Document douglascountywi_gov_doc_70823291fb

Safety Data Sheets Hawthorne Maintenance Closet Maintenance - Hawthorne Hwy Shop 11/16/2015 ---PAGE BREAK--- Safety Data Sheet Index Binder: Maintenance - Hawthorne Hwy Shop - Hawthorne Maintenance Closet 1PA23 - PK100 Sunscreen Towelettes 8 x 10 ITW Dymon 08/29/2006 5 3M PN07042 Tire Shine 3M - International Operations 11/19/2004 7 450 Yellow Zone Marking Paint The Valspar Corporation - Architectural Coatings Division 04/04/2012 14 Advanced Oxy Zep Commercial Sales & Services 11/27/2013 23 Bactizyme Bacterial Enzyme Drain Cleaner Nyco Products Company 07/18/2013 26 Bleach (2.0% Regular, Lemon) James Austin Company 09/30/2010 28 Calci-Solve Super Strength Descaler Nyco Products Company 12/31/2014 32 CHAMPION SPRAYON CHEWING GUM & CANDLE WAX REMOVER Chase Products Company 03/16/2015 40 CHAMPION SPRAYON X-IT-OUT VANDAL MARK REMOVER Chase Products Company 03/17/2015 47 Citra-Blaze Organic Foaming Cleaner Nyco 59 CTC 75W-90 GEAR OIL SHELL CANADA LIMITED 11/21/2011 67 DEFOAMER Spartan Chemical Company, Inc. 03/04/2015 71 DETAIL DEMON AUTO FINISH CLEANER/POLISH Nyco Products Company 01/06/2011 75 DG Auto Protectant Aiken Chemical Company, Inc. 08/30/2013 80 DUST MOP / DUST CLOTH TREATMENT (AEROSOL) Spartan Chemical Company, Inc. 05/01/2015 83 ENERGINE SPOT REMOVER 64742-89-8 Reckitt Benckiser North America, Inc. 06/06/2006 88 EUCO DIAMOND HARD Euclid Chemical Company 07/08/2012 92 Evap Pow'r-C Nu-Calgon Wholesaler, Inc. 03/21/2005 97 F-G Grout Cleaner Nyco Products Company 04/06/2012 99 FRESH LINEN AIR FRESHENER & DEODORIZER Claire Manufacturing Company 06/22/2015 101 GERMICIDAL CLEANER Claire Manufacturing Company 03/23/2015 110 GLEME GLASS CLEANER Claire Manufacturing Company 05/26/2015 119 GOJO Antibacterial Luxury Foam Handwash Chloroxylenol Liquid GOJO Industries, Inc. 02/18/2015 129 Product Name CAS Number Manufacturer Version Date Page Page 2 of 328 Page 2 of 328 Page 2 of 328 Page 2 of 328 ---PAGE BREAK--- GP Forward 8 General Purpose Cleaner Diversey, Inc. 06/25/2015 150 Graffiti & Spray Paint Remover ITW Professional Brands 11/24/2014 155 GREEN KLEEN MULTI-PURPOSE CLEANER DEGREASER Nyco Products Company 04/06/2012 169 GRITMASTER CITRA CLEAN HAND CLEANER Warsaw Chemical Company, Inc. 02/24/2015 171 Hand Sanitizer Apollo Health and Beauty Care Corporation 10/01/2014 178 Hand Soap Fair & Square 182 HARD COAT 19 FLOOR FINISH Nyco Products Company 07/03/2012 189 HOSPECO HEALTH GARDS AIR FRESHENERS: HG BABY POWDER 07909; VERY VANILLA 07915; MANGO MADNESS 07917; FRESH LINEN 07918; FRUIT BASKET 07929; ORCHARD SPICE 07930; CITRUS GROVE 07931; FRESH GARDEN 07932 HOSPECO 05/23/2012 191 Hot Shot Natural Flying Insect Killer CHEMSICO DIV OF UNITED INDUSTRIES CORP 03/11/2015 193 INSECT SHIELD Insect Repellant Towel 64-17-5 Dymon - ITW 04/11/2006 199 Kimberly Clark Professional Hand Wipes; Kimberly Clark Professional Heavy Duty Hand Cleaning Wipes; Wypall Waterless Hand Wipes Kimberly-Clark Corporation 09/05/2003 202 Microburst 3000 & 9000 Air Neutralizer- All Fragrance Rubbermaid Commercial Products' SeBreeze 3000 & 9000 Series - All Fragrance Rubbermaid Commercial Products 11/04/2013 207 MOBIL DTE OIL HEAVY Exxon Mobil Corporation 03/17/2015 210 NL262 Hi-Cling Bowl Cleaner Nyco Products Company 02/01/2000 220 Peaches N' Clean Odor Counteractant Nyco Products Company 02/05/2011 222 PURELL Advanced Instant Hand Sanitizer GOJO Industries, Inc. 02/10/2015 224 RAID ANT & ROACH KILLER1 26 (OUTDOOR FRESH) S.C. Johnson & Son, Inc. 02/24/2015 239 RAID ANT KILLER 26 (PINE FOREST FRESH) S.C. Johnson & Son, Inc. 02/24/2015 253 Shell Spirax S6 AXME 75W-90 Shell Canada Products 01/15/2015 267 SHINE -ON PRIME SOURCE 09/06/2005 274 Snow Plow Coating Total Solutions 10/06/2008 275 SPARCLING Spartan Chemical Company, Inc. 05/07/2015 277 Squeegee off Ettore Products Co. 08/18/2014 283 SST Shower, Sink & Tub Cleaner Nyco Products Company 08/02/2013 288 Product Name CAS Number Manufacturer Version Date Page Page 3 of 328 Page 3 of 328 Page 3 of 328 Page 3 of 328 ---PAGE BREAK--- Stainless Steel Cleaner Total Solutions 03/23/2004 290 SUPER FLOOR CLEANER #10 Madison Chemical Company, Inc. 04/01/2015 292 Super Toilet Bowl Cleaner Nyco Products Company 01/14/2015 298 SUPERIOR HIGH SHINE STAINLESS STEEL CLEANER & POLISH Spartan Chemical Company, Inc. 05/18/2015 306 SURE PASS Spray Buff RAMSEY COMPANY 01/11/2007 311 TNT FOAMING DISINFECTANT CLEANER Spartan Chemical Company, Inc. 05/08/2015 315 UNITED 195 SMELL JEL United Laboratories Inc. 12/22/2012 320 UNITED 231 VANISHING ACT United Laboratories Inc. 02/05/2013 322 Winter Salt Rinse The Cleaning House 01/09/2013 324 Zoom Spout Lawson Products, Inc. 08/27/2013 326 Product Name CAS Number Manufacturer Version Date Page Page 4 of 328 Page 4 of 328 Page 4 of 328 Page 4 of 328 ---PAGE BREAK--- Page 5 of 328 Page 5 of 328 Page 5 of 328 Page 5 of 328 ---PAGE BREAK--- Page 6 of 328 Page 6 of 328 Page 6 of 328 Page 6 of 328 ---PAGE BREAK--- 3M MATERIAL SAFETY DATA SHEET 3M PN07042 Tire Shine 11/19/2004 Page 1 of 7 Material Safety Data Sheet Copyright, 2004, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: the information is copied in full with no changes unless prior written agreement is obtained from 3M, and neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M PN07042 Tire Shine MANUFACTURER: 3M DIVISION: International Operations Automotive Aftermarket ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-[PHONE REDACTED] or (651) 737-6501 (24 hours) Issue Date: 11/19/2004 Supercedes Date: Initial Issue Document Group: 19-7358-5 Product Use: General Use: Used to clean wheel and tire in car. SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt GAS OIL 64741-44-2 30 - 50 LIQUEFIED PETROLEUM GAS 68476-85-7 15 - 45 WHITE MINERAL OIL (PETROLEUM) 8042-47-5 15 - 45 63148-62-9 5 - 15 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Aerosol Odor, Color, Grade: Clear liquid, solvent odor General Physical Form: Liquid Immediate health, physical, and environmental hazards: Extremely flammable liquid and vapor. Aerosol container contains flammable gas under pressure. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains flammable material under pressure. May cause target organ effects. 3.2 POTENTIAL HEALTH EFFECTS Page 7 of 328 Page 7 of 328 Page 7 of 328 Page 7 of 328 ---PAGE BREAK--- 3M MATERIAL SAFETY DATA SHEET 3M PN07042 Tire Shine 11/19/2004 Page 2 of 7 Eye Contact: Moderate Eye Irritation: may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Moderate Skin Irritation: may include localized redness, swelling, itching, and dryness. Inhalation: Upper Respiratory Tract Irritation: may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Intentional concentration and inhalation may be harmful or fatal. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: may include abdominal pain, nausea, diarrhea and vomiting. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If develop, get medical attention. If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point -156 ºF [Details: Based on LP Gas] Page 8 of 328 Page 8 of 328 Page 8 of 328 Page 8 of 328 ---PAGE BREAK--- 3M MATERIAL SAFETY DATA SHEET 3M PN07042 Tire Shine 11/19/2004 Page 3 of 7 Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Extremely flammable liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains flammable material under pressure. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-[PHONE REDACTED]) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non- sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that can dissolve in water. An AR - AFFF type foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with detergent and water. Seal the container. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. Do not pierce or burn container, even after use. No smoking while handling this material. Do not spray near flames or sources of ignition. Avoid breathing of vapors, mists or spray. Aerosol container contains flammable gas under pressure. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. For industrial or professional use only. Avoid contact with oxidizing agents. 7.2 STORAGE Store away from acids. Store away from heat. Store out of direct sunlight. Keep container closed. Do not store containers on Page 9 of 328 Page 9 of 328 Page 9 of 328 Page 9 of 328 ---PAGE BREAK--- 3M MATERIAL SAFETY DATA SHEET 3M PN07042 Tire Shine 11/19/2004 Page 4 of 7 their sides. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Do not use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Indirect Vented Goggles. 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface pressure demand self-contained breathing apparatus. Consult the current 3M Respiratory Selection Guide for additional information or call 1-[PHONE REDACTED] for 3M technical assistance. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information LIQUEFIED PETROLEUM GAS ACGIH TWA 1000 ppm LIQUEFIED PETROLEUM GAS OSHA TWA 1000 ppm Table Z-1A OIL MIST, MINERAL ACGIH TWA, as mist 5 mg/m3 OIL MIST, MINERAL ACGIH STEL, as mist 10 mg/m3 OIL MIST, MINERAL OSHA TWA, as mist 5 mg/m3 Table Z-1 WHITE MINERAL OIL (PETROLEUM) CMRG TWA 5 mg/m3 WHITE MINERAL OIL (PETROLEUM) CMRG STEL 10 mg/m3 SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Aerosol Odor, Color, Grade: Clear liquid, solvent odor General Physical Form: Liquid Page 10 of 328 Page 10 of 328 Page 10 of 328 Page 10 of 328 ---PAGE BREAK--- 3M MATERIAL SAFETY DATA SHEET 3M PN07042 Tire Shine 11/19/2004 Page 5 of 7 Autoignition temperature No Data Available Flash Point -156 ºF [Details: Based on LP Gas] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available Boiling point No Data Available Density No Data Available Vapor Density No Data Available Vapor Pressure No Data Available Specific Gravity No Data Available pH Not Applicable Melting point No Data Available Solubility in Water Complete SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: Heat; Avoid shock or friction.; Combustibles; High shear and high temperature conditions; Sparks and/or flames Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Formaldehyde During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. Page 11 of 328 Page 11 of 328 Page 11 of 328 Page 11 of 328 ---PAGE BREAK--- 3M MATERIAL SAFETY DATA SHEET 3M PN07042 Tire Shine 11/19/2004 Page 6 of 7 SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. Facility must be capable of handling aerosol cans. Dispose of empty product containers in a sanitary landfill. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. STATE REGULATIONS Contact 3M for more information. CHEMICAL INVENTORIES All the components of this product are listed on China's Inventory of Chemical Substances. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. Page 12 of 328 Page 12 of 328 Page 12 of 328 Page 12 of 328 ---PAGE BREAK--- 3M MATERIAL SAFETY DATA SHEET 3M PN07042 Tire Shine 11/19/2004 Page 7 of 7 This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 2 Flammability: 4 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. No revision information is available. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M are available at www.3M.com Page 13 of 328 Page 13 of 328 Page 13 of 328 Page 13 of 328 ---PAGE BREAK--- Material Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION Product Identification Product ID: 1C72302 Product Name: 450 Yellow Zone Marking Paint Product Use: Paint product. Print date: 09/Apr/2012 Revision Date: 04/Apr/2012 Company Identification The Valspar Corporation - Architectural Coatings Division 1191 Wheeling Road Wheeling, IL 60090 Manufacturer's Phone: 1-[PHONE REDACTED] 24-Hour Medical Emergency Phone: 1-[PHONE REDACTED] 2. HAZARDS IDENTIFICATION Primary Routes of Exposure: Inhalation Ingestion Skin absorption Eye Contact: • Moderate eye irritation Skin Contact: • Causes skin irritation. • Dermatitis • May cause defatting of the skin. Ingestion: • Irritation of the mouth, throat, and stomach. • Aspiration hazard if swallowed - can enter lungs and cause damage. Product ID: 1C72302 Page 1 / 9 Page 14 of 328 Page 14 of 328 Page 14 of 328 Page 14 of 328 ---PAGE BREAK--- Inhalation: • Causes respiratory tract irritation. • Harmful by inhalation. Target Organ and Other Health Effects: • Kidney injury may occur. • Causes headache, drowsiness or other effects to the central nervous system. • Liver injury may occur. This product contains ingredients that may contribute to the following potential chronic health effects: • Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. • Prolonged exposure over TLV may produce pneumoconiosis. • Chronic exposure may cause permanent damage of health. • Prolonged exposure to respirable quartz silica may cause delayed chronic injury (silicosis). Carcinogens: • Possible cancer hazard. Contains material which may cause cancer based on animal data. • Cancer hazard. Contains material which can cause cancer. 3. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS Ingredient Name CAS-No. Approx. Weight % Chemical Name MINERAL SPIRITS 64742-47-8 15 - 20 Petroleum distillates, hydrotreated light PROPRIETARY INERT 15 - 20 PROPRIETARY INERT TALC 14807-96-6 15 - 20 Talc (Mg3H2(SiO3)4) PROPRIETARY INERT 5 - 10 PROPRIETARY INERT NAPHTHA 64742-89-8 5 - 10 SOLVENT NAPHTHA, PETROLEUM, LIGHT ALIPH TITANIUM DIOXIDE 13463-67-7 5 - 10 Titanium dioxide STODDARD SOLVENT 8052-41-3 1 - 5 Stoddard solvent SILICA 14808-60-7 .1 - 1 QUARTZ (Si02) 100-41-4 .1 - 1 Ethyl benzene If this section is blank there are no hazardous components per OSHA guidelines. 4. FIRST AID MEASURES Eye Contact: Get medical attention, if develop or persist. Immediately flush eye(s) with plenty of water. Remove any contact lenses and open eyes wide apart. Skin Contact: Remove contaminated clothing and shoes. Wash off immediately with plenty of water for at least 15 minutes. Get medical attention, if develop or persist. Product ID: 1C72302 Page 2 / 9 Page 15 of 328 Page 15 of 328 Page 15 of 328 Page 15 of 328 ---PAGE BREAK--- Ingestion: Rinse mouth with water. Give one or two glasses of water. Only induce vomiting at the instruction of medical personnel. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If vomiting occurs, keep head lower than hips to prevent aspiration. Get medical attention immediately. Inhalation: Move injured person into fresh air and keep person calm under observation. Get medical attention immediately. Medical conditions aggravated by exposure: Any respiratory or skin condition. 5. FIRE FIGHTING MEASURES Flash point (Fahrenheit): 52 Flash point (Celsius): 11 Lower explosive limit 1 Upper explosive limit 7 Autoignition temperature: not determined Sensitivity to impact: no Sensitivity to static discharge: Subject to static discharge hazards. Please see bonding and grounding information in Section 7. Hazardous combustion products: See Section 10. Unusual fire and explosion hazards: Contaminated rags, wipes, saw dust, etc., may catch fire spontaneously. Store waste under water in closed metal containers or in approved self-closing containers designed to prevent spontaneous combustion until disposed of in compliance with applicable regulations. Oxidizing Material Extinguishing media: Carbon dioxide, dry chemical, foam and/or water fog. Fire fighting procedures: Firefighters should be equipped with self-contained breathing apparatus and turn out gear. Keep containers and surroundings cool with water spray. 6. ACCIDENTAL RELEASE MEASURES Action to be taken if material is released or spilled: Ventilate the area. Avoid breathing dust or vapor. Use self-containing breathing apparatus or airmask for large spills in a confined area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 7, "Handling and Storage", for proper container and storage procedures. Remove all sources of ignition. Soak up with inert absorbent material. Use only non-sparking tools. Avoid contact with eyes. 7. HANDLING AND STORAGE Precautions to be taken in handling and storage: Keep away from heat, sparks and open flame. - No smoking. Keep container closed when not in use. Do not store above 120 degrees F. (49 degrees Based on flash point and vapor pressure, suitable storage should be provided in accordance with OSHA regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty containers may contain product residue, including flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must be observed until the container has been commercially cleaned or reconditioned. If the product is used near or above the flashpoint, an ignition hazard may be present. Activities, uses, or operations which liberate vapor (such as mixing or free fall of liquids) may also present an ignition hazard. Please ensure containers and other interconnected equipment are properly bonded and grounded at all times. 8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS Personal Protective Equipment Product ID: 1C72302 Page 3 / 9 Page 16 of 328 Page 16 of 328 Page 16 of 328 Page 16 of 328 ---PAGE BREAK--- Eye and face protection: Wear safety glasses or goggles to protect against exposure. Skin protection: Appropriate chemical resistant gloves should be worn. Other Personel Protection Data: To prevent skin contact wear protective clothing covering all exposed areas. Respiratory protection: If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an air purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's literature to ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's instructions. Ventilation Use only in well-ventilated areas. Ensure adequate ventilation, especially in confined areas. Ovens used for curing should contain a fresh air purge to prevent vapours from accumulating and creating a possible explosive mixture. Where the product is used in a hazardous classified area, use explosion-proof electrical/ventilating/lighting/equipment. Exposure Guidelines OSHA Permissible Exposure Limits (PEL's) Ingredient Name CAS-No. Approx. Weight % TWA (final) Ceilings limits (final) Skin designations PROPRIETARY INERT 15 - 20 15 mg/m3 TWA dust total 5 mg/m3 TWA respirable fraction TALC 14807-96-6 15 - 20 Respirable. Listed. Total dust. Listed. PROPRIETARY INERT 5 - 10 15 mg/m3 TWA dust total 5 mg/m3 TWA respirable fraction TITANIUM DIOXIDE 13463-67-7 5 - 10 15 mg/m3 TWA dust total STODDARD SOLVENT 8052-41-3 1 - 5 2900 mg/m3 TWA 500 ppm TWA SILICA 14808-60-7 .1 - 1 (30)/(%SiO2 + 2) mg/m3 TWA, total dust (250)/(%SiO2 + 5) TWA, respirable fraction (10)/(%SiO2 + 2) mg/m3 TWA, respirable fraction 100-41-4 .1 - 1 100 ppm TWA 435 mg/m3 TWA ACGIH Threshold Limit Value (TLV's) Ingredient Name CAS-No. Approx. Weight % TWA STEL Ceiling limits Skin designations PROPRIETARY INERT 15 - 20 10 mg/m3 Inhalable particles. 3 mg/m3 Respirable particles. Product ID: 1C72302 Page 4 / 9 Page 17 of 328 Page 17 of 328 Page 17 of 328 Page 17 of 328 ---PAGE BREAK--- Ingredient Name CAS-No. Approx. Weight % TWA STEL Ceiling limits Skin designations TALC 14807-96-6 15 - 20 2 mg/m3 TWA respirable fraction, particulate matter containing no asbestos and silica PROPRIETARY INERT 5 - 10 2 mg/m3 TWA respirable fraction, particulate matter containing no asbestos and silica TITANIUM DIOXIDE 13463-67-7 5 - 10 10 mg/m3 TWA STODDARD SOLVENT 8052-41-3 1 - 5 100 ppm TWA SILICA 14808-60-7 .1 - 1 0.025 mg/m3 TWA respirable fraction 100-41-4 .1 - 1 100 ppm TWA 125 ppm STEL 9. PHYSICAL PROPERTIES Odor: Normal for this product type. Physical State: liquid pH: not determined Vapor pressure: 103 mmHg @ 100ºF (37.78ºC) Vapor density (air = 1.0): 5.1 Boiling point: not determined Solubility in water: not determined Coefficient of water/oil distribution: not determined Density (lbs per US gallon): 11.14 Specific Gravity: 1.33 Evaporation rate (butyl acetate = 1.0): 1.4 Flash point (Fahrenheit): 52 Flash point (Celsius): 11 Lower explosive limit 1 Upper explosive limit 7 Autoignition temperature: not determined 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions. Conditions to Avoid: Heat. Incompatibility: Strong oxidizing agents Hazardous Polymerization: None anticipated. Hazardous Decomposition Products: Silicon dioxide. Carbon monoxide and carbon dioxide. Metal oxide fumes. Sensitivity to static discharge: Subject to static discharge hazards. Please see bonding and grounding information in Section 7. Product ID: 1C72302 Page 5 / 9 Page 18 of 328 Page 18 of 328 Page 18 of 328 Page 18 of 328 ---PAGE BREAK--- 11. TOXICOLOGICAL INFORMATION Ingredient Name CAS-No. Approx. Weight % NIOSH - Selected LD50s and LC50s MINERAL SPIRITS 64742-47-8 15 - 20 > 2000 mg/kg Dermal LD50 Rabbit > 5.2 mg/L Inhalation LC50 Rat 4 h > 5000 mg/kg Oral LD50 Rat NAPHTHA 64742-89-8 5 - 10 = 3000 mg/kg Dermal LD50 Rabbit = 5000 mg/kg Oral LD50 Mouse TITANIUM DIOXIDE 13463-67-7 5 - 10 > 10000 mg/kg Oral LD50 Rat SILICA 14808-60-7 .1 - 1 = 500 mg/kg Oral LD50 Rat 100-41-4 .1 - 1 = 15354 mg/kg Dermal LD50 Rabbit = 17.2 mg/L Inhalation LC50 Rat 4 h = 3500 mg/kg Oral LD50 Rat Mutagens/Teratogens/Carcinogens: Possible cancer hazard. Contains material which may cause cancer based on animal data. Cancer hazard. Contains material which can cause cancer. Contains which has been determined by NTP to be an animal carcinogen with no known relevance to humans. IARC has classified as possibly carcinogenic to humans (2b) on the basis of sufficient evidence of carcinogenicity in laboratory animals but inadequate evidence of cancer in humans. Contains TIO2 which is listed by IARC as a possible human carcinogen (Group 2B) based on animal data. Neither long term animal studies, nor human epidemiology studies of workers exposed to TIO2 provide an adequate basis to conclude TIO2 is carcinogenic. TIO2 is not classified as a carcinogen by NTP, U.S. OSHA, or the U.S. EPA. Contains silica. The IARC has determined that silica inhaled in the form of quartz or cristobablite from occupational sources is carcinogenic to humans (group Refer to IARC monograph 68 in conjunction with the use of these materials. Risk of cancer depends on the duration and level of exposure. In coatings products, risk is due primarily to inhalation of sanding dusts or respirable particles in spray mists. The NTP has also determined that silica is a known human carcinogen in the form of fine, breathable particles. Risk of cancer depends on duration and level of exposure in coatings products, risk is due primarily to inhalation of sanding dust or respirable particles in spray mist. Ingredient Name CAS-No. Approx. Weight % California Prop 65 - Reproductive (Female) California Prop 65 - Carcinogen SILICA 14808-60-7 .1 - 1 Listed. initial date 10/1/88 - carcinogen 100-41-4 .1 - 1 Listed. initial date 6/11/04 - carcinogen Ingredient Name CAS-No. Approx. Weight % IARC Group 1 - Human Evidence IARC Group 2A - Limited Human Data IARC Group 2B - Sufficient Animal Data TITANIUM DIOXIDE 13463-67-7 5 - 10 Monograph 47 [1989] SILICA 14808-60-7 .1 - 1 Monograph 68 [1997] 100-41-4 .1 - 1 Monograph 77 [2000] Product ID: 1C72302 Page 6 / 9 Page 19 of 328 Page 19 of 328 Page 19 of 328 Page 19 of 328 ---PAGE BREAK--- Ingredient Name CAS-No. Approx. Weight % NTP Known Carcinogens NTP Suspect Carcinogens NTP Evidence of Carcinogenicity TALC 14807-96-6 15 - 20 male rat-some evidence; female rat-clear evidence; male mice-no evidence; female mice- no evidence TITANIUM DIOXIDE 13463-67-7 5 - 10 male rat-negative; female rat-negative; male mice-negative; female mice-negative SILICA 14808-60-7 .1 - 1 Known Human Carcinogen 100-41-4 .1 - 1 male rat-clear evidence; female rat-some evidence; male mice- some evidence; female mice-some evidence Ingredient Name CAS-No. Approx. Weight % OSHA - Hazard Communication Carcinogens OSHA - Specifically Regulated Carcinogens ACGIH Carcinogens TITANIUM DIOXIDE 13463-67-7 5 - 10 Present SILICA 14808-60-7 .1 - 1 Present A2 Suspected Human Carcinogen 100-41-4 .1 - 1 Present A3 Confirmed Animal Carcinogen with Unknown Relevance to Humans 12. ECOLOGICAL DATA No information on ecology is available. 13. DISPOSAL CONSIDERATIONS Disposal should be made in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION U.S. Department of Transportation UN ID Number (msds): UN1263 Proper Shipping Name: PAINT Hazard Class: 3 Packing Group: II U.S Hazmat and/or International DG shipment exceptions The supplier may apply one of the following exceptions: Combustible Liquid, Consumer Commodity, Limited Quantity, Viscous Liquid, Does Not Sustain Combustion, or others, as allowed under 49CFR Hazmat Regulations. Please consult 49CFR Subchapter C to ensure that subsequent shipments comply with these exceptions. Reportable Quantity Description: International Air Transport Association (IATA): UN ID Number (msds): UN1263 Proper Shipping Name: Paint Product ID: 1C72302 Page 7 / 9 Page 20 of 328 Page 20 of 328 Page 20 of 328 Page 20 of 328 ---PAGE BREAK--- Hazard Class: 3 Packing Group: II International Maritime Organization (IMO): IMO UN/ID Number (msds): UN1263 Proper Shipping Name: PAINT Hazard Class: 3 Packing Group: II 15. REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: Ingredient Name CAS-No. Approx. Weight % SARA 302 SARA 313 CERCLA RQ in lbs. 100-41-4 .1 - 1 form R reporting required for 1.0% de minimis concentration 1000 SARA 311/312 Hazard Class: Acute: yes Chronic: yes Flammability: yes Reactivity: no Sudden Pressure: no U.S. STATE REGULATIONS: Right to Know: The specific chemical identity of a component may be withheld as a trade secret under 34 Code, Chapter 317. Right To Know: PROPRIETARY INERT Trade Secret PROPRIETARY INERT Trade Secret TITANIUM DIOXIDE 13463-67-7 TALC 14807-96-6 MINERAL SPIRITS 64742-47-8 NAPHTHA 64742-89-8 STODDARD SOLVENT 8052-41-3 Additional Non-Hazardous Materials PROPRIETARY RESIN Trade Secret California Proposition 65: WARNING: This product contains chemicals known to the State of California to cause cancer. Rule 66 status of product Not photochemically reactive. INTERNATIONAL REGULATIONS - Chemical Inventories US TSCA Inventory: All components of this product are in compliance with U.S. TSCA Chemical Substance Inventory Requirements. Canada Domestic Substances List: All components of this product are listed on the Domestic Substances List. Product ID: 1C72302 Page 8 / 9 Page 21 of 328 Page 21 of 328 Page 21 of 328 Page 21 of 328 ---PAGE BREAK--- 16. OTHER INFORMATION HMIS Codes Health: 2* Flammability: 3 Reactivity: 1 PPE: X - See Section 8 for Personal Protective Equipment (PPE). Abbreviations: OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer, NIOSH - National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH - American Conference of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management District, TSCA - Toxic Substances Control Act, IATA - International Air Transport Association, IMO - International Maritime Organization, DOT - Department of Transportation, NA - Not applicable, NOT ESTAB - Not established, N.A.V. - Not available, RQ - Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams per liter, MM - Millimeters, - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per thousand, TCC/PM - Tag closed cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time Weighted Average, STEL - Short term exposure limit, C - Celsius, F - Fahrenheit. Disclaimer: The data on this sheet represent typical values. Since application variables are a major factor in product performance, this information should serve only as a general guide. Valspar assumes no obligation or liability for use of this information. UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES, EXPRESS OR IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. VALSPAR WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only remedy for any defect in this product is the replacement of the defective product, or a refund of its purchase price, at our option. This MSDS contains additional information required by the state of Preparation Information: Prepared By: Regulatory Affairs Department Print date: 09/Apr/2012 Revision Date: 04/Apr/2012 Product ID: 1C72302 Page 9 / 9 Page 22 of 328 Page 22 of 328 Page 22 of 328 Page 22 of 328 ---PAGE BREAK--- Safety Data Sheet Date of issue 11/27/13 Product name Advanced Oxy Product code ZUOXSR Supersedes 09/19/11 Emergency Telephone Numbers For MSDS Information: Compliance Services 1-877-I-BUY-ZEP (428-9937) For Medical Emergency (877) 541-2016 Toll Free - All Calls Recorded For Transportation Emergency CHEMTREC: (800) 424-9300 - All Calls Recorded In the District of Columbia (202) 483-7616 Prepared By Compliance Services 1259 Seaboard Industrial Blvd. Atlanta, GA 30318 Section 1. Chemical Product and Company Identification Zep Commercial Sales & Service 1310 Seaboard Industrial Blvd. Atlanta, GA 30318 1-888-805-HELP (4357) www.zepcommercial.com Emergency overview CAUTION CAUSES EYE IRRITATION. *Hazard Determination System (HDS): Health, Flammability, Reactivity Acute Effects Eyes Skin Inhalation Ingestion Routes of Entry Dermal contact. Eye contact. Inhalation. NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse effects are lessened by following all prescribed safety precautions, including the use of proper personal protective equipment. Chronic effects Contains material which may cause damage to the following organs: blood, lungs, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea. Repeated or prolonged contact with spray or mist may produce chronic eye irritation and severe skin irritation. Section 2. Hazards Identification 1 0 0 No known acute effects of this product resulting from inhalation. May be harmful if swallowed. May cause burns to mouth, throat and stomach. Prolonged or repeated contact may dry skin and cause irritation. Skin inflammation is characterized by itching, scaling, or reddening. Causes eye irritation. Inflammation of the eye is characterized by redness, watering and itching. Liquid in eye may cause irritation with possible damage if not rinsed immediately. Additional information: See toxicological information (Section 11) Carcinogenicity Classification No known significant effects or critical hazards. Section 3. Composition/Information on Ingredients Name % CAS number hydrogen peroxide 7722-84-1 1 - 5 Eye Contact Skin Contact Inhalation Ingestion Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Get medical attention if irritation develops. Move exposed person to fresh air. If irritation persists, get medical attention. Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If affected person is conscious, give plenty of water to drink. Get medical attention immediately. Section 4. First Aid Measures Page: 1/3 Page 23 of 328 Page 23 of 328 Page 23 of 328 Page 23 of 328 ---PAGE BREAK--- Safety Data Sheet Product Name Advanced Oxy Product code ZUOXSR Closed cup: >93.33°C (>200°F) Flash Point Not available. National Fire Protection Association 1 0 0 Flammable Limits Flammability Fire hazard In a fire or if heated, a pressure increase will occur and the container may burst. Non-combustible. Fire-Fighting Procedures Use an extinguishing agent suitable for the surrounding fire. Fire-fighters should wear appropriate protective equipment. Section 5. Fire Fighting Measures Spill Clean up Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Section 6. Accidental Release Measures Handling Storage Put on appropriate personal protective equipment (see Section Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Do not ingest. Wash thoroughly after handling. Do not reuse container. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Keep out of the reach of children. Section 7. Handling and Storage Personal Protective Equipment (PPE) Eyes Body Respiratory Safety glasses. For prolonged or repeated handling, use the following type of gloves: Rubber gloves. No special ventilation requirements. Section 8. Exposure Controls/Personal Protection Ingredient Exposure limits hydrogen peroxide ACGIH TLV (United States, 3/2012). TWA: 1 ppm 8 hours. TWA: 1.4 mg/m³ 8 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 1 ppm 8 hours. TWA: 1.4 mg/m³ 8 hours. NIOSH REL (United States, 1/2013). TWA: 1 ppm 10 hours. TWA: 1.4 mg/m³ 10 hours. OSHA PEL (United States, 6/2010). TWA: 1 ppm 8 hours. TWA: 1.4 mg/m³ 8 hours. Physical State pH Boiling Point Specific Gravity Solubility Liquid. 4.5 to 5.5 >100°C (>212°F) 1.022 Color Odor Vapor Pressure Vapor Density Evaporation Rate VOC (Consumer) Clear. Colorless. Pleasant. Not available. Not available. 1 (Water = 1) Easily soluble in the following materials: cold water and hot water. Section 9. Physical and Chemical Properties 0 % (w/w) 0 lbs/gal (0 g/l) The product is stable. Under normal conditions of storage and use, hazardous polymerization will not occur. Stability and Reactivity Hazardous Decomposition Products Hazardous Polymerization reactive or incompatible with the following materials: alkalis. Incompatibility carbon oxides (CO, CO₂) Section 10. Stability and Reactivity Page: 2/3 Page 24 of 328 Page 24 of 328 Page 24 of 328 Page 24 of 328 ---PAGE BREAK--- Safety Data Sheet Product Name Advanced Oxy Product code ZUOXSR Section 11. Toxicological Information Product/ingredient name Not available. Result Species Dose Exposure Environmental Effects Not available. Section 12. Ecological Information Aquatic ecotoxicity Product/ingredient name Species Exposure Result hydrogen peroxide Acute EC50 1.2 mg/l Marine water Algae - Dunaliella tertiolecta - Exponential growth phase 72 hours Acute EC50 5.38 mg/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Acute EC50 2320 µg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 22 ppm Fresh water Fish - mykiss - Juvenile (Fledgling, Hatchling, Weanling) 96 hours Waste Information Waste Stream Classification: Non-hazardous waste by Characteristic. Origin: RCRA waste. Section 13. Disposal Considerations Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or regional authorities for additional information. Regulatory information UN number Proper shipping name Classes PG* Label - - - Section 14. Transport Information DOT Classification Not regulated. IMDG Class Not regulated. - - - TDG Classification Not regulated. - - - U.S. Federal Regulations Clean Water Act (CWA) 311: No products were found. Clean Air Act (CAA) 112 regulated toxic substances: No products were found. State Regulations California Prop 65 All Components of this product are listed or exempt from listing on TSCA Inventory. Section 15. Regulatory Information SARA 313 toxic chemical notification and release reporting: No products were found. No products were found. Canada WHMIS (Canada) Class D-1B: Material causing immediate and serious toxic effects (Toxic). To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. *NOTE: Hazard Determination System (HDS) ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although these ratings are not required on under 29 CFR 1910.1200, the preparer may choose to provide them. HDS ratings are to be used with a fully implemented program to relay the meanings of this scale. Section 16. Other Information klm Page 25 of 328 Page 25 of 328 Page 25 of 328 Page 25 of 328 ---PAGE BREAK--- N044 Page 1 of 2 5332 Dansher Road Illinois 60525 MATERIAL SAFETY DATA SHEET Revision Date: 7/18/2013 MSDS No. N044 Supersedes Date: 4/4/2012 Emergency Phones: [PHONE REDACTED] (NYCO) [PHONE REDACTED] (CHEMTREC) PLEASE NOTE: This MSDS is being provided to your company for the purpose of providing current health and safety information to your management and for your employees who work with this material. Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT-TO-KNOW regulations. Also make this information available to any employee who requests it. It is your obligation to comply with these regulations. SECTION I - PRODUCT IDENTITY PRODUCT NAME: Bactizyme Bacterial Enzyme Drain Cleaner Formula: Mixture bioenzymatics, detergents and odorants in water. Chemical Type: as above HMIS RATINGS Health = 0 (Minimal) Flammability = 0 (Minimal) Reactivity = 0 (Minimal) Protection = B (Safety Glasses, Gloves) SECTION II - HAZARDOUS INGREDIENTS CARCINOGEN PERCENT TLV (OSHA,TP,IARC) None No SECTION III - CHEMICAL AND PHYSICAL Appearance: Cloudy Green Liquid Boiling Point: 210OF. Odor: Fresh and Clean Melting Point: N/A pH: 7.0-9.0 Spec. Gravity (H20 = 1.00 Water Solubility: Complete Vapor Pressure (Mm Hg): N/A Viscosity @ 25oC: < 25 cps (Brookfield) VOC Content: None SECTION IV - FIRE AND EXPLOSION HAZARDS Flash Point (Method): None Explosion Limits: Upper: N/A Lower: N/A Extinguishing Media: Use media appropriate for surrounding material. Special Firefighting Procedures and Hazards: Minimize prolonged skin and eye contact. Wear eye protection if exposure is likely. SECTION V - REACTIVITY INFORMATION Stable: Unstable: Precautions: Incompatibility: None known Hazardous Decomposition Products: If in a fire: CO, CO2, hydrocarbons. Hazardous Polymerization: Occurs: Does Not Occur: Page 26 of 328 Page 26 of 328 Page 26 of 328 Page 26 of 328 ---PAGE BREAK--- N044 Page 2 of 2 SECTION VI - HEALTH HAZARDS - PROTECTIVE MEASURES - FIRST AID Inhalation: Breathing of mists may cause irritation. Remove to fresh air. Give artificial respiration or oxygen if needed. Skin: Extended contact may cause irritation. Wash skin with soap and plenty of water. Remove contaminated clothing and wash before wearing again. Eyes: May cause irritation from misting. Flush with water for 15 minutes. If irritation persists consult a doctor. Ingestion: No effects reported. Avoid swallowing. Drink lots of water or, preferably, milk. Get medical attention if effects persist. Most likely routes of entry: Skin, Eyes. Other Important Medical or Precautionary Information: None SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE Spills and Leaks: Small spills can be flushed into normal drainage or into ground with copious amounts of water, or taken up with absorbent material. Do not drain to sewer without dilution. Larger spills should be contained by diking or other methods and held for disposal or reuse. Storage and Handling: No special precautions Waste Disposal: May be disposable in sewers if diluted and if local regulations permit. Otherwise, send to licensed treatment and disposal facility for handling and disposal. Observe label precautions. Empty Containers: Rinse well before handling and disposal. Observe label precautions. Other Precautions N/A SECTION VIII - REGULATORY INFORMATION Reportable for SARA Title III, S.313 (Form None The information herein has been compiled from sources believed to be reliable and is accurate to the best of our knowledge. However, NYCO Products Company cannot give any guarantees regarding information from other sources, and expressly does not make any warranties, nor assumes any liability, for its use. Page 27 of 328 Page 27 of 328 Page 27 of 328 Page 27 of 328 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME Bleach (2.0% Regular, Lemon) PRODUCT Brand EMERGENCY TELEPHONE NUMBERS ISSUE DATE September 30, 2010 Medical Information: 1-[PHONE REDACTED] MANUFACTURER James Austin Company Transportation: 1-[PHONE REDACTED]* STREET ADDRESS 115 Downieville Road * For spill, leak, fire or transport accident emergencies. CITY, STATE, ZIP Mars, PA 16046 Product Information: 1-[PHONE REDACTED] SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS HAZARDOUS EXPOSURE LIMITS COMPONENT CAS No. % by wt. OSHA PEL ACGIH TLV NIOSH REL Sodium hypochlorite 7681-52-9 2.00 - 2.50 None None None SECTION 3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW IRRITANT; may cause severe skin and eye irritation or chemical burns to broken skin. Vapors extremely irritating to eyes and respiratory tract. Harmful and potentially fatal if swallowed. If mixed with other prohibited chemicals or materials, chlorine gas will be released which is also irritating to eyes, lungs, mucous membranes and in some cases can be fatal. (see Setion 10 for more information) POTENTIAL HEALTH EFFECTS INGESTION Can cause corrosion of mucous membranes, severe esophageal burns and perforation of esophagus or stomach. INHALATION Inhalation of vapors can cause bronchial irritation, coughing, difficulty in breathing, nausea and pulmonary edema. EYE CONTACT Irritating to the eyes; may cause severe and permanent damage. SKIN CONTACT Severe irritant; contact can produce blistering and eczema. MSDS PRODUCT Bleach CODE PAGE 2 OF 4 Page 28 of 328 Page 28 of 328 Page 28 of 328 Page 28 of 328 ---PAGE BREAK--- SECTION 4 FIRST AID MEASURES INGESTION If swallowed, DO NOT induce vomiting. Immediately drink a large quantity of water. Do not give liquids if victim is unconscious. Do not use acidic antidotes or sodium bicarbonate (baking soda). Do not administer alcohol. Call a physician or poison control center immediately. INHALATION If exposed to excessive vapor levels, remove to fresh air and seek medical attention if cough or other develop. EYE CONTACT Immediately flush eye with plenty of cool, running water. Remove contact lenses if applicable, and continue flushing for at least 15 minutes. Get medical attention immediately. SKIN CONTACT Flush affected skin area with copious amounts of water and wash with soap and water. If irritation develops or persists, get medical attention. Remove clothing and wash before reuse. NOTE TO PHYSICIAN Information pertaining to ingestion toxicology, therapy, and treatment can be found in Clinical Toxicology of Commercial Products, authored by Gosselin, Smith and Hodge and published by Williams & Wilkins, Baltimore, Maryland. See listing for Hypochlorite in Therapeutics Index, Section III. SECTION 5 FIRE FIGHTING MEASURES FLASH POINT / METHOD None / N.A. FLAMMABLE LIMITS Not flammable or combustible EXTINGUISHING MEDIA If involved in a fire, alcohol foam, carbon dioxide, dry chemical or water fog. Use extinguishing media that is appropriate for surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES Avoid fumes from spilled or exposed liquid. Firefighters should wear full protective clothing and OSHA/NIOSH self-contained breathing apparatus. Cool fire-exposed containers with water spray from a safe distance. FIRE AND EXPLOSION HAZARDS Sodium hypochlorite bleach is a strong oxidizing agent and decomposes when heated. Decomposition products may cause containers to explode. Vigorous reactions may occur with organic materials or oxidizable materials, causing fires. SECTION 6 ACCIDENTAL RELEASE MEASURES RESPONSE TO SPILLS Small spills: Dilute product by flooding area with large quantity of water and flush to sanitary sewer. Large spills: Contain run-off by diking with suitable material. Soak up liquid on inert absorbent and transfer to approved container. Prevent spill from entering sewers or waterways. SECTION 7 HANDLING AND STORAGE HANDLING PRECAUTIONS Wash after handling and before eating. Use personal protective equipment and wear suitable chemical-resistant clothing. Keep container closed when not in use. Follow label directions closely. STORAGE PRECAUTIONS Store upright in a cool (below 85 dry, well-ventilated area. Keep away from heat or direct sunlight. Separate from incompatible materials, such as acids, ammonia, soap-based products or organic materials. Protect containers from physical damage. Keep away from children. MSDS PRODUCT Bleach CODE PAGE 3 OF 4 Page 29 of 328 Page 29 of 328 Page 29 of 328 Page 29 of 328 ---PAGE BREAK--- SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION HYGIENIC PRACTICES Avoid breathing vapors. Do not store near food stuffs, water or feed. Protect eyes, skin and clothing from contact with this product. ENGINEERING CONTROLS Use local ventilation to remove vapors at the source. Facilities using this product must be equipped with an eyewash station. PERSONAL PROTECTIVE EQUIPMENT X RESPIRATOR Not normally necessary; use NIOSH approved respirator for concentrated vapors X GOGGLES / FACE SHIELD Recommended but not needed. Should be chemical splash type. X APRON Recommended but not needed to avoid skin contact and protect clothing from damage X GLOVES Recommended but not needed, use impervious PVC/Neoprene with long gauntlet X BOOTS Recommended but not needed to protect shoes and feet when using product for floor cleaning SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Clear pale yellow liquid BOILING POINT 212 deg F ODOR Chlorine FREEZING POINT 28 deg F pH 12.0 - 12.8 VAPOR PRESSURE 17.5 mm Hg @ 20 C SPECIFIC GRAVITY 1.080 VAPOR DENSITY Not applicable SOLUBILITY IN WATER Complete EVAPORATION RATE Not applicable SECTION 10 STABILITY AND REACTIVITY CHEMICAL STABILITY STABLE X UNSTABLE CONDITIONS TO AVOID Heat or direct sunlight; temperatures above 85 F. NEVER mix with solutions containing ammonia. INCOMPATIBILITY Acids, ammonia, ether, urea, oxidizable materials, soaps, oils, greases, phenolic disinfectants and metals (including nickel, copper, tin, aluminum and iron). HAZARDOUS PRODUCTS OF DECOMPOSITION Chlorine gas from contact with highly acidic materials. Chloramines from contact with ammonia. phenols from contact with phenolic disinfectants. POLYMERIZATION WILL NOT OCCUR X MAY OCCUR CONDITIONS TO AVOID Not applicable SECTION 11 TOXICOLOGICAL INFORMATION CARCINOGENICITY THIS PRODUCT CONTAINS A KNOWN OR SUSPECTED CARCINOGEN X THIS PRODUCT DOES NOT CONTAIN ANY KNOWN OR ANTICIPATED CARCINOGENS ACCORDING TO THE CRITERIA OF THE NTP ANNUAL REPORT ON CARCINOGENS AND OSHA 29 CFR 1910, Z OTHER EFFECTS ACUTE Toxicity arises from corrosive activity; stems from oxidizing potency, a function of concentration CHRONIC Not determined Page 30 of 328 Page 30 of 328 Page 30 of 328 Page 30 of 328 ---PAGE BREAK--- MSDS PRODUCT Bleach CODE PAGE 4 OF 4 SECTION 12 ECOLOGICAL INFORMATION BIODEGRADABILITY CONSIDERED BIODEGRADABLE X NOT BIODEGRADABLE BOD / COD VALUE Not established ECOTOXICITY No data available SECTION 13 DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD If in accordance with an NPDES permit or approved by local sewage treatment plant authority, small amounts may be flushed to a sanitary sewer with plenty of water. Large amounts of unused product must be disposed of as hazardous waste at an approved hazardous waste management facility. RCRA CLASSIFICATION Hazardous, corrosive D002 (if pH is equal to or greater than 12.5) RECYCLE CONTAINER YES X CODE 2 - HDPE NO SECTION 14 TRANSPORT INFORMATION DOT CLASSIFICATION HAZARDOUS NOT HAZARDOUS X DOT Proper Shipping Name Hazard Class Identification Number Packing Group Label/Placard RQ Not regulated as per DOT/IMDG/IATA N/A N/A N/A None None EXCEPTIONS SECTION 15 REGULATORY INFORMATION REGULATORY STATUS EPA REGISTERED (UNDER FIFRA) No FDA REGULATED No KOSHER No SARA TITLE III MATERIAL Bottled product not regulated USDA AUTHORIZED No SECTION 16 OTHER INFORMATION NFPA CLASSIFICATION Approved Specifications 1 BLUE HEALTH HAZARD Federal Specification O-S-602E 0 RED FLAMMABILITY Commercial Item Description A-1427C 0 YELLOW REACTIVITY COR WHITE SPECIAL HAZARD Information contained in this MSDS refers only to the specific material designated and does not relate to any process or use involving other materials. This information is based on data believed to be reliable, and the Product is intended to be used in a manner that is customary and reasonably foreseeable. Since actual use and handling are beyond our control, no warranty, express or implied, is made and no liability is assumed by James Austin Company in connection with the use of this information. Page 31 of 328 Page 31 of 328 Page 31 of 328 Page 31 of 328 ---PAGE BREAK--- SAFETY DATA SHEET Issue Date 31-Dec-2014 Revision Date 31-Dec-2014 Version 1 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Product Name Calci-Solve Super Strength Descaler Other means of identification Product Code NL001 Synonyms None Details of the supplier of the safety data sheet Emergency telephone number Emergency Telephone Chemtrec 1-[PHONE REDACTED] 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Category 4 Acute toxicity - Dermal Not classified Acute toxicity - Inhalation (Gases) Category 3 Acute toxicity - Inhalation (Dusts/Mists) Category 4 Skin corrosion/irritation Category 1 Sub-category B Serious eye damage/eye irritation Category 1 Specific target organ toxicity (single exposure) Category 3 Label elements Emergency Overview Company Name Page 1 / 8 Nyco Products Company 5332 Dansher Road IL 60525 (708) 579-8100 nycoproducts.com Danger Hazard statements Harmful if swallowed Toxic if inhaled Causes severe skin burns and eye damage May cause respiratory irritation. May cause drowsiness or dizziness Page 32 of 328 Page 32 of 328 Page 32 of 328 Page 32 of 328 ---PAGE BREAK--- NL001 Calci-Solve Super Strength Descaler Revision Date 31-Dec-2014 Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Use only outdoors or in a well-ventilated area Do not breathe dust/fume/gas/mist/vapors/spray Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response Immediately call a POISON CENTER or doctor/physician Specific Treatment (See Section 4 on the SDS) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell Immediately call a POISON CENTER or doctor/physician IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Do NOT induce vomiting Precautionary Statements - Storage Store in a well-ventilated place. Keep container closed Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Other Information Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. Weight-% Trade Secret Hydrochloric Acid 7647-01-0 15-40 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES First aid measures General advice Immediate medical attention is required. Skin Contact Immediately flush skin with plenty of water for at least 15 (30 or 60) minutes. Remove contaminated clothing and shoes. Wash contaminated clothing before reuse. Immediate medical attention is required. Appearance Clear Light Red/Orange Physical state Liquid Odor Acidic Page 33 of 328 Page 33 of 328 Page 33 of 328 Page 33 of 328 ---PAGE BREAK--- NL001 Calci-Solve Super Strength Descaler Revision Date 31-Dec-2014 Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open while rinsing. Do not rub affected area. Immediate medical attention is required. Inhalation Remove to fresh air. Call a physician or poison control center immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Ingestion Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Drink plenty of water. Immediate medical attention is required. Remove from exposure, lie down. Clean mouth with water and drink afterwards plenty of water. Call a physician or poison control center immediately. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important and effects, both acute and delayed Any additional important and effects are described in Section 11: Toxicology Information. Indication of any immediate medical attention and special treatment needed Note to physicians Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated. Do not give chemical antidotes. from glottal edema may occur. Marked decrease in blood pressure may occur with moist rales, frothy sputum, and high pulse pressure. Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media Caution: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical The product causes burns of eyes, skin and mucous membranes. Thermal decomposition can lead to release of irritating and toxic gases and vapors. In the event of fire and/or explosion do not breathe fumes. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment as required. Evacuate personnel to safe areas. Avoid contact with skin, eyes or clothing. Keep people away from and upwind of spill/leak. Environmental precautions Environmental precautions Do not allow into any sewer, on the ground or into any body of water. Should not be released into the environment. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading. Dike far ahead of liquid spill for later disposal. Page 34 of 328 Page 34 of 328 Page 34 of 328 Page 34 of 328 ---PAGE BREAK--- NL001 Calci-Solve Super Strength Descaler Revision Date 31-Dec-2014 Methods for cleaning up Dike far ahead of liquid spill for later disposal. Soak up with inert absorbent material. Take up mechanically, placing in appropriate containers for disposal. Clean contaminated surface thoroughly. Prevent product from entering drains. Dam up. After cleaning, flush away traces with water. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Ensure adequate ventilation, especially in confined areas. In case of insufficient ventilation, wear suitable respiratory equipment. Use only with adequate ventilation and in closed systems. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container closed in a dry and well-ventilated place. Keep out of the reach of children. Keep containers closed in a dry, cool and well-ventilated place. Keep in properly labeled containers. Incompatible materials Incompatible with strong acids and bases. Incompatible with oxidizing agents. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Hydrochloric Acid 7647-01-0 Ceiling: 2 ppm (vacated) Ceiling: 5 ppm (vacated) Ceiling: 7 mg/m3 Ceiling: 5 ppm Ceiling: 7 mg/m3 IDLH: 50 ppm Ceiling: 5 ppm Ceiling: 7 mg/m3 Propargyl Alcohol 107-19-7 TWA: 1 ppm S* (vacated) TWA: 1 ppm (vacated) TWA: 2 mg/m3 (vacated) S* TWA: 1 ppm TWA: 2 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers, Eyewash stations & Ventilation systems. Individual protection measures, such as personal protective equipment Eye/face protection Tight sealing safety goggles. Face protection shield. Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. General Hygiene When using do not eat, drink or smoke. Wash contaminated clothing before reuse. Keep away from food, drink and animal feeding stuffs. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is recommended. Avoid contact with skin, eyes or clothing. Take off all contaminated clothing and wash it before reuse. Wear suitable gloves and eye/face protection. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 35 of 328 Page 35 of 328 Page 35 of 328 Page 35 of 328 ---PAGE BREAK--- NL001 Calci-Solve Super Strength Descaler Revision Date 31-Dec-2014 Information on basic physical and chemical properties Physical state Liquid Other Information Density Lbs/Gal 9.66 VOC Content < 0.1% 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Exposure to air or moisture over prolonged periods. Incompatible materials Incompatible with strong acids and bases. Incompatible with oxidizing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating and toxic gases and vapors. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information The primary effects and toxicity of this material are due to it corrosive nature. Inhalation Toxic by inhalation. Breathing of vapor can cause respiratory irritation and inflammation. Breathing of mist or liquid can cause burns to the respiratory tract. Eye contact Corrosive to the eyes and may cause severe damage including blindness. Appearance Clear Light Red/Orange Color Light Red/Orange Odor Acidic Odor threshold No Information available Property Values Remarks • Method pH <1 Specific Gravity 1.16 Viscosity < 25 cP @ 25°C Melting point/freezing point No Information available Flash point None Boiling point / boiling range Est 180 °F Evaporation rate No Information available Flammability (solid, gas) Flammability Limits in Air Upper flammability limit: No Information available Lower flammability limit: No Information available Vapor pressure 39 mm Hg Vapor density No Information available Water solubility Complete Partition coefficient No Information available Autoignition temperature No Information available Decomposition temperature No Information available No data available Page 36 of 328 Page 36 of 328 Page 36 of 328 Page 36 of 328 ---PAGE BREAK--- NL001 Calci-Solve Super Strength Descaler Revision Date 31-Dec-2014 Skin Contact Corrosive. Contact with skin may cause severe irritation and burns. Ingestion Toxic if swallowed. Ingestion causes acute irritation and burns to the mucous membranes of the mouth, trachea, esophagus and stomach. Information on toxicological effects No Information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization May cause sensitization by skin contact. Germ cell mutagenicity No Information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA Hydrochloric Acid 7647-01-0 Yes Group 3 Yes Yes IARC (International Agency for Research on Cancer) Not classifiable as a human carcinogen Reproductive toxicity No Information available. STOT - single exposure No Information available. STOT - repeated exposure No Information available. Chronic toxicity Chronic exposure to corrosive fumes/gases may cause erosion of the teeth followed by jaw necrosis. Bronchial irritation with chronic cough and frequent attacks of pneumonia are common. Gastrointestinal disturbances may also be seen. Avoid repeated exposure. Possible risk of irreversible effects. Target organ effects EYES, Respiratory system, Skin. Aspiration hazard No Information available. Numerical measures of toxicity - Product Information Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document . 12. ECOLOGICAL INFORMATION Ecotoxicity 0.414% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea Hydrochloric Acid 7647-01-0 Yes 282: 96 h Gambusia affinis mg/L LC50 static Yes Propargyl Alcohol 107-19-7 Yes 1.49 - 1.56: 96 h Pimephales promelas mg/L LC50 flow-through 32: 24 h Daphnia magna mg/L EC50 Persistence and degradability No Information available. Bioaccumulation No Information available. Other adverse effects No Information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes Page 37 of 328 Page 37 of 328 Page 37 of 328 Page 37 of 328 ---PAGE BREAK--- NL001 Calci-Solve Super Strength Descaler Revision Date 31-Dec-2014 Propargyl Alcohol 107-19-7 P102 Yes Yes Yes 14. TRANSPORT INFORMATION The basic description below is specific to the container size. This information is provided for at a glance DOT information. Please refer to the container and/or shipping papers for the appropriate shipping description before tendering this material for shipment. For additional information, please contact the distributor listed in section 1 of this SDS. DOT Regulated UN/ID No. UN 1789 Proper shipping name Hydrochloric acid Hazard Class 8 Packing Group II Special Provisions A3, A6, B3, B15,I B2, N41, T8, TP1 Description UN1789, Hydrochloric acid solution, 8, II Emergency Response Guide Number 157 TDG UN/ID No. UN1789 Proper shipping name Hydrochloric acid Hazard Class 8 Packing Group II Description UN1789, Hydrochloric acid solution, 8, II 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % Hydrochloric Acid - 7647-01-0 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Hydrochloric Acid 7647-01-0 5000 lb Yes Yes X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Page 38 of 328 Page 38 of 328 Page 38 of 328 Page 38 of 328 ---PAGE BREAK--- NL001 Calci-Solve Super Strength Descaler Revision Date 31-Dec-2014 Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) Hydrochloric Acid 7647-01-0 5000 lb 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Hydrochloric Acid 7647-01-0 X X X Propargyl Alcohol 107-19-7 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not Applicable 16. OTHER INFORMATION Issue Date 31-Dec-2014 Revision Date 31-Dec-2014 Revision Note No Information available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health hazards 3 Flammability 0 Instability 0 Physical and Chemical Properties Yes HMIS Health hazards 3 Flammability 0 Physical hazards 0 Personal protection D Page 39 of 328 Page 39 of 328 Page 39 of 328 Page 39 of 328 ---PAGE BREAK--- 1. Identification of the Substance/Preparation and of the Company/Undertaking Product Identifier Product name CHAMPION SPRAYON CHEWING GUM & CANDLE WAX REMOVER Chemical name 5-5615 Other means of identification Product code FG 438-5165-6 Synonyms Chewing gum and candle wax remover. Recommended use of the chemical and restrictions on use Recommended Use To remove chewing gum and candle wax. Uses advised against See directions for use on product's label. Details of the supplier of the safety data sheet Emergency Telephone Number Company Phone Number [PHONE REDACTED] 24 Hour Emergency Phone Number 1-[PHONE REDACTED] Emergency telephone ChemTel 1-[PHONE REDACTED] 2. Hazards Identification Classification Label Elements EMERGENCY OVERVIEW Precautionary Statements - Prevention Keep away from heat, sparks, open flames and hot surfaces. — No smoking Page 1 / 7 Category 1 EXTREMELY FLAMMABLE AEROSOL Gases Under Pressure Contains gas under pressure; may explode if heated Manufacturer Address Chase Products Co. 2727 Gardner Road Broadview, IL 60155 [PHONE REDACTED] liquefied gas Version 1 Safety Data Sheet Supplier Address Chase Products Co. 2727 Gardner Road Broadview, IL 60155 [PHONE REDACTED] Issue date 16-Mar-2015 DANGER FLAMMABLE AEROSOLS Liquid contents may cause frostbite on contact with skin. The product contains no substances which at their given concentration, are considered to be hazardous to health Appearance Non visible gas Physical State Aerosol Odor Sweet, petroleum odor Page 40 of 328 Page 40 of 328 Page 40 of 328 Page 40 of 328 ---PAGE BREAK--- Pressurized container: Do not pierce or burn, even after use Do not spray on an open flame or other ignition source Precautionary Statements - Storage Protect from sunlight. Store in a well-ventilated place Do not expose to temperatures exceeding 50°C (122 Hazards not otherwise classified (HNOC) Other Information 0% of the mixture consists of ingredient(s) of unknown toxicity 3. Composition/information on Ingredients Common Name Chewing gum and candle wax remover. Synonyms Chewing gum and candle wax remover. Chemical Family MIXTURES. Formula 5-5615 Chemical nature Hydrocarbon propellant. Chemical name CAS No weight-% Trade secret N-Butane 106-97-8 70-75 * Propane 74-98-6 25-30 * * The exact percentage (concentration) of composition has been withheld as a trade secret. 4. First aid measures FIRST AID MEASURES Eye Contact Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Skin contact In case of contact, immediately flush skin with plenty of water. Wash skin with soap and water. If irritation develops, consult a physician. inhalation If overcome by vapor, move person to fresh air. If person is not breathing, call 911 or an ambulance, then provide artifical respiration, preferably mouth-to-mouth, if possible. Call a poison control center or doctor for further treatment advise. INGESTION Ingestion from an aerosol product is unlikely to occur. Most important and effects, both acute and delayed Prolonged contact with the skin may cause severe freeze burns. Over inhalation of vapor or mist may cause anesthetic effects, headaches, dizziness and nausea. Indication of any immediate medical attention and special treatment needed Note to physicians None needed. 5. Fire-fighting measures Suitable extinguishing media Dry chemical extinguisher water. Unsuitable extinguishing media Caution: Use of water spray when fighting fire may be inefficient. Page 2 / 7 FG 438-5165-6 CHAMPION SPRAYON CHEWING GUM & CANDLE WAX REMOVER Page 41 of 328 Page 41 of 328 Page 41 of 328 Page 41 of 328 ---PAGE BREAK--- Specific hazards arising from the chemical Vapors are heavier than air and may travel along the ground and be ignited by pilot lights, other flames, sparks, heaters, smoking or other ignition sources. Hazardous combustion decomposition may release carbon monoxide and carbon dioxide. Explosion data Sensitivity to Mechanical Impact Contents under pressure, keep away from heat and open flame. Sensitivity to Static Discharge Keep away from heat, sparks, flame, and other sources of ignition pilot lights, electric motors and static electricity). Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Personal precautions Use with adequate general or local exhaust ventilation. For emergency responders Remove all sources of ignition. Environmental Precautions Environmental Precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for Containment Provide adequate ventilation. Avoid sources of ignition. Methods for cleaning up Clean contaminated surface thoroughly. 7. Handling and Storage Precautions for safe handling Advice on safe handling Avoid contact with skin. Avoid getting spray into eyes. Do not deliberately inhale vapor or mist. Do not contaminate food or food handling surfaces. Keep out of reach of children. Conditions for safe storage, including any incompatibilities Storage Conditions Store in a cool, dry place away from heat and open flame. Keep out of reach of children. AEROSOL STORAGE LEVEL III (NFPA-30B). Incompatible Materials Keep away from heat, sparks, flame and other sources of ignition pilot lights, electric motors and static electricity. 8. Exposure Controls/Personal Protection Control parameters Exposure guidelines See occupational exposure limits listed below. Chemical name ACGIH TLV OSHA PEL NIOSH IDLH N-Butane 106-97-8 STEL: 1000 ppm (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 TWA: 800 ppm TWA: 1900 mg/m3 Propane 74-98-6 TWA: 1000 ppm TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 Page 3 / 7 FG 438-5165-6 CHAMPION SPRAYON CHEWING GUM & CANDLE WAX REMOVER Page 42 of 328 Page 42 of 328 Page 42 of 328 Page 42 of 328 ---PAGE BREAK--- Appropriate engineering controls Engineering controls Use with adequate general or local exhaust ventilation. Individual protection measures, such as personal protective equipment Eye/face Protection Conventional eyeglasses to guard against splashing. Skin and Body Protection Rubber, vinyl or household type gloves required. Respiratory protection Use in a well-ventilated area ONLY. WHEN USING INDOORS, KEEP WINDOWS AND DOORS OPEN UNTIL FUMES DISSIPATE. General hygiene considerations Wash hands thoroughly after handling. 9. Physical and Chemical Properties Information on basic physical and chemical properties Physical State Aerosol Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC content 100% Density 4.62 lb/gal Bulk Density No information available 10. Stability and Reactivity Reactivity Chemical stability Stable. Page 4 / 7 Specific gravity 0.555 No information available No information available Odor threshold No information available Water solubility Boiling point/boiling range 0.008% -6.4 to 10.9 °F Solubility in other solvents No information available No information available Partition coefficient No information available Autoignition Temperature Flash Point Extremely flammable gas -156 °F No information available Decomposition temperature Odor No information available No information available Kinematic viscosity Sweet, petroleum odor No information available Evaporation Rate Dynamic viscosity Immediate No information available Property Values No information available Flammability (solid, gas) FG 438-5165-6 CHAMPION SPRAYON CHEWING GUM & CANDLE WAX REMOVER No information available Remarks • Method Flammability Limits in Air No information available pH Upper flammability limits Not available Not applicable Color Colorless Lower Flammability Limit Not available Gasseous material Not applicable Not applicable Vapor pressure 46 psig Appearance No information available Melting point/freezing point Not applicable Vapor Density Non visible gas No information available Page 43 of 328 Page 43 of 328 Page 43 of 328 Page 43 of 328 ---PAGE BREAK--- Possibility of hazardous reactions Temperatures above 130 °F may cause cans to burst with force. hazardous polymerization Hazardous polymerization does not occur. Conditions to Avoid Temperatures above 122 °F (50 Incompatible Materials Keep away from heat, sparks, flame and other sources of ignition pilot lights, electric motors and static electricity. Hazardous decomposition products Thermal decomposition may yield gases like carbon monoxide and carbon dioxide. 11. Toxicological Information Information on likely routes of exposure Product Information This product has not been tested as whole. See below for information on ingredients. inhalation no data available. Eye Contact no data available. Skin contact no data available. INGESTION no data available. Chemical name Oral LD50 dermal LD50 Inhalation LC50 N-Butane 106-97-8 - - = 658 g/m3 ( Rat ) 4 h Propane 74-98-6 - - = 658 mg/L ( Rat ) 4 h Information on toxicological effects Over inhalation of vapor or mist may cause anesthetic effects, headaches, dizziness and nausea. Delayed and immediate effects as well as chronic effects from short and long-term exposure Skin corrosion/irritation Prolonged contact with the skin may cause severe freeze burns. Serious eye damage/eye irritation Can cause severe eye irritation, redness, tearing and possible freeze burns. corrosivity Not applicable. sensitization No a skin sensitizer. Germ Cell Mutagenicity No information available. carcinogenicity Not known chronic effects based on available data. None of the ingredients present in excess of 0.1% are listed as carcinogenic by NTP, IARC or OSHA. Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Aspiration Hazard Not applicable. Numerical measures of toxicity - Product Information Unknown acute toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (inhalation-gas) 2293333 mg/l ATEmix (inhalation-vapor) 658 mg/l 12. Ecological Information This product does not contain marine pollutants. Page 5 / 7 FG 438-5165-6 CHAMPION SPRAYON CHEWING GUM & CANDLE WAX REMOVER Page 44 of 328 Page 44 of 328 Page 44 of 328 Page 44 of 328 ---PAGE BREAK--- ecotoxicity 100% of the mixture consists of components(s) of unknown hazards to the aquatic environment Persistence and degradability No information available. Bioaccumulation No information available. Chemical name Partition coefficient N-Butane 106-97-8 2.89 Propane 74-98-6 2.3 Other adverse effects No information available 13. Disposal Considerations Waste treatment methods Disposal of wastes Dispose of in accordance with federal, state and local regulations. Contaminated packaging Pressurized container: Do not pierce or burn, even after use. Do not puncture or incinerate container. If empty: Place in trash or offer for recycling if available. If partly filled: Call your local solid waste agency for disposal instructions. 14. Transport Information DOT Limited quantity (LQ) Chewing gum and candle wax remover. UN/ID no UN1950 Proper Shipping Name Limited quantity (LQ) Hazard Class 2.1 Marine pollutant This product does not contain marine pollutants. 15. Regulatory information International Inventories TSCA All ingredients of this product are listed or are excluded from listing under the U.S. Toxic Subtances Control Act (TSCA) Chemical Substance Inventory. DSL All ingredients are listed or are excluded from listing on the DSL. Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List US Federal Regulations Page 6 / 7 FG 438-5165-6 CHAMPION SPRAYON CHEWING GUM & CANDLE WAX REMOVER Page 45 of 328 Page 45 of 328 Page 45 of 328 Page 45 of 328 ---PAGE BREAK--- SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute Health Hazard yes Chronic Health Hazard No Fire Hazard yes Sudden release of pressure hazard yes Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical name New Jersey Massachusetts N-Butane 106-97-8 X X X Propane 74-98-6 X X X U.S. EPA Label information EPA Pesticide registration number Not applicable 16. Other information Issue date 16-Mar-2015 Revision note This SDS supersedes a previous MSDS dated September 05, 2013. Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 7 / 7 Instability 1 NFPA Physical and chemical properties Not applicable HMIS FG 438-5165-6 CHAMPION SPRAYON CHEWING GUM & CANDLE WAX REMOVER Health Hazards 1 Health Hazards 1 Flammability 4 Physical Hazards 1 Personal Protection B - Eyes and hands protection Flammability 4 Page 46 of 328 Page 46 of 328 Page 46 of 328 Page 46 of 328 ---PAGE BREAK--- 1. Identification of the Substance/Preparation and of the Company/Undertaking Product Identifier Product name CHAMPION SPRAYON X-IT-OUT VANDAL MARK REMOVER Chemical name 7-7786-2 Other means of identification Product code FG 438-5149-11 Synonyms Graffiti Remover Recommended use of the chemical and restrictions on use Recommended Use Vandal mark remover. Uses advised against Do not use to clean glass or wood surfaces. DO NOT USE ON FLOORS Details of the supplier of the safety data sheet Emergency Telephone Number Company Phone Number [PHONE REDACTED] 24 Hour Emergency Phone Number 1-[PHONE REDACTED] Emergency telephone ChemTel 1-[PHONE REDACTED] 2. Hazards Identification Classification Acute toxicity - Oral Category 4 Acute toxicity - Inhalation (Gases) Category 2 Acute toxicity - Inhalation (Vapors) Category 4 Acute toxicity - Inhalation (Dusts/Mists) Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Skin sensitization Category 1 carcinogenicity Category 1B Reproductive Toxicity Category 2 Specific target organ toxicity (single exposure) Category 3 Specific target organ toxicity (repeated exposure) Category 2 Aspiration toxicity Category 1 Label Elements EMERGENCY OVERVIEW Page 1 / 12 Issue date 17-Mar-2015 Manufacturer Address Chase Products Co. 2727 Gardner Road Broadview, IL 60155 [PHONE REDACTED] DANGER FLAMMABLE AEROSOLS Category 1 hazard statements HARMFUL IF SWALLOWED Contains methanol, may cause blindess if swallowed. Fatal if inhaled CAUSES SKIN IRRITATION Causes serious eye irritation Gases Under Pressure Version 1 liquefied gas Safety Data Sheet Supplier Address Chase Products Co. 2727 Gardner Road Broadview, IL 60155 [PHONE REDACTED] Page 47 of 328 Page 47 of 328 Page 47 of 328 Page 47 of 328 ---PAGE BREAK--- Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Wear protective gloves, protective clothing, eye protection and face protection. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Do not breathe fumes, mist, vapors or spray. Use only outdoors or in a well-ventilated area Wear respiratory protection Contaminated work clothing should not be allowed out of the workplace Wear protective gloves Keep away from heat, sparks, open flames and hot surfaces. — No smoking Pressurized container: Do not pierce or burn, even after use Do not spray on an open flame or other ignition source Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention Specific treatment is urgent. See additional cautionary statements and "NOTICE" on this label. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water Take off contaminated clothing and wash before reuse If skin irritation or rash occurs: Get medical advice/attention IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a POISON CENTER or doctor. IF SWALLOWED: Rinse mouth. Immediately call a POISON CENTER or doctor. Do NOT induce vomiting Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep container closed Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Other Information • Harmful to aquatic life with long lasting effects • MAY BE HARMFUL IF SWALLOWED • May be harmful in contact with skin • Toxic to aquatic life with long lasting effects Page 2 / 12 EXTREMELY FLAMMABLE AEROSOL Pressurized container: May burst if heated May cause an allergic skin reaction May cause cancer Suspected of damaging fertility or the unborn child May cause respiratory irritation. May cause drowsiness or dizziness May cause damage to organs through prolonged or repeated exposure May be fatal if swallowed and enters airways Contains gas under pressure; may explode if heated FG 438-5149-11 CHAMPION SPRAYON X-IT-OUT VANDAL MARK REMOVER Odor Citrus odor Appearance Yellowish liquid Physical State Aerosol Page 48 of 328 Page 48 of 328 Page 48 of 328 Page 48 of 328 ---PAGE BREAK--- - 3. Composition/information on Ingredients Synonyms Graffiti Remover. Chemical Family MIXTURES. Formula 7-7786-2 Chemical name CAS No weight-% Trade secret Naphtha (petroleum), heavy aromatic 64742-94-5 15-20 * Toluene 108-88-3 15-20 * Acetone 67-64-1 15-20 * Dimethyl Glutarate 1119-40-0 15-20 * Carbon Dioxide 124-38-9 1-5 * Pine Oil 8002-09-3 1-5 * Methyl alcohol 67-56-1 <3 * Naphthalene 91-20-3 1-2 * Cocamide diethanolamine 68603-42-9 1-2 * D-Limonene 5989-27-5 1-5 * * The exact percentage (concentration) of composition has been withheld as a trade secret. 4. First aid measures FIRST AID MEASURES Eye Contact Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Skin contact Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advise. inhalation If overcome by vapor, move person to fresh air. If person is not breathing, call 911 or an ambulance, then provide artifical respiration, preferably mouth-to-mouth, if possible. Call a poison control center or doctor for further treatment advise. INGESTION Call a poison control center or doctor for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Most important and effects, both acute and delayed Acute: Prolonged inhalation of concentrated vapor or mist may cause headaches, dizziness and nausea. Prolonged and repeated contact with skin may cause irritation and reddening. Contact with eyes causes irritation. Indication of any immediate medical attention and special treatment needed Note to physicians Contains petroleum distillates, do not induce vomiting because of aspiration neumonia hazard. 5. Fire-fighting measures Suitable extinguishing media Dry chemical, CO2 or water spray. Unsuitable extinguishing media Caution: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical Page 3 / 12 FG 438-5149-11 CHAMPION SPRAYON X-IT-OUT VANDAL MARK REMOVER Page 49 of 328 Page 49 of 328 Page 49 of 328 Page 49 of 328 ---PAGE BREAK--- This product is under pressure. Water spray may be used to cool cans in the vicinity of fire or excessive heat to prevent the explosion of the cans. Hazardous combustion decomposition may yield gases like nitrogen oxides, carbon monoxide and carbon dioxide. Explosion data Sensitivity to Mechanical Impact Contents under pressure. This product is extremely flammable. Keep away from heat, sparks, flame and other sources of ignition pilot lights, electric motors and static electricity). Sensitivity to Static Discharge Keep away from heat, sparks, flame, and other sources of ignition pilot lights, electric motors and static electricity). Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Personal precautions Use in well-ventilated area ONLY. NOTICE: Reports have associated repeated and prolonged occupational over exposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. To avoid breathing vapor or spray mist open windows and doors or use other means to ensure fresh air entry during application and drying. If you experience eye watering, headaches, or dizziness, increase fresh air or wear an appropriate, properly fitted respirator (NIOSH approved), or leave the area. NOTE: Follow respirator manufacturer's instructions carefully for respirator use. For emergency responders Remove all sources of ignition. Environmental Precautions Environmental Precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for Containment Provide adequate ventilation to area being treated. Soak up spills with chemically inert, absorbent material. Methods for cleaning up Clean contaminated surface thoroughly. 7. Handling and Storage Precautions for safe handling Advice on safe handling Handle as an extremely flammable material. Avoid contact with skin, eyes and clothing. Store cans in a cool, dry place away from heat and open flame. Conditions for safe storage, including any incompatibilities Storage Conditions Keep away from heat, sparks, flame and other sources of ignition pilot lights, electric motors and static electricity). AEROSOL STORAGE LEVEL III (NFPA-30B). Incompatible Materials Avoid heat, open flame and contact with strong acids, strong bases and strong oxidizers. 8. Exposure Controls/Personal Protection Control parameters Exposure guidelines See occupational exposure limits listed below. Page 4 / 12 FG 438-5149-11 CHAMPION SPRAYON X-IT-OUT VANDAL MARK REMOVER Page 50 of 328 Page 50 of 328 Page 50 of 328 Page 50 of 328 ---PAGE BREAK--- Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Acetone 67-64-1 STEL: 750 ppm TWA: 500 ppm TWA: 1000 ppm TWA: 2400 mg/m3 (vacated) TWA: 750 ppm (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors (vacated) STEL: 1000 ppm IDLH: 2500 ppm TWA: 250 ppm TWA: 590 mg/m3 Toluene 108-88-3 TWA: 20 ppm TWA: 200 ppm (vacated) TWA: 100 ppm (vacated) TWA: 375 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 560 mg/m3 Ceiling: 300 ppm IDLH: 500 ppm TWA: 100 ppm TWA: 375 mg/m3 STEL: 150 ppm STEL: 560 mg/m3 Carbon Dioxide 124-38-9 STEL: 30000 ppm TWA: 5000 ppm TWA: 5000 ppm TWA: 9000 mg/m3 (vacated) TWA: 10000 ppm (vacated) TWA: 18000 mg/m3 (vacated) STEL: 30000 ppm (vacated) STEL: 54000 mg/m3 IDLH: 40000 ppm TWA: 5000 ppm TWA: 9000 mg/m3 STEL: 30000 ppm STEL: 54000 mg/m3 Methyl alcohol 67-56-1 STEL: 250 ppm TWA: 200 ppm S* TWA: 200 ppm TWA: 260 mg/m3 (vacated) TWA: 200 ppm (vacated) TWA: 260 mg/m3 (vacated) STEL: 250 ppm (vacated) STEL: 325 mg/m3 (vacated) S* IDLH: 6000 ppm TWA: 200 ppm TWA: 260 mg/m3 STEL: 250 ppm STEL: 325 mg/m3 Naphthalene 91-20-3 TWA: 10 ppm S* TWA: 10 ppm TWA: 50 mg/m3 (vacated) TWA: 10 ppm (vacated) TWA: 50 mg/m3 (vacated) STEL: 15 ppm (vacated) STEL: 75 mg/m3 IDLH: 250 ppm TWA: 10 ppm TWA: 50 mg/m3 STEL: 15 ppm STEL: 75 mg/m3 1,2,4 95-63-6 - - TWA: 25 ppm TWA: 125 mg/m3 Appropriate engineering controls Engineering controls Use with adequate general or local exhaust ventilation. Individual protection measures, such as personal protective equipment Eye/face Protection Conventional eyeglasses to guard against splashing. Skin and Body Protection Chemical resistant gloves required. Respiratory protection Use in well-ventilated area ONLY. NOTICE: Reports have associated repeated and prolonged occupational over exposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. To avoid breathing vapor or spray mist open windows and doors or use other means to ensure fresh air entry during application and drying. If you experience eye watering, headaches, or dizziness, increase fresh air or wear an appropriate, properly fitted respirator (NIOSH approved), or leave the area. NOTE: Follow respirator manufacturer's instructions carefully for respirator use. General hygiene considerations Wash hands thoroughly after handling. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. 9. Physical and Chemical Properties Information on basic physical and chemical properties Page 5 / 12 FG 438-5149-11 CHAMPION SPRAYON X-IT-OUT VANDAL MARK REMOVER Page 51 of 328 Page 51 of 328 Page 51 of 328 Page 51 of 328 ---PAGE BREAK--- Physical State Aerosol Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC content 48.96% Density 7.62 b/gal Bulk Density No information available 10. Stability and Reactivity Reactivity Chemical stability Stable. Possibility of hazardous reactions Temperatures above 130 °F may cause cans to burst with force. hazardous polymerization Hazardous polymerization does not occur. Conditions to Avoid Temperatures above 122 °F (50 Incompatible Materials Avoid heat, open flame and contact with strong acids, strong bases and strong oxidizers. Hazardous decomposition products Thermal decomposition may yield gases like nitrogen oxides, carbon monoxide and carbon dioxide. 11. Toxicological Information Information on likely routes of exposure Page 6 / 12 No information available Partition coefficient No information available Autoignition Temperature Flash Point Not Available. This is an aerosol product for which Flame Projection is over 18 inches with 8 in flashback. Temperatures above 120 F may cause cans to burst. No information available Decomposition temperature Odor No information available No information available Kinematic viscosity Citrus odor No information available Evaporation Rate Dynamic viscosity Faster than butyl acetate No information available Property Values No information available Flammability (solid, gas) FG 438-5149-11 CHAMPION SPRAYON X-IT-OUT VANDAL MARK REMOVER No information available Remarks • Method Flammability Limits in Air No information available pH Upper flammability limits Not available Not applicable Color light yellow Lower Flammability Limit Not available Solvent-based product. Not applicable no data available Vapor pressure Appearance No information available Melting point/freezing point Not applicable Vapor Density Yellowish liquid No information available Specific gravity 0.910 to 0.920 concentrate No information available No information available Odor threshold No information available Water solubility Insoluble in water Boiling point/boiling range No information available Heavy Aromatic Solvent Naphtha 363-401 °F 183-205°C Solubility in other solvents No information available Page 52 of 328 Page 52 of 328 Page 52 of 328 Page 52 of 328 ---PAGE BREAK--- Product Information This product has not been tested as whole. See below for information on ingredients. inhalation no data available. Eye Contact no data available. Skin contact no data available. INGESTION no data available. Chemical name Oral LD50 dermal LD50 Inhalation LC50 Naphtha (petroleum), heavy aromatic 64742-94-5 > 5000 mg/kg ( Rat ) > 2 mL/kg ( Rabbit ) > 590 mg/m3 ( Rat ) 4 h Toluene 108-88-3 = 2600 mg/kg ( Rat ) = 12000 mg/kg ( Rabbit ) = 12.5 mg/L ( Rat ) 4 h Acetone 67-64-1 = 5800 mg/kg ( Rat ) - = 50100 mg/m3 ( Rat ) 8 h Dimethyl Glutarate 1119-40-0 = 8191 mg/kg ( Rat ) - > 5.6 mg/L ( Rat ) 4 h Pine Oil 8002-09-3 = 3200 mg/kg ( Rat ) = 5 g/kg ( Rabbit ) - Methyl alcohol 67-56-1 = 6200 mg/kg ( Rat ) = 15800 mg/kg ( Rabbit ) = 22500 ppm ( Rat ) 8 h = 64000 ppm ( Rat ) 4 h Naphthalene 91-20-3 = 490 mg/kg ( Rat ) = 1110 mg/kg ( Rat ) > 20 g/kg ( Rabbit ) = 1120 mg/kg ( Rabbit ) > 340 mg/m3 ( Rat ) 1 h Cocamide diethanolamine 68603-42-9 = 12400 µL/kg ( Rat ) - - D-Limonene 5989-27-5 = 4400 mg/kg ( Rat ) > 5 g/kg ( Rabbit ) - Information on toxicological effects Inhalation of high vapor concentrations may cause like headache, dizziness, tiredness, nausea and vomiting. Delayed and immediate effects as well as chronic effects from short and long-term exposure Skin corrosion/irritation May cause skin irritation and reddening after prolonged or repeated contact with skin. Serious eye damage/eye irritation Irritating to eyes. irritation May cause skin and eye irritation. corrosivity Not applicable. sensitization No information available. Germ Cell Mutagenicity No information available. carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical name ACGIH IARC NTP OSHA Toluene 108-88-3 Group 3 Naphthalene 91-20-3 A3 Group 2A Group 2B Reasonably Anticipated X Cocamide diethanolamine 68603-42-9 Group 2B X D-Limonene 5989-27-5 Group 2A Group 3 X Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Aspiration Hazard No information available. Numerical measures of toxicity - Product Information Unknown acute toxicity - Page 7 / 12 FG 438-5149-11 CHAMPION SPRAYON X-IT-OUT VANDAL MARK REMOVER Page 53 of 328 Page 53 of 328 Page 53 of 328 Page 53 of 328 ---PAGE BREAK--- The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 1291 mg/kg ATEmix (dermal) 2054 mg/kg ATEmix (inhalation-gas) 393 mg/l ATEmix (inhalation-dust/mist) 1.9 mg/l ATEmix (inhalation-vapor) 12 mg/l 12. Ecological Information This product contains chemicals which are listed as a marine pollutants according to DOT. ecotoxicity 12.996% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical name Algae/aquatic plants Fish Toxicity to Microorganisms Crustacea Naphtha (petroleum), heavy aromatic 64742-94-5 2.5: 72 h Skeletonema costatum mg/L EC50 41: 96 h Pimephales promelas mg/L LC50 1740: 96 h Lepomis macrochirus mg/L LC50 static 2.34: 96 h mykiss mg/L LC50 45: 96 h Pimephales promelas mg/L LC50 flow-through 19: 96 h Pimephales promelas mg/L LC50 static 0.95: 48 h Daphnia magna mg/L EC50 Toluene 108-88-3 433: 96 h Pseudokirchneriella subcapitata mg/L EC50 12.5: 72 h Pseudokirchneriella subcapitata mg/L EC50 static 15.22 - 19.05: 96 h Pimephales promelas mg/L LC50 flow-through 12.6: 96 h Pimephales promelas mg/L LC50 static 5.89 - 7.81: 96 h mykiss mg/L LC50 flow-through 54: 96 h Oryzias latipes mg/L LC50 static 11.0 - 15.0: 96 h Lepomis macrochirus mg/L LC50 static 28.2: 96 h Poecilia reticulata mg/L LC50 semi-static 50.87 - 70.34: 96 h Poecilia reticulata mg/L LC50 static 14.1 - 17.16: 96 h mykiss mg/L LC50 static 5.8: 96 h mykiss mg/L LC50 semi-static EC50 = 19.7 mg/L 30 min 5.46 - 9.83: 48 h Daphnia magna mg/L EC50 Static 11.5: 48 h Daphnia magna mg/L EC50 Acetone 67-64-1 6210 - 8120: 96 h Pimephales promelas mg/L LC50 static 4.74 - 6.33: 96 h mykiss mL/L LC50 8300: 96 h Lepomis macrochirus mg/L LC50 EC50 = 14500 mg/L 15 min 10294 - 17704: 48 h Daphnia magna mg/L EC50 Static 12600 - 12700: 48 h Daphnia magna mg/L EC50 Dimethyl Glutarate 1119-40-0 19.6 - 26.2: 96 h Pimephales promelas mg/L LC50 static 122.1 - 163.5: 48 h Daphnia magna mg/L EC50 Pine Oil 8002-09-3 17 - 28: 48 h Daphnia magna mg/L EC50 Flow through Methyl alcohol 67-56-1 28200: 96 h Pimephales promelas mg/L LC50 flow-through 100: 96 h Pimephales promelas mg/L LC50 static 19500 - 20700: 96 h mykiss mg/L LC50 flow-through 18 - 20: 96 h mykiss mL/L LC50 static 13500 - 17600: 96 h EC50 = 39000 mg/L 25 min EC50 = 40000 mg/L 15 min EC50 = 43000 mg/L 5 min Page 8 / 12 FG 438-5149-11 CHAMPION SPRAYON X-IT-OUT VANDAL MARK REMOVER Page 54 of 328 Page 54 of 328 Page 54 of 328 Page 54 of 328 ---PAGE BREAK--- Lepomis macrochirus mg/L LC50 flow-through Naphthalene 91-20-3 0.4: 72 h Skeletonema costatum mg/L EC50 5.74 - 6.44: 96 h Pimephales promelas mg/L LC50 flow-through 1.6: 96 h mykiss mg/L LC50 flow-through 0.91 - 2.82: 96 h mykiss mg/L LC50 static 1.99: 96 h Pimephales promelas mg/L LC50 static 31.0265: 96 h Lepomis macrochirus mg/L LC50 static EC50 = 0.93 mg/L 30 min EC50 > 20 mg/L 18 h 2.16: 48 h Daphnia magna mg/L LC50 1.96: 48 h Daphnia magna mg/L EC50 Flow through 1.09 - 3.4: 48 h Daphnia magna mg/L EC50 Static Cocamide diethanolamine 68603-42-9 3.6: 96 h Brachydanio rerio mg/L LC50 semi-static 4.2: 24 h Daphnia magna mg/L EC50 D-Limonene 5989-27-5 0.619 - 0.796: 96 h Pimephales promelas mg/L LC50 flow-through 35: 96 h mykiss mg/L LC50 Persistence and degradability No information available. Bioaccumulation No information available. Chemical name Partition coefficient Naphtha (petroleum), heavy aromatic 64742-94-5 2.9 - 6.1 Toluene 108-88-3 2.65 Acetone 67-64-1 -0.24 Methyl alcohol 67-56-1 -0.77 Naphthalene 91-20-3 3.3 Other adverse effects No information available Ozone This product does not contain CFCs or other ozone depleting substances. Federal regulations prohibit the use CFC propellants in aerosols. 13. Disposal Considerations Waste treatment methods Disposal of wastes Dispose of in accordance with federal, state and local regulations. Contaminated packaging Pressurized container: Do not pierce or burn, even after use. Do not puncture or incinerate container. If empty: Place in trash or offer for recycling if available. If partly filled: Call your local solid waste agency for disposal instructions. Chemical name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes Toluene 108-88-3 U220 Included in waste streams: F005, F024, F025, F039, K015, K036, K037, K149, K151 U220 Acetone 67-64-1 Included in waste stream: F039 U002 Methyl alcohol 67-56-1 Included in waste stream: F039 U154 Naphthalene 91-20-3 U165 Included in waste streams: F024, F025, F034, F039, K001, K035, K060, K087, U165 Page 9 / 12 FG 438-5149-11 CHAMPION SPRAYON X-IT-OUT VANDAL MARK REMOVER Page 55 of 328 Page 55 of 328 Page 55 of 328 Page 55 of 328 ---PAGE BREAK--- K145 Chemical name RCRA - Halogenated Organic Compounds RCRA - P Series Wastes RCRA - F Series Wastes RCRA - K Series Wastes Toluene 108-88-3 Toxic waste waste number F025 Waste description: Condensed light ends, spent filters and filter aids, and spent desiccant wastes from the production of certain chlorinated aliphatic hydrocarbons, by free radical catalyzed processes. These chlorinated aliphatic hydrocarbons are those having carbon chain ranging from one to and including five, with varying amounts and positions of chlorine substitution. Naphthalene 91-20-3 Toxic waste waste number F025 Waste description: Condensed light ends, spent filters and filter aids, and spent desiccant wastes from the production of certain chlorinated aliphatic hydrocarbons, by free radical catalyzed processes. These chlorinated aliphatic hydrocarbons are those having carbon chain ranging from one to and including five, with varying amounts and positions of chlorine substitution. Chemical name California Hazardous Waste Status Toluene 108-88-3 Toxic Ignitable Acetone 67-64-1 Ignitable Methyl alcohol 67-56-1 Toxic Ignitable Naphthalene 91-20-3 Toxic D-Limonene 5989-27-5 Toxic 14. Transport Information DOT Limited Quantity - Graffiti Remover UN/ID no UN1950 Proper Shipping Name Limited quantity (LQ) Hazard Class 2.2 Marine pollutant This product contains chemicals which are listed as a marine pollutants according to DOT. Page 10 / 12 FG 438-5149-11 CHAMPION SPRAYON X-IT-OUT VANDAL MARK REMOVER Page 56 of 328 Page 56 of 328 Page 56 of 328 Page 56 of 328 ---PAGE BREAK--- 15. Regulatory information International Inventories TSCA All ingredients of this product are listed or are excluded from listing under the U.S. Toxic Subtances Control Act (TSCA) Chemical Substance Inventory. DSL All ingredients are listed or are excluded from listing on the DSL. Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List US Federal Regulations SARA 313 This product contains the following toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 and 40 CFR 372. This information must be included in all SDSs that are copied and distributed for this material. Chemical name CAS No weight-% SARA 313 - Threshold Values % Toluene - 108-88-3 108-88-3 15-20 1.0 Methyl alcohol - 67-56-1 67-56-1 <3 1.0 Naphthalene - 91-20-3 91-20-3 1-2 0.1 SARA 311/312 Hazard Categories Acute Health Hazard yes Chronic Health Hazard yes Fire Hazard yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Toluene 108-88-3 1000 lb X X X Naphthalene 91-20-3 100 lb X X X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) Toluene 108-88-3 1 lb RQ 1 lb final RQ RQ 0.454 kg final RQ Acetone 67-64-1 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ Methyl alcohol 67-56-1 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ Naphthalene 91-20-3 1 lb RQ 1 lb final RQ RQ 0.454 kg final RQ US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals. Chemical name California Proposition 65 Toluene - 108-88-3 Developmental Female Reproductive Methyl alcohol - 67-56-1 Developmental Page 11 / 12 FG 438-5149-11 CHAMPION SPRAYON X-IT-OUT VANDAL MARK REMOVER Page 57 of 328 Page 57 of 328 Page 57 of 328 Page 57 of 328 ---PAGE BREAK--- Naphthalene - 91-20-3 Carcinogen Cocamide diethanolamine - 68603-42-9 Carcinogen U.S. State Right-to-Know Regulations Chemical name New Jersey Massachusetts Toluene 108-88-3 X X X Acetone 67-64-1 X X X Carbon Dioxide 124-38-9 X X X Pine Oil 8002-09-3 X Methyl alcohol 67-56-1 X X X Naphthalene 91-20-3 X X X U.S. EPA Label information EPA Pesticide registration number Not applicable 16. Other information Prepared by Regulatory Department Issue date 17-Mar-2015 Revision note This SDS supercedes a previous MSDS dated: September 10, 2013 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 12 / 12 Physical and chemical properties Not applicable HMIS FG 438-5149-11 CHAMPION SPRAYON X-IT-OUT VANDAL MARK REMOVER Health Hazards 2* Health Hazards 2 Flammability 4 Physical Hazards 1 Personal Protection B Flammability 4 Instability 1 NFPA Page 58 of 328 Page 58 of 328 Page 58 of 328 Page 58 of 328 ---PAGE BREAK--- Page 59 of 328 Page 59 of 328 Page 59 of 328 Page 59 of 328 ---PAGE BREAK--- Page 60 of 328 Page 60 of 328 Page 60 of 328 Page 60 of 328 ---PAGE BREAK--- Page 61 of 328 Page 61 of 328 Page 61 of 328 Page 61 of 328 ---PAGE BREAK--- Page 62 of 328 Page 62 of 328 Page 62 of 328 Page 62 of 328 ---PAGE BREAK--- Page 63 of 328 Page 63 of 328 Page 63 of 328 Page 63 of 328 ---PAGE BREAK--- Page 64 of 328 Page 64 of 328 Page 64 of 328 Page 64 of 328 ---PAGE BREAK--- Page 65 of 328 Page 65 of 328 Page 65 of 328 Page 65 of 328 ---PAGE BREAK--- Page 66 of 328 Page 66 of 328 Page 66 of 328 Page 66 of 328 ---PAGE BREAK---                     % &                ! "      888/3++/     /     0245120,( 3   6 ("03                 03 38      0%#2!3  Page 67 of 328 Page 67 of 328 Page 67 of 328 Page 67 of 328 ---PAGE BREAK--- CTC 75W-90 GEAR OIL 460-721 Revision Number: 4   2%       3 36 56 4  8    6          38   2     ) 3       42 #  11(21(# % ! ( 0 *%#2!241 (02!  1(2%  1    A8 B 002%     *  A  Page 68 of 328 Page 68 of 328 Page 68 of 328 Page 68 of 328 ---PAGE BREAK--- CTC 75W-90 GEAR OIL 460-721 Revision Number: 4    3   36  3  01#( 36 3       % 3  11 ( 3 ( 0 2 EF 2# A 00,(  & -02 A    0  1 %  - 13 11 - A#0*20#%+3 $1 ( 3 12( % ,  2 44#*# FB'3 B % 2  ? !%03 97 3   - 3 6  *   3  6 *2$120#%#2!  % 03 2   0245120,( 3       *%03  67  67   44 *%03      Page 69 of 328 Page 69 of 328 Page 69 of 328 Page 69 of 328 ---PAGE BREAK--- CTC 75W-90 GEAR OIL 460-721 Revision Number: 4    3   "   7      ! # 00#4#*     00#4#  6 24%        %,03    ?#0#2!03  Page 70 of 328 Page 70 of 328 Page 70 of 328 Page 70 of 328 ---PAGE BREAK--- Revision Date: 04-Mar-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: DEFOAMER Product Number: 3024 Recommended Use: Defoamer Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification Not Classified Not dangerous according to the Globally Harmonized System (GHS) GHS Label Elements Signal Word: No signal word Hazard Statements: No hazard statements Precautionary Statements: Prevention: Not Applicable Response: -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Not Applicable Disposal: Not Applicable Hazards Not Otherwise Classified: Not Applicable Other Information: • May be harmful if swallowed. • May cause eye irritation. • May cause skin irritation. • Keep out of reach of children. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 60-100 organosiloxane PROPRIETARY 1-5 Page 1 / 4 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. Symbols: Page 71 of 328 Page 71 of 328 Page 71 of 328 Page 71 of 328 ---PAGE BREAK--- 3024 - DEFOAMER Revision Date: 04-Mar-2015 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Product does not support combustion, Use extinguishing agent suitable for type of surrounding fire Specific Hazards Arising from the Chemical: Dried product is capable of burning. Combustion products are toxic. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Cool fire-exposed containers with water spray. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 7. HANDLING AND STORAGE Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Storage Conditions: Keep containers closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep from freezing. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: None established. Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Personal Protective Equipment Eye/Face Protection: Not required with expected use. Skin and Body Protection: Not required with expected use. Respiratory Protection: Page 2 / 4 Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. Page 72 of 328 Page 72 of 328 Page 72 of 328 Page 72 of 328 ---PAGE BREAK--- 3024 - DEFOAMER Revision Date: 04-Mar-2015 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatible Materials: Strong oxidizing agents. Strong acids. Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Pain and redness. -Skin Contact: Drying of the skin. -Inhalation: Nasal discomfort and coughing. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. Data not available or insufficient for classification. Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence and Degradability: No information available. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Liquid Color: White emulsion Odor: Bland pH: 9.0-10.0 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 100 °C / 212 °F Flash Point: > 100 °C / > 212 °F ASTM D56 Evaporation Rate: < 1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 1.00 Solubility(ies): Miscible in water Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 3 / 4 Decomposition Temperature: No information available. Viscosity: No information available. Page 73 of 328 Page 73 of 328 Page 73 of 328 Page 73 of 328 ---PAGE BREAK--- 3024 - DEFOAMER Revision Date: 04-Mar-2015 Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT: Not Regulated Proper Shipping Name: Non-Hazardous Product 15. REGULATORY INFORMATION TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product does not contain listed substances above the "de minimus" level SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: No Reactive Hazard: No California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 formaldehyde - 50-00-0 Carcinogen methanol - 67-56-1 Developmental ethyl acrylate - 140-88-5 Carcinogen WARNING: This product contains a chemical known to the State of California to cause cancer. WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. 16. OTHER INFORMATION Revision Date: 04-Mar-2015 Reasons for Revision: No information available. Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 1 Flammability: 0 Instability: 0 Special: N/A HMIS Page 4 / 4 Health Hazards: 1 Flammability: 0 Physical Hazards: 0 Page 74 of 328 Page 74 of 328 Page 74 of 328 Page 74 of 328 ---PAGE BREAK--- Common Name: DETAIL DEMON AUTO FINISH CLEANER/POLISH Manufacturer: NYCO PRODUCTS MSDS Revision Date: 1/6/2011 Grainger Item Number(s): 11U479 Manufacturer Model Number(s): MSDS Table of Contents Click the desired link below to jump directly to that section in the MSDS. SECTION I - PRODUCT IDENTITY SECTION II - HAZARDOUS INGREDIENTS SECTION III - CHEMICAL AND PHYSICAL SECTION IV - FIRE AND EXPLOSION HAZARDS SECTION V - REACTIVITY INFORMATION SECTION VI - HEALTH HAZARDS - PROTECTIVE MEASURES - FIRST AID SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE SECTION VIII - REGULATORY INFORMATION MATERIAL SAFETY DATA SHEET MSDS NO.: N524 NYCO PRODUCTS CO. 5332 DANSHER ROAD ILLINOIS 60525 EMERGENCY PHONES: [PHONE REDACTED] (NYCO) [PHONE REDACTED] (CHEMTREC) REVISION DATE: 1/6/2011 SUPERSEDES DATE: 8/8/2005 PLEASE NOTE: THIS MSDS IS BEING PROVIDED TO YOUR COMPANY FOR THE PURPOSE OF PROVIDING CURRENT HEALTH AND SAFETY INFORMATION TO YOUR MANAGEMENT AND FOR YOUR EMPLOYEES WHO WORK WITH THIS MATERIAL. PLEASE READ THE Page 75 of 328 Page 75 of 328 Page 75 of 328 Page 75 of 328 ---PAGE BREAK--- INFORMATION ON THESE SHEETS, AND THEN PROVIDE THIS INFORMATION TO THOSE PEOPLE AT YOUR COMPANY WHOSE RESPONSIBILITY IT IS TO COMPLY WITH FEDERAL AND STATE RIGHT-TO-KNOW REGULATIONS. ALSO MAKE THIS INFORMATION AVAILABLE TO ANY EMPLOYEE WHO REQUESTS IT. IT IS YOUR OBLIGATION TO COMPLY WITH THESE REGULATIONS. SECTION I - PRODUCT IDENTITY PRODUCT NAME: DETAIL DEMON AUTO FINISH CLEANER/POLISH FORMULA: MIXTURE, ADDITIVES AND ALCOHOL IN WATER. CHEMICAL TYPE: AS ABOVE HMIS RATINGS: HEALTH 1 (SLIGHT) FLAMMABILITY 2 (MODERATE) REACTIVITY 0 (MINIMAL) PROTECTION B (GOGGLES & GLOVES) SECTION II - HAZARDOUS INGREDIENTS INGREDIENT PERCENT TLV CARCINOGEN (OSHA, TP, IARC) ISOPROPANOL 400 PPM NO CAS NO.: 67-63-0 STEL: 500 PPM SECTION III - CHEMICAL AND PHYSICAL APPEARANCE: OPAQUE VIOLET LIQUID BOILING POINT: <212 DEG. F ODOR: TUITTI-FRUITTI MELTING POINT: N/A pH: 7.0 - 8.0 SPEC. GRAVITY (H2O = 1.00 WATER SOLUBILITY: COMPLETE VAPOR PRESSURE (MMHg): N/A Page 76 of 328 Page 76 of 328 Page 76 of 328 Page 76 of 328 ---PAGE BREAK--- VISCOSITY @ 25 DEG. C: WATER THIN (BROOKFIELD) VOC CONTENT: 3% SECTION IV - FIRE AND EXPLOSION HAZARDS FLASH POINT (METHOD): 161 DEG. F CL.CP. EXPLOSION LIMITS: UPPER: N/A LOWER: N/A EXTINGUISHING MEDIA: WATER FOG, FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL SPECIAL FIREFIGHTING PROCEDURES AND HAZARDS: TREAT AS A COMBUSTIBLE LIQUID. NOTE: THIS PRODUCT IS COMBUSTIBLE UNDER OSHA CRITERIA, BUT IS NOT REGULATED BY DOT SINCE IT CONTAINS LESS THAN 24% ALCOHOL AND OVER 50% WATER, AND THE OTHER INGREDIENTS DO NOT CONSTITUTE A DOT HAZARD: SEE (CFR 173.115(B)(2)(I) AND (II). SECTION V - REACTIVITY INFORMATION STABLE UNSTABLE ( ) PRECAUTIONS: INCOMPATIBILITY: NONE KNOWN HAZARDOUS DECOMPOSITION PRODUCTS: IF IN A FIRE: CO, CO2, HYDROCARBONS. HAZARDOUS POLYMERIZATION: OCCURS ( ) DOES NOT OCCUR SECTION VI - HEALTH HAZARDS - PROTECTIVE MEASURES - FIRST AID INHALATION: BREATHING OF VAPORS MAY CAUSE DIZZINESS AND SHORTNESS OF BREATH. WEAR Page 77 of 328 Page 77 of 328 Page 77 of 328 Page 77 of 328 ---PAGE BREAK--- APPROVED VAPOR RESPIRATOR IF NEEDED. REMOVE TO FRESH AIR. SKIN: EXTENDED CONTACT MAY CAUSE IRRITATION OR DEFATTING. PROLONGED CONTACT WITH 2-BUTOXYETHANOL MAY RESULT IN THE ABSORPTION OF POTENTIALLY HARMFUL AMOUNTS LEADING TO POSSIBLE LIVER AND KIDNEY DAMAGE. WEAR PROTECTIVE GLOVES IF NEEDED. REMOVE CONTAMINATED CLOTHING & WASH IF NECESSARY BEFORE REUSE. FLUSH SKIN THOROUGHLY WITH WATER FOR 15 MINUTES. EYES: CAN CAUSE IRRITATION. WEAR GOGGLES AS NEEDED. FLUSH IMMEDIATELY WITH WATER FOR 15 MINUTES. GET PROMPT MEDICAL ATTENTION IF NEEDED. INGESTION: MAY CAUSE A MILD GASTRIC DISTURBANCE. DRINK LOTS OF WATER. DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IF EFFECTS PERSIST. MOST LIKELY ROUTES OF ENTRY: SKIN, EYES. OTHER IMPORTANT MEDICAL OR PRECAUTIONARY INFORMATION: NONE SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE SPILLS AND LEAKS: SMALL SPILLS CAN BE FLUSHED INTO NORMAL DRAINAGE OR INTO GROUND WITH COPIOUS AMOUNTS OF WATER, OR TAKEN UP WITH ABSORBENT MATERIAL. LARGER SPILLS SHOULD BE CONTAINED BY DIKING OR OTHER METHODS AND HELD FOR DISPOSAL OR REUSE. REMOVE ALL SOURCES OF IGNITION. PROVIDE STRONG VENTILATION. STORAGE AND HANDLING: CHECK DAILY FOR ANY LEAKS FROM CONTAINERS, VESSELS, PUMPS, AND PIPING. KEEP AWAY FROM SOURCES OF IGNITION. KEEP AT TEMPERATURES BELOW 95 DEG. F. WASTE DISPOSAL: COLLECT IN CLOSED CONTAINERS AND SEND TO A LICENSED TREATMENT OR DISPOSAL FACILITY. EMPTY CONTAINERS: RINSE WELL BEFORE HANDLING AND DISPOSAL. OBSERVE LABEL PRECAUTIONS. DO NOT Page 78 of 328 Page 78 of 328 Page 78 of 328 Page 78 of 328 ---PAGE BREAK--- CUT, WELD OR BURN. OTHER PRECAUTIONS: NONE SECTION VIII - REGULATORY INFORMATION REPORTABLE FOR SARA TITLE III, S.313 (FORM NONE. THE INFORMATION HEREIN HAS BEEN COMPILED FROM SOURCES BELIEVED TO BE RELIABLE AND IS ACCURATE TO THE BEST OF OUR KNOWLEDGE. HOWEVER, NYCO PRODUCTS COMPANY CANNOT GIVE ANY GUARANTEES REGARDING INFORMATION FROM OTHER SOURCES, AND EXPRESSLY DOES NOT MAKE ANY WARRANTIES, NOR ASSUMES ANY LIABILITY, FOR ITS USE. Page 79 of 328 Page 79 of 328 Page 79 of 328 Page 79 of 328 ---PAGE BREAK--- 1 MATERIAL SAFETY DATA SHEET May be used to comply with OSHA’s Hazard Communication Standard 29 CFR 1910.1200. Standard must be consulted for specific requirements. U.S. Department of Labor Occupational Safety and Health Administration (Non-Mandatory Form) Form Approved OMB No. 12180072 IDENTITY (As used on label and list) DG Auto Protectant Note: Blank spaces are not permitted. If any item is not applicable or no information is available, the space must be marked to indicate that. Section I - Manufacturer Manufacturer’s Name: Aiken Chemical Company Emergency Telephone Number 1-[PHONE REDACTED] Address (Number, Street, City, State and Zip Code) P.O. Box 27147 Telephone Number for Information (864)968-1250; 1-[PHONE REDACTED] Greenville, SC 29616 Date Prepared: November 15, 2007 Revision August 30, 2013 12 Shelter Drive, Greer, SC 29650 Signature of Preparer (Optional) Section II – Hazardous Ingredients / Identity Information Hazardous Components (Specific Chemical Identity: Common Name(s) OSHA PEL ACGIH TLV OTHER LIMITS % No Reportable Hazardous Ingredients NFPA HMIS 0-1-0 1-1-0 TCSA Information: All ingredients of this product are either listed on or exempt from the TSCA inventory. Section III – Routes and Effects of Overexposure SKIN: Prolonged or repeated contact can cause slight irritation. EYES: May produce slight oil film causing brief reversible dimness of sight. INGESTION: Amounts transferred to the mouth during normal operations should not cause injury. INHALATION: No irritation to nose or throat expected. Medical Conditions Generally Aggravated by Exposure: Pre-existing skin conditions. Section IV – Emergency and First Aid Procedures SKIN: Remove contaminated clothing. Thoroughly wash exposed area with soap and water for at least 15 minutes. If irritation persists, seek medical attention. EYES: Immediately flush eyes with large amounts of water for at least 15 minutes, lifting upper and lower eyelids periodically to insure complete flushing. If irritation persists, seek medical attention. INGESTION: DO NOT induce vomiting. Dilute by giving large amounts of water. Seek medical attention immediately. INHALATION: No problem is expected from this route of entry. Section V – Fire-Fighting Measures EXTINGUISHING MEDIA: Water fog, alcohol foam, carbon dioxide or dry chemical. SPECIAL FIRE-FIGHTING MEDIA: Use water to keep fire-exposed containers cool until fire is out. UNUSUAL FIRE AND EXPLOSION HAZARDS: None. Product is very slippery – use caution to avoid falls. Section VI – Accidental Release Measures Steps to be Taken in Case Material is Released or Spilled: Stop spill at the source, dike area to prevent spreading. Remaining liquid may be taken up with sand, clay, floor absorbent, or other absorbent material and shoveled into salvage containers. Spilled material is very slippery – use caution to avoid falls. Waste Disposal Method: Dispose of in accordance with all local, state and federal regulations. Precautions to Be Taken in Handling and Storage: Spilled material is slippery on walkways and floors. Remove spills Other Precautions: Protect from freezing. Wear body-covering impervious protective clothing, chemical goggles or safety glasses with side shields and/or face shield and chemical resistant gloves and boots. Page 80 of 328 Page 80 of 328 Page 80 of 328 Page 80 of 328 ---PAGE BREAK--- 2 Section VII – Handling and Storage Handling: Do not get in eyes, on skin or clothing. Do not swallow. Wash thoroughly after handling. Do not allow to freeze. Wash thoroughly after handling. Spills can be slippery – use caution. Storage: Keep in closed containers. Store in a cool area and protect product from freezing. Other Precautions: Containers, even those that have been emptied, can contain product and vapors. Avoid contact with residual product. Clean up spills immediately. Section VIII – Exposure Controls and Personal Protection Respiratory Protection (Specify Type) None needed Ventilation: General Local Exhaust None should be needed Special: NONE Mechanical (General) Other: NONE Protective Gloves No special protection needed Eye Protection Chemical safety glasses with side shields and/or face shield. Other Protective Clothing or Equipment None needed. Always use caution when working with chemicals. Material is slippery if spilled. Work Hygienic Practices Wash hands before eating or smoking. Section IX – Physical / Chemical Characteristics Boiling Point: >200° F Specific Gravity (H20 – 1.015 Vapor Pressure (mm Hg.): Not Determined Melting Point: NA Vapor Density (AIR=1): Not Determined Evaporation Rate (Butyl Acetate=1): <1.0 Solubility in Water: Complete pH: 6.4 Appearance and Odor: Milky white liquid with characteristic scent LEL: UEL: Not Determined Not Determined Flammable Limits: Not Determined Flash Point (Method Used): >200° F (PMCC) Section X – Reactivity Data Stability: Unstable: Conditions to Avoid Mixing or blending with oxidizing or low pH solutions. Stable: X Incompatibility (Materials to Avoid): Avoid contact with reactive metals, strong mineral acids and organic acids. Hazardous Decomposition or Byproducts: Carbon dioxide, carbon monoxide, silicone oxides and various hydrocarbons. Hazardous Polymenzation May Occur Conditions to Avoid None Will Not Occur X Section XI – Toxicological Information None known. Section XII – Ecological Information No data available. Section XIII – Transport Information PROPER SHIPPING NAME: Cleaning Compound, Non-hazardous material, N.O.S. HAZARD CLASS: NA ID NUMBER: NA PACKING GROUP: NA Page 81 of 328 Page 81 of 328 Page 81 of 328 Page 81 of 328 ---PAGE BREAK--- 3 Section XIV – Regulatory Information TSCA Status: All components are listed on the Toxic Substance Control Act Chemical Substances Inventory Section 311 Hazard Category - None Section 313 Toxic Release Inventory Chemical: None listed California Safe Drinking Water Enforcement Act (Prop 65): This product contains no listed substances known to the State of California to cause cancer, birth defects or other reproductive harm at levels which would require a warning under the statute. (Worker and Community Right-to-Know Act): Special Hazardous Substances List: To the best of our knowledge, this product does not contain chemicals that require reporting under this statute. New Jersey Right-to-Know Hazardous Substance List: To the best of our knowledge, this product does not contain chemicals that require reporting under this statute. Massachusetts Substance List: To the best of our knowledge, this product does not contain chemicals that require reporting under this statute. Page 82 of 328 Page 82 of 328 Page 82 of 328 Page 82 of 328 ---PAGE BREAK--- Revision Date: 01-May-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: DUST MOP / DUST CLOTH TREATMENT (AEROSOL) Product Number: 6099 Recommended Use: Cleaning agent Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification GHS Label Elements Signal Word: Danger Hazard Statements: Extremely flammable aerosol. Contains gas under pressure; may explode if heated Precautionary Statements: Prevention: Keep away from heat/sparks/open flames/hot surfaces. — No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Response: -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Protect from sunlight. Do not expose to temperatures exceeding 122°F (50°C) Store in a well-ventilated place Disposal: Not Applicable Hazards Not Otherwise Classified: Not Applicable Flammable Aerosols Category 1 Gases Under Pressure Page 1 / 5 Liquefied gas Symbols: Page 83 of 328 Page 83 of 328 Page 83 of 328 Page 83 of 328 ---PAGE BREAK--- 6099 - DUST MOP / DUST CLOTH TREATMENT (AEROSOL) Revision Date: 01-May-2015 Other Information: • May be harmful if swallowed. • May cause eye irritation. • May cause skin irritation. • Inhalation of vapors or mist may cause respiratory irritation. • Keep out of reach of children. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 40-70 petroleum distillates 64742-47-8 5-10 white mineral oil 8042-47-5 5-10 N-butane 106-97-8 3-7 propane 74-98-6 1-5 decaglyceryl monooleate 9007-48-1 1-5 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Water spray (fog), Foam Specific Hazards Arising from the Chemical: Extremely flammable aerosol. Exposure to high temperature may cause containers to burst. Bursting aerosol containers may be propelled from fire at high speed. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Water may be used to cool closed containers to prevent pressure build-up and possible auto ignition or explosion when exposed to extreme heat. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 7. HANDLING AND STORAGE Page 2 / 5 Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Wash thoroughly after handling. Page 84 of 328 Page 84 of 328 Page 84 of 328 Page 84 of 328 ---PAGE BREAK--- 6099 - DUST MOP / DUST CLOTH TREATMENT (AEROSOL) Revision Date: 01-May-2015 Storage Conditions: NFPA 30B Level 1 Aerosol. Do not store in direct sunlight or above 122 F° / 50 Exposure to high temperature may cause containers to burst. Keep out of the reach of children. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: . Chemical Name ACGIH TLV OSHA PEL NIOSH N-butane 106-97-8 TWA: 1000 ppm (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 TWA: 800 ppm TWA: 1900 mg/m3 propane 74-98-6 TWA: 1000 ppm TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Personal Protective Equipment Eye/Face Protection: Not required with expected use. Skin and Body Protection: Not required with expected use. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatible Materials: Strong oxidizing agents. Strong acids. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Aerosol Color: White emulsion Odor: Bland pH: 8.0-9.0 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 132 °C / 270 °F (Product without propellant) Estimated Flash Point: < -58 °C / < -72 °F (Propellant-estimated) Evaporation Rate: < 1 Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 0.95 (Product without propellant) Solubility(ies): No information available. Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 3 / 5 Decomposition Temperature: No information available. Viscosity: No information available. Page 85 of 328 Page 85 of 328 Page 85 of 328 Page 85 of 328 ---PAGE BREAK--- 6099 - DUST MOP / DUST CLOTH TREATMENT (AEROSOL) Revision Date: 01-May-2015 Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Pain and redness. -Skin Contact: Drying of the skin. -Inhalation: Nasal discomfort and coughing. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Target Organ Effects: Central nervous system. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 27233 mg/kg ATEmix (dermal): 20202 mg/kg ATEmix (inhalation-gas): 3021468 mg/l Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available petroleum distillates 64742-47-8 > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5.2 mg/L ( Rat ) 4 h white mineral oil 8042-47-5 > 5000 mg/kg ( Rat ) Not Available Not Available N-butane 106-97-8 Not Available Not Available = 658 mg/L ( Rat ) 4 h propane 74-98-6 Not Available Not Available = 658 mg/L ( Rat ) 4 h Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Microorganisms Crustacea petroleum distillates 64742-47-8 Not Available 45: 96 h Pimephales promelas mg/L LC50 flow-through 2.2: 96 h Lepomis macrochirus mg/L LC50 static 2.4: 96 h mykiss mg/L LC50 static Not Available 4720: 96 h Den-dronereides heteropoda mg/L LC50 white mineral oil 8042-47-5 Not Available 10000: 96 h Lepomis macrochirus mg/L LC50 Not Available Not Available Persistence and Degradability: No information available. Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Page 4 / 5 Contaminated Packaging: Pressurized container: Do not pierce or burn, even after use. Dispose of in accordance with federal, state and local regulations. Page 86 of 328 Page 86 of 328 Page 86 of 328 Page 86 of 328 ---PAGE BREAK--- 6099 - DUST MOP / DUST CLOTH TREATMENT (AEROSOL) Revision Date: 01-May-2015 14. TRANSPORT INFORMATION DOT: UN/ID No: UN1950 Proper Shipping Name: Aerosols Hazard Class: 2.1 Special Provisions: This product meets the exception requirements of section 49 CFR 173.306 as a limited quantity and may be shipped as a limited quantity. 15. REGULATORY INFORMATION TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product does not contain listed substances above the "de minimus" level SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: Yes Reactive Hazard: No California Proposition 65 This product does not contain any Proposition 65 chemicals 16. OTHER INFORMATION Revision Date: 01-May-2015 Reasons for Revision: No information available. Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 1 Flammability: 1 Instability: 0 Special: N/A HMIS Page 5 / 5 Health Hazards: 1 Flammability: 2 Physical Hazards: 2 Page 87 of 328 Page 87 of 328 Page 87 of 328 Page 87 of 328 ---PAGE BREAK--- ENERGINE® SPOT REMOVER Not available. Not available. Chemtrec: 1-[PHONE REDACTED] (U.S. & Canada) Outside the U.S & Canada (North America), call: [PHONE REDACTED] Reckitt Benckiser North America, Inc. Morris Corporate Center IV 399 Interpace Parkway (P.O. Box 225) Parsippany, N.J. 07054-0225 Material Safety Data Sheet Section 1. Product and Company Identification Product Name MSDS# Validation Date Print Date In case of Emergency: Manufacturer Product Description 6/6/2006 6/6/2006 Product Identifier Not available. Telephone: [PHONE REDACTED] Transportation Emergencies: Item Number Formula Number 117-092 (F/F 354040) 354040 UPC Number 19200-00441 (8 fl. oz. / 237 ml.) Section 2. Composition and Information on Ingredients 1) NAPHTHA (PETROLEUM), LIGHT ALPHATIC 64742-89-8 100 TWA: 300 (ppm) from ACGIH (TLV) TWA: 300 STEL: 400 (ppm) from OSHA (PEL) Name CAS # Exposure Limits : TLV/PEL % by Weight Section 3. Hazards Identification Emergency Overview DANGER: Flammable liquid and vapor. Harmful or fatal if swallowed. May cause eye and skin irritation. Contains 100% Naphtha. KEEP OUT OF REACH OF CHILDREN. Section 4. First Aid Measures Eye Contact Skin Contact Inhalation Ingestion If in eyes, immediately flush eyes with water, remove any contact lenses, and continue to flush eyes with plenty of water for at least 15 minutes. If irritation persists, get medical attention. If on skin, remove contaminated clothing and flush skin with plenty of soap and water. Move user to fresh air and maintain respiration. Call a poison center or physician immediately. If swallowed, DO NOT induce vomiting. Call physician or poison control center immediately. Note to Physician: This product contains petroleum distillates. A severe lung aspiration hazard exists. Flammable. See Section 14 for any Shipping Classifications. Not available. CLOSED CUP: 12.778°C (55°F). (Tagliabue). Not available. Section 5. Fire and Explosion Data Flammability Flash Point Explosive Limits in Air Products of Combustion Continued on Next Page Page 88 of 328 Page 88 of 328 Page 88 of 328 Page 88 of 328 ---PAGE BREAK--- ENERGINE® SPOT REMOVER Page Number: 2 Use water fog, foam, dry chemical or CO2. Do not use a direct stream of water. Product will float and can be reignited on surface of water. Containers exposed to intense heat from fires should be cooled with water to prevent vapor pressure build-up which could result in container rupture. Areas with storage of large concentration of containers exposed to direct flame contact should be cooled with large quantities of water as needed to prevent weakening of container structure. Vapors may cause flash fire. Fire and Explosion Hazards Fire Fighting Media and Instructions Wear self-contained breathing apparatus and protective clothing appropriate for fighting a chemical fire. Special Fire Fighting Instructions DANGER: Flammable liquid and vapor. Vapors may cause flash fire. Keep away from heat, spark, open flame, electrical motors, and outlets, pilot lights, lighted cigarettes or other ignition sources during use and until all vapors are gone. Use only with good ventilation - provide constant flow of fresh air. Take up spills with an absorbent material and place in non-leaking containers. Seal for proper disposal. Section 6. Accidental Release Measures Accidental Spill Section 7. Handling and Storage Handling and Storage DANGER: FLAMMABLE LIQUID AND VAPOR. HARMFUL OR FATAL IF SWALLOWED. MAY CAUSE EYE AND SKIN IRRITATION. Contains 100% Naphtha. Do not store or use near heat, sparks or flame. Vapors may cause flash fire. Keep away from heat, sparks, open flame, electrical motors and outlets, pilot lights, lighted cigarettes or other ignition sources during use and until all vapors are gone. Use only with good ventilation - provide constant flow of fresh air. Avoid repeated or prolonged breathing of vapors. Avoid contact with eyes or skin. Close container after each use and store only with container closed. Intentional misuse by deliberately concentrating or inhaling the contents may be harmful or fatal. Repeated prolonged over-exposure to Naphtha has been associated with neurological damage. KEEP OUT OF REACH OF CHILDREN. Section 8. Exposure Controls/Personal Protection Ventilation Requirements Use only with adequate ventilation, provide a constant flow of fresh air. May cause eye irritation. Do not get in eyes. Emergency responders should wear full eye and face protection. Wash thoroughly with soap and water after handling. Emergency responders should wear impermeable clothing and footwear when responding to a situation where contact with the liquid is possible. Work/Hygienic Practices Respiratory Protection Other Protection Eye Protection Skin Protection May cause skin irritation after prolonged or repeated use. Avoid skin contact. Emergency responders should wear impermeable gloves. Avoid repeated or prolonged breathing of vapor. In case of insufficient ventilation, wear suitable respiratory equipment. Emergency responders should wear suitable respiratory protection where long term exposure to large areas of spilled liquid is possible such as a major spill, a fire or a clean-up operation. 129.44°C (265°F) Thin liquid. Not available. 0.75 3.8 26mm Hg @ 100°F Negligible Hydrocarbon. Off-white. Pale color. Section 9. Physical and Chemical Properties Description Odor Color pH Boiling/Condensation Point Specific Gravity Vapor Pressure Vapor Density Solubility Not available. Viscosity Not available. Physical Chemical Comments Continued on Next Page Page 89 of 328 Page 89 of 328 Page 89 of 328 Page 89 of 328 ---PAGE BREAK--- ENERGINE® SPOT REMOVER Page Number: 3 The product is stable. Strong oxidizing agents. Will not occur. Carbon monoxide, carbon dioxide and unidentified organic compounds. Keep away from heat, spark, open flame, electrical motors, and outlets, pilot lights, lighted cigarettes or other ignition sources during use. Section 10. Stability and Reactivity Data Chemical Stability Conditions of Instability Incompatibility with Various Substances Hazardous Decomposition Products Hazardous Polymerization Carcinogenicity: NTP: No IARC: No OSHA: No. Repeated prolonged over exposure to Naphtha has been associated with neurological damage. Section 11. Toxicological Information Exposure effects Carcinogenicity Harmful or fatal if swallowed. Use only with adequate ventilation, provide a constant flow of fresh air during use. Avoid repeated or prolonged breathing of vapor. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Inhalation Ingestion Eye Contact May cause eye irritation. Skin Contact May cause skin irritation. Not available. Section 12. Ecological Information Ecotoxicity Dispose of in accordance with local, state and federal regulations. None of the ingredients in this product are listed under the SARA Title III, Section 313 List of Toxic Chemicals. Section 13. Disposal Considerations Waste Disposal DOT Classification UN1268, Petroleum distillates, n.o.s. (Naptha Petroleum) Class 3, PG II - Limited Quantity. [FP 12.778º C / 55º F, Closed Cup] Re-Classed as Consumer Commodity ORM-D. Not applicable. Not applicable. Section 14. Transport Information DOT Identification Number Special Provisions for Transport Consumer Commodity Not applicable. Not applicable. Proper Shipping Name Packing Group Hazardous Substances Reportable Quantity UN1268, Petroleum distillates, n.o.s. (Naptha Petroleum) Class 3, PG II - Limited Quantity. [FP 12.778º C / 55º F, Closed Cup] Re-Classed as Consumer Commodity ORM-D. TDG Classification Maritime Transportation Not applicable. ADR Classification Not applicable. Continued on Next Page Page 90 of 328 Page 90 of 328 Page 90 of 328 Page 90 of 328 ---PAGE BREAK--- ENERGINE® SPOT REMOVER Page Number: 4 IMDG Classification UN1268, Petroleum distillates, n.o.s. (Naptha Petroleum) Class 3, PG II - Limited Quantity. [FP 12.778º C / 55º F, Closed Cup] UN1268, Petroleum distillates, n.o.s. (Naptha Petroleum) Class 3, PG II - Limited Quantity. Or: Consumer Commodity, ID 8000. IATA Classification WHMIS CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). WHMIS CLASS D-2A: Material causing other toxic effects (VERY TOXIC). Other Classifications WHMIS (Canada) Federal and State Regulations Section 15. Regulatory Information None None California Proposition 65: This product contains the following ingredients which require a warning under the Safe Drinking Water & Toxic Enforcement Act: SARA Title III, Section 313 Toxic Chemical Notification & Release Reporting: Notice to Reader Printed 6/6/2006. Validated by Product Safety on 6/6/2006. Section 16. Other Information HMIS 0 3 2 National Fire Protection Association Health Fire Hazard Reactivity Specific hazard 2 3 0 D Health Hazard Fire Hazard Reactivity Personal Protection To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. NFPA Aerosol Level Not applicable. Page 91 of 328 Page 91 of 328 Page 91 of 328 Page 91 of 328 ---PAGE BREAK--- Material Safety Data Sheet EUCO DIAMOND HARD Version 3.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012 1/5 59H 55 SECTION 1 - PRODUCT IDENTIFICATION Trade name : EUCO DIAMOND HARD Product code : 59H 55 COMPANY : Euclid Chemical Company 19218 Redwood Road Cleveland, OH 44110 Telephone : 1-[PHONE REDACTED] Emergency Phone: : U.S. only: 1-[PHONE REDACTED] International Users Call Collect: 1-[PHONE REDACTED] Product use : Sealer SECTION 2 - HAZARDS IDENTIFICATION Emergency Overview Clear. Liquid. May cause mucous membrane irritation. Leave area to breathe fresh air. Avoid further overexposure. If persist, get medical attention. Acute Potential Health Effects/ Routes of Entry Inhalation : May cause mucous membrane irritation. Eyes : May cause irreversible damage and burns to the eyes. Ingestion : May cause burns to lips, tongue, oral mucosa, esophagus and stomach. Skin : May cause severe burns, blistering and skin damage. Aggravated Medical Conditions Pre-existing eye, skin and respiratory disorders may be aggravated by exposure. Chronic Health Effects Fillers are encapsulated and not expected to be released from product under normal conditions of use. Target Organs: Skin, Eye, Lung SECTION 3 - PRODUCT COMPOSITION Chemical Name CAS-No. Weight % Water 7732-18-5 > 60.0 Sodium silicate 1344-09-8 15.0 - 40.0 Potassium 31795-24-1 5.0 - 10.0 SECTION 4 - FIRST AID MEASURES Get immediate medical attention for any significant overexposure. Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If persist, get medical attention. Eye contact : Flush with water for 15 minutes. If irritation persists, get medical attention. Page 92 of 328 Page 92 of 328 Page 92 of 328 Page 92 of 328 ---PAGE BREAK--- Material Safety Data Sheet EUCO DIAMOND HARD Version 3.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012 2/5 59H 55 Skin contact : Wash area of contact thoroughly with hand cleaner followed by soap and water. If irritation, rash or other disorders develop, get medical attention immediately. Ingestion : Get medical attention. Do not induce vomiting. Notes to physician : Not applicable. SECTION 5 - FIRE FIGHTING MEASURES Flash point : Not available. Method : Not available. Lower explosion limit : Not available. Upper explosion limit : Not available. Autoignition temperature : Not available. Extinguishing media : This product is not expected to burn under normal conditions of use. Hazardous combustion products : Carbon monoxide and carbon dioxide can form.Hydrogen chloride.Smoke, fumes. Protective equipment for firefighters : Use accepted fire fighting techniques. Wear full firefighting protective clothing, including self-contained breathing apparatus (SCBA). Fire and explosion conditions : This product not expected to ignite under normal conditions of use. SECTION 6 - ACCIDENTAL RELEASE MEASURES Transfer to appropriate container for disposal. Stop flow. Contain spill. Keep out of water courses. Absorb spill in sand, earth or other suitable material. Transfer to appropriate container for disposal. Use appropriate protective equipment. Avoid contact with material. SECTION 7 - HANDLING AND STORAGE Handle in compliance with common hygienic practices. Clean hands thoroughly after handling. Keep from freezing. Do not use in confined or poorly ventilated areas. Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed when not in use. Precautions also apply to emptied containers. Store in sealed containers in a dry, ventilated warehouse location above freezing. SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION Personal protection equipment Respiratory protection : Not required under normal conditions of use.Wear appropriate, NIOSH/MSHA approved respirator with combination particulate filter and vapor/gas removing cartridge when the ventilation is not adequate or if it is necessary to abrade or grind surfaces coated with this product. Hand protection : Use suitable impervious rubber or vinyl gloves and protective apparel to reduce exposure. Eye protection : Wear appropriate eye protection.Wear chemical safety goggles and/or face shield to prevent eye contact. Do not wear contact lenses. Do not touch eyes with contaminated body parts or materials. Have eye washing facilities readily available. Page 93 of 328 Page 93 of 328 Page 93 of 328 Page 93 of 328 ---PAGE BREAK--- Material Safety Data Sheet EUCO DIAMOND HARD Version 3.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012 3/5 59H 55 Skin and body protection : Prevent contact with shoes and clothing. Use rubber apron and overshoes. Protective measures : Other equipment not normally required.Use professional judgment in the selection, care, and use. Engineering measures : Not required under normal conditions of use.Use local exhaust when the general ventilation is inadequate. Exposure Limits No known components with exposure limits. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Form : Liquid Color : Clear Odor : None pH : 12 - 13 Vapour pressure : Not available. Vapor density : Heavier than air Melting point/range : Not available. Freezing point : Not available. Boiling point/range : 212 100 °C Water solubility : Soluble Specific Gravity : 1.175 % Volatile Weight : 76.3 % SECTION 10 - REACTIVITY / STABILITY Substances to avoid : Acids.Metal. Stability : Stable Hazardous polymerization : Will not occur. SECTION 11 - TOXICOLOGICAL INFORMATION Sodium silicate, CAS-No.: 1344-09-8 Acute oral toxicity (LD-50 oral) 1,100 - 1,600 mg/kg ( Rat ) 1,100 mg/kg ( Mouse ) Page 94 of 328 Page 94 of 328 Page 94 of 328 Page 94 of 328 ---PAGE BREAK--- Material Safety Data Sheet EUCO DIAMOND HARD Version 3.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012 4/5 59H 55 SECTION 12 - ECOLOGICAL INFORMATION No Data Available SECTION 13 - DISPOSAL CONSIDERATIONS RCRA Class : D002: Reportable Quantity = 100 lbs. (Characteristic of corrosivity) This classification applies only to the material as it was originally produced. Disposal Method : Subject to hazardous waste treatment, storage, and disposal requirements under RCRA. Recycle or incinerate waste at EPA approved facility or dispose of in compliance with federal, state and local regulations. SECTION 14 - TRANSPORTATION / SHIPPING DATA CFR / DOT: UN1719, Caustic alkali liquids, n.o.s. (Potassium 8, PG III TDG: UN1719, CAUSTIC ALKALI LIQUID, N.O.S. (Potassium 8, PG III IMDG: UN1719, CAUSTIC ALKALI LIQUID, N.O.S. (Potassium 8, PG III Further Information: The above shipping description may not be accurate for all container sizes and all modes of transportation. Please refer to Bill of Lading. SECTION 15 - REGULATORY INFORMATION North American Inventories: All components are listed or exempt from the TSCA inventory. This product or its components are listed on, or exempt from the Canadian Domestic Substances List. U.S. Federal Regulations: SARA 313 Components : None present or none present in regulated quantities. SARA 311/312 Hazards : Acute Health Hazard OSHA Hazardous Components : Sodium silicate 1344-09-8 Potassium 31795-24-1 OSHA Status: Considered hazardous based on the following criteria: : Irritant Corrosive Page 95 of 328 Page 95 of 328 Page 95 of 328 Page 95 of 328 ---PAGE BREAK--- Material Safety Data Sheet EUCO DIAMOND HARD Version 3.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012 5/5 59H 55 OSHA Flammability : Not Regulated Regulatory VOC (less water and exempt solvent) : 0 g/l VOC Method 310 : 0 % U.S. State Regulations: Penn RTK Components : Water 7732-18-5 Sodium silicate 1344-09-8 Potassium 31795-24-1 NJ RTK Components : Water 7732-18-5 Sodium silicate 1344-09-8 Potassium 31795-24-1 Components under California Proposition 65: None known. SECTION 16 - OTHER INFORMATION HMIS Rating : Health 3 0 = Minimum 1 = Slight 2 = Moderate 3 = Serious 4 = Severe Flammability 0 Reactivity 1 PPE Further information: For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the consideration of the user, subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition. Prepared by: Rich Mikol Legend ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act RCRA - Resource Conservation and Recovery Act DOT - Department of Transportation RTK - Right To Know DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act EPA - Environmental Protection Agency STEL - Short Term Exposure Limit HMIS - Hazardous Materials Information System TLV - Threshold Limit Value IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act MSHA - Mine Safety Health Administration TWA - Time Weighted Average NDSL - Non-Domestic Substance List V - Volume NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound NTP - National Toxicology Program WHMIS - Workplace Hazardous Materials Information System OSHA - Occupational Safety and Health Administration Page 96 of 328 Page 96 of 328 Page 96 of 328 Page 96 of 328 ---PAGE BREAK--- Page 97 of 328 Page 97 of 328 Page 97 of 328 Page 97 of 328 ---PAGE BREAK--- Page 98 of 328 Page 98 of 328 Page 98 of 328 Page 98 of 328 ---PAGE BREAK--- Page 99 of 328 Page 99 of 328 Page 99 of 328 Page 99 of 328 ---PAGE BREAK--- Page 100 of 328 Page 100 of 328 Page 100 of 328 Page 100 of 328 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Product number [PHONE REDACTED] Product identifier FRESH LINEN AIR FRESHENER & DEODORIZER Company information Claire Manufacturing Co. 1005 S. Westgate Drive Addison, IL 60101 United States Company phone General Assistance 1-[PHONE REDACTED] Emergency telephone US 1-[PHONE REDACTED] Emergency telephone outside US 1-[PHONE REDACTED] Version # 01 Recommended use Air Freshener Recommended restrictions None known. 2. Hazard(s) identification Category 1 Flammable aerosols Physical hazards Category 2A Serious eye damage/eye irritation Health hazards Category 3 narcotic effects Specific target organ toxicity, single exposure Not classified. Environmental hazards Not classified. OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Causes serious eye irritation. May cause drowsiness or dizziness. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing gas. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear eye/face protection. Response If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. If eye irritation persists: Get medical advice/attention. Collect spillage. Storage Store in a well-ventilated place. Keep container closed. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number % Chemical name Common name and synonyms 67-64-1 Acetone 60 - 80 106-97-8 Butane 10 - 20 1 / 9 Product name: FRESH LINEN AIR FRESHENER & DEODORIZER Product [PHONE REDACTED] Version 01 Issue date: 06-22-2015 SDS US Page 101 of 328 Page 101 of 328 Page 101 of 328 Page 101 of 328 ---PAGE BREAK--- CAS number % Chemical name Common name and synonyms 74-98-6 Propane Other components below reportable levels 1 - 2.5 10 - 20 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical attention if irritation develops and persists. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician or poison control center immediately. Ingestion Rinse mouth. Get medical attention if occur. Most important acute and delayed Irritation of nose and throat. Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat Keep victim under observation. may be delayed. General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Contents under pressure. Pressurized container may explode when exposed to heat or flame. During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Fire-fighting equipment/instructions Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. General fire hazards Extremely flammable aerosol. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing gas. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. 2 / 9 Product name: FRESH LINEN AIR FRESHENER & DEODORIZER Product [PHONE REDACTED] Version 01 Issue date: 06-22-2015 SDS US Page 102 of 328 Page 102 of 328 Page 102 of 328 Page 102 of 328 ---PAGE BREAK--- 7. Handling and storage Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Do not re-use empty containers. Avoid breathing gas. Avoid contact with eyes. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Level 3 Aerosol. Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Store in a well-ventilated place. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Type PEL 2400 mg/m3 Acetone (CAS 67-64-1) 1000 ppm PEL 1800 mg/m3 Propane (CAS 74-98-6) 1000 ppm US. ACGIH Threshold Limit Values Value Components Type STEL 750 ppm Acetone (CAS 67-64-1) TWA 500 ppm STEL 1000 ppm Butane (CAS 106-97-8) US. NIOSH: Pocket Guide to Chemical Hazards Value Components Type TWA 590 mg/m3 Acetone (CAS 67-64-1) 250 ppm TWA 1900 mg/m3 Butane (CAS 106-97-8) 800 ppm TWA 1800 mg/m3 Propane (CAS 74-98-6) 1000 ppm Biological limit values ACGIH Biological Exposure Indices Value Components Determinant Specimen Sampling Time 50 mg/l Acetone Urine * Acetone (CAS 67-64-1) * - For sampling details, please see the source document. Appropriate engineering controls Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Hand protection Wear appropriate chemical resistant gloves. Skin protection Other Wear suitable protective clothing. Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. Thermal hazards Wear appropriate thermal protective clothing, when necessary. 3 / 9 Product name: FRESH LINEN AIR FRESHENER & DEODORIZER Product [PHONE REDACTED] Version 01 Issue date: 06-22-2015 SDS US Page 103 of 328 Page 103 of 328 Page 103 of 328 Page 103 of 328 ---PAGE BREAK--- General hygiene considerations When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Gas. Form Aerosol. Color clear colorless Odor Characteristic. Odor threshold Not available. pH Not applicable estimated Melting point/freezing point Not available. Initial boiling point and boiling range 89.81 °F (32.12 estimated Flash point -156.0 °F (-104.4 propellant estimated Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Not available. Flammability limit - upper Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 50 - 60 psig @70°F estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Specific gravity 0.694 estimated estimated 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Hazardous polymerization does not occur. Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Fire or intense heat may cause violent rupture of packages. Incompatible materials Acids. Strong oxidizing agents. Nitrates. Fluorine. Chlorine. Hazardous decomposition products No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. 4 / 9 Product name: FRESH LINEN AIR FRESHENER & DEODORIZER Product [PHONE REDACTED] Version 01 Issue date: 06-22-2015 SDS US Page 104 of 328 Page 104 of 328 Page 104 of 328 Page 104 of 328 ---PAGE BREAK--- Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful. Skin contact Causes mild skin irritation. Eye contact Causes serious eye irritation. related to the physical, chemical and toxicological characteristics Irritation of nose and throat. Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. of overexposure may be headache, dizziness, tiredness, nausea and vomiting. May cause central nervous system effects. Information on toxicological effects Acute toxicity Narcotic effects. Expected to be a low hazard for usual industrial or commercial handling by trained personnel. Test Results Product Species FRESH LINEN AIR FRESHENER & DEODORIZER (CAS Mixture) LD50 Rat Dermal Acute 29401 mg/kg LC50 Rat Inhalation 106 mg/l/4h LD50 Rat Oral Test Results Components Species Acetone (CAS 67-64-1) LD50 Guinea pig Dermal Acute > 7426 mg/kg, 24 Hours > 9.4 ml/kg, 24 Hours Rabbit > 7426 mg/kg, 24 Hours > 9.4 ml/kg, 24 Hours LC50 Rat Inhalation 55700 ppm, 3 Hours 132 mg/l, 3 Hours 50.1 mg/l LD50 Rat Oral 5800 mg/kg 2.2 ml/kg Butane (CAS 106-97-8) LC50 Mouse Inhalation Acute 1237 mg/l, 120 Minutes 52 120 Minutes Rat 1355 mg/l Propane (CAS 74-98-6) LC50 Mouse Inhalation Acute 1237 mg/l, 120 Minutes 52 120 Minutes Rat 1355 mg/l 658 mg/l/4h * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Causes mild skin irritation. Serious eye damage/eye irritation Causes serious eye irritation. 5 / 9 Product name: FRESH LINEN AIR FRESHENER & DEODORIZER Product [PHONE REDACTED] Version 01 Issue date: 06-22-2015 SDS US Page 105 of 328 Page 105 of 328 Page 105 of 328 Page 105 of 328 ---PAGE BREAK--- Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure May cause drowsiness or dizziness. May cause drowsiness and dizziness. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Not likely, due to the form of the product. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity Product Test Results Species FRESH LINEN AIR FRESHENER & DEODORIZER (CAS Mixture) Aquatic EC50 Crustacea 19781 mg/L, 48 Hours Daphnia LC50 Fish 8121 mg/L, 96 Hours Fish Components Test Results Species Acetone (CAS 67-64-1) Aquatic EC50 Crustacea 21.6 - 23.9 mg/l, 48 hours Water flea (Daphnia magna) * Estimates for product may be based on additional component data not shown. LC50 Fish 4740 - 6330 mg/l, 96 hours Rainbow trout,donaldson trout mykiss) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) Acetone -0.24 Butane 2.89 Propane 2.36 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. US RCRA Hazardous Waste U List: Reference Acetone (CAS 67-64-1) U002 Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). 6 / 9 Product name: FRESH LINEN AIR FRESHENER & DEODORIZER Product [PHONE REDACTED] Version 01 Issue date: 06-22-2015 SDS US Page 106 of 328 Page 106 of 328 Page 106 of 328 Page 106 of 328 ---PAGE BREAK--- Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. 14. Transport information DOT UN1950 UN number Aerosols, flammable, (each not exceeding 1 L capacity) UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk 2.1 Label(s) Not applicable. Packing group Read safety instructions, SDS and emergency procedures before handling. Special precautions for user N82 Special provisions 306 Packaging exceptions None Packaging non bulk None Packaging bulk This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently. IATA UN1950 UN number Aerosols, flammable UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk 2.1 Label(s) Not applicable. Packing group No. Environmental hazards 10L ERG Code Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Allowed. Passenger and cargo aircraft Other information Allowed. Cargo aircraft only LTD QTY Packaging Exceptions IMDG UN1950 UN number AEROSOLS UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk 2.1 Label(s) Not applicable. Packing group No. Marine pollutant Environmental hazards F-D, S-U EmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user LTD QTY Packaging Exceptions Not applicable. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 7 / 9 Product name: FRESH LINEN AIR FRESHENER & DEODORIZER Product [PHONE REDACTED] Version 01 Issue date: 06-22-2015 SDS US Page 107 of 328 Page 107 of 328 Page 107 of 328 Page 107 of 328 ---PAGE BREAK--- DOT IATA; IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Butane (CAS 106-97-8) Propane (CAS 74-98-6) Safe Drinking Water Act (SDWA) Not regulated. Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1) 6532 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1) 35 %WV 8 / 9 Product name: FRESH LINEN AIR FRESHENER & DEODORIZER Product [PHONE REDACTED] Version 01 Issue date: 06-22-2015 SDS US Page 108 of 328 Page 108 of 328 Page 108 of 328 Page 108 of 328 ---PAGE BREAK--- DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1) 6532 US state regulations US. Massachusetts RTK - Substance List Acetone (CAS 67-64-1) Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. New Jersey Worker and Community Right-to-Know Act Acetone (CAS 67-64-1) Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. Rhode Island RTK Acetone (CAS 67-64-1) Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* No Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) No Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) No New Zealand New Zealand Inventory No Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 06-22-2015 Version # 01 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 9 / 9 Product name: FRESH LINEN AIR FRESHENER & DEODORIZER Product [PHONE REDACTED] Version 01 Issue date: 06-22-2015 SDS US Page 109 of 328 Page 109 of 328 Page 109 of 328 Page 109 of 328 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 1 / 9 SAFETY DATA SHEET 1. Identification Product number [PHONE REDACTED] Product identifier GERMICIDAL CLEANER Revision date 03-23-2015 Company information Claire Manufacturing Co. 1005 S. Westgate Drive Addison, IL 60101 United States Company phone General Assistance 1-[PHONE REDACTED] Emergency telephone US 1-[PHONE REDACTED] Emergency telephone outside US 1-[PHONE REDACTED] Version # 04 Supersedes date 03-05-2015 Recommended use Cleaner Recommended restrictions None known. 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements Flammable aerosols Serious eye damage/eye irritation Not classified. Not classified. Category 1 Category 2 Signal word Danger Hazard statement Extremely flammable aerosol. Causes serious eye irritation. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash thoroughly after handling. Wear eye/face protection. Response If swallowed: Rinse mouth. Do NOT induce vomiting. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Storage Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Disposal Not available. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % 2-Butoxyethanol Butane EDTA Tertrasodium Salt 111-76-2 106-97-8 64-02-8 2.5 - 10 1 - 2.5 1 - 2.5 Other components below reportable levels 90 - 100 Page 110 of 328 Page 110 of 328 Page 110 of 328 Page 110 of 328 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 2 / 9 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Call a physician if develop or persist. Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists. Eye contact Rinse with water. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Get medical attention if occur. Most important acute and delayed Indication of immediate medical attention and special treatment needed Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. Provide general supportive measures and treat Keep victim under observation. may be delayed. General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water. Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Do not use water jet as an extinguisher, as this will spread the fire. Contents under pressure. Pressurized container may explode when exposed to heat or flame. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Use water spray to cool unopened containers. In the event of fire and/or explosion do not breathe fumes. General fire hazards Extremely flammable aerosol. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Level 1 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). Page 111 of 328 Page 111 of 328 Page 111 of 328 Page 111 of 328 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 3 / 9 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value 2-Butoxyethanol (CAS 111-76-2) US. ACGIH Threshold Limit Values PEL 240 mg/m3 50 ppm Components Type Value 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) TWA 20 ppm STEL 1000 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Biological limit values ACGIH Biological Exposure Indices TWA 24 mg/m3 5 ppm TWA 1900 mg/m3 800 ppm Components Value Determinant Specimen Sampling Time 2-Butoxyethanol (CAS 111-76-2) 200 mg/g Butoxyacetic acid (BAA), Creatinine in urine * with hydrolysis * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies 2-Butoxyethanol (CAS 111-76-2) Skin designation applies. US - Tennesse OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Hand protection Wear appropriate chemical resistant gloves. Skin protection Other Wear suitable protective clothing. Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Page 112 of 328 Page 112 of 328 Page 112 of 328 Page 112 of 328 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 4 / 9 9. Physical and chemical properties Appearance Physical state Gas. Form Aerosol. Color Not available. Odor Not available. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 212 °F (100 estimated Flash point -156.0 °F (-104.4 Propellant estimated Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Flammability limit - upper Not available. Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 55 - 75 psig @70F estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Specific gravity 0.979 estimated 10. Stability and reactivity Reactivity Reacts violently with strong acids. This product may react with oxidizing agents. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid Avoid temperatures exceeding the flash point. Do not mix with other chemicals. Contact with incompatible materials. Incompatible materials Acids. Oxidizing agents. Hazardous decomposition products No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation Prolonged inhalation may be harmful. Skin contact 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Eye contact Causes serious eye irritation. Page 113 of 328 Page 113 of 328 Page 113 of 328 Page 113 of 328 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 5 / 9 related to the physical, chemical and toxicological characteristics Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. Information on toxicological effects Acute toxicity Harmful if inhaled. Harmful if swallowed. Components Species 2-Butoxyethanol (CAS 111-76-2) Acute Dermal LD50 Guinea pig Test Results 230 ml/kg, 24 Hours 7.3 ml/kg, 4 Days Inhalation Rabbit 450 ml/kg, 24 Hours 435 mg/kg, 24 Hours 0.63 ml/kg Rat > 2000 mg/kg, 24 Hours LC50 Rabbit 400 ppm, 7 Hours Oral Rat 450 ppm, 4 Hours LD100 Rabbit 695 mg/kg LD50 Dog > 695 mg/kg Guinea pig 1200 mg/kg Rat 530 - 2800 mg/kg Butane (CAS 106-97-8) Acute Inhalation LC50 Mouse 1237 mg/l, 120 Minutes 52 120 Minutes Rat 1355 mg/l EDTA Tertrasodium Salt (CAS 64-02-8) Acute Oral LD50 Rat 1658 mg/kg * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Causes skin burns. Serious eye damage/eye irritation Respiratory or skin sensitization Causes eye burns. Risk of serious damage to eyes. Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity 2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Not classified. Page 114 of 328 Page 114 of 328 Page 114 of 328 Page 114 of 328 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 6 / 9 Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not likely, due to the form of the product. Chronic effects Prolonged inhalation may be harmful. May be harmful if absorbed through skin. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components 2-Butoxyethanol (CAS 111-76-2) Aquatic Species Test Results Fish LC50 Inland silverside (Menidia beryllina) 1250 mg/l, 96 hours EDTA Tertrasodium Salt (CAS 64-02-8) Aquatic Algae Fish IC50 LC50 Algae Bluegill (Lepomis macrochirus) 1.01 mg/L, 72 Hours 472 - 500 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) 2-Butoxyethanol 0.83 Butane 2.89 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. 14. Transport information DOT UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group UN1950 Aerosols 2.2 - 2.2 Not applicable. Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Packaging exceptions Packaging non bulk Packaging bulk 306 None None Page 115 of 328 Page 115 of 328 Page 115 of 328 Page 115 of 328 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 7 / 9 This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently. IATA UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards ERG Code UN1950 Aerosols, non-flammable 2.2 - 2.2 Not applicable. Yes 2L Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Other information Passenger and cargo aircraft Cargo aircraft only Packaging Exceptions IMDG UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards Marine pollutant EmS Allowed. Allowed. LTD QTY UN1950 AEROSOLS 2.2 - 2.2 Not applicable. Yes Not available. Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Packaging Exceptions Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT IATA; IMDG LTD QTY Not applicable. Page 116 of 328 Page 116 of 328 Page 116 of 328 Page 116 of 328 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 8 / 9 Marine pollutant 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Chemical name CAS number Reportable quantity Threshold planning quantity Threshold planning quantity, lower value Threshold planning quantity, upper value Ammonia 7664-41-7 100 500 lbs Hydrogen Peroxide 7722-84-1 1000 1000 lbs SARA 311/312 Hazardous No chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Butane (CAS 106-97-8) Safe Drinking Water Act (SDWA) US state regulations Not regulated. US. Massachusetts RTK - Substance List 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) US. New Jersey Worker and Community Right-to-Know Act 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) US. Worker and Community Right-to-Know Law 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) US. Rhode Island RTK Butane (CAS 106-97-8) Page 117 of 328 Page 117 of 328 Page 117 of 328 Page 117 of 328 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 9 / 9 US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Domestic Substances List (DSL) Canada Non-Domestic Substances List (NDSL) China Inventory of Existing Chemical Substances in China (IECSC) Europe European Inventory of Existing Commercial Chemical Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) Japan Inventory of Existing and New Chemical Substances (ENCS) Korea Existing Chemicals List (ECL) New Zealand New Zealand Inventory Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) No Yes No Yes No No Yes No No No Yes A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 07-28-2014 Revision date 03-23-2015 Version # 04 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Revision Information Product and Company Identification: Alternate Trade Names Page 118 of 328 Page 118 of 328 Page 118 of 328 Page 118 of 328 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Product number [PHONE REDACTED] Product identifier GLEME GLASS CLEANER Company information Claire Manufacturing Co. 1005 S. Westgate Drive Addison, IL 60101 United States Company phone General Assistance 1-[PHONE REDACTED] Emergency telephone US 1-[PHONE REDACTED] Emergency telephone outside US 1-[PHONE REDACTED] Version # 01 Recommended use cleaner Recommended restrictions None known. 2. Hazard(s) identification Liquefied gas Gases under pressure Physical hazards Not classified. Health hazards Not classified. Environmental hazards Not classified. OSHA defined hazards Label elements Signal word Warning Hazard statement Contains gas under pressure; may explode if heated. Precautionary statement Prevention Observe good industrial hygiene practices. Response Wash hands after handling. Storage Protect from sunlight. Store in a well-ventilated place. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number % Chemical name Common name and synonyms 111-76-2 2-Butoxyethanol 2.5 - 10 64-17-5 Ethyl Alcohol 2.5 - 10 106-97-8 Butane 1 - 2.5 74-98-6 Propane Other components below reportable levels 90 - 100 1 - 2.5 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Get medical attention if persist. 1 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 119 of 328 Page 119 of 328 Page 119 of 328 Page 119 of 328 ---PAGE BREAK--- Skin contact Get medical attention if irritation develops and persists. Eye contact Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Most important acute and delayed Direct contact with eyes may cause temporary irritation. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Contents under pressure. During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire-fighting equipment/instructions In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed to heat. Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. See Section 8 of the SDS for Personal Protective Equipment. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into waterways, sewer, basements or confined areas. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Ground and bond containers when transferring material. Do not re-use empty containers. Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Level 1 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. Keep containers closed in a dry, cool and well-ventilated place. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). 2 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 120 of 328 Page 120 of 328 Page 120 of 328 Page 120 of 328 ---PAGE BREAK--- 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Type PEL 240 mg/m3 2-Butoxyethanol (CAS 111-76-2) 50 ppm PEL 1900 mg/m3 Ethyl Alcohol (CAS 64-17-5) 1000 ppm PEL 1800 mg/m3 Propane (CAS 74-98-6) 1000 ppm US. ACGIH Threshold Limit Values Value Components Type TWA 20 ppm 2-Butoxyethanol (CAS 111-76-2) STEL 1000 ppm Butane (CAS 106-97-8) STEL 1000 ppm Ethyl Alcohol (CAS 64-17-5) US. NIOSH: Pocket Guide to Chemical Hazards Value Components Type TWA 24 mg/m3 2-Butoxyethanol (CAS 111-76-2) 5 ppm TWA 1900 mg/m3 Butane (CAS 106-97-8) 800 ppm TWA 1900 mg/m3 Ethyl Alcohol (CAS 64-17-5) 1000 ppm TWA 1800 mg/m3 Propane (CAS 74-98-6) 1000 ppm Biological limit values ACGIH Biological Exposure Indices Value Components Determinant Specimen Sampling Time 200 mg/g Butoxyacetic acid (BAA), with hydrolysis Creatinine in urine * 2-Butoxyethanol (CAS 111-76-2) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies 2-Butoxyethanol (CAS 111-76-2) Skin designation applies. US - Tennesse OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection If contact is likely, safety glasses with side shields are recommended. Hand protection For prolonged or repeated skin contact use suitable protective gloves. Skin protection Other Wear suitable protective clothing. 3 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 121 of 328 Page 121 of 328 Page 121 of 328 Page 121 of 328 ---PAGE BREAK--- Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Clear. Physical state Gas. Form Aerosol. Liquefied gas. Color Light yellow. Odor Characteristic. Odor threshold Not available. pH 9.1 - 10.1 estimated Melting point/freezing point Not available. Initial boiling point and boiling range 212 °F (100 estimated Flash point -156.0 °F (-104.4 Propellant estimated Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Not available. Flammability limit - upper Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 80 - 100 psig @70F estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Aerosol spray enclosed space Deflagration density > 2.52 g/cm3 Tested Aerosol spray ignition distance < 15 cm Tested estimated Specific gravity 0.977 - 0.997 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Hazardous polymerization does not occur. Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. 4 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 122 of 328 Page 122 of 328 Page 122 of 328 Page 122 of 328 ---PAGE BREAK--- Incompatible materials Strong oxidizing agents. Hazardous decomposition products No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation Prolonged inhalation may be harmful. Skin contact No adverse effects due to skin contact are expected. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Eye contact Direct contact with eyes may cause temporary irritation. related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity May be harmful if swallowed. May be harmful in contact with skin. May be harmful if inhaled. Expected to be a low hazard for usual industrial or commercial handling by trained personnel. Test Results Components Species 2-Butoxyethanol (CAS 111-76-2) LD50 Guinea pig Dermal Acute 230 ml/kg, 24 Hours 7.3 ml/kg, 4 Days Rabbit 450 ml/kg, 24 Hours 435 mg/kg, 24 Hours 0.63 ml/kg Rat > 2000 mg/kg, 24 Hours LC50 Rabbit Inhalation 400 ppm, 7 Hours Rat 450 ppm, 4 Hours LD100 Rabbit Oral 695 mg/kg LD50 Dog > 695 mg/kg Guinea pig 1200 mg/kg Rat 530 - 2800 mg/kg Butane (CAS 106-97-8) LC50 Mouse Inhalation Acute 1237 mg/l, 120 Minutes 52 120 Minutes Rat 1355 mg/l Ethyl Alcohol (CAS 64-17-5) LC50 Cat Inhalation Acute 85.41 mg/l, 4.5 Hours 43.68 mg/l, 6 Hours Mouse > 60000 ppm 79.43 mg/l, 134 Minutes Rat > 115.9 mg/l, 4 Hours 5 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 123 of 328 Page 123 of 328 Page 123 of 328 Page 123 of 328 ---PAGE BREAK--- Test Results Components Species 51.3 mg/l, 6 Hours LD50 Monkey Oral 6000 mg/kg Mouse 10500 ml/kg Rat 1187 - 2769 mg/kg 7800 ml/kg Propane (CAS 74-98-6) LC50 Mouse Inhalation Acute 1237 mg/l, 120 Minutes 52 120 Minutes Rat 1355 mg/l 658 mg/l/4h * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation May be irritating to the skin. Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. May be irritating to eyes. Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity 2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Not likely, due to the form of the product. Chronic effects Prolonged inhalation may be harmful. May be harmful if absorbed through skin. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. 12. Ecological information Ecotoxicity Harmful to aquatic life. Product Test Results Species GLEME GLASS CLEANER (CAS Mixture) Aquatic EC50 Crustacea 13838.1602 mg/l, 48 hours estimated Daphnia Components Test Results Species 2-Butoxyethanol (CAS 111-76-2) Aquatic LC50 Fish 1250 mg/l, 96 hours Inland silverside (Menidia beryllina) 6 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 124 of 328 Page 124 of 328 Page 124 of 328 Page 124 of 328 ---PAGE BREAK--- Components Test Results Species Ethyl Alcohol (CAS 64-17-5) Aquatic EC50 Crustacea 7700 - 11200 mg/l, 48 hours Water flea (Daphnia magna) * Estimates for product may be based on additional component data not shown. LC50 Fish > 100.1 mg/l, 96 hours Fathead minnow (Pimephales promelas) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) 2-Butoxyethanol 0.83 Butane 2.89 Ethyl Alcohol -0.31 Propane 2.36 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. 14. Transport information DOT UN1950 UN number Aerosols UN proper shipping name 2.2 Class Transport hazard class(es) - Subsidiary risk 2.2 Label(s) Not applicable. Packing group Read safety instructions, SDS and emergency procedures before handling. Special precautions for user 306 Packaging exceptions None Packaging non bulk None Packaging bulk This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently. IATA UN1950 UN number Aerosols, non-flammable UN proper shipping name 2.2 Class Transport hazard class(es) - Subsidiary risk 2.2 Label(s) Not applicable. Packing group No. Environmental hazards 2L ERG Code Read safety instructions, SDS and emergency procedures before handling. Special precautions for user 7 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 125 of 328 Page 125 of 328 Page 125 of 328 Page 125 of 328 ---PAGE BREAK--- Allowed. Passenger and cargo aircraft Other information Allowed. Cargo aircraft only LTD QTY Packaging Exceptions IMDG UN1950 UN number AEROSOLS UN proper shipping name 2.2 Class Transport hazard class(es) - Subsidiary risk 2.2 Label(s) Not applicable. Packing group No. Marine pollutant Environmental hazards Not available. EmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user LTD QTY Packaging Exceptions Not applicable. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT IATA; IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. 8 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 126 of 328 Page 126 of 328 Page 126 of 328 Page 126 of 328 ---PAGE BREAK--- Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Butane (CAS 106-97-8) Propane (CAS 74-98-6) Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. Massachusetts RTK - Substance List 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) Propane (CAS 74-98-6) US. New Jersey Worker and Community Right-to-Know Act 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) Propane (CAS 74-98-6) US. Worker and Community Right-to-Know Law 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) Propane (CAS 74-98-6) US. Rhode Island RTK Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Yes Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) Yes China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) No New Zealand New Zealand Inventory No Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) 9 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 127 of 328 Page 127 of 328 Page 127 of 328 Page 127 of 328 ---PAGE BREAK--- Country(s) or region Inventory name On inventory (yes/no)* Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 05-26-2015 Version # 01 References EPA: AQUIRE database NLM: Hazardous Substances Data Base US. IARC Monographs on Occupational Exposures to Chemical Agents Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 10 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 128 of 328 Page 128 of 328 Page 128 of 328 Page 128 of 328 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Version 1.2 Revision Date: 02/18/2015 MSDS Number: 31378-00003 Date of last issue: 02/10/2015 Date of first issue: 12/11/2014 1 / 21 SECTION 1. IDENTIFICATION Product name : GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Manufacturer or supplier's details Company name of supplier : GOJO Industries, Inc. Address : One GOJO Plaza, Suite 500 Akron OH 44311 Telephone : 1 (330) 255-6000 Emergency telephone : 1-[PHONE REDACTED] CHEMTREC Recommended use of the chemical and restrictions on use Recommended use : Antibacterial Soap Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 3 Serious eye damage : Category 1 GHS Label element Hazard pictograms : Signal Word : Danger Page 129 of 328 Page 129 of 328 Page 129 of 328 Page 129 of 328 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Version 1.2 Revision Date: 02/18/2015 MSDS Number: 31378-00003 Date of last issue: 02/10/2015 Date of first issue: 12/11/2014 2 / 21 Hazard Statements : H226 Flammable liquid and vapor. H318 Causes serious eye damage. Precautionary Statements : Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P233 Keep container closed. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P280 Wear protective gloves/ eye protection/ face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards Vapors may form explosive mixture with air. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous ingredients Chemical Name CAS-No. Concentration Ethanol 64-17-5 1 - < 5 Alpha-Sulfo-omega-(dodecyloxy)-poly(oxy-1,2- ethanediyl), Ammonium salt 67762-19-0 1 - < 5 Ammonium dodecyl sulphate 2235-54-3 1 - < 5 Propylene glycol 57-55-6 1 - < 5 88-04-0 0.1 - < 1 SECTION 4. FIRST AID MEASURES General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When persist or in all cases of doubt seek medical advice. If inhaled : If inhaled, remove to fresh air. Get medical attention if occur. Page 130 of 328 Page 130 of 328 Page 130 of 328 Page 130 of 328 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Version 1.2 Revision Date: 02/18/2015 MSDS Number: 31378-00003 Date of last issue: 02/10/2015 Date of first issue: 12/11/2014 3 / 21 In case of skin contact : Wash with water and soap as a precaution. Get medical attention if occur. In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Get medical attention immediately. If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if occur. Rinse mouth thoroughly with water. Most important and effects, both acute and delayed : Causes serious eye damage. Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists. Notes to physician : Treat and supportively. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2) Unsuitable extinguishing media : High volume water jet Specific hazards during fire fighting : Do not use a solid water stream as it may scatter and spread fire. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. Exposure to combustion products may be a hazard to health. Hazardous combustion prod- ucts : Carbon oxides Sulfur oxides Nitrogen oxides (NOx) Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area. Special protective equipment for fire-fighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. Page 131 of 328 Page 131 of 328 Page 131 of 328 Page 131 of 328 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Version 1.2 Revision Date: 02/18/2015 MSDS Number: 31378-00003 Date of last issue: 02/10/2015 Date of first issue: 12/11/2014 4 / 21 SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Remove all sources of ignition. Use personal protective equipment. Follow safe handling advice and personal protective equipment recommendations. Environmental precautions : Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for containment and cleaning up : Non-sparking tools should be used. Soak up with inert absorbent material. Suppress (knock down) gases/vapors/mists with a water spray jet. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements. SECTION 7. HANDLING AND STORAGE Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Local/Total ventilation : Use with local exhaust ventilation. Use only in an area equipped with explosion proof exhaust ventilation. Advice on safe handling : Avoid inhalation of vapor or mist. Do not swallow. Do not get in eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice. Non-sparking tools should be used. Keep container closed. Keep away from heat and sources of ignition. Page 132 of 328 Page 132 of 328 Page 132 of 328 Page 132 of 328 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Version 1.2 Revision Date: 02/18/2015 MSDS Number: 31378-00003 Date of last issue: 02/10/2015 Date of first issue: 12/11/2014 5 / 21 Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment. Conditions for safe storage : Keep in properly labeled containers. Keep closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition. Materials to avoid : Do not store with the following product types: Strong oxidizing agents Organic peroxides Flammable solids Pyrophoric liquids Pyrophoric solids Self-heating substances and mixtures Substances and mixtures which in contact with water emit flammable gases Explosives Gases SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Ethanol 64-17-5 TWA 1,000 ppm 1,900 mg/m3 NIOSH REL TWA 1,000 ppm 1,900 mg/m3 OSHA Z-1 STEL 1,000 ppm ACGIH Propylene glycol 57-55-6 TWA 10 mg/m3 US WEEL Hazardous components without workplace control parameters Ingredients CAS-No. Alpha-Sulfo-omega- (dodecyloxy)-poly(oxy-1,2- ethanediyl), Ammonium salt 67762-19-0 Ammonium dodecyl sulphate 2235-54-3 88-04-0 Engineering measures : Minimize workplace exposure concentrations. Use only in an area equipped with explosion proof exhaust ventilation. Use with local exhaust ventilation. Dust formation may be relevant in the processing of this product. In addition to substance-specific OELs, general limitations of concentrations of particulates in the air at workplaces have to be considered in workplace risk Page 133 of 328 Page 133 of 328 Page 133 of 328 Page 133 of 328 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Version 1.2 Revision Date: 02/18/2015 MSDS Number: 31378-00003 Date of last issue: 02/10/2015 Date of first issue: 12/11/2014 6 / 21 assessment. Relevant limits include: OSHA PEL for Particulates Not Otherwise Regulated of 15 mg/m3 - total dust, 5 mg/m3 - respirable fraction; and ACGIH TWA for Particles (insoluble or poorly soluble) Not Otherwise Specified of 3 mg/m3 - respirable particles, 10 mg/m3 - inhalable particles. Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. Hand protection Material : Impervious gloves Material : Flame retardant gloves Remarks : Choose gloves to protect hands against chemicals depending on the concentration specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. Eye protection : Wear the following personal protective equipment: Chemical resistant goggles must be worn. If splashes are likely to occur, wear: Face-shield Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Wear the following personal protective equipment: Flame retardant antistatic protective clothing. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc). Hygiene measures : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. Page 134 of 328 Page 134 of 328 Page 134 of 328 Page 134 of 328 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Version 1.2 Revision Date: 02/18/2015 MSDS Number: 31378-00003 Date of last issue: 02/10/2015 Date of first issue: 12/11/2014 7 / 21 SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Color : clear, amber, brown Odor : fruity Odor Threshold : No data available pH : 4.5 - 8.5 Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Flash point : 26.00 °C Evaporation rate : No data available Flammability (solid, gas) : Not applicable Upper explosion limit : No data available Lower explosion limit : No data available Vapor pressure : No data available Relative vapor density : No data available Density : 1.00 g/cm3 Solubility(ies) Water solubility : soluble Partition coefficient: n- octanol/water : Not applicable Autoignition temperature : No data available Decomposition temperature : The substance or mixture is not classified self-reactive. Viscosity Viscosity, kinematic : 10 - 20 mm2/s (20 Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. Page 135 of 328 Page 135 of 328 Page 135 of 328 Page 135 of 328 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Version 1.2 Revision Date: 02/18/2015 MSDS Number: 31378-00003 Date of last issue: 02/10/2015 Date of first issue: 12/11/2014 8 / 21 SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reac- tions : Flammable liquid and vapor. Vapors may form explosive mixture with air. Can react with strong oxidizing agents. Conditions to avoid : Heat, flames and sparks. Incompatible materials : Oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Ingredients: Ethanol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): 124.7 mg/l Exposure time: 4 h Test atmosphere: vapor Alpha-Sulfo-omega-(dodecyloxy)-poly(oxy-1,2-ethanediyl), Ammonium salt: Acute oral toxicity : LD50 (Rat): 4,100 mg/kg Method: OECD Test Guideline 401 Remarks: Based on data from similar materials Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 402 Assessment: The substance or mixture has no acute dermal toxicity Remarks: Based on data from similar materials Ammonium dodecyl sulphate: Page 136 of 328 Page 136 of 328 Page 136 of 328 Page 136 of 328 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Version 1.2 Revision Date: 02/18/2015 MSDS Number: 31378-00003 Date of last issue: 02/10/2015 Date of first issue: 12/11/2014 9 / 21 Acute oral toxicity : LD50 (Rat): 2,000 mg/kg Method: EC Directive 92/69/EEC B.1 Acute Toxicity (Oral) Remarks: Based on data from similar materials Propylene glycol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rabbit): > 159 mg/l, > 51091 ppm Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Acute oral toxicity : Acute toxicity estimate: 500 mg/kg Method: Expert judgment Remarks: Based on harmonised classification in EU regulation 1272/2008, Annex VI Acute inhalation toxicity : LC50 (Rat): > 6.29 mg/l Test atmosphere: dust/mist Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation Ingredients: Ethanol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Alpha-Sulfo-omega-(dodecyloxy)-poly(oxy-1,2-ethanediyl), Ammonium salt: Species: Rabbit Method: OECD Test Guideline 404 Result: Skin irritation Remarks: Based on data from similar materials Ammonium dodecyl sulphate: Species: Rabbit Method: OECD Test Guideline 404 Result: Skin irritation Propylene glycol: Page 137 of 328 Page 137 of 328 Page 137 of 328 Page 137 of 328 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Version 1.2 Revision Date: 02/18/2015 MSDS Number: 31378-00003 Date of last issue: 02/10/2015 Date of first issue: 12/11/2014 10 / 21 Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Result: Skin irritation Remarks: Based on harmonised classification in EU regulation 1272/2008, Annex VI Serious eye damage/eye irritation Causes serious eye damage. Ingredients: Ethanol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Method: OECD Test Guideline 405 Alpha-Sulfo-omega-(dodecyloxy)-poly(oxy-1,2-ethanediyl), Ammonium salt: Species: Rabbit Result: Irreversible effects on the eye Remarks: Based on data from similar materials Ammonium dodecyl sulphate: Species: Rabbit Result: Irreversible effects on the eye Method: OECD Test Guideline 405 Propylene glycol: Species: Rabbit Result: No eye irritation Method: OECD Test Guideline 405 Result: Irreversible effects on the eye Respiratory or skin sensitization Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information. Product: Assessment: Does not cause skin sensitization. Ingredients: Ethanol: Test Type: Local node assay (LLNA) Routes of exposure: Skin contact Species: Mouse Result: negative Alpha-Sulfo-omega-(dodecyloxy)-poly(oxy-1,2-ethanediyl), Ammonium salt: Test Type: Maximization Test (GPMT) Routes of exposure: Skin contact Page 138 of 328 Page 138 of 328 Page 138 of 328 Page 138 of 328 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Version 1.2 Revision Date: 02/18/2015 MSDS Number: 31378-00003 Date of last issue: 02/10/2015 Date of first issue: 12/11/2014 11 / 21 Species: Guinea pig Method: OECD Test Guideline 406 Result: negative Remarks: Based on data from similar materials Ammonium dodecyl sulphate: Test Type: Maximization Test (GPMT) Routes of exposure: Skin contact Species: Guinea pig Result: negative Remarks: Based on data from similar materials Propylene glycol: Test Type: Maximization Test (GPMT) Routes of exposure: Skin contact Species: Guinea pig Result: negative Assessment: Probability or evidence of skin sensitization in humans Remarks: Based on harmonised classification in EU regulation 1272/2008, Annex VI Germ cell mutagenicity Not classified based on available information. Ingredients: Ethanol: Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Result: negative Genotoxicity in vivo : Test Type: Rodent dominant lethal test (germ cell) (in vivo) Species: Mouse Application Route: Ingestion Result: negative Alpha-Sulfo-omega-(dodecyloxy)-poly(oxy-1,2-ethanediyl), Ammonium salt: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative Remarks: Based on data from similar materials : Test Type: In vitro mammalian cell gene mutation test Method: OECD Test Guideline 476 Result: negative Remarks: Based on data from similar materials Genotoxicity in vivo : Test Type: Mutagenicity (in vivo mammalian bone-marrow cytogenetic test, chromosomal analysis) Species: Mouse Application Route: Ingestion Method: OECD Test Guideline 475 Result: negative Remarks: Based on data from similar materials Page 139 of 328 Page 139 of 328 Page 139 of 328 Page 139 of 328 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Version 1.2 Revision Date: 02/18/2015 MSDS Number: 31378-00003 Date of last issue: 02/10/2015 Date of first issue: 12/11/2014 12 / 21 Ammonium dodecyl sulphate: Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Result: negative Remarks: Based on data from similar materials Genotoxicity in vivo : Test Type: Mammalian micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Ingestion Method: OECD Test Guideline 474 Result: negative Remarks: Based on data from similar materials Propylene glycol: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Genotoxicity in vivo : Test Type: In vivo micronucleus test Species: Mouse Application Route: Intraperitoneal injection Result: negative Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Carcinogenicity Not classified based on available information. Ingredients: Ammonium dodecyl sulphate: Species: Rat Application Route: Ingestion Exposure time: 2 Years Result: negative Remarks: Based on data from similar materials Propylene glycol: Species: Rat Application Route: Ingestion Exposure time: 2 Years Result: negative IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No ingredient of this product present at levels greater than or Page 140 of 328 Page 140 of 328 Page 140 of 328 Page 140 of 328 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Version 1.2 Revision Date: 02/18/2015 MSDS Number: 31378-00003 Date of last issue: 02/10/2015 Date of first issue: 12/11/2014 13 / 21 equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. Ingredients: Ethanol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion Method: OECD Test Guideline 416 Result: negative Alpha-Sulfo-omega-(dodecyloxy)-poly(oxy-1,2-ethanediyl), Ammonium salt: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative Remarks: Based on data from similar materials Effects on fetal development : Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative Remarks: Based on data from similar materials Ammonium dodecyl sulphate: Effects on fetal development : Test Type: Embryo-fetal development Species: Rat Application Route: Ingestion Result: negative Remarks: Based on data from similar materials Propylene glycol: Effects on fertility : Species: Mouse Application Route: Ingestion Result: negative Effects on fetal development : Test Type: Embryo-fetal development Species: Mouse Application Route: Ingestion Result: negative STOT-single exposure Not classified based on available information. STOT-repeated exposure Not classified based on available information. Repeated dose toxicity Ingredients: Page 141 of 328 Page 141 of 328 Page 141 of 328 Page 141 of 328 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Version 1.2 Revision Date: 02/18/2015 MSDS Number: 31378-00003 Date of last issue: 02/10/2015 Date of first issue: 12/11/2014 14 / 21 Ethanol: Species: Rat NOAEL: 2,400 mg/kg Application Route: Ingestion Exposure time: 2 y Alpha-Sulfo-omega-(dodecyloxy)-poly(oxy-1,2-ethanediyl), Ammonium salt: Species: Rat NOAEL: > 225 mg/kg Application Route: Ingestion Exposure time: 90 d Method: OECD Test Guideline 408 Remarks: Based on data from similar materials Propylene glycol: Species: Rat NOAEL: 1,700 mg/kg Application Route: Ingestion Exposure time: 2 y Species: Rabbit LOAEL: 180 mg/kg Application Route: Skin contact Exposure time: 90 d Aspiration toxicity Not classified based on available information. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Ingredients: Ethanol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 1,000 mg/l Exposure time: 48 h Toxicity to algae : EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 9.6 mg/l Exposure time: 9 d Toxicity to bacteria : EC50 (Photobacterium phosphoreum): 32.1 mg/l Exposure time: 0.25 h Page 142 of 328 Page 142 of 328 Page 142 of 328 Page 142 of 328 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Version 1.2 Revision Date: 02/18/2015 MSDS Number: 31378-00003 Date of last issue: 02/10/2015 Date of first issue: 12/11/2014 15 / 21 Alpha-Sulfo-omega-(dodecyloxy)-poly(oxy-1,2-ethanediyl), Ammonium salt: Toxicity to fish : LC50 (Danio rerio (zebra fish)): 7.1 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 7.4 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Remarks: Based on data from similar materials Toxicity to algae : ErC50 (Desmodesmus subspicatus (green algae)): 27.7 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Remarks: Based on data from similar materials NOEC (Desmodesmus subspicatus (green algae)): 0.95 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Remarks: Based on data from similar materials Toxicity to fish (Chronic toxicity) : NOEC mykiss (rainbow trout)): 0.14 mg/l Exposure time: 28 d Method: OECD Test Guideline 204 Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 0.27 mg/l Exposure time: 21 d Remarks: Based on data from similar materials Toxicity to bacteria : EC10 (Pseudomonas putida): > 10 g/l Exposure time: 16 h Method: DIN 38 412 Part 8 Remarks: Based on data from similar materials Ammonium dodecyl sulphate: Toxicity to fish : LC50 mykiss (rainbow trout)): 3.6 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 4.7 mg/l Exposure time: 48 h Method: Tested according to Directive 92/69/EEC. Remarks: Based on data from similar materials Toxicity to algae : ErC50 (Desmodesmus subspicatus (green algae)): > 20 mg/l Exposure time: 72 h Method: Directive 67/548/EEC, Annex V, C.3. Remarks: Based on data from similar materials EC10 (Desmodesmus subspicatus (green algae)): 5.4 mg/l Exposure time: 72 h Method: Directive 67/548/EEC, Annex V, C.3. Page 143 of 328 Page 143 of 328 Page 143 of 328 Page 143 of 328 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Version 1.2 Revision Date: 02/18/2015 MSDS Number: 31378-00003 Date of last issue: 02/10/2015 Date of first issue: 12/11/2014 16 / 21 Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Ceriodaphnia dubia (water flea)): 0.88 mg/l Exposure time: 7 d Remarks: Based on data from similar materials Toxicity to bacteria : EC0 (Pseudomonas putida): 409 mg/l Exposure time: 16 h Method: DIN 38 412 Part 8 Remarks: Based on data from similar materials Propylene glycol: Toxicity to fish : LC50 mykiss (rainbow trout)): 40,613 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Ceriodaphnia dubia (water flea)): 18,340 mg/l Exposure time: 48 h Toxicity to algae : EC50 (Skeletonema costatum (marine diatom)): 19,000 mg/l Exposure time: 48 h Method: OECD Test Guideline 201 Toxicity to fish (Chronic toxicity) : Chronic Toxicity Value: 2,500 mg/l Exposure time: 30 d Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Ceriodaphnia dubia (water flea)): 29,000 mg/l Exposure time: 7 d Toxicity to bacteria : NOEC (Pseudomonas putida): > 20,000 mg/l Exposure time: 18 h Toxicity to fish : LC50 mykiss (rainbow trout)): 0.76 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 7.7 mg/l Exposure time: 48 h M-Factor (Acute aquatic tox- icity) : 1 Persistence and degradability Ingredients: Ethanol: Biodegradability : Result: Readily biodegradable. Biodegradation: 84 % Exposure time: 20 d Alpha-Sulfo-omega-(dodecyloxy)-poly(oxy-1,2-ethanediyl), Ammonium salt: Biodegradability : Result: Readily biodegradable. Biodegradation: 100 % Page 144 of 328 Page 144 of 328 Page 144 of 328 Page 144 of 328 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Version 1.2 Revision Date: 02/18/2015 MSDS Number: 31378-00003 Date of last issue: 02/10/2015 Date of first issue: 12/11/2014 17 / 21 Exposure time: 28 d Method: Directive 67/548/EEC Annex V, C.4.C. Remarks: Based on data from similar materials Ammonium dodecyl sulphate: Biodegradability : Result: Readily biodegradable. Biodegradation: 75.7 % Exposure time: 28 d Method: OECD Test Guideline 301B Remarks: Based on data from similar materials Propylene glycol: Biodegradability : Result: Readily biodegradable. Biodegradation: 98.3 % Exposure time: 28 d Method: OECD Test Guideline 301F Bioaccumulative potential Ingredients: Ethanol: Partition coefficient: n- octanol/water : log Pow: -0.35 Alpha-Sulfo-omega-(dodecyloxy)-poly(oxy-1,2-ethanediyl), Ammonium salt: Partition coefficient: n- octanol/water : log Pow: 0.3 Ammonium dodecyl sulphate: Partition coefficient: n- octanol/water : log Pow: 0.8 - 0.91 Propylene glycol: Partition coefficient: n- octanol/water : log Pow: -1.07 Partition coefficient: n- octanol/water : log Pow: 3.27 Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. Contaminated packaging : Dispose of as unused product. Page 145 of 328 Page 145 of 328 Page 145 of 328 Page 145 of 328 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Version 1.2 Revision Date: 02/18/2015 MSDS Number: 31378-00003 Date of last issue: 02/10/2015 Date of first issue: 12/11/2014 18 / 21 Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION International Regulation UN number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S. (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : 3 IATA-DGR UN/ID No. : UN 1987 Proper shipping name : Alcohols, n.o.s. (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : Flammable Liquids Packing instruction (cargo aircraft) : 366 Packing instruction (passenger aircraft) : 355 IMDG-Code UN number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S. (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : 3 EmS Code : F-E, S-D Marine pollutant : no Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. Domestic regulation 49 CFR UN/ID/NA number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S. Class : 3 Packing group : III Labels : FLAMMABLE LIQUID ERG Code : 127 Page 146 of 328 Page 146 of 328 Page 146 of 328 Page 146 of 328 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Version 1.2 Revision Date: 02/18/2015 MSDS Number: 31378-00003 Date of last issue: 02/10/2015 Date of first issue: 12/11/2014 19 / 21 Marine pollutant : no SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Fire Hazard Acute Health Hazard SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. US State Regulations Right To Know Water 7732-18-5 70 - 90 % Ethanol 64-17-5 1 - 5 % Ammonium dodecyl sulphate 2235-54-3 1 - 5 % Alpha-Sulfo-omega-(dodecyloxy)-poly(oxy- 1,2-ethanediyl), Ammonium salt 67762-19-0 1 - 5 % Propylene glycol 57-55-6 1 - 5 % Ammonium sulfate 7783-20-2 0.1 - 1 % Propan-2-ol 67-63-0 0.1 - 1 % New Jersey Right To Know Water 7732-18-5 70 - 90 % Ethanol 64-17-5 1 - 5 % Ammonium dodecyl sulphate 2235-54-3 1 - 5 % Alpha-Sulfo-omega-(dodecyloxy)-poly(oxy- 1,2-ethanediyl), Ammonium salt 67762-19-0 1 - 5 % Propylene glycol 57-55-6 1 - 5 % California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: AICS : All ingredients listed or exempt. Inventories Page 147 of 328 Page 147 of 328 Page 147 of 328 Page 147 of 328 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Version 1.2 Revision Date: 02/18/2015 MSDS Number: 31378-00003 Date of last issue: 02/10/2015 Date of first issue: 12/11/2014 20 / 21 AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), NECSI (Taiwan), TSCA (USA) SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants US WEEL : USA. Workplace Environmental Exposure Levels (WEEL) ACGIH / STEL : Short-term exposure limit NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek OSHA Z-1 / TWA : 8-hour time weighted average US WEEL / TWA : 8-hr TWA Sources of key data used to compile the Material Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen- cy, http://echa.europa.eu/ Revision Date : 02/18/2015 The information provided in this Safety Data Sheet is correct to the best of our knowledge, in- formation and belief at the date of its publication. The information is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information pro- vided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, un- less specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, in- cluding an assessment of the appropriateness of the SDS material in the user’s end product, if applicable. Flammability Health Instability 3 3 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 3 0 3 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 148 of 328 Page 148 of 328 Page 148 of 328 Page 148 of 328 ---PAGE BREAK--- SAFETY DATA SHEET GOJO® Antibacterial Luxury Foam Handwash Chloroxylenol Liquid Version 1.2 Revision Date: 02/18/2015 MSDS Number: 31378-00003 Date of last issue: 02/10/2015 Date of first issue: 12/11/2014 21 / 21 US / Z8 Page 149 of 328 Page 149 of 328 Page 149 of 328 Page 149 of 328 ---PAGE BREAK--- GP Forward 8 General Purpose Cleaner SAFETY DATA SHEET Version Number: 2 Preparation date: 2015-06-25 1. IDENTIFICATION Product name: GP Forward 8 General Purpose Cleaner Product Code: 904516, 904518, 904523 SDS MS0800184 Recommended use: • Industrial/Institutional • Cleaning product • This product is intended to be diluted prior to use Uses advised against: Uses other than those identified are not recommended Emergency telephone number: 1-[PHONE REDACTED] 1-[PHONE REDACTED] (Int'l) 2. HAZARDS IDENTIFICATION Classification for the undiluted product Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Signal Word: Danger. Precautionary Statements CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE DAMAGE. Avoid contact with eyes, skin and clothing. Causes burns/ serious damage to mouth, throat and stomach. Keep container closed. Wash affected areas thoroughly after handling. Wear chemical-splash goggles and chemical-resistant gloves. IF SWALLOWED: Rinse mouth. DO NOT induce vomiting unless directed to do so by medical personnel. Drink a cupful of milk or water. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing for at least 15 minutes. Immediately call a Poison Center (1-[PHONE REDACTED]) or physician. Take off contaminated clothing and wash it before reuse. Dispose of in accordance with all federal, state and local applicable regulations. Health hazards not otherwise classified (HHNOC) - Not applicable Physical hazards not otherwise classified (PHNOC) - Not applicable Percentage of unknown Acute Toxicity 1.24846 (RC_EDTA) GP Forward 8 General Purpose Cleaner Manufacturer, importer, supplier: US Headquarters Diversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-1964 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.diversey.com 1 of 5 Canadian Headquarters Diversey, Inc. - Canada 3755 Laird Road Mississauga, Ontario L5L 0B3 Phone: 1-[PHONE REDACTED] Page 150 of 328 Page 150 of 328 Page 150 of 328 Page 150 of 328 ---PAGE BREAK--- 3. COMPOSITION/INFORMATION ON INGREDIENTS Classified Ingredients Ingredient(s) CAS # Weight % Alcohol ethoxylates 68439-46-3 1% - < 3% Tetrasodium salt of EDTA 64-02-8 1% - < 3% Sodium xylene sulfonate 1300-72-7 1% - < 3% Sodium silicate 1344-09-8 1% - < 3% Sodium hydroxide 1310-73-2 > 0.1% - < 1% *Exact percentages are being withheld as trade secret information 4. FIRST AID MEASURES Undiluted Product: Eyes: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing for at least 15 minutes. Skin: IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Inhalation: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Ingestion: IF SWALLOWED: Rinse mouth. DO NOT induce vomiting unless directed to do so by medical personnel. Drink a cupful of milk or water. Most Important No information available. Immediate medical attention and special treatment needed Not applicable. Aggravated Medical Conditions: Persons with pre-existing skin disorders may be more susceptible to irritating effects. 5. FIRE-FIGHTING MEASURES Specific methods: No special methods required Suitable extinguishing media: The product is not flammable. Extinguish fire using agent suitable for surrounding fire. Specific hazards: Not applicable. Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Extinguishing media which must not be used for safety reasons: No information available. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Put on appropriate personal protective equipment (see Section Environmental precautions and clean-up methods: Clean-up methods - large spillage. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use a water rinse for final clean-up. 7. HANDLING AND STORAGE Handling: Avoid contact with skin, eyes and clothing. Wash thoroughly after handling. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Classification for the diluted product @ 1:64 This product, when diluted as stated on the label, is not classified as hazardous according to OSHA 29CFR 1910.1200 (HazCom 2012-GHS) and Canadian Hazardous Products Regulations (HPR) (WHMIS 2015-GHS). Precautionary Statements None required. Diluted Product: GP Forward 8 General Purpose Cleaner 2 of 5 Eyes: Rinse with plenty of water If irritation occurs and persists, get medical attention. Skin: Rinse with plenty of water If irritation occurs and persists, get medical attention. Inhalation: No specific first aid measures are required Ingestion: Rinse mouth with water. Page 151 of 328 Page 151 of 328 Page 151 of 328 Page 151 of 328 ---PAGE BREAK--- Storage: Protect from freezing. Keep closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN. Aerosol Level (if applicable) : Not applicable 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines: . Ingredient(s) CAS # ACGIH OSHA Alcohol ethoxylates 68439-46-3 - - Tetrasodium salt of EDTA 64-02-8 - - Sodium xylene sulfonate 1300-72-7 - - Sodium silicate 1344-09-8 - - Sodium hydroxide 1310-73-2 2 mg/m3 (Ceiling) 2 mg/m3 (TWA) Undiluted Product: Engineering measures to reduce exposure: No special ventilation requirements General room ventilation is adequate Personal Protective Equipment Eye protection: Chemical-splash goggles. Hand protection: Chemical-resistant gloves. Skin and body protection: No special requirements under normal use conditions. Respiratory protection: No special requirements under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES: Explosion limits: - upper: Not determined - lower: Not determined * - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 10. STABILITY AND REACTIVITY Reactivity: Not Applicable Stability: The product is stable Hazardous decomposition products: None reasonably foreseeable. Materials to avoid: Acids. Conditions to avoid: No information available. 11. TOXICOLOGICAL INFORMATION Diluted Product: Personal Protective Equipment Eye protection: No personal protective equipment required under normal use conditions. Hand protection: No personal protective equipment required under normal use conditions. Skin and body protection: No personal protective equipment required under normal use conditions. Respiratory protection: No personal protective equipment required under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Physical State: Liquid Color: Clear, Green Evaporation Rate: No information available Odor: Citrus Fruity Odor threshold: No information available. Boiling point/range: Not determined Melting point/range: Not determined Decomposition temperature: Not determined Autoignition temperature: No information available Solubility: Completely Soluble Solubility in other solvents: No information available Relative Density (relative to water): 1.033 Density: 8.62 1.033 Vapor density: No information available Bulk density: No information available Vapor pressure: No information available. Flash point: > 200 °F > 93.3 °C Partition coefficient (n-octanol/water): No information available Dilution Flash Point: > 200 °F > 93.3 °C Viscosity: No information available Elemental Phosphorus: 0 % by wt. VOC: 0.18 % * pH: 12.9 VOC % by wt. at use dilution 0 % * GP Forward 8 General Purpose Cleaner 3 of 5 Dilution pH: 10.5 @ 1:64 Flammability (Solid or Gas): Not applicable Metal Corrosion: Not determined Page 152 of 328 Page 152 of 328 Page 152 of 328 Page 152 of 328 ---PAGE BREAK--- Information on likely routes of exposure: Eye contact, Skin contact, Inhalation, Ingestion Delayed, immediate, or chronic effects and from short and long-term exposure Skin contact: Causes skin irritation. may include pain (which may be delayed), redness, and/or discomfort. Eye contact: Corrosive. Causes serious eye damage. may include pain, burning sensation, redness, watering, blurred vision or loss of vision. Ingestion: Causes burns/ serious damage to mouth, throat and stomach. may include stomach pain and nausea. Inhalation: May cause irritation and corrosive effects to nose, throat and respiratory tract. may include coughing and difficulty breathing. Sensitization: No known effects. Target Organs (SE): None known Target Organs (RE): None known Numerical measures of toxicity ATE - Oral (mg/kg): >5000 ATE - Inhalatory, mists (mg/l): >20 Percentage of unknown Acute Toxicity 1.24846 (RC_EDTA) 12. ECOLOGICAL INFORMATION Ecotoxicity: No information available. Persistence and Degradability: No information available. Bioaccumulation: No information available. 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: This product, as sold, if discarded or disposed, is a hazardous waste according to Federal regulations (40 CFR 261.4 Dispose in compliance with all Federal, state, provincial, and local laws and regulations. This product, when diluted as stated on this SDS, is not a hazardous waste according to Federal regulations (40 CFR 261.4 Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal, whether the waste solution meets RCRA criteria for hazardous waste. Dispose in compliance with all Federal, state, provincial, and local laws and regulations. Contaminated Packaging: Do not re-use empty containers. RCRA Hazard Class (undiluted product): D002 Corrosive Waste RCRA Hazard Class (diluted product): Not Regulated 14. TRANSPORT INFORMATION DOT/TDG/IMDG: Proper shipping descriptions can vary by pack size. Please refer to the Diversey HazMat Library, only available through Internet Explorer, http://naextranet.diversey.com/dot/, for up to date shipping information. DOT (Ground) Bill of Lading Description: CLEANING, WASHING, BUFFING, OR POLISHING COMPOUNDS LIQUID IMDG (Ocean) Bill of Lading Description: CLEANING, WASHING, BUFFING, OR POLISHING COMPOUNDS LIQUID 15. REGULATORY INFORMATION International Inventories at CAS# Level All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL). U.S. Regulations GP Forward 8 General Purpose Cleaner 4 of 5 California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65. Page 153 of 328 Page 153 of 328 Page 153 of 328 Page 153 of 328 ---PAGE BREAK--- RIGHT TO KNOW (RTK) Ingredient(s) CAS # MARTK: PARTK: RIRTK: Water 7732-18-5 - - - - Alcohol ethoxylates 68439-46-3 - - - - Tetrasodium salt of EDTA 64-02-8 - - - - Sodium xylene sulfonate 1300-72-7 - - - - Sodium silicate 1344-09-8 - - - - CERCLA/ SARA SARA 311/312 Hazard Categories Immediate: X Delayed: - Fire: - Reactivity: - Sudden Release of Pressure: - Canadian Regulations 16. OTHER INFORMATION NFPA (National Fire Protection Association) Rating Scale: (Low Hazard) 0 - 4 (Extreme Hazard) Health 3 Flammability 0 Instability 0 Version Number: 2 Preparation date: 2015-06-25 Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: GP Forward 8 General Purpose Cleaner 5 of 5 • Contains an added fragrance, see "Odor" heading in section 9 for specific description Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Page 154 of 328 Page 154 of 328 Page 154 of 328 Page 154 of 328 ---PAGE BREAK--- Page 1 of 14 Safety Data Sheet acc. to HCS and GHS Printing date 11/24/2014 Reviewed on 11/24/2014 40.0 1 Identification · Product identifier · Trade name: Graffiti & Spray Paint Remover · Article number: 078 · Application of the substance / the mixture Graffiti remover · Details of the supplier of the Safety Data Sheet · Manufacturer/Supplier: ITW Pro Brands 805 East Old 56 Highway Olathe, Kansas 66061 Phone: 1-[PHONE REDACTED] · Emergency telephone number: Infotrac Emergency Hotline: 1-[PHONE REDACTED] 2 Hazard(s) identification · Classification of the substance or mixture GHS 04 gas cylinder H280 Contains gas under pressure; may explode if heated. GHS02 Flame Flam. Aerosol 1 H222-H229 Extremely flammable aerosol. Pressurized container: May burst if heated. GHS08 Health hazard Repr. 2 H361 Suspected of damaging fertility or the unborn child. Route of exposure: Inhalative. STOT RE 2 H373 May cause damage to the central nervous system through prolonged or repeated exposure. Route of exposure: Inhalative. Asp. Tox. 1 H304 May be fatal if swallowed and enters airways. GHS07 Skin Irrit. 2 H315 Causes skin irritation. STOT SE 3 H336 May cause drowsiness or dizziness. · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). (Contd. on page 2) Page 155 of 328 Page 155 of 328 Page 155 of 328 Page 155 of 328 ---PAGE BREAK--- Page 2 of 14 Safety Data Sheet acc. to HCS and GHS Printing date 11/24/2014 Reviewed on 11/24/2014 Trade name: Graffiti & Spray Paint Remover (Contd. of page 1) 40.0 · Hazard pictograms GHS02 GHS07 GHS08 · Signal word Danger · Hazard-determining components of labeling: toluene · Hazard statements H280 Contains gas under pressure; may explode if heated. H222-H229 Extremely flammable aerosol. Pressurized container: May burst if heated. H315 Causes skin irritation. H361 Suspected of damaging fertility or the unborn child. Route of exposure: Inhalative. H336 May cause drowsiness or dizziness. H373 May cause damage to the central nervous system through prolonged or repeated exposure. Route of exposure: Inhalative. H304 May be fatal if swallowed and enters airways. · Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P251 Pressurized container: Do not pierce or burn, even after use. P260 Do not breathe mist/vapours/spray. P211 Do not spray on an open flame or other ignition source. P281 Use personal protective equipment as required. P308+P313 IF exposed or concerned: Get medical advice/attention. P302+P352 If on skin: Wash with plenty of water. P405 Store locked up. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 P403+P233 Store in a well-ventilated place. Keep container closed. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Additional information: Pressurized container: May burst if heated. · Hazard description: · WHMIS-symbols: A - Compressed gas B5 - Flammable aerosol D2A - Very toxic material causing other toxic effects · Classification system: · NFPA ratings (scale 0 - 4) 1 4 0 Health = 1 Fire = 4 Reactivity = 0 (Contd. on page 3) Page 156 of 328 Page 156 of 328 Page 156 of 328 Page 156 of 328 ---PAGE BREAK--- Page 3 of 14 Safety Data Sheet acc. to HCS and GHS Printing date 11/24/2014 Reviewed on 11/24/2014 Trade name: Graffiti & Spray Paint Remover (Contd. of page 2) 40.0 · HMIS-ratings (scale 0 - 4) HEALTH FIRE REACTIVITY *1 4 0 Health = *1 Fire = 4 Reactivity = 0 * - Indicates a long term health hazard from repeated or prolonged exposures. · Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. 3 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Mixture of the substances listed below with nonhazardous additions. · Dangerous components: 108-88-3 toluene Flam. Liq. 2, H225 Repr. 2, H361; STOT RE 2, H373; Asp. Tox. 1, H304 Skin Irrit. 2, H315; STOT SE 3, H336 20-40% 72-28-5 Isobutane Flam. Gas 1, H220 10-20% 111-76-2 2-butoxyethanol Acute Tox. 4, H302; Acute Tox. 4, H312; Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319 Flam. Liq. 4, H227 1-5% 74-98-6 propane Flam. Gas 1, H220 Press. Gas, H280 1-5% 71011-25-1 Alkyl Quaternary ammonium bentonite Eye Irrit. 2A, H319 1-5% 4 First-aid measures · Description of first aid measures · General information: Take affected persons out into the fresh air. · After inhalation: Supply fresh air; consult doctor in case of complaints. Provide oxygen treatment if affected person has difficulty breathing. In case of irregular breathing or respiratory arrest provide artificial respiration. In case of unconsciousness place patient stably in side position for transportation. · After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. In cases of frostbite, rinse with plenty of water. Do not remove clothing. (Contd. on page 4) Page 157 of 328 Page 157 of 328 Page 157 of 328 Page 157 of 328 ---PAGE BREAK--- Page 4 of 14 Safety Data Sheet acc. to HCS and GHS Printing date 11/24/2014 Reviewed on 11/24/2014 Trade name: Graffiti & Spray Paint Remover (Contd. of page 3) 40.0 · After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If persist, consult a doctor. · After swallowing: Unlikely route of exposure. Rinse out mouth and then drink plenty of water. Do not induce vomiting; immediately call for medical help. · Most important and effects, both acute and delayed Headache Dizziness Nausea Gastric or intestinal disorders when ingested. Breathing difficulty Allergic reactions Coughing Irritant to skin and mucous membranes. Slight irritant effect on eyes. Disorientation · Danger Danger of impaired breathing. Vapours may cause drowsiness and dizziness. May damage fertility or the unborn child. Route of exposure: Inhalative. Route of exposure: Inhalative. Danger of disturbed cardiac Danger of pulmonary edema. Condition may deteriorate with alcohol consumption. Repeated exposure may cause skin dryness or cracking. Danger of serious damage to health by prolonged exposure. · Indication of any immediate medical attention and special treatment needed If swallowed, gastric irrigation with added, activated carbon. If necessary oxygen respiration treatment. Medical supervision for at least 48 hours. If swallowed or in case of vomiting, danger of entering the lungs. Treat skin and mucous membrane with antihistamine and corticoid preparations. 5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · For safety reasons unsuitable extinguishing agents: Water stream. · Special hazards arising from the substance or mixture Danger of receptacles bursting because of high vapor pressure if heated. Formation of toxic gases is possible during heating or in case of fire. · Advice for firefighters · Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. · Additional information Eliminate all ignition sources if safe to do so. (Contd. on page 5) Page 158 of 328 Page 158 of 328 Page 158 of 328 Page 158 of 328 ---PAGE BREAK--- Page 5 of 14 Safety Data Sheet acc. to HCS and GHS Printing date 11/24/2014 Reviewed on 11/24/2014 Trade name: Graffiti & Spray Paint Remover (Contd. of page 4) 40.0 Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Cool endangered product with water spray. 6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. If containers are leaking, use respiratory protective device against the effects of fumes/dust/aerosol. Ensure adequate ventilation. Keep away from ignition sources. · Environmental precautions: Do not allow to enter sewers/ surface or ground water. · Methods and material for containment and cleaning up: Allow to evaporate. Absorb liquid components with liquid-binding material. Pick up mechanically. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Send for recovery or disposal in suitable receptacles. · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage · Precautions for safe handling Keep away from heat and direct sunlight. Use only in well ventilated areas. Pressurized container: Do not pierce or burn, even after use. · Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Fumes can combine with air to form an explosive mixture. Flammable gas-air mixtures may be formed in empty receptacles. Do not spray on a naked flame or any incandescent material. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Observe official regulations on storing packagings with pressurized containers. Provide ventilation for receptacles. Avoid storage near extreme heat, ignition sources or open flame. · Information about storage in one common storage facility: Store away from foodstuffs. Store away from oxidizing agents. · Further information about storage conditions: Store in a cool place. Heat will increase pressure and may lead to the receptacle bursting. (Contd. on page 6) Page 159 of 328 Page 159 of 328 Page 159 of 328 Page 159 of 328 ---PAGE BREAK--- Page 6 of 14 Safety Data Sheet acc. to HCS and GHS Printing date 11/24/2014 Reviewed on 11/24/2014 Trade name: Graffiti & Spray Paint Remover (Contd. of page 5) 40.0 · Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection · Additional information about design of technical systems: No further data; see item 7. · Control parameters · Components with limit values that require monitoring at the workplace: 108-88-3 toluene PEL (USA) Long-term value: 200 ppm Ceiling limit value: 300; 500* ppm *10-min peak per 8-hr shift REL (USA) Short-term value: 560 mg/m³, 150 ppm Long-term value: 375 mg/m³, 100 ppm TLV (USA) Long-term value: 75 mg/m³, 20 ppm BEI EL (Canada) Long-term value: 20 ppm R EV (Canada) Long-term value: 20 ppm LMPE (Mexico) Long-term value: 20 ppm A4, IBE 111-76-2 2-butoxyethanol PEL (USA) Long-term value: 240 mg/m³, 50 ppm Skin REL (USA) Long-term value: 24 mg/m³, 5 ppm Skin TLV (USA) Long-term value: 97 mg/m³, 20 ppm BEI EL (Canada) Long-term value: 20 ppm EV (Canada) Long-term value: 20 ppm Skin LMPE (Mexico) Long-term value: 20 ppm A3, IBE 74-98-6 propane PEL (USA) Long-term value: 1800 mg/m³, 1000 ppm REL (USA) Long-term value: 1800 mg/m³, 1000 ppm TLV (USA) refer to Appendix F EL (Canada) Long-term value: 1000 ppm EV (Canada) Long-term value: 1.000 ppm LMPE (Mexico) Long-term value: 1000 ppm (Contd. on page 7) Page 160 of 328 Page 160 of 328 Page 160 of 328 Page 160 of 328 ---PAGE BREAK--- Page 7 of 14 Safety Data Sheet acc. to HCS and GHS Printing date 11/24/2014 Reviewed on 11/24/2014 Trade name: Graffiti & Spray Paint Remover (Contd. of page 6) 40.0 · Ingredients with biological limit values: 108-88-3 toluene BEI (USA) 0.02 mg/L Medium: blood Time: prior to last shift of workweek Parameter: Toluene 0.03 mg/L Medium: urine Time: end of shift Parameter: Toluene 0.3 mg/g creatinine Medium: urine Time: end of shift Parameter: o-Cresol with hydrolysis (background) 111-76-2 2-butoxyethanol BEI (USA) 200 mg/g creatinine Medium: urine Time: end of shift Parameter: Butoxyacetic acid with hydrolysis · Additional information: The lists that were valid during the creation were used as basis. · Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work. Do not inhale gases / fumes / aerosols. Pregnant women should strictly avoid inhalation or skin contact. Avoid contact with the eyes and skin. · Breathing equipment: Suitable respiratory protective device recommended. For spills, respiratory protection may be advisable. Use suitable respiratory protective device in case of insufficient ventilation. NIOSH or EN approved organic vapor respirator equipped with a dust/mist prefilter should be used. · Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves (Contd. on page 8) Page 161 of 328 Page 161 of 328 Page 161 of 328 Page 161 of 328 ---PAGE BREAK--- Page 8 of 14 Safety Data Sheet acc. to HCS and GHS Printing date 11/24/2014 Reviewed on 11/24/2014 Trade name: Graffiti & Spray Paint Remover (Contd. of page 7) 40.0 The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing · Limitation and supervision of exposure into the environment No further relevant information available. 9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Form: Aerosol Color: Light Tan · Odor: Aromatic · Odor threshold: Not determined. · pH-value: 6.3 - 7.3 · Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: Not applicable, as aerosol. · Flash point: < 2 °C 36 (liquid) · Flammability (solid, gaseous): Not applicable. · Auto-ignition temperature: Not determined. · Decomposition temperature: Not determined. · Auto igniting: Product is not self-igniting. · Danger of explosion: Product is not explosive. However, formation of explosive air/ vapor mixtures are possible. · Explosion limits: Lower: Not determined. Upper: Not determined. · Vapor pressure at 21 °C (70 125 psig · Density at 21 °C (70 0.94 g/cm³ (7.844 lbs/gal) · Relative density Not determined. · Vapour density > 1 (Air=1) (Contd. on page 9) Page 162 of 328 Page 162 of 328 Page 162 of 328 Page 162 of 328 ---PAGE BREAK--- Page 9 of 14 Safety Data Sheet acc. to HCS and GHS Printing date 11/24/2014 Reviewed on 11/24/2014 Trade name: Graffiti & Spray Paint Remover (Contd. of page 8) 40.0 · Evaporation rate Not applicable. · Solubility in / Miscibility with Water: Fully miscible. · Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Not determined. Kinematic: Not determined. · Solvent content: VOC content: 49.6 % · Other information No further relevant information available. 10 Stability and reactivity · Reactivity · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications. Danger of receptacles bursting because of high vapor pressure if heated. · Possibility of hazardous reactions Can form explosive mixtures in air if heated above flash point and/or when sprayed or atomized. Extremely flammable aerosol. Used empty containers may contain product gases which form explosive mixtures with air. Toxic fumes may be released if heated above the decomposition point. Reacts violently with oxidizing agents. Danger of receptacles bursting because of high vapor pressure if heated. · Conditions to avoid Keep away from heat and direct sunlight. Keep ignition sources away - Do not smoke. Store away from oxidizing agents. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: Carbon monoxide and carbon dioxide Hydrocarbons Nitrogen oxides 11 Toxicological information · Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: 108-88-3 toluene Oral LD50 5000 mg/kg (rat) Dermal LD50 12124 mg/kg (rabbit) Inhalative LC50/4h 5320 mg/l (mouse) (Contd. on page 10) Page 163 of 328 Page 163 of 328 Page 163 of 328 Page 163 of 328 ---PAGE BREAK--- Page 10 of 14 Safety Data Sheet acc. to HCS and GHS Printing date 11/24/2014 Reviewed on 11/24/2014 Trade name: Graffiti & Spray Paint Remover (Contd. of page 9) 40.0 · Primary irritant effect: · on the skin: Irritant to skin and mucous membranes. · on the eye: Slight irritant effect on eyes. · Sensitization: No sensitizing effects known. · Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant Inhalation of concentrated vapors as well as oral intake will lead to anaesthesia-like conditions and headache, dizziness, etc. Toxic and/or corrosive effects may be delayed up to 24 hours. Suspected of damaging fertility or the unborn child. Route of exposure: Inhalative. Route of exposure: Inhalative. · Carcinogenic categories · NTP (National Toxicology Program) None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. · Repeated Dose Toxicity: May cause damage to organs through prolonged or repeated exposure. 12 Ecological information · Toxicity · Aquatic toxicity: No further relevant information available. · Persistence and degradability The product is partially biodegradable. Significant residuals remain. · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Avoid transfer into the environment. Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects No further relevant information available. 13 Disposal considerations · Waste treatment methods · Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Contact waste processors for recycling information. The user of this material has the responsibility to dispose of unused material, residues and containers in compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and disposal for hazardous and nonhazardous wastes. Residual materials should be treated as hazardous. (Contd. on page 11) Page 164 of 328 Page 164 of 328 Page 164 of 328 Page 164 of 328 ---PAGE BREAK--- Page 11 of 14 Safety Data Sheet acc. to HCS and GHS Printing date 11/24/2014 Reviewed on 11/24/2014 Trade name: Graffiti & Spray Paint Remover (Contd. of page 10) 40.0 · Waste disposal key: EPA RCRA Code (USA) : D001, F005 . · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. 14 Transport information · UN-Number · DOT, ADR, IMDG, IATA UN1950 · UN proper shipping name Limited Quantity for packages less than 30 kg (66 lb) and inner packagings less than 1 L (0.3 gal). · DOT Aerosols, flammable · ADR 1950 AEROSOLS, flammable · IMDG AEROSOLS · IATA AEROSOLS, flammable · Transport hazard class(es) · DOT · Class 2.1 · Label 2.1 · ADR · Class 2 5F Gases · Label 2.1 · IMDG · Class 2 Gases · Label 2.1 · IATA · Class 2.1 · Label 2.1 (Contd. on page 12) Page 165 of 328 Page 165 of 328 Page 165 of 328 Page 165 of 328 ---PAGE BREAK--- Page 12 of 14 Safety Data Sheet acc. to HCS and GHS Printing date 11/24/2014 Reviewed on 11/24/2014 Trade name: Graffiti & Spray Paint Remover (Contd. of page 11) 40.0 · Packing group · DOT, ADR, IMDG, IATA Not Regulated · Environmental hazards: · Marine pollutant: No · Special precautions for user Warning: Gases · Danger code (Kemler): - · EMS Number: F-D,S-U · Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional information: · DOT · Quantity limitations On passenger aircraft/rail: 75kg On cargo aircraft only: 150kg · ADR · Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity · IMDG · Limited quantities (LQ) 1000mL · Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity · UN "Model Regulation": UN1950, Aerosols, 2.1 15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture · SARA · Section 355 (extremely hazardous substances): None of the ingredients is listed. · Section 313 (Specific toxic chemical listings): 108-88-3 toluene 111-76-2 2-butoxyethanol · TSCA (Toxic Substances Control Act): All ingredients are listed. · Proposition 65 (California) · Chemicals known to cause cancer: Present in trace quantities. 14808-60-7 Quartz (SiO2) · Chemicals known to cause reproductive toxicity for females: 108-88-3 toluene · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. (Contd. on page 13) Page 166 of 328 Page 166 of 328 Page 166 of 328 Page 166 of 328 ---PAGE BREAK--- Page 13 of 14 Safety Data Sheet acc. to HCS and GHS Printing date 11/24/2014 Reviewed on 11/24/2014 Trade name: Graffiti & Spray Paint Remover (Contd. of page 12) 40.0 · Chemicals known to cause developmental toxicity: 108-88-3 toluene · Carcinogenic categories · EPA (Environmental Protection Agency) 108-88-3 toluene II 111-76-2 2-butoxyethanol NL · IARC (International Agency for Research on Cancer) 108-88-3 toluene 3 111-76-2 2-butoxyethanol 3 · TLV (Threshold Limit Value established by ACGIH) 108-88-3 toluene A4 111-76-2 2-butoxyethanol A3 · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. · State Right to Know Listings Some ingredients listed. · Canadian substance listings: · Canadian Domestic Substances List (DSL) All ingredients are listed. · Canadian Ingredient Disclosure list (limit 0.1%) None of the ingredients is listed. · Canadian Ingredient Disclosure list (limit 108-88-3 toluene 111-76-2 2-butoxyethanol · Other regulations, limitations and prohibitive regulations This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Date of preparation / last revision 11/24/2014 / - · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances (Contd. on page 14) Page 167 of 328 Page 167 of 328 Page 167 of 328 Page 167 of 328 ---PAGE BREAK--- Page 14 of 14 Safety Data Sheet acc. to HCS and GHS Printing date 11/24/2014 Reviewed on 11/24/2014 Trade name: Graffiti & Spray Paint Remover (Contd. of page 13) 40.0 CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) WHMIS: Workplace Hazardous Materials Information System (Canada) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Flam. Gas 1: Flammable gases, Hazard Category 1 Flam. Aerosol 1: Flammable aerosols, Hazard Category 1 Press. Gas: Gases under pressure: Compressed gas Flam. Liq. 2: Flammable liquids, Hazard Category 2 Flam. Liq. 4: Flammable liquids, Hazard Category 4 Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A Repr. 2: Reproductive toxicity, Hazard Category 2 STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 STOT RE 2: Specific target organ toxicity - Repeated exposure, Hazard Category 2 Asp. Tox. 1: Aspiration hazard, Hazard Category 1 · Sources SDS Prepared by: ChemTel Inc. 1305 North Florida Avenue Tampa, Florida USA 33602-2902 Toll Free North America 1-[PHONE REDACTED] Intl. +01 [PHONE REDACTED] Website: www.chemtelinc.com Page 168 of 328 Page 168 of 328 Page 168 of 328 Page 168 of 328 ---PAGE BREAK--- N950 Page 1 of 2 5332 Dansher Road Illinois 60525 MATERIAL SAFETY DATA SHEET Revision Date: 4/6/2012 MSDS No. N950 Supersedes Date: 10/4/2011 Emergency Phones: [PHONE REDACTED] (NYCO) [PHONE REDACTED] (CHEMTREC) PLEASE NOTE: This MSDS is being provided to your company for the purpose of providing current health and safety information to your management and for your employees who work with this material. Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT-TO-KNOW regulations. Also make this information available to any employee who requests it. It is your obligation to comply with these regulations. SECTION I - PRODUCT IDENTITY PRODUCT NAME: GREEN KLEEN MULTI-PURPOSE CLEANER DEGREASER Formula: Mixture of propylene glycol ethers and detergents in water. Chemical Type: Organic compounds in water HMIS RATINGS Health = 0 (Minimal) Flammability = 0 (Minimal) Reactivity = 0 (Minimal) Protection = B (Safety goggles & gloves) SECTION II - HAZARDOUS INGREDIENTS CARCINOGEN PERCENT TLV (OSHA,TP,IARC) Dipropylene glycol methyl ether CAS # 34590-94-8 1-5% TWA – 100 ppm STEL – 150 ppm No SECTION III - CHEMICAL AND PHYSICAL Appearance: Clear Green Liquid Boiling Point: 212OF Odor: Sassafras Melting Point: N/A pH: 10.0-11.5 Spec. Gravity (H20 = 1.01 Water Solubility: Complete Vapor Pressure (Mm Hg): N/A Viscosity @ 25°C.: < 25 cps (Brookfield) VOC Content: 3.5% SECTION IV - FIRE AND EXPLOSION HAZARDS Flash Point (Method): > 200oF. (TCC) Explosion Limits: Upper: N/A Lower: N/A Extinguishing Media: Water fog, CO2, halon system, foam Special Firefighting Procedures and Hazards: Minimize prolonged skin and eye contact. Wear eye protection if exposure to liquid is likely. SECTION V - REACTIVITY INFORMATION Stable: Unstable: Precautions: Incompatibility: None known Hazardous Decomposition Products: If in a fire: CO, CO2, hydrocarbons. Hazardous Polymerization: Occurs: Does Not Occur: Page 169 of 328 Page 169 of 328 Page 169 of 328 Page 169 of 328 ---PAGE BREAK--- N950 Page 2 of 2 SECTION VI - HEALTH HAZARDS - PROTECTIVE MEASURES - FIRST AID Inhalation: Breathing of mists may cause irritation. Wear an approved mist respirator if exposure is likely. Remove to fresh air. Give artificial respiration or oxygen if needed. Skin: Extended contact may cause irritation and defatting. Wear protective gloves if needed. Wash skin with soap and plenty of water. Remove contaminated clothing and wash before wearing again. Eye: May cause irritation from misting. Wear splash proof goggles as needed. Flush with water for 15 minutes. If irritation persists consult a doctor. Ingestion: May cause mild gastric disturbances, nausea. Avoid swallowing. Drink lots of water or, preferably, milk. Do not induce vomiting. Get medical attention if effects persist. Most likely routes of entry: Skin, Eyes. Other Important Medical or Precautionary Information: None SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE Spills and Leaks: Small spills can be flushed into normal drainage or into ground with copious amounts of water, or taken up with absorbent material. Do not drain to sewer without dilution. Larger spills should be contained by diking or other methods and held for disposal or reuse. Storage and Handling: Check daily for any leaks from containers, vessels, pumps, and piping. Waste Disposal: May be disposable in sewers if local regulations permit. Otherwise, send to licensed treatment and disposal facility. Rinse well before handling and disposal. Observe label precautions. Empty Containers: Rinse well before handling and disposal. Observe label precautions. Other Precautions: N/A SECTION VIII - REGULATORY INFORMATION Reportable for SARA Title III, S.313 (Form None The information herein has been compiled from sources believed to be reliable and is accurate to the best of our knowledge. However, NYCO Products Company cannot give any guarantees regarding information from other sources, and expressly does not make any warranties, nor assumes any liability, for its use. Page 170 of 328 Page 170 of 328 Page 170 of 328 Page 170 of 328 ---PAGE BREAK--- Section 1. Chemical product and company identification Product Name: GRITMASTER CITRA CLEAN HAND CLEANER Product use: Cleaner Contact Information: Warsaw Chemical Co., Inc. P.O. Box 858 Warsaw, IN 46581 Tel: 1.[PHONE REDACTED] Fax: 1.[PHONE REDACTED] Emergency Phone: INFOTRAC [PHONE REDACTED] USA & Canada [PHONE REDACTED] International Section 2. Hazards identification GHS Classification: Serious eye damage/eye irritation(Category 2B) Pictogram(s): Signal Word: WARNING Hazard Statements: H320 Causes eye irritation Precautionary Statement(s): P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing Safety Data Sheet GRITMASTER CITRA CLEAN HAND CLEANER UNCONTROLLED DOCUMENT Warsaw Chemical Co., Inc. posts our Safety Data Sheets (SDS) to our company website ONLY. Warsaw Chemical is NOT responsible for any SDS found on other sites. Version 1.0010 Revision Date 02/24/2015 Print Date 02/24/2015 Page 171 of 328 Page 171 of 328 Page 171 of 328 Page 171 of 328 ---PAGE BREAK--- Section 3. Composition/information on ingredients Name CAS number % Less Than Alkali 1310-58-3 0.1000 Humectant 57-55-6 2.0000 Aloe Barbadensis Gel 8001-97-6 1.0000 SOLVENT 94266-47-4 14.0000 The chemical identity of some or all components is confidential business information (trade secret) and is being withheld as permitted by 29CFR19191200 No other ingredients known to be hazardous. Section 4. First aid measures Eye contact: Check for and remove contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. Skin contact: Wash skin surfaces thoroughly after contact. Wash clothing and clean shoes thoroughly before reuse. Get medical attention if irritation develops. Inhalation: Move exposed person to fresh air. If breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen clothing. Get medical attention immediately. Ingestion: Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. General: Physicians: No specific treatment. Treat Contact poison treatment specialist if large quantities have been inhaled or ingested. See Section 11 for exposure Pg 2/7 Safety Data Sheet GRITMASTER CITRA CLEAN HAND CLEANER UNCONTROLLED DOCUMENT Warsaw Chemical Co., Inc. posts our Safety Data Sheets (SDS) to our company website ONLY. Warsaw Chemical is NOT responsible for any SDS found on other sites. Version 1.0010 Revision Date 02/24/2015 Print Date 02/24/2015 Page 172 of 328 Page 172 of 328 Page 172 of 328 Page 172 of 328 ---PAGE BREAK--- Safety Data Sheet GRITMASTER CITRA CLEAN HAND CLEANER UNCONTROLLED DOCUMENT Warsaw Chemical Co., Inc. posts our Safety Data Sheets (SDS) to our company website ONLY. Warsaw Chemical is NOT responsible for any SDS found on other sites. Version 1.0010 Revision Date 02/24/2015 Print Date 02/24/2015 Section 5. Fire-fighting measures Flammability: In a fire or if heated, a pressure increase will occur and the container may burst. Extinguishing Media: Use an extinguishing agent suitable for the surrounding fire. Protective Equipment: Fire-fighters should wear appropriate protective equipment and self- contained breathing apparatus (SCBA) with full face-piece operated in positve pressure mode. Additional Information: Thermal decomposition products-carbon monoxide, sulfur oxides, metal oxide/ oxides, halogenated compounds. Section 6. Accidental release measures Personal Precautions: No action should be taken involving individual risk or without suitable training. Isolate area. Avoid contact with material. Do not breath vapors. Provide adequate ventilation. Wear proper personal protective equipment. Environmental: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform relevant authorities if the product reaches sewers, waterways or soil. Containment/Cleanup: Stop leak if without risk. Move containers from spill area. Contain or absorb with inert dry material. Dispose of according to local regulations. See Section 1 for emergency contact information and 13 for waste disposal. Section 7. Handling and storage Safe Handling: Wear appropriate personal protective equipment (see Section Eating drinking and smoking should be prohibited. Do not get into eyes or on skin Do not ingest. Keep containers closed. Do not reuse container. Safe Storage: Store in accordance with local regulations. Store in original container away from foods, drink and incompatible materials. Keep container closed. Do not store unlabeled. Use appropriate containment. Pg 3/7 Page 173 of 328 Page 173 of 328 Page 173 of 328 Page 173 of 328 ---PAGE BREAK--- Safety Data Sheet GRITMASTER CITRA CLEAN HAND CLEANER UNCONTROLLED DOCUMENT Warsaw Chemical Co., Inc. posts our Safety Data Sheets (SDS) to our company website ONLY. Warsaw Chemical is NOT responsible for any SDS found on other sites. Version 1.0010 Revision Date 02/24/2015 Print Date 02/24/2015 Section 8. Exposure controls/personal protection Engineering Controls: Apply technical measures to comply with occupational exposure limits. Mechanical ventilation, eyewash stations, showers where necessary. Eye Protection: Safety eyewear/face shield complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Respiratory Protection: Use a properly fitted air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates necessity. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product & the safe working limits of the chosen respirator. Hand Protection: Chemical resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Skin Protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. COMPONENT ACGIH TWA ppm OSHA/NIOSH STEL ppm OSHA/ACGHI STEL mg/m3 Humectant 10 SOLVENT 30 Section 9. Physical and chemical properties Physical State: Liquid Color: White Odor: Citrus Odor Threshold: N/E pH: 8.0-8.5 Melting Point: N/E Freezing Point: N/E Boiling Point: N/E Flash Point: Nonflammable Evaporation Rate: N/E Flammability: Nonflammable Upper Explosive Limits: N/A Lower Explosive Limits: N/A Vapor Pressure: N/E Vapor Density: N/E Relative Density: N/E Solubility: Soluble Partition coefficient: N/E Auto-Ignition Temperature: N/E Decompostion Temperature: N/E Specific Gravity: 0.99 % Volatile: 8% Pg 4/7 Page 174 of 328 Page 174 of 328 Page 174 of 328 Page 174 of 328 ---PAGE BREAK--- Section 10. Stability and reactivity Reactivity: Stable under normal conditions Chemical stability: Stable under normal conditions Possibility of hazardous reactions: None known Conditions to avoid: None Known Incompatible materials: Strong acids and oxidizers. Hazardous Decomposition Products: Material does not decompose at ambient temperatures. Section 11. Toxicological information Routes of entry: Inhalation Absorption Ingestion Acute Exposure Hazards: Eye contact: Irritation Dermal: None expected Oral: Nausea, diarrhea Inhalation: Minimally toxic based on test data for structurally similar materials. COMPONENT Result Species Dose Exposure Humectant LD50 ORAL Rabbit 20,000 mg/kg SOLVENT LD50 ORAL Rabbit >5 g/kg Pg 5/7 Safety Data Sheet GRITMASTER CITRA CLEAN HAND CLEANER UNCONTROLLED DOCUMENT Warsaw Chemical Co., Inc. posts our Safety Data Sheets (SDS) to our company website ONLY. Warsaw Chemical is NOT responsible for any SDS found on other sites. Version 1.0010 Revision Date 02/24/2015 Print Date 02/24/2015 Page 175 of 328 Page 175 of 328 Page 175 of 328 Page 175 of 328 ---PAGE BREAK--- Safety Data Sheet GRITMASTER CITRA CLEAN HAND CLEANER UNCONTROLLED DOCUMENT Warsaw Chemical Co., Inc. posts our Safety Data Sheets (SDS) to our company website ONLY. Warsaw Chemical is NOT responsible for any SDS found on other sites. Version 1.0010 Revision Date 02/24/2015 Print Date 02/24/2015 Section 12. Ecological information Ecotoxicity: No data available. Persistance & degradability: No data available. Bioaccumulative potential: No data available. Mobility in soil: No data available. Other adverse effects: No data available. Component Result Species Dose Exposure Section 13. Disposal considerations Material that cannot be saved for recovery or recycling should be managed in an appropriate and approved waste facility. Processing, use or contamination of this product may change the waste management options. Waste generators must decide if discarded material is a hazardous waste. State and local disposal regulations may differ from federal disposal definitions. Dispose of container and unused contents in accordance with federal, state and local requirements. Section 14. Transport information DOT (US) Hazard Class: UN Number: N/A Packing Group: N/A Shipping Name: Section 15. Regulatory information SARA 313 Components CAS No. % Less Than California Prop. 65 Components CAS No. % Less Than Pg 6/7 Page 176 of 328 Page 176 of 328 Page 176 of 328 Page 176 of 328 ---PAGE BREAK--- Safety Data Sheet GRITMASTER CITRA CLEAN HAND CLEANER UNCONTROLLED DOCUMENT Warsaw Chemical Co., Inc. posts our Safety Data Sheets (SDS) to our company website ONLY. Warsaw Chemical is NOT responsible for any SDS found on other sites. Version 1.0010 Revision Date 02/24/2015 Print Date 02/24/2015 Section 16. Other information Hazardous Material Information System Health Hazard 1 Fire Hazard 0 Reactivity 0 Personal Protection A Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks and 4 representing significant hazards or risks. PERSONAL PROTECTION INDEX A Safety Glasses B Safety Glasses, Gloves C Safety Glasses, Gloves, Apron D Face Shield, Gloves, Apron E Safety Glasses, Gloves, Dust Respirator F Safety Glasses, Gloves, Apron, Dust Respirator G Safety Glasses, Gloves, Vapor Respirator H Splash Goggles, Gloves, Apron, Dust & Vapor Respirator I Safety Glasses, Gloves, Dust & Vapor Respirator J Splash Goggles, Gloves, Apron, Dust & Vapor Respirator K Airline Hood or Mask, Gloves, Full Suit, Boots X Consult your supervisor for special handling directions National Fire Protection Association Health 1 Flammability 0 Instability/Reactivity 0 Special NFPA warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. Information on this form is furnished solely for the purpose of compliance with the Occupational Safety and Health Act of 1970 and shall not be used for any other purpose. Use or dissemination of all or any part of this information can be grounds for legal action. To the best of our knowledge, the information provided in this Safety Data Sheet is accurate as of the date of its issue. However, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE. The information this Safety Data Sheet contains is being given for safety guidance purposes and relates only to the specific material and uses described in it. This information does not necessarily apply to that material when combined with other material(s) or when used otherwise than as described herein. In all cases, it is the responsibility of the user to determine the applicability of such information and recommendations and the suitability of any product for its own particular purpose. All materials may represent unknown hazards and should be used with caution. Pg 7/7 Page 177 of 328 Page 177 of 328 Page 177 of 328 Page 177 of 328 ---PAGE BREAK--- SAFETY DATA SHEET 1 – PRODUCT AND COMPANY IDENTIFICATION 2 – HAZARDOUS IDENTIFICATION Emergency Overview May cause eye irritation Appearance: Clear gel Physical State: Liquid Odor: Mild Potential Health Effects: Principal Routes of Exposure: Eye contact. Skin Contact. Inhalation Acute Toxicity: Eyes: May cause irritation Skin: May cause slight irritation Chronic Effects: None known Aggravated Medical Conditions: None known Inhalation: Inhalation of mist or spray may cause irritation of respiratory tract. Ingestion: May cause irritation of the gastrointestinal tract. Environmental Hazard: None known 3 – COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No. Weight % Ethanol 64-17-5 60.0 -70.0 % Others < 2.0 % 4 – FIRST AID MEASURES Eyes: Flush eyes immediately with copious amounts of water for at least 15 minutes holding lids apart to ensure flushing of the entire surface. Washing eyes within 1 minute is essential to achieve maximum effectiveness. Seek medical attention. Skin: Wash thoroughly with soap and water. Remove contaminated clothing and footwear. Wash clothing prior to reuse. Seek medical attention if irritation should develop. Inhalation: Move to fresh air. If persist, seek medical attention. Ingestion: Have conscious patient drink several glasses of water. Keep the air passages clear. Do NOT induce vomiting. Seek medical help. Never give an unconscious patient anything by mouth. Notes to Physician: Treat 5 – FIRE-FIGHTING MEASURES Flammable Properties: Yes Flash Point: 30-320C Suitable Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Hazardous Combustion Products: Carbon oxides Explosion Data: Sensitivity to Mechanical Impact: No Sensitivity to Static Discharge: No Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health Hazard 2 Flammability 3 Stability 0 Physical & Chemical Hazards: Product Identifier: Hand Sanitizer Formula Various Issue Date: October 2014 Recommended Use: Personal care/Hand Sanitizer Manufacturer’s Apollo Health and Beauty Care Name & Address: 1 Apollo Place Toronto, Ontario, Canada M3J 0H2 Telephone No.: (416) 758-3700 Fax: (416) 758-3701 Website: www.apollocorp.com Page 178 of 328 Page 178 of 328 Page 178 of 328 Page 178 of 328 ---PAGE BREAK--- Page 2 of 4 SAFETY DATA SHEET Hand Sanitizer 6 – ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with eyes. Environmental Precautions: Refer to protective measures listed in sections 7 and 8. Methods of Containment: Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up: Dam up. Soak up with inert absorbent material. 7 – HANDLING AND STORAGE Handling: Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes. Storage: Keep closed in a dry and cool place. Keep in properly labeled containers. 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering Measures: Showers, Eyewash stations, Ventilation systems Personal Protective Equipment: Eye/Face Protection : Tight fitting safety goggles. Skin and Body Protection: No special protective equipment required Respiratory Protection: No protective equipment is needed under normal conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required Hygiene Measures: When using, do not eat, drink or smoke. Provide regular cleaning of equipment, work area and clothing. Wash hands before breaks and immediately after handling the product. Keep away from food, drink and animal feeding stuffs. 9-PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear Green Odor: Mild alcoholic odor Odor Threshold: Ethanol=0.1-5100 Physical State: Liquid pH: 6.0-8.0 Viscosity: 10,000-25,000cps Flash Point: 30-320C Decomposition Temperature: No data available Boiling Point/Range: 80-850C Melting Point / Range: No data available Water Solubility: Soluble in water Solubility: No data available Evaporation Rate: > 1.7 Vaporation Rate: No data available Patition Coeficient:n-octanol/water: No data available 10-STABILITY AND REACTIVITY Stability: Stable under recommended storage conditions. Conditions to avoid: Strong acids, strong bases, strong oxidizing agents Incompatible Products: Not known Hazardous Decomposition Products: Carbon oxides Hazardous Polymerization: Does not occur 11 – TOXICOLOGICAL INFORMATION Acute toxicity: Eye Contact: Irritating to eyes Skin Contact: May cause irritation Ingestion: No hazard from product as supplied. Ingestion may cause irritation to mucous membranes. Chronic toxicity: No known effect based on known information Genetic toxicity: No known effect based on known information based on experimental/calculated data. Aspiration Hazard: No aspiration hazard expected Target Organ Effects: None known 12 – ECOLOGICAL INFORMATION Ecotoxicity The environmental impact of this has not been fully investigated. Fish Acute: No data available regarding toxicity to fish Chronic: No data available regarding toxicity to fish Aquatic invertebrates Acute: No data available regarding toxicity Chronic: No data available regarding toxicity Page 179 of 328 Page 179 of 328 Page 179 of 328 Page 179 of 328 ---PAGE BREAK--- Page 3 of 4 SAFETY DATA SHEET Hand Sanitizer 13– DISPOSAL CONSIDERATIONS Waste Disposal Methods: This material, as supplied, is not a hazardous waste according to Federal Regulations (40 CFR Part 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR Part 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements. 14 – TRANSPORT INFORMATION DOT Hazard Class- ORM-D Shipping Name- Consumer commodity TDG Hazard Class- 3 PIN- UN # 1170 (Alcohol Solution) MEX Hazard Class- ORM-D Shipping Name- Consumer commodity ICAO Hazard Class- ORM-D ID 8000 Shipping Name- Consumer commodity IATA Hazard Class- ORM-D ID 8000 Shipping Name- Consumer commodity IMDG/IMO Hazard Class- ORM-D Shipping Name- Consumer commodity 15– REGULATORY INFORMATION International Inventories: TSCA: Complies DSL: Not determined EINECS: Complies U.S. Federal Regulations: SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: NONE Chemical Name CAS No Weight % SARA 313 - Threshold Value % SARA 311/312 Hazard Categories: Acute Health Hazard: No Chronic Health Hazard: No Fire Hazard: No Sudden Release of Pressure Hazard: No Reactive Hazard: No Clean Water Act This product does not contain any substances regulated as pollutants pursuant to Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. U.S. State Regulations: California Proposition 65 This product does not contain any Proposition 65 chemicals. Page 180 of 328 Page 180 of 328 Page 180 of 328 Page 180 of 328 ---PAGE BREAK--- Page 4 of 4 Hand Sanitizer 16 – OTHER INFORMATION All the information, recommendations, and suggestions appearing herein concerning our product are based upon tests and data believed to be reliable. However, it is the user’s responsibility to determine the safety, toxicity, and suitability for his own use of the product described herein. Since the actual use by others is beyond our control, no guarantee, expressed or implied, is made by as to the effects of such use, the results to be obtained, or the safety and toxicity of the product nor does assume any liability arising out of use by others or the product referred to herein. The information herein is not to be construed as absolutely complete since additional information may be necessary or described when particular or exceptional conditions or circumstances exist or because of applicable laws or government regulations. Prepared by: Derek Sanderson, Director of Research and Development Telephone: (416) 758-3700 Fax: (416) 758-3701 E-Mail: [EMAIL REDACTED] Page 181 of 328 Page 181 of 328 Page 181 of 328 Page 181 of 328 ---PAGE BREAK---  


 

        



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Page 187 of 328 Page 187 of 328 Page 187 of 328 Page 187 of 328 ---PAGE BREAK---  Page 188 of 328 Page 188 of 328 Page 188 of 328 Page 188 of 328 ---PAGE BREAK--- N167 Page 1 of 2 5332 Dansher Road Illinois 60525 MATERIAL SAFETY DATA SHEET Revision Date: 7/3/2012 MSDS No. N167 Supersedes Date: 6/2/2011 Emergency Phones: [PHONE REDACTED] (NYCO) [PHONE REDACTED] (CHEMTREC) PLEASE NOTE: This MSDS is being provided to your company for the purpose of providing current health and safety information to your management and for your employees who work with this material. Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT-TO-KNOW regulations. Also make this information available to any employee who requests it. It is your obligation to comply with these regulations. SECTION I - PRODUCT IDENTITY PRODUCT NAME: Hard Coat 19 Floor Finish Formula: Mixture acrylic polymer, plasticizer, solubilizers and wax in water Chemical Type: As above HMIS RATINGS Health = 1 (Minimal) Flammability = 0 (Minimal) Reactivity = 0 (Minimal) Protection = B (Goggles & Gloves) SECTION II - HAZARDOUS INGREDIENTS CARCINOGEN PERCENT TLV (OSHA,TP,IARC) Diethylene glycol methyl ether 1-5% None No CAS No. 111-77-3 Tributoxyethyl phosphate 1-4% None No CAS No. 78-51-3 SECTION III - CHEMICAL AND PHYSICAL Appearance: White emulsion Boiling Point: 212oF. Odor: Typical acrylic polymer Melting Point: N/A pH: 8.0-9.0 Spec. Gravity (H20 = 1.025 Water Solubility: Complete Vapor Pressure (mm Hg): N/A Viscosity @ 25°C: < 25 cps (Brookfield) VOC Content: 3% SECTION IV - FIRE AND EXPLOSION HAZARDS Flash Point (Method): N/A Explosion Limits: Upper: N/A Lower: N/A Extinguishing Media: Product is non-flammable Special Firefighting Procedures and Hazards: This applies to liquid product only. If in a fire: CO, CO2, hydrocarbons. If floor polish is cured on the floor, the flooring could burn in a fire and produce hazardous materials from tile degradation etc. SECTION V - REACTIVITY INFORMATION Stable: Unstable: Precautions: Incompatibility: Strong oxidizing agents. Hazardous Decomposition Products: This applies to liquid product only. If in a fire: CO, CO2, hydrocarbons. If floor polish is cured on the floor, the flooring could burn in a fire and produce hazardous materials from tile degradation etc. Hazardous Polymerization: Occurs: Does Not Occur: Page 189 of 328 Page 189 of 328 Page 189 of 328 Page 189 of 328 ---PAGE BREAK--- N167 Page 2 of 2 SECTION VI - HEALTH HAZARDS - PROTECTIVE MEASURES - FIRST AID Inhalation: Breathing of mists may cause irritation. Remove to fresh air. Give artificial respiration or oxygen if needed. Skin: Extended contact may cause irritation or defatting. Wear protective gloves if necessary. Flush skin with water for 15 minutes. Get medical attention for any irritation. Eyes: Can cause irritation. Wear goggles as needed. Flush immediately with water for 15 minutes. Get prompt medical attention if needed. Ingestion: May cause a mild gastric disturbance. Drink lots of water or, preferably milk or juices. Do not induce vomiting. Get medical attention if effects persist. Most likely routes of entry: Skin, Eyes. Other Important Medical or Precautionary Information: None SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE Spills and Leaks: Small spills can be flushed into normal drainage or into ground with copious amounts of water, or taken up with absorbent material. Larger spills should be contained by diking or other methods and held for disposal or reuse. Storage and Handling: Check daily for any leaks from containers, vessels, pumps, and piping. Waste Disposal: Product may be disposable in sewers if local regulations permit. Otherwise send to a licensed treatment facility. Empty Containers: Rinse well before handling and disposal. Observe label precautions. Other Precautions: None SECTION VIII - REGULATORY INFORMATION Reportable for SARA Title III, S.313 (Form none The information herein has been compiled from sources believed to be reliable and is accurate to the best of our knowledge. However, NYCO Products Company cannot give any guarantees regarding information from other sources, and expressly does not make any warranties, nor assumes any liability, for its use. Page 190 of 328 Page 190 of 328 Page 190 of 328 Page 190 of 328 ---PAGE BREAK--- HOSPECO HEALTH GARDS METERED AIR FRESHENERS BABY POWDER 07909; VERY VANILLA 07915; MANGO MADNESS 07917; FRESH LINEN 07918; FRUIT BASKET 07929; ORCHARD SPICE 07930; CITRUS GROVE 07931; FRESH GARDEN 07932; Material Safety Data Sheet Quick Identifier (In Plant Common Name) Manufacturer’s Name & Address HOSPECO 26301 Curtiss-Wright Parkway Cleveland, Ohio 44143 HMIS Symbol: Health 1 Flammability 3 Reactivity 0 HMIS Minimal Slight Moderate Serious Severe 0 1 2 3 4 NFPA Insignificant Slight Moderate High Extreme NFPA Symbol: Telephone No. 1-[PHONE REDACTED] Date Prepared: May 23, 2012 Prepared By: Supercedes: NEW SECTION 1 - IDENTITY Common Name: (used on label) (Trade name & Synonyms) HOSPECO HEALTH GARDS AIR FRESHENERS: HG BABY POWDER 07909; VERY VANILLA 07915; MANGO MADNESS 07917; FRESH LINEN 07918; FRUIT BASKET 07929; ORCHARD SPICE 07930; CITRUS GROVE 07931; FRESH GARDEN 07932; Chemical Name Mixture packaged in pressurized aerosol spray can. SECTION 2 - HAZARDOUS INGREDIENTS Principal Hazardous Component(s) CAS No. OSHA PEL ACGIH TLV Other Limits 2-Propanone 67-64-1 1000 ppm 500 ppm 750 ppm STEL Liquefied Petroleum Gas 68476-86-8 Unknown 1000 ppm *Section 313 Supplier Notification - Indicates hazardous ingredients which are toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372. SECTION 3 - PHYSICAL & CHEMICAL CHARACTERISTICS Boiling Point >100°F Specific Gravity (H20=1)(Conc) 0.78 – 0.81g/ml Vapor Pressure (Propellant) No Data % - VOC 29.50% Evaporation Rate (BuAc=1) >1.00 pH N/A Solubility In Water Insoluble Appearance and Odor(Conc) Water white clear liquid with a characteristic odor(s) SECTION 4 - FIRE & EXPLOSION DATA Flammability (per flame projection) FLAMMABLE Flammable Limits in Air (Propellants) Lower N/A Upper N/A Extinguisher Media Dry chemical, CO2, Alcohol-resistant foam Special Fire Fighting Procedures Keep containers cool using water spray. Use proper equipment to protect personnel from bursting containers. Unusual Fire and Explosion Hazards Contents under pressure. Do not expose to temperatures exceeding 120° F as containers may vent, rupture or burst. SECTION 5 - PHYSICAL HAZARDS Stability Unstable □ Stable ■ Conditions to Avoid Heat, sparks open flames; Temp. > 120°F. Hazardous Polymerization May Occur □ Will not Occur ■ Incompatibility (Materials to Avoid) Acids, alkalis, Reducing agents, Strong oxidizing agents Hazardous Decomposition Products CO and CO2 SECTION 6 - HEALTH HAZARDS Routes of Entry Inhalation: Yes Eyes / Skin: Yes Ingestion: Unlikely Page 191 of 328 Page 191 of 328 Page 191 of 328 Page 191 of 328 ---PAGE BREAK--- 1254129 / 9014118 / 9004129; 1274109 / 9036195 / 9024109; 1274111 / 9036195 / 9024111; 1254118 / 9004118 / 9014118; 1254119 / 9014118 / 9004119; 1254124 / 9014118 / 9004124; 1254127 / 9014118 / 9004127; 1254128 / 9014118 / 9004128 122305 Signs and of Exposure (Acute & Chronic) Eye contact: Can cause eye irritation. include stinging, tearing, redness, and swelling of eyes; Skin contact: May cause mild skin irritation. Prolonged or repeated contact may dry the skin. may include redness, burning, drying and cracking of skin, and skin burns. Passage of this material into the body through the skin is possible, but it is unlikely that this would result in harmful effects during safe handling and use. Ingestion: Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. This material can get into the lungs during swallowing or vomiting. This can result into lung inflammation and other lung injury; Inhalation: Breathing of vapor or mist is possible. Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Medical Conditions Generally Aggravated by Exposure Pre-existing skin and lung disorders Chemical Listed as Carcinogen or Potential Carcinogen National Toxicology Program Yes No   I.A.R.C. Monographs Yes No   OSHA Yes No   Emergency and First Aid Procedures 1. Inhalation Immediately move to fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention. 2. Eyes Immediately move to fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention. 3. Skin Remove contaminated clothing. Wash exposed area with soap and water. If persist, seek medical attention. Launder clothing before reuse. 4. Ingestion Seek medical attention. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. SECTION 7 – SPECIAL PROTECTION INFORMATION Respiratory Protection (Specify Type) None required for normal use. Ventilation Local Exhaust Maintain adequate ventilation. Mechanical (General) N/A Special N/A Other N/A Protective Gloves Chemical Resistant Eye Protection Safety Glasses Other Protective Clothing or Equipment Wash hands after use. SECTION 8 – SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES Precautions to be Taken Handling and Storage WARNING: FLAMMABLE. Contents under pressure. Keep away from heat, sparks and open flames. Excessive inhalation in confined areas may cause headaches or dizziness. Intentional misuse by deliberately concentrating or inhaling the contents may be harmful or fatal. Avoid contact with skin and eyes. Avoid contact with food and food handling surfaces. Avoid contact with painted, varnished or plastic surfaces. Do not store at temperatures above 120°F. Do not puncture or incinerate containers. Keep out of reach of children. Store in accordance with NFPA 30B for Level 3 Aerosols. Other Precautions Read label cautions carefully. Follow label directions to avoid injury. Steps to be Taken in Case Material is Released or Spilled Absorb spill with inert material then place in a chemical waste container. Dispose of spill material in accordance with regulations. Waste Disposal Methods Dispose of in accordance with local, state, and federal regulations. Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986: This product is not known to contain any chemicals currently listed as carcinogens or reproductive toxins under California Proposition 65 at levels which would be subject to the proposition. Transportation Info DOT CLASSIFICATION: HAZARDOUS PACKING GROUP: N/A DESCRIPTION: CONSUMER COMMODITY, ORM-D UN NUMBER: UN 1950 HAZARD CLASS: 2.1 We believe all information given is accurate. It is offered in good faith, but without guarantee. Since conditions are beyond our control, user assumes all responsibility and risk. Page 192 of 328 Page 192 of 328 Page 192 of 328 Page 192 of 328 ---PAGE BREAK--- SAFETY DATA SHEET Spectrum Group Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Hot Shot Natural Flying Insect Killer 1-[PHONE REDACTED] HG-95844 21-1082 Page 1 SDS Date: 03/11/15 Product Name: Hot Shot Natural Flying Insect Killer CAS Aerosol Product Use: Flying Insect Killer Aerosol Manufacturer: Chemsico Div. of United Industries Corp. P.O. Box 142642 St. Louis, MO 63114 This product is classified according to the Globally Harmonized System (GHS). ROUTES OF EXPOSURE Potential short term health effects: Eyes, Skin Eyes: Causes moderate eye irritation. Skin: May cause skin irritation. Inhalation: No expected reaction. Ingestion: No expected reaction. Target organs: Eyes, Skin Chronic effects: Prolonged or repeated exposure can cause drying, defatting and dermatitis. Signs and may include redness, edema, drying, defatting and cracking of the skin. Composition comments: This product is considered not hazardous under 29 CFR 1910.1200 (Hazard Communication). NOTE: No reportable quantities of hazardous ingredients are present per OSHA 29 CFR 1910.1200. No toxic chemical(s) subject to reporting requirements of Section 313 of Title III and 40 CFR 372 are present. ACTIVE COMPONENT CAS# PERCENTAGE Lemongrass Oil 8007-02-1 3.00% Carbon Dioxide 124-38-9 2.50% OTHER COMPONENT CAS# PERCENTAGE Other N/A 94.50% Note: Ingredients not identified are not hazardous. SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION SECTION 2 - HAZARDS IDENTIFICATION SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS Page 193 of 328 Page 193 of 328 Page 193 of 328 Page 193 of 328 ---PAGE BREAK--- SAFETY DATA SHEET Spectrum Group Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Hot Shot Natural Flying Insect Killer 1-[PHONE REDACTED] HG-95844 21-1082 Page 2 FIRST AID PROCEDURES Eye contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses if present after the first 5 minutes then continue rinsing eye. Contact a physician for treatment advice. Skin contact: Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum or using the toilet. Inhalation: None required Ingestion: None required Note to Physician: Skin may be delayed. General advice: If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Keep out of reach of children. Flammable properties: Pressurized Aerosol Container. SUITABLE EXTINGUISHING MEDIA Extinguishing media: Water Fog, Foam, CO2, Dry Chemical Unsuitable extinguishing media: Not Available SPECIFIC HAZARDS ARISING FROM THE CHEMICAL Protection of firefighters: Not Available Protective equipment for firefighters: Firefighters should wear full protective clothing including self-contained breathing apparatus. Hazardous combustion products: None known SENSITIVITY TO MECHANICAL IMPACT Explosion data: Not Available Sensitivity to static discharge: Not Available Personal precautions: Keep unnecessary personnel away. Do not touch or walk through spilled material. HMIS Ratings Health Hazard 1 Fire Hazard 0 Reactivity 0 Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. SECTION 4 - FIRST AID MEASURES SECTION 5 - FIRE FIGHTING MEASURES SECTION 6 - ACCIDENTAL RELEASE MEASURES Page 194 of 328 Page 194 of 328 Page 194 of 328 Page 194 of 328 ---PAGE BREAK--- SAFETY DATA SHEET Spectrum Group Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Hot Shot Natural Flying Insect Killer 1-[PHONE REDACTED] HG-95844 21-1082 Page 3 Methods for cleaning up: Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with earth, sand or absorbent material swept up and placed in suitable, covered, and labeled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills in original containers for re-use. Handling: Use good industrial hygiene practices in handling this material. Storage: Keep out of reach of children. Store in a closed container away from incompatible materials. Engineering controls: General ventilation normally adequate. EYE / FACE PROTECTION Personal protective equipment: None required Hand protection: None required Skin and body protection: None required Respiratory protection: None required General hygiene considerations: Handle in accordance with good industrial hygiene and safety practice. When using, do not eat or drink. Wash hands before breaks and immediately after handling the product. Appearance: Clear to hazy Color: Yellow Form: Aerosol Odor: Lemongrass & Wintergreen Odor threshold: Not Available Physical state: Pressurized liquid pH: 8.3 Freezing point: 32°F Boiling point: 212°F Flash point: 1300F (liquid portion) Flame Extension 0” (level 1 aerosol) Flammability limits in air, lower, % by volume: Not Available SECTION 7 - HANDLING AND STORAGE SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES Page 195 of 328 Page 195 of 328 Page 195 of 328 Page 195 of 328 ---PAGE BREAK--- SAFETY DATA SHEET Spectrum Group Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Hot Shot Natural Flying Insect Killer 1-[PHONE REDACTED] HG-95844 21-1082 Page 4 Flammability limits in air, upper, % by volume: Not Available Vapor pressure: Not Available Vapor density: Not Available Specific gravity: 0.985 Octanol/water coefficient: Not Available Auto-ignition temperature: Not Available Chemical stability: Stable under recommended storage conditions. Conditions to avoid: Do not mix with other chemicals. Incompatible materials: Avoid strong oxidizers. Hazardous decomposition products: None known. Possibility of hazardous reactions: Hazardous polymerization does not occur. EFFECTS OF ACUTE EXPOSURE Eye: Causes temporary eye injury. Skin: May cause skin irritation. Inhalation: LC50 > 2mg/L (EPA Tox category IV) Ingestion: LD50 > 5000 mg/kg Sensitization: Not a skin sensitizer. Chronic effects/ Carcinogenicity: Not Available Mutagenicity: Not Available Reproductive effects: Not Available Teratogenicity: Not Available Ecotoxicity: Not Available Environmental effects: Not Available Aquatic toxicity: Not Available Persistence / degradability: Not Available Bioaccumulation / accumulation: Not Available Partition coefficient: Not Available Mobility in environmental media: Not Available Chemical fate information: Not Available SECTION 10 - CHEMICAL STABILITY & REACTIVITY INFORMATION SECTION 11 - TOXICOLOGICAL INFORMATION SECTION 12 - ECOLOGICAL INFORMATION Page 196 of 328 Page 196 of 328 Page 196 of 328 Page 196 of 328 ---PAGE BREAK--- SAFETY DATA SHEET Spectrum Group Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Hot Shot Natural Flying Insect Killer 1-[PHONE REDACTED] HG-95844 21-1082 Page 5 Waste codes: Not Available Disposal instructions: Dispose in accordance with all applicable regulations. Waste from residues / unused products: Not Available Contaminated packaging: Not Available U.S. Department of Transportation (DOT): Aerosols, Flammable, 2.1, UN-1950, Limited Quantity U.S. Federal regulations: This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. IATA: 1950, Aerosols, Flammable, 2.1 IMDG: 1950, Aerosols, 2.1, Limited Quantity 29 CFR 1910.1200 hazardous chemical Occupational Safety and Health Administration (OSHA): No CERCLA (Superfund) reportable quantity: Not Available HAZARD CATEGORIES Superfund Amendments and Reauthorization Act of 1986 (SARA): Immediate Hazard No Delayed Hazard No Fire Hazard No Pressure Hazard No Reactivity Hazard No Section 302 extremely hazardous Substance: No Section 311 hazardous chemical: No Clean Air Act (CAA): Not Available Clean Water Act (CWA): Not Available State regulations: INVENTORY STATUS Inventory Country(s) or region name on inventory (yes/no)*: N/A, Regulated by EPA SECTION 13 - DISPOSAL CONSIDERATIONS SECTION 14 - TRANSPORTATION INFORMATION SECTION 15 - REGULATORY INFORMATION Page 197 of 328 Page 197 of 328 Page 197 of 328 Page 197 of 328 ---PAGE BREAK--- SAFETY DATA SHEET Spectrum Group Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Hot Shot Natural Flying Insect Killer 1-[PHONE REDACTED] HG-95844 21-1082 Page 6 Disclaimer: Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. Issue date: 3/11/15 Prepared by: United Industries Corp. (800) 242-1166 SECTION 16 - OTHER INFORMATION Page 198 of 328 Page 198 of 328 Page 198 of 328 Page 198 of 328 ---PAGE BREAK--- Page 199 of 328 Page 199 of 328 Page 199 of 328 Page 199 of 328 ---PAGE BREAK--- Page 200 of 328 Page 200 of 328 Page 200 of 328 Page 200 of 328 ---PAGE BREAK--- Page 201 of 328 Page 201 of 328 Page 201 of 328 Page 201 of 328 ---PAGE BREAK--- Page 202 of 328 Page 202 of 328 Page 202 of 328 Page 202 of 328 ---PAGE BREAK--- Page 203 of 328 Page 203 of 328 Page 203 of 328 Page 203 of 328 ---PAGE BREAK--- Page 204 of 328 Page 204 of 328 Page 204 of 328 Page 204 of 328 ---PAGE BREAK--- Page 205 of 328 Page 205 of 328 Page 205 of 328 Page 205 of 328 ---PAGE BREAK--- Page 206 of 328 Page 206 of 328 Page 206 of 328 Page 206 of 328 ---PAGE BREAK--- Page 207 of 328 Page 207 of 328 Page 207 of 328 Page 207 of 328 ---PAGE BREAK--- Page 208 of 328 Page 208 of 328 Page 208 of 328 Page 208 of 328 ---PAGE BREAK--- Page 209 of 328 Page 209 of 328 Page 209 of 328 Page 209 of 328 ---PAGE BREAK--- Product Name: MOBIL DTE OIL HEAVY Revision Date: 17 Mar 2015 Page 1 of 10 SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: MOBIL DTE OIL HEAVY Product Description: Base Oil and Additives Product Code: 201560501580, 600189-00, 970106 Intended Use: Turbine oil COMPANY IDENTIFICATION Supplier: EXXON MOBIL CORPORATION 22777 Springwoods Village Parkway Spring, TX. 77389 USA 24 Hour Health Emergency [PHONE REDACTED] Transportation Emergency Phone [PHONE REDACTED] or [PHONE REDACTED] CHEMTREC Product Technical Information [PHONE REDACTED] MSDS Internet Address http://www.exxon.com, http://www.mobil.com SECTION 2 HAZARDS IDENTIFICATION This material is not hazardous according to regulatory guidelines (see (M)SDS Section 15). Other hazard information: HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200. PHYSICAL / CHEMICAL HAZARDS No significant hazards. HEALTH HAZARDS High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, or respiratory irritation. ENVIRONMENTAL HAZARDS No significant hazards. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. Page 210 of 328 Page 210 of 328 Page 210 of 328 Page 210 of 328 ---PAGE BREAK--- Product Name: MOBIL DTE OIL HEAVY Revision Date: 17 Mar 2015 Page 2 of 10 SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS This material is defined as a mixture. Hazardous Substance(s) or Complex Substance(s) required for disclosure Name CAS# Concentration* GHS Hazard Codes 128-39-2 0.1 - < 1% H315, H319(2A), H400(M factor H410(M factor 1) * All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. As per paragraph of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and exact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact percentage composition will be provided to health professionals, employees, or designated representatives in accordance with applicable provisions of paragraph SECTION 4 FIRST AID MEASURES INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Page 211 of 328 Page 211 of 328 Page 211 of 328 Page 211 of 328 ---PAGE BREAK--- Product Name: MOBIL DTE OIL HEAVY Revision Date: 17 Mar 2015 Page 3 of 10 Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Incomplete combustion products, Smoke, Fume, Sulfur oxides, Oxides of carbon, Aldehydes FLAMMABILITY PROPERTIES Flash Point [Method]: >215°C (419°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802. PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended. SPILL MANAGEMENT Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, Page 212 of 328 Page 212 of 328 Page 212 of 328 Page 212 of 328 ---PAGE BREAK--- Product Name: MOBIL DTE OIL HEAVY Revision Date: 17 Mar 2015 Page 4 of 10 sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE HANDLING Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present during switch-loading operations). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. STORAGE The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store in open or unlabelled containers. Keep away from incompatible materials. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols can occur the following are recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction), 5 mg/m³ - OSHA PEL. NOTE: Limits/standards shown for guidance only. Follow applicable regulations. No biological limits allocated. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. Page 213 of 328 Page 213 of 328 Page 213 of 328 Page 213 of 328 ---PAGE BREAK--- Product Name: MOBIL DTE OIL HEAVY Revision Date: 17 Mar 2015 Page 5 of 10 For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Physical State: Liquid Color: Amber Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 0.879 Flammability (Solid, Gas): N/A Flash Point [Method]: >215°C (419°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) Decomposition Temperature: N/D Vapor Density (Air = > 2 at 101 kPa Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C Evaporation Rate (n-butyl acetate = N/D Page 214 of 328 Page 214 of 328 Page 214 of 328 Page 214 of 328 ---PAGE BREAK--- Product Name: MOBIL DTE OIL HEAVY Revision Date: 17 Mar 2015 Page 6 of 10 pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 98.5 cSt (98.5 mm2/sec) at 40 °C I 9.9 cSt (9.9 mm2/sec) at 100°C Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -18°C (0°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt SECTION 10 STABILITY AND REACTIVITY REACTIVITY: See sub-sections below. STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS Hazard Class Conclusion / Remarks Inhalation Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Ingestion Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Corrosion/Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on assessment of the components. Eye Serious Eye Damage/Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components. Sensitization Respiratory Sensitization: No end point data for material. Not expected to be a respiratory sensitizer. Skin Sensitization: No end point data for material. Not expected to be a skin sensitizer. Based on assessment of the components. Aspiration: Data available. Not expected to be an aspiration hazard. Based on Page 215 of 328 Page 215 of 328 Page 215 of 328 Page 215 of 328 ---PAGE BREAK--- Product Name: MOBIL DTE OIL HEAVY Revision Date: 17 Mar 2015 Page 7 of 10 physico-chemical properties of the material. Germ Cell Mutagenicity: No end point data for material. Not expected to be a germ cell mutagen. Based on assessment of the components. Carcinogenicity: No end point data for material. Not expected to cause cancer. Based on assessment of the components. Reproductive Toxicity: No end point data for material. Not expected to be a reproductive toxicant. Based on assessment of the components. Lactation: No end point data for material. Not expected to cause harm to breast-fed children. Specific Target Organ Toxicity (STOT) Single Exposure: No end point data for material. Not expected to cause organ damage from a single exposure. Repeated Exposure: No end point data for material. Not expected to cause organ damage from prolonged or repeated exposure. Based on assessment of the components. OTHER INFORMATION Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Not expected to be harmful to aquatic organisms. MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. Page 216 of 328 Page 216 of 328 Page 216 of 328 Page 216 of 328 ---PAGE BREAK--- Product Name: MOBIL DTE OIL HEAVY Revision Date: 17 Mar 2015 Page 8 of 10 SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. Protect the environment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents, brake fluids or coolants. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (DOT): Not Regulated for Land Transport LAND (TDG): Not Regulated for Land Transport SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code Marine Pollutant: No AIR (IATA): Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION Page 217 of 328 Page 217 of 328 Page 217 of 328 Page 217 of 328 ---PAGE BREAK--- Product Name: MOBIL DTE OIL HEAVY Revision Date: 17 Mar 2015 Page 9 of 10 OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with OSHA HazCom 2012, 29 CFR 1910.1200. Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, IECSC, PICCS, TSCA EPCRA SECTION 302: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. The following ingredients are cited on the lists below: Chemical Name CAS Number List Citations PHOSPHORODITHOIC ACID, O,O-DI C1-14-ALKYL ESTERS, ZINC SALTS (2:1) (ZDDP) 68649-42-3 15 ZINC DITHIOPHOSPHATE 68649-42-3 15 --REGULATORY LISTS SEARCHED-- 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK 5 = TSCA 4 10 = CA P65 CARC 15 = MI 293 Code key: CARC=Carcinogen; REPRO=Reproductive SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only): H315: Causes skin irritation; Skin Corr/Irritation, Cat 2 H319(2A): Causes serious eye irritation; Serious Eye Damage/Irr, Cat 2A H400: Very toxic to aquatic life; Acute Env Tox, Cat 1 H410: Very toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 1 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Updates made in accordance with implementation of GHS requirements. Page 218 of 328 Page 218 of 328 Page 218 of 328 Page 218 of 328 ---PAGE BREAK--- Product Name: MOBIL DTE OIL HEAVY Revision Date: 17 Mar 2015 Page 10 of 10 The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A DGN: 2007096XUS (1013599) Copyright 2002 Exxon Mobil Corporation, All rights reserved Page 219 of 328 Page 219 of 328 Page 219 of 328 Page 219 of 328 ---PAGE BREAK--- N262.0200 Page 1 of 2 5332 Dansher Road Illinois 60525 MATERIAL SAFETY DATA SHEET Revision Date: 2-01-00 MSDS No. N262 Emergency Phones: [PHONE REDACTED] (NYCO) [PHONE REDACTED] (CHEMTREC) PLEASE NOTE: This MSDS is being provided to your company for the purpose of providing current health and safety information to your management and for your employees who work with this material. Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT-TO-KNOW regulations. Also make this information available to any employee who requests it. It is your obligation to comply with these regulations. SECTION I - PRODUCT IDENTITY PRODUCT NAME: Hi Cling Disinfectant Bowl Cleaner Formula: Mixture, water, hydrochloric acid, detergents and additives Chemical Type: as above EPA No.: 47371-86-8370 HMIS RATINGS Health = 3 (Serious) Flammability = 0 (Insignificant) Reactivity = 0 (Minimal) Protection = C (Safety Glasses, Gloves, Apron) SECTION II - HAZARDOUS INGREDIENTS CARCINOGEN PERCENT TLV STEL (OSHA,TP,IARC) Hydrochloric Acid <10% 5ppm none 7647-01-0 ceiling SECTION III - CHEMICAL AND PHYSICAL Appearance: Aqua-Blue Boiling Point: 210ºF Odor: mint Melting Point: N/A pH: <1.0 Spec. Gravity (H20 = 1.04 Water Solubility: Complete Vapor Pressure (mm Hg): N/A Viscosity, Cp. @ 25°C: A-5 (Gardner) VOC Content: none SECTION IV - FIRE AND EXPLOSION HAZARDS Flash Point (Method): none Explosion Limits: Upper: N/A Lower: N/A Extinguishing Media: N/A (product is non-flammable) Special Firefighting Procedures and Hazards: Avoid skin and eye contact, and breathing of acid vapors. Wear head and body protection and HCl respirator if exposure to liquid is likely. SECTION V - REACTIVITY INFORMATION Stable: Unstable: Precautions: Incompatibility: Strong alkalies, materials not resistant to strong acids, active metals (zinc, aluminum, magnesium, etc.). Hazardous Decomposition Products: Hydrogen chloride vapors. Contact with active metals can release flammable gas Hazardous Polymerization: Occurs: Does Not Occur: Page 220 of 328 Page 220 of 328 Page 220 of 328 Page 220 of 328 ---PAGE BREAK--- N262.0200 Page 2 of 2 SECTION VI - HEALTH HAZARDS - PROTECTIVE MEASURES - FIRST AID Inhalation: Breathing of vapor can cause respiratory irritation and inflammation. Skin: Corrosive. Causes irritation and burns. Wear acid-resistant protective gloves, boots, and clothing. Provide convenient safety showers. Remove contaminated clothing. Flush skin thoroughly with water for 15 minutes. Get medical attention if burns persist. Eyes: Corrosive. Causes eye damage. Wear splash proof goggles. Provide convenient eyewash stations. Flush immediately with water for 15 minutes. Get prompt medical attention. Ingestion: Corrosive. Causes irritation and burning in mouth and throat. Wear face shield (or respirator). Avoid swallowing. Drink lots of water or, preferably, milk. Get medical attention if effects persist. Do not induce vomiting. Most likely routes of entry: Skin, Eyes, Inhalation Other Important Medical or Precautionary Information: None SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE Spills and Leaks: Small spills can be flushed into normal drainage or into ground with copious amounts of water, or taken up with absorbent material. Larger spills should be contained by diking or other methods and held for collection and/or reuse, or for neutralization with alkali before collection and disposal. Personnel should use eye and skin protection. Storage and Handling: Check daily for any leaks from containers, vessels, pumps, and piping. Have water hoses and alkali (caustic soda, lime, etc.) convenient. Only use containers and equipment designed for acid service. Use a respirator if area is poorly ventilated. Waste Disposal: If neutralized, may be disposable in sewers if local regulations permit. Otherwise, send to licensed treatment and disposal facility. As supplied, this product is a RCRA hazardous waste. Empty Containers: Rinse well before handling and disposal. Other Precautions: SECTION VIII - REGULATORY INFORMATION Reportable for SARA Title III, S.313 (Form Hydrochloric acid The information herein has been compiled from sources believed to be reliable and is accurate to the best of our knowledge. However, NYCO Products Company cannot give any guarantees regarding information from other sources, and expressly does not make any warranties, nor assumes any liability, for its use. Page 221 of 328 Page 221 of 328 Page 221 of 328 Page 221 of 328 ---PAGE BREAK--- N748.0200 Page 1 of 2 5332 Dansher Road Illinois 60525 MATERIAL SAFETY DATA SHEET Revision Date: 2/5/2011 MSDS No. N748 Supersedes Date: 8/10/2005 Emergency Phones: [PHONE REDACTED] (NYCO) [PHONE REDACTED] (CHEMTREC) PLEASE NOTE: This MSDS is being provided to your company for the purpose of providing current health and safety information to your management and for your employees who work with this material. Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT-TO-KNOW regulations. Also make this information available to any employee who requests it. It is your obligation to comply with these regulations. SECTION I - PRODUCT IDENTITY PRODUCT NAME: PEACHES N' CLEAN ODOR COUNTERACTANT Formula: Mixture, natural fruity oils, additives, water Chemical Type: Organic compound in water HMIS RATINGS Health = 0 (Minimal) Flammability = 0 (Minimal) Reactivity = 0 (Minimal) Protection = A (Safety Glasses) SECTION II - HAZARDOUS INGREDIENTS CARCINOGEN PERCENT TLV (OSHA,TP,IARC) None SECTION III - CHEMICAL AND PHYSICAL Appearance: Clear Orange/Peach Color Boiling Point: 210 Odor: Peach Melting Point: N/A pH: 6.5-7.5 Spec. Gravity (H20 = 0.99 Water Solubility: Complete Vapor Pressure (mm Hg): N/A Viscosity @ 25oC: < 25 cps (Brookfield) VOC Content: 0% SECTION IV - FIRE AND EXPLOSION HAZARDS Flash Point (Method): Est. >200 Explosion Limits: Upper: N/A Lower: N/A Extinguishing Media: Water fog, carbon dioxide, halon system, foam Special Firefighting Procedures and Hazards: Minimize prolonged skin and eye contact. Wear eye protection if exposure is likely. SECTION V - REACTIVITY INFORMATION Stable: Unstable: Precautions: Incompatibility: None known Hazardous Decomposition Products: If in a fire: carbon oxides, hydrocarbons. Hazardous Polymerization: Occurs: Does Not Occur: Page 222 of 328 Page 222 of 328 Page 222 of 328 Page 222 of 328 ---PAGE BREAK--- N-748 Page 2 SECTION VI - HEALTH HAZARDS - PROTECTIVE MEASURES - FIRST AID Inhalation: Breathing of mists may cause irritation. Remove to fresh air. Give artificial respiration or oxygen if needed. Skin: Extended contact may cause irritation. Wash skin with soap and plenty of water. Remove contaminated clothing and wash before wearing again. Eyes: May cause irritation from misting. Flush with water for 15 minutes. If irritation persists consult a doctor. Ingestion: Harmful if swallowed. Drink milk or water and contact medical help if needed. Most likely routes of entry: Skin, Eyes. Other Important Medical or Precautionary Information: None SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE Spills and Leaks: Small spills can be flushed into normal drainage or into ground with copious amounts of water, or taken up with absorbent material. Do not drain to sewer without dilution. Larger spills should be contained by diking or other methods and held for disposal or reuse. Storage and Handling: Check daily for any leaks from containers, vessels, pumps, and piping. Do not heat above 165oF. Keep away from heat and ignition sources. Waste Disposal: May be disposable in sewers if diluted and if local regulations permit. Otherwise, send to licensed treatment and disposal center. Empty Containers: Rinse well before handling and disposal. Observe label precautions. Other Precautions: N/A SECTION VIII - REGULATORY INFORMATION Reportable for SARA Title III, S.313 (Form None The information herein has been compiled from sources believed to be reliable and is accurate to the best of our knowledge. However, NYCO Products Company cannot give any guarantees regarding information from other sources, and expressly does not make any warranties, nor assumes any liability, for its use. Page 223 of 328 Page 223 of 328 Page 223 of 328 Page 223 of 328 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Advanced Instant Hand Sanitizer Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36762-00002 Date of last issue: 12/12/2014 Date of first issue: 12/12/2014 1 / 15 SECTION 1. IDENTIFICATION Product name : PURELL® Advanced Instant Hand Sanitizer Manufacturer or supplier's details Company name of supplier : GOJO Industries, Inc. Address : One GOJO Plaza, Suite 500 Akron OH 44311 Telephone : 1 (330) 255-6000 Emergency telephone : 1-[PHONE REDACTED] CHEMTREC Recommended use of the chemical and restrictions on use Recommended use : Hand Sanitizer Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 3 Eye irritation : Category 2A GHS Label element Hazard pictograms : Signal Word : Warning Hazard Statements : H226 Flammable liquid and vapor. H319 Causes serious eye irritation. Page 224 of 328 Page 224 of 328 Page 224 of 328 Page 224 of 328 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Advanced Instant Hand Sanitizer Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36762-00002 Date of last issue: 12/12/2014 Date of first issue: 12/12/2014 2 / 15 Precautionary Statements : Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P233 Keep container closed. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ eye protection/ face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards Vapors may form explosive mixture with air. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous ingredients Chemical Name CAS-No. Concentration Ethanol 64-17-5 50 - < 70 Propan-2-ol 67-63-0 1 - < 5 SECTION 4. FIRST AID MEASURES General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When persist or in all cases of doubt seek medical advice. If inhaled : If inhaled, remove to fresh air. Get medical attention if occur. In case of skin contact : Wash with water and soap as a precaution. Get medical attention if occur. In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Page 225 of 328 Page 225 of 328 Page 225 of 328 Page 225 of 328 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Advanced Instant Hand Sanitizer Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36762-00002 Date of last issue: 12/12/2014 Date of first issue: 12/12/2014 3 / 15 Get medical attention. If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if occur. Rinse mouth thoroughly with water. Most important and effects, both acute and delayed : Causes serious eye irritation. Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists. Notes to physician : Treat and supportively. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2) Unsuitable extinguishing media : High volume water jet Specific hazards during fire fighting : Do not use a solid water stream as it may scatter and spread fire. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. Exposure to combustion products may be a hazard to health. Hazardous combustion prod- ucts : Carbon oxides Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area. Special protective equipment for fire-fighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Remove all sources of ignition. Use personal protective equipment. Follow safe handling advice and personal protective equipment recommendations. Environmental precautions : Discharge into the environment must be avoided. Page 226 of 328 Page 226 of 328 Page 226 of 328 Page 226 of 328 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Advanced Instant Hand Sanitizer Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36762-00002 Date of last issue: 12/12/2014 Date of first issue: 12/12/2014 4 / 15 Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for containment and cleaning up : Non-sparking tools should be used. Soak up with inert absorbent material. Suppress (knock down) gases/vapors/mists with a water spray jet. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements. SECTION 7. HANDLING AND STORAGE Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Local/Total ventilation : Use with local exhaust ventilation. Use only in an area equipped with explosion proof exhaust ventilation. Advice on safe handling : Do not breathe vapors or spray mist. Do not swallow. Do not get in eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice. Non-sparking tools should be used. Keep container closed. Keep away from heat and sources of ignition. Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment. Conditions for safe storage : Keep in properly labeled containers. Keep closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition. Materials to avoid : Do not store with the following product types: Strong oxidizing agents Page 227 of 328 Page 227 of 328 Page 227 of 328 Page 227 of 328 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Advanced Instant Hand Sanitizer Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36762-00002 Date of last issue: 12/12/2014 Date of first issue: 12/12/2014 5 / 15 Organic peroxides Flammable solids Pyrophoric liquids Pyrophoric solids Self-heating substances and mixtures Substances and mixtures which in contact with water emit flammable gases Explosives Gases SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Ethanol 64-17-5 TWA 1,000 ppm 1,900 mg/m3 NIOSH REL TWA 1,000 ppm 1,900 mg/m3 OSHA Z-1 STEL 1,000 ppm ACGIH Propan-2-ol 67-63-0 TWA 200 ppm ACGIH STEL 400 ppm ACGIH TWA 400 ppm 980 mg/m3 NIOSH REL ST 500 ppm 1,225 mg/m3 NIOSH REL TWA 400 ppm 980 mg/m3 OSHA Z-1 Biological occupational exposure limits Ingredients CAS-No. Control parameters Biological specimen Sam- pling time Permissible concentratio n Basis Propan-2-ol 67-63-0 Acetone Urine End of shift at end of work- week 40 mg/l ACGIH BEI Engineering measures : Minimize workplace exposure concentrations. Use only in an area equipped with explosion proof exhaust ventilation. Use with local exhaust ventilation. Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and Page 228 of 328 Page 228 of 328 Page 228 of 328 Page 228 of 328 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Advanced Instant Hand Sanitizer Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36762-00002 Date of last issue: 12/12/2014 Date of first issue: 12/12/2014 6 / 15 use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. Hand protection Material : Impervious gloves Material : Flame retardant gloves Remarks : Choose gloves to protect hands against chemicals depending on the concentration specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. Eye protection : Wear the following personal protective equipment: Safety goggles Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Wear the following personal protective equipment: Flame retardant antistatic protective clothing. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc). Hygiene measures : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : gel Color : clear, light blue Odor : fruity Odor Threshold : No data available pH : 6.5 - 8.5 Melting point/freezing point : No data available Initial boiling point and boiling range : 73 °C Page 229 of 328 Page 229 of 328 Page 229 of 328 Page 229 of 328 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Advanced Instant Hand Sanitizer Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36762-00002 Date of last issue: 12/12/2014 Date of first issue: 12/12/2014 7 / 15 Flash point : 25 °C Evaporation rate : No data available Flammability (solid, gas) : Not applicable Upper explosion limit : No data available Lower explosion limit : No data available Vapor pressure : No data available Relative vapor density : No data available Density : 0.881 g/cm3 Solubility(ies) Water solubility : soluble Partition coefficient: n- octanol/water : Not applicable Autoignition temperature : No data available Decomposition temperature : The substance or mixture is not classified self-reactive. Viscosity Viscosity, kinematic : 1,000 - 17,000 mm2/s (20 Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reac- tions : Flammable liquid and vapor. Vapors may form explosive mixture with air. Can react with strong oxidizing agents. Conditions to avoid : Heat, flames and sparks. Incompatible materials : Oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. Page 230 of 328 Page 230 of 328 Page 230 of 328 Page 230 of 328 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Advanced Instant Hand Sanitizer Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36762-00002 Date of last issue: 12/12/2014 Date of first issue: 12/12/2014 8 / 15 SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Ingredients: Ethanol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): 124.7 mg/l Exposure time: 4 h Test atmosphere: vapor Propan-2-ol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): 72.6 mg/l Exposure time: 4 h Test atmosphere: vapor Acute dermal toxicity : LD50 (Rat): > 5,000 mg/kg Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation Ingredients: Ethanol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Propan-2-ol: Species: Rabbit Result: No skin irritation Serious eye damage/eye irritation Causes serious eye irritation. Ingredients: Page 231 of 328 Page 231 of 328 Page 231 of 328 Page 231 of 328 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Advanced Instant Hand Sanitizer Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36762-00002 Date of last issue: 12/12/2014 Date of first issue: 12/12/2014 9 / 15 Ethanol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Method: OECD Test Guideline 405 Propan-2-ol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Respiratory or skin sensitization Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information. Product: Assessment: Does not cause skin sensitization. Ingredients: Ethanol: Test Type: Local node assay (LLNA) Routes of exposure: Skin contact Species: Mouse Result: negative Propan-2-ol: Test Type: Buehler Test Routes of exposure: Skin contact Species: Guinea pig Method: OECD Test Guideline 406 Result: negative Germ cell mutagenicity Not classified based on available information. Ingredients: Ethanol: Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Result: negative Genotoxicity in vivo : Test Type: Rodent dominant lethal test (germ cell) (in vivo) Species: Mouse Application Route: Ingestion Result: negative Propan-2-ol: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Genotoxicity in vivo : Test Type: Mammalian micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Intraperitoneal injection Result: negative Page 232 of 328 Page 232 of 328 Page 232 of 328 Page 232 of 328 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Advanced Instant Hand Sanitizer Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36762-00002 Date of last issue: 12/12/2014 Date of first issue: 12/12/2014 10 / 15 Carcinogenicity Not classified based on available information. Ingredients: Propan-2-ol: Species: Rat Application Route: inhalation (vapor) Exposure time: 104 weeks Method: OECD Test Guideline 451 Result: negative IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. Ingredients: Ethanol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion Method: OECD Test Guideline 416 Result: negative Propan-2-ol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative Effects on fetal development : Test Type: Embryo-fetal development Species: Rat Application Route: Ingestion Result: negative STOT-single exposure Not classified based on available information. Ingredients: Propan-2-ol: Assessment: May cause drowsiness or dizziness. Page 233 of 328 Page 233 of 328 Page 233 of 328 Page 233 of 328 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Advanced Instant Hand Sanitizer Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36762-00002 Date of last issue: 12/12/2014 Date of first issue: 12/12/2014 11 / 15 STOT-repeated exposure Not classified based on available information. Repeated dose toxicity Ingredients: Ethanol: Species: Rat NOAEL: 2,400 mg/kg Application Route: Ingestion Exposure time: 2 y Propan-2-ol: Species: Rat NOAEL: 5000 ppm Application Route: inhalation (vapor) Exposure time: 104 w Method: OECD Test Guideline 413 Aspiration toxicity Not classified based on available information. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Ingredients: Ethanol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 1,000 mg/l Exposure time: 48 h Toxicity to algae : EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 9.6 mg/l Exposure time: 9 d Toxicity to bacteria : EC50 (Photobacterium phosphoreum): 32.1 mg/l Exposure time: 0.25 h Propan-2-ol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 10,000 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 10,000 mg/l Exposure time: 24 h Toxicity to algae : ErC50 (Scenedesmus quadricauda (Green algae)): > 1,800 mg/l Page 234 of 328 Page 234 of 328 Page 234 of 328 Page 234 of 328 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Advanced Instant Hand Sanitizer Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36762-00002 Date of last issue: 12/12/2014 Date of first issue: 12/12/2014 12 / 15 Exposure time: 8 d Toxicity to bacteria : EC50 (Pseudomonas putida): > 1,050 mg/l Exposure time: 16 h Persistence and degradability Ingredients: Ethanol: Biodegradability : Result: Readily biodegradable. Biodegradation: 84 % Exposure time: 20 d Propan-2-ol: Biodegradability : Result: rapidly degradable Bioaccumulative potential Ingredients: Ethanol: Partition coefficient: n- octanol/water : log Pow: -0.35 Propan-2-ol: Partition coefficient: n- octanol/water : log Pow: 0.05 Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION International Regulation UN number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S. Page 235 of 328 Page 235 of 328 Page 235 of 328 Page 235 of 328 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Advanced Instant Hand Sanitizer Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36762-00002 Date of last issue: 12/12/2014 Date of first issue: 12/12/2014 13 / 15 (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : 3 IATA-DGR UN/ID No. : UN 1987 Proper shipping name : Alcohols, n.o.s. (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : Flammable Liquids Packing instruction (cargo aircraft) : 366 Packing instruction (passenger aircraft) : 355 IMDG-Code UN number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S. (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : 3 EmS Code : F-E, S-D Marine pollutant : no Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. Domestic regulation 49 CFR UN/ID/NA number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S. Class : 3 Packing group : III Labels : FLAMMABLE LIQUID ERG Code : 127 Marine pollutant : no SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Fire Hazard Page 236 of 328 Page 236 of 328 Page 236 of 328 Page 236 of 328 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Advanced Instant Hand Sanitizer Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36762-00002 Date of last issue: 12/12/2014 Date of first issue: 12/12/2014 14 / 15 Acute Health Hazard SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : The following components are subject to reporting levels established by SARA Title III, Section 313: Propan-2-ol 67-63-0 3.4086 % US State Regulations Right To Know Ethanol 64-17-5 50 - 70 % Water 7732-18-5 30 - 50 % Propan-2-ol 67-63-0 1 - 5 % New Jersey Right To Know Ethanol 64-17-5 50 - 70 % Water 7732-18-5 30 - 50 % Propan-2-ol 67-63-0 1 - 5 % California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: REACH : All ingredients (pre-)registered or exempt. TSCA : All chemical substances in this material are included on or exempted from listing on the TSCA Inventory of Chemical Substances. DSL : All chemical substances in this product comply with the CEPA 1999 and NSNR and are on or exempt from listing on the Canadian Domestic Substances List (DSL). AICS : All ingredients listed or exempt. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), NECSI (Taiwan), TSCA (USA) Page 237 of 328 Page 237 of 328 Page 237 of 328 Page 237 of 328 ---PAGE BREAK--- SAFETY DATA SHEET PURELL® Advanced Instant Hand Sanitizer Version 1.1 Revision Date: 02/10/2015 MSDS Number: 36762-00002 Date of last issue: 12/12/2014 Date of first issue: 12/12/2014 15 / 15 SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) ACGIH BEI : ACGIH - Biological Exposure Indices (BEI) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants ACGIH / TWA : 8-hour, time-weighted average ACGIH / STEL : Short-term exposure limit NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek NIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceeded at any time during a workday OSHA Z-1 / TWA : 8-hour time weighted average Sources of key data used to compile the Material Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen- cy, http://echa.europa.eu/ Revision Date : 02/10/2015 The information provided in this Safety Data Sheet is correct to the best of our knowledge, in- formation and belief at the date of its publication. The information is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information pro- vided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, un- less specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, in- cluding an assessment of the appropriateness of the SDS material in the user’s end product, if applicable. US / Z8 Flammability Health Instability 2 3 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 3 0 2 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 238 of 328 Page 238 of 328 Page 238 of 328 Page 238 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026010 1/14 1. PRODUCT AND COMPANY IDENTIFICATION Product information Product name : RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®) Recommended use : Insecticide Manufacturer, importer, supplier : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236 Telephone : +18005585252 Emergency telephone number : 24 Hour Medical Emergency Phone: (866)231-5406 24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300 2. HAZARDS IDENTIFICATION Classification of the substance or mixture Globally Harmonized System (GHS) Classification Hazard classification Hazard category Hazards identification Aerosol Category 2 Gases under pressure Liquefied gas Contains gas under pressure; may explode if heated. Labelling Hazard symbols Flame Gas cylinder Signal word Warning Hazard statements Flammable aerosol. Contains gas under pressure; may explode if heated. Precautionary statements Protect from sunlight. Do not expose to temperatures exceeding 50 122 Protect from sunlight. Store in a well-ventilated place. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Page 239 of 328 Page 239 of 328 Page 239 of 328 Page 239 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026010 2/14 Other hazards : None identified 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No. Weight percent Alkanes, C14-16 90622-46-1 10.00 - 30.00 Propane 74-98-6 5.00 - 10.00 Butane 106-97-8 1.00 - 5.00 Isobutane 75-28-5 1.00 - 5.00 Isopropanol 67-63-0 1.00 - 5.00 Cypermethrin 52315-07-8 0.10 - 1.00 Imiprothrin 72963-72-5 0.0001 - 0.10 The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Eye contact : No special requirements Skin contact : No special requirements Inhalation : No special requirements. Ingestion : No special requirements 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during firefighting : Aerosol Product - Containers may rocket or explode in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses. Further information : Fight fire from maximum distance or protected area. Although Page 240 of 328 Page 240 of 328 Page 240 of 328 Page 240 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026010 3/14 this product has a flash point below 200 Deg F, it is an aqueous solution containing an alcohol and does not sustain combustion. Cool and use caution when approaching or handling fire-exposed containers. Fight fire with normal precautions from a reasonable distance. Standard procedure for chemical fires. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Remove all sources of ignition. Wear personal protective equipment. Wash thoroughly after handling. Environmental precautions : Do not flush into surface water or sanitary sewer system. Use appropriate containment to avoid environmental contamination. Outside of normal use, avoid release to the environment. Methods and materials for containment and cleaning up : If damage occurs to aerosol can: Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Dike large spills. Clean residue from spill site. 7. HANDLING AND STORAGE Handling Precautions for safe handling : Avoid contact with skin, eyes and clothing. Do not enter places where used or stored until adequately ventilated. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Pressurized container. Do not pierce or burn, even after use. Page 241 of 328 Page 241 of 328 Page 241 of 328 Page 241 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026010 4/14 Advice on protection against fire and explosion : Keep away from sources of ignition - No smoking. Do not spray on an open flame or other ignition source. Storage Requirements for storage areas and containers : Protect from sunlight. Do not expose to temperatures exceeding 50 122 Keep away from food, drink and animal feedingstuffs. Keep in a dry, cool and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Non- standard units Basis Propane 74-98-6 - 1,000 ppm - ACGIH TWA Propane 74-98-6 1,800 mg/m3 1,000 ppm - OSHA TWA Butane 106-97-8 - 1,000 ppm - ACGIH STEL Isobutane 75-28-5 - 1,000 ppm - ACGIH STEL Isopropanol 67-63-0 980 mg/m3 400 ppm - OSHA TWA Isopropanol 67-63-0 - 400 ppm - ACGIH STEL Isopropanol 67-63-0 - 200 ppm - ACGIH TWA Personal protective equipment Respiratory protection : Do not spray in enclosed areas. Hand protection : No special requirements. Eye protection : No special requirements. Page 242 of 328 Page 242 of 328 Page 242 of 328 Page 242 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026010 5/14 Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : aerosol Form : Compressed gas Color : clear Odor : floral Odour Threshold : Test not applicable for this product type pH : Test not applicable for this product type Melting point/freezing point : Test not applicable for this product type Initial boiling point and boiling range : Test not applicable for this product type Flash point : < 0 °C < 32 °F Propellant 18 °C 64.4 °F liquid Evaporation rate : Test not applicable for this product type Flammability (solid, gas) : Does not sustain combustion. Upper/lower flammability or explosive limits : Test not applicable for this product type Page 243 of 328 Page 243 of 328 Page 243 of 328 Page 243 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026010 6/14 Vapour pressure : Test not applicable for this product type Vapour density : Test not applicable for this product type Relative density : 0.877 g/cm3 at 70 °FCalculated Solubility(ies) : partly soluble Partition coefficient: n- octanol/water : Test not applicable for this product type Auto-ignition temperature : does not ignite Decomposition temperature : Test not applicable for this product type Viscosity, dynamic : Test not applicable for this product type Viscosity, kinematic : Test not applicable for this product type Oxidizing properties : Test not applicable for this product type Volatile Organic Compounds Total VOC (wt. : 12.1 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations Other information : None identified : 10. STABILITY AND REACTIVITY Possibility of hazardous reactions : Stable under recommended storage conditions. Page 244 of 328 Page 244 of 328 Page 244 of 328 Page 244 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026010 7/14 Possibility of hazardous reactions : Stable under recommended storage conditions. Conditions to avoid : Heat, flames and sparks. Incompatible materials : Strong oxidizing agents Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. 11. TOXICOLOGICAL INFORMATION Emergency Overview : Warning Acute oral toxicity : NA GHS LD50 estimated > 5,000 mg/kg see user defined free text Acute inhalation toxicity : NA GHS LC50 (dust and mist) estimated > 5.1 mg/l see user defined free text Acute dermal toxicity : NA GHS LD50 estimated > 5,000 mg/kg GHS Properties Classification Routes of entry Acute toxicity No classification proposed - Skin corrosion/irritation No classification proposed - Serious eye damage/eye irritation No classification proposed - Skin sensitisation No classification proposed - Respiratory sensitisation No classification proposed - Germ cell mutagenicity No classification proposed - Page 245 of 328 Page 245 of 328 Page 245 of 328 Page 245 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026010 8/14 Carcinogenicity No classification proposed - Reproductive toxicity No classification proposed - Specific target organ toxicity - single exposure No classification proposed - Specific target organ toxicity - repeated exposure No classification proposed - Aspiration hazard No classification proposed - Aggravated Medical Condition : None known. 12. ECOLOGICAL INFORMATION Product : The product itself has not been tested. Toxicity The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions. Toxicity to fish Alkanes, C14-16 No data available Propane LC50 Fish 27.98 mg/l 96 h Butane No data available Isobutane LC50 Fish 27.98 mg/l 96 h Isopropanol LC50 Pimephales promelas (fathead minnow) 9,640 mg/l 96 h Components End point Species Value Exposure time Page 246 of 328 Page 246 of 328 Page 246 of 328 Page 246 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026010 9/14 Cypermethrin LC50 mykiss (rainbow trout) 0.00283 mg/l 96 h NOEC Pimephales promelas (fathead minnow) 0.00001 mg/l 28 d Imiprothrin LC50 mykiss (rainbow trout) 0.038 mg/l 96 h Toxicity to aquatic invertebrates Alkanes, C14-16 No data available Propane LC50 Daphnid 14.22 mg/l 48 h Butane No data available Isobutane LC50 Daphnid 16.33 mg/l 48 h Isopropanol EC50 Daphnia magna (Water flea) 13,299 mg/l 48 h Cypermethrin EC50 Daphnia magna (Water flea) 0.00471 mg/l 48 h Components End point Species Value Exposure time Page 247 of 328 Page 247 of 328 Page 247 of 328 Page 247 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026010 10/14 NOEC Daphnia magna (Water flea) 0.00004 mg/l 21 d Imiprothrin EC50 Daphnia magna (Water flea) 0.051 mg/l 48 h Toxicity to aquatic plants Alkanes, C14-16 No data available Propane No data available Butane No data available Isobutane EC50 Green algea 8.57 mg/l 96 h Isopropanol EC50 Desmodesmus subspicatus (green algae) > 1,000 mg/l 72 h Cypermethrin ErC50 No data available > 0.0033 mg/l 72 h Imiprothrin NOEC Pseudokirchneriella subcapitata (green algae) 1.3 mg/l 72 h Persistence and degradability Component Biodegradation Exposure time Summary Alkanes, C14-16 82 % 28 d Readily biodegradable Propane 70 % < 10 d Readily biodegradable Butane 100 % 385.5 h Readily biodegradable Isobutane 70 % < 10 d Readily biodegradable Isopropanol 53 % 5 d Readily biodegradable Components End point Species Value Exposure time Page 248 of 328 Page 248 of 328 Page 248 of 328 Page 248 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026010 11/14 Cypermethrin 0.6 - 1.4 % 33 d Not readily biodegradable. Imiprothrin 58 % 28 d Not readily biodegradable. Bioaccumulative potential Component Bioconcentration factor (BCF) Partition Coefficient n- Octanol/water (log) Alkanes, C14-16 No data available No data available Propane No data available 2.36 Butane No data available 2.89 Isobutane 1.57 - 1.97 2.8 Isopropanol 0.96 estimated 0.05 Cypermethrin 373.4 Measured 5.3 - 5.6 Imiprothrin 58.2 Calculated 2.9 Mobility Component End point Value Alkanes, C14-16 No data available Propane No data available Butane No data available Isobutane No data available Isopropanol No data available Cypermethrin Koc 80653 - 574360 Imiprothrin Koc 268 PBT and vPvB assessment Component Results Alkanes, C14-16 Not fulfilling PBT and vPvB criteria Propane Not fulfilling PBT and vPvB criteria Butane Not fulfilling PBT and vPvB criteria Page 249 of 328 Page 249 of 328 Page 249 of 328 Page 249 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026010 12/14 Isobutane Not fulfilling PBT and vPvB criteria Isopropanol Not fulfilling PBT and vPvB criteria Cypermethrin Not fulfilling PBT and vPvB criteria Imiprothrin Not fulfilling PBT and vPvB criteria Other adverse effects : None known. 13. DISPOSAL CONSIDERATIONS PESTICIDAL WASTE: For disposal information, please read and follow Disposal instructions on the pesticide label. Consumer may discard empty container in trash, or recycle where facilities exist. 14. TRANSPORT INFORMATION Please refer to the Bill of Lading/receiving documents for up-to-date shipping information. Land transport Sea transport Air transport UN number 1950 1950 1950 UN proper shipping name AEROSOLS, Flammable, 2.1 AEROSOLS, Flammable, 2.1 AEROSOLS, Flammable, 2.1 Transport hazard class(es) 2.1 2 2.1 Packing group - - - Environmental hazards - - - Special precautions for user Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. 15. REGULATORY INFORMATION Page 250 of 328 Page 250 of 328 Page 250 of 328 Page 250 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026010 13/14 FIFRA Labeling This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION: Contents under pressure. Exposure to temperatures above 130° F may cause bursting. Flammable. Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Registration # / Agency 4822-596/US/EPA 16. OTHER INFORMATION HMIS Ratings Health 2 Flammability 4 Reactivity 0 Page 251 of 328 Page 251 of 328 Page 251 of 328 Page 251 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026010 14/14 NFPA Ratings Health 2 Fire 4 Reactivity 0 Special - This information is being provided in accordance with the Occupational Safety and Health Administration (OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use. Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 252 of 328 Page 252 of 328 Page 252 of 328 Page 252 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT KILLER 26 (PINE FOREST FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026050 1/14 1. PRODUCT AND COMPANY IDENTIFICATION Product information Product name : RAID® ANT KILLER 26 (PINE FOREST FRESH®) Recommended use : Insecticide Manufacturer, importer, supplier : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236 Telephone : +18005585252 Emergency telephone number : 24 Hour Medical Emergency Phone: (866)231-5406 24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300 2. HAZARDS IDENTIFICATION Classification of the substance or mixture Globally Harmonized System (GHS) Classification Hazard classification Hazard category Hazards identification Aerosol Category 2 Flammable aerosol. Gases under pressure Liquefied gas Contains gas under pressure; may explode if heated. Labelling Hazard symbols Flame Gas cylinder Signal word Warning Hazard statements Flammable aerosol. Contains gas under pressure; may explode if heated. Precautionary statements Protect from sunlight. Do not expose to temperatures exceeding 50 122 Protect from sunlight. Store in a well-ventilated place. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Page 253 of 328 Page 253 of 328 Page 253 of 328 Page 253 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT KILLER 26 (PINE FOREST FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026050 2/14 Other hazards : None identified 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No. Weight percent Alkanes, C14-16 90622-46-1 10.00 - 30.00 Propane 74-98-6 5.00 - 10.00 Butane 106-97-8 1.00 - 5.00 Isobutane 75-28-5 1.00 - 5.00 Isopropanol 67-63-0 1.00 - 5.00 Cypermethrin 52315-07-8 0.10 - 1.00 Imiprothrin 72963-72-5 0.0001 - 0.10 The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Eye contact : No special requirements Skin contact : No special requirements Inhalation : No special requirements. Ingestion : No special requirements 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during firefighting : Aerosol Product - Containers may rocket or explode in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses. Further information : Fight fire from maximum distance or protected area. Although Page 254 of 328 Page 254 of 328 Page 254 of 328 Page 254 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT KILLER 26 (PINE FOREST FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026050 3/14 this product has a flash point below 200 Deg F, it is an aqueous solution containing an alcohol and does not sustain combustion. Cool and use caution when approaching or handling fire-exposed containers. Fight fire with normal precautions from a reasonable distance. Standard procedure for chemical fires. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Remove all sources of ignition. Wear personal protective equipment. Wash thoroughly after handling. Environmental precautions : Do not flush into surface water or sanitary sewer system. Use appropriate containment to avoid environmental contamination. Outside of normal use, avoid release to the environment. Methods and materials for containment and cleaning up : If damage occurs to aerosol can: Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Dike large spills. Clean residue from spill site. 7. HANDLING AND STORAGE Handling Precautions for safe handling : Avoid contact with skin, eyes and clothing. Do not enter places where used or stored until adequately ventilated. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Pressurized container. Do not pierce or burn, even after use. Page 255 of 328 Page 255 of 328 Page 255 of 328 Page 255 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT KILLER 26 (PINE FOREST FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026050 4/14 Advice on protection against fire and explosion : Keep away from sources of ignition - No smoking. Do not spray on an open flame or other ignition source. Storage Requirements for storage areas and containers : Protect from sunlight. Do not expose to temperatures exceeding 50 122 Keep away from food, drink and animal feedingstuffs. Keep in a dry, cool and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Non- standard units Basis Propane 74-98-6 - 1,000 ppm - ACGIH TWA Propane 74-98-6 1,800 mg/m3 1,000 ppm - OSHA TWA Butane 106-97-8 - 1,000 ppm - ACGIH STEL Isobutane 75-28-5 - 1,000 ppm - ACGIH STEL Isopropanol 67-63-0 980 mg/m3 400 ppm - OSHA TWA Isopropanol 67-63-0 - 400 ppm - ACGIH STEL Isopropanol 67-63-0 - 200 ppm - ACGIH TWA Personal protective equipment Respiratory protection : Do not spray in enclosed areas. Hand protection : No special requirements. Eye protection : No special requirements. Page 256 of 328 Page 256 of 328 Page 256 of 328 Page 256 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT KILLER 26 (PINE FOREST FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026050 5/14 Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : aerosol Form : Compressed gas Color : clear Odor : Herbal Odour Threshold : Test not applicable for this product type pH : Test not applicable for this product type Melting point/freezing point : Test not applicable for this product type Initial boiling point and boiling range : Test not applicable for this product type Flash point : < 0 °C < 32 °F Propellant 18 °C 64.4 °F liquid Evaporation rate : Test not applicable for this product type Flammability (solid, gas) : Does not sustain combustion. Upper/lower flammability or explosive limits : Test not applicable for this product type Page 257 of 328 Page 257 of 328 Page 257 of 328 Page 257 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT KILLER 26 (PINE FOREST FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026050 6/14 Vapour pressure : Test not applicable for this product type Vapour density : Test not applicable for this product type Relative density : 0.877 g/cm3 at 70 °FCalculated Solubility(ies) : partly soluble Partition coefficient: n- octanol/water : Test not applicable for this product type Auto-ignition temperature : does not ignite Decomposition temperature : Test not applicable for this product type Viscosity, dynamic : Test not applicable for this product type Viscosity, kinematic : Test not applicable for this product type Oxidizing properties : Test not applicable for this product type Volatile Organic Compounds Total VOC (wt. : 12.2 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations Other information : None identified : 10. STABILITY AND REACTIVITY Possibility of hazardous reactions : Stable under recommended storage conditions. Page 258 of 328 Page 258 of 328 Page 258 of 328 Page 258 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT KILLER 26 (PINE FOREST FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026050 7/14 Possibility of hazardous reactions : Stable under recommended storage conditions. Conditions to avoid : Heat, flames and sparks. Incompatible materials : Strong oxidizing agents Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. 11. TOXICOLOGICAL INFORMATION Emergency Overview : Warning Acute oral toxicity : NA GHS LD50 estimated > 5,000 mg/kg see user defined free text Acute inhalation toxicity : NA GHS LC50 (dust and mist) estimated > 5.1 mg/l see user defined free text Acute dermal toxicity : NA GHS LD50 estimated > 5,000 mg/kg GHS Properties Classification Routes of entry Acute toxicity No classification proposed - Skin corrosion/irritation No classification proposed - Serious eye damage/eye irritation No classification proposed - Skin sensitisation No classification proposed - Respiratory sensitisation No classification proposed - Germ cell mutagenicity No classification proposed - Page 259 of 328 Page 259 of 328 Page 259 of 328 Page 259 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT KILLER 26 (PINE FOREST FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026050 8/14 Carcinogenicity No classification proposed - Reproductive toxicity No classification proposed - Specific target organ toxicity - single exposure No classification proposed - Specific target organ toxicity - repeated exposure No classification proposed - Aspiration hazard No classification proposed - Aggravated Medical Condition : None known. 12. ECOLOGICAL INFORMATION Product : The product itself has not been tested. Toxicity The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions. Toxicity to fish Alkanes, C14-16 No data available Propane LC50 Fish 27.98 mg/l 96 h Butane No data available Isobutane LC50 Fish 27.98 mg/l 96 h Isopropanol LC50 Pimephales promelas (fathead minnow) 9,640 mg/l 96 h Components End point Species Value Exposure time Page 260 of 328 Page 260 of 328 Page 260 of 328 Page 260 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT KILLER 26 (PINE FOREST FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026050 9/14 Cypermethrin LC50 mykiss (rainbow trout) 0.00283 mg/l 96 h NOEC Pimephales promelas (fathead minnow) 0.00001 mg/l 28 d Imiprothrin LC50 mykiss (rainbow trout) 0.038 mg/l 96 h Toxicity to aquatic invertebrates Alkanes, C14-16 No data available Propane LC50 Daphnid 14.22 mg/l 48 h Butane No data available Isobutane LC50 Daphnid 16.33 mg/l 48 h Isopropanol EC50 Daphnia magna (Water flea) 13,299 mg/l 48 h Cypermethrin EC50 Daphnia magna (Water flea) 0.00471 mg/l 48 h Components End point Species Value Exposure time Page 261 of 328 Page 261 of 328 Page 261 of 328 Page 261 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT KILLER 26 (PINE FOREST FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026050 10/14 NOEC Daphnia magna (Water flea) 0.00004 mg/l 21 d Imiprothrin EC50 Daphnia magna (Water flea) 0.051 mg/l 48 h Toxicity to aquatic plants Alkanes, C14-16 No data available Propane No data available Butane No data available Isobutane EC50 Green algea 8.57 mg/l 96 h Isopropanol EC50 Desmodesmus subspicatus (green algae) > 1,000 mg/l 72 h Cypermethrin ErC50 No data available > 0.0033 mg/l 72 h Imiprothrin NOEC Pseudokirchneriella subcapitata (green algae) 1.3 mg/l 72 h Persistence and degradability Component Biodegradation Exposure time Summary Alkanes, C14-16 82 % 28 d Readily biodegradable Propane 70 % < 10 d Readily biodegradable Butane 100 % 385.5 h Readily biodegradable Isobutane 70 % < 10 d Readily biodegradable Isopropanol 53 % 5 d Readily biodegradable Components End point Species Value Exposure time Page 262 of 328 Page 262 of 328 Page 262 of 328 Page 262 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT KILLER 26 (PINE FOREST FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026050 11/14 Cypermethrin 0.6 - 1.4 % 33 d Not readily biodegradable. Imiprothrin 58 % 28 d Not readily biodegradable. Bioaccumulative potential Component Bioconcentration factor (BCF) Partition Coefficient n- Octanol/water (log) Alkanes, C14-16 No data available No data available Propane No data available 2.36 Butane No data available 2.89 Isobutane 1.57 - 1.97 2.8 Isopropanol 0.96 estimated 0.05 Cypermethrin 373.4 Measured 5.3 - 5.6 Imiprothrin 58.2 Calculated 2.9 Mobility Component End point Value Alkanes, C14-16 No data available Propane No data available Butane No data available Isobutane No data available Isopropanol No data available Cypermethrin Koc 80653 - 574360 Imiprothrin Koc 268 PBT and vPvB assessment Component Results Alkanes, C14-16 Not fulfilling PBT and vPvB criteria Propane Not fulfilling PBT and vPvB criteria Butane Not fulfilling PBT and vPvB criteria Page 263 of 328 Page 263 of 328 Page 263 of 328 Page 263 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT KILLER 26 (PINE FOREST FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026050 12/14 Isobutane Not fulfilling PBT and vPvB criteria Isopropanol Not fulfilling PBT and vPvB criteria Cypermethrin Not fulfilling PBT and vPvB criteria Imiprothrin Not fulfilling PBT and vPvB criteria Other adverse effects : None known. 13. DISPOSAL CONSIDERATIONS PESTICIDAL WASTE: For disposal information, please read and follow Disposal instructions on the pesticide label. Consumer may discard empty container in trash, or recycle where facilities exist. 14. TRANSPORT INFORMATION Please refer to the Bill of Lading/receiving documents for up-to-date shipping information. Land transport Sea transport Air transport UN number 1950 1950 1950 UN proper shipping name AEROSOLS, Flammable, 2.1 AEROSOLS, Flammable, 2.1 AEROSOLS, Flammable, 2.1 Transport hazard class(es) 2.1 2 2.1 Packing group - - - Environmental hazards - - - Special precautions for user Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. 15. REGULATORY INFORMATION Page 264 of 328 Page 264 of 328 Page 264 of 328 Page 264 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT KILLER 26 (PINE FOREST FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026050 13/14 FIFRA Labeling This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION: Contents under pressure. Flammable. Exposure to temperatures above 130° F may cause bursting. Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Registration # / Agency 4822-596/US/EPA 16. OTHER INFORMATION HMIS Ratings Health 2 Flammability 4 Reactivity 0 Page 265 of 328 Page 265 of 328 Page 265 of 328 Page 265 of 328 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® ANT KILLER 26 (PINE FOREST FRESH®) Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000026050 14/14 NFPA Ratings Health 2 Fire 4 Reactivity 0 Special - This information is being provided in accordance with the Occupational Safety and Health Administration (OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use. Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 266 of 328 Page 266 of 328 Page 266 of 328 Page 266 of 328 ---PAGE BREAK--- Shell Spirax S6 AXME 75W-90 Version 1.4 Effective Date 2015-01-15 Material Safety Data Sheet According to the Controlled Product Regulations 1/7 Print Date 2015-01-15 000000019770 MSDS_CA 1. MATERIAL AND COMPANY IDENTIFICATION Material Name : Shell Spirax S6 AXME 75W-90 Uses : Transmission fluid Product Code : 001D8290 Manufacturer/Supplier : Shell Canada Products 400 - 4th Avenue S.W Calgary AB T2P 0J4 Canada Telephone : [PHONE REDACTED] Fax : [PHONE REDACTED] Emergency Telephone Number : CHEMTREC (24 hr): [PHONE REDACTED] CANUTEC (24 hr): [PHONE REDACTED] 2. COMPOSITION/INFORMATION ON INGREDIENTS Mixture Description: : Blend of severely hydrotreated slack wax, esters, polyolefins and additives. Highly refined mineral oil. The highly refined mineral oil contains (w/w) DMSO-extract, according to IP346. Refer to Chapter 8 for Occupational Exposure Guidelines. 3. HAZARDS IDENTIFICATION WHMIS Class/Description : THIS PRODUCT IS NOT A WHMIS CONTROLLED SUBSTANCE. Routes of Exposure : Skin and eye contact are the primary routes of exposure although exposure may occur following accidental ingestion. Health Hazards : Not expected to be a health hazard when used under normal conditions. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Used oil may contain harmful impurities. Signs and : Oil acne/folliculitis signs and may include formation of black pustules and spots on the skin of exposed areas. Ingestion may result in nausea, vomiting and/or diarrhoea. Safety Hazards : Not classified as flammable but will burn. Environmental Hazards : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Page 267 of 328 Page 267 of 328 Page 267 of 328 Page 267 of 328 ---PAGE BREAK--- Shell Spirax S6 AXME 75W-90 Version 1.4 Effective Date 2015-01-15 Material Safety Data Sheet According to the Controlled Product Regulations 2/7 Print Date 2015-01-15 000000019770 MSDS_CA 4. FIRST AID MEASURES General Information : Not expected to be a health hazard when used under normal conditions. Inhalation : No treatment necessary under normal conditions of use. If persist, obtain medical advice. Skin Contact : Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention. Eye Contact : Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention. Ingestion : In general no treatment is necessary unless large quantities are swallowed, however, get medical advice. Advice to Physician : Treat 5. FIRE FIGHTING MEASURES Clear fire area of all non-emergency personnel. Flash point : Typical 210 °C / 410 °F (COC) Upper / lower Flammability or Explosion limits : Typical 1 - 10 Auto ignition temperature : > 320 °C / 608 °F Hazardous Combustion Products and Specific Hazards : Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Suitable Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media : Do not use water in a jet. Protective Equipment for Firefighters : Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space. 6. ACCIDENTAL RELEASE MEASURES Protective Measures : Avoid contact with skin and eyes. Use appropriate containment to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately. Prevent from spreading by making a barrier with sand, earth or other containment material. Reclaim liquid directly or in an absorbent. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly. Additional Advice : Local authorities should be advised if significant spillages cannot be contained. Page 268 of 328 Page 268 of 328 Page 268 of 328 Page 268 of 328 ---PAGE BREAK--- Shell Spirax S6 AXME 75W-90 Version 1.4 Effective Date 2015-01-15 Material Safety Data Sheet According to the Controlled Product Regulations 3/7 Print Date 2015-01-15 000000019770 MSDS_CA 7. HANDLING AND STORAGE General Precautions : Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Use the information in this data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling vapour and/or mists. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. Storage : Keep container closed and in a cool, well-ventilated place. Use properly labelled and closeable containers. Store at ambient temperature. Recommended Materials : For containers or container linings, use mild steel or high density polyethylene. Unsuitable Materials : PVC. Additional Information : Polyethylene containers should not be exposed to high temperatures because of possible risk of distortion. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION If the American Conference of Governmental Industrial Hygienists (ACGIH) value is provided on this document, it is provided for information only. Occupational Exposure Limits Material Source Type ppm mg/m3 Notation Oil mist, mineral ACGIH TWA(Inhala ble fraction.) 5 mg/m3 Consult local authorities for acceptable exposure limits within their jurisdiction. Exposure Controls : The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Adequate ventilation to control airborne concentrations. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated. Personal Protective Equipment : Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers. Respiratory Protection : No respiratory protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene Page 269 of 328 Page 269 of 328 Page 269 of 328 Page 269 of 328 ---PAGE BREAK--- Shell Spirax S6 AXME 75W-90 Version 1.4 Effective Date 2015-01-15 Material Safety Data Sheet According to the Controlled Product Regulations 4/7 Print Date 2015-01-15 000000019770 MSDS_CA practices, precautions should be taken to avoid breathing of material. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. Select a filter suitable for combined particulate/organic gases and vapours [boiling point >65°C(149 Hand Protection : Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection: PVC, neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. Eye Protection : Wear safety glasses or full face shield if splashes are likely to occur. Protective Clothing : Skin protection not ordinarily required beyond standard issue work clothes. Monitoring Methods : Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate. Environmental Exposure Controls : Minimise release to the environment. An environmental assessment must be made to ensure compliance with local environmental legislation. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Amber. Liquid at room temperature. Odour : Slight hydrocarbon. Odour threshold : Data not available pH : Not applicable. Initial Boiling Point and Boiling Range : > 280 °C / 536 °F estimated value(s) Pour point : Typical -42 °C / -44 °F Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s)) Specific gravity : Density : Typical 878 kg/m3 at 15 °C / 59 °F Water solubility : Negligible. n-octanol/water partition coefficient (log Pow) : > 6 (based on information on similar products) Page 270 of 328 Page 270 of 328 Page 270 of 328 Page 270 of 328 ---PAGE BREAK--- Shell Spirax S6 AXME 75W-90 Version 1.4 Effective Date 2015-01-15 Material Safety Data Sheet According to the Controlled Product Regulations 5/7 Print Date 2015-01-15 000000019770 MSDS_CA Kinematic viscosity : Typical 115 mm2/s at 40 °C / 104 °F Vapour density (air=1) : > 1 (estimated value(s)) Evaporation rate (nBuAc=1) : Data not available 10. STABILITY AND REACTIVITY Stability : Stable. Conditions to Avoid : Extremes of temperature and direct sunlight. Materials to Avoid : Strong oxidising agents. Hazardous Decomposition Products : Hazardous decomposition products are not expected to form during normal storage. Hazardous Polymerisation : No Sensitivity to Mechanical Impact : No Sensitivity to Static Discharge : No 11. TOXICOLOGICAL INFORMATION Basis for Assessment : Information given is based on data on the components and the toxicology of similar products. Routes of Exposure : Skin and eye contact are the primary routes of exposure although exposure may occur following accidental ingestion. Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat. Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit. Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal conditions of use. Low toxicity by inhalation. Skin Irritation : Expected to be irritating. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Eye Irritation : Expected to be irritating. Respiratory Irritation : Inhalation of vapours or mists may cause irritation. Sensitisation : Not expected to be a skin sensitiser. Repeated Dose Toxicity : Not expected to be a hazard. Mutagenicity : Not considered a mutagenic hazard. Carcinogenicity : Components are not known to be associated with carcinogenic effects. Reproductive and Developmental Toxicity : Not expected to be a hazard. Additional Information : Used oils may contain harmful impurities that have accumulated during use. The concentration of such impurities will depend on use and they may present risks to health and the environment on disposal. ALL used oil should be handled with caution and skin contact avoided as far as possible. Page 271 of 328 Page 271 of 328 Page 271 of 328 Page 271 of 328 ---PAGE BREAK--- Shell Spirax S6 AXME 75W-90 Version 1.4 Effective Date 2015-01-15 Material Safety Data Sheet According to the Controlled Product Regulations 6/7 Print Date 2015-01-15 000000019770 MSDS_CA 12. ECOLOGICAL INFORMATION Ecotoxicological data have not been determined specifically for this product. Information given is based on a knowledge of the components and the ecotoxicology of similar products. Acute Toxicity : Poorly soluble mixture.May cause physical fouling of aquatic organisms.Expected to be harmful:LL/EL/IL50 10-100 mg/l(to aquatic organisms)(LL/EL50 expressed as the nominal amount of product required to prepare aqueous test extract). Mobility : Liquid under most environmental conditions. Floats on water. If it enters soil, it will adsorb to soil particles and will not be mobile. Persistence/degradability : Expected to be not readily biodegradable. Major constituents are expected to be inherently biodegradable, but the product contains components that may persist in the environment. Bioaccumulation : Contains components with the potential to bioaccumulate. Other Adverse Effects : Product is a mixture of non-volatile components, which are not expected to be released to air in any significant quantities. Not expected to have ozone depletion potential, photochemical ozone creation potential or global warming potential. 13. DISPOSAL CONSIDERATIONS Material Disposal : Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations. Do not dispose into the environment, in drains or in water courses. Container Disposal : Dispose in accordance with prevailing regulations, preferably to a recognised collector or contractor. The competence of the collector or contractor should be established beforehand. Local Legislation : Disposal should be in accordance with applicable regional, national, and local laws and regulations. 14. TRANSPORT INFORMATION Canadian Road and Rail Shipping Classification This product is not regulated under the Canadian Transportation of Dangerous Goods Regulations for transport by road and rail. 15. REGULATORY INFORMATION The regulatory information is not intended to be comprehensive. Other regulations may apply to this material. Page 272 of 328 Page 272 of 328 Page 272 of 328 Page 272 of 328 ---PAGE BREAK--- Shell Spirax S6 AXME 75W-90 Version 1.4 Effective Date 2015-01-15 Material Safety Data Sheet According to the Controlled Product Regulations 7/7 Print Date 2015-01-15 000000019770 MSDS_CA This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Class/Description : THIS PRODUCT IS NOT A WHMIS CONTROLLED SUBSTANCE. Inventory Status EINECS : All components listed or polymer exempt. TSCA : All components listed. DSL : All components listed. 16. OTHER INFORMATION MSDS Version Number : 1.4 MSDS Effective Date : 2015-01-15 MSDS Revisions : A vertical bar in the left margin indicates an amendment from the previous version. MSDS Regulation : The content and format of this (M)SDS is in accordance with the Controlled Product Regulations. MSDS Prepared By : Shell Product Stewardship; 1-[PHONE REDACTED] MSDS Distribution : The information in this document should be made available to all who may handle the product. Disclaimer : The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of health, safety and environmental requirements only. No warranty or guarantee is expressed or implied regarding the accuracy of these data or the results to be obtained from the use of the product. Page 273 of 328 Page 273 of 328 Page 273 of 328 Page 273 of 328 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MANUFACTURED FOR: PRIME SOURCE ST. LOUIS, MO. 63141 EMERGENCY TELEPHONE: 1-[PHONE REDACTED] HEALTH SALUD FLAMMABILITY INFLAMABILIDAD REACTIVITY REACTIVIDAD PERSONAL PROTECTION PROTECCIÓN PERSONAL 0-LEAST / MÍNIMO 1-SLIGHT / LIGERO 2-MODERATE / MODERADO 3-HIGH / SERIO 4-EXTREME / MUY GRAVE HMIS HAZARD RATING A - glasses/lentes SECTION 1 - PRODUCT NAME: SHINE -ON Product No: 4489, 4490 Product Type: UHS Restorer/Spray Buff 9/6/05 SECTION 2 - HAZARDOUS INGREDIENTS None SECTION 3 - HEALTH HAZARD & FIRST AID 1. Acute Health Effect None 2. Chronic Health Effects None 3. Carcinogen NO 4. Primary Entry Routes: a) Skin & Eyes: Prolonged contact with the skin may be irritating. Eye contact may be irritating. b) Ingestion: May be harmful. c) Inhalation: Not considered a hazard. 5. First Aid: a) Skin: Wash effected area with soap & water. Get medical attention for persistent irritation. b) Eyes: Wash eyes with large volumes of water for at least 15 minutes while lifting the upper and lower eyelids and rotating the eyeball. Get medical attention if irritation persists. c) Ingestion: Give large volumes of water. Do not induce vomiting. Get medical attention. d) Inhalation: N/A SECTION 4 - PHYSICAL & CHEMICAL CHARACTERISTICS 1. Physical State Liquid 2. Color Milky white 3. Odor Floral 4. Solubility in water Emulsifiable 5. Specific Gravity (H2O=1.0) 1.01 6. pH 8.0 7. Freezing Point N/A 8. Flash Point None (will not burn) 9. Vapor Pressure N/A SECTION 5 - FIRE AND EXPLOSION HAZARD 1. Flash Point None (will not burn) 2. Extinguishing Media N/A 3. Special Fire Fighting Procedures N/A 4. Unusual Fire & Explosion Hazard Fire fighters should observe all precautions that apply to any fire where chemicals are stored. SECTION 6 - REACTIVITY DATA 1. Stability Stable 2. Conditions to Avoid None known SECTION 7 - SPILL OR LEAK PROCEDURES 1. If product leaks or spills - Flood area with water-mop up dispose to sanitary sewer. 2. Abide by Federal, State, and Local regulations. SECTION 8 - PERSONAL PROTECTION 1. Wear glasses. SECTION 9 - SPECIAL PRECAUTIONS 1. Store containers closed and in an upright position. 2. Do not destroy or deface the label. SECTION 10 - SECTION 313 SUPPLIER NOTIFICATION (SARA) This product contains the following toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372: None SECTION 11 - TOXICOLOGICAL INFORMATION None SECTION 12 - ECOLOGICAL INFORMATION None SECTION 13 - DISPOSAL CONSIDERATIONS 1. See Section 7 above. SECTION 14 - DOT TRANSPORT INFORMATION 1. This product is Not Regulated. SECTION 15 - OTHER REGULATORY INFORMATION All ingredients appear on the TSCA Inventory List. SECTION 16 - OTHER INFORMATION *Revision on 9/6/05 in Section 6. 1. N/A = Not Applicable 2. PMCC = Pensky Martin Closed Cup The health hazards given on this Material Safety Data Sheet apply to this product in its concentrated form (as supplied) and may differ significantly at use dilution. The signs and of overexposure apply only to negligence in handling or misuse of the concentrated product and not to the routine exposure of the diluted product under conditions of ordinary use. 1 0 0 A 644 Page 274 of 328 Page 274 of 328 Page 274 of 328 Page 274 of 328 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Total Solutions P.O. Box 240014 Milwaukee, WI 53224 GENERAL INFORMATION NUMBER: (414) 354-6417 REVISION DATE: October 6, 2008 CHEMTREC: (800) 424-9300 DATE OF ISSUE: October 6, 2008 I - Product Identification Snow Plow Coating PRODUCT CODE: 0385 CHEMICAL FORMULATION: Protective coating mixture NFPA HAZARD IDENTIFICATION SYSTEM: HEALTH: 1 FLAMMABILITY: 2 REACTIVITY: 0 HAZARD RATING: 4 - Extreme; 3 - High; 2 - Moderate; 1 - Slight; 0 - Insignificant II - Hazardous Ingredients Values reported as TWA unless noted. EPA 40 CFR: SUBSTANCE APPROX % OSHA PEL ACGIH TLV 302 355 372 CAS # Mineral spirits > 90.0 N/E N/E N N N 8052-41-3 Key: PEL: Permissible Exposure Limit TLV: Threshold Limit Value C: Ceiling level STEL: Short Term Exposure Limit N/A: Not Applicable N/D: Not Determined N/E: Not Established Y: Yes N: No 302: CERCLA List of Hazardous Substances and Reportable Quantities (40 CFR 302.4). 355: SARA TITLE III / List of Extremely Hazardous Substances for Emergency Planning and Notification (40 CFR 355). 372: SARA TITLE III / List of Toxic Chemicals subject to Release Reporting (Community Right to Know) (40 CFR 372). III - Physical Data BOILING POINT N/D SPECIFIC GRAVITY (WATER = 0.79 VAPOR PRESSURE (mm Hg): N/D VOC CONTENT by weight): > 90.0 VAPOR DENSITY (AIR = N/D EVAPORATION RATE (WATER = >1.00 SOLUBILITY IN WATER: Insoluble pH: N/A APPEARANCE AND ODOR: Clear, colorless liquid; characteristic solvent odor. IV - Fire and Explosion Hazard Data FLASH POINT 103 (TEST METHOD): Closed cup FLAMMABLE LIMITS IN AIR (VOLUME UPPER: N/E LOWER: N/E EXTINGUISHING MEDIA: Foam, carbon dioxide, dry chemical. SPECIAL FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water fog. Firefighters should be equipped with full protective gear including self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARD: May emit toxic fumes when heated. Vapors may travel considerable distance to a source of ignition and flash back. Page 275 of 328 Page 275 of 328 Page 275 of 328 Page 275 of 328 ---PAGE BREAK--- PRODUCT NAME: Snow Plow Coating PRODUCT CODE: 0385 V - Reactivity Data STABILITY: Stable INCOMPATIBILITY: Strong acids and oxidizing agents. CONDITIONS TO AVOID: Heat, sparks or open flame. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may produce oxides of carbon and sulfur oxide. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: None VI - Health Hazard Data ROUTES OF ENTRY INHALATION: X EYE CONTACT: X SKIN CONTACT: X INGESTION: X INGREDIENTS THAT ARE CONSIDERED BY OSHA, NTP, IARC TO BE SUSPECTED HUMAN CARCINOGENS: None. EFFECTS OF OVEREXPOSURE IF IN EYES: Moderate irritation, redness, tearing, blurred vision. IF ON SKIN: Irritation, with prolonged or repeated contact, dermatitis. IF SWALLOWED: Gastrointestinal irritation, nausea, cramps, vomiting. May be harmful or fatal if swallowed. Small amounts of the liquid aspirated into the respiratory system during ingestion, or from vomiting, may cause bronchiopneumonia or pulmonary edema. IF INHALED: Irritation to upper respiratory tract, dizziness, weakness, headache, nausea, and unconsciousness. EMERGENCY AND FIRST AID PROCEDURES IF IN EYES: Flush eyes and under eyelids with plenty of cool water for at least 15 minutes. Obtain medical attention. IF ON SKIN: Remove contaminated clothing and launder before re-use. Wash with soap and water. If irritation persists, obtain medical attention. IF SWALLOWED: Contact physician or poison control center immediately. Do not induce vomiting unless told to do so by a physician or poison control center. Never give anything to an unconscious person. IF INHALED: Remove person to fresh air. Perform artificial respiration if indicated. Obtain medical attention. VII - Spill or Leak Protection STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Ventilate area and remove all sources of ignition. Soak up spilled material with inert absorbent material and place in a properly marked closed container for proper disposal. WASTE DISPOSAL METHOD: Consult local environmental authorities. VIII - Special Protection Information RESPIRATORY PROTECTION: Use with adequate ventilation. If recommended Exposure Limits are exceeded wear a NIOSH approved respirator, following manufacturer’s recommendations. VENTILATION LOCAL: Recommended MECHANICAL: Not required PROTECTIVE GLOVES: Chemical resistant gloves. EYE PROTECTION: Safety glasses and/or face shield. OTHER PROTECTIVE EQUIPMENT: Eye wash station. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in a cool, dry place away from heat and open flame. Wash thoroughly after handling. Keep container closed when not in use. OTHER PRECAUTIONS: Keep out of reach of children. Do not cut or weld on empty container as they may contain flammable residues. IX - Transportation Information (ground transportation only) DOT ID NUMBER: None DOT PROPER SHIPPING NAME: None DOT CLASS: None DOT PACKING GROUP: None The shipping information listed above applies only to non-bulk 119 gallons) containers of this product. This product may have more than one proper shipping name depending on packaging, product properties, & mode of shipment. If any alteration of packaging, product, or mode of transportation is further intended, different shipping names and labeling may apply. REVISION DATE: October 6, 2008 Prepared by: Technical Dept. DATE OF ISSUE: October 6, 2008 This information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Total Solutions assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material such vendees or users assume all risks associated with the use of this material. Page 276 of 328 Page 276 of 328 Page 276 of 328 Page 276 of 328 ---PAGE BREAK--- Revision Date: 07-May-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: SPARCLING Product Number: 7118 , 7108 Recommended Use: Disinfectant Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification Acute Toxicity - Inhalation (Gases): Category 4 Acute toxicity - Inhalation (Dusts/Mists) Category 4 Skin Corrosion/Irritation: Category 1 Serious Eye Damage/Eye Irritation: Category 1 GHS Label Elements Signal Word: Danger Hazard Statements: Harmful if inhaled. Causes severe skin burns and serious eye damage. May be corrosive to metals. Precautionary Statements: Prevention: Use only outdoors or in a well-ventilated area. Do not breathe mist, vapors or spray. Wash hands and any exposed skin thoroughly after handling. Wear protective gloves. Wear eye / face protection. Wear protective clothing. Keep in original or other corrosion resistant container. Response: IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. -Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. -Skin IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Wash contaminated clothing before reuse. -Inhalation: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. -Ingestion: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Corrosive to Metals: Page 1 / 6 Category 1 Symbols: Page 277 of 328 Page 277 of 328 Page 277 of 328 Page 277 of 328 ---PAGE BREAK--- 7118 - SPARCLING Revision Date: 07-May-2015 -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Spill: Absorb spillage to prevent material damage. Storage: Store locked up. Store in corrosion resistant container. Disposal: Dispose of contents and container in accordance with local, state and federal regulations. Hazards Not Otherwise Classified: Not Applicable Other Information: • Corrosive. • Harmful if swallowed • Do not mix with hypochlorite-type bleach or other household chemicals as hazardous vapors or gases may be produced. • Keep out of reach of children. • NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. 3.11613% of the mixture consists of ingredient(s) of unknown toxicity. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 60-100 hydrochloric acid 7647-01-0 7-13 betaines, bis(hydroxyethyl)tallow alkyl 70750-46-8 1-5 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. -Skin Contact: Take off immediately all contaminated clothing and shoes. Rinse with water or shower for at least 15 minutes. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. Wash contaminated clothing before reuse. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. -Ingestion: Rinse mouth. Do NOT induce vomiting. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. Never give anything by mouth to an unconscious person. Note to Physicians: NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Product does not support combustion, Use extinguishing agent suitable for type of surrounding fire Specific Hazards Arising from the Chemical: Dried product is capable of burning. Combustion products are toxic. Contact with metals may evolve flammable hydrogen gas. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Cool fire-exposed containers with water spray. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Page 2 / 6 Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). Page 278 of 328 Page 278 of 328 Page 278 of 328 Page 278 of 328 ---PAGE BREAK--- 7118 - SPARCLING Revision Date: 07-May-2015 7. HANDLING AND STORAGE Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Storage Conditions: Keep containers closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep from freezing. Incompatible Materials: Sodium hypochlorite (or other hypochlorites). Strong bases. Reactive metals such as aluminum, zinc and tin. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: None established. Chemical Name ACGIH TLV OSHA PEL NIOSH hydrochloric acid 7647-01-0 Ceiling: 2 ppm (vacated) Ceiling: 5 ppm (vacated) Ceiling: 7 mg/m3 Ceiling: 5 ppm Ceiling: 7 mg/m3 IDLH: 50 ppm Ceiling: 5 ppm Ceiling: 7 mg/m3 Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Eye wash stations and shower facilities should be readily accessible in areas where the product is handled. Personal Protective Equipment Eye/Face Protection: Wear splash goggles. Skin and Body Protection: Wear rubber or other chemical-resistant gloves. Use of impervious apron, boots and other protective equipment should be considered in order to prevent or minimize contact with this product. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Liquid Color: Green Odor: Mint fragrance pH: < 1.0 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 100 °C / 212 °F Flash Point: > 100 °C / > 212 °F ASTM D56 Evaporation Rate: < 1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 1.04 Solubility(ies): Soluble in water Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 3 / 6 Decomposition Temperature: No information available. Viscosity: No information available. Page 279 of 328 Page 279 of 328 Page 279 of 328 Page 279 of 328 ---PAGE BREAK--- 7118 - SPARCLING Revision Date: 07-May-2015 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatible Materials: Sodium hypochlorite (or other hypochlorites). Strong bases. Reactive metals such as aluminum, zinc and tin. Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Pain, redness, swelling of the conjunctiva and tissue damage. Eye contact may cause permanent damage. -Skin Contact: Pain, redness, blistering and possible chemical burn. -Inhalation: Irritation or damage to the mucus membranes of the respiratory tract. Nasal discomfort and coughing. -Ingestion: Damage or chemical burns to mouth, throat and stomach. Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Target Organ Effects: -Eyes. Respiratory System. -Skin. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 5068 mg/kg ATEmix (dermal): 26843 mg/kg ATEmix (inhalation-gas): 15152 mg/l ATEmix (inhalation-dust/mist): 4.6 mg/l Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available hydrochloric acid 7647-01-0 = 700 mg/kg ( Rat ) > 5010 mg/kg ( Rabbit ) = 3124 ppm ( Rat ) 1 h Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Microorganisms Crustacea hydrochloric acid 7647-01-0 Not Available 282: 96 h Gambusia affinis mg/L LC50 static Not Available Not Available Persistence and Degradability: No information available. Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Page 4 / 6 Contaminated Packaging: Dispose of in accordance with federal, state and local regulations. US EPA Waste Number: D002 Page 280 of 328 Page 280 of 328 Page 280 of 328 Page 280 of 328 ---PAGE BREAK--- 7118 - SPARCLING Revision Date: 07-May-2015 14. TRANSPORT INFORMATION DOT: UN/ID No: UN1760 Proper Shipping Name: Corrosive liquids, n.o.s., (contains hydrochloric (muriatic) acid) Hazard Class: 8 Packing Group: III Special Provisions: Shipping descriptions may vary based on mode of transport, quantities, package size, and/or origin and destination. Check with a trained hazardous materials transportation expert for information specific to your situation. 15. REGULATORY INFORMATION TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product contains the following listed substances: hydrochloric acid CAS No 7647-01-0 acid aerosols including mists, vapors, gas, fog, and other airborne forms of any particle size SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: No Reactive Hazard: No California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 ethanol - 64-17-5 Carcinogen Developmental WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. EPA Pesticide Registration Number: 5741-17 EPA Statement: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: EPA Pesticide Label: Danger. Corrosive. Causes irreversible eye damage or skin burns. Harmful if swallowed or absorbed through skin or inhaled. Do not get in eyes, on skin or on clothing. Avoid breathing vapor or spray mist. Wear coveralls over long-sleeved shirt and long pants, socks and chemical-resistant footwear, goggles or face shield, and chemical resistant gloves (such as barrier laminate or butyl) rubber, nitrile rubber, neoprene rubber, PVC or viton). Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. Remove contaminated clothing and wash clothing before reuse. 16. OTHER INFORMATION Revision Date: 07-May-2015 Reasons for Revision: No information available. NFPA Health Hazards: 3 Flammability: 0 Instability: 0 Special: N/A HMIS Page 5 / 6 Health Hazards: 3 Flammability: 0 Physical Hazards: 0 Page 281 of 328 Page 281 of 328 Page 281 of 328 Page 281 of 328 ---PAGE BREAK--- 7118 - SPARCLING Revision Date: 07-May-2015 Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 6 / 6 Page 282 of 328 Page 282 of 328 Page 282 of 328 Page 282 of 328 ---PAGE BREAK--- Page 283 of 328 Page 283 of 328 Page 283 of 328 Page 283 of 328 ---PAGE BREAK--- Page 284 of 328 Page 284 of 328 Page 284 of 328 Page 284 of 328 ---PAGE BREAK--- Page 285 of 328 Page 285 of 328 Page 285 of 328 Page 285 of 328 ---PAGE BREAK--- Page 286 of 328 Page 286 of 328 Page 286 of 328 Page 286 of 328 ---PAGE BREAK--- Page 287 of 328 Page 287 of 328 Page 287 of 328 Page 287 of 328 ---PAGE BREAK--- Page 288 of 328 Page 288 of 328 Page 288 of 328 Page 288 of 328 ---PAGE BREAK--- Page 289 of 328 Page 289 of 328 Page 289 of 328 Page 289 of 328 ---PAGE BREAK--- Page 290 of 328 Page 290 of 328 Page 290 of 328 Page 290 of 328 ---PAGE BREAK--- Page 291 of 328 Page 291 of 328 Page 291 of 328 Page 291 of 328 ---PAGE BREAK--- S A F E T Y D A T A S H E E T 3141 Clifty Drive Madison, IN 47250 Page 1 of 6 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION NAME: SUPER FLOOR CLEANER #10 TYPE: Alkaline Cleaner PRODUCT # 854602 FOR INDUSTRIAL USE ONLY – KEEP OUT OF THE REACH OF CHILDREN EMERGENCY RESPONSE INFORMATION: CHEMTREC Company Offices: Cara Cyrus: Bill Torline: [PHONE REDACTED] [PHONE REDACTED] [PHONE REDACTED] [PHONE REDACTED] 24-Hour Service Weekdays Evenings and Weekends Evenings and Weekends PREPARED DATE: 04-01-15 PREPARED BY: David Craft SECTION 2: HAZARDS IDENTIFICATION GHS Classification Corrosive to Metals Acute Toxicity, oral Skin Corrosion/Irritation Serious Eye Damage/Eye Irritation Specific Target Organ Toxicity Aquatic Toxicity (Acute) Category 1 Category 4 Category 1A Category 1 Category 2 Category 3 H290 H302 H314 H318 H373 H402 Signal Word DANGER Symbol Hazard Statements H290 May be corrosive to metals. H302 Harmful if swallowed H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage. H373 May cause damage to organs (liver and kidneys) through prolonged or repeated exposure H402 Harmful to aquatic life. Precautionary Statements P260 Do not breathe mist, spray, vapors. P264 Wash hands, forearms, and exposed areas thoroughly after handling. P273 Avoid release to the environment. P280 Wear eye protection, face protection, protective clothing, protective gloves. P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water / shower. P304 + P340 IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor / physician. Page 292 of 328 Page 292 of 328 Page 292 of 328 Page 292 of 328 ---PAGE BREAK--- SAFETY DATA SHEET Page 2 of 6 Super Floor Cleaner#10 Precautionary Statements Continued P321 Specific treatment (see Section P363 Wash contaminated clothing before reuse. P405 Store locked up. P501 Dispose of contents / container according to local, regional, national and international regulations. SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS COMPONENT SYNONYM CAS NO. % BY WEIGHT Sodium metasilicate None 6834-92-0 10 – 20 Sodium hydroxide Caustic soda 1310-73-2 5 - 15 Dipropylene glycol methyl ether DPM 34590-94-8 1 – 10 SECTION 4: FIRST AID MEASURES DESCRIPTION OF FIRST AID MEASURES: EYES: Immediately flush with large quantities of cool water continuously for at least 15 minutes. Call a physician. SKIN: Immediately flush with large quantities of cool water continuously for at least 15 minutes. Call a physician. Remove contaminated clothing and shoes. Do not put contaminated clothing and shoes back on. Wash clothing and shoes thoroughly in soap and water; rinse repeatedly in clean water and dry before reuse. INGESTION: If conscious, immediately give large quantities of water. DO NOT INDUCE VOMITING. Call a physician at once. DO NOT give anything by mouth if the person is unconscious or if having convulsions. INHALATION: Remove subject to fresh air. Give artificial respiration if necessary. Get medical attention immediately. PRIMARY ROUTE(S) OF ENTRY: Eyes, skin, inhalation. MOST IMPORTANT / EFFECTS, ACUTE AND DELAYED: EYE CONTACT: Causes serious eye damage. SKIN CONTACT: Corrosive. Causes burns. INGESTION: Harmful if swallowed. INHALATION: May cause nasal and respiratory irritation. CHRONIC Chronic overexposure to dipropylene glycol methyl ether has apparently been found to cause liver abnormalities and kidney damage in laboratory animals. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF NECESSARY: If you experience any of the / effects listed above seek medical advice. SECTION 5: FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Use extinguishing media as appropriate for surrounding fire. SPECIFIC HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE: Not considered flammable or explosive. Hazardous reactions will not occur under normal conditions. Contact with metals such as magnesium, aluminum and zinc alloys can rapidly generate hydrogen, which is explosive. ADVICE FOR FIRE FIGHTERS: Wear self-contained breathing apparatus and full protective clothing. Use water spray to keep containers cool. Hazardous Combustion Products: Carbon dioxide, carbon monoxide, phosphorus, phosphorus oxides. SECTION 6: ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, AND EMERGENCY PROCEDURES: Avoid all contact with skin, eyes and clothing. Avoid breathing vapors. Wear nitrile, neoprene, or natural rubber gloves. Goggles and faceshield necessary. Wear suitable protective clothing. Use NIOSH / MSHA approved positive pressure self-contained breathing apparatus when any material is involved in a fire. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Sweep up spills. If dissolved in water, contain liquid spills with sand and absorb on inert material. Dispose with solid waste. See Waste Disposal Method. Ventilate area. Do not discharge to sewers or waterways without proper treatment. Page 293 of 328 Page 293 of 328 Page 293 of 328 Page 293 of 328 ---PAGE BREAK--- SAFETY DATA SHEET Page 3 of 6 Super Floor Cleaner#10 SECTION 7: HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING: Wear proper safety equipment when handling this product. Handle in accordance with good industrial hygiene and safety procedures. CONDITIONS FOR SAFE STORAGE, INCLUDING INCOMPATIBILITIES: Store in dry area. Avoid adding to hot water (over 120°F). May cause flash boiling. Store away from acids. Keep container closed when not in use. SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES: CHEMICAL IDENTITY CAS NO. OSHA PEL ACGIH TLV Sodium hydroxide 1310-73-2 2 mg / M3* 2 mg / M3* Sodium metasilicate 6834-92-0 Dipropylene glycol methyl ether 34590-94-8 100 ppm (skin) 100 ppm (skin) *Denotes ceiling limit. **Manufacturer recommends a ceiling limit of 2 mg / M3. ENGINEERING CONTROLS: Use good ventilation. Local exhaust is recommended if TLVs are exceeded. INDIVIDUAL PROTECTION MEASURES: Selection of personal protective equipment should be based upon the anticipated exposure and made in accordance with OSHA’s Personal Protective Equipment Standard found in 29 CFR 1910 Subpart I. The following information may be used to assist in PPE selection. RESPIRATORY PROTECTION: In absence of proper environmental control, use NIOSH / MSHA approved respirator for dusts and mists where airborne exposure is excessive. SKIN PROTECTION: Nitrile rubber, neoprene or natural rubber gloves. Rubber apron and rubber boots required. Other equipment as required to avoid contact. EYE PROTECTION: Goggles and face shield necessary. GENERAL HYGIENE CONSIDERATIONS: Eyewash facility and emergency shower should be in close proximity. Always wash hands after handling any chemical. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Non-dusty, orange powder. ODOR: Pleasant, medicinal. ODOR THRESHOLD: Not available. pH (4 oz/gallon): 12.6 – 12.8 MELTING POINT/FREEZING POINT Not available INITIAL BOILING POINT AND BOILING RANGE Not available FLASH POINT (METHOD USED) Not available. EVAPORATION RATE Not available. FLAMMABILITY (SOLID, GAS) Not available. UPPER/LOWER FLAMMABLE OR EXPLOSIVE LIMIT Not available. VAPOR PRESSURE Not available. VAPOR DENSITY Not available. SPECIFIC GRAVITY Not available. SOLUBILITY IN WATER Appreciable. PARTITION COEFFICIENT: N-OCTANOL/WATER Not available. AUTO-IGNITION TEMPERATURE Not available. VISCOSITY, DYNAMIC Not available. DECOMPOSITION TEMPERATURE Not available. VISCOSITY Not available. Page 294 of 328 Page 294 of 328 Page 294 of 328 Page 294 of 328 ---PAGE BREAK--- SAFETY DATA SHEET Page 4 of 6 Super Floor Cleaner#10 SECTION 10: STABILITY AND REACTIVITY REACTIVITY: Hazardous reactions will not occur under normal conditions. CHEMICAL STABILITY: Stable under recommended handling and storage conditions (see Section POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. CONDITIONS TO AVOID: Excessive moisture. INCOMPATIBLE MATERIALS: Aluminum, tin, zinc, and their alloys; strong acids, hot water (causes flash boiling). Avoid contact with leather and wool. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon dioxide, carbon monoxide, phosphorus, phosphorus oxides. SECTION 11: TOXOLOGICAL INFORMATION ACUTE TOXICITY: Not classified. LD50 AND LC50 DATA: Not available. ROUTES OF EXPOSURE / EYES: DANGER! Causes serious eye damage. SKIN: DANGER! Causes burns. INGESTION: WARNING! Harmful if swallowed. INHALATION: WARNING! May cause nasal and respiratory irritation. GERM CELL MUTAGENICITY: Not classified. TERATOGENICITY: Not available. CHRONIC EFFECTS / CARCINOGENICITY: This material contains no ingredient above de minimus concentrations known or suspected to cause cancer. Chronic overexposure to dipropylene glycol methyl ether has apparently been found to cause liver abnormalities and kidney damage in laboratory animals. SPECIFIC TARGET ORGAN TOXICITY (Repeated exposure): May cause damage to organs (liver and kidneys) through prolonged or repeated exposure REPRODUCTIVE TOXICITY: Not classified. SPECIFIC TARGET ORGAN TOXICITY (Single exposure): Not classified. ASPIRATION HAZARD: Not classified. COMPONENT INFORMATION: Sodium hydroxide LD50 Oral Rat: 0.24 g/kg LD50 Dermal Rabbit: 1350 mg/kg LD50 Inhalation: no data Sodium metasilicate LD50 Oral Rat: 1280 mg/kg LD50 Dermal: No data LD50 Inhalation: No data Diethylene glycol methyl ether LD50 Oral: No data LD50 Dermal rabbit: 9,510 mg/kg LC50 Inhalation rat: 552 ppm 7 hours Page 295 of 328 Page 295 of 328 Page 295 of 328 Page 295 of 328 ---PAGE BREAK--- SAFETY DATA SHEET Page 5 of 6 Super Floor Cleaner#10 SECTION 12: ECOLOGICAL INFORMATION ECOTOXICITY The ecotoxicity of this product is not known COMPONENT INFORMATION Sodium hydroxide LC50 Fish, Guppy, Poecilia reticulate: 196 mg/L/96 hours Sodium metasilicate LC50 Fish (Gambusia affnis): 2320 ppm/96 hr LC50 water fleas (Daphnia magna): 247 ppm/96 hr LC50 snail egg (Lymnea): 632 ppm/ 96 hr LC50 Amphipoda: 160 ppm/96 hr Diethylene glycol methyl ether Acute Toxicity: LC50 fathead minnow: 10,000mg/l 96 hours LC50 Daphnia magna: 1,919 mg/l 48 hours EC50 selenastrum capricomutum: 1,000 mg/l 72 hours EC10 pseudomonay putida cell growth: 4,168 mg/l Chronic Toxicity: NOEC daphnia magna: 0.5 mg/l 22 days PERSISTENCE AND DEGRADABILITY: Not available. BIOACCUMULATIVE POTENTIAL: Not available. MOBILITY IN SOIL: Not available. OTHER ADVERSE EFFECTS: This material contains no hazardous air pollutants (HAPS). SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Normal for alkaline wastes containing phosphorus compounds. May require pH adjustment for neutralization. Dispose in accordance with local, state and federal regulations. SECTION 14: TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME: Corrosive solid, basic, inorganic, n.o.s. (contains sodium hydroxide) HAZARD CLASS: 8 IDENTIFICATION NUMBER: UN3262 PACKING GROUP: III EMERGENCY RESPONSE GUIDE: ERG #154 Page 296 of 328 Page 296 of 328 Page 296 of 328 Page 296 of 328 ---PAGE BREAK--- SAFETY DATA SHEET Page 6 of 6 Super Floor Cleaner#10 SECTION 15: REGULATORY INFORMATION VOC: 002 pounds per pound (20 grams per kilogram). TSCA STATUS All ingredients are listed on the TSCA inventory. CERCLA REPORTABLE QUANTITY 1,000 pounds for sodium hydroxide (approximately 10,000 pounds). SARA 311 / 312 HAZARD CLASSES x ACUTE HEALTH FIRE SUDDEN RELEASE OF PRESSURE x CHRONIC HEALTH REACTIVE SARA 312 INFORMATION Storage of 10,000 pounds or more may require filing a Tier 2 form. Threshold planning quantity for reporting is 10,000 pounds. This material is not an extremely hazardous substance (EHS). SARA 313 INFORMATION This material contains the following substances subject to the reporting requirements of Section 313 of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372 CHEMICAL NAME CATEGORY CODE CAS NUMBER % BY WEIGHT NONE STATE REGULATORY INFORMATION CALIFORNIA PROPOSITION 65 California has not identified the ingredients listed in Section 3 as known to cause cancer or reproductive toxicity. HEALTH 3 FLAMMABILITY 0 PHYSICAL HAZARD 0 FOR INDUSTRIAL USE ONLY – KEEP OUT OF THE REACH OF CHILDREN SECTION 16: OTHER INFORMATION MSDS STATUS: Revised to GHS Standards on 04-01-15. Page 297 of 328 Page 297 of 328 Page 297 of 328 Page 297 of 328 ---PAGE BREAK--- SAFETY DATA SHEET Issue Date 14-Jan-2015 Revision Date 14-Jan-2015 Version 1 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Product Name Super Toilet Bowl Cleaner Other means of identification Product Code N065 Synonyms None Details of the supplier of the safety data sheet Emergency telephone number Emergency Telephone Chemtrec 1-[PHONE REDACTED] 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Category 4 Acute toxicity - Dermal Not classified Acute toxicity - Inhalation (Gases) Category 3 Acute toxicity - Inhalation (Dusts/Mists) Category 4 Skin corrosion/irritation Category 1 Serious eye damage/eye irritation Category 1 Specific target organ toxicity (single exposure) Category 3 Label elements Emergency Overview Company Name Page 1 / 8 Nyco Products Company 5332 Dansher Road IL 60525 (708) 579-8100 nycoproducts.com Danger Hazard statements Harmful if swallowed Toxic if inhaled Causes severe skin burns and eye damage May cause respiratory irritation. May cause drowsiness or dizziness Page 298 of 328 Page 298 of 328 Page 298 of 328 Page 298 of 328 ---PAGE BREAK--- N065 Super Toilet Bowl Cleaner Revision Date 14-Jan-2015 Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Use only outdoors or in a well-ventilated area Do not breathe dust/fume/gas/mist/vapors/spray Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response Immediately call a POISON CENTER or doctor/physician Specific Treatment (See Section 4 on the SDS) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell Immediately call a POISON CENTER or doctor/physician IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Do NOT induce vomiting Precautionary Statements - Storage Store in a well-ventilated place. Keep container closed Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Other Information Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. Weight-% Trade Secret Hydrochloric Acid 7647-01-0 10-30 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES First aid measures General advice Immediate medical attention is required. Skin Contact Immediate medical attention is required. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Appearance Milky White Physical state Liquid Odor Acidic Page 299 of 328 Page 299 of 328 Page 299 of 328 Page 299 of 328 ---PAGE BREAK--- N065 Super Toilet Bowl Cleaner Revision Date 14-Jan-2015 Eye contact Immediate medical attention is required. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Do not rub affected area. Inhalation Remove to fresh air. Call a physician or poison control center immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Ingestion Immediate medical attention is required. Do NOT induce vomiting. Drink plenty of water. Never give anything by mouth to an unconscious person. Remove from exposure, lie down. Clean mouth with water and drink afterwards plenty of water. Call a physician or poison control center immediately. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important and effects, both acute and delayed Any additional important and effects are described in Section 11: Toxicology Information. Indication of any immediate medical attention and special treatment needed Note to physicians Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated. Do not give chemical antidotes. from glottal edema may occur. Marked decrease in blood pressure may occur with moist rales, frothy sputum, and high pulse pressure. Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media Caution: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical The product causes burns of eyes, skin and mucous membranes. Thermal decomposition can lead to release of irritating and toxic gases and vapors. In the event of fire and/or explosion do not breathe fumes. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Evacuate personnel to safe areas. Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Keep people away from and upwind of spill/leak. Environmental precautions Environmental precautions Do not allow into any sewer, on the ground or into any body of water. Should not be released into the environment. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Page 300 of 328 Page 300 of 328 Page 300 of 328 Page 300 of 328 ---PAGE BREAK--- N065 Super Toilet Bowl Cleaner Revision Date 14-Jan-2015 Methods for cleaning up Dike far ahead of liquid spill for later disposal. Soak up with inert absorbent material. Take up mechanically, placing in appropriate containers for disposal. Clean contaminated surface thoroughly. Prevent product from entering drains. Dam up. After cleaning, flush away traces with water. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation, especially in confined areas. In case of insufficient ventilation, wear suitable respiratory equipment. Use only with adequate ventilation and in closed systems. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container closed in a dry and well-ventilated place. Keep out of the reach of children. Keep containers closed in a dry, cool and well-ventilated place. Keep in properly labeled containers. Incompatible materials Incompatible with strong acids and bases. Incompatible with oxidizing agents. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Hydrochloric Acid 7647-01-0 Ceiling: 2 ppm (vacated) Ceiling: 5 ppm (vacated) Ceiling: 7 mg/m3 Ceiling: 5 ppm Ceiling: 7 mg/m3 IDLH: 50 ppm Ceiling: 5 ppm Ceiling: 7 mg/m3 Ethanol 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers, Eyewash stations & Ventilation systems. Individual protection measures, such as personal protective equipment Eye/face protection Tight sealing safety goggles. Face protection shield. Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. General Hygiene When using do not eat, drink or smoke. Keep away from food, drink and animal feeding stuffs. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is recommended. Avoid contact with skin, eyes or clothing. Take off all contaminated clothing and wash it before reuse. Wear suitable gloves and eye/face protection. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 301 of 328 Page 301 of 328 Page 301 of 328 Page 301 of 328 ---PAGE BREAK--- N065 Super Toilet Bowl Cleaner Revision Date 14-Jan-2015 Information on basic physical and chemical properties Physical state Liquid Other Information Density Lbs/Gal 9.16 VOC Content 0.0125 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Exposure to air or moisture over prolonged periods. Incompatible materials Incompatible with strong acids and bases. Incompatible with oxidizing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating and toxic gases and vapors. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information The primary effects and toxicity of this material are due to it corrosive nature. Inhalation Toxic by inhalation. Breathing of vapor can cause respiratory irritation and inflammation. Breathing of mist or liquid can cause burns to the respiratory tract. Eye contact Corrosive to the eyes and may cause severe damage including blindness. Appearance Milky White Color White Odor Acidic Odor threshold No Information available Property Values Remarks • Method pH <1 Specific Gravity 1.10 Viscosity < 25 cP @ 25°C Melting point/freezing point No Information available Flash point None Boiling point / boiling range 200 °F Evaporation rate No Information available Flammability (solid, gas) Flammability Limits in Air Upper flammability limit: Not Applicable Lower flammability limit: Not Applicable Vapor pressure No Information available Vapor density No Information available Water solubility Complete Partition coefficient No Information available Autoignition temperature No Information available Decomposition temperature No Information available No data available Page 302 of 328 Page 302 of 328 Page 302 of 328 Page 302 of 328 ---PAGE BREAK--- N065 Super Toilet Bowl Cleaner Revision Date 14-Jan-2015 Skin Contact Corrosive. Contact with skin may cause severe irritation and burns. Ingestion Toxic if swallowed. Ingestion causes acute irritation and burns to the mucous membranes of the mouth, trachea, esophagus and stomach. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Hydrochloric Acid 7647-01-0 = 700 mg/kg (Rat) > 5010 mg/kg ( Rabbit ) = 1.68 mg/L ( Rat ) 1 h Ethanol 64-17-5 = 7060 mg/kg ( Rat ) Yes = 124.7 mg/L ( Rat ) 4 h Information on toxicological effects No Information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No Information available. Germ cell mutagenicity No Information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA Hydrochloric Acid 7647-01-0 Yes Group 3 Yes Yes IARC (International Agency for Research on Cancer) Not classifiable as a human carcinogen Reproductive toxicity No Information available. STOT - single exposure No Information available. STOT - repeated exposure No Information available. Chronic toxicity Chronic exposure to corrosive fumes/gases may cause erosion of the teeth followed by jaw necrosis. Bronchial irritation with chronic cough and frequent attacks of pneumonia are common. Gastrointestinal disturbances may also be seen. Avoid repeated exposure. Possible risk of irreversible effects. Target organ effects EYES, Respiratory system, Skin. Aspiration hazard No Information available. Numerical measures of toxicity - Product Information Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document . 12. ECOLOGICAL INFORMATION Ecotoxicity 0.78% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea Hydrochloric Acid 7647-01-0 Yes 282: 96 h Gambusia affinis mg/L LC50 static Yes Ethanol 64-17-5 Yes 12.0 - 16.0: 96 h mykiss mL/L LC50 static 100: 96 h Pimephales promelas mg/L LC50 static 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through 9268 - 14221: 48 h Daphnia magna mg/L LC50 2: 48 h Daphnia magna mg/L EC50 Static 10800: 24 h Daphnia magna mg/L EC50 Persistence and degradability No Information available. Bioaccumulation No Information available. Other adverse effects No Information available 13. DISPOSAL CONSIDERATIONS Page 303 of 328 Page 303 of 328 Page 303 of 328 Page 303 of 328 ---PAGE BREAK--- N065 Super Toilet Bowl Cleaner Revision Date 14-Jan-2015 Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. This product contains one or more substances that are listed with the State of California as a hazardous waste. 14. TRANSPORT INFORMATION The basic description below is specific to the container size. This information is provided for at a glance DOT information. Please refer to the container and/or shipping papers for the appropriate shipping description before tendering this material for shipment. For additional information, please contact the distributor listed in section 1 of this SDS. DOT UN/ID No. UN1760 Proper shipping name Corrosive liquids, n.o.s. Hazard Class 8 Packing Group II Special Provisions B2, IB2, T11, TP2, TP27 Description UN1760, Corrosive liquids, n.o.s. (contains Hydrochloric Acid), 8, II Emergency Response Guide Number 154 TDG UN/ID No. UN1760 Proper shipping name Corrosive liquid, n.o.s. Hazard Class 8 Packing Group II Description UN1760, Corrosive liquids, n.o.s. (Contains Hydrochloric Acid), 8, II 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % Hydrochloric Acid - 7647-01-0 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Page 304 of 328 Page 304 of 328 Page 304 of 328 Page 304 of 328 ---PAGE BREAK--- N065 Super Toilet Bowl Cleaner Revision Date 14-Jan-2015 Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Hydrochloric Acid 7647-01-0 5000 lb Yes Yes X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) Hydrochloric Acid 7647-01-0 5000 lb 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 Ethanol - 64-17-5 Carcinogen Developmental U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Hydrochloric Acid 7647-01-0 X X X Ethanol 64-17-5 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not Applicable 16. OTHER INFORMATION Issue Date 14-Jan-2015 Revision Date 14-Jan-2015 Revision Note No Information available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health hazards 3 Flammability 0 Instability 0 Physical and Chemical Properties Yes HMIS Health hazards 3 Flammability 0 Physical hazards 0 Personal protection C Page 305 of 328 Page 305 of 328 Page 305 of 328 Page 305 of 328 ---PAGE BREAK--- Page 306 of 328 Page 306 of 328 Page 306 of 328 Page 306 of 328 ---PAGE BREAK--- Page 307 of 328 Page 307 of 328 Page 307 of 328 Page 307 of 328 ---PAGE BREAK--- Page 308 of 328 Page 308 of 328 Page 308 of 328 Page 308 of 328 ---PAGE BREAK--- Page 309 of 328 Page 309 of 328 Page 309 of 328 Page 309 of 328 ---PAGE BREAK--- Page 310 of 328 Page 310 of 328 Page 310 of 328 Page 310 of 328 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SURE PASS SPRAY BUFF Preparation date: 2007-01-11 Version Number: 2 1. PRODUCT AND COMPANY IDENTIFICATION Product name: SURE PASS SPRAY BUFF MSDS 529300250003 Product code: 6082320 Recommended use: Floor care. Emergency telephone number: 1-[PHONE REDACTED] (Prosar); 1-[PHONE REDACTED] (Int'l Prosar); 01-[PHONE REDACTED] (México) 2. HAZARDS IDENTIFICATION Principle routes of exposure: Eye contact. Skin contact. Inhalation. Eye contact: May be mildly irritating to eyes. Skin contact: May be mildly irritating to skin. Inhalation: None known. Ingestion: None known. 3. COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS COMPONENTS Ingredient(s) CAS # Weight % Triethanolamine 102-71-6 0.1 - 1.5% 4. FIRST AID MEASURES Eye contact: Flush immediately with plenty of water. Get medical attention if irritation occurs. Skin contact: Flush immediately with plenty of water. Get medical attention if irritation occurs. Inhalation: No specific first aid measures are required. Ingestion: No specific first aid measures are required. Aggravated Medical Conditions: Persons with pre-existing skin disorders may be more susceptable to irritating effects 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: Use dry chemical, CO2, water spray or "alcohol" foam. Extinguishing media which must not be used for safety reasons: No information available Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-0902 Ramsey Information Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.ramseycompany.com SURE PASS SPRAY BUFF 1 of 4 EMERGENCY OVERVIEW • CAUTION • MAY BE MILDLY IRRITATING TO EYES • MAY BE MILDLY IRRITATING TO SKIN Page 311 of 328 Page 311 of 328 Page 311 of 328 Page 311 of 328 ---PAGE BREAK--- 529300250003 Preparation date: 2007-01-11 Version Number: 2 Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Specific hazards: Not applicable Unusual hazards: None known Specific methods: No special methods required 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Use personal protective equipment Environmental precautions and clean-up methods: Prevent product from entering drains. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. 7. HANDLING AND STORAGE Handling: Avoid contact with skin and eyes. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep closed in a dry, cool and well-ventilated place. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: No special ventilation requirements. General room ventilation is adequate. Personal Protective Equipment Eye protection: No special requirements under normal use conditions Hand protection: No special requirements under normal use conditions Skin and body protection: No special requirements under normal use conditions Respiratory protection: No special requirements under normal use conditions Hygiene measures: Handle in accordance with good industrial hygiene and safety practice Ingredient(s) ACGIH OSHA Mexico Triethanolamine 5 mg/m3 (TWA) Personal protective equipment None / Aucune / Ninguno 9. PHYSICAL AND CHEMICAL PROPERTIES Solubility in other solvents: No information available Partition coefficient (n-octanol/water): No information available Boiling point/range: Not determined Melting point/range: Not determined Flash point: >200°F >93.3°C Decomposition temperature: Not determined Autoignition temperature: No information available 2 of 4 Flammability: 0 Density: 8.19 lbs/gal Reactivity Bulk density: No information available 0 Vapor density: No information available Evaporation Rate No information available Instability: 0 Viscosity: No information available Solubility: Soluble VOC: 8.5% * NFPA Health: 1 Physical State: Liquid HMIS Appearance: Liquid Color: White Health Odor: Citrus 1 pH: 8.4 Dilution pH: No information available. Fire Hazard 0 Specific gravity: 0.9816 Page 312 of 328 Page 312 of 328 Page 312 of 328 Page 312 of 328 ---PAGE BREAK--- 529300250003 Preparation date: 2007-01-11 Version Number: 2 9. PHYSICAL AND CHEMICAL PROPERTIES Elemental Phosphorus: 0 %P * - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 10. STABILITY AND REACTIVITY Stability: The product is stable Polymerization: Hazardous polymerization does not occur Hazardous decomposition products: None reasonably foreseeable. 11. TOXICOLOGICAL INFORMATION HAZARDOUS COMPONENTS Ingredient(s) LD50 Oral - Rat LD50 Dermal - Rabbit LC50 Inhalation - Rat Triethanolamine =4190 mg/kg >2000 mg/kg Not available Acute toxicity Oral LD50 estimated to be greater than 5000 mg/kg Chronic toxicity: None known Specific effects Carcinogenic effects: None known Mutagenic effects: None known Reproductive toxicity: None known Target organ effects: None known HAZARDOUS COMPONENTS Ingredient(s) NTP IARC OSHA Triethanolamine 102-71-6 3 12. ECOLOGICAL INFORMATION Environmental Information: No data available 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Dispose of according to all federal, state and local applicable regulations 14. TRANSPORT INFORMATION DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL), Australia (AICS), Korea (ECL), Philippines (PICCS), China (IECSC). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 STATE RIGHT TO KNOW Ingredient(s) CAS # MARTK: PARTK: RIRTK: Sorbitan monooleate 1338-43-8 - - - - Modified styrene acrylic polymers 64461-17-2 - - - - Water 7732-18-5 - - - - Isoparaffinic hydrocarbon solvent 64742-48-9 - - - - Alcohol ethoxylates 68131-39-5 - - - - Triethanolamine 102-71-6 X - X X Diethylene glycol monoethyl ether 111-90-0 - - X - 3 of 4 Page 313 of 328 Page 313 of 328 Page 313 of 328 Page 313 of 328 ---PAGE BREAK--- 529300250003 Preparation date: 2007-01-11 Version Number: 2 CERCLA/ SARA Ingredient(s) Weight % CERCLA/SARA RQ (lbs) Section 302 TPQ (lbs) Section 313 Diethylene glycol monoethyl ether 111-90-0 1 - 5% X Ingredient(s) CAA HAP CAA ODS CWA Priority Pollutants Diethylene glycol monoethyl ether 111-90-0 X SARA 311/312 Hazard Categories Immediate: - Delayed: - Fire: - Reactivity: - Sudden Release of Pressure: - Canada WHMIS hazard class: Non-controlled. Ingredient(s) CAS # NPRI Triethanolamine 102-71-6 X Diethylene glycol monoethyl ether 111-90-0 X 16. OTHER INFORMATION Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: None Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 4 of 4 Page 314 of 328 Page 314 of 328 Page 314 of 328 Page 314 of 328 ---PAGE BREAK--- Revision Date: 08-May-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: TNT FOAMING DISINFECTANT CLEANER Product Number: 6343 Recommended Use: Disinfectant Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification GHS Label Elements Signal Word: No signal word Hazard Statements: No hazard statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated Precautionary Statements: Prevention: Keep away from heat/sparks/open flames/hot surfaces. — No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Response: -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Protect from sunlight. Do not expose to temperatures exceeding 122°F (50°C) Store in a well-ventilated place Disposal: Not Applicable Hazards Not Otherwise Classified: Not Applicable Flammable Aerosols Category 1 Gases Under Pressure Page 1 / 5 Liquefied gas Symbols: Page 315 of 328 Page 315 of 328 Page 315 of 328 Page 315 of 328 ---PAGE BREAK--- 6343 - TNT FOAMING DISINFECTANT CLEANER Revision Date: 08-May-2015 Other Information: • May be harmful if swallowed. • May cause eye irritation. • May cause skin irritation. • Inhalation of vapors or mist may cause respiratory irritation. • Keep out of reach of children. 0.0249% of the mixture consists of ingredient(s) of unknown toxicity. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 60-100 diethylene glycol monobutyl ether 112-34-5 1-5 N-butane 106-97-8 1-5 tetrapotassium pyrophosphate 7320-34-5 1-5 alkyl dimethyl ammonium chloride 85409-23-0 <0.1 alkyl dimethyl benzyl ammonium chloride 68391-01-5 <0.1 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Water spray (fog), Foam Specific Hazards Arising from the Chemical: Extremely flammable aerosol. Exposure to high temperature may cause containers to burst. Bursting aerosol containers may be propelled from fire at high speed. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Water may be used to cool closed containers to prevent pressure build-up and possible auto ignition or explosion when exposed to extreme heat. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Remove all sources of ignition. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 7. HANDLING AND STORAGE Page 2 / 5 Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Wash thoroughly after handling. Page 316 of 328 Page 316 of 328 Page 316 of 328 Page 316 of 328 ---PAGE BREAK--- 6343 - TNT FOAMING DISINFECTANT CLEANER Revision Date: 08-May-2015 Storage Conditions: NFPA 30B Level 1 Aerosol. Do not store in direct sunlight or above 122 F° / 50 Exposure to high temperature may cause containers to burst. Keep out of the reach of children. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: None established. Chemical Name ACGIH TLV OSHA PEL NIOSH N-butane 106-97-8 TWA: 1000 ppm (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 TWA: 800 ppm TWA: 1900 mg/m3 Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Personal Protective Equipment Eye/Face Protection: Wear splash goggles. Skin and Body Protection: Wear rubber or other chemical-resistant gloves. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatible Materials: Strong oxidizing agents. Strong acids. Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Aerosol Color: Colorless Odor: Mint fragrance pH: 10.5-11.0 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 99 °C / 210 °F Flash Point: < -18 °C / < 0 °F (Propellant-estimated) Evaporation Rate: < 1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 1.01 (Product without propellant) Solubility(ies): Soluble in water Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 3 / 5 Decomposition Temperature: No information available. Viscosity: No information available. Page 317 of 328 Page 317 of 328 Page 317 of 328 Page 317 of 328 ---PAGE BREAK--- 6343 - TNT FOAMING DISINFECTANT CLEANER Revision Date: 08-May-2015 Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Pain and redness. -Skin Contact: Drying of the skin. -Inhalation: Nasal discomfort and coughing. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Target Organ Effects: Central nervous system. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 75960 mg/kg ATEmix (dermal): 53016 mg/kg ATEmix (inhalation-gas): 6292528 mg/l ATEmix (inhalation-dust/mist): 491.2 mg/l Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available diethylene glycol monobutyl ether 112-34-5 = 3384 mg/kg ( Rat ) = 2700 mg/kg ( Rabbit ) Not Available N-butane 106-97-8 Not Available Not Available = 658 mg/L ( Rat ) 4 h tetrapotassium pyrophosphate 7320-34-5 Not Available > 4640 mg/kg ( Rabbit ) Not Available Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Microorganisms Crustacea diethylene glycol monobutyl ether 112-34-5 100: 96 h Desmodesmus subspicatus mg/L EC50 1300: 96 h Lepomis macrochirus mg/L LC50 static Not Available 2850: 24 h Daphnia magna mg/L EC50 100: 48 h Daphnia magna mg/L EC50 tetrapotassium pyrophosphate 7320-34-5 Not Available 100: 96 h mykiss mg/L LC50 Not Available 100: 48 h water flea mg/L EC50 Persistence and Degradability: No information available. Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Pressurized container: Do not pierce or burn, even after use. Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT: UN/ID No: UN1950 Proper Shipping Name: Page 4 / 5 Aerosols Hazard Class: 2.1 Page 318 of 328 Page 318 of 328 Page 318 of 328 Page 318 of 328 ---PAGE BREAK--- 6343 - TNT FOAMING DISINFECTANT CLEANER Revision Date: 08-May-2015 Special Provisions: This product meets the exception requirements of section 49 CFR 173.306 as a limited quantity and may be shipped as a limited quantity. Shipping descriptions may vary based on mode of transport, quantities, package size, and/or origin and destination. Check with a trained hazardous materials transportation expert for information specific to your situation. 15. REGULATORY INFORMATION TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product contains the following listed substances: diethylene glycol monobutyl ether CAS No 112-34-5 applies to R-(OCH2CH2)n-OR', where n = 1, 2, or 3, R=Alkyl C7 or less, or R = Phenyl or Alkyl substituted phenyl, R' = H or Alkyl C7 or less, or OR' consisting of Carboxylic acid ester, Sulfate, Phosphate, Nitrate, or Sulfonate, Chemical Category N230 SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: Yes Sudden release of pressure hazard: No Reactive Hazard: No California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 ethanol - 64-17-5 Carcinogen Developmental WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. EPA Pesticide Registration Number: 5741-14 EPA Statement: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: EPA Pesticide Label: Caution. Causes moderate eye irritation. Avoid contact with eyes or clothing. Wash thoroughly with soap and water after handling. 16. OTHER INFORMATION Revision Date: 08-May-2015 Reasons for Revision: No information available. Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 1 Flammability: 1 Instability: 0 Special: N/A HMIS Page 5 / 5 Health Hazards: 1 Flammability: 2 Physical Hazards: 2 Page 319 of 328 Page 319 of 328 Page 319 of 328 Page 319 of 328 ---PAGE BREAK--- - 1 - UNITED 195 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 195 SMELL JEL Jellied Deodorant Spray December 22, 2012 HMIS III HEALTH (0 = Maximum Safety) 0 PHYSICAL HAZARD (0 = Maximum Safety) 0 Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 FLAMMABILITY (0 = Maximum Safety) 1 2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) Isopropyl alcohol 67-63-0 5-10 200 ppm 400 ppm 980 mg/m3 >5045 mg/kg (Rat/oral) 16000 ppm 8 hr (Rat) 1.2-propanediol 57-55-6 5-10 N/A N/A 22000-31000 Mg/kg(Rat/oral) N/A Propane/N-Butane 68476-85-7 10-30 1000 ppm 1800 mg/m3 1000 ppm 1800 mg/m3 N/A N/A 3. HAZARDS IDENTIFICATION Emergency Overview: Aerosol under pressure do not expose to high temperatures 120°F/49°C or store in direct sunlight. Routes of Entry: Eyes, Skin, Ingestion, Inhalation Eyes: May cause irritation. Skin: May cause slight irritation, possible dryness with prolonged contact. Inhalation: Intentional overexposure to mist or vapors may result in dizziness and headache. Ingestion: May cause nausea or gastric discomfort. Chronic Health Hazards: None known. Medical Conditions Generally Aggravated by Exposure: None known. Carcinogenicity (NTP/IARC/OSHA): None 4. FIRST AID MEASURES Eyes: Flush with plenty of water for 15 minutes and call a physician immediately. Skin: Wash with soap and water. If irritation persists, call a physician. If Inhaled: Remove patient to fresh air immediately. Apply artificial respiration if needed and call a physician. If Swallowed: Drink several glasses of water. Call a physician immediately. 5. FIRE FIGHTING MEASURES Flash Point (TCC): 180°F/82.2°C Explosive Limits: Lower (LEL): ND Upper (UEL): ND Flame Projection (Aerosol): Nonflammable per 16 CFR 1500.45 Hazardous Products of Combustion: When strongly heated, as in a fire, this product may produce carbon dioxide and carbon monoxide. Fire and Explosion Hazards: Do not expose aerosols to temperatures above 120°F/49°C or the container may burst, rupture or vent. Extinguishing Media: Water, foam, Carbon dioxide, Dry chemical, Fire Fighting Instructions: Wear self-contained breathing apparatus w/full protective clothing. Containers should be cooled with water to prevent vapor pressure build up. Prevent runoff from entering sewers and public waterways. 6. ACCIDENTAL RELEASE MEASURES Small Spills: Pick up small spills with rag or towel. Clean surface thoroughly to remove residual contamination. Large Spills: Remove sources of ignition and ventilate area. Soak up with an inert absorbent and place in designated disposal container. Prevent material from entering sewers or drains. Wash area thoroughly to remove residual contamination. MATERIAL SAFETY DATA SHEET 320 37th Avenue, St. Charles, Illinois 60174 To Reorder Call: www.unitedlabsinc.com . www.unitedlabsinc.ca [PHONE REDACTED] Always follow Label Directions and Cautions. * Chronic 2 Moderate 4 Severe 1 Slight 3 Serious 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: A Page 320 of 328 Page 320 of 328 Page 320 of 328 Page 320 of 328 ---PAGE BREAK--- - 2 - 7. HANDLING AND STORAGE Keep this product properly labeled and store in a cool, well-ventilated area, away from heat or other sources of ignition. Do not expose to direct sunlight or store at temperatures above 120°F/49°C. may cause bursting. Wash hands and face with soap and water after using this product. Keep out of reach of children. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Safety glasses recommended if direct contact is possible. Skin: Chemical resistant gloves recommended only for prolonged or repeated exposure. Respiratory: Not normally needed. If TLV is exceeded, an organic vapor cartridge respirator or SCBA may be needed. Engineering Controls: Ventilation not normally required and local exhaust generally adequate. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 212°F/100°C (Initial-Concentrate) Specific Gravity: 0.99 (Concentrate@77°F) Vapor Pressure: 17.5 77°F Melting Point: ND Vapor Density: >1 Evaporation Rate: <1 Solubility in Water: Soluble pH: 7.6—7.7 VOC (Volatile Organic Compounds): 24.9% Appearance and Odor: White aerosol foam in orange or mulberry scent 10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: When strongly heated, as in a fire, this product may produce carbon dioxide and carbon monoxide. Chemical Stability: Stable Conditions to Avoid (Polymerization): None Incompatibility: Avoid contact with strong oxidizers, alkalies, and acids. 11. TOXICOLOGICAL INFORMATION See section 2 12. ECOLOGICAL INFORMATION N/A 13. DISPOSAL CONSIDERATIONS Consult your local, state, provincial and federal regulations for proper disposal guidelines. Do not puncture or incinerate containers. Wrap container and place in trash collection. Disposal regulations may be different for each state and/or locality. Aerosol cans when vented to atmospheric pressure through normal use pose no disposal hazard. RCRA Hazard Class: Considered non-hazardous under RCA, however product should be fully characterized prior to disposal (40 CFR 261) 14. TRANSPORT INFORMATION US DOT: Consumer Commodity, ORM-D IMDG-Water/Ocean: UN 1950, AEROSOLS IN LIMITED QUANTITIES OF CLASS 2, 2.2, PG None IATA-Air: UN 1950, AEROSOLS IN LIMITED QUANTITIES OF CLASS 2, 2.2 PG None 15. REGULATORY INFORMATION U.S. Federal Regulations: TSCA (Toxic Substances Control Act): All Chemicals are listed or exempt CERCLA (Comprehensive Response Compensation, and Liability Act): None SARA Title III Section 302 EHS: None SARA Title III Section 311/312: None SARA Title III Section 313 Toxic Chemicals: Isopropyl Alcohol – CAS#67-63-0 State Regulations: California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? No Right-to-know acts for Rhode Island, Florida, Minnesota, Massachusetts, New Jersey, Tennessee, Connecticut hazardous material survey. Illinois toxic substances disclosure to employee act. 195WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR. California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? No 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 195 SMELL JEL PREPARED BY: Sandy Kopacz Page 321 of 328 Page 321 of 328 Page 321 of 328 Page 321 of 328 ---PAGE BREAK--- - 1 - UNITED 231 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 231 VANISHING ACT Industrial Strength Spot and Stain Remover February 05, 2013 HMIS III HEALTH (0 = Maximum Safety) 2 PHYSICAL HAZARD (0 = Maximum Safety) 0 Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 FLAMMABILITY (0 = Maximum Safety) 0 2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) Sodium thiosulfate 7772-98-7 3-7 NE NE NE NE 3. HAZARDS IDENTIFICATION Eyes: May cause irritation, burns, and/or destruction of tissues. Skin: Prolonged or repeated contact may cause irritation and burns. Inhalation: Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Ingestion: May cause serious damage to the mouth, esophogus, stomach, and other contacted tissues. 4. FIRST AID MEASURES Eyes: Immediately flush with plenty of water for at least 15 minutes.Get prompt medical attention. Skin: Wash with soap and plenty of water. If develop, seek medical attention. Inhalation: Remove to fresh air. If develop, seek medical attention. If not breathing, give artificial respiration. Ingestion: DO NOT induce vomiting. Get medical attention immediately. Never give anything by mouth to an unconscious person. Give several glasses of water to dilute. 5. FIRE FIGHTING MEASURES Flash Point (TCC): None Explosive Limits: Lower (LEL): ND Upper (UEL): ND Flame Projection (Aerosol): NA Hazardous Products of Combustion: When heated strongly, as in a fire, this product may produce oxides of carbon and oxides of phosphorous. Fire and Explosion Hazards: In the presence of extreme heat, as in a fire, product may react with active metals (e.g. aluminum, zinc) to release flammable hydrogen gas. Extinguishing Media: Water; dry chemical; carbon dioxide; foam Fire Fighting Instructions: Wear self-contained breathing apparatus w/full protective clothing. Containers should be cooled with water to prevent vapor pressure build up. 6. ACCIDENTAL RELEASE MEASURES Small Spills: Spills up to one gallon may be diluted with plenty of water and flushed to sewage drain. Large Spills: Soak up with an inert absorbent and place in designated disposal container. Wash area thoroughly.. MATERIAL SAFETY DATA SHEET 320 37th Avenue, St. Charles, Illinois 60174 To Reorder Call: www.unitedlabsinc.com . www.unitedlabsinc.ca [PHONE REDACTED] Always follow Label Directions and Cautions. * Chronic 2 Moderate 4 Severe 1 Slight 3 Serious 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: B Page 322 of 328 Page 322 of 328 Page 322 of 328 Page 322 of 328 ---PAGE BREAK--- - 2 - 7. HANDLING AND STORAGE Store in a cool, dry area. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Safety glasses recommended Skin: Chemical resistant gloves recommended Respiratory: Normally not required. Engineering Controls: Normally not required. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 212 F/100 C Specific Gravity: 1.05 (H2O=1) Vapor Pressure: ND Melting Point: ND Vapor Density: ND Evaporation Rate: 1 (Water=1) Solubility in Water: Complete pH: 12-13 Appearance and Odor: Clear colorless liquid with very faint scent 10. STABILITY AND REACTIVITY Hazardous Polymerization: NA Hazardous Decomposition: When strongly heated, as in a fire, this product may produce oxides of carbon and oxides of phosphorous. Chemical Stability: Stable Incompatibility: Oxidizing agents such as bleach and strong acids. 11. TOXICOLOGICAL INFORMATION Carcinogenicity (NTP/IARC/OSHA): None California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? None 12. ECOLOGICAL INFORMATION ND 13. DISPOSAL CONSIDERATIONS Consult your local, state and federal regulations for proper disposal guidelines. Disposal regulations may be different for each state and/or locality. 14. TRANSPORT INFORMATION DOT: Not regulated for transportation. TDG: Not regulated for transportation. UN: Available upon request. 15. REGULATORY INFORMATION VOC (Volatile Organic Compounds): None TSCA (Toxic Substances Control Act): Listed SARA Title III Section 302 EHS: None SARA Title III Section 311/312: ND SARA Title III Section 313 Toxic Chemicals: None WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 231 VANISHING ACT PREPARED BY: Sandy Kopacz Page 323 of 328 Page 323 of 328 Page 323 of 328 Page 323 of 328 ---PAGE BREAK--- Page 324 of 328 Page 324 of 328 Page 324 of 328 Page 324 of 328 ---PAGE BREAK--- Page 325 of 328 Page 325 of 328 Page 325 of 328 Page 325 of 328 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 27-Aug-2013 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 64066 Product name Zoom Spout Recommended Use Lubricant Disinfectant Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known. Principal Routes of Exposure Eyes. Skin. Potential health effects Eyes May cause the following effects:. Moderately irritating to the eyes. Stinging sensation. Watery eyes. Redness. Skin Direct contact may cause the following effects. Mild irritation. Redness. Burning sensation. Inhalation Severity depends on degree of exposure. Toxic by inhalation. Ingestion Diarrhea. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Paraffinic Mineral Oil 8042-47-5 60-100 4. FIRST AID MEASURES Eye contact Remove to fresh air. Flush eyes with plenty of water. Seek medical attention if irritation persists. Skin contact Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. Seek medical attention if irritation persists. Ingestion No specific treatment is necessary since this material is not likely to be hazardous by ingestion. Vomiting may cause aspiration pneumonia. Inhalation No specific treatment is necessary since this material is not likely to be hazardous by inhalation. Remove to fresh air. Contact physician if breathing difficulty develops. Notes to physician Treat 5. FIRE FIGHTING MEASURES Flash point °C 174 Flash point °F 345 Method Cleveland closed cup Autoignition temperature °C Not Applicable Autoignition temperature °F Not Applicable Flammability Limits in Air) Upper No data available Lower No data available Suitable extinguishing media Dry chemical powder. Carbon dioxide (CO2). Halons. Foam. Water spray. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Special Fire-Fighting Procedures Keep people away from and upwind of spill/leak. Specific hazards Keep product and empty container away from heat and sources of ignition. Page 1 / 3 Emergency Overview No information available Page 326 of 328 Page 326 of 328 Page 326 of 328 Page 326 of 328 ---PAGE BREAK--- Fire and Explosion Hazards Evacuate area of unprotected and unnecessary personnel. Do not enter any enclosed or confined fire space without proper protective equipment. Keep product and empty container away from heat and sources of ignition. Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Water or foam may cause frothing. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat . Empty containers contain residue and/or vapors. Do not weld, cut, pressurize, braze, solder, drill, grind, or expose such containers to heat, sparks, flame, static electricity, or other sources of ignition. They may explode and cause injury or death. Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Personnel should wear appropriate protective equipment. Follow all precautions for handling. Please refer to appropriate sections of MSDS for additional information. Evacuate area of unprotected and unnecessary personnel. Eliminate all sources of ignition. Do not allow product to reach sewage system, soil, surface or ground water, or any water course. Notify proper authorities if entry occurs. Dike or dam large spills. Soak up excess with absorbent material. Dispose of absorbent in accordance with local, state and federal regulations. 7. HANDLING AND STORAGE Handling Use normal safe handling procedures. Wear personal protective equipment. Remove and wash contaminated clothing before re-use. Thoroughly wash hands and exposed skin after handling. Containers can contain explosive vapors or residues. Concentrated vapors of this product are heavier than air and will collect in low areas, pits, storage tanks and other confined spaces. Do not enter those areas. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such contents to heat, flames, and other sources of ignition. Storage Keep containers closed in a dry, cool and well-ventilated place. Keep away from heat and sources of ignition. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Paraffinic Mineral Oil - - - - Ventilation and Environmental Controls If current ventilation practices are not adequate in maintaining airborne concentrations below the established exposure limits, additional ventilation or exhaust systems may be required. Hygiene measures General industrial hygiene practice Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Hand Protection Gloves are not required in normal use. Eye protection Use safety eyewear designed to protect against splash of liquids. Skin and body protection Impervious clothing. Other Protective Equipment A safety shower and eye wash station should be available for emergency use. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Liquid Color Colorless Odor None Odor Threshold Not Applicable pH Not Applicable Specific Gravity 0.85 Vapor pressure Not Applicable Vapor density >1 (Air = 1) Evaporation Rate <1 (Butyl Acetate = 1) Water solubility Negligible Partition Coefficient (n-octanol/water) Not Applicable Boiling point/range °C > 300 Boiling point/range °F > 572 Melting point/range °C Not Applicable Melting point/range °F Not Applicable Flash point °C 174 Flash point °F 345 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Avoid extreme temperatures. Incompatability Strong oxidizing agents. Hazardous Decomposition Products Carbon oxides. Sulphur oxides. Nitrogen. Polymerization Hazardous polymerization does not occur. Page 2 / 3 Product code 64066 Product name Zoom Spout Page 327 of 328 Page 327 of 328 Page 327 of 328 Page 327 of 328 ---PAGE BREAK--- 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Paraffinic Mineral Oil 8042-47-5 5000 mg/kg - - Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity None known Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects See Section 2 Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Paraffinic Mineral Oil Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Disposal Information As supplied, this product is a RCRA Hazardous Waste . Waste from residues / unused products No information available. 14. TRANSPORTATION INFORMATION DOT Not Regulated TDG Not Regulated 15. REGULATORY INFORMATION State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Paraffinic Mineral Oil Not Listed Not Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA Paraffinic Mineral Oil X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION NFPA Health - 1 Flammability - 1 Reactivity - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 3 / 3 Product code 64066 Product name Zoom Spout Page 328 of 328 Page 328 of 328 Page 328 of 328 Page 328 of 328