dizziness. Nausea. Upper respiratory tract irritation. Central nervous system effects. Loss of coordination. Extreme overexposure may cause. Possible unconsciousness. Death. Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Ingestion May be harmful if swallowed. 3. COMPOSITION/INFORMATION ON INGREDIENTS Page 1 / 7 Emergency Overview Flammable. Irritant. May be harmful if swallowed. Form Aerosol Color Colorless Odor Solvent Page 595 of 878 Page 595 of 878 Page 595 of 878 Page 595 of 878 ---PAGE BREAK--- Product code 52812 Product name PowrOff Contact Cleaner Chemical Name CAS-No Weight % Toluene 108-88-3 1-5 Cyclohexane 110-82-7 5-10 Ethyl alcohol 64-17-5 7-13 Isopropyl alcohol 67-63-0 7-13 Propane 74-98-6 10-30 Heptanes 142-82-5 30-60 4. FIRST AID MEASURES Eye contact Flush with plenty of water for at least 15 minutes. Seek medical attention. Skin contact Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. Ingestion Do not induce vomiting. Immediate medical attention is required. Inhalation Remove from exposure. Restore breathing. Keep warm and quiet. Contact physician if breathing difficulty develops. 5. FIRE FIGHTING MEASURES Flash point °C < -29 Flash point °F < -20 Method Pensky-Martens C.C. Autoignition temperature °C Not Applicable Autoignition temperature °F Not Applicable Flammability Limits in Air) Upper 19.0 Lower 1.0 Suitable extinguishing media Carbon dioxide (CO2). Dry chemical. Foam. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fire and Explosion Hazards During emergency conditions, overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat . Water spray may be ineffective. If water is used, fog nozzles are preferable. In the event of fire and/or explosion do not breathe fumes. Avoid skin and eye contact. Keep product and empty container away from heat and sources of ignition. 6. ACCIDENTAL RELEASE MEASURES Page 2 / 7 Sensitivity to static discharge No information available. Sensitivity to shock No information available. Page 596 of 878 Page 596 of 878 Page 596 of 878 Page 596 of 878 ---PAGE BREAK--- Product code 52812 Product name PowrOff Contact Cleaner Methods for cleaning up Eliminate all sources of ignition. Ventilate area to maintain exposure below permissible exposure limits. Soak up with inert absorbent material. 7. HANDLING AND STORAGE Handling Keep in a well-ventilated place. Turn off other sources of ignition prior to use and until all vapors have dissipated. Vapors may accumulate readily and may ignite explosively. Remove all sources of ignition. Keep away from open flame. Do not smoke. Check to make sure that all equipment is properly grounded and installed to satisfy electrical classification requirements. Contents under pressure. Do not puncture or incinerate. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of reach of children. Storage Store in temperatures below 120 degrees F. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Heptanes 2000 mg/m³ 500 ppm - 400 ppm 500 ppm Propane 1000 ppm 1800 mg/m³ - 1000 ppm 1000 ppm listed under aliphatic hydrocarbon gases alkane C1-C4 - Ethyl alcohol 1000 ppm 1900 mg/m³ - 1000 ppm - Isopropyl alcohol 400 ppm 980 mg/m³ - 200 ppm 400 ppm Cyclohexane 1050 mg/m³ 300 ppm - 100 ppm - Toluene 200 ppm 300 ppm 50 ppm - Ventilation and Environmental Controls Adequate ventilation should be provided to keep exposure levels below current acceptable exposure limits. Local: recommended. General: as necessary. Hygiene measures Wash hands before breaks and immediately after handling the product. Other precautions Avoid contact with the skin and the eyes Personal protective equipment Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Wear a NIOSH approved organic vapor/particulate respirator. Hand Protection Gloves are not required in normal use. The following glove(s) are recommended to prevent prolonged or repeated contact:. Chemical resistant gloves. Page 3 / 7 Page 597 of 878 Page 597 of 878 Page 597 of 878 Page 597 of 878 ---PAGE BREAK--- Product code 52812 Product name PowrOff Contact Cleaner Eye protection Wear safety glasses with side shields. Skin and body protection None necessary under normal conditions 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid None known. Incompatability None known . Hazardous Decomposition Products Carbon dioxide. Carbon monoxide. Polymerization Hazardous polymerization does not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat) LD50 (dermal,rat/rabbit) LC50 (inhalation,rat) Heptanes 142-82-5 - - 103 g/m3 Propane 74-98-6 - 658 mg/kg - Ethyl alcohol 64-17-5 1501 mg/kg - 124.7 mg/L Page 4 / 7 Color Vapor pressure 272mmHg @68°F Colorless Vapor density >1 (Air = 1) Evaporation Rate >1 (ether = 1) Odor VOC Content 5.56 lbs/gal Solvent Water solubility Negligible Form Partition Coefficient (n-octanol/water) Not Applicable Odor Threshold Not Applicable Boiling point/range °C -18 - 114 Aerosol Boiling point/range °F 0 - 238 pH Melting point/range °C Not Applicable Not Applicable Melting point/range °F Not Applicable Flash point °C < -29 Specific Gravity Flash point °F < -20 0.67 Page 598 of 878 Page 598 of 878 Page 598 of 878 Page 598 of 878 ---PAGE BREAK--- Product code 52812 Product name PowrOff Contact Cleaner Isopropyl alcohol 67-63-0 4396 mg/kg 12800 mg/kg 12800 mg/kg 72.6 mg/L Cyclohexane 110-82-7 5000 mg/kg 2000 mg/kg 13.9 mg/L Toluene 108-88-3 636 mg/kg 8390 mg/kg 12.5 mg/L 26700 ppm Synergistic Products None known Potential health effects Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinogens IARC NTP - Known Carcinogens NTP - Suspected Human Carcinogens OSHA RTK Carcinogens Heptanes Not Listed Not Listed Not Listed Not Listed Not Listed Propane Not Listed Not Listed Not Listed Not Listed Not Listed Ethyl alcohol A4 - Not Classifiable as a Human Carcinogen Not Listed Not Listed Not Listed Not Listed Isopropyl alcohol A4 - Not Classifiable as a Human Carcinogen Not Listed Not Listed Not Listed Listed Cyclohexane Not Listed Not Listed Not Listed Not Listed Not Listed Toluene A4 - Not Classifiable as a Human Carcinogen Not Listed Not Listed Not Listed Not Listed Specific Hazards Reports have associated repeated and prolonged occupational exposure to solvents with permanent brain damage. 12. ECOLOGICAL INFORMATION Page 5 / 7 Reproductive toxicity None known Target Organ Effects None Known Chronic toxicity Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous . Mutagenic effects None known Sensitization None known Teratogenic effects None known Page 599 of 878 Page 599 of 878 Page 599 of 878 Page 599 of 878 ---PAGE BREAK--- Product code 52812 Product name PowrOff Contact Cleaner 13. DISPOSAL CONSIDERATIONS Disposal Information As supplied, this product is a RCRA Hazardous Waste . Waste must be tested for ignitability to determine EPA hazardous waste numbers. Do not puncture or incinerate. Depressurize before disposal. Waste from residues / unused products Dispose in accordance with federal, state, and local regulations. 14. TRANSPORT INFORMATION DOT UN1950 Aerosols, flammable (Heptane/Propane/Cyclohexane), Class 2.1 Exception: (Flammable Liquids PG II not more than 1.0L) Consumer Commodity ORM-D TDG UN1950 AEROSOLS, flammable (Heptane/Propane/Cyclohexane), Class 2.1 IMDG/IMO UN1950 AEROSOLS (Heptane/Propane/Cyclohexane), Class 2.1 IATA UN1950 Aerosols, flammable (Heptane/Propane/Cyclohexane), Class 2.1 MEX UN1950 AEROSOLES (Heptane/Propane/Cyclohexane), 2.1 Page 6 / 7 Toluene Microtox Data Photobacterium phosphoreum EC50=19.7 mg/L (30 min) Microtox Data Photobacterium phosphoreum EC50=35390 mg/L (5 min) Water Flea Data water flea EC50=11.3 mg/L (48 h) water flea EC50=310 mg/L (48 h) Cyclohexane Microtox Data Photobacterium phosphoreum EC50=34634 mg/L (30 min) Photobacterium phosphoreum EC50=35470 mg/L (5 min) Microtox Data Photobacterium phosphoreum EC50=85.5 mg/L (5 min) Photobacterium phosphoreum EC50=93 mg/L (10 min) Ethyl alcohol Water Flea Data water flea EC50=400.0 mg/L (48 h) Isopropyl alcohol Page 600 of 878 Page 600 of 878 Page 600 of 878 Page 600 of 878 ---PAGE BREAK--- Product code 52812 Product name PowrOff Contact Cleaner 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Isopropyl alcohol Listed Cyclohexane Listed Toluene Listed Chemical Name New Jersey - RTK - RTK California Prop. 65 Heptanes Listed Listed Not Listed Propane Listed Listed Not Listed Ethyl alcohol Listed Listed Developmental Isopropyl alcohol Listed Listed Listed Not Listed Cyclohexane Listed Listed Not Listed Toluene Listed Listed Developmental Chemical Name EINECS DSL NDSL TSCA Heptanes X X - X Propane X X - X Ethyl alcohol X X - X Isopropyl alcohol X X - X Cyclohexane X X - X Toluene X X - X CPRC This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION Prepared By Michael Katz, Regulatory Affairs Specialist The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 7 / 7 HMIS NFPA - Flammability - Health 2 Health Flammability 4 Reactivity - Physical Hazard 0 Page 601 of 878 Page 601 of 878 Page 601 of 878 Page 601 of 878 ---PAGE BREAK--- Page 602 of 878 Page 602 of 878 Page 602 of 878 Page 602 of 878 ---PAGE BREAK--- Page 603 of 878 Page 603 of 878 Page 603 of 878 Page 603 of 878 ---PAGE BREAK--- Page 604 of 878 Page 604 of 878 Page 604 of 878 Page 604 of 878 ---PAGE BREAK--- Page 605 of 878 Page 605 of 878 Page 605 of 878 Page 605 of 878 ---PAGE BREAK--- Page 606 of 878 Page 606 of 878 Page 606 of 878 Page 606 of 878 ---PAGE BREAK--- PROTEIN SPOTTER 4195 Industrial/Institutional: Carpet care. 04/19/2000 04/20/2000 Material Safety Data Sheet Product Name Product Use Validation Date Print Date In Case of Emergency Section 1. Chemical Product and Company Identification Supersedes 04/12/2000. Health 1 0 0 Fire Hazard Reactivity Specific Hazard Health Fire Hazard Reactivity Protective Clothing 0 0 1 (800) 851-7145 Johnson Wax Professional 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249 MSDS Internet Address: www.jwp.com U.S. Headquarters Johnson Wax Professional 100 Matheson Blvd. East, Suite 203 Mississauga, Ontario L4Z 2G7 Phone: (905) 755-0913 or (888) 746-5971 Hazardous Material Information System (HMIS) National Fire Protection Association (NFPA) Code MSDS# 126334001 432304 Canadian Headquarters Clear Yellow. Liquid. See Section 9. CAUTION: May be mildly irritating to eyes. May be mildly irritating to skin. Emergency Overview None required. PMS# PROTEIN SPOTTER Alkoxylated Linear Alcohols 1-5 Not available. Not available. Propylene Glycol 57-55-6 30-60 Not available. ORAL (LD50): Acute: 20000 mg/kg [Rat]. DERMAL (LD50): Acute: 20800 mg/kg [Rabbit]. Water 7732-18-5 60-100 Not available. Not available. Section 2. Composition and Information on Ingredients Ingredients CAS # % by Weight Exposure Limits LC50/LD50 Inhalation. Skin contact. Eye contact. Medical Conditions Aggravated by Overexposure: Persons with pre-existing sensitivity to enzymes may be more susceptible to allergic reaction. Section 3. Hazards Identification Routes of Entry Potential Acute Health Effects None known. May be mildly irritating to eyes. None known. May be mildly irritating to skin. Eyes Skin Inhalation Ingestion See Toxicological Information (section 11) No specific first aid measures are required. Flush immediately with plenty of water. Get medical attention if irritation occurs. Flush immediately with plenty of water. Get medical attention if irritation occurs. No specific first aid measures are required. Section 4. First Aid Measures Eye Contact Skin Contact Inhalation Ingestion Continued on Next Page Page: 1/3 Page 607 of 878 Page 607 of 878 Page 607 of 878 Page 607 of 878 ---PAGE BREAK--- Material Safety Data Sheet PROTEIN SPOTTER None known. None known. Not available. Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire fighting procedure may be used. None known. Section 5. Fire Fighting Measures Flammability of the Product Flash Points Products of Combustion Fire Fighting Media and Instructions Special Remarks on Fire and Explosion Hazards In the event of major spillage: Use appropriate containment to avoid environmental contamination. Sweep or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a water rinse for final clean-up. Put on appropriate personal protective equipment (see Section Section 6. Accidental Release Measures Personal Precautions Environmental Precautions and Clean-up Methods Do not use with sprayer. Wash thoroughly after handling. Store in a dry, cool and well-ventilated area. Protect from freezing. Product residue may remain on/in empty containers. All precautions for handling the product must be used in handling the empty container and residue. KEEP OUT OF REACH OF CHILDREN. Avoid contact with skin and eyes. FOR INDUSTRIAL USE ONLY Section 7. Handling and Storage Handling Storage No special ventilation requirements. General room ventilation is adequate. Section 8. Exposure Controls/Personal Protection Engineering Controls No special protective clothing is required. No special protective clothing is required. No special protective clothing is required. No special protective clothing is required. No special protective clothing is required. Personal Protection Eyes Hands Respiratory Feet Body Liquid. 5.8 [Acidic.] 1.03 Bland. Clear Yellow. Section 9. Physical and Chemical Properties Physical State and Appearance pH Specific Gravity Solubility in water Odor Color Complete. The product is stable. Not available. Will not occur. None known. None known. Section 10. Stability and Reactivity Stability and Reactivity Conditions of Instability Incompatibility with Various Substances Hazardous Decomposition Products Hazardous Polymerization Continued on Next Page Page: 2/3 Page 608 of 878 Page 608 of 878 Page 608 of 878 Page 608 of 878 ---PAGE BREAK--- Material Safety Data Sheet PROTEIN SPOTTER Section 11. Toxicological Information Effects of Chronic Exposure Other Toxic Effects None known. ORAL (LD50) Greater than 5000 mg/kg (rat). Acute toxicity Not available. Section 12. Ecological Information Not available. No special precautions. Dispose of according to all federal, state and local regulations. Waste Information Section 13. Disposal Considerations Section 14. Transport Information DOT Classification TDG Classification Not regulated Not regulated State Section 15. Regulatory Information Chemical Inventory Status US Regulations Canadian Regulations CLASS D-2B: Material causing other toxic effects (TOXIC). All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Registered Product Information This product is not subject to the reporting requirements under California's Proposition 65. Reporting in this section is based on ingredients disclosed in Section 2 WHMIS Classification WHMIS Icon RTK: Propylene Glycol Registered Product Information Not applicable. Not applicable. Not available. Section 16. Other Information Other Special Considerations Notice to Reader This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Version 1 Page 609 of 878 Page 609 of 878 Page 609 of 878 Page 609 of 878 ---PAGE BREAK--- SAFETY DATA SHEET PROVON® Enriched Lotion Cleanser Version 1.2 Revision Date: 02/10/2015 MSDS Number: 31606-00003 Date of last issue: 12/02/2014 Date of first issue: 11/24/2014 1 / 11 SECTION 1. IDENTIFICATION Product name : PROVON® Enriched Lotion Cleanser Manufacturer or supplier's details Company name of supplier : GOJO Industries, Inc. Address : One GOJO Plaza, Suite 500 Akron OH 44311 Telephone : 1 (330) 255-6000 Emergency telephone : 1-[PHONE REDACTED] CHEMTREC Recommended use of the chemical and restrictions on use Recommended use : Skin-care Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Not a hazardous substance or mixture. GHS Label element Not a hazardous substance or mixture. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous ingredients Chemical Name CAS-No. Concentration Alcohols, C10-16, ethoxylated, sulfates, sodium 68585-34-2 1 - < 5 Page 610 of 878 Page 610 of 878 Page 610 of 878 Page 610 of 878 ---PAGE BREAK--- SAFETY DATA SHEET PROVON® Enriched Lotion Cleanser Version 1.2 Revision Date: 02/10/2015 MSDS Number: 31606-00003 Date of last issue: 12/02/2014 Date of first issue: 11/24/2014 2 / 11 salts Cocoamidopropyl betaine 61789-40-0 1 - < 5 SECTION 4. FIRST AID MEASURES If inhaled : If inhaled, remove to fresh air. Get medical attention if occur. In case of skin contact : Wash with water and soap as a precaution. Get medical attention if occur. In case of eye contact : Flush eyes with water as a precaution. Get medical attention if irritation develops and persists. If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if occur. Rinse mouth thoroughly with water. Most important and effects, both acute and delayed : None known. Protection of first-aiders : No special precautions are necessary for first aid responders. Notes to physician : Treat and supportively. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2) Unsuitable extinguishing media : None known. Specific hazards during fire fighting : Exposure to combustion products may be a hazard to health. Hazardous combustion prod- ucts : Sulfur oxides Carbon oxides Metal oxides Chlorine compounds Nitrogen oxides (NOx) Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area. Page 611 of 878 Page 611 of 878 Page 611 of 878 Page 611 of 878 ---PAGE BREAK--- SAFETY DATA SHEET PROVON® Enriched Lotion Cleanser Version 1.2 Revision Date: 02/10/2015 MSDS Number: 31606-00003 Date of last issue: 12/02/2014 Date of first issue: 11/24/2014 3 / 11 Special protective equipment for fire-fighters : Wear self-contained breathing apparatus for firefighting if necessary. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Follow safe handling advice and personal protective equipment recommendations. Environmental precautions : Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for containment and cleaning up : Soak up with inert absorbent material. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements. SECTION 7. HANDLING AND STORAGE Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Local/Total ventilation : Use only with adequate ventilation. Advice on safe handling : Handle in accordance with good industrial hygiene and safety practice. Take care to prevent spills, waste and minimize release to the environment. Conditions for safe storage : Keep in properly labeled containers. Store in accordance with the particular national regulations. Materials to avoid : Do not store with the following product types: Strong oxidizing agents Page 612 of 878 Page 612 of 878 Page 612 of 878 Page 612 of 878 ---PAGE BREAK--- SAFETY DATA SHEET PROVON® Enriched Lotion Cleanser Version 1.2 Revision Date: 02/10/2015 MSDS Number: 31606-00003 Date of last issue: 12/02/2014 Date of first issue: 11/24/2014 4 / 11 SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Contains no substances with occupational exposure limit values. Hazardous components without workplace control parameters Ingredients CAS-No. Alcohols, C10-16, ethoxylated, sulfates, sodium salts 68585-34-2 Cocoamidopropyl betaine 61789-40-0 Engineering measures : Ensure adequate ventilation, especially in confined areas. Minimize workplace exposure concentrations. Dust formation may be relevant in the processing of this product. In addition to substance-specific OELs, general limitations of concentrations of particulates in the air at workplaces have to be considered in workplace risk assessment. Relevant limits include: OSHA PEL for Particulates Not Otherwise Regulated of 15 mg/m3 - total dust, 5 mg/m3 - respirable fraction; and ACGIH TWA for Particles (insoluble or poorly soluble) Not Otherwise Specified of 3 mg/m3 - respirable particles, 10 mg/m3 - inhalable particles. Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. Hand protection Remarks : Wash hands before breaks and at the end of workday. Eye protection : Wear the following personal protective equipment: Safety glasses Skin and body protection : Skin should be washed after contact. Hygiene measures : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. Page 613 of 878 Page 613 of 878 Page 613 of 878 Page 613 of 878 ---PAGE BREAK--- SAFETY DATA SHEET PROVON® Enriched Lotion Cleanser Version 1.2 Revision Date: 02/10/2015 MSDS Number: 31606-00003 Date of last issue: 12/02/2014 Date of first issue: 11/24/2014 5 / 11 SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Color : opalescent, pink Odor : floral Odor Threshold : No data available pH : 4.8 - 6.2 Melting point/freezing point : No data available Solidification / Setting point 2.9 °C Initial boiling point and boiling range : 97.00 °C Flash point : > 100 °C Evaporation rate : No data available Flammability (solid, gas) : Not applicable Upper explosion limit : No data available Lower explosion limit : No data available Vapor pressure : No data available Relative vapor density : No data available Density : 1.00 g/cm3 Solubility(ies) Water solubility : soluble Partition coefficient: n- octanol/water : Not applicable Autoignition temperature : No data available Decomposition temperature : The substance or mixture is not classified self-reactive. Viscosity Viscosity, kinematic : 3,000 - 16,000 mm2/s (20 Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. Page 614 of 878 Page 614 of 878 Page 614 of 878 Page 614 of 878 ---PAGE BREAK--- SAFETY DATA SHEET PROVON® Enriched Lotion Cleanser Version 1.2 Revision Date: 02/10/2015 MSDS Number: 31606-00003 Date of last issue: 12/02/2014 Date of first issue: 11/24/2014 6 / 11 SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reac- tions : Can react with strong oxidizing agents. Conditions to avoid : None known. Incompatible materials : Oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Ingredients: Alcohols, C10-16, ethoxylated, sulfates, sodium salts: Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg Assessment: The substance or mixture has no acute oral toxicity Cocoamidopropyl betaine: Acute oral toxicity : LD50: > 5,000 mg/kg Method: OECD Test Guideline 401 Remarks: Based on data from similar materials Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 402 Assessment: The substance or mixture has no acute dermal toxicity Remarks: Based on data from similar materials Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation Page 615 of 878 Page 615 of 878 Page 615 of 878 Page 615 of 878 ---PAGE BREAK--- SAFETY DATA SHEET PROVON® Enriched Lotion Cleanser Version 1.2 Revision Date: 02/10/2015 MSDS Number: 31606-00003 Date of last issue: 12/02/2014 Date of first issue: 11/24/2014 7 / 11 Ingredients: Alcohols, C10-16, ethoxylated, sulfates, sodium salts: Result: Skin irritation Serious eye damage/eye irritation Not classified based on available information. Product: Result: No eye irritation Ingredients: Alcohols, C10-16, ethoxylated, sulfates, sodium salts: Result: Irreversible effects on the eye Cocoamidopropyl betaine: Species: Rabbit Result: Irreversible effects on the eye Method: OECD Test Guideline 405 Remarks: Based on data from similar materials Respiratory or skin sensitization Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information. Product: Assessment: Does not cause skin sensitization. Ingredients: Cocoamidopropyl betaine: Test Type: Maximization Test (GPMT) Routes of exposure: Skin contact Species: Guinea pig Result: negative Remarks: Based on data from similar materials Germ cell mutagenicity Not classified based on available information. Ingredients: Cocoamidopropyl betaine: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative Remarks: Based on data from similar materials Genotoxicity in vivo : Test Type: Mammalian micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Ingestion Result: negative Page 616 of 878 Page 616 of 878 Page 616 of 878 Page 616 of 878 ---PAGE BREAK--- SAFETY DATA SHEET PROVON® Enriched Lotion Cleanser Version 1.2 Revision Date: 02/10/2015 MSDS Number: 31606-00003 Date of last issue: 12/02/2014 Date of first issue: 11/24/2014 8 / 11 Remarks: Based on data from similar materials Carcinogenicity Not classified based on available information. IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. Ingredients: Cocoamidopropyl betaine: Effects on fetal development : Test Type: Embryo-fetal development Species: Rat Application Route: Ingestion Method: OECD Test Guideline 414 Result: negative Remarks: Based on data from similar materials STOT-single exposure Not classified based on available information. STOT-repeated exposure Not classified based on available information. Repeated dose toxicity Ingredients: Cocoamidopropyl betaine: Species: Rat NOAEL: 250 mg/kg Application Route: Ingestion Exposure time: 90 d Method: OECD Test Guideline 408 Remarks: Based on data from similar materials Aspiration toxicity Not classified based on available information. Page 617 of 878 Page 617 of 878 Page 617 of 878 Page 617 of 878 ---PAGE BREAK--- SAFETY DATA SHEET PROVON® Enriched Lotion Cleanser Version 1.2 Revision Date: 02/10/2015 MSDS Number: 31606-00003 Date of last issue: 12/02/2014 Date of first issue: 11/24/2014 9 / 11 SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Ingredients: Cocoamidopropyl betaine: Toxicity to fish : LC50: > 1 - 10 mg/l Exposure time: 96 h Method: ISO 7346/2 Remarks: Based on data from similar materials Toxicity to bacteria : EC50: > 100 mg/l Method: OECD Test Guideline 209 Remarks: Based on data from similar materials Persistence and degradability Product: Biodegradability : Result: Biodegradable Ingredients: Alcohols, C10-16, ethoxylated, sulfates, sodium salts: Biodegradability : Result: Readily biodegradable. Cocoamidopropyl betaine: Biodegradability : Result: Readily biodegradable. Biodegradation: > 60 % Exposure time: 28 d Method: OECD Test Guideline 301 Remarks: Based on data from similar materials Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Page 618 of 878 Page 618 of 878 Page 618 of 878 Page 618 of 878 ---PAGE BREAK--- SAFETY DATA SHEET PROVON® Enriched Lotion Cleanser Version 1.2 Revision Date: 02/10/2015 MSDS Number: 31606-00003 Date of last issue: 12/02/2014 Date of first issue: 11/24/2014 10 / 11 SECTION 14. TRANSPORT INFORMATION International Regulation Not regulated as a dangerous good IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. Domestic regulation 49 CFR Not regulated as a dangerous good SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : No SARA Hazards SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. US State Regulations Right To Know Water 7732-18-5 70 - 90 % Alcohols, C10-16, ethoxylated, sulfates, sodium salts 68585-34-2 1 - 5 % Sodium chloride 7647-14-5 1 - 5 % New Jersey Right To Know Water 7732-18-5 70 - 90 % Alcohols, C10-16, ethoxylated, sulfates, sodium salts 68585-34-2 1 - 5 % Sodium chloride 7647-14-5 1 - 5 % Cocoamidopropyl betaine 61789-40-0 1 - 5 % Page 619 of 878 Page 619 of 878 Page 619 of 878 Page 619 of 878 ---PAGE BREAK--- SAFETY DATA SHEET PROVON® Enriched Lotion Cleanser Version 1.2 Revision Date: 02/10/2015 MSDS Number: 31606-00003 Date of last issue: 12/02/2014 Date of first issue: 11/24/2014 11 / 11 California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: AICS : All ingredients listed or exempt. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), NECSI (Taiwan), TSCA (USA) SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Sources of key data used to compile the Material Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen- cy, http://echa.europa.eu/ Revision Date : 02/10/2015 The information provided in this Safety Data Sheet is correct to the best of our knowledge, in- formation and belief at the date of its publication. The information is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provid- ed relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, un- less specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, in- cluding an assessment of the appropriateness of the SDS material in the user’s end product, if applicable. US / Z8 Flammability Health Instability 0 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 0 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 620 of 878 Page 620 of 878 Page 620 of 878 Page 620 of 878 ---PAGE BREAK--- Page 621 of 878 Page 621 of 878 Page 621 of 878 Page 621 of 878 ---PAGE BREAK--- Page 622 of 878 Page 622 of 878 Page 622 of 878 Page 622 of 878 ---PAGE BREAK--- Page 623 of 878 Page 623 of 878 Page 623 of 878 Page 623 of 878 ---PAGE BREAK--- Page 624 of 878 Page 624 of 878 Page 624 of 878 Page 624 of 878 ---PAGE BREAK--- Page 625 of 878 Page 625 of 878 Page 625 of 878 Page 625 of 878 ---PAGE BREAK--- Page 626 of 878 Page 626 of 878 Page 626 of 878 Page 626 of 878 ---PAGE BREAK--- Page 627 of 878 Page 627 of 878 Page 627 of 878 Page 627 of 878 ---PAGE BREAK--- Page 628 of 878 Page 628 of 878 Page 628 of 878 Page 628 of 878 ---PAGE BREAK--- Page 629 of 878 Page 629 of 878 Page 629 of 878 Page 629 of 878 ---PAGE BREAK--- Page 630 of 878 Page 630 of 878 Page 630 of 878 Page 630 of 878 ---PAGE BREAK--- Page 631 of 878 Page 631 of 878 Page 631 of 878 Page 631 of 878 ---PAGE BREAK--- Page 632 of 878 Page 632 of 878 Page 632 of 878 Page 632 of 878 ---PAGE BREAK--- Quaker State Advanced Durability SAE 5W-30 Motor Oil MSDS# 11878 Version 1.2 Material Safety Data Sheet Effective Date 03/13/2013 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 1/9 Print Date 04/24/2013 000000018029 MSDS_US 1. MATERIAL AND COMPANY IDENTIFICATION Material Name : Quaker State Advanced Durability SAE 5W-30 Motor Oil Uses : Engine oil. Manufacturer/Supplier : SOPUS Products PO BOX 4427 Houston, TX 77210-4427 USA SDS Request : [PHONE REDACTED] Emergency Telephone Number Spill Information : [PHONE REDACTED] Health Information : [PHONE REDACTED] 2. COMPOSITION/INFORMATION ON INGREDIENTS Highly refined mineral oils and additives. The highly refined mineral oil contains (w/w) DMSO-extract, according to IP346. 3. HAZARDS IDENTIFICATION Emergency Overview Appearance and Odour : Amber. Liquid at room temperature. Slight hydrocarbon. Health Hazards : Not classified as dangerous for supply or conveyance. Safety Hazards : Not classified as flammable but will burn. Environmental Hazards : Not classified as dangerous for the environment. Health Hazards : Not expected to be a health hazard when used under normal conditions. Health Hazards Inhalation : Under normal conditions of use, this is not expected to be a primary route of exposure. Skin Contact : Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Eye Contact : May cause slight irritation to eyes. Ingestion : Low toxicity if swallowed. Other Information : Used oil may contain harmful impurities. Signs and : Oil acne/folliculitis signs and may include formation of black pustules and spots on the skin of exposed areas. Ingestion may result in nausea, vomiting and/or diarrhoea. Aggravated Medical Conditions : Pre-existing medical conditions of the following organ(s) or organ system(s) may be aggravated by exposure to this material: Skin. Environmental Hazards : Not classified as dangerous for the environment. Page 633 of 878 Page 633 of 878 Page 633 of 878 Page 633 of 878 ---PAGE BREAK--- Quaker State Advanced Durability SAE 5W-30 Motor Oil MSDS# 11878 Version 1.2 Material Safety Data Sheet Effective Date 03/13/2013 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 2/9 Print Date 04/24/2013 000000018029 MSDS_US Additional Information : Under normal conditions of use or in a foreseeable emergency, this product does not meet the definition of a hazardous chemical when evaluated according to the OSHA Hazard Communication Standard, 29 CFR 1910.1200. 4. FIRST AID MEASURES General Information : Not expected to be a health hazard when used under normal conditions. Inhalation : No treatment necessary under normal conditions of use. If persist, obtain medical advice. Skin Contact : Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention. Eye Contact : Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention. Ingestion : In general no treatment is necessary unless large quantities are swallowed, however, get medical advice. Advice to Physician : Treat 5. FIRE FIGHTING MEASURES Clear fire area of all non-emergency personnel. Flash point : > 220 °C / 428 °F (COC) Upper / lower Flammability or Explosion limits : Typical 1 - 10 %(V)(based on mineral oil) Auto ignition temperature : > 320 °C / 608 °F Specific Hazards : Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Suitable Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media : Do not use water in a jet. Protective Equipment for Firefighters : Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space. 6. ACCIDENTAL RELEASE MEASURES Avoid contact with spilled or released material. For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on disposal. Observe the relevant local and international regulations. Protective measures : Avoid contact with skin and eyes. Use appropriate containment to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately. Page 634 of 878 Page 634 of 878 Page 634 of 878 Page 634 of 878 ---PAGE BREAK--- Quaker State Advanced Durability SAE 5W-30 Motor Oil MSDS# 11878 Version 1.2 Material Safety Data Sheet Effective Date 03/13/2013 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 3/9 Print Date 04/24/2013 000000018029 MSDS_US Prevent from spreading by making a barrier with sand, earth or other containment material. Reclaim liquid directly or in an absorbent. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly. Additional Advice : Local authorities should be advised if significant spillages cannot be contained. 7. HANDLING AND STORAGE General Precautions : Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Use the information in this data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling vapour and/or mists. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Storage : Keep container closed and in a cool, well-ventilated place. Use properly labelled and closeable containers. Store at ambient temperature. Product Transfer : This material has the potential to be a static accumulator. Proper grounding and bonding procedures should be used during all bulk transfer operations. Recommended Materials : For containers or container linings, use mild steel or high density polyethylene. Unsuitable Materials : PVC. Additional Information : Polyethylene containers should not be exposed to high temperatures because of possible risk of distortion. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Material Source Type ppm mg/m3 Notation Oil mist, mineral ACGIH TWA(Inhalabl e fraction.) 5 mg/m3 Oil mist, mineral OSHA Z1 PEL(Mist.) 5 mg/m3 Biological Exposure Index (BEI) No biological limit allocated. Exposure Controls : The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls Page 635 of 878 Page 635 of 878 Page 635 of 878 Page 635 of 878 ---PAGE BREAK--- Quaker State Advanced Durability SAE 5W-30 Motor Oil MSDS# 11878 Version 1.2 Material Safety Data Sheet Effective Date 03/13/2013 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 4/9 Print Date 04/24/2013 000000018029 MSDS_US based on a risk assessment of local circumstances. Appropriate measures include: Adequate ventilation to control airborne concentrations. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated. Personal Protective Equipment : Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers. Respiratory Protection : No respiratory protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid breathing of material. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. Select a filter suitable for combined particulate/organic gases and vapours [boiling point >65°C(149 Hand Protection : Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection: PVC, neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. For continuous contact we recommend gloves with breakthrough time of more than 240 minutes with preference for > 480 minutes where suitable gloves can be identified. For short-term/splash protection we recommend the same, but recognise that suitable gloves offering this level of protection may not be available and in this case a lower breakthrough time may be acceptable so long as appropriate maintenance and replacement regimes are followed. Glove thickness is not a good predictor of glove resistance to a chemical as it is dependent on the exact composition of the glove material. Eye Protection : Wear safety glasses or full face shield if splashes are likely to occur. Protective Clothing : Skin protection not ordinarily required beyond standard issue work clothes. Monitoring Methods : Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate. Validated exposure measurement methods should be applied by a competent person and samples Page 636 of 878 Page 636 of 878 Page 636 of 878 Page 636 of 878 ---PAGE BREAK--- Quaker State Advanced Durability SAE 5W-30 Motor Oil MSDS# 11878 Version 1.2 Material Safety Data Sheet Effective Date 03/13/2013 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 5/9 Print Date 04/24/2013 000000018029 MSDS_US analysed by an accredited laboratory. Examples of sources of recommended exposure measurement methods are given below or contact the supplier. Further national methods may be available. National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods http://www.cdc.gov/niosh/ Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods http://www.osha.gov/ Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances http://www.hse.gov.uk/ Institut für Deutschen Gesetzlichen Unfallversicherung (IFA), Germany. http://www.dguv.de/inhalt/index.jsp L'Institut National de Recherche et de Securité, (INRS), France http://www.inrs.fr/accueil Environmental Exposure Controls : Minimise release to the environment. An environmental assessment must be made to ensure compliance with local environmental legislation. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Amber. Liquid at room temperature. Odour : Slight hydrocarbon. pH : Not applicable. Initial Boiling Point and Boiling Range : > 280 °C / 536 °F estimated value(s) Pour point : Typical -38 °C / -36 °F Flash point : > 220 °C / 428 °F (COC) Upper / lower Flammability or Explosion limits : Typical 1 - 10 (based on mineral oil) Auto-ignition temperature : > 320 °C / 608 °F Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s)) Specific gravity : Typical 0.88 at 15 °C / 59 °F Density : Typical 886 kg/m3 at 15 °C / 59 °F Water solubility : Negligible. n-octanol/water partition coefficient (log Pow) : > 6 (based on information on similar products) Kinematic viscosity : > 50 cSt at 40 °C / 104 °F Vapour density (air=1) : > 1 (estimated value(s)) Electrical conductivity : This material is not expected to be a static accumulator. Evaporation rate (nBuAc=1) : Data not available 10. STABILITY AND REACTIVITY Stability : Stable. Conditions to Avoid : Extremes of temperature and direct sunlight. Materials to Avoid : Strong oxidising agents. Hazardous Decomposition : Hazardous decomposition products are not expected to form Page 637 of 878 Page 637 of 878 Page 637 of 878 Page 637 of 878 ---PAGE BREAK--- Quaker State Advanced Durability SAE 5W-30 Motor Oil MSDS# 11878 Version 1.2 Material Safety Data Sheet Effective Date 03/13/2013 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 6/9 Print Date 04/24/2013 000000018029 MSDS_US Products during normal storage. 11. TOXICOLOGICAL INFORMATION Basis for Assessment : Information given is based on data on the components and the toxicology of similar products. Unless indicated otherwise, the data presented is representative of the product as a whole, rather than for individual component(s). Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal conditions of use. Skin Irritation : Expected to be irritating. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Eye Irritation : Expected to be irritating. Respiratory Irritation : Inhalation of vapours or mists may cause irritation. Sensitisation : Not expected to be a skin sensitiser. Repeated Dose Toxicity : Not expected to be a hazard. Mutagenicity : Not considered a mutagenic hazard. Carcinogenicity : Not expected to be carcinogenic. Product contains mineral oils of types shown to be non-carcinogenic in animal skin-painting studies. Highly refined mineral oils are not classified as carcinogenic by the International Agency for Research on Cancer (IARC). Material : Carcinogenicity Classification Highly refined mineral oil (IP346 : ACGIH Group A4: Not classifiable as a human carcinogen. Highly refined mineral oil (IP346 : IARC 3: Not classifiable as to carcinogenicity to humans. Highly refined mineral oil (IP346 : GHS / CLP: No carcinogenicity classification Reproductive and Developmental Toxicity : Not expected to be a hazard. Additional Information : Used oils may contain harmful impurities that have accumulated during use. The concentration of such impurities will depend on use and they may present risks to health and the environment on disposal. ALL used oil should be handled with caution and skin contact avoided as far as possible. Continuous contact with used engine oils has caused skin cancer in animal tests. Page 638 of 878 Page 638 of 878 Page 638 of 878 Page 638 of 878 ---PAGE BREAK--- Quaker State Advanced Durability SAE 5W-30 Motor Oil MSDS# 11878 Version 1.2 Material Safety Data Sheet Effective Date 03/13/2013 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 7/9 Print Date 04/24/2013 000000018029 MSDS_US 12. ECOLOGICAL INFORMATION Ecotoxicological data have not been determined specifically for this product. Information given is based on a knowledge of the components and the ecotoxicology of similar products. Unless indicated otherwise, the data presented is representative of the product as a whole, rather than for individual component(s). Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic organisms. Expected to be practically non toxic: LL/EL/IL50 > 100 mg/l (to aquatic organisms) LL/EL50 expressed as the nominal amount of product required to prepare aqueous test extract. Mineral oil is not expected to cause any chronic effects to aquatic organisms at concentrations less than 1 mg/l. Mobility : Liquid under most environmental conditions. If it enters soil, it will adsorb to soil particles and will not be mobile. Floats on water. Persistence/degradability : Expected to be not readily biodegradable. Major constituents are expected to be inherently biodegradable, but the product contains components that may persist in the environment. Bioaccumulation : Contains components with the potential to bioaccumulate. Other Adverse Effects : Product is a mixture of non-volatile components, which are not expected to be released to air in any significant quantities. Not expected to have ozone depletion potential, photochemical ozone creation potential or global warming potential. 13. DISPOSAL CONSIDERATIONS Material Disposal : Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations. Do not dispose into the environment, in drains or in water courses. Container Disposal : Dispose in accordance with prevailing regulations, preferably to a recognised collector or contractor. The competence of the collector or contractor should be established beforehand. Local Legislation : Disposal should be in accordance with applicable regional, national, and local laws and regulations. 14. TRANSPORT INFORMATION US Department of Transportation Classification (49CFR) This material is not subject to DOT regulations under 49 CFR Parts 171-180. IMDG This material is not classified as dangerous under IMDG regulations. Page 639 of 878 Page 639 of 878 Page 639 of 878 Page 639 of 878 ---PAGE BREAK--- Quaker State Advanced Durability SAE 5W-30 Motor Oil MSDS# 11878 Version 1.2 Material Safety Data Sheet Effective Date 03/13/2013 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 8/9 Print Date 04/24/2013 000000018029 MSDS_US IATA (Country variations may apply) This material is either not classified as dangerous under IATA regulations or needs to follow country specific requirements. 15. REGULATORY INFORMATION The regulatory information is not intended to be comprehensive. Other regulations may apply to this material. Federal Regulatory Status Notification Status EINECS All components listed or polymer exempt. TSCA All components listed. DSL All components listed. Shell classifies this material as an "oil" under the CERCLA Petroleum Exclusion, therefore releases to the environment are not reportable under CERCLA. State Regulatory Status California Safe Drinking Water and Toxic Enforcement Act (Proposition 65) This material does not contain any chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. 16. OTHER INFORMATION NFPA Rating (Health, Fire, Reactivity) : 0, 1, 0 SDS Version Number : 1.2 SDS Effective Date : 03/13/2013 SDS Revisions : A vertical bar in the left margin indicates an amendment from the previous version. Page 640 of 878 Page 640 of 878 Page 640 of 878 Page 640 of 878 ---PAGE BREAK--- Quaker State Advanced Durability SAE 5W-30 Motor Oil MSDS# 11878 Version 1.2 Material Safety Data Sheet Effective Date 03/13/2013 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 9/9 Print Date 04/24/2013 000000018029 MSDS_US SDS Regulation : The content and format of this MSDS is in accordance with the OSHA Hazard Communication Standard, 29 CFR 1910.1200. SDS Distribution : The information in this document should be made available to all who may handle the product. Disclaimer : The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of health, safety and environmental requirements only. No warranty or guarantee is expressed or implied regarding the accuracy of these data or the results to be obtained from the use of the product. Page 641 of 878 Page 641 of 878 Page 641 of 878 Page 641 of 878 ---PAGE BREAK--- Page 642 of 878 Page 642 of 878 Page 642 of 878 Page 642 of 878 ---PAGE BREAK--- Page 643 of 878 Page 643 of 878 Page 643 of 878 Page 643 of 878 ---PAGE BREAK--- Page 644 of 878 Page 644 of 878 Page 644 of 878 Page 644 of 878 ---PAGE BREAK--- Page 645 of 878 Page 645 of 878 Page 645 of 878 Page 645 of 878 ---PAGE BREAK--- Telephone: (913) 851-3500 Fax: (913) 851-3377 12980 Metcalf Avenue – Suite 240 Overland Park, Kansas 66213 Scotwood Industries, Inc. MATERIAL SAFETY DATA SHEET Effective Date: May 1999 Identity: Roadrunner Ice Melting Compound Contains a proprietary combination of Potassium Chloride, Sodium Chloride, Calcium Chloride and Magnesium Chloride. Hazardous Ingredients/Identity Information: Does not contain Hazardous Components Physical/Chemical Characteristics: Boiling Point: Not Applicable Vapor Pressure: Not Applicable Vapor Density: Not Applicable Melting Point: Not Applicable Evaporation Rate: Not Applicable Specific Gravity: 2.076 Solubility in Water: 317 gpl @ 0 degrees C Appearance & Odor: White Dry Granules, Minimal Odor Fire and Explosion Hazard Data: Flash Point: Not Applicable Flammable Limits: Not Applicable Lel and Uel: Not Applicable Extinguishing Media:Water or Foam Spec. Fire Fighting Procedures: None Unusual Fire & Explosion Hazards: None Reactivity Data: Stability: Stable Condition to Avoid: Strong Oxidizing Acids Incompatibility: Not Applicable Hazardous Decomposition or By-Products: Not Applicable Hazardous Polymerization: Will not occur Page 646 of 878 Page 646 of 878 Page 646 of 878 Page 646 of 878 ---PAGE BREAK--- Page 2/2 Health Hazard Data: Routes of Entry Inhalation: Not Applicable Under Normal Conditions Skin: Not Applicable Under Normal Conditions Ingestion: Not Applicable Under Normal Conditions Health Hazards: None Known Carcinogenicity: NTP Not Applicable Larc Monographs Not Applicable OSHA Regulated Not Applicable Signs & of Exposure: None Medical Conditions Generally Aggravated by Exposure: None Known Emergency and First Aid Procedures: Wash Off With Water In case of eye contact, flush eyes with running water. If ingested, induce vomiting by lavage with water or milk. Precautions for Safe Handling and Use: Steps to be taken in case material is released or spilled: 1. Sweep up clean material into clean container. Waste disposal method: 1. Discard in normal waste disposal according to local regulations. Precautions to be Taken in Handling or Storage: 1. Store in a dry area - Wash hands after handling. Control Measures: Respiratory Protection: Not Normally Needed Ventilation: Not Needed Under Normal Conditions Protective Clothing or Equipment: Gloves------------Optional Eye Protection--Optional Other-------------Optional Work/Hygienic Practices: Wash Hands after Handling with Warm Soapy Water Precautions: Storage and Handling Precautions: Store in Dry, Well Ventilated Area Practice Good Housekeeping, Clean up Spills Immediately References & Definitions: Combinations: KCL CAS# 7447-40-7 NACL CAS# 7647-14-5 CACL2 CAS# 010043-52-4 MGCL2 CAS# 7786-30-3 Page 647 of 878 Page 647 of 878 Page 647 of 878 Page 647 of 878 ---PAGE BREAK--- Monsanto Company, Lawn & Garden Products Page: 1 / 10 Roundup® Weed & Grass Killer Concentrate Plus Version: 1.0 Effective date: 05/13/2015 Monsanto Company, Lawn & Garden Products Safety Data Sheet Commercial Product 1. PRODUCT AND COMPANY IDENTIFICATION 1.1. Product identifier Roundup® Weed & Grass Killer Concentrate Plus 1.1.1. Chemical name Not applicable. 1.1.2. Synonyms None 1.1.3. EPA Reg. No. 71995-29 1.2. Product use Herbicide 1.3. Company Monsanto Company, Lawn & Garden Products, P.0. Box 418, Marysville, OH, 43041 Telephone: 1-[PHONE REDACTED] E-mail: [EMAIL REDACTED] 1.4. Emergency numbers FOR CHEMICAL EMERGENCY, SPILL LEAK, FIRE, EXPOSURE, OR ACCIDENT Call CHEMTREC - Day or Night: 1-[PHONE REDACTED] toll free in the continental U.S., Puerto Rico, Canada, or Virgin Islands. For calls originating elsewhere: [PHONE REDACTED] (collect calls accepted). FOR MEDICAL EMERGENCY - Day or Night: 1-[PHONE REDACTED] 2. HAZARDS IDENTIFICATION 2.1. Classification OSHA Hazard Communication Standard, 29 CFR 1910.1200 (2012) STOT RE - Category 1 2.2. Label elements 2.2.1. Signal word DANGER! 2.2.2. Hazard pictogram/pictograms 2.2.3. Hazard statement/statements Causes damage to liver, kidney, blood, eyes, cardiovascular system and/or gastrointestinal tract through prolonged or repeated exposure. 2.2.4. Precautionary statement/statements Do not breathe mist/vapours/spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Get medical advice/attention if you feel unwell. Page 648 of 878 Page 648 of 878 Page 648 of 878 Page 648 of 878 ---PAGE BREAK--- Monsanto Company, Lawn & Garden Products Page: 2 / 10 Roundup® Weed & Grass Killer Concentrate Plus Version: 1.0 Effective date: 05/13/2015 Dispose of contents/container in accordance with local, regaional, national and international regulations. 2.3. Appearance and odour (colour/form/odour) Amber /Liquid / Musky 2.4. OSHA Status This product is hazardous according to the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Refer to section 11 for toxicological and section 12 for environmental information. 3. COMPOSITION/INFORMATION ON INGREDIENTS Active ingredient Isopropylamine salt of N-(phosphonomethyl)glycine; {Isopropylamine salt of 6,7-Dihydrodipyrido(1,2-a:2',1'c) pyrazinedium dibromide; {Diquat dibromide} Composition COMPONENT CAS No. % by weight (approximate) Isopropylamine salt of 38641-94-0 18 Diquat dibromide 85-00-7 0.73 Other ingredients 81.27 The specific chemical identity is being withheld because it is trade secret information of Monsanto Company. 4. FIRST AID MEASURES Use personal protection recommended in section 8. 4.1. Description of first aid measures 4.1.1. Skin contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15- 20 minutes. Call a poison control center or doctor for treatment advice. 4.1.2. Inhalation: If inhaled, move person to fresh air. If person is not breathing, call emergency number or ambulance, then give artificial respiration, preferably mouth-to-mouth, if possible. Call a poison control center or doctor for treatment advice. 4.1.3. Ingestion: Call poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison center or doctor. Do not give anything by mouth to an unconscious person. 4.2. Most important and effects, both acute and delayed 4.2.1. Eye contact, short term: May cause temporary eye irritation. 4.2.2. Skin contact, short term: Not expected to produce significant adverse effects when recommended use instructions are followed. 4.2.3. Inhalation, short term: Not expected to produce significant adverse effects when recommended use instructions are followed. 4.2.4. Single ingestion: Not expected to produce significant adverse effects when recommended use instructions are followed. 4.3. Indication of any immediate medical attention and special treatment needed 4.3.1. Advice to doctors: This product is not an inhibitor of cholinesterase. 4.3.2. Antidote: Treatment with atropine and oximes is not indicated. Page 649 of 878 Page 649 of 878 Page 649 of 878 Page 649 of 878 ---PAGE BREAK--- Monsanto Company, Lawn & Garden Products Page: 3 / 10 Roundup® Weed & Grass Killer Concentrate Plus Version: 1.0 Effective date: 05/13/2015 5. FIRE-FIGHTING MEASURES 5.1. Extinguishing media 5.1.1. Recommended: Water, foam, dry chemical, carbon dioxide (CO2) 5.2. Special hazards 5.2.1. Unusual fire and explosion hazards None. Minimise use of water to prevent environmental contamination. Environmental precautions: see section 6. 5.2.2. Hazardous products of combustion Carbon monoxide (CO), nitrogen oxides (NOx), phosphorus oxides (PxOy), hydrogen bromide (HBr) 5.3. Fire fighting equipment: Self-contained breathing apparatus. Equipment should be thoroughly decontaminated after use. 5.4. Flash point Does not flash. 6. ACCIDENTAL RELEASE MEASURES 6.1. Environmental precautions SMALL QUANTITIES: Low environmental hazard. LARGE QUANTITIES: Minimise spread. Keep out of drains, sewers, ditches and water ways. 6.2. Methods for cleaning up SMALL QUANTITIES: Flush spill area with water. LARGE QUANTITIES: Absorb in earth, sand or absorbent material. Absorb only in non-combustible material. Dig up heavily contaminated soil. Refer to section 7 for types of containers. Collect in containers for disposal. Flush residues with small quantities of water. Minimise use of water to prevent environmental contamination. Refer to section 13 for disposal of spilled material. Use handling recommendations in Section 7 and personal protection recommendations in Section 8. 7. HANDLING AND STORAGE Good industrial practice in housekeeping and personal hygiene should be followed. 7.1. Precautions for safe handling Avoid contact with eyes. Avoid breathing vapour or mist. When using do not eat, drink or smoke. Wash hands thoroughly after handling or contact. Wash contaminated clothing before re-use. Thoroughly clean equipment after use. Do not contaminate drains, sewers and water ways when disposing of equipment rinse water. Refer to section 13 of the safety data sheet for disposal of rinse water. 7.2. Conditions for safe storage Page 650 of 878 Page 650 of 878 Page 650 of 878 Page 650 of 878 ---PAGE BREAK--- Monsanto Company, Lawn & Garden Products Page: 4 / 10 Roundup® Weed & Grass Killer Concentrate Plus Version: 1.0 Effective date: 05/13/2015 Compatible materials for storage: stainless steel, aluminium, fibreglass, plastic, glass lining Incompatible materials for storage: galvanised steel, unlined mild steel, see section 10. Keep out of reach of children. Keep away from food, drink and animal feed. Keep container closed in a cool, well-ventilated place. Keep only in the original container. Partial may occur on prolonged storage below the minimum storage temperature. If frozen, place in warm room and shake frequently to put back into solution. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Airborne exposure limits Components Exposure Guidelines Isopropylamine salt of No specific occupational exposure limit has been established. Diquat dibromide TLV (ACGIH): 0.5 mg/m3: inhalable fraction, skin, The exposure limit indicated is for the diquat cation. TLV (ACGIH): 0.1 mg/m3: respirable fraction, skin, The exposure limit indicated is for the diquat cation. PEL (OSHA): No specific occupational exposure limit has been established. Other ingredients No specific occupational exposure limit has been established. 8.2. Engineering controls: No special requirement when used as recommended. If airborne exposure is excessive: Provide adequate ventilation to keep airborne concentration below exposure limits. 8.3. Recommendations for personal protective equipment 8.3.1. Eye protection: If there is significant potential for contact: Wear chemical goggles. 8.3.2. Skin protection: No special requirement when used as recommended. If repeated or prolonged contact: Wear chemical resistant gloves. 8.3.3. Respiratory protection: No special requirement when used as recommended. If airborne exposure is excessive: Wear respirator. Respiratory protection programs must comply with all local/regional/national regulations. When recommended, consult manufacturer of personal protective equipment for the appropriate type of equipment for a given application. 9. PHYSICAL AND CHEMICAL PROPERTIES These physical data are typical values based on material tested but may vary from sample to sample. Typical values should not be construed as a guaranteed analysis of any specific lot or as specifications for the product. Colour/colour range: Amber Odour: Musky Form: Liquid Physical form changes (melting, boiling, etc.): Melting point: Not applicable. Boiling point: No data. Flash point: Does not flash. Explosive properties: No data. Auto ignition temperature: No data. Self-accelerating decomposition No data. Page 651 of 878 Page 651 of 878 Page 651 of 878 Page 651 of 878 ---PAGE BREAK--- Monsanto Company, Lawn & Garden Products Page: 5 / 10 Roundup® Weed & Grass Killer Concentrate Plus Version: 1.0 Effective date: 05/13/2015 temperature (SADT): Oxidizing properties: No data. Specific gravity: 1.0775 @ 20 °C / 15.6 °C Vapour pressure: No significant volatility; aqueous solution. Vapour density: Not applicable. Evaporation rate: No data. Dynamic viscosity: No data. Kinematic viscosity: No data. Density: 1.0775 g/cm3 @ 20 °C Solubility: Water: Soluble pH: 4.6 Partition coefficient: log Pow: -3.2 @ 25 °C Partition coefficient: log Pow: -4.60 @ 20 °C (diquat dibromide) 10. STABILITY AND REACTIVITY 10.1. Reactivity Reacts with galvanised steel or unlined mild steel to produce hydrogen, a highly flammable gas that could explode. 10.2. Stability Stable under normal conditions of handling and storage. 10.3. Possibility of hazardous reactions Reacts with galvanised steel or unlined mild steel to produce hydrogen, a highly flammable gas that could explode. 10.4. Incompatible materials galvanised steel;unlined mild steel;see section 10.; Compatible materials for storage: see section 7.2. 10.5. Hazardous decomposition Thermal decomposition: Hazardous products of combustion: see section 5. 11. TOXICOLOGICAL INFORMATION This section is intended for use by toxicologists and other health professionals. Likely routes of exposure: eye contact, Skin contact, inhalation Potential health effects Eye contact, short term: May cause temporary eye irritation. Skin contact, short term: Not expected to produce significant adverse effects when recommended use instructions are followed. Inhalation, short term: Not expected to produce significant adverse effects when recommended use instructions are followed. Single ingestion: Not expected to produce significant adverse effects when recommended use instructions are followed. Data obtained on product and components are summarized below. Acute oral toxicity Rat, female, LD50 (Method: Up-and-down procedure (OECD 425)): > 5,000 mg/kg body weight Practically non-toxic. No mortality. Page 652 of 878 Page 652 of 878 Page 652 of 878 Page 652 of 878 ---PAGE BREAK--- Monsanto Company, Lawn & Garden Products Page: 6 / 10 Roundup® Weed & Grass Killer Concentrate Plus Version: 1.0 Effective date: 05/13/2015 Acute dermal toxicity Rat, LD50: > 5,000 mg/kg body weight Practically non-toxic. No mortality. Acute inhalation toxicity Rat, LC50, 4 hours, aerosol: > 2.05 mg/L Practically non-toxic. For purposes of the inhalation test, product was artificially aerosolized. Since this material will not become aerosolized to a hazardous concentration during transport, it is classified as non- hazardous under the transportation regulations in accordance with 2.6.2.2.4.7(b) and of the UN Recommendations on the Transport of Dangerous Goods. No mortality. Skin irritation Rabbit, 3 animals, OECD 404 test: Days to heal: 3 Primary Irritation Index (PII): 0.5/8.0 Slight irritation. Eye irritation Rabbit, 3 animals, OECD 405 test: Days to heal: 7 Moderate irritation. Skin sensitization Guinea pig, 3-induction Buehler test: Positive incidence: 0 % Negative. N-(phosphonomethyl)glycine; { acid} Genotoxicity Not genotoxic. Carcinogenicity Not carcinogenic in rats or mice. Reproductive/Developmental Toxicity Reproductive effects in rats only in the presence of significant maternal toxicity. Developmental effects in rats and rabbits only in the presence of significant maternal toxicity. Diquat dibromide Genotoxicity Not genotoxic in vivo. Carcinogenicity Not carcinogenic in rats or mice. Reproductive/Developmental Toxicity Reproductive effects in rats only in the presence of maternal toxicity. Developmental effects in rats, rabbits, and mice only in the presence of maternal toxicity. Page 653 of 878 Page 653 of 878 Page 653 of 878 Page 653 of 878 ---PAGE BREAK--- Monsanto Company, Lawn & Garden Products Page: 7 / 10 Roundup® Weed & Grass Killer Concentrate Plus Version: 1.0 Effective date: 05/13/2015 12. ECOLOGICAL INFORMATION This section is intended for use by ecotoxicologists and other environmental specialists. Data obtained on a similar formulation and/or are summarized below. The minor active ingredient is not predicted to significantly contribute to the ecological toxicity of this formulation. Similar formulation Aquatic toxicity, fish Zebra fish (Brachydanio rerio): Acute toxicity, 96 hours, semi-static, LC50: 28.3 mg/L toxic. Aquatic toxicity, invertebrates Water flea (Daphnia magna): Acute toxicity, 48 hours, static, EC50: 42.2 mg/L toxic. Aquatic toxicity, algae/aquatic plants Green algae (Selenastrum capricornutum): Acute toxicity, 72 hours, static, EyC50 (yield): 7.12 mg/L Moderately toxic. Arthropod toxicity Honey bee (Apis mellifera): Contact, 48 hours, LD50: > 208 µg/bee Practically non-toxic. Soil organism toxicity, invertebrates Earthworm (Eisenia foetida): Acute toxicity, 14 days, LC50: > 1,000 mg/kg soil Practically non-toxic. Similar formulation Aquatic toxicity, fish Rainbow trout mykiss): Acute toxicity, 96 hours, static, LC50: 5.4 mg/L Moderately toxic. Bluegill sunfish (Lepomis macrochirus): Acute toxicity, 96 hours, static, LC50: 7.3 mg/L Moderately toxic. Avian toxicity Mallard duck (Anas Dietary toxicity, 5 days, LC50: > 5,620 mg/kg diet Practically non-toxic. Bobwhite quail (Colinus virginianus): Dietary toxicity, 5 days, LC50: > 5,620 mg/kg diet Practically non-toxic. Arthropod toxicity Honey bee (Apis mellifera): Oral/contact, 48 hours, LD50: > 100 µg/bee Practically non-toxic. N-(phosphonomethyl)glycine { Bioaccumulation Page 654 of 878 Page 654 of 878 Page 654 of 878 Page 654 of 878 ---PAGE BREAK--- Monsanto Company, Lawn & Garden Products Page: 8 / 10 Roundup® Weed & Grass Killer Concentrate Plus Version: 1.0 Effective date: 05/13/2015 Bluegill sunfish (Lepomis macrochirus): Whole fish: BCF: < 1 No significant bioaccumulation is expected. Dissipation Soil, field: Half life: 2 - 174 days Koc: 884 - 60,000 L/kg Adsorbs strongly to soil. Water, aerobic: Half life: < 7 days 13. DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods 13.1.1. Product Keep out of drains, sewers, ditches and water ways. Recycle if appropriate facilities/equipment available. Burn in special, controlled high temperature incinerator. Follow all local/regional/national/international regulations. 13.1.2. Container See the individual container label for disposal information. Emptied packages retain product residue and dust. Observe all labeled safeguards until container is cleaned, reconditioned or destroyed. Empty packaging completely. Triple or pressure rinse empty containers. Do NOT contaminate water when disposing of rinse waters. Ensure packaging cannot be reused. Do NOT re-use containers. Store for collection by approved waste disposal service. Recycle if appropriate facilities/equipment available. Follow all local/regional/national/international regulations. Use handling recommendations in Section 7 and personal protection recommendations in Section 8. 14. TRANSPORT INFORMATION The data provided in this section is for information only. Please apply the appropriate regulations to properly classify your shipment for transportation. 14.1. US Dept. of Transportation (DOT) Hazardous Materials Regulations (49 CFR Parts 105-180) Proper Shipping Name (Technical Name if required): Not regulated for domestic ground transportation. 14.2. IMDG Code Proper Shipping Name (Technical Name if required): Not regulated for transport under IMO Regulations 14.3. IATA/ICAO Proper Shipping Name (Technical Name if required): Not regulated for transport under IATA/ICAO Regulations 15. REGULATORY INFORMATION 15.1. Environmental Protection Agency 15.1.1. TSCA Inventory Exempt 15.1.2. SARA Title III Rules Page 655 of 878 Page 655 of 878 Page 655 of 878 Page 655 of 878 ---PAGE BREAK--- Monsanto Company, Lawn & Garden Products Page: 9 / 10 Roundup® Weed & Grass Killer Concentrate Plus Version: 1.0 Effective date: 05/13/2015 Section 311/312 Hazard Categories: Immediate Section 302 Extremely Hazardous Substances: Not applicable. Section 313 Toxic Chemical(s): Not applicable. 15.1.3. CERCLA Reportable quantity Not applicable. 15.1.4. Federal Insecticide, Fungicide, Rodenticide Act (FIFRA) This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. CAUTION! CAUSES MODERATE EYE IRRITATION Acute oral toxicity: FIFRA category IV. Acute dermal toxicity: FIFRA category IV. Acute inhalation toxicity: FIFRA category IV. Skin irritation: FIFRA category IV. Eye irritation: FIFRA category III. 16. OTHER INFORMATION The information given here is not necessarily exhaustive but is representative of relevant, reliable data. Follow all local/regional/national/international regulations. Please consult supplier if further information is needed. In this document the British spelling was applied. Health Flammability Instability Additional Markings NFPA 1 1 1 0 = Minimal hazard, 1 = Slight hazard, 2 = Moderate hazard, 3 = Severe hazard, 4 = Extreme hazard Full denomination of most frequently used acronyms. BCF (Bioconcentration Factor), BOD (Biochemical Oxygen Demand), COD (Chemical Oxygen Demand), EC50 (50% effect concentration), ED50 (50% effect dose), I.M. (intramuscular), I.P. (intraperitoneal), I.V. (intravenous), Koc (Soil adsorption coefficient), LC50 (50% lethality concentration), LD50 (50% lethality dose), LDLo (Lower limit of lethal dosage), LEL (Lower Explosion Limit), LOAEC (Lowest Observed Adverse Effect Concentration), LOAEL (Lowest Observed Adverse Effect Level), LOEC (Lowest Observed Effect Concentration), LOEL (Lowest Observed Effect Level), MEL (Maximum Exposure limit), MTD (Maximum Tolerated Dose), NOAEC (No Observed Adverse Effect Concentration), NOAEL (No Observed Adverse Effect Level), NOEC (No Observed Effect Concentration), NOEL (No Observed Effect Level), OEL (Occupational Exposure Limit), PEL (Permissible Exposure Limit), PII (Primary Irritation Index), Pow (Partition coefficient n-octanol/water), S.C. (subcutaneous), STEL (Short-Term Exposure Limit), TLV-C (Threshold Limit Value-Ceiling), TLV-TWA (Threshold Limit Value - Time Weighted Average), UEL (Upper Explosion Limit) This Material Safety Data Sheet (MSDS) serves different purposes than and DOES NOT REPLACE OR MODIFY THE EPA-APPROVED PRODUCT LABELING (attached to and accompanying the product container). This MSDS provides important health, safety, and environmental information for employers, employees, emergency responders and others handling large quantities of the product in activities generally other than product use, while the labeling provides that information specifically for product use in the ordinary course. Use, storage and disposal of pesticide products are regulated by the EPA under the authority of the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA) through the product labeling, and all necessary and appropriate precautionary, use, storage, and disposal information is set forth on that labeling. It is a violation of federal law to use a pesticide product in any manner not prescribed on the EPA-approved label. Page 656 of 878 Page 656 of 878 Page 656 of 878 Page 656 of 878 ---PAGE BREAK--- Monsanto Company, Lawn & Garden Products Page: 10 / 10 Roundup® Weed & Grass Killer Concentrate Plus Version: 1.0 Effective date: 05/13/2015 Although the information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed to be correct as of the date hereof, MONSANTO Company or any of its subsidiaries makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving same will make their own determination as to its suitability for the purposes prior to use. In no event will MONSANTO Company or any of its subsidiaries be responsible for damages of any nature whatsoever resulting from the use of or reliance upon information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR TO THE PRODUCT TO WHICH INFORMATION REFERS. 000000035801 End of document Page 657 of 878 Page 657 of 878 Page 657 of 878 Page 657 of 878 ---PAGE BREAK--- Page 658 of 878 Page 658 of 878 Page 658 of 878 Page 658 of 878 ---PAGE BREAK--- Page 659 of 878 Page 659 of 878 Page 659 of 878 Page 659 of 878 ---PAGE BREAK--- Page 660 of 878 Page 660 of 878 Page 660 of 878 Page 660 of 878 ---PAGE BREAK--- Page 661 of 878 Page 661 of 878 Page 661 of 878 Page 661 of 878 ---PAGE BREAK--- Page 662 of 878 Page 662 of 878 Page 662 of 878 Page 662 of 878 ---PAGE BREAK--- Page 663 of 878 Page 663 of 878 Page 663 of 878 Page 663 of 878 ---PAGE BREAK--- Page 664 of 878 Page 664 of 878 Page 664 of 878 Page 664 of 878 ---PAGE BREAK--- Page 665 of 878 Page 665 of 878 Page 665 of 878 Page 665 of 878 ---PAGE BREAK--- Page 666 of 878 Page 666 of 878 Page 666 of 878 Page 666 of 878 ---PAGE BREAK--- Notas De la Exposici ón Ninguno Descripción De la Emergencia: Las concentraciones altas de vapores pueden irritar a los ojos, nariz y las vias respiratorias. Causa irritaciones en la nariz y la garganta. Dañino si es inhalado. Puede afectar al cerebro o al sistema nervioso causando mareos, dolores de cabeza o nausea. Dañino si es ingerido o tragado. Causa irritacion en los ojos. Liquido y vapor inflamables. Efectos de la Sobreexposición - Contacto Con Los Ojos: Causa irritacion en los ojos. Efectos de la Sobreexposición - Contacto Con la Piel: Un contacto prolongado o repetido puede causar irritacion en la piel. Efectos de la Sobreexposición - Inhalacion: Alta concentracion de vapores es irritante para los ojos, nariz, garganta, y pulmones. Puede causar dolores de cabeza y mareos. Evite respirar los vapores o la niebla. Dañino si Hoja De Datos De Seguridad Del Material Emergencia: 1-[PHONE REDACTED] Rust-Oleum Corp. www.rustoleum.com 1 - Producto Quimico E Identificacion De La Compañia Nombre Del Producto: Rust Oleum American Accents Decorative Paint Pens Fecha De Revision: 08/30/2007 Número de identificación: 215123, 215153, 215154, 215155, 215156, 215157, 215168, 215169, 222643, 222644, 222645, 222646, 222647, 222648 Uso De Producto/Clase: Decorative Paint Pens/American Accents Surtidor: Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA Fabricante: Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA Preparador: Departamento Regulador 2 - Composicion/Informacion Sobre Ingredientes Conocido Químico CAS Numero Menos peso que el % ACGIH TLV-TWA ACGIH TLV-STELOSHA PEL-TWA OSHA PEL-TECHO Dióxido de Titanio 13463-67-7 30.0 10 mg/m3 N.E. 10 mg/m3 N.E. Nafta Disolvente (Petróleo), Fracción Alifática64742-89-8 25.0 300 PPM N.E. 300 PPM N.E. Nafta Solvente 64742-47-8 10.0 100 PPM N.E. N.E. N.E. Carbón Negro 1333-86-4 5.0 3.5 mg/m3 N.E. 3.5 mg/m3 N.E. Silicato de Magnesio 14807-96-6 5.0 10 mg/m3 N.E. 15 mg/m3 N.E. Silicato de Aluminio 1332-58-7 5.0 2 mg/m3 N.E. 5 mg/m3 N.E. Xileno 1330-20-7 5.0 100 PPM 150 PPM 100 PPM N.E. Etilobenceno 100-41-4 1.0 100 PPM 125 PPM 100 PPM N.E. Pigment Red 122 980-26-7 1.0 15mg/m3 N.E. 5mg/m3 N.E. 3 - Identificacion De Peligros Page 1 of 6 215123, 215153, 215154, 215155, 215156, 215157, 215168, 215169, 222643, 222644, 222... Page 667 of 878 Page 667 of 878 Page 667 of 878 Page 667 of 878 ---PAGE BREAK--- es inhalado. Efectos de la Sobreexposición - Ingestion: Peligro si aspiracion si es que es ingerido o tragado; puede entrar en los pulmones y causar daños. Dañino si es ingerido o tragado. Efectos de la Sobreexposición - Crónicos Peligros: IARC enlista al como un posible carcinógeno humano (grupo 2B). Reportes han asociado una sobreexposicion ocupacional repetida y prolongada a solventes con daños permanentes al cerebro y al sistema nervioso. Una sobreexposicion a Xileno en animales de laboratorio ha sido asociada con anormalidades del higado, riñónes, pulmones, el bazo y tambien daños a los ojos. Los efectos en los humanos incluyen anormalidades del higado y cardiacas. Contiene carbon negro. Se han observado inflamaciones cronicas, fibrosis en los pulmones y tumores en los pulmones, en algunas ratas expuestas experimentalmente por periodos largos de tiempo a concentraciones excesivas de carbon negro y varias particulas insolubles de polvo fino. Los tumores no se han observado en otras especies de animales (ejemplo: raton y hamster) bajo circunstancias similares y condiciones de estudio. Estudios epidemilogicos conducidos con trabajadores en America del Norte no demuestran evidencia de efectos clinicos adversos para la salud debido a una exposicion ocupacional a carbon negro. El carbon negro esta clasificado en listas como Grupo 2B - "posiblemente agente carcinogeno para humanos" por IARC y se ha propuesto que se clasifique en listas como A4- "no ha sido clasificado como un agente carcinogeno para los humanos" por la Conferencia Americana de Higienistas Industriales Gubernamentales. No se anticipa una exposicion significante durante la aplicacion usando una brocha o el secado. El riesgo para una sobreexposicion depende en la duracion y el nivel de la exposicion al polvo del lijado repetido de las superficies o a la niebla del rociado y la concentracion actual del carbon negro en la formula. Ruta de la entrada: Contacto De la Piel, Absorci ón De la Piel, Inhalación, Contacto Con Los Ojos Primeros auxilios - Contacto Con Los Ojos: Manteniendo los parpados abiertos enjuague los ojos con grandes cantidades de agua por lo menos durante 15 minutos. Obtenga atencion medica. Primeros auxilios - Contacto Con la Piel: Lave con jabon y agua. Obtenga atencion medica si es que una irritacion se desarrolla o persiste. Primeros auxilios - Inhalacion: Lleve donde se encuentra aire fresco. Si no esta respirando, dispense respiracion artificial. Si la respiracion es dificil, dispense oxigeno. Obtenga atencion medica inmediatamente. Primeros auxilios - Ingestion: Peligro de aspiracion: no induzca el vomito o dispense algo por la boca porque este material puede entrar en los pulmones y causar daños severos en los pulmones. Obtenga atencion medica inmediatamente. Medio De Extincion: Producto químico Seco, Espuma, Niebla Del Agua Unusual Peligros De Fuego Y Explosion: Los vapores pueden formar unas mezclas explosivas con el aire. Los vapores pueden viajar hasta una fuente de ignicion y pueden explotar. Aisle y proteja contra el calor, equipo electrico, chispas y llamas de fuego. Contra Fuego: Se puede usar agua para enfriar los contenedores cerrados para prevenir la acumulacion de la presion y una posible autoignicion o explosion. Evacue el area y combata el fuego desde una distancia segura. 4 - Medidas De Primeros Auxilios 5 - Medidas Para Combatir Incendios Temperatura de Inflama, F: 67 F Límite Explosivo Inferior, 0.7 % (Setaflash) Límite Explosivo Superior, 36.0 % Page 2 of 6 215123, 215153, 215154, 215155, 215156, 215157, 215168, 215169, 222643, 222644, 222... Page 668 of 878 Page 668 of 878 Page 668 of 878 Page 668 of 878 ---PAGE BREAK--- Pasos de progresión Que se tomarán Si El Material Release/versión O Se derrama: Contenga el liquido derramado con arena o tierra. NO USE materiales combustibles como aserrin. Elimine todas las fuentes de ignicion; use equipo a prueba de explosion. Ponga los materiales en contenedores y deseche de acuerdo a las leyes locales, provincianas, estatales y las regulaciones federales. Manipulacion: Lavese las manos antes de comer. Lavese completamente despues de haber manejado. Use con una ventilacion adecuada. Siga toda las precauciones de la etiqueta y la Hoja de Informacion Sobre la Seguridad del Material aun si es que el contenedor esta vacio porque puede contener residuos del producto. Alamacenamiento: Mantenga el contenedor cerrado cuando no se esta usando. Mantenga lejos del calor, chispas, llamas o fuentes de ignicion. Mantenga los contenedores cerrados hermeticamente. Aisle contra el calor, equipo electrico, chispas o llamas de fuego. Controles De la Ingeniería: Prevenga la acumulacion de los vapores al abrir todas las puertas y ventanas para lograr una ventilacion cruzada. Use recintos de proceso, ventilacion local de escape, o cualquier otros controles de ingenieria para controlar los niveles llevados por el aire para que no lleguen a los limites de los niveles de exposicion. Respiratoria Protecci ón: Un programa para la proteccion respiratoria que conforma con los requisitos de OSHA 1910.134 y de ANSI Z88.2 se debe seguir cuando quiera que las condiciones del lugar de trabajo justifican el uso de un respirador. Un respirador con purificacion de aire aprobado por NIOSH/MSHA con un cartucho o un bote para filtrar vapores organicos puede ser permisible dentro de ciertas circunstancias cuando se espera que las concentraciones flotando en el aire lleguen a exceder los limites de exposicion. La proteccion proveida por los respiradores que solamente purifican el aire es limitada. Use un respirador con abastecimiento de presion de aire positiva si es que existe la posibilidad de una descarga fuera de control, cuando los niveles de exposicion no son conocidos, o cualquier otra circunstancia cuando los respiradores para purificar el aire no pueden proveer una proteccion adecuada. Proteccion De Los Piel: Guantes de Nitrilo o Neopreno pueden ofrecer una proteccion adecuada para la piel. Use guantes impermeables para prevenir un contacto con la piel y la absorcion de este material en la piel. Proteccion De Los Ojos: Use proteccion para los ojos disenada para proteger contra las salpicaduras de los liquidos. El Otro Protector Equipo: Refierase al supervisor de la seguridad o al higienista industrial para obtener informacion adicional acerca del equipo para la proteccion personal y su aplicacion. Higiénicas Prácticas: Lavese completamente con jabon y agua antes de comer, beber liquidos o fumar. 6 - Medidas De Escape Accidental 7 - Manejo Y Almacenamiento 8 - Controles De Exposicion, Proteccion Personal 9 - Propiedades Fisicas Y Quimicas Punto De Ebullicion: 69 - 999 F Densidad Del Vapor: Mas Pesado Que Aire Olor: Como Solvente Concentración Límite de Olor: ND Apariencia: Líquido Velocidad De Evaporacion: Slower than Ether Solubilidad En Agua: Leve Temperatura De Gravedad Específica: Page 3 of 6 215123, 215153, 215154, 215155, 215156, 215157, 215168, 215169, 222643, 222644, 222... Page 669 of 878 Page 669 of 878 Page 669 of 878 Page 669 of 878 ---PAGE BREAK--- (Vea la sección 16 para la leyenda de la abreviatura) Condicions Que Se Deben Evitar: Evite todas las fuentes de ignicion. Incompatibildades: No es comparable con fuertes asidos y bases. Decomposicion Peligrosa: Irritalosojos con las llames expuestas. Por llama de fuego, monoxido de carbono y bioxido de carbono. Polymerizacion: No ocurrirá bajo condiciones normales. Estabilidad: Este producto es estable bajo condiciones normales de almacenamiento. Informacion Ecologica: El producto es una mezcla de los componentes en la lista. Consideraciones Acerca De La Eliminacion: Deseche los materiales de acuerdo a las regulaciones y ordenanzas locales, estatales y federales. No permita que entren en los sistemas de alcantarillas o drenaje para tormentas. Congelación: ND 1.1200 Presíon De Vapor: PH: NE Estado Fisico: Líquido 10 - Estabilidad Y Reactividad 11 - Propiedades Toxicologicas Producto LD50: ND Producto LC50: ND Conocido Químico LD50 LC50 Dióxido de Titanio >7500 mg/kg (ORAL, RATA)N.D. Nafta Disolvente (Petróleo), Fracción Alifática >5000 mg/kg (Oral, Rata) N.D. Nafta Solvente N.D. N.D. Carbón Negro N.D. N.D. Silicato de Magnesio N.D. TCLo:11mg/m3 inh. Silicato de Aluminio 5000 mg/kg (ORAL RATA) N.D. Xileno N.D. N.D. Etilobenceno 3500 mg/kg (ORAL, RATA) N.D. Pigment Red 122 N.D. N.D. 12 - Informacion Ecologica 13 - Consideraciones De Eliminacion 14 - Informacion De Transportacion DOT Nombre apropiado del envío: Paint Grupo Del Embalaje: II DOT Nombre T écnico: Subclase De Risques: Page 4 of 6 215123, 215153, 215154, 215155, 215156, 215157, 215168, 215169, 222643, 222644, 222... Page 670 of 878 Page 670 of 878 Page 670 of 878 Page 670 of 878 ---PAGE BREAK--- CERCLA Categorias Peligrosas SARA Este producto se ha repasado según las categorías del peligro de EPA promulgadas bajo secciones 311 y 312 de la enmienda de Superfund y del acto de Reauthorization de 1986 (el título de SARA III) y se considera, bajo definiciones aplicables, resolver siguientes las categorías: PELIGRO DE SALUD INMEDIATO, PELIGRO DE SALUD CRONICO, PELIGRO DE INCENDIO Sección 313 De La Ley SARA: Este producto contiene las sustancias siguientes conforme a los requisitos que señalan de la secci ón 313 del título III de la enmienda de Superfund y del acto de Reauthorization de la parte 372 de 1986 y 40 CFR: TSCA: Este producto contiene las sustancias químicas siguientes conforme a los requisitos que señalan de TSCA 12(b) si está exportado de los Estados Unidos: Ninguno Regulaciones Estatales New Jersey RTK: Los materiales siguientes son no-peligrosos, pero están entre los cinco componentes superiores en este producto. RTK: Los ingredientes no-peligrosos siguientes están presentes en el producto en mayor que DOT Clase De Risques: 3 Paginación De la Guía: 128 DOT UN/NA: UN1263 15 - Informacion Reguladora Conocido Químico CAS Numero Xileno 1330-20-7 Etilobenceno 100-41-4 Conocido Químico CAS Numero ESPIRITUS MINERALES 64742-88-7 Modified Alkyd Propietario Resin 9003-53-6 Conocido Químico CAS Numero ESPIRITUS MINERALES 64742-88-7 Modified Alkyd Propietario Resin 9003-53-6 PIGMENTO DE OXIDO DE HIERRO NARANJA 7023-61-2 Oxido de Hierro Rojo 1332-37-2 Oxido de Hierro Amarillo 51274-00-1 Pigmento de Ftalocianina Azul 147-14-8 Page 5 of 6 215123, 215153, 215154, 215155, 215156, 215157, 215168, 215169, 222643, 222644, 222... Page 671 of 878 Page 671 of 878 Page 671 of 878 Page 671 of 878 ---PAGE BREAK--- Proposicion 65 de California: ¡Advertencia! Este producto contiene químicos que son conocidos en el Estado de California porque causan cáncer. Estos productos no contienen ningún producto químico sabido al Estado de California para causar los defectos de nacimiento o el otro daño reproductivo. Regulaciones Internacionales: Regulaciones Canadiense Este MSDS ha sido preparado de acuerto con las normas de productos controlados, excepto para el uso de los 16 enlistado. CANADIAN WHMIS CLASS: B2, D2B Contenido de COV, GR/LTR: Razón de la revisión: Legend: N.A. - No aplicable, N.E. - No establecido, N.D. - No resuelto La informaci ón contenida en este MSDS se ha controlado y debe ser exacta. Sin embargo, es la responsabilidad del utilizador conformarse con todo el federal, estado, y locales leyes y regulaciones. 16 - Otra Informacion Clasificaciones HMIS: Salud:: 2 Fuego: 4 Reactividad: 0 Personal Protección: X Page 6 of 6 215123, 215153, 215154, 215155, 215156, 215157, 215168, 215169, 222643, 222644, 222... Page 672 of 878 Page 672 of 878 Page 672 of 878 Page 672 of 878 ---PAGE BREAK--- Page 673 of 878 Page 673 of 878 Page 673 of 878 Page 673 of 878 ---PAGE BREAK--- Page 674 of 878 Page 674 of 878 Page 674 of 878 Page 674 of 878 ---PAGE BREAK--- Page 675 of 878 Page 675 of 878 Page 675 of 878 Page 675 of 878 ---PAGE BREAK--- Page 676 of 878 Page 676 of 878 Page 676 of 878 Page 676 of 878 ---PAGE BREAK--- Page 677 of 878 Page 677 of 878 Page 677 of 878 Page 677 of 878 ---PAGE BREAK--- Page 678 of 878 Page 678 of 878 Page 678 of 878 Page 678 of 878 ---PAGE BREAK--- Emergency Overview Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. Combustible liquid and vapor. Suspect cancer hazard. Harmful if swallowed. Causes eye Material Safety Data Sheet 24 Hour Assistance: 1-[PHONE REDACTED] Rust-Oleum Corp. www.rustoleum.com Section 1 - Chemical Product / Company Information Product Name: Rust-Oleum High Performance Industrial Enamel Topcoats Revision Date: 12/16/2004 Identification Number: 1210300, 1210402, 1210504, 1282300, 1282402, 1282504, 2764300, 2764402, 2766300, 2766402, 2766504, 412300, 412402, 412504, 559300, 559402, 634300, 634402, 634504, 721300, 721402, 721504, 7232402, 7280300, 7280402, 7290402, 7434300, 7434402, 7446300, 7446402, 7447402, 7448402, 745300, 745402, 8494402, 865300, 865402, 865504, 865504, 866300, 866402, 904300, 904402, 906300, 906402, 906504, 925300, 925402, 925504, 933402, 935300, 935402, 944300, 944402, 944504, 956300, 956402, 956504, 964300, 964402, 964504, 975300, 975402, 975504, 977300, 977402, 977504, 2766100, 868402, 206455 Product Use/Class: Topcoat/Alkyd Supplier: Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA Manufacturer: Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA Preparer: Department, Regulatory Section 2 - Composition / Information On Ingredients Chemical Name CAS Number Weight % Less Than ACGIH TLV-TWA ACGIH TLV-STEL OSHA PEL-TWA OSHA PEL-CEILING Stoddard Solvents 8052-41-3 50.0 100 PPM N.E. 500 PPM N.E. Titanium Dioxide 13463-67-7 25.0 10 mg/m3 N.E. 10 mg/m3 N.E. Calcined Aluminum Silicate 1332-58-7 20.0 2 mg/m3 N.E. 5 mg/m3 N.E. Pigment Red 3 2425-85-6 10.0 N.E. N.E. N.E. N.E. Pigment Orange 5 3468-63-1 10.0 2mg/m3. N.E 5mg/m3 N.E. Magnesium Silicate 14807-96-6 10.0 10 mg/m3 N.E. 15 mg/m3 N.E. Pigment Yellow 74 6358-31-2 10.0 N.E. N.E. N.E. N.E. Pigment Black 7 1333-86-4 5.0 3.5 mg/m3 N.E. 3.5 mg/m3 N.E. Pigment Green 7 1328-53-6 5.0 N.E. N.E. N.E. N.E. 100-41-4 1.0 100 PPM 125 PPM 100 PPM N.E. Section 3 - Hazards Identification Page 1 of 6 Page 679 of 878 Page 679 of 878 Page 679 of 878 Page 679 of 878 ---PAGE BREAK--- irritation. Vapors irritating to eyes and respiratory tract. Effects Of Overexposure - Eye Contact: Causes eye irritation. Effects Of Overexposure - Skin Contact: May cause skin irritation. Effects Of Overexposure - Inhalation: High vapor concentrations are irritating to the eyes, nose, throat and lungs. May cause headaches and dizziness. Harmful if inhaled. Effects Of Overexposure - Ingestion: Aspiration hazard if swallowed; can enter lungs and cause damage. Substance may be harmful if swallowed. Effects Of Overexposure - Chronic Hazards: IARC lists as a possible human carcinogen (group 2B). Suspect cancer hazard--contains material which may cause cancer. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. Contains carbon black. Chronic inflammation, lung fibrosis, and lung tumors have been observed in some rats experimentally exposed for long periods of time to excessive concentrations of carbon black and several insoluble fine dust particles. Tumors have not been observed in other animal species mouse and hampster) under similar circumstances and study conditions. Epidemiological studies of North American workers show no evidence of clinically significant adverse health effects due to occupational exposure to carbon black. Carbon black is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC and is proposed to be listed as A4- "not classified as a human carcinogen" by the American Conference of Govermental Industrial Hygienists. Significant exposure is not anticipated during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of carbon black in the formula. Primary Route(s) Of Entry: Skin Contact, Inhalation, Eye Contact First Aid - Eye Contact: Hold eyelids apart and flush with plenty of water for at least 15 minutes. Get medical attention. First Aid - Skin Contact: Wash with soap and water. Get medical attention if irritation develops or persists. First Aid - Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. First Aid - Ingestion: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. Extinguishing Media: Dry Chemical, Foam, Water Fog Unusual Fire And Explosion Hazards: Keep containers closed. Special Firefighting Procedures: Evacuate area and fight fire from a safe distance. Water may be used to cool Section 4 - First Aid Measures Section 5 - Fire Fighting Measures Flash Point: 104 F LOWER EXPLOSIVE LIMIT: 0.9 % (Setaflash) UPPER EXPLOSIVE LIMIT : 22.7 % Page 2 of 6 Page 680 of 878 Page 680 of 878 Page 680 of 878 Page 680 of 878 ---PAGE BREAK--- closed containers to prevent pressure buildup and possible autoignition or explosion. Steps To Be Taken If Material Is Released Or Spilled: Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Handling: Avoid contact with eyes. Avoid breathing vapor or mist. Wash hands before eating. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Wash thoroughly after handling. Storage: Keep away from heat, sparks, flame and sources of ignition. Keep containers closed. Isolate from heat, electrical equipment, sparks and open flame. Keep container closed when not in use. Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation. Respiratory Protection: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. Skin Protection: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection. Eye Protection: Use safety eyewear designed to protect against splash of liquids. Other protective equipment: Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application. Hygienic Practices: Wash thoroughly with soap and water before eating, drinking or smoking. Section 6 - Accidental Release Measures Section 7 - Handling And Storage Section 8 - Exposure Controls / Personal Protection Section 9 - Physical And Chemical Properties Boiling Range: 232 - 400 F Vapor Density: Heavier than air Odor: Solvent Like Odor Threshold: ND Appearance: Liquid Evaporation Rate: Slower than Ether Solubility in H2O: Slight Freeze Point: ND Specific Gravity: 1.0800 Vapor Pressure: PH: NE Physical State: Liquid Page 3 of 6 Page 681 of 878 Page 681 of 878 Page 681 of 878 Page 681 of 878 ---PAGE BREAK--- (See section 16 for abbreviation legend) Conditions To Avoid: Avoid all possible sources of ignition. Incompatibility: Incompatible with strong oxidizing agents, strong acids and strong alkalies. Hazardous Decomposition: When heated to decomposition it emits acrid smoke and irritating fumes. By open flame, carbon monoxide and carbon dioxide. Hazardous Polymerization: Will not occur under normal conditions. Stability: This product is stable under normal storage conditions. Ecological Information: Product is a mixture of listed components. Disposal Information: Dispose of material in accordance to local, state and federal regulations and ordinances. Do not allow to enter storm drains or sewer systems. Section 10 - Stability And Reactivity Section 11 - Toxicological Information Product LD50: ND Product LC50: ND Chemical Name LD50 LC50 Stoddard Solvents N.D. N.D. Titanium Dioxide >7500 mg/kg (ORAL, RAT) N.D. Calcined Aluminum Silicate N.D. N.D. Pigment Red 3 >2000 mg/kg (ORAL, RAT) N.D. Pigment Orange 5 N.D. N.D. Magnesium Silicate N.D. TCLo:11mg/m3 inh. Pigment Yellow 74 >15000 mg/kg (ORAL, RAT) N.D. Pigment Black 7 >8000 mg/kg (ORAL, RAT) N.D. Pigment Green 7 >5000 mg/kg (ORAL, RAT) N.D. 3500 mg/kg (ORAL, RAT) N.D. Section 12 - Ecological Information Section 13 - Disposal Information Section 14 - Transportation Information Page 4 of 6 Page 682 of 878 Page 682 of 878 Page 682 of 878 Page 682 of 878 ---PAGE BREAK--- CERCLA - SARA Hazard Category This product has been reviewed according to the EPA "Hazard Categories" promulgated under Sections 311and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD SARA Section 313: Listed below are the substances (if any) contained in this product that are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Toxic Substances Control Act: Listed below are the substances (if any) contained in this product that are subject to the reporting requirements of TSCA 12(B) if exported from the United States: None known U.S. State Regulations: As follows - New Jersey Right-to-Know: The following materials are non-hazardous, but are among the top five components in this product. Right-to-Know: The following non-hazardous ingredients are present in the product at greater than DOT Proper Shipping Name: Paint Packing Group: III DOT Technical Name: Hazard Subclass: DOT Hazard Class: 3 Resp. Guide Page: 127 DOT UN/NA Number: UN 1263 Section 15 - Regulatory Information Chemical Name CAS Number Pigment Green 7 1328-53-6 100-41-4 Chemical Name CAS Number Calcium Carbonate 1317-65-3 Alkyd Resin PROPRIETARY Alkyd Resin PROPRIETARY Chemical Name CAS Number Calcium Carbonate 1317-65-3 Alkyd Resin PROPRIETARY Page 5 of 6 Page 683 of 878 Page 683 of 878 Page 683 of 878 Page 683 of 878 ---PAGE BREAK--- California Proposition 65: WARNING! This product contains a chemical(s) known by the State of California to cause cancer. These products contain no known chemicals known by the State of California to cause birth defects or other reproductive harm. International Regulations: As follows - CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings. CANADIAN WHMIS CLASS: B3 D2B VOLATILE ORGANIC COMPOUNDS, g/l: <450 REASON FOR REVISION: Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined The information contained on this MSDS has been checked and should be accurate. However, it is the responsibility of the user to comply with all Federal, State, and Local laws and regulations. Alkyd Resin PROPRIETARY Red Iron Oxide 1332-37-2 Yellow Iron Oxide 51274-00-1 Iron Oxide 1309-37-1 Section 16 - Other Information HMIS Ratings: Health: 2* Flammability: 2 Reactivity: 0 Personal Protection: X Page 6 of 6 Page 684 of 878 Page 684 of 878 Page 684 of 878 Page 684 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Product Name Safe Step Ice Melter . 1. Product and Company Identification space CAS # Mixture space Product use De-icer. space Manufacturer North American Salt Company A Compass Minerals Company 9900 West 109th Street, Suite 600 Overland Park, KS 66210 US Phone: [PHONE REDACTED] space CHEMTREC 1-[PHONE REDACTED] space CANUTEC 1-[PHONE REDACTED] space Personal Protection Physical Hazard Flammability Health E 0 0 1 / Minimal Slight Moderate Serious LEGEND 4 3 2 1 0 Severe 0 1 0 HMIS/NFPA space Emergency overview CAUTION May cause eye and skin irritation. . 2. Hazards Identification space Routes of exposure Potential short term health effects Eye, Skin contact, Inhalation, Ingestion. space Eyes May cause irritation. space Skin May cause irritation. space Inhalation Dusts of this product may cause irritation of the nose, throat, and respiratory tract. space Ingestion May cause stomach distress, nausea or vomiting. space Target organs Eyes. Skin. Respiratory system. space Chronic effects Prolonged or repeated exposure can cause drying, defatting and dermatitis. space Signs and may include redness, edema, drying, defatting and cracking of the skin. of overexposure may be headache, dizziness, tiredness, nausea and vomiting. space Ingredient(s) CAS # Percent 40 - 60 7447-40-7 Potassium chloride 40 - 60 7647-14-5 Sodium chloride 0.1 - 1 57-13-6 Urea . 3. Composition / Information on Ingredients space Eye contact First aid procedures Flush with cool water. Remove contact lenses, if applicable, and continue flushing. Obtain medical attention if irritation persists. . 4. First Aid Measures space Skin contact Flush with cool water. Wash with soap and water. Obtain medical attention if irritation persists. space Inhalation If develop move victim to fresh air. If persist, obtain medical attention. space Page 1 of 6 #12472 30-Oct-2008 Issue date Page 685 of 878 Page 685 of 878 Page 685 of 878 Page 685 of 878 ---PAGE BREAK--- Ingestion Do not induce vomiting. Rinse mouth with water, then drink one or two glasses of water. Obtain medical attention. Never give anything by mouth if victim is unconscious, or is convulsing. space Notes to physician may be delayed. space General advice If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Keep out of reach of children. space Flammable properties Not flammable by WHMIS/OSHA criteria. . 5. Fire Fighting Measures space Suitable extinguishing media Extinguishing media Treat for surrounding material. space Unsuitable extinguishing media Not available space Specific hazards arising from the chemical Protection of firefighters Not available space Protective equipment for firefighters Firefighters should wear full protective clothing including self contained breathing apparatus. space Hazardous combustion products May include and are not limited to: Hydrogen chloride. Chlorine gas. space Sensitivity to mechanical impact Explosion data Not available space Sensitivity to static discharge Not available space Personal precautions Before attempting clean up, refer to hazard data given above. Use broom or dry vacuum to collect material for proper disposal without raising dust. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. . 6. Accidental Release Measures space Methods for containment Prevent entry into waterways, sewers, basements or confined areas. space Methods for cleaning up Before attempting clean up, refer to hazard data given above. Use broom or dry vacuum to collect material for proper disposal without raising dust. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. space Handling Avoid breathing dusts from this material. Use good industrial hygiene practices in handling this material. . 7. Handling and Storage space Storage Keep out of reach of children. Keep containers closed in a cool, well-ventilated place. space Page 2 of 6 #12472 30-Oct-2008 Issue date Page 686 of 878 Page 686 of 878 Page 686 of 878 Page 686 of 878 ---PAGE BREAK--- Exposure limits Ingredient(s) Potassium chloride Exposure Limits Not established ACGIH-TLV OSHA-PEL Not established Sodium chloride Not established ACGIH-TLV OSHA-PEL Not established Urea Not established ACGIH-TLV OSHA-PEL Not established . 8. Exposure Controls / Personal Protection space Engineering controls TWA PEL: No specific limits have been established for potassium chloride or sodium chloride (soluble substances). As a guideline, OSHA (United States) has established the following limits which are generally recognized for inert or nuisance dust. Particulates Not Otherwise Regulated (PNOR): 5mg/cu.m. Respirable Dust 8-Hour TWA PEL, 15mg/cu.m. Total Dust 8-Hour TWA PEL. TWA TLV: No specific limits have been established for potassium chloride or sodium chloride (soluble substances). As a guideline, ACGIH (United States) has established the following limits which are generally recognized for inert or nuisance dust. Particulates (insolubles) Not Otherwise Classified (PNOC): 10mg/cu.m. Inhalable Particulate 8-Hours TWA TLV, 3mg/cu.m. Respirable Particulate TWA TLV. Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. If user operations generate dust, fumes, or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. space Eye / face protection Personal protective equipment Safety glasses space Hand protection Rubber gloves. Confirm with a reputable supplier first. space Skin and body protection As required by employer code. space Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator or NIOSH-approved filtering facepiece. space General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. Wash hands before breaks and immediately after handling the product. space Appearance . 9. Physical & Chemical Properties space Color White space Form space Odor Odorless space Odor threshold Not available space Physical state Solid space pH Not available space Melting point Not available space Freezing point Not available space Boiling point Not available space Flash point Not applicable space Evaporation rate Not available space Page 3 of 6 #12472 30-Oct-2008 Issue date Page 687 of 878 Page 687 of 878 Page 687 of 878 Page 687 of 878 ---PAGE BREAK--- Flammability limits in air, lower, % by volume Not applicable space Flammability limits in air, upper, % by volume Not applicable space Vapor pressure Not available space Vapor density Not available space Specific gravity Not available space Octanol/water coefficient Not available space Solubility (H2O) Partially soluble space Auto-ignition temperature Not available space Percent volatile Not available space Chemical stability Stable under recommended storage conditions. . 10. Chemical Stability & Reactivity Information space Conditions to avoid Do not mix with incompatible materials. space Incompatible materials This product reacts with acids. space Hazardous decomposition products May include and are not limited to: Hydrogen chloride. Chlorine gas. space Possibility of hazardous reactions Hazardous polymerization does not occur. space Component analysis - LC50 Ingredient(s) Potassium chloride LC50 Not available Sodium chloride > 21000 mg/m3 rat Urea Not available . 11. Toxicological Information space Component analysis - Oral LD50 Ingredient(s) Potassium chloride LD50 1500 mg/kg mouse; 2500 mg/kg guinea pig; 2600 mg/kg rat Sodium chloride 3000 mg/kg rat; 4000 mg/kg mouse Urea 11000 mg/kg mouse; 8471 mg/kg rat; 510 mg/kg cattle; 510 mg/kg sheep space Eye Effects of acute exposure May cause irritation. space Skin May cause irritation. space Inhalation Dusts of this product may cause irritation of the nose, throat, and respiratory tract. space Ingestion May cause stomach distress, nausea or vomiting. space Sensitization Not classified or listed by IARC, NTP, OSHA and ACGIH. space Chronic effects Not classified or listed by IARC, NTP, OSHA and ACGIH. space Carcinogenicity Not classified or listed by IARC, NTP, OSHA and ACGIH. space Mutagenicity Not classified or listed by IARC, NTP, OSHA and ACGIH. space Reproductive effects Not classified or listed by IARC, NTP, OSHA and ACGIH. space Teratogenicity Not classified or listed by IARC, NTP, OSHA and ACGIH. space Ecotoxicity May be harmful to freshwater aquatic species and to plants that are not saline tolerant. . 12. Ecological Information space Environmental effects Not available space Aquatic toxicity Not available space Persistence / degradability Not available space Bioaccumulation / accumulation Not available space Partition coefficient Not available space Mobility in environmental media Not available space Page 4 of 6 #12472 30-Oct-2008 Issue date Page 688 of 878 Page 688 of 878 Page 688 of 878 Page 688 of 878 ---PAGE BREAK--- Chemical fate information Not available space Other adverse effects Not available space Waste codes Not available . 13. Disposal Considerations space Disposal instructions Waste must be disposed of in accordance with federal, state/provincial and local environmental control regulations. space Waste from residues / unused products Not available space Contaminated packaging Not available space U.S. Department of Transportation (DOT) Not regulated as dangerous goods. . 14. Transport Information space Transportation of Dangerous Goods (TDG - Canada) Not regulated as dangerous goods. space Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. . 15. Regulatory Information space US Federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. CERCLA/SARA Hazardous Substances - Not applicable. space 29 CFR 1910.1200 hazardous chemical Occupational Safety and Health Administration (OSHA) No space CERCLA (Superfund) reportable quantity None space Hazard categories Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No space Section 302 extremely hazardous substance No space Section 311 hazardous chemical No space Clean Air Act (CAA) Not available space Clean Water Act (CWA) Not available space Safe Drinking Water Act (SDWA) Not available space Drug Enforcement Agency (DEA) Not available space Food and Drug Administration (FDA) Not available space WHMIS status Not Controlled space State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. space A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) Inventory name Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada No Non-Domestic Substances List (NDSL) United States & Puerto Rico Yes Toxic Substances Control Act (TSCA) Inventory space Page 5 of 6 #12472 30-Oct-2008 Issue date Page 689 of 878 Page 689 of 878 Page 689 of 878 Page 689 of 878 ---PAGE BREAK--- Disclaimer Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. . 16. Other Information space Issue date 30-Oct-2008 space Effective date 31-Oct-2008 space Expiry date 31-Oct-2011 space Prepared by Dell Tech Laboratories Ltd. (519) 858-5021 space Page 6 of 6 #12472 30-Oct-2008 Issue date Page 690 of 878 Page 690 of 878 Page 690 of 878 Page 690 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) TILE AND GROUT PROTECTOR 08/03/11 Page 1 of 8 Material Safety Data Sheet Copyright, 2011, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: the information is copied in full with no changes unless prior written agreement is obtained from 3M, and neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: SCOTCHGARD(TM) TILE AND GROUT PROTECTOR MANUFACTURER: 3M DIVISION: Building & Commercial Services Division ADDRESS: 3M Center, St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-[PHONE REDACTED] or (651) 737-6501 (24 hours) Issue Date: 08/03/11 Supercedes Date: 01/10/05 Document Group: 17-8304-2 Product Use: Intended Use: Hard Surface Cleaner SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt 100-41-4 < 0.1 WATER 7732-18-5 60 - 100 METHYL HYDROGEN POLYSILOXANE 63148-57-2 1 - 5 556-67-2 .1 - 5 2943-75-1 0.1 - 1 TRIMETHYLATED SILICA 68988-56-7 0.1 - 1 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Liquid Odor, Color, Grade: White, slight odor. General Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. 3.2 POTENTIAL HEALTH EFFECTS Page 691 of 878 Page 691 of 878 Page 691 of 878 Page 691 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) TILE AND GROUT PROTECTOR 08/03/11 Page 2 of 8 Eye Contact: Mild Eye Irritation: may include redness, pain, and tearing. Skin Contact: Mild Skin Irritation: may include localized redness, swelling, and itching. Inhalation: Respiratory Tract Irritation: may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. Get immediate medical attention. Skin Contact: Wash affected area with soap and water. If develop, get medical attention. Inhalation: Remove person to fresh air. If develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point >=212 ºF [Test Method: Closed Cup] Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available OSHA Flammability Classification: Class IIIB Combustible Liquid 5.2 EXTINGUISHING MEDIA Ordinary combustible material. Use fire extinguishers with class A extinguishing agents water, foam). 5.3 PROTECTION OF FIRE FIGHTERS Page 692 of 878 Page 692 of 878 Page 692 of 878 Page 692 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) TILE AND GROUT PROTECTOR 08/03/11 Page 3 of 8 Special Fire Fighting Procedures: See Hazardous Decomposition section for products of combustion. Unusual Fire and Explosion Hazards: Not applicable. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Clean-up methods Observe precautions from other sections. Call 3M- HELPS line (1-[PHONE REDACTED]) for more information on handling and managing the spill. Contain spill. Cover or dilute with water. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with water. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Keep out of the reach of children. Avoid breathing of vapors, mists or spray. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep container closed when not in use. Avoid contact with oxidizing agents. Do not mix this product with alcohols or bases. 7.2 STORAGE Store away from areas where product may come into contact with food or pharmaceuticals. Keep container in well-ventilated area. Store away from acids. Store away from oxidizing agents. Store away from strong bases. Protect from freezing. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use in a well-ventilated area. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact. The following eye protection(s) are recommended: Safety Glasses with side shields . Page 693 of 878 Page 693 of 878 Page 693 of 878 Page 693 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) TILE AND GROUT PROTECTOR 08/03/11 Page 4 of 8 8.2.2 Skin Protection Avoid prolonged or repeated skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Butyl Rubber Neoprene . 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information 1,2-Propanediol AIHA TWA, as aerosol 10 mg/m3 Benzene, dimethyl- ACGIH TWA 100 ppm Benzene, dimethyl- ACGIH STEL 150 ppm Benzene, dimethyl- OSHA TWA 435 mg/m3 ACGIH TWA 100 ppm ACGIH STEL 125 ppm CMRG TWA 25 ppm CMRG STEL 75 ppm OSHA TWA 435 mg/m3 CMRG TWA 10 ppm SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Liquid Odor, Color, Grade: White, slight odor. General Physical Form: Liquid Autoignition temperature No Data Available Flash Point >=212 ºF [Test Method: Closed Cup] Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Boiling Point >=150 ºF Density 1.001 Vapor Density No Data Available Vapor Pressure <=27 mmHg Specific Gravity Approximately 1.001 [Ref Std: WATER=1] pH Approximately 3 Units not avail. or not appl. Page 694 of 878 Page 694 of 878 Page 694 of 878 Page 694 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) TILE AND GROUT PROTECTOR 08/03/11 Page 5 of 8 Melting point No Data Available Solubility in Water Complete Evaporation rate No Data Available Volatile Organic Compounds Approximately 1.5 % weight [Test Method: calculated per CARB title 2] Kow - Oct/Water partition coef No Data Available Percent volatile <=99 % VOC Less H2O & Exempt Solvents <=550 g/l [Test Method: calculated per CARB title 2] Viscosity >=50 centipoise [Test Method: Brookfield] SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid Not determined 10.2 Materials to avoid Strong acids Strong bases Strong oxidizing agents Alcohols Additional Information: This product will produce hydrogen gas if mixed with alcohols or bases. Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Formaldehyde During Combustion Chlorine During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Gas Moisture Hazardous Decomposition: Hazardous decomposition products may also include metal oxides and silicon dioxide. SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. Page 695 of 878 Page 695 of 878 Page 695 of 878 Page 695 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) TILE AND GROUT PROTECTOR 08/03/11 Page 6 of 8 CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose of waste product in a facility permitted to accept chemical waste. As a disposal alternative, incinerate in an industrial or commercial facility in the presence of a combustible material. EPA Hazardous Waste Number (RCRA): Not regulated Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number UPC ID Number UPC 70-0709-9394-7 00-48011-29696-8 70-0709-9408-5 00-48011-29697-5 70-0709-9738-5 00-48011-29985-3 70-0709-9739-3 00-48011-29986-0 For Transport Information, please visit http://3M.com/Transportinfo or call 1-[PHONE REDACTED] or [PHONE REDACTED]. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes STATE REGULATIONS CALIFORNIA PROPOSITION 65 Ingredient C.A.S. No. Classification 100-41-4 **Carcinogen WARNING: contains a chemical which can cause cancer. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. The components of this product are listed on the Canadian Domestic Substances List. All components of this product are listed on the Inventory of Existing Chemical Substances in China or are exempt. INTERNATIONAL REGULATIONS This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION Page 696 of 878 Page 696 of 878 Page 696 of 878 Page 696 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) TILE AND GROUT PROTECTOR 08/03/11 Page 7 of 8 NFPA Hazard Classification Health: 1 Flammability: 1 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 2 Flammability: 1 Reactivity: 0 Protection: X - See PPE section. Hazardous Material Identification System (HMIS®) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint and Coatings Association (NPCA). Reason for Reissue: European Statements Revision Changes: Section 1: Product use information was modified. Section 16: HMIS hazard classification for health was modified. Section 1: Division name was modified. Section 16: Disclaimer (second paragraph) was modified. Section 3: Potential effects from skin contact information was modified. Section 3: Potential effects from inhalation information was modified. Section 3: Potential effects from ingestion information was modified. Section 7: Handling information was modified. Section 7: Storage information was modified. Section 8: Engineering controls information was modified. Section 8: Eye/face protection phrase was modified. Section 8: Skin protection phrase was modified. Section 8: Respiratory protection information was modified. Section 13: Waste disposal method information was modified. Section 8: Eye/face protection information was modified. Section 8: Skin protection - recommended gloves information was modified. Section 4: First aid for inhalation - termination of exposure - was modified. Section 4: First aid for inhalation - medical assistance - was modified. Section 14: Transportation legal text was modified. Section 15: 311/312 Delayed Hazard score was modified. Section 15: Inventories information was modified. Section 9: Boiling point information was modified. Section 5: Flammable limits (UE) information was modified. Section 5: Flammable limits (LEL) information was modified. Section 9: Property description for optional properties was modified. Section 9: Flammable limits (LEL) information was modified. Section 9: Flammable limits (UEL) information was modified. Section 3: Other potential health effects heading was added. Section 13: EPA hazardous waste number (RCRA) heading was added. Section 13: EPA hazardous waste number (RCRA) information was added. Section 3: Immediate other hazard(s) was added. Section 3: Other health effects information was added. Section 3: Other health effects information (reproductive hazards) was added. Section 14: ID Number(s) and/or UPC(s) Template 1 was added. Section 2: Ingredient table was added. Section 8: Exposure guidelines ingredient information was added. Page 697 of 878 Page 697 of 878 Page 697 of 878 Page 697 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) TILE AND GROUT PROTECTOR 08/03/11 Page 8 of 8 Section 8: Exposure guidelines data source legend was added. Section 15: California proposition 65 ingredient information was added. Section 15: California proposition 65 heading was added. Section 15: California proposition 65 cancer warning was added. Section 6: 6.2. Environmental precautions heading was added. Section 6: 6.1. Personal precautions, protective equipment and emergency procedures heading was added. Section 10.1 Conditions to avoid heading was added. Section 10.2 Materials to avoid heading was added. Section 16: Web address was added. Section 6: Personal precautions information was added. Section 6: Environmental procedures information was added. Section 6: Methods for cleaning up information was added. Section 10: Materials to avoid physical property was added. Section 10: Conditions to avoid physical property was added. Section 1: Address was added. Copyright was added. Company logo was added. Section 6: Clean-up methods heading was added. Telephone header was added. Company Telephone was added. Section 1: Emergency phone information was added. Section 1: Emergency phone information was deleted. Company Logo was deleted. Copyright was deleted. Section 16: Web address heading was deleted. Section 6: Release measures information was deleted. Section 6: Release measures heading was deleted. Section 10: Materials and conditions to avoid physical property was deleted. Section 1: Address line 1 was deleted. Section 1: Address line 2 was deleted. Section 4: First aid for inhalation - none - was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M 3M USA are available at www.3M.com Page 698 of 878 Page 698 of 878 Page 698 of 878 Page 698 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) TILE AND GROUT PROTECTOR 08/03/11 Page 1 of 8 Material Safety Data Sheet Copyright, 2011, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: the information is copied in full with no changes unless prior written agreement is obtained from 3M, and neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: SCOTCHGARD(TM) TILE AND GROUT PROTECTOR MANUFACTURER: 3M DIVISION: Building & Commercial Services Division ADDRESS: 3M Center, St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-[PHONE REDACTED] or (651) 737-6501 (24 hours) Issue Date: 08/03/11 Supercedes Date: 01/10/05 Document Group: 17-8304-2 Product Use: Intended Use: Hard Surface Cleaner SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt 100-41-4 < 0.1 WATER 7732-18-5 60 - 100 METHYL HYDROGEN POLYSILOXANE 63148-57-2 1 - 5 556-67-2 .1 - 5 2943-75-1 0.1 - 1 TRIMETHYLATED SILICA 68988-56-7 0.1 - 1 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Liquid Odor, Color, Grade: White, slight odor. General Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. 3.2 POTENTIAL HEALTH EFFECTS Page 699 of 878 Page 699 of 878 Page 699 of 878 Page 699 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) TILE AND GROUT PROTECTOR 08/03/11 Page 2 of 8 Eye Contact: Mild Eye Irritation: may include redness, pain, and tearing. Skin Contact: Mild Skin Irritation: may include localized redness, swelling, and itching. Inhalation: Respiratory Tract Irritation: may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. Get immediate medical attention. Skin Contact: Wash affected area with soap and water. If develop, get medical attention. Inhalation: Remove person to fresh air. If develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point >=212 ºF [Test Method: Closed Cup] Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available OSHA Flammability Classification: Class IIIB Combustible Liquid 5.2 EXTINGUISHING MEDIA Ordinary combustible material. Use fire extinguishers with class A extinguishing agents water, foam). 5.3 PROTECTION OF FIRE FIGHTERS Page 700 of 878 Page 700 of 878 Page 700 of 878 Page 700 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) TILE AND GROUT PROTECTOR 08/03/11 Page 3 of 8 Special Fire Fighting Procedures: See Hazardous Decomposition section for products of combustion. Unusual Fire and Explosion Hazards: Not applicable. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Clean-up methods Observe precautions from other sections. Call 3M- HELPS line (1-[PHONE REDACTED]) for more information on handling and managing the spill. Contain spill. Cover or dilute with water. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with water. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Keep out of the reach of children. Avoid breathing of vapors, mists or spray. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep container closed when not in use. Avoid contact with oxidizing agents. Do not mix this product with alcohols or bases. 7.2 STORAGE Store away from areas where product may come into contact with food or pharmaceuticals. Keep container in well-ventilated area. Store away from acids. Store away from oxidizing agents. Store away from strong bases. Protect from freezing. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use in a well-ventilated area. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact. The following eye protection(s) are recommended: Safety Glasses with side shields . Page 701 of 878 Page 701 of 878 Page 701 of 878 Page 701 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) TILE AND GROUT PROTECTOR 08/03/11 Page 4 of 8 8.2.2 Skin Protection Avoid prolonged or repeated skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Butyl Rubber Neoprene . 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information 1,2-Propanediol AIHA TWA, as aerosol 10 mg/m3 Benzene, dimethyl- ACGIH TWA 100 ppm Benzene, dimethyl- ACGIH STEL 150 ppm Benzene, dimethyl- OSHA TWA 435 mg/m3 ACGIH TWA 100 ppm ACGIH STEL 125 ppm CMRG TWA 25 ppm CMRG STEL 75 ppm OSHA TWA 435 mg/m3 CMRG TWA 10 ppm SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Liquid Odor, Color, Grade: White, slight odor. General Physical Form: Liquid Autoignition temperature No Data Available Flash Point >=212 ºF [Test Method: Closed Cup] Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Boiling Point >=150 ºF Density 1.001 Vapor Density No Data Available Vapor Pressure <=27 mmHg Specific Gravity Approximately 1.001 [Ref Std: WATER=1] pH Approximately 3 Units not avail. or not appl. Page 702 of 878 Page 702 of 878 Page 702 of 878 Page 702 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) TILE AND GROUT PROTECTOR 08/03/11 Page 5 of 8 Melting point No Data Available Solubility in Water Complete Evaporation rate No Data Available Volatile Organic Compounds Approximately 1.5 % weight [Test Method: calculated per CARB title 2] Kow - Oct/Water partition coef No Data Available Percent volatile <=99 % VOC Less H2O & Exempt Solvents <=550 g/l [Test Method: calculated per CARB title 2] Viscosity >=50 centipoise [Test Method: Brookfield] SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid Not determined 10.2 Materials to avoid Strong acids Strong bases Strong oxidizing agents Alcohols Additional Information: This product will produce hydrogen gas if mixed with alcohols or bases. Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Formaldehyde During Combustion Chlorine During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Gas Moisture Hazardous Decomposition: Hazardous decomposition products may also include metal oxides and silicon dioxide. SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. Page 703 of 878 Page 703 of 878 Page 703 of 878 Page 703 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) TILE AND GROUT PROTECTOR 08/03/11 Page 6 of 8 CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose of waste product in a facility permitted to accept chemical waste. As a disposal alternative, incinerate in an industrial or commercial facility in the presence of a combustible material. EPA Hazardous Waste Number (RCRA): Not regulated Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number UPC ID Number UPC 70-0709-9394-7 00-48011-29696-8 70-0709-9408-5 00-48011-29697-5 70-0709-9738-5 00-48011-29985-3 70-0709-9739-3 00-48011-29986-0 For Transport Information, please visit http://3M.com/Transportinfo or call 1-[PHONE REDACTED] or [PHONE REDACTED]. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes STATE REGULATIONS CALIFORNIA PROPOSITION 65 Ingredient C.A.S. No. Classification 100-41-4 **Carcinogen WARNING: contains a chemical which can cause cancer. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. The components of this product are listed on the Canadian Domestic Substances List. All components of this product are listed on the Inventory of Existing Chemical Substances in China or are exempt. INTERNATIONAL REGULATIONS This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION Page 704 of 878 Page 704 of 878 Page 704 of 878 Page 704 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) TILE AND GROUT PROTECTOR 08/03/11 Page 7 of 8 NFPA Hazard Classification Health: 1 Flammability: 1 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 2 Flammability: 1 Reactivity: 0 Protection: X - See PPE section. Hazardous Material Identification System (HMIS®) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint and Coatings Association (NPCA). Reason for Reissue: European Statements Revision Changes: Section 1: Product use information was modified. Section 16: HMIS hazard classification for health was modified. Section 1: Division name was modified. Section 16: Disclaimer (second paragraph) was modified. Section 3: Potential effects from skin contact information was modified. Section 3: Potential effects from inhalation information was modified. Section 3: Potential effects from ingestion information was modified. Section 7: Handling information was modified. Section 7: Storage information was modified. Section 8: Engineering controls information was modified. Section 8: Eye/face protection phrase was modified. Section 8: Skin protection phrase was modified. Section 8: Respiratory protection information was modified. Section 13: Waste disposal method information was modified. Section 8: Eye/face protection information was modified. Section 8: Skin protection - recommended gloves information was modified. Section 4: First aid for inhalation - termination of exposure - was modified. Section 4: First aid for inhalation - medical assistance - was modified. Section 14: Transportation legal text was modified. Section 15: 311/312 Delayed Hazard score was modified. Section 15: Inventories information was modified. Section 9: Boiling point information was modified. Section 5: Flammable limits (UE) information was modified. Section 5: Flammable limits (LEL) information was modified. Section 9: Property description for optional properties was modified. Section 9: Flammable limits (LEL) information was modified. Section 9: Flammable limits (UEL) information was modified. Section 3: Other potential health effects heading was added. Section 13: EPA hazardous waste number (RCRA) heading was added. Section 13: EPA hazardous waste number (RCRA) information was added. Section 3: Immediate other hazard(s) was added. Section 3: Other health effects information was added. Section 3: Other health effects information (reproductive hazards) was added. Section 14: ID Number(s) and/or UPC(s) Template 1 was added. Section 2: Ingredient table was added. Section 8: Exposure guidelines ingredient information was added. Page 705 of 878 Page 705 of 878 Page 705 of 878 Page 705 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) TILE AND GROUT PROTECTOR 08/03/11 Page 8 of 8 Section 8: Exposure guidelines data source legend was added. Section 15: California proposition 65 ingredient information was added. Section 15: California proposition 65 heading was added. Section 15: California proposition 65 cancer warning was added. Section 6: 6.2. Environmental precautions heading was added. Section 6: 6.1. Personal precautions, protective equipment and emergency procedures heading was added. Section 10.1 Conditions to avoid heading was added. Section 10.2 Materials to avoid heading was added. Section 16: Web address was added. Section 6: Personal precautions information was added. Section 6: Environmental procedures information was added. Section 6: Methods for cleaning up information was added. Section 10: Materials to avoid physical property was added. Section 10: Conditions to avoid physical property was added. Section 1: Address was added. Copyright was added. Company logo was added. Section 6: Clean-up methods heading was added. Telephone header was added. Company Telephone was added. Section 1: Emergency phone information was added. Section 1: Emergency phone information was deleted. Company Logo was deleted. Copyright was deleted. Section 16: Web address heading was deleted. Section 6: Release measures information was deleted. Section 6: Release measures heading was deleted. Section 10: Materials and conditions to avoid physical property was deleted. Section 1: Address line 1 was deleted. Section 1: Address line 2 was deleted. Section 4: First aid for inhalation - none - was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M 3M USA are available at www.3M.com Page 706 of 878 Page 706 of 878 Page 706 of 878 Page 706 of 878 ---PAGE BREAK--- Emergency Overview green liquid with solvent odor Class IC - Flammable Liquid Potential Health Effects - Eye: Moderate irritation with redness and minor discomfort after direct splash to eye. Potential Health Effects - Skin: Moderately irritating with possible redness and discomfort. May cause dry skin by dissolving skin oils. Contains a component which can be absorbed through the skin in harmful amounts. Potential Health Effects - Inhalation: Moderately irritating to nose, throat or breathing passages. May cause unconsciousness by depressing the central nervous system after prolonged exposure to high concentrations. Potential Health Effects -Ingestion: Moderately irritating to the mouth, stomach, and digestive system. No ingestion exposure expected with normal occupational use. Potential Health Effects - Chronic Hazards: Eye effects from chronic exposure are unknown. Frequent or prolonged skin contact may cause irritation or a rash (dermatitis). Chronic exposure may cause problems of the liver and bile duct system. Chronic ingestion exposure would be unlikely due to the method of use or physical properties of this product. The components listed in Section 2 may affect the following target organs: Blood. Central Nervous System. Eyes. Gastrointestinal Tract. Hematopoietic System. Kidneys. Liver. System. Peripheral Nervous System. Reproductive System. Respiratory System. Skin. Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Eye Contact First Aid - Eye Contact: If this product contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention. First Aid - Skin Contact: If this product contacts the skin, wash the contaminated skin with soap & water. If this product penetrates the clothing, remove the clothing and wash the skin with soap & water. If irritation persists after washing, get medical attention. Launder clothing before reuse. First Aid - Inhalation: If a person breathes large amounts of this product, move the exposed person to fresh air at once. If breathing is difficult, get medical attention. MATERIAL SAFETY DATA SHEET F4101; SEA FOAM 1. Identification of the Product and Company . Product Code & Product Name: F4101; SEA FOAM Company: Akzo Nobel - Awlgrip North America 2270 Morris Avenue Union, NJ 07083 Tel. [PHONE REDACTED]; Fax [PHONE REDACTED] Health & Safety Information [PHONE REDACTED] Emergency: Emergency telephone (US) CHEMTREC - [PHONE REDACTED] Emergency telephone (Outside US) CHEMTREC - [PHONE REDACTED] NOTE: CHEMTREC numbers to be used only in the event of emergencies involving a spill, leak, fire, exposure or accident involving chemicals. Product Use: Coating 2. Composition / Information on Ingredients Chemical Name CAS Number WT % ACGIH TLV TWAACGIH TLV STELOSHA PEL COSHA PEL TWA TITANIUM DIOXIDE 13463-67-7 15-40 10 mg/m3 dust N.D. N.D. 15 mg/m3 dust METHYL AMYL KETONE 110-43-0 10-30 50 ppm N.D. N.D. 100 ppm 2-ETHOXYETHYL ACETATE 111-15-9 10-30 5 ppm N.D. N.D. 100 ppm 2-BUTOXYETHYL ACETATE 112-07-2 1-5 N.D. N.D. N.D. N.D. 100-41-4 0.1-1.0 100 ppm 125 ppm N.D. 100 ppm 3. Hazards Identification 4. First Aid Measures MSDS: F4101, Page 1 of 4 Page 707 of 878 Page 707 of 878 Page 707 of 878 Page 707 of 878 ---PAGE BREAK--- First Aid - Ingestion: If this product has been swallowed, get medical attention immediately. Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam Unusual Fire And Explosion Hazards: Flammable Liquid. Vapors are heavier than air and may travel to a source of ignition and flash back. Special Fire Fighting Procedures: Firefighters and others exposed to vapors or products of combustion should wear self-contained breathing apparatus. Steps To Be Taken If Material Is Released Or Spilled: Eliminate all ignition sources. Stop or control the spill, if this can be done without undue risk. Do not allow material to enter sewers or ground. Isolate discharged material for proper disposal. Wear appropriate personal protective equipment. Handling: Grounding or bonding of containers is recommended before material transfer. Storage: Storage areas should be dry and well-ventilated. Engineering Controls: It is recommended that work be done in an adequately ventilated area ventilation sufficient to maintain concentrations below one half of the PEL and other relevant standards). Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination. Respiratory Protection: Appropriate respirators must be used, and a program that follows 29 CFR 1910.134 or other applicable regulatory requirements must be followed, when workplace hazards warrant the use of a respirator. NIOSH-approved or other appropriate respirators must be used when respiratory protection is necessary. Eye Protection: Wear appropriate goggles, face shields or other PPE, which will be effective under the circumstances if the possibility of contact exists. A program meeting 29 CFR 1910.133 or other applicable regulatory requirements must be followed when PPE is necessary. Other Protective Equipment: Use impermeable gloves and protective clothing as necessary to prevent skin contact. Hygienic Practices: Do not eat, drink, chew tobacco or gum, or apply cosmetics while working with this product. Wash hands before performing any of these activities. 5. Fire-Fighting Measures . Flash Point 78 LOWER EXPLOSIVE LIMIT: 0.1 UPPER EXPLOSIVE LIMIT: 15.0 6. Accidental Release Measures 7. Handling and Storage 8. Exposure Controls / Personal Protection 9. Physical and Chemical Properties Theoretical Values Boiling Range 252 - 662 VOC (g/l)(less water & exempt): 419 Freeze Point N.D. VOC (lb/gal)(less water & exempt): 3.5 Specific Gravity: 1.3 % Solids By Weight: 68 Appearance: green % Solids By Volume: 53 Physical State: liquid Density (lb/gal): 10.9 Odor: solvent . 10. Stability and Reactivity MSDS: F4101, Page 2 of 4 Page 708 of 878 Page 708 of 878 Page 708 of 878 Page 708 of 878 ---PAGE BREAK--- Conditions To Avoid: Avoid contact with heat, open flame, sparks, or ignition sources. Hazardous Polymerization: Will not occur. Stability: Stable. Akzo Nobel has not conducted specific studies on the eco toxicity or environmental fate of this product. Commonly available data on certain ingredients indicate that acute or chronic effects could result from uncontrolled releases to soil, ground water, storm waters, or air. Appropriate measures should be taken to prevent uncontrolled releases. Prompt containment and clean up should be performed if releases do occur. Legal disposition of wastes is the responsibility of the owner/generator of the waste. Applicable federal, state, and/or local regulations must be followed during treatment, storage, or disposal of waste containing this product. Do not dispose of in an uncontrolled manner. U.S. FEDERAL REGULATIONS: As follows - CERCLA - SARA Hazard Category: This product is considered, under applicable definitions, to meet the following categories: IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD SARA Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and 40 CFR 372: Clean Air Act: This product contains the following chemical substances listed as Hazardous Air Pollutants (HAPs) under the Clean Air Act of 1990: Toxic Substances Control Act: All the components of this product comply with applicable requirements of the US EPA TSCA inventory. Contains chemical(s) subject to the reporting requirements of TSCA 12b if exported from the US. U.S. STATE REGULATIONS: As follows - 11. Toxicological Information Chemical Name LD50 LC50 IARC NTP OSHA TITANIUM DIOXIDE N.D. N.D. METHYL AMYL KETONE Oral Rat: 1600 mg/kg N.D. 2-ETHOXYETHYL ACETATE Oral Rat: 2700 mg/kg Inhalation Rat: 12100 mg/m3/8H 2-BUTOXYETHYL ACETATE Oral Rat: 2400 mg/kg N.D. Oral Rat: 3500 mg/kg N.D. Group 2B 12. Ecological Information 13. Disposal Considerations 14. Transport Information . DOT Proper Shipping Name: Paint IATA Proper Shipping Name: Paint IMO Proper Shipping Name: Paint DOT Hazard Class: 3 IATA Hazard Class: 3 IMO Hazard Class: 3 DOT UN Number: UN1263 IATA UN Number: UN1263 IMO UN Number: UN1263 DOT Packing Group: III IATA Packing Group: III IMO Packing Group: III Resp. Guide Page: 128 IATA Hazard Subclass: N/A Marine Pollutant: No Chemical Name CAS Number RQ (lbs) 100-41-4 1000 15. Regulatory Information Chemical Name 313 Category CAS Number WT % 2-ETHOXYETHYL ACETATE Glycol Ethers 111-15-9 12.3 2-BUTOXYETHYL ACETATE Glycol Ethers 112-07-2 3.3 100-41-4 0.3 Chemical Name HAP Category CAS Number WT % 2-ETHOXYETHYL ACETATE Glycol Ethers 111-15-9 12.3 2-BUTOXYETHYL ACETATE Glycol Ethers 112-07-2 3.3 100-41-4 0.3 MSDS: F4101, Page 3 of 4 Page 709 of 878 Page 709 of 878 Page 709 of 878 Page 709 of 878 ---PAGE BREAK--- California Proposition 65: WARNING: This product contains chemicals known to the State of CA to cause cancer and birth defects or other reproductive harm. INTERNATIONAL REGULATIONS: As follows - Canadian WHMIS Class: B2, D2 Korean Inventory - All the components of this product are listed or are exempt from listing. Legend: N.A. - Not Applicable, N.D. - Not Determined This MSDS relates only to the specific material identified in Section 2. In compiling this MSDS, Akzo Nobel has relied in good faith on information provided to Akzo Nobel by suppliers of the components of this material, and, in some cases, provided by independent data resources. Akzo Nobel has not independently verified such information, and, in addition, users should be aware that all materials may present unknown hazards. Use of this material in combination with other materials and/or in specific processes may render information set forth in the MSDS inaccurate or otherwise invalid. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE REGARDING THE INFORMATION FURNISHED ON THIS MSDS. Revision Date: 09/23/2004 16. Other Information . National Paint & Coatings Association (NPCA) Hazardous Material Identification System (HMIS): Health: 3 Flammability: 3 Reactivity: 0 Personal Protection: See Section 8 MSDS: F4101, Page 4 of 4 Page 710 of 878 Page 710 of 878 Page 710 of 878 Page 710 of 878 ---PAGE BREAK--- Sea Foam Sales Company P.O. Box 5178 Hopkins, MN 55343-1178 Phone (952)938-4811 MATERIAL SAFETY DATA INFORMATION FOR SEA FOAM MOTOR TREATMENT Part No. SF-16, SF-128 SEA FOAM TRANS TUNE Part No. TT-16 Note: Each product contains the same ingredients; however, the percentage of each ingredient varies within the limits of the printed percentages, depending on the use of each product SECTION I IDENTITY AS USED ON LABEL AND LIST Motor Treatment and Trans Tune Sea Foam Formula: Proprietary Blend Date Prepared: 1-26-2006 Emergency (800)535-5053 MFG. Code ID: 34066 SECTION II-A HAZARDOUS COMPONENTS NO. COMPONENT EPC# % BY WT. 1 PALE OIL 4229 40-60% 2 NAPHTHA 20 25-35% 3 IPA 125 10-20% NONE OF THE COMPONENTS OF THIS PRODUCT ARE RECOGNIZED AS CARCINOGENIC. SECTION II-B OCCUPATIONAL EXPOSURE LIMITS NO. (OSHA) PEL/TWA PEL/CEILING NO. (OSHA) PEL/STEL SKIN* 1 5.000mg/m3 N/E 1 N/E N 2 300.000ppm N/E 2 400.000ppm N 3 400.000ppm N/E 3 500.000ppm N NO. (ACGIH) TLV/TWA TLV/CEILING NO. (AC GIH) TLV/STEL SKIN* 1 5.000mg/m3 N/E 1 10.000mg/m3 N 2 300.000ppm N/E 2 N/E N 3 400.000ppm N/E 3 500.000ppm N * (SKIN) ABSORPTION MAY CONTRIBUTE TO THE OVERALL EXPOSURE TO THIS MATERIAL. TAKE APPROPRIATE MEASURES TO PREVENT SKIN CONTACT. SECTION III PHYSICAL DATA BOILING POINT : 180 (DEGREES F) EVAPORATION RATE: < 1 (ETHER = 1) % SOLID : 40-60% (THEORETICAL) VAPOR DENSITY : > 1 (AIR = 1) WEIGHT PER GALLON : 6.93 (THEORETICAL) (Boiling point represents boiling point of lowest boiling raw material.) SECTION IV HEALTH INFORMATION - EYE CONTACT - BASED ON THE PRESENCE OF COMPONENTS 2 AND 3 PRODUCT IS PRESUMED TO BE MODERATELY IRRITATING TO THE EYES. BASED ON THE PRESENCE OF COMPONENTS 2 AND 3 PRODUCT VAPORS AND/OR MISTS MAY ALSO BE IRRITATING TO THE EYES. - SKIN CONTACT - EXPOSURE MAY PRODUCE SKIN IRRITATION. BASED ON THE PRESENCE OF COMPONENTS 2 AND 3 PROLONGED OR REPEATED CONTACT MAY RESULT IN DEFATTING AND DRYING OF THE SKIN WHICH MAY RESULT IN DERMATITIS. - INHALATION - EXPOSURE MAY PRODUCE IRRITATION TO THE NOSE, THROAT, RESPIRATORY TRACT, AND OTHER MUCOUS MEMBRANES. BASED ON THE PRESENCE OF COMPONENTS 2 AND 3 EXPOSURE TO HIGH CONCENTRATIONS OF VAPOR MAY PRODUCE CENTRAL NERVOUS SYSTEM DEPRESSION. - INGESTION - BASED ON THE PRESENCE OF COMPONENTS 2 AND 3 PRODUCT IS PRESUMED TO BE TOXIC. BASED ON THE PRESENCE OF COMPONENT 3 INGESTION MAY CAUSE KIDNEY DAMAGE. BASED ON THE PRESENCE OF COMPONENT 3 INGESTION MAY CAUSE LIVER DAMAGE. BASED ON THE PRESENCE OF COMPONENTS 2 AND 3 SMALL AMOUNTS OF THE LIQUID ASPIRATED INTO THE LUNGS DURING INGESTION OR FROM VOMITING MAY RESULT IN SEVERE LUNG DAMAGE. BASED ON THE PRESENCE OF COMPONENT 3 INGESTION MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. - SIGNS AND - OF EYE IRRITATION INCLUDE PAIN, TEARING, REDDENING AND SWELLING. OF SKIN IRRITATION INCLUDE REDDENING, SWELLING, RASH AND REDNESS. OF RESPIRATORY IRRITATION INCLUDE RUNNY NOSE, SORE THROAT, COUGHING, CHEST DISCOMFORT, SHORTNESS OF BREATH AND REDUCED LUNG FUNCTION. OF GASTROINTESTIONAL IRRITATION INCLUDE SORE THROAT, ABDOMINAL PAIN, NAUSEA, VOMITING AND DIARRHEA. BASED ON THE PRESENCE OF COMPONENTS 2 AND 3 CENTRAL NERVOUS SYSTEM DEPRESSION MAY BE EVIDENCED BY HEADACHE, DIZZINESS, NAUSEA AND OF INTOXICATION; IN EXTREME CASES, UNCONSCIOUSNESS AND DEATH MAY OCCUR. OF CHRONIC OVEREXPOSURE INCLUDE LOSS OF MEMORY, LOSS OF INTELLECTUAL ABILITY AND LOSS OF COORDINATION. - AGGRAVATED MEDICAL CONDITIONS - PREEXISTING SKIN, EYE AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY Page 711 of 878 Page 711 of 878 Page 711 of 878 Page 711 of 878 ---PAGE BREAK--- - OTHER HEALTH EFFECTS - BASED ON THE PRESENCE OF COMPONENT 3 PRODUCT IS PRESUMED TO BE FETOTOXIC. BASED ON THE PRESENCE OF COMPONENT 3 PRODUCT IS PRESUMED TO BE MUTAGENIC. BASED ON THE PRESENCE OF COMPONENT 2 CHRONIC OVEREXPOSURE MAY CAUSE DAMAGE TO THE KIDNEYS. SECTION V EMERGENCY AND FIRST AID PROCEDURES - EYE CONTACT - IMMEDIATELY FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION IF ANY PERSIST. - SKIN CONTACT - REMOVE CONTAMINATED CLOTHING AND SHOES. WIPE EXCESS FROM SKIN AND FLUSH WITH WATER USING SOAP IF AVAILABLE. SEEK MEDICAL ATTENTION IF IRRITATION OCCURS. DO NOT REUSE CLOTHING UNTIL THOROUGHLY DECONTAMINATED. - INHALATION - REMOVE VICTIM TO FRESH AIR AND TREAT PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GIVE ARTIFICIAL RESPIRATION IF THE VICTIM IS NOT BREATHING. SEEK PROMPT MEDICAL ATTENTION. - INGESTION - DO NOT INDUCE VOMITING. IF VOMITING SPONTANEOUSLY OCCURS, KEEP THE VICTIM'S HEAD BELOW THE HIPS TO PREVENT ASPIRATION INTO THE LUNGS. SINCE ASPIRATION INTO THE LUNGS CAN CAUSE VERY SERIOUS, PERMANENT DAMAGE, THE DECISION OF WHETHER TO INDUCE VOMITING OR NOT SHOULD BE MADE BY A PHYSICIAN. DANGER FROM LUNG ASPIRATION MUST BE WEIGHED AGAINST TOXICITY WHEN CONSIDERING EMPTYING THE STOMACH. CONSULT A PHYSICIAN, HOSPITAL OR POISON CONTROL CENTER AND/OR TRANSPORT TO AN EMERGENCY FACILITY IMMEDIATELY. - NOTES FOR PHYSICIAN - THE FOLLOWING COMPONENT-SPECIFIC INFORMATION MAY CONTAIN CONTRADICTIONS, AND IS INTENTIONALLY INCLUDED TO GIVE THE ATTENDING PHYSICIAN SPECIFIC INFORMATION ABOUT THE INDIVIDUAL COMPONENTS OF THE BLEND. COMPONENTS 2 AND 3 MAY CAUSE SEVERE, PERMANENT DAMAGE IF ASPIRATED AND VOMITING SHOULD NOT BE INDUCED. SECTION VI FIRE AND EXPLOSION HAZARDS FLASH POINT : 55 DEGREES F. TCC - EXTINGUISHING MEDIA - USE WATER FOG, FOAM, DRY CHEMICAL OR CARBON DIOXIDE. - SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS - WARNING. FLAMMABLE. CLEAR FIRE AREA OF UNPROTECTED PERSONNEL. DO NOT ENTER CONFINED FIRE SPACE WITHOUT HELMET, FACE SHIELD, BUNKER COAT, GLOVES, RUBBER BOOTS, AND A POSITIVE PRESSURE NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. - UNUSUAL FIRE AND EXPLOSION HAZARDS - CONTAINERS EXPOSED TO INTENSE HEAT FROM FIRES SHOULD BE COOLED WITH WATER TO PREVENT VAPOR PRESSURE BUILDUP WHICH COULD RESULT IN CONTAINER RUPTURE. CONTAINERS THAT ARE EXPOSED TO DIRECT FLAME SHOULD BE COOLED WITH WATER TO ELIMINATE STRUCTURAL WEAKENING OF THE CONTAINER'S WALL AND POSSIBLE RUPTURE. SECTION VII REACTIVITY STABILITY : STABLE HAZARDOUS POLYMERIZATION : WILL NOT OCCUR - CONDITIONS AND MATERIALS TO AVOID - BASED ON THE PRESENCE OF COMPONENTS 1, 2 AND 3 AVOID OXIDIZING MATERIALS. - HAZARDOUS DECOMPOSITION PRODUCTS - CARBON DIOXIDE, CARBON MONOXIDE AND UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION. SECTION VIII EMPLOYEE PROTECTION - RESPIRATORY PROTECTION - USE VENTILATION AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS - AT LEAST 10 AIR CHANGES PER HOUR ARE RECOMMENDED FOR GOOD GENERAL ROOM VENTILATION. IF EXPOSURE EXCEEDS THE PEL/TLV, USE THE APPROPRIATE NIOSH-APPROVED RESPIRATOR. - PROTECTIVE CLOTHING - WEAR SAFTEY GLASSES, GOGGLES, OR A SPLASH SHIELD TO PREVENT EYE CONTACT. CONTACT LENSES SHOULD NOT BE WORN. WEAR APPROPRIATE GLOVES AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND CLOTHING. - ADDITIONAL PROTECTIVE MEASURES - EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE FOR USE IN AN EMERGENCY. SECTION IX ENVIRONMENTAL PROTECTION - SPILL OR LEAK PROCEDURES - LARGE SPILLS EVACUATE THE HAZARD AREA OF UNPROTECTED PERSONNEL. WEAR APPROPRIATE RESPIRATOR AND PROTECTIVE CLOTHING. SHUT OFF SOURCE OF LEAK ONLY IF SAFE TO DO SO. DIKE AND CONTAIN. IF VAPOR CLOUD FORMS, WATER FOG MAY BE USED TO SUPPRESS; CONTAIN RUN-OFF. REMOVE WITH VACUUM TRUCKS OR PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE WITH AN ABSORBENT SUCH AS CLAY, SAND OR OTHER SUITABLE MATERIAL; PLACE IN NON-LEAKING CONTAINERS FOR PROPER DISPOSAL. FLUSH AREA WITH WATER TO REMOVE TRACE RESIDUE; DISPOSE OF FLUSH SOLUTIONS AS ABOVE. SMALL SPILLS TAKE UP WITH AN ABSORBENT MATERIAL AND PLACE IN NON-LEAKING CONTAINERS; SEAL FOR PROPER DISPOSAL. - WASTE DISPOSAL - OBSERVE ALL FEDERAL, STATE, AND LOCAL REGULATIONS REGARDING PROPER DISPOSAL. SECTION X ADDITIONAL PRECAUTIONS KEEP LIQUID AND VAPOR AWAY FROM HEAT, SPARKS, AND FLAME. EXTINGUISH PILOT LIGHTS, CIGARETTES AND TURN OFF OTHER POSSIBLE SOURCES OF IGNITION PRIOR TO USE AND UNTIL VAPORS ARE GONE. SURFACES THAT ARE SUFFICIENTLY HOT MAY IGNITE PRODUCT IN THE ABSENCE OF SPARKS OR FLAME. VAPORS MAY ACCUMULATE AND TRAVEL TO IGNITION SOURCES DISTANT FROM HANDLING SITE. KEEP CONTAINERS CLOSED WHEN NOT IN USE. USE WITH ADEQUATE VENTILATION. CONTAINERS, EVEN IF EMPTY, CAN CONTAIN EXPLOSIVE VAPORS OR RESIDUES. DO NOT CUT, DRILL, GRIND, OR WELD NEAR CONTAINERS AFTER CONTACT WITH PRODUCT OR CONTAINER WASH WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING, OR USING TOILET FACILITIES. THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVILABLE TO US AND IS BELIEVED TO BE CORRECT. HOWEVER, WE MAKE NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. WE ASSUME NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. Page 712 of 878 Page 712 of 878 Page 712 of 878 Page 712 of 878 ---PAGE BREAK--- MSDS NO. 06300 Page 1 of 4 MATERIAL SAFETY DATA SHEET SHEETROCK® All Purpose Joint Compound United States Gypsum Company 125 South Franklin Street Chicago, Illinois 60606-4678 Product Safety: 1 (800) 507-8899 Version Date: March 27, 1998 Version 2 SECTION I PRODUCT IDENTIFICATION PRODUCT(S): SHEETROCK® All Purpose Joint Compound. CHEMICAL FAMILY: Mixture of limestone, polyvinyl alcohol and minerals. SECTION II INGREDIENTS MATERIAL WT% TLV (mg/m3) PEL( mg/m3) CAS NUMBER Limestone >65 10 15(T)/5(R) 1317-65-3 Or Dolomite 10 15(T)/5(R) 16389-88-1 Mica <20 3(R) 3(R) 12001-26-2 Attapulgite <5 (NE) (NE) 12174-11-7 Vinyl Alcohol Polymer <5 (NE) (NE) 9002-89-5 Starch <5 10 15(T)/5(R) 9005-25-8 Silica <5 0.1(R) 0.1(R) 14808-60-7 – Total – Respirable (NE) – Not Established This is a Non-Asbestos Product. All ingredients of this product are included in the U.S. Environmental Protection Agency’s Toxic Substances Control Act Chemical Substance Inventory. All components of this product are included in the Canadian Domestic Substances List (DSL) or the Canadian Non-Domestic Substances List (NDSL). INFORMATION FOR HANDLING AND IDENTIFICATION OF CHEMICAL HAZARDS NFPA Ratings: Health: 0 Fire: 0 Reactivity: 0 Other: N/A HIMS Ratings: Health: 0 Fire: 0 Reactivity: 0 Personal Protection: Use eye and skin protection. Use NIOSH/MSHA-approved respiratory protection when necessary. 0 = Minimal Hazard 1 = Slight Hazard 2 = Moderate Hazard 3 = Serious Hazard 4 = Severe Hazard SECTION III PHYSICAL DATA Appearance and Odor: Off white to gray powder; low odor. Melting Point: 1450ºC – decomposes Solubility In Water: 0.15% Specific Gravity (H20 = 2.3-2.6 pH Range: 7.5-8.5 Coating Voc: 0 g/l Material Voc. 0 g/l Hardening Time: Varies. Check usage and/or product specification data for each product. SECTION IV Page 713 of 878 Page 713 of 878 Page 713 of 878 Page 713 of 878 ---PAGE BREAK--- MSDS NO. 06300 Page 2 of 4 MATERIAL SAFETY DATA SHEET SHEETROCK® All Purpose Joint Compound FIRE AND EXPLOSION HAZARD DATA Flash Point (Method Used): Noncombustible Extinguishing Media: Use extinguishing media appropriate for surrounding fire. Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None Special Fire Fighting Protective Equipment: None SECTION V HEALTH HAZARD DATA Nuisance dust can be released during dry sanding of this product. Eye, skin, nose, throat, and upper respiratory irritation can occur with prolonged dust exposure. EFFECTS OF OVEREXPOSURE: ACUTE: EYES: Direct contact can cause mechanical irritation of eyes. If burning, redness, itching, pain or other persist or develop, consult physician. SKIN: Direct, prolonged or repeated contact with the skin may cause irritation. May dry skin. Rubbing of this product against the skin can result in abrasions. Rinse with water until free of material to avoid abrasions, then wash skin thoroughly with mild soap and water. May dry skin. If irritation persists, consult physician. INHALATION: Inhalation of dust from this product may irritate the nose, throat, lungs, and upper respiratory tract. Persons subjected to large amounts of this dust will be forced to leave area because of nuisance conditions such as coughing, sneezing and nasal irritation from dust. Labored breathing may occur after excessive inhalation. If respiratory persist, consult physician. INGESTION: Unlikely to occur, but may cause gastric disturbances if swallowed. CHRONIC: This material displays no specific toxic properties. EYES: None known. SKIN: None known. INHALATION: Chronic overexposure to respirable silica may result in lung disease silicosis) and/or lung cancer. Prolonged and repeated breathing of respirable mica dust may cause lung disease (pulmonary fibrosis). INGESTION: No known effects. EMERGENCY AND FIRST AID PROCEDURES: EYES: Flush thoroughly with plenty of water for 15 minutes to remove particles. If irritation persists, consult physician. SKIN: Rinse with water, then wash with mild soap and water. A commercially available hand lotion may be used to treat dry skin areas. If skin has become cracked, take appropriate action to prevent infection and promote healing. If irritation persists, consult physician. INHALATION: Remove to fresh air. Leave the area of dust exposure and remain away until coughing and other subside. Other measures are usually not necessary, however, if conditions warrant, contact physician. INGESTION: No harmful effects expected. No specific recommendation. If gastric disturbance occurs, call physician. TARGET ORGANS: Eyes, skin, and respiratory system. MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED: Pre-existing upper respiratory and lung diseases such as, but not limited to, bronchitis, and asthma. PRIMARY ROUTES OF ENTRY: Inhalation; Eye and/or Skin contact. CARCINOGENICITY OF INGREDIENTS: MATERIAL IARC NTP Respirable Silica Group 1 Anticipated In June, 1997, the International Agency for Research on Cancer (IARC) classified silica (quartz and Page 714 of 878 Page 714 of 878 Page 714 of 878 Page 714 of 878 ---PAGE BREAK--- MSDS NO. 06300 Page 3 of 4 MATERIAL SAFETY DATA SHEET SHEETROCK® All Purpose Joint Compound cristobalite) as a human carcinogen. In making the overall evaluation, the IARC Working Group noted that carcinogenicity in humans was not detected in all industrial circumstances studies. Carcinogenicity may be dependent on inherent characteristics of the silica or on external factors affecting its biological activity or distribution of its polymorphs. IARC states that silica inhaled in the form of quartz or cristobalite from occupational sources in carcinogenic to humans (Group SECTION VI REACTIVITY DATA STABILITY: Stable. INCOMPATIBILITY: Acids. HAZARDOUS POLYMERIZATION: Will not occur. HAZARDOUS DECOMPOSITION: Above 1450ºC – CaO and SO2. SECTION VII SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Use normal clean up procedure. Shovel material from spillage into a waste container for disposal, avoid creating excessive dust and minimize airborne dust. If already mixed with water, scoop up and place in disposable container. Wear appropriate protection equipment. If washed down, may plug drains. WASTE DISPOSAL METHOD: Dispose of material in accordance with federal, state, and local regulations. Slurry may plus drains. SECTION VIII SPECIAL PROTECTION INFORMATION No TLV assigned to this mixture; see Ingredients Section. Minimize dust exposures in accordance with good hygiene practice. RESPIRATORY PROTECTION: Not typically necessary under normal conditions of use. Provide general ventilation and local exhaust ventilation to meet TLV requirements of individual ingredients and to control dusting conditions. Wear a NIOSH/MSHA-approved respirator when dusty conditions exist, in poorly ventilated areas, and if TLV is exceeded. VENTILATION: Ventilate to keep exposures below TLV. General ventilation is expected to be satisfactory. Use local exhaust ventilation if necessary to control dust. PERSONAL PROTECTIVE EQUIPMENT: Wear eye protection (safety glasses or goggles) to avoid particulate irritation of the eye. Gloves or protective clothing are usually not necessary, but may be desirable in specific work situations. Wear adequate clothing to minimize chafing or drying of skin. SECTION IX SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Normal precautions should be followed in handling, storage, and use. During handling and use wear the appropriate Page 715 of 878 Page 715 of 878 Page 715 of 878 Page 715 of 878 ---PAGE BREAK--- MSDS NO. 06300 Page 4 of 4 MATERIAL SAFETY DATA SHEET SHEETROCK® All Purpose Joint Compound respiratory, eye and skin protection of warranted per environmental conditions. Use wet sanding technique to reduce dust exposure when finishing joints. See “Finishing and Decorating Gypsum Panels – Wet Sanding, J-610/12-87”. Recommended Storage Methods: Keep dry. Dew point conditions or other conditions causing presence of liquid will harden this material during storage.
WARNING! Dust generated from sanding product may cause eye, skin, nose, throat or respiratory irritation. Use wet-sanding to avoid creating dust. Avoid inhalation of dust and eye contact. If dusty, wear a NIOSH/MSHA-approved respirator. Prolonged and repeated exposure to respirable mica may cause lung disease. Wear eye protection. Provide good general ventilation and local exhaust ventilation to avoid excessive amounts of dust. If eye contact occurs, flush thoroughly with water for 15 minutes. If irritation persists, call physician. Do not ingest. If ingested, call physician. Product safety information: (800) 507-8899. KEEP OUT OF REACH OF CHILDREN. END Page 716 of 878 Page 716 of 878 Page 716 of 878 Page 716 of 878 ---PAGE BREAK--- 114440020 - SHINE-UP (LEMON - AEROSOL) Page 1 of 6 1/1/99 114440020 - SHINE-UP (LEMON - AEROSOL) Date Issued: 17Apr1997 Supersedes: 27Apr1994 US MANUFACTURER: S.C. Johnson Commercial Markets, Inc. S.C. Johnson Professional 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (800) 725-6737 MSDS Internet Address: Emergency Phone: (800) 851-7145 CANADIAN MANUFACTURER: S.C. Johnson Professional, Inc. Phone: (519) 756-7900 1 Webster Street, Suite 100 Brantford, Ontario N3T 5R1 Transportation Emergency: CANUTEC (collect) (613) 996-6666 Emergency Phone: (800) 851-7145 DISTRIBUTED IN CANADA BY: S.C. Johnson Professional, Inc. Phone: (519) 758-6611 1 Webster Street, Suite 100 Brantford, Ontario N3T 5R1 HAZARD RATING HMIS HAZARD NFPA 4-Very High 0 Health 0 3-High 4 Flammability 4 2-Moderate 0 Reactivity 0 1-Slight Special 0-Insignificant SECTION 1 - PRODUCT IDENTIFICATION PRODUCT NAME SHINE-UP (LEMON - AEROSOL) REASON FOR CHANGE New format. PRODUCT USE Furniture care SECTION 2 - INGREDIENT INFORMATION WEIGHT% INGREDIENT AND EXPOSURE LIMIT Page 717 of 878 Page 717 of 878 Page 717 of 878 Page 717 of 878 ---PAGE BREAK--- 114440020 - SHINE-UP (LEMON - AEROSOL) Page 2 of 6 1/1/99 1-3 Silicone (CAS# 63148-62-9) Exposure Limit: NOT ESTABLISHED 1-5 Butane (CAS# 106-97-8) Exposure Limit: 800 ppm ACGIH/OSHA TWA 1-5 Propane (CAS# 74-98-6) Exposure Limit: 1000 ppm OSHA PEL 1-5 Isobutane (CAS# 75-28-5) Exposure Limit: NOT ESTABLISHED 10-20 Isoparaffinic Hydrocarbon Solvent (CAS# 64742-48-9) Exposure Limit: 300 ppm-SUPPLIER RECOMMENDED 70-80 Water (CAS# 7732-18-5) Exposure Limit: NOT ESTABLISHED SECTION 3 - HEALTH HAZARDS IDENTIFICATION (Also See Section 11) ROUTE(S) OF ENTRY Eye contact. EFFECTS OF ACUTE EXPOSURE: EYE May cause: Mild eye irritation. SKIN None known. INHALATION None known. INGESTION None known. MEDICAL CONDITIONS GENERALLY RECOGNIZED AS BEING AGGRAVATED BY EXPOSURE None known. SECTION 4 - FIRST AID MEASURES EYE CONTACT Flush immediately with plenty of water for at least 15 to 20 minutes. If irritation persists, get medical attention. SKIN CONTACT Wash contaminated area with water and soap. INHALATION Remove to fresh air. INGESTION Immediately drink 1-2 glasses of water or milk. Seek immediate medical attention. Page 718 of 878 Page 718 of 878 Page 718 of 878 Page 718 of 878 ---PAGE BREAK--- 114440020 - SHINE-UP (LEMON - AEROSOL) Page 3 of 6 1/1/99 SECTION 5 - FIRE AND EXPLOSION INFORMATION FLASH POINT ‹ 20°F -7°C) (propellant) FLAMMABLE LIMITS Not applicable. AUTOIGNITION TEMPERATURE Not applicable. EXTINGUISHING MEDIA Foam. CO2. Dry chemical. Water fog. SPECIAL FIREFIGHTING PROCEDURES Normal fire fighting procedure may be used. Fight fire from maximum distance or protected area. Cool and use caution when approaching or handling fire-exposed containers. UNUSUAL FIRE AND EXPLOSION HAZARDS No special hazards known. SECTION 6 - PREVENTIVE RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Eliminate all ignition sources. Absorb with oil-dri or similar inert material. Sweep or scrape up and containerize. Rinse affected area thoroughly with water. SECTION 7 - HANDLING AND STORAGE PRECAUTIONARY INFORMATION CAUTION: FLAMMABLE: Avoid prolonged or repeated breathing of vapours. Eye irritant. Do not use near open fire, flames or heat. Do not puncture or incinerate. Do not store at temperatures above 120 °F (50 Keep away from heat. Do not spray or use on floors. Keep out of reach of children. OTHER HANDLING AND STORAGE CONDITIONS Store in a cool, dry place with adequate ventilation. Keep from freezing. Do not pressurize, cut, heat, weld or expose container to flame; explosion could occur. SECTION 8 - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION No special requirements under normal use conditions. VENTILATION General room ventilation adequate. PROTECTIVE GLOVES No special requirements under normal use conditions. EYE PROTECTION No special requirements under normal use conditions. OTHER PROTECTIVE MEASURES Page 719 of 878 Page 719 of 878 Page 719 of 878 Page 719 of 878 ---PAGE BREAK--- 114440020 - SHINE-UP (LEMON - AEROSOL) Page 4 of 6 1/1/99 No special requirements. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES COLOR Off-white PRODUCT STATE Dispensed as a spray mist. ODOR Lemon pH Not applicable. ODOR THRESHOLD Not available SOLUBILITY IN WATER Moderate SPECIFIC GRAVITY (H2O=1) 0.876 VAPOR DENSITY (AIR=1) Not available. EVAPORATION RATE (BUTYL ACETATE=1) Not available. VAPOR PRESSURE (mm HG) Not available. BOILING POINT Not applicable. FREEZING POINT Not applicable. COEFFICIENT OF WATER/OIL Not available. PERCENT VOLATILE BY VOLUME Not available. VOLATILE ORGANIC COMPOUND (VOC) Hydrocarbon propellant Isoparaffinic Hydrocarbon THEORETICAL VOC (LB/GAL) 1.78 SECTION 10 - STABILITY AND REACTIVITY STABILITY Stable STABILITY - CONDITIONS TO AVOID No special requirements. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS No special requirements. HAZARDOUS POLYMERIZATION Will not occur. HAZARDOUS POLYMERIZATION - CONDITIONS TO AVOID Page 720 of 878 Page 720 of 878 Page 720 of 878 Page 720 of 878 ---PAGE BREAK--- 114440020 - SHINE-UP (LEMON - AEROSOL) Page 5 of 6 1/1/99 None known. SECTION 11 - TOXICOLOGY INFORMATION (Also See Section 3) LD50 (ACUTE ORAL TOX) Estimated to be greater than 5000 mg/kg (rats). LD50 (ACUTE DERMAL TOX) Not available. EFFECTS OF CHRONIC EXPOSURE None known. SENSITIZATION None known. CARCINOGENICITY None known. REPRODUCTIVE TOXICITY None known. TERATOGENICITY None known. MUTAGENICITY None known. SECTION 12 - ECOLOGICAL INFORMATION ENVIRONMENTAL DATA Not available. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL INFORMATION If possible, recycle empty aerosol can to nearest steel recycling center. Use up package or give to someone who can. SECTION 14 - TRANSPORTATION INFORMATION US DOT INFORMATION Aerosols, 2.1, UN 1950, Ltd. Qty. CANADIAN SHIPPING NAME AEROSOLS, Limited Quantity. TDG CLASSIFICATION 2.2 PIN/NIP UN 1950 PACKING GROUP Not applicable. EXEMPTION NAME Page 721 of 878 Page 721 of 878 Page 721 of 878 Page 721 of 878 ---PAGE BREAK--- 114440020 - SHINE-UP (LEMON - AEROSOL) Page 6 of 6 1/1/99 Limited Quantity SECTION 15 - REGULATORY INFORMATION WHMIS CLASSIFICATION A; B,5; All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. All ingredients in this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA). This product is not subject to the reporting requirements under California's Proposition 65. SECTION 16 - OTHER INFORMATION ADDITIONAL INFORMATION NFPA 30B Level 1 Aerosol. EPA REGISTRATION # Not applicable. PREPARATION INFORMATION - PREPARED BY Manufacturer's Technical Support Department. Refer to page 1 (Manufacturer) for contact information. This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Page 722 of 878 Page 722 of 878 Page 722 of 878 Page 722 of 878 ---PAGE BREAK--- SECTION I: PRODUCT INFORMATION SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1% or greater, carcinogens at 0.1% or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. SECTION III: PHYSICAL DATA Spartan Chemical Company, Inc. Material Safety Data Sheet Product Name or Number (as it appears on label): Product Division: SIGN OFF Product Number: 3290 Janitorial Spartan Chemical Company, Inc. Product/Technical Information:1-(800)-537-8990 1110 Spartan Drive Medical Emergency:1-(888)-314-6171 (24 hours) Maumee OH 43537 Chemical Leak/Spil Emergency:CHEMTREC 1-(800) 424-9300 (24 hours) Shipping Description: Cleaning compounds, liquid, n.o.s. NFPA Ratings: HMIS Ratings: Health: 1- Slight Health: 1- Slight Fire: 0 - Minimal Fire: 0 - Minimal Reactivity: 0 - Minimal Reactivity: 0 - Minimal Pers. Prot. Equip.: See Section VIII Chemical Name(s) % W CAS Registry No. Table Z- 1 - A NTP, IARC or OSHA Carcinogen TWA mg/m3 STEL mg/m 3 CELING mg/m3 NO HAZARDOUS INGREDIENTS AS DEFINED BY 29 CFR 1910.1200 AT 1% OR GREATER CONCENTRATION NA NA NA NA NA No Boiling Point: 212 °F Vapor Pressure: Not determined Vapor Density (AIR = Unknown Solubility in Water: Complete pH: 8.5-9.0 Specific Gravity (H2O=1): 1.00 Evaporation Rate (but.ace.=1): <1 Percent Solid by Weight: < 1.0 Physical State: Liquid Appearance & Odor: Green liquid, floral fragrance Page 723 of 878 Page 723 of 878 Page 723 of 878 Page 723 of 878 ---PAGE BREAK--- SECTION IV: FIRE & EXPLOSIVE HAZARD DATA SECTION V: HEALTH HAZARD DATA Emergency & First Aid Procedures: SECTION VI: REACTIVITY DATA SECTION VII: SPILL OR LEAK PROCEDURES Flash Point: > 212°F Method Used: ASTM-D56 Flammable Limits: Not Established Flame Extension: N/A Extinguishing Media: Product does not support combustion. Use extinguishing media appropriate for surrounding fire. Special Fire Fighting Procedures: Wear NIOSH approved self-contained breathing apparatus and protective clothing. Cool fire- exposed containers with water spray. Unusual Fire & Explosive Hazards: Combustion products are toxic. Threshold Limit Value: Not Established Primary Routes of Entry: Inhalation, Skin Contact, Eyes and Oral Effects of Overexposure- Conditions to Avoid: May cause mild eye and skin irritation. May be harmful if swallowed. Inhalation of product mist may cause respiratory irritation. Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Do not swallow. Avoid breathing product mist. Wash thoroughly after handling. Conditions Aggravated by Use: Use of this product may aggravate preexisting skin; eye and respiratory disorders including asthma and dermatitis. Eyes: Flush eyes with plenty of water for at least 15 minutes. Remove contact lenses. Get medical attention. Skin: Wash skin thoroughly with soap and water. Get medical attention if irritation persists. Wash contaminated clothing before reuse. Ingestion: Do not induce vomiting. Drink one or two glasses of water to dilute product. Get medical attention. Do not give anything by mouth to an unconscious person. Inhalation: In case of respiratory irritation; move person to fresh air. Get medical attention if irritation persists. Stability: Stable Incompatible Materials: Strong oxidizers Hazardous Decomposition Products: CO, CO2 Hazardous Polymerization: Will Not Occur Steps to be Taken in Case Material is Released or Spilled: Small spills of one gallon or less may be flushed with plenty of water to sanitary sewer system (If permitted by local sewer regulations). Dike and contain large spills with inert material and transfer liquid to containers for disposal. Keep spill out of storm sewers and waterways. Waste Disposal Method: Dispose of in compliance with all federal, state and local laws and regulations. Page 724 of 878 Page 724 of 878 Page 724 of 878 Page 724 of 878 ---PAGE BREAK--- SECTION VIII: SPECIAL PROTECTION INFORMATION SECTION IX: SPECIAL PRECAUTIONS Respiratory Protection: None required Ventilation: Provide good general ventilation. Local exhaust ventilation may be necessary for some operations. Protective Gloves(Specify Type): Not required. Impervious gloves may be worn if desired. Eye Protection(Specify Type): Not required. Splash goggles may be worn if desired. Other Protective Equipment: See 29 CFR 1910.132-138 for further guidance. Precautions; Handling & Storing: Keep from freezing. Other Precautions: Keep out of reach of children. © SCC 03/25/2008 Name: Ronald T. Cook Title: Manager, Regulatory Affairs SIGN OFF Effective Date: 03/25/2008 Supercedes: 05/26/2005 Ref: 29 CFR 1910.1200 (OSHA) Changes: General Update This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. Page 725 of 878 Page 725 of 878 Page 725 of 878 Page 725 of 878 ---PAGE BREAK--- Safety Data Sheet: Simple Green® Industrial Cleaner & Degreaser  Version No. 13000-15A Issue Date: July 31, 2015 Supersedes Date: September 13, 2014 OSHA HCS-2012 / GHS Page 1 of 4 Section 1: IDENTIFICATION Product Name: Simple Green® Industrial Cleaner & Degreaser Additional Names: Manufacturer’s Part Number: *Please refer to Section 16 Recommended Use: Cleaner & Degreaser for water tolerant surfaces. Restrictions on Use: Do not use on non-rinsable surfaces. Company: Sunshine Makers, Inc. 15922 Pacific Coast Highway Huntington Beach, CA 92649 USA Telephone: [PHONE REDACTED] ● [PHONE REDACTED] Mon – Fri, 8am – 5pm PST Fax: [PHONE REDACTED] Email: [EMAIL REDACTED] Emergency Phone: Chem-Tel 24-Hour Emergency Service: [PHONE REDACTED] Section 2: HAZARDS IDENTIFICATION This product is not classified as hazardous under 2012 OSHA Hazard Communication Standards (29 CFR 1910.1200). OSHA HCS 2012 Label Elements Signal Word: None Hazard Symbol(s)/Pictogram(s): None required Hazard Statements: None Precautionary Statements: None Hazards Not Otherwise Classified (HNOC): None Other Information: None Known Section 3: COMPOSITION/INFORMATION ON INGREDIENTS Ingredient CAS Number Percent Range Water 7732-18-5 > 84.8%* Ethoxylated Alcohol 68439-46-3 < Sodium Citrate 68-04-2 < Tetrasodium N,N-bis(carboxymethyl)-L-glutamate 51981-21-6 < Sodium Carbonate 497-19-8 < Citric Acid 77-92-9 < Isothiazolinone mixture 55965-84-9 < 0.2%* Fragrance Proprietary Mixture < Colorant Proprietary Mixture < *specific percentages of composition are being withheld as a trade secret Section 4: FIRST-AID MEASURES Inhalation: Not expected to cause respiratory irritation. If adverse effect occurs, move to fresh air. Skin Contact: Not expected to cause skin irritation. If adverse effect occurs, rinse skin with water. Eye Contact: Not expected to cause eye irritation. If adverse effect occurs, flush eyes with water. Ingestion: May cause upset stomach. Drink plenty of water to dilute. See section 11. Most Important Acute and Delayed: None known. Indication of Immediate Medical Attention and Special Treatment Needed, if necessary: Treat Page 726 of 878 Page 726 of 878 Page 726 of 878 Page 726 of 878 ---PAGE BREAK--- Safety Data Sheet: Simple Green® Industrial Cleaner & Degreaser  Version No. 13000-15A Issue Date: July 31, 2015 Supersedes Date: September 13, 2014 OSHA HCS-2012 / GHS Page 2 of 4 Section 5: FIRE-FIGHTING MEASURES Suitable & Unsuitable Extinguishing Media: Use Dry chemical, CO2, water spray or “alcohol” foam. Avoid high volume jet water. Specific Hazards Arising from Chemical: In event of fire, fire created carbon oxides may be formed. Special Protective Actions for Fire-Fighters: Wear positive pressure self-contained breathing apparatus; Wear full protective clothing. This product is non-flammable. See Section 9 for Physical Properties. Section 6: ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures: For non-emergency and emergency personnel: See section 8 – personal protection. Avoid eye contact. Safety goggles suggested. Environmental Precautions: Do not allow into open waterways and ground water systems. Methods and Materials for Containment and Clean Up: Dike or soak up with inert absorbent material. See section 13 for disposal considerations. Section 7: HANDLING AND STORAGE Precautions for Safe Handling: Ensure adequate ventilation. Keep out of reach of children. Keep away from heat, sparks, open flame and direct sunlight. Do not pierce any part of the container. Do not mix or contaminate with any other chemical. Do not eat, drink or smoke while using this product. Conditions for Safe Storage including Incompatibilities: Keep container closed. Keep in cool dry area. Avoid prolonged exposure to sunlight. Do not store at temperatures above 109oF (42.7oC). If separation occurs, mix the product for reconstitution. Section 8: EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Limit Values: No components listed with TWA or STEL values under OSHA or ACGIH. Appropriate Engineering Controls: Showers, eyewash stations, ventilation systems Individual Protection Measures / Personal Protective Equipment (PPE) Eye Contact: Use protective glasses or safety goggles if splashing or spray-back is likely. Respiratory: Use in well ventilated areas or local exhaust ventilations when cleaning small spaces. Skin Contact: Use protective gloves (any material) when used for prolonged periods or dermally sensitive. General Hygiene Considerations: Wash thoroughly after handling and before eating or drinking. Section 9: PHYSICAL AND CHEMICAL PROPERTIES Appearance: Green Liquid Partition Coefficient: n-octanol/water: Not determined Odor: Added sassafras odor Autoignition Temperature: Non-flammable Odor Threshold: Not determined Decomposition Temperature: 109oF pH ASTM D-1293: 8.5 – 9.5 Viscosity: Like water Freezing Point ASTM D-1177: 0-3.33oC (32-38oF) Specific Gravity ASTM D-891: 1.01 – 1.03 Boiling Point & Range ASTM D-1120: 101oC (213.8oF) VOCs: **Water & fragrance exemption in calculation Flash Point ASTM D-93: > 212oF SCAQMD 304-91 / EPA 24: 0 g/L 0 lb/gal 0% Evaporation Rate ASTM D-1901: ½ Butyl Acetate @ 25oC CARB Method 310**: 2.5 g/L 0.021 lb/gal 0.25% Flammability (solid, gas): Not applicable SCAQMD Method 313: Not tested Upper/Lower Flammability or Explosive Limits: Not applicable VOC Composite Partial Pressure: Not determined Vapor Pressure ASTM D-323: 0.60 PSI @77oF, 2.05 PSI @100oF Relative Density ASTM D-4017: 8.34 – 8.42 lb/gal Vapor Density: Not determined Solubility: 100% in water Page 727 of 878 Page 727 of 878 Page 727 of 878 Page 727 of 878 ---PAGE BREAK--- Safety Data Sheet: Simple Green® Industrial Cleaner & Degreaser  Version No. 13000-15A Issue Date: July 31, 2015 Supersedes Date: September 13, 2014 OSHA HCS-2012 / GHS Page 3 of 4 Section 10: STABILITY AND REACTIVITY Reactivity: Non-reactive. Chemical Stability: Stable under normal conditions 70oF (21oC) and 14.7 psig (760 mmHg). Possibility of Hazardous Reactions: None known. Conditions to Avoid: Excessive heat or cold. Incompatible Materials: Do not mix with oxidizers, acids, bathroom cleaners, or disinfecting agents. Hazardous Decomposition Products: Normal products of combustion - CO, CO2. Section 11: TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Inhalation - Overexposure may cause headache. Skin Contact - Not expected to cause irritation, repeated contact may cause dry skin. Eye Contact - Not expected to cause irritation. Ingestion - May cause upset stomach. related to the physical, chemical and toxicological characteristics: no expected under typical use conditions. Delayed and immediate effects and or chronic effects from short term exposure: no expected under typical use conditions. Delayed and immediate effects and or chronic effects from long term exposure: headache, dry skin, or skin irritation may occur. Interactive effects: Not known. Numerical Measures of Toxicity Acute Toxicity: Oral LD50 (rat) > 5 g/kg body weight Dermal LD50 (rabbit) > 5 g/kg body weight Calculated via OSHA HCS 2012 / Globally Harmonized System of Classification and Labelling of Chemicals Skin Corrosion/Irritation: Non-irritant per Dermal Irritection® assay modeling. No animal testing performed. Eye Damage/Irritation: Minimal irritant per Ocular Irritection® assay modeling. No animal testing performed. Germ Cell Mutagenicity: Mixture does not classify under this category. Carcinogenicity: No ingredients trigger or classify under this category under NTP, IARC or OSHA. Reproductive Toxicity: Mixture does not classify under this category. STOT-Single Exposure: Mixture does not classify under this category. STOT-Repeated Exposure: Mixture does not classify under this category. Aspiration Hazard: Mixture does not classify under this category. Section 12: ECOLOGICAL INFORMATION Ecotoxicity: Volume of ingredients used does not trigger toxicity classifications under the Globally Harmonized System of Classification and Labelling of Chemicals. Aquatic: Aquatic Toxicity - Low, based on OECD 201, 202, 203 + Microtox: EC50 & IC50 ≥100 mg/L. Volume of ingredients used does not trigger toxicity classifications under the Globally Harmonized System of Classification and Labelling of Chemicals. Terrestrial: Not tested on finished formulation. Persistence and Degradability: Readily Biodegradable per OCED 301D, Closed Bottle Test Bioaccumulative Potential: No data available. Mobility in Soil: No data available. Other Adverse Effects: No data available. Section 13: DISPOSAL CONSIDERATIONS Unused or Used Liquid: May be considered hazardous in your area depending on usage and tonnage of disposal – check with local, regional, and or national regulations for appropriate methods of disposal. Empty Containers: May be offered for recycling. Never dispose of used degreasing rinsates into lakes, streams, and open bodies of water or storm drains. Page 728 of 878 Page 728 of 878 Page 728 of 878 Page 728 of 878 ---PAGE BREAK--- Safety Data Sheet: Simple Green® Industrial Cleaner & Degreaser  Version No. 13000-15A Issue Date: July 31, 2015 Supersedes Date: September 13, 2014 OSHA HCS-2012 / GHS Page 4 of 4 Section 14: TRANSPORT INFORMATION U.N. Number: Not applicable U.N. Proper Shipping Name: Cleaning Compound, Liquid NOI Transport Hazard Class(es): Not applicable NMFC Number: 48580-3 Packing Group: Not applicable Class: 55 Environmental Hazards: Marine Pollutant - NO Transport in Bulk (according to Annex II of MARPOL 73/78 and IBC Code): Unknown. Special precautions which user needs to be aware of/comply with, in connection with transport or conveyance either within or outside their premises: None known. U.S. (DOT) / Canadian TDG: Not Regulated for shipping. ICAO/ IATA: Not classified as Hazardous IMO / IDMG: Not classified as Hazardous ADR/RID: Not classified as Hazardous Section 15: REGULATORY INFORMATION All components are listed on: TSCA and DSL Inventory. SARA Title III: Sections 311/312 Hazard Categories – Not applicable. Sections 313 Superfunds Amendments and Reauthorizations Act of 1986 – Not applicable. Sections 302 – Not applicable. Clean Air Act (CAA): Not applicable Clean Water Act (CWA): Not applicable State Right To Know Lists: No ingredients listed California Proposition 65: No ingredients listed Texas ESL: Ethoxylated Alcohol 68439-46-3 60 µg/m3 long term 600 µg/m3 short term Sodium Citrate 68-04-2 5 µg/m3 long term 50 µg/m3 short term Sodium Carbonate 497-19-8 5 µg/m3 long term 50 µg/m3 short term Citric Acid 77-92-9 10 µg/m3 long term 100 µg/m3 short term Section 16: OTHER INFORMATION Size UPC Size UPC 22 oz. Trigger 043318130229 2.5 Gallon 043318000041 24 oz. Trigger 043318000034 5 Gallon 043318000010 32 oz. 043318130328 55 Gallon 043318000027 1 Gallon 043318000003 15 Gallon 043318000225 1 Gallon w/ Dilution Bottle 043318001253 260 Gallon 043318130663 1 Gallon w/ Dilution Bottle 043318480416 275 Gallon 043318000102 1 Gallon w/ Dilution Bottle 043318000003 USA items listed only. Not all items listed. USA items may not be valid for international sale. NFPA: Health – None Stability – Stable Flammability – Non-flammable Special - None Acronyms NTP National Toxicology Program IARC International Agency for Research on Cancer OSHA Occupational Safety and Health Administration CPSC Consumer Product Safety Commission TSCA Toxic Substances Control Act DSL Domestic Substances List Prepared / Revised By: Sunshine Makers, Inc., Regulatory Department. This SDS has been revised in the following sections: Section 16 – corrected UPC DISCLAIMER: The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Page 729 of 878 Page 729 of 878 Page 729 of 878 Page 729 of 878 ---PAGE BREAK--- Page 730 of 878 Page 730 of 878 Page 730 of 878 Page 730 of 878 ---PAGE BREAK--- Page 731 of 878 Page 731 of 878 Page 731 of 878 Page 731 of 878 ---PAGE BREAK--- Page 732 of 878 Page 732 of 878 Page 732 of 878 Page 732 of 878 ---PAGE BREAK--- Page 733 of 878 Page 733 of 878 Page 733 of 878 Page 733 of 878 ---PAGE BREAK--- Spartan Chemical Company, Inc. Material Safety Data Sheet SECTION I: PRODUCT INFORMATION Product Name or Number (as it appears on label): Product Division: SPARCLING Product Number: 7118 Janitorial Spartan Chemical Company , Inc. Product/Technical Information: 1-(800)-537-8990 1110 Spartan Drive Medical Emergency: 1-(888)-314-6171 (24 hours) Maumee OH 43537 Chemical Leak/Spill Emergency: CHEMTREC 1-(800) 424-9300 (24 hours) Shipping Description: UN 1760, Corrosive liquids, n.o.s., (contains hydrochloric (muriatic) acid), 8, III NFPA Ratings: HMIS Ratings: Health: 3 - Serious Health: 3 - Serious Fire: 0 - Minimal Fire: 0 - Minimal Reactivity: 0 - Minimal Reactivity: 0 - Minimal Pers. Prot. Equip.: See Section VIII SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1% or greater, carcinogens at 0.1% or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. Table Z-1-A Chemical Name(s) %Wt CAS Registry No. TWA mg/m 3 STEL mg/m 3 CEILING mg/m 3 NTP, IARC or OSHA Carcinogen *Hydrochloric acid Betaines bis(hydroxyethyl)tallow alkyl 5-10 1-5 - 7647-01-0 70750-46-8 - Not Established Not Established - Not Established Not Established - 7 (3 ACGIH) Not Established - No No - Comment: *This substance is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (SARA) and of 40 CFR 372. SECTION III: PHYSICAL DATA Boiling Point: 210-212 °F Vapor Pressure: Undetermined Vapor Density (AIR = Unknown Solubility in Water: Complete pH: < 1 Specific Gravity (H2O=1): 1.04 Evaporation Rate (but.ace.=1): <1 Percent Solid by Weight: 8-10 Physical State: Liquid Appearance & Odor: Green liquid, mint fragrance SECTION IV: FIRE & EXPLOSIVE HAZARD DATA Flash Point: > 210°F Method Used: ASTM-D56 Flammable Limits: Not Established Flame Extension: N/A Extinguishing Media: Product does not support combustion. Use extinguishing media appropriate for surrounding fire. Special Fire Fighting Procedures: Wear NIOSH approved self-contained breathing apparatus and protective clothing. Cool fire-exposed containers with water spray. Unusual Fire & Explosive Hazards: Combustion products are toxic. Acid action on most metals may release hydrogen, an explosive gas. Page 734 of 878 Page 734 of 878 Page 734 of 878 Page 734 of 878 ---PAGE BREAK--- SECTION V: HEALTH HAZARD DATA Threshold Limit Value: Not Established Primary Routes of Entry: Inhalation, Skin Contact, Eyes & Oral Effects of Overexposure- Conditions to Avoid: CORROSIVE. CAUSES IRREVERSIBLE EYE DAMAGE AND SKIN BURNS: may include pain, redness, swelling and tissue damage. Harmful if absorbed through the skin. HARMFUL IF SWALLOWED . may include nausea, vomiting, pain and diarrhea. INHALATION OF SPRAY MIST MAY CAUSE RESPIRATORY HARM OR IRRITATION. Breathing spray mist may cause coughing and difficulty breathing. Do not get in eyes on skin or clothing . Do not swallow. Avoid breathing product mist . Wash thoroughly with soap and water after handling . Conditions Aggravated by Use: Use of this product may aggravate preexisting skin; eye and respiratory disorders including asthma and dermatitis. Emergency & First Aid Procedures: Eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses after the first 5 minutes then continue rinsing eye. Call a poison control center or doctor for treatment advice. Skin: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. Wash contaminated clothing before reuse. Ingestion: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Inhalation: In case of respiratory irritation; move person to fresh air. If person is not breathing call 911 or an ambulance then give artificial respiration preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. SECTION VI: REACTIVITY DATA Stability: Stable Incompatible Materials: Strong alkalis; hypochlorites (bleach) ammonia; cyanides. Hazardous Decomposition Products: HCL, CO, CO2 H Hazardous Polymerization: Will Not Occur SECTION VII: SPILL OR LEAK PROCEDURES Steps to be Taken in Case Material is Released or Spilled: Dike and contain spill with inert material (sand, earth, commercial absorbent, etc.) and transfer to containers for disposal. Rinse area with water and flush to sanitary sewer. Keep spill out of storm sewers and waterways. Waste Disposal Method: Dispose of in compliance with all federal, state and local laws and regulations. SECTION VIII: SPECIAL PROTECTION INFORMATION Respiratory Protection: Not normally required when good general ventilation is provided. However, if exposure limits (see Section II) are exceeded or respiratory irritation occurs, use of a NIOSH approved respirator suitable for the use-conditions and chemicals in Section II should be considered. Ventilation: Provide good general ventilation. Local exhaust ventilation may be necessary for some operations. Protective Gloves(Specify Type): Rubber or neoprene gloves are recommended. Eye Protection(Specify Type): Splash goggles are recommended to prevent eye contact. Other Protective Equipment: Acid resistant aprons and boots are recommended where body or foot contact is likely. Eye wash stations and washing facilities should be readily accessible. See 29 CFR 1910.132-138. SECTION IX: SPECIAL PRECAUTIONS Precautions; Handling & Storing: Do not contaminate water, food or feed by storage or disposal. Keep from freezing. Do not use with other chemicals. Mixtures of this product with other chemicals, particularly those containing chlorine bleach or ammonia may result in the production of toxic gases, fire or explosion. Other Precautions: Keep out of reach of children. © SCC 06/01/2013 Name: Ronald T. Cook Title: Manager, Regulatory Affairs SPARCLING Effective Date: 06/01/2013 Supercedes: 06/01/2010 Ref: 29 CFR 1910.1200 (OSHA) Changes: Revise Shipping Description This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as Page 735 of 878 Page 735 of 878 Page 735 of 878 Page 735 of 878 ---PAGE BREAK--- to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. Page 736 of 878 Page 736 of 878 Page 736 of 878 Page 736 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Item Number: 841 - Solar Version 4 Effective Date: 11-12 Originally prepared by: Sue Heiser Section(s) Revised: IX Supercedes 06-15-02 IDENTITY (As on labels and lists): Stainless Steel Polish EMERGENCY MEDICAL Telephone 1-[PHONE REDACTED] x 009 (24 hrs) Outside of the USA call [PHONE REDACTED] PRODUCT HAZARD RATINGS (HMIS): Health=2 Fire=4 Reactivity=0 Protective Equipment=B (Rating Legend: 4=Extreme, 3=Serious, 2=Moderate, 1=Slight, 0=Minimal, *=Chronic Hazard) SECTION 1 Dalco Telephone # for information: 1-[PHONE REDACTED] 300 5th Ave NW Date Printed: 10/10/03 New Brighton, MN 55112 Name of Preparer: Regulatory Compliance SECTION 2 - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION SARA Title III ACGIH Chemical Names CAS# SEC 313 TLV/TWA OSHA PEL % by Wt. Mineral spirits 64741-65-7 No 177 ppm* 177 ppm* 20-30 Isoparaffinic Solvent64741-66-8 No NE 400 ppm** 40-50 Mineral oil 8042-47-5 No NE NE 10-20 Propane 68476-85-7 No 2500 ppm 1000 ppm 10-20 *ExxonMobil recommendation **Exxon recommendation Balance of ingredients are non-hazardous or below reportable levels. SECTION 3 - PYSICAL CHARACTERISTICS Boiling Points: NA Vapor Pressure (psig): 60@130F Specific Gravity (H2O=1): <1.0 Solubility/Water: Negligible Vapor Density (AIR=1): >1 Evaporation Rate (Ether=1): <1 Appearance and Odor: Clear with Hydrocarbon Odor SECTION 4 - FIRE AND EXPLOSION HAZARD DATA Aerosol Flammability: Product is to be labeled as flammable as described in 16 CFR 1500.3 and 1500.45. Flashpoint: <0F (Propellant); >80F (Concentrate) Flammable Limits - % Volume in Air (Propellant): LEL: 2.2 UEL: 9.5 Extinguishing Media: Carbon dioxide, foam and/or dry chemical may be used. Special Firefighting procedures: Containers should be cooled with water to prevent vapor pressure build up. Use equipment or shielding, as required, to protect personnel from bursting, rupturing or venting containers. Unusual Fire and Explosion Hazards: At elevated temperatures (over 54C-130F) containers exposed to direct flame or heat contact should be cooled with water to prevent weakening of container structure. SECTION 5 - REACTIVITY DATA Stability: Stable Hazardous Polymerization: NA Incompatibility (Materials to Avoid): Oxidizing agents Hazardous Decomposition Products: Carbon Monoxide and additional hazardous materials may be formed in small amounts. Conditions to avoid: Do no store above 54C-130F. Keep away from heat, direct sunlight, open flames or sparks. Dropping of containers may cause bursting. SECTION 6 - HEALTH HAZARD DATA Route(s) of Entry - Inhalation: X Eyes: X Skin: X Ingestion: Signs of of Exposure: High vapor concentrations may result in central nervous system depression and evidenced by giddiness, headache and nausea. Ingestion may result in vomiting. Prolonged or repeated skin contact can result in drying and defatting of skin. Moderate eye irritant. Medical Conditions Generally Aggravated by Exposure: Preexisting skin or eye disorders may be aggravated by exposure to this product. Emergency and First Aid Procedures: Eye contact: Flush eyes with plenty of water for 15 minutes while holding eyelids open. Get medical attention if irritation persists. Skin Contact: Remove contaminated clothing. Flush skin with water, followed by washing with soap and water. If irritation persists, get medical attention. Do not reuse clothing until cleaned. Inhalation: Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial respiration if not breathing. Get medical attention. Ingestion: Get medical attention. (Breathing of vomitus into lungs must be avoided as even small quantity may result in aspiration pneumonitis). CARCINOGENICITY: No regulated ingredients. TOXICITY INFORMATION: No data available. SECTION 7 - PRECAUTIONS FOR SAFE HANDLING AND USE Released or Spilled: Remove all sources of ignition and ventilate area. Soak up spill with an inert absorbent and place into a designated disposal container. Consult local regulatory agency for proper disposition of material. Waste Disposal Method: Do not puncture or incinerate containers. When contents are depleted continue to depress button until all gas is expelled. Dispose of container in accordance with local, state, and federal regulations. Handling and Storing: avoid breathing vapor. Keep away from heat and flame. Use with adequate ventilation. Do not puncture or incinerate containers. Do not expose to direct sunlight or store at temperatures above 130F (54C). Store as Level 3 Aerosol (NFPA 30B). SECTION 8 - EMPLOYEE PROTECTION Respiratory Protection (Type): None required if good ventilation is maintained. If exposure exceeds occupational exposure limits (Sec. II), use a NODSH approved respirator to prevent overexposure. Ventilation: General ventilation is adequate under normal conditions, mechanical ventilation is optional. Protective Gloves: Chemical resistant gloves are recommended - consult glove manufacturer to determine the proper type for specific operation. Eye Protection: Chemical safety glasses are recommended. Other Protective Clothing or Equipment: Wear impervious clothing to prevent skin contact. Work/Hygienic Practices: Ensure strict sanitary conditions are conformed to when working around chemicals. Protective clothing and equipment should be in accordance with 29 CFR 1910.132 and CFR 1910.133. SECTION 9 - OTHER REGULATORY CONTROLS FEDERAL: Toxic Substance Control Act (TSCA): Ingredients of this product are listed on the EPA/TSCA Inventory of Chemical Substances. STATE RIGHT-TO-KNOW: Jersey Right-To-Know (Chemical and CAS No.): Mineral spirits 64741-65-7 Isoparaffinic Solvent 64741-66-8 Mineral oil 8042-47-5 872-50-4 Propane 68476-85-7 Shipping Name: Consumer Commodity Hazard Class: ORM-D While the information set forth herein is believed to be accurate as of the data hereof, the Company makes no warranty or guarantee, express or implied, and disclaims all liability arising out of the use of this information.Effective Date: 07-31- 02 Supercedes 06-15-02 Originally prepared by: Sue Heiser Page 737 of 878 Page 737 of 878 Page 737 of 878 Page 737 of 878 ---PAGE BREAK--- 0DWHULDOQDPH 67$7,&*8$5'$17,67$7,&635$<  0L[WXUH $17,67$7,&635$< 0HOURVH3DUN,/86 (PHUJHQF\3KRQH (PHUJHQF\ (PHUJHQF\3KRQH (PHUJHQF\RYHUYLHZ &217(17681'(535(6685(  (\HV XVH 6NLQ 7DUJHWRUJDQV &HQWUDOQHUYRXVV\VWHP(\HV5HVSLUDWRU\V\VWHP6NLQ &KURQLFHIIHFWV 3HUFHQW +\GURIOXRURFDUERQ$  )LUVWDLG  )LUVW$LG0HDVXUHV 0DWHULDOQDPH 67$7,&*8$5'$17,67$7,&635$< )RUPXOD 0$53ULQWGDWH 06'686 Page 738 of 878 Page 738 of 878 Page 738 of 878 Page 738 of 878 ---PAGE BREAK--- V  KD]DUGV  6PDOO)LUHV /DUJH)LUHV :DWHUVSUD\IRJRUUHJXODUIRDP 3URSHOODQW 6WRS  /DUJH6SLOOV 6PDOO6SLOOV :LSHXSZLWKDEVRUEHQWPDWHULDO HJFORWKIOHHFH WKRURXJKO\ +DQGOLQJ  +DQGOLQJDQG6WRUDJH 6WRUDJH /HYHO$HURVRO DSSURSULDWHFHUWLILHGUHVSLUDWRUV  DVUHTXLUHG 0DWHULDOQDPH 67$7,&*8$5'$17,67$7,&635$< )RUPXOD 0$53ULQWGDWH 06'686 Page 739 of 878 Page 739 of 878 Page 739 of 878 Page 739 of 878 ---PAGE BREAK---  3K\VLFDO )ODPPDELOLW\ 1RWDYDLODEOH )RUP $HURVRO 3HUFHQWYRODWLOH 9DSRUSUHVVXUH 92&  6WDELOLW\   /RFDOHIIHFWV 86$&*,+7KUHVKROG/LPLW9DOXHV &KURQLFWR[LFLW\ (FRWR[LFLW\ ,QYHUWHEUDWH7R[LFLW\ (&YDOXH :DWHUIOHD :DWHUIOHD :DWHUIOHD :DWHUIOHD :DWHUIOHD :DWHUIOHD :DWHUIOHD :DWHUIOHD :DWHUIOHD :DWHUIOHD /&YDOXH 7XUEHOODULDQIODWZRUP   0DWHULDOQDPH 67$7,&*8$5'$17,67$7,&635$< )RUPXOD 0$53ULQWGDWH 06'686 Page 740 of 878 Page 740 of 878 Page 740 of 878 Page 740 of 878 ---PAGE BREAK--- '27 250' 1RQH 1RQH +D]DUGFODVV (5*QXPEHU  '27 $HURVROVIODPPDEOH 81 1RQH 1RQH +D]DUGFODVV 81QXPEHU (5*QXPEHU  +D]DUGFODVV 81QXPEHU $HURVROVIODPPDEOH  +D]DUGFODVV 81QXPEHU $(5262/6IODPPDEOH    +D]DUGFODVV 81QXPEHU ,WHP /DEHOVUHTXLUHG 0DWHULDOQDPH 67$7,&*8$5'$17,67$7,&635$< )RUPXOD 0$53ULQWGDWH 06'686 Page 741 of 878 Page 741 of 878 Page 741 of 878 Page 741 of 878 ---PAGE BREAK---  26+$  0.1% - < 1% Terpene solvent 68956-56-9 > 0.1% - < 1% d-Limonene 5989-27-5 < 0.1% *Exact percentages are being withheld as trade secret information 4. FIRST AID MEASURES Undiluted Product: Eyes: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing for at least 15 minutes. If eye irritation persists: Get medical advice/attention. Skin: In case of contact, immediately flush with plenty of water. If irritation occurs and persists, get medical attention. Inhalation: No specific first aid measures are required. Ingestion: IF SWALLOWED: Rinse mouth. Drink a cupful of milk or water. Most Important No information available. Immediate medical attention and special treatment needed Not applicable. Aggravated Medical Conditions: None known. 5. FIRE-FIGHTING MEASURES Specific methods: No special methods required Suitable extinguishing media: The product is not flammable. Extinguish fire using agent suitable for surrounding fire. Specific hazards: Not applicable. Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Extinguishing media which must not be used for safety reasons: No information available. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Put on appropriate personal protective equipment (see Section Environmental precautions and clean-up methods: Clean-up methods - large spillage. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use a water rinse for final clean-up. 7. HANDLING AND STORAGE Handling: Avoid contact with skin, eyes and clothing. Do not taste or swallow. Remove and wash contaminated clothing and footwear before re-use. Wash thoroughly after handling. Product residue may remain on/in empty containers. All precautions for handling the product must be used in handling the empty container and residue. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN. This product, when diluted as stated on the label, is not classified as hazardous according to OSHA 29CFR 1910.1200 (HazCom 2012-GHS) and current Canadian Controlled Products Regulations (CPR). Precautionary Statements Diluted Product: Stride Citrus HC 3 Neutral Cleaner 2 of 5 Eyes: Rinse with plenty of water If irritation occurs and persists, get medical attention Skin: Rinse with plenty of water If irritation occurs and persists, get medical attention Inhalation: No specific first aid measures are required Ingestion: Rinse mouth with water. Page 748 of 878 Page 748 of 878 Page 748 of 878 Page 748 of 878 ---PAGE BREAK--- Aerosol Level (if applicable) : Not applicable 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines: . Ingredient(s) CAS # ACGIH OSHA Alcohol ethoxylates 68439-46-3 - - Sodium xylene sulfonate 1300-72-7 - - Coconut fatty acid 61788-47-4 - - Dipropylene glycol methyl ether 34590-94-8 150 ppm (STEL) 100 ppm (TWA) Skin 100 ppm (TWA) 600 mg/m3 (TWA) Terpene solvent 68956-56-9 - - d-Limonene 5989-27-5 - - Undiluted Product: Engineering measures to reduce exposure: No special ventilation requirements General room ventilation is adequate Personal Protective Equipment Eye protection: Chemical-splash goggles. Hand protection: Chemical-resistant gloves. Skin and body protection: No special protective clothing is required. Respiratory protection: No special protective clothing is required. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES: Explosion limits: - upper: Not determined - lower: Not determined * - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 10. STABILITY AND REACTIVITY Reactivity: Not Applicable Stability: The product is stable Hazardous decomposition products: None reasonably foreseeable. Materials to avoid: None known. Conditions to avoid: No information available. 11. TOXICOLOGICAL INFORMATION Diluted Product: Personal Protective Equipment Eye protection: No special requirements under normal use conditions. Hand protection: No special requirements under normal use conditions. Skin and body protection: No special requirements under normal use conditions. Respiratory protection: No special requirements under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Physical State: Liquid Color: Clear, Orange Evaporation Rate: No information available Odor: Citrus Odor threshold: No information available. Boiling point/range: Not determined Melting point/range: Not determined Decomposition temperature: Not determined Autoignition temperature: No information available Solubility: Completely Soluble Solubility in other solvents: No information available Relative Density (relative to water): 1.007 Density: 8.4 lbs/gal 1.007 Kg/L Vapor density: No information available Bulk density: No information available Vapor pressure: No information available. Flash point: > 200 °F > 93.3 °C Partition coefficient (n-octanol/water): No information available Dilution Flash Point: > 200 °F > 93.3 °C Viscosity: No information available Elemental Phosphorus: 0.00 % by wt. VOC: 1.1 % * pH: 7.3 VOC % by wt. at use dilution 0 % * Stride Citrus HC 3 Neutral Cleaner 3 of 5 Dilution pH: 7.4 @ 1:375 Flammability (Solid or Gas): Not applicable Metal Corrosion: Not determined Page 749 of 878 Page 749 of 878 Page 749 of 878 Page 749 of 878 ---PAGE BREAK--- Information on likely routes of exposure: Eye contact, Skin contact, Inhalation, Ingestion Delayed, immediate, or chronic effects and from short and long-term exposure Skin contact: May be mildly irritating to skin. may include redness and/or transient discomfort. Eye contact: Causes serious eye irritation. may include pain, redness, and watering. Ingestion: May be irritating to mouth, throat and stomach. may include stomach pain and nausea. Inhalation: May be irritating to nose, throat, and respiratory tract. may include coughing and difficulty breathing. Sensitization: No known effects. Numerical measures of toxicity ATE - Oral (mg/kg): 4600 12. ECOLOGICAL INFORMATION Ecotoxicity: No information available. Persistence and Degradability: No information available. Bioaccumulation: No information available. 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: This product, as sold, if discarded or disposed, is not a hazardous waste according to Federal regulations (40 CFR 261.4 Dispose in compliance with all Federal, state, provincial, and local laws and regulations. This product, when diluted as stated on this SDS, is not a hazardous waste according to Federal regulations (40 CFR 261.4 Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal, whether the waste solution meets RCRA criteria for hazardous waste. Dispose in compliance with all Federal, state, provincial, and local laws and regulations. Contaminated Packaging: Do not re-use empty containers. RCRA Hazard Class (undiluted product): Not Regulated RCRA Hazard Class (diluted product): Not Regulated 15. REGULATORY INFORMATION International Inventories at CAS# Level All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65. RIGHT TO KNOW (RTK) Ingredient(s) CAS # MARTK: PARTK: RIRTK: Water 7732-18-5 - - - - Alcohol ethoxylates 68439-46-3 - - - - Sodium xylene sulfonate 1300-72-7 - - - - Coconut fatty acid 61788-47-4 - - - - Dipropylene glycol methyl ether 34590-94-8 X X X - 14. TRANSPORT INFORMATION DOT/TDG/IMDG: Please refer to the Diversey HazMat Library, only available through Internet Explorer, http://naextranet.diversey.com/dot/, for up to date shipping information. DOT (Ground) Bill of Lading Description: CLEANING, WASHING, BUFFING, OR POLISHING COMPOUNDS LIQUID Stride Citrus HC 3 Neutral Cleaner 4 of 5 IMDG (Ocean) Bill of Lading Description: CLEANING, WASHING, BUFFING, OR POLISHING COMPOUNDS LIQUID Page 750 of 878 Page 750 of 878 Page 750 of 878 Page 750 of 878 ---PAGE BREAK--- Terpene solvent 68956-56-9 - - - - d-Limonene 5989-27-5 - X - - CERCLA/ SARA Ingredient(s) CAA HAP CAA ODS CWA Priority Pollutants Dipropylene glycol methyl ether X SARA 311/312 Hazard Categories Immediate: X Delayed: - Fire: - Reactivity: - Sudden Release of Pressure: - Canada Ingredient(s) CAS # NPRI Terpene solvent 68956-56-9 X d-Limonene 5989-27-5 X 16. OTHER INFORMATION NFPA Health 2 Flammability 0 Instability 0 Version Number: 2 Preparation date: 2014-08-19 Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: Stride Citrus HC 3 Neutral Cleaner 5 of 5 • Contains an added fragrance, see "Odor" heading in section 9 for specific description • When used through dispensing/autodose equipment, this product meets Green Seal' s requirements for skin and eye irritation and acute toxicity at the as-used dilution Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Page 751 of 878 Page 751 of 878 Page 751 of 878 Page 751 of 878 ---PAGE BREAK--- STRIDE CITRUS SC NEUTRAL CLEANER 7821 Industrial/Institutional: Cleaning product. This product is intended to be diluted prior to use. 8/2/2001 8/2/2001 Material Safety Data Sheet Product Name Product Use Validation Date Print Date In Case of Emergency Section 1. Chemical Product and Company Identification Supersedes 7/30/2001. Health 1 0 0 Fire Hazard Reactivity Specific Hazard Health Fire Hazard Reactivity Protective Clothing 0 0 1 (800) 851-7145 Johnson Wax Professional 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249 MSDS Internet Address: www.jwp.com U.S. Headquarters Johnson Wax Professional 100 Matheson Blvd. East, Suite 203 Mississauga, Ontario L4Z 2G7 Phone: (905) 755-0913 or (888) 746-5971 Hazardous Material Information System (HMIS) National Fire Protection Association (NFPA) Code MSDS# 113909004 448697 Canadian Headquarters Orange. Liquid. See Section 9. CAUTION: May be mildly irritating to eyes. May be mildly irritating to skin. Emergency Overview None required. PMS# STRIDE CITRUS SC NEUTRAL CLEANER Sodium Xylene Sulfonate 1300-72-7 1-5 Not available. Not available. Alcohol Ethoxylates 34398-01-1 10-30 Not available. Not available. Water 7732-18-5 60-100 Not available. Not available. Section 2. Composition and Information on Ingredients Ingredients CAS # % by Weight Exposure Limits LC50/LD50 Eye contact. Skin contact Inhalation. Medical Conditions Aggravated by Overexposure: None known. Section 3. Hazards Identification Routes of Entry Potential Acute Health Effects None known. May be mildly irritating to eyes. May cause abdominal discomfort, nausea, vomiting and diarrhea. May be mildly irritating to skin. Eyes Skin Inhalation Ingestion See Toxicological Information (section 11) No specific first aid measures are required. Flush immediately with plenty of water. Get medical attention if irritation occurs. Flush immediately with plenty of water. Get medical attention if irritation occurs. No specific first aid measures are required. Section 4. First Aid Measures Eye Contact Skin Contact Inhalation Ingestion Continued on Next Page Page: 1/4 Page 752 of 878 Page 752 of 878 Page 752 of 878 Page 752 of 878 ---PAGE BREAK--- Material Safety Data Sheet STRIDE CITRUS SC NEUTRAL CLEANER None known. None known. None. Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire fighting procedure may be used. None known. Section 5. Fire Fighting Measures Flammability of the Product Flash Points Products of Combustion Fire Fighting Media and Instructions Special Remarks on Fire and Explosion Hazards In the event of major spillage: Use appropriate containment to avoid environmental contamination. Sweep or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a water rinse for final clean-up. Put on appropriate personal protective equipment (see Section Section 6. Accidental Release Measures Personal Precautions Environmental Precautions and Clean-up Methods Store in a dry, cool and well-ventilated area. Protect from freezing. KEEP OUT OF REACH OF CHILDREN. Avoid contact with skin and eyes. Wash thoroughly after handling. FOR INDUSTRIAL USE ONLY Section 7. Handling and Storage Handling Storage No special ventilation requirements. General room ventilation is adequate. Section 8. Exposure Controls/Personal Protection Engineering Controls No special requirements under normal use conditions. No special requirements under normal use conditions. If major exposure is possible, wear suitable protective clothing. No special requirements under normal use conditions. No special requirements under normal use conditions. Personal Protection Eyes Hands Respiratory Feet Body 100°C (212°F) Liquid. 7.2 to 7.8 [Basic.] 0°C (32°F) 1.01 Citrus. Orange. Boiling/Condensation Point Melting/Freezing Point Section 9. Physical and Chemical Properties Physical State and Appearance pH Specific Gravity Solubility in water Odor Color Complete. The product is stable. None known. Will not occur. When exposed to fire: Produces normal products of combustion. None known. Section 10. Stability and Reactivity Stability and Reactivity Conditions of Instability Incompatibility with Various Substances Hazardous Decomposition Products Hazardous Polymerization Continued on Next Page Page: 2/4 Page 753 of 878 Page 753 of 878 Page 753 of 878 Page 753 of 878 ---PAGE BREAK--- Material Safety Data Sheet STRIDE CITRUS SC NEUTRAL CLEANER Section 11. Toxicological Information Effects of Chronic Exposure Other Toxic Effects None known. ORAL (LD50) Estimated to be greater than 5000 mg/kg (rat). Acute toxicity None known. Section 12. Ecological Information Not available. No special precautions. Dispose of according to all federal, state and local regulations. Waste Information Section 13. Disposal Considerations Please refer to the Bill of Lading/receiving documents for up to date shipping information. Section 14. Transport Information DOT Classification DOT Proper Shipping Name DOT Class UN/NA DOT Special Considerations TDG Classification TDG Proper Shipping Name TDG Class PIN/NIP TDG Special Considerations Please refer to the Bill of Lading/receiving documents for up to date shipping information. Section 15. Regulatory Information Chemical Inventory Status Canadian Regulations CLASS D-2B: Material causing other toxic effects (TOXIC). All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Registered Product Information This product is not subject to the reporting requirements under California's Proposition 65. Reporting in this section is based on ingredients disclosed in Section 2 WHMIS Classification WHMIS Icon Registered Product Information Not applicable. Not applicable. US Regulations Not available. Section 16. Other Information Other Special Considerations Notice to Reader Version 2 Continued on Next Page Page: 3/4 Page 754 of 878 Page 754 of 878 Page 754 of 878 Page 754 of 878 ---PAGE BREAK--- Material Safety Data Sheet STRIDE CITRUS SC NEUTRAL CLEANER This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Page 755 of 878 Page 755 of 878 Page 755 of 878 Page 755 of 878 ---PAGE BREAK--- Page 756 of 878 Page 756 of 878 Page 756 of 878 Page 756 of 878 ---PAGE BREAK--- Page 757 of 878 Page 757 of 878 Page 757 of 878 Page 757 of 878 ---PAGE BREAK--- Page 758 of 878 Page 758 of 878 Page 758 of 878 Page 758 of 878 ---PAGE BREAK--- Material Safety Data Sheet U.S. Department of Labor May be used to comply with Occupational Safety and Health Administration OSHA's Hazard Communication Standard, (Non-Mandatory-Form) 29 CFR 1910.1200. Standard must be Form Approved consulted for specific requirements. OMB No. 1218-0072 IDENTITY (As Used on Label and List) SUN BRITE BLEACH Note: Blank spaces are not permitted. If any item is not applicable, or no information is available, the space must be marked to indicate that. Section I NA = Not Applicable NIA = No Information Available Manufacturer's Name Sunburst Chemicals, Inc. Emergency Telephone Number 1-[PHONE REDACTED] (7 days/24 hours) Address (Number, Street, City, State, and ZIP Code) 220 W. 86th Street Telephone Number For Information (952)884-3144 Bloomington, MN 55420 Date Prepared 07-19-07 Signature of Preparer (optional) Section II - Hazardous Ingredients/Identity Information Other Limits Hazardous Components (Specific Chemical Identity; Common Name(s)) OSHA PEL ACGIH TLV Recommended %(optional) Sodium Hypochlorite Bleach – CAS #7681-52-9 0.5 ppm TWA 1 ppm TWA Sodium Hydroxide 1310-73-2 2 mg/m3 2mg/m3 Ceiling Section III - Physical/Chemical Characteristics Boiling Point 212°F. Specific Gravity (H20=1) 1.08 Vapor Pressure (mm Hg.) NIA Melting Point NA Vapor Density (AIR=1) NIA Evaporation Rate (Butyl Acetate = 1) NIA Solubility In Water Complete. pH 12.7 Appearance and Odor Clear yellow liquid, chlorine odor. Section IV - Fire and Explosion Hazard Data Flash Point (Method Used) None. Flammable Limits LEL NA UEL NA Extinguishing Media Water, CO2, Dry chemical. Special Fire Fighting Procedures Flood containers with cool water to keep from rupturing. Unusual Fire and Explosion Hazards In extreme heat drums can rupture and chlorine gas may be evolved. HMIS NFPA 2 HEALTH HEALTH HAZARD FIRE HAZARD Flash Points SPECIFIC HAZARD REACTIVITY 0 FLAMMABILITY 4 Deadly 4 Below 73°F (Boiling pt. below 100°F) X Oxidizer OX 4 May detonate 1 REACTIVITY 3 Extreme danger 3 Below 73°F (Boiling pt. at/above 100°F) Acid ACID 3 Shock and heat may detonate B PERSONAL X 2 Hazardous and/or at/above 73°F - not exceeding 100°F Alkali ALK 2 Violent chemical change PROTECTION 1 hazardous 2 Above 100°F, Not Exceeding 200°F Corrosive COR X 1 Unstable if heated 0 Normal material 1 Above 200°F Use NO WATER 0 Stable 0 0 Will not burn Radioactive Page 1 Page 759 of 878 Page 759 of 878 Page 759 of 878 Page 759 of 878 ---PAGE BREAK--- (CONTINUED) – SUN BRITE BLEACH Section V - Reactivity Data Stability Unstable X Conditions to Avoid Heat, acids, ammonia. Stable Incompatibility (Materials to Avoid) Strong acids, ammonia. Hazardous Decomposition or Byproducts Chlorine gas, chloramines. Hazardous Polymerization May Occur Conditions to Avoid Will Not Occur X Section VI - Health Hazard Data Routes(s) of Entry: Inhalation? Skin? Ingestion? Danger of Chlorine gas Minor Not Likely Health Hazards (Acute and Chronic) ACUTE – Skin & Eyes – burns, severe eye damage, blindness. INGESTION – poisoning, gastric distress. CHRONIC – NIA. Carcinogenicity: NTP? IARC Monographs? OSHA Regulated? NIA NIA NIA Signs and of Exposure SKIN – warm sensation, white bubbles form. EYES – severe burning sensation. INGESTION – severe pain in mouth and throat, choking. Medical Conditions Generally Aggravated by Exposure Open sores or wounds, chronic respiratory problems. Emergency and First Aid Procedures EXTERNAL – thoroughly rinse with water for at least 15 minutes. Get immediate medical attention if irritation persists. INTERNAL – drink a large quantity of milk, raw eggs or water. Get immediate medical attention. Section VII – Precautions for Safe Handling and Use Steps to Be Taken in Case Material is Released or Spilled Absorb spilled material with an absorbent material such as clay, or sand. Sweep up as much of this as possible and place in a sealed, labeled container or in a proper landfill. Thoroughly rinse the affected area with water. Waste Disposal Method Spilled material should be collected as above for disposal in a landfill according to Federal, State, and Local regulations. Any rinsing of the affected area should also be in accordance with Federal, State and Local regulations. Precautions to Be Taking in Handling and Storing Avoid contact with skin or clothing. Store between 50-80°F. Keep closed when not in use. Other Precautions Do not allow concentrated product to dry on cloth, paper or flammable material as fire may result. Keep out of reach of children. Section VIII – Control Measures Respiratory Protection (Specify Type) If chlorine gas is expected use self contained breathing apparatus. Ventilation Local Exhaust Use in well ventilated areas. Special NIA Mechanical (General) NIA Other NIA Protective Gloves Rubber or vinyl. Eye Protection Safety glasses, goggles. Other Protective Clothing or Equipment Rubber or vinyl apron or boots. Work/Hygienic Practices Quickly and thoroughly clean up any spills. Always wash hands after handling. Page 2 Page 760 of 878 Page 760 of 878 Page 760 of 878 Page 760 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Product Name Super Iron Out® . 1. Product and Company Identification space CAS # Mixture space Product use Rust & Stain Remover space Manufacturer Iron Out dba Summit Brands 7201 Engle Road Fort Wayne, IN 46804-5875 US Phone: [PHONE REDACTED] Emergency Phone: 1-[PHONE REDACTED] (CHEMTREC) space Personal Protection Physical Hazard Flammability Health B 1 0 2 * Minimal Slight Moderate Serious LEGEND 4 3 2 1 0 Severe 0 2 1 HMIS/NFPA space Emergency overview CAUTION EYE AND SKIN IRRITANT. May cause sensitization by inhalation. . 2. Hazards Identification space Routes of exposure Potential short term health effects Eye, Skin contact, Inhalation, Ingestion. space Eyes Causes irritation. space Skin Causes irritation. space Inhalation Dusts of this product may cause irritation of the nose, throat, and respiratory tract. space Ingestion May cause stomach distress, nausea or vomiting. space Target organs Eyes. Respiratory system. Skin. space Chronic effects Prolonged or repeated exposure can cause drying, defatting and dermatitis. space Signs and may include redness, edema, drying, defatting and cracking of the skin. of overexposure may be headache, dizziness, tiredness, nausea and vomiting. space Ingredient(s) CAS # Percent 30 - 60 7775-14-6 Sodium hydrosulfite 3 - 7 497-19-8 Sodium carbonate 15 - 40 7647-14-5 Sodium chloride 15 - 40 7681-57-4 Sodium metabisulfite 1 - 5 77-92-9 Citric acid 0.1 - 1 7631-90-5 Sodium bisulfite . 3. Composition / Information on Ingredients space Eye contact First aid procedures Immediately flush with cool water. Remove contact lenses, if applicable, and continue flushing for 15 minutes. Obtain medical attention if irritation develops or persists. . 4. First Aid Measures space Skin contact Immediately flush with water. Wash with soap and water. Obtain medical attention if irritation persists. space Inhalation If develop move victim to fresh air. If persist, obtain medical attention. space Page 1 of 7 #7840 22-Aug-2008 Issue date Page 761 of 878 Page 761 of 878 Page 761 of 878 Page 761 of 878 ---PAGE BREAK--- Ingestion Do not induce vomiting. Rinse mouth with water, then drink one or two glasses of water. Obtain medical attention. Never give anything by mouth if victim is unconscious, or is convulsing. space Notes to physician may be delayed. space General advice If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of children. space Flammable properties Not flammable by WHMIS/OSHA criteria. . 5. Fire Fighting Measures space Suitable extinguishing media Extinguishing media Dry chemical. Carbon dioxide. Foam. space Unsuitable extinguishing media Not available space Specific hazards arising from the chemical Protection of firefighters Not available space Protective equipment for firefighters Firefighters should wear full protective clothing including self contained breathing apparatus. space Hazardous combustion products May include and are not limited to: Oxides of sulphur. Hydrogen sulphide. Oxides of carbon. Hydrogen chloride. space Sensitivity to mechanical impact Explosion data Not available space Sensitivity to static discharge Not available space Personal precautions Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak. . 6. Accidental Release Measures space Methods for containment Prevent entry into waterways, sewers, basements or confined areas. space Methods for cleaning up Should not be released into the environment. Before attempting clean up, refer to hazard data given above. Use broom or dry vacuum to collect material for proper disposal without raising dust. Rinse area with water. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. space Handling Use good industrial hygiene practices in handling this material. . 7. Handling and Storage space Storage Keep out of reach of children. Store in a closed container away from incompatible materials. space Page 2 of 7 #7840 22-Aug-2008 Issue date Page 762 of 878 Page 762 of 878 Page 762 of 878 Page 762 of 878 ---PAGE BREAK--- Exposure limits Ingredient(s) Citric acid Exposure Limits TWA: 10 mg/m3 ACGIH-TLV OSHA-PEL TWA: 10 mg/m3 Sodium bisulfite TWA: 5 mg/m3 ACGIH-TLV OSHA-PEL Not established Sodium carbonate Not established ACGIH-TLV OSHA-PEL Not established Sodium chloride Not established ACGIH-TLV OSHA-PEL Not established Sodium hydrosulfite Not established ACGIH-TLV OSHA-PEL Not established Sodium metabisulfite TWA: 5 mg/m3 ACGIH-TLV OSHA-PEL Not established . 8. Exposure Controls / Personal Protection space Engineering controls Use only under good ventilation conditions or with respiratory protection. space Eye / face protection Personal protective equipment Wear safety glasses with side shields. space Hand protection Rubber gloves. Confirm with a reputable supplier first. space Skin and body protection As required by employer code. space Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. space General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. Wash hands before breaks and immediately after handling the product. space Appearance Powder . 9. Physical & Chemical Properties space Color White space Form Powder space Odor Characteristic space Odor threshold Not available space Physical state Solid space pH Not available space Melting point Not available space Freezing point Not available space Boiling point Not available space Flash point None space Evaporation rate Not available space Page 3 of 7 #7840 22-Aug-2008 Issue date Page 763 of 878 Page 763 of 878 Page 763 of 878 Page 763 of 878 ---PAGE BREAK--- Flammability limits in air, lower, % by volume Not applicable space Flammability limits in air, upper, % by volume Not applicable space Vapor pressure Not available space Vapor density Not available space Specific gravity Not available space Octanol/water coefficient Not available space Auto-ignition temperature Not available space Percent volatile Not available space Chemical stability Stable under recommended storage conditions. . 10. Chemical Stability & Reactivity Information space Conditions to avoid Do not mix with other chemicals. space Incompatible materials Acids. Oxidizers. space Hazardous decomposition products May include and are not limited to: Oxides of sulphur. Hydrogen sulphide. Oxides of carbon. Hydrogen chloride. space Possibility of hazardous reactions Hazardous polymerization does not occur. space Component analysis - LC50 Ingredient(s) Citric acid LC50 Not available Sodium bisulfite Not available Sodium carbonate 400 mg/m3 guinea pig Sodium chloride > 21000 mg/m3 rat Sodium hydrosulfite Not available Sodium metabisulfite Not available . 11. Toxicological Information space Component analysis - Oral LD50 Ingredient(s) Citric acid LD50 5040 mg/kg mouse; 3000 mg/kg rat Sodium bisulfite 1420 mg/kg rat Sodium carbonate 4090 mg/kg rat Sodium chloride 3000 mg/kg rat; 4000 mg/kg mouse Sodium hydrosulfite 2500 mg/kg rat Sodium metabisulfite 1131 mg/kg rat space Eye Effects of acute exposure Causes irritation. space Skin Causes irritation. space Inhalation Dusts of this product may cause irritation of the nose, throat, and respiratory tract. space Ingestion May cause stomach distress, nausea or vomiting. space Sensitization Hazardous by WHMIS/OSHA criteria. May cause sensitization by inhalation. space Chronic effects Not classified or listed by IARC, NTP, OSHA and ACGIH. space Page 4 of 7 #7840 22-Aug-2008 Issue date Page 764 of 878 Page 764 of 878 Page 764 of 878 Page 764 of 878 ---PAGE BREAK--- ACGIH - Threshold Limit Values - Carcinogens Sodium bisulfite 7631-90-5 A4 - Not Classifiable as a Human Carcinogen Sodium metabisulfite 7681-57-4 A4 - Not Classifiable as a Human Carcinogen IARC - Group 3 (Not Classifiable) Sodium bisulfite 7631-90-5 Monograph 54 [1992] (listed under Sulfur dioxide and some sulfites bisulfites and metabisulfites) Sodium metabisulfite 7681-57-4 Monograph 54 [1992] (listed under Sulfur dioxide and some sulfites bisulfites and metabisulfites) Carcinogenicity Not classified or listed by IARC, NTP, OSHA and ACGIH. space Mutagenicity Not classified or listed by IARC, NTP, OSHA and ACGIH. space Reproductive effects Not classified or listed by IARC, NTP, OSHA and ACGIH. space Teratogenicity Not classified or listed by IARC, NTP, OSHA and ACGIH. space Ecotoxicity - Freshwater Algae Data Sodium carbonate 497-19-8 120 Hr EC50 242 mg/L Sodium hydrosulfite 7775-14-6 72 Hr EC50 Scenedesmus subspicatus: 120 mg/L; 96 Hr EC50 Scenedesmus subspicatus: 87 mg/L Sodium metabisulfite 7681-57-4 72 Hr EC50 Scenedesmus subspicatus: 48 mg/L; 96 Hr EC50 Scenedesmus subspicatus: 40 mg/L Ecotoxicity - Freshwater Fish Species Data Citric acid 77-92-9 96 Hr LC50 Lepomis macrochirus: 1516 mg/L [static]; 96 Hr LC50 Leuciscus idus: 440 mg/L [static] Sodium bisulfite 7631-90-5 96 Hr LC50 Gambusia affinis: 240 mg/L [static] Sodium carbonate 497-19-8 96 Hr LC50 Lepomis macrochirus: 300 mg/L [static] Sodium hydrosulfite 7775-14-6 96 Hr LC50 Leuciscus idus: 46-68 mg/L [static] Sodium metabisulfite 7681-57-4 96 Hr LC50 Lepomis macrochirus: 32 mg/L [static] Ecotoxicity - Microtox Data Citric acid 77-92-9 15 Min EC50 Photobacterium phosphoreum: 14 mg/L Sodium hydrosulfite 7775-14-6 17 Hr EC50 Pseudomonas putida: 107 mg/L Sodium metabisulfite 7681-57-4 17 Hr EC50 Pseudomonas putida: 56 mg/L Ecotoxicity - Water Flea Data Citric acid 77-92-9 72 Hr EC50 Daphnia magna: 120 mg/L Sodium bisulfite 7631-90-5 48 Hr EC50 Daphnia magna: 119 mg/L Sodium carbonate 497-19-8 48 Hr EC50 Daphnia magna: 265 mg/L Sodium hydrosulfite 7775-14-6 48 Hr EC50 Daphnia magna Straus: 98 mg/L Sodium metabisulfite 7681-57-4 24 Hr EC50 Daphnia magna Straus: 89 mg/L Ecotoxicity Not available . 12. Ecological Information space Environmental effects Not available space Aquatic toxicity Not available space Persistence / degradability Not available space Bioaccumulation / accumulation Not available space Partition coefficient Not available space Mobility in environmental media Not available space Chemical fate information Not available space Waste codes Not available . 13. Disposal Considerations space Disposal instructions Review federal, provincial, and local government requirements prior to disposal. space Waste from residues / unused products Not available space Contaminated packaging Not available space U.S. Department of Transportation (DOT) Not regulated as dangerous goods. . 14. Transport Information space Transportation of Dangerous Goods (TDG - Canada) Not regulated as dangerous goods. space Page 5 of 7 #7840 22-Aug-2008 Issue date Page 765 of 878 Page 765 of 878 Page 765 of 878 Page 765 of 878 ---PAGE BREAK--- Canada - WHMIS - Ingredient Disclosure List Citric acid 77-92-9 1 % Sodium bisulfite 7631-90-5 1 % Sodium carbonate 497-19-8 1 % Sodium metabisulfite 7681-57-4 1 % Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. . 15. Regulatory Information space U.S. - CERCLA/SARA - Hazardous Substances and their Reportable Quantities Sodium bisulfite 7631-90-5 5000 Lb final RQ; 2270 kg final RQ US Federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. space 29 CFR 1910.1200 hazardous chemical Occupational Safety and Health Administration (OSHA) Yes space CERCLA (Superfund) reportable quantity Sodium bisulfite: 5000.0000 Sodium tripolyphosphate: 5000.0000 Metaphosphoric acid, trisodium salt: 5000.0000 space Hazard categories Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - No Pressure Hazard - No Reactivity Hazard - Yes space Section 302 extremely hazardous substance No space Section 311 hazardous chemical Yes space Clean Air Act (CAA) Not available space Clean Water Act (CWA) Not available space Safe Drinking Water Act (SDWA) Not available space Drug Enforcement Agency (DEA) Not available space Food and Drug Administration (FDA) Not available space WHMIS status Controlled space WHMIS classification Class D - Division 2A, 2B space WHMIS labeling space Page 6 of 7 #7840 22-Aug-2008 Issue date Page 766 of 878 Page 766 of 878 Page 766 of 878 Page 766 of 878 ---PAGE BREAK--- U.S. - California - 8 CCR Section 339 - Director's List of Hazardous Substances Sodium bisulfite 7631-90-5 Present Sodium metabisulfite 7681-57-4 Present U.S. - Louisiana - Reportable Quantity List for Pollutants Sodium bisulfite 7631-90-5 5000 Lb final RQ; 2270 kg final RQ U.S. - Massachusetts - Right To Know List Sodium bisulfite 7631-90-5 Present Sodium hydrosulfite 7775-14-6 Present Sodium metabisulfite 7681-57-4 Present U.S. - Minnesota - Hazardous Substance List Sodium bisulfite 7631-90-5 Present Sodium metabisulfite 7681-57-4 Present U.S. - New Jersey - Right to Know Hazardous Substance List Sodium bisulfite 7631-90-5 sn 1685 Sodium hydrosulfite 7775-14-6 sn 1697 Sodium metabisulfite 7681-57-4 sn 1708 U.S. - New York - Reporting of Releases Part 597 - List of Hazardous Substances Sodium bisulfite 7631-90-5 5000 Lb RQ (air); 100 lb RQ (land/water) U.S. - - RTK (Right to Know) List Sodium bisulfite 7631-90-5 Environmental hazard Sodium hydrosulfite 7775-14-6 Present Sodium metabisulfite 7681-57-4 Present U.S. - Rhode Island - Hazardous Substance List Sodium bisulfite 7631-90-5 Toxic Sodium hydrosulfite 7775-14-6 Flammable Sodium metabisulfite 7681-57-4 Toxic State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. space A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) Inventory name Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada No Non-Domestic Substances List (NDSL) United States & Puerto Rico Yes Toxic Substances Control Act (TSCA) Inventory space Disclaimer Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. . 16. Other Information space Issue date 22-Aug-2008 space Effective date 15-Aug-2008 space Expiry date 15-Aug-2011 space Prepared by Dell Tech Laboratories Ltd. (519) 858-5021 space Page 7 of 7 #7840 22-Aug-2008 Issue date Page 767 of 878 Page 767 of 878 Page 767 of 878 Page 767 of 878 ---PAGE BREAK--- Spartan Chemical Company, Inc. Material Safety Data Sheet SECTION I: PRODUCT INFORMATION Product Name or Number (as it appears on label): Product Division: SUPERIOR HIGH SHINE STAINLESS STEEL CLEANER & POLISH (AEROSOL) Product Number: 6290 Janitorial Spartan Chemical Company, Inc. Product/Technical Information:1-(800)-537-8990 1110 Spartan Drive Medical Emergency:1-(888)-314-6171 (24 hours) Maumee, OH 43537 Chemical Leak/Spill Emergency:CHEMTREC 1-(800) 424-9300 (24 hours) Shipping Description: ORM-D, Consumer commodity NFPA Ratings: HMIS Ratings: Health: 1- Slight Health: *1 - Slight; Chronic Hazard Fire: 3 - Serious Fire: 3 - Serious Reactivity: 1- Slight Reactivity: 1- Slight Pers. Prot. Equip.: See Section VIII SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1% or greater, carcinogens at 0.1% or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. Chemical Name(s) % W CAS Registry No. Table Z- 1 - A NTP, IARC or OSHA Carcinogen TWA mg/m3 STEL mg/m 3 CELING mg/m3 Petroleum distillate 55-65 64742-47-8 1200 (Exxon) Not Established Not Established No Petroleum distillate 10-20 64741-44-2 5 (oil mist) 10 (NIOSH) Not Established No Propane 10-20 74-98-6 1800 Not Established Not Established No Isobutane 10-20 75-28-5 1900 (NIOSH) Not Established Not Established No SECTION III: PHYSICAL DATA Boiling Point: -44 to 529 °F Vapor Pressure: Unknown Vapor Density (AIR = Heavier than air. Solubility in Water: Negligible pH: NA Specific Gravity (H2O=1): 0.75 (Concentrate) Evaporation Rate (but.ace.=1): <1 Percent Solid by Weight: NA Physical State: Aerosol can (pressurized liquid) Appearance & Odor: Lemon fragrance Page 768 of 878 Page 768 of 878 Page 768 of 878 Page 768 of 878 ---PAGE BREAK--- SECTION IV: FIRE & EXPLOSIVE HAZARD DATA Flash Point: Propellant: < 0°F Method Used: Estimate Flammable Limits: Not Established Explosive Limits: Lower: 0.5% Upper: 9.5% Flame Extension: > 18 Inches NFPA 30B Level 3 Aerosol Extinguishing Media: Carbon dioxide, Dry chemical, Special Fire Fighting Procedures: Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Wear a full face positive pressure self contained breathing apparatus when fighting fires. Unusual Fire & Explosive Hazards: Material is highly volatile and readily gives off vapors which may travel along the ground or be moved by ventilation and ignited by pilot lights, other flames, sparks, heaters, smoking, electrical motors, static discharge or other ignition sources at locations distant from material handling point. SECTION V: HEALTH HAZARD DATA Threshold Limit Value: Not Established Primary Routes of Entry: Inhalation, Skin Contact, Eyes & Oral Effects of Overexposure- Conditions to Avoid: Harmful or Fatal if Swallowed. Small amounts of this product aspirated into the respiratory system during ingestion or vomiting may cause mild to severe pulmonary injury. Harmful if Inhaled. Inhalation of vapors may cause central nervous system effects including dizziness, weakness, fatigue, nausea, headache, loss of consciousness depending on vapor concentration and duration of exposure. Prolonged exposure above the OSHA permissible exposure limits may result in kidney and liver damage. The intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Causes Skin Irritation. Frequent or prolonged contact may cause dermatitis. Causes Eye Irritation. Do not breathe vapors or mists. Avoid contact with eyes and skin. Do not swallow. Conditions Aggravated by Use: Preexisting skin; eye and respiratory disorders. Emergency & First Aid Procedures: Eyes: Flush eyes with water for at least 15 minutes. Remove contact lenses. Get medical attention. Skin: Wash thoroughly with soap and water while removing contaminated clothing. Get medical attention if irritation persists. Wash contaminated clothing before reuse. Ingestion: Do not induce vomiting. Call a physician immediately. Inhalation: Move person to fresh air. If breathing is difficult; give oxygen. If breathing has stopped; give artificial respiration. Get medical attention. Note to Physician: Contains Petroleum distillates. May cause chemical pneumonia if aspirated into the lungs. SECTION VI: REACTIVITY DATA Stability: Stable Incompatible Materials: Avoid contact with strong oxidizing agents; strong alkalis and strong mineral acids. Hazardous Decomposition Products: Burning can produce carbon monoxide, carbon dioxide and phosgene gas Hazardous Polymerization: Will Not Occur SECTION VII: SPILL OR LEAK PROCEDURES Steps to be Taken in Case Material is Released or Spilled: Ventilate area. Remove all sources of ignition. Clean up with inert materials and dispose of in accordance with all local, state and federal regulations. Page 769 of 878 Page 769 of 878 Page 769 of 878 Page 769 of 878 ---PAGE BREAK--- Waste Disposal Method: Do not puncture or incinerate aerosol containers. Empty containers may be disposed of through normal channels. Full or partially filled containers are considered hazardous waste. SECTION VIII: SPECIAL PROTECTION INFORMATION Respiratory Protection: Not normally required. However, if exposure limits are exceeded (see Section II) a fully functioning NIOSH approved respirator suitable for the ingredients in Section II should be worn. Ventilation: Good general ventilation should be sufficient for most conditions. Local exhaust ventilation may be necessary for some operations. Protective Gloves(Specify Type): Rubber or other impervious gloves are recommended for skin contact. Eye Protection(Specify Type): Use of chemical goggles is recommended to prevent eye contact. Other Protective Equipment: See 29 CFR 1910.132 -138. Page 770 of 878 Page 770 of 878 Page 770 of 878 Page 770 of 878 ---PAGE BREAK--- SECTION IX: SPECIAL PRECAUTIONS Precautions; Handling & Storing: Do not puncture or incinerate container. Do not use or store product near heat, sparks or open flame. Do not store in direct sunlight or above 120 F. High temperatures may cause container to burst. Wash thoroughly after handling. Other Precautions: Keep out of reach of children. © SCC 06/08/2009 Name: Ronald T. Cook Title: Manager, Regulatory Affairs SUPERIOR HIGH SHINE STAINLESS STEEL CLEANER & POLISH (AEROSOL) Effective Date: 06/08/2009 Supercedes: 05/03/2006 Ref: 29 CFR 1910.1200 (OSHA) Changes: Update Section V This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. Page 771 of 878 Page 771 of 878 Page 771 of 878 Page 771 of 878 ---PAGE BREAK--- TANNIN STAIN REMOVER 4252 Industrial/Institutional: Carpet care. 1/17/2001 1/17/2001 Material Safety Data Sheet Product Name Product Use Validation Date Print Date In Case of Emergency Section 1. Chemical Product and Company Identification Supersedes 1/10/2001. Health 1 0 0 Fire Hazard Reactivity Specific Hazard Health Fire Hazard Reactivity Protective Clothing 0 0 1 (800) 851-7145 Johnson Wax Professional 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249 MSDS Internet Address: www.jwp.com U.S. Headquarters Johnson Wax Professional 100 Matheson Blvd. East, Suite 203 Mississauga, Ontario L4Z 2G7 Phone: (905) 755-0913 or (888) 746-5971 Hazardous Material Information System (HMIS) National Fire Protection Association (NFPA) Code MSDS# 126333004 436897 Canadian Headquarters Clear Colorless. Liquid. See Section 9. CAUTION: May be mildly irritating to eyes. May be mildly irritating to skin. Emergency Overview None required. PMS# TANNIN STAIN REMOVER Sodium Xylene Sulfonate 1300-72-7 1-5 Not available. Not available. Surfactant [PHONE REDACTED]-P-PC) 1-5 Not available. Not available. Diethylene Glycol Butyl Ether 112-34-5 1-5 Not available. ORAL (LD50): Acute: 5660 mg/kg [Rat]. DERMAL (LD50): Acute: 2700 mg/kg [Rabbit]. Citric Acid 77-92-9 5-10 Not available. ORAL (LD50): Acute: 3000 mg/kg [Rat]. Water 7732-18-5 60-100 Not available. Not available. Section 2. Composition and Information on Ingredients Ingredients CAS # % by Weight Exposure Limits LC50/LD50 Inhalation. Skin contact. Eye contact. Medical Conditions Aggravated by Overexposure: None known. Section 3. Hazards Identification Routes of Entry Potential Acute Health Effects None known. May be mildly irritating to eyes. None known. May be mildly irritating to skin. Eyes Skin Inhalation Ingestion See Toxicological Information (section 11) No specific first aid measures are required. Flush immediately with plenty of water. Get medical attention if irritation occurs. Flush immediately with plenty of water. Get medical attention if irritation occurs. No specific first aid measures are required. Section 4. First Aid Measures Eye Contact Skin Contact Inhalation Ingestion Continued on Next Page Page: 1/4 Page 772 of 878 Page 772 of 878 Page 772 of 878 Page 772 of 878 ---PAGE BREAK--- Material Safety Data Sheet TANNIN STAIN REMOVER None known. None known. None. Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire fighting procedure may be used. None known. Section 5. Fire Fighting Measures Flammability of the Product Flash Points Products of Combustion Fire Fighting Media and Instructions Special Remarks on Fire and Explosion Hazards In the event of major spillage: Use appropriate containment to avoid environmental contamination. Sweep or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a water rinse for final clean-up. Put on appropriate personal protective equipment (see Section Section 6. Accidental Release Measures Personal Precautions Environmental Precautions and Clean-up Methods Store in a dry, cool and well-ventilated area. Protect from freezing. KEEP OUT OF REACH OF CHILDREN. Avoid contact with skin and eyes. FOR INDUSTRIAL USE ONLY. Section 7. Handling and Storage Handling Storage No special ventilation requirements. General room ventilation is adequate. Section 8. Exposure Controls/Personal Protection Engineering Controls No special requirements under normal use conditions. No special requirements under normal use conditions. No special protective clothing is required. No special requirements under normal use conditions. No special requirements under normal use conditions. Personal Protection Eyes Hands Respiratory Feet Body Liquid. 3 to 3.4 [Acidic.] 0°C (32°F) 1.03 Fruity. Clear Colorless. Melting/Freezing Point Section 9. Physical and Chemical Properties Physical State and Appearance pH Specific Gravity Solubility in water Odor Color Complete. The product is stable. Avoid mixing with: alkalis Will not occur. When exposed to fire: Produces normal products of combustion. None known. Section 10. Stability and Reactivity Stability and Reactivity Conditions of Instability Incompatibility with Various Substances Hazardous Decomposition Products Hazardous Polymerization Continued on Next Page Page: 2/4 Page 773 of 878 Page 773 of 878 Page 773 of 878 Page 773 of 878 ---PAGE BREAK--- Material Safety Data Sheet TANNIN STAIN REMOVER Section 11. Toxicological Information Effects of Chronic Exposure Other Toxic Effects None known. ORAL (LD50) Greater than 5000 mg/kg (rat). Acute toxicity None known. Section 12. Ecological Information Not available. No special precautions. Dispose of according to all federal, state and local regulations. Waste Information Section 13. Disposal Considerations Consumer Commodity ORM-D Section 14. Transport Information DOT Classification DOT Proper Shipping Name DOT Class TDG Classification TDG Proper Shipping Name TDG Class Consumer Commodity ORM-D State Section 15. Regulatory Information Chemical Inventory Status Federal Canadian Regulations Not controlled under WHMIS (Canada). All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Registered Product Information This product is not subject to the reporting requirements under California's Proposition 65. Reporting in this section is based on ingredients disclosed in Section 2 WHMIS Classification WHMIS Icon New Jersey spill list: Diethylene Glycol Butyl Ether New Jersey: Diethylene Glycol Butyl Ether RTK: Diethylene Glycol Butyl Ether CERCLA: Hazardous substances.: Diethylene Glycol Butyl Ether Registered Product Information Not applicable. Not applicable. US Regulations Continued on Next Page Page: 3/4 Page 774 of 878 Page 774 of 878 Page 774 of 878 Page 774 of 878 ---PAGE BREAK--- Material Safety Data Sheet TANNIN STAIN REMOVER Not available. Section 16. Other Information Other Special Considerations Notice to Reader This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Version 1.02 Page 775 of 878 Page 775 of 878 Page 775 of 878 Page 775 of 878 ---PAGE BREAK--- SECTION 1: Identification Manufacturer: Tech Enterprises, Inc. PO Box 259294 - Madison, WI 53725-9294 Call for emergency or further assistance: [PHONE REDACTED] M-Th: 8:00am - 4:00pm; Fri: 8:00am - 12:00pm Chemical Name: TECH Stain Remover Synonyms: N/A Chemical Family: N/A Formula: Proprietary/Trade Secret Molecular Weight: N/A Product Identifier/Name: TECH Stain Remover Product Use: Removal of water based and oil based stains on carpet, clothing, upholstery, and vinyl. Manufacturer UPC: 38048 Restrictions on Use: Use for the removal of water based and oil based stains on carpet, clothing, upholstery, and vinyl. SDS Preparation Date: 12/12/2014 SDS # 3030 Revision # 1.1 SECTION 2: Hazards Identification EMERGENCY OVERVIEW: Non-hazardous, non-toxic, not considered to be an eye-irritant or a skin irritant. Physical State: Liquid Odor: Undetectable Color: Transparent - Colorless How Best Monitored: Use as directed Emergency Instructions: Rinse with water. Product is completely non-toxic, not a skin irritant nor an eye irritant. Potential Health and Environmental Effects: To the best of our knowledge this product has no potential for adverse health or environmental effects. This product is considered to be non-hazardous according to the criteria established by OSHA and CA Prop 65. SECTION 3: Composition/Information on Ingredients Hazardous Ingredients: None Note: This product is a water-based substance which contains no hydrocarbons and is non-flammable. To the best of our knowledge this product is regarded as non-hazardous according to the criteria and list of chemicals provided by OSHA. No TLV's or USOS limits are established. Substances: Proprietary Mixtures: Proprietary All Chemicals: Proprietary Proprietary/Trade Secret: The specific chemical identity of composition has been withheld as a trade secret. SECTION 4: First Aid Measures Emergency/First Aid Procedures for Ingestion, skin contact, or eye contact: Rinse with water. Immediate None Delayed None SECTION 5: Fire Fighting Measures THIS PRODUCT IS NOT COMBUSTIBLE NOR DOES IT SUPPORT COMBUSTION. FLASH POINT (TEST METHOD) N/A AUTOIGNITION TEMP. N/A FLAMMABLE LIMITS IN AIR - % BY VOLUME LOWER - N/A UPPER - N/A EXTINGUISHING MEDIA N/A SPECIAL FIRE FIGHTING PROCEDURES N/A SPECIAL FIRE FIGHTING PROTECTIVE EQUIPMENT N/A UNUSUAL FIRE AND EXPLOSION HAZARD N/A HEALTH: HMIS NFPA KEY 0 0 0=Minimal 1=Slight 2=Moderate 3=Serious 4=Severe REACTIVITY: 0 0 FLAMMABILITY: 0 0 SECTION 6: Accidental Release Measures Steps to be taken if Material is Released or Spilled: Pick up excess with absorbent type material. Remainder can be flushed/rinsed down the drain to a municipal water treatment system. Spilled material is somewhat slippery on walkways and highways. Personal Precautions and Protective Equipment: N/A Methods and Materials need for Containment: N/A Waste Disposal Method: N/A Emergency Procedures: N/A SECTION 7: Handling and Storage HANDLING Avoid elevated or freezing temperatures. Keep containers closed. STORAGE CONDITIONS Store at ambient temperatures. Maintain above freezing. SECTION 8: Exposure Controls / Personal Protection PRECAUTIONARY LABELING WHICH MEETS FEDERAL GOVERNMENT REQUIREMENTS N/A - The information contained above is believed to be accurate at the time of submission. It is offered in good faith but without guarantee. Since conditions of use are beyond our control all risks of use are assumed by the user. No type of personal protective equipment is required under normal conditions. PPE: (Personal Protective Equipment) Respiratory Protection: Not Required Ventilation: Not Required STAIN REMOVER Safety Data Sheet (SDS) Page 776 of 878 Page 776 of 878 Page 776 of 878 Page 776 of 878 ---PAGE BREAK--- Protective Gloves: Not Required Eye Protection: Not Required TLV: (Threshold Limit Value) TECH Stain Remover is considered: non-toxic by oral ingestion, not a primary skin irritant, not an eye irritant. PEL: (Personal Exposure Limits) Effects of Overexposure: N/A Recommended Exposure Limit There is no exposure limit. SECTION 9: Physical and Chemical Properties ph BALANCE 9.5 VISCOSITY 1.09 cs (ASTM D 445) Cannon-Fenske BOILING PT. 760 mm. Hg 100 C FREEZING POINT 0 C MELTING POINT N/A FLASH POINT N/A FLAMMABILITY N/A UPPER/LOWER FLAMMABILITY/EXPLOSIVE LIMITS N/A AUTO IGNITION TEMPERTURE N/A PARTITION COEFFICIENT: n-octanol/water N/A DECOMPOSITION TEMPERATURE N/A SPECIFIC GRAVITY (H2O=1) 1.024 VAPOR PRESSURE AT 20 C 17 mm Hg VAPOR DENSITY (AIR = 1) <1 SOLUBILITY IN WATER, % by wt. at 20 C. INFINITE -FULLY ODOR ODOR THRESHOLD Undetectable N/A EVAPORATION RATE (WATER=1) 1 RELATIVE DENSITY 1 APPEARANCE AND COLOR Liquid Colorless Transparent Odorless VOLATILE ORGANIC COMPOUND VOC None SECTION 10: Stability and Reactivity STABILITY REACTIVITY HAZARDS Non-stable: Stable: X None expected - 0 Hazardous polymerization will NOT occur. Keep out of intense sunlight Conditions to avoid: NONE Keep from freezing Hazardous decomposition products: NONE Materials to avoid: NONE SECTION 11: Toxicological Information TLV: Not established Inhalation/Ingestion/Skin Contact/Eye Contact: Non-hazardous, non-toxic, not considered to be an eye-irritant or a skin irritant. Immediate Effects: None Delayed Effects: None Level of Toxicity: N/A N/A This product is considered to be non-carcinogenic. SECTION 12: Ecological Information Non- Hazardous, Biodegradable. - Dispose of in accordance with all local, state and federal regulations. SECTION 13: Disposal Considerations Non- Hazardous. No special or specific disposal instructions required. Dispose of in accordance with all local, state and federal regulations. SECTION 14: Transport Information Non- Hazardous US DEPT OF TRANSPORTATION WATER TRANSPORTATION AIR TRANSPORTATION Proper Shipping Name: Not regulated by the DOT Proper Shipping Name: Not regulated Proper Shipping Name: Not regulated Hazard Class: N/A Hazard Class: N/A Hazard Class: N/A ID Number: N/A ID Number: N/A ID Number: N/A Packing Group: N/A Packing Group: N/A Packing Group: N/A Label Statement: N/A Label Statement: N/A Label Statement: N/A SECTION 15: Regulatory Information TSCA (Toxic Substance Control Act) All chemical substances contained in this product are either on the TSCA Inventory List or are exempt from TSCA Inventory requirements. 313 Reportable ingredients: N/A CERCLA (Comprehensive Response Compensation and Liability Act) Releases of this material to air, land, or water are not reportable to the National Response Center under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) or to state and local emergency planning committees under Superfund Amendments and Reauthorization Act (SARA) Title III Section 304. State Regulations: California (Proposition 65) - No substances known to the State of California to cause cancer, birth defects, or other reproductive harm are found in this product or vapors. Follow all applicable directions for use when handling this product. (California Health and Safety Code Section 25249.6) SARA TITLE III (Superfund Amendments and Reauthorization Act) N/A International Regulations: 311/312 Hazard Categories: N/A Notes: Non-hazardous SECTION 16: Other Information - The information contained herein is believed to be accurate, based on current component SDS knowledge and experience. It is provided independently of any sale of this product for purpose of hazard communication as part of the product safety program. It is not intended to constitute performance information concerning this product. No responsibility is assumed that the information is sufficient or correct in all cases. No express or implied warranty of merchantability or fitness for particular purpose is made with respect to the product or the information contained herein. This information and product are provided on the condition that the user shall make determination as to the suitability for a particular purpose, and on the condition that the user shall assume all risks of use thereof. Page 777 of 878 Page 777 of 878 Page 777 of 878 Page 777 of 878 ---PAGE BREAK--- SECTION 1: Product and Company Identification Manufacturer: Tech Enterprises, Inc. PO Box 259294 - Madison, WI 53725-9294 Call for emergency or further assistance: [PHONE REDACTED] M-Th: 8:00am - 4:00pm; Fri: 8:00am - 12:00pm Chemical Name: Non hazardous Synonyms: Non hazardous Chemical Family: Non hazardous Formula: Non hazardous Molecular Weight: N/A Product Name: TECH Stain Remover Product Use: Removal of water based and oil based stains on carpet, clothing, upholstery, and vinyl. Manufacturer UPC: 38048 MSDS Preparation Date: 01/01/2013 SECTION 2: Composition/Information on Ingredients - Hazardous Ingredients Hazardous Ingredients: None Note: This product is a water-based substance which contains no hydrocarbons and is non-flammable. To the best of our knowledge this product is regarded as non-hazardous according to the criteria and list of chemicals provided by OSHA. No TLV's or USOS limits are established. SECTION 3: Hazards Identification: Physical and Chemical Characteristics EMERGENCY OVERVIEW: Non-hazardous, non-toxic, not considered to be an eye-irritant or a skin irritant. Physical State: Liquid Odor: Undetectable Color: Transparent - Colorless How Best Monitored: Use as directed Emergency Instructions: Rinse with water. Product is completely non-toxic, not a skin irritant nor an eye irritant. Potential Health and Environmental Effects: To the best of our knowledge this product has no potential for adverse health or environmental effects. This product is considered to be non hazardous according to the criteria established by OSHA and CA Prop 65. SECTION 4: First Aid Measures Emergency/First Aid Procedures for Ingestion , skin contact, or eye contact: Rinse with water. Immediate Effects: None Delayed Effects: None SECTION 5: Fire and Explosion Data - Fire Fighting Measures THIS PRODUCT IS NOT COMBUSTIBLE NOR DOES IT SUPPORT COMBUSTION. FLASH POINT (TEST METHOD) N/A AUTOIGNITION TEMP. N/A FLAMMABLE LIMITS IN AIR - % BY VOLUME LOWER - N/A UPPER - N/A EXTINGUISHING MEDIA N/A SPECIAL FIRE FIGHTING PROCEDURES N/A UNUSUAL FIRE AND EXPLOSION HAZARD N/A HEALTH: HMIS NFPA KEY 0 0 0=Minimal 1=Slight 2=Moderate 3=Serious 4=Severe REACTIVITY: 0 0 FLAMMABILITY: 0 0 SECTION 6: Accidental Release Measures Steps to be taken if Material is Released or Spilled: Pick up excess with absorbent type material. Remainder can be flushed/rinsed down the drain to a municipal water treatment system. Spilled material is somewhat slippery on walkways and highways. Waste Disposal Method: N/A SECTION 7: Handling and Storage HANDLING Avoid elevated or freezing temperatures. Keep containers closed. STORAGE CONDITIONS Store at ambient temperatures. Maintain above freezing. SECTION 8: Exposure Controls / Personal Protection PRECAUTIONARY LABELING WHICH MEETS FEDERAL GOVERNMENT REQUIREMENTS N/A - The information contained above is believed to be accurate at the time of submission. It is offered in good faith but without guarantee. Since conditions of use are beyond our control all risks of use are assumed by the user. No type of personal protective equipment is required under normal conditions. Respiratory Protection: Not Required Ventilation: Not Required Protective Gloves: Not Eye Protection: Not Required STAIN REMOVER Material Safety Data Sheet Page 778 of 878 Page 778 of 878 Page 778 of 878 Page 778 of 878 ---PAGE BREAK--- Required Threshold Limit Value TECH Stain Remover is considered: non-toxic by oral ingestion, not a primary skin irritant, not an eye irritant. Effects of Overexposure: N/A Recommended Exposure Limit There is no exposure limit. SECTION 9: Physical and Chemical Properties ph BALANCE 9.5 VISCOSITY 1.09 cs (ASTM D 445) Cannon-Fenske BOILING PT. 760 mm. Hg 100 C FREEZING POINT 0 C SPECIFIC GRAVITY (H2O=1) 1.024 VAPOR PRESSURE AT 20 C 17 mm Hg VAPOR DENSITY (AIR = 1) <1 SOLUBILITY IN WATER, % by wt. at 20 C. INFINITE -FULLY ODOR Undetectable EVAPORATION RATE (WATER=1) 1 APPEARANCE AND COLOR Liquid Colorless Transparent Odorless VOLATILE ORGANIC COMPOUND VOC None SECTION 10: Stability and Reactivity STABILITY HAZARDS Non-stable: Stable: X Hazardous polymerization will NOT occur. Keep out of intense sunlight Conditions to avoid: NONE Keep from freezing Hazardous decomposition products: NONE Materials to avoid: NONE SECTION 11: Toxicological Information TLV: Not established SECTION 12: Ecological Information Non- Hazardous, Biodegradable. - Dispose of in accordance with all local, state and federal regulations. SECTION 13: Disposal Considerations Non- Hazardous. No special or specific disposal instructions required. Dispose of in accordance with all local, state and federal regulations. SECTION 14: Transport Information Non- Hazardous US DEPT OF TRANSPORTATION WATER TRANSPORTATION AIR TRANSPORTATION Proper Shipping Name: Not regulated by the DOT Proper Shipping Name: Not regulated Proper Shipping Name: Not regulated Hazard Class: N/A Hazard Class: N/A Hazard Class: N/A ID Number: N/A ID Number: N/A ID Number: N/A Packing Group: N/A Packing Group: N/A Packing Group: N/A Label Statement: N/A Label Statement: N/A Label Statement: N/A SECTION 15: Regulatory Information TSCA (Toxic Substance Control Act) All chemical substances contained in this product are either on the TSCA Inventory List or are exempt from TSCA Inventory requirements. 313 Reportable ingredients: N/A CERCLA (Comprehensive Response Compensation and Liability Act) Releases of this material to air, land, or water are not reportable to the National Response Center under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) or to state and local emergency planning committees under Superfund Amendments and Reauthorization Act (SARA) Title III Section 304. State Regulations: California (Proposition 65) - No substances known to the State of California to cause cancer, birth defects, or other reproductive harm are found in this product or vapors. Follow all applicable directions for use when handling this product. (California Health and Safety Code Section 25249.6) SARA TITLE III (Superfund Amendments and Reauthorization Act) N/A International Regulations: 311/312 Hazard Categories: N/A Notes: Non-hazardous SECTION 16: Other Information - The information contained herein is believed to be accurate, based on current component MSDS knowledge and experience. It is provided independently of any sale of this product for purpose of hazard communication as part of the product safety program. It is not intended to constitute performance information concerning this product. No responsibility is assumed that the information is sufficient or correct in all cases. No express or implied warranty of merchantability or fitness for particular purpose is made with respect to the product or the information contained herein. This information and product are provided on the condition that the user shall make determination as to the suitability for a particular purpose, and on the condition that the user shall assume all risks of use thereof. Page 779 of 878 Page 779 of 878 Page 779 of 878 Page 779 of 878 ---PAGE BREAK--- STAIN REMOVER Material Safety Data Sheet SECTION 1: Product and Company Identification Manufacturer: Tech Enterprises, Inc. PO Box 259294 - Madison, WI 53725-9294 Call for emergency or further assistance: [PHONE REDACTED] M-Th: 8:00am - 4:00pm; Fri: 8:00am - 12:00pm Chemical Name: Non hazardous Synonyms: Non hazardous Chemical Family: Non hazardous Formula: Non hazardous Molecular Weight: N/A Product Name: TECH Stain Remover Product Use: Removal of water based and oil based stains on carpet, clothing, upholstery, and vinyl. Manufacturer UPC: 38048 MSDS Preparation Date: 01/01/2010 SECTION 2: Composition/Information on Ingredients - Hazardous Ingredients Hazardous Ingredients: None Note: This product is a water-based substance which contains no hydrocarbons and is non-flammable. To the best of our knowledge this product is regarded as non-hazardous according to the criteria and list of chemicals provided by OSHA. No TLV's or USOS limits are established. SECTION 3: Hazards Identification: Physical and Chemical Characteristics EMERGENCY OVERVIEW: Non-hazardous, non-toxic, not considered to be an eye-irritant or a skin irritant. Physical State: Liquid Odor: Undetectable Color: Transparent - Colorless How Best Monitored: Use as directed Emergency Instructions: Rinse with water. Product is completely non-toxic, not a skin irritant nor an eye irritant. Potential Health and Environmental Effects: To the best of our knowledge this product has no potential for adverse health or environmental effects. This product is considered to be non hazardous according to the criteria established by OSHA and CA Prop 65. SECTION 4: First Aid Measures Emergency/First Aid Procedures for Ingestion , skin contact, or eye contact: Rinse with water. Immediate Effects: None Delayed Effects: None SECTION 5: Fire and Explosion Data - Fire Fighting Measures THIS PRODUCT IS NOT COMBUSTIBLE NOR DOES IT SUPPORT COMBUSTION. FLASH POINT (TEST METHOD) N/A AUTOIGNITION TEMP. N/A FLAMMABLE LIMITS IN IR - % BY VOLUME A LOWER - N/A UPPER - N/A EXTINGUISHING MEDIA N/A SPECIAL FIRE FIGHTING PROCEDURES N/A UNUSUAL FIRE AND EXPLOSION HAZARD N/A HEALTH: HMIS NFPA KEY 0 0 0=Minimal 1=Slight 2=Moderate 3=Serious 4=Severe REACTIVITY: 0 0 FLAMMABILITY: 0 0 SECTION 6: Accidental Release Measures Steps to be taken if Material is Released or Spilled: Pick up excess with absorbent type material. Remainder can be flushed/rinsed down the drain to a municipal water treatment system. Spilled material is somewhat slippery on walkways and highways. Waste Disposal Method: N/A SECTION 7: Handling and Storage HANDLING Avoid elevated or freezing temperatures. Keep containers closed. STORAGE CONDITIONS Store at ambient temperatures. Maintain above freezing. SECTION 8: Exposure Controls / Personal Protection PRECAUTIONARY LABELING WHICH MEETS FEDERAL GOVERNMENT REQUIREMENTS N/A - The information contained above is believed to be accurate at the time of submission. It is offered in good faith but without guarantee. Since conditions of use are beyond our control all risks of use are assumed by the user. No type of personal protective equipment is required under normal conditions. Page 780 of 878 Page 780 of 878 Page 780 of 878 Page 780 of 878 ---PAGE BREAK--- Respiratory Protection: Not Required Ventilation: Not Required Protective Gloves: Not Required Eye Protection: Not Required Threshold Limit Value TECH Stain Remover is considered: non-toxic by oral ingestion, not a primary skin irritant, not an eye irritant. Effects of Overexposure: N/A Recommended Exposure Limit There is no exposure limit. SECTION 9: Physical and Chemical Properties ph BALANCE 9.5 VISCOSITY 1.09 cs (ASTM D 445) Cannon-Fenske BOILING PT. 760 mm. Hg 100 C FREEZING POINT 0 C SPECIFIC GRAVITY (H2O=1) 1.024 VAPOR PRESSURE AT 20 C 17 mm Hg VAPOR DENSITY (AIR = 1) <1 SOLUBILITY IN WATER, % by wt. at 20 C. INFINITE -FULLY ODOR Undetectable EVAPORATION RATE (WATER=1) 1 APPEARANCE AND COLOR Liquid Colorless Transparent Odorless VOLATILE ORGANIC COMPOUND VOC None SECTION 10: Stability and Reactivity STABILITY HAZARDS Non-stable: Stable: X Hazardous polymerization will NOT occur. Keep out of intense sunlight Conditions to avoid: NONE Keep from freezing Hazardous decomposition products: NONE Materials to avoid: NONE SECTION 11: Toxicological Information TLV: Not established SECTION 12: Ecological Information Non- Hazardous, Biodegradable. - Dispose of in accordance with all local, state and federal regulations. SECTION 13: Disposal Considerations Non- Hazardous. No special or specific disposal instructions required. Dispose of in accordance with all local, state and federal regulations. SECTION 14: Transport Information Non- Hazardous US DEPT OF TRANSPORTATION WATER TRANSPORTATION AIR TRANSPORTATION Proper Shipping Name: Not regulated by the DOT Proper Shipping Name: Not regulated Proper Shipping Name: Not regulated Hazard Class: N/A Hazard Class: N/A Hazard Class: N/A ID Number: N/A ID Number: N/A ID Number: N/A Packing Group: N/A Packing Group: N/A Packing Group: N/A Label Statement: N/A Label Statement: N/A Label Statement: N/A SECTION 15: Regulatory Information TSCA (Toxic Substance Control Act) All chemical substances contained in this product are either on the TSCA Inventory List or are exempt from TSCA Inventory requirements. 313 Reportable ingredients: N/A CERCLA (Comprehensive Response Compensation and Liability Act) Releases of this material to air, land, or water are not reportable to the National Response Center under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) or to state and local emergency planning committees under Superfund Amendments and Reauthorization Act (SARA) Title III Section 304. State Regulations: California (Proposition 65) - No substances known to the State of California to cause cancer, birth defects, or other reproductive harm are found in this product or vapors. Follow all applicable directions for use when handling this product. (California Health and Safety Code Section 25249.6) SARA TITLE III (Superfund Amendments and Reauthorization Act) N/A International Regulations: 311/312 Hazard Categories: N/A Notes: Non-hazardous SECTION 16: Other Information - The information contained herein is believed to be accurate, based on current component MSDS knowledge and experience. It is provided independently of any sale of this product for purpose of hazard communication as part of the product safety program. It is not intended to constitute performance information concerning this product. No responsibility is assumed that the information is sufficient or correct in all cases. No express or implied warranty of merchantability or fitness for particular purpose is made with respect to the product or the information contained herein. This information and product are provided on the condition that the user shall make determination as to the suitability for a particular purpose, and on the condition that the user shall assume all risks of use thereof. Page 781 of 878 Page 781 of 878 Page 781 of 878 Page 781 of 878 ---PAGE BREAK--- Material Safety Data Sheet MSDS No: 1124 Senoret Chemical Company 69 North Locust Street Lititz, PA 17543 Domestic Emergency Phone [PHONE REDACTED] International Emergency Phone 703- 527-3887 Information Phone [PHONE REDACTED] Intl Info Phone: [PHONE REDACTED] Product Number/Size: T2401 Trade Name: Terro® Multi-Purpose Insect Bait Also Known As: Multi-Purpose Bait Description: Dust Insecticide Chemical Composition: Dust Regulatory Licenses: EPA Reg. No. 64405-2-149 Boiling Point: Not Applicable Vapor Pressure (mm Hg): Not Applicable Vapor Density (AIR=1): Not Applicable Bulk Density: Not Applicable Freezing Point: Not Applicable Solubility in Water: Insoluble Appearance: Brown, Granular Particles Odor: None Specific Gravity (Water=1): 0.62 Percent, Volitile by Volume Not Applicable Evaporation Rate (Xylene=1): Not Applicable Physical State: Solid pH: N/A Flash Point (method): Not Determined Flammable Lel: Not Applicable Flammable Uel: Not Applicable Hazardous Products of Combustion: None Known Autoignition Temp.: Not Applicable Extinguishing Material: Water, Foam, CO2, Dry Chemical NFPA Health Rating: 0 NFPA Fire Rating: 0 NFPA Reactivity Rating: 0 General Statement: None of the ingredients of this material meet the definition of "Hazardous Chemical" given in OSHA Hazard communication regulation 29 CFR 1910.1200(c). Occupational Exposure Limit: No Limits Effects of Over Exposure: None Expected under conditions of normal usage. See Page 2 for effects of Overexposure. Carcinogenicity: None listed per OSHA, NTP, IARC Chronic Effects: None Expected Rec. Exp. Limits: No Limits Potential Health Effects: None Expected under normal use conditions Acute Oral: >5000 mg/kg rat Acute Dermal: >2000 mg/kg rat Acute Inhalation: N/A Eye Irritation: Moderate Irritation Skin Irritation: Slight Irritation Sensitization: Not A Sensitizer SECTION I: MATERIAL IDENTIFICATION SECTION II: INGREDIENTS SECTION III: PHYSICAL DATA SECTION IV: FIRE AND EXPLOSION HAZARD DATA SECTION V: HEALTH HAZARD DATA 2 LB Viscosity: Not Applicable Special Fire Fighting Procedures: Wear self-contained breathing apparatus and protective clothing. Non-Hazardous Component CAS # Chemical Formula % BY WT Orthoboric Acid 10043-35-3 N/A 5.0 Tuesday, September 04, 2012 Page 1 of 3 Page 782 of 878 Page 782 of 878 Page 782 of 878 Page 782 of 878 ---PAGE BREAK--- Conditions to avoid: Moisture, Excessive Heat Materials to avoid: Potassium, acetic Hazardous Decomposition: Will Not Occur Conditions to avoid: None Known Hazardous Polymerization: Will Not Occur Conditions to avoid: None Known Steps to be taken if material is released or spilled: Large spills can be swept up. Protect from ignition. Keep out of water sources and sewers. See waste/product disposal, below. Waste Disposal Method: Waste is not hazardous as defined by RCRA (40 CFR 261). Other National, Provincial, and Local regulations may vary. Consult local agencies as needed. Used material which has been contaminated may have significantly different characteristics based on the contaminants and should be evaluated accordingly. Product Disposal Method: Do not refill or reuse container. If empty, dispose of in trash or offer for recycling. If partially filled, call your local solid waste agency for disposal instructions. Respiratory Protection: Dust mask if prolonged concentrated dust exposure expected. Protective Gloves: Not generally required. Eye Protection: Not generally required. Protective Clothing: Not generally required. Ventilation: Use adequate ventilation. Other Protective Equipment: Not generally required. Protection Note: Prolonged and repeated exposure to excessive concentrations of this product's dust, or any nuisance dust, can cause chronic pulmonary disease/irritation. SECTION VI: REACTIVITY DATA Stability: Stable SECTION VII: SPILL OR LEAK PROCEDURES SECTION VIII: SPECIAL PROTECTION INFORMATION Storage and Handling: Avoid skin and eye contact. Avoid breathing dusts. Store in cool, well-ventilated area. Provide means of controlling spills. Protect from ignition. Wash hands after handling. Do not allow product to contaminate water sources, food or feed. Other Precautions: None Precaution Note: None SECTION IX: SPECIAL PRECAUTIONS Ecotoxicity: Generally considered chemically inert in the environment. Use of material which has become contaminated may have significantly different characteristics based on the contaminant and should be evaluated accordingly. Environmental Fate: Persists SECTION X: ECOLOGICAL INFORMATION Route of Entry of Overexposure First Aid Irritation from prolonged exposure Immediately wash skin with plenty of water for 15 minutes. Remove contaminated clothing and launder before reuse. Skin May irritate mucous membranes of upper respiratory tract. If inhaled, remove to fresh air immediately. If not breathing, call an ambulance and give artificial respiration. If breathing is difficult, administer oxygen. Inhalation May cause eye irritation Flush with large amounts of water for 15 minutes lifting eyelids occassionally. Remove contact lenses after the first 5 minutes then continue rinsing eye. Get medical attention if irritation persists. Eye Can cause nausea, vomiting, diarrhea. If ingested, immedately consume 2 glasses of water and induce vomiting by drinking Ipecac syrup or by placing finger in back of throat. Never give anything by mouth to an unconscious person. Seek medical attention immediately. Ingestion Tuesday, September 04, 2012 Page 2 of 3 Page 783 of 878 Page 783 of 878 Page 783 of 878 Page 783 of 878 ---PAGE BREAK--- SECTION XI: TRANSPORTATION INFORMATION DOT HAZARD DESCRIPTION Packaging Group: None Packaging Instructions: Not regulated Special Instructions: Not regulated Placard: Not required. Emergency Response Guide#: N/A US Surface Freight Class: Not regulated DOT Hazard Class/Division: None DOT Proper Shipping Name: Not regulated Identification Number: None IATA Bulk Packaging Inst: Not regulated IATA Shipping Notes: Not regulated IMO Bulk Packaging Inst: Not regulated SARA Product Classification: Not classified. Acute: N/A Chronic: N/A Fire: N/A Reactivity: N/A Pressure Generating: N/A 311/312 Hazard Categories: N/A 313 Reportable Ingredients: Not subject to reporting. TSCA Regulatory: Not regulated. State Regulations: Senoret Chemical Company is unaware of any local, state or federal regulations, which define the active ingredients as hazardous. As of the preparation date, this product did not contain a chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Proposition 65 Statement: None Listed Memo: While this information and recommendations set forth are believed to be accurate as of the date hereof, Senoret Chemical Company makes no warranty with respect hereto and disclaims all liability from reliance thereon. SARA Title III: Not Regulated IATA CLASSIFICATION IATA Identification Number: Packaging Group: None IMO CLASSIFICATION IMO Identification Number: Packaging Group: None SECTION XII: REGULATORY INFORMATION SECTION XIII: OTHER INFORMATION IMO Shipping Notes: Not regulated IMO Stowage Category: Not regulated IATA Hazard Class/Division: Not regulated IMO Hazard Class/Division: Not regulated IATA Proper Shipping Name: Not regulated IMO Proper Shipping Name: Not regulated European Classification: Date MSDS Prepared: 9/4/2012 Supercedes Date: Contact: Mark Mongiovi Title: Regulatory Affairs Tuesday, September 04, 2012 Page 3 of 3 Page 784 of 878 Page 784 of 878 Page 784 of 878 Page 784 of 878 ---PAGE BREAK--- MSDS No: 023030 Issue Date: 8 Jan 2010 Page: 1 of 5 MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION Trade Name: TFE Paste Part Numbers Covered: See Section 16. Product Use: Pure white thread lubricant and sealant for plastic or metal threads in heavy duty applications. Formula: See Section 3. Synonyms: Pipe thread compound. Firm Name & William H. Harvey Company Mailing Address: 4334 South 67th Street Omaha, NE 68117-1019 http://www.wmharvey.com Emergency Phone For chemical transportation emergencies ONLY, call CHEMTREC at Numbers: (800)424-9300. Outside the U.S. (703)527-3887. Information Telephone Number: (800)228-9681 Prepared By: Technical Dept. Contact: Information telephone number – (800) 228-9681 Preparation Date: January 8, 2010 SECTION 2 HAZARDS IDENTIFICATION Emergency Overview: Thick, white paste with a petroleum odor. May cause mild irritation to the eye and skin. Inhalation of vapors may cause respiratory tract irritation, and possible dizziness. Long term inhalation of dust may cause silicosis or cancer. Potential Health Effects: Skin: Irritation, including redness and dryness. Eyes: May cause mechanical irritation, redness, tearing, and blurred vision. Inhalation: Vapors may cause irritation to mucous membranes and the respiratory system. Headache, dizziness. Long term inhalation of dust may cause silicosis or cancer. Ingestion: May cause irritation to the mouth and throat. OSHA Hazard Classification: Irritant, target organ effects SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENTS: % wt/wt: CAS NUMBER: Calcium Carbonate 50 – 70% 1317-65-3 Oxidized Soy Bean Oil 10 – 30% 68152-81-8 Polytetrafluoroethylene 3 – 7% 9002-84-0 2-Butoxyethanol 3 – 7% 111-76-2 Titanium Dioxide 1 – 5% 13463-67-7 Ethoxylated 1 – 5% 9016-45-9 Alkyl Quaternary Ammonium Bentonite 1 – 5% 68953-58-2 Silica, quartz < 1.2% 14808-60-7 Page 785 of 878 Page 785 of 878 Page 785 of 878 Page 785 of 878 ---PAGE BREAK--- MSDS No: 023030 Issue Date: 8 Jan 2010 Page: 2 of 5 SECTION 4 FIRST AID MEASURES CALL TOLL FREE 1-[PHONE REDACTED] Skin: Remove contaminated clothing. Wash thoroughly with soap and water. Call a physician or poison control center if irritation develops. Eyes: Remove contact lenses if any. Rinse eyes with water for 15 minutes. Get medical attention if irritation develops. Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Keep victim quiet and warm. Call a poison control center or physician if persist. Ingestion: NEVER give anything by mouth if victim is unconscious. Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Call the Poison Control Center at 1-[PHONE REDACTED]. SECTION 5 FIRE FIGHTING MEASURES Extinguishing Media: Use dry chemical, CO2, water, or foam extinguisher. Special Fire Fighting Procedures: Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing for fires in areas where chemicals are used or stored. Unusual Fire and Explosion Hazards: None known. SECTION 6 ACCIDENTAL RELEASE MEASURES Spill or Leak Procedures: Pick up released product with appropriate implements and return to original container if reusable. If not reusable, place in appropriate containers for disposal. Appropriate personal protective equipment cited in Section 8 should be worn during all clean-up operations. SECTION 7 HANDLING AND STORAGE Handling: Avoid contact with eyes, skin, or clothing. Do not take internally. Avoid breathing vapors or fumes. Use only with adequate ventilation. Wash thoroughly after handling. Keep container closed when not in use. Handle with care. Keep out of reach of children. Storage: Store in original, labeled container. Other: Containers, even empty, will retain residue and may be harmful. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION INGREDIENTS: CAS NUMBER: ACGIH TLV TWA OSHA PEL TWA Calcium carbonate 1317-65-3 10 mg/m3 silica) 15 mg/m3 (total dust) 5 mg/m3 (respirable) 2-butoxyethanol 111-76-2 20 ppm 50 ppm Titanium dioxide 13463-67-7 10 mg/m3 15 mg/m3 (total dust) silica 14808-60-7 0.025 mg/m3 10 mg/m3 / %SiO2 Ventilation: Good general ventilation (equivalent to outdoors) should be adequate for normal use. For operations where the TLV may be exceeded, mechanical ventilation such as local exhaust may be needed to maintain exposure levels below applicable limits. Respiratory Protection: For operations where the TLV may be exceeded, a NIOSH approved particulate / organic vapor respirator or supplied air respirator is recommended. Equipment selection depends on contaminant type and concentration, select in accordance with 29 CFR 1910.134 and good industrial hygiene practice. For firefighting, use self- contained breathing apparatus. Skin Protection: Normally not needed. Launder soiled clothing before re-use. Eye Protection: Safety glasses with sideshields or safety goggles. Other: Eye wash and safety shower should be available. Page 786 of 878 Page 786 of 878 Page 786 of 878 Page 786 of 878 ---PAGE BREAK--- MSDS No: 023030 Issue Date: 8 Jan 2010 Page: 3 of 5 SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Flashpoint / Method: > 145 Degrees F (62 Degrees (Estimated) Flammability: LEL = Not determined, UEL = Not determined. Boiling Point: Not determined. Melting Point: Not determined. Vapor Pressure: Not determined. Vapor Density: (Air = 1) Greater than 1. Volatile Components: Not determined. Solubility In Water: Negligible. pH: Not applicable. Specific Gravity: 1.74 @ 20 Degrees C. Evaporation Rate: Not applicable. Appearance: Thick white paste. Odor: Petroleum odor. Will Dissolve In: Not determined. Material Is: Paste. SECTION 10 STABILITY AND REACTIVITY Stability: Stable. Conditions To Avoid: None. Hazardous Decomposition Products: Hydrocarbons, aldehydes, smoke, carbon monoxide, carbon dioxide. Oxides of nitrogen, titanium, calcium. Small amounts of hydrogen fluoride may evolve at very high temperatures. Incompatibility/ Materials To Avoid: Strong oxidizing agents, strong acids. Hazardous Polymerization: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Inhalation: Vapors may cause headache, dizziness, and irritation to mucous membranes. Dust may contain silica. Long term inhalation may cause silicosis or cancer. Above 300 degrees C, product may liberate fine particulate fume, which if inhaled, can produce polymer fume fever, a temporary flu-like condition. Skin: Contact may cause mild irritation. Eye: Vapors or fumes may cause redness and irritation. Ingestion: May cause irritation. Toxicity Data: 2-Butoxyethanol: Calcium Carbonate: ethoxylate: Oral LD50 (rat): 1,746 mg/kg. Dermal LD50 (rabbit): 435 mg/kg. Inhalation LC50 (mouse): 7h: 700ppm. Oral LD50 (rat): 6,450 mg/kg. Oral LD50 (rat): 3,310 mg/kg. Sensitization: None of the components are known to cause sensitization. Carcinogenicity: silica is listed by IARC as a Group 1 carcinogen (carcinogenic to humans). ACGIH lists silica as a suspect human carcinogen (A2). Titanium dioxide is listed by IARC as a Group 2B carcinogen (possibly carcinogenic to humans) and ACGIH lists titanium dioxide as A4 (not classifiable as a human carcinogen). Mutagenicity: None of the components have been found to be mutagenic. Reproductive Toxicity: None of the components are known to cause adverse reproductive effects. Medical Conditions Aggravated By Exposure: Persons with pre-existing skin or lung disorders may be at increased risk from exposure to this product. Page 787 of 878 Page 787 of 878 Page 787 of 878 Page 787 of 878 ---PAGE BREAK--- MSDS No: 023030 Issue Date: 8 Jan 2010 Page: 4 of 5 SECTION 12 ECOLOGICAL INFORMATION Acute Aquatic Effects Data: 2-Butoxyethanol: 24 h LC50 (goldfish): 1,650 - 1700 mg/l. 96 h LC50 (fathead minnow): 2137 mg/l. 24 h LC50 (daphnia): 1,850 mg/l. 48 h LC50 (daphnia): 835 mg/l. VOC Information: This product emits VOC’s (Volatile Organic Compounds) in its use. Make sure that use of this product complies with local VOC emission regulations, where they exist. VOC Content: 87 grams/liter Per Method 94515(b) of Title 17 of the California Code of Regulations. SECTION 13 DISPOSAL CONSIDERATIONS Waste Disposal: Dispose of in accordance with federal, state, and local regulations. It is the responsibility of the end-user to determine at the time of disposal of the product. EPA Hazardous Waste Number: None. EPA Hazard Waste Class: None. SECTION 14 TRANSPORT INFORMATION DOT Proper Shipping Name: Not regulated in quantities less than 119 gallons. Hazard Class/Packing Group: None. UN/NA Number: None. Hazard Labels: None. IMDG Proper Shipping Name: Not regulated. Hazard Class/Packing Group: None. UN/NA Number: None. Hazard Labels: None. SECTION 15 REGULATORY INFORMATION Hazard Category for Section 311/312: Acute Health, Chronic Health, Fire Section 302 Extremely Hazardous Substances (TPQ): This product does not contain chemicals regulated under SARA Title III, Section 302. Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313 Reporting requirements: Chemical CAS # % by wt. 2-Butoxyethanol 111-76-2 3 – 7% CERCLA 103 Reportable Quantity: Spills of this product over the RQ (reportable quantity) must be reported to the National Response Center. The RQ for the product, based on the RQ for 2-butoxyethanol (10% max) of 1 lb, is 10 lbs. Chemical CAS # RQ, lbs. 2-Butoxyethanol 111-76-2 * * A statutory RQ of one pound was assigned. No final RQ has been assigned to the broad class of glycol ethers. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. California Proposition 65: This product may contain a small quantity of silica and tetrafluoroethylene, which are known to the State of California to cause cancer. TSCA Inventory: All of the components of this product are listed on the TSCA inventory. Page 788 of 878 Page 788 of 878 Page 788 of 878 Page 788 of 878 ---PAGE BREAK--- MSDS No: 023030 Issue Date: 8 Jan 2010 Page: 5 of 5 SECTION 15 (continued) Canadian WHMIS Classification: Class D, Division 2, Subdivision B; B3; D1A; D2A. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. SECTION 16 OTHER INFORMATION NFPA and HMIS: NFPA Hazard Signal Health: 2 Flammability: 2 Reactivity: 0 Special: None HMIS Hazard Signal: Health: 2* Flammability: 2 Reactivity: 0 PPE: A Part Nos. Covered by this MSDS: 023001 023036 023053 023077 023257 023005 023037 023054 023090 023259 023008 023038 023055 023105 023260 023012 023040 023056 023150 023270 023013 023041 023057 023200 090 2050 023014 023042 023058 023201 090 2055 023015 023043 023059 023202 4047429 023028 023044 023060 023203 45281 023029 023045 023061 023204 45282 023030 023046 023065 023210 B13185 023031 023047 023066 023250 B13202 023032 023048 023067 023251 Premier 441007 023033 023050 023071 023253 Premier 441011 023034 023051 023074 023255 Premier 441013 023035 023052 023075 023256 PV023253 Disclaimer: The information in this MSDS was obtained from sources we believe to be reliable. However, the information is provided by the William H. Harvey Company without any warranty, express or implied, regarding its correctness. Some information presented and conclusions drawn herein are from sources other than direct test data on the substance itself. The MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. Users should make their own investigations to determine the suitability of the information or products for their particular purpose. The conditions or methods of handling, storage, use, and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, the William H. Harvey Company does not assume responsibility and expressly disclaims liability for loss, damage or expense arising out of or in any way connected with handling, storage, use or disposal of the product. Page 789 of 878 Page 789 of 878 Page 789 of 878 Page 789 of 878 ---PAGE BREAK--- MSDS No: 023030 Issue Date: 8 Jan 2010 Page: 1 of 5 MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION Trade Name: TFE Paste Part Numbers Covered: See Section 16. Product Use: Pure white thread lubricant and sealant for plastic or metal threads in heavy duty applications. Formula: See Section 3. Synonyms: Pipe thread compound. Firm Name & William H. Harvey Company Mailing Address: 4334 South 67th Street Omaha, NE 68117-1019 http://www.wmharvey.com Emergency Phone For chemical transportation emergencies ONLY, call CHEMTREC at Numbers: (800)424-9300. Outside the U.S. (703)527-3887. Information Telephone Number: (800)228-9681 Prepared By: Technical Dept. Contact: Information telephone number – (800) 228-9681 Preparation Date: January 8, 2010 SECTION 2 HAZARDS IDENTIFICATION Emergency Overview: Thick, white paste with a petroleum odor. May cause mild irritation to the eye and skin. Inhalation of vapors may cause respiratory tract irritation, and possible dizziness. Long term inhalation of dust may cause silicosis or cancer. Potential Health Effects: Skin: Irritation, including redness and dryness. Eyes: May cause mechanical irritation, redness, tearing, and blurred vision. Inhalation: Vapors may cause irritation to mucous membranes and the respiratory system. Headache, dizziness. Long term inhalation of dust may cause silicosis or cancer. Ingestion: May cause irritation to the mouth and throat. OSHA Hazard Classification: Irritant, target organ effects SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENTS: % wt/wt: CAS NUMBER: Calcium Carbonate 50 – 70% 1317-65-3 Oxidized Soy Bean Oil 10 – 30% 68152-81-8 Polytetrafluoroethylene 3 – 7% 9002-84-0 2-Butoxyethanol 3 – 7% 111-76-2 Titanium Dioxide 1 – 5% 13463-67-7 Ethoxylated 1 – 5% 9016-45-9 Alkyl Quaternary Ammonium Bentonite 1 – 5% 68953-58-2 Silica, quartz < 1.2% 14808-60-7 Page 790 of 878 Page 790 of 878 Page 790 of 878 Page 790 of 878 ---PAGE BREAK--- MSDS No: 023030 Issue Date: 8 Jan 2010 Page: 2 of 5 SECTION 4 FIRST AID MEASURES CALL TOLL FREE 1-[PHONE REDACTED] Skin: Remove contaminated clothing. Wash thoroughly with soap and water. Call a physician or poison control center if irritation develops. Eyes: Remove contact lenses if any. Rinse eyes with water for 15 minutes. Get medical attention if irritation develops. Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Keep victim quiet and warm. Call a poison control center or physician if persist. Ingestion: NEVER give anything by mouth if victim is unconscious. Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Call the Poison Control Center at 1-[PHONE REDACTED]. SECTION 5 FIRE FIGHTING MEASURES Extinguishing Media: Use dry chemical, CO2, water, or foam extinguisher. Special Fire Fighting Procedures: Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing for fires in areas where chemicals are used or stored. Unusual Fire and Explosion Hazards: None known. SECTION 6 ACCIDENTAL RELEASE MEASURES Spill or Leak Procedures: Pick up released product with appropriate implements and return to original container if reusable. If not reusable, place in appropriate containers for disposal. Appropriate personal protective equipment cited in Section 8 should be worn during all clean-up operations. SECTION 7 HANDLING AND STORAGE Handling: Avoid contact with eyes, skin, or clothing. Do not take internally. Avoid breathing vapors or fumes. Use only with adequate ventilation. Wash thoroughly after handling. Keep container closed when not in use. Handle with care. Keep out of reach of children. Storage: Store in original, labeled container. Other: Containers, even empty, will retain residue and may be harmful. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION INGREDIENTS: CAS NUMBER: ACGIH TLV TWA OSHA PEL TWA Calcium carbonate 1317-65-3 10 mg/m3 silica) 15 mg/m3 (total dust) 5 mg/m3 (respirable) 2-butoxyethanol 111-76-2 20 ppm 50 ppm Titanium dioxide 13463-67-7 10 mg/m3 15 mg/m3 (total dust) silica 14808-60-7 0.025 mg/m3 10 mg/m3 / %SiO2 Ventilation: Good general ventilation (equivalent to outdoors) should be adequate for normal use. For operations where the TLV may be exceeded, mechanical ventilation such as local exhaust may be needed to maintain exposure levels below applicable limits. Respiratory Protection: For operations where the TLV may be exceeded, a NIOSH approved particulate / organic vapor respirator or supplied air respirator is recommended. Equipment selection depends on contaminant type and concentration, select in accordance with 29 CFR 1910.134 and good industrial hygiene practice. For firefighting, use self- contained breathing apparatus. Skin Protection: Normally not needed. Launder soiled clothing before re-use. Eye Protection: Safety glasses with sideshields or safety goggles. Other: Eye wash and safety shower should be available. Page 791 of 878 Page 791 of 878 Page 791 of 878 Page 791 of 878 ---PAGE BREAK--- MSDS No: 023030 Issue Date: 8 Jan 2010 Page: 3 of 5 SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Flashpoint / Method: > 145 Degrees F (62 Degrees (Estimated) Flammability: LEL = Not determined, UEL = Not determined. Boiling Point: Not determined. Melting Point: Not determined. Vapor Pressure: Not determined. Vapor Density: (Air = 1) Greater than 1. Volatile Components: Not determined. Solubility In Water: Negligible. pH: Not applicable. Specific Gravity: 1.74 @ 20 Degrees C. Evaporation Rate: Not applicable. Appearance: Thick white paste. Odor: Petroleum odor. Will Dissolve In: Not determined. Material Is: Paste. SECTION 10 STABILITY AND REACTIVITY Stability: Stable. Conditions To Avoid: None. Hazardous Decomposition Products: Hydrocarbons, aldehydes, smoke, carbon monoxide, carbon dioxide. Oxides of nitrogen, titanium, calcium. Small amounts of hydrogen fluoride may evolve at very high temperatures. Incompatibility/ Materials To Avoid: Strong oxidizing agents, strong acids. Hazardous Polymerization: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Inhalation: Vapors may cause headache, dizziness, and irritation to mucous membranes. Dust may contain silica. Long term inhalation may cause silicosis or cancer. Above 300 degrees C, product may liberate fine particulate fume, which if inhaled, can produce polymer fume fever, a temporary flu-like condition. Skin: Contact may cause mild irritation. Eye: Vapors or fumes may cause redness and irritation. Ingestion: May cause irritation. Toxicity Data: 2-Butoxyethanol: Calcium Carbonate: ethoxylate: Oral LD50 (rat): 1,746 mg/kg. Dermal LD50 (rabbit): 435 mg/kg. Inhalation LC50 (mouse): 7h: 700ppm. Oral LD50 (rat): 6,450 mg/kg. Oral LD50 (rat): 3,310 mg/kg. Sensitization: None of the components are known to cause sensitization. Carcinogenicity: silica is listed by IARC as a Group 1 carcinogen (carcinogenic to humans). ACGIH lists silica as a suspect human carcinogen (A2). Titanium dioxide is listed by IARC as a Group 2B carcinogen (possibly carcinogenic to humans) and ACGIH lists titanium dioxide as A4 (not classifiable as a human carcinogen). Mutagenicity: None of the components have been found to be mutagenic. Reproductive Toxicity: None of the components are known to cause adverse reproductive effects. Medical Conditions Aggravated By Exposure: Persons with pre-existing skin or lung disorders may be at increased risk from exposure to this product. Page 792 of 878 Page 792 of 878 Page 792 of 878 Page 792 of 878 ---PAGE BREAK--- MSDS No: 023030 Issue Date: 8 Jan 2010 Page: 4 of 5 SECTION 12 ECOLOGICAL INFORMATION Acute Aquatic Effects Data: 2-Butoxyethanol: 24 h LC50 (goldfish): 1,650 - 1700 mg/l. 96 h LC50 (fathead minnow): 2137 mg/l. 24 h LC50 (daphnia): 1,850 mg/l. 48 h LC50 (daphnia): 835 mg/l. VOC Information: This product emits VOC’s (Volatile Organic Compounds) in its use. Make sure that use of this product complies with local VOC emission regulations, where they exist. VOC Content: 87 grams/liter Per Method 94515(b) of Title 17 of the California Code of Regulations. SECTION 13 DISPOSAL CONSIDERATIONS Waste Disposal: Dispose of in accordance with federal, state, and local regulations. It is the responsibility of the end-user to determine at the time of disposal of the product. EPA Hazardous Waste Number: None. EPA Hazard Waste Class: None. SECTION 14 TRANSPORT INFORMATION DOT Proper Shipping Name: Not regulated in quantities less than 119 gallons. Hazard Class/Packing Group: None. UN/NA Number: None. Hazard Labels: None. IMDG Proper Shipping Name: Not regulated. Hazard Class/Packing Group: None. UN/NA Number: None. Hazard Labels: None. SECTION 15 REGULATORY INFORMATION Hazard Category for Section 311/312: Acute Health, Chronic Health, Fire Section 302 Extremely Hazardous Substances (TPQ): This product does not contain chemicals regulated under SARA Title III, Section 302. Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313 Reporting requirements: Chemical CAS # % by wt. 2-Butoxyethanol 111-76-2 3 – 7% CERCLA 103 Reportable Quantity: Spills of this product over the RQ (reportable quantity) must be reported to the National Response Center. The RQ for the product, based on the RQ for 2-butoxyethanol (10% max) of 1 lb, is 10 lbs. Chemical CAS # RQ, lbs. 2-Butoxyethanol 111-76-2 * * A statutory RQ of one pound was assigned. No final RQ has been assigned to the broad class of glycol ethers. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. California Proposition 65: This product may contain a small quantity of silica and tetrafluoroethylene, which are known to the State of California to cause cancer. TSCA Inventory: All of the components of this product are listed on the TSCA inventory. Page 793 of 878 Page 793 of 878 Page 793 of 878 Page 793 of 878 ---PAGE BREAK--- MSDS No: 023030 Issue Date: 8 Jan 2010 Page: 5 of 5 SECTION 15 (continued) Canadian WHMIS Classification: Class D, Division 2, Subdivision B; B3; D1A; D2A. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. SECTION 16 OTHER INFORMATION NFPA and HMIS: NFPA Hazard Signal Health: 2 Flammability: 2 Reactivity: 0 Special: None HMIS Hazard Signal: Health: 2* Flammability: 2 Reactivity: 0 PPE: A Part Nos. Covered by this MSDS: 023001 023036 023053 023077 023257 023005 023037 023054 023090 023259 023008 023038 023055 023105 023260 023012 023040 023056 023150 023270 023013 023041 023057 023200 090 2050 023014 023042 023058 023201 090 2055 023015 023043 023059 023202 4047429 023028 023044 023060 023203 45281 023029 023045 023061 023204 45282 023030 023046 023065 023210 B13185 023031 023047 023066 023250 B13202 023032 023048 023067 023251 Premier 441007 023033 023050 023071 023253 Premier 441011 023034 023051 023074 023255 Premier 441013 023035 023052 023075 023256 PV023253 Disclaimer: The information in this MSDS was obtained from sources we believe to be reliable. However, the information is provided by the William H. Harvey Company without any warranty, express or implied, regarding its correctness. Some information presented and conclusions drawn herein are from sources other than direct test data on the substance itself. The MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. Users should make their own investigations to determine the suitability of the information or products for their particular purpose. The conditions or methods of handling, storage, use, and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, the William H. Harvey Company does not assume responsibility and expressly disclaims liability for loss, damage or expense arising out of or in any way connected with handling, storage, use or disposal of the product. Page 794 of 878 Page 794 of 878 Page 794 of 878 Page 794 of 878 ---PAGE BREAK--- BALMAR, LLC MATERIAL SAFETY DATA SHEET Eye: Possible irritation with repeated or prolonged contact. Eye: Immediately flush eyes with plenty of water for at least 15 minutes while holding eyelids open. Get immediate medical attention. Appearance: Brown Liquid Manufacturer/Supplier BALMAR, L.L.C. LAFAYETTE, LA 70507-4002 Phone: (337) 232-2496 CHEMTREC 1-[PHONE REDACTED] Emergency Phone: Product: 108 Chemical Family:Thread Preservative Thread Guard Use: Rust Preventative for Threads PRODUCT IDENTIFICATION INGREDIENT COMPONENTS CAS# Weight % OSHA LIMIT (PEL) ACGIH (TLV) *Mineral Spirits 64742-88-7 35-45 500ppm 100ppm TWA Skin Possible irritation with repeated or prolonged contact. Inhalation: Exposure to mist or spray may cause coughing, sneezing, and upper respiratory tract irritation. Ingestion: Possible irritation, nausea, or diarrhea if ingested. Aspiration hazard. HEALTH EFFECTS FIRST AID Skin: Wash with soap and water thoroughly after handling. Ingestion: Do NOT induce vomiting. If conscious, drink large quantities of water. Get medical attention immediately. Inhalation: Remove to fresh air. Apply artificial respiration or administer oxygen as necessary. If conscious, irrigate nasal passages with water. Get medical attention. FIRE PROTECTION INFORMATION Extinquishing Method Carbon Dioxide, dry chemical, foam, or water fog. Hazardous Decomposition Incomplete combustion can yield carbon monoxide and various hydrocarbons. Fire and Explosion Method No known explosion hazards. May produce toxic fumes at temperatures above 930°F. Personal Protection Eye: Safety glasses to protect from unexpected splashes. Skin For prolonged or repeated contact, use nitrile or neoprene gloves. Ventilation: Local exhaust must be sufficient to keep airborne concentrations below the TLV limit. Spcl Protect Not required under normal conditions of use. HANDLING AND STORAGE Storage: Do not store with strong oxidizers. Avoid exposure to extreme temperatures. Shipping Information: Domestic (bulk only): NA1993, COMBUSTIBLE LIQUID, N.O.S. (CONTAINS PETROLEUM DISTILLATES), III PersonalPrecautions Spills: Pick up and place in container for disposal. Waste Disposal: Utilize permitted industrial waste disposal site. Comply with environmental regulations. Burning is NOT recommended. PHYSICAL AND CHEMICAL PROPERTIES Odor Mild Solvent Boiling Point: Not Available Vapor Pressure: Not Available Evaporation Point: Not Available Percent Volatile: 35-45 Vapor Density >1 Specific Gravity: 0.90 Solubility in water: <1 Flash Point 145°F Auto Ignition Not Available Flammable Limits: Estimated Value Title III Ingredient: Not Applicable Title III, Sec. 313 Status Title III Percentage: Title III CAS#: Reported as potential carcinogen or carcinogen: Not Applicable OSHA International Agency For Research On Cancer National Toxicology Program American Conference of Governmental Industrial Hygienists HAZARDOUS POLYMERIZATION: Will Not Occur May Occur X Stability: Stable Unstable X Auto Ignition Temperature Not Available Flammable Limits % vol in air Estimated Value Lower% 1.0 Upper% 6.0 RESPIRATORY PROTECTION (UTILIZE NIOSH-APPROVED RESPIRATORS. REFER TO MFG PROTECTION FACTORS AND OSHA STANDARD 1910.134 AS A GUIDELINE)Not required under normal conditions of use. DISCLAIMER: The information contained herein is based upon data available to us and reflects our best professional judgment. Since it is impossible to anticipate the conditions under which our products may be used, we cannot guarantee that the recommendations will be adequate for all individuals and situations. Each user of this product should determine the suitability of the product for his particular purpose and should comply with all environmental regulations. Our goal is to manufacture products with zero or minimum hazards. Our products are improved daily as up-to-date information and research data is received from our suppliers in our quest to use products with less or no hazards. Please feel free to contact us for current information. Hazardous components indicated with asterick * Hazardous components in a dust form only** Address: 616 W. PONT DES MOUTON RD Fax: (337) 234-5825 NFPA SYMBOL Toxicity 2 Fire 2 Reactivity 0 HMIS SYMBOL Health Flammability Reactivity PPI B 0 2 2 ADDITIONAL COMMENTS: Containers should be either reconditioned by CERTIFIED firms or properly disposed of by APPROVED firms. Disposal of containers should be in accordance with applicable laws and regulations. EMPTY drums should not be given to individuals. Serious accidents have resulted from the misuse of EMPTIED containers (drums, pails, etc.). Refer to Section IV and IX. Last Updated 6/28/2007 NA Page 795 of 878 Page 795 of 878 Page 795 of 878 Page 795 of 878 ---PAGE BREAK--- Page 796 of 878 Page 796 of 878 Page 796 of 878 Page 796 of 878 ---PAGE BREAK--- Spartan Chemical Company, Inc. Material Safety Data Sheet SECTION I: PRODUCT INFORMATION Product Name or Number (as it appears on label): Product Division: TNT FOAMING DISINFECTANT CLEANER Product Number: 6343 Janitorial Spartan Chemical Company, Inc. Product/Technical Information: 1-(800)-537-8990 1110 Spartan Drive Medical Emergency: 1-(888)-314-6171 (24 hours) Maumee OH 43537 Chemical Leak/Spil Emergency: CHEMTREC 1-(800) 424-9300 (24 hours) Shipping Description: ORM-D, Consumer commodity, cleaning compounds, aerosol, n.o.s. NFPA Ratings: HMIS Ratings: Health: 1- Slight Health: *1 - Slight; Chronic Hazard Fire: 0 - Minimal Fire: 0 - Minimal Reactivity: 0 - Minimal Reactivity: 0 - Minimal Pers. Prot. Equip.: See Section VIII SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1% or greater, carcinogens at 0.1% or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. Table Z-1-A Chemical Name(s) %Wt CAS Registry No. TWA mg/m 3 STEL mg/m 3 CEILING mg/m 3 NTP, IARC or OSHA Carcinogen Isobutane *2-Butoxyethanol Tetrapotassium pyrophosphate Alkyl dimethyl benzyl ammonium chloride Alkyl dimethyl ethyl benzyl ammonium chloride 1-5 1-5 1-5 < 1.0 - < 1.0 - 75-28-5 111-76-2 7320-34-5 68391-01-5 - 68956-79-6 - 1900 (NIOSH) 240 [skin] 96 Not Established Not Established - Not Established - Not Established Not Established Not Established Not Established - Not Established - Not Established Not Established Not Established Not Established - Not Established - No No No No - No - Comment: *This substance is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (SARA) and of 40 CFR 372. SECTION III: PHYSICAL DATA Boiling Point: (Concentrate) 210 °F Vapor Pressure: Unknown Vapor Density (AIR = Unknown Solubility in Water: Complete pH: 10.5-11.0 Specific Gravity (H2O=1): 1.01 Evaporation Rate (but.ace.=1): <1 Percent Solid by Weight: 1-2 Physical State: Pressurized liquid (Aerosol can) Appearance & Odor: Foam spray, mint fragrance SECTION IV: FIRE & EXPLOSIVE HAZARD DATA Flash Point: Propellant: < 0°F Method Used: Estimate Flammable Limits: Not Established Flame Extension: 0 Inches NFPA 30B Level 1 Aerosol Extinguishing Media: Carbon dioxide, dry chemical, water fog, foam. Special Fire Fighting Procedures: Water may be used to cool closed containers to prevent pressure build-up and possible rupture when exposed to heat. Wear a full face positive pressure self contained breathing apparatus when fighting fires. Unusual Fire & Explosive Hazards: Product vapor may travel along the ground or pool in low areas and be ignited by pilot lights, other flames, sparks, heaters, smoking, electrical motors, static electricity or other ignition sources. Page 797 of 878 Page 797 of 878 Page 797 of 878 Page 797 of 878 ---PAGE BREAK--- SECTION V: HEALTH HAZARD DATA Threshold Limit Value: Not Established Primary Routes of Entry: Inhalation, Skin Contact, Eyes and Ingestion Effects of Overexposure- Conditions to Avoid: Causes moderate eye irritation. Harmful if absorbed through the skin. May be harmful if swallowed. Inhalation may cause respiratory irritation. Contains 2-butoxyethanol which may cause central nervous system depression with such as headache; dizziness; nausea and drowsiness. Exposure to 2-butoxyethanol may cause blood cell; liver and kidney damage based on animal data. Avoid contact with eyes, skin or clothing. Do not swallow. Avoid breathing product mist. Wash thoroughly with soap and water after handling. Conditions Aggravated by Use: Use of this product may aggravate preexisting skin; eye and respiratory disorders including asthma and dermatitis. Emergency & First Aid Procedures: Eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses; If present after the first 5 minutes; then continue rinsing eye. Call a poison control center or doctor for treatment advice. Skin: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Get medical attention if irritation persists. Ingestion: Do not induce vomiting. Drink one or two glasses of water to dilute product. Get medical attention. Do not give anything by mouth to an unconscious person. Inhalation: In case of respiratory irritation; move person to fresh air. Get medical attention if irritation persists. SECTION VI: REACTIVITY DATA Stability: Stable Incompatible Materials: Strong oxidizers Hazardous Decomposition Products: None Hazardous Polymerization: Will Not Occur SECTION VII: SPILL OR LEAK PROCEDURES Steps to be Taken in Case Material is Released or Spilled: Flush with water to sanitary sewer. Keep spill out of storm sewers and waterways. Waste Disposal Method: Do not puncture or incinerate aerosol containers. Dispose of in accordance with federal, state and local regulations. SECTION VIII: SPECIAL PROTECTION INFORMATION Respiratory Protection: Not normally required when good general ventilation is provided. Ventilation: Provide good general ventilation. Local exhaust ventilation may be necessary for some operations. Protective Gloves(Specify Type): Rubber gloves are recommended. Eye Protection(Specify Type): Splash goggles or safety glasses are recommended. Other Protective Equipment: See 29 CFR 1910.132-138 SECTION IX: SPECIAL PRECAUTIONS Precautions; Handling & Storing: Contents under pressure. Do not use near fire, sparks or flame. Do not store where temperatures could exceed 120 F. Do not puncture or incinerate container. Other Precautions: Keep out of reach of children. © SCC 06/01/2007 Name: Ronald T. Cook Title: Manager, Regulatory Affairs TNT FOAMING DISINFECTANT CLEANER Effective Date: 06/01/2007 Supercedes: 06/30/2005 Ref: 29 CFR 1910.1200 (OSHA) Changes: Update Section II This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. Page 798 of 878 Page 798 of 878 Page 798 of 878 Page 798 of 878 ---PAGE BREAK--- Trade Name: Tomcat Bait Stations Date Created: 09 April 2008 Supplier: Motomco Ltd. Page 1 of 2 TOMCAT BAIT STATIONS SAFETY DATA SHEET ACCORDING TO EEC DIRECTIVE: 1907/2006 DATE OF ISSUE: 09 April 2008 PREPARED BY: TH 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY PRODUCT NAME: TOMCAT BAIT STATIONS USE: Rodent Control Bait Delivery Device FORM: Injection Molded Plastic MANUFACTURER/IMPORTER: Motomco Ltd. 3699 Kinsman Blvd. Madison, WI 53704, USA email: [EMAIL REDACTED] EMERGENCY PHONE NO.: 1-[PHONE REDACTED] (United States/Canada) +1-[PHONE REDACTED] (Outside United States/Canada) or Local or Regional Poison Control Center 2. HAZARD IDENTIFICATION PRIMARY ROUTES OF ENTRY: None 3. COMPOSITION/INFORMATION ON INGREDIENTS COMPOSITION: No Toxic Ingredients % BY WEIGHT: N/A CAS NO.: N/A EEC NO.: N/A 4. FIRST AID MEASURES EYE CONTACT: None SKIN CONTACT: None INHALATION: None INGESTION: None None ADVICE TO PHYSICIAN: N/A 5. FIRE-FIGHTING MEASURES EXTIGUISHING MEDIA: Extinguish with water, foam or inert gas. MEASURES UNSUITABLE FOR SAFETY REASONS: None PROTECTIVE EQUIPMENT: Firefighters should be equipped with protective clothing and self-contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES PERSONAL PROTECTION: Not required ENVIRONMENTAL PROTECTION: N/A CLEAN UP AND DISPOSAL: Dispose of in accordance with all local, regional and national regulations. 7. HANDLING AND STORAGE HANDLING: No special requirements. STORAGE: No special requirements Page 799 of 878 Page 799 of 878 Page 799 of 878 Page 799 of 878 ---PAGE BREAK--- Trade Name: Tomcat Bait Stations Date Created: 09 April 2008 Supplier: Motomco Ltd. Page 2 of 2 8. EXPOSURE CONTROL/PERSONAL PROTECTION SPECIAL PROTECTIVE EQUIPMENT: Not required VENTILATION: Not required RESPIRATOR TYPE: Not required SKIN PROTECTION: Not required EYE PROTECTION: Not required HYGIENE RECOMMENDATIONS: Not Applicable 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Injection Molded Plastic Bait Delivery Device BOILING POINT: N/A MELTING POINT: N/A FREEZING POINT: N/A FLASH POINT: N/A DENSITY: N/A VAPOR PRESSURE: N/A SOLUBILITY: N/A 10. STABILITY AND REACTIVITY STABILITY: N/A INCOMPATIBILITY/CONDTIONS TO AVOID: N/A HAZARDOUS DECOMPOSITION PRODUCTS: None 11. TOXICOLOGICAL INFORMATION LD50, ORAL (INGESTION): Non-Toxic LD50, DERMAL (SKIN CONTACT): Non-Toxic LC50, INHALATION: N/A EYE IRRITATION: None SKIN IRRITATION: None DERMAL SENSITIZATION: Non-Toxic 12. ECOLOGICAL INFORMATION ENVIRONMENTAL BEHAVIOR: Non-Toxic ENVIRONMENTAL TOXICOLOGY: Non-Toxic EFFECTS ON WASTEWATER TREATMENT: Non-Toxic 13. DISPOSAL WASTE DISPOSAL METHOD: Dispose of in accordance with all local, state and national regulations. 14. TRANSPORT INFORMATION CLASSIFICATION: Not regulated or not classified as dangerous by DOT (USA), IATA (Air), or IMDG (Vessel). SHIPPING NAME: None 15. REGULATORY INFORMATION CLASSIFICATION: None 16. OTHER INFORMATIONS The information provided in this Safety Data Sheet has been obtained from sources believed to be reliable. Motomco Ltd. provides no warranties, either expressed or implied, and assumes no responsibility for the accuracy or completeness of the data contained herein. This information is offered for your consideration and investigation. The user is responsible to ensure that they have all current data relevant to their particular use. Page 800 of 878 Page 800 of 878 Page 800 of 878 Page 800 of 878 ---PAGE BREAK--- Material Safety Data Sheet: TOP DOWN AEROSOL, O/G Supercedes Date 28-Sep-2001 Issuing Date 29-Jan-2008 1. PRODUCT AND COMPANY IDENTIFICATION Product Name TOP DOWN AEROSOL, O/G Product Code 5416 Recommended Use herbicide Chemical Nature No information available Information on Manufacturer Emergency Telephone Number CERTIFIED LABS, DIV. OF NCH CORP. CHEMTREC ® [PHONE REDACTED] BOX 152170 IRVING, TEXAS 75015 2. HAZARDS IDENTIFICATION Emergency Overview WARNING! Flammable Vapors may cause flash fire or explosion Harmful by inhalation May cause drowsiness and dizziness Harmful in contact with skin Irritating to skin Irritating to eyes Harmful if swallowed Color Yellow - Light brown Physical State Aerosol Odor Aromatic Potential Health Effects Principle Route of Exposure Skin contact, Eye contact. Primary Routes of Entry Inhalation, Skin Absorption, Ingestion. Acute Effects Eyes Irritating to eyes. Skin Irritating to skin. May be absorbed through the skin in harmful amounts. Inhalation Harmful by inhalation. Irritating to respiratory system. Ingestion Toxic if swallowed. Ingestion may cause irritation to mucous membranes. Chronic Effects Prolonged skin contact may defat the skin and produce dermatitis. Harmful if inhaled and may cause delayed lung injury. Target Organ Effects Central nervous system. Aggravated Medical Conditions Skin disorders. Central nervous system. Potential Environmental Effects See Section 12 for additional Ecological information 3. COMPOSITION / INFORMATION ON INGREDIENTS Component CAS-No 2,4-D 94-75-7 Isopropyl alcohol 67-63-0 L.P.G. (liquified petroleum gas) 68476-85-7 4. FIRST AID MEASURES General Advice Do not breathe dust/fume/gas/mist/vapours/spray. Eye Contact Flush eyes with water at least 15 minutes. Get medical attention if eye irritation develops or persists. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Get medical attention if irritation develops and persists. Inhalation Move to fresh air. If breathing has stopped, apply artificial respiration. Immediate medical attention is required. Ingestion If swallowed, DO NOT induce vomiting. Drink plenty of water. Immediate medical attention is required. Never give anything by mouth to an unconscious person. Notes to Physician No information available. Treat 5. FIRE-FIGHTING MEASURES Flash Point 99°F / 37°C Method Seta closed cup Autoignition Temperature No information available Flammability Limits in Air Upper 9.0 Lower 1.9 Suitable Extinguishing Media Dry powder. Water spray. Carbon dioxide (CO2). Foam. Specific Hazards Arising from the Chemical In the event of fire, cool tanks with water spray. Vapours may form explosive mixtures with air. Static charges generated by emptying container in or near flammable vapors may cause flash fire.. Material can create slippery conditions. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 2 Flammability 3 Instability 1 HMIS Health 2 Flammability 3 Instability 1 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Avoid contact with the skin and the eyes. Remove all sources of ignition. Take precautionary measures against static discharges. Environmental Precautions Prevent product from entering drains. Methods for Containment No information available Methods for Cleaning Up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust) 7. HANDLING AND STORAGE Page 1 / 4 Page 801 of 878 Page 801 of 878 Page 801 of 878 Page 801 of 878 ---PAGE BREAK--- Handling Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharges. To avoid ignition of vapours by static electricity discharge, all metal parts of the equipment must be grounded. Storage Keep away from heat and sources of ignition. Storage Temperature Minimum 40°F / 4°C Maximum 120°F / 49°C Storage Conditions Indoor X Outdoor Heated Refrigerated 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH 2,4-D TWA: 10 mg/m3 TWA: 10 mg/m3 IDLH: 100 mg/m3 TWA: 10 mg/m3 Isopropyl alcohol TWA: 200 ppm STEL: 400 ppm TWA: 400 ppm TWA: 980 mg/m3 IDLH: 2000 ppm STEL 1225 mg/m3 STEL 500 ppm TWA: 400 ppm TWA: 980 mg/m3 L.P.G. (liquified petroleum gas) TWA: 1000 ppm TWA: 1000 ppm TWA: 1800 mg/m3 IDLH: 2000 ppm TWA: 1800 mg/m3 TWA: 1000 ppm Engineering Measures Use with local exhaust ventilation. Ensure adequate ventilation, especially in confined areas. Personal Protective Equipment Eye/Face Protection Safety glasses with side-shields. Skin Protection Neoprene gloves. Respiratory Protection Use NIOSH approved respiratory protection. General Hygiene Considerations Avoid contact with skin, eyes and clothing. Ensure that eyewash stations and safety showers are close to the workstation location. Remove and wash contaminated clothing before re-use. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Aerosol Viscosity Non viscous Color Yellow - Light brown Odor Aromatic Appearance Cloudy pH Not applicable Specific Gravity 0.89 Bulk Density No data available Evaporation Rate <1 (ether = 1) Percent Volatile (Volume) 100 VOC Content 99.2 Vapor Pressure 3102 mmHg @ 70 °F Vapor Density 4 Solubility Insoluble Boiling Point/Range 250°F / 121°C 10. STABILITY AND REACTIVITY Chemical Stability Stable under normal conditions. Hazardous polymerisation does not occur. Conditions to Avoid Keep away from open flames, hot surfaces, and sources of ignition. Keep away from children. Incompatible Products Strong oxidizing agents. Strong acids. Hazardous Decomposition Products Carbon oxides. Nitrogen oxides (NOx). Possibility of Hazardous Reactions None under normal processing 11. TOXICOLOGICAL INFORMATION Product Information No information available Component Information Acute toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Draize Test Other 2,4-D 375 mg/kg ( Rat ) 1400 mg/kg ( Rabbit ) no data available no data available no data available Isopropyl alcohol 4396 mg/kg ( Rat ) 12800 mg/kg ( Rabbit ) 12800 mg/kg ( Rat ) 72.6 mg/L ( Rat ) 4 h no data available no data available L.P.G. (liquified petroleum gas) no data available no data available no data available no data available no data available Chronic Toxicity Component Sensitization Mutagenicity Developmental Toxicity Reproductive Toxicity Target Organ Effects 2,4-D no data available no data available no data available no data available no data available Isopropyl alcohol no data available no data available no data available no data available no data available L.P.G. (liquified petroleum gas) no data available no data available no data available no data available no data available Carcinogenicity . Component ACGIH IARC NTP OSHA Other 2,4-D not applicable Group 2B not applicable X not applicable Isopropyl alcohol not applicable Group 1 not applicable X not applicable L.P.G. (liquified petroleum gas) not applicable not applicable not applicable not applicable not applicable 12. ECOLOGICAL INFORMATION Product Information No information available Component Information Component Toxicity to Algae Toxicity to Fish Microtox Water Flea log Pow 2,4-D EC50= 33.2 mg/L Selenastrum capricornutum 120 h LC50 128 - 217 mg/L Menidia beryllina 96 h EC50 = 5.74 mg/L 15 min EC50 = 417.8 mg/L 48 h 2.58 - 2.83 Isopropyl alcohol EC50> 1000 mg/L Scenedesmus LC50= 61200 mg/L Pimephales promelas 96 h EC50 = 35390 mg/L 5 min EC50 = 13299 mg/L 48 h 0.05 5416 - TOP DOWN AEROSOL, O/G 5416 - TOP DOWN AEROSOL, O/G 5416 - TOP DOWN AEROSOL, O/G 5416 - TOP DOWN AEROSOL, O/G Issuing Date 29-Jan-2008 Issuing Date 29-Jan-2008 Issuing Date 29-Jan-2008 Issuing Date 29-Jan-2008 Page 2 / 4 Page 802 of 878 Page 802 of 878 Page 802 of 878 Page 802 of 878 ---PAGE BREAK--- subspicatus 72 h EC50> 1000 mg/L Scenedesmus subspicatus 96 h LC50= 94900 mg/L Pimephales promelas 96 h LC50= 9640 mg/L Pimephales promelas 96 h L.P.G. (liquified petroleum gas) no data available no data available no data available no data available 2.8 Persistence and Degradability No information available Bioaccumulation No information available Mobility No information available 13. DISPOSAL CONSIDERATIONS Product Disposal Dispose of in accordance with local regulations Container Disposal Contains gas under pressure; may explode if heated 14. TRANSPORT INFORMATION DOT Proper Shipping Name CONSUMER COMMODITY Hazard Class ORM-D TDG Proper shipping name Aerosols Hazard Class 2.1 UN-No UN1950 Description AEROSOLS,2.1,UN1950 ICAO UN-No UN1950 Proper Shipping Name Aerosols Hazard Class 2.1 Shipping Description Aerosols,UN1950 IATA UN-No UN1950 Proper Shipping Name Aerosols, flammable Hazard Class 2.1 ERG Code 10L Shipping Description UN1950,Aerosols, flammable,2.1 LIMITED QUANTITY IMDG/IMO Proper Shipping Name Aerosols Hazard Class 2.1 UN-No UN1950 EmS No. F-D, S-U Shipping Description UN1950, Aerosols,2.1 LIMITED QUANTITY 15. REGULATORY INFORMATION Inventories TSCA Complies DSL Complies U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part 372: Component CAS-No Weight % SARA 313 - Threshold Values 2,4-D 94-75-7 0.1-1 0.1 Isopropyl alcohol 67-63-0 1-5 1.0 SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard Yes Sudden Release of Pressure Hazard No Reactive Hazard Yes CERCLA Component Hazardous Substances RQs CERCLA EHS RQs 2,4-D 100 lb Not applicable Isopropyl alcohol Not applicable Not applicable L.P.G. (liquified petroleum gas) Not applicable Not applicable Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class Non-controlled. 16. OTHER INFORMATION Prepared By Mike McDowell Supercedes Date 28-Sep-2001 Issuing Date 29-Jan-2008 Reason for Revision No information available Glossary No information available 5416 - TOP DOWN AEROSOL, O/G 5416 - TOP DOWN AEROSOL, O/G 5416 - TOP DOWN AEROSOL, O/G 5416 - TOP DOWN AEROSOL, O/G Issuing Date 29-Jan-2008 Issuing Date 29-Jan-2008 Issuing Date 29-Jan-2008 Issuing Date 29-Jan-2008 Page 3 / 4 Page 803 of 878 Page 803 of 878 Page 803 of 878 Page 803 of 878 ---PAGE BREAK--- List of References No information available CERTIFIED LABS, DIV. OF NCH CORP. The information contained herein is based on date obtained considered to be accurate in light of current formulation. However, no warranty is expressed or implied regarding the accuracy of the data or the results to be obtained from the use thereof. 5416 - TOP DOWN AEROSOL, O/G 5416 - TOP DOWN AEROSOL, O/G 5416 - TOP DOWN AEROSOL, O/G 5416 - TOP DOWN AEROSOL, O/G Issuing Date 29-Jan-2008 Issuing Date 29-Jan-2008 Issuing Date 29-Jan-2008 Issuing Date 29-Jan-2008 Page 4 / 4 Page 804 of 878 Page 804 of 878 Page 804 of 878 Page 804 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET:TOP DOWN AEROSOL, O/G DATE OF ISSUE: 09/28/2001 SUPERCEDES: 07/02/2001 SECTION I - GENERAL INFORMATION Chemical Name & Synonyms: Trade Name & Synonyms: N/A TOP DOWN AEROSOL, O/G Chemical Family: Formula Mixture: X PETROLEUM HYDROCARBON/ALCOHOL BLEND Manufacturer's Name: CHEMSEARCH DIV. OF NCH CORP. Address: BOX 152170 IRVING, TX 75015 Prepared By: Product Code Number Emergency Phone Number C Williamson/Chemist 5416 [PHONE REDACTED] SECTION II - HAZARDOUS INGREDIENTS THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS Chemical Name (Ingredients) Hazard TLV PEL STEL CAS # 2,4-DICHLOROPHENOXYACETIC ACID, DMA SALT SL TOX/CAR N/E 1 N/E 2 N/E 94-75-7 AROMATIC HYDROCARBON IRRITANT 50 PPM 3 N/E 2 N/E 64742-95-6 LIQUEFIED PETROLEUM GAS IRRITANT 1000PPM 1 1000PPM 2 N/E 68476-85-7 ISOPROPANOL IRR/FLAM 400PPM 1 400PPM 2 N/E 67-63-0 SECTION III - PHYSICAL DATA Boiling Point >250º Specific Gravity (H20=1): 0.89 Vapor Pressure (MM HG): 35-60psi Color: STRAW Vapor Density (Air=1): >1 Odor: AROMATIC NAPHTHA PH @ 100% : N/A Clarity HAZY % Volatile by Volume: 98 Evaporation Rate (BU A/C=1): <1 H20 Solubility: NEGLIGIBLE Viscosity: NON-VISCOUS SECTION IV - FIRE AND EXPLOSION HAZARD Flash Point: Flammable Limits: LEL: UEL: <100ºF / T.C.C. AROM HC/IPA 1.0% 12.7%@200º Extinguishing Media: Foam:X Alcohol Foam: CO2:X Dry Chemical:X Water Spray:X Other: Special Fire Fighting Procedures: FIREFIGHTERS SHOULD WEAR A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR. COOL FIRE-EXPOSED CONTAINERS WITH WATER SPRAY TO PREVENT BURSTING. Unusual Fire and Explosion Hazards: VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL TO DISTANT SOURCES OF IGNITION AND FLASHBACK. PRODUCT MAY PRODUCE A FLOATING FIRE HAZARD AS LIQUID FLOATS ON WATER. FLAME EXTENSION IS >36 INCHES, BURNBACK IS 0 INCHES. Aerosol Level (NFPA 30B): 3 NFPA Hazard Rating: (0=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme) Health:2 Flammability:4 Instability:1 Special: SECTION V - HEALTH HAZARD DATA Threshold Limit Value: NOT ESTABLISHED FOR MIXTURE. SEE SECTION II. ---PAGE BREAK--- Effects of Overexposure: -Acute(Short Term Exposure) EYE CONTACT: CAUSES IRRITATION SEEN AS REDNESS, STINGING AND TEARING. SKIN CONTACT: CAUSES IRRITATION SEEN AS ITCHING AND REDNESS; PRODUCT MAY BE ABSORBED THROUGH THE SKIN IN HARMFUL AMOUNTS. INHALATION: CAUSES HEADACHE, DIZZINESS AND NAUSEA; EXCESSIVE INHALATION MAY LEAD TO UNCONSCIOUSNESS. CAUSES RESPIRATORY IRRITATION SEEN AS COUGHING AND SNEEZING. ADVERSE CLINICAL REACTIONS FROM EXTREME EXPOSURES TO ISOPROPANOL VAPORS MAY CAUSE DIZZINESS, DROWSINESS, HEADACHE, NAUSEA, VOMITING, DIARRHEA, DECREASED URINATION, LOSS OF REFLEXES, CNS AND RESPIRATORY DEPRESSION, HYPOTENSION, STUPOR AND UNCONSCIOUSNESS. INGESTION: CAUSES IRRITATION WITH POSSIBLE NAUSEA, VOMITING AND DIARRHEA. INGESTION OF ISOPROPANOL MAY CAUSE CNS DEPRESSION, HEADACHE, DROWSINESS, LOSS OF COORDINATION, HYPOTENSION, HYPOTHERMIA, KIDNEY AND LIVER DYSFUNCTION AND COMA. -Chronic (Long Term Exposure) REPEATED INHALATION EXPOSURE TO PHENOXY HERBICIDES MAY CAUSE CANCER. THE RISK OF CANCER DEPENDS ON THE LEVEL AND DURATION OF EXPOSURE. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE ARE PRE-EXISTING RESPIRATORY AND SKIN CONDITIONS SUCH AS ASTHMA, AND DERMATITIS. TARGET ORGANS: CENTRAL NERVOUS SYSTEM, KIDNEYS AND LIVER. Primary Routes of Entry: Inhalation:X Ingestion:X Absorption:X Emergency and First Aid Procedures: -Inhalation: MOVE PERSON TO FRESH AIR. IF PERSON IS NOT BREATHING, CALL 911 OR AN AMBULANCE, THEN GIVE ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH IF POSSIBLE. CALL A POISON CONTROL CENTER OR DOCTOR FOR FURTHER TREATMENT ADVICE. -Eye Contact: HOLD THE EYE OPEN AND RINSE SLOWLY AND GENTLY FOR 15-20 MINUTES. REMOVE CONTACT LENSES, IF PRESENT, AFTER THE FIRST 5 MINUTES OF TREATMENT, THEN CONTINUE RINSING THE EYE. CALL A POISON CONTROL CENTER OR A DOCTOR FOR TREATMENT ADVICE. -Skin Contact: TAKE OFF CONTAMINATED CLOTHING. RINSE THE SKIN IMMEDIATELY WITH PLENTY OF SOAP AND WATER FOR 15-20 MINUTES. CALL A POISON CONTROL CENTER OR A DOCTOR FOR TREATMENT ADVICE. -Ingestion: CALL A POISON CONTROL CENTER OR A DOCTOR IMMEDIATELY FOR TREATMENT ADVICE. HAVE THE PERSON SIP A GLASS OF WATER, IF ABLE TO SWALLOW. DO NOT INDUCE VOMITING UNLESS TOLD TO DO SO BY A POISON CONTROL CENTER OR A DOCTOR. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSING PERSON. -Notes to Physician: INGESTION AND SUBSEQUENT VOMITING OF THIS PRODUCT CAN LEAD TO ASPIRATION OF THE PRODUCT INTO THE LUNGS WHICH CAN CAUSE DAMAGE AND MAY BE FATAL. DEPENDING ON THE AMOUNT INGESTED AND RETAINED AS WELL AS THE TOXICITY OF THE PRODUCT, GASTRIC LAVAGE SHOULD BE CONSIDERED. KEEP PATIENT'S HEAD BELOW HIPS TO PREVENT PULMONARY ASPIRATION. IF COMATOSE, A CUFFED ENDOTRACHAEL TUBE WILL PREVENT ASPIRATION. SECTION VI - TOXICITY INFORMATION Product Contains Chemicals Listed as Carcinogen or Potential Carcinogen By: IARC: Yes NTP: No OSHA: No ACGIH: No OTHER: No 2,4-DICHLOROPHENOXYACETIC ACID, DMA SALT ORL-RAT LD50: 625 MG/KG 3. SKN-RBT LD50: 2115 MG/KG 3. 2,4-D IS A CHLOROPHENOXY-HERBICIDE WHICH, AS A GROUP, HAS BEEN CLASSIFIED BY IARC AS POSSIBLY CARCINOGENIC TO HUMANS (GROUP 2B). AROMATIC HYDROCARBON EYE-RBT SDT: 100 UL/24H MILD 3. ORL-RAT LD50: 8400 MG/KG 3. IHL-RAT TCLO: 1320 PPM/6H/90D-I 3. LIQUEFIED PETROLEUM GAS NO TOXICOLOGICAL DATA AVAILABLE ---PAGE BREAK--- ISOPROPANOL ORL-HMN LDLo: 5272 KG/KG 4. ORL-RAT LD50: 5045 MG/KG 4. IHL-RAT LC50: 16000 PPM/8H 4. SKN-RBT LD50: 12800 MG/KG 4. SKN-RBT SDT: 500 MG MODERATE 4. EYE-RBT SDT: 100 MG/24H MODERATE 4. IHL-RAT TLo: 8000 PPM/8H/20W-I PERIPHERAL NERVES 4. IHL-RAT TCLo: 3500 PPM/7H FEMALE 1-19D AFTER CONCEPTION: FETOTOXICTY 4. ISOPROPANOL HAS BEEN SHOWN TO CAUSE HARM TO THE FETUS IN LABORATORY ANIMAL STUDIES. HARM TO THE FETUS OCCURS ONLY AT EXPOSURE LEVELS THAT HARM THE PREGNANT ANIMAL. THE RELEVANCE OF THESE FINDINGS TO HUMANS IS UNCERTAIN. OVEREXPOSURE TO THIS MATERIAL HAS BEEN FOUND TO CAUSE MILD, REVERSIBLE LIVER EFFECTS IN LABORATORY ANIMALS. 4. SECTION VII - REACTIVITY DATA Stability: Stable:X Unstable: Conditions to Avoid: AVOID HEAT, HOT SURFACES, SPARKS AND OPEN FLAMES. AVOID TEMPERATURES ABOVE 120ºF. Incompatibility (Materials to Avoid): STRONG OXIDIZING AGENTS SUCH AS CHLORINE BLEACH AND CONCENTRATED HYDROGEN PEROXIDE; STRONG ACIDS AND SOME PLASTICS. Hazardous Decomposition Products: OXIDES OF CARBON AND NITROGEN. Hazardous Polymerization: May Occur: Will Not Occur:X Conditions to Avoid: N/A SECTION VIII - SPILL OR LEAK PROCEDURES Steps to be Taken if Material is Released or Spilled: DUE TO THE NATURE OF THE AEROSOL PACKAGING, A LARGE SPILL IS UNLIKELY. FOR A SMALL SPILL, VENTILATE THE AREA. ABSORB WITH AN INERT MATERIAL AND TRANSFER ALL MATERIAL INTO A PROPERLY LABELED CONTAINER FOR DISPOSAL. WEAR APPROPRIATE PROTECTIVE CLOTHING. Waste Disposal Method(s): DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS. TYPICAL DISPOSAL IS TO WRAP THE EMPTY AEROSOL CONTAINER IN SEVERAL LAYERS OF NEWSPAPER AND DISPOSE OF IN THE TRASH. AEROSOL RECYCLING PROGRAMS ARE AVAILABLE IN MANY AREAS. DO NOT PUNCTURE OR INCINERATE THIS CONTAINER. Neutralizing Agent: N/A SECTION IX - SPECIAL PROTECTION INFORMATION Required Ventilation: LOCAL VENTILATION IS RECOMMENDED TO CONTROL EXPOSURE FROM OPERATIONS THAT CAN GENERATE MISTS OR VAPORS. Respiratory Protection: A NIOSH/MSHA APPROVED RESPIRATOR IN POORLY VENTILATED AREAS AND/OR FOR EXPOSURE ABOVE THE ACGIH TLV OR OSHA PEL OR WHERE MISTING EXISTS. Glove Protection: NEOPRENE OR NITRILE RUBBER GLOVES SHOULD BE WORN. Eye Protection: CHEMICAL GOGGLES SHOULD BE WORN. Other Protection: WEAR PROTECTIVE CLOTHING INCLUDING LONG-SLEEVED SHIRT, LONG PANTS, SOCKS AND SHOES WHEN HANDLING. WASH HANDS, FACE AND ARMS WITH SOAP AND WATER AS SOON AS POSSIBLE AFTER USING AND ---PAGE BREAK--- BEFORE USING THE TOILET, EATING, SMOKING OR DRINKING. AFTER WORK, REMOVE ALL CLOTHING AND SHOWER USING SOAP AND WATER. DO NOT REUSE CLOTHING WORN DURING THE PREVIOUS DAY'S MIXING AND LOADING OR APPLICATION OF THIS PRODUCT WITHOUT CLEANING FIRST. CLOTHING MUST BE KEPT AND WASHED SEPARATELY FROM OTHER HOUSEHOLD LAUNDRY. REMOVE AND WASH CONTAMINATED CLOTHING IMMEDIATELY. SECTION X - STORAGE AND HANDLING INFORMATION Storage Temperature: Indoors:X Outdoors: Heated: Refrigerated: Minimum Temperature:40ºF Maximum Temperature:120ºF Precautions to be taken in Handling and Storing: DO NOT ALLOW PESTICIDE TO CONTAMINATE FOOD, FEED OR NATURAL BODIES OF WATER. DO NOT USE AROUND HEAT, SPARKS, PILOT LIGHTS, STATIC ELECTRICITY AND OPEN FLAME. Other Precautions: KEEP OUT OF REACH OF CHILDREN AND ANIMALS. READ THE ENTIRE LABEL BEFORE USING THE PRODUCT. FOLLOW THE LABEL DIRECTIONS. SECTION XI - REGULATORY INFORMATION Chemical Name CAS Number Upper % Limit Those Ingredients listed above are subject to the reporting requirements of 313 of Title III& of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372. PLEASE CALL 1-[PHONE REDACTED] FOR ADDITIONAL INFORMATION IF YOU ARE A CALIFORNIA CUSTOMER. THIS MSDS IS NOT INTENDED FOR USERS IN THE STATE OF CALIFORNIA SECTION XII - REFERENCES 1. THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS AND BIOLOGICAL EXPOSURE INDICES, ACGIH, 2001. 2. OSHA PEL. 3. REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES, CCINFODisc, 2001. 4. VENDOR'S MSDS. ALL COMPONENTS IN THIS PRODUCT CAN BE FOUND IN THE CURRENT TSCA INVENTORY. IRR:IRRITANT, FLAM/FLAMM:FLAMMABLE, COMB:COMBUSTIBLE, CORR:CORROSIVE CARC:CARCINOGENIC, TOX:TOXIC, N/A:NOT APPLICABLE, N/E:NOT ESTABLISHED, COC:CLEVELAND OPEN CUP, PMCC:PENSKY-MARTIN CLOSED CUP, TCC:TAGLIABUE CLOSED CUP, LEL:LOWER EXPLOSION LIMIT, UEL:UPPER EXPLOSION LIMIT, NFPA:NATIONAL FIRE PROTECTION ASSOCIATION, IARC:INTERNATIONAL AGENCY FOR THE RESEARCH ON CANCER, NTP:NATIONAL TOXICOLOGY PROGRAM, OSHA:OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION, ACGIH:AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS, TLV:THRESHOLD LIMIT VALUE, PEL:PERMISSIBLE EXPOSURE LIMIT, STEL:SHORT-TERM EXPOSURE LIMIT, MLD:MILD, MOD:MODERATE, SEV:SEVERE, MUT:MUTAGENIC, PNOS: PARTICULATES (INSOLUBLE) NOT OTHERWISE SPECIFIED, SDT:STANDARD DRAIZE TEST, ORL: ORAL, HMN: HUMAN, IHL:INHALATION THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE IN LIGHT OF CURRENT FORMULATION.HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. CHEMSEARCH DIV. OF NCH CORP. assumes no responsibility for personal injury or property damage caused by the use, storage, or disposal of the product in a manner not recommended on the product label. Users assume all risks associated with such unrecommended use,storage or disposal of the product." ---PAGE BREAK--- Page 809 of 878 Page 809 of 878 Page 809 of 878 Page 809 of 878 ---PAGE BREAK--- Page 810 of 878 Page 810 of 878 Page 810 of 878 Page 810 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET TRIAD II DISINFECTANT CLEANER Version Number: 1 Preparation date: 2006-03-01 Personal protective equipment NFPA HMIS Reactivity 0 Health Fire Hazard 3 0 0 3 0 1. PRODUCT AND COMPANY IDENTIFICATION Product name: TRIAD II DISINFECTANT CLEANER MSDS 113961001 Product code: 113961001, 113961X, 54336, 53957, 53958 Recommended use: Disinfectant. This product is intended to be diluted prior to use. Emergency telephone number: 1-[PHONE REDACTED] (Prosar); 1-[PHONE REDACTED] (Int'l Prosar); 01-[PHONE REDACTED] (México) 2. HAZARDS IDENTIFICATION Principle routes of exposure: Eye contact. Skin contact. Inhalation. Eye contact: Corrosive. Causes permanent eye damage, including blindness. Skin contact: Corrosive. Causes permanent damage . Inhalation: May cause irritation and corrosive effects to nose, throat and respiratory tract. Ingestion: Corrosive. Causes burns to mouth, throat and stomach. 3. COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS COMPONENTS Ingredient(s) CAS # Weight % LD50 Oral LD50 Dermal LC50 Inhalation N-alkyl Dimethyl Benzyl Ammonium Chloride 68424-85-1 1 - 5% 426 mg/kg (rat) Not available Not available Octyl decyl dimethyl ammonium chloride 68424-95-5 1 - 5% Not available Not available Not available Ethyl alcohol 64-17-5 0.1 - 1.5% 7060 mg/kg (rat) Not available 20 g/kg/10H (rat) 4. FIRST AID MEASURES Eye contact: Immediately flush eyes with running water for at least 15-20 minutes, keeping eyelids open. Get medical attention immediately. Skin contact: Flush immediately with plenty of water for at least 15-20 minutes. Get medical attention immediately. Inhalation: If breathing is affected, remove to fresh air. Get medical attention immediately. Ingestion: If swallowed, give a cupful of water or milk. THEN IMMEDIATELY CONTACT A PHYSICIAN OR POISON CENTER. DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Aggravated Medical Conditions: Persons with pre-existing skin disorders may be more susceptable to irritating effects 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: Not applicable Specific hazards: Not applicable Unusual hazards: None known Specific methods: No special methods required EMERGENCY OVERVIEW DANGER. CORROSIVE. CAUSES SKIN AND EYE BURNS. HARMFUL OR FATAL IF SWALLOWED. Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-0902 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.johnsondiversey.com TRIAD II DISINFECTANT CLEANER Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-[PHONE REDACTED] 1 of 3 Page 811 of 878 Page 811 of 878 Page 811 of 878 Page 811 of 878 ---PAGE BREAK--- Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: No information available 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Use personal protective equipment Environmental precautions and clean-up methods: Use appropriate containment to avoid environmental contamination. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use a water rinse for final clean-up. 7. HANDLING AND STORAGE Handling: Avoid contact with skin, eyes and clothing. Do not taste or swallow. Avoid breathing vapors or mists. Use only with adequate ventilation. Remove and wash contaminated clothing and footwear before re-use. Wash thoroughly after handling. Product residue may remain on/in empty containers. All precautions for handling the product must be used in handling the empty container and residue. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep closed in a dry, cool and well-ventilated place. KEEP OUT OF THE REACH OF CHILDREN. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: Good general ventilation should be sufficient to control airborne levels. Respiratory protection is not required if good ventilation is maintained. Personal Protective Equipment Eye protection: Chemical splash goggles. Hand protection: Chemical resistant gloves Skin and body protection: Protective footwear. If major exposure is possible, wear suitable protective clothing and footwear. Respiratory protection: In case of insufficient ventilation wear suitable respiratory equipment. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice Ingredient(s) CAS # ACGIH OSHA Mexico Ethyl alcohol 64-17-5 1000 ppm (TWA) 1000 ppm (TWA) 1900 mg/m3 (TWA) 1000 ppm (TWA) 1900 mg/m3 (TWA) 9. PHYSICAL AND CHEMICAL PROPERTIES Elemental Phosphorous: 0 10. STABILITY AND REACTIVITY Stability: The product is stable. Polymerization: Hazardous polymerization does not occur. Hazardous decomposition products: None reasonably foreseeable. 11. TOXICOLOGICAL INFORMATION Acute toxicity Oral LD50 estimated to be greater than 5000 mg/kg Component Information: See Section 3 Chronic toxicity: None known Specific effects Carcinogenic effects: None known Mutagenic effects: None known pH: Solubility in other solvents: No information available Evaporation rate: No information available 12.6 Odor: Minty Physical State: Boiling point/range: Not determined Dilution pH: Specific gravity: 1.024 10 Melting point/range: Not determined Bulk density: Density: 1.024 Appearance: Decomposition temperature: Not determined Liquid VOC: 1.4 No information available Autoignition temperature: No information available Vapor density: Flash point: >200 >93.3 No information available Viscosity: No information available Liquid Solubility: Soluble Color: TRIAD II DISINFECTANT CLEANER Partition coefficient (n-octanol/water): No information available 2 of 3 Clear Green Page 812 of 878 Page 812 of 878 Page 812 of 878 Page 812 of 878 ---PAGE BREAK--- Reproductive toxicity: None known Target organ effects: None known 12. ECOLOGICAL INFORMATION Environmental Information: No data available 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: PESTICIDAL WASTE - Observe all applicable Federal/Provincial/State regulations and Local/Municipal ordinances regarding disposal of pesticide wastes. 14. TRANSPORT INFORMATION DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 STATE RIGHT TO KNOW Ingredient(s) CAS # MARTK: PARTK: RIRTK: Ethyl alcohol 64-17-5 X X X X N-alkyl Dimethyl Benzyl Ammonium Chloride 68424-85-1 - - - - Water 7732-18-5 - - - - Tetrasodium salt of EDTA 64-02-8 - - - - polyethoxyethanol 26027-38-3 - - - - Octyl decyl dimethyl ammonium chloride 68424-95-5 - - - - CERCLA / SARA None Canada WHMIS hazard class: E Corrosive material . Ingredient(s) CAS # NPRI Ethyl alcohol 64-17-5 X polyethoxyethanol 26027-38-3 X DIN No. : 02164078 PCP No. : 24161 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: None Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 3 of 3 TRIAD II DISINFECTANT CLEANER Page 813 of 878 Page 813 of 878 Page 813 of 878 Page 813 of 878 ---PAGE BREAK--- There was a PDF conversion failure for - Product Name: Triad III CAS Number: Manufacturer: JohnsonDiversey SDS Date: 6/7/2007 To complete your binder, please link a different SDS for this product or print the SDS manually from http://www.msdsonline.com/Partners/ShowDocument/Default.aspx?ShowId=LN5Cw%2bdH66s%3d and add to your binder. We are currently researching solutions to this issue. Thank you for your patience. Page 814 of 878 Page 814 of 878 Page 814 of 878 Page 814 of 878 ---PAGE BREAK--- Page 1 of 4 Procter & Gamble P&G Household Care F&HC Innovation Center 5299 Spring Grove Avenue Cincinnati, OH 45217-1087 MATERIAL SAFETY DATA SHEET MSDS FH/L/2006/RWRB-6SQJ3Y Issue Date: 9/2/06 Supersedes: FH/L/2005/RWRB-6QQE2Z Issue Date: 6/20/06 SECTION I - CHEMICAL PRODUCT Identity: Liquid Hand Dishwashing Detergent Finished, Packaged Product Brands: Ultra Dawn Power Plus Ultra Dawn Plus Hand Care Ultra Dawn Oxi Ultra Dawn with Bleach Alternative (Mountain Spring, Fresh Rapids) Dawn Complete (Original Scent, Apple Blossom, Floral Scent, Antibacterial Hand Soap) P&G Telephone Number: DAWN 1-[PHONE REDACTED] (DAWN) or call Local Poison Control Center or your physician SECTION II - COMPOSITION AND INGREDIENTS Ingredients listed on the product label are: biodegradable surfactants (anionic and nonionic), enzymes and no phosphate. The active ingredient in the Dawn Complete Dishwashing Liquid + Antibacterial Hand Soap is triclosan at 0.1%. The Drug Facts box on the back label of this product lists all inactive ingredients in the formula. Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200. Chemical Name Common Name CAS No. Composition Range LD50/LC50 Ethyl alcohol Ethanol 64-17-5 1-5% LD50 (rabbit, oral)= 6300 mg/kg Page 815 of 878 Page 815 of 878 Page 815 of 878 Page 815 of 878 ---PAGE BREAK--- 2 Liquid Hand Dishwashing Detergent (Continued) Page 2 of 4 SECTION III - HAZARDS IDENTIFICATION Potential Health Hazards (Acute and Chronic): (See Section 11 for more information) Ingestions: Ingestion may cause transient gastrointestinal irritation. Eye Contact: May cause mild, transient irritation. Skin: Transient irritation with prolonged exposure to concentrated material. Inhalation: N/A Signs and of Exposure: Ingestion: May result in nausea, vomiting, and/or diarrhea. Eye Contact: May cause stinging, tearing, itching, swelling, and/or redness. Skin: Prolonged contact with concentrated material may be drying or transiently irritating to skin. Inhalation: N/A Potential Environmental Effects: (See Section 12 for more information) SECTION IV - FIRST AID INFORMATION First Aid Procedures: Ingestion: Drink 1 or 2 glasses of water. Eye Contact: Flush thoroughly with water for 15 minutes. Skin: If prolonged contact occurs, rinse thoroughly with water. If spilled on clothing, change clothes. If persist or recur, seek medical attention. Inhalation: N/A Other: Consumer product package has a voluntary avoid accidents statement on the back label: “Keep out of reach of children. If the product gets in eyes, rinse thoroughly with water. If swallowed, drink a glass of water to dilute.” SECTION V - FIRE FIGHTING INFORMATION Flammable Properties: The liquid hand dishwashing detergents have a flashpoint of 115-135°F (46.1-57.2°C) Pensky-Martens (Closed cup). However, the detergents are an aqueous solution (>50% water) and do not sustain combustion according to ASTM D4206. Extinguishing Media: Suitable: CO2, water or dry chemical. Protection of Firefighters: Specific Hazards Arising form the Material: None Special Fire Fighting Procedures: None. SECTION VI - ACCIDENTAL RELEASE MEASURES Personal Precautions: None Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS. Solutions of the detergents may be allowed to be flushed down sewer - First check with your local water treatment plant. Recycling is recommended for undiluted scrap product. Do not landfill. Steps To Be Taken in Case Material is Released or Spilled: Prevent spills from reaching a waterway. Sorbents may be used. Read “Waste Disposal Method” below for further information. Page 816 of 878 Page 816 of 878 Page 816 of 878 Page 816 of 878 ---PAGE BREAK--- 3 Liquid Hand Dishwashing Detergents Continued) Page 3 of 4 SECTION VII - HANDLING AND STORAGE Precautions To Be Taken in Handling: No unusual precautions necessary. Precautions To Be Taken in Storage: No unusual precautions necessary. SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION Recommended Exposure Guidelines: Ethanol (CAS# 64-17-5) ACGIH-TLV 1000 ppm OSHA Z-1 PEL 1000 ppm Engineering Controls: Personal Protective Equipment (PPE): Eye/Face Protection: None required with normal household use. Industrial Setting: For splash protection, use chemical goggles. Eye wash fountain is recommended. Skin Protection: None required with normal household use. Industrial Setting: Protective gloves (rubber, neoprene) should be used for prolonged direct contact. Respiratory Protection: None required with normal household use. Ventilation Local Exhaust: None required with normal consumer use. Special: None Industrial (General): Normal/general dilution ventilation is acceptable. Other: None SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES Boiling Point N/K Specific Gravity (H2O=1)/Density: ca. 1 Vapor Pressure (mm Hg): N/K Physical State: Liquid Vapor Density (Air=1): N/K Melting/Freezing Point: ~ 30 °F Flash Point (Method Used): 115-135°F (46.1- 57.2°C) Pensky-Martens (Closed cup). This is an aqueous solution (>50% water) that contains less than 24% by volume of alcohol and does not sustain combustion according to ASTM D4206. pH (10% solution): 9-9.2 Solubility in Water: Completely Reserve Alkalinity: N/A Appearance and Odor: Colored liquids. All products are perfumed. Partition Coefficient (n-octanol/water): N/K Auto-Ignition Temperature: N/K Decomposition Temperature: N/K Evaporation Rate (nBuOAc=1): N/K Explosive Limits: LEL: N/A UEL: N/A SECTION X - STABILITY AND REACTIVITY Chemical Stability: Stable Possible Hazardous Reactions/Conditions: None known Conditions to Avoid: None Incompatible Materials: None Hazardous Decomposition Products: None known SECTION XI - TOXICOLOGICAL INFORMATION Liquid hand dishwashing detergents have a relatively low order of toxicity. They may be irritating, but they are not expected to be corrosive. They are expected to be emetic. Page 817 of 878 Page 817 of 878 Page 817 of 878 Page 817 of 878 ---PAGE BREAK--- 4 Liquid Hand Dishwashing Detergents (Continued) Page 4 of 4 SECTION XII - ECOLOGICAL INFORMATION All surfactants are readily biodegradable. These products are safe for septic tanks. SECTION XIII - DISPOSAL CONSIDERATIONS Waste Disposal Method: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH FEDERAL, STATE/PROVINCIAL AND LOCAL REGULATIONS. Household Disposal: Household product is safe for disposal down the drain with running water. The empty container may be discarded in the trash or recycled where facilities exist. Non-household Setting: Products covered by this MSDS, in their original form, when disposed as waste, are considered non-hazardous waste according to Federal RCRA regulations (40 CFR 261). The products are aqueous solutions (>50% water) that contain less than 24% by volume of alcohol. Solutions of diluted detergent in the course of use, may be allowed to be flushed down sewer. First check with your local water treatment plant. Recycling is recommended for undiluted scrap product. Do not landfill. SECTION XIV - TRANSPORT INFORMATION Transportation Information – These products are not regulated for transportation. For finished, packaged product transported by ground (DOT): Not regulated For finished, packaged product transported by water/vessel (IMDG): Not regulated For finished, packaged product transported by air (IATA): Not regulated SECTION XV - ADDITIONAL REGULATORY INFORMATION All intentionally-added components are listed on the US TSCA Inventory. These products are not subject to warning labeling under California Proposition 65. Perfumes contained within the products covered by this MSDS comply with appropriate IFRA guidance. All ingredients are CEPA approved for import to Canada by Procter & Gamble only. SECTION XVI - OTHER INFORMATION P&G Hazard Rating: Health: 1 4 = EXTREME Flammability: 1 3 = HIGH Reactivity: 0 2 = MODERATE 1 = SLIGHT 0=NOT SIGNIFICANT *N/A. - Not Applicable *N/K. - Not Known Data supplied is for use only in connection with occupational safety and health. The information contained herein has been compiled from sources considered by Procter & Gamble to be dependable and is accurate to the best of the Company’s knowledge. The information relates to the specific material designated herein, and does not relate to the use in combination with any other material or any other process. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, for any damage to any property resulting from misuse of the controlled product. Page 818 of 878 Page 818 of 878 Page 818 of 878 Page 818 of 878 ---PAGE BREAK--- - 1 - UNITED 101 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 101 MOISTURE BARRIER Moisture Barrier and Electrical Lubricant February 6, 2015 HMIS III HEALTH (0 = Maximum Safety) 1 PHYSICAL HAZARD (0 = Maximum Safety) 0 Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 FLAMMABILITY (0 = Maximum Safety) 1 2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) Food grade mineral oil 8042-47-5 40-70 5 mg/m3 5 mg/m3 NE NE 556-67-2 1-5 10 ppm* NE NE NE Dipropylene glycol monomethyl ether 34590-94-8 1-5 100 ppm (Skin) 100 ppm (Skin) NE NE 541-02-6 1-5 10 ppm* NE NE NE Carbon dioxide 124-38-9 1-5 5000 ppm 5000 ppm NE NE * Manufacturer’s recommended TWA exposure limit. 3. HAZARDS IDENTIFICATION Eyes: May cause slight irritation; does not injure eye tissue. Skin: Prolonged or repeated contact may cause moderate irritation. Inhalation: Exposure to massive amount of vapors may cause dizziness, drowsiness, throat irritation, unconsciousness and CNS effects. Ingestion: May cause upset stomach, nausea, vomiting, and diarrhea. Possible aspiration hazard may cause inflammation of the lungs. 4. FIRST AID MEASURES Eyes: Flush with large amounts of cool running water for at least 15 minutes while holding upper and lower lids open. If irritation persists call a physician. Skin: Wash with soap and water. If irritation persists call a physician. Inhalation: Remove to fresh air immediately. Apply artificial respiration if needed. Call a physician immediately. Ingestion: DO NOT induce vomiting. Call a physician immediately. Aspiration may cause chemical pneumonitis. 5. FIRE FIGHTING MEASURES Flash Point (TOC) : >200°F/93.3°C Explosive Limits: Lower (LEL): NE Upper (UEL): NE Flame Projection (Aerosol): Non- flammable per 16 CFR 1500.3 and 1500.45. Hazardous Products of Combustion: When strongly heated, as in a fire, this product may produce oxides of carbon. Fire and Explosion Hazards: Aerosol container (pressurized) may burst if heated over 120°F/48°C. Extinguishing Media: Foam, Dry chemical, Carbon dioxide. Fire Fighting Instructions: Wear self-contained breathing apparatus w/full protective clothing in chemical fires. Cool fire exposed containers with water to prevent pressure build up. MATERIAL SAFETY DATA SHEET 320 37th Avenue, St. Charles, Illinois 60174 To Reorder Call: www.unitedlabsinc.com . www.unitedlabsinc.com [PHONE REDACTED] Always follow Label Directions and Cautions. * Chronic 2 Moderate 4 Severe 1 Slight 3 Serious 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: B Page 819 of 878 Page 819 of 878 Page 819 of 878 Page 819 of 878 ---PAGE BREAK--- - 2 - 6. ACCIDENTAL RELEASE MEASURES Small Spills: Soak up with an inert absorbent and place in designated disposal container. Wash area thoroughly. Large Spills: Remove sources of ignition and ventilate area. Soak up with an inert absorbent and place in designated disposal container. Wash area thoroughly. 7. HANDLING AND STORAGE Keep away from heat, sparks, and flame. Use with adequate ventilation. Do not puncture or incinerate containers. Store as NFPA Code 30B Rating: Level 1 Aerosol. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Safety glasses or chemical splash goggles are recommended. Skin: Chemical resistant gloves are recommended. Respiratory: Not normally required. If vapor concentration exceeds TLV, use a NIOSH or MSHA approved respirator. Engineering Controls: Mechanical ventilation recommended when handling in enclosed/tight spaces. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 500°F/260°C Specific Gravity: 0.840 (H2O=1) Vapor Pressure: 68 psig Melting Point: ND Vapor Density: > 1 (air=1) Evaporation Rate: ND Solubility in Water: Slight pH: N/A Appearance and Odor: Aerosol; Brown liquid with solvent scent. 10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: When strongly heated, as in a fire, this product may produce oxides of carbon. Chemical Stability: Stable Incompatibility: Oxidizing agents such as bleach. 11. TOXICOLOGICAL INFORMATION Carcinogenicity (NTP/IARC/OSHA): None California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? None 12. ECOLOGICAL INFORMATION ND 13. DISPOSAL CONSIDERATIONS Consult your local, state, provincial and federal regulations for proper disposal guidelines. Do not puncture or incinerate containers. Disposal regulations may be different for each state and/or locality. 14. TRANSPORT INFORMATION DOT: Available upon request TDG: Available upon request UN: Availabale upon request 15. REGULATORY INFORMATION VOC (Volatile Organic Compounds): 3.34% TSCA (Toxic Substances Control Act): Listed SARA Title III Section 302 EHS: None SARA Title III Section 311/312: ND SARA Title III Section 313 Toxic Chemicals: None WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 101 MOISTURE BARRIER PREPARED BY: TechDept.AD Page 820 of 878 Page 820 of 878 Page 820 of 878 Page 820 of 878 ---PAGE BREAK--- There was a PDF conversion failure for - Product Name: UNITED 107 AEROSOL SAFETY SOLVENT CAS Number: Manufacturer: United Laboratories Inc. SDS Date: 6/3/2015 To complete your binder, please link a different SDS for this product or print the SDS manually from http://www.msdsonline.com/Legacy/Partners/Show-Document/Default.aspx?ShowId=SyoR1zpP2E8%3d and add to your binder. We are currently researching solutions to this issue. Thank you for your patience. Page 821 of 878 Page 821 of 878 Page 821 of 878 Page 821 of 878 ---PAGE BREAK--- - 1 - UNITED 107 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 107 AEROSOL SAFETY SOLVENT Multi Purpose Cleaner February 21, 2012 HMIS III HEALTH (0 = Maximum Safety) *2 PHYSICAL HAZARD (0 = Maximum Safety) 0 Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 FLAMMABILITY (0 = Maximum Safety) 2 2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) Trichloroethylene 79-01-6 > 90 10 ppm 100 ppm NE NE Carbon Dioxide 124-38-9 3 - 5 5,000 ppm 5,000 ppm NE NE ACGIH (STEL) Trichloroethylene CAS#79-01-6 25 ppm, Carbon Dioxide CAS #124-38-9 30,000 ppm 3. HAZARDS IDENTIFICATION Eyes: May cause slight irritation. Skin: May cause irritation. Prolonged or repeated contact can result in defatting and drying of the skin, irritation and dermatitis. Inhalation: Intentional misuse by inhaling the product can be harmful or fatal. High concentrations or prolonged exposure to lower concentrations may be irritating to mucous membranes. Ingestion: Exposure by ingestion of an aerosol is unlikely. May cause delayed lung damage. Components of the product may be absorbed into the body by ingestion. Chronic Effects: May cause central nervous system disorder and/or damage. May cause delayed lung damage. Prolonged skin contact may defat the skin and produce dermatitis. 4. FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops or persists. Skin: Wash off with warm water and soap. Get medical attention if irritation develops or persists. Inhalation: Move to fresh air. Oxgen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled to substance. Call a physician if develop or persist. Ingestion: If material is ingested, immediately contact a poison control center. Rinse mouth. Do not induce vomiting without advice from poiso control center. If vomiting occurs naturally, have vixtim lean forward to reduce risk of aspiration. 5. FIRE FIGHTING MEASURES Flash Point (TCC): Not flammable & not combustible by OSHA Explosive Limits: Lower (LEL): 7.3 Upper (UEL): 36.0 Flame Projection (Aerosol): Non-flammable per 16 CFR 1500.3 and 1500.45. Hazardous Products of Combustion: Material decomposed by fire may produce irritating, corrosive and/or toxic gases. Fire and Explosion Hazards: Exposure to temperature above 130°F/ 54.4°C may cause container to burst, rupture, or vent. Containers should be cooled with water to prevent vapor pressure build up. Runoff to sewer may cause fire or explosion hazard. Extinguishing Media: Water, Water fog, Foam, Dry chemical, Carbon dioxide. Fire Fighting Instructions: Wear self-contained breathing apparatus and protective clothing. Cool fire exposed containers to prevent rupturing. MATERIAL SAFETY DATA SHEET 320 37th Avenue, St. Charles, Illinois 60174 To Reorder Call: www.unitedlabsinc.com . www.unitedlabsinc.ca [PHONE REDACTED] Always follow Label Directions and Cautions. * Chronic 2 Moderate 4 Severe 1 Slight 3 Serious 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: X Consult Supervisor Page 822 of 878 Page 822 of 878 Page 822 of 878 Page 822 of 878 ---PAGE BREAK--- - 2 - 6. ACCIDENTAL RELEASE MEASURES Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated surface thoroughly. After removal flush contaminated area thoroughly with water. Large Spills: Ventilate area and remove all sources of ignition. Cover with absorbent material like vermiculite, sand or earth to soak up product and place in a disposal container. Clean contaminated surface thoroughly. Prevent entry into waterways, sewers or confined spaces. 7. HANDLING AND STORAGE Store in a cool, dry place away from heat, sparks or open flame. Do not store at temperatures above 49°C/ 120°F. Keep out of sunlight. Contents under pressure. Do not puncture, incinerate or crush. For Industrial and Institutional use only. NFPA Code 30B Rating: Level 1 Aerosol. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Chemical safety googles are recommended. Skin: Chemical resistant gloves are recommended. Wear appropriate chemical resistant clothing. Respiratory: None needed for proper use in accordance with label directions. If recommended exposure limits are exceeded wear a NIOSH approved respirator with mechanical filter/organic vapor cartridge. Engineering Controls: Insure adequate ventilation, especially in confined areas. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 186.8°F/ 86.1°C Specific Gravity: 1.47 (H2O=1) Vapor Pressure: 72-91 psig@70°F Melting Point: Concentrate -86°C Vapor Density: > 1 Evaporation Rate: ND Solubility in Water: Negligible pH: NA Appearance and Odor: Aerosol, clear, colorless, liquid with ether-like odor. 10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: Material decomposed by fire may produce irritating and/or toxic gases. Chemical Stability: Stable Incompatibility: Oxidizing agents, heat, flames and sparks. 11. TOXICOLOGICAL INFORMATION Carcinogenicity (NTP/IARC/OSHA): Trichloroethylene CAS# 79-01-6 California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? Yes – Trichloroethylene CAS# 79-01--6 12. ECOLOGICAL INFORMATION Components of this product are hazardous to aquatic life. 13. DISPOSAL CONSIDERATIONS Consult your local, state and federal regulations for proper disposal guidelines. Do not puncture or incinerate containers. Disposal regulations may be different for each state and/or locality. Waste codes: D040: Waste Trichloroethylene 14. TRANSPORT INFORMATION DOT: Available upon request TDG: Available upon request UN: Availabale upon request 15. REGULATORY INFORMATION VOC (Volatile Organic Compounds): 96.60 % TSCA (Toxic Substances Control Act): Listed SARA Title III Section 302 EHS: No SARA Title III Section 311/312: Yes SARA Title III Section 313 Toxic Chemicals: Trichloroethylene CAS# 79-01-6 (0.97 lb.)* * Pounds of reportable material per can of UNITED product. WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 107 AEROSOL SAFETY SOLVENT PREPARED BY: Sandy Kopacz Page 823 of 878 Page 823 of 878 Page 823 of 878 Page 823 of 878 ---PAGE BREAK--- - 1 - UNITED 125 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 125 ALL STIK Waterproof Adhesive Spray February 6, 2015 HMIS III HEALTH (0 = Maximum Safety) 1 PHYSICAL HAZARD (0 = Maximum Safety) 0 Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 FLAMMABILITY (0 = Maximum Safety) 4 2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) Propane 74-98-6 20-30 1000 ppm 1000 ppm NE NE n-Butane 106-97-8 15-20 1000 ppm NE NE 658 ppm/ 4 hr (rat) Acetone 67-64-1 15-20 500 ppm 1188 mg/m3 1000 ppm 2400 mg/m3 5800 mg/kg (rat/oral) NE n-Hexane 110-54-3 10-15 Skin: 50 ppm 176 mg/m3 500 ppm 1800 mg/m3 28710 mg/kg (rat/oral) 48000 ppm/ 4 hr. (rat) Methyl acetate 79-20-9 5- 8 200 ppm 200 ppm NE NE Acetone 67-64-1 ACGIH (STEL) 750 ppm, n-Hexane 110-54-3 ACGIH (STEL) 1000 ppm 3. HAZARDS IDENTIFICATION Eyes: May cause irritation. Skin: May cause irritation. Prolonged or repeated contact can result in defatting and drying of the skin. Inhalation: Intentional misuse by concentrating and inhaling the product can be harmful or fatal. Prolonged inhalation may be harmful. Ingestion: Exposure by ingestion of an aerosol is unlikely. May cause gastrointestinal irritation, nausea, vomiting and diarrhea. May cause delayed lung damage. Target organs: Central nervous system, respiratory system. Chronic effects: May cause central nervous system disorder and/or damage. May cause delayed lung damage. 4. FIRST AID MEASURES Eyes: Immediately flush with cool water for at least 15 minutes while holding eyelids open. Get medical attention if irritation develops or persists. Skin: Immediately remove all contaminated clothing. Wash with soap and water. If irritation develops or persists, get medical attention. If Inhaled: Remove to fresh air. Administer artificial respiration if needed. Call a physician or poison control center. Ingestion: DO NOT induce vomiting. rinse mouth thoroughly with water. If vomiting occurs have person lean forward to reduce risk of aspiration. Call a physician or poison control center immediately. 5. FIRE FIGHTING MEASURES Flash Point : -156°F/-104°C estimated propellant Explosive Limits: Lower (LEL): NE Upper (UEL): NE Flame Projection (Aerosol): Flammable Spray as per CFR 1500.3 and 1500.45 Hazardous Products of Combustion: When strongly heated, as in a fire, this product may produce oxides of carbon. Fire and Explosion Hazards: Do not breathe fumes. At elevated temperatures (above 120°F/49°C) containers may vent, rupture, or burst, greatly increasing the fire hazard. Vapor or gas may spread to distant ignition sources and flash back. Extinguishing Media: Foam, Water fog, Alcohol foam, Dry chemical, Carbon Dioxide, Halon. Fire Fighting Instructions: Wear self-contained breathing apparatus w/full protective clothing in chemical fires. Cool fire exposed containers to prevent rupturing. MATERIAL SAFETY DATA SHEET 320 37th Avenue, St. Charles, Illinois 60174 To Reorder Call: www.unitedlabsinc.com . www.unitedlabsinc.ca [PHONE REDACTED] Always follow Label Directions and Cautions. * Chronic 2 Moderate 4 Severe 1 Slight 3 Serious 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: n & p Page 824 of 878 Page 824 of 878 Page 824 of 878 Page 824 of 878 ---PAGE BREAK--- - 2 - 6. ACCIDENTAL RELEASE MEASURES Small Spills: Wipe up or soak up spilled material with inert absorbent material and place in a properly labeled closed container for proper disposal. Clean contaminated surface thoroughly. Large Spills: Ventilate area and eliminate all sources of ignition. Contain spill and soak up spilled material with inert absorbent material and place in a properly labeled closed container for proper disposal. Clean contaminated surface thoroughly. 7. HANDLING AND STORAGE Keep out of reach of children. Store in a cool, dry area away from heat or open flame. Do not store at temperatures above 120°F/49°C. For Industrial and Institutional use only. Pressurized container: Do not pierce or burn, even after use. Avoid prolonged exposure. Do not get this material in contact with eyes or skin. Do not use if spray button is missing or defective. NFPA Code 30B Rating: Level 3 Aerosol. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Chemical goggles are recommended. Skin: Chemical resistant gloves are recommended. Respiratory: None needed for proper use in accordance with label directions. If ventilation is not adequate to reduce vapors below TLV levels, use a NIOSH approved air purifying respirator with organic vapor cartridges. Engineering Controls: Provide local exhaust to keep vapor concentration below TLV and prevent accumulation of excessive vapors. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 44.6°F/7.2°C Specific Gravity: 0.6834 (H2O=1) Vapor Pressure: 65-75 psig @ 70F Melting Point: NA Vapor Density: NA Evaporation Rate: NA Solubility in Water: Partially pH: NA Appearance and Odor: Aerosol spray with characteristic odor. 10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: When strongly heated, as in a fire, this product may produce oxides of carbon. Chemical Stability: Stable Incompatibility: Strong oxidizing agents and nitrates. 11. TOXICOLOGICAL INFORMATION Carcinogenicity (NTP/IARC/OSHA): None California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? None 12. ECOLOGICAL INFORMATION ND 13. DISPOSAL CONSIDERATIONS Consult your local, state, provincial, and federal regulations for proper disposal guidelines. Do not puncture or incinerate containers. Disposal regulations may be different for each state and/or locality. If discarded, this product is considered a RCRA ignitable waste, D001. 14. TRANSPORT INFORMATION DOT: Available upon request TDG: Available upon request UN: Availabale upon request 15. REGULATORY INFORMATION VOC(Volatile Organic Compounds): 53.2% TSCA (Toxic Substances Control Act): Listed SARA Title III Section 302 EHS: NO SARA Title III Section 311/312: YES SARA Title III Section 313 Toxic Chemicals: n-Hexane CAS# 110-54-3 1.0% de minimis concentration WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 125 ALL STIK PREPARED BY: Tech Dept. AD Page 825 of 878 Page 825 of 878 Page 825 of 878 Page 825 of 878 ---PAGE BREAK--- There was a PDF conversion failure for - Product Name: UNITED 125 ALL STIK CAS Number: Manufacturer: United Laboratories Inc. SDS Date: 6/26/2015 To complete your binder, please link a different SDS for this product or print the SDS manually from http://www.msdsonline.com/Legacy/Partners/Show-Document/Default.aspx?ShowId=rn20F%2fuEXaQ%3d and add to your binder. We are currently researching solutions to this issue. Thank you for your patience. Page 826 of 878 Page 826 of 878 Page 826 of 878 Page 826 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 320 37th Avenue • St. Charles, Illinois 60174 • To Reorder, Call [PHONE REDACTED] PRODUCT IDENTIFICATION USE / DESCRIPTION REVISION DATE FOR MEDICAL AND UNITED 231 Industrial Strength September 10, 2003 TRANSPORTATION EMERGENCIES: VANISHING ACT Spot and Stain Remover INFOTRAC: [PHONE REDACTED] HEALTH (0 = Maximum Safety) REACTIVITY (0 = Maximum Safety) Always follow Label Directions and Cautions. Susceptible to Release of Energy. 4 Extreme. 3 High. 2 Moderate. 1 Slight. 0 Minimal. See Health Hazard Data Section of this M.S.D.S. for more detailed information. FLAMMABILITY (0 = Maximum Safety) Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated to burn. 3 Ignites at normal temperature. 0 Will not burn. 2 Ignites when moderately heated. HAZARDOUS CAS ACGIH ACGIH OSHA OTHER S.A.R.A. TITLE III COMPONENTS NUMBER TWA STEL PEL RECOMMENDED LIMITS QUANTITIES Sodium thiosulfate 7772-98-7 Not Not Not None None established established established BOILING POINT SPECIFIC GRAVITY (H20 = 1) Greater than 212°F. 1.05 VAPOR PRESSURE (mm Hg.) MELTING POINT (At 77° F) Not determined Not determined VAPOR DENSITY (Air = 1) EVAPORATION RATE Not determined (Water = 1) Approximately 1.0 SOLUBILITY IN WATER VOLATILE ORGANIC COMPOUNDS Complete (Pounds Per Gallon Of Product) None APPEARANCE AND ODOR pH Clear colorless liquid with very faint odor 12.0 - 13.0 FLASH POINT (Method Used) FLAMMABLE LIMITS LEL UEL None (Tag Closed Cup) Not applicable Not applicable Not applicable EXTINGUISHING MEDIA Water, dry chemical, carbon dioxide, foam SPECIAL FIRE FIGHTING PROCEDURES Firefighters should wear full protective equipment and NIOSH-approved self-contained breathing apparatus. Use water spray or mist to cool fire-exposed containers. UNUSUAL FIRE AND EXPLOSION HAZARDS In the presence of extreme heat (as in a fire), product may react with active metals (eg. Aluminum, Zinc, etc.) to release flammable hydrogen gas. 4 May detonate-vacate area if 2 Violent chemical change Materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. PERSONAL PROTECTION UNITED 231 HAZARDOUS COMPONENTS IDENTITY, EXPOSURE LIMITS AND S.A.R.A. TITLE III INFORMATION PHYSICAL / CHEMICAL CHARACTERISTICS FIRE AND EXPLOSION HAZARD DATA 0 2 0 PAGE (CONTINUED ON REVERSE SIDE) L A B O R A T O R I E S Page 827 of 878 Page 827 of 878 Page 827 of 878 Page 827 of 878 ---PAGE BREAK--- STABILITY: STABLE X CONDITIONS TO AVOID UNSTABLE X None known INCOMPATIBILITY (Materials To Avoid) Strong acids and oxidizers. In the presence of extreme heat (as in a fire) product may react with aluminum and other active metals to release flammable hydrogen gas. HAZARDOUS DECOMPOSITION OR BY PRODUCTS Upon very strong heating, as in a fire, this product may release carbon monoxide, carbon dioxide and oxides of phosphorous. HAZARDOUS POLYMERIZATION:WILL NOT OCCUR X CONDITIONS TO AVOID MAY OCCUR X None known HEALTH HAZARDS EYES: May cause irritation, burns and/or destruction of tissues. SKIN: May cause irritation and burns upon prolonged contact. INHALATION: Inhalilng large amounts may cause coughing and irritation of nose, throat and mucous membranes. IF SWALLOWED: May cause serious damage to the mouth, esophogus, stomach and other contacted tissues. CARCINOGENICITY: NTP? No IARC MONOGRAPHS? No OSHA REGULATED? No This product contains a chemical known to the state of California to cause cancer or reproductive toxicity? No SIGNS AND OF OVEREXPOSURE EYES: Irritation, tears, redness SKIN: Severe irritation INHALATION: Irritation of the nose, throat and lungs. IF SWALLOWED: Diarrhea and stomach upset MEDICAL CONDITIONS GENERALLY AGGRAVATED BY OVEREXPOSURE None known TARGET ORGANS: Eyes and skin EMERGENCY AND FIRST AID PROCEDURES EYES: Flush with plenty of tepid water for at least 15 minutes. Hold eyelids open during flushing. Call a physician or poison center immediately. SKIN: Flush area with water while removing contaminated clothing and shoes. Follow by washing with soap and water. If irritation persists, call a physician or poison center. INHALATION: Remove victim to fresh air. Apply CPR if needed. If irritation persists, call a physician or poison center immediately. IF SWALLOWED: DO NOT induce vomiting. Drink cold water to dilute. Never give anything by mouth to an unconscious person. Call a physician or poison center immediately. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED For small spills, flush up to one gallon of product with water to the nearest sewer to drain. For larger spills, contain and collect on suitable absorbent. Place in corrosion resistant container for proper disposal. WASTE DISPOSAL METHOD Consult local, state, and federal authorities for disposal guidelines. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Keep containers closed. Store in a cool, dry, and well ventilated area. Store away from incompatible materials. Do not let the drums freeze, as they may split or rupture. RESPIRATORY PROTECTION (Specify Type) Normally not required VENTILATION: MECHANICAL (General) LOCAL EXHAUST Provide adequate ventilation Generally adequate PROTECTIVE GLOVES EYE PROTECTION Chemically resistant gloves required for prolonged skin contact Safety glasses OTHER PROTECTIVE CLOTHING OR EQUIPMENT Shirts with long sleeves are suggested WORK HYGENIC PRACTICES Remove contaminated clothing immediately and wash with soap and water before reusing. Wash hands and face with soap and water after using this product. REACTIVITY DATA HEALTH HAZARD DATA PRECAUTIONS FOR SAFE HANDLING AND USE CONTROL MEASURES FOR USE WHERE SIGNIFICANT EYE, SKIN OR INHALATION EXPOSURE IS LIKELY PAGE UNITED 231 VANISHING ACT Page 828 of 878 Page 828 of 878 Page 828 of 878 Page 828 of 878 ---PAGE BREAK--- - 1 - UNITED 50 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 50 PINK MARVEL Cleaner Descaler February 16, 2012 HMIS III HEALTH (0 = Maximum Safety) 2 PHYSICAL HAZARD (0 = Maximum Safety) 0 Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 FLAMMABILITY (0 = Maximum Safety) 0 2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) Phosphoric acid 7664-38-2 15-40 1mg/m3 1 mg/m3 1530 mg/kg (Rat/oral) NE Ethanol, 2,2’-imiaobis n-tallow Alkyl derivs 61791-44-4 5-10 NE NE 1200-1500 Mg/kg (Rat/oral) 220 ppm @ 1 hr (Rat) 3. HAZARDS IDENTIFICATION Eyes: May cause irritation or burns. Can cause destructive burns and permanent damage. Skin: Prolonged or repeated contact with the liquid may cause irritation or burns. Inhalation: Mists of this product are irritating to the respiratory tract and may cause breathing difficulty and pulmonary edema. Ingestion: Corrosive. Causes destructive burns to mouth, throat, and stomach. 4. FIRST AID MEASURES Eyes: Flush with cool water for at least 15 minutes. Hold eyelids apart to ensure thorough rinsing of the entire surface of the eye and lids with water. Call a physician or poison center. Skin: Wash with soap and water and remove contaminated clothing. If irritation persists, call a physician or poison center. Inhalation: Remove to fresh air. Apply artificial respiration if needed. Call a physician or poison center immediately. Ingestion: DO NOT induce vomiting. Call a physician or poison center immediately. Drink large amounts of water. If vomiting occurs give fluids. Never give anything by mouth to an unconscious person. 5. FIRE FIGHTING MEASURES Flash Point (TCC): None Explosive Limits: Lower (LEL): ND Upper (UEL): ND Flame Projection (Aerosol): NA Hazardous Products of Combustion: When strongly heated, as in a fire, may decompose to phosphoric oxide fumes and acid mist. Fire and Explosion Hazards: Thermal decomposition products may be hazardous. These include phosphorous oxide fumes. Extinguishing Media: Water, Dry chemical, Carbon dioxide, Alcohol foam. Fire Fighting Instructions: Wear self-contained breathing apparatus w/full protective clothing in chemical fires. Vapors are irritating to the respiratory tract and may cause difficulty breathing and pulmonary edema. Provide protection of employees and residents. 6. ACCIDENTAL RELEASE MEASURES Small Spills: Absorb small spills with an inert material and then place in chemical waste container for disposal. Neutralize washing with base such as soda ash or lime. Flush residual spill area with large amounts of water. Exercise caution during neutralization as considerable heat may be generated. MATERIAL SAFETY DATA SHEET 320 37th Avenue, St. Charles, Illinois 60174 To Reorder Call: www.unitedlabsinc.com . www.unitedlabsinc.ca [PHONE REDACTED] Always follow Label Directions and Cautions. * Chronic 2 Moderate 4 Severe 1 Slight 3 Serious 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: p & n Page 829 of 878 Page 829 of 878 Page 829 of 878 Page 829 of 878 ---PAGE BREAK--- - 2 - Large Spills: Contain large spills with dikes and absorb with an inert material and then place in a chemical waste container. Neutralize washing with a base such as soda ash or lime. Flush residual spill area with large amounts of water. Exercise caution during neutralization as considerable heat may be generated. 7. HANDLING AND STORAGE When diluting, always add acid slowly to water and stir well to avoid spattering. NEVER ADD WATER TO ACID! Containers should be stored in a cool, dry, well-ventilated area away from incompatible materials. Exercise caution to prevent damage to or leakage from the container. Wash hands and face with soap and water after using this product. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Chemical splash goggles are recommended. Skin: Chemical resistant gloves, rubber or neoprene are recommended. Respiratory: None needed for proper use in accordance with label directions. Use a NIOSH/MSHA approved respirators where mist or spray may be generated. Engineering Controls: Provide adequate ventilation and provide local exhaust. Do not use in closed or confined spaces. Avoid creating dust or mist. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 275°F/135°C Specific Gravity: 1.185 (H2O=1) Vapor Pressure: 5.65 Melting Point: -0.5°F/-17.5°C Vapor Density: ND Evaporation Rate: ~ 1 Solubility in Water: Complete pH: 1-2 Appearance and Odor: Bright pink liquid, with mint scent. 10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: Under fire conditions, product may decompose to phosphoric oxide fumes and acid mist. Chemical Stability: Stable Incompatibility: This product reacts violently with bases, liberating heat and spattering. 11. TOXICOLOGICAL INFORMATION Carcinogenicity (NTP/IARC/OSHA): None California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? None 12. ECOLOGICAL INFORMATION ND 13. DISPOSAL CONSIDERATIONS Consult your local, state, provincial and federal regulations for proper disposal guidelines. Disposal regulations may be different for each state and/or locality. 14. TRANSPORT INFORMATION DOT: Available upon request TDG: Available upon request UN: Availabale upon request 15. REGULATORY INFORMATION VOC (Volatile Organic Compounds): None TSCA (Toxic Substances Control Act): Listed SARA Title III Section 302 EHS: None SARA Title III Section 311/312: ND SARA Title III Section 313 Toxic Chemicals: None WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 50 PINK MARVEL PREPARED BY: Sandy Kopacz Page 830 of 878 Page 830 of 878 Page 830 of 878 Page 830 of 878 ---PAGE BREAK--- There was a PDF conversion failure for - Product Name: UNITED 50 PINK MARVEL CAS Number: Manufacturer: United Laboratories Inc. SDS Date: 4/3/2015 To complete your binder, please link a different SDS for this product or print the SDS manually from http://www.msdsonline.com/Legacy/Partners/Show-Document/Default.aspx?ShowId=wwEfVONBl1E%3d and add to your binder. We are currently researching solutions to this issue. Thank you for your patience. Page 831 of 878 Page 831 of 878 Page 831 of 878 Page 831 of 878 ---PAGE BREAK--- Page 832 of 878 Page 832 of 878 Page 832 of 878 Page 832 of 878 ---PAGE BREAK--- Page 833 of 878 Page 833 of 878 Page 833 of 878 Page 833 of 878 ---PAGE BREAK--- Page 834 of 878 Page 834 of 878 Page 834 of 878 Page 834 of 878 ---PAGE BREAK--- Page 835 of 878 Page 835 of 878 Page 835 of 878 Page 835 of 878 ---PAGE BREAK--- Page 836 of 878 Page 836 of 878 Page 836 of 878 Page 836 of 878 ---PAGE BREAK--- Emergency Overview Do not taste or swallow. Effects Of Overexposure - Eye Contact: Irritating, and may injure eye tissue if not removed Effects Of Overexposure - Skin Contact: Low hazard for usual industrial handling or commercial handling by trained personnel. Effects Of Overexposure - Inhalation: No Information. Effects Of Overexposure - Ingestion: Substance may be harmful if swallowed. Effects Of Overexposure - Chronic Hazards: No Information. Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Eye Contact First Aid - Eye Contact: Hold eyelids apart and flush with plenty of water for at least 15 minutes. Get medical attention. First Aid - Skin Contact: Wash with soap and water. Get medical attention if irritation develops or persists. Material Safety Data Sheet 24 Hour Assistance: 1-[PHONE REDACTED] Rust-Oleum Corp. www.rustoleum.com Section 1 - Chemical Product / Company Information Product Name: Varathane Wood Filler Tubes Revision Date: 02/04/2005 Identification Number: 215202, 215198, 215199, 215210, 215211, 215212, 215213, 215214 Product Use/Class: Wood Filler Supplier: Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA Manufacturer: Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA Preparer: Department, Regulatory Section 2 - Composition / Information On Ingredients Chemical Name CAS Number Weight % Less Than ACGIH TLV-TWA ACGIH TLV-STEL OSHA PEL-TWA OSHA PEL-CEILING TITANIUM DIOXIDE PIGMENT 13463-67-7 1.0 10 MG/M3 15 MG/M3 AMORPHOUS SILICA 7631-86-9 1.0 10 MG/M3 6 MG/M3 Section 3 - Hazards Identification Section 4 - First Aid Measures Page 1 of 5 Page 837 of 878 Page 837 of 878 Page 837 of 878 Page 837 of 878 ---PAGE BREAK--- First Aid - Inhalation: No Information. First Aid - Ingestion: Swallowing less than an ounce will not cause significant harm. For larger amounts, do not induce vomiting, but give one or two glasses of water to drink and get medical attention. Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog Unusual Fire And Explosion Hazards: No Information. Special Firefighting Procedures: No Information. Steps To Be Taken If Material Is Released Or Spilled: No Information. Handling: Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Wash thoroughly after handling. Storage: Keep away from heat, sparks, flame and sources of ignition. Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation. Respiratory Protection: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Skin Protection: Use gloves to prevent prolonged skin contact. Eye Protection: Use safety eyewear designed to protect against splash of liquids. Other protective equipment: Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application. Hygienic Practices: Wash thoroughly with soap and water before eating, drinking or smoking. Section 5 - Fire Fighting Measures Flash Point: 240 F LOWER EXPLOSIVE LIMIT: 0.9 % (Setaflash) UPPER EXPLOSIVE LIMIT : 24.6 % Section 6 - Accidental Release Measures Section 7 - Handling And Storage Section 8 - Exposure Controls / Personal Protection Section 9 - Physical And Chemical Properties Boiling Range: 200 - 999 F Vapor Density: Heavier than air Odor: Odor Threshold: Page 2 of 5 Page 838 of 878 Page 838 of 878 Page 838 of 878 Page 838 of 878 ---PAGE BREAK--- (See section 16 for abbreviation legend) Conditions To Avoid: No Information. Incompatibility: Incompatible with strong oxidizing agents, strong acids and strong alkalies. Hazardous Decomposition: By open flame, carbon monoxide and carbon dioxide. Hazardous Polymerization: No Information. Stability: No Information. Ecological Information: Product is a mixture of listed components. Disposal Information: Dispose of material in accordance to local, state and federal regulations and ordinances. Do not allow to enter storm drains or sewer systems. Ammonia Like ND Appearance: Solid Evaporation Rate: Slower than Ether Solubility in H2O: Soluble Freeze Point: ND Specific Gravity: Vapor Pressure: ND PH: NE Physical State: Solid Section 10 - Stability And Reactivity Section 11 - Toxicological Information Product LD50: ND Product LC50: ND Chemical Name LD50 LC50 TITANIUM DIOXIDE PIGMENT AMORPHOUS SILICA 10000. Section 12 - Ecological Information Section 13 - Disposal Information Section 14 - Transportation Information DOT Proper Shipping Name: Non Hazardous Packing Group: Non Hazardous DOT Technical Name: Hazard Subclass: DOT Hazard Class: Non Hazardous Resp. Guide Page: DOT UN/NA Number: Non Hazardous Section 15 - Regulatory Information Page 3 of 5 Page 839 of 878 Page 839 of 878 Page 839 of 878 Page 839 of 878 ---PAGE BREAK--- CERCLA - SARA Hazard Category This product has been reviewed according to the EPA "Hazard Categories" promulgated under Sections 311and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: SARA Section 313: Listed below are the substances (if any) contained in this product that are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: None known Toxic Substances Control Act: Listed below are the substances (if any) contained in this product that are subject to the reporting requirements of TSCA 12(B) if exported from the United States: None known U.S. State Regulations: As follows - New Jersey Right-to-Know: The following materials are non-hazardous, but are among the top five components in this product. Right-to-Know: The following non-hazardous ingredients are present in the product at greater than California Proposition 65: These products contain no known chemicals known by the State of California to cause cancer. These products contain no known chemicals known by the State of California to cause birth defects or other reproductive harm. International Regulations: As follows - Chemical Name CAS Number Silica 14808-60-7 Water 7732-18-5 Acrylic Resin PROPRIETARY Yellow Oxide Dispersion MIXTURE Red Oxide Dispersion MIXTURE Chemical Name CAS Number Silica 14808-60-7 Water 7732-18-5 Acrylic Resin PROPRIETARY Yellow Oxide Dispersion MIXTURE Red Oxide Dispersion MIXTURE Page 4 of 5 Page 840 of 878 Page 840 of 878 Page 840 of 878 Page 840 of 878 ---PAGE BREAK--- CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings. CANADIAN WHMIS CLASS: VOLATILE ORGANIC COMPOUNDS, g/l: REASON FOR REVISION: Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined The information contained on this MSDS has been checked and should be accurate. However, it is the responsibility of the user to comply with all Federal, State, and Local laws and regulations. Section 16 - Other Information HMIS Ratings: Health: 1 Flammability: 0 Reactivity: 0 Personal Protection: X Page 5 of 5 Page 841 of 878 Page 841 of 878 Page 841 of 878 Page 841 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET OSHI\ CAM, ANSI, ~ ~ ~ .1Id EC MliOdII SAttHy Dal., SfttIOI1. otfonJcS' putlUltil" O$HA~ HQ.~ ~""on (2J Ci'R 181o.f3OO). 0 "",III _lOtapp'''.NII/Y II1/II_ PART I What is the material and what do I need to know in an emergency? TRADE NAME (AS LABELEO): CHEMICA1.. NA.MEICLASS~ SYNONYMS: PRODUCT USE: 1. PRODUCT IDENTIRCATION VICTOR LOCK DEoiCER Flammabla Aerosol Mixt1.Jre Not AppUcable SUPPL.IER/MANUFACTURER'S NAME: De-icing of I.oclan Dlaldllo (prapollanl gae) 204-11_ TIilCI WMo MInoraI 011 804204706 232-CS5-a 3.S'lIt IlOproponol 87.e300 200-IIII1-7 88.'" NE • Not EIIaIIIlIllhIld. SeoIlon '8 fer D.nnWon. DfTarma Uaod. I NOT6 WHMIS requllIId '-inCluded In oppl'aprl oactIan. ~ an tho ANSI Zo4OO.','IlIlB formal. ThIa product hn baln JQod In willi u,olmard .rIIotia at tho CPA Ind U\e MSDS conlaln tho InfonnaUon by \he CPR. PART II What shoula I do jf a hazardous situation occurs? 4. FIRST·AlD MEASURES of chemical exposure must be takan for medical attenUon. If adverse health affeels p-ccur. Rescuers should be I8,ken for medical attention. I' nBCASS8ry. Take copy of label and MSDS 10 health professional with victIm. sKIN exPOSURE: If skin contact resullS or other adverse effect. seek the advice of a doctor. EYE EXPOSURE: If this product the 'YIS, opon oyes while under genUe running waler. Use sufflalent fCrc810 open uyuJids. Havo vIctim "roll' eyos. Minimum Hushing III for 1a minutes. VIctim must Milk medical aUanUan If health 8ffec\s occur. INHALATION: If IhI5 gas Inhaled. remove to freSh air. It nocosu/y. I.ISB artJtioJaJ respJratton to suppa" vital· func:tlons. Seek If adverse effect occurs. INGESTION: Not II likely route of exposure. MEDICAL CQNDI"IONS AGGRAVATED BY EXPOSURE: Pre-existing central norvalla or skin disorders may be aggravated by this product. RECOMMENDATIONS TO PHYSICIANS: Treat sn£! eliminate overexpO&ure. VICTOR L.OCK DE·leER MIlDS EFFECTIVE DATa: AUGUST 1 B. 2007 PACIE 2 OF 12 . Page 843 of 878 Page 843 of 878 Page 843 of 878 Page 843 of 878 ---PAGE BREAK--- a. MEASURES FLASH POINT: Not determined for product. For IsopropanDI: 11 .7"C (63"Fl AUTOIGNIT!ON TEMPERATURE: Not determined for product. For Isopropanol: 39000 (750°F) FLAMMABLE UMITS Un air by voluma, 'Io): Lower Q,ELl; Not determined for product, Por Isopropanol; URgar (UELl; Not determined for product. For Isopropanol: 12.0% FIRE EXTINGUISHING MATERIALS: If this product Is Involved In I fire. use extinguishing materials appropriate for surroUnding materials. UNUSUAL FIRE AND EXPLOSION HAZARDS: The main component of NFPARATING OlHII this proc:Iuct, IsopropanOl, Is a IC flammable liquid. When Involved In II fire, this product may decompose ana produce toxic gases (Including carbon monoxidlil and carbon dioxide). Vapors of this product may form 8xploslve with air, III or above 11.7"0 (53"P). The vapolS of this product are aae Seellon 18 for heavier than air and may spread long distances; distant Igoilion Ind flash- gf back are possible. Vapors can accumulata In confined spaces, creating an oxygan-deticiantilimospnare and tillmmebUlty hszalti. §XP!oslon 10 Mechanical Imaact: Not sensitive. explosion S!!IJSIIIVllY tp Stalic Olschowo: Not SPECIAL. FIRE-FIGHTING PROCEDURES: Incipient firo responders should wear eye protection. Structural must WBlir Salf-Contained Breathing Apparat~$ and full prolectlve eQulpmenl. Move containers from tire araB If II can be . done without risk to porsonnel. Use waler spray to keep ftre-exposed containers cool. If posalble, prevent IUnoOff waler from enlerlng storm drillna, bodies of water, or other environmentally areBS. ' 6, ACCIDENTAL RELEASe MEASURES LEAK RESPONSE! A relelltie of e slogle oontolner or slIveral containers presents 8 minimal haurd. Allow centalnars to vanl and remove container for appropriate disposal, If a large qUlntIIy of oans of product II Involved, eV8CUll1e Immediate aree, Vapors of this produot Ihlln air: rallla$BS will concentrate In low-lying areas, creating pockets of an oxygen-deficient Bnd may create a flammability hazard. Uncontrolled release l'Iould be responded to by tralnod personnol using pre-planned procedures. Proper protective equipment should be used. Eliminate all sourcea of Ignition bufora cleanup opar.Uons begm, Use tools, If 8 large of product Is .Involved, the minimum personal Equlpmant should be Lavel B: Self-Contained Breathing Apparatus. Allow the prodUct to dissipate. Monitor the surrounding area for the lovel of oxygen. Monitor thll surrounding arall for combustible vapor levels. The )evel of combusUbie vapors must ba below 10% of the LEL of components (se8 Section 5, Fire-Fighting M8I1liUntS) and the atmosphere must have allea51 19.5 percenl Oxygen befora parsonnelera allowed Into the spill area, Dispose of Involved cans In accordance with applicable U.S. Federal. Stale. or local procerlul'Gs. or appropriate Canadian standards and those of EO Member Slates (see Section 13, Disposal ConsideralloM), PART III How can I preVent hazardous situations from occurring 7. HANDUNG and STORAGE WORK PRACTices AND HYOtENE PRACTICES: 00 not eat Dr while handling Ihls material. Use lIentllallon and other engineering controls to minimize potential exposure to tile aerosol of Ihls product. STORAGE AND HANDUNG PRACTICES: Siore containers in a coal, dry locellon, away rrom direct sunlight, souroos of inlense heat, or where freezing Is possible. Malerial Should be stored In secondery containers or In a diked area, 8S appropriate. store containers away from Incompatible I:hemlcels (sell SIICUon 1 D, Stability and Conlalners should be sepllrateCi from oxidizing materials by 8 minimum distance of 20 It. or by 8 bertier of non-combustible material alll.8I 5 ft. high a tire-resistance rating of a.s hOUIS., storage areas should ba'made of fire resistant materials. Post wamlng and "NO SMOKING" signs In storage and use areas, as appropriate. Have appropriate extinguishing equipment In the storage area sprinkler system, portable fire extinguishers). Inspect all Incoming containers before storage to ensure containers are properl~ labeled and not damaged. Refer to NFPA 30, Flammeble IlI1d Liqalds Code, for additional Informallon on storage. Empty containers mlly conteln residual liquid or vapors which ara nammable; therefore, empty containers should be handled with oare. Do not InCinerate empty or partially filled containers. . PROTECTIVE PRACTIC~ DURING MAINTENANCE Of CONTAMiNATED EQUIPMENT; Nat applicable. VICTOR. LOCI< DE-ICI!R. MSCS EFFECTIVE DATE: AUGUST 18.2007 PAQl1a OF 12 Page 844 of 878 Page 844 of 878 Page 844 of 878 Page 844 of 878 ---PAGE BREAK--- B. EXPOSURE CONTROLS - PERSONAL PROTECTION EXPOSURi LIMITS/GUIDELINEs: Cl16Ml~ CAS. exPOSURE UMITliIN AIR NAME ACGIH·T~V OSH, PE~ NIOSH OTHER TWA aTEL TWA 5TEI. TWA 5Ti!L IPLH .om ppm ppm ppm ppm ppm ppm C/lrIIIln Ololddo 1244H acoo 30._ 5CQO 30,000 5DOO 30,000 C,COO DPGMAI (UnroporiodoinlanQ 1375 mgIIqJ: Lo... (OlIII-RaQ 50415 mgIIIg: 1!a/IIvI0000t d OralZa T I (Ey.RIIIbIt) 100 Organa lind Spa"l (Eye); elfecl, hOI p IIIJIo (including chongct In rIghIiIg Seve", CICllIIwt.. tplcilled; Ballevicnt 1OII\nOIt".. fII-n 1 dopro8lOd 1C1MIy) . Slandatd 01111;10 TOIl (1i~liIlr 10 mv: dopronlld 8C1M1y). haltJalnallonl, LO., (0/a1oR1Ij 5000 III. Banawtoral: genmJ MCIdoI'ltD diol_ porcopClonl ana.lhalla SID1IdOld (~~bblO 100 mg12.4 LOu (OIoI-HUman) S71 mL/lql Lc,. (O ) 3!100 BoIJ • ..ran.t: houIII; _l1iii0 LOi.J> (OndoMlII1) 5712 mgl1qf: 8anav1ota1; ma: 1IIII0rai aneathotlc TDi.J> (OI1l~H""") 2QB mWfW1) , 4,0432 mgIIcg:. e.h..torat UlL,o (U/VOpcIIlItllon, Inducllol1. or chonge In blood or lnealhl1llc, eIBXIa: Related 10 Chronlo Data! unepocllled) B D11V1tg: PtW1phl11'11 and Un 1tIItI8: vue chollnoalorn. daalll lIGntIillIn: opnlIc p.rarpl. WIth 01' wIIholll TCI.D (tnh.tallon·RaI) 5CllO ppmIIl hlluraI9D TCI.D (InhIIalloM.lollO') SDOO I'fIII1I8 /IOU1'8Il3 U""IY ching.; aoh1l\1orll: ganoml.neelhillo: ~ Itlonl Boha'MllII: _ w tca.lnto_, a.NI\IknI: lamn.I "'or.tIC, fit R lIhoIIQu ocIMty (tpeCll1c VI (g"",,1II dapranod Uvor. ohtng In TOle (Or.llollat) 7 IIIL1kG17 d.ya.InIannIt"nt TCLo (Inhot.lJon.Rot) 2500 ppml811aunot2 YDI(Io IV'r WIlIIm: BlOOd: 01 1ed r.d Liver. chana : Etfoct on U\Ier. In r WlIgIl~ blood a.1JII speclDc _n;yml; a .l1lmirl. Inowd~ fI1II1lD Kldnay, IJIIIer, Bliddar. _ aUtnl108 In LIlInt TCL.o ) SODO pp1I1III /IOUI." 3 TOle (Oral.fW) 11 ,3010 mg/1cg/45 dip. composition, ohang 1n waolooolntOlmMlont gontral EndocrIIIe: oIIoet on monal"",1 Tel. (Inh.IoIIon.RQQ SOO g/m'I~ hourall22 IInIDlhoUo. otmda; Uvor. ohango.1n l w.lghi cycto daya.lnl8tl'n_ Uuor: rnulliple 01100\0: I (OmIoRal) 82 gm/ka11'2 TCLe (InhataUon·RDI) aooo ppm/8 houroi2O Spoclflo O "",mentat. AlJROII!I8hII : Uvot: In liver weIQht: BlOOd: chango' _.InI ont: NII!VO and mUllOuk11IkDbdat oyalem IrI lau~ (WaC) caunt; 1 IIIId lIGntIUon: ohIng. involving Gre I.1alDbolto; welghl Ioee or daomlOd , 110M, frem por!Ph.,..1 molar IIIM1 watght gain SUSPECTED CANCER AGENT: Components of this product ara listed by agencies tracking carcinogenic potonUal 01 chemical comppundB, 115 follows: IIIOPI\ClPYI. ALCOHOL: IARC03: (Unclollillobl In HIImano), AOGIH TLV-A4 CNO! CI_llablo p Human Carcinogen) WHITE MINeRAL OIL: IARC03' (UnoIutIIIablo III. Humano) The remaining components of tnla product Bre not found on the fOllowing lists: FEDERAL OSHA Z LIST, NTP, IARC, and CALJOSHA, ane! tl\Brofor~ are not considered to be, nor suspected 10 be, cancor,cBuslng agents by these agencies, IRRITANCY OF PRODUCT: This produot may be IrrllaUng 'f contact Is prolonged. SENSITIZATION TO THE PRODUCT: Components of this product Brl! nol known to be B human skin or respiratory REPRODUCTIVE TOXICI'l'Y INFORMATION: Listed below Is lnformallon conoemlno the effacts of tni5 produot alld lIS components on the numan reproductive systam. MutagenicIty: Components of tills produet are not reported to prod~clI mutagenic affects in human&, Oat rll available for Isopropanol In mlcroorganism$, of this prodUCt ara nat reported 10 procluce embryotoxlc affects In human. Components of this produQt lira not reported to OIIU5e teralogenle effects In humans, Reproquctiye Compooonta of this product arll nDI reported 10 causa adverse reproductive effects In humans, Animal reptoducUlIII toxiCity data are available for Isopropanol: these data werD obtained during clinical studies Dn specific animallissues exposed to of lhls compound, VICTOR L.OCK DE-ICER MSDS EFFECTIVE DATE; AUGUST 19, 2007 PAGEe OP 12 Page 847 of 878 Page 847 of 878 Page 847 of 878 Page 847 of 878 ---PAGE BREAK--- 11. TOXICOLOGICAL INFORMATION (Continued) REPRODUCTIVE TOXICITY INFORMATION A mutagen Is II chemical whiCh causes pBrmanl/nt o/JlI11l18$ til genatlc: malarial (DNA) suCh thElt the ahengss will propagate through gsneralicmallines. An is a c/iflmioaJ which "auses damsgs to II dsveloping embryo (i,e, within thlJ first /light weaks of In humans). but the damage dp,s not propagst • • !lfln.ft/Honel linN, A terlllOCI@Q Is It ohamioal whICh causes damage to e develop/nQ fatus, but the damage doss not propagate aOfOss A ceptyduo//ve IOxtn Is 1liiY liub"snoe which Interfere. In any way wllh t/111 process. BIOLOGICAL EXPOSURE INDiCES: CurrenUy, Ihere are no following Biological clIpgsure Indloel (81;18) for tile of this Ilroduot. 12. ECOLOGICAL INFORMATION ALL WORK PRACTICes MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION. ENVIRONMENTAL STABILITY: The followIng Is enlilronmon\al fate Information for components 01 tills product. ISOPROPANOl.: Terraattlal Fato: allied.., I ochomt. llIIealimaled i(lIc Q/ 25, ~ed lrom I log Kow of 0.05(2) aIId a /eIIrnlIonodelived oquDIIon. Incllool8l \hill IIIIf'IOPi'tlIlI III 10 h '1lIIY mobUlly In U. or iocpraplnoJ !ram 0Ij(f"" II IIIIpOCIocIIII be an prOCH. ~ • HontjIa Law _ or B I DXlOoIIIIIftloGtJ mImo Tho potanIiaI /Qt .oIalh~l\Qn 01 I~ lram dry aoilUrIiICto /lIII~ "'01 baeed upon a _ p at <15.4 mm Hg. 10",,_01 II raadUy In .arablc .VId ; the fling. 01 hatl'Iv BorolJlg degmtal/oo u~ a 0GWIIg0 IIU0 readily dogredoCl _ anaa,"". OQodl1lono. AqU1dlc FoIe: Baud on a cto lncallon hl llIIIIIlocI i(lIc tu. 01 25. lrom .Ia~ Kow 0/0.05 and I rogreealonodorlvod oquotIon, IncIIcatoo !hid I ~ ho rIO! evpe4IocI 10 _ III lUopandad lid. II/Id 1I0/.I 11an 'ram 'Nlllor I peeled bued upon 0 Law coru;tlnt 01 8.10X100111_ ilolnS \hII Henry'o ~IIW _"Iant and an amalion melhod, voladllz""'" tmI, I modo! tlvor IIlIII modeliaM ~ hOUlII1IIIC! 29 cIay&. roapacIlvoIy, Ac<:0IdIng 10 • ci 11bdton IICbam 11ft oaIlmaIad IIcF Q/3. from. log I 500 mglL dayI"1 ,BOO mlliL (craok cI1UI» 20 hOuri • goo m;rt. LC (Ialhead m!MoW) 1 hOur. I I ,830 rnul~ eCo (/;ntQS/plron _atIIm 72 h " ~CU (A/III".. III.) 24houra "16.700 rnQIL minnow) 24hout1 o 11.180 mgll. 4,1130 tnQII. Lc" (SIf8p1OCSpIJo/II. praboroJdeu$) 24 houtII • LCoa (l11th.1Id minnow) 48 MUll. 1 , .130 II1QiL ECa Chatton-LwoH) • 3.4a 1 , ,Il00 mg/L. LC (Ialhead minnow) 72 houno" ",180 mgII. mg/L Lc" (Oophnla "'911') 24 houra • B,5OU mg/1,' (latllied minnow) EIII hCUII" l' ,180 mgII, ec e mtnutn. 22,aoa mulL Lc", 24 ~ • 2II.IlIlO (Po rallCIII./. guppy) 7 dava • 1,080 ECooIDoplrn/JI mgJI. mg/~ mgl~ liCoo plAldo) '0 1.060 (~"l1"n CIIO.n IIrOwn ohrimp) 4 ~Cap (CIlpMla mounl) 4.Il00 mlliL mc;t. .',400 mg/L (cr kc:hub) 241loU1a. ~,IOO mlliL 13. DISPOSAL CONSIDERATIONS PREPARING WASTES FOR DISPOSAL: II'roduCl remove, Dllta 5heel for on Ihls product. ADDITIONAl. CANADIAN REGULATIONS: CANADIAN DSUNDSL INVENTORV STATUS: The component Is on tile eSl.lnventory. OTHER CANADIAN REGULATIONS: Not applicable. CANADIAN ENVIRONMENTAL PROTECTION ACt (CEPAJ PRIORITIES SUBSTANCES USTS: The compgnunl5 of this product .re not on the CE:PA Firat Priorities SubBlance Lists. CANADIAN WHMIS CLASSIFICATION and SYMElOI.S: ClUB A: COmpressed Gas CIIaa B6: Flamma biB Aeroeola Class D2B: Skin or Eye Irritation produClIS defined 8S an Aerosol, as defined In EC Directive. 7S13241I!EC. As sul:h product must be clearly lind legibly msrked Ill! follows: 'I"ressurb:ed container: pratect from sunlight Bncl do not axpose \0 temperatures exceeding 50·C. 00 not pierce or bum, avan a(tar UIIII. 00 not spray on naked flame or any Ineandescent melerlal'. ec CLASSIFICATION: Due to Ihe overall .mount of product contaIned In each can (less than 10 mL), no ot Ihls per CounCil Directive 8312eSJEEC, 18 May, 1-983, Article e, 8 PREPARED BY: DATE OF PRINTING: VICTOR LOCK DEoiCER MSDS 16. OTHER INFORMATION CHEMICAL SAFE'I'I' ASSOCIATES, PO Box 3519, La Mesa, CA91944-3519 819i87~OS August 23. 2007 EFFECTIVE D,A.TE! AUGUST 19. 2007 PAOl!80F12 Page 850 of 878 Page 850 of 878 Page 850 of 878 Page 850 of 878 ---PAGE BREAK--- 18. OTHER INFORMATION (Continued) Tho Inlannalkln canlllin.d herein 10 od on dtII call1lklorod OCOll/llte _tv I. e>q)rnood or ImpUOCI ~aRIIn~ h _"l'IIcy 0/ Ih dolo .r IhO ,..l1li0 10 lit obIaIned Irom Ih. 11\0,,01. COIpanllon 111\Il100 no fot Injury ID IN vendae or pra>OIItod by thO molGrlal U 'Hloneblo P/OCtduru.", not odh.rod 10 IIllIpuIahod In Ihl _ lhaat. AddIUonoUy, UIIIIImoIIw _ Inc. aaaumol no 'ar ~ 10 vondoo or Ihl/d pIrtI.". d by abnoImai 01 th. _I W r ulot~ ro loUawod. Funhennoro, nell umao Iho dot In hll 11M oIlhe II1II"'1. DEANmONS OF TERMS A 10'01 numbolr of and Icranyma appow on I MIICS. Some 01111 whIoh oro commonly uaed Includo1he IcIlOlolfta: CAS iI' TIlle 10 the ChoInlcal AbtIniGt S.Mco Number Ihm"~ HAZARDOUS MATERIALS IDENTIPICATION SYSTEM klenllnos IlICn eonalluon'. RATIN08 EXPOSURE LIMITS IN AIR: CEIUNa LIM!L: Tha thO! ahal nat be dod durIftg port 01 !he WOI1dnu elt/lceu",. t..oQ, Urn~ 0/ Ouonillallon. MAK: Fad 1 flopUbUc of GorII1'1~ Maldrnum ca/lOOllItaUon Vatu" In the 1MIriID Nf, Nol EatahlohOd, WIlIIII no ur. QuldoJln" "'"bIIaI1od, 11/1 arMy of NE hi mado fat , Me, Noll of Intandod Chong"- NIOSH CI!IUNG: Th. up thai ohall lID! be ._IOCI du~ng Iny poll alth. WOI'kIIQ, II InaIOntuncauo monIlOOng 1."lbIo, tho aoMlng IhaII too etllUllOd 118 .,S-nWlull TWA , clhI",,1H opeolnod) thll ohall not 1>0 II,ony nme dUMg' NIOSH RI5U: NIOSH'. ~rmlla. PIi~rml"lblo e.po.uro IJmIU OIlHA P.rml ~11!iIo. TIlle _,uro IIIIue mean. am:CIy lilt ID/IIO U • TLV, lhol ft hi by OSHA. Tho OStiA ~ble e.p. umltt _ In Ihl INII PEL. and Iha 19n IIlr Rull (fmIaI &IliJtgt; 158; 3a33145361 end 58! Q1Il TIme Walgnlod Avorqe tl(!Iaollll cancanuatiOll Ter a 8-hr (TLV, PEL) or up I lo.hr (REI.) WIlI1cday IIIId • ~O.hr wwkweak. IDLH.lmmoalar.1y Dlngerous 10 Lila and Ha.Hh: TnIII 1 rapr a _1rI1Ion from v.1llcn ano _..ape wRhIn 3DomInUlOl n.uI CIt PI/IMflGIII ~ury HAZARDOUS MAtERIALS IDENTIFICATION SYSTEM HAZARD RATINGS! TIIIa (BUng syalem a_pod by thl Not 1 PIIInI and Coaling and hU by Indualry I. identify Iht ao_ 01 mloal hobrdo. HeALTH HgyP: ~ CMJolmol HRIlrj: No h 1Ih rl.k, Irritation .r akin or eyn not IIIdn 11IfI.1fDrr. Euonll1llly PII or Or.lza • Syolnil.lIGn: ,..,.1rr\IatIng. or mInlmalall which elOlr In < 24 hauI1I lo.g. mochOntcal Drab. 01'1/ TIIIIIDIIy La Rlr. « SOOO 1IIIJo'IcII, CIormai Tukhy l.O,.R/lf or < 2DOO mgJIrG. , Inhalation fohn 1A.lloc • 20 mgII..); 1 (SIgIlt Hazard: MInor ravwvl/Jia mtY cccur; eJlQhUy or IrrllIItIIIQ. Sldn Irdiotiotr. or mildly IrrJ:illn;. eye Imillan: or ",Udly ~~11I11ng, Oral TDJdaIJy I.D Rot. lSaIo5QOQ mg/lc~, o.nnal Tt»tIdry LO.,Rol.r RlIIIII/t: • 1000.2000 Ift/IIIIe. roxJrJ/y LI< +In Rit. > 2·20 mgA.): 2 (Maaelllli Hazard: Tompal'Dly or lI\jury /1liiy aaaur. SWn fmt.fJan: 11I'I1Il1lng, prlmory 1trIIan1; 1IO~.MIz", PII or cr. 0, Ii, Syo IlIfW/IIn' lA.dol'QlOlY 10 -lilt IIr1Iollng .nd/or 00(1'001II0, "",lIIIIbIo Cllmell or ,"llIIU" cIoaring In 11021 dB)'I. > 0, 5 25. Otrl TOICIaIIy I.D" R.t > ti().SIlO rngJIcg. DfmW TOICIoItf 1.O,.R41 or Rabbit • 2(1).1000 mgll BO with .lIocIo 1rrevcroIcI. In 21 daye. J.O,. Rill: • I.~O mg/i o.os.o.s 4 (S HQIfd: Ulo-Ihrealonlng; Inljor at pel'lII1Inont domago mov rod frGm ling" II( rep ted upoOUrtI, SIIIn IIIfIaIJotr. Nat 00 net rate II • baaed o. IIdn InllaUon oIone. Eyo tnIto!lGn: Not Co nol nlit blood on aya 1trIta1lMl1llon.. Orol 1.0,. RM: 1 m;Ikg. _ TOIIioIty LD.,Rar or RlbIJIt 20 mg/I(Q To.odDilyLC +iI~ R.t 0.05 mglL), FLAMMAEIIYTY HaZARDI • lMInImaf _al,Nola thol wiD nol In .If whan _ouro to • laml>l/llura 81U'O (ISOCI'F] far. polled Ii & t. 1 mUll be ."...hoalod occur. MoIerI.1 reqvlre oanoIdanIIIIa """haling, und., ambIllit tomJ>Of1lW'" oo~1Ii1JOnI bef.ro 19nIIII:In end oom/>UaIIon can /ICCIII', 11IGIUcIU1G' M~ II1IJI will bum In Ilr WIltIl ad 10 • Itmpelllure or elu'e (ISOQiFllor • period 0' 5 mihUIU CIt : Llq!jicll, uldl and hiving • l1li.11 point II CI _113.1'0 !2!lD"F] (I.g OSI'IA Clan IIIB, or: MOIl QI'dIlWY (La waca, peper, 110.1: a (ModIlllO muat be hilled FlllIIw/y hIQh Ignitlan coeur. MaI.r111I. In 11\1& dell.... WOUld nat. IIndor nOrmal rorm huDrclaul almDopho,oa In air, but Undor hiD/! IGmpoPIIIRI ar made""o hilling may ttII vapor In auffIcIont quanUIloI 10 ptad_ haIarcIOUI In IIIr, including: hI~ne • /Ia&ho poiIIl-' orellave 37,1'0 (1I1O"Ft. Solid mat~ In th. 10IIII 0/ _ dUSI. that may bum bUllh1t gon.1IIIIy ao not /linn UP!"llve iIolld /nIIiDllAla In • mor- or ahmddod form tnat 1liiy rapidly and llaal1 fir, _ (o.g. collen, 1, hemp; Boldo Ind .amlaoUdolh.lroodily glYII orr IltunmGlo 0 (SarlIILIe liquid. and ilGl(da tho! CIIn 1>0 IQnIIad undlr .tmoOI III ImblenI Iompl/lluro candllionl. MalIIriII8 In IhII diU,"" praGu hA28tdoul atmo.p/IarH \0IIII lilt under limaol all 10....,.l1li' , lit, unaHoClod I>V IlImparatUra roodDr IilnKed UndIIr 1l1li081 la lIIo1ud1ng: LIquIdo n; • lIooh paint billow ~/l'C 173'1') Inc! hiving • bailing peW ltD' .1rIv.:W0 rl00'FJ _ billow 37,8"0 (lQII'I') [o.g. OSHA CI IS and 1°1: awcrtaIe lhal on lIQ.Daunl of ",ai, phyeIcal Iorm D1 oan form mlxlUIlIa wMh air and aro "odIIjr dla/Hlllod In air (Lg" duaIo 'f combuilibl. mIolI 0( dmpIaIa at IIquldol: MaIoII thai burn utromaly Iy by meon Of uJloGCnI,lned GlIYQII\ [6.g, dry nllracolilADN and mtn)' orgonIo potaoiIdoIll: 4 Joj0fd.Mlllerlale thai wat 1lIplcIy" oompl4lely vaporize lIa_Iphorto preeaute and hlmporaIurl or IhII ora . ",""Ily dIaporaod In III', and which IMI bum ~,lncludlng: FIIlmmIlolo ga".: mDlorla : /Int liquid or 0I110UI mlilltlallhalia IIqIJd _Ir pl url .net IluIl point beloW 22.B'C [73'FJ ond • bolDng pont belOW 37.8"C (100"1'] 'e.g. OSHA CIIIS IA; _althot !gllli' opGnl''*~'1y whon upoued ta 01 Q af fl4,4'0 r13O"F] or bol (e.g. EFFeCTIVE DATe, AUGUST 18, 2007 PAGI01QOFI2 Page 851 of 878 Page 851 of 878 Page 851 of 878 Page 851 of 878 ---PAGE BREAK--- DEFlNITlONS OF TERMS (Continued) MATERIALS IDENTIFICATION SYSTEM "ATfNI~S /contlnUed): Melnll th8t do not IOlot with wate,. Olgonia Poi"""Ito.. ~~~iO UlD' oro nOl'lNlIly _e on undor nre CoI>dllotle Ind \IIIU not IUd wUh MI.r. /!)CpItJs/Va4! S Iho! lit N UIlGUlbIl G : No Rating. !'1rophodol: N. RAtIng. No .1IowGcI. VnsIobIG R OIIw., SUbs' IhDt wi. nol poJymorizo. aocompo _donu or .II'o(no1.)j 1 (wat.r RoaoJM/y. Ihli chItIgo .r _palO upon OlIpOIIUI'O 10 molalul f"oNt/rIM: Malerill. tI1DI alO nGI'lnolJy otabIt. but CIIn bocom. u labl. at high lornpendiUn and pro"U'". ThHo tnallrilil mav r.1 with walOI, but wm no! , _ I rgy. Exp/o6~ OMolon 1.5 & I.e IUlllIAnCIIo 1/101'10 mv In 01' Utat do lUll hi"" I m ,"",Iollon ~ed Gator ProaSllI row OSHA doIInItIarI. No Riling. OIlirllZ.r.; PlOklgiIIQ Group 1II;.&lIiJlII~ any tnoIOr1III \hilI In ollllar ~11lI.1IoII Ie&laa • .mIblts a mean burning limo 1/1111 « oquallD the mootl bumlng dmt .r a 3-:1 paII'BrUm bro/ll.I_u1... lila crllerll lor Packing Group I and II aro not maL J.IiJJIila: ony mol.rial u,at 0lCh1blt8 • 'TIl"" p, 110. limo lhan « equal'. Ill. preaoura lime 01 I 1;1 lICId (85'l6)1caIlUloll6 mIxtur. IlIId Ihe _rID lor PaoIlplAeIw 011001 oro la,geIy conllnad 10 !he padatgo and praJodlon or IJu or I11III' 1IlIPedltd. An e>lJemli tire mUll nQI callie iJlalantanaouo "",,'ollon 01 QIma8t lilt 0111" _.·af pockaga. ComptOOHd G, P aouri2lld and moot OSHA IIUI c 51~.7 Pli obooIuIo at 21.1'e (70'1') (5OQ pII8J. Pyrophod..: No Rallng. CIIrIdr.1'I: P..,Jdng Group II auua: III1Y matorlol 11lI1. llIha, iJl lral"'" bJIlad. exhIbita • maon buMing lime 0' leu IIIln o.qUIII 10 lila bumIng lime of a 2;3 bramoleI kI and the crIIori. I.t Pllo1clng GIro"" I Oil maL 1.IaJj!JIJ: onv mDlIIIaI 1h81 miDlI. D maon pr tlea 11m lhan .r .quollo !hI riu 01 I 1:1 JIlIIl &odium _ .alUllAn (-)I00I mJ>duto and. !he crtle~.lor Group I notlllat. tlnS/ob'. RoIll1llVor. Subsl.,,_ Ihllt /Illy ~otIH. docompCIH, COndo.... or et 01 IIIIIbIen"omparotute 8IId/., prouuta. but he a loW hut u-'!on 0' 1ll!pIosI .uI>otancP. lIlal haV1ll • IIrII I\ozDJd ancl allhar ami"., bIe. ~td'M • millOl projocU&Jn ~rd or boJh, but a. no! hDvo • m lIWpIaoIon ~od GIIPS' Pro 61 d psi aboolUl. II 21.1'0 (7O'F) f500 pelsl· Pytophorlw. No RoUng, 0JrIcinm Pooldng Group I lil$I; 011)' lII0I. In oUllor 11"" "'"loci. """lObo I b B lime lhan tho burnbig lime of • 3.;2 potal. btanatalGIIIIUooo rnb4u.... l.iIJuldI: AnI rnIIetIoI thot aponllMOulIy Ignl whon ~ with olllu..o In , ,Nto, or whiOh 1DIh1bll mean pro_'. flu t\InI II \halt Iho pIG ra ria. Uml 0/ • 1:1 ~orIO .l1l&I (5O".6)1ca1lu10111 mixturv. Unstable R.DafVn: GUbitancol that may po~. r:tl uJ/.,.qo1 01 omblonl ternportt"'. ""ellor P_URI and a moati'll. potonllal 10 COllll<>llol nD llampo""UII and pr.o _ EJrp/oIlvta: ClvIolon 1.1 & IUbI_lIIat hi". 8 mhO oxpIoolan h_rd Dr IutY4I • pJD/eCIIorIhoard. II IIIIIlt II ono Ihat onll load 1n11an1an.""IIIy. CMI/IftU.d QUail No Rating. I'ytop/lorlDl: Ada 10 tho daOnillon 0/ ClrIdzI,.: No ,.,Ing. Unst.all R.1tCINw. Sulltdan_ IIntI mov polymerlz decompo , ndonn 0( W'ro~cl III amblonl _ pili"'",. and haVl • high po/.nUa/ 10 hIaI g..,.,.1an or oxpIooIon.). NATIONAL FIRE PROTeCTION ASSOCIA1'ION HAZARD AATINGS: HealTH HAZARD; D (motorial thai Dn OlIpOIIUII undor n conalllonl \\OUId ullilr no h\lZlIIII boyolld thoI .f ordinary oorn"".tlblo mo_a); 1 (maier"'. IIlaton _ro under lin! could ca IrrIblUan or milar MId.oJ Z (",lIonOia on Inlan", 1IlIP.'''' unde, In III pa lbla raoddUIIllnjuryj: s Ihtd CDUI~ l1DUI Iom_ .r undor mv ohon uill ca MIII,rIolI lhol will not bum und Iyplcal nre malarlole oUCh concrato, MIII/IeI8 thsl mUll bit pllhoatad 19nIt1.., can IhIe dIIQIe. ,.qUir' oonoId_ prohotdi"ll. , oil ombla", ternporatunl aJllona. beloro IgnlilOn and oomI>UtI1IOII con r 2 Matorlalo IIntI muaJ I1'I'lIIorIItaly d at erpoeed 10 lelatlvoly hIgh .rnl>Iont lomporllu,ol bltroro Ignition can OCCIU. Maleriall In 1It1. dogroo WOuld nol tma.r notml' Iorm Ol/llOpaa with air, bt4 lO1dor high _lint Iatnpotatu,... undor modi"" lIng lIQuid roIouo vapor In IIIl11c1enl qUltNIlOos tD produ ~ .tmOlp""",, with IIr. 3 UquJda and .aI'do \hit can boo 1;nIt'" aD arnblenllomporoMO 00/lCIItI0M. ~ In tIIII degr produce hamJdoUI W\IIIlir ulldar _ .1 Irnblenl I~ or. tltaugn unanoclld by Imblanl Ita readily I;riatd II_r 11111""" III ""ndillon.. 4 MatorlaJl lhIl wIIIlfll'ldl)l at camp 1y lIIportll aJ atmoaptterto prouure and nonnal amblanllompontlunt til' lItol IllS -nv dl.~ In III, II/IQ will.,.." reIIdily HAZARD: 0 MlIterlole 111111 In 11torna.1vo1 JIll nomtOlly IIIbI undor n'l 1 Motorlll. In lhem ' I/O normally IIIbIe, bul Ill.. Oln ioIcGma wOI1itb1o III _d lompototw'u .nd pn' u,1I. Z Mallrlola IhaI r.adlly dorgo WlionI OItomiell ohang. DI litMolad tompentl pmtIaufH. a Mtltarlola Utll In OlD 01 Clalunolioft 111' 1P!pl00I1 docomposltlan or IIIIJIIoofve rllellon. but Ihat raqulra a IIRlng InlUatlnO _IDII or that tnIJIl bit hoaled "" lram 1 10 4. SUb~ (2A, lB. ilia.) iliac ",ad. OIIUIr in/ormation! BI:!. ACOIH Blalaglcal Expoaunr Ind1cea, tho 1o. at alllormlnanla o.i1Ich DI. "",II 10 too oboervld n apaclmenl cotIoobId rram • haallhy worker who haa baen """,oed III III Iha IIIIml "",anI • worlcer wIlh InhokIlian to Iha TL V. ECOl.OGICAl. INFORMATION: flC II Iha a11101 ,,"don In WUIaI'. BCF. BIooo.OIntrotlo. P.r, whlan III determine II • wiD coneenl/otoln 1I1,'orma WII~ consumo pIInI or malle, modlan Itnahoid 1hII; Qo.rllolonl a' OfIWaier Ia repra_d 101' log "-01 log end II uaad to _ a .ubl~e _la, In Ihe lII1'IIl'DIImlnt. ReGULATORY INFORMATION: u.s. Ind CANADA: ACOIH: AnU,.kWI canl_ 0' W\lelnmonlBl 10$1_1 HVOlonl,", I prolaaalonalllUllOiallon which Thlt _Ion uplolna the IIJIPQOI 01 val10ue _ Ind ,.gUIII""'" en III, malOHIII, SPA 1111116 u.s. EI!\IItQmoanlal ProIoeI\all AOonCY. NI05H jj Ihto Nollenll InelJWle at Cacupallanal SIllily 8IIIl HOIIIIII. which IIthl arm of tho U.s, 0aQIIp!lllan11 SlIIoty H IIII AIIInIn Uan (OSHA). WHMIB tho C8nacIIan WOIkpilGo t.1oIarIoIII Inlorrmliion SyaI.." DOT IIIWI TO Ira IhII u.S, Oopll/llllanl 01 lind 1111 T/IIIIIIIOII Canldl, roll"'cUY1lly, B~patf\IIId Amandrnanli end UIhodzallon Act (SARA); Ih8 OIll'dIan SUb LIlt III. U.S. TOld. ConIrol Act /'I'SCA): Marine PoikIlanIllllue ~ 10 Ih8 COT: lilt ComprehenelYw Environmonlll ReopQnOo, Com_dun, lI1CI tJlIbIty 01.01 ICl!RCLA 0' Sllpertundl: Ind wntGoIa alato _10li001, Thill aio:IIon IncUlo:s In_ an tho procaultol1ll/V ~ga which 1IfIPIII' on In. "....rltoI'a pookIIlI" label. OSHA· U.S, SI'IIY end HoIIIIII EC. l!1mo n Economic ConmunllY). EUROPE: EINIlCB. 'Il1Io the Eil'Dpeln II1'IOI1IOtY at Naw.Eldadng O_ S- The ARC It Ihto Eurapoen ~m.nl ConcernInG 1M _uOnol carriage .r Dong"""," by and !he RID oro ilia InIWIIIIlonaI Regulellona In. CarrlDO' at Olngl_ - by Rail. EFFECTIVE PATEl AUG'UST 18, 2007 VICTOR l.ocl< oe-tCfR MSDS PAGlE120FU Page 853 of 878 Page 853 of 878 Page 853 of 878 Page 853 of 878 ---PAGE BREAK--- 1 Material Safety Data Sheet 0531, 0532, 0534, 0538, 0615 Vinyl Spackling Compound MSDS No. 0035 Rev. 5 Emergency Phone No. [PHONE REDACTED] - INFOTRAC SECTION 1 – PRODUCT NAME & MANUFACTURER INFORMATION PRODUCT NAME Vinyl Spackling Compound MANUFACTURER’S NAME & TELEPHONE NUMBER Red Devil, Inc. [PHONE REDACTED] STREET ADDRESS 4175 Webb Street CITY / STATE / ZIP Pryor, Oklahoma 74361 SECTION 2 – COMPOSITION / HAZARDOUS INGREDIENTS % TLV PEL UNITS PRODUCT CONSISTS OF: Aqueous Vinyl Acrylic Emulsion (mixture) < 20 NE NE Soda Lime Borosilicate (65997-17-3) < 4 NE NE Calcium Carbonate (1317-65-3) (as nuisance particulate, total) < 70 10 15 mg/m3 Amino Methyl Propanol (AMP-95) (124-68-5) < 0.10 NE NE Propylene Glycol (57-55-6) < 1 400*** NE ppm Non-hazardous ingredients * <10 NA NA *Unlisted ingredients are not considered hazardous under the OSHA Hazard Communication Standard (29 CFR 1910.1200). Inhalation not likely due to products physical state. TWA. Contains no EG. Calculated VOC: < 0.5%/wt, < 10 g/L. CARB Compliance: Yes. Prop 65 Ingredients: Yes (See Section 16) SECTION 3 – HAZARDS IDENTIFICATION PRIMARY ROUTE(S) OF ENTRY Skin Contact Skin Absorption Eye Contact Inhalation Ingestion EMERGENCY OVERVIEW White to off-white paste w/ a sweet odor. May cause eye, skin, nose, throat & respiratory tract irritation. EFFECTS OF OVEREXPOSURE May cause eye, skin, nose, throat & respiratory tract irritation. Harmful if swallowed. Inhalation of dust may result in pulmonary & respiratory damages. Prolonged or repeated exposure to dust may cause lung damage. This product may contain small amounts of vinyl acetate, identified by IARC as a potential carcinogen; however there should be minimal risk when used w/ ventilation adequate to keep the atmospheric concentration of vinyl acetate below the recommended exposure limit. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE If dry sanded, asthma & asthma-like conditions may worsen from prolonged or repeated exposure to dust. SECTION 4 – FIRST AID MEASURES SKIN CONTACT Wash w/ soap & water for @ least 15 minutes. Get medical attention if persist. Remove & wash contaminated clothing. EYE CONTACT Immediately flush w/ large quantities of water for @ least 15 minutes until irritation subsides. Get medical attention. INHALATION If inhaled, remove to fresh air. If breathing difficult, leave area to obtain fresh air. If breathing remains difficult, get medical attention. INGESTION DO NOT INDUCE VOMITING. Get immediate medical attention. Page 854 of 878 Page 854 of 878 Page 854 of 878 Page 854 of 878 ---PAGE BREAK--- 2 SECTION 5 – FIRE FIGHTING MEASURES FLAMMABLE Yes No EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam, Water Fog FLASHPOINT & METHOD >200F (Seta Closed Cup) UPPER EXPLOSIVE LIMIT BY VOLUME) NE LOWER EXPLOSIVE LIMIT BY VOLUME) NE AUTOIGNITION TEMPERTURE NE UNUSUAL FIRE & EXPLOSION HAZARDS None known. SPECIAL FIREFIGHTING PROCEDURES Wear self-contained breathing apparatus pressure demand (NIOSH approved or equivalent) & full protective gear. Use water spray to cool exposed surfaces. SECTION 6 – ACCIDENTAL RELEASE MEASURES PROCEDURES Wear proper protective equipment (Section Use absorbent material or scrape up dried material & place in approved container. SECTION 7 – HANDLING & STORAGE HANDLING PROCEDURES & EQUIPMENT Keep out of reach of children & pets. Do not take internally. Do not breathe vapors or inhale dusts of this product. Avoid contact w/ skin & eyes. Do not get on clothing. Use w/ adequate ventilation. Ensure fresh air during application & drying by opening windows & doors. STORAGE REQUIREMENTS Close container after each use. Store containers away from excessive heat & freezing. Do not store @ temperatures above 120F. Store away from caustics & oxidizers. SECTION 8 – EXPOSURE CONTROL / PERSONAL PROTECTION RESPIRATORY In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air purifying respirator w/ organic vapor cartridge may be necessary under circumstances where concentrations are expected to exceed exposure limits. Prevent build-up of dust & vapors by opening windows & doors. Wet sanding is recommended to avoid generation of dust. EYEWEAR Goggles or safety glasses w/ side shields. CLOTHING / GLOVES Gloves recommended for prolonged or repeated skin contact. HYGENIC PRACTICES Remove & wash contaminated clothing before re-use. Wash hands before breaks & @ end of workday. SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Paste ODOR & APPEARANCE Slight sweet. off-white paste. SPECIFIC GRAVITY Approximately 1.75 to 2.0 VAPOR DENSITY (AIR=1) NE EVAPORATION RATE NE BOILING RANGE NE pH Approximately 7.5 to 9.5 SOLUBILITY IN WATER NE VAPOR PRESSURE (MM Hg) NE %/WT VOLATILE (TNV) 18 to 22% SECTION 10 – STABILITY AND REACTIVITY STABILITY Yes No Stable under normal conditions. INCOMPATABILITY Yes No Incompatible w/ strong bases & strong oxidizing agents. CONDITIONS TO AVOID Excessive heat & freezing. HAZARDOUS POLYMERIZATION/HAZARDOUS DECOMPOSITION PRODUCTS Hazardous polymerization will not occur under normal conditions. Normal decomposition products, ie: COx, NOx. Page 855 of 878 Page 855 of 878 Page 855 of 878 Page 855 of 878 ---PAGE BREAK--- 3 SECTION 11 – TOXICOLOGICAL INFORMATION / CARCINOGENICITY ACGIH Silica, (14808-60-7), present in Calcium Carbonate filler is a suspected human carcinogen. Vinyl acetate (108-05-4), present in base emulsion is a confirmed animal carcinogen w/ unknown relevance to humans. OSHA NE IARC Silica, (14808-60-7), present in Calcium Carbonate filler identified as a human carcinogen. Vinyl acetate (108-05-4), present in base emulsion identified as a possible carcinogen. NTP Silica, (14808-60-7), present in Calcium Carbonate filler identified as a Known carcinogen. DATA WITH POSSIBLE RELEVANCE TO HUMANS Product may contain trace amounts of vinyl acetate, identified by IARC as a potential carcinogen. There is presently no evidence that it has caused cancer in humans. Silica is known to the State of California to cause cancer. SECTION 12 – ECOLOGICAL INFORMATION AQUATIC TOXICITY Ecological injuries are not known or expected under normal use. SECTION 13 – DISPOSAL CONSIDERATIONS WASTE DISPOSAL EPA WASTE CODE IF DISCARDED (40CFR Sec.261) Dispose of material in accordance w/ Federal, State & Local regulations. None. SECTION 14 – TRANSPORT INFORMATION SPECIAL SHIPPING INFORMATION Product not regulated by DOT. SECTION 15 – REGULATORY INFORMATION CERCLA – SARA HAZARD CATEGORY SARA 311 & 312: Immediate health hazard, Chronic health hazard. U.S. STATE REGS See Section 16. SARA 313 None. TSCA All ingredients either on TSCA Inventory or exempt. SECTION 16 – OTHER INFORMATION / SPECIAL PRECAUTIONS / LEGEND NJ Right-to-Know: (Top 5 Ingredients): Vinyl Acrylic Emulsion (mixture), Water (7732-18-5), Petroleum Distillate (64742-48-9), Soda Lime Borosilicate (Glass Bubbles) (65997-17-3), Propylene Glycol (57-55-6) Right-to-Know (Non-Haz @ Water (7732-18-5). Ingredients Known to State of California to cause cancer, birth defects or reproductive harm: Vinyl acetate (108-05-4) residual in base emulsion, Silica, (14808-60-7) @ .1 to .7%/wt in calcium carbonate filler. Canadian WHMIS Class: Not regulated. HMIS Ratings: Health: 1, Flammability: 0, Reactivity: 0, Personal Protection: X. WARNING: This product contains chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. INTERNATIONAL EMERGENCY NUMBER: [PHONE REDACTED] - INFOTRAC LEGEND: NA – Not Applicable, NE – Not Established, UN – Unavailable, VOC – Volatile Organic Compound, PEL – Permissible Exposure Limit, TLV – Threshold Limit Value, STEL – Short Term Exposure Limit, MSDS – Material Safety Data Sheet, ACGIH – American Conference of Governmental Industrial Hygienists, SARA – Superfund Amendments & Reauthorization Act of 1986, OSHA – Occupational Safety & Health Administration, HMIS – Hazardous Materials Identification System, NTP – National Toxicology Program, CEIL – Ceiling Exposure Limit, CASRN (CAS Number) – Chemical Abstracts Service Registry Number, TSCA – Toxic Substances Control Act Reviewed By: _Larry G. Brandon__________ VP Technology & General March 6, 2012__ NAME TITLE DATE The information contained herein has been developed based upon currently available scientific data. New information may be developed from time to time which may render the conclusions of this report obsolete. Therefore, no warranty is extended as to the applicability of this information to the user’s intended purpose or for the consequences of its use or misuse. Page 856 of 878 Page 856 of 878 Page 856 of 878 Page 856 of 878 ---PAGE BREAK--- Page 857 of 878 Page 857 of 878 Page 857 of 878 Page 857 of 878 ---PAGE BREAK--- Page 858 of 878 Page 858 of 878 Page 858 of 878 Page 858 of 878 ---PAGE BREAK--- Page 859 of 878 Page 859 of 878 Page 859 of 878 Page 859 of 878 ---PAGE BREAK--- Page 860 of 878 Page 860 of 878 Page 860 of 878 Page 860 of 878 ---PAGE BREAK--- Page 861 of 878 Page 861 of 878 Page 861 of 878 Page 861 of 878 ---PAGE BREAK--- Page 862 of 878 Page 862 of 878 Page 862 of 878 Page 862 of 878 ---PAGE BREAK--- Page 863 of 878 Page 863 of 878 Page 863 of 878 Page 863 of 878 ---PAGE BREAK--- Page 864 of 878 Page 864 of 878 Page 864 of 878 Page 864 of 878 ---PAGE BREAK--- Page 865 of 878 Page 865 of 878 Page 865 of 878 Page 865 of 878 ---PAGE BREAK--- page 1 of 4 HMIS Codes Health 2* Flammability 1 Reactivity 0 DATE OF PREPARATION Mar 20, 2015 MATERIAL SAFETY DATA SHEET WL8801010 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER WL8801010 PRODUCT NAME WHITE LIGHTNING® FLAME BUSTER™ Intumescent Silicone Sealant MANUFACTURER'S NAME THE SHERWIN-WILLIAMS CO. Consumer Group - Industrial Cleveland, OH 44115 Telephone Numbers and Websites Product Information (800) 241-5295 www.wlcaulk.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 9 556-67-2 ACGIH TLV Not Available 1 mm OSHA PEL Not Available 0.5 14808-60-7 Quartz ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.1 mg/m3 as Resp. Dust 3 7631-86-9 Amorphous Silica ACGIH TLV 10 mg/m3 as Dust OSHA PEL 6 mg/m3 as Dust SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE May cause allergic skin reaction in susceptible persons or skin sensitization. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. If irritation persists or occurs later, get medical attention. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. Page 866 of 878 Page 866 of 878 Page 866 of 878 Page 866 of 878 ---PAGE BREAK--- WL8801010 page 2 of 4 UEL Not Applicable LEL Not Applicable FLASH POINT Not Applicable SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PROTECTIVE EQUIPMENT Use of barrier cream on exposed skin is recommended. Page 867 of 878 Page 867 of 878 Page 867 of 878 Page 867 of 878 ---PAGE BREAK--- WL8801010 page 3 of 4 SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 10.39 lb/gal 1244 g/l SPECIFIC GRAVITY 1.25 BOILING POINT 347 - 348 °F 175 - 175 °C MELTING POINT Not Available VOLATILE VOLUME 11% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.00 lb/gal 0 g/l Less Water and Federally Exempt Solvents 0.00 lb/gal 0 g/l Emitted VOC SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide , Oxides of Nitrogen, possibility of Hydrogen Cyanide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. TOXICOLOGY DATA CAS No. Ingredient Name 556-67-2 LC50 RAT 4HR Not Available LD50 RAT Not Available 14808-60-7 Quartz LC50 RAT 4HR Not Available LD50 RAT Not Available 7631-86-9 Amorphous Silica LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. Page 868 of 878 Page 868 of 878 Page 868 of 878 Page 868 of 878 ---PAGE BREAK--- WL8801010 page 4 of 4 IMO Not Regulated for Transportation. IMO Not Regulated for Transportation. IATA/ICAO Not Regulated for Transportation. SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. CALIFORNIA PROPOSITION 65 WARNING: This product contains a chemical known to the State of California to cause cancer. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 869 of 878 Page 869 of 878 Page 869 of 878 Page 869 of 878 ---PAGE BREAK--- Safety Data Sheet Windshield De-Icer PAGE 1 of 4 SECTION I - IDENTIFICATION PRODUCT NAME: Windshield De-Icer PRODUCT CODE: 95101 PRODUCT USE: Ice removal COMPANY NAME: Lawson Products, Inc. COMPANY ADDRESS: 8770 W. Bryn Mawr Suite 900, Chicago, Il 60631 COMPANY PHONE: [PHONE REDACTED] EMERGENCY PHONE: [PHONE REDACTED] SECTION II – HAZARDS IDENTIFICATION CLASSIFICATION: Flammable Aerosol: Category 1 Dissolved Gas Actue Toxicity (Oral / Inhalation / Dermal): Category 3 Skin Irritant: Category 2 Eye Irritant: Category 2b Specific Target Organ Toxicity (Single Exposure): Category 1 HAZARD STATEMENT(S): DANGER: Extremely Flammable Aerosol Contains gas under pressure; May explode if heated. Toxic if swallowed, in contact with skin, and if inhaled. Causes eye and skin irritation. Causes damage to Eyes and Central nervous system. This product contains the following percentage of chemicals of unknown toxicity: 0% PRECAUTIONARY STATEMENTS: Keep away from heat, sparks, open flames, and hot surfaces. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Protect from sunlight. Store in a well-ventilated place. Do not expose to temperatures exceeding 50°C/122°F. Wash hands thoroughly after handling. Do not eat, drink, or smoke when using this product. Wear safety glasses and protective gloves. Do not breathe mist, vapors, or spray. If on skin: Wash with plenty of water. If skin irritation occurs: Get medical advice or attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. Take off immediately all contaminated clothing and wash before reuse. If swallowed: Immediately call a poison center or doctor. Rinse Mouth. Call a poison center or doctor if exposed or you feel unwell. Use only outdoors or in a well-ventilated area. Store locked up. Dispose of contents and container in accordance with local, state, and national regulations. If in eyes: rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: get medical attention. SYMBOL: HAZARDS NOT OTHERWISE CLASSIFIED: N/A SECTION III – COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS INGREDIENT CAS NUMBER PERCENT Carbon Dioxide 124-38-9 3-7% Ethylene Glycol 107-21-1 5-10% Isopropyl Alcohol 67-63-0 1-5% Methyl Alchol 67-56-1 60-100% SECTION IV - FIRST AID MEASURES EYES: Immediately flush with water for 15 minutes while holding eyelids open. Seek immediate medical attention. INGESTION: Seek immediate medical attention. INHALATION: Move to fresh air. If breathing is difficult, administer oxygen. If not breathing administer artificial respiration or at any sign of loss of consciousness seek immediate medical attention. SKIN: Immediately wash with soap and water for 15 minutes. ACUTE HEALTH HAZARDS: Eyes: Redness and tearing Skin: Absor\pbtion of large amounts of product causes Eye and Central nervous system damage, and possibly death. Inhalation: Anesthetic, irritation, prolonged exposure may lead to unconsciousness and death. Page 870 of 878 Page 870 of 878 Page 870 of 878 Page 870 of 878 ---PAGE BREAK--- Safety Data Sheet Windshield De-Icer PAGE 2 of 4 Oral: abdominal irritation, nausea, vomiting, and diarrhea, consumption of large quantities causes Eye, Central Nervous System damage, and death CHRONIC HEALTH HAZARDS: May cause damage to the following organs: blood, kidneys, liver, mucous membranes, bone marrow, central nervous system (CNS). NOTE TO PHYSICIAN: There is no specific treatment regimen. Treatment of overexposure should be directed at the control of and the clinical condition of the patient. SECTION V – FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA: Carbon dioxide, standard chemical fire extinguisher, and water fog. UNSUITABLE EXTINGUISHING MEDIA: Water spray/stream. SPECIAL FIRE FIGHTING PROCEDURES: Wear NIOSH approved Self Contained Breathing Apparatus with a full face piece operated in a positive pressure demand mode with full body protective clothing when fighting fires. Avoid contact with skin and breathing smoke, fumes, and decomposition products. Cool fire exposed containers with water fog to prevent bursting. UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep away from sparks, open flames, and hot surfaces. No smoking. Do not spray on an open flame or other ignition source. HAZARDOUS COMBUSTION PRODUCTS: Oxides of carbon SECTION VI – ACCIDENTAL RELEASE MEASURES PERSONAL PROTECTIVE EQUIPMENT: Refer to section VIII for proper Personal Protective Equipment. SPILL: Absorb with non-combustible material like vermiculite, sand or earth and rinse with small amount of soapy water. Do not allow to drain into sewers or storm drains. Dispose of in accordance with local, state and federal regulations. WASTE DISPOSAL: Dispose of in accordance with local, state and federal regulations. RCRA STATUS: Product should be fully characterized prior to disposal (40 CFR 261). SECTION VII – HANDLING AND STORAGE HANDLING AND STORAGE: Protect from sunlight. Store in a well-ventilated place. Do not expose to temperatures exceeding 50°C/122°F. Pressurized container: Do not pierce or burn, even after use. OTHER PRECAUTIONS: Keep out of the reach of children. INCOMPATIBILITY: Strong oxidizing agents. SECTION VIII – EXPOSURE CONTROLS/PERSONAL PROTECTION HAZARDOUS INGREDIENT OSHA PEL ACGIH TLV Carbon Dioxide 5000 ppm 5000 ppm Ethylene Glycol 125 mg/m3 100 mg/m3 Isopropyl Alcohol 400 ppm 200 ppm Methyl Alchol 200 ppm 200 ppm ENGINEERING CONTROLS / VENTILATION: General ventilation and local exhaust should be adequate. RESPIRATORY PROTECTION: Wear NIOSH/MSHA approved respiratory protection if used in confined, poorly ventilated areas. PERSONAL PROTECTIVE EQUIPMENT: Safety glasses ADDITIONAL MEASURES: Wash hands thoroughly after handling. Do not breathe vapors. Do not eat, drink, or smoke while using product. Get medical attention if you feel unwell. SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear, Colorless Aerosol ODOR: Alcohol Odor ODOR THRESHOLD: N/D BOILING POINT: > 148°F (64.4°C) FREEZING POINT: N/D FLAMMABILITY: Extremely Flammable Aerosol FLASH POINT: 65°F (18°C) AUTOIGNITION TEMPERATURE: N/D Page 871 of 878 Page 871 of 878 Page 871 of 878 Page 871 of 878 ---PAGE BREAK--- Safety Data Sheet Windshield De-Icer PAGE 3 of 4 LOWER FLAMMABILITY LIMIT: N/D UPPER FLAMMABILITY LIMIT: N/D VAPOR PRESSURE (mm Hg): 89 mmHg VAPOR DENSITY (AIR=1): > 1 EVAPORATION RATE: > 1 SPECIFIC GRAVITY (H2O=1): 0.815 @ 77° F (25° C) pH: N/A SOLIDS N/D SOLUBILITY IN WATER: 100% PARTITION COEFFICIENT: n-OCTANOL/WATER (KOW): N/D VOLATILITY INCLUDING WATER 100% VOLATILE ORGANIC COMPOUNDS (VOC): 96% DIELECTRIC STRENGTH (Volts): N/A DECOMPOSITION TEMPERATURE: N/D VISCOSITY: N/D SECTION X – STABILITY AND REACTIVITY DATA REACTIVITY: None Known CHEMICAL STABILITY: Stable CONDITIONS TO AVOID: Temperatures greater than 120°F may cause bursting. INCOMPATIBILITY: Strong oxidizing agents. HAZARDOUS DECOMPOSITION OR BY-PRODUCT: Oxides of carbon POSSIBLE HAZARDOUS REACTIONS: None Known SECTION XI – TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION: Isopropyl Alcohol (67-63-0) LD50 (Oral,Rat) 5045 mg/kg; LD50 (Oral, Rabbit) 5045 mg/kg; LD50 (Dermal, Rabbit) 12,800 mg/kg; LC50 (Inhalation, Rat, 8hr) 16,000 ppm Methyl Alcohol (67-56-1) LD50 (Oral, Man) 5628 mg/kg; LD50 (Dermal, Rabbit) 20,000 mg/kg Ethylene Glycol (107-21-1) LD50 (Oral, Rat) 4700 mg/kg; LC50 (Rat, 4 hrs) > 200 mg/m3 ROUTES OF ENTRY: Eyes, Ingestion, Inhalation, Skin EYES: Causes severe irritation, redness, tearing. INGESTION: Not a likely route of exposure under normal product handling conditions. INHALATION: Acute exposure may cause nausea, vomiting, coughing and pulmonary irritation. SKIN: Causes localized defatting, irritation. MEDICAL CONDITION AGGRAVATED: Pre-existing disorders of the skin, respiratory system, and eyes will be aggravated by over exposure. ACUTE HEALTH HAZARDS: Eyes: Redness and tearing Skin: Absor\pbtion of large amounts of product causes Eye and Central nervous system damage, and possibly death. Inhalation: Anesthetic, irritation, prolonged exposure may lead to unconsciousness and death. Oral: abdominal irritation, nausea, vomiting, and diarrhea, consumption of large quantities causes Eye, Central Nervous System damage, and death CHRONIC HEALTH HAZARDS: May cause damage to the following organs: blood, kidneys, liver, mucous membranes, bone marrow, central nervous system (CNS). CARCINOGENICITY: OSHA: No ACGIH: No NTP: No IARC: No OTHER: N/A SECTION XII – ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: Isopropyl Alcohol (67-63-0) LC50 (Fathead Minnow, 96 hrs) 100,000 mg/L Methyl Alcohol (67- 56-1) LC50 (Fathead Minnow, 96hrs) 29400 mg/L The half-life of methanol in surface water ranges from 24 - 168 hrs. Ethylene Glycol (107-21-1) LC50 (Trout, 96 hrs) 41,000 mg/L; (Water Flea, 48 hrs) 46,300 mg/L; (Bluegill Fish, 96 hrs) 34,250 mg/L; (Goldfish, 72 hrs) 34,250 mg/L BIODEGRADABILITY: This product is biodegradable. BIOACCUMULATION: This product is not expected to bioaccumulate. SOIL MOBILITY: This product is mobile in soil. OTHER ECOLOGICAL HAZARDS: None Known Page 872 of 878 Page 872 of 878 Page 872 of 878 Page 872 of 878 ---PAGE BREAK--- Safety Data Sheet Windshield De-Icer PAGE 4 of 4 SECTION XIII – DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with local, state and federal regulations. RCRA STATUS: Product should be fully characterized prior to disposal (40 CFR 261). SECTION XIV - TRANSPORTATION INFORMATION PROPER SHIPPING NAME: Aerosols, Ltd. Qty. HAZARD CLASS/DIVISION: 2.1 UN/NA NUMBER: UN 1950 PACKAGING GROUP: N/A AIR SHIPMENT PROPER SHIPPING NAME: Aerosols, Ltd. Qty. HAZARD CLASS/DIVISION: 2.1 UN/NA NUMBER: UN 1950 SHIPPING BY WATER: VESSEL (IMO/IMDG) PROPER SHIPPING NAME: Aerosols, Ltd. Qty. HAZARD CLASS/DIVISION: 2.1 UN/NA NUMBER: UN 1950 ENVIRONMENTAL HAZARDS WATER: N/A SECTION XV - REGULATORY INFORMATION TSCA STATUS: All Chemicals are listed or exempt. CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): Methanol (67-56-1) Reportable Quantity = 5,000 lbs Ethylene Glycol (107-21-1) Reportable Quantity = 5,000 lbs SARA 311/312 HAZARD CATEGORIES: Fire Hazard SARA 313 REPORTABLE INGREDIENTS: Methanol (67-56-1), Ethylene Glycol (107-21-1) CLEAN WATER ACT: None STATE REGULATIONS: Isopropyl Alcohol (67-63-0) Right-to-Know acts for Rhode Island, Florida, Minnesota, Massachusetts, New Jersey, Tennesee Connecticut hazardous material survey. Isopropyl alcohol Illinois toxic substances disclosure to employee act INTERNATIONAL REGULATIONS: All components are listed or exempted. NFPA HEALTH: 3 HMIS HEALTH: 3 NFPA FLAMMABILITY: 3 HMIS FLAMMABILITY: 3 NFPA REACTIVITY: 1 HMIS REACTIVITY: 1 NFPA OTHER: None HMIS PROTECTION: B SECTION XVI - ADDTIONAL INFORMATION PREPARATION BY: Maureen Ruggeberg, Regulatory Affairs Specialist DATE PREPARED: 01/16/2014 REVISION DATE: 10/30/2014 N/A = Not Applicable; N/D = Not Determined DISCLAIMER: To the best of our knowledge, information contained herein is accurate. However there is no assumption of liability for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazard which exists. The information contained in this SDS was obtained from current and reliable sources; however, the data is provided without any warranty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of the manufacturer, the manufacturer will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this SDS shall be created or inferred by any statement in this SDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this SDS. The user is responsible for full compliance. Page 873 of 878 Page 873 of 878 Page 873 of 878 Page 873 of 878 ---PAGE BREAK--- M A T E R I A L S A F E T Y D A T A S H E E T Page 1 of 4 Woolite Heavy Traffic Carpet Cleaner - with FibraPure HMIS HEALTH 0 FLAMMABILITY 0 REACTIVITY 0 PERSONAL PROTECTION 1 1. Product And Company Identification Distributor Manufacturer Playtex Products, Inc. Not Applicable 50 N. DuPont Highway P.O. Box 7016 Dover, DE 19903 USA Company Contact: Consumer Affairs Telephone Number: (888) 999 - 6736 FAX Number: (201) 785 - 8202 Web Site: www.playtexproductsinc.com Supplier Emergency Contacts & Phone Number Manufacturer Emergency Contacts & Phone Number Medical Emergency: (888) 879 - 3798 None Given Transportation Emergency: (703) 858 - 5744 Issue Date: 7-15-94 Issue Date: 01/29/2002 Product Name: Woolite Heavy Traffic Carpet Cleaner - with FibraPure MSDS Number: 81 Synonyms N/A Product/Material Uses Use as Labeling Instruction 2. Composition/Information On Ingredients Ingredient CAS Percent Of Name Number Total Weight Isobutane 75-28-5 1 - 10 Propane 74-98-6 1 - 10 3. Hazards Identification Primary Routes(s) Of Entry Skin Eye Hazards Overexposure may cause transient eye discomfort Page 874 of 878 Page 874 of 878 Page 874 of 878 Page 874 of 878 ---PAGE BREAK--- M A T E R I A L S A F E T Y D A T A S H E E T Page 2 of 4 Woolite Heavy Traffic Carpet Cleaner - with FibraPure 3. Hazards Identification - Continued Signs And May cause transient eye discomfort Conditions Aggravated By Exposure None known 4. First Aid Measures Eye Flush eyes immediately with running water for at least 15 minutes, while keeping the eyelids open. Consult with a physician Skin Remove contaminated clothing. Wash skin with water. If irritation occurs and/or persists or if contact has been prolonged, obtain medical attention. Ingestion Treatment of overexposure should be directed at the control of and the clinical condition. Consult with a physician immediately in all cases Inhalation Remove the subject from contaminated area. Consult with a physician in case of respiratory 5. Fire Fighting Measures Extinguishing Media CO2, dry chemical, foam, water spray Fire Fighting Instructions Product contents under pressure. Cool containers with water spray. Wear full protective equipment: eye/face (shield), body (full bunker gear), respiratory (SCBA) Flame extension: Less than 18 inches (estimated) 6. Accidental Release Measures In case of leakage or spillage: Soak up with absorbent mateial. Rinse area well to avoid slippery condition 7. Handling And Storage Handling And Storage Precautions Do not puncture or incinerate container. Do not expose to heat or store at temperatures above 120°F. Avoid freezing. Keep out of reach of children. Keep children away from newly shampoosed rugs for several hours or until thoroughly dry 8. Exposure Controls/Personal Protection Eye/Face Protection None required Skin Protection None required Respiratory Protection None required Other/General Protection Ventilation Requirements: No specific controls are needed Personal Protective Euqipment: None required Page 875 of 878 Page 875 of 878 Page 875 of 878 Page 875 of 878 ---PAGE BREAK--- M A T E R I A L S A F E T Y D A T A S H E E T Page 3 of 4 Woolite Heavy Traffic Carpet Cleaner - with FibraPure 9. Physical And Chemical Properties Appearance White aerosol foam Odor Characteristic pleasant Chemical Type: Mixture Specific Gravity: Approx. 1.0 @25°C (concentrate) Percent Volatiles: Approx. 95% Vapor Pressure: Not Determined Vapor Density: Not Determined pH Factor: 8.8-9.5 At a Concentration Of 25°C S o l u b i l i t y : Complete Freezing Point: Approx. 32°F Pressure in Can: 52-58 psig@70°F (estimated) 10. Stability And Reactivity S t a b i l i t y : Stable Hazardous Polymerization: Will not occur Conditions To Avoid (Stability) None known Incompatible Materials None known Hazardous Decomposition Products None known Conditions To Avoid (Polymerization) None known 11. Toxicological Information Eye Effects This product has not been tested for acute effects. Skin Effects Not a primary skin irritant and sensitizer Acute Oral Effects This products has not been tested for acute effects Acute Inhalation Effects Inhalation toxicity not determined Chronic/Carcinogenicity The product has not been tested as a whole for chronic effects. No ingredient is a listed carcinogen (NTP, IARC, OSHA). 12. Ecological Information Not established 13. Disposal Considerations Consumer Disposal: Discard individual container with trash Large Quantity Disposal: Degas cans and discharge liquid contents to sanitary sewer or accumulate intact cans for transport to shredder, approved incinerator or other facilty in accord with Federal, Page 876 of 878 Page 876 of 878 Page 876 of 878 Page 876 of 878 ---PAGE BREAK--- M A T E R I A L S A F E T Y D A T A S H E E T Page 4 of 4 Woolite Heavy Traffic Carpet Cleaner - with FibraPure 13. Disposal Considerations - Continued State and local law. 14. Transport Information Proper Shipping Name Woolite Heavy Traffic Carpet Cleaner - with FibraPure Hazard Class ORM-D 15. Regulatory Information U.S. Regulatory Information Exposure Limits OSHA TWA ACGIH TWA Propane 1000 ppm 1000 ppm Isobutane 800 ppm 800 ppm I SARA Section 313 Notification None CERCLA ("Superfund") Reportable Quantity: 11,800 pounds (sodium nitrate) 16. Other Information HMIS Rating H e a l t h : 0 F i r e : 0 R e a c t i v i t y : 0 Personal Protection: 1 Revision/Preparer Information MSDS Preparer: XYY MSDS Preparer Phone Number: [PHONE REDACTED] This MSDS Supercedes A Previous MSDS Dated: 07/26/2001 Other Information NFPA Aerosol Level 1 Disclaimer Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purpose(s). Playtex Products, Inc. Printed Using MSDS Generator™ 2000 Page 877 of 878 Page 877 of 878 Page 877 of 878 Page 877 of 878 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET (COMPLIES WITH 29CFR 1910.1200) SECTION I - CHEMICAL PRODUCT & COMPANY IDENTIFICATION Identity (As Used on Label and List): Xtra Duty Stripper Product Class: Water-based floor finish stripper Emergency Telephone Number: [PHONE REDACTED] Telephone Number for Information: [PHONE REDACTED] Distributed by: Dalco 300 5th Ave. NW New Brighton, Minnesota 55112 SECTION II - COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Components (Specific Chemical Identity): Chemical Common Name(s) % A 2-Butoxy Ethanol 15 - 40 CAS #111-76-2 B Potassium Hydroxide 0.5 - 1.5 CAS #1310-58-3 C Ethylene Glycol Phenyl Ether 1 - 5 CAS #122-99-6 D Ethanolamine 5 - 10 CAS #141-43-5 E Water 40 - 70 CAS #7732-18-5 SECTION III - HAZARDS IDENTIFICATION Emergency Overview Primary Hazards: Corrosive Appearance and Odor: Clear liquid, Sassafras fragrance Potential Health Hazards Route(s) of Entry: Skin Absorption: X Ingestion: Inhalation: X Eye: May cause chemical burns on contact. Skin: May cause chemical burns on contact. Ingestion: May be harmful if swallowed. Inhalation: Overexposure to butyl vapors may be harmful. Signs and of Exposure: Eye Contact: Possible burning, tearing, redness and corneal damage. Skin Contact: Possible slippery feeling, redness, swelling and burns. may be delayed. Inhalation: Overexposure to 2-Butoxy ethanol (butyl) vapors may cause central nervous system effects including drowsiness, headache, nausea and dizziness. Carcinogenicity: NTP? No IARC Monographs? No OSHA Regulated? No Target Organ Eyes, skin, liver, kidneys, system, respiratory system and blood. Medical Conditions Generally Aggravated by Exposure: N. Av. Health Hazards, Chronic: Overexposure to 2-Butoxy ethanol may cause damage to one or more of the target organs listed above. SECTION IV - FIRST AID MEASURES Emergency and First Aid Procedures: For Eye Contact: Immediately flush eyes with running water for at least 15 minutes. Obtain immediate medical attention. Continue to flush eyes until medical attention arrives. If Swallowed: Do not induce vomiting. Drink several glasses of water. Obtain immediate medical attention. For Skin Contact: Flush thoroughly with cool water. Remove and wash contaminated clothing before reuse. For Inhalation: Remove to fresh air. If irritation persists, obtain medical attention. Sources Used: Raw material data, general toxicology from the trade for similar products. SECTION V - FIRE FIGHTING MEASURES Flammability: No Autoignition Temperature: N. Ap. Flash Point (method used): None Flammable Limits: N. Ap. LEL UEL Extinguishing Media N. Ap. Water? Foam? Water Fog? Alcohol Foam? CO2? Dry Chemical? Vaporizing Liquid? Other? Special Fire Fighting Procedures: N. Ap. Unusual Fire and Explosion Hazards: N. Av. TDG Flammability Classification: Non-flammable Sensitivity to Mechanical Impact: None Sensitivity to Static Discharge: None SECTION VI - ACCIDENTAL RELEASE MEASURES Steps to be Taken in Case Material is Released or Spilled: Dike and contain spill with inert material (sand, earth, etc). Collect spill with mop, absorbent material (example: floor-dri) or vacuum. Thoroughly rinse affected area with water. SECTION VII - HANDLING AND STORAGE Precautions to be Taken in Handling and Storing: Normal care in handling and storage. Other Precautions: Keep out of reach of children. Keep from freezing. THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE, HOWEVER NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. MINUTEMAN INTERNATIONAL, INC. ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE TO VENDEES, USERS OR THIRD PARTIES CAUSED BY THE MATERIAL. SUCH VENDEES OR USERS ASSUME ALL RISKS ASSOCIATED WITH THE USE OF THE MATERIAL. SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION Respiratory Protection (Specify Types): Not required where ventilation is sufficient to maintain 2-Butoxy ethanol vapor level below listed TLV. Use NIOSH/MSHA approved organic vapor respirator in areas where vapor level exceeds TLV. Ventilation: Local Exhaust: Not required Special: Not required Mechanical (General): As required to keep vapor levels below TLV & PEL, listed in Section XI. Other: Not required Protective Gloves: Chemical Resistant. Natural rubber or Eye Protection: Approved safety goggles or shield. Footwear: Rubber footwear. Other Protective Clothing or Equipment: Not required Work/Hygienic Practices: Do not contaminate food or beverages with cleaning chemicals. SECTION IX - PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: Approximately 212°F pH: 13.5 - 14 Specific Gravity (H20) = 1: .99 % Volatile: 75 - 95 Vapor Density (Air = > 1 Odor Threshold: N. Av. Evaporation Rate (Butyl Acetate = N. Av. Oil/Water Distribution Solubility in Water: Complete Coefficient: N. Av. Vapor Pressure (MM HG): N. Av. Melting Point: N. Ap. SECTION X - STABILITY AND REACTIVITY Stability: Unstable: Stable: X Conditions to Avoid: N. Ap. Incompatibility (materials to avoid): N. Av. Hazardous Decomposition or By-products: N. Av. Hazardous Polymerization: May occur: Will not occur: X Conditions to Avoid: N. Ap. SECTION XI - TOXICOLOGICAL INFORMATION Chemical OSHA PEL ACGIH TLV Recom. LD50 LC50 A 25 ppm 25 ppm 25 ppm 1.48 g/kg N. Av. (skin) (skin) (skin) (rat, oral) B C2 mg/M3 C2 mg/M3 N. Av. 205 mg/kg N. Av. (rat, oral) C None None N. Av. 1,400-4,000 N. Av. mg/kg (rat, oral) D 3 ppm 3 ppm N. Av. N. Av. N. Av E None None N. Av. N. Av. N. Av. Teratogen, Mutagen, Reproductive Toxin Status: No data with known relevance to humans. Toxicologically Synergistic Products: N. Av. SECTION XII - ECOLOGICAL INFORMATION Ecotoxicological Information: N. Av. Chemical Fate Information: N. Av. SECTION XIII - DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose of spilled material in accordance with local, state and federal regulations. Waste from normal cleaning procedures may be sewered, depending on the materials and/or contaminates being cleaned as well as state, federal and local sewer commission regulations. RCRA Hazard Class: DOO2, characteristic corrosive. SECTION XIV - TRANSPORT INFORMATION Shipping Classification: Corrosive liquid, basic inorganic NOS (potassium hydroxide) class 8 UN Number: UN3266 Packing Group: II SECTION XV - PREPARATION DATA Prepared By: Mike Elms Telephone Number: [PHONE REDACTED] Date: 2/03 SECTION XVI - REGULATORY INFORMATION US Federal Regulations TSCA Status: All ingredients listed. CERCLA Reportable Quality: N. Av. SARA Title III Section 302 Extremely Hazardous Chemicals: None Section 311/312 Hazard Category: Immediate health, chronic health Section 313 Toxic Chemicals: Glycol ether State Regulations NOTICE STATE OF CALIFORNIA Warning: This product may contain chemicals known to the State of California to cause cancer or reproductive defects as trace impurities in the standard industrial materials used in the manufacture of this product. International Regulations WHMIS Controlled Product Hazard Class: N/A SECTION XVII - OTHER INFORMATION None N. Ap. - Not Applicable; N.Av. - Not Available NFPA SYSTEM A. Health Hazard A. Fire Hazard A. Reactivity Hazard Page 878 of 878 Page 878 of 878 Page 878 of 878 Page 878 of 878