Document douglascountywi_gov_doc_611d011ff6

Safety Data Sheets Forestry Field Shop Forestry Department 12/10/2015 ---PAGE BREAK--- Safety Data Sheet Index Binder: Forestry Department - Forestry Field Shop #1062 Hand Sanitizer Hillyard Industries, Inc. 01/01/1999 11 #950 RV Plus Antifreeze ZECOL PRODUCTS COMPANY 05/01/2005 13 -20 (Degree) F Splash Windshield Washer Fluid Splash Products, Inc. 01/06/2012 15 -35 Degree F Ultimate Windshield Washer Fluid Splash Products, Inc. 01/06/2012 20 03405-5523 MASTERCRAFT PAINT & VARNISH REMOVER K-G SPRAY-PAK INC. 01/21/2014 25 28201 - HEET Gas Line Antifreeze 67-56-1 GOLD EAGLE COMPANY 03/11/2010 29 30080 ARMOR ALL MULTI PURPOSE CLEANER Armor All Products Corporation 10/12/1999 36 4216.00100 DEVFLEX HP WHITE SG E ICI Paints North America 12/06/2006 39 4216.00100 DEVFLEX HP WHITE SG E ICI Paints North America 12/16/2006 43 44 21929 ANTI RUST ENAM C BAS Valspar Corporation 07/23/1998 47 450 Yellow Zone Marking Paint The Valspar Corporation - Architectural Coatings Division 04/04/2012 51 4GB22 - Eye Wash Saline Concentrate 180 oz Sperian Eye & Face Protection, Inc. 06/16/2009 60 5FW88 GLOSS BLACK 9702833 Rust-Oleum Corporation 05/05/1998 61 5FW93 GLOSS RED - 9702838 Rust-Oleum Corporation 06/11/1997 71 6230-9-30 – Black Jack All Weather Plastic Roof Cement GARDNER-GIBSON 08/17/2011 78 80000 VAL IND ENAMEL GLOSS BLACK 6U The Valspar Corporation 03/02/2011 86 948-57291 VALSPAR GLOSS ENAMEL WHITE Dulux New Zealand, a division of DuluxGroup (New Zealand) Pty Ltd 04/13/2010 95 AERO SPOT CO2 ALL COLORS Nelson Paint Company 05/30/2002 102 All Purpose Purex Salt; California Pure Fine Sea Salt; California Pure Medium Sea Salt; California Pure Coarse Sea Salt; Canning & Pickling Salt; Commercial Grade, Water; Softening Pellets; Culinox 999 Chemical Grade Salt; Culinox 999 Fine Salt; Culinox 9 7647-14-5 MORTON SALT 02/14/2011 107 ANTIBACTERIAL FANTASTIK ALL PURPOSE CLEANER S.C. Johnson & Son, Inc. 05/31/2005 110 Antibacterial SCRUBBING BUBBLES Bathroom Cleaner Diversey, Inc. 04/27/2011 114 Product Name CAS Number Manufacturer Version Date Page Page 2 of 1235 Page 2 of 1235 Page 2 of 1235 Page 2 of 1235 ---PAGE BREAK--- Antibacterial SCRUBBING BUBBLES Bathroom Cleaner JohnsonDiversey, Inc. 09/01/2010 118 ARISTA 100% Exterior Latex Flat Paint, White Base Sherwin-Williams Company 04/18/2007 122 ARM & HAMMER BAKING SODA 144-55-8 Church & Dwight Co., Inc. 06/23/1986 127 Armor All Original Protectant The Armor All/STP Products Company 01/31/2015 129 ARMOR ALL PROTECTANT WIPES Armor All Products Corporation 06/01/2000 134 AUTOMATIC TRANSMISSION FLIID EXXONMOBIL OIL CORPORATION 135 Baby Powder Cornstarch Vi-Jon Inc. 02/28/2008 144 BLAST BLEACH ZECOL PRODUCTS COMPANY 05/01/2007 148 Bowl Fresh Plus Oxygen Bleach Willert Home Products 04/12/2006 150 BRP XP-S Mineral Two Stroke Injection Oil BP LUBRICANTS USA INC 11/05/2007 156 Burgess Bug Killer Insect Fog 64742-46-7 Fountainhead Group, Inc. 01/16/2004 161 Butane WestAir Gases & Equipment Inc 08/03/2015 163 CARNUBA WAX 8015-86-9 Xenex Laboratories Inc 04/27/2005 168 CARQUEST ANTIFREEZE COOLANT Ashland 09/06/2013 170 CARQUEST ANTIFREEZE COOLANT ASHLAND CHEMICAL COMPANY 10/13/2009 182 CARQUEST ANTIFREEZE COOLANT ASHLAND CHEMICAL COMPANY 05/01/2012 192 Castle Corrosion Off Castle Products, Inc. 01/07/2011 205 Castle Corrosion Off Castle Products, Inc. 06/14/2013 206 Castle Endura Castle Products, Inc. 06/14/2013 209 Castle Endura Castle Products, Inc. 06/14/2013 212 Castle Endura Castle Products, Inc. 01/07/2011 215 Castle Kleenz Oil Castle Products, Inc. 01/21/2009 216 Castle Long Life Castle Products, Inc. 10/07/2009 217 Castle Muscle Grease Castle Products, Inc. 06/14/2013 218 Castle Muscle Grease Castle Products, Inc. 01/07/2011 221 Castle Rubberized Undercoating Castle Products, Inc. 01/10/2011 222 Castle Rubberized Undercoating Castle Products, Inc. 06/17/2013 223 Castle Streak Proof Castle Products, Inc. 01/07/2011 226 Castle Streak Proof Castle Products, Inc. 09/20/2013 227 Product Name CAS Number Manufacturer Version Date Page Page 3 of 1235 Page 3 of 1235 Page 3 of 1235 Page 3 of 1235 ---PAGE BREAK--- Castle Streak Proof Castle Products, Inc. 06/14/2013 230 Castle Thrust Castle Products, Inc. 01/06/2011 233 Castle Thrust Castle Products, Inc. 06/14/2013 234 Castle Thrust Castle Products, Inc. 06/13/2013 237 Castle White Lithium Grease Castle Products, Inc. 01/07/2011 240 Castle Zapp Castle Products, Inc. 01/07/2011 241 Castle Zapp Castle Products, Inc. 06/14/2013 242 Castle Zapp Castle Products, Inc. 02/15/2012 245 CAT ANTI-SEIZE COMPOUND (HIGH TEMP) Chemtool, Inc. 10/07/2008 246 CAT HYDRAULIC OIL (HYDO) SAE 10W Exxon Mobil Corporation 03/02/2015 254 Clear Reflections ITW Professional Brands 01/06/2015 264 Clorox Bleach The Clorox Company 01/05/2015 275 Clorox Bleach The Clorox Company 05/01/2005 296 CLOROX REGULAR-BLEACH The Clorox Company 07/01/2012 297 Cool-Gard Antifreeze Pre-Diluted Northland Products Company 03/05/2001 298 CRANKCASE OIL ISO 68 SPECIAL FORMULA PREMIUM GRADE CAT PUMPS 12/01/2009 303 CRANKCASE OIL ISO 68 SPECIAL FORMULA PREMIUM GRADE CAT PUMPS 06/01/2015 304 CRANKCASE OIL ISO 68 SPECIAL FORMULA PREMIUM GRADE CAT PUMPS 06/30/2011 310 DAWN (All Variations) Procter & Gamble 09/08/2005 314 DAWN (All Variations), IVORY (All Variations), JOY (All Variations), SALVO Procter & Gamble - Fabric and Home Care 09/25/2003 318 DDC POWER GUARD DELVAC 1300 SUPER 15W-40 Mobil Oil 06/03/1999 322 DERMA FLEUR Lotion ZEE MEDICAL, INC. 02/01/2012 328 Diamond Solar Salt - Extra Coarse, Diamond Solar Salt - Coarse 7647-14-5 Cargill Salt 02/01/2005 330 DIESEL FUEL SUPPLEMENT +CETANE BOOST Power Service Products, Inc. 11/01/2011 336 Distilled White Vinegar 8028-52-2 H.J. HEINZ CO. 08/22/2011 347 DURATECH SATIN ENAMEL WHITE HALLMAN PAINTS CO/LINDSAY FINISHES 02/09/2001 349 DUTCH BOY* Professional Ext. Acrylic Latex Traffic Zone Marking Paint, Yellow Dutch Boy Group 10/28/2004 352 Product Name CAS Number Manufacturer Version Date Page Page 4 of 1235 Page 4 of 1235 Page 4 of 1235 Page 4 of 1235 ---PAGE BREAK--- Expunge Lawson Products, Inc. 07/29/2014 357 Expunge Lawson Products, Inc. 02/03/2014 361 EXXON UNLEADED GASOLINE 87 EXXON COMPANY, U.S.A. 10/08/1987 365 Flexseal Dispense-A-Gasket RTV Black Silicone Drummond, A Lawson Brand 10/30/2014 371 Formula 4-Stroke Engine Oil, SAE 0W-40 Amsoil, Inc. 06/18/2003 382 Formula 4-Stroke Engine Oil, SAE 0W-40 Amsoil, Inc. 10/18/2006 386 GardenTech Sevin-5 Ready-To-Use 5% Dust Bug Killer TechPac, LLC. 09/01/2009 390 Gel Threadlocker - Red Lawson Products, Inc. 05/08/2012 394 GERM X WECHEM INC. 11/07/2002 397 GL-5 85W140 Multi-Purpose Gear Oil Spectrum Lubricants Corporation 10/14/2004 398 Glade Neutralizer Aerosol S.C. Johnson & Son, Inc. 01/16/2007 401 Gloss Blue Rust-Oleum Corporation 10/24/2001 405 GOJO ORIGINAL FORMULA HAND CLEANER GOJO Industries, Inc. 09/02/2010 414 GRAISSE BLANCHE MULTIFONCTIONS White Lithium Grease + PTFE Aerosol CRC Industries Europe bvba 11/23/2010 420 Gunk Car & Truck Wash - Concentrated RSC Chemical Solutions 06/23/2015 428 HARVEY'S PIPE THREAD COMPOUND HARVEY, WILLIAM H CO 10/12/1999 434 HARVEY'S PIPE THREAD COMPOUND HARVEY, WILLIAM H CO 03/28/1995 437 Heavy Duty Metal Protectant AmsOil 440 HIGH STRENGTH THREADLOCKER RED GEL 10 GR ITW Permatex 04/07/2015 452 Hydraulic Fluid OD-15-200 Micromeritics Instrument Corporation 06/23/2004 460 Hydraulic Fluid OD-15-200 Micromeritics Instrument Corporation 05/20/2014 466 Industrial Enamel Paint - Flat Black Rust-Oleum Corporation 06/11/1997 472 Isagel SWEEN CORP 01/30/1996 479 ISO-HEET FUEL SYSTEM DRYER 67-63-0 Bowman Distribution 01/01/2003 481 K&N AIR FILTER CLEANER Rock Oil Company 12/16/2009 488 KINGSFORD ODORLESS CHARCOAL LIGHTER The Kingsford Manufacturing Company 10/01/1998 490 Product Name CAS Number Manufacturer Version Date Page Page 5 of 1235 Page 5 of 1235 Page 5 of 1235 Page 5 of 1235 ---PAGE BREAK--- Klean Strip Odorless Mineral Spirits W.M. BARR 04/16/2015 491 KLEAN STRIP PAINT THINNER 8052-41-3 W. M. Barr 10/03/2005 497 Klean Strip Xylol Xylene W. M. Barr 04/14/2015 503 Klotz Foam Air Filter Oil (Aerosol) – KL-606 Klotz Special Formula Products, Inc. 02/24/2005 512 LARGE DIAMETER THREADLOCKER RED 36ML ITW Permatex 05/01/2015 515 Lectra Motive Electric Parts Cleaner (aerosol) 127-18-4 CRC Industries, Inc. 07/24/2012 523 Lectra Motive Electric Parts Cleaner (aerosol) 127-18-4 CRC Industries, Inc. 08/25/2011 530 Lectra Motive Electric Parts Cleaner (aerosol) 127-18-4 CRC Industries, Inc. 05/17/2010 537 Lloyds Glass Cleaner & Polish Lloyds Laboratories, Inc. 04/26/2004 544 LOCTITE 263 THREADLOCKER Henkel Canada Corporation 02/05/2015 545 Lubri-Temp Lawson Products, Inc. 10/30/2014 550 MAG 1 BRAKE PARTS CLEANER Warren Distribution, Inc. 08/11/2009 554 Marvel Air Tool Oil Marvel Oil Company 03/01/2010 559 MCCLOSKEY SPECIAL EFFECTS CLEAR COAT -FLAT The Valspar Corporation - Architectural Coatings Division 12/09/2003 564 MCCLOSKEY SPECIAL EFFECTS CLEAR COAT -FLAT The Valspar Corporation - Architectural Coatings Division 03/02/2010 569 Mean Green Super Strength Cleaner & Degreaser CR Brands, Inc. 10/01/2009 575 Mean Green Super Strength Cleaner & Degreaser CR Brands, Inc. 07/01/2012 577 Mean Green Super Strength Cleaner & Degreaser CR Brands, Inc. 01/01/2012 579 MINWAX Hardwood Floor Cleaner MINWAX Company 02/19/2013 581 MINWAX Hardwood Floor Cleaner MINWAX Company 04/03/2010 584 MINWAX Hardwood Floor Cleaner MINWAX Company 04/06/2015 587 MINWAX Hardwood Floor Cleaner MINWAX Company 11/17/2011 596 Minwax Hardwood Floor REVIVER, Low Gloss MINWAX 09/29/2007 599 MIRACLE GLASS CLEANER CP INDUSTRIES 01/01/2010 604 MOBIL CLEAN 5000 5W-30 Exxon Mobil Corporation 05/14/2008 606 Mobil Delvac 1300 Super 10W-30 Mobil Oil 04/02/1999 615 MOBIL DELVAC 1300 SUPER 10W-30 Exxon Mobil Corporation 03/03/2003 621 Product Name CAS Number Manufacturer Version Date Page Page 6 of 1235 Page 6 of 1235 Page 6 of 1235 Page 6 of 1235 ---PAGE BREAK--- MOBIL DELVAC 1300 SUPER 10W-30 Imperial Oil Products Division 03/21/2011 628 MOBIL DELVAC 1300 SUPER 10W-30 Imperial Oil Products Division 08/06/2009 637 MOBIL DELVAC 1300 SUPER 10W-30 68649-42-3 Exxon Mobil Corporation 04/29/2003 645 MOBIL DELVAC 1300 SUPER 15W-40 EXXONMOBIL OIL CORPORATION 06/17/2003 654 MOBIL DELVAC 1300 SUPER 15W-40 Imperial Oil Products Division 10/22/2007 662 MOBIL DELVAC 1300 SUPER 15W-40 Exxon Mobil Corporation 08/29/2006 670 MOBIL DELVAC 1300 SUPER 15W-40 Exxon Mobil Corporation 01/09/2004 679 MOBIL SPECIAL 5W-20 Exxon Mobil Corporation 09/02/2010 685 MOBIL SPECIAL 5W-20 Exxon Mobil Corporation 04/08/2013 694 MOBIL SPECIAL 5W-20 Exxon Mobil Corporation 09/10/2010 703 Mobil Trans HD 30 Exxon Mobil Corporation 11/29/2010 712 MOBILFLUID 424 Exxon Mobil Corporation 05/19/2009 721 MOBILGREASE XHP 222 SPECIAL Exxon Mobil Corporation 09/29/2015 729 MOBILGREASE XHP 222 SPECIAL Exxon Mobil Corporation 03/17/2015 739 MOBILUBE HD LS 80W-90 Mobil Oil 05/22/2001 749 Moly Coat Lawson Products, Inc. 05/02/2014 756 Moly Coat Lawson Products, Inc. 05/10/2010 760 Moly Coat Lawson Products, Inc. 05/01/2013 768 Motorcraft MERCON LV ATF Phillips 66 Lubricants 01/28/2013 772 MP HD Heavy Duty Metal Protector - Aerosol Amsoil, Inc. 09/15/2014 779 Murphy Oil Soap (Liquid) Colgate-Palmolive Company 03/01/2005 791 NAPA/CRC QD Electronic Cleaner (Aerosol) CRC Industries, Inc. 04/07/2009 794 Natural Magic Citrus Odor Blaster THE HOMAX GROUP, INC 11/30/2011 800 NEW HOLLAND AMBRA MASTERGOLD HSP ENGINE OIL-ALL GRADES VISCOSITY OIL 05/15/2003 803 NYK CORROSION COMPOUND NIAGARA LURBICANT 08/29/2006 808 O’REILLY POWER STEERING FLUID OMNI Specialty Packaging 01/21/2011 811 OFF! FamilyCare Spray Insect Repellent For Use on Kids Tropical Fresh REG. NO. 27325 P.C.P. ACT S.C. Johnson and Son, Limited 12/06/2013 818 P733 Fossil Grey S/G Flex Hybrid Diamond Vogel Paint 08/10/2015 826 PEAK LONG LIFE 50/50 ANTIFREEZE & Old World Industries, Inc. 06/04/2012 834 Product Name CAS Number Manufacturer Version Date Page Page 7 of 1235 Page 7 of 1235 Page 7 of 1235 Page 7 of 1235 ---PAGE BREAK--- COOLANT PERMATEX ANTI SEIZE LUBRICANT Loctite Corporation 05/30/1990 845 POLAR ISOPROPYL GASLINE ANTIFREEZE 67-63-0 Warren Distribution, Inc. 12/31/2002 847 Polar Starting Fluid SPRAY PRODUCTS CORPORATION 04/19/2011 851 Prestone 50/50 Ready-to-Use Antifreeze/Coolant Honeywell Consumer Products Group 08/15/2008 857 PRESTONE ANTIFREEZE/COOLANT Prestone Products Corporation 07/21/2005 864 Prime Blend BC20 Brake Cleaner 127-18-4 Prime Automotive 08/05/2009 872 PROPANE 74-98-6 BERNZOMATIC 06/11/2011 875 Propane 74-98-6 SpecAir Specialty Gases 11/28/2006 878 Pure Guard HD,SUPER,SAE 30, 40, 50, 15W- 40 DIESEL ENGINE OIL OMNI Specialty Packaging 01/06/2009 881 Pure Guard Super Heavy Duty BRAKE FLUID DOT 3 – 450 min OMNI INDUSTRIES, INC. 03/27/2006 887 Pure Guard Super Heavy Duty BRAKE FLUID DOT 3 – 450 min OMNI INDUSTRIES, INC. 02/20/2008 889 RAID FLYING INSECT KILLER 7 (COUNTRY FRESH) S.C. Johnson & Son, Inc. 02/25/2015 891 RAID WASP & HORNET KILLER 33 S.C. Johnson & Son, Inc. 02/23/2015 905 RED AUTO PRIMER Rust-Oleum Corporation - Industrial Coatings 05/19/2000 919 RENUZIT ADJUSTABLE SOLID AIR FRESHENER (RETAIL): SUPER ODOR KILLER,POWDER ROOM, COUNTRY FIELDS, AFTER THE RAIN, FRESH CUT FLOWERS,VANILLA, APPLE CINNAMON, RASPBERRY, LAVANDA, ROSA, GARDEN FRESH,FESTIVE PINE, FESTIVE POTPOURRI, CITRUS SUNBURST, WILD ORCHID DIAL CORPORATION 01/30/2001 928 Rust Stain Remover Whink Products Company 02/01/2008 932 Rust Stain Remover Whink Products Company 10/06/2008 939 Rust Stain Remover Whink Products Company 07/20/2014 947 Rust Stain Remover Whink Products Company 04/03/2012 953 SC JOHNSON ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE S.C. Johnson & Son Inc. 06/27/2011 961 SC JOHNSON ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE S.C. Johnson & Son Inc. 10/21/2008 969 SC Johnson One Step No Buff Wax - Fine S. C. Johnson & Son, Inc. 06/27/2011 977 Product Name CAS Number Manufacturer Version Date Page Page 8 of 1235 Page 8 of 1235 Page 8 of 1235 Page 8 of 1235 ---PAGE BREAK--- Wood Floor Care SEA FOAM Akzo Nobel - Awlgrip North America 09/23/2004 985 Sea Foam Motor Treatment SEA FOAM SALES CO 01/26/2006 989 Severe Gear EP Lubricant, Amsoil, Inc. 11/07/2007 991 Shell Rotella T5 10W-30 Shell Oil Products US 02/05/2014 995 Shellzone All-Season Antifreeze/Coolant SOPUS Products 07/11/2008 1004 SIKKENS MATTE SELECT NA 1QT Akzo Nobel Coatings, Inc. 09/20/2013 1015 SOFT CARE LOTIONIZED HAND SOAP Johnson Wax Professional 02/25/2003 1024 Softsoap Antibacterial Hand Soap Colgate-Palmolive Company 04/30/2002 1027 Softsoap Cucumber Melon LHS Colgate-Palmolive Company 09/21/2010 1030 SPLASH RV AND MARINE ANTIFREEZE 57-55-6 SuperClean Brands, Inc. 12/12/2007 1037 Sta-Lube Compressor Oil CRC Industries, Inc. 10/28/2002 1042 Stihl Bar & Chain Lubricant 64742-52-5 OMNI Specialty Packaging 01/03/2004 1045 STIHL HP ULTRA OMNI Specialty Packaging 10/01/2009 1047 STIHL HP ULTRA 2-CYCLE ENGINE OIL OMNI Specialty Packaging 06/02/2015 1053 STIHL WOODCUTTER BAR & CHAIN LUBRICANT OMNI Specialty Packaging 05/08/2015 1054 Streak Proof - Glass Cleaner Castle Products, Inc. 12/07/2002 1062 Super Clean Cleaner Degreaser PRO-TEX-ALL 06/17/1998 1063 SUPER SPOT TREE MARK ALL COLOR Nelson Paint Company 05/09/2002 1064 TFE Paste William H. Harvey Company 01/08/2010 1067 TFE Paste William H. Harvey Company 01/08/2010 1072 The Works Disinfectant Toilet Bowl Cleaner HomeCare Labs Inc 03/16/2005 1077 Titebond III Ultimate Wood Glue Franklin International 06/03/2015 1081 Tree & Log Marking Paint Nelson Paint Company 01/05/2010 1091 Turtle Wax Bug & Tar Remover - Spray Turtle Wax, Inc. 11/19/2014 1095 Universal Multi-Task Concentrate National Interchem Inc 12/01/2005 1102 UNIVIS N 32 Exxon Mobil Corporation 01/01/2002 1104 Valvoline DEXRON-VI FULL AUTOMATIC TRANSMISSION FLUID Ashland 07/03/2013 1113 Valvoline DEXRON-VI FULL AUTOMATIC TRANSMISSION FLUID ASHLAND CHEMICAL COMPANY 03/11/2010 1123 Valvoline DEXRON-VI FULL Ashland 07/03/2013 1135 Product Name CAS Number Manufacturer Version Date Page Page 9 of 1235 Page 9 of 1235 Page 9 of 1235 Page 9 of 1235 ---PAGE BREAK--- AUTOMATIC TRANSMISSION FLUID Wash N Shine 40185 Concentrated Car Soap S5-U Ashland 01/30/2008 1145 Wash N Shine 40185 Concentrated Car Soap S5-U Ashland 01/26/2008 1154 Weatherguard Lo-Sheen White HALLMAN PAINTS CO/LINDSAY FINISHES 10/19/2004 1163 WINDEX GLASS AND SURFACE WIPES WITH VINEGAR S.C. Johnson & Son, Inc. 10/21/2002 1166 WINDEX ORIGINAL GLASS CLEANER WITH AMMONIA-D S.C. Johnson & Son, Inc. 02/25/2015 1170 WINDEX POWDERIZED - ORIGINAL S.C. Johnson & Son, Inc. 08/11/2010 1179 WIPING WOOD STAIN AEROSOL DARK RED MAHOGANY Mohawk Finishing Products Division of RPM Wood Finishes Group, Inc. 07/05/2015 1186 Zerex ANTIFREEZE COOLANT Ashland 09/18/2008 1193 Zerex ANTIFREEZE COOLANT Ashland 12/02/2011 1202 Zerex ANTIFREEZE COOLANT Ashland 09/06/2013 1215 Zip-Strip Premium Paint & Finish Remover Recochem Inc. 02/03/2014 1227 Product Name CAS Number Manufacturer Version Date Page Page 10 of 1235 Page 10 of 1235 Page 10 of 1235 Page 10 of 1235 ---PAGE BREAK--- NFPA Rating Health 1 Flammability 2 Reactivity 0 HMIS Rating Health 1 Flammability 2 Reactivity 0 Material Safety Data Sheet This MSDS complies with OSHA’s Hazard Comm. Standard 29 CFR 1910.1200 and OSHA Form 174 DOT Hazard Classification * Consumer commodity, ORM-D Distributed By: Hillyard Industries, Inc. Identity (Trade Name) #1062 Hand Sanitizer Address: P.O. Box 909 MSDS Number * 1062-99-1 St. Joseph, MO 64502 Date Prepared: January 1, 1999 Telephone (Information) (816) 233-1321 (Ext.2303) http://www.hillyard.com Prepared By: Regulatory Dept. Telephone (Emergency) CHEMTREC (1-[PHONE REDACTED]) NOTE: Blank spaces are not permitted. If any item is not applicable or no information is available, the space must be marked to indicate that. SECTION II - Ingredients/Identity Information Components (Specific Other Limits Chemical Identity, Common Name(s)) CAS No. OSHA PEL ACGIH-TLV Recommended %(Opt.) Ethanol (SDA 40B) 64-17-5 1000 ppm 1000 ppm Water 7732-18-5 None None Mineral oil 8042-47-5 None None Oily ester 110-27-0 None None n-alkyl dimethyl benzyl ammonium chloride Mixture None None <1 n-alkyl dimethyl ethyl benzyl ammonium chloride Mixture None None <1 This product is not known to contain any compound listed and in quantities requiring reporting under SARA Title III Section 313. Any substance listed as hazardous by the States of California, Florida, Illinois, Michigan, New Jersey, Ohio, or Texas is described above if known present in regulated concentrations. SECTION III Physical/Chemical Characteristics Boiling Point 190 o F Specific Gravity (H2O = 1) @70 o F 0.957 Vapor Pressure (mm-Hg @ 70 o F) No Data Melting Point No Data Vapor Density (AIR = 1) Greater than one(1) Evaporation Rate (Butyl Acetate = 1) No Data Solubility in Water Complete pH 7.75+ 0.5 Appearance and Odor - Colorless translucent liquid with an alcohol - floral scent towel. SECTION IV - Fire and Explosion Hazard Data Flash Point (Method Used) 107° F (TCC) Flammable Limits No Data LEL No Data UEL No Data Extinguishing Media - Use carbon dioxide, dry chemical, foam or fog. Do not use water as it may froth and cause the fire to spread. Special Fire Fighting Procedures - Keep containers cool and vapors down with water spray. Prevent runoff from entering sewers and public waterways. Wear SCBA in chemical fires. Unusual Fire and Explosion Hazards - Combustible liquid on a polypropylene towel. Page 11 of 1235 Page 11 of 1235 Page 11 of 1235 Page 11 of 1235 ---PAGE BREAK--- 1062-99-1 January 1, 1999 SECTION V - Reactivity Data Stability Unstable Conditions to Avoid - Do not use near open flame, sparks, static electricity, welding arcs, etc. Do not smoke while using. Stable X Incompatibility (Materials to Avoid) - Strong oxidizing agents such as acetyl chloride, nitric acid, and hydrogen peroxide. Hazardous Decomposition or Byproducts - Carbon dioxide, carbon monoxide, formaldehyde, nitrous oxides, ammoniacal vapors, smoke, soot and various organic oxidation by-products. Hazardous May Occur Conditions to Avoid - None known Polymerization Will Not Occur X SECTION VI - Health Hazard Data Route(s) of Entry Eyes? Yes Inhalation? Yes Skin? No Ingestion? No Health Hazards (Acute and Chronic) - WARNING. Causes eye irritation. Maybe harmful if swallowed. Prolonged skin exposure may lead to dermatitis. Deliberate concentration and inhalation of vapors may cause central nervous system effects. Follow good chemical hygiene practices to avoid these hazards. Carcinogenicity: None known NTP? No IARC Monographs? No OSHA Regulated? No Signs and of Exposure - Redness, tearing or burning in eyes. Redness, drying or cracking skin. Swallowing may cause nausea, diarrhea, drowsiness, dizziness, fatigue, or loss of coordination. Medical Conditions Generally Aggravated by Exposure - Pre-existing skin or gastrointestinal disorders may be adversely affected. Follow good chemical hygiene practices to avoid these hazards. Emergency and First Aid Procedures: - Eyes - Flush with plenty of water for at least 15 minutes lifting eyelids to insure complete removal. See a physician immediately. Ingestion - Call a physician or poison control center. Not a likely route of overexposure. Inhalation - Get to fresh air. If breathing has stopped, qualified personnel should administer artificial respiration. Skin - Wash with soap and water. If irritation persists, call physician. SECTION VII - Precautions for Safe Handling and Use Steps to be Taken in Case Material is Released or Spilled - CAUTION. Slip hazard. Wipe up small spills For large spills, isolate area. Dike area to prevent spreading. Stay upwind. Eliminate ignition sources. Pick up on absorbent material. Put in suitable container Waste Disposal Method - Consult local, state, and federal regulations. Triple rinse empty container then offer for recycling, reuse, or reconditioning. Precautions to be Taken in Handling and Storing - Do not get in eyes. Do not swallow. Avoid prolonged skin contact. Keep containers sealed when not in use. Store indoors in a dry area. Keep from freezing. Use from original container only. Do not store with fertilizers, seeds, insecticides or fungicides. Other Precautions - Follow label directions carefully. Keep out of reach of children. Keep container sealed when not in use. Do not contaminate water, food or feed by use or storage. Do not smoke while using. SECTION VIII - Control Measures Respiratory Protection (Specify Type) - Not usually necessary. Use with adequate ventilation. Use NIOSH/MSHA approved respirator if PELs or TLVs are exceeded. Ventilation Local Exhaust Not usually needed Special None Mechanical (General) Yes Other None Protective Gloves - Not usually necessary. Only for packaging. Eye Protection - Not usually necessary. Avoid direct contact. Other Protective Clothing or Equipment - Not usually needed. For prolonged contact wear any necessary protective gear. Work/Hygienic Practices - Normal. Wash hands after use and before eating, drinking, smoking, using restrooms, etc. DISCLAIMER OF WARRANTIES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, OR OF ANY NATURE ARE MADE WITH RESPECT TO THE PRODUCT(S) OR INFORMATION CONTAINED IN THIS MATERIAL SAFETY DATA SHEET. The information and recommendations contained in this Material Safety Data Sheet are supplied pursuant to 29 CFR 1910.1200 of the Occupational Safety and Health Standards Hazard Communication Rule. All information contained herein is presented in good faith and is believed to be appropriate and accurate. THE BUYER OR USER ASSUMES ALL RISKS ASSOCIATED WITH THE USE, MISUSE OR DISPOSAL OF THIS PRODUCT. THE BUYER OR USER IS RESPONSIBLE TO COMPLY WITH ALL FEDERAL, STATE OR LOCAL REGULATIONS CONCERNING THE USE, MISUSE OR DISPOSAL OF THESE PRODUCTS. Page 12 of 1235 Page 12 of 1235 Page 12 of 1235 Page 12 of 1235 ---PAGE BREAK--- #950 RV PLUS ANTIFREEZE The information contained herein is based on current knowledge and experience; no responsibility is accepted that the information is sufficient or correct in all cases. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use and disposal of these materials and the safety and health of employees and customers and the protection of the environment. QUICK IDENTIFIER Common Name: (used on label and list) SECTION 2 - HAZARDOUS INGREDIENTS/IDENTITY 1 - 2 - 0 HEALTH FLAMMABILITY H F R REACTIVITY PERSONAL PROTECTION Style NC-L503R SECTION 1 - GENERAL INFORMATION Address Signature of Person Responsible for Preparation (Optional) City, State, and ZIP Name Emergency Telephone No. Other Information Calls Date Prepared ZECOL PRODUCTS COMPANY MEDINA, MN 55340 4635 WILLOW DRIVE (CHEM-TEL) 1-[PHONE REDACTED] (763) 478-3438 MAY 1, 2005 (REV) SECTION 4 - FIRE & EXPLOSION DATA Hazardous Component(s) [chemical & common name(s)] OSHA PEL ACGIH TLV CAS ppm ppm NO. Appearance and Odor Solubility in Water Boiling Point SECTION 3 - PHYSICAL & CHEMICAL CHARACTERISTICS 175o F. Soluble Pink liquid. Alcohol odor. Specific Gravity (H2O=1) Auto-Ignition Temperature Flash Point Unusual Fire and Explosion Hazards 148o F. NA Special Fire Fight- ing Procedure Water spray should be used to cool fire exposed containers and/or to disperse unignited vapors. Use NIOSH/ MSHA approved possitive pressure self-contained breathing apparatus when any material is involved in a fire. None Method Used COC Extinguisher Media Water spray, dry chemical, alcohol, foam, or carbon dioxide. Flammable Limits in Air % by Volume LEL Lower 2.6 UEL Upper 12.5 2 1 0 0 Evaporation Rate (N-Butyl Acetate=1) Vapor Density (Air=1) Vapor Pressure (mm Hg) 1.010 @ 60/60F NA 2.8 @ 20o C. NA May be used to comply with OSHA's Hazard Communication Standard, 29CFR1910.1200. Standard must be consulted for specific requirements. Material Safety Data Sheet RV Antifreeze Grade Propylene Glycol NE NE 57-55-6 Ethanol 1000 1000 64-17-5 (Not subject to the reporting requirements of Section 313, Title III of SARA.) ZECOL PRODUCTS COMPANY Page 13 of 1235 Page 13 of 1235 Page 13 of 1235 Page 13 of 1235 ---PAGE BREAK--- Other Precautions Precautions to be Taken in Handling and Storage SECTION 7 - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES Waste Disposal Methods (Consult federal, state, and local regulations) Respiratory Protection (Specify Type) SECTION 5 - PHYSICAL HAZARDS (REACTIVITY DATA) #950 RV PLUS ANTIFREEZE (cont.) Stability Unstable Stable Conditions to Avoid Incompatability (Materials to Avoid) Strong oxidizers. Hazardous Decomposition Products Carbon monoxide, carbon dioxide. Hazardous Polymerization May Occur Will Not Occur Conditions to Avoid SECTION 6 - HEALTH HAZARDS 1. Acute 2. Chronic Signs and of Exposure Medical Conditions Generally Aggravated by Exposure Chemical Listed as Carcinogen or Potential Carcinogen Yes No OSHA Yes No I.A.R.C. Monographs Yes No National Toxicology Program ROUTES OF ENTRY 1. Inhalation Remove victim to fresh air. 2. Eyes Flush with water for 15 minutes. Call a physician. 3. Skin Flush with water. If irritation develops, call a physician. 4. Ingestion Drink water to dilute. SECTION 8 - SPECIAL PROTECTION INFORMATION/CONTROL MEASURES Steps to be Taken in Case Material is Released or Spilled Avoid contact with eyes, skin, or clothing. Do not take internally. Upon contact with skin or eyes, wash off with water. Avoid breathing mist or vapor. Store in a cool, dry, well-ventilated area. Wear goggles, coveralls, impervious gloves and boots. Add dry absorbent; shovel or sweep up. Place in appropriate container and seal. Wash all contaminated clothing before reuse. In the event of a large spill, call the emergency telephone number shown on the front of this sheet. Dispose of contaminated product, empty containers and materials used in cleaning up spills or leaks in a manner approved for this material. Consult appropriate federal, state, or local regula- tory agencies to ascertain proper disposal procedures. Protective Gloves Ventilation Other Protective Clothing or Equipment Work/Hygienic Practices May be skin sensitizer in some individuals. Mild eye and skin irritant. None beyond good room ventilation normally required. x x x x x Emergency and First Aid Procedures None Impervious. Goggles. Avoid contact with eyes, skin, and clothing. Keep away from extreme heat and flame. None known. Irritated skin or eyes, diarrhea. T/C/D Page 14 of 1235 Page 14 of 1235 Page 14 of 1235 Page 14 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MATERIAL IDENTITY: -20° F Splash Windshield Washer Fluid SECTION 1 – PRODUCT IDENTIFICATION & COMPANY INFORMATION Manufacturer: SPLASH PRODUCTS, INC. Telephone: (651) 489-8211 51 East Maryland Avenue St. Paul, MN 55117-4615 Facsimile: (651) 489-8247 Transportation Emergency for immediate information about a chemical or to seek assistance from a manufacturer: 1-[PHONE REDACTED] Date Updated: January 6, 2012 SECTION 2 - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION Hazardous Component* Approximate Composition OSHA Permissible Exposure Limit** NIOSH REL ACGIH Threshold Limit Value IDLH (NIOSH) Methanol (Methyl Alcohol) -CAS 67-56-1 -UN 1230 (DOT Guide 28) 31 percent by weight 200 ppm (260 mg/m3 ) 8-Hour TWA (Skin) 200 ppm (260 mg/m3) 8-Hour TWA 250 ppm (310 mg/m3) Ceiling (Skin) 200 ppm (260 mg/m3) 8-Hour TWA 250 ppm (310 mg/m3) Short-term Exposure Limit (15-minute TWA) (Skin) 6,000 ppm (0.6 percent in air) HMIS: HEALTH: 2 FLAMMABILITY: 2 REACTIVITY: 0 SPECIAL: NONE RATING SCALE: 0=MINIMAL 1=SLIGHT 2=MODERATE 3=SERIOUS 4=SEVERE SECTION 3 – HAZARDOUS IDENTIFICATION The hazardous component listed is not a known or suspected human carcinogen as listed or determined by the National Agency for Research on Cancer, National Toxicological Program “NTP Seventh Annual Report on Carcinogens,” or International Agency for Research on Cancer (IARC) monograph reviews. In addition, it is not considered a carcinogen by the Occupational Safety and Health Administration or the National Institute for Occupational Safety and Health. Can cause eye and skin irritation. HARMFUL IF SWALLOWED. DANGER POISON. FLAMMABLE. CANNOT BE MADE NONPOISONOUS. Irritation to respiratory track. INGESTION: Can cause blindness. INHALATION: May cause headaches, dizziness, nausea, incoordination, drowsiness, visual impairment and unconsciousness EYE CONTACT: Irritating to eyes; may cause severe and permanent damage. SKIN CONTACT: Prolonged or repeated contact without rinsing with water may cause irritation. MSDS -20° F Splash Windshield Washer Fluid Page 1 of 5 Page 15 of 1235 Page 15 of 1235 Page 15 of 1235 Page 15 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MATERIAL IDENTITY: -20° F Splash Windshield Washer Fluid SECTION 4 – FIRST AID MEASURES INGESTION: Do not give liquid if victim is unconscious or drowsy. Otherwise, give 1 or 2 glasses of water. Call doctor, hospital emergency room or poison control center for instructions to induce vomiting. When medical advice is not available, induce vomiting using syrup of ipecac according to direction. If ipecac not available, induce vomiting with finger or back of spoon by touching the back of the victim’s throat. Get medical attention. INHALATION: If exposed to excessive levels of vapors. Remove to fresh air. EYE CONTACT: Immediately flush eye with plenty of cool, running water. Remove contact lenses if applicable, and continue flushing for at least 15 minutes, holding eyelids apart to ensure thorough rinsing of the entire eye. Speed is essential to minimize injury. Call a physician immediately. SKIN CONTACT: immediately flush skin with plenty of cool running water for at least 15 minutes. Wash with soap and water. If irritation develops or persists, get medical attention. Remove contaminated clothing and shoes; wash before reuse. SECTION 5 – FIRE FIGHTING MEASURES FLASH POINT: 93°F FLAMMABLE LIMITS: In air % by volume, LEL: 6% UEL: 36% EXTINGUISHING MEDIA: Use of dry chemical, carbon dioxide, water spray, alcohol foam. SPECIAL FIRE FIGHTING PROCEDURES: Use fog or spray to prevent flooding. Be prepared to use MSHA-NIOSH self contained breathing apparatus and protecting clothing. FIRE AND EXPLOSION HAZARDS: Treat as flammable liquid. There is a chance of moderate explosion and/or dangerous fire hazard. SECTION 6 – ACCIDENTAL RELEASE MEASURES RESPONSE TO SPILLS: Eliminate all sources of ignition immediately. Mop up residue and rinse area thoroughly with water. Contain run-off with absorbent material such as sand or clay and diking. Transfer liquid and absorbent material in approved container. Flush and mop area with water allowing to air dry. Keep spill out of sewers and open bodies of water. SECTION 7 – HANDLING AND STORAGE HANDLING PRECAUTIONS: Follow directions on label. Wash after handling and before eating. STORAGE PRECAUTIONS: Store container upright. Tighten cap securely. Avoid heat, sparks, and flames. Protect container from physical damage. KEEP AWAY FROM CHILDREN MSDS -20° F Splash Windshield Washer Fluid Page 2 of 5 Page 16 of 1235 Page 16 of 1235 Page 16 of 1235 Page 16 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MATERIAL IDENTITY: -20° F Splash Windshield Washer Fluid SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION HYGIENIC PRACTICES: Avoid breathing vapors. Use with adequate ventilation. Wash thoroughly with soap and water after handling. Follow direction on label. Do not store near food stuffs, water or feed. SKIN PROTECTION: Rubber or neoprene gloves and additional protection including impervious boots, apron, or coveralls, as needed in areas of unusual exposure. EYE PROTECTION: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area. SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear blue liquid BOILING POINT: 170°F ODOR: Mild alcohol odor FREEZE POINT: -20°F pH: 8.2 VAPOR PRESSURE (mm of Hg): 97 @20C (68F) SPECIFIC GRAVITY: (water .952 @60°F VAPOR DENSITY (Air 1.1 SOLUBILITY IN WATER: 100% EVAPORATION RATE (BuAc=1): 5.9 SECTION 10 – STABILITY AND REACTIVITY CONDITIONS TO AVOID: HEAT, SPARKS, FLAMES. No smoking when using. INCOMPATIBILITY: Strong oxidizing agents such as nitrates and sulfuric acid. HAZARDOUS DECOMPOSITION PRODUCTS: Burning can product carbon monoxide and /or carbon dioxide. Carbon monoxide is highly toxic if inhaled. Carbon dioxide in sufficient concentration can act as an HAZARDOUS POLYMERIZATION: will not occur. SECTION 11 – TOXICOLOGICAL INFORMATION CARCINOGENICITY: This product does not contain any known or anticipated carcinogens according to the criteria of the NPT annual report on carcinogens and OSHA 29 CFR 1910, Z. Methyl Alcohol (Methanol): Oral rat LD50: 5628 mg/kg: inhalation rat LC50: 64000 ppm/4H: skin rabbit LD50: 15800 mg/kg; irritation data-standard Draize test: skin, rabbit: 20mg/24hr. Moderate; eye, rabbit: 100mg/24hr. Moderate. Investigated as a mutagen, reproductive effector. METHYL ALCOHOL (67-56-1) CARCINOGEN: Known: No. Anticipated: No. MSDS -20° F Splash Windshield Washer Fluid Page 3 of 5 Page 17 of 1235 Page 17 of 1235 Page 17 of 1235 Page 17 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MATERIAL IDENTITY: -20° F Splash Windshield Washer Fluid SECTION 12 – ECOLOGICAL INFORMATION ENVIRONMENTAL: When released into the soil, this material is expected to readily biodegrade. When released into the soil, this material is expected to leach into groundwater. When released into the soil, this material is expected to quickly evaporate. When released into water, this material is expected to have a half-life between 1 and 10 days. When released into water, this material is expected to readily biodegrade. When released into the air, this material is expected to exist in the aerosol phase with a short half-life. When released into the air, this material is expected to readily degraded by reaction with photo chemically produced hydroxyl radicals. When released into air, this material is expected to have a half-life between 10 and 30 days. When released into the air, this material is expected to be readily removed from the atmosphere by wet deposition. ENVIRONMENTAL TOXICITY: This material is expected to be toxic to aquatic life. SECTION 13 – DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: Dispose in accordance with federal, state and local regulations. SECTION 14 – TRANSPORT INFORMATION (U.S. D.O.T.) – U.S. Department of Transportation: PROPER SHIPPING NAME: Consumer Commodity ORM-D Exceptions: Per 49 CFR 173.150 (pg III, inner package not over 5.0 L) SECTION 15 – REGULATORY INFORMATION THIS PRODUCT CONTAINS COMPONENT(S) CITED ON THE FOLLOWING REGULATIONS: CHEMICAL NAME CAS NUMBER Methanol 67-56-1 U.S.FEDERAL REGULATIONS TSCA (Toxic Substance Control Act) Status – TSCA (UNITED STATES) CERCLA RQ – 40 CFR 3.2.1 Component RQ (lbs) Methyl Alcohol 5,000 MSDS -20° F Splash Windshield Washer Fluid Page 4 of 5 Page 18 of 1235 Page 18 of 1235 Page 18 of 1235 Page 18 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MATERIAL IDENTITY: -20° F Splash Windshield Washer Fluid SARA 302 Components – 40 CFR 355 Appendix A None Section 311/312 Hazard Class – 40CFR 370.2 Immediate Delayed Fire Reactive Sudden Release of Pressure SARA 313 Components - 40 CFR 372.65 Section 313 Components(s) CAS Number % Methanol 67-56-1 31 INTERNATIONAL REGULATIONS Inventory Status – DSL (CANADA) The international ingredients of this are listed. WHMIS Information: B2, D1A ECL (SOUTH KOREA) The international ingredients of this product are listed. EINECS (EUROPE) The international ingredients of this product are listed. ENCS (JAPAN) The international ingredients of this product are listed. State and Local Regulations – California Proposition 65 New Jersey RTK (Right-To-Know) Label information Methyl Alcohol 67-56-1 RTK (Right-To-Know) Label information Methanol 67-56-1 Atmospheric Standards: The Clean Air Act Amendments of 1990 list methanol as a hazardous air pollutant. SECTION 16 – OTHER INFORMATION Information in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The condition or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. MSDS -20° F Splash Windshield Washer Fluid Page 5 of 5 Page 19 of 1235 Page 19 of 1235 Page 19 of 1235 Page 19 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MATERIAL IDENTITY: -35° F Ultimate Windshield Washer Fluid SECTION 1 – PRODUCT IDENTIFICATION & COMPANY INFORMATION Manufacturer: SPLASH PRODUCTS, INC. Telephone: (651) 489-8211 51 East Maryland Avenue St. Paul, MN 55117-4615 Facsimile: (651) 489-8247 Transportation Emergency for immediate information about a chemical or to seek assistance from a manufacturer: 1-[PHONE REDACTED] Date Updated: January 6, 2012 SECTION 2 - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION Hazardous Component* Approximate Composition OSHA Permissible Exposure Limit** NIOSH REL ACGIH Threshold Limit Value IDLH (NIOSH) Methanol (Methyl Alcohol) -CAS 67-56-1 -UN 1230 (DOT Guide 28) Ethylene Glycol - CAS 107-21-1 34 percent by weight (by weight) 200 ppm (260 mg/m3 ) 8-Hour TWA (Skin) 200 ppm (260 mg/m3) 8-Hour TWA 250 ppm (310 mg/m3) Ceiling (Skin) 50 ppm (125 mg/m3) 100 ppm mg/m3 200 ppm (260 mg/m3) 8-Hour TWA 250 ppm (310 mg/m3) Short-term Exposure Limit (15-minute TWA) (Skin) 50 ppm (125 mg/m3) 100 ppm mg/m3 6,000 ppm (0.6 percent in air) NA HMIS: HEALTH: 2 FLAMMABILITY: 2 REACTIVITY: 0 SPECIAL: NONE RATING SCALE: 0=MINIMAL 1=SLIGHT 2=MODERATE 3=SERIOUS 4=SEVERE SECTION 3 – HAZARDOUS IDENTIFICATION The hazardous component listed is not a known or suspected human carcinogen as listed or determined by the National Agency for Research on Cancer, National Toxicological Program “NTP Seventh Annual Report on Carcinogens,” or International Agency for Research on Cancer (IARC) monograph reviews. In addition, it is not considered a carcinogen by the Occupational Safety and Health Administration or the National Institute for Occupational Safety and Health. Can cause eye and skin irritation. HARMFUL IF SWALLOWED. DANGER POISON. FLAMMABLE. CANNOT BE MADE NONPOISONOUS. Irritation to respiratory track. INGESTION: Can cause blindness. INHALATION: May cause headaches, dizziness, nausea, incoordination, drowsiness, visual impairment and unconsciousness EYE CONTACT: Irritating to eyes; may cause severe and permanent damage. SKIN CONTACT: Prolonged or repeated contact without rinsing with water may cause irritation. MSDS -35° F UltimateWindshield Washer Fluid Page 1 of 5 Page 20 of 1235 Page 20 of 1235 Page 20 of 1235 Page 20 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MATERIAL IDENTITY: -35° F Ultimate Windshield Washer Fluid SECTION 4 – FIRST AID MEASURES INGESTION: Do not give liquid if victim is unconscious or drowsy. Otherwise, give 1 or 2 glasses of water. Call doctor, hospital emergency room or poison control center for instructions to induce vomiting. When medical advice is not available, induce vomiting using syrup of ipecac according to direction. If ipecac not available, induce vomiting with finger or back of spoon by touching the back of the victim’s throat. Get medical attention. INHALATION: If exposed to excessive levels of vapors. Remove to fresh air. EYE CONTACT: Immediately flush eye with plenty of cool, running water. Remove contact lenses if applicable, and continue flushing for at least 15 to 20 minutes, holding eyelids apart to ensure thorough rinsing of the entire eye. Speed is essential to minimize injury. Call a physician immediately. SKIN CONTACT: immediately flush skin with plenty of cool running water for at least 15 minutes. Wash with soap and water. If irritation develops or persists, get medical attention. Remove contaminated clothing and shoes; wash before reuse. SECTION 5 – FIRE FIGHTING MEASURES FLASH POINT: 90°F FLAMMABLE LIMITS: In air % by volume, LEL: 6% UEL: 36% EXTINGUISHING MEDIA: Use of dry chemical, carbon dioxide, water spray, alcohol foam. SPECIAL FIRE FIGHTING PROCEDURES: Use fog or spray to prevent flooding. Be prepared to use MSHA-NIOSH self contained breathing apparatus and protecting clothing. FIRE AND EXPLOSION HAZARDS: Treat as flammable liquid. There is a chance of moderate explosion and/or dangerous fire hazard. SECTION 6 – ACCIDENTAL RELEASE MEASURES RESPONSE TO SPILLS: Eliminate all sources of ignition immediately. Mop up residue and rinse area thoroughly with water. Contain run-off with absorbent material such as sand or clay and diking. Transfer liquid and absorbent material in approved container. Flush and mop area with water allowing to air dry. Keep spill out of sewers and open bodies of water. SECTION 7 – HANDLING AND STORAGE HANDLING PRECAUTIONS: Follow directions on label. Wash after handling and before eating. STORAGE PRECAUTIONS: Store container upright. Tighten cap securely. Avoid heat, sparks, and flames. Protect container from physical damage. KEEP AWAY FROM CHILDREN MSDS -35° F Ultimate Windshield Washer Fluid Page 2 of 5 Page 21 of 1235 Page 21 of 1235 Page 21 of 1235 Page 21 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MATERIAL IDENTITY: -35° F Ultimate Windshield Washer Fluid SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION HYGIENIC PRACTICES: Avoid breathing vapors. Use with adequate ventilation. Wash thoroughly with soap and water after handling. Follow direction on label. Do not store near food stuffs, water or feed. SKIN PROTECTION: Rubber or neoprene gloves and additional protection including impervious boots, apron, or coveralls, as needed in areas of unusual exposure. EYE PROTECTION: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area. SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear purple liquid BOILING POINT: 170°F ODOR: Mild alcohol odor FREEZE POINT: -35°F pH: 8.2 VAPOR PRESSURE (mm of Hg): 97 @20C (68F) SPECIFIC GRAVITY: (water .948 @60°F VAPOR DENSITY (Air 1.1 SOLUBILITY IN WATER: 100% EVAPORATION RATE (BuAc=1): 5.9 SECTION 10 – STABILITY AND REACTIVITY CONDITIONS TO AVOID: HEAT, SPARKS, FLAMES. No smoking when using. INCOMPATIBILITY: Strong oxidizing agents such as nitrates and sulfuric acid. HAZARDOUS DECOMPOSITION PRODUCTS: Burning can product carbon monoxide and /or carbon dioxide. Carbon monoxide is highly toxic if inhaled. Carbon dioxide in sufficient concentration can act as an HAZARDOUS POLYMERIZATION: will not occur. SECTION 11 – TOXICOLOGICAL INFORMATION CARCINOGENICITY: This product does not contain any known or anticipated carcinogens according to the criteria of the NPT annual report on carcinogens and OSHA 29 CFR 1910, Z. Methyl Alcohol (Methanol): Oral rat LD50: 5628 mg/kg: inhalation rat LC50: 64000 ppm/4H: skin rabbit LD50: 15800 mg/kg; irritation data-standard Draize test: skin, rabbit: 20mg/24hr. Moderate; eye, rabbit: 100mg/24hr. Moderate. Investigated as a mutagen, reproductive effector. METHYL ALCOHOL (67-56-1) CARCINOGEN: Known: No. Anticipated: No. MSDS -35° F Ultimate Windshield Washer Fluid Page 3 of 5 Page 22 of 1235 Page 22 of 1235 Page 22 of 1235 Page 22 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MATERIAL IDENTITY: -35° F Ultimate Windshield Washer Fluid SECTION 12 – ECOLOGICAL INFORMATION ENVIRONMENTAL: When released into the soil, this material is expected to readily biodegrade. When released into the soil, this material is expected to leach into groundwater. When released into the soil, this material is expected to quickly evaporate. When released into water, this material is expected to have a half-life between 1 and 10 days. When released into water, this material is expected to readily biodegrade. When released into the air, this material is expected to exist in the aerosol phase with a short half-life. When released into the air, this material is expected to readily degraded by reaction with photo chemically produced hydroxyl radicals. When released into air, this material is expected to have a half-life between 10 and 30 days. When released into the air, this material is expected to be readily removed from the atmosphere by wet deposition. ENVIRONMENTAL TOXICITY: This material is expected to be toxic to aquatic life. SECTION 13 – DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: Dispose in accordance with federal, state and local regulations. SECTION 14 – TRANSPORT INFORMATION (U.S. D.O.T.) – U.S. Department of Transportation: PROPER SHIPPING NAME: Consumer Commodity ORM-D Exceptions: Per 49 CFR 173.150 (pg III, inner package not over 5.0 L) SECTION 15 – REGULATORY INFORMATION THIS PRODUCT CONTAINS COMPONENT(S) CITED ON THE FOLLOWING REGULATIONS: CHEMICAL NAME CAS NUMBER Methanol 67-56-1 U.S.FEDERAL REGULATIONS TSCA (Toxic Substance Control Act) Status – TSCA (UNITED STATES) CERCLA RQ – 40 CFR 3.2.1 Component RQ (lbs) Methyl Alcohol 5,000 MSDS -35° F Ultimate Windshield Washer Fluid Page 4 of 5 Page 23 of 1235 Page 23 of 1235 Page 23 of 1235 Page 23 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MATERIAL IDENTITY: -35° F Ultimate Windshield Washer Fluid SARA 302 Components – 40 CFR 355 Appendix A None Section 311/312 Hazard Class – 40CFR 370.2 Immediate Delayed Fire Reactive Sudden Release of Pressure SARA 313 Components - 40 CFR 372.65 Section 313 Components(s) CAS Number % Methanol 67-56-1 34 INTERNATIONAL REGULATIONS Inventory Status – DSL (CANADA) The international ingredients of this are listed. WHMIS Information: B2, D1A ECL (SOUTH KOREA) The international ingredients of this product are listed. EINECS (EUROPE) The international ingredients of this product are listed. ENCS (JAPAN) The international ingredients of this product are listed. State and Local Regulations – California Proposition 65 New Jersey RTK (Right-To-Know) Label information Methyl Alcohol 67-56-1 RTK (Right-To-Know) Label information Methanol 67-56-1 Atmospheric Standards: The Clean Air Act Amendments of 1990 list methanol as a hazardous air pollutant. SECTION 16 – OTHER INFORMATION Information in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The condition or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. MSDS -35° F Ultimate Windshield Washer Fluid Page 5 of 5 Page 24 of 1235 Page 24 of 1235 Page 24 of 1235 Page 24 of 1235 ---PAGE BREAK--- Page 25 of 1235 Page 25 of 1235 Page 25 of 1235 Page 25 of 1235 ---PAGE BREAK--- Page 26 of 1235 Page 26 of 1235 Page 26 of 1235 Page 26 of 1235 ---PAGE BREAK--- Page 27 of 1235 Page 27 of 1235 Page 27 of 1235 Page 27 of 1235 ---PAGE BREAK--- Page 28 of 1235 Page 28 of 1235 Page 28 of 1235 Page 28 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 28201 - HEET Gas Line Antifreeze SEC 1 - PRODUCT AND MANUFACTURER INFO SEC 9 - PHYS, CHEM PROPERTIES SEC 2 - COMPOSITION INFORMATION SEC 10 - STABILITY, REACTIVITY SEC 3 - HAZARDS IDENTIFICATION SEC 11 - TOXICOLOGY INFORMATION SEC 4 - FIRST AID MEASURES SEC 12 - ECOLOGICAL INFORMATION SEC 5 - FIRE FIGHTING MEASURES SEC 13 - DISPOSAL CONSIDERATIONS SEC 6 - ACCIDENTAL RELEASE MEASURES SEC 14 - TRANSPORT INFORMATION SEC 7 - HANDLING AND STORAGE SEC 15 - REGULATORY INFORMATION SEC 8 - EXPOSURE, PERS. PROTECTION SEC 16 - ADDITIONAL INFORMATION SECTION 1 - CHEMICAL PRODUCT AND MANUFACTURER IDENTIFICATION Product Name: 28201 - HEET Gas Line Antifreeze Part Number: 28201 Product CAS: (None) Product Code: 28201 Synonyms: 28201 - HEET Gas Line Antifreeze MANUFACTURER IDENTIFICATION Name: Gold Eagle Company Address: 4400 S. Kildare Blvd. City: Chicago State: IL Zip: 60632-4372 For information call: [PHONE REDACTED] Emergency Number: N/A Emergency Agency: INFOTRAC Agency Number: 1-[PHONE REDACTED] MSDS Effective Date: 1/1/1980 MSDS Supersedes Date: 3/11/2010 Miscellaneous: Product CAS: Mixture Brief Description: Gas line dryer and antifreeze for automobiles. Return to top SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS 1 of 7 2/15/2011 11:30 AM Page 29 of 1235 Page 29 of 1235 Page 29 of 1235 Page 29 of 1235 ---PAGE BREAK--- Chemical Name CAS MIN MAX Methanol 67-56-1 99 99 Proprietary Additive (none) 1 1 Miscellaneous: CHEMICAL NAME LIMIT VALUES Methanol PEL 200 ppm PEL 260 mg/m3 Proprietary Additive (CAS#:Mixture) N/A Return to top SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: NFPA: Health: 1 Fire: 3 Reactivity: 0 Specific Hazard: None HMIS: Health: 1 Flammability: 3 Reactivity: 0 PPE: B Miscellaneous: This product does not contain any components above de minimus concentrations that are considered carcinogenic by OSHA, IARC or NTP. POTENTIAL HEALTH EFFECTS Target Organs/Primary Route(s) of Entry: Eye: Mild irritant. Skin: Prolonged or repeated skin contact may cause dermatitis, scaling and possible systemic effects. Ingestion: POISON-Oral human lowest lethal dose = 6.4 g/kg Inhalation: Poisonous, narcotic chemical affecting central nervous system resulting in: dizziness, nausea, visual impairment, narcosis and muscular impairment. Miscellaneous: Return to top SECTION 4 - FIRST AID MEASURES Eye: If the product contacts the eyes, immediately wash the eyes with large quantities of room temperature water for at least 15 minutes, occasionally lifting the lower and upper lids. Get medical attention immediately. A follow up visit to an ophthalmologist should be made. Contact lenses should not be worn when working with this chemical. Skin: If the product contacts the skin, wash the contaminated skin with soap and water for at least 15 minutes. If this product penetrates the clothing, remove the clothing and wash the skin with soap and water. Systemic effects may be delayed 18 to 72 hours, therefore keep individual under observation. Ingestion: If this product is ingested and the person is conscious, induce vomiting, then give 2 teaspoons of baking soda in a glass of water. DO NOT INDUCE AN UNCONSCIOUS PERSON TO VOMIT. Get medical attention immediately. 2 of 7 2/15/2011 11:30 AM Page 30 of 1235 Page 30 of 1235 Page 30 of 1235 Page 30 of 1235 ---PAGE BREAK--- Inhalation: Move the exposed person to fresh air at once and call emergency medical care. If breathing has stopped, give artificial respiration. If breathing is difficult, give humidified oxygen. Notes to Physician: No data available. Return to top SECTION 5 - FIRE FIGHTING MEASURES Flash Point: 52 F. (11 TOC AutoIgnition Temperature: N/A Flammable Limits Lower Limit: Explosive Limit (LEL): 6.0 Upper Limit: Explosive Limit (UEL): 36.5 Extinguishing Media: Use halon replacement or carbon dioxide extinguishers or alcohol foam for small fires. Water spray or fog can cool fire but may not be effective in extinguishing fire. Large fires should be extinguished with alcohol foam. Use water spray to cool containers exposed to fire. Containers may explode in heat or fire. Unusual Fire and Explosion Hazards: Dangerous fire and explosion hazard when exposed to heat or flame. Methanol is extremely flammable and forms explosive mixtures with air. Methanol vapors may travel considerable distance to a source of ignition and flash back. Special Fire Fighting Procedures: Wear NIOSH approved SCBA respirator in the positive pressure mode and chemical protective clothing. General Information: Flammable Limits: 6.0 to 36.5 Return to top SECTION 6 - ACCIDENTAL RELEASE MEASURES Small Spill: Remove sources of heat or ignition, provide adequate ventilation, contain leak using absorbent, inert, non-combustible material. Large Spill: Contain spill, transfer to secure containers. In the event of an uncontrolled material release, the user should determine if release is reportable under applicable laws and regulations. Return to top SECTION 7 - HANDLING AND STORAGE Handling: See other sections of MSDS. Storage: See other sections of MSDS. 3 of 7 2/15/2011 11:30 AM Page 31 of 1235 Page 31 of 1235 Page 31 of 1235 Page 31 of 1235 ---PAGE BREAK--- Return to top SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION GENERAL HYGIENE CONSIDERATIONS: Use normal hygiene practices. OTHER PRECAUTIONS: Methanol waste and material contaminated with methanol would be regulated as a hazardous waste material under the hazardous waste number U154. ENGINEERING CONTROLS: Local Exhaust: Provide local ventilation to maintain exposure levels below recommended exposure limits. Mechanical (General): In confined spaces, mechanical ventilation may be required. Special Ventilation: N/A Other Ventilation: N/A PERSONAL PROTECTIVE EQUIPMENT Eyes/face: Use splash proof chemical, safety goggles or appropriate full-face respirator. Contact lenses should not be worn when working with this chemical. Skin: Use natural rubber or neoprene gloves as required. Respirators: Do not use air purifying respirator. Use NIOSH approved respirator approved supplied or self contained respirator. Respirators must be selected based on the airborne levels found in the workplace and must not exceed the working limits of the respirator. Other Protective Clothing/Equipment: If there is a possibility of exposure of an individual's body to methanol, wear body covering work clothes to avoid prolonged or repeated exposure. Return to top SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance/Odor: Yellow liquid, solvent odor pH: N/A Vapor Pressure: (MM HG): 97.0 Vapor Density(Air=1): 1.1 Evaporation Rate: N/A Viscosity: N/A Boiling Point: 148 F. (65 N/A 4 of 7 2/15/2011 11:30 AM Page 32 of 1235 Page 32 of 1235 Page 32 of 1235 Page 32 of 1235 ---PAGE BREAK--- Freezing/Melting Point: N/A Decomposition Temperature: N/A Solubility in Water: Soluble Specific Gravity: 0.795 Molecular Formula: N/A Molecular Weight: N/A VOC Coating (minus water): 0 Lbs/Gallon Coating Density : 0 Lbs/Gallon Solvent Density : 0 Lbs/Gallon Percent Solvent (volume): 0 Percent Solids (volume): 0 Percent Water (volume): 0 Percent Volatile by Weight: 0 Miscellaneous: % Volatile/Volume: 100.0 Specific Gravity (H2O = N/A Percent Solvent (Volume): N/A Percent Solids (Volume): N/A Percent Water (Volume): N/A Product is flammable, keep away from sources of ignition, combustibles, oxidizing material and acid. Store in an area equipped with automatic sprinklers or fire extinguishing system. Empty containers contain product residues, assume empty container to have the same hazards as full containers. Return to top SECTION 10 - STABILITY AND REACTIVITY Chemical Stability: Stable: Yes Conditions to Avoid: Store in a well ventilated place away from sources of ignition, combustibles, oxidizing materials and acid. Incompatibilities with Other Materials: Strong oxidizing agents, aluminum, zinc, or metals that displace hydrogen, rubber and rubber based coatings, chromic lead perchlorate and perchloric acids. Hazardous Decomposition Products: Excessive heating and/or incomplete combustion will produce carbon monoxide. Hazardous Polymerization: 5 of 7 2/15/2011 11:30 AM Page 33 of 1235 Page 33 of 1235 Page 33 of 1235 Page 33 of 1235 ---PAGE BREAK--- Hazardous Polymerization May Occur: No Return to top SECTION 11 - TOXICOLOGICAL INFORMATION No data available. Return to top SECTION 12 - ECOLOGICAL INFORMATION No data available. Return to top SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of product in accordance with local, state, and federal regulations. Before attempting clean up, refer to other sections of MSDS for hazard warning information. Return to top SECTION 14 - TRANSPORT INFORMATION Transportation Information: Shipping Information (CFR 49 and IMDG): Proper Shipping Name: Gasoline Additive, N.O.I. DOT Hazard Class: Consumer commodity, ORM-D DOT UN Number: None required. IMDG Shipping Name: Dangerous Goods in Limited Quantities of Class 3.2 (Methanol), PGII Label Information: No data available. Return to top SECTION 15 - REGULATORY INFORMATION SARA Title III: Section 302: None Section 304: None Section 311: Hazard categories-Fire Hazard-Yes; Acute=Yes and Chronic=Yes Section 313: Methanol, CAS# 67-56-1, 99.0% CERCLA: Section 311(b)(4): Requires discharges of crude oil and petroleum products in any kind or form to waters must immediately be reported to the National Response Center at (800) 424-8802. Return to top 6 of 7 2/15/2011 11:30 AM Page 34 of 1235 Page 34 of 1235 Page 34 of 1235 Page 34 of 1235 ---PAGE BREAK--- SECTION 16 - ADDITIONAL INFORMATION Disclaimer: Information presented herein is believed to be factual, as it has been derived from the works and opinions of persons believed to be qualified experts. However, nothing contained in this information is to be taken as warranty or representation for which the Gold Eagle Co. bears legal responsibility. The user should review any recommendations in the specific context of the intended use to determine whether they are appropriate. Prepared by: Mike Profetto Return to top 7 of 7 2/15/2011 11:30 AM Page 35 of 1235 Page 35 of 1235 Page 35 of 1235 Page 35 of 1235 ---PAGE BREAK--- Page 36 of 1235 Page 36 of 1235 Page 36 of 1235 Page 36 of 1235 ---PAGE BREAK--- Page 37 of 1235 Page 37 of 1235 Page 37 of 1235 Page 37 of 1235 ---PAGE BREAK--- Page 38 of 1235 Page 38 of 1235 Page 38 of 1235 Page 38 of 1235 ---PAGE BREAK--- SECTION 1 PRODUCT IDENTIFIER 4216.00100 DEVFLEX HP WHITE SG E DATE OF PREPARATION DECEMBER 16, 2006 PRODUCT USE PROTECTIVE COATING MANUFACTURED BY: ICI PAINTS NORTH AMERICA, 15885 WEST SPRAGUE ROAD, STRONGSVILLE, OHIO 44136, U.S.A ICI PAINTS (CANADA), 8200 KEELE STREET, CONCORD, ONTARIO L4K 2A5, CANADA. EMERGENCY AND MSDS TELEPHONE NUMBER: 1−800−545−2643 MSDS PREPARED BY: PRODUCT SAFETY AND TOXICOLOGY DEPARTMENT ICI PAINTS NORTH AMERICA SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENT WT.%: CHEMICAL NAME ACRYLIC RESIN 20−30 COMMON NAME : ACRYLIC RESIN CAS NUMBER: CONFIDENTIAL CHEMICAL NAME ETHANOL, 2−(2−METHOXYETHOXY)− 1−5 COMMON NAME : DIETHYLENE GLYCOL MONOMETHYL ETHER CAS NUMBER: 111−77−3 CHEMICAL NAME ETHANOL, 2−(2−BUTOXYETHOXY)− 5−10 COMMON NAME : DIETHYLENE GLYCOL MONOBUTYL ETHER CAS NUMBER: 112−34−5 CHEMICAL NAME TITANIUM OXIDE 20−30 COMMON NAME : TITANIUM DIOXIDE CAS NUMBER: 13463−67−7 CHEMICAL NAME WATER 40−50 COMMON NAME : WATER CAS NUMBER: 7732−18−5 SECTION 3: HAZARDS IDENTIFICATION PRIMARY ROUTE(S) OF EXPOSURE INHALATION, SKIN CONTACT, EYE CONTACT, INGESTION. EFFECTS OF OVEREXPOSURE INHALATION PROLONGED INHALATION MAY LEAD TO MUCOUS MEMBRANE IRRITATION, DIZZINESS AND/OR LIGHTHEADEDNESS, HEADACHE, NAUSEA, COUGHING, CENTRAL NERVOUS SYSTEM DEPRESSION. SKIN CONTACT IRRITATION OF SKIN. EYE CONTACT IRRITATION OF EYES. PROLONGED OR REPEATED CONTACT CAN CAUSE CONJUNCTIVITIS, TEARING OF EYES, REDNESS OF EYES. INGESTION INGESTION MAY CAUSE MOUTH AND THROAT IRRITATION, DROWSINESS, DIZZINESS AND/OR LIGHTHEADEDNESS, HEADACHE, UNCOORDINATION, NAUSEA, GASTRO−INTESTINAL DISTURBANCES, CENTRAL NERVOUS SYSTEM DEPRESSION, INTOXICATION, LIVER DAMAGE, KIDNEY DAMAGE, REPRODUCTIVE SYSTEM DAMAGE. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE EYE, SKIN, RESPIRATORY DISORDERS. SECTION 4: FIRST−AID MEASURES INHALATION REMOVE TO FRESH AIR. RESTORE AND SUPPORT CONTINUED BREATHING. GET EMERGENCY MEDICAL ATTENTION. HAVE TRAINED PERSON GIVE OXYGEN IF NECESSARY. GET MEDICAL HELP FOR ANY BREATHING DIFFICULTY. REMOVE TO FRESH AIR IF INHALATION CAUSES EYE WATERING, HEADACHES, DIZZINESS, OR OTHER DISCOMFORT. SKIN CONTACT WASH THOROUGHLY WITH SOAP AND WATER. IF ANY PRODUCT REMAINS, GENTLY RUB PETROLEUM JELLY, VEGETABLE OR MINERAL/BABY OIL ONTO SKIN. REPEATED APPLICATIONS MAY BE NEEDED. REMOVE CONTAMINATED CLOTHING. 4216.00100 DEVFLEX HP WHITE 1/4 Page 39 of 1235 Page 39 of 1235 Page 39 of 1235 Page 39 of 1235 ---PAGE BREAK--- WASH CONTAMINATED CLOTHING BEFORE RE−USE. EYE CONTACT FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER, ESPECIALLY UNDER LIDS FOR AT LEAST 15 MINUTES. IF IRRITATION OR OTHER EFFECTS PERSIST, OBTAIN MEDICAL TREATMENT. INGESTION IF SWALLOWED, OBTAIN MEDICAL TREATMENT IMMEDIATELY. SECTION 5: FIRE−FIGHTING MEASURES FLASH POINT (SETA) NONE LOWER EXPLOSIVE LIMIT NOT AVAILABLE UPPER EXPLOSIVE LIMIT 22.0 FIRE EXTINGUISHING MEDIA DRY CHEMICAL OR FOAM WATER FOG. CARBON DIOXIDE. UNUSUAL FIRE AND EXPLOSION HAZARDS CLOSED CONTAINERS MAY BURST IF EXPOSED TO EXTREME HEAT OR FIRE. FIRE FIGHTING PROCEDURES WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS. FIREFIGHTERS SHOULD USE FULL PROTECTIVE CLOTHING, EYE PROTECTION, AND SELF−CONTAINED BREATHING APPARATUS. HAZARDOUS DECOMPOSITION OR COMBUSTION PRODUCTS CARBON MONOXIDE, CARBON DIOXIDE, ACRYLIC MONOMERS. SECTION 6 ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED COMPLY WITH ALL APPLICABLE HEALTH AND ENVIRONMENTAL REGULATIONS. ELIMINATE ALL SOURCES OF IGNITION. VENTILATE AREA. PLACE COLLECTED MATERIAL IN PROPER CONTAINER. SPILLED MATERIAL IS EXTREMELY SLIPPERY. COMPLETE PERSONAL PROTECTIVE EQUIPMENT MUST BE USED DURING CLEANUP. LARGE SPILLS − SHUT OFF LEAK IF SAFE TO DO SO. DIKE AND CONTAIN SPILL. PUMP TO STORAGE OR SALVAGE VESSELS. USE ABSORBENT TO PICK UP EXCESS RESIDUE. KEEP SALVAGEABLE MATERIAL AND RINSE WATER OUT OF SEWERS AND WATER COURSES. SMALL SPILLS − USE ABSORBENT TO PICK UP RESIDUE AND DISPOSE OF PROPERLY. SECTION 7 HANDLING AND STORAGE HANDLING AND STORAGE STORE BELOW 100F (38C). KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. KEEP FROM FREEZING. KEEP CONTAINER CLOSED IN A WELL−VENTILATED AREA. OTHER PRECAUTIONS USE ONLY WITH ADEQUATE VENTILATION. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT WITH SKIN AND EYES, AND BREATHING OF VAPORS. WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY BEFORE EATING OR SMOKING. KEEP CONTAINERS CLOSED AND UPRIGHT WHEN NOT IN USE. EMPTY CONTAINERS MAY CONTAIN HAZARDOUS RESIDUES. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION COMMON NAME : TITANIUM DIOXIDE CAS NUMBER: 13463−67−7 ACGIH(TWA): 10 MG/M3 OSHA(TWA): 10 MG/M3 RESPIRATORY PROTECTION CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE EXPOSURE STANDARDS WHEN USING THIS MATERIAL. WHEN RESPIRATORY PROTECTION IS DETERMINED TO BE NECESSARY, USE A NIOSH/MSHA (CANADIAN Z94.4) APPROVED ELASTOMERIC SEALING− SURFACE FACEPIECE RESPIRATOR OUTFITTED WITH ORGANIC VAPOR CARTRIDGES AND PAINT SPRAY (DUST/MIST) PREFILTERS. DETERMINE THE PROPER LEVEL OF PROTECTION BY CONDUCTING 4216.00100 DEVFLEX HP WHITE 2/4 Page 40 of 1235 Page 40 of 1235 Page 40 of 1235 Page 40 of 1235 ---PAGE BREAK--- APPROPRIATE AIR MONITORING. CONSULT 29CFR1910.134 FOR SELECTION OF RESPIRATORS (CANADIAN Z94.4). VENTILATION PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT BUILD−UP OF VAPORS. PERSONAL PROTECTIVE EQUIPMENT EYE WASH, SAFETY SHOWER, SAFETY GLASSES OR GOGGLES. IMPERVIOUS GLOVES, IMPERVIOUS CLOTHING, FACE SHIELD. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES VAPOR PRESSURE: NOT AVAILABLE SPECIFIC GRAVITY: 1.231 BOILING RANGE 212−453/100−234 WEIGHT PER GALLON: 10.25/ 12.31IMP %VOLATILE BY VOLUME: 66.37 PHYSICAL STATE: LIQUID APPEARANCE WHITE SOLUBILITY IN WATER: NOT AVAILABLE PH: NOT AVAILABLE SECTION 10: STABILITY AND REACTIVITY UNDER NORMAL CONDITIONS STABLE SEE SECTION 5 FIRE FIGHTING MEASURES MATERIALS TO AVOID OXIDIZERS, ACIDS, BASES, ALKALIS, CAUSTICS. CONDITIONS TO AVOID ELEVATED TEMPERATURES, CONTACT WITH OXIDIZING AGENT, FREEZING. HAZARDOUS POLYMERIZATION WILL NOT OCCUR SECTION 11: TOXICOLOGICAL INFORMATION COMMON NAME : DIETHYLENE GLYCOL MONOMETHYL ETHER CAS NUMBER: 111−77−3 CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO LD50: 5500.00 MG/KG ORL RAT LD50: 8222.00 MG/KG ORL MOU LD50: 6540.00 MG/KG SKN RBT COMMON NAME : DIETHYLENE GLYCOL MONOBUTYL ETHER CAS NUMBER: 112−34−5 CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO LD50: 5660.00 MG/KG ORL RAT LD50: 2200.00 MG/KG SKN RBT COMMON NAME : TITANIUM DIOXIDE CAS NUMBER: 13463−67−7 CARCINOGENICITY LISTED BY: NTP YES 2B IARC YES 2B OSHA NO ACGIH NO LD50: 24.00 GM/KG ORL RAT LC50: 6820.00 MG/M3/4HR IHL RAT SUPPLEMENTAL HEALTH INFORMATION CONTAINS A CHEMICAL THAT MAY BE ABSORBED THROUGH SKIN. NOTICE − REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL. OTHER EFFECTS OF OVEREXPOSURE MAY INCLUDE TOXICITY TO LIVER, KIDNEY, BLOOD, REPRODUCTIVE SYSTEM. CARCINOGENICITY IN A LIFETIME INHALATION STUDY, EXPOSURE TO 250 MG/M3 TITANIUM DIOXIDE RESULTED IN THE DEVELOPMENT OF LUNG TUMORS IN RATS. THESE TUMORS OCCURRED ONLY AT DUST LEVELS THAT OVERWHELMED THE ANIMALS' LUNG CLEARANCE MECHANISMS AND WERE DIFFERENT FROM COMMON HUMAN LUNG TUMORS IN BOTH TYPE AND LOCATION. THE RELEVANCE OF THESE FINDINGS TO HUMANS IS UNKNOWN BUT QUESTIONABLE. THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) HAS CLASSIFIED TITANIUM DIOXIDE AS POSSIBLY CARCINOGENIC TO HUMANS (GROUP 2B) BASED ON INADEQUATE EVIDENCE OF 4216.00100 DEVFLEX HP WHITE 3/4 Page 41 of 1235 Page 41 of 1235 Page 41 of 1235 Page 41 of 1235 ---PAGE BREAK--- CARCINOGENICITY IN HUMANS AND SUFFICIENT EVIDENCE OF CARCINOGENICITY IN EXPERIMENTAL ANIMALS. REPRODUCTIVE EFFECTS NO REPRODUCTIVE EFFECTS ARE ANTICIPATED MUTAGENICITY NO MUTAGENIC EFFECTS ARE ANTICIPATED TERATOGENICITY PROLONGED INGESTION OF DIETHYLENE GLYCOL MONOMETHYL ETHER HAS RESULTED IN FETAL DEVELOPMENT ABNORMALITIES IN RATS AND EFFECTS ON FERTILITY IN MICE. SECTION 12: ECOLOGICAL INFORMATION NO ECOLOGICAL TESTING HAS BEEN DONE BY ICI PAINTS ON THIS PRODUCT AS A WHOLE. SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS. SECTION 14: TRANSPORT INFORMATION DOT PAINT PROTECT FROM FREEZING IMDG NOT AVAILABLE IATA NOT AVAILABLE TDG NOT AVAILABLE SECTION 15: REGULATORY INFORMATION SARA SARA CERCLA HAZ AIR MARINE 302 313 302.4 POLLUTANT POLTNT CAS NUMBER: 111−77−3 NO YES NO YES NO COMMON NAME : DIETHYLENE GLYCOL MONOMETHYL ETHER CAS NUMBER: 112−34−5 NO YES NO YES NO COMMON NAME : DIETHYLENE GLYCOL MONOBUTYL ETHER AS OF THE DATE OF THIS MSDS, ALL OF THE COMPONENTS IN THIS PRODUCT ARE LISTED (OR ARE OTHERWISE EXEMPT FROM LISTING) ON THE TSCA INVENTORY. THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR (CONTROLLED PRODUCTS REGULATIONS) AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR. SECTION 16: OTHER INFORMATION THE INFORMATION CONTAINED HEREIN IS BASED ON DATA AVAILABLE AT THE TIME OF PREPARATION OF THIS DATA SHEET AND WHICH ICI PAINTS BELIEVES TO BE RELIABLE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA. ICI PAINTS SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS INFORMATION, OR OF ANY PRODUCT, METHOD OR APPARATUS MENTIONED AND YOU MUST MAKE YOUR OWN DETERMINATION OF ITS SUITABILITY AND COMPLETENESS FOR YOUR OWN USE, FOR THE PROTECTION OF THE ENVIRONMENT, AND THE HEALTH AND SAFETY OF YOUR EMPLOYEES AND USERS OF THIS MATERIAL. COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD 29CFR1910.1200. 4216.00100 DEVFLEX HP WHITE 4/4 Page 42 of 1235 Page 42 of 1235 Page 42 of 1235 Page 42 of 1235 ---PAGE BREAK--- 4216.00100 DEVFLEX HP WHITE SECTION 1 PRODUCT IDENTIFIER 4216.00100 DEVFLEX HP WHITE SG E ) DATE OF PREPARATION DECEMBER 16, 2006 PRODUCT USE PROTECTIVE COATING MANUFACTURED BY: ICI PAINTS NORTH AMERICA, 15885 WEST SPRAGUE ROAD, STRONGSVILLE, OHIO 44136, U.S.A ICI PAINTS (CANADA), 8200 KEELE STREET, CONCORD, ONTARIO L4K 2A5, CANADA. EMERGENCY AND MSDS TELEPHONE NUMBER: 1—800—545—2643 MSDS PREPARED BY: PRODUCT SAFETY AND TOXICOLOGY DEPARTMENT ICI PAINTS NORTH AMERICA SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENT WT.*: CHEMICAL NAME ACRYLIC RESIN 20-30 COMMON NAME : ACRYLIC RESIN CAS NUMBER: CONFIDENTIAL CHEMICAL NAME ETHANOL, 2-(2-METHOXYETHOXY)- 1-5 COMMON NAME : DIETHYLENE GLYCOL MONOMETHYL ETHER CAS NUMBER: 111-77-3 CHEMICAL NAME ETHANOL, 2-(2-BUTOXYETHOXY)- 5-10 COMMON NAME : DIETHYLENE GLYCOL MONOBUTYL ETHER CAS NUMBER: 112-34—5 CHEMICAL NAME TITANIUM OXIDE 20-30 COMMON NAME : TITANIUM DIOXIDE CAS NUMBER: 13463-67—7 CHEMICAL NAME WATER 40-50 COMMON NAME : WATER CAS NUMBER: 7732-18—5 SECTION 3: HAZARDS IDENTIFICATION PRIMARY ROUTE(S) OF EXPOSURE INHALATION, SKIN CONTACT, EYE CONTACT, INGESTION. EFFECTS OF OVEREXPOSURE INHALATION PROLONGED INHALATION MAY LEAD TO MUCOUS MEMBRANE IRRITATION, DIZZINESS AND/OR LIGHTHEADEDNESS, HEADACHE, NAUSEA, COUGHING CENTRAL NERVOUS SYSTEM DEPRESSION SKIN CONTACT IRRITATION OF SKIN. EYE CONTACT IRRITATION OF EYES. PROLONGED OR REPEATED CONTACT CAN CAUSE CONJUNCTIVITIS, TEARING OF EYES, REDNESS OF EYES. INGESTION INGESTION MAY CAUSE MOUTH AND THROAT IRRITATION, DROWSINESS, DIZZINESS AND/OR LIGHTHEADEDNESS, HEADACHE, UNCOORDINATION, NAUSEA, GASTRO-INTESTINAL DISTURBANCES, CENTRAL NERVOUS SYSTEM DEPRESSION, INTOXICATION, LIVER DAMAGE, KIDNEY DAMAGE, REPRODUCTIVE SYSTEM DAMAGE. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE EYE, SKIN, RESPIRATORY DISORDERS SECTION 4: FIRST-AID MEASURES INHALATION SKIN CONTACT REMOVE TO FRESH AIR. RESTORE AND SUPPORT CONTINUED BREATHING. GET EMERGENCY MEDICAL ATTENTION. HAVE TRAINED PERSON GIVE OXYGEN IF NECESSARY. GET MEDICAL HELP FOR ANY BREATHING DIFFICULTY. REMOVE TO FRESH AIR IF INHALATION CAUSES EYE WATERING, HEADACHES, DIZZINESS, OR OTHER DISCOMFORT. WASH THOROUGHLY WITH SOAP AND WATER. IF ANY PRODUCT REMAINS, GENTLY RUB PETROLEUM JELLY, VEGETABLE OR MINERAL/BABY OIL ONTO SKIN. REPEATED APPLICATIONS MAY BE NEEDED. REMOVE CONTAMINATED CLOTHING. 1/4 Page 43 of 1235 Page 43 of 1235 Page 43 of 1235 Page 43 of 1235 ---PAGE BREAK--- 4216.00100 DEVFLEX HP WHITE WASH CONTAMINATED CLOTHING BEFORE RE-USE. EYE CONTACT FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER, ESPECIALLY UNDER LIDS FOR AT LEAST 15 MINUTES. IF IRRITATION OR OTHER EFFECTS PERSIST, OBTAIN MEDICAL TREATMENT. INGESTION IF SWALLOWED, OBTAIN MEDICAL TREATMENT IMMEDIATELY. SECTION 5: FIRE-FIGHTING MEASURES FLASH POINT (SETA) NONE LOWER EXPLOSIVE LIMIT NOT AVAILABLE UPPER EXPLOSIVE LIMIT 22.0 FIRE EXTINGUISHING MEDIA DRY CHEMICAL OR FOAM WATER FOG. CARBON DIOXIDE. UNUSUAL FIRE AND EXPLOSION HAZARDS CLOSED CONTAINERS MAY BURST IF EXPOSED TO EXTREME HEAT OR FIRE. FIRE FIGHTING PROCEDURES WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS. FIREFIGHTERS SHOULD USE FULL PROTECTIVE CLOTHING, EYE PROTECTION, AND SELF-CONTAINED BREATHING APPARATUS. HAZARDOUS DECOMPOSITION OR COMBUSTION PRODUCTS CARBON MONOXIDE, CARBON DIOXIDE, ACRYLIC MONOMERS. SECTION 6 ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED COMPLY WITH ALL APPLICABLE HEALTH AND ENVIRONMENTAL REGULATIONS. ELIMINATE ALL SOURCES OF IGNITION. VENTILATE AREA. PLACE COLLECTED MATERIAL IN PROPER CONTAINER. SPILLED MATERIAL IS EXTREMELY SLIPPERY. COMPLETE PERSONAL PROTECTIVE EQUIPMENT MUST BE USED DURING CLEANUP. LARGE SPILLS - SHUT OFF LEAK IF SAFE TO DO SO. DIKE AND CONTAIN SPILL. PUMP TO STORAGE OR SALVAGE VESSELS. USE ABSORBENT TO PICK UP EXCESS RESIDUE. KEEP SALVAGEABLE MATERIAL AND RINSE WATER OUT OF SEWERS AND WATER COURSES. SMALL SPILLS - USE ABSORBENT TO PICK UP RESIDUE AND DISPOSE OF PROPERLY. SECTION 7 HANDLING AND STORAGE HANDLING AND STORAGE STORE BELOW 100F (38C). KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. KEEP FROM FREEZING. KEEP CONTAINER CLOSED IN A WELL-VENTILATED AREA. OTHER PRECAUTIONS USE ONLY WITH ADEQUATE VENTILATION. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT WITH SKIN AND EYES, AND BREATHING OF VAPORS. WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY BEFORE EATING OR SMOKING. KEEP CONTAINERS CLOSED AND UPRIGHT WHEN NOT IN USE. EMPTY CONTAINERS MAY CONTAIN HAZARDOUS RESIDUES. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION COMMON NAME : TITANIUM DIOXIDE CAS NUMBER: 13463-67-7 ACGIH (TWA): 10 MG/M3 OSHA(TWA): 10 MG/M3 RESPIRATORY PROTECTION CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE EXPOSURE STANDARDS WHEN USING THIS MATERIAL. WHEN RESPIRATORY PROTECTION IS DETERMINED TO BE NECESSARY, USE A NIOSH/MSHA (CANADIAN Z94.4) APPROVED ELASTOMERIC SEALING SURFACE FACEPIECE RESPIRATOR OUTFITTED WITH ORGANIC VAPOR CARTRIDGES AND PAINT SPRAY (DUST/MIST) PREFILTERS. DETERMINE THE PROPER LEVEL OF PROTECTION BY CONDUCTING ) 2/4 Page 44 of 1235 Page 44 of 1235 Page 44 of 1235 Page 44 of 1235 ---PAGE BREAK--- 421 6.00100 DEVFLEX HP WHITE APPROPRIATE AIR MONITORING. CONSULT 29CFR1910.134 FOR SELECTION OF RESPIRATORS (CANADIAN Z94.4) VENTILATION PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT BUILD-UP OF VAPORS. PERSONAL PROTECTIVE EQUIPMENT EYE WASH, SAFETY SHOWER, SAFETY GLASSES OR GOGGLES. IMPERVIOUS GLOVES, IMPERVIOUS CLOTHING, FACE SHIELD. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES SECTION 10: STABILITY AND REACTIVITY UNDER NORMAL CONDITIONS STABLE SEE SECTION 5 FIRE FIGHTING MEASURES MATERIALS TO AVOID CONDITIONS TO AVOID HAZARDOUS POLYMERI ZAT ION WILL NOT OCCUR VAPOR PRESSURE: BOILING RANGE WOLATILE BY VOLUME: PHYSICAL STATE: SOLUBILITY IN WATER: NOT AVAILABLE SPECIFIC GRAVITY: 212-453/100—234 WEIGHT PER GALLON: 66.37 LIQUID APPEARANCE NOT AVAILABLE PH: 1.231 10.25/ 12.31IMP WHITE NOT AVAILABLE OXIDIZERS, ACIDS, BASES, ALKALIS, CAUSTICS. ELEVATED TEMPERATURES, CONTACT WITH OXIDIZING AGENT, FREEZING. SECTION 11: TOXICOLOGICAL INFORMATION COMMON NAME : DIETHYLENE GLYCOL MONOMETHYL ETHER CAS NUMBER: 111-77—3 CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO LD5O: 5500.00 MG/KG OWl RAT LD5O: 8222.00 MG/KG ORL MOU LD5O: 6540.00 MG/KG SKN RBT COMMON NAME : DIETHYLENE GLYCOL MONOBUTYL ETHER CAS NUMBER: 112-34—5 CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO LDSO: 5660.00 MG/KG ORL RAT LD5O: 2200.00 MG/KG SKN RBT COMMON NAME : TITANIUM DIOXIDE CAS NUMBER: 13463—67—7 CARCINOGENICITY LISTED BY: NTP YES 2B IARC YES 2B OSHA NO ACGIH NO LD5O: 24.00 GM/KG ORL RAT LC5O: 6820.00 MG/M3/4HR IHL RAT SUPPLEMENTAL HEALTH INFORMATION CONTAINS A CHEMICAL THAT MAY BE ABSORBED THROUGH SKIN. NOTICE - REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL. OTHER EFFECTS OF OVEREXPOSURE MAY INCLUDE TOXICITY TO LIVER, KIDNEY, BLOOD, REPRODUCTIVE SYSTEM. CARCINOGENICITY IN A LIFETIME INHALATION STUDY, EXPOSURE TO 250 MG/M3 TITANIUM DIOXIDE RESULTED IN THE DEVELOPMENT OF LUNG TUMORS IN RATS. THESE TUMORS OCCURRED ONLY AT DUST LEVELS THAT OVERWHELMED THE ANIMALS’ LUNG CLEARANCE MECHANISMS AND WERE DIFFERENT FROM COMMON HUMAN LUNG TUMORS IN BOTH TYPE AND LOCATION. THE RELEVANCE OF THESE FINDINGS TO HUMANS IS UNKNOWN BUT QUESTIONABLE. THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) HAS CLASSIFIED TITANIUM DIOXIDE AS POSSIBLY CARCINOGENIC TO HUMANS (GROUP 2B) BASED ON INADEQUATE EVIDENCE OF 3/4 Page 45 of 1235 Page 45 of 1235 Page 45 of 1235 Page 45 of 1235 ---PAGE BREAK--- 4216.00100 DEVFLEX HP WHITE CARCINOGENICITY IN HUMANS AND SUFFICIENT EVIDENCE OF CARCINOGENICITY IN EXPERIMENTAL ANIMALS. NO REPRODUCTIVE EFFECTS ARE ANTICIPATED NO MUTAGENIC EFFECTS ARE ANTICIPATED PROLONGED INGESTION OF DIETHYLENE GLYCOL MONOMETHYL ETHER HAS RESULTED IN FETAL DEVELOPMENT ABNORMALITIES IN RATS AND EFFECTS ON FERTILITY IN MICE. SECTION 12: ECOLOGICAL INFORMATION NO ECOLOGICAL TESTING HAS BEEN DONE BY ICI PAINTS ON THIS PRODUCT AS A WHOLE. SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS AVOID DISCHARGE TO NATURAL WATERS. SECTION 14: TRANSPORT INFORMATION PAINT PROTECT FROM FREEZING NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE SECTION 15: REGULATORY INFORMATION SARA SARA CERCLA 302 313 302.4 111-77-3 NO YES NO DIETHYLENE GLYCOL MONOMETHYL ETHER 112-34-5 NO YES NO YES NO DIETHYLENE GLYCOL MONOBUTYL ETHER AS OF THE DATE OF THIS MSDS, ALL OF THE COMPONENTS IN THIS PRODUCT ARE LISTED (OR ARE OTHERWISE EXEMPT FROM LISTING) ON THE TSCA INVENTORY. THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR (CONTROLLED PRODUCTS REGULATIONS) AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR. SECTION 16: OTHER INFORMATION THE INFORMATION CONTAINED HEREIN IS BASED ON DATA AVAILABLE AT THE TIME OF PREPARATION OF THIS DATA SHEET AND WHICH ICI PAINTS BELIEVES TO BE RELIABLE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA. ICI PAINTS SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS INFORMATION, OR OF ANY PRODUCT, METHOD OR APPARATUS MENTIONED AND YOU MUST MAKE YOUR OWN DETERMINATION OF ITS SUITABILITY AND COMPLETENESS FOR YOUR OWN USE, FOR THE PROTECTION OF THE ENVIRONMENT, AND THE HEALTH AND SAFETY OF YOUR EMPLOYEES AND USERS OF THIS MATERIAL. COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD 29CFR1910 .1200. REPRODUCTIVE EFFECTS MUTAGENICITY TERATOGENI C ITY DOT IMDG IATA TDG CAS NUMBER: COMMON NAME CAS NUMBER: COMMON NAME HAZ AIR POLLUTANT YES MARINE POLTNT NO ) 4/4 Page 46 of 1235 Page 46 of 1235 Page 46 of 1235 Page 46 of 1235 ---PAGE BREAK--- Page 47 of 1235 Page 47 of 1235 Page 47 of 1235 Page 47 of 1235 ---PAGE BREAK--- Page 48 of 1235 Page 48 of 1235 Page 48 of 1235 Page 48 of 1235 ---PAGE BREAK--- Page 49 of 1235 Page 49 of 1235 Page 49 of 1235 Page 49 of 1235 ---PAGE BREAK--- Page 50 of 1235 Page 50 of 1235 Page 50 of 1235 Page 50 of 1235 ---PAGE BREAK--- Material Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION Product Identification Product ID: 1C72302 Product Name: 450 Yellow Zone Marking Paint Product Use: Paint product. Print date: 09/Apr/2012 Revision Date: 04/Apr/2012 Company Identification The Valspar Corporation - Architectural Coatings Division 1191 Wheeling Road Wheeling, IL 60090 Manufacturer's Phone: 1-[PHONE REDACTED] 24-Hour Medical Emergency Phone: 1-[PHONE REDACTED] 2. HAZARDS IDENTIFICATION Primary Routes of Exposure: Inhalation Ingestion Skin absorption Eye Contact: • Moderate eye irritation Skin Contact: • Causes skin irritation. • Dermatitis • May cause defatting of the skin. Ingestion: • Irritation of the mouth, throat, and stomach. • Aspiration hazard if swallowed - can enter lungs and cause damage. Product ID: 1C72302 Page 1 / 9 Page 51 of 1235 Page 51 of 1235 Page 51 of 1235 Page 51 of 1235 ---PAGE BREAK--- Inhalation: • Causes respiratory tract irritation. • Harmful by inhalation. Target Organ and Other Health Effects: • Kidney injury may occur. • Causes headache, drowsiness or other effects to the central nervous system. • Liver injury may occur. This product contains ingredients that may contribute to the following potential chronic health effects: • Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. • Prolonged exposure over TLV may produce pneumoconiosis. • Chronic exposure may cause permanent damage of health. • Prolonged exposure to respirable quartz silica may cause delayed chronic injury (silicosis). Carcinogens: • Possible cancer hazard. Contains material which may cause cancer based on animal data. • Cancer hazard. Contains material which can cause cancer. 3. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS Ingredient Name CAS-No. Approx. Weight % Chemical Name MINERAL SPIRITS 64742-47-8 15 - 20 Petroleum distillates, hydrotreated light PROPRIETARY INERT 15 - 20 PROPRIETARY INERT TALC 14807-96-6 15 - 20 Talc (Mg3H2(SiO3)4) PROPRIETARY INERT 5 - 10 PROPRIETARY INERT NAPHTHA 64742-89-8 5 - 10 SOLVENT NAPHTHA, PETROLEUM, LIGHT ALIPH TITANIUM DIOXIDE 13463-67-7 5 - 10 Titanium dioxide STODDARD SOLVENT 8052-41-3 1 - 5 Stoddard solvent SILICA 14808-60-7 .1 - 1 QUARTZ (Si02) 100-41-4 .1 - 1 Ethyl benzene If this section is blank there are no hazardous components per OSHA guidelines. 4. FIRST AID MEASURES Eye Contact: Get medical attention, if develop or persist. Immediately flush eye(s) with plenty of water. Remove any contact lenses and open eyes wide apart. Skin Contact: Remove contaminated clothing and shoes. Wash off immediately with plenty of water for at least 15 minutes. Get medical attention, if develop or persist. Product ID: 1C72302 Page 2 / 9 Page 52 of 1235 Page 52 of 1235 Page 52 of 1235 Page 52 of 1235 ---PAGE BREAK--- Ingestion: Rinse mouth with water. Give one or two glasses of water. Only induce vomiting at the instruction of medical personnel. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If vomiting occurs, keep head lower than hips to prevent aspiration. Get medical attention immediately. Inhalation: Move injured person into fresh air and keep person calm under observation. Get medical attention immediately. Medical conditions aggravated by exposure: Any respiratory or skin condition. 5. FIRE FIGHTING MEASURES Flash point (Fahrenheit): 52 Flash point (Celsius): 11 Lower explosive limit 1 Upper explosive limit 7 Autoignition temperature: not determined Sensitivity to impact: no Sensitivity to static discharge: Subject to static discharge hazards. Please see bonding and grounding information in Section 7. Hazardous combustion products: See Section 10. Unusual fire and explosion hazards: Contaminated rags, wipes, saw dust, etc., may catch fire spontaneously. Store waste under water in closed metal containers or in approved self-closing containers designed to prevent spontaneous combustion until disposed of in compliance with applicable regulations. Oxidizing Material Extinguishing media: Carbon dioxide, dry chemical, foam and/or water fog. Fire fighting procedures: Firefighters should be equipped with self-contained breathing apparatus and turn out gear. Keep containers and surroundings cool with water spray. 6. ACCIDENTAL RELEASE MEASURES Action to be taken if material is released or spilled: Ventilate the area. Avoid breathing dust or vapor. Use self-containing breathing apparatus or airmask for large spills in a confined area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 7, "Handling and Storage", for proper container and storage procedures. Remove all sources of ignition. Soak up with inert absorbent material. Use only non-sparking tools. Avoid contact with eyes. 7. HANDLING AND STORAGE Precautions to be taken in handling and storage: Keep away from heat, sparks and open flame. - No smoking. Keep container closed when not in use. Do not store above 120 degrees F. (49 degrees Based on flash point and vapor pressure, suitable storage should be provided in accordance with OSHA regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty containers may contain product residue, including flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must be observed until the container has been commercially cleaned or reconditioned. If the product is used near or above the flashpoint, an ignition hazard may be present. Activities, uses, or operations which liberate vapor (such as mixing or free fall of liquids) may also present an ignition hazard. Please ensure containers and other interconnected equipment are properly bonded and grounded at all times. 8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS Personal Protective Equipment Product ID: 1C72302 Page 3 / 9 Page 53 of 1235 Page 53 of 1235 Page 53 of 1235 Page 53 of 1235 ---PAGE BREAK--- Eye and face protection: Wear safety glasses or goggles to protect against exposure. Skin protection: Appropriate chemical resistant gloves should be worn. Other Personel Protection Data: To prevent skin contact wear protective clothing covering all exposed areas. Respiratory protection: If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an air purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's literature to ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's instructions. Ventilation Use only in well-ventilated areas. Ensure adequate ventilation, especially in confined areas. Ovens used for curing should contain a fresh air purge to prevent vapours from accumulating and creating a possible explosive mixture. Where the product is used in a hazardous classified area, use explosion-proof electrical/ventilating/lighting/equipment. Exposure Guidelines OSHA Permissible Exposure Limits (PEL's) Ingredient Name CAS-No. Approx. Weight % TWA (final) Ceilings limits (final) Skin designations PROPRIETARY INERT 15 - 20 15 mg/m3 TWA dust total 5 mg/m3 TWA respirable fraction TALC 14807-96-6 15 - 20 Respirable. Listed. Total dust. Listed. PROPRIETARY INERT 5 - 10 15 mg/m3 TWA dust total 5 mg/m3 TWA respirable fraction TITANIUM DIOXIDE 13463-67-7 5 - 10 15 mg/m3 TWA dust total STODDARD SOLVENT 8052-41-3 1 - 5 2900 mg/m3 TWA 500 ppm TWA SILICA 14808-60-7 .1 - 1 (30)/(%SiO2 + 2) mg/m3 TWA, total dust (250)/(%SiO2 + 5) TWA, respirable fraction (10)/(%SiO2 + 2) mg/m3 TWA, respirable fraction 100-41-4 .1 - 1 100 ppm TWA 435 mg/m3 TWA ACGIH Threshold Limit Value (TLV's) Ingredient Name CAS-No. Approx. Weight % TWA STEL Ceiling limits Skin designations PROPRIETARY INERT 15 - 20 10 mg/m3 Inhalable particles. 3 mg/m3 Respirable particles. Product ID: 1C72302 Page 4 / 9 Page 54 of 1235 Page 54 of 1235 Page 54 of 1235 Page 54 of 1235 ---PAGE BREAK--- Ingredient Name CAS-No. Approx. Weight % TWA STEL Ceiling limits Skin designations TALC 14807-96-6 15 - 20 2 mg/m3 TWA respirable fraction, particulate matter containing no asbestos and silica PROPRIETARY INERT 5 - 10 2 mg/m3 TWA respirable fraction, particulate matter containing no asbestos and silica TITANIUM DIOXIDE 13463-67-7 5 - 10 10 mg/m3 TWA STODDARD SOLVENT 8052-41-3 1 - 5 100 ppm TWA SILICA 14808-60-7 .1 - 1 0.025 mg/m3 TWA respirable fraction 100-41-4 .1 - 1 100 ppm TWA 125 ppm STEL 9. PHYSICAL PROPERTIES Odor: Normal for this product type. Physical State: liquid pH: not determined Vapor pressure: 103 mmHg @ 100ºF (37.78ºC) Vapor density (air = 1.0): 5.1 Boiling point: not determined Solubility in water: not determined Coefficient of water/oil distribution: not determined Density (lbs per US gallon): 11.14 Specific Gravity: 1.33 Evaporation rate (butyl acetate = 1.0): 1.4 Flash point (Fahrenheit): 52 Flash point (Celsius): 11 Lower explosive limit 1 Upper explosive limit 7 Autoignition temperature: not determined 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions. Conditions to Avoid: Heat. Incompatibility: Strong oxidizing agents Hazardous Polymerization: None anticipated. Hazardous Decomposition Products: Silicon dioxide. Carbon monoxide and carbon dioxide. Metal oxide fumes. Sensitivity to static discharge: Subject to static discharge hazards. Please see bonding and grounding information in Section 7. Product ID: 1C72302 Page 5 / 9 Page 55 of 1235 Page 55 of 1235 Page 55 of 1235 Page 55 of 1235 ---PAGE BREAK--- 11. TOXICOLOGICAL INFORMATION Ingredient Name CAS-No. Approx. Weight % NIOSH - Selected LD50s and LC50s MINERAL SPIRITS 64742-47-8 15 - 20 > 2000 mg/kg Dermal LD50 Rabbit > 5.2 mg/L Inhalation LC50 Rat 4 h > 5000 mg/kg Oral LD50 Rat NAPHTHA 64742-89-8 5 - 10 = 3000 mg/kg Dermal LD50 Rabbit = 5000 mg/kg Oral LD50 Mouse TITANIUM DIOXIDE 13463-67-7 5 - 10 > 10000 mg/kg Oral LD50 Rat SILICA 14808-60-7 .1 - 1 = 500 mg/kg Oral LD50 Rat 100-41-4 .1 - 1 = 15354 mg/kg Dermal LD50 Rabbit = 17.2 mg/L Inhalation LC50 Rat 4 h = 3500 mg/kg Oral LD50 Rat Mutagens/Teratogens/Carcinogens: Possible cancer hazard. Contains material which may cause cancer based on animal data. Cancer hazard. Contains material which can cause cancer. Contains which has been determined by NTP to be an animal carcinogen with no known relevance to humans. IARC has classified as possibly carcinogenic to humans (2b) on the basis of sufficient evidence of carcinogenicity in laboratory animals but inadequate evidence of cancer in humans. Contains TIO2 which is listed by IARC as a possible human carcinogen (Group 2B) based on animal data. Neither long term animal studies, nor human epidemiology studies of workers exposed to TIO2 provide an adequate basis to conclude TIO2 is carcinogenic. TIO2 is not classified as a carcinogen by NTP, U.S. OSHA, or the U.S. EPA. Contains silica. The IARC has determined that silica inhaled in the form of quartz or cristobablite from occupational sources is carcinogenic to humans (group Refer to IARC monograph 68 in conjunction with the use of these materials. Risk of cancer depends on the duration and level of exposure. In coatings products, risk is due primarily to inhalation of sanding dusts or respirable particles in spray mists. The NTP has also determined that silica is a known human carcinogen in the form of fine, breathable particles. Risk of cancer depends on duration and level of exposure in coatings products, risk is due primarily to inhalation of sanding dust or respirable particles in spray mist. Ingredient Name CAS-No. Approx. Weight % California Prop 65 - Reproductive (Female) California Prop 65 - Carcinogen SILICA 14808-60-7 .1 - 1 Listed. initial date 10/1/88 - carcinogen 100-41-4 .1 - 1 Listed. initial date 6/11/04 - carcinogen Ingredient Name CAS-No. Approx. Weight % IARC Group 1 - Human Evidence IARC Group 2A - Limited Human Data IARC Group 2B - Sufficient Animal Data TITANIUM DIOXIDE 13463-67-7 5 - 10 Monograph 47 [1989] SILICA 14808-60-7 .1 - 1 Monograph 68 [1997] 100-41-4 .1 - 1 Monograph 77 [2000] Product ID: 1C72302 Page 6 / 9 Page 56 of 1235 Page 56 of 1235 Page 56 of 1235 Page 56 of 1235 ---PAGE BREAK--- Ingredient Name CAS-No. Approx. Weight % NTP Known Carcinogens NTP Suspect Carcinogens NTP Evidence of Carcinogenicity TALC 14807-96-6 15 - 20 male rat-some evidence; female rat-clear evidence; male mice-no evidence; female mice- no evidence TITANIUM DIOXIDE 13463-67-7 5 - 10 male rat-negative; female rat-negative; male mice-negative; female mice-negative SILICA 14808-60-7 .1 - 1 Known Human Carcinogen 100-41-4 .1 - 1 male rat-clear evidence; female rat-some evidence; male mice- some evidence; female mice-some evidence Ingredient Name CAS-No. Approx. Weight % OSHA - Hazard Communication Carcinogens OSHA - Specifically Regulated Carcinogens ACGIH Carcinogens TITANIUM DIOXIDE 13463-67-7 5 - 10 Present SILICA 14808-60-7 .1 - 1 Present A2 Suspected Human Carcinogen 100-41-4 .1 - 1 Present A3 Confirmed Animal Carcinogen with Unknown Relevance to Humans 12. ECOLOGICAL DATA No information on ecology is available. 13. DISPOSAL CONSIDERATIONS Disposal should be made in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION U.S. Department of Transportation UN ID Number (msds): UN1263 Proper Shipping Name: PAINT Hazard Class: 3 Packing Group: II U.S Hazmat and/or International DG shipment exceptions The supplier may apply one of the following exceptions: Combustible Liquid, Consumer Commodity, Limited Quantity, Viscous Liquid, Does Not Sustain Combustion, or others, as allowed under 49CFR Hazmat Regulations. Please consult 49CFR Subchapter C to ensure that subsequent shipments comply with these exceptions. Reportable Quantity Description: International Air Transport Association (IATA): UN ID Number (msds): UN1263 Proper Shipping Name: Paint Product ID: 1C72302 Page 7 / 9 Page 57 of 1235 Page 57 of 1235 Page 57 of 1235 Page 57 of 1235 ---PAGE BREAK--- Hazard Class: 3 Packing Group: II International Maritime Organization (IMO): IMO UN/ID Number (msds): UN1263 Proper Shipping Name: PAINT Hazard Class: 3 Packing Group: II 15. REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: Ingredient Name CAS-No. Approx. Weight % SARA 302 SARA 313 CERCLA RQ in lbs. 100-41-4 .1 - 1 form R reporting required for 1.0% de minimis concentration 1000 SARA 311/312 Hazard Class: Acute: yes Chronic: yes Flammability: yes Reactivity: no Sudden Pressure: no U.S. STATE REGULATIONS: Right to Know: The specific chemical identity of a component may be withheld as a trade secret under 34 Code, Chapter 317. Right To Know: PROPRIETARY INERT Trade Secret PROPRIETARY INERT Trade Secret TITANIUM DIOXIDE 13463-67-7 TALC 14807-96-6 MINERAL SPIRITS 64742-47-8 NAPHTHA 64742-89-8 STODDARD SOLVENT 8052-41-3 Additional Non-Hazardous Materials PROPRIETARY RESIN Trade Secret California Proposition 65: WARNING: This product contains chemicals known to the State of California to cause cancer. Rule 66 status of product Not photochemically reactive. INTERNATIONAL REGULATIONS - Chemical Inventories US TSCA Inventory: All components of this product are in compliance with U.S. TSCA Chemical Substance Inventory Requirements. Canada Domestic Substances List: All components of this product are listed on the Domestic Substances List. Product ID: 1C72302 Page 8 / 9 Page 58 of 1235 Page 58 of 1235 Page 58 of 1235 Page 58 of 1235 ---PAGE BREAK--- 16. OTHER INFORMATION HMIS Codes Health: 2* Flammability: 3 Reactivity: 1 PPE: X - See Section 8 for Personal Protective Equipment (PPE). Abbreviations: OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer, NIOSH - National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH - American Conference of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management District, TSCA - Toxic Substances Control Act, IATA - International Air Transport Association, IMO - International Maritime Organization, DOT - Department of Transportation, NA - Not applicable, NOT ESTAB - Not established, N.A.V. - Not available, RQ - Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams per liter, MM - Millimeters, - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per thousand, TCC/PM - Tag closed cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time Weighted Average, STEL - Short term exposure limit, C - Celsius, F - Fahrenheit. Disclaimer: The data on this sheet represent typical values. Since application variables are a major factor in product performance, this information should serve only as a general guide. Valspar assumes no obligation or liability for use of this information. UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES, EXPRESS OR IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. VALSPAR WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only remedy for any defect in this product is the replacement of the defective product, or a refund of its purchase price, at our option. This MSDS contains additional information required by the state of Preparation Information: Prepared By: Regulatory Affairs Department Print date: 09/Apr/2012 Revision Date: 04/Apr/2012 Product ID: 1C72302 Page 9 / 9 Page 59 of 1235 Page 59 of 1235 Page 59 of 1235 Page 59 of 1235 ---PAGE BREAK--- Page 60 of 1235 Page 60 of 1235 Page 60 of 1235 Page 60 of 1235 ---PAGE BREAK--- RUST-OLEUM 5FW88 GLOSS BLACK 9702833 Revised: 5/5/1998 MSDS Contents SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS SECTION 3 - HAZARDS IDENTIFICATION SECTION 4 - FIRST AID MEASURES SECTION 5 - FIRE FIGHTING MEASURES SECTION 6 - ACCIDENTAL RELEASE MEASURES SECTION 7 - HANDLING AND STORAGE SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES SECTION 10 - STABILITY AND REACTIVITY SECTION 11 - TOXICOLOGICAL PROPERTIES SECTION 12 - ECOLOGICAL INFORMATION SECTION 13 - DISPOSAL CONSIDERATIONS SECTION 14 - TRANSPORTATION INFORMATION SECTION 15 - REGULATORY INFORMATION SECTION 16 - OTHER INFORMATION Item Number: 6KP58, 5FW88 Mfg. Model Number: V2602-402, V2602-830 MATERIAL SAFETY DATA SHEET SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 5FW88 GLOSS BLACK 9702833 IDENTIFICATION NUMBER: V2602 830 DATE PRINTED: 07/21/98 PRODUCT USE/CLASS: DEM-KOTE VOC AEROSOL SUPPLIER: RUST-OLEUM CORPORATION 11 HAWTHORN PARKWAY VERNON HILLS, ILLINOIS 60061 USA (847) 367-7700 RUST-OLEUM CORP. MON.-FRI, 8:00 AM-4:30 PM MANUFACTURER: RUST-OLEUM CORPORATION 11 HAWTHORN PARKWAY VERNON HILLS, ILLINOIS 60061 USA (847) 367-7700 RUST-OLEUM CORP. MON.-FRI, 8:00 AM-4:30 PM Page 61 of 1235 Page 61 of 1235 Page 61 of 1235 Page 61 of 1235 ---PAGE BREAK--- PREPARER: LDW PHONE: PREPARE DATE: 05/05/98 SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS WT/WT % ITEM CHEMICAL NAME CAS NUMBER LESS THAN 01 ACETONE 67-64-1 30.0 % 02 LIQUIFIED PETROLEUM GAS 68476-85-7 25.0 % 03 COPOLYMER RESIN SOLUTION PROPRIETARY 20.0 % 04 XYLENE 1330-20-7 15.0 % 05 100-41-4 5.0 % 06 VM&P NAPHTHA(PETROLEUM DISTILLATES) 8032-32-4 5.0 % 07 AROMATIC SOLVENT 64742-95-6 5.0 % 08 CARBON BLACK 1333-86-4 5.0 % EXPOSURE LIMITS ACGIH OSHA MEXICAN ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN 01 750 PPM 1000 PPM 750 PPM N.E. N.E. NO 02 1000 PPM N.E. 1000 PPM N.E. N.E. NO 03 N.E. N.E. N.E. N.E. N.E. NO 04 100PPM 150PPM 100PPM N.E. N.E. NO 05 100 PPM 125 PPM 100 PPM N.E. N.E. NO 06 300 PPM N.E. 300 PPM N.E. N.E. NO 07 N.E. N.E. N.E. N.E. N.E. NO 08 3.5 MG/M3 N.E. 3.5 MG/M3 N.E. N.E. NO (SEE SECTION 16 FOR ABBREVIATION LEGEND) Page 62 of 1235 Page 62 of 1235 Page 62 of 1235 Page 62 of 1235 ---PAGE BREAK--- SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: HARMFUL IF INHALED. HARMFUL IF SWALLOWED. EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPORS MAY CAUSE FLASH FIRE OR EXPLOSION. EFFECTS OF OVEREXPOSURE - EYE CONTACT: CAUSES EYE IRRITATION. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: SUBSTANCE MAY CAUSE SLIGHT SKIN IRRITATION. PROLONGED OR REPEATED CONTACT MAY CAUSE SKIN IRRITATION. EFFECTS OF OVEREXPOSURE - INHALATION: HARMFUL IF INHALED. HIGH GAS, VAPOR, MIST OR DUST CONCENTRATIONS MAY BE HARMFUL IF INHALED. AVOID BREATHING VAPORS OR MISTS. HIGH VAPOR CONCENTRATIONS ARE IRRITATING TO THE EYES, NOSE, THROAT AND LUNGS. EFFECTS OF OVEREXPOSURE - INGESTION: SUBSTANCE MAY BE HARMFUL IF SWALLOWED. ASPIRATION HAZARD IF SWALLOWED; CAN ENTER LUNGS AND CAUSE DAMAGE. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: MAY CAUSE CENTRAL NERVOUS SYSTEM DISORDER (E,G.,NARCOSIS INVOLVING A LOSS OF COORDINATION, WEAKNESS, FATIGUE, MENTAL CONFUSION, AND BLURRED VISION) AND/OR DAMAGE. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. OVEREXPOSURE TO XYLENE IN LABORATORY ANIMALS HAS BEEN ASSOCIATED WITH LIVER ABNORMALITIES, KIDNEY, LUNG, SPLEEN AND EYE DAMAGE AS WELL AS ANEMIA. EFFECTS IN HUMANS HAVE INCLUDED LIVER AND CARDIAC ABNORMALITIES. CONTAINS CARBON BLACK. CHRONIC INFLAMMATION, LUNG FIBROSIS, AND LUNG TUMORS HAVE BEEN OBSERVED IN SOME RATS EXPERIMENTALLY EXPOSED FOR LONG PERIODS OF TIME TO EXCESSIVE CONCENTRATIONS OF CARBON BLACK AND SEVERAL INSOLUBLE FINE DUST PARTICLES. TUMORS HAVE NOT BEEN OBSERVED IN OTHER ANIMAL SPECIES MOUSE AND HAMSTER) UNDER SIMILAR CIRCUMSTANCES AND STUDY CONDITIONS. EPIDEMIOLOGICAL STUDIES OF NORTH AMERICAN WORKERS SHOW NO EVIDENCE OF CLINICALLY SIGNIFICANT ADVERSE HEALTH EFFECTS DUE TO OCCUPATIONAL EXPOSURE TO CARBON BLACK. CARBON BLACK IS LISTED AS A GROUP 2B- "POSSIBLY CARCINOGENIC TO HUMANS" BY IARC AND IS PROPOSED TO BE LISTED AS A4- "NOT CLASSIFIED AS A HUMAN CARCINOGEN" BY THE AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS. SIGNIFICANT EXPOSURE IS NOT ANTICIPATED DURING BRUSH APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND LEVEL OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST AND THE ACTUAL CONCENTRATION OF CARBON BLACK IN THE FORMULA. PRIMARY ROUTE(S) OF ENTRY: SKIN ABSORPTION, INHALATION, EYE CONTACT. Page 63 of 1235 Page 63 of 1235 Page 63 of 1235 Page 63 of 1235 ---PAGE BREAK--- SECTION 4 - FIRST AID MEASURES FIRST AID - EYE CONTACT: HOLD EYELIDS APART AND FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. FIRST AID - SKIN CONTACT: WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS OR PERSISTS. FIRST AID - INHALATION: IF YOU EXPERIENCE DIFFICULTY IN BREATHING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS EXPERIENCED, GET MEDICAL ASSISTANCE IMMEDIATELY. FIRST AID - INGESTION: ASPIRATION HAZARD: DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH BECAUSE THIS MATERIAL CAN ENTER THE LUNGS AND CAUSE SEVERE LUNG DAMAGE. GET IMMEDIATE MEDICAL ATTENTION. SECTION 5 - FIRE FIGHTING MEASURES FLASH POINT: * F LOWER EXPLOSIVE LIMIT: 0.9 % UPPER EXPLOSIVE LIMIT: 12.8 % AUTOIGNITION TEMPERATURE: ND EXTINGUISHING MEDIA: DRY CHEMICAL, FOAM, WATER FOG. UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20 DEG. F. - EXTREMELY FLAMMABLE LIQUID AND VAPOR! WATER SPRAY MAY BE INEFFECTIVE. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT DUE TO BUILDUP OF STEAM. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR. VAPORS CAN TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK. KEEP CONTAINERS CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND OPEN FLAME. PERFORATION OF THE PRESSURIZED CONTAINER MAY CAUSE BURSTING OF THE CAN. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. SPECIAL FIREFIGHTING PROCEDURES: Page 64 of 1235 Page 64 of 1235 Page 64 of 1235 Page 64 of 1235 ---PAGE BREAK--- EVACUATE AREA AND FIGHT FIRE FROM A SAFE DISTANCE. SECTION 6 - ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: EVACUATE THE AREA, REMOVE ALL SOURCES OF IGNITION AND VENTILATE WELL. CONTAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE MATERIALS SUCH AS SAWDUST. REMOVE ALL SOURCES OF IGNITION, VENTILATE AREA AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. DISPOSE OF ACCORDING TO LOCAL, STATE (PROVINCIAL) AND FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS. SECTION 7 - HANDLING AND STORAGE HANDLING: WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. USE ONLY IN A WELL- VENTILATED AREA. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID BREATHING VAPOR OR MIST. STORAGE: KEEP CONTAINERS CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND OPEN FLAME. DO NOT STORE ABOVE 120 DEGREES F. STORE LARGE QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF NFPA CLASS I FLAMMABLE LIQUIDS. CONTENTS UNDER PRESSURE. DO NOT EXPOSE TO HEAT OR STORE ABOVE 120 DEGREES F. SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. USE EXPLOSION- PROOF VENTILATION EQUIPMENT. PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE CROSS-VENTILATION. RESPIRATORY PROTECTION: A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR WITH AN Page 65 of 1235 Page 65 of 1235 Page 65 of 1235 Page 65 of 1235 ---PAGE BREAK--- ORGANIC VAPOR CARTRIDGE OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED EXPOSURE LIMITS. PROTECTION PROVIDED BY AIR PURIFYING RESPIRATORS IS LIMITED. USE A POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR AN UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE NOT KNOWN, OR ANY OTHER CIRCUMSTANCES WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE PROTECTION. SKIN PROTECTION: USE IMPERVIOUS GLOVES TO PREVENT SKIN CONTACT AND ABSORPTION OF THIS MATERIAL THROUGH THE SKIN. NITRILE OR NEOPRENE GLOVES MAY AFFORD ADEQUATE SKIN PROTECTION. EYE PROTECTION: USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS. OTHER PROTECTIVE EQUIPMENT: REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER INFORMATION REGARDING PERSONAL PROTECTIVE EQUIPMENT AND ITS APPLICATION. HYGIENIC PRACTICES: WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES BOILING RANGE: -34 - 338 F VAPOR DENSITY: IS HEAVIER THAN AIR ODOR: SOLVENT ODOR THRESHOLD: ND APPEARANCE: LIQUID EVAPORATION RATE: IS SLOWER THAN ETHER SOLUBILITY IN H2O: SLIGHT FREEZE POINT: ND SPECIFIC GRAVITY: 0.895 VAPOR PRESSURE: ND PH @ 0.0 ND PHYSICAL STATE: LIQUID Page 66 of 1235 Page 66 of 1235 Page 66 of 1235 Page 66 of 1235 ---PAGE BREAK--- VISCOSITY: ND COEFFICIENT OF WATER/OIL DISTRIBUTION: ND' (SEE SECTION 16 FOR ABBREVIATION LEGEND) SECTION 10 - STABILITY AND REACTIVITY CONDITIONS TO AVOID: AVOID TEMPERATURES ABOVE 120 DEGREES F. AVOID ALL POSSIBLE SOURCES OF IGNITION. INCOMPATIBILITY: INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG ALKALIES. HAZARDOUS DECOMPOSITION PRODUCTS: BY OPEN FLAME, CARBON MONOXIDE AND CARBON DIOXIDE. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS. STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS. SECTION 11 - TOXICOLOGICAL PROPERTIES COMPONENT TOXICOLOGICAL INFORMATION: CHEMICAL NAME LD50 LC50 ACETONE RAT 5800MG/KG RAT 50100MG/M3 8H LIQUIFIED PETROLEUM GAS N.E N.E. COPOLYMER RESIN SOLUTION 4300MG/KG RAT 5000 PPM 4HR XYLENE RAT 4300MG/KG RAT 5000 PPM 4HR RAT 3500MG/KG N.A. VM&P NAPHTHA(PETROLEUM DISTILLATES) N.D. N.D. AROMATIC SOLVENT 4900MG/KG(RAT) N.E. CARBON BLACK N.A. N.A. Page 67 of 1235 Page 67 of 1235 Page 67 of 1235 Page 67 of 1235 ---PAGE BREAK--- SECTION 12 - ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: PRODUCT IS A MIXTURE OF LISTED COMPONENTS. SECTION 13 - DISPOSAL CONSIDERATIONS DISPOSAL METHOD: DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE AND FEDERAL REGULATIONS AND ORDINANCES. DO NOT ALLOW TO ENTER STORM DRAINS OR SEWER SYSTEMS. SECTION 14 - TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME: AEROSOLS DOT TECHNICAL NAME: DOT HAZARD CLASS: 2 HAZARD SUBCLASS: 1 DOT UN/NA NUMBER: UN1950 PACKING GROUP: RESP. GUIDE PAGE: 126 SECTION 15 - REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: AS FOLLOWS - OSHA: HAZARDOUS BY DEFINITION OF HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) CERCLA - SARA HAZARD CATEGORY: Page 68 of 1235 Page 68 of 1235 Page 68 of 1235 Page 68 of 1235 ---PAGE BREAK--- THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES' PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES: IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD SARA SECTION 313: THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372: CHEMICAL NAME CAS NUMBER WT/WT % IS LESS THAN XYLENE 1330-20-7 15.0 % 100-41-4 5.0 % TOXIC SUBSTANCES CONTROL ACT: THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES: CHEMICAL NAME CAS NUMBER NO INFORMATION IS AVAILABLE. U.S. STATE REGULATIONS: AS FOLLOWS - NEW JERSEY RIGHT-TO-KNOW: THE FOLLOWING MATERIALS ARE NON-HAZARDOUS, BUT ARE AMONG THE TOP FIVE COMPONENTS IN THIS PRODUCT: CHEMICAL NAME CAS NUMBER NO NON-HAZARDOUS MATERIALS ARE AMONG THE TOP FIVE INGREDIENTS RIGHT-TO-KNOW: THE FOLLOWING NON-HAZARDOUS INGREDIENTS ARE PRESENT IN THE PRODUCT AT GREATER THAN CHEMICAL NAME CAS NUMBER NO NON-HAZARDOUS INGREDIENTS ARE PRESENT AT GREATER THAN 3% CALIFORNIA PROPOSITION 65: WARNING: THE CHEMICAL(S) NOTED BELOW AND CONTAINED IN THIS PRODUCT, ARE KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM: CHEMICAL NAME CAS NUMBER Page 69 of 1235 Page 69 of 1235 Page 69 of 1235 Page 69 of 1235 ---PAGE BREAK--- TOLUENE 108-88-3 INTERNATIONAL REGULATIONS: AS FOLLOWS - CANADIAN WHMIS: THIS MSDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT REGULATIONS EXCEPT FOR USE OF THE 16 HEADINGS. CANADIAN WHMIS CLASS: NO INFORMATION AVAILABLE SECTION 16 - OTHER INFORMATION HMIS RATINGS: HEALTH: FLAMMABILITY: REACTIVITY: PREVIOUS MSDS REVISION DATE: 01/05/98 REASON FOR REVISION: TRANSPORTATION INFORMATION LEGEND: N.A. - NOT APPLICABLE N.E. - NOT ESTABLISHED, N.D. - NOT DETERMINED, NO INFORMATION. THE INFORMATION CONTAINED ON THIS MSDS HAS BEEN CHECKED AND SHOULD BE ACCURATE. HOWEVER, IT IS THE RESPONSIBILITY OF THE USER TO COMPLY WITH ALL FEDERAL, STATE, AND LOCAL LAWS AND REGULATIONS. Page 70 of 1235 Page 70 of 1235 Page 70 of 1235 Page 70 of 1235 ---PAGE BREAK--- ¦ M A T E R I A L S A F E T Y D A T A S H E E T ¦ ¦ SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ¦ PRODUCT NAME : 5FW93 GLOSS RED 9702838 IDENTIFICATION NUMBER: V2607 830 DATE PRINTED : 10/23/97 PRODUCT USE/CLASS : DEM-KOTE VOC AEROSOL SUPPLIER: MANUFACTURER: Rust-Oleum Corporation Rust-Oleum Corporation 11 Hawthorn Parkway 11 Hawthorn Parkway Vernon Hills, Illinois Vernon Hills, Illinois 60061 USA 60061 USA (847) 367-7700 Rust-Oleum Corp. (847) 367-7700 Rust-Oleum Corp. Mon.-Fri, 8:00 AM-4:30 PM Mon.-Fri, 8:00 AM-4:30 PM PREPARER: LJW, PHONE: , PREPARE DATE: 06/11/97 ¦ SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS ¦ WT/WT % ITEM CHEMICAL NAME CAS NUMBER LESS THAN 01 ACETONE 67-64-1 35.0 % 02 PROPANE 74-98-6 20.0 % 03 COPOLYMER RESIN SOLUTION MIXTURE 20.0 % 04 XYLENE 1330-20-7 15.0 % 05 N-BUTANE 106-97-8 5.0 % 06 100-41-4 5.0 % 07 VM&P NAPHTHA(PETROLEUM DISTILLATES) 8032-32-4 5.0 % 08 ISOBUTANE 75-28-5 5.0 % 09 AROMATIC SOLVENT 64742-95-6 5.0 % EXPOSURE LIMITS ACGIH OSHA COMPANY ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN 01 750 PPM 1000 PPM 750 PPM N.E. N.E. NO 02 N.E. 1000 PPM N.E. N.E. YES 03 N.E. N.E. N.E. N.E. N.E. NO 04 100PPM 150PPM 100PPM N.E. N.E. NO 05 800 PPM N.E. N.E. N.E. N.E. NO 06 100 PPM 125 PPM 100 PPM N.E. N.E. NO 07 300 PPM N.E. 300 ppm N.E. N.E. NO 08 N.E. N.E. N.E. N.E. N.E. NO (Continued on Page 2) Page 71 of 1235 Page 71 of 1235 Page 71 of 1235 Page 71 of 1235 ---PAGE BREAK--- Product: V2607 830 Preparation Date: 06/11/97 Page 2 ¦ SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS ¦ EXPOSURE LIMITS ACGIH OSHA COMPANY ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN 09 N.E. N.E. N.E. N.E. 50 PPM NO (See Section 16 for abbreviation legend) ¦ SECTION 3 - HAZARDS IDENTIFICATION ¦ EMERGENCY OVERVIEW Harmful if inhaled. Harmful if swallowed. Extremely flammable liquid and vapor. Vapors may cause flash fire or explosion. EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin irritation. Prolonged or repeated contact may cause skin irritation. EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing vapors or mists. High vapor concentrations are irritating to the eyes, nose, throat and lungs. EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed. Aspiration hazard if swallowed; can enter lungs and cause damage. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: May cause central nervous system disorder (e,g.,narcosis involving a loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen and eye damage as well as anemia. Effects in humans have included liver and cardiac abnormalities. PRIMARY ROUTE(S) OF ENTRY: INHALATION EYE CONTACT ¦ SECTION 4 - FIRST AID MEASURES ¦ FIRST AID - EYE CONTACT: Hold eyelids apart and flush with plenty of water for at lease 15 minutes. Get medical attention. FIRST AID - SKIN CONTACT: Wash with soap and water. Get medical attention if irritation develops or persists. (Continued on Page 3) Page 72 of 1235 Page 72 of 1235 Page 72 of 1235 Page 72 of 1235 ---PAGE BREAK--- Product: V2607 830 Preparation Date: 06/11/97 Page 3 ¦ SECTION 4 - FIRST AID MEASURES ¦ FIRST AID - INHALATION: No Information. FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. ¦ SECTION 5 - FIRE FIGHTING MEASURES ¦ FLASH POINT: 15 F LOWER EXPLOSIVE LIMIT: 0.9 % UPPER EXPLOSIVE LIMIT: 12.8 % AUTOIGNITION TEMPERATURE: ND EXTINGUISHING MEDIA: DRY CHEMICAL FOAM WATER FOG UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20 DEG. F. - EXTREMELY FLAMMABLE LIQUID AND VAPOR! Water spray may be ineffective. Closed containers may explode when exposed to extreme heat due to buildup of steam. Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a source of ignition and flash back. Keep containers closed. Isolate from heat, electrical equipment, sparks and open flame. Perforation of the pressurized container may cause bursting of the can. Closed containers may explode when exposed to extreme heat. SPECIAL FIREFIGHTING PROCEDURES: Evacuate area and fight fire from a safe distance. ¦ SECTION 6 - ACCIDENTAL RELEASE MEASURES ¦ STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Evacuate the area, remove all sources of ignition and ventilate well. Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. ¦ SECTION 7 - HANDLING AND STORAGE ¦ HANDLING: Wash thoroughly after handling. Wash hands before eating. Use only in a well-ventilated area. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing vapor or mist. STORAGE: Keep containers closed. Isolate from heat, electrical (Continued on Page 4) Page 73 of 1235 Page 73 of 1235 Page 73 of 1235 Page 73 of 1235 ---PAGE BREAK--- Product: V2607 830 Preparation Date: 06/11/97 Page 4 ¦ SECTION 7 - HANDLING AND STORAGE ¦ equipment, sparks and open flame. Do not store above 120 degrees F. Store large quantities in buildings designed and protected for storage of NFPA Class I flammable liquids. Contents under pressure. Do not expose to heat or store above 120 degrees F. ¦ SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION ¦ ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use explosion-proof ventilation equipment. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation. RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection. EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids. OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application. HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. ¦ SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ¦ BOILING RANGE : -44 - 338 F VAPOR DENSITY : Is heavier than air ODOR : SOLVENT ODOR THRESHOLD : ND APPEARANCE : LIQUID EVAPORATION RATE: Is faster than Ether SOLUBILITY IN H2O : SLIGHT FREEZE POINT : ND SPECIFIC GRAVITY: 0.9925 VAPOR PRESSURE : ND pH @ 0.0 % : ND PHYSICAL STATE : LIQUID VISCOSITY : ND (Continued on Page 5) Page 74 of 1235 Page 74 of 1235 Page 74 of 1235 Page 74 of 1235 ---PAGE BREAK--- Product: V2607 830 Preparation Date: 06/11/97 Page 5 ¦ SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ¦ COEFFICIENT OF WATER/OIL DISTRIBUTION: ND (See Section 16 for abbreviation legend) ¦ SECTION 10 - STABILITY AND REACTIVITY ¦ CONDITIONS TO AVOID: Avoid temperatures above 120 degrees F. Avoid all possible sources of ignition. INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies. HAZARDOUS DECOMPOSITION PRODUCTS: By open flame, carbon monoxide and carbon dioxide. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. ¦ SECTION 11 - TOXICOLOGICAL PROPERTIES ¦ COMPONENT TOXICOLOGICAL INFORMATION: CHEMICAL NAME LD50 LC50 ACETONE RAT 5800MG/KG RAT 50100MG/M^3 8H PROPANE N.E. N.E. COPOLYMER RESIN SOLUTION 4300MG/KG RAT 5000PPM 4HR XYLENE RAT 4300MG/KG RAT 5000PPM 4HR N-BUTANE RAT 658G/M^3 4HR N.E. RAT 3500MG/KG N.A. VM&P NAPHTHA(PETROLEUM DISTILLATES) N.D. N.D. ISOBUTANE N.E. N.E. AROMATIC SOLVENT 4900mg/kg(rat) N.E. ¦ SECTION 12 - ECOLOGICAL INFORMATION ¦ ECOLOGICAL INFORMATION: Product is a mixture of listed components. ¦ SECTION 13 - DISPOSAL CONSIDERATIONS ¦ DISPOSAL METHOD: Dispose of material in accordance to local, state and federal regulations and ordinances. Do not allow to enter storm drains or sewer systems. (Continued on Page 6) Page 75 of 1235 Page 75 of 1235 Page 75 of 1235 Page 75 of 1235 ---PAGE BREAK--- Product: V2607 830 Preparation Date: 06/11/97 Page 6 ¦ SECTION 14 - TRANSPORTATION INFORMATION ¦ No transportation information is available. ¦ SECTION 15 - REGULATORY INFORMATION ¦ U.S. FEDERAL REGULATIONS: AS FOLLOWS - OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) CERCLA - SARA HAZARD CATEGORY: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD PRESSURIZED GAS HAZARD SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER WT/WT % IS LESS THAN XYLENE 1330-20-7 15.0 % 100-41-4 5.0 % 95-63-6 1.0 % TOLUENE 108-88-3 0.1 % TOXIC SUBSTANCES CONTROL ACT: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: CHEMICAL NAME CAS NUMBER No information is available. U.S. STATE REGULATIONS: AS FOLLOWS - NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components in this product: CHEMICAL NAME CAS NUMBER No non-hazardous materials are among the top five ingredients. (Continued on Page 7) Page 76 of 1235 Page 76 of 1235 Page 76 of 1235 Page 76 of 1235 ---PAGE BREAK--- Product: V2607 830 Preparation Date: 06/11/97 Page 7 ¦ SECTION 15 - REGULATORY INFORMATION ¦ RIGHT-TO-KNOW: The following non-hazardous ingredients are present in the product at greater than CHEMICAL NAME CAS NUMBER No non-hazardous ingredients are present at greater than CALIFORNIA PROPOSITION 65: WARNING: The chemical(s) noted below and contained in this product, are known to the state of California to cause cancer, birth defects or other reproductive harm: CHEMICAL NAME CAS NUMBER TOLUENE 108-88-3 INTERNATIONAL REGULATIONS: AS FOLLOWS - CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: No information available. ¦ SECTION 16 - OTHER INFORMATION ¦ HMIS RATINGS - HEALTH: FLAMMABILITY: REACTIVITY: PREVIOUS MSDS REVISION DATE: 04/10/97 LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined : No Information. The information contained on this MSDS has been checked and should be accurate. However, it is the responsibility of the user to comply with all Federal, State, and Local laws and regulations. Page 77 of 1235 Page 77 of 1235 Page 77 of 1235 Page 77 of 1235 ---PAGE BREAK--- Material Safety Data Sheet Section 1 - Product and Company Identification Material Name - 6230-9-30 – Black Jack All Weather Plastic Roof Cement Chemical Category - Mixture Product Code ‐ 6230-9-30 Product Description ‐ Black paste. Product Use ‐ Repair cracks, seams and holes in roofing materials. Synonyms ‐ Plastic roof and flashing cement Manufacturer ‐ Gardner-Gibson 4161 E. 7th Avenue Tampa, FL 33605 United States www.gardner‐gibson.com Please use "Contact Us" form on the website Telephone Technical ‐ [PHONE REDACTED] - Customer Service: 8 AM - 5 PM M-F Eastern Standard Time Emergency ‐ [PHONE REDACTED] - CHEMTREC Emergency ‐ [PHONE REDACTED] - CHEMTREC (Outside US) Preparation Date ‐ 7/22/2011 Last Revision Date ‐ 8/17/2011 Section 2 - Hazards Identification EMERGENCY OVERVIEW CAUTION Combustible liquid. Harmful if inhaled. Harmful if swallowed. Causes mild skin irritation. Causes eye irritation. Prevention Avoid breathing dust, fume, gas, mist, vapours and/or spray. Do not handle until all safety precautions have been read and understood. Keep away from flames and hot surfaces. ‐ No smoking. Use personal protective equipment as required. Keep out of reach of children. Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN: Wash with plenty of soap and water. IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician. Storage/Disposal Store in a closed container. Store in a well‐ventilated place. Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. CAUTION! COMBUSTIBLE LIQUID. Central nervous system depressent. Vapor may cause light‐headedness, headache, nausea, loss of coordination and respiratory tract irritation. May cause skin irritation. Physical Form ‐ Liquid Color ‐ Black Odor ‐ Petroleum solvent odor. Page 78 of 1235 Page 78 of 1235 Page 78 of 1235 Page 78 of 1235 ---PAGE BREAK--- Page 2 of 8 Flash Point ‐ 105 F(40.5556 C) OSHA ‐ Combustible Liquid, Irritant, Carcinogen WHMIS ‐ Class B - Flammable and Combustible Materials - Division 3, Class D - Poisonous and Infectious Materials - Division 2 - Subdivision A ‐ ‐ R65, R25, R36/37/38, R45 GHS ‐ Flammable Liquids - Category 3, Skin Corrosion/Irritation - Category 2, Serious Eye Damage, Eye Irritation - Category 2A, Carcinogenicity - Category 1A Route Of Entry ‐ Inhalation, Skin, Eye, Ingestion/Oral NFPA Potential Health Effects Inhalation Acute (Immediate) ‐ May cause irritation. Excessive breathing of high vapor concentration can cause possible unconsciousness and even Chronic (Delayed) ‐ Refer to other information found in Section 11-Toxicology. Skin Acute (Immediate) ‐ May cause irritation. Chronic (Delayed) ‐ Repeated and prolonged exposure to the skin may cause dermatitis. Eye Acute (Immediate) ‐ May cause irritation. Chronic (Delayed) ‐ Repeated and prolonged exposure may cause irritation. Ingestion Acute (Immediate) ‐ May be harmful or fatal if swallowed. Chronic (Delayed) ‐ Repeated and prolonged exposure may be harmful. Carcinogenic Effects ‐ This product or one of its ingredients present at 0.1% or more is listed as a carcinogen by NTP, IARC or OSHA. See Section 11 - Toxicological Information for more details. Carcinogenic Effects CAS IARC NTP Asphalt 8052‐42‐4 Group 2B‐Possible Carcinogen Under Consideration Section 3 - Composition/Information on Ingredients Hazardous Components Chemical Name CAS %(wt) UN;EINECS LD50/LC50 EU R & S Phrases Other Asphalt 8052‐ 42‐4 30% TO 40% NA1999, 232‐ 490‐9 Ingestion/Oral‐Rat LD50 ∙ >5000 mg/kgInhalation‐Rat LC50 ∙ >94.4 mg/m³ NDA NDA mineral spirits 8052‐ 41‐3 8% TO 15% 232‐489‐3 Carc.Cat.2; R45 Muta.Cat.2; R46 Xn; NDA Page 79 of 1235 Page 79 of 1235 Page 79 of 1235 Page 79 of 1235 ---PAGE BREAK--- Page 3 of 8 Hazardous Components Chemical Name CAS %(wt) UN;EINECS LD50/LC50 EU R & S Phrases Other R65 Cellulose 9004‐ 34‐6 2% TO 6% 232‐674‐9 Ingestion/Oral‐Rat LD50 ∙ >5 g/kgInhalation‐Rat LC50 ∙ >5800 mg/m³ 4 Hour(s)Skin‐Rabbit LD50 ∙ >2 g/kg NDA NDA Bentonite 1302‐ 78‐9 1% TO 5% 215‐108‐5 NDA NDA NDA 1,2,4‐ 95‐63‐6 < 1% 202‐436‐9 Ingestion/Oral‐Rat LD50 ∙ 5 g/kgInhalation‐Rat LC50 ∙ 18000 mg/m³ 4 Hour(s) R10 Xn; R20 Xi; R36/37/38 N; R51 R53 NDA Benzene, 1,3,5‐ trimethyl 108‐67‐ 8 < 1% UN2325, 203‐ 604‐4 R10 Xi; R37 N; R51 R53 NDA Surfactant 30113‐ 45‐2 < 0.5% 250‐056‐7 NDA NDA Non‐Hazardous Components Chemical Name CAS %(wt) UN;EINECS LD50/LC50 EU R & S Phrases Other Water 7732‐ 18‐5 35% TO 45% 231‐791‐2 NDA NDA This product is an encapsulated mixture which reduces the likelihood of exposure to hazardous particulates. Airborne exposures to hazardous dusts or mists may be generated by spraying, sanding or grinding. See Section 11 for Toxicological Information. Section 4 - First Aid Measures Inhalation ‐ IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell. Move victim to fresh air. If breathing is difficult, give oxygen. Skin ‐ IF ON SKIN: Wash with plenty of soap and water. If irritation develops and persists, get medical attention. Eye ‐ IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion ‐ If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Section 5 - Fire Fighting Measures Extinguishing Media ‐ LARGE FIRE: Water spray, fog or regular foam. SMALL FIRES: Dry chemical, CO2, water spray or regular foam. Unsuitable Extinguishing Media ‐ Do not use direct stream of water. Firefighting Procedures ‐ Fight advanced or massive fires from safe distance or protected location. Avoid water in a straight hose stream as the stream will cause splatter and spread fire. If product is heated above its flash point it will produce vapors sufficient to support combustion. Vapors are heavier than air and may travel along the ground and be ignited by heat, pilot lights, other flames and ignition sources at locations near the point of release. Unusual Fire and Explosion Hazards ‐ Combustible liquid. May release irritating or toxic gases, fumes, or vapors. Hazardous Combustion Products ‐ Carbon monoxide, carbon dioxide, hydrocarbons. Page 80 of 1235 Page 80 of 1235 Page 80 of 1235 Page 80 of 1235 ---PAGE BREAK--- Page 4 of 8 Protection of Firefighters ‐ Firefighters should wear self-contained breathing apparatus and full protective gear. Flash Point ‐ 105 F(40.5556 C) CC (Closed Cup) Explosion Limits Upper ‐ 6 % Lower ‐ .9 % Autoignition Temperature ‐ 450 F(232.2222 C) Section 6 - Accidental Release Measures Personal Precautions ‐ Do not touch damaged containers or spilled material unless wearing appropriate protective clothing Stay upwind Ventilate the area before entry Emergency Procedures ‐ ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area) Stop leak if you can do it without risk Isolate the area and contain the spilled material. Persons not wearing the appropriate PPE should be removed from the area until the spill is cleaned up Keep unauthorized personnel away Environmental Precautions ‐ Prevent entry into waterways, sewers, basements or confined areas Containment/Clean-up Measures ‐ Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in suitable container. Do not use water to flush spill area. Use appropriate Personal Protective Equipment (PPE) Prohibited Materials ‐ Avoid contact with strong oxidizing agents Section 7 - Handling and Storage Handling ‐ KEEP OUT OF THE REACH OF CHILDREN! Keep away from heat and ignition sources – No Smoking. Use only with adequate ventilation. Storage ‐ Store in a well-ventilated place. Keep container closed. Keep container/package closed in a cool, well-ventilated place. No open flames, no sparks and no smoking. Special Packaging Materials ‐ No data available Incompatible Materials or Ignition Sources ‐ Avoid contact with strong oxidizing agents and acids. Section 8 - Exposure Controls/Personal Protection Personal Protective Equipment Pictograms ‐ Respiratory ‐ In case of insufficient ventilation, wear suitable respiratory equipment. If listed exposure limits are expected to be exceeded, use approved respirtory protection suitable for the hazard. Eye/Face ‐ Wear ANSI approved safety glasses with side shields or safety goggles. Hands ‐ Wear chemical protective gloves made of Nitrile or Neoprene. Skin/Body ‐ Wear clothing that covers the skin to prevent skin exposure. General Industrial Hygiene Considerations ‐ Avoid contact with skin, eyes or clothing. Wash thoroughly with soap and water after handling. Avoid breathing vapors. Engineering Measures/Controls ‐ Adequate ventilation systems as needed to control concentrations of airborne contaminants below applicable threshold limit values. Use precaution to protect building intake from fumes and vapors created outdoors. Page 81 of 1235 Page 81 of 1235 Page 81 of 1235 Page 81 of 1235 ---PAGE BREAK--- Page 5 of 8 Exposure Limits/Guidelines Result ACGIH Canada Ontario OSHA United States ‐ California Cellulose (9004‐34‐ 6) TWAs 10 mg/m3 TWA 10 mg/m3 TWAEV (paper fibre, total dust) 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) 10 mg/m3 PEL (total dust); 5 mg/m3 PEL (respirable fraction) mineral spirits (8052‐41‐ 3) TWAs 100 ppm TWA 525 mg/m3 TWAEV 500 ppm TWA; 2900 mg/m3 TWA 100 ppm PEL; 525 mg/m3 PEL Asphalt (8052‐42‐ 4) TWAs 0.5 mg/m3 TWA (as benzene soluble aerosol, fume, inhalable fraction) 0.5 mg/m3 TWAEV (fume, inhalable, as benzene‐ soluble aerosol) Not established 5 mg/m3 PEL (fume) Exposure Control Notations ACGIH ▪ Asphalt (8052‐42‐4):Carcinogens:A4 ‐ Not Classifiable as a Human Carcinogen (fume, coal tar‐free) Key to abbreviations PEL = Permissible Exposure Level determined by the Occupational Safety and Health Administration (OSHA) TWA = Time‐Weighted Averages are based on 8h/day, 40h/week exposures Section 9 - Physical and Chemical Properties Physical Form ‐ Liquid Appearance/Description ‐ Black paste. Color: Black Odor: Petroleum solvent odor. Taste: NDA Odor Threshold: NDA Boiling Point: 300 to 400 F(148.8889 to 204.4444 C) Vapor Pressure: = 2 mmHg (torr) @ 68 F(20 C) Melting Point: NDA Vapor Density: = 1 Air=1 Specific Gravity/Relative Density: = 1.046 Water=1 Evaporation Rate: NDA Density: = 8.71 lbs/gal VOC = 1.66 lbs/gal Bulk Density: NDA VOC (Vol.): < 200 g/L pH: NDA Volatiles NDA Water Solubility: NDA Volatiles (Vol.): = 60 % Solvent Solubility: Yes Flash Point: 105 F(40.5556 C) Viscosity: NDA Flash Point Test Type: CC (Closed Cup) Half-Life: NDA Octanol/Water Partition coefficient: NDA Coefficient of Water: NDA Autoignition: 450 F(232.2222 C) Bioaccumulation Factor: NDA Bioconcentration Factor: NDA Biochemical Oxygen Demand BOD/BOD5: NDA Chemical Oxygen Demand: NDA Persistence: NDA Degradation: NDA Section 10 - Stability and Reactivity Stability ‐ Stable under normal temperatures and pressures. Hazardous Polymerization ‐ Hazardous polymerization will not occur. Conditions to Avoid ‐ Avoid contact with strong oxidizing agents and flame. Incompatible Materials ‐ Strong oxidizers and acids. Page 82 of 1235 Page 82 of 1235 Page 82 of 1235 Page 82 of 1235 ---PAGE BREAK--- Page 6 of 8 Hazardous Decomposition Products ‐ Carbon monoxide, carbon dioxide and hydrocarbons. Section 11 - Toxicological Information Component Name Concentration CAS Data Water 35% TO 45% 7732‐18‐5 Acute Toxicity: ; orl‐rat LD50:>90 mL/kg Asphalt 30% TO 40% 8052‐42‐4 Acute Toxicity: ; orl‐rat LD50:>5000 mg/kg; ihl‐rat LC50:>94.4 mg/m3 Tumorigen/Carcinogen: ; skn‐mus TD :69 gm/kg/43W‐I; skn‐mus TDLo:905 gm/kg/2Y‐I Cellulose 2% TO 6% 9004‐34‐6 Acute Toxicity: ; orl‐rat LD50:>5 gm/kg; ihl‐rat LC50:>5800 mg/m3/4H; skn‐rbt LD50:>2 gm/kg Bentonite 1% TO 5% 1302‐78‐9 Acute Toxicity: ; orl‐mus TDLo:14 gm/kg/7D‐I < 1% 95‐63‐6 Acute Toxicity: ; orl‐rat LD50:5 gm/kg; ihl‐rat LC50:18000 mg/m3/4H Other Component Information ‐ IARC has concluded that the following chemicals in this product are carcinogenic to humans (Group silica, quartz. ACGIH has designated the following chemicals in this product as suspected human carcinogens (A2): silica, quartz. NTP has listed the following chemicals in this product as known human carcinogens: silica, quartz. Risk of cancer depends on duration and level of exposure to this product as a dust or aerosol mist. Other Information ‐ This product contains petroleum asphalt. Petroleum asphalt is not listed as a carcinogen by OSHA or NTP. The National Institute of Occupational Safety and Health (NIOSH), has concluded that at higher temperatures roofing asphalt fumes are a potential occupational carcinogen. If this product is heated or comes in contact with heated material, avoid breathing fumes. This product may contain small amounts of aromatic hydrocarbons (PAH’s) which are recognized carcinogens in humans and experimental animals. Mouse skin painting studies of roofing asphalt vapor concentrate have shown evidence of tumor formation associated with localized skin irritation in recent studies. Inhalation studies of high airborne concentrations of asphalt/bitumen fumes in rats and mice produced bronchitis, pneumonitis, and lung changes such as fibrosis and cell damage. Key to abbreviations TC = Toxic Concentration TD = Toxic Dose Section 12 - Ecological Information Ecological Fate ‐ No data available. Persistence/Degradability ‐ No data available. Bioaccumulation Potential ‐ No data available. Mobility in Soil ‐ No data available. Section 13 - Disposal Considerations Product ‐ Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Page 83 of 1235 Page 83 of 1235 Page 83 of 1235 Page 83 of 1235 ---PAGE BREAK--- Page 7 of 8 Section 14 - Transportation Information DOT – Department of Transportation - Not Regulated when shipped in containers <119 gallons. TDG Transportation Other Information▪: Not Restricted under General Exemption for small container packaging. TDG - Canada Transportation of Dangerous Goods: Tars, Liquids; UN1999; Hazard Class: 3; Packing Group: III 1.33 Class 3, Flammable Liquids IMO/IMDG –International Maritime Transport ▪ IMDG Code 2.3.2.5 - exempted from marking, labeling & testing of packages. IATA - International Air Transport Association - TARS, LIQUID; UN1999; Hazard Class: 3; Packing Group: III. Section 15 - Regulatory Information SARA Hazard Classifications ‐ Acute, Chronic Risk & Safety Phrases ‐ California PROP 65: Asphalt and Asphalt Fumes may contain detectable amounts of chemicals known to the State of California to cause cancer or reproductive harm. . State Right To Know Component CAS MA MN NJ PA Water 7732-18-5 No No No No Asphalt 8052-42-4 Yes Yes Yes Yes mineral spirits 8052-41-3 Yes Yes Yes Yes Cellulose 9004-34-6 Yes Yes Yes Yes Bentonite 1302-78-9 No No No No 95-63-6 Yes Yes Yes Yes Benzene, 1,3,5-trimethyl 108-67-8 Yes No No No Surfactant 30113-45-2 No No No No Inventory Component CAS EU EINECS TSCA Water 7732-18-5 Yes Yes Asphalt 8052-42-4 Yes Yes mineral spirits 8052-41-3 Yes Yes Cellulose 9004-34-6 Yes Yes Bentonite 1302-78-9 Yes Yes 95-63-6 Yes Yes Benzene, 1,3,5-trimethyl 108-67-8 Yes Yes Surfactant 30113-45-2 Yes Yes Canada Labor Canada - WHMIS - Classifications of Substances ▪ Cellulose 9004-34-6 2% TO 6% Uncontrolled product according to WHMIS classification criteria (including and paper fibers) Page 84 of 1235 Page 84 of 1235 Page 84 of 1235 Page 84 of 1235 ---PAGE BREAK--- Page 8 of 8 ▪ Asphalt 8052-42-4 30% TO 40% Not Listed ▪ 95-63-6 < 1% B3 ▪ Bentonite 1302-78-9 1% TO 5% D2A ▪ Water 7732-18-5 35% TO 45% Uncontrolled product according to WHMIS classification criteria ▪ mineral spirits 8052-41-3 8% TO 15% B3, D2B ▪ Benzene, 1,3,5-trimethyl 108-67-8 < 1% B3 ▪ Surfactant 30113-45-2 < 0.5% Not Listed United States Environment U.S. - CERCLA/SARA - Section 313 - Emission Reporting ▪ Cellulose 9004-34-6 2% TO 6% Not Listed ▪ Asphalt 8052-42-4 30% TO 40% Not Listed ▪ 95-63-6 < 1% 1.0 % de minimis concentration ▪ Bentonite 1302-78-9 1% TO 5% Not Listed ▪ Water 7732-18-5 35% TO 45% Not Listed ▪ mineral spirits 8052-41-3 8% TO 15% Not Listed ▪ Benzene, 1,3,5-trimethyl 108-67-8 < 1% Not Listed ▪ Surfactant 30113-45-2 < 0.5% Not Listed Section 16 - Other Information Last Revision Date ‐ 8/17/2011 Prepared By ‐ Gardner-Gibson Preparation Date ‐ 7/22/2011 Disclaimer/Statement of Liability ‐ This information relates to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is to the best of our knowledge and belief, accurate and reliable as of the date compiled. However, no representation, warranty or guarantee is made as to its accuracy, reliability or completeness. It is the user’s responsibility to verify the suitability and completeness of such information for particular use. Gardner-Gibson does not accept liability for any loss or damage that may occur from the use of this information. Page 85 of 1235 Page 85 of 1235 Page 85 of 1235 Page 85 of 1235 ---PAGE BREAK--- 1. PRODUCT AND COMPANY IDENTIFICATION Product Identification Product ID: [PHONE REDACTED].077 Product Name: 80000 VAL IND ENAMEL GLOSS BLACK 6U Product Use: Paint product. Print date: 02/Mar/2011 Revision Date: 02/Mar/2011 Company Identification The Valspar Corporation 1000 Lake Road Medina, OH 44256 Manufacturer's Phone: 1-[PHONE REDACTED] 24-Hour Medical Emergency Phone: 1-[PHONE REDACTED] 2. HAZARDS IDENTIFICATION Primary Routes of Exposure: Inhalation Ingestion Skin absorption Eye Contact: • Severe eye irritation • Risk of serious damage to eyes. Skin Contact: • Causes skin irritation. • May cause defatting of the skin. • Dermatitis • Harmful if absorbed through skin. • May cause sensitization by skin contact. Ingestion: • Irritation of the mouth, throat, and stomach. • Harmful if swallowed. • Aspiration hazard if swallowed - can enter lungs and cause damage. Product ID: [PHONE REDACTED].077 Page 1 / 9 Material Safety Data Sheet Page 86 of 1235 Page 86 of 1235 Page 86 of 1235 Page 86 of 1235 ---PAGE BREAK--- Inhalation: • Causes respiratory tract irritation. • Harmful by inhalation. • • May cause sensitization by inhalation. Acute Other Health Effects: • May cause frostbite • Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Target Organ and Other Health Effects: • Causes headache, drowsiness or other effects to the central nervous system. • Kidney injury may occur. • Cardiac • Blood disorders • Contains glycol ether which has been shown to cause blood effects damage in laboratory animals. • Liver injury may occur. This product contains ingredients that may contribute to the following potential chronic health effects: • Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. • Possible sensitization. Carcinogens: • Possible cancer hazard. Contains material which may cause cancer based on animal data. 3. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS Ingredient Name CAS-No. Approx. Weight % Chemical Name DIMETHYL KETONE- EXEMPT SOLVENT 67-64-1 25 - 30 Acetone PROPANE 74-98-6 15 - 20 Propane BUTANE 106-97-8 5 - 10 Butane BUTYL ACETATE 123-86-4 5 - 10 n-Butyl acetate METHYL ISOBUTYL KETONE 108-10-1 5 - 10 Methylisobutyl ketone ETHYLENE GLYCOL MONOPROPYL ETHER 2807-30-9 1 - 5 Ethylene glycol monopropyl ether PROPRIETARY INERT 1 - 5 PROPRIETARY INERT ISOBUTYL ACETATE 110-19-0 1 - 5 Isobutyl acetate C.I. PIGMENT BLACK 7 1333-86-4 1 - 5 Carbon black METHYL PROPYLKETONE 107-87-9 1 - 5 ketone COBALT OCTOATE 136-52-7 .1 - 1 Hexanoic acid, 2-ethyl-, cobalt(2+) salt Product ID: [PHONE REDACTED].077 Page 2 / 9 Page 87 of 1235 Page 87 of 1235 Page 87 of 1235 Page 87 of 1235 ---PAGE BREAK--- If this section is blank there are no hazardous components per OSHA guidelines. 4. FIRST AID MEASURES Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. If medical assistance is not immediately available, flush an additional 15 minutes. Get medical attention immediately. Skin Contact: Remove contaminated clothing and shoes. Wash off immediately with plenty of water for at least 15 minutes. Get medical attention, if develop or persist. Ingestion: Rinse mouth with water. Give one or two glasses of water. Only induce vomiting at the instruction of medical personnel. Never give anything by mouth to an unconscious person. Do NOT induce vomiting. If vomiting occurs, keep head lower than hips to prevent aspiration. Get medical attention immediately. Inhalation: Move injured person into fresh air and keep person calm under observation. Get medical attention immediately. For breathing difficulties, oxygen may be necessary. If breathing stops, provide artificial respiration. Do not give direct mouth- to-mouth resuscitation if inhaled. To protect rescuer, use air-viva, oxy-viva or one-way mask. Resuscitate in a well- ventilated area. Medical conditions aggravated by exposure: Any respiratory or skin condition. 5. FIRE FIGHTING MEASURES Flash point (Fahrenheit): -31 Flash point (Celsius): -35 Lower explosive limit 1 Upper explosive limit 13 Autoignition temperature: not determined Sensitivity to impact: no Sensitivity to static discharge: Subject to static discharge hazards. Please see bonding and grounding information in Section 7. Hazardous combustion products: See Section 10. Unusual fire and explosion hazards: None known. Extinguishing media: Carbon dioxide, dry chemical, foam and/or water fog. Fire fighting procedures: Firefighters should be equipped with self-contained breathing apparatus and turn out gear. Keep containers and surroundings cool with water spray. 6. ACCIDENTAL RELEASE MEASURES Action to be taken if material is released or spilled: Ventilate the area. Avoid breathing dust or vapor. Use self-containing breathing apparatus or airmask for large spills in a confined area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 7, "Handling and Storage", for proper container and storage procedures. Remove all sources of ignition. Soak up with inert absorbent material. Use only non-sparking tools. Avoid contact with eyes. Product ID: [PHONE REDACTED].077 Page 3 / 9 Page 88 of 1235 Page 88 of 1235 Page 88 of 1235 Page 88 of 1235 ---PAGE BREAK--- 7. HANDLING AND STORAGE Precautions to be taken in handling and storage: Keep away from heat, sparks and open flame. - No smoking. Keep container closed when not in use. Do not store above 120 degrees F. (49 degrees Based on flash point and vapor pressure, suitable storage should be provided in accordance with OSHA regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty containers may contain product residue, including flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must be observed until the container has been commercially cleaned or reconditioned. If the product is used near or above the flashpoint, an ignition hazard may be present. Activities, uses, or operations which liberate vapor (such as mixing or free fall of liquids) may also present an ignition hazard. Please ensure containers and other interconnected equipment are properly bonded and grounded at all times. 8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS Personal Protective Equipment Eye and face protection: Wear chemical goggles with splash shields or face shield. Contact lenses should not be worn when working with chemicals because contact lenses may contribute to the severity of an eye injury in case of exposure. Skin protection: Appropriate chemical resistant gloves should be worn. Other Personel Protection Data: To prevent skin contact wear protective clothing covering all exposed areas. Ensure that eyewash stations and safety showers are close to the workstation location. Respiratory protection: If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an air purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's literature to ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's instructions. Ventilation Use only in well-ventilated areas. Ensure adequate ventilation, especially in confined areas. Ovens used for curing should contain a fresh air purge to prevent vapours from accumulating and creating a possible explosive mixture. Where the product is used in a hazardous classified area, use explosion-proof electrical/ventilating/lighting/equipment. Exposure Guidelines OSHA Permissible Exposure Limits (PEL's) Ingredient Name CAS-No. Approx. Weight % TWA (final) Ceilings limits (final) Skin designations DIMETHYL KETONE- EXEMPT SOLVENT 67-64-1 25 - 30 1000 ppm TWA 2400 mg/m3 TWA PROPANE 74-98-6 15 - 20 1000 ppm TWA 1800 mg/m3 TWA BUTYL ACETATE 123-86-4 5 - 10 150 ppm TWA 710 mg/m3 TWA METHYL ISOBUTYL KETONE 108-10-1 5 - 10 100 ppm TWA 410 mg/m3 TWA PROPRIETARY INERT 1 - 5 5 mg/m3 TWA respirable fraction ISOBUTYL ACETATE 110-19-0 1 - 5 150 ppm TWA 700 mg/m3 TWA C.I. PIGMENT BLACK 7 1333-86-4 1 - 5 3.5 mg/m3 TWA Product ID: [PHONE REDACTED].077 Page 4 / 9 Page 89 of 1235 Page 89 of 1235 Page 89 of 1235 Page 89 of 1235 ---PAGE BREAK--- Ingredient Name CAS-No. Approx. Weight % TWA (final) Ceilings limits (final) Skin designations METHYL PROPYLKETONE 107-87-9 1 - 5 200 ppm TWA 700 mg/m3 TWA ACGIH Threshold Limit Value (TLV's) Ingredient Name CAS-No. Approx. Weight % TWA STEL Ceiling limits Skin designations DIMETHYL KETONE- EXEMPT SOLVENT 67-64-1 25 - 30 500 ppm TWA 750 ppm STEL PROPANE 74-98-6 15 - 20 1000 ppm TWA BUTANE 106-97-8 5 - 10 1000 ppm TWA BUTYL ACETATE 123-86-4 5 - 10 150 ppm TWA 200 ppm STEL METHYL ISOBUTYL KETONE 108-10-1 5 - 10 50 ppm TWA 75 ppm STEL PROPRIETARY INERT 1 - 5 10 mg/m3 TWA ISOBUTYL ACETATE 110-19-0 1 - 5 150 ppm TWA C.I. PIGMENT BLACK 7 1333-86-4 1 - 5 3.5 mg/m3 TWA METHYL PROPYLKETONE 107-87-9 1 - 5 200 ppm 150 ppm STEL 9. PHYSICAL PROPERTIES Odor: Normal for this product type. Physical State: Aerosol pH: not determined Vapor pressure: NOT DETERMINED mmHg @ 68ºF (20ºC) Vapor density (air = 1.0): 4 Boiling point: not determined Solubility in water: not determined Coefficient of water/oil distribution: not determined Density (lbs per US gallon): 6.59 Specific Gravity: .79 Evaporation rate (butyl acetate = 1.0): 5.6 Flash point (Fahrenheit): -31 Flash point (Celsius): -35 Lower explosive limit 1 Upper explosive limit 13 Autoignition temperature: not determined 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions. Conditions to Avoid: Heat. Incompatibility: Strong oxidizing agents Hazardous Polymerization: None anticipated. Product ID: [PHONE REDACTED].077 Page 5 / 9 Page 90 of 1235 Page 90 of 1235 Page 90 of 1235 Page 90 of 1235 ---PAGE BREAK--- 10. STABILITY AND REACTIVITY Hazardous Decomposition Products: Carbon monoxide and carbon dioxide. Sensitivity to static discharge: Subject to static discharge hazards. Please see bonding and grounding information in Section 7. 11. TOXICOLOGICAL INFORMATION Ingredient Name CAS-No. Approx. Weight % NIOSH - Selected LD50s and LC50s DIMETHYL KETONE- EXEMPT SOLVENT 67-64-1 25 - 30 = 5800 mg/kg Oral LD50 Rat PROPANE 74-98-6 15 - 20 = 658 mg/L Inhalation LC50 Rat 4 h BUTANE 106-97-8 5 - 10 = 658 mg/L Inhalation LC50 Rat 4 h BUTYL ACETATE 123-86-4 5 - 10 = 10768 mg/kg Oral LD50 Rat = 390 ppm Inhalation LC50 Rat 4 h > 17600 mg/kg Dermal LD50 Rabbit METHYL ISOBUTYL KETONE 108-10-1 5 - 10 = 2080 mg/kg Oral LD50 Rat = 8.2 mg/L Inhalation LC50 Rat 4 h > 16000 mg/kg Dermal LD50 Rabbit ETHYLENE GLYCOL MONOPROPYL ETHER 2807-30-9 1 - 5 = 3089 mg/kg Oral LD50 Rat = 960 µL/kg Dermal LD50 Rabbit ISOBUTYL ACETATE 110-19-0 1 - 5 = 13400 mg/kg Oral LD50 Rat > 5000 mg/kg Dermal LD50 Rabbit C.I. PIGMENT BLACK 7 1333-86-4 1 - 5 > 15400 mg/kg Oral LD50 Rat > 3 g/kg Dermal LD50 Rabbit METHYL PROPYLKETONE 107-87-9 1 - 5 = 1600 mg/kg Oral LD50 Rat = 6500 mg/kg Dermal LD50 Rabbit Mutagens/Teratogens/Carcinogens: Possible cancer hazard. Contains material which may cause cancer based on animal data. IARC has classified carbon black as possibly carcinogenic to humans (Group 2B). The International Agency For Research On Cancer (IARC) has determined that Cobalt and Cobalt Compounds are substances that are possibly carcinogenic to humans (IARC group 2B). Ingredient Name CAS-No. Approx. Weight % IARC Group 1 - Human Evidence IARC Group 2A - Limited Human Data IARC Group 2B - Sufficient Animal Data C.I. PIGMENT BLACK 7 1333-86-4 1 - 5 Monograph 65 [1996] COBALT OCTOATE 136-52-7 .1 - 1 Monograph 52 [1991] Ingredient Name CAS-No. Approx. Weight % NTP Known Carcinogens NTP Suspect Carcinogens NTP Evidence of Carcinogenicity METHYL ISOBUTYL KETONE 108-10-1 5 - 10 male rat-some evidence; female rat-equivocal evidence; male mice- some evidence; female mice-some evidence Product ID: [PHONE REDACTED].077 Page 6 / 9 Page 91 of 1235 Page 91 of 1235 Page 91 of 1235 Page 91 of 1235 ---PAGE BREAK--- Ingredient Name CAS-No. Approx. Weight % OSHA - Hazard Communication Carcinogens OSHA - Specifically Regulated Carcinogens ACGIH Carcinogens C.I. PIGMENT BLACK 7 1333-86-4 1 - 5 Present COBALT OCTOATE 136-52-7 .1 - 1 Present 12. ECOLOGICAL DATA No information on ecology is available. 13. DISPOSAL CONSIDERATIONS Disposal should be made in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION U.S. Department of Transportation UN ID Number (msds): CONCOM Proper Shipping Name: CONSUMER COMMODITY ORM-D [Paint] U.S Hazmat and/or International DG shipment exceptions The supplier may apply one of the following exceptions: Combustible Liquid, Consumer Commodity, Limited Quantity, Viscous Liquid, Does Not Sustain Combustion, or others, as allowed under 49CFR Hazmat Regulations. Please consult 49CFR Subchapter C to ensure that subsequent shipments comply with these exceptions. Reportable Quantity Description: International Air Transport Association (IATA): UN ID Number (msds): UN1950 Proper Shipping Name: AEROSOLS, FLAMMABLE Hazard Class: 2.1 International Maritime Organization (IMO): IMO UN/ID Number (msds): UN1950 Proper Shipping Name: AEROSOLS, FLAMMABLE Hazard Class: 2.1 15. REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: Ingredient Name CAS-No. Approx. Weight % SARA 302 SARA 313 CERCLA RQ in lbs. DIMETHYL KETONE- EXEMPT SOLVENT 67-64-1 25 - 30 5000 BUTYL ACETATE 123-86-4 5 - 10 5000 METHYL ISOBUTYL KETONE 108-10-1 5 - 10 form R reporting required for 1.0% de minimis concentration 5000 ETHYLENE GLYCOL MONOPROPYL ETHER 2807-30-9 1 - 5 YES ISOBUTYL ACETATE 110-19-0 1 - 5 5000 Product ID: [PHONE REDACTED].077 Page 7 / 9 Page 92 of 1235 Page 92 of 1235 Page 92 of 1235 Page 92 of 1235 ---PAGE BREAK--- 15. REGULATORY INFORMATION COBALT OCTOATE 136-52-7 .1 - 1 YES 10 SARA 311/312 Hazard Class: Acute: yes Chronic: yes Flammability: yes Reactivity: no Sudden Pressure: yes U.S. STATE REGULATIONS: Right to Know: The specific chemical identity of a component may be withheld as a trade secret under 34 Code, Chapter 317. Right To Know: BUTANE 106-97-8 METHYL PROPYLKETONE 107-87-9 METHYL ISOBUTYL KETONE 108-10-1 ISOBUTYL ACETATE 110-19-0 BUTYL ACETATE 123-86-4 C.I. PIGMENT BLACK 7 1333-86-4 ETHYLENE GLYCOL MONOPROPYL ETHER 2807-30-9 DIMETHYL KETONE- EXEMPT SOLVENT 67-64-1 PROPANE 74-98-6 PROPRIETARY INERT Trade Secret Additional Non-Hazardous Materials PROPRIETARY RESIN Trade Secret PROPRIETARY RESIN Trade Secret Rule 66 status of product Not photochemically reactive. INTERNATIONAL REGULATIONS - Chemical Inventories US TSCA Inventory: All components of this product are in compliance with U.S. TSCA Chemical Substance Inventory Requirements. Canada Domestic Substances List: All components of this product are listed on the Domestic Substances List. 16. OTHER INFORMATION HMIS Codes Health: 2* Flammability: 4 Reactivity: 1 PPE: X - See Section 8 for Personal Protective Equipment (PPE). Product ID: [PHONE REDACTED].077 Page 8 / 9 Page 93 of 1235 Page 93 of 1235 Page 93 of 1235 Page 93 of 1235 ---PAGE BREAK--- Abbreviations: OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer, NIOSH - National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH - American Conference of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management District, TSCA - Toxic Substances Control Act, IATA - International Air Transport Association, IMO - International Maritime Organization, DOT - Department of Transportation, NA - Not applicable, NOT ESTAB - Not established, N.A.V. - Not available, RQ - Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams per liter, MM - Millimeters, - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per thousand, TCC/PM - Tag closed cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time Weighted Average, STEL - Short term exposure limit, C - Celsius, F - Fahrenheit. Disclaimer: The data on this sheet represent typical values. Since application variables are a major factor in product performance, this information should serve only as a general guide. Valspar assumes no obligation or liability for use of this information. UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES, EXPRESS OR IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. VALSPAR WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only remedy for any defect in this product is the replacement of the defective product, or a refund of its purchase price, at our option. This MSDS contains additional information required by the state of Preparation Information: Prepared By: Regulatory Affairs Department Print date: 02/Mar/2011 Revision Date: 02/Mar/2011 Product ID: [PHONE REDACTED].077 Page 9 / 9 Page 94 of 1235 Page 94 of 1235 Page 94 of 1235 Page 94 of 1235 ---PAGE BREAK--- Safety Data Sheet 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Product Name: 948-57291 VALSPAR GLOSS ENAMEL WHITE Recommended Use: Solvent based surface coating. Applied by brush, roller or spray. Supplier: Dulux New Zealand, a division of DuluxGroup (New Zealand) Pty Ltd ABN 55 133 404 118 Co. 2355191 Street Address: 150 Hutt Park Road Lower Hutt, New Zealand Telephone Number: +64 4 576 6400 Facsimile: +64 4 576 6496 Emergency Telephone: 0 800 734 607 (ALL HOURS) 2. HAZARDS IDENTIFICATION Classified as a Dangerous Good according to NZS 5433:2007 Transport of Dangerous Goods on Land. Classified as hazardous according to criteria in the HS (Minimum Degrees of Hazard) Regulations 2001. Subclasses: Subclass 3.1 Category C (medium hazard) - Flammable Liquids. Subclass 6.1 Category E - Substances which are acutely toxic. Subclass 6.3 Category B - Substances that are mildly irritating to the skin. Subclass 6.5 Category B - Substances that are contact sensitisers. Subclass 6.8 Category B - Substances that are suspected human reproductive or developmental toxicants. Subclass 6.9 Category B - Substances that are harmful to human target organs or systems. Subclass 9.1 Category B - Substances that are ecotoxic in the aquatic environment. Surface Coatings and Colourants (Flammable) Group Standard 2006 Hazard and Precautionary Information: Warning. Flammable liquid and vapour. May be harmful if swallowed. Causes mild skin irritation. May cause an allergic skin reaction. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects. Keep out of reach of children. Read label before use. Read Safety Data Sheet before use. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Keep container closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/protective clothing/eye protection/face protection. Contaminated work clothing should not be allowed out of the workplace. Use personal protective equipment as required. Avoid release to the environment. In case of fire: Use extinguishing media as outlined in Section 5 of this Safety Data Sheet for extinction. IF ON SKIN(or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a POISON CENTER or doctor/physician if you feel unwell. Do NOT induce vomitting. IF exposed or concerned: Get medical advice/attention. Store in a well-ventilated place. Keep cool. In case of a substance that is in compliance with a HSNO approval other than a Part 6A (Group Standards) approval, a label must provide a description of one or more appropriate and achievable methods for the disposal of a substance in accordance with the Hazardous Substances (Disposal) Regulations 2001. This may also include any method of disposal that must be avoided. Product Name: 948-57291 VALSPAR GLOSS ENAMEL WHITE Issued: 13/04/2010 Substance No: 000000004425 Version: 5 Page 1 of 7 Page 95 of 1235 Page 95 of 1235 Page 95 of 1235 Page 95 of 1235 ---PAGE BREAK--- Safety Data Sheet 3. COMPOSITION/INFORMATION ON INGREDIENTS Components CAS Number Proportion Risk Phrases polymer(s) - 10-60% - Pigments - 10-60% - Mineral turpentine - 10-60% R10, R38, R65 Kerosine 8008-20-6 10-60% R10, R38, R65 White spirit (Stoddard solvent) 8052-41-3 10-60% R65 Solvent naphtha (petroleum), light arom. 64742-95-6 1-<10% R65 Xylene 1330-20-7 1-<5% R10 R20/21 R38 Ingredients determined not to be hazardous - to 100% - 4. FIRST AID MEASURES For advice, contact a Poisons Information Centre (e.g. phone Australia 131 126; New Zealand 0800 764 766) or a doctor. Inhalation: Remove victim from area of exposure - avoid becoming a casualty. Remove contaminated clothing and loosen remaining clothing. Allow patient to assume most comfortable position and keep warm. Keep at rest until fully recovered. If patient finds breathing difficult and develops a bluish discolouration of the skin (which suggests a lack of oxygen in the blood - cyanosis), ensure airways are clear of any obstruction and have a qualified person give oxygen through a face mask. Apply artificial respiration if patient is not breathing. Seek immediate medical advice. Skin Contact: If skin or hair contact occurs, immediately remove any contaminated clothing and wash skin and hair thoroughly with running water. If swelling, redness, blistering or irritation occurs seek medical assistance. Eye Contact: If in eyes, wash out immediately with water. In all cases of eye contamination it is a sensible precaution to seek medical advice. Ingestion: If swallowed, do NOT induce vomiting. Give a glass of water. Get to a doctor or hospital quickly. Medical attention and special treatment: Treat 5. FIRE FIGHTING MEASURES Hazards from combustion products: Flammable liquid. On burning will emit toxic fumes. Precautions for fire fighters and special protective equipment: Keep containers cool with water spray. Fire fighters to wear self-contained breathing apparatus and suitable protective clothing if risk of exposure to vapour or products of combustion. Suitable Extinguishing Media: Alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal protein foam can be used. Hazchem Code: · 3Y Product Name: 948-57291 VALSPAR GLOSS ENAMEL WHITE Issued: 13/04/2010 Substance No: 000000004425 Version: 5 Page 2 of 7 Page 96 of 1235 Page 96 of 1235 Page 96 of 1235 Page 96 of 1235 ---PAGE BREAK--- Safety Data Sheet 6. ACCIDENTAL RELEASE MEASURES Emergency procedures: If contamination of sewers or waterways has occurred advise local emergency services. Methods and materials for containment and clean up: SMALL SPILLS: Collect in a container for disposal via special chemical waste collection. LARGE SPILLS: Shut off all possible sources of ignition. Wear protective equipment to prevent skin and eye contact. Avoid breathing in vapours. Work up wind or increase ventilation. Contain - prevent run off into drains and waterways. Use absorbent (soil, sand or other inert material). Collect and seal in properly labelled containers or drums for disposal. 7. HANDLING AND STORAGE Precautions for safe handling: Keep out of reach of children. Avoid skin and eye contact and breathing in vapour. All potential sources of ignition (open flames, pilot lights, furnaces, spark producing switches and electrical equipment etc) must be eliminated both in and near the work area. Do NOT smoke. Vapour may travel a considerable distance to source of ignition and flash back. Conditions for safe storage: Store in a well ventilated area away from foodstuffs, oxidising agents and sources of heat or ignition. Keep containers closed when not in use - check regularly for leaks. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: No value assigned for this specific material by the New Zealand Occupational Safety and Health Service (OSH). However, Workplace Exposure Standard(s) for constituent(s): White spirits (Stoddard solvent): WES-TWA 100 ppm, 525 mg/m3 Xylene p-isomers): WES-TWA 50 ppm, 217 mg/m3 No value assigned for this specific material by the New Zealand Occupational Safety and Health Service (OSH). No Exposure Standards assigned to other constituents. WES - TWA (Workplace Exposure Standard - Time Weighted Average) - The eight-hour, time-weighted average exposure standard is designed to protect the worker from the effects of long-term exposure. WES - STEL (Workplace Exposure Standard - Short Term Exposure Limits) - The 15 minute average exposure standard. Applies to any 15 minute period in the working day and is designed to protect the worker against adverse effects of irritation, chronic or irreversible tissue change, or narcosis that may increase the likelihood of accidents. The WES-STEL is not an alternative to the WES-TWA; both short-term and eight-hour, time-weighted average exposures should be determined. These Exposure Standards are guides to be used in the control of occupational health hazards. All atmospheric contamination should be kept to as low a level as is workable. These exposure standards should not be used as fine dividing lines between safe and dangerous concentrations of chemicals. They are not a measure of relative toxicity. Product Name: 948-57291 VALSPAR GLOSS ENAMEL WHITE Issued: 13/04/2010 Substance No: 000000004425 Version: 5 Page 3 of 7 Page 97 of 1235 Page 97 of 1235 Page 97 of 1235 Page 97 of 1235 ---PAGE BREAK--- Safety Data Sheet Engineering controls: Provide adequate ventilation. If using indoors, keep windows and doors open during use. Keep containers closed when not in use. Personal Protective Equipment: The selection of PPE is dependant on a detailed risk assessment. The risk assessment should consider the work situation, the physical form of the chemical, the handling methods, and environmental factors. Personal Protection: G - OVERALLS, SAFETY SHOES, SAFETY GLASSES, GLOVES, RESPIRATOR. MANUFACTURE, PACKAGING AND TRANSPORT: Wear overalls, safety glasses and impervious gloves. Use with adequate ventilation. If inhalation risk exists wear organic vapour/particulate respirator meeting the requirements of AS/NZS 1715 and AS/NZS1716. Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated clothing and other protective equipment before storage or re-use. FOR CONSUMER USE: Avoid contact with eyes and skin. Use with adequate ventilation. If risk of inhalation exists, wear organic vapour/particulate respirator meeting the requirements of AS/NZS 1715 and AS/NZS 1716. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Viscous liquid Colour: Coloured Odour: Solvent Solubility: Insoluble in water. Soluble in organic solvents. Specific Gravity: 0.9-1.4 @20°C Relative Vapour Density (air=1): >1 Vapour Pressure (20 Not available Flash Point >23 Flammability Limits Not available Autoignition Temperature Not available % Volatile by Volume: Not available Solubility in water Insoluble Melting Point/Range Not applicable Boiling Point/Range Not available Decomposition Point Not available pH: Not applicable Viscosity: Not available Evaporation Rate: Not available Product Name: 948-57291 VALSPAR GLOSS ENAMEL WHITE Issued: 13/04/2010 Substance No: 000000004425 Version: 5 Page 4 of 7 Page 98 of 1235 Page 98 of 1235 Page 98 of 1235 Page 98 of 1235 ---PAGE BREAK--- Safety Data Sheet 10. STABILITY AND REACTIVITY Chemical stability: Stable under normal conditions of use. Conditions to avoid: Avoid contact with foodstuffs. Avoid exposure to heat, sources of ignition, and open flame. Avoid contact with oxidising agents. Incompatible materials: Incompatible with oxidising agents. Hazardous decomposition products: Oxides of carbon. Hazardous reactions: None known. 11. TOXICOLOGICAL INFORMATION No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label. or effects that may arise if the product is mishandled and overexposure occurs are: Ingestion: Swallowing can result in nausea, vomiting and central nervous system depression. If the victim is showing signs of central system depression (like those of drunkeness) there is greater likelihood of the patient breathing in vomit and causing damage to the lungs. Eye contact: May be an eye irritant. Skin contact: Contact with skin will result in irritation. Will have a degreasing action on the skin. Repeated or prolonged skin contact may lead to irritant contact dermatitis. Inhalation: Material may be irritant to the mucous membranes of the respiratory tract (airways). Breathing in vapour can result in headaches, dizziness, drowsiness, and possible nausea. Breathing in high concentrations can produce central nervous system depression, which can lead to loss of co-ordination, impaired judgement and if exposure is prolonged, unconsciousness. Long Term Effects: No information available for the product. Toxicological Data: No LD50 data available for the product. 12. ECOLOGICAL INFORMATION Ecotoxicity Avoid contaminating waterways. 13. DISPOSAL CONSIDERATIONS Product Name: 948-57291 VALSPAR GLOSS ENAMEL WHITE Issued: 13/04/2010 Substance No: 000000004425 Version: 5 Page 5 of 7 Page 99 of 1235 Page 99 of 1235 Page 99 of 1235 Page 99 of 1235 ---PAGE BREAK--- Safety Data Sheet Disposal methods: For large quantities: Refer to Waste Management Authority. Advise flammable nature. Dispose of material through a licensed waste contractor. Normally suitable for incineration by an approved agent. For small quantities: Do not pour leftover paint down the drain. Unwanted paint should be brushed out on newspaper, allowed to dry and then disposed of via domestic waste collection. Empty paint containers should be left open in a well ventilated area to dry out. When dry recycle the container via steel can recycling programs. Disposal of empty paint containers via domestic recycling programs may differ between local authorities. Check with your local council first. 14. TRANSPORT INFORMATION Road and Rail Transport Classified as a Dangerous Good according to NZS 5433:2007 Transport of Dangerous Goods on Land. FLAMMABLE LIQUID 3 UN No: 1263 Class-primary 3 Flammable Liquid Packing Group: III Proper Shipping Name: PAINT Hazchem Code: · 3Y Marine Transport Classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea; DANGEROUS GOODS. UN No: 1263 Class-primary: 3 Flammable Liquid Packing Group: III Proper Shipping Name: PAINT Air Transport Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air; DANGEROUS GOODS. UN No: 1263 Packing Group: III Proper Shipping Name: PAINT 15. REGULATORY INFORMATION Classification: Classified as hazardous according to criteria in the HS (Minimum Degrees of Hazard) Regulations 2001. Product Name: 948-57291 VALSPAR GLOSS ENAMEL WHITE Issued: 13/04/2010 Substance No: 000000004425 Version: 5 Page 6 of 7 Page 100 of 1235 Page 100 of 1235 Page 100 of 1235 Page 100 of 1235 ---PAGE BREAK--- Safety Data Sheet Subclasses: Subclass 3.1 Category C (medium hazard) - Flammable Liquids. Subclass 6.1 Category E - Substances which are acutely toxic. Subclass 6.3 Category B - Substances that are mildly irritating to the skin. Subclass 6.5 Category B - Substances that are contact sensitisers. Subclass 6.8 Category B - Substances that are suspected human reproductive or developmental toxicants. Subclass 6.9 Category B - Substances that are harmful to human target organs or systems. Subclass 9.1 Category B - Substances that are ecotoxic in the aquatic environment. Surface Coatings and Colourants (Flammable) Group Standard 2006 16. OTHER INFORMATION Reason(s) for Issue: Change to Transport Information Alignment to HSNO requirements This safety data sheet has been prepared by SH&E Shared Services. This SDS summarises to our best knowledge at the date of issue, the chemical health and safety hazards of the material and general guidance on how to safely handle the material in the workplace. Since DuluxGroup Limited cannot anticipate or control the conditions under which the product may be used, each user must, prior to usage, assess and control the risks arising from its use of the material. If clarification or further information is needed, the user should contact their DuluxGroup representative or DuluxGroup Limited at the contact details on page 1. DuluxGroup Limited's responsibility for the material as sold is subject to the terms and conditions of sale, a copy of which is available upon request. Product Name: 948-57291 VALSPAR GLOSS ENAMEL WHITE Issued: 13/04/2010 Substance No: 000000004425 Version: 5 Page 7 of 7 Page 101 of 1235 Page 101 of 1235 Page 101 of 1235 Page 101 of 1235 ---PAGE BREAK--- I M A T E R I A L S A F E T Y D A T A S H E E T I I SECTION I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION I PRODUCT NAME : AERO-SPOT-CO2-ALL COLORS IDENTIFICATION NUMBER: E&I 30 14 AEC DATE PRINTED: 05/30/02 PRODUCT USE/CLASS : SUPPLIER: MANUFACTURER: The Nelson Paint Co of Michigan Inc The Nelson Paint Co of Michigan Inc PO Box 2040 PO Box 2040 Kingsford, MI 49802-2040 Kingsford, MI 49802-2040 EMERGENCY TELEPHONE:[PHONE REDACTED] EMERGENCY TELEPHONE:[PHONE REDACTED] CHEMTEL: 24 hours CHEMTEL: 24 hours PREPARER: Doyle Yoder, PHONE: [PHONE REDACTED], PREPARE DATE: 05/30/02 I SECTION II - COMPOSITION/INFORMATION ON INGREDIENTS I WT. PERCENT OCCUPATIONAL EXPOSURE LIMITS CHEMICAL NAME CAS NUMBER IS LESS THAN TLV-TWA TLV-STEL PEL-TWA PEL-CEILING SKIN Methyl Alcohol 67-56-1 15.0 % 200ppm 250ppm 200ppm N.E. YES Aliphatic Hydrocarbons 8052-41-3 35.0 % 100ppm N.E 100ppm N.E. NO (See Section XI for abbreviation legend) I SECTION III - PHYSICAL DATA I BOILING RANGE : 147 - 385 F VAPOR DENSITY : Is heavier than air ODOR : Slight solvent SPECIFIC GRAVITY: 0.0000 APPEARANCE : Ccolored liquid EVAPORATION RATE: Is faster than Butyl SOLUBILITY IN H2O : Partial Acetate VOLATILE BY WEIGHT: 74.3% VOLATILE BY VOL.: 84.9% VOCS, lbs/gal : 5.15 VOCS, grams/ltr : 617 (See Section 11 for abbreviation legend) I SECTION IV - FIRE AND EXPLOSION HAZARD DATA I FLASH POINT: 74 F LOWER EXPLOSIVE LIMIT: 1.0 % UPPER EXPLOSIVE LIMIT: 36.0 % EXTINGUISHING MEDIA: ALCOHOL FOAM CO2 DRY CHEMICAL FOAM UNUSUAL FIRE AND EXPLOSION HAZARDS: Avoid breathing dusts and fumes from burning material. Vapors may form explosive mixture with air. Vapors can travel to a source of ignition and flash back. “Empty” containers retain Page 102 of 1235 Page 102 of 1235 Page 102 of 1235 Page 102 of 1235 ---PAGE BREAK--- product residue (liquid and/or vapor) and can be dangerous. DO NOT (Continued on Page 2) Product: E&I 30 14 AEC Preparation Date: 05/30/02 Page 2 I SECTION IV - FIRE AND EXPLOSION HAZARD DATA I PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Empty drums should be completely drained, properly bunged and returned to a drum reconditioner, or properly disposed of. Keep containers closed . Isolate from heat, electrical equipment, sparks and open flame. Closed containers may explode when exposed to extreme heat. SPECIAL FIREFIGHTING PROCEDURES: Containers can build up pressure if exposed to heat (fire). As in any fire, wear self-contained breathing apparatus pressure-demand (MSHA/NIOSH approved or equivalent) and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. Water spray may be used for cooling containers to prevent possible pressure build-up and auto-ignition or explosion when exposed to extreme heat. I SECTION V - HEALTH HAZARD DATA I EFFECTS OF OVEREXPOSURE - EYE CONTACT: Liquid, aerosols and vapors of this product are irritating and can cause pain, tearing, reddening and swelling accompanied by a stinging sensation and/or a feeling like that of fine dust in the eyes. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). EFFECTS OF OVEREXPOSURE - INHALATION: Headaches, dizziness, nausea, decreased blood pressure, changes in heart rate and cyanosis (characterized by bluish discoloration of the skin and nails) may result from over-exposure to vapor or skin exposure. EFFECTS OF OVEREXPOSURE - INGESTION: This material may be harmful or fatal if swallowed. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for 15 minutes. Get immediate medical attention. FIRST AID - SKIN CONTACT: Immediately flush skin with plenty of water. Wash with soap and water. Remove soiled clothing. Wash clothing separately before reuse. Get medical attention if irritation develops or persists. FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Page 103 of 1235 Page 103 of 1235 Page 103 of 1235 Page 103 of 1235 ---PAGE BREAK--- (Continued on Page 3) Product: E&I 30 14 AEC Preparation Date: 05/30/02 Page 3 I SECTION V - HEALTH HAZARD DATA I FIRST AID - INGESTION: NOTE TO PHYSICIAN: This product contains methanol which can cause intoxication and central nervous system depression. Methanol is metabolized to formic acid and formaldehyde. These metabolites can cause metabolic acidosis, visual disturbances and blindness. Since metabolism is required for these toxic their onset may be delayed from 6 to 30 hours following ingestion. Ethanol competes for the same metabolic pathway and has been used to prevent methanol metabolism. Ethanol administration is indicated in patients or at methanol concentrations above 20 UG/DL. Methanol is effectively removed by hemodialysis. Keep person warm, quiet and get immediate medical attention. Do NOT induce vomiting, because aspiration of material into the lungs from vomiting can cause chemical pneumonitis which can be fatal. PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT SKIN ABSORPTION INHALATION INGESTION EYE CONTACT I SECTION VI - REACTIVITY DATA I HAZARDOUS DECOMPOSITION PRODUCTS: Hazardous decomposition products: CO, CO2 and Nox. CONDITIONS TO AVOID: Heat, sparks and open flames. INCOMPATABILITY: Avoid contact with: strong oxidizing agents. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. I SECTION VII - SPILL OR LEAK PROCEDURES I STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Evacuate all non-essential personnel. Remove all sources of ignition. Ventilate the area. Equip employees with appropriate protection equipment. Dike around spilled material. Cover spill with absorbent material and shovel with non-sparking tools into container. Remove containers to safe area and seal. Avoid runoff into storm sewers and ditches which lead to waterways. WASTE DISPOSAL METHOD: Dispose of in accordance with State and Federal laws. Do not discharge into waterways without proper authority. I SECTION VIII - SAFE HANDLING AND USE INFORMATION I RESPIRATORY PROTECTION: A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is Page 104 of 1235 Page 104 of 1235 Page 104 of 1235 Page 104 of 1235 ---PAGE BREAK--- (Continued on Page 4) Product: E&I 30 14 AEC Preparation Date: 05/30/02 Page 4 I SECTION VIII - SAFE HANDLING AND USE INFORMATION I limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. VENTILATION: Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product. SKIN PROTECTION: Where contact is likely, wear chemical resistant gloves, a chemical suit and rubber boots. EYE PROTECTION: Do not wear contact lenses. Wear safety glasses with side shields or goggles. OTHER PROTECTIVE EQUIPMENT: Where splashing is possible, full chemically resistant protective clothing and boots are required. HYGENIC PRACTICES: Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor Liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Wash hands before eating or smoking. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid prolonged or repeated contact with skin. Avoid breathing vapors from heated material. Avoid contact with eyes, skin, and clothing. I SECTION IX - SPECIAL PRECAUTIONS I PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store away from incompatible substances. Wash thoroughly after handling. Keep away from heat, sparks and flame. Keep container closed when not in use. OTHER PRECAUTIONS: Do not inhale mist or vapor. Keep out of reach of children. Apply with back to wind during outdoor application. I SECTION X - HMIS RATINGS I HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 3 REACTIVITY: 1 I SECTION XI - OTHER REGULATIONS I (Continued on Page 5) Product: E&I 30 14 AEC Preparation Date: 05/30/02 Page 5 I SECTION XI - OTHER REGULATIONS I Page 105 of 1235 Page 105 of 1235 Page 105 of 1235 Page 105 of 1235 ---PAGE BREAK--- SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER WT/WT % IS LESS THAN Methyl Alcohol 67-56-1 15.0 % PREVIOUS MSDS REVISION DATE: 01/28/97 LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined **The Nelson Paint Company, Inc. (TNPC) expressly disclaims all expressed or implied warranties of merchantability and fitness for a particular purpose, with respect to the product or information provided herein.** All information appearing herein is based upon data obtained from the manufacturer and/or recognized technical sources. While the information is believed to be accurate, TNPC makes no representations as to its accuracy or sufficiency. Conditions of use are beyond TNPC’s control and therefore users are responsible to verify this data under their own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use, handling, and disposal of the product, or from the publication or use of, or reliance upon, information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process. Page 106 of 1235 Page 106 of 1235 Page 106 of 1235 Page 106 of 1235 ---PAGE BREAK--- Page 1 of 3 Material Safety Data Sheet MSDS 001, February 14, 2011 1. PRODUCT IDENTIFICATION Emergency Phone Number: 312/807-2000 Chemical Name: Sodium Chloride Common Name: Salt CAS Number: 7647-14-5 Chemical Formula: NaCl Product Names (Salt w/o additives): All Purpose Purex Salt California Pure Fine Sea Salt California Pure Medium Sea Salt California Pure Coarse Sea Salt Canning & Pickling Salt Commercial Grade, Water Softening Pellets Culinox 999 Chemical Grade Salt Culinox 999 Fine Salt Culinox 999 Food Grade Salt Evaporated Granulated Salt Evaporated Salt Pellets Fine Mixing Salt Hay & Stock Salt, F&R H.G. Blending Salt Industrial Crude Solar Salt KD Crude Solar Salt Kleer Fine Salt Kleer Granulated Salt Mill Run Salt Northern Fine +20 Rock Salt (Northern Rock) Feed Mixing Salt, F & R Purex Salt Purex Select Salt Reagent Grade Sodium Chloride Refined Sea Salt Rock Pretzel Salt Rock Salt for Making Ice Cream Safe-T-Salt (bagged only) Select Extra Coarse Rock Salt Service Pack Salt (all) Ship n' Shore Rock Salt Stock Salt USP Sodium Chloride Valu-Soft Solar Salt White Rock Salt (all) White Solar Salt (all) White Water Softening Solar Salt (all) 2. COMPOSITION / INFORMATION ON INGREDIENTS Formula CAS # % Sodium Chloride NaCl 7647-14-5 100* *Including small quantities of naturally occurring moisture and calcium/magnesium salts 3. HEALTH HAZARD DATA Effects of Overexposure: Ingestion: Very large doses can cause vomiting, diarrhea, and prostration. Oral toxicity rat LD50: 3000 mg / kg. Skin Contact: Mild skin irritant. Eye Contact: Moderate irritant. Inhalation: Inhalation of dust may cause mild irritation to mucous membranes, nose and throat. may include coughing, dryness and sore throat. Acute Systemic Effects: Dehydration and congestion may occur in internal organs. Hypertonic salt solutions can produce inflammatory reactions in the gastrointestinal tract. Chronic Systemic Effects: No information found. 4. EMERGENCY AND FIRST AID PROCEDURES Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Call a physician if irritation persists. Skin Contact: Wash exposed area with soap and water. Get medical advice if irritation develops. Hazard Rating (0=None, 4=Extreme) n Health m Flammability m Reactivity Page 107 of 1235 Page 107 of 1235 Page 107 of 1235 Page 107 of 1235 ---PAGE BREAK--- MSDS 001 Page 2 of 3 Morton Salt, Inc.• 123 N. Wacker Drive • Chicago, IL 60606-1743 Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty. Ingestion: If large amounts were swallowed, get medical advice. 5. FIRE AND EXPLOSION HAZARD DATA Product is non-combustible; no extinguishing media or special fire-fighting procedures are required. There are no unusual fire or explosion hazards. 6. REACTIVITY DATA Stability: X Stable Unstable Stable and inert under normal conditions. No hazardous polymerization can occur. No hazardous decomposition products or conditions. Materials to Avoid: Will react with strong acids (to generate hydrogen chloride) and strong oxidizing agents (to generate chlorine gas). 7. PHYSICAL DATA Appearance: Colorless or white Odor: None Density (Water = 2.165 g / cc Solubility in Water: 36 g / 100 cc water at 20°C (68°F) pH: About 7 % Non-Volatile: 100 Vapor Pressure (mm Hg): 1 mm @ 865°C (1589°F) Boiling Point (760 mm Hg): 1413°C (2575°F) 8. SPILL OR LEAK PROCEDURES Response to Small Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. Response to Large Spills: Shovel and sweep up; containerize for reclamation or disposal. Hazards to be Avoided: None. Reportable Quantity: Check your state for requirements. Waste Classification: Some states have set maximum limits on chlorides in waste effluent. Disposal Methods: Whatever cannot be saved for reclamation may be delivered to an approved waste disposal facility or if local ordinances allow, can be dissolved in sufficient amounts of water to meet water quality standards, and flushed down a sewer drain. Ensure compliance with local, state and federal regulations. Page 108 of 1235 Page 108 of 1235 Page 108 of 1235 Page 108 of 1235 ---PAGE BREAK--- MSDS 001 Page 3 of 3 Morton Salt, Inc.• 123 N. Wacker Drive • Chicago, IL 60606-1743 9. SPECIAL PROTECTION INFORMATION Respiratory Protection: For conditions of use where exposure to the dust is apparent, a NIOSH approved dust/mist respirator may be worn. For emergencies, a self-contained breathing apparatus may be necessary. For Hands, Body: If deemed necessary, wear protective gloves and clean body-covering clothing. For Eyes: If deemed necessary, use chemical safety glasses or goggles. Contact lenses should not be worn when working with this material. Eye wash fountain or water for eyewashing should be available. Ventilation: In general, dilution ventilation is a satisfactory health hazard control for this substance. However, if conditions of use create discomfort to the worker, a local exhaust system should be considered. 10. SPECIAL PRECAUTIONS Transport in dry equipment; store in dry location. Handling procedures should minimize generation of airborne dust. Dust respirator as appropriate where exposure exceeds the 10 mg/m2 ACGIH TLV for nuisance dust. 11. LABELING INFORMATION DOT Shipping Name: Salt (common), sodium chloride DOT Label: Not applicable UN No.: Not applicable Additional Product Label: Not applicable Warning: None 12. USER’S RESPONSIBILITY The responsibility to provide a safe workplace remains with the user. The user should consider the health hazards and safety information contained herein as a guide and should take those precautions required in an individual operation to instruct employees and develop work practice procedures for a safe work environment. The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by use of this material. It is the responsibility of the user to comply with all applicable federal, state, and local laws and regulations. Nothing contained herein is to be construed as a recommendation for use in violation of any patents or of applicable laws or regulations. Page 109 of 1235 Page 109 of 1235 Page 109 of 1235 Page 109 of 1235 ---PAGE BREAK--- Page 110 of 1235 Page 110 of 1235 Page 110 of 1235 Page 110 of 1235 ---PAGE BREAK--- Page 111 of 1235 Page 111 of 1235 Page 111 of 1235 Page 111 of 1235 ---PAGE BREAK--- Page 112 of 1235 Page 112 of 1235 Page 112 of 1235 Page 112 of 1235 ---PAGE BREAK--- Page 113 of 1235 Page 113 of 1235 Page 113 of 1235 Page 113 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET HMIS Antibacterial SCRUBBING BUBBLES Bathroom Cleaner NFPA Personal protective equipment 4 1 Version Number: 2 Health 4 Preparation date: 2011-04-27 Reactivity 0 0 1 Fire Hazard None / Aucune / Ninguno 112-34-5 5 - 10% 3384 2700 mg/kg Not available MSDS Isobutane 75-28-5 5 - 10% Not available Not available 658 mg/L (4 h) MS0500042 Principal routes of exposure: Skin contact. Inhalation. Eye contact. Emergency telephone number: 4. FIRST AID MEASURES 1-[PHONE REDACTED] 1-[PHONE REDACTED] (Int'l) Eye contact: May be mildly irritating to eyes. Eye contact: Flush immediately with plenty of water. If irritation develops, get medical attention. Product name: Skin contact: Skin contact: Flush immediately with plenty of water. If irritation develops, get medical attention. May be mildly irritating to skin. Inhalation: No specific first aid measures are required. Inhalation: Ingestion: No specific first aid measures are required. None Product Code: Aggravated Medical Conditions: None known 2. HAZARDS IDENTIFICATION Ingestion: None known. 94308 5. FIRE-FIGHTING MEASURES Antibacterial SCRUBBING BUBBLES Bathroom Cleaner Suitable extinguishing media: Dry chemical, water spray, foam, carbon dioxide. 3. COMPOSITION/INFORMATION ON INGREDIENTS 1. PRODUCT AND COMPANY IDENTIFICATION Specific hazards: Aerosol product - Containers may rocket or explode in heat of fire. NFPA 30B Level 1 Aerosol . Unusual hazards: None known Recommended use: Ingredient(s) CAS # Weight % LD50 Oral - Rat (mg/kg) LD50 Dermal - Rabbit LC50 Inhalation - Rat Cleaning product. Industrial/Institutional. Restroom Care. Diethylene glycol butyl ether 1 of 4 Manufacturer, importer, supplier: US Headquarters Diversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-1964 Phone: 1-[PHONE REDACTED] MSDS Internet Address: www.diversey.com Antibacterial SCRUBBING BUBBLES Bathroom Cleaner EMERGENCY OVERVIEW CAUTION. MAY BE MILDLY IRRITATING TO EYES. MAY BE MILDLY IRRITATING TO SKIN. Page 114 of 1235 Page 114 of 1235 Page 114 of 1235 Page 114 of 1235 ---PAGE BREAK--- Isobutane 75-28-5 1000 ppm (TWA) Engineering measures to reduce exposure: No special ventilation requirements General room ventilation is adequate 7. HANDLING AND STORAGE 9. PHYSICAL AND CHEMICAL PROPERTIES Personal Protective Equipment Specific methods: Personal precautions: Eye protection: No special requirements under normal use conditions. Handling: Avoid contact with skin and eyes. FOR COMMERICAL AND INDUSTRIAL USE ONLY. Use personal protective equipment Flame Extension (inches): 0 Hand protection: Explosion limits: - upper: Not determined - lower: Not determined No special requirements under normal use conditions Storage: Protect from freezing. Keep closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN. * - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 Skin and body protection: No special requirements under normal use conditions. 10. STABILITY AND REACTIVITY Extinguishing media which must not be used for safety reasons: No information available Environmental precautions and clean-up methods: Stability: The product is stable Respiratory protection: Polymerization: Hazardous polymerization does not occur No special requirements under normal use conditions. Hazardous decomposition products: None reasonably foreseeable. Remove all sources of ignition. Soak up with inert absorbent material. Shovel into suitable container for disposal. Use a water rinse for final clean-up. Materials to avoid: Acids. Strong oxidising agents. Do not mix with any other product or chemical. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. 11. TOXICOLOGICAL INFORMATION No special methods required 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Acute toxicity: Oral Dermal LD50 estimated to be greater than 5000 mg/kg 6. ACCIDENTAL RELEASE MEASURES Component Information: See Section 3 Ingredient(s) CAS # ACGIH OSHA Mexico Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Bulk density: No information available Autoignition temperature: No information available Solubility in other solvents: No information available Odor: Fresh Elemental Phosphorus: 0 % by wt. Melting point/range: Not determined Appearance: Viscous liquid Physical State: Aerosol Flash point: 19 °F -7 °C VOC: 6.1 % * Solubility: Completely Soluble Vapor density: No information available Evaporation Rate No information available Decomposition temperature: Not determined pH: Not applicable Partition coefficient (n-octanol/water): No information available Boiling point/range: Not determined Density: 8.67 lbs/gal 1.04 Kg/L Color: Clear 2 of 4 Dilution pH: No information available. Antibacterial SCRUBBING BUBBLES Bathroom Cleaner Specific gravity: 1.04 Viscosity:No information available Page 115 of 1235 Page 115 of 1235 Page 115 of 1235 Page 115 of 1235 ---PAGE BREAK--- California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 Environmental Information: Container Disposal: Pesticide product disposal requirements vary by package size and type. Pesticides include disinfectants and sanitizers. See product label for complete disposal instructions. Always dispose of according to all federal, state and local applicable regulations. No data available Reproductive toxicity: CERCLA/ SARA None known SARA 311/312 Hazard Categories Target organ effects: Immediate: X 13. DISPOSAL CONSIDERATIONS None known Delayed: - Carcinogenic effects: Fire: X None known Reactivity: - Do not contaminate water, food, or feed by storage or disposal Sudden Release of Pressure: X None known 15. REGULATORY INFORMATION 16. OTHER INFORMATION Reason for revision: Not applicable Pesticide Storage: Store in original container in areas inaccessible to children. Open dumping is prohibited. Do not reuse empty container Prepared by: NAPRAC International Inventories at CAS# Level Mutagenic effects: Additional advice: Contains an added fragrance, see "Odor" heading in section 9 for specific description. 12. ECOLOGICAL INFORMATION All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL). None known Specific effects Pesticide Disposal: Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal Law U.S. Regulations Chronic toxicity: EPA Reg. No. : 70627-59 DOT/TDG/IMDG: Please refer to the Diversey HazMat Library, http://naextranet.diversey.com/dot/, for up to date shipping information. 14. TRANSPORT INFORMATION 3 of 4 Antibacterial SCRUBBING BUBBLES Bathroom Cleaner Page 116 of 1235 Page 116 of 1235 Page 116 of 1235 Page 116 of 1235 ---PAGE BREAK--- Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Antibacterial SCRUBBING BUBBLES Bathroom Cleaner 4 of 4 Page 117 of 1235 Page 117 of 1235 Page 117 of 1235 Page 117 of 1235 ---PAGE BREAK--- Page 118 of 1235 Page 118 of 1235 Page 118 of 1235 Page 118 of 1235 ---PAGE BREAK--- Page 119 of 1235 Page 119 of 1235 Page 119 of 1235 Page 119 of 1235 ---PAGE BREAK--- Page 120 of 1235 Page 120 of 1235 Page 120 of 1235 Page 120 of 1235 ---PAGE BREAK--- Page 121 of 1235 Page 121 of 1235 Page 121 of 1235 Page 121 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET B30WV100 03 00 Section 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER HMIS CODES Health 2* B30WV100 Flammability 0 Reactivity 0 PRODUCT NAME ARISTA™ 100% Exterior Latex Flat Paint, White Base MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. THE SHERWIN-WILLIAMS COMPANY (216) 566-2917 101 Prospect Avenue N.W. Cleveland, OH 44115 DATE OF PREPARATION INFORMATION TELEPHONE NO. 18-APR-07 (216) 566-2902 Section 2 COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE 1 14464-46-1 Cristobalite ACGIH TLV 0.05 mg/m3 as Resp. Dust OSHA PEL 0.05 mg/m3 as Resp. Dust 18 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction Section 3 HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE May cause allergic skin reaction in susceptible persons or skin sensitization. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Continued on page 2 Page 122 of 1235 Page 122 of 1235 Page 122 of 1235 Page 122 of 1235 ---PAGE BREAK--- B30WV100 page 2 Section 4 FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. Section 5 FIRE FIGHTING MEASURES FLASH POINT LEL UEL Not Applicable N.A. N.A. FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Section 7 HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Continued on page 3 Page 123 of 1235 Page 123 of 1235 Page 123 of 1235 Page 123 of 1235 ---PAGE BREAK--- B30WV100 page 3 Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. Section 9 PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 11.45 lb/gal 1371 g/l SPECIFIC GRAVITY 1.38 BOILING POINT 212 - 500 F 100 - 260 C MELTING POINT Not Available VOLATILE VOLUME 62 % EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 9.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.62 lb/gal 74 g/l Less Water and Federally Exempt Solvents 0.25 lb/gal 30 g/l Emitted VOC Continued on page 4 Page 124 of 1235 Page 124 of 1235 Page 124 of 1235 Page 124 of 1235 ---PAGE BREAK--- B30WV100 page 4 Section 10 STABILITY AND REACTIVITY STABILITY Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Section 11 TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung cancer, however, such exposure levels are not attainable in the workplace. TOXICOLOGY DATA CAS No. Ingredient Name 14464-46-1 Cristobalite LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available Section 12 ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Section 13 DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Continued on page 5 Page 125 of 1235 Page 125 of 1235 Page 125 of 1235 Page 125 of 1235 ---PAGE BREAK--- B30WV100 page 5 Section 14 TRANSPORT INFORMATION US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. Section 15 REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Section 16 OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 126 of 1235 Page 126 of 1235 Page 126 of 1235 Page 126 of 1235 ---PAGE BREAK--- Page 127 of 1235 Page 127 of 1235 Page 127 of 1235 Page 127 of 1235 ---PAGE BREAK--- Page 128 of 1235 Page 128 of 1235 Page 128 of 1235 Page 128 of 1235 ---PAGE BREAK--- Safety Data Sheet The Armor All/STP Products Company The Armor All/STP Products Company The Armor All/STP Products Company The Armor All/STP Products Company 44 Old Ridgebury Road Suite 300 Danbury, CT 06810 Tel. 1-[PHONE REDACTED] ARMOR ALL® Original Protectant Page 1 of 5 1. Product And Company Identification Product Name: ARMOR ALL® Original Protectant Responsible Party: The Armor All/STP Products Company 44 Old Ridgebury Road Suite 300 Danbury, CT 06810 Information Phone Number: +1 [PHONE REDACTED] Emergency Phone Number: For Medical Emergencies, call 1-[PHONE REDACTED] / +1 [PHONE REDACTED] (Outside US and Canada) For Transportation Emergencies, call 1-[PHONE REDACTED] (Chemtrec) +1-[PHONE REDACTED] for Outside US and Canada (call collect) SDS Date Of Preparation: 01/31/2015 Product Use and Uses Advised Against: Automotive maintenance product – For consumer and professional use 2. Hazards Identification Note: This product is a consumer product and is labeled in accordance with the Consumer Product Safety Commission regulations and not OSHA regulations. The requirements for the labeling of consumer products take precedence over OSHA labeling so the actual product label will differ from the OSHA information shown below. GHS Classification: Physical: Health: Not Hazardous Not Hazardous GHS Label Elements: None Hazards not otherwise specified: None Percentage of unknown toxicity: N/a 3. Composition/Information On Ingredients Component CAS No. Amount Non-Hazardous Ingredients Mixture 95> - 100% Mineral Oil 8042-47-5 < 5% The specific identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. 4. First Aid Measures Inhalation: If of exposure develop, remove to fresh air. Seek medical attention if persist. Skin Contact: Rinse skin with plenty of water. If skin irritation or redness develops, seek medical attention. Eye Contact: Flush eyes with plenty of water. If irritation or other persist, seek medical attention. Page 129 of 1235 Page 129 of 1235 Page 129 of 1235 Page 129 of 1235 ---PAGE BREAK--- Safety Data Sheet The Armor All/STP Products Company The Armor All/STP Products Company The Armor All/STP Products Company The Armor All/STP Products Company 44 Old Ridgebury Road Suite 300 Danbury, CT 06810 Tel. 1-[PHONE REDACTED] ARMOR ALL® Original Protectant Page 2 of 5 Ingestion: Do not induce vomiting unless directed to by doctor or physician. If the victim is fully conscious, have them drink a glass of water. Get medical assistance by calling a doctor or poison center. Never give anything by mouth to a person who is unconscious or drowsy. Most Important Direct eye contact may cause mild irritation. Indication of Immediate Medical Attention/Special Treatment: Immediate medical attention should not be required. 5. Firefighting Measures Suitable (and Unsuitable) Extinguishing Media: Use dry chemical, carbon dioxide, foam, or water spray. Specific Hazards Arising from the Chemical: Closed containers may rupture if exposed to extreme heat. Thermal decomposition will generate oxides of carbon and silicon and formaldehyde. Special Protective Equipment and Precautions for Fire-fighters: Firefighters should wear positive pressure self- contained breathing apparatus and full protective clothing for fires in areas where chemicals are used or stored. 6: Accidental Release Measures Personal Precautions, Protective Equipment, and Emergency Procedures: Wear appropriate protective equipment. Environmental Precautions: Prevent entry in storm sewers and waterways. Report spill as required by local and national regulations. Methods for Containment and Clean-Up: Absorb with an inert material. Collect into a suitable container for disposal. Rinse area with water. 7. Handling and Storage Precautions for Safe Handling: Avoid contact with eyes. Avoid prolonged contact with skin and clothing. Wash hands after use. Keep out of the reach of children. Conditions for Safe Storage, Including any Incompatibilities: No special storage required. 8. Exposure Controls / Personal Protection Exposure Guidelines: CHEMICAL EXPOSURE LIMIT Non-Hazardous Ingredients None Established Mineral Oil 5.0 mg/m3 inhalable TWA ACGIH TLV 5.0 mg/m3 TWA OSHA PEL Engineering Controls: General ventilation should be adequate for all normal use. Personal Protective Equipment Page 130 of 1235 Page 130 of 1235 Page 130 of 1235 Page 130 of 1235 ---PAGE BREAK--- Safety Data Sheet The Armor All/STP Products Company The Armor All/STP Products Company The Armor All/STP Products Company The Armor All/STP Products Company 44 Old Ridgebury Road Suite 300 Danbury, CT 06810 Tel. 1-[PHONE REDACTED] ARMOR ALL® Original Protectant Page 3 of 5 Respiratory Protection: None required under normal use conditions. Gloves: None required under normal use conditions. Eye Protection: None required for normal use. Avoid eye contact. Other Protective Equipment/Clothing: None required under normal use conditions. 9. Physical and Chemical Properties Appearance and Odor: Opaque, white viscous liquid with a slight odor. Physical State: Liquid Odor Threshold: Not available pH: 7.5 - 9.0 Specific Gravity: ~1 Initial Boiling Point/Range: Not determined Vapor Pressure: Not determined Melting/Freezing Point: Not determined Vapor Density: Not determined Solubility In Water: Easily soluble Percent Volatile: >80% Viscosity: ~ 3,000 cP Evaporation Rate: Not determined Coefficient Of Water/Oil Distribution: Not determined VOC Content: Not determined Flash Point: >212°F (>100°C) Autoignition Temp: Not determined Decomposition Temperature: Not determined Flammability Limits: LEL: Not determined UEL: Not determined Flammability (solid, gas): Not applicable 10. Stability and Reactivity Reactivity: Not normally reactive Chemical Stability: Stable. Possibility of Hazardous Reactions: None known Conditions To Avoid: None known Incompatible Materials: Strong oxidizing agents. Hazardous Decomposition Products: Thermal decomposition will generate oxides of carbon, silicon dioxide, and formaldehyde. 11. Toxicological Information POTENTIAL HEALTH EFFECTS: Acute Hazards: Inhalation: No adverse effects expected from the normal use of this product. Skin Contact: No adverse effects expected from the normal use of this product. Eye Contact: Direct contact may cause slight eye irritation. Ingestion: Swallowing may cause gastrointestinal disturbances. Page 131 of 1235 Page 131 of 1235 Page 131 of 1235 Page 131 of 1235 ---PAGE BREAK--- Safety Data Sheet The Armor All/STP Products Company The Armor All/STP Products Company The Armor All/STP Products Company The Armor All/STP Products Company 44 Old Ridgebury Road Suite 300 Danbury, CT 06810 Tel. 1-[PHONE REDACTED] ARMOR ALL® Original Protectant Page 4 of 5 Chronic Hazards: None currently known. Carcinogenicity Listing: None of the components is listed as a carcinogen or potential carcinogen by IARC, NTP, ACGIH or OSHA. Acute Toxicity Values: No data available for product. Mineral Oil: LD50 Rat oral > 5,000 mg/kg LD50 Rabbit dermal > 2,000 mg/ kg LC50 Rat inhalation > 5,000 mg/L/4 hr. 12. Ecological Information Ecotoxicity: No ecotoxicity data is currently available for product. Mineral Oil: NOEL mykiss 100 mg/L/96 hr. NOEL Daphnia magna>= 100 mg/L/96 hr. Persistence and Degradability: No data available Bio accumulative Potential: No data available Mobility in Soil: No data available Other Adverse Effects: No data available 13. Disposal Considerations Dispose of in accordance with all local, state/provincial and federal regulations. Offer empty containers for recycling. 14. Transport Information DOT Hazardous Materials Description: Not Regulated Canadian TDG Hazardous Materials Description: Not Regulated IMDG Dangerous Goods Description: Not Regulated 15. Regulatory Information United States: EPA TSCA INVENTORY: All of the components of this material are listed on the Toxic Substances Control Act (TSCA) Chemical Substances Inventory. Page 132 of 1235 Page 132 of 1235 Page 132 of 1235 Page 132 of 1235 ---PAGE BREAK--- Safety Data Sheet The Armor All/STP Products Company The Armor All/STP Products Company The Armor All/STP Products Company The Armor All/STP Products Company 44 Old Ridgebury Road Suite 300 Danbury, CT 06810 Tel. 1-[PHONE REDACTED] ARMOR ALL® Original Protectant Page 5 of 5 CERCLA Section 103: This product has no RQ, however, oil spills must be reported to the National Response Center. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. SARA Hazard Category (311/312): Not hazardous SARA 313: This product contains the following chemicals subject to Annual Release Reporting Requirements Under SARA Title III, Section 313 (40 CFR 372): None Canada: Canadian WHMIS Classification: Not a controlled product. Canadian Environmental Protection Act: All of the ingredients are listed on the Canadian DSL. This SDS has been prepared according to the criteria of the Controlled Products Regulation (CPR) and the SDS contains all of the information required by the CPR. 16. Other Information NFPA Rating (NFPA 704): Health: 0 Fire: 0 Instability: 0 HMIS Rating: Health: 0 Fire: 0 Physical Hazard: 0 REVISION SUMMARY: January 31, 2015 Update to GHS SDS format and name change: Changes to all sections. DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH Page 133 of 1235 Page 133 of 1235 Page 133 of 1235 Page 133 of 1235 ---PAGE BREAK--- II Health Hazard Data to skm an0 eyes Unoer normal cons,mer dse an0 cond.tlons. Armor All Products Company 1221 Broadway Material Safety Oakland, CA 94612 Tel. (510) 271-7000 Data Sheet I Product: ARMOR ALL PROTECTANT WIPES Description: WIPES MOISTENED WITH MILKY WHITE LIQUID. SLIGHT ODOR the likelihood of adverse health effects is low. NO medical conditions are known to be aggrevated by exposure to this product. Emergency Telephone Nos. For Medical Emergencies call: (800) 446-1014 For Trans~ortation Emergencies Chemtrac Other Designations FIRST AID: EYECONTACT: Remove contact Tenses. Rush eyes througmy with plenty of water for 15 minutes. If irritation occurs, get medical attention. Manufacturer Armor All Products Company 1221 Broadwav SKIN CONTACT: Wash area wlh soap and water. If irritation occurs, get medical attention. INGESTION: Drink a glassful of water. Get medical attention if effects occur. INHALATION: If breathing problems occur, remove to fresh air. IV Special Protection and Precautions Hyqenc Pract~ces: Wash nands wlth soap and water after use Enqineerinq Controls: Use general ventilation to minimize exposure to vapor or mists. Work PracnceL Av0.d eye and sen contact an0 mha~atlon of vapor or mlst Wear materlal resistant gloves 11 handling product for prolonged or repeated periods sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed down material. For spills of multiple products, responders should evaluate the MSDS's of the products for incompatibility with this product. Waste Dis~osal: Dispose of in accordance with all applicable federal, state and local regulations. Vlll Fire and Explosion Data Combustion: Non flammable or explosive. Fire Extinquishinq Aoents: Water, water fog, dry chemical, foam or carbon dioxide (CO,) fire extinguishers. If product has undergone partial or complete evaporation, may be combustible. a1963.1991 T DATA SUPPLIED IS FOR USE ONLY IN CONN U~ lg- Concentratmn Womer Expos~re L m 1 ;..!cone Emuls~on 30 - 40% Not establ~snea \ 94612 :AS # NIA ' (800) 424-9300 lone of the ingredients in this product are on the IARC. NTP or OSHA arcinogen lisf. II Hazardous lnaredients V Transportation and Regulatory Data IOTIIATAJIMO kot restricted rSCA Status: All ingredients in this product are listed on the TSCA nventory. EPA - SARA T~tle IlllCERCLA Packaged product s not reponable unoer Sectlons 31 11312 Conta.ns no chemicals regulated under CERLA Sectons 31 1, 312, 313, or 304 VII Reactivity Data Stable under nonal use and conditions. IX Physical Data Boilino Point 212"Fl100'C LOROX COMPANY 10N WfTH OCCUPATIONAL SAFETY AND HEALTH OATEPREPARED 6100 Page 134 of 1235 Page 134 of 1235 Page 134 of 1235 Page 134 of 1235 ---PAGE BREAK--- Page 135 of 1235 Page 135 of 1235 Page 135 of 1235 Page 135 of 1235 ---PAGE BREAK--- Page 136 of 1235 Page 136 of 1235 Page 136 of 1235 Page 136 of 1235 ---PAGE BREAK--- Page 137 of 1235 Page 137 of 1235 Page 137 of 1235 Page 137 of 1235 ---PAGE BREAK--- Page 138 of 1235 Page 138 of 1235 Page 138 of 1235 Page 138 of 1235 ---PAGE BREAK--- Page 139 of 1235 Page 139 of 1235 Page 139 of 1235 Page 139 of 1235 ---PAGE BREAK--- Page 140 of 1235 Page 140 of 1235 Page 140 of 1235 Page 140 of 1235 ---PAGE BREAK--- Page 141 of 1235 Page 141 of 1235 Page 141 of 1235 Page 141 of 1235 ---PAGE BREAK--- Page 142 of 1235 Page 142 of 1235 Page 142 of 1235 Page 142 of 1235 ---PAGE BREAK--- Page 143 of 1235 Page 143 of 1235 Page 143 of 1235 Page 143 of 1235 ---PAGE BREAK--- Item Number: 9L2 Page 02/28/2008 of 4 1 Material Safety Data Sheet Section 1: PRODUCT AND COMPANY IDENTIFICATION Vi-Jon Incorporated Phone: [PHONE REDACTED] 8515 Page Avenue In Case of Spill Emergency Contact: Saint Louis, MO 63114 Chemtrec: 1-[PHONE REDACTED] Product Name: Baby Powder Cornstarch Product Code: 9L2 Product Use: Baby Powder Issue Date: 02/28/08 Supersedes Date: None Section 2: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: Keep out of reach of children. Appearance/Odor: Various size, circular, transparent particles. Off white, matte powder with a sweet floral, baby powder fragrance. of Exposure: Inhalation: May cause irritation of the respiratory tract. Ingestion: May cause nausea, vomiting and diarrhea. Eyes: May cause irritation to the eyes. Skin: None expected. This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. This material does not contain any component s that are considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: COMPOSITION/INFORMATION ON INGREDIENTS There are no components that are considered a health hazard. Section 4: FIRST AID MEASURES Emergency first aid procedures by route of exposure: Inhalation: If are experience, remove source of contamination or move victim to fresh air. If affected person is not breathing, apply artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Page 144 of 1235 Page 144 of 1235 Page 144 of 1235 Page 144 of 1235 ---PAGE BREAK--- Item Number: 9L2 Page 02/28/2008 of 4 2 Ingestion: Do not induce vomiting. If the material is swallowed, get medical attention or advice. Skin: If irritation is experienced, rinse with soap and water. If persist, get medical attention. Eyes: Immediately flush eyes with water for at least 15 minutes while holding eyelids open. If persist, get medical attention. Section 5: FIRE FIGHTING MEASURES Flash Point: Not Available Method Used: Not Available Auto Ignition: Not Available Flammability Classification: Not Available Extinguishing Media: Use methods appropriate for the surrounding fire. Consider water spray or fog, carbon dioxide, dry chemical powder, or alcohol resistant foam. Products of Combustion: Upon decomposition this product may emit carbon dioxide, carbon monoxide and/or low molecular weight hydrocarbons. Fire Fighting Equipment/Instructions: Wear protective clothing and equipment suitable for the surrounding fire, including helmet, facemask, and self contained breathing apparatus. NFPA Rating: Health:0 Fire: 0 Reactivity:0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe Section 6: ACCIDENTAL RELEASE MEASURES Personal Precautions: For large spills wear gloves, safety glasses and when levels exceed OSHA PEL use appropriate NIOSH approved respiratory protection. Keep unnecessary personnel away. Methods for Clean-Up: Containerize in approved chemical waste container. Wash spill area with water. Section 7: HANDLING AND STORAGE Handling: Prevent contact with eyes. Avoid inhalation. Storage: Keep the container closed and in a cool, well ventilated place.. Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Starch (9005-25-8) ACGIH: 10 mg/m3 TWA OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Engineering Controls: Normal room ventilation is usually adequate under normal use. Personal Protective Equipment (PPE) Eye/Face Protection: None needed under normal use. Skin Protection: None needed under normal use. Respiratory Protection: None needed under normal use. General Hygiene Considerations: Wash hands after use. Page 145 of 1235 Page 145 of 1235 Page 145 of 1235 Page 145 of 1235 ---PAGE BREAK--- Item Number: 9L2 Page 02/28/2008 of 4 3 Section 9: PHYSICAL AND CHEMICAL PROPERTIES Appearance/Color:Off White Odor: Baby Powder Physical State:Powder pH: Not Available Vapor Density: Not Available Boiling Point: Not Available Vapor Pressure: Not Availalbe Melting Point: Not Available Freezing Point: Not Available Flash Point Not Available Flammability Properties Not Available Solubility (in water): Not Available Specific Gravity @ 25°C: not Available Evaporation Rate: Not Available Octanol/Water partition coefficient (Kow): Not Available Auto-ignition temperature: Not Available Decomposition temperature: Not Available Section 10: STABILITY AND REACTIVITY Stability: Stable under normal ambient temperatures 70°C (21°C) Condition to Avoid: Not Available Incompatible Materials: This product reacts with strong acid, strong bases, and oxidizing agents. Hazardous Decomposition: upon decomposition, this product evolves carbon monoxide, carbon dioxide, and/or low weight hydrocarbons. Hazardous Reactions: Hazardous polymerization will not occur. Section 11: TOXICOLOGY INFORMATION ACUTE EFFECTS: A: General Product information Not expected to cause irritation when used in accordance to label. CHRONIC EFFECTS: Component Starch (9005-25-8) Carcinogenicity: ACGIH A4 – Not Classifiable as a Human Carcinogen Neurotoxicity: No information available for product. Mutagenicity: No information available for product. Reproductive: No information available for product. Developmental: No information available for product. Target Organs: Starch can target the respiratory system, skin, and eyes. Page 146 of 1235 Page 146 of 1235 Page 146 of 1235 Page 146 of 1235 ---PAGE BREAK--- Item Number: 9L2 Page 02/28/2008 of 4 4 Section 12: ECOLOGICAL INFORMATION Ecotoxicity: no information available for product. Section 13: DISPOSAL CONSIDERATIONS Dispose of in accordance with federal, state, and local regulations. Section 14: TRANSPORTATION INFORMATION This material is not regulated as a hazardous material for transportation. Section 15: REGULATORY INFORMATION Starch (CAS 9005-25-8) is partially exempt chemical substance under 40 CFR 710.46 from the TSCA inventory. Tricalcium Phosphate (CAS 7758-87-4 ) is on the TSCA inventory. Section 16: Other Information Prepared by: Vi-Jon Inc. Disclaimer: The information and recommendations contained in the Material Safety Data Sheet (MSDS) are supplied pursuant to 29 CFR 1910.1200 of the Occupational Safety and Health Standards Hazard Communication Rule. The information and recommendations set forth herein are presented in good faith and believed to be correct as of this date hereof. Vi-Jon, however, makes no representation as to the completeness or accuracy thereof, and information is supplied upon the express condition that the persons receiving the information will be required to make their own determination as to its suitability for their purposes prior to use. In no event will Vi-Jon be responsible for any damages of any nature whatsoever resulting from the use of, reliance upon, or the misuse of this information. User assumes all risk of use, storage and handling of the product in compliance with applicable federal, state and local laws and regulations. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, OR OF ANY OTHER NATURE, ARE MADE BY VI-JON HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS. The information as supplied herein is simply to be informative and intended solely to alert the user of the substance which is the subject matter of this MSDS. The ultimate compliance with federal, state or local regulations concerning the use of this compound, or compliance with respect to product liability, rests solely upon the purchaser thereof. This information relates to the material designated and may not be valid for such material used in combination with any other materials nor in any process. Page 147 of 1235 Page 147 of 1235 Page 147 of 1235 Page 147 of 1235 ---PAGE BREAK--- Page 148 of 1235 Page 148 of 1235 Page 148 of 1235 Page 148 of 1235 ---PAGE BREAK--- Page 149 of 1235 Page 149 of 1235 Page 149 of 1235 Page 149 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET HMIS RATINGS Willert Product No. 310 Health Hazard: 2 Issue Date: 4/12/06 Flammability Hazard: 0 Supersedes: 2/21/06 Reactivity Hazard: 1 . Product Name: Bowl Fresh® Plus Oxygen Bleach (The information provided in this Material Safety Data Sheet is directed at occupational exposure and may not be applicable to consumer use of the product.) Willert Home Products, Inc. 4044 Park St. St. Louis, MO 63110 EMERGENCY TELEPHONE NUMBER: [PHONE REDACTED] (8:30 AM to 4:30 PM CST) CHEMTREC [PHONE REDACTED] SECTION 2: COMPONENT INFORMATION Hazardous Ingredients CAS Number Concentration in Product Sodium percarbonate 15630-89-4 <10% Sodium dodecylbenzene sulfonate 68081-81-2 <50% SECTION 3: HAZARDS IDENTIFICATION Emergency Overview: White fused cylinder. Harmful if swallowed. May be irritating to eyes and skin. Dust may cause respiratory tract irritation. Potential Health Effects: Relevant Routes Of Exposure: Inhalation, Ingestion, Eye Contact, Skin Contact. Acute Effects: Ingestion: May be harmful or fatal if swallowed. Eyes: Contact with the eyes can cause severe irritation and possibly eye burns. Inhalation: Dust can cause respiratory tract irritation. Skin: Repeated or prolonged could cause skin irritation. Carcinogenicity: None of the ingredients are listed by NTP, OSHA and IARC. Reproductive Effects: None expected. Target Organs: Ocular, respiratory, dermal, and gastrointestinal. Page 150 of 1235 Page 150 of 1235 Page 150 of 1235 Page 150 of 1235 ---PAGE BREAK--- Medical Conditions Aggravated By Exposure: None known. SECTION 4: FIRST AID PROCEDURES First Aid Procedures: EYES: Immediately flush eyes with a directed stream of water for at least 15 minutes, forcibly holding eyelids apart to ensure complete irrigation of all eye and lid tissue. Remove contact lenses, if present, after the first five minutes and continue rinsing the eye. Call a physician or poison control center immediately. SKIN: Immediately flush skin with plenty of water while removing contaminated clothing and shoes. Wash clothing before reuse. If irritation occurs, get medical attention. INHALATION: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. INGESTION: Do not give anything by mouth to an unconscious person. Call poison control center or doctor immediately for treatment advice. Have person rinse the mouth with water. If able to swallow, have the person sip a glass of water. DO NOT INDUCE VOMITING unless told to do so by a poison control center or doctor. SECTION 5: FIRE HAZARDS Unusual Fire and Explosion Hazards: None known. Fire Fighting Procedures: NIOSH approved positive pressure, self-contained breathing apparatus and full protective turn- out gear. Evacuate personnel to an area upwind to avoid smoke and vapors. Remove containers of this material if it can be done safely. Use water to keep fire exposed containers cool. Protective clothing and equipment must be decontaminated if contact with the material or vapors has occurred. Extinguishing Media: All common extinguishing media are suitable. Conditions to Avoid: Elevated temperatures. Hazardous Combustion Products: May produce irritating and toxic smoke and fumes. The composition of the combustion products has not been determined. Flash Point: Not determined. Flammability Limits: Lower: Not determined Upper: Not determined Autoignition Temperature: Not determined. SECTION 6: ACCIDENTAL RELEASE MEASURES Pre-Entry Spill Procedure: Shut off source of spill if it is safe to do so. Page 151 of 1235 Page 151 of 1235 Page 151 of 1235 Page 151 of 1235 ---PAGE BREAK--- Eliminate sources of ignition. Review Section 3 - Hazards Identification and Section 8- Exposure Control/Personal Protection before proceeding with the clean up. Clean Up and Containment: Scoop or shovel spilled material into suitable labeled containers with a tight fitting lid. Secure the drum cover and move the container to a safe holding area. Check area for residual material and repeat clean up if detected. Environmental Concerns: None known. Treatment and Disposal: Decontaminate or dispose of all protective clothing and equipment. See Section 13 - Disposal Recommendations for disposal information. Reporting Requirements: Report all releases which are likely to endanger the public health, harm the environment, or cause complaint to the appropriate State or Local officials. SECTION 7: HANDLING AND STORAGE General Measures: Store in a dry area at room temperature. Do not generate dust or exposure to ignition source. Keep away from heat, sparks, and flame. Materials or Conditions to Avoid: Contact with oxidizing, reducing agents, acids, alkalis, high temperature and moisture. Moisture and high humidity conditions. Elevated temperatures. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION General Hygienic Practices: Do not get on eyes, skin, or clothing. Do not breathe dust or fumes. Wash thoroughly after handling. Eyewear: Chemical goggles. Skin: Gloves are recommended if there is a potential for skin contact. A plastic or rubber glove which provides a physical barrier to the powder is required. Use disposable spun polyolefin (e.g. Tyvek) coveralls or equivalent to protect against contact. Consult the glove and clothing manufacturers, suppliers and/or industrial hygienist for further information. Respiratory Protection: Respiratory protection is required whenever air contamination (dust, mist, or vapors) is generated by the process. A NIOSH approved high efficiency toxic dust/mist/fume respirator is recommended. Page 152 of 1235 Page 152 of 1235 Page 152 of 1235 Page 152 of 1235 ---PAGE BREAK--- Work Practices and Engineering Controls: General room ventilation is adequate unless the process generates dust or fumes. Prevent the accumulation of dust in the work area by thorough periodic cleaning of the area. Protective Measures During Repair and Maintenance: No special measures are required. Follow the recommendation for personal protective equipment. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Physical State: Fused cylinder [1 inches diameter x 2.43 inches (long)]. Weight: 1.76 oz. (50g) Color: Light or sandy tan. Odor: Slight pleasant - lavender. Taste: Not determined. pH: Not determined. Volatile (Wt. or Vol.), Not determined. Moisture Content, (Wt.) Not determined. Solubility in Water: soluble in water. Solubility - other solvents: Not determined. . Specific Gravity/Bulk Density: Not determined. Vapor Pressure: Not determined. Vapor Density (air = Not determined. Evaporation Rate: < butyl acetate Boiling Point: Not determined. Melting Point: Not determined. SECTION 10: STABILITY AND REACTIVITY General Stability Considerations: Stable at room temperature. Incompatible Materials: Reducing agents, acids, alkalis, high temperature and moisture. Hazardous Decomposition Products: Not determined. Hazardous Polymerization: Does not occur. SECTION 11: TOXICOLOGICAL INFORMATION No data available on the formulated product. SECTION 12: ECOLOGICAL INFORMATION Environmental Fate: No data available Page 153 of 1235 Page 153 of 1235 Page 153 of 1235 Page 153 of 1235 ---PAGE BREAK--- Ecotoxicity: No data available. SECTION 13: DISPOSAL RECOMMENDATIONS Waste Disposal Method: Dispose of material, liners, and containers in accordance with all applicable federal, state, and local environmental regulations. SECTION 14: TRANSPORTATION INFORMATION U.S. DOT: Not regulated. SECTION 15: REGULATORY INFORMATION SARA TITLE III: Not applicable. California Proposition 65 List: None of the ingredients are listed. SECTION 16: OTHER INFORMATION None. Page 154 of 1235 Page 154 of 1235 Page 154 of 1235 Page 154 of 1235 ---PAGE BREAK--- Page 6 of 7 LIST OF ACRONYMS ACGIH: American Conference of Governmental Industrial Hygiene AIHA WEEL: American Industrial Hygienists Association - Workplace Environmental Exposure Level ANSI: American National Standards Institute C: Ceiling California Prop. 65: California Safe Drinking Water and Toxic Enforcement Act (Prop 65) Canadian WHMIS: Canadian Workplace Hazardous Materials Information System Ingredient Disclosure CASRN: Chemical Abstracts Service Registry Number CERCLA: Comprehensive Emergency Response, Compensation and Liability Act DOT: U. S. Department of Transportation HMIS: Hazardous Materials Identification System IARC: International Agency for Research on Cancer IATA: International Air Transport Association IMO: International Maritime Organization N/A: Not Applicable NOR: Not Otherwise Regulated NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration PEL: OSHA Permissible Exposure Limit RCRA: Resource Conservation and Recovery Act RQ: Reportable Quantity SARA: Superfund Amendment Reauthorization Act STEL: Short-Term Exposure Limit TLV: Threshold Limit Values (registered trademark of ACGIH) TPQ: Threshold Planning Quantity TSCA: Toxic Substances Control Act TWA: Time Weighted Average The information and recommendations contained in this Material Safety Data Sheet have been compiled from sources believed to be reliable and to represent the most reasonable current opinion on the subject when the MSDS was prepared. No warranty, guaranty, or representation is made as to the correctness or sufficiency of the information. The user of this product must decide what safety measures are necessary to safely use this product, either alone or in combination with other products, and determine its environmental regulatory compliance obligations under any applicable federal or state laws. Page 155 of 1235 Page 155 of 1235 Page 155 of 1235 Page 155 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SECTION I: IDENTITY Product/Material Name: BRP XP-S Mineral Two Stroke Injection Oil Chemical Name: Mixture Chemical Family/Classification: Petroleum hydrocarbon Molecular Weight: NA Chemical Formula: NA Material Use: Motor Oil (2-Stroke Oil) HMIS HAZARD RATING: [0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe] Health: 1 Flammability: 2 Reactivity: 0 WARNING STATEMENTS (If Applicable): CAUTION! COMBUSTIBLE LIQUID AND VAPOR. Avoid inhalation and skin contact. MANUFACTURER'S/ SUPPLIER NAME & ADDRESS: In the US : In Canada : In Latin America : BP Lubricants USA Inc. Castrol Canada Inc. Castrol Latin America Lubricants 1500 Valley Road 3660 Lakeshore Blvd. 3750 NW 87th Ave., Suite 600 Wayne, NJ 07474 Toronto (Ontario) M8W 1P2 Miami, FL 33178 Telephone : (973) 633-2200 Telephone : (416) 252-5511 Telephone : (305) 714-2640 Telecopier : (973) 633-7475 Telecopier : (416) 252-1774 Telecopier : (786) 437-6380 IN THE EVENT OF AN EMERGENCY PLEASE CALL: BP Emergency Response Center 1-[PHONE REDACTED] Date Prepared/Updated: 11/05/2007 Preparer: Regulatory, Environmental, Safety Department Telephone: (973) 633-2200 SECTION II: PRODUCT/HAZARDOUS INGREDIENT INFORMATION INGREDIENTS - CHEMICAL/COMMON NAME EXPOSURE LIMITS - TLV LD50 LC50 % Severely refined petroleum basestocks. May contain one or more of the following CASRN 72623-87-1; 64742-65-0; 64742-54-7; 64742-57-0 PEL/TWA: 5 mg/m3, mist (OSHA, ACGIH) STEL: 10 mg/m3, mist (ACGIH) Oral, rat: > 5 g/kg Inhalation, 4 hr., rat: > 5000 mg/m3 60-100 Petroleum distillate [CASRN 64742-47-8] 1250 mg/m3 recommended Oral, rat: > 8000 mg/kg Dermal, rat: > 4000 mg/kg Inhalation, 4 hr., rat: >37 ppm. 10-30 Multi-functional additive blend consisting of ashless dispersant, anti-oxidant and pour point depressant [CASRN NA, mixture] ND ND ND 5-10 Dye [CASRN NA, mixture] ND Oral, rat: >5000 mg/kg ND < 0.1 NOTE: Product contains no materials currently classified as carcinogenic per the Annual Report of the National Toxicology Program [NTP], OSHA Hazard Communication Standard or the International Agency for Research on Cancer [IARC, Groups 1, 2A or 2B]. Page 156 of 1235 Page 156 of 1235 Page 156 of 1235 Page 156 of 1235 ---PAGE BREAK--- PAGE 2 PRODUCT NAME: BRP XP-S Mineral Two Stroke Injector Oil NA - Not Applicable; ND - No Data Available SECTION III: FIRST AID MEASURES Transient eye irritation, redness, tearing. Eye contact: Flush with clear water for at least 15 minutes or until any irritation subsides. If irritation persists, seek medical attention. Skin contact: Remove contaminated clothing and wash before reuse. Wipe excess material from skin. Wash exposed area with soap and water. Inhalation: If irritation or drowsiness occur, move the person to fresh air. Administer respiratory assistance if breathing is difficult or stops; Consult a physician. Ingestion: Give plenty of water or other mild drinkable fluids and call a physician immediately. Do not induce vomiting without express consent of medical personnel. SECTION IV: HEALTH HAZARD DATA Exposure Limits: See Section II, Product/Ingredient Information. PRIMARY ROUTES OF ENTRY: Eye Contact Skin Contact [ ] Skin Absorption Inhalation (Acute) Inhalation (Chronic) [ ] Ingestion EFFECTS OF EXPOSURE Acute - (Evaluation based on components and/or similar products) Eyes: Contact may cause mild eye irritation. Not expected to cause prolonged or significant eye irritation. Skin: Contact may cause mild skin and irritation. Not expected to cause prolonged or significant skin irritation. Respiratory system: Vapors or mists in excess of permissible concentrations may cause irritation of nose and throat, headache, nausea Ingestion: Slight to moderate toxicity. Ingestion of small amounts may produce irritation and diarrhea. Ingestion of large amounts may cause generalized depression, headache, drowsiness, nausea, vomiting or diarrhea. Possible risk of aspiration of product into lungs. Chronic - Prolonged or repeated skin contact may cause skin drying, cracking, irritation, defatting and dermatitis. Repeated, excessive exposure to mists or fumes may induce pulmonary irritation or chronic bronchitis. The product contains petroleum baseoils which may be refined by various processes including severe solvent extraction, severe hydrocracking, or severe hydrotreating. None of the oils require a cancer warning under the OSHA Hazard Communication Standard [29 CFR 1910.1200]. These oils have not been listed in the National Toxicology Program (NTP) Annual Report nor have they been classified by the International Agency for Research on Cancer (IARC) as carcinogenic to humans (Group probably carcinogenic to humans (Group 2A) or possibly carcinogenic to humans (Group 2B). Medical Conditions Generally Aggravated by Exposure: Pre-existing skin disorders. TOXICOLOGY DATA (Product) Acute Data (Median Lethal Dose - species) Oral LD50 - rat: ND Dermal LD50 - rabbit: ND Inhalation LC50 - rat: ND Irritancy Data Eye irritation - rabbit: ND Skin irritation - rabbit: ND Sensitization - guinea pig: ND Other: No data regarding presence of carcinogenicity, tetragenicity, mutagenicity, respiratory toxicity, sensitizing ability or synergistic substances. Page 157 of 1235 Page 157 of 1235 Page 157 of 1235 Page 157 of 1235 ---PAGE BREAK--- PAGE 3 PRODUCT NAME: BRP XP-S Mineral Two Stroke Injector Oil NA - Not Applicable; ND - No Data Available SECTION V: EMPLOYEE PROTECTION Ventilation: No special ventilation is usually necessary. However, if operating conditions may create high airborne concentrations of this material, special or local ventilation may be needed. PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: None required under normal use. If exposure is expected to exceed occupational exposure limits, use a NIOSH-approved respirator to prevent overexposure. In accordance with 29 CFR 1910.134, use either an atmosphere supplying respirator or an air-purifying respirator for organic vapors and particulates. Eye: Safety goggles or glasses. Gloves (specify): Wear oil impervious type, such as neoprene, nitrile, to minimize skin contact. Clothing: No special requirement; Normal work clothing. A coverall or apron may be used to minimize skin contact Footwear: No special requirement. Other: NA Work/Hygienic Practices: Avoid prolonged and repeated skin contact. Do not wear contaminated clothing; Launder before reuse or discard. Wash thoroughly with soap and water after handling. Storage/Handling: Keep containers closed when not in use. Do not store near heat, sparks, flame or strong oxidants. Avoid breathing mist. Maintain adequate ventilation. Avoid prolonged or repeated contact with skin. Maintain storage below 150 degrees F (66 degrees SECTION VI: PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: ND Specific Gravity (Water=1): 0.86 to 0.87 Vapor Pressure (mm.Hg. @ 25 degrees ND Vapor Density (Air=1): > 1 Percent Volatiles: 10-30 % Evaporation Rate (BuAc=1): < 1 Solubility in Water: Negligible Freezing Point: -44 degrees F (-42 degrees C) pH-Value: NA Viscosity @ 40 C, cSt.: 24 - 38 typ. Odor Threshold: ND Coefficient of Water/Oil Distribution: ND Appearance, Odor & Physical State: Clear, amber liquid; mild petroleum odor SECTION VII: FIRE AND EXPLOSION DATA FLAMMABILITY Yes No [ ] NFPA Class IIIA material - Combustible liquid Flash Point (PMCC): 151 degrees F (66 degrees C) min. Fire Point (PMCC): ND Autoignition Temperature: ND Flammability limits in Air, % Vol.: Upper - 6.0 Lower - 1.0 Extinguishing Media: CO2, dry chemical, foam and water fog. Do not use water jets. Special Firefighting Procedures/Unusual and Explosion Hazards: Material must be preheated to burn. Do not enter confined areas without full protective equipment, including a positive pressure NIOSH approved self- contained breathing apparatus. Cool fire exposed containers with water. EXPLOSION DATA Sensitivity to Mechanical Impact: NA Sensitivity to Static Discharge: NA Page 158 of 1235 Page 158 of 1235 Page 158 of 1235 Page 158 of 1235 ---PAGE BREAK--- PAGE 4 PRODUCT NAME: BRP XP-S Mineral Two Stroke Injector Oil NA - Not Applicable; ND - No Data Available SECTION VIII: REACTIVITY Stability: Stable at ambient temperatures Hazardous Polymerization: Will not occur. Conditions and Materials to Avoid (Incompatibilities): Heat, open flame and oxidizing materials. Hazardous Combustion or Decomposition Products: Smoke, fumes, oxides of carbon SECTION IX: ENVIRONMENTAL PROTECTION CHEMTREC EMERGENCY PHONE NUMBER: (800) 424-9300, 24 hrs. for U.S. transportation related spills, leaks, fire, exposure or accident. Spill or Leak Procedures: Use best engineering practices when attempting cleanup of a large spill. Large spills - Wear respirator and protective clothing as appropriate. Remove sources of heat or ignition; Provide adequate ventilation. Stop source of leak if possible. Prevent entry into water sources. Dike and contain spill. Remove with vacuum trucks or pump to storage/salvage vessels. Soak up residue with an inert absorbent such as clay, sand or other suitable materials; Store and dispose of properly. Where feasible and appropriate, remove contaminated soil. Small spills - Soak up spill with an inert absorbent such as clay, sand or other suitable materials; Store in a closed container and dispose of properly. Provide adequate ventilation. Regulatory spill reporting requirements may apply; Contact governmental agency or legal counsel for advice. Waste Disposal Method: If discarded as supplied, material does not meet RCRA characteristic definition of ignitability, corrosivity or reactivity and is not listed in 40 CFR 261.33. The toxicity characteristic has not been evaluated. Under RCRA, the applicable hazardous waste classification must be evaluated prior to disposal of the material. Use of the product, processing or contamination may render the resulting material hazardous. All recovered material should be packaged, labeled, transported and disposed of or reclaimed in accordance with governmental regulations regarding air pollution, water pollution or health. Don't pollute - Conserve Resources. Dispose of used oil properly. CAUTION: Improper disposal or reuse of the empty container may be hazardous and illegal. Cutting or welding of empty containers may cause fire, explosion or toxic fumes from residues. Do not pressurize or expose to open flame or heat. Keep container closed and drum bungs in place. Refer to applicable governmental regulations. Page 159 of 1235 Page 159 of 1235 Page 159 of 1235 Page 159 of 1235 ---PAGE BREAK--- PAGE 5 PRODUCT NAME: BRP XP-S Mineral Two Stroke Injector Oil NA - Not Applicable; ND - No Data Available SECTION X: REGULATORY INFORMATION TRANSPORTATION Special Shipping Information/DOT Proper Shipping Name: When shipped in containers greater than 110 gallons US - Combustible liquid, NOS (petroleum distillates), 3, NA1993, PG III Follow all requirements regarding transportation of a regulated material. Not regulated under Canadian TDG Regulations CHEMICAL CONTROL REGULATIONS: TSCA Status: All components of this material appear on the U.S. Toxic Substance Control Act Chemical Substances Inventory. CEPA Status: All components of this product are in compliance with chemical notification requirements under the Canadian Environmental Protection Canadian Workplace Hazardous Material Identification System (WHMIS) Classification: Material is a controlled product. [ ] Class A - Compressed Gas [ ] Class B-1 - Flammable Gases [ ] Class B-2 - Flammable Liquids Class B-3 - Combustible Liquids [ ] Class B-4 - Flammable Solids [ ] Class B-5 - Flammable Aerosols [ ] Class B-6 - Reactive Flammable Materials [ ] Class C - Oxidizing Material Class D, Div.1 - Materials Causing Immediate and Serious Toxic Effects [ ] Class D-1A - Very Toxic Material [ ] Class D-1B - Toxic Material Class D, Div.2 - Materials Causing Other Toxic Effects [ ] Class D-2A - Very Toxic Materials [ ] Class D-2B - Toxic Materials [ ] Class D-3 - Biohazardous Infectious Material [ ] Class E - Corrosive Material [ ] Class F - Dangerously Reactive Material EPCRA - Emergency Planning and Community Right to Know Act (SARA Title III): Section 302/304 Extremely Hazardous Substance: NA CERCLA Section 102(a) Hazardous Substance: NA Section 311 Hazard Category [ ] Acute (immediate) [ ] Chronic (delayed) Fire [ ] Sudden Release of Pressure [ ] Reactive [ ] Not applicable Section 313 Toxic Release Inventory Chemical/Category: No toxic chemical is present above de minimis quantities. U.S. STATE RIGHT TO KNOW LAWS New Jersey Worker and Community Right to Know Act, N.J.A.C. 8:59-5 Labelling Information: Petroleum Oil (2-Stroke Oil). NOTICE: The information presented herein is compiled from sources considered to be dependable, believed to be accurate to the best of BP Lubricants USA Inc. knowledge, and offered in good faith for the purpose of hazard communication. Because product use is beyond our control, no warranty is given, expressed or implied. BP Lubricants USA Inc. cannot assume any liability for the use of information contained herein. To determine applicability or effect of any law or regulation with respect to the product, users should consult a legal advisor or appropriate governmental agency. Page 160 of 1235 Page 160 of 1235 Page 160 of 1235 Page 160 of 1235 ---PAGE BREAK--- SECTION 1 1 • IDENTIFICATION IDENTITY: Burgess Bug Killer Insect Fog EPA Registration No. 45385-27-53853 • Product Code: O-309 ACTIVE INGREDIENT CHEMICAL NAME: PYRETHRINS CHEMICAL FAMILY: Pyretheroid Sold By: The Fountainhead Group, Inc. / Burgess Products 23 Garden Street NY Mills, NY 13417 Prepared by: Bart Baker Date Prepared: January 16, 2004 HMIS Rating: Health: 1 Flammability: 1 Reactivity: 0 Protection: Safety Glasses & Rubber Gloves Emergency Telephone Number: 1-[PHONE REDACTED], CHEMTREC at 1-[PHONE REDACTED] or National Pesticide Telecommunications Network at 1-[PHONE REDACTED] or Telephone Number for Information: 9 AM to 5 PM EST - [PHONE REDACTED] SECTION 2 2 HAZARDOUS INGREDIENTS HAZARDOUS COMPONENTS CAS NUMBER Resmethrin* 10453-86-8 Conosol 260 64742-46-7 * REPORTABLE UNDER SARA SECT. 313 <-OSHA LIMITS OPTIONAL PEL STEL CEILING ACGIH TLV % N/A N/A N/A N/A 0.2 N/A N/A N/A N/A 99.5 SECTION 3 3 • PHYSICAL / CHEMICAL DATA BOILING POINT: N/A SOLUBILITY IN H2O: N/A APPEARANCE / ODOR: Light yellow liquid. Mineral Spirits odor. SPECIFIC GRAVITY: (Water = 0.793 VAPOR PRESSURE: (mm hg): N/A SECTION 4 4 • FIRE & EXPLOSION HAZARD DATA FLASH POINT: >250° F FLAMMABLE LIMITS: LEL: N/A UEL: N/A EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or CO2. SPECIAL FIRE FIGHTING PROCEDURES: Warning. Flammable. Clear fire area of unprotected personnel. Cool fire exposed containers. Use self-contained breathing apparatus for confined areas. EMERGENCY RESPONSE GUIDE No. 128 UNUSUAL FIRE & EXPLOSION HAZARDS: Cool containers exposed to intense heat with water to prevent container rupture from vapor pressure build-up. SECTION 5 5 • REACTIVITY DATA CHEMICAL STABILITY: Stable. Avoid heat, sparks and flame. CONDITIONS TO AVOID: Avoid sparks, heat, flame, strong oxidizing agents, alkali metal hydroxides. INCOMPATIBLE MATERIALS: Avoid strong oxidizing materials. DECOMPOSITION PRODUCTS: Carbon monoxide and unidentified organics may be formed during combustion. HAZARDOUS POLYMERIZATION: Will not occur SECTION 6 6 • HEALTH HAZARD DATA ROUTES OF ENTRY: INHALATION? SKIN? INGESTION? YES YES YES MATERIAL SAFETY DATA SHEET Burgess Bug Killer Insect Fog Page 161 of 1235 Page 161 of 1235 Page 161 of 1235 Page 161 of 1235 ---PAGE BREAK--- M ATERIAL S AFETY D ATA S HEET SECTION 6 6 • HEALTH HAZARD DATA (CONT.) HEALTH HAZARDS (ACUTE and CHRONIC): Liquid is irritating to eyes and skin. Inhalation of high concentration may cause CNS depression. Liquid is toxic and will be harmful if swallowed. CARCINOGENICITY: NTP? IARC MONOGRAPH? OSHA REGULATED? NO NO NO SIGNS & OF EXPOSURE: Irritation as noted above. Early CNS depression may be evidenced by headache, dizziness and nausea. In extreme case, death may occur. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye, skin and respiratory disorders. FIRST AID PROCEDURES: EYES: Flush with plenty of water. SKIN: Flush with water and remove contaminated clothing and shoes. INHALATION: Fresh air and oxygen if required. INGESTION: Do NOT induce vomiting. Get medical attention. SECTION 7 7 • PRECAUTIONS FOR SAFE HANDLING IN CASE MATERIAL IS RELEASED OR SPILLED: Keep liquid and vapor away from heat, sparks and flame. Shut off source of leak if safe to do so. Dike and contain. Clean up with absorbents. WASTE DISPOSAL METHOD: Waste material is considered hazardous under EPA-RCRA (40 CFR 261.33). Follow latest EPA or state regulations regarding proper disposal. HANDLING AND STORAGE: Keep liquid and vapor away from heat, sparks and flame. Empty containers can contain explosive vapors. Avoid static electricity by grounding equipment. OTHER PRECAUTIONS: Bond and ground transfer equipment. SECTION 8 8 • CONTROL MEASURES RESPIRATORY PROTECTION: Air purifying respirator for organic vapors or air-supplying respirator. VENTILATION: LOCAL EXHAUST: Use explosion-proof ventilation as required: MECHANICAL EXHAUST: Use explosion-proof ventilation as required. PROTECTIVE GLOVES: Chemical resistant. EYE PROTECTION: Safety glasses or goggles. OTHER PROTECTIVE EQUIPMENT: Use ventilation as required. WORK / HYGIENIC PRACTICES: Explosion-proof ventilation. Air dry contaminated clothing in a well ventilated area. SECTION 9 9 • SHIPPING INFORMATION Environmentally Hazardous Substances, liquid, N.O.S. (Resmethrin) HAZARD CLASS: Environmentally Hazardous Substance UN NUMBER: UN3082, PGIII Manufacture makes no warranty, express or implied, other than indicated on Label and MSDS. Customer assumes all risk of use and/or handling of this material when such use and / or handling is contrary to Label and MSDS Burgess Products EPA Registration No. 45385-27-53853 • Product Code: O-309 Page 2 D.O.T. Hazard Classification: Combustible Liquid Bill of lading Description: Chemicals, NOI All information contained in this Material Safety Data Sheet is furnished free of charge and is intended for your evaluation. In our opin- ion the information is, as of the date of this Material Safety Data Sheet, reliable, however, it is your responsibility to determine the suit- ability of the information for your use. You are advised not to construe the information as absolutely complete since additional informa- tion may be necessary or desirable when particular, exceptional or variable conditions or circumstances exist or because of applicable laws or government regulations. Therefore. you should use this information only as a supplement to other information gathered by you and you must make independent determinations of the suitability and completeness of the information from all source to assure both proper use of the material described herein and the safety and health of employees. Accordingly, no guarantee expressed, or implied is made by Burgess Products. as to the results to be obtained based upon your use of the information nor does Burgess Products assume any liability arising out of your use of the information. Page 162 of 1235 Page 162 of 1235 Page 162 of 1235 Page 162 of 1235 ---PAGE BREAK--- WestAir Gases & Equipment Inc page 1 of 5 Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved Generated: 08/03/2015 13:46:21 Safety Data Sheet Butane WestAir Gases & Equipment Inc 2506 Market St San Diego, CA 92102 [PHONE REDACTED] http://westairgases.com Section 1: Product and Company Identification WestAir Gases & Equipment Inc 2506 Market St San Diego, CA 92102 [PHONE REDACTED] http://westairgases.com Product Code: Butane Section 2: Hazards Identification Danger Hazard Classification: Flammable (Category 1) Gases Under Pressure Hazard Statements: Contains gas under pressure; may explode if heated Extremely flammable gas Precautionary Statements Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Response: Eliminate all ignition sources if safe to do so. Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Storage: Protect from sunlight. Store in well-ventilated place. Page 163 of 1235 Page 163 of 1235 Page 163 of 1235 Page 163 of 1235 ---PAGE BREAK--- WestAir Gases & Equipment Inc page 2 of 5 Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved Generated: 08/03/2015 13:46:21 Section 3: Composition/Information on Ingredients Chemical Substance Chemical Family Trade Names BUTANE hydrocarbons, aliphatic N-BUTANE; LIQUIFIED PETROLEUM GAS; NORMAL BUTANE; BUTYL HYDRIDE; LPG; UN 1011; C4H10 Section 4: First Aid Measures Skin Contact Eye Contact Ingestion Inhalation Note to Physicians If frostbite or freezing occur, immediately flush with plenty of lukewarm water (105-115 F; 41-46 DO NOT USE HOT WATER. If warm water is not available, gently wrap affected parts in blankets. Get immediate medical attention. Contact with liquid: Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. Not likely route of exposure. If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. For inhalation, consider oxygen. Section 5: Fire Fighting Measures Suitable Extinguishing Media Products of Combustion Protection of Firefighters Carbon dioxide, regular dry chemical Large fires: Flood with fine water spray. Carbon monoxide, carbon dioxide, water and toxic and irritating fumes.  Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply.  Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply. Section 6: Accidental Release Measures Personal Precautions Environmental Precautions Methods for Containment Keep unnecessary people away, isolate hazard area and deny entry. Ventilate closed spaces before entering. Do not touch spilled material. Avoid heat, flames, sparks and other sources of ignition. Stop leak if possible without personal risk. Reduce vapors with water spray. Remove sources of ignition. Methods for Cleanup Other Information Stop leak, evacuate area. Use protective equipment. Contact emergency personnel. None Section 7: Handling and Storage Handling Storage Grounding and bonding required. Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. Keep separated from incompatible substances. Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.110. CAS # 106-97-8 Page 164 of 1235 Page 164 of 1235 Page 164 of 1235 Page 164 of 1235 ---PAGE BREAK--- WestAir Gases & Equipment Inc page 3 of 5 Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved Generated: 08/03/2015 13:46:21 Section 8: Exposure Controls/Personal Protection Exposure Guidelines N-BUTANE: 800 ppm (1900 mg/m3) OSHA TWA (vacated by 58 FR 35338, June 30, 1993) 800 ppm (1900 mg/m3) NIOSH recommended TWA 10 hour(s) LIQUIFIED PETROLEUM GAS (LPG): 1000 ppm (1800 mg/m3) OSHA TWA 1000 ppm (1800 mg/m3) NIOSH recommended TWA 10 hour(s) ALIPHATIC HYDROCARBON GASES ALKANE (C1-C4): 1000 ppm ACGIH TWA Engineering Controls Handle only in fully enclosed systems. Eye Protection Skin Protection Respiratory Protection For the gas: Eye protection not required, but recommended. For the liquid: Wear splash resistant safety goggles. Contact lenses should not be worn. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. For the gas: Protective clothing is not required. For the liquid: Wear appropriate protective, cold insulating clothing. Any supplied-air respirator with full facepiece and operated in a pressure- demand or other positive-pressure mode in combination with a separate escape supply. General Hygiene considerations  Avoid breathing vapor or mist  Avoid contact with eyes and skin  Wash thoroughly after handling and before eating or drinking Section 9: Physical and Chemical Properties Physical State Appearance Color Change in Appearance Physical Form Odor Taste Gas Colorless Colorless N/A Gas Unpleasant odor N/A Flash Point Flammability Partition Coefficient Autoignition Temperature Upper Explosive Limits Lower Explosive Limits -76 F (-60 C) (CC) Not available 630.96 (log = 2.80) (estimated from water solubility) 549 F (287 C) 0.085 0.019 Boiling Point Freezing Point Vapor Pressure Vapor Density Specific Gravity Water Solubility pH Odor Threshold Evaporation Rate Viscosity 30 F C) -216 F 138 C) 1557 mmHg @ 20 C 2.1 (Air=1) 0.5788 @ 0 C 0.15 Not applicable 6.16 ppm Not applicable for gas. Liquefied n- butane will evaporate rapidly at room temperature Not available Molecular Weight Molecular Formula Density Weight per Gallon Volatility by Volume Volatility Solvent Solubility 58.12 C-H3-(C-H2)2-C- H3 Not available Not available 100% Not applicable Soluble: Alcohol, ether, chloroform Section 10: Stability and Reactivity Stability Conditions to Avoid Incompatible Materials Stable at normal temperatures and pressure. Stable at normal temperatures and pressure. Oxidizing materials, halogen compounds Hazardous Decomposition Products Possibility of Hazardous Reactions Oxides of carbon. Will not polymerize. Page 165 of 1235 Page 165 of 1235 Page 165 of 1235 Page 165 of 1235 ---PAGE BREAK--- WestAir Gases & Equipment Inc page 4 of 5 Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved Generated: 08/03/2015 13:46:21 Section 11: Toxicology Information Acute Effects Oral LD50 Dermal LD50 Inhalation LC(50): 658 mg/l (270,000 ppm) butane (4 hour-rat) Not established Irritation, nausea, vomiting, headache, drowsiness, of drunkenness, tingling sensation, suffocation, convulsions, coma, can displace oxygen at high concentrations Eye Irritation Skin Irritation Sensitization Frostbite, blurred vision Blisters, frostbite Central nervous system depression, difficulty breathing Chronic Effects Carcinogenicity Mutagenicity Reproductive Effects Developmental Effects None Not established Not established No data Section 12: Ecological Information Fate and Transport Eco toxicity Persistence / Degradability Bioaccumulation / Accumulation Mobility in Environment Fish toxicity: Not available Invertibrate toxicity: Not available Algal toxicity: Not available Phyto toxicity: Not available Other toxicity: Expected to exist entirely in the vapor phase in ambient air. Not available Not available Not available Section 13: Disposal Considerations Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. Section 14: Transportation Information U.S. DOT 49 CFR 172.101 Proper Shipping Name ID Number Hazard Class or Division Packing Group Labeling Requirements Passenger Aircraft or Railcar Quantity Limitations Cargo Aircraft Only Quantity Limitations Additional Shipping Description Butane UN1011 2.1 Not applicable 2.1 Forbidden 150 kg N/A Canadian Transportation of Dangerous Goods Shipping Name UN Number Class Packing Group / Risk Group Butane UN1011 2.1 Not applicable Section 15: Regulatory Information U.S. Regulations CERCLA Sections SARA 355.30 SARA 355.40 Not regulated. Not regulated. Not regulated. SARA 370.21 Acute Chronic Fire Reactive Sudden Release Page 166 of 1235 Page 166 of 1235 Page 166 of 1235 Page 166 of 1235 ---PAGE BREAK--- WestAir Gases & Equipment Inc page 5 of 5 Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved Generated: 08/03/2015 13:46:21 Yes No Yes No Yes SARA 372.65 Not regulated. OSHA Process Safety Not regulated. State Regulations CA Proposition 65 Not regulated. Canadian Regulations WHMIS Classification A,B1 National Inventory Status US Inventory (TSCA) TSCA 12b Export Notification Canada Inventory (DSL/NDSL) Listed on inventory. Not listed. Listed on inventory. Section 16: Other Information NFPA Rating HEALTH=1 FIRE=4 REACTIVITY=0 0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Page 167 of 1235 Page 167 of 1235 Page 167 of 1235 Page 167 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SECTION 1 - PRODUCT IDENTIFICATION AND USE PRODUCT PRODUCT IDENTIFICATION IDENTIFIER CARNUBA WAX NUMBER (PIN): N.AV. PRODUCT USE N.AV. MANUFACTURERS NAME: N.AV. SUPPLIERS NAME: XENEX LABORATORIES INC. STREET ADDRESS: N.AV. STREET ADDRESS: 2402 CANOE AVENUE CITY: N.AV. PROVINCE: N.AV. CITY: COQUITLAM PROVINCE: B.C. POSTAL EMERGENCY POSTAL EMERGENCY TELEPHONE NO: CODE: N.AV. TELEPHONE NO: N.AV. CODE: V3K 6C2 1-[PHONE REDACTED] SECTION 2 - HAZARDOUS INGREDIENTS HAZARDOUS INGREDIENTS % CAS NUMBER LD50OF INGREDIENT LD50OF INGREDIENT (SPECIFY SPECIES AND ROUTE) (SPECIFY SPECIES AND ROUTE) Carnuba wax 100 8015-86-9 N.AV. N.AV. SECTION 3 - PHYSICAL DATA PHYSICAL STATE ODOUR AND APPEARANCE ODOUR THRESHOLD (ppm) Solid Yellow to green. Pungent characteristic odor N.AV. VAPOUR PRESSURE VAPOUR DENSITY EVAPORATION RATE BOILING POINT FREEZING POINT (mm Hg) N.AV. (AIR = 1) N.AV. N.AV. N.AV. N.AV. pH SPECIFIC GRAVITY COEFF. WATER/OIL DIST. N.AV. 0.995 N.AV. SECTION 4 - FIRE AND EXPLOSION DATA FLAMMABILITY YES NO IF YES, UNDER May be combustible at high temperatures WHAT CONDITIONS? MEANS OF EXTINCTION Water spray; CO2; dry chemical FLASHPOINT AND METHOD UPPER FLAMMABLE LIMIT LOWER FLAMMABLE LIMIT 282.22 (cc) BY VOLUME) N.AV. BY VOLUME) N.AV. AUTOIGNITION TEMPERATURE HAZARDOUS COMBUSTION PRODUCTS N.AV. N.AV. SECTION 5 - REACTIVITY DATA CHEMICAL STABILITY YES NO IF NO, UNDER WHICH CONDITIONS? INCOMPATIBILITY WITH OTHER SUBSTANCES YES NO IF SO, N.AV. WHICH ONES? REACTIVITY, AND UNDER WHAT CONDITIONS N.AV. HAZARDOUS DECOMPOSITION PRODUCTS N.AV. Page 168 of 1235 Page 168 of 1235 Page 168 of 1235 Page 168 of 1235 ---PAGE BREAK--- PRODUCT IDENTIFIER CARNUBA WAX SECTION 6 - TOXICOLOGICAL PROPERTIES ROUTE OF ENTRY SKIN CONTACT SKIN ABSORPTION EYE CONTACT INHALATION INGESTION EFFECTS OF ACUTE EXPOSURE TO PRODUCT Very hazardous in case of ingestion. Hazardous in case of eye contact (irritant), of inhalation. EFFECTS OF CHRONIC EXPOSURE TO PRODUCT Same as above EXPOSURE LIMITS IRRITANCY OF PRODUCT SENSITIZATION OF PRODUCT CARCINOGENICITY N.AV. N.AV. N.AV. N.AV. TERATOGENICITY REPRODUCTIVE TOXICITY MUTAGENICITY SYNERGISTIC PRODUCTS N.AV. N.AV. N.AV. N.AV. SECTION 7 - PREVENTATIVE MEASURE PERSONAL PROTECTIVE EQUIPMENT SEE BELOW GLOVES (SPECIFY) RESPIRATOR (SPECIFY) EYE (SPECIFY) Yes (rubber) No Safety goggles, face shield FOOTWEAR (SPECIFY) CLOTHING (SPECIFY) OTHER (SPECIFY) No Coveralls or lab coat Eyewash equipment nearby ENGINEERING CONTROLS (SPECIFY eg. VENTILATION,ENCLOSED PROCESS) Local exhaust LEAK AND SPILL PROCEDURE Wash down residue with hot water. Take up with absorbent materials and squeegee and store in drums. WASTE DISPOSAL According to local, provincial and federal regulations HANDLING PROCEDURES AND EQUIPMENT Avoid contact and inhalation STORAGE REQUIREMENTS Room temperature SPECIAL SHIPPING INFORMATION No special precautions SECTION 8 - FIRST AID MEASURES SPECIFIC MEASURES SKIN WASH WITH WATER FOR 15 MINUTES. EYES WASH WELL WITH WATER FOR 15 MINUTES, OCCASIONALLY LIFTING UPPER AND LOWER EYELIDS. INHALATION REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION.KEEP PERSON WARM AT REST. INGESTION DO NOT INDUCE VOMITING, LOOSEN TIGHT CLOTHING. IF VICTIM IS NOT BREATHING PERFORM MOUTH TO MOUTH RESUSCITATION. SEEK IMMEDIATE MEDICAL ATTENTION. IF SKIN IRRITATION PERSISTS AND IN ALL OTHER CASES, GET IMMEDIATE MEDICAL ATTENTION. SECTION 9 - PREPARATION DATE OF M.S.D.S. PREPARED BY (GROUP, DEPARTMENT, ETC.) PHONE NUMBER DATE: CONTROL DEPARTMENT (604) 552-3031 April 27, 2005 Page 169 of 1235 Page 169 of 1235 Page 169 of 1235 Page 169 of 1235 ---PAGE BREAK--- Page: 1 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 9/30/2013 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.4 Page 1 / 12 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Ashland Regulatory Information Number 1-[PHONE REDACTED] P.O. Box 2219 Telephone [PHONE REDACTED] Columbus, OH 43216 Emergency telephone number 1-800-ASHLAND (1-[PHONE REDACTED]) Product name Carquest® ANTIFREEZE COOLANT Product code CQ001 2. HAZARDS IDENTIFICATION Emergency Overview Appearance: liquid, green WARNING! MAY AFFECT THE CENTRAL NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. MAY CAUSE EYE IRRITATION. HARMFUL IF SWALLOWED. Potential Health Effects Exposure routes Inhalation, Skin absorption, Skin contact, Eye Contact, Ingestion Eye contact Can cause eye irritation. include stinging, tearing, redness, and swelling of eyes. Skin contact May cause slight skin irritation. Skin absorption of this material (or a component) may be increased through injured skin. Ingestion Swallowing this material may be harmful. Liver, kidney and brain damage in humans has resulted from swallowing lethal or near-lethal amounts of ethylene glycol. Inhalation It is possible to breathe this material under certain conditions of handling and use (for example, during heating, spraying, or stirring). Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. are not expected at air concentrations below the recommended exposure limits, if applicable (see Section Aggravated Medical Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, lung (for example, asthma-like conditions), Liver, Kidney, Central nervous system, Exposure to this material may aggravate any preexisting condition sensitive to a decrease in available oxygen, such as chronic lung disease, coronary artery disease or anemias. Page 170 of 1235 Page 170 of 1235 Page 170 of 1235 Page 170 of 1235 ---PAGE BREAK--- Page: 2 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 9/30/2013 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.4 Page 2 / 12 Signs and of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways), Cough, central nervous system excitation (giddiness, liveliness, light-headed feeling) followed by central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness) and other central nervous system effects, involuntary eye movement, pain in the abdomen and lower back, cyanosis (causes blue coloring of the skin and nails from lack of oxygen), lung edema (fluid buildup in the lung tissue), acute kidney failure (sudden slowing or stopping of urine production), liver damage, Convulsions, coma Target Organs Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals:, reproductive effects, kidney damage, liver damage, central nervous system damage, Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans:, liver damage, kidney damage Carcinogenicity This material is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration (OSHA).This material is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration (OSHA). Reproductive hazard Ethylene glycol has caused birth defects in animal studies at high oral doses. However, it did not cause harm to the pregnant animal or to the fetus when applied to the skin of the pregnant animal., This material (or a component) has been shown to cause harm to the fetus in laboratory animal studies. Harm to the fetus occurs only at exposure levels that harm the pregnant animal. The relevance of these findings to humans is uncertain.Ethylene glycol has caused birth defects in animal studies at high oral doses. However, it did not cause harm to the pregnant animal or to the fetus when applied to the skin of the pregnant animal., This material (or a component) has been shown to cause harm to the fetus in laboratory animal studies. Harm to the fetus occurs only at exposure levels that harm the pregnant animal. The relevance of these findings to humans is uncertain. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Components CAS-No. / Trade Secret No. Concentration ETHYLENE GLYCOL 107-21-1 >=90-<=100% DIETHYLENE GLYCOL 111-46-6 4. FIRST AID MEASURES Eyes If develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention. Page 171 of 1235 Page 171 of 1235 Page 171 of 1235 Page 171 of 1235 ---PAGE BREAK--- Page: 3 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 9/30/2013 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.4 Page 3 / 12 Skin Remove contaminated clothing. Wash exposed area with soap and water. If persist, seek medical attention. Launder clothing before reuse. Ingestion Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. Inhalation If develop, immediately move individual away from exposure and into fresh air. Seek immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial respiration. If breathing is difficult, administer oxygen. Notes to physician Hazards: Effects of acute ethylene glycol poisoning appear in three fairly distinct stages. The initial stage occurs shortly after exposure, lasts 6-12 hours, and is characterized by central nervous system effects (transient exhilaration, nausea, vomiting, and in severe cases, coma, convulsions, and possible death). The second stage lasts from 12-36 hours after exposure and is initiated by the onset of coma. This phase is characterized by tachycardia, mild hypotension, cyanosis, and in severe cases, pulmonary edema, bronchopneumonia, cardiac enlargement, and congestive failure. The final stage occurs 24-72 post-exposure and is characterized by renal failure, ranging from a mild increase in blood urea nitrogen and creatinine followed by recovery, to complete anuria with acute tubular necrosis that can lead to death. Oxaluria is found in most cases. The most significant laboratory finding in ethylene glycol intoxication is severe metabolic acidosis. Ingestion or other significant exposure to this material (or a component) may cause metabolic acidosis. Treatment: This product contains ethylene glycol. Ethanol decreases the metabolism of ethylene glycol to toxic metabolites. Ethanol should be administered as soon as possible in cases of severe poisoning since the elimination half-life of ethylene glycol is 3 hours. If medical care will be delayed several hours, give the patient three to four 1-ounce oral "shots" of 86-proof or higher whiskey before or during transport to the hospital. Fomepizole is an effective antagonist of alcohol dehydrogenase, and as such, may be used as an antidote in the treatment of ethylene glycol poisoning. Hemodialysis effectively removes ethylene glycol and its metabolites from the body. Fomepizole is an effective antagonist of alcohol dehydrogenase, and as such, may be used as an antidote in the treatment of ethylene glycol, diethylene glycol and methanol poisoning. 5. FIREFIGHTING MEASURES Suitable extinguishing media Dry chemical, Carbon dioxide (CO2), Water spray Hazardous combustion products Alcohols, Aldehydes, carbon dioxide and carbon monoxide, ethers, Hydrocarbons, toxic fumes Precautions for fire-fighting Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). DO NOT direct a solid stream of water or foam into hot, burning pools of liquid since this may cause frothing and increase fire intensity. Frothing can be violent and possibly endanger any firefighter standing too close to the burning liquid. Page 172 of 1235 Page 172 of 1235 Page 172 of 1235 Page 172 of 1235 ---PAGE BREAK--- Page: 4 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 9/30/2013 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.4 Page 4 / 12 Use water spray to cool fire exposed containers and structures until fire is out if it can be done with minimal risk. Avoid spreading burning material with water used for cooling purposes. NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB 6. ACCIDENTAL RELEASE MEASURES Personal precautions For personal protection see section 8. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions Prevent spreading over a wide area (e.g. by containment or oil barriers). Do not let product enter drains. Do not flush into surface water or sanitary sewer system. Methods for cleaning up Keep in suitable, closed containers for disposal. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Other information Comply with all applicable federal, state, and local regulations. 7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Storage Store in a cool, dry, ventilated area. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines ETHYLENE GLYCOL 107-21-1 ACGIH Ceiling Limit Value: 100 mg/m3 Aerosol. DIETHYLENE GLYCOL 111-46-6 WEEL time weighted average 10 mg/m3 General advice These recommendations provide general guidance for handling this product. Personal protective equipment should be selected for individual applications and should consider factors which affect exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities. Page 173 of 1235 Page 173 of 1235 Page 173 of 1235 Page 173 of 1235 ---PAGE BREAK--- Page: 5 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 9/30/2013 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.4 Page 5 / 12 Exposure controls Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Eye protection Wear chemical splash goggles when there is the potential for exposure of the eyes to liquid, vapor or mist. Skin and body protection Wear normal work clothing including long pants, long-sleeved shirts and foot covering to prevent direct contact of the product with the skin. Launder clothing before reuse. If skin irritation develops, contact your facility health and safety professional or your local safety equipment supplier to determine the proper personal protective equipment for your use. Wear resistant gloves (consult your safety equipment supplier). Respiratory protection Respiratory protection is not required under normal conditions of use. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state liquid Colour green Boiling point/boiling range 387.7 °F / 197.6 °C @ 1,013.23 hPa Calculated Phase Transition Liquid/Gas pH 9 - < 11 Flash point > 232 °F / > 111 °C Lower explosion limit/Upper explosion limit 3.2 / 15.3 Calculated Explosive Limit Vapour pressure 0.122 hPa @ 77 °F / 25 °C Calculated Vapor Pressure Density 1.1205 g/cm3 @ 60.1 °F / 15.6 °C 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid Heat, flames and sparks., Exposure to moisture. Incompatible products Acids, Aldehydes, Alkali metals, Alkaline earth metals, aluminum, Bases, strong alkalis, Strong oxidizing agents, Sulphur compounds Hazardous decomposition products Alcohols, Aldehydes, carbon dioxide and carbon monoxide, ethers, Hydrocarbons, Organic acids, ketones Page 174 of 1235 Page 174 of 1235 Page 174 of 1235 Page 174 of 1235 ---PAGE BREAK--- Page: 6 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 9/30/2013 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.4 Page 6 / 12 Hazardous reactions Product will not undergo hazardous polymerization. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation Skin absorption Skin contact Eye Contact Ingestion Product Acute oral toxicity : no data available Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Skin corrosion/irritation : no data available Serious eye damage/eye irritation : no data available Respiratory or skin sensitisation : no data available Target Organ Systemic Toxicant - Repeated Exposure : Target Organs: Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals:, reproductive effects, kidney damage, liver damage, central nervous system damage, Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans:, liver damage, kidney damage Components: ETHYLENE GLYCOL: Acute oral toxicity : LD 50 Rat: 6,140 mg/kg Acute dermal toxicity : LD 50 Rabbit: 9,530 mg/kg STOT - repeated exposure : Exposure routes: Ingestion Page 175 of 1235 Page 175 of 1235 Page 175 of 1235 Page 175 of 1235 ---PAGE BREAK--- Page: 7 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 9/30/2013 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.4 Page 7 / 12 Target Organs: Kidney, Liver Assessment: May cause damage to organs through prolonged or repeated exposure. DIETHYLENE GLYCOL: Acute oral toxicity : LD 50 Rat: 12,565 mg/kg Acute inhalation toxicity : LC Lo Mouse: 130 mg/m3 Exposure time: 2 h Acute dermal toxicity : LD 50 Rabbit: 11,890 mg/kg Experience with human exposure : Liver 12. ECOLOGICAL INFORMATION Ecotoxicity Product: no data available Components: ETHYLENE GLYCOL: Toxicity to fish : LC 50 (Bluegill (Lepomis macrochirus)): 27,540 mg/l Exposure time: 96 h Method: Static Mortality LC 50 (Fathead minnow (Pimephales promelas)): 8,050 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : LC 50 (Water flea (Daphnia magna)): > 10,000 mg/l Exposure time: 48 h Test Method: static test DIETHYLENE GLYCOL: Toxicity to fish : LC 50 (Western mosquitofish (Gambusia affinis)): > 32,000 mg/l Exposure time: 96 h Method: Static Mortality Page 176 of 1235 Page 176 of 1235 Page 176 of 1235 Page 176 of 1235 ---PAGE BREAK--- Page: 8 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 9/30/2013 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.4 Page 8 / 12 Toxicity to daphnia and other aquatic invertebrates : LC 50 (Water flea (Daphnia magna)): > 10,000 mg/l Exposure time: 24 h Method: Static Mortality Persistence and degradability Product: no data available Components: DIETHYLENE GLYCOL: Biodegradability : Biodegradation: 92 % Exposure time: 28 d Bioaccumulative potential Product: no data available Components: ETHYLENE GLYCOL: Bioaccumulation : Species: Crayfish (Procambarus) Exposure time: 61 d Concentration: 1000 mg/l Bioconcentration factor (BCF): 0.27 Method: Flow through Partition coefficient: n- octanol/water : log Pow: -1.36 DIETHYLENE GLYCOL: Partition coefficient: n- octanol/water : log Pow: -1.47 Mobility in soil Product: no data available Components: Page 177 of 1235 Page 177 of 1235 Page 177 of 1235 Page 177 of 1235 ---PAGE BREAK--- Page: 9 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 9/30/2013 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.4 Page 9 / 12 ETHYLENE GLYCOL: Surface tension : 48.4 mN/m DIETHYLENE GLYCOL: Surface tension : 48.5 mN/m 13. DISPOSAL CONSIDERATIONS Waste disposal methods Dispose of in accordance with all applicable local, state and federal regulations. 14. TRANSPORT INFORMATION REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP MARINE POLLUTANT / LTD. QTY. U.S. DOT - ROAD Not dangerous goods U.S. DOT - RAIL Not dangerous goods U.S. DOT - INLAND WATERWAYS Not dangerous goods TRANSPORT CANADA - ROAD Not dangerous goods TRANSPORT CANADA - RAIL Not dangerous goods TRANSPORT CANADA - INLAND WATERWAYS Not dangerous goods INTERNATIONAL MARITIME DANGEROUS GOODS Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER Not dangerous goods Page 178 of 1235 Page 178 of 1235 Page 178 of 1235 Page 178 of 1235 ---PAGE BREAK--- Page: 10 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 9/30/2013 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.4 Page 10 / 12 MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTES Not dangerous goods *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. 15. REGULATORY INFORMATION California Prop. 65 Proposition 65 warnings are not required for this product based on the results of a risk assessment. SARA Hazard Classification SARA 311/312 Classification Acute Health Hazard SARA 313 Component(s) ETHYLENE GLYCOL 95.75 % New Jersey RTK Label Information ETHYLENE GLYCOL 107-21-1 DIETHYLENE GLYCOL 111-46-6 WATER 7732-18-5 RTK Label Information ETHYLENE GLYCOL 107-21-1 DIETHYLENE GLYCOL 111-46-6 Notification status US. Toxic Substances Control Act y (positive listing) Canada. Canadian Environmental Protection Act (CEPA). Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133) y (positive listing) Australia. Industrial Chemical (Notification and Assessment) Act y (positive listing) Japan. ENCS - Existing and New Chemical Substances Inventory n (Negative listing) Korea. Toxic Chemical Control Law (TCCL) List y (positive listing) Philippines. The Toxic Substances and Hazardous and Nuclear Waste Control Act y (positive listing) China. Inventory of Existing Chemical Substances y (positive listing) Reportable quantity - Product US. EPA CERCLA Hazardous Substances (40 CFR 302) 5221 lbs Reportable quantity-Components Page 179 of 1235 Page 179 of 1235 Page 179 of 1235 Page 179 of 1235 ---PAGE BREAK--- Page: 11 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 9/30/2013 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.4 Page 11 / 12 ETHYLENE GLYCOL 107-21-1 5000 lbs HMIS NFPA Health 1* 1 Flammability 1 1 Physical hazards 0 Instability 0 Specific Hazard 16. OTHER INFORMATION The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department (1-[PHONE REDACTED]). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the “International Air Transport Association” (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the “International Civil Aviation Organization” IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level Page 180 of 1235 Page 180 of 1235 Page 180 of 1235 Page 180 of 1235 ---PAGE BREAK--- Page: 12 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 9/30/2013 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.4 Page 12 / 12 CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System Page 181 of 1235 Page 181 of 1235 Page 181 of 1235 Page 181 of 1235 ---PAGE BREAK--- Page: 1 SAFETY DATA SHEET Revision Date: 10/13/2009 Print Date: 11/11/2009 MSDS Number: R0311762 CARQUEST® ANTIFREEZE COOLANT CQ001 Version: 2.4 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Ashland Regulatory Information Number 1-[PHONE REDACTED] P.O. Box 2219 Telephone [PHONE REDACTED] Columbus, OH 43216 Emergency telephone 1-800-ASHLAND (1-[PHONE REDACTED]) Product name CARQUEST® ANTIFREEZE COOLANT Product code CQ001 Product Use Description No data 2. HAZARDS IDENTIFICATION Emergency Overview Appearance: liquid, green WARNING! MAY AFFECT THE CENTRAL NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. HARMFUL IF SWALLOWED. MAY CAUSE EYE IRRITATION. MAY CAUSE SKIN AND RESPIRATORY TRACT IRRITATION. Potential Health Effects Exposure routes Skin absorption, Skin contact, Eye Contact, Inhalation, Ingestion Eye contact Can cause eye irritation. include stinging, tearing, redness, and swelling of eyes. Skin contact May cause mild skin irritation. may include redness and burning of skin. Although rare, skin contact with ethylene glycol may cause allergic skin reaction (delayed skin rash which may be followed by blistering, scaling and other skin effects). Passage of this material into the body through the skin is possible, but it is unlikely that this would result in harmful effects during safe handling and use. Ingestion Page 1 / 10 Page 182 of 1235 Page 182 of 1235 Page 182 of 1235 Page 182 of 1235 ---PAGE BREAK--- Page: 2 SAFETY DATA SHEET Revision Date: 10/13/2009 Print Date: 11/11/2009 MSDS Number: R0311762 CARQUEST® ANTIFREEZE COOLANT CQ001 Version: 2.4 Swallowing this material may be harmful.Liver, kidney and brain damage in humans has resulted from swallowing lethal or near-lethal amounts of ethylene glycol.Ingestion of medications contaminated with diethylene glycol has caused kidney failure and death in humans. Products containing diethylene glycol should be considered toxic by ingestion. Inhalation Breathing of vapor or fume is possible. Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. are not expected at air concentrations below the recommended exposure limits, if applicable (see Section Aggravated Medical Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, lung (for example, asthma-like conditions), Liver, Kidney, Exposure to this material may aggravate any preexisting condition sensitive to a decrease in available oxygen, such as chronic lung disease, coronary artery disease or anemias. Signs and of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways), Cough, central nervous system excitation (giddiness, liveliness, light-headed feeling) followed by central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness) and other central nervous system effects, involuntary eye movement, cyanosis (causes blue coloring of the skin and nails from lack of oxygen), lung edema (fluid buildup in the lung tissue), acute kidney failure (sudden slowing or stopping of urine production), liver damage, Convulsions, coma Target Organs Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals:, reproductive effects, kidney damage, liver damage, Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans:, kidney damage, liver damage Carcinogenicity Page 2 / 10 Page 183 of 1235 Page 183 of 1235 Page 183 of 1235 Page 183 of 1235 ---PAGE BREAK--- Page: 3 SAFETY DATA SHEET Revision Date: 10/13/2009 Print Date: 11/11/2009 MSDS Number: R0311762 CARQUEST® ANTIFREEZE COOLANT CQ001 Version: 2.4 This material is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration (OSHA). Reproductive hazard Ethylene glycol has caused birth defects in animal studies at high oral doses. However, it did not cause harm to the pregnant animal or to the fetus when applied to the skin of the pregnant animal. 3. COMPOSITION/INFORMATION ON INGREDIENTS Components CAS-No. Concentration ETHYLENE GLYCOL 107-21-1 >=90-<=100% DIETHYLENE GLYCOL 111-46-6 INORGANIC SALT NJTS# 254504001-5237 4. FIRST AID MEASURES Eyes If develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention. Skin Remove contaminated clothing. Flush exposed area with large amounts of water. If skin is damaged, seek immediate medical attention. If skin is not damaged and persist, seek medical attention. Launder clothing before reuse. Ingestion Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. Inhalation Page 3 / 10 Page 184 of 1235 Page 184 of 1235 Page 184 of 1235 Page 184 of 1235 ---PAGE BREAK--- Page: 4 SAFETY DATA SHEET Revision Date: 10/13/2009 Print Date: 11/11/2009 MSDS Number: R0311762 CARQUEST® ANTIFREEZE COOLANT CQ001 Version: 2.4 If develop, move individual away from exposure and into fresh air. If persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention. Notes to physician Hazards: Effects of acute ethylene glycol poisoning appear in three fairly distinct stages. The initial stage occurs shortly after exposure, lasts 6-12 hours, and is characterized by central nervous system effects (transient exhilaration, nausea, vomiting, and in severe cases, coma, convulsions, and possible death). The second stage lasts from 12-36 hours after exposure and is initiated by the onset of coma. This phase is characterized by tachycardia, mild hypotension, cyanosis, and in severe cases, pulmonary edema, bronchopneumonia, cardiac enlargement, and congestive failure. The final stage occurs 24-72 post-exposure and is characterized by renal failure, ranging from a mild increase in blood urea nitrogen and creatinine followed by recovery, to complete anuria with acute tubular necrosis that can lead to death. Oxaluria is found in most cases. The most significant laboratory finding in ethylene glycol intoxication is severe metabolic acidosis. Treatment: This product contains ethylene glycol. Ethanol decreases the metabolism of ethylene glycol to toxic metabolites. Ethanol should be administered as soon as possible in cases of severe poisoning since the elimination half-life of ethylene glycol is 3 hours. If medical care will be delayed several hours, give the patient three to four 1-ounce oral "shots" of 86-proof or higher whiskey before or during transport to the hospital. Fomepizole is an effective antagonist of alcohol dehydrogenase, and as such, may be used as an antidote in the treatment of ethylene glycol poisoning. Hemodialysis effectively removes ethylene glycol and its metabolites from the body. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Water spray, Dry chemical, Carbon dioxide (CO2) Hazardous combustion products carbon dioxide and carbon monoxide, various hydrocarbons Precautions for fire-fighting Never use welding or cutting torch on or near drum (even empty) because product (even just residue) can ignite explosively.Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). DO NOT direct a solid stream of Page 4 / 10 Page 185 of 1235 Page 185 of 1235 Page 185 of 1235 Page 185 of 1235 ---PAGE BREAK--- Page: 5 SAFETY DATA SHEET Revision Date: 10/13/2009 Print Date: 11/11/2009 MSDS Number: R0311762 CARQUEST® ANTIFREEZE COOLANT CQ001 Version: 2.4 water or foam into hot, burning pools of liquid since this may cause frothing and increase fire intensity. Frothing can be violent and possibly endanger any firefighter standing too close to the burning liquid. Use water spray to cool fire exposed containers and structures until fire is out if it can be done with minimal risk. Avoid spreading burning liquid with water used for cooling purposes. Flammability Class for Flammable Liquids Combustible Liquid Class IIIB 6. ACCIDENTAL RELEASE MEASURES Personal precautions For personal protection see section 8. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions Prevent spreading over a wide area (e.g. by containment or oil barriers). Do not let product enter drains. Do not flush into surface water or sanitary sewer system. Methods for cleaning up Keep in suitable, closed containers for disposal. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Other information Comply with all applicable federal, state, and local regulations. 7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed.Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Storage Store in a cool, dry, ventilated area. Page 5 / 10 Page 186 of 1235 Page 186 of 1235 Page 186 of 1235 Page 186 of 1235 ---PAGE BREAK--- Page: 6 SAFETY DATA SHEET Revision Date: 10/13/2009 Print Date: 11/11/2009 MSDS Number: R0311762 CARQUEST® ANTIFREEZE COOLANT CQ001 Version: 2.4 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines ETHYLENE GLYCOL 107-21-1 ACGIH Ceiling Limit Value: 100 mg/m3 Aerosol. General advice These recommendations provide general guidance for handling this product. Personal protective equipment should be selected for individual applications and should consider factors which affect exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities. Exposure controls General room ventilation should be adequate for normal conditions of use. However, if unusual operating conditions exist, provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Eye protection Wear chemical splash goggles when there is the potential for exposure of the eyes to liquid, vapor or mist. Skin and body protection Wear normal work clothing including long pants, long-sleeved shirts and foot covering to prevent direct contact of the product with the skin. Launder clothing before reuse. If skin irritation develops, contact your facility health and safety professional or your local safety equipment supplier to determine the proper personal protective equipment for your use. Wear resistant gloves such as: Neoprene polyvinyl chloride Nitrile rubber Respiratory protection Respiratory protection is not required under normal conditions of use. Page 6 / 10 Page 187 of 1235 Page 187 of 1235 Page 187 of 1235 Page 187 of 1235 ---PAGE BREAK--- Page: 7 SAFETY DATA SHEET Revision Date: 10/13/2009 Print Date: 11/11/2009 MSDS Number: R0311762 CARQUEST® ANTIFREEZE COOLANT CQ001 Version: 2.4 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state liquid Form No data Colour green Odour No data Boiling point/boiling range 330.00 °F / 330 760.00 mmHg pH 0.7) 10.7 Flash point 250 °F / 121 °C Evaporation rate No data Explosion limits 3.2 15.3 Vapour pressure 23.33 hPa @ 68 °F / 20 °C Vapour density No data Density (Average) 1.236 g/cm3 @ 60.01 °F / 15.56 °C 9.41 lb/gal @ 60.1 °F / 15.6 °C Solubility soluble in water Partition coefficient: n- octanol/water No data log Pow no data available Autoignition temperature No data 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid None known. Incompatible products Strong oxidizing agents Hazardous decomposition products carbon dioxide and carbon monoxide, various hydrocarbons Hazardous reactions Product will not undergo hazardous polymerization. Thermal decomposition Page 7 / 10 Page 188 of 1235 Page 188 of 1235 Page 188 of 1235 Page 188 of 1235 ---PAGE BREAK--- Page: 8 SAFETY DATA SHEET Revision Date: 10/13/2009 Print Date: 11/11/2009 MSDS Number: R0311762 CARQUEST® ANTIFREEZE COOLANT CQ001 Version: 2.4 No data 11. TOXICOLOGICAL INFORMATION Acute oral toxicity ETHYLENE GLYCOL LD 50 Rat: 6,140 mg/kg DIETHYLENE GLYCOL LD 50 Rat: 12,565 mg/kg INORGANIC SALT LD 50 Rat: > 500 mg/kg Acute inhalation toxicity ETHYLENE GLYCOL no data available DIETHYLENE GLYCOL LC Lo Mouse: 130 mg/m3 , 2 h INORGANIC SALT no data available Acute dermal toxicity ETHYLENE GLYCOL LD 50 Rabbit: 9,530 mg/kg DIETHYLENE GLYCOL LD 50 Rabbit: 11,890 mg/kg INORGANIC SALT LD 50 Rabbit: > 300 mg/kg 12. ECOLOGICAL INFORMATION Aquatic toxicity Acute and Prolonged Toxicity to Fish No data Acute Toxicity to Aquatic Invertebrates No data Environmental fate and pathways No data 13. DISPOSAL CONSIDERATIONS Waste disposal methods Page 8 / 10 Page 189 of 1235 Page 189 of 1235 Page 189 of 1235 Page 189 of 1235 ---PAGE BREAK--- Page: 9 SAFETY DATA SHEET Revision Date: 10/13/2009 Print Date: 11/11/2009 MSDS Number: R0311762 CARQUEST® ANTIFREEZE COOLANT CQ001 Version: 2.4 Destroy by liquid incineration. Dispose of in accordance with all applicable local, state and federal regulations. For assistance with your waste management needs - including disposal, recycling and waste stream reduction, contact Ashland Distribution's Environmental Services Group at [PHONE REDACTED]. 14. TRANSPORT INFORMATION Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. 15. REGULATORY INFORMATION California Prop. 65 Proposition 65 warnings are not required for this product based on the results of a risk assessment. SARA Hazard Classification Acute Health Hazard SARA 313 Component(s) ETHYLENE GLYCOL 107-21-1 % New Jersey RTK Label Information ETHYLENE GLYCOL 107-21-1 DIETHYLENE GLYCOL 111-46-6 WATER 7732-18-5 INORGANIC SALT NJTS 254504001-5237 RTK Label Information ETHYLENE GLYCOL 107-21-1 DIETHYLENE GLYCOL 111-46-6 Reportable quantity - Product US. EPA CERCLA Hazardous Substances (40 CFR 302) 5262 lbs Reportable quantity - Components ETHYLENE GLYCOL 107-21-1 5000 lbs Page 9 / 10 Page 190 of 1235 Page 190 of 1235 Page 190 of 1235 Page 190 of 1235 ---PAGE BREAK--- Page: 10 SAFETY DATA SHEET Revision Date: 10/13/2009 Print Date: 11/11/2009 MSDS Number: R0311762 CARQUEST® ANTIFREEZE COOLANT CQ001 Version: 2.4 DIETHYLENE GLYCOL 111-46-6 none INORGANIC SALT NJTS# 254504001-5237 none Health Flammability Reactivity Other HMIS 2* 1 0 NFPA 1 1 0 16. OTHER INFORMATION The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department (1-[PHONE REDACTED]). Page 10 / 10 Page 191 of 1235 Page 191 of 1235 Page 191 of 1235 Page 191 of 1235 ---PAGE BREAK--- Page: 1 SAFETY DATA SHEET Revision Date: 05/01/2012 Print Date: 5/3/2012 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.2 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Ashland Regulatory Information Number 1-[PHONE REDACTED] P.O. Box 2219 Telephone [PHONE REDACTED] Columbus, OH 43216 Emergency telephone number 1-800-ASHLAND (1-800-274- 5263) Product name Carquest® ANTIFREEZE COOLANT Product code CQ001 2. HAZARDS IDENTIFICATION Emergency Overview Appearance: liquid, green WARNING! MAY AFFECT THE CENTRAL NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. MAY CAUSE EYE IRRITATION. HARMFUL IF SWALLOWED. Potential Health Effects Exposure routes Inhalation, Skin absorption, Skin contact, Eye Contact, Ingestion Eye contact Can cause eye irritation. include stinging, tearing, redness, and swelling of eyes. Skin contact May cause slight skin irritation. Skin absorption of this material (or a component) may be increased through injured skin. Ingestion Swallowing this material may be harmful. Liver, kidney and brain damage in humans has resulted from swallowing lethal or near-lethal amounts of ethylene glycol. Page 1 / 13 Page 192 of 1235 Page 192 of 1235 Page 192 of 1235 Page 192 of 1235 ---PAGE BREAK--- Page: 2 SAFETY DATA SHEET Revision Date: 05/01/2012 Print Date: 5/3/2012 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.2 Inhalation It is possible to breathe this material under certain conditions of handling and use (for example, during heating, spraying, or stirring). Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. are not expected at air concentrations below the recommended exposure limits, if applicable (see Section Aggravated Medical Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, lung (for example, asthma-like conditions), Liver, Kidney, Exposure to this material may aggravate any preexisting condition sensitive to a decrease in available oxygen, such as chronic lung disease, coronary artery disease or anemias., Central nervous system Signs and of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways), Cough, central nervous system excitation (giddiness, liveliness, light- headed feeling) followed by central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness) and other central nervous system effects, involuntary eye movement, pain in the abdomen and lower back, cyanosis (causes blue coloring of the skin and nails from lack of oxygen), lung edema (fluid buildup in the lung tissue), acute kidney failure (sudden slowing or stoppingof urine production), liver damage, Convulsions, coma Target Organs Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals:, reproductive effects, kidney damage, liver damage, central nervous system damage, Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans:, liver damage, kidney damage Carcinogenicity This material is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration (OSHA). Reproductive hazard Ethylene glycol has caused birth defects in animal studies at high oral doses. However, it did not cause harm to the pregnant animal or to the fetus when applied to the skin of the pregnant animal., This material (or a component) has been shown to cause harm to the fetus in laboratory animal studies. Harm to the fetus occurs only at exposure levels that harm the pregnant animal. The relevance of these findings to humans is uncertain. Page 2 / 13 Page 193 of 1235 Page 193 of 1235 Page 193 of 1235 Page 193 of 1235 ---PAGE BREAK--- Page: 3 SAFETY DATA SHEET Revision Date: 05/01/2012 Print Date: 5/3/2012 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.2 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Components CAS-No. / Trade Secret No. Concentration ETHYLENE GLYCOL 107-21-1 >=90-<=100% DIETHYLENE GLYCOL 111-46-6 4. FIRST AID MEASURES Eyes If develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention. Skin Remove contaminated clothing. Wash exposed area with soap and water. If persist, seek medical attention. Launder clothing before reuse. Ingestion Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. Inhalation If develop, immediately move individual away from exposure and into fresh air. Seek immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial respiration. If breathing is difficult, administer oxygen. Notes to physician Hazards: Effects of acute ethylene glycol poisoning appear in three fairly distinct stages. The initial stage occurs shortly after exposure, lasts 6-12 hours, and is characterized by central nervous system effects (transient exhilaration, nausea, vomiting, and in severe cases, coma, convulsions, and possible death). The second stage lasts from 12-36 hours after exposure and is initiated by the onset of Page 3 / 13 Page 194 of 1235 Page 194 of 1235 Page 194 of 1235 Page 194 of 1235 ---PAGE BREAK--- Page: 4 SAFETY DATA SHEET Revision Date: 05/01/2012 Print Date: 5/3/2012 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.2 coma. This phase is characterized by tachycardia, mild hypotension, cyanosis, and in severe cases, pulmonary edema, bronchopneumonia, cardiac enlargement, and congestive failure. The final stage occurs 24-72 post-exposure and is characterized by renal failure, ranging from a mild increase in blood urea nitrogen and creatinine followed by recovery, to complete anuria with acute tubular necrosis that can lead to death. Oxaluria is found in most cases. The most significant laboratory finding in ethylene glycol intoxication is severe metabolic acidosis. Ingestion or other significant exposure to this material (or a component) may cause metabolic acidosis. Treatment: This product contains ethylene glycol. Ethanol decreases the metabolism of ethylene glycol to toxic metabolites. Ethanol should be administered as soon as possible in cases of severe poisoning since the elimination half-life of ethylene glycol is 3 hours. If medical care will be delayed several hours, give the patient three to four 1-ounce oral "shots" of 86-proof or higher whiskey before or during transport to the hospital. Fomepizole is an effective antagonist of alcohol dehydrogenase, and as such, may be used as an antidote in the treatment of ethylene glycol poisoning. Hemodialysis effectively removes ethylene glycol and its metabolites from the body. 5. FIREFIGHTING MEASURES Suitable extinguishing media Dry chemical, Carbon dioxide (CO2), Water spray Hazardous combustion products Alcohols, Aldehydes, carbon dioxide and carbon monoxide, ethers, toxic fumes, Hydrocarbons Precautions for fire-fighting Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). DO NOT direct a solid stream of water or foam into hot, burning pools of liquid since this may cause frothing and increase fire intensity. Frothing can be violent and possibly endanger any firefighter standing too close to the burning liquid. Use water spray to cool fire exposed containers and structures until fire is out if it can be done with minimal risk. Avoid spreading burning material with water used for cooling purposes. NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB 6. ACCIDENTAL RELEASE MEASURES Personal precautions Page 4 / 13 Page 195 of 1235 Page 195 of 1235 Page 195 of 1235 Page 195 of 1235 ---PAGE BREAK--- Page: 5 SAFETY DATA SHEET Revision Date: 05/01/2012 Print Date: 5/3/2012 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.2 For personal protection see section 8. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions Prevent spreading over a wide area (e.g. by containment or oil barriers). Do not let product enter drains. Do not flush into surface water or sanitary sewer system. Methods for cleaning up Keep in suitable, closed containers for disposal. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Other information Comply with all applicable federal, state, and local regulations. 7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Storage Store in a cool, dry, ventilated area. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines ETHYLENE GLYCOL 107-21-1 ACGIH Ceiling Limit Value: 100 mg/m3 Aerosol. DIETHYLENE GLYCOL 111-46-6 WEEL time weighted average 10 mg/m3 General advice These recommendations provide general guidance for handling this product. Personal protective equipment should be selected for individual applications and should consider factors which affect Page 5 / 13 Page 196 of 1235 Page 196 of 1235 Page 196 of 1235 Page 196 of 1235 ---PAGE BREAK--- Page: 6 SAFETY DATA SHEET Revision Date: 05/01/2012 Print Date: 5/3/2012 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.2 exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities. Exposure controls Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Eye protection Wear chemical splash goggles when there is the potential for exposure of the eyes to liquid, vapor or mist. Skin and body protection Wear normal work clothing including long pants, long-sleeved shirts and foot covering to prevent direct contact of the product with the skin. Launder clothing before reuse. If skin irritation develops, contact your facility health and safety professional or your local safety equipment supplier to determine the proper personal protective equipment for your use. Wear resistant gloves (consult your safety equipment supplier). Respiratory protection A NIOSH-approved air-purifying respirator with an appropriate cartridge and/or filter may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits (if applicable) or if overexposure has otherwise been determined. Protection provided by air- purifying respirators is limited. Use a positive pressure, air-supplied respirator if there is any potential for uncontrolled release, exposure levels are not known or any other circumstances where an air- purifying respirator may not provide adequate protection. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state liquid Colour green Boiling point/boiling range 387.7 °F / 197.6 °C @ 1,013.23 hPa Calculated Phase Transition Liquid/Gas pH 0.5) 10.7 Flash point > 232 °F / > 111 °C Page 6 / 13 Page 197 of 1235 Page 197 of 1235 Page 197 of 1235 Page 197 of 1235 ---PAGE BREAK--- Page: 7 SAFETY DATA SHEET Revision Date: 05/01/2012 Print Date: 5/3/2012 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.2 Lower explosion limit/Upper explosion limit 3.2 / 15.3 Calculated Explosive Limit Vapour pressure 0.122 hPa @ 77 °F / 25 °C Calculated Vapor Pressure 9.363 lb/gal 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid excessive heat Incompatible products Acids, Aldehydes, Alkali metals, Alkaline earth metals, aluminum, Bases, strong alkalis, Strong oxidizing agents, Sulphur compounds Hazardous decomposition products carbon dioxide and carbon monoxide, Aldehydes, ketones, Organic acids, Alcohols, ethers, Hydrocarbons Hazardous reactions Product will not undergo hazardous polymerization. 11. TOXICOLOGICAL INFORMATION Acute oral toxicity Acute oral toxicity - Product : no data available Acute oral toxicity - Components ETHYLENE GLYCOL : LD 50: 6,140 mg/kg Species: Rat DIETHYLENE GLYCOL : LD 50: 12,565 mg/kg Species: Rat Page 7 / 13 Page 198 of 1235 Page 198 of 1235 Page 198 of 1235 Page 198 of 1235 ---PAGE BREAK--- Page: 8 SAFETY DATA SHEET Revision Date: 05/01/2012 Print Date: 5/3/2012 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.2 Acute inhalation toxicity Acute inhalation toxicity - Product : no data available Acute inhalation toxicity - Components DIETHYLENE GLYCOL : LC Lo: 130 mg/m3 Exposure time: 2 h Species: Mouse Acute dermal toxicity Acute dermal toxicity - Product : no data available Acute dermal toxicity - Components ETHYLENE GLYCOL : LD 50: 9,530 mg/kg Species: Rabbit DIETHYLENE GLYCOL : LD 50: 11,890 mg/kg Species: Rabbit Acute toxicity (other routes of administration) Acute toxicity (other routes of administration) : no data available 12. ECOLOGICAL INFORMATION Biodegradability Biodegradability - Product : no data available Biodegradability - Components DIETHYLENE GLYCOL : 92 % Bioaccumulation Bioaccumulation - Product : no data available Bioaccumulation - Components ETHYLENE GLYCOL : Species: Crayfish (Procambarus) Exposure time: 61 d Concentration: 1,000 mg/l Bioconcentration factor (BCF): 0.27 Method: Flow through Page 8 / 13 Page 199 of 1235 Page 199 of 1235 Page 199 of 1235 Page 199 of 1235 ---PAGE BREAK--- Page: 9 SAFETY DATA SHEET Revision Date: 05/01/2012 Print Date: 5/3/2012 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.2 Ecotoxicity effects Toxicity to fish Toxicity to fish - Product : no data available Toxicity to fish - Components ETHYLENE GLYCOL : LC 50: 27,540 mg/l Exposure time: 96 h Species: Bluegill (Lepomis macrochirus) Method: Static Remarks: Mortality LC 50: 8,050 mg/l Exposure time: 96 h Species: Fathead minnow (Pimephales promelas) DIETHYLENE GLYCOL : LC 50: > 32,000 mg/l Exposure time: 96 h Species: Western mosquitofish (Gambusia affinis) Method: Static Remarks: Mortality Toxicity to daphnia and other aquatic invertebrates Toxicity to daphnia and other aquatic invertebrates - Product : no data available Toxicity to daphnia and other aquatic invertebrates - Components ETHYLENE GLYCOL : LC 50: > 10,000 mg/l Exposure time: 48 h Species: Water flea (Daphnia magna) Test Type: static test DIETHYLENE GLYCOL : LC 50: > 10,000 mg/l Exposure time: 24 h Species: Water flea (Daphnia magna) Method: Static Remarks: Mortality Page 9 / 13 Page 200 of 1235 Page 200 of 1235 Page 200 of 1235 Page 200 of 1235 ---PAGE BREAK--- Page: 10 SAFETY DATA SHEET Revision Date: 05/01/2012 Print Date: 5/3/2012 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.2 Toxicity to algae Toxicity to algae - Product : no data available Toxicity to bacteria Toxicity to bacteria - Product : no data available 13. DISPOSAL CONSIDERATIONS Waste disposal methods Dispose of in accordance with all applicable local, state and federal regulations. 14. TRANSPORT INFORMATION REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP MARINE POLLUTANT / LTD. QTY. U.S. DOT - ROAD Not dangerous goods U.S. DOT - RAIL Not dangerous goods U.S. DOT - INLAND WATERWAYS Not dangerous goods TRANSPORT CANADA - ROAD Not dangerous goods TRANSPORT CANADA - RAIL Page 10 / 13 Page 201 of 1235 Page 201 of 1235 Page 201 of 1235 Page 201 of 1235 ---PAGE BREAK--- Page: 11 SAFETY DATA SHEET Revision Date: 05/01/2012 Print Date: 5/3/2012 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.2 Not dangerous goods TRANSPORT CANADA - INLAND WATERWAYS Not dangerous goods INTERNATIONAL MARITIME DANGEROUS GOODS Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER Not dangerous goods MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTES Not dangerous goods *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. 15. REGULATORY INFORMATION California Prop. 65 Proposition 65 warnings are not required for this product based on the results of a risk assessment. SARA Hazard Classification SARA 311/312 Classification Acute Health Hazard SARA 313 Component(s) ETHYLENE GLYCOL 95.75 % New Jersey RTK Label Information ETHYLENE GLYCOL 107-21-1 Page 11 / 13 Page 202 of 1235 Page 202 of 1235 Page 202 of 1235 Page 202 of 1235 ---PAGE BREAK--- Page: 12 SAFETY DATA SHEET Revision Date: 05/01/2012 Print Date: 5/3/2012 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.2 DIETHYLENE GLYCOL 111-46-6 WATER 7732-18-5 RTK Label Information ETHYLENE GLYCOL 107-21-1 DIETHYLENE GLYCOL 111-46-6 Notification status US. Toxic Substances Control Act y (positive listing) Canada. Canadian Environmental Protection Act (CEPA). Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133) y (positive listing) Australia. Industrial Chemical (Notification and Assessment) Act y (positive listing) New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand n (Negative listing) Japan. Kashin-Hou Law List n (Negative listing) Korea. Toxic Chemical Control Law (TCCL) List y (positive listing) Philippines. The Toxic Substances and Hazardous and Nuclear Waste Control Act y (positive listing) China. Inventory of Existing Chemical Substances y (positive listing) Reportable quantity - Product US. EPA CERCLA Hazardous Substances (40 CFR 302) 5221 lbs Reportable quantity-Components ETHYLENE GLYCOL 107-21-1 5000 lbs HMIS NFPA Health 1* 1 Flammability 1 1 Physical hazards 0 Instability 0 Specific Hazard 16. OTHER INFORMATION Page 12 / 13 Page 203 of 1235 Page 203 of 1235 Page 203 of 1235 Page 203 of 1235 ---PAGE BREAK--- Page: 13 SAFETY DATA SHEET Revision Date: 05/01/2012 Print Date: 5/3/2012 MSDS Number: 000000139197 Carquest® ANTIFREEZE COOLANT CQ001 Version: 1.2 The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department (1-[PHONE REDACTED]). Page 13 / 13 Page 204 of 1235 Page 204 of 1235 Page 204 of 1235 Page 204 of 1235 ---PAGE BREAK--- MANUFACTURER MATERIAL SAFETY DATA SHEET HAZARD RATING Castle Products, Inc. Hazard: 0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme. Health 1 424 St. Paul Street Protection: A-Goggles, B-Goggles & gloves, Fire 4 Rochester, NY 14605 C-Goggles, gloves, & protective wear. Reactivity 0 1-[PHONE REDACTED] Other: NA-Not Applicable, ND-Not Determined, Protection B EMERGENCY (585) 275-3232 NE-Not Established. SECTION I DESCRIPTION TRADE NAME: Castle® Corrosion Off™ PRODUCT TYPE: Battery Cleaner & Leak Detector SECTION II HAZARDOUS INGREDIENTS INGREDIENT CAS # PEL TLV STEL % Propane/Isobutane/N-Butane 68476-86-8 800 ppm 1000 ppm NE 20.0 % Triethanolamine 102-71-6 NE 5 mg/m3 NE 4.0 % SECTION III PHYSICAL DATA BOILING POINT(F)(CONC): -43 – 651 F SPECIFIC GRAVITY (H2O=1): 0.889 @ 20 C VAPOR PRESSURE: 35-45 VOCS: 499 grams/liter VAPOR DENSITY: >1 EVAPORATION RATE: < 1 SOLUBILITY IN WATER: Soluble APPEARANCE & ODOR Yellow / Mild Solvent SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT (TAG Closed Cup): -156°F LOWER EXPLOSIVE LIMIT: 1.8% UPPER EXPLOSIVE LIMIT: 8.4% EXTINGUISHING MEDIA: Water, Carbon Dioxide, Dry Chemical, Foam. UNUSUAL FIRE & EXPLOSION HAZARDS: Avoid all sources of ignition, welding arcs, and open flames. Vapors can travel to source of ignition and flash back. “Empty” cans may retain product residue and can be hazardous. Do not pressurize, cut, weld, braze, solder, drill, or grind cans. Do not expose cans to heat, flame, sparks, static electricity, or other sources of ignition. Heated cans may build up pressure and explode; can cause injury or death. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus (MSHA / NIOSH approved or equivalent) and full protective gear. SECTION V HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: Eye contact, skin contact, inhalation, and ingestion. EFFECTS OF OVEREXPOSURE: Long-term exposure may cause damage to lungs, kidneys, and/or nervous system. • Eyes: may cause irritation, pain, tearing, reddening, swelling, and stinging. • Skin: defatting and/or drying, irritation, and rash. • Inhalation: difficulty in breathing, headaches, dizziness, nausea, decreased blood pressure, changes in heart rate, and cyanosis. • Ingestion: harmful or fatal. Corrosive: may cause severe, permanent damage to mouth, throat, and stomach. EMERGENCY & FIRST AID PROCEDURES: • Eyes and skin: Flush immediately with plenty of water. Get immediate medical attention. Remove affected clothing and wash separately before reusing. • Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. • Ingestion: Do NOT induce vomiting. Give glass of water or milk. Call physician or poison control immediately. Never give food or drink to an unconscious person. SECTION VI REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (materials to avoid): Strong acids, alkalis, oxidizers, and amines. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. HAZARDOUS DECOMPOSITION PRODUCTS: Hydrocarbon fumes and smoke, oxides of carbon, oxides of nitrogen; may produce forms of chloride, chlorine, and phosgene. SECTION VII SPILL OR LEAK PROCEDURES IF RELEASED OR SPILLED: Absorb spill with inert material (such as dry sand or earth). Dispose in chemical waste container. WASTE DISPOSAL METHOD: Dispose as hazardous waste in accordance with federal, state, and local regulations. SECTION VIII SPECIAL PROTECTION INFORMATION VENTILATION: LOCAL MECHANICAL OTHER RESPIRATORY PROTECTION: If airborne concentrations are expected to exceed exposure limits (listed above), a NIOSH / MSHA approved air-purifying respirator may be permissible. If potential for uncontrolled release, exposure levels are unknown, or if air-purifying respirators may not provide adequate protection, use self-contained, positive pressure air-supplied respirator. EYE PROTECTION: Safety glasses with side shields (or safety goggles) and a face shield. PROTECTIVE GLOVES: Where contact is likely, wear chemical resistant gloves. OTHER PROTECTIVE EQUIPMENT: Where contact is likely, wear chemical suit and rubber boots. Follow standard industrial clothing standards. SECTION IX SPECIAL PRECAUTIONS HANDLING & STORING PRECAUTIONS: Wash thoroughly after handling. Keep away from heat, sparks, or open flame. Store in temperatures below 120°F. Keep from freezing. PREPARED: 07/16/93 UPDATED: 1/7/11 PRODUCT C1614 Page 205 of 1235 Page 205 of 1235 Page 205 of 1235 Page 205 of 1235 ---PAGE BREAK--- Corrosion Off Product Code: C1614 Page 1 of 3 SAFETY DATA SHEET SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle® Corrosion Off™ PRODUCT TYPE: Battery Cleaner PRODUCT CODE: C1614 MANUFACTURED FOR: Castle Products, Inc. 424 St. Paul Street Rochester, NY 14605 [PHONE REDACTED] • FAX [PHONE REDACTED] EMERGENCY [PHONE REDACTED] SECTION 2 HAZARD IDENTIFICATION EMERGENCY OVERVIEW: DANGER: Gases Under Pressure, Flammable, Irritant POTENTIAL HEALTH EFFECTS: Eyes: Irritating to eyes. Skin: Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis. Inhalation: Irritating to respiratory system. Avoid breathing vapors or mists. of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting, and diarrhea. Potential for aspiration if swallowed. SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % Propane/Isobutane/N-Butane 68476-86-8 NE NE NE 10-30% Triethanolamine 102-71-6 50 ppm 5 mg/m3 NE 1-5% 2-Butoxyethanol 111-76-2 NE NE NE SECTION 4 FIRST AID MEASURES First Aid Procedures: Eye contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician if irritation persists. Skin contact: For skin contact flush with large amounts of water. Call a physician if irritation persists. Inhalation: Immediately remove from further exposure. Give supplemental oxygen, if breathing is difficult. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by mouth to an unconscious person. Note to physician: No information available. SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: ≥ -156°F -104°C) LOWER EXPLOSIVE LIMIT: ND UPPER EXPLOSIVE LIMIT: ND EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate for surrounding fire. UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area. Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Ventilate spaces before entering. Environmental precautions: Prevent further leakage or spillage if safe to do so. Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Eliminate ignition sources including sources of electrical, static or frictional sparks. Wear appropriate protective equipment and clothing during clean-up. Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal. Page 206 of 1235 Page 206 of 1235 Page 206 of 1235 Page 206 of 1235 ---PAGE BREAK--- Corrosion Off Product Code: C1614 Page 2 of 3 Large Spills: Dike far ahead of liquid spill for later disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. SECTION 7 HANDLING AND STORAGE Handling: Propellant is extremely flammable. Do not store near ignition sources. Avoid breathing mist. Avoid contact with skin and eyes. Wear suitable protective clothing. Wash hands after handling. Storage: Keep from freezing. Keep containers closed. Store in a cool, dry place. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established. Engineering controls: Use local exhaust ventilation. Personal protective equipment: Gloves: Not normally required. Eye/Face Protection: Safety glasses or goggles. Skin Protection: Wear clothing suited to the task being performed. Respiratory Protection: Not normally required if good ventilation is maintained. SECTION 9 PHYSICAL and CHEMICAL PROPERTIES BOILING POINT: ND SPECIFIC GRAVITY (H2O=1): ND VAPOR PRESSURE: ND PERCENT VOLATILE BY VOL 18% VAPOR DENSITY (air=1) >1 EVAPORATION RATE (Butyl Acetate=1): ND SOLUBILITY IN WATER: ND APPEARANCE & ODOR: Yellow Liquid / Mild Solvent pH: 9 SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable. INCOMPATIBILITY (material to avoid): Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Oxides, Nitrogen Oxides, fumes. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Components Test Results: Triethanolamine: Oral LD50 (rat) 4190 mg/kg; Dermal LD50 (rabbit) 2000 mg/kg 2-Butoxyethanol: Oral LD50 (rat) 470 mg/kg; Dermal LD50 (rabbit) 220 mg/kg; Inhalation LC50 (rat) 450 ppm (4h) There are no known carcinogenic chemicals in this product. SECTION 12 ECOLOGICAL INFORMATION Component Test Results: None reported. SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Dispose according to all applicable Federal, State, and Local regulations. SECTION 14 TRANSPORT INFORMATION DOT Ground: Consumer Commodity ORM-D, or Limited Quantity. SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations. CERCLA (Superfund) reportable quantity: None SARA (Superfund Amendments and Reauthorization Act of 1986): 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Section 302 extremely hazardous substance: No Section 311 hazardous chemical: Acute Health Hazard: Yes; Chronic Health Hazard: No; Fire Hazard: No; Sudden Release of Pressure Hazard: No. Page 207 of 1235 Page 207 of 1235 Page 207 of 1235 Page 207 of 1235 ---PAGE BREAK--- Corrosion Off Product Code: C1614 Page 3 of 3 Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR. SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.) HMIS® ratings Health: 1 Flammability: 2 Physical hazard: 2 NFPA ratings Health: 1 Flammability: 4 Instability: 0 Other: NA-Not Applicable, ND-Not Determined, NE-Not Established. Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. PREPARED: 7/16/93 UPDATED: 6/14/13 PRODUCT C1614 Page 208 of 1235 Page 208 of 1235 Page 208 of 1235 Page 208 of 1235 ---PAGE BREAK--- Endura Product Code: C1630 Page 1 of 3 SAFETY DATA SHEET SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle® Endura™ PRODUCT TYPE: Heavy Duty Penetrating Grease PRODUCT CODE: C1630 MANUFACTURED FOR: Castle Products, Inc. 424 St. Paul Street Rochester, NY 14605 [PHONE REDACTED] • FAX [PHONE REDACTED] EMERGENCY [PHONE REDACTED] SECTION 2 HAZARD IDENTIFICATION EMERGENCY OVERVIEW: DANGER: Gases Under Pressure, Flammable, Irritant POTENTIAL HEALTH EFFECTS: Eyes: Irritating to eyes. Skin: Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis. Inhalation: Irritating to the respiratory system. Avoid breathing vapors or mists. of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, and cessation of breathing. Ingestion: Not an expected route of exposure. Potential for aspiration if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting, and diarrhea. SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % Propane/Isobutane/N-Butane 68476-86-8 NE NE NE 15-40% Naphthenic Oil, Severely Hydrotreated 64742-52-5 NE NE NE 10-30% Heptane 64742-49-0 NE NE NE 10-30% Polymer Viscosity Modifier Mixture NE NE NE 7-13% Petrolatum 8009-03-8 NE NE NE 5-10% SECTION 4 FIRST AID MEASURES First Aid Procedures: Eye contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician if irritation persists. Skin contact: For skin contact flush with large amounts of water. Call a physician if irritation persists. Inhalation: Immediately remove from further exposure. Give supplemental oxygen, if breathing is difficult. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by mouth to an unconscious person. Note to physician: If the product is ingested, treat the affected person SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: -141°F (-96°C) LOWER EXPLOSIVE LIMIT: ND UPPER EXPLOSIVE LIMIT: ND EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate for surrounding fire. UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: Pressure can build up in containers if exposed to heat (fire). Keep containers in surrounding areas cool with water spray. As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area. Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Ventilate spaces before entering. Environmental precautions: Prevent further leakage or spillage if safe to do so. Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Eliminate ignition sources including sources of electrical, static or frictional sparks. Wear appropriate protective equipment and clothing during clean-up. Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal. Page 209 of 1235 Page 209 of 1235 Page 209 of 1235 Page 209 of 1235 ---PAGE BREAK--- Endura Product Code: C1630 Page 2 of 3 Large Spills: Dike far ahead of liquid spill for later disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. SECTION 7 HANDLING AND STORAGE Handling: Aerosol is extremely flammable. Do not store near heat, sparks, or flames. Avoid breathing mist. Avoid contact with skin and eyes. Wear suitable protective clothing. Wash hands after handling. Storage: Keep from freezing. Keep containers closed. Store in a cool, dry place. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established. Engineering controls: Use local exhaust ventilation. Personal protective equipment: Gloves: Wear impervious gloves. Eye/Face Protection: Wear safety glasses or goggles. Skin Protection: Wear clothing suited to the task being performed. Respiratory Protection: Not normally required if good ventilation is maintained. SECTION 9 PHYSICAL and CHEMICAL PROPERTIES BOILING POINT: ND SPECIFIC GRAVITY (H2O=1): ND VAPOR PRESSURE: ND PERCENT VOLATILE BY VOL 50% VAPOR DENSITY (air=1) >1 EVAPORATION RATE (Butyl Acetate=1): ND SOLUBILITY IN WATER: ND APPEARANCE & ODOR: Red Grease / Solvent pH: NA SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable under recommended storage conditions. INCOMPATIBILITY (material to avoid): Strong oxidizing agents, strong bases. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon oxides, fumes. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Components Test Results: None reported. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. SECTION 12 ECOLOGICAL INFORMATION Component Test Results: None reported. SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Dispose according to all applicable Federal, State, and Local regulations. SECTION 14 TRANSPORT INFORMATION DOT ground, Consumer Commodity ORM-D, or Limited Quantity. SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations. CERCLA (Superfund) reportable quantity: None SARA (Superfund Amendments and Reauthorization Act of 1986): 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Section 302 extremely hazardous substance: No Section 311 hazardous chemical: No Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR. Page 210 of 1235 Page 210 of 1235 Page 210 of 1235 Page 210 of 1235 ---PAGE BREAK--- Endura Product Code: C1630 Page 3 of 3 SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.) HMIS® ratings Health: 1 Flammability: 4 Physical hazard: 2 NFPA ratings Health: 1 Flammability: 4 Instability: 0 Other: NA-Not Applicable, ND-Not Determined, NE-Not Established. Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. PREPARED: 6/21/93 UPDATED: 6/14/13 PRODUCT C1630 Page 211 of 1235 Page 211 of 1235 Page 211 of 1235 Page 211 of 1235 ---PAGE BREAK--- Endura Product Code: C1630 Page 1 of 3 SAFETY DATA SHEET SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle® Endura™ PRODUCT TYPE: Heavy Duty Penetrating Grease PRODUCT CODE: C1630 MANUFACTURED FOR: Castle Products, Inc. 424 St. Paul Street Rochester, NY 14605 [PHONE REDACTED] • FAX [PHONE REDACTED] EMERGENCY [PHONE REDACTED] SECTION 2 HAZARD IDENTIFICATION EMERGENCY OVERVIEW: DANGER: Gases Under Pressure, Flammable, Irritant POTENTIAL HEALTH EFFECTS: Eyes: Irritating to eyes. Skin: Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis. Inhalation: Irritating to the respiratory system. Avoid breathing vapors or mists. of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, and cessation of breathing. Ingestion: Not an expected route of exposure. Potential for aspiration if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting, and diarrhea. SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % Propane/Isobutane/N-Butane 68476-86-8 NE NE NE 15-40% Naphthenic Oil, Severely Hydrotreated 64742-52-5 NE NE NE 10-30% Heptane 64742-49-0 NE NE NE 10-30% Polymer Viscosity Modifier Mixture NE NE NE 7-13% Petrolatum 8009-03-8 NE NE NE 5-10% SECTION 4 FIRST AID MEASURES First Aid Procedures: Eye contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician if irritation persists. Skin contact: For skin contact flush with large amounts of water. Call a physician if irritation persists. Inhalation: Immediately remove from further exposure. Give supplemental oxygen, if breathing is difficult. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by mouth to an unconscious person. Note to physician: If the product is ingested, treat the affected person SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: -141°F (-96°C) LOWER EXPLOSIVE LIMIT: ND UPPER EXPLOSIVE LIMIT: ND EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate for surrounding fire. UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: Pressure can build up in containers if exposed to heat (fire). Keep containers in surrounding areas cool with water spray. As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area. Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Ventilate spaces before entering. Environmental precautions: Prevent further leakage or spillage if safe to do so. Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Eliminate ignition sources including sources of electrical, static or frictional sparks. Wear appropriate protective equipment and clothing during clean-up. Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal. Page 212 of 1235 Page 212 of 1235 Page 212 of 1235 Page 212 of 1235 ---PAGE BREAK--- Endura Product Code: C1630 Page 2 of 3 Large Spills: Dike far ahead of liquid spill for later disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. SECTION 7 HANDLING AND STORAGE Handling: Aerosol is extremely flammable. Do not store near heat, sparks, or flames. Avoid breathing mist. Avoid contact with skin and eyes. Wear suitable protective clothing. Wash hands after handling. Storage: Keep from freezing. Keep containers closed. Store in a cool, dry place. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established. Engineering controls: Use local exhaust ventilation. Personal protective equipment: Gloves: Wear impervious gloves. Eye/Face Protection: Wear safety glasses or goggles. Skin Protection: Wear clothing suited to the task being performed. Respiratory Protection: Not normally required if good ventilation is maintained. SECTION 9 PHYSICAL and CHEMICAL PROPERTIES BOILING POINT: ND SPECIFIC GRAVITY (H2O=1): ND VAPOR PRESSURE: ND PERCENT VOLATILE BY VOL 50% VAPOR DENSITY (air=1) >1 EVAPORATION RATE (Butyl Acetate=1): ND SOLUBILITY IN WATER: ND APPEARANCE & ODOR: Red Grease / Solvent pH: NA SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable under recommended storage conditions. INCOMPATIBILITY (material to avoid): Strong oxidizing agents, strong bases. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon oxides, fumes. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Components Test Results: None reported. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. SECTION 12 ECOLOGICAL INFORMATION Component Test Results: None reported. SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Dispose according to all applicable Federal, State, and Local regulations. SECTION 14 TRANSPORT INFORMATION DOT ground, Consumer Commodity ORM-D, or Limited Quantity. SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations. CERCLA (Superfund) reportable quantity: None SARA (Superfund Amendments and Reauthorization Act of 1986): 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Section 302 extremely hazardous substance: No Section 311 hazardous chemical: No Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR. Page 213 of 1235 Page 213 of 1235 Page 213 of 1235 Page 213 of 1235 ---PAGE BREAK--- Endura Product Code: C1630 Page 3 of 3 SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.) HMIS® ratings Health: 1 Flammability: 4 Physical hazard: 2 NFPA ratings Health: 1 Flammability: 4 Instability: 0 Other: NA-Not Applicable, ND-Not Determined, NE-Not Established. Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. PREPARED: 6/21/93 UPDATED: 6/14/13 PRODUCT C1630 Page 214 of 1235 Page 214 of 1235 Page 214 of 1235 Page 214 of 1235 ---PAGE BREAK--- MANUFACTURER MATERIAL SAFETY DATA SHEET HAZARD RATING Castle Products, Inc. Hazard: 0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme. Health 1 424 St. Paul Street Protection: A-Goggles, B-Goggles & gloves, Fire 4 Rochester, NY 14605 C-Goggles, gloves, & protective wear. Reactivity 0 1-[PHONE REDACTED] Other: NA-Not Applicable, ND-Not Determined, Protection B EMERGENCY (585) 275-3232 NE-Not Established. SECTION I DESCRIPTION TRADE NAME: Castle® Endura™ PRODUCT TYPE: Heavy Duty Penetrating Grease SECTION II HAZARDOUS INGREDIENTS INGREDIENT CAS # PEL TLV STEL % Propane/Isobutane/n-Butane 68476-86-8 800 ppm 1000 ppm NE 35.0 % N-Heptane 142-82-5 400 ppm 400 ppm 500 ppm 20.0 % Olefin Polymer Proprietary 5 mg/m3 5 mg/m3 10 mg/m3 15.0 % LT. Naphthenic Distillate 64742-52-5 NE NE NE < 10 % Petrolatum 8009-03-8 NE NE NE < 10 % SECTION III PHYSICAL DATA BOILING POINT: -43°F - 209°F SPECIFIC GRAVITY (H2O=1): 0.6829 VAPOR PRESSURE: 60-70 PERCENT VOLATILE BY VOL % NE VAPOR DENSITY: Heavier than air EVAPORATION RATE: Faster than Butyl Acetate SOLUBILITY IN WATER: Negligible APPEARANCE & ODOR: Hazy Amber / Solvent SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT (method used): -156°F (Pensky-Martens C.C.) LOWER EXPLOSIVE LIMIT: 1.2 % UPPER EXPLOSIVE LIMIT: 9.5 % EXTINGUISHING MEDIA: CO2, dry chemical foam, or water fog. UNUSUAL FIRE & EXPLOSION HAZARDS: Avoid all sources of ignition, welding arcs, and open flames. Vapors can travel to source of ignition and flash back. “Empty” cans may retain product residue and can be hazardous. Do not pressurize, cut, weld, braze, solder, drill, or grind cans. Do not expose cans to heat, flame, sparks, static electricity, or other sources of ignition. Heated cans may build up pressure and explode; can cause injury or death. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus (MSHA / NIOSH approved or equivalent) and full protective gear. SECTION V HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: Eye contact, skin contact, inhalation, and ingestion. EFFECTS OF OVEREXPOSURE: Long-term exposure may cause damage to lungs, kidneys, and/or nervous system. • Eyes: may cause irritation, pain, tearing, reddening, swelling, and stinging. • Skin: defatting, drying, irritation, and rash. • Inhalation: difficulty in breathing, headaches, dizziness, nausea, decreased blood pressure, changes in heart rate, and cyanosis. • Ingestion: harmful or fatal. Corrosive: may cause severe, permanent damage to mouth, throat, and stomach. EMERGENCY & FIRST AID PROCEDURES: • Eyes and skin: Flush immediately with plenty of water. Get immediate medical attention. Remove affected clothing and wash separately before reusing. • Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. • Ingestion: Do NOT induce vomiting. Give glass of water or milk. Call physician or poison control immediately. Never give food or drink to an unconscious person. SECTION VI REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (materials to avoid): Strong acids, alkalis, oxidizers, and amines. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon, oxides of nitrogen; may produce forms of chloride, chlorine, and phosgene. SECTION VII SPILL OR LEAK PROCEDURES IF RELEASED OR SPILLED: Absorb spill with inert material (such as dry sand or earth). Dispose in chemical waste container. WASTE DISPOSAL METHOD: Dispose as hazardous waste in accordance with federal, state, and local regulations. SECTION VIII SPECIAL PROTECTION INFORMATION VENTILATION: LOCAL MECHANICAL OTHER RESPIRATORY PROTECTION: If airborne concentrations are expected to exceed exposure limits (listed above), a NIOSH / MSHA approved air-purifying respirator may be permissible. If potential for uncontrolled release, exposure levels are unknown, or if air-purifying respirators may not provide adequate protection, use self-contained, positive pressure air-supplied respirator. EYE PROTECTION: Safety glasses with side shields (or safety goggles) and a face shield. PROTECTIVE GLOVES: Where contact is likely, wear chemical resistant gloves. OTHER PROTECTIVE EQUIPMENT: Where contact is likely, wear chemical suit and rubber boots. Follow standard industrial clothing standards. SECTION IX SPECIAL PRECAUTIONS HANDLING & STORING PRECAUTIONS: Wash thoroughly after handling. Keep away from heat, sparks, or open flame. Store in temperatures below 120°F. Keep from freezing. PREPARED: 06/21/93 UPDATED: 1/7/11 PRODUCT C1630 Page 215 of 1235 Page 215 of 1235 Page 215 of 1235 Page 215 of 1235 ---PAGE BREAK--- MANUFACTURER MATERIAL SAFETY DATA SHEET HAZARD RATING Castle Products, Inc. Hazard: 0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme. Health 1 424 St. Paul Street Protection: A-Goggles, B-Goggles & gloves, Fire 4 Rochester, NY 14605 C-Goggles, gloves, & protective wear. Reactivity 0 1-[PHONE REDACTED] Other: NA-Not Applicable, ND-Not Determined, Protection B EMERGENCY (585) 275-3232 NE-Not Established. SECTION I DESCRIPTION TRADE NAME: Castle® Kleenz Oil™ PRODUCT TYPE: Spray Degreaser SECTION II HAZARDOUS INGREDIENTS INGREDIENT CAS # PEL TLV STEL % Isopar M Fluid 64742-47-8 NE NE NE 65.0 % Solvent Naphtha 64742-94-5 100 ppm 100 ppm NE 20.0 % Propane/Isobutane/n-Butane 68476-86-8 800 ppm 800 ppm NE 15.0 % Naphthalene 91-20-3 10 ppm 10 ppm (skin) 15 ppm (skin) 5.0 % SECTION III PHYSICAL DATA BOILING POINT: -43°F - 522°F SPECIFIC GRAVITY (H2O=1): 0.7840 VAPOR PRESSURE: 80-90 PERCENT VOLATILE BY VOL NE VAPOR DENSITY: Heavier than air EVAPORATION RATE: Faster than Butyl Acetate SOLUBILITY IN WATER: Negligible APPEARANCE & ODOR: Clear / Bouquet SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT (method used): -156°F (Pensky-Martens C.C.) LOWER EXPLOSIVE LIMIT: 0.9 % UPPER EXPLOSIVE LIMIT: 9.5 % EXTINGUISHING MEDIA: Alcohol foam, CO2, dry chemical foam, or water fog. UNUSUAL FIRE & EXPLOSION HAZARDS: Avoid all sources of ignition, welding arcs, and open flames. Vapors can travel to source of ignition and flash back. “Empty” cans may retain product residue and can be hazardous. Do not pressurize, cut, weld, braze, solder, drill, or grind cans. Do not expose cans to heat, flame, sparks, static electricity, or other sources of ignition. Heated cans may build up pressure and explode; can cause injury or death. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus (MSHA / NIOSH approved or equivalent) and full protective gear. SECTION V HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: Eye contact, skin contact, inhalation, and ingestion. EFFECTS OF OVEREXPOSURE: Long-term exposure may cause damage to lungs, kidneys, and/or nervous system. •Eyes: may cause irritation, pain, tearing, reddening, swelling, and stinging. •Skin: defatting, drying, irritation, and rash. •Inhalation: difficulty in breathing, headaches, dizziness, nausea, decreased blood pressure, changes in heart rate, and cyanosis. •Ingestion: harmful or fatal. May cause severe, permanent damage to mouth, throat, and stomach. EMERGENCY & FIRST AID PROCEDURES: •Eyes and skin: Flush immediately with plenty of water. Get immediate medical attention. Remove affected clothing and wash separately before reusing. •Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. •Ingestion: Do NOT induce vomiting. Give glass of water or milk. Call physician or poison control immediately. Never give food or drink to an unconscious person. SECTION VI REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (material to avoid): Strong acids, alkalis, oxidizers, and amines. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon, oxides of nitrogen, and may produce forms of chloride, chlorine, and phosgene. SECTION VII SPILL OR LEAK PROCEDURES IF RELEASED OR SPILLED: Absorb spill with inert material (such as dry sand or earth). Dispose in chemical waste container. WASTE DISPOSAL METHOD: Dispose as hazardous waste accordance with federal, state, and local regulations. SECTION VIII SPECIAL PROTECTION INFORMATION VENTILATION: LOCAL MECHANICAL OTHER RESPIRATORY PROTECTION: If airborne concentrations are expected to exceed Threshold Limit Values (TLV), a NIOSH/MSHA approved air-purifying respirator may be permissible. If potential for uncontrolled release, exposure levels are unknown, or if air-purifying respirators may not provide adequate protection, use self-contained, positive pressure air-supplied respirator. EYE PROTECTION: Safety glasses with side shields (or safety goggles) and a face shield. PROTECTIVE GLOVES: Where contact is likely, wear chemical resistant gloves. OTHER PROTECTIVE EQUIPMENT: Where contact is likely, wear chemical suit and rubber boots. Follow standard industrial clothing standards. SECTION IX SPECIAL PRECAUTIONS PRECAUTIONS FOR HANDLING & STORING: Wash hands thoroughly after handling. Keep away from heat, sparks, or open flame. Store at temperatures below 120°F. Keep from freezing. PREPARED: 04/22/93 UPDATED: 1/21/09 PRODUCT C2008 Page 216 of 1235 Page 216 of 1235 Page 216 of 1235 Page 216 of 1235 ---PAGE BREAK--- MANUFACTURER MATERIAL SAFETY DATA SHEET HAZARD RATING Castle Products, Inc. Hazard: 0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme. Health 2 424 St. Paul Street Protection: A-Goggles, B-Goggles & gloves, Fire 4 Rochester, NY 14605 C-Goggles, gloves, & protective wear. Reactivity 0 1-[PHONE REDACTED] Other: NA-Not Applicable, ND-Not Determined, Protection B EMERGENCY (585) 275-3232 NE-Not Established. SECTION I DESCRIPTION TRADE NAME: Castle® Long Life™ PRODUCT TYPE: Battery Protector SECTION II HAZARDOUS INGREDIENTS INGREDIENT CAS # PEL TLV STEL % Heptanes 64742-49-0 500 ppm 400 ppm 500 ppm 40-50 % Propane/Isobutane/n-Butane 68476-86-8 NE NE NE 30-40% Distillates, petroleum, hydrotreated nap 64742-52-5 5 mg/m3 5 mg/m3 10 mg/m3 10-20 % Residual oils, petroleum, severely refin 64742-01-4 100 ppm 100 ppm NE 1-10 % Corrosion inhibitor Mixture 100 ppm 100 ppm NE 1-10% Mineral spirits 8052-41-3 100 ppm 100 ppm NE 1-10 % SECTION III PHYSICAL DATA BOILING POINT: -23°F - 387°F SPECIFIC GRAVITY (H2O=1): 0.8523 @ 20C VAPOR PRESSURE: ND VOCS 77.57% VAPOR DENSITY: Heavier than air EVAPORATION RATE (Butyl Acetate=1): Faster than Butyl Acetate SOLUBILITY IN WATER: Negligible APPEARANCE & ODOR Purple / Solvent SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT (method used): -141°F (TCC) LOWER EXPLOSIVE LIMIT: 0.7 % UPPER EXPLOSIVE LIMIT: 9.5 % EXTINGUISHING MEDIA: Alcohol foam, CO2, dry chemical foam, or water fog. UNUSUAL FIRE & EXPLOSION HAZARDS: Avoid all sources of ignition, welding arcs, and open flames. Vapors can travel to source of ignition and flash back. “Empty” cans may retain product residue and can be hazardous. Do not pressurize, cut, weld, braze, solder, drill, or grind cans. Do not expose cans to heat, flame, sparks, static electricity, or other sources of ignition. Heated cans may build up pressure and explode; can cause injury or death. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus (MSHA / NIOSH approved or equivalent) and full protective gear. SECTION V HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: Eye contact, skin contact, inhalation, and ingestion. EFFECTS OF OVEREXPOSURE: Vapors irritating to eyes and respiratory tract. Vapors may cause flash fire or explosion. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. • Eyes: may cause irritation, pain, tearing, reddening, swelling, and stinging. • Skin: defatting, drying, irritation, and rash. • Inhalation: Prolonged inhalation may be harmful. • Ingestion: harmful or fatal. Aspiration hazard. EMERGENCY & FIRST AID PROCEDURES: • Eyes and skin: Flush immediately with plenty of water. Get immediate medical attention. Remove affected clothing and wash separately before reusing. • Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. • Ingestion: Do NOT induce vomiting. Call physician or poison control immediately. Never give food or drink to an unconscious person. SECTION VI REACTIVITY DATA STABILITY: Avoid all sources of ignition, welding arcs, and open flames. INCOMPATIBILITY (materials to avoid): Strong oxidizing agents such as chlorates, nitrates, peroxides, etc. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. HAZARDOUS DECOMPOSITION PRODUCTS: Smoke, oxides of carbon, oxides of nitrogen, phosphorous, and/or sulfur are possible. SECTION VII SPILL OR LEAK PROCEDURES IF RELEASED OR SPILLED: Absorb spill with inert material (such as dry sand or earth). Dispose in chemical waste container. WASTE DISPOSAL METHOD: Dispose in accordance with federal, state, and local regulations. SECTION VIII SPECIAL PROTECTION INFORMATION VENTILATION: LOCAL MECHANICAL OTHER RESPIRATORY PROTECTION: If airborne concentrations are expected to exceed exposure limits (listed above), a NIOSH / MSHA approved air-purifying respirator may be permissible. If potential for uncontrolled release, exposure levels are unknown, or if air-purifying respirators may not provide adequate protection, use self-contained, positive pressure air-supplied respirator. EYE PROTECTION: Safety glasses with side shields (or safety goggles) and a face shield. PROTECTIVE GLOVES: Where contact is likely, wear chemical resistant gloves. OTHER PROTECTIVE EQUIPMENT: Where contact is likely, wear chemical suit and rubber boots. Follow standard industrial clothing standards. SECTION IX SPECIAL PRECAUTIONS HANDLING & STORING PRECAUTIONS: Wash thoroughly after handling. Keep away from heat, sparks, or open flame. Store at temperature below 120°F. Keep from freezing. PREPARED: 10/21/93 UPDATED: 10/7/09 PRODUCT C1607 Page 217 of 1235 Page 217 of 1235 Page 217 of 1235 Page 217 of 1235 ---PAGE BREAK--- Muscle Grease Product Code: C1606 Page 1 of 3 SAFETY DATA SHEET SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle® Muscle Grease™ PRODUCT TYPE: Lubricating Grease PRODUCT CODE: C1606 MANUFACTURED FOR: Castle Products, Inc. 424 St. Paul Street Rochester, NY 14605 [PHONE REDACTED] • FAX [PHONE REDACTED] EMERGENCY [PHONE REDACTED] SECTION 2 HAZARD IDENTIFICATION EMERGENCY OVERVIEW: DANGER: Gases Under Pressure, Flammable, Irritant POTENTIAL HEALTH EFFECTS: Eyes: Irritating to eyes. Skin: Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis. Inhalation: Irritating to respiratory system. Avoid breathing vapors or mists. of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting, and diarrhea. Potential for aspiration if swallowed. SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % Naphthenic Oil, Severely Hydrotreated 64742-52-5 NE NE NE 10-30% Heptane 64742-49-0 NE NE NE 10-30% Propane/Isobutane/N-Butane 68476-86-8 NE NE NE 10-30% Acetone 67-64-1 1000ppm 750ppm 750ppm 7-13% Bright Stock, Severely Hydrotreated 64742-57-0 NE NE NE 3-7% Aluminum Complex Thickener Proprietary NE NE NE 1-5% SECTION 4 FIRST AID MEASURES First Aid Procedures: Eye contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician if irritation persists. Skin contact: For skin contact flush with large amounts of water. Call a physician if irritation persists. Inhalation: Immediately remove from further exposure. Give supplemental oxygen, if breathing is difficult. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by mouth to an unconscious person. Note to physician: If the product is ingested, treat the affected person SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: Propellants: <0°F PRODUCT: LOWER EXPLOSIVE LIMIT: ND UPPER EXPLOSIVE LIMIT: ND EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area. Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Ventilate spaces before entering. Environmental precautions: Prevent further leakage or spillage if safe to do so. Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Eliminate ignition sources including sources of electrical, static or frictional sparks. Wear appropriate protective equipment and clothing during clean-up. Page 218 of 1235 Page 218 of 1235 Page 218 of 1235 Page 218 of 1235 ---PAGE BREAK--- Muscle Grease Product Code: C1606 Page 2 of 3 Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal. Large Spills: Dike far ahead of liquid spill for later disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. SECTION 7 HANDLING AND STORAGE Handling: Propellant is extremely flammable. Avoid breathing mist. Avoid contact with skin and eyes. Wear suitable protective clothing. Wash hands after handling. Storage: Keep from freezing. Keep containers closed. Store in a cool, dry place. Do not store near ignition sources. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established. Engineering controls: Use local exhaust ventilation. Personal protective equipment: General: Eye wash fountain and emergency showers are recommended. Eye/face Protection: Safety glasses or goggles. Skin Protection: Wear suitable protective clothing. Impervious gloves are recommended, but not required. Respiratory Protection: Generally not required. When respiratory protection is required, wear a NIOSH/MSHA approved self-contained breathing apparatus with full facepiece operated in a positive-pressure mode. SECTION 9 PHYSICAL and CHEMICAL PROPERTIES BOILING POINT: -23 to 551°F SPECIFIC GRAVITY (H2O=1): ND VAPOR PRESSURE: ND PERCENT VOLATILE BY VOL 49% VAPOR DENSITY (air=1) >1 EVAPORATION RATE (Butyl Acetate=1): ND SOLUBILITY IN WATER: Negligible APPEARANCE & ODOR: Red Liquid / Solvent pH: NA VOC 30-70% SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (material to avoid): Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide, Carbon Dioxide, Hydrocarbon fumes and smoke. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Components Test Results: NA. There are no known carcinogenic chemicals in this product. SECTION 12 ECOLOGICAL INFORMATION Component Test Results: NA. SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Do not puncture or incinerate containers, even when empty. Dispose according to all applicable Federal, State, and Local regulations. SECTION 14 TRANSPORT INFORMATION This product is packaged appropriately for consumer use. Therefore, the classification is: CONSUMER COMMODITY, ORM-D SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations. CERCLA (Superfund) reportable quantity: None SARA (Superfund Amendments and Reauthorization Act of 1986): 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Section 302 extremely hazardous substance: No Section 311 hazardous chemical: No Page 219 of 1235 Page 219 of 1235 Page 219 of 1235 Page 219 of 1235 ---PAGE BREAK--- Muscle Grease Product Code: C1606 Page 3 of 3 Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR. SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.) HMIS® ratings Health: 1 Flammability: 4 Physical hazard: 2 NFPA ratings Health: 1 Flammability: 4 Instability: 0 Other: NA-Not Applicable, ND-Not Determined, NE-Not Established. Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. PREPARED: 11/29/93 UPDATED: 6/14/13 PRODUCT C1606 Page 220 of 1235 Page 220 of 1235 Page 220 of 1235 Page 220 of 1235 ---PAGE BREAK--- MANUFACTURER MATERIAL SAFETY DATA SHEET HAZARD RATING Castle Products, Inc. Hazard: 0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme. Health 1 424 St. Paul Street Protection: A-Goggles, B-Goggles & gloves, Fire 4 Rochester, NY 14605 C-Goggles, gloves, & protective wear. Reactivity 0 1-[PHONE REDACTED] Other: NA-Not Applicable, ND-Not Determined, Protection B EMERGENCY (585) 275-3232 NE-Not Established. SECTION I DESCRIPTION TRADE NAME: Castle® Muscle Grease™ PRODUCT TYPE: Red Grease Lubricant SECTION II HAZARDOUS INGREDIENTS INGREDIENT CAS # PEL TLV STEL % N-Heptane 142-82-5 400 ppm 400 ppm 500 ppm 30 % Propane/Isobutane/n-Butane 68476-86-8 800 ppm 1000 ppm NE 25 % 2-Propanone 67-64-1 750 ppm 750 ppm 1000 ppm 15 % Petroleum Hydrocarbon 64742-57-0 5 mg/m3 NE 10 mg/m3 10 % Mineral Oil Hydrotreated 64742-52-5 NE NE NE > 3 % Petroleum Lubricating Grease Mixture NE NE NE > 3 % Toluene 108-88-3 200 ppm NE NE NE Benzene 71-43-2 1 ppm NE 5 ppm NE SECTION III PHYSICAL DATA BOILING POINT: -43°F - 551°F SPECIFIC GRAVITY (H2O=1): 0.7074 VAPOR PRESSURE: 80-90 PERCENT VOLATILE BY VOL NE VAPOR DENSITY: Heavier than air EVAPORATION RATE: Faster than Butyl Acetate SOLUBILITY IN WATER: Negligible APPEARANCE & ODOR: Red / Solvent SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT (method used): -156°F (Pensky-Martens C.C.) LOWER EXPLOSIVE LIMIT: 1.2% UPPER EXPLOSIVE LIMIT: 12.8 % EXTINGUISHING MEDIA: Alcohol foam, CO2, dry chemical foam, or water fog. UNUSUAL FIRE & EXPLOSION HAZARDS: Avoid all sources of ignition, welding arcs, and open flames. Vapors can travel to source of ignition and flash back. “Empty” cans may retain product residue and can be hazardous. Do not pressurize, cut, weld, braze, solder, drill, or grind cans. Do not expose cans to heat, flame, sparks, static electricity, or other sources of ignition. Heated cans may build up pressure and explode; can cause injury or death. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus (MSHA / NIOSH approved or equivalent) and full protective gear. SECTION V HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: Eye contact, skin contact, inhalation, and ingestion. EFFECTS OF OVEREXPOSURE: Long-term exposure may cause damage to lungs, kidneys, and/or nervous system. • Eyes: may cause irritation, pain, tearing, reddening, swelling, and stinging. • Skin: defatting, drying, irritation, and rash. • Inhalation: difficulty in breathing, headaches, dizziness, nausea, decreased blood pressure, changes in heart rate, and cyanosis. • Ingestion: harmful or fatal. Corrosive: may cause severe, permanent damage to mouth, throat, and stomach. EMERGENCY & FIRST AID PROCEDURES: • Eyes and skin: Flush immediately with plenty of water. Get immediate medical attention. Remove affected clothing and wash separately before reusing. • Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. • Ingestion: Do NOT induce vomiting. Give glass of water or milk. Call physician or poison control immediately. Never give food or drink to an unconscious person. SECTION VI REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (materials to avoid): Strong acids, alkalis, oxidizers, and amines. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon, oxides of nitrogen; may produce forms of chloride, chlorine, and phosgene. SECTION VII SPILL OR LEAK PROCEDURES IF RELEASED OR SPILLED: Absorb spill with inert material (such as dry sand or earth). Dispose in chemical waste container. WASTE DISPOSAL METHOD: Dispose as hazardous waste in accordance with federal, state, and local regulations. SECTION VIII SPECIAL PROTECTION INFORMATION VENTILATION: LOCAL MECHANICAL OTHER RESPIRATORY PROTECTION: If airborne concentrations are expected to exceed exposure limits (listed above), a NIOSH / MSHA approved air-purifying respirator may be permissible. If potential for uncontrolled release, exposure levels are unknown, or if air-purifying respirators may not provide adequate protection, use self-contained, positive pressure air-supplied respirator. EYE PROTECTION: Safety glasses with side shields (or safety goggles) and a face shield. PROTECTIVE GLOVES: Where contact is likely, wear chemical resistant gloves. OTHER PROTECTIVE EQUIPMENT: Where contact is likely, wear chemical suit and rubber boots. Follow standard industrial clothing standards. SECTION IX SPECIAL PRECAUTIONS HANDLING & STORING PRECAUTIONS: Wash thoroughly after handling. Keep away from heat, sparks, or open flame. Store at temperature below 120°F. Keep from freezing. PREPARED: 11/29/93 UPDATED: 1/7/11 PRODUCT C1606 Page 221 of 1235 Page 221 of 1235 Page 221 of 1235 Page 221 of 1235 ---PAGE BREAK--- MANUFACTURER MATERIAL SAFETY DATA SHEET HAZARD RATING Castle Products, Inc. Hazard: 0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme. Health 2 424 St. Paul Street Protection: A-Goggles, B-Goggles & gloves, Fire 3 Rochester, NY 14605 C-Goggles, gloves, & protective wear. Reactivity 0 1-[PHONE REDACTED] Other: NA-Not Applicable, ND-Not Determined, Protection B EMERGENCY (585) 275-3232 NE-Not Established. SECTION I DESCRIPTION TRADE NAME: Castle® Rubberized Undercoating™ PRODUCT TYPE: Abrasion-Resistant Undercoat SECTION II HAZARDOUS INGREDIENTS INGREDIENT CAS # PEL TLV STEL % Acetone 67-64-1 NE NE NE 10-45 % Toluene 108-88-3 NE 50 ppm NE 10-30 % Propane 74-98-6 NE 1000 ppm NE 10-30 % Calcium Carbonate 1317-65-3 NE NE NE 7-13 % Isobutane 75-28-5 NE NE NE 5-10 % Carbon Black 1333-86-4 NE NE NE .1-1 % SECTION III PHYSICAL DATA BOILING POINT: NE SPECIFIC GRAVITY (H2O=1): 0.92 – 0.96 (liquid by weight) VAPOR PRESSURE: 55-65 PERCENT VOLATILE BY VOL NE VAPOR DENSITY (air=1): Greater than 1 EVAPORATION RATE (Butyl Acetate=1): Greater than 1 SOLUBILITY IN WATER: Negligible APPEARANCE & ODOR: Black / Aromatic SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT (method used): 4.4°C (TCC) LOWER EXPLOSIVE LIMIT: 1.2 % UPPER EXPLOSIVE LIMIT: 7.1 % EXTINGUISHING MEDIA: Carbon dioxide, dry chemical, or foam. UNUSUAL FIRE & EXPLOSION HAZARDS: Extremely flammable, particularly under conditions of excessive heat, sparks, and open flame. Heated cans may burst. SPECIAL FIRE FIGHTING PROCEDURES: Full protective equipment, including self-contained breathing apparatus, should be worn in a fire involving this material. Water from fogging nozzles may be used to cool closed containers to prevent pressure build-up if exposed to extreme temperatures. SECTION V HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: Eye contact, skin contact, inhalation, and ingestion. EFFECTS OF OVEREXPOSURE: • Eyes: May cause irritation. • Skin: May cause irritation. Chronic exposure may cause defatting and/or dermatitis. • Inhalation: Inhalation of solvents may cause irritation. Propellant is a simple • Ingestion: May cause headache, nausea, vomiting, and weakness. EMERGENCY & FIRST AID PROCEDURES: • Eyes: Flush with plenty of water for at least 15 minutes and get medical attention. • Skin: Wash thoroughly with soap and water. • Inhalation: Remove to fresh air. • Ingestion: Do not induce vomiting. Get immediate medical attention. SECTION VI REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (materials to avoid): Strongly oxidizing agents. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. HAZARDOUS DECOMPOSITION PRODUCTS: In fire, will decompose to hydrocarbon fumes and smoke and carbon monoxide where combustion is incomplete. SECTION VII SPILL OR LEAK PROCEDURES IF RELEASED OR SPILLED: Remove all sources of ignition. Use inert absorbent material and non-sparking tools. Avoid breathing fumes. Ventilate area. Prevent from entering watercourses. WASTE DISPOSAL METHOD: Do not puncture or incinerate even when empty. Dispose of in accordance with federal, state, and local regulations. SECTION VIII SPECIAL PROTECTION INFORMATION VENTILATION: LOCAL MECHANICAL (if used indoors on a continuous basis) OTHER RESPIRATORY PROTECTION: If used indoors on a continuous basis, use of a cartridge type respirator (NIOSH / MSHATC 23C or equivalent) is recommended. EYE PROTECTION: Safety goggles. PROTECTIVE GLOVES: Chemical resistant gloves. OTHER PROTECTIVE EQUIPMENT: Long sleeves and long pants. SECTION IX SPECIAL PRECAUTIONS HANDLING & STORING PRECAUTIONS: Store in a cool, well-ventilated area not to exceed 50°C. Keep away from heat, sparks, or open flame. PREPARED: 09/25/93 UPDATED: 1/10/11 PRODUCT C2402 Page 222 of 1235 Page 222 of 1235 Page 222 of 1235 Page 222 of 1235 ---PAGE BREAK--- Rubberized Undercoating Product Code: C2402 Page 1 of 3 SAFETY DATA SHEET SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle® Rubberized Undercoating™ PRODUCT TYPE: Undercoating PRODUCT CODE: C2402 MANUFACTURED FOR: Castle Products, Inc. 424 St. Paul Street Rochester, NY 14605 [PHONE REDACTED] • FAX [PHONE REDACTED] EMERGENCY [PHONE REDACTED] SECTION 2 HAZARD IDENTIFICATION EMERGENCY OVERVIEW: DANGER: Gases Under Pressure, Flammable, Irritant POTENTIAL HEALTH EFFECTS: Eyes: May cause irritation. Skin: May cause irritation. Inhalation: May cause irritation. Propellant is a simple Ingestion: May cause headache, nausea, vomiting, and weakness. Effects of chronic exposure: Solvents may cause defatting dermatitis. SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % Acetone 67-64-1 750 ppm NE NE 15-40% Propane 74-98-6 1000 ppm NE NE 10-30% Toluene 108-88-3 50 ppm NE NE 10-30% Calcium Carbonate 1317-65-3 15 mg/m3 NE NE 7-13% Isobutane 75-28-5 1000 ppm NE NE 5-10% Organic Clay 68911-87-5 NE NE NE 1-5% Carbon Black 1333-86-4 3.5mg/m3 NE NE .1-1% SECTION 4 FIRST AID MEASURES First Aid Procedures: Eye contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician if irritation persists. Skin contact: For skin contact flush with large amounts of water. Call a physician if irritation persists. Inhalation: Immediately remove from further exposure. Give supplemental oxygen, if breathing is difficult. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by mouth to an unconscious person. Note to physician: If the product is ingested, treat the affected person SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: -0.4°F (-18°C) LOWER EXPLOSIVE LIMIT: 2.6% UPPER EXPLOSIVE LIMIT: 12.8% EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate for surrounding fire. HAZARDOUS COMBUSTION PRODUCTS: Hydrocarbon fumes and smoke. Carbon monoxide where combustion is incomplete. UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area. Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Ventilate spaces before entering. Environmental precautions: Prevent further leakage or spillage if safe to do so. Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Eliminate ignition sources including sources of electrical, static or frictional sparks. Wear appropriate protective equipment and clothing during clean-up. Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal. Page 223 of 1235 Page 223 of 1235 Page 223 of 1235 Page 223 of 1235 ---PAGE BREAK--- Rubberized Undercoating Product Code: C2402 Page 2 of 3 Large Spills: Dike far ahead of liquid spill for later disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. SECTION 7 HANDLING AND STORAGE Handling: Keep away from heat, sparks, and open flames. Avoid breathing mist. Avoid contact with skin and eyes. Wear suitable protective clothing. Wash hands after handling. Storage: Keep from freezing. Keep containers closed. Store in a cool, dry place. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established. Engineering controls: Use local exhaust ventilation. Personal protective equipment: Gloves: Wear impervious gloves. Eye/Face Protection: Wear safety glasses or goggles. Skin Protection: Wear clothing suited to the task being performed. Respiratory Protection: Not normally required if good ventilation is maintained. SECTION 9 PHYSICAL and CHEMICAL PROPERTIES BOILING POINT: ND SPECIFIC GRAVITY (H2O=1): 0.97-0.98 (liquid) VAPOR PRESSURE: 55-65 PERCENT VOLATILE BY VOL ND VAPOR DENSITY (air=1) >1 EVAPORATION RATE (Butyl Acetate=1): >1 SOLUBILITY IN WATER: Negligible APPEARANCE & ODOR: Black / Aromatic pH: NA SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (material to avoid): Strong oxidizing agents, HAZARDOUS DECOMPOSITION PRODUCTS: Hydrocarbon fumes and smoke. Carbon Monoxide where combustion is incomplete. HAZARDOUS POLYMERIZATION: Will not occur SECTION 11 TOXICOLOGICAL INFORMATION Components Test Results: Reproductive Effects: Prolonged and repeated exposure of pregnant animals to toluene (levels greater than approximately 1500 ppm), has been reported to cause adverse fetal developmental effects. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. SECTION 12 ECOLOGICAL INFORMATION Component Test Results: Not available. SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Do not puncture or incinerate containers, even when empty. Dispose according to all applicable Federal, State, and Local regulations. SECTION 14 TRANSPORT INFORMATION T.D.G. Classification: Consumer commodity (Aerosols, UN1950, Class 2.1) D.O.T. Classification: Consumer commodity, ORM-D SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations. CERCLA (Superfund) reportable quantity: None SARA (Superfund Amendments and Reauthorization Act of 1986): 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Page 224 of 1235 Page 224 of 1235 Page 224 of 1235 Page 224 of 1235 ---PAGE BREAK--- Rubberized Undercoating Product Code: C2402 Page 3 of 3 Section 302 extremely hazardous substance: No Section 311 hazardous chemical: No Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR. SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.) HMIS® ratings Health: 2 Flammability: 3 Physical hazard: 0 NFPA Code 30B: Level 2 Other: NA-Not Applicable, ND-Not Determined, NE-Not Established. Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. PREPARED: 9/25/93 UPDATED: 6/17/13 PRODUCT C2402 Page 225 of 1235 Page 225 of 1235 Page 225 of 1235 Page 225 of 1235 ---PAGE BREAK--- MANUFACTURER MATERIAL SAFETY DATA SHEET HAZARD RATING Castle Products, Inc. Hazard: 0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme Health 2 424 St. Paul Street Protection: A-Goggles, B-Goggles & gloves, Fire 2 Rochester, NY 14605 C-Goggles, gloves, & protective wear. Reactivity 0 1-[PHONE REDACTED] Other: NA-Not Applicable, ND-Not Determined, Protection B EMERGENCY (585) 275-3232 NE-Not Established. SECTION I DESCRIPTION TRADE NAME: Castle® Streak Proof™ PRODUCT TYPE: Glass Cleaner SECTION II HAZARDOUS INGREDIENTS INGREDIENT CAS # PEL TLV STEL % Isopropanol 67-63-0 NE 500 ppm NE 1-5 % Ethyleneglycol monobutyl ether 111-76-2 NE 25 ppm (skin) NE 1-5 % Isobutane 75-28-5 NE 1000 ppm NE 1-5 % Propane 74-98-6 NE 1000 ppm NE 0.5-1.5% SECTION III PHYSICAL DATA BOILING RANGE: 180°F SPECIFIC GRAVITY: NE VAPOR PRESSURE: NE PERCENT VOLATILE BY VOL NE VAPOR DENSITY: NE EVAPORATION RATE: NE SOLUBILITY IN WATER: Easily soluble APPEARANCE & ODOR: Clear / Bouquet SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT (method used): ND LOWER EXPLOSIVE LIMIT: ND UPPER EXPLOSIVE LIMIT: ND EXTINGUISHING MEDIA: Alcohol foam, CO2, dry chemical foam, or water fog. UNUSUAL FIRE & EXPLOSION HAZARDS: Mechanical impact and static discharge raise the risk of explosion. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus (MSHA / NIOSH approved or equivalent) and full protective gear. Keep containers cool with water spray to prevent pressure build-up or explosion. Use equipment or shielding to protect against bursting or venting containers. SECTION V HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: Eye contact, skin contact, inhalation, and ingestion. EFFECTS OF OVEREXPOSURE: • Eyes: May cause irritation, redness, and tearing. • Skin: May cause skin irritation. • Inhalation: May cause dizziness, weakness, fatigue, nausea, and headaches. • Ingestion: May cause gastrointestinal irritation, nausea, vomiting, and diarrhea. EMERGENCY & FIRST AID PROCEDURES: • Eyes: Flush eyes with plenty of water for at least 15 minutes, lifting upper and lower lids, occasionally. If irritation persists, consult physician. • Skin: Wash thoroughly with soap and water. If irritation persists, consult physician. • Inhalation: Remove to fresh air. If affected person has difficulty breathing, give oxygen. If not breathing, give artificial respiration. Get immediate medical attention. • Ingestion: Do NOT induce vomiting. Rinse mouth with water. Have conscious person drink 1 to 2 glasses of water. Do not give anything by mouth if affected person is unconscious. Get medical attention. SECTION VI REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (material to avoid): Strong acids, strong alkalis, and strong oxidizers. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon oxides (CO and CO2) and other irritating gases. SECTION VII SPILL OR LEAK PROCEDURES IF RELEASED OR SPILLED: Absorb with an inert dry material and place in an appropriate waste disposal container. WASTE DISPOSAL METHOD: Recycle to process, if possible. Consult your local or regional authorities. When container is empty, press button to release all pressure, then dispose of in garbage can. Dispose in accordance with federal, state, and local regulations. SECTION VIII SPECIAL PROTECTION INFORMATION VENTILATION: LOCAL MECHANICAL OTHER RESPIRATORY PROTECTION: If airborne concentrations are expected to exceed exposure limits (listed above), a NIOSH / MSHA approved air-purifying respirator may be permissible. If potential for uncontrolled release, exposure levels are unknown, or if air-purifying respirators may not provide adequate protection, use self-contained, positive pressure air-supplied respirator. EYE PROTECTION: Safety glasses with side shields (or safety goggles) and a face shield. PROTECTIVE GLOVES: Where contact is likely, wear chemical resistant gloves. OTHER PROTECTIVE EQUIPMENT: Where contact is likely, wear chemical suit and rubber boots. Follow standard industrial clothing standards. SECTION IX SPECIAL PRECAUTIONS HANDLING & STORING PRECAUTIONS: Wash thoroughly after handling. Keep away from heat, sparks, or open flame. Store in a cool, dry place. Do not puncture, incinerate, or store the container at temperatures over 50°C or in direct sunlight. PREPARED: 09/09/94 UPDATED: 1/7/11 PRODUCT C0603, C2003 Page 226 of 1235 Page 226 of 1235 Page 226 of 1235 Page 226 of 1235 ---PAGE BREAK--- Streak Proof Product Code: C0603, C2003 Page 1 of 3 SAFETY DATA SHEET SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle® Streak Proof™ PRODUCT TYPE: Glass Cleaner PRODUCT CODE: C0603, C2003 MANUFACTURED FOR: Castle Products, Inc. 424 St. Paul Street Rochester, NY 14605 [PHONE REDACTED] • FAX [PHONE REDACTED] EMERGENCY [PHONE REDACTED] SECTION 2 HAZARD IDENTIFICATION EMERGENCY OVERVIEW: WARNING: Gases Under Pressure, Irritant POTENTIAL HEALTH EFFECTS: Eyes: Ethylene glycol monobutyl ether causes moderate irritation and possible corneal injury Skin: Ethylene glycol monobutyl ether penetrates skin readily. Frequent or widespread contact may result in the absorption of potentially harmful amounts. Signs and of toxicity are similar to those of swallowing. Solvents may cause defatting dermatitis. Inhalation: Isopropanol vapors could produce irritation of nose and throat. Propellant is a simple Ingestion: May cause headache, nausea, vomiting, and weakness. Ethylene glycol monobutyl ether may cause red blood cell hemolysis and possible liver and kidney damage. SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % Water 7732-18-5 NE NE NE 75-100% Ethylene Glycol Monobutyl Ether 111-76-2 25 ppm NE NE 1-5% Isobutane 75-28-5 1000 ppm NE NE 1-5% Isopropanol 67-63-0 400 ppm NE NE 1-5% Propane 74-98-6 1000 ppm NE NE 0.5-1.5% SECTION 4 FIRST AID MEASURES First Aid Procedures: Eye contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician if irritation persists. Skin contact: For skin contact flush with large amounts of water. Call a physician if irritation persists. Inhalation: Immediately remove from further exposure. Give supplemental oxygen, if breathing is difficult. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by mouth to an unconscious person. Note to physician: If the product is ingested, treat the affected person SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: [Propellants: ≥-155°F (≥-104°C)] LOWER EXPLOSIVE LIMIT: 1.1% UPPER EXPLOSIVE LIMIT: 12% EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate for surrounding fire. UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area. Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Ventilate spaces before entering. Environmental precautions: Prevent further leakage or spillage if safe to do so. Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Eliminate ignition sources including sources of electrical, static or frictional sparks. Wear appropriate protective equipment and clothing during clean-up. Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal. Page 227 of 1235 Page 227 of 1235 Page 227 of 1235 Page 227 of 1235 ---PAGE BREAK--- Streak Proof Product Code: C0603, C2003 Page 2 of 3 Large Spills: Dike far ahead of liquid spill for later disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. SECTION 7 HANDLING AND STORAGE Handling: Keep away from heat, sparks, and open flames. Avoid breathing mist. Avoid contact with skin and eyes. Wear suitable protective clothing. Wash hands after handling. Storage: Keep from freezing. Keep containers closed. Store in a cool, dry place. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established. Personal protective equipment: Gloves: Not normally required. Eye/Face Protection: Not normally required. Skin Protection: Wear clothing suited to the task being performed. Respiratory Protection: Not normally required if good ventilation is maintained. SECTION 9 PHYSICAL and CHEMICAL PROPERTIES BOILING POINT: ND SPECIFIC GRAVITY (H2O=1): 1 VAPOR PRESSURE: NE PERCENT VOLATILE BY VOL 99-100% VAPOR DENSITY (air=1) >1 EVAPORATION RATE (Butyl Acetate=1): <1 SOLUBILITY IN WATER: Complete APPEARANCE & ODOR: Clear liquid / fragrant pH: 10.5 SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (material to avoid): Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide, Carbon Dioxide, Hydrocarbon fumes and smoke. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Components Test Results: No information available. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. SECTION 12 ECOLOGICAL INFORMATION Component Test Results: No information available. SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Do not puncture or incinerate containers, even when empty. Dispose according to all applicable Federal, State, and Local regulations. SECTION 14 TRANSPORT INFORMATION T.D.G. Classification: Consumer commodity (Aerosols, UN1950, Class 2.2) D.O.T. Classification: Consumer commodity, ORM-D. SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations. CERCLA (Superfund) reportable quantity: None SARA (Superfund Amendments and Reauthorization Act of 1986): 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Section 302 extremely hazardous substance: No Section 311 hazardous chemical: No Page 228 of 1235 Page 228 of 1235 Page 228 of 1235 Page 228 of 1235 ---PAGE BREAK--- Streak Proof Product Code: C0603, C2003 Page 3 of 3 Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR. SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.) HMIS® ratings Health: 2 Flammability: 1 Physical hazard: 0 NFPA Code 30B: Level 1. Other: NA-Not Applicable, ND-Not Determined, NE-Not Established. Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. PREPARED: 9/9/94 UPDATED: 9/20/2013 PRODUCT C0603, C2003 Page 229 of 1235 Page 229 of 1235 Page 229 of 1235 Page 229 of 1235 ---PAGE BREAK--- Streak Proof Product Code: C0603, C2003 Page 1 of 3 SAFETY DATA SHEET SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle® Streak Proof™ PRODUCT TYPE: Glass Cleaner PRODUCT CODE: C0603, C2003 MANUFACTURED FOR: Castle Products, Inc. 424 St. Paul Street Rochester, NY 14605 [PHONE REDACTED] • FAX [PHONE REDACTED] EMERGENCY [PHONE REDACTED] SECTION 2 HAZARD IDENTIFICATION EMERGENCY OVERVIEW: WARNING: Gases Under Pressure, Irritant POTENTIAL HEALTH EFFECTS: Eyes: Ethylene glycol monobutyl ether causes moderate irritation and possible corneal injury Skin: Ethylene glycol monobutyl ether penetrates skin readily. Frequent or widespread contact may result in the absorption of potentially harmful amounts. Signs and of toxicity are similar to those of swallowing. Solvents may cause defatting dermatitis. Inhalation: Isopropanol vapors could produce irritation of nose and throat. Propellant is a simple Ingestion: May cause headache, nausea, vomiting, and weakness. Ethylene glycol monobutyl ether may cause red blood cell hemolysis and possible liver and kidney damage. SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % Water 7732-18-5 NE NE NE 75-100% Ethylene Glycol Monobutyl Ether 111-76-2 25 ppm NE NE 1-5% Isobutane 75-28-5 1000 ppm NE NE 1-5% Isopropanol 67-63-0 400 ppm NE NE 1-5% Propane 74-98-6 1000 ppm NE NE 0.5-1.5% SECTION 4 FIRST AID MEASURES First Aid Procedures: Eye contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician if irritation persists. Skin contact: For skin contact flush with large amounts of water. Call a physician if irritation persists. Inhalation: Immediately remove from further exposure. Give supplemental oxygen, if breathing is difficult. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by mouth to an unconscious person. Note to physician: If the product is ingested, treat the affected person SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: [Propellants: ≥-155°F (≥-104°C)] LOWER EXPLOSIVE LIMIT: 1.1% UPPER EXPLOSIVE LIMIT: 12% EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate for surrounding fire. UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area. Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Ventilate spaces before entering. Environmental precautions: Prevent further leakage or spillage if safe to do so. Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Eliminate ignition sources including sources of electrical, static or frictional sparks. Wear appropriate protective equipment and clothing during clean-up. Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal. Page 230 of 1235 Page 230 of 1235 Page 230 of 1235 Page 230 of 1235 ---PAGE BREAK--- Streak Proof Product Code: C0603, C2003 Page 2 of 3 Large Spills: Dike far ahead of liquid spill for later disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. SECTION 7 HANDLING AND STORAGE Handling: Keep away from heat, sparks, and open flames. Avoid breathing mist. Avoid contact with skin and eyes. Wear suitable protective clothing. Wash hands after handling. Storage: Keep from freezing. Keep containers closed. Store in a cool, dry place. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established. Personal protective equipment: Gloves: Not normally required. Eye/Face Protection: Eye protection not normally required but recommended. Skin Protection: Wear clothing suited to the task being performed. Respiratory Protection: Not normally required if good ventilation is maintained. SECTION 9 PHYSICAL and CHEMICAL PROPERTIES BOILING POINT: ND SPECIFIC GRAVITY (H2O=1): 1 VAPOR PRESSURE: NE PERCENT VOLATILE BY VOL 99-100% VAPOR DENSITY (air=1) >1 EVAPORATION RATE (Butyl Acetate=1): <1 SOLUBILITY IN WATER: Complete APPEARANCE & ODOR: Clear liquid / fragrant pH: 10.5 SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (material to avoid): Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide, Carbon Dioxide, Hydrocarbon fumes and smoke. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Components Test Results: No information available. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. SECTION 12 ECOLOGICAL INFORMATION Component Test Results: No information available. SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Do not puncture or incinerate containers, even when empty. Dispose according to all applicable Federal, State, and Local regulations. SECTION 14 TRANSPORT INFORMATION T.D.G. Classification: Consumer commodity (Aerosols, UN1950, Class 2.2) D.O.T. Classification: Consumer commodity, ORM-D. SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations. CERCLA (Superfund) reportable quantity: None SARA (Superfund Amendments and Reauthorization Act of 1986): 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Section 302 extremely hazardous substance: No Section 311 hazardous chemical: No Page 231 of 1235 Page 231 of 1235 Page 231 of 1235 Page 231 of 1235 ---PAGE BREAK--- Streak Proof Product Code: C0603, C2003 Page 3 of 3 Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR. SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.) HMIS® ratings Health: 2 Flammability: 1 Physical hazard: 0 NFPA Code 30B: Level 1. Other: NA-Not Applicable, ND-Not Determined, NE-Not Established. Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. PREPARED: 9/9/94 UPDATED: 6/14/13 PRODUCT C0603, C2003 Page 232 of 1235 Page 232 of 1235 Page 232 of 1235 Page 232 of 1235 ---PAGE BREAK--- MANUFACTURER MATERIAL SAFETY DATA SHEET HAZARD RATING Castle Products, Inc. Hazard: 0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme. Health 1 424 St. Paul Street Protection: A-Goggles, B-Goggles & gloves, Fire 4 Rochester, NY 14605 C-Goggles, gloves, & protective wear. Reactivity 0 1-[PHONE REDACTED] Other: NA-Not Applicable, ND-Not Determined, Protection B EMERGENCY (585) 275-3232 NE-Not Established. SECTION I DESCRIPTION TRADE NAME: Castle® Thrust™ PRODUCT TYPE: Heavy Duty Penetrating Oil SECTION II HAZARDOUS INGREDIENTS INGREDIENT CAS # PEL TLV STEL % Heavy Naphthenic Distillate 64742-52-5 5 mg/m3 5 mg/m3 NE 60.0 % Kerosene 8008-20-6 400 ppm 400 ppm NE 20.0 % Propane / Isobutane / n-Butane 68476-86-8 800 ppm 800 ppm NE 20.0 % Ethyl Acetic Ester 141-78-6 400 ppm 400 ppm NE 5.0 % -Kerosene contains 0.5-1.5% xylene(1330-20-7), 0.5-1.5% naphthalene(91-20-3), and 0.4-1.2% biphenyl(92-52-4) which are subject to the reporting requirements of Section 313 of SARA Title III. SECTION III PHYSICAL DATA BOILING POINT: -43°F – 522°F SPECIFIC GRAVITY (H2O=1): 0.7962 VAPOR PRESSURE: 80-90 PERCENT VOLATILE BY VOL NE VAPOR DENSITY (AIR=1): Heavier than air EVAPORATION RATE: Faster than Butyl Acetate SOLUBILITY IN WATER: Negligible APPEARANCE & ODOR: Green-Black / Solvent SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT (method used): -156°F (TCC) LOWER EXPLOSIVE LIMIT: 1.0 % UPPER EXPLOSIVE LIMIT: 11.0 % EXTINGUISHING MEDIA: Use water fog, dry chemical or carbon dioxide. UNUSUAL FIRE & EXPLOSION HAZARDS: Avoid all sources of ignition, welding arcs, and open flames. Vapors can travel to source of ignition and flash back. “Empty” cans may retain product residue and can be hazardous. Do not pressurize, cut, weld, braze, solder, drill, or grind cans. Do not expose cans to heat, flame, sparks, static electricity, or other sources of ignition. Heated cans may build up pressure and explode; can cause injury or death. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus (MSHA / NIOSH approved or equivalent) and full protective gear. SECTION V HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: Eye contact, skin contact, inhalation, and ingestion. EFFECTS OF OVEREXPOSURE: Long-term exposure may cause damage to lungs, kidneys, and/or nervous system. • Eyes: may cause irritation, pain, tearing, reddening, swelling, and stinging. • Skin: defatting, drying, irritation, and rash. • Inhalation: difficulty in breathing, headaches, dizziness, nausea, decreased blood pressure, changes in heart rate, and cyanosis. • Ingestion: harmful or fatal. Corrosive: may cause severe, permanent damage to mouth, throat, and stomach. EMERGENCY & FIRST AID PROCEDURES: • Eyes and skin: Flush immediately with plenty of water. Get immediate medical attention. Remove affected clothing and wash separately before reusing. • Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. • Ingestion: Do NOT induce vomiting. Give glass of water or milk. Call physician or poison control immediately. Never give food or drink to an unconscious person. SECTION VI REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (materials to avoid): Strong acids, alkalis, oxidizers, and amines. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon, oxides of nitrogen; may produce forms of chloride, chlorine, and phosgene. SECTION VII SPILL OR LEAK PROCEDURES IF RELEASED OR SPILLED: Absorb spill with inert material (such as dry sand or earth). Dispose in chemical waste container. WASTE DISPOSAL METHOD: Dispose as hazardous waste in accordance with federal, state, and local regulations. SECTION VIII SPECIAL PROTECTION INFORMATION VENTILATION: LOCAL MECHANICAL OTHER RESPIRATORY PROTECTION: If airborne concentrations are expected to exceed exposure limits (listed above), a NIOSH / MSHA approved air-purifying respirator may be permissible. If potential for uncontrolled release, exposure levels are unknown, or if air-purifying respirators may not provide adequate protection, use self-contained, positive pressure air-supplied respirator. EYE PROTECTION: Safety glasses with side shields (or safety goggles) and a face shield. PROTECTIVE GLOVES: Where contact is likely, wear chemical resistant gloves. OTHER PROTECTIVE EQUIPMENT: Where contact is likely, wear chemical suit and rubber boots. Follow standard industrial clothing standards. SECTION IX SPECIAL PRECAUTIONS HANDLING & STORING PRECAUTIONS: Wash thoroughly after handling. Keep away from heat, sparks, or open flame. Store at temperatures below 120°F. Keep from freezing. PREPARED: 09/25/96 UPDATED: 1/6/11 PRODUCT C0805 Page 233 of 1235 Page 233 of 1235 Page 233 of 1235 Page 233 of 1235 ---PAGE BREAK--- Thrust Product Code: C2005 Page 1 of 3 SAFETY DATA SHEET SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle® Thrust™ PRODUCT TYPE: Penetrating Oil PRODUCT CODE: C2005 MANUFACTURED FOR: Castle Products, Inc. 424 St. Paul Street Rochester, NY 14605 [PHONE REDACTED] • FAX [PHONE REDACTED] EMERGENCY [PHONE REDACTED] SECTION 2 HAZARD IDENTIFICATION EMERGENCY OVERVIEW: DANGER: Gases Under Pressure, Flammable, Irritant POTENTIAL HEALTH EFFECTS: Eyes: May cause irritation. Skin: May cause irritation. Prolonged exposure may cause fatting dermatitis. Inhalation: May cause irritation. Propellant is a simple Ingestion: May cause headache, nausea, vomiting, and weakness. Effects of chronic exposure: Lifetime skin painting tests indicate that materials of similar composition as kerosene may have produced skin cancer in experimental animals. The relationship of these results to humans has not been fully established. SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % Petroleum Oil Blend (Mixture) 64742-52-5 5 mg/m3 NE NE 30-60% Kerosene (Petroleum) 8008-20-6 5 ppm NE NE 10-30% Propane 74-98-6 1000 ppm NE NE 7-15% Isobutane 75-28-5 1000 ppm NE NE 5-10% Ethyl acetate 141-78-6 400 ppm NE NE 1-5% SECTION 4 FIRST AID MEASURES First Aid Procedures: Eye contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician if irritation persists. Skin contact: For skin contact flush with large amounts of water. Call a physician if irritation persists. Inhalation: Immediately remove from further exposure. Give supplemental oxygen, if breathing is difficult. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by mouth to an unconscious person. Note to physician: If the product is ingested, treat the affected person SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: 25°F LOWER EXPLOSIVE LIMIT: 2.0% UPPER EXPLOSIVE LIMIT: 10.7% [Propellant: ≥-141°F EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate for surrounding fire. UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: Water from fogging nozzles may be used to cool closed containers to prevent pressure build-up if exposed to extreme temperatures. As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area. Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Ventilate spaces before entering. Environmental precautions: Prevent further leakage or spillage if safe to do so. Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Eliminate ignition sources including sources of electrical, static or frictional sparks. Wear appropriate protective equipment and clothing during clean-up. Page 234 of 1235 Page 234 of 1235 Page 234 of 1235 Page 234 of 1235 ---PAGE BREAK--- Thrust Product Code: C2005 Page 2 of 3 Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal. Large Spills: Dike far ahead of liquid spill for disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. SECTION 7 HANDLING AND STORAGE Handling: Avoid breathing mist. Avoid contact with skin and eyes. Wear suitable protective clothing. Wash hands after handling. Storage: Keep from freezing. Keep containers closed. Store in a cool, dry place. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established. Engineering controls: Use local exhaust ventilation. Personal protective equipment: General: Eye wash fountain and emergency showers are recommended. Eye/face Protection: Wear safety glasses or goggles. Skin Protection: Wear suitable protective clothing. Wear chemical resistant gloves. Respiratory Protection: When respiratory protection is required, wear a NIOSH/MSHA approved self-contained breathing apparatus with full facepiece operated in a positive-pressure mode. SECTION 9 PHYSICAL and CHEMICAL PROPERTIES BOILING POINT: 168°F (76°C) SPECIFIC GRAVITY (H2O=1): 0.88-0.89 (liquid) 0.75-0.79 (aerosol) VAPOR PRESSURE: 55-65 PERCENT VOLATILE BY VOL >95% VAPOR DENSITY (air=1) >1 EVAPORATION RATE (Butyl Acetate=1): <1 SOLUBILITY IN WATER: Negligible APPEARANCE & ODOR: Dark amber liquid / characteristic pH: NA SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (material to avoid): Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide, Carbon Dioxide, Hydrocarbon fumes and smoke where combustion is incomplete. HAZARDOUS POLYMERIZATION: Will not occur SECTION 11 TOXICOLOGICAL INFORMATION Components Test Results: No information available. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. SECTION 12 ECOLOGICAL INFORMATION Component Test Results: No information available. SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Do not puncture or incinerate containers, even when empty. Dispose according to all applicable Federal, State, and Local regulations. SECTION 14 TRANSPORT INFORMATION D.O.T. Classification: Consumer Commodity, ORM-D T.D.G. Classification: Consumer Commodity (Aerosols, UN1950, Class 2.1) SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations. CERCLA (Superfund) reportable quantity: None SARA (Superfund Amendments and Reauthorization Act of 1986): 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Page 235 of 1235 Page 235 of 1235 Page 235 of 1235 Page 235 of 1235 ---PAGE BREAK--- Thrust Product Code: C2005 Page 3 of 3 Section 302 extremely hazardous substance: No Section 311 hazardous chemical: No Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR. SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.) HMIS® ratings Health: 2 Flammability: 4 Physical hazard: 0 NFPA Code 30B: Level 3 Other: NA-Not Applicable, ND-Not Determined, NE-Not Established. Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. PREPARED: 9/25/96 UPDATED: 6/14/13 PRODUCT C2005 Page 236 of 1235 Page 236 of 1235 Page 236 of 1235 Page 236 of 1235 ---PAGE BREAK--- Thrust Product Code: C0805 Page 1 of 3 SAFETY DATA SHEET SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle® Thrust™ PRODUCT TYPE: Penetrating Oil PRODUCT CODE: C0805 MANUFACTURED FOR: Castle Products, Inc. 424 St. Paul Street Rochester, NY 14605 [PHONE REDACTED] • FAX [PHONE REDACTED] EMERGENCY [PHONE REDACTED] SECTION 2 HAZARD IDENTIFICATION EMERGENCY OVERVIEW: DANGER: Gases Under Pressure, Flammable, Irritant POTENTIAL HEALTH EFFECTS: Eyes: Irritating to eyes. Skin: Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis. Inhalation: Irritating to respiratory system. Avoid breathing vapors or mists. of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. Ingestion: Not an expected route of exposure. Potential for aspiration if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting, and diarrhea. SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % Petroleum Oil 64742-52-5 NE NE NE 40-70% Kerosene 8008-20-6 NE 200mg/m3 NE 10-30% Propane/Isobutane/N-Butane 68476-86-8 NE NE NE 10-30% Ethyl Acetic Ester 141-78-6 400ppm 400ppm NE 1-5% SECTION 4 FIRST AID MEASURES First Aid Procedures: Eye contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician if irritation persists. Skin contact: For skin contact flush with large amounts of water. Call a physician if irritation persists. Inhalation: Immediately remove from further exposure. Give supplemental oxygen, if breathing is difficult. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by mouth to an unconscious person. Note to physician: If the product is ingested, treat the affected person SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: -143°F (-97°C) LOWER EXPLOSIVE LIMIT: ND UPPER EXPLOSIVE LIMIT: ND EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate for surrounding fire. UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area. Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Ventilate spaces before entering. Environmental precautions: Prevent further leakage or spillage if safe to do so. Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Eliminate ignition sources including sources of electrical, static or frictional sparks. Wear appropriate protective equipment and clothing during clean-up. Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal. Page 237 of 1235 Page 237 of 1235 Page 237 of 1235 Page 237 of 1235 ---PAGE BREAK--- Thrust Product Code: C0805 Page 2 of 3 Large Spills: Dike far ahead of liquid spill for later disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. SECTION 7 HANDLING AND STORAGE Handling: Aerosol is extremely flammable. Store away from heat, sparks, and flames. Avoid breathing mist. Avoid contact with skin and eyes. Wear suitable protective clothing. Wash hands after handling. Storage: Keep from freezing. Keep containers closed. Store in a cool, dry place. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established. Engineering controls: Use local exhaust ventilation. Personal protective equipment: Gloves: Not normally required. Eye/Face Protection: Wear Safety Glasses or Goggles. Skin Protection: Wear clothing suited to the task being performed. Respiratory Protection: Not normally required if good ventilation is maintained. SECTION 9 PHYSICAL and CHEMICAL PROPERTIES BOILING POINT: ND SPECIFIC GRAVITY (H2O=1): ND VAPOR PRESSURE: ND PERCENT VOLATILE BY VOL 40% VAPOR DENSITY (air=1) >1 EVAPORATION RATE (Butyl Acetate=1): ND SOLUBILITY IN WATER: ND APPEARANCE & ODOR: Dark Green Liquid / Solvent pH: NA SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable under recommended storage conditions. INCOMPATIBILITY (material to avoid): Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide, Carbon Dioxide, Hydrocarbon fumes and smoke. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Component Test Results: None reported. Carcinogenicity: ACGIH A3 (animal carcinogen) for Kerosene. Target organ effects: Central nervous system, eyes, respiratory system, skin. SECTION 12 ECOLOGICAL INFORMATION Component Test Results: None reported. SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Dispose according to all applicable Federal, State, and Local regulations. SECTION 14 TRANSPORT INFORMATION DOT ground: Consumer Commodity ORM-D, or Limited Quantity. IATA: UN1950, Aerosols, Flammable, 2.1 LTD QTY. IMDG: UN1950, Aerosols, 2.1, LTD QTY. SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations. CERCLA (Superfund) reportable quantity: None SARA (Superfund Amendments and Reauthorization Act of 1986): 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Section 302 extremely hazardous substance: No Section 311 hazardous chemical: No Page 238 of 1235 Page 238 of 1235 Page 238 of 1235 Page 238 of 1235 ---PAGE BREAK--- Thrust Product Code: C0805 Page 3 of 3 Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR. SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.) HMIS® ratings Health: 2 Flammability: 4 Physical hazard: 2 NFPA ratings Health: 2 Flammability: 4 Instability: 0 Other: NA-Not Applicable, ND-Not Determined, NE-Not Established. Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. PREPARED: 9/25/96 UPDATED: 6/13/13 PRODUCT C0805 Page 239 of 1235 Page 239 of 1235 Page 239 of 1235 Page 239 of 1235 ---PAGE BREAK--- MANUFACTURER MATERIAL SAFETY DATA SHEET HAZARD RATING Castle Products, Inc. Hazard: 0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme. Health 1 424 St. Paul Street Protection: A-Goggles, B-Goggles & gloves, Fire 4 Rochester, NY 14605 C-Goggles, gloves, & protective wear. Reactivity 0 1-[PHONE REDACTED] Other: NA-Not Applicable, ND-Not Determined, Protection B EMERGENCY (585) 275-3232 NE-Not Established. SECTION I DESCRIPTION TRADE NAME: Castle® White Lithium Grease™ PRODUCT TYPE: Heavy Duty Grease SECTION II HAZARDOUS INGREDIENTS INGREDIENT CAS # PEL TLV STEL % N-Heptane 142-82-5 400 ppm 400 ppm 500 ppm 30 % Propane/Isobutane/N-Butane 68476-86-8 800 ppm 1000 ppm NE 25 % 2-Propanone 67-64-1 750 ppm 750 ppm 1000 ppm 4 % Mineral Oil Hydrotreated 64742-52-5 NE NE NE 20 % Octadecanoic Acid, 12-hydroxy-, monolithium salt 7620-77-1 NE NE NE 5 % Hitec 350 (Ethyl Corporation) Proprietary NE NE NE 5 % SECTION III PHYSICAL DATA BOILING POINT: -43 – 209 °F SPECIFIC GRAVITY (H20=1) 0.8545 VAPOR PRESSURE: NE VOCS: 364 grams / liter VAPOR DENSITY(air=1): > 1 EVAPORATION RATE: < Butyl Acetate SOLUBILITY IN WATER: Negligible APPEARANCE & ODOR: Cream / Petroleum SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Pensky-Martens C.C): -156 °F LOWER EXPLOSIVE LIMIT: 1.2% UPPER EXPLOSIVE LIMIT: 12.8 % EXTINGUISHING MEDIA: Alcohol foam, CO2, dry chemical foam, or water fog. UNUSUAL FIRE & EXPLOSION HAZARDS: Avoid all sources of ignition, welding arcs, and open flames. Vapors can travel to source of ignition and flash back. “Empty” cans may retain product residue and can be hazardous. Do not pressurize, cut, weld, braze, solder, drill, or grind cans. Do not expose cans to heat, flame, sparks, static electricity, or other sources of ignition. Heated cans may build up pressure and explode; can cause injury or death. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus (MSHA / NIOSH approved or equivalent) and full protective gear. SECTION V HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: Eye contact, skin contact, inhalation, and ingestion. EFFECTS OF OVEREXPOSURE: Long-term exposure may cause damage to lungs, kidneys, and/or nervous system. • Eyes: may cause irritation, pain, tearing, reddening, swelling, and stinging. • Skin: defatting, drying, irritation, and rash. • Inhalation: difficulty in breathing, headaches, dizziness, nausea, decreased blood pressure, changes in heart rate, and cyanosis. • Ingestion: harmful or fatal. Corrosive: may cause severe, permanent damage to mouth, throat, and stomach. EMERGENCY & FIRST AID PROCEDURES: • Eyes and skin: Flush immediately with plenty of water. Get immediate medical attention. Remove affected clothing and wash separately before reusing. • Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. • Ingestion: Do NOT induce vomiting. Give glass of water or milk. Call physician or poison control immediately. Never give food or drink to an unconscious person. SECTION VI REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (materials to avoid): Strong acids, alkalis, oxidizers, and amines. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon, oxides of nitrogen; may produce forms of chloride, chlorine, and phosgene. SECTION VII SPILL OR LEAK PROCEDURES IF RELEASED OR SPILLED: Absorb spill with inert material (such as dry sand or earth). Dispose in chemical waste container. WASTE DISPOSAL METHOD: Dispose as hazardous waste in accordance with federal, state, and local regulations. SECTION VIII SPECIAL PROTECTION INFORMATION VENTILATION: LOCAL MECHANICAL OTHER RESPIRATORY PROTECTION: If airborne concentrations are expected to exceed exposure limits (listed above), a NIOSH / MSHA approved air-purifying respirator may be permissible. If potential for uncontrolled release, exposure levels are unknown, or if air-purifying respirators may not provide adequate protection, use self-contained, positive pressure air-supplied respirator. EYE PROTECTION: Safety glasses with side shields (or safety goggles) and a face shield. PROTECTIVE GLOVES: Where contact is likely, wear chemical resistant gloves. OTHER PROTECTIVE EQUIPMENT: Where contact is likely, wear chemical suit and rubber boots. Follow standard industrial clothing standards. SECTION IX SPECIAL PRECAUTIONS HANDLING & STORING PRECAUTIONS: Wash thoroughly after handling. Keep away from heat, sparks, or open flame. Store in temperatures below 120°F. Keep from freezing. SECTION X TRANSPORTATION IMDG HAZARD CLASS: 2.1 SHIP NAME: AEROSOLS, FLAMMABLE ORM-D IMDG SHIP: UN1950 IATA EXEMPTIONS: LIMITED QUANTITY PREPARED: 08/13/93 UPDATED: 1/7/11 PRODUCT C1602 Page 240 of 1235 Page 240 of 1235 Page 240 of 1235 Page 240 of 1235 ---PAGE BREAK--- MANUFACTURER MATERIAL SAFETY DATA SHEET HAZARD RATING Castle Products, Inc. Hazard: 0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme. Health 2 424 St. Paul Street Protection: A-Goggles, B-Goggles & gloves, Fire 0 Rochester, NY 14605 C-Goggles, gloves, & protective wear. Reactivity 0 1-[PHONE REDACTED] Other: NA-Not Applicable, ND-Not Determined, Protection B EMERGENCY (585) 275-3232 NE-Not Established. SECTION I DESCRIPTION TRADE NAME: Castle® Zapp™ PRODUCT TYPE: Special Electronic Cleaner SECTION II HAZARDOUS INGREDIENTS INGREDIENT CAS # PEL TLV STEL % n-Propyl Bromide 106-95-5 NE 100 ppm NE >90 % Ethyl Alcohol 64-17-5 NE 1000 ppm NE 1-5 % Carbon Dioxide 124-38-9 NE 5000 ppm NE 1-5 % SECTION III PHYSICAL DATA BOILING POINT: 90°180°F SPECIFIC GRAVITY (H2O=1): 1.35+-0.05 VAPOR PRESSURE: 95-105 PERCENT VOLATILE BY VOL NE VAPOR DENSITY: Heavier than air EVAPORATION RATE: Slower than Ether SOLUBILITY IN WATER: Negligible APPEARANCE & ODOR Clear / Solvent SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT (method used): Non-Flammable ASTM D3065-77 Flame Extension Test LOWER EXPLOSIVE LIMIT: 4 UPPER EXPLOSIVE LIMIT: 8 EXTINGUISHING MEDIA: Alcohol foam, CO2, or dry chemical. UNUSUAL FIRE & EXPLOSION HAZARDS: Avoid all sources of ignition, welding arcs, and open flames. Vapors can travel to source of ignition and flash back. “Empty” cans may retain product residue and can be hazardous. Do not pressurize, cut, weld, braze, solder, drill, or grind cans. Do not expose cans to heat, flame, sparks, static electricity, or other sources of ignition. Heated cans may build up pressure and explode; can cause injury or death. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus (MSHA / NIOSH approved or equivalent) and full protective gear. SECTION V HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: Eye contact, skin contact, inhalation, and ingestion. EFFECTS OF OVEREXPOSURE: Long-term exposure may cause damage to lungs, kidneys, and/or nervous system. • Eyes: may cause irritation, pain, tearing, reddening, swelling, and stinging. • Skin: defatting, drying, irritation, and rash. • Inhalation: difficulty in breathing, headaches, dizziness, nausea, decreased blood pressure, changes in heart rate, and cyanosis. • Ingestion: harmful or fatal. Corrosive: may cause severe, permanent damage to mouth, throat, and stomach. EMERGENCY & FIRST AID PROCEDURES: • Eyes and skin: Flush immediately with plenty of water. Get immediate medical attention. Remove affected clothing and wash separately before reusing. • Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. • Ingestion: Do NOT induce vomiting. Give glass of water or milk. Call physician or poison control immediately. Never give food or drink to an unconscious person. SECTION VI REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (materials to avoid): Strong acids, alkalis, oxidizers, and amines. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon, oxides of nitrogen; may produce forms of chloride, chlorine, and phosgene. SECTION VII SPILL OR LEAK PROCEDURES IF RELEASED OR SPILLED: Absorb spill with inert material (such as dry sand or earth). Dispose in chemical waste container. WASTE DISPOSAL METHOD: Dispose as hazardous waste in accordance with federal, state, and local regulations. SECTION VIII SPECIAL PROTECTION INFORMATION VENTILATION: LOCAL MECHANICAL OTHER RESPIRATORY PROTECTION: If airborne concentrations are expected to exceed exposure limits (listed above), a NIOSH / MSHA approved air-purifying respirator may be permissible. If potential for uncontrolled release, exposure levels are unknown, or if air-purifying respirators may not provide adequate protection, use self-contained, positive pressure air-supplied respirator. EYE PROTECTION: Safety glasses with side shields (or safety goggles) and a face shield. PROTECTIVE GLOVES: Where contact is likely, wear chemical resistant gloves. OTHER PROTECTIVE EQUIPMENT: Where contact is likely, wear chemical suit and rubber boots. Follow standard industrial clothing standards. SECTION IX SPECIAL PRECAUTIONS HANDLING & STORING PRECAUTIONS: Wash thoroughly after handling. Keep away from heat, sparks, or open flame. Store in temperatures below 120°F. Keep from freezing. DATE PREPARED: 1/10/94 UPDATED: 1/7/011 PRODUCT C1629 Page 241 of 1235 Page 241 of 1235 Page 241 of 1235 Page 241 of 1235 ---PAGE BREAK--- Zapp Product Code: C1629 Page 1 of 3 SAFETY DATA SHEET SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle® Zapp™ PRODUCT TYPE: Special Electronic Cleaner PRODUCT CODE: C1629 MANUFACTURED FOR: Castle Products, Inc. 418 St. Paul Street Rochester, NY 14605 [PHONE REDACTED] • FAX [PHONE REDACTED] EMERGENCY [PHONE REDACTED] SECTION 2 HAZARD IDENTIFICATION EMERGENCY OVERVIEW: WARNING: Gases Under Pressure, Flammable, Irritant Keep out of reach of children. POTENTIAL HEALTH EFFECTS: Eyes: May be irritating to eyes. Skin: Possible skin irritation. Inhalation: May cause mucous membrane irritation. Ingestion: Harmful if swallowed. May cause gastrointestinal discomfort. . SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % n-Propyl Bromide 106-94-5 10ppm NE NE 60-100% Ethanol 64-17-5 1000ppm NE NE 1-5% Carbon Dioxide 124-38-9 5000ppm NE NE 1-5% SECTION 4 FIRST AID MEASURES First Aid Procedures: Eye contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician if irritation persists. Skin contact: For skin contact flush with large amounts of water. Call a physician if irritation persists. Inhalation: Immediately remove from further exposure. Give supplemental oxygen, if breathing is difficult. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by mouth to an unconscious person. Note to physician: If the product is ingested, treat the affected person SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: 25°F ( -4°C) LOWER EXPLOSIVE LIMIT: 4% UPPER EXPLOSIVE LIMIT: 8% EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate for surrounding fire. UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area. Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Ventilate spaces before entering. Environmental precautions: Prevent further leakage or spillage if safe to do so. Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Eliminate ignition sources including sources of electrical, static or frictional sparks. Wear appropriate protective equipment and clothing during clean-up. Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal. Large Spills: Dike far ahead of liquid spill for later disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. Page 242 of 1235 Page 242 of 1235 Page 242 of 1235 Page 242 of 1235 ---PAGE BREAK--- Zapp Product Code: C1629 Page 2 of 3 SECTION 7 HANDLING AND STORAGE Handling: Avoid breathing mist. Avoid contact with skin and eyes. Wear suitable protective clothing. Wash hands after handling. Storage: Product is flammable. Keep away from heat and sources of ignition. Keep from freezing. Keep containers closed. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established. Engineering controls: Use local exhaust ventilation. Personal protective equipment: Gloves: Not normally required. Eye/Face Protection: Wear safety glasses or goggles. Skin Protection: Wear clothing suited to the task being performed. Respiratory Protection: Not normally required if good ventilation is maintained. SECTION 9 PHYSICAL and CHEMICAL PROPERTIES BOILING POINT: 156F (69C) SPECIFIC GRAVITY (H2O=1): 1.3 VAPOR PRESSURE: 60-70 PERCENT VOLATILE BY VOL 100% VAPOR DENSITY (air=1): >1 EVAPORATION RATE (Butyl Acetate=1): ND SOLUBILITY IN WATER: 2.4g/L APPEARANCE & ODOR: Clear Colorless Liquid / Solvent pH: NA SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (material to avoid): Strong acids or oxidizing agents, HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and low molecular weight hydrocarbons may be produced. HAZARDOUS POLYMERIZATION: Will not occur SECTION 11 TOXICOLOGICAL INFORMATION Components Test Results: No Data Available Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. SECTION 12 ECOLOGICAL INFORMATION Components Information: No Data Available SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Dispose according to all applicable Federal, State, and Local regulations. SECTION 14 TRANSPORT INFORMATION DOT: Consumer Commodity, ORM-D. TDG: Consumer Commodity (Aerosols, UN1950, Class 2.1) SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations. CERCLA (Superfund) reportable quantity: None SARA (Superfund Amendments and Reauthorization Act of 1986): 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Section 302 extremely hazardous substance: No Section 311 hazardous chemical: No Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR. Page 243 of 1235 Page 243 of 1235 Page 243 of 1235 Page 243 of 1235 ---PAGE BREAK--- Zapp Product Code: C1629 Page 3 of 3 SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.) HMIS® ratings Health: 2 Flammability: 2 Physical hazard: 0 NFPA ratings Health: 2 Flammability: 2 Instability: 0 Other: NA-Not Applicable, ND-Not Determined, NE-Not Established. Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. PREPARED: 5/14/99 UPDATED: 6/14/13 PRODUCT C1629 Page 244 of 1235 Page 244 of 1235 Page 244 of 1235 Page 244 of 1235 ---PAGE BREAK--- MANUFACTURER MATERIAL SAFETY DATA SHEET HAZARD RATING Castle Products, Inc. Hazard: 0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme. Health 2 424 St. Paul Street Protection: A-Goggles, B-Goggles & gloves, Fire 2 Rochester, NY 14605 C-Goggles, gloves, & protective wear. Reactivity 0 1-[PHONE REDACTED] Other: NA-Not Applicable, ND-Not Determined, Protection B EMERGENCY (585) 275-3232 NE-Not Established. SECTION I DESCRIPTION TRADE NAME: Castle® Zapp™ PRODUCT TYPE: Special Electronic Cleaner SECTION II HAZARDOUS INGREDIENTS INGREDIENT CAS # PEL TLV STEL % n-Propyl Bromide 106-94-5 NE 10 ppm NE 60-100% Ethanol 64-17-5 NE 200 ppm NE 1-5% Carbon Dioxide 124-38-9 NE 1000 ppm NE 1-5% SECTION III PHYSICAL DATA BOILING POINT: 69°C SPECIFIC GRAVITY (H2O=1): 1.3-1.4 VAPOR PRESSURE: 60-70 PERCENT VOLATILE BY VOL 100 VAPOR DENSITY: >1 EVAPORATION RATE: Not available SOLUBILITY IN WATER : 2.4g/L APPEARANCE & ODOR Colorless / Sweet SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT (method used): -4.5°C LOWER EXPLOSIVE LIMIT: 4 UPPER EXPLOSIVE LIMIT: 8 EXTINGUISHING MEDIA: Alcohol foam, CO2, or dry chemical. UNUSUAL FIRE & EXPLOSION HAZARDS: Avoid all sources of ignition, welding arcs, and open flames. Vapors can travel to source of ignition and flash back. “Empty” cans may retain product residue and can be hazardous. Do not pressurize, cut, weld, braze, solder, drill, or grind cans. Do not expose cans to heat, flame, sparks, static electricity, or other sources of ignition. Heated cans may build up pressure and explode; can cause injury or death. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus (MSHA / NIOSH approved or equivalent) and full protective gear. SECTION V HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: Eye contact, skin contact, and inhalation. Product is a gas. Therefore, ingestion is not a likely route of exposure. EFFECTS OF OVEREXPOSURE: Dizziness, nausea. Irritation to skin and eyes. • Eyes: may cause irritation. • Skin: May cause irritation or frostbite. • Inhalation: difficulty in breathing, headaches, dizziness, nausea, decreased blood pressure, changes in heart rate, and cyanosis. • Inhalation: Propellant is a simple EMERGENCY & FIRST AID PROCEDURES: • Eyes and skin: Flush immediately with plenty of water. Get immediate medical attention. • Inhalation: Move person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Never give food or drink to an unconscious person. SECTION VI REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (materials to avoid): Strong oxidizing agents. HAZARDOUS POLYMERIZATION: Will not occur. HAZARDOUS DECOMPOSITION PRODUCTS: Hydrocarbon fumes and smoke, carbon monoxide where combustion is incomplete. SECTION VII SPILL OR LEAK PROCEDURES IF RELEASED OR SPILLED: Remove all sources of ignition. Absorb spill with inert material (such as dry sand or earth). Ventilate area. Prevent from entering a watercourse. WASTE DISPOSAL METHOD: Dispose as hazardous waste in accordance with federal, state, and local regulations. SECTION VIII SPECIAL PROTECTION INFORMATION VENTILATION: LOCAL MECHANICAL OTHER RESPIRATORY PROTECTION: If airborne concentrations are expected to exceed exposure limits (listed above), a NIOSH / MSHA approved air-purifying respirator may be permissible. If potential for uncontrolled release, exposure levels are unknown, or if air-purifying respirators may not provide adequate protection, use self-contained, positive pressure air-supplied respirator. EYE PROTECTION: Safety glasses with side shields (or safety goggles) and a face shield. PROTECTIVE GLOVES: Where contact is likely, wear chemical resistant gloves. OTHER PROTECTIVE EQUIPMENT: Not required. SECTION IX SPECIAL PRECAUTIONS HANDLING & STORING PRECAUTIONS: Keep away from heat, sparks, or open flames. Store a cool, ventilated area not to exceed 50°C. DATE PREPARED: 2/15/12 UPDATED: 2/15/12 PRODUCT C1629 Page 245 of 1235 Page 245 of 1235 Page 245 of 1235 Page 245 of 1235 ---PAGE BREAK--- Page 246 of 1235 Page 246 of 1235 Page 246 of 1235 Page 246 of 1235 ---PAGE BREAK--- Page 247 of 1235 Page 247 of 1235 Page 247 of 1235 Page 247 of 1235 ---PAGE BREAK--- Page 248 of 1235 Page 248 of 1235 Page 248 of 1235 Page 248 of 1235 ---PAGE BREAK--- Page 249 of 1235 Page 249 of 1235 Page 249 of 1235 Page 249 of 1235 ---PAGE BREAK--- Page 250 of 1235 Page 250 of 1235 Page 250 of 1235 Page 250 of 1235 ---PAGE BREAK--- Page 251 of 1235 Page 251 of 1235 Page 251 of 1235 Page 251 of 1235 ---PAGE BREAK--- Page 252 of 1235 Page 252 of 1235 Page 252 of 1235 Page 252 of 1235 ---PAGE BREAK--- Page 253 of 1235 Page 253 of 1235 Page 253 of 1235 Page 253 of 1235 ---PAGE BREAK--- Product Name: CAT HYDRAULIC OIL (HYDO) SAE 10W Revision Date: 02 Mar 2015 Page 1 of 10 SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: CAT HYDRAULIC OIL (HYDO) SAE 10W Product Description: Base Oil and Additives Product Code: 20202050B020, 478909-00, 971670 Intended Use: Hydraulic/transmission fluid COMPANY IDENTIFICATION Supplier: EXXON MOBIL CORPORATION 3225 GALLOWS RD. FAIRFAX, VA. 22037 USA 24 Hour Health Emergency [PHONE REDACTED] Transportation Emergency Phone [PHONE REDACTED] or [PHONE REDACTED] CHEMTREC Product Technical Information [PHONE REDACTED] MSDS Internet Address http://www.exxon.com, http://www.mobil.com SECTION 2 HAZARDS IDENTIFICATION This material is not hazardous according to regulatory guidelines (see (M)SDS Section 15). Other hazard information: HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1900.1200. PHYSICAL / CHEMICAL HAZARDS No significant hazards. HEALTH HAZARDS High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, or respiratory irritation. ENVIRONMENTAL HAZARDS No significant hazards. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert Page 254 of 1235 Page 254 of 1235 Page 254 of 1235 Page 254 of 1235 ---PAGE BREAK--- Product Name: CAT HYDRAULIC OIL (HYDO) SAE 10W Revision Date: 02 Mar 2015 Page 2 of 10 advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS This material is defined as a mixture. Hazardous Substance(s) or Complex Substance(s) required for disclosure Name CAS# Concentration* GHS Hazard Codes ZINC DITHIOPHOSPHATE 68649-42-3 1 - 2.5% H315, H318, H401, H411 * All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. As per paragraph of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and exact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact percentage composition will be provided to health professionals, employees, or designated representatives in accordance with applicable provisions of paragraph SECTION 4 FIRST AID MEASURES INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Page 255 of 1235 Page 255 of 1235 Page 255 of 1235 Page 255 of 1235 ---PAGE BREAK--- Product Name: CAT HYDRAULIC OIL (HYDO) SAE 10W Revision Date: 02 Mar 2015 Page 3 of 10 Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Pressurized mists may form a flammable mixture. Hazardous Combustion Products: Aldehydes, Oxides of carbon, Smoke, Fume, Sulfur oxides, Incomplete combustion products FLAMMABILITY PROPERTIES Flash Point [Method]: >200°C (392°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802. PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended. SPILL MANAGEMENT Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. Page 256 of 1235 Page 256 of 1235 Page 256 of 1235 Page 256 of 1235 ---PAGE BREAK--- Product Name: CAT HYDRAULIC OIL (HYDO) SAE 10W Revision Date: 02 Mar 2015 Page 4 of 10 ENVIRONMENTAL PRECAUTIONS Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE HANDLING Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present during switch-loading operations). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. STORAGE The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store in open or unlabelled containers. Keep away from incompatible materials. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols can occur the following are recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction), 5 mg/m³ - OSHA PEL. NOTE: Limits/standards shown for guidance only. Follow applicable regulations. No biological limits allocated. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to Page 257 of 1235 Page 257 of 1235 Page 257 of 1235 Page 257 of 1235 ---PAGE BREAK--- Product Name: CAT HYDRAULIC OIL (HYDO) SAE 10W Revision Date: 02 Mar 2015 Page 5 of 10 be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Physical State: Liquid Color: Amber Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 0.878 Flammability (Solid, Gas): N/A Flash Point [Method]: >200°C (392°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) [Estimated] Decomposition Temperature: N/D Vapor Density (Air = > 2 at 101 kPa [Estimated] Page 258 of 1235 Page 258 of 1235 Page 258 of 1235 Page 258 of 1235 ---PAGE BREAK--- Product Name: CAT HYDRAULIC OIL (HYDO) SAE 10W Revision Date: 02 Mar 2015 Page 6 of 10 Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C [Estimated] Evaporation Rate (n-butyl acetate = N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 [Estimated] Solubility in Water: Negligible Viscosity: 37.7 cSt (37.7 mm2/sec) at 40 °C I 6.1 cSt (6.1 mm2/sec) at 100°C Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -18°C (0°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt SECTION 10 STABILITY AND REACTIVITY REACTIVITY: See sub-sections below. STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS Hazard Class Conclusion / Remarks Inhalation Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Ingestion Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Corrosion/Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on assessment of the components. Eye Serious Eye Damage/Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components. Sensitization Respiratory Sensitization: No end point data Not expected to be a respiratory sensitizer. Page 259 of 1235 Page 259 of 1235 Page 259 of 1235 Page 259 of 1235 ---PAGE BREAK--- Product Name: CAT HYDRAULIC OIL (HYDO) SAE 10W Revision Date: 02 Mar 2015 Page 7 of 10 for material. Skin Sensitization: No end point data for material. Not expected to be a skin sensitizer. Based on assessment of the components. Aspiration: Data available. Not expected to be an aspiration hazard. Based on physico-chemical properties of the material. Germ Cell Mutagenicity: No end point data for material. Not expected to be a germ cell mutagen. Based on assessment of the components. Carcinogenicity: No end point data for material. Not expected to cause cancer. Based on assessment of the components. Reproductive Toxicity: No end point data for material. Not expected to be a reproductive toxicant. Based on assessment of the components. Lactation: No end point data for material. Not expected to cause harm to breast-fed children. Specific Target Organ Toxicity (STOT) Single Exposure: No end point data for material. Not expected to cause organ damage from a single exposure. Repeated Exposure: No end point data for material. Not expected to cause organ damage from prolonged or repeated exposure. Based on assessment of the components. OTHER INFORMATION Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Not expected to be harmful to aquatic organisms. MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable Page 260 of 1235 Page 260 of 1235 Page 260 of 1235 Page 260 of 1235 ---PAGE BREAK--- Product Name: CAT HYDRAULIC OIL (HYDO) SAE 10W Revision Date: 02 Mar 2015 Page 8 of 10 BIOACCUMULATION POTENTIAL Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. Protect the environment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents, brake fluids or coolants. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (DOT): Not Regulated for Land Transport LAND (TDG): Not Regulated for Land Transport SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code Marine Pollutant: No Page 261 of 1235 Page 261 of 1235 Page 261 of 1235 Page 261 of 1235 ---PAGE BREAK--- Product Name: CAT HYDRAULIC OIL (HYDO) SAE 10W Revision Date: 02 Mar 2015 Page 9 of 10 AIR (IATA): Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with OSHA HazCom 2012, 29 CFR 1910.1200. Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, ENCS, IECSC, KECI, PICCS, TSCA EPCRA SECTION 302: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: Chemical Name CAS Number Typical Value ZINC DITHIOPHOSPHATE 68649-42-3 1 - 2.5% The following ingredients are cited on the lists below: Chemical Name CAS Number List Citations ZINC DITHIOPHOSPHATE 68649-42-3 13, 15, 17, 19 --REGULATORY LISTS SEARCHED-- 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK 5 = TSCA 4 10 = CA P65 CARC 15 = MI 293 Code key: CARC=Carcinogen; REPRO=Reproductive SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only): H315: Causes skin irritation; Skin Corr/Irritation, Cat 2 H318: Causes serious eye damage; Serious Eye Damage/Irr, Cat 1 H401: Toxic to aquatic life; Acute Env Tox, Cat 2 H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2 Page 262 of 1235 Page 262 of 1235 Page 262 of 1235 Page 262 of 1235 ---PAGE BREAK--- Product Name: CAT HYDRAULIC OIL (HYDO) SAE 10W Revision Date: 02 Mar 2015 Page 10 of 10 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Updates made in accordance with implementation of GHS requirements. The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A DGN: 2004671XUS (546411) Copyright 2002 Exxon Mobil Corporation, All rights reserved Page 263 of 1235 Page 263 of 1235 Page 263 of 1235 Page 263 of 1235 ---PAGE BREAK--- Page 1 of 11 Safety Data Sheet acc. to HCS and GHS Printing date 01/06/2015 Reviewed on 01/06/2015 40.0.2 1 Identification · Product identifier · Trade name: Clear Reflections · Article number: 385 · Application of the substance / the mixture Glass Cleaner · Details of the supplier of the Safety Data Sheet · Manufacturer/Supplier: ITW Pro Brands 805 East Old 56 Highway Olathe, Kansas 66061 Phone: 1-[PHONE REDACTED] · Emergency telephone number: Infotrac Emergency Hotline: 1-[PHONE REDACTED] 2 Hazard(s) identification · Classification of the substance or mixture GHS04 Gas cylinder Press. Gas H280 Contains gas under pressure; may explode if heated. · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms GHS04 · Signal word Warning · Hazard statements H280 Contains gas under pressure; may explode if heated. · Precautionary statements P410+P403 Protect from sunlight. Store in a well-ventilated place. · Hazard description: · WHMIS-symbols: A - Compressed gas · Classification system: · NFPA ratings (scale 0 - 4) 0 0 0 Health = 0 Fire = 0 Reactivity = 0 (Contd. on page 2) Page 264 of 1235 Page 264 of 1235 Page 264 of 1235 Page 264 of 1235 ---PAGE BREAK--- Page 2 of 11 Safety Data Sheet acc. to HCS and GHS Printing date 01/06/2015 Reviewed on 01/06/2015 Trade name: Clear Reflections (Contd. of page 1) 40.0.2 · HMIS-ratings (scale 0 - 4) HEALTH FIRE REACTIVITY 0 0 0 Health = 0 Fire = 0 Reactivity = 0 · Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. 3 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Mixture of the substances listed below with nonhazardous additions. · Dangerous components: 74-98-6 propane Flam. Gas 1, H220 Press. Gas, H280 2.5-10% 72-28-5 Isobutane Flam. Gas 1, H220 2.5% 64-17-5 ethanol Flam. Liq. 2, H225 Eye Irrit. 2A, H319 2.5% 111-76-2 2-butoxyethanol Acute Tox. 4, H302; Acute Tox. 4, H312; Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319 Flam. Liq. 4, H227 2.5% 4 First-aid measures · Description of first aid measures · General information: Take affected persons out into the fresh air. · After inhalation: Supply fresh air; consult doctor in case of complaints. Provide oxygen treatment if affected person has difficulty breathing. · After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation is experienced, consult a doctor. · After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If persist, consult a doctor. · After swallowing: Unlikely route of exposure. Rinse out mouth and then drink plenty of water. Do not induce vomiting; immediately call for medical help. (Contd. on page 3) Page 265 of 1235 Page 265 of 1235 Page 265 of 1235 Page 265 of 1235 ---PAGE BREAK--- Page 3 of 11 Safety Data Sheet acc. to HCS and GHS Printing date 01/06/2015 Reviewed on 01/06/2015 Trade name: Clear Reflections (Contd. of page 2) 40.0.2 · Most important and effects, both acute and delayed Headache Breathing difficulty Dizziness Coughing Nausea Disorientation · Danger Danger of impaired breathing. · Indication of any immediate medical attention and special treatment needed If necessary oxygen respiration treatment. 5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: Use fire fighting measures that suit the environment. · For safety reasons unsuitable extinguishing agents: None. · Special hazards arising from the substance or mixture Danger of receptacles bursting because of high vapor pressure if heated. Formation of toxic gases is possible during heating or in case of fire. · Advice for firefighters · Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. · Additional information No further relevant information available. 6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. For large spills, wear protective clothing. For large spills, use respiratory protective device against the effects of fumes/dust/aerosol. · Environmental precautions: No special measures required. · Methods and material for containment and cleaning up: Absorb liquid components with liquid-binding material. Pick up mechanically. Dispose contaminated material as waste according to item 13. Send for recovery or disposal in suitable receptacles. · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage · Precautions for safe handling Keep away from heat and direct sunlight. Use only in well ventilated areas. (Contd. on page 4) Page 266 of 1235 Page 266 of 1235 Page 266 of 1235 Page 266 of 1235 ---PAGE BREAK--- Page 4 of 11 Safety Data Sheet acc. to HCS and GHS Printing date 01/06/2015 Reviewed on 01/06/2015 Trade name: Clear Reflections (Contd. of page 3) 40.0.2 Avoid splashes or spray in enclosed areas. · Information about protection against explosions and fires: No special measures required. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Observe official regulations on storing packagings with pressurized containers. Provide ventilation for receptacles. · Information about storage in one common storage facility: Store away from foodstuffs. Store away from oxidizing agents. · Further information about storage conditions: Store in a cool place. Heat will increase pressure and may lead to the receptacle bursting. Protect from frost. · Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection · Additional information about design of technical systems: No further data; see item 7. · Control parameters · Components with limit values that require monitoring at the workplace: 74-98-6 propane PEL (USA) Long-term value: 1800 mg/m³, 1000 ppm REL (USA) Long-term value: 1800 mg/m³, 1000 ppm TLV (USA) refer to Appendix F EL (Canada) Long-term value: 1000 ppm EV (Canada) Long-term value: 1.000 ppm LMPE (Mexico) Long-term value: 1000 ppm 64-17-5 ethanol PEL (USA) Long-term value: 1900 mg/m³, 1000 ppm REL (USA) Long-term value: 1900 mg/m³, 1000 ppm TLV (USA) Short-term value: 1880 mg/m³, 1000 ppm EL (Canada) Short-term value: 1000 ppm EV (Canada) Long-term value: 1.900 mg/m³, 1.000 ppm LMPE (Mexico) Long-term value: 1000 ppm A3 111-76-2 2-butoxyethanol PEL (USA) Long-term value: 240 mg/m³, 50 ppm Skin REL (USA) Long-term value: 24 mg/m³, 5 ppm Skin TLV (USA) Long-term value: 97 mg/m³, 20 ppm BEI (Contd. on page 5) Page 267 of 1235 Page 267 of 1235 Page 267 of 1235 Page 267 of 1235 ---PAGE BREAK--- Page 5 of 11 Safety Data Sheet acc. to HCS and GHS Printing date 01/06/2015 Reviewed on 01/06/2015 Trade name: Clear Reflections (Contd. of page 4) 40.0.2 EL (Canada) Long-term value: 20 ppm EV (Canada) Long-term value: 20 ppm Skin LMPE (Mexico) Long-term value: 20 ppm A3, IBE · Ingredients with biological limit values: 111-76-2 2-butoxyethanol BEI (USA) 200 mg/g creatinine Medium: urine Time: end of shift Parameter: Butoxyacetic acid with hydrolysis · Additional information: The lists that were valid during the creation were used as basis. · Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work. Do not inhale gases / fumes / aerosols. Avoid close or long term contact with the skin. Avoid contact with the eyes. · Breathing equipment: Not required under normal conditions of use. For spills, respiratory protection may be advisable. Use suitable respiratory protective device in case of insufficient ventilation. · Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing · Limitation and supervision of exposure into the environment No further relevant information available. (Contd. on page 6) Page 268 of 1235 Page 268 of 1235 Page 268 of 1235 Page 268 of 1235 ---PAGE BREAK--- Page 6 of 11 Safety Data Sheet acc. to HCS and GHS Printing date 01/06/2015 Reviewed on 01/06/2015 Trade name: Clear Reflections (Contd. of page 5) 40.0.2 9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Form: Aerosol Color: Colorless · Odor: Pleasant · Odor threshold: Not determined. · pH-value: 9.0 - 10.0 · Change in condition Melting point/Melting range: Not applicable, as aerosol. Boiling point/Boiling range: Not applicable, as aerosol. · Flash point: Not applicable, as aerosol. · Flammability (solid, gaseous): Not applicable. · Auto-ignition temperature: Not determined. · Decomposition temperature: Not determined. · Auto igniting: Product is not self-igniting. · Danger of explosion: Not determined. · Explosion limits: Lower: Not determined. Upper: Not determined. · Vapor pressure at 21 °C (70 125 psig · Density at 20 °C (68 0.996 g/cm³ (8.312 lbs/gal) · Relative density Not determined. · Vapour density > 1 (Air=1) · Evaporation rate Not applicable. · Solubility in / Miscibility with Water: Soluble. · Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Not determined. Kinematic: Not determined. · Solvent content: VOC content: 7.38 % · Other information No further relevant information available. (Contd. on page 7) Page 269 of 1235 Page 269 of 1235 Page 269 of 1235 Page 269 of 1235 ---PAGE BREAK--- Page 7 of 11 Safety Data Sheet acc. to HCS and GHS Printing date 01/06/2015 Reviewed on 01/06/2015 Trade name: Clear Reflections (Contd. of page 6) 40.0.2 10 Stability and reactivity · Reactivity · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications. · Possibility of hazardous reactions Toxic fumes may be released if heated above the decomposition point. Reacts with strong acids and oxidizing agents. · Conditions to avoid Keep away from heat and direct sunlight. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: Possible in traces. Carbon monoxide and carbon dioxide Nitrogen oxides 11 Toxicological information · Information on toxicological effects · Acute toxicity: · Primary irritant effect: · on the skin: No irritant effect. · on the eye: No irritating effect. · Sensitization: No sensitizing effects known. · Additional toxicological information: · Carcinogenic categories · IARC (International Agency for Research on Cancer) See Section 15. · NTP (National Toxicology Program) None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. 12 Ecological information · Toxicity · Aquatic toxicity: No further relevant information available. · Persistence and degradability No further relevant information available. · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. · Results of PBT and vPvB assessment · PBT: Not applicable. (Contd. on page 8) Page 270 of 1235 Page 270 of 1235 Page 270 of 1235 Page 270 of 1235 ---PAGE BREAK--- Page 8 of 11 Safety Data Sheet acc. to HCS and GHS Printing date 01/06/2015 Reviewed on 01/06/2015 Trade name: Clear Reflections (Contd. of page 7) 40.0.2 · vPvB: Not applicable. · Other adverse effects No further relevant information available. 13 Disposal considerations · Waste treatment methods · Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Contact waste processors for recycling information. The user of this material has the responsibility to dispose of unused material, residues and containers in compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and disposal for hazardous and nonhazardous wastes. Residual materials should be treated as hazardous. · Waste disposal key: EPA RCRA Code (USA) : D001 . · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. 14 Transport information · UN-Number · DOT, ADR, IMDG, IATA UN1950 · UN proper shipping name Limited Quantity for packages less than 30 kg (66 lb) and inner packagings less than 1 L (0.3 gal). · DOT Aerosols · ADR 1950 AEROSOLS · IMDG AEROSOLS · IATA Aerosols, non-flammable · Transport hazard class(es) · DOT · Class 2 Gases · Label 2.2 · ADR · Class 2 5A Gases (Contd. on page 9) Page 271 of 1235 Page 271 of 1235 Page 271 of 1235 Page 271 of 1235 ---PAGE BREAK--- Page 9 of 11 Safety Data Sheet acc. to HCS and GHS Printing date 01/06/2015 Reviewed on 01/06/2015 Trade name: Clear Reflections (Contd. of page 8) 40.0.2 · Label 2.2 · IMDG · Class 2 Gases · Label 2.2 · IATA · Class 2.2 · Label 2.2 · Packing group · DOT, ADR, IMDG, IATA Not Regulated · Environmental hazards: · Marine pollutant: No · Special precautions for user Warning: Gases · Danger code (Kemler): - · EMS Number: F-D,S-U · Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional information: · DOT · Quantity limitations On passenger aircraft/rail: 75kg On cargo aircraft only: 150kg · ADR · Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity · IMDG · Limited quantities (LQ) 1L · Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity · UN "Model Regulation": UN1950, Aerosols, 2.2 15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture · SARA · Section 355 (extremely hazardous substances): None of the ingredients is listed. (Contd. on page 10) Page 272 of 1235 Page 272 of 1235 Page 272 of 1235 Page 272 of 1235 ---PAGE BREAK--- Page 10 of 11 Safety Data Sheet acc. to HCS and GHS Printing date 01/06/2015 Reviewed on 01/06/2015 Trade name: Clear Reflections (Contd. of page 9) 40.0.2 · Section 313 (Specific toxic chemical listings): 111-76-2 2-butoxyethanol · TSCA (Toxic Substances Control Act): All ingredients are listed. · Proposition 65 (California) · Chemicals known to cause cancer: Ethanol - listing refers specifically to alcoholic beverage consumption and is not applicable for product. 64-17-5 ethanol · Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: Ethanol - listing refers specifically to alcoholic beverage consumption and is not applicable for product. 64-17-5 ethanol · Carcinogenic categories · EPA (Environmental Protection Agency) 111-76-2 2-butoxyethanol NL · IARC (International Agency for Research on Cancer) 64-17-5 ethanol 1 111-76-2 2-butoxyethanol 3 · TLV (Threshold Limit Value established by ACGIH) 64-17-5 ethanol A3 111-76-2 2-butoxyethanol A3 · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. · State Right to Know Listings None of the ingredients is listed. · Canadian substance listings: · Canadian Domestic Substances List (DSL) All ingredients are listed. · Canadian Ingredient Disclosure list (limit 0.1%) 64-17-5 ethanol · Canadian Ingredient Disclosure list (limit 111-76-2 2-butoxyethanol · Other regulations, limitations and prohibitive regulations This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations. (Contd. on page 11) Page 273 of 1235 Page 273 of 1235 Page 273 of 1235 Page 273 of 1235 ---PAGE BREAK--- Page 11 of 11 Safety Data Sheet acc. to HCS and GHS Printing date 01/06/2015 Reviewed on 01/06/2015 Trade name: Clear Reflections (Contd. of page 10) 40.0.2 · Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Date of preparation / last revision 01/06/2015 / - · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) WHMIS: Workplace Hazardous Materials Information System (Canada) VOC: Volatile Organic Compounds (USA, EU) Flam. Gas 1: Flammable gases, Hazard Category 1 Press. Gas: Gases under pressure: Compressed gas Flam. Liq. 2: Flammable liquids, Hazard Category 2 Flam. Liq. 4: Flammable liquids, Hazard Category 4 Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A · Sources SDS Prepared by: ChemTel Inc. 1305 North Florida Avenue Tampa, Florida USA 33602-2902 Toll Free North America 1-[PHONE REDACTED] Intl. +01 [PHONE REDACTED] Website: www.chemtelinc.com Page 274 of 1235 Page 274 of 1235 Page 274 of 1235 Page 274 of 1235 ---PAGE BREAK--- SAFETY DATA SHEET Issuing Date January 5, 2015 Revision Date New Revision Number 0 Page 1 / 10 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Clorox® Bleach Other means of identification Synonyms None Recommended use of the chemical and restrictions on use Recommended use Laundry and household bleach Uses advised against No information available Details of the supplier of the safety data sheet Supplier Address The Clorox Company of Canada Ltd. 150 Biscayne Crescent Brampton, Ontario L6W 4V3 Emergency telephone number Emergency Phone Numbers For Medical Emergencies, call: 1-[PHONE REDACTED] For Transportation Emergencies, call Chemtrec: 1-[PHONE REDACTED] 2. HAZARDS IDENTIFICATION Page 275 of 1235 Page 275 of 1235 Page 275 of 1235 Page 275 of 1235 ---PAGE BREAK--- Clorox® Bleach Revision Date New Page 2 / 10 Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Serious eye damage/eye irritation Category 2A GHS Label elements, including precautionary statements Emergency Overview Signal word Warning Hazard Statements Causes serious eye irritation Appearance Clear, pale yellow Physical State Liquid Odor Bleach Precautionary Statements - Prevention Wash hands and any exposed skin thoroughly after handling. Wear eye protection/face protection such as safety glasses. Precautionary Statements - Response Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Precautionary Statements - Storage None Precautionary Statements - Disposal None Hazards not otherwise classified (HNOC) Not applicable. Unknown Toxicity 0.06% of the mixture consists of ingredient(s) of unknown toxicity Other information Very toxic to aquatic life with long lasting effects. Interactions with Other Chemicals Reacts with other household chemicals such as toilet bowl cleaners, rust removers, acids, and ammonia-containing products to produce hazardous gases, such as chlorine and other chlorinated compounds. Page 276 of 1235 Page 276 of 1235 Page 276 of 1235 Page 276 of 1235 ---PAGE BREAK--- Clorox® Bleach Revision Date New Page 3 / 10 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Trade Secret Sodium hypochlorite 7681-52-9 1 - 5 * Sodium hydroxide 1310-73-2 0.1 - 1 * * The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES First aid measures General Advice Show this safety data sheet to the doctor in attendance. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open while rinsing. Do not rub affected area. Get medical attention if irritation develops and persists. Skin Contact Take off contaminated clothing. Rinse skin with plenty of water. If irritation develops, call a doctor. Inhalation Move to fresh air. If breathing is affected, call a doctor. Ingestion Drink a glassful of water. Call a poison control center or doctor immediately. DO NOT induce vomiting unless told to do so by a poison control center or doctor. Protection of First-aiders Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Wear personal protective clothing (see section Most important and effects, both acute and delayed Most Important and Effects Stinging and irritation of eyes. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat Page 277 of 1235 Page 277 of 1235 Page 277 of 1235 Page 277 of 1235 ---PAGE BREAK--- Clorox® Bleach Revision Date New Page 4 / 10 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical No information available. Explosion Data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Avoid contact with eyes, skin, and clothing. Use personal protective equipment as required. Other Information Refer to protective measures listed in Sections 7 and 8. Environmental precautions Environmental Precautions See Section 12 for ecological Information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed-down material. 7. HANDLING AND STORAGE Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Conditions for safe storage, including any incompatibilities Storage Keep containers closed in a dry, cool and well-ventilated place. Incompatible Products Toilet bowl cleaners, rust removers, acids, and ammonia-containing products. Page 278 of 1235 Page 278 of 1235 Page 278 of 1235 Page 278 of 1235 ---PAGE BREAK--- Clorox® Bleach Revision Date New Page 5 / 10 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Sodium hydroxide 1310-73-2 Ceiling: 2 mg/m3 TWA: 2 mg/m3 IDLH: 10 mg/m3 Ceiling: 2 mg/m3 ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health. Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection If splashes are likely to occur: Wear safety glasses with side shields (or goggles). None required for consumer use. Skin and Body Protection Wear rubber or neoprene gloves if there is the potential for repeated or prolonged skin contact. Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Hygiene Measures Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Page 279 of 1235 Page 279 of 1235 Page 279 of 1235 Page 279 of 1235 ---PAGE BREAK--- Clorox® Bleach Revision Date New Page 6 / 10 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Physical State Liquid Appearance Clear Odor Bleach Color Pale yellow Odor Threshold No information available Property Values Remarks/ Method pH ~12.5 None known Melting/freezing point No data available None known Boiling point / boiling range No data available None known Flash Point Not flammable None known Evaporation rate No data available None known Flammability (solid, gas) No data available None known Flammability Limits in Air Upper flammability limit No data available None known Lower flammability limit No data available None known Vapor pressure No data available None known Vapor density No data available None known Specific Gravity ~1.05 None known Water Solubility Soluble in water None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/water No data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known Explosive Properties Not explosive Oxidizing Properties No data available Other Information Softening Point No data available VOC Content No data available Particle Size No data available Particle Size Distribution No data available 10. STABILITY AND REACTIVITY Reactivity Reacts with other household chemicals such as toilet bowl cleaners, rust removers, acids, and ammonia-containing products to produce hazardous gases, such as chlorine and other chlorinated compounds. Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid None known based on information supplied. Incompatible materials Toilet bowl cleaners, rust removers, acids, and ammonia-containing products. Hazardous Decomposition Products None known based on information supplied. Page 280 of 1235 Page 280 of 1235 Page 280 of 1235 Page 280 of 1235 ---PAGE BREAK--- Clorox® Bleach Revision Date New Page 7 / 10 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information . Inhalation Exposure to vapor or mist may irritate respiratory tract. Eye Contact May cause eye irritation. Skin Contact Prolonged contact may cause irritation. Ingestion Ingestion may cause irritation to mucous membranes and gastrointestinal tract, nausea, vomiting, and diarrhea. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Sodium hypochlorite 7681-52-9 8200 mg/kg (Rat) >10000 mg/kg (Rabbit) - Sodium hydroxide 1310-73-2 - 1350 mg/kg (Rabbit) - Information on toxicological effects May cause redness and tearing of the eyes. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Mutagenic Effects No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA Sodium hypochlorite 7681-52-9 - Group 3 - - IARC (International Agency for Research on Cancer) Group 3 - Not Classifiable as to Carcinogenicity in Humans Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Chronic Toxicity Carcinogenic potential is unknown. Target Organ Effects Respiratory system, eyes, skin, gastrointestinal tract (GI). Aspiration Hazard No information available. Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS document 117.20 mg/l ATEmix (4 hr) Page 281 of 1235 Page 281 of 1235 Page 281 of 1235 Page 281 of 1235 ---PAGE BREAK--- Clorox® Bleach Revision Date New Page 8 / 10 12. ECOLOGICAL INFORMATION Ecotoxicity Very toxic to aquatic life with long lasting effects. Persistence and Degradability No information available. Bioaccumulation No information available. Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Disposal methods Dispose of in accordance with all applicable federal, state, and local regulations. Contaminated Packaging Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local regulations. 14. TRANSPORT INFORMATION DOT NOT REGULATED TDG UN-No UN3082 Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard Class 9 Packing Group III Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM HYPOCHLORITE), 9, III, MARINE POLLUTANT ICAO UN-No UN3082 Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard Class 9 Packing Group III Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM HYPOCHLORITE), 9, III IATA UN-No UN3082 Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard Class 9 Packing Group III Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM HYPOCHLORITE), 9, III Page 282 of 1235 Page 282 of 1235 Page 282 of 1235 Page 282 of 1235 ---PAGE BREAK--- Clorox® Bleach Revision Date New Page 9 / 10 IMDG/IMO UN-No UN3082 Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard Class 9 Packing Group III EmS No. F-A, S-F Marine Pollutant Product is a marine pollutant according to the criteria set by IMDG/IMO Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM HYPOCHLORITE), 9, III, MARINE POLLUTANT 15. REGULATORY INFORMATION Chemical Inventories TSCA All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt from listing. DSL/NDSL All components are on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Sodium hypochlorite 7681-52-9 100 lb X Sodium hydroxide 1310-73-2 1000 lb X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs RQ Sodium hypochlorite 7681-52-9 100 lb - RQ 100 lb final RQ RQ 45.4 kg final RQ Sodium hydroxide 1310-73-2 1000 lb - RQ 1000 lb final RQ RQ 454 kg final RQ Page 283 of 1235 Page 283 of 1235 Page 283 of 1235 Page 283 of 1235 ---PAGE BREAK--- Clorox® Bleach Revision Date New Page 10 / 10 US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Rhode Island Illinois Sodium hypochlorite 7681-52-9 X X X X Sodium hydroxide 1310-73-2 X X X X International Regulations Canada WHMIS Hazard Class D2B - Toxic materials 16. OTHER INFORMATION NFPA Health Hazard 2 Flammability 0 Instability 0 Physical and Chemical Hazards - HMIS Health Hazard 2 Flammability 0 Physical Hazard 0 Personal Protection B Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-[PHONE REDACTED] Revision Date New Revision Note Reference New 1076851/173214.001 General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 284 of 1235 Page 284 of 1235 Page 284 of 1235 Page 284 of 1235 ---PAGE BREAK--- FICHE DE DONNÉES DE SÉCURITÉ Date d'émission 5 janvier 2015 Date de révision Nouvelle Numéro de révision 0 Page 1 / 11 IDENTIFICATION DE LA SUBSTANCE/DE LA PRÉPARATION ET DE LA SOCIÉTÉ/L’ENTREPRISE Identificateur de produit Nom du produit Eau de Javel Clorox® Autres moyens d’identification Synonymes Aucun Utilisation recommandée pour le produit chimique et restrictions en matière d’utilisation Utilisation recommandée Lessive et eau de Javel domestique Utilisations déconseillées Aucune information disponible Renseignements concernant le fournisseur de la fiche de données de sécurité Adresse du fournisseur The Clorox Company of Canada Ltd. 150 Biscayne Crescent Brampton, Ontario L6W 4V3 Numéro de téléphone d’urgence Numéros de téléphone d’urgence Pour des urgences médicales, appelez : 1 [PHONE REDACTED] Pour des urgences en matière de transport, appelez Chemtrec : 1 [PHONE REDACTED] Page 285 of 1235 Page 285 of 1235 Page 285 of 1235 Page 285 of 1235 ---PAGE BREAK--- Eau de Javel Clorox® Date de révision Nouvelle Page 2 / 11 2. IDENTIFICATION DES DANGERS Classification Ce produit chimique est considéré comme dangereux selon la norme sur la communication des renseignements à l’égard des matières dangereuses 2012 d’OSHA (29 CFR 1910.1200) Lésions oculaires graves/irritation oculaire Catégorie 2A Éléments d’étiquetage SGH, y compris les conseils de prudence Vue d’ensemble des procédures d’urgence Mot indicateur Avertissement Mentions de danger Provoque une sévère irritation des yeux Apparence Transparent, jaune pâle État physique Liquide Odeur Javellisant Conseils de prudence - Prévention Se laver les mains et toute peau exposée à fond après manutention. Porter une protection oculaire/faciale telle que des lunettes de sécurité. Conseils de prudence - Réaction Yeux : EN CAS DE CONTACT AVEC LES YEUX : Rincer prudemment avec de l’eau pendant plusieurs minutes. Retirer les verres de contact si la victime en porte et qu’il est possible de les retirer facilement. Continuer à rincer. Si l’irritation oculaire persiste : Obtenir une consultation médicale ou des soins médicaux. Conseils de prudence - Stockage Aucun Conseils de prudence - Élimination Aucun Dangers non classés ailleurs (DNCA) Sans objet. Toxicité inconnue 0,06 % du mélange est constitué d’ingrédients de toxicité inconnue Autres informations Très toxique pour les organismes aquatiques, entraîne des effets à long terme Interactions avec d’autres produits chimiques Réagit avec d’autres produits chimiques domestiques tels que nettoyants de cuvette de toilette, les produits antirouille, les acides et les produits à base d’ammoniac pour produire des gaz dangereux, comme le chlore et autres produits chlorés. Page 286 of 1235 Page 286 of 1235 Page 286 of 1235 Page 286 of 1235 ---PAGE BREAK--- Eau de Javel Clorox® Date de révision Nouvelle Page 3 / 11 3. COMPOSITION / INFORMATION SUR LES COMPOSANTS Nom chimique No CAS % en poids Secret commercial Hypochlorite de sodium 7681-52-9 1 - 5 * Hydroxyde de sodium 1310-73-2 0,1 - 1 * * Le pourcentage (concentration) exact de composition est retenu comme un secret commercial. 4. PREMIERS SOINS Premiers soins Conseils généraux Présenter cette fiche signalétique au médecin traitant. Contact avec les yeux Rincer immédiatement avec une grande quantité d’eau, également sous les paupières, pendant au moins quinze minutes. Retirer les verres de contact si la victime en porte et qu’il est possible de les retirer facilement. Continuer à rincer. Garder les yeux grands ouverts lors du rinçage. Ne pas frotter la partie touchée. Obtenir des soins médicaux si une irritation se produit et persiste. Contact avec la peau Retirer les vêtements contaminés. Rincer la peau avec beaucoup d’eau. En cas d’irritaiton, appeler un médecin. Inhalation Déplacer à l’air frais. Si la respiration est touchée, appeler un médecin. Ingestion Boire un verre d’eau. Appeler immédiatement un centre antipoison ou un médecin. NE PAS provoquer de vomissements à moins d’en avoir reçu la directive d’un centre antipoison ou d’un médecin. Protection des secouristes Éviter le contact avec la peau, les yeux ou les vêtements. Utiliser l’équipement de protection individuel requis. Porter des vêtements de protection individuelle (voir la section les plus importants, aigus et retardés les plus importants Picotement et irritation des yeux. Indications quant à la nécessité éventuelle d’une prise en charge médicale immédiate ou d’un traitement spécial Notes au médecin Traiter en fonction des Page 287 of 1235 Page 287 of 1235 Page 287 of 1235 Page 287 of 1235 ---PAGE BREAK--- Eau de Javel Clorox® Date de révision Nouvelle Page 4 / 11 5. MESURES À PRENDRE EN CAS D’INCENDIE Agents extincteurs appropriés Utiliser des mesures d’extinction appropriées aux circonstances locales et à l’environnement immédiat. Agents extincteurs inappropriés ATTENTION : L’utilisation d’une pulvérisation d’eau pour combattre un incendie peut se révéler inefficace. Dangers spécifiques du produit Aucune information disponible. Données sur les risques d’explosion Sensibilité à un choc mécanique Aucune. Sensibilité à une décharge statique Aucune. Équipement de protection et précautions pour les pompiers Comme avec tout incendie, porter un appareil respiratoire autonome à demande de pression, MSHA/NIOSH (homologué ou équivalent) et une tenue de protection complète. 6. MESURES À PRENDRE EN CAS DE DÉVERSEMENTS ACCIDENTELS Précautions individuelles, équipement de protection et mesures d’urgence Précautions individuelles Éviter tout contact avec les yeux, la peau et les vêtements. Utiliser l’équipement de protection individuelle requis. Autres informations Consulter les mesures de protection données aux sections 7 et 8. Précautions relatives à l’environnement Précautions relatives à l’environnement Voir la Section 12 pour des données écologiques. Méthodes et matériaux pour l’isolation et le nettoyage Méthodes d’isolation Empêcher d’autres fuites ou déversements lorsqu’il est possible de le faire en toute sécurité. Méthodes de nettoyage Absorber et conteneuriser. Laver les résider et les envoyer à un égout sanitaire. Contacter une installation de traitement sanitaire à l’avance pour s’assurer de sa capacité à traiter le matériel emporté. 7. MANUTENTION ET STOCKAGE Précautions relatives à la sécurité de manutention Manutention Manipuler conformément aux bonnes pratiques de sécurité et d’hygiène industrielle. Éviter le contact avec la peau, les yeux et les vêtements Ne pas manger, boire ou fumer en manipulant le produit. Conditions de sécurité de stockage, y compris les incompatibilités Stockage Conserver les récipients bien fermés dans un endroit sec, frais et bien ventilé. Produits incompatibles Nettoyants de cuvette de toilette, les produits antirouille, les acides et les produits à base d’ammoniac. Page 288 of 1235 Page 288 of 1235 Page 288 of 1235 Page 288 of 1235 ---PAGE BREAK--- Eau de Javel Clorox® Date de révision Nouvelle Page 5 / 11 8. CONTRÔLE DE L’EXPOSITION/PROTECTION INDIVIDUELLE Paramètres de contrôle Directives relatives à l’exposition Nom chimique ACGIH TLV OSHA PEL NIOSH IDLH Hydroxyde de sodium 1310-73-2 Valeur plafond : 2 mg/m3 TWA : 2 mg/m3 IDLH : 10 mg/m3 Valeur plafond : 2 mg/m3 ACGIH TLV : Conférence américaine des hygiénistes industriels gouvernementaux - valeur limite d’exposition OSHA PEL : Administration de la sécurité et de la santé professionnelle - limites d’exposition admissibles NIOSH IDLH : Dangereux immédiatement pour la santé ou la vie. Contrôles d’ingénierie appropriés Mesures techniques Douches Douches oculaires Systèmes de ventilation Mesures de protection individuelle telles que les équipements de protection individuelle Protection des yeux/du visage En cas d’éclaboussures probables : Porter des lunettes de sécurité à écrans latéraux (ou des lunettes à coques). Aucune nécessaire pour une utilisation par le consommateur. Protection de la peau et du corps Porter des gants en caoutchouc ou en néoprène s’il existe une possibilité d’un contact répété ou prolongé avec la peau. Protection respiratoire En cas d’irritation ou de dépassement des limites d’exposition, vous devez porter une protection respiratoire approuvée NIOSH/MSHA. Des respirateurs à adduction d’air à pression positive peuvent être requis pour des concentrations élevées de contaminants atmosphériques. Une protection respiratoire doit être fournie conformément à la réglementation locale en cours. Mesures d’hygiène Retirer et laver les vêtements contaminés avant de les réutiliser. Éviter le contact avec la peau, les yeux ou les vêtements. Ne pas manger, boire ou fumer en manipulant le produit. Page 289 of 1235 Page 289 of 1235 Page 289 of 1235 Page 289 of 1235 ---PAGE BREAK--- Eau de Javel Clorox® Date de révision Nouvelle Page 6 / 11 9. PROPRIÉTÉS PHYSIQUES ET CHIMIQUES Propriétés physiques et chimiques État physique Liquide Apparence Transparent Odeur Javellisant Couleur Jaune pâle Seuil olfactif Aucune information disponible Propriété Valeurs Remarques/ Méthode pH ~ 12,5 Aucune connue Point de fusion/point de congélation Aucune donnée disponible Aucune connue Point d’ébullition / Domaine d’ébullition Aucune donnée disponible Aucune connue Point d’éclair Ininflammable Aucune connue Taux d’évaporation Aucune donnée disponible Aucune connue Inflammabilité (solide, gaz) Aucune donnée disponible Aucune connue Limites d’inflammabilité dans l’air Limite supérieure d’inflammabilité Aucune donnée disponible Aucune connue Limite inférieure d’inflammabilité Aucune donnée disponible Aucune connue Tension de vapeur Aucune donnée disponible Aucune connue Densité de la vapeur Aucune donnée disponible Aucune connue Densité ~ 1,05 Aucune connue Solubilité dans l’eau Soluble dans l’eau Aucune connue Solubilité dans d’autres solvants Aucune donnée disponible Aucune connue Coefficient de partage : n-octanol/eau Aucune donnée disponible Aucune connue Température d’auto-inflammation Aucune donnée disponible Aucune connue Température de décomposition Aucune donnée disponible Aucune connue Viscosité cinématique Aucune donnée disponible Aucune connue Viscosité dynamique Aucune donnée disponible Aucune connue Propriétés explosives Non explosif Propriétés comburantes Aucune donnée disponible Autres informations Point de ramollissement Aucune donnée disponible Teneur en COV Aucune donnée disponible Dimension de particules Aucune donnée disponible Distribution granulométrique Aucune donnée disponible Page 290 of 1235 Page 290 of 1235 Page 290 of 1235 Page 290 of 1235 ---PAGE BREAK--- Eau de Javel Clorox® Date de révision Nouvelle Page 7 / 11 10. STABILITÉ ET RÉACTIVITÉ Réactivité Réagit avec d’autres produits chimiques domestiques tels que nettoyants de cuvette de toilette, les produits antirouille, les acides et les produits à base d’ammoniac pour produire des gaz dangereux, comme le chlore et autres produits chlorés. Stabilité chimique Stable dans les conditions de stockage recommandées. Risque de réactions dangereuses Aucun dans des conditions normales de traitement. Conditions à éviter Aucune connue selon les renseignements fournis. Matériaux incompatibles Nettoyants de cuvette de toilette, les produits antirouille, les acides et les produits à base d’ammoniac. Produits de décomposition dangereux Aucune connue selon les renseignements fournis. 11. DONNÉES TOXICOLOGIQUES Les voies d’exposition probables Renseignements sur le produit . Inhalation Une exposition aux vapeurs ou à la bruine peut irriter les voies respiratoires. Contact avec les yeux Peut causer une irritation des yeux. Contact avec la peau Un contact prolongé peut causer une irritation. Ingestion Une ingestion peut provoquer une irritation des muqueuses et du tractus gastro-intestinal, des nausées, des vomissements et une diarrhée. Informations sur les composants Nom chimique DL50 orale DL50 cutanée CL50 par inhalation Hypochlorite de sodium 7681-52-9 8 200 mg/kg (rat) > 10 000 mg/kg (lapin) - Hydroxyde de sodium 1310-73-2 - 1350 mg/kg (lapin) - Informations sur les effets toxicologiques Peut causer une rougeur et un larmoiement des yeux. Les effets retardés et immédiats ainsi que les effets chroniques dus à une exposition à court et long terme Sensibilisation Aucune information disponible. Effets mutagènes Aucune information disponible. Cancérogénicité Le tableau ci-dessous indique si chaque agence a inscrit un ingrédient comme étant cancérigène. Page 291 of 1235 Page 291 of 1235 Page 291 of 1235 Page 291 of 1235 ---PAGE BREAK--- Eau de Javel Clorox® Date de révision Nouvelle Page 8 / 11 Nom chimique ACGIH CIRC NTP OSHA Hypochlorite de sodium 7681-52-9 - Groupe 3 - - CIRC (Centre international de recherche sur le cancer) Groupe 3 - Ne peut être classifié pour la cancérogénicité chez les humains Toxicité pour la reproduction Aucune information disponible. Toxicité pour certains organes cibles - exposition unique Aucune information disponible. Toxicité pour certains organes cibles - exposition répétée Aucune information disponible. Toxicité chronique Le potentiel cancérogène est inconnu. Effets sur les organes cibles Appareil respiratoire, yeux, peau, tractus gastro-intestinal (GI). Danger par aspiration Aucune information disponible. Valeurs numériques de la toxicité - Information sur le produit Les valeurs suivantes sont calculées selon le chapitre 3.1 du document SGH : 117,20 mg/l ETAmél (4 h) 12. DONNÉES ÉCOLOGIQUES Écotoxicité Très toxique pour les organismes aquatiques, entraîne des effets à long terme. Persistance et dégradation Aucune information disponible. Bioaccumulation Aucune information disponible. Autres effets nocifs Aucune information disponible. 13. DONNÉES SUR L’ÉLIMINATION DU PRODUIT Méthodes d’élimination Éliminer conformément à tous les règlements fédéraux, provinciaux et locaux. Récipients contaminés Ne pas réutiliser les récipients vides. Éliminer conformément à tous les règlements fédéraux, provinciaux et locaux. 14. INFORMATIONS RELATIVES AU TRANSPORT DOT NON RÉGLEMENTÉ TMD Numéro ONU UN3082 Désignation officielle de transport MATIÈRE DANGEREUSE DU POINT DE VUE DE L’ENVIRONNEMENT, LIQUIDE, N.S.A. Classe de danger 9 Groupe d’emballage III Description UN3082, MATIÈRE DANGEREUSE DU POINT DE VUE DE L’ENVIRONNEMENT, LIQUIDE, N.S.A. (HYPOCHLORITE DE SODIUM), 9, III, POLLUANT MARIN Page 292 of 1235 Page 292 of 1235 Page 292 of 1235 Page 292 of 1235 ---PAGE BREAK--- Eau de Javel Clorox® Date de révision Nouvelle Page 9 / 11 OACI : Numéro ONU UN3082 Désignation officielle de transport MATIÈRE DANGEREUSE DU POINT DE VUE DE L’ENVIRONNEMENT, LIQUIDE, N.S.A. Classe de danger 9 Groupe d’emballage III Description UN3082, MATIÈRE DANGEREUSE DU POINT DE VUE DE L’ENVIRONNEMENT, LIQUIDE, N.S.A. (HYPOCHLORITE DE SODIUM), 9, III IATA Numéro ONU UN3082 Désignation officielle de transport MATIÈRE DANGEREUSE DU POINT DE VUE DE L’ENVIRONNEMENT, LIQUIDE, N.S.A. Classe de danger 9 Groupe d’emballage III Description UN3082, MATIÈRE DANGEREUSE DU POINT DE VUE DE L’ENVIRONNEMENT, LIQUIDE, N.S.A. (HYPOCHLORITE DE SODIUM), 9, III IMDG/OMI Numéro ONU UN3082 Désignation officielle de transport MATIÈRE DANGEREUSE DU POINT DE VUE DE L’ENVIRONNEMENT, LIQUIDE, N.S.A. Classe de danger 9 Groupe d’emballage III EmS No F-A, S-F Polluant marin Le produit est un polluant marin selon les critères fixés par l’IMDG/OMI Description UN3082, MATIÈRE DANGEREUSE DU POINT DE VUE DE L’ENVIRONNEMENT, LIQUIDE, N.S.A. (HYPOCHLORITE DE SODIUM), 9, III, POLLUANT MARIN 15. INFORMATIONS SUR LA RÉGLEMENTATION Inventaire de produits chimiques TSCA Tous les composants de ce produit sont soit inscrits sur l’inventaire TSCA 8(b) ou sont exempts d’inscription. LIS/LES Tous les composants sont inclus dans la LIS ou la LES. TSCA - États-Unis - Section 8 de l’inventaire TSCA (loi réglementant les substances toxiques) LIS/LES – liste intérieure des substances/liste extérieure des substances pour le Canada ÉTATS-UNIS Règlements fédéraux SARA 313 Section 313 du titre III de la loi du Superfund Amendments and Reauthorization Act de 1986 (SARA). Ce produit ne contient aucun produit chimique soumis aux exigences en matière de rapport de la Loi et du titre 40 du Code of Federal Regulations, partie 372 SARA 311/312 Catégories de dangers Risque aigu pour la santé Oui Danger chronique pour la santé Non Risque d’incendie Non Danger de libération soudaine de pression Non Danger de réaction Non Loi sur la qualité de l’eau (Clean Water Act) Ce produit contient les substances suivantes qui sont des polluants réglementés conformément à la loi sur la qualité de l’eau (Clean Water Act) (40 CFR 122.21 et 40 CFR 122.42) Page 293 of 1235 Page 293 of 1235 Page 293 of 1235 Page 293 of 1235 ---PAGE BREAK--- Eau de Javel Clorox® Date de révision Nouvelle Page 10 / 11 Nom chimique CWA - quantités à déclarer CWA - polluants toxiques CWA - polluants prioritaires CWA - substances dangereuses Hypochlorite de sodium 7681-52-9 100 lb X Hydroxyde de sodium 1310-73-2 1000 lb X CERCLA Sous sa forme commerciale, ce produit contient une ou plusieurs substances réglementées comme une substance dangereuse en vertu de CERCLA (Comprehensive Environmental Response Compensation and Liability Act) (40 CFR 302) Nom chimique Quantités à déclarer de substances dangereuses Quantités à déclarer de substances très dangereuses Quantité à déclarer (QD) Hypochlorite de sodium 7681-52-9 100 lb - QD 100 lb QD finale QD 45,4 kg QD finale Hydroxyde de sodium 1310-73-2 1000 lb - QD 1000 lb QD finale QD 454 kg QD finale Page 294 of 1235 Page 294 of 1235 Page 294 of 1235 Page 294 of 1235 ---PAGE BREAK--- Eau de Javel Clorox® Date de révision Nouvelle Page 11 / 11 États-Unis - Réglementation des états Proposition 65 de la Californie Ce produit ne contient aucun produit chimique de la proposition 65. Règlement d’état sur le droit à l’information aux États-Unis Nom chimique New Jersey Massachusetts Rhode Island Illinois Hypochlorite de sodium 7681-52-9 X X X X Hydroxyde de sodium 1310-73-2 X X X X Règlements internationaux Canada Classe de dangers du SIMDUT D2B - Matières toxiques 16. AUTRES INFORMATIONS NFPA Danger pour la santé 2 Inflammabilité 0 Instabilité 0 Propriétés physiques et chimiques - HMIS Danger pour la santé 2 Inflammabilité 0 Danger physique 0 Protection individuelle B Préparée par Product Stewardship 23 British American Blvd. Latham, NY 12110 1 [PHONE REDACTED] Date de révision Nouvelle Note de révision Référence Nouvelle 1076851/173214.001 Avis de non-responsabilité général À notre connaissance et selon nos renseignements et notre opinion à la date de publication de cette fiche signalétique, les renseignements fournis dans cette dernière sont exacts. Les renseignements donnés sont conçus uniquement comme un guide pour la manipulation, l’utilisation, le traitement, l’entreposage, le transport, l’élimination et le rejet sécuritaires du produit et ne doivent pas être considérés comme une garantie ou une norme de qualité. Les renseignements sont liés uniquement au produit particulier indiqué et peuvent ne pas être valides pour un tel produit utilisé en association avec toute autre substance ou dans tout autre procédé, sauf si indiqué dans le texte. Fin de la fiche signalétique Page 295 of 1235 Page 295 of 1235 Page 295 of 1235 Page 295 of 1235 ---PAGE BREAK--- The Clorox Company 1221 Broadway Oakland, CA 94612 Tel. (510) 271-7000 Material Safety Data Sheet I Product: CLOROX REGULAR-BLEACH Description: CLEAR, LIGHT YELLOW LIQUID WITH A CHARACTERISTIC CHLORINE ODOR Other Designations Distributor Emergency Telephone Nos. Clorox Bleach EPA Reg. No. 5813-50 Clorox Sales Company 1221 Broadway Oakland, CA 94612 For Medical Emergencies call: (800) 446-1014 For Transportation Emergencies Chemtrec (800) 424-9300 II Health Hazard Data III Hazardous Ingredients DANGER: CORROSIVE. May cause severe irritation or damage to eyes and skin. Vapor or mist may irritate. Harmful if swallowed. Keep out of reach of children. Some clinical reports suggest a low potential for sensitization upon exaggerated exposure to sodium hypochlorite if skin damage irritation) occurs during exposure. Under normal consumer use conditions the likelihood of any adverse health effects are low. Medical conditions that may be aggravated by exposure to high concentrations of vapor or mist: heart conditions or chronic respiratory problems such as asthma, chronic bronchitis or obstructive lung disease. FIRST AID: Eye Contact: Hold eye open and rinse with water for 15-20 minutes. Remove contact lenses, after first 5 minutes. Continue rinsing eye. Call a physician. Skin Contact: Wash skin with water for 15-20 minutes. If irritation develops, call a physician. Ingestion: Do not induce vomiting. Drink a glassful of water. If irritation develops, call a physician. Do not give anything by mouth to an unconscious person. Inhalation: Remove to fresh air. If breathing is affected, call a physician. Ingredient Concentration Exposure Limit Sodium hypochlorite 6.15% Not established CAS# 7681-52-9 Sodium hydroxide 2 mg/m 3; 1 CAS# 1310-73-2 2 mg/m 3; 2 1ACGIH Threshold Limit Value (TLV) - Ceiling 2OHSA Permissible Exposure Limit (PEL) – Time Weighted Average (TWA) None of the ingredients in this product are on the IARC, NTP or OSHA carcinogen lists. IV Special Protection and Precautions V Transportation and Regulatory Data No special protection or precautions have been identified for using this product under directed consumer use conditions. The following recommendations are given for production facilities and for other conditions and situations where there is increased potential for accidental, large-scale or prolonged exposure. Hygienic Practices: Avoid contact with eyes, skin and clothing. Wash hands after direct contact. Do not wear product-contaminated clothing for prolonged periods. Engineering Controls: Use general ventilation to minimize exposure to vapor or mist. Personal Protective Equipment: Wear safety glasses. Use rubber or nitrile gloves if in contact liquid, especially for prolonged periods. KEEP OUT OF REACH OF CHILDREN DOT/IMDG/IATA - Not restricted. EPA - SARA TITLE III/CERCLA: Bottled product is not reportable under Sections 311/312 and contains no chemicals reportable under Section 313. This product does contain chemicals (sodium hydroxide <0.2% and sodium hypochlorite <7.35% ) that are regulated under Section 304/CERCLA. TSCA/DSL STATUS: All components of this product are on the U.S. TSCA Inventory and Canadian DSL. VI Spill Procedures/Waste Disposal VII Reactivity Data Spill Procedures: Control spill. Containerize liquid and use absorbents on residual liquid; dispose appropriately. Wash area and let dry. For spills of multiple products, responders should evaluate the MSDS’s of the products for incompatibility with sodium hypochlorite. Breathing protection should be worn in enclosed, and/or poorly ventilated areas until hazard assessment is complete. Waste Disposal: Dispose of in accordance with all applicable federal, state, and local regulations. Stable under normal use and storage conditions. Strong oxidizing agent. Reacts with other household chemicals such as toilet bowl cleaners, rust removers, vinegar, acids or ammonia containing products to produce hazardous gases, such as chlorine and other chlorinated species. Prolonged contact with metal may cause pitting or discoloration. VIII Fire and Explosion Data IX Physical Data Flash Point: None Special Firefighting Procedures: None Unusual Fire/Explosion Hazards: None. Not flammable or explosive. Product does not ignite when exposed to open flame. Boiling 212°F/100°C Specific Gravity (H20=1) ~ 1.1 at 70 oF Solubility in Water complete pH 1963, 1991 THE CLOROX COMPANY DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH DATE PREPARED 05/05 Page 296 of 1235 Page 296 of 1235 Page 296 of 1235 Page 296 of 1235 ---PAGE BREAK--- The Clorox Company 1221 Broadway Oakland, CA 94612 Tel. (510) 271-7000 Material Safety Data Sheet I Product: CLOROX REGULAR-BLEACH Description: CLEAR, LIGHT YELLOW LIQUID WITH A CHARACTERISTIC CHLORINE ODOR Other Designations Distributor Emergency Telephone Nos. Clorox Bleach EPA Reg. No. 5813-100 Clorox Sales Company 1221 Broadway Oakland, CA 94612 For Medical Emergencies call: (800) 446-1014 For Transportation Emergencies Chemtrec (800) 424-9300 II Health Hazard Data III Hazardous Ingredients DANGER: CORROSIVE. HARMFUL IF SWALLOWED. May cause severe irritation or damage to eyes, skin and mucous membranes. Wear rubber gloves. Vapors may irritate. Keep out of reach of children. Some clinical reports suggest a low potential for sensitization upon exaggerated exposure to sodium hypochlorite if skin damage irritation) occurs during exposure. Under normal consumer use conditions the likelihood of any adverse health effects are low. Medical conditions that may be aggravated by exposure to high concentrations of vapor or mist: heart conditions or chronic respiratory problems such as asthma, chronic bronchitis or obstructive lung disease. FIRST AID: Eye Contact: Immediately rinse with water for 15 minutes. Remove contact lenses, after first 5 minutes. Call a doctor. Skin Contact: Remove contaminated clothing and wash skin thoroughly with water. If irritation persists, call a doctor. Ingestion: DO NOT induce vomiting. Drink a glassful of water. Call a doctor or poison control center immediately. Do not try to give anything by mouth to an unconscious person. Inhalation: Remove to fresh air. If breathing is affected, call a physician. Ingredient Concentration Exposure Limit Sodium hypochlorite 5-15 % Not established CAS# 7681-52-9 Sodium hydroxide 0.1 - 1% 2 mg/m - TLV - C1 CAS# 1310-73-2 2 mg/m - PEL - TWA 2 1ACGIH Threshold Limit Value (TLV) - Ceiling 2OHSA Permissible Exposure Limit (PEL) – Time Weighted Average (TWA) None of the ingredients in this product are on the IARC, NTP or OSHA carcinogen lists. IV Special Protection and Precautions V Transportation and Regulatory Data No special protection or precautions have been identified for using this product under directed consumer use conditions. The following recommendations are given for production facilities and for other conditions and situations where there is increased potential for accidental, large-scale or prolonged exposure. Hygienic Practices: Avoid contact with eyes, skin and clothing. Wash hands after direct contact. Do not wear product-contaminated clothing for prolonged periods. Engineering Controls: Use general ventilation to minimize exposure to vapor or mist. Personal Protective Equipment: Wear safety goggles. Use rubber or nitrile gloves if in contact liquid, especially for prolonged periods. KEEP OUT OF REACH OF CHILDREN DOT: Consumer Commodity ORM-D. IATA: UN 1791, Hypochlorite solution, Class 8, PG III. IMDG: UN 1791, Hypochlorite solution, Class 8, PG III. EPA - SARA TITLE III/CERCLA: Bottled product is not reportable under Sections 311/312 and contains no chemicals reportable under Section 313. This product does contain chemicals (sodium hydroxide <0.2% and sodium hypochlorite <7.35%) that are regulated under Section 304/CERCLA. TSCA/DSL STATUS: All components of this product are on the U.S. TSCA Inventory and Canadian DSL. VI Spill Procedures/Waste Disposal VII Reactivity Data Spill Procedures: Control spill. Containerize liquid and use absorbents on residual liquid; dispose appropriately. Wash area and let dry. For spills of multiple products, responders should evaluate the MSDS’s of the products for incompatibility with sodium hypochlorite. Breathing protection should be worn in enclosed, and/or poorly ventilated areas until hazard assessment is complete. Waste Disposal: Dispose of in accordance with all applicable federal, state, and local regulations. Stable under normal use and storage conditions. Strong oxidizing agent. Reacts with other household chemicals such as toilet bowl cleaners, rust removers, vinegar, acids or ammonia containing products to produce hazardous gases, such as chlorine and other chlorinated species. Prolonged contact with metal may cause pitting or discoloration. VIII Fire and Explosion Data IX Physical Data Flash Point: None Special Firefighting Procedures: None Unusual Fire/Explosion Hazards: None. Not flammable or explosive. Product does not ignite when exposed to open flame. Boiling point approx. 212°F/100°C Specific Gravity (H20=1) ~ 1.1 at 70oF Solubility in Water complete pH ~11.9 1963, 1991 THE CLOROX COMPANY DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH DATE PREPARED 07/12 Page 297 of 1235 Page 297 of 1235 Page 297 of 1235 Page 297 of 1235 ---PAGE BREAK--- Page 298 of 1235 Page 298 of 1235 Page 298 of 1235 Page 298 of 1235 ---PAGE BREAK--- Page 299 of 1235 Page 299 of 1235 Page 299 of 1235 Page 299 of 1235 ---PAGE BREAK--- Page 300 of 1235 Page 300 of 1235 Page 300 of 1235 Page 300 of 1235 ---PAGE BREAK--- Page 301 of 1235 Page 301 of 1235 Page 301 of 1235 Page 301 of 1235 ---PAGE BREAK--- Page 302 of 1235 Page 302 of 1235 Page 302 of 1235 Page 302 of 1235 ---PAGE BREAK--- I. COMPANY IDENtIFICATION - CHEMICAL INFORMATION Cat Pumps Emergency Telephone Number [PHONE REDACTED] 1681 94th Lane NE Telephone Number for information [PHONE REDACTED] Minneapolis, Minnesota, 55449 Chemical Name & synonyms: Petroleum-based, hydraulic oil with advanced additive package to protect against wear, oxidation, rust and corrosion. Chemical Family: Petroleum hydrocarbon plus additives. Freight Class: 65 ii. Hazardous ingredients - identity information INGREDIENTS CAS# % OSHA OSHA ACGIH SKIN Severly refined mineral oils Mixture >90 5 mg/m3 10 mg/m3* 5 mg/m3 NO (PEL)* (TLV) Proprietary additives Mixture — — — NO Zinc dithiophosphate 68649-42-3 <0.5 — — — NO * Applicable to oil mist, not defined for base oils iii. physical data a. Boiling point >500°F (>260°C) f. Percent volatile by volume: Negligible b. Vapor pressure (mm Hg): Not determined. g. Evaporation rate: (n-Butyl Acetate=1) >1 c. Vapor density (Air = >1 h. Appearance and odor: Greenish fluid, mild petroleum odor d. Solubility in water Negligible i. Melting point: Liquid e. Specific gravity (H20 = 0.88@60°F (15.6°C) iv. fire and explosion hazard data a. Flash point: >300°F f. Unusual fire and explosion hazards: Empty containers can be b. Ignition temperature 730 estimated dangerous; do not cut, weld, solder, drill or grind—explosion c. Flammable limitation: LEL 0.9% UEL: 7% can result. d. Extinguishing media: Water Spray, Foam, Co2, Dry Chemicals g. HMIS Rating: Health - 1, Fire - 1, Reactivity - 0, Special Hazard - B e. Special fire fighting procedures: Use water spray to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors. Utilize air-supplied breathing equipment in confined or enclosed areas. V. Reactivity data a. Stability: Stable b. Incompatible materials: Strong oxidizing materials and acids. c. Hazardous Decomposition Products: May form oxides of carbon, sulfur, phosphorus and nitrogen if combusted. d. Hazardous Polymerization: Will not occur. e. Conditions to avoid: High temperature and product contamination. VI. Health hazard data Emergency and First Aid Procedures: a. Route(s) of Entry: Inhalation Not a problem at room temperature/avoid mist a. Eyes: Flush with clean, clear water until irritation subsides. If irritation Skin Avoid prolonged skin contact. persists, see a physician. Ingestion Possible b. Skin: Remove contaminated clothing, wash contaminated area b. Health Hazards (Acute and Chronic): Prolonged or repeated skin contact thoroughly with soap and water. If redness or irritation occurs, seek may cause irritation. Eye contact can cause discomfort. Ingestion can medical attention. cause gastrointestinal distress. c. Inhalation: If overcome by inhalation of hot vapors, remove to fresh c. Carcinogenicity: NTP No air. Seek immediate medical attention if necessary. IARC Monographs No e. Ingestion: Do not induce vomiting, contact a physician. OSHA Regulated No d. Medical Conditions: Generally Aggravated by Exposure: Product has a low order of toxicity. In normal use should not be harmful. VII. Precautions for safe handling and use a. Steps to be taken in case material is released or spilled: Contain spill c. Precautions to be taken in handling and storing: Keep containers with use of sorbent media. Keep spill from entering sewers or waterways. closed when not in use. Store in cool, dry area away from sources b. Waste disposal methods: Disposal must be in accordance with local, of ignition. state and federal regulations. d. Other precautions: Do not pressurize, weld, cut, solder, or drill empty drums. Fumes can be explosive. VIII. Control measures a. Respiratory Protection (Specify Type): Normally not needed. d. Eye Protection: Chemical goggles, splash shield. b. Ventilation: Local exhaust: Not Necessary e. Other Protective Clothing or Equipment: Oil resistant apron if desired. Mechanical (General): Recommended f. Work/Hygienic Practices: Launder contaminated clothing before re-use. Special: No Other: No Cleanse skin thoroughly after contact. Properly dispose of contaminated c. Protective Gloves: Oil resistant. leather articles and other materials which cannot be decontaminated. MATERIAL SAFETY DATA SHEET CRANKCASE OIL ISO 68 SPECIAL FORMULA PREMIUM GRADE CONFORMS WITH OSHA FORM OMB NO. 1218-0072 Date Prepared 12-01-2009 PN 993161 Rev G 12/09 11007 CAT PUMPS LTD. 1 Fleet Business Park, Sandy Lane, Church Crookham FLEET, Hampshire, GU52 8BF, England Phone Fleet 44 1252-622031 — Fax 44 1252-626655 e-mail: [EMAIL REDACTED] www.catpumps.co.uk N.V. CAT PUMPS INTERNATIONAL S.A. Heiveldekens 6A, B-2550 Kontich, Belgium Phone 32-3-450.71.50 — Fax 32-3-450.71.51 e-mail: [EMAIL REDACTED] www.catpumps.be CAT PUMPS GmbH Buchwiese 2, D-65510 Idstein, Germany Phone 49 6126-9303 0 — Fax 49 6126-9303 33 e-mail: [EMAIL REDACTED] www.catpumps.de World Headquarters CAT PUMPS 1681 - 94th Lane N.E. Minneapolis, MN 55449-4324 Phone (763) 780-5440 — FAX (763) 780-2958 e-mail: [EMAIL REDACTED] www.catpumps.com International Inquiries FAX (763) 785-4329 e-mail: [EMAIL REDACTED] The Pumps with Nine Lives “Original Instructions” Page 303 of 1235 Page 303 of 1235 Page 303 of 1235 Page 303 of 1235 ---PAGE BREAK--- Page 1 of 6 Safety Data Sheet Cat Pump Crankcase Oil ISO 68 Revision Date: 6/1/15 SECTION 1 CHEMICAL PRODUCT IDENTIFICATION Cat Pumps 1681 94th Lane NE., Minneapolis, MN 55449-4324 Tel: [PHONE REDACTED] Product Trade Name: Crankcase Oil ISO 68 Special Formula Premium Grade CAS Number: Mixture Synonyms/Other: N/A Part Number(s): N/A Recommended Use: Pump Oil Restrictions on Use: Not determined Created Date: 2/17/2015 Preparation/Revision Date: 6/1/2015 Emergency Phone Number: 1-[PHONE REDACTED] (CHEMTREC) SDS CODE: 10410 SECTION 2 HAZARD IDENTIFICATION Appearance: Clear, Dark Green Odor: Petroleum Classification: This material is not considered to be hazardous according to the Globally Harmonized System of Classification and Labelling Chemicals (GHS), Third Revised Edition. Target Organs: Not applicable. Pictogram(s): None required. Signal Word: None required. Hazard Statement: Not required. Other Hazards: Not determined. Prevention: None required. Response: None required. Storage Procedures: None required. Disposal: None required. Other: See section 11 for complete health hazard information. SECTION 3 COMPOSITION OF INGREDIENTS No Hazardous Substance(s) or Complex Substance(s) required for disclosure. SECTION 4 FIRST AID MEASURES Eye Contact: If irritation occurs, cautiously rinse eyes with lukewarm, gently flowing water for 5 minutes, while holding the eyelids open. If eye irritation persists: Get medical advice/attention. Skin Contact: Call a doctor if you feel unwell. Inhalation: Get medical advice or attention if you feel unwell or are concerned. Ingestion: If you feel unwell or concerned: Get medical advice/attention. Rinse mouth. Do NOT induce vomiting. If vomiting occurs naturally, lie on your side, in the recovery position. Other: No additional information Prepared according to Global Harmonized System (GHS) standards Page 304 of 1235 Page 304 of 1235 Page 304 of 1235 Page 304 of 1235 ---PAGE BREAK--- Page 2 of 6 SECTION 5 FIRE FIGHTING MEASURES Flash Point: 204°C by Cleveland Open Cup Tester. Flammable limits: Not determined. Extinguishing media: Use dry chemical, alcohol foam, all purpose AFFF or carbon dioxide to extinguish fire. Special firefighting procedures: DO NOT direct a solid stream of water or foam into hot, burning pools of liquid since this may cause frothing and increase fire intensity. Frothing can be violent and possibly endanger any firefighter standing too close to the burning liquid. Use water spray to cool fire exposed containers and structures until fire is out if it can be done with minimal risk. Avoid spreading burning material with water used for cooling purposes. Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). Unusual fire & explosion hazards: Dense smoke may be generated while burning. Toxic fumes, gases or vapors may evolve on burning. High temperatures may create heavy flammable vapors that may settle along ground level and low spots to create an invisible fire hazard. Byproducts of combustion: Fires involving this product may release oxides of carbon, phosphorus, nitrogen and sulfur; reactive hydrocarbons and irritating vapors. Autoignition temperature: Not determined. Explosion data: Not determined. Care should always be exercised in dust/mist areas. Other: Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. SECTION 6 ACCIDENTAL RELEASE MEASURES Spill control procedures (land): Immediately turn off or isolate any source of ignition (pilot lights, electrical equipment, flames, heaters, etc.). Evacuate area and ventilate. Personnel wearing proper protective equipment should contain spill immediately with inert materials (sand, earth, chemical spill pads of cotton) by forming dikes. Dikes should be placed to contain spill in a manner that will prevent material from entering sewers and waterways. Large spills, once contained, may be picked up using explosion proof, non-sparking vacuum pumps, shovels, or buckets, and disposed of in suitable containers for disposal. If a large spill occurs notify appropriate authorities. In case of road spill or accident contact ChemTrec (800-424- 9300). Spill control procedures (water): Try to contain large spills with floating booms to prevent spill from spreading. Remove from surface by skimming or with suitable adsorbents. If a large spill occurs notify appropriate authorities (normally the National Response Center or Coast Guard at 800- 424-8802). Waste disposal method: Do not empty into drains. All disposals must comply with federal, state, and local regulations. The material, if spilled or discarded may be a regulated waste. Refer to state and local regulations. Department of Transportation (DOT) regulations may apply for transporting this material when spilled. See Section 14. Other: CAUTION - If spilled material is cleaned up using a regulated solvent, the resulting waste mixture will be regulated. SECTION 7 HANDLING AND STORAGE Handling procedures: Keep containers closed when not in use. Do not transfer to unmarked containers. Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld, or use for any other purposes. Return drums to reclamation centers for proper cleaning and reuse. Handling temperatures should not exceed 60°C (140°F) to minimize danger of burns. Open containers carefully in a well ventilated area or use appropriate respiratory protection. Wash thoroughly after handling. Storage procedures: Store containers away from heat, sparks, open flame, or oxidizing materials. Extended storage at excessive temperatures may produce odorous and toxic fumes from product decomposition. Additional information: No additional information. Safety Data Sheet Cat Pump Crankcase Oil ISO 68 Revision Date: 6/1/15 Page 305 of 1235 Page 305 of 1235 Page 305 of 1235 Page 305 of 1235 ---PAGE BREAK--- Page 3 of 6 SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits/standards for materials that can be formed when handling this product: Contains highly refined petroleum oil OSHA TWA *5 mg/m³ (PEL) OSHA STEL *10 mg/m³ ACGIH TWA *5 mg/m³ (TLV) * Exposure limits not defined. Limits used are for, “oil mist”. TWA – Time Weighted Average is the employee’s average airborne exposure in any 8-hour work shift of a 40-hour work week which shall not be exceeded. STEL – Short Term Exposure Limit is the employee’s 15-minute time weighted average exposure which shall not be exceeded at any time during a work day unless another time limit is specified. All base oils, including additive carriers, contain <3.0% DMSO extractable material. Personal protection: Applicable mainly to persons in repeated contact situations such as packaging of product, service/maintenance, and cleanup/spill control personnel. Respiratory protection: None required if ventilation is adequate. Otherwise a respiratory protection program meeting OSHA 1910.134 and ANSI Z88.2 requirements must be followed. Where misting may occur, wear an MSHA/NIOSH approved (or equivalent) half-mask form dust/mist air purifying respirator. Eye protection: Eye protection is strongly recommended. Wear safety glasses with side shields or vented/splash proof goggles (ANSI Z87.1 or approved equivalent). Hand protection: Impervious, chemically resistant gloves such as neoprene or nitrile rubber to avoid skin sensitization and absorption. Other protection: Use of an apron and overboots of chemically impervious materials such as neoprene or nitrile rubber is recommended based on level of activity and exposure. If handling hot material use insulated protective equipment. Launder soiled clothes. Properly dispose of contaminated leather articles and other materials which cannot be decontaminated. Local control measures: Use adequate ventilation when working with material in an enclosed area. Mechanical methods such as fume hoods or area fans may be used to reduce localized vapor/mist areas. If vapor or mist is generated when the material is handled, adequate ventilation in accordance with good engineering practice must be provided to maintain concentrations below the specified exposure. Eyewash stations and showers should be available in areas where this material is used and stored. Other: Consumption of food and drink should be avoided in work areas where product is present. Always wash hands and face with soap and water before eating, drinking or smoking. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear, Dark Green Odor: Petroleum. Odor threshold: Not determined. pH: Not applicable. Melting/Freezing point: Not determined. Initial boiling point: Not determined. Boiling range: Not determined. Flash point: 204°C. Evaporation rate: Not determined. Flammability: Not determined. Upper flammable limit: Not determined. Lower flammable limit: Not determined. Vapor pressure: Not determined. Vapor density: Not determined. Relative density: 0.88 at 60°F Solubility: Negligible in water, miscible in most petroleum solvents. Partition Coefficient: Not determined. Safety Data Sheet Cat Pump Crankcase Oil ISO 68 Revision Date: 6/1/15 Page 306 of 1235 Page 306 of 1235 Page 306 of 1235 Page 306 of 1235 ---PAGE BREAK--- Page 4 of 6 SECTION 9 continued PHYSICAL AND CHEMICAL PROPERTIES Auto-ignition temperature: Not determined. Decomposition temperature: Not determined. Viscosity: 68 cSt at 40°C. Other Not applicable. SECTION 10 STABILITY AND REACTIVITY Reactivity Chemical stability: Material is chemically stable at room temperatures and pressure. Hazardous polymerization: Will not occur. Conditions to avoid: Avoid high temperatures and product contamination. Incompatibility with other materials: Avoid contact with acids and strong oxidizing materials. Decomposition products: Smoke, carbon monoxide, carbon dioxide, and other aldehydes of incomplete combustion. Oxides of carbon, nitrogen, and sulfur; reactive hydrocarbons and irritating vapors. Other: Not applicable. SECTION 11 TOXICOLOGICAL INFORMATION Acute toxicity (LD50) *See note at the bottom of the section Oral: >5000 mg/kg Dermal: >5000 mg/kg Inhalation: >20.0 mg/l Skin irritation: Non-irritant Eye irritation: Non-irritant Dermal sensitization: Not expected to have a sensitizing effect. Respiratory sensitization: Not expected to have a sensitizing effect. Aspiration Hazard: Not applicable Chronic Toxicity Mutagenicity: Not suspected of causing genetic defects Carcinogenicity: Not suspected of causing cancer. Reproductive toxicity: Not expected to have adverse effects on reproduction. STOT-single exposure: Not expected to have adverse effects. STOT-repeated exposure: Not expected to have long term adverse effects. Other: *All data in this section is based off calculations from Part 3 of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS) utilizing information from the constituent components. SECTION 12 ECOLOGICAL INFORMATION Environmental toxicity Fish: > 100 mg/l. Invertebrates: > 100 mg/l. Aquatic plants: > 100 mg/l. Microorganism: > 100 mg/l. Persistence/Degradability: This product is not expected to be readily biodegradable. Bioaccumulation: Not determined. Mobility in soil: Not determined. Other: All classifications are based on calculations in Part 4 of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS) utilizing information from the constituent components. Safety Data Sheet Cat Pump Crankcase Oil ISO 68 Revision Date: 6/1/15 Page 307 of 1235 Page 307 of 1235 Page 307 of 1235 Page 307 of 1235 ---PAGE BREAK--- Page 5 of 6 SECTION 13 DISPOSAL CONSIDERATIONS Waste disposal: This product unadulterated by other materials can be classified as a non-hazardous waste. Depending on use, used product may be regulated. Dispose of in a licensed facility. Do not discharge product in to sewer system. Dispose of containers by crushing or puncturing, so as to prevent unauthorized use of used containers. Waste management should be in full compliance with federal, state, and local laws. Other The transportation, storage, treatment and disposal of RCRA waste material must be conducted in compliance with 40 CFR 262, 263, 264, 268 and 270. Chemical additions, processing or otherwise altering this material may make the waste management information presented in this SDS incomplete, inaccurate or otherwise inappropriate. SECTION 14 TRANSPORT INFORMATION Land Transport (DOT): Not Regulated. Proper Shipping Name: Not Applicable. Land Transport (TDG): Not Regulated. Proper Shipping Name: Not Applicable. Sea Transport (IMDG): Not Regulated. Proper Shipping Name: Not Applicable. Air Transport (IATA): Not Regulated. Proper Shipping Name: Not Applicable. Other: Not Applicable. SECTION 15 REGULATORY INFORMATION Federal Regulation WHMIS: Not Controlled. Clean water act/oil: Under Section 311 of the Clean Water Act (40 CFR 110) and the Oil Pollution Control Act of 1990, this material is considered an oil. Any spill or discharges that produce a visible sheen or film on surface of water, or in waterways, ditches, or sewers leading to surface water must be reported. Contact the National Response Center at [PHONE REDACTED]. TSCA: All components of this material are listed in the U.S. TSCA Inventory. Other TSCA: Not applicable. SARA title III: Section 302/304 extremely hazardous substances: None Section 311, 312 hazard categorization: Acute (immediate health effects): NO Chronic (delayed health effects): NO Fire (hazard): NO Reactivity (hazard): NO Pressure ( sudden release hazard): NO Section 313 toxic chemicals: No components present are at or greater than the de minimis (minimum reportable) concentration requirements for reporting. CERCLA: For stationary/moving sources – reportable quantity (due to): Not hazardous due to the petroleum exclusion. State Regulations Right-to-know Not determined. Other: A release of this product, as supplied, is exempt from reporting under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA). However, releases may be reportable to the Nation Response Center under the Clean Water Act, 33 U.S.C. 1321(b)(3) and - see head of Section 15. Failure to report may result in substantial civil and criminal penalties. Recommend contacting the local authorities in the event of any type of spill to determine local reporting requirements and also to aid in the cleanup. Safety Data Sheet Cat Pump Crankcase Oil ISO 68 Revision Date: 6/1/15 Page 308 of 1235 Page 308 of 1235 Page 308 of 1235 Page 308 of 1235 ---PAGE BREAK--- SECTION 16 OTHER INFORMATION NFPA 704 NPCA-HMIS KEY HEALTH: 1 1 0 = Minimal FIRE: 1 1 1 = Slight REACTIVITY: 0 0 2 = Moderate SPECIFIC HAZARD: None N/A 3 = Serious PROTECTION INDEX: N/A B 4 = Severe Version: I INFORMATION PROVIDED IN THIS SDS IS CONSIDERED ACCURATE AND RELIABLE BASED ON INFORMATION ISSUED FROM INTERNAL AND OUTSIDE SOURCES TO THE BEST OF THE AUTHORS’ KNOWLEDGE. HOWEVER, THE AUTHOR’S MAKE NO REPRESENTATIONS, GUARANTEES OR WARRANTIES, EXPRESSED OR IMPLIED, OF MERCHANTABILITY OR FITNESS FOR THE PARTICULAR PURPOSE, REGARDING THE ACCURACY OF SUCH INFORMATION OR THE RESULT TO BE OBTAINED FROM THE USE THEREOF, OR AS TO THE SUFFICIENCY OF THE INFORMATION HEREIN PRESENTED. THE AUTHORS ASSUME NO RESPONSIBILITY FOR INJURY TO RECIPIENT OR TO THIRD PERSONS OR FOR ANY DAMAGE TO ANY PROPERTY AND RECIPIENT ASSUMES ALL SUCH RISKS. Revisions / Comments: None CAT PUMPS 1681 - 94TH LANE N.E. MINNEAPOLIS, MN 55449-4324 PHONE (763) 780-5440 — FAX (763) 780-2958 e-mail: [EMAIL REDACTED] www.catpumps.com PN 993161 Rev J 7/15 Safety Data Sheet Cat Pump Crankcase Oil ISO 68 Revision Date: 6/1/15 Page 309 of 1235 Page 309 of 1235 Page 309 of 1235 Page 309 of 1235 ---PAGE BREAK--- Company Information Revision Date: June 30, 2011 Cat Pumps 1681 94th Lane Northeast Minneapolis, MN 55449 Includes Cat Pumps Part Numbers: 6100, 6102, 6105, 6107, and 6109 Electronic MSDS Copy: www.catpumps.com Emergency: [PHONE REDACTED] Information: [PHONE REDACTED] Composition Information Ingredients Severely refined mineral oils Proprietary additives Zinc dithiophosphate CAS # Mixture Mixture 68649-42-3 % >90 <0.5 OSHA TWA 5 mg/m3 (PEL)* OSHA STEL 10 mg/m3* ACGIH TWA 5 mg/m3 (TLV) SKIN No No No Comments Applicable to oil mist, not defined for base oils. TWA – Time Weighted Average is the employee’s average airborne exposure in any 8-hour work shift of a 40-hour work week which shall not be exceeded. STEL – Short Term Exposure Limit is the employee’s 15-minute time weighted average exposure which shall not be exceeded at any time during a work day unless another time limit is specified. Hazardous Identification Warning MAY CAUSE EYE IRRITATION, MAY CAUSE SKIN IRRITATION Eye Contact Direct contact may cause irritation, redness, tearing and blurred vision. Skin Contact Avoid prolonged skin contact. This product contains materials that may cause skin irritation. Prolonged or repeated contact may result in dermatitis (dryness, chapping, and reddening of skin). Inhalation Overexposure by inhalation of hot material may cause nonspecific discomfort, such as nausea, headache or weakness. Caution should be taken to prevent aerosolization or misting of this product without proper respiratory protection. Ingestion Do not ingest. Product is expected to be relatively non-toxic unless lung aspiration occurs. Aspiration is not expected with this material due to viscosity. Should aspiration occur, it may lead to chemical pneumonitis which is characterized by pulmonary edema and hemorrhage and may be fatal. Signs of lung involvement include increased respiratory rate, increased heart rate, and a bluish discoloration of the skin. Coughing, choking and gagging are often noted at the time of aspiration. This product has laxative properties and may result in abdominal cramps and diarrhea. Other Not applicable First Aid Measures Eye Contact Check for and remove contact lenses. Flush eyes with cool, clean, low-pressure water for at least 15 minutes. Hold eyelids apart to ensure complete irrigation of the eye and eyelid tissue. If irritation persists seek medical attention. If material is hot, treat for thermal burns and take victim to hospital immediately. Skin Contact Remove contaminated clothing. Wash contaminated area thoroughly with soap and water. If redness or irritation occurs, seek medical attention. If material is hot, submerge injured area in cold water. If victim is severely burned, remove to a hospital immediately. Wash contaminated clothing before reuse. Inhalation If overcome by inhalation of hot vapors, remove to fresh air. Use oxygen if there is difficulty breathing or artificial respiration if breathing has stopped. Do not leave victim unattended. Seek immediate medical attention if necessary. Ingestion Do not induce vomiting unless directed by a physician. During vomiting there is a danger of aspirating liquid into lungs, causing serious damage and chemical pneumonitis. If spontaneous vomiting occurs keep head below hips to prevent aspiration and monitor for breathing difficulty. Gastric lavage should be performed only by qualified medical personnel. Keep affected person warm and at rest. Seek immediate medical attention. Other Not applicable Fire Fighting Measures Flash point 204°C (400°F) by ASTM D 92 Flammable limits Not determined Extinguishing media Use water spray, dry chemical, alcohol foam, all purpose AFFF or carbon dioxide to extinguish fire. Special firefighting procedures Evacuate area and fight fire from a safe distance. If leak or spill has not ignited, ventilate area and use water spray to disperse gas or vapor and to protect personnel attempting to stop a leak. Use water spray to cool adjacent structures and to protect personnel. Shut off source of flow if possible (safely). Stay away from storage tank ends. Withdraw immediately in case of rising sound from venting safety device or any discoloration of storage tank due to fire. Fire fighters must wear MSHA/NIOSH approved positive pressure breathing apparatus (SCBA) with full face mask and full protective equipment. Unusual fire & explosion hazards Dense smoke may be generated while burning. Toxic fumes, gases or vapors may evolve on burning. High temperatures may create heavy flammable vapors that may settle along ground level and low spots to create an invisible fire hazard. Byproducts of combustion Fires involving this product may release oxides of carbon, phosphorus, nitrogen and sulfur; reactive hydrocarbons and irritating vapors. Auto ignition temperature Not determined Explosion data Not determined. Car should always be exercised in dust/mist areas. Other Not applicable Material Safety Data Sheet Crankcase Oil ISO 68 Special Formula Premium Grade Page 310 of 1235 Page 310 of 1235 Page 310 of 1235 Page 310 of 1235 ---PAGE BREAK--- Accidental Release Measures Spill control procedures (land) Immediately turn off or isolate any source of ignition (pilot lights, electrical equipment, flames, heaters, etc.). Evacuate area and ventilate. Personnel wearing proper protective equipment should contain spill immediately with inert materials (sand, earth, chemical spill pads of cotton) by forming dikes. Dikes should be placed to contain spill in a manner that will prevent material from entering sewers and waterways. Large spill, once contained, may be picked up using explosion proof, non-sparking vacuum pumps, shovels, or buckets, and disposed of in suitable containers for disposal. If a large spill occurs notify appropriate authorities. In case of road spill or accident contact Chem-Trec ([PHONE REDACTED]). Spill control procedures (water) Try to contain large spills with floating booms to prevent spill from spreading. Remove from surface by skimming or with suitable adsorbents. If a large spill occurs notify appropriate authorities (normally the National Response Center or Coast Guard at [PHONE REDACTED]). Waste disposal method Most oil based products are incinerated, land-filled or reclaimed. All disposals must comply with federal, state, and local regulations. The material, if spilled or discarded may be a regulated waste. Refer to state and local regulations. Department of Transportation (DOT) regulations may apply for transporting this material when spilled. See “Transport” section. Other CAUTION - If spilled material is cleaned up using a regulated solvent, the resulting waste mixture will be regulated. Handling and Storage Handling procedures Keep containers closed when not in use. Do not transfer to unmarked containers. Fire extinguishers should be kept readily available. See NFPA 30 and OSHA 1910.106 Flammable and Combustible Liquids. Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld, or use for any other purposes. Return drums to reclamation centers for proper cleaning and reuse. Handling temperatures should not exceed 60°C (140°F) to minimize danger of burns. Open containers carefully in a well ventilated area or use appropriate respiratory protection. Wash thoroughly after handling. Storage procedures Store containers away from heat, sparks, open flame, or oxidizing materials. Product should not be stored above 45°C (113°F). Extended storage at excessive temperatures may produce odorous and toxic fumes from product decomposition. Additional Information No additional information Exposure Controls & Personal Protection Personal protection Applicable mainly to persons in repeated contact situations such as packaging of product, service/ maintenance, and cleanup/spill control personnel. Respiratory protection None required if airborne concentrations are maintained below threshold limits listed on page one. Otherwise a respiratory protection program meeting OSHA 1910.134 and ANSI Z88.2 requirements must be followed. Where misting may occur, wear an MSHA/NIOSH approved (or equivalent) half-mask form dust/mist air purifying respirator. Eye protection Eye protection is strongly recommended. If material is handled such that it could be splashed into the eyes, wear safety glasses with side shields or vented/splash proof goggles (ANSI Z87.1 or approved equivalent). Hand protection Impervious gloves such as neoprene or nitrile rubber to avoid skin sensitization and absorption. Other protection Use of an apron and over-boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to avoid skin sensitization and absorption. If handling hot material use insulated protective equipment. Launder soiled clothes. Properly dispose of contaminated leather articles and other materials which cannot be decontaminated. Local control measures Use adequate ventilation when working with material in an enclosed area. Mechanical methods such as fume hoods or area fans may be used to reduce localized vapor/mist areas. If vapor or mist is generated when the material handled, adequate ventilation in accordance with good engineering practice must be provided to maintain concentrations below the specified exposure. Eyewash stations and showers should be available in areas where this material is used and stored. Other Consumption of food and drink should be avoided in work areas where product is present. Always wash hands and face with soap and water before eating, drinking or smoking. Physical and Chemical Properties Vapor pressure Not determined API gravity 29.4° at 15.6°C (60.0°F) Density 7.32 lbs/gal at 15.6°C (60.0°F) Specific gravity 0.88 at 15.6°C (60.0°F) Solubility Negligible in water, miscible in most petroleum solvents. Percent volatile Negligible Vapor density (air = 1) >1 Evaporation rate (n-Butyl Acetate = 1) Negligible Odor Mild, oil odor Appearance Un-dyed material is amber in color. Normally dyed green. Fluid. Viscosity 68.0 cSt at 40°C (104°F) Boiling point >260°C (>500°F) Pour/freeze point -40°C (-40°F) Other Not applicable Material Safety Data Sheet Crankcase Oil ISO 68 Special Formula Premium Grade Page 311 of 1235 Page 311 of 1235 Page 311 of 1235 Page 311 of 1235 ---PAGE BREAK--- Stability and Reactivity Stability Material is stable at room temperatures and pressure. Conditions to avoid Avoid high temperatures and product contamination. Incompatibility with other materials Avoid contact with acids and oxidizing materials. Decomposition products Smoke, carbon monoxide and dioxide, and other aldehydes of incomplete combustion. Oxides of carbon, phosphorus, nitrogen and sulfur; reactive hydrocarbons and irritating vapors. Hazardous polymerization Will not occur Other Not applicable Toxicological Information Oral toxicity Not determined Dermal toxicity Not determined Inhalation toxicity On rare occasions, prolonged and repeated exposure to oil mist poses a risk of pulmonary disease such as chronic lung inflammation. This condition is usually as a result of repeated small aspirations. Shortness of breath and cough are the most common Based on data from similar materials. Dermal sensitization Prolonged or repeated contact may make skin more sensitive to other skin sensitizers. Based on data from similar materials. Chronic toxicity Not determined Carcinogenicity The known components of this material are not listed by IARC, NTP, OSHA or ACGIH has known or suspected carcinogens. Mutagenicity Not determined Reproductive toxicity Not determined Other This product contains petroleum base oils which may be refined by various processes including severe solvent extraction, severe hydro-cracking, or severe hydro treating. None of the oils require a cancer warning under the OSHA Hazard Communication Standard (29 CFR 1910.1200). These oils have not been listed in the National Toxicology Program (NTP) Annual Report nor have they been classified by the International Agency for Research on Cancer (IARC) as; carcinogenic to humans (Group probably carcinogenic to humans (Group 2A), or possibly carcinogenic to humans (Group 2B). Ecological Information Environmental toxicity This material may be toxic to aquatic organisms and should be kept out of sewage and drainage systems and all bodies of water. Environmental fate Not determined Other Not applicable Disposal Considerations Waste disposal Under RCRA it is the responsibility of the user of the product to determine at the time of disposal whether the product meets RCRA criteria for hazardous waste. This product unadulterated by other materials may be classified as a non-regulated waste in some areas - but still needs to be disposed of at approved facilities. Waste management should be in full compliance with federal, state, and local laws. Disposal consideration Most used and non-use oils are incinerated by licensed burner facilities for heat value, or reclaimed by oil recycling services. Look in a local telephone directory or internet for headings under, ‘Waste’, ‘Waste Services’, ‘Waste Disposal’ for companies licensed to handle such material. Additional information can be obtained from local EPA, DNR, Sewer and Land-Fill sites. Unused, packaged fluids may be donated to other companies or charities (fluids MUST be unused). Other The transportation, storage, treatment and disposal of RCRA waste material must be conducted in compliance with 40 CFR 262, 263, 264, 268 and 270. Disposal can only occur in properly permitted facilities. Check state and local regulations for any additional requirements as these may be more restrictive than federal laws and regulations. Chemical additions, processing or otherwise altering this material may make the waste management information presented in this MSDS incomplete, inaccurate or otherwise inappropriate. Disposal of this material must be conducted in compliance with all federal, state, and local regulations. Transport Information U.S. DOT shipping description Not regulated U.S. DOT identification number Not regulated U.S. DOT hazard classification Not applicable Packaging class Not applicable Other Not applicable Material Safety Data Sheet Crankcase Oil ISO 68 Special Formula Premium Grade Page 312 of 1235 Page 312 of 1235 Page 312 of 1235 Page 312 of 1235 ---PAGE BREAK--- Regulatory Information Clean water act/oil pollution act Under Section 311 of the Clean Water Act (40 CFR 110) and the Oil Pollution Control Act of 1990, this material is considered an oil. Any spill or discharges that produce a visible sheen or film on surface of water, or in waterways, ditches, or sewers leading to surface water must be reported. Contact the National Response Center at [PHONE REDACTED]. This material contains zinc, a Clean Water Act Priority Pollutant. TSCA All components of this material are listed in the U.S. TSCA Inventory. Other TSCA Not applicable SARA Title III Section 302/304 extremely hazardous substances: None. Section 311, 312 hazard categorization: · Acute (immediate health effects): NO · Chronic (delayed health effects): NO · Fire (hazard): NO · Reactivity (hazard): NO · Pressure (sudden release hazard): NO Section 313 toxic chemicals: Zinc dithiophosphate (68649-42-3) at <0.5% wt. CERCLA For stationary/moving sources – reportable quantity (due to): Exempt due to petroleum exclusion. Other A release of this product, as supplied, is exempt from reporting under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) by the petroleum exclusion. However, releases may be reportable to the Nation Response Center under the Clean Water Act, 33 U.S.C. 1321(b) and - see head of Section 15. Failure to report may result in substantial civil and criminal penalties. Recommend contacting the local authorities in the event of any type of spill to determine local reporting requirements and also to aid in the cleanup. Other Information NFPA 704 NPCA – HMIS Key Health 1 1 0 = minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe Fire 1 1 Reactivity 0 0 Specific hazard None N/A Protection index N/A B Precautionary labels MAY CAUSE EYE IRRITATION. MAY CAUSE SKIN IRRITATION External information This product may be formulated in part with components purchased from other companies. In many instances, especially when proprietary or trade secret materials are used. Diversified Dynamics must rely on information provided by those materials manufacturers or distributors. Creation date March 21, 2000 File Diversified Dynamics Special Cat Pump Oil 68 Version V CAT PUMPS 1681 - 94TH LANE N.E. MINNEAPOLIS, MN 55449-4324 PHONE (763) 780-5440 — FAX (763) 780-2958 e-mail: [EMAIL REDACTED] www.catpumps.com For International Inquiries go to www.catpumps.com and navigate to the “Contact Us” link. PN 993161 Rev H 7/11 61112 INFORMATION PROVIDED IN THIS MSDS IS CONSIDERED ACCURATE AND RELIABLE BASED ON INFORMATION ISSUED FROM INTERNAL AND OUTSIDE SOURCES TO THE BEST OF CAT PUMPS KNOWLEDGE. HOWEVER, CAT PUMPS MAKES NO REPRESENTATIONS, GUARANTEES OR WARRANTIES, EXPRESSED OR IMPLIED, OF MERCHANTABILITY OR FITNESS FOR THE PARTICULAR PURPOSE, REGARDING THE ACCURACY OF SUCH INFORMATION OR THE RESULT TO BE OBTAINED FROM THE USE THEREOF, OR AS TO THE SUFFICIENCY OF THE INFORMATION HEREIN PRESENTED. CAT PUMPS ASSUMES NO RESPONSIBILITY FOR INJURY TO RECIPIENT OR TO THIRD PERSONS OR FOR ANY DAMAGE TO ANY PROPERTY AND RECIPIENT ASSUMES ALL SUCH RISKS. Material Safety Data Sheet Crankcase Oil ISO 68 Special Formula Premium Grade Page 313 of 1235 Page 313 of 1235 Page 313 of 1235 Page 313 of 1235 ---PAGE BREAK--- Page 1 of 4 Procter & Gamble P&G Household Care Ivorydale Technical Center 5299 Spring Grove Avenue Cincinnati, OH 45217-1087 MATERIAL SAFETY DATA SHEET MSDS FH/L/2005/RWRB-6FLJW3 Issue Date: 09/08/05 Supersedes: LDL 0006 Issue Date: 09/25/03 SECTION I - CHEMICAL PRODUCT Identity: Liquid Hand Dishwashing Detergents Brands: DAWN (All Variations) IVORY (All Variations) JOY (All Variations) SALVO Hazard Rating: Health: 1 4=EXTREME Flammability: 1 3=HIGH Reactivity: 0 2= MODERATE 1=SLIGHT Emergency Telephone Number: DAWN 1-[PHONE REDACTED] (DAWN) IVORY 1-[PHONE REDACTED] (IVORY) JOY 1-[PHONE REDACTED] (JOY) SALVO 1-[PHONE REDACTED] or call Local Poison Control Center or your physician SECTION II - COMPOSITION AND INGREDIENTS Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200. Chemical Name Common Name CAS No. Recommended Limits Composition Range LD50/LC50 Ethyl alcohol Ethanol 64-17-5 ACGIH TLV: 1880 mg/m3 1-6% Page 314 of 1235 Page 314 of 1235 Page 314 of 1235 Page 314 of 1235 ---PAGE BREAK--- 2 Liquid Hand Dishwashing Detergents (Continued) Page 2 of 4 SECTION III - HAZARDS IDENTIFICATION Health Hazards (Acute and Chronic): Ingestions: Ingestion may cause transient gastrointestinal irritation. Eye Contact: May cause mild, transient irritation. Skin: Transient irritation with prolonged exposure to concentrated material. Signs and of Exposure: Ingestion: May result in nausea, vomiting, and/or diarrhea. Eye Contact: May cause stinging, tearing, itching, swelling, and/or redness. Skin: Prolonged contact with concentrated material may be drying or transiently irritating to skin. SECTION IV - FIRST AID INFORMATION Emergency and First Aid Procedures: Ingestion: Drink 1 or 2 glasses of water. Eye Contact: Flush thoroughly with water for 15 minutes. Skin: If prolonged contact occurs, rinse thoroughly with water. If spilled on clothing, change clothes. If persist or recur, seek medical attention. Other: Consumer product package has a voluntary avoid accidents statement. SECTION V - FIRE FIGHTING INFORMATION Flash Point (Method Used): 115-135°F. Pensky- Martens (Closed cup) Explosive Limits: LEL: N/A UEL: N/A Extinguishing Media: CO2, water or dry chemical. Special Fire Fighting Procedures: None. Although this product has a flash point below 200°F (closed cup), it is a >50% aqueous solution that does not sustain combustion. DOT classification is non-hazardous. Unusual Fire Hazards: None Stability Unstable: Stable: X Conditions to Avoid: None known Incompatibility (Materials to Avoid): None known Hazardous Decomposition/By Products: None known Hazardous Polymerization: May Occur: Will Not Occur: X Conditions to Avoid: None known SECTION VI - ACCIDENTAL RELEASE MEASURES Personal Precautions: None Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL REGULATIONS. Solutions of the detergents may be allowed to be flushed down sewer First check with your local water treatment plant. Recycling is recommended for undiluted scrap product. Do not landfill. Steps To Be Taken in Case Material is Released or Spilled: Prevent spills from reaching a waterway. Sorbents may be used. Read “Waste Disposal Method” below for further information. Page 315 of 1235 Page 315 of 1235 Page 315 of 1235 Page 315 of 1235 ---PAGE BREAK--- 3 Liquid Hand Dishwashing Detergents (Continued) Page 3 of 4 SECTION VII - HANDLING AND STORAGE Precautions To Be Taken in Handling and Storing: No unusual precautions necessary. Other Precautions: None known SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION Respiratory Protection (Specify Type): None required with normal use. Ventilation Local Exhaust: None required with normal consumer use. Special: None Mechanical (General): Normal/general dilution ventilation is acceptable. Other: None Eye Protection: None required with normal consumer use. Industrial Setting: For splash protection, use chemical goggles. Eye Wash fountain is desirable. Protective Gloves: None required with normal use. Industrial Setting: Protective gloves (rubber, neoprene) should be used for prolonged direct contact. Other Protective Equipment: None required with normal use. SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES Boiling Point Not known Specific Gravity (H2O=1): ca. 1 Vapor Pressure (mm Hg): N/A Percent Volatile by Volume ~60-65% Vapor Density (Air=1): N/A Evaporation Rate (nBuOAc=1): Unknown Odor Threshold: N/A Freezing Point: ~ 30 F Coefficient of Water/Oil Distribution: N/A pH: 8-9 Scooped Density: N/A Solubility in Water: Completely Appearance and Odor: Purple, Blue, Green, Yellow, Pink or Orange liquids. All products are perfumed. Reserve Alkalinity: N/A SECTION X - STABILITY AND REACTIVITY Possible Hazardous Reactions/Conditions: None known Conditions to Avoid: None Materials to Avoid: None Hazardous Decomposition Products: None known Other Recommendations: None SECTION XI - TOXICOLOGICAL INFORMATION LD50 (rats oral): approx 12 mL/kg ED50 approx 2.3 mL/kg Liquid hand dishwashing detergents have a relatively low order of toxicity. They may be irritating, but they are not expected to be corrosive. They are expected to be emetic. Page 316 of 1235 Page 316 of 1235 Page 316 of 1235 Page 316 of 1235 ---PAGE BREAK--- 4 Liquid Hand Dishwashing Detergents (Continued) Page 4 of 4 SECTION XII - ECOLOGICAL INFORMATION All surfactants are readily biodegradable. These products are safe for septic tanks. SECTION XIII - DISPOSAL CONSIDERATIONS Waste Disposal Method: Disposal is to be performed in compliance with Federal, state and local regulations. Household product is safe for disposal down the drain during use or in the trash. Industrial Setting: Solutions of diluted detergent in the course of use, may be allowed to be flushed down sewer. First check with your local water treatment plant. Recycling is recommended for undiluted scrap product. Do not landfill. SECTION XIV - TRANSPORT INFORMATION Non-hazardous under DOT. SECTION XV - ADDITIONAL REGULATORY INFORMATION All components are listed on the US TSCA Inventory. No components are affected by Significant New Use Rules (SNURs) under TSCA No components of Dawn, Ivory, Joy or Salvo are subject to California Proposition 65 labeling. All ingredients are CEPA approved for import to Canada by Procter & Gamble only. SECTION XVI - OTHER INFORMATION *N/A. - Not Applicable *N/K. - Not Known The submission of this MSDS may be required by law, but this is not an assertion that the substance is hazardous when used in accordance with proper safety practices and normal handling procedures. Data supplied is for use only in connection with occupational safety and health. The information contained herein has been compiled from sources considered by Procter & Gamble to be dependable and is accurate to the best of the Company’s knowledge. The information relates to the specific material designated herein, and does not relate to the use in combination with any other material or any other process. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, for any damage to any property resulting from misuse of the controlled product. Page 317 of 1235 Page 317 of 1235 Page 317 of 1235 Page 317 of 1235 ---PAGE BREAK--- Page 1 of 4 Procter & Gamble Fabric and Home Care Division Ivorydale Technical Center 5299 Spring Grove Avenue Cincinnati, OH 45217-1087 MATERIAL SAFETY DATA SHEET MSDS LDL 0006 Issue Date: 09/25/03 Supersedes: LDL 0005 Issue Date: 02/10/03 SECTION I - CHEMICAL PRODUCT Identity: Liquid Hand Dishwashing Detergents Brands: DAWN (All Variations) IVORY (All Variations) JOY (All Variations) SALVO Hazard Rating: Health: 1 4=EXTREME Flammability: 1 3=HIGH Reactivity: 0 2= MODERATE 1=SLIGHT Emergency Telephone Number: 24hr P&G Operator: DAWN 1-[PHONE REDACTED] (DAWN) IVORY 1-[PHONE REDACTED] (IVORY) JOY 1-[PHONE REDACTED] (JOY) SALVO 1-[PHONE REDACTED] or call Local Poison Control Center or your physician Chemical Name Common Name CAS No. Recommended Limits Composition Range Ethyl alcohol Ethanol 64-17-5 ACGIH TLV: 1880 mg/m3 1-6% Subtilisin Protease 9014-01-1 NIOSH STEL 0.00006 mg/m3 <0.01% Amylase Amylase 9000-90-2 NIOSH STEL 0.00006 mg/m3 <0.01% Page 318 of 1235 Page 318 of 1235 Page 318 of 1235 Page 318 of 1235 ---PAGE BREAK--- LIQUID HAND DISHWASHING DETERGENTS MSDS (Continued) Page 2 of 4 SECTION III - HAZARDS IDENTIFICATION Health Hazards (Acute and Chronic): Ingestions: Ingestion may cause transient gastrointestinal irritation. Eye Contact: May cause mild, transient irritation. Skin: Transient irritation with prolonged exposure to concentrated material. Signs and of Exposure: Ingestion: May result in nausea, vomiting, and/or diarrhea. Eye Contact: May cause stinging, tearing, itching, swelling, and/or redness. Skin: Prolonged contact with concentrated material may be drying or transiently irritating to skin. SECTION IV - FIRST AID INFORMATION Emergency and First Aid Procedures: Ingestion: Drink 1 or 2 glasses of water. Eye Contact: Flush thoroughly with water for 15 minutes. Skin: If prolonged contact occurs, rinse thoroughly with water. If spilled on clothing, change clothes. If persist or recur, seek medical attention. Other: Consumer product package has a voluntary avoid accidents statement. SECTION V - FIRE FIGHTING INFORMATION Flash Point (Method Used): 115-135°F. Pensky- Martens (Closed cup) Explosive Limits: LEL: N/A UEL: N/A Extinguishing Media: CO2, water or dry chemical. Special Fire Fighting Procedures: None. Although this product has a flash point below 200°F (closed cup), it is a >50% aqueous solution that does not sustain combustion. DOT classification is non-hazardous. Unusual Fire Hazards: None Stability Unstable: Stable: X Conditions to Avoid: None known Incompatibility (Materials to Avoid): None known Hazardous Decomposition/By Products: None known Hazardous Polymerization: May Occur: Will Not Occur: X Conditions to Avoid: None known SECTION VI - ACCIDENTAL RELEASE MEASURES Personal Precautions: None Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL REGULATIONS. Solutions of the detergents may be allowed to be flushed down sewer First check with your local water treatment plant. Recycling is recommended for undiluted scrap product. Do not landfill. Steps To Be Taken in Case Material is Released or Spilled: Prevent spills from reaching a waterway. Sorbents may be used. Read “Waste Disposal Method” below for further information. 2 Page 319 of 1235 Page 319 of 1235 Page 319 of 1235 Page 319 of 1235 ---PAGE BREAK--- LIQUID HAND DISHWASHING DETERGENTS MSDS (Continued) Page 3 of 4 SECTION VII - HANDLING AND STORAGE Precautions To Be Taken in Handling and Storing: No unusual precautions necessary. Other Precautions: None known SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION Respiratory Protection (Specify Type): None required with normal use. Ventilation Local Exhaust: None required with normal consumer use. Special: None Mechanical (General): Normal/general dilution ventilation is acceptable. Other: None Eye Protection: None required with normal consumer use. Industrial Setting: For splash protection, use chemical goggles. Eye Wash fountain is desirable. Protective Gloves: None required with normal use. Industrial Setting: Protective gloves (rubber, neoprene) should be used for prolonged direct contact. Other Protective Equipment: None required with normal use. SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES Boiling Point Not known Specific Gravity (H2O=1): ca. 1 Vapor Pressure (mm Hg): N/A Percent Volatile by Volume ~60-65% Vapor Density (Air=1): N/A Evaporation Rate (nBuOAc=1): Unknown Odor Threshold: N/A Freezing Point: ~ 30 F Coefficient of Water/Oil Distribution: N/A pH: 8-9 Scooped Density: N/A Solubility in Water: Completely Appearance and Odor: Purple, Blue, Green, Yellow, Pink or Orange liquids. All products are perfumed. Reserve Alkalinity: N/A SECTION X - STABILITY AND REACTIVITY Possible Hazardous Reactions/Conditions: None known Conditions to Avoid: None Materials to Avoid: None Hazardous Decomposition Products: None known Other Recommendations: None SECTION XI - TOXICOLOGICAL INFORMATION LD50 (rats oral): approx 12 mL/kg ED50 approx 2.3 mL/kg Liquid hand dishwashing detergents have a relatively low order of toxicity. They may be irritating, but they are not expected to be corrosive. They are expected to be emetic. 3 Page 320 of 1235 Page 320 of 1235 Page 320 of 1235 Page 320 of 1235 ---PAGE BREAK--- 4 LIQUID HAND DISHWASHING DETERGENTS MSDS (Continued) Page 4 of 4 SECTION XII - ECOLOGICAL INFORMATION All surfactants are readily biodegradable. These products are safe for septic tanks. SECTION XIII - DISPOSAL CONSIDERATIONS Waste Disposal Method: Disposal is to be performed in compliance with Federal, state and local regulations. Household product is safe for disposal down the drain during use or in the trash. Industrial Setting: Solutions of diluted detergent in the course of use, may be allowed to be flushed down sewer. First check with your local water treatment plant. Recycling is recommended for undiluted scrap product. Do not landfill. SECTION XIV - TRANSPORT INFORMATION Dawn, Joy, Ivory and Salvo are non-hazardous under DOT. SECTION XV - ADDITIONAL REGULATORY INFORMATION All components are listed on the US TSCA Inventory. No components are affected by Significant New Use Rules (SNURs) under TSCA No components of Dawn, Ivory, Joy or Salvo are subject to California Proposition 65 labeling. All ingredients are CEPA approved for import to Canada by Procter & Gamble only. SECTION XVI - OTHER INFORMATION *N/A. - Not Applicable *N/K. - Not Known The submission of this MSDS may be required by law, but this is not an assertion that the substance is hazardous when used in accordance with proper safety practices and normal handling procedures. Data supplied is for use only in connection with occupational safety and health. The information contained herein has been compiled from sources considered by Procter & Gamble to be dependable and is accurate to the best of the Company’s knowledge. The information relates to the specific material designated herein, and does not relate to the use in combination with any other material or any other process. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, for any damage to any property resulting from misuse of the controlled product. Page 321 of 1235 Page 321 of 1235 Page 321 of 1235 Page 321 of 1235 ---PAGE BREAK--- 451005-00 DDC POWER GUARD DELVAC 1300 SUPER 15W-40 MATERIAL SAFETY DATA BULLETIN 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: DDC POWER GUARD DELVAC 1300 SUPER 15W-40 SUPPLIER: MOBIL OIL CORP. NORTH AMERICA MARKETING AND REFINING 3225 GALLOWS RD. FAIRFAX, VA 22037 24 - Hour Emergency (call collect): [PHONE REDACTED] Product and MSDS Information: [PHONE REDACTED] [PHONE REDACTED] CHEMTREC: [PHONE REDACTED] [PHONE REDACTED] 2. COMPOSITION/INFORMATION ON INGREDIENTS CHEMICAL NAMES AND SYNONYMS: SEVERE TREAT MIN. OILS & ADDITIVES INGREDIENTS CONSIDERED HAZARDOUS TO HEALTH: This product is not formulated to contain ingredients which have exposure limits established by U.S. agencies. It is not hazardous to health as defined by the European Union Dangerous Substances/Preparations Directives. See Section 15 for a regulatory analysis of the ingredients. See Section 15 for European Label Information. See Section 8 for exposure limits (if applicable). 3. HAZARDS IDENTIFICATION US OSHA HAZARD COMMUNICATION STANDARD: Product assessed in accordance with OSHA 29 CFR 1910.1200 and determined not to be hazardous. EFFECTS OF OVEREXPOSURE: No significant effects expected. EMERGENCY RESPONSE DATA: Brown Liquid. DOT ERG No. - NA 4. FIRST AID MEASURES EYE CONTACT: Flush thoroughly with water. If irritation occurs, call a physician. SKIN CONTACT: Wash contact areas with soap and water. INHALATION: Not expected to be a problem. INGESTION: Not expected to be a problem. However, if greater than 1/2 liter(pint) ingested, immediately give 1 to 2 glasses of water and call a physician, hospital emergency room or poison control center for assistance. Do not induce vomiting or give anything by mouth to an unconscious person. 5. FIRE-FIGHTING MEASURES Page 322 of 1235 Page 322 of 1235 Page 322 of 1235 Page 322 of 1235 ---PAGE BREAK--- EXTINGUISHING MEDIA: Carbon dioxide, foam, dry chemical and water fog. SPECIAL FIRE FIGHTING PROCEDURES: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposure. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. SPECIAL PROTECTIVE EQUIPMENT: For fires in enclosed areas, fire fighters must use self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS: None. Flash Point C(F): 216(421) (ASTM D-92). Flammable limits - LEL: NA, UEL: NA. NFPA HAZARD ID: Health: 0, Flammability: 1, Reactivity: 0 HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide. Metal oxides. Elemental oxides. 6. ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES: Report spills as required to appropriate authorities. U. S. Coast Guard regulations require immediate reporting of spills that could reach any waterway including intermittent dry creeks. Report spill to Coast Guard toll free number (800) 424-8802. In case of accident or road spill notify CHEMTREC (800) 424-9300. PROCEDURES IF MATERIAL IS RELEASED OR SPILLED: Adsorb on fire retardant treated sawdust, diatomaceous earth, etc. Shovel up and dispose of at an appropriate waste disposal facility in accordance with current applicable laws and regulations, and product characteristics at time of disposal. ENVIRONMENTAL PRECAUTIONS: Prevent spills from entering storm sewers or drains and contact with soil. PERSONAL PRECAUTIONS: See Section 8 7. HANDLING AND STORAGE HANDLING: No special precautions are necessary beyond normal good hygiene practices. See Section 8 for additional personal protection advice when handling this product. STORAGE: Do not store in open or unlabelled containers. Store away from strong oxidizing agents or combustible material. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION VENTILATION: No special requirements under ordinary conditions of use and with adequate ventilation. RESPIRATORY PROTECTION: No special requirements under ordinary conditions of use and with adequate ventilation. EYE PROTECTION: Normal industrial eye protection practices should be employed. SKIN PROTECTION: No special equipment required. However, good personal hygiene practices should always be followed. EXPOSURE LIMITS: This product does not contain any components which have recognized exposure limits. However, a exposure limit of 5.00 mg/m3 is suggested for oil mist. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 323 of 1235 Page 323 of 1235 Page 323 of 1235 Page 323 of 1235 ---PAGE BREAK--- Typical physical properties are given below. Consult Product Data Sheet for specific details. APPEARANCE: Liquid COLOR: Brown ODOR: Mild ODOR THRESHOLD-ppm: NE pH: NA BOILING POINT C(F): > 316(600) MELTING POINT C(F): NA FLASH POINT C(F): 216(421) (ASTM D-92) FLAMMABILITY: NE AUTO FLAMMABILITY: NE EXPLOSIVE PROPERTIES: NA OXIDIZING PROPERTIES: NA VAPOR PRESSURE-mmHg 20 C: < 0.1 VAPOR DENSITY: NE EVAPORATION RATE: NE RELATIVE DENSITY, 15/4 C: 0.888 SOLUBILITY IN WATER: Negligible PARTITION COEFFICIENT: > 3.5 VISCOSITY AT 40 C, cSt: 120.7 VISCOSITY AT 100 C, cSt: 15.5 POUR POINT C(F): < -24(-11) FREEZING POINT C(F): NE VOC: < 3.00 (Wt. 0.220 lbs/gal NA=NOT APPLICABLE NE=NOT ESTABLISHED D=DECOMPOSES FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING REPRESENTATIVE 10. STABILITY AND REACTIVITY STABILITY (THERMAL, LIGHT, ETC.): Stable. CONDITIONS TO AVOID: Extreme heat. INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide. Metal oxides. Elemental oxides. HAZARDOUS POLYMERIZATION: Will not occur. 11. TOXICOLOGICAL DATA ---ACUTE TOXICOLOGY--- ORAL TOXICITY (RATS): Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. DERMAL TOXICITY (RABBITS): Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. INHALATION TOXICITY (RATS): Practically non-toxic (LC50: greater than 5 mg/l). ---Based on testing of similar products and/or the components. EYE IRRITATION (RABBITS): Practically non-irritating. (Draize score: greater than 6 but 15 or less). ---Based on testing of similar products and/or the components. SKIN IRRITATION (RABBITS): Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than ---Based on testing of similar products and/or the components. ---SUBCHRONIC TOXICOLOGY (SUMMARY)--- Severely solvent refined and severely hydrotreated mineral base oils Page 324 of 1235 Page 324 of 1235 Page 324 of 1235 Page 324 of 1235 ---PAGE BREAK--- have been tested at Mobil Environmental and Health Sciences Laboratory by dermal application to rats 5 days/week for 90 days at doses significantly higher than those expected during normal industrial exposure. Extensive evaluations including microscopic examination of internal organs and clinical chemistry of body fluids, showed no adverse effects. ---CHRONIC TOXICOLOGY (SUMMARY)--- The base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic mouse skin painting studies of severely treated oils showed no evidence of carcinogenic effects. These results are confirmed on a continuing basis using various screening methods such as the Mobil Modified Ames Test and IP-346. ---OTHER TOXICOLOGY DATA--- Used gasoline engine oils have shown evidence of skin carcinogenic activity in laboratory tests when no effort was made to wash the oil off between applications. Used oil from diesel engines did not produce this effect. 12. ECOLOGICAL INFORMATION ENVIRONMENTAL FATE AND EFFECTS: Not established. 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Product is suitable for burning in an enclosed, controlled burner for fuel value or disposal by supervised incineration. Such burning may be limited pursuant to the Resource Conservation and Recovery Act. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of at an appropriate government waste disposal facility. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. RCRA INFORMATION: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrosivity, or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. 14. TRANSPORT INFORMATION USA DOT: NOT REGULATED BY USA DOT. RID/ADR: NOT REGULATED BY RID/ADR. IMO: NOT REGULATED BY IMO. IATA: NOT REGULATED BY IATA. 15. REGULATORY INFORMATION Governmental Inventory Status: All components comply with TSCA, EINECS/ELINCS, and MITI. Page 325 of 1235 Page 325 of 1235 Page 325 of 1235 Page 325 of 1235 ---PAGE BREAK--- EU Labeling: EU labeling not required. U.S. Superfund Amendments and Reauthorization Act (SARA) Title III: This product contains no "EXTREMELY HAZARDOUS SUBSTANCES". SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. This product contains the following SARA (313) Toxic Release Chemicals: CHEMICAL NAME CAS NUMBER CONC. ZINC DITHIOPHOSPHATE 68649-42-3 1.69% The following product ingredients are cited on the lists below: CHEMICAL NAME CAS NUMBER LIST CITATIONS NAPHTHALENE (COMPONENT ANALYSIS) 91-20-3 22 STYRENE MONOMER (COMPONENT 100-42-5 22 ANALYSIS) (0.02%) PHENOL (COMPONENT ANALYSIS) 108-95-2 22 XYLENES (COMPONENT ANALYSIS) 1330-20-7 22 ZINC (ELEMENTAL ANALYSIS) (0.14%) 7440-66-6 22 ZINC DITHIOPHOSPHATE 68649-42-3 18, 21, 24 REGULATORY LISTS SEARCHED 1=ACGIH ALL 6=IARC 1 11=TSCA 4 16=CA P65 CARC 21=LA RTK 2=ACGIH A1 7=IARC 2A 12=TSCA 5a2 17=CA P65 REPRO 22=MI 293 3=ACGIH A2 8=IARC 2B 13=TSCA 5e 18=CA RTK 23=MN RTK 4=NTP CARC 9=OSHA CARC 14=TSCA 6 19=FL RTK 24=NJ RTK 5=NTP SUS 10=OSHA Z 15=TSCA 12b 20=IL RTK 25=PA RTK 26=RI RTK Code key: CARC=Carcinogen; SUS=Suspected Carcinogen; REPRO=Reproductive 16. OTHER INFORMATION USE: COMMERCIAL ENGINE OIL NOTE: MOBIL PRODUCTS ARE NOT FORMULATED TO CONTAIN PCBS. Please call the Customer Response Center on [PHONE REDACTED] for formulation disclosure. For Internal Use Only: MHC: 1* 1* 0* 1* MPPEC: A, TRN: 451005-00, CMCS97: 977374, REQ: US - MARKETING, SAFE USE: L EHS Approval Date: 03JUN1999 Legally required information is given in accordance with applicable Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for particular uses are beyond our control; all risks of use of the product are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO THE USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a recommendation for uses which infringe valid patents or as extending any license under valid patents. Appropiate warnings and safe handling procedures should be providedto handlers and users. Use or re- transmission of the information contained herein in any other format than the format as presented is strictly prohibited. Mobil neither represents nor warrants that the format, content or product formulas contained in this document comply with the laws of any other country Page 326 of 1235 Page 326 of 1235 Page 326 of 1235 Page 326 of 1235 ---PAGE BREAK--- except the United States of America. Copyright 1996 Mobil Corporation, All rights reserved Page 327 of 1235 Page 327 of 1235 Page 327 of 1235 Page 327 of 1235 ---PAGE BREAK--- MSDS: 501 MATERIAL SAFETY DATA SHEET REV. DATE: 2/12 PAGE 1 OF 2 Section I - PRODUCT IDENTIFICATION ZEE MEDICAL, INC. TRADE NAME: DERMA FLEUR Lotion 22 Corporate Park #2219, 2220 Irvine, CA 92606 800/841-8417 Emergency Phone No. (CHEMTREC): 800/424-9300 Section II - HAZARDOUS INGREDIENTS CAS PEL, TLV, INGREDIENT NUMBER OSHA (mg/M3) ACGIH (mg/M3) Contains no hazardous ingredients NOTE: This product has been formulated for skin application and is regulated by the FDA as a cosmetic product. Under normal conditions of use, this product is not a hazardous material as defined by the OSHA Hazard Communication Standard (29 CFR 1910.1200). See product label for list of ingredients. Section III - PHYSICAL DATA Boiling Point: N/A Specific Gravity: 1.05 Vapor Pressure: (mm Hg): N/A Melting Point: N/A Vapor Density: N/A Evaporation Rate: N/A Solubility In Water: Soluble Appearance and Odor: White lotion, odorless. Section IV - FIRE AND EXPLOSION HAZARD DATA Flash Point: N/A Extinguishing Media: N/A Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None NFPA Hazard Rating: Health: 0 Flammability: 0 Reactivity: 0 Special: N/A HMIS Hazard Rating: Health: 0 Flammability: 0 Reactivity: 0 Hazard Index: 4=Severe, 3=Serious, 2=Moderate, 1=Slight, 0=Minimal Page 328 of 1235 Page 328 of 1235 Page 328 of 1235 Page 328 of 1235 ---PAGE BREAK--- MSDS: 501 MATERIAL SAFETY DATA SHEET REV. DATE: 2/12 PAGE 2 OF 2 Section V - HEALTH HAZARD DATA Primary Routes of Entry: Eye Contact Health Hazards: Eye contact may cause irritation and redness of the eyes. Carcinogenicity: NTP: NO IARC: NO OSHA: NO Emergency First Aid Procedures: If material gets in eyes, flush thoroughly with water, lifting upper and lower eyelids occasionally. Section VI - REACTIVITY DATA Stability Stability: Stable Incompatibilities: None Hazardous Decomposition Products: None Hazardous Polymerization: Will not occur Section VII - SPILL AND DISPOSAL PROCEDURES Spill: Collect spill with absorbent material and place in sealed container for disposal. Disposal: Dispose of in accordance with local, state and federal regulations. Section VIII - SAFE HANDLING AND USE INFORMATION Respiratory Protection: Not required Ventilation: General mechanical. Protective Equipment: Use eye protection as necessary to prevent excessive contact. Section IX - SPECIAL PRECAUTIONS None N/A = Not applicable N/E = Not established Page 329 of 1235 Page 329 of 1235 Page 329 of 1235 Page 329 of 1235 ---PAGE BREAK--- 1 Material Safety Data Sheet 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Chemical Product Name Sodium Chloride (Salt) Chemical Family Alkali Metal/Halide Chemical Name Sodium Chloride INCI Name SODIUM CHLORIDE INN Name sodium chloride Formula NaCl Molecular Weight 58.44 Commercial Name Diamond Solar Salt - Extra Coarse, Diamond Solar Salt - Coarse Manufacturer Emergency Telephone Numbers Cargill Salt CHEMTREC (800) 424-9300 P.O. Box 5621 Minneapolis, MN 55440 2. COMPOSITION/INFORMATION ON INGREDIENTS Description White solid Ingredient Name CAS Number Exposure Limits Concentration Sodium Chloride 7647-14-5 100 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW None – GRAS Substance (Generally Recognized As Safe) Potential Health Effects Route(s) Of Entry: Ingestion, skin/eye contact, inhalation. Human Effects and of Overexposure: Acute Inhalation: Irritation of the respiratory tract. Chronic Inhalation: No applicable information found for chronic system effects. Acute Skin Contact: Large amounts can cause irritation, and, if applied to damaged skin, absorption can occur with effects similar to those via ingestion. Chronic Skin Contact: No applicable information found for chronic system effects. Page 330 of 1235 Page 330 of 1235 Page 330 of 1235 Page 330 of 1235 ---PAGE BREAK--- 2 Acute Eye Contact: Irritation with burning and tearing (salt concentrations greater than the normal saline present). Chronic Eye Contact: No applicable information found for chronic systemic effects. Acute Ingestion: Intake of large amounts has generally occurred for deliberate reasons: suicide, absorption, and to induce vomiting. The following effects were observed; nausea and vomiting, diarrhea, cramps, restlessness, irritability, dehydration, water retention, nose bleed, gastrointestinal tract damage, fever, sweating, sunken eyes, high blood pressure, muscle weakness, dry mouth and nose, shock, cerebral edema (fluid on brain), pulmonary edema (fluid in lungs), blood cell shrinkage, and brain damage (due to dehydration of brain cells). Death is generally due to cardiovascular collapse or CNS damage. Less than a few grams would not be harmful. For larger quantities, drink large amounts of water or milk. Chronic Ingestion: No applicable information found for chronic systemic effects. Carcinogenicity NTP: Not listed as carcinogen or mutagen. IARC: Not listed as carcinogen or mutagen. OSHA: Not listed as carcinogen or mutagen. Medical Conditions Aggravated by Exposure: In some cases of confirmed hypertension, ingestion may result in elevated blood pressure. 4. FIRST AID MEASURES First Aid for Eyes: For eye contact, flush with water immediately, lifting eyelids occasionally. First Aid for Skin: Remove clothing from affected area. Wash skin thoroughly. Rinse carefully. First Aid for Inhalation: If person breathes large quantities, remove to fresh air at once. If breathing stops, apply artificial respiration immediately. First Aid for Ingestion: Less than a few grams would not be harmful. For larger quantities, drink large amounts of water or milk. 5. FIRE AND MEASURES Flash Point: N/A Extinguishing Media: N/A. This product is nonflammable. Special Fire Fighting Procedures: N/A 6. ACCIDENTAL RELEASE MEASURES Spill or Leak Procedures: Contain spills to prevent contamination of water supply or sanitary sewer system. Vacuum or sweep into containers for proper disposal. 7. HANDLING AND STORAGE Page 331 of 1235 Page 331 of 1235 Page 331 of 1235 Page 331 of 1235 ---PAGE BREAK--- 3 Storage Temperature (min./max.): Avoid humid or wet conditions as product will cake and become hard. Special Sensitivity: Avoid contact with strong acids. Handling and Storage Precautions: Becomes hygroscopic at 75% relative humidity. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection Requirements: Eyeglasses or goggles should be worn in dusty areas. Skin Protection Requirements: Protective clothing may be worn in dusty areas, but is generally not required. Respiratory/Ventilation Requirements: NIOSH/MSHA approved respirator for particulates. Exposure Limits: Not listed. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical Form: White solid with slight halogen odor. Color: White to opaque. Odor: Halogen odor when heated. Boiling Point (760mm 1465 Melting Point/Freezing Point 801 pH: 6.7 – 10.0 Solubility in Water 26.4 Specific Gravity (H2O = 2.16 Bulk Density (lbs./ft3): 35-83 % Volatile by Weight: N/A Vapor Pressure (mm Hg/747°C): 2.4 Vapor Density (Air=1): N/A 10. REACTIVITY Stability: Stable Incompatibilities: Avoid contact with strong acids. Becomes corrosive to metals when wet. Page 332 of 1235 Page 332 of 1235 Page 332 of 1235 Page 332 of 1235 ---PAGE BREAK--- 4 Decomposition Products: May evolve chlorine gas when in contact with strong acids. 11. TOXICOLOGICAL INFORMATION Description: Not listed. 12. ECOLOGICAL INFORMATION Ecotoxicity: Not listed. Environmental Degradation: Not listed. 13. DISPOSAL CONSIDERATIONS Waste Disposal Method: Follow applicable Federal, state, and local regulations. 14. TRANSPORTATION INFORMATION D.O.T. Shipping Name: Not listed. Technical Shipping Name: Not listed. D.O.T. Hazard Class: Not listed. U.N./N.A. Number: Not listed. Product Rq (lbs.): N/A D.O.T. Label: Not listed. D.O.T. Placard: N/A Freight Class Bulk: N/A Freight Class Package: N/A Product Label: N/A 15. REGULATORY INFORMATION OSHA Status: Not listed. TSCA Status: Listed as non-hazardous. CERCLA Reportable Quantity SARA Title III Section 302 Extremely Hazardous Substances: Not listed. Section 311/312 Hazard Categories: Not listed. Page 333 of 1235 Page 333 of 1235 Page 333 of 1235 Page 333 of 1235 ---PAGE BREAK--- 5 Section 313 Toxic Chemicals: Not listed. RCRA Status: Not listed. EINECS Number: 231-598-3 ENCS Number: 1-236 ECL Serial Number: KE-31387 SWISS Number: G-2580 HMIS Rating: 1 0 0 A State Regulatory Information Company Name/Cas Number Concentration State Code N/A 16. OTHER INFORMATION Reason for Issue: Regulatory compliance. Prepared By: Steve Karl Approved By: Dave Merriweather Title: Technical Director Approval Date: February 2005 Supersedes Date: September 2002 MSDS Number: ND7 Disclaimer: All statements, technical information and recommendations contained herein are, to the best of our knowledge, reliable and accurate; however, no warranty, either expressed or implied is made with respect thereto, nor will any liability be assumed for damages resultant from the use of the material described. It is the responsibility of the user to comply with all applicable Federal, state and local laws and regulations. It is also the responsibility of the user to maintain a safe workplace. The user should consider the health hazards and safety information provided herein as a guide and should take the necessary steps to instruct employees, and to develop work practice procedures to ensure a safe work environment. This information is not intended as a license to operate under, or a recommendation to practice or infringe upon any patent of this Company or others covering any process, composition of matter or use. Page 334 of 1235 Page 334 of 1235 Page 334 of 1235 Page 334 of 1235 ---PAGE BREAK--- 6 Page 335 of 1235 Page 335 of 1235 Page 335 of 1235 Page 335 of 1235 ---PAGE BREAK--- Page 336 of 1235 Page 336 of 1235 Page 336 of 1235 Page 336 of 1235 ---PAGE BREAK--- Page 337 of 1235 Page 337 of 1235 Page 337 of 1235 Page 337 of 1235 ---PAGE BREAK--- Page 338 of 1235 Page 338 of 1235 Page 338 of 1235 Page 338 of 1235 ---PAGE BREAK--- Page 339 of 1235 Page 339 of 1235 Page 339 of 1235 Page 339 of 1235 ---PAGE BREAK--- Page 340 of 1235 Page 340 of 1235 Page 340 of 1235 Page 340 of 1235 ---PAGE BREAK--- Page 341 of 1235 Page 341 of 1235 Page 341 of 1235 Page 341 of 1235 ---PAGE BREAK--- Page 342 of 1235 Page 342 of 1235 Page 342 of 1235 Page 342 of 1235 ---PAGE BREAK--- Page 343 of 1235 Page 343 of 1235 Page 343 of 1235 Page 343 of 1235 ---PAGE BREAK--- Page 344 of 1235 Page 344 of 1235 Page 344 of 1235 Page 344 of 1235 ---PAGE BREAK--- Page 345 of 1235 Page 345 of 1235 Page 345 of 1235 Page 345 of 1235 ---PAGE BREAK--- Page 346 of 1235 Page 346 of 1235 Page 346 of 1235 Page 346 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Date Issued: Revised 8/22/2011 Trade Name: Distilled White Vinegar Chemical Name: Dilute Acetic Acid (CH 3COOH) C.A.S. - 8028-52-2 Definition Product made by the acetous fermentation of Ethyl Alcohol to contain 4–10% acetic acid (or 40–100 grain vinegar) Manufacturer’s Name H. J. Heinz Co. And Address: Heinz 57 Center 357 6th Avenue Pittsburgh, Pa 15222-2530 Contact: Customer & Consumer Resource Center Phone Number: 1-[PHONE REDACTED] HEALTH HAZARD DATA INHALATION Threshold Limit Value: 10 ppm Short Term Exposure: 15 ppm for 15 minutes Odor Threshold: 1.0 ppm Prolonged inhalation of vapors can cause irritation to respiration tract. EYES Will cause eye irritation – smarting and reddening of the eye. Page 347 of 1235 Page 347 of 1235 Page 347 of 1235 Page 347 of 1235 ---PAGE BREAK--- MSDS: Distilled White Vinegar Page 2. EMERGENCY AND FIRST – AID PROCEDURES In case of eye contact, flush immediately and thoroughly with water for 15–20 minutes (timed by a clock). Call a physician. If swallowed in large amounts, water should be consumed to dilute. Do not induce vomiting. Do not give emetics of baking soda. Call a physician. Stability – GOOD HAZARDOUS POLYMERIZATION WILL NOT OCCUR. SPILL OR LEAK PROCEDURES If vinegar is spilled, water may be used to dilute. PHYSICAL DATA Appearance and Odor Clear liquid, odor of vinegar. Boiling Point: 244 oF Vapor Pressure (MM Hg): 11 MM Vapor Density (Air = 2.1 Solubility in Water: Complete Specific Gravity: 1.01 pH: 2.2 @ 100 Grain Questions? Contact: Ms. Karen White, Senior Manager Government & Regulatory Affairs and Customer & Consumer Resource Center Heinz North America P.O. Box 57 Pittsburgh, PA. 15230 Page 348 of 1235 Page 348 of 1235 Page 348 of 1235 Page 348 of 1235 ---PAGE BREAK--- 318 MATERIAL SAFETY DATA SHEET Page: 1 PRODUCT NAME: DURATECH SATIN ENAMEL WHITE HMIS CODES: H F R PRODUCT CODE: 318 1 1 0 SECTION I - MANUFACTURER IDENTIFICATION MANUFACTURER'S NAME: HALLMAN/LINDSAY PAINTS DATE PRINTED: 02/09/01 ADDRESS: P.O. BOX 109 NAME OF PREPARER: MICHAEL MC NULTY SUN PRAIRIE, WI 53590 INFORMATION PHONE: (608) 834-8844 EMERGENCY PHONE: 1-[PHONE REDACTED] SECTION II - HAZARDOUS INGREDIENTS/SARA III INFORMATION VAPOR PRESSURE WEIGHT REPORTABLE COMPONENTS CAS NUMBER mm Hg @ TEMP PERCENT TITANIUM DIOXIDE 13463-67-7 OSHA PEL: 10 MG/M3, ACGIH TLV: 10 MG/M3, STEL TLV: N/A BARIUM SULFATE 7727-43-7 * Indicates toxic chemical(s) subject to the reporting requirements of section 313 of Title III and of 40 CFR 372. Sanding the cured product may produce a nuisance dust. Observe a TLV of 10 mg/m3 for total dust containing no asbestos and silica. Observe a TLV of 5mg/m3 for respirable dust. SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS BOILING RANGE: 212 DEG F - 490 deg F SPECIFIC GRAVITY (H2O=1): 1.22 VAPOR DENSITY: HEAVIER THAN AIR EVAPORATION RATE: SLOWER THAN ETHER COATING V.O.C.: 195 g/l DENSITY 10.14 lb/gl COATING V.O.C.: 1.63 lb/gl SOLUBILITY IN WATER: N/A APPEARANCE AND ODOR: LIQUID COATING WITH MILD ODOR SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT: 182 F METHOD USED: TCC FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER: .6 UPPER: 73 EXTINGUISHING MEDIA: WATER FOG, DRY CHEMICAL, CARBON DIOXIDE SPECIAL FIREFIGHTING PROCEDURES Water spray may cool containers. Normal firefighting proceedures may be used. UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may burst when exposed to extreme heat. SECTION V - REACTIVITY DATA STABILITY: STABLE CONDITIONS TO AVOID Keep from freezing. INCOMPATIBILITY (MATERIALS TO AVOID) Strong oxidizing agents. HAZARDOUS DECOMPOSITION OR BYPRODUCTS Under heat, Carbon Dioxide and Carbon Monoxide may be produced. HAZARDOUS POLYMERIZATION: Will Not Occur 318 MATERIAL SAFETY DATA SHEET Page: 2 SECTION VI - HEALTH HAZARD DATA INHALATION HEALTH RISKS AND OF EXPOSURE Page 349 of 1235 Page 349 of 1235 Page 349 of 1235 Page 349 of 1235 ---PAGE BREAK--- May irritate respitory tract(nose, throat, lungs) SKIN AND EYE CONTACT HEALTH RISKS AND OF EXPOSURE EYE CONTACT: Short term liquid or vapor contact may result in slight irritation. Prolonged or repeated contact may be more irritating. SKIN CONTACT: May cause mild irritation to skin. Prolonged and repeated contact with skin can cause defatting and drying of the skin which may result in skin irritation and dermatitus. SKIN ABSORPTION HEALTH RISKS AND OF EXPOSURE Can dry and defat skin causing cracks, irritation, and dermatitis. INGESTION HEALTH RISKS AND OF EXPOSURE DO NOT TAKE INTERNALLY HEALTH HAZARDS (ACUTE AND CHRONIC) EFFECTS OF ACUTE EXPOSURE EYE CONTACT.............May cause: Mild eye irritation. cause: Mild skin irritation. INHALATION..............None known. INGESTION...............May cause:Nausea. CARCINOGENICITY: NTP CARCINOGEN: N/AIARC MONOGRAPHS: N/AOSHA REGULATED: N/A CARCINOGEN CONTENT None of the ingrediants in this product are listed as a potential carcinogen by the NTP, IARC, or OSHA MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE Skin Disorders EMERGENCY AND FIRST AID PROCEDURES INHALATION OVEREXPOSURE-Move person to fresh air. INGESTION-Give two glasses of water to drink. Call a DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. SKIN CONTACT- Wash thoroughly with soap and water. EYE CONTACT- Flush with large quantities of water for 15 minutes SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Dike spill to minimize contamination. Absorb with inert material. Collect in containers. Keep spill out of waterways. WASTE DISPOSAL METHOD Dispose of material in accordance with Federal, State and Local regulations. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Avoid prolonged contact with liquid and/or vapor. KEEP FROM FREEZING. OTHER PRECAUTIONS Never take internally. Wash thoroughly after use. SECTION VIII - CONTROL MEASURES RESPIRATORY PROTECTION When spraying this material use a NIOSH approved cartridge respirator to keep airborne mists and vapor concentrations below TLV values. VENTILATION MECHANICAL-(GENERAL) Adequate 318 MATERIAL SAFETY DATA SHEET Page: 3 PROTECTIVE GLOVES Impervious gloves EYE PROTECTION Safety glasses recommended. OTHER PROTECTIVE CLOTHING OR EQUIPMENT Eye Wash Page 350 of 1235 Page 350 of 1235 Page 350 of 1235 Page 350 of 1235 ---PAGE BREAK--- WORK/HYGIENIC PRACTICES Eye washes and safety showers in the workplace are recommended. Wash hands thoroughly with soap and water after applying product. SECTION IX - DISCLAIMER This M.S.D.S. is furnished without charge to responsible persons who use it at their discretion and risk. Although the information and suggestions contained herein have been compiled, as of the issue date above, from sources believed to be reliable, there is no warranty of any kind, express or implied, as to the completeness and accuracy thereof. Page 351 of 1235 Page 351 of 1235 Page 351 of 1235 Page 351 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 31−1013− 11 00 Section 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER HMIS CODES Health 3 31−1013− Flammability 2 Reactivity 0 PRODUCT NAME DUTCH BOY* Professional Ext. Acrylic Latex Traffic Zone Marking Paint, Yellow MANUFACTURER’S NAME EMERGENCY TELEPHONE NO. DUTCH BOY (216) 566−2917 101 Prospect Avenue N.W. Cleveland, OH 44115 DATE OF PREPARATION INFORMATION TELEPHONE NO. 28−OCT−04 (216) 566−2902 Section 2 COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE 3 67−56−1 Methanol ACGIH TLV 200 ppm (Skin) 92 mm ACGIH TLV 250 ppm (Skin) STEL OSHA PEL 200 ppm (Skin) OSHA PEL 250 ppm (Skin) STEL 1 112−34−5 2−(2−Butoxyethoxy)−ethanol ACGIH TLV Not Available 0.06 mm OSHA PEL Not Available 53 471−34−1 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 15 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 3 13463−67−7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction Section 3 HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Continued on page 2 Page 352 of 1235 Page 352 of 1235 Page 352 of 1235 Page 352 of 1235 ---PAGE BREAK--- 31−1013− page 2 SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Section 4 FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re−use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. Section 5 FIRE FIGHTING MEASURES FLASH POINT LEL UEL 145 F PMCC 0.9 36.5 FLAMMABILITY CLASSIFICATION Combustible, Flash above 99 and below 200 F EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build−up of pressure) when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self−contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build−up and possible autoignition or explosion when exposed to extreme heat. Section 6 ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Continued on page 3 Page 353 of 1235 Page 353 of 1235 Page 353 of 1235 Page 353 of 1235 ---PAGE BREAK--- 31−1013− page 3 Section 7 HANDLING AND STORAGE STORAGE CATEGORY DOL Storage Class IIIA PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Contents are COMBUSTIBLE. Keep away from heat and open flame. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1−800−424−LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Continued on page 4 Page 354 of 1235 Page 354 of 1235 Page 354 of 1235 Page 354 of 1235 ---PAGE BREAK--- 31−1013− page 4 Section 9 PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 13.35 lb/gal 1599 g/l SPECIFIC GRAVITY 1.61 BOILING POINT 148 − 448 F 64 − 231 C MELTING POINT Not Available VOLATILE VOLUME 40 % EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 9.5 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical) 0.87 lb/gal 104 g/l Less Water and Federally Exempt Solvents 0.59 lb/gal 70 g/l Emitted VOC Section 10 STABILITY AND REACTIVITY STABILITY Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Section 11 TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver and urinary systems. Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung cancer, however, such exposure levels are not attainable in the workplace. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. TOXICOLOGY DATA CAS No. Ingredient Name 67−56−1 Methanol LC50 RAT 4HR 64000 ppm LD50 RAT 5630 mg/kg 112−34−5 2−(2−Butoxyethoxy)−ethanol LC50 RAT 4HR Not Available LD50 RAT 5660 mg/kg 471−34−1 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available 13463−67−7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available Continued on page 5 Page 355 of 1235 Page 355 of 1235 Page 355 of 1235 Page 355 of 1235 ---PAGE BREAK--- 31−1013− page 5 Section 12 ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Section 13 DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Section 14 TRANSPORT INFORMATION No data available. Section 15 REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element 67−56−1 Methanol 3 Glycol Ethers 1 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Section 16 OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 356 of 1235 Page 356 of 1235 Page 356 of 1235 Page 356 of 1235 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 29-Jul-2014 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 83570 Product name Expunge Recommended Use Paint Remover Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Skin contact. Inhalation. Eyes. Potential health effects Eyes Exposure to vapors or mists may cause the following effects:. Irritation. Reddening. Burning sensation. Skin Repeated or prolonged exposure may cause:. Skin Irritation. Redness. Itching. Burning sensation. Inhalation Exposure to vapors may cause the following effects. Irritating to respiratory system. Headaches. Dizziness. Nausea. Loss of coordination. Extreme overexposure may cause. Central nervous system depression. Cardiac abnormalities. Liver damage. Reproductive system damage. Possible unconsciousness. Death. Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Ingestion May be harmful if swallowed. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Toluene 108-88-3 30-60 Propane 74-98-6 10-30 Diacetone alcohol 123-42-2 5-10 Butane 106-97-8 5-10 Isopropyl alcohol 67-63-0 1-5 Acetone 67-64-1 1-5 4. FIRST AID MEASURES Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek medical attention. Skin contact Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. Ingestion Do Not induce vomiting. Immediate medical attention is required. Inhalation Remove to fresh air. Restore breathing. Keep warm and quiet. 5. FIRE FIGHTING MEASURES Flash point °C < -17.78 Flash point °F < 0 Method No information available Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 12.8 Lower 1.0 Specific Information for Aerosol Products Flame extension 40" without extension tube Flashback Yes Suitable extinguishing media Carbon dioxide (CO2). Dry chemical. Alcohol foam. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fire and Explosion Hazards Containers may vent or burst under extreme or prolonged fire conditions. Flash back possible over considerable distance. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat . During emergency conditions, overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. Sensitivity to shock No information available. Sensitivity to static discharge Yes. Take precautionary measures against static discharges. Page 1 / 4 Emergency Overview Extremely flammable. Contents under pressure. Irritant. Page 357 of 1235 Page 357 of 1235 Page 357 of 1235 Page 357 of 1235 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Eliminate all sources of ignition. Ventilate area to maintain exposure below permissible exposure limits. Soak up with inert absorbent material. Dispose of absorbent in accordance with local, state and federal regulations. 7. HANDLING AND STORAGE Handling Keep away from open flames, hot surfaces and sources of ignition. Vapors may accumulate readily and may ignite explosively. Ensure adequate ventilation. Avoid breathing spray mist. Do not smoke. Turn off other sources of ignition prior to use and until all vapors have dissipated. Do not puncture or incinerate. Do not take internally. Keep out of reach of children. Check to make sure that all equipment is properly grounded and installed to satisfy electrical classification requirements. Standard safety precautions should be observed when handling this material. Storage Containers exposed to extreme heat may burst. Keep away from heat and sources of ignition. Store in temperatures below 120 degrees F (50 degrees C) . Keep away from direct sunlight. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Propane 1000 ppm 1800 mg/m3 - 1000 ppm - Butane 800 ppm - - 1000 ppm Toluene 200 ppm 300 ppm 20 ppm - Isopropyl alcohol 400 ppm 980 mg/m3 - 200 ppm 400 ppm Diacetone alcohol 50 ppm 240 mg/m3 - 50 ppm - Acetone 1000 ppm 2400 mg/m3 - 500 ppm 750 ppm Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Use in a well ventilated area. Consult OSHA standard 1910.94, 1910.107, 1910.108. Hygiene measures Wash hands before eating or using the washroom. Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes and clothing. Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Wear a NIOSH approved organic vapor/particulate respirator. Hand Protection Gloves are not required in normal use. The following gloves are recommended for prolonged or repeated contact: . Chemical resistant gloves. Eye protection Wear safety glasses with side shields. Skin and body protection None necessary under normal conditions Other Protective Equipment An eye wash station should be available. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Colorless Odor No information available Odor Threshold No information available pH 7.0 Specific Gravity 0.80 Vapor pressure No data available Density 6.65 lb/gal; 796 g/l Vapor density >Air Evaporation Rate >1 (Ether Water solubility No data available VOC Content 71.66% Partition Coefficient (n-octanol/water) No data available Boiling point/range °C < -18 - 172 Boiling point/range °F < 0 - 342 Melting point/range °C No data available Melting point/range °F No data available Flash point °C < -17.78 Flash point °F < 0 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid None known. Incompatability None known. Page 2 / 4 Product name Expunge Product code 83570 Page 358 of 1235 Page 358 of 1235 Page 358 of 1235 Page 358 of 1235 ---PAGE BREAK--- Hazardous Decomposition Products Carbon dioxide. Carbon monoxide. Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Propane 74-98-6 - - 658 mg/L Butane 106-97-8 - - 658 g/m3 Toluene 108-88-3 636 mg/kg 8390 mg/kg 12.5 mg/L Isopropyl alcohol 67-63-0 4396 mg/kg 12800 mg/kg 16000 ppm Diacetone alcohol 123-42-2 4 g/kg - - Acetone 67-64-1 - - 50100 mg/m3 Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity See Section 2 . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity Possible risk of harm to the unborn fetus. Target Organ Effects See Section 2. Reports have associated prolonged overexposure to solvents with permanent brain and nervous system damage. Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Propane Not Listed Not Listed Not Listed Not Listed Not Listed Butane Not Listed Not Listed Not Listed Not Listed Not Listed Toluene A4 Not Listed Not Listed Not Listed Not Listed Isopropyl alcohol A4 Not Listed Not Listed Not Listed Not Listed Diacetone alcohol Not Listed Not Listed Not Listed Not Listed Not Listed Acetone A4 Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Ecotoxicity effects No information available 13. DISPOSAL CONSIDERATIONS Disposal Information As supplied, this product is a RCRA Hazardous Waste . Waste must be tested for ignitability to determine EPA hazardous waste numbers. Do not puncture or incinerate. Depressurize before disposal. Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT UN1950 Aerosols, flammable, 2.1. Consumer commodity, ORM-D. This product meets the "Limited quantity" exemption TDG UN1950 AEROSOLS, flammable, 2.1 Consumer commodity, ORM-D. This product meets the "limited quantity" exemption 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Isopropyl alcohol Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Propane Listed Listed Not Listed Butane Listed Listed Not Listed Toluene Listed Listed Development al Female Reproductive Isopropyl alcohol Listed Listed Not Listed Diacetone alcohol Listed Listed Not Listed Page 3 / 4 Product name Expunge Microtox Data Photobacterium phosphoreum EC50=35390 mg/L (5 min) Microtox Data Photobacterium phosphoreum EC50=19.7 mg/L (30 min) Water Flea Data Daphnia magna EC50=13299 mg/L (48 h) Acetone Microtox Data Photobacterium phosphoreum EC50=14500 mg/L (15 min) Water Flea Data Daphnia magna EC505.46 - 9.83 mg/L (48 h) Daphnia magna EC50=11.5 mg/L (48 h) Water Flea Data Daphnia magna EC5010294 - 17704 mg/L (48 h) Daphnia magna EC5012600 - 12700 mg/L (48 h) Toluene Isopropyl alcohol Product code 83570 Page 359 of 1235 Page 359 of 1235 Page 359 of 1235 Page 359 of 1235 ---PAGE BREAK--- Chemical Name New Jersey - RTK - RTK California Prop. 65 Acetone Not Listed Listed Not Listed Chemical Name Type Toluene - 108-88-3 Female Reproductive WARNING: This product contains a chemical(s) known to the state of California to cause cancer and birth defects or other reproductive harm International Inventories Chemical Name EINECS DSL NDSL TSCA Propane X X - X Butane X X - X Toluene X X - X Isopropyl alcohol X X - X Diacetone alcohol X X - X Acetone X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION HMIS Health - 2 * Flammability - 3 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product name Expunge Product code 83570 Page 360 of 1235 Page 360 of 1235 Page 360 of 1235 Page 360 of 1235 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 03-Feb-2014 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 83570 Product name Expunge Recommended Use Paint Remover Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Skin contact. Inhalation. Eyes. Potential health effects Eyes Exposure to vapors or mists may cause the following effects:. Irritation. Reddening. Burning sensation. Skin Repeated or prolonged exposure may cause:. Skin Irritation. Redness. Itching. Burning sensation. Inhalation Exposure to vapors may cause the following effects. Irritating to respiratory system. Headaches. Dizziness. Nausea. Loss of coordination. Extreme overexposure may cause. Central nervous system depression. Cardiac abnormalities. Liver damage. Reproductive system damage. Possible unconsciousness. Death. Misuse by deliberately concentrating vapors and inhaling contents can be harmful or fatal. Ingestion May be harmful if swallowed. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Toluene 108-88-3 30-60 Propane 74-98-6 10-30 Diacetone alcohol 123-42-2 5-10 Butane 106-97-8 5-10 Isopropyl alcohol 67-63-0 1-5 Acetone 67-64-1 1-5 4. FIRST AID MEASURES Eye contact Flush with plenty of water for at least 15 minutes. Seek medical attention. Skin contact Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. Seek medical attention if irritation persists. Ingestion Do Not induce vomiting. Call a physician or Poison Control Center immediately. Inhalation Remove to fresh air. Restore breathing. Keep warm and quiet. 5. FIRE FIGHTING MEASURES Flash point °C < -17.78 Flash point °F < 0 Method No information available Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 12.8 Lower 1.0 Specific Information for Aerosol Products Flame extension 40" without extension tube Flashback Yes Suitable extinguishing media Carbon dioxide (CO2). Dry chemical. Alcohol foam. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 1 / 4 Emergency Overview Extremely flammable. Contents under pressure. Irritant. Page 361 of 1235 Page 361 of 1235 Page 361 of 1235 Page 361 of 1235 ---PAGE BREAK--- Fire and Explosion Hazards Containers may vent or burst under extreme or prolonged fire conditions. Flash back possible over considerable distance. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat . During emergency conditions, overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. Sensitivity to shock No information available. Sensitivity to static discharge Yes. Take precautionary measures against static discharges. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Eliminate all sources of ignition. Ventilate area to maintain exposure below permissible exposure limits. Soak up with inert absorbent material. Dispose of absorbent in accordance with local, state and federal regulations. 7. HANDLING AND STORAGE Handling Keep away from open flames, hot surfaces and sources of ignition. Vapors may accumulate readily and may ignite explosively. Ensure adequate ventilation. Avoid breathing spray mist. Do not smoke. Turn off other sources of ignition prior to use and until all vapors have dissipated. Do not puncture or incinerate. Do not take internally. Keep out of reach of children. Check to make sure that all equipment is properly grounded and installed to satisfy electrical classification requirements. Standard safety precautions should be observed when handling this material. Storage Containers exposed to extreme heat may burst. Keep away from heat and sources of ignition. Store in temperatures below 120 degrees F (50 degrees C) . Keep away from direct sunlight. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Propane 1000 ppm 1800 mg/m3 - 1000 ppm - Butane 800 ppm - - 1000 ppm Toluene 200 ppm 300 ppm 20 ppm - Isopropyl alcohol 400 ppm 980 mg/m3 - 200 ppm 400 ppm Diacetone alcohol 50 ppm 240 mg/m3 - 50 ppm - Acetone 1000 ppm 2400 mg/m3 - 500 ppm 750 ppm Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Use in a well ventilated area. Hygiene measures Wash hands before eating or using the washroom. Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes and clothing. Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Wear a NIOSH approved organic vapor/particulate respirator. Hand Protection Gloves are not required in normal use. The following gloves are recommended for prolonged or repeated contact: . Chemical resistant gloves. Eye protection Wear safety glasses with side shields. Skin and body protection None necessary under normal conditions 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Colorless Odor No information available Odor Threshold No information available pH No data available Specific Gravity 0.80 Vapor pressure No data available Density 6.65 lb/gal; 796 g/l Vapor density >Air Evaporation Rate >1 (Ether Water solubility No data available VOC Content 71.70% Partition Coefficient (n-octanol/water) No data available Boiling point/range °C < -18 - 172 Boiling point/range °F < 0 - 342 Melting point/range °C No data available Melting point/range °F No data available Flash point °C < -17.78 Flash point °F < 0 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid None known. Incompatability None known. Hazardous Decomposition Products Carbon dioxide. Carbon monoxide. Page 2 / 4 Product code 83570 Product name Expunge Page 362 of 1235 Page 362 of 1235 Page 362 of 1235 Page 362 of 1235 ---PAGE BREAK--- Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Propane 74-98-6 - - 658 mg/L Butane 106-97-8 - - 658 g/m3 Toluene 108-88-3 636 mg/kg 8390 mg/kg 12.5 mg/L Isopropyl alcohol 67-63-0 4396 mg/kg 12800 mg/kg 16000 ppm Diacetone alcohol 123-42-2 4 g/kg - - Acetone 67-64-1 - - 50100 mg/m3 Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity See Section 2 . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity Possible risk of harm to the unborn fetus. Target Organ Effects See Section 2. Reports have associated prolonged overexposure to solvents with permanent brain and nervous system damage. Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Propane Not Listed Not Listed Not Listed Not Listed Not Listed Butane Not Listed Not Listed Not Listed Not Listed Not Listed Toluene A4 Not Listed Not Listed Not Listed Not Listed Isopropyl alcohol A4 Not Listed Not Listed Not Listed Not Listed Diacetone alcohol Not Listed Not Listed Not Listed Not Listed Not Listed Acetone A4 Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Aquatic toxicity Do not let product enter drains. Harmful to aquatic organisms 13. DISPOSAL CONSIDERATIONS Disposal Information As supplied, this product is a RCRA Hazardous Waste . Waste must be tested for ignitability to determine EPA hazardous waste numbers. Do not puncture or incinerate. Depressurize before disposal. Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT Consumer commodity, ORM-D. TDG Consumer commodity, ORM-D. 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Isopropyl alcohol Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Propane Listed Listed Not Listed Butane Listed Listed Not Listed Toluene Listed Listed Development al Female Reproductive Isopropyl alcohol Listed Listed Not Listed Diacetone alcohol Listed Listed Not Listed Acetone Not Listed Listed Not Listed Chemical Name Type Toluene - 108-88-3 Female Reproductive Page 3 / 4 Acetone Microtox Data Photobacterium phosphoreum EC50=14500 mg/L (15 min) Water Flea Data Daphnia magna EC505.46 - 9.83 mg/L (48 h) Daphnia magna EC50=11.5 mg/L (48 h) Water Flea Data Daphnia magna EC5010294 - 17704 mg/L (48 h) Daphnia magna EC5012600 - 12700 mg/L (48 h) Toluene Isopropyl alcohol Product name Expunge Microtox Data Photobacterium phosphoreum EC50=35390 mg/L (5 min) Microtox Data Photobacterium phosphoreum EC50=19.7 mg/L (30 min) Water Flea Data Daphnia magna EC50=13299 mg/L (48 h) Product code 83570 Page 363 of 1235 Page 363 of 1235 Page 363 of 1235 Page 363 of 1235 ---PAGE BREAK--- WARNING: This product contains a chemical(s) known to the state of California to cause cancer and birth defects or other reproductive harm International Inventories Chemical Name EINECS DSL NDSL TSCA Propane X X - X Butane X X - X Toluene X X - X Isopropyl alcohol X X - X Diacetone alcohol X X - X Acetone X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION HMIS Health - 2 Flammability - 3 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product code 83570 Product name Expunge Page 364 of 1235 Page 364 of 1235 Page 364 of 1235 Page 364 of 1235 ---PAGE BREAK--- Page 365 of 1235 Page 365 of 1235 Page 365 of 1235 Page 365 of 1235 ---PAGE BREAK--- Page 366 of 1235 Page 366 of 1235 Page 366 of 1235 Page 366 of 1235 ---PAGE BREAK--- Page 367 of 1235 Page 367 of 1235 Page 367 of 1235 Page 367 of 1235 ---PAGE BREAK--- Page 368 of 1235 Page 368 of 1235 Page 368 of 1235 Page 368 of 1235 ---PAGE BREAK--- Page 369 of 1235 Page 369 of 1235 Page 369 of 1235 Page 369 of 1235 ---PAGE BREAK--- Page 370 of 1235 Page 370 of 1235 Page 370 of 1235 Page 370 of 1235 ---PAGE BREAK--- Page 371 of 1235 Page 371 of 1235 Page 371 of 1235 Page 371 of 1235 ---PAGE BREAK--- Page 372 of 1235 Page 372 of 1235 Page 372 of 1235 Page 372 of 1235 ---PAGE BREAK--- Page 373 of 1235 Page 373 of 1235 Page 373 of 1235 Page 373 of 1235 ---PAGE BREAK--- Page 374 of 1235 Page 374 of 1235 Page 374 of 1235 Page 374 of 1235 ---PAGE BREAK--- Page 375 of 1235 Page 375 of 1235 Page 375 of 1235 Page 375 of 1235 ---PAGE BREAK--- Page 376 of 1235 Page 376 of 1235 Page 376 of 1235 Page 376 of 1235 ---PAGE BREAK--- Page 377 of 1235 Page 377 of 1235 Page 377 of 1235 Page 377 of 1235 ---PAGE BREAK--- Page 378 of 1235 Page 378 of 1235 Page 378 of 1235 Page 378 of 1235 ---PAGE BREAK--- Page 379 of 1235 Page 379 of 1235 Page 379 of 1235 Page 379 of 1235 ---PAGE BREAK--- Page 380 of 1235 Page 380 of 1235 Page 380 of 1235 Page 380 of 1235 ---PAGE BREAK--- Page 381 of 1235 Page 381 of 1235 Page 381 of 1235 Page 381 of 1235 ---PAGE BREAK--- AMSOIL Material Safety Data Sheet Date Issued/Revised: June 18, 2003 Supersedes: October 8, 2002 Product Code: AFF, Formula 4-Stroke Engine Oil, API CH-4/SJ, SAE 0W-40 Page 1 of 4 Section 1: Product and Company Identification Manufacturer: AMSOIL, Inc. Telephone: 925 Tower Avenue CHEMTREC (Spill Emergency Only): 1-[PHONE REDACTED] Superior, WI 54880 Information: [PHONE REDACTED] AMSOIL Product Code ………AFF Product Label Formula 4-Stroke Engine Oil, SAE 0W-40 Product LUBRICATING OIL Section 2: Composition/Information on Ingredients OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200) This product is not formulated to contain ingredients that have exposure limits exceeding those established by US agencies. *See Section 8 for exposure limits. Section 3: Hazards Identification POTENTIAL HEALTH EFFECTS: Minor eye, inhalation and skin irritant. *See Section 11 for toxicological information. Section 4: First Aid Measures EYE: Flush with water for 15-20 minutes. Seek medical attention if irritation develops. SKIN: Wash immediately with soap and water. Remove contaminated clothing and launder before reuse. Discard shoes and leather articles saturated with the product. Obtain medical advice if irritation occurs. INHALATION: Remove exposed person to fresh air. If breathing is labored give oxygen. If breathing has stopped apply artificial respiration. Get immediate medical attention. INGESTION: DO NOT INDUCE VOMITING. If conscious, give 2 glasses of water. If vomiting does occur, keep head below hips to reduce risk of aspiration. Get immediate medical attention. Section 5: Fire Fighting Measures FLAMMABILITY PROPERTIES: Flash 435°F(224°C) Method ASTM D-92 LFL/UFL Determined Auto-ignition Temperature Determined EXTINGUISHING MEDIA: Carbon dioxide, dry chemical, and alcohol foam. FIREFIGHTING EQUIPMENT: Full bunker gear recommended including a positive pressure self-contained breathing apparatus. Red Flammability 1 Blue Health 1 Yellow Reactivity 0 White Special N/A NFPA & HMIS Rating Page 382 of 1235 Page 382 of 1235 Page 382 of 1235 Page 382 of 1235 ---PAGE BREAK--- AMSOIL Material Safety Data Sheet Date Issued/Revised: June 18, 2003 Supersedes: October 8, 2002 Product Code: AFF, Formula 4-Stroke Engine Oil, API CH-4/SJ, SAE 0W-40 Page 2 of 4 Section 6: Accidental Release Measures Isolate spill area. Provide adequate ventilation. Wear appropriate personal protection. Recover free product for recycle and/or disposal. Add sand, earth or other suitable absorbent to spill area. Prevent entry into sewers and waterways. Check under Transportation and Labeling (DOT/CERCLA) and Other Regulator Information Section (SARA) for hazardous substances to determine regulatory reporting requirements for spill. Section 7: Handling and Storage HANDLING: Keep containers closed. Avoid contact with eyes, skin or clothing. Wash hands after handling. Empty container may retain product residue which may exhibit hazards of product. STORAGE: Keep away from heat or flame. Section 8: Exposure Controls/Personal Protection VENTILATION: Use adequate general or local exhaust ventilation to keep airborne concentrations below exposure limits. RESPIRATORY: Use a NIOSH approved respirator when necessary. SKIN: Use Viton or Nitrile gloves to avoid prolonged or repeated skin contact. EYE: Use splash goggles or face shield where splashing is expected or can occur. EXPOSURE LIMITS: The Threshold Limit Value (TLV) of 5 mg/m3 is suggested for oil mist. Section 9: Physical and Chemical Properties Physical Liquid Boiling Point Not Determined Freezing/Melting Point -65°F(-54°C) Vapor Pressure Not Determined Vapor Density (Air=1) Evaporation Not Determined Solubility in Specific Gravity (Water=1) 0.8540 Density, Volatility VOC pH Neutral Coefficient of Water/Oil Distribution Not Determined Mild, Bland, Hydrocarbon Odor Odor Threshold Not Determined Appearance Amber Transparent Colored Liquid Viscosity, cSt @ 100°C Viscosity, cSt @ Viscosity Index Page 383 of 1235 Page 383 of 1235 Page 383 of 1235 Page 383 of 1235 ---PAGE BREAK--- AMSOIL Material Safety Data Sheet Date Issued/Revised: June 18, 2003 Supersedes: October 8, 2002 Product Code: AFF, Formula 4-Stroke Engine Oil, API CH-4/SJ, SAE 0W-40 Page 3 of 4 Section 10: Stability and Reactivity STABILITY: Stable under moderately elevated temperatures and pressures. INCOMPATIBILITY: Avoid contact with strong oxidants. HAZARDOUS POLYMERIZATION: Will not occur. HAZARDOUS DECOMPOSITION OF PRODUCT: Toxic oxides of carbon, aldehydes and other products of incomplete combustion. Section 11: Toxicological Information ACUTE EXPOSURE Eye Irritation: Moderate to strong eye irritation. Based on data from components or similar material. Skin Irritation: Not expected to be a primary skin irritant. Based on data from components or similar material. Prolonged or repeated skin contact as from clothing wet with material may cause dermatitis. may include redness, edema, drying, defatting, and cracking of the skin. Respiratory Irritation: If material is misted or if vapors are generated from heating, exposure may cause irritation of mucous membranes and the upper respiratory tract similar to that observed with mineral oil. Based on data from components or similar materials. Under good industrial hygiene practices where all exposure limits are observed, respiratory irritation should not be a problem. CHRONIC EXPOSURE Chronic Toxicity: No data available to indicate product present at greater than 1.0% are chronic health hazards. Carcinogenicity: No data available to indicate product present at greater than 0.1% are a carcinogenic hazard. Mutagenicity: No data available to indicate product present at greater than 1.0% present a mutagenic or genotoxic hazard. Reproductive Toxicity: No data available to indicate product present at greater than 1.0% present a reproductive hazard. Teratogenicity: No data available to indicate product present at greater than 1.0% present a teratogenic hazards. ADDITIONAL INFORMATION Exposure Limits: Under conditions which may generate mists, observe the OSHA PEL of 5 mg per cubic meter. Page 384 of 1235 Page 384 of 1235 Page 384 of 1235 Page 384 of 1235 ---PAGE BREAK--- AMSOIL Material Safety Data Sheet Date Issued/Revised: June 18, 2003 Supersedes: October 8, 2002 Product Code: AFF, Formula 4-Stroke Engine Oil, API CH-4/SJ, SAE 0W-40 Page 4 of 4 Section 12: Ecological Information No data available on the adverse effects of this product on the environment. Section 13: Disposal Considerations If this product as supplied becomes a waste, it does not meet the criteria of a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Section 14: Transport Information This product is not classified as hazardous material for DOT shipping. For further information relative to spills resulting from transportation incidents, refer to the latest DOT Emergency Response Guidebook for Hazardous Materials. Section 15: Regulatory Information U.S. Federal Regulations OSHA Table Base Stock(mist) TSCA Not Applicable CERCLA 40 CFR 302.4 Zinc Compounds @1.62-2.5%, RQ 1 lb SARA Title III Section 302 Extremely Hazardous Not Applicable Section 311/312 Fire Hazard Reactive Hazard No Release of Pressure No Acute Health Hazard Chronic Health Hazard No Section 313 Toxic Chemical Not Applicable U.S. State Regulations California (Prop 65) Does not contain chemicals known to the state of California to cause cancer. International Regulations WHMIS All components listed Section 16: Other Information The information and recommendations contained herein are, to the best of AMSOIL’s knowledge and belief, accurate and reliable as of the date issued. AMSOIL makes no warranty or guarantee, expressed or implied, of their accuracy or reliability, and AMSOIL shall not be liable for any loss or damage based upon the criteria supplied by the developers of these rating systems, together with AMSOIL’s interpretation of the available data. Page 385 of 1235 Page 385 of 1235 Page 385 of 1235 Page 385 of 1235 ---PAGE BREAK--- AMSOIL Material Safety Data Sheet Date Issued/Revised: October 18, 2006 Supersedes: January 4, 2006 Section 1: Product and Company Identification Manufacturer: AMSOIL, Inc. Telephone: 925 Tower Avenue CHEMTREC (Spill Emergency Only): 1-[PHONE REDACTED] Superior, WI 54880 Information: [PHONE REDACTED] AMSOIL Product Code ………AFF Product Label Formula 4-Stroke Engine Oil, SAE 0W-40 Product OIL NFPA Rating Section 2: Composition/Information on Ingredients White Special N/A Red Flammability 1 Yellow Instability 0 Blue Health 1 OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200) This product is not formulated to contain ingredients that have exposure limits exceeding those established by US agencies. *See Section 8 for exposure limits. Section 3: Hazards Identification POTENTIAL HEALTH EFFECTS: Minor eye, inhalation and skin irritant. *See Section 11 for toxicological information. Section 4: First Aid Measures EYE: Flush with water for 15-20 minutes. Seek medical attention if irritation develops. SKIN: Wash immediately with soap and water. Remove contaminated clothing and launder before reuse. Discard shoes and leather articles saturated with the product. Obtain medical advice if irritation occurs. INHALATION: Remove exposed person to fresh air. If breathing is labored give oxygen. If breathing has stopped apply artificial respiration. Get immediate medical attention. INGESTION: DO NOT INDUCE VOMITING. If conscious, give 2 glasses of water. If vomiting does occur, keep head below hips to reduce risk of aspiration. Get immediate medical attention. Section 5: Fire Fighting Measures FLAMMABILITY PROPERTIES: Flash Point Method ASTM D-92 LFL/UFL Determined Auto-ignition Temperature Determined EXTINGUISHING MEDIA: Carbon dioxide, dry chemical, alcohol foam and water fog. SPECIAL PROCEDURES: Water or foam may cause frothing. Use water to keep fire exposed surface cool. Water spray may be used to flush spills away from exposure. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water. PROTECTIVE EQUIPMENT: For fires in enclosed areas, fire fighters must use self-contained breathing apparatus. Product Code: AFF, Formula 4-Stroke Engine Oil, API SL/CF, SAE 0W-40 Page 1 of 4 Page 386 of 1235 Page 386 of 1235 Page 386 of 1235 Page 386 of 1235 ---PAGE BREAK--- AMSOIL Material Safety Data Sheet Date Issued/Revised: October 18, 2006 Supersedes: January 4, 2006 Section 6: Accidental Release Measures Eliminate all ignition sources. Ventilate all confined spaces. Keep public away. Recover free product. Add sand, earth or other suitable absorbent to spill area. Keep product out of sewers and waterways. Check under Transportation and Labeling (DOT/CERCLA) and Other Regulator Information Section (SARA) for reporting requirements. Section 7: Handling and Storage HANDLING: Keep containers closed. Avoid contact with eyes, skin or clothing. Wash hands after handling. Empty container may retain product residue which may exhibit hazards of product. STORAGE: Keep away from heat or flame. Section 8: Exposure Controls/Personal Protection VENTILATION: Use adequate general or local exhaust ventilation to keep airborne concentrations below exposure limits. RESPIRATORY: Use a NIOSH approved respirator when necessary. SKIN: Use Viton or Nitrile gloves to avoid prolonged or repeated skin contact. EYE: Use splash goggles or face shield where splashing is expected or can occur. EXPOSURE LIMITS: The Threshold Limit Value (TLV) of 5 mg/m3 is suggested for oil mist. Section 9: Physical and Chemical Properties Physical State Liquid Boiling Point Determined Freezing/Melting Point -60°F(-51°C) Vapor Pressure Determined Vapor Density Evaporation Rate Determined Solubility in Water Specific Gravity (Water=1) Density, Volatility (Volume) Neutral Coefficient of Water/Oil Determined Odor Mild, Bland, Hydrocarbon Odor Odor Threshold Determined Amber Transparent Colored Liquid Viscosity, cSt @ 100°C Viscosity, cSt @ 40°C Viscosity Index Product Code: AFF, Formula 4-Stroke Engine Oil, API SL/CF, SAE 0W-40 Page 2 of 4 Page 387 of 1235 Page 387 of 1235 Page 387 of 1235 Page 387 of 1235 ---PAGE BREAK--- AMSOIL Material Safety Data Sheet Date Issued/Revised: October 18, 2006 Supersedes: January 4, 2006 Section 10: Stability and Reactivity STABILITY: Stable under moderately elevated temperatures and pressures. INCOMPATIBILITY: Avoid contact with strong oxidants. HAZARDOUS POLYMERIZATION: Will not occur. HAZARDOUS DECOMPOSITION OF PRODUCT: Toxic oxides of carbon, aldehydes and other products of incomplete combustion. Section 11: Toxicological Information ACUTE EXPOSURE Eye Irritation: Moderate to strong eye irritation. Based on data from components or similar material. Skin Irritation: Not expected to be a primary skin irritant. Based on data from components or similar material. Prolonged or repeated skin contact as from clothing wet with material may cause dermatitis. may include redness, edema, drying, defatting, and cracking of the skin. Respiratory Irritation: If material is misted or if vapors are generated from heating, exposure may cause irritation of mucous membranes and the upper respiratory tract similar to that observed with mineral oil. Based on data from components or similar materials. Under good industrial hygiene practices where all exposure limits are observed, respiratory irritation should not be a problem. CHRONIC EXPOSURE Chronic Toxicity: No data available to indicate product present at greater than 1.0% are chronic health hazards. Carcinogenicity: No data available to indicate product present at greater than 0.1% are a carcinogenic hazard. Mutagenicity: No data available to indicate product present at greater than 1.0% present a mutagenic or genotoxic hazard. Reproductive Toxicity: No data available to indicate product present at greater than 1.0% present a reproductive hazard. Teratogenicity: No data available to indicate product present at greater than 1.0% present a teratogenic hazards. ADDITIONAL INFORMATION Exposure Limits: Under conditions which may generate mists, observe the OSHA PEL of 5 mg per cubic meter. Section 12: Ecological Information No data available on the adverse effects of this product on the environment. Product Code: AFF, Formula 4-Stroke Engine Oil, API SL/CF, SAE 0W-40 Page 3 of 4 Page 388 of 1235 Page 388 of 1235 Page 388 of 1235 Page 388 of 1235 ---PAGE BREAK--- AMSOIL Material Safety Data Sheet Date Issued/Revised: October 18, 2006 Supersedes: January 4, 2006 Section 13: Disposal Considerations If this product as supplied becomes a waste, it does not meet the criteria of a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Section 14: Transport Information This product is not classified as hazardous material for DOT shipping. For further information relative to spills resulting from transportation incidents, refer to the latest DOT Emergency Response Guidebook for Hazardous Materials. Section 15: Regulatory Information U.S. Federal Regulations OSHA Table Z Base Stock(mist) TSCA Applicable CERCLA 40 CFR Zinc Compounds @1.62-2.5%, RQ 1 lb SARA Title III Section 302 Extremely Applicable Section 311/312 Fire Hazard Reactive Release of Acute Health Chronic Health Section 313 Toxic Applicable U.S. State Regulations California (Prop 65) Does not contain chemicals known to the state of California to cause cancer. International Regulations WHMIS components listed Section 16: Other Information The information and recommendations contained herein are, to the best of AMSOIL’s knowledge and belief, accurate and reliable as of the date issued. AMSOIL makes no warranty or guarantee, expressed or implied, of their accuracy or reliability, and AMSOIL shall not be liable for any loss or damage based upon the criteria supplied by the developers of these rating systems, together with AMSOIL’s interpretation of the available data. Product Code: AFF, Formula 4-Stroke Engine Oil, API SL/CF, SAE 0W-40 Page 4 of 4 Page 389 of 1235 Page 389 of 1235 Page 389 of 1235 Page 389 of 1235 ---PAGE BREAK--- TechPac, LLC. P.O. Box 24830 – Lexington, KY 40524 Material Safety Data Sheet GardenTech Sevin-5 Ready-To-Use 5% Dust Bug Killer This product is used by Homeowners and Professionals September 2009 Product Code(s): S7000, S7000D, S7007, S7008, S7009 SECTION 1 - PRODUCT IDENTIFICATION Medical Emergency: [PHONE REDACTED] Product Information: [PHONE REDACTED] Transportation or Spill: [PHONE REDACTED] EPA Reg. Number: 432-1209-71004 Chemical Name: Carbaryl: Trade Names: Sevin® Brand Carbaryl Insecticide SECTION 2 - COMPOSITION Component Percentage ACGIH Exposure Limit OSHA Exposure Limit Carbaryl [63-25-2] 5% TLV - 5 mg/m3 PEL - 5 mg/m3 Quartz [14808-60-7] 47 – 57% 0.1 mg/m3 from respirable fraction TWA respirable fraction formula = 10 mg/m3/% SiO2 + 2 Mica [12001-26-2] 16 – 24% None established 3 mg/m3 from respirable fraction Kaolin Clay [1332-58-7] 1 – 5% None established 5 mg/m3 from respirable fraction [12269-78-2] > 35% None established 15 mg/m3 total dust 5 mg/m3 respirable dust SECTION 3 - HEALTH HAZARD DATA EMERGENCY OVERVIEW A tan to brown powder with a slight chemical odor that is: • Harmful if swallowed. • May cause mechanical eye or skin irritation in high concentrations. • Prolonged inhalation may cause lung injury. • Extremely toxic to aquatic and estuarine invertebrates. ROUTE(S) OF ENTRY: Ingestion, inhalation, and skin contact. EYES: May mechanical irritation in high concentrations. SKIN: May cause mechanical skin irritation in high concentrations. INGESTION: Harmful if swallowed. INHALATION: May cause irritation of the eyes, nose, throat and mucus membranes upon inhalation of dust. Prolonged inhalation may cause lung injury. SIGNS AND This product causes reversible cholinesterase inhibition. Overexposure to this product may lead to rapid onset of nausea, vomiting, abdominal pain, diarrhea, pinpoint pupils, blurred vision, profuse sweating, salivation, tremors, muscle twitching, and temporary paralysis. In severe poisoning, respiratory depression and convulsion may occur. SECTION 4 - FIRST AID IF SWALLOWED: Call a physician or Poison Control Center. Drink 1 or 2 glasses of water and induce vomiting by touching back of throat with finger or blunt object. Do not induce vomiting or give anything by mouth to an unconscious person. IF IN EYES: Flush eyes with plenty of water. Call a physician if irritation persists. IF ON SKIN: Wash with plenty of soap and water. Get medical attention. IF INHALED: Remove victim to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. Get medical attention. NOTE TO PHYSICIAN: Carbaryl is a moderate reversible cholinesterase inhibitor. Atropine is antidotal. DO NOT use 2-PAM, opiates, or cholinesterase-inhibiting drugs. 110 Page 390 of 1235 Page 390 of 1235 Page 390 of 1235 Page 390 of 1235 ---PAGE BREAK--- TechPac, LLC. P.O. Box 24830 – Lexington, KY 40524 Material Safety Data Sheet GardenTech Sevin-5 Ready-To-Use 5% Dust Bug Killer This product is used by Homeowners and Professionals September 2009 Product Code(s): S7000, S7000D, S7007, S7008, S7009 SECTION 5 - FIRE & EXPLOSION HAZARDS FLASH POINT: Dry mixture >5000 F EXTINGUISHING MEDIA: Water Fog; CO2 or Chemical Foam SPECIAL FIRE FIGHTING PROCEDURES: Firefighters should wear NIOSH/MSHA approved self-contained breathing apparatus and full protective clothing. Keep unnecessary people away, isolate hazard area and deny entry. Dike area to prevent runoff and contamination of water sources. Dispose of fire control water later. UNUSUAL FIRE OR EXPLOSION HAZARDS: None known HAZARDOUS DECOMPOSITION MATERIALS (Under Fire Conditions): Nitrogen oxides, Carbon oxides and Methyl isocyanate (trace amounts, no adverse health effects expected). SECTION 6 - SPILL AND LEAK PROCEDURES SMALL SPILL: Put spilled solid in a waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and state regulation. Decontaminate tools and equipment following cleanup. Avoid creation of dusty conditions. LARGE SPILL: Use a shovel to put the material into a proper waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and state regulations. ENVIRONMENTAL AND REGULATORY REPORTING: If spilled on the ground, the affected area should be scraped clean and placed in an appropriate container for disposal. Runoff from dilution water may cause pollution. Prevent material from entering public sewer system or any waterways. SECTION 7 - STORAGE & HANDLING Storage: Store in original container. Store in an area that is cool, dry, away from foodstuffs or animal feed, out of reach of children and animals. Storage Temperatures: Normal warehouse temperatures <100 degrees F. Handling: Avoid contact with eyes, skin or clothing. Avoid breathing dust. Was thoroughly with soap and water after handling. SECTION 8 - SPECIAL PROTECTION INFORMATION ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, use ventilation to keep exposure to airborne contaminants below the exposure limit. If local exhaust is used, a capture velocity of 150-200 fpm is recommended. RESPIRATORY PROTECTION: When airborne concentrations meet or exceed regulated limits, use a NIOSH/MSHA approved cartridges/canisters approved for use against pesticides EYE/FACE PROTECTION: Chemical safety glasses with side shields or splash-proof goggles. SKIN PROTECTION: Chemical-resistant gloves. OTHER PROTECTION: Long-sleeved shirt and long pants. Shoes plus socks. SECTION 9 - PHYSICAL DATA Physical Form: Solid Color: Natural peanut shell tan/brown Odor: Slight Chemical Vapor Pressure: N/E Not available Bulk Density: 33 lbs/ft3 Specific Gravity: Not available Melting Point: Not available pH: Not available Water Solubility: Insoluble SECTION 10 - REACTIVITY DATA Stability: Stable. Polymerization: Will not occur Conditions To Avoid: Elevated storage above temperatures 100 degrees will lead to non-hazardous decomposition. Keep containers closed. Store product in garage or shed; not in home. Keep out of reach of children. Decomposition Products: Dense smoke presents breathing problem. Self contained breathing apparatus may be required in containing fire. Nitrogen oxides, Carbon Monoxide and Dioxide will form in fire conditions. 110 Page 391 of 1235 Page 391 of 1235 Page 391 of 1235 Page 391 of 1235 ---PAGE BREAK--- TechPac, LLC. P.O. Box 24830 – Lexington, KY 40524 Material Safety Data Sheet GardenTech Sevin-5 Ready-To-Use 5% Dust Bug Killer This product is used by Homeowners and Professionals September 2009 Product Code(s): S7000, S7000D, S7007, S7008, S7009 SECTION 11 - TOXICOLOGICAL INFORMATION ACUTE INGESTION: Not available ACUTE ABSORPTION: Not available ACUTE INHALATION: Not available EYE IRRITATION(rabbit): Not available SKIN IRRITATION (rabbit): Not available DERMAL SENSITIZATION (guinea pig): Not available CHRONIC TOXICITY: Carbaryl has been shown to cause tumors in laboratory animals in lifetime feeding studies. Carbaryl, when administered by various routes, at doses toxic to the maternal animals, has been shown to produce developmental toxicity in a number of species. Carbaryl produces no teratogenic effects in the absence of maternal toxicity. Sparse literature specifically addressing dust exposures are complicated by concurrent silica exposures. Absent free silica, a low category pneumoconiosis (with little respiratory disability) is probable in prolonged, high dust concentrations. Kaolin: Published literature suggests that extremely high exposures to kaolin dust over a prolonged period of time can lead to a low category pneumoconiosis (with little respiratory disability) in a small number of workers. Silica: Overexposure to respirable silica dust can cause silicosis, a form of progressive pulmonary fibrosis. “Inhalable” silica (quartz) is listed as a Group 1 carcinogen (lung) based on “sufficient evidence” in occupationally exposed humans and sufficient evidence in animals. silica is also listed by the NTP as a substance reasonably anticipated to be a carcinogen. Some studies have not demonstrated a cancer association and considerable controversy exists concerning the IARC and NTP classification. SECTION 12 - ECOLOGICAL INFORMATION This product is extremely toxic to aquatic and estuarine invertebrates. For terrestrial uses, do not apply directly to water, or to areas where surface water is present or to intertidal areas below the mean high water mark, except under the forest canopy and use on rice. Discharge from rice fields may kill aquatic and estuarine invertebrates. Do not contaminate water by cleaning of equipment or disposal of wastes. This product is highly toxic to bees exposed to direct treatment or residues on blooming crops or weeds. Do not apply this product or allow it to drift to blooming crops or weeds if bees are visiting the treatment area. ECOTOXICOLOGICAL INFORMATION: The following data is based on the technical grade active ingredient (TGAI). Dietary concentration Mallard duck LC50 > 5,000 mg/kg/8 days Dietary concentration Bobwhite Quail LC50 > 5,000 mg/kg/8 days Rainbow trout LC50 = 1,950 ug/l/96 hr Bluegill sunfish LC50 = 6,760 ug/l/96 hr SECTION 13 - DISPOSAL Wastes resulting from this product may be disposed of on site or at an approved waste disposal facility. Completely empty bag into application equipment. Then dispose of empty bag in a sanitary landfill or by incineration, or, if allowed by state and local authorities, by burning. If burned, stay out of smoke. For containers one pound or less: Do not reuse container. Wrap and discard in trash. 110 Page 392 of 1235 Page 392 of 1235 Page 392 of 1235 Page 392 of 1235 ---PAGE BREAK--- TechPac, LLC. P.O. Box 24830 – Lexington, KY 40524 Material Safety Data Sheet GardenTech Sevin-5 Ready-To-Use 5% Dust Bug Killer This product is used by Homeowners and Professionals September 2009 Product Code(s): S7000, S7000D, S7007, S7008, S7009 SECTION 14 - TRANSPORTATION Proper Shipping Name: GardenTech Sevin-5 Ready-to-Use 5% Dust Bug Killer Technical Name (if applicable): UN Initial & Number: Not regulated Class: Packing Group: RQ: Not required Hazard Labels: None required SECTION 15 - REGULATORY INFORMATION FEDERAL REGULATIONS: TSCA Inventory Status: This product is excluded from TSCA because it is solely for FIFRA regulated use SARA Title III Hazard Classes: Fire Hazard - No Reactive Hazard - No Release of Pressure - No Acute Health Hazard - Yes Chronic Health Hazard - Yes SARA Title III Section 313: Carbaryl, CAS# 63-25-2, 5% is a SARA Title III, Section 313 Chemical. CERCLA; Reportable Quantity: Carbaryl, 100 lbs., 2000 lbs of product IARC, NTP, OSHA Carcinogens: Quartz (IARC and NTP) STATE REGULATIONS: California Proposition 65: This product contains the following ingredients for which the State of California has found to cause cancer, birth defects or other reproductive harm, which would require a warning under the statute: Quartz RTK: Quartz Florida: Quartz Minnesota: Quartz Massachusetts: Quartz New Jersey: Quartz SECTION 16 - OTHER INFORMATION NOTICE FROM TECHPAC, LLC. The information contained herein is offered only as a guide to the handling of this specific material. Since such information does not relate to use of the material with any other material or in any process, any person using this information must determine for himself its suitability for any particular application. The buyer and user assumes all risk and liability of use, storage and/or handling of this product not in accordance with the terms of the product label. ABBREVIATIONS KEY: N/A = Not available or applicable N/E = Not established TLV=Threshold Limit Value PEL= Permissible Exposure Limit 110 Page 393 of 1235 Page 393 of 1235 Page 393 of 1235 Page 393 of 1235 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 08-May-2012 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 16321 Product name Gel Threadlocker - RED Recommended Use Adhesive Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions Pre-existing skin, eye, or respiratory conditions may be aggravated by exposure to this product. Principal Routes of Exposure Inhalation. Skin contact. Eyes. Potential health effects Eyes Moderately irritating to the eyes. Skin Prolonged skin contact may cause skin irritation and/or dermatitis. Inhalation May cause irritation of respiratory tract. Ingestion No information available. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Saccharin 81-07-2 3-5 Cumene hydroperoxide 80-15-9 1-3 4. FIRST AID MEASURES Eye contact Flush with plenty of water for at least 15 minutes. Seek medical attention. Skin contact Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. Ingestion Do Not induce vomiting. Keep calm. Seek medical attention. Inhalation Remove to fresh air. Seek medical attention if irritation persists. 5. FIRE FIGHTING MEASURES Flash point °C > 148 Flash point °F > 300 Method Pensky-Martens C.C. Autoignition temperature °C Not Applicable Autoignition temperature °F Not Applicable Flammability Limits in Air) Upper No data available Lower No data available Suitable extinguishing media Foam. Dry chemical powder. Carbon dioxide. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Specific hazards No information available . Hazardous decomposition products See Section 10. Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Soak up with inert absorbent material. Prevent product from entering drains. Take up mechanically and collect in suitable container for disposal. 7. HANDLING AND STORAGE Page 1 / 3 Emergency Overview No information available Page 394 of 1235 Page 394 of 1235 Page 394 of 1235 Page 394 of 1235 ---PAGE BREAK--- 7. HANDLING AND STORAGE Handling Avoid contact with skin, eyes and clothing. Avoid breathing vapors or mists. Keep away from open flames, hot surfaces and sources of ignition. Storage Store in temperatures below 100 degrees F. Keep away from heat and sources of ignition. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Saccharin - - - - Cumene hydroperoxide - - - - Ventilation and Environmental Controls Provide local exhaust ventilation. Hygiene measures General industrial hygiene practice. Respiratory protection None necessary under normal conditions. Use NIOSH approved respirator if TLV limit is exceeded. Hand Protection Polyethylene Gloves. Rubber gloves. Neoprene gloves. Eye protection ANSI approved safety glasses or splash goggles with face shield are recommended. Skin and body protection None necessary under normal conditions 9. PHYSICAL AND CHEMICAL PROPERTIES Form Liquid Color Red Odor Mild Odor Threshold Not Applicable pH Not Applicable Specific Gravity 1.1 @ 75F (23C) Vapor pressure < 5mmHg Vapor density >1 (Air = 1) Evaporation Rate Not Applicable Water solubility soluble VOC Content 7.85 Partition Coefficient (n-octanol/water) Not Applicable Boiling point/range °C > 148 Boiling point/range °F > 300 Melting point/range °C Not Applicable Melting point/range °F Not Applicable Flash point °C > 148 Flash point °F > 300 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid None known. Incompatability Strong oxidizers. Reducing agents. Alkalies. Copper. Aluminum. Iron Oxide (rust) . Zinc. Hazardous Decomposition Products Irritating organic vapors. Carbon oxides. Nitrogen oxides (NOx). Sulfur oxides. Polymerization Hazardous polymerization does not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Saccharin 81-07-2 - - - Cumene hydroperoxide 80-15-9 382 mg/kg 500 mg/kg 220 ppm Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity See Section 2 . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects See Section 2 Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Saccharin Not Listed Not Listed Not Listed Not Listed Not Listed Cumene hydroperoxide Not Listed Not Listed Not Listed Not Listed Not Listed Page 2 / 3 Product code 16321 Product name Gel Threadlocker - RED Page 395 of 1235 Page 395 of 1235 Page 395 of 1235 Page 395 of 1235 ---PAGE BREAK--- 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products As supplied, this product is classified as non-hazardous waste according to RCRA regulations. Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT Not Regulated. TDG Not Regulated 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Saccharin Listed Cumene hydroperoxide Listed State Regulations Chemical Name New Jersey - RTK - RTK California Prop. 65 Saccharin Not Listed Listed Not Listed Cumene hydroperoxide Listed Listed Not Listed International Inventories Chemical Name EINECS DSL NDSL TSCA Saccharin X X - X Cumene hydroperoxide X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION NFPA Health - 1 Flammability - 1 Reactivity - 1 HMIS Health - 1 Flammability - 1 Physical Hazard - 1 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 3 / 3 Product name Gel Threadlocker - RED Cumene hydroperoxide Water Flea Data Daphnia magna EC50=7 mg/L (24 h) Product code 16321 Page 396 of 1235 Page 396 of 1235 Page 396 of 1235 Page 396 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET This MSDS complies with OSHA'S Hazard Communication Standard 29 CFR 1910.1200 and OSHA Form 174 IDENTITY AND MANUFACTURER'S INFORMATION NFPA Rating: Health-;2 Flammability-;1 Reactivity-;0 Special- HMIS Rating: Health-;2 Flammability-;1 Reactivity-;0 Personal Protection- Supplier Name: WECHEM INC. Address: 5734 Susitna Drive Harahan, LA 70123 IDENTITY (Trade name as used on label): GERM X PROPER SHIPPING NAME: CONSUMER COMMODITY , ORM-D Date Prepared: 11/07/02 Prepared By: CHARITO KUYLEN MSDS Number: D300A Revision – 11/07/02 Information Calls: (504) 733-1152 EMERGENCY RESPONSE NUMBER: 1-[PHONE REDACTED] NOTICE: JUDGMENT BASED ON INDIRECT TEST DATA SECTION 1 - MATERIAL IDENTIFICATION AND INFORMATION COMPONENTS-CHEMICAL NAMES AND COMMON NAMES (Hazardous Components 1% or greater; Carcinogens 0.1% or greater) CAS Number SARA 313 % WT OSHA PEL (ppm) ACGIH TLV (ppm) Carcinogen Ref. Source HYDROGEN CHLORIDE 7647-01-0 5-15 5 5 D NONIONIC SURFACTANT 26027-38-3 NO N/A N/A D AMMONIUM CHLORIDE N/A NO N/A N/A D SECTION 2 - PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: 2120F Specific Gravity (H2O=1): 1.130+/0.05 Vapor Pressure PSIG @ 70 DEG. F (AEROSOLS): N/A Vapor Pressure (Non-Aerosols)(mm Hg and Temperature): N/A Vapor Density (Air = N/A Evaporation Rate: (H2O=1)N/A Solubility in Water: COMPLETE Water Reactive: NO Appearance and Odor: THICK CLEAR BLUE LIQUID WITH CHARACTERISTIC ODOR pH: LESS THAN 1 SECTION 3 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY as per CPSC FLAME EXTENSION TEST (aerosols): N/A Auto Ignition T perature em N/A Flamma Limits in Air by % in Volume: bility % LEL: N/A % UEL: N/A FLASH POINT AND METHOD USED: NONE TO BOILING (TCC) EXTINGUISHER MEDIA: FOAM, DRY CHEMICAL, CARBON DIOXIDE, WATER. SPECIAL FIRE FIGHTING PROCEDURES: SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING IF NEEDED. Unusual Fire & Explosion Hazards: N/A SECTION 4 - REACTIVITY HAZARD DATA STABILITY STABLE [ ] UNSTABLE HAZARDOUS POLYMERIZATION [ ] WILL [ X ] WILL NOT OCCUR Incompatibility (Mat. to avoid): STRONG ALKALIS, MOST METALS, BLEACHES AND OTHER XIDIZING AGENTS O Conditions to Avoid: CONTACT WITH STRONG ALKALIS, MOST METALS, BLEACH AND OTHER OXIDIZING AGENTS Hazardous Decomposition Products: HYDROGEN OR CHLORINE GAS SECTION 5 - HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: [ X ] INHALATION [ X ] INGESTION [ X ] SKIN ABSORPTION [ X ] EYE [ ] NOT HAZARDOUS CUTE EFFECTS A Inhalation: MAY CAUSE IRRITATION TO MUCOUS, MEMBRANES OF THE NOSE, THROAT AND LUNGS. Eye Contact: CAUSES SEVERE IRRITATION, MIST CAN CAUSE TEARING. POSSIBLE WELLING OF THE CONJUCTIVA , AND CORNEAL INJURY. S Skin Contact: SKIN IRRITANT. PROLONGED OR REPEATED EXPOSURE CAN CAUSE DERMATITIS. Ingestion: MAY BE IRRITATING OR CORROSIVE TO THE MOUTH, THROAT AND UPPER GASTROINTESTINAL TRACT. CHRONIC EFFECTS: Medical Conditions Generally Aggravated by Exposure: EXISTING EYE, SKIN OR UPPER RESPIRATORY CONDITIONS. EMERGENCY FIRST AID PROCEDURES Eye Contact: FLUSH WITH WATER FOR 15 MINUTES. SEEK MEDICAL ATTENTION. COVER WITH MOIST MAGNESIA OR BAKING SODA. Skin Contact: WASH WITH SOAP AND WATER. IF IRRITATED, SEEK MEDICAL ATTENTION. COVER WITH MOIST MAGNESIA OR BAKING SODA. Inhalation: REMOVE TO FRESH AIR. RESUSCITATE IF NECESSARY. GET MEDICAL ATTENTION. Ingestion: DO NOT INDUCE VOMITING. DRINK TWO LARGE GLASSES OF WATER OR A TEASPOONFUL OR MORE OF MAGNESIA OR CHALK. GET IMMEDIATE MEDICAL ATTENTION. SECTION 6 - CONTROL AND PROTECTIVE MEASURES Respiratory Protection (specify type): ADEQUATE VENTILATION Protective Gloves: ACID PROOF Eye Protection: SAFETY GLASSES, GOGGLES Ventilation Requirements: GENERAL SHOULD BE SUFFICIENT. LOCAL EXHAUST MAY BE NECESSARY IN SOME OPERATIONS. Other Protective Clothing & Equipment: APRON, BOOTS: DEPENDING ON EXTENT OF EXPOSURE. Hygienic Work Practices: WASH WITH SOAP AND WATER BEFORE HANDLING FOOD. SECTION 7 - PRECAUTIONS FOR SAFE HANDLING AND USE Steps To Be Taken If Material Is Spilled Or Released: ABSORB WITH SUITABLE MEDIUM. Waste Disposal Methods: DISPOSE OF ACCORDING TO LOCAL, STATE OR FEDERAL REGULATIONS Precautions To Be Taken In Handling & Storage: HANDLE ALL CONTAINERS CAREFULLY. Other Precautions &/or Special Hazards: KEEP OUT OF REACH OF CHILDREN. READ & FOLLOW LABEL DIRECTIONS. We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. Chemical Listed a ] Animal Data Only s Carcinogen or Potential Carcinogen. NTP IARC Monograph OSHA Not Listed [e N/A = NOT AVAILABLE N/D = NOT DETERMINED Page 397 of 1235 Page 397 of 1235 Page 397 of 1235 Page 397 of 1235 ---PAGE BREAK--- Spectrum Lubricants Corporation 500 Industrial Park Drive Selmer, TN 38375 MATERIAL SAFETY DATA SHEET SECTION 1 IDENTIFICATION Product Trade Name: GL-5 85W140 Multi-Purpose Gear Oil Revision Date: 10-14-04 Phone Number: (731) 645-4972 Fax Number: (731) 645-4810 E-mail Address: [EMAIL REDACTED] Emergency Number: [PHONE REDACTED] after 5:00 p.m. Chemical Family: Petroleum Lubricating Oil NOTE: Petroleum lubricating oils with a flashpoint above 200°F, are not regulated by D.O.T. standards. SECTION 2 HAZARDOUS INGREDIENTS Name CAS # Approximate % Regulatory Agency Exposure Limit Base Stock (mixture) 64742-54-7 85-95 OSHA/ACGIH 5mg/m3 Mist E.P. Additive proprietary 5-10 OSHA/ACGIH 5mg/m3 Mist Pour Depressant 64742-54-7 < 1 OSHA/ACGIH 5mg/m3 Mist HMIS/NFPA CODES Health Flammability Reactivity Protective Equipment 1 1 0 C, D See Section 6, Chronic Effects, for potenti al over-exposure hazard. SECTION 3 PHYSICAL DATA Vapor Pressure (mmHg) at 20°C: Specific Gravity at 60°F: 0.95 Water Solubility: Negligible Boiling Point: wide range Vapor Density (Air=1): > 1 Evaporation Rate: < 1 Odor: Mild Petroleum Odor Appearance: Dark amber color fluid Viscosity at 100°C CST: 24.0 SECTION 4 FIRE AND EXPLOSION HAZARDS Flash Point: 470°F Fire Point: 495°F Extinguishing Media: Water Fog, Chemical Foam, Dry Chemical Powder, and CO2 Special Firefighting Procedures: Cool exposed containers with water spray. Avoid breathing fumes. Unusual Fire and Explosion Hazards: Pressure increase in over heated closed containers. Cool containers with water spray. Page 398 of 1235 Page 398 of 1235 Page 398 of 1235 Page 398 of 1235 ---PAGE BREAK--- SECTION 5 REACTIVITY DATA Stability: Stable Incompatibility: Avoid strong oxidants. Polymerization: Will not occur. Thermal Decomposition: Partial burning produces fumes, smoke and carbon monoxide. SECTION 6 HEALTH HAZARD DATA Inhalation: Inhalation of fumes may result in dizziness, headache and respiratory irritation. Eye Contact: Contact with eyes may cause minimal irritation. Skin Contact: Mild irritation may occur with prolonged or repeated contact. Ingestion: toxic. Pulmonary aspiration hazard if vomiting occurs. TLV: 5mg/m3 as mist. ACGIH 1984-85. Chronic Effects: Product has a low order of acute oral toxicity. Ingredients of this product are not listed as potential carcinogens in N.T.P. Annual Report on Carcinogens, I.A.R.C. Monographs, or by O.S.H.A. HCS (vii). SECTION 7 SPECIAL PROTECTION INFORMATION Ventilation Procedure: Ventilate as needed to comply with exposure limit. Gloves Protection: Use impervious gloves to avoid repeated/prolonged skin contact. Eye Protection: Use goggles/face shield to avoid eye contact. Work/Hygienic Practices: If clothing becomes contaminated, change to fresh clean clothing. Do not wear until thoroughly laundered. SECTION 8 SPILL OR LEAK PROCEDURES Spill Procedures: Remove ignition sources. Recover liquid. Add absorbent to spill area. Ventilate confined spaces. Advise authorities if product enters sewers, etc. Waste Disposal: Assure conformity with applicable disposal regulations. Dispose of absorbed material at approved waste site. SECTION 9 SPECIAL PRECAUTIONS Handling and Storage Precautions: Keep containers closed when not in use. Do not handle or store near heat or flames. Use chemical resistant gloves and apron. EMERGENCY FIRST AID PROCEDURES Skin: Wash skin with soap and warm water. Wash clothing before re-use. Eye: If splashed into eyes flush eyes with clear water for five minutes. Inhalation: If overcome by fumes remove from exposure immediately. Page 399 of 1235 Page 399 of 1235 Page 399 of 1235 Page 399 of 1235 ---PAGE BREAK--- Oral: If ingested, do not induce vomiting. Call a physician. ΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩΩ The data presented herein is based upon tests and information, which we believe to be reliable. However, users should make their own investigations to determine the suitability of the information for their particular purpose. Page 400 of 1235 Page 400 of 1235 Page 400 of 1235 Page 400 of 1235 ---PAGE BREAK--- Page 401 of 1235 Page 401 of 1235 Page 401 of 1235 Page 401 of 1235 ---PAGE BREAK--- Page 402 of 1235 Page 402 of 1235 Page 402 of 1235 Page 402 of 1235 ---PAGE BREAK--- Page 403 of 1235 Page 403 of 1235 Page 403 of 1235 Page 403 of 1235 ---PAGE BREAK--- Page 404 of 1235 Page 404 of 1235 Page 404 of 1235 Page 404 of 1235 ---PAGE BREAK--- I M A T E R I A L S A F E T Y D A T A S H E E T I I SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION I PRODUCT NAME : GLOSS BLUE 0003910 IDENTIFICATION NUMBER: V2408 830 DATE PRINTED : 10/24/01 PRODUCT USE/CLASS : OVERALL SPRAY PAINT SUPPLIER: MANUFACTURER: Rust-Oleum Corporation Rust-Oleum Corporation 11 Hawthorn Parkway 11 Hawthorn Parkway Vernon Hills, Illinois Vernon Hills, Illinois 60061 USA 60061 USA (847) 367-7700 Rust-Oleum Corp. (847) 367-7700 Rust-Oleum Corp. 8:00 AM-4:30 PM/24-hr Emer.Assist 8:00 AM-4:30 PM/24-hr Emer.Assist PREPARER: MTM, PHONE: [PHONE REDACTED], PREPARE DATE: 10/24/01 I SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS I WT/WT % ITEM CHEMICAL NAME CAS NUMBER LESS THAN 01 ACETONE 67-64-1 35.0 % 02 LIQUIFIED PETROLEUM GAS 68476-85-7 30.0 % 03 XYLENE 1330-20-7 15.0 % 04 TOLUENE 108-88-3 5.0 % 05 100-41-4 5.0 % 06 VM&P NAPHTHA 64742-89-8 5.0 % 07 Titanium Dioxide 13463-67-7 5.0 % EXPOSURE LIMITS ACGIH OSHA MEXICAN ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN 01 750 PPM 1000 PPM 750 PPM N.E. N.E. NO 02 1000 PPM N.E. 1000 PPM N.E. N.E. NO 03 100PPM 150PPM 100PPM N.E. 100 PPM YES Page 405 of 1235 Page 405 of 1235 Page 405 of 1235 Page 405 of 1235 ---PAGE BREAK--- 04 50 PPM 150 PPM 200 PPM 300 PPM N.E. YES 05 100 PPM 125 PPM 100 PPM N.E. N.E. YES 06 300 PPM N.E. 300 ppm N.E. N.E. NO 07 10 mg/m3 N.E. 15 mg/m3 N.E. N.E. NO (See Section 16 for abbreviation legend) (Continued on Page 2) Product: V2408 830 Preparation Date: 10/24/01 Page 2 I SECTION 3 - HAZARDS IDENTIFICATION I EMERGENCY OVERVIEW Harmful if inhaled. Harmful if swallowed. Extremely flammable liquid and vapor. Vapors may cause flash fire or explosion. Harmful if inhaled. May effect the brain or nervous system causing dizziness, headache or nausea. Contents Under Pressure. EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin irritation. Prolonged or repeated contact may cause skin irritation. EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing vapors or mists. High vapor concentrations are irritating to the eyes, nose, throat and lungs. EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed. Aspiration hazard if swallowed; can enter lungs and cause damage. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: May cause central nervous system disorder (e,g.,narcosis involving a loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. Overexposure to toluene in laboratory animals has been associated with liver abnormalities, kidney, lung and spleen damage. Effects in humans have included liver and cardiac abnormalities. PRIMARY ROUTE(S) OF ENTRY: SKIN ABSORPTION INHALATION EYE CONTACT Page 406 of 1235 Page 406 of 1235 Page 406 of 1235 Page 406 of 1235 ---PAGE BREAK--- I SECTION 4 - FIRST AID MEASURES I FIRST AID - EYE CONTACT: Hold eyelids apart and flush with plenty of water for at lease 15 minutes. Get medical attention. FIRST AID - SKIN CONTACT: Wash with soap and water. Get medical attention if irritation develops or persists. FIRST AID - INHALATION: If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately. FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. (Continued on Page 3) Product: V2408 830 Preparation Date: 10/24/01 Page 3 I SECTION 5 - FIRE FIGHTING MEASURES I FLASH POINT: -99 F LOWER EXPLOSIVE LIMIT: 0.9 % UPPER EXPLOSIVE LIMIT: 12.8 % AUTOIGNITION TEMPERATURE: ND EXTINGUISHING MEDIA: DRY CHEMICAL FOAM UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20 DEG. F. - EXTREMELY FLAMMABLE LIQUID AND VAPOR! Water spray may be ineffective. Closed containers may explode when exposed to extreme heat due to buildup of steam. Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a source of ignition and flash back. Keep containers closed. Isolate from heat, electrical equipment, sparks and open flame. Perforation of the pressurized container may cause bursting of the can. Closed containers may explode when exposed to extreme heat. SPECIAL FIREFIGHTING PROCEDURES: Evacuate area and fight fire from a safe distance. I SECTION 6 - ACCIDENTAL RELEASE MEASURES I STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Evacuate the area, remove all sources of ignition and ventilate well. Contain spilled liquid with sand or earth. DO NOT use combustible materials such as Page 407 of 1235 Page 407 of 1235 Page 407 of 1235 Page 407 of 1235 ---PAGE BREAK--- sawdust. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. I SECTION 7 - HANDLING AND STORAGE I HANDLING: Wash thoroughly after handling. Wash hands before eating. Use only in a well-ventilated area. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing vapor or mist. STORAGE: Keep containers closed. Isolate from heat, electrical equipment, sparks and open flame. Do not store above 120 degrees F. Store large quantities in buildings designed and protected for storage of NFPA Class I flammable liquids. Contents under pressure. Do not expose to heat or store above 120 degrees F. (Continued on Page 4) Product: V2408 830 Preparation Date: 10/24/01 Page 4 I SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION I ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use explosion-proof ventilation equipment. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation. RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. Page 408 of 1235 Page 408 of 1235 Page 408 of 1235 Page 408 of 1235 ---PAGE BREAK--- SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection. EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids. OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application. HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. I SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES I BOILING RANGE : -34 - 285 F VAPOR DENSITY : Is heavier than air ODOR : SOLVENT ODOR THRESHOLD : ND APPEARANCE : LIQUID EVAPORATION RATE: Is faster than Ether SOLUBILITY IN H2O : SLIGHT FREEZE POINT : ND SPECIFIC GRAVITY: 0.8565 VAPOR PRESSURE : ND pH @ 0.0 % : ND PHYSICAL STATE : LIQUID VISCOSITY : ND COEFFICIENT OF WATER/OIL DISTRIBUTION: ND (See Section 16 for abbreviation legend) I SECTION 10 - STABILITY AND REACTIVITY I CONDITIONS TO AVOID: Avoid temperatures above 120 degrees F. Avoid all possible sources of ignition. (Continued on Page 5) Product: V2408 830 Preparation Date: 10/24/01 Page 5 I SECTION 10 - STABILITY AND REACTIVITY I INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies. HAZARDOUS DECOMPOSITION PRODUCTS: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition it emits acrid smoke and irritating fumes. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. Page 409 of 1235 Page 409 of 1235 Page 409 of 1235 Page 409 of 1235 ---PAGE BREAK--- STABILITY: This product is stable under normal storage conditions. I SECTION 11 - TOXICOLOGICAL PROPERTIES I COMPONENT TOXICOLOGICAL INFORMATION: CHEMICAL NAME LD50 LC50 ACETONE RAT 5800MG/KG RAT 50100MG/M^3 8H LIQUIFIED PETROLEUM GAS N.E. N.E. XYLENE RAT 4300MG/KG RAT 5000PPM 4HR TOLUENE RAT 5000MG/KG MOUSE 5320PPM 8HR RAT 3500MG/KG N.A. VM&P NAPHTHA N.D. N.D. Titanium Dioxide 24000mg/kg Rats 6820mg/m3 Rats I SECTION 12 - ECOLOGICAL INFORMATION I ECOLOGICAL INFORMATION: Product is a mixture of listed components. According to our raw material suppliers, all components are listed on the TSCA inventory as required or meet the polymer exemption as defined in Section 5.5.2 of the Toxic Substances Control Act. I SECTION 13 - DISPOSAL CONSIDERATIONS I DISPOSAL METHOD: Dispose of material in accordance to local, state and federal regulations and ordinances. Do not allow to enter storm drains or sewer systems. I SECTION 14 - TRANSPORTATION INFORMATION I DOT PROPER SHIPPING NAME: AEROSOL DOT TECHNICAL NAME: (Continued on Page 6) Product: V2408 830 Preparation Date: 10/24/01 Page 6 I SECTION 14 - TRANSPORTATION INFORMATION I Page 410 of 1235 Page 410 of 1235 Page 410 of 1235 Page 410 of 1235 ---PAGE BREAK--- DOT HAZARD CLASS: 2 HAZARD SUBCLASS: 1 DOT UN/NA NUMBER: UN1950 PACKING GROUP: RESP. GUIDE PAGE: 126 I SECTION 15 - REGULATORY INFORMATION I U.S. FEDERAL REGULATIONS: AS FOLLOWS - OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) CERCLA - SARA HAZARD CATEGORY: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER WT/WT % IS LESS THAN XYLENE 1330-20-7 15.0 % TOLUENE 108-88-3 5.0 % 100-41-4 5.0 % U.S. STATE REGULATIONS: AS FOLLOWS - NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components in this product: CHEMICAL NAME CAS NUMBER RESIN SOLUTION NOT AVAILABLE RIGHT-TO-KNOW: The following non-hazardous ingredients are present in the product at greater than CHEMICAL NAME CAS NUMBER RESIN SOLUTION NOT AVAILABLE Page 411 of 1235 Page 411 of 1235 Page 411 of 1235 Page 411 of 1235 ---PAGE BREAK--- (Continued on Page 7) Product: V2408 830 Preparation Date: 10/24/01 Page 7 I SECTION 15 - REGULATORY INFORMATION I CALIFORNIA PROPOSITION 65: WARNING: The chemical(s) noted below and contained in this product, are known to the state of California to cause cancer, birth defects or other reproductive harm: CHEMICAL NAME CAS NUMBER TOLUENE 108-88-3 INTERNATIONAL REGULATIONS: AS FOLLOWS - CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: A B5 D2A D2B I SECTION 16 - OTHER INFORMATION I HMIS RATINGS - HEALTH: FLAMMABILITY: REACTIVITY: PREVIOUS MSDS REVISION DATE: 06/28/00 LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined : No Information. Page 412 of 1235 Page 412 of 1235 Page 412 of 1235 Page 412 of 1235 ---PAGE BREAK--- The information contained on this MSDS has been checked and should be accurate. However, it is the responsibility of the user to comply with all Federal, State, and Local laws and regulations. Page 413 of 1235 Page 413 of 1235 Page 413 of 1235 Page 413 of 1235 ---PAGE BREAK--- IMPERIAL SUPPLIES LLC MSDS SHEET FOR 4021 Material Safety Data Sheet I I Date of issue: IRevision Date: 2 September IRevision Number: I2010 I Imperial Supplies Part Number: 0040210.pdf 1. PRODUCT AND COMPANY IDENTIFICATION Manufacturer: GOJO Industries, Inc. One GOJO Plaza, Suite 500 Akron, OH 44311 Telephone: Non-Emergency Phone: (330) 255-6000 MSDS Request Phone: (330) 255-6000 x8804 Emergency Phone: 1-[PHONE REDACTED] CHEMTREC Product Name: GOJO® ORIGINAL FORMULA HAND CLEANER Product Code(s): 1106-511 Recommended Use: UN-Number: Product Type: 2. HAZARDS IDENTIFICATION Appearance: White IPhysical State: IOdor: characteristic opaque gel I Isolvent odor Potential Health Effects Principle Routes of Exposure Acute Effects: Eyes IMay cause eye irritation. Skin INo irritation or reaction expected. Inhalation INot applicable. Ingestion IMay cause upset stomach, nausea (Abnormal entry Iroute). Notes: Chronic Effects: Eyes I Skin I Inhalation I Ingestion I Notes: Aggravated Medical Conditions Environmental Hazard 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical/Ingredient Name ICAS-No IWeight% IACGIH, IOSHA-PEIOther I I ITLV-TWA IL I Petroleum Distillates I64742-47-8 I< 40% I200 mg/m3 I I (vapor) I I I I I Mineral Oil (mist) I8042-47-5 I< 15% I5 mg/m3 I5 mg/m3I Mineral Spirits I8032-32-4 I< 5% I100 ppm I500 ppmI Propylene Glycol I57-55-6 I I I I I I I I I I I I I I I I I I I Notes Page 414 of 1235 Page 414 of 1235 Page 414 of 1235 Page 414 of 1235 ---PAGE BREAK--- 4. FIRST AID MEASURES General Advice Eyes IDo not rub eyes. Flush eyes thoroughly with water for I15 minutes. If condition worsens or irritation Ipersists, contact physician. Skin INot applicable. Inhalation INot applicable. Ingestion IDo not induce vomiting. Contact a physician or Poison IControl Center. Notes to Physician I Protection of I First-aiders I Notes I 5. FIRE-FIGHTING MEASURES Flammability/Flammable I properties I Flash point I>212°F/100°C Recommended Extinguishing I(X) Water Fog Media I(X) Alcohol Foam I(X) CO2 I(X) Dry Chemical I( ) Other Special Fire-Fighting INone known. Procedures I I Explosion Data INone known. Sensitivity to Mechanical I Impact I Sensitivity to Static I Discharge I I Specific Hazards from I Chemical I I Protective Equipment I NFPA IHealth Hazard: IFlammability: 2IInstability:IPhysical Hazard I1 I I0 I HMIS IHealth Hazard: IFlammability: 1IPhysical IPPE: None I1 I IHazard: 0 I 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Environmental Precautions Methods for Containment Methods for Cleaning Up Notes: No special requirements. Water clean up and rinse. CAUTION - WILL CAUSE SLIPPERY SURFACES. 7. HANDLING AND STORAGE Handling: Keep containers sealed. Use older containers first. Avoid freezing conditions. Storage: Store at normal room temperature away from reach of small children. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name IACGIH TLV IOSHA PEL INIOSH IDLH IOTHER Page 415 of 1235 Page 415 of 1235 Page 415 of 1235 Page 415 of 1235 ---PAGE BREAK--- I I I I I I I I I I I I Engineering Measures Personal Protective Equipment Eyes/Face INone required under normal conditions. Protection I Skin and Body INone required under normal conditions. Protection I Respiratory INone required under normal conditions. Protection I Ventilation/Other INone required under normal conditions. Hygiene Measures 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance IWhite opaque IOdor Icharacteristic Igel I Isolvent odor Odor Threshold I IPhysical State I Color I IViscosity I pH I9 typical IPercent Volatile, I I Iwt. % I Flash Point I>212°F/100°C IAuto-ignition I I ITemperature I Decomposition I IBoiling Point/ RangeI Temp I I I Melting I IFreezing Point I Point/Range I I I Flammability I IExplosion Limits I Specific Gravity I IWater Solubility I Solubility I IEvaporation Rate I Vapor Pressure I IVapor Density I VOC content, wt. I7 I I % I I I I I I Notes 10. STABILITY AND REACTIVITY Chemical Stability IStable/Non reactive product. Incompatible Products I Conditions to avoid I Hazardous Decomposition I Products I Hazardous Polymerization I Notes: Stable/Non reactive product. 11. TOXICOLOGY INFORMATION Acute Toxicity: No acute or chronic toxic effects expected when used according to directions. Product I Information I Inhalation I Eye Contact I Skin Contact I Ingestion I Chemical Name ILD50 Oral ILD50 Dermal ILC50 Inhalation I I I I I I Chronic ToxicityI Page 416 of 1235 Page 416 of 1235 Page 416 of 1235 Page 416 of 1235 ---PAGE BREAK--- Chemical Name IACGIH IIARC INTP IOSHA I I I I I I I I Target Organ Effects 12. ECOLOGICAL INFORMATION Ecotoxicity The Environmental impact of this product has been fully investigated Chemical NameIToxicity to IToxicity to ITox, to IDaphnia Magna IAlgea IFish IMicroorganismsI(water flea) I I I I I I I I I I I I Notes: No ecological or special considerations when used according to directions. Not considered environmentally harmful from normal dilution, expected usage and typical drainage to sewers, septic systems and treatment plants. 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods Contaminated Packaging US EPA Waste number Notes: No special considerations when disposed according to local, state and Federal regulations. 14. TRANSPORTATION INFORMATION Not classified as a hazardous material. DOT UN-Number I Proper Shipping nameI Hazard Class I Packing Group I Description I Emergency Response I Guide Number I TDG UN-Number I Proper Shipping nameI Hazard Class I Packing Group I Description I MEX I UN-Number I Proper Shipping nameI Hazard Class I Packing Group I Description I ICAO UN-Number I Proper Shipping nameI Hazard Class I Packing Group I Description I Page 417 of 1235 Page 417 of 1235 Page 417 of 1235 Page 417 of 1235 ---PAGE BREAK--- IATA UN-Number I Proper Shipping nameI Hazard Class I Packing Group I ERG Code I Description I IMDG/IMO UN-Number I Proper Shipping nameI Hazard Class I Packing Group I EmS No. I Description I RID UN-Number I Proper Shipping I name I Hazard Class I Packing Group I Classification CodeI Description I ADR/RID-Labels I ADR UN-Number I Proper Shipping I name I Hazard Class I Packing Group I Classification CodeI Description I ADR/RID-Labels I ADN UN-Number Proper Shipping name Hazard Class Packing Group Classification Code Special Provisions Description Hazard Labels Limited Quantity 15. REGULATORY INFORMATION International Inventories TSCA: All ingredients are listed or exempt per reference 15 USC 2602 (iv). Complies with current FDA regulations for cosmetic and/or over-the-counter drug products. DSL EINECS ENCS IECSC PICCS AICS U.S. Federal Regulations SARA 313 SARA 311/312 Hazard Categories Acute Health Hazard Page 418 of 1235 Page 418 of 1235 Page 418 of 1235 Page 418 of 1235 ---PAGE BREAK--- Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Clean Water Act CERCLA U.S. State Regulations U.S. State Right-to-Know Regulations International Regulations Canada WHMIS: Not controlled 16. OTHER INFORMATION Prepared By: Revision Date: 2 September 2010 Company: GOJO Industries, Inc. Revision number Telephone number: Non-Emergency Phone: (330) 255-6000 MSDS Request Phone: (330) 255-6000 x8804 Notes Other Information Disclaimer information: The information herein is based on data considered to be accurate as of the date of preparation of this material safety data sheet. However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and safety information. The user assumes all liability for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices or from any hazards inherent in the nature of the product. END OF MATERIAL SAFETY DATA SHEET Page 419 of 1235 Page 419 of 1235 Page 419 of 1235 Page 419 of 1235 ---PAGE BREAK--- PROGRESS IS OUR COMMITMENT THE EARTH OUR CONCERN CRC Industries Europe bvba Touwslagerstraat 1 9240 Zele - Belgium Tel (+32) 52 / 45 60 11 - Fax (+32) 52 / 45 00 34 Material Safety Data Sheet Regulation EC No 1907/2006 Art.31 Productname : GRAISSE BLANCHE MULTIFONCTIONS White Lithium Grease + PTFE Creationdate : 23.11.10 Ref.Nr.: AB32400-3-231110 Replaces: 28.07.10 1. IDENTIFICATION OF PRODUCT AND COMPANY Productname : GRAISSE BLANCHE MULTIFONCTIONS White Lithium Grease + PTFE Aerosol Application : Lubricants Company : CRC Industries Europe bvba Touwslagerstraat 1 9240 ZELE Belgium Tel.: (+32)(0)52/456011 Fax: (+32)(0)52/450034 E-mail : [EMAIL REDACTED] In case of emergency : (+32) (0)52/45 60 11 Subsidiaries Tel Fax CRC Industries Finland Asemanrinne 13, 08500 Lohja AS (+358)(0)19/32921 (+358)(0)19/383676 CRC Industries France 12, Bld des de Chateaubriant F-95102 Argenteuil Cédex (+33)(0)1/34112000 (+33)(0)1/34110996 CRC Industries Südring 9, 76473 Iffezheim (+49)(0)7229/3030 (+49)(0)7229/303266 CRC Industries Iberia Gremio del cuero S/N, 40195 (+34)921/427546 (+34)921/436270 7KH LP DJ H EH GLVSOD\ HG 7KH ILOH P D\ KDYH EHHQ P RYHG UHQDP HG RU GHOHWHG 9HULI\ WKDW WKH OLQN WR WKH FRUUHFW ILOH DQG 7KH LP DJ H EH GLVSOD\ HG 7KH ILOH P D\ KDYH EHHQ P RYHG UHQDP HG RU GHOHWHG 9HULI\ WKDW WKH OLQN WR WKH FRUUHFW ILOH DQG Page 420 of 1235 Page 420 of 1235 Page 420 of 1235 Page 420 of 1235 ---PAGE BREAK--- Subsidiaries Tel Fax Segovia CRC Industries Sweden 14, 43153 Mölndal (+46)(0)31/7068480 (+46)(0)31/273991 2. HAZARD IDENTIFICATION Health and Safety : Extremely Flammable (propane/butane propellant) Vapours may cause drowsiness and dizziness. Remark: Preparations classified as harmful on the basis of an aspiration hazard need not be labelled as harmful with R65 when placed on the market in aerosol containers or in containers fitted with a sealed spray attachment. (EU-Directive 67/548 Annex VI 9.4) Environment : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Other hazards : Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Without adequate ventilation formation of explosive mixtures may be possible. 3. COMPOSITION AND INFORMATION ON COMPONENTS Hazardous ingredient CAS-nbr. EINECS w/w % symbol R-phrases* Notes phenol carbolic acid monohydroxybenzene phenylalcohol 108-95-2 203-632-7 <0.01 T,C 23/24/25-34-48/20/ 21/22-68 A zinc oxide 1314-13-2 215-222-5 <1 N 50/53 B titanium dioxide 13463-67-7 236-675-5 <0.1 - - B Naphtha (petroleum), hydrotreated light (benzene<0.1%) 64742-49-0 265-151-9 <20 F,Xn,N 11-38-51/53-65-67 B,P Distillates (petroleum), hydrotreated heavy naphthenic; Baseoil - unspecified 64742-52-5 265-155-0 <20 Xi R36/37/38 L Hydrocarbons,C3-4- rich, petroleum distillate 68512-91-4 270-990-9 60-100 F+ 12 K Page 421 of 1235 Page 421 of 1235 Page 421 of 1235 Page 421 of 1235 ---PAGE BREAK--- Hazardous ingredient CAS-nbr. EINECS w/w % symbol R-phrases* Notes Petroleumgas (1,3- butadiene < 0.1%) zinc alkyl dithiophosphate 68649-42-3 272-028-3 <1 N 51/53 propionic acid % 79-09-4 201-176-3 <1 C 34 A Explanation notes A : substance with Community workplace exposure limit B : substance with national established workplace exposure limit K : not classified as carcinogen, less than 0.1% w/w 1,3- butadiene (Einecs-nr. 203-450-8) L : not classified as carcinogen, less than 3% DMSO extract as measured by IP 346 P : not classified as carcinogen, less than 0.1% w/w benzene (Einecs-nr. 200-753- 7) Explanation risk-phrases : see chapter 16) 4. FIRST AID MEASURES General Advice : The usual precautions for handling chemicals should be observed If any should occur, seek medical advice. Contact with eyes : If substance has got into eyes, immediately wash out with plenty of water Seek medical attention if irritation persists Contact with skin : Wash with water and soap. Seek medical attention if irritation persists Inhalation : Fresh air, keep warm and at rest. Seek medical attention if ill effects occur Page 422 of 1235 Page 422 of 1235 Page 422 of 1235 Page 422 of 1235 ---PAGE BREAK--- Ingestion : Ingestion is unlikely to occur If swallowed do not induce vomiting because of risk of aspiration into the lungs. If aspiration is suspected obtain immediate medical attention 5. FIRE-FIGHTING MEASURES Flash point (without propellant): < 0 °C Explosion limits : upper limit : Not available. lower limit : Not available. Extinguishing media : water, foam, carbon dioxide or dry agent Fire-fighting procedures : Keep container(s) exposed to fire cool, by spraying with water Unusual exposure hazard : Aerosols may explode if heated above 50°C 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Shut off all ignition sources Ensure adequate ventilation Environmental precautions : Do not allow to enter public sewers and watercourses If polluted water reaches drainage systems or water courses, immediately inform appropriate authorities Cleaning methods : Absorb spillage in suitable inert material 7. HANDLING AND STORAGE Handling procedures : Use only in well ventilated areas Keep away from heat and sources of ignition Do not spray on a naked flame or incandescent material. Do not pierce or burn aerosols, even after use. Do not breathe aerosols or vapours. Avoid contact with skin and eyes. Storage procedures : Pressurized container : protect from sunlight and do not expose to temperatures exceeding 50°C. Keep in a cool, dry, well ventilated place Keep out of reach of children. 8. EXPOSURE CONTROL AND PERSONAL PROTECTION Control procedures : Ensure adequate ventilation Keep away from heat and sources of ignition Take precautionary measures against static discharges Page 423 of 1235 Page 423 of 1235 Page 423 of 1235 Page 423 of 1235 ---PAGE BREAK--- Personal protection : It is advisable to take precautions to avoid contact with skin and eyes when handling the product. Use only in well ventilated areas inhalation : In case of insufficient ventilation, wear suitable respiratory equipment. (Filter type AX) hands and skin : Wear suitable protective gloves (nitrile) eyes : Wear safety goggles. Exposure limits : Hazardous ingredient CAS-nbr. method EU established exposure limits: phenol carbolic acid monohydroxybenzene phenylalcohol 108-95-2 TWA 2 ppm propionic acid % 79-09-4 TWA 10 ppm STEL 20 ppm 9. PHYSICAL AND CHEMICAL PROPERTIES (for aerosols without propellant) Apperance : physical state : Propane/butane propelled liquid. colour : White. odour : Solvent. Boiling point/range : 60-100 °C Relative density : 0.794 g/cm3 20°C). pH : Not applicable. Vapour pressure : Not available. Relative vapour density : 3 20°C). Solubility in water : Insoluble in water Flash point : < 0 °C Auto-ignition : > 200 °C Viscosity : Not available. Evaporation rate : Not available. 10. STABILITY AND REACTIVITY Conditions to be avoided : Pressurized container : protect from sunlight and do not expose to temperatures exceeding 50°C. Materials to be avoided : Strong oxidising agent Hazardous decomposition compounds : CO,CO2 Page 424 of 1235 Page 424 of 1235 Page 424 of 1235 Page 424 of 1235 ---PAGE BREAK--- 11. TOXICOLOGICAL INFORMATION Inhalation : Inhalation of solvent vapours may give rise to nausea, headaches and dizziness Ingestion : Ingestion is unlikely to occur After vomiting of swallowed product aspiration into lungs is likely. Solvents may induce chemical pneumonia. Skin contact : Prolonged skin contact will result in defatting of the skin, leading to irritation, and in some cases, dermatitis 12. ECOLOGICAL INFORMATION Other adverse effects : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do not allow to enter public sewers and watercourses 13. WASTE DISPOSAL Product : Do not discharge into drains or the environment, dispose to an authorised waste collection point. This material and its container must be disposed of in a safe way. Disposal should be in accordance with local, state or national legislation 14. TRANSPORT UN-number : 1950 Road/Rail - ADR/RID : UN1950 Aerosols Class : 2, PG : NA, Class code : 5F, Label : 2.1, Tunnel-code : Sea - IMDG : UN1950 Aerosols Class : 2, PG : NA, Label : 2.1 EmS F-D, S-U Air - IATA/ICAO : UN1950 Aerosols, flammable Class : 2, PG : NA, Label : 2.1 15. REGULATORY INFORMATION Warning symbol(s) : F+ : EXTREMELY FLAMMABLE Page 425 of 1235 Page 425 of 1235 Page 425 of 1235 Page 425 of 1235 ---PAGE BREAK--- Risk-phrase(s) : R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67: Vapours may cause drowsiness and dizziness. Safety-phrase(s) : S2: Keep out of the reach of children. S16: Keep away from sources of ignition - No smoking. S23: Do not breathe vapours/spray. S35: This material and its container must be disposed of in a safe way. S51: Use only in well-ventilated areas. Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Without adequate ventilation formation of explosive mixtures may be possible. Classified according to Dir. 2008/47/EC amendment of the aerosol dispenser directive 75/324/EEC. Classification according to EU-directive 99/45/EC 16. OTHER INFORMATION This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation. The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties. Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks, no part of these documents may be reproduced by any process without written permission from CRC. REVISIONS IN CHAPTRE : 2,3,4,7,8,15 Page 426 of 1235 Page 426 of 1235 Page 426 of 1235 Page 426 of 1235 ---PAGE BREAK--- *Explanation risk-phrases: R11: Highly flammable. R12: Extremely flammable. R23/24/25: Toxic by inhalation, in contact with skin and if swallowed. R34: Causes burns. RR36/37/38 R48/20/21/22: Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. R38: Irritating to skin. R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65: Harmful: may cause lung damage if swallowed. R67: Vapours may cause drowsiness and dizziness. R68: Possible risks of irreversible effects. This Material Safety Data Sheet may already have been revised at this moment for reason such as legislation, availability of components and newly acquired experiences. The latest and only valid version of this Material Safety Data Sheet will be sent to you upon simple request or can be found on our website : www.crcind.com. We recommend you to register on this website for this product so you will be able to receive any future updated version automatically. Page 427 of 1235 Page 427 of 1235 Page 427 of 1235 Page 427 of 1235 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Gunk Car & Truck Wash - Concentrated Product identifier Other means of identification VW5 SDS number VW5 Part No. 3402.90.5030 Tariff code Cleaner Recommended use None known. Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufacturer RSC Chemical Solutions Address 600 Radiator Road Company name Website Telephone Customer Service: (704) 821-7643 Technical: (704) 684-1811 Emergency phone number Emergency Telephone: (303) 623-5716 Emergency Contact: ([PHONE REDACTED]) E-mail United States Not available. Indian Trail, NC 28079 2. Hazard(s) identification Not classified. Physical hazards Not classified. Health hazards Not classified. Environmental hazards Not classified. OSHA defined hazards Label elements None. Hazard symbol Signal word None. Hazard statement The mixture does not meet the criteria for classification. Precautionary statement Prevention Observe good industrial hygiene practices. Response Wash hands after handling. Storage Store away from incompatible materials. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures The manufacturer lists no ingredients as hazardous according to OSHA 29 CFR 1910.1200. *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Move to fresh air. Call a physician if develop or persist. Inhalation Wash off with soap and water. Get medical attention if irritation develops and persists. Skin contact Rinse with water. Get medical attention if irritation develops and persists. Eye contact 1 / 6 Material name: Gunk Car & Truck Wash - Concentrated VW5 Version 01 Issue date: 06-23-2015 SDS US Page 428 of 1235 Page 428 of 1235 Page 428 of 1235 Page 428 of 1235 ---PAGE BREAK--- Rinse mouth. Get medical attention if occur. Ingestion Direct contact with eyes may cause temporary irritation. Most important acute and delayed Treat Indication of immediate medical attention and special treatment needed Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. General information 5. Fire-fighting measures Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Unsuitable extinguishing media During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Special protective equipment and precautions for firefighters Move containers from fire area if you can do so without risk. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Specific methods No unusual fire or explosion hazards noted. General fire hazards 6. Accidental release measures Keep unnecessary personnel away. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Stop the flow of material, if this is without risk. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid discharge into drains, water courses or onto the ground. Environmental precautions 7. Handling and storage Observe good industrial hygiene practices. Precautions for safe handling Store in original closed container. Keep out of the reach of children. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection No exposure limits noted for ingredient(s). Occupational exposure limits No biological exposure limits noted for the ingredient(s). Biological limit values Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Appropriate engineering controls Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles). Eye/face protection Skin protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Hand protection Wear suitable protective clothing. Other Dust mask. Respiratory protection Wear appropriate thermal protective clothing, when necessary. Thermal hazards 2 / 6 Material name: Gunk Car & Truck Wash - Concentrated VW5 Version 01 Issue date: 06-23-2015 SDS US Page 429 of 1235 Page 429 of 1235 Page 429 of 1235 Page 429 of 1235 ---PAGE BREAK--- Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Clear. Viscous. Liquid. Appearance Liquid. Physical state Liquid. Form Dark blue. Color Pleasant. Odor Odor threshold Not available. pH 7.5 - 8.5 @ 20°C Melting point/freezing point Not available. Initial boiling point and boiling range 212 °F (100 Flash point Not available. Evaporation rate Not available. Not applicable. Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower Not available. Flammability limit - upper Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 23 hPa Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Density 8.42 lb/gal Not explosive. Explosive properties Not oxidizing. Oxidizing properties Specific gravity 1.01 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Reactivity Material is stable under normal conditions. Chemical stability No dangerous reaction known under conditions of normal use. Possibility of hazardous reactions Contact with incompatible materials. Conditions to avoid Strong oxidizing agents. Incompatible materials No hazardous decomposition products are known. Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation No adverse effects due to inhalation are expected. 3 / 6 Material name: Gunk Car & Truck Wash - Concentrated VW5 Version 01 Issue date: 06-23-2015 SDS US Page 430 of 1235 Page 430 of 1235 Page 430 of 1235 Page 430 of 1235 ---PAGE BREAK--- Skin contact No adverse effects due to skin contact are expected. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Expected to be a low ingestion hazard. related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity Not available. Prolonged skin contact may cause temporary irritation. Skin corrosion/irritation Direct contact with eyes may cause temporary irritation. Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. This product is not expected to cause skin sensitization. Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. This product is not expected to cause reproductive or developmental effects. Reproductive toxicity Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. 12. Ecological information The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Ecotoxicity No data is available on the degradability of this product. Persistence and degradability No data available. Bioaccumulative potential No data available. Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Disposal instructions Dispose in accordance with all applicable regulations. Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Contaminated packaging 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. 4 / 6 Material name: Gunk Car & Truck Wash - Concentrated VW5 Version 01 Issue date: 06-23-2015 SDS US Page 431 of 1235 Page 431 of 1235 Page 431 of 1235 Page 431 of 1235 ---PAGE BREAK--- Not established. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Hazard categories SARA 302 Extremely hazardous substance Not listed. No SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated. Safe Drinking Water Act (SDWA) US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. Massachusetts RTK - Substance List Not regulated. US. New Jersey Worker and Community Right-to-Know Act Not listed. US. Worker and Community Right-to-Know Law Not listed. US. Rhode Island RTK Not regulated. US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Yes Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) Yes China Inventory of Existing Chemical Substances in China (IECSC) 5 / 6 Material name: Gunk Car & Truck Wash - Concentrated VW5 Version 01 Issue date: 06-23-2015 SDS US Page 432 of 1235 Page 432 of 1235 Page 432 of 1235 Page 432 of 1235 ---PAGE BREAK--- Country(s) or region Inventory name On inventory (yes/no)* Yes Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) Yes Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 06-23-2015 Issue date Version # 01 Health: 0 Flammability: 0 Physical hazard: 0 HMIS® ratings Health: 0 Flammability: 0 Instability: 0 NFPA ratings NFPA ratings 0 0 0 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Disclaimer 6 / 6 Material name: Gunk Car & Truck Wash - Concentrated VW5 Version 01 Issue date: 06-23-2015 SDS US Page 433 of 1235 Page 433 of 1235 Page 433 of 1235 Page 433 of 1235 ---PAGE BREAK--- Page 434 of 1235 Page 434 of 1235 Page 434 of 1235 Page 434 of 1235 ---PAGE BREAK--- Page 435 of 1235 Page 435 of 1235 Page 435 of 1235 Page 435 of 1235 ---PAGE BREAK--- Page 436 of 1235 Page 436 of 1235 Page 436 of 1235 Page 436 of 1235 ---PAGE BREAK--- HARVEY WILLIAM H CO HARVEY'S PIPE THREAD COMPOUND MSDS Safety Information FSC: 6850 MSDS Date: 03/28/1995 MSDS Num: LIIN: 00F056847 Product ID: HARVEY'S PIPE THREAD COMPOUND MFN: 01 Responsible Party Cage: 51947 Name: HARVEY WILLIAM H CO Address: 4334 S 67TH ST City: OMAHA NE 68117-1019 Info Phone Number: [PHONE REDACTED] Emergency Phone Number: [PHONE REDACTED] Review Ind: Y Published: Y Preparer Co. when other than Responsible Party Co. Cage: 51947 Name: WILLIAM H HARVEY CO Address: 4334 SOUTH 67TH ST City: OMAHA NE 68117-1019 Contractor Summary Cage: 51947 Name: WILLIAM H HARVEY CO Address: 4334 SOUTH 67TH ST City: OMAHA NE 68117-1019 Phone: [PHONE REDACTED] Ingredients Cas: 64742-52-5 RTECS PY8035001 Name: PETROLEUM OIL, HYDROTREATED HEAVY NAPHTHENIC DISTILLATE (PETROLEUM), PETROLEUM DISTILLATES, MINERAL OIL (SEVERE) Cas: 68649-95-6 RTECS 1006336LO Name: LINSEED OIL, OXIDIZED *98-3* Cas: 64741-52-2 RTECS PY8037000 Name: PETROLEUM OIL (GROUP 1 CARCINOGEN BY IARC) *98-3* Health Hazards Data Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: YES Page 437 of 1235 Page 437 of 1235 Page 437 of 1235 Page 437 of 1235 ---PAGE BREAK--- OSHA: NO Effects of Exposure: SKIN: MILD IRRITANT. INHALATION: RESPIRATORY IRRITATION. PROLONGED/REPEATED CONTACT W/SKIN MAY LEAD TO DERMATITIS. Explanation Of Carcinogenicity: SEE INGREDIENTS. Signs And Of Overexposure: IRRITATION, DIZZINESS, HEADACHE, DRY/DEFATTING OF SKIN, UNCONSCIOUSNESS First Aid: INHALATION: REMOVE FROM EXPOSURE. INGESTION: DON'T INDUCE VOMITING.EYES: FLUSH IMMEDIATELY W/COLD WATER. SKIN: WASH W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. Handling and Disposal Spill Release Procedures: SCOOP UP MATERIAL & PLACE IN TRASH CONTAINER. WASH DOWN W/SOAP & WATER. Waste Disposal Methods: DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. Handling And Storage Precautions: KEEP AWAY FROM ACIDS & EXTREME HEAT. KEEP OUT OF REACH OF CHILDREN. Fire and Explosion Hazard Information Flash Point Method: TCC Flash Point Text: 430F Extinguishing Media: DRY CHEMICAL, CO2, FOAM Fire Fighting Procedures: RECOMMEND SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard: NONE Control Measures Respiratory Protection: NONE Ventilation: AS NECESSARY TO PREVENT VAPOR BUILDUP. Protective Gloves: NONE REQUIRED Eye Protection: NONE Other Protective Equipment: CLEAN CLOTHES/APRON Work Hygienic Practices: MINIMIZE EXPOSURE & ALWAYS WASH WHEN EXPOSED. Physical/Chemical Properties B.P. Text: NONE Vapor Pres: 0.1 Vapor Density: >1 Spec Gravity: 1.75 Solubility in Water: INSOLUBLE Appearance and Odor: GRAY PASTE W/PETROLEUM ODOR Reactivity Data Stability Indicator: YES Stability Condition To Avoid: EXTREME HEAT Materials To Avoid: STRONG OXIDIZING AGENTS, ACIDS Hazardous Decomposition Products: BY BURNING: FUMES, SMOKE & CO Hazardous Polymerization Indicator: NO Toxicological Information Ecological Information Page 438 of 1235 Page 438 of 1235 Page 438 of 1235 Page 438 of 1235 ---PAGE BREAK--- MSDS Transport Information Regulatory Information Other Information HAZCOM Label Product ID: HARVEY'S PIPE THREAD COMPOUND Cage: 51947 Company Name: WILLIAM H HARVEY CO Street: 4334 SOUTH 67TH ST City: OMAHA NE Zipcode: 68117-1019 Health Emergency Phone: [PHONE REDACTED] Label Required IND: Y Date Of Label Review: 10/12/1999 Status Code: A Origination Code: G Hazard And Precautions: SKIN: MILD IRRITANT. INHALATION: RESPIRATORY IRRITATION. PROLONGED/REPEATED CONTACT W/SKIN MAY LEAD TO DERMATITIS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation. Page 439 of 1235 Page 439 of 1235 Page 439 of 1235 Page 439 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol Aerosol. GHS product identifier Product type Emergency telephone number (with hours of operation) Section 1. Identification : : : Code : AMHSC Supplier's details : Identified uses R MP HD Heavy Duty Metal Protector - Aerosol SAFETY DATA SHEET Conforms to HazCom 2012 - United States AMSOIL INC. One AMSOIL Center Superior, WI 54880 [PHONE REDACTED] CHEMTREC: Within USA and Canada: 1-[PHONE REDACTED] Outside USA and Canada: +1 [PHONE REDACTED] (collect calls accepted) (24/7) Rust Preventative and Lubricating Fluid. Date Version : : 09/15/2014 5 FLAMMABLE AEROSOLS - Category 1 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B Classification of the substance or mixture : Signal word : Danger Hazard statements : Extremely flammable aerosol. Causes eye irritation. Hazard pictograms : Precautionary statements Prevention : Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Pressurized container: Do not pierce or burn, even after use. Do not spray on an open flame or other ignition source. Wash hands thoroughly after handling. Response : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 Disposal : Not applicable. GHS label elements OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 2. Hazards identification 1/12 09/15/2014 : Date of issue Page 440 of 1235 Page 440 of 1235 Page 440 of 1235 Page 440 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC Hazards not otherwise classified : None known. Propane 10 - 30 74-98-6 Butane 10 - 30 106-97-8 Stoddard solvent 10 - 30 8052-41-3 Distillates, hydrotreated light 10 - 30 64742-47-8 Acetone 10 - 30 67-64-1 Ingredient name CAS number % Other means of identification : Not available. CAS number : Not applicable. Substance/mixture Product code : AMHSC CAS number/other identifiers : Mixture There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. United States Section 3. Composition/information on ingredients Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. Get medical attention if occur. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. If irritation persists, get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Get medical attention if occur. Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Section 4. First aid measures 2/12 09/15/2014 : Date of issue Page 441 of 1235 Page 441 of 1235 Page 441 of 1235 Page 441 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC Protection of first-aiders : It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Most important acute and delayed Inhalation : No known significant effects or critical hazards. May be irritating to mouth, throat and stomach. : Ingestion Skin contact : No known significant effects or critical hazards. Causes eye irritation. : Eye contact Over-exposure Skin contact Ingestion Inhalation Adverse may include the following: respiratory tract irritation coughing No known significant effects or critical hazards. No known significant effects or critical hazards. : : : Eye contact : Adverse may include the following: irritation watering redness Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide Extremely flammable aerosol. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 5. Fire-fighting measures 3/12 09/15/2014 : Date of issue Page 442 of 1235 Page 442 of 1235 Page 442 of 1235 Page 442 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : Environmental precautions Personal precautions, protective equipment and emergency procedures : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : Spill Section 6. Accidental release measures Protective measures Put on appropriate personal protective equipment (see Section Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Avoid breathing vapor or mist. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. : Precautions for safe handling Section 7. Handling and storage 4/12 09/15/2014 : Date of issue Page 443 of 1235 Page 443 of 1235 Page 443 of 1235 Page 443 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. : : Propane NIOSH REL (United States, 4/2013). TWA: 1800 mg/m³ 10 hours. TWA: 1000 ppm 10 hours. OSHA PEL (United States, 2/2013). TWA: 1800 mg/m³ 8 hours. TWA: 1000 ppm 8 hours. Butane NIOSH REL (United States, 4/2013). TWA: 1900 mg/m³ 10 hours. TWA: 800 ppm 10 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 800 ppm 8 hours. TWA: 1900 mg/m³ 8 hours. ACGIH TLV (United States, 6/2013). STEL: 1000 ppm 15 minutes. Stoddard solvent ACGIH TLV (United States, 6/2013). TWA: 525 mg/m³ 8 hours. TWA: 100 ppm 8 hours. NIOSH REL (United States, 4/2013). CEIL: 1800 mg/m³ 15 minutes. TWA: 350 mg/m³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 2900 mg/m³ 8 hours. TWA: 500 ppm 8 hours. Distillates, hydrotreated light ACGIH TLV (United States, 6/2013). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours. Acetone ACGIH TLV (United States, 3/2012). STEL: 1782 mg/m³ 15 minutes. STEL: 750 ppm 15 minutes. TWA: 1188 mg/m³ 8 hours. TWA: 500 ppm 8 hours. NIOSH REL (United States, 1/2013). TWA: 590 mg/m³ 10 hours. TWA: 250 ppm 10 hours. OSHA PEL (United States, 6/2010). TWA: 2400 mg/m³ 8 hours. TWA: 1000 ppm 8 hours. Ingredient name Exposure limits Appropriate engineering controls : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Control parameters Occupational exposure limits Section 8. Exposure controls/personal protection 5/12 09/15/2014 : Date of issue Page 444 of 1235 Page 444 of 1235 Page 444 of 1235 Page 444 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC Hand protection Use a properly fitted, air-purifying or supplied air respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Physical state Melting point / Pour point Vapor pressure Vapor density Liquid. [Aerosol.] Not available. >1 [Air = 1] Not available. Mild hydrocarbon. Odor pH Brown. Color Evaporation rate <1 (ether = 1) Flash point Closed cup: -104.44°C (-156°F) [Pensky-Martens.] Not available. Not available. Odor threshold : : : : : : : : : : Appearance Boiling point : -42.222 to 260°C (-44 to 500°F) Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Lower: 0.7% Upper: 13% Section 9. Physical and chemical properties 6/12 09/15/2014 : Date of issue Page 445 of 1235 Page 445 of 1235 Page 445 of 1235 Page 445 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC Relative density Solubility 0.7 Insoluble Auto-ignition temperature Not available. Not available. Viscosity Not available. Partition coefficient: n- octanol/water : : : : : Decomposition temperature : Not available. Type of aerosol : Spray Heat of combustion : 26.13 kJ/g Aerosol product Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability Reactive or incompatible with the following materials: oxidizing materials, acids and alkalis. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 10. Stability and reactivity Information on toxicological effects Acute toxicity Acetone LD50 Oral Rat 5800 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Stoddard solvent Eyes - Moderate irritant Rabbit - 24 hours 500 mg - Eyes - Mild irritant Human - 100 ppm - Acetone Eyes - Mild irritant Human - 186300 ppm - Eyes - Mild irritant Rabbit - 10 µL - Eyes - Moderate irritant Rabbit - 24 hours 20 mg - Eyes - Severe irritant Rabbit - 20 mg - Skin - Mild irritant Rabbit - 24 hours 500 mg - Skin - Mild irritant Rabbit - 395 mg - Product/ingredient name Result Score Exposure Observation Sensitization Species Section 11. Toxicological information 7/12 09/15/2014 : Date of issue Page 446 of 1235 Page 446 of 1235 Page 446 of 1235 Page 446 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC Carcinogenicity Specific target organ toxicity (single exposure) Acetone Category 3 Not applicable. Narcotic effects Name Category Route of exposure Target organs There is no data available. Information on the likely routes of exposure Inhalation : No known significant effects or critical hazards. May be irritating to mouth, throat and stomach. : Ingestion Skin contact : No known significant effects or critical hazards. Causes eye irritation. : Eye contact related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse may include the following: respiratory tract irritation coughing No known significant effects or critical hazards. No known significant effects or critical hazards. : : : Eye contact : Adverse may include the following: irritation watering redness Delayed and immediate effects and also chronic effects from short and long term exposure Specific target organ toxicity (repeated exposure) Aspiration hazard Name Result Stoddard solvent ASPIRATION HAZARD - Category 1 Distillates, hydrotreated light ASPIRATION HAZARD - Category 1 : Dermal contact. Eye contact. Inhalation. Ingestion. Potential acute health effects Potential immediate effects : No known significant effects or critical hazards. Short term exposure Potential delayed effects : No known significant effects or critical hazards. Potential immediate effects : No known significant effects or critical hazards. Long term exposure Potential delayed effects : No known significant effects or critical hazards. There is no data available. Classification Acetone - - - A4 - - Product/ingredient name ACGIH EPA NIOSH NTP IARC OSHA 8/12 09/15/2014 : Date of issue Page 447 of 1235 Page 447 of 1235 Page 447 of 1235 Page 447 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC No known significant effects or critical hazards. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Potential chronic health effects Numerical measures of toxicity Acute toxicity estimates There is no data available. LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Toxicity Product/ingredient name Species Result Exposure Persistence and degradability Soil/water partition coefficient (KOC) : There is no data available. Mobility in soil Distillates, hydrotreated light Acute LC50 2200 µg/l Fresh water Fish - Lepomis macrochirus 4 days Acetone Acute EC50 20.565 mg/L Marine water Algae - Ulva pertusa 96 hours Acute LC50 6000000 µg/l Fresh water Crustaceans - Gammarus pulex 48 hours Acute LC50 10000 µg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 100 mg/L Fresh water Fish - Pimephales promelas - Juvenile (Fledgling, Hatchling, Weanling) 96 hours Chronic NOEC 4.95 mg/L Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 0.016 ml/L Fresh water Crustaceans - Daphniidae 21 days Chronic NOEC 0.1 ml/L Fresh water Daphnia - Daphnia magna - Neonate 21 days There is no data available. Stoddard solvent 3.16 to 7.06 - high Acetone -0.23 - low Section 12. Ecological information 9/12 09/15/2014 : Date of issue Page 448 of 1235 Page 448 of 1235 Page 448 of 1235 Page 448 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. : Disposal methods United States - RCRA Toxic hazardous waste List Acetone 67-64-1 Listed U002 Ingredient CAS # Status Reference number Section 13. Disposal considerations Aerosols, flammable (each not exceeding 1 L capacity) 2.1 - Aerosols, flammable (each not exceeding 1 L capacity) 2.1 - Aerosols, flammable (each not exceeding 1 L capacity) UN1950 2.1 - UN1950 UN1950 The marine pollutant mark is not required when transported on inland waterways in sizes of ≤5 L or ≤5 kg or by road, rail, or inland air in non-bulk sizes. Reportable quantity 33333.3 lbs / 15133.3 kg [5711.1 gal / 21619 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. Remarks Limited quantity The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg. Emergency schedules (EmS) F-D, S-U Remarks Limited quantity The environmentally hazardous substance mark may appear if required by other transportation regulations. Remarks Limited quantity IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards No. Yes. No. DOT Classification Section 14. Transport information 10/12 09/15/2014 : Date of issue Page 449 of 1235 Page 449 of 1235 Page 449 of 1235 Page 449 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. : AERG : 126 U.S. Federal regulations The following components are listed: Propane; Stoddard solvent; Butane; Acetone Clean Air Act (CAA) 112 regulated flammable substances: Propane; Butane Massachusetts : : California Prop. 65 Clean Air Act Section 112 Hazardous Air Pollutants (HAPs) : Not listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Listed New York : The following components are listed: Acetone New Jersey : The following components are listed: Propane; Stoddard solvent; Butane; Acetone; Distillates, hydrotreated heavy naphthenic : The following components are listed: Propane; Stoddard solvent; Butane; Acetone State regulations SARA 302/304 SARA 304 RQ : Not applicable. SARA 311/312 Classification : Fire hazard Immediate (acute) health hazard Stoddard solvent 10 - 30 Yes. No. No. No. No. Acetone 10 - 30 Yes. No. No. Yes. No. Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients Section 15. Regulatory information United States inventory (TSCA 8b): All components are listed or exempted. No products were found. 11/12 09/15/2014 : Date of issue Page 450 of 1235 Page 450 of 1235 Page 450 of 1235 Page 450 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC No products were found. International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Montreal Protocol (Annexes A, B, C, E) Not listed. Ingredient name List name Status Stockholm Convention on Persistent Organic Pollutants Not listed. Ingredient name List name Status Rotterdam Convention on Prior Inform Consent (PIC) Not listed. Ingredient name List name Status Not listed. Ingredient name List name Status UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. Ingredient name List name Status History Prepared by : Date of issue mm/dd/yyyy Date of previous issue Version : : : 5 09/15/2014 06/15/2013 Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Section 16. Other information AMSOIL INC. 12/12 09/15/2014 : Date of issue Page 451 of 1235 Page 451 of 1235 Page 451 of 1235 Page 451 of 1235 ---PAGE BREAK--- 1. IDENTIFICATION Product identifier Product Name HIGH STRENGTH THREADLOCKER RED GEL 10 GR Other means of identification Product Code 27010 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Adhesive Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: [PHONE REDACTED] International Emergency: 00+1+ [PHONE REDACTED] Contract Number: MIS0003453 E-mail address [EMAIL REDACTED] 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Category 4 Acute toxicity - Dermal Category 4 Acute toxicity - Inhalation (Dusts/Mists) Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Specific target organ toxicity (repeated exposure) Category 2 Label elements Emergency Overview Page 1 / 8 Warning Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Revision Date 07-Apr-2015 SAFETY DATA SHEET Version 1 Page 452 of 1235 Page 452 of 1235 Page 452 of 1235 Page 452 of 1235 ---PAGE BREAK--- Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Wear protective gloves/protective clothing/eye protection/face protection Use only outdoors or in a well-ventilated area Do not breathe dust/fume/gas/mist/vapors/spray Precautionary Statements - Response Get medical advice/attention if you feel unwell Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician IF ON SKIN: Wash with plenty of soap and water Call a POISON CENTER or doctor/physician if you feel unwell If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Precautionary Statements - Storage Store in a well-ventilated place. Keep container closed Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Harmful to aquatic life with long lasting effects Unknown acute toxicity 94.985% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret DIMETHACRYLATE 25852-47-5 40 - 70 * Page 2 / 8 27010 - HIGH STRENGTH THREADLOCKER RED GEL 10 GR Harmful if swallowed Harmful in contact with skin Harmful if inhaled Causes skin irritation Causes serious eye irritation May cause damage to organs through prolonged or repeated exposure Revision Date 07-Apr-2015 Appearance Red Physical state Gel Odor Mild Page 453 of 1235 Page 453 of 1235 Page 453 of 1235 Page 453 of 1235 ---PAGE BREAK--- POLYESTER RESIN MIXTURE - 10 - 30 * HYDROPEROXIDE 80-15-9 1 - 5 * PROPYLENE GLYCOL 57-55-6 1 - 5 * SACCHARIN 81-07-2 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If persist, call a physician. Ingestion IF SWALLOWED. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important and effects, both acute and delayed See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Page 3 / 8 27010 - HIGH STRENGTH THREADLOCKER RED GEL 10 GR Revision Date 07-Apr-2015 Page 454 of 1235 Page 454 of 1235 Page 454 of 1235 Page 454 of 1235 ---PAGE BREAK--- Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers closed in a dry, cool and well-ventilated place. Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Gel Appearance Red Odor Mild Odor threshold No information available Page 4 / 8 Revision Date 07-Apr-2015 27010 - HIGH STRENGTH THREADLOCKER RED GEL 10 GR Page 455 of 1235 Page 455 of 1235 Page 455 of 1235 Page 455 of 1235 ---PAGE BREAK--- Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Page 5 / 8 Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values Lower flammability limit: No information available 27010 - HIGH STRENGTH THREADLOCKER RED GEL 10 GR Vapor pressure No information available Boiling point / boiling range > 149 °C / 300 °F No data available Vapor density >1 Remarks • Method Air = 1 Relative density 1.11-1.15 Flash point Water solubility Insoluble > 93 °C / > 200 °F Revision Date 07-Apr-2015 Solubility in other solvents No information available Tag Closed Cup pH Partition coefficient No information available No information available Evaporation rate No information available Autoignition temperature No information available Decomposition temperature No information available Page 456 of 1235 Page 456 of 1235 Page 456 of 1235 Page 456 of 1235 ---PAGE BREAK--- Skin contact May cause skin irritation and/or dermatitis. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 HYDROPEROXIDE 80-15-9 = 382 mg/kg ( Rat ) = 0.126 mL/kg ( Rabbit ) = 220 ppm ( Rat ) 4 h PROPYLENE GLYCOL 57-55-6 = 20000 mg/kg ( Rat ) = 20800 mg/kg ( Rabbit ) - Information on toxicological effects No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA SACCHARIN 81-07-2 - Group 3 - - IARC (International Agency for Research on Cancer) Not classifiable as a human carcinogen The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 631 mg/kg ATEmix (dermal) 1780 mg/kg ATEmix (inhalation-dust/mist) 0.8 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 94% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea HYDROPEROXIDE 80-15-9 - 3.9: 96 h mykiss mg/L LC50 static 7: 24 h Daphnia magna mg/L EC50 PROPYLENE GLYCOL 57-55-6 19000: 96 h Pseudokirchneriella subcapitata mg/L EC50 51600: 96 h mykiss mg/L LC50 static 41 - 47: 96 h mykiss mL/L LC50 static 51400: 96 h Pimephales promelas mg/L LC50 static 710: 96 h Pimephales promelas mg/L LC50 1000: 48 h Daphnia magna mg/L EC50 Static 10000: 24 h Daphnia magna mg/L EC50 SACCHARIN 81-07-2 - 18300: 96 h Pimephales promelas mg/L LC50 - Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Page 6 / 8 Revision Date 07-Apr-2015 27010 - HIGH STRENGTH THREADLOCKER RED GEL 10 GR Page 457 of 1235 Page 457 of 1235 Page 457 of 1235 Page 457 of 1235 ---PAGE BREAK--- Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes HYDROPEROXIDE 80-15-9 - - - U096 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status HYDROPEROXIDE 80-15-9 Toxic Ignitable 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Not Listed. ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Page 7 / 8 27010 - HIGH STRENGTH THREADLOCKER RED GEL 10 GR Revision Date 07-Apr-2015 Page 458 of 1235 Page 458 of 1235 Page 458 of 1235 Page 458 of 1235 ---PAGE BREAK--- Chemical Name SARA 313 - Threshold Values % HYDROPEROXIDE - 80-15-9 1.0 SACCHARIN - 81-07-2 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) HYDROPEROXIDE 80-15-9 10 lb - RQ 10 lb final RQ RQ 4.54 kg final RQ US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts HYDROPEROXIDE 80-15-9 X X X PROPYLENE GLYCOL 57-55-6 X - X SACCHARIN 81-07-2 X X X 1,4-NAPHTHOQUINONE 130-15-4 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 07-Apr-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 8 / 8 Revision Date 07-Apr-2015 - HMIS NFPA Health hazards 2 Flammability 1 Physical hazards 0 Personal protection B Health hazards 2 27010 - HIGH STRENGTH THREADLOCKER RED GEL 10 GR Flammability 1 Instability 0 Page 459 of 1235 Page 459 of 1235 Page 459 of 1235 Page 459 of 1235 ---PAGE BREAK--- Micromeritics Material Safety Data Sheet Title : HYDRAULIC FLUID OD-15-200 (5-G) MSDS No. : 004/16144/00MSDS Date of Preparation :06/23/04 Revision : B Micromeritics Instrument Corp. and Micromeritics Analytical Services www.micromeritics.com www.particletesting.com Surface Area - Porosity - Density - Particle Size, Shape & Count - Catalytic Activity - Surface Energy - Analytical Services Page 1 of 6 Section 1 - Chemical Product and Company Identification Product/Chemical Name: Hydraulic Fluid OD-15-200 Chemical Formula: Not Applicable CAS Number: Not Applicable Other Designations: Not Applicable General Use: Hydraulic Fluid Supplier: Micromeritics Instrument Corp. Contact: Human Resources 1 Micromeritics Dr. Phone: (770) 662-3620 Norcross, GA 30093-1877 USA Fax: (770) 662-3696 Manufacturer: Micromeritics Instrument Corp., 1 Micromeritics Dr, Norcross, GA 30093-1877 USA, Phone: (770) 662-3678 Sun Company, Inc., Ten Penn Center, 1801 Market St., Philadelphia, PA 19103-1699 Section 2 - Composition / Information on Ingredients Ingredient Name CAS Number % wt. Severely Solvent Refined Heavy Paraffinic Petroleum Oil 64741-88-4 90.00 - 100.00 Zinc Dialkyl Dithiophosphate 68649-42-3 1.00 Calcium Sulfonate 61789-86-4 1.00 Butylated Phenol Not Applicable 1.00 Acrylic Copolymer 68171-46-0 1.00 104-76-7 1.00 Trace Impurities: OSHA PEL ACGIH TLV NIOSH REL NIOSH Ingredient TWA STEL TWA STEL TWA STEL IDLH Hydraulic Oil 5 mg/m3 none estab. 5 mg/m3 none estab. none estab. none estab. none estab. Oil Mist 5 mg/m3 none estab. 5 mg/m3 none estab. none estab. none estab. none estab. Page 460 of 1235 Page 460 of 1235 Page 460 of 1235 Page 460 of 1235 ---PAGE BREAK--- MSDS No. 004/16144/00MSDS HYDRAULIC FLUID OD-15-200(5-G) Rev: B Micromeritics Instrument Corp. and Micromeritics Analytical Services www.micromeritics.com www.particletesting.com Surface Area - Porosity - Density - Particle Size, Shape & Count - Catalytic Activity - Surface Energy - Analytical Services Page 2 of 6 Section 3 - Hazards Identification Emergency Overview Potential Health Effects Primary Entry Routes: Skin Target Organs: Not Applicable Acute Effects Inhalation: No effects expected. Eye: Contact with the eye may cause minimal irritation. Skin: Practically non-toxic if absorbed (LD50 greater than 2000mg/Kg). May cause mild irritation with prolonged or repeated contact. Ingestion: Practically non-toxic. (LD50> 15g/Kg) Carcinogenicity: Not Applicable Medical Conditions Aggravated by Long-Term Exposure: Not Applicable Chronic Effects: Not Applicable Section 4 - First Aid Measures Inhalation: Move person to fresh air. Eye Contact: Flush with water. Skin Contact: Wash with soap and water until no odor remains. Wash clothing before reuse. Ingestion: Practically non-toxic. Induction of vomiting not required. Obtain emergency medical attention. Small amounts which accidentally enter mouth should be rinsed out until taste of it is gone. Note to Physicians: Not Applicable Special Precautions/Procedures: Warning!! High pressure injection of oil through the skin is a medical emergency. There may be no sign of injury and no initial pain. This oil must be removed completely by a physician. Failure to obtain immediate treatment has resulted in loss of a finger, hand or arm. WHMIS Classification: Not controlled. Section 5 - Fire-Fighting Measures Flash Point: 380 minimum COC (192 min. COC Flash Point Method: COC Burning Rate: Not Applicable Autoignition Temperature: Not Applicable LEL: Not Applicable UEL: Not Applicable Flammability Classification: Not Applicable Extinguishing Media: Water spray, regular foam, dry chemical, carbon dioxide. Unusual Fire or Explosion Hazards: Not Applicable Hazardous Combustion Products: Not Applicable Fire-Fighting Instructions: Wear self-contained breathing apparatus. Wear structural firefighters protective clothing. Fire-Fighting Equipment: Not Applicable Section 6 - Accidental Release Measures Spill /Leak Procedures: Not Applicable Small Spills: Not Applicable Large Spills: Not Applicable Containment: Not Applicable HMIS H F R 1 1 0 PPE† †Sec. 8 NFPA 1 1 0 - Page 461 of 1235 Page 461 of 1235 Page 461 of 1235 Page 461 of 1235 ---PAGE BREAK--- MSDS No. 004/16144/00MSDS HYDRAULIC FLUID OD-15-200(5-G) Rev: B Micromeritics Instrument Corp. and Micromeritics Analytical Services www.micromeritics.com www.particletesting.com Surface Area - Porosity - Density - Particle Size, Shape & Count - Catalytic Activity - Surface Energy - Analytical Services Page 3 of 6 Cleanup: Not Applicable Regulatory Requirements: Not Applicable Page 462 of 1235 Page 462 of 1235 Page 462 of 1235 Page 462 of 1235 ---PAGE BREAK--- MSDS No. 004/16144/00MSDS HYDRAULIC FLUID OD-15-200(5-G) Rev: B Micromeritics Instrument Corp. and Micromeritics Analytical Services www.micromeritics.com www.particletesting.com Surface Area - Porosity - Density - Particle Size, Shape & Count - Catalytic Activity - Surface Energy - Analytical Services Page 4 of 6 Section 7 - Handling and Storage Handling Precautions: Not Applicable Storage Requirements: Not Applicable Regulatory Requirements: Not Applicable Section 8 - Exposure Controls / Personal Protection Engineering Controls: Not Applicable Ventilation: Not Applicable Administrative Controls: Not Applicable Respiratory Protection: Not Applicable Protective Clothing/Equipment: Not Applicable Safety Stations: Not Applicable Contaminated Equipment: Comments: Not Applicable Section 9 - Physical and Chemical Properties Physical State: Not Applicable Appearance and Odor: Clear fluid, little odor. Odor Threshold: Not Applicable Vapor Pressure: <0.0001 mmHg at 20°C Vapor Density (Air=1): 10+ Formula Weight: Not Applicable Density: Not Applicable Specific Gravity (H2O=1): 0.87 pH: Not Applicable Water Solubility: NIL by volume) Other Solubilities: Not Applicable Boiling Point: Not Applicable Freezing/Melting Point: Not Applicable Viscosity: 165 SUS @ 100°F 32.0 CST @ 40°C Refractive Index: Not Applicable Surface Tension: Not Applicable % Volatile: Not Applicable Evaporation Rate: 1000X slower (Ethyl Ether Section 10 - Stability and Reactivity Stability: Stable Polymerization: Will not occur Chemical Incompatibilities: Strong Oxidizers Conditions to Avoid: Not Applicable Hazardous Decomposition Products: Combustion produces carbon monoxide, oxides of sulfur and Section 11- Toxicological Information Toxicity Data: Eye Effects: Not Applicable Skin Effects: Not Applicable Acute Inhalation Effects: Not Applicable Acute Oral Effects: Not Applicable Chronic Effects: Not Applicable Carcinogenicity: Not Applicable Mutagenicity: Not Applicable Teratogenicity: Not Applicable Section 12 - Ecological Information Ecotoxicity: Not Applicable Environmental Fate: Not Applicable Environmental Degradation: Not Applicable Page 463 of 1235 Page 463 of 1235 Page 463 of 1235 Page 463 of 1235 ---PAGE BREAK--- MSDS No. 004/16144/00MSDS HYDRAULIC FLUID OD-15-200(5-G) Rev: B Micromeritics Instrument Corp. and Micromeritics Analytical Services www.micromeritics.com www.particletesting.com Surface Area - Porosity - Density - Particle Size, Shape & Count - Catalytic Activity - Surface Energy - Analytical Services Page 5 of 6 Soil Absorption/Mobility: Not Applicable Page 464 of 1235 Page 464 of 1235 Page 464 of 1235 Page 464 of 1235 ---PAGE BREAK--- MSDS No. 004/16144/00MSDS HYDRAULIC FLUID OD-15-200(5-G) Rev: B Micromeritics Instrument Corp. and Micromeritics Analytical Services www.micromeritics.com www.particletesting.com Surface Area - Porosity - Density - Particle Size, Shape & Count - Catalytic Activity - Surface Energy - Analytical Services Page 6 of 6 Section 13 - Disposal Considerations Disposal: Not Applicable Disposal Regulatory Requirements: Not Applicable Container Cleaning and Disposal: Not Applicable Section 14 - Transport Information DOT Transportation Data (49 CFR 172.101): Shipping Name: Not Applicable Shipping Symbols: Not Applicable Hazard Class: Not Applicable ID No.: Not Applicable Packing Group: Not Applicable Label: Not Applicable Special Provisions (172.102): Not Applicable Packaging Authorizations a) Exceptions: Not Applicable b) Non-bulk Packaging: Not Applicable c) Bulk Packaging: Not Applicable Quantity Limitations a) Passenger, Aircraft, or Railcar: Not Applicable b) Cargo Aircraft Only: Not Applicable Vessel Stowage Requirements a) Vessel Stowage: Not Applicable b) Other: Not Applicable Section 15 - Regulatory Information EPA Regulations: Not Applicable OSHA Regulations: Not Applicable State Regulations: Not Applicable Section 16 - Other Information Prepared By: ADG Revision Notes: Not Applicable Additional Hazard Rating Systems: Not Applicable Disclaimer: Not Applicable Page 465 of 1235 Page 465 of 1235 Page 465 of 1235 Page 465 of 1235 ---PAGE BREAK--- 1 SAFETY DATA SHEET SECTION 1: IDENTIFICATION Product Identification: Hydraulic fluid OD-15-200 CAS Number: Volumes: 5 GAL, 1 L Other Designations: Recommended Use: Restrictions: For industrial use only. Supplier Information: Micromeritics Instrument Corp. Contact: Human Resources 4356 Communications Drive Phone: (770) 662-3620 Norcross, GA 30093-2901 USA Fax: (770) 662-3696 Manufacturer: Micromeritics Instrument Corp., 4356 Communications Drive, Norcross, GA 30093-1877 USA, Phone: (770) 662-3678 Sun Company, Inc., Ten Penn Center, 1801 Market St., Philadelphia, PA 19103-699 SECTION 2: HAZARDS IDENTIFICATION GHS Classification: Not Applicable Signal word: Not Applicable Hazard Statement: Not Applicable Pictograms: Not Applicable Potential Health Effects Primary Entry Routes: Skin Target Organs: Not Applicable Acute Effects Inhalation: No effects expected. Eye: Contact with the eye may cause minimal irritation. Skin: Practically non-toxic if absorbed (LD50 greater than 2000mg/Kg). May cause mild irritation with prolonged or repeated contact. Ingestion: Practically non-toxic. (LD50> 15g/Kg) Carcinogenicity: Not Applicable Medical Conditions Aggravated by Long-Term Exposure: Not Applicable Chronic Effects: Not Applicable Hydraulic Fluid Date of Preparation: 05/20/2014 SDS 004-16144-00MSDS Page 466 of 1235 Page 466 of 1235 Page 466 of 1235 Page 466 of 1235 ---PAGE BREAK--- 2 SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Ingredient Name CAS Number % wt Severely Solvent Refined Heavy Paraffinic Petroleum Oil 64741-88-4 90.00- 100.00 Zinc Dialkyl Dithiophosphate 68649-42-3 1.00 Calcium Sulfonate 61789-86-4 1.00 Butylated Phenol Not Applicable 1.00 Acrylic Copolymer 68171-46-0 1.00 104-76-7 1.00 Trace Impurities: OSHA PEL ACGIH TLV NIOSH REL NIOSH Ingredient TWA STEL TWA STEL TWA STEL IDLH Hydraulic Oil 5 mg/m3 none estab. 5 mg/m3 none estab. none estab. none estab. none estab. Oil Mist 5 mg/m3 none estab. 5 mg/m3 none estab. none estab. none estab. none estab. SECTION 4: FIRST-AID MEASURES Inhalation: Move person to fresh air. Eye Contact: Flush with water. Skin Contact: Wash with soap and water until no odor remains. Wash clothing before reuse. Ingestion: Practically non-toxic. Induction of vomiting not required. Obtain emergency medical attention. Small amounts which accidentally enter mouth should be rinsed out until taste of it is gone. Note to Physicians: Not Applicable Special Precautions/Procedures: Warning!! High pressure injection of oil through the skin is a medical emergency. There may be no sign of injury and no initial pain. This oil must be removed completely by a physician. Failure to obtain immediate treatment has resulted in loss of a finger, hand or arm. WHMIS Classification: Not controlled. SECTION 5: FIRE-FIGHTING MEASURES Flammability Classification: Not Applicable Extinguishing Media: Water spray, regular foam, dry chemical, carbon dioxide. Unusual Fire or Explosion Hazards: Not Applicable Hazardous Combustion Products: Not Applicable Fire-Fighting Instructions: Wear self-contained breathing apparatus. Wear structural firefighter’s protective clothing. Fire-Fighting Equipment: Not Applicable Page 467 of 1235 Page 467 of 1235 Page 467 of 1235 Page 467 of 1235 ---PAGE BREAK--- 3 SECTION 6: ACCIDENTAL RELEASE MEASURES Small Spills: Wear protective equipment to prevent skin and eye contamination. Avoid inhalation of vapors. Wipe up with absorbent (clean rag or paper towels). Collect and seal in properly labelled containers or drums for disposal. Large Spills: Prevent further leakage or spillage if safe to do so. Slippery when spilt. Avoid accidents, clean up immediately. Wear protective equipment to prevent skin and eye contamination and the inhalation of vapors. Work up wind or increase ventilation. Prevent run off into drains and waterways. Use absorbent (soil, sand or other inert material). Collect and seal in properly labelled containers or drums for disposal. Regulatory Requirements: Not Applicable SECTION 7: HANDLING AND STORAGE Handling Precautions: Avoid eye contact and repeated or prolonged skin contact. Storage Requirements: Store in a cool, dry, well-ventilated place and out of direct sunlight. Regulatory Requirements: Not Applicable SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls: Natural ventilation should be adequate under normal use conditions. Keep containers closed when not in use. Ventilation: Not Applicable Administrative Controls: Not Applicable Respiratory Protection: Not Applicable Protective Clothing/Equipment: Safety shoes, safety glasses, gloves Safety Stations: Not Applicable Contaminated Equipment: Not Applicable Comments: Not Applicable SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Flash Point: 380 minimum COC (192 min. OC°C) Flash Point Method: COC Burning Rate: Not Applicable Autoignition Temperature: Not Applicable LEL: Not Applicable UEL: Not Applicable Physical State: Not Applicable Water Solubility: NIL by volume) Appearance and Odor: Clear fluid, little odor. Other Solubilities: Not Applicable Page 468 of 1235 Page 468 of 1235 Page 468 of 1235 Page 468 of 1235 ---PAGE BREAK--- 4 Odor Threshold: Not Applicable Boiling Point: Not Applicable Vapor Pressure: <0.0001 mmHg at 20°C Freezing/Melting Point: Not Applicable Vapor Density (Air=1): 10+ Viscosity: 165 SUS @ 100°F 32.0 CST @ 40°C Formula Weight: Not Applicable Refractive Index: Not Applicable Density: Not Applicable Surface Tension: Not Applicable Specific Gravity (H2O=1): 0.87 % Volatile: Not Applicable pH: Not Applicable Evaporation Rate: 1000X slower (Ethyl Ether SECTION 10: STABILITY AND REACTIVITY Stability: Stable Polymerization: Will not occur Chemical Incompatibilities: Strong Oxidizers Conditions to Avoid: Elevated temperatures and sources of ignition Hazardous Decomposition Products: Combustion produces carbon monoxide, oxides of sulfur and SECTION 11: TOXICOLOGICAL INFORMATION Eye Effects: Not Applicable Acute Inhalation Effects: Not Applicable Skin Effects: Not Applicable Acute Oral Effects: Not Applicable Chronic Effects: Not Applicable Carcinogenicity: Not Applicable Mutagenicity: Not Applicable Teratogenicity: Not Applicable SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity: Not Available Environmental Fate: Not Available Environmental Degradation: Not Available Soil Absorption/Mobility: Not Available Page 469 of 1235 Page 469 of 1235 Page 469 of 1235 Page 469 of 1235 ---PAGE BREAK--- 5 SECTION 13: DISPOSAL CONSIDERATIONS Disposal: Persons conducting disposal, recycling or reclamation activities should ensure that appropriate personal protection equipment is used, see “Section 8. Exposure Controls and Personal Protection” of this SDS. If possible material and its container should be recycled. Disposal Regulatory Requirements: Not Available Container Cleaning and Disposal: Not Available SECTION 14: TRANSPORT INFORMATION DOT Transportation Data (49 CFR 172.101): Shipping Name: Not regulated Shipping Symbols: Not Applicable Hazard Class: Not regulated ID No.: Not regulated Packing Group: Not Applicable Label: Not Applicable Special Provisions (172.102): Not Applicable Packaging Authorizations a) Exceptions: Not Applicable b) Non-bulk Packaging: Not Applicable c) Bulk Packaging: Not Applicable Quantity Limitations a) Passenger, Aircraft, or Railcar: Not Applicable b) Cargo Aircraft Only: Not Applicable Vessel Stowage Requirements a) Vessel Stowage: Not Applicable b) Other: Not Applicable Canadian TDG Hazard Class & PIN – Not regulated SECTION 15: REGULATORY INFORMATION EPA Regulations: Not Applicable OSHA Regulations: Not Applicable State Regulations: Not Applicable Page 470 of 1235 Page 470 of 1235 Page 470 of 1235 Page 470 of 1235 ---PAGE BREAK--- 6 SECTION 16: OTHER INFORMATION Prepared By: Zuniga, A. Revision Notes: Not Applicable Additional Hazard Rating Systems: Not Applicable Disclaimer: The information presented herein is believed to be accurate and was obtained from sources believed to be reliable. However, the information is provided without any representation or warranty, expressed or implied, with respect to its accuracy or completeness. It is the users’ responsibility to determine the suitability of this product and the relevance of this information for their use. Page 471 of 1235 Page 471 of 1235 Page 471 of 1235 Page 471 of 1235 ---PAGE BREAK--- Material Safety Data Sheet I M A T E R I A L S A F E T Y D A T A S H E E T I I SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION I PRODUCT NAME : FLAT BLACK 9702344 IDENTIFICATION NUMBER: 7776 402 DATE PRINTED : 11/03/97 PRODUCT USE/CLASS : ENAMEL/ALKYD SUPPLIER: MANUFACTURER: Rust-Oleum Corporation Rust-Oleum Corporation 11 Hawthorn Parkway 11 Hawthorn Parkway Vernon Hills, Illinois Vernon Hills, Illinois 60061 USA 60061 USA (847) 367-7700 Rust-Oleum Corp. (847) 367-7700 Rust-Oleum Corp. Mon.-Fri, 8:00 AM-4:30 PM Mon.-Fri, 8:00 AM-4:30 PM PREPARER: LJW, PHONE: , PREPARE DATE: 06/11/97 I SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS I WT/WT % ITEM CHEMICAL NAME CAS NUMBER LESS THAN 01 Calcium Carbonate 1317-65-3 50.0 % 02 Stoddard Solvent 8052-41-3 25.0 % 03 Carbon Black 1333-86-4 5.0 % 04 108-67-8 5.0 % 05 95-63-6 5.0 % 06 Cobalt Drier 136-52-7 0.1 % EXPOSURE LIMITS ACGIH OSHA COMPANY ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN 01 10mg/m3 N.E. 15mg/m3 N.E. N.E. NO 02 100ppm N.E. 100ppm N.E. N.E. NO 03 3.5 mg/m3 N.E. 3.5 mg/m3 N.E. N.E. NO 04 25 PPM N.E. N.E. N.E. N.E. NO 05 25 PPM N.E. N.E. N.E. N.E. NO 06 N.E. N.E. N.E. N.E. N.E. NO (See Section 16 for abbreviation legend) (Continued on Page 2) Product: 7776 402 Preparation Date: 06/11/97 Page 2 I SECTION 3 - HAZARDS IDENTIFICATION I (1 of 7) [12/20/2001 3:32:06 PM] Page 472 of 1235 Page 472 of 1235 Page 472 of 1235 Page 472 of 1235 ---PAGE BREAK--- EMERGENCY OVERVIEW Harmful if swallowed. Causes (target organ or system) damage. Causes eye irritation. Vapors irritating to eyes and respiratory tract. Combustible liquid and vapor. EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation. EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. May cause headaches and dizziness. EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed. Aspiration hazard if swallowed; can enter lungs and cause damage. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Contains carbon black. Chronic inflammation, lung fibrosis, and lung tumors have been observed in some rats experimentally exposed for long periods of time to excessive concentrations of carbon black and several insoluble fine dust particles. Tumors have not been observed in other animal species mouse and hampster) under similar circumstances and study conditions. Epidemiological studies of North American workers show no evidence of clinically significant adverse health effects due to occupational exposure to carbon black. Carbon black is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC and is proposed to be listed as A4- "not classified as a human carcinogen" by the American Conference of Govermental Industrial Hygienists. Significant exposure is not anticipated during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration ofcarbon black in the formula. PRIMARY ROUTE(S) OF ENTRY: INHALATION EYE CONTACT I SECTION 4 - FIRST AID MEASURES I FIRST AID - EYE CONTACT: Hold eyelids apart and flush with plenty of water for at lease 15 minutes. Get medical attention. FIRST AID - SKIN CONTACT: Wash with soap and water. Get medical attention if irritation develops or persists. FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give (Continued on Page 3) Product: 7776 402 Preparation Date: 06/11/97 Page 3 I SECTION 4 - FIRST AID MEASURES I anything by mouth because this material can enter the lungs and cause (2 of 7) [12/20/2001 3:32:06 PM] Page 473 of 1235 Page 473 of 1235 Page 473 of 1235 Page 473 of 1235 ---PAGE BREAK--- severe lung damage. Get immediate medical attention. I SECTION 5 - FIRE FIGHTING MEASURES I FLASH POINT: 102 F LOWER EXPLOSIVE LIMIT: 0.9 % UPPER EXPLOSIVE LIMIT: 6.4 % AUTOIGNITION TEMPERATURE: ND EXTINGUISHING MEDIA: DRY CHEMICAL FOAM WATER FOG UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers closed. SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Evacuate area and fight fire from a safe distance. I SECTION 6 - ACCIDENTAL RELEASE MEASURES I STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. I SECTION 7 - HANDLING AND STORAGE I HANDLING: Wash thoroughly after handling. Wash hands before eating. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing vapor or mist. Avoid contact with eyes. STORAGE: Keep containers closed. Isolate from heat, electrical equipment, sparks and open flame. Keep away from heat, sparks, flame and sources of ignition. Keep container closed when not in use. I SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION I ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation. RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA (Continued on Page 4) Product: 7776 402 Preparation Date: 06/11/97 Page 4 I SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION I 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible (3 of 7) [12/20/2001 3:32:06 PM] Page 474 of 1235 Page 474 of 1235 Page 474 of 1235 Page 474 of 1235 ---PAGE BREAK--- under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection. EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids. OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application. HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. I SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES I BOILING RANGE : 318 - 383 F VAPOR DENSITY : Is heavier than air ODOR : SOLVENT ODOR THRESHOLD : ND APPEARANCE : LIQUID EVAPORATION RATE: Is slower than Ether SOLUBILITY IN H2O : SLIGHT FREEZE POINT : ND SPECIFIC GRAVITY: 1.3351 VAPOR PRESSURE : ND pH @ 0.0 % : ND PHYSICAL STATE : LIQUID VISCOSITY : ND COEFFICIENT OF WATER/OIL DISTRIBUTION: ND (See Section 16 for abbreviation legend) I SECTION 10 - STABILITY AND REACTIVITY I CONDITIONS TO AVOID: Avoid all possible sources of ignition. INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies. HAZARDOUS DECOMPOSITION PRODUCTS: By open flame, carbon monoxide and carbon dioxide. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. (Continued on Page 5) Product: 7776 402 Preparation Date: 06/11/97 Page 5 I SECTION 10 - STABILITY AND REACTIVITY I STABILITY: This product is stable under normal storage conditions. I SECTION 11 - TOXICOLOGICAL PROPERTIES I COMPONENT TOXICOLOGICAL INFORMATION: (4 of 7) [12/20/2001 3:32:06 PM] Page 475 of 1235 Page 475 of 1235 Page 475 of 1235 Page 475 of 1235 ---PAGE BREAK--- CHEMICAL NAME LD50 LC50 Calcium Carbonate None None Stoddard Solvent 4900mg/kg(rat) N.E. Carbon Black N.A. N.A. RAT 1303MG/KG RAT 24MG/M^3 4HR N.E. RAT 18G/M^3 4HR Cobalt Drier NA NA I SECTION 12 - ECOLOGICAL INFORMATION I ECOLOGICAL INFORMATION: Product is a mixture of listed components. I SECTION 13 - DISPOSAL CONSIDERATIONS I DISPOSAL METHOD: Dispose of material in accordance to local, state and federal regulations and ordinances. Do not allow to enter storm drains or sewer systems. I SECTION 14 - TRANSPORTATION INFORMATION I No transportation information is available. I SECTION 15 - REGULATORY INFORMATION I U.S. FEDERAL REGULATIONS: AS FOLLOWS - OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) (Continued on Page 6) Product: 7776 402 Preparation Date: 06/11/97 Page 6 I SECTION 15 - REGULATORY INFORMATION I CERCLA - SARA HAZARD CATEGORY: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and (5 of 7) [12/20/2001 3:32:06 PM] Page 476 of 1235 Page 476 of 1235 Page 476 of 1235 Page 476 of 1235 ---PAGE BREAK--- Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER WT/WT % IS LESS THAN 95-63-6 5.0 % XYLENE 1330-20-7 1.0 % 100-41-4 1.0 % TOXIC SUBSTANCES CONTROL ACT: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: CHEMICAL NAME CAS NUMBER No information is available. U.S. STATE REGULATIONS: AS FOLLOWS - NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components in this product: CHEMICAL NAME CAS NUMBER Alkyd Resin 66070-60-8 RIGHT-TO-KNOW: The following non-hazardous ingredients are present in the product at greater than CHEMICAL NAME CAS NUMBER Alkyd Resin 66070-60-8 CALIFORNIA PROPOSITION 65: WARNING: The chemical(s) noted below and contained in this product, are known to the state of California to cause cancer, birth defects or other reproductive harm: CHEMICAL NAME CAS NUMBER No Proposition 65 chemicals exist in this product. INTERNATIONAL REGULATIONS: AS FOLLOWS - (Continued on Page 7) Product: 7776 402 Preparation Date: 06/11/97 Page 7 I SECTION 15 - REGULATORY INFORMATION I CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: No information available. I SECTION 16 - OTHER INFORMATION I HMIS RATINGS - HEALTH: FLAMMABILITY: REACTIVITY: PREVIOUS MSDS REVISION DATE: 04/10/97 LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined (6 of 7) [12/20/2001 3:32:06 PM] Page 477 of 1235 Page 477 of 1235 Page 477 of 1235 Page 477 of 1235 ---PAGE BREAK--- : No Information. The information contained on this MSDS has been checked and should be accurate. However, it is the responsibility of the user to comply with all Federal, State, and Local laws and regulations. (7 of 7) [12/20/2001 3:32:06 PM] Page 478 of 1235 Page 478 of 1235 Page 478 of 1235 Page 478 of 1235 ---PAGE BREAK--- Page 479 of 1235 Page 479 of 1235 Page 479 of 1235 Page 479 of 1235 ---PAGE BREAK--- Page 480 of 1235 Page 480 of 1235 Page 480 of 1235 Page 480 of 1235 ---PAGE BREAK--- Click here to go back to MSDS Barnes Distribution 1301 E. 9th Street, #700 Cleveland OH 44114 (800) 726-9626 Material Safety Data Sheet MSDS Form No. : MSDS19428 Item No. : 19428 MATERIAL SAFETY DATA SHEET ISO-HEET FUEL SYSTEM DRYER & ANTIFREEZE 12 FL. OZ. Part # MSDS19428 SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS Name: ISO-HEET FUEL SYSTEM DRYER & ANTIFREEZE 12 FL. OZ. Product CAS: (none) Product Code: Synonyms: 19428; ISO-HEET FUEL SYSTEM DRYER & ANTIFREEZE 12 FL. OZ. Company Identification: Name: BOWMAN DISTRIBUTION Address: 1301 E. 9TH ST., ST. 700 Address: City: CLEVELAND State: OH Zip: 44114 For information, call: HEALTH AND TECHNICAL CONTACTS: HEALTH ISSUES AND TECHNICAL INFORMATION (8AM-5PM ET): 1-[PHONE REDACTED] X 5860 Emergency Number: ROCKY MOUNTAIN POISON CONTROL CENTER (24 HOURS EVERYDAY): 1-[PHONE REDACTED] Emergency Agency: CHEMTREC (24 HOURS EVERYDAY): Number: 1-[PHONE REDACTED] MSDS Creation Date: 1/1/2003 Supersedes Date: 4/11/2000 SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS Chemical Name CAS MIN MAX ISOPROPYL ALCOHOL 67-63-0 100 100 Miscellaneous: INGREDIENT OSHA PEL ACGIH TLV OTHER LIMITS ISOPROPYL 400 PPM 500 PPM MSDS - MSDS19428 http://apps.barnesdistribution.com/website/msds.nsf/webview/MSDS19428ENG?OpenDocument (1 of 7) [5/24/2006 3:53:11 PM] Page 481 of 1235 Page 481 of 1235 Page 481 of 1235 Page 481 of 1235 ---PAGE BREAK--- Lbs of VOC per Gallon Coating (minus water): 0 Coating Density (lbs/gal): 0 Solvent Density (lbs/gal): 0 Percent Solvent (volume): 0 Percent Solids (volume): 0 Percent Water (volume): 0 SECTION 3 - HAZARDS IDENTIFICATION NFPA: Health: 2 Fire: 3 Reactivity: 0 Other: 0 HMIS: Health: Fire: Reactivity: Special Protection: Miscellaneous: HMIS AND NFPA HAZARD RATINGS: HMIS / NFPA ACUTE HEALTH: N.E. / 2 FLAMMABILITY: N.E. / 3 REACTIVITY: N.E. / 0 PERSONAL PROT.: N.E. SPECIFIC HAZ.: 0 POTENTIAL HEALTH EFFECTS Target Organs: TARGET ORGAN AND OTHER EFFECTS: NO DATA PROVIDED. PRIMARY ROUTES OF EXPOSURE: INHALATION SKIN, EYE AND INGESTION. Eye: HEALTH HAZARDS (ACUTE AND CHRONIC - INCLUDE TARGET ORGAN EFFECTS): VAPOR CAN IRRITATE EYES. LIQUID MAY DAMAGE EYE TISSUE IF NOT VOMITING, AND ABDOMINAL PAIN. ASPIRATION OF VOMITUS MAY CAUSE CHEMICAL PNEUMONIA OR PULMONARY EDEMA. Skin: Ingestion: SEE "EYES". Inhalation: HEALTH HAZARDS (ACUTE AND CHRONIC - INCLUDE TARGET ORGAN EFFECTS): HIGH CONCENTRATIONS OF VAPOR CAN IRRITATE RESPIRATORY TACT, CAUSE NAUSEA, GIDDINESS, HEADACHE, OR DIZZINESS. Miscellaneous: CONDITIONS TO AVOID: N.A. MSDS - MSDS19428 http://apps.barnesdistribution.com/website/msds.nsf/webview/MSDS19428ENG?OpenDocument (2 of 7) [5/24/2006 3:53:11 PM] Page 482 of 1235 Page 482 of 1235 Page 482 of 1235 Page 482 of 1235 ---PAGE BREAK--- MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: REPEATED INHALATION OR LIQUID CONTACT MAY AGGRAVATE PRE-EXISTING SKIN, EYE, OR RESPIRATORY CONDITIONS SUCH AS OR BRONCHITIS. SIGNS AND OF OVEREXPOSURE: N.A. SECTION 4 - FIRST AID MEASURES Eye: FLUSH WITH WATER FOR 15 MINUTES. OBTAIN MEDICAL ATTENTION, IF IRRITATION PERSISTS. Skin: N.A. Ingestion: DO NOT INDUCE VOMITING. KEEP AT REST. IF VOMITING OCCURS SPONTANEOUSLY, KEEP AT REST. IF VOMITING OCCURS SPONTANEOUSLY, KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION OF LIQUID INTO LUNGS. GET MEDICAL ATTENTION AT ONCE. Inhalation: REMOVE VICTIM TO FRESH AIR. RESTORE OR ASSIST BREATHING. OBTAIN MEDICAL ATTENTION, IF NECESSARY. Notes to Physician: SECTION 5 - FIRE FIGHTING MEASURES Unusual Fire and Explosion Hazards: VAPORS ARE FLAMMABLE AND MAY TRAVEL ALONG GROUND TO BE IGNITED BY DISTANT IGNITION SOURCES. RUNOFF FROM FIRE CONTROL MAY CAUSE POLLUTION. Special Fire Fighting Procedures: FIREFIGHTERS MUST WEAR FULL FACE POSITIVE PRESSURE, SELF-CONTAINED BREATHING APPARATUS. USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. Extinguishing Media: CO2, DRY CHEMICAL, AND FOAM. Flash Point: AND METHOD: 55 F METHOD USED: TCC Flammable Limits: Lower Limit: LEL: 2.5 MSDS - MSDS19428 http://apps.barnesdistribution.com/website/msds.nsf/webview/MSDS19428ENG?OpenDocument (3 of 7) [5/24/2006 3:53:11 PM] Page 483 of 1235 Page 483 of 1235 Page 483 of 1235 Page 483 of 1235 ---PAGE BREAK--- Upper Limit: UEL: 12.1 AutoIgnition Temperature: General Information: FLAMMABILITY LIMITS N.D. SECTION 6 - ACCIDENTAL RELEASE MEASURES Disposal: INCINERATION OF LIQUID. INCINERATION OR LANDFILL OF CONTAMINATED ABSORBENT IN ACCORDANCE WITH LOCAL, STATE, OR FEDERAL REGULATIONS. CONTACT LOCAL AUTHORITIES FOR PROPER DISPOSAL METHOD. PRODUCT IS CONSIDERED TO BE A HAZARDOUS WASTE AS DEFINED BY RCRA. RCRA HAZARDOUS WASTE NUMBER: THE EPA HAZARDOUS WASTE NUMBER IS D001. Spills/Leaks: ELIMINATE ALL IGNITION SOURCES (VAPOR FLAMMABLE). VENTILATE AREA. STOP LEAK AT SOURCE. DIKE SPILL AND COLLECT LIQUID INTO RECOVERY VESSEL. REMAINING LIQUID SHOULD BE PICKED UP ON NON-FLAMMABLE ABSORBENT. IF VENTILATION IS NOT ADEQUATE, WEAR FULL FACE, POSITIVE PRESSURE S.C.B.A. AND PROTECTIVE CLOTHING. ADVISE AUTHORITIES IF PRODUCT ENTERS SEWER OR WATERWAYS. SECTION 7 - HANDLING and STORAGE Handling: PRODUCT SHOULD BE KEPT IN COOL, DRY ENVIRONMENT. KEEP PRODUCT AWAY FROM IGNITION SOURCES. Storage: SEE "HANDLING" ABOVE. SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: VENTILATION: LOCAL EXHAUST: N.A., MECHANICAL: N.A. Eyes: GOGGLES. ALWAYS AVOID EYE CONTACT. Skin: MSDS - MSDS19428 http://apps.barnesdistribution.com/website/msds.nsf/webview/MSDS19428ENG?OpenDocument (4 of 7) [5/24/2006 3:53:11 PM] Page 484 of 1235 Page 484 of 1235 Page 484 of 1235 Page 484 of 1235 ---PAGE BREAK--- YES. (CHEMICAL RESISTANT) Clothing: OTHER PROTECTIVE EQUIPMENT: SOLVENT-RESISTANT BOOTS, APRON, AND HEADGEAR WHERE SPLASHING IS A PROBLEM. SAFETY SHOWER AND EYEWASH STATION. Respirators: AIR-SUPPLIED MASK IN CONFINED, NON-VENTILATED AREAS. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance/Odor: CLEAR LIQUID, ALCOHOLIC ODOR. pH: N.A. Vapor Pressure: .33 MM HG @ 68 F Vapor Density: (AIR = 2.1 Evaporation Rate: (ETHER=1): 2.4 Viscosity: Boiling Point: 180 F Freezing/Melting Point: Decomposition Temperature: Solubility: IN WATER: COMPLETE Specific Gravity: .79 Molecular Formula: Molecular Weight: Miscellaneous: % VOLATILE BY VOL: 99.9 SECTION 10 - STABILITY AND REACTIVITY Chemical Stability: STABLE. Conditions to Avoid: STABILITY: KEEP AWAY FROM HEAT OR IGNITION SOURCES. POLYMERIZATION: N.A. Incompatibilities with Other Materials: KEEP CONCENTRATE AWAY FROM STRONG OXIDIZING AGENTS, STRONG ACIDS, OR BASES. Hazardous Decomposition Products: COMBUSTION OF LIQUID MAY FORM OXIDES OF CARBON AND/OR ORGANIC COMPOUNDS. Hazardous Polymerization: WILL NOT OCCUR. MSDS - MSDS19428 http://apps.barnesdistribution.com/website/msds.nsf/webview/MSDS19428ENG?OpenDocument (5 of 7) [5/24/2006 3:53:11 PM] Page 485 of 1235 Page 485 of 1235 Page 485 of 1235 Page 485 of 1235 ---PAGE BREAK--- SECTION 11 - TOXICOLOGICAL INFORMATION Toxicological Information: CARCINOGENICITY: NO DATA PROVIDED INGREDIENT ACGIH IARC NTP OSHA ISOPROPYL 400 PPM NO NO NO SECTION 12 - ECOLOGICAL INFORMATION Ecological Information: NO DATA AVAILABLE. SECTION 13 - OTHER PRECAUTIONS Other Precautions: KEEP OUT OF REACH OF CHILDREN. Work/Hygienic Practices: SECTION 14 - TRANSPORT INFORMATION Transportation Information: DOT SHIPPING NAME: N.A. HAZARD CLASS OR DIVISION: NONE CARTON MARKINGS: NONE. IDENTIFICATION NUMBER: NONE PACKING GROUP: NONE LABELS: NONE Label Information: SECTION 15 - REGULATORY INFORMATION Regulatory Information: TSCA STATUS: EACH INGREDIENT IS ON THE TSCA INVENTORY. MSDS - MSDS19428 http://apps.barnesdistribution.com/website/msds.nsf/webview/MSDS19428ENG?OpenDocument (6 of 7) [5/24/2006 3:53:11 PM] Page 486 of 1235 Page 486 of 1235 Page 486 of 1235 Page 486 of 1235 ---PAGE BREAK--- NSR STATUS (CANADA): NOT DETERMINED. HAZARD CATEGORIES: ACUTE HEALTH: YES CHRONIC HEALTH: NO FIRE HAZARD: YES PRESSURE HAZARD: NO REPORTABLE INGREDIENTS: SECTION 313: NONE CERCLA RQ: N.A. SECTION 16 - ADDITIONAL INFORMATION Additional Information: N.A.=NOT APPLICABLE N.D.=NOT DETERMINED N.E.=NOT ESTABLISHED REVISION SUMMARY: THIS MSDS REPLACES THE MARCH 11, 1997 MSDS. PREPARED APRIL 11, 2000. MSDS - MSDS19428 http://apps.barnesdistribution.com/website/msds.nsf/webview/MSDS19428ENG?OpenDocument (7 of 7) [5/24/2006 3:53:11 PM] Page 487 of 1235 Page 487 of 1235 Page 487 of 1235 Page 487 of 1235 ---PAGE BREAK--- Page 1 of 2 MSDS K&N Air Filter Cleaner 99-0606EU, 99-0608EU, 99-5000EU, 99-5003EU K&N AIR FILTER CLEANER 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY Product name: K&N AIR FILTER CLEANER Code No: 14140/16 Revision Date: 16/12/2009 Revision Number: 1 Company Name: ROCK OIL 90 PRIESTLEY STREET WARRINGTON CHESHIRE WA5 1ST Day time tel No. +44(0)1925 636191 Emergency Telephone No: +44(0)1925 636191 Fax: +44(0)1925 632499 E-mail: [EMAIL REDACTED] 2 HAZARDS IDENTIFICATION Irritating to eyes and skin. 3 COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENT NAME EINECS CAS No. CONTENTS SYMBOL & RISK No. PHOSPHORIC ACID 231-633-2 7664-38-2 0-1 % C 34 POTASSIUM HYDROXIDE 215-181-3 1310-58-3 0-1 % Xn-R22, C-R35 D008 NONIONIC SURFACTANT 68412-54-4 1-5 % Xn 22, 36/38, 53 D006 NONIONIC SURFACTANT 68412-54-4 1-5 % Xi 36/38, 53 TRISODIUM NITRILOACETIC ACID 225-768-6 5064-31-3 1-5 % Carc Cat-3-R40 Xn-R22 Xi-R36 The full text for all R-phrases is shown in section 16. 4 FIRST AID MEASURES INHALATION: If inhalation of vapours causes irritation or drowsiness, remove to fresh air. INGESTION: Rinse mouth thoroughly. DO NOT induce vomiting. Get medical attention immediately. SKIN: Rinse the skin immediately with lots of water. Get medical attention if any discomfort continues. EYES: Rinse the eye with water immediately. Continue to rinse for at least 15 minutes and get medical attention. 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: This material is not flammable. 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS DURING SPILL: Prevent eye and skin contact. SPILL CLEANUP METHODS: Absorb in vermiculite, dry sand or earth and place into containers. 7 HANDLING AND STORAGE STORAGE PRECAUTIONS: Store at moderate temperatures in dry, well ventilated area. 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION INGREDIENT NAME CAS No STD LT EXP ST EXP (8 hrs) (15 min) PHOSPHORIC ACID 7664-38-2 OES 1 mg/m 3 2 mg/m3 POTASSIUM HYDROXIDE 1310-58-3 OES No std. 2 mg/m3 INGREDIENT COMMENTS: OES = Occupational Exposure Standard. PROTECTIVE EQUIPMENT: PROTECTIVE GLOVES: Protective gloves should be used if there is a risk of direct contact or splash. Page 488 of 1235 Page 488 of 1235 Page 488 of 1235 Page 488 of 1235 ---PAGE BREAK--- Page 2 of 2 MSDS K&N Air Filter Cleaner 99-0606EU, 99-0608EU, 99-5000EU, 99-5003EU EYE PROTECTION: Wear splash-proof eye goggles to prevent any possibility of eye contact. 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Liquid. COLOUR: Pink. pH: 8.5 10 STABILITY AND REACTIVITY STABILITY: Normally stable. 11 TOXICOLOGICAL INFORMATION HEALTH WARNINGS: INHALATION. May cause irritation to the respiratory system. SKIN CONTACT. Prolonged or repeated exposure may cause severe irritation. EYE CONTACT. May cause severe irritation to eyes. INGESTION. May cause discomfort. May cause stomach pain or vomiting. 12 ECOLOGICAL INFORMATION ENVIRONMENTAL HAZARDS: Not classified as dangerous to the environment. 13 DISPOSAL CONSIDERATIONS DISPOSAL METHODS: Dispose of in accordance with Local Authority requirements. 14 TRANSPORT INFORMATION GENERAL: NOT CLASSIFIED FOR TRANSPORT ROAD: RAIL: SEA: AIR: 15 REGULATORY INFORMATION HAZARD SYMBOLS: Irritant RISK PHRASES: R-36/38 Irritating to eyes and skin. SAFETY PHRASES: S-2 Keep out of reach of children. S-23 Do not breathe fumes or spray. S-24/25 Avoid contact with skin and eyes. S-26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S-35 This material and its container must be disposed of in a safe way. S-46 If swallowed seek medical advice immediately and show this container label. S-51 Use only in well ventilated areas. 16 OTHER INFORMATION R-PHRASES (Full Text): R-22 Harmful if swallowed. R-34 Causes burns. R-35 Causes severe burns. R-36 Irritating to eyes. R-40 Limited evidence of carcinogenic effect. R-53 May cause long-term adverse effects in the aquatic environment. Page 489 of 1235 Page 489 of 1235 Page 489 of 1235 Page 489 of 1235 ---PAGE BREAK--- The Kingsford Products Company 1221 Broadway Oakland, CA 94612 Tel. (510) 271-7000 Material Safety Data Sheet I Product: KINGSFORD ODORLESS CHARCOAL LIGHTER Description: ALIPHATIC PETROLEUM SOLVENT Other Designations Manufacturer Emergency Telephone Nos. The Kingsford Manufacturing Company 1221 Broadway Oakland, CA 94612 For Medical Emergencies call: (800) 446-1014 For Transportation Emergencies Chemtrac (800) 424-9300 II Health Hazard Data III Hazardous Ingredients Vapors may cause irritation to the nose, throat, and respiratory tract. Repeated or prolonged exposure to concentrations above the Worker Exposure Limit may cause central nervous system depression (e.g. dizziness, weakness, nausea, headaches and/or unconsciousness). Small amounts of liquid aspirated into lungs can cause chemical pneumonitis which can be fatal. Liquid may be irritating to eyes and skin. Solvents similar to this product have caused adverse kidney effects in male rats after prolonged and repeated inhalation exposure. Reports have associated repeated and prolonged occupational exposure to solvents with permanent brain and nervous system damage. Preexisting eye, skin, and respiratory disorders may be aggravated by exposure to this product. FIRST AID: INGESTION: DO NOT INDUCE VOMITING. Call a physician immediately. INHALATION: Remove from exposure. If irritation or breathing problems persist, call a physician. EYE CONTACT: Flush eyes thoroughly with water for at least 15 minutes; then call a physician. SKIN CONTACT: Wash skin with soap and water. If irritation occurs, call a physician. Ingredient Concentration Worker Exposure Limit Aliphatic petroleum solvent 100% 100 ppm - TLV-TWA a,b CAS # 8052-41-3 500 ppm - PEL-TWA b.c CAS # 64742-88-7 50 ppm - TLV-TWA d aTLV-TWA = ACGIH Threshold Limit Value-Time Weighted Average. bBased on the ACGIH TLV-TWA for Stoddard solvent. cPEL-TWA = OSHA Permissible Exposure Limit-Time Weighted Average. dClorox observes a 50 ppm exposure limit in its facilities. This material is not on the IARC, OSHA, or NTP carcinogen lists. IV Special Protection and Precautions V Transportation and Regulatory Data Hygienic Practices: Wash hands with soap and water after direct contact. Do not wear product-contaminated clothing for prolonged periods. Engineering Controls: Use local or general ventilation to minimize exposure to vapors. Personal Protective Equipment: Wear safety glasses or goggles. Wear chemical-resistant (e.g. nitrile) gloves if handling product for prolonged or repeated periods. Use a NIOSH-approved respirator if exposure may exceed occupational exposure limits. Keep container closed when not in use. Store away from open flames, sparks, heat sources, direct sunlight, strong oxidants, and corrosives. Do not smoke while using this product. DOT: Not restricted. IMO Proper Shipping Name:Dangerous goods in limited quantities of Class 3.3, PGIII. IATA Proper Shipping Name:Petroleum distillates, N.O.S., Class 3, UN 1268, PGIII. TSCA Status: This material is on the TSCA inventory. SCAQMD Status: Approved - reference number C13. EPA - SARA Title III/CERCLA: Packaged product is not reportable under Sections 311/312. This product contains no chemicals regulated under Section 313 or under Section 304/CERCLA. VI Spill Procedures/Waste Disposal VII Reactivity Data Spill Procedures: CAUTION - COMBUSTIBLE. Eliminate potential sources of ignition. Absorb and containerize. Do not wash down sanitary sewer. Waste Disposal: Dispose of in accordance with all applicable federal, state, and local regulations. Stable under normal use and storage conditions. Avoid contact with strong oxidants such as liquid chlorine, concentrated oxygen, and sodium or calcium hypochlorite. VIII Fire and Explosion Data IX Physical Data Flash Point: ~105°F (closed cup) Flammable limits by volume in air): 1% - 7% Fire Extinguishing Agents: Foam, water fog, dry chemical, or carbon dioxide (CO2). Do not use a direct stream of water. NFPA Class II Combustible Liquid. Boiling ~315 - 350°F Specific gravity 15 ~0.78 Vapor pressure 20 ~3 mm Hg Vapor density (air = 1) ~4.7 Solubility in Negligible 1983, 1991 THE CLOROX COMPANY DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH DATE PREPARED 10/98 Page 490 of 1235 Page 490 of 1235 Page 490 of 1235 Page 490 of 1235 ---PAGE BREAK--- 04/16/2015 Revision: 04/16/2015 Printed: Page: 1 Klean Strip Odorless Mineral Spirits SAFETY DATA SHEET 03/26/2015 Supersedes Revision: Klean Strip Odorless Mineral Spirits Product Name: W. M. Barr Company Name: 2105 Channel Avenue Memphis, TN 38113 3E 24 Hour Emergency Contact Emergency Contact: (800)451-8346 W.M. Barr Customer Service Information: (800)398-3892 1631.1 Reference (901)775-0100 Phone Number: Paint, stain, and varnish thinning. Intended Use: www.wmbarr.com Web site address: GKSP94006P, QKSP94005, QKSP94205, GKSP94006, GKSP94214 Synonyms: 1. PRODUCT AND COMPANY IDENTIFICATION This product is regulated by the United States Consumer Product Safety Commission and is subject to certain labeling requirements under the Federal Hazardous Substances Act. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS). The product label also includes other important information, including directions for use, and should always be read in its entirety prior to using the product. Additional Information 2. HAZARDS IDENTIFICATION P233: Keep container closed. P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P280: Wear protective gloves/protective clothing/eye protection/face protection. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting equipment. P243: Take precautionary measures against static discharge. P242: Use only non-sparking tools. GHS Precaution Phrases: P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331: Do NOT induce vomiting. P370+378: In case of fire, use dry chemical to extinguish. P303+361+353: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. GHS Response Phrases: P405: Store locked up. P501: Dispose of contents/container according to local, state and federal regulations. P403+235: Store in cool/well-ventilated place. GHS Storage and Disposal Phrases: H304: May be fatal if swallowed and enters airways. H226: Flammable liquid and vapor. GHS Hazard Phrases: Aspiration Toxicity, Category 1 Flammable Liquids, Category 3 Danger GHS Signal Word: Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 491 of 1235 Page 491 of 1235 Page 491 of 1235 Page 491 of 1235 ---PAGE BREAK--- 04/16/2015 Revision: 04/16/2015 Printed: Page: 2 Klean Strip Odorless Mineral Spirits SAFETY DATA SHEET 03/26/2015 Supersedes Revision: Hazard Rating System: Instability Special Hazard Health Flammability HEALTH FLAMMABILITY PPE PHYSICAL 1 0 2 * X 1 2 0 NFPA: HMIS: This material is classified as hazardous under OSHA regulations. OSHA Regulatory Status: None known. Medical Conditions Generally Aggravated By Exposure: Inhalation Acute Exposure Effects: Vapor concentration may cause headache, dizziness, irritation of the respiratory tract, eye irritation, stupor, depression of the central nervous system, watering of the eyes, weakness, nausea, muscle twitches, and kidney effects. Aspiration into lungs may cause pneumonia or death. Severe overexposure may cause convulsions, unconsciousness, and death. Skin Contact Acute Exposure Effects: May cause irritation. Eye Contact Acute Exposure Effects: Liquid contact may cause irritation. Ingestion Acute Exposure Effects: Harmful or fatal if swallowed. May cause nausea, weakness, muscle twitches, gastrointestinal irritation, diarrhea, unconsciousness, and death. Chronic Exposure Effects: Reports have associated repeated and prolonged overexposure to solvents with neurological and other physiological damage. Repeated or prolonged skin contact may cause redness, irritation, and scaling of the skin. May cause skin irritation, anemia, bone marrow damage, liver damage, and jaundice. Potential Health Effects (Acute and Chronic): CAS # Hazardous Components (Chemical Name) 3. COMPOSITION/INFORMATION ON INGREDIENTS Concentration RTECS # 64742-47-8 Hydrotreated light distillate (petroleum) 100.0 % OA5504000 4. FIRST AID MEASURES Inhalation: If user experiences breathing difficulty, move to air free of vapors. Administer oxygen or artificial respiration until medical assistance can be rendered. Skin contact: Wash with soap and large quantities of water for at least 15 minutes. Seek medical attention if irritation from contact persists. Eye contact: Immediately flush eyes with water, remove nay contact lens, continue flushing with water for at least 15 minutes. Get medical attention. Ingestion: Do not induce vomiting. Call your poison control center, hospital emergency room, or physician immediately. Emergency and First Aid Procedures: Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 492 of 1235 Page 492 of 1235 Page 492 of 1235 Page 492 of 1235 ---PAGE BREAK--- 04/16/2015 Revision: 04/16/2015 Printed: Page: 3 Klean Strip Odorless Mineral Spirits SAFETY DATA SHEET 03/26/2015 Supersedes Revision: Call your local poison control center for further instructions. Note to Physician: Primary routes of exposure: Inhalation, ingestion, and dermal. Signs and Of Exposure: 5. FIRE FIGHTING MEASURES Flash Pt: > 105.00 F Self-contained respiratory protection should be provided for fire fighters fighting fires in buildings or confined areas. Storage containers exposed to fire should be kept cool with water spray to prevent pressure build-up. Stay away from heads of containers that have been exposed to intense heat or flame. Fire Fighting Instructions: No data available. Flammable Properties and Hazards: Autoignition Pt: No data. Explosive Limits: LEL: 0.8 UEL: 6 NFPA Class II Use carbon dioxide, dry chemical powder, or foam. Suitable Extinguishing Media: 6. ACCIDENTAL RELEASE MEASURES Clean-up: Keep unnecessary people away, isolate hazard area and deny entry. Stay upwind, out of low areas, and ventilate closed spaces before entering. Shut off ignition sources, keep flares, smoking or flames out of hazard area. Small spills: Take up the spilled liquid with sand, earth, or other noncombustible absorbent material and place in a plastic container where applicable. Large spills: Dike far ahead of spill for later disposal. Steps To Be Taken In Case Material Is Released Or Spilled: 7. HANDLING AND STORAGE Read carefully all cautions and directions on product label before use. Since empty container retains residue, follow all label warnings even after container is empty. Dispose of empty container according to all regulations. Do not reuse this container. Precautions To Be Taken in Handling: Keep container closed when not in use. Store in a cool, dry place. Do not store near flames or at elevated temperatures. Precautions To Be Taken in Storing: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OSHA TWA ACGIH TWA CAS # Partial Chemical Name Other Limits No data. TLV: 200 mg/m3 64742-47-8 Hydrotreated light distillate (petroleum) No data. For OSHA controlled work place and other regular users. Use only with adequate ventilation under engineered air control systems designed to prevent exceeding appropriate TLV. For occasional use, where engineered air control is not feasible, use properly maintained and properly fitted NIOSH approved respirator for organic solvent vapors. A dust mask does not provide protection against vapors. Respiratory Equipment (Specify Type): Safety glasses, chemical goggles or face shields are recommended to safeguard against potential eye contact, irritation, or injury. Contact lenses should not be worn while working with chemicals. Eye Protection: Wear impermeable gloves. Gloves contaminated with product should be discarded. Protective Gloves: Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 493 of 1235 Page 493 of 1235 Page 493 of 1235 Page 493 of 1235 ---PAGE BREAK--- 04/16/2015 Revision: 04/16/2015 Printed: Page: 4 Klean Strip Odorless Mineral Spirits SAFETY DATA SHEET 03/26/2015 Supersedes Revision: remove clothing that becomes soiled with product. Various application methods can dictate use of additional protective safety equipment, such as impermeable aprons, etc., to minimize exposure. Before reuse, thoroughly clean any clothing or protective equipment that has been contaminated by prior use. Discard any clothing or other protective equipment that cannot be decontaminated, such as gloves or shoes. Other Protective Clothing: Use only with adequate ventilation to prevent build-up of vapors. Open all windows and doors. Use only with a cross ventilation of moving fresh air across the work area. If strong odor is noticed or you experience slight dizziness, headache, nausea, or eye-watering Stop ventilation is inadequate. Leave area immediately. Engineering Controls (Ventilation etc.): A source of clean water should be available in the work area for flushing eyes and skin. Do not eat, drink, or smoke in the work area. Wash hands thoroughly after use. Work/Hygienic/Maintenance Practices: 9. PHYSICAL AND CHEMICAL PROPERTIES Physical States: [ ] Gas [ X ] Liquid [ ] Solid Melting Point: No data. Boiling Point: 318.00 F - 354.00 F Autoignition Pt: No data. Flash Pt: > 105.00 F Explosive Limits: LEL: 0.8 UEL: 6 Specific Gravity (Water = 0.78 Colorless to light yellow Solvent odor Appearance and Odor: Vapor Pressure (vs. Air or mm Hg): No data. Vapor Density (vs. Air = 5 Air = 1 Evaporation Rate: No data. Solubility in Water: No data. Very soluble in cold water w/w) Solubility Notes: Percent Volatile: 100.0 % by weight. VOC / Volume: 780.0000 G/L Additional Physical Information Conductivity = <5 picosiemens/meter 10. STABILITY AND REACTIVITY No data available. Conditions To Avoid - Instability: Unstable [ ] Stable [ X ] Stability: Incompatible with strong oxidizing agents. Incompatibility - Materials To Avoid: Thermal decomposition may produce carbon monoxide and carbon dioxide. Hazardous Decomposition Or Byproducts: Will occur [ ] Will not occur [ X ] Possibility of Hazardous Reactions: No data available. Conditions To Avoid - Hazardous Reactions: Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 494 of 1235 Page 494 of 1235 Page 494 of 1235 Page 494 of 1235 ---PAGE BREAK--- 04/16/2015 Revision: 04/16/2015 Printed: Page: 5 Klean Strip Odorless Mineral Spirits SAFETY DATA SHEET 03/26/2015 Supersedes Revision: CAS # Hazardous Components (Chemical Name) NTP 11. TOXICOLOGICAL INFORMATION Refer to section 2 for acute and chronic effects. Toxicological Information: IARC ACGIH OSHA 64742-47-8 Hydrotreated light distillate (petroleum) n.a. n.a. A4 n.a. No data available. 12. ECOLOGICAL INFORMATION Dispose in accordance with applicable local, state, and federal regulations. Waste Disposal Method: 13. DISPOSAL CONSIDERATIONS 14. TRANSPORT INFORMATION Paint Related Material, Not Regulated DOT Proper Shipping Name: DOT Hazard Class: UN/NA Number: LAND TRANSPORT (US DOT): Paint Related Material EMS: F-E, S-E IMDG/IMO Shipping Name: MARINE TRANSPORT (IMDG/IMO): IUN1 UN Number: III Packing Group: Hazard Class: I IMDG MFAG Number: I IMDG EMS Page: Paint Related Material Packaging Instructions: See IATA Dangerous Goods Regulations ICAO/IATA Shipping Name: AIR TRANSPORT (ICAO/IATA): 1263 UN Number: III Packing Group: Hazard Class: The shipper may apply one of the following exceptions: Combustible Liquid, Consumer Commodity, Limited Quantity, Viscous Liquid, Does Not Sustain Combustion, or others, as allowed under 49CFR Hazmat Regulations. Please consult 49CFR Subchapter C to ensure that subsequent shipments comply with these exceptions. Additional Transport Information: CAS # Hazardous Components (Chemical Name) 15. REGULATORY INFORMATION S. 302 (EHS) S. 304 RQ S. 313 (TRI) EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists 64742-47-8 Hydrotreated light distillate (petroleum) No No No Yes [ ] No Acute (immediate) Health Hazard Yes [ ] No Chronic (delayed) Health Hazard Yes [ ] No Fire Hazard [ ] Yes No Sudden Release of Pressure Hazard [ ] Yes No Reactive Hazard This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated: Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 495 of 1235 Page 495 of 1235 Page 495 of 1235 Page 495 of 1235 ---PAGE BREAK--- 04/16/2015 Revision: 04/16/2015 Printed: Page: 6 Klean Strip Odorless Mineral Spirits SAFETY DATA SHEET 03/26/2015 Supersedes Revision: CAS # Hazardous Components (Chemical Name) Other US EPA or State Lists 64742-47-8 Hydrotreated light distillate (petroleum) CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No All components of this material are listed on the TSCA Inventory or are exempt. Regulatory Information Statement: 16. OTHER INFORMATION No data available. Additional Information About This Product: The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, state and local laws and regulations. Company Policy or Disclaimer: 04/16/2015 Revision Date: W.M. Barr EHS Department (901)775-0100 Preparer Name: Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 496 of 1235 Page 496 of 1235 Page 496 of 1235 Page 496 of 1235 ---PAGE BREAK--- 1 Page: KLEAN STRIP PAINT THINNER MATERIAL SAFETY DATA SHEET 1 2 0 Special Health Flammability Instability 10/03/2005 10/03/2005 Date Created: Revision: 12/14/2005 Printed: FLAMMABILITY PPE PHYSICAL HAZ. G HEALTH 2 0 2 1. Product and Company Identification Product Code: QPT1KS Product Name: KLEAN STRIP PAINT THINNER Reference 1677 Manufacturer Information Company Name: W. M. Barr 2105 Channel Avenue Memphis, TN 38113 Phone Number: (901)775-0100 Emergency Contact: 3E 24 Hour Emergency Contact (800)451-8346 Information: W.M. Barr Customer Service (800)398-3892 Web site address: www.wmbarr.com 2. Composition/Information on Ingredients Stoddard solvent Hazardous Components (Chemical Name) 8052-41-3 CAS # 95.0 -100.0 % Percentage 500 ppm OSHA TWA 100 ppm ACGIH TWA No data. Other Limits 1. 95-63-6 1.0 -2.0 % 200 ppm 50 ppm No data. 2. Raffinates (petroleum), sorption process 64741-85-1 95.0 -100.0 % 1000 ppm 500 ppm No data. 3. Stoddard solvent Hazardous Components (Chemical Name) WJ8925000 RTECS # No data. OSHA STEL No data. OSHA CEIL 250 ppm ACGIH STEL No data. ACGIH CEIL 1. DC3325000 500 ppm/(10min) 300 ppm No data. No data. 2. Raffinates (petroleum), sorption process NA No data. No data. 750 ppm No data. 3. 3. Hazards Identification Caution! Combustible. Keep away from heat, sparks, flame and all other sources of ignition. Vapors may cause fire. Vapors may travel long distances to other areas and rooms away from work site. Do not smoke. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and all other sources of ignition anywhere in the structure, dwelling or building during use and until all vapors are gone from work site and all areas away from work site. Keep away from electrical outlets and switches. Beware of static electricity that may be generated by clothing and other sources. Emergency Overview OSHA Regulatory Status: This material is classified as hazardous under OSHA regulations. Inhalation Acute Exposure Effects: May cause dizziness; headache; watering of eyes; eye irritation; weakness; nausea; muscle twitches, and depression of central nervous system. Severe overexposure may cause convulsions; unconsciousness; and death. Intentional misuse of this product by deliberately concentrating and inhaling can be harmful or fatal. Skin Contact Acute Exposure Effects: May cause irritation; numbness in the fingers and arms; drying of skin; and dermatitis. May cause increased severity of listed under inhalation. Eye Contact Acute Exposure Effects: This material is an eye irritant. May cause irritation; burns; conjunctivitis of eyes; and corneal ulcerations of the eye. Vapors may irritate eyes. Ingestion Acute Exposure Effects: Health Hazards (Acute and Chronic) Licensed to W.M. Barr and Company ANSI Z400.1 Format Page 497 of 1235 Page 497 of 1235 Page 497 of 1235 Page 497 of 1235 ---PAGE BREAK--- 10/03/2005 Revision: 12/14/2005 Printed: 2 Page: KLEAN STRIP PAINT THINNER MATERIAL SAFETY DATA SHEET Harmful or fatal if swallowed. May cause nausea; weakness; muscle twitches; gastrointestinal irritation; and diarrhea. Severe overexposure may cause convulsions; unconsciousness; and death. Chronic Exposure Effects: Reports have associated repeated and prolonged overexposure to solvents with neurological and other physiological damage. Prolonged or repeated contact may cause dermatitis. May cause jaundice; bone marrow damage; liver damage; anemia; and skin irritation. Inhalation, ingestion, and dermal are possible routes of exposure. Signs and Of Exposure Diseases of the skin, eyes, liver, kidneys, central nervous system and respiratory system. Medical Conditions Generally Aggravated By Exposure HEALTH HAZARDS : N/E PHYSICAL HAZARDS : N/E TARGET ORGANS & EFFECTS: N/E OSHA Hazard Classes: 4. First Aid Measures Inhalation: If user experiences breathing difficulty, move to air free of vapors, Administer oxygen or artificial medical assistance can be rendered. Skin Contact: Wash with soap and large quantities of water and seek medical attention if irritation from contact persists. Eye Contact: Flush with large quantities of water for at least 15 minutes and seek immediate medical attention. Ingestion: Do not induce vomiting. Call your local poison control center, hospital emergency room or physician immediately for instructions to induce vomiting. Emergency and First Aid Procedures Call your local poison control center for further information. Note to Physician 5. Fire Fighting Measures Flammability Classification: Class II Flash Pt: 105.00 F Method Used: SCC Explosive Limits: LEL: 1.00 UEL: No data. Autoignition Pt: No data. Self-contained respiratory protection should be provided for fire fighters fighting fires in buildings or confined areas. Storage containers exposed to fire should be kept cool with water spray to prevent pressure build-up. Stay away from heads of containers that have been exposed to intense heat or flame. Special Fire Fighting Procedures No data available. Unusual Fire and Explosion Hazards Use carbon dioxide, dry powder, or foam. Extinguishing Media No data available. Unsuitable Extinguishing Media Licensed to W.M. Barr and Company ANSI Z400.1 Format Page 498 of 1235 Page 498 of 1235 Page 498 of 1235 Page 498 of 1235 ---PAGE BREAK--- 10/03/2005 Revision: 12/14/2005 Printed: 3 Page: KLEAN STRIP PAINT THINNER MATERIAL SAFETY DATA SHEET 6. Accidental Release Measures Clean up: Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, out of low areas, and ventilate closed spaces before entering. Shut off ignition sources; keep flares, smoking or flames out of hazard area. Small spills: Take up with sand, earth or other noncombustible absorbent material and place in a plastic container where applicable. Large spills: Dike far ahead of spill for later disposal. Waste Disposal: Dispose in accordance with applicable local, state and federal regulations. Steps To Be Taken In Case Material Is Released Or Spilled 7. Handling and Storage Read carefully all cautions and directions on product label before use. Since empty container retains residue, follow all label warnings even after container is empty. Dispose of empty container according to all regulations. Do not reuse this container. Precautions To Be Taken in Handling Keep container closed when not in use. Store in a cool, dry place. Do not store near flames or at elevated temperatures. Precautions To Be Taken in Storing 8. Exposure Controls/Personal Protection For OSHA controlled work place and other regular users. Use only with adequate ventilation under engineered air control systems designed to prevent exceeding appropriate TLV. For occasional use, where engineered air control is not feasible, use properly maintained and properly fitted NIOSH approved respirator for organic solvent vapors. A dust mask does not provide protection against vapors. Respiratory Equipment (Specify Type) Safety glasses, goggles or face shields are recommended to safeguard against potential eye contact, irritation, or injury. Contact lenses should not be worn while working with chemicals. Eye Protection Wear impermeable gloves. Gloves contaminated with product should be discarded. remove clothing that becomes soiled with product. Protective Gloves Various application methods can dictate use of additional protective safety equipment, such as impermeable aprons, etc., to minimize exposure. A source of clean water should be available in the work area for flushing eyes and skin. Do not eat, drink, or smoke in the work area. Wash hands thoroughly after use. Before reuse, thoroughly clean any clothing or protective equipment that has been contaminated by prior use. Discard any clothing or other protective equipment that cannot be decontaminated, such as gloves or shoes. Other Protective Clothing Use only with adequate ventilation to prevent build-up of vapors. Open all windows and doors. Use only with a cross ventilation of moving fresh air across the work area. If strong odor is noticed or you experience slight dizziness, headache, nausea, or eye-watering - Stop - ventilation is inadequate. Leave area immediately. Ventilation Licensed to W.M. Barr and Company ANSI Z400.1 Format Page 499 of 1235 Page 499 of 1235 Page 499 of 1235 Page 499 of 1235 ---PAGE BREAK--- 10/03/2005 Revision: 12/14/2005 Printed: 4 Page: KLEAN STRIP PAINT THINNER MATERIAL SAFETY DATA SHEET 9. Physical and Chemical Properties Physical States: [ ] Gas [ X ] Liquid [ ] Solid Melting Point: No data. Boiling Point: > 310.00 F Autoignition Pt: No data. Flash Pt: 105.00 F Method: SCC Explosive Limits: LEL: 1.00 UEL: No data. Specfic Gravity: No data. Bulk Density: 6.659 LB/GA Vapor Presure: No data. Vapor Density: No data. Evaporation Rate: No data. Solubility in Water: No data. Percent Volatile: 100.0 % by weight. VOC / Volume: 800.0000 G/L Corrosion Rate: No data. pH: No data. Water White / Free and Clear Appearance and Odor 10. Stability and Reactivity Stability: Unstable [ ] Stable [ X ] No data available. Conditions To Avoid - Instability Incompatible with strong oxidizing agents. Incompatibility - Materials To Avoid Decomposition may produce carbon monoxide and carbon dioxide. Hazardous Decomposition Or Byproducts Hazardous Polymerization: Will occur [ ] Will not occur [ X ] No data available. Conditions To Avoid - Hazardous Polymerization 11. Toxicological Information No data available. Toxicological Information No data available. Carcinogenicity/Other Information Carcinogenicity: NTP? No IARC Monographs? No OSHA Regulated? No 12. Ecological Information No data available. Ecological Information 13. Disposal Considerations Dispose in accordance with federal, state, and local regulations. Waste Disposal Method Licensed to W.M. Barr and Company ANSI Z400.1 Format Page 500 of 1235 Page 500 of 1235 Page 500 of 1235 Page 500 of 1235 ---PAGE BREAK--- 10/03/2005 Revision: 12/14/2005 Printed: 5 Page: KLEAN STRIP PAINT THINNER MATERIAL SAFETY DATA SHEET 14. Transport Information LAND TRANSPORT (US DOT) No data available. DOT Proper Shipping Name 15. Regulatory Information US EPA SARA Title III Stoddard solvent Hazardous Components (Chemical Name) 8052-41-3 CAS # No Sec.302 (EHS) No Sec.304 RQ No Sec.313 (TRI) No Sec.110 1. 95-63-6 No No Yes No 2. Raffinates (petroleum), sorption process 64741-85-1 No No No No 3. US EPA CAA, CWA, TSCA Stoddard solvent Hazardous Components (Chemical Name) 8052-41-3 CAS # No EPA CAA No EPA CWA NPDES No EPA TSCA No CA PROP 65 1. 95-63-6 No No No No 2. Raffinates (petroleum), sorption process 64741-85-1 No No No No 3. SARA (Superfund Amendments and Reauthorization Act of 1986) Lists: Sec.302: EPA SARA Title III Section 302 Extremely Hazardous Chemical with TPQ. * indicates 10000 LB TPQ if not volatile. Sec.304: EPA SARA Title III Section 304: CERCLA Reportable + Sec.302 with Reportable Quantity. indicates statutory RQ. Sec.313: EPA SARA Title III Section 313 Toxic Release Inventory. Note: -Cat indicates a member of a chemical category. Sec.110: EPA SARA 110 Superfund Site Priority Contaminant List TSCA (Toxic Substances Control Act) Lists: 5A(2): Chemical Subject to Significant New Rules (SNURS) 6A: Commercial Chemical Control Rules 8A: Toxic Substances Subject To Information Rules on Production 8A CAIR: Comprehensive Assessment Information Rules - (CAIR) 8A PAIR: Preliminary Assessment Information Rules - (PAIR) 8C: Records of Allegations of Significant Adverse Reactions 8D: Health and Safety Data Reporting Rules 8D TERM: Health and Safety Data Reporting Rule Terminations Other Important Lists: CWA NPDES: EPA Clean Water Act NPDES Permit Chemical CAA HAP: EPA Clean Air Act Hazardous Air Pollutant CAA ODC: EPA Clean Air Act Ozone Depleting Chemical (1=CFC, 2=HCFC) CA PROP 65: California Proposition 65 This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated: EPA Hazard Categories: [ ] Yes No Acute (immediate) Health Hazard [ ] Yes No Chronic (delayed) Health Hazard [ ] Yes No Fire Hazard [ ] Yes No Reactive Hazard [ ] Yes No Sudden Release of Pressure Hazard Licensed to W.M. Barr and Company ANSI Z400.1 Format Page 501 of 1235 Page 501 of 1235 Page 501 of 1235 Page 501 of 1235 ---PAGE BREAK--- 10/03/2005 Revision: 12/14/2005 Printed: 6 Page: KLEAN STRIP PAINT THINNER MATERIAL SAFETY DATA SHEET 16. Other Information The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, state and local laws and regulations. Company Policy or Disclaimer Licensed to W.M. Barr and Company ANSI Z400.1 Format Page 502 of 1235 Page 502 of 1235 Page 502 of 1235 Page 502 of 1235 ---PAGE BREAK--- 04/14/2015 Revision: 04/14/2015 Printed: Page: 1 Klean Strip Xylol Xylene SAFETY DATA SHEET 03/26/2015 Supersedes Revision: Klean Strip Xylol Xylene Product Name: W. M. Barr Company Name: 2105 Channel Avenue Memphis, TN 38113 3E 24 Hour Emergency Contact Emergency Contact: (800)451-8346 W.M. Barr Customer Service Information: (800)398-3892 (901)775-0100 Phone Number: Paint, stain, and varnish thinning. Intended Use: www.wmbarr.com Web site address: GXY24, QXY24, CXY24 Synonyms: 1. PRODUCT AND COMPANY IDENTIFICATION This product is regulated by the United States Consumer Product Safety Commission and is subject to certain labeling requirements under the Federal Hazardous Substances Act. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS). The product label also includes other important information, including directions for use, and should always be read in its entirety prior to using the product. Additional Information 2. HAZARDS IDENTIFICATION P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P233: Keep container closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P260: Do not breathe gas/mist/vapors/spray. P264: Wash hands thoroughly after handling. GHS Precaution Phrases: H226: Flammable liquid and vapor. H304: May be fatal if swallowed and enters airways. H312: Harmful in contact with skin. H315: Causes skin irritation. H319: Causes serious eye irritation. H332: Harmful if inhaled. H335: May cause respiratory irritation. H351: Suspected of causing cancer if inhaled. H373: May cause damage to ears through prolonged or repeated exposure if inhaled. GHS Hazard Phrases: Flammable Liquids, Category 3 Acute Toxicity: Skin, Category 4 Acute Toxicity: Inhalation, Category 4 Skin Corrosion/Irritation, Category 2 Serious Eye Damage/Eye Irritation, Category 2A Carcinogenicity, Category 2 Specific Target Organ Toxicity (single exposure), Category 3 Specific Target Organ Toxicity (repeated exposure), Category 2 Aspiration Toxicity, Category 1 Danger GHS Signal Word: Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 503 of 1235 Page 503 of 1235 Page 503 of 1235 Page 503 of 1235 ---PAGE BREAK--- 04/14/2015 Revision: 04/14/2015 Printed: Page: 2 Klean Strip Xylol Xylene SAFETY DATA SHEET 03/26/2015 Supersedes Revision: P271: Use only outdoors or in a well-ventilated area. P280: Wear protective gloves/protective clothing/eye protection/face protection. P235: Keep cool. P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302+352: IF ON SKIN: Wash with plenty of soap and water. P303+361+353: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+313: IF exposed or concerned: Get medical attention/advice. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P314: Get medical attention/advice if you feel unwell. P321: Specific treatment see label. P331: Do NOT induce vomiting. P332+313: If skin irritation occurs, get medical advice/attention. P337+313: If eye irritation persists, get medical advice/attention. P362: Take off contaminated clothing and wash before re-use. P363: Wash contaminated clothing before reuse. P370+378: In case of fire, use dry chemical powder to extinguish. GHS Response Phrases: P403+233: Store container closed in well-ventilated place. P405: Store locked up. P501: Dispose of contents/container according to local, state and federal regulations. GHS Storage and Disposal Phrases: Hazard Rating System: Instability Special Hazard Health Flammability HEALTH FLAMMABILITY PPE PHYSICAL 2 0 3 * X 2 3 0 NFPA: HMIS: This material is classified as hazardous under OSHA regulations. OSHA Regulatory Status: Inhalation Acute Exposure Effects: Vapor harmful. May cause dizziness, headache, irritation of respiratory tract, weakness, drowsiness, depression of central nervous system, and watering of eyes. Severe overexposure may cause unconsciousness, anesthesia, irregular heartbeat, and death. Intentional misuse of this product by deliberately concentrating and inhaling can be harmful or fatal. Skin Contact Acute Exposure Effects: This product is a skin irritant. It may be absorbed through the skin. It may cause irritation, dermatitis, drying of skin, and numbness in fingers and arms. May increase severity of listed under inhalation. Eye Contact Acute Exposure Effects: This material is an eye irritant. It may cause irritation, redness, stinging, tearing, excessive swelling of the conjunctiva; and or excessive blinking. Ingestion Acute Exposure Effects: Harmful or fatal if swallowed. May cause nausea, vomiting, gastrointestinal irritation, or diarrhea. Chronic Exposure Effects: Reports have associated repeated and prolonged overexposure to solvents with Potential Health Effects (Acute and Chronic): Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 504 of 1235 Page 504 of 1235 Page 504 of 1235 Page 504 of 1235 ---PAGE BREAK--- 04/14/2015 Revision: 04/14/2015 Printed: Page: 3 Klean Strip Xylol Xylene SAFETY DATA SHEET 03/26/2015 Supersedes Revision: Diseases of the skin, liver, and kidneys. Medical Conditions Generally Aggravated By Exposure: neurological and other physiological damage. Prolonged or repeated contact may cause dermatitis. May cause skin irritation, permanent central nervous system changes, kidney damage, and liver damage. CAS # Hazardous Components (Chemical Name) 3. COMPOSITION/INFORMATION ON INGREDIENTS Concentration RTECS # 1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} 60.0 -100.0 % ZE2100000 100-41-4 Phenylethane} 10.0 -30.0 % DA0700000 98-82-8 Cumene {Benzene, 1-Methylethyl-; Isopropylbenzene} 0.1 -1.0 % GR8575000 is a component of Xylene. Additional Chemical Information 4. FIRST AID MEASURES Inhalation: If user experiences breathing difficulty, move to air free of vapors. Administer oxygen or artificial respiration until medical assistance can be rendered. Skin Contact: Irritation may result. Immediately wash with soap and water. Eye Contact: Immediately flush with water, remove any contact lenses, continue flushing with water for at least 15 minutes, then get medical attention. Ingestion: Do not induce vomiting. Call you local poison control center, hospital emergency room, or physician immediately for instructions. Emergency and First Aid Procedures: Call your local poison control center for further information. Note to Physician: See Potential Health Effects. Signs and Of Exposure: 5. FIRE FIGHTING MEASURES Flash Pt: 81.00 F Method Used: Closed Cup Self-contained respiratory protection should be provided for fire fighters fighting fires in buildings or confined areas. Storage containers exposed to fire should be kept cool with water spay to prevent pressure build-up. Stay away from heads of containers that have been exposed to intense heat or flame. Fire Fighting Instructions: Flammable Liquid! This material releases vapors at or below ambient temperatures. When mixed with air in certain proportions and exposed to an ignition source, its vapor can cause a flash fire. Use only with adequate ventilation. Vapors are heavier than air and may travel long distances along the ground to an ignition source and flash back. A vapor and air Flammable Properties and Hazards: Autoignition Pt: 432.00 C Explosive Limits: LEL: AP 1% UEL: AP 7% NFPA Class IC flammable liquid Use carbon dioxide, dry powder, or foam. Suitable Extinguishing Media: Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 505 of 1235 Page 505 of 1235 Page 505 of 1235 Page 505 of 1235 ---PAGE BREAK--- 04/14/2015 Revision: 04/14/2015 Printed: Page: 4 Klean Strip Xylol Xylene SAFETY DATA SHEET 03/26/2015 Supersedes Revision: mixture can create an explosion hazard in confined spaces such as sewers. If container is not properly cooled, it can rupture in the heat of a fire. Flammability Classification: 6. ACCIDENTAL RELEASE MEASURES Vapors may cause flash fire or ignite explosively. Clean up: Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, out of low areas, and ventilate closed spaces before entering. Shut off ignition sources; keep flares, smoking or flames out of hazard area. Use non-sparking tools. Use proper bonding and grounding methods for all equipment and processes. Keep out of waterways and bodies of water. Be cautious of vapors collecting in small enclosed spaces, sewers, low lying areas, confined spaces, etc. Small spills: Take up with sand, earth or other noncombustible absorbent material and place in a plastic container where applicable. Large spills: Dike far ahead of spill for later disposal. Waste Disposal: Dispose in accordance with applicable local, state and federal regulations. Steps To Be Taken In Case Material Is Released Or Spilled: 7. HANDLING AND STORAGE Read carefully all cautions and directions on product label before use. Since empty container retains residue, follow all label warnings even after container is empty. Dispose of empty container according to all regulations. Do not reuse this container. Do not use this product near any source of heat or open flame, furnace areas, pilot lights, stoves, etc. Do not use in small enclosed spaces, such as basements and bathrooms. Vapors can accumulate and explode if ignited. Do not spread this product over large surface areas because fire and health safety risks will increase dramatically. Precautions To Be Taken in Handling: Keep container closed when not in use. Store in a cool, dry place. Do not store near flames or at elevated temperatures. Precautions To Be Taken in Storing: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OSHA TWA ACGIH TWA CAS # Partial Chemical Name Other Limits PEL: 100 ppm TLV: 100 ppm STEL: 150 ppm 1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} No data. PEL: 100 ppm TLV: 100 ppm STEL: 125 ppm 100-41-4 Phenylethane} No data. PEL: 50 ppm TLV: 50 ppm 98-82-8 Cumene {Benzene, 1-Methylethyl-; Isopropylbenzene} No data. Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 506 of 1235 Page 506 of 1235 Page 506 of 1235 Page 506 of 1235 ---PAGE BREAK--- 04/14/2015 Revision: 04/14/2015 Printed: Page: 5 Klean Strip Xylol Xylene SAFETY DATA SHEET 03/26/2015 Supersedes Revision: For OSHA controlled work place and other regular users --Use only with adequate ventilation under engineered air control systems designed to prevent exceeding appropriate TLV. For occasional use, where engineered air control is not feasible, use properly maintained and properly fitted NIOSH approved respirator for organic solvent vapors. A dust mask does not provided protection against vapors. Respiratory Equipment (Specify Type): Safety glasses, chemical goggles or face shields are recommended to safeguard against potential eye contact, irritation, or injury. Contact lenses should not be worn while working with chemicals. Eye Protection: Wear gloves with as much resistance to the chemical ingredients as possible. Glove materials such as nitrile rubber may provide protection. Glove selection should be based on chemicals being used and conditions of use. Consult your glove supplier for additional information. Gloves contaminated with product should be discarded and not reused. Protective Gloves: Various application methods can dictate the use of additional protective safety equipment, such as impermeable aprons, etc., to minimize exposure. Other Protective Clothing: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use only with adequate ventilation to prevent buildup of vapors. Do not use in areas where vapors can accumulate and concentrate, such as basements, bathrooms or small enclosed areas. Whenever possible, use outdoors in an open air area. If using indoors open all windows and doors and maintain a cross ventilation of moving fresh air across the work area. If strong odor is noticed or you experience slight dizziness, headache, nausea or eye-watering STOP ventilation is inadequate. Leave area immediately and move to fresh air. Engineering Controls (Ventilation etc.): Wash hands thoroughly after use and before eating, drinking, or smoking. Do not eat, drink, or smoke in the work area. Discard any clothing or other protective equipment that cannot be decontaminated. Facilities storing or handling this material should be equipped with an emergency eyewash and safety shower. Work/Hygienic/Maintenance Practices: 9. PHYSICAL AND CHEMICAL PROPERTIES Physical States: [ ] Gas [ X ] Liquid [ ] Solid Melting Point: -48.00 C - -25.00 C Boiling Point: 280.00 F - 288.00 F Autoignition Pt: 432.00 C Flash Pt: 81.00 F Method Used: Closed Cup Explosive Limits: LEL: AP 1% UEL: AP 7% Specific Gravity (Water = 0.87 Density: 7.18 LB/GL at 77.0 F Sweet, pungent aromatic hydrocarbon Appearance and Odor: Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 507 of 1235 Page 507 of 1235 Page 507 of 1235 Page 507 of 1235 ---PAGE BREAK--- 04/14/2015 Revision: 04/14/2015 Printed: Page: 6 Klean Strip Xylol Xylene SAFETY DATA SHEET 03/26/2015 Supersedes Revision: Vapor Pressure (vs. Air or mm Hg): 7 MM HG at 20.0 C Vapor Density (vs. Air = No data. Evaporation Rate: No data. Solubility in Water: No data. Percent Volatile: 99.999 % by weight. VOC / Volume: 872.0000 G/L 10. STABILITY AND REACTIVITY No data available. Conditions To Avoid - Instability: Unstable [ ] Stable [ X ] Stability: Incompatible with strong oxidizing agents. Incompatibility - Materials To Avoid: Decomposition may produce carbon monoxide and carbon dioxide. Hazardous Decomposition Or Byproducts: Will occur [ ] Will not occur [ X ] Possibility of Hazardous Reactions: No data available. Conditions To Avoid - Hazardous Reactions: 11. TOXICOLOGICAL INFORMATION Overexposure to xylene may cause upper respiratory tract irritation, headache, cyanosis, blood serum changes, CNS damage and narcosis. Effects may be increased by the use of alcoholic beverages. Evidence of liver and kidney impairment were reported in workers recovering from a gross over-exposure. Toxicological Information: CAS# 1330-20-7: Acute toxicity, LC50, Inhalation, Rat, 5000. PPM, 4 H. Result: Behavioral: Muscle contraction or spasticity. Lungs, Thorax, or Respiration:Other changes. - Raw Material Data Handbook, Vol.1: Organic Solvents, 1974., National Assoc. of Printing Ink Research Institute, Francis McDonald Sinclair Memorial Labor, Lehigh Univ., Bethlehem, PA 18015, Vol/p/yr: 1,123, 1974 Standard Draize Test, Eyes, Species: Rabbit, 5.000 MG, 24 H, Severe. Result: Behavioral: General anesthetic. Behavioral: Somnolence (general depressed activity). Behavioral: Irritability. - "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," , Institut Pro Vychovu Vedoucicn P, Marhold, J.V., Institut Pro Vychovu Vedoucicn, Pracovniku Chemickeho, Prumyclu Praha Czechoslovakia, Vol/p/yr: -,24, 1972 CAS# 100-41-4: Tumorigenic Effects:, TCLo, Inhalation, Rat, 750.0 ppm. Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 508 of 1235 Page 508 of 1235 Page 508 of 1235 Page 508 of 1235 ---PAGE BREAK--- 04/14/2015 Revision: 04/14/2015 Printed: Page: 7 Klean Strip Xylol Xylene SAFETY DATA SHEET 03/26/2015 Supersedes Revision: Xylene, all isomers: Effects from Prolonged or Repeated Exposure: Impaired neurological function was reported in workers exposed to solvents including xylene. Studies in laboratory animals have shown evidence of impaired hearing following high levels of exposure. Studies in laboratory animals suggest some changes in reproductive organs following high levels of exposure but no significant effects on reproduction were observed. Studies in laboratory animals indicate skeletal and visceral malformations, developmental delays, and increased fetal resorptions following extremely high levels of maternal exposure. Adverse effects on the liver, kidney, bone marrow (changes in blood cell parameters) were observed in laboratory animals following high levels of exposure. The relevance of these observations to humans is not clear at this time. Ethyl Benzene: Effects from Prolonged or Repeated Exposure: Findings from a 2-year inhalation study in rodents conducted by NTP were as follows: Effects were observed only at the highest exposure level (750 ppm). At this level the incidence of renal tumors was elevated in male rats (tubular carcinomas) and female rats (tubular adenomas). Also, the incidence of tumors was elevated in male mice (alveolar and bronchiolar carcinomas) and female mice (hepatocellular carcinomas). IARC has classified ethyl benzene as “possibly carcinogenic to humans” (Group 2B). Studies in laboratory animals indicate some evidence of post-implantation deaths following high levels of maternal exposure. The relevance of these findings to humans is not clear at this time. Studies in laboratory animals indicate limited evidence of renal malformations, resorptions, and developmental delays following high levels of maternal exposure. The relevance of these findings to humans is not clear at this time. Studies in laboratory animals indicate some evidence of adverse effects on the liver, kidney, thyroid, and pituitary gland. Chronic Toxicological Effects: IARC 2B - Possibly Carcinogenic to Humans ACGIH A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans ACGIH A4 - Not Classifiable as a Human Carcinogen. Carcinogenicity/Other Information: Result: Tumorigenic: Carcinogenic by RTECS criteria. Kidney, Ureter, Bladder: Tumors. Standard Draize Test, Eyes, Species: Rabbit, 500.0 MG, Severe. Result: Effects on Fertility: Post-implantation mortality dead and/or resorbed implants per total number of implants). Effects on Fertility: Litter size # fetuses per litter; measured before birth). Effects on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus). - American Journal of Ophthalmology., Ophthalmic Pub. Co., 435 N. Michigan Ave., Suite 1415, Chicago, IL 60611, Vol/p/yr: 29,1363, 1946 Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 509 of 1235 Page 509 of 1235 Page 509 of 1235 Page 509 of 1235 ---PAGE BREAK--- 04/14/2015 Revision: 04/14/2015 Printed: Page: 8 Klean Strip Xylol Xylene SAFETY DATA SHEET 03/26/2015 Supersedes Revision: CAS # Hazardous Components (Chemical Name) NTP IARC ACGIH OSHA 1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} n.a. 3 A4 n.a. 100-41-4 Phenylethane} n.a. 2B A3 n.a. 98-82-8 Cumene {Benzene, 1-Methylethyl-; Isopropylbenzene} n.a. 2B n.a. n.a. No data available. 12. ECOLOGICAL INFORMATION Dispose in accordance with local, state, and federal regulations. Waste Disposal Method: 13. DISPOSAL CONSIDERATIONS 14. TRANSPORT INFORMATION Xylenes DOT Proper Shipping Name: 3 FLAMMABLE LIQUID DOT Hazard Class: UN1307 UN/NA Number: III Packing Group: LAND TRANSPORT (US DOT): The shipper/supplier may apply one of the following exceptions: Combustible Liquid, Consumer Commodity, Limited Quantity, Viscous Liquid, Does Not Sustain Combustion, or others, as allowed under 49CFR Hazmat Regulations. Please consult 49CFR Subchapter C to ensure that subsequent shipments comply with these exceptions. Additional Transport Information: CAS # Hazardous Components (Chemical Name) 15. REGULATORY INFORMATION S. 302 (EHS) S. 304 RQ S. 313 (TRI) EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists 1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} No Yes 100 LB Yes 100-41-4 Phenylethane} No Yes 1000 LB Yes 98-82-8 Cumene {Benzene, 1-Methylethyl-; Isopropylbenzene} No Yes 5000 LB Yes Yes [ ] No Acute (immediate) Health Hazard Yes [ ] No Chronic (delayed) Health Hazard Yes [ ] No Fire Hazard [ ] Yes No Sudden Release of Pressure Hazard [ ] Yes No Reactive Hazard This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated: CAS # Hazardous Components (Chemical Name) Other US EPA or State Lists 1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} CAA HAP,ODC: HAP; CWA NPDES: Yes; TSCA: Yes - Inventory; CA PROP.65: No 100-41-4 Phenylethane} CAA HAP,ODC: HAP; CWA NPDES: Yes; TSCA: Yes - Inventory, 4 Test; CA PROP.65: Yes 98-82-8 Cumene {Benzene, 1-Methylethyl-; Isopropylbenzene} CAA HAP,ODC: HAP; CWA NPDES: No; TSCA: Yes - Inventory, 4 Test; CA PROP.65: Yes Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 510 of 1235 Page 510 of 1235 Page 510 of 1235 Page 510 of 1235 ---PAGE BREAK--- 04/14/2015 Revision: 04/14/2015 Printed: Page: 9 Klean Strip Xylol Xylene SAFETY DATA SHEET 03/26/2015 Supersedes Revision: All components of this material are listed on the TSCA Inventory or are exempt. Regulatory Information Statement: 16. OTHER INFORMATION No data available. Additional Information About This Product: The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, state and local laws and regulations. Company Policy or Disclaimer: 04/14/2015 Revision Date: W.M. Barr EHS Department (901)775-0100 Preparer Name: Licensed to W.M. Barr and Company: MIRS MSDS, A V Systems, Inc. GHS format Page 511 of 1235 Page 511 of 1235 Page 511 of 1235 Page 511 of 1235 ---PAGE BREAK--- 1 MATERIAL SAFETY DATA SHEET Klotz Special Formula Products, Inc. Telephone Number: 7424 Freedom Way [PHONE REDACTED] Fort Wayne, IN 46818 [PHONE REDACTED] (fax) Chemtrec – 1-[PHONE REDACTED] Chemical Name & Synonyms Chemical Family Foam Air Filter Oil Trade Name: Klotz Foam Air Filter Oil (Aerosol) – KL-606 Lubricant Propane Weight Percent: 88% 12% CAS No.: 64742-52-5 00074-98-6 OSHA PEL: NE 1000 PPM ACGIH TLV: NE Vapor Pressure (mmHg@ 68) .01 6350 Boiling Point: -44°F Specific Gravity: 0.81 Freezing Point: N/A % Volatile By Volume: N/A Melting Point: N/A Viscosity SUS: N/A Vapor Pressure (mmHg): .01 Vapor Density (Air=1): Heavier than Air Solubility in Water: Nil Bulk Density: N/A Evaporation Rate (Water=1): Slower than Ether Pour Point: N/A Decomposition Temp: N/A Appearance: Aerosol product Odor: Aerosol product Weight per gallon: Auto ignition Temperature: N/A Flammability in Air: Lower: 2.1 Upper: 9.5 Flash Point: N/A Basic Fire Fighting Procedures: Foam, CO2, Dry Chemical, Water Fog Unusual Fire & Explosion Hazards: Closed containers may explode from internal pressure build-up when exposed to extreme heat and discharge contents. Vapor accumulation can flash or explode if ignited. Overexposure to decomposition products may cause a health hazard. may not be readily apparent. Obtain medical attention. Special Fire and Explosion Hazards: Water spray may be ineffective. Water may be used to cool containers to prevent pressure build-up and explosion when exposed to extreme heat. If water is used, fog nozzles preferred. Wear goggles and self-contained breathing apparatus. SECTION I - IDENTIFICATION SECTION II - HAZARDOUS COMPONENTS SECTION III - PHYSICAL DATA SECTION IV - FIRE & EXPLOSION HAZARD INFORMATION Page 512 of 1235 Page 512 of 1235 Page 512 of 1235 Page 512 of 1235 ---PAGE BREAK--- 2 Incompatibility: Strong oxidizing agents. Stability: Stable Hazardous Polymerization: Will not occur. Hazardous Reactions/Decomposition Products: May produce fumes when heated to decomposition. Fumes may contain carbon monoxide. Conditions to avoid: Application to hot surfaces. Storage above 120°F. Exposure to open flame. Spill or Release to the Environment: Avoid breathing vapors. Ventilate area. Remove all sources of ignition. Clean up area with absorbent material and place in closed containers for disposal. Waste Disposal: DO NOT incinerate. Dispose in accordance with Federal, State and Local regulations regarding pollution. Before attempting clean up, refer to other sections of this MSDS for hazard caution information. The Routes of Exposure and the Effects of Overexposure Ingestion: Not a likely route of exposure. If swallowed, DO NOT induce vomiting. Seek immediate medical advice and/or attention. Skin: Not easily absorbed. Solvent action can dry and defat the skin causing the skin to crack, leading to dermatitis. Prolonged contact may cause moderate irritation. Eyes: Liquid or vapor can cause moderate to severe irritation. Inhalation: May cause respiratory irritation, headache, nausea, fatigue, drowsiness, impaired co-ordination. Ingestion: DO NOT INDUCE VOMITING. Call physician immediately. Skin Contact: Wipe off with towel. Wash with soap and water. Get medical attention if irritation persists. Inhalation: Remove to fresh air. Administer oxygen if needed. Apply artificial respiration if breathing has stopped. Get medical attention. Eye Contact: Wash immediately with large volumes of fresh water for at least 15 minutes. Get medical attention. Handling/Storage: Store and use in cool, dry, well-ventilated areas. DO NOT store above 120°F. DO NOT puncture or incinerate (burn) cans. DO NOT stick pin, nail, or any other sharp object into opening on top of can. DO NOT spray in eyes. DO NOT take internally. See product label for additional information. Skin Protection: Wear impervious gloves and protective clothing to prevent skin contact. Respiratory Protection: None under normal use. Avoid breathing vapors. In restricted areas, use approved chemical/mechanical filters designed to remove a combination of particles and vapor. In confined areas, use SECTION V - REACTIVITY DATA SECTION VI - SPILL, LEAK, & DISPOSAL PROCEDURES SECTION VII - HEALTH HAZARD DATA SECTION VIII - FIRST AID PROCEDURES SECTION IX - SPECIAL PROTECTION INFORMATION Page 513 of 1235 Page 513 of 1235 Page 513 of 1235 Page 513 of 1235 ---PAGE BREAK--- 3 approved air line type respirator or hood. Self-contained breathing apparatus is required for vapor concentrations above PEL/TLV limits. Eye Protection: None under normal use; however, use of safety glasses with splash guards or full face shield is recommended. DO NOT wear contact lenses when working with this substance. Have eye baths readily available where eye contact can occur. Other Protective Clothing or Equipment: None under normal use; however, use of solvent resistant to aprons or other clothing is recommended. Ventilation: Sufficient to prevent inhalation of solvent vapors. General dilution and/or local exhaust ventilation in volume or pattern to keep PEL/TLV of most hazardous ingredients below acceptable limit and LEL below stated limit. Other Precautions: Small pressurized containers of flammable products may be stored in areas suitable for ordinary combustibles with respect to construction, drainage, control of ignition sources, and ventilation. They should not be stored in basements. Work/Hygienic Practices: Eye washes and safety showers in the workplace are recommended. DOT Not Regulated ORM-D DOT Category: Consumer Commodity ORM-D Hazard ID Number: UN 1950 Packaging Group: N/A IMCO Hazard Class: 2 IMCO Page 95 2004 Edition RCRA Classification: Not a Marine Pollutant Revised: 2-24-05 SECTION X - DOT TRANSPORTATION Page 514 of 1235 Page 514 of 1235 Page 514 of 1235 Page 514 of 1235 ---PAGE BREAK--- Page 515 of 1235 Page 515 of 1235 Page 515 of 1235 Page 515 of 1235 ---PAGE BREAK--- Page 516 of 1235 Page 516 of 1235 Page 516 of 1235 Page 516 of 1235 ---PAGE BREAK--- Page 517 of 1235 Page 517 of 1235 Page 517 of 1235 Page 517 of 1235 ---PAGE BREAK--- Page 518 of 1235 Page 518 of 1235 Page 518 of 1235 Page 518 of 1235 ---PAGE BREAK--- Page 519 of 1235 Page 519 of 1235 Page 519 of 1235 Page 519 of 1235 ---PAGE BREAK--- Page 520 of 1235 Page 520 of 1235 Page 520 of 1235 Page 520 of 1235 ---PAGE BREAK--- Page 521 of 1235 Page 521 of 1235 Page 521 of 1235 Page 521 of 1235 ---PAGE BREAK--- Page 522 of 1235 Page 522 of 1235 Page 522 of 1235 Page 522 of 1235 ---PAGE BREAK--- Material Safety Data Sheet Page 1 of 7 Section 1: Product & Company Identification Product Name: Lectra Motive® Electric Parts Cleaner (aerosol) Product Number 05018 Product Use: Energized Electrical Cleaner Manufacturer / Supplier Contact Information: In United States: In Canada: In Mexico: CRC Industries, Inc. CRC Canada Co. CRC Industries Mexico 885 Louis Drive 2-1246 Lorimar Drive Av. Benito Juárez 4055 G Warminster, PA 18974 Mississauga, Ontario L5S 1R2 Colonia Orquídea www.crcindustries.com www.crc-canada.ca San Luís Potosí, SLP CP 78394 1-[PHONE REDACTED] (General) 1-[PHONE REDACTED] www.crc-mexico.com (800) 521-3168 (Technical) 52-[PHONE REDACTED] (800) 272-4620 (Customer Service) 24-Hr Emergency – CHEMTREC: (800) 424-9300 or (703) 527-3887 Section 2: Hazards Identification Emergency Overview DANGER: Vapor Harmful. Contents Under Pressure. Appearance & Odor: Colorless liquid, irritating odor at high concentrations. Potential Health Effects: ACUTE EFFECTS: EYE: May cause slight temporary eye irritation. Vapors may irritate the eyes at concentrations of 100 ppm. SKIN: Short single exposure may cause skin irritation. Prolonged exposure may cause severe skin irritation, even a burn. A single prolonged exposure is not likely to result in the material being absorbed through the skin in harmful amounts. INHALATION: Dizziness may occur at concentrations of 200 ppm. Progressively higher levels may also cause nasal irritation, nausea, incoordination, and drunkenness. Very high levels or prolonged exposure could lead to unconsciousness and death. INGESTION: Single dose oral toxicity is considered to be extremely low. Swallowing large amounts may cause injury if aspirated into the lungs. This may be rapidly absorbed through the lungs and result in injury to other body systems. CHRONIC EFFECTS: Repeated contact with skin may cause drying or flaking of skin. Excessive or long term exposure to vapors may increase sensitivity to epinephrine and increase myocardial irritability. TARGET ORGANS: Central nervous system, possibly liver and kidney Medical Conditions Aggravated by Exposure: None known. See Section 11 for toxicology and carcinogenicity information on product ingredients. Page 523 of 1235 Page 523 of 1235 Page 523 of 1235 Page 523 of 1235 ---PAGE BREAK--- Product Name: Lectra Motive® Electric Parts Cleaner (aerosol) Product Number 05018 Page 2 of 7 Section 3: Composition/Information on Ingredients COMPONENT CAS NUMBER % by Wt. Tetrachloroethylene (PERC) 127-18-4 > 95 Carbon Dioxide 124-38-9 < 5 Section 4: First Aid Measures Eye Contact: Immediately flush with plenty of water for 15 minutes. Call a physician if irritation persists. Skin Contact: Remove contaminated clothing and wash affected area with soap and water. Call a physician if irritation persists. Wash contaminated clothing prior to re-use. Inhalation: Remove person to fresh air. Keep person calm. If not breathing, give artificial respiration. If breathing is difficult give oxygen. Call a physician. Ingestion: Do NOT induce vomiting. Call a physician immediately. Note to Physicians: Because rapid absorption may occur through lungs if aspirated and cause systemic effects, the decision of whether to induce vomiting or not should be made by a physician. If lavage is performed, suggest endotracheal and/or esophageal control. If burn is present, treat as any thermal burn, after decontamination. Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. No specific antidote. Section 5: Fire-Fighting Measures Flammable Properties: This product is nonflammable in accordance with aerosol flammability definitions. (See 16 CFR 1500.3(c)(6) ) Flash Point: None (TCC) Upper Explosive Limit: None Autoignition Temperature: None Lower Explosive Limit: None Fire and Explosion Data: Suitable Extinguishing Media: This material does not burn. Use extinguishing agent suitable for surrounding fire. Products of Combustion: Hydrogen chloride. Trace amounts of phosgene and chlorine. Explosion Hazards: Aerosol containers, when exposed to heat from fire, may build pressure and explode. Protection of Fire-Fighters: Firefighters should wear self-contained, NIOSH-approved breathing apparatus for protection against suffocation and possible toxic decomposition products. Proper eye and skin protection should be provided. Use water spray to keep fire-exposed containers cool and to knock down vapors which may result from product decomposition. Section 6: Accidental Release Measures Personal Precautions: Use personal protection recommended in Section 8. Do not breathe vapors. Environmental Precautions: Take precautions to prevent contamination of ground and surface waters. Do not flush into sewers or storm drains. Methods for Containment & Clean-up: Dike area to contain spill. Ventilate the area with fresh air. If in confined space or limited air circulation area, clean-up workers should wear appropriate Page 524 of 1235 Page 524 of 1235 Page 524 of 1235 Page 524 of 1235 ---PAGE BREAK--- Product Name: Lectra Motive® Electric Parts Cleaner (aerosol) Product Number 05018 Page 3 of 7 respiratory protection. Recover or absorb spilled material using an absorbent designed for chemical spills. Place used absorbents into proper waste containers. Section 7: Handling and Storage Handling Procedures: Vapors of this product are heavier than air and will collect in low areas. Make sure ventilation removes vapors from low areas. Do not eat, drink or smoke while using this product. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. For product use instructions, please see the product label. Storage Procedures: Store in a cool dry area out of direct sunlight. Aerosol cans must be maintained below 120°F / 49°C to prevent cans from rupturing. Aerosol Storage Level: I Section 8: Exposure Controls/Personal Protection Exposure Guidelines: OSHA ACGIH OTHER COMPONENT TWA STEL TWA STEL TWA SOURCE UNIT Tetrachloroethylene 100 N.E. 25 100 N.E. ppm Carbon dioxide 5000 30000 v 5000 30,000 N.E. ppm N.E. – Not Established – ceiling – skin – vacated Controls and Protection: Engineering Controls: Area should have ventilation to provide fresh air. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at the source, preventing dispersion into the general work area. Use mechanical means if necessary to maintain vapor levels below the exposure guidelines. If working in a confined space, follow applicable OSHA regulations. Respiratory Protection: None required for normal work where adequate ventilation is provided. If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with organic vapor cartridge. Air monitoring is needed to determine actual employee exposure levels. Use a self-contained breathing apparatus in confined spaces and for emergencies. Eye/face Protection: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear splash-proof goggles. Skin Protection: Use protective gloves such as PVA, Teflon, or Viton. Also, use full protective clothing if there is prolonged or repeated contact of liquid with skin. Section 9: Physical and Chemical Properties Physical State: liquid Color: colorless Odor: irritating odor Odor Threshold: 50 ppm Specific Gravity: 1.619 Page 525 of 1235 Page 525 of 1235 Page 525 of 1235 Page 525 of 1235 ---PAGE BREAK--- Product Name: Lectra Motive® Electric Parts Cleaner (aerosol) Product Number 05018 Page 4 of 7 Initial Boiling Point: 250°F / 121°C Freezing Point: ND Vapor Pressure: 13 mmHg @ 68°F / 20°C Vapor Density: 5.76 (air = 1) Evaporation Rate: very fast Solubility: 0.015 g / 100 g @ 77°F / 25°C in water Coefficient of water/oil distribution (log Pow): 2.88 pH: NA Volatile Organic Compounds: wt 0 g/L: 0 lbs./gal: 0 Section 10: Stability and Reactivity Stability: Stable Conditions to Avoid: Avoid direct sunlight or ultraviolet sources. Avoid open flames, welding arcs, and other high temperature sources which induce thermal decomposition. Incompatible Materials: Avoid contact with metals such as: aluminum powders, magnesium powders, potassium, sodium, and zinc powder. Avoid unintended contact with amines. Avoid contact with strong bases and strong oxidizers. Hazardous Decomposition Products: Hydrogen chloride, trace amounts of chlorine and phosgene Possibility of Hazardous Reactions: No Section 11: Toxicological Information Long-term toxicological studies have not been conducted for this product. The following information is available for components of this product. Acute Toxicity: Component Oral LD50 (rat) Dermal LD50 (rabbit) Inhalation LC50 (rat) Tetrachloroethylene 2629 mg/kg 3228 mg/kg 5200 mg/kg/4H Carbon dioxide No data No data 470,000 ppm/30M Chronic Toxicity: Component OSHA Carcinogen IARC Carcinogen NTP Carcinogen Irritant Sensitizer Tetrachloroethylene No Group 2A Reasonably Anticipated to be a Carcinogen Skin No Carbon dioxide No No No No No Reproductive Toxicity: No information available Teratogenicity: No information available Mutagenicity: Tetrachloroethylene: In vitro studies were negative Animal studies were negative Synergistic Effects: No information available Section 12: Ecological Information Ecological studies have not been conducted for this product. The following information is available for components of this product. Page 526 of 1235 Page 526 of 1235 Page 526 of 1235 Page 526 of 1235 ---PAGE BREAK--- Product Name: Lectra Motive® Electric Parts Cleaner (aerosol) Product Number 05018 Page 5 of 7 Ecotoxicity: Tetrachloroethylene 96 Hr LC50 Rainbow Trout: 5.28 mg/L (static) 96 Hr LC50 Fathead minnow: 13.4 mg/L (flow-through) Persistence / Degradability: Biodegradation under aerobic conditions is below detectable limits. Biodegradation may occur under anaerobic conditions. Biodegradation rate may increase in soil and/or water with acclimation. Bioaccumulation / Accumulation: Bioconcentration potential is low (BCF less than 100). Mobility in Environment: Potential for mobility in soil is medium. Section 13: Disposal Considerations Waste Classification: The dispensed liquid product is a RCRA hazardous waste for toxicity with the following potential waste codes: U210, F001, F002, D039. (See 40 CFR Part 261.20 – 261.33) Empty aerosol containers may be recycled. Any liquid product should be managed as a hazardous waste. All disposal activities must comply with federal, state, provincial and local regulations. Local regulations may be more stringent than state, provincial or national requirements. Section 14: Transport Information US DOT (ground): UN1950, Aerosols, non-flammable, 2.2 Limited Quantity** ICAO/IATA (air): UN1950, Aerosols, non-flammable, containing substances in Division 6.1, Packing Group III, 2.2 Limited Quantity IMO/IMDG (water): UN1950, Aerosols, 2.2 (6.1) Special Provisions: Marine Pollutant **This product can be classified and labeled as ‘Consumer Commodity, ORM-D’ for domestic ground shipping until January 1, 2014. If shipping as limited quantity by ground, note that shipping papers are not required. Section 15: Regulatory Information U.S. Federal Regulations: Toxic Substances Control Act (TSCA): All ingredients are either listed on the TSCA inventory or are exempt. Comprehensive Environmental Response, Compensation and Liability Act (CERCLA): Reportable Quantities (RQ’s) exist for the following ingredients: Tetrachloroethylene (100 lbs) Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center ([PHONE REDACTED]) and to your Local Emergency Planning Committee. Superfund Amendments Reauthorization Act (SARA) Title III: Section 302 Extremely Hazardous Substances (EHS): None Section 311/312 Hazard Categories: Fire Hazard No Reactive Hazard No Release of Pressure Yes Acute Health Hazard Yes Chronic Health Hazard Yes Page 527 of 1235 Page 527 of 1235 Page 527 of 1235 Page 527 of 1235 ---PAGE BREAK--- Product Name: Lectra Motive® Electric Parts Cleaner (aerosol) Product Number 05018 Page 6 of 7 Section 313 Toxic Chemicals: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: tetrachloroethylene (98%) Clean Air Act: Section 112 Hazardous Air Pollutants (HAPs): tetrachloroethylene Occupational Safety and Health Administration: This product is regulated by the Hazard Communications Standard. U.S. State Regulations: California Safe Drinking Water and Toxic Enforcement Act (Prop 65): This product may contain the following chemicals known to the state of California to cause cancer, birth defects or other reproductive harm: tetrachloroethylene Consumer Products VOC Regulations: For users in California, Connecticut, Delaware, District of Columbia, Illinois, Indiana, Maine, Maryland, Massachusetts, Michigan, New Jersey, New York, Ohio, Rhode Island and Virginia, this product is an Energized Electrical Cleaner. Energized equipment use only. Not to be used for motorized vehicle maintenance or their parts. State Right to Know: New Jersey: 127-18-4, 124-38-9 127-18-4, 124-38-9 Massachusetts: 127-18-4, 124-38-9 Rhode Island : 127-18-4, 124-38-9 Canadian Regulations: Controlled Products Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. WHMIS Hazard Class: A, D1B, D2A, D2B Canadian DSL Inventory: All ingredients are either listed on the DSL Inventory or are exempt. European Union Regulations: RoHS Compliance: This product is compliant with Directive 2002/95/EC of the European Parliament and of the Council of 27 January 2003. This product does not contain any of the restricted substances as listed in Article 4(1) of the RoHS Directive. Additional Regulatory Information: None Page 528 of 1235 Page 528 of 1235 Page 528 of 1235 Page 528 of 1235 ---PAGE BREAK--- Product Name: Lectra Motive® Electric Parts Cleaner (aerosol) Product Number 05018 Page 7 of 7 Section 16: Other Information HMIS® (II) Health: 2 Flammability: 0 Reactivity: 0 PPE: B Ratings range from 0 (no hazard) to 4 (severe hazard) NFPA Prepared By: Michelle Rudnick CRC 491G Revision Date: 07/24/2012 Changes since last revision: Section 14: transport information Section 15: Consumer Products VOC Regulations The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this MSDS consult your supervisor, a health & safety professional, or CRC Industries. ACGIH: American Conference of Governmental Industrial Hygienists CAS: Chemical Abstract Service CFR: Code of Federal Regulations DOT: Department of Transportation DSL: Domestic Substance List g/L: grams per Liter HMIS: Hazardous Materials Identification System IARC: International Agency for Research on Cancer IATA: International Air Transport Association ICAO: International Civil Aviation Organization IMDG: International Maritime Dangerous Goods IMO: International Maritime Organization lbs./gal: pounds per gallon LC: Lethal Concentration LD: Lethal Dose NA: Not Applicable ND: Not Determined NIOSH: National Institute of Occupational Safety & Health NFPA: National Fire Protection Association NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration PMCC: Pensky-Martens Closed Cup PPE: Personal Protection Equipment ppm: Parts per Million RoHS: Restriction of Hazardous Substances STEL: Short Term Exposure Limit TCC: Tag Closed Cup TWA: Time Weighted Average WHMIS: Workplace Hazardous Materials Information System 0 0 2 Page 529 of 1235 Page 529 of 1235 Page 529 of 1235 Page 529 of 1235 ---PAGE BREAK--- Page 1 of 7 Section 1: Product & Company Identification Product Name: Lectra Motive® Electric Parts Cleaner (aerosol) Product Number 05018 Product Use: Energized Electrical Cleaner Manufacturer / Supplier Contact Information: In United States: In Canada: In Mexico: CRC Industries, Inc. CRC Canada Co. CRC Industries Mexico 885 Louis Drive 2-1246 Lorimar Drive Av. Benito Juárez 4055 G Warminster, PA 18974 Mississauga, Ontario L5S 1R2 Colonia Orquídea www.crcindustries.com www.crc-canada.ca San Luís Potosí, SLP CP 78394 1-[PHONE REDACTED] (General) 1-[PHONE REDACTED] www.crc-mexico.com (800) 521-3168 (Technical) 52-[PHONE REDACTED] (800) 272-4620 (Customer Service) 24-Hr Emergency – CHEMTREC: (800) 424-9300 or (703) 527-3887 Section 2: Hazards Identification Emergency Overview DANGER: Vapor Harmful. Contents Under Pressure. As defined by OSHA’s Hazard Communication Standard, this product is hazardous. Appearance & Odor: Colorless liquid, irritating odor at high concentrations Potential Health Effects: ACUTE EFFECTS: EYE: May cause slight temporary eye irritation. Vapors may irritate the eyes at concentrations of 100 ppm. SKIN: Short single exposures may cause skin irritation. Prolonged exposure may cause severe skin irritation, even a burn. A single prolonged exposure is not likely to result in the material being absorbed through skin in harmful amounts. INHALATION: Dizziness may occur at concentrations of 200 ppm. Progressively higher levels may also cause nasal irritation, nausea, incoordination, and drunkenness. Very high levels or prolonged exposure could lead to unconsciousness and death. INGESTION: Single dose oral toxicity is considered to be extremely low. Swallowing large amounts may cause injury if aspirated into the lungs. This may be rapidly absorbed through the lungs and result in injury to other body systems. CHRONIC EFFECTS: Repeated contact with skin may cause drying or flaking of skin. Excessive or long term exposure to vapors may increase sensitivity to epinephrine and increase myocardial irritability. TARGET ORGANS: Central nervous system. Possibly liver and kidney. Medical Conditions Aggravated by Exposure: None known. See Section 11 for toxicology and carcinogenicity information on product ingredients. Page 530 of 1235 Page 530 of 1235 Page 530 of 1235 Page 530 of 1235 ---PAGE BREAK--- Product Name: Lectra Motive® Electric Parts Cleaner (aerosol) Product Number 05018 Page 2 of 7 Section 3: Composition/Information on Ingredients COMPONENT CAS NUMBER % by Wt. Tetrachloroethylene (PERC) 127-18-4 > 95 Carbon Dioxide 124-38-9 < 5 Section 4: First Aid Measures Eye Contact: Immediately flush with plenty of water for 15 minutes. Call a physician if irritation persists. Skin Contact: Remove contaminated clothing and wash affected area with soap and water. Call a physician if irritation persists. Wash contaminated clothing prior to re-use. Inhalation: Remove person to fresh air. Keep person calm. If not breathing, give artificial respiration. If breathing is difficult give oxygen. Call a physician. Ingestion: Do NOT induce vomiting. Call a physician immediately. Note to Physicians: Because rapid absorption may occur through lungs if aspirated and cause systemic effects, the decision of whether to induce vomiting or not should be made by a physician. If lavage is performed, suggest endotracheal and/or esophageal control. If burn is present, treat as any thermal burn, after decontamination. Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. No specific antidote. Section 5: Fire-Fighting Measures Flammable Properties: This product is nonflammable in accordance with aerosol flammability definitions. (See 16 CFR 1500.3(c)(6) ) Flash Point: None (TCC) Upper Explosive Limit: None Autoignition Temperature: None Lower Explosive Limit: None Fire and Explosion Data: Suitable Extinguishing Media: This material does not burn. Use extinguishing agent suitable for surrounding fire. Products of Combustion: Hydrogen chloride, trace amounts of phosgene and chlorine Explosion Hazards: Aerosol containers, when exposed to heat from fire, may build pressure and explode. Protection of Fire-Fighters: Firefighters should wear self-contained, NIOSH-approved breathing apparatus for protection against suffocation and possible toxic decomposition products. Proper eye and skin protection should be provided. Use water spray to keep fire-exposed containers cool and to knock down vapors which may result from product decomposition. Section 6: Accidental Release Measures Personal Precautions: Use personal protection recommended in Section 8. Do not breathe vapors. Environmental Precautions: Take precautions to prevent contamination of ground and surface waters. Do not flush into sewers or storm drains. Methods for Containment & Clean-up: Dike area to contain spill. Ventilate the area with fresh air. If in confined space or limited air circulation area, clean-up workers should wear appropriate Page 531 of 1235 Page 531 of 1235 Page 531 of 1235 Page 531 of 1235 ---PAGE BREAK--- Product Name: Lectra Motive® Electric Parts Cleaner (aerosol) Product Number 05018 Page 3 of 7 respiratory protection. Recover or absorb spilled material using an absorbent designed for chemical spills. Place used absorbents into proper waste containers. Section 7: Handling and Storage Handling Procedures: Vapors of this product are heavier than air and will collect in low areas. Make sure ventilation removes vapors from low areas. Do not eat, drink or smoke while using this product. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. For product use instructions, please see the product label. Storage Procedures: Store in a cool dry area out of direct sunlight. Aerosol cans must be maintained below 120 F to prevent cans from rupturing. Aerosol Storage Level: I Section 8: Exposure Controls/Personal Protection Exposure Guidelines: OSHA ACGIH OTHER COMPONENT TWA STEL TWA STEL TWA SOURCE UNIT Tetrachloroethylene 100 N.E. 25 100 N.E. ppm Carbon dioxide 5000 30000 v 5000 30,000 N.E. ppm N.E. – Not Established – ceiling – skin – vacated Controls and Protection: Engineering Controls: Area should have ventilation to provide fresh air. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at the source, preventing dispersion into the general work area. Use mechanical means if necessary to maintain vapor levels below the exposure guidelines. If working in a confined space, follow applicable OSHA regulations. Respiratory Protection: None required for normal work where adequate ventilation is provided. If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with organic vapor cartridge. Air monitoring is needed to determine actual employee exposure levels. Use a self-contained breathing apparatus in confined spaces and for emergencies. Eye/face Protection: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear splash-proof goggles. Skin Protection: Use protective gloves such as PVA, Teflon, or Viton. Also, use full protective clothing if there is prolonged or repeated contact of liquid with skin. Section 9: Physical and Chemical Properties Physical State: liquid Color: colorless Odor: irritating odor Odor Threshold: 50 ppm Specific Gravity: 1.619 Initial Boiling Point: 250°F / 121°C Page 532 of 1235 Page 532 of 1235 Page 532 of 1235 Page 532 of 1235 ---PAGE BREAK--- Product Name: Lectra Motive® Electric Parts Cleaner (aerosol) Product Number 05018 Page 4 of 7 Freezing Point: ND Vapor Pressure: 13 mmHg @ 68°F / 20°C Vapor Density: 5.76 (air = 1) Evaporation Rate: very fast Solubility: 0.015 g/ 100 g @ 77 F in water Coefficient of water/oil distribution (log Pow): 2.88 pH: NA Volatile Organic Compounds: wt 0 g/L: 0 lbs./gal: 0 Section 10: Stability and Reactivity Stability: Stable Conditions to Avoid: Avoid direct sunlight or ultraviolet sources. Avoid open flames, welding arcs, and other high temperature sources which induce thermal decomposition. Incompatible Materials: Avoid contact with metals such as: aluminum powders, magnesium powders, potassium, sodium, and zinc powder. Avoid unintended contact with amines. Avoid contact with strong bases and strong oxidizers. Hazardous Decomposition Products: Hydrogen chloride, trace amounts of chlorine and phosgene Possibility of Hazardous Reactions: No Section 11: Toxicological Information Long-term toxicological studies have not been conducted for this product. The following information is available for components of this product. Acute Toxicity: Component Oral LD50 (rat) Dermal LD50 (rabbit) Inhalation LC50 (rat) Tetrachloroethylene 2629 mg/kg > 10 g/kg 5200 mg/kg/4H Carbon dioxide No data No data 470,000 ppm/30M Chronic Toxicity: Component OSHA Carcinogen IARC Carcinogen NTP Carcinogen Irritant Sensitizer Tetrachloroethylene No Group 2A Reasonably Anticipated to be a Carcinogen E (mild) / S (severe) No Carbon dioxide No No No None No Reproductive Toxicity: No information available Teratogenicity: No information available Mutagenicity: Tetrachloroethylene: in vitro studies were negative animal studies were negative Synergistic Effects: No information available Section 12: Ecological Information Ecological studies have not been conducted for this product. The following information is available for components of this product. Ecotoxicity: Tetrachloroethylene 96 Hr LC50 Rainbow Trout: 5.28 mg/L (static) E – Eye S – Skin R - Respiratory Page 533 of 1235 Page 533 of 1235 Page 533 of 1235 Page 533 of 1235 ---PAGE BREAK--- Product Name: Lectra Motive® Electric Parts Cleaner (aerosol) Product Number 05018 Page 5 of 7 96 Hr LC50 Fathead minnow: 13.4 mg/L (flow-through) Persistence / Degradability: Biodegradation under aerobic conditions is below detectable limits. Biodegradation may occur under anaerobic conditions. Biodegradation rate may increase in soil and/or water with acclimation. Bioaccumulation / Accumulation: Bioconcentration potential is low (BCF less than 100). Mobility in Environment: Potential for mobility in soil is medium. Section 13: Disposal Considerations Waste Classification: The dispensed liquid product is a RCRA hazardous waste for toxicity with the following potential waste codes: U210, F001, F002, D039. (See 40 CFR Part 261.20 – 261.33) Empty aerosol containers may be recycled. Any liquid product should be managed as a hazardous waste. All disposal activities must comply with federal, state, provincial and local regulations. Local regulations may be more stringent than state, provincial or national requirements. Section 14: Transport Information US DOT (ground): Consumer Commodity, ORM-D ICAO/IATA (air): Aerosols, non-flammable, containing substances in Division 6.1, Packing Group III, UN1950, 2.2 (6.1) IMO/IMDG (water): Aerosols, UN1950, 2.2 Limited Quantity Special Provisions: Marine Pollutant Section 15: Regulatory Information U.S. Federal Regulations: Toxic Substances Control Act (TSCA): All ingredients are either listed on the TSCA inventory or are exempt. Comprehensive Environmental Response, Compensation and Liability Act (CERCLA): Reportable Quantities (RQ’s) exist for the following ingredients: Tetrachloroethylene (100 lbs) Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center ([PHONE REDACTED]) and to your Local Emergency Planning Committee. Superfund Amendments Reauthorization Act (SARA) Title III: Section 302 Extremely Hazardous Substances (EHS): None Section 311/312 Hazard Categories: Fire Hazard No Reactive Hazard No Release of Pressure Yes Acute Health Hazard Yes Chronic Health Hazard Yes Section 313 Toxic Chemicals: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: Tetrachloroethylene (97.7%) Page 534 of 1235 Page 534 of 1235 Page 534 of 1235 Page 534 of 1235 ---PAGE BREAK--- Product Name: Lectra Motive® Electric Parts Cleaner (aerosol) Product Number 05018 Page 6 of 7 Clean Air Act: Section 112 Hazardous Air Pollutants (HAPs): Tetrachloroethylene U.S. State Regulations: California Safe Drinking Water and Toxic Enforcement Act (Prop 65): This product may contain the following chemicals known to the state of California to cause cancer, birth defects or other reproductive harm: Tetrachloroethylene Consumer Products VOC Regulations: For users in California, Connecticut, Delaware, Indiana, Maine, Maryland, Massachusetts, Michigan, New Jersey, New York, Ohio, Rhode Island, and Virginia, this product is an Energized Electrical Cleaner. Energized equipment use only. Not to be used for motorized vehicle maintenance or their parts. State Right to Know: New Jersey: 127-18-4, 124-38-9 127-18-4, 124-38-9 Massachusetts: 127-18-4, 124-38-9 Rhode Island : 127-18-4, 124-38-9 Canadian Regulations: Controlled Products Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. WHMIS Hazard Class: A, D1B, D2A, D2B Canadian DSL Inventory: All ingredients are either listed on the DSL Inventory or are exempt. European Union Regulations: RoHS Compliance: This product is compliant with Directive 2002/95/EC of the European Parliament and of the Council of 27 January 2003. This product does not contain any of the restricted substances as listed in Article 4(1) of the RoHS Directive. Additional Regulatory Information: None Section 16: Other Information HMIS® (II) Health: 2 Flammability: 0 Reactivity: 0 PPE: B Ratings range from 0 (no hazard) to 4 (severe hazard) NFPA Prepared By: Michelle Rudnick CRC 491G Revision Date: 08/25/2011 0 0 2 Page 535 of 1235 Page 535 of 1235 Page 535 of 1235 Page 535 of 1235 ---PAGE BREAK--- Product Name: Lectra Motive® Electric Parts Cleaner (aerosol) Product Number 05018 Page 7 of 7 Changes since last revision: Section 14: Transport Information The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this MSDS consult your supervisor, a health & safety professional, or CRC Industries. ACGIH: American Conference of Governmental Industrial Hygienists CAS: Chemical Abstract Service CFR: Code of Federal Regulations DOT: Department of Transportation DSL: Domestic Substance List g/L: grams per Liter HMIS: Hazardous Materials Identification System IARC: International Agency for Research on Cancer IATA: International Air Transport Association ICAO: International Civil Aviation Organization IMDG: International Maritime Dangerous Goods IMO: International Maritime Organization lbs./gal: pounds per gallon LC: Lethal Concentration LD: Lethal Dose NA: Not Applicable ND: Not Determined NIOSH: National Institute of Occupational Safety & Health NFPA: National Fire Protection Association NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration PMCC: Pensky-Martens Closed Cup PPE: Personal Protection Equipment ppm: Parts per Million RoHS: Restriction of Hazardous Substances STEL: Short Term Exposure Limit TCC: Tag Closed Cup TWA: Time Weighted Average WHMIS: Workplace Hazardous Materials Information System Page 536 of 1235 Page 536 of 1235 Page 536 of 1235 Page 536 of 1235 ---PAGE BREAK--- Material Safety Data Sheet Page 1 of 7 Section 1: Product & Company Identification Product Name: Lectra Motive® Electric Parts Cleaner (aerosol) Product Number 05018 Product Use: Energized Electrical Cleaner Manufacturer / Supplier Contact Information: In United States: In Canada: In Mexico: CRC Industries, Inc. CRC Canada Co. CRC Industries Mexico 885 Louis Drive 2-1246 Lorimar Drive Av. Benito Juárez 4055 G Warminster, PA 18974 Mississauga, Ontario L5S 1R2 Colonia Orquídea www.crcindustries.com www.crc-canada.ca San Luís Potosí, SLP CP 78394 1-[PHONE REDACTED] (General) 1-[PHONE REDACTED] www.crc-mexico.com (800) 521-3168 (Technical) 52-[PHONE REDACTED] (800) 272-4620 (Customer Service) 24-Hr Emergency – CHEMTREC: (800) 424-9300 or (703) 527-3887 Section 2: Hazards Identification Emergency Overview DANGER: Vapor Harmful. Contents Under Pressure. As defined by OSHA’s Hazard Communication Standard, this product is hazardous. Appearance & Odor: Colorless liquid, irritating odor at high concentrations Potential Health Effects: ACUTE EFFECTS: EYE: May cause slight temporary eye irritation. Vapors may irritate the eyes at concentrations of 100 ppm. SKIN: Short single exposures may cause skin irritation. Prolonged exposure may cause severe skin irritation, even a burn. A single prolonged exposure is not likely to result in the material being absorbed through skin in harmful amounts. INHALATION: Dizziness may occur at concentrations of 200 ppm. Progressively higher levels may also cause nasal irritation, nausea, incoordination, and drunkenness. Very high levels or prolonged exposure could lead to unconsciousness and death. INGESTION: Single dose oral toxicity is considered to be extremely low. Swallowing large amounts may cause injury if aspirated into the lungs. This may be rapidly absorbed through the lungs and result in injury to other body systems. CHRONIC EFFECTS: Repeated contact with skin may cause drying or flaking of skin. Excessive or long term exposure to vapors may increase sensitivity to epinephrine and increase myocardial irritability. TARGET ORGANS: Central nervous system. Possibly liver and kidney. Medical Conditions Aggravated by Exposure: None known. See Section 11 for toxicology and carcinogenicity information on product ingredients. Page 537 of 1235 Page 537 of 1235 Page 537 of 1235 Page 537 of 1235 ---PAGE BREAK--- Product Name: Lectra Motive® Electric Parts Cleaner (aerosol) Product Number 05018 Page 2 of 7 Section 3: Composition/Information on Ingredients COMPONENT CAS NUMBER % by Wt. Tetrachloroethylene (PERC) 127-18-4 > 95 Carbon Dioxide 124-38-9 < 5 Section 4: First Aid Measures Eye Contact: Immediately flush with plenty of water for 15 minutes. Call a physician if irritation persists. Skin Contact: Remove contaminated clothing and wash affected area with soap and water. Call a physician if irritation persists. Wash contaminated clothing prior to re-use. Inhalation: Remove person to fresh air. Keep person calm. If not breathing, give artificial respiration. If breathing is difficult give oxygen. Call a physician. Ingestion: Do NOT induce vomiting. Call a physician immediately. Note to Physicians: Because rapid absorption may occur through lungs if aspirated and cause systemic effects, the decision of whether to induce vomiting or not should be made by a physician. If lavage is performed, suggest endotracheal and/or esophageal control. If burn is present, treat as any thermal burn, after decontamination. Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. No specific antidote. Section 5: Fire-Fighting Measures Flammable Properties: This product is nonflammable in accordance with aerosol flammability definitions. (See 16 CFR 1500.3(c)(6) ) Flash Point: None (TCC) Upper Explosive Limit: None Autoignition Temperature: None Lower Explosive Limit: None Fire and Explosion Data: Suitable Extinguishing Media: This material does not burn. Use extinguishing agent suitable for surrounding fire. Products of Combustion: Hydrogen chloride, trace amounts of phosgene and chlorine Explosion Hazards: Aerosol containers, when exposed to heat from fire, may build pressure and explode. Protection of Fire-Fighters: Firefighters should wear self-contained, NIOSH-approved breathing apparatus for protection against suffocation and possible toxic decomposition products. Proper eye and skin protection should be provided. Use water spray to keep fire-exposed containers cool and to knock down vapors which may result from product decomposition. Section 6: Accidental Release Measures Personal Precautions: Use personal protection recommended in Section 8. Do not breathe vapors. Environmental Precautions: Take precautions to prevent contamination of ground and surface waters. Do not flush into sewers or storm drains. Methods for Containment & Clean-up: Dike area to contain spill. Ventilate the area with fresh air. If in confined space or limited air circulation area, clean-up workers should wear appropriate Page 538 of 1235 Page 538 of 1235 Page 538 of 1235 Page 538 of 1235 ---PAGE BREAK--- Product Name: Lectra Motive® Electric Parts Cleaner (aerosol) Product Number 05018 Page 3 of 7 respiratory protection. Recover or absorb spilled material using an absorbent designed for chemical spills. Place used absorbents into proper waste containers. Section 7: Handling and Storage Handling Procedures: Vapors of this product are heavier than air and will collect in low areas. Make sure ventilation removes vapors from low areas. Do not eat, drink or smoke while using this product. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. For product use instructions, please see the product label. Storage Procedures: Store in a cool dry area out of direct sunlight. Aerosol cans must be maintained below 120 F to prevent cans from rupturing. Aerosol Storage Level: I Section 8: Exposure Controls/Personal Protection Exposure Guidelines: OSHA ACGIH OTHER COMPONENT TWA STEL TWA STEL TWA SOURCE UNIT Tetrachloroethylene 100 N.E. 25 100 N.E. ppm Carbon dioxide 5000 30000 v 5000 30,000 N.E. ppm N.E. – Not Established – ceiling – skin – vacated Controls and Protection: Engineering Controls: Area should have ventilation to provide fresh air. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at the source, preventing dispersion into the general work area. Use mechanical means if necessary to maintain vapor levels below the exposure guidelines. If working in a confined space, follow applicable OSHA regulations. Respiratory Protection: None required for normal work where adequate ventilation is provided. If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with organic vapor cartridge. Air monitoring is needed to determine actual employee exposure levels. Use a self-contained breathing apparatus in confined spaces and for emergencies. Eye/face Protection: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear splash-proof goggles. Skin Protection: Use protective gloves such as PVA, Teflon, or Viton. Also, use full protective clothing if there is prolonged or repeated contact of liquid with skin. Section 9: Physical and Chemical Properties Physical State: liquid Color: colorless Odor: irritating odor Odor Threshold: 50 ppm Specific Gravity: 1.619 Page 539 of 1235 Page 539 of 1235 Page 539 of 1235 Page 539 of 1235 ---PAGE BREAK--- Product Name: Lectra Motive® Electric Parts Cleaner (aerosol) Product Number 05018 Page 4 of 7 Initial Boiling Point: 250 F Freezing Point: ND Vapor Pressure: 13 mmHg @ 68 F Vapor Density: 5.76 (air = 1) Evaporation Rate: very fast Solubility: 0.015 g/ 100 g @ 77 F in water Coefficient of water/oil distribution (log Pow): 2.88 pH: NA Volatile Organic Compounds: wt 0 g/L: 0 lbs./gal: 0 Section 10: Stability and Reactivity Stability: Stable Conditions to Avoid: Avoid direct sunlight or ultraviolet sources. Avoid open flames, welding arcs, and other high temperature sources which induce thermal decomposition. Incompatible Materials: Avoid contact with metals such as: aluminum powders, magnesium powders, potassium, sodium, and zinc powder. Avoid unintended contact with amines. Avoid contact with strong bases and strong oxidizers. Hazardous Decomposition Products: Hydrogen chloride, trace amounts of chlorine and phosgene Possibility of Hazardous Reactions: No Section 11: Toxicological Information Long-term toxicological studies have not been conducted for this product. The following information is available for components of this product. Acute Toxicity: Component Oral LD50 (rat) Dermal LD50 (rabbit) Inhalation LC50 (rat) Tetrachloroethylene 2629 mg/kg > 10 g/kg 5200 mg/kg/4H Carbon dioxide No data No data 470,000 ppm/30M Chronic Toxicity: Component OSHA Carcinogen IARC Carcinogen NTP Carcinogen Irritant Sensitizer Tetrachloroethylene No Group 2A Reasonably Anticipated to be a Carcinogen E (mild) / S (severe) No Carbon dioxide No No No None No Reproductive Toxicity: No information available Teratogenicity: No information available Mutagenicity: Tetrachloroethylene: in vitro studies were negative animal studies were negative Synergistic Effects: No information available Section 12: Ecological Information Ecological studies have not been conducted for this product. The following information is available for components of this product. E – Eye S – Skin R - Respiratory Page 540 of 1235 Page 540 of 1235 Page 540 of 1235 Page 540 of 1235 ---PAGE BREAK--- Product Name: Lectra Motive® Electric Parts Cleaner (aerosol) Product Number 05018 Page 5 of 7 Ecotoxicity: Tetrachloroethylene 96 Hr LC50 Rainbow Trout: 5.28 mg/L (static) 96 Hr LC50 Fathead minnow: 13.4 mg/L (flow-through) Persistence / Degradability: Biodegradation under aerobic conditions is below detectable limits. Biodegradation may occur under anaerobic conditions. Biodegradation rate may increase in soil and/or water with acclimation. Bioaccumulation / Accumulation: Bioconcentration potential is low (BCF less than 100). Mobility in Environment: Potential for mobility in soil is medium. Section 13: Disposal Considerations Waste Classification: The dispensed liquid product is a RCRA hazardous waste for toxicity with the following potential waste codes: U210, F001, F002, D039. Pressurized containers are a D003 reactive waste. (See 40 CFR Part 261.20 – 261.33) Empty aerosol containers may be recycled. Any liquid product should be managed as a hazardous waste. All disposal activities must comply with federal, state, provincial and local regulations. Local regulations may be more stringent than state, provincial or national requirements. Section 14: Transport Information US DOT (ground): Consumer Commodity, ORM-D ICAO/IATA (air): Aerosols, non-flammable, UN1950, 2.2 PGIII IMO/IMDG (water): Aerosols, UN1950, 2.2, Limited Quantity Special Provisions: None Section 15: Regulatory Information U.S. Federal Regulations: Toxic Substances Control Act (TSCA): All ingredients are either listed on the TSCA inventory or are exempt. Comprehensive Environmental Response, Compensation and Liability Act (CERCLA): Reportable Quantities (RQ’s) exist for the following ingredients: Tetrachloroethylene (100 lbs) Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center ([PHONE REDACTED]) and to your Local Emergency Planning Committee. Superfund Amendments Reauthorization Act (SARA) Title III: Section 302 Extremely Hazardous Substances (EHS): None Section 311/312 Hazard Categories: Fire Hazard No Reactive Hazard No Release of Pressure Yes Acute Health Hazard Yes Chronic Health Hazard Yes Section 313 Toxic Chemicals: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: Page 541 of 1235 Page 541 of 1235 Page 541 of 1235 Page 541 of 1235 ---PAGE BREAK--- Product Name: Lectra Motive® Electric Parts Cleaner (aerosol) Product Number 05018 Page 6 of 7 Tetrachloroethylene (97.7%) Clean Air Act: Section 112 Hazardous Air Pollutants (HAPs): Tetrachloroethylene U.S. State Regulations: California Safe Drinking Water and Toxic Enforcement Act (Prop 65): This product may contain the following chemicals known to the state of California to cause cancer, birth defects or other reproductive harm: Tetrachloroethylene Consumer Products VOC Regulations: For users in California, Connecticut, Delaware, Maine, Maryland, Massachusetts, Michigan, New Jersey, New York, Ohio, and Rhode Island, this product is an Energized Electrical Cleaner. Energized equipment use only. Not to be used for motorized vehicle maintenance or their parts. State Right to Know: New Jersey: 127-18-4, 124-38-9 127-18-4, 124-38-9 Massachusetts: 127-18-4, 124-38-9 Rhode Island : 127-18-4, 124-38-9 Canadian Regulations: Canadian DSL Inventory: All ingredients are either listed on the DSL Inventory or are exempt. WHMIS Hazard Class: A, D1B, D2A, D2B European Union Regulations: RoHS Compliance: This product is compliant with Directive 2002/95/EC of the European Parliament and of the Council of 27 January 2003. This product does not contain any of the restricted substances as listed in Article 4(1) of the RoHS Directive. Additional Regulatory Information: None Section 16: Other Information HMIS® (II) Health: 2 Flammability: 0 Reactivity: 0 PPE: B Ratings range from 0 (no hazard) to 4 (severe hazard) NFPA Prepared By: Michelle Rudnick CRC 491G Revision Date: 05/17/2010 Changes since last revision: Section 15: Consumer Products VOC Regulations revised 0 0 2 Page 542 of 1235 Page 542 of 1235 Page 542 of 1235 Page 542 of 1235 ---PAGE BREAK--- Product Name: Lectra Motive® Electric Parts Cleaner (aerosol) Product Number 05018 Page 7 of 7 The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this MSDS consult your supervisor, a health & safety professional, or CRC Industries. ACGIH: American Conference of Governmental Industrial Hygienists CAS: Chemical Abstract Service CFR: Code of Federal Regulations DOT: Department of Transportation DSL: Domestic Substance List g/L: grams per Liter HMIS: Hazardous Materials Identification System IARC: International Agency for Research on Cancer IATA: International Air Transport Association ICAO: International Civil Aviation Organization IMDG: International Maritime Dangerous Goods IMO: International Maritime Organization lbs./gal: pounds per gallon LC: Lethal Concentration LD: Lethal Dose NA: Not Applicable ND: Not Determined NIOSH: National Institute of Occupational Safety & Health NFPA: National Fire Protection Association NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration PMCC: Pensky-Martens Closed Cup PPE: Personal Protection Equipment ppm: Parts per Million RoHS: Restriction of Hazardous Substances STEL: Short Term Exposure Limit TCC: Tag Closed Cup TWA: Time Weighted Average WHMIS: Workplace Hazardous Materials Information System Page 543 of 1235 Page 543 of 1235 Page 543 of 1235 Page 543 of 1235 ---PAGE BREAK--- Lloyd's Glass Cleaner & Polish Lloyd's Inc. [PHONE REDACTED] y 4437 Venture Ave [PHONE REDACTED] Duluth, MN 55811 April 26, 2004 Lloyd's Glass Cleaner & Polish Generic Description: Polymer Cleaner - Water Based. HMIS Rating: Health - 1 : Flamability - 1 : Reactivity - 0 No Hazardous Components as defined by OSHA HMIS Rating: Health 1 : Flamability 1 : Reactivity 0 Notice: No representations or warranties, either expressed or implied, or merchantability, fitness for a particular purpose, or of any nature, are made with respect to information concerning the product refered to in this MSDS refered to in this MSDS. USE only according to label directions. 212 deg F 1.00 g N/A N/A N/A N/A / Not determined Clear - Cloudy Appearance. PH: Not Applicable g y y pp No Odor N/A NON FLAMMABLE N/E N/E N/E Water spray, Carbon Dioxide, Dry Chemical, Foam Always wear full body protection gear including self- contained breathing apparatus. When heated to temperatures above boilng point 150 degrees C in the presence of air, product can form traces of formaldahyde vapors. None known Page 544 of 1235 Page 544 of 1235 Page 544 of 1235 Page 544 of 1235 ---PAGE BREAK--- Material Safety Data Sheet Revision Number: 004.0 Issue date: 02/05/2015 IDH number: 1330583 Product name: LOCTITE® 263™ THREADLOCKER Page 1 of 5 1. PRODUCT AND COMPANY IDENTIFICATION Product name: LOCTITE® 263™ THREADLOCKER IDH number: 1330583 Product use: Anaerobic Sealant Item number: 1330583 Region: Canada Company address: Contact information: Henkel Canada Corporation 2515 Meadowpine Boulevard Mississauga, Ontario L5N 6C3 Telephone: [PHONE REDACTED] MEDICAL EMERGENCY Phone: Poison Control Center 1-[PHONE REDACTED] (toll free) or 1-[PHONE REDACTED] TRANSPORT EMERGENCY Phone: CHEMTREC 1-[PHONE REDACTED] (toll free) or 1-[PHONE REDACTED] Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Physical state: Liquid WHMIS hazard class: D.2.A, D.2.B Color: Red Odor: Characteristic WARNING: CAUSES EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE RESPIRATORY TRACT IRRITATION. MAY BE HARMFUL IF SWALLOWED. Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion Potential Health Effects Inhalation: May cause respiratory tract irritation. Skin contact: May cause allergic skin reaction. Irritating to skin. Eye contact: Contact with eyes will cause irritation. Pain and discomfort. Excess tearing. Ingestion: May be harmful if swallowed. Existing conditions aggravated by exposure: Eye, skin, and respiratory disorders. See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components CAS NUMBER % Methacrylate monomer Proprietary 10 - 30 dimethacrylate 25852-47-5 10 - 30 Bisphenol A fumarate resin 39382-25-7 10 - 30 Polyurethane Methacrylate Resin Proprietary 10 - 30 dimethacrylate 109-16-0 5 - 10 Cumene hydroperoxide 80-15-9 1 - 5 114-83-0 0.1 - 1 Cumene 98-82-8 0.1 - 1 4. FIRST AID MEASURES Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention. Page 545 of 1235 Page 545 of 1235 Page 545 of 1235 Page 545 of 1235 ---PAGE BREAK--- IDH number: 1330583 Product name: LOCTITE® 263™ THREADLOCKER Page 2 of 5 Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. Wash clothing before reuse. Get medical attention. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention. 5. FIRE FIGHTING MEASURES Flash point: 100 °C (212°F) ; Estimated Autoignition temperature: Not available. Flammable/Explosive limits - lower: Not available. Flammable/Explosive limits - upper: Not available. Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide. Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. In case of fire, keep containers cool with water spray. Unusual fire or explosion hazards: Uncontrolled polymerization may occur at high temperatures resulting in explosions or rupture of storage containers. Hazardous combustion products: Oxides of carbon. Oxides of nitrogen. Thermal decomposition can lead to release of irritating gases and vapors. Sensitivity to Mechanical Impact: Not available. Sensitivity to static discharge: Not available. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Do not allow product to enter sewer or waterways. Clean-up methods: Remove all sources of ignition. Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean- up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Scrape up as much material as possible. Store in a partly filled, closed container until disposal. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up. 7. HANDLING AND STORAGE Handling: Use only with adequate ventilation. Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Keep container closed. Refer to Section 8. Storage: For safe storage, store at or below 38 °C (100.4 Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container closed until ready for use. For information on product shelf life contact Henkel Canada Customer Service at [PHONE REDACTED]. Page 546 of 1235 Page 546 of 1235 Page 546 of 1235 Page 546 of 1235 ---PAGE BREAK--- IDH number: 1330583 Product name: LOCTITE® 263™ THREADLOCKER Page 3 of 5 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER Methacrylate monomer None None None None dimethacrylate None None None None Bisphenol A fumarate resin None None None None Polyurethane Methacrylate Resin None None None None dimethacrylate None None None None Cumene hydroperoxide None None 1 ppm (6 mg/m3) TWA (SKIN) None None None None None Cumene 50 ppm TWA 50 ppm (245 mg/m3) PEL (SKIN) None None Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available. Skin protection: Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. Neoprene gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Red Odor: Characteristic Odor threshold: Not available. pH: Not available. Vapor pressure: Not available. Boiling point/range: Not available. Melting point/ range: Not available. Specific gravity: 1.08 at 20 °C (68°F) Vapor density: Not available. Flash point: 100 °C (212°F) ; Estimated Flammable/Explosive limits - lower: Not available. Flammable/Explosive limits - upper: Not available. Autoignition temperature: Not available. Evaporation rate: Not available. Solubility in water: Slight Partition coefficient (n-octanol/water): Not available. VOC content: 0.36 % Page 547 of 1235 Page 547 of 1235 Page 547 of 1235 Page 547 of 1235 ---PAGE BREAK--- IDH number: 1330583 Product name: LOCTITE® 263™ THREADLOCKER Page 4 of 5 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions of storage and use. Hazardous reactions: None under normal processing. Polymerization may occur at elevated temperature or in the presence of incompatible materials. Hazardous decomposition products: Oxides of carbon. Oxides of nitrogen. Irritating organic vapours. Incompatible materials: Strong oxidizing agents. Reducing agents. Strong acids and strong bases. Oxygen scavengers. Other polymerization initiators. Heavy metals. Conditions to avoid: Elevated temperatures. Heat, flames, sparks and other sources of ignition. Store away from incompatible materials. 11. TOXICOLOGICAL INFORMATION Toxicologically synergistic products: Not available. Refer to the following for Irritancy of Product, Sensitization to Product, Carcinogenicity, Reproductive Toxicity, Teratogenicity, and Mutagenicity. Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) ACGIH Carcinogen Methacrylate monomer No No No No dimethacrylate No No No No Bisphenol A fumarate resin No No No No Polyurethane Methacrylate Resin No No No No dimethacrylate No No No No Cumene hydroperoxide No No No No No No No No Cumene No Group 2B No No Hazardous components LD50s and LC50s Health Effects/Target Organs Methacrylate monomer None No Records dimethacrylate None Allergen, Irritant Bisphenol A fumarate resin None No Target Organs Polyurethane Methacrylate Resin None Irritant, Allergen dimethacrylate None Irritant, Allergen Cumene hydroperoxide None Allergen, Central nervous system, Corrosive, Irritant, Mutagen None Allergen, Blood, Kidney, Mutagen, Some evidence of carcinogenicity Cumene Oral LD50 (RAT) = 2.91 g/kg Oral LD50 (RAT) = 1,400 mg/kg Inhalation LC50 (RAT, 4 h) = 8000 ppm Central nervous system, Irritant, Lung 12. ECOLOGICAL INFORMATION Ecological information: Not available. Page 548 of 1235 Page 548 of 1235 Page 548 of 1235 Page 548 of 1235 ---PAGE BREAK--- IDH number: 1330583 Product name: LOCTITE® 263™ THREADLOCKER Page 5 of 5 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. 14. TRANSPORT INFORMATION The shipping classification in this section are for bulk packaging only. Shipping classification may be different for non-bulk packaging as exceptions may apply. Refer to shipping documents for package specific transportation classification. Canada Transportation of Dangerous Goods - Ground Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None International Air Transportation (ICAO/IATA) Proper shipping name: Environmentally hazardous substance, liquid, n.o.s. Hazard class or division: 9 Identification number: UN 3082 Packing group: III Water Transportation (IMO/IMDG) Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard class or division: 9 Identification number: UN 3082 Packing group: III 15. REGULATORY INFORMATION Canada Regulatory Information CEPA DSL/NDSL Status: One or more components are not listed on, and are not exempt from listing on either the Domestic Substances List or the Non-Domestic Substances List. United States Regulatory Information TSCA 8 Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet format. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR), and the MSDS contains all the information required by the CPR. Prepared by: Sheila Gines, Regulatory Affairs Specialist DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 549 of 1235 Page 549 of 1235 Page 549 of 1235 Page 549 of 1235 ---PAGE BREAK--- Safety Data Sheet Lubri-Temp PAGE 1 of 4 SECTION I - IDENTIFICATION PRODUCT NAME: Lubri-Temp PRODUCT CODE: 19923 PRODUCT USE: Lubricant COMPANY NAME: Lawson Products, Inc. COMPANY ADDRESS: 8770 W. Bryn Mawr Suite 900, Chicago, Il 60631 COMPANY PHONE: [PHONE REDACTED] EMERGENCY PHONE: [PHONE REDACTED] SECTION II – HAZARDS IDENTIFICATION CLASSIFICATION: Does not present a hazard according to OSHA (29CFR 1910.1200) HAZARD STATEMENT(S): N/A This product contains the following percentage of chemicals of unknown toxicity: 0% PRECAUTIONARY STATEMENTS: N/A SYMBOL: N/A HAZARDS NOT OTHERWISE CLASSIFIED: N/A SECTION III – COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS INGREDIENT CAS NUMBER PERCENT N/A N/A N/A SECTION IV - FIRST AID MEASURES EYES: Immediately flush with water for 15 - 20 minutes while holding eyelids open. Seek medical attention if irritation persists. INGESTION: Rinse mouth with water. Do not induce vomiting unless directed by medical authority. Seek medical attention if irritation persists. INHALATION: Move to fresh air. Avoid breathing oil mists. If breathing is difficult, administer oxygen. If not breathing administer artificial respiration. Seek immediate medical attention. SKIN: Immediately wash with soap and water for 15 minutes. Seek medical attention if irritation develops. ACUTE HEALTH HAZARDS: None Known CHRONIC HEALTH HAZARDS: None known NOTE TO PHYSICIAN: There is no specific treatment regimen. Treatment of overexposure should be directed at the control of and the clinical condition of the patient. SECTION V – FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA: Dry chemical or suitable for surrounding materials. UNSUITABLE EXTINGUISHING MEDIA: Water spray/stream. SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing and NIOSH approved SCBA with full facepiece operated in positive pressure or pressure demand. Use water mist to keep material cool in fire situations. UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep away from oxygen generating materials. HAZARDOUS COMBUSTION PRODUCTS: N/A SECTION VI – ACCIDENTAL RELEASE MEASURES PERSONAL PROTECTIVE EQUIPMENT: Refer to section VIII for proper Personal Protective Equipment. SPILL: Clean up using cloth or absorbent material. dispose of product-containing wiping cloth or absorbent paper in suitable manner. place waste in proper containers for waste disposal. WASTE DISPOSAL: Dispose of in accordance with federal, state, and local regulations. Do not reuse container and recycle or place in trash collection. Drums and pails should be offered for recycling. RCRA STATUS: Product should be fully characterized prior to disposal (40 CFR 261). Page 550 of 1235 Page 550 of 1235 Page 550 of 1235 Page 550 of 1235 ---PAGE BREAK--- Safety Data Sheet Lubri-Temp PAGE 2 of 4 SECTION VII – HANDLING AND STORAGE HANDLING AND STORAGE: Store in a cool, dry area. Do not use or store near heat or open flames. Keep container closed when not in use. OTHER PRECAUTIONS: Keep out of the reach of children. INCOMPATIBILITY: None Known SECTION VIII – EXPOSURE CONTROLS/PERSONAL PROTECTION HAZARDOUS INGREDIENT OSHA PEL ACGIH TLV N/A N/A N/A ENGINEERING CONTROLS / VENTILATION: Ambient ventilation adequate. RESPIRATORY PROTECTION: Not required with normal use. PERSONAL PROTECTIVE EQUIPMENT: Safety glasses and chemical resistant gloves ADDITIONAL MEASURES: Wash hands thoroughly with soap and water after use. SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Grey-Aluminum paste ODOR: Bland odor ODOR THRESHOLD: N/D BOILING POINT: Decomposes FREEZING POINT: N/D FLAMMABILITY: Not considered a flammable liquid by OSHA (29CFR 1910.1200) FLASH POINT: N/D AUTOIGNITION TEMPERATURE: N/D LOWER FLAMMABILITY LIMIT: N/D UPPER FLAMMABILITY LIMIT: N/D VAPOR PRESSURE (mm Hg): N/A VAPOR DENSITY (AIR=1): N/A EVAPORATION RATE: < 1 SPECIFIC GRAVITY (H2O=1): 0.950 SOLIDS N/A SOLUBILITY IN WATER: 0% PARTITION COEFFICIENT: n-OCTANOL/WATER (KOW): N/D VOLATILITY INCLUDING WATER VOLATILE ORGANIC COMPOUNDS (VOC): 0% DIELECTRIC STRENGTH (Volts): N/D DECOMPOSITION TEMPERATURE: N/D VISCOSITY: N/D SECTION X – STABILITY AND REACTIVITY DATA REACTIVITY: None Known CHEMICAL STABILITY: Stable CONDITIONS TO AVOID: Excessive heat. Sources of ignition. INCOMPATIBILITY: None Known HAZARDOUS DECOMPOSITION OR BY-PRODUCT: None Known POSSIBLE HAZARDOUS REACTIONS: None Known SECTION XI – TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION: Not Established ROUTES OF ENTRY: Eyes, Ingestion,Skin EYES: May cause irritation with prolonged exposure. INGESTION: Causes gastrointestinal irritation, nausea, diarrhea, vomiting. Page 551 of 1235 Page 551 of 1235 Page 551 of 1235 Page 551 of 1235 ---PAGE BREAK--- Safety Data Sheet Lubri-Temp PAGE 3 of 4 INHALATION: Unlikely due to low vapor pressure. Mist may cause irritation to the respiratory tract, headache. SKIN: Causes irritation with prolonged contact. MEDICAL CONDITION AGGRAVATED: None known ACUTE HEALTH HAZARDS: None Known CHRONIC HEALTH HAZARDS: None known CARCINOGENICITY: OSHA: No ACGIH: No NTP: No IARC: No OTHER: N/A SECTION XII – ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: Not Established BIODEGRADABILITY: Component or components of this product are not biodegradable. BIOACCUMULATION: Components in this mixture can bioaccumulate in aquatic organisms. SOIL MOBILITY: This product is not mobile in soil OTHER ECOLOGICAL HAZARDS: None Known SECTION XIII – DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with federal, state, and local regulations. Do not reuse container and recycle or place in trash collection. Drums and pails should be offered for recycling. RCRA STATUS: Product should be fully characterized prior to disposal (40 CFR 261). SECTION XIV - TRANSPORTATION INFORMATION PROPER SHIPPING NAME: Lubricating Oil Petroleum Base HAZARD CLASS/DIVISION: Not Regulated UN/NA NUMBER: N/A PACKAGING GROUP: None AIR SHIPMENT PROPER SHIPPING NAME: Lubricating Oil Petroleum Base HAZARD CLASS/DIVISION: Not Regulated UN/NA NUMBER: N/A SHIPPING BY WATER: VESSEL (IMO/IMDG) PROPER SHIPPING NAME: Lubricating Oil Petroleum Base HAZARD CLASS/DIVISION: Not Regulated UN/NA NUMBER: N/A ENVIRONMENTAL HAZARDS WATER: N/A SECTION XV - REGULATORY INFORMATION TSCA STATUS: All Chemicals are listed or exempt. CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): None SARA 311/312 HAZARD CATEGORIES: None SARA 313 REPORTABLE INGREDIENTS: None STATE REGULATIONS: California Proposition 65: None INTERNATIONAL REGULATIONS: All components are listed or exempted. NFPA HEALTH: 1 HMIS HEALTH: 1 NFPA FLAMMABILITY: 1 HMIS FLAMMABILITY: 1 NFPA REACTIVITY: 1 HMIS REACTIVITY: 1 NFPA OTHER: None HMIS PROTECTION: A SECTION XVI - ADDTIONAL INFORMATION PREPARATION BY: Maureen Ruggeberg, Regulatory Affairs Specialist DATE PREPARED: 12/4/2012 Page 552 of 1235 Page 552 of 1235 Page 552 of 1235 Page 552 of 1235 ---PAGE BREAK--- Safety Data Sheet Lubri-Temp PAGE 4 of 4 REVISION DATE: 10/30/2014 N/A = Not Applicable; N/D = Not Determined DISCLAIMER: To the best of our knowledge, information contained herein is accurate. However there is no assumption of liability for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazard which exists. The information contained in this SDS was obtained from current and reliable sources; however, the data is provided without any warranty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of the manufacturer, the manufacturer will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this SDS shall be created or inferred by any statement in this SDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this SDS. The user is responsible for full compliance. Page 553 of 1235 Page 553 of 1235 Page 553 of 1235 Page 553 of 1235 ---PAGE BREAK--- Material Safety Data Sheet Revision Date: 2009-08-11 07:56:38 I. PRODUCT AND COMPANY IDENTIFICATION Product Name: MAG 1 BRAKE PARTS CLEANER Product Code: MG750408 Emergency Phone: (800) 424-9300 (202) 483-7616 (CHEMTREC) Poison Control Center: (800) 222-1222 Company: Warren Distribution, Inc. 727 S. 13th St. Omaha, NE 68102 Information Phone: (800) 825-1235 (402) 341-9397 Revision Number: 2 II. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name % CAS # OSHA Exposure Limits Tetrachloroethylene 90 - 99 127-18-4 100 ppm TWA; C 200 ppm Carbon dioxide 1 - 5 124-38-9 5000 ppm TWA; 9000 mg/m3 TWA Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication Standard). III. HAZARDS IDENTIFICATION Routes of Entry: Eye contact, Skin contact, Ingestion, Inhalation Target Organs Potentially Affected by Exposure: Eyes Medical Conditions Aggravated by Exposure: Eye disease Immediate (Acute) Health Effects by Route of Exposure: Inhalation Irritation: Can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea and headache. Inhalation Toxicity: Toxic! Can cause systemic damage (see "Target Organs"). Respiratory failure is possible at high doses. Skin Contact: Can cause severe irritation, defatting, and dermatitis. Irritation effects may last for hours or days but will not likely result in permanent damage. Skin Absorption: No absorption hazard in normal industrial use. Eye Contact: Can cause severe irritation. Eye contact may result in corneal injury. may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Temporary vision impairment (cloudy or blurred vision) is possible. Ingestion Irritation: Irritating to mouth, throat, and stomach. Can cause abdominal discomfort, nausea, vomiting and diarrhea. Ingestion Toxicity: Toxic if swallowed. May cause target organ failure and/or death. Long-Term (Chronic) Health Effects: Reproductive and Developmental Toxicity: No data available to indicate product or any components present at greater than 0.1% may cause birth defects. Mutagenicity: No data available to indicate product or any components present at greater than 0.1% is mutagenic or genotoxic. Inhalation: Toxic! Can cause systemic damage upon prolonged and/or repeated exposure (see "Target Organs). MAG 1 BRAKE PARTS CLEANER Page 1 of 5 Page 554 of 1235 Page 554 of 1235 Page 554 of 1235 Page 554 of 1235 ---PAGE BREAK--- Material Safety Data Sheet Revision Date: 2009-08-11 07:56:38 Skin Contact: Upon prolonged or repeated contact can cause severe irritation, defatting, and dermatitis. May cause lingering affects but not likely to result in permanent damage if the exposure is eliminated. Skin Absorption: Upon prolonged or repeated exposure, no hazard in normal industrial use. HMIS Ratings: Health: 3 Flammability: 0 Reactivity: 0 PPE: B 0 - Least 1 - Slight 2 - Moderate 3 - High 4 - Extreme IV. FIRST-AID MEASURES Inhalation: Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not breathing, give artificial respiration and have a trained individual administer oxygen. Get medical attention immediately. Eyes: Immediately flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Get immediate medical attention and monitor the eye daily as advised by your physician. Skin Contact: Wash with soap and water. Remove contaminated clothing, launder immediately, and discard contaminated leather goods. Get medical attention immediately. Ingestion: Do not induce vomiting and seek medical attention immediately. Provide medical care provider with this MSDS.Contains a toxic substance. Seek medical help immediately and contact a poison information service. Drink two glasses of water or milk to dilute. Notes to Doctor: No additional first aid information available V. FIRE FIGHTING MEASURES Flammability Summary: Not combustible/ not flammable. Extinguishing Media: Not combustible. Use extinguishing media appropriate for surrounding fire. Fire and/or Explosion Hazards: Material will not ignite or burn. Fire Fighting Methods and Protection: Will not burn, no special instructions available. Use methods appropriate for surrounding materials. Hazardous Combustion Products: Carbon dioxide, Carbon monoxide VI. ACCIDENTAL RELEASE MEASURES Personal Precautions and Equipment: Exposure to the spilled material may be severely irritating or toxic. Follow personal protective equipment recommendations found in Section VIII of this MSDS. Personal protective equipment needs must be evaluated based on the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Methods for Clean-up: Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section VIII at a minimum. Dike with suitable absorbent material. Gather and store in a sealed container pending a waste disposal evaluation. VII. HANDLING AND STORAGE MAG 1 BRAKE PARTS CLEANER Page 2 of 5 Page 555 of 1235 Page 555 of 1235 Page 555 of 1235 Page 555 of 1235 ---PAGE BREAK--- Material Safety Data Sheet Revision Date: 2009-08-11 07:56:38 Handling Technical Measures and Precautions: Toxic or severely irritating material. Avoid contacting and avoid breathing the material. Use only in a well ventilated area. Empty containers may retain product residues/ vapors. Use proper bonding and grounding during bulk product transfer. Storage Technical Measures and Conditions: No special requirements VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures: No exposure limits exist for the constituents of this product. Use local exhaust ventilation or other engineering controls to minimize exposures and maintain operator comfort. Respiratory Protection: Respiratory protection may be required to avoid overexposure when handling this product. General or local exhaust ventilation is the preferred means of protection. Use a respirator if general room ventilation is not available or sufficient to eliminate Eye Protection: Wear chemically resistant safety glasses with side shields when handling this product. Wear additional eye protection such as chemical splash goggles and/or face shield when the possibility exists for eye contact with splashing or spraying liquid, or airborne material. Do not wear contact lenses. Have an eye wash station available. Skin Protection: Avoid skin contact by wearing chemically resistant gloves, an apron and other protective equipment depending upon conditions of use. Inspect gloves for chemical break-through and replace at regular intervals. Clean protective equipment regularly. Wash hands and other exposed areas with mild soap and water before eating, drinking, and when leaving work. Gloves: No information available Control Parameters: Chemical Name ACGIH TLV-TWA ACGIH STEL IDLH Tetrachloroethylene 25 ppm TWA; 170 mg/m3 TWA 100 ppm STEL; 685 mg/m3 STEL 150 ppm IDLH Carbon dioxide 5000 ppm TWA 30000 ppm STEL 40000 ppm IDLH IX. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Colorless Odor: Irritating pH: ND Solubility in Water: Complete; 100% Specific Gravity: 1.619 Bulk Density: 8.345 X. STABILITY AND REACTIVITY Stability: Stable under normal conditions. Conditions to Avoid: None known. Materials to Avoid/Chemical Incompatibility: Strong oxidizing agents XI. TOXICOLOGICAL INFORMATION Component Toxicology Data (NIOSH): Chemical Name CAS Number LD50/LC50 MAG 1 BRAKE PARTS CLEANER Page 3 of 5 Page 556 of 1235 Page 556 of 1235 Page 556 of 1235 Page 556 of 1235 ---PAGE BREAK--- Material Safety Data Sheet Revision Date: 2009-08-11 07:56:38 Ethylene, tetrachloro- 127-18-4 Inhalation LC50 Rat : 34200 mg/m3/8H; Inhalation LC50 Mouse : 5200 ppm/4H; Ora XII. ECOLOGICAL INFORMATION Overview: This material is not expected to be harmful to the ecology. Mobility: No data Persistence: No data Bioaccumulation: No data Degradability: No data XIII. DISPOSAL CONSIDERATIONS Disposal of Packaging: Containers of this material may be hazardous when emptied. Disposal Methods: Dispose of in a landfill. Disposal is not likely to be regulated. XIV. TRANSPORTATION INFORMATION DOT Basic Description: CONSUMER COMMODITY DOT Hazard Class: ORM-D IMDG Basic Description: AEROSOLS IMDG Hazard Class: 2.2 IMDG UN Number: UN1950 IMDG Exceptions: LTD QTY IMDG EmS: F-D,S-U IATA Basic Description: AEROSOLS IATA Hazard Class: 2.2 IATA UN Number: UN1950 XV. REGULATORY INFORMATION TSCA Status: All components of this material are on the US TSCA Inventory or are exempt. NAFTA Tariff Code: 2903.23.0000 Chemical Name CAS # Regulation % Range Ethene, tetrachloro- CERCLA RQ 127-18-4 100 lb final RQ; 45.4 kg final RQ Tetrachloroethylene (Perchloroethylene) 127-18-4 SARA 313 90 - 99 Tetrachloroethylene 127-18-4 CA Prop 65 - Cancer 90 - 99 Perchloroethylene 127-18-4 Canadian WHMIS list 90 - 99 Carbon dioxide 124-38-9 Canadian WHMIS list 1 - 5 Tetrachloroethylene 127-18-4 Massachusetts RTK List 90 - 99 Carbon dioxide 124-38-9 Massachusetts RTK List 1 - 5 Tetrachloroethylene 127-18-4 New Jersey RTK List 90 - 99 Carbon dioxide 124-38-9 New Jersey RTK List 1 - 5 Ethene, tetrachloro- 127-18-4 RTK List 90 - 99 Carbon dioxide 124-38-9 RTK List 1 - 5 Consumer Product Safety Improvement Act of 2008 General Conformity Certification: The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer MAG 1 BRAKE PARTS CLEANER Page 4 of 5 Page 557 of 1235 Page 557 of 1235 Page 557 of 1235 Page 557 of 1235 ---PAGE BREAK--- Material Safety Data Sheet Revision Date: 2009-08-11 07:56:38 Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product container. XVI. ADDITIONAL INFORMATION Disclaimer: This material safety data sheet and the information it contains is offered to you in good faith as accurate. We have reviewed any information contained in the data sheet which we have received from outside sources and we believe the information to be correct, but cannot guarantee its accuracy or completeness. Health and safety precautions in this data sheet may not be adequate for all individuals and/or situations. It is the user's obligation to evaluate and use this product in a safe manner and to comply with all applicable laws and regulations. No statement made in this data sheet shall be construed as permission or recommendation for the use of any product in a manner that might infringe existing patents. No warranty is made, either expressed or implied. MAG 1 BRAKE PARTS CLEANER Page 5 of 5 Page 558 of 1235 Page 558 of 1235 Page 558 of 1235 Page 558 of 1235 ---PAGE BREAK--- March 1,2010 Page 1 of 5 MATERIAL SAFETY DATA SHEET 1. PRODUCT AND COMPANY IDENTICATION PRODUCT NAME PRODUCT CODE CHEMICAL FAMILY CHEMICAL NAME FORMULA MANUFACTURER Marvel Oil Company, !nc 625 Willowbrook Centre Parkway Willowbrook, IL 60527 Phone: [PHONE REDACTED] Fax: [PHONE REDACTED] Marvel Air Tool Oil MM080, MM085, MM85R, MM086, MM088R, MM089 MM, MM85RI Petroleum Distillates Complex Mixture of Hydrocarbons Mixture EMERGENCY TELEPHONE NUMBERS Transportation: CHEMTREC: [PHONE REDACTED] Medical: ROCKY MTN POISON CTR: [PHONE REDACTED] POSITION/INFORMATION ON INGREDIENTS COMPONENT CAS NUMBER Naphthenic Hydrocarbons 64742-52-5 Mineral Spirits 08052-41-3 Chlorinated Hydrocarbons 00095-50-1 EXPOSURE LIMITS 8 hrs. TWA(ppni) OSHA PEL 5 as oil mist 100 25 CONCENTRATION (wt 70- 20- 0- -80 -30 -1 ACGIH TLV 5 as oil mist 100 25 Naphthenic Hydrocarbons Mineral Spirits Chlorinated Hydrocarbons HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS INHALATION: Can cause nasal and respiratory irritation, dizziness, weakness, fatigue, nausea, headache, possible unconsciousness and even INGESTION: Can cause gastrointestinal irritation, nausea, vomiting and diarrhea. Aspiration into lungs can cause pneumcmitis wiiich can be fatal. SKIN CONTACT: Prolonged or repeated contact can cause moderated irritation, defatting or dermatitis. EYE CONTACT: Can cause severe irritation, redness, tearing or blurred vision. PDF created with pdfFactory trial version www.pdffactorv.com Page 559 of 1235 Page 559 of 1235 Page 559 of 1235 Page 559 of 1235 ---PAGE BREAK--- March 1,2010 Page 2 of 5 4. FIRST AID MEASURES EYE: Flush with large amounts of water, lifting upper and lower eyelids occasionally. Get medical attention. SKIN: Thoroughly was exposed area with soap and water. Remove contaminated clothing. Launder before re-use. INHALATION: Remove person to fresh air. If breathing difficult, administer oxygen. If breathing has stopped, give artificial respiratiOTi. Keep person warm and quiet. Call a physician. INGESTION: Do not induce vomiting. Keep person quiet and warm. Get medical attenticm. Aspiration of material into lungs can cause chemical pneumonitis which can be fatal. 5. FIRE FIGHTING MEASURES FLASHPOINT: 128 " F (53 TCC EXTINGUISHING MEDIA: Carbon dioxide, dry chemical, foam. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus with ftiil facepiece operated with positive pressure-demand when fighting large fires. 6. ACCIDENTIAL RELEASE MEASURES SPILL OR LEAK PROCEDURES: Ventilate area. Remove sources of ignition. Prevent entry into sewers and waterways. Pick up free liquid for recycle and/or disposal. Absorb small amounts on inert material for disposal. 7. HANDLING AND STORAGE STORAGE TEMPERATURE (MIN./MAX.): -40 " F (-40 * 120 F (49 C) SHELF LIFE: 7-10 years minimum when the original container is kept closed and properiy stored. SPECIAL SENSITIVITY: None. HANDLING AND STORAGE PRECAUTIONS: Empty containers may be dangerous since fumes may still exist. Observe precautions given for this product as stated in this document. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION EYE PROTECTION REQUIREMENTS: Splash goggles. SKIN PROTECTION REQUIREMENTS: Wear chemically resistant gloves. RESPIRATOIWENTILATION REQUIREMENTS: Provide sufficient ventilation to avoid exposure levels above the established TLV's. EXPOSURE LIMITS: Not established for product as whole. Mineral Spirits NIOSH 100 ppm TWA Oil Mist OSHA 5 mg/m3 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL FORM: Thin liquid PDF created witli pdfFactory trial version www.pdffactorv.com Page 560 of 1235 Page 560 of 1235 Page 560 of 1235 Page 560 of 1235 ---PAGE BREAK--- March 1,2010 Page 3 of 5 COLOR: Red ODOR: Petroleum BOILING POINT: Not determined MELT / FREEZE POINT - 60 " F ( - 51 C) FH: Not applicable SOLUBILITY IN WATER: Insoluble SPECIFIC GRAVITY: 0.876 @ 60 " F (15.6 ° C) % VOLATILE BY WEIGHT: 25 % VAPOR PRESSURE: Not determined VAPOR DENSITY: Not determined 10. REACTIVITY STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur. INCOMPATIBILITIES: Strong oxidizing agents. DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide and hydrocarbons. 11. TOXICOLOGICAL INFORMATION ACUTE INHALATION: Aspiration into lungs can cause pneumonitis which can be fatal. CHRONIC INHALATION: Not determined. ACUTE SKIN CONTACT: Prolonged or repeated contact can cause moderate irritation, defatting or dermatitis. CHRONIC SKIN CONTACT: Not determined. ACUTE EYE CONTACT: Can cause severe irritation, redness, tearing or blurred vision. 12. ECOLOGICAL INFORMATION No data available. 13. DISPOSAL CONSIDERATIONS Ignitable hazardous waste, EPA Hazardous Waste Number DOOl WASTE DISPOSAL METHOD: Dispose of product in accordance with all local, state and federal laws and regulations. 14. TRANSPORT INFORMATION DOT INFORMATION: PDF created with pdfFactory trial version www.pdffactorv.com Page 561 of 1235 Page 561 of 1235 Page 561 of 1235 Page 561 of 1235 ---PAGE BREAK--- March 1,2010 Page 4 of 5 15. PROPER SHIPPING NAME: TECHNICAL SHIPPING NAME: HAZARD CLASS: UN NUMBER: PRODUCT RQ (lbs): LABEL: PLACARD: FREIGHT CLASS BULK: FREIGHT CLASS PACKAGE: PRODUCT LABEL REGULATORY INFORMATION TSCA STATUS: CERCLA REPORTABLE QUANTITY: SARA TITLE lU: SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES SECTION 311/312 HAZARD CATEGORIES Non Bulk Not regulated Bulk Petroleum distillates, n.o.s. Fuel and oil additive Non Bulk Bulk Non Bulk Bulk Non Bulk Bulk ORM-D Class 3 UN 1268 None ORM-D Flammable Liquid None Flammable Liquid PGIII None None All ingredients listed. None None Acute Health Chronic Health Fire Reactive Sudden Release of Pressure SECTION 313 CHEMICAL NAME Orth o-di ch 1 oroben zene Yes Yes Yes No No CAS NUMBER 00095-50-1 CONCENTRATION 0 - 0.25 % RCRA STATUS: If discarded in its purchased form, this product would be an ignitable waste with an EPA Hazardous Waste Number of DOOl. However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product should be classified as a hazardous waste. (40CFR261.20-24) PDF created with pdfFactory trial version www.Ddffactorv.com Page 562 of 1235 Page 562 of 1235 Page 562 of 1235 Page 562 of 1235 ---PAGE BREAK--- March 1,2010 Page 5 of 5 CANADIAN STATUS: All materials contained in this product are listed on the Canadian Domestic Substances List. EUROPEAN UNION: All materials contained in this product are listed on EINECS. STATE REGULATORY INFORMATION The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the MSDS may also be applicable for state requirements. For details on your regulatory requirements you should contact the appropriate agency in your state. COMPONENT/ CAS NUMBER p-dichlorobenzene 00106-46-7 CONCENTRATION less than 150 ppm STATE CODE CA CA = Material known to the state of California to cause cancer and/or birth defects. (California Proposition 65). 16. OTHER INFORMATION HMIS CLASSIFICATION NFPA RATING Health Flanrunability Reactivity PPI Health Fire Reactivity Special 2 2 0 B 2 2 0 None Shelf Life Up-date James P. Heidel Technical Director, R&D November 15, 2010 March 1,2010 #09 REASON FOR ISSUE PREPARED BY TITLE APPROVAL DATE SUPERCEDES DATE REVISION NUMBER This information is to the best of Marvel Oil Company's knowledge and belief, accurate and reliable. However, no representation, warranty, or guarantee is made to its accuracy, reliability or completeness. It is the users responsibility to satisfy himself as to the suitableness and completeness of such information for his own particular use. doc PDF created with pdfFactory trial version www.pdffactorv.com Page 563 of 1235 Page 563 of 1235 Page 563 of 1235 Page 563 of 1235 ---PAGE BREAK--- The Valspar Corporation Material Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION Material Identification Product ID: [PHONE REDACTED] Product Name: MCCLOSKEY SPECIAL EFFECTS CLEAR COAT -FLAT Product Use: Paint product. Date Published: 2004/10/20 Revision Date: 2003/12/09 Company Identification The Valspar Corporation - Architectural Coatings Division 1191 Wheeling Road Wheeling, IL 60090 Manufacturer's Phone: 1-[PHONE REDACTED] 24-Hour Medical Emergency Phone: 1-[PHONE REDACTED] 2. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS Common Name CAS # Approx Wt% Chemical name AMORPHOUS SILICA 112945-52-5 1 - 5 PROPRIETARY INGREDIENT If this section is blank there are no hazardous components per OSHA guidelines. 3. HAZARDS IDENTIFICATION Primary Routes of Exposure: Inhalation Ingestion Skin absorption Emergency Overview: This section not in use. This product contains ingredients that may contribute to the following potential acute health effects: Inhalation Effects: Exposure to high concentrations causes irritation of the respiratory tract. Eye Contact: May irritate eyes. Skin Contact: Can dry skin. Product ID: [PHONE REDACTED] Page 1 of 5 Page 564 of 1235 Page 564 of 1235 Page 564 of 1235 Page 564 of 1235 ---PAGE BREAK--- Acute Ingestion: None known Other Effects: None known This product contains ingredients that may contribute to the following potential chronic health effects: See Section 11 for toxicological information about Mutagens, Teratogens and Carcinogens. If this section is blank, no information is available. 4. FIRST AID MEASURES Inhalation: If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention. Eye Contact: In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing. Skin Contact: Remove contaminated clothing and launder before reuse. In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. If irritation persists get medical attention. Ingestion: If swallowed, contact medical personnel immediately to determine best course of action. Medical conditions aggravated by exposure: Any respiratory or skin condition. 5. FIRE FIGHTING MEASURES Flash point (Fahrenheit): 201º F ( 94º C) TCC/PM Lower explosive limit: Not available. % Upper explosive limit: Not available. % Autoignition temperature: Not available.º F ( º C) Sensitivity to impact: No. Sensitivity to static discharge: Sensitivity to static discharge is not expected. Hazardous combustion products: See Section 10. Unusual fire and explosion hazards: None known. Extinguishing media: Carbon dioxide, dry chemical, foam and/or water fog. Fire fighting procedures: Firefighters should be equipped with self-contained breathing apparatus and turn out gear. 6. ACCIDENTAL RELEASE MEASURES Product ID: [PHONE REDACTED] Page 2 of 5 Page 565 of 1235 Page 565 of 1235 Page 565 of 1235 Page 565 of 1235 ---PAGE BREAK--- Action to be taken if material is released or spilled: Not determined. 7. HANDLING AND STORAGE Precautions to be taken in handling and storage: Keep container closed when not in use. 8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS Personal Protective Equipment Eye and face protection: Avoid contact with eyes. Wear chemical goggles if there is the possibility of contact or splashing in the eye. Skin protection: Appropriate chemical resistant gloves should be worn.To prevent skin contact wear protective clothing covering all exposed areas. Respiratory protection: If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an air purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's literature to ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's instructions. Ventilation Required when spraying or applying in confined area. Exposure Guidelines OSHA Permissible Exposure Limits (PEL's) ACGIH Threshold Limit Value (TLV's) If this section is blank, no information is available. 9. PHYSICAL PROPERTIES Odor: Normal for this product type. Physical State: Liquid pH: Not determined. Vapor pressure: 24 mmHG @ 77º F ( 25º C) Vapor density (air = 1.0): 2.6 Boiling point: 212º F ( 100º C) Solubility in water: Not determined. Coefficient of water/oil distribution: Not determined. Density (weight per gallon): 8.41 Specific gravity (water = 1.01 Evaporation rate (butyl acetate = 1.0): 0.4 10. STABILITY AND REACTIVITY Product ID: [PHONE REDACTED] Page 3 of 5 Page 566 of 1235 Page 566 of 1235 Page 566 of 1235 Page 566 of 1235 ---PAGE BREAK--- Stability: This product is stable. Conditions to Avoid: None known. Incompatibility: None known. Hazardous Polymerization: None anticipated. Hazardous Decomposition Products: Carbon monoxide and carbon dioxide. Sensitivity to static discharge: Sensitivity to static discharge is not expected. 11. TOXICOLOGICAL INFORMATION If this section is blank, no information is available. 12. ECOLOGICAL DATA Not available at this time. 13. DISPOSAL CONSIDERATIONS Disposal should be made in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION U.S. Department of Transportation Proper Shipping Name: PAINT, NOT REGULATED 49 CFR Hazardous Material Regulations Parts 100-180 The supplier will apply the combustible liquid exception in 49 CFR 173.150(f), limited quantity or "does not sustain combustion" exceptions and consumer commodity rules, when authorized. Please check 49 CFR Parts 100-180 to determine if the use of these exceptions applies to your shipments when re-shipping our products. International Air Transport Association: Proper Shipping Name: PAINT, NOT REGULATED International Maritime Organization: Proper Shipping Name: PAINT, NOT REGULATED 15. REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: SARA 311/312 Hazard Class: Acute: Yes Chronic: No Flammability: No Reactivity: No Sudden Pressure: No U.S. STATE REGULATIONS: Product ID: [PHONE REDACTED] Page 4 of 5 Page 567 of 1235 Page 567 of 1235 Page 567 of 1235 Page 567 of 1235 ---PAGE BREAK--- Right To Know: AMORPHOUS SILICA 112945-52-5 Additional Non-Hazardous Materials PROPYLENE GLYCOL 57-55-6 WATER 7732-18-5 PROPRIETARY INGREDIENT Trade Secret Rule 66 status of product Not photochemically reactive. INTERNATIONAL REGULATIONS - Chemical Inventories TSCA Inventory: All components of this product are in compliance with U.S. TSCA Chemical Substance Inventory Requirements. Canada Domestic Substances List: Not all components in this product are listed on the Domestic Substances List. 16. OTHER INFORMATION HMIS Codes Health: 1 Flammability: 1 Reactivity: 0 PPE: X - See Section 8 for Personal Protective Equipment (PPE). Abbreviations: OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer, NIOSH - National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH - American Conference of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management District, TSCA - Toxic Substances Control Act, IATA - International Air Transport Association, IMO - International Maritime Organization, DOT - Department of Transportation, NA - Not applicable, NOT ESTAB - Not established, N.A.V. - Not available, RQ - Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams per liter, MM - Millimeters, - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per thousand, TCC/PM - Tag closed cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time Weighted Average, STEL - Short term exposure limit, C - Celsius, F - Fahrenheit. Disclaimer: The data on this sheet represent typical values. Since application variables are a major factor in product performance, this information should serve only as a general guide. Valspar assumes no obligation or liability for use of this information. UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES, EXPRESS OR IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. VALSPAR WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only remedy for any defect in this product is the replacement of the defective product, or a refund of its purchase price, at our option. This MSDS contains additional information required by the state of Product ID: [PHONE REDACTED] Page 5 of 5 Page 568 of 1235 Page 568 of 1235 Page 568 of 1235 Page 568 of 1235 ---PAGE BREAK--- Material Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION Product Identification Product ID: [PHONE REDACTED] Product Name: MCCLOSKEY SPECIAL EFFECTS CLEAR COAT -FLAT Product Use: Paint product. Print date: 20/Mar/2010 Revision Date: 02/Mar/2010 Company Identification The Valspar Corporation - Architectural Coatings Division 1191 Wheeling Road Wheeling, IL 60090 Manufacturer's Phone: 1-[PHONE REDACTED] 24-Hour Medical Emergency Phone: 1-[PHONE REDACTED] 2. HAZARDS IDENTIFICATION Primary Routes of Exposure: Inhalation Ingestion Skin absorption Eye Contact: • May cause eye irritation. Skin Contact: • Causes mild skin irritation. Ingestion: None known. Inhalation: • May cause irritation of respiratory tract. 3. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS Ingredient Name CAS-No. Approx. Weight % Chemical Name Product ID: [PHONE REDACTED] Page 1 / 6 Page 569 of 1235 Page 569 of 1235 Page 569 of 1235 Page 569 of 1235 ---PAGE BREAK--- 3. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS PROPYLENE GLYCOL 57-55-6 1 - 5 1,2-Propylene glycol PROPRIETARY INERT 1 - 5 PROPRIETARY INERT If this section is blank there are no hazardous components per OSHA guidelines. 4. FIRST AID MEASURES Eye Contact: Get medical attention, if develop or persist. Immediately flush eye(s) with plenty of water. Skin Contact: Wash off with plenty of water. Ingestion: Get medical attention if occur Inhalation: Move to fresh air. Get medical attention, if develop or persist. Medical conditions aggravated by exposure: Any respiratory or skin condition. 5. FIRE FIGHTING MEASURES Flash point (Fahrenheit): 201 Flash point (Celsius): 94 Lower explosive limit not determined Upper explosive limit not determined Autoignition temperature: not determined Sensitivity to impact: no Sensitivity to static discharge: Sensitivity to static discharge is not expected. Hazardous combustion products: See Section 10. Unusual fire and explosion hazards: None known. Extinguishing media: Carbon dioxide, dry chemical, foam and/or water fog. Fire fighting procedures: Firefighters should be equipped with self-contained breathing apparatus and turn out gear. Keep containers and surroundings cool with water spray. 6. ACCIDENTAL RELEASE MEASURES Action to be taken if material is released or spilled: Ventilate the area. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Avoid contact with eyes. 7. HANDLING AND STORAGE Precautions to be taken in handling and storage: Keep container closed when not in use. Do not freeze. Since emptied containers may contain product residue, follow all label warnings, even after container is emptied. Do not cut, drill, grind, or weld on or near this container. Product ID: [PHONE REDACTED] Page 2 / 6 Page 570 of 1235 Page 570 of 1235 Page 570 of 1235 Page 570 of 1235 ---PAGE BREAK--- 8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS Personal Protective Equipment Eye and face protection: Wear safety glasses or goggles to protect against exposure. Skin protection: Appropriate chemical resistant gloves should be worn. Respiratory protection: If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an air purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's literature to ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's instructions. Ventilation Use only in well-ventilated areas. Ensure adequate ventilation, especially in confined areas. Exposure Guidelines OSHA Permissible Exposure Limits (PEL's) Ingredient Name CAS-No. Approx. Weight % TWA (final) Ceilings limits (final) Skin designations PROPRIETARY INERT 1 - 5 5 mg/m3 Respirable fraction. 15 mg/m3 Total dust. Respirable fraction. Listed. Total dust. Listed. ACGIH Threshold Limit Value (TLV's) Ingredient Name CAS-No. Approx. Weight % TWA STEL Ceiling limits Skin designations PROPRIETARY INERT 1 - 5 10 mg/m³ 9. PHYSICAL PROPERTIES Odor: Normal for this product type. Physical State: liquid pH: not determined Vapor pressure: 24 mmHg @ 77ºF (25ºC) Vapor density (air = 1.0): 2.62 Boiling point: not determined Solubility in water: not determined Coefficient of water/oil distribution: not determined Density (lbs per US gallon): 8.41 Specific Gravity: 1.01 Evaporation rate (butyl acetate = 1.0): 0.1 Flash point (Fahrenheit): 201 Flash point (Celsius): 94 Lower explosive limit not determined Upper explosive limit not determined Product ID: [PHONE REDACTED] Page 3 / 6 Page 571 of 1235 Page 571 of 1235 Page 571 of 1235 Page 571 of 1235 ---PAGE BREAK--- 9. PHYSICAL PROPERTIES Autoignition temperature: not determined 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions. Conditions to Avoid: None known. Incompatibility: Avoid water-reactive materials, heat or contact with peroxides or other Hazardous Polymerization: None anticipated. Hazardous Decomposition Products: Carbon monoxide and carbon dioxide. Sensitivity to static discharge: Sensitivity to static discharge is not expected. 11. TOXICOLOGICAL INFORMATION Ingredient Name CAS-No. Approx. Weight % NIOSH - Selected LD50s and LC50s PROPYLENE GLYCOL 57-55-6 1 - 5 = 20000 mg/kg Oral LD50 Rat = 20800 mg/kg Dermal LD50 Rabbit PROPRIETARY INERT 1 - 5 = 3160 mg/kg Oral LD50 Rat Mutagens/Teratogens/Carcinogens: None known. 12. ECOLOGICAL DATA No information on ecology is available. 13. DISPOSAL CONSIDERATIONS Disposal should be made in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION U.S. Department of Transportation Proper Shipping Name: PAINT, NOT REGULATED U.S. Highway & Rail Shipments The supplier may apply one of the following exceptions: Combustible Liquid, Consumer Commodity, Limited Quantity, Viscous Liquid, Does Not Sustain Combustion, or others, as allowed under 49CFR Hazmat Regulations. Please consult 49CFR Subchapter C to ensure that subsequent shipments comply with these exceptions. Reportable Quantity Description: International Air Transport Association (IATA): Proper Shipping Name: PAINT, NOT REGULATED International Maritime Organization (IMO): Proper Shipping Name: PAINT, NOT REGULATED 15. REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: SARA 311/312 Hazard Class: Product ID: [PHONE REDACTED] Page 4 / 6 Page 572 of 1235 Page 572 of 1235 Page 572 of 1235 Page 572 of 1235 ---PAGE BREAK--- 15. REGULATORY INFORMATION Acute: yes Chronic: no Flammability: no Reactivity: no Sudden Pressure: no U.S. STATE REGULATIONS: Right to Know: The specific chemical identity of a component may be withheld as a trade secret under 34 Code, Chapter 317. Right To Know: PROPRIETARY INERT Trade Secret PROPYLENE GLYCOL 57-55-6 Additional Non-Hazardous Materials WATER 7732-18-5 PROPRIETARY ADDITIVE Trade Secret Rule 66 status of product Not photochemically reactive. INTERNATIONAL REGULATIONS - Chemical Inventories US TSCA Inventory: All components of this product are in compliance with U.S. TSCA Chemical Substance Inventory Requirements. Canada Domestic Substances List: Not all components in this product are listed on the Domestic Substances List. 16. OTHER INFORMATION HMIS Codes Health: 1 Flammability: 1 Reactivity: 0 PPE: X - See Section 8 for Personal Protective Equipment (PPE). Abbreviations: OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer, NIOSH - National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH - American Conference of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management District, TSCA - Toxic Substances Control Act, IATA - International Air Transport Association, IMO - International Maritime Organization, DOT - Department of Transportation, NA - Not applicable, NOT ESTAB - Not established, N.A.V. - Not available, RQ - Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams per liter, MM - Millimeters, - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per thousand, TCC/PM - Tag closed cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time Weighted Average, STEL - Short term exposure limit, C - Celsius, F - Fahrenheit. Product ID: [PHONE REDACTED] Page 5 / 6 Page 573 of 1235 Page 573 of 1235 Page 573 of 1235 Page 573 of 1235 ---PAGE BREAK--- Disclaimer: The data on this sheet represent typical values. Since application variables are a major factor in product performance, this information should serve only as a general guide. Valspar assumes no obligation or liability for use of this information. UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES, EXPRESS OR IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. VALSPAR WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only remedy for any defect in this product is the replacement of the defective product, or a refund of its purchase price, at our option. This MSDS contains additional information required by the state of Preparation Information: Prepared By: Regulatory Affairs Department Print date: 20/Mar/2010 Revision Date: 02/Mar/2010 Product ID: [PHONE REDACTED] Page 6 / 6 Page 574 of 1235 Page 574 of 1235 Page 574 of 1235 Page 574 of 1235 ---PAGE BREAK--- Mean Green Super Strength Cleaner & Degreaser Material Safety Data Sheet Manufacturer CR Brands, Inc. PO Box 2708, Spartanburg, SC 29304 [PHONE REDACTED] Preparation Date October, 2009 Emergency Contact CHEM-TEL 1-[PHONE REDACTED] Product Name Mean Green Super Strength Cleaner & Degreaser Product Description A detergent compound containing builders, 2-butoxyethanol, surfactant, and water. Product Item 32 oz.-100 40 oz.-140 Gallon-101 30 Gallon-103 55 Gallon-104 Section I- Hazardous Ingredients Hazardous Ingredients ACGIH TLV OSHA PEL CAS# % 2-butoxyethanol 25ppm skin 50ppm skin 111-76-2 2-4 Tetrasodium EDTA None established 64-02-8 1-4 Section II - Physical Data ph 12.2 - 12.5 Boiling Point N/D Vapor Pressure N/D Melting Point N/A Solubility In Water Complete Evap. Rate (Ether=1) <1 Appearance and Odor Clear green liquid with mild odor Section III- Fire and Explosion Hazard Data Flash Point None Flammable Limits LFL N/A UFL N/A Extinguishing Media This material is not flammable. Use extinguisher suitable for surrounding fire, e.g., water fog, CO2, dry chemicals foam. Special Fire Fighting Procedures: Fire Fighters should wear full protective clothing and breathing apparatus. Unusual Fire and Explosion Hazards: None Known Section IV- Reactivity Stability Stable at ambient temperature and pressures. Conditions to Avoid None Known Incompatibility (Materials to Avoid) Strong Oxidizing agents, bleaches, strong acids Hazardous Decomposition Products : As with any organic compound, burning of product can generate carbon dioxide and/or carbon monoxide. Hazardous Polymerization Will not occur. Section V- Health Hazard Data Mean Green is formulated to be used full strength on difficult jobs or diluted with water for normal jobs. If product is used full strength the following precautions should be taken if performing large jobs. (sections 5,6,7,8) Route(s) of Entry Inhalation, Ingestion, skin and eye contact. Eyes (acute) Contact causes irritation. Avoid prolonged contact. Skin (acute) Contact can irritate the skin. Prolonged contact can cause skin irritation. Inhalation Exposure to mists may cause irritation Ingestion Can cause irritation of the mouth, throat, and digestive tract. Skin Absorption Glycol ether is absorbed through the skin and over exposure may cause systemic effects such as headache, dizziness, and nausea. Carcinogenicity: NTP?- No; IARC Monographs? -No OSHA Regulated- Yes,(butoxyethanol) Medical Conditions Generally Aggravated by Exposure: Persons with impaired pulmonary function may be at increased risk of exposure Page 575 of 1235 Page 575 of 1235 Page 575 of 1235 Page 575 of 1235 ---PAGE BREAK--- Mean Green Super Strength Cleaner & Degreaser MSDS page 2 Section VI- Emergency and First Aid Procedures Eye Contact Immediately rinse with large amounts of water for at least 15 minutes, occasionally lifting upper and lower lids. Obtain medical attention. Skin Contact Remove all contaminated clothing. Flush contaminated skin with large quantities of water. Obtain medical attention if irritation persists. Launder clothing before reuse. Inhalation Move to fresh air. If breathing is difficult, administer oxygen. If breathing has stopped, give artificial respiration. Ingestion Drink plenty of water. Consult physician if necessary. Section VII- Precautions for Safe Handling and Use Steps to be taken in case material is released or spilled: In case of any spill consult local, state, or EPA regulations authorities for guidelines. Section VIII- Control Measures When Product is Used Full Strength on Large Tasks & Overhead Respiratory Protection None normally required. Ventilation Provide ventilation (general and or local exhaust) to maintain exposure below TLV. Eye Protection Safety glasses with side shields or chemical safety goggles. Skin Protection Chemical resistant apron. Impervious clothing, rubber gloves. Other Protective Clothing or Equipment Safety shower and eye wash station. N/D= Not Determined N/A= Not Applicable This information is provided as a customer service and to the best of our knowledge is current and accurate. It’s user’s obligation to determine the conditions of safe use of the product. Section IX- Other Regulatory Information A. Mean Green Super Strength Cleaner & Degreaser HMIS Health 2 Flammability 0 Reactivity 1 Personal Protection B Density- 1.015 B. VOC Content 4% C. SARA 313 Supplier Notification This product contains the following toxic chemicals subject to the reporting requirements if section 313 of the Emergency Planning and Community Right- to-know Act of 1986 (40 CFR 372) CAS#: 111-76-2 Chemical name: 2-butoxyethanol % by weight: 2-4 D. State right to know: NJ, PA, MA Water 7732-18-5 2-butoxyethanol 111-76-2 Ethoxylated alcohol 9016-45-9 Tetrasodium ethylenediamine tetraacetate 64-02-8 Sodium Silicate 1344-09-8 E. This product may contain the following material in excess of threshold limits listed in California Proposition 65 as a potential carcinogen: Ethylene oxide CAS# 75218 Page 576 of 1235 Page 576 of 1235 Page 576 of 1235 Page 576 of 1235 ---PAGE BREAK--- Mean Green Super Strength Cleaner & Degreaser Material Safety Data Sheet Manufacturer CR Brands, Inc. 141 Venture Blvd., Spartanburg, SC 29306, [PHONE REDACTED] Preparation Date July, 2012 Emergency Contact CHEM-TEL 1-[PHONE REDACTED] Product Name Mean Green Super Strength Cleaner & Degreaser Product Description A detergent compound containing builders, 2-butoxyethanol, surfactant, and water. Product Item 32 oz.-100 40 oz.-140 Gallon-101 30 Gallon-103 55 Gallon-104 Section I- Hazardous Ingredients Hazardous Ingredients ACGIH TLV OSHA PEL CAS# % 2-butoxyethanol 25ppm skin 50ppm skin 111-76-2 2-4 Tetrasodium EDTA None established 64-02-8 1-4 Section II - Physical Data ph 12.2 - 12.5 Boiling Point N/D Vapor Pressure N/D Melting Point N/A Solubility In Water Complete Evap. Rate (Ether=1) <1 Appearance and Odor Clear green liquid with mild odor Section III- Fire and Explosion Hazard Data Flash Point None Flammable Limits LFL N/A UFL N/A Extinguishing Media This material is not flammable. Use extinguisher suitable for surrounding fire, e.g., water fog, CO2, dry chemicals foam. Special Fire Fighting Procedures: Fire Fighters should wear full protective clothing and breathing apparatus. Unusual Fire and Explosion Hazards: None Known Section IV- Reactivity Stability Stable at ambient temperature and pressures. Conditions to Avoid None Known Incompatibility (Materials to Avoid) Strong Oxidizing agents, bleaches, strong acids Hazardous Decomposition Products : As with any organic compound, burning of product can generate carbon dioxide and/or carbon monoxide. Hazardous Polymerization Will not occur. Section V- Health Hazard Data Mean Green is formulated to be used full strength on difficult jobs or diluted with water for normal jobs. If product is used full strength the following precautions should be taken if performing large jobs. (sections 5,6,7,8) Route(s) of Entry Inhalation, Ingestion, skin and eye contact. Eyes (acute) Contact causes irritation. Avoid prolonged contact. Skin (acute) Contact can irritate the skin. Prolonged contact can cause skin irritation. Inhalation Exposure to mists may cause irritation Ingestion Can cause irritation of the mouth, throat, and digestive tract. Skin Absorption Glycol ether is absorbed through the skin and over exposure may cause systemic effects such as headache, dizziness, and nausea. Carcinogenicity: NTP?- No; IARC Monographs? -No OSHA Regulated- Yes,(butoxyethanol) Medical Conditions Generally Aggravated by Exposure: Persons with impaired pulmonary function may be at increased risk of exposure Page 577 of 1235 Page 577 of 1235 Page 577 of 1235 Page 577 of 1235 ---PAGE BREAK--- Mean Green Super Strength Cleaner & Degreaser MSDS page 2 Section VI- Emergency and First Aid Procedures Eye Contact Immediately rinse with large amounts of water for at least 15 minutes, occasionally lifting upper and lower lids. Obtain medical attention. Skin Contact Remove all contaminated clothing. Flush contaminated skin with large quantities of water. Obtain medical attention if irritation persists. Launder clothing before reuse. Inhalation Move to fresh air. If breathing is difficult, administer oxygen. If breathing has stopped, give artificial respiration. Ingestion Drink plenty of water. Consult physician if necessary. Section VII- Precautions for Safe Handling and Use Steps to be taken in case material is released or spilled: In case of any spill consult local, state, or EPA regulations authorities for guidelines. Section VIII- Control Measures When Product is Used Full Strength on Large Tasks & Overhead Respiratory Protection None normally required. Ventilation Provide ventilation (general and or local exhaust) to maintain exposure below TLV. Eye Protection Safety glasses with side shields or chemical safety goggles. Skin Protection Chemical resistant apron. Impervious clothing, rubber gloves. Other Protective Clothing or Equipment Safety shower and eye wash station. N/D= Not Determined N/A= Not Applicable This information is provided as a customer service and to the best of our knowledge is current and accurate. It’s user’s obligation to determine the conditions of safe use of the product. Section IX- Other Regulatory Information A. Mean Green Super Strength Cleaner & Degreaser HMIS Health 2 Flammability 0 Reactivity 1 Personal Protection B Density- 1.015 B. VOC Content 3% C. SARA 313 Supplier Notification This product contains the following toxic chemicals subject to the reporting requirements if section 313 of the Emergency Planning and Community Right- to-know Act of 1986 (40 CFR 372) CAS#: 111-76-2 Chemical name: 2-butoxyethanol % by weight: 2-4 D. State right to know: NJ, PA, MA Water 7732-18-5 2-butoxyethanol 111-76-2 Ethoxylated Fatty Alcohol 160875-66-1 Tetrasodium ethylenediamine tetraacetate 64-02-8 Sodium Silicate 1344-09-8 E. This product may contain the following material in excess of threshold limits listed in California Proposition 65 as a potential carcinogen: Ethylene oxide CAS# 75-21-8 Page 578 of 1235 Page 578 of 1235 Page 578 of 1235 Page 578 of 1235 ---PAGE BREAK--- Mean Green Super Strength Cleaner & Degreaser Material Safety Data Sheet Manufacturer CR Brands, Inc. 141 Venture Blvd., Spartanburg, SC 29306, [PHONE REDACTED] Preparation Date January, 2012 Emergency Contact CHEM-TEL 1-[PHONE REDACTED] Product Name Mean Green Super Strength Cleaner & Degreaser Product Description A detergent compound containing builders, 2-butoxyethanol, surfactant, and water. Product Item 32 oz.-100 40 oz.-140 Gallon-101 30 Gallon-103 55 Gallon-104 Section I- Hazardous Ingredients Hazardous Ingredients ACGIH TLV OSHA PEL CAS# % 2-butoxyethanol 25ppm skin 50ppm skin 111-76-2 2-4 Tetrasodium EDTA None established 64-02-8 1-4 Section II - Physical Data ph 12.2 - 12.5 Boiling Point N/D Vapor Pressure N/D Melting Point N/A Solubility In Water Complete Evap. Rate (Ether=1) <1 Appearance and Odor Clear green liquid with mild odor Section III- Fire and Explosion Hazard Data Flash Point None Flammable Limits LFL N/A UFL N/A Extinguishing Media This material is not flammable. Use extinguisher suitable for surrounding fire, e.g., water fog, CO2, dry chemicals foam. Special Fire Fighting Procedures: Fire Fighters should wear full protective clothing and breathing apparatus. Unusual Fire and Explosion Hazards: None Known Section IV- Reactivity Stability Stable at ambient temperature and pressures. Conditions to Avoid None Known Incompatibility (Materials to Avoid) Strong Oxidizing agents, bleaches, strong acids Hazardous Decomposition Products : As with any organic compound, burning of product can generate carbon dioxide and/or carbon monoxide. Hazardous Polymerization Will not occur. Section V- Health Hazard Data Mean Green is formulated to be used full strength on difficult jobs or diluted with water for normal jobs. If product is used full strength the following precautions should be taken if performing large jobs. (sections 5,6,7,8) Route(s) of Entry Inhalation, Ingestion, skin and eye contact. Eyes (acute) Contact causes irritation. Avoid prolonged contact. Skin (acute) Contact can irritate the skin. Prolonged contact can cause skin irritation. Inhalation Exposure to mists may cause irritation Ingestion Can cause irritation of the mouth, throat, and digestive tract. Skin Absorption Glycol ether is absorbed through the skin and over exposure may cause systemic effects such as headache, dizziness, and nausea. Carcinogenicity: NTP?- No; IARC Monographs? -No OSHA Regulated- Yes,(butoxyethanol) Medical Conditions Generally Aggravated by Exposure: Persons with impaired pulmonary function may be at increased risk of exposure Page 579 of 1235 Page 579 of 1235 Page 579 of 1235 Page 579 of 1235 ---PAGE BREAK--- Mean Green Super Strength Cleaner & Degreaser MSDS page 2 Section VI- Emergency and First Aid Procedures Eye Contact Immediately rinse with large amounts of water for at least 15 minutes, occasionally lifting upper and lower lids. Obtain medical attention. Skin Contact Remove all contaminated clothing. Flush contaminated skin with large quantities of water. Obtain medical attention if irritation persists. Launder clothing before reuse. Inhalation Move to fresh air. If breathing is difficult, administer oxygen. If breathing has stopped, give artificial respiration. Ingestion Drink plenty of water. Consult physician if necessary. Section VII- Precautions for Safe Handling and Use Steps to be taken in case material is released or spilled: In case of any spill consult local, state, or EPA regulations authorities for guidelines. Section VIII- Control Measures When Product is Used Full Strength on Large Tasks & Overhead Respiratory Protection None normally required. Ventilation Provide ventilation (general and or local exhaust) to maintain exposure below TLV. Eye Protection Safety glasses with side shields or chemical safety goggles. Skin Protection Chemical resistant apron. Impervious clothing, rubber gloves. Other Protective Clothing or Equipment Safety shower and eye wash station. N/D= Not Determined N/A= Not Applicable This information is provided as a customer service and to the best of our knowledge is current and accurate. It’s user’s obligation to determine the conditions of safe use of the product. Section IX- Other Regulatory Information A. Mean Green Super Strength Cleaner & Degreaser HMIS Health 2 Flammability 0 Reactivity 1 Personal Protection B Density- 1.015 B. VOC Content 3% C. SARA 313 Supplier Notification This product contains the following toxic chemicals subject to the reporting requirements if section 313 of the Emergency Planning and Community Right- to-know Act of 1986 (40 CFR 372) CAS#: 111-76-2 Chemical name: 2-butoxyethanol % by weight: 2-4 D. State right to know: NJ, PA, MA Water 7732-18-5 2-butoxyethanol 111-76-2 Ethoxylated 127087-87-0 Tetrasodium ethylenediamine tetraacetate 64-02-8 Sodium Silicate 1344-09-8 E. This product may contain the following material in excess of threshold limits listed in California Proposition 65 as a potential carcinogen: Ethylene oxide CAS# 75-21-8 Page 580 of 1235 Page 580 of 1235 Page 580 of 1235 Page 580 of 1235 ---PAGE BREAK--- page 1 of 3 UEL Not Applicable LEL Not Applicable FLASH POINT Not Applicable HMIS Codes Health 0 Flammability 0 Reactivity 0 DATE OF PREPARATION Feb 19, 2013 MATERIAL SAFETY DATA SHEET 62127 04 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER 62127 PRODUCT NAME MINWAX® Hardwood Floor Cleaner MANUFACTURER'S NAME MINWAX Company 10 Mountainview Road Upper Saddle River, NJ 07458 Telephone Numbers and Websites Product Information (800) 523-9299 www.minwax.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS No ingredients in this product are hazardous as defined by the Department of Labor. SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. Page 581 of 1235 Page 581 of 1235 Page 581 of 1235 Page 581 of 1235 ---PAGE BREAK--- 62127 page 2 of 3 During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. PROTECTIVE GLOVES Required for long or repeated contact. EYE PROTECTION Wear safety spectacles with unperforated sideshields. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 8.34 lb/gal 998 g/l SPECIFIC GRAVITY 1.00 BOILING POINT 212 - 213 °F 100 - 100 °C MELTING POINT Not Available VOLATILE VOLUME 99% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available pH 7.1 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.57 lb/gal 68 g/l Less Water and Federally Exempt Solvents 0.00 lb/gal 0 g/l Emitted VOC SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Page 582 of 1235 Page 582 of 1235 Page 582 of 1235 Page 582 of 1235 ---PAGE BREAK--- 62127 page 3 of 3 SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. TOXICOLOGY DATA No LC50 or LD50 data available. SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. IATA/ICAO Not Regulated for Transportation. SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 583 of 1235 Page 583 of 1235 Page 583 of 1235 Page 583 of 1235 ---PAGE BREAK--- page 1 of 3 UEL N.A. LEL N.A. FLASH POINT Not Applicable HMIS Codes Health 0 Flammability 0 Reactivity 0 DATE OF PREPARATION Apr 3, 2010 MATERIAL SAFETY DATA SHEET 62127 02 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER 62127 PRODUCT NAME MINWAX® Hardwood Floor Cleaner MANUFACTURER'S NAME MINWAX Company 10 Mountainview Road Upper Saddle River, NJ 07458 Telephone Numbers and Websites Product Information (800) 523-9299 Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident) * SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS No ingredients in this product are hazardous as defined by the Department of Labor. SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. Page 584 of 1235 Page 584 of 1235 Page 584 of 1235 Page 584 of 1235 ---PAGE BREAK--- 62127 page 2 of 3 SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. PROTECTIVE GLOVES Required for long or repeated contact. EYE PROTECTION Wear safety spectacles with unperforated sideshields. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 8.34 lb/gal 998 g/l SPECIFIC GRAVITY 1.00 BOILING POINT 212 - 213 °F 100 - 100 °C MELTING POINT Not Available VOLATILE VOLUME 99% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.1 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.57 lb/gal 68 g/l Less Water and Federally Exempt Solvents 0.00 lb/gal 0 g/l Emitted VOC SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. Page 585 of 1235 Page 585 of 1235 Page 585 of 1235 Page 585 of 1235 ---PAGE BREAK--- 62127 page 3 of 3 TOXICOLOGY DATA No LC50 or LD50 data available. SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 586 of 1235 Page 586 of 1235 Page 586 of 1235 Page 586 of 1235 ---PAGE BREAK--- MINWAX® Hardwood Floor Cleaner Not available. Liquid. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer : MINWAX Company 10 Mountainview Road Upper Saddle River, NJ 07458 Relevant identified uses of the substance or mixture and uses advised against Not applicable. 62127 62127 Product code : Product Information Telephone Number : (800) 523-9299 Regulatory Information Telephone Number : (216) 566-2902 Transportation Emergency Telephone Number : (800) 424-9300 Section 2. Hazards identification Not classified. Classification of the substance or mixture : Signal word : No signal word. Precautionary statements Prevention : Not applicable. Response : Not applicable. Storage : Not applicable. Disposal Not applicable. GHS label elements General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product. Hazards not otherwise classified :None known. No known significant effects or critical hazards. : Hazard statements Please refer to the SDS for additional information. Do not transfer contents to other containers for storage. Supplemental label elements FOR INDUSTRIAL USE ONLY. Date of issue/Date of revision : 4/6/2015. Date of previous issue : No previous validation. Version : 1 1/9 Page 587 of 1235 Page 587 of 1235 Page 587 of 1235 Page 587 of 1235 ---PAGE BREAK--- Section 3. Composition/information on ingredients There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification : Not available. Substance/mixture CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if occur. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if occur. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if occur. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Description of necessary first aid measures Specific treatments : No specific treatment. Most important acute and delayed Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. : Eye contact Over-exposure Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : No specific data. Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Date of issue/Date of revision : 4/6/2015. Date of previous issue : No previous validation. Version : 1 2/9 Page 588 of 1235 Page 588 of 1235 Page 588 of 1235 Page 588 of 1235 ---PAGE BREAK--- Section 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical No specific data. In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. : Protective measures Put on appropriate personal protective equipment (see Section : Precautions for safe handling Date of issue/Date of revision : 4/6/2015. Date of previous issue : No previous validation. Version : 1 3/9 Page 589 of 1235 Page 589 of 1235 Page 589 of 1235 Page 589 of 1235 ---PAGE BREAK--- Section 7. Handling and storage Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : None. Section 8. Exposure controls/personal protection Hand protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Control parameters Individual protection measures Occupational exposure limits Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Liquid. Not available. Not available. Odor pH Not available. Color 7.1 Not available. Odor threshold : : : : : : Appearance Date of issue/Date of revision : 4/6/2015. Date of previous issue : No previous validation. Version : 1 4/9 Page 590 of 1235 Page 590 of 1235 Page 590 of 1235 Page 590 of 1235 ---PAGE BREAK--- Section 9. Physical and chemical properties Vapor pressure Relative density Vapor density Solubility 1 1 [Air = 1] 0.31 kPa (2.333 mm Hg) [at 20°C] Not available. Evaporation rate 0.09 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: >93.3°C (>199.9°F) Not available. Viscosity Kinematic (room temperature): >0.07 cm2/s cSt) Kinematic (40°C (104°F)): >0.07 cm2/s cSt) Partition coefficient: n- octanol/water : : : : : : : : : Boiling point : 100°C (212°F) Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Decomposition temperature : Not available. Heat of combustion : 0.000000555 kJ/g Aerosol product Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Not available. Carcinogenicity Not available. Mutagenicity Not available. Irritation/Corrosion Not available. Sensitization Not available. Information on toxicological effects Date of issue/Date of revision : 4/6/2015. Date of previous issue : No previous validation. Version : 1 5/9 Page 591 of 1235 Page 591 of 1235 Page 591 of 1235 Page 591 of 1235 ---PAGE BREAK--- Section 11. Toxicological information Teratogenicity Not available. Reproductive toxicity Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Not available. Not available. Aspiration hazard Not available. Not available. Information on the likely routes of exposure Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. : Eye contact No known significant effects or critical hazards. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : No specific data. Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Acute toxicity estimates : Not available. Potential acute health effects Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Date of issue/Date of revision : 4/6/2015. Date of previous issue : No previous validation. Version : 1 6/9 Page 592 of 1235 Page 592 of 1235 Page 592 of 1235 Page 592 of 1235 ---PAGE BREAK--- Not available. Section 12. Ecological information Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Not available. Toxicity Not available. Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Not available. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. : Disposal methods Section 14. Transport information - - - - - - Not regulated. Not regulated. Special provisions Not Applicable Emergency schedules (EmS) Not Applicable DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards No. No. TDG Classification Not regulated. - - - No. Special provisions Not Applicable Mexico Classification Not regulated. - - - No. Special provisions Not Applicable IATA Not regulated. - - - No. Special provisions Not Applicable Date of issue/Date of revision : 4/6/2015. Date of previous issue : No previous validation. Version : 1 7/9 Page 593 of 1235 Page 593 of 1235 Page 593 of 1235 Page 593 of 1235 ---PAGE BREAK--- Section 14. Transport information Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Not available. : Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. Section 15. Regulatory information U.S. Federal regulations : State regulations Section 16. Other information It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all Notice to reader Hazardous Material Information System 0 0 0 Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Date of issue/Date of revision : 4/6/2015. Date of previous issue : No previous validation. Version : 1 8/9 Page 594 of 1235 Page 594 of 1235 Page 594 of 1235 Page 594 of 1235 ---PAGE BREAK--- Section 16. Other information country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Date of issue/Date of revision : 4/6/2015. Date of previous issue : No previous validation. Version : 1 9/9 Page 595 of 1235 Page 595 of 1235 Page 595 of 1235 Page 595 of 1235 ---PAGE BREAK--- page 1 of 3 UEL N.A. LEL N.A. FLASH POINT Not Applicable HMIS Codes Health 0 Flammability 0 Reactivity 0 DATE OF PREPARATION Nov 17, 2011 MATERIAL SAFETY DATA SHEET 62127 03 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER 62127 PRODUCT NAME MINWAX® Hardwood Floor Cleaner MANUFACTURER'S NAME MINWAX Company 10 Mountainview Road Upper Saddle River, NJ 07458 Telephone Numbers and Websites Product Information (800) 523-9299 Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident) * SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS No ingredients in this product are hazardous as defined by the Department of Labor. SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. Page 596 of 1235 Page 596 of 1235 Page 596 of 1235 Page 596 of 1235 ---PAGE BREAK--- 62127 page 2 of 3 SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. PROTECTIVE GLOVES Required for long or repeated contact. EYE PROTECTION Wear safety spectacles with unperforated sideshields. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 8.34 lb/gal 998 g/l SPECIFIC GRAVITY 1.00 BOILING POINT 212 - 213 °F 100 - 100 °C MELTING POINT Not Available VOLATILE VOLUME 99% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.1 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.57 lb/gal 68 g/l Less Water and Federally Exempt Solvents 0.00 lb/gal 0 g/l Emitted VOC SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. Page 597 of 1235 Page 597 of 1235 Page 597 of 1235 Page 597 of 1235 ---PAGE BREAK--- 62127 page 3 of 3 TOXICOLOGY DATA No LC50 or LD50 data available. SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. IATA/ICAO Not Regulated for Transportation. SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 598 of 1235 Page 598 of 1235 Page 598 of 1235 Page 598 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET 6096 02 00 Section 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DATE OF PREPARATION HMIS CODES Health 2 6096 29-SEP-07 Flammability 0 Reactivity 0 PRODUCT NAME MINWAX® Hardwood Floor REVIVER, Low Gloss MANUFACTURER'S NAME MINWAX 200 Confederation Pkwy Vaughan, ON L4K 4T8 TELEPHONE NUMBERS and WEBSITES Product Information (800) 523-9299 Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency for Chemical Emergency ONLY (spill, leak, (800) 424-9300 fire, exposure, or accident) Section 2 COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE 1 29911-28-2 1-(2-Butoxymethylethoxy)-propanol ACGIH TLV Not Available 0.06 mm OSHA PEL Not Available 3 5131-66-8 Butoxypropanol ACGIH TLV Not Available 0.6 mm OSHA PEL Not Available 2 107-21-1 Ethylene Glycol ACGIH TLV 100 mg/m3 CEILI (aerosol) 0.12 mm OSHA PEL 50 ppm CEILING 1 9014-85-1 Decylpoly(ethyleneoxy)ethanol ACGIH TLV Not Available OSHA PEL Not Available 1 872-50-4 1-Methyl-2-Pyrrolidone ACGIH TLV Not Available 1 mm OSHA PEL Not Available Section 3 HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. Continued on page 2 Page 599 of 1235 Page 599 of 1235 Page 599 of 1235 Page 599 of 1235 ---PAGE BREAK--- 6096 page 2 EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver and urinary systems. SIGNS AND OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Section 4 FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. Section 5 FIRE FIGHTING MEASURES FLASH POINT LEL UEL >200 F PMCC N.A. N.A. FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Continued on page 3 Page 600 of 1235 Page 600 of 1235 Page 600 of 1235 Page 600 of 1235 ---PAGE BREAK--- 6096 page 3 Section 7 HANDLING AND STORAGE STORAGE CATEGORY DOL Storage Class IIIB PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. Continued on page 4 Page 601 of 1235 Page 601 of 1235 Page 601 of 1235 Page 601 of 1235 ---PAGE BREAK--- 6096 page 4 Section 9 PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 8.50 lb/gal 1017 g/l SPECIFIC GRAVITY 1.02 BOILING POINT 212 - 449 F 100 - 231 C MELTING POINT Not Available VOLATILE VOLUME 76 % EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 8.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 2.20 lb/gal 263 g/l Less Water and Federally Exempt Solvents 0.71 lb/gal 85 g/l Emitted VOC Section 10 STABILITY AND REACTIVITY STABILITY Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Section 11 TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. Ethylene Glycol is considered an animal teratogen. It has been shown to cause birth defects in rats and mice at high doses when given in drinking water or by gavage. There is no evidence to indicate it causes birth defects in humans. TOXICOLOGY DATA CAS No. Ingredient Name 29911-28-2 1-(2-Butoxymethylethoxy)-propanol LC50 RAT 4HR Not Available LD50 RAT Not Available 5131-66-8 Butoxypropanol LC50 RAT 4HR Not Available LD50 RAT 1900 mg/kg 107-21-1 Ethylene Glycol LC50 RAT 4HR Not Available LD50 RAT 4700 mg/kg 9014-85-1 Decylpoly(ethyleneoxy)ethanol LC50 RAT 4HR Not Available LD50 RAT Not Available 872-50-4 1-Methyl-2-Pyrrolidone LC50 RAT 4HR Not Available LD50 RAT 4200 mg/kg Continued on page 5 Page 602 of 1235 Page 602 of 1235 Page 602 of 1235 Page 602 of 1235 ---PAGE BREAK--- 6096 page 5 Section 12 ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Section 13 DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Section 14 TRANSPORT INFORMATION US Ground (DOT) Not Regulated for Transportation. DOT (Dept of Transportation) Hazardous Substances & Reportable Quantities Di-n-butyl phthalate 10 lb RQ Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. Section 15 REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element 107-21-1 Ethylene Glycol 2 872-50-4 1-Methyl-2-Pyrrolidone 1 TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Section 16 OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 603 of 1235 Page 603 of 1235 Page 603 of 1235 Page 603 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SECTION I – MATERIAL IDENTIFICATION AND USE MATERIAL NAME: MIRACLE GLASS CLEANER MANUFACTURERS NAME: SUPPLIERS NAME: CP INDUSTRIES LTD. CP INDUSTRIES LTD. P.O. BOX 300, 535 DICKSON DR., P.O. BOX 300, 535 DICKSON DR., FERGUS, ONTARIO N1M 2W8 FERGUS, ONTARIO N1M 2W8 EMERGENCY TELEPHONE NUMBER: (613) 996-6666 EMERGENCY TELEPHONE NUMBER: (613) 996-6666 Non-Office Hours, Weekends, or Holidays – (CANUTEC) Call Collect Non-Office Hours, Weekends, or Holidays – (CANUTEC) Call Collect CHEMICAL NAME CHEMICAL FAMILY CHEMICAL FORMULA WHMIS CLASS Not Applicable Dilute Solvent Solution Not Applicable D2B MOLECULAR WEIGHT TRADE NAME AND SYNONYMS MATERIAL USE Not Applicable Not Available Glass, Mirror and Window Cleaner SECTION II – HAZARDOUS INGREDIENTS OF MATERIAL HAZARDOUS INGREDIENTS APPROXIMATE C.A.S.N.A. “EXPOSURE LIMITS” LD50 / LC50 CONCENTRATION % SPECIFY SPECIES & ROUTE Isopropanol 1 - 2 67-63-0 TLV 400 ppm LD50 5045 mg/kg (oral/rat) 2-Butoxyethanol 1 – 2 111-76-2 TLV (ACGIH) 25 ppm LD50 470 mg/kg (oral/rat) (TWA-skin) SECTION III – PHYSICAL DATA FOR MATERIAL PHYSICAL STATE ODOUR AND APPEARANCE ODOUR THRESHOLD SPECIFIC GRAVITY GAS LIQUID X SOLID Clear Light Blue Liquid Not Available 1.0 VAPOUR PRESSURE (mm) VAPOUR DENSITY (Air=1) EVAPORATION RATE BOILING POINT Not Available Not Available Not Available 100°C approx. FREEZING POINT SOLUBILITY IN WATER % VOLATILE (by volume) pH 0°C approx. Complete 99% approx. 10.5 COEFFICIENT OF WATER/OIL DISTRIBUTION: Not Available SECTION IV – FIRE AND EXPLOSION DATA FLAMMABILITY IF YES, UNDER WHAT CONDITIONS YES NO X MEANS OF EXTINCTION: As for surrounding fire SPECIAL PROCEDURES: Wear protective clothing. FLASH POINT AND METHOD: None AUTO IGNITION TEMPERATURE Not Applicable UPPER EXPLOSION LIMIT BY VOLUME): Not Applicable LOWER EXPLOSION LIMIT BY VOLUME): Not Applicable HAZARDOUS COMBUSTION PRODUCTS: Oxides of carbon EXPLOSION DATA SENSITIVITY TO MECHANICAL IMPACT: Not Applicable RATE OF BURNING EXPLOSIVE POWER SENSITIVITY TO STATIC DISCHARGE Not Applicable Not Applicable Not Applicable SECTION V – REACTIVITY DATA CHEMICAL STABILITY IF NO, UNDER WHAT CONDITIONS? YES X NO INCOMPATIBILITY TO OTHER SUBSTANCES IF SO, WHICH ONES? YES NO X REACTIVITY AND UNDER WHAT CONDITIONS: Not dangerously reactive HAZARDOUS DECOMPOSITION PRODUCTS: Not Applicable Page 604 of 1235 Page 604 of 1235 Page 604 of 1235 Page 604 of 1235 ---PAGE BREAK--- MATERIAL NAME: MIRACLE GLASS CLEANER SECTION VI – TOXICOLOGICAL PROPERTIES OF PRODUCT ROUTE OF ENTRY SKIN CONTACT: X SKIN ABSORPTION: X EYE CONTACT: X INHALATION ACUTE: X INHALATION CHRONIC: INGESTION: X EFFECTS OF ACUTE EXPOSURE TO PRODUCT EYE: May cause irritation. May cause temporary or permanent damage if not treated SKIN: May cause irritation. May be absorbed through skin. INHALATION: Inhalation of mist or spray may cause irritation. INGESTION: May cause irritation to digestive tract. EFFECTS OF CHRONIC EXPOSURE TO PRODUCT: None known LD50 OF PRODUCT (SPECIFY SPECIES & ROUTE) IRRITANCY OF PRODUCT EXPOSURE LIMITS OF PRODUCT 43,290 mg/kg (oral/rat) (calculated) Low Not Available LC50 OF PRODUCT (SPECIFY SPECIES) SENSITIZATION TO PRODUCT SYNERGISTIC MATERIALS Not Available Not Available Not Applicable CARCINOGENICITY REPRODUCTIVE EFFECTS TERATOGENICITY MUTAGENICITY Not Applicable Not Available Not Available Not Available SECTION VII – PREVENTATIVE MEASURES PERSONAL PROTECTIVE EQUIPMENT GLOVES RESPIRATORY (SPECIFY) EYE (SPECIFY) Rubber Not normally required Safety Glasses if risk of contact FOOTWEAR (SPECIFY) CLOTHING (SPECIFY) OTHER (SPECIFY) Not Applicable Not Applicable Not Applicable ENGINEERING CONTROLS (E.G. VENTILATION, ENCLOSED PROCESS, (SPECIFY): General ventilation adequate. LEAK AND SPILL PROCEDURE: Mop up or soak up with absorbent material for disposal. WASTE DISPOSAL: Dispose of according to local, provincial, and federal regulations. HANDLING PROCEDURES & EQUIPMENT: No special requirements. STORAGE REQUIREMENTS: Store in a cool, dry place in a closed container. SPECIAL SHIPPING INFORMATION: Not Applicable. SECTION VIII – FIRST AID PROCEDURES SKIN: Wash with soap and water. EYE: Flush eyes with water for at least 15 minutes. If irritation persists, seek medical attention immediately. INHALATION: Remove patient to fresh air. INGESTION: DO NOT induce vomiting. Seek medical attention. GENERAL ADVICE: None SECTION IX - PREPARATION DATE OF MSDS ADDITIONAL INFORMATION/COMMENTS: None SOURCES USED: Supplier MSDS PREPARED BY: CP INDUSTRIES LTD. PHONE NUMBER: (519) 843-6300 DATE: January 1, 2010 DEVELOPMENT DEPT. INSTITUTIONAL DIVISION Page 605 of 1235 Page 605 of 1235 Page 605 of 1235 Page 605 of 1235 ---PAGE BREAK--- Page 606 of 1235 Page 606 of 1235 Page 606 of 1235 Page 606 of 1235 ---PAGE BREAK--- Page 607 of 1235 Page 607 of 1235 Page 607 of 1235 Page 607 of 1235 ---PAGE BREAK--- Page 608 of 1235 Page 608 of 1235 Page 608 of 1235 Page 608 of 1235 ---PAGE BREAK--- Page 609 of 1235 Page 609 of 1235 Page 609 of 1235 Page 609 of 1235 ---PAGE BREAK--- Page 610 of 1235 Page 610 of 1235 Page 610 of 1235 Page 610 of 1235 ---PAGE BREAK--- Page 611 of 1235 Page 611 of 1235 Page 611 of 1235 Page 611 of 1235 ---PAGE BREAK--- Page 612 of 1235 Page 612 of 1235 Page 612 of 1235 Page 612 of 1235 ---PAGE BREAK--- Page 613 of 1235 Page 613 of 1235 Page 613 of 1235 Page 613 of 1235 ---PAGE BREAK--- Page 614 of 1235 Page 614 of 1235 Page 614 of 1235 Page 614 of 1235 ---PAGE BREAK--- 440461-00 MOBIL DELVAC 1300 SUPER 10W-30 MATERIAL SAFETY DATA BULLETIN 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: MOBIL DELVAC 1300 SUPER 10W-30 SUPPLIER: MOBIL OIL CORP. NORTH AMERICA MARKETING AND REFINING 3225 GALLOWS RD. FAIRFAX, VA 22037 24 - Hour Emergency (call collect): [PHONE REDACTED] Product and MSDS Information: [PHONE REDACTED] [PHONE REDACTED] CHEMTREC: [PHONE REDACTED] [PHONE REDACTED] 2. COMPOSITION/INFORMATION ON INGREDIENTS CHEMICAL NAMES AND SYNONYMS: SEVERE TREAT MIN. OILS & ADDITIVES INGREDIENTS CONSIDERED HAZARDOUS TO HEALTH: This product is not formulated to contain ingredients which have exposure limits established by U.S. agencies. It is not hazardous to health as defined by the European Union Dangerous Substances/Preparations Directives. See Section 15 for a regulatory analysis of the ingredients. See Section 15 for European Label Information. See Section 8 for exposure limits (if applicable). 3. HAZARDS IDENTIFICATION US OSHA HAZARD COMMUNICATION STANDARD: Product assessed in accordance with OSHA 29 CFR 1910.1200 and determined not to be hazardous. EFFECTS OF OVEREXPOSURE: No significant effects expected. EMERGENCY RESPONSE DATA: Brown Liquid. DOT ERG No. - NA 4. FIRST AID MEASURES EYE CONTACT: Flush thoroughly with water. If irritation occurs, call a physician. SKIN CONTACT: Wash contact areas with soap and water. INHALATION: Not expected to be a problem. INGESTION: Not expected to be a problem. However, if greater than 1/2 liter(pint) ingested, immediately give 1 to 2 glasses of water and call a physician, hospital emergency room or poison control center for assistance. Do not induce vomiting or give anything by mouth to an unconscious person. 5. FIRE-FIGHTING MEASURES Page 615 of 1235 Page 615 of 1235 Page 615 of 1235 Page 615 of 1235 ---PAGE BREAK--- EXTINGUISHING MEDIA: Carbon dioxide, foam, dry chemical and water fog. SPECIAL FIRE FIGHTING PROCEDURES: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposure. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. SPECIAL PROTECTIVE EQUIPMENT: For fires in enclosed areas, fire fighters must use self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS: None. Flash Point C(F): > 206(403) (ASTM D-92). Flammable limits - LEL: NA, UEL: NA. NFPA HAZARD ID: Health: 0, Flammability: 1, Reactivity: 0 HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide. Metal oxides. Elemental oxides. 6. ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES: Report spills as required to appropriate authorities. U. S. Coast Guard regulations require immediate reporting of spills that could reach any waterway including intermittent dry creeks. Report spill to Coast Guard toll free number (800) 424-8802. In case of accident or road spill notify CHEMTREC (800) 424-9300. PROCEDURES IF MATERIAL IS RELEASED OR SPILLED: Adsorb on fire retardant treated sawdust, diatomaceous earth, etc. Shovel up and dispose of at an appropriate waste disposal facility in accordance with current applicable laws and regulations, and product characteristics at time of disposal. ENVIRONMENTAL PRECAUTIONS: Prevent spills from entering storm sewers or drains and contact with soil. PERSONAL PRECAUTIONS: See Section 8 7. HANDLING AND STORAGE HANDLING: No special precautions are necessary beyond normal good hygiene practices. See Section 8 for additional personal protection advice when handling this product. STORAGE: Do not store in open or unlabelled containers. Store away from strong oxidizing agents or combustible material. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION VENTILATION: No special requirements under ordinary conditions of use and with adequate ventilation. RESPIRATORY PROTECTION: No special requirements under ordinary conditions of use and with adequate ventilation. EYE PROTECTION: Normal industrial eye protection practices should be employed. SKIN PROTECTION: No special equipment required. However, good personal hygiene practices should always be followed. EXPOSURE LIMITS: This product does not contain any components which have recognized exposure limits. However, a exposure limit of 5.00 mg/m3 is suggested for oil mist. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 616 of 1235 Page 616 of 1235 Page 616 of 1235 Page 616 of 1235 ---PAGE BREAK--- Typical physical properties are given below. Consult Product Data Sheet for specific details. APPEARANCE: Liquid COLOR: Brown ODOR: Mild ODOR THRESHOLD-ppm: NE pH: NA BOILING POINT C(F): > 316(600) MELTING POINT C(F): NA FLASH POINT C(F): > 206(403) (ASTM D-92) FLAMMABILITY: NE AUTO FLAMMABILITY: NE EXPLOSIVE PROPERTIES: NA OXIDIZING PROPERTIES: NA VAPOR PRESSURE-mmHg 20 C: < 0.1 VAPOR DENSITY: NE EVAPORATION RATE: NE RELATIVE DENSITY, 15/4 C: 0.882 SOLUBILITY IN WATER: Negligible PARTITION COEFFICIENT: > 3.5 VISCOSITY AT 40 C, cSt: 73.0 VISCOSITY AT 100 C, cSt: 11.0 POUR POINT C(F): > -27(-17) FREEZING POINT C(F): NE VOC: < 3.00 (Wt. 0.220 lbs/gal NA=NOT APPLICABLE NE=NOT ESTABLISHED D=DECOMPOSES FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING REPRESENTATIVE 10. STABILITY AND REACTIVITY STABILITY (THERMAL, LIGHT, ETC.): Stable. CONDITIONS TO AVOID: Extreme heat. INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide. Metal oxides. Elemental oxides. HAZARDOUS POLYMERIZATION: Will not occur. 11. TOXICOLOGICAL DATA ---ACUTE TOXICOLOGY--- ORAL TOXICITY (RATS): Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. DERMAL TOXICITY (RABBITS): Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. INHALATION TOXICITY (RATS): Practically non-toxic (LC50: greater than 5 mg/l). ---Based on testing of similar products and/or the components. EYE IRRITATION (RABBITS): Practically non-irritating. (Draize score: greater than 6 but 15 or less). ---Based on testing of similar products and/or the components. SKIN IRRITATION (RABBITS): Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than ---Based on testing of similar products and/or the components. ---SUBCHRONIC TOXICOLOGY (SUMMARY)--- Severely solvent refined and severely hydrotreated mineral base oils Page 617 of 1235 Page 617 of 1235 Page 617 of 1235 Page 617 of 1235 ---PAGE BREAK--- have been tested at Mobil Environmental and Health Sciences Laboratory by dermal application to rats 5 days/week for 90 days at doses significantly higher than those expected during normal industrial exposure. Extensive evaluations including microscopic examination of internal organs and clinical chemistry of body fluids, showed no adverse effects. ---CHRONIC TOXICOLOGY (SUMMARY)--- The base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic mouse skin painting studies of severely treated oils showed no evidence of carcinogenic effects. These results are confirmed on a continuing basis using various screening methods such as the Mobil Modified Ames Test and IP-346. ---OTHER TOXICOLOGY DATA--- Used gasoline engine oils have shown evidence of skin carcinogenic activity in laboratory tests when no effort was made to wash the oil off between applications. Used oil from diesel engines did not produce this effect. 12. ECOLOGICAL INFORMATION ENVIRONMENTAL FATE AND EFFECTS: Not established. 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Product is suitable for burning in an enclosed, controlled burner for fuel value or disposal by supervised incineration. Such burning may be limited pursuant to the Resource Conservation and Recovery Act. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of at an appropriate government waste disposal facility. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. RCRA INFORMATION: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrosivity, or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. 14. TRANSPORT INFORMATION USA DOT: NOT REGULATED BY USA DOT. RID/ADR: NOT REGULATED BY RID/ADR. IMO: NOT REGULATED BY IMO. IATA: NOT REGULATED BY IATA. 15. REGULATORY INFORMATION Governmental Inventory Status: All components comply with TSCA, EINECS/ELINCS, and MITI. Page 618 of 1235 Page 618 of 1235 Page 618 of 1235 Page 618 of 1235 ---PAGE BREAK--- EU Labeling: EU labeling not required. U.S. Superfund Amendments and Reauthorization Act (SARA) Title III: This product contains no "EXTREMELY HAZARDOUS SUBSTANCES". SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. This product contains the following SARA (313) Toxic Release Chemicals: CHEMICAL NAME CAS NUMBER CONC. ZINC DITHIOPHOSPHATE 68649-42-3 1.69% The following product ingredients are cited on the lists below: CHEMICAL NAME CAS NUMBER LIST CITATIONS NAPHTHALENE (COMPONENT ANALYSIS) 91-20-3 22 STYRENE MONOMER (COMPONENT 100-42-5 22 ANALYSIS) (0.02%) PHENOL (COMPONENT ANALYSIS) 108-95-2 22 XYLENES (COMPONENT ANALYSIS) 1330-20-7 22 ZINC (ELEMENTAL ANALYSIS) (0.14%) 7440-66-6 22 CHLORINE (ELEMENTAL ANALYSIS) 7782-50-5 22 (0.29%) ZINC DITHIOPHOSPHATE 68649-42-3 18, 21, 24 REGULATORY LISTS SEARCHED 1=ACGIH ALL 6=IARC 1 11=TSCA 4 16=CA P65 CARC 21=LA RTK 2=ACGIH A1 7=IARC 2A 12=TSCA 5a2 17=CA P65 REPRO 22=MI 293 3=ACGIH A2 8=IARC 2B 13=TSCA 5e 18=CA RTK 23=MN RTK 4=NTP CARC 9=OSHA CARC 14=TSCA 6 19=FL RTK 24=NJ RTK 5=NTP SUS 10=OSHA Z 15=TSCA 12b 20=IL RTK 25=PA RTK 26=RI RTK Code key: CARC=Carcinogen; SUS=Suspected Carcinogen; REPRO=Reproductive 16. OTHER INFORMATION USE: COMMERCIAL ENGINE OIL NOTE: MOBIL PRODUCTS ARE NOT FORMULATED TO CONTAIN PCBS. Please call the Customer Response Center on [PHONE REDACTED] for formulation disclosure. For Internal Use Only: MHC: 1* 1* 0* 1* MPPEC: A, TRN: 440461-00, CMCS97: 971601, REQ: US - MARKETING, SAFE USE: L EHS Approval Date: 02APR1999 Legally required information is given in accordance with applicable Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for particular uses are beyond our control; all risks of use of the product are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO THE USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a recommendation for uses which infringe valid patents or as extending any license under valid patents. Appropiate warnings and safe handling procedures should be providedto handlers and users. Use or re- transmission of the information contained herein in any other format than the format as presented is strictly prohibited. Mobil neither Page 619 of 1235 Page 619 of 1235 Page 619 of 1235 Page 619 of 1235 ---PAGE BREAK--- represents nor warrants that the format, content or product formulas contained in this document comply with the laws of any other country except the United States of America. Copyright 1996 Mobil Corporation, All rights reserved Page 620 of 1235 Page 620 of 1235 Page 620 of 1235 Page 620 of 1235 ---PAGE BREAK--- 440461-00 MOBIL DELVAC 1300 SUPER 10W-30 MATERIAL SAFETY DATA BULLETIN 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: MOBIL DELVAC 1300 SUPER 10W-30 SUPPLIER: EXXONMOBIL CORPORATION 3225 GALLOWS RD. FAIRFAX, VA 22037 24 - Hour Health and Safety Emergency (call collect): [PHONE REDACTED] 24 - Hour Transportation Emergency: CHEMTREC: [PHONE REDACTED] [PHONE REDACTED] LUBES AND FUELS: [PHONE REDACTED] Product and Technical Information: Lubricants and Specialties: [PHONE REDACTED] [PHONE REDACTED] Fuels Products: [PHONE REDACTED] MSDS Fax on Demand: [PHONE REDACTED] MSDS Internet Website: 2. COMPOSITION/INFORMATION ON INGREDIENTS CHEMICAL NAMES AND SYNONYMS: SEVERE TREAT MIN. OILS & ADDITIVES GLOBALLY REPORTABLE MSDS INGREDIENTS: Substance Name Approx. Wt% ZINC DITHIOPHOSPHATE 1-5 (68649-42-3) See Section 8 for exposure limits (if applicable). 3. HAZARDS IDENTIFICATION Under normal conditions of use, this product is not considered hazardous according to regulatory guidelines (See section 15). EMERGENCY OVERVIEW: Brown Liquid. DOT ERG No. : NA POTENTIAL HEALTH EFFECTS: Under normal conditions of intended use, this product does not pose a risk to health. Excessive exposure may result in eye, skin or respiratory irritation. For further health effects/toxicological data, see Section 11. 4. FIRST AID MEASURES EYE CONTACT: Flush thoroughly with water. If irritation occurs, call a physician. SKIN CONTACT: Wash contact areas with soap and water. Remove and clean oil soaked clothing daily and wash affected area. (See Section 16 - Injection Injury) INHALATION: Not expected to be a problem. However, if respiratory Page 1 of 7 04/21/2003 Page 621 of 1235 Page 621 of 1235 Page 621 of 1235 Page 621 of 1235 ---PAGE BREAK--- irritation, dizziness, nausea, or unconsciousness occurs due to excessive vapor or mist exposure, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or mouth-to-mouth resuscitation. INGESTION: Not expected to be a problem. Seek medical attention if discomfort occurs. Do not induce vomiting. 5. FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA: Carbon dioxide, foam, dry chemical and water fog. SPECIAL FIRE FIGHTING PROCEDURES: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposure. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. SPECIAL PROTECTIVE EQUIPMENT: For fires in enclosed areas, fire fighters must use self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS: None. COMBUSTION PRODUCTS: Fumes, smoke, carbon monoxide, sulfur oxides, aldehydes and other decomposition products, in the case of incomplete combustion. Flash Point C(F): 245(473) (ASTM D-92). Flammable Limits (approx.% vol.in air) - LEL: 0.9%, UEL: 7.0% NFPA HAZARD ID: Health: 0, Flammability: 1, Reactivity: 0 6. ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES: Report spills/releases as required to appropriate authorities. U.S. Coast Guard and EPA regulations require immediate reporting of spills/releases that could reach any waterway including intermittent dry creeks. Report spill/release to Coast Guard National Response Center toll free number (800)424-8802. In case of accident or road spill notify CHEMTREC (800) 424-9300. PROCEDURES IF MATERIAL IS RELEASED OR SPILLED: LAND SPILL: Shut off source taking normal safety precautions. Take measures to minimize the effects on ground water. Recover by pumping or contain spilled material with sand or other suitable absorbent and remove mechanically into containers. If necessary, dispose of adsorbed residues as directed in Section 13. WATER SPILL: Confine the spill immediately with booms. Warn other ships in the vicinity. Notify port and other relevant authorities. Remove from the surface by skimming or with suitable absorbents. If permitted by regulatory authorities the use of suitable dispersants should be considered where recommended in local oil spill procedures. ENVIRONMENTAL PRECAUTIONS: Prevent material from entering sewers, water sources or low lying areas; advise the relevant authorities if it has, or if it contaminates soil/vegetation. PERSONAL PRECAUTIONS: See Section 8 7. HANDLING AND STORAGE HANDLING: No special precautions are necessary beyond normal good Page 2 of 7 04/21/2003 Page 622 of 1235 Page 622 of 1235 Page 622 of 1235 Page 622 of 1235 ---PAGE BREAK--- hygiene practices. See Section 8 for additional personal protection advice when handling this product. STORAGE: Keep containers closed when not in use. Do not store in open or unlabelled containers. Store away from strong oxidizing agents and combustible materials. Do not store near heat, sparks, flame or strong oxidants. SPECIAL PRECAUTIONS: Prevent small spills and leakages to avoid slip hazard. EMPTY CONTAINER WARNING: Empty containers retain residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or clean container since residue is difficult to remove. Empty drums should be completely drained, properly bunged and returned to a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS: When mists/aerosols can occur, the following are recommended: 5 mg/m3 (as oil mist)- ACGIH Threshold Limit Value (TLV), 10 mg/m3 (as oil mist) - ACGIH Short Term Exposure Limit (STEL), 5 mg/m3 (as oil mist) - OSHA Permissible Exposure Limit (PEL) VENTILATION: If mists are generated, use adequate ventilation, local exhaust or enclosures to control below exposure limits. RESPIRATORY PROTECTION: If mists are generated, and/or when ventilation is not adequate, wear approved respirator. EYE PROTECTION: If eye contact is likely, safety glasses with side shields or chemical type goggles should be worn. SKIN PROTECTION: Not normally required. When splashing or liquid contact can occur frequently, wear oil resistant gloves and/or other protective clothing. Good personal hygiene practices should always be followed. 9. PHYSICAL AND CHEMICAL PROPERTIES Typical physical properties are given below. Consult Product Data Sheet for specific details. APPEARANCE: Liquid COLOR: Brown ODOR: Mild ODOR THRESHOLD-ppm: NE pH: NA BOILING POINT C(F): > 316(600) MELTING POINT C(F): NA FLASH POINT C(F): 245(473) (ASTM D-92) FLAMMABILITY (solids): NE AUTO FLAMMABILITY C(F): NA EXPLOSIVE PROPERTIES: NA OXIDIZING PROPERTIES: NA VAPOR PRESSURE-mmHg 20 C: NE VAPOR DENSITY: NE EVAPORATION RATE: NE Page 3 of 7 04/21/2003 Page 623 of 1235 Page 623 of 1235 Page 623 of 1235 Page 623 of 1235 ---PAGE BREAK--- RELATIVE DENSITY, 15/4 C: 0.866 SOLUBILITY IN WATER: Negligible PARTITION COEFFICIENT: > 3.5 VISCOSITY AT 40 C, cSt: 74.0 VISCOSITY AT 100 C, cSt: 11.5 POUR POINT C(F): -30(-22) FREEZING POINT C(F): NE VOC: < 3.00 (Wt. 0.220 lbs/gal DMSO EXTRACT, IP-346 for mineral oil only NA=NOT APPLICABLE NE=NOT ESTABLISHED D=DECOMPOSES FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING REPRESENTATIVE 10. STABILITY AND REACTIVITY STABILITY (THERMAL, LIGHT, ETC.): Stable. CONDITIONS TO AVOID: Extreme heat and high energy sources of ignition. INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS: Product does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. 11. TOXICOLOGICAL DATA ---ACUTE TOXICOLOGY--- ORAL TOXICITY (RATS): Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. DERMAL TOXICITY (RABBITS): Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. INHALATION TOXICITY (RATS): Practically non-toxic (LC50: greater than 5 mg/l). ---Based on testing of similar products and/or the components. EYE IRRITATION (RABBITS): Practically non-irritating. (Draize score: greater than 6 but 15 or less). ---Based on testing of similar products and/or the components. SKIN IRRITATION (RABBITS): Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than ---Based on testing of similar products and/or the components. OTHER ACUTE TOXICITY DATA: Although an acute inhalation study was not performed with this product, a variety of mineral and oils, such as those in this product, have been tested. These samples had virtually no effect other than a nonspecific inflammatory response in the lung to the aerosolized mineral oil. The presence of additives in other tested formulations (in approximately the same amounts as in the present formulation) did not alter the observed effects. ---SUBCHRONIC TOXICOLOGY (SUMMARY)--- No significant adverse effects were found in studies using repeated dermal applications of similar formulations to the skin of laboratory animals for 13 weeks at doses significantly higher than those expected during normal industrial exposure. The animals were evaluated extensively for effects of exposure (hematology, serum chemistry, urinalysis, organ weights, microscopic examination of tissues etc.). ---REPRODUCTIVE TOXICOLOGY (SUMMARY)--- Page 4 of 7 04/21/2003 Page 624 of 1235 Page 624 of 1235 Page 624 of 1235 Page 624 of 1235 ---PAGE BREAK--- No teratogenic effects would be expected from dermal exposure, based on laboratory developmental toxicity studies of major components in this formulation and/or materials of similar composition. ---CHRONIC TOXICOLOGY (SUMMARY)--- Repeated and/or prolonged exposure may cause irritation to the skin, eyes or respiratory tract. Overexposure to oil mist may result in oil droplet deposition and/or granuloma formation. For mineral base oils: Base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic mouse skin painting studies of severely treated oils showed no evidence of carcinogenic effects. These results are confirmed on a continuing basis using various screening methods such as Modified Ames Test, IP-346, and/or other analytical methods. For base oils: The base oils in this product have been tested in the Ames assay and other tests of mutagenicity with negative results. These base oils are not expected to be carcinogenic with chronic dermal exposures. ---SENSITIZATION (SUMMARY)--- Not expected to be sensitizing based on tests of this product, components, or similar products. ---OTHER TOXICOLOGY DATA--- Used gasoline engine oils have shown evidence of skin carcinogenic activity in laboratory tests when no effort was made to wash the oil off between applications. Used oil from diesel engines did not produce this effect. 12. ECOLOGICAL INFORMATION ENVIRONMENTAL FATE AND EFFECTS: In the absence of specific environmental data for this product, this assessment is based on information for representative products. ECOTOXICITY: Available ectoxicity data (LL50 >1000 mg/L) indicates that adverse effects to aquatic organisms are not expected from this product. MOBILITY: When released into the environment, adsorption to sediment and soil will be the predominant behavior. PERSISTENCE AND DEGRADABILITY: This product is expected to be inherently biodegradable. BIOACCUMULATIVE POTENTIAL: Bioaccumulation is unlikely due to the very low water solubility of this product, therefore bioavailability to aquatic organisms is minimal. 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Product is suitable for burning in an enclosed, controlled burner for fuel value. Such burning may be limited pursuant to the Resource Conservation and Recovery Act. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of at an appropriate government waste disposal facility. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. RCRA INFORMATION: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed hazardous wastes. It does not exhibit the hazardous Page 5 of 7 04/21/2003 Page 625 of 1235 Page 625 of 1235 Page 625 of 1235 Page 625 of 1235 ---PAGE BREAK--- characteristics of ignitability, corrosivity, or reactivity. The unused product is not formulated with substances covered by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. 14. TRANSPORT INFORMATION USA DOT: NOT REGULATED BY USA DOT. RID/ADR: NOT REGULATED BY RID/ADR. IMO: NOT REGULATED BY IMO. IATA: NOT REGULATED BY IATA. STATIC ACCUMULATOR (50 picosiemens or less): YES 15. REGULATORY INFORMATION US OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this product is not classified as hazardous in accordance with OSHA 29 CFR 1910.1200. EU Labeling: Product is not dangerous as defined by the European Union Dangerous Substances/Preparations Directives. EU labeling not required. Governmental Inventory Status: All components comply with TSCA, EINECS/ELINCS, AICS, METI, DSL, KOREA, and PHILIPPINES. U.S. Superfund Amendments and Reauthorization Act (SARA) Title III: This product contains no "EXTREMELY HAZARDOUS SUBSTANCES". SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. This product contains the following SARA (313) Toxic Release Chemicals: CHEMICAL NAME CAS NUMBER CONC. ZINC DITHIOPHOSPHATE 68649-42-3 The following product ingredients are cited on the lists below: CHEMICAL NAME CAS NUMBER LIST CITATIONS ZINC (ELEMENTAL ANALYSIS) (0.15%) 7440-66-6 22 ZINC DITHIOPHOSPHATE 68649-42-3 18, 21, 24 REGULATORY LISTS SEARCHED 1=ACGIH ALL 6=IARC 1 11=TSCA 4 16=CA P65 CARC 21=LA RTK 2=ACGIH A1 7=IARC 2A 12=TSCA 5a2 17=CA P65 REPRO 22=MI 293 3=ACGIH A2 8=IARC 2B 13=TSCA 5e 18=CA RTK 23=MN RTK 4=NTP CARC 9=OSHA CARC 14=TSCA 6 19=FL RTK 24=NJ RTK 5=NTP SUS 10=OSHA Z 15=TSCA 12b 20=IL RTK 25=PA RTK 26=RI RTK Code key: CARC=Carcinogen; SUS=Suspected Carcinogen; REPRO=Reproductive 16. OTHER INFORMATION USE: COMMERCIAL ENGINE OIL NOTE: PRODUCTS OF EXXON MOBIL CORPORATION AND ITS AFFILIATED COMPANIES ARE NOT FORMULATED TO CONTAIN PCBS. Health studies have shown that many hydrocarbons pose potential human health risks which may vary from person to person. Information provided on this MSDS reflects intended use. This product should not be used for other applications. In any case, the following advice should be Page 6 of 7 04/21/2003 Page 626 of 1235 Page 626 of 1235 Page 626 of 1235 Page 626 of 1235 ---PAGE BREAK--- considered: INJECTION INJURY WARNING: If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. INDUSTRIAL LABEL Under normal conditions of intended use, this product does not pose a risk to health. Excessive exposure may result in eye, skin or respiratory irritation. Always observe good hygiene measures. First Aid: Wash skin with soap and water. Flush eyes with water. If overcome by fumes or vapor, remove to fresh air. If ingested do not induce vomiting. If persist seek medical assistance. Read and understand the MSDS before using this product. For Internal Use Only: MHC: 1* 1* 1* 1* MPPEC: A, TRN: 440461-00, CMCS97: 971601, REQ: US - MARKETING, SAFE USE: L EHS Approval Date: 03MAR2003 Legally required information is given in accordance with applicable Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for particular uses are beyond our control; all risks of use of the product are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO THE USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a recommendation for uses which infringe valid patents or as extending any license under valid patents. Appropiate warnings and safe handling procedures should be providedto handlers and users. Use or re- transmission of the information contained herein in any other format than the format as presented is strictly prohibited. Mobil neither represents nor warrants that the format, content or product formulas contained in this document comply with the laws of any other country except the United States of America. Copyright 1996 Mobil Corporation, All rights reserved Page 7 of 7 04/21/2003 Page 627 of 1235 Page 627 of 1235 Page 627 of 1235 Page 627 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 21 Mar 2011 Page 1 of 9 MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: (see Section 16 for Synonyms) MOBIL DELVAC 1300 SUPER 10W-30 Product Description: Base Oil and Additives MSDS Number: 8052 Intended Use: Engine oil COMPANY IDENTIFICATION Supplier: Imperial Oil Products Division 240 4th Avenue Calgary, ALBERTA. T2P 3M9 Canada 24 Hour Environmental / Health Emergency Telephone 1-[PHONE REDACTED] Transportation Emergency Phone Number 1-[PHONE REDACTED] Product Technical Information 1-[PHONE REDACTED] Supplier General Contact 1-[PHONE REDACTED] SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 3 HAZARDS IDENTIFICATION This material is not considered to be hazardous according to regulatory guidelines see Section 15. HEALTH EFFECTS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek Page 628 of 1235 Page 628 of 1235 Page 628 of 1235 Page 628 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 21 Mar 2011 Page 2 of 9 immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulphur oxides, Incomplete combustion products, Oxides of carbon FLAMMABILITY PROPERTIES Flash Point [Method]: 230C (446F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: 315°C (599°F) SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum Page 629 of 1235 Page 629 of 1235 Page 629 of 1235 Page 629 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 21 Mar 2011 Page 3 of 9 requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended. SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE HANDLING Avoid contact with used product. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present during switch-loading operations). Use proper bonding and/or earthing procedures. However, bonding and earthing may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. STORAGE The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Page 630 of 1235 Page 630 of 1235 Page 630 of 1235 Page 630 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 21 Mar 2011 Page 4 of 9 Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m³ - ACGIH TLV, 10 mg/m³ - ACGIH STEL. NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping. ENVIRONMENTAL CONTROLS Page 631 of 1235 Page 631 of 1235 Page 631 of 1235 Page 631 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 21 Mar 2011 Page 5 of 9 See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional data. GENERAL INFORMATION Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 0.863 Flash Point [Method]: 230C (446F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: 315°C (599°F) Boiling Point / Range: > 316C (600F) Vapour Density (Air = > 2 at 101 kPa Vapour Pressure: [N/D at 20°C] I < 1 kPa (7.5 mm Hg) at 38C Evaporation Rate (n-butyl acetate = < 0.1 pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: [N/D at 40°C] I 12 cSt (12 mm2/sec) at 100C Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -30°C (-22°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation Toxicity (Rat): LC50 > 5000 mg/m3 Minimally Toxic. Based on test data for structurally similar materials. Page 632 of 1235 Page 632 of 1235 Page 632 of 1235 Page 632 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 21 Mar 2011 Page 6 of 9 Irritation: No end point data. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components. Ingestion Toxicity (Rat): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Skin Toxicity (Rabbit): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Irritation (Rabbit): Data available. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials. Eye Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials. CHRONIC/OTHER EFFECTS For the product itself: Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Oils that are used in gasoline engines may become hazardous and display the following properties: Carcinogenic in animal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains aromatic compounds (PAC) from combustion products of gasoline and/or thermal degradation products. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non- specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request. CMR Status: None. --REGULATORY LISTS SEARCHED-- 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Not expected to be harmful to aquatic organisms. MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable Page 633 of 1235 Page 633 of 1235 Page 633 of 1235 Page 633 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 21 Mar 2011 Page 7 of 9 BIOACCUMULATION POTENTIAL Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. Protect the environment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents, brake fluids or coolants. REGULATORY DISPOSAL INFORMATION Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (TDG): Not Regulated for Land Transport LAND (DOT): Not Regulated for Land Transport SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code AIR (IATA): Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION WHMIS Classification: Not controlled This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Page 634 of 1235 Page 634 of 1235 Page 634 of 1235 Page 634 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 21 Mar 2011 Page 8 of 9 Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Complies with the following national/regional chemical inventory requirements: AICS, TSCA, DSL, KECI, IECSC, PICCS Special Cases: Inventory Status ELINCS Restrictions Apply ENCS Restrictions Apply The Following Ingredients are Cited on the Lists Below: Chemical Name CAS Number List Citations ZINC DITHIOPHOSPHATE 68649-42-3 6 --REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 15: National Chemical Inventory Listing was modified. Section 01: Product Identification Product Name was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 16: Synonyms was added. Section 16: Synonyms - Header was added. Section 01: Product Name - Header was added. Section 04: First Aid Eye - Header was modified. Section 13: Regulatory Disposal Information - Header was modified. Section 06: Protective Measures was added. Section 06: Notification Procedures - Header was modified. Section 13: Disposal Considerations - Disposal Recommendations was modified. Section 06: Accidental Release - Protective Measures - Header was added. Section 11: Acute Toxicity Table Header was modified. Section 09: Colour was modified. Section 11: Inhalation - Header was modified. Section 09: Evaporation Rate - Header was modified. Section 09: Vapour Pressure - Header was modified. Section 07: Handling and Storage-Handling was modified. Page 635 of 1235 Page 635 of 1235 Page 635 of 1235 Page 635 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 21 Mar 2011 Page 9 of 9 Section 07: Handling and Storage-Storage Phrases was modified. Section 11: Inhalation Lethality Test Data was modified. Section 05: Hazardous Combustion Products was modified. Section 06: Accidental Release- Spill Management- Water was modified. Section 09: Flash Point C(F) was modified. Section 09 Viscosity was modified. Section 14: Sea (IMDG) - Header was modified. Section 14: Air (IATA) - Header was modified. Section 14: LAND (TDG) - Header was modified. Section 14: LAND (DOT) - Header was modified. Section 14: LAND (DOT) - Default was modified. Section 14: LAND (TDG) Default was modified. Section 14: Sea (IMDG) - Default was modified. Section 14: Air (IATA) - Default was modified. Section 15: National Chemical Inventory Listing - Header was modified. Section 09: Relative Density was modified. Hazard Identification: Hazards Note was modified. Section 16: CA Prepared by - Header was modified. Section 09: Oxidizing Properties was modified. Section 15: Canadian List Citations Table was added. Section 15: Chemical Name - Header was added. Section 15: CAS Number - Header was added. Section 15: List Citations -Header was added. Section 15: List Citation Table - Header was modified. Section 04: First Aid Ingestion - Header was modified. SYNONYMS: XD-3 EXTRA ENGINE OIL 10W-30 WHMIS Classification: Not controlled The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. DGN: 5006939 (543611) Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, IH and Product Safety Page 636 of 1235 Page 636 of 1235 Page 636 of 1235 Page 636 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 06 Aug 2009 Page 1 of 8 MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Product Description: Base Oil and Additives MSDS Number: 17756 Intended Use: Engine oil COMPANY IDENTIFICATION Supplier: Imperial Oil Products Division 240 4th Avenue Calgary, ALBERTA. T2P 3M9 Canada 24 Hour Environmental / Health Emergency Telephone [PHONE REDACTED] Transportation Emergency Phone Number [PHONE REDACTED] Product Technical Information 1-[PHONE REDACTED] Supplier General Contact 1-[PHONE REDACTED] SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 3 HAZARDS IDENTIFICATION This material is not considered to be hazardous according to regulatory guidelines see Section 15. HEALTH EFFECTS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Page 637 of 1235 Page 637 of 1235 Page 637 of 1235 Page 637 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 06 Aug 2009 Page 2 of 8 SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. Eye Contact Flush thoroughly with water. If irritation occurs, get medical assistance. Ingestion First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion products, Oxides of carbon FLAMMABILITY PROPERTIES Flash Point [Method]: 205C (401F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: 315°C (599°F) SECTION 6 ACCIDENTAL RELEASE MEASURES Notification Procedures In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a Page 638 of 1235 Page 638 of 1235 Page 638 of 1235 Page 638 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 06 Aug 2009 Page 3 of 8 specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE HANDLING Avoid contact with used product. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator. STORAGE Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m³ - ACGIH TLV, 10 mg/m³ - ACGIH STEL. NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Page 639 of 1235 Page 639 of 1235 Page 639 of 1235 Page 639 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 06 Aug 2009 Page 4 of 8 Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional data. GENERAL INFORMATION Physical State: Liquid Colour: dark brown Odour: Characteristic Odour Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 0.87 Flash Point [Method]: 205C (401F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: 315°C (599°F) Boiling Point / Range: > 316C (600F) Vapour Density (Air = > 2 at 101 kPa VAPOUR PRESSURE: [N/D at 20°C] I < 1 kPa (7.5 mm Hg) at 38C Evaporation Rate (N-Butyl Acetate = < 0.1 pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: [N/D at 40°C] I 11.6 cSt (11.6 mm²/sec) at 100C Oxidizing properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Page 640 of 1235 Page 640 of 1235 Page 640 of 1235 Page 640 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 06 Aug 2009 Page 5 of 8 Pour Point: -30°C (-22°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Acute Toxicity Route of Exposure Conclusion / Remarks INHALATION Toxicity (Rat): LC50 > 5000 mg/m³ Minimally Toxic. Based on test data for structurally similar materials. Irritation: No end point data. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components. Ingestion Toxicity (Rat): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Skin Toxicity (Rabbit): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Irritation (Rabbit): Data available. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials. Eye Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials. CHRONIC/OTHER EFFECTS For the product itself: Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Oils that are used in gasoline engines may become hazardous and display the following properties: Carcinogenic in animal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains aromatic compounds (PAC) from combustion products of gasoline and/or thermal degradation products. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request. Page 641 of 1235 Page 641 of 1235 Page 641 of 1235 Page 641 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 06 Aug 2009 Page 6 of 8 CMR Status: None. --REGULATORY LISTS SEARCHED-- 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Not expected to be harmful to aquatic organisms. MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. Regulatory Disposal Information Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (TDG) : Not Regulated for Land Transport Page 642 of 1235 Page 642 of 1235 Page 642 of 1235 Page 642 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 06 Aug 2009 Page 7 of 8 LAND (DOT) : Not Regulated for Land Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION WHMIS Classification: Not controlled This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. National Chemical Inventory Listing: AICS, IECSC, DSL, KECI, PICCS, TSCA Special Cases: Inventory Status ELINCS Restrictions Apply ENCS Restrictions Apply The Following Ingredients are Cited on the Lists Below: None. --REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 04: First Aid Eye - Header was modified. Section 13: Regulatory Disposal Information - Header was modified. Section 06: Notification Procedures - Header was modified. Section 11: Ingestion Acute Lethality - Header was modified. Section 09: Vapour Pressure - Header was modified. Section 07: Handling and Storage-Storage was modified. Section 05: Hazardous Combustion Products was modified. Section 15: National Chemical Inventory Listing - Header was modified. Page 643 of 1235 Page 643 of 1235 Page 643 of 1235 Page 643 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 10W-30 Revision Date: 06 Aug 2009 Page 8 of 8 Section 15: National Chemical Inventory Listing was modified. Section 15: Special Cases - Header was added. Section 15: Special Cases Table was added. Section 15: Inventory - Header was added. Section 15: Status - Header was added. Section 11: Tox Table - Header was modified. Section 15: Canadian List Citations Table was deleted. Section 15: Chemical Name - Header was deleted. Section 15: CAS Number - Header was deleted. Section 15: List Citations -Header was deleted. Section 15: List Citation Table - Header was modified. Section 04: First Aid Ingestion - Header was modified. WHMIS Classification: Not controlled The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. DGN: 5016329 (543611) Copyright 2002 Imperial Oil Limited, All rights reserved Prepared By: Imperial Oil Limited, IH and Product Safety Page 644 of 1235 Page 644 of 1235 Page 644 of 1235 Page 644 of 1235 ---PAGE BREAK--- 440461-00 MOBIL DELVAC 1300 SUPER 10W-30 MATERIAL SAFETY DATA BULLETIN 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: MOBIL DELVAC 1300 SUPER 10W-30 SUPPLIER: EXXONMOBIL OIL CORPORATION 3225 GALLOWS RD. FAIRFAX, VA 22037 24 - Hour Health and Safety Emergency (call collect): [PHONE REDACTED] 24 - Hour Transportation Emergency: CHEMTREC: [PHONE REDACTED] [PHONE REDACTED] LUBES AND FUELS: [PHONE REDACTED] Product and Technical Information: Lubricants and Specialties: [PHONE REDACTED] [PHONE REDACTED] Fuels Products: [PHONE REDACTED] MSDS Fax on Demand: [PHONE REDACTED] MSDS Internet Website: http://www.exxon.com, http://www.mobil.com 2. COMPOSITION/INFORMATION ON INGREDIENTS CHEMICAL NAMES AND SYNONYMS: SEVERE TREAT MIN. OILS & ADDITIVES GLOBALLY REPORTABLE MSDS INGREDIENTS: Substance Name Approx. Wt% PHOSPHORODITHIOIC ACID, 1-5 O,O-DI-C1-14-ALKYL ESTERS, ZINC SALT (2:1) ZDDP (68649-42-3) See Section 8 for exposure limits (if applicable). 3. HAZARDS IDENTIFICATION Under normal conditions of use, this product is not considered hazardous according to regulatory guidelines (See section 15). Page 645 of 1235 Page 645 of 1235 Page 645 of 1235 Page 645 of 1235 ---PAGE BREAK--- EMERGENCY OVERVIEW: Brown Liquid. DOT ERG No. : NA POTENTIAL HEALTH EFFECTS: Under normal conditions of intended use, this product does not pose a risk to health. Excessive exposure may result in eye, skin or respiratory irritation. For further health effects/toxicological data, see Section 11. 4. FIRST AID MEASURES EYE CONTACT: Flush thoroughly with water. If irritation occurs, call a physician. SKIN CONTACT: Wash contact areas with soap and water. Remove and clean oil soaked clothing daily and wash affected area. (See Section 16 - Injection Injury) INHALATION: Not expected to be a problem. However, if respiratory irritation, dizziness, nausea, or unconsciousness occurs due to excessive vapor or mist exposure, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or mouth-to-mouth resuscitation. INGESTION: Not expected to be a problem. Seek medical attention if discomfort occurs. Do not induce vomiting. 5. FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA: Carbon dioxide, foam, dry chemical and water fog. SPECIAL FIRE FIGHTING PROCEDURES: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposure. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. SPECIAL PROTECTIVE EQUIPMENT: For fires in enclosed areas, fire fighters must use self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS: None. COMBUSTION PRODUCTS: Fumes, smoke, carbon monoxide, sulfur oxides, aldehydes and other decomposition products, in the case of incomplete combustion. Flash Point C(F): 229(444) (ASTM D-92). Flammable Limits (approx.% vol.in air) - LEL: 0.9%, UEL: 7.0% NFPA HAZARD ID: Health: 0, Flammability: 1, Reactivity: 0 6. ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES: Report spills/releases as required to appropriate authorities. U.S. Coast Guard and EPA regulations require immediate reporting of spills/releases that could reach any waterway including intermittent dry creeks. Report spill/release to Coast Guard National Response Center toll free number (800)424-8802. In case of accident or road spill notify CHEMTREC (800) 424-9300. PROCEDURES IF MATERIAL IS RELEASED OR SPILLED: LAND SPILL: Shut off source taking normal safety precautions. Take measures to minimize the effects on ground water. Recover by pumping or contain spilled material with sand or other suitable Page 646 of 1235 Page 646 of 1235 Page 646 of 1235 Page 646 of 1235 ---PAGE BREAK--- absorbent and remove mechanically into containers. If necessary, dispose of adsorbed residues as directed in Section 13. WATER SPILL: Confine the spill immediately with booms. Warn other ships in the vicinity. Notify port and other relevant authorities. Remove from the surface by skimming or with suitable absorbents. If permitted by regulatory authorities the use of suitable dispersants should be considered where recommended in local oil spill procedures. ENVIRONMENTAL PRECAUTIONS: Prevent material from entering sewers, water sources or low lying areas; advise the relevant authorities if it has, or if it contaminates soil/vegetation. PERSONAL PRECAUTIONS: See Section 8 7. HANDLING AND STORAGE HANDLING: No special precautions are necessary beyond normal good hygiene practices. See Section 8 for additional personal protection advice when handling this product. STORAGE: Keep containers closed when not in use. Do not store in open or unlabelled containers. Store away from strong oxidizing agents and combustible materials. Do not store near heat, sparks, flame or strong oxidants. SPECIAL PRECAUTIONS: Prevent small spills and leakages to avoid slip hazard. EMPTY CONTAINER WARNING: Empty containers retain residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or clean container since residue is difficult to remove. Empty drums should be completely drained, properly bunged and returned to a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS: When mists/aerosols can occur, the following are recommended: 5 mg/m3 (as oil mist)- ACGIH Threshold Limit Value (TLV), 10 mg/m3 (as oil mist) - ACGIH Short Term Exposure Limit (STEL), 5 mg/m3 (as oil mist) - OSHA Permissible Exposure Limit (PEL) VENTILATION: If mists are generated, use adequate ventilation, local exhaust or enclosures to control below exposure limits. RESPIRATORY PROTECTION: If mists are generated, and/or when ventilation is not adequate, wear approved respirator. EYE PROTECTION: If eye contact is likely, safety glasses with side shields or chemical type goggles should be worn. SKIN PROTECTION: Not normally required. When splashing or liquid contact can occur frequently, wear oil resistant gloves and/or other protective clothing. Good personal hygiene practices should always be followed. Page 647 of 1235 Page 647 of 1235 Page 647 of 1235 Page 647 of 1235 ---PAGE BREAK--- 9. PHYSICAL AND CHEMICAL PROPERTIES Typical physical properties are given below. Consult Product Data Sheet for specific details. APPEARANCE: Liquid COLOR: Brown ODOR: Mild ODOR THRESHOLD-ppm: NE pH: NA BOILING POINT C(F): > 316(600) MELTING POINT C(F): NA FLASH POINT C(F): 229(444) (ASTM D-92) FLAMMABILITY (solids): NE AUTO FLAMMABILITY C(F): NA EXPLOSIVE PROPERTIES: NA OXIDIZING PROPERTIES: NA VAPOR PRESSURE-mmHg 20 C: NE VAPOR DENSITY: NE EVAPORATION RATE: NE RELATIVE DENSITY, 15/4 C: 0.866 SOLUBILITY IN WATER: Negligible PARTITION COEFFICIENT: > 3.5 VISCOSITY AT 40 C, cSt: 74.0 VISCOSITY AT 100 C, cSt: 11.5 POUR POINT C(F): -30(-22) FREEZING POINT C(F): NE VOC: < 3.00 (Wt. 0.220 lbs/gal DMSO EXTRACT, IP-346 for mineral oil only NA=NOT APPLICABLE NE=NOT ESTABLISHED D=DECOMPOSES FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING REPRESENTATIVE 10. STABILITY AND REACTIVITY STABILITY (THERMAL, LIGHT, ETC.): Stable. CONDITIONS TO AVOID: Extreme heat and high energy sources of ignition. INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS: Product does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. 11. TOXICOLOGICAL DATA ---ACUTE TOXICOLOGY--- ORAL TOXICITY (RATS): Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. DERMAL TOXICITY (RABBITS): Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. INHALATION TOXICITY (RATS): Practically non-toxic (LC50: greater than 5 mg/l). ---Based on testing of similar products and/or the Page 648 of 1235 Page 648 of 1235 Page 648 of 1235 Page 648 of 1235 ---PAGE BREAK--- components. EYE IRRITATION (RABBITS): Practically non-irritating. (Draize score: greater than 6 but 15 or less). ---Based on testing of similar products and/or the components. SKIN IRRITATION (RABBITS): Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than ---Based on testing of similar products and/or the components. OTHER ACUTE TOXICITY DATA: Although an acute inhalation study was not performed with this product, a variety of mineral and oils, such as those in this product, have been tested. These samples had virtually no effect other than a nonspecific inflammatory response in the lung to the aerosolized mineral oil. The presence of additives in other tested formulations (in approximately the same amounts as in the present formulation) did not alter the observed effects. ---SUBCHRONIC TOXICOLOGY (SUMMARY)--- No significant adverse effects were found in studies using repeated dermal applications of similar formulations to the skin of laboratory animals for 13 weeks at doses significantly higher than those expected during normal industrial exposure. The animals were evaluated extensively for effects of exposure (hematology, serum chemistry, urinalysis, organ weights, microscopic examination of tissues etc.). ---REPRODUCTIVE TOXICOLOGY (SUMMARY)--- No teratogenic effects would be expected from dermal exposure, based on laboratory developmental toxicity studies of major components in this formulation and/or materials of similar composition. ---CHRONIC TOXICOLOGY (SUMMARY)--- Repeated and/or prolonged exposure may cause irritation to the skin, eyes or respiratory tract. Overexposure to oil mist may result in oil droplet deposition and/or granuloma formation. For mineral base oils: Base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic mouse skin painting studies of severely treated oils showed no evidence of carcinogenic effects. These results are confirmed on a continuing basis using various screening methods such as Modified Ames Test, IP-346, and/or other analytical methods. For base oils: The base oils in this product have been tested in the Ames assay and other tests of mutagenicity with negative results. These base oils are not expected to be carcinogenic with chronic dermal exposures. ---SENSITIZATION (SUMMARY)--- Not expected to be sensitizing based on tests of this product, components, or similar products. ---OTHER TOXICOLOGY DATA--- Used gasoline engine oils have shown evidence of skin carcinogenic activity in laboratory tests when no effort was made to wash the oil off between applications. Used oil from diesel engines did not produce this effect. 12. ECOLOGICAL INFORMATION Page 649 of 1235 Page 649 of 1235 Page 649 of 1235 Page 649 of 1235 ---PAGE BREAK--- ENVIRONMENTAL FATE AND EFFECTS: In the absence of specific environmental data for this product, this assessment is based on information for representative products. ECOTOXICITY: Available ectoxicity data (LL50 >1000 mg/L) indicates that adverse effects to aquatic organisms are not expected from this product. MOBILITY: When released into the environment, adsorption to sediment and soil will be the predominant behavior. PERSISTENCE AND DEGRADABILITY: This product is expected to be inherently biodegradable. BIOACCUMULATIVE POTENTIAL: Bioaccumulation is unlikely due to the very low water solubility of this product, therefore bioavailability to aquatic organisms is minimal. 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Product is suitable for burning in an enclosed, controlled burner for fuel value. Such burning may be limited pursuant to the Resource Conservation and Recovery Act. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of at an appropriate government waste disposal facility. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. RCRA INFORMATION: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrosivity, or reactivity. The unused product is not formulated with substances covered by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. 14. TRANSPORT INFORMATION USA DOT: NOT REGULATED BY USA DOT. RID/ADR: NOT REGULATED BY RID/ADR. IMO: NOT REGULATED BY IMO. IATA: NOT REGULATED BY IATA. STATIC ACCUMULATOR (50 picosiemens or less): YES Page 650 of 1235 Page 650 of 1235 Page 650 of 1235 Page 650 of 1235 ---PAGE BREAK--- 15. REGULATORY INFORMATION US OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this product is not classified as hazardous in accordance with OSHA 29 CFR 1910.1200. EU Labeling: Product is not dangerous as defined by the European Union Dangerous Substances/Preparations Directives. EU labeling not required. Governmental Inventory Status: All components comply with TSCA, EINECS/ELINCS, AICS, METI, DSL, KOREA, and PHILIPPINES. U.S. Superfund Amendments and Reauthorization Act (SARA) Title III: This product contains no "EXTREMELY HAZARDOUS SUBSTANCES". SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. This product contains the following SARA (313) Toxic Release Chemicals: CHEMICAL NAME CAS NUMBER CONC. ZINC DITHIOPHOSPHATE 68649-42-3 The following product ingredients are cited on the lists below: CHEMICAL NAME CAS NUMBER LIST CITATIONS * ZINC (ELEMENTAL ANALYSIS) (0.15%) 7440-66-6 22 ZINC DITHIOPHOSPHATE 68649-42-3 18, 20, 21, 22, 24, 25 REGULATORY LISTS SEARCHED 1=ACGIH ALL 6=IARC 1 11=TSCA 4 16=CA P65 CARC 21=LA RTK 2=ACGIH A1 7=IARC 2A 12=TSCA 5a2 17=CA P65 REPRO 22=MI 293 3=ACGIH A2 8=IARC 2B 13=TSCA 5e 18=CA RTK 23=MN RTK 4=NTP CARC 9=OSHA CARC 14=TSCA 6 19=FL RTK 24=NJ RTK 5=NTP SUS 10=OSHA Z 15=TSCA 12b 20=IL RTK 25=PA RTK 26=RI RTK * EPA recently added new chemical substances to its TSCA Section 4 test rules. Please contact the supplier to confirm whether the ingredients in this product currently appear on a TSCA 4 or TSCA 12b list. Code key:CARC=Carcinogen; SUS=Suspected Carcinogen; REPRO=Reproductive 16. OTHER INFORMATION Page 651 of 1235 Page 651 of 1235 Page 651 of 1235 Page 651 of 1235 ---PAGE BREAK--- USE: COMMERCIAL ENGINE OIL NOTE: PRODUCTS OF EXXON MOBIL CORPORATION AND ITS AFFILIATED COMPANIES ARE NOT FORMULATED TO CONTAIN PCBS. Health studies have shown that many hydrocarbons pose potential human health risks which may vary from person to person. Information provided on this MSDS reflects intended use. This product should not be used for other applications. In any case, the following advice should be considered: INJECTION INJURY WARNING: If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. INDUSTRIAL LABEL Under normal conditions of intended use, this product does not pose a risk to health. Excessive exposure may result in eye, skin or respiratory irritation. Always observe good hygiene measures. First Aid: Wash skin with soap and water. Flush eyes with water. If overcome by fumes or vapor, remove to fresh air. If ingested do not induce vomiting. If persist seek medical assistance. Read and understand the MSDS before using this product. For Internal Use Only: MHC: 1* 1* 1* 1* MPPEC: A, TRN: 440461-00, CMCS97: 971601, REQ: US - MARKETING, SAFE USE: L EHS Approval Date: 29APR2003 Page 652 of 1235 Page 652 of 1235 Page 652 of 1235 Page 652 of 1235 ---PAGE BREAK--- Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for particular uses are beyond our control; all risks of use of the product are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO THE USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a recommendation for uses which infringe valid patents or as extending license under valid patents. Appropriate warnings and safe handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. Exxon Mobil Corporation and its affiliated companies assume no responsibility for accuracy of information unless the document is the most current available from an official ExxonMobil distribution system. Exxon Mobil Corporation and its affiliated companies neither represent nor warrant that the format, content or product formulas contained in this document comply with the laws of any other country except the United States of America. Prepared by: ExxonMobil Oil Corporation Environmental Health and Safety Department, Clinton, USA Page 653 of 1235 Page 653 of 1235 Page 653 of 1235 Page 653 of 1235 ---PAGE BREAK--- Page 654 of 1235 Page 654 of 1235 Page 654 of 1235 Page 654 of 1235 ---PAGE BREAK--- Page 655 of 1235 Page 655 of 1235 Page 655 of 1235 Page 655 of 1235 ---PAGE BREAK--- Page 656 of 1235 Page 656 of 1235 Page 656 of 1235 Page 656 of 1235 ---PAGE BREAK--- Page 657 of 1235 Page 657 of 1235 Page 657 of 1235 Page 657 of 1235 ---PAGE BREAK--- Page 658 of 1235 Page 658 of 1235 Page 658 of 1235 Page 658 of 1235 ---PAGE BREAK--- Page 659 of 1235 Page 659 of 1235 Page 659 of 1235 Page 659 of 1235 ---PAGE BREAK--- Page 660 of 1235 Page 660 of 1235 Page 660 of 1235 Page 660 of 1235 ---PAGE BREAK--- Page 661 of 1235 Page 661 of 1235 Page 661 of 1235 Page 661 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 15W-40 Revision Date: 22Oct2007 Page 1 of 8 MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: MOBIL DELVAC 1300 SUPER 15W-40 Product Description: Base Oil and Additives MSDS Number: 12560 Intended Use: Engine oil COMPANY IDENTIFICATION Supplier: Imperial Oil Products Division 240 4th Avenue Calgary, ALBERTA. T2P 3M9 Canada 24 Hour Environmental / Health Emergency Telephone [PHONE REDACTED] Transportation Emergency Phone Number [PHONE REDACTED] Product Technical Information 1-[PHONE REDACTED] Supplier General Contact 1-[PHONE REDACTED] SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 3 HAZARDS IDENTIFICATION This material is not considered to be hazardous according to regulatory guidelines see Section 15. HEALTH EFFECTS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Page 662 of 1235 Page 662 of 1235 Page 662 of 1235 Page 662 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 15W-40 Revision Date: 22Oct2007 Page 2 of 8 SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulphur Oxides, Oxides of carbon, Incomplete combustion products FLAMMABILITY PROPERTIES Flash Point [Method]: 232C (450F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Page 663 of 1235 Page 663 of 1235 Page 663 of 1235 Page 663 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 15W-40 Revision Date: 22Oct2007 Page 3 of 8 Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE HANDLING Avoid contact with used product. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator. STORAGE Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m³ - ACGIH TLV, 10 mg/m³ - ACGIH STEL. NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Page 664 of 1235 Page 664 of 1235 Page 664 of 1235 Page 664 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 15W-40 Revision Date: 22Oct2007 Page 4 of 8 Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Work conditions can greatly affect glove durability; inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional data. GENERAL INFORMATION Physical State: Liquid Colour: brown Odour: Characteristic Odour Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 0.872 Flash Point [Method]: 232C (450F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D Boiling Point / Range: N/D Vapour Density (Air = N/D Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20°C Evaporation Rate (N-Butyl Acetate = N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: [N/D at 40°C] I 15 cSt (15 mm²/sec) at 100C Oxidizing properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A DMSO Extract (mineral oil only), IP-346: < 3 %wt SECTION 10 STABILITY AND REACTIVITY Page 665 of 1235 Page 665 of 1235 Page 665 of 1235 Page 665 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 15W-40 Revision Date: 22Oct2007 Page 5 of 8 STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Acute Toxicity Route of Exposure Conclusion / Remarks INHALATION Toxicity (Rat): LC50 > 5000 mg/m³ Minimally Toxic. Based on test data for structurally similar materials. Irritation: No end point data. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components. INGESTION Toxicity (Rat): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Skin Toxicity (Rabbit): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Irritation (Rabbit): Data available. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials. Eye Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials. CHRONIC/OTHER EFFECTS For the product itself: Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Oils that are used in gasoline engines may become hazardous and display the following properties: Carcinogenic in animal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains aromatic compounds (PAC) from combustion products of gasoline and/or thermal degradation products. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. Additional information is available by request. CMR Status: None. --REGULATORY LISTS SEARCHED-- Page 666 of 1235 Page 666 of 1235 Page 666 of 1235 Page 666 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 15W-40 Revision Date: 22Oct2007 Page 6 of 8 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Not expected to be harmful to aquatic organisms. MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (TDG) : Not Regulated for Land Transport LAND (DOT) : Not Regulated for Land Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code Page 667 of 1235 Page 667 of 1235 Page 667 of 1235 Page 667 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 15W-40 Revision Date: 22Oct2007 Page 7 of 8 AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION WHMIS Classification: Not controlled This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. NATIONAL CHEMICAL INVENTORY LISTING: TSCA, DSL The Following Ingredients are Cited on the Lists Below: None. --REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 05: Fire Fighting Measures - Fire Fighting Instruction was modified. Section 13: Empty Container Warning was modified. Section 09: Phys/Chem Properties Note was modified. Section 08: Hand Protection was modified. Section 06: Accidental Release- Spill Management- Water was modified. Section 09: Physical State was deleted. Section 09: Flash Point C(F) was modified. Section 09 Viscosity was modified. Section 15: National Chemical Inventory Listing was modified. Section 09: Form - Header was deleted. Section 09: Relative Density - Header was modified. WHMIS Classification: Not controlled The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and Page 668 of 1235 Page 668 of 1235 Page 668 of 1235 Page 668 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 15W-40 Revision Date: 22Oct2007 Page 8 of 8 recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. DGN: 5010580 (1011991) Copyright 2002 Imperial Oil Limited, All rights reserved Prepared By: Imperial Oil Limited, IH and Product Safety Page 669 of 1235 Page 669 of 1235 Page 669 of 1235 Page 669 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 15W-40 Revision Date: 29Aug2006 Page 1 of 9 MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: MOBIL DELVAC 1300 SUPER 15W-40 Product Description: Base Oil and Additives Product Code: 440693-00, 970529 Intended Use: Engine oil COMPANY IDENTIFICATION Supplier: EXXON MOBIL CORPORATION 3225 GALLOWS RD. FAIRFAX, VA. 22037 USA 24 Hour Health Emergency [PHONE REDACTED] Transportation Emergency Phone [PHONE REDACTED] ExxonMobil Transportation No. [PHONE REDACTED] MSDS Requests [PHONE REDACTED] Product Technical Information [PHONE REDACTED], [PHONE REDACTED] MSDS Internet Address http://www.exxon.com, http://www.mobil.com SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 3 HAZARDS IDENTIFICATION This material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). POTENTIAL HEALTH EFFECTS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use Page 670 of 1235 Page 670 of 1235 Page 670 of 1235 Page 670 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 15W-40 Revision Date: 29Aug2006 Page 2 of 9 mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Aldehydes, Sulfur oxides, Oxides of carbon, Incomplete combustion products, Smoke, Fume FLAMMABILITY PROPERTIES Flash Point [Method]: >215C (419F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. U.S. regulations require reporting releases of this material to the environment which exceed the reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802. SPILL MANAGEMENT Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent. Page 671 of 1235 Page 671 of 1235 Page 671 of 1235 Page 671 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 15W-40 Revision Date: 29Aug2006 Page 3 of 9 Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE HANDLING Avoid contact with used product. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator. STORAGE Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m³ - ACGIH TLV, 10 mg/m³ - ACGIH STEL, 5 mg/m³ - OSHA PEL. NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of Page 672 of 1235 Page 672 of 1235 Page 672 of 1235 Page 672 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 15W-40 Revision Date: 29Aug2006 Page 4 of 9 respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Work conditions can greatly effect glove durability; inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional data. GENERAL INFORMATION Physical State: Liquid Color: Brown Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C 0.874 Flash Point [Method]: >215C (419F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapor Density (Air = N/D Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 C Evaporation Rate (n-butyl acetate = N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 113 cSt (113 mm2/sec ) at 40 C I 15 cSt (15 mm2/sec) at 100C Page 673 of 1235 Page 673 of 1235 Page 673 of 1235 Page 673 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 15W-40 Revision Date: 29Aug2006 Page 5 of 9 Oxidizing Properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -27°C (-17°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation Toxicity (Rat): LC50 > 5000 mg/m3 Minimally Toxic. Based on test data for structurally similar materials. Irritation: No end point data. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components. Ingestion Toxicity (Rat): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Skin Toxicity (Rabbit): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Irritation (Rabbit): Data available. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials. Eye Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials. CHRONIC/OTHER EFFECTS For the product itself: Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Oils that are used in gasoline engines may become hazardous and display the following properties: Carcinogenic in animal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains aromatic compounds (PAC) from combustion products of gasoline and/or thermal degradation products. Page 674 of 1235 Page 674 of 1235 Page 674 of 1235 Page 674 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 15W-40 Revision Date: 29Aug2006 Page 6 of 9 Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non- specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. Additional information is available by request. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Not expected to be harmful to aquatic organisms. MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with Page 675 of 1235 Page 675 of 1235 Page 675 of 1235 Page 675 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 15W-40 Revision Date: 29Aug2006 Page 7 of 9 contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Empty Container Warning PRECAUTIONARY LABEL TEXT: Empty containers may retain residue and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or clean container since residue is difficult to remove. Empty drums should be completely drained, properly bunged and returned to a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. SECTION 14 TRANSPORT INFORMATION LAND (DOT) : Not Regulated for Land Transport LAND (TDG) : Not Regulated for Land Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not classified as hazardous in accordance with OSHA 29 CFR 1910.1200. NATIONAL CHEMICAL INVENTORY LISTING: TSCA Special Cases: Inventory Status ELINCS Restrictions Apply EPCRA: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. The Following Ingredients are Cited on the Lists Below: Chemical Name CAS Number List Citations DIPHENYLAMINE 122-39-4 5, 9, 18 PHOSPHORUS 7723-14-0 1, 4 ZINC DITHIOPHOSPHATE 68649-42-3 15 --REGULATORY LISTS SEARCHED-- Page 676 of 1235 Page 676 of 1235 Page 676 of 1235 Page 676 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 15W-40 Revision Date: 29Aug2006 Page 8 of 9 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK 5 = TSCA 4 10 = CA P65 CARC 15 = MI 293 Code key: CARC=Carcinogen; REPRO=Reproductive SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 05: Hazardous Combustion Products was modified. Section 09: Viscosity was modified. Section 09: Viscosity was modified. Section 15: List Citations Table was modified. Section 15: List Citation Table - Header was modified. Section 15: SARA (313) TOXIC RELEASE INVENTORY - Header was modified. Section 15: National Chemical Inventory Listing was modified. Section 09: Relative Density was modified. Section 16: MSN, MAT ID was modified. Section 02: No components was modified. Section 15: Special Cases - Header was added. Section 15: Special Cases Table was added. Section 15: Inventory - Header was added. Section 15: Status - Header was added. Section 02: Component table was deleted. Section 15: SARA (313) TOXIC RELEASE INVENTORY - Table was deleted. Section 15: SARA 313 - Chemical Name - Header was deleted. Section 15: SARA 313 - CAS Number - Header was deleted. Section 15: SARA313 - Typical Value - Header was deleted. Section 02: Primary Ingredient Name was deleted. Section 02: CAS Number was deleted. Section 02: Concentration - Header was deleted. Section 02: Substances Table - Header was deleted. Section 02: Concentration Footnote was deleted. Section 15: TSCA Class 2 Statement was deleted. The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re- publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. Page 677 of 1235 Page 677 of 1235 Page 677 of 1235 Page 677 of 1235 ---PAGE BREAK--- Product Name: MOBIL DELVAC 1300 SUPER 15W-40 Revision Date: 29Aug2006 Page 9 of 9 Internal Use Only MHC: 0, 0, 0, 0, 0, 0 PPEC: A DGN: 2003305XUS (1012124) Copyright 2002 Exxon Mobil Corporation, All rights reserved Page 678 of 1235 Page 678 of 1235 Page 678 of 1235 Page 678 of 1235 ---PAGE BREAK--- Page 1 of 6 Date Prepared: January 09, 2004 Supersedes: March 27, 2002 MSDS Number: 12560 1. PRODUCT INFORMATION Product Identifier: MOBIL DELVAC 1300 SUPER 15W-40 Application and Use: Mineral oil for diesel engines Product Description: A mixture of refined petroleum lubricant basestocks, and additives. REGULATORY CLASSIFICATION WHMIS: Not a controlled product CEPA: CANADIAN ENVIRONMENTAL PROTECTION ACT All components of this product are either on the Domestic Substances List (DSL) or are exempt. TDG INFORMATION (RAIL/ROAD): Not Regulated in Canada. Please be aware that other regulations may apply. TELEPHONE NUMBERS MANUFACTURER/SUPPLIER: Emergency 24 hr. (519) 339-2145 IMPERIAL OIL Technical Info. (800) 268-3183 Products Division 240 4th Avenue S.W. Calgary, Alberta T2P 3M9 MSDS No: 12560 MOBIL DELVAC 1300 SUPER 15W-40 Page 679 of 1235 Page 679 of 1235 Page 679 of 1235 Page 679 of 1235 ---PAGE BREAK--- Page 2 of 6 2. REGULATED COMPONENTS The following components are defined in accordance with sub-paragraph 13(a) to (iv) or paragraph 14(a) of the Hazardous Products Act: NAME % CAS # Not applicable 3. TYPICAL PHYSICAL & CHEMICAL PROPERTIES Physical State: Liquid Specific gravity: 0.887 to 0.000 at 15.5 deg C Viscosity: >116.80 cSt at 40 deg C Vapour Density: > 0 Boiling Point: not available Evaporation rate: <1 n-butylacetate) Solubility in water: INSOLUBLE Freezing/Pour Point: -27 deg C nav < Odour Threshold: not available Vapour Pressure: <0.013 kPa at 24 deg C Density: 0.00 g/cc Appearance/odour: Clear brown liquid, mild petroleum odour. 4. HEALTH HAZARD INFORMATION NATURE OF HAZARD INHALATION: Negligible hazard at normal temperatures (up to 38 deg Elevated temperatures or mechanical action may form vapours, mists or fumes which may be irritating to the eyes, nose, throat and lungs. Avoid breathing vapours or mists. EYE CONTACT: irritating, but will not injure eye tissue. SKIN CONTACT: Low toxicity. Frequent or prolonged contact may irritate the skin. INGESTION: Low toxicity. CHRONIC: Prolonged and/or repeated contact with used gasoline engine oil has caused MSDS No: 12560 MOBIL DELVAC 1300 SUPER 15W-40 Page 680 of 1235 Page 680 of 1235 Page 680 of 1235 Page 680 of 1235 ---PAGE BREAK--- Page 3 of 6 skin cancer in experimental animals. The relationship of these results to humans has not been fully established. ACUTE TOXICITY DATA: Based on animal testing data from similar materials and products, the acute toxicity of this product is expected to be: Oral : LD50 > 5000 mg/kg (Rat) Dermal : LD50 > 3160 mg/kg (Rabbit) Inhalation : LC50 > 5000 mg/m3 (Rat) OCCUPATIONAL EXPOSURE LIMIT: ACGIH recommends: For oil mists, 5 mg/m3. Local regulated limits may vary. 5. FIRST AID MEASURES INHALATION: Vapour pressure of this material is low and as such inhalation under normal conditions is usually not a problem. If overexposed to oil mist, remove from further exposure. Administer artificial respiration if breathing has stopped. Keep at rest. Call for prompt medical attention. EYE CONTACT: Flush eyes with large amounts of water until irritation subsides. If irritation persists, get medical attention. SKIN CONTACT: Flush with large amounts of water. Use soap if available. Remove severely contaminated clothing (including shoes) and launder before reuse. If irritation persists, seek medical attention. INGESTION: If swallowed, DO NOT induce vomiting. Keep at rest. Get prompt medical attention. 6. PREVENTIVE AND CORRECTIVE MEASURES PERSONAL PROTECTION: The selection of personal protective equipment varies, depending upon conditions of use. MSDS No: 12560 MOBIL DELVAC 1300 SUPER 15W-40 Page 681 of 1235 Page 681 of 1235 Page 681 of 1235 Page 681 of 1235 ---PAGE BREAK--- Page 4 of 6 In open systems where contact is likely, wear safety goggles, chemical- resistant overalls, and chemically impervious gloves. Where only incidental contact is likely, wear safety glasses with side shields. No other special precautions are necessary provided skin/eye contact is avoided. Where concentrations in air may exceed the occupational exposure limits given in Section 4 and where engineering, work practices or other means of exposure reduction are not adequate, approved respirators may be necessary to prevent overexposure by inhalation. ENGINEERING CONTROLS: The use of local exhaust ventilation is recommended to control emissions near the source. Laboratory samples should be handled in a fumehood. Provide mechanical ventilation of confined spaces. HANDLING, STORAGE AND SHIPPING: Keep containers closed. Handle and open containers with care. Store in a cool, well ventilated place away from incompatible materials. In keeping with good personal hygiene practices, wash hands thoroughly after handling the material. Empty containers may contain product residue. Do not pressurize cut, heat, or weld empty containers. Do not reuse empty containers without commercial cleaning or reconditioning. LAND SPILL: Eliminate source of ignition. Keep public away. Prevent additional discharge of material, if possible to do so without hazard. Prevent spills from entering sewers, watercourses or low areas. Contain spilled liquid with sand or earth. Recover by pumping or by using a suitable absorbant. If liquid is too viscous for pumping, scrape up. Consult an expert on disposal of recovered material. Ensure disposal in compliance with government requirements and ensure conformity to local disposal regulations. Notify the appropriate authorities immediately. Take all additional action necessary to prevent and remedy the adverse effects of the spill. WATER SPILL: Remove from surface by skimming or with suitable absorbents. If allowed by local authorities and environmental agencies, sinking and/or suitable dispersants may be used in unconfined waters. Consult an expert on disposal of recovered material. Ensure disposal in compliance with government requirements and ensure conformity to local disposal regulations. Notify the appropriate authorities immediately. Take all additional action necessary to prevent and remedy the adverse effects of the spill. 7. FIRE AND EXPLOSION HAZARD MSDS No: 12560 MOBIL DELVAC 1300 SUPER 15W-40 Page 682 of 1235 Page 682 of 1235 Page 682 of 1235 Page 682 of 1235 ---PAGE BREAK--- Page 5 of 6 Flashpoint and method: >216 deg C (COC) Estimated Autoignition: NA Flammable Limits: LEL: 0.6% UEL: 7.0% GENERAL HAZARDS: Low Hazard; liquids may burn upon heating to temperatures at or above the flash point. Decomposes; flammable/toxic gases will form at elevated temperatures (thermal decomposition). Toxic gases will form upon combustion. FIRE FIGHTING: Use water spray to cool fire exposed surfaces and to protect personnel. Shut off fuel to fire. Use foam, dry chemical or water spray to extinguish fire. Respiratory and eye protection required for fire fighting personnel. A self-contained breathing apparatus (SCBA) should be used for all indoor fires and any significant outdoor fires. For small outdoor fires, which may easily be extinguished with a portable fire extinguisher, use of an SCBA may not be required. HAZARDOUS COMBUSTION PRODUCTS: Various metal oxides Smoke, carbon monoxide, carbon dioxide and traces of oxides of sulphur 8. REACTIVITY DATA STABILITY: This product is stable. Hazardous polymerization will not occur. INCOMPATIBLE MATERIALS AND CONDITIONS TO AVOID: Strong oxidizing agents HAZARDOUS DECOMPOSITION: See: Hazardous Combustion Products 9. NOTES . 10. PREPARATION Date Prepared: January 09, 2004 MSDS No: 12560 MOBIL DELVAC 1300 SUPER 15W-40 Page 683 of 1235 Page 683 of 1235 Page 683 of 1235 Page 683 of 1235 ---PAGE BREAK--- Page 6 of 6 Prepared by: Lubricants & Specialties IMPERIAL OIL Products Division 240 4th Avenue S.W. Calgary, Alberta T2P 3M9 (800) 268-3183 CAUTION: " The information contained herein relates only to this product or material and may not be valid when used in combination with any other product or material or in any process. If the product is not to be used for a purpose or under conditions which are normal or reasonably foreseeable, this information cannot be relied upon as complete or applicable. For greater certainty, uses other than those described in Section 1 must be reviewed with the supplier. The information contained herein is based on the information available at the indicated date of preparation. This MSDS is for the use of Imperial Oil customers and their employees and agents only. Any further distribution of this MSDS by Imperial Oil customers is prohibited without the written consent of Imperial Oil." MSDS No: 12560 MOBIL DELVAC 1300 SUPER 15W-40 Page 684 of 1235 Page 684 of 1235 Page 684 of 1235 Page 684 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 02 Sep 2010 Page 1 of 9 MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: MOBIL SPECIAL 5W-20 Product Description: Base Oil and Additives Product Code: 201510401580, 445460-00, 97BT45 Intended Use: Engine oil COMPANY IDENTIFICATION Supplier: EXXON MOBIL CORPORATION 3225 GALLOWS RD. FAIRFAX, VA. 22037 USA 24 Hour Health Emergency [PHONE REDACTED] Transportation Emergency Phone [PHONE REDACTED] ExxonMobil Transportation No. [PHONE REDACTED] Product Technical Information [PHONE REDACTED], [PHONE REDACTED] MSDS Internet Address http://www.exxon.com, http://www.mobil.com SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 3 HAZARDS IDENTIFICATION This material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). POTENTIAL HEALTH EFFECTS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use Page 685 of 1235 Page 685 of 1235 Page 685 of 1235 Page 685 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 02 Sep 2010 Page 2 of 9 adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulfur oxides, Incomplete combustion products, Oxides of carbon FLAMMABILITY PROPERTIES Flash Point [Method]: 221C (430F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802. Page 686 of 1235 Page 686 of 1235 Page 686 of 1235 Page 686 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 02 Sep 2010 Page 3 of 9 PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. SPILL MANAGEMENT Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE HANDLING Avoid contact with used product. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present during switch-loading operations). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. STORAGE The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m³ - ACGIH TLV, 10 mg/m³ - ACGIH STEL, 5 mg/m³ - OSHA PEL. Page 687 of 1235 Page 687 of 1235 Page 687 of 1235 Page 687 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 02 Sep 2010 Page 4 of 9 NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional data. Page 688 of 1235 Page 688 of 1235 Page 688 of 1235 Page 688 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 02 Sep 2010 Page 5 of 9 GENERAL INFORMATION Physical State: Liquid Color: Amber Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 0.86 Flash Point [Method]: 221C (430F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapor Density (Air = N/D Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 C Evaporation Rate (n-butyl acetate = N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 49.2 cSt (49.2 mm2/sec) at 40 C I 8.6 cSt (8.6 mm2/sec) at 100C Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -33°C (-27°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation Toxicity (Rat): LC50 > 5000 mg/m3 Minimally Toxic. Based on test data for structurally similar materials. Irritation: No end point data. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components. Ingestion Toxicity (Rat): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Page 689 of 1235 Page 689 of 1235 Page 689 of 1235 Page 689 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 02 Sep 2010 Page 6 of 9 Skin Toxicity (Rabbit): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Irritation (Rabbit): Data available. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials. Eye Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials. CHRONIC/OTHER EFFECTS For the product itself: Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Oils that are used in gasoline engines may become hazardous and display the following properties: Carcinogenic in animal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains aromatic compounds (PAC) from combustion products of gasoline and/or thermal degradation products. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. Additional information is available by request. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Not expected to be harmful to aquatic organisms. MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Page 690 of 1235 Page 690 of 1235 Page 690 of 1235 Page 690 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 02 Sep 2010 Page 7 of 9 Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. Protect the environment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents, brake fluids or coolants. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (DOT): Not Regulated for Land Transport LAND (TDG): Not Regulated for Land Transport SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code AIR (IATA): Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not classified as hazardous in accordance with OSHA 29 CFR 1910.1200. NATIONAL CHEMICAL INVENTORY LISTING: DSL, EINECS, KECI, PICCS, TSCA Page 691 of 1235 Page 691 of 1235 Page 691 of 1235 Page 691 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 02 Sep 2010 Page 8 of 9 EPCRA: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. The following ingredients are cited on the lists below: Chemical Name CAS Number List Citations DIPHENYLAMINE 122-39-4 5, 18 ZINC 68649-42-3 15 ZINC DITHIOPHOSPHATE 68649-42-3 15 --REGULATORY LISTS SEARCHED-- 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK 5 = TSCA 4 10 = CA P65 CARC 15 = MI 293 Code key: CARC=Carcinogen; REPRO=Reproductive SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: No revision information is available. The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A Page 692 of 1235 Page 692 of 1235 Page 692 of 1235 Page 692 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 02 Sep 2010 Page 9 of 9 DGN: 7108632XUS (1018102) Copyright 2002 Exxon Mobil Corporation, All rights reserved Page 693 of 1235 Page 693 of 1235 Page 693 of 1235 Page 693 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 08 Apr 2013 Page 1 of 9 MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: MOBIL SPECIAL 5W-20 Product Description: Base Oil and Additives Product Code: 201510401580, 445460-00, 97BT45 Intended Use: Engine oil COMPANY IDENTIFICATION Supplier: EXXON MOBIL CORPORATION 3225 GALLOWS RD. FAIRFAX, VA. 22037 USA 24 Hour Health Emergency [PHONE REDACTED] Transportation Emergency Phone [PHONE REDACTED] ExxonMobil Transportation No. [PHONE REDACTED] Product Technical Information [PHONE REDACTED], [PHONE REDACTED] MSDS Internet Address http://www.exxon.com, http://www.mobil.com SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 3 HAZARDS IDENTIFICATION This material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). POTENTIAL HEALTH EFFECTS Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use Page 694 of 1235 Page 694 of 1235 Page 694 of 1235 Page 694 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 08 Apr 2013 Page 2 of 9 adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulfur oxides, Incomplete combustion products, Oxides of carbon FLAMMABILITY PROPERTIES Flash Point [Method]: 221°C (430°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802. Page 695 of 1235 Page 695 of 1235 Page 695 of 1235 Page 695 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 08 Apr 2013 Page 3 of 9 PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended. SPILL MANAGEMENT Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE HANDLING Avoid contact with used product. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present during switch-loading operations). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. STORAGE The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store in open or unlabelled containers. Page 696 of 1235 Page 696 of 1235 Page 696 of 1235 Page 696 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 08 Apr 2013 Page 4 of 9 SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols can occur the following are recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction), 5 mg/m³ - OSHA PEL. NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. Page 697 of 1235 Page 697 of 1235 Page 697 of 1235 Page 697 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 08 Apr 2013 Page 5 of 9 ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Physical State: Liquid Color: Amber Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 0.86 Flash Point [Method]: 221°C (430°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) Vapor Density (Air = N/D Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C Evaporation Rate (n-butyl acetate = N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 49.2 cSt (49.2 mm2/sec) at 40 °C I 8.6 cSt (8.6 mm2/sec) at 100°C Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -27°C (-17°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. Page 698 of 1235 Page 698 of 1235 Page 698 of 1235 Page 698 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 08 Apr 2013 Page 6 of 9 SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Ingestion Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on assessment of the components. Eye Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components. CHRONIC/OTHER EFFECTS For the product itself: Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Oils that are used in gasoline engines may become hazardous and display the following properties: Carcinogenic in animal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains aromatic compounds (PAC) from combustion products of gasoline and/or thermal degradation products. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Not expected to be harmful to aquatic organisms. Page 699 of 1235 Page 699 of 1235 Page 699 of 1235 Page 699 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 08 Apr 2013 Page 7 of 9 MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. Protect the environment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents, brake fluids or coolants. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (DOT): Not Regulated for Land Transport LAND (TDG): Not Regulated for Land Transport Page 700 of 1235 Page 700 of 1235 Page 700 of 1235 Page 700 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 08 Apr 2013 Page 8 of 9 SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code AIR (IATA): Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not classified as hazardous in accordance with OSHA 29 CFR 1910.1200. Complies with the following national/regional chemical inventory requirements: DSL, KECI, PICCS, TSCA EPCRA SECTION 302: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. The following ingredients are cited on the lists below: Chemical Name CAS Number List Citations DIPHENYLAMINE 122-39-4 18 ZINC 68649-42-3 15, 19 ZINC DITHIOPHOSPHATE 68649-42-3 15, 19 --REGULATORY LISTS SEARCHED-- 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK 5 = TSCA 4 10 = CA P65 CARC 15 = MI 293 Code key: CARC=Carcinogen; REPRO=Reproductive SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 06: Protective Measures was modified. Section 13: Disposal Considerations - Disposal Recommendations was modified. Section 09: Phys/Chem Properties Note was modified. Section 09: Boiling Point C(F) was modified. Page 701 of 1235 Page 701 of 1235 Page 701 of 1235 Page 701 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 08 Apr 2013 Page 9 of 9 Section 09: Pour Point C(F) was modified. Section 08: Comply with applicable regulations phrase was modified. Section 09: Vapor Pressure was modified. Hazard Identification: Health Hazards was modified. Section 11: Dermal Lethality Test Data was modified. Section 11: Dermal Lethality Test Comment was modified. Section 11: Oral Lethality Test Data was modified. Section 11: Inhalation Lethality Test Data was modified. Section 11: Dermal Irritation Test Data was modified. Section 11: Eye Irritation Test Data was modified. Section 11: Oral Lethality Test Comment was modified. Section 11: Inhalation Lethality Test Comment was modified. Section 11: Dermal Irritation Test Comment was modified. Section 11: Eye Irritation Test Comment was modified. Section 11: Inhalation Irritation Test Data was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Viscosity was modified. Section 09: Viscosity was modified. Section 14: LAND (TDG) - Header was modified. Section 15: List Citations Table was modified. Section 11: Inhalation Lethality Test Comment was modified. Section 15: National Chemical Inventory Listing - Header was modified. Section 15: National Chemical Inventory Listing was modified. Section 15: Community RTK - Header was modified. Section 11: Additional Health Information was modified. Section 08: Exposure limits/standards was modified. Section 01: Company Contact Methods Sorted by Priority was modified. The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A DGN: 7108632XUS (1018102) Copyright 2002 Exxon Mobil Corporation, All rights reserved Page 702 of 1235 Page 702 of 1235 Page 702 of 1235 Page 702 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 02 Sep 2010 Page 1 of 9 MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: MOBIL SPECIAL 5W-20 Product Description: Base Oil and Additives Product Code: 201510401580, 445460-00, 97BT45 Intended Use: Engine oil COMPANY IDENTIFICATION Supplier: EXXON MOBIL CORPORATION 3225 GALLOWS RD. FAIRFAX, VA. 22037 USA 24 Hour Health Emergency [PHONE REDACTED] Transportation Emergency Phone [PHONE REDACTED] ExxonMobil Transportation No. [PHONE REDACTED] Product Technical Information [PHONE REDACTED], [PHONE REDACTED] MSDS Internet Address http://www.exxon.com, http://www.mobil.com SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 3 HAZARDS IDENTIFICATION This material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). POTENTIAL HEALTH EFFECTS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION Page 703 of 1235 Page 703 of 1235 Page 703 of 1235 Page 703 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 02 Sep 2010 Page 2 of 9 Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulfur oxides, Incomplete combustion products, Oxides of carbon FLAMMABILITY PROPERTIES Flash Point [Method]: 221C (430F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The Page 704 of 1235 Page 704 of 1235 Page 704 of 1235 Page 704 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 02 Sep 2010 Page 3 of 9 National Response Center can be reached at (800)424-8802. PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. SPILL MANAGEMENT Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE HANDLING Avoid contact with used product. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present during switch-loading operations). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. STORAGE The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Page 705 of 1235 Page 705 of 1235 Page 705 of 1235 Page 705 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 02 Sep 2010 Page 4 of 9 Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m³ - ACGIH TLV, 10 mg/m³ - ACGIH STEL, 5 mg/m³ - OSHA PEL. NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. Page 706 of 1235 Page 706 of 1235 Page 706 of 1235 Page 706 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 02 Sep 2010 Page 5 of 9 ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional data. GENERAL INFORMATION Physical State: Liquid Color: Amber Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 0.86 Flash Point [Method]: 221C (430F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316C (600F) Vapor Density (Air = N/D Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 C Evaporation Rate (n-butyl acetate = N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 49.2 cSt (49.2 mm2/sec) at 40 C I 8.6 cSt (8.6 mm2/sec) at 100C Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -33°C (-27°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Page 707 of 1235 Page 707 of 1235 Page 707 of 1235 Page 707 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 02 Sep 2010 Page 6 of 9 ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation Toxicity (Rat): LC50 > 5000 mg/m3 Minimally Toxic. Based on test data for structurally similar materials. Irritation: No end point data. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components. Ingestion Toxicity (Rat): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Skin Toxicity (Rabbit): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Irritation (Rabbit): Data available. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials. Eye Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials. CHRONIC/OTHER EFFECTS For the product itself: Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Oils that are used in gasoline engines may become hazardous and display the following properties: Carcinogenic in animal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains aromatic compounds (PAC) from combustion products of gasoline and/or thermal degradation products. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non- specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. Additional information is available by request. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Page 708 of 1235 Page 708 of 1235 Page 708 of 1235 Page 708 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 02 Sep 2010 Page 7 of 9 Material Not expected to be harmful to aquatic organisms. MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. Protect the environment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents, brake fluids or coolants. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (DOT): Not Regulated for Land Transport LAND (TDG): Not Regulated for Land Transport Page 709 of 1235 Page 709 of 1235 Page 709 of 1235 Page 709 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 02 Sep 2010 Page 8 of 9 SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code AIR (IATA): Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not classified as hazardous in accordance with OSHA 29 CFR 1910.1200. NATIONAL CHEMICAL INVENTORY LISTING: DSL, EINECS, KECI, PICCS, TSCA EPCRA: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. The following ingredients are cited on the lists below: Chemical Name CAS Number List Citations DIPHENYLAMINE 122-39-4 5, 18 ZINC 68649-42-3 15 ZINC DITHIOPHOSPHATE 68649-42-3 15 --REGULATORY LISTS SEARCHED-- 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK 5 = TSCA 4 10 = CA P65 CARC 15 = MI 293 Code key: CARC=Carcinogen; REPRO=Reproductive SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: No revision information is available. Page 710 of 1235 Page 710 of 1235 Page 710 of 1235 Page 710 of 1235 ---PAGE BREAK--- Product Name: MOBIL SPECIAL 5W-20 Revision Date: 02 Sep 2010 Page 9 of 9 The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re- publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A DGN: 7108632XUS (1018102) Copyright 2002 Exxon Mobil Corporation, All rights reserved Page 711 of 1235 Page 711 of 1235 Page 711 of 1235 Page 711 of 1235 ---PAGE BREAK--- Page 712 of 1235 Page 712 of 1235 Page 712 of 1235 Page 712 of 1235 ---PAGE BREAK--- Page 713 of 1235 Page 713 of 1235 Page 713 of 1235 Page 713 of 1235 ---PAGE BREAK--- Page 714 of 1235 Page 714 of 1235 Page 714 of 1235 Page 714 of 1235 ---PAGE BREAK--- Page 715 of 1235 Page 715 of 1235 Page 715 of 1235 Page 715 of 1235 ---PAGE BREAK--- Page 716 of 1235 Page 716 of 1235 Page 716 of 1235 Page 716 of 1235 ---PAGE BREAK--- Page 717 of 1235 Page 717 of 1235 Page 717 of 1235 Page 717 of 1235 ---PAGE BREAK--- Page 718 of 1235 Page 718 of 1235 Page 718 of 1235 Page 718 of 1235 ---PAGE BREAK--- Page 719 of 1235 Page 719 of 1235 Page 719 of 1235 Page 719 of 1235 ---PAGE BREAK--- Page 720 of 1235 Page 720 of 1235 Page 720 of 1235 Page 720 of 1235 ---PAGE BREAK--- Product Name: MOBILFLUID 424 Revision Date: 19May2009 Page 1 of 8 MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: MOBILFLUID 424 Product Description: Base Oil and Additives Product Code: 522334-00, 971955 Intended Use: Hydraulic fluid COMPANY IDENTIFICATION Supplier: EXXON MOBIL CORPORATION 3225 GALLOWS RD. FAIRFAX, VA. 22037 USA 24 Hour Health Emergency [PHONE REDACTED] Transportation Emergency Phone [PHONE REDACTED] ExxonMobil Transportation No. [PHONE REDACTED] MSDS Requests [PHONE REDACTED] Product Technical Information [PHONE REDACTED], [PHONE REDACTED] MSDS Internet Address http://www.exxon.com, http://www.mobil.com SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# Concentration* ZINC DITHIOPHOSPHATE 68649-42-3 < 2.5% * All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. SECTION 3 HAZARDS IDENTIFICATION This material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). POTENTIAL HEALTH EFFECTS Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES Page 721 of 1235 Page 721 of 1235 Page 721 of 1235 Page 721 of 1235 ---PAGE BREAK--- Product Name: MOBILFLUID 424 Revision Date: 19May2009 Page 2 of 8 INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Pressurized mists may form a flammable mixture. Hazardous Combustion Products: Aldehydes, Incomplete combustion products, Smoke, Fume, Oxides of carbon, Sulfur oxides FLAMMABILITY PROPERTIES Flash Point [Method]: >198°C (389°F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable Page 722 of 1235 Page 722 of 1235 Page 722 of 1235 Page 722 of 1235 ---PAGE BREAK--- Product Name: MOBILFLUID 424 Revision Date: 19May2009 Page 3 of 8 regulations. U.S. regulations require reporting releases of this material to the environment which exceed the reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802. SPILL MANAGEMENT Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent. Water Spill: Confine the spill immediately with booms. Stop leak if you can do it without risk. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is a static accumulator. STORAGE Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m³ - ACGIH TLV, 10 mg/m³ - ACGIH STEL, 5 mg/m³ - OSHA PEL. NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Page 723 of 1235 Page 723 of 1235 Page 723 of 1235 Page 723 of 1235 ---PAGE BREAK--- Product Name: MOBILFLUID 424 Revision Date: 19May2009 Page 4 of 8 Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Work conditions can greatly effect glove durability; inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional data. GENERAL INFORMATION Physical State: Liquid Color: Amber Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 °C 0.884 Flash Point [Method]: >198°C (389°F) [ ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) Page 724 of 1235 Page 724 of 1235 Page 724 of 1235 Page 724 of 1235 ---PAGE BREAK--- Product Name: MOBILFLUID 424 Revision Date: 19May2009 Page 5 of 8 Vapor Density (Air = > 2 at 101 kPa Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20°C Evaporation Rate (n-butyl acetate = N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 55 cSt (55 mm²/sec ) at 40 °C I 9.6 cSt (9.6 mm²/sec) at 100°C Oxidizing Properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -36°C (-33°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation Toxicity (Rat): LC50 > 5000 mg/m³ Minimally Toxic. Based on assessment of the components. Irritation: No end point data. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components. Ingestion Toxicity (Rat): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Skin Toxicity (Rabbit): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Irritation (Rabbit): Data available. Negligible irritation to skin at ambient temperatures. Based on assessment of the components. Eye Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components. CHRONIC/OTHER EFFECTS Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Page 725 of 1235 Page 725 of 1235 Page 725 of 1235 Page 725 of 1235 ---PAGE BREAK--- Product Name: MOBILFLUID 424 Revision Date: 19May2009 Page 6 of 8 Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. Additional information is available by request. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Not expected to be harmful to aquatic organisms. MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Page 726 of 1235 Page 726 of 1235 Page 726 of 1235 Page 726 of 1235 ---PAGE BREAK--- Product Name: MOBILFLUID 424 Revision Date: 19May2009 Page 7 of 8 Empty Container Warning PRECAUTIONARY LABEL TEXT: Empty containers may retain residue and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or clean container since residue is difficult to remove. Empty drums should be completely drained, properly bunged and returned to a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. SECTION 14 TRANSPORT INFORMATION LAND (DOT) : Not Regulated for Land Transport LAND (TDG) : Not Regulated for Land Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not classified as hazardous in accordance with OSHA 29 CFR 1910.1200. NATIONAL CHEMICAL INVENTORY LISTING: AICS, DSL, EINECS, ENCS, KECI, PICCS, TSCA EPCRA: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: Chemical Name CAS Number Typical Value ZINC DITHIOPHOSPHATE 68649-42-3 < 2.5% The Following Ingredients are Cited on the Lists Below:* Chemical Name CAS Number List Citations PHOSPHORUS 7723-14-0 1, 4 TOLUENE 108-88-3 15 ZINC DITHIOPHOSPHATE 68649-42-3 13, 15, 17 --REGULATORY LISTS SEARCHED-- 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK Page 727 of 1235 Page 727 of 1235 Page 727 of 1235 Page 727 of 1235 ---PAGE BREAK--- Product Name: MOBILFLUID 424 Revision Date: 19May2009 Page 8 of 8 5 = TSCA 4 10 = CA P65 CARC 15 = MI 293 Code key: CARC=Carcinogen; REPRO=Reproductive * EPA recently added new chemical substances to its TSCA Section 4 test rules. Please contact the supplier to confirm whether the ingredients in this product currently appear on a TSCA 4 or TSCA 12b list. SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: No revision information is available. The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. Internal Use Only MHC: 0, 0, 0, 0, 0, 0 PPEC: A DGN: 2005922XUS (538859) Copyright 2002 Exxon Mobil Corporation, All rights reserved Page 728 of 1235 Page 728 of 1235 Page 728 of 1235 Page 728 of 1235 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 29 Sep 2015 Page 1 of 10 SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: MOBILGREASE XHP 222 SPECIAL Product Description: Base Oil and Additives Product Code: 2015A0202531, 530550-00, 97G870 Intended Use: Grease COMPANY IDENTIFICATION Supplier: EXXON MOBIL CORPORATION 22777 Springwoods Village Parkway Spring, TX. 77253 USA 24 Hour Health Emergency [PHONE REDACTED] Transportation Emergency Phone [PHONE REDACTED] or [PHONE REDACTED] CHEMTREC Product Technical Information [PHONE REDACTED] MSDS Internet Address http://www.exxon.com, http://www.mobil.com SECTION 2 HAZARDS IDENTIFICATION This material is not hazardous according to regulatory guidelines (see (M)SDS Section 15). Other hazard information: HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200. PHYSICAL / CHEMICAL HAZARDS No significant hazards. HEALTH HAZARDS High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, or respiratory irritation. ENVIRONMENTAL HAZARDS No significant hazards. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary Page 729 of 1235 Page 729 of 1235 Page 729 of 1235 Page 729 of 1235 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 29 Sep 2015 Page 2 of 10 from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS This material is defined as a mixture. Hazardous Substance(s) or Complex Substance(s) required for disclosure Name CAS# Concentration* GHS Hazard Codes BENZENAMINE, N-PHENYL-, REACTION PRODUCTS WITH 68411-46-1 1 - < 5% H402, H412 ZINC DITHIOPHOSPHATE 68649-42-3 1 - < 2.5% H315, H318, H401, H411 * All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. As per paragraph of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and exact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact percentage composition will be provided to health professionals, employees, or designated representatives in accordance with applicable provisions of paragraph SECTION 4 FIRST AID MEASURES INHALATION Under normal conditions of intended use, this material is not expected to be an inhalation hazard. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, Page 730 of 1235 Page 730 of 1235 Page 730 of 1235 Page 730 of 1235 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 29 Sep 2015 Page 3 of 10 sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Aldehydes, Incomplete combustion products, Oxides of carbon, Smoke, Fume, Sulfur oxides FLAMMABILITY PROPERTIES Flash Point [Method]: >204°C (400°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802. PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended. SPILL MANAGEMENT Land Spill: Scrape up spilled material with shovels into a suitable container for recycle or disposal. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Skim from surface. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Prevent entry into waterways, sewers, basements or confined areas. Page 731 of 1235 Page 731 of 1235 Page 731 of 1235 Page 731 of 1235 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 29 Sep 2015 Page 4 of 10 SECTION 7 HANDLING AND STORAGE HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator. STORAGE Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION NOTE: Limits/standards shown for guidance only. Follow applicable regulations. No biological limits allocated. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Page 732 of 1235 Page 732 of 1235 Page 732 of 1235 Page 732 of 1235 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 29 Sep 2015 Page 5 of 10 Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Physical State: Solid Form: Semi-fluid Color: Dark Gray Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 0.914 Flammability (Solid, Gas): N/A Flash Point [Method]: >204°C (400°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) [Estimated] Decomposition Temperature: N/D Vapor Density (Air = N/D Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C [Estimated] Evaporation Rate (n-butyl acetate = N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 [Estimated] Solubility in Water: Negligible Viscosity: 220 cSt (220 mm2/sec) at 40 °C I >16 cSt (16 mm2/sec) at 100°C Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: >260°C (500°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt NOTE: Most physical properties above are for the oil component in the material. Page 733 of 1235 Page 733 of 1235 Page 733 of 1235 Page 733 of 1235 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 29 Sep 2015 Page 6 of 10 SECTION 10 STABILITY AND REACTIVITY REACTIVITY: See sub-sections below. STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS Hazard Class Conclusion / Remarks Inhalation Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Ingestion Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Corrosion/Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on assessment of the components. Eye Serious Eye Damage/Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components. Sensitization Respiratory Sensitization: No end point data for material. Not expected to be a respiratory sensitizer. Skin Sensitization: No end point data for material. Not expected to be a skin sensitizer. Based on assessment of the components. Aspiration: Data available. Not expected to be an aspiration hazard. Based on physico-chemical properties of the material. Germ Cell Mutagenicity: No end point data for material. Not expected to be a germ cell mutagen. Based on assessment of the components. Carcinogenicity: No end point data for material. Not expected to cause cancer. Based on assessment of the components. Reproductive Toxicity: No end point data for material. Not expected to be a reproductive toxicant. Based on assessment of the components. Lactation: No end point data for material. Not expected to cause harm to breast-fed children. Specific Target Organ Toxicity (STOT) Single Exposure: No end point data for material. Not expected to cause organ damage from a single exposure. Repeated Exposure: No end point data for Not expected to cause organ damage from prolonged or repeated Page 734 of 1235 Page 734 of 1235 Page 734 of 1235 Page 734 of 1235 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 29 Sep 2015 Page 7 of 10 material. exposure. Based on assessment of the components. OTHER INFORMATION Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. Middle distillates: Carcinogenic in animal tests. Lifetime skin painting tests produced tumors, but the mechanism is due to repeated cycles of skin damage and restorative hyperplasia. This mechanism is considered unlikely in humans where such prolonged skin irritation would not be tolerated. Did not cause mutations In Vitro. Inhalation of vapors did not result in reproductive or developmental effects in laboratory animals. Inhalation of high concentrations in animals resulted in respiratory tract irritation, lung changes and some reduction in lung function. Non-sensitizing in test animals. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Not expected to be harmful to aquatic organisms. MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. Page 735 of 1235 Page 735 of 1235 Page 735 of 1235 Page 735 of 1235 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 29 Sep 2015 Page 8 of 10 SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (DOT): Not Regulated for Land Transport LAND (TDG): Not Regulated for Land Transport SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code Marine Pollutant: No AIR (IATA): Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with OSHA HazCom 2012, 29 CFR 1910.1200. Listed or exempt from listing/notification on the following chemical inventories: AICS, ENCS, IECSC, KECI, PICCS, TSCA Special Cases: Inventory Status Page 736 of 1235 Page 736 of 1235 Page 736 of 1235 Page 736 of 1235 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 29 Sep 2015 Page 9 of 10 NDSL Restrictions Apply EPCRA SECTION 302: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: Chemical Name CAS Number Typical Value ZINC DITHIOPHOSPHATE 68649-42-3 1 - < 2.5% The following ingredients are cited on the lists below: Chemical Name CAS Number List Citations NAPHTHENIC ACIDS, ZINC SALTS 12001-85-3 15 ZINC DITHIOPHOSPHATE 68649-42-3 13, 15, 17, 19 ZINC NEODECANOATE 27253-29-8 15 --REGULATORY LISTS SEARCHED-- 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK 5 = TSCA 4 10 = CA P65 CARC 15 = MI 293 Code key: CARC=Carcinogen; REPRO=Reproductive SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only): H315: Causes skin irritation; Skin Corr/Irritation, Cat 2 H318: Causes serious eye damage; Serious Eye Damage/Irr, Cat 1 H401: Toxic to aquatic life; Acute Env Tox, Cat 2 H402: Harmful to aquatic life; Acute Env Tox, Cat 3 H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2 H412: Harmful to aquatic life with long lasting effects; Chronic Env Tox, Cat 3 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 01: Company Mailing Address information was modified. Section 05: Hazardous Combustion Products information was modified. Page 737 of 1235 Page 737 of 1235 Page 737 of 1235 Page 737 of 1235 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 29 Sep 2015 Page 10 of 10 Section 14: Marine Pollutant information was modified. Section 09: Flammability (Solid, Gas) information was added. Section 16: Revision Information - Implementation of GHS requirements phrase. information was deleted. The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A DGN: 2006163XUS (550276) Copyright 2002 Exxon Mobil Corporation, All rights reserved Page 738 of 1235 Page 738 of 1235 Page 738 of 1235 Page 738 of 1235 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 17 Mar 2015 Page 1 of 10 SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: MOBILGREASE XHP 222 SPECIAL Product Description: Base Oil and Additives Product Code: 2015A0202531, 530550-00, 97G870 Intended Use: Grease COMPANY IDENTIFICATION Supplier: EXXON MOBIL CORPORATION 22777 Springwoods Village Parkway Spring, TX. 77389 USA 24 Hour Health Emergency [PHONE REDACTED] Transportation Emergency Phone [PHONE REDACTED] or [PHONE REDACTED] CHEMTREC Product Technical Information [PHONE REDACTED] MSDS Internet Address http://www.exxon.com, http://www.mobil.com SECTION 2 HAZARDS IDENTIFICATION This material is not hazardous according to regulatory guidelines (see (M)SDS Section 15). Other hazard information: HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200. PHYSICAL / CHEMICAL HAZARDS No significant hazards. HEALTH HAZARDS High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, or respiratory irritation. ENVIRONMENTAL HAZARDS No significant hazards. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. Page 739 of 1235 Page 739 of 1235 Page 739 of 1235 Page 739 of 1235 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 17 Mar 2015 Page 2 of 10 SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS This material is defined as a mixture. Hazardous Substance(s) or Complex Substance(s) required for disclosure Name CAS# Concentration* GHS Hazard Codes BENZENAMINE, N-PHENYL-, REACTION PRODUCTS WITH 68411-46-1 1 - < 5% H402, H412 ZINC DITHIOPHOSPHATE 68649-42-3 1 - < 2.5% H315, H318, H401, H411 * All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. As per paragraph of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and exact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact percentage composition will be provided to health professionals, employees, or designated representatives in accordance with applicable provisions of paragraph SECTION 4 FIRST AID MEASURES INHALATION Under normal conditions of intended use, this material is not expected to be an inhalation hazard. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed Page 740 of 1235 Page 740 of 1235 Page 740 of 1235 Page 740 of 1235 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 17 Mar 2015 Page 3 of 10 spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Aldehydes, Oxides of carbon, Smoke, Fume, Sulfur oxides, Incomplete combustion products FLAMMABILITY PROPERTIES Flash Point [Method]: >204°C (400°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802. PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended. SPILL MANAGEMENT Land Spill: Scrape up spilled material with shovels into a suitable container for recycle or disposal. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Skim from surface. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE Page 741 of 1235 Page 741 of 1235 Page 741 of 1235 Page 741 of 1235 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 17 Mar 2015 Page 4 of 10 HANDLING Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator. STORAGE Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION NOTE: Limits/standards shown for guidance only. Follow applicable regulations. No biological limits allocated. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or Page 742 of 1235 Page 742 of 1235 Page 742 of 1235 Page 742 of 1235 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 17 Mar 2015 Page 5 of 10 manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Physical State: Solid Form: Semi-fluid Color: Dark Gray Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 0.914 Flammability (Solid, Gas): Flash Point [Method]: >204°C (400°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) [Estimated] Decomposition Temperature: N/D Vapor Density (Air = N/D Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C [Estimated] Evaporation Rate (n-butyl acetate = N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 [Estimated] Solubility in Water: Negligible Viscosity: 220 cSt (220 mm2/sec) at 40 °C I >16 cSt (16 mm2/sec) at 100°C Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: >260°C (500°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt NOTE: Most physical properties above are for the oil component in the material. Page 743 of 1235 Page 743 of 1235 Page 743 of 1235 Page 743 of 1235 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 17 Mar 2015 Page 6 of 10 SECTION 10 STABILITY AND REACTIVITY REACTIVITY: See sub-sections below. STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS Hazard Class Conclusion / Remarks Inhalation Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Ingestion Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Corrosion/Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on assessment of the components. Eye Serious Eye Damage/Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components. Sensitization Respiratory Sensitization: No end point data for material. Not expected to be a respiratory sensitizer. Skin Sensitization: No end point data for material. Not expected to be a skin sensitizer. Based on assessment of the components. Aspiration: Data available. Not expected to be an aspiration hazard. Based on physico-chemical properties of the material. Germ Cell Mutagenicity: No end point data for material. Not expected to be a germ cell mutagen. Based on assessment of the components. Carcinogenicity: No end point data for material. Not expected to cause cancer. Based on assessment of the components. Reproductive Toxicity: No end point data for material. Not expected to be a reproductive toxicant. Based on assessment of the components. Lactation: No end point data for material. Not expected to cause harm to breast-fed children. Specific Target Organ Toxicity (STOT) Single Exposure: No end point data for material. Not expected to cause organ damage from a single exposure. Repeated Exposure: No end point data for material. Not expected to cause organ damage from prolonged or repeated exposure. Based on assessment of the components. Page 744 of 1235 Page 744 of 1235 Page 744 of 1235 Page 744 of 1235 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 17 Mar 2015 Page 7 of 10 OTHER INFORMATION Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. Middle distillates: Carcinogenic in animal tests. Lifetime skin painting tests produced tumors, but the mechanism is due to repeated cycles of skin damage and restorative hyperplasia. This mechanism is considered unlikely in humans where such prolonged skin irritation would not be tolerated. Did not cause mutations In Vitro. Inhalation of vapors did not result in reproductive or developmental effects in laboratory animals. Inhalation of high concentrations in animals resulted in respiratory tract irritation, lung changes and some reduction in lung function. Non-sensitizing in test animals. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material Not expected to be harmful to aquatic organisms. MOBILITY Base oil component Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. SECTION 13 DISPOSAL CONSIDERATIONS Page 745 of 1235 Page 745 of 1235 Page 745 of 1235 Page 745 of 1235 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 17 Mar 2015 Page 8 of 10 Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (DOT): Not Regulated for Land Transport LAND (TDG): Not Regulated for Land Transport SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code Marine Pollutant: No AIR (IATA): Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with OSHA HazCom 2012, 29 CFR 1910.1200. Listed or exempt from listing/notification on the following chemical inventories: AICS, ENCS, IECSC, KECI, PICCS, TSCA Special Cases: Inventory Status Page 746 of 1235 Page 746 of 1235 Page 746 of 1235 Page 746 of 1235 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 17 Mar 2015 Page 9 of 10 NDSL Restrictions Apply EPCRA SECTION 302: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: Chemical Name CAS Number Typical Value ZINC DITHIOPHOSPHATE 68649-42-3 1 - < 2.5% The following ingredients are cited on the lists below: Chemical Name CAS Number List Citations NAPHTHENIC ACIDS, ZINC SALTS 12001-85-3 15 ZINC DITHIOPHOSPHATE 68649-42-3 13, 15, 17, 19 ZINC NEODECANOATE 27253-29-8 15 --REGULATORY LISTS SEARCHED-- 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK 5 = TSCA 4 10 = CA P65 CARC 15 = MI 293 Code key: CARC=Carcinogen; REPRO=Reproductive SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only): H315: Causes skin irritation; Skin Corr/Irritation, Cat 2 H318: Causes serious eye damage; Serious Eye Damage/Irr, Cat 1 H401: Toxic to aquatic life; Acute Env Tox, Cat 2 H402: Harmful to aquatic life; Acute Env Tox, Cat 3 H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2 H412: Harmful to aquatic life with long lasting effects; Chronic Env Tox, Cat 3 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Updates made in accordance with implementation of GHS requirements. Page 747 of 1235 Page 747 of 1235 Page 747 of 1235 Page 747 of 1235 ---PAGE BREAK--- Product Name: MOBILGREASE XHP 222 SPECIAL Revision Date: 17 Mar 2015 Page 10 of 10 The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A DGN: 2006163XUS (550276) Copyright 2002 Exxon Mobil Corporation, All rights reserved Page 748 of 1235 Page 748 of 1235 Page 748 of 1235 Page 748 of 1235 ---PAGE BREAK--- [HOME] [SEARCH] [PREV LIST] [CURR LIST] [NEXT LIST] [FIRST DOC] [PREV DOC] [CURR DOC] [NEXT DOC] [LAST DOC] [BOTTOM] [NEXT HIT] [HELP] Print View 510438-00 510438-00 MOBILUBE HD LS 80W-90 MATERIAL SAFETY DATA BULLETIN 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: MOBILUBE HD LS 80W-90 SUPPLIER: EXXONMOBIL OIL CORPORATION 3225 GALLOWS RD. FAIRFAX, VA 22037 24 - Hour Emergency (call collect): [PHONE REDACTED] Product and MSDS Information: [PHONE REDACTED] [PHONE REDACTED] CHEMTREC: [PHONE REDACTED] [PHONE REDACTED] 2. COMPOSITION/INFORMATION ON INGREDIENTS CHEMICAL NAMES AND SYNONYMS: PET. HYDROCARBONS AND ADDITIVES INGREDIENTS CONSIDERED HAZARDOUS TO HEALTH: This product is not formulated to contain ingredients which have exposure limits established by U.S. agencies. It is not hazardous to health as defined by the European Union Dangerous Substances/Preparations Directives. See Section 15 for a regulatory analysis of the ingredients. See Section 15 for European Label Information. See Section 8 for exposure limits (if applicable). 3. HAZARDS IDENTIFICATION US OSHA HAZARD COMMUNICATION STANDARD: Product assessed in accordance with OSHA 29 CFR 1910.1200 and determined not to be hazardous. (1 of 7) [11/21/2001 11:06:34 PM] Page 749 of 1235 Page 749 of 1235 Page 749 of 1235 Page 749 of 1235 ---PAGE BREAK--- EFFECTS OF OVEREXPOSURE: No significant effects expected. EMERGENCY RESPONSE DATA: Brown Liquid. DOT ERG No. : NA 4. FIRST AID MEASURES EYE CONTACT: Flush thoroughly with water. If irritation occurs, call a physician. SKIN CONTACT: Wash contact areas with soap and water. INHALATION: Remove from further exposure. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with bag-valve-mask device or use mouth-to-mouth resuscitation. INGESTION: Not expected to be a problem. However, if greater than 1/2 liter (pint) ingested, seek medical attention. 5. FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA: Carbon dioxide, foam, dry chemical and water fog. SPECIAL FIRE FIGHTING PROCEDURES: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposure. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. SPECIAL PROTECTIVE EQUIPMENT: For fires in enclosed areas, fire fighters must use self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS: None. Flash Point C(F): 216(421) (ASTM D-92). Flammable limits - LEL: NA, UEL: NA. NFPA HAZARD ID: Health: 0, Flammability: 1, Reactivity: 0 HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide. 6. ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES: Report spills as required to appropriate authorities. U. S. Coast Guard regulations require immediate reporting of spills that could reach any waterway including intermittent dry creeks. Report spill to Coast Guard toll free number (800) 424-8802. In case of accident or road spill notify CHEMTREC (800) 424-9300. PROCEDURES IF MATERIAL IS RELEASED OR SPILLED: Adsorb on fire retardant treated sawdust, diatomaceous earth, etc. Shovel up and dispose of at an appropriate waste disposal facility in accordance with current applicable laws and regulations, and product characteristics at time of disposal. ENVIRONMENTAL PRECAUTIONS: Prevent spills from entering storm sewers (2 of 7) [11/21/2001 11:06:34 PM] Page 750 of 1235 Page 750 of 1235 Page 750 of 1235 Page 750 of 1235 ---PAGE BREAK--- or drains and contact with soil. PERSONAL PRECAUTIONS: See Section 8 7. HANDLING AND STORAGE HANDLING: No special precautions are necessary beyond normal good hygiene practices. See Section 8 for additional personal protection advice when handling this product. STORAGE: Do not store in open or unlabelled containers. Store away from strong oxidizing agents or combustible material. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION VENTILATION: Use in well ventilated area. RESPIRATORY PROTECTION: No special requirements under ordinary conditions of use and with adequate ventilation. EYE PROTECTION: Normal industrial eye protection practices should be employed. SKIN PROTECTION: No special equipment required. However, good personal hygiene practices should always be followed. EXPOSURE LIMITS: This product does not contain any components which have recognized exposure limits. However, a exposure limit of 5.00 mg/m3 is suggested for oil mist. 9. PHYSICAL AND CHEMICAL PROPERTIES Typical physical properties are given below. Consult Product Data Sheet for specific details. APPEARANCE: Liquid COLOR: Brown ODOR: Mild ODOR THRESHOLD-ppm: NE pH: NA BOILING POINT C(F): > 316(600) MELTING POINT C(F): NA FLASH POINT C(F): 216(421) (ASTM D-92) FLAMMABILITY: NE AUTO FLAMMABILITY: NE EXPLOSIVE PROPERTIES: NA OXIDIZING PROPERTIES: NA VAPOR PRESSURE-mmHg 20 C: < 0.1 VAPOR DENSITY: > 2.0 EVAPORATION RATE: NE RELATIVE DENSITY, 15/4 C: 0.893 (3 of 7) [11/21/2001 11:06:34 PM] Page 751 of 1235 Page 751 of 1235 Page 751 of 1235 Page 751 of 1235 ---PAGE BREAK--- SOLUBILITY IN WATER: Negligible PARTITION COEFFICIENT: > 3.5 VISCOSITY AT 40 C, cSt: 135.0 VISCOSITY AT 100 C, cSt: 14.6 POUR POINT C(F): -18(0) FREEZING POINT C(F): NE VOLATILE ORGANIC COMPOUND: NE NA=NOT APPLICABLE NE=NOT ESTABLISHED D=DECOMPOSES FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING REPRESENTATIVE 10. STABILITY AND REACTIVITY STABILITY (THERMAL, LIGHT, ETC.): Stable. CONDITIONS TO AVOID: Extreme heat. INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide. HAZARDOUS POLYMERIZATION: Will not occur. 11. TOXICOLOGICAL DATA ---ACUTE TOXICOLOGY--- ORAL TOXICITY (RATS): Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. DERMAL TOXICITY (RABBITS): Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. INHALATION TOXICITY (RATS): Not established EYE IRRITATION (RABBITS): Practically non-irritating. (Draize score: greater than 6 but 15 or less). ---Based on testing of similar products and/or the components. SKIN IRRITATION (RABBITS): Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than ---Based on testing of similar products and/or the components. ---SUBCHRONIC TOXICOLOGY (SUMMARY)--- Severely solvent refined and severely hydrotreated mineral base oils have been tested at [PREV HIT] [NEXT HIT]Mobil Environmental and Health Sciences Laboratory by dermal application to rats 5 days/week for 90 days at doses significantly higher than those expected during normal industrial exposure. Extensive evaluations including microscopic examination of internal organs and clinical chemistry of body fluids, showed no adverse effects. ---CHRONIC TOXICOLOGY (SUMMARY)--- The base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic mouse skin painting studies of (4 of 7) [11/21/2001 11:06:34 PM] Page 752 of 1235 Page 752 of 1235 Page 752 of 1235 Page 752 of 1235 ---PAGE BREAK--- severely treated oils showed no evidence of carcinogenic effects. These results are confirmed on a continuing basis using various screening methods such as the [PREV HIT] [NEXT HIT]Mobil Modified Ames Test and IP-346. 12. ECOLOGICAL INFORMATION ENVIRONMENTAL FATE AND EFFECTS: This product is expected to be inherently biodegradable. There is no evidence to suggest bioaccumulation will occur. It is not expected to be toxic to aquatic organisms. Accidental spillage may lead to penetration in the soil and groundwater. However, there is no evidence that this would cause adverse ecological effects. 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Product is suitable for burning in an enclosed, controlled burner for fuel value or disposal by supervised incineration. Such burning may be limited pursuant to the Resource Conservation and Recovery Act. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of at an appropriate government waste disposal facility. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. RCRA INFORMATION: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrosivity, or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. 14. TRANSPORT INFORMATION USA DOT: NOT REGULATED BY USA DOT. RID/ADR: NOT REGULATED BY RID/ADR. IMO: NOT REGULATED BY IMO. IATA: NOT REGULATED BY IATA. (5 of 7) [11/21/2001 11:06:34 PM] Page 753 of 1235 Page 753 of 1235 Page 753 of 1235 Page 753 of 1235 ---PAGE BREAK--- 15. REGULATORY INFORMATION Governmental Inventory Status: All components comply with TSCA, EINECS/ELINCS, AICS, and MITI. EU Labeling: EU labeling not required. U.S. Superfund Amendments and Reauthorization Act (SARA) Title III: This product contains no "EXTREMELY HAZARDOUS SUBSTANCES". SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. This product contains no chemicals subject to the supplier notification requirements of SARA (313) toxic release program. The following product ingredients are cited on the lists below: CHEMICAL NAME CAS NUMBER LIST CITATIONS NO REPORTABLE INGREDIENTS REGULATORY LISTS SEARCHED 1=ACGIH ALL 6=IARC 1 11=TSCA 4 16=CA P65 CARC 21=LA RTK 2=ACGIH A1 7=IARC 2A 12=TSCA 5a2 17=CA P65 REPRO 22=MI 293 3=ACGIH A2 8=IARC 2B 13=TSCA 5e 18=CA RTK 23=MN RTK 4=NTP CARC 9=OSHA CARC 14=TSCA 6 19=FL RTK 24=NJ RTK 5=NTP SUS 10=OSHA Z 15=TSCA 12b 20=IL RTK 25=PA RTK 26=RI RTK Code key: CARC=Carcinogen; SUS=Suspected Carcinogen; REPRO=Reproductive 16. OTHER INFORMATION USE: AUTOMOTIVE GEAR OIL NOTE: PRODUCTS OF EXXON [PREV HIT] [NEXT HIT]MOBIL CORPORATION AND ITS AFFILIATED COMPANIES ARE NOT FORMULATED TO CONTAIN PCBS. Please call the Customer Response Center on [PHONE REDACTED] for formulation disclosure. For Internal Use Only: MHC: 1* 1* NE 1* MPPEC: A, TRN: 510438-00, CMCS97: 977636, REQ: US - MARKETING, SAFE USE: L EHS Approval Date: 22MAY2001 Legally required information is given in accordance with applicable Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for particular uses are beyond our control; all risks of use of the product are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF (6 of 7) [11/21/2001 11:06:34 PM] Page 754 of 1235 Page 754 of 1235 Page 754 of 1235 Page 754 of 1235 ---PAGE BREAK--- MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO THE USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a recommendation for uses which infringe valid patents or as extending any license under valid patents. Appropiate warnings and safe handling procedures should be providedto handlers and users. Use or re- transmission of the information contained herein in any other format than the format as presented is strictly prohibited. ExxonMobil neither represents nor warrants that the format, content or product formulas contained in this document comply with the laws of any other country except the United States of America. Copyright 1996 ExxonMobil Corporation, All rights reserved [HOME] [SEARCH] [PREV LIST] [CURR LIST] [NEXT LIST] [FIRST DOC] [PREV DOC] [CURR DOC] [NEXT DOC] [LAST DOC] [TOP] [PREV HIT] [HELP] (7 of 7) [11/21/2001 11:06:34 PM] Page 755 of 1235 Page 755 of 1235 Page 755 of 1235 Page 755 of 1235 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 02-May-2014 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 92964 Product name Moly Coat Recommended Use Lubricant Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Eyes. Skin contact. Inhalation. Ingestion. Potential health effects Eyes May cause the following effects:. Irritation. Pain. Tearing. Reddening. Swelling. Stinging sensation. Feeling like that of fine dust in the eye. Skin Repeated or prolonged exposure may cause:. Skin Irritation. Defatting. Dermatitis. Chronic exposure causes drying effect on the skin . Inhalation Harmful by inhalation. Avoid breathing vapors or mists. Repeated or prolonged exposure may cause the following effects:. Headaches. Dizziness. Nausea. Decreased blood pressure. Changes in heart rate. Cyanosis. Central nervous system damage. Lung damage. Kidney damage. Liver damage. Ingestion No hazard under normal industrial and institutional use. Harmful or fatal if swallowed. Can burn mouth, throat, and stomach. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Propane/Isobutane/N- Butane 68476-86-8 40-50 2-Propanone 67-64-1 20-30 1330-20-7 10-20 Isopropyl Alcohol 67-63-0 1-10 100-41-4 1-10 Molybdenum sulfide 1317-33-5 1-10 4. FIRST AID MEASURES Eye contact Flush eyes immediately with large amounts of water. Seek medical attention if irritation persists. Skin contact Wash off immediately with soap and plenty of water. Seek medical attention if irritation persists. Ingestion Seek medical attention immediately. Do not induce vomiting. Give victim a glass of water or milk. Contact physician or poison control center immediately. Do not give anything by mouth to an unconscious person. Inhalation Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Immediate medical attention is required. 5. FIRE FIGHTING MEASURES Flash point °C -96.11 Flash point °F -141 Method Pensky-Martens C.C. Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 12.8 Lower 0.8 Specific Information for Aerosol Products Flame extension Unknown Flashback Unknown Suitable extinguishing media Alcohol foam. Carbon dioxide (CO2). Dry chemical powder. Foam. Water fog. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 1 / 4 Emergency Overview Vapors may be irritating to eyes, nose, throat, and lungs. Vapors may cause flash fire or explosion. Page 756 of 1235 Page 756 of 1235 Page 756 of 1235 Page 756 of 1235 ---PAGE BREAK--- Fire and Explosion Hazards Containers may vent or burst under extreme or prolonged fire conditions. Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Empty containers contain residue and/or vapors. Do not weld, cut, pressurize, braze, solder, drill, grind, or expose such containers to heat, sparks, flame, static electricity, or other sources of ignition. They may explode and cause injury or death. Sensitivity to shock No information available. Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Soak up with noncombustible inert absorbent material. Place in suitable container for disposal as hazardous waste. 7. HANDLING AND STORAGE Handling Thoroughly wash hands and exposed skin after handling. Wash hands with soap and water before eating, drinking, smoking, or using toilet facilities. Control airborne concentration below exposure level. Use only according to label directions. Handle empty containers as if they were full. Avoid breathing vapors. Do not get on skin or in eyes. Storage Keep away from heat. Keep away from open flames, hot surfaces and sources of ignition. Do not freeze. NFPA Storage Code Store as Level 3 Aerosol (NFPA 30B) 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Propane/Isob utane/N- Butane - - - - 2-Propanone 1000 ppm 2400 mg/m3 - 500 ppm 750 ppm ene 100 ppm 435 mg/m3 - 100 ppm 150 ppm Isopropyl Alcohol 400 ppm 980 mg/m3 - 200 ppm 400 ppm 100 ppm 435 mg/m3 - 20 ppm - Molybdenum sulfide - - - - Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Other precautions Avoid contact with skin, eyes and clothing. Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Protection provided by air purifying respirators is limited. Use a positive pressure supplied air respirator. if there is any potential for an uncontrolled release:. where exposure levels are not known. or other circumstances where an air purifying respirator (P100) may not provide adequate protection . Seek professional advise prior to respirator selection and use. Hand Protection Chemical resistant gloves. Consult glove manufacturer to determine the proper type for a specific operation. Eye protection Wear safety glasses with side shields. Skin and body protection Wear appropriate clothing to minimize skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Black - Green Odor Solvent Odor Threshold No information available pH Not Applicable Specific Gravity 0.6752 Vapor pressure No data available Vapor density heavier than air Evaporation Rate Is faster than Butyl Acetate Water solubility Negligible VOC Content 68.6%; 369 gm/liter; 3.08 lbs/gal Partition Coefficient (n-octanol/water) No data available Boiling point/range °C -30.6 - 175 Boiling point/range °F -23 - 284 Melting point/range °C No data available Melting point/range °F No data available Flash point °C -96.11 Flash point °F -141 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Contact with ignition sources, hot-glowing surfaces, electrical arcs, sparks, and open flame. Do not use near welding arcs. Incompatability Strong acids. Alkalies. Oxidizers. Page 2 / 4 Product code 92964 Product name Moly Coat Page 757 of 1235 Page 757 of 1235 Page 757 of 1235 Page 757 of 1235 ---PAGE BREAK--- Hazardous Decomposition Products Carbon oxides. Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Propane/Isobutan e/N-Butane 68476-86-8 - - - 2-Propanone 67-64-1 - - 50100 mg/m3 1330-20-7 4300 mg/kg - 47635 mg/L Isopropyl Alcohol 67-63-0 4396 mg/kg 12800 mg/kg 16000 ppm 100-41-4 3500 mg/kg 15354 mg/kg 17.2 mg/L Molybdenum sulfide 1317-33-5 - - 2820 mg/m3 Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity Possible risks of irreversible effects . Prolonged exposure may cause chronic effects . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects Long term exposure to vapor may cause lung damage. Long term exposure to vapor may cause kidney damage. Central nervous system. Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Propane/Isob utane/N- Butane Not Listed Not Listed Not Listed Not Listed Not Listed 2-Propanone A4 Not Listed Not Listed Not Listed Not Listed ene A4 Not Listed Not Listed Not Listed Not Listed Isopropyl Alcohol A4 Not Listed Not Listed Not Listed Not Listed A3 Group 2B Not Listed Not Listed Listed Molybdenum sulfide Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Disposal Information Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT Consumer commodity, ORM-D. TDG Consumer commodity, ORM-D. 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Listed Isopropyl Alcohol Listed Listed State Regulations Page 3 / 4 Microtox Data Photobacterium phosphoreum EC50=9.68 mg/L (30 min) Nitrosomonas EC50=96 mg/L (24 h) Product name Moly Coat Water Flea Data Daphnia magna EC501.8 - 2.4 mg/L (48 h) Microtox Data Photobacterium phosphoreum EC50=0.0084 mg/L (24 h) Microtox Data Photobacterium phosphoreum EC50=14500 mg/L (15 min) Water Flea Data water flea hEC50 48 (3.82 mg/L) Gammarus lacustris hLC50 48 (0.6 mg/L) water flea hEC50 48 (3.82 mg/L) Isopropyl Alcohol Product code 92964 Microtox Data Photobacterium phosphoreum EC50=35390 mg/L (5 min) Water Flea Data Daphnia magna EC5010294 - 17704 mg/L (48 h) Daphnia magna EC5012600 - 12700 mg/L (48 h) Water Flea Data Daphnia magna EC50=13299 mg/L (48 h) 2-Propanone Page 758 of 1235 Page 758 of 1235 Page 758 of 1235 Page 758 of 1235 ---PAGE BREAK--- Chemical Name New Jersey - RTK - RTK California Prop. 65 Propane/Isobutane/N- Butane Not Listed Not Listed Not Listed 2-Propanone Not Listed Listed Not Listed Not Listed Listed Not Listed Isopropyl Alcohol Not Listed Listed Not Listed Not Listed Listed Carcinogen Molybdenum sulfide Not Listed Not Listed Not Listed WARNING: This product contains a chemical(s) known to the state of California to cause cancer and birth defects or other reproductive harm International Inventories Chemical Name EINECS DSL NDSL TSCA Propane/Isobutane/N- Butane X X - X 2-Propanone X X - X X X - X Isopropyl Alcohol X X - X X X - X Molybdenum sulfide X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. OTHER INFORMATION HMIS Health - 2 Flammability - 4 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product code 92964 Product name Moly Coat Page 759 of 1235 Page 759 of 1235 Page 759 of 1235 Page 759 of 1235 ---PAGE BREAK--- 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product code 92964 Product name Moly Coat Recommended Use Lubricant Supplier Lawson Products, Inc. 1666 East Touhy Avenue Des Plaines, IL 60018 (847)-827-9666 Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Eyes. Skin contact. Inhalation. Ingestion. Potential health effects Eyes May cause the following effects:. Irritation. Pain. Tearing. Reddening. Swelling. Stinging sensation. Feeling like that of fine dust in the eye. Skin Repeated or prolonged exposure may cause:. Skin Irritation. Defatting. Dermatitis. Chronic exposure causes drying effect on the skin . Inhalation Harmful by inhalation. Avoid breathing vapors or mists. Repeated or prolonged exposure may cause the following effects. Headaches. Dizziness. Nausea. Decreased blood pressure. Changes in heart rate. Cyanosis. Central nervous system damage. Lung damage. Kidney damage. Liver damage. Ingestion No hazard under normal industrial and institutional use. Harmful or fatal if swallowed. Can burn mouth, throat, and stomach. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Propane/Isobutane/N-Butane 68476-86-8 40-50 2-Propanone 67-64-1 20-30 1330-20-7 10-20 Isopropyl Alcohol 67-63-0 1-10 100-41-4 1-10 Molybdenum sulfide 1317-33-5 1-10 Page 1 / 8 Revision Date 10-May-2010 Material Safety Data Sheet Emergency Overview Vapors may be irritating to eyes, nose, throat, and lungs. Vapors may cause flash fire or explosion. Odor Solvent Form Aerosol Color Black - Green Page 760 of 1235 Page 760 of 1235 Page 760 of 1235 Page 760 of 1235 ---PAGE BREAK--- 4. FIRST AID MEASURES Eye contact Flush eyes immediately with large amounts of water. Seek medical attention if irritation persists. Skin contact Wash off immediately with soap and plenty of water. Seek medical attention if irritation persists. Ingestion Seek medical attention immediately. Do not induce vomiting. Give victim a glass of water or milk. Contact physician or poison control center immediately. Do not give anything by mouth to an unconscious person. Inhalation Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Immediate medical attention is required. 5. FIRE FIGHTING MEASURES Flash point °C -96.11 Flash point °F -141 Method Pensky-Martens C.C. Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 12.8 Lower 0.8 Specific Information for Aerosol Products Flame extension Unknown Flashback Unknown Suitable extinguishing media Alcohol foam. Carbon dioxide (CO2). Dry chemical. Foam. Water fog. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fire and Explosion Hazards Containers may vent or burst under extreme or prolonged fire conditions. Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Empty containers contain residue and/or vapors. Do not weld, cut, pressurize, braze, solder, drill, grind, or expose such containers to heat, sparks, flame, static electricity, or other sources of ignition. They may explode and cause injury or death. 6. ACCIDENTAL RELEASE MEASURES Page 2 / 8 Product code 92964 Sensitivity to shock No information available. Product name Moly Coat Sensitivity to static discharge No information available. Page 761 of 1235 Page 761 of 1235 Page 761 of 1235 Page 761 of 1235 ---PAGE BREAK--- 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Soak up with noncombustible inert absorbent material. Place in suitable container for disposal as hazardous waste. 7. HANDLING AND STORAGE Handling Thoroughly wash hands and exposed skin after handling. Wash hands with soap and water before eating, drinking, smoking, or using toilet facilities. Control airborne concentration below exposure level. Use only according to label directions. Handle empty containers as if they were full. Avoid breathing vapors. Do not get on skin or in eyes. Storage Keep away from heat. Keep away from open flames, hot surfaces and sources of ignition. Do not freeze. NFPA Storage Code Store as Level 3 Aerosol (NFPA 30B) Page 3 / 8 Product name Moly Coat Product code 92964 Page 762 of 1235 Page 762 of 1235 Page 762 of 1235 Page 762 of 1235 ---PAGE BREAK--- 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Propane/Isobutane/N- Butane - - - - 2-Propanone 1000 ppm 2400 mg/m3 - 500 ppm 750 ppm 100 ppm 435 mg/m3 - 100 ppm 150 ppm Isopropyl Alcohol 400 ppm 980 mg/m3 - 200 ppm 400 ppm 100 ppm 435 mg/m3 - 100 ppm 125 ppm Molybdenum sulfide - - - - Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Other precautions Avoid contact with skin, eyes and clothing Personal protective equipment Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Protection provided by air purifying respirators is limited. Use a positive pressure supplied air respirator. if there is any potential for an uncontrolled release. where exposure levels are not known. or other circumstances where an air purifying respirator (P100) may not provide adequate protection . Seek professional advise prior to respirator selection and use. Hand Protection Chemical resistant gloves. Consult glove manufacturer to determine the proper type for a specific operation. Eye protection Wear safety glasses with side shields. Skin and body protection Wear appropriate clothing to minimize skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 4 / 8 Product name Moly Coat Product code 92964 Page 763 of 1235 Page 763 of 1235 Page 763 of 1235 Page 763 of 1235 ---PAGE BREAK--- 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Contact with ignition sources, hot-glowing surfaces, electrical arcs, sparks, and open flame. Do not use near welding arcs. Incompatability Strong acids. Alkalis. Oxidizers. Hazardous Decomposition Products Carbon oxides. Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat) LD50 (dermal,rat/rabbit) LC50 (inhalation,rat) Propane/Isobutane/N-Butane 68476-86-8 - - - 2-Propanone 67-64-1 5800 mg/kg - - 1330-20-7 4300 mg/kg 1700 mg/kg 47635 mg/L 5000 ppm Isopropyl Alcohol 67-63-0 4396 mg/kg 12800 mg/kg 12870 mg/kg 72.6 mg/L 100-41-4 3500 mg/kg 15354 mg/kg 17.2 mg/L Molybdenum sulfide 1317-33-5 - - 2820 mg/m3 Page 5 / 8 Color Vapor density heavier than air Black - Green Evaporation Rate Is faster than Butyl Acetate Product name Moly Coat VOC Content 68.6%; 369 gm/liter; 3.08 lbs/gal Odor Water solubility Negligible Solvent Partition Coefficient (n-octanol/water) No data available Odor Threshold No information available Boiling point/range °C -30.6 - 175 Form Boiling point/range °F -23 - 284 pH Melting point/range °C No data available Not Applicable Melting point/range °F No data available Aerosol Flash point °C -96.11 Specific Gravity Flash point °F -141 0.6752 Product code 92964 Vapor pressure No data available Page 764 of 1235 Page 764 of 1235 Page 764 of 1235 Page 764 of 1235 ---PAGE BREAK--- Synergistic Products None known Potential health effects Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinogens IARC NTP - Known Carcinogens NTP - Suspected Human Carcinogens OSHA RTK Carcinogens Propane/Isobutane/N-Butane Not Listed Not Listed Not Listed Not Listed Not Listed 2-Propanone Listed Not Listed Not Listed Not Listed Not Listed Listed Not Listed Not Listed Not Listed Not Listed Isopropyl Alcohol Listed Not Listed Not Listed Not Listed Not Listed Listed Group 2B Not Listed Not Listed Listed Molybdenum sulfide Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Page 6 / 8 Microtox Data Photobacterium phosphoreum EC50=14500 mg/L (15 min) Product name Moly Coat Water Flea Data water flea hEC50 48 (0.0039 mg/L) water flea hEC50 48 (12700 mg/L) Daphnia magna hEC50 48 (12600 mg/L) water flea hEC50 48 (0.0039 mg/L) Chronic toxicity Possible risks of irreversible effects . Prolonged exposure may cause chronic effects . Mutagenic effects None known Microtox Data Photobacterium phosphoreum EC50=0.0084 mg/L (24 h) Product code 92964 Water Flea Data water flea hEC50 48 (3.82 mg/L) Gammarus lacustris hLC50 48 (0.6 mg/L) water flea hEC50 48 (3.82 mg/L) Teratogenic effects None known Isopropyl Alcohol Sensitization None known Microtox Data Photobacterium phosphoreum EC50=35390 mg/L (5 min) Reproductive toxicity None known 2-Propanone Target Organ Effects Long term exposure to vapor may cause lung damage. Long term exposure to vapor may cause kidney damage. Central nervous system. Page 765 of 1235 Page 765 of 1235 Page 765 of 1235 Page 765 of 1235 ---PAGE BREAK--- 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Disposal Information Dispose in accordance with federal, state, and local regulations. 14. TRANSPORT INFORMATION DOT Consumer commodity, ORM-D TDG Consumer commodity, ORM-D IMDG/IMO UN1950 Aerosols, flammable, 2.1 IATA ID8000 Consumer commodity, 9 MEX UN1950 Aerosols, flammable, 2.1 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Listed Isopropyl Alcohol Listed Listed Chemical Name New Jersey - RTK - RTK California Prop. 65 Propane/Isobutane/N-Butane Not Listed Not Listed Not Listed 2-Propanone Not Listed Listed Not Listed Not Listed Listed Not Listed Isopropyl Alcohol Not Listed Listed Not Listed Not Listed Listed Carcinogen Molybdenum sulfide Not Listed Not Listed Not Listed Page 7 / 8 Water Flea Data Daphnia magna hEC50 48 (1.8 - 2.4 mg/L) Product code 92964 Product name Moly Coat Microtox Data Photobacterium phosphoreum EC50=9.68 mg/L (30 min) Nitrosomonas EC50=96 mg/L (24 h) Water Flea Data Daphnia magna hEC50 48 (13299 mg/L) Page 766 of 1235 Page 766 of 1235 Page 766 of 1235 Page 766 of 1235 ---PAGE BREAK--- WARNING: This product contains a chemical(s) known to the state of California to cause cancer and birth defects or other reproductive harm Chemical Name EINECS DSL NDSL TSCA Propane/Isobutane/N-Butane X X - X 2-Propanone X X - X X X - X Isopropyl Alcohol X X - X X X - X Molybdenum sulfide X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations 16. OTHER INFORMATION Prepared By J. Cameron, Regulatory Affairs Coordinator The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 8 / 8 NFPA HMIS Product code 92964 Product name Moly Coat - Flammability - Health 2 Health Flammability 4 Reactivity - Physical Hazard 0 Page 767 of 1235 Page 767 of 1235 Page 767 of 1235 Page 767 of 1235 ---PAGE BREAK--- Material Safety Data Sheet Revision Date 01-May-2013 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product code 92964 Product name Moly Coat Recommended Use Lubricant Supplier Lawson Products, Inc. 8770 W.Bryn Mawr Ave.- Suite 900 Chicago, IL 60631 1-[PHONE REDACTED] Emergency telephone number (888) 426-4851 2. HAZARDS IDENTIFICATION Aggravated Medical Conditions None Known Principal Routes of Exposure Eyes. Skin contact. Inhalation. Ingestion. Potential health effects Eyes May cause the following effects:. Irritation. Pain. Tearing. Reddening. Swelling. Stinging sensation. Feeling like that of fine dust in the eye. Skin Repeated or prolonged exposure may cause:. Skin Irritation. Defatting. Dermatitis. Chronic exposure causes drying effect on the skin . Inhalation Harmful by inhalation. Avoid breathing vapors or mists. Repeated or prolonged exposure may cause the following effects:. Headaches. Dizziness. Nausea. Decreased blood pressure. Changes in heart rate. Cyanosis. Central nervous system damage. Lung damage. Kidney damage. Liver damage. Ingestion No hazard under normal industrial and institutional use. Harmful or fatal if swallowed. Can burn mouth, throat, and stomach. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Propane/Isobutane/N- Butane 68476-86-8 40-50 2-Propanone 67-64-1 20-30 1330-20-7 10-20 Isopropyl Alcohol 67-63-0 1-10 100-41-4 1-10 Molybdenum sulfide 1317-33-5 1-10 4. FIRST AID MEASURES Eye contact Flush eyes immediately with large amounts of water. Seek medical attention if irritation persists. Skin contact Wash off immediately with soap and plenty of water. Seek medical attention if irritation persists. Ingestion Seek medical attention immediately. Do not induce vomiting. Give victim a glass of water or milk. Contact physician or poison control center immediately. Do not give anything by mouth to an unconscious person. Inhalation Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Immediate medical attention is required. 5. FIRE FIGHTING MEASURES Flash point °C -96.11 Flash point °F -141 Method Pensky-Martens C.C. Autoignition temperature °C No data available Autoignition temperature °F No data available Flammability Limits in Air) Upper 12.8 Lower 0.8 Specific Information for Aerosol Products Flame extension Unknown Flashback Unknown Suitable extinguishing media Alcohol foam. Carbon dioxide (CO2). Dry chemical powder. Foam. Water fog. Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fire and Explosion Hazards Containers may vent or burst under extreme or prolonged fire conditions. Vapors are heavier than air and may travel along the ground to an ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted cigarettes, heating elements, electric motors, sparks from electrical switches. Empty containers contain residue and/or vapors. Do not weld, cut, pressurize, braze, solder, drill, grind, or expose such containers to heat, sparks, flame, static electricity, or other sources of ignition. They may explode and cause injury or death. Sensitivity to shock No information available. Page 1 / 4 Emergency Overview Vapors may be irritating to eyes, nose, throat, and lungs. Vapors may cause flash fire or explosion. Page 768 of 1235 Page 768 of 1235 Page 768 of 1235 Page 768 of 1235 ---PAGE BREAK--- Sensitivity to static discharge No information available. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Soak up with noncombustible inert absorbent material. Place in suitable container for disposal as hazardous waste. 7. HANDLING AND STORAGE Handling Thoroughly wash hands and exposed skin after handling. Wash hands with soap and water before eating, drinking, smoking, or using toilet facilities. Control airborne concentration below exposure level. Use only according to label directions. Handle empty containers as if they were full. Avoid breathing vapors. Do not get on skin or in eyes. Storage Keep away from heat. Keep away from open flames, hot surfaces and sources of ignition. Do not freeze. NFPA Storage Code Store as Level 3 Aerosol (NFPA 30B) 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL) Propane/Isob utane/N- Butane - - - - 2-Propanone 1000 ppm 2400 mg/m3 - 500 ppm 750 ppm ene 100 ppm 435 mg/m3 - 100 ppm 150 ppm Isopropyl Alcohol 400 ppm 980 mg/m3 - 200 ppm 400 ppm 100 ppm 435 mg/m3 - 20 ppm - Molybdenum sulfide - - - - Ventilation and Environmental Controls Use enough ventilation, local exhaust at the work area, general, or both, to keep below the TLV's in the worker's breathing zone and the general area. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Other precautions Avoid contact with skin, eyes and clothing. Respiratory protection If the exposure limits are exceeded, a NIOSH/MSHA approved respirator is recommended. Protection provided by air purifying respirators is limited. Use a positive pressure supplied air respirator. if there is any potential for an uncontrolled release:. where exposure levels are not known. or other circumstances where an air purifying respirator (P100) may not provide adequate protection . Seek professional advise prior to respirator selection and use. Hand Protection Chemical resistant gloves. Consult glove manufacturer to determine the proper type for a specific operation. Eye protection Wear safety glasses with side shields. Skin and body protection Wear appropriate clothing to minimize skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Aerosol Color Black - Green Odor Solvent Odor Threshold No information available pH Not Applicable Specific Gravity 0.6752 Vapor pressure No data available Vapor density heavier than air Evaporation Rate Is faster than Butyl Acetate Water solubility Negligible VOC Content 68.6%; 369 gm/liter; 3.08 lbs/gal Partition Coefficient (n-octanol/water) No data available Boiling point/range °C -30.6 - 175 Boiling point/range °F -23 - 284 Melting point/range °C No data available Melting point/range °F No data available Flash point °C -96.11 Flash point °F -141 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Contact with ignition sources, hot-glowing surfaces, electrical arcs, sparks, and open flame. Do not use near welding arcs. Incompatability Strong acids. Alkalies. Oxidizers. Page 2 / 4 Product code 92964 Product name Moly Coat Page 769 of 1235 Page 769 of 1235 Page 769 of 1235 Page 769 of 1235 ---PAGE BREAK--- Hazardous Decomposition Products Carbon oxides. Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION Component Information Chemical Name LD50 (oral,rat ) LD50 (dermal ,rat/rab bit) LC50 (inhalation,rat) Propane/Isobutan e/N-Butane 68476-86-8 - - - 2-Propanone 67-64-1 5800 mg/kg - - 1330-20-7 4300 mg/kg 1700 mg/kg 47635 mg/L 5000 ppm Isopropyl Alcohol 67-63-0 4396 mg/kg 12800 mg/kg 12870 mg/kg 72.6 mg/L 100-41-4 3500 mg/kg 15354 mg/kg 17.2 mg/L Molybdenum sulfide 1317-33-5 - - 2820 mg/m3 Synergistic Products None known Potential health effects Sensitization None known Chronic toxicity Possible risks of irreversible effects . Prolonged exposure may cause chronic effects . Mutagenic effects None known Teratogenic effects None known Reproductive toxicity None known Target Organ Effects Long term exposure to vapor may cause lung damage. Long term exposure to vapor may cause kidney damage. Central nervous system. Carcinogenic effects See table below Chemical Name ACGIH OEL - Carcinoge ns IARC NTP - Known Carcinoge ns NTP - Suspected Human Carcinoge ns OSHA RTK Carcinoge ns Propane/Isob utane/N- Butane Not Listed Not Listed Not Listed Not Listed Not Listed 2-Propanone A4 Not Listed Not Listed Not Listed Not Listed ene A4 Not Listed Not Listed Not Listed Not Listed Isopropyl Alcohol A4 Not Listed Not Listed Not Listed Not Listed A3 Group 2B Not Listed Not Listed Listed Molybdenum sulfide Not Listed Not Listed Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Disposal Information Dispose in accordance with federal, state, and local regulations. 14. TRANSPORTATION INFORMATION DOT Consumer commodity, ORM-D TDG Consumer commodity, ORM-D 15. REGULATORY INFORMATION Chemical Name US EPA SARA 313 Emission Reporting Listed Isopropyl Alcohol Listed Listed State Regulations Page 3 / 4 Microtox Data Photobacterium phosphoreum EC50=9.68 mg/L (30 min) Nitrosomonas EC50=96 mg/L (24 h) Product name Moly Coat Water Flea Data Daphnia magna EC501.8 - 2.4 mg/L (48 h) Microtox Data Photobacterium phosphoreum EC50=0.0084 mg/L (24 h) Microtox Data Photobacterium phosphoreum EC50=14500 mg/L (15 min) Water Flea Data water flea hEC50 48 (3.82 mg/L) Gammarus lacustris hLC50 48 (0.6 mg/L) water flea hEC50 48 (3.82 mg/L) Isopropyl Alcohol Product code 92964 Microtox Data Photobacterium phosphoreum EC50=35390 mg/L (5 min) Water Flea Data Daphnia magna EC5010294 - 17704 mg/L (48 h) Daphnia magna EC5012600 - 12700 mg/L (48 h) Water Flea Data Daphnia magna EC50=13299 mg/L (48 h) 2-Propanone Page 770 of 1235 Page 770 of 1235 Page 770 of 1235 Page 770 of 1235 ---PAGE BREAK--- Chemical Name New Jersey - RTK - RTK California Prop. 65 Propane/Isobutane/N- Butane Not Listed Not Listed Not Listed 2-Propanone Not Listed Listed Not Listed Not Listed Listed Not Listed Isopropyl Alcohol Not Listed Listed Not Listed Not Listed Listed Carcinogen Molybdenum sulfide Not Listed Not Listed Not Listed WARNING: This product contains a chemical(s) known to the state of California to cause cancer and birth defects or other reproductive harm International Inventories Chemical Name EINECS DSL NDSL TSCA Propane/Isobutane/N- Butane X X - X 2-Propanone X X - X X X - X Isopropyl Alcohol X X - X X X - X Molybdenum sulfide X X - X CPR This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. 16. OTHER INFORMATION HMIS Health - 2 Flammability - 4 Physical Hazard - 0 Prepared By V. Shargorodsky, Regulatory Affairs Engineer The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Page 4 / 4 Product code 92964 Product name Moly Coat Page 771 of 1235 Page 771 of 1235 Page 771 of 1235 Page 771 of 1235 ---PAGE BREAK--- Safety Data Sheet According to OSHA HCS 2012 (29 CFR 1910.1200) Uses Advised Against: Inhalation (Breathing): First aid is not normally required. If breathing difficulties develop, move victim away from source of exposure and into fresh air in a position comfortable for breathing. Seek immediate medical attention. All others Ingestion (Swallowing): First aid is not normally required; however, if swallowed and develop, seek medical attention. SDS Number: Most important and effects: 778901 Acute: None known or anticipated Section 1: Identification Delayed: Dry skin and possible irritation with repeated or prolonged exposure. Product Identifier: Notes to Physician: Acute aspirations of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. Intended Use: Section 5: Fire-Fighting Measures Section 4: First Aid Measures Automatic Transmission Fluid Eye Contact: If irritation or redness develops from exposure, flush eyes with clean water. If persist, seek medical attention. Motorcraft MERCON® LV ATF Skin Contact: Remove contaminated shoes and clothing and cleanse affected area(s) thoroughly by washing with mild soap and water or a waterless hand cleaner. If irritation or redness develops and persists, seek medical attention. Section 2: Hazards Identification Lubricant Base Oil (Petroleum) VARIOUS >85 Label Elements Additives Proprietary <15 ¹ All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Other Hazards None Known Manufacturer: Phillips 66 Lubricants P.O. Box 4428 Houston, TX 77210 Emergency Health and Safety Number: Chemtrec: [PHONE REDACTED] (24 Hours) Classified Hazards Section 3: Composition / Information on Ingredients SDS Information: Phone: [PHONE REDACTED] Email: [EMAIL REDACTED] URL: www.Phillips66.com This material is not hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200. Chemical Name _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ CASRN Concentration¹ Customer Service: U.S.: 1-[PHONE REDACTED] or International: +1-83-2486-3363 Technical Information: 1-[PHONE REDACTED] Date of Issue: 28-Jan-2013 Page 1/7 Status: FINAL No classified hazards. 778901 - Motorcraft MERCON® LV ATF Page 772 of 1235 Page 772 of 1235 Page 772 of 1235 Page 772 of 1235 ---PAGE BREAK--- _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Date of Issue: 28-Jan-2013 778901 - Motorcraft MERCON® LV ATF Status: FINAL Page 2/7 Environmental Precautions: Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems, and natural waterways. Use water sparingly to minimize environmental contamination and reduce disposal requirements. If spill occurs on water notify appropriate authorities and advise shipping of any hazard. Spills into or upon navigable waters, the contiguous zone, or adjoining shorelines that cause a sheen or discoloration on the surface of the water, may require notification of the National Response Center (phone number [PHONE REDACTED]). Specific hazards arising from the chemical Special protective actions for firefighters: For fires beyond the initial stage, emergency responders in the immediate hazard area should wear protective clothing. When the potential chemical hazard is unknown, in enclosed or confined spaces, a self contained breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions warrant (see Section Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Cool equipment exposed to fire with water, if it can be done safely. Avoid spreading burning liquid with water used for cooling purposes. Methods and material for containment and cleaning up: Notify relevant authorities in accordance with all applicable regulations. Immediate cleanup of any spill is recommended. Dike far ahead of spill for later recovery or disposal. Absorb spill with inert material such as sand or vermiculite, and place in suitable container for disposal. If spilled on water remove with appropriate methods (e.g. skimming, booms or absorbents). In case of soil contamination, remove contaminated soil for remediation or disposal, in accordance with local regulations. Recommended measures are based on the most likely spillage scenarios for this material; however local conditions and regulations may influence or limit the choice of appropriate actions to be taken. See Section 13 for information on appropriate disposal. Section 7: Handling and Storage See Section 9 for Flammable Properties including Flash Point and Flammable (Explosive) Limits NFPA 704 Hazard Class Unusual Fire & Explosion Hazards: This material may burn, but will not ignite readily. If container is not properly cooled, it can rupture in the heat of a fire. Section 6: Accidental Release Measures Extinguishing Media: Dry chemical, carbon dioxide, foam, or water spray is recommended. Water or foam may cause frothing of materials heated above 212°F / 100°C. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam. _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Personal precautions, protective equipment and emergency procedures: This material may burn, but will not ignite readily. Keep all sources of ignition away from spill/release. Stay upwind and away from spill/release. Avoid direct contact with material. For large spillages, notify persons down wind of the spill/release, isolate immediate hazard area and keep unauthorized personnel out. Wear appropriate protective equipment, including respiratory protection, as conditions warrant (see Section See Sections 2 and 7 for additional information on hazards and precautionary measures. Hazardous Combustion Products: Combustion may yield smoke, carbon monoxide, and other products of incomplete combustion. Oxides of sulfur, nitrogen or phosphorus may also be formed. Date of Issue: 28-Jan-2013 Flammability: 1 Page 2/7 Instability: 0 Status: FINAL 778901 - Motorcraft MERCON® LV ATF Health: 0 0 (Minimal) 1 (Slight) 2 (Moderate) 3 (Serious) 4 (Severe) Page 773 of 1235 Page 773 of 1235 Page 773 of 1235 Page 773 of 1235 ---PAGE BREAK--- _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Page 3/7 Date of Issue: 28-Jan-2013 778901 - Motorcraft MERCON® LV ATF Status: FINAL Note: State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or similar professional, or your local agencies, for further information. Conditions for safe storage: Keep container(s) closed and properly labeled. Use and store this material in cool, dry, well-ventilated area away from heat and all sources of ignition. Store only in approved containers. Keep away from any incompatible material (see Section 10). Protect container(s) against physical damage. "Empty" containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury or death. "Empty" drums should be completely drained, properly bunged, and shipped to the supplier or a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. Before working on or in tanks which contain or have contained this material, refer to OSHA regulations, ANSI Z49.1, and other references pertaining to cleaning, repairing, welding, or other contemplated operations. Respiratory Protection: Where there is potential for airborne exposure above the exposure limit a NIOSH certified air purifying respirator equipped with R or P95 filters may be used. A respiratory protection program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed whenever workplace conditions warrant a respirator's use. Air purifying respirators provide limited protection and cannot be used in atmospheres that exceed the maximum use concentration (as directed by regulation or the manufacturer's instructions), in oxygen deficient (less than 19.5 percent oxygen) situations, or under conditions that are immediately dangerous to life and health (IDLH). Precautions for safe handling: Keep away from flames and hot surfaces. Wash thoroughly after handling. Use good personal hygiene practices and wear appropriate personal protective equipment (see section Spills will produce very slippery surfaces. Do not enter confined spaces such as tanks or pits without following proper entry procedures such as ASTM D-4276 and 29CFR 1910.146. Do not wear contaminated clothing or shoes. Chemical Name ACGIH Suggestions provided in this section for exposure control and specific types of protective equipment are based on readily available information. Users should consult with the specific manufacturer to confirm the performance of their protective equipment. Specific situations may require consultation with industrial hygiene, safety, or engineering professionals. Engineering controls: If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure limits, additional engineering controls may be required. OSHA Other Section 9: Physical and Chemical Properties Section 8: Exposure Controls / Personal Protection Data represent typical values and are not intended to be specifications. N/A = Not Applicable; N/D = Not Determined Eye/Face Protection: The use of eye/face protection is not normally required; however, good industrial hygiene practice suggests the use of eye protection that meets or exceeds ANSI Z.87.1 whenever working with chemicals. Lubricant Base Oil (Petroleum) TWA: 5mg/m3 STEL: 10 mg/m3 as Oil Mist, if Generated TWA: 5mg/m3 as Oil Mist, if Generated Skin/Hand Protection: The use of gloves impervious to the specific material handled is advised to prevent skin contact. Users should check with manufacturers to confirm the breakthrough performance of their products. Suggested protective materials: Nitrile Bulk Density: 6.99 - 7.08 lbs/gal Upper Explosive Limits (vol % in air): No data Odor Threshold: No data Test Method: Pensky-Martens Closed Cup (PMCC), ASTM D93, EPA 1010 Vapor Density (air=1): >1 Evaporation Rate (nBuAc=1): <1 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ pH: Not applicable Auto-ignition Temperature: No data Initial Boiling Point/Range: No data Odor: Petroleum Specific Gravity (water=1): 0.84 - 0.85 @ 60ºF (15.6ºC) Flash Point: > 338 °F / > 170 °C Melting/Freezing Point: No data Lower Explosive Limits (vol % in air): No data Date of Issue: 28-Jan-2013 Vapor Pressure: <1 mm Hg Particle Size: N/A Page 3/7 Partition Coefficient (n-octanol/water) (Kow): No data Status: FINAL Physical Form: Liquid 778901 - Motorcraft MERCON® LV ATF Appearance: Red Decomposition Temperature: No data Page 774 of 1235 Page 774 of 1235 Page 774 of 1235 Page 774 of 1235 ---PAGE BREAK--- _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Status: FINAL Page 4/7 Date of Issue: 28-Jan-2013 778901 - Motorcraft MERCON® LV ATF Chemical stability: Stable under normal ambient and anticipated conditions of use. Skin Corrosion/Irritation: Not expected to be irritating. Repeated exposure may cause skin dryness or cracking. Information on Toxicological Effects of Substance/Mixture Serious Eye Damage/Irritation: Not expected to be irritating. of Overexposure: Inhalation of oil mists or vapors generated at elevated temperatures may cause respiratory irritation. Accidental ingestion can result in minor irritation of the digestive tract, nausea and diarrhea. Incompatible materials: Avoid contact with strong oxidizing agents and strong reducing agents. Skin Sensitization: No information available on the mixture, however none of the components have been classified for skin sensitization (or are below the concentration threshold for classification). Respiratory Sensitization: No information available. Reactivity: Stable under normal ambient and anticipated conditions of use. Specific Target Organ Toxicity (Single Exposure): No information available on the mixture, however none of the components have been classified for target organ toxicity (or are below the concentration threshold for classification). Specific Target Organ Toxicity (Repeated Exposure): No information available on the mixture, however none of the components have been classified for target organ toxicity (or are below the concentration threshold for classification). Possibility of hazardous reactions: Hazardous reactions not anticipated. Hazardous decomposition products: Not anticipated under normal conditions of use. Carcinogenicity: No information available on the mixture, however none of the components have been classified for carcinogenicity (or are below the concentration threshold for classification). Germ Cell Mutagenicity: No information available on the mixture, however none of the components have been classified for germ cell mutagenicity (or are below the concentration threshold for classification). Section 10: Stability and Reactivity Reproductive Toxicity: No information available on the mixture, however none of the components have been classified for reproductive toxicity (or are below the concentration threshold for classification). Information on Toxicological Effects of Components Lubricant Base Oil (Petroleum) Section 11: Toxicological Information Conditions to avoid: Extended exposure to high temperatures can cause decomposition. Avoid all possible sources of ignition. Aspiration Hazard: Not expected to be an aspiration hazard. Solubility in Water: Negligible Unlikely to be harmful Viscosity: 5.8 - 6.2 cSt @ 100°C; 28.0 - 32.0 cSt @ 40°C Dermal Acute Toxicity Unlikely to be harmful Additional Information Flammability (solid, gas): N/A >5 mg/L (mist, estimated) Oral _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ > 2 g/kg (estimated) Percent Volatile: Negligible Unlikely to be harmful Inhalation Date of Issue: 28-Jan-2013 LC50/LD50 Data Page 4/7 Hazard Status: FINAL > 5 g/kg (estimated) 778901 - Motorcraft MERCON® LV ATF Page 775 of 1235 Page 775 of 1235 Page 775 of 1235 Page 775 of 1235 ---PAGE BREAK--- _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Date of Issue: 28-Jan-2013 778901 - Motorcraft MERCON® LV ATF Status: FINAL Page 5/7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable Other Adverse Effects: None anticipated. Toxicity: All acute aquatic toxicity studies on samples of lubricant base oils show acute toxicity values greater than 100 mg/L for invertebrates, algae and fish. These tests were carried out on water accommodated fractions and the results are consistent with the predicted aquatic toxicity of these substances based on their hydrocarbon compositions. International Civil Aviation Org. / International Air Transport Assoc. (ICAO/IATA) U.S. Department of Transportation (DOT) UN/ID Not regulated Shipping Description: Note: U.S. DOT compliance requirements may apply. See 49 CFR 171.22, 23 & 24. Not regulated Bioaccumulative Potential: Log Kow values measured for the hydrocarbon components of this material are greater than 5.3, and therefore regarded as having the potential to bioaccumulate. In practice, metabolic processes may reduce bioconcentration. Carcinogenicity: The petroleum base oils contained in this product have been highly refined by a variety of processes including severe hydrocracking/hydroprocessing to reduce aromatics and improve performance characteristics. All of the oils meet the IP-346 criteria of less than 3 percent PAH's and are not considered carcinogens by NTP, IARC, or OSHA. Note: If shipped by land in a packaging having a capacity of 3,500 gallons or more, the provisions of 49 CFR, Part 130 apply. (Contains oil) Section 13: Disposal Considerations International Maritime Dangerous Goods (IMDG) Section 12: Ecological Information Shipping Description: Not regulated The generator of a waste is always responsible for making proper hazardous waste determinations and needs to consider state and local requirements in addition to federal regulations. This material, if discarded as produced, would not be a federally regulated RCRA "listed" hazardous waste and is not believed to exhibit characteristics of hazardous waste. See Sections 7 and 8 for information on handling, storage and personal protection and Section 9 for physical/chemical properties. It is possible that the material as produced contains constituents which are not required to be listed in the MSDS but could affect the hazardous waste determination. Additionally, use which results in chemical or physical change of this material could subject it to regulation as a hazardous waste. This material under most intended uses would become "Used Oil" due to contamination by physical or chemical impurities. Whenever possible, Recycle used oil in accordance with applicable federal and state or local regulations. Container contents should be completely used and containers should be emptied prior to discard. Mobility in Soil: Volatilization to air is not expected to be a significant fate process due to the low vapor pressure of this material. In water, base oils will float and spread over the surface at a rate dependent upon viscosity. There will be significant removal of hydrocarbons from the water by sediment adsorption. In soil and sediment, hydrocarbon components will show low mobility with adsorption to sediments being the predominant physical process. The main fate process is expected to be slow biodegradation of the hydrocarbon constituents in soil and sediment. _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Note: U.S. DOT compliance requirements may apply. See 49 CFR 171.22, 23 & 25. Persistence and Degradability: The hydrocarbons in this material are not readily biodegradable, but since they can be degraded by microorganisms, they are regarded as inherently biodegradable. Date of Issue: 28-Jan-2013 Section 14: Transport Information Cargo Aircraft Only Page 5/7 Passenger Aircraft Status: FINAL 778901 - Motorcraft MERCON® LV ATF LTD. QTY Page 776 of 1235 Page 776 of 1235 Page 776 of 1235 Page 776 of 1235 ---PAGE BREAK--- _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Date of Issue: 28-Jan-2013 778901 - Motorcraft MERCON® LV ATF Status: FINAL Page 6/7 Section 16: Other Information Acute Health: No EPA (CERCLA) Reportable Quantity (in pounds): This material does not contain any chemicals with CERCLA Reportable Quantities. Chronic Health: No California Proposition 65: This material does not contain any chemicals which are known to the State of California to cause cancer, birth defects or other reproductive harm at concentrations that trigger the warning requirements of California Proposition 65. CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs (in pounds): This material does not contain any chemicals subject to the reporting requirements of SARA 302 and 40 CFR 372. Fire Hazard: No International Hazard Classification Pressure Hazard: No Canada: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all the information required by the Regulations. Reactive Hazard: No WHMIS Hazard Class: None National Chemical Inventories All components are either listed on the US TSCA Inventory, or are not regulated under TSCA This product contains one or more components on the NDSL (Non-Domestic Substances List) which are subject to Canada's New Substance Notification requirements if exported quantities of component exceed 1000 kg/yr. All other components are on the DSL Section 15: Regulatory Information CERCLA/SARA - Section 313 and 40 CFR 372: This material does not contain any chemicals subject to the reporting requirements of SARA 313 and 40 CFR 372. U.S. Export Control Classification Number: EAR99 CERCLA/SARA - Section 311/312 (Title III Hazard Categories) Max. Net Qty. Per Package: Packaging Instruction Revised Sections or Basis for Revision: Periodic review and update; Format change; Physical Properties (Section Toxicological (Section 11) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 26-Jul-2012 FINAL Date of Issue: 28-Jan-2013 28-Jan-2013 Previous Issue Date: Page 6/7 Date of Issue: Status: FINAL 778901 778901 - Motorcraft MERCON® LV ATF SDS Number: Status: Page 777 of 1235 Page 777 of 1235 Page 777 of 1235 Page 777 of 1235 ---PAGE BREAK--- _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Date of Issue: 28-Jan-2013 778901 - Motorcraft MERCON® LV ATF Status: FINAL Page 7/7 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Guide to Abbreviations: ACGIH = American Conference of Governmental Industrial Hygienists; CASRN = Chemical Abstracts Service Registry Number; CEILING = Ceiling Limit (15 minutes); CERCLA = The Comprehensive Environmental Response, Compensation, and Liability Act; EPA = Environmental Protection Agency; GHS = Globally Harmonized System; IARC = International Agency for Research on Cancer; INSHT = National Institute for Health and Safety at Work; IOPC = International Oil Pollution Compensation; LEL = Lower Explosive Limit; NE = Not Established; NFPA = National Fire Protection Association; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration; PEL = Permissible Exposure Limit (OSHA); SARA = Superfund Amendments and Reauthorization Act; STEL = Short Term Exposure Limit (15 minutes); TLV = Threshold Limit Value (ACGIH); TWA = Time Weighted Average (8 hours); UEL = Upper Explosive Limit; WHMIS = Worker Hazardous Materials Information System (Canada) Page 7/7 Status: FINAL Date of Issue: 28-Jan-2013 778901 - Motorcraft MERCON® LV ATF Disclaimer of Expressed and implied Warranties: The information presented in this Safety Data Sheet is based on data believed to be accurate as of the date this Safety Data Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. No responsibility is assumed for any damage or injury resulting from abnormal use or from any failure to adhere to recommended practices. The information provided above, and the product, are furnished on the condition that the person receiving them shall make their own determination as to the suitability of the product for their particular purpose and on the condition that they assume the risk of their use. In addition, no authorization is given nor implied to practice any patented invention without a license. Page 778 of 1235 Page 778 of 1235 Page 778 of 1235 Page 778 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol Aerosol. GHS product identifier Product type Emergency telephone number (with hours of operation) Section 1. Identification : : : Code : AMHSC Supplier's details : Identified uses R MP HD Heavy Duty Metal Protector - Aerosol SAFETY DATA SHEET Conforms to HazCom 2012 - United States AMSOIL INC. One AMSOIL Center Superior, WI 54880 [PHONE REDACTED] CHEMTREC: Within USA and Canada: 1-[PHONE REDACTED] Outside USA and Canada: +1 [PHONE REDACTED] (collect calls accepted) (24/7) Rust Preventative and Lubricating Fluid. Date Version : : 09/15/2014 5 FLAMMABLE AEROSOLS - Category 1 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B Classification of the substance or mixture : Signal word : Danger Hazard statements : Extremely flammable aerosol. Causes eye irritation. Hazard pictograms : Precautionary statements Prevention : Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Pressurized container: Do not pierce or burn, even after use. Do not spray on an open flame or other ignition source. Wash hands thoroughly after handling. Response : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 Disposal : Not applicable. GHS label elements OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 2. Hazards identification 1/12 09/15/2014 : Date of issue Page 779 of 1235 Page 779 of 1235 Page 779 of 1235 Page 779 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC Hazards not otherwise classified : None known. Propane 10 - 30 74-98-6 Butane 10 - 30 106-97-8 Stoddard solvent 10 - 30 8052-41-3 Distillates, hydrotreated light 10 - 30 64742-47-8 Acetone 10 - 30 67-64-1 Ingredient name CAS number % Other means of identification : Not available. CAS number : Not applicable. Substance/mixture Product code : AMHSC CAS number/other identifiers : Mixture There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. United States Section 3. Composition/information on ingredients Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. Get medical attention if occur. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. If irritation persists, get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Get medical attention if occur. Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Section 4. First aid measures 2/12 09/15/2014 : Date of issue Page 780 of 1235 Page 780 of 1235 Page 780 of 1235 Page 780 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC Protection of first-aiders : It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Most important acute and delayed Inhalation : No known significant effects or critical hazards. May be irritating to mouth, throat and stomach. : Ingestion Skin contact : No known significant effects or critical hazards. Causes eye irritation. : Eye contact Over-exposure Skin contact Ingestion Inhalation Adverse may include the following: respiratory tract irritation coughing No known significant effects or critical hazards. No known significant effects or critical hazards. : : : Eye contact : Adverse may include the following: irritation watering redness Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide Extremely flammable aerosol. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 5. Fire-fighting measures 3/12 09/15/2014 : Date of issue Page 781 of 1235 Page 781 of 1235 Page 781 of 1235 Page 781 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : Environmental precautions Personal precautions, protective equipment and emergency procedures : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : Spill Section 6. Accidental release measures Protective measures Put on appropriate personal protective equipment (see Section Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Avoid breathing vapor or mist. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. : Precautions for safe handling Section 7. Handling and storage 4/12 09/15/2014 : Date of issue Page 782 of 1235 Page 782 of 1235 Page 782 of 1235 Page 782 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. : : Propane NIOSH REL (United States, 4/2013). TWA: 1800 mg/m³ 10 hours. TWA: 1000 ppm 10 hours. OSHA PEL (United States, 2/2013). TWA: 1800 mg/m³ 8 hours. TWA: 1000 ppm 8 hours. Butane NIOSH REL (United States, 4/2013). TWA: 1900 mg/m³ 10 hours. TWA: 800 ppm 10 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 800 ppm 8 hours. TWA: 1900 mg/m³ 8 hours. ACGIH TLV (United States, 6/2013). STEL: 1000 ppm 15 minutes. Stoddard solvent ACGIH TLV (United States, 6/2013). TWA: 525 mg/m³ 8 hours. TWA: 100 ppm 8 hours. NIOSH REL (United States, 4/2013). CEIL: 1800 mg/m³ 15 minutes. TWA: 350 mg/m³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 2900 mg/m³ 8 hours. TWA: 500 ppm 8 hours. Distillates, hydrotreated light ACGIH TLV (United States, 6/2013). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours. Acetone ACGIH TLV (United States, 3/2012). STEL: 1782 mg/m³ 15 minutes. STEL: 750 ppm 15 minutes. TWA: 1188 mg/m³ 8 hours. TWA: 500 ppm 8 hours. NIOSH REL (United States, 1/2013). TWA: 590 mg/m³ 10 hours. TWA: 250 ppm 10 hours. OSHA PEL (United States, 6/2010). TWA: 2400 mg/m³ 8 hours. TWA: 1000 ppm 8 hours. Ingredient name Exposure limits Appropriate engineering controls : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Control parameters Occupational exposure limits Section 8. Exposure controls/personal protection 5/12 09/15/2014 : Date of issue Page 783 of 1235 Page 783 of 1235 Page 783 of 1235 Page 783 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC Hand protection Use a properly fitted, air-purifying or supplied air respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Physical state Melting point / Pour point Vapor pressure Vapor density Liquid. [Aerosol.] Not available. >1 [Air = 1] Not available. Mild hydrocarbon. Odor pH Brown. Color Evaporation rate <1 (ether = 1) Flash point Closed cup: -104.44°C (-156°F) [Pensky-Martens.] Not available. Not available. Odor threshold : : : : : : : : : : Appearance Boiling point : -42.222 to 260°C (-44 to 500°F) Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Lower: 0.7% Upper: 13% Section 9. Physical and chemical properties 6/12 09/15/2014 : Date of issue Page 784 of 1235 Page 784 of 1235 Page 784 of 1235 Page 784 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC Relative density Solubility 0.7 Insoluble Auto-ignition temperature Not available. Not available. Viscosity Not available. Partition coefficient: n- octanol/water : : : : : Decomposition temperature : Not available. Type of aerosol : Spray Heat of combustion : 26.13 kJ/g Aerosol product Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability Reactive or incompatible with the following materials: oxidizing materials, acids and alkalis. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 10. Stability and reactivity Information on toxicological effects Acute toxicity Acetone LD50 Oral Rat 5800 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Stoddard solvent Eyes - Moderate irritant Rabbit - 24 hours 500 mg - Eyes - Mild irritant Human - 100 ppm - Acetone Eyes - Mild irritant Human - 186300 ppm - Eyes - Mild irritant Rabbit - 10 µL - Eyes - Moderate irritant Rabbit - 24 hours 20 mg - Eyes - Severe irritant Rabbit - 20 mg - Skin - Mild irritant Rabbit - 24 hours 500 mg - Skin - Mild irritant Rabbit - 395 mg - Product/ingredient name Result Score Exposure Observation Sensitization Species Section 11. Toxicological information 7/12 09/15/2014 : Date of issue Page 785 of 1235 Page 785 of 1235 Page 785 of 1235 Page 785 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC Carcinogenicity Specific target organ toxicity (single exposure) Acetone Category 3 Not applicable. Narcotic effects Name Category Route of exposure Target organs There is no data available. Information on the likely routes of exposure Inhalation : No known significant effects or critical hazards. May be irritating to mouth, throat and stomach. : Ingestion Skin contact : No known significant effects or critical hazards. Causes eye irritation. : Eye contact related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse may include the following: respiratory tract irritation coughing No known significant effects or critical hazards. No known significant effects or critical hazards. : : : Eye contact : Adverse may include the following: irritation watering redness Delayed and immediate effects and also chronic effects from short and long term exposure Specific target organ toxicity (repeated exposure) Aspiration hazard Name Result Stoddard solvent ASPIRATION HAZARD - Category 1 Distillates, hydrotreated light ASPIRATION HAZARD - Category 1 : Dermal contact. Eye contact. Inhalation. Ingestion. Potential acute health effects Potential immediate effects : No known significant effects or critical hazards. Short term exposure Potential delayed effects : No known significant effects or critical hazards. Potential immediate effects : No known significant effects or critical hazards. Long term exposure Potential delayed effects : No known significant effects or critical hazards. There is no data available. Classification Acetone - - - A4 - - Product/ingredient name ACGIH EPA NIOSH NTP IARC OSHA 8/12 09/15/2014 : Date of issue Page 786 of 1235 Page 786 of 1235 Page 786 of 1235 Page 786 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC No known significant effects or critical hazards. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Potential chronic health effects Numerical measures of toxicity Acute toxicity estimates There is no data available. LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Toxicity Product/ingredient name Species Result Exposure Persistence and degradability Soil/water partition coefficient (KOC) : There is no data available. Mobility in soil Distillates, hydrotreated light Acute LC50 2200 µg/l Fresh water Fish - Lepomis macrochirus 4 days Acetone Acute EC50 20.565 mg/L Marine water Algae - Ulva pertusa 96 hours Acute LC50 6000000 µg/l Fresh water Crustaceans - Gammarus pulex 48 hours Acute LC50 10000 µg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 100 mg/L Fresh water Fish - Pimephales promelas - Juvenile (Fledgling, Hatchling, Weanling) 96 hours Chronic NOEC 4.95 mg/L Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 0.016 ml/L Fresh water Crustaceans - Daphniidae 21 days Chronic NOEC 0.1 ml/L Fresh water Daphnia - Daphnia magna - Neonate 21 days There is no data available. Stoddard solvent 3.16 to 7.06 - high Acetone -0.23 - low Section 12. Ecological information 9/12 09/15/2014 : Date of issue Page 787 of 1235 Page 787 of 1235 Page 787 of 1235 Page 787 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. : Disposal methods United States - RCRA Toxic hazardous waste List Acetone 67-64-1 Listed U002 Ingredient CAS # Status Reference number Section 13. Disposal considerations Aerosols, flammable (each not exceeding 1 L capacity) 2.1 - Aerosols, flammable (each not exceeding 1 L capacity) 2.1 - Aerosols, flammable (each not exceeding 1 L capacity) UN1950 2.1 - UN1950 UN1950 The marine pollutant mark is not required when transported on inland waterways in sizes of ≤5 L or ≤5 kg or by road, rail, or inland air in non-bulk sizes. Reportable quantity 33333.3 lbs / 15133.3 kg [5711.1 gal / 21619 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. Remarks Limited quantity The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg. Emergency schedules (EmS) F-D, S-U Remarks Limited quantity The environmentally hazardous substance mark may appear if required by other transportation regulations. Remarks Limited quantity IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards No. Yes. No. DOT Classification Section 14. Transport information 10/12 09/15/2014 : Date of issue Page 788 of 1235 Page 788 of 1235 Page 788 of 1235 Page 788 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. : AERG : 126 U.S. Federal regulations The following components are listed: Propane; Stoddard solvent; Butane; Acetone Clean Air Act (CAA) 112 regulated flammable substances: Propane; Butane Massachusetts : : California Prop. 65 Clean Air Act Section 112 Hazardous Air Pollutants (HAPs) : Not listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Listed New York : The following components are listed: Acetone New Jersey : The following components are listed: Propane; Stoddard solvent; Butane; Acetone; Distillates, hydrotreated heavy naphthenic : The following components are listed: Propane; Stoddard solvent; Butane; Acetone State regulations SARA 302/304 SARA 304 RQ : Not applicable. SARA 311/312 Classification : Fire hazard Immediate (acute) health hazard Stoddard solvent 10 - 30 Yes. No. No. No. No. Acetone 10 - 30 Yes. No. No. Yes. No. Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients Section 15. Regulatory information United States inventory (TSCA 8b): All components are listed or exempted. No products were found. 11/12 09/15/2014 : Date of issue Page 789 of 1235 Page 789 of 1235 Page 789 of 1235 Page 789 of 1235 ---PAGE BREAK--- MP HD Heavy Duty Metal Protector - Aerosol AMHSC No products were found. International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Montreal Protocol (Annexes A, B, C, E) Not listed. Ingredient name List name Status Stockholm Convention on Persistent Organic Pollutants Not listed. Ingredient name List name Status Rotterdam Convention on Prior Inform Consent (PIC) Not listed. Ingredient name List name Status Not listed. Ingredient name List name Status UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. Ingredient name List name Status History Prepared by : Date of issue mm/dd/yyyy Date of previous issue Version : : : 5 09/15/2014 06/15/2013 Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Section 16. Other information AMSOIL INC. 12/12 09/15/2014 : Date of issue Page 790 of 1235 Page 790 of 1235 Page 790 of 1235 Page 790 of 1235 ---PAGE BREAK--- Murphy’s Oil Soap Liquid 1 COLGATE-PALMOLIVE Company MATERIAL SAFETY DATA SHEET This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Murphy Oil Soap Liquid Effective Date: March 1, 2005 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION COLGATE-PALMOLIVE COMPANY 300 Park Avenue New York NY 10022 PRODUCT NAME: Murphy Oil Soap Liquid CAS NUMBER: Not applicable – product is a mixture GENERAL USE: Mild, multi-purpose cleaner. EMERGENCY TELEPHONE NUMBER: For emergency involving spill, leak, fire, exposure or accident, call CHEMTREC (800) 424-9300, day or night FOR MEDICAL EMERGENCIES INVOLVING THIS PRODUCT CALL COLLECT: (888) 489-3861 2. COMPOSITION/INFORMATION ON INGREDIENTS OSHA-REGULATED COMPONENTS (present at a concentration of > or = Component CAS# % PEL TLV Not Applicable The following components, present at a concentration of > or = 0.1%, are listed as carcinogens or potential carcinogens by either the National Toxicology Program (NTP), the International Agency for Research on Cancer (IARC) or OSHA: Component CAS# % PEL TLV Not Applicable 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: May cause eye irritation on direct contact.. SKIN CONTACT: May cause skin irritation on prolonged or repeated contact. INGESTION: May be harmful if swallowed in large quantities. INHALATION: No adverse effects expected. 4. FIRST AID MEASURES EYE CONTACT: Flush eyes with large amounts of water for 15 minutes. Get medical attention if irritation persists. SKIN CONTACT: Rinse area with plenty of water. Get medical attention if irritation persists. INGESTION: Drink 1-2 glasses of water. Get medical attention. INHALATION: Not Applicable. 5. FIRE FIGHTING MEASURES Flash Point (Method): Not Applicable Extinguishing Media: Water spray, all-purpose dry chemical, CO2. SPECIAL FIRE FIGHTING PROCEDURES: Self-contained breathing apparatus and protective clothing should be worn when fighting chemical fires. Page 791 of 1235 Page 791 of 1235 Page 791 of 1235 Page 791 of 1235 ---PAGE BREAK--- Murphy’s Oil Soap Liquid 2 6. ACCIDENTAL RELEASE MEASURES Cover with inert, absorbent material and remove to disposal container. Spill area may be slippery. Flush with plenty of water. 7. HANDLING AND STORAGE Store in a closed container in a cool, dry, well-ventilated area. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION GENERAL CONTROLS: Avoid eye and skin contact. PROTECTIVE CLOTHING: The use of safety goggles and protective gloves is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance and odor: Amber, viscous paste with citrus odor. pH solution): 11.0 0.6 Specific gravity: approximately 1.01 0.006 10. STABILITY AND REACTIVITY GENERAL: This product is stable. Hazardous polymerization will not occur. INCOMPATIBLE MATERIALS: Avoid contact with strong acids, alkalis and oxidizing and reducing agents, organic peroxides and easily ignited materials. Avoid prolonged contact with reactive metals aluminum, brass, bronze, etc.) HAZARDOUS DECOMPOSITION: May produce irritating and/or toxic fumes upon thermal decomposition. 11. TOXICOLOGICAL INFORMATION This product has not been tested as a whole. However, this formula was reviewed by expert toxicologists in the Product Safety Assurance Department of Colgate-Palmolive and is determined to be safe for its intended use. This review has taken into consideration available safety-related information including information on individual ingredients, similar ingredients, similar formulas and potential ingredient interactions. This review is a component of the hazard determination used to prepare the statements in Section 3 of the MSDS. 12. ECOLOGICAL INFORMATION Not Available 13. DISPOSAL CONSIDERATIONS Any disposal practice must be in compliance with local, state, and federal laws and regulations (contact local or state environmental agency for specific rules). Do not dump into sewers, any body of water or onto the ground. 14. TRANSPORTATION Not regulated as a DOT hazardous material. Page 792 of 1235 Page 792 of 1235 Page 792 of 1235 Page 792 of 1235 ---PAGE BREAK--- Murphy’s Oil Soap Liquid 3 15. REGULATORY INFORMATION RCRA (40 CFR 261, Subpart Not Applicable CLEAN WATER ACT: Not Applicable CLEAN AIR ACT: Contains ethanol which is a Section 111 material. SARA: Sections 301-304 (Threshold planning quantity - TPQ) 40 CFR 355: No TPQ for any component. Not Applicable Section 313 (Toxic chemical release reporting) 40 CFR 372: The following chemicals must be reported under SARA 313: Not Applicable CERCLA: Section 102 (Reportable Quantity - RQ) 40 CFR 302: Not Applicable New Jersey Right to Know Hazardous Substance List: This product contains the following components subject to reporting requirements: Hydrogen peroxide Hazardous Substance List: This product contains the following components subject to reporting requirements: Hydrogen peroxide Massachusetts Substance List: This product contains the following components subject to reporting requirements: Hydrogen peroxide Canada: Workplace Hazardous materials Information System (WHMIS)-listed material. This product contains the following components subject to reporting requirements: None TSCA Section 8(b) Inventory Status: All ingredients in this product are listed on the TSCA Inventory or are not required to be listed on the TSCA Inventory. 16. OTHER INFORMATION Effective Date: March 1, 2005 Supersedes MSDS dated June 10, 2002 MSDS Status: Revised sections 1,3,4,8,9,15 The information on this sheet is limited to the material identified and is believed by the Colgate-Palmolive Company to be correct based on its knowledge and information as of the date noted. Colgate makes no representation, guarantee or warranty, expressed or implied, as to the accuracy, reliability or completeness of the information and assumes no responsibility for injury, damage or loss resulting from the use of the material. Page 793 of 1235 Page 793 of 1235 Page 793 of 1235 Page 793 of 1235 ---PAGE BREAK--- Material Safety Data Sheet Page 1 of 6 Section 1: Product & Company Identification Product Name: NAPA/CRC® QD® Electronic Cleaner (Aerosol) Product Number 091843 Manufactured By: CRC Industries, Inc. General Information (215) 674-4300 885 Louis Drive Technical Assistance (800) 521-3168 Warminster, PA 18974 Customer Service (800) 272-4620 www.crcindustries.com 24-Hr Emergency (CHEMTREC) (800) 424-9300 Section 2: Hazards Identification Emergency Overview Appearance & Odor: Clear, colorless liquid with alcohol odor DANGER Extremely flammable. Harmful or fatal if swallowed. Contents under pressure. As defined by OSHA’s Hazard Communication Standard, this product is hazardous. Potential Health Effects: EYE: May cause mild irritation including stinging and redness, but does not injure eye. SKIN: Single, brief exposures may cause mild irritation. Frequent or prolonged contact may cause more severe irritation, defatting of the skin, and dermatitis. INHALATION: High vapor concentrations are irritating to the respiratory tract and may cause headaches, dizziness, anesthesia, drowsiness, unconsciousness and other central nervous system effects, including death. May cause peripheral nervous system disorder and/or damage. INGESTION: Low order of toxicity by ingestion. Main hazard is aspiration into the lungs during swallowing or vomiting. Small amounts aspirated into the respiratory system may cause bronchopneumonia or pulmonary adema, possible progressing to death. CHRONIC EFFECTS: Overexposure to n-hexane may cause progressive and potentially irreversible damage to the peripheral nervous system, particularly in the arms and legs. TARGET ORGANS: central nervous system, peripheral nervous system, respiratory system Medical Conditions Aggravated by Exposure: skin and respiratory conditions See Section 11 for toxicology and carcinogenicity information on product ingredients. Page 794 of 1235 Page 794 of 1235 Page 794 of 1235 Page 794 of 1235 ---PAGE BREAK--- Product Name: NAPA/CRC® QD® Electronic Cleaner (Aerosol) Product Number 091843 Page 2 of 6 Section 3: Composition/Information on Ingredients COMPONENT CAS NUMBER % by Wt. Hexane isomers various 60 - 70 n-Hexane 110-54-3 4.8 isoparaffinic hydrocarbon 64741-66-8 5 - 10 Methanol 67-56-1 < 1 1,1-Difluoroethane (HFC-152a) 75-37-6 20 - 30 Section 4: First Aid Measures Eye Contact: Immediately flush with plenty of water for 15 minutes. Call a physician if irritation persists. Skin Contact: Remove contaminated clothing and wash affected area with soap and water. Call a physician if irritation persists. Wash contaminated clothing prior to re-use. Inhalation: Remove person to fresh air. Keep person calm. If not breathing, give artificial respiration. If breathing is difficult give oxygen. Call a physician. Ingestion: DO NOT induce vomiting. Contact a physician immediately. Note to Physicians: Treat Gastric lavage using a cuffed endotracheal tube may be performed at your discretion. Section 5: Fire-Fighting Measures Flammable Properties: This product is extremely flammable in accordance with aerosol flammability definitions (16 CFR 1500.3(c)(6) Flash Point: < 0 F (TCC) Upper Explosive Limit: 9.0 Autoignition Temperature: 489 F Lower Explosive Limit: 1.7 Suitable Extinguishing Media: Class B fire extinguishers, dry chemical, foam or CO2 Products of Combustion: fumes, smoke and carbon monoxide Protection of Fire-Fighters: Firefighters should wear self-contained, NIOSH-approved breathing apparatus for protection against suffocation and possible toxic decomposition products. Proper eye and skin protection should be provided. Use water fog or spray to keep fire-exposed containers cool and to knock down vapors which may result from product decomposition. Do not spray water directly on fire; product will float and could be reignited on surface of water. Section 6: Accidental Release Measures Personal Precautions: Use personal protection recommended in Section 8. Page 795 of 1235 Page 795 of 1235 Page 795 of 1235 Page 795 of 1235 ---PAGE BREAK--- Product Name: NAPA/CRC® QD® Electronic Cleaner (Aerosol) Product Number 091843 Page 3 of 6 Environmental Precautions: Take precautions to prevent contamination of ground and surface waters. Do not flush into sewers or storm drains. Methods for Containment & Clean-up: Dike area to contain spill. Remove all sources of ignition. Ventilate the area with fresh air. If in confined space or limited air circulation area, clean-up workers should wear appropriate respiratory protection. Recover or absorb spilled material using an absorbent designed for chemical spills. Place used absorbents into proper waste containers. Section 7: Handling and Storage Handling Procedures: Use proper grounding and bonding procedures for transferring materials. Do not use product near any source of ignition. Do not touch container to electrical sources as container will conduct electricity. Avoid contact with eyes and skin. Avoid breathing vapors. Storage Procedures: Store in a cool dry area out of direct sunlight. Aerosol cans must be maintained below 120 F to prevent cans from rupturing. Aerosol Storage Level: III Section 8: Exposure Controls/Personal Protection Exposure Guidelines: OSHA ACGIH OTHER COMPONENT TWA STEL TWA STEL TWA SOURCE UNIT Hexane isomers 500(v) 1000(v) 500 1000 NE ppm n-Hexane 500 NE 50(s) NE NE ppm isoparaffinic hydrocarbon NE NE NE NE NE Methanol 200 250 200 250 NE ppm 1,1-Difluoroethane (HFC-152a) NE NE NE NE 1000 AIHA ppm N.E. – Not Established – ceiling – skin – vacated Engineering Controls: Area should have ventilation to provide fresh air. Use local exhaust to prevent accumulation of vapors. Use mechanical means if necessary to maintain vapor levels below the exposure guidelines. If working in a confined space, follow applicable OSHA regulations Respiratory Protection: None required for normal work where adequate ventilation is provided. Use a NIOSH- approved cartridge respirator with an organic vapor cartridge if vapors exceed exposure limits. Use a self-contained breathing apparatus in confined spaces and for emergencies. Eye/face Protection: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear splash-proof goggles. Skin Protection: Use protective gloves such as nitrile, PVC or Viton. Also, use full protective clothing if there is prolonged or repeated contact of liquid with skin. Page 796 of 1235 Page 796 of 1235 Page 796 of 1235 Page 796 of 1235 ---PAGE BREAK--- Product Name: NAPA/CRC® QD® Electronic Cleaner (Aerosol) Product Number 091843 Page 4 of 6 Section 9: Physical and Chemical Properties Physical State: liquid Color: clear, colorless Odor: alcohol Specific Gravity: 0.6699 Initial Boiling Point: 140 F Freezing Point: < -76 F Vapor Pressure: 160 mmHg @ 68 F Vapor Density: > 1 (air = 1) Evaporation Rate: > 1 (Butyl acetate = 1) Solubility: negligible in water pH: NA Volatile Organic Compounds: wt 75 g/L: 501.8 lbs./gal: 4.2 Section 10: Stability and Reactivity Stability: Stable Conditions to Avoid: sources of ignition, temperature extremes Incompatible Materials: strong oxidizers Hazardous Decomposition Products: oxides of carbon Possibility of Hazardous Reactions: No Section 11: Toxicological Information Long-term toxicological studies have not been conducted for this product. The following information is available for components of this product. ACUTE EFFECTS Component Test Result Route Species n-hexane LD50 28710 mg/kg Oral Rat n-hexane LD50 3000 mg/kg Dermal Rabbit n-hexane LC50 48000 ppm/4H Inhalation Rat CHRONIC EFFECTS Carcinogenicity: Component Result OSHA: None listed IARC: None listed NTP: None listed Mutagenicity: No information available Page 797 of 1235 Page 797 of 1235 Page 797 of 1235 Page 797 of 1235 ---PAGE BREAK--- Product Name: NAPA/CRC® QD® Electronic Cleaner (Aerosol) Product Number 091843 Page 5 of 6 Section 12: Ecological Information Ecological studies have not been conducted for this product. The following information is available for components of this product. Ecotoxicity: n-hexane - 48 Hr EC50 water flea: 3.87 mg/L 96 Hr LC50 Lepomis macrochirus: 4.12 mg/L Persistence / Degradability: No information available Bioaccumulation / Accumulation: No information available Mobility in Environment: No information available Section 13: Disposal Considerations Disposal: The dispensed liquid product is a RCRA hazardous waste for the characteristic of ignitability with a waste code of D001 (See 40 CFR Part 261.20 – 261.33). Aerosol containers should be emptied and depressurized before disposal. Empty containers may be recycled. Any liquid product should be managed as a hazardous waste. All disposal activities must comply with federal, state and local regulations. Local regulations may be more stringent than state or national requirements. Section 14: Transport Information Proper shipping description: US DOT (ground): Consumer Commodity, ORM-D Special Provisions: None Section 15: Regulatory Information U.S. Federal Toxic Substances Control Act (TSCA): All ingredients are either listed on the TSCA inventory or are exempt. Comprehensive Environmental Response, Compensation and Liability Act (CERCLA): Reportable Quantities (RQ’s) exist for the following ingredients: n-hexane (5000 lbs) methanol (5000 lbs) Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center ([PHONE REDACTED]) and to your Local Emergency Planning Committee. Superfund Amendments Reauthorization Act (SARA) Title III: Section 302 Extremely Hazardous Substances (EHS): None Section 311/312 Hazard Categories: Fire Hazard Yes Reactive Hazard No Release of Pressure Yes Acute Health Hazard Yes Chronic Health Hazard Yes Page 798 of 1235 Page 798 of 1235 Page 798 of 1235 Page 798 of 1235 ---PAGE BREAK--- Product Name: NAPA/CRC® QD® Electronic Cleaner (Aerosol) Product Number 091843 Page 6 of 6 Section 313 Toxic Chemicals: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: n-hexane methanol Clean Air Act: Section 112 Hazardous Air Pollutants (HAPs): n-hexane, methanol State Regulations California Safe Drinking Water and Toxic Enforcement Act (Prop 65): This product may contain the following chemicals known to the state of California to cause cancer, birth defects or other reproductive harm: NONE State Right to Know: New Jersey: 75-83-2, 110-54-3, 79-29-8, 67-56-1, 75-37-6 107-83-5, 75-83-2, 110-54-3, 79-29-8, 67-56-1, 75-37-6 Massachusetts: 107-83-5, 75-83-2, 110-54-3, 79-29-8, 67-56-1, 75-37-6 Rhode Island : 110-54-3, 67-56-1, 75-37-6 Additional Regulatory Information: This product complies with the VOC limit for Electronic Cleaners under California’s Consumer Products VOC Regulations. Section 16: Other Information NFPA: Health: 2 Flammability: 3 Reactivity: 0 HMIS: Health: 2 Flammability: 3 Reactivity: 0 PPE: B Prepared By: Michelle Rudnick CRC 599C Revision Date: 04/07/2009 Changes since last revision: Propellant change The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. CAS: Chemical Abstract Service NA: Not Applicable ppm: Parts per Million ND: Not Determined TCC: Tag Closed Cup NE: Not Established PMCC: Pensky-Martens Closed Cup g/L: grams per Liter PPE: Personal Protection Equipment lbs./gal: pounds per gallon TWA: Time Weighted Average STEL: Short Term Exposure Limit OSHA: Occupational Safety and Health Administration ACGIH American Conference of Governmental Industrial Hygienists NIOSH National Institute of Occupational Safety & Health Page 799 of 1235 Page 799 of 1235 Page 799 of 1235 Page 799 of 1235 ---PAGE BREAK--- NATURAL MAGIC MATERIAL SAFETY DATA SHEET 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY PRODUCT NAME Natural Magic Citrus Odor Blaster PART No. 6000 APPLICATIONS Air Freshener DATE 11/30/2011 SUPPLIER The Homax Group, Inc 200 Westerly Rd. Bellingham, WA 98226 USA Phone: [PHONE REDACTED] 2. COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENT NAME CAS No. CONTENTS NON HAZARDOUS MIXTURE 100 % The ingredients of this product do not contribute hazards beyond those described in this document. All pertinent health, safety and environmental information has been presented, per the requirements of the US Federal OSHA Hazard Communication Standard (29CFR 1910.1200). 3. HAZARDS IDENTIFICATION Potential Health Effects: Eye: No adverse effects anticipated. Prolonged contact may cause irritation. Skin: No adverse effects anticipated. Prolonged contact may cause irritation. Ingestion: May cause gastrointestinal disturbances. Inhalation: No adverse effects anticipated. Chronic Effects: Carcinogenicity: No components are listed by IARC, NTP, or OSHA as carcinogens. 4. FIRST AID MEASURES INHALATION: Move to fresh air. INGESTION: Do not induce vomiting. Rinse mouth thoroughly. Give a glass of water to drink. Get immediate medical attention. SKIN: Remove contaminated clothing. Rinse immediately with plenty water. Get medical attention if any discomfort continues. EYES: Immediately flush with water for 15 minutes. Get medical attention if any discomfort continues. 5. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Use extinguishing media appropriate for surrounding fire. UNUSUAL FIRE & EXPLOSION HAZARDS: No unusual fire or explosion hazards noted. HAZARDOUS DECOMPOSITION PRODUCTS: Fire creates: Carbon monoxide [CO].Carbon dioxide [CO2] PROTECTIVE MEASURES IN FIRE: Wear self-contained breathing apparatus and full protective clothing to prevent any contact with skin and eyes 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS DURING SPILL: Wear suitable protective equipment as specified under Protective Data on this Safety Data Sheet. SPILL CLEANUP METHODS: Solidified product: Scoop up solids and place in suitable containers for disposal. Melted product: Allow to solidify and treat as above. Solution: Absorb in vermiculite, dry sand or earth and place in appropriate containers. 7. HANDLING AND STORAGE USAGE PRECAUTIONS: Avoid skin and eye contact. Keep Out of Reach of Children. 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Page 800 of 1235 Page 800 of 1235 Page 800 of 1235 Page 800 of 1235 ---PAGE BREAK--- Engineering Controls: Not normally required. Respiratory protection: Not normally required. Eye protection: Goggles or glasses may be used. Skin protection: Rubber gloves may be used. Other protective clothing or equipment: Access to eye wash and safety shower. Work Hygienic Practices: The usual precaution for the handling of chemicals should be observed. 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE AND COLOR: Clear Liquid ODOR: Non Scented SOLUBILITY DESCRIPTION: Soluble BOILING POINT: Not available SPECIFIC GRAVITY[Water=1]: 1.00 PH VALUE 7 FLASH POINT: None 10. STABILITY AND REACTIVITY STABILITY: Stable INCOMPATIBLE MATERIALS None Known. HAZARDOUS POLYMERIZATION Will not occur. CONDITIONS TO AVOID: None Known. 11. TOXICOLOGICAL INFORMATION Product was not tested. 12. ECOLOGICAL INFORMATION ENVIORNMENTAL HAZARDS: Not regarded as dangerous for the environment. 13. DISPOSAL CONSIDERATIONS DISPOSAL METHODS Dispose of in accordance with Federal, State and Local requirements 14. TRANSPORT INFORMATION U.S. DOT (Road or Rail): NOT REGULATED Proper Shipping Name: Hazard Class: ID Number: Packing Group: AIR / WATER / INTERNATIONAL Transport: NOT REGULATED Proper Shipping Name: Hazard Class: ID Number: Packing Group: 15. REGULATORY INFORMATION Toxic Substances Control Act (TSCA): All ingredients are listed on the inventory or are exempt. SARA Section 313 components: None SARA 311/312: Acute: No Chronic: No Fire: No Pressure: No Reactivity: No SARA Section 302 components: None CERCLA components: None California Prop. 65 components: None 16. OTHER INFORMATION This product is sold to consumers for household use in containers of relatively small volume. This MSDS has been Page 801 of 1235 Page 801 of 1235 Page 801 of 1235 Page 801 of 1235 ---PAGE BREAK--- developed to address safety concerns affecting those individuals working in warehouses and other places where large numbers of these containers are stored, as well as those affecting potential users of this product in industrial /occupational settings. All pertinent health, safety and environmental information have been presented in this document, per the requirements of the US Federal OSHA Hazard Communication Standard (29 CFR 1910.1200) and Canadian WHMIS. Disclaimer: As the handling and use of products under user’s conditions are beyond our control, no warranty, expressed or implied, including, but not limited to merchantability or fitness for a particular use, is made concerning this product. The user assumes all risk of use or handling whether or not in accordance with any directions or suggestions of the supplier. Seller shall not be liable to purchaser or any other person for loss or damages directly or indirectly arising from the use of our products, from breach of any warranty or from any other cause, the exclusive remedy against the seller being to require replacement or repair of defective goods. Page 802 of 1235 Page 802 of 1235 Page 802 of 1235 Page 802 of 1235 ---PAGE BREAK--- Page 803 of 1235 Page 803 of 1235 Page 803 of 1235 Page 803 of 1235 ---PAGE BREAK--- Page 804 of 1235 Page 804 of 1235 Page 804 of 1235 Page 804 of 1235 ---PAGE BREAK--- Page 805 of 1235 Page 805 of 1235 Page 805 of 1235 Page 805 of 1235 ---PAGE BREAK--- Page 806 of 1235 Page 806 of 1235 Page 806 of 1235 Page 806 of 1235 ---PAGE BREAK--- Page 807 of 1235 Page 807 of 1235 Page 807 of 1235 Page 807 of 1235 ---PAGE BREAK--- Page 808 of 1235 Page 808 of 1235 Page 808 of 1235 Page 808 of 1235 ---PAGE BREAK--- Page 809 of 1235 Page 809 of 1235 Page 809 of 1235 Page 809 of 1235 ---PAGE BREAK--- Page 810 of 1235 Page 810 of 1235 Page 810 of 1235 Page 810 of 1235 ---PAGE BREAK--- O’REILLY POWER STEERING FLUID Revision Date: 21-January-2011 Page 1 of 7 Material Safety Data Sheet NFPA HMIS Health Hazard 0 Fire Hazard 1 Reactivity 0 Issuing Date 21-January-2011 Revision Date 21-January-2011 Revision Number 2 1. PRODUCT AND COMPANY IDENTIFICATION Product Name O’REILLY POWER STEERING FLUID Part Number: 72813, 72810, 72805, 72805-3 Recommended Use Manufactured by: Omni Specialty Packaging 10399 S. Hwy 1 Shreveport, LA 71115 Phone: 1 (318) 524-1100 Emergency Telephone Number CHEMTREC 1 (800) 424-9300 2. HAZARDS IDENTIFICATION Emergency Overview Appearance Clear Liquid Physical State Liquid Odor Mild petroleum odor Potential Health Effects Principal Routes of Exposure Eye contact, Skin contact, Inhalation, Ingestion Acute Toxicity Eyes Eye contact may result in slight irritation and redness.. Skin Minimally irritating upon direct contact. Inhalation Low hazard at standard temperatures and pressures. Inhalation of oil mist or fumes can cause irritation of the nose, throat and upper respiratory tract Ingestion Do not ingest. May cause nausea, vomiting/diarrhea. Other On rare occasions, prolonged and repeated exposure to oil mist poses a risk of pulmonary disease such as chronic lung inflammation. This condition is usually 1 0 0 Page 811 of 1235 Page 811 of 1235 Page 811 of 1235 Page 811 of 1235 ---PAGE BREAK--- O’REILLY POWER STEERING FLUID Revision Date: 21-January-2011 Page 2 of 7 as a result of repeated small aspirations. Chronic Effects Prolonged exposure may cause chronic effects. Aggravated Medical Conditions Personnel with pre-existing skin disorders should avoid contact with this product. Environmental Hazard See Section 12 for additional Ecological Information. 3. COMPOSITION/INFORMATION ON INGREDIENTS Formula Mixture Chemical Name CAS-No Weight % Solvent-Dewaxed Heavy Paraffinic Distillates (Petroleum) 64742-65-0 91 Viscosity Index Improver Lubricant Mixture 7 Antifoam Package N/A 2 4. FIRST AID MEASURES Eye Contact Flush with large amount of water for 15 minutes. Get medical attention if eye irritation develops or persists. If material is hot, treat for thermal burns and take victim to the hospital immediately. Skin Contact Wash off immediately with soap and plenty of water for at least 15 minutes while removing all contaminated clothing and shoes. Get medical attention immediately if skin discoloration occurs. Inhalation If affected, remove individual to fresh air. If not breathing, give mouth-to-mouth resuscitation. Get medical attention if develop or persist. Ingestion CALL PHYSICIAN IMMEDIATELY. Never give anything by mouth to an unconscious person. Don’t induce vomiting except at the instructions of the physician. Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Flammable Properties Not flammable. Flash Point 380°F Suitable Extinguishing Media Water Fog. Carbon dioxide (CO2). Foam. Dry chemical. Unsuitable Extinguishing Media Water stream may spread fire. Hazardous Combustion Products Decomposition and combustion products may include smoke, carbon dioxide, carbon monoxide, and other low molecular weight hydrocarbons. Explosion Data Sensitivity to Mechanical Impact Not sensitive. Sensitivity to Static Discharge Not sensitive. Protective Equipment and Precautions for Firefighters Wear positive pressure self-contained breathing apparatus (SCUBA). Use water to cool containers exposed to flames. Structural firefighters’ protective clothing will only provide limited protection. Mist or sprays may be flammable below the product normal flash point. Page 812 of 1235 Page 812 of 1235 Page 812 of 1235 Page 812 of 1235 ---PAGE BREAK--- O’REILLY POWER STEERING FLUID Revision Date: 21-January-2011 Page 3 of 7 NFPA Health Hazard 0 Flammability 1 Reactivity 0 Physical and Chemical Hazards - 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Use personal protective equipment. Avoid contact with skin, eyes, and clothing. Ensure adequate ventilation. Methods for Containment Dike far ahead of liquid spill for later disposal. Methods for Cleaning Up Pick up free liquid for recycle and/or disposal. Residual liquid and/or solid can be absorbed on inert material. Evacuation Procedures Large Spill Consider initial downwind evacuate for at least 300 meters (1000 feet). Fire If tank, rail car or tank car is involved in a fire, isolate for 800 meters (1/2 mile) in all directions; also consider initial evacuation for 800 meters (1/2 mile) in all directions. Reporting Requirements Spills that enter a water body must be reported immediately to the USEPA’s National Response Center at (800)546-2972. Check with your local and state regulators regarding their reporting requirements. 7. HANDLING AND STORAGE Handling Do not pressure, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition; they may explode. See NFPA 30 and OSHA 1910.106 – flammable and combustible liquids. Storage Store away from heat, sparks, open flame, or strong oxidizing agents in closed and properly labeled containers. Empty containers retain product residue (liquid, and/or vapor) and can be dangerous 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Solvent-Dewaxed Heavy Paraffinic Distillates (Petroleum) 64742-65-0 5 mg/m³ mist 5 mg/m³ mist None listed Engineering Measures Additional area ventilation or local exhaust may be required to maintain air concentrations below recommended limits. Personal Protective Equipment Eye/Face Protection Safety glasses or face shield where splashing is possible. Full face-shield to be worn during emergencies. Skin and Body Protection As needed to prevent repeated skin contact. Solvent resistant gloves should be used if needed. Respiratory Protection Not normally needed. During emergencies wear respirator. Hygiene Measures Remove and wash contaminated clothing before re-use. Wash hands before breaks and immediately after handling the product. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 813 of 1235 Page 813 of 1235 Page 813 of 1235 Page 813 of 1235 ---PAGE BREAK--- O’REILLY POWER STEERING FLUID Revision Date: 21-January-2011 Page 4 of 7 Appearance Clear Liquid Odor Mild petroleum odor Physical State Liquid pH N/A Flash Point 380°F Autoignition Temperature 600°F Boiling Point/Range >500°F Freezing Point <-40°C Explosion Limits N/A Flammability Limits in Air N/A Specific Gravity 0.85 Solubility Negligible Evaporation Rate N/A Vapor Pressure N/A Vapor Density Not Determine Density N/A 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions. Incompatible Products Open Flame and strong oxidizing agents. Conditions to Avoid Heat, flames, and sparks. Hazardous Decomposition Products Decomposition and combustion products may include hydrogen sulfide, alkyl mercaptans, sulfides, oxides or sulfur, oxides of : phosphorous, calcium and zinc; aldehydes, carbon monoxide and carbon dioxide. Hazardous Polymerization None under normal processing. 11. TOXICOLOGICAL INFORMATION Acute Toxicity Product Information Test on similar materials show a low order of acute oral and dermal toxicity. Acute Oral Effects Test on similar materials indicates low order of acute toxicity. Acute Inhalation Effects Low acute toxicity expected on inhalation. Skin Effects Practically non-toxic if absorbed. Other similar highly refined products have not shown skin tumors in mouse skin painting studies. Eye Irritation Minimal irritation on contact. Eye irritation or practically non-irritating base on similar products. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Solvent-Dewaxed Heavy Paraffinic Distillates (Petroleum) 64742-65-0 Rat >2000 mg/kg Rabbit >2000 mg/kg Rat > 2.18 mg/L 4 hours Chronic Toxicity Chronic Toxicity Prolonged exposure may cause chronic effects. Carcinogenicity Not considered a potential carcinogen base on IP346 DMSO of less than 3.0 wt% Target Organ Effects Respiratory system, Eyes, Skin, Genotoxicity This product is considered non-mutagenic and has negative potential for tumor development based on from Modified Ames Assay, with Mutagenic Index of less than 1.0. 12. ECOLOGICAL INFORMATION Ecotoxicity If applied to leaves, this product may kill grasses and small plants by interfering with Page 814 of 1235 Page 814 of 1235 Page 814 of 1235 Page 814 of 1235 ---PAGE BREAK--- O’REILLY POWER STEERING FLUID Revision Date: 21-January-2011 Page 5 of 7 transpiration and respiration. This product is not toxic to fish but may coat gill structures resulting in suffocation if spilled in shallow, running water. Product may be moderately toxic to amphibians by preventing dermal respiration. This product may cause gastrointestinal distress to birds and mammals through ingestion during pelage grooming. Chemical Name Toxicity to Algae Toxicity to Fish Microtox Daphnia Magna (Water Flea) Solvent-Dewaxed Heavy Paraffinic Distillates (Petroleum) 64742-65-0 13. DISPOSAL CONSIDERATIONS Waste Disposal Method Dispose of in accordance with local regulations. Keep this product out of sewers and waterways. Contaminated Packaging Dispose of in accordance with local regulations. Chemical Name RCRA – Halogenated Organic Compounds RCRA – P Series Wastes RCRA – F Series Wastes RCRA – K Series Wastes Does not meet hazardous waste criteria Does not meet hazardous waste criteria Does not meet hazardous waste criteria Does not meet hazardous waste criteria 14. TRANSPORT INFORMATION DOT Not regulated IATA Not regulated IMDG/IMO Not regulated 15. REGULATORY INFORMATION International Inventories TSCA DSL EINECS/ELINCS ENCS IECSC KECL PICCS AICS Solvent-Dewaxed Heavy Paraffinic Distillates (Petroleum) 64742-65-0 Present X 265-169-7 X X X X X U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No Page 815 of 1235 Page 815 of 1235 Page 815 of 1235 Page 815 of 1235 ---PAGE BREAK--- O’REILLY POWER STEERING FLUID Revision Date: 21-January-2011 Page 6 of 7 Clean Water Act If spilled into navigable waters it is reportable to National Response Center, [PHONE REDACTED]. Reportable Quantity = Oil Sheen present on navigable water surface. (40 CFR 116; 401.15) Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990. CERCLA U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. Florida No listed ingredients are present Massachusetts RTK No listed ingredients are present Minnesota RTK No listed ingredients are present New Jersey RTK Lists petroleum oil, but this product does not contain hazardous ingredients. RTK Lists petroleum oil, but this product does not contain hazardous ingredients greater than Illinois DOL TSL No listed ingredients are present International Regulations Mexico – Grade No information available. Canada Not listed on the Canadian Controlled Product Ingredient Disclosure and is compliant with Controlled Products Regulation CONEG Metals Since cadmium, chromium, lead and mercury are not detectable and it does not exceed 100 ppm total in this product, it is compliant with CONEG Metals regulation. EEC (Europe) This product is not known to be a dangerous good internationally. R-Phrases R45: May Cause Cancer S-Phrases S53: Avoid Exposure S45 Hazard Label None Danger Symbol T : Toxic This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class D2B Toxic materials 16. OTHER INFORMATION Prepared By Safety Department Issuing Date 21-January-2011 Revision Date 21-January-2011 Revision Note Not applicable Page 816 of 1235 Page 816 of 1235 Page 816 of 1235 Page 816 of 1235 ---PAGE BREAK--- O’REILLY POWER STEERING FLUID Revision Date: 21-January-2011 Page 7 of 7 Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of MSDS Page 817 of 1235 Page 817 of 1235 Page 817 of 1235 Page 817 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 OFF!® FamilyCare Spray Insect Repellent For Use on Kids Tropical Fresh® REG. NO. 27325 P.C.P. ACT Version 1.0 Print Date 06/24/2015 Revision Date 12/06/2013 MSDS Number 350000022090 1/8 1. PRODUCT AND COMPANY IDENTIFICATION Product information Trade name : OFF!® FamilyCare Spray Insect Repellent For Use on Kids Tropical Fresh® REG. NO. 27325 P.C.P. ACT Use of the Substance/Mixture : Insect Repellent Company : S.C. Johnson and Son, Limited 1 Webster Street Brantford ON N3T 5R1 Emergency telephone number : 24 Hour Transport & Medical Emergency Phone (866) 231- 5406 24 Hour International Emergency Phone (952) 852-4647 24 Hour Canadian Transport Emergency Phone (CANUTEC) (613) 996-6666 2. HAZARDS IDENTIFICATION Emergency Overview Appearance / Odor : clear / liquid / pleasant Immediate Concerns : Warning FLAMMABLE: CAUSES EYE IRRITATION. Keep away from heat, sparks and flame. Avoid contact with eyes and lips. Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion. Eyes : Causes: Moderate eye irritation Skin : May cause skin reactions in rare cases. Prolonged or repeated contact may dry skin and cause irritation. Inhalation : May cause nose, throat, and lung irritation. Inhalation may cause central nervous system effects. Ingestion : May cause irritation to mouth, throat and stomach. May cause abdominal discomfort. Causes headache, drowsiness or other effects to the central nervous system. Page 818 of 1235 Page 818 of 1235 Page 818 of 1235 Page 818 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 OFF!® FamilyCare Spray Insect Repellent For Use on Kids Tropical Fresh® REG. NO. 27325 P.C.P. ACT Version 1.0 Print Date 06/24/2015 Revision Date 12/06/2013 MSDS Number 350000022090 2/8 Aggravated Medical Condition : Persons with pre-existing skin disorders may be more susceptible to irritating effects. Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, etc. may be more susceptible to irritating effects Do not apply to cuts or irritated skin. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or the Canadian Controlled Products Regulations are listed in this table: Chemical Name CAS-No. Weight percent Ethyl alcohol 64-17-5 60.00 - 100.00 N,N-Diethyl-m-toluamide 134-62-3 5.00 - 10.00 For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Eye contact : Remove contact lenses. Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention if irritation develops and persists. Skin contact : Wash off immediately with plenty of water. Rinse with plenty of water. Get medical attention if irritation develops and persists. If you suspect a reaction to this product, discontinue use and remove contaminated clothing. Inhalation : Remove to fresh air. Ingestion : If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during firefighting : Flammable liquid. Vapors are heavier than air and may travel to a source of ignition and flash back. Liquid run-off to sewers may create fire/explosion hazard. Burns with colourless flame. Container may melt and leak in heat of fire. Do not allow run-off Page 819 of 1235 Page 819 of 1235 Page 819 of 1235 Page 819 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 OFF!® FamilyCare Spray Insect Repellent For Use on Kids Tropical Fresh® REG. NO. 27325 P.C.P. ACT Version 1.0 Print Date 06/24/2015 Revision Date 12/06/2013 MSDS Number 350000022090 3/8 from fire fighting to enter drains or water courses. Further information : Fight fire from maximum distance or protected area. Cool and use caution when approaching or handling fire-exposed containers. For large quantities of flammable liquids, consider containment to prevent the spread of fire. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. Flash point : 63 °F Method: Tag Closed Cup (TCC) Lower explosion limit : Note: no data available Upper explosion limit : Note: no data available 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Remove all sources of ignition. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Wear personal protective equipment. Environmental precautions : Do not flush into surface water or sanitary sewer system. Use appropriate containment to avoid environmental contamination. Outside of normal use, avoid release to the environment. Methods for cleaning up : Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Dike large spills. Clean residue from spill site. 7. HANDLING AND STORAGE Handling Advice on safe handling : Avoid contact with eyes and lips. Avoid breathing vapours, mist or gas. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Page 820 of 1235 Page 820 of 1235 Page 820 of 1235 Page 820 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 OFF!® FamilyCare Spray Insect Repellent For Use on Kids Tropical Fresh® REG. NO. 27325 P.C.P. ACT Version 1.0 Print Date 06/24/2015 Revision Date 12/06/2013 MSDS Number 350000022090 4/8 Advice on protection against fire and explosion : Keep away from heat and sources of ignition. Take measures to prevent the build up of electrostatic charge. Storage Requirements for storage areas and containers : Keep away from food, drink and animal feedingstuffs. Keep container closed when not in use. Keep in a dry, cool and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Non- standard units Basis Ethyl alcohol 64-17-5 - 1,000 ppm - ACGIH STEL Personal protective equipment Respiratory protection Use only with adequate ventilation. Do not spray in enclosed areas. Hand protection : No special requirements. Eye protection Safety glasses with side-shields Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : liquid Color : clear Odor : pleasant pH : 7.58 at 20 °C Melting point : no data available Page 821 of 1235 Page 821 of 1235 Page 821 of 1235 Page 821 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 OFF!® FamilyCare Spray Insect Repellent For Use on Kids Tropical Fresh® REG. NO. 27325 P.C.P. ACT Version 1.0 Print Date 06/24/2015 Revision Date 12/06/2013 MSDS Number 350000022090 5/8 Boiling point : no data available Freezing point : no data available Flash point : 63 °F Method: Tag Closed Cup (TCC) Evaporation rate : no data available Flammability (solid, gas) : Sustains combustion Auto-ignition temperature : no data available Lower explosion limit : no data available Upper explosion limit : no data available Vapour pressure : no data available Density : 0.826 g/cm3 at 20 °C Water solubility : soluble Partition coefficient: n- octanol/water : no data available Viscosity, dynamic : no data available Viscosity, kinematic : no data available Relative vapour density : no data available Volatile Organic Compounds Total VOC (wt. : 89.9 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations 10. STABILITY AND REACTIVITY Conditions to avoid : Heat, flames and sparks. Materials to avoid : Strong oxidizing agents Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. Page 822 of 1235 Page 822 of 1235 Page 822 of 1235 Page 822 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 OFF!® FamilyCare Spray Insect Repellent For Use on Kids Tropical Fresh® REG. NO. 27325 P.C.P. ACT Version 1.0 Print Date 06/24/2015 Revision Date 12/06/2013 MSDS Number 350000022090 6/8 Thermal decomposition : Note: no data available Hazardous reactions : Stable under recommended storage conditions. 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50 > 5,000 mg/kg Acute inhalation toxicity : LC50 > 2.2 mg/l Acute dermal toxicity : LD50 > 2,000 mg/kg Chronic effects Carcinogenicity : no data available Mutagenicity : no data available Reproductive effects : no data available Teratogenicity : no data available Sensitisation : no data available 12. ECOLOGICAL INFORMATION Ecotoxicity effects : no data available 13. DISPOSAL CONSIDERATIONS PESTICIDAL WASTE: Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle Page 823 of 1235 Page 823 of 1235 Page 823 of 1235 Page 823 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 OFF!® FamilyCare Spray Insect Repellent For Use on Kids Tropical Fresh® REG. NO. 27325 P.C.P. ACT Version 1.0 Print Date 06/24/2015 Revision Date 12/06/2013 MSDS Number 350000022090 7/8 where facilities exist. RCRA waste class : D001 (Ignitable Waste) 14. TRANSPORT INFORMATION Land transport  U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name UN 1993 Flammable liquid, N.O.S. (Ethyl alcohol) Class: 3 UN number 1993 Packaging group: III Note: SC Johnson ships this product as INSECTICIDES OR INSECT REPELLENTS, NOI, OTHER THAN POISON. Sea transport  IMDG: Proper shipping name UN 1993 Flammable liquid, N.O.S. (Ethyl alcohol) Class: 3 UN number: 1993 Packaging group: III EmS: F-E, S-E Note: Limited quantities derogation may be applicable to this product, please check transport documents. Air transport  ICAO/IATA: Proper shipping name UN 1993 Flammable liquid, N.O.S. (Ethyl alcohol) Class: 3 UN/ID No.: UN 1993 Packaging group: III Note: SC Johnson typically does not ship products via air. Refer to IATA/ICAO Dangerous Goods Regulations for detailed instructions when shipping this item by air. 15. REGULATORY INFORMATION Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Notification status : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA). Page 824 of 1235 Page 824 of 1235 Page 824 of 1235 Page 824 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 OFF!® FamilyCare Spray Insect Repellent For Use on Kids Tropical Fresh® REG. NO. 27325 P.C.P. ACT Version 1.0 Print Date 06/24/2015 Revision Date 12/06/2013 MSDS Number 350000022090 8/8 California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65. 16. OTHER INFORMATION HMIS Ratings Health 2 Flammability 4 Reactivity 0 NFPA Ratings Health 2 Fire 4 Reactivity 0 Special - This information is being provided in accordance with Occupational Safety and Health Administration (OSHA) and Canada’s Workplace Hazard Material Information System (WHMIS) regulations. The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use. Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 825 of 1235 Page 825 of 1235 Page 825 of 1235 Page 825 of 1235 ---PAGE BREAK--- Page 826 of 1235 Page 826 of 1235 Page 826 of 1235 Page 826 of 1235 ---PAGE BREAK--- Page 827 of 1235 Page 827 of 1235 Page 827 of 1235 Page 827 of 1235 ---PAGE BREAK--- Page 828 of 1235 Page 828 of 1235 Page 828 of 1235 Page 828 of 1235 ---PAGE BREAK--- Page 829 of 1235 Page 829 of 1235 Page 829 of 1235 Page 829 of 1235 ---PAGE BREAK--- Page 830 of 1235 Page 830 of 1235 Page 830 of 1235 Page 830 of 1235 ---PAGE BREAK--- Page 831 of 1235 Page 831 of 1235 Page 831 of 1235 Page 831 of 1235 ---PAGE BREAK--- Page 832 of 1235 Page 832 of 1235 Page 832 of 1235 Page 832 of 1235 ---PAGE BREAK--- Page 833 of 1235 Page 833 of 1235 Page 833 of 1235 Page 833 of 1235 ---PAGE BREAK--- Peak Long Life 50/50 Antifreeze/Coolant 1 Initial Preparation Date: 7/08/2004 Last Revision Date: 4/04/2012 Effective Date: 6/4/2012 MATERIAL SAFETY DATA SHEET PRODUCT IDENTITY: PEAK LONG LIFE 50/50 ANTIFREEZE & COOLANT 1. CHEMICAL PRODUCT & COMPANY INFORMATION OLD WORLD INDUSTRIES, LLC 4065 COMMERCIAL AVENUE ILLINOIS 60062 PHONE: [PHONE REDACTED] EMERGENCY PHONE: 1-[PHONE REDACTED] (CHEMTREC) 2. COMPOSITION/INFORMATION ON INGREDIENTS Material CAS# % by Wt PEL (OSHA) TLV (ACGIH) Water 7732-18-5 49-50 None None Ethylene Glycol 107-21-1 45-48 50 ppm 50 ppm Diethylene Glycol 111-46-6 <3 None None Denatonium Benzoate 3734-33-6 30-50 ppm None None Organic acid salts proprietary <3 10mg/m3 1mg/m3 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Slight odor. May be fatal if swallowed. Vapors can cause eye irritation. Lowest Known LD50 (Oral) 107-21-1 11,680 mg/kg (Rats) Lowest Known LD50 (Skin) 107-21-1 19,060 mg/kg (Rabbits) HAZARD RATING SYSTEM NFPA: HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0 HMIS: HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0 KEY: 0 – Minimal 1 – Slight 2 - Moderate 3 - Serious 4 - Severe Page 834 of 1235 Page 834 of 1235 Page 834 of 1235 Page 834 of 1235 ---PAGE BREAK--- Peak Long Life 50/50 Antifreeze/Coolant 2 POTENTIAL HEALTH EFFECTS Routes of Exposure: Inhalation, Ingestion, Skin Contact/Absorption, Eye Contact Eye: May cause slight transient (temporary) eye irritation. Corneal injury is unlikely. Vapors or mists may cause eye irritation. Skin: Prolonged or repeated exposure not likely to cause significant skin irritation. A single prolonged exposure is not likely to result in the material being absorbed through skin in harmful amounts. Repeated skin exposure may result in absorption of harmful amounts. Massive contact with damaged skin or of material sufficiently hot to burn skin may result in absorption of potential lethal amounts. Ingestion: Single dose oral toxicity is considered to be moderate. Excessive exposure may cause central nervous system effects, cardiopulmonary effects (metabolic acidosis), and kidney failure. Small amounts swallowed incidental to normal handling operations are not likely to cause injury; however, swallowing amounts larger than that may cause serious injury, even death. Inhalation: At room temperature, exposures to vapors are minimal due to physical properties; higher temperatures may generate vapor levels sufficient to cause adverse effects. Systemic (Other Target Organ) Effects: Repeated excessive exposures may cause severe kidney and also liver and gastrointestinal effects. Signs and of excessive exposure may be central nervous system effects. Signs and of excessive exposure may be nausea and/or vomiting. Signs and of excessive exposure may be anesthetic or narcotic effects. Observations in animals include formation of bladder stones after repeated oral doses of ethylene glycol. Reports of kidney failure and death in burn patients suggest the ethylene glycol may have been a factor. The use of topical applications containing this material may not be appropriate in severely burned patients or individuals with impaired renal function. Cancer Information: Based on data from long-term animal studies, ethylene glycol is not believed to pose a carcinogenic risk to man. Teratology (Birth Defects): Exposure to ethylene glycol has caused birth defects in laboratory animals only at doses toxic to the mother. Reproductive Effects: Ethylene glycol has not interfered with reproduction in animal studies except at very high doses. CHRONIC, PROLONGED OR REPEATED OVEREXPOSURE Effects of Repeated Overexposure: Repeated inhalation of ethylene glycol mist may produce signs of central nervous system involvement, particularly dizziness and nystagmus. Other Effects of Overexposure: repeated skin contact with ethylene glycol may, in a very small proportion of cases, cause sensitization with the development of allergic contact dermatitis. The incidence is significantly less than 1% with the undiluted material. Page 835 of 1235 Page 835 of 1235 Page 835 of 1235 Page 835 of 1235 ---PAGE BREAK--- Peak Long Life 50/50 Antifreeze/Coolant 3 4. FIRST AID MEASURES Ensure physician has access to this MSDS. TREATMENT Eyes: Immediately flush eyes with large amounts of water for 15 minutes, lifting lower and upper lids. Get medical attention as soon as possible. Contact lenses should never be worn when working with this chemical. Skin: Flush area of skin contact immediately with large amounts of water for at least 15 minutes while removing contaminated clothing. If irritation persists after flushing, get medical attention Wash clothing before re- use. Inhalation: If inhaled, immediately remove victim to fresh air and call emergency medical care. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Ingestion: Obtain medical attention immediately. If patient is fully conscious, give two glasses of water. Do not induce vomiting. If medical advice is delayed, and if the person has swallowed a moderate volume of material (a few ounces), then give three to four ounces of hard liquor, such as whisky. For children, give proportionally less liquor, according to weight. Notes to Physician: It is estimated that the lethal oral dose to adults is of the order of 1.0 ml/kg. Ethylene glycol is metabolized by alcohol dehydrogenate to various metabolites including glyceraldehydes, glycolic acid and oxalic acid which cause an elevated anion-gap metabolic acidosis and renal tubular injury. The signs and in ethylene glycol poisoning are those of metabolic acidosis, CNS depression, and kidney injury. Urinalysis may show albuminuria, hematuria and oxaluria. Clinical chemistry may reveal anion-gap metabolic acidosis and uremia. The currently recommended medical management of ethylene glycol poisoning includes elimination of ethylene glycol and metabolites, correction of metabolic acidosis and prevention of kidney injury. It is essential to have immediate and follow up urinalysis and clinical chemistry. There should be particular emphasis on acid-base balance and renal function tests. A continuous infusion of 5% sodium bicarbonate with frequent monitoring of electrolytes and fluid balance is used to achieve correction of metabolic acidosis and forced diuresis. As a competitive substrate for alcohol dehydrogenase, ethanol is antidotal. Given in the early stages of intoxication, it blocks the formulation of nephrotoxic metabolites. A therapeutically effective blood concentration of ethanol is in the range 100-150 mg/dl, and should be achieved by a rapid loading dose and maintained by intravenous infusion. For severe and/or deteriorating cases, hemodialysis may be required. Dialysis should be considered for patients who are have severe metabolic acidosis, a blood ethylene glycol concentration greater than 25 md/dl, or compromise of renal functions. A more effective intravenous antidote for physician use is a potent inhibitor of alcohol dehydrogenases, which effectively blocks the formation of toxic metabolites of ethylene glycol. It has been used to decrease the metabolic consequences of ethylene glycol poisoning before metabolic acidosis coma, seizures, and renal failure have occurred. A generally recommended protocol is a loading dose of 15 mg/kg followed by 10 mg/kg every 12 hours for 4 doses and then 15 mg/kg every 12 hours until ethylene glycol concentrations are below 20 mg/100 ml. Slow intravenous infusion is required. Since is dialyzable, increased dosage may be necessary during hemodialysis. Additional therapeutic measures may include the administration of cofactors involved in the metabolism of ethylene glycol. Thiamine (100 mg) and pyridoxine (50 mg) should be given every six hours. Pulmonary edema with hypoxemia has been described in a number of patients following poisoning with ethylene glycol. The mechanism of production has not been elucidated, but it appears to be non-cardiogenic in origin in several cases. Respiratory support with mechanical ventilation and positive end expiratory pressure may be required. There may be cranial nerve involvement in the late stages of toxicity from swallowed ethylene glycol. In particular, effects have been reported involving the seventh, eighth and ninth cranial nerves, presenting with bilateral facial paralysis, diminished hearing and Page 836 of 1235 Page 836 of 1235 Page 836 of 1235 Page 836 of 1235 ---PAGE BREAK--- Peak Long Life 50/50 Antifreeze/Coolant 4 5. FIRE FIGHTING MEASURES Flammable Properties: Flash Point: None, since percentage of water is over 20. Auto-ignition Temperature: 100% ethylene glycol is 398C (748F). Flammability Limits: Percentage of vapor concentration at which product can ignite in presence of spark: Lower Flammability Limit: Not determined Upper Flammability Limit: Not determined Flammability limits are not determined on this product because the solution consists of 50% water. If and when the water evaporates and 100% glycol is left, the upper and lower flammability limits would be 3.2% and 15.3% (the same as concentrated Ethylene glycol). Hazardous Combustion Products: Hazardous combustion products may include and are not limited to carbon monoxide, carbon dioxide and trace amounts of aldehydes and organic acids. When available oxygen is limited, as in a fire or when heated to very high temperatures by a hot wire or plate, carbon monoxide and other hazardous compounds such as aldehydes might be generated. Extinguishing Media: Water fog or fine spray. Alcohol resistant foams (ATC type) are preferred if available. General purpose foams (including AFFF) or protein foams may function, but much less effectively. Carbon dioxide. Dry chemical. Do not use direct water stream. May spread fire. Fire Fighting Instructions: No fire and explosion hazards expected under normal storage and handling conditions (i.e. ambient temperatures). However, ethylene glycol or solutions of ethylene glycol and water can form flammable vapors with air if heated sufficiently. Keep people away. Isolate fire area and deny unnecessary entry. Protective Equipment for Fire Fighters: Wear positive-pressure, self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire-fighting helmet, coat, pants, boots and gloves). 6. ACCIDENTAL RELEASE MEASURES Protect People: Material is moderately toxic when ingested. Take adequate precautions to keep people, especially children away from spill site. PVC-coated rubber gloves and mono-goggles or face shield can be used during cleanup of spill site. Product on surfaces can cause slippery conditions. Practice reasonable care and cleanliness. Avoid breathing spray mists if generated. Keep out of reach of children. Product may become a solid at temperatures below -18oC (0oF). Do not store near food, foodstuffs, drugs or potable water supplies. Protect the Environment: Do not dump used product or diluted material into sewers, on the ground, or into any body of water. Cleanup: Small spills: Soak up with absorbent material. Large spills: Dike and pump into suitable containers for disposal. Ensure compliance with all applicable statues that require notification of appropriate government officials. 7. HANDLING AND STORAGE Steps to be Taken in Case Material is Released or Spilled: Eliminate all sources of ignition in vicinity of the spilled or released fluid. Other Precautions: Use normal precautions in handling any combustible liquid. Keep container closed when not in use. Store away from heat or open flame. Product on surfaces can cause slippery conditions. Practice reasonable Page 837 of 1235 Page 837 of 1235 Page 837 of 1235 Page 837 of 1235 ---PAGE BREAK--- Peak Long Life 50/50 Antifreeze/Coolant 5 care and cleanliness. Avoid breathing spray mists if generated. Keep out of reach of children. Product may become a solid at temperatures below -37oC (-34oF). Do not store near food, foodstuffs, drugs or potable water supplies. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Respiratory Protection: Respiratory protection is required if airborne concentration exceeds TLV. At any detectable concentration any self-contained breathing apparatus with a full face piece and operated in a pressure- demand or other positive pressure mode or any supplied-air respirator with a full face piece and operated in a pressure-demand or other positive pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive pressure mode. Escape: Any air-purifying full face piece respirator (gas mask) with a chin-style or front- or back-mounted organic vapor canister or any appropriate escape-type self-contained breathing apparatus. Skin Protection: Protective gloves recommended when prolonged skin contact cannot be avoided. Polyethylene; Neoprene; Nitrile; Polyvinyl alcohol; Natural Rubber, Butyl Rubber. Safety shower should be available. Eye Protection: Safety goggles and face shield. Emergency eyewash should be available. Contact lenses should not be worn when working with this chemical. Engineering Controls: Use general or local exhaust ventilation to meet TLV requirements. EXPOSURE LIMITS Component Exposure Limits Skin Form Ethylene glycol 100 mg/m3 CEILING ACGIH Aerosol Ethylene glycol 125 mg/m3 CEILING OSHA-vacated 50 ppm CEILING OSHA – vacated 100 mg/m3 CEILING UCC Aerosol and Vapor Diethylene glycol 50 ppm TWA8 AIHA WEEL Aerosol and Vapor Diethylene glycol 10 mg/m3 TWA8 AIHA WEEL Aerosol In the Exposure Limits Chart above, if there is no specific qualifier Aerosol) listed in the Form Column for a particular limit, the listed limit includes all airborne forms of the substance that can be inhaled. A “blank” in the Skin column indicates that exposure by the cutaneous (skin) route is not a potential significant contributor to overall exposure. 9. PHYSICAL / CHEMICAL PROPERTIES Boiling Point: 107oC (226oF) Freeze Point: -37oC (-34oF) Specific Gravity (Water 1.07 Vapor Pressure (mm of Hg) @ 20C: <0.1 Vapor Density (air=1): Not Established Water Solubility: Complete Evaporation Rate (BuAc = Nil % Volatile By Volume: 45-48 Appearance: Yellow/Green Odor: Mild pH: 8.0 Page 838 of 1235 Page 838 of 1235 Page 838 of 1235 Page 838 of 1235 ---PAGE BREAK--- Peak Long Life 50/50 Antifreeze/Coolant 6 10. STABILITY & REACTIVITY DATA Stability: Stable Conditions to Avoid: Keep away from flame Incompatibility (Materials to Avoid): Strong acid or oxidizing agents Hazardous Decomposition Products: Incomplete combustion may produce CO gas Hazardous Polymerization: Will not occur 11. TOXICOLOGICAL INFORMATION (Concentrated Ethylene Glycol) Skin: The dermal LD50 has not been determined. Ingestion: The lethal dose in humans is estimated to be 100 ml (3 ozs.). The oral LD50 for rats is in the 6000- 13,000-mg/kg range. Hydrated Inorganic Acid Sodium Salt: The lowest dose of a similar compound reported to produce death in humans was estimated to be 709 mg/kg body weight for a person weighing 150 pounds, this would be equivalent to swallowing about one-tenth of a pound of the dry material in a short period of time. Acute oral LD50s for a similar compound = 2,650 mg/kg (rats) 2,000 mg/kg (mice) Mutagenicity (The Effects on Genetic Material): In vitro mutagenicity studies were negative. Animal mutagenicity studies were negative. Significant Data with Possible Relevance to Humans: Ethylene glycol has been shown to produce dose-related teratogenic effects in rats and mice when given by gavage or in drinking water at high concentrations or doses. The no-effect doses for developmental toxicity for ethylene glycol given by gavage over the period of organogenesis has been shown to be 150 mg/kg/day for the mouse and 500 mg/kg/day for the rat. Also, in a preliminary study to asses the effects of exposure of pregnant rats and made to aerosis at concentrations of 150, 1000 and 25000 mg/m3 for 6 hours a day throughout the period of organogenesis, teratogenic effects were produced at the highest concentration, but only in mice. The conditions of these latter experiments did not allow a conclusion as to whether the developmental toxicity was mediated by inhalation of aerosol percutaneous absorption of ethylene glycol from contaminated skin, or swallowing ethylene glycol as a result of grooming the wetted coat. In a further study, comparing effects from high aerosol concentration by whole-body or nose-only exposure, it was shown that nose- only exposure resulted in maternal toxicity (1000 and 25000 mg/m3) and developmental toxicity with minimal evidence of teratogenicity (2500 mg/m3). The no-effects concentration (based on maternal toxicity) was 500 mg/m3. In a further study in mice, no teratogenic effects could be produced when ethylene glycol was applied to skin of pregnant mice over the period of organogenesis. The above observations suggest that ethylene glycol is to be regarded as an animal teratogen. There is currently no available information to suggest that ethylene glycol has caused birth defects in humans. Cutaneous application of ethylene glycol is ineffective in producing developmental toxicity. Exposure to high aerosol concentrations is only minimally effective in producing developmental toxicity. The major route for producing developmental toxicity is perorally. Two chronic feeding studies, using rats and mice, have not produced any evidence that ethylene glycol causes dose-related increases in tumor incidence or a different pattern of tumors compared with untreated controls. The absence of carcinogenic potential for ethylene glycol has been supported by numerous in vitro genotoxicity studies showing that it does not produce mutagenic or clastogenic effects. A chronic dietary feeding study of diethylene glycol with rats showed mild kidney injury at while concentrations of 2% and 4% caused more marked kidney injury. In addition, at 2% and 4% of diethylene glycol in the diet, some rats developed benign papillary tumors in the urinary bladder. These have been attributed to the presence of urinary Page 839 of 1235 Page 839 of 1235 Page 839 of 1235 Page 839 of 1235 ---PAGE BREAK--- Peak Long Life 50/50 Antifreeze/Coolant 7 bladder calcium oxalate stones. No evidence for carcinogenicity was found with a chronic skin-painting study with diethylene glycol in mice. The absence of a direct chemical carcinogenic effect addords with the results in vitro genotoxicity studies that show that it does not produce mutagenic or clastogenic effects. A feeding study employing up to 5.0% diethylene glycol in the diet failed to produce any teratogenic effects. In a mouse continuous breeding study with large doses of diethylene glycol in drinking water, there was evidence for reproductive toxicity at 3.5% (equivalent to 6.1 g/kg/day) as reduced number of litter, live pups per litter and live pup weight. No such effects were seen at 1.75% (approximately 3.05 g/kg/day). The relevance of these very high dosages to human health is uncertain. Pregnant rats receiving undiluted diethylene glycol by gavage over the period of organogenesis had toxic effects at 4.0 and 8.0 ml/kg/day as mortality, decreased body weight, decreased food consumption increased water consumption and increased liver and kidney weights. Fetotoxicity was seen only at these maternally toxic dosages. Decreased fetal body weight occurred at 8.0 ml/kg/day, and increased skeletal variants at 4.0 and 8.0 ml/kg/day. No embryotixic or teratogenic effects were seen. Neither maternal toxicity nor fetotoxicity occurred at 1.0 ml/kg/day. In a study with mice also receiving undiluted diethylene glycol over the period of organogenesis, maternal toxicity occurred at 2.5 and 10.0 ml/kg/day, but not at 0.5 ml/kg/day. Definitive developmental toxicity was not seen in this species. ACUTE TOXICITY Peroral: The lethal dose in humans is estimated to be 3 oz. or 100 ml. Rat: LD50 (6000 – 13000) mg/kg Percutaneous: Rabbit: LD50 = >22270 mg/kg; 24 h occluded Inhalation: Rat: 8-hour exposure, substantially saturated vapor studies, dynamic generation method Mortality: 0/6 Inhalation: Mist/vapor study, rat, at 170C, 8-hour exposure = 2.2 mg/l Mortality: 0/6 Inhalation: Rat: 8-hour exposure, fog = 10000 ppm; 65 - 70C Mortality: 0/6 IRRITATION Skin: Rabbit: 24-hour occluded contact, 0.5 ml Results: Minor erythema and edema Skin: Human: Primary irritation patch test, 48-hour occluded, 0.2 ml Results: Evidence of irritation Eye: Rabbit: 0.1 ml Results: Minor transient iritis, conjunctival irritation with discharge REPEATED EXPOSURE In a 7-day dietary study with rats, a significant increase in kidney weights in females was observed at 5.0 gm/kg. The NOEL was 2.5 gm/kg. In a 24-month dietary study with rats, increased mortality in males was observed at the highest dose, 1.0 gm/kg/day. There were multiple signs: mineralization of several organs, including the cardiac vessels, cardiac muscle, vas deferens, stomach and pulmonary vessels; cellular hyperplasia of the parathyroids, hemosiderosis of the spleen, myocardial fibrosis, portal fibrosis of the liver, bile duct hyperplasia and hydronephrosis and oxylate nephrosis of the kidneys. Ethylene glycol was not oncogenic. Page 840 of 1235 Page 840 of 1235 Page 840 of 1235 Page 840 of 1235 ---PAGE BREAK--- Peak Long Life 50/50 Antifreeze/Coolant 8 In a 90-day dietary study with dogs, repeated exposures to 2.5 gm/kg resulted in acute renal failure and deaths. The NOAEL was 1.0 gm/kg. SENSITIZATION (ANIMAL AND HUMAN STUDIES) Repeated skin contact with ethylene glycol may, in a very small proportion of cases, cause sensitization with the development of allergic contact dermatitis. The incidence is significantly less than 1% with the undiluted material. REPRODUCTIVE TOXICITY A three-generation study indicated that ethylene glycol did not affect reproductive parameters at dietary concentrations up to 1.0 gm/kg/day in any generation. CHRONIC TOXICITY AND CARCINOGENICITY Two chronic feeding studies, using rats and mice, have not produced any evidence that ethylene glycol causes dose- related increases in tumor incidence or a different pattern of tumors compared with untreated controls. The absence of a carcinogenic potential for ethylene glycol has been supported by numerous in vitro genotoxicity studies showing that it does not produce mutagenic or clastogenic effects. GENETIC TOXICOLOGY In Vitro: Ethylene glycol was devoid of genotoxic activity in an Ames test, forward gene mutation and sister chromatid exchange (SCE) studies in Chinese Hamster Ovary (CHO) cells and an in vitro cytogenetics study. In Vivo: Ethylene glycol by three different routes (intravenous, peroral and percutaneous) demonstrates apparent first-order pharmacokinetic behavior for the disposition in and the elimination from the plasma. Dose-dependent changes occur for the elimination of metabolites in the urine and as 14CO2 after single doses for the intravenous and peroral, but not the percutaneous route. The hypothesis from literature sources exists that developmental toxicity is caused by a metabolite of ethylene glycol, called glycolic acid, and not parent ethylene glycol. Under most conditions of ethylene glycol exposure, the glycolic acid metabolite is present in the blood in very low levels. However, it can become the major metabolite following large doses of ethylene glycol due to saturation of glycolic acid oxidation and/or elimination. When levels of this acidic metabolite exceed the capacity of maternal blood buffers to neutralize it, a maternal metabolic acidosis ensues, which has been hypothesized to be the true agent responsible for ethylene glycol induced developmental toxicity. Research suggests that ethylene glycol developmental toxicity is due to a dose-rate dependent toxicokinetic shift leading to glycolate accumulation and metabolic acidosis. ADDITIONAL STUDIES Ethylene glycol has been shown to produce dose-related teratogenic effects in rats and mice when given by gavage or in drinking water at high concentrations or doses. The no-effect doses for developmental toxicity for ethylene glycol given by gavage over the period of organogenesis has been shown to be 150 mg/kg/day for the mouse and 500 mg/kg/day for the rat. Also, in a preliminary study to assess the effects of exposure of pregnant rats and mice to aerosols at concentrations of 150, 1000 and 2500 mg/m3 for 6 hours a day throughout the period of organogenesis, teratogenic effects were produced at the highest concentration, but only in mice. The conditions of these latter experiments did not allow a conclusion as to whether the developmental toxicity was mediated by inhalation of aerosol, percutaneous absorption of ethylene glycol from contaminated skin, or swallowing of ethylene glycol as a result of grooming the wetted coat. In a further study, comparing effects from high aerosol concentration by whole- body or nose-only exposure, it was shown that nose-only exposure resulted in maternal toxicity (1000 and 2500 mg/m3) and developmental toxicity with minimal evidence of teratogenicity (2500 mg/m3). The no-effects concentration (based on maternal toxicity) was 500 mg/m3. In a further study in mice, no teratogenic effects could be produced when ethylene glycol was applied to the skin of pregnant mice over the period of organogenesis. The Page 841 of 1235 Page 841 of 1235 Page 841 of 1235 Page 841 of 1235 ---PAGE BREAK--- Peak Long Life 50/50 Antifreeze/Coolant 9 above observations suggest that ethylene glycol is to be regarded as an animal teratogen. There is currently no available information to suggest that ethylene glycol has caused birth defects in humans. Cutaneous application of ethylene glycol is ineffective in producing developmental toxicity. Exposure to high aerosol concentrations is only minimally effective in producing developmental toxicity. 12. ECOLOGICAL INFORMATION (Concentrated Ethylene Glycol) ENVIRONMENTAL FATE Movement & Partitioning: Bioconcentration potential is low (BCF less than 100 or Log Kow less than Log octanol/water partition coefficient (log Kow) is -1.36. Henry's Law Constant is 6.0E-08 atm-m3/mol. Bioconcentration factor (BCF) is 10 in golden orfe. Degradation & Transformation: Biodegradation under aerobic static laboratory conditions is high (BOD20 or BOD28/ThOD greater than 40%). 5-Day biochemical oxygen demand (BOD5) is 0.78 p/p. 10-Day biochemical oxygen demand (BOD10) is 1.06 p/p. 20-Day biochemical oxygen demand (BOD20) is 1.15 p/p. Theoretical oxygen demand (THOD) is calculated to be 1.29 p/p. Biodegradation may occur under both aerobic and anaerobic conditions (in either the presence or absence of oxygen). Inhibitory concentration (IC50) in OECD "Activated Sludge, Respiration Inhibition Test" (Guideline # 209) is < 1000 mg/L. Degradation is expected in the atmospheric environment within days to weeks. Ecotoxicology: Material is practically non-toxic to aquatic organisms on an acute basis (LC50 greater than 100 mg/L in most sensitive species). Acute LC50 for fathead minnow (Pimephales promelas) is 51000 mg/L. Acute LC50 for bluegill (Lepomis macrochirus) is 27549 mg/L. Acute LC50 for rainbow trout mykiss) is about 18000-46000 mg/L. Acute LC50 for guppy (Poecilia reticulata) is 49300 mg/L. Acute LC50 for water flea (Daphnia magna) is 46300-51100 mg/L. Acute LC50 for the cladoceran Ceriodaphnia dubia is 10000-25800 mg/L. Acute LC50 for crayfish is 91430 mg/L. Acute LC50 for brine shrimp (Artemia salina) is 20000 mg/L. Acute LC50 for golden orfe (Leuciscus idus) is greater than 10000 mg/L. Acute LC50 for goldfish (Carassius auratus) is greater than 5000 mg/L. Growth inhibition EC50 for green alga Selenastrum capricornutum is 9500-13000 mg/L. BOD Oxygen Consumption): Day 5 Day 10 Day 15 Day 20 Day 30 51% 80% 97% ECOTOXICITY Toxicity to Micro-organisms: Bacterial / NA: 16 h; IC50 Result Value: >10000 mg/l Toxicity to Aquatic Invertebrates: Daphnia: 48 h; LC50 Result Value: >100000 mg/l Toxicity to Fish Fathead Minnow: 94 h; LC50 Result Value: 70000 mg/l Page 842 of 1235 Page 842 of 1235 Page 842 of 1235 Page 842 of 1235 ---PAGE BREAK--- Peak Long Life 50/50 Antifreeze/Coolant 10 FURTHER INFORMATION Chemical Oxygen Demand (COD) – Measured: 1.29 mg/mg Theoretical Oxygen Demand (THOD) – Calculated: 1.30 mg/mg Octanol/Water Partition Coefficient – Measured: -1.36 13. DISPOSAL CONSIDERATIONS DO NOT discharge to sewer. Wear appropriate personal protection. Take up with sand, vermiculite, or similar inert material. Dispose in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION Non-Bulk: Not regulated by the US D.O.T. (in quantities under 5,000 lbs in any one inner package) Bulk: Proper Shipping Name: Environmentally Hazardous Substance, LIQUID N.O.S. (ETHYLENE GLYCOL) Technical Name: ETHYLENE GLYCOL ID Number: UN 3082 Hazard Class: 9 Packing Group: PG III Reportable Quantity: 5,000 lb. IATA Non-Bulk: Not Regulated by IATA IMDG Non-Bulk: Not regulated by IMDG (in quantities under 5,000 lbs in any one inner package) 15. REGULATORY INFORMATION THIS PRODUCT CONTAINS COMPONENT(S) CITED ON THE FOLLOWING REGULATIONS. Chemical Name Cas Number Ethylene Glycol 107-21-1 United States - TSCA Inventory: Listed Water Standards: No data available Atmospheric Standards: Clean Air Act (1990) - List of Hazardous Air Contaminants: listed CERCLA: Reportable Quantity (RQ): 5,000 pounds (532 gallons) Page 843 of 1235 Page 843 of 1235 Page 843 of 1235 Page 843 of 1235 ---PAGE BREAK--- Peak Long Life 50/50 Antifreeze/Coolant 11 OSHA Hazard Communication Standard: This product is a “hazardous chemical” as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. SARA Title III: Section 311/312 - Categories: Acute hazard; chronic hazard Section 312 - Inventory Reporting: Ethylene glycol is subject to Tier I and/or Tier II annual inventory reporting. Section 313 - Emission Reporting: Ethylene glycol is subject to Form R reporting requirements. Section 302 - Extremely Hazardous Substances: Ethylene glycol is not listed. State Right-To-Know: California - Exposure Limits - Ceilings: vapor-50 ppm ceiling; 125 mg/m3 ceiling Director's List of Hazardous Substances: listed Florida - Hazardous Substances List: listed Massachusetts - Right-to-Know List: listed Minnesota - Haz. Subs. List: listed (particulate and vapor) New Jersey - Right-to-Know List (Total): Present greater than 1.0% Right-to-Know List: environmental hazard Canadian Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required. WHMIS Information: D2A - material has potential toxic effects. Refer elsewhere in the MSDS for specific warnings and safe handling information. Refer to the employer's workplace education program. California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986): The normal consumer use of this product does not result in exposure to chemicals known to the state of California to cause Cancer and/or reproductive harm above the significant risk level for carcinogens or the maximum allowable dose levels for reproductive toxins. Warnings are not required for consumer packaging. However, industrial or other occupational use of this product at higher frequency and using larger quantities of this product may result in exposures exceeding these levels and are labeled accordingly. California SCAQMD Rule 443.1 (South Coast Air Quality Management District Rule 443.1, Labeling of Materials Containing Organic Solvents): VOC: Vapor pressure 0.06 mmHg at 20C, 1113.38 g/l 16. OTHER INFORMATION Contact: Thomas Cholke Phone: (847) 559-2225 Old World Industries, LLC makes no warranty, representation or guarantee as to the accuracy, sufficiency or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity and suitability of his own use, handling and disposal of this product. Since actual use by others is beyond our control, no warranty, expressed or implied, is made by Old World Industries, LLC as to the effects of such use, the results to be obtained or the safety and toxicity of this product, nor does Old World Industries, LLC assume liability arising out of the use by others of this product referred to herein. The data in this MSDS relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Page 844 of 1235 Page 844 of 1235 Page 844 of 1235 Page 844 of 1235 ---PAGE BREAK--- Page 845 of 1235 Page 845 of 1235 Page 845 of 1235 Page 845 of 1235 ---PAGE BREAK--- Page 846 of 1235 Page 846 of 1235 Page 846 of 1235 Page 846 of 1235 ---PAGE BREAK--- 1 Printed in the U.S.A. SS94-63 MATERIAL SAFETY DATA SHEET IDENTITY (As used on label and list): POLAR ISOPROPYL GASLINE ANTIFREEZE & WATER REMOVER PRODUCT CODE: PO010032, POGLAI12, POGLAI10 NFPA Hazard Identification 0 – Least 1 – Slight 2– Moderate 3 – High 4 - Extreme Health: 1 Fire: 3 Reactivity: 0 Section I - General Information Warren Distribution, Inc. 2849 River Road Council Bluffs, IA 51501 Information (402) 341-9397 Emergency (402) 677-1331 Chemtrec (800) 424-9300 Reviewed: 12/31/02 Section II - Composition/Information on Ingredients COMPONENT NAME % CAS OSHA PEL ACGIH TLV Isopropyl alcohol 100 67-63-0 400ppm 400ppm Section 313 Supplier Information This product contains a toxic chemical subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-know Act of 1986 (40 CFR 372): NON-HAZARDOUS INGREDIENTS No IARC, NTP, OSHA and ACGIH listed carcinogens. Section III - Hazards Identification EYE CONTACT: May cause moderate irritation; Liquid may damage eye tissue if not removed properly. SKIN CONTACT: Prolonged or repeated contact may cause dryness, irritation, and/or dermatitis. INHALATION: Prolonged exposure may cause coughing, shortness of breath, headache, nausea, dizziness, and/or intoxication. INGESTION: May cause nausea, vomiting, abdominal pain; Aspiration of vomitus may cause chemical pneumonia or pulmonary edema. CARCINOGENICITY: n/a Page 847 of 1235 Page 847 of 1235 Page 847 of 1235 Page 847 of 1235 ---PAGE BREAK--- 2 MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Repeated inhalation or liquid contact may aggravate preexisting skin, eye, or respiratory conditions such as or bronchitis. OTHER HEALTH INFORMATION: n/a Section IV - First Aid Procedures EYE CONTACT: Flush with water for fifteen minutes; seek medical attention if irritation persists SKIN CONTACT: Thoroughly wash exposed area with copious amounts of soap and water. Seek medical attention if irritation develops. INHALATION: Remove victim to fresh air, restore or assist breathing and/or obtain medical assistance if necessary. INGESTION: Induce Vomiting using syrup of ipecac or the back of a spoon. Call physician, hospital emergency room, or poison control for instructions. Section V - Fire and Explosion Hazard Data Flash Point (deg 55 Method Used: TCC Flammable or Explosive Limits (approximate % by volume in air) LEL: 2.5 UEL: 12.1 EXTINGUISHING MEDIA: Dry chemical, carbon dioxide, foam SPECIAL FIRE FIGHTING PROCEDURES: Full face, positive pressure, self contained breathing apparatus must be worn. Use water spray to cool exposed containers. UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapors are flammable at less than ambient temperatures, and are heavier than air, and thus may travel along ground to distant ignition source and flash back. Also, containers may rupture in intense heat. Section VI - Accidental Release Measures STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Eliminate all ignition sources. Ventilate area. Stop leak at source. Dam spill and collect liquid into recovery vessel. Remaining liquid should be picked up on non-flammable absorbent. If ventilation is not adequate wear full-face positive pressure S.C.B.A. and protective clothing. Advise authorities if product enters sewers or waterways. Section VII - Handling and Storage PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in cool, dry environment. Keep away from ignition sources. OTHER PRECAUTIONS: Keep out of reach of children. Section VIII - Exposure Controls/Personal Protection RESPIRATORY PROTECTION: Use an air supplied mask in confined, non-ventilated areas. VENTILATION: Face velocity >60 lfpm in confined space. Use explosion proof equipment sufficient to prevent exceeding exposure limits. PROTECTIVE GLOVES: Use chemical resistant gloves if possibility of skin contact exists. Page 848 of 1235 Page 848 of 1235 Page 848 of 1235 Page 848 of 1235 ---PAGE BREAK--- 3 EYE PROTECTION: Wear chemical splash goggles. OTHER PROTECTIVE EQUIPMENT: Remove contaminated clothing WORK PRACTICES/ENGINEERING CONTROLS: Keep containers closed when not in use. PERSONAL HYGIENE: Wash after any and all contact with product. Section IX- Physical/Chemical Characteristics Boiling Point (deg 180 Specific Gravity (H2O=1): .789 Vapor Pressure (mm Hg): 33 Melting Point (deg -127 Vapor Density (Air=1): 2.1 Solubility in water: Complete Evaporation Rate (n-butyl Acetate=1): 2.4 APPEARANCE AND ODOR: Clear liquid, slight alcohol odor. Section X - Reactivity Data STABILITY: Stable INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizing agents, strong acids, strong bases. HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Incomplete combustion may yield carbon monoxide and other toxic fumes. HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: High temperatures, sparks & open flames. Section XI - Toxicological Information See Section IV Section XII - Ecological Information Section XIII - Disposal Considerations WASTE DISPOSAL METHOD: Liquid can be incinerated in accordance with all applicable regulations. Contaminated absorbent must be disposed of in accordance with local, state, and/or federal regulations. Product is considered to be a hazardous waste as defined by RCRA. Section XIV - Transport Information CONSUMER COMMODITY, ORM-D Section XV-Regulatory Information SARA SECTION 313: This product does not contain greater than 1.0% (greater than 0.1% for carcinogenic substances) of any chemical substance listed under SARA Section 313. WHMIS classification for product: This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. Page 849 of 1235 Page 849 of 1235 Page 849 of 1235 Page 849 of 1235 ---PAGE BREAK--- 4 This material safety data sheet and the information it contains is offered to you in good faith as accurate. We have reviewed any information contained in the data sheet which we received from sources outside our company and we believe that information to be correct, but cannot guarantee its accuracy or completeness. Health and safety precautions in this data sheet may not be adequate for all individuals and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. No statement made in this data sheet shall be construed as permission or recommendation for the use of any product in a manner that might infringe existing patents. No warranty is made, either expressed or implied. Page 850 of 1235 Page 850 of 1235 Page 850 of 1235 Page 850 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Quick Identifier (In Plant Common Name): Polar Starting Fluid MANUFACTURER INFORMATION MANUFACTURER'S NAME: SPRAY PRODUCTS CORPORATION ADDRESS: P.O. Box 737, Norristown, PA 19404 EMERGENCY TELEPHONE NUMBER: Chemtrec 1-800- 424-9300 GENERAL INFORMATION TELEPHONE NUMBER: 1-[PHONE REDACTED] DATE PREPARED: April 19th, 2011 SECTION 1 - IDENTITY COMMON NAME (used on label)(Trade Name & Synonyms): POLAR STARTING FLUID CAS. NUMBER: See Section 2 CHEMICAL NAME: Aerosol Starting Fluid CHEMICAL FAMILY: Ether & Heptane FORMULA: N/A SECTION 2 - HAZARDOUS INGREDIENTS Principal Hazardous Component(s) CHEMICAL AND OSHA ACGIH VAPOR FLASH COMMON NAME(S) CAS # PEL TLV PRESS @ 25 DEG. C LEL UEL POINT DEG. F Wt % Diethyl Ether 60-29-7 400ppm 400ppm 1.85 48.0 -49(TCC) 25 - 30 Heptane 142-82-5 400ppm 400ppm 45 mmHg 1.2 6.7 <20(TCC) 70 - 75 Carbon Dioxide 124-38-9 5000ppm N/A 1 atm. None None <10 Upper Cylinder Lubricant 64741-89-5 NE NE N/A N/A N/A N/A N/A is not available or not applicable NE is not established Page 851 of 1235 Page 851 of 1235 Page 851 of 1235 Page 851 of 1235 ---PAGE BREAK--- SECTION 3 - PHYSICAL & CHEMICAL CHARACTERISTICS (Fire & Explosion Data) BOILING POINT (Deg. Concentrate Range: 95 - 200 SPECIFIC GRAVITY (Water = Concentrate: 0.7 VAPOR PRESSURE (mmHg): See Section 2 PERCENT VOLATILE BY WEIGHT 100% VAPOR DENSITY (Air = >1 EVAPORATION RATE (BA = >1 SOLUBILITY IN WATER: Slight REACTIVITY IN WATER: None APPEARANCE AND ODOR: CONCENTRATE: Clear liquid with ether odor; PROPELLANT: Colorless, odorless gas; FINISHED PACKAGE: Pressurized containers. FLASH POINT: See Section 2 FLAMMABLE LIMITS IN AIR - % BY VOLUME: See Section 2 EXTINGUISHER MEDIA: Carbon dioxide, foam, dry chemical AUTO-IGNITION TEMPERATURE: Unknown SPECIAL FIRE FIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure build-up and possible bursting when exposed to high temperatures. Firemen should wear self-contained respiratory equipment. UNUSUAL FIRE AND EXPLOSION HAZARDS: Extremely flammable. Contents under pressure. Do not use or store near heat or ignition sources. Containers may burst at temperatures above 130 deg. F. SECTION 4 - PHYSICAL HAZARDS STABILITY: Stable CONDITIONS TO AVOID: Avoid any ignition sources. Avoid excessive heat. INCOMPATIBILITY (Materials to Avoid): Nitric plus Acetic Acids, Nitric plus Sulfuric Acid, Amines, Strong Oxidizing Agents. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: Not Applicable. Page 852 of 1235 Page 852 of 1235 Page 852 of 1235 Page 852 of 1235 ---PAGE BREAK--- SECTION 5 - HEALTH HAZARDS THRESHOLD LIMIT VALUE: See Section 2 SIGNS AND OF EXPOSURE: EYE CONTACT: May cause moderate eye irritation and moderate corneal injury. Vapors may irritate eyes; SKIN CONTACT: Prolonged contact may cause irritation, defatting of skin; INHALATION: May cause nose and throat irritation. May cause nervous system depression characterized by the following progressive steps: Headache, dizziness, nausea, staggering gait, confusion, unconsciousness. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage; INGESTION: If aspirated (liquid enters the lungs), it may be rapidly absorbed through the lungs and result in injury to other body systems. Gastro-intestinal distress. IMPORTANT NOTE: REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS MAY LEAD TO PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. EYE WATERING, HEADACHES, NAUSEA, DIZZINESS AND LOSS OF COORDINATION ARE SIGNS THAT SOLVENT LEVELS ARE TOO HIGH. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL. CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN: NATIONAL TOXICOLOGY PROGRAM: No I.A.R.C. MONOGRAPHS: No OSHA: No OSHA PERMISSIBLE EXPOSURE LIMIT: See Section 2 ACGIH THRESHOLD LIMIT VALUE: See Section 2 OTHER EXPOSURE LIMIT USED: None EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove to fresh air. If not breathing, give mouth-to-mouth. If breathing is difficult, give oxygen. Call a physician. EYES: Flush with flowing water immediately and continuously for 15 minutes. Consult medical personnel. SKIN: Wash off in flowing water or shower. Remove contaminated clothing and wash before reuse. If irritation persists, call a physician. INGESTION: Do not induce vomiting. Call a physician immediately. Page 853 of 1235 Page 853 of 1235 Page 853 of 1235 Page 853 of 1235 ---PAGE BREAK--- SECTION 6 - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: NIOSH or Bureau of Mines approved organic vapor-type respirator is required in absence of proper environmental control. VENTILATION: LOCAL EXHAUST: To keep below TLV MECHANICAL (General): To keep below TLV SPECIAL: None OTHER: None PROTECTIVE GLOVES: Solvent resistant gloves - impervious gloves EYE PROTECTION: Safety glasses or goggles OTHER PROTECTIVE CLOTHING OR EQUIPMENT: None reasonably foreseeable. SECTION 7 - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Do not store above 120 deg. F. Avoid breathing vapors. Avoid prolonged or repeated contact with skin. OTHER PRECAUTIONS: Extremely flammable. Do not use or store near open flames, heat, or any sources of ignition. Contents under pressure. Do not puncture or incinerate. Vapors are heavier than air and will collect in low areas. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SMALL SPILLS: Remove ignition sources. Mop up, wipe up, or soak up immediately. Use proper protective equipment. LARGE SPILLS: Evacuate area. Remove ignition sources. Contain liquid; transfer to closed containers; keep out of water supplies. WASTE DISPOSAL METHODS: Dispose in accordance with Federal, State, and Local regulations. Do not incinerate closed or empty containers. SECTION 8 – NFPA HAZARD RATINGS Health = 2 Flammability = 4 Reactivity = 0 Section 9 - Other Information TRANSPORTATION INFORMATION – DOMESTIC GROUND Shipping Name: Consumer Commodity Hazard Class: ORM-D UN Number: N/A Packing Group: N/A Hazard Label: None Carton Marking: Consumer Commodity, ORM-D Page 854 of 1235 Page 854 of 1235 Page 854 of 1235 Page 854 of 1235 ---PAGE BREAK--- Disclaimer SPRAY PRODUCTS CORPORATION believes that the information contained herein is accurate and reliable as of the date of this material safety data sheet, but no representation guarantee or warranty, express or implied, is made as to the accuracy, reliability, or completeness of the information. Persons receiving this information are encouraged to make their own determination as to the information’s suitability and completeness for their particular application. NO INFORMATION CONTAINED HEREIN CONSTITUTES A PRODUCT WARRANTY OF ANY KIND, WHETHER EXPRESS OR IMPLIED; AND ALL IMPLIED WARRANTIES OF MERCHANT ABILITY AND OF FITNESS FOR A PARTICULAR PURPOSE ARE HEREBY DISCLAIMED BY SPRAY PRODUCTS CORPORATION. Page 855 of 1235 Page 855 of 1235 Page 855 of 1235 Page 855 of 1235 ---PAGE BREAK--- SECTION 8 – NFPA HAZARD RATINGS Health = 2 Flammability = 4 Reactivity = 0 Page 856 of 1235 Page 856 of 1235 Page 856 of 1235 Page 856 of 1235 ---PAGE BREAK--- Page 857 of 1235 Page 857 of 1235 Page 857 of 1235 Page 857 of 1235 ---PAGE BREAK--- Page 858 of 1235 Page 858 of 1235 Page 858 of 1235 Page 858 of 1235 ---PAGE BREAK--- Page 859 of 1235 Page 859 of 1235 Page 859 of 1235 Page 859 of 1235 ---PAGE BREAK--- Page 860 of 1235 Page 860 of 1235 Page 860 of 1235 Page 860 of 1235 ---PAGE BREAK--- Page 861 of 1235 Page 861 of 1235 Page 861 of 1235 Page 861 of 1235 ---PAGE BREAK--- Page 862 of 1235 Page 862 of 1235 Page 862 of 1235 Page 862 of 1235 ---PAGE BREAK--- Page 863 of 1235 Page 863 of 1235 Page 863 of 1235 Page 863 of 1235 ---PAGE BREAK--- MSDS149 1 SECTION 1: IDENTIFICATION MSDS ID: MSDS149 PRODUCT NAME: PRESTONE(R) Antifreeze/Coolant PRODUCT NUMBER: AF777, 71944, 70192 FORMULA NUMBER: YA721, YA718, YA718B MANUFACTURER: Honeywell Consumer Products Group 39 Old Ridgebury Road Danbury, CT 06810-5109 CANADIAN OFFICE: Honeywell Consumer Products Group 3333 Unity Drive Mississauga, Ontario L5L 3S6 INFORMATION PHONE NUMBER: (800)862-7737 (in the US) (800)668-9349 (in Canada) EMERGENCY PHONE NUMBER: CHEMTREC 1-[PHONE REDACTED] (in the US) CANUTEC (613)996-6666 (in Canada) MSDS DATE OF PREPARATION/REVISION: 07/21/05 PRODUCT USE: Automobile antifreeze - consumer product NFPA RATING (NFPA 704) - FIRE: 1 HEALTH: 2 REACTIVITY: 0 SECTION 2: PRODUCT COMPONENTS HAZARDOUS COMPONENTS CAS# PERCENT EXPOSURE LIMITS Ethylene Glycol 107-21-1 80-96 None Established-OSHA PEL (aerosol) 100 mg/m3 Ceiling ACGIH TLV Diethylene Glycol 111-46-6 0-8 None Established OSHA PEL, ACGIH TLV Non-Hazardous Ingredients Water 7732-18-5 SECTION 3: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Eye and upper respiratory irritant. May cause nausea, vomiting, headache, drowsiness, blurred vision, convulsions, coma or death if ingested or inhaled. Prolonged or repeated skin contact may cause dermatitis or skin sensitization. Page 864 of 1235 Page 864 of 1235 Page 864 of 1235 Page 864 of 1235 ---PAGE BREAK--- MSDS149 2 POTENTIAL HEALTH EFFECTS: INHALATION: May cause irritation of the nose and throat with headache, particularly from mists. High vapor concentrations caused, for example, by heating the material in an enclosed and poorly ventilated workplace, may produce nausea, vomiting, headache, dizziness and irregular eye movements. SKIN CONTACT: No evidence of adverse effects from available information. EYE CONTACT: Liquid, vapors or mist may cause discomfort in the eye with persistent conjunctivitis, seen as slight excess redness or conjunctiva. Serious corneal injury is not anticipated. INGESTION: Following ingestion, a bitter taste may be noted. May cause abdominal discomfort or pain, nausea, vomiting, dizziness, drowsiness, malaise, blurring of vision, irritability, back pain, decrease in urine output, kidney failure, and central nervous system effects, including irregular eye movements, convulsions and coma. Cardiac failure and pulmonary edema may develop. Severe kidney damage which may be fatal may follow the swallowing of ethylene glycol. A few reports have been published describing the development of weakness of the facial muscles, diminishing hearing, and difficulty with swallowing, during the late stages of severe poisoning. CHRONIC EFFECTS: Prolonged or repeated inhalation exposure may produce signs of central nervous system involvement, particularly dizziness and jerking eye movements. Prolonged or repeated skin contact may cause skin sensitization and an associated dermatitis in some individuals. Ethylene glycol has been found to cause birth defects in laboratory animals. The significance of this finding to humans has not been determined. See section 11 for additional information. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: The available toxicological information and a knowledge of the physical and chemical properties of the material suggest that overexposure in unlikely to aggravate existing medical conditions. CARCINOGEN: None of the components of these products is listed as a carcinogen or suspected carcinogen by IARC, NTP or OSHA. SECTION 4: FIRST AID MEASURES INHALATION: Remove the victim to fresh air. If breathing has stopped administer artificial respiration. If breathing is difficult, have medical personnel administer oxygen. Get medical attention. SKIN CONTACT: Remove contaminated clothing. Immediately wash contacted area thoroughly with soap and water. If irritation persists, get medical attention. Page 865 of 1235 Page 865 of 1235 Page 865 of 1235 Page 865 of 1235 ---PAGE BREAK--- MSDS149 3 EYE CONTACT: Immediately flush eyes with large amounts of water for 15 minutes. Get medical attention if irritation persists. INGESTION: Seek immediate medical attention. Immediately call local poison control center or go to an emergency department. Never give anything by mouth to or induce vomiting in an unconscious or drowsy person. NOTES TO PHYSICIAN: The principal toxic effects of ethylene glycol, when swallowed, are kidney damage and metabolic acidosis. The combination of metabolic acidosis, an osmol gap and oxalate in the urine is evidence of ethylene glycol poisoning. Pulmonary edema with hypoxemia has been described in a number of patients following poisoning with ethylene glycol. Respiratory support with mechanical ventilation may be required. There may be cranial nerve involvement in the late stages of toxicity from swallowed ethylene glycol. In particular, effects have been reported involving the seventh, eighth, and ninth cranial nerves, presenting with bilateral facial paralysis, diminished hearing and Ethanol is antidotal and its early administration may block the formation of nephrotoxic metabolites of ethylene glycol in the liver. The objective is to rapidly achieve and maintain a blood ethanol level of approximately 100 mg/dl by giving a loading dose of ethanol followed by a maintenance dose. Intravenous administration of ethanol is the preferred route. Ethanol blood levels should be checked frequently. Hemodialysis may be required. 4-Methyl pyrazole (Fomepizole(R)), a potent inhibitor of alcohol dehydrogenase, has been used therapeutically to decrease the metabolic consequences of ethylene glycol poisoning. Fomepizole is easier to use clinically than ethanol, does not cause CNS depression or hypoglycemia and requires less monitoring than ethanol. Additional therapeutic modalities which may decrease the adverse consequences of ethylene glycol metabolism are the administration of both thiamine and pyridoxine. As there are complicated and serious overdoses, we recommend you consult with the toxicologists at your poison control center. SECTION 5: FIRE AND EXPLOSION DATA FLASH POINT: 242 F (117 C) TOC 220 F (104 C) PMCC AUTOIGNITION TEMPERATURE: Not determined FLAMMABILITY LIMITS: LEL: 3.2% UEL: 15.3% NFPA CLASSIFICATION: IIIB Page 866 of 1235 Page 866 of 1235 Page 866 of 1235 Page 866 of 1235 ---PAGE BREAK--- MSDS149 4 EXTINGUISHING MEDIA: For large fires, use alcohol type or all-purpose foams. For small fires, use water spray, carbon dioxide or dry chemical. SPECIAL FIRE FIGHTING PROCEDURES: Do not spray pool fires directly. Cool fire exposed containers with water. Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing for fires in areas where chemicals are used or stored. UNUSUAL FIRE HAZARDS: A solid stream of water or foam directed into hot, burning liquid can cause frothing. HAZARDOUS COMBUSTION PRODUCTS: Burning may produce carbon monoxide and carbon dioxide. SECTION 6: ACCIDENTAL RELEASE MEASURES Wear appropriate protective clothing and equipment (See Section Collect with absorbent material and place in appropriate, labeled container for disposal or, if permitted flush spill area with water. SECTION 7: HANDLING AND STORAGE DANGER: Harmful or Fatal if Swallowed Do not drink antifreeze or solution. Avoid eye and prolonged or repeated skin contact. Avoid breathing vapors or mists. Wash exposed skin thoroughly with soap and water after use. Do not store in opened or unlabeled containers. Keep container away from open flames and excessive heat. Do not reuse empty containers unless properly cleaned. Empty containers retain product residue and may be dangerous. Do not cut, weld, drill, etc. containers, even empty. Sudden release of hot organic chemical vapors or mists from process equipment operating at elevated temperature and pressure, or sudden ingress of air into vacuum equipment, may result in ignitions without any obvious ignition sources. Published "autoignition" or "ignition" temperatures cannot be treated as safe operating temperatures in chemical processes without analysis of the actual process conditions. Use of this product in elevated temperature applications should be thoroughly evaluated to assure safe operating conditions. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION VENTILATION: Use general ventilation or local exhaust as required to maintain exposures below the occupational exposure limits. RESPIRATORY PROTECTION: For operations where the TLV is exceeded a NIOSH approved respirator with organic vapor cartridges and dust/mist Page 867 of 1235 Page 867 of 1235 Page 867 of 1235 Page 867 of 1235 ---PAGE BREAK--- MSDS149 5 prefilters or supplied air respirator is recommended. Equipment selection depends on contaminant type and concentration. Select and use in accordance with 29 CFR 1910.134 and good industrial hygiene practice. For firefighting, use self-contained breathing apparatus. GLOVES: Chemical resistant gloves such as neoprene or PVC where contact is possible EYE PROTECTION: Splash-proof goggles. OTHER PROTECTIVE EQUIPMENT/CLOTHING: Appropriate protective clothing as needed to minimize skin contact. Suitable washing and eye flushing facilities should be available in the work area. Contaminated clothing should be removed and laundered before re-use. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE AND ODOR: Yellow liquid with a mild odor. pH: Not determined SPECIFIC GRAVITY: 1.12 BOILING POINT 334 F VAPOR PRESSURE: Less than 0.1 FREEZING POINT -8 F VAPOR DENSITY: 2.1 SOLUBILITY IN WATER: 100% EVAPORATION RATE: Less than 1 PERCENT VOLATILE: None VISCOSITY: Not determine COEFFICIENT OF WATER/OIL DISTRIBUTION: Not determined SECTION 10: STABILITY AND REACTIVITY STABILITY: Stable CONDITIONS TO AVOID: None known. INCOMPATIBILITY: Normally unreactive, however, avoid strong bases at high temperatures, strong acids, strong oxidizing agents, and materials reactive with hydroxyl compounds. DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: None known. SECTION 11: TOXICOLOGICAL INFORMATION ACUTE TOXICITY VALUES: Ethylene Glycol: LD50 Oral Rat: 4700 mg/kg LD50 Skin Rabbit: 9530 mg/kg Diethylene Glycol: LD50 Oral Rat: 12,565 mg/kg LD50 Skin Rabbit: 11,890 mg/kg SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH: Ethylene glycol has been shown to produce dose-related teratogenic effects in rats and mice when given by gavage or in drinking water at high concentrations or doses. Also, in a preliminary study to assess the effects of exposure of pregnant rats and mice to aerosols at concentrations 150, 1,000 and 2,500 mg/m3 for 6 hours a day throughout Page 868 of 1235 Page 868 of 1235 Page 868 of 1235 Page 868 of 1235 ---PAGE BREAK--- MSDS149 6 the period of organogenesis, teratogenic effects were produced at the highest concentrations, but only in mice. The conditions of these latter experiments did not allow a conclusion as to whether the developmental toxicity was mediated by inhalation of aerosol, percutaneous absorption of ethylene glycol from contaminated skin, or swallowing of ethylene glycol as a result of grooming the wetted coat. In a further study, comparing effects from high aerosol concentration by whole-body or nose-only exposure, it was shown that nose-only exposure resulted in maternal toxicity (1,000 and 2,500 mg/m3) and developmental toxicity in with minimal evidence of teratogenicity (2,500 mg/m3). The no-effects concentration (based on maternal toxicity) was 500 mg/m3. In a further study in mice, no teratogenic effects could be produced when ethylene glycol was applied to the skin of pregnant mice over the period of organogenesis. The above observations suggest that ethylene glycol is to be regarded as an animal teratogen; there is currently no available information to suggest that ethylene glycol caused birth defects in humans. Cutaneous application of ethylene glycol is ineffective in producing developmental toxicity; exposure to high aerosol concentration is only minimally effective in producing developmental toxicity; the major route for producing developmental toxicity is perorally. Two chronic feeding studies, using rats and mice, have not produced any evidence that ethylene glycol causes dose-related increases in tumor incidence or a different pattern of tumors compared with untreated controls. The absence of carcinogenic potential for ethylene glycol has been supported by numerous invitro genotoxicity studies showing that it does not produce mutagenic or clastogenic effects. This products contains less than 0.5% tolytriazole which has demonstrates mutagenic activity in a bacterial test system. A correlation has been established between mutagenic activity and carcinogenic activity for many chemicals. Tolytriazole has not been identified as a carcinogen or probable carcinogen by NTP, IARC or OSHA. SECTION 12: ECOLOGICAL INFORMATION Ethylene Glycol: LC50 Goldfish: 5,000 mg/L/24 hr. at 20 C static conditions. Toxicity threshold (cell multiplication inhibition test): Bacterial (Pseudomonas putida): 10,000 mg/l Protozoa (Entosiphon sulcatum and Uronema parduczi Chatton-Lwoff): >10,000 mg/l Algae (Microcystis aeruginosa): 2,000 mg/l Green algae (Scenedesmus quandricauda): >10,000 mg/l SECTION 13: DISPOSAL INFORMATION Dispose of product in accordance with all local, state/provincial and federal regulations. Page 869 of 1235 Page 869 of 1235 Page 869 of 1235 Page 869 of 1235 ---PAGE BREAK--- MSDS149 7 SECTION 14: TRANSPORT INFORMATION U.S. DOT HAZARD CLASSIFICATION: Not Regulated (unless package contains a reportable quantity) Note: IF A SHIPMENT OF A REPORTABLE QUANTITY (5,208 LBS/557 GAL.) IN A SINGLE PACKAGE IS INVOLVED, THE FOLLOWING INFORMATION APPLIES: PROPER SHIPPING NAME: RQ, Environmentally hazardous substance, liquid, n.o.s. (Ethylene glycol) UN NUMBER: UN3082 PACKING GROUP: III LABELS REQUIRED: Class 9 DOT MARINE POLLUTANTS: This product does not contain Marine Pollutants as defined in 49 CFR 171.8. IMDG CODE SHIPPING CLASSIFICATION: Not Regulated CANADIAN TDG CLASSIFICATION: Not Regulated SECTION 15: REGULATORY INFORMATION EPA SARA 311/312 HAZARD CLASSIFICATION: Acute health, chronic health EPA SARA 313: This Product Contains the Following Chemicals Subject to Annual Release Reporting Requirements Under SARA Title III, Section 313 (40 CFR 372): Ethylene Glycol 107-21-1 80-96% PROTECTION OF STRATOSPHERIC OZONE: This product is not known to contain or to have been manufactured with ozone depleting substances as defined in 40 CFR Part 82, Appendix A to Subpart A. CERCLA SECTION 103: Spills of this product over the RQ (reportable quantity) must be reported to the National Response Center. The RQ for this product, based on the RQ for Ethylene Glycol (96% maximum) of 5,000 lbs, is 5,208 lbs. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. CALIFORNIA PROPOSITION 65: The normal consumer use of this product does not result in exposures to chemicals known to the State of California to cause Cancer and/or Reproductive Harm above the significant risk level for carcinogens or the maximum allowable dose levels for reproductive toxins. Therefore, no warnings are required for consumer packages. Industrial or other occupational use of this product at higher frequency and using larger quantities of this product may result in exposures exceeding these levels and are labeled accordingly. Page 870 of 1235 Page 870 of 1235 Page 870 of 1235 Page 870 of 1235 ---PAGE BREAK--- MSDS149 8 EPA TSCA INVENTORY: All of the components of this material are listed on the Toxic Substances Control Act (TSCA) Chemical Substances Inventory. CANADIAN ENVIRONMENTAL PROTECTION ACT: All of the ingredients are listed on the Canadian Domestic Substances List. CANADIAN WHMIS CLASSIFICATION: Class D - Division 2 - Subdivision A - (A very toxic material causing other toxic effects) CANADIAN WHIMIS HAZARD SYMBOLS: Toxic - Division 2 This MSDS has been prepared according to the criteria of the Controlled Products Regulation (CPR) and the MSDS contains all of the information required by the CPR. EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES (EINECS): All of the ingredients are listed on the EINECS inventory. SECTION 16: OTHER INFORMATION REVISION SUMMARY: Section 15: Canadian WHMIS Classification This MSDS is directed to professional users and bulk handlers of the product. Consumer products are labeled in accordance with Federal Hazardous Substances Act regulations. While Prestone Products Corporation believes that the data contained herein are factual and the opinions expressed are those of qualified experts regarding the results of tests conducted, the data are not to be taken as a warranty or representation for which Prestone Products Corporation assumes legal responsibility. They are offered for your consideration, investigation and verification. Any use of these data and information must be determined by the user to be in accordance with applicable federal, state and local laws and regulations. If more information is needed, please contact: Technical Services Prestone Products Corporation 55 Federal Road Danbury, CT 06810 (800) 862-7737 Page 871 of 1235 Page 871 of 1235 Page 871 of 1235 Page 871 of 1235 ---PAGE BREAK--- Page 872 of 1235 Page 872 of 1235 Page 872 of 1235 Page 872 of 1235 ---PAGE BREAK--- Page 873 of 1235 Page 873 of 1235 Page 873 of 1235 Page 873 of 1235 ---PAGE BREAK--- Page 874 of 1235 Page 874 of 1235 Page 874 of 1235 Page 874 of 1235 ---PAGE BREAK--- Page 875 of 1235 Page 875 of 1235 Page 875 of 1235 Page 875 of 1235 ---PAGE BREAK--- Page 876 of 1235 Page 876 of 1235 Page 876 of 1235 Page 876 of 1235 ---PAGE BREAK--- Page 877 of 1235 Page 877 of 1235 Page 877 of 1235 Page 877 of 1235 ---PAGE BREAK--- Page 878 of 1235 Page 878 of 1235 Page 878 of 1235 Page 878 of 1235 ---PAGE BREAK--- SpecAir Specialty Gases Revision Date: 11/28/06 Propane Page 2 of 4 Suitable extinguishing media : Carbon dioxide, water spray, or dry chemical. Specific hazards : Severe when exposed to heat or flame. Vapors may travel a considerable distance to the source of ignition and flash back. May form explosive mixture in air. Cylinder rupture may occur under fire conditions. Special protective equipment for fire- fighters : Wear self contained breathing apparatus and full protective clothing. Keep fire exposed cylinders cool with water spray. If possible, stop the product flow. 6. Accidental Release Measures Personal precautions : None. Environmental precautions : None. Methods for cleaning up : Evacuate and ventilate area. Remove leaking cylinder to exhaust hood or safe outdoor area. Shut off source if possible and remove source of heat. Additional advice : None. 7. Handling and Storage Handling Secure cylinder when using to protect from falling. Use suitable hand truck to move cylinders. Storage Store in well ventilated areas. Keep valve protection cap on cylinders when not in use. 8. Exposure Controls / Personal Protection Engineering measures Provide adequate general and local exhaust ventilation to maintain concentration below exposure limits and to avoid Personal protective equipment Respiratory protection : Use a self-contained breathing apparatus in case of leakage. Hand protection : Protective gloves to prevent contact with cold equipment. Eye protection : Safety glasses. Skin and body protection : Safety shoes when handling cylinders. 9. Physical and Chemical Properties Form : Liquefied gas. Color : Colorless. Odor : Sweet odor. Vapor pressure : @ 21.1 C: 158.42 atm Vapor density : 1.55 (Air = 1) Boiling point : -42.1 Water solubility : @ 18 C v/v: 0.065 Specific gravity : @ 20 C: 0.501 (water = 1) Evaporation rate : Gas. 10. Stability and Reactivity Page 879 of 1235 Page 879 of 1235 Page 879 of 1235 Page 879 of 1235 ---PAGE BREAK--- SpecAir Specialty Gases Revision Date: 11/28/06 Propane Page 3 of 4 Stability : Stable under normal conditions. Conditions to avoid : Storage in poorly ventilated areas. Storage near a heat source. Materials to avoid : Oxidizing agents. Hazardous decomposition products : Carbon oxides form when burned. 11. Toxicological Information Acute Health Hazard Ingestion : Not available. Inhalation : Not available. Skin : Not available. 12. Ecological Information No adverse ecological effects are expected. 13. Disposal Considerations Waste from residues / unused products : Dispose of non-refillable cylinders in accordance with federal, state and local regulations. Allow gas to vent slowly to atmosphere in an unconfined area or exhaust hood. If the cylinders are refillable type, return cylinders to supplier with any valve outlet plugs or caps secured and valve protection caps in place. Contaminated packaging : Return cylinder to supplier. 14. Transport Information DOT (US only) Proper shipping name : Propane Class : 2.1 UN/ID No. : UN1978 Labeling : Flammable Gas Further information Cylinders should be transported in a secure upright position in a well ventilated truck. 15. Regulatory Information OSHA Hazard Communication Standard (29 CFR 1910.1200) Hazard Class(es) Material is not listed in appendix A of 29 CFR 1910.119 as highly hazardous chemical. TCSA Material is listed in TSCA inventory. SARA The threshold planning quantity for material is 10,000 lbs. Number in Annex 1 of DIR 67/548 Not listed in annex 1. Page 880 of 1235 Page 880 of 1235 Page 880 of 1235 Page 880 of 1235 ---PAGE BREAK--- Material Safety Data Sheet Omni Specialty Packaging For Compliance with OSHA 29 CFR 1910.1200 and ANSI Z400.1-1998 1. Product and Company Identification Product Name MSDS Code Number Pure Guard HD,SUPER,SAE 30, 40, 50, 15W-40 DIESEL ENGINE OIL Trade Name & Synonyms Date of Last Revision 01/06/2009 Chemical Name Manufacturer Omni Specialty Packaging C.A.S. Number Address 10399 Hwy. 1 Shreveport, La. 71115 Grades or Minor Variant Identities Information Telephone Number (318) 524-1100 For Chemical Emergency, Spill Leak Fire Exposure or Accident Call CHEMTREC Day or Night DOMESTIC NORTH AMERICA [PHONE REDACTED] INTERNATIONAL, CALL [PHONE REDACTED] (collect calls accepted) Product Use (for Canada) 2. Composition/Information on Ingredients Hazardous Components C.A.S Number Exposure Limits Oil Mist % Base Lubricants Oils Mixture None 5MG/M3 70-95 Detergent/Inhibitor System Mixture None 5 MG/M3 5-20 Viscosity Index Improver Mixture None Not Established 5-15 Pour Point Depressant Mixture None N/A <1 OSHA Regulatory Status 29 CFR 1910.1200. 3. Hazards Identification Emergency Overview This product is considered not hazardous under 29 CFR 1910.1200 (Hazard Communication). Routes of Exposure Signs and Single, Repeated, or Lifetime Exposures Severity (Mild, Moderate, Severe) Acute and Chronic Health Effect(s) Target Organ(s) Eye Practically non- irritating to the eye upon direct contact. Skin Minimally irritating upon direct contact. May cause irritation/dermatitis. Inhalation Low hazard at standard temperatures and pressures. Inhalation of oil mist or fumes can cause irritation of the nose, throat and upper respiratory tract Ingestion Do not ingest. May cause nausea, vomiting/diarrhea. Other On rare occasions, prolonged and repeated exposure to oil mist poses a risk of pulmonary disease such as chronic lung inflammation. This condition is usually as a result of repeated small aspirations. Medical Conditions Aggravated by Exposure Personnel with pre-existing skin disorders should avoid contact with this product. Page 881 of 1235 Page 881 of 1235 Page 881 of 1235 Page 881 of 1235 ---PAGE BREAK--- MSDS – OMNI SPECIALTY PACKAGING Page 2 of 6 4. First Aid Measures Routes of Exposure First Aid Instructions Immediate Medical Attention Delayed Eye Flush with large amount of water for 15 minutes. Get medical attention if eye irritation develops or persists. Skin Wash with soap and water. Remove contaminated clothes and wash before reuse. Get medical attention if skin discolor develops. Inhalation This material is not expected to present an inhalation exposure at ambient conditions Ingestion Do not induce vomiting. Get immediate medical attention or advice. Other Not available Note to Physicians (Treatment, Testing, and Monitoring) Not available 5. Fire Fighting Measures Flashpoint Method: °F Flammable (Explosive) Limits in Air LEL UEL Autoignition Temperature °F Hazard Rating COC 405 Not determined Not determined 315 600 Health 0 Fire 1 Reactivity 0 PPE B Flame Propagation or Burning Rate (for solids) Properties Contributing to Fire Intensity Flammability Classification N/A Not Determined N/A Extinguishing Media Extinguishing Media to Avoid Reactions to Extinguishing Media Water fog, foam, CO2, dry chemical Not Available Not Available Protection and Procedures for Firefighters Wear positive pressure self-contained breathing apparatus (SCUBA). Use water to cool containers exposed to flames. Structural firefighters’ protective clothing will only provide limited protection. Unusual Fire and Explosion Hazards Mist or sprays may be flammable below the product normal flash point. 6. Accidental Release Measures Spill/Leak Clean-up Procedures and Equipment Observing health hazards described above, ventilate area. Dike to contain spill. Pick up free liquid for recycle and/or disposal. Residual liquid and/or solid can be absorbed on inert material. Keep from sewers and natural water. Evacuation Procedures Large spill • Consider initial downwind evacuate for at least 300 meters (1000 feet). Fire * If tank, rail car or tank car is involved in a fire, isolate for 800 meters (1/2 mile) in all directions; also consider initial evacuation for 800 meters (1/2 mile) in all directions. Special Instructions When using this material, do not eat, drink, or smoke. Wash thoroughly after handling. Keep away from animals and children. Reporting Requirements Spills that enter a water body must be reported immediately to the USEPA’s National Response Center at (800)546-2972. Check with your local and state regulators regarding their reporting requirements. 7. Handling and Storage Handling Practices and Warnings Do not pressure, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition; they may explode. See NFPA 30 and OSHA 1910.106 – flammable and combustible liquids. Storage Practices and Warnings Store away from heat, sparks, open flame, or strong oxidizing agents in closed and properly labeled containers. Empty containers retain product residue (liquid, and/or vapor) and can be dangerous. Page 882 of 1235 Page 882 of 1235 Page 882 of 1235 Page 882 of 1235 ---PAGE BREAK--- MSDS – OMNI SPECIALTY PACKAGING Page 3 of 6 8. Exposure Control/Personal Protection Other Engineering controls Ventilation N/A Additional area ventilation or local exhaust may be required to maintain air concentrations below recommended limits. Routes of Entry: Personal Protective Equipment (PPE) for Normal Use: PPE for Emergencies Eye/Face Safety glasses or face shield where splashing is possible. Full face shield Skin As needed to prevent repeated skin contact. Solvent resistant gloves should be used if needed. Inhalation Not normally needed. Respirator 9. Physical and Chemical Properties Appearance Odor Clear light yellow liquid Mild petroleum odor Normal Physical State: Boiling Point 575 ° F x Liquid Gas Melting Point N/A ° F Solid (Other) Freezing Point -25 ° F Specific Gravity or Density (H20 = 1) Solubility in Water pH 0.88 Negligible N/A Vapor Pressure (mm Hg.) Vapor Density (AIR = 1) Evaporation Rate (Butyl Acetate = 1) <0.1 @ 20c Not Determined Not Available Other N/A 10. Stability and Reactivity Incompatibility (Materials to Avoid) Heat, open flame, and oxidizing agents. Hazardous Products Produced During Decomposition Combustion products may include smoke, fumes, oxides of phosphorus, boron, sulfur, nitrogen, carbon dioxide, carbon monoxide, and other low molecular weight hydrocarbons. Hazardous Polymerization? May Occur X Will Not Occur Conditions to Avoid Stability? X Stable Unstable Conditions to Avoid Sources of ignition 11. Toxicological Information Toxicity Data, Epidemiology Studies, Carcinogenicity, Neurological Effects, Genetic Effects, Reproductive Effects, or Structure Activity Data Acute Toxicity: Test on similar materials show a low order of acute oral and dermal toxicity. Acute Oral Effects: Test on similar materials indicates low order of acute toxicity. Acute Inhalation Effects: Low acute toxicity expected on inhalation. Skin Effects: Practically non-toxic if absorbed. Other similar highly refined products have not shown skin tumors in mouse skin painting studies. Eye Irritation: Minimal irritation on contact. Eye irritation or practically non-irritating base on similar products. Carcinogenicity: Skin: Not considered a potential carcinogen base on IP346 DMSO of less than 3.0 wt% Genotoxicity: This product is considered non-mutagenic and has negative potential for tumor development based on from Modified Ames Assay, with Mutagenic Index of less than 1.0. Page 883 of 1235 Page 883 of 1235 Page 883 of 1235 Page 883 of 1235 ---PAGE BREAK--- MSDS – OMNI SPECIALTY PACKAGING Page 4 of 6 12. Ecological Information Toxicity, Environmental Fate, Physical/Chemical Data, or Other Data Supporting Environmental Hazard Statements If applied to leaves, this product may kill grasses and small plants by interfering with transpiration and respiration. This product is not toxic to fish but may coat gill structures resulting in suffocation if spilled in shallow, running water. Product may be moderately toxic to amphibians by preventing dermal respiration. This product may cause gastrointestinal distress to birds and mammals through ingestion during pelage grooming. 13. Disposal Considerations Regulations Dispose in accordance with all local, state, and federal regulations. Keep this product out of sewers and waterways. Note: State or local requirements may differ from federal regulations. Processing or using this product may make the information here inappropriate. Waste generators are responsible for waste classification, transport, and disposal. 14. Transport Information Regulated for shipping? Proper Shipping Name Packing Group Yes X No N/A N/A Do changes in quantity, packaging, or shipment method change product qualification? Hazard Class Identification Number Yes x No N/A N/A Other N/A Page 884 of 1235 Page 884 of 1235 Page 884 of 1235 Page 884 of 1235 ---PAGE BREAK--- MSDS – OMNI SPECIALTY PACKAGING Page 5 of 6 15. Regulatory Information Federal Regulations (OSHA, TSCA, CERCLA, FIFRA, EPCRA, CAA, CWA, SDWA, CPSA, DEA, FDA/USDA, etc.) State Regulations U.S. Federal Regulatory Information: CERCLA/SARA 302/303/304 Categories: Extremely Hazardous Substances No (40 CFR 355 Appendix A) 311/312 Categories: Immediate (Acute) Health Effects No (40 CFR 370) Delayed (Chronic) Health Effects No Fire Hazard No Sudden Release of Pressure Hazard No Reactivity Hazard No 313 Categories: Toxic Chemicals (40 CFR 372) No Clean Air Act: Hazardous Air Pollutants (HAPS) No Clean Water Act: If spilled into navigable waters it is reportable to National Response Center, [PHONE REDACTED] (40 CFR 116; 401.15) Reportable Quantity = Oil Sheen present on navigable water surface OSHA (29 CFR 1910): This product is not hazardous under Hazard Communication Standard 29 CFR 1910.1200 RCRA (40 CFR 261.133) This product does not meet hazardous waste criteria. EPA/TSCA Inventory: The components of this product are listed on the EPA/TSCA inventory of chemicals. CAS No. 64742-52-5 State Regulations: California Prop 65 No Proposition 65 chemicals exist in this product, no labeling required. Florida No listed ingredients are present Massachusetts RTK No listed ingredients are present Minnesota RTK No listed ingredients are present New Jersey RTK Lists petroleum oil, but this product does not contain hazardous ingredients. RTK Lists petroleum oil, but this product does not contain hazardous ingredients greater than Illinois DOL TSL No listed ingredients are present Other Regulations: WHMIS (Canada) Not listed on the Canadian Controlled Product Ingredient Disclosure and is compliant with Controlled Products Regulation CONEG Metals: Since cadmium, chromium, lead and mercury are not detectable and it does not exceed 100 ppm total in this product, it is compliant with CONEG Metals regulation. EEC (Europe): This product is not known to be a dangerous good internationally. No known R-Phrases or S-Phrases Hazard Label None Danger Symbol None Foreign/International Inventories: The components of this product are listed under the following foreign inventories: European Union’s EINICS No. 265-155- 0 Korea’s ECL No. KE-12543 Australia’s AICS No. 64742-52-5 Canada’s DSL No. 64742-52-5 Philippines’ PICCS – on List International Regulations N/A Other Not all ingredients will be present in some finished products. Page 885 of 1235 Page 885 of 1235 Page 885 of 1235 Page 885 of 1235 ---PAGE BREAK--- MSDS – OMNI SPECIALTY PACKAGING Page 6 of 6 16. Other Information Label Text, Hazard Rating System, Key Legend, or Other Abbreviations ACGIH(American Conference of Governmental Industrial Hygienists); ANSI(American National Standards Institute); CAS(Chemical Abstract Service); CERCLA(Comprehensive Environmental Response, Compensation, & Liability Act); CFR(Code of Federal Regulations); CHIP (Chemicals Hazard Information & Packaging for Supply); CONCAWE (European Organization for Environment, Health & Safety); CPR(Controlled Products Regulations); DOL (Department of Labor); EED(European Economic Community Directives); EINECS (European Inventory of Existing Commercial Chemical Substances); EL50 (Effective loading rate required to immobilize 50% invertebrate species); ELINCS(European List of New Chemical Substances); EPA (Environmental Protection Agency); EPCRA(Emergency Planning & Community Right-To-Know Act of 1986); EU(European Union); FDA(Food & Drug Administration-USA); GHS (Global Harmonization System); HCS (Hazard Communication Standard); IARC(International Agency for Research on Cancer); ILO(International Labor Organization); LC50(Lethal Concentration 50% test organisms); LD50(Lethal Dose 50% test organisms); LVP-VOC(Low Vapor Pressure Volatile Organic Compound); MSDS(Material Safety Data Sheet); MSHA(Mine Safety & Health Administration); NIOSH(National Institute of Occupational Safety & Health);NTP(National Toxicology Program); OSHA(Occupational Safety & Health Administration); PEL(Permissible Exposure Limit); Prop 65(California Proposition 65); PMCC(Pensky Martin Closed Cup); RCRA(Resource Conservation & Recovery Act); RTK(Right-To-Know); R-Phrases(EU Risk Phrases; S-Phrases (EU Safety Phrases); SARA(Superfund Amendments & Reauthorization Act); TSCA (Toxic Substances Control Act); TSL (Toxic Substance List); TLV(Threshold Limit Value); WHMIS(Workplace Hazardous Materials Information System- Canada); lrL50 (Inhibitory loading rate required to reduce algal growth rate by 50%; lbL50 (Inhibitory loading rate required to reduce area under growth curve or biomass by 50%); ppm (parts per million); mg/m3 (milligrams per cubic meter); N(no); Y (yes) NFPA Hazard Rating – Health 0 Slight -Fire 1 Slight Reactivity 0 Least Prepared By: Juan Parker Phone: (318) 524-1100 This MSDS complies with OSHA Hazard Communication Standard (HCS) 29 CFR 1910.1200 and conforms to ANSI Z 400.1 16-Section Format. Disclaimer: Omni Specialty Packaging believes this information is accurate but not all-inclusive in all circumstances. It is the responsibility of the user to determine suitability of the material for their purposes. No warranty, expressed or implied, is given. NOTE: OSHA’s Hazard Communication Standard (29 CFR 1910.1200) does not require the information requested in Sections 11, 12, 13, 4, 15, and 16 for If your company chooses not to fill in these sections, you may wish to enter something (like N/R for “not regulated” or N/A for “not applicable”) to indicate that the field is purposely being left blank. Page 886 of 1235 Page 886 of 1235 Page 886 of 1235 Page 886 of 1235 ---PAGE BREAK--- Revised on 3/27/06 MATERIAL SAFETY DATA SHEET O M N I I N D U S T R I E S, I N C. 7031 BRYCE CANYON AVENUE • GREENWELL SPRINGS, LA 70739 • (225) 261-6559 MATERIAL SAFETY DATA SHEET May be used to comply OSHA’s Hazard Communication Standard 29 CFR 1910.1200. Standard must be consulted for specific requirements. U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration. (Non-Mandatory Form) Form Approved OMB No.1218-0072. SECTION I GENERAL INFORMATION PRODUCT NAME Pure Guard Super Heavy Duty BRAKE FLUID DOT 3 – 450 min PART NUMBER SECTION II HAZARDOUS INGREDIENTS/IDENTITY INFORMATION COMPONENT WT.% C.A.S. No TLV(ACGIHxx OSHA--) Polyethylene Glycol Ethers 50-85 112-505 N/A Polyethylene Glycol 15-50 25322-68-3 N/A Comments: National Toxicology Program (NTP) Components not identified are non-hazardous according to 29 CFR 1910.1200 SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS Specific Gravity (H2O=1) 1.038-1.04 Appearance and Odor Clear, amber liquid with slight etheric odor Solubility in Water Complete pH N/A Flash Point (TOC), °F 270 Solubility in Solvent N/A Melting Point, °F N/A %Volatiles By Wt. N/A Vapor Pressure (mmHg) <0.1@ 20°C Boiling Point, °F 455-475 Evaporation Rate (Butyl Acetate=1) N/A Vapor Density (Air=1) N/A SECTION IV FIRE AND EXPLOSION HAZARD DATA EXTINGUISHING MEDIA: Water Fog xx Foam xx CO2 xx Dry Chemicals xx SPECIAL FIRE FIGHTING PROCEDURES: Water may be ineffective but can be used to cool containers exposed to heat or flame. When using water or foam, frothing may occur, especially if sprayed into containers of hot, burning liquid. Fire fighters should wear self-contained, positive pressure breathing apparatus and protective clothes. UNUSUAL FIRE AND EXPLOSION HAZARDS: None known. SECTION V REACTIVITY DATA Stable xx Unstable Corrosive Hazardous - Polymerization? Yes No xx Incompatibilities: Strong oxidizing agents. Hazardous Decomposition or Byproducts: Fire: Normal products of combustion; carbon dioxide, carbon monoxide. Page 887 of 1235 Page 887 of 1235 Page 887 of 1235 Page 887 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Page 2 Revision Date: 02/20/2007 SECTION VI HEALTH HAZARD INFORMATION Recommended TLV of Product Not Established EYE CONTACT Low hazard for usual handling. SKIN CONTACT Prolonged contact with skin could result in irritation. INHALATION Low hazard at ambient condition. Avoid prolonged inhalation of mist or vapors. Acute or chronic overexposure may be irritating to the respiratory tract. Severe intoxication may lead to drowsiness, dullness, numbness, and headache followed by dizziness, weakness, and nausea. INGESTION Do not ingest. Ingestion of large quantities may be fatal. OTHER None known. SECTION VII EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT Flush with water for 15 minutes thoroughly and continue flushing until irritation subsides. SKIN CONTACT Wash with soap and water thoroughly. Remove contaminated clothing and wash before re-use. If redness or irritation occurs, seek medical attention. INHALATION Remove effected person to fresh air immediately. INGESTION If person is conscious, give large quantities of water immediately. Induce vomiting. Get immediate medical attention. SECTION VIII SPECIAL PROTECTION INFORMATION CONSUMER BULK HANDLING (Prolonged Exposure) RESPIRATORY PROTECTION N/A If TVL is exceeded, wear NIOSH approved respirator. VENTILATION Use with adequate ventilation. General. EYE PROTECTION N/A Goggles or face shield. PROTECTIVE CLOTHING N/A Impervious rubber clothing (bots, gloves, aprons, etc.) over parts of the body subject to exposure. SECTION IX PRECAUTIONS FOR SAFE HANDLING AND USE SPILL OR LEAK PROCEDURE Remove all sources of ignition. Small spills may be collected with absorbent materials. For larger spills, flush area with water spray. Prevent runoff from entering drains, sewers, or streams. Large spills may be picked up using vacuum pumps, shovels, buckets, or other means and placed in drums or other suitable containers. WASTE DISPOSAL METHOD Dispose in accordance with all local, state and federal regulations. Department of Transportation (DOT) regulations may apply for transporting this material when spilled. Waste material may be land filled or incinerated at an approved facility. Materials should be recycled if possible. STORAGE AND HANDLING PRECAUTIONS Store in properly marked, closed containers away from heat, sparks, open flame, and oxidizing agents. OTHER PRECAUTIONS Wearing contact lenses is inadvisable. Wash thoroughly after handling. Good hygiene practice should be followed which includes minimizing skin contact. Keep away from children and animals. OSHA While Omni Industry, Inc. believes this data is accurate as of revision date, we make no warranty with respect to the data and we expressly disclaim all liability for thereon. The data is offered solely for your information, investigation, and verification. Page 888 of 1235 Page 888 of 1235 Page 888 of 1235 Page 888 of 1235 ---PAGE BREAK--- Revised on 01/12/2009 MATERIAL SAFETY DATA SHEET O M N I I N D U S T R I E S, I N C. 7031 BRYCE CANYON AVENUE • GREENWELL SPRINGS, LA 70739 • (225) 261-6559 For Chemical Emergency, Spill Leak Fire Exposure or Accident Call CHEMTREC Day or Night DOMESTIC NORTH AMERICA [PHONE REDACTED] INTERNATIONAL, CALL [PHONE REDACTED] (collect calls accepted) MATERIAL SAFETY DATA SHEET May be used to comply OSHA’s Hazard Communication Standard 29 CFR 1910.1200. Standard must be consulted for specific requirements. U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration. (Non-Mandatory Form) Form Approved OMB No.1218-0072. SECTION I GENERAL INFORMATION PRODUCT NAME Pure Guard Super Heavy Duty BRAKE FLUID DOT 3 – 450 min PART NUMBER SECTION II HAZARDOUS INGREDIENTS/IDENTITY INFORMATION COMPONENT WT.% C.A.S. No TLV(ACGIHxx OSHA--) Polyethylene Glycol Ethers 50-85 112-505 N/A Polyethylene Glycol 15-50 25322-68-3 N/A Comments: National Toxicology Program (NTP) Components not identified are non-hazardous according to 29 CFR 1910.1200 SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS Specific Gravity (H2O=1) 1.038-1.04 Appearance and Odor Clear, amber liquid with slight etheric odor Solubility in Water Complete pH N/A Flash Point (TOC), °F 270 Solubility in Solvent N/A Melting Point, °F N/A %Volatiles By Wt. N/A Vapor Pressure (mmHg) <0.1@ 20°C Boiling Point, °F 455-475 Evaporation Rate (Butyl Acetate=1) N/A Vapor Density (Air=1) N/A SECTION IV FIRE AND EXPLOSION HAZARD DATA EXTINGUISHING MEDIA: Water Fog xx Foam xx CO2 xx Dry Chemicals xx SPECIAL FIRE FIGHTING PROCEDURES: Water may be ineffective but can be used to cool containers exposed to heat or flame. When using water or foam, frothing may occur, especially if sprayed into containers of hot, burning liquid. Fire fighters should wear self-contained, positive pressure breathing apparatus and protective clothes. UNUSUAL FIRE AND EXPLOSION HAZARDS: None known. SECTION V REACTIVITY DATA Stable xx Unstable Corrosive Hazardous - Polymerization? Yes No xx Incompatibilities: Strong oxidizing agents. Hazardous Decomposition or Byproducts: Fire: Normal products of combustion; carbon dioxide, carbon monoxide. Page 889 of 1235 Page 889 of 1235 Page 889 of 1235 Page 889 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Page 2 Revision Date: 02/20/2008 SECTION VI HEALTH HAZARD INFORMATION Recommended TLV of Product Not Established EYE CONTACT Low hazard for usual handling. SKIN CONTACT Prolonged contact with skin could result in irritation. INHALATION Low hazard at ambient condition. Avoid prolonged inhalation of mist or vapors. Acute or chronic overexposure may be irritating to the respiratory tract. Severe intoxication may lead to drowsiness, dullness, numbness, and headache followed by dizziness, weakness, and nausea. INGESTION Do not ingest. Ingestion of large quantities may be fatal. OTHER None known. SECTION VII EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT Flush with water for 15 minutes thoroughly and continue flushing until irritation subsides. SKIN CONTACT Wash with soap and water thoroughly. Remove contaminated clothing and wash before re-use. If redness or irritation occurs, seek medical attention. INHALATION Remove effected person to fresh air immediately. INGESTION If person is conscious, give large quantities of water immediately. Induce vomiting. Get immediate medical attention. SECTION VIII SPECIAL PROTECTION INFORMATION CONSUMER BULK HANDLING (Prolonged Exposure) RESPIRATORY PROTECTION N/A If TVL is exceeded, wear NIOSH approved respirator. VENTILATION Use with adequate ventilation. General. EYE PROTECTION N/A Goggles or face shield. PROTECTIVE CLOTHING N/A Impervious rubber clothing (bots, gloves, aprons, etc.) over parts of the body subject to exposure. SECTION IX PRECAUTIONS FOR SAFE HANDLING AND USE SPILL OR LEAK PROCEDURE Remove all sources of ignition. Small spills may be collected with absorbent materials. For larger spills, flush area with water spray. Prevent runoff from entering drains, sewers, or streams. Large spills may be picked up using vacuum pumps, shovels, buckets, or other means and placed in drums or other suitable containers. WASTE DISPOSAL METHOD Dispose in accordance with all local, state and federal regulations. Department of Transportation (DOT) regulations may apply for transporting this material when spilled. Waste material may be land filled or incinerated at an approved facility. Materials should be recycled if possible. STORAGE AND HANDLING PRECAUTIONS Store in properly marked, closed containers away from heat, sparks, open flame, and oxidizing agents. OTHER PRECAUTIONS Wearing contact lenses is inadvisable. Wash thoroughly after handling. Good hygiene practice should be followed which includes minimizing skin contact. Keep away from children and animals. OSHA While Omni Industry, Inc. believes this data is accurate as of revision date, we make no warranty with respect to the data and we expressly disclaim all liability for thereon. The data is offered solely for your information, investigation, and verification. Page 890 of 1235 Page 890 of 1235 Page 890 of 1235 Page 890 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® FLYING INSECT KILLER 7 (COUNTRY FRESH) Version 1.0 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000016860 1/14 1. PRODUCT AND COMPANY IDENTIFICATION Product information Product name : RAID® FLYING INSECT KILLER 7 (COUNTRY FRESH) Recommended use : Insecticide Manufacturer, importer, supplier : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236 Telephone : +18005585252 Emergency telephone number : 24 Hour Medical Emergency Phone: (866)231-5406 24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300 2. HAZARDS IDENTIFICATION Classification of the substance or mixture Globally Harmonized System (GHS) Classification Hazard classification Hazard category Hazards identification Aerosol Category 2 Flammable aerosol. Gases under pressure Liquefied gas Contains gas under pressure; may explode if heated. Labelling Hazard symbols Flame Gas cylinder Signal word Warning Hazard statements Flammable aerosol. Contains gas under pressure; may explode if heated. Precautionary statements Protect from sunlight. Do not expose to temperatures exceeding 50 122 Protect from sunlight. Store in a well-ventilated place. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Page 891 of 1235 Page 891 of 1235 Page 891 of 1235 Page 891 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® FLYING INSECT KILLER 7 (COUNTRY FRESH) Version 1.0 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000016860 2/14 Other hazards : None identified 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No. Weight percent Hydrocarbons, C14-C18, n-alkanes, isoalkanes, cyclics, aromatics 64742-47-8 10.00 - 30.00 Butane 106-97-8 5.00 - 10.00 Propane 74-98-6 5.00 - 10.00 Isobutane 75-28-5 5.00 - 10.00 d-Phenothrin 188023-86-1 0.10 - 1.00 Prallethrin 23031-36-9 0.10 - 1.00 The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Eye contact : No special requirements Skin contact : No special requirements Inhalation : No special requirements. Ingestion : No special requirements 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during firefighting : Aerosol Product - Containers may rocket or explode in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses. Further information : Fight fire from maximum distance or protected area. Cool and use caution when approaching or handling fire-exposed Page 892 of 1235 Page 892 of 1235 Page 892 of 1235 Page 892 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® FLYING INSECT KILLER 7 (COUNTRY FRESH) Version 1.0 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000016860 3/14 containers. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. NFPA Classification : NFPA Level 1 Aerosol 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Remove all sources of ignition. Wear personal protective equipment. Wash thoroughly after handling. Environmental precautions : Do not flush into surface water or sanitary sewer system. Use appropriate containment to avoid environmental contamination. Outside of normal use, avoid release to the environment. Methods and materials for containment and cleaning up : If damage occurs to aerosol can: Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Dike large spills. Clean residue from spill site. 7. HANDLING AND STORAGE Handling Precautions for safe handling : Avoid contact with skin, eyes and clothing. Do not enter places where used or stored until adequately ventilated. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Pressurized container. Do not pierce or burn, even after use. Advice on protection against fire and explosion : Keep away from sources of ignition - No smoking. Do not spray on an open flame or other ignition source. Page 893 of 1235 Page 893 of 1235 Page 893 of 1235 Page 893 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® FLYING INSECT KILLER 7 (COUNTRY FRESH) Version 1.0 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000016860 4/14 Storage Requirements for storage areas and containers : Protect from sunlight. Do not expose to temperatures exceeding 50 122 Keep away from food, drink and animal feedingstuffs. Keep in a dry, cool and well-ventilated place. Protect from sunlight. Store in a well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Non- standard units Basis Hydrocarbons, C14-C18, n- alkanes, isoalkanes, cyclics, aromatics 64742-47-8 1,200 mg/m3 152 ppm - SUPPLIER Butane 106-97-8 - 1,000 ppm - ACGIH STEL Propane 74-98-6 - 1,000 ppm - ACGIH TWA Propane 74-98-6 1,800 mg/m3 1,000 ppm - OSHA TWA Isobutane 75-28-5 - 1,000 ppm - ACGIH STEL Personal protective equipment Respiratory protection : Do not spray in enclosed areas. Hand protection : No special requirements. Eye protection : No special requirements. Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety Page 894 of 1235 Page 894 of 1235 Page 894 of 1235 Page 894 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® FLYING INSECT KILLER 7 (COUNTRY FRESH) Version 1.0 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000016860 5/14 practice. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : aerosol Color : natural colour Odor : pleasant mild Odour Threshold : No data available pH : 7.0 Melting point/freezing point : No data available Initial boiling point and boiling range : 225 °C Flash point : -7 °C 19.4 °F Propellant Evaporation rate : No data available Flammability (solid, gas) : No data available Upper/lower flammability or explosive limits : No data available Vapour pressure : No data available Vapour density : No data available Page 895 of 1235 Page 895 of 1235 Page 895 of 1235 Page 895 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® FLYING INSECT KILLER 7 (COUNTRY FRESH) Version 1.0 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000016860 6/14 Relative density : 0.82 g/cm3 Solubility(ies) : dispersible Partition coefficient: n- octanol/water : No data available Auto-ignition temperature : No data available Decomposition temperature : Viscosity, dynamic : No data available Viscosity, kinematic : Not applicable Oxidizing properties : No data available Volatile Organic Compounds Total VOC (wt. : 19.1 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations Other information : None identified : 10. STABILITY AND REACTIVITY Possibility of hazardous reactions : If accidental mixing occurs and toxic gas is formed, exit area immediately. Do not return until well ventilated. Conditions to avoid : Heat, flames and sparks. Incompatible materials : Strong oxidizing agents Do not mix with bleach or any other household cleaners. Strong bases Page 896 of 1235 Page 896 of 1235 Page 896 of 1235 Page 896 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® FLYING INSECT KILLER 7 (COUNTRY FRESH) Version 1.0 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000016860 7/14 Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. 11. TOXICOLOGICAL INFORMATION Emergency Overview : Warning Acute oral toxicity : LD50 Measured > 5,000 mg/kg Acute inhalation toxicity : LC50 Measured > 5.05 mg/l Acute dermal toxicity : LD50 Measured > 5,000 mg/kg GHS Properties Classification Routes of entry Acute toxicity No classification proposed - Skin corrosion/irritation No classification proposed - Serious eye damage/eye irritation No classification proposed - Skin sensitisation No classification proposed - Respiratory sensitisation No classification proposed - Germ cell mutagenicity No classification proposed - Carcinogenicity No classification proposed - Reproductive toxicity No classification proposed - Specific target organ toxicity - single exposure No classification proposed - Specific target organ toxicity - repeated No classification proposed - Page 897 of 1235 Page 897 of 1235 Page 897 of 1235 Page 897 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® FLYING INSECT KILLER 7 (COUNTRY FRESH) Version 1.0 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000016860 8/14 exposure Aspiration hazard No classification proposed - Aggravated Medical Condition : None known. 12. ECOLOGICAL INFORMATION Product : The product itself has not been tested. Toxicity The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions. Toxicity to fish Hydrocarbons, C14-C18, n- alkanes, isoalkanes, cyclics, aromatics LC50 Fish > 1,028 mg/l 96 h Butane No data available Propane LC50 Fish 27.98 mg/l 96 h Isobutane LC50 Fish 27.98 mg/l 96 h d-Phenothrin LC50 mykiss (rainbow trout) 0.0027 mg/l 96 h NOEC mykiss (rainbow trout) > 0.0011 mg/l 90 d Prallethrin LC50 mykiss (rainbow trout) 0.012 mg/l 96 h Components End point Species Value Exposure time Page 898 of 1235 Page 898 of 1235 Page 898 of 1235 Page 898 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® FLYING INSECT KILLER 7 (COUNTRY FRESH) Version 1.0 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000016860 9/14 Toxicity to aquatic invertebrates Hydrocarbons, C14-C18, n- alkanes, isoalkanes, cyclics, aromatics EC50 No data available > 3,193 mg/l 48 h Butane No data available Propane LC50 Daphnid 14.22 mg/l 48 h Isobutane LC50 Daphnid 16.33 mg/l 48 h d-Phenothrin EC50 Daphnia (water flea) 0.0043 mg/l 48 h NOEC Daphnia (water flea) 0.00062 mg/l 21 d Prallethrin EC50 Daphnia magna (Water flea) 0.0062 mg/l 48 h Toxicity to aquatic plants Hydrocarbons, C14-C18, n- EC50 Skeletonema costatum 3,198 mg/l 72 h Components End point Species Value Exposure time Components End point Species Value Exposure time Page 899 of 1235 Page 899 of 1235 Page 899 of 1235 Page 899 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® FLYING INSECT KILLER 7 (COUNTRY FRESH) Version 1.0 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000016860 10/14 alkanes, isoalkanes, cyclics, aromatics Butane No data available Propane No data available Isobutane EC50 Green algea 8.57 mg/l 96 h d-Phenothrin EbC50 No data available > 0.011 mg/l 72 h Prallethrin No data available Pseudokirchneriella subcapitata (green algae) 2 mg/l 96 h Persistence and degradability Component Biodegradation Exposure time Summary Hydrocarbons, C14-C18, n- alkanes, isoalkanes, cyclics, aromatics No data available Butane 100 % 385.5 h Readily biodegradable Propane 70 % < 10 d Readily biodegradable Isobutane 70 % < 10 d Readily biodegradable d-Phenothrin 1 % 28 d Not readily biodegradable. Prallethrin No data available Not readily biodegradable. Bioaccumulative potential Component Bioconcentration factor (BCF) Partition Coefficient n- Octanol/water (log) Hydrocarbons, C14-C18, n- alkanes, isoalkanes, cyclics, aromatics No data available No data available Butane No data available 2.89 Propane No data available 2.36 Isobutane 1.57 - 1.97 2.8 Page 900 of 1235 Page 900 of 1235 Page 900 of 1235 Page 900 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® FLYING INSECT KILLER 7 (COUNTRY FRESH) Version 1.0 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000016860 11/14 d-Phenothrin 2,506 - 3,192 Measured 6.8 Prallethrin No data available 4.49 Mobility Component End point Value Hydrocarbons, C14-C18, n- alkanes, isoalkanes, cyclics, aromatics No data available - Butane No data available Propane No data available Isobutane No data available d-Phenothrin Koc 125893 Prallethrin No data available PBT and vPvB assessment Component Results Butane Not fulfilling PBT and vPvB criteria Propane Not fulfilling PBT and vPvB criteria Isobutane Not fulfilling PBT and vPvB criteria d-Phenothrin Not fulfilling PBT and vPvB criteria Prallethrin Not fulfilling PBT and vPvB criteria Other adverse effects : None known. 13. DISPOSAL CONSIDERATIONS PESTICIDAL WASTE: For disposal information, please read and follow Disposal instructions on the pesticide label. Consumer may discard empty container in trash, or recycle where facilities exist. Page 901 of 1235 Page 901 of 1235 Page 901 of 1235 Page 901 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® FLYING INSECT KILLER 7 (COUNTRY FRESH) Version 1.0 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000016860 12/14 14. TRANSPORT INFORMATION Please refer to the Bill of Lading/receiving documents for up-to-date shipping information. Land transport Sea transport Air transport UN number 1950 1950 1950 UN proper shipping name AEROSOLS, Flammable, 2.1 AEROSOLS, Flammable, 2.1 AEROSOLS, Flammable, 2.1 Transport hazard class(es) 2.1 2 2.1 Packing group - - - Environmental hazards - - - Special precautions for user Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. 15. REGULATORY INFORMATION Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65. Page 902 of 1235 Page 902 of 1235 Page 902 of 1235 Page 902 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® FLYING INSECT KILLER 7 (COUNTRY FRESH) Version 1.0 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000016860 13/14 16. OTHER INFORMATION HMIS Ratings Health 2 Flammability 4 Reactivity 0 NFPA Ratings Health 2 Fire 4 Reactivity 0 Special - This information is being provided in accordance with the Occupational Safety and Health Administration (OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use. Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 903 of 1235 Page 903 of 1235 Page 903 of 1235 Page 903 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® FLYING INSECT KILLER 7 (COUNTRY FRESH) Version 1.0 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000016860 14/14 Page 904 of 1235 Page 904 of 1235 Page 904 of 1235 Page 904 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 1/14 1. PRODUCT AND COMPANY IDENTIFICATION Product information Product name : RAID® WASP & HORNET KILLER 33 Recommended use : Insecticide Manufacturer, importer, supplier : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236 Telephone : +18005585252 Emergency telephone number : 24 Hour Medical Emergency Phone: (866)231-5406 24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300 2. HAZARDS IDENTIFICATION Classification of the substance or mixture Globally Harmonized System (GHS) Classification Hazard classification Hazard category Hazards identification Aerosol Category 1 Extremely flammable aerosol. Aspiration hazard Category 1 May be fatal if swallowed and enters airways. Gases under pressure Compressed gas Contains gas under pressure; may explode if heated. Labelling Hazard symbols Flame Gas cylinder Health hazard Signal word Danger Hazard statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal if swallowed and enters airways. Precautionary statements If medical advice is needed, have product container or label at hand. Page 905 of 1235 Page 905 of 1235 Page 905 of 1235 Page 905 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 2/14 Keep out of reach of children. Read label before use. IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. Do NOT induce vomiting. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 122 Protect from sunlight. Store in a well-ventilated place. Dispose of contents/ container to an approved incineration plant. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Other hazards : None identified 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No. Weight percent Distillates (petroleum), hydrotreated light 64742-47-8 60.00 - 100.00 Carbon dioxide 124-38-9 1.00 - 5.00 Isopropanol 67-63-0 1.00 - 5.00 Cypermethrin 52315-07-8 0.0001 - 0.10 Prallethrin 23031-36-9 0.0001 - 0.10 The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Eye contact : No special requirements Skin contact : No special requirements Inhalation : No special requirements. Ingestion : IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. Do NOT induce vomiting. Page 906 of 1235 Page 906 of 1235 Page 906 of 1235 Page 906 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 3/14 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during firefighting : Do not use a solid water stream as it may scatter and spread fire. Aerosol Product - Containers may rocket or explode in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses. Further information : Fight fire from maximum distance or protected area. Cool and use caution when approaching or handling fire-exposed containers. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. NFPA Classification : NFPA Level 3 Aerosol 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Remove all sources of ignition. Wear personal protective equipment. Wash thoroughly after handling. Environmental precautions : Do not flush into surface water or sanitary sewer system. Use appropriate containment to avoid environmental contamination. Outside of normal use, avoid release to the environment. Methods and materials for containment and cleaning up : If damage occurs to aerosol can: Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Dike large spills. Clean residue from spill site. 7. HANDLING AND STORAGE Handling Page 907 of 1235 Page 907 of 1235 Page 907 of 1235 Page 907 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 4/14 Precautions for safe handling : Avoid contact with skin, eyes and clothing. Do not enter places where used or stored until adequately ventilated. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Pressurized container. Do not pierce or burn, even after use. Advice on protection against fire and explosion : Keep away from sources of ignition - No smoking. Do not spray on an open flame or other ignition source. Storage Requirements for storage areas and containers : Protect from sunlight. Do not expose to temperatures exceeding 50 122 Keep away from food, drink and animal feedingstuffs. Keep in a dry, cool and well-ventilated place. Store locked up. Page 908 of 1235 Page 908 of 1235 Page 908 of 1235 Page 908 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 5/14 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Non- standard units Basis Distillates (petroleum), hydrotreated light 64742-47-8 1,200 mg/m3 152 ppm - SUPPLIER Carbon dioxide 124-38-9 9,000 mg/m3 5,000 ppm - OSHA TWA Carbon dioxide 124-38-9 - 30,000 ppm - ACGIH STEL Carbon dioxide 124-38-9 - 5,000 ppm - ACGIH TWA Isopropanol 67-63-0 980 mg/m3 400 ppm - OSHA TWA Isopropanol 67-63-0 - 400 ppm - ACGIH STEL Isopropanol 67-63-0 - 200 ppm - ACGIH TWA Personal protective equipment Respiratory protection : Do not spray in enclosed areas. Hand protection : No special requirements. Eye protection : No special requirements. Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 909 of 1235 Page 909 of 1235 Page 909 of 1235 Page 909 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 6/14 Form : aerosol Color : clear Odor : characteristic Odour Threshold : No data available pH : Not applicable Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Flash point : 22 °C 71.6 °F Evaporation rate : No data available Flammability (solid, gas) : Sustains combustion Upper/lower flammability or explosive limits : No data available Vapour pressure : Not applicable Vapour density : No data available Relative density : 0.81 g/cm3 at 21 °CGLP: yes Solubility(ies) : negligible Partition coefficient: n- : No data available Page 910 of 1235 Page 910 of 1235 Page 910 of 1235 Page 910 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 7/14 octanol/water Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity, dynamic : No data available Viscosity, kinematic : No data available Oxidizing properties : No data available Volatile Organic Compounds Total VOC (wt. : 3 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations Other information : None identified : 10. STABILITY AND REACTIVITY Possibility of hazardous reactions : Stable under recommended storage conditions. Conditions to avoid : Heat, flames and sparks. Incompatible materials : Strong oxidizing agents Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. 11. TOXICOLOGICAL INFORMATION Emergency Overview : Danger Page 911 of 1235 Page 911 of 1235 Page 911 of 1235 Page 911 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 8/14 Acute oral toxicity : NA GHS LD50 estimated > 5,000 mg/kg Acute inhalation toxicity : NA GHS LC50 (dust and mist) estimated > 5.47 mg/l Acute dermal toxicity : NA GHS LD50 estimated > 5,000 mg/kg GHS Properties Classification Routes of entry Acute toxicity No classification proposed - Acute toxicity No classification proposed - Acute toxicity No classification proposed - Skin corrosion/irritation No classification proposed - Serious eye damage/eye irritation No classification proposed - Skin sensitisation No classification proposed - Respiratory sensitisation No classification proposed - Germ cell mutagenicity No classification proposed - Carcinogenicity No classification proposed - Reproductive toxicity No classification proposed - Specific target organ toxicity - single exposure No classification proposed - Specific target organ toxicity - repeated exposure No classification proposed - Aspiration hazard Category 1 - Aggravated Medical : None known. Page 912 of 1235 Page 912 of 1235 Page 912 of 1235 Page 912 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 9/14 Condition 12. ECOLOGICAL INFORMATION Product : The product itself has not been tested. Toxicity The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions. Toxicity to fish Distillates (petroleum), hydrotreated light static test LC50 Lepomis macrochirus 2.2 mg/l 96 h Carbon dioxide No data available Isopropanol LC50 Pimephales promelas (fathead minnow) 9,640 mg/l 96 h Cypermethrin LC50 mykiss (rainbow trout) 0.00283 mg/l 96 h NOEC Pimephales promelas (fathead minnow) 0.00001 mg/l 28 d Prallethrin LC50 mykiss (rainbow trout) 0.012 mg/l 96 h Toxicity to aquatic invertebrates Distillates (petroleum), hydrotreated light No data available Components End point Species Value Exposure time Components End point Species Value Exposure time Page 913 of 1235 Page 913 of 1235 Page 913 of 1235 Page 913 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 10/14 Carbon dioxide No data available Isopropanol EC50 Daphnia magna (Water flea) 13,299 mg/l 48 h Cypermethrin EC50 Daphnia magna (Water flea) 0.00471 mg/l 48 h NOEC Daphnia magna (Water flea) 0.00004 mg/l 21 d Prallethrin EC50 Daphnia magna (Water flea) 0.0062 mg/l 48 h Toxicity to aquatic plants Distillates (petroleum), hydrotreated light No data available Carbon dioxide No data available Isopropanol EC50 Desmodesmus subspicatus (green algae) > 1,000 mg/l 72 h Cypermethrin ErC50 No data available > 0.0033 mg/l 72 h Prallethrin No data available Pseudokirchneriella subcapitata (green algae) 2 mg/l 96 h Persistence and degradability Component Biodegradation Exposure time Summary Components End point Species Value Exposure time Page 914 of 1235 Page 914 of 1235 Page 914 of 1235 Page 914 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 11/14 Distillates (petroleum), hydrotreated light No data available Carbon dioxide No data available Isopropanol 53 % 5 d Readily biodegradable Cypermethrin 0.6 - 1.4 % 33 d Not readily biodegradable. Prallethrin No data available Not readily biodegradable. Bioaccumulative potential Component Bioconcentration factor (BCF) Partition Coefficient n- Octanol/water (log) Distillates (petroleum), hydrotreated light 61 - 159 No data available Carbon dioxide No data available No data available Isopropanol 0.96 estimated 0.05 Cypermethrin 373.4 Measured 5.3 - 5.6 Prallethrin No data available 4.49 Mobility Component End point Value Distillates (petroleum), hydrotreated light No data available Carbon dioxide No data available Isopropanol No data available Cypermethrin Koc 80653 - 574360 Prallethrin No data available PBT and vPvB assessment Component Results Distillates (petroleum), hydrotreated light Not fulfilling PBT and vPvB criteria Isopropanol Not fulfilling PBT and vPvB criteria Page 915 of 1235 Page 915 of 1235 Page 915 of 1235 Page 915 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 12/14 Cypermethrin Not fulfilling PBT and vPvB criteria Prallethrin Not fulfilling PBT and vPvB criteria Other adverse effects : None known. 13. DISPOSAL CONSIDERATIONS PESTICIDAL WASTE: For disposal information, please read and follow Disposal instructions on the pesticide label. Consumer may discard empty container in trash, or recycle where facilities exist. 14. TRANSPORT INFORMATION Please refer to the Bill of Lading/receiving documents for up-to-date shipping information. Land transport Sea transport Air transport UN number 1950 1950 1950 UN proper shipping name AEROSOLS, Flammable, 2.1 AEROSOLS, Flammable, 2.1 AEROSOLS, Flammable, 2.1 Transport hazard class(es) 2.1 2 2.1 Packing group - - - Environmental hazards - - - Special precautions for user Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. 15. REGULATORY INFORMATION FIFRA Labeling This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to Page 916 of 1235 Page 916 of 1235 Page 916 of 1235 Page 916 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 13/14 certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION: CONTENTS UNDER PRESSURE. Exposure to temperatures above 130° F may cause bursting. Extremely flammable. This product is extremely toxic to fish and aquatic invertebrates. Drift and runoff may be hazardous to fish in water adjacent to treated areas. Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Registration # / Agency 4822-553/US/EPA 16. OTHER INFORMATION HMIS Ratings Health 2 Flammability 3 Reactivity 0 Page 917 of 1235 Page 917 of 1235 Page 917 of 1235 Page 917 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 14/14 NFPA Ratings Health 2 Fire 3 Reactivity 0 Special - This information is being provided in accordance with the Occupational Safety and Health Administration (OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use. Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 918 of 1235 Page 918 of 1235 Page 918 of 1235 Page 918 of 1235 ---PAGE BREAK--- I M A T E R I A L S A F E T Y D A T A S H E E T I I SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION I PRODUCT NAME : RED AUTO PRIMER 0006360 IDENTIFICATION NUMBER: 2067 830 DATE PRINTED : 05/19/00 PRODUCT USE/CLASS : Stops Rust Spray Primer SUPPLIER: MANUFACTURER: Rust-Oleum Corporation Rust-Oleum Corporation 11 Hawthorn Parkway 11 Hawthorn Parkway Vernon Hills, Illinois Vernon Hills, Illinois 60061 USA 60061 USA (847) 367-7700 Rust-Oleum Corp. (847) 367-7700 Rust-Oleum Corp. 8:00 AM-4:30 PM/24-hr Emer.Assist 8:00 AM-4:30 PM/24-hr Emer.Assist PREPARER: L.J.W., PHONE: [PHONE REDACTED], PREPARE DATE: 05/11/00 I SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS I WT/WT % ITEM CHEMICAL NAME CAS NUMBER LESS THAN 01 LIQUIFIED PETROLEUM GAS 68476-85-7 35.0 % 02 XYLENE 1330-20-7 20.0 % 03 MAGNESIUM SILICATE HYDRATE-TALC 14807-96-6 20.0 % 04 TOLUENE 108-88-3 15.0 % 05 100-41-4 5.0 % EXPOSURE LIMITS ACGIH OSHA MEXICAN ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN 01 1000 PPM N.E. 1000 PPM N.E. N.E. NO 02 100PPM 150PPM 100PPM N.E. 100 PPM YES 03 10mg/m3 N.E. 15mg/m3 N.E. N.E. NO 04 50 PPM N.E. 200 PPM 300 PPM N.E. YES 05 100 PPM 125 PPM 100 PPM N.E. N.E. YES Page 919 of 1235 Page 919 of 1235 Page 919 of 1235 Page 919 of 1235 ---PAGE BREAK--- (See Section 16 for abbreviation legend) (Continued on Page 2) Product: 2067 830 Preparation Date: 05/11/00 Page 2 I SECTION 3 - HAZARDS IDENTIFICATION I EMERGENCY OVERVIEW Harmful if inhaled. Harmful if swallowed. Extremely flammable liquid and vapor. Vapors may cause flash fire or explosion. Harmful if inhaled. May effect the brain or nervous system causing dizziness, headache or nausea. Contents Under Pressure. EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin irritation. Prolonged or repeated contact may cause skin irritation. EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing vapors or mists. High vapor concentrations are irritating to the eyes, nose, throat and lungs. EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed. Aspiration hazard if swallowed; can enter lungs and cause damage. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: May cause central nervous system disorder (e,g.,narcosis involving a loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. Overexposure to toluene in laboratory animals has been associated with liver abnormalities, kidney, lung and spleen damage. Effects in humans have included liver and cardiac abnormalities. PRIMARY ROUTE(S) OF ENTRY: SKIN ABSORPTION INHALATION EYE CONTACT Page 920 of 1235 Page 920 of 1235 Page 920 of 1235 Page 920 of 1235 ---PAGE BREAK--- I SECTION 4 - FIRST AID MEASURES I FIRST AID - EYE CONTACT: Hold eyelids apart and flush with plenty of water for at lease 15 minutes. Get medical attention. FIRST AID - SKIN CONTACT: Wash with soap and water. Get medical attention if irritation develops or persists. FIRST AID - INHALATION: If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately. FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. (Continued on Page 3) Product: 2067 830 Preparation Date: 05/11/00 Page 3 I SECTION 5 - FIRE FIGHTING MEASURES I FLASH POINT: -99 F LOWER EXPLOSIVE LIMIT: 1.0 % UPPER EXPLOSIVE LIMIT: 9.5 % AUTOIGNITION TEMPERATURE: ND EXTINGUISHING MEDIA: DRY CHEMICAL FOAM WATER FOG UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20 DEG. F. - EXTREMELY FLAMMABLE LIQUID AND VAPOR! Water spray may be ineffective. Closed containers may explode when exposed to extreme heat due to buildup of steam. Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a source of ignition and flash back. Keep containers closed. Isolate from heat, electrical equipment, sparks and open flame. Perforation of the pressurized container may cause bursting of the can. Closed containers may explode when exposed to extreme heat. SPECIAL FIREFIGHTING PROCEDURES: Evacuate area and fight fire from a safe distance. I SECTION 6 - ACCIDENTAL RELEASE MEASURES I STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Evacuate the area, remove all sources of ignition and ventilate well. Contain spilled liquid with sand or earth. DO NOT use combustible materials such as Page 921 of 1235 Page 921 of 1235 Page 921 of 1235 Page 921 of 1235 ---PAGE BREAK--- sawdust. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. I SECTION 7 - HANDLING AND STORAGE I HANDLING: Wash thoroughly after handling. Wash hands before eating. Use only in a well-ventilated area. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing vapor or mist. STORAGE: Keep containers closed. Isolate from heat, electrical equipment, sparks and open flame. Do not store above 120 degrees F. Store large quantities in buildings designed and protected for storage of NFPA Class I flammable liquids. Contents under pressure. Do not expose to heat or store above 120 degrees F. (Continued on Page 4) Product: 2067 830 Preparation Date: 05/11/00 Page 4 I SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION I ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use explosion-proof ventilation equipment. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation. RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. Page 922 of 1235 Page 922 of 1235 Page 922 of 1235 Page 922 of 1235 ---PAGE BREAK--- SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection. EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids. OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application. HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. I SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES I BOILING RANGE : -34 - 284 F VAPOR DENSITY : Is heavier than air ODOR : SOLVENT ODOR THRESHOLD : ND APPEARANCE : LIQUID EVAPORATION RATE: Is faster than Ether SOLUBILITY IN H2O : SLIGHT FREEZE POINT : ND SPECIFIC GRAVITY: 1.2878 VAPOR PRESSURE : ND pH @ 0.0 % : ND PHYSICAL STATE : LIQUID VISCOSITY : ND COEFFICIENT OF WATER/OIL DISTRIBUTION: ND (See Section 16 for abbreviation legend) I SECTION 10 - STABILITY AND REACTIVITY I CONDITIONS TO AVOID: Avoid temperatures above 120 degrees F. Avoid all possible sources of ignition. (Continued on Page 5) Product: 2067 830 Preparation Date: 05/11/00 Page 5 I SECTION 10 - STABILITY AND REACTIVITY I INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies. HAZARDOUS DECOMPOSITION PRODUCTS: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition it emits acrid smoke and irritating fumes. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. Page 923 of 1235 Page 923 of 1235 Page 923 of 1235 Page 923 of 1235 ---PAGE BREAK--- STABILITY: This product is stable under normal storage conditions. I SECTION 11 - TOXICOLOGICAL PROPERTIES I COMPONENT TOXICOLOGICAL INFORMATION: CHEMICAL NAME LD50 LC50 LIQUIFIED PETROLEUM GAS N.E. N.E. XYLENE RAT 4300MG/KG RAT 5000PPM 4HR MAGNESIUM SILICATE HYDRATE-TALC None None TOLUENE RAT 5000MG/KG MOUSE 5320PPM 8HR RAT 3500MG/KG N.A. I SECTION 12 - ECOLOGICAL INFORMATION I ECOLOGICAL INFORMATION: Product is a mixture of listed components. According to our raw material suppliers, all components are listed on the TSCA inventory as required or meet the polymer exemption as defined in Section 5.5.2 of the Toxic Substances Control Act. I SECTION 13 - DISPOSAL CONSIDERATIONS I DISPOSAL METHOD: Dispose of material in accordance to local, state and federal regulations and ordinances. Do not allow to enter storm drains or sewer systems. I SECTION 14 - TRANSPORTATION INFORMATION I DOT PROPER SHIPPING NAME: AEROSOL DOT TECHNICAL NAME: DOT HAZARD CLASS: 2.1 HAZARD SUBCLASS: .1 (Continued on Page 6) Product: 2067 830 Preparation Date: 05/11/00 Page 6 I SECTION 14 - TRANSPORTATION INFORMATION I Page 924 of 1235 Page 924 of 1235 Page 924 of 1235 Page 924 of 1235 ---PAGE BREAK--- DOT UN/NA NUMBER: UN1950 PACKING GROUP: RESP. GUIDE PAGE: 126 I SECTION 15 - REGULATORY INFORMATION I U.S. FEDERAL REGULATIONS: AS FOLLOWS - OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) CERCLA - SARA HAZARD CATEGORY: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER WT/WT % IS LESS THAN XYLENE 1330-20-7 20.0 % TOLUENE 108-88-3 15.0 % 100-41-4 5.0 % U.S. STATE REGULATIONS: AS FOLLOWS - NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components in this product: CHEMICAL NAME CAS NUMBER NATURAL IRON OXIDE ROUGE/METELLIC BROWNS 1332-37-2 RIGHT-TO-KNOW: The following non-hazardous ingredients are present in the product at greater than CHEMICAL NAME CAS NUMBER NATURAL IRON OXIDE ROUGE/METELLIC BROWNS 1332-37-2 CALIFORNIA PROPOSITION 65: Page 925 of 1235 Page 925 of 1235 Page 925 of 1235 Page 925 of 1235 ---PAGE BREAK--- (Continued on Page 7) Product: 2067 830 Preparation Date: 05/11/00 Page 7 I SECTION 15 - REGULATORY INFORMATION I WARNING: The chemical(s) noted below and contained in this product, are known to the state of California to cause cancer, birth defects or other reproductive harm: CHEMICAL NAME CAS NUMBER TOLUENE 108-88-3 INTERNATIONAL REGULATIONS: AS FOLLOWS - CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: A B5 D2A D2B I SECTION 16 - OTHER INFORMATION I HMIS RATINGS - HEALTH: 2* FLAMMABILITY: 4 REACTIVITY: 0 PREVIOUS MSDS REVISION DATE: 04/27/00 REASON FOR REVISION: RESIN CHANGE. LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined : No Information. Page 926 of 1235 Page 926 of 1235 Page 926 of 1235 Page 926 of 1235 ---PAGE BREAK--- The information contained on this MSDS has been checked and should be accurate. However, it is the responsibility of the user to comply with all Federal, State, and Local laws and regulations. Page 927 of 1235 Page 927 of 1235 Page 927 of 1235 Page 927 of 1235 ---PAGE BREAK--- Page 1 of 4 MATERIAL SAFETY DATA SHEET MSDS W-121 REVISION 10 THE DIAL CORPORATION CENTER FOR INNOVATION MEDICAL EMERGENCIES: 1-[PHONE REDACTED] 15101 NORTH SCOTTSDALE ROAD CHEMTREC: 1-[PHONE REDACTED] (24 Hours Daily) SCOTTSDALE, ARIZONA 85254 OTHER INFORMATION: 1-[PHONE REDACTED] SUBSTANCE IDENTIFICATION SUBSTANCE: SOLID AIR FRESHENER TRADE NAMES/SYNONYMS: RENUZIT ADJUSTABLE SOLID AIR FRESHENER (RETAIL): SUPER ODOR KILLER, POWDER ROOM, COUNTRY FIELDS, AFTER THE RAIN, FRESH CUT FLOWERS, VANILLA, APPLE CINNAMON, RASPBERRY, LAVANDA, ROSA, GARDEN FRESH, FESTIVE PINE, FESTIVE POTPOURRI, CITRUS SUNBURST, WILD ORCHID, SIMMERING SPICE, GLACIER SPRINGS, HAZELNUT VANILLA, SPRING ROSE, HEATHER MIST CHEMICAL FAMILY: Mixture I.D. NUMBERS: Super Odor Killer (915002, 915199), Powder Room (915042, 915200), Country Fields (915043, 915201), After the Rain (915044, 915202), Fresh Cut Flowers (915045, 915203), Vanilla (915046), Apple & Cinnamon (915056, 915209), Raspberry (915047, 915204), Lavanda (915048), Rosa (915049), Garden Fresh (915053), Festive Pine (915051, 915205), Festive Potpourri (915052, 915206), Citrus Sunburst (915054, 915207), Wild Orchid (915055, 915208), Simmering Spice (915079, 915211), Glacier Springs (915078, 915210), Hazelnut Vanilla (915147, 915148, 915212), Spring Rose (915149, 915213), Heather Mist (915177, 915214) NFPA RATINGS (Scale 0-4, where 4=high degree of hazard): HEALTH=1 FLAMMABILITY=0 REACTIVITY=0 HMIS RATINGS (Scale 0-4, where 4=severe hazard): HEALTH=1 FLAMMABILITY=0 REACTIVITY=0 This product is labeled in accordance with regulations administered by the Consumer Product Safety Commission. The use pattern and exposure in the workplace are generally not consistent with those experienced by consumers. The requirements of the Occupational Safety and Health Administration applicable to this Material Safety Data Sheet differ from the requirements of the CPSC and as a result, this MSDS may contain additional health hazard information not pertinent to consumer use and not found on the product label. HAZARDOUS INGREDIENT INFORMATION COMPONENT: CONCENTRATED PERFUME OIL CAS# Proprietary Mixture Carcinogen status of components: Not listed as carcinogenic by NTP, IARC, or OSHA. PHYSICAL AND CHEMICAL DATA DESCRIPTION: Colored, fragranced gel. SPECIFIC GRAVITY (Water = Not determined. pH: 6.0-8.0. SOLUBILITY IN WATER Miscible. VISCOSITY: 200 mPa's @ 168-172 °F (RVF, Spindle 20 rpm) Page 928 of 1235 Page 928 of 1235 Page 928 of 1235 Page 928 of 1235 ---PAGE BREAK--- MSDS W-121 (Rev. 10) Page 2 of 4 FIRE AND EXPLOSION DATA FLASH POINT: Not applicable. FIRE AND EXPLOSION HAZARD - Negligible fire hazard when exposed to heat or flames. FIRE FIGHTING MEDIA - Use water, dry alcohol-type or all-purpose foam, dry chemical, carbon dioxide. FIRE FIGHTING - Move containers from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Avoid breathing vapors; keep upwind. HEALTH HAZARD DATA NOTE: The acute health effects described below are those which could potentially occur for the finished product. They are based on the toxicology information available for the finished product and/or each hazardous ingredient, and are consistent with the product type and the likelihood of a specific route of exposure. Known chronic health effects related to exposure to a specific ingredient are indicated. ACUTE HEALTH EFFECTS: INHALATION: Vapors may cause irritation of the nose, throat, and respiratory tract. Breathing high vapor concentrations may produce anesthetic effects, nausea, dizziness, headache. SKIN CONTACT: Repeated or prolonged excessive exposure may cause irritation and allergic contact dermatitis. EYE CONTACT: May cause irritation. INGESTION: Not an anticipated route of exposure given the nature of the finished product. Nonetheless, ingestion may cause nausea, vomiting, abdominal pain, diarrhea, and lethargy. Ingestion of large quantities may be harmful. SUBCHRONIC/CHRONIC HEALTH EFFECTS: None known. MEDICAL CONDITIONS GENERALLY RECOGNIZED AS BEING AGGRAVATED BY EXPOSURE: Persons with pre- existing respiratory and skin conditions. EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove from exposure area to fresh air immediately. Keep affected person warm and at rest. Treat and supportively. Contact physician or local poison control center. If breathing has stopped, give artificial respiration, and get medical attention immediately. SKIN CONTACT: Rinse affected area with mild soap and plenty of water until no evidence of product remains. Get medical attention if irritation persists. EYE CONTACT: Immediately rinse eyes with plenty of water, occasionally lifting upper and lower lids, until no evidence of product remains. Get medical attention if pain or irritation persist. INGESTION: Treat and supportively. Maintain airway and respiration. If vomiting occurs, keep head below hips to prevent aspiration. Dilution by rinsing the mouth and giving water or milk to drink is generally recommended. If unconscious, the victim should not be given anything to drink. Contact physician or local poison control center. Page 929 of 1235 Page 929 of 1235 Page 929 of 1235 Page 929 of 1235 ---PAGE BREAK--- MSDS W-121 (Rev. 10) Page 3 of 4 REACTIVITY REACTIVITY - Stable under normal temperatures and pressures. INCOMPATIBILITIES: Strong oxidizers, alkalis, acids. DECOMPOSITION - Thermal decomposition may produce irritating smoke, carbon monoxide, and carbon dioxide. POLYMERIZATION - Hazardous polymerization has not been reported to occur under normal temperatures and pressures. STORAGE AND DISPOSAL Store in a well-ventilated area, away from incompatible substances and excessive heat. Observe all federal, state and local regulations when storing or disposing of this substance. CONDITIONS TO AVOID Avoid contact with incompatible substances and excessive heat. SPILL AND LEAK PROCEDURES OCCUPATIONAL SPILL - Sweep or scoop up and place into containers for later disposal. Keep unnecessary people away. OCCUPATIONAL PROTECTIVE EQUIPMENT VENTILATION: - Provide general dilution ventilation to keep exposure to vapors as low as possible. RESPIRATOR - If respiratory protection is required, it must be based on the contamination levels found in the workplace, must not exceed the working limits of the respirator and be jointly approved by the National Institute for Occupational Safety and Health and the Mine Safety and Health Administration (NIOSH-MSHA). FOR FIRE FIGHTING AND OTHER IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONDITIONS - Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive- pressure mode. Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure- demand or other positive-pressure mode. CLOTHING - Protective clothing is required where repeated or prolonged skin contact may occur. GLOVES - Chemical-resistant gloves are required where repeated or prolonged skin contact may occur. EYE PROTECTION - Safety glasses are required in situations where eye contact may potentially occur. REGULATORY INFORMATION DOT FLAMMABILITY CLASSIFICATION: Not applicable. EPA - SARA TITLE III SECTION 313: Not applicable - Consumer product. Page 930 of 1235 Page 930 of 1235 Page 930 of 1235 Page 930 of 1235 ---PAGE BREAK--- MSDS W-121 (Rev. 10) Page 4 of 4 TSCA: All components of this product are listed or are exempted or excluded from listing on the U.S. Toxic Substances Control Act (TSCA) chemical substance inventory. The information contained herein is provided in good faith and is believed to be correct as of the date hereof. However, the Dial Corporation makes no representation as to the comprehensiveness or accuracy of the information. It is expected that individuals receiving the information will exercise their independent judgment in determining its appropriateness for a particular purpose. Accordingly, the Dial Corporation will not be responsible for damages of any kind resulting from the use of or reliance upon such information. No representations, or warranties, either expressed or implied of merchantability, fitness for a particular purpose or of any other nature are made hereunder with respect to the information set forth herein or to the product to which the information refers. MSDS CREATION DATE: 10/25/88 SUPERCEDES: Rev. 9; 11/02/00 REVISION DATE: 01/30/01 REVISION: Updated Substance Identification. Page 931 of 1235 Page 931 of 1235 Page 931 of 1235 Page 931 of 1235 ---PAGE BREAK--- Material Safety Data Sheet NFPA HMIS PPE Transport Symbol Issuing Date 02.01.2008 Revision Date 02.01.2008 Revision Number 1 Page 1 / 7 1. PRODUCT AND COMPANY IDENTIFICATION Product Name Rust Stain Remover Recommended Use Rust Remover Supplier Address Whink Products Company PO Box 230 1901 15th Ave., Eldora, IA, 50627 United States of America Phone: [PHONE REDACTED] Fax: [PHONE REDACTED] Emergency Phone: [PHONE REDACTED] CHEMTREC: [PHONE REDACTED] Company Emergency Phone Number [PHONE REDACTED] 2. HAZARDS IDENTIFICATION Emergency Overview Very toxic by inhalation, in contact with skin and if swallowed. Causes severe burn. Inhalation of vapors in high concentration may cause shortness of breath (lung oedema). Ingestion causes burns of the upper digestive and respiratory tracts. Will penetrate skin and attack underlying tissues and bone. Appearance Clear Physical State Liquid Odor Acrid Potential Health Effects Principle Routes of Exposure Eyes, Skin, Inhalation and Ingestion Acute Toxicity Eyes Avoid contact with eyes. Risk of serious damage to eyes. May cause burns. Severely irritating to eyes. Seek Medical Attention. Skin Causes serious injury to skin, which may not be immediately painful or visible. Inhalation Causes respiratory irritation. may be delayed for several hours. Ingestion Ingestion is toxic and can causes severe mouth, throat and stomach burns. Seek medical attention. Environmental Hazard See Section 12 for additional Ecological Information Page 932 of 1235 Page 932 of 1235 Page 932 of 1235 Page 932 of 1235 ---PAGE BREAK--- Rust Stain Remover Revision Date 02012008 Page 2 / 7 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Water 7732-18-5 90 - 100 Hydrofluoric Acid (Hydrogen Fluoride) 7664-39-3 1.50 – 3.5 Denatonium Benzoate 3734-33-6 0.01 – 0.10 4. FIRST AID MEASURES General Advice Call [PHONE REDACTED] or emergency medical service. Remove and isolate contaminated clothing and shoes. Eye Contact In case of contact with substance, remove contacts if needed, immediately flush eyes with running water for at least 20 minutes. Get medical attention immediately. Skin Contact Avoid spreading material on unaffected skin. Wash off immediately with plenty of water for 15 minutes. Treat with Calcium gluconate or with a over-the-counter anti-acid containing Calcium or Magnesium. Seek Medical Attention Immediately! Inhalation Move injured party to fresh air. Apply artificial respiration if injured party is not breathing. Administer oxygen if breathing is difficult. Get Medical Attention Immediately! Ingestion Do not induce vomiting. Rinse mouth. Drink large amounts of water. Several glasses of milk or several ounces of milk of magnesia may be given for soothing. Take Injured Partyto a Doctor Immediately! 5. FIRE-FIGHTING MEASURES Flammable Properties Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Produces Hydrogen Fluoride Gas or Hydrogen Gas upon heating. Containers may rupture due to gas build-up when heated. Reaction with certain metals generates flammable and potentially explosive hydrogen gas. Flash Point Not Flammable. Suitable Extinguishing Media Use water or suitable agent for fires. Do not use solid water streams. Acid reacts with water and can splatter acid onto personnel. Care should be exercised when water is used to dilute acid. Will react with water and generate heat and fumes. Hazardous Combustion Products Hydrogen Gas and/or Hydrogen Fluoride Gas Explosion Data Sensitivity to mechanical impact Not sensitive Sensitivity to static discharge Not sensitive Protective Equipment and Precautions for Firefighters In the event of a fire wear full protective clothing and NIOSH-approved self- contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Wear full protective clothing. National Fire Protection Association (NFPA) Ratings: This information is intended solely for the use of individuals trained in the NFPA system. Health Hazard 3 Flammability 0 Stability 1 Physical and Chemical Hazards W Other: Acid/ Toxic Page 933 of 1235 Page 933 of 1235 Page 933 of 1235 Page 933 of 1235 ---PAGE BREAK--- Rust Stain Remover Revision Date 02012008 Page 3 / 7 6. ACCIDENTAL RELEASE MEASURES Methods for Containment Always wear Personal Protective Equipment. Use sand, or pigs to dike area. Keep out of sewer Methods for Cleaning Up Carefully neutralize with caustic soda, lime or other alkaline material. Put into approved disposal container. Other Information Do not use metal or glass containers. Do not use metal tools for cleaning spills. 7. HANDLING AND STORAGE Handling Always wear recommended Personal Protective Equipment. Do not breathe vapor or mist. Use only with adequate ventilation. Avoid contact with skin, eyes and clothing. Do not add water to product. Care should be taken when adding to water to prevent splattering and heat buildup. Storage Store only in the original container. Store in cool, well-ventilated area. Do not store in metal containers. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines This product does contain a hazardous material with occupational exposure limits established by the region specific regulatory bodies. Engineering Measures Showers – quick-drench Eyewash stations Ventilation systems – sufficient to reduce vapor and acid mists below permissible TLV levels. Personal Protective Equipment Eye/Face Protection fitting safety goggles. Face-shield. Skin and Body Protection Wear Chemical Resistant Gloves. Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations Hygiene Measures When using, do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colorless Odor Acrid / Sharp Pungent Odor Threshold No information available Physical State Liquid pH As is < 1 Autoignition Temperature No information available. Flash Point No information available. Boiling Point/Range 212oF Decomposition Temperature No information available. Explosion Limits No information available. Melting Point/Range No information available. Solubility Water Flammability Limits in Air No information available. Vapor Pressure No data available. Water Solubility Complete (Weight%) VOC Content Not applicable. Evaporation Rate < 1 (Compared to: Ether) Partition Coefficient (n-octanol/water) No data available. Vapor Density No data available. Page 934 of 1235 Page 934 of 1235 Page 934 of 1235 Page 934 of 1235 ---PAGE BREAK--- Rust Stain Remover Revision Date 02012008 Page 4 / 7 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions Incompatible Products Glass, concrete and other silicone materials. Carbonates, sulfides and cyanides (yields toxic gases). Alkalies and oxides (cause violent exothermic reactions). Common metals (yield Hydrogen Gas, fire and explosive reactive hazard). Corrosive to many materials (includes leather and many organics). Water added to product yields heat and violent reaction. Conditions to Avoid Moisture, humidity, heat, flame, ignition sources and incompatibles. Hazardous Decomposition Products Emits sulfur oxide gases under fire conditions and in contact with water. Hazardous Reactions Reacts violently with water, metals, alkalies, oxides, carbonates, sulfides, cyanides, glass, concrete and other silicones. Hazardous Polymerization Hazardous polymerization will not occur. 11. TOXICOLOGICAL INFORMATION Signs and of Overexposure Eye, Mouth, Nasal and Mucous Membrane irritation. Burning of the skin, mottling of teeth and bones. Acute Effects Eyes May cause severe conjunctiva irritation and corneal damage. May cause burns. Skin 2% solution of hydrofluoric acid was corrosive to rabbit skin with 1 hour exposure, but not with 1 minute. Inhalation May cause irritation of respiratory tract and mucous membranes. Ingestion Harmful or fatal if swallowed. Ingestion may cause burns and irritation to gastrointestinal track. Target Organ Effects Bone and joints Chronic Toxicity Prolonged exposure can cause bone and joint changes in humans (Fluorosis). Carcinogenicity Contains no ingredient listed as a carcinogen. Acute Toxicity Values Oral LD50 (Rat) = Not Determined Dermal LD50 (Rabbit) = Not Determined Inhalation LC50 (Rat) = Not Determined 12. ECOLOGICAL INFORMATION Ecotoxicity The environmental impact of this product has not been fully investigated Page 935 of 1235 Page 935 of 1235 Page 935 of 1235 Page 935 of 1235 ---PAGE BREAK--- Rust Stain Remover Revision Date 02012008 Page 5 / 7 13. DISPOSAL CONSIDERATIONS Waste Disposal Method This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements Contaminated Packaging Dispose of in accordance with local regulations California Hazardous Waste Codes 791 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status Hydrofluoric Acid (Hydrogen Fluoride) Corrosive 14. TRANSPORT INFORMATION DOT Proper Shipping Name Consumer commodity Hazard Class ORM-D Description Consumer commodity, ORM-D TDG Proper Shipping Name Hydrofluoric Acid, with 60% strength Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, II MEX Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II ICAO UN-No UN1790 Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Packing Group II Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II IATA UN-No UN1790 Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Packing Group II ERG Code 8L Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II IMDG/IMO Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Page 936 of 1235 Page 936 of 1235 Page 936 of 1235 Page 936 of 1235 ---PAGE BREAK--- Rust Stain Remover Revision Date 02012008 Page 6 / 7 14. TRANSPORT INFORMATION Subsidiary Class Toxic UN-No UN1790 Packing Group II EmS No. 8.03 Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II RID Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Classification Code 2XE Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1,II, RID ADR/RID-Labels 8, 6.1 ADR Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Classification Code 2XE Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, II ADN Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Packing Group II Classification Code Unknown Special Provisions 274 Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, II Hazard Labels 8 Limited Quantity Unknown 15. REGULATORY INFORMATION International Inventories TSCA Hydrofluoric Acid, Aqueous is listed U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does contain chemicals (hydrogen fluoride), which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard Yes Page 937 of 1235 Page 937 of 1235 Page 937 of 1235 Page 937 of 1235 ---PAGE BREAK--- Rust Stain Remover Revision Date 02012008 Page 7 / 7 15. REGULATORY INFORMATION Cont. Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990 CERCLA This material, as supplied, does contain a substance regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). Hydrogen Fluoride (Hydrofluoric Acid) 100 lbs. There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name Massachusetts New Jersey Illinois Rhode Island Hydrofluoric Acid NA NA NA NA NA International Regulations See Specific Country for Regulations required. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class E Corrosive material D1A Toxic materials 16. OTHER INFORMATION Revision Date 02.01.2008 Revision Note First Revision Prepared By: Manufacturer’s Technical Services Department Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of MSDS Page 938 of 1235 Page 938 of 1235 Page 938 of 1235 Page 938 of 1235 ---PAGE BREAK--- Material Safety Data Sheet NFPA HMIS PPE Transport Symbol Issuing Date 10/06/2008 Revision Date 10/06/2008 Revision Number 2 Page 1 / 8 1. PRODUCT AND COMPANY IDENTIFICATION Product Name Rust Stain Remover Recommended Use Rust Remover Supplier Address Whink Products Company PO Box 230 1901 15th Ave., Eldora, IA, 50627 United States of America Phone: [PHONE REDACTED] Fax: [PHONE REDACTED] Emergency Phone: [PHONE REDACTED] CHEMTREC: [PHONE REDACTED] Company Emergency Phone Number [PHONE REDACTED] 2. HAZARDS IDENTIFICATION Emergency Overview Very toxic by inhalation, in contact with skin and if swallowed. Causes severe burns. Inhalation of vapors in high concentration may cause shortness of breath (lung edema). Ingestion causes burns of the upper digestive and respiratory tracts. Will penetrate skin and attack underlying tissues and bone. Appearance Clear Physical State Liquid Odor Acrid Potential Health Effects Principle Routes of Exposure Eyes, Skin, Inhalation and Ingestion Acute Toxicity Eyes Avoid contact with eyes. Risk of serious damage to eyes. May cause burns. Severely irritating to eyes. Seek Medical Attention. Skin Causes serious injury to skin, which may not be immediately painful or visible. Inhalation Causes respiratory irritation. may be delayed for several hours. Ingestion Ingestion is toxic and can causes severe mouth, throat and stomach burns. Seek medical attention. Environmental Hazard See Section 12 for additional Ecological Information Page 939 of 1235 Page 939 of 1235 Page 939 of 1235 Page 939 of 1235 ---PAGE BREAK--- Rust Stain Remover Revision Date 10/06/2008 Page 2 / 8 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Water 7732-18-5 90 - 100 Hydrofluoric Acid (Hydrogen Fluoride) 7664-39-3 1.50 – 3.5 Denatonium Benzoate 3734-33-6 0.01 – 0.10 4. FIRST AID MEASURES General Advice Call [PHONE REDACTED] or emergency medical service. Remove and isolate contaminated clothing and shoes. Eye Contact In case of contact with eyes, remove contacts if needed, immediately flush eyes with running water for at least 20 minutes. Get medical attention immediately. Skin Contact Avoid spreading material on unaffected skin. Wash off immediately with plenty of water for 15 minutes. Treat with Calcium Gluconate or with a over-the-counter anti-acid containing Calcium or Magnesium. Seek Medical Attention Immediately! Inhalation Move injured party to fresh air. Apply artificial respiration if injured party is not breathing. Administer oxygen if breathing is difficult. Get Medical Attention Immediately! Ingestion Do not induce vomiting. Rinse mouth. Drink large amounts of water. Several glasses of milk or several ounces of milk of magnesia may be given for soothing. Take Injured Party to a Doctor Immediately! 5. FIRE-FIGHTING MEASURES Flammable Properties Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Produces Hydrogen Fluoride Gas or Hydrogen Gas upon heating. Containers may rupture due to gas build-up when heated. Reaction with certain metals generates flammable and potentially explosive hydrogen gas. Flash Point Not Flammable. Suitable Extinguishing Media Use water or suitable agent for fires. Do not use solid water streams. Acid reacts with water and can splatter acid onto personnel. Care should be exercised when water is used to dilute acid. Will react with water and generate heat and fumes. Hazardous Combustion Products Hydrogen Gas and/or Hydrogen Fluoride Gas Explosion Data Sensitivity to mechanical impact Not sensitive Sensitivity to static discharge Not sensitive Protective Equipment and Precautions for Firefighters In the event of a fire wear full protective clothing and NIOSH-approved self- contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Wear full protective clothing. National Fire Protection Association (NFPA) Ratings: This information is intended solely for the use of individuals trained in the NFPA system. Health Hazard 3 Flammability 0 Stability 1 Physical and Chemical Hazards W Other: Acid/ Toxic 6. ACCIDENTAL RELEASE MEASURES Methods for Containment Always wear Personal Protective Equipment. Use sand, or pigs to dike area. Keep out of sewer Page 940 of 1235 Page 940 of 1235 Page 940 of 1235 Page 940 of 1235 ---PAGE BREAK--- Rust Stain Remover Revision Date 10/06/2008 Page 3 / 8 Methods for Cleaning Up Carefully neutralize with caustic soda, lime or other alkaline material. Put into approved disposal container. Other Information Do not use metal or glass containers. Do not use metal tools for cleaning spills. 7. HANDLING AND STORAGE Handling Always wear recommended Personal Protective Equipment. Do not breathe vapor or mist. Use only with adequate ventilation. Avoid contact with skin, eyes and clothing. Do not add water to product. Care should be taken when adding to water to prevent splattering and heat buildup. Storage Store only in the original container. Store in cool, well-ventilated area. Do not store in metal containers. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines This product does contain a hazardous material with occupational exposure limits established by the region specific regulatory bodies. Engineering Measures Showers – quick-drench Eyewash stations Ventilation systems – sufficient to reduce vapor and acid mists below permissible TLV levels. Personal Protective Equipment Eye/Face Protection fitting safety goggles. Face-shield. Skin and Body Protection Wear Chemical Resistant Gloves. Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations Hygiene Measures When using, do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing. This Space Intentionally Left Blank Page 941 of 1235 Page 941 of 1235 Page 941 of 1235 Page 941 of 1235 ---PAGE BREAK--- Rust Stain Remover Revision Date 10/06/2008 Page 4 / 8 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colorless Odor Acrid / Sharp Pungent Odor Threshold No information available Physical State Liquid pH As is < 1 Autoignition Temperature No information available. Flash Point No information available. Boiling Point/Range 212oF Decomposition Temperature No information available. Explosion Limits No information available. Melting Point/Range No information available. Solubility Water Fl ammability Limits in Air No information available. Vapor Pressure No data available. Water Solubility Complete (Weight%) VOC Content Not applicable. Evaporation Rate < 1 (Compared to: Ether) P artition Coefficient (n-octanol/water) No data available. Vapor Density No data available. 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions Incompatible Products Glass, concrete and other silicone materials. Carbonates, sulfides and cyanides (yields toxic gases). Alkalies and oxides (cause violent exothermic reactions). Common metals (yield Hydrogen Gas, fire and explosive reactive hazard). Corrosive to many materials (includes leather and many organics). Water added to product yields heat and violent reaction. Conditions to Avoid Moisture, humidity, heat, flame, ignition sources and incompatibles. Hazardous Decomposition Products Emits sulfur oxide gases under fire conditions and in contact with water. Hazardous Reactions Reacts violently with water, metals, alkalies, oxides, carbonates, sulfides, cyanides, glass, concrete and other silicones. Hazardous Polymerization Hazardous polymerization will not occur. 11. TOXICOLOGICAL INFORMATION Signs and of Overexposure Eye, Mouth, Nasal and Mucous Membrane irritation. Burning of the skin, mottling of teeth and bones. Acute Effects Eyes May cause severe conjunctiva irritation and corneal damage. May cause burns. Skin 2% solution of hydrofluoric acid was corrosive to rabbit skin with 1 hour exposure, but not with 1 minute. Inhalation May cause irritation of respiratory tract and mucous membranes. Ingestion Harmful or fatal if swallowed. Ingestion may cause burns and irritation to gastrointestinal tract. Target Organ Effects Bone and joints Chronic Toxicity Prolonged exposure can cause bone and joint changes in humans (Fluorosis). Carcinogenicity Contains no ingredient listed as a carcinogen. Acute Toxicity Values Oral LD50 (Rat) = Not Determined Dermal LD50 (Rabbit) = Not Determined Inhalation LC50 (Rat) = Not Determined Page 942 of 1235 Page 942 of 1235 Page 942 of 1235 Page 942 of 1235 ---PAGE BREAK--- Rust Stain Remover Revision Date 10/06/2008 Page 5 / 8 12. ECOLOGICAL INFORMATION Ecotoxicity The environmental impact of this product has not been fully investigated 13. DISPOSAL CONSIDERATIONS Waste Disposal Method This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements Contaminated Packaging Dispose of in accordance with local regulations California Hazardous Waste Codes 791 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status Hydrofluoric Acid (Hydrogen Fluoride) Corrosive 14. TRANSPORT INFORMATION DOT Proper Shipping Name Consumer commodity Hazard Class ORM-D Description Consumer commodity, ORM-D TDG Proper Shipping Name Hydrofluoric Acid, with 60% strength Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, II MEX Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II ICAO UN-No UN1790 Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Packing Group II Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II IATA UN-No UN1790 Proper Shipping Name Hydrofluoric Acid, with 60% strength. Page 943 of 1235 Page 943 of 1235 Page 943 of 1235 Page 943 of 1235 ---PAGE BREAK--- Rust Stain Remover Revision Date 10/06/2008 Page 6 / 8 14. TRANSPORT INFORMATION Hazard Class 8, 6.1 Packing Group II ERG Code 8L Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II IMDG/IMO Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Subsidiary Class Toxic UN-No UN1790 Packing Group II EmS No. 8.03 Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II RID Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Classification Code 2XE Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1,II, RID ADR/RID-Labels 8, 6.1 ADR Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Classification Code 2XE Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, II ADN Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Packing Group II Classification Code Unknown Special Provisions 274 Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, II Hazard Labels 8 Limited Quantity Unknown This Space Intentionally Left Blank Page 944 of 1235 Page 944 of 1235 Page 944 of 1235 Page 944 of 1235 ---PAGE BREAK--- Rust Stain Remover Revision Date 10/06/2008 Page 7 / 8 15. REGULATORY INFORMATION International Inventories TSCA Hydrofluoric Acid, Aqueous is listed U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does contain chemicals (hydrogen fluoride), which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard Yes 15. REGULATORY INFORMATION Cont. Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990 CERCLA This material, as supplied, does contain a substance regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). Hydrogen Fluoride (Hydrofluoric Acid) 100 lbs. There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material This Space Intentionally Left Blank Page 945 of 1235 Page 945 of 1235 Page 945 of 1235 Page 945 of 1235 ---PAGE BREAK--- Rust Stain Remover Revision Date 10/06/2008 Page 8 / 8 U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name Massachusetts New Jersey Illinois Rhode Island Hydrofluoric Acid NA NA NA NA NA International Regulations See Specific Country for Regulations required. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class E Corrosive material F Dangerously reactive material D1A Toxic materials 16. OTHER INFORMATION Revision Date 10/06/2008 Revision Note Second Revision Prepared By: Manufacturer’s Technical Services Department Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of MSDS This Space Intentionally Left Blank Page 946 of 1235 Page 946 of 1235 Page 946 of 1235 Page 946 of 1235 ---PAGE BREAK--- Page 947 of 1235 Page 947 of 1235 Page 947 of 1235 Page 947 of 1235 ---PAGE BREAK--- Page 948 of 1235 Page 948 of 1235 Page 948 of 1235 Page 948 of 1235 ---PAGE BREAK--- Page 949 of 1235 Page 949 of 1235 Page 949 of 1235 Page 949 of 1235 ---PAGE BREAK--- Page 950 of 1235 Page 950 of 1235 Page 950 of 1235 Page 950 of 1235 ---PAGE BREAK--- Page 951 of 1235 Page 951 of 1235 Page 951 of 1235 Page 951 of 1235 ---PAGE BREAK--- Page 952 of 1235 Page 952 of 1235 Page 952 of 1235 Page 952 of 1235 ---PAGE BREAK--- Material Safety Data Sheet NFPA HMIS PPE Transport Symbol Revision Date 04/03/2012 Revision Number 3 Page 1 / 8 1. PRODUCT AND COMPANY IDENTIFICATION Product Name Rust Stain Remover Recommended Use Rust Remover Supplier Address Whink Products Company PO Box 230 1901 15th Ave., Eldora, IA, 50627 United States of America Phone: [PHONE REDACTED] Fax: [PHONE REDACTED] Emergency Phone: [PHONE REDACTED] CHEMTREC: [PHONE REDACTED] Company Emergency Phone Number [PHONE REDACTED] 2. HAZARDS IDENTIFICATION Emergency Overview Very toxic by inhalation, in contact with skin and if swallowed. Causes severe burns. Inhalation of vapors in high concentration may cause shortness of breath (lung edema). Ingestion causes burns of the upper digestive and respiratory tracts. Will penetrate skin and attack underlying tissues and bone. Appearance Clear Physical State Liquid Odor Acrid Potential Health Effects Principle Routes of Exposure Eyes, Skin, Inhalation and Ingestion Acute Toxicity Eyes Avoid contact with eyes. Risk of serious damage to eyes. May cause burns. Severely irritating to eyes. Seek Medical Attention. Skin Causes serious injury to skin, which may not be immediately painful or visible. Inhalation Causes respiratory irritation. may be delayed for several hours. Ingestion Ingestion is toxic and can causes severe mouth, throat and stomach burns. Seek medical attention. Environmental Hazard See Section 12 for additional Ecological Information Page 953 of 1235 Page 953 of 1235 Page 953 of 1235 Page 953 of 1235 ---PAGE BREAK--- Rust Stain Remover Revision Date 04/03/2012 Page 2 / 8 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Water 7732-18-5 90 - 100 Hydrofluoric Acid (Hydrogen Fluoride) 7664-39-3 1.50 – 3.5 Denatonium Benzoate 3734-33-6 0.01 – 0.10 4. FIRST AID MEASURES General Advice Call [PHONE REDACTED] or emergency medical service. Remove and isolate contaminated clothing and shoes. Eye Contact In case of contact with eyes, remove contacts if needed, immediately flush eyes with running water for at least 20 minutes. Get medical attention immediately. Skin Contact Avoid spreading material on unaffected skin. Wash off immediately with plenty of water for 15 minutes. Treat with Calcium Gluconate or with a over-the-counter anti-acid containing Calcium or Magnesium. Seek Medical Attention Immediately! Inhalation Move injured party to fresh air. Apply artificial respiration if injured party is not breathing. Administer oxygen if breathing is difficult. Get Medical Attention Immediately! Ingestion Do not induce vomiting. Rinse mouth. Drink large amounts of water. Several glasses of milk or several ounces of milk of magnesia may be given for soothing. Take Injured Party to a Doctor Immediately! 5. FIRE-FIGHTING MEASURES Flammable Properties Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Produces Hydrogen Fluoride Gas or Hydrogen Gas upon heating. Containers may rupture due to gas build-up when heated. Reaction with certain metals generates flammable and potentially explosive hydrogen gas. Flash Point Not Flammable. Suitable Extinguishing Media Use water or suitable agent for fires. Do not use solid water streams. Acid reacts with water and can splatter acid onto personnel. Care should be exercised when water is used to dilute acid. Will react with water and generate heat and fumes. Hazardous Combustion Products Hydrogen Gas and/or Hydrogen Fluoride Gas Explosion Data Sensitivity to mechanical impact Not sensitive Sensitivity to static discharge Not sensitive Protective Equipment and Precautions for Firefighters In the event of a fire wear full protective clothing and NIOSH-approved self- contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Wear full protective clothing. National Fire Protection Association (NFPA) Ratings: This information is intended solely for the use of individuals trained in the NFPA system. Health Hazard 3 Flammability 0 Stability 1 Physical and Chemical Hazards W Other: Acid/ Toxic Page 954 of 1235 Page 954 of 1235 Page 954 of 1235 Page 954 of 1235 ---PAGE BREAK--- Rust Stain Remover Revision Date 04/03/2012 Page 3 / 8 6. ACCIDENTAL RELEASE MEASURES Methods for Containment Always wear Personal Protective Equipment. Use sand, or pigs to dike area. Keep out of sewer Methods for Cleaning Up Carefully neutralize with caustic soda, lime or other alkaline material. Put into approved disposal container. Other Information Do not use metal or glass containers. Do not use metal tools for cleaning spills. 7. HANDLING AND STORAGE Handling Always wear recommended Personal Protective Equipment. Do not breathe vapor or mist. Use only with adequate ventilation. Avoid contact with skin, eyes and clothing. Do not add water to product. Care should be taken when adding to water to prevent splattering and heat buildup. Storage Store only in the original container. Store in cool, well-ventilated area. Do not store in metal containers. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines This product does contain a hazardous material with occupational exposure limits established by the region specific regulatory bodies. Engineering Measures Showers – quick-drench Eyewash stations Ventilation systems – sufficient to reduce vapor and acid mists below permissible TLV levels. Personal Protective Equipment Eye/Face Protection fitting safety goggles. Face-shield. Skin and Body Protection Wear Chemical Resistant Gloves. Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations Hygiene Measures When using, do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing. This Space Intentionally Left Blank Page 955 of 1235 Page 955 of 1235 Page 955 of 1235 Page 955 of 1235 ---PAGE BREAK--- Rust Stain Remover Revision Date 04/03/2012 Page 4 / 8 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colorless Odor Acrid / Sharp Pungent Odor Threshold No information available Physical State Liquid pH As is < 1 Autoignition Temperature No information available. Flash Point No information available. Boiling Point/Range 212 oF Decomposition Temperature No information available. Explosion Limits No information available. Melting Point/Range No information available. Solubility Water Flammability Limits in Air No information available. Vapor Pressure No data available. Water Solubility Complete (Weight%) VOC Content Not applicable. Evaporation Rate < 1 (Compared to: Ether) Partition Coefficient (n-octanol/water) No data available. Vapor Density No data available. 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions Incompatible Products Glass, concrete and other silicone materials. Carbonates, sulfides and cyanides (yields toxic gases). Alkalies and oxides (cause violent exothermic reactions). Common metals (yield Hydrogen Gas, fire and explosive reactive hazard). Corrosive to many materials (includes leather and many organics). Water added to product yields heat and violent reaction. Conditions to Avoid Moisture, humidity, heat, flame, ignition sources and incompatibles. Hazardous Decomposition Products Emits sulfur oxide gases under fire conditions and in contact with water. Hazardous Reactions Reacts violently with water, metals, alkalies, oxides, carbonates, sulfides, cyanides, glass, concrete and other silicones. Hazardous Polymerization Hazardous polymerization will not occur. 11. TOXICOLOGICAL INFORMATION Signs and of Overexposure Eye, Mouth, Nasal and Mucous Membrane irritation. Burning of the skin, mottling of teeth and bones. Acute Effects Eyes May cause severe conjunctiva irritation and corneal damage. May cause burns. Skin 2% solution of hydrofluoric acid was corrosive to rabbit skin with 1 hour exposure, but not with 1 minute. Inhalation May cause irritation of respiratory tract and mucous membranes. Ingestion Harmful or fatal if swallowed. Ingestion may cause burns and irritation to gastrointestinal tract. Target Organ Effects Bone and joints Chronic Toxicity Prolonged exposure can cause bone and joint changes in humans (Fluorosis). Carcinogenicity Contains no ingredient listed as a carcinogen. Page 956 of 1235 Page 956 of 1235 Page 956 of 1235 Page 956 of 1235 ---PAGE BREAK--- Rust Stain Remover Revision Date 04/03/2012 Page 5 / 8 Acute Toxicity Values Oral LD50 (Rat) = Not Determined Dermal LD50 (Rabbit) = Not Determined Inhalation LC50 (Rat) = Not Determined 12. ECOLOGICAL INFORMATION Ecotoxicity The environmental impact of this product has not been fully investigated 13. DISPOSAL CONSIDERATIONS Waste Disposal Method This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements Contaminated Packaging Dispose of in accordance with local regulations California Hazardous Waste Codes 791 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status Hydrofluoric Acid (Hydrogen Fluoride) Corrosive 14. TRANSPORT INFORMATION DOT Proper Shipping Name Limited Quantity Hazard Class Limited Quantity Description Limited Quantity TDG Proper Shipping Name Hydrofluoric Acid, with 60% strength Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, II MEX Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II ICAO UN-No UN1790 Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Packing Group II Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II Page 957 of 1235 Page 957 of 1235 Page 957 of 1235 Page 957 of 1235 ---PAGE BREAK--- Rust Stain Remover Revision Date 04/03/2012 Page 6 / 8 14. TRANSPORT INFORMATION IATA UN-No UN1790 Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Packing Group II ERG Code 8L Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II IMDG/IMO Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Subsidiary Class Toxic UN-No UN1790 Packing Group II EmS No. 8.03 Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, PG II RID Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Classification Code 2XE Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1,II, RID ADR/RID-Labels 8, 6.1 ADR Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 UN-No UN1790 Packing Group II Classification Code 2XE Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, II ADN Proper Shipping Name Hydrofluoric Acid, with 60% strength. Hazard Class 8, 6.1 Packing Group II Classification Code Unknown Special Provisions 274 Description UN 1790 Hydrofluoric Acid, with 60% strength (Hydrofluoric Acid 8, 6.1, II Hazard Labels 8 Limited Quantity Unknown This Space Intentionally Left Blank Page 958 of 1235 Page 958 of 1235 Page 958 of 1235 Page 958 of 1235 ---PAGE BREAK--- Rust Stain Remover Revision Date 04/03/2012 Page 7 / 8 15. REGULATORY INFORMATION International Inventories TSCA Hydrofluoric Acid, Aqueous is listed U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does contain chemicals (hydrogen fluoride), which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard Yes 15. REGULATORY INFORMATION Cont. Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990 CERCLA This material, as supplied, does contain a substance regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). Hydrogen Fluoride (Hydrofluoric Acid) 100 lbs. There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material This Space Intentionally Left Blank Page 959 of 1235 Page 959 of 1235 Page 959 of 1235 Page 959 of 1235 ---PAGE BREAK--- Rust Stain Remover Revision Date 04/03/2012 Page 8 / 8 U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name Massachusetts New Jersey Illinois Rhode Island Hydrofluoric Acid NA NA NA NA NA International Regulations See Specific Country for Regulations required. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class E Corrosive material F Dangerously reactive material D1A Toxic materials 16. OTHER INFORMATION Revision Date 04/03/2012 Revision Note Third Revision Prepared By: Manufacturer’s Technical Services Department Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of MSDS This Space Intentionally Left Blank Page 960 of 1235 Page 960 of 1235 Page 960 of 1235 Page 960 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 2.0 Print Date 08/26/2011 Revision Date 06/27/2011 MSDS Number 350000011783 1/8 1. PRODUCT AND COMPANY IDENTIFICATION Product information Trade name : SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Use of the Substance/Mixture : Floor Polish/Cleaner Company : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236 Emergency telephone number : 24 Hour Transport & Medical Emergency Phone (866) 231- 5406 24 Hour International Emergency Phone (952) 852-4647 2. HAZARDS IDENTIFICATION Emergency Overview Appearance / Odor : clear yellow / liquid / solvent-like Immediate Concerns : Danger COMBUSTIBLE: HARMFUL OR FATAL IF SWALLOWED. Avoid contact with skin, eyes and clothing. Keep away from heat, sparks and flame. Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion. Eyes : May cause: Mild eye irritation Skin : Prolonged or repeated contact may dry skin and cause irritation. Inhalation : Excessive exposures may affect human health, as follows: May cause nose, throat, and lung irritation. Inhalation may cause central nervous system effects. Ingestion : May cause irritation to mouth, throat and stomach. May cause abdominal discomfort. Harmful or fatal if swallowed. Aspiration hazard if swallowed - can enter lungs and cause damage. Aggravated Medical : Persons with pre-existing skin disorders may be more Page 961 of 1235 Page 961 of 1235 Page 961 of 1235 Page 961 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 2.0 Print Date 08/26/2011 Revision Date 06/27/2011 MSDS Number 350000011783 2/8 Condition susceptible to irritating effects. Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, etc. may be more susceptible to irritating effects. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or the Canadian Controlled Products Regulations are listed in this table: Chemical Name CAS-No. Weight percent Solvent naphtha, petroleum, medium aliphatic 64742-88-7 30.00 - 60.00 Stoddard solvent 8052-41-3 30.00 - 60.00 Aromatic petroleum solvent 64742-95-6 1.00 - 5.00 Xylene 1330-20-7 1.00 - 5.00 Trimethyl benzene 25551-13-7 1.00 - 5.00 For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Eye contact : Rinse with plenty of water. Get medical attention if irritation develops and persists. Skin contact : Rinse with plenty of water. Get medical attention if irritation develops and persists. Inhalation : Remove to fresh air. If breathing is affected, get medical attention. Ingestion : If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during fire fighting : Do not use a solid water stream as it may scatter and spread fire. Container may melt and leak in heat of fire. Further information : Cool and use caution when approaching or handling fire- Page 962 of 1235 Page 962 of 1235 Page 962 of 1235 Page 962 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 2.0 Print Date 08/26/2011 Revision Date 06/27/2011 MSDS Number 350000011783 3/8 exposed containers. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. Flash point : 39 °C 102.2 °F Method: Tag Closed Cup (TCC) Lower explosion limit : Note: no data available Upper explosion limit : Note: no data available 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Remove all sources of ignition. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Wear personal protective equipment. Environmental precautions : Outside of normal use, avoid release to the environment. Methods for cleaning up : Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Dike large spills. Clean residue from spill site. 7. HANDLING AND STORAGE Handling Advice on safe handling : Avoid breathing vapors, mist or gas. KEEP OUT OF REACH OF CHILDREN AND PETS. Advice on protection against fire and explosion : Keep away from heat and sources of ignition. Take measures to prevent the build up of electrostatic charge. Storage Requirements for storage areas and containers : Keep container closed when not in use. Keep in a dry, cool and well-ventilated place. Page 963 of 1235 Page 963 of 1235 Page 963 of 1235 Page 963 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 2.0 Print Date 08/26/2011 Revision Date 06/27/2011 MSDS Number 350000011783 4/8 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Non- standard units Basis Stoddard solvent 8052-41-3 2,900 mg/m3 500 ppm - OSHA TWA Stoddard solvent 8052-41-3 - 100 ppm - ACGIH TWA Xylene 1330-20-7 435 mg/m3 100 ppm - OSHA TWA Xylene 1330-20-7 - 150 ppm - ACGIH STEL Xylene 1330-20-7 - 100 ppm - ACGIH TWA Trimethyl benzene 25551-13-7 - 25 ppm - ACGIH TWA Personal protective equipment Respiratory protection Industrial setting : Use only with adequate ventilation. Household setting : Use only with adequate ventilation. Hand protection : For prolonged or repeated contact use protective gloves. Eye protection Industrial setting : No special requirements. Household setting : Avoid contact with eyes. Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Smoking, eating and drinking should be prohibited in the application area. Page 964 of 1235 Page 964 of 1235 Page 964 of 1235 Page 964 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 2.0 Print Date 08/26/2011 Revision Date 06/27/2011 MSDS Number 350000011783 5/8 9. PHYSICAL AND CHEMICAL PROPERTIES Form : liquid Color : clear yellow Odor : solvent-like pH : not applicable Boiling point : no data available Freezing point : not applicable Flash point : 39 °C 102.2 °F Method: Tag Closed Cup (TCC) Evaporation rate : no data available Autoignition temperature : no data available Lower explosion limit : no data available Upper explosion limit : no data available Vapour pressure : no data available Density : 0.7929 g/cm3 at 25 °C Water solubility : negligible Partition coefficient: n- octanol/water : no data available Viscosity, dynamic : 4 mPa.s Viscosity, kinematic : 4 mm2/s 10. STABILITY AND REACTIVITY Conditions to avoid : Heat, flames and sparks. Materials to avoid : Strong oxidizing agents Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. Page 965 of 1235 Page 965 of 1235 Page 965 of 1235 Page 965 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 2.0 Print Date 08/26/2011 Revision Date 06/27/2011 MSDS Number 350000011783 6/8 Hazardous reactions : Stable under recommended storage conditions. 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50 > 20,000 mg/kg Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Chronic effects Carcinogenicity : no data available Mutagenicity : no data available Reproductive effects : no data available Teratogenicity : no data available Sensitisation : no data available 12. ECOLOGICAL INFORMATION Ecotoxicity effects : no data available 13. DISPOSAL CONSIDERATIONS Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle where facilities exist. RCRA waste class : D001 (Ignitable Waste) 14. TRANSPORT INFORMATION Land transport Page 966 of 1235 Page 966 of 1235 Page 966 of 1235 Page 966 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 2.0 Print Date 08/26/2011 Revision Date 06/27/2011 MSDS Number 350000011783 7/8  U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name Flammable Liquid n.o.s. (Mineral Spirits, Xylene) Class: 3 UN number 1993 Packaging group: III Note: SC Johnson ships this product as "Limited Quantity" per DOT exception for Flammable Liquids. (49 CFR 173.150) Sea transport  IMDG: Proper shipping name Flammable Liquid n.o.s. (Mineral Spirits, Xylene) Class: 3 UN number: 1993 Packaging group: III EmS: F-E, S-E Air transport  ICAO/IATA: Proper shipping name Flammable Liquid n.o.s. (Mineral Spirits, Xylene) Class: 3 UN/ID No.: UN 1993 Packaging group: III 15. REGULATORY INFORMATION Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Notification status : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA). California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65. Canada Regulations : This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. 16. OTHER INFORMATION HMIS Ratings Health 3 Flammability 2 Page 967 of 1235 Page 967 of 1235 Page 967 of 1235 Page 967 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 2.0 Print Date 08/26/2011 Revision Date 06/27/2011 MSDS Number 350000011783 8/8 Reactivity 0 NFPA Ratings Health 3 Fire 2 Reactivity 0 Special Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by: SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 968 of 1235 Page 968 of 1235 Page 968 of 1235 Page 968 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 1. Print Date 10/29/2008 Revision Date 10/21/2008 MSDS Number 350000011783 1/8 1. PRODUCT AND COMPANY IDENTIFICATION Product information Trade name : SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Use of the Substance/Preparation : Floor Polish/Cleaner Company : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236 Emergency telephone : 24 Hour Transport & Medical Emergency Phone (866) 231- 5406 24 Hour International Emergency Phone (952) 852-4647 2. HAZARDS IDENTIFICATION Emergency Overview Appearance / Odor : clear yellow / liquid / solvent Immediate Concerns : DANGER COMBUSTIBLE: Keep away from heat, sparks and flame. HARMFUL OR FATAL IF SWALLOWED. Potential Health Effects Routes of exposure : Eye, Skin, Inhalation, Ingestion. Eyes : May cause: Mild eye irritation Skin : Prolonged or repeated contact may dry skin and cause irritation. Inhalation : Inhalation may cause central nervous system effects. of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Ingestion : Harmful or fatal if swallowed. Aspiration hazard if swallowed - can enter lungs and cause damage. Aggravated Medical Condition : None known. Page 969 of 1235 Page 969 of 1235 Page 969 of 1235 Page 969 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 1. Print Date 10/29/2008 Revision Date 10/21/2008 MSDS Number 350000011783 2/8 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No. Weight % Solvent naphtha, petroleum, medium aliphatic 64742-88-7 30.00 - 60.00 Stoddard solvent 8052-41-3 30.00 - 60.00 Xylene 1330-20-7 1.00 - 5.00 Trimethyl benzene 25551-13-7 1.00 - 5.00 4. FIRST AID MEASURES Eye contact : Rinse with plenty of water. Get medical attention if irritation develops and persists. Skin contact : Wash off with soap and water. Get medical attention if irritation develops and persists. Inhalation : Remove to fresh air. If breathing is affected, get medical attention. Ingestion : If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Alcohol foam, carbon dioxide, dry chemical, water fog Specific hazards during fire fighting : Do not allow run-off from fire fighting to enter drains or water courses. Further information : Cool and use caution when approaching or handling fire- exposed containers. Wear full protective clothing and positive pressure self-contained breathing apparatus. Flash point : 102.6 °F Method: Tag Closed Cup (TCC) Flash point : 39 °C Method: Tag Closed Cup (TCC) Lower explosion limit : Note: no data available Page 970 of 1235 Page 970 of 1235 Page 970 of 1235 Page 970 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 1. Print Date 10/29/2008 Revision Date 10/21/2008 MSDS Number 350000011783 3/8 Upper explosion limit : Note: no data available 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Remove all sources of ignition. Methods for cleaning up : Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. 7. HANDLING AND STORAGE Handling Advice on safe handling : Avoid contact with skin, eyes and clothing. KEEP OUT OF REACH OF CHILDREN AND PETS. Do not taste or swallow. Advice on protection against fire and explosion : Keep away from heat and sources of ignition. Storage Requirements for storage areas and containers : Keep container closed when not in use. Keep in a dry, cool and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Basis Stoddard solvent 8052-41-3 - 100 ppm ACGIH TWA Stoddard solvent 8052-41-3 2,900 mg/m3 500 ppm OSHA TWA Xylene 1330-20-7 - 150 ppm ACGIH STEL Xylene 1330-20-7 - 100 ppm ACGIH TWA Xylene 1330-20-7 435 mg/m3 100 ppm OSHA TWA Trimethyl benzene 25551-13- 7 - 25 ppm ACGIH TWA Personal protective equipment Respiratory protection Page 971 of 1235 Page 971 of 1235 Page 971 of 1235 Page 971 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 1. Print Date 10/29/2008 Revision Date 10/21/2008 MSDS Number 350000011783 4/8 Industrial setting : Substantial amounts of mist/vapors can be controlled with local exhaust ventilation or respiratory protection. Household setting : No personal respiratory protective equipment normally required. Hand protection Industrial setting : For prolonged or repeated contact use protective gloves. Household setting : not required under normal use Eye protection Industrial setting : No special requirements. Household setting : No special requirements. Hygiene measures : Use only with adequate ventilation. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : liquid Color : clear yellow Odor : solvent pH : not applicable Boiling point : not determined Freezing point : not applicable Flash point : 102.6 °F Method: Tag Closed Cup (TCC) Flash point : 39 °C Method: Tag Closed Cup (TCC) Evaporation rate : no data available Autoignition temperature : no data available Lower explosion limit : no data available Page 972 of 1235 Page 972 of 1235 Page 972 of 1235 Page 972 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 1. Print Date 10/29/2008 Revision Date 10/21/2008 MSDS Number 350000011783 5/8 Upper explosion limit : no data available Vapour pressure : no data available Density : 0.7929 g/cm3 at 25 °C Water solubility : negligible Partition coefficient: n- octanol/water : no data available Viscosity, dynamic : 4 mPa.s Viscosity, kinematic : 4 mm2/s Specific Gravity : 0.7953 Percent volatile : 90 10. STABILITY AND REACTIVITY Conditions to avoid : Heat, flames and sparks. Materials to avoid : Do not mix with oxidizing agents. Hazardous decomposition products : When exposed to fire, produces normal products of combustion. Hazardous reactions : Stable 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50 rat Dose: > 20,000 mg/kg Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Chronic effects Carcinogenicity : no data available Mutagenicity : no data available Page 973 of 1235 Page 973 of 1235 Page 973 of 1235 Page 973 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 1. Print Date 10/29/2008 Revision Date 10/21/2008 MSDS Number 350000011783 6/8 Reproductive effects : no data available Teratogenicity : no data available Sensitisation : Not known to be a sensitizer. 12. ECOLOGICAL INFORMATION Ecotoxicity effects : Not Available 13. DISPOSAL CONSIDERATIONS Industrial setting : Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Household setting : Consumer may discard empty container in trash, or recycle where facilities exist. 14. TRANSPORT INFORMATION Land transport U.S. DOT and Canadian TDG Surface Transportation: NA number 1993 Proper shipping name Combustible Liquid, N.O.S. Class: Combustible liquid Packaging group: III Note: SC Johnson ships this product as "Non-Regulated" per DOT exception for Combustible Liquids. (49 CFR 173.150) Sea transport IMDG: UN-Number: None. Packaging group: None. Proper shipping name not regulated Class: None. Air transport ICAO/IATA: Page 974 of 1235 Page 974 of 1235 Page 974 of 1235 Page 974 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 1. Print Date 10/29/2008 Revision Date 10/21/2008 MSDS Number 350000011783 7/8 Class: None. Packaging group: None. Proper shipping name not regulated UN/ID No.: None. 15. REGULATORY INFORMATION Global Chemical Inventories Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA). California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65. : This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. 16. OTHER INFORMATION HMIS Ratings Health 2 Flammability 2 Reactivity 0 NFPA Ratings Health 2 Page 975 of 1235 Page 975 of 1235 Page 975 of 1235 Page 975 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 1. Print Date 10/29/2008 Revision Date 10/21/2008 MSDS Number 350000011783 8/8 Fire 2 Reactivity 0 Special Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by: SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 976 of 1235 Page 976 of 1235 Page 976 of 1235 Page 976 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 2.0 Print Date 08/26/2011 Revision Date 06/27/2011 MSDS Number 350000011783 1/8 1. PRODUCT AND COMPANY IDENTIFICATION Product information Trade name : SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Use of the Substance/Mixture : Floor Polish/Cleaner Company : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236 Emergency telephone number : 24 Hour Transport & Medical Emergency Phone (866) 231- 5406 24 Hour International Emergency Phone (952) 852-4647 2. HAZARDS IDENTIFICATION Emergency Overview Appearance / Odor : clear yellow / liquid / solvent-like Immediate Concerns : Danger COMBUSTIBLE: HARMFUL OR FATAL IF SWALLOWED. Avoid contact with skin, eyes and clothing. Keep away from heat, sparks and flame. Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion. Eyes : May cause: Mild eye irritation Skin : Prolonged or repeated contact may dry skin and cause irritation. Inhalation : Excessive exposures may affect human health, as follows: May cause nose, throat, and lung irritation. Inhalation may cause central nervous system effects. Ingestion : May cause irritation to mouth, throat and stomach. May cause abdominal discomfort. Harmful or fatal if swallowed. Aspiration hazard if swallowed - can enter lungs and cause damage. Aggravated Medical : Persons with pre-existing skin disorders may be more Page 977 of 1235 Page 977 of 1235 Page 977 of 1235 Page 977 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 2.0 Print Date 08/26/2011 Revision Date 06/27/2011 MSDS Number 350000011783 2/8 Condition susceptible to irritating effects. Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, etc. may be more susceptible to irritating effects. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or the Canadian Controlled Products Regulations are listed in this table: Chemical Name CAS-No. Weight percent Solvent naphtha, petroleum, medium aliphatic 64742-88-7 30.00 - 60.00 Stoddard solvent 8052-41-3 30.00 - 60.00 Aromatic petroleum solvent 64742-95-6 1.00 - 5.00 Xylene 1330-20-7 1.00 - 5.00 Trimethyl benzene 25551-13-7 1.00 - 5.00 For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Eye contact : Rinse with plenty of water. Get medical attention if irritation develops and persists. Skin contact : Rinse with plenty of water. Get medical attention if irritation develops and persists. Inhalation : Remove to fresh air. If breathing is affected, get medical attention. Ingestion : If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during fire fighting : Do not use a solid water stream as it may scatter and spread fire. Container may melt and leak in heat of fire. Further information : Cool and use caution when approaching or handling fire- Page 978 of 1235 Page 978 of 1235 Page 978 of 1235 Page 978 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 2.0 Print Date 08/26/2011 Revision Date 06/27/2011 MSDS Number 350000011783 3/8 exposed containers. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. Flash point : 39 °C 102.2 °F Method: Tag Closed Cup (TCC) Lower explosion limit : Note: no data available Upper explosion limit : Note: no data available 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Remove all sources of ignition. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Wear personal protective equipment. Environmental precautions : Outside of normal use, avoid release to the environment. Methods for cleaning up : Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Dike large spills. Clean residue from spill site. 7. HANDLING AND STORAGE Handling Advice on safe handling : Avoid breathing vapors, mist or gas. KEEP OUT OF REACH OF CHILDREN AND PETS. Advice on protection against fire and explosion : Keep away from heat and sources of ignition. Take measures to prevent the build up of electrostatic charge. Storage Requirements for storage areas and containers : Keep container closed when not in use. Keep in a dry, cool and well-ventilated place. Page 979 of 1235 Page 979 of 1235 Page 979 of 1235 Page 979 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 2.0 Print Date 08/26/2011 Revision Date 06/27/2011 MSDS Number 350000011783 4/8 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Non- standard units Basis Stoddard solvent 8052-41-3 2,900 mg/m3 500 ppm - OSHA TWA Stoddard solvent 8052-41-3 - 100 ppm - ACGIH TWA Xylene 1330-20-7 435 mg/m3 100 ppm - OSHA TWA Xylene 1330-20-7 - 150 ppm - ACGIH STEL Xylene 1330-20-7 - 100 ppm - ACGIH TWA Trimethyl benzene 25551-13-7 - 25 ppm - ACGIH TWA Personal protective equipment Respiratory protection Industrial setting : Use only with adequate ventilation. Household setting : Use only with adequate ventilation. Hand protection : For prolonged or repeated contact use protective gloves. Eye protection Industrial setting : No special requirements. Household setting : Avoid contact with eyes. Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Smoking, eating and drinking should be prohibited in the application area. Page 980 of 1235 Page 980 of 1235 Page 980 of 1235 Page 980 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 2.0 Print Date 08/26/2011 Revision Date 06/27/2011 MSDS Number 350000011783 5/8 9. PHYSICAL AND CHEMICAL PROPERTIES Form : liquid Color : clear yellow Odor : solvent-like pH : not applicable Boiling point : no data available Freezing point : not applicable Flash point : 39 °C 102.2 °F Method: Tag Closed Cup (TCC) Evaporation rate : no data available Autoignition temperature : no data available Lower explosion limit : no data available Upper explosion limit : no data available Vapour pressure : no data available Density : 0.7929 g/cm3 at 25 °C Water solubility : negligible Partition coefficient: n- octanol/water : no data available Viscosity, dynamic : 4 mPa.s Viscosity, kinematic : 4 mm2/s 10. STABILITY AND REACTIVITY Conditions to avoid : Heat, flames and sparks. Materials to avoid : Strong oxidizing agents Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. Page 981 of 1235 Page 981 of 1235 Page 981 of 1235 Page 981 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 2.0 Print Date 08/26/2011 Revision Date 06/27/2011 MSDS Number 350000011783 6/8 Hazardous reactions : Stable under recommended storage conditions. 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50 > 20,000 mg/kg Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Chronic effects Carcinogenicity : no data available Mutagenicity : no data available Reproductive effects : no data available Teratogenicity : no data available Sensitisation : no data available 12. ECOLOGICAL INFORMATION Ecotoxicity effects : no data available 13. DISPOSAL CONSIDERATIONS Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle where facilities exist. RCRA waste class : D001 (Ignitable Waste) 14. TRANSPORT INFORMATION Land transport Page 982 of 1235 Page 982 of 1235 Page 982 of 1235 Page 982 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 2.0 Print Date 08/26/2011 Revision Date 06/27/2011 MSDS Number 350000011783 7/8  U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name Flammable Liquid n.o.s. (Mineral Spirits, Xylene) Class: 3 UN number 1993 Packaging group: III Note: SC Johnson ships this product as "Limited Quantity" per DOT exception for Flammable Liquids. (49 CFR 173.150) Sea transport  IMDG: Proper shipping name Flammable Liquid n.o.s. (Mineral Spirits, Xylene) Class: 3 UN number: 1993 Packaging group: III EmS: F-E, S-E Air transport  ICAO/IATA: Proper shipping name Flammable Liquid n.o.s. (Mineral Spirits, Xylene) Class: 3 UN/ID No.: UN 1993 Packaging group: III 15. REGULATORY INFORMATION Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Notification status : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA). California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65. Canada Regulations : This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. 16. OTHER INFORMATION HMIS Ratings Health 3 Flammability 2 Page 983 of 1235 Page 983 of 1235 Page 983 of 1235 Page 983 of 1235 ---PAGE BREAK--- Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 SC JOHNSON® ONE STEP NO BUFF WAX - FINE WOOD FLOOR CARE Version 2.0 Print Date 08/26/2011 Revision Date 06/27/2011 MSDS Number 350000011783 8/8 Reactivity 0 NFPA Ratings Health 3 Fire 2 Reactivity 0 Special Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by: SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 984 of 1235 Page 984 of 1235 Page 984 of 1235 Page 984 of 1235 ---PAGE BREAK--- Emergency Overview green liquid with solvent odor Class IC - Flammable Liquid Potential Health Effects - Eye: Moderate irritation with redness and minor discomfort after direct splash to eye. Potential Health Effects - Skin: Moderately irritating with possible redness and discomfort. May cause dry skin by dissolving skin oils. Contains a component which can be absorbed through the skin in harmful amounts. Potential Health Effects - Inhalation: Moderately irritating to nose, throat or breathing passages. May cause unconsciousness by depressing the central nervous system after prolonged exposure to high concentrations. Potential Health Effects -Ingestion: Moderately irritating to the mouth, stomach, and digestive system. No ingestion exposure expected with normal occupational use. Potential Health Effects - Chronic Hazards: Eye effects from chronic exposure are unknown. Frequent or prolonged skin contact may cause irritation or a rash (dermatitis). Chronic exposure may cause problems of the liver and bile duct system. Chronic ingestion exposure would be unlikely due to the method of use or physical properties of this product. The components listed in Section 2 may affect the following target organs: Blood. Central Nervous System. Eyes. Gastrointestinal Tract. Hematopoietic System. Kidneys. Liver. System. Peripheral Nervous System. Reproductive System. Respiratory System. Skin. Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Eye Contact First Aid - Eye Contact: If this product contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention. First Aid - Skin Contact: If this product contacts the skin, wash the contaminated skin with soap & water. If this product penetrates the clothing, remove the clothing and wash the skin with soap & water. If irritation persists after washing, get medical attention. Launder clothing before reuse. First Aid - Inhalation: If a person breathes large amounts of this product, move the exposed person to fresh air at once. If breathing is difficult, get medical attention. MATERIAL SAFETY DATA SHEET F4101; SEA FOAM 1. Identification of the Product and Company . Product Code & Product Name: F4101; SEA FOAM Company: Akzo Nobel - Awlgrip North America 2270 Morris Avenue Union, NJ 07083 Tel. [PHONE REDACTED]; Fax [PHONE REDACTED] Health & Safety Information [PHONE REDACTED] Emergency: Emergency telephone (US) CHEMTREC - [PHONE REDACTED] Emergency telephone (Outside US) CHEMTREC - [PHONE REDACTED] NOTE: CHEMTREC numbers to be used only in the event of emergencies involving a spill, leak, fire, exposure or accident involving chemicals. Product Use: Coating 2. Composition / Information on Ingredients Chemical Name CAS Number WT % ACGIH TLV TWAACGIH TLV STELOSHA PEL COSHA PEL TWA TITANIUM DIOXIDE 13463-67-7 15-40 10 mg/m3 dust N.D. N.D. 15 mg/m3 dust METHYL AMYL KETONE 110-43-0 10-30 50 ppm N.D. N.D. 100 ppm 2-ETHOXYETHYL ACETATE 111-15-9 10-30 5 ppm N.D. N.D. 100 ppm 2-BUTOXYETHYL ACETATE 112-07-2 1-5 N.D. N.D. N.D. N.D. 100-41-4 0.1-1.0 100 ppm 125 ppm N.D. 100 ppm 3. Hazards Identification 4. First Aid Measures MSDS: F4101, Page 1 of 4 Page 985 of 1235 Page 985 of 1235 Page 985 of 1235 Page 985 of 1235 ---PAGE BREAK--- First Aid - Ingestion: If this product has been swallowed, get medical attention immediately. Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam Unusual Fire And Explosion Hazards: Flammable Liquid. Vapors are heavier than air and may travel to a source of ignition and flash back. Special Fire Fighting Procedures: Firefighters and others exposed to vapors or products of combustion should wear self-contained breathing apparatus. Steps To Be Taken If Material Is Released Or Spilled: Eliminate all ignition sources. Stop or control the spill, if this can be done without undue risk. Do not allow material to enter sewers or ground. Isolate discharged material for proper disposal. Wear appropriate personal protective equipment. Handling: Grounding or bonding of containers is recommended before material transfer. Storage: Storage areas should be dry and well-ventilated. Engineering Controls: It is recommended that work be done in an adequately ventilated area ventilation sufficient to maintain concentrations below one half of the PEL and other relevant standards). Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination. Respiratory Protection: Appropriate respirators must be used, and a program that follows 29 CFR 1910.134 or other applicable regulatory requirements must be followed, when workplace hazards warrant the use of a respirator. NIOSH-approved or other appropriate respirators must be used when respiratory protection is necessary. Eye Protection: Wear appropriate goggles, face shields or other PPE, which will be effective under the circumstances if the possibility of contact exists. A program meeting 29 CFR 1910.133 or other applicable regulatory requirements must be followed when PPE is necessary. Other Protective Equipment: Use impermeable gloves and protective clothing as necessary to prevent skin contact. Hygienic Practices: Do not eat, drink, chew tobacco or gum, or apply cosmetics while working with this product. Wash hands before performing any of these activities. 5. Fire-Fighting Measures . Flash Point 78 LOWER EXPLOSIVE LIMIT: 0.1 UPPER EXPLOSIVE LIMIT: 15.0 6. Accidental Release Measures 7. Handling and Storage 8. Exposure Controls / Personal Protection 9. Physical and Chemical Properties Theoretical Values Boiling Range 252 - 662 VOC (g/l)(less water & exempt): 419 Freeze Point N.D. VOC (lb/gal)(less water & exempt): 3.5 Specific Gravity: 1.3 % Solids By Weight: 68 Appearance: green % Solids By Volume: 53 Physical State: liquid Density (lb/gal): 10.9 Odor: solvent . 10. Stability and Reactivity MSDS: F4101, Page 2 of 4 Page 986 of 1235 Page 986 of 1235 Page 986 of 1235 Page 986 of 1235 ---PAGE BREAK--- Conditions To Avoid: Avoid contact with heat, open flame, sparks, or ignition sources. Hazardous Polymerization: Will not occur. Stability: Stable. Akzo Nobel has not conducted specific studies on the eco toxicity or environmental fate of this product. Commonly available data on certain ingredients indicate that acute or chronic effects could result from uncontrolled releases to soil, ground water, storm waters, or air. Appropriate measures should be taken to prevent uncontrolled releases. Prompt containment and clean up should be performed if releases do occur. Legal disposition of wastes is the responsibility of the owner/generator of the waste. Applicable federal, state, and/or local regulations must be followed during treatment, storage, or disposal of waste containing this product. Do not dispose of in an uncontrolled manner. U.S. FEDERAL REGULATIONS: As follows - CERCLA - SARA Hazard Category: This product is considered, under applicable definitions, to meet the following categories: IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD SARA Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and 40 CFR 372: Clean Air Act: This product contains the following chemical substances listed as Hazardous Air Pollutants (HAPs) under the Clean Air Act of 1990: Toxic Substances Control Act: All the components of this product comply with applicable requirements of the US EPA TSCA inventory. Contains chemical(s) subject to the reporting requirements of TSCA 12b if exported from the US. U.S. STATE REGULATIONS: As follows - 11. Toxicological Information Chemical Name LD50 LC50 IARC NTP OSHA TITANIUM DIOXIDE N.D. N.D. METHYL AMYL KETONE Oral Rat: 1600 mg/kg N.D. 2-ETHOXYETHYL ACETATE Oral Rat: 2700 mg/kg Inhalation Rat: 12100 mg/m3/8H 2-BUTOXYETHYL ACETATE Oral Rat: 2400 mg/kg N.D. Oral Rat: 3500 mg/kg N.D. Group 2B 12. Ecological Information 13. Disposal Considerations 14. Transport Information . DOT Proper Shipping Name: Paint IATA Proper Shipping Name: Paint IMO Proper Shipping Name: Paint DOT Hazard Class: 3 IATA Hazard Class: 3 IMO Hazard Class: 3 DOT UN Number: UN1263 IATA UN Number: UN1263 IMO UN Number: UN1263 DOT Packing Group: III IATA Packing Group: III IMO Packing Group: III Resp. Guide Page: 128 IATA Hazard Subclass: N/A Marine Pollutant: No Chemical Name CAS Number RQ (lbs) 100-41-4 1000 15. Regulatory Information Chemical Name 313 Category CAS Number WT % 2-ETHOXYETHYL ACETATE Glycol Ethers 111-15-9 12.3 2-BUTOXYETHYL ACETATE Glycol Ethers 112-07-2 3.3 100-41-4 0.3 Chemical Name HAP Category CAS Number WT % 2-ETHOXYETHYL ACETATE Glycol Ethers 111-15-9 12.3 2-BUTOXYETHYL ACETATE Glycol Ethers 112-07-2 3.3 100-41-4 0.3 MSDS: F4101, Page 3 of 4 Page 987 of 1235 Page 987 of 1235 Page 987 of 1235 Page 987 of 1235 ---PAGE BREAK--- California Proposition 65: WARNING: This product contains chemicals known to the State of CA to cause cancer and birth defects or other reproductive harm. INTERNATIONAL REGULATIONS: As follows - Canadian WHMIS Class: B2, D2 Korean Inventory - All the components of this product are listed or are exempt from listing. Legend: N.A. - Not Applicable, N.D. - Not Determined This MSDS relates only to the specific material identified in Section 2. In compiling this MSDS, Akzo Nobel has relied in good faith on information provided to Akzo Nobel by suppliers of the components of this material, and, in some cases, provided by independent data resources. Akzo Nobel has not independently verified such information, and, in addition, users should be aware that all materials may present unknown hazards. Use of this material in combination with other materials and/or in specific processes may render information set forth in the MSDS inaccurate or otherwise invalid. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE REGARDING THE INFORMATION FURNISHED ON THIS MSDS. Revision Date: 09/23/2004 16. Other Information . National Paint & Coatings Association (NPCA) Hazardous Material Identification System (HMIS): Health: 3 Flammability: 3 Reactivity: 0 Personal Protection: See Section 8 MSDS: F4101, Page 4 of 4 Page 988 of 1235 Page 988 of 1235 Page 988 of 1235 Page 988 of 1235 ---PAGE BREAK--- Sea Foam Sales Company P.O. Box 5178 Hopkins, MN 55343-1178 Phone (952)938-4811 MATERIAL SAFETY DATA INFORMATION FOR SEA FOAM MOTOR TREATMENT Part No. SF-16, SF-128 SEA FOAM TRANS TUNE Part No. TT-16 Note: Each product contains the same ingredients; however, the percentage of each ingredient varies within the limits of the printed percentages, depending on the use of each product SECTION I IDENTITY AS USED ON LABEL AND LIST Motor Treatment and Trans Tune Sea Foam Formula: Proprietary Blend Date Prepared: 1-26-2006 Emergency (800)535-5053 MFG. Code ID: 34066 SECTION II-A HAZARDOUS COMPONENTS NO. COMPONENT EPC# % BY WT. 1 PALE OIL 4229 40-60% 2 NAPHTHA 20 25-35% 3 IPA 125 10-20% NONE OF THE COMPONENTS OF THIS PRODUCT ARE RECOGNIZED AS CARCINOGENIC. SECTION II-B OCCUPATIONAL EXPOSURE LIMITS NO. (OSHA) PEL/TWA PEL/CEILING NO. (OSHA) PEL/STEL SKIN* 1 5.000mg/m3 N/E 1 N/E N 2 300.000ppm N/E 2 400.000ppm N 3 400.000ppm N/E 3 500.000ppm N NO. (ACGIH) TLV/TWA TLV/CEILING NO. (AC GIH) TLV/STEL SKIN* 1 5.000mg/m3 N/E 1 10.000mg/m3 N 2 300.000ppm N/E 2 N/E N 3 400.000ppm N/E 3 500.000ppm N * (SKIN) ABSORPTION MAY CONTRIBUTE TO THE OVERALL EXPOSURE TO THIS MATERIAL. TAKE APPROPRIATE MEASURES TO PREVENT SKIN CONTACT. SECTION III PHYSICAL DATA BOILING POINT : 180 (DEGREES F) EVAPORATION RATE: < 1 (ETHER = 1) % SOLID : 40-60% (THEORETICAL) VAPOR DENSITY : > 1 (AIR = 1) WEIGHT PER GALLON : 6.93 (THEORETICAL) (Boiling point represents boiling point of lowest boiling raw material.) SECTION IV HEALTH INFORMATION - EYE CONTACT - BASED ON THE PRESENCE OF COMPONENTS 2 AND 3 PRODUCT IS PRESUMED TO BE MODERATELY IRRITATING TO THE EYES. BASED ON THE PRESENCE OF COMPONENTS 2 AND 3 PRODUCT VAPORS AND/OR MISTS MAY ALSO BE IRRITATING TO THE EYES. - SKIN CONTACT - EXPOSURE MAY PRODUCE SKIN IRRITATION. BASED ON THE PRESENCE OF COMPONENTS 2 AND 3 PROLONGED OR REPEATED CONTACT MAY RESULT IN DEFATTING AND DRYING OF THE SKIN WHICH MAY RESULT IN DERMATITIS. - INHALATION - EXPOSURE MAY PRODUCE IRRITATION TO THE NOSE, THROAT, RESPIRATORY TRACT, AND OTHER MUCOUS MEMBRANES. BASED ON THE PRESENCE OF COMPONENTS 2 AND 3 EXPOSURE TO HIGH CONCENTRATIONS OF VAPOR MAY PRODUCE CENTRAL NERVOUS SYSTEM DEPRESSION. - INGESTION - BASED ON THE PRESENCE OF COMPONENTS 2 AND 3 PRODUCT IS PRESUMED TO BE TOXIC. BASED ON THE PRESENCE OF COMPONENT 3 INGESTION MAY CAUSE KIDNEY DAMAGE. BASED ON THE PRESENCE OF COMPONENT 3 INGESTION MAY CAUSE LIVER DAMAGE. BASED ON THE PRESENCE OF COMPONENTS 2 AND 3 SMALL AMOUNTS OF THE LIQUID ASPIRATED INTO THE LUNGS DURING INGESTION OR FROM VOMITING MAY RESULT IN SEVERE LUNG DAMAGE. BASED ON THE PRESENCE OF COMPONENT 3 INGESTION MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. - SIGNS AND - OF EYE IRRITATION INCLUDE PAIN, TEARING, REDDENING AND SWELLING. OF SKIN IRRITATION INCLUDE REDDENING, SWELLING, RASH AND REDNESS. OF RESPIRATORY IRRITATION INCLUDE RUNNY NOSE, SORE THROAT, COUGHING, CHEST DISCOMFORT, SHORTNESS OF BREATH AND REDUCED LUNG FUNCTION. OF GASTROINTESTIONAL IRRITATION INCLUDE SORE THROAT, ABDOMINAL PAIN, NAUSEA, VOMITING AND DIARRHEA. BASED ON THE PRESENCE OF COMPONENTS 2 AND 3 CENTRAL NERVOUS SYSTEM DEPRESSION MAY BE EVIDENCED BY HEADACHE, DIZZINESS, NAUSEA AND OF INTOXICATION; IN EXTREME CASES, UNCONSCIOUSNESS AND DEATH MAY OCCUR. OF CHRONIC OVEREXPOSURE INCLUDE LOSS OF MEMORY, LOSS OF INTELLECTUAL ABILITY AND LOSS OF COORDINATION. - AGGRAVATED MEDICAL CONDITIONS - PREEXISTING SKIN, EYE AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY Page 989 of 1235 Page 989 of 1235 Page 989 of 1235 Page 989 of 1235 ---PAGE BREAK--- - OTHER HEALTH EFFECTS - BASED ON THE PRESENCE OF COMPONENT 3 PRODUCT IS PRESUMED TO BE FETOTOXIC. BASED ON THE PRESENCE OF COMPONENT 3 PRODUCT IS PRESUMED TO BE MUTAGENIC. BASED ON THE PRESENCE OF COMPONENT 2 CHRONIC OVEREXPOSURE MAY CAUSE DAMAGE TO THE KIDNEYS. SECTION V EMERGENCY AND FIRST AID PROCEDURES - EYE CONTACT - IMMEDIATELY FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION IF ANY PERSIST. - SKIN CONTACT - REMOVE CONTAMINATED CLOTHING AND SHOES. WIPE EXCESS FROM SKIN AND FLUSH WITH WATER USING SOAP IF AVAILABLE. SEEK MEDICAL ATTENTION IF IRRITATION OCCURS. DO NOT REUSE CLOTHING UNTIL THOROUGHLY DECONTAMINATED. - INHALATION - REMOVE VICTIM TO FRESH AIR AND TREAT PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GIVE ARTIFICIAL RESPIRATION IF THE VICTIM IS NOT BREATHING. SEEK PROMPT MEDICAL ATTENTION. - INGESTION - DO NOT INDUCE VOMITING. IF VOMITING SPONTANEOUSLY OCCURS, KEEP THE VICTIM'S HEAD BELOW THE HIPS TO PREVENT ASPIRATION INTO THE LUNGS. SINCE ASPIRATION INTO THE LUNGS CAN CAUSE VERY SERIOUS, PERMANENT DAMAGE, THE DECISION OF WHETHER TO INDUCE VOMITING OR NOT SHOULD BE MADE BY A PHYSICIAN. DANGER FROM LUNG ASPIRATION MUST BE WEIGHED AGAINST TOXICITY WHEN CONSIDERING EMPTYING THE STOMACH. CONSULT A PHYSICIAN, HOSPITAL OR POISON CONTROL CENTER AND/OR TRANSPORT TO AN EMERGENCY FACILITY IMMEDIATELY. - NOTES FOR PHYSICIAN - THE FOLLOWING COMPONENT-SPECIFIC INFORMATION MAY CONTAIN CONTRADICTIONS, AND IS INTENTIONALLY INCLUDED TO GIVE THE ATTENDING PHYSICIAN SPECIFIC INFORMATION ABOUT THE INDIVIDUAL COMPONENTS OF THE BLEND. COMPONENTS 2 AND 3 MAY CAUSE SEVERE, PERMANENT DAMAGE IF ASPIRATED AND VOMITING SHOULD NOT BE INDUCED. SECTION VI FIRE AND EXPLOSION HAZARDS FLASH POINT : 55 DEGREES F. TCC - EXTINGUISHING MEDIA - USE WATER FOG, FOAM, DRY CHEMICAL OR CARBON DIOXIDE. - SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS - WARNING. FLAMMABLE. CLEAR FIRE AREA OF UNPROTECTED PERSONNEL. DO NOT ENTER CONFINED FIRE SPACE WITHOUT HELMET, FACE SHIELD, BUNKER COAT, GLOVES, RUBBER BOOTS, AND A POSITIVE PRESSURE NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. - UNUSUAL FIRE AND EXPLOSION HAZARDS - CONTAINERS EXPOSED TO INTENSE HEAT FROM FIRES SHOULD BE COOLED WITH WATER TO PREVENT VAPOR PRESSURE BUILDUP WHICH COULD RESULT IN CONTAINER RUPTURE. CONTAINERS THAT ARE EXPOSED TO DIRECT FLAME SHOULD BE COOLED WITH WATER TO ELIMINATE STRUCTURAL WEAKENING OF THE CONTAINER'S WALL AND POSSIBLE RUPTURE. SECTION VII REACTIVITY STABILITY : STABLE HAZARDOUS POLYMERIZATION : WILL NOT OCCUR - CONDITIONS AND MATERIALS TO AVOID - BASED ON THE PRESENCE OF COMPONENTS 1, 2 AND 3 AVOID OXIDIZING MATERIALS. - HAZARDOUS DECOMPOSITION PRODUCTS - CARBON DIOXIDE, CARBON MONOXIDE AND UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION. SECTION VIII EMPLOYEE PROTECTION - RESPIRATORY PROTECTION - USE VENTILATION AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS - AT LEAST 10 AIR CHANGES PER HOUR ARE RECOMMENDED FOR GOOD GENERAL ROOM VENTILATION. IF EXPOSURE EXCEEDS THE PEL/TLV, USE THE APPROPRIATE NIOSH-APPROVED RESPIRATOR. - PROTECTIVE CLOTHING - WEAR SAFTEY GLASSES, GOGGLES, OR A SPLASH SHIELD TO PREVENT EYE CONTACT. CONTACT LENSES SHOULD NOT BE WORN. WEAR APPROPRIATE GLOVES AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND CLOTHING. - ADDITIONAL PROTECTIVE MEASURES - EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE FOR USE IN AN EMERGENCY. SECTION IX ENVIRONMENTAL PROTECTION - SPILL OR LEAK PROCEDURES - LARGE SPILLS EVACUATE THE HAZARD AREA OF UNPROTECTED PERSONNEL. WEAR APPROPRIATE RESPIRATOR AND PROTECTIVE CLOTHING. SHUT OFF SOURCE OF LEAK ONLY IF SAFE TO DO SO. DIKE AND CONTAIN. IF VAPOR CLOUD FORMS, WATER FOG MAY BE USED TO SUPPRESS; CONTAIN RUN-OFF. REMOVE WITH VACUUM TRUCKS OR PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE WITH AN ABSORBENT SUCH AS CLAY, SAND OR OTHER SUITABLE MATERIAL; PLACE IN NON-LEAKING CONTAINERS FOR PROPER DISPOSAL. FLUSH AREA WITH WATER TO REMOVE TRACE RESIDUE; DISPOSE OF FLUSH SOLUTIONS AS ABOVE. SMALL SPILLS TAKE UP WITH AN ABSORBENT MATERIAL AND PLACE IN NON-LEAKING CONTAINERS; SEAL FOR PROPER DISPOSAL. - WASTE DISPOSAL - OBSERVE ALL FEDERAL, STATE, AND LOCAL REGULATIONS REGARDING PROPER DISPOSAL. SECTION X ADDITIONAL PRECAUTIONS KEEP LIQUID AND VAPOR AWAY FROM HEAT, SPARKS, AND FLAME. EXTINGUISH PILOT LIGHTS, CIGARETTES AND TURN OFF OTHER POSSIBLE SOURCES OF IGNITION PRIOR TO USE AND UNTIL VAPORS ARE GONE. SURFACES THAT ARE SUFFICIENTLY HOT MAY IGNITE PRODUCT IN THE ABSENCE OF SPARKS OR FLAME. VAPORS MAY ACCUMULATE AND TRAVEL TO IGNITION SOURCES DISTANT FROM HANDLING SITE. KEEP CONTAINERS CLOSED WHEN NOT IN USE. USE WITH ADEQUATE VENTILATION. CONTAINERS, EVEN IF EMPTY, CAN CONTAIN EXPLOSIVE VAPORS OR RESIDUES. DO NOT CUT, DRILL, GRIND, OR WELD NEAR CONTAINERS AFTER CONTACT WITH PRODUCT OR CONTAINER WASH WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING, OR USING TOILET FACILITIES. THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVILABLE TO US AND IS BELIEVED TO BE CORRECT. HOWEVER, WE MAKE NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. WE ASSUME NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. Page 990 of 1235 Page 990 of 1235 Page 990 of 1235 Page 990 of 1235 ---PAGE BREAK--- AMSOIL Material Safety Data Sheet Date Issued/Revised: November 7, 2007 Supersedes: Product Code: SRN, Severe Gear EP Lubricant SAE 150 SRT, Severe Gear EP Lubricant SAE 250 Page 1 of 4 Section 1: Product and Company Identification Manufacturer: AMSOIL, Inc. Telephone: 925 Tower Avenue CHEMTREC (Spill Emergency Only): 1-[PHONE REDACTED] Superior, WI 54880 Information: [PHONE REDACTED] Product Code SRN SAE 190 SRT, SAE 250 Label Name Severe Gear EP Lubricant Severe Gear EP Lubricant Product Use LUBRICATING OIL Section 2: Composition/Information on Ingredients OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200) This product is not formulated to contain ingredients that have exposure limits exceeding those established by US agencies.% *See Section 8 for exposure limits. Section 3: Hazards Identification POTENTIAL HEALTH EFFECTS: Minor eye, inhalation and skin irritant. *See Section 11 for toxicological information. Section 4: First Aid Measures EYE: Flush with water for 15-20 minutes. Seek medical attention if irritation develops. SKIN: Wash immediately with soap and water. Remove contaminated clothing and launder before reuse. Discard shoes and leather articles saturated with the product. Obtain medical advice if irritation occurs. INHALATION: Remove exposed person to fresh air. If breathing is labored give oxygen. If breathing has stopped apply artificial respiration. Get immediate medical attention. INGESTION: DO NOT INDUCE VOMITING. If conscious, give 2 glasses of water. If vomiting does occur, keep head below hips to reduce risk of aspiration. Get immediate medical attention. Section 5: Fire Fighting Measures FLAMMABILITY PROPERTIES: SRN SAE 190 SRT, SAE 250 Flash Point 424 F(218 C) 442 F(228 C) Method COC ASTM D-92 LFL/UFL Not Determined Auto-ignition Temperature Not Determined EXTINGUISHING MEDIA: Carbon dioxide, dry chemical, alcohol foam and water fog. SPECIAL PROCEDURES: Water or foam may cause frothing. Use water to keep fire exposed surface cool. Water spray may be used to flush spills away from exposure. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water. PROTECTIVE EQUIPMENT: For fires in enclosed areas, fire fighters must use self-contained breathing apparatus Red Flammability 1 Blue Health 1 Yellow Instability 0 White Special N/A NFPA Rating Page 991 of 1235 Page 991 of 1235 Page 991 of 1235 Page 991 of 1235 ---PAGE BREAK--- AMSOIL Material Safety Data Sheet Date Issued/Revised: November 7, 2007 Supersedes: Product Code: SRN, Severe Gear EP Lubricant SAE 150 SRT, Severe Gear EP Lubricant SAE 250 Page 2 of 4 Section 6: Accidental Release Measures Isolate spill area. Provide adequate ventilation. Wear appropriate personal protection. Recover free product for recycle and/or disposal. Add sand, earth or other suitable absorbent to spill area. Prevent entry into sewers and waterways. Check under Transportation and Labeling (DOT/CERCLA) and Other Regulator Information Section (SARA) for hazardous substances to determine regulatory reporting requirements for spill. Section 7: Handling and Storage HANDLING: Keep containers closed. Avoid contact with eyes, skin or clothing. Wash hands after handling. Empty container may retain product residue which may exhibit hazards of product. STORAGE: Keep away from heat or flame. Section 8: Exposure Controls/Personal Protection VENTILATION: Use adequate general or local exhaust ventilation to keep airborne concentrations below exposure limits. RESPIRATORY: Use a NIOSH approved respirator when necessary. SKIN: Use Viton or Nitrile gloves to avoid prolonged or repeated skin contact. EYE: Use splash goggles or face shield where splashing is expected or can occur. EXPOSURE LIMITS: The Threshold Limit Value (TLV) of 5 mg/m3 is suggested for oil mist. Section 9: Physical and Chemical Properties SRN SAE 190 SRT, SAE 250 Physical State Liquid Boiling Point Not Determined Freezing/Melting Point -22 F(-30 C) -15 F(-26 C) Vapor Pressure Not Determined Vapor Density (Air=1) Negligible Evaporation Rate Not Determined Solubility in Water Negligible Specific Gravity (Water=1) 0.8838 0.8894 Density, lb./gal. 7.360 7.406 Volatility (Volume) Negligible VOC Unknown pH Essentially Neutral Odor Mild, Sulfur, Hydrocarbon Odor Odor Threshold Not Determined Appearance Transparent Dark Green Colored Liquid Transparent Dark Green Colored Liquid Viscosity, cSt @ 100 C 37.62 47.38 Viscosity, cSt @ 40 C 375.67 502.69 Section 10: Stability and Reactivity STABILITY: Stable under moderately elevated temperatures and pressures. INCOMPATIBILITY: Avoid contact with strong oxidants. Page 992 of 1235 Page 992 of 1235 Page 992 of 1235 Page 992 of 1235 ---PAGE BREAK--- AMSOIL Material Safety Data Sheet Date Issued/Revised: November 7, 2007 Supersedes: Product Code: SRN, Severe Gear EP Lubricant SAE 150 SRT, Severe Gear EP Lubricant SAE 250 Page 3 of 4 HAZARDOUS POLYMERIZATION: Will not occur. HAZARDOUS DECOMPOSITION OF PRODUCT: Toxic oxides of carbon, aldehydes and other products of incomplete combustion. Section 11: Toxicological Information ACUTE EXPOSURE Eye Irritation: Moderate to strong eye irritation. Based on data from components or similar material. Skin Irritation: Not expected to be a primary skin irritant. Based on data from components or similar material. Prolonged or repeated skin contact as from clothing wet with material may cause dermatitis. may include redness, edema, drying, defatting, and cracking of the skin. Respiratory Irritation: If material is misted or if vapors are generated from heating, exposure may cause irritation of mucous membranes and the upper respiratory tract similar to that observed with mineral oil. Based on data from components or similar materials. Under good industrial hygiene practices where all exposure limits are observed, respiratory irritation should not be a problem. CHRONIC EXPOSURE Chronic Toxicity: No data available to indicate product present at greater than 1.0% are chronic health hazards. Carcinogenicity: No data available to indicate product present at greater than 0.1% are a carcinogenic hazard. Mutagenicity: No data available to indicate product present at greater than 1.0% present a mutagenic or genotoxic hazard. Reproductive Toxicity: No data available to indicate product present at greater than 1.0% present a reproductive hazard. Teratogenicity: No data available to indicate product present at greater than 1.0% present a teratogenic hazards. ADDITIONAL INFORMATION Exposure Limits: Under conditions which may generate mists, observe the OSHA PEL of 5 mg per cubic meter. Section 12: Ecological Information No data available on the adverse effects of this product on the environment. Section 13: Disposal Considerations If this product as supplied becomes a waste, it does not meet the criteria of a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Section 14: Transport Information This product is not classified as hazardous material for DOT shipping. For further information relative to spills resulting from transportation incidents, refer to the latest DOT Emergency Response Guidebook for Hazardous Materials. Page 993 of 1235 Page 993 of 1235 Page 993 of 1235 Page 993 of 1235 ---PAGE BREAK--- AMSOIL Material Safety Data Sheet Date Issued/Revised: November 7, 2007 Supersedes: Product Code: SRN, Severe Gear EP Lubricant SAE 150 SRT, Severe Gear EP Lubricant SAE 250 Page 4 of 4 Section 15: Regulatory Information U.S. Federal Regulations OSHA Table Z Base Stock (mist) TSCA Not Applicable CERCLA 40 CFR 302.4 Not Applicable SARA Title III Section 302 Extremely Hazardous Not Applicable Section 311/312 Fire Hazard No Reactive Hazard No Release of Pressure No Acute Health Hazard Yes Chronic Health Hazard No Section 313 Toxic Chemical Not Applicable U.S. State Regulations California (Prop 65) Does not contain chemicals known to the state of California to cause cancer. International Regulations WHMIS All components listed Section 16: Other Information The information and recommendations contained herein are, to the best of AMSOIL’s knowledge and belief, accurate and reliable as of the date issued. AMSOIL makes no warranty or guarantee, expressed or implied, of their accuracy or reliability, and AMSOIL shall not be liable for any loss or damage based upon the criteria supplied by the developers of these rating systems, together with AMSOIL’s interpretation of the available data. Page 994 of 1235 Page 994 of 1235 Page 994 of 1235 Page 994 of 1235 ---PAGE BREAK--- Shell Rotella T5 10W-30 MSDS# 11045DA Version 1.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 1/9 Print Date 07/03/2014 000000014560 MSDS_US 1. MATERIAL AND COMPANY IDENTIFICATION Material Name : Shell Rotella T5 10W-30 Product Code : 001D5436 Uses : Engine oil. Manufacturer/Supplier : Shell Oil Products US P.O. Box 4427 Houston TX 77210-4427 USA SDS Request : [PHONE REDACTED] Emergency Telephone Number Spill Information : [PHONE REDACTED] Health Information : [PHONE REDACTED] 2. COMPOSITION/INFORMATION ON INGREDIENTS Lithium alkaryl sulphonate 28214-91-7 1.00 - 15.00 % Blend of polyolefins, highly-refined mineral oil and additives. The highly refined mineral oil contains (w/w) DMSO-extract, according to IP346. The highly refined mineral oil is only present as additive diluent. Refer to chapter 16 for full text of EC R-phrases. 3. HAZARDS IDENTIFICATION Emergency Overview Appearance and Odour : Amber. Liquid at room temperature. Slight hydrocarbon. Health Hazards : Not classified as dangerous for supply or conveyance. Safety Hazards : Not classified as flammable but will burn. Environmental Hazards : Not classified as dangerous for the environment. Health Hazards : Not expected to be a health hazard when used under normal conditions. Health Hazards Inhalation : Under normal conditions of use, this is not expected to be a primary route of exposure. Skin Contact : Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Eye Contact : May cause slight irritation to eyes. Ingestion : Low toxicity if swallowed. Other Information : Used oil may contain harmful impurities. Signs and : Oil acne/folliculitis signs and may include formation of black pustules and spots on the skin of exposed areas. Ingestion may result in nausea, vomiting and/or diarrhoea. Page 995 of 1235 Page 995 of 1235 Page 995 of 1235 Page 995 of 1235 ---PAGE BREAK--- Shell Rotella T5 10W-30 MSDS# 11045DA Version 1.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 2/9 Print Date 07/03/2014 000000014560 MSDS_US Aggravated Medical Conditions : Pre-existing medical conditions of the following organ(s) or organ system(s) may be aggravated by exposure to this material: Skin. Environmental Hazards : Not classified as dangerous for the environment. Additional Information : Under normal conditions of use or in a foreseeable emergency, this product does not meet the definition of a hazardous chemical when evaluated according to the OSHA Hazard Communication Standard, 29 CFR 1910.1200. 4. FIRST-AID MEASURES General Information : Not expected to be a health hazard when used under normal conditions. Inhalation : No treatment necessary under normal conditions of use. If persist, obtain medical advice. Skin Contact : Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention. Eye Contact : Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention. Ingestion : In general no treatment is necessary unless large quantities are swallowed, however, get medical advice. Advice to Physician : Treat 5. FIRE-FIGHTING MEASURES Clear fire area of all non-emergency personnel. Flash point : > 230 °C / 446 °F (COC) Upper / lower Flammability or Explosion limits : Typical 1 - 10 Auto ignition temperature : > 320 °C / 608 °F Specific Hazards : Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide may be evolved if incomplete combustion occurs. Unidentified organic and inorganic compounds. Suitable Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media : Do not use water in a jet. Protective Equipment for Firefighters : Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space. 6. ACCIDENTAL RELEASE MEASURES Avoid contact with spilled or released material. For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on disposal. Observe the relevant local and international regulations. Page 996 of 1235 Page 996 of 1235 Page 996 of 1235 Page 996 of 1235 ---PAGE BREAK--- Shell Rotella T5 10W-30 MSDS# 11045DA Version 1.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 3/9 Print Date 07/03/2014 000000014560 MSDS_US Protective measures : Avoid contact with skin and eyes. Use appropriate containment to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately. Prevent from spreading by making a barrier with sand, earth or other containment material. Reclaim liquid directly or in an absorbent. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly. Additional Advice : Local authorities should be advised if significant spillages cannot be contained. 7. HANDLING AND STORAGE General Precautions : Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Use the information in this data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling vapour and/or mists. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Storage : Keep container closed and in a cool, well-ventilated place. Use properly labelled and closeable containers. Store at ambient temperature. Product Transfer : This material has the potential to be a static accumulator. Proper grounding and bonding procedures should be used during all bulk transfer operations. Recommended Materials : For containers or container linings, use mild steel or high density polyethylene. Unsuitable Materials : PVC. Additional Information : Polyethylene containers should not be exposed to high temperatures because of possible risk of distortion. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Material Source Type ppm mg/m3 Notation Oil mist, mineral ACGIH TWA(Inhalabl e fraction.) 5 mg/m3 Oil mist, mineral OSHA Z1 PEL(Mist.) 5 mg/m3 Biological Exposure Index (BEI) Page 997 of 1235 Page 997 of 1235 Page 997 of 1235 Page 997 of 1235 ---PAGE BREAK--- Shell Rotella T5 10W-30 MSDS# 11045DA Version 1.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 4/9 Print Date 07/03/2014 000000014560 MSDS_US No biological limit allocated. Exposure Controls : The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Adequate ventilation to control airborne concentrations. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated. Define procedures for safe handling and maintenance of controls. Educate and train workers in the hazards and control measures relevant to normal activities associated with this product. Ensure appropriate selection, testing and maintenance of equipment used to control exposure, e.g. personal protective equipment, local exhaust ventilation. Drain down system prior to equipment break-in or maintenance. Retain drain downs in sealed storage pending disposal or for subsequent recycle. Always observe good personal hygiene measures, such as washing hands after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. Personal Protective Equipment : Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers. Respiratory Protection : No respiratory protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid breathing of material. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. Select a filter suitable for combined particulate/organic gases and vapours [boiling point >65°C(149 Hand Protection : Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection: PVC, neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. For continuous contact we recommend gloves with Page 998 of 1235 Page 998 of 1235 Page 998 of 1235 Page 998 of 1235 ---PAGE BREAK--- Shell Rotella T5 10W-30 MSDS# 11045DA Version 1.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 5/9 Print Date 07/03/2014 000000014560 MSDS_US breakthrough time of more than 240 minutes with preference for > 480 minutes where suitable gloves can be identified. For short-term/splash protection we recommend the same, but recognise that suitable gloves offering this level of protection may not be available and in this case a lower breakthrough time may be acceptable so long as appropriate maintenance and replacement regimes are followed. Glove thickness is not a good predictor of glove resistance to a chemical as it is dependent on the exact composition of the glove material. Glove thickness should be typically greater than 0.35 mm depending on the glove make and model. Eye Protection : Wear safety glasses or full face shield if splashes are likely to occur. Protective Clothing : Skin protection not ordinarily required beyond standard issue work clothes. Monitoring Methods : Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate. Validated exposure measurement methods should be applied by a competent person and samples analysed by an accredited laboratory. Examples of sources of recommended exposure measurement methods are given below or contact the supplier. Further national methods may be available. National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods http://www.cdc.gov/niosh/ Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods http://www.osha.gov/ Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances http://www.hse.gov.uk/ Institut für Deutschen Gesetzlichen Unfallversicherung (IFA), Germany. http://www.dguv.de/inhalt/index.jsp L'Institut National de Recherche et de Securité, (INRS), France http://www.inrs.fr/accueil Environmental Exposure Controls : Take appropriate measures to fulfil the requirements of relevant environmental protection legislation. Avoid contamination of the environment by following advice given in Chapter 6. If necessary, prevent undissolved material from being discharged to waste water. Waste water should be treated in a municipal or industrial waste water treatment plant before discharge to surface water. Local guidelines on emission limits for volatile substances must be observed for the discharge of exhaust air containing vapour. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Amber. Liquid at room temperature. Page 999 of 1235 Page 999 of 1235 Page 999 of 1235 Page 999 of 1235 ---PAGE BREAK--- Shell Rotella T5 10W-30 MSDS# 11045DA Version 1.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 6/9 Print Date 07/03/2014 000000014560 MSDS_US Odour : Slight hydrocarbon. pH : Not applicable. Initial Boiling Point and Boiling Range : > 280 °C / 536 °F estimated value(s) Pour point : Typical -20 °C / -4 °F Flash point : > 230 °C / 446 °F (COC) Upper / lower Flammability or Explosion limits : Typical 1 - 10 Auto-ignition temperature : > 320 °C / 608 °F Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s)) Specific gravity : Typical 0.89 at 15 °C / 59 °F Density : Typical 895 kg/m3 at 15 °C / 59 °F Water solubility : Negligible. n-octanol/water partition coefficient (log Pow) : > 6 (based on information on similar products) Kinematic viscosity : > 30 mm2/s at 40 °C / 104 °F Vapour density (air=1) : > 1 (estimated value(s)) Electrical conductivity : This material is not expected to be a static accumulator. Evaporation rate (nBuAc=1) : Data not available 10. STABILITY AND REACTIVITY Stability : Stable. Conditions to Avoid : Extremes of temperature and direct sunlight. Materials to Avoid : Strong oxidising agents. Hazardous Decomposition Products : Hazardous decomposition products are not expected to form during normal storage. 11. TOXICOLOGICAL INFORMATION Basis for Assessment : Information given is based on data on the components and the toxicology of similar products. Unless indicated otherwise, the data presented is representative of the product as a whole, rather than for individual component(s). Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal conditions of use. Skin Irritation : Expected to be irritating. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Eye Irritation : Expected to be irritating. Respiratory Irritation : Inhalation of vapours or mists may cause irritation. Sensitisation : Not expected to be a skin sensitiser. Repeated Dose Toxicity : Not expected to be a hazard. Mutagenicity : Not considered a mutagenic hazard. Carcinogenicity : Not expected to be carcinogenic. Material : Carcinogenicity Classification Page 1000 of 1235 Page 1000 of 1235 Page 1000 of 1235 Page 1000 of 1235 ---PAGE BREAK--- Shell Rotella T5 10W-30 MSDS# 11045DA Version 1.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 7/9 Print Date 07/03/2014 000000014560 MSDS_US Highly refined mineral oil (IP346 : ACGIH Group A4: Not classifiable as a human carcinogen. Highly refined mineral oil (IP346 : IARC 3: Not classifiable as to carcinogenicity to humans. Highly refined mineral oil (IP346 : GHS / CLP: No carcinogenicity classification Reproductive and Developmental Toxicity : Not expected to be a hazard. Additional Information : Used oils may contain harmful impurities that have accumulated during use. The concentration of such impurities will depend on use and they may present risks to health and the environment on disposal. ALL used oil should be handled with caution and skin contact avoided as far as possible. Continuous contact with used engine oils has caused skin cancer in animal tests. 12. ECOLOGICAL INFORMATION Ecotoxicological data have not been determined specifically for this product. Information given is based on a knowledge of the components and the ecotoxicology of similar products. Unless indicated otherwise, the data presented is representative of the product as a whole, rather than for individual component(s). Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic organisms. Expected to be practically non toxic: LL/EL/IL50 > 100 mg/l (to aquatic organisms) LL/EL50 expressed as the nominal amount of product required to prepare aqueous test extract. Mobility : Liquid under most environmental conditions. If it enters soil, it will adsorb to soil particles and will not be mobile. Floats on water. Persistence/degradability : Expected to be not readily biodegradable. Major constituents are expected to be inherently biodegradable, but the product contains components that may persist in the environment. Bioaccumulation : Contains components with the potential to bioaccumulate. Other Adverse Effects : Product is a mixture of non-volatile components, which are not expected to be released to air in any significant quantities. Not expected to have ozone depletion potential, photochemical ozone creation potential or global warming potential. 13. DISPOSAL CONSIDERATIONS Material Disposal : Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations. Do not dispose into the environment, in Page 1001 of 1235 Page 1001 of 1235 Page 1001 of 1235 Page 1001 of 1235 ---PAGE BREAK--- Shell Rotella T5 10W-30 MSDS# 11045DA Version 1.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 8/9 Print Date 07/03/2014 000000014560 MSDS_US drains or in water courses. Container Disposal : Dispose in accordance with prevailing regulations, preferably to a recognised collector or contractor. The competence of the collector or contractor should be established beforehand. Local Legislation : Disposal should be in accordance with applicable regional, national, and local laws and regulations. 14. TRANSPORT INFORMATION US Department of Transportation Classification (49CFR) This material is not subject to DOT regulations under 49 CFR Parts 171-180. IMDG This material is not classified as dangerous under IMDG regulations. IATA (Country variations may apply) This material is either not classified as dangerous under IATA regulations or needs to follow country specific requirements. 15. REGULATORY INFORMATION The regulatory information is not intended to be comprehensive. Other regulations may apply to this material. Federal Regulatory Status Notification Status EINECS All components listed or polymer exempt. TSCA All components listed. DSL All components listed. Comprehensive Environmental Release, Compensation & Liability Act (CERCLA) Zinc alkyl dithiophosphate (68649- 42-3) Shell classifies this material as an "oil" under the CERCLA Petroleum Exclusion, therefore releases to the environment are not reportable under CERCLA. Page 1002 of 1235 Page 1002 of 1235 Page 1002 of 1235 Page 1002 of 1235 ---PAGE BREAK--- Shell Rotella T5 10W-30 MSDS# 11045DA Version 1.1 Material Safety Data Sheet Effective Date 02/05/2014 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 9/9 Print Date 07/03/2014 000000014560 MSDS_US SARA Hazard Categories (311/312) No SARA 311/312 Hazards. SARA Toxic Release Inventory (TRI) (313) Zinc alkyl dithiophosphate (68649- 42-3) 5.00% State Regulatory Status California Safe Drinking Water and Toxic Enforcement Act (Proposition 65) This material does not contain any chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. New Jersey Right-To-Know Chemical List Zinc alkyl dithiophosphate (68649-42-3) 5.00% Listed. 16. OTHER INFORMATION NFPA Rating (Health, Fire, Reactivity) : 0, 1, 0 SDS Version Number : 1.1 SDS Effective Date : 02/05/2014 SDS Revisions : A vertical bar in the left margin indicates an amendment from the previous version. SDS Regulation : The content and format of this MSDS is in accordance with the OSHA Hazard Communication Standard, 29 CFR 1910.1200. SDS Distribution : The information in this document should be made available to all who may handle the product. Disclaimer : The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of health, safety and environmental requirements only. No warranty or guarantee is expressed or implied regarding the accuracy of these data or the results to be obtained from the use of the product. Page 1003 of 1235 Page 1003 of 1235 Page 1003 of 1235 Page 1003 of 1235 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET TRANSMITTAL Request Date 7/11/2008 MSDS Number 001168 Product Group 2 Mag Part Number 703-003-021 Material Name SHELLZONE ALL-SEASON ANTIFREEZE/COOLANT [PHONE REDACTED] Manufacturer's Name SOPUS PRODUCTS Supplier's Name SOPUS PRODUCTS Requestor KURT SAUTTER Dept Name VEHICLE MAINTENANCE Department Number 485 Proposed Or Intended Use(s) Of This Material: FOR MAG VEHICLES AND FORKLIFTS AND OTHER MATERIAL HANDLING EQUIPMENT Building(s)/Location(s) Where The Material Will Be Used: 1555 S. BAKER Dept. Number(s) 485 Storage Location: (State if different from above, or in addition to where the material will be used.) Dept Number(s) Check The Applicable Box(es) For The Proposed Change(s) Below: Production Operating Supply ;Maintenance Construction Special Use (e.g. rework project, R&D, etc.) Total Quantity Purchased: 1 Unit Of Measure: CS Container Size (i.e. oz., qt., etc.) GL Buyer's Name: MELINDA WOODWARD Approved For Use: ; Yes No Proposition 65 Chemical: Yes ; No CAL/OSHA 339 Chemical: ; Yes No NFPA Rating 1 Fire Hazard 2 Health Hazard 0 Reactivity Specific Hazard: ACID-Acid ALK-Alkali COR-Corrosive OXY-Oxidizer P-Polymerization Radioactive Use No Water Personal Protection Equipment: Wear nitrile gloves and safety glasses with nitrile. Training Resources/Requirements: Notes: Attach MSDS Or Supplemental Materials Shellzone All-Season Antifreeze-Coolant MSDS.pdf Adobe Acrobat 7.0 Document 1.83 MB Page 1004 of 1235 Page 1004 of 1235 Page 1004 of 1235 Page 1004 of 1235 ---PAGE BREAK--- Expiration Date: (Automatic 1 Year From Submittal) Approved By: Sam Olaluwoye Sam Olaluwoye / Gus Hawthorn Distribution: ; MSDS Online ; Dept Used KURT SAUTTER ; Safety Committee Cindy Samarin, Jim Zecchini, Gus Hawthorn, Sam Olaluwoye, Gus Hawthorn, Jeff Roop, Julie Rodriguez, John Maglica, Randy Fick, Tony Maglica Jr, Sandra Lyster ; Buyer Melinda Woodward 703-016-160 2/07 Page 1005 of 1235 Page 1005 of 1235 Page 1005 of 1235 Page 1005 of 1235 ---PAGE BREAK--- Page 1006 of 1235 Page 1006 of 1235 Page 1006 of 1235 Page 1006 of 1235 ---PAGE BREAK--- Page 1007 of 1235 Page 1007 of 1235 Page 1007 of 1235 Page 1007 of 1235 ---PAGE BREAK--- Page 1008 of 1235 Page 1008 of 1235 Page 1008 of 1235 Page 1008 of 1235 ---PAGE BREAK--- Page 1009 of 1235 Page 1009 of 1235 Page 1009 of 1235 Page 1009 of 1235 ---PAGE BREAK--- Page 1010 of 1235 Page 1010 of 1235 Page 1010 of 1235 Page 1010 of 1235 ---PAGE BREAK--- Page 1011 of 1235 Page 1011 of 1235 Page 1011 of 1235 Page 1011 of 1235 ---PAGE BREAK--- Page 1012 of 1235 Page 1012 of 1235 Page 1012 of 1235 Page 1012 of 1235 ---PAGE BREAK--- Page 1013 of 1235 Page 1013 of 1235 Page 1013 of 1235 Page 1013 of 1235 ---PAGE BREAK--- Page 1014 of 1235 Page 1014 of 1235 Page 1014 of 1235 Page 1014 of 1235 ---PAGE BREAK--- 20 September 2013 Date of printing Material Safety Data Sheet Akzo Nobel Coatings Inc. encourages and expects you to read and understand this entire MSDS, as there is important information throughout the document. Further, Akzo Nobel Coatings Inc. expects you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. To promote safe handling, each customer or recipient should: 1) Notify its employees, agents, contractors, and others whom it knows or believes will use this material of the information contained in this MSDS and any other information regarding hazards and safety; 2) Furnish this same information to each of its customers for the product; 3) Request its customers to notify their employees, customers, and other users of the product of this information; and 4) Notify its employees, agents, contractors, and others that the precautions identified for this product and any other products with which mixtures may be created are transferable and cumulative to the mixture. CHEMTREC (800) 424-9300 (Inside the US) IN CASE OF EMERGENCY (HEALTH OR SPILLS): CHEMTREC International +1 (703) 527-3887 (Outside the US, collect calls accepted) Product code 500324 : Product name SIKKENS MATTE SELECT NA 1QT MSDS # For the most recent update to this Material Safety Data Sheet, visit our website at http://www.akzonobelcarrefinishes.net For additional information call the Akzo Nobel Car Refinishes Techline at 1-[PHONE REDACTED]. RA16147 Akzo Nobel Coatings, Inc. 3587 Parkway Lane, NW Norcross GA 30092 USA 1-[PHONE REDACTED] Manufacturer Akzo Nobel Coatings Ltd. 110 Woodbine Downs Blvd. Unit #4 Etobicoke, Ontario Canada M9W 5S6 1-[PHONE REDACTED] Canadian Supplier Date of issue 9/20/2013. Version 1.01 : : : : : Section 1. Chemical product and company identification Emergency overview Potential acute health effects Irritating to respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Severely irritating to eyes. Risk of serious damage to eyes. Harmful if swallowed. Harmful in contact with skin. Irritating to skin. Eyes Skin Inhalation Ingestion WARNING! FLAMMABLE LIQUID AND VAPOR. CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION. MAY BE HARMFUL IF ABSORBED THROUGH SKIN OR IF SWALLOWED. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON ANIMAL DATA. POSSIBLE BIRTH DEFECT HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE BIRTH DEFECTS, BASED ON ANIMAL DATA. : : : : : Section 2. Hazards identification Potential chronic health effects Chronic effects : Contains material that may cause target organ damage, based on animal data. Akzo Nobel Coatings Inc. Page 1015 of 1235 Page 1015 of 1235 Page 1015 of 1235 Page 1015 of 1235 ---PAGE BREAK--- RA16147 Page: 2/9 Section 2. Hazards identification See toxicological information (Section 11) Medical conditions aggravated by over- exposure Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. : Carcinogenicity : Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : Contains material which may cause birth defects, based on animal data. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Over-exposure Ingestion : Adverse may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Skin : Adverse may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations Eyes : Adverse may include the following: pain or irritation watering redness reduced fetal weight increase in fetal deaths skeletal malformations Inhalation : Adverse may include the following: respiratory tract irritation coughing reduced fetal weight increase in fetal deaths skeletal malformations Target organs : Contains material which may cause damage to the following organs: blood, kidneys, lungs, the nervous system, liver, gastrointestinal tract, cardiovascular system, upper respiratory tract, skin, central nervous system (CNS), ears, eye, lens or cornea. 4-chloro-α,α,α-trifluorotoluene 98-56-6 40 - 70 xylene 1330-20-7 5 - 10 25973-55-1 5 - 10 bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate 41556-26-7 1 - 5 100-41-4 1 - 5 methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate 82919-37-7 1 - 5 Name CAS number % United States Section 3. Composition/information on ingredients There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Akzo Nobel Coatings Inc. Page 1016 of 1235 Page 1016 of 1235 Page 1016 of 1235 Page 1016 of 1235 ---PAGE BREAK--- RA16147 Page: 3/9 Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion In case of inhalation of decomposition products in a fire, may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Notes to physician : : : : : Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Use dry chemical, CO₂, water spray (fog) or foam. Section 5. Fire-fighting measures Extinguishing media isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : Special exposure hazards : Do not use water jet. Suitable : Not suitable : Hazardous thermal decomposition products : Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides halogenated compounds carbonyl halides metal oxide/oxides Flammability of the product : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section Environmental precautions Section 6. Accidental release measures : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions : Akzo Nobel Coatings Inc. Page 1017 of 1235 Page 1017 of 1235 Page 1017 of 1235 Page 1017 of 1235 ---PAGE BREAK--- RA16147 Page: 4/9 Section 6. Accidental release measures Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion- proof equipment. Dispose of via a licensed waste disposal contractor. Small spill : Methods for cleaning up Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Put on appropriate personal protective equipment (see Section Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Avoid exposure during pregnancy. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. Section 7. Handling and storage Handling Storage : : xylene ACGIH TLV (United States, 3/2012). STEL: 651 mg/m³ 15 minutes. STEL: 150 ppm 15 minutes. TWA: 434 mg/m³ 8 hours. TWA: 100 ppm 8 hours. OSHA PEL (United States, 6/2010). TWA: 435 mg/m³ 8 hours. TWA: 100 ppm 8 hours. ACGIH TLV (United States, 3/2012). TWA: 20 ppm 8 hours. NIOSH REL (United States, 6/2009). STEL: 545 mg/m³ 15 minutes. STEL: 125 ppm 15 minutes. TWA: 435 mg/m³ 10 hours. Section 8. Exposure controls/personal protection Product name Exposure limits United States Akzo Nobel Coatings Inc. Page 1018 of 1235 Page 1018 of 1235 Page 1018 of 1235 Page 1018 of 1235 ---PAGE BREAK--- RA16147 Page: 5/9 Section 8. Exposure controls/personal protection TWA: 100 ppm 10 hours. OSHA PEL (United States, 6/2010). TWA: 435 mg/m³ 8 hours. TWA: 100 ppm 8 hours. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Personal protection Eyes Skin Respiratory Consult local authorities for acceptable exposure limits. : : : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Hands : Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/ or hazardous fumes. Wet sanding/flatting should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Akzo Nobel Coatings Inc. Page 1019 of 1235 Page 1019 of 1235 Page 1019 of 1235 Page 1019 of 1235 ---PAGE BREAK--- RA16147 Page: 6/9 136°C (276.8°F) Liquid. Not available. Not available. 1.271 Not available. Not available. Not available. Not available. Boiling/condensation point Melting/freezing point Section 9. Physical and chemical properties Physical state pH Specific gravity Vapor pressure Odor threshold Odor Appearance : : : : : : : : : Flash point : Closed cup: 29°C (84.2°F) Not available. : Auto-ignition temperature Flammable limits : Not available. Vapor density : Heavier than air Density : 10.61 lbs per gal 1.271 g/cm³ Weight Volatiles : 66.55% (w/w) Volume Volatiles : 68.01 Weight Solids : 33.45 Volume Solids : 31.99 VOC : 2.2 lbs/gal (264 g/l) Dispersibility properties : Not dispersible in the following materials: cold water. The product is stable. Reactive or incompatible with the following materials: oxidizing materials Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Section 10. Stability and reactivity Stability Conditions to avoid Materials to avoid Hazardous decomposition products Hazardous polymerization : : : : : Flammable in the presence of the following materials or conditions: open flames, sparks and static discharge and oxidizing materials. Conditions of reactivity : United States Section 11. Toxicological information Acute toxicity 4-chloro-α,α,α-trifluorotoluene LD50 Dermal Rabbit >2700 mg/kg LD50 Dermal Rabbit >2700 mg/kg LD50 Oral Rat 13 g/kg LD50 Oral Rat >6800 mg/kg LD50 Oral Rat >6800 mg/kg LC50 Inhalation Vapor Rat 22000 mg/m³ LC50 Inhalation Vapor Rat 22000 mg/m³ xylene LD50 Intraperitoneal Rat 2459 mg/kg LD50 Oral Rat 4300 mg/kg LD50 Subcutaneous Rat 1700 mg/kg TDLo Dermal Rabbit 4300 mg/kg LD50 Dermal Rabbit >5000 mg/kg LD50 Dermal Rabbit 17800 uL/kg Product/ingredient name Result Species Dose Akzo Nobel Coatings Inc. Page 1020 of 1235 Page 1020 of 1235 Page 1020 of 1235 Page 1020 of 1235 ---PAGE BREAK--- RA16147 Page: 7/9 Section 11. Toxicological information LD50 Oral Rat 3500 mg/kg TDLo Dermal Rat 0.08 mL/kg TDLo Intraperitoneal Rat 1062 mg/kg Conclusion/Summary : Not available. Chronic toxicity Conclusion/Summary : Not available. Carcinogenicity Conclusion/Summary : Not available. Mutagenicity Conclusion/Summary : Not available. Teratogenicity Conclusion/Summary : Not available. Reproductive toxicity Conclusion/Summary : Not available. Classification xylene A4 3 - None. - - A3 2B - None. - - Product/ingredient name ACGIH EPA NIOSH NTP IARC OSHA Irritation/Corrosion Product/ingredient name Result Score Exposure Observation Conclusion/Summary : Not available. Sensitizer Conclusion/Summary : Not available. Species xylene Eyes - Mild irritant Rabbit - 87 milligrams - Eyes - Severe irritant Rabbit - 24 hours 5 milligrams - Skin - Mild irritant Rat - 8 hours 60 microliters - Skin - Moderate irritant Rabbit - 24 hours 500 milligrams - Skin - Moderate irritant Rabbit - 100 Percent - Eyes - Severe irritant Rabbit - 500 milligrams - Skin - Mild irritant Rabbit - 24 hours 15 milligrams - Environmental effects : No known significant effects or critical hazards. : Not available. Biodegradability : Not available. Aquatic ecotoxicity Other adverse effects : No known significant effects or critical hazards. Section 12. Ecological information : Ecotoxicological data for one or more components are known and will be made available on request. Akzo Nobel Coatings Inc. Page 1021 of 1235 Page 1021 of 1235 Page 1021 of 1235 Page 1021 of 1235 ---PAGE BREAK--- RA16147 Page: 8/9 The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal Section 13. Disposal considerations Disposal should be in accordance with applicable regional, national and local laws and regulations. : Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 14. Transport information Consult your shipping specialist or supplier for appropriate assignment of the DOT information. Section 15. Regulatory information WHMIS (Canada) Class B-2: Flammable liquid Class D-1B: Material causing immediate and serious toxic effects (Toxic). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). : SARA 313 Canada United States Product name CAS number Concentration EU regulations : Hazard symbol or symbols : xylene 1330-20-7 5 - 10 100-41-4 1 - 5 Form R - Reporting requirements : United States inventory (TSCA 8b) : All components are listed or exempted. Canada inventory : All components are listed or exempted. Hazard symbol or symbols Not available. OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). : California Prop. 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. Akzo Nobel Coatings Inc. Page 1022 of 1235 Page 1022 of 1235 Page 1022 of 1235 Page 1022 of 1235 ---PAGE BREAK--- RA16147 Page: 9/9 Section 15. Regulatory information Australia inventory (AICS): All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. Japan inventory: All components are listed or exempted. Korea inventory: All components are listed or exempted. Malaysia Inventory (EHS Register): At least one component is not listed. New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted. Philippines inventory (PICCS): All components are listed or exempted. Taiwan inventory (CSNN): At least one component is not listed. International regulations International lists : S24- Avoid contact with skin. S37- Wear suitable gloves. S61- Avoid release to the environment. Refer to special instructions/safety data sheet. R10- Flammable. R43- May cause sensitization by skin contact. R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Risk phrases Safety phrases : Section 16. Other information Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Page 1023 of 1235 Page 1023 of 1235 Page 1023 of 1235 Page 1023 of 1235 ---PAGE BREAK--- SOFT CARE LOTIONIZED HAND SOAP 5454 & 5468 & 5475 & 5487 & 5500 & 5564 & 5593 Industrial/Institutional: Personal care product. 2/25/2003 2/25/2003 Material Safety Data Sheet Product Name Product Use Validation Date Print Date In Case of Emergency Section 1. Chemical Product and Company Identification Supersedes No Previous Validation Health 1 0 0 Fire Hazard Reactivity Specific Hazard Health Fire Hazard Reactivity Protective Clothing 0 0 1 (800) 851-7145 Johnson Wax Professional 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249 MSDS Internet Address: www.jwp.com U.S. Headquarters Johnson Wax Professional 100 Matheson Blvd. East, Suite 203 Mississauga, Ontario L4Z 2G7 Phone: (905) 755-0913 or (888) 746-5971 Hazardous Material Information System (HMIS) National Fire Protection Association (NFPA) Code MSDS# 115500008 3043938 Canadian Headquarters Pink. Liquid. See Section 9. CAUTION: May be mildly irritating to eyes. Emergency Overview None required. PMS# SOFT CARE LOTIONIZED HAND SOAP Cocamide Diethanolamine 61791-31-9 1-5 Not available. Not available. Ammonium Lauryl Sulfate 68081-96-9 1-5 Not available. Not available. Ammonium Laureth Sulfate 67762-19-0 1-5 Not available. Not available. Water 7732-18-5 60-100 Not available. Not available. Section 2. Composition and Information on Ingredients Ingredients CAS # % by Weight Exposure Limits LC50/LD50 Inhalation. Eye contact. Medical Conditions Aggravated by Overexposure: Persons with pre-existing skin disorders may be more susceptable to irritating effects. Section 3. Hazards Identification Routes of Entry Potential Acute Health Effects None known. May be mildly irritating to eyes. May cause abdominal discomfort, nausea, vomiting and diarrhea. Prolonged or repeated contact may dry skin and cause irritation. Eyes Skin Inhalation Ingestion See Toxicological Information (section 11) Immediately drink plenty of water. If discomfort persists, get medical attention. Flush immediately with plenty of water. Get medical attention if irritation occurs. Rinse with plenty of running water. No specific first aid measures are required. Section 4. First Aid Measures Eye Contact Skin Contact Inhalation Ingestion Continued on Next Page Page: 1/3 Page 1024 of 1235 Page 1024 of 1235 Page 1024 of 1235 Page 1024 of 1235 ---PAGE BREAK--- Material Safety Data Sheet SOFT CARE LOTIONIZED HAND SOAP None known. None known. Not available. Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire fighting procedure may be used. None known. Section 5. Fire Fighting Measures Flammability of the Product Flash Points Products of Combustion Fire Fighting Media and Instructions Special Remarks on Fire and Explosion Hazards In the event of major spillage: Use appropriate containment to avoid environmental contamination. Sweep or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a water rinse for final clean-up. Put on appropriate personal protective equipment (see Section Section 6. Accidental Release Measures Personal Precautions Environmental Precautions and Clean-up Methods Store in a dry, cool and well-ventilated area. Protect from freezing. KEEP OUT OF REACH OF CHILDREN. Avoid contact with eyes. Use appropriate hygiene measures when handling product. FOR INDUSTRIAL USE ONLY. Section 7. Handling and Storage Handling Storage No special ventilation requirements. General room ventilation is adequate. Section 8. Exposure Controls/Personal Protection Engineering Controls No special requirements under normal use conditions. No special requirements under normal use conditions. No special protective clothing is required. No special requirements under normal use conditions. No special requirements under normal use conditions. Personal Protection Eyes Hands Respiratory Feet Body 93°C (199.4°F) Liquid. 6.3 to 7 [Neutral.] 1.01 Fragrance like. Pink. Boiling/Condensation Point 2000-4000 cP (Dynamic). Section 9. Physical and Chemical Properties Physical State and Appearance pH Specific Gravity Viscosity Solubility in water Odor Color Complete. The product is stable. Not available. Will not occur. When exposed to fire: Produces normal products of combustion. None known. Section 10. Stability and Reactivity Stability and Reactivity Conditions of Instability Incompatibility with Various Substances Hazardous Decomposition Products Hazardous Polymerization Continued on Next Page Page: 2/3 Page 1025 of 1235 Page 1025 of 1235 Page 1025 of 1235 Page 1025 of 1235 ---PAGE BREAK--- Material Safety Data Sheet SOFT CARE LOTIONIZED HAND SOAP Section 11. Toxicological Information Effects of Chronic Exposure Other Toxic Effects None known. ORAL (LD50) Greater than 20000 mg/kg (rat). DERMAL (LD50) Estimated to be greater than 2000 mg/kg (rabbit). Acute toxicity Not available. Section 12. Ecological Information Not available. No special precautions. Dispose of according to all federal, state and local regulations. Waste Information Section 13. Disposal Considerations Please refer to the Bill of Lading/receiving documents for up to date shipping information. Section 14. Transport Information DOT Classification DOT Proper Shipping Name TDG Classification TDG Proper Shipping Name Please refer to the Bill of Lading/receiving documents for up to date shipping information. Section 15. Regulatory Information Chemical Inventory Status Canadian Regulations Not applicable. All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory Registered Product Information Reporting in this section is based on ingredients disclosed in Section 2 WHMIS Classification WHMIS Icon Registered Product Information Not applicable. Not applicable. US Regulations This product is not subject to the reporting requirements under California's Proposition 65. Not available. Section 16. Other Information Other Special Considerations Notice to Reader This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Version 1 Page 1026 of 1235 Page 1026 of 1235 Page 1026 of 1235 Page 1026 of 1235 ---PAGE BREAK--- Softsoap Antibacterial Hand Soap 1 COLGATE-PALMOLIVE Company MATERIAL SAFETY DATA SHEET This industrial Material Safety Data Sheet is intended for use by workers in the workplace. It does not apply to consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Softsoap Antibacterial Hand Soap Effective Date: April 30, 2002 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Acute Health…1 Fire…………….0 Reactivity…….0 PRODUCT NAME: Softsoap Antibacterial Hand Soap SKU#: 1901 CAS NUMBER: Not applicable – product is a mixture GENERAL USE: A liquid soap formulated for industrial and institutional use. COLGATE-PALMOLIVE COMPANY Institutional Products Division 191 East Hanover Avenue Morristown NJ 07962 EMERGENCY TELEPHONE NUMBER: For emergency involving spill, leak, fire, exposure or accident, call CHEMTREC (800) 424-9300, day or night THE PITTSBURGH POISON CENTER HAS BEEN PROVIDED SPECIFIC INFORMATION FOR USE IN MEDICAL EMERGENCIES INVOLVING THIS PRODUCT: CALL COLLECT: (412) 692-5596. 2. COMPOSITION/INFORMATION ON INGREDIENTS OSHA-REGULATED COMPONENTS (present at a concentration of > or = Component CAS# % PEL TLV Not Applicable The following components, present at a concentration of > or = 0.1%, are listed as carcinogens or potential carcinogens by either the National Toxicology Program (NTP), the International Agency for Research on Cancer (IARC) or OSHA: Component CAS# % PEL TLV Not Applicable 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Causes eye irritation on direct contact, but no permanent eye injury is expected. SKIN CONTACT: May cause skin irritation on prolonged or excessive contact. INGESTION: May be harmful if swallowed in large quantities. INHALATION: No adverse effects expected. 4. FIRST AID MEASURES EYE CONTACT: Flush eyes with large amounts of water for 15 minutes. Get medical attention if irritation persists. SKIN CONTACT: Rinse area with plenty of water. Get medical attention if irritation persists. INGESTION: Drink 1-2 glasses of a clear liquid. Get medical attention. INHALATION: Not Applicable. HMIS HAZARD RATING Least=0 Slight=1 Moderate=2 High=3 Extreme =4 Page 1027 of 1235 Page 1027 of 1235 Page 1027 of 1235 Page 1027 of 1235 ---PAGE BREAK--- Softsoap Antibacterial Hand Soap 2 5. FIRE FIGHTING MEASURES Flash Point (Method): Not Applicable Extinguishing Media: Water spray, all-purpose dry chemical, CO2. SPECIAL FIRE FIGHTING PROCEDURES: Self-contained breathing apparatus and protective clothing should be worn when fighting chemical fires. 6. ACCIDENTAL RELEASE MEASURES Cover with inert, absorbent material and remove to disposal container. Spill area may be slippery. Flush with plenty of water. 7. HANDLING AND STORAGE Store in a closed container in a cool, dry, well-ventilated area. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION GENERAL CONTROLS: Avoid eye contact. PROTECTIVE CLOTHING: The use of safety goggles and protective gloves is recommended in soaking or spraying operations where splashing may occur. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Viscous liquid pH: 6.7 0.7 10. STABILITY AND REACTIVITY GENERAL: This product is stable. Hazardous polymerization will not occur. INCOMPATIBLE MATERIALS: None known HAZARDOUS DECOMPOSITION: None known 11. TOXICOLOGICAL INFORMATION This product has not been tested as a whole. However, this formula was reviewed by expert toxicologists in the Product Safety Assurance Department of Colgate-Palmolive and is determined to be safe for its intended use. This review has taken into consideration available safety-related information including information on individual ingredients, similar ingredients, similar formulas and potential ingredient interactions. This review is a component of the hazard determination used to prepare the statements in Section 3 of the MSDS. 12. ECOLOGICAL INFORMATION Not Available 13. DISPOSAL CONSIDERATIONS Any disposal practice must be in compliance with local, state, and federal laws and regulations (contact local or state environmental agency for specific rules). Do not dump into sewers, any body of water or onto the ground. Page 1028 of 1235 Page 1028 of 1235 Page 1028 of 1235 Page 1028 of 1235 ---PAGE BREAK--- Softsoap Antibacterial Hand Soap 3 14. TRANSPORTATION This product is not regulated as a DOT hazardous material. 15. REGULATORY INFORMATION RCRA (40 CFR 261, Subpart Not Applicable CLEAN WATER ACT: Not Applicable CLEAN AIR ACT: Contains diethanolamine which is a Section 111 material. SARA: Sections 301-304 (Threshold planning quantity - TPQ) 40 CFR 355: Not Applicable Section 313 (Toxic chemical release reporting) 40 CFR 372: The following chemicals must be reported under SARA 313: Not Applicable CERCLA: Section 102 (Reportable Quantity - RQ) 40 CFR 302: The Reportable Quantity (RQ) for this product to the environment is 50,000 lbs. based on the presence of diethanolamine Releases greater than or equal to 50,000 must be reported to the National Response Center (NRC) immediately: [PHONE REDACTED]. New Jersey Right to Know Hazardous Substance List: This product contains the following components subject to reporting requirements: Diethanolamine Hazardous Substance List: This product contains the following components subject to reporting requirements: None Massachusetts Substance List: This product contains the following components subject to reporting requirements: Diethanolamine California Safe Drinking Water and Toxic Enforcement Act (Proposition 65): This product contains the following components subject to reporting requirements: None Canada: Workplace Hazardous materials Information System (WHMIS)-listed material. This product contains the following components subject to reporting requirements: None 16. OTHER INFORMATION Effective Date: April 30, 2002 Supersedes MSDS dated December 19, 2000 MSDS Status: Revised section 1,3,4,8,9,11 The information on this sheet is limited to the material identified and is believed by the Colgate-Palmolive Company to be correct based on its knowledge and information as of the date noted. Colgate makes no representation, guarantee or warranty, expressed or implied, as to the accuracy, reliability or completeness of the information and assumes no responsibility for injury, damage or loss resulting from the use of the material. Page 1029 of 1235 Page 1029 of 1235 Page 1029 of 1235 Page 1029 of 1235 ---PAGE BREAK--- Softsoap Cucumber Melon LHS This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 Revision Date 09/21/2010 Print Date 09/21/2010 1 / 7 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Softsoap Cucumber Melon LHS MSDS Number 200000012150 CAS-No. : Not applicable - product is a mixture General Use : Personal care A formulated liquid hand soap. Company : Colgate-Palmolive Co 300 Park Avenue New York, NY 10022 Telephone : Emergency telephone number : For emergency involving spill, leak, fire, exposure or accident, call CHEMTREC (800)424-9300, day or night. Medical Emergency (24HR): For MEDICAL EMERGENCIES involving this product call: (888) 489-3861 SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Form : Liquid Appearance : Light green Odour : Characteristic Potential Health Effects Eye contact : Causes eye irritation on direct contact. Skin contact : Prolonged or repeated skin contact may cause irritation. Inhalation : No adverse effects due to inhalation are expected. Ingestion : May be harmful if swallowed in large quantities. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components OSHA-REGULATED COMPONENTS (present at a concentration of > or = Chemical Name CAS-No. Concentration * C10-16 ALCOHOL EO SODIUM SULFATE 68585-34-2 5.00 - 10.00 COCAMIDOPROPYL BETAINE 61789-40-0 1.00 - 5.00 * All concentrations are present by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Page 1030 of 1235 Page 1030 of 1235 Page 1030 of 1235 Page 1030 of 1235 ---PAGE BREAK--- Softsoap Cucumber Melon LHS This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 Revision Date 09/21/2010 Print Date 09/21/2010 2 / 7 Carcinogenicity: Listed Carcinogens: The following components, present at a concentration of > or = 0.1%, are listed as carcinogens or potential carcinogens by either the National Toxicology Program (NTP), the International Agency for Research on Cancer (IARC), OSHA or ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. SECTION 4. FIRST AID MEASURES First aid procedures Eye contact : Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical attention. Skin contact : Flush skin with large amounts of water. If irritation develops and persists, get medical attention. Inhalation : Remove victim to fresh air. Get medical attention, if persist. Ingestion : Drink 8 ounces of clear water. Get medical attention. SECTION 5. FIRE-FIGHTING MEASURES Flammable properties Flash point : > 200 °F 93 Fire fighting Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Protective equipment and precautions for firefighters Special protective equipment for fire-fighters : Self-contained breathing apparatus and full protective clothing should be worn when fighting chemical fires. Page 1031 of 1235 Page 1031 of 1235 Page 1031 of 1235 Page 1031 of 1235 ---PAGE BREAK--- Softsoap Cucumber Melon LHS This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 Revision Date 09/21/2010 Print Date 09/21/2010 3 / 7 SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Use personal protection recommended in Section 8 of the MSDS. Methods for containment / Methods for cleaning up : Cover with inert, absorbent material and remove to disposal container. Spill area may be slippery. Flush with plenty of water. SECTION 7. HANDLING AND STORAGE Storage Requirements for storage areas and containers : Store at controlled room temperature at 20-25°C (68-77°F). SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Engineering Controls : In an industrial work environment, no special precautions or control measures are required. Personal protective equipment Protective measures : In an industrial work environment, if a splash is likely, chemical goggles may be needed. Prolonged skin contact may require protective goggles. For consumer use, no unusual precautions are necessary. General Hygiene Considerations : In an industrial work environment, avoid eye and prolonged skin contact. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Form : Liquid Appearance : Light green Odour : Characteristic Flash point : > 200 °F 93 pH : 6.0 - 7.4 Page 1032 of 1235 Page 1032 of 1235 Page 1032 of 1235 Page 1032 of 1235 ---PAGE BREAK--- Softsoap Cucumber Melon LHS This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 Revision Date 09/21/2010 Print Date 09/21/2010 4 / 7 Density : 1.0 g/cm3 Viscosity, dynamic : 2,500 - 6,100 mPa.s SECTION 10. STABILITY AND REACTIVITY Materials to avoid : Remarks: Strong oxidizing agents Hazardous decomposition products : Note: None known. Hazardous reactions : Hazardous polymerisation does not occur. SECTION 11. TOXICOLOGICAL INFORMATION This product has not been tested as a whole. However, this formula was reviewed by expert toxicologists in the Product Safety Assurance Department of Colgate-Palmolive and is determined to be safe for its intended use. This review has taken into consideration available safety-related information including information on individual ingredients, similar formulas and potential ingredient interactions. This review is a component of the hazard determination used to prepare the statements in Section 3 of the MSDS. SECTION 12. ECOLOGICAL INFORMATION The product has not been tested as a whole for environmental toxicity. However, environmental information on the ingredients in this product have been reviewed by the Environmental Occupational Health and Safety group of Colgate-Palmolive and determined to have an acceptable environmental profile. This evaluation is based on available information on individual ingredients, interactions of ingredients, and similar ingredients. Biodegradability claims are supported by data on ingredients surfactants are biodegradable) or testing conducted on the final product This product is biodegradable). SECTION 13. DISPOSAL CONSIDERATIONS Further information : Any disposal practice must be in compliance with local, state and federal laws and regulations (contact local or state environment agency for specific rules). Do not dump in sewers, any body of water or on the ground. SECTION 14. TRANSPORT INFORMATION DOT : Not regulated. Page 1033 of 1235 Page 1033 of 1235 Page 1033 of 1235 Page 1033 of 1235 ---PAGE BREAK--- Softsoap Cucumber Melon LHS This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 Revision Date 09/21/2010 Print Date 09/21/2010 5 / 7 TDG : Not regulated. IATA : Not regulated. IMDG : Not regulated. SECTION 15. REGULATORY INFORMATION US Regulations SARA Section 302 Extremely Hazardous Substances (40 CFR 355, Appendix A) : FORMALDEHYDE CERCLA Hazardous Substance List (40 CFR 302.4) - Reportable Quantity : 429824 lbs FORMALDEHYDE 99796415 lbs DISODIUM HYDROGENORTHOPHOSPHATE 167400439 lbs METHANOL Clean Air Act Clean Air Act 111 Standards of Performance for New Stationary Sources : FORMALDEHYDE METHANOL CITRIC ACID Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) : FORMALDEHYDE Sulfuric Acid Clean Water Act Page 1034 of 1235 Page 1034 of 1235 Page 1034 of 1235 Page 1034 of 1235 ---PAGE BREAK--- Softsoap Cucumber Melon LHS This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 Revision Date 09/21/2010 Print Date 09/21/2010 6 / 7 Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3) : FORMALDEHYDE DISODIUM HYDROGENORTHOPHOSPHATE Sulfuric Acid State Regulations Massachusetts Right-To- Know List : FORMALDEHYDE New Jersey Right-To- Know List : WATER C10-16 ALCOHOL EO SODIUM SULFATE COCAMIDOPROPYL BETAINE SODIUM CHLORIDE Right-To- Know List : WATER C10-16 ALCOHOL EO SODIUM SULFATE FORMALDEHYDE Canada Canadian Workplace Hazardous Materials Information System (WHMIS) Listed Material : SODIUM CHLORIDE Canadian Controlled Products Regulations: This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. Other Information In accordance with OSHA 29 CFR 1910.1048 formaldehyde is not listed in Section 3 of this MSDS, however, formaldehyde is regulated by State and Federal regulations at varying concentrations. State and Federal information can be found above in Section 15. SECTION 16. OTHER INFORMATION Further information MSDS Number : 200000012150 Disclaimer: The information on this sheet is limited to the material identified and is believed by the Colgate-Palmolive Company to be correct based on its knowledge and information as of the date noted. Colgate makes no representation, guarantee or warranty, expressed or implied, as to the accuracy, reliability or completeness of the information and assumes no responsibility for injury, damage or loss Page 1035 of 1235 Page 1035 of 1235 Page 1035 of 1235 Page 1035 of 1235 ---PAGE BREAK--- Softsoap Cucumber Melon LHS This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 Revision Date 09/21/2010 Print Date 09/21/2010 7 / 7 resulting from the use of the material. Page 1036 of 1235 Page 1036 of 1235 Page 1036 of 1235 Page 1036 of 1235 ---PAGE BREAK--- Common Name: SPLASH RV AND MARINE ANTIFREEZE Manufacturer: SUPERCLEAN BRANDS MSDS Revision Date: 12/12/2007 Grainger Item Number(s): 2EXW9 Manufacturer Model Number(s): MSDS Table of Contents Click the desired link below to jump directly to that section in the MSDS. SECTION 1 - MANUFACTURER'S INFORMATION SECTION 2 - NORMAL HANDLING PROCEDURES SECTION 3 - HAZARDOUS INGREDIENTS SECTION 4 - FIRE AND EXPLOSION HAZARD DATA SECTION 5 - HEALTH HAZARD DATA SECTION 6 - TOXICOLOGY (PRODUCT) SECTION 7 - SPILL AND LEAKAGE PROCEDURES SECTION 8 - SHIPPING DATA SECTION 9 - REACTIVITY DATA SECTION 10 - PHYSICAL DATA MATERIAL SAFETY DATA SHEET MATERIAL IDENTITY: SPLASH RV AND MARINE ANTIFREEZE SECTION 1 - MANUFACTURER'S INFORMATION MANUFACTURER: SUPERCLEAN BRANDS, INC. 51 EAST MARYLAND AVENUE ST. PAUL, MN 55117-4615 TELEPHONE: (651) 489-8211 FACSIMILE: (651) 489-8247 TRADE NAME: PROPYLENE GLYCOL - INHIBITED Page 1037 of 1235 Page 1037 of 1235 Page 1037 of 1235 Page 1037 of 1235 ---PAGE BREAK--- CHEMICAL FAMILY: POLYALCOHOL FORMULA: CH3CHOHCH2OH CAS NO: 57-55-6 TRANSPORTATION EMERGENCY (FOR IMMEDIATE INFORMATION ABOUT A CHEMICAL OR TO SEEK ASSISTANCE FROM A MANUFACTURER): 1-[PHONE REDACTED] SECTION 2 - NORMAL HANDLING PROCEDURES PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: AVOID CONTACT WITH EYES, SKIN, OR CLOTHING. DO NOT TAKE INTERNALLY. UPON CONTACT WITH SKIN OR EYES, WASH OFF WITH WATER. AVOID BREATHING MIST OR VAPOR. STORE IN A COOL, DRY WELL-VENTILATED PLACE. PROTECTIVE EQUIPMENT: EYES: GOGGLES GLOVES: IMPERVIOUS OTHER: NOT REQUIRED VENTILATION REQUIREMENTS: NONE BEYOND GOOD ROOM VENTILATION NORMALLY REQUIRED. SECTION 3 - HAZARDOUS INGREDIENTS BASIC MATERIAL % OSHA PEL LD50 LC50 SIGNIFICANT EFFECTS PROPYLENE GLYCOL 27.5 NONE >10 G/KG NO DATA PRACTICALLY ESTABLISHED NON-TOXIC MILD SKIN AND EYE IRRITANT. DIPOTASSIUM .2 NONE THIS PRODUCT IS NOT SUBJECT TO PHOSPHATE ESTABLISHED SECTION 313 OF TITLE III OF S.A.R.A. SECTION 4 - FIRE AND EXPLOSION HAZARD DATA FLASH POINT METHOD: 225 DEG. F COC OSHA CLASSIFICATION: NOT REGULATED (IGNITABLE) FLAMMABLE EXPLOSIVE LIMIT: LOWER: 2.6 UPPER: 12.5 Page 1038 of 1235 Page 1038 of 1235 Page 1038 of 1235 Page 1038 of 1235 ---PAGE BREAK--- EXTINGUISHING MEDIA: WATER SPRAY, DRY CHEMICAL, ALCOHOL, FOAM OR CARBON DIOXIDE. SPECIAL FIRE HAZARD & FIRE FIGHTING PROCEDURES: WATER SPRAY SHOULD BE USED TO COOL FIRE EXPOSED CONTAINERS AND/OR TO DISPERSE UNIGNITED VAPORS. USE NIOSH/MSHA APPROVED POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS WHEN ANY MATERIAL IS INVOLVED IN A FIRE. SECTION 5 - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE: NONE ESTABLISHED. OF OVER EXPOSURE: PRACTICALLY NON-TOXIC. MILD SKIN AND EYE IRRITANT. MAY CAUSE DIARRHEA BY ORAL INGESTION. EMERGENCY FIRST AID PROCEDURES: SKIN: FLUSH WITH WATER. IF AN IRRITATION DEVELOPS, CALL A PHYSICIAN. EYES: FLUSH WITH WATER FOR 15 MINUTES, CALL A PHYSICIAN. INGESTION: DRINK WATER TO DILUTE. INHALATION: REMOVE VICTIM TO FRESH AIR. SECTION 6 - TOXICOLOGY (PRODUCT) ACUTE ORAL LD50: >10 G/KG ACUTE DERMAL LD50: >2 G/KG ACUTE INHALATION LC50: NO DATA CARCINOGENICITY: NOT KNOWN TO BE A CARCINOGENIC. MUTAGENICITY: NOT KNOWN TO BE A MUTAGENIC. EYE IRRITATION: SLIGHT IRRITANT. PRIMARY SKIN IRRITATION: SLIGHT IRRITANT. PRINCIPAL ROUTES OF ABSORPTION: INHALATION. EFFECTS OF ACUTE EXPOSURE: MAY CAUSE DIARRHEA BY ORAL INGESTION. MAY BE A SLIGHT IRRITANT. EFFECTS OF CHRONIC EXPOSURE: MAY BE A SKIN SENSITIZER IN SOME INDIVIDUALS. SECTION 7 - SPILL AND LEAKAGE PROCEDURES Page 1039 of 1235 Page 1039 of 1235 Page 1039 of 1235 Page 1039 of 1235 ---PAGE BREAK--- (CONTROL PROCEDURES) ACTION FOR MATERIAL RELEASE OR SPILL: WEAR GOGGLES, COVERALLS, IMPERVIOUS GLOVES AND BOOTS. ADD DRY ABSORBENT, SHOVEL OR SWEEP UP. PLACE IN AN APPROPRIATE CONTAINER AND SEAL, WASH ALL CONTAMINATED CLOTHING BEFORE REUSE. IN THE EVENT OF A LARGE SPILL, CALL THE EMERGENCY TELEPHONE NUMBER SHOWN ON THE FRONT OF THIS SHEET. WASTE DISPOSAL METHOD: DISPOSE OF CONTAMINATED PRODUCT, EMPTY CONTAINERS AND MATERIALS USED IN CLEANING UP SPILLS OR LEAKS IN A MANNER APPROVED FOR THIS MATERIAL. CONSULT APPROPRIATE FEDERAL, STATE AND LOCAL REGULATORY AGENCIES TO ASCERTAIN PROPER DISPOSAL PROCEDURES. SECTION 8 - SHIPPING DATA D.O.T.: NOT REGULATED. SECTION 9 - REACTIVITY DATA STABLE: YES UNSTABLE AT: C F HAZARDOUS POLYMERIZATION: MAY OCCUR ( ) WILL NOT OCCUR (XXX) CONDITIONS TO AVOID: EXTREME HEAT INCOMPATIBILITY (MATERIAL TO AVOID): STRONG OXIDIZERS HAZARDOUS DECOMPOSITION PRODUCTS: CARBON MONOXIDE. CARBON DIOXIDE. SECTION 10 - PHYSICAL DATA MELTING POINT: NO DATA VAPOR PRESSURE: 0.5 MMHg/20 DEG. C VOLATILES: NO DATA BOILING POINT: 370 DEG. F SOLUBILITY IN WATER: SOLUBLE Page 1040 of 1235 Page 1040 of 1235 Page 1040 of 1235 Page 1040 of 1235 ---PAGE BREAK--- EVAPORATION RATE: NO DATA SPECIFIC GRAVITY (H2O=1): 1.038 pH: NO DATA VAPOR DENSITY (AIR=1): NO DATA DATE UPDATED: DECEMBER 12, 2007 Page 1041 of 1235 Page 1041 of 1235 Page 1041 of 1235 Page 1041 of 1235 ---PAGE BREAK--- Page 1042 of 1235 Page 1042 of 1235 Page 1042 of 1235 Page 1042 of 1235 ---PAGE BREAK--- Page 1043 of 1235 Page 1043 of 1235 Page 1043 of 1235 Page 1043 of 1235 ---PAGE BREAK--- Page 1044 of 1235 Page 1044 of 1235 Page 1044 of 1235 Page 1044 of 1235 ---PAGE BREAK--- Page 1045 of 1235 Page 1045 of 1235 Page 1045 of 1235 Page 1045 of 1235 ---PAGE BREAK--- Page 1046 of 1235 Page 1046 of 1235 Page 1046 of 1235 Page 1046 of 1235 ---PAGE BREAK--- Material Safety Data Sheet Omni Specialty Packaging For Compliance with OSHA 29 CFR 1910.1200 and ANSI Z400.1-1998 Packaged for Stihl Incorporated, 536 Viking Drive, Virginia Beach, VA 23452 1. Product and Company Identification Product Name MSDS Code Number STIHL HP ULTRA PART NUMBER; 0781-313-8004 (2.6OZ); 0781-313- 8007 (5.2oz); 0781-313-8010 (6.4oz); 0781-313-8013 (12.8 oz); 0781-313- 8016 (5 Gal); 0781-313- 8017 (55 Gal); 7010-871-0174 (1 Gal); 7010-871- 0173 Keg (16 Gal); Trade Name & Synonyms Date of Last Revision 10/01/2009 Chemical Name Supplier Omni Specialty Packaging ( United States) C.A.S. Number Address 10399 Hwy. 1 South Shreveport, La. 71115 Grades or Minor Variant Identities Information Telephone Number (318) 524-1100 For Chemical Emergency, Spill Leak Fire Exposure or Accident Call CHEMTREC Day or Night DOMESTIC NORTH AMERICA [PHONE REDACTED] INTERNATIONAL, CALL [PHONE REDACTED] (collect calls accepted) Product Use (for Canada) 2. Composition/Information on Ingredients Hazardous Components C.A.S Number Exposure Limits Oil Mist % Petroleum Distillates, Hydrotreated Heavy Paraffinic 64742-54-7 5 mg/m3 Blend OSHA Regulatory Status 29 CFR 1910.1200. 3. Hazards Identification Emergency Overview This product is considered not hazardous under 29 CFR 1910.1200 (Hazard Communication). Routes of Exposure Signs and Single, Repeated, or Lifetime Exposures Severity (Mild, Moderate, Severe) Acute and Chronic Health Effect(s) Target Organ(s) Eye Practically non- irritating to the eye upon direct contact. Skin Minimally irritating upon direct contact. Inhalation No significant health hazards identified. Ingestion Don not ingest. May cause nausea, vomiting/diarrhea. Other None identified. Medical Conditions Aggravated by Exposure Personnel with pre-existing skin disorders should avoid contact with this product. Page 1047 of 1235 Page 1047 of 1235 Page 1047 of 1235 Page 1047 of 1235 ---PAGE BREAK--- MSDS – OMNI SPECIALTY PACKAGING Page 2 of 6 4. First Aid Measures Routes of Exposure First Aid Instructions Immediate Medical Attention Delayed Eye Flush with large amount of water for 15 minutes. Get medical attention if eye irritation develops or persists. Skin Wash with soap and water. Remove contaminated clothes and wash before reuse. Get medical attention if skin discolor develop. Inhalation This material is not expected to present an inhalation exposure at ambient conditions Ingestion Do not induce vomiting. Get immediate medical attention or advice. Other Not available Note to Physicians (Treatment, Testing, and Monitoring) Not available 5. Fire Fighting Measures Flashpoint Method: °F Flammable (Explosive) Limits in Air LEL UEL Autoignition Temperature °F Hazard rating PMCC 220 Not determined Not determined N/A N/A Fire 1 Health 0 reactivity 0 Flame Propagation or Burning Rate (for solids) Properties Contributing to Fire Intensity Flammability Classification Not Available Not Determined Not Available Extinguishing Media Extinguishing Media to Avoid Reactions to Extinguishing Media Water for, foam, CO2, dry chemical Not Available Not Available Protection and Procedures for Firefighters Wear positive pressure self-contained breathing apparatus (SCUBA). Use water to cool containers exposed to flames. Structural firefighters’ protective clothing will only provide limited protection. Unusual Fire and Explosion Hazards Mist or sprays may be flammable below the product normal flash point. 6. Accidental Release Measures Spill/Leak Clean-up Procedures and Equipment Observing health hazards described above, ventilate area. Dike to contain spill. Pick up free liquid for recycle and/or disposal. Residual liquid and/or solid can be absorbed on inert material. Keep from sewers and natural water. Evacuation Procedures Large spill * Consider initial downwind evacuate for at least 300 meters (1000 feet). Fire * If tank, rail car or tank car is involved in a fire, isolate for 800 meters (1/2 mile) in all directions; also consider initial evacuation for 800 meters (1/2 mile) in all directions. Special Instructions When using this material, do not eat, drink, or smoke. Wash thoroughly after handling. Keep away from animals and children. Reporting Requirements Spills that enter a water body must be reported immediately to the USEPA’s National Response Center at (800)546-2972. Check with your local and state regulators regarding their reporting requirements. 7. Handling and Storage Handling Practices and Warnings Do not pressure, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition; they may explode. See NFPA 30 and OSHA 1910.106 – flammable and combustible liquids. Storage Practices and Warnings Store away from heat, sparks, open flame, or strong oxidizing agents in closed and properly labeled containers. Empty containers retain product residue (liquid, and/or vapor) and can be dangerous. 8. Exposure Control/Personal Protection Other Engineering controls Ventilation N/A Additional area ventilation or local exhaust may be required to maintain air concentrations below recommended limits. Routes of Entry: Personal Protective Equipment (PPE) for Normal Use: PPE for Emergencies Page 1048 of 1235 Page 1048 of 1235 Page 1048 of 1235 Page 1048 of 1235 ---PAGE BREAK--- MSDS – OMNI SPECIALTY PACKAGING Page 3 of 6 Eye/Face Safety glasses or face shield where splashing is possible. Full face shield Skin As needed to prevent repeated skin contact. Solvent resistant gloves should be used if needed. Inhalation Not normally needed. Respirator 9. Physical and Chemical Properties Appearance Odor Green Liquid Mild petroleum odor Normal Physical State: Boiling Point N/A ° F x Liquid Gas Melting Point N/A ° F Solid (Other) Freezing Point 0 ° F Specific Gravity or Density (H20 = 1) Solubility in Water pH 0.93 Negligible N/A Vapor Pressure (mm Hg.) Vapor Density (AIR = 1) Evaporation Rate (Butyl Acetate = 1) <0.01 Not Determined Not Available Other N/A 10. Stability and Reactivity Incompatibility (Materials to Avoid) Heat, open flame, and oxidizing agents. Hazardous Products Produced During Decomposition Combustion products may include smoke, fumes, oxides of phosphorus, boron, sulfur, nitrogen, carbon dioxide, carbon monoxide, and other low molecular weight hydrocarbons. Hazardous Polymerization? May Occur X Will Not Occur Conditions to Avoid Not Available Stability? X Stable Unstable Conditions to Avoid Not Available 11. Toxicological Information Toxicity Data, Epidemiology Studies, Carcinogenicity, Neurological Effects, Genetic Effects, Reproductive Effects, or Structure Activity Data Acute Toxicity: Test on similar materials show a low order of acute oral and dermal toxicity. Acute Oral Effects: Test on similar materials indicates low order of acute toxicity. Acute Inhalation Effects: Low acute toxicity expected on inhalation. Skin Effects: Practically non-toxic if absorbed. Other similar highly refined products have not shown skin tumors in mouse skin painting studies. Eye Irritation: Minimal irritation on contact. Eye irritation or practically non-irritating base on similar products. Carcinogenicity: Skin: Not considered a potential carcinogen base on IP346 DMSO of less tan 3.0 wt% Genotoxicity: This product is considered non-mutagenic and has negative potential for tumor development based on from Modified Ames Assay, with Mutagenic Index of less than 1.0. Page 1049 of 1235 Page 1049 of 1235 Page 1049 of 1235 Page 1049 of 1235 ---PAGE BREAK--- MSDS – OMNI SPECIALTY PACKAGING Page 4 of 6 12. Ecological Information Toxicity, Environmental Fate, Physical/Chemical Data, or Other Data Supporting Environmental Hazard Statements No testing has been performed by the manufacturer. Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be impaired. 13. Disposal Considerations Regulations Dispose in accordance with all local, state, and federal regulations. Keep this product out of sewers and waterways. Where possible arrange for product to be recycled. Note: State or local requirements may differ from federal regulations. Processing or using this product may make the information here inappropriate. Waste generators are responsible for waste classification, transport, and disposal. 14. Transport Information Regulated for shipping? Proper Shipping Name Packing Group Yes X No N/A N/A Do changes in quantity, packaging, or shipment method change product qualification? Hazard Class Identification Number Yes x No N/A N/A Other N/A Page 1050 of 1235 Page 1050 of 1235 Page 1050 of 1235 Page 1050 of 1235 ---PAGE BREAK--- MSDS – OMNI SPECIALTY PACKAGING Page 5 of 6 15. Regulatory Information Federal Regulations (OSHA, TSCA, CERCLA, FIFRA, EPCRA, CAA, CWA, SDWA, CPSA, DEA, FDA/USDA, etc.) State Regulations U.S. Federal Regulatory Information: CERCLA/SARA 302/303/304 Categories: Extremely Hazardous Substances No (40 CFR 355 Appendix A) 311/312 Categories: Immediate (Acute) Health Effects No (40 CFR 370) Delayed (Chronic) Health Effects No Fire Hazard No Sudden Release of Pressure Hazard No Reactivity Hazard No 313 Categories: Toxic Chemicals (40 CFR 372) No Clean Air Act: Hazardous Air Pollutants (HAPS) No Clean Water Act: If spilled into navigable waters it is reportable to National Response Center, [PHONE REDACTED] (40 CFR 116; 401.15) Reportable Quantity = Oil Sheen present on navigable water surface OSHA (29 CFR 1910): This product is not hazardous under Hazard Communication Standard 29 CFR 1910.1200 RCRA (40 CFR 261.133) This product does not meet hazardous waste criteria. EPA/TSCA Inventory: The components of this product are listed on the EPA/TSCA inventory of chemicals. CAS No. 64742-54-7 State Regulations: California Prop 65 No Proposition 65 chemicals exist in this product, no labeling required. Florida No listed ingredients are present Massachusetts RTK No listed ingredients are present Minnesota RTK No listed ingredients are present New Jersey RTK Lists petroleum oil, but this product does not contain hazardous ingredients. RTK Lists petroleum oil, but this product does not contain hazardous ingredients greater than Illinois DOL TSL No listed ingredients are present Other Regulations: WHMIS (Canada) Not listed on the Canadian Controlled Product Ingredient Disclosure and is compliant with Controlled Products Regulation CONEG Metals: Since cadmium, chromium, lead and mercury are not detectable and it does not exceed 100 ppm total in this product, it is compliant with CONEG Metals regulation. EEC (Europe): This product is not known to be a dangerous good internationally. No known R-Phrases or S-Phrases Hazard Label None Danger Symbol None International Regulations N/A Other N/A Page 1051 of 1235 Page 1051 of 1235 Page 1051 of 1235 Page 1051 of 1235 ---PAGE BREAK--- MSDS – OMNI SPECIALTY PACKAGING Page 6 of 6 16. Other Information Label Text, Hazard Rating System, Key Legend, or Other Abbreviations ACGIH(American Conference of Governmental Industrial Hygienists); ANSI(American National Standards Institute); CAS(Chemical Abstract Service); CERCLA(Comprehensive Environmental Response, Compensation, & Liability Act); CFR(Code of Federal Regulations); CHIP (Chemicals Hazard Information & Packaging for Supply); CONCAWE (European Organization for Environment, Health & Safety); CPR(Controlled Products Regulations); DOL (Department of Labor); EED(European Economic Community Directives); EINECS (European Inventory of Existing Commercial Chemical Substances); EL50 (Effective loading rate required to immobilize 50% invertebrate species); ELINCS(European List of New Chemical Substances); EPA (Environmental Protection Agency); EPCRA(Emergency Planning & Community Right-To-Know Act of 1986); EU(European Union); FDA(Food & Drug Administration-USA); GHS (Global Harmonization System); HCS (Hazard Communication Standard); IARC(International Agency for Research on Cancer); ILO(International Labor Organization); LC50(Lethal Concentration 50% test organisms); LD50(Lethal Dose 50% test organisms); LVP-VOC(Low Vapor Pressure Volatile Organic Compound); MSDS(Material Safety Data Sheet); MSHA(Mine Safety & Health Administration); NIOSH(National Institute of Occupational Safety & Health);NTP(National Toxicology Program); OSHA(Occupational Safety & Health Administration); PEL(Permissible Exposure Limit); Prop 65(California Proposition 65); PMCC(Pensky Martin Closed Cup); RCRA(Resource Conservation & Recovery Act); RTK(Right-To-Know); R-Phrases(EU Risk Phrases; S-Phrases (EU Safety Phrases); SARA(Superfund Amendments & Reauthorization Act); TSCA (Toxic Substances Control Act); TSL (Toxic Substance List); TLV(Threshold Limit Value); WHMIS(Workplace Hazardous Materials Information System- Canada); lrL50 (Inhibitory loading rate required to reduce algal growth rate by 50%; lbL50 (Inhibitory loading rate required to reduce area under growth curve or biomass by 50%); ppm (parts per million); mg/m3 (milligrams per cubic meter); N(no); Y (yes) NFPA Hazard Rating – Health 0 Slight -Fire 1 Slight Reactivity 0 Least Prepared By: Juan Parker Phone: (318) 524-1100 This MSDS complies with OSHA Hazard Communication Standard (HCS) 29 CFR 1910.1200 and conforms to ANSI Z 400.1 16-Section Format. Disclaimer: Omni Specialty Packaging believes this information is accurate but not all-inclusive in all circumstances. It is the responsibility of the user to determine suitability of the material for their purposes. No warranty, expressed or implied, is given. NOTE: OSHA’s Hazard Communication Standard (29 CFR 1910.1200) does not require the information requested in Sections 11, 12, 13, 4, 15, and 16 for If your company chooses not to fill in these sections, you may wish to enter something (like N/R for “not regulated” or N/A for “not applicable”) to indicate that the field is purposely being left blank. Page 1052 of 1235 Page 1052 of 1235 Page 1052 of 1235 Page 1052 of 1235 ---PAGE BREAK--- There was a PDF conversion failure for - Product Name: STIHL HP ULTRA 2-CYCLE ENGINE OIL CAS Number: Manufacturer: OMNI Specialty Packaging SDS Date: 6/2/2015 To complete your binder, please link a different SDS for this product or print the SDS manually from http://www.msdsonline.com/Legacy/Partners/Show-Document/Default.aspx?ShowId=jtu5MUlngYo%3d and add to your binder. We are currently researching solutions to this issue. Thank you for your patience. Page 1053 of 1235 Page 1053 of 1235 Page 1053 of 1235 Page 1053 of 1235 ---PAGE BREAK--- STIHL WOODCUTTER BAR & CHAIN LUBRICANT Packaged for Stihl Incorporated, 536 Viking Drive, Virginia Beach, VA 23452 Page 1 of 8 Safety Data Sheet Conforms to HCS 2012 (29 CFR 1910.1200) Section 1. Identification Product identifier Product Name: STIHL WOODCUTTER BAR & CHAIN LUBRICANT Other names: F-7410, Stihl Woodcutter Bar and Saw Chain Lubricant Part/Product Number(s): 7010-871-0000, 7010-871-0240 Material Use: Bar and chain lubricant Uses advised against: Not for internal engine use. Manufacturer: Omni Specialty Packaging, LLC 10399 Hwy 1 South Shreveport, LA 71115 1-[PHONE REDACTED] Issuing date: May 8, 2015 Revision date: May 8, 2015 Revision number: 0 Company contact: OMNI EHS Department; E-Mail: [EMAIL REDACTED]; Contact phone: [PHONE REDACTED] (Monday-Friday, 8:00 AM – 4:00 PM, CST) In case of emergency : CHEMTREC: Within USA and Canada: 1 (800) 524-9300 (24/7) CHEMTREC Outside USA and Canada: +1 [PHONE REDACTED] (24/7) Section 2. Hazards Identification OSHA/HCS Status: This product is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the substance or Mixture: Not classified GHS Label Elements Hazard pictograms: None Signal word: None Hazard statement: None Precautionary statements General: Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Prevention: Not applicable Response: Not applicable Storage: Not applicable Disposal: Not applicable Hazards not otherwise classified (HNOC): Defatting to the skin. Page 1054 of 1235 Page 1054 of 1235 Page 1054 of 1235 Page 1054 of 1235 ---PAGE BREAK--- STIHL WOODCUTTER BAR & CHAIN LUBRICANT May 8, 2015 Page 2 of 8 Section 3. Composition/Information on Ingredients Petroleum mineral oil lubricant base stock with proprietary performance additives mixture. Substance/mixture: Mixture Components Name CAS number Weight Lubricant Base Oil (Petroleum) Highly refined mineral oils (C15-C50) Various 95 – 99 Bar & Chain Oil Additive Mixture Proprietary 1-5 This product does not contain known hazardous materials at the ≥ 1% level or known carcinogens at the ≥ 0.1% level as defined by 29 CFR 1910.1200. * The exact percentage of composition has been withheld as a trade secret. Section 4. First Aid Measures Description of necessary first aid measures General Advice: No specific first aid measures are required. Get medical attention if irritation develops and persists. Eye contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing. Check for and remove any contact lenses. Get medical attention if irritation develops and persists. Skin contact: Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Get medical attention if irritation develops and persists. Inhalation: In case of inhalation of decomposition products in a fire, may be delayed. If inhaled, remove to fresh air. The exposed person may need to be kept under medical surveillance for 48 hours. Get medical attention if occur. Ingestion: Do NOT induce vomiting. Drink plenty of water. If persist, call a physician. Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training. Remove all sources of ignition. Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. Wear personal protective clothing (see section Most important and effects, both acute and delayed See Section 11 for more detailed information on health effects and Most Important and Effects: Personnel with pre-existing skin disorders should avoid contact with this product. Under normal use conditions, no adverse effects to health are known. Eye contact: Not expected to cause prolonged or significant eye irritation. Skin contact: Contact with skin is not expected to cause prolonged or significant irritation. Contact with skin is not expected to cause an allergic skin response. Not expected to be harmful to internal organs if absorbed through the skin. Inhalation: Not expected to be harmful if inhaled. Contains petroleum-based mineral oil. May cause respiratory irritation or other pulmonary effects following prolonged or repeated inhalation of oil mist at airborne levels above the recommended oil mist exposure limit. of respiratory irritation may include coughing and difficult breathing. Ingestion: Not expected to be harmful if swallowed. Note to physician: Treat Page 1055 of 1235 Page 1055 of 1235 Page 1055 of 1235 Page 1055 of 1235 ---PAGE BREAK--- STIHL WOODCUTTER BAR & CHAIN LUBRICANT May 8, 2015 Page 3 of 8 Section 5. Fire-Fighting Measures Uniform Fire Code: Class IIIB Flash Point: >126.7°C (>260°F) Extinguishing Media Suitable Media: In case of fire, use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water fog, alcohol resistant foam, dry chemical, carbon dioxide (CO2) extinguisher or spray. Unsuitable Media: CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical: Keep product and empty container away from heat and sources of ignition as product will burn. Contact with strong oxidizers may cause fire. In the event of fire, cool tanks with water spray. Fire residues and contaminated fire extinguishing water must be contained, prevented from being discharged to any waterway, sewer or drain and disposed of in accordance with local regulations. Hazardous Combustion Products: Combustion products may include the following: Carbon dioxide (CO2) Carbon monoxide (CO), and Nitrogen oxides. Protection of Fire Fighters: isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Section 6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Do not touch or walk through spilled material. Put on appropriate personal protective equipment. Floors may be slippery; use care to avoid falling. For emergency responders: If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. Ensure adequate ventilation. Keep people away from and upwind of spill/leak. See also the information in "For non- emergency personnel". Environmental precautions: Avoid dispersal of spilled material onto soil or into waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). See Section 12 for ecological information. Methods and materials for containment and cleaning up Small Spills: Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large Spills: Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. NOTE: If RQ (Reportable Quantity) is exceeded or if spills enter a body of water, report immediately to the USEPA’s National Response Center at (800) 424-8802. Check with your local and state regulators regarding their reporting requirements. Section 7. Handling and Storage Precautions for safe handling Protective measures: Safety glasses with shied shields. Eye protection and face shield should be used if material is used under conditions that increase the chances of splattering. Put on Page 1056 of 1235 Page 1056 of 1235 Page 1056 of 1235 Page 1056 of 1235 ---PAGE BREAK--- STIHL WOODCUTTER BAR & CHAIN LUBRICANT May 8, 2015 Page 4 of 8 appropriate personal protective equipment (see Section Keep out of reach of children. Advice on general occupational hygiene: Do not get in eyes, on skin or on clothing. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Conditions for safe storage, Including any incompatibilities: Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials, strong oxidizing agents (see Section 10) and food and drink. Keep away from heat, sparks, flame and other sources of ignition pilot lights, electric motors and static electricity). Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Use appropriate containment to avoid environmental contamination. Avoid contaminating soil or releases into sewage or drainage systems and bodies of water. Section 8. Exposure Controls/Personal Protection Control parameters Occupational Exposure Limits Chemical name ACGIH OSHA NIOSH TLV STEL PEL STEL TWA Ceiling Lubricant Base Oil (Petroleum) Highly refined mineral oils (C15-C50) 5 mg/m3 (mist) 10 mg/m3 (mist) 5 mg/m3 (mist) _ _ _ Appropriate engineering controls: Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Emergency shower and eyewash station. Environmental exposure controls: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual protection measures Hygiene measures: Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Eye/Face Protection: Wear safety glasses with side shields. A face shield may be necessary under some conditions. Skin and Body Protection Hand protection: Wear protective gloves if prolonged or repeated contact is likely. Wear chemical resistant gloves. Recommended: Nitrile gloves. Consult your supervisor or Standard Operating Procedure (SOP) for special handling instructions. Body protection: No protective equipment is needed under normal use conditions. For non-routine tasks, personal protection equipment for the body should be selected based on the task being performed and the risks involved. Other skin protection: Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved. Respiratory protection: No respiratory protection is normally required. If user operation generates an oil mist, determine if airborne concentrations are below the occupational exposure limit for mineral oil mist. If not, wear an approved respirator that provides adequate protection from measured concentrations of this material. The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. For air-purifying respirators use a particulate cartridge. Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not provide adequate protection. Page 1057 of 1235 Page 1057 of 1235 Page 1057 of 1235 Page 1057 of 1235 ---PAGE BREAK--- STIHL WOODCUTTER BAR & CHAIN LUBRICANT May 8, 2015 Page 5 of 8 Section 9. Physical and Chemical Properties Appearance (Typical or Target) Physical State: Liquid Color: Straw colored Odor: Petroleum like Odor threshold: Not available pH: Not applicable Boiling Point: Not available Flash Point (Closed cup): >126.7°C (>260°F) Evaporation rate (Butyl acetate = Not available Flammability (solid, gas): Not applicable. Based on - Physical state Flammable) Limit in Air Not available Vapor pressure: Not available Vapor density (Air = >1 Relative density: 0.92 - 0.94 g/l at 15°C Solubility: In soluble in water Partition coefficient (n-Octanol/water): Not available Auto-ignition temperature: Not available Decomposition temperature: Not available Viscosity – Kinematic (cSt (mm2/s)@ 40°C): 65 – 173.5 Viscosity – Kinematic (cSt (mm2/s) @ 100°C):8.3 – 12.4 VOC 0 % Section 10. Stability and Reactivity Reactivity: Not reactive under normal storage conditions Chemical stability: Stable under normal storage conditions Possibility of hazardous reactions: None under normal processing. Hazardous polymerization: Hazardous polymerization does not occur. Conditions to avoid: Heat, flames and sparks. Incompatible materials: Oxidizing agents and open flames. Hazardous decomposition products: May include: Fumes, Oil vapors, Smoke, Carbon Oxides (including carbon monoxide and carbon dioxide), Aldehydes, Nitrogen oxides, and incomplete combustion products. Section 11. Toxicological Information Information on toxicological effects Basis for Assessment: Information given is based on product data, a knowledge of the components and the toxicity of similar products. Likely Routs of Exposure: Exposure may occur via skin absorption, skin or eye contact, inhalation, ingestion. Substance/Mixture Acute Toxicity Oral LD50 Dermal LD50 Inhalation LC50 Lubricant Base Oil (Petroleum) Highly refined mineral oils (C15- C50) Mixture - Typical >2000 mg/Kg (rat) >2000 mg/Kg (rabbit) >2.18 mg/L (rat) 4h (mist) Aspiration hazard: Not expected to be an aspiration hazard. Skin Corrosion/Irritation: No known significant effects or critical hazards. Serious Eye Damage/Irritation: No known significant effects or critical hazards. Skin Sensitization: No known significant effects or critical hazards. Respiratory Sensitization: No known significant effects or critical hazards. Specific Target Organ Toxicity (Single Exposure) - STOT-SE: No known significant effects or critical hazards. Specific Target Organ Toxicity (Repeated Exposure) – STOT-RE: No known significant effects or critical hazards. Carcinogenicity: No known significant effects or critical hazards. Page 1058 of 1235 Page 1058 of 1235 Page 1058 of 1235 Page 1058 of 1235 ---PAGE BREAK--- STIHL WOODCUTTER BAR & CHAIN LUBRICANT May 8, 2015 Page 6 of 8 Germ Cell Mutagenicity: No known significant effects or critical hazards. Reproductive Toxicity No known significant effects or critical hazards. Information on Toxicity Effects of Compounds Lubricant Base Mineral Oil (Petroleum) Mineral oils are known to cause cancer because of carcinogenic components (e.g. Benzene). The lubricant base mineral oils in this product have been highly refined by a variety of processes including severe solvent extraction, severe hydro cracking or severe hydro treating to reduce aromatics and improve performance characteristics. The oils in the is product meets the IP-346 criteria of less than 3 percent PHA’s and are not considered to be a carcinogen by the International Agency for Research on Cancer. None of the oils in this product requires a cancer warning under the OSHA Hazard Communication Standard (29 CFR 1910.1200). These oils have not been listed in the National Toxicology Program (NTP) Annual Report nor have they been classified by the International Agency for Research on Cancer (IRAC) as: carcinogenic to humans (Group probably carcinogenic to humans (Group 2A), or possibly carcinogenic to humans (Group 2B). These oils have not been classified by the American Conference of Governmental Industrial Hygienists (ACGIH) as: confirmed human carcinogen (A1), suspected human carcinogen (A2), or confirmed animal carcinogen with unknown relevance to humans (A3). The information is based on data available for the material, the components of the material, and similar materials. Ecotoxicity: No testing has been performed by the manufacturer. Ecotoxicity hazard is based on an evaluation of data for the components or a similar material. Not expected to be harmful to aquatic organisms. Mobility: Base oil component – Low solubility and floats on water. It is expected to migrate from water to land. Expected to partition to sediment and wastewater solids. Soil/water partition coefficient (Koc): Not available. Persistence and degradation Biodegradation: The material is not expected to be readily biodegradable. The biodegradability of this material is based on an evaluation of data for the components or a similar material. Bioaccumulative potential Bioaccumulation: This product is not expected to bioaccumulate through food chain in the environment. Other adverse effects: No known significant effects or critical hazards. Other ecological information: Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be impaired. Section 13. Disposal Considerations Disposal recommendations based on material supplied. Waste treatment methods: This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). Consult the appropriate state, regional, or local regulations for additional requirements. The generation of waste should be avoided or minimized wherever possible. Product waste: Significant quantities of waste product residues should not be disposed of via the sanitary sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non- recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Incineration or landfill should only be considered when recycling is not feasible. Oil collection services are available for used oil recycling. Section 12. Ecological Information Page 1059 of 1235 Page 1059 of 1235 Page 1059 of 1235 Page 1059 of 1235 ---PAGE BREAK--- STIHL WOODCUTTER BAR & CHAIN LUBRICANT May 8, 2015 Page 7 of 8 Contaminated packaging: Empty containers or liners may retain some product residues and could pose a potential fire and explosion hazard. Do not cut, puncture, or weld containers. Other information: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Section 14. Transport Information General information: Petroleum Lubricating oil - Not regulated. DOT Classification IMDG IATA Bar & Chain Oil Not Regulated Not Regulated Not Regulated Special precautions for user: Transport within user’s premises: Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Section 15. Regulatory Information United States Regulations United States Inventory (TSCA 8b): All components are listed or exempted. SARA 302/304: No products were found. SARA 311/312: Immediate (Acute) Health Effects: No Delayed (Chronic) Health Effects: No Fire Hazard: No Sudden Release of Pressure Hazard: No Reactivity Hazard: No SARA 313: The following components of this material are found on the EPCRA 313 list: None Supplier notification: This product does not contain any hazardous ingredients at or above regulated thresholds. CWA (Clean Water Act): This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA: This material, as supplied, does not contain any substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302). State Regulations Massachusetts: None of the components are at or above regulated thresholds. New Jersey: None of the components are at or above regulated thresholds. None of the components are at or above regulated thresholds. California Proposition 65: WARNING: This product contains a chemical known to the State of California to cause cancer. None Canada WHMIS Hazard Class: Not classified. This Product Is Not Controlled Under WHMIS (Canada) International Chemical Inventories: All components comply with the following chemical inventory requirements: DSL (Canada) Page 1060 of 1235 Page 1060 of 1235 Page 1060 of 1235 Page 1060 of 1235 ---PAGE BREAK--- STIHL WOODCUTTER BAR & CHAIN LUBRICANT May 8, 2015 Page 8 of 8 Section 16. Other Information NFPA Rating: Health Hazard – 0 Flammability – 1 Instability/Reactivity – 0 HMIS Rating: Health Hazard – 0 Flammability – 1 Physical Hazards – 0 (NFPA & HMIS Hazard Rating Key: 0 - Minimum Hazard; 1 - Slight Hazard; 2 - Moderate Hazard; 3 - High Hazard; 4 - Extreme Hazard; * - Chronic Hazard Indicator, & PPE - Personal Protective Equipment Index A to L. These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating Association (for HMIS or Hazardous Material Identification System). Key to abbreviations: OSHA = Occupational Safety and Health Administration LogPow = logarithm of the octanol/water partition coefficient ACGIH= American Conference of Industrial Hygienists OEL = Occupational Exposure Limit ATE = Acute Toxicity Estimate SDS = Safety Data Sheet BCF = Bioconcentration Factor STEL = Short term exposure Limit CAS = Chemical Abstracts Service Registry Number UN = United Nations cSt = Centistroke (mm2/s) UN Number = United Nations Number, a four digit number GHS = Global Harmonized System of Classification and Labeling assigned by the United Nations Committee of Experts on Of Chemicals. the Transportation of Dangerous Goods IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods Prepared By: OMNI Specialty Packaging EH&S Department Revision Date: May 8, 2015 Status: Final Revision Note: All Sections. First version in OSHA GHS SDS format. Consumer Product Improvement Act of 2008, General Conformity Certification For Consumer Product Packages: This product has been evaluated and is certified to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission. Where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No testing is required to certify compliance with the provisions. The date of the manufacturing is stamped on the product container. Disclaimer All reasonably practicable steps have been taken to ensure the information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. This information is furnished upon condition that the person receiving it shall make their own determination of the suitability of the material for their particular purpose. End of Safety Data Sheet Page 1061 of 1235 Page 1061 of 1235 Page 1061 of 1235 Page 1061 of 1235 ---PAGE BREAK--- MFG’S INFORMATION MATERIAL SAFETY DATA SHEET HAZARD RATING Castle Products, Inc. 0-least, 1-slight, 2-moderate, 3-high Health 2 424 St. Paul Street 4-extreme, A-goggles, B-goggles & Fire 2 Rochester, NY 14605 gloves, C-goggles & gloves & Reactivity 0 1-[PHONE REDACTED] protective wear Personal B EMERGENCY (585) 275-3232 SECTION I DESCRIPTION STOCK NUMBER TRADE NAME & SYNONYMS Streak Proof - Glass Cleaner CHEMICAL FAMILY FORMULA SECTION II HAZARDOUS INGREDIENTS CAS NO. PEL TLV STEL 2-Butoxyethanol 111-76-2 25skin 25skin 1-10 Isopropanol 67-63-0 400 400 500 1-10 Isobutane 75-28-5 1-10 Deionized Water 7732-18-5 70-80 SECTION III PHYSICAL DATA BOILING POINT -11.7°F to 212°F SPECIFIC GRAVITY(H2O=1) 0.9 VAPOR PRESSURE 45 PERCENT VOLATILE BY VOL % NA VAPOR DENSITY(AIR=1) 4.0 EVAPORATION RATE(Butyl Acetate=1) <1 SOLUBILITY IN WATER Soluble APPEARANCE & ODOR Clear/Floral SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT(method used) FLAMMABLE LIMITS LEL UEL -160°F TCC 1.9 8.5 EXTINGUISHING MEDIA: Use water fog, dry chemical, carbon dioxide and foam. SPECIAL FIRE FIGHTING PROCEDURES: Keep containers cool. Use equipment or shielding required to protect against bursting or venting containers. UNUSUAL FIRE & EXPLOSION HAZARDS: Heated cans may burst. SECTION V HEALTH HAZARD DATA THRESHOLD LIMIT VALUE: EFFECT OF OVEREXPOSURE: Difficulty breathing if inhaled. Eye and skin irritant. Ingestion-vomiting. Long term exposure may cause lung, liver, kidney damage and affect the central nervous system. EMERGENCY & FIRST AID PROCEDURES: Give oxygen-do not induce vomiting-gastric lavage-wash eyes and skin with water. SECTION VI REACTIVITY DATA STABILITY: STABLE UNSTABLE INCOMPATIBILITY(mat’l to avoid): Strong oxidizers, acids, chlorine, acetaldehyde, ethylene oxide, isocyanates, aluminum surfaces above 120°F and strong alkalies. HAZARDOUS DECOMPOSITION PRODUCTS: In fire, will decompose to carbon dioxide. HAZARDOUS POLYMERIZATION: MAY OCCUR WON’T OCCUR XXXX SECTION VII SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. WASTE DISPOSAL METHOD: Dispose as hazardous waste in accordance with EOA RCRA. SECTION VIII SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: Use NIOSH approved respirator if TLV limit is exceeded. VENTILATION: LOCAL MECHANICAL OTHER PROTECTIVE GLOVES: None required if spraying. EYE PROTECTION: Yes OTHER PROTECTIVE EQUIPMENT: Long sleeves and long pants SECTION IX SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep away from heat, sparks, or open flames. Store at temperatures below 120°F. PRODUCT 0603, 2003 DATE PREPARED: 09/09/94 DATE REVISED: 12/07/02 Page 1062 of 1235 Page 1062 of 1235 Page 1062 of 1235 Page 1062 of 1235 ---PAGE BREAK--- Material Safety Data Sheet Pro-Tex-All Company 210 S Morton Ave, Evansville, IN 47713 [PHONE REDACTED] SUPER CLEAN CLEANER DEGREASER Manufacturer: Pro-Tex-All Company Date Amended: 17 June 1998 IDENTITY Common Name: Super Clean Cleaner Degreaser Proper Shipping Name, Hazard Class, Hazard ID No: Not a regulated material INGREDIENT INFORMATION Principal Hazardous Components: CAS No. % Threshold Limit Aliphatic propylene glycol ethers 29911-28-2 10-15 NE SARA Title III Section 313 and 40 CFR Part 372 Notification: Ingredients in this product are currently not subject to notification. PHYSICAL & CHEMICAL CHARACTERISTICS Boiling Point: 212 o F Specific Gravity: 1.05-1.08 Vapor Pressure: 17.5 mm Hg Percent Volatile by Volume: 93 Water Solubility: Complete Evaporation Rate: ND Appearance & Odor: yellow liquid, soapy odor Extinguisher Media: NA Special Fire Fighting Procedures: This product is not flammable. Vapor Density: >1 Unusual Fire & Explosion Hazards: None ND = Not Determined, NE = Not Established, NA = Not Applicable REACTIVITY DATA Stability: Stable Conditions to Avoid: Store at temperatures above freezing and below 115F. Incompatability: acids, oxidizers Hazardous Polymerization: Will not occur. Hazardous Decomposition Products: Normal products of combustion. HAZARD DATA Signs & of Exposure: Direct contact of product with eyes may cause irritation and redness. Prolonged or repeated skin contact may cause irritation. Inhalation of mist may irritate nasal and respiratory passages. Chemicals Listed as Carcinogens or Potential Carcinogens: None. Emergency & First Aid Procedures: 1. Inhalation: Remove to fresh air. If breathing difficulty persists, seek medical attention. 2. Eyes: Immediately flush with water for several minutes. If irritation persists, seek medical attention. 3. Skin: Immediately flush with water for several minutes. If irritation persists, seek medical attention. 4. Ingestion: Drink large quantities of water. Seek immediate medical attention. For chemical emergency, spill, leak, fire, exposure or accident, call CHEMTREC day or night at [PHONE REDACTED]. SPECIAL PROTECTION INFORMATION Respiratory Protection: None required if good ventilation is maintained. Protective Gloves: Where skin contact is possible, wear rubber or other impervious gloves. Eye Protection: Where eye contact may occur, wear chemical splash goggles and/or face shield. SPECIAL PRECAUTIONS & SPILL/LEAK PROCEDURES Handling & Storage: Use good personal hygiene practice. Wash contaminated clothing & equipment before reuse. Release or Spill: Before attempting clean-up, refer to Hazard Data above. Use mop or wet vacuum to collect material for proper disposal. Rinse area with water. Waste Disposal: Dispose of this material in accordance with federal, state & local regulations. The information on this data sheet represents our current data & best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user. Page 1063 of 1235 Page 1063 of 1235 Page 1063 of 1235 Page 1063 of 1235 ---PAGE BREAK--- M A T E R I A L S A F E T Y D A T A S H E E T SECTION I - CHEMICAL PRODUCT AND COMPANY INDENTIFICATION PRODUCT NAME : SUPER-SPOT TREE MARK-ALL COLOR IDENTIFICATION NUMBER : E&I 23 20 DATE PRINTED: 05/30/02 PRODUCT USE/CLASS : SUPPLIER: The Nelson Paint Co of Michigan Inc PO Box 2040 Kingsford, MI 49802-2040 EMERGENCY TELEPHONE : [PHONE REDACTED] CHEMTEL : 24 hours MANUFACTURER: The Nelson Paint Co of Michigan Inc PO Box 2040 Kingsford, MI 49802-2040 EMERGENCY TELEPHONE : [PHONE REDACTED] CHEMTEL : 24 hours PREPARER: Doyle Yoder, PHONE: [PHONE REDACTED], PREPARE DATE: 05/09/02 SECTION II - COMPOSITION / INFORMATION ON INGREDIENTS WT. PERCENT IS LESS THAN EXPOSURE CHEMICAL NAME CAS NUMBER TLV-TWA TLV-STEL PEL-TWA PEL-CEILING SKIN Methyl Alcohol 67-56-1 15.0 % 200ppm 250ppm 200ppm N.E. YES Aliphatic Hydrocarbons 8052-41-3 35.0 % 100ppm N.E. 100ppm N.E. NO (See Section XI for abbreviation legend) SECTION III - PHYSICAL DATA BOILING RANGE : 147 - 385 F VAPOR DENSITY : Is heavier than air ODOR : Slight Solvent SPECIFIC GRAVITY : 0.9882 APPEARANCE : Colored Liquid EVAPORATION RATE : Is faster than Butyl Acetate SOLUBILITY IN H2O : Partial VOLATILE BY WEIGHT : 73.4 % VOLATILE BY VOLUME : 84.1 % VOCS, lbs/gal : 5.09 VOCS, grams/ltr : 610 (See Section XI for abbreviation legend) SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT : 73 F LOWER EXPLOSIVE LIMIT : 1.0 % UPPER EXPLOSIVE LIMIT: 36.0 % EXTINGUISHING MEDIA : ALCOHOL FOAM CO2 DRY CHEMICAL FOAM UNUSUAL FIRE AND EXPLOSION HAZARDS: Avoid breathing dusts and fumes from burning material. Vapors may form explosive mixture with air. Vapors can travel to a source of ignition and flash back. "Empty" containers retain product residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Empty drums should be completely drained, properly bunged and returned to a drum reconditioner, or properly disposed of. Keep containers closed . Isolate from heat, electrical equipment, sparks and open flame. Closed containers may explode when exposed to extreme heat. SPECIAL FIREFIGHTING PROCEDURES: Containers can build up pressure if exposed to heat (fire). As in any fire, wear self-contained breathing apparatus pressure-demand (MSHA/NIOSH approved or equivalent) and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. Water spray may be used for cooling containers to prevent possible pressure build-up and auto-ignition or explosion when exposed to extreme heat. SECTION V - HEALTH HAZARD DATA Page 1064 of 1235 Page 1064 of 1235 Page 1064 of 1235 Page 1064 of 1235 ---PAGE BREAK--- EFFECTS OF OVEREXPOSURE - EYE CONTACT: Liquid, aerosols and vapors of this product are irritating and can cause pain, tearing, reddening and swelling accompanied by a stinging sensation and/or a feeling like that of fine dust in the eyes. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). EFFECTS OF OVEREXPOSURE - INHALATION: Headaches, dizziness, nausea, decreased blood pressure, changes in heart rate and cyanosis (characterized by bluish discoloration of the skin and nails) may result from over-exposure to vapor or skin exposure. EFFECTS OF OVEREXPOSURE - INGESTION: This material may be harmful or fatal if swallowed. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for 15 minutes. Get immediate medical attention. FIRST AID - SKIN CONTACT: Immediately flush skin with plenty of water. Wash with soap and water. Remove soiled clothing. Wash clothing separately before reuse. Get medical attention if irritation develops or persists. FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. FIRST AID - INGESTION: NOTE TO PHYSICIAN: This product contains methanol which can cause intoxication and central nervous system depression. Methanol is metabolized to formic acid and formaldehyde. These metabolites can cause metabolic acidosis, visual disturbances and blindness. Since metabolism is required for these toxic their onset may be delayed from 6 to 30 hours following ingestion. Ethanol competes for the same metabolic pathway and has been used to prevent methanol metabolism. Ethanol administration is indicated in patients or at methanol concentrations above 20 UG/DL. Methanol is effectively removed by hemodialysis. Keep person warm, quiet and get immediate medical attention. Do NOT induce vomiting, because aspiration of material into the lungs from vomiting can cause chemical pneumonitis which can be fatal. PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT SKIN ABSORPTION INHALATION INGESTION EYE CONTACT SECTION VI - REACTIVITY DATA HAZARDOUS DECOMPOSITION PRODUCTS: Hazardous decomposition products: CO, CO2 and Nox. CONDITIONS TO AVOID: Heat, sparks and open flames. INCOMPATABILITY: Avoid contact with: strong oxidizing agents. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Evacuate all non-essential personnel. Remove all sources of ignition. Ventilate the area. Equip employees with appropriate protection equipment. Dike around spilled material. Cover spill with absorbent material and shovel with non-sparking tools into container. Remove containers to safe area and seal. Avoid runoff into storm sewers and ditches which lead to waterways. WASTE DISPOSAL METHOD: Dispose of in accordance with all local, state and federal regulations. SECTION VIII - SAFE HANDLING AND USE INFORMATION Page 1065 of 1235 Page 1065 of 1235 Page 1065 of 1235 Page 1065 of 1235 ---PAGE BREAK--- RESPIRATORY PROTECTION: A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. VENTILATION: Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product. SKIN PROTECTION: Where contact is likely, wear chemical resistant gloves, a chemical suit and rubber boots. EYE PROTECTION: Do not wear contact lenses. Wear safety glasses with side shields or goggles. OTHER PROTECTIVE EQUIPMENT: Where splashing is possible, full chemically resistant protective clothing and boots are required. HYGENIC PRACTICES: Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor Liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Wash hands before eating or smoking. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid prolonged or repeated contact with skin. Avoid breathing vapors from heated material. Avoid contact with eyes, skin, and clothing. SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store away from incompatible substances. Wash thoroughly after handling. Keep away from heat, sparks and flame. Keep container closed when not in use. OTHER PRECAUTIONS: Do not inhale mist or vapor. Keep out of reach of children. Apply with back to wind during outdoor application. SECTION X - HMIS RATINGS HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 3 REACTIVITY: 1 SECTION XI - OTHER REGULATIONS SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER WT/WT % IS LESS THAN Methyl Alcohol 67-56-1 15.0 % PREVIOUS MSDS REVISION DATE: 06/28/00 LEGEND : N.A. - Not Applicable, N.E. - Not Established N.D. - Not Determined DISCLAIMER **The Nelson Paint Company, Inc. (TNPC) expressly disclaims all expressed or implied warranties of merchantability and fitness for a particular purpose, with respect to the product or information provided herein.** All information appearing herein is based upon data obtained from the manufacturer and/or recognized technical sources. While the information is believed to be accurate, TNPC makes no representations as to its accuracy or sufficiency. Conditions of use are beyond TNPC's control and therefore users are responsible to verify this data under their own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use, handling, and disposal of the product, or from the publication or use of, or reliance upon, information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process. (END OF MSDS) Page 1066 of 1235 Page 1066 of 1235 Page 1066 of 1235 Page 1066 of 1235 ---PAGE BREAK--- MSDS No: 023030 Issue Date: 8 Jan 2010 Page: 1 of 5 MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION Trade Name: TFE Paste Part Numbers Covered: See Section 16. Product Use: Pure white thread lubricant and sealant for plastic or metal threads in heavy duty applications. Formula: See Section 3. Synonyms: Pipe thread compound. Firm Name & William H. Harvey Company Mailing Address: 4334 South 67th Street Omaha, NE 68117-1019 http://www.wmharvey.com Emergency Phone For chemical transportation emergencies ONLY, call CHEMTREC at Numbers: (800)424-9300. Outside the U.S. (703)527-3887. Information Telephone Number: (800)228-9681 Prepared By: Technical Dept. Contact: Information telephone number – (800) 228-9681 Preparation Date: January 8, 2010 SECTION 2 HAZARDS IDENTIFICATION Emergency Overview: Thick, white paste with a petroleum odor. May cause mild irritation to the eye and skin. Inhalation of vapors may cause respiratory tract irritation, and possible dizziness. Long term inhalation of dust may cause silicosis or cancer. Potential Health Effects: Skin: Irritation, including redness and dryness. Eyes: May cause mechanical irritation, redness, tearing, and blurred vision. Inhalation: Vapors may cause irritation to mucous membranes and the respiratory system. Headache, dizziness. Long term inhalation of dust may cause silicosis or cancer. Ingestion: May cause irritation to the mouth and throat. OSHA Hazard Classification: Irritant, target organ effects SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENTS: % wt/wt: CAS NUMBER: Calcium Carbonate 50 – 70% 1317-65-3 Oxidized Soy Bean Oil 10 – 30% 68152-81-8 Polytetrafluoroethylene 3 – 7% 9002-84-0 2-Butoxyethanol 3 – 7% 111-76-2 Titanium Dioxide 1 – 5% 13463-67-7 Ethoxylated 1 – 5% 9016-45-9 Alkyl Quaternary Ammonium Bentonite 1 – 5% 68953-58-2 Silica, quartz < 1.2% 14808-60-7 Page 1067 of 1235 Page 1067 of 1235 Page 1067 of 1235 Page 1067 of 1235 ---PAGE BREAK--- MSDS No: 023030 Issue Date: 8 Jan 2010 Page: 2 of 5 SECTION 4 FIRST AID MEASURES CALL TOLL FREE 1-[PHONE REDACTED] Skin: Remove contaminated clothing. Wash thoroughly with soap and water. Call a physician or poison control center if irritation develops. Eyes: Remove contact lenses if any. Rinse eyes with water for 15 minutes. Get medical attention if irritation develops. Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Keep victim quiet and warm. Call a poison control center or physician if persist. Ingestion: NEVER give anything by mouth if victim is unconscious. Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Call the Poison Control Center at 1-[PHONE REDACTED]. SECTION 5 FIRE FIGHTING MEASURES Extinguishing Media: Use dry chemical, CO2, water, or foam extinguisher. Special Fire Fighting Procedures: Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing for fires in areas where chemicals are used or stored. Unusual Fire and Explosion Hazards: None known. SECTION 6 ACCIDENTAL RELEASE MEASURES Spill or Leak Procedures: Pick up released product with appropriate implements and return to original container if reusable. If not reusable, place in appropriate containers for disposal. Appropriate personal protective equipment cited in Section 8 should be worn during all clean-up operations. SECTION 7 HANDLING AND STORAGE Handling: Avoid contact with eyes, skin, or clothing. Do not take internally. Avoid breathing vapors or fumes. Use only with adequate ventilation. Wash thoroughly after handling. Keep container closed when not in use. Handle with care. Keep out of reach of children. Storage: Store in original, labeled container. Other: Containers, even empty, will retain residue and may be harmful. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION INGREDIENTS: CAS NUMBER: ACGIH TLV TWA OSHA PEL TWA Calcium carbonate 1317-65-3 10 mg/m3 silica) 15 mg/m3 (total dust) 5 mg/m3 (respirable) 2-butoxyethanol 111-76-2 20 ppm 50 ppm Titanium dioxide 13463-67-7 10 mg/m3 15 mg/m3 (total dust) silica 14808-60-7 0.025 mg/m3 10 mg/m3 / %SiO2 Ventilation: Good general ventilation (equivalent to outdoors) should be adequate for normal use. For operations where the TLV may be exceeded, mechanical ventilation such as local exhaust may be needed to maintain exposure levels below applicable limits. Respiratory Protection: For operations where the TLV may be exceeded, a NIOSH approved particulate / organic vapor respirator or supplied air respirator is recommended. Equipment selection depends on contaminant type and concentration, select in accordance with 29 CFR 1910.134 and good industrial hygiene practice. For firefighting, use self- contained breathing apparatus. Skin Protection: Normally not needed. Launder soiled clothing before re-use. Eye Protection: Safety glasses with sideshields or safety goggles. Other: Eye wash and safety shower should be available. Page 1068 of 1235 Page 1068 of 1235 Page 1068 of 1235 Page 1068 of 1235 ---PAGE BREAK--- MSDS No: 023030 Issue Date: 8 Jan 2010 Page: 3 of 5 SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Flashpoint / Method: > 145 Degrees F (62 Degrees (Estimated) Flammability: LEL = Not determined, UEL = Not determined. Boiling Point: Not determined. Melting Point: Not determined. Vapor Pressure: Not determined. Vapor Density: (Air = 1) Greater than 1. Volatile Components: Not determined. Solubility In Water: Negligible. pH: Not applicable. Specific Gravity: 1.74 @ 20 Degrees C. Evaporation Rate: Not applicable. Appearance: Thick white paste. Odor: Petroleum odor. Will Dissolve In: Not determined. Material Is: Paste. SECTION 10 STABILITY AND REACTIVITY Stability: Stable. Conditions To Avoid: None. Hazardous Decomposition Products: Hydrocarbons, aldehydes, smoke, carbon monoxide, carbon dioxide. Oxides of nitrogen, titanium, calcium. Small amounts of hydrogen fluoride may evolve at very high temperatures. Incompatibility/ Materials To Avoid: Strong oxidizing agents, strong acids. Hazardous Polymerization: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Inhalation: Vapors may cause headache, dizziness, and irritation to mucous membranes. Dust may contain silica. Long term inhalation may cause silicosis or cancer. Above 300 degrees C, product may liberate fine particulate fume, which if inhaled, can produce polymer fume fever, a temporary flu-like condition. Skin: Contact may cause mild irritation. Eye: Vapors or fumes may cause redness and irritation. Ingestion: May cause irritation. Toxicity Data: 2-Butoxyethanol: Calcium Carbonate: ethoxylate: Oral LD50 (rat): 1,746 mg/kg. Dermal LD50 (rabbit): 435 mg/kg. Inhalation LC50 (mouse): 7h: 700ppm. Oral LD50 (rat): 6,450 mg/kg. Oral LD50 (rat): 3,310 mg/kg. Sensitization: None of the components are known to cause sensitization. Carcinogenicity: silica is listed by IARC as a Group 1 carcinogen (carcinogenic to humans). ACGIH lists silica as a suspect human carcinogen (A2). Titanium dioxide is listed by IARC as a Group 2B carcinogen (possibly carcinogenic to humans) and ACGIH lists titanium dioxide as A4 (not classifiable as a human carcinogen). Mutagenicity: None of the components have been found to be mutagenic. Reproductive Toxicity: None of the components are known to cause adverse reproductive effects. Medical Conditions Aggravated By Exposure: Persons with pre-existing skin or lung disorders may be at increased risk from exposure to this product. Page 1069 of 1235 Page 1069 of 1235 Page 1069 of 1235 Page 1069 of 1235 ---PAGE BREAK--- MSDS No: 023030 Issue Date: 8 Jan 2010 Page: 4 of 5 SECTION 12 ECOLOGICAL INFORMATION Acute Aquatic Effects Data: 2-Butoxyethanol: 24 h LC50 (goldfish): 1,650 - 1700 mg/l. 96 h LC50 (fathead minnow): 2137 mg/l. 24 h LC50 (daphnia): 1,850 mg/l. 48 h LC50 (daphnia): 835 mg/l. VOC Information: This product emits VOC’s (Volatile Organic Compounds) in its use. Make sure that use of this product complies with local VOC emission regulations, where they exist. VOC Content: 87 grams/liter Per Method 94515(b) of Title 17 of the California Code of Regulations. SECTION 13 DISPOSAL CONSIDERATIONS Waste Disposal: Dispose of in accordance with federal, state, and local regulations. It is the responsibility of the end-user to determine at the time of disposal of the product. EPA Hazardous Waste Number: None. EPA Hazard Waste Class: None. SECTION 14 TRANSPORT INFORMATION DOT Proper Shipping Name: Not regulated in quantities less than 119 gallons. Hazard Class/Packing Group: None. UN/NA Number: None. Hazard Labels: None. IMDG Proper Shipping Name: Not regulated. Hazard Class/Packing Group: None. UN/NA Number: None. Hazard Labels: None. SECTION 15 REGULATORY INFORMATION Hazard Category for Section 311/312: Acute Health, Chronic Health, Fire Section 302 Extremely Hazardous Substances (TPQ): This product does not contain chemicals regulated under SARA Title III, Section 302. Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313 Reporting requirements: Chemical CAS # % by wt. 2-Butoxyethanol 111-76-2 3 – 7% CERCLA 103 Reportable Quantity: Spills of this product over the RQ (reportable quantity) must be reported to the National Response Center. The RQ for the product, based on the RQ for 2-butoxyethanol (10% max) of 1 lb, is 10 lbs. Chemical CAS # RQ, lbs. 2-Butoxyethanol 111-76-2 * * A statutory RQ of one pound was assigned. No final RQ has been assigned to the broad class of glycol ethers. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. California Proposition 65: This product may contain a small quantity of silica and tetrafluoroethylene, which are known to the State of California to cause cancer. TSCA Inventory: All of the components of this product are listed on the TSCA inventory. Page 1070 of 1235 Page 1070 of 1235 Page 1070 of 1235 Page 1070 of 1235 ---PAGE BREAK--- MSDS No: 023030 Issue Date: 8 Jan 2010 Page: 5 of 5 SECTION 15 (continued) Canadian WHMIS Classification: Class D, Division 2, Subdivision B; B3; D1A; D2A. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. SECTION 16 OTHER INFORMATION NFPA and HMIS: NFPA Hazard Signal Health: 2 Flammability: 2 Reactivity: 0 Special: None HMIS Hazard Signal: Health: 2* Flammability: 2 Reactivity: 0 PPE: A Part Nos. Covered by this MSDS: 023001 023036 023053 023077 023257 023005 023037 023054 023090 023259 023008 023038 023055 023105 023260 023012 023040 023056 023150 023270 023013 023041 023057 023200 090 2050 023014 023042 023058 023201 090 2055 023015 023043 023059 023202 4047429 023028 023044 023060 023203 45281 023029 023045 023061 023204 45282 023030 023046 023065 023210 B13185 023031 023047 023066 023250 B13202 023032 023048 023067 023251 Premier 441007 023033 023050 023071 023253 Premier 441011 023034 023051 023074 023255 Premier 441013 023035 023052 023075 023256 PV023253 Disclaimer: The information in this MSDS was obtained from sources we believe to be reliable. However, the information is provided by the William H. Harvey Company without any warranty, express or implied, regarding its correctness. Some information presented and conclusions drawn herein are from sources other than direct test data on the substance itself. The MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. Users should make their own investigations to determine the suitability of the information or products for their particular purpose. The conditions or methods of handling, storage, use, and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, the William H. Harvey Company does not assume responsibility and expressly disclaims liability for loss, damage or expense arising out of or in any way connected with handling, storage, use or disposal of the product. Page 1071 of 1235 Page 1071 of 1235 Page 1071 of 1235 Page 1071 of 1235 ---PAGE BREAK--- MSDS No: 023030 Issue Date: 8 Jan 2010 Page: 1 of 5 MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION Trade Name: TFE Paste Part Numbers Covered: See Section 16. Product Use: Pure white thread lubricant and sealant for plastic or metal threads in heavy duty applications. Formula: See Section 3. Synonyms: Pipe thread compound. Firm Name & William H. Harvey Company Mailing Address: 4334 South 67th Street Omaha, NE 68117-1019 http://www.wmharvey.com Emergency Phone For chemical transportation emergencies ONLY, call CHEMTREC at Numbers: (800)424-9300. Outside the U.S. (703)527-3887. Information Telephone Number: (800)228-9681 Prepared By: Technical Dept. Contact: Information telephone number – (800) 228-9681 Preparation Date: January 8, 2010 SECTION 2 HAZARDS IDENTIFICATION Emergency Overview: Thick, white paste with a petroleum odor. May cause mild irritation to the eye and skin. Inhalation of vapors may cause respiratory tract irritation, and possible dizziness. Long term inhalation of dust may cause silicosis or cancer. Potential Health Effects: Skin: Irritation, including redness and dryness. Eyes: May cause mechanical irritation, redness, tearing, and blurred vision. Inhalation: Vapors may cause irritation to mucous membranes and the respiratory system. Headache, dizziness. Long term inhalation of dust may cause silicosis or cancer. Ingestion: May cause irritation to the mouth and throat. OSHA Hazard Classification: Irritant, target organ effects SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENTS: % wt/wt: CAS NUMBER: Calcium Carbonate 50 – 70% 1317-65-3 Oxidized Soy Bean Oil 10 – 30% 68152-81-8 Polytetrafluoroethylene 3 – 7% 9002-84-0 2-Butoxyethanol 3 – 7% 111-76-2 Titanium Dioxide 1 – 5% 13463-67-7 Ethoxylated 1 – 5% 9016-45-9 Alkyl Quaternary Ammonium Bentonite 1 – 5% 68953-58-2 Silica, quartz < 1.2% 14808-60-7 Page 1072 of 1235 Page 1072 of 1235 Page 1072 of 1235 Page 1072 of 1235 ---PAGE BREAK--- MSDS No: 023030 Issue Date: 8 Jan 2010 Page: 2 of 5 SECTION 4 FIRST AID MEASURES CALL TOLL FREE 1-[PHONE REDACTED] Skin: Remove contaminated clothing. Wash thoroughly with soap and water. Call a physician or poison control center if irritation develops. Eyes: Remove contact lenses if any. Rinse eyes with water for 15 minutes. Get medical attention if irritation develops. Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Keep victim quiet and warm. Call a poison control center or physician if persist. Ingestion: NEVER give anything by mouth if victim is unconscious. Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Call the Poison Control Center at 1-[PHONE REDACTED]. SECTION 5 FIRE FIGHTING MEASURES Extinguishing Media: Use dry chemical, CO2, water, or foam extinguisher. Special Fire Fighting Procedures: Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing for fires in areas where chemicals are used or stored. Unusual Fire and Explosion Hazards: None known. SECTION 6 ACCIDENTAL RELEASE MEASURES Spill or Leak Procedures: Pick up released product with appropriate implements and return to original container if reusable. If not reusable, place in appropriate containers for disposal. Appropriate personal protective equipment cited in Section 8 should be worn during all clean-up operations. SECTION 7 HANDLING AND STORAGE Handling: Avoid contact with eyes, skin, or clothing. Do not take internally. Avoid breathing vapors or fumes. Use only with adequate ventilation. Wash thoroughly after handling. Keep container closed when not in use. Handle with care. Keep out of reach of children. Storage: Store in original, labeled container. Other: Containers, even empty, will retain residue and may be harmful. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION INGREDIENTS: CAS NUMBER: ACGIH TLV TWA OSHA PEL TWA Calcium carbonate 1317-65-3 10 mg/m3 silica) 15 mg/m3 (total dust) 5 mg/m3 (respirable) 2-butoxyethanol 111-76-2 20 ppm 50 ppm Titanium dioxide 13463-67-7 10 mg/m3 15 mg/m3 (total dust) silica 14808-60-7 0.025 mg/m3 10 mg/m3 / %SiO2 Ventilation: Good general ventilation (equivalent to outdoors) should be adequate for normal use. For operations where the TLV may be exceeded, mechanical ventilation such as local exhaust may be needed to maintain exposure levels below applicable limits. Respiratory Protection: For operations where the TLV may be exceeded, a NIOSH approved particulate / organic vapor respirator or supplied air respirator is recommended. Equipment selection depends on contaminant type and concentration, select in accordance with 29 CFR 1910.134 and good industrial hygiene practice. For firefighting, use self- contained breathing apparatus. Skin Protection: Normally not needed. Launder soiled clothing before re-use. Eye Protection: Safety glasses with sideshields or safety goggles. Other: Eye wash and safety shower should be available. Page 1073 of 1235 Page 1073 of 1235 Page 1073 of 1235 Page 1073 of 1235 ---PAGE BREAK--- MSDS No: 023030 Issue Date: 8 Jan 2010 Page: 3 of 5 SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Flashpoint / Method: > 145 Degrees F (62 Degrees (Estimated) Flammability: LEL = Not determined, UEL = Not determined. Boiling Point: Not determined. Melting Point: Not determined. Vapor Pressure: Not determined. Vapor Density: (Air = 1) Greater than 1. Volatile Components: Not determined. Solubility In Water: Negligible. pH: Not applicable. Specific Gravity: 1.74 @ 20 Degrees C. Evaporation Rate: Not applicable. Appearance: Thick white paste. Odor: Petroleum odor. Will Dissolve In: Not determined. Material Is: Paste. SECTION 10 STABILITY AND REACTIVITY Stability: Stable. Conditions To Avoid: None. Hazardous Decomposition Products: Hydrocarbons, aldehydes, smoke, carbon monoxide, carbon dioxide. Oxides of nitrogen, titanium, calcium. Small amounts of hydrogen fluoride may evolve at very high temperatures. Incompatibility/ Materials To Avoid: Strong oxidizing agents, strong acids. Hazardous Polymerization: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Inhalation: Vapors may cause headache, dizziness, and irritation to mucous membranes. Dust may contain silica. Long term inhalation may cause silicosis or cancer. Above 300 degrees C, product may liberate fine particulate fume, which if inhaled, can produce polymer fume fever, a temporary flu-like condition. Skin: Contact may cause mild irritation. Eye: Vapors or fumes may cause redness and irritation. Ingestion: May cause irritation. Toxicity Data: 2-Butoxyethanol: Calcium Carbonate: ethoxylate: Oral LD50 (rat): 1,746 mg/kg. Dermal LD50 (rabbit): 435 mg/kg. Inhalation LC50 (mouse): 7h: 700ppm. Oral LD50 (rat): 6,450 mg/kg. Oral LD50 (rat): 3,310 mg/kg. Sensitization: None of the components are known to cause sensitization. Carcinogenicity: silica is listed by IARC as a Group 1 carcinogen (carcinogenic to humans). ACGIH lists silica as a suspect human carcinogen (A2). Titanium dioxide is listed by IARC as a Group 2B carcinogen (possibly carcinogenic to humans) and ACGIH lists titanium dioxide as A4 (not classifiable as a human carcinogen). Mutagenicity: None of the components have been found to be mutagenic. Reproductive Toxicity: None of the components are known to cause adverse reproductive effects. Medical Conditions Aggravated By Exposure: Persons with pre-existing skin or lung disorders may be at increased risk from exposure to this product. Page 1074 of 1235 Page 1074 of 1235 Page 1074 of 1235 Page 1074 of 1235 ---PAGE BREAK--- MSDS No: 023030 Issue Date: 8 Jan 2010 Page: 4 of 5 SECTION 12 ECOLOGICAL INFORMATION Acute Aquatic Effects Data: 2-Butoxyethanol: 24 h LC50 (goldfish): 1,650 - 1700 mg/l. 96 h LC50 (fathead minnow): 2137 mg/l. 24 h LC50 (daphnia): 1,850 mg/l. 48 h LC50 (daphnia): 835 mg/l. VOC Information: This product emits VOC’s (Volatile Organic Compounds) in its use. Make sure that use of this product complies with local VOC emission regulations, where they exist. VOC Content: 87 grams/liter Per Method 94515(b) of Title 17 of the California Code of Regulations. SECTION 13 DISPOSAL CONSIDERATIONS Waste Disposal: Dispose of in accordance with federal, state, and local regulations. It is the responsibility of the end-user to determine at the time of disposal of the product. EPA Hazardous Waste Number: None. EPA Hazard Waste Class: None. SECTION 14 TRANSPORT INFORMATION DOT Proper Shipping Name: Not regulated in quantities less than 119 gallons. Hazard Class/Packing Group: None. UN/NA Number: None. Hazard Labels: None. IMDG Proper Shipping Name: Not regulated. Hazard Class/Packing Group: None. UN/NA Number: None. Hazard Labels: None. SECTION 15 REGULATORY INFORMATION Hazard Category for Section 311/312: Acute Health, Chronic Health, Fire Section 302 Extremely Hazardous Substances (TPQ): This product does not contain chemicals regulated under SARA Title III, Section 302. Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313 Reporting requirements: Chemical CAS # % by wt. 2-Butoxyethanol 111-76-2 3 – 7% CERCLA 103 Reportable Quantity: Spills of this product over the RQ (reportable quantity) must be reported to the National Response Center. The RQ for the product, based on the RQ for 2-butoxyethanol (10% max) of 1 lb, is 10 lbs. Chemical CAS # RQ, lbs. 2-Butoxyethanol 111-76-2 * * A statutory RQ of one pound was assigned. No final RQ has been assigned to the broad class of glycol ethers. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. California Proposition 65: This product may contain a small quantity of silica and tetrafluoroethylene, which are known to the State of California to cause cancer. TSCA Inventory: All of the components of this product are listed on the TSCA inventory. Page 1075 of 1235 Page 1075 of 1235 Page 1075 of 1235 Page 1075 of 1235 ---PAGE BREAK--- MSDS No: 023030 Issue Date: 8 Jan 2010 Page: 5 of 5 SECTION 15 (continued) Canadian WHMIS Classification: Class D, Division 2, Subdivision B; B3; D1A; D2A. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. SECTION 16 OTHER INFORMATION NFPA and HMIS: NFPA Hazard Signal Health: 2 Flammability: 2 Reactivity: 0 Special: None HMIS Hazard Signal: Health: 2* Flammability: 2 Reactivity: 0 PPE: A Part Nos. Covered by this MSDS: 023001 023036 023053 023077 023257 023005 023037 023054 023090 023259 023008 023038 023055 023105 023260 023012 023040 023056 023150 023270 023013 023041 023057 023200 090 2050 023014 023042 023058 023201 090 2055 023015 023043 023059 023202 4047429 023028 023044 023060 023203 45281 023029 023045 023061 023204 45282 023030 023046 023065 023210 B13185 023031 023047 023066 023250 B13202 023032 023048 023067 023251 Premier 441007 023033 023050 023071 023253 Premier 441011 023034 023051 023074 023255 Premier 441013 023035 023052 023075 023256 PV023253 Disclaimer: The information in this MSDS was obtained from sources we believe to be reliable. However, the information is provided by the William H. Harvey Company without any warranty, express or implied, regarding its correctness. Some information presented and conclusions drawn herein are from sources other than direct test data on the substance itself. The MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. Users should make their own investigations to determine the suitability of the information or products for their particular purpose. The conditions or methods of handling, storage, use, and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, the William H. Harvey Company does not assume responsibility and expressly disclaims liability for loss, damage or expense arising out of or in any way connected with handling, storage, use or disposal of the product. Page 1076 of 1235 Page 1076 of 1235 Page 1076 of 1235 Page 1076 of 1235 ---PAGE BREAK--- Page 1077 of 1235 Page 1077 of 1235 Page 1077 of 1235 Page 1077 of 1235 ---PAGE BREAK--- Page 1078 of 1235 Page 1078 of 1235 Page 1078 of 1235 Page 1078 of 1235 ---PAGE BREAK--- Page 1079 of 1235 Page 1079 of 1235 Page 1079 of 1235 Page 1079 of 1235 ---PAGE BREAK--- Page 1080 of 1235 Page 1080 of 1235 Page 1080 of 1235 Page 1080 of 1235 ---PAGE BREAK--- Titebond III Ultimate Wood Glue None known. Liquid. GHS product identifier Other means of identification Product type Section 1. Identification : : : Relevant identified uses of the substance or mixture and uses advised against Wide dispersive use of substances in professional and DIY adhesives. Industrial use wood glue. Identified uses 1414 Franklin Security (614) 445-1300 Franklin International 2020 Bruck Street Columbus OH 43207 6/4/2015. 6/3/2015. mixture Franklin Technical Services (800) 877-4583 6192 (800) 424 - 9300 (703) 527 - 3887 Adhesive. : : : : : : : : : : : : CAS # Address Product code Date of revision Print date In case of emergency Contact person Telephone Reference number Chemtrec (24 Hour) Chemtrec International Chemical family Safety Data Sheet Titebond III Ultimate Wood Glue Section 2. Hazards identification Not classified. Classification of the substance or mixture : Signal word : No signal word. Hazard statements : No known significant effects or critical hazards. Precautionary statements GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 6.3% General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product. Hazards not otherwise classified : None known. Date of issue/Date of revision : 6/3/2015. Version : 4.1 1/10 Page 1081 of 1235 Page 1081 of 1235 Page 1081 of 1235 Page 1081 of 1235 ---PAGE BREAK--- Titebond III Ultimate Wood Glue Section 3. Composition/information on ingredients There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. Hazardous ingredients Name CAS number % No hazardous ingredient IDLH H F R Special Classification UN number Mexico No hazardous ingredient Name CAS number % No hazardous ingredient Name CAS number % United States Canada Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if occur. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if occur. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if occur. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Notes to physician : Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Description of necessary first aid measures Most important acute and delayed Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. : Eye contact Over-exposure Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : No specific data. Potential acute health effects Indication of immediate medical attention and special treatment needed, if necessary Date of issue/Date of revision : 6/3/2015. Version : 4.1 2/10 Page 1082 of 1235 Page 1082 of 1235 Page 1082 of 1235 Page 1082 of 1235 ---PAGE BREAK--- Titebond III Ultimate Wood Glue Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. Specific treatments : No specific treatment. See toxicological information (Section 11) Section 5. Fire-fighting measures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision : 6/3/2015. Version : 4.1 3/10 Page 1083 of 1235 Page 1083 of 1235 Page 1083 of 1235 Page 1083 of 1235 ---PAGE BREAK--- Titebond III Ultimate Wood Glue Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store between the following temperatures: -15.309 to 23.889°C (4.4 to 75°F). Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section : Precautions for safe handling No exposure limit value known. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Control parameters Individual protection measures Occupational exposure limits Consult local authorities for acceptable exposure limits. No exposure limit value known. Canada Mexico Ingredient Exposure limits Occupational exposure limits Ingredient List name ppm mg/ m³ Other ppm mg/ m³ Other ppm mg/ m³ Other Notations No exposure limit value known. TWA (8 hours) STEL (15 mins) Ceiling Occupational exposure limits United States Date of issue/Date of revision : 6/3/2015. Version : 4.1 4/10 Page 1084 of 1235 Page 1084 of 1235 Page 1084 of 1235 Page 1084 of 1235 ---PAGE BREAK--- Titebond III Ultimate Wood Glue Section 8. Exposure controls/personal protection Hand protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Relative density Solubility Liquid. Not available. 1.11 Soluble in the following materials: cold water and hot water. Characteristic. [Slight] Odor pH Brown. [Light] Color Evaporation rate Flash point Closed cup: >93.333°C (>200°F) [Setaflash.] 2.5 to 3.5 Not available. Odor threshold : : : : : : : : : : Appearance Boiling point : 98.889°C (210°F) VOC (less water, less exempt solvents) : 5.6 g/l <1 (butyl acetate = 1) Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Date of issue/Date of revision : 6/3/2015. Version : 4.1 5/10 Page 1085 of 1235 Page 1085 of 1235 Page 1085 of 1235 Page 1085 of 1235 ---PAGE BREAK--- Titebond III Ultimate Wood Glue Section 11. Toxicological information Information on the likely routes of exposure Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards. : Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards. : Eye contact related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : No specific data. Delayed and immediate effects and also chronic effects from short and long term exposure Information on toxicological effects : Routes of entry not anticipated: Oral, Dermal, Inhalation. Potential acute health effects Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Section 12. Ecological information Other adverse effects : No known significant effects or critical hazards. Toxicity Conclusion/Summary : Not available. Persistence and degradability Not available. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. : Disposal methods Date of issue/Date of revision : 6/3/2015. Version : 4.1 6/10 Page 1086 of 1235 Page 1086 of 1235 Page 1086 of 1235 Page 1086 of 1235 ---PAGE BREAK--- Titebond III Ultimate Wood Glue Section 14. Transport information - - - - - - - Not regulated. - - Not regulated. Not regulated. - - - DOT Classification IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No. No. No. Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. : TDG Classification Not regulated. - - - No. - ADR/RID Not regulated. - - - No. - Mexico Classification Not regulated. - - - No. - Section 15. Regulatory information U.S. Federal regulations None of the components are listed. Massachusetts : : Clean Air Act Section 112 Hazardous Air Pollutants (HAPs) : Not listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed State regulations TSCA 8(a) CDR Exempt/Partial exemption: Not determined SARA 302/304 SARA 304 RQ : Not applicable. No products were found. Composition/information on ingredients SARA 311/312 Classification : Not applicable. No products were found. Composition/information on ingredients All components are listed or exempted. United States inventory (TSCA 8b): Date of issue/Date of revision : 6/3/2015. Version : 4.1 7/10 Page 1087 of 1235 Page 1087 of 1235 Page 1087 of 1235 Page 1087 of 1235 ---PAGE BREAK--- Titebond III Ultimate Wood Glue Section 15. Regulatory information Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level California Prop. 65 New York : None of the components are listed. New Jersey : None of the components are listed. : None of the components are listed. None of the components are listed. Australia inventory (AICS): Not determined. China inventory (IECSC): Not determined. Japan inventory: Not determined. Korea inventory: Not determined. Malaysia Inventory (EHS Register): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan inventory (CSNN): Not determined. International regulations International lists : Canada Mexico 1 0 0 Health Flammability Reactivity Special Classification : This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Canadian NPRI : Canada inventory : Not determined. Chemical Weapons Convention List Schedule I Chemicals : Not listed Chemical Weapons Convention List Schedule II Chemicals : Not listed Chemical Weapons Convention List Schedule III Chemicals : Not listed CEPA Toxic substances : None of the components are listed. Canadian lists Not applicable. Not available. Europe : Not determined. Date of issue/Date of revision : 6/3/2015. Version : 4.1 8/10 Page 1088 of 1235 Page 1088 of 1235 Page 1088 of 1235 Page 1088 of 1235 ---PAGE BREAK--- Titebond III Ultimate Wood Glue Section 16. Other information 6/4/2015. History Date of printing Date of issue/Date of revision Version Notice to reader Date of previous issue : : : : Indicates information that has changed from previously issued version. References : Not available. Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 6/3/2015. 5/22/2015. 4.1 Hazardous Material Information System 0 1 0 0 1 0 National Fire Protection Association Health Special Instability/Reactivity Flammability Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Date of issue/Date of revision : 6/3/2015. Version : 4.1 9/10 Page 1089 of 1235 Page 1089 of 1235 Page 1089 of 1235 Page 1089 of 1235 ---PAGE BREAK--- Titebond III Ultimate Wood Glue Section 16. Other information To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue/Date of revision : 6/3/2015. Version : 4.1 10/10 Page 1090 of 1235 Page 1090 of 1235 Page 1090 of 1235 Page 1090 of 1235 ---PAGE BREAK--- Tree & Log Marking Paint Page 1 of 4 MATERIAL SAFETY DATA SHEET SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION Product identifier: Tree & Log Marking Paint Product Numbers: 3242 Blue, 3244A Red, 3145 Green, 3246 Black, 3247 White, 3141LF Yellow, 3143LF Orange, 6242 Dark Blue, 6245 Dark Green, 6249 Gray, 3142FL Blue-Glo, 3144FL Orange-Glo, 3145FL Green-Glo, 3148FL Pink-Glo, 3149FL Red-Glo. Product use: Nelson Aerosol: Industrial forestry marking in pressurized spray containers. Supplier name and address: Manufacturer's name and address: Nelson Paint Company of Canada Refer to supplier 48 Industrial Park Crescent Sault Ste. Marie, ON, Canada P6B 5P2 Emergency Telephone [PHONE REDACTED] (Canutec) SECTION 2 —COMPOSITION / INFORMATION ON INGREDIENTS LC50 (rat, inh) LD50 (mg/kg) Ingredients CAS # % (weight) (4hr) rat, oral dermal, rabbit Petroleum solvent 64742-88-7 15 – 40 > 5500 mg/m3 > 5000 > 2000 Methanol 67-56-1 7 – 10 64,000 ppm 5628 15,800 Propane (propellant) 74-98-6 10 – 20 N/Av N/Ap N/Ap 3246 Black and 6249 Gray also contain: Carbon black 1333-86-4 0.1 – 1.0 6750 mg/m3 > 15,400 > 3000 SECTION 3 — HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Liquid aerosol, various colours. Solvent odour. Danger! Flammable aerosol. Contents under pressure. May be harmful if inhaled, swallowed or absorbed through the skin in large amounts. May cause blindness if swallowed. Causes eye irritation. ***POTENTIAL HEALTH EFFECTS*** Target organs: Eyes, skin, respiratory system, digestive system, central nervous system (CNS) Signs and of short-term (acute) exposure: Inhalation: Inhalation of mists or vapours may cause irritation to the nose, throat and upper respiratory tract. Additional may include headache, nausea, vomiting, dizziness, loss of co-ordination and other central nervous system (CNS) effects. In high concentrations, affected person may experience a latent period, which could then be followed by visual effects including sensitivity to light and blurred vision. Product could potentially act as an and cause increased breathing and pulse rates, fatigue, nausea and vomiting. Skin contact: Liquid concentrate may be irritating to the skin. Product may be absorbed if left on the skin, causing similar to those listed for inhalation. Spraying product directly onto skin could cause of frostbite including numbness, prickling and itching. Eye contact: Liquid concentrate causes moderate irritation to the eyes. Spraying product directly into eyes could cause freezing of the eye. Ingestion: Liquid concentrate is poisonous if swallowed. Causes severe irritation to mouth, throat, and stomach. Severe stomach pains, vomiting and diarrhea may follow. Ingestion of extremely large amounts could cause the product to be absorbed. Absorption could cause additional similar to those listed for inhalation. Blindness or death may occur. Effects of long-term (chronic) exposure: Prolonged skin contact may cause drying and cracking of the skin (dermatitis). Other important hazards: Continual and prolonged overexposure to solvents has been shown to cause CNS effects. For further information on other important hazards, see TOXICOLOGICAL INFORMATION, Section 11. Page 1091 of 1235 Page 1091 of 1235 Page 1091 of 1235 Page 1091 of 1235 ---PAGE BREAK--- Tree & Log Marking Paint Page 2 of 4 SECTION 4 — FIRST AID MEASURES Inhalation: Immediately remove to fresh air. Obtain medical attention. Skin contact: Remove contaminated clothing and wash skin with plenty of soap and water. Obtain medical attention if irritation persists. Eye contact: Flush immediately with water for at least 15 minutes. Obtain medical attention. Ingestion: Contact a physician immediately. Inducing vomiting should only be performed under the direct supervision of medical personnel. If the person is conscious, have victim rinse mouth with water. Give one to two glasses of water to drink to dilute material in the stomach. Never give anything by mouth to an unconscious person. SECTION 5 — FIRE FIGHTING MEASURES Fire hazards/conditions of flammability: Extremely flammable aerosol. Cans are pressurized to 60 - 80 psi (414 – 552 kPa) at 21oC and can explode if heated above 49oC. Vapours are heavier than air and may collect in confined and low-lying areas. The vapours can travel considerable distances and flashback to a source of ignition. Flash point (Method): 24oC (TCC) (estimated) Auto-ignition temperature: N/Av Lower flammable limit by volume): 1.9 Upper flammable limit by volume): 9.5 Explosion data: Sensitivity to mechanical impact / static discharge: N/Av Oxidizing properties: No Suitable extinguishing media: Carbon dioxide, dry chemical, water fog. Special fire-fighting procedures/equipment: Self Contained Breathing Apparatus (SCBA) & protective clothing must be worn by fire fighting personnel. Move containers from fire area if it can be done without risk. Use water spray to cool fire exposed equipment and containers. Avoid spreading burning liquid with water spray used for cooling purposes. Hazardous combustion products: Carbon oxides, formaldehyde gas and other irritating fumes. Nitrogen oxides and sulfur oxides may also be released during a fire. SECTION 6 — ACCIDENTAL RELEASE MEASURES Personal precautions: Restrict access to area until completion of clean-up. Ensure clean-up is conducted by trained personnel only. All persons dealing with clean-up should wear the appropriate protective equipment including self-contained breathing apparatus. Keep all other personnel upwind and away from the spill/release. Environmental precautions: Ensure spilled product does not enter drains, sewers, waterways, or confined spaces. For large spills, dike far ahead of the spill for later recovery or disposal. Spill response/Cleanup: Avoid breathing vapours or mists. Increase ventilation in area of release to prevent the build-up of a flammable / explosive atmosphere. Eliminate all sources of ignition and heat. Stop leak if you can do so without risk. Contain any spilled liquid concentrate and absorb with inert, non-combustible absorbent material, then place absorbent material into a container for later disposal (see Section 13). Contaminated absorbent material may pose the same hazards as the spilled product. Notify the appropriate authorities as required. Prohibited materials: None known. SECTION 7 — HANDLING AND STORAGE Safe handling procedures: Wear appropriate protective equipment. Use in a well ventilated area. Avoid inhalation of vapours or mists. Avoid prolonged or repeated contact with skin and clothing. Avoid contact with eyes. Do not use near sparks, heat or open flame. Keep cans out of direct sunlight. Turn cans upside down, empty the tube, and replace cap when through using. Do not puncture or incinerate. Wash thoroughly after handling. Storage requirements: Store indoors at temperatures of 4 to 32oC, and away from incompatibles. Do not store near furnaces or other sources of heat. Cans are hazardous when emptied; all labelled precautions must be observed. Inspect periodically for damage or leaks. No smoking in the area. Incompatible materials: Oxidizing agents (e.g. Chlorine, Peroxides, etc.), strong acids (e.g. Sulfuric acid), strong bases (e.g. Sodium hydroxide). Page 1092 of 1235 Page 1092 of 1235 Page 1092 of 1235 Page 1092 of 1235 ---PAGE BREAK--- Tree & Log Marking Paint Page 3 of 4 SECTION 8 — EXPOSURE CONTROLS / PERSONAL PROTECTION Permissible exposure levels: Ingredient name: OSHA PEL ACGIH TLV Petroleum solvent *500 ppm *100 ppm Methanol 200 ppm 200 ppm (skin) Propane (propellant) 1000 ppm *1000 ppm 3246 Black and 6249 Gray also contain: Carbon black 3.5 mg/m3 3.5 mg/m3 *Note: The OSHA PEL and ACGIH TLV listed above for Petroleum solvent is for “Stoddard Solvent”. The ACGIH TLV listed above for Propane is for “Aliphatic hydrocarbon gases”. Ventilation and engineering controls: Must be adequate to control vapours and mists below TLV levels. Product normally used outdoors. Respiratory protection: Use of NIOSH-approved respirators or face masks advisable in windy conditions. Advice should be sought from respiratory protection specialists. Protective gloves: Gloves impervious to the material are recommended. Confirmation of what type of material is most suitable for the intended application, should be obtained from glove suppliers. Eye protection: Use safety splash goggles when transferring paint or solvent, or during spraying applications. Other protective equipment: Eyewash bottles should be readily available at all times. Other protective equipment may be required as prescribed by workplace standards. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES Odour and appearance: Solvent odour. Colour is dependant on the product number being used. Physical State: Liquid aerosol. Odour threshold: N/Av pH: N/Av Boiling point: 150 – 205oC Vapour pressure: 60 – 70 psig (414 – 483 kPa) @ 20oC Freezing point: N/Av Solubility in water: Insoluble Coefficient of oil/water distribution: N/Av Specific gravity: 0.98 – 1.10 @25oC Vapour density (Air = >1 Evaporation rate (Ether = Slower than ether Volatiles 50.3 – 64.0 SECTION 10 — STABILITY AND REACTIVITY Stability and reactivity: Stable under the recommended storage and handling conditions prescribed. Hazardous polymerization will not occur. Conditions to avoid: Avoid heat, sparks, open flame and direct sunlight. Stable under ambient pressure and temperature. Materials to avoid: Incompatible materials (see Section Hazardous decomposition products: None known. Refer to ‘Hazardous combustion products’, Section 5. SECTION 11 — TOXICOLOGICAL INFORMATION Routes of exposure: Eye contact, skin contact, skin absorption, inhalation and ingestion. Toxicological data: There is no available data for the product itself. See Section 2 for ingredient LD50 and LC50 data. Carcinogenicity: Product numbers 3246 and 6249 contain Carbon black. Carbon black is classified by IARC as possibly carcinogenic to humans, based on animal evidence (Group 2B). Teratogenicity, mutagenicity, other reproductive effects: These products contain Methanol. Methanol may cause fetotoxic and teratogenic effects, based on animal data. Sensitization to material: No skin or respiratory sensitization effects are known. Synergistic materials: Not available. SECTION 12 — ECOLOGICAL INFORMATION Environmental effects: The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. Important environmental characteristics: N/Av Aquatic toxicity: There is no data available on the product itself. Page 1093 of 1235 Page 1093 of 1235 Page 1093 of 1235 Page 1093 of 1235 ---PAGE BREAK--- Tree & Log Marking Paint Page 4 of 4 SECTION 13 —DISPOSAL CONSIDERATIONS Handling for disposal: Handle waste according to recommendations in Section 7. Methods of disposal: Containers should be disposed of in accordance with all applicable local, provincial and federal regulations. SECTION 14 — TRANSPORT INFORMATION Transportation of Dangerous Goods Regulations (TDGR) information: The product, as supplied, can be shipped under the Limited Quantity Exemption within Canada. Refer to Section 1.17 for additional Limited Quantity requirements, if shipping under this exemption. SECTION 15 — REGULATORY INFORMATION WHMIS information: Class A (Compressed Gas), Class B5 (Flammable Aerosol), Class D2A (Materials Causing Other Toxic Effects, Very Toxic Material), Class D2B (Materials Causing Other Toxic Effects, Toxic Material). This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and this MSDS contains all the information required by the CPR. CEPA information: All ingredients are listed on the DSL. TSCA information: All ingredients are listed on the TSCA inventory. SECTION 16 — OTHER INFORMATION Prepared by: Nelson Paint Company of Canada Telephone number: [PHONE REDACTED] Preparation date: January 5, 2010 Legend: ACGIH – American Conference of Governmental Industrial Hygienists NIOSH – National Institute for Occupational Safety and Health RTECS: Registry of Toxic Effects of Chemical Substances WHMIS – Workplace Hazardous Material Information System TSCA – Toxic Substances Control Act CEPA – Canadian Environmental Protection Act CAS: Chemical Abstract Services HSDB: Hazardous Substances Data Bank DSL – Domestic Substances List IARC – International Agency for Research on Cancer Inh – Inhalation N/Ap – Not Applicable N/Av – Not Available OSHA – Occupational Safety and Health Act PEL: Permissible Exposure Limit TCC: Tagliabue Closed Cup TLV – Threshold Limit Value References: 1. Canadian Centre for Occupational Health and Safety, CCInfoWeb databases, 2007 (Chempendium, HSDB and RTECs). 2. Material Safety Data Sheet from manufacturer. 3. ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents & Biological Exposure Indices for 2006. 4. International Agency for Research on Cancer Monographs, searched 2007. DISCLAIMER OF LIABILITY **The Nelson Paint Company Of Canada (TNPC) expressly disclaims all expressed or implied warranties of merchantability and fitness for a particular purpose, with respect to the product or information provided herein.** All information appearing herein is based upon the data obtained from the manufacturer and/or recognized technical sources. While the information is believed to be accurate, TNPC makes no representations as to its accuracy or sufficiency. Conditions of use are beyond TNPC’s control and therefore users are responsible to verify this data under their own operating conditions to determine whether the product is suitable from their particular purposes and they assume all risks, of their use, handling, and disposal of the product, or from the publication or use of, or reliance upon, information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process. END OF DOCUMENT Page 1094 of 1235 Page 1094 of 1235 Page 1094 of 1235 Page 1094 of 1235 ---PAGE BREAK--- TURTLE WAX, INC. 625 WILLOWBROOK CTR PKWY WILLOWBROOK, IL 60527 SAFETY DATA SHEET 1. Product and Company Identification 1.1 Product Identifier Product Name: Turtle Wax Bug & Tar Remover - Spray Product Code (SKU): T520A (50382), T520A4PK (50383), T520AC (50384) 1.2 Relevant Identified Uses Of The Substance Product Use: Bug & Tar Remover (Non-Aerosol) 1.3 Details of the Supplier of the SDS Company Name: Turtle Wax, Inc. Street Address: 625 Willowbrook Centre Parkway City, State, Zip Code: Willowbrook, Illinois 60527 1.4 Emergency Telephone Numbers Phone Number: 1(630)455-3700 Fax Number: 1(630)455-3868 Transportation: 1(800)424-9300 (CHEMTREC) Medical Assistance: Call your local Poison Control Center 2. Hazard Identification: 2.1 Classification of the Substance or Mixture Hazard Classification: Flammable Liquid 3 Serious Eye Irritation 2A Skin Sensitization 1 Aspiration Hazard 1 2.2 Label Elements Pictogram: Signal Word: Danger Hazard Statement: Flammable liquid and vapor. Causes serious eye irritation. May cause an allergic skin reaction. May be fatal if swallowed and enters airways. Precautionary Statement: Keep away from heat, sparks, hot surfaces, and open flames. No smoking. Keep container closed. Ground container and receiving equipment. Use explosion proof ventilation, lighting, and tools. Protect against static charge. Avoid breathing fumes, vapors, and spray. Wash hands thoroughly after handling. Wear protective gloves, goggles, and clothing. If on skin or hair, remove immediately all clothing and launder before re-use. If irritation occurs, get medical attention. If in eyes, rinse Page 1095 of 1235 Page 1095 of 1235 Page 1095 of 1235 Page 1095 of 1235 ---PAGE BREAK--- thoroughly with water for 15 minutes. Remove contact lenses if easy to do. If eye irritation persists, get medical attention. If swallowed, call a poison control center or a physician immediately. Do not induce vomiting. Store in a cool, well ventilated place. Dispose of in accordance with local, state, and federal regulations. 2.3 Other Hazards Description of additional HNOC: None 3. Information on Ingredients: 3.1 Substance not applicable 3.2 Mixture Component CAS Number Concentration (wt%) Petroleum Distillates Hydroteated Light 64742-47-8 20-30% Isopropyl Alcohol 67-63-0 1-5% 2-Butoxyethanol 111-76-2 1-5% Amides, Tall-oil fatty, N,N-bis (Hydroxyethyl) 68155-20-4 0.5-1.5% Hydrocarbons, terpene processing by products 68956-56-9 0.1-1.0% 1,2-Dibromo-2,4-dicyanobutane 35691-65-7 0.1 – 1. 4. First Aid Measures: 4.1 Description of First Aid Measures Inhalation: Remove to fresh air and promote deep breathing. Get medical attention if effects persist. Skin: In case of skin contact, wash thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If irritation persists, get medical attention. Eyes: In case of eye contact, immediately flush eyes with plenty of water. Remove contact lenses if worn. If irritation persists, get medical attention Ingestion: If swallowed, do not induce vomiting. Never give anything by mouth to an unconscious person. Call a poison control center or physician immediately. 4.2 Most important and effects – acute and chronic Inhalation: May cause respiratory tract irritation. Skin: May cause skin irritation. Contact may cause redness, drying, de-fatting, and cracking of the skin. Contact may cause sensitization by skin contact. Eyes: Cause serious eye irritation. may include discomfort, excess blinking, and tearing, with redness and conjunctiva. Ingestion: May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea, and vomiting. 4.3 Indication of any immediate medical attention and special treatment may not appear immediately. Seek medical attention if effects persist and you feel un- well. 5. Fire Fighting Measures: Page 1096 of 1235 Page 1096 of 1235 Page 1096 of 1235 Page 1096 of 1235 ---PAGE BREAK--- 5.1 Extinguishing media Water spray, carbon dioxide, dry chemical, and alcohol foam 5.2 Special hazards arising from the substance or mixture CO2, CO, and hydrocarbons 5.3 Advice for Fire Fighters Keep up wind of fire. Wear full firefighting turn out gear (full bunker gear) and respiratory protection (SCBA). See Section 8 for personal protection. 6. Accidental Release Measures: 6.1 Personal precautions, protective equipment, and emergency procedures Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. 6.2 Methods and materials for containment and clean up For containment: Contain and absorb spill with inert material. Place in suitable container for disposal. Spilled material may be slippery. For clean up: Take up material and place in a suitable container. Provide adequate ventilation. Spilled material may be slippery. 7. Handling and Storage 7.1 Precautions for safe handling Avoid contact with skin and eyes. Do not swallow. Do not eat, drink or smoke while handling. Wash hands with soap and water after handling. Launder all clothing and foot wear before re- use. Use only non-sparking tools. Keep away from sparks, open flames, and hot surfaces. 7.2 Conditions for safe storage including incompatibilities Keep out of reach of children. Keep container closed. Store in a well ventilated place. Do not store above 49°C (120°F). 7.3 Specific end uses Shelf Life: Shelf life is considered to be 7 – 10 years when properly stored and kept closed. 8. Exposure Control/Personal Protection: 8.1 Control parameters Exposure Limits 8 hr TWA: (OSHA PEL) (ACGIH TWA) Petroleum Distillate, Hydrotreated Light 100 ppm 200 ppm (64742-47-8) Isopropyl Alcohol (67-63-0) 400 ppm 400 ppm 2-Butoxyethanol (111-76-2) 50 ppm 20 ppm Amides, Tall-oil fatty N,N-bis(hydroxyethyl) not applicable not applicable (68155-20-4) Hydrocarbon, terpene processing not applicable not applicable by-products (68956-56-9) Page 1097 of 1235 Page 1097 of 1235 Page 1097 of 1235 Page 1097 of 1235 ---PAGE BREAK--- 8.2 Exposure controls Use adequate ventilation to keep exposure below recommended limits. Ensure that eye wash station and safety shower are close to work station. Hand Protection Equipment: Wear chemical resistant gloves and clothing to prevent skin contact. Eye Protection Equipment: Wear safety glasses or splash goggles to prevent eye contact. Skin and Body Protection: Wear suitable protective clothing. Respiration/Ventilation Protection Requirements: Provide good ventilation. Ingestion Protection Requirements: Do not eat, drink or smoke while handling. Wash hands with soap and water after handling. Launder all clothing and foot wear before re-use. 9. Physical And Chemical Properties: 9.1 Information of basic chemical and physical properties Physical Form: thin liquid Color: beige to off white Odor: typical solvent Odor Threshold: not available pH: not applicable (oil out emulsion) Melting Point/Freeze Point: 0°C (32°F) – Based on Water Initial Boiling Point: 100°C (212°F) – Based on Water Flash Point (Seta Closed Cup): 43°C (110°F) Flammability Limits: Explosive Limits: Upper: not available Lower: not available Evaporation Rate: not available Flammability Solid/Gas: not applicable Vapor Pressure: not available Vapor Density: not available Specific Gravity: 0.889 Solubility in Water: insoluble Auto Ignition Temperature: not available Partition coefficient (n/octonol/water): not available Viscosity: 1200 cP 9. 2 Other information %NVM by Weight: 3.5% %VOC Content (California): 27.0% 10. Stability and Reactivity: 10.1 Reactivity Does not react under normal conditions 10.2 Chemical stability Stable 10.3 Possibility of hazardous reactions Does not react under normal conditions 10.4 Conditions to avoid Heat and incompatible materials 10.5 Incompatible materials Strong oxidizers such as bleach and peroxides Page 1098 of 1235 Page 1098 of 1235 Page 1098 of 1235 Page 1098 of 1235 ---PAGE BREAK--- 10.6 Hazardous decomposition products CO2, CO and hydrocarbons 11. Toxicological Information: 11.1 Information on Toxicological effects Turtle Wax Bug & Tar Remover - Spray LD50 – Oral Rat >2000 mg/Kg LD50 – Dermal Rabbit >2000 mg/Kg LC50 – Inhalation Rat >20 mg/L (4hr) Petroleum Distillates, Hydrotreated Light (64742-47-8) LD50 – Oral Rat >5000 mg/Kg LD50 – Dermal Rabbit >2000 mg/Kg LC50 – Inhalation Rat >5.2 mg/L (4hr) Isopropyl Alcohol (67-63-0) LD50 – Oral Rat 4396 mg/Kg LD50 – Dermal Rabbit 12870 mg/Kg LC50 – Inhalation Rat >72.6 mg/L (4hr) 2-Butoxyethanol (111-76-2) LD50 – Oral Rat 470 mg/Kg LC50 – Inhalation Rat 450 ppm (4hr) Hydrocarbons, terpene processing by-products (68956-56-9) LD50 – Oral Rat >2000 mg/Kg LD50 – Dermal Rabbit >2000 mg/Kg Skin corrosion/irritation Based on available data, classification data are not met Serious eye damage/irritation Causes serious eye irritation Respiratory or skin sensitization May cause an allergic skin reaction Germ cell mutagenicity Based on available data, classification data are not met Carcinogenicity Based on available data, classification data are not met Isopropyl alcohol (67-63-0) IARC Group 3 2-Butoxyethanol (111-76-2) IARC Group 3 / NPT status 1 Reproductive toxicity Based on available data, classification data are not met Specific target organs – single exposure Based on available data, classification data are not met Specific target organs – repeated exposure Based on available data, classification data are not met Aspiration hazard May be fatal if swallowed and enters airways after inhalation May cause respiratory tract irritation after skin contact May cause skin irritation. Contact may cause redness, drying, de-fatting, and cracking of the skin. Contact may cause sensitization by skin contact. after eye contact Cause serious eye irritation. may include discomfort, excess blinking, and tearing, with redness and conjunctiva. after ingestion May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea, and vomiting. Page 1099 of 1235 Page 1099 of 1235 Page 1099 of 1235 Page 1099 of 1235 ---PAGE BREAK--- 12. Ecological Information: 12.1 Toxicity Not recommended for release into aquatic systems without treatment 12.2 Persistence and degradability Not established 12.3 Bioaccumulative potential Not established 12.4 Mobility in soil Not established 12.5 Other adverse effects None known 13. Disposal Considerations: 13.1 Waste treatment methods RCRA Hazardous Waste: Regulated as a RCRA Hazardous waste – D001 ignitable Waste Disposal Method: Dispose of in accordance with local, state and federal regulations Waste Disposal Vessel: Metal drums. 14. Transportation Information: 14.1 UN number 1993 14.2 UN Proper shipping name Flammable liquid N.O.S. (Petroleum distillates, Isopropanol, 2-Butoxyethanol) 14.3 Transport Hazard class 3 14.4 Packaging group III 14.5 Marine Pollutant No 14.6 Transportation in Bulk Not applicable 14.7 Special precautions Qualifies as Limited Quantity 15. Regulatory Information: 15.1 US Federal Regulations TSCA Status: All ingredients are commercially available and listed by the manufacturer under TSCA. 15.2 Foreign Regulations Page 1100 of 1235 Page 1100 of 1235 Page 1100 of 1235 Page 1100 of 1235 ---PAGE BREAK--- Canadian Status: All materials contained in this product are listed on the Canadian Domestic Substance List (DSL). Consult Turtle Wax, Inc. regarding status of ingredients. European Union: All materials contained in this product are listed on EINECS. AICS: All materials are registered for AICS (Australia) 15.3 State Regulations State Regulatory Information: The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the SDS may also be applicable for state requirements. For details on your regulatory requirements, contact the appropriate agency in your state. California Prop 65: CAS Number Concentration State Code None 15.4 HIMS & NFPA Classifications HIMS Classification: Health 2 Flammability 2 Reactivity 0 NFPA Classification: Health 2 Flammability 2 Reactivity 0 16. Other Information: Reason For Issue Conversion to OSHA GHS SDS Format Prepared By James Heidel Preparer’s Title Technical Director, R&D SDS Administrator Jean Mayszak - Technical Compliance Manager, R&D Approval Date November 19, 2014 Supersedes Date December 12, 2012 Revision Number A – 5 This information is, to the best of Turtle Wax, Inc.’s knowledge and belief, accurate and reliable. However, no representation, warranty, or guarantee is made to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy oneself as to the suitableness and completeness of such information for their own particular use. Page 1101 of 1235 Page 1101 of 1235 Page 1101 of 1235 Page 1101 of 1235 ---PAGE BREAK--- Page 1102 of 1235 Page 1102 of 1235 Page 1102 of 1235 Page 1102 of 1235 ---PAGE BREAK--- Page 1103 of 1235 Page 1103 of 1235 Page 1103 of 1235 Page 1103 of 1235 ---PAGE BREAK--- 7341356-00 UNIVIS N 32 MATERIAL SAFETY DATA BULLETIN 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: UNIVIS N 32 SUPPLIER: EXXON MOBIL CORPORATION 3225 GALLOWS RD. FAIRFAX, VA 22037 24 - Hour Health and Safety Emergency (call collect): [PHONE REDACTED] 24 - Hour Transportation Emergency (Primary) CHEMTREC: [PHONE REDACTED] (Secondary) [PHONE REDACTED] Product and Technical Information: [PHONE REDACTED] MSDS Fax on Demand: [PHONE REDACTED], other MSDS information: [PHONE REDACTED] 2. COMPOSITION/INFORMATION ON INGREDIENTS CHEMICAL NAMES AND SYNONYMS: BASE OIL AND ADDITIVES GLOBALLY REPORTABLE MSDS INGREDIENTS: None. See Section 8 for exposure limits (if applicable). 3. HAZARDS IDENTIFICATION Under normal conditions of use, this product is not considered hazardous according to regulatory guidelines (See section 15). EMERGENCY OVERVIEW: Clear Yellow Liquid. Note: Pressurized mists may form a flammable mixture. DOT ERG No. : NA POTENTIAL HEALTH EFFECTS: Under normal conditions of intended use, this product does not pose a risk to health. Excessive exposure may result in eye, skin or respiratory irritation. For further health effects/toxicological data, see Section 11. Page 1104 of 1235 Page 1104 of 1235 Page 1104 of 1235 Page 1104 of 1235 ---PAGE BREAK--- 4. FIRST AID MEASURES EYE CONTACT: Flush thoroughly with water. If irritation occurs, call a physician. SKIN CONTACT: Wash contact areas with soap and water. Remove and clean oil soaked clothing daily and wash affected area. INJECTION INJURY WARNING: If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. INHALATION: Not expected to be a problem. However, if respiratory irritation, dizziness, nausea, or unconsciousness occurs due to excessive vapor or mist exposure, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or mouth-to-mouth resuscitation. INGESTION: Not expected to be a problem. Seek medical attention if discomfort occurs. Do not induce vomiting. 5. FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA: Carbon dioxide, foam, dry chemical and water fog. SPECIAL FIRE FIGHTING PROCEDURES: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposure. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. SPECIAL PROTECTIVE EQUIPMENT: For fires in enclosed areas, fire fighters must use self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS: Note: Pressurized mists may form a flammable mixture. COMBUSTION PRODUCTS: Fumes, smoke, carbon monoxide, sulfur oxides, aldehydes and other decomposition products, in the case of incomplete combustion. Flash Point C(F): 194(381) (ASTM D-92). Flammable Limits (approx.% vol.in air) - LEL: 0.9%, UEL: 7.0% NFPA HAZARD ID: Health: 0, Flammability: 1, Reactivity: 0 6. ACCIDENTAL RELEASE MEASURES Page 1105 of 1235 Page 1105 of 1235 Page 1105 of 1235 Page 1105 of 1235 ---PAGE BREAK--- NOTIFICATION PROCEDURES: Report spills/releases as required to appropriate authorities. U.S. Coast Guard and EPA regulations require immediate reporting of spills/releases that could reach any waterway including intermittent dry creeks. Report spill/release to Coast Guard National Response Center toll free number (800)424-8802. In case of accident or road spill notify CHEMTREC (800) 424-9300. PROCEDURES IF MATERIAL IS RELEASED OR SPILLED: LAND SPILL: Shut off source taking normal safety precautions. Take measures to minimize the effects on ground water. Recover by pumping or contain spilled material with sand or other suitable absorbent and remove mechanically into containers. If necessary, dispose of adsorbed residues as directed in Section 13. WATER SPILL: Confine the spill immediately with booms. Warn other ships in the vicinity. Notify port and other relevant authorities. Remove from the surface by skimming or with suitable absorbents. If permitted by regulatory authorities the use of suitable dispersants should be considered where recommended in local oil spill procedures. ENVIRONMENTAL PRECAUTIONS: Prevent material from entering sewers, water sources or low lying areas; advise the relevant authorities if it has, or if it contaminates soil/vegetation. PERSONAL PRECAUTIONS: See Section 8 7. HANDLING AND STORAGE HANDLING: High pressure injection under the skin may occur due to the rupture of pressurized lines. Always seek medical attention. No special precautions are necessary beyond normal good hygiene practices. See Section 8 for additional personal protection advice when handling this product. STORAGE: Keep containers closed when not in use. Do not store in open or unlabelled containers. Store away from strong oxidizing agents and combustible materials. Do not store near heat, sparks, flame or strong oxidants. SPECIAL PRECAUTIONS: Prevent small spills and leakages to avoid slip hazard. EMPTY CONTAINER WARNING: Empty containers retain residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or clean container since residue is difficult to remove. Empty drums should be completely drained, properly bunged and returned to a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in Page 1106 of 1235 Page 1106 of 1235 Page 1106 of 1235 Page 1106 of 1235 ---PAGE BREAK--- accordance with governmental regulations. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS: When mists/aerosols can occur, the following are recommended: 5 mg/m3 (as oil mist)- ACGIH Threshold Limit Value (TLV), 10 mg/m3 (as oil mist) - ACGIH Short Term Exposure Limit (STEL), 5 mg/m3 (as oil mist) - OSHA Permissible Exposure Limit (PEL) VENTILATION: If mists are generated, use adequate ventilation, local exhaust or enclosures to control below exposure limits. RESPIRATORY PROTECTION: If mists are generated, and/or when ventilation is not adequate, wear approved respirator. EYE PROTECTION: If eye contact is likely, safety glasses with side shields or chemical type goggles should be worn. SKIN PROTECTION: Not normally required. When splashing or liquid contact can occur frequently, wear oil resistant gloves and/or other protective clothing. Good personal hygiene practices should always be followed. 9. PHYSICAL AND CHEMICAL PROPERTIES Typical physical properties are given below. Consult Product Data Sheet for specific details. APPEARANCE: Liquid COLOR: Clear Yellow ODOR: Mild ODOR THRESHOLD-ppm: NE pH: NA BOILING POINT C(F): > 271(520) MELTING POINT C(F): NA FLASH POINT C(F): 194(381) (ASTM D-92) FLAMMABILITY (solids): NE AUTO FLAMMABILITY: NA EXPLOSIVE PROPERTIES: NA OXIDIZING PROPERTIES: NA VAPOR PRESSURE-mmHg 20 C: < 0.1 VAPOR DENSITY: > 2.0 EVAPORATION RATE: NE RELATIVE DENSITY, 15/4 C: 0.87 SOLUBILITY IN WATER: Negligible PARTITION COEFFICIENT: > 3.5 Page 1107 of 1235 Page 1107 of 1235 Page 1107 of 1235 Page 1107 of 1235 ---PAGE BREAK--- VISCOSITY AT 40 C, cSt: 32.0 VISCOSITY AT 100 C, cSt: NE POUR POINT C(F): -40(-40) FREEZING POINT C(F): NE VOLATILE ORGANIC COMPOUND: NE DMSO EXTRACT, IP-346 for mineral oil only NA=NOT APPLICABLE NE=NOT ESTABLISHED D=DECOMPOSES FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING REPRESENTATIVE 10. STABILITY AND REACTIVITY STABILITY (THERMAL, LIGHT, ETC.): Stable. CONDITIONS TO AVOID: Extreme heat and high energy sources of ignition. INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS: Product does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. 11. TOXICOLOGICAL DATA ---ACUTE TOXICOLOGY--- ORAL TOXICITY (RATS): Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. DERMAL TOXICITY (RABBITS): Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. INHALATION TOXICITY (RATS): Practically non-toxic (LC50: greater than 5 mg/l). ---Based on testing of similar products and/or the components. EYE IRRITATION (RABBITS): Practically non-irritating. (Draize score: greater than 6 but 15 or less). ---Based on testing of similar products and/or the components. SKIN IRRITATION (RABBITS): Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than ---Based on testing of similar products and/or the components. OTHER ACUTE TOXICITY DATA: Although an acute inhalation study was not performed with this product, a variety of mineral and oils, such as those in this product, have been tested. These samples had virtually no effect other than a nonspecific inflammatory response in the lung to the aerosolized mineral oil. The presence of additives in other tested formulations (in approximately the same amounts as in the present formulation) did Page 1108 of 1235 Page 1108 of 1235 Page 1108 of 1235 Page 1108 of 1235 ---PAGE BREAK--- not alter the observed effects. ---SUBCHRONIC TOXICOLOGY (SUMMARY)--- No significant adverse effects were found in studies using repeated dermal applications of similar formulations to the skin of laboratory animals for 13 weeks at doses significantly higher than those expected during normal industrial exposure. The animals were evaluated extensively for effects of exposure (hematology, serum chemistry, urinalysis, organ weights, microscopic examination of tissues etc.). ---REPRODUCTIVE TOXICOLOGY (SUMMARY)--- No teratogenic effects would be expected from dermal exposure, based on laboratory developmental toxicity studies of major components in this formulation and/or materials of similar composition. ---CHRONIC TOXICOLOGY (SUMMARY)--- Repeated and/or prolonged exposure may cause irritation to the skin, eyes or respiratory tract. Overexposure to oil mist may result in oil droplet deposition and/or granuloma formation. For mineral base oils: Base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic mouse skin painting studies of severely treated oils showed no evidence of carcinogenic effects. These results are confirmed on a continuing basis using various screening methods such as Modified Ames Test, IP-346, and/or other analytical methods. For base oils: The base oils in this product have been tested in the Ames assay and other tests of mutagenicity with negative results. These base oils are not expected to be carcinogenic with chronic dermal exposures. ---SENSITIZATION (SUMMARY)--- Not expected to be sensitizing based on tests of this product, components, or similar products. 12. ECOLOGICAL INFORMATION ENVIRONMENTAL FATE AND EFFECTS: In the absence of specific environmental data for this product, this assessment is based on information for representative products. When released into the environment, adsorption to sediment and soil will be the predominant behavior. Available ecotoxicity data (LL50 >1000 mg/L) indicates that adverse effects to aquatic organisms are not expected from this product. Bioaccumulation is unlikely due to the very low water solubility of this product, therefore bioavailability to aquatic organisms is minimal. This product is expected to be inherently biodegradable. Page 1109 of 1235 Page 1109 of 1235 Page 1109 of 1235 Page 1109 of 1235 ---PAGE BREAK--- 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Product is suitable for burning in an enclosed, controlled burner for fuel value. Such burning may be limited pursuant to the Resource Conservation and Recovery Act. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of at an appropriate government waste disposal facility. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. RCRA INFORMATION: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrosivity, or reactivity. The unused product is not formulated with substances covered by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. 14. TRANSPORT INFORMATION USA DOT: NOT REGULATED BY USA DOT. RID/ADR: NOT REGULATED BY RID/ADR. IMO: NOT REGULATED BY IMO. IATA: NOT REGULATED BY IATA. STATIC ACCUMULATOR (50 picosiemens or less): YES 15. REGULATORY INFORMATION US OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this product is not classified as hazardous in accordance with OSHA 29 CFR 1910.1200. EU Labeling: Product is not dangerous as defined by the European Union Dangerous Substances/Preparations Directives. EU labeling not required. Governmental Inventory Status: All components comply with TSCA. U.S. Superfund Amendments and Reauthorization Act (SARA) Title III: This product contains no "EXTREMELY HAZARDOUS SUBSTANCES". SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. This product contains no chemicals subject to the supplier notification Page 1110 of 1235 Page 1110 of 1235 Page 1110 of 1235 Page 1110 of 1235 ---PAGE BREAK--- requirements of SARA (313) toxic release program. The following product ingredients are cited on the lists below: CHEMICAL NAME CAS NUMBER LIST CITATIONS NO REPORTABLE INGREDIENTS REGULATORY LISTS SEARCHED 1=ACGIH ALL 6=IARC 1 11=TSCA 4 16=CA P65 CARC 21=LA RTK 2=ACGIH A1 7=IARC 2A 12=TSCA 5a2 17=CA P65 REPRO 22=MI 293 3=ACGIH A2 8=IARC 2B 13=TSCA 5e 18=CA RTK 23=MN RTK 4=NTP CARC 9=OSHA CARC 14=TSCA 6 19=FL RTK 24=NJ RTK 5=NTP SUS 10=OSHA Z 15=TSCA 12b 20=IL RTK 25=PA RTK 26=RI RTK Code key: CARC=Carcinogen; SUS=Suspected Carcinogen; REPRO=Reproductive 16. OTHER INFORMATION USE: HYDRAULIC OIL NOTE: PRODUCTS OF EXXON MOBIL CORPORATION AND ITS AFFILIATED COMPANIES ARE NOT FORMULATED TO CONTAIN PCBS. Health studies have shown that many hydrocarbons pose potential human health risks which may vary from person to person. Information provided on this MSDS reflects intended use. This product should not be used for other applications. In any case, the following advice should be considered: INDUSTRIAL LABEL Under normal conditions of intended use, this product does not pose a risk to health. Excessive exposure may result in eye, skin or respiratory irritation. Always observe good hygiene measures. First Aid: Wash skin with soap and water. Flush eyes with water. If overcome by fumes or vapor, remove to fresh air. If ingested do not induce vomiting. If persist seek medical assistance. Read and understand the MSDS before using this product. For Internal Use Only: MHC: 1* 1* 1* 1* MPPEC: A, TRN: 7341356-00, CMCS97: 97P975, REQ: PS+C, SAFE USE: L EHS Approval Date: 05DEC2001 Legally required information is given in accordance with applicable Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for particular uses are beyond our control; all risks of use of the product are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF Page 1111 of 1235 Page 1111 of 1235 Page 1111 of 1235 Page 1111 of 1235 ---PAGE BREAK--- MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO THE USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a recommendation for uses which infringe valid patents or as extending any license under valid patents. Appropiate warnings and safe handling procedures should be providedto handlers and users. Use or re- transmission of the information contained herein in any other format than the format as presented is strictly prohibited. Mobil neither represents nor warrants that the format, content or product formulas contained in this document comply with the laws of any other country except the United States of America. Copyright 1996 Mobil Corporation, All rights reserved Page 1112 of 1235 Page 1112 of 1235 Page 1112 of 1235 Page 1112 of 1235 ---PAGE BREAK--- Page: 1 SAFETY DATA SHEET Revision Date: 07/03/2013 Print Date: 10/2/2013 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 4.0 Page 1 / 10 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Ashland Regulatory Information Number 1-[PHONE REDACTED] P.O. Box 2219 Telephone [PHONE REDACTED] Columbus, OH 43216 Emergency telephone number 1-800-ASHLAND (1-[PHONE REDACTED]) Product name Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID Product code VV370 2. HAZARDS IDENTIFICATION Emergency Overview Appearance: liquid, red CAUTION! MAY CAUSE EYE IRRITATION. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. Potential Health Effects Exposure routes Inhalation, Skin absorption, Skin contact, Eye Contact, Ingestion Eye contact Can cause eye irritation. include stinging, tearing, redness, and swelling of eyes. Skin contact May cause slight skin irritation. Prolonged or repeated contact may dry the skin. may include redness, burning, and drying and cracking of skin, skin burns, and other skin damage. Ingestion Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. This material can get into the lungs during swallowing or vomiting. This results in lung inflammation and other lung injury. Inhalation It is possible to breathe this material under certain conditions of handling and use (for example, during heating, spraying, or stirring). Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. are not expected at air concentrations below the recommended exposure limits, if applicable (see Section Aggravated Medical Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, Skin, lung (for example, asthma-like conditions) Page 1113 of 1235 Page 1113 of 1235 Page 1113 of 1235 Page 1113 of 1235 ---PAGE BREAK--- Page: 2 SAFETY DATA SHEET Revision Date: 07/03/2013 Print Date: 10/2/2013 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 4.0 Page 2 / 10 Signs and of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, acne, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways) Target Organs No data Carcinogenicity This material is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration (OSHA). Reproductive hazard There are no data available for assessing risk to the fetus from maternal exposure to this material. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Components CAS-No. / Trade Secret No. Concentration HYDROTREATED HEAVY PARAFFINIC BASE OIL 64742-54-7 >=50-<60% HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 >=40-<50% MINERAL OIL METHACRYLATE COPOLYMER 4. FIRST AID MEASURES Eyes If develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention. Skin Remove contaminated clothing. Wash exposed area with soap and water. If persist, seek medical attention. Launder clothing before reuse. Ingestion Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. Inhalation Page 1114 of 1235 Page 1114 of 1235 Page 1114 of 1235 Page 1114 of 1235 ---PAGE BREAK--- Page: 3 SAFETY DATA SHEET Revision Date: 07/03/2013 Print Date: 10/2/2013 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 4.0 Page 3 / 10 If develop, move individual away from exposure and into fresh air. If persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention. Notes to physician Hazards: Acute aspiration of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. Repeated aspiration of small quantities of mineral oil can produce chronic inflammation of the lungs (i.e. lipoid pneumonia) that may progress to pulmonary fibrosis. are often subtle and radiological changes appear worse than clinical abnormalities. Occasionally, persistent cough, irritation of the upper respiratory tract, shortness of breath with exertion, fever, and bloody sputum occur. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. Treatment: No information available. 5. FIREFIGHTING MEASURES Suitable extinguishing media Dry chemical, Carbon dioxide (CO2), Water spray Hazardous combustion products carbon dioxide and carbon monoxide, Hydrocarbons Precautions for fire-fighting Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). DO NOT direct a solid stream of water or foam into hot, burning pools of liquid since this may cause frothing and increase fire intensity. Frothing can be violent and possibly endanger any firefighter standing too close to the burning liquid. Use water spray to cool fire exposed containers and structures until fire is out if it can be done with minimal risk. Avoid spreading burning material with water used for cooling purposes. NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB 6. ACCIDENTAL RELEASE MEASURES Personal precautions For personal protection see section 8. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions Prevent spreading over a wide area (e.g. by containment or oil barriers). Do not let product enter drains. Do not flush into surface water or sanitary sewer system. Methods for cleaning up Keep in suitable, closed containers for disposal. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Page 1115 of 1235 Page 1115 of 1235 Page 1115 of 1235 Page 1115 of 1235 ---PAGE BREAK--- Page: 4 SAFETY DATA SHEET Revision Date: 07/03/2013 Print Date: 10/2/2013 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 4.0 Page 4 / 10 Other information Comply with all applicable federal, state, and local regulations. 7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Storage Store in a cool, dry, ventilated area. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 NIOSH Recommended exposure limit (REL): 5 mg/m3 Mist. NIOSH Short term exposure limit 10 mg/m3 Mist. OSHA Z1 Permissible exposure limit 5 mg/m3 Mist. ACGIH time weighted average 5 mg/m3 Inhalable fraction. MINERAL OIL NIOSH Recommended exposure limit (REL): 5 mg/m3 Mist. NIOSH Short term exposure limit 10 mg/m3 Mist. OSHA Z1 Permissible exposure limit 5 mg/m3 Mist. ACGIH time weighted average 5 mg/m3 Inhalable fraction. General advice These recommendations provide general guidance for handling this product. Personal protective equipment should be selected for individual applications and should consider factors which affect exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities. Exposure controls Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Eye protection Wear chemical splash goggles when there is the potential for exposure of the eyes to liquid, vapor or mist. Skin and body protection Page 1116 of 1235 Page 1116 of 1235 Page 1116 of 1235 Page 1116 of 1235 ---PAGE BREAK--- Page: 5 SAFETY DATA SHEET Revision Date: 07/03/2013 Print Date: 10/2/2013 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 4.0 Page 5 / 10 Wear normal work clothing including long pants, long-sleeved shirts and foot covering to prevent direct contact of the product with the skin. Launder clothing before reuse. If skin irritation develops, contact your facility health and safety professional or your local safety equipment supplier to determine the proper personal protective equipment for your use. Wear resistant gloves (consult your safety equipment supplier). Respiratory protection Respiratory protection is not required under normal conditions of use. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state liquid Colour red Flash point > 356 °F / > 180 °C Cleveland open cup Lower explosion limit/Upper explosion limit 1 / 6 Calculated Explosive Limit Density 0.849 g/cm3 @ 60.01 °F / 15.56 °C 7.08 lb/gal 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid excessive heat Incompatible products Strong oxidizing agents Hazardous decomposition products carbon dioxide and carbon monoxide, Hydrocarbons Hazardous reactions Product will not undergo hazardous polymerization. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation Skin absorption Skin contact Page 1117 of 1235 Page 1117 of 1235 Page 1117 of 1235 Page 1117 of 1235 ---PAGE BREAK--- Page: 6 SAFETY DATA SHEET Revision Date: 07/03/2013 Print Date: 10/2/2013 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 4.0 Page 6 / 10 Eye Contact Ingestion Product Acute oral toxicity : no data available Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Skin corrosion/irritation : no data available Serious eye damage/eye irritation : no data available Respiratory or skin sensitisation : no data available Aspiration toxicity : The substance or mixture is known to cause human aspiration toxicity hazards or has to be regarded as if it causes a human aspiration toxicity hazard. Components: HYDROTREATED HEAVY PARAFFINIC BASE OIL: Acute oral toxicity : LD 50 Rat: > 15 g/kg Acute dermal toxicity : LD 50 Rabbit: > 5 g/kg 12. ECOLOGICAL INFORMATION Ecotoxicity Product: no data available Components: no data available Persistence and degradability Product: no data available Page 1118 of 1235 Page 1118 of 1235 Page 1118 of 1235 Page 1118 of 1235 ---PAGE BREAK--- Page: 7 SAFETY DATA SHEET Revision Date: 07/03/2013 Print Date: 10/2/2013 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 4.0 Page 7 / 10 Components: no data available Bioaccumulative potential Product: no data available Components: no data available Mobility in soil Product: no data available Components: no data available 13. DISPOSAL CONSIDERATIONS Waste disposal methods Dispose of in accordance with all applicable local, state and federal regulations. 14. TRANSPORT INFORMATION REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP MARINE POLLUTANT / LTD. QTY. U.S. DOT - ROAD Not dangerous goods U.S. DOT - RAIL Not dangerous goods U.S. DOT - INLAND WATERWAYS Not dangerous goods TRANSPORT CANADA - ROAD Not dangerous goods Page 1119 of 1235 Page 1119 of 1235 Page 1119 of 1235 Page 1119 of 1235 ---PAGE BREAK--- Page: 8 SAFETY DATA SHEET Revision Date: 07/03/2013 Print Date: 10/2/2013 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 4.0 Page 8 / 10 TRANSPORT CANADA - RAIL Not dangerous goods TRANSPORT CANADA - INLAND WATERWAYS Not dangerous goods INTERNATIONAL MARITIME DANGEROUS GOODS Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER Not dangerous goods MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTES Not dangerous goods *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. 15. REGULATORY INFORMATION California Prop. 65 Proposition 65 warnings are not required for this product based on the results of a risk assessment. SARA Hazard Classification SARA 311/312 Classification Acute Health Hazard SARA 313 Component(s) SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Notification status US. Toxic Substances Control Act y (positive listing) Canada. Canadian Environmental Protection Act (CEPA). Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133) y (positive listing) Australia. Industrial Chemical (Notification and Assessment) Act y (positive listing) Japan. ENCS - Existing and New Chemical Substances Inventory n (Negative listing) Korea. Toxic Chemical Control Law (TCCL) List y (positive listing) Page 1120 of 1235 Page 1120 of 1235 Page 1120 of 1235 Page 1120 of 1235 ---PAGE BREAK--- Page: 9 SAFETY DATA SHEET Revision Date: 07/03/2013 Print Date: 10/2/2013 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 4.0 Page 9 / 10 Philippines. The Toxic Substances and Hazardous and Nuclear Waste Control Act y (positive listing) China. Inventory of Existing Chemical Substances y (positive listing) HMIS NFPA Health 1 1 Flammability 1 1 Physical hazards 0 Instability 0 Specific Hazard 16. OTHER INFORMATION The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department (1-[PHONE REDACTED]). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the “International Air Transport Association” (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the “International Civil Aviation Organization” IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity Page 1121 of 1235 Page 1121 of 1235 Page 1121 of 1235 Page 1121 of 1235 ---PAGE BREAK--- Page: 10 SAFETY DATA SHEET Revision Date: 07/03/2013 Print Date: 10/2/2013 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 4.0 Page 10 / 10 TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System Page 1122 of 1235 Page 1122 of 1235 Page 1122 of 1235 Page 1122 of 1235 ---PAGE BREAK--- Page: 1 SAFETY DATA SHEET Revision Date: 03/11/2010 Print Date: 11/18/2011 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.3 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Ashland Regulatory Information Number 1-[PHONE REDACTED] P.O. Box 2219 Telephone [PHONE REDACTED] Columbus, OH 43216 Emergency telephone 1-800-ASHLAND (1-800-274- 5263) Product name Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID Product code VV370 Product Use Description no data available 2. HAZARDS IDENTIFICATION Emergency Overview Appearance: liquid, red CAUTION! PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. Potential Health Effects Exposure routes Inhalation, Skin contact, Eye Contact, Ingestion Eye contact Unlikely to cause eye irritation or injury. Skin contact Unlikely to cause skin irritation or injury. Prolonged or repeated contact may dry and crack the skin. Ingestion Page 1 / 12 Page 1123 of 1235 Page 1123 of 1235 Page 1123 of 1235 Page 1123 of 1235 ---PAGE BREAK--- Page: 2 SAFETY DATA SHEET Revision Date: 03/11/2010 Print Date: 11/18/2011 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.3 Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. Inhalation It is possible to breathe this material under certain conditions of handling and use (for example, during heating, spraying, or stirring). Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. are not expected at air concentrations below the recommended exposure limits, if applicable (see Section Aggravated Medical Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, skin, lung (for example, asthma-like conditions) Signs and of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways) Target Organs No data Carcinogenicity This material is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration (OSHA). Reproductive hazard There are no data available for assessing risk to the fetus from maternal exposure to this material. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Components CAS-No. Concentration HEAVY PARAFFINIC DISTILLATE 64742-54-7 >=50-<60% HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 >=30-<40% MINERAL OIL Page 2 / 12 Page 1124 of 1235 Page 1124 of 1235 Page 1124 of 1235 Page 1124 of 1235 ---PAGE BREAK--- Page: 3 SAFETY DATA SHEET Revision Date: 03/11/2010 Print Date: 11/18/2011 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.3 4. FIRST AID MEASURES Eyes If develop, move individual away from exposure and into fresh air. Flush eyes gently with water while holding eyelids apart. If persist or there is any visual difficulty, seek medical attention. Skin Remove contaminated clothing. Wash exposed area with soap and water. If persist, seek medical attention. Launder clothing before reuse. Ingestion Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. Inhalation If develop, move individual away from exposure and into fresh air. If persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention. Notes to physician Hazards: Acute aspiration of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long- term sequelae. Repeated aspiration of small quantities of mineral oil can produce chronic inflammation of the lungs (i.e. lipoid pneumonia) that may progress to pulmonary fibrosis. are often subtle and radiological changes appear worse than clinical abnormalities. Occasionally, persistent cough, irritation of the upper respiratory tract, shortness of breath with exertion, fever, and bloody sputum occur. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. Treatment: No information available. 5. FIRE-FIGHTING MEASURES Page 3 / 12 Page 1125 of 1235 Page 1125 of 1235 Page 1125 of 1235 Page 1125 of 1235 ---PAGE BREAK--- Page: 4 SAFETY DATA SHEET Revision Date: 03/11/2010 Print Date: 11/18/2011 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.3 Suitable extinguishing media Water spray, Dry powder, Foam, Carbon dioxide (CO2) Hazardous combustion products carbon dioxide and carbon monoxide, oxides of sulfur, nitrogen and phosphorus, various hydrocarbons, zinc oxide Precautions for fire-fighting Never use welding or cutting torch on or near drum (even empty) because product (even just residue) can ignite explosively.Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). DO NOT direct a solid stream of water or foam into hot, burning pools of liquid since this may cause frothing and increase fire intensity. Frothing can be violent and possibly endanger any firefighter standing too close to the burning liquid. NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB 6. ACCIDENTAL RELEASE MEASURES Personal precautions For personal protection see section 8. Spills of this material are very slippery. Environmental precautions Prevent run-off to sewers, streams or other bodies of water. If run-off occurs, notify proper authorities as required, that a spill has occurred. Methods for cleaning up Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source, dike area of spill to prevent spreading, pump liquid to salvage tank. Remaining liquid may be taken up on sand, clay, earth, floor absorbent, or other absorbent material and shoveled into containers. Other information Notify the proper authorities as required that a spill has occurred. Comply with all applicable federal, state, and local regulations. 7. HANDLING AND STORAGE Page 4 / 12 Page 1126 of 1235 Page 1126 of 1235 Page 1126 of 1235 Page 1126 of 1235 ---PAGE BREAK--- Page: 5 SAFETY DATA SHEET Revision Date: 03/11/2010 Print Date: 11/18/2011 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.3 Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Storage Store in a cool, dry, ventilated area. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 ACGIH time weighted average 5 mg/m3 Mist. ACGIH Short term exposure limit 10 mg/m3 Mist. ACGIH NIC time weighted average 0.2 mg/m3 Inhalable fraction. General advice These recommendations provide general guidance for handling this product. Personal protective equipment should be selected for individual applications and should consider factors which affect exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities. Exposure controls General room ventilation should be adequate for normal conditions of use. However, if unusual operating conditions exist, provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Eye protection Not required under normal conditions of use. Wear splash-proof safety goggles if material could be misted or splashed into eyes. Skin and body protection Not normally required. However, wear resistant gloves such as nitrile rubber to prevent irritation which may result from prolonged or repeated skin contact with product. Page 5 / 12 Page 1127 of 1235 Page 1127 of 1235 Page 1127 of 1235 Page 1127 of 1235 ---PAGE BREAK--- Page: 6 SAFETY DATA SHEET Revision Date: 03/11/2010 Print Date: 11/18/2011 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.3 Wear normal work clothing including long pants, long-sleeved shirts and foot covering to prevent direct contact of the product with the skin. Launder clothing before reuse. If skin irritation develops, contact your facility health and safety professional or your local safety equipment supplier to determine the proper personal protective equipment for your use. Respiratory protection Respiratory protection is not required under normal conditions of use. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state liquid Form no data available Colour red Odour no data available Boiling point/boiling range 662 °F / 350 °C @ 1,013.33 hPa Calculated Phase Transition Liquid/Gas Melting point/range no data available Sublimation point no data available pH no data available Flash point (>)180.00 °C Cleveland open cup Ignition temperature no data available Evaporation rate no data available Lower explosion limit/Upper explosion limit 1 / 6 Calculated Explosive Limit Particle size no data available Vapour pressure 0.133 hPa @ 68 °F / 20 °C Calculated Vapor Pressure Vapour density no data available Density 0.849 g/cm3 @ 60.01 °F / 15.56 °C Bulk density 7.08 lb/gal Water solubility no data available Solubility no data available Partition coefficient: n-octanol/water no data available log Pow no data available Autoignition temperature no data available Viscosity, kinematic no data available Solids in Solution no data available Decomposition temperature no data available Page 6 / 12 Page 1128 of 1235 Page 1128 of 1235 Page 1128 of 1235 Page 1128 of 1235 ---PAGE BREAK--- Page: 7 SAFETY DATA SHEET Revision Date: 03/11/2010 Print Date: 11/18/2011 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.3 Burning number no data available Dust explosion constant no data available Minimum ignition energy no data available 10. STABILITY AND REACTIVITY Stability Stable Conditions to avoid None known. Incompatible products strong oxidizing agents Hazardous decomposition products carbon dioxide and carbon monoxide, oxides of sulfur, nitrogen and phosphorus, zinc oxide, various hydrocarbons Hazardous reactions Product will not undergo hazardous polymerization. Thermal decomposition No data 11. TOXICOLOGICAL INFORMATION Acute oral toxicity HEAVY PARAFFINIC DISTILLATE : LD 50 Rat: > 15 g/kg HYDROTREATED LIGHT PARAFFINIC DISTILLATE : no data available MINERAL OIL : no data available Acute inhalation toxicity HEAVY PARAFFINIC DISTILLATE : no data available Page 7 / 12 Page 1129 of 1235 Page 1129 of 1235 Page 1129 of 1235 Page 1129 of 1235 ---PAGE BREAK--- Page: 8 SAFETY DATA SHEET Revision Date: 03/11/2010 Print Date: 11/18/2011 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.3 HYDROTREATED LIGHT PARAFFINIC DISTILLATE : no data available MINERAL OIL : no data available Acute dermal toxicity HEAVY PARAFFINIC DISTILLATE : LD 50 Rabbit: > 5 g/kg HYDROTREATED LIGHT PARAFFINIC DISTILLATE : no data available MINERAL OIL : no data available 12. ECOLOGICAL INFORMATION Biodegradability HEAVY PARAFFINIC DISTILLATE : no data available HYDROTREATED LIGHT PARAFFINIC DISTILLATE : no data available MINERAL OIL : no data available Bioaccumulation HEAVY PARAFFINIC DISTILLATE : no data available HYDROTREATED LIGHT PARAFFINIC DISTILLATE : no data available MINERAL OIL : no data available Ecotoxicity effects Toxicity to fish HEAVY PARAFFINIC DISTILLATE : no data available HYDROTREATED LIGHT PARAFFINIC DISTILLATE : no data available MINERAL OIL : no data available Page 8 / 12 Page 1130 of 1235 Page 1130 of 1235 Page 1130 of 1235 Page 1130 of 1235 ---PAGE BREAK--- Page: 9 SAFETY DATA SHEET Revision Date: 03/11/2010 Print Date: 11/18/2011 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.3 Toxicity to daphnia and other aquatic invertebrates. HEAVY PARAFFINIC DISTILLATE : no data available HYDROTREATED LIGHT PARAFFINIC DISTILLATE : no data available MINERAL OIL : no data available Toxicity to algae HEAVY PARAFFINIC DISTILLATE : no data available HYDROTREATED LIGHT PARAFFINIC DISTILLATE : no data available MINERAL OIL : no data available Toxicity to bacteria HEAVY PARAFFINIC DISTILLATE : no data available HYDROTREATED LIGHT PARAFFINIC DISTILLATE : no data available MINERAL OIL : no data available Biochemical Oxygen Demand (BOD) HEAVY PARAFFINIC DISTILLATE : no data available HYDROTREATED LIGHT PARAFFINIC DISTILLATE : no data available MINERAL OIL : no data available Chemical Oxygen Demand (COD) HEAVY PARAFFINIC DISTILLATE : no data available HYDROTREATED LIGHT PARAFFINIC DISTILLATE : no data available MINERAL OIL : no data available Additional ecological information HEAVY PARAFFINIC DISTILLATE : no data available HYDROTREATED LIGHT PARAFFINIC DISTILLATE : no data available Page 9 / 12 Page 1131 of 1235 Page 1131 of 1235 Page 1131 of 1235 Page 1131 of 1235 ---PAGE BREAK--- Page: 10 SAFETY DATA SHEET Revision Date: 03/11/2010 Print Date: 11/18/2011 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.3 MINERAL OIL : no data available 13. DISPOSAL CONSIDERATIONS Waste disposal methods For assistance with your waste management needs - including disposal, recycling and waste stream reduction, contact Ashland Distribution's Environmental Services Group at [PHONE REDACTED]. Dispose of in accordance with all applicable local, state and federal regulations. 14. TRANSPORT INFORMATION REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP MARINE POLLUTANT / LTD. QTY. U.S. DOT - ROAD Not dangerous goods U.S. DOT - RAIL Not dangerous goods U.S. DOT - INLAND WATERWAYS Not dangerous goods TRANSPORT CANADA - ROAD Not dangerous goods TRANSPORT CANADA - RAIL Not dangerous goods TRANSPORT CANADA - INLAND WATERWAYS Not dangerous goods INTERNATIONAL MARITIME DANGEROUS GOODS Not dangerous goods Page 10 / 12 Page 1132 of 1235 Page 1132 of 1235 Page 1132 of 1235 Page 1132 of 1235 ---PAGE BREAK--- Page: 11 SAFETY DATA SHEET Revision Date: 03/11/2010 Print Date: 11/18/2011 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.3 INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER Not dangerous goods MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTES Not dangerous goods *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. 15. REGULATORY INFORMATION California Prop. 65 Proposition 65 warnings are not required for this product based on the results of a risk assessment. SARA Hazard Classification Acute Health Hazard New Jersey RTK Label Information HEAVY PARAFFINIC DISTILLATE 64742-54-7 HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 MINERAL OIL METHACRYLATE COPOLYMER RTK Label Information HEAVY PARAFFINIC DISTILLATE 64742-54-7 HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 MINERAL OIL METHACRYLATE COPOLYMER Notification status Page 11 / 12 Page 1133 of 1235 Page 1133 of 1235 Page 1133 of 1235 Page 1133 of 1235 ---PAGE BREAK--- Page: 12 SAFETY DATA SHEET Revision Date: 03/11/2010 Print Date: 11/18/2011 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.3 US. Toxic Substances Control Act y (positive listing) Canada. Canadian Environmental Protection Act (CEPA). Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133) y (positive listing) Australia. Industrial Chemical (Notification and Assessment) Act q (quantity restricted) New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand n (Negative listing) Japan. Kashin-Hou Law List n (Negative listing) Korea. Toxic Chemical Control Law (TCCL) List y (positive listing) Philippines. The Toxic Substances and Hazardous and Nuclear Waste Control Act y (positive listing) China. Inventory of Existing Chemical Substances y (positive listing) HMIS NFPA Health 1 1 Flammability 1 1 Physical hazards Instability 0 Specific Hazard 16. OTHER INFORMATION The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department (1-[PHONE REDACTED]). Page 12 / 12 Page 1134 of 1235 Page 1134 of 1235 Page 1134 of 1235 Page 1134 of 1235 ---PAGE BREAK--- Page: 1 SAFETY DATA SHEET Revision Date: 07/03/2013 Print Date: 9/18/2013 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.0 Page 1 / 10 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Ashland Regulatory Information Number 1-[PHONE REDACTED] P.O. Box 2219 Telephone [PHONE REDACTED] Columbus, OH 43216 Emergency telephone number 1-800-ASHLAND (1-[PHONE REDACTED]) Product name Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID Product code VV370 2. HAZARDS IDENTIFICATION Emergency Overview Appearance: liquid, red CAUTION! MAY CAUSE EYE IRRITATION. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. Potential Health Effects Exposure routes Inhalation, Skin absorption, Skin contact, Eye Contact, Ingestion Eye contact Can cause eye irritation. include stinging, tearing, redness, and swelling of eyes. Skin contact May cause slight skin irritation. Prolonged or repeated contact may dry the skin. may include redness, burning, and drying and cracking of skin, skin burns, and other skin damage. Ingestion Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. This material can get into the lungs during swallowing or vomiting. This results in lung inflammation and other lung injury. Inhalation It is possible to breathe this material under certain conditions of handling and use (for example, during heating, spraying, or stirring). Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. are not expected at air concentrations below the recommended exposure limits, if applicable (see Section Aggravated Medical Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, Skin, lung (for example, asthma-like conditions) Page 1135 of 1235 Page 1135 of 1235 Page 1135 of 1235 Page 1135 of 1235 ---PAGE BREAK--- Page: 2 SAFETY DATA SHEET Revision Date: 07/03/2013 Print Date: 9/18/2013 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.0 Page 2 / 10 Signs and of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways) Target Organs No data Carcinogenicity This material is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration (OSHA). Reproductive hazard There are no data available for assessing risk to the fetus from maternal exposure to this material. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Components CAS-No. / Trade Secret No. Concentration HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 >=40-<50% METHACRYLATE COPOLYMER 4. FIRST AID MEASURES Eyes If develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention. Skin Remove contaminated clothing. Wash exposed area with soap and water. If persist, seek medical attention. Launder clothing before reuse. Ingestion Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. Inhalation If develop, move individual away from exposure and into fresh air. If persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention. Page 1136 of 1235 Page 1136 of 1235 Page 1136 of 1235 Page 1136 of 1235 ---PAGE BREAK--- Page: 3 SAFETY DATA SHEET Revision Date: 07/03/2013 Print Date: 9/18/2013 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.0 Page 3 / 10 Notes to physician Hazards: Acute aspiration of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. Repeated aspiration of small quantities of mineral oil can produce chronic inflammation of the lungs (i.e. lipoid pneumonia) that may progress to pulmonary fibrosis. are often subtle and radiological changes appear worse than clinical abnormalities. Occasionally, persistent cough, irritation of the upper respiratory tract, shortness of breath with exertion, fever, and bloody sputum occur. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. Treatment: No information available. 5. FIREFIGHTING MEASURES Suitable extinguishing media Dry chemical, Carbon dioxide (CO2), Water spray Hazardous combustion products carbon dioxide and carbon monoxide, Hydrocarbons Precautions for fire-fighting Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). DO NOT direct a solid stream of water or foam into hot, burning pools of liquid since this may cause frothing and increase fire intensity. Frothing can be violent and possibly endanger any firefighter standing too close to the burning liquid. Use water spray to cool fire exposed containers and structures until fire is out if it can be done with minimal risk. Avoid spreading burning material with water used for cooling purposes. NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB 6. ACCIDENTAL RELEASE MEASURES Personal precautions For personal protection see section 8. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions Prevent spreading over a wide area (e.g. by containment or oil barriers). Do not let product enter drains. Do not flush into surface water or sanitary sewer system. Methods for cleaning up Keep in suitable, closed containers for disposal. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Other information Comply with all applicable federal, state, and local regulations. Page 1137 of 1235 Page 1137 of 1235 Page 1137 of 1235 Page 1137 of 1235 ---PAGE BREAK--- Page: 4 SAFETY DATA SHEET Revision Date: 07/03/2013 Print Date: 9/18/2013 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.0 Page 4 / 10 7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Storage Store in a cool, dry, ventilated area. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 OEL (QUE) time weighted average 5 mg/m3 Mist. OEL (QUE) Short term exposure limit 10 mg/m3 Mist. CAD AB OEL time weighted average 5 mg/m3 Mist. CAD AB OEL Short term exposure limit 10 mg/m3 Mist. CAD BC OEL time weighted average 0.2 mg/m3 Mist. CAD BC OEL time weighted average 1 mg/m3 Mist. CAD MB OEL time weighted average 5 mg/m3 Inhalable fraction. CAD ON OEL time weighted average 5 mg/m3 Mist. CAD ON OEL Short term exposure limit 10 mg/m3 Mist. MINERAL OIL CAD ON OEL time weighted average 5 mg/m3 Mist. CAD ON OEL Short term exposure limit 10 mg/m3 Mist. OEL (QUE) time weighted average 5 mg/m3 Mist. OEL (QUE) Short term exposure limit 10 mg/m3 Mist. CAD AB OEL time weighted average 5 mg/m3 Mist. CAD AB OEL Short term exposure limit 10 mg/m3 Mist. CAD BC OEL time weighted average 0.2 mg/m3 Mist. CAD BC OEL time weighted average 1 mg/m3 Mist. General advice These recommendations provide general guidance for handling this product. Personal protective equipment should be selected for individual applications and should consider factors which affect exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities. Exposure controls Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Eye protection Wear chemical splash goggles when there is the potential for exposure of the eyes to liquid, vapor or mist. Page 1138 of 1235 Page 1138 of 1235 Page 1138 of 1235 Page 1138 of 1235 ---PAGE BREAK--- Page: 5 SAFETY DATA SHEET Revision Date: 07/03/2013 Print Date: 9/18/2013 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.0 Page 5 / 10 Skin and body protection Wear normal work clothing including long pants, long-sleeved shirts and foot covering to prevent direct contact of the product with the skin. Launder clothing before reuse. If skin irritation develops, contact your facility health and safety professional or your local safety equipment supplier to determine the proper personal protective equipment for your use. Wear resistant gloves (consult your safety equipment supplier). Respiratory protection Respiratory protection is not required under normal conditions of use. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state liquid Colour red Flash point > 356 °F / > 180 °C Cleveland open cup Lower explosion limit/Upper explosion limit 1 / 6 Calculated Explosive Limit Density 0.849 g/cm3 @ 60.01 °F / 15.56 °C 7.08 lb/gal 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid excessive heat Incompatible products Strong oxidizing agents Hazardous decomposition products carbon dioxide and carbon monoxide, Hydrocarbons Hazardous reactions Product will not undergo hazardous polymerization. 11. TOXICOLOGICAL INFORMATION Information on likely routes of : Inhalation Page 1139 of 1235 Page 1139 of 1235 Page 1139 of 1235 Page 1139 of 1235 ---PAGE BREAK--- Page: 6 SAFETY DATA SHEET Revision Date: 07/03/2013 Print Date: 9/18/2013 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.0 Page 6 / 10 exposure Skin absorption Skin contact Eye Contact Ingestion Product Acute oral toxicity : no data available Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Skin corrosion/irritation : no data available Serious eye damage/eye irritation : no data available Respiratory or skin sensitisation : no data available Aspiration toxicity : The substance or mixture is known to cause human aspiration toxicity hazards or has to be regarded as if it causes a human aspiration toxicity hazard. Components: no data available 12. ECOLOGICAL INFORMATION Ecotoxicity Product: no data available Components: no data available Persistence and degradability Product: no data available Components: Page 1140 of 1235 Page 1140 of 1235 Page 1140 of 1235 Page 1140 of 1235 ---PAGE BREAK--- Page: 7 SAFETY DATA SHEET Revision Date: 07/03/2013 Print Date: 9/18/2013 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.0 Page 7 / 10 no data available Bioaccumulative potential Product: no data available Components: no data available Mobility in soil Product: no data available Components: no data available 13. DISPOSAL CONSIDERATIONS Waste disposal methods Dispose of in accordance with all applicable local, state and federal regulations. 14. TRANSPORT INFORMATION REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP MARINE POLLUTANT / LTD. QTY. U.S. DOT - ROAD Not dangerous goods U.S. DOT - RAIL Not dangerous goods U.S. DOT - INLAND WATERWAYS Not dangerous goods TRANSPORT CANADA - ROAD Not dangerous goods TRANSPORT CANADA - RAIL Page 1141 of 1235 Page 1141 of 1235 Page 1141 of 1235 Page 1141 of 1235 ---PAGE BREAK--- Page: 8 SAFETY DATA SHEET Revision Date: 07/03/2013 Print Date: 9/18/2013 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.0 Page 8 / 10 Not dangerous goods TRANSPORT CANADA - INLAND WATERWAYS Not dangerous goods INTERNATIONAL MARITIME DANGEROUS GOODS Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER Not dangerous goods MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTES Not dangerous goods *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. 15. REGULATORY INFORMATION WHMIS Classification D2B Toxic Material Causing Other Toxic Effects This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. Canadian National Pollutant Release Inventory (NPRI)Canadian National Pollutant Release Inventory (NPRI): No component is listed on NPRI. Notification status US. Toxic Substances Control Act y (positive listing) Canada. Canadian Environmental Protection Act (CEPA). Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133) y (positive listing) Australia. Industrial Chemical (Notification and Assessment) Act y (positive listing) Page 1142 of 1235 Page 1142 of 1235 Page 1142 of 1235 Page 1142 of 1235 ---PAGE BREAK--- Page: 9 SAFETY DATA SHEET Revision Date: 07/03/2013 Print Date: 9/18/2013 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.0 Page 9 / 10 Japan. ENCS - Existing and New Chemical Substances Inventory n (Negative listing) Korea. Toxic Chemical Control Law (TCCL) List y (positive listing) Philippines. The Toxic Substances and Hazardous and Nuclear Waste Control Act y (positive listing) China. Inventory of Existing Chemical Substances y (positive listing) HMIS NFPA Health 1 1 Flammability 1 1 Physical hazards 0 Instability 0 Specific Hazard 16. OTHER INFORMATION The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department (1-[PHONE REDACTED]). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the “International Air Transport Association” (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the “International Civil Aviation Organization” IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment Page 1143 of 1235 Page 1143 of 1235 Page 1143 of 1235 Page 1143 of 1235 ---PAGE BREAK--- Page: 10 SAFETY DATA SHEET Revision Date: 07/03/2013 Print Date: 9/18/2013 MSDS Number: R0412087 Valvoline™ DEXRON®-VI FULL AUTOMATIC TRANSMISSION FLUID VV370 Version: 3.0 Page 10 / 10 STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System Page 1144 of 1235 Page 1144 of 1235 Page 1144 of 1235 Page 1144 of 1235 ---PAGE BREAK--- Page: 1 SAFETY DATA SHEET Revision Date: 01/30/2008 Print Date: 6/5/2008 MSDS Number: R0405762 WASH N SHINE #40185 Concentrated Car Soap Version: 1.3 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Ashland Regulatory Information Number 1-[PHONE REDACTED] P.O. Box 2219 Telephone [PHONE REDACTED] Columbus, OH 43216 Emergency telephone 1-800-ASHLAND (1-[PHONE REDACTED]) Product name WASH N SHINE #40185 Concentrated Car Soap Product code Product Use Description No data 2. HAZARDS IDENTIFICATION Emergency Overview Appearance: liquid,, greenish-blue CAUTION! MAY AFFECT THE CENTRAL NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. MAY CAUSE EYE IRRITATION. PROLONGED OR REPEATED CONTACT MAY DRY THE SKIN AND CAUSE IRRITATION AND BURNS. Potential Health Effects Routes of exposure Inhalation, Skin absorption, Skin contact, Eye Contact Eye contact Can cause eye irritation. include stinging, tearing, redness, and swelling of eyes. Skin contact May cause mild skin irritation. Prolonged or repeated contact may dry the skin. may include redness, burning, drying and cracking of skin, and skin burns. Ingestion Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. Page 1 / 9 Page 1145 of 1235 Page 1145 of 1235 Page 1145 of 1235 Page 1145 of 1235 ---PAGE BREAK--- Page: 2 SAFETY DATA SHEET Revision Date: 01/30/2008 Print Date: 6/5/2008 MSDS Number: R0405762 WASH N SHINE #40185 Concentrated Car Soap Version: 1.3 Inhalation It is possible to breathe this material under certain conditions of handling and use (for example, during heating, spraying, or stirring). Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. Aggravated Medical Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, skin, lung (for example, asthma-like conditions) Signs and of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways) Target Organs Studies with rabbits indicate that sustained, occluded skin contact with undiluted surfactant may result in the development of inflammatory changes in the lung., Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals:, mild, reversible liver effects, mild, reversible kidney effects Carcinogenicity This product contains ethanol. The International Agency for Research on Cancer (IARC) has determined that exposure to ethanol through chronic human consumption of alcoholic beverages can cause cancer. The relevance of this finding to ethanol exposure in industrial environments is uncertain. Reproductive hazard Based on the available information, risk to the fetus from maternal exposure to this material cannot be assessed. 3. COMPOSITION/INFORMATION ON INGREDIENTS Components CAS-No. Concentration DODECANOL, ETHOXYLATED, MONOETHER WITH SULFURIC ACID, SODIUM SALT 9004-82-4 Page 2 / 9 Page 1146 of 1235 Page 1146 of 1235 Page 1146 of 1235 Page 1146 of 1235 ---PAGE BREAK--- Page: 3 SAFETY DATA SHEET Revision Date: 01/30/2008 Print Date: 6/5/2008 MSDS Number: R0405762 WASH N SHINE #40185 Concentrated Car Soap Version: 1.3 4. FIRST AID MEASURES Eyes If develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention. Skin Remove contaminated clothing. Wash exposed area with soap and water. If persist, seek medical attention. Launder clothing before reuse. Ingestion Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. Inhalation If develop, move individual away from exposure and into fresh air. If persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention. Notes to physician Hazards: No information available. Treatment: No information available. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Alcohol-resistant foam, Agents approved for class B hazards or water fog., Carbon dioxide (CO2), Dry chemical Hazardous combustion products May form:, carbon dioxide and carbon monoxide, sodium oxides, sulfur oxides, various hydrocarbons Precautions for fire-fighting Page 3 / 9 Page 1147 of 1235 Page 1147 of 1235 Page 1147 of 1235 Page 1147 of 1235 ---PAGE BREAK--- Page: 4 SAFETY DATA SHEET Revision Date: 01/30/2008 Print Date: 6/5/2008 MSDS Number: R0405762 WASH N SHINE #40185 Concentrated Car Soap Version: 1.3 Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). DO NOT direct a solid stream of water or foam into hot, burning pools of liquid since this may cause frothing and increase fire intensity. Frothing can be violent and possibly endanger any firefighter standing too close to the burning liquid. Use water spray to cool fire exposed containers and structures until fire is out if it can be done with minimal risk. Avoid spreading burning liquid with water used for cooling purposes. 6. ACCIDENTAL RELEASE MEASURES Personal precautions For personal protection see section 8. Spills of this material are very slippery. Environmental precautions No data Methods for cleaning up Absorb liquid on vermiculite, floor absorbent or other absorbent material. Flush area with water. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source, dike area of spill to prevent spreading, pump liquid to salvage tank. Remaining liquid may be taken up on sand, clay, earth, floor absorbent, or other absorbent material and shoveled into containers. 7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. This material is slippery when wet. Avoid prolonged or frequently repeated skin contact with this material. Skin contact can be minimized by wearing impervious protective gloves. As with all products of this nature, good personal hygiene is essential. Hands and other exposed areas should be washed thoroughly with soap and water after contact, especially before eating and/or smoking. Regular laundering of contaminated clothing is essential to reduce indirect skin contact with this material. Warning. Sudden release of hot organic chemical vapors or mists from process equipment operating at elevated temperature and pressure, or sudden ingress of air into vacuum equipment, may result in ignitions without the presence of obvious ignition sources. Published "autoignition" or "ignition" temperature values cannot be treated as safe operating temperatures in chemical processes without analysis Page 4 / 9 Page 1148 of 1235 Page 1148 of 1235 Page 1148 of 1235 Page 1148 of 1235 ---PAGE BREAK--- Page: 5 SAFETY DATA SHEET Revision Date: 01/30/2008 Print Date: 6/5/2008 MSDS Number: R0405762 WASH N SHINE #40185 Concentrated Car Soap Version: 1.3 of the actual process conditions. Any use of this product in elevated temperature processes should be thoroughly evaluated to establish and maintain safe operating conditions. Storage Store in closed containers in a dry, well-ventilated area. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines General advice These recommendations provide general guidance for handling this product. Personal protective equipment should be selected for individual applications and should consider factors which affect exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities. Exposure controls General room ventilation should be adequate for normal conditions of use. However, if unusual operating conditions exist, provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Eye protection Not required under normal conditions of use. Wear splash-proof safety goggles if material could be misted or splashed into eyes. Skin and body protection Not normally required. However, wear resistant gloves such as nitrile rubber to prevent irritation which may result from prolonged or repeated skin contact with product. Wear normal work clothing including long pants, long-sleeved shirts and foot covering to prevent direct contact of the product with the skin. Launder clothing before reuse. If skin irritation develops, contact your facility health and safety professional or your local safety equipment supplier to determine the proper personal protective equipment for your use. Page 5 / 9 Page 1149 of 1235 Page 1149 of 1235 Page 1149 of 1235 Page 1149 of 1235 ---PAGE BREAK--- Page: 6 SAFETY DATA SHEET Revision Date: 01/30/2008 Print Date: 6/5/2008 MSDS Number: R0405762 WASH N SHINE #40185 Concentrated Car Soap Version: 1.3 Respiratory protection Respiratory protection is not required under normal conditions of use. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state liquid Form No data Colour greenish-blue Odour alcoholic Boiling point/boilingrange 100.00 °C / 212 1,013.33 hPa pH 9.5 Flash point No data Evaporation rate No data Explosion limits No data Vapour pressure 23.33 hPa @ 68 °F / 20 °C Vapour density No data Density No data No data Solubility No data Partition coefficient: n- octanol/water No data Autoignition temperature No data 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid Incompatible products Avoid contact with:, strong acids, strong oxidizing agents Hazardous decomposition products May form:, carbon dioxide and carbon monoxide, sodium oxides, Sulphur oxides, various hydrocarbons Page 6 / 9 Page 1150 of 1235 Page 1150 of 1235 Page 1150 of 1235 Page 1150 of 1235 ---PAGE BREAK--- Page: 7 SAFETY DATA SHEET Revision Date: 01/30/2008 Print Date: 6/5/2008 MSDS Number: R0405762 WASH N SHINE #40185 Concentrated Car Soap Version: 1.3 Hazardous reactions Product will not undergo hazardous polymerization. Thermal decomposition No data 11. TOXICOLOGICAL INFORMATION Acute oral toxicity DODECANOL, ETHOXYLATED, MONOETHER WITH SULFURIC ACID, SODIUM SALT LD 50 Rat: 1,600 mg/kg Acute inhalation toxicity Acute dermal toxicity 12. ECOLOGICAL INFORMATION Aquatic toxicity Acute and Prolonged Toxicity to Fish No data Acute Toxicity to Aquatic Invertebrates No data Environmental fate and pathways No data 13. DISPOSAL CONSIDERATIONS Waste disposal methods Dispose of in accordance with all applicable local, state and federal regulations. Do not discharge effluent containing this product into lakes, streams, ponds or estuaries, oceans, or other waters unless in accordance with the requirements of a National Page 7 / 9 Page 1151 of 1235 Page 1151 of 1235 Page 1151 of 1235 Page 1151 of 1235 ---PAGE BREAK--- Page: 8 SAFETY DATA SHEET Revision Date: 01/30/2008 Print Date: 6/5/2008 MSDS Number: R0405762 WASH N SHINE #40185 Concentrated Car Soap Version: 1.3 Pollutant Discharge Elimination System (NPDES) permit, and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. For assistance with your waste management needs - including disposal, recycling and waste stream reduction, contact Ashland Distribution's Environmental Services Group at [PHONE REDACTED]. 14. TRANSPORT INFORMATION Dangerous goods descriptions (if indicated above) may not reflect package size, quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. 15. REGULATORY INFORMATION WHMIS Classification D2B Toxic Material Causing Other Toxic Effects This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. Health Flammability Reactivity Other HMIS 1 0 0 NFPA No data 16. OTHER INFORMATION The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This Page 8 / 9 Page 1152 of 1235 Page 1152 of 1235 Page 1152 of 1235 Page 1152 of 1235 ---PAGE BREAK--- Page: 9 SAFETY DATA SHEET Revision Date: 01/30/2008 Print Date: 6/5/2008 MSDS Number: R0405762 WASH N SHINE #40185 Concentrated Car Soap Version: 1.3 MSDS has been prepared by Ashland's Environmental Health and Safety Department [PHONE REDACTED]). Page 9 / 9 Page 1153 of 1235 Page 1153 of 1235 Page 1153 of 1235 Page 1153 of 1235 ---PAGE BREAK--- Page: 1 SAFETY DATA SHEET Revision Date: 01/26/2008 Print Date: 6/5/2008 MSDS Number: R0405762 WASH N SHINE #40185 Concentrated Car Soap Version: 1.3 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Ashland Regulatory Information Number 1-[PHONE REDACTED] P.O. Box 2219 Telephone [PHONE REDACTED] Columbus, OH 43216 Emergency telephone 1-800-ASHLAND (1-[PHONE REDACTED]) Product name WASH N SHINE #40185 Concentrated Car Soap Product code Product Use Description No data 2. HAZARDS IDENTIFICATION Emergency Overview Appearance: liquid,, greenish-blue CAUTION! MAY AFFECT THE CENTRAL NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. MAY CAUSE EYE IRRITATION. PROLONGED OR REPEATED CONTACT MAY DRY THE SKIN AND CAUSE IRRITATION AND BURNS. Potential Health Effects Routes of exposure Inhalation, Skin absorption, Skin contact, Eye Contact Eye contact Can cause eye irritation. include stinging, tearing, redness, and swelling of eyes. Skin contact May cause mild skin irritation. Prolonged or repeated contact may dry the skin. may include redness, burning, drying and cracking of skin, and skin burns. Ingestion Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. Page 1 / 9 Page 1154 of 1235 Page 1154 of 1235 Page 1154 of 1235 Page 1154 of 1235 ---PAGE BREAK--- Page: 2 SAFETY DATA SHEET Revision Date: 01/26/2008 Print Date: 6/5/2008 MSDS Number: R0405762 WASH N SHINE #40185 Concentrated Car Soap Version: 1.3 Inhalation It is possible to breathe this material under certain conditions of handling and use (for example, during heating, spraying, or stirring). Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. Aggravated Medical Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, skin, lung (for example, asthma-like conditions) Signs and of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways) Target Organs Studies with rabbits indicate that sustained, occluded skin contact with undiluted surfactant may result in the development of inflammatory changes in the lung., Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals:, mild, reversible liver effects, mild, reversible kidney effects Carcinogenicity This product contains ethanol. The International Agency for Research on Cancer (IARC) has determined that exposure to ethanol through chronic human consumption of alcoholic beverages can cause cancer. The relevance of this finding to ethanol exposure in industrial environments is uncertain. Reproductive hazard Based on the available information, risk to the fetus from maternal exposure to this material cannot be assessed. 3. COMPOSITION/INFORMATION ON INGREDIENTS Components CAS-No. Concentration DODECANOL, ETHOXYLATED, MONOETHER WITH SULFURIC ACID, SODIUM SALT 9004-82-4 Page 2 / 9 Page 1155 of 1235 Page 1155 of 1235 Page 1155 of 1235 Page 1155 of 1235 ---PAGE BREAK--- Page: 3 SAFETY DATA SHEET Revision Date: 01/26/2008 Print Date: 6/5/2008 MSDS Number: R0405762 WASH N SHINE #40185 Concentrated Car Soap Version: 1.3 ETHANOL 64-17-5 4. FIRST AID MEASURES Eyes If develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention. Skin Remove contaminated clothing. Wash exposed area with soap and water. If persist, seek medical attention. Launder clothing before reuse. Ingestion Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. Inhalation If develop, move individual away from exposure and into fresh air. If persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention. Notes to physician Hazards: No information available. Treatment: No information available. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Alcohol-resistant foam, Agents approved for class B hazards or water fog., Carbon dioxide (CO2), Dry chemical Hazardous combustion products May form:, carbon dioxide and carbon monoxide, sodium oxides, sulfur oxides, various hydrocarbons Page 3 / 9 Page 1156 of 1235 Page 1156 of 1235 Page 1156 of 1235 Page 1156 of 1235 ---PAGE BREAK--- Page: 4 SAFETY DATA SHEET Revision Date: 01/26/2008 Print Date: 6/5/2008 MSDS Number: R0405762 WASH N SHINE #40185 Concentrated Car Soap Version: 1.3 Precautions for fire-fighting Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). DO NOT direct a solid stream of water or foam into hot, burning pools of liquid since this may cause frothing and increase fire intensity. Frothing can be violent and possibly endanger any firefighter standing too close to the burning liquid. Use water spray to cool fire exposed containers and structures until fire is out if it can be done with minimal risk. Avoid spreading burning liquid with water used for cooling purposes. 6. ACCIDENTAL RELEASE MEASURES Personal precautions For personal protection see section 8. Spills of this material are very slippery. Environmental precautions No data Methods for cleaning up Absorb liquid on vermiculite, floor absorbent or other absorbent material. Flush area with water. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source, dike area of spill to prevent spreading, pump liquid to salvage tank. Remaining liquid may be taken up on sand, clay, earth, floor absorbent, or other absorbent material and shoveled into containers. 7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. This material is slippery when wet. Avoid prolonged or frequently repeated skin contact with this material. Skin contact can be minimized by wearing impervious protective gloves. As with all products of this nature, good personal hygiene is essential. Hands and other exposed areas should be washed thoroughly with soap and water after contact, especially before eating and/or smoking. Regular laundering of contaminated clothing is essential to reduce indirect skin contact with this material. Warning. Sudden release of hot organic chemical vapors or mists from process equipment operating at elevated temperature and pressure, or sudden ingress of air into vacuum equipment, may result in ignitions without the presence of obvious ignition sources. Published "autoignition" or "ignition" temperature values Page 4 / 9 Page 1157 of 1235 Page 1157 of 1235 Page 1157 of 1235 Page 1157 of 1235 ---PAGE BREAK--- Page: 5 SAFETY DATA SHEET Revision Date: 01/26/2008 Print Date: 6/5/2008 MSDS Number: R0405762 WASH N SHINE #40185 Concentrated Car Soap Version: 1.3 cannot be treated as safe operating temperatures in chemical processes without analysis of the actual process conditions. Any use of this product in elevated temperature processes should be thoroughly evaluated to establish and maintain safe operating conditions. Storage Store in closed containers in a dry, well-ventilated area. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines General advice These recommendations provide general guidance for handling this product. Personal protective equipment should be selected for individual applications and should consider factors which affect exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities. Exposure controls General room ventilation should be adequate for normal conditions of use. However, if unusual operating conditions exist, provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Eye protection Not required under normal conditions of use. Wear splash-proof safety goggles if material could be misted or splashed into eyes. Skin and body protection Not normally required. However, wear resistant gloves such as nitrile rubber to prevent irritation which may result from prolonged or repeated skin contact with product. Wear normal work clothing including long pants, long-sleeved shirts and foot covering to prevent direct contact of the product with the skin. Launder clothing before reuse. If skin irritation develops, contact your facility health and safety professional or your local safety equipment supplier to determine the proper personal protective equipment for your use. Page 5 / 9 Page 1158 of 1235 Page 1158 of 1235 Page 1158 of 1235 Page 1158 of 1235 ---PAGE BREAK--- Page: 6 SAFETY DATA SHEET Revision Date: 01/26/2008 Print Date: 6/5/2008 MSDS Number: R0405762 WASH N SHINE #40185 Concentrated Car Soap Version: 1.3 Respiratory protection Respiratory protection is not required under normal conditions of use. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state liquid Form No data Colour greenish-blue Odour alcoholic Boiling point/boilingrange 100.00 °C / 212 1,013.33 hPa pH 9.5 Flash point No data Evaporation rate No data Explosion limits No data Vapour pressure 23.33 hPa @ 68 °F / 20 °C Vapour density No data Density No data No data Solubility No data Partition coefficient: n- octanol/water No data Autoignition temperature No data 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid Incompatible products Avoid contact with:, strong acids, strong oxidizing agents Hazardous decomposition products May form:, carbon dioxide and carbon monoxide, sodium oxides, Sulphur oxides, various hydrocarbons Page 6 / 9 Page 1159 of 1235 Page 1159 of 1235 Page 1159 of 1235 Page 1159 of 1235 ---PAGE BREAK--- Page: 7 SAFETY DATA SHEET Revision Date: 01/26/2008 Print Date: 6/5/2008 MSDS Number: R0405762 WASH N SHINE #40185 Concentrated Car Soap Version: 1.3 Hazardous reactions Product will not undergo hazardous polymerization. Thermal decomposition No data 11. TOXICOLOGICAL INFORMATION Acute oral toxicity DODECANOL, ETHOXYLATED, MONOETHER WITH SULFURIC ACID, SODIUM SALT LD 50 Rat: 1,600 mg/kg ETHANOL LD 50 Rat: 7,060 mg/kg Acute inhalation toxicity ETHANOL LC 50 Rat: 20000 ppm, 10 h Acute dermal toxicity ETHANOL LD Lo Rabbit: 20 g/kg 12. ECOLOGICAL INFORMATION Aquatic toxicity Acute and Prolonged Toxicity to Fish No data Acute Toxicity to Aquatic Invertebrates No data Environmental fate and pathways No data Page 7 / 9 Page 1160 of 1235 Page 1160 of 1235 Page 1160 of 1235 Page 1160 of 1235 ---PAGE BREAK--- Page: 8 SAFETY DATA SHEET Revision Date: 01/26/2008 Print Date: 6/5/2008 MSDS Number: R0405762 WASH N SHINE #40185 Concentrated Car Soap Version: 1.3 13. DISPOSAL CONSIDERATIONS Waste disposal methods Dispose of in accordance with all applicable local, state and federal regulations. Do not discharge effluent containing this product into lakes, streams, ponds or estuaries, oceans, or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit, and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. For assistance with your waste management needs - including disposal, recycling and waste stream reduction, contact Ashland Distribution's Environmental Services Group at [PHONE REDACTED]. 14. TRANSPORT INFORMATION Dangerous goods descriptions (if indicated above) may not reflect package size, quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. 15. REGULATORY INFORMATION California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer. ETHANOL NICKEL COBALT 1,4-DIOXANE SARA Hazard Classification Acute Health Hazard Chronic Health Hazard SARA 313 Component(s) Page 8 / 9 Page 1161 of 1235 Page 1161 of 1235 Page 1161 of 1235 Page 1161 of 1235 ---PAGE BREAK--- Page: 9 SAFETY DATA SHEET Revision Date: 01/26/2008 Print Date: 6/5/2008 MSDS Number: R0405762 WASH N SHINE #40185 Concentrated Car Soap Version: 1.3 Health Flammability Reactivity Other HMIS 1 0 0 NFPA No data 16. OTHER INFORMATION The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department [PHONE REDACTED]). Page 9 / 9 Page 1162 of 1235 Page 1162 of 1235 Page 1162 of 1235 Page 1162 of 1235 ---PAGE BREAK--- 174' 10/19/2004 M A T E R I A L S A F E T Y D A T A S H E E T PRODUCT NAME: WEATHERGUARD LO-SHEEN WHITE HMIS CODES: H F R P PRODUCT CODE: 174' 1 1 0 B SECTION I - MANUFACTURER IDENTIFICATION MANUFACTURER'S NAME: HALLMAN/LINDSAY PAINTS ADDRESS : P.O. BOX 109 SUN PRAIRIE, WI 53590 EMERGENCY PHONE : 1-[PHONE REDACTED] DATE PRINTED : 10/19/2004 INFORMATION PHONE : (608) 834-8844 NAME OF PREPARER : MICHAEL MC NULTY SECTION II - HAZARDOUS INGREDIENTS/SARA III INFORMATION WEIGHT REPORTABLE COMPONENTS CAS NUMBER PERCENT TITANIUM DIOXIDE 13463-67-7 OSHA PEL: 10 MG/M3, ACGIH TLV: 10 MG/M3, STEL TLV: N/A ALUMINUM SILICATE 1332-58-7 OSHA PEL: 5 MG/M3 ACGIH TLV: 5MG/M3 No toxic chemical(s) subject to the reporting requirements of section 313 of Title III and of 40 CFR 372 are present. Sanding the cured product may produce a nuisance dust. Observe a TLV of 10 mg/m3 for total dust containing no asbestos and silica. Observe a TLV of 5mg/m3 for respirable dust. SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS BOILING RANGE: N/A SPECIFIC GRAVITY (H2O=1): 1.29 VAPOR DENSITY: HEAVIER THAN AIR EVAPORATION RATE: SLOWER THAN ETHER COATING V.O.C.: 0.96 lb/gl MATERIAL V.O.C.: 0.43 lb/gl SOLUBILITY IN WATER: N/A APPEARANCE AND ODOR: LIQUID COATING WITH MILD ODOR SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT: N/A METHOD USED: N/A FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER: N/A UPPER: N/A EXTINGUISHING MEDIA: WATER FOG, DRY CHEMICAL, CARBON DIOXIDE SPECIAL FIREFIGHTING PROCEDURES Water spray may cool containers. Normal firefighting proceedures may be used. UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may burst when exposed to extreme heat. SECTION V - REACTIVITY DATA STABILITY: STABLE CONDITIONS TO AVOID Keep from freezing. Page 1163 of 1235 Page 1163 of 1235 Page 1163 of 1235 Page 1163 of 1235 ---PAGE BREAK--- INCOMPATIBILITY (MATERIALS TO AVOID) Strong oxidizing agents. HAZARDOUS DECOMPOSITION OR BYPRODUCTS Under heat, Carbon Dioxide and Carbon Monoxide may be produced. HAZARDOUS POLYMERIZATION: Will Not Occur SECTION VI - HEALTH HAZARD DATA INHALATION HEALTH RISKS AND OF EXPOSURE May irritate respitory tract(nose, throat, lungs) SKIN AND EYE CONTACT HEALTH RISKS AND OF EXPOSURE EYE CONTACT: Short term liquid or vapor contact may result in slight irritation. Prolonged or repeated contact may be more irritating. SKIN CONTACT: May cause mild irritation to skin. Prolonged and repeated contact with skin can cause defatting and drying of the skin which may result in skin irritation and dermatitus. SKIN ABSORPTION HEALTH RISKS AND OF EXPOSURE Can dry and defat skin causing cracks, irritation, and dermatitis. INGESTION HEALTH RISKS AND OF EXPOSURE DO NOT TAKE INTERNALLY HEALTH HAZARDS (ACUTE AND CHRONIC) EFFECTS OF ACUTE EXPOSURE EYE CONTACT.............May cause: Mild eye irritation. cause: Mild skin irritation. INHALATION..............None known. INGESTION...............May cause:Nausea. CARCINOGENICITY: NTP CARCINOGEN: N/A IARC MONOGRAPHS: N/A OSHA REGULATED: N/A None of the ingrediants in this product are listed as a potential carcinogen by the NTP, IARC, or OSHA MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE Skin Disorders EMERGENCY AND FIRST AID PROCEDURES INHALATION OVEREXPOSURE-Move person to fresh air. INGESTION-Give two glasses of water to drink. Call a DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. SKIN CONTACT- Wash thoroughly with soap and water. EYE CONTACT- Flush with large quantities of water for 15 minutes SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Dike spill to minimize contamination. Absorb with inert material. Collect in containers. Keep spill out of waterways. WASTE DISPOSAL METHOD Dispose of material in accordance with Federal, State and Local regulations. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Avoid prolonged contact with liquid and/or vapor. KEEP FROM FREEZING. Page 1164 of 1235 Page 1164 of 1235 Page 1164 of 1235 Page 1164 of 1235 ---PAGE BREAK--- OTHER PRECAUTIONS Never take internally. Wash thoroughly after use. SECTION VIII - CONTROL MEASURES RESPIRATORY PROTECTION When spraying this material use a NIOSH approved cartridge respirator to keep airborne mists and vapor concentrations below TLV values. VENTILATION MECHANICAL-(GENERAL) Adequate PROTECTIVE GLOVES Impervious gloves EYE PROTECTION Safety glasses recommended. OTHER PROTECTIVE CLOTHING OR EQUIPMENT Eye Wash WORK/HYGIENIC PRACTICES Eye washes and safety showers in the workplace are recommended. Wash hands thoroughly with soap and water after applying product. SECTION IX - DISCLAIMER This M.S.D.S. is furnished without charge to responsible persons who use it at their discretion and risk. Although the information and suggestions contained herein have been compiled, as of the issue date above, from sources believed to be reliable, there is no warranty of any kind, express or implied, as to the completeness and accuracy thereof. Page 1165 of 1235 Page 1165 of 1235 Page 1165 of 1235 Page 1165 of 1235 ---PAGE BREAK--- Page 1166 of 1235 Page 1166 of 1235 Page 1166 of 1235 Page 1166 of 1235 ---PAGE BREAK--- Page 1167 of 1235 Page 1167 of 1235 Page 1167 of 1235 Page 1167 of 1235 ---PAGE BREAK--- Page 1168 of 1235 Page 1168 of 1235 Page 1168 of 1235 Page 1168 of 1235 ---PAGE BREAK--- Page 1169 of 1235 Page 1169 of 1235 Page 1169 of 1235 Page 1169 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 WINDEX® ORIGINAL GLASS CLEANER WITH AMMONIA-D® Version 1.1 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000014153 1/9 1. PRODUCT AND COMPANY IDENTIFICATION Product information Product name : WINDEX® ORIGINAL GLASS CLEANER WITH AMMONIA- D® Recommended use : Hard Surface Cleaner Manufacturer, importer, supplier : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236 Telephone : +18005585252 Emergency telephone number : 24 Hour Medical Emergency Phone: (866)231-5406 24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300 2. HAZARDS IDENTIFICATION Classification of the substance or mixture Globally Harmonized System (GHS) Classification This product does not meet the criteria for classification in any hazard class according to regulation OSHA 29 CFR 1910.1200. Labelling Precautionary statements Other hazards : None identified 3. COMPOSITION/INFORMATION ON INGREDIENTS This product does not contain hazardous chemicals at or above a reportable level as defined by OSHA 29 CFR 1910.1200 For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Page 1170 of 1235 Page 1170 of 1235 Page 1170 of 1235 Page 1170 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 WINDEX® ORIGINAL GLASS CLEANER WITH AMMONIA-D® Version 1.1 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000014153 2/9 Eye contact : No special requirements Skin contact : No special requirements Inhalation : No special requirements. Ingestion : No special requirements 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during firefighting : Container may melt and leak in heat of fire. Further information : Fight fire with normal precautions from a reasonable distance. Standard procedure for chemical fires. Wear full protective clothing and positive pressure self-contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Wash thoroughly after handling. Environmental precautions : Outside of normal use, avoid release to the environment. Methods and materials for containment and cleaning up : Dike large spills. Clean residue from spill site. 7. HANDLING AND STORAGE Handling Precautions for safe handling : Avoid contact with skin, eyes and clothing. For personal protection see section 8. KEEP OUT OF REACH OF CHILDREN AND PETS. Page 1171 of 1235 Page 1171 of 1235 Page 1171 of 1235 Page 1171 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 WINDEX® ORIGINAL GLASS CLEANER WITH AMMONIA-D® Version 1.1 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000014153 3/9 Advice on protection against fire and explosion : Normal measures for preventive fire protection. Storage Requirements for storage areas and containers : Keep container closed when not in use. Other data : Stable under normal conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits ACGIH or OSHA exposure limits have not been established for this product or reportable ingredients unless noted in the table above. Personal protective equipment Respiratory protection : No special requirements. Hand protection : No special requirements. Eye protection : No special requirements. Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : liquid Color : blue Odor : pleasant Odour Threshold : Test not applicable for this product type pH : 10.7 Page 1172 of 1235 Page 1172 of 1235 Page 1172 of 1235 Page 1172 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 WINDEX® ORIGINAL GLASS CLEANER WITH AMMONIA-D® Version 1.1 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000014153 4/9 at (25 C) Melting point/freezing point : 0 C Initial boiling point and boiling range : 100 C Flash point : > 93 °C > 199.4 °F Approximate Evaporation rate : No data available Flammability (solid, gas) : Does not sustain combustion. Upper/lower flammability or explosive limits : No data available Vapour pressure : No data available Vapour density : No data available Relative density : 1.00 g/cm3 at 25 C Solubility(ies) : soluble Partition coefficient: n- octanol/water : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Page 1173 of 1235 Page 1173 of 1235 Page 1173 of 1235 Page 1173 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 WINDEX® ORIGINAL GLASS CLEANER WITH AMMONIA-D® Version 1.1 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000014153 5/9 Viscosity, dynamic : No data available Viscosity, kinematic : No data available Oxidizing properties : No data available Volatile Organic Compounds Total VOC (wt. : 0.2 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations Other information : None identified : 10. STABILITY AND REACTIVITY Possibility of hazardous reactions : If accidental mixing occurs and toxic gas is formed, exit area immediately. Do not return until well ventilated. Conditions to avoid : Direct sources of heat. Incompatible materials : Do not mix with bleach or any other household cleaners. Strong bases Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. 11. TOXICOLOGICAL INFORMATION Emergency Overview : This product does not meet the criteria for classification in any hazard class according to regulation OSHA 29 CFR 1910.1200. Acute oral toxicity : LD50 estimated Page 1174 of 1235 Page 1174 of 1235 Page 1174 of 1235 Page 1174 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 WINDEX® ORIGINAL GLASS CLEANER WITH AMMONIA-D® Version 1.1 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000014153 6/9 > 5,000 mg/kg Acute inhalation toxicity : LC50 estimated > 2.58 mg/l Acute dermal toxicity : LD50 estimated > 5,000 mg/kg GHS Properties Classification Routes of entry Acute toxicity No classification proposed - Skin corrosion/irritation No classification proposed - Serious eye damage/eye irritation No classification proposed - Skin sensitisation No classification proposed - Respiratory sensitisation No classification proposed - Germ cell mutagenicity No classification proposed - Carcinogenicity No classification proposed - Reproductive toxicity No classification proposed - Specific target organ toxicity - single exposure No classification proposed - Specific target organ toxicity - repeated exposure No classification proposed - Aspiration hazard No classification proposed - Aggravated Medical Condition : None known. Page 1175 of 1235 Page 1175 of 1235 Page 1175 of 1235 Page 1175 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 WINDEX® ORIGINAL GLASS CLEANER WITH AMMONIA-D® Version 1.1 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000014153 7/9 12. ECOLOGICAL INFORMATION Product : The product itself has not been tested. Toxicity The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions. No environmental data required. Other adverse effects : None known. 13. DISPOSAL CONSIDERATIONS Consumer may discard empty container in trash, or recycle where facilities exist. 14. TRANSPORT INFORMATION Please refer to the Bill of Lading/receiving documents for up-to-date shipping information. Land transport Not classified as dangerous in the meaning of transport regulations. Sea transport Not classified as dangerous in the meaning of transport regulations. Air transport Not classified as dangerous in the meaning of transport regulations. 15. REGULATORY INFORMATION Notification status : All ingredients of this product are listed or are excluded from Page 1176 of 1235 Page 1176 of 1235 Page 1176 of 1235 Page 1176 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 WINDEX® ORIGINAL GLASS CLEANER WITH AMMONIA-D® Version 1.1 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000014153 8/9 listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Notification status : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA). California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. 16. OTHER INFORMATION HMIS Ratings Health 1 Flammability 2 Reactivity 0 NFPA Ratings Health 1 Fire 2 Reactivity 0 Special - This information is being provided in accordance with the Occupational Safety and Health Administration (OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use. Further information Page 1177 of 1235 Page 1177 of 1235 Page 1177 of 1235 Page 1177 of 1235 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 WINDEX® ORIGINAL GLASS CLEANER WITH AMMONIA-D® Version 1.1 Print Date 03/04/2015 Revision Date 02/25/2015 SDS Number 350000014153 9/9 This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 1178 of 1235 Page 1178 of 1235 Page 1178 of 1235 Page 1178 of 1235 ---PAGE BREAK--- Page 1179 of 1235 Page 1179 of 1235 Page 1179 of 1235 Page 1179 of 1235 ---PAGE BREAK--- Page 1180 of 1235 Page 1180 of 1235 Page 1180 of 1235 Page 1180 of 1235 ---PAGE BREAK--- Page 1181 of 1235 Page 1181 of 1235 Page 1181 of 1235 Page 1181 of 1235 ---PAGE BREAK--- Page 1182 of 1235 Page 1182 of 1235 Page 1182 of 1235 Page 1182 of 1235 ---PAGE BREAK--- Page 1183 of 1235 Page 1183 of 1235 Page 1183 of 1235 Page 1183 of 1235 ---PAGE BREAK--- Page 1184 of 1235 Page 1184 of 1235 Page 1184 of 1235 Page 1184 of 1235 ---PAGE BREAK--- Page 1185 of 1235 Page 1185 of 1235 Page 1185 of 1235 Page 1185 of 1235 ---PAGE BREAK--- Date Printed: 7/7/2015 Product: M145-2276 Safety Data Sheet 1. Identification Product Information: M145-2276 Product Name: WIPING WOOD™ STAIN AEROSOL DARK RED MAHOGANY Recommended Use: Surface Preparation or Protection Mohawk Finishing Products Division of RPM Wood Finishes Group, Inc. 22 South Center Street Hickory, NC 28602 USA Supplied by: Company Phone No: (800) 522-8266 Emergency Phone No. CHEMTREC: (800) 424-9300 (703) 527-3887 (Collect calls are accepted) International Emergency No. CHEMTREC: 2. Hazards Identification GHS Classification Acute Tox. 4 Inhalation, Asp. Tox. 1, Carc. 1A, Fl Aer, 1, Muta. 1B, STOT RE 1 Symbol(s) of Product Signal Word Danger GHS HAZARD STATEMENTS Flammable Aerosol, category 1 H222 Extremely flammable aerosol. Aspiration Hazard, category 1 H304 May be fatal if swallowed and enters airways. Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled. Germ Cell Mutagenicity, category 1B H340 May cause genetic defects. Carcinogenicity, category 1A H350 May cause cancer. STOT, repeated exposure, category 1 H372 Causes damage to organs through prolonged or repeated exposure. GHS LABEL PRECAUTIONARY STATEMENTS P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P211 Do not spray on an open flame or other ignition source. P251 Do not pierce or burn, even after use. P260 Do not breathe dust/fume/gas/mist/vapours/spray. Page 1 / 7 Page 1186 of 1235 Page 1186 of 1235 Page 1186 of 1235 Page 1186 of 1235 ---PAGE BREAK--- Date Printed: 7/7/2015 Product: M145-2276 P264 Wash hands thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308+P313 IF exposed or concerned: Get medical advice/attention. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P331 Do NOT induce vomiting. P405 Store locked up. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C/ 122°F. GHS SDS PRECAUTIONARY STATEMENTS P270 Do not eat, drink or smoke when using this product. 3. Composition/Information on ingredients Chemical Name CAS-No. Wt. % GHS Symbols GHS Statements aliphatic petroleum distillates 64742-88-7 25-40 GHS06-GHS08 H304-331-372 aliphatic petroleum distillates 64742-47-8 25-40 GHS06-GHS08 H304-331 sweetened liquid petroluem gas 68476-86-8 10-25 GHS07-GHS08 H332-340-350 m-xylene 108-38-3 1.0-2.5 GHS02-GHS07 H226-315-332 carbon black 1333-86-4 0.1-1.0 GHS02 H251 p-xylene 106-42-3 0.1-1.0 GHS02-GHS07 H226-312-315-332 aliphatic hydrocarbons 8052-41-3 0.1-1.0 GHS08 H304-340-350-372 aromatic hydrocarbons 64742-95-6 0.1-1.0 GHS06-GHS08 H304-331-340-350 silica 14808-60-7 0.1-1.0 GHS07 H302 benzene 71-43-2 <0.1 GHS02-GHS07- GHS08 H225-302-304-315-319-340-350 -372 The text for GHS Hazard Statements shown above (if any) is given in the "Other information" Section. 4. First-aid Measures FIRST AID - EYE CONTACT: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. FIRST AID - SKIN CONTACT: IF ON SKIN: Gently wash with plenty of Soap and Water. If skin irritation occurs: Get medical advice/ attention. FIRST AID - INGESTION: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. FIRST AID - INHALATION: IF INHALED: Remove person to fresh air and keep comfortable for breathing. 5. Fire-fighting Measures SPECIAL FIREFIGHTING PROCEDURES: Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. FIREFIGHTING EQUIPMENT: This is a NFPA/OSHA Category 1 flammable aerosol. Follow NFPA 30B, Chapter 4 for fire protection Page 2 / 7 Page 1187 of 1235 Page 1187 of 1235 Page 1187 of 1235 Page 1187 of 1235 ---PAGE BREAK--- Date Printed: 7/7/2015 Product: M145-2276 and fire suppression. Use a dry chemical, carbon dioxide, or similar ABC fire extinguisher for incipient fires. Water may be used to cool and prevent rupture of containers that are exposed to heat from fire 6. Accidental Release Measures ENVIRONMENTAL MEASURES: No Information STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Follow personal protective equipment recommendations found in Section VIII. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage system or open waterways. 7. Handling and Storage HANDLING: Avoid inhalation and contact with eyes, skin, and clothing. Wash hands thoroughly after handling and before eating or drinking. In keeping with safe handling practices, avoid ignition sources (smoking, flames, pilot lights, electrical sparks); ground and bond containers when transferring the material to prevent static electricity sparks that could ignite vapor and use spark proof tools and explosion proof equipment. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Any of these actions can potentially cause an explosion that may lead to injury. STORAGE: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials. 8. Exposure Controls/Personal Protection Ingredients with Occupational Exposure Limits Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA OSHA PEL-CEILING aliphatic petroleum distillates N.D. N.D. N.D. N.D. aliphatic petroleum distillates N.D. N.D. N.D. N.D. sweetened liquid petroluem gas N.D. N.D. N.D. N.D. m-xylene 100 ppm 150 ppm 100 ppm N.D. carbon black 3 mg/m3 N.D. 3.5 mg/m3 N.D. p-xylene 100 ppm 150 ppm 100 ppm N.D. aliphatic hydrocarbons 100 ppm N.D. 500 ppm N.D. aromatic hydrocarbons N.D. N.D. N.D. N.D. silica 0.025 mg/m3 N.D. N.D. N.D. benzene 0.5 ppm 2.5 ppm 10 ppm 25 ppm Further Advice: MEL = Maximum Exposure Limit OES = Occupational Exposure Standard SUP = Supplier's Recommendation Sk = Skin Sensitizer N.E. = Not Established N.D. = Not Determined Personal Protection RESPIRATORY PROTECTION: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. SKIN PROTECTION: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate. Page 3 / 7 Page 1188 of 1235 Page 1188 of 1235 Page 1188 of 1235 Page 1188 of 1235 ---PAGE BREAK--- Date Printed: 7/7/2015 Product: M145-2276 EYE PROTECTION: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying of material. OTHER PROTECTIVE EQUIPMENT: No Information HYGIENIC PRACTICES: It is good practice to avoid contact with the product and/or its vapors, mists or dust by using appropriate protective measures. Wash thoroughly after handling and before eating or drinking. 9. Physical and Chemical Properties Colored Liquid Aerosol Appearance: Physical State: Oily Hydrocarbon Not determined Odor: Odor Threshold: 0.747 Not determined Density, g/cm3: pH: Not determined Not determined Freeze Point, Viscosity: Not determined Partition Coefficient, n-octanol/ water: Not determined Solubility in Water: Not determined Not determined Decomposition temperature, Explosive Limits, Not determined -69 ° F Boiling Range, Flash Point, Supports Combustion Not determined Combustibility: Auto-Ignition Temperature, Faster than Diethyl Ether Not determined Evaporation Rate: Vapor Pressure, mmHg: Not determined Vapor Density: N.I. = No Information 10. Stability and reactivity STABILITY: Stable under normal conditions. CONDITIONS TO AVOID: Heat, flames and sparks. INCOMPATIBILITY: Acids, Bases, Oxidizing agents HAZARDOUS DECOMPOSITION PRODUCTS: Not determined. Page 4 / 7 Page 1189 of 1235 Page 1189 of 1235 Page 1189 of 1235 Page 1189 of 1235 ---PAGE BREAK--- Date Printed: 7/7/2015 Product: M145-2276 11. Toxicological information Practical Experiences EMERGENCY OVERVIEW: No Information EFFECT OF OVEREXPOSURE - EYE CONTACT: No Information EFFECT OF OVEREXPOSURE - INGESTION: No Information EFFECT OF OVEREXPOSURE - INHALATION: No Information EFFECT OF OVEREXPOSURE - SKIN CONTACT: No Information CARCINOGENICITY: May cause cancer. PRIMARY ROUTE(S) OF ENTRY: Ingestion, Inhalation Acute Toxicity Values The acute effects of this product have not been tested. Data on individual components are tabulated below CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50 64742-88-7 aliphatic petroleum distillates >5000 mg/kg Rat 3000 mg/kg Rabbit >5.28 mg/L Rat 64742-47-8 aliphatic petroleum distillates >5000 mg/kg Rat >2000 mg/kg Rabbit >5.2 mg/L Rat 68476-86-8 sweetened liquid petroluem gas 6960 mg/kg Rat N.I. 1355 mg/L Rat 108-38-3 m-xylene 5000 mg/kg Rat 6500 mg/kg Rabbit >20 mg/l Rat 1333-86-4 carbon black >5000 mg/kg Rat >3000 mg/kg Rabbit >20 mg/l 106-42-3 p-xylene 4029 mg/kg Rat N.I. >20 mg/l Rat 8052-41-3 aliphatic hydrocarbons >5000 mg/kg Rat >3160 mg/kg Rat 21 mg/L Rat 64742-95-6 aromatic hydrocarbons 14000 mg/kg Rat >2000 mg/kg Rabbit >4.96 mg/l Rat 14808-60-7 silica 500 mg/kg Rat N.I. >20 mg/l Rat 71-43-2 benzene 810 mg/kg Rat >8200 mg/kg Rabbit 44.66 mg/L Rat N.I. = No Information 12. Ecological information ECOLOGICAL INFORMATION: Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the environment without governmental approval/permits. 13. Disposal Information Product DISPOSAL METHOD: Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Follow personal protective equipment recommendations found in Section VIII. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled product to enter public drainage system or open waterways. Page 5 / 7 Page 1190 of 1235 Page 1190 of 1235 Page 1190 of 1235 Page 1190 of 1235 ---PAGE BREAK--- Date Printed: 7/7/2015 Product: M145-2276 14. Transport Information SPECIAL TRANSPORT PRECAUTIONS: No Information DOT: CONSUMER COMMODITY IATA: CONSUMER COMMODITY, ID 8000 IMDG: LIMITED QUANTITY UN1950 15. Regulatory Information U.S. Federal Regulations: CERCLA - SARA Hazard Category This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Fire Hazard, Acute Health Hazard, Chronic Health Hazard SARA SECTION 313 This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name CAS-No. m-xylene 108-38-3 TOXIC SUBSTANCES CONTROL ACT This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: No TSCA components exist in this product. U.S. State Regulations: CALIFORNIA PROPOSITION 65 CARCINOGENS WARNING: This product contains a chemical known to the State of California to cause cancer. CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Page 6 / 7 Page 1191 of 1235 Page 1191 of 1235 Page 1191 of 1235 Page 1191 of 1235 ---PAGE BREAK--- Date Printed: 7/7/2015 Product: M145-2276 16. Other Information 7/3/2015 Supersedes Date: Revision Date: 7/5/2015 Reason for revision: No Information Datasheet produced by: Regulatory Department HMIS Ratings: Health: 2 Flammability: 4 Reactivity: 0 Personal Protection: X Volatile Organic Compounds, gr/ltr: 655 Text for GHS Hazard Statements shown in Section 3 describing each ingredient: H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H251 Self-heating: may catch fire. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H331 Toxic if inhaled. H332 Harmful if inhaled. H340 May cause genetic defects. H350 May cause cancer. H372 Causes damage to organs through prolonged or repeated exposure. Icons for GHS Pictograms shown in Section 3 describing each ingredient: GHS02 GHS06 GHS07 GHS08 The information on this sheet corresponds to our present knowledge. It is not a specification and it does not guarantee specific properties. The information is intended to provide general guidance as to health and safety based upon our knowledge of the handling, storage, and use of the product. It is not applicable to unusual or non-standard uses of the product where instructions and recommendations are not followed. Page 7 / 7 Page 1192 of 1235 Page 1192 of 1235 Page 1192 of 1235 Page 1192 of 1235 ---PAGE BREAK--- Page: 1 SAFETY DATA SHEET Revision Date: 09/18/2008 Print Date: 1/8/2009 MSDS Number: R0311762 Zerex® ANTIFREEZE COOLANT 3493 Version: 1.9 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Ashland Regulatory Information Number 1-[PHONE REDACTED] P.O. Box 2219 Telephone [PHONE REDACTED] Columbus, OH 43216 Emergency telephone 1-800-ASHLAND (1-[PHONE REDACTED]) Product name Zerex® ANTIFREEZE COOLANT Product code 3493 Product Use Description No data 2. HAZARDS IDENTIFICATION Emergency Overview Appearance: liquid, green WARNING! MAY AFFECT THE CENTRAL NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. HARMFUL IF SWALLOWED. MAY CAUSE EYE IRRITATION. MAY CAUSE SKIN AND RESPIRATORY TRACT IRRITATION. Potential Health Effects Routes of exposure Skin absorption, Skin contact, Eye Contact, Inhalation, Ingestion Eye contact Can cause eye irritation. include stinging, tearing, redness, and swelling of eyes. Skin contact May cause mild skin irritation. may include redness and burning of skin. Although rare, skin contact with ethylene glycol may cause allergic skin reaction (delayed skin rash which may be followed by blistering, scaling and other skin effects). Passage of this material into the body through the skin is possible, and may add to toxic effects from breathing or swallowing. Ingestion Page 1 / 9 Page 1193 of 1235 Page 1193 of 1235 Page 1193 of 1235 Page 1193 of 1235 ---PAGE BREAK--- Page: 2 SAFETY DATA SHEET Revision Date: 09/18/2008 Print Date: 1/8/2009 MSDS Number: R0311762 Zerex® ANTIFREEZE COOLANT 3493 Version: 1.9 Swallowing this material may be harmful. Liver, kidney and brain damage in humans has resulted from swallowing lethal or near-lethal amounts of ethylene glycol. Inhalation Breathing of vapor or fume is possible. Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. are not expected at air concentrations below the recommended exposure limits, if applicable (see Section Aggravated Medical Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, lung (for example, asthma-like conditions), Liver, Kidney, Exposure to this material may aggravate any preexisting condition sensitive to a decrease in available oxygen, such as chronic lung disease, coronary artery disease or anemias. Signs and of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways), Cough, central nervous system excitation (giddiness, liveliness, light-headed feeling) followed by central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness) and other central nervous system effects, involuntary eye movement, cyanosis (causes blue coloring of the skin and nails from lack of oxygen), lung edema (fluid buildup in the lung tissue), acute kidney failure (sudden slowing or stopping of urine production), liver damage, Convulsions, coma Target Organs Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals:, reproductive effects, kidney damage, liver damage, Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans:, kidney damage, liver damage Carcinogenicity Based on the available information, this material cannot be classified with regard to carcinogenicity. This material is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration (OSHA). Reproductive hazard Page 2 / 9 Page 1194 of 1235 Page 1194 of 1235 Page 1194 of 1235 Page 1194 of 1235 ---PAGE BREAK--- Page: 3 SAFETY DATA SHEET Revision Date: 09/18/2008 Print Date: 1/8/2009 MSDS Number: R0311762 Zerex® ANTIFREEZE COOLANT 3493 Version: 1.9 Ethylene glycol has caused birth defects in animal studies at high oral doses. However, it did not cause harm to the pregnant animal or to the fetus when applied to the skin of the pregnant animal. 3. COMPOSITION/INFORMATION ON INGREDIENTS Components CAS-No. Concentration ETHYLENE GLYCOL 107-21-1 >=90-<=100% INORGANIC SALT NJTS# 254504001-5237 4. FIRST AID MEASURES Eyes If develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention. Skin Remove contaminated clothing. Wash exposed area with soap and water. If persist, seek medical attention. Launder clothing before reuse. Ingestion Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. Inhalation If develop, immediately move individual away from exposure and into fresh air. Seek immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial respiration. If breathing is difficult, administer oxygen. Notes to physician Hazards: Effects of acute ethylene glycol poisoning appear in three fairly distinct stages. The initial stage occurs shortly after exposure, lasts 6-12 hours, and is characterized by central nervous system effects (transient exhilaration, nausea, vomiting, and in severe cases, coma, convulsions, and possible death). The second stage lasts from 12-36 hours after exposure and is initiated by the onset of coma. This phase is Page 3 / 9 Page 1195 of 1235 Page 1195 of 1235 Page 1195 of 1235 Page 1195 of 1235 ---PAGE BREAK--- Page: 4 SAFETY DATA SHEET Revision Date: 09/18/2008 Print Date: 1/8/2009 MSDS Number: R0311762 Zerex® ANTIFREEZE COOLANT 3493 Version: 1.9 characterized by tachycardia, mild hypotension, cyanosis, and in severe cases, pulmonary edema, bronchopneumonia, cardiac enlargement, and congestive failure. The final stage occurs 24-72 post-exposure and is characterized by renal failure, ranging from a mild increase in blood urea nitrogen and creatinine followed by recovery, to complete anuria with acute tubular necrosis that can lead to death. Oxaluria is found in most cases. The most significant laboratory finding in ethylene glycol intoxication is severe metabolic acidosis. Treatment: This product contains ethylene glycol. Ethanol decreases the metabolism of ethylene glycol to toxic metabolites. Ethanol should be administered as soon as possible in cases of severe poisoning since the elimination half-life of ethylene glycol is 3 hours. If medical care will be delayed several hours, give the patient three to four 1-ounce oral "shots" of 86-proof or higher whiskey before or during transport to the hospital. Fomepizole is an effective antagonist of alcohol dehydrogenase, and as such, may be used as an antidote in the treatment of ethylene glycol poisoning. Hemodialysis effectively removes ethylene glycol and its metabolites from the body. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Dry chemical, Alcohol-resistant foam, Carbon dioxide (CO2), Water mist Hazardous combustion products carbon dioxide and carbon monoxide, various hydrocarbons Precautions for fire-fighting Never use welding or cutting torch on or near drum (even empty) because product (even just residue) can ignite explosively.Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). Flammability Class for Flammable Liquids Combustible Liquid Class IIIB 6. ACCIDENTAL RELEASE MEASURES Personal precautions No data Environmental precautions Page 4 / 9 Page 1196 of 1235 Page 1196 of 1235 Page 1196 of 1235 Page 1196 of 1235 ---PAGE BREAK--- Page: 5 SAFETY DATA SHEET Revision Date: 09/18/2008 Print Date: 1/8/2009 MSDS Number: R0311762 Zerex® ANTIFREEZE COOLANT 3493 Version: 1.9 No data Methods for cleaning up Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source, dike area of spill to prevent spreading, pump liquid to salvage tank. Remaining liquid may be taken up on sand, clay, earth, floor absorbent, or other absorbent material and shoveled into containers. 7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Storage Store in a cool, dry, ventilated area, away from incompatible substances. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines ETHYLENE GLYCOL 107-21-1 ACGIH Ceiling Limit Value: 100 mg/m3 Aerosol. General advice These recommendations provide general guidance for handling this product. Personal protective equipment should be selected for individual applications and should consider factors which affect exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities. Exposure controls Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Eye protection Not required under normal conditions of use. Wear splash-proof safety goggles if material could be misted or splashed into eyes. Page 5 / 9 Page 1197 of 1235 Page 1197 of 1235 Page 1197 of 1235 Page 1197 of 1235 ---PAGE BREAK--- Page: 6 SAFETY DATA SHEET Revision Date: 09/18/2008 Print Date: 1/8/2009 MSDS Number: R0311762 Zerex® ANTIFREEZE COOLANT 3493 Version: 1.9 Skin and body protection Wear normal work clothing including long pants, long-sleeved shirts and foot covering to prevent direct contact of the product with the skin. Launder clothing before reuse. If skin irritation develops, contact your facility health and safety professional or your local safety equipment supplier to determine the proper personal protective equipment for your use. Wear resistant gloves such as: Neoprene polyvinyl chloride Nitrile rubber Respiratory protection Respiratory protection is not required under normal conditions of use. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state liquid Form No data Colour green Odour No data Boiling point/boiling range 330.00 °F / 330 760.00 mmHg pH 0.7) 10.7 Flash point 250 °F / 121 °C Evaporation rate No data Explosion limits 3.2 15.3 Vapour pressure 23.33 hPa @ 68 °F / 20 °C Vapour density No data Density (Average) 1.236 g/cm3 @ 60.01 °F / 15.56 °C 9.41 lb/gal @ 60.1 °F / 15.6 °C Solubility soluble in water Partition coefficient: n- octanol/water No data log Pow no data available Autoignition temperature No data 10. STABILITY AND REACTIVITY Stability Page 6 / 9 Page 1198 of 1235 Page 1198 of 1235 Page 1198 of 1235 Page 1198 of 1235 ---PAGE BREAK--- Page: 7 SAFETY DATA SHEET Revision Date: 09/18/2008 Print Date: 1/8/2009 MSDS Number: R0311762 Zerex® ANTIFREEZE COOLANT 3493 Version: 1.9 Stable Conditions to avoid Incompatible products Strong oxidizing agents Hazardous decomposition products carbon dioxide and carbon monoxide, various hydrocarbons Hazardous reactions Product will not undergo hazardous polymerization. Thermal decomposition No data 11. TOXICOLOGICAL INFORMATION Acute oral toxicity ETHYLENE GLYCOL LD 50 Rat: 6,140 mg/kg LD 50 Mouse: 14,600 mg/kg INORGANIC SALT LD 50 Rat: > 500 mg/kg Acute inhalation toxicity ETHYLENE GLYCOL no data available INORGANIC SALT no data available Acute dermal toxicity ETHYLENE GLYCOL LD 50 Rabbit: 10,611 mg/kg INORGANIC SALT LD 50 Rabbit: > 300 mg/kg 12. ECOLOGICAL INFORMATION Aquatic toxicity Acute and Prolonged Toxicity to Fish No data Acute Toxicity to Aquatic Invertebrates Page 7 / 9 Page 1199 of 1235 Page 1199 of 1235 Page 1199 of 1235 Page 1199 of 1235 ---PAGE BREAK--- Page: 8 SAFETY DATA SHEET Revision Date: 09/18/2008 Print Date: 1/8/2009 MSDS Number: R0311762 Zerex® ANTIFREEZE COOLANT 3493 Version: 1.9 No data Environmental fate and pathways No data 13. DISPOSAL CONSIDERATIONS Waste disposal methods Destroy by liquid incineration. Dispose of in accordance with all applicable local, state and federal regulations. For assistance with your waste management needs - including disposal, recycling and waste stream reduction, contact Ashland Distribution's Environmental Services Group at [PHONE REDACTED]. 14. TRANSPORT INFORMATION Dangerous goods descriptions (if indicated above) may not reflect package size, quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. 15. REGULATORY INFORMATION California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer. 1,4-DIOXANE LEAD NICKEL ARSENIC CADMIUM ACETALDEHYDE WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm. LEAD MERCURY CADMIUM Page 8 / 9 Page 1200 of 1235 Page 1200 of 1235 Page 1200 of 1235 Page 1200 of 1235 ---PAGE BREAK--- Page: 9 SAFETY DATA SHEET Revision Date: 09/18/2008 Print Date: 1/8/2009 MSDS Number: R0311762 Zerex® ANTIFREEZE COOLANT 3493 Version: 1.9 SARA Hazard Classification Acute Health Hazard SARA 313 Component(s) ETHYLENE GLYCOL 107-21-1 95.0117% Reportable quantity - Product US. EPA CERCLA Hazardous Substances (40 CFR 302) 5262 lbs Reportable quantity - Components ETHYLENE GLYCOL 107-21-1 5000 lbs INORGANIC SALT NJTS# 254504001-5237 none Health Flammability Reactivity Other HMIS 2* 1 0 NFPA 1 1 0 16. OTHER INFORMATION The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department (1-[PHONE REDACTED]). Page 9 / 9 Page 1201 of 1235 Page 1201 of 1235 Page 1201 of 1235 Page 1201 of 1235 ---PAGE BREAK--- Page: 1 SAFETY DATA SHEET Revision Date: 12/02/2011 Print Date: 8/31/2013 MSDS Number: R0311762 Zerex™ ANTIFREEZE COOLANT 3493 Version: 2.6 Page 1 / 13 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Ashland Regulatory Information Number 1-[PHONE REDACTED] P.O. Box 2219 Telephone [PHONE REDACTED] Columbus, OH 43216 Emergency telephone number 1-800-ASHLAND (1-800-274- 5263) Product name Zerex™ ANTIFREEZE COOLANT Product code 3493 2. HAZARDS IDENTIFICATION Emergency Overview Appearance: liquid, green WARNING! MAY AFFECT THE CENTRAL NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. MAY CAUSE EYE IRRITATION. MAY CAUSE SKIN AND RESPIRATORY TRACT IRRITATION. HARMFUL IF SWALLOWED. Potential Health Effects Exposure routes Inhalation, Skin absorption, Skin contact, Eye Contact, Ingestion Eye contact Can cause eye irritation. include stinging, tearing, redness, and swelling of eyes. Skin contact Can cause skin irritation. may include redness and burning of skin, and other skin damage. Skin absorption of this material (or a component) may be increased through injured skin. Ingestion Swallowing this material may be harmful. Liver, kidney and brain damage in humans has resulted from swallowing lethal or near-lethal amounts of ethylene glycol. Page 1202 of 1235 Page 1202 of 1235 Page 1202 of 1235 Page 1202 of 1235 ---PAGE BREAK--- Page: 2 SAFETY DATA SHEET Revision Date: 12/02/2011 Print Date: 8/31/2013 MSDS Number: R0311762 Zerex™ ANTIFREEZE COOLANT 3493 Version: 2.6 Page 2 / 13 Inhalation Breathing of vapor or mist is possible. Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. are not expected at air concentrations below the recommended exposure limits, if applicable (see Section Aggravated Medical Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, lung (for example, asthma-like conditions), Liver, Kidney, Central nervous system, Exposure to this material may aggravate any preexisting condition sensitive to a decrease in available oxygen, such as chronic lung disease, coronary artery disease or anemias., Individuals with preexisting kidney disorders are more susceptible to hyperkalemia from overexposure to potassium compounds. Signs and of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways), Cough, central nervous system excitation (giddiness, liveliness, light- headed feeling) followed by central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness) and other central nervous system effects, pain in the abdomen and lower back, cyanosis (causes blue coloring of the skin and nails from lack of oxygen), lung edema (fluid buildup in the lung tissue), acute kidney failure (sudden slowing or stopping of urine production), liver damage, Convulsions, coma Target Organs Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals:, reproductive effects, kidney damage, liver damage, central nervous system damage, Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans:, liver damage, kidney damage Carcinogenicity This material is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration (OSHA). Reproductive hazard Ethylene glycol has caused birth defects in animal studies at high oral doses. However, it did not cause harm to the pregnant animal or to the fetus when applied to the skin of the pregnant animal., This material (or a component) has been shown to cause harm to the fetus in laboratory animal studies. Harm Page 1203 of 1235 Page 1203 of 1235 Page 1203 of 1235 Page 1203 of 1235 ---PAGE BREAK--- Page: 3 SAFETY DATA SHEET Revision Date: 12/02/2011 Print Date: 8/31/2013 MSDS Number: R0311762 Zerex™ ANTIFREEZE COOLANT 3493 Version: 2.6 Page 3 / 13 to the fetus occurs only at exposure levels that harm the pregnant animal. The relevance of these findings to humans is uncertain. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Components CAS-No. / Trade Secret No. Concentration ETHYLENE GLYCOL 107-21-1 >=90-<=100% DIETHYLENE GLYCOL 111-46-6 DIPOTASSIUM PHOSPHATE 7758-11-4 4. FIRST AID MEASURES Eyes If develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention. Skin Remove contaminated clothing. Flush exposed area with large amounts of water. If skin is damaged, seek immediate medical attention. If skin is not damaged and persist, seek medical attention. Launder clothing before reuse. Ingestion Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. Inhalation If develop, move individual away from exposure and into fresh air. If persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention. Notes to physician Page 1204 of 1235 Page 1204 of 1235 Page 1204 of 1235 Page 1204 of 1235 ---PAGE BREAK--- Page: 4 SAFETY DATA SHEET Revision Date: 12/02/2011 Print Date: 8/31/2013 MSDS Number: R0311762 Zerex™ ANTIFREEZE COOLANT 3493 Version: 2.6 Page 4 / 13 Hazards: Effects of acute ethylene glycol poisoning appear in three fairly distinct stages. The initial stage occurs shortly after exposure, lasts 6-12 hours, and is characterized by central nervous system effects (transient exhilaration, nausea, vomiting, and in severe cases, coma, convulsions, and possible death). The second stage lasts from 12-36 hours after exposure and is initiated by the onset of coma. This phase is characterized by tachycardia, mild hypotension, cyanosis, and in severe cases, pulmonary edema, bronchopneumonia, cardiac enlargement, and congestive failure. The final stage occurs 24-72 post-exposure and is characterized by renal failure, ranging from a mild increase in blood urea nitrogen and creatinine followed by recovery, to complete anuria with acute tubular necrosis that can lead to death. Oxaluria is found in most cases. The most significant laboratory finding in ethylene glycol intoxication is severe metabolic acidosis. Ingestion or other significant exposure to this material (or a component) may cause metabolic acidosis. Excessive levels of phosphorus can cause low blood calcium, with tetany and convulsions. Treatment: This product contains ethylene glycol. Ethanol decreases the metabolism of ethylene glycol to toxic metabolites. Ethanol should be administered as soon as possible in cases of severe poisoning since the elimination half-life of ethylene glycol is 3 hours. If medical care will be delayed several hours, give the patient three to four 1-ounce oral "shots" of 86-proof or higher whiskey before or during transport to the hospital. Fomepizole is an effective antagonist of alcohol dehydrogenase, and as such, may be used as an antidote in the treatment of ethylene glycol poisoning. Hemodialysis effectively removes ethylene glycol and its metabolites from the body. Fomepizole is an effective antagonist of alcohol dehydrogenase, and as such, may be used as an antidote in the treatment of ethylene glycol, diethylene glycol and methanol poisoning. 5. FIREFIGHTING MEASURES Suitable extinguishing media Dry chemical, Carbon dioxide (CO2), Water spray Hazardous combustion products Alcohols, Aldehydes, carbon dioxide and carbon monoxide, ethers, Hydrocarbons, Oxides of phosphorus, potassium oxide, toxic fumes Precautions for fire-fighting Never use welding or cutting torch on or near drum (even empty) because product (even just residue) can ignite explosively.Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). DO NOT direct a solid stream of water or foam into hot, burning pools of liquid since this may cause frothing and increase fire intensity. Frothing can be violent and possibly endanger any firefighter standing too close to the burning liquid. Use water spray to cool fire exposed containers Page 1205 of 1235 Page 1205 of 1235 Page 1205 of 1235 Page 1205 of 1235 ---PAGE BREAK--- Page: 5 SAFETY DATA SHEET Revision Date: 12/02/2011 Print Date: 8/31/2013 MSDS Number: R0311762 Zerex™ ANTIFREEZE COOLANT 3493 Version: 2.6 Page 5 / 13 and structures until fire is out if it can be done with minimal risk. Avoid spreading burning material with water used for cooling purposes. NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB 6. ACCIDENTAL RELEASE MEASURES Personal precautions For personal protection see section 8. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions Prevent spreading over a wide area (e.g. by containment or oil barriers). Do not let product enter drains. Do not flush into surface water or sanitary sewer system. Methods for cleaning up Keep in suitable, closed containers for disposal. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Other information Comply with all applicable federal, state, and local regulations. 7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Storage Store in a cool, dry, ventilated area. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Page 1206 of 1235 Page 1206 of 1235 Page 1206 of 1235 Page 1206 of 1235 ---PAGE BREAK--- Page: 6 SAFETY DATA SHEET Revision Date: 12/02/2011 Print Date: 8/31/2013 MSDS Number: R0311762 Zerex™ ANTIFREEZE COOLANT 3493 Version: 2.6 Page 6 / 13 ETHYLENE GLYCOL 107-21-1 ACGIH Ceiling Limit Value: 100 mg/m3 Aerosol. General advice These recommendations provide general guidance for handling this product. Personal protective equipment should be selected for individual applications and should consider factors which affect exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities. Exposure controls Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Eye protection Wear chemical splash goggles when there is the potential for exposure of the eyes to liquid, vapor or mist. Skin and body protection Wear resistant gloves such as: Neoprene polyvinyl chloride Nitrile rubber Wear normal work clothing including long pants, long-sleeved shirts and foot covering to prevent direct contact of the product with the skin. Launder clothing before reuse. If skin irritation develops, contact your facility health and safety professional or your local safety equipment supplier to determine the proper personal protective equipment for your use. Discard gloves that show tears, pinholes, or signs of wear. Respiratory protection A NIOSH-approved air-purifying respirator with an appropriate cartridge and/or filter may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits (if applicable) or if overexposure has otherwise been determined. Protection provided by air- purifying respirators is limited. Use a positive pressure, air-supplied respirator if there is any potential for uncontrolled release, exposure levels are not known or any other circumstances where an air- purifying respirator may not provide adequate protection. Page 1207 of 1235 Page 1207 of 1235 Page 1207 of 1235 Page 1207 of 1235 ---PAGE BREAK--- Page: 7 SAFETY DATA SHEET Revision Date: 12/02/2011 Print Date: 8/31/2013 MSDS Number: R0311762 Zerex™ ANTIFREEZE COOLANT 3493 Version: 2.6 Page 7 / 13 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state liquid Colour green Boiling point/boiling range 330 °F / 166 °C @ 760.00 mmHg pH 0.7) 10.7 Flash point > 250 °F / > 121 °C Lower explosion limit/Upper explosion limit 3.2 / 15.3 Vapour pressure 23.333 hPa @ 68 °F / 20 °C Calculated Vapor Pressure Density (Average) 1.236 g/cm3 @ 60.01 °F / 15.56 °C 9.41 lb/gal @ 60.1 °F / 15.6 °C Water solubility soluble 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid None known. Incompatible products Acids, Aldehydes, Alkali metals, Alkaline earth metals, Bases, Heavy metals, strong alkalis, Strong oxidizing agents, Sulphur compounds Hazardous decomposition products Alcohols, Aldehydes, carbon dioxide and carbon monoxide, ethers, Hydrocarbons, Organic acids, Oxides of phosphorus, potassium oxide, ketones Hazardous reactions Product will not undergo hazardous polymerization. Page 1208 of 1235 Page 1208 of 1235 Page 1208 of 1235 Page 1208 of 1235 ---PAGE BREAK--- Page: 8 SAFETY DATA SHEET Revision Date: 12/02/2011 Print Date: 8/31/2013 MSDS Number: R0311762 Zerex™ ANTIFREEZE COOLANT 3493 Version: 2.6 Page 8 / 13 11. TOXICOLOGICAL INFORMATION Acute oral toxicity Acute oral toxicity - Product : no data available Acute oral toxicity - Components ETHYLENE GLYCOL : LD 50: 6,140 mg/kg Species: Rat DIETHYLENE GLYCOL : LD 50: 12,565 mg/kg Species: Rat DIPOTASSIUM PHOSPHATE : LD50: > 2,000 mg/kg Species: Rat Acute inhalation toxicity Acute inhalation toxicity - Product : no data available Acute inhalation toxicity - Components DIETHYLENE GLYCOL : LC Lo: 130 mg/m3 Exposure time: 2 h Species: Mouse Acute dermal toxicity Acute dermal toxicity - Product : no data available Acute dermal toxicity - Components ETHYLENE GLYCOL : LD 50: 9,530 mg/kg Species: Rabbit DIETHYLENE GLYCOL : LD 50: 11,890 mg/kg Species: Rabbit DIPOTASSIUM PHOSPHATE : LD 50: > 5,000 mg/kg Species: Rabbit Method: OECD Test Guideline 402 Acute toxicity (other routes of administration) Acute toxicity (other routes of administration) : no data available 12. ECOLOGICAL INFORMATION Biodegradability Page 1209 of 1235 Page 1209 of 1235 Page 1209 of 1235 Page 1209 of 1235 ---PAGE BREAK--- Page: 9 SAFETY DATA SHEET Revision Date: 12/02/2011 Print Date: 8/31/2013 MSDS Number: R0311762 Zerex™ ANTIFREEZE COOLANT 3493 Version: 2.6 Page 9 / 13 Biodegradability - Product : no data available Biodegradability - Components DIETHYLENE GLYCOL : 92 % Bioaccumulation Bioaccumulation - Product : no data available Bioaccumulation - Components ETHYLENE GLYCOL : Species: Crayfish (Procambarus) Exposure time: 61 d Concentration: 1,000 mg/l Bioconcentration factor (BCF): 0.27 Method: Flow through Ecotoxicity effects Toxicity to fish Toxicity to fish - Product : no data available Toxicity to fish - Components ETHYLENE GLYCOL : LC 50: 27,540 mg/l Exposure time: 96 h Species: Bluegill (Lepomis macrochirus) Method: Static Remarks: Mortality LC 50: 8,050 mg/l Exposure time: 96 h Species: Fathead minnow (Pimephales promelas) Remarks: Mortality DIETHYLENE GLYCOL : LC 50: > 32,000 mg/l Exposure time: 96 h Species: Western mosquitofish (Gambusia affinis) Method: Static Remarks: Mortality Toxicity to daphnia and other aquatic invertebrates. Toxicity to daphnia and other aquatic invertebrates. : no data available Page 1210 of 1235 Page 1210 of 1235 Page 1210 of 1235 Page 1210 of 1235 ---PAGE BREAK--- Page: 10 SAFETY DATA SHEET Revision Date: 12/02/2011 Print Date: 8/31/2013 MSDS Number: R0311762 Zerex™ ANTIFREEZE COOLANT 3493 Version: 2.6 Page 10 / 13 - Product Toxicity to daphnia and other aquatic invertebrates. - Components ETHYLENE GLYCOL : LC 50: > 10,000 mg/l Exposure time: 48 h Species: Water flea (Daphnia magna) Method: Static Remarks: Mortality DIETHYLENE GLYCOL : LC 50: > 10,000 mg/l Exposure time: 24 h Species: Water flea (Daphnia magna) Method: Static Remarks: Mortality Toxicity to algae Toxicity to algae - Product : no data available Toxicity to bacteria Toxicity to bacteria - Product : no data available 13. DISPOSAL CONSIDERATIONS Waste disposal methods Dispose of in accordance with all applicable local, state and federal regulations. 14. TRANSPORT INFORMATION REGULATION Page 1211 of 1235 Page 1211 of 1235 Page 1211 of 1235 Page 1211 of 1235 ---PAGE BREAK--- Page: 11 SAFETY DATA SHEET Revision Date: 12/02/2011 Print Date: 8/31/2013 MSDS Number: R0311762 Zerex™ ANTIFREEZE COOLANT 3493 Version: 2.6 Page 11 / 13 ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP MARINE POLLUTANT / LTD. QTY. U.S. DOT - ROAD Not dangerous goods U.S. DOT - RAIL Not dangerous goods U.S. DOT - INLAND WATERWAYS Not dangerous goods TRANSPORT CANADA - ROAD Not dangerous goods TRANSPORT CANADA - RAIL Not dangerous goods TRANSPORT CANADA - INLAND WATERWAYS Not dangerous goods INTERNATIONAL MARITIME DANGEROUS GOODS Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER Not dangerous goods MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTES Not dangerous goods *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. Page 1212 of 1235 Page 1212 of 1235 Page 1212 of 1235 Page 1212 of 1235 ---PAGE BREAK--- Page: 12 SAFETY DATA SHEET Revision Date: 12/02/2011 Print Date: 8/31/2013 MSDS Number: R0311762 Zerex™ ANTIFREEZE COOLANT 3493 Version: 2.6 Page 12 / 13 15. REGULATORY INFORMATION California Prop. 65 Proposition 65 warnings are not required for this product based on the results of a risk assessment. SARA Hazard Classification SARA 311/312 Classification Acute Health Hazard SARA 313 Component(s) ETHYLENE GLYCOL 95.01 % New Jersey RTK Label Information ETHYLENE GLYCOL 107-21-1 DIETHYLENE GLYCOL 111-46-6 WATER 7732-18-5 DIPOTASSIUM PHOSPHATE 7758-11-4 RTK Label Information ETHYLENE GLYCOL 107-21-1 DIETHYLENE GLYCOL 111-46-6 Notification status US. Toxic Substances Control Act y (positive listing) Australia. Industrial Chemical (Notification and Assessment) Act y (positive listing) Canada. Canadian Environmental Protection Act (CEPA). Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133) y (positive listing) Japan. Kashin-Hou Law List n (Negative listing) Korea. Toxic Chemical Control Law (TCCL) List y (positive listing) Philippines. The Toxic Substances and Hazardous and Nuclear y (positive listing) Page 1213 of 1235 Page 1213 of 1235 Page 1213 of 1235 Page 1213 of 1235 ---PAGE BREAK--- Page: 13 SAFETY DATA SHEET Revision Date: 12/02/2011 Print Date: 8/31/2013 MSDS Number: R0311762 Zerex™ ANTIFREEZE COOLANT 3493 Version: 2.6 Page 13 / 13 Waste Control Act China. Inventory of Existing Chemical Substances y (positive listing) New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand n (Negative listing) Reportable quantity - Product US. EPA CERCLA Hazardous Substances (40 CFR 302) 5262 lbs Reportable quantity-Components ETHYLENE GLYCOL 107-21-1 5000 lbs HMIS NFPA Health 2* 1 Flammability 1 1 Physical hazards 0 Instability 0 Specific Hazard 16. OTHER INFORMATION The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department (1-[PHONE REDACTED]). Page 1214 of 1235 Page 1214 of 1235 Page 1214 of 1235 Page 1214 of 1235 ---PAGE BREAK--- Page: 1 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 10/7/2014 MSDS Number: 000000139197 Zerex™ ANTIFREEZE COOLANT 3493 Version: 1.4 Page 1 / 12 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Ashland Regulatory Information Number 1-[PHONE REDACTED] P.O. Box 2219 Telephone [PHONE REDACTED] Columbus, OH 43216 Emergency telephone number 1-800-ASHLAND (1-[PHONE REDACTED]) Product name Zerex™ ANTIFREEZE COOLANT Product code 3493 2. HAZARDS IDENTIFICATION Emergency Overview Appearance: liquid, green WARNING! MAY AFFECT THE CENTRAL NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. MAY CAUSE EYE IRRITATION. HARMFUL IF SWALLOWED. Potential Health Effects Exposure routes Inhalation, Skin absorption, Skin contact, Eye Contact, Ingestion Eye contact Can cause eye irritation. include stinging, tearing, redness, and swelling of eyes. Skin contact May cause slight skin irritation. Skin absorption of this material (or a component) may be increased through injured skin. Ingestion Swallowing this material may be harmful. Liver, kidney and brain damage in humans has resulted from swallowing lethal or near-lethal amounts of ethylene glycol. Inhalation It is possible to breathe this material under certain conditions of handling and use (for example, during heating, spraying, or stirring). Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. are not expected at air concentrations below the recommended exposure limits, if applicable (see Section Aggravated Medical Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, Skin, lung (for example, asthma-like conditions), Liver, Kidney, Central nervous system, Exposure to this material may aggravate any preexisting condition sensitive to a decrease in available oxygen, such as chronic lung disease, coronary artery disease or anemias. Page 1215 of 1235 Page 1215 of 1235 Page 1215 of 1235 Page 1215 of 1235 ---PAGE BREAK--- Page: 2 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 10/7/2014 MSDS Number: 000000139197 Zerex™ ANTIFREEZE COOLANT 3493 Version: 1.4 Page 2 / 12 Signs and of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways), Cough, central nervous system excitation (giddiness, liveliness, light-headed feeling) followed by central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness) and other central nervous system effects, involuntary eye movement, pain in the abdomen and lower back, cyanosis (causes blue coloring of the skin and nails from lack of oxygen), lung edema (fluid buildup in the lung tissue), acute kidney failure (sudden slowing or stopping of urine production), liver damage, Convulsions, coma Target Organs Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals:, reproductive effects, effects on male fertility, testis damage, kidney damage, liver damage, central nervous system damage, Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans:, liver damage, kidney damage Carcinogenicity This material is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration (OSHA).This material is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration (OSHA). Reproductive hazard Ethylene glycol has caused birth defects in animal studies at high oral doses. However, it did not cause harm to the pregnant animal or to the fetus when applied to the skin of the pregnant animal., This material (or a component) has been shown to cause harm to the fetus in laboratory animal studies. Harm to the fetus occurs only at exposure levels that harm the pregnant animal. The relevance of these findings to humans is uncertain.Ethylene glycol has caused birth defects in animal studies at high oral doses. However, it did not cause harm to the pregnant animal or to the fetus when applied to the skin of the pregnant animal., This material (or a component) has been shown to cause harm to the fetus in laboratory animal studies. Harm to the fetus occurs only at exposure levels that harm the pregnant animal. The relevance of these findings to humans is uncertain., This material (or a component) has been shown to cause harm to the fetus in laboratory animal studies. The relevance of these findings to humans is uncertain. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Components CAS-No. / Trade Secret No. Concentration ETHYLENE GLYCOL 107-21-1 >=90-<=100% DIETHYLENE GLYCOL 111-46-6 DISODIUM TETRABORATE 1330-43-4 4. FIRST AID MEASURES Page 1216 of 1235 Page 1216 of 1235 Page 1216 of 1235 Page 1216 of 1235 ---PAGE BREAK--- Page: 3 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 10/7/2014 MSDS Number: 000000139197 Zerex™ ANTIFREEZE COOLANT 3493 Version: 1.4 Page 3 / 12 Eyes If develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention. Skin Remove contaminated clothing. Wash exposed area with soap and water. If persist, seek medical attention. Launder clothing before reuse. Ingestion Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. Inhalation If develop, immediately move individual away from exposure and into fresh air. Seek immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial respiration. If breathing is difficult, administer oxygen. Notes to physician Hazards: Effects of acute ethylene glycol poisoning appear in three fairly distinct stages. The initial stage occurs shortly after exposure, lasts 6-12 hours, and is characterized by central nervous system effects (transient exhilaration, nausea, vomiting, and in severe cases, coma, convulsions, and possible death). The second stage lasts from 12-36 hours after exposure and is initiated by the onset of coma. This phase is characterized by tachycardia, mild hypotension, cyanosis, and in severe cases, pulmonary edema, bronchopneumonia, cardiac enlargement, and congestive failure. The final stage occurs 24-72 post-exposure and is characterized by renal failure, ranging from a mild increase in blood urea nitrogen and creatinine followed by recovery, to complete anuria with acute tubular necrosis that can lead to death. Oxaluria is found in most cases. The most significant laboratory finding in ethylene glycol intoxication is severe metabolic acidosis. Ingestion or other significant exposure to this material (or a component) may cause metabolic acidosis. Treatment: This product contains ethylene glycol. Ethanol decreases the metabolism of ethylene glycol to toxic metabolites. Ethanol should be administered as soon as possible in cases of severe poisoning since the elimination half-life of ethylene glycol is 3 hours. If medical care will be delayed several hours, give the patient three to four 1-ounce oral "shots" of 86-proof or higher whiskey before or during transport to the hospital. Fomepizole is an effective antagonist of alcohol dehydrogenase, and as such, may be used as an antidote in the treatment of ethylene glycol poisoning. Hemodialysis effectively removes ethylene glycol and its metabolites from the body. Fomepizole is an effective antagonist of alcohol dehydrogenase, and as such, may be used as an antidote in the treatment of ethylene glycol, diethylene glycol and methanol poisoning. 5. FIREFIGHTING MEASURES Suitable extinguishing media Dry chemical, Carbon dioxide (CO2), Water spray Hazardous combustion products Alcohols, Aldehydes, carbon dioxide and carbon monoxide, ethers, Hydrocarbons, toxic fumes Precautions for fire-fighting Page 1217 of 1235 Page 1217 of 1235 Page 1217 of 1235 Page 1217 of 1235 ---PAGE BREAK--- Page: 4 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 10/7/2014 MSDS Number: 000000139197 Zerex™ ANTIFREEZE COOLANT 3493 Version: 1.4 Page 4 / 12 Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). DO NOT direct a solid stream of water or foam into hot, burning pools of liquid since this may cause frothing and increase fire intensity. Frothing can be violent and possibly endanger any firefighter standing too close to the burning liquid. Use water spray to cool fire exposed containers and structures until fire is out if it can be done with minimal risk. Avoid spreading burning material with water used for cooling purposes. NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB 6. ACCIDENTAL RELEASE MEASURES Personal precautions For personal protection see section 8. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions Prevent spreading over a wide area (e.g. by containment or oil barriers). Do not let product enter drains. Do not flush into surface water or sanitary sewer system. Methods for cleaning up Keep in suitable, closed containers for disposal. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Other information Comply with all applicable federal, state, and local regulations. 7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Storage Store in a cool, dry, ventilated area. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines ETHYLENE GLYCOL 107-21-1 CAD BC OEL time weighted average 10 mg/m3 Particulate. CAD BC OEL Ceiling Limit Value: 50 ppm Vapor. CAD BC OEL Ceiling Limit Value: 100 mg/m3 Aerosol. CAD BC OEL Short term exposure limit 20 mg/m3 Particulate. OEL (QUE) Ceiling Limit Value: 50 ppm Vapor and mist. OEL (QUE) Ceiling Limit Value: 127 mg/m3 Vapor and mist. Page 1218 of 1235 Page 1218 of 1235 Page 1218 of 1235 Page 1218 of 1235 ---PAGE BREAK--- Page: 5 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 10/7/2014 MSDS Number: 000000139197 Zerex™ ANTIFREEZE COOLANT 3493 Version: 1.4 Page 5 / 12 CAD AB OEL Ceiling Limit Value: 100 mg/m3 CAD MB OEL Ceiling Limit Value: 100 mg/m3 Aerosol. CAD ON OEL Ceiling Limit Value: 100 mg/m3 Aerosol. General advice These recommendations provide general guidance for handling this product. Personal protective equipment should be selected for individual applications and should consider factors which affect exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities. Exposure controls Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Eye protection Wear chemical splash goggles when there is the potential for exposure of the eyes to liquid, vapor or mist. Skin and body protection Wear normal work clothing including long pants, long-sleeved shirts and foot covering to prevent direct contact of the product with the skin. Launder clothing before reuse. If skin irritation develops, contact your facility health and safety professional or your local safety equipment supplier to determine the proper personal protective equipment for your use. Wear resistant gloves (consult your safety equipment supplier). Respiratory protection Respiratory protection is not required under normal conditions of use. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state liquid Colour green Boiling point/boiling range 387.7 °F / 197.6 °C @ 1,013.23 hPa Calculated Phase Transition Liquid/Gas pH 9 - < 11 Flash point > 232 °F / > 111 °C Lower explosion limit/Upper explosion limit 3.2 / 15.3 Calculated Explosive Limit Vapour pressure 0.122 hPa @ 77 °F / 25 °C Calculated Vapor Pressure Density 1.1205 g/cm3 @ 60.1 °F / 15.6 °C 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid Page 1219 of 1235 Page 1219 of 1235 Page 1219 of 1235 Page 1219 of 1235 ---PAGE BREAK--- Page: 6 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 10/7/2014 MSDS Number: 000000139197 Zerex™ ANTIFREEZE COOLANT 3493 Version: 1.4 Page 6 / 12 Heat, flames and sparks., Exposure to moisture. Incompatible products Acids, Aldehydes, Alkali metals, Alkaline earth metals, aluminum, Bases, strong alkalis, Strong oxidizing agents, Sulphur compounds Hazardous decomposition products Alcohols, Aldehydes, carbon dioxide and carbon monoxide, ethers, Hydrocarbons, Organic acids, ketones Hazardous reactions Product will not undergo hazardous polymerization. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation Skin absorption Skin contact Eye Contact Ingestion Product Acute oral toxicity : no data available Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Skin corrosion/irritation : no data available Serious eye damage/eye irritation : no data available Respiratory or skin sensitisation : no data available Target Organ Systemic Toxicant - Repeated Exposure : Target Organs: Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals:, reproductive effects, effects on male fertility, testis damage, kidney damage, liver damage, central nervous system damage, Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans:, liver damage, kidney damage Page 1220 of 1235 Page 1220 of 1235 Page 1220 of 1235 Page 1220 of 1235 ---PAGE BREAK--- Page: 7 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 10/7/2014 MSDS Number: 000000139197 Zerex™ ANTIFREEZE COOLANT 3493 Version: 1.4 Page 7 / 12 Components: ETHYLENE GLYCOL: Acute oral toxicity : LD 50 Rat: 6,140 mg/kg Acute dermal toxicity : LD 50 Rabbit: 9,530 mg/kg STOT - repeated exposure : Exposure routes: Ingestion Target Organs: Kidney, Liver Assessment: May cause damage to organs through prolonged or repeated exposure. DIETHYLENE GLYCOL: Acute oral toxicity : LD 50 Rat: 12,565 mg/kg Acute inhalation toxicity : LC Lo Mouse: 130 mg/m3 Exposure time: 2 h Acute dermal toxicity : LD 50 Rabbit: 11,890 mg/kg Experience with human exposure : Liver DISODIUM TETRABORATE Acute oral toxicity : LD50 rat: 1,200 mg/kg Acute dermal toxicity : LD 50 Rabbit: > 1,055 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity Product: no data available Components: ETHYLENE GLYCOL: Toxicity to fish : LC 50 (Bluegill (Lepomis macrochirus)): 27,540 mg/l Exposure time: 96 h Method: Static Mortality Page 1221 of 1235 Page 1221 of 1235 Page 1221 of 1235 Page 1221 of 1235 ---PAGE BREAK--- Page: 8 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 10/7/2014 MSDS Number: 000000139197 Zerex™ ANTIFREEZE COOLANT 3493 Version: 1.4 Page 8 / 12 LC 50 (Fathead minnow (Pimephales promelas)): 8,050 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : LC 50 (Water flea (Daphnia magna)): > 10,000 mg/l Exposure time: 48 h Test Method: static test DIETHYLENE GLYCOL: Toxicity to fish : LC 50 (Western mosquitofish (Gambusia affinis)): > 32,000 mg/l Exposure time: 96 h Method: Static Mortality Toxicity to daphnia and other aquatic invertebrates : LC 50 (Water flea (Daphnia magna)): > 10,000 mg/l Exposure time: 24 h Method: Static Mortality Persistence and degradability Product: no data available Components: DIETHYLENE GLYCOL: Biodegradability : Biodegradation: 92 % Exposure time: 28 d Bioaccumulative potential Product: no data available Components: ETHYLENE GLYCOL: Bioaccumulation : Species: Crayfish (Procambarus) Exposure time: 61 d Concentration: 1000 mg/l Bioconcentration factor (BCF): 0.27 Method: Flow through Page 1222 of 1235 Page 1222 of 1235 Page 1222 of 1235 Page 1222 of 1235 ---PAGE BREAK--- Page: 9 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 10/7/2014 MSDS Number: 000000139197 Zerex™ ANTIFREEZE COOLANT 3493 Version: 1.4 Page 9 / 12 Partition coefficient: n- octanol/water : log Pow: -1.36 DIETHYLENE GLYCOL: Partition coefficient: n- octanol/water : log Pow: -1.47 Mobility in soil Product: no data available Components: ETHYLENE GLYCOL: Surface tension : 48.4 mN/m DIETHYLENE GLYCOL: Surface tension : 48.5 mN/m 13. DISPOSAL CONSIDERATIONS Waste disposal methods Dispose of in accordance with all applicable local, state and federal regulations. 14. TRANSPORT INFORMATION REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP MARINE POLLUTANT / LTD. QTY. U.S. DOT - ROAD Not dangerous goods U.S. DOT - RAIL Not dangerous goods U.S. DOT - INLAND WATERWAYS Not dangerous goods TRANSPORT CANADA - ROAD Page 1223 of 1235 Page 1223 of 1235 Page 1223 of 1235 Page 1223 of 1235 ---PAGE BREAK--- Page: 10 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 10/7/2014 MSDS Number: 000000139197 Zerex™ ANTIFREEZE COOLANT 3493 Version: 1.4 Page 10 / 12 Not dangerous goods TRANSPORT CANADA - RAIL Not dangerous goods TRANSPORT CANADA - INLAND WATERWAYS Not dangerous goods INTERNATIONAL MARITIME DANGEROUS GOODS Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER Not dangerous goods MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTES Not dangerous goods *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. 15. REGULATORY INFORMATION WHMIS Classification D1B Toxic Material Causing Immediate and Serious Toxic Effects D2A Very Toxic Material Causing Other Toxic Effects D2B Toxic Material Causing Other Toxic Effects WHMIS Ingredient Disclosure List IDL: No component is listed on the WHMIS ingredients disclosure list. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. Canadian National Pollutant Release Inventory (NPRI) ETHYLENE GLYCOL 95.75 % Page 1224 of 1235 Page 1224 of 1235 Page 1224 of 1235 Page 1224 of 1235 ---PAGE BREAK--- Page: 11 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 10/7/2014 MSDS Number: 000000139197 Zerex™ ANTIFREEZE COOLANT 3493 Version: 1.4 Page 11 / 12 Notification status US. Toxic Substances Control Act y (positive listing) Canada. Canadian Environmental Protection Act (CEPA). Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133) y (positive listing) Australia. Industrial Chemical (Notification and Assessment) Act y (positive listing) Japan. ENCS - Existing and New Chemical Substances Inventory n (Negative listing) Korea. Toxic Chemical Control Law (TCCL) List y (positive listing) Philippines. The Toxic Substances and Hazardous and Nuclear Waste Control Act y (positive listing) China. Inventory of Existing Chemical Substances y (positive listing) HMIS NFPA Health 1* 1 Flammability 1 1 Physical hazards 0 Instability 0 Specific Hazard 16. OTHER INFORMATION The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department (1-[PHONE REDACTED]). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the “International Air Transport Association” (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the “International Civil Aviation Organization” IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified Page 1225 of 1235 Page 1225 of 1235 Page 1225 of 1235 Page 1225 of 1235 ---PAGE BREAK--- Page: 12 SAFETY DATA SHEET Revision Date: 09/06/2013 Print Date: 10/7/2014 MSDS Number: 000000139197 Zerex™ ANTIFREEZE COOLANT 3493 Version: 1.4 Page 12 / 12 OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System Page 1226 of 1235 Page 1226 of 1235 Page 1226 of 1235 Page 1226 of 1235 ---PAGE BREAK--- Zip-Strip Aerosol Paint and Finish Remover Not available. Not applicable. Not available. Not applicable. 33-560ZIPEXP Not available. Recochem Inc. Communications and Regulatory Affairs Department (905) 878-5544 Recochem Inc. 850 Montee de Liesse Montreal, Quebec H4T 1P4 (514) 341-3550 www.recochem.com Class B-5: Flammable aerosol. Material Safety Data Sheet WHMIS (Pictograms) WHMIS (Classification) Personal protective equipment Section 1. Product and Company Identification Product name / Trade name Synonym Chemical family Chemical formula Manufacturer/Supplier Material uses Associated Product’s Item Code CAS # In case of emergency Print date Validation date 2014-02-03. 2014-02-03. Very hazardous by the following route of exposure: of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation (lung irritant). hazardous by the following route of exposure: of skin contact (corrosive, permeator). Severe over-exposure can result in death. Inflammation of the eye is characterized by redness, watering and itching. Skin inflammation is characterized by itching, scaling, reddening or, occasionally, blistering. Not available. Section 2. Hazards identification Potential Acute Health Effects Note to Physician Emergency Overview May be harmful if swallowed. Avoid exposure - obtain special instructions before use. Do not breathe vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. May cause target organ damage, based on animal data. Contains material which can cause cancer. Risk of cancer depends on duration and level of exposure. Wash thoroughly after handling. CAUTION! MAY BE HARMFUL IF SWALLOWED. MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. CANCER HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE CANCER. See section 11 for more detailed information on health effects and Section 3. Composition, information on ingredients Canada Name CAS number Conc. w/w) Continued on next page Page 1227 of 1235 Page 1227 of 1235 Page 1227 of 1235 Page 1227 of 1235 Zip-Strip Premium Paint & Finish Remover 33-560ZIPEXP Feb. 03 2014 Feb. 03 2014 ---PAGE BREAK--- Zip-Strip Aerosol Paint and Finish Remover Page: 2/9 Validated on 2014-02-03. There are no other ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Methylene Chloride 75-09-2 45 - 55 Methanol 67-56-1 9 - 13 Toluene. 108-88-3 9 - 12 Propane 74-98-6 8 - 12 BUTANE 106-97-6 8 - 12 Solvent naphtha (petroleum), medium aliph 64742-88-7 2 - 6 Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 30 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 30 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion Notes to physician No specific treatment. Treat Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Decomposition products may include the following materials: carbon dioxide carbon monoxide halogenated compounds carbonyl halides Use an extinguishing agent suitable for the surrounding fire. Not available. Not available. Section 5. Fire-fighting measures Products of combustion Fire-fighting media and instructions Fire Hazards Explosion Hazards Continued on next page Page 1228 of 1235 Page 1228 of 1235 Page 1228 of 1235 Page 1228 of 1235 Feb. 03 2014 Zip-Strip Premium Paint & Finish Remover ---PAGE BREAK--- Zip-Strip Aerosol Paint and Finish Remover Page: 3/9 Validated on 2014-02-03. Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section 13 for waste disposal. Section 6. Accidental release measures Small spill and leak Large spill and leak Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Use appropriate containment to avoid environmental contamination. Put on appropriate personal protective equipment (see section Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing gas. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Empty containers retain product residue and can be hazardous. Section 7. Handling and Storage Handling Storage Section 8. Exposure controls/personal protection Engineering controls Personal protection Eyes Body Respiratory Hands Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Recommended: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Recommended: Use a properly fitted, air- purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Continued on next page Page 1229 of 1235 Page 1229 of 1235 Page 1229 of 1235 Page 1229 of 1235 Feb. 03 2014 Zip-Strip Premium Paint & Finish Remover ---PAGE BREAK--- Zip-Strip Aerosol Paint and Finish Remover Page: 4/9 Validated on 2014-02-03. Product name Exposure limits United States Methylene Chloride ACGIH TLV (United States, 1/2008). TWA: 50 ppm 8 hour(s). TWA: 174 mg/m³ 8 hour(s). OSHA PEL 1989 (United States, 3/1989). STEL: 125 ppm 15 minute(s). TWA: 25 ppm 8 hour(s). OSHA PEL Z2 (United States, 11/2006). STEL: 125 ppm 15 minute(s). TWA: 25 ppm 8 hour(s). Methanol ACGIH TLV (United States, 1/2008). Absorbed through skin. TWA: 200 ppm 8 hour(s). TWA: 262 mg/m³ 8 hour(s). STEL: 250 ppm 15 minute(s). STEL: 328 mg/m³ 15 minute(s). OSHA PEL 1989 (United States, 3/1989). Absorbed through skin. TWA: 200 ppm 8 hour(s). TWA: 260 mg/m³ 8 hour(s). STEL: 250 ppm 15 minute(s). STEL: 325 mg/m³ 15 minute(s). NIOSH REL (United States, 6/2008). Absorbed through skin. TWA: 200 ppm 10 hour(s). TWA: 260 mg/m³ 10 hour(s). STEL: 250 ppm 15 minute(s). STEL: 325 mg/m³ 15 minute(s). OSHA PEL (United States, 11/2006). TWA: 200 ppm 8 hour(s). TWA: 260 mg/m³ 8 hour(s). OSHA (United States, 2003). TWA: 200 ppm 8 hour(s). TWA: 260 mg/m³ 8 hour(s). Toluene. OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm 8 hour(s). TWA: 375 mg/m³ 8 hour(s). STEL: 150 ppm 15 minute(s). STEL: 560 mg/m³ 15 minute(s). OSHA PEL Z2 (United States, 11/2006). TWA: 200 ppm 8 hour(s). CEIL: 300 ppm AMP: 500 ppm 10 minute(s). NIOSH REL (United States, 6/2008). TWA: 100 ppm 10 hour(s). Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this i necessary. >8 hours (breakthrough time): Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Continued on next page Page 1230 of 1235 Page 1230 of 1235 Page 1230 of 1235 Page 1230 of 1235 Feb. 03 2014 Zip-Strip Premium Paint & Finish Remover ---PAGE BREAK--- Zip-Strip Aerosol Paint and Finish Remover Page: 5/9 Validated on 2014-02-03. TWA: 375 mg/m³ 10 hour(s). STEL: 150 ppm 15 minute(s). STEL: 560 mg/m³ 15 minute(s). ACGIH TLV (United States, 1/2008). TWA: 20 ppm 8 hour(s). Propane ACGIH TLV (United States). TWA: 1000 ppm, 1 times per shift, 8 hour(s). BUTANE ACGIH TLV (United States). TWA: 800 ppm 8 hour(s). Solvent naphtha (petroleum), medium aliph. OSHA (United States, 2003). TWA: 500 ppm 8 hour(s). TWA: 2900 mg/m³ 8 hour(s). [1]Absorbed through skin. Methylene Chloride US ACGIH 1/2008 50 174 - - - - - - - AB 6/2008 50 174 - - - - - - - BC 6/2008 25 - - - - - - - - ON 6/2008 50 175 - - - - - - - QC 6/2008 50 174 - - - - - - - Methanol US ACGIH 1/2008 200 262 - 250 328 - - - - AB 6/2008 200 262 - 250 328 - - - - BC 6/2008 200 - - 250 - - - - - ON 6/2008 200 260 - 250 325 - - - - QC 6/2008 200 262 - 250 328 - - - - Toluene. US ACGIH 1/2008 20 - - - - - - - - AB 6/2008 50 188 - - - - - - - BC 6/2008 20 - - - - - - - - ON 6/2008 50 - - - - - - - - QC 6/2008 50 188 - - - - - - - BUTANE US ACGIH 800 - - - - - - - - Propane 1000 - - - - - - - - Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations Ceiling STEL (15 mins) TWA (8 hours) Occupational exposure limits Not available. Boiling/condensation point Gas. [Aerosol.] 90 to 98% (v/v) Not available. Not available. Not available. Not available. Not available. Not applicable. Not available. Not available. White. [Light] Not available. Not available. Section 9. Physical and chemical properties Physical State and Appearance Molecular weight pH Odour Taste Colour Relative density Vapor pressure Volatility Odour Threshold Viscosity Evaporation rate Melting/freezing point Continued on next page Page 1231 of 1235 Page 1231 of 1235 Page 1231 of 1235 Page 1231 of 1235 Feb. 03 2014 Zip-Strip Premium Paint & Finish Remover ---PAGE BREAK--- Zip-Strip Aerosol Paint and Finish Remover Page: 6/9 Validated on 2014-02-03. >1 [Air = 1] Easily soluble in the following materials: cold water, hot water, methanol, diethyl ether, n-octanol and acetone. Lower: 14% Upper: 25% Not available. Not available. May be combustible at high temperature. Extremely flammable in the presence of the following materials or conditions: open flames, sparks and static discharge and heat. Non-flammable in the presence of the following materials or conditions: shocks and mechanical impacts. Vapour Density Solubility The product is: Auto-ignition temperature Flash point Flammable limits Fire hazards in the presence of various substances VOC content Other Properties Not available. 75.5 % (w/w) The product is stable. Reactive or incompatible with the following materials: oxidizing materials and acids. reactive or incompatible with the following materials: alkalis. Not available. Section 10. Stability and reactivity Stability Conditions of instability Incompatibility with various substances Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. Acute toxicity Chronic toxicity Carcinogenicity Section 11. Toxicological Information Canada Methylene Chloride LC50 Inhalation Vapor Rat 76000 mg/m3 4 hours LD50 Oral Rat 985 mg/kg - Methanol LC50 Inhalation Gas. Rat 64000 ppm 4 hours LD50 Dermal Rabbit 15800 mg/kg - LD50 Dermal Rabbit 15840 mg/kg - LD50 Oral Rat 5600 mg/kg - LD50 Oral Rat 5600 mg/kg - Toluene. LC50 Inhalation Vapor Rat 49 g/m3 4 hours LD50 Oral Rat 636 mg/kg - Solvent naphtha (petroleum), medium aliph. LD50 Oral Rat >5000 mg/kg - Conclusion/Summary Not available. Conclusion/Summary Not available. Continued on next page Page 1232 of 1235 Page 1232 of 1235 Page 1232 of 1235 Page 1232 of 1235 Feb. 03 2014 Zip-Strip Premium Paint & Finish Remover ---PAGE BREAK--- Zip-Strip Aerosol Paint and Finish Remover Page: 7/9 Validated on 2014-02-03. Mutagenicity Conclusion/Summary : Teratogenicity Conclusion/Summary : Reproductive Toxicity Conclusion/Summary : Classification Product/ingredient name ACGIH EPA NIOSH NTP IARC OSHA Methylene Chloride A3 2B - + Possible + Methanol A5 4 - - - None. Toluene. A4 3 - - - - Not available. Not available. Not available. Conclusion/Summary Not available. Section 12. Ecological information For accidental discharges into the environment, see Section 6:"Accidental Release Measures" for suggested instructions. Canada : Aquatic ecotoxicity Product/ingredient name Result Species Exposure Methylene Chloride Acute EC50 99000 to 121500 ug/L Fresh water Fish - Pimephales promelas - 49 mm - 1.04 g 96 hours Acute LC50 108500 to 130900 ug/L Marine water Crustaceans - Palaemonetes pugio - Juvenile (Fledgling, Hatchling, Weanling) - 20 mm 48 hours Acute LC50 220000 to 330000 ug/L Fresh water Daphnia - Daphnia magna - <24 hours 48 hours Chronic NOEC 130 ppm Marine water Fish - Cyprinodon variegatus - Juvenile (Fledgling, Hatchling, Weanling) - 8 to 15 mm 96 hours Methanol Acute LC50 2500000 ug/L Marine water Crustaceans - Crangon crangon - Adult 48 hours Acute LC50 3289 to 4395 mg/L Fresh water Daphnia - Daphnia magna - Neonate - <24 hours 48 hours Acute LC50 >100000 ug/L Fresh water Fish - Pimephales promelas - Juvenile (Fledgling, Hatchling, Weanling) - 0.2 to 0.5 g 96 hours Toluene. Acute EC50 6000 ug/L Fresh water Daphnia - Daphnia magna - Juvenile (Fledgling, Hatchling, Weanling) 48 hours Acute LC50 15500 ug/L Marine water Crustaceans - Palaemonetes pugio 48 hours Acute LC50 5500 ug/L Fresh water Fish - kisutch - 96 hours Ecotoxicity No known significant effects or critical hazards. Continued on next page Page 1233 of 1235 Page 1233 of 1235 Page 1233 of 1235 Page 1233 of 1235 Feb. 03 2014 Zip-Strip Premium Paint & Finish Remover ---PAGE BREAK--- Zip-Strip Aerosol Paint and Finish Remover Page: 8/9 Validated on 2014-02-03. Conclusion/Summary : Biodegradability Conclusion/Summary : Not available. FRY - 1 g Not available. The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non- recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Do not puncture or incinerate container. Waste information Section 13. Disposal considerations Disposal should be in accordance with applicable regional, national and local laws and regulations. Consumer Commodity. Class Not a pollutant. No placard (handling and hazard label) required. Section 14. Transport information Proper Shipping Name (Canada) TDG Special provisions - - Marine pollutant Proper Shipping Name IMDG No placard (handling and hazard label) required. Special provisions Remarks Limited quantity - Subsidiary class - - Class Subsidiary class United States DOT (Classification) IMDG Classification Canada TDG Classification - Not regulated. - UN number Packing Group - Not regulated. UN number Packing Group Continued on next page Page 1234 of 1235 Page 1234 of 1235 Page 1234 of 1235 Page 1234 of 1235 Feb. 03 2014 Zip-Strip Premium Paint & Finish Remover ---PAGE BREAK--- Zip-Strip Aerosol Paint and Finish Remover Page: 9/9 Validated on 2014-02-03. No placard (handling and hazard label) required. ORM-D Special provisions Not available. Proper Shipping Name (United States) DOT Consumer Commodity. - Subsidiary class International Air Transport Association (IATA) For air shipment classification and associated regulations, please refer to the latest edition of IATA Dangerous Goods Regulations. Class Not available. - UN number Packing Group 2 1 1 1 1 2 Compressed gas Carcinogen Target organ effects U.S.A. Regulatory Lists Section 15. Regulatory information HCS Classification Hazardous Material Information System National Fire Protection Association Health Specific hazard Reactivity Flammability Health Flammability Reactivity Personal protection Class B-5: Flammable aerosol. WHMIS Classification (Canada) TSCA 4(a) final test rules: Solvent naphtha (petroleum), medium aliph. United States inventory (TSCA 8b): Not determined. Not determined. Canada Domestic Substances List (DSL) Status Section 16. Other information Validated and verified by Compliance and Technical Information Manager on 2014-02-03 ph.# [PHONE REDACTED]. Printed 2014-02-03. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. MSDS are available at www.recochem.com Page 1235 of 1235 Page 1235 of 1235 Page 1235 of 1235 Page 1235 of 1235 Feb. 03 2014 Zip-Strip Premium Paint & Finish Remover Feb. 03 2014 Feb. 03 2014