Document douglascountywi_gov_doc_60883f5996

Safety Data Sheet Index Binder: Maple Highway Shop - Maple Highway Shop #1 Diesel Sinclair Oil Company 01/23/2015 4 #275 Di-Lex Hydraulic Oil SAE 20 Schaeffer Mfg. Company 04/30/2004 12 +22 Degree F Splash Windshield Washer Fluid Splash Products, Inc. 01/06/2012 14 Aeroshell Grease Shell Oil Company 09/22/2003 19 AJAX CLEANER POWDER-OXYGEN BLEACH Colgate-Palmolive Co - Commerical Consumer Group 05/14/2015 24 Castle Dry Lub Castle Products, Inc. 09/19/2013 34 Castle Thrust Castle Products, Inc. 06/14/2013 37 CITRA CLEAN HAND CLEANER WITH PUMICE Mark V Products 12/31/2005 40 Citra-Blaze 535 Cleaner Degreaser Nyco Products Company 12/17/2012 42 DIESEL FUEL SUPPLEMENT +CETANE BOOST Power Service Products, Inc. 05/30/2015 44 DUST MOP / DUST CLOTH TREATMENT (AEROSOL) Spartan Chemical Company, Inc. 05/01/2015 57 Eagle One ETCHING MAG WHEEL CLEANER Ashland 09/17/2012 62 Eagle One WAX-AS-U-DRY SPRAY WAX Ashland 06/22/2013 76 FARM AND INDUSTRIAL NEW EQUIPMENT YELLOW SEYMOUR OF SYCAMORE 01/02/2007 87 FAST ORANGE SMOOTH LOTION WITH BRUSH 15 FL.OZ ITW Permatex 05/15/2015 91 GERMICIDAL CLEANER Claire Manufacturing Company 03/23/2015 98 GLEME GLASS CLEANER Claire Manufacturing Company 05/26/2015 107 GS RESTROOM CLEANER Spartan Chemical Company, Inc. 05/04/2015 117 Hi-lex Bleah HI-LEX CORP 04/05/1999 122 HOSPECO HEALTH GARDS AIR FRESHENER VINEYARD, 7OZ HOSPECO 03/21/2013 123 Hot Shot Natural Flying Insect Killer CHEMSICO DIV OF UNITED INDUSTRIES CORP 03/11/2015 125 Industrial Gloss Enamel ARROWHEAD PAINT PRODUCTS, INC. 10/01/2007 131 Product Name CAS Number Manufacturer Version Date Page ---PAGE BREAK--- Insect Repellent CRC Industries, Inc. 05/21/2015 134 Ivory Original Liquid Hand Soap Procter & Gamble 02/18/2015 144 Kiwi Select All Protector Rain and Stain Protector Sara Lee Household and Body Care USA 06/09/2003 150 KRYLON Industrial QUIK-MARK Solvent-Based Inverted Marking Paint (Fluorescent), Red Orange THE SHERWIN-WILLIAMS COMPANY - KRYLON INDUSTRIAL PRODUCTS GROUP 05/04/2015 154 No-Ad SPF 50 Sport Sunblock Lotion Sun & Skin Care Research 07/09/2012 160 OFF! DEEP WOODS INSECT REPELLENT VII S.C. Johnson & Son, Inc. 02/24/2015 162 Orange Away Total Solutions 01/08/2015 174 PARTS MASTER PREMIUM POWER STEERING FLUID OMNI Specialty Packaging 01/31/2012 175 PEAK BLUE 13463-67-7 Standridge Color Corporation 08/03/2012 181 POLAR WINDSHIELD WASH & DEICER FLUID -30 Degree F Old World Industries, LLC 10/29/2014 186 PRIME SOURCE SILKY PINK HAND SOAP PRIME SOURCE 04/27/2015 196 Propane 74-98-6 BERNZ-O-MATIC 06/11/2011 208 RAID WASP & HORNET KILLER 33 S.C. Johnson & Son, Inc. 02/23/2015 211 TC Gel Air Neutralizers - All Fragrances Listed Technical Concepts 02/15/2005 225 TWINKLE METAL POLISH & FIBERGLASS CLEANER JohnsonDiversey 04/19/2000 228 UNITED 166 POWER UP United Laboratories Inc. 03/05/2008 232 UNITED 195 SMELL JEL United Laboratories Inc. 12/22/2012 234 UNITED 77 BIATRON United Laboratories Inc. 02/08/2013 236 Unleaded Gasoline - All Grades Silver Eagle Refining, Inc. 05/18/2015 238 White Lithium Grease (aerosol) CRC Industries, Inc. 06/09/2015 253 Xtreme Gleme All Weather Surface Degreaser Claire Manufacturing Company 10/03/2012 260 Product Name CAS Number Manufacturer Version Date Page Page 2 of 262 Page 2 of 262 Page 2 of 262 Page 2 of 262 ---PAGE BREAK--- Safety Data Sheet #1 Diesel SECTION 1 IDENTIFICATION Product Name: #1 Diesel SDS F3.2 Product Use: Fuel Restrictions on Use: Use only as directed Manufacturer: Sinclair Oil Company P.O. Box 30825 Salt Lake City, Utah 84130 Telephone: General Information: (801) 524-2777 Fax: (801) 524-2740 Contact person: Jeremiah Webster Emergency Telephone: [PHONE REDACTED] (CHEMTREC) or (703) 527-3887 SDS Date of Preparation: January 23, 2015 SECTION 2: HAZARDS IDENTIFICATION Classification: Physical Health Flammable Liquid Category 3 Aspiration Toxicity Category 1 Skin Irritation Category 2 Specific Target Organ Toxicity Single Exposure Category 3 (Nervous System) Carcinogen Category 1A Germ Cell Mutagenicity Category 1B Label Elements: Danger! Hazard Phrases: Combustible Liquid. May be fatal if swallowed and enters airways. Causes skin irritation. May cause drowsiness or dizziness. May cause cancer. May cause genetic defects. Precautionary Phrases: Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood Page 3 of 262 Page 3 of 262 Page 3 of 262 Page 3 of 262 ---PAGE BREAK--- Jet A Fuel January 23, 2015 Page 2 of 8 Keep away from heat, sparks, open flames, and hot surfaces. No smoking. Keep container closed. Ground and bond container and receiving equipment Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing vapors, mists or spray. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves, skin protection and eye protection. Response IF SWALLOWED: Immediately call a POISON CENTER or doctor. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. If skin irritation occurs: Get medical attention. Take off contaminated clothing and wash it before reuse. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF exposed or concerned: Get medical attention. In case of fire: Use water fog, carbon dioxide, dry chemical and foam to extinguish. Storage and Disposal Store in a well-ventilated place. Keep container closed. Store locked up. Dispose of contents and container in accordance with local and national regulations. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Chemical name CAS No. Concentration Kerosene 8008-30-6 95-100% Hydrocarbons C7-C9 68920-06-9 0-15% Naphthalene 91-20-3 0-3% Benzene 71-43-2 0-0.2% SECTION 4 EMERGENCY and FIRST AID PROCEDURES Eye Contact: Immediately flush eyes with water for several minutes. Get medical attention if irritation persists. Skin Contact: Remove contaminated clothing and flush skin with water for several minutes. Wash thoroughly with soap and water. Get medical attention if irritation develops or persists. Launder clothing before reuse. Discard contaminated shoes. Inhalation: Remove to fresh air. If breathing is difficult have qualified personnel administer oxygen. If breathing has stopped, administer artificial respiration. Get medical attention. Ingestion: Do not induce vomiting. Rinse mouth with water. Never give anything by mouth to an unconsciousness person. If vomiting occurs spontaneously, keep head below hips to prevent aspiration into the lungs. Get immediate medical attention. Page 4 of 262 Page 4 of 262 Page 4 of 262 Page 4 of 262 ---PAGE BREAK--- Jet A Fuel January 23, 2015 Page 3 of 8 Most important acute and delayed: May cause eye irritation. Causes skin irritation with redness and drying. Inhalation may cause respiratory irritation and central nervous system effects. Harmful or fatal if swallowed. Aspiration during swallowing or vomiting may cause lung damage. May cause cancer. May cause genetic defects. Indication of immediate medical attention and special treatment, if necessary: Immediate medical attention is required for ingestion. SECTION 5 FIRE and EXPLOSION HAZARD DATA Suitable extinguishing media: Use water fog, alcohol foam, carbon dioxide, or dry chemical. Do not use a steady stream of water. Product may float on the surface of water and create a floating fire hazard. Specific hazards arising from the chemical: This product is flammable and forms explosive mixtures with air. Vapors are heavier than air and will travel along surfaces to remote ignition sources and flash back. Closed containers may explode if exposed to extreme heat. Combustion may produce carbon oxides and other products of incomplete combustion. Special protective equipment and precautions for fire-fighters: Firefighters should wear full emergency equipment and a NIOSH approved positive pressure self-contained breathing apparatus. Cool fire exposed container with water. Do not allow run-off from firefighting to enter drains or water courses. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment, and emergency procedures: Wear appropriate protective equipment. Eliminate ignitions sources and ventilate the area with explosion proof equipment. Wash thoroughly after handling. Environmental hazards: Avoid release into the environment. Report spill as required by local and federal regulations. Methods and materials for containment and cleaning up: Contain with an inert absorbent and place into a closable container for disposal. Use non-sparking tools and equipment. If spill has not ignited, use water spray to disperse the vapors and protect personnel attempting to stop leak. Prevent entry in storm sewers and waterways. Runoff can cause a fire or explosion hazard in sewers. SECTION 7 HANDLING and STORAGE Precautions for safe handling: Avoid contact with the eyes, skin and clothing. Avoid breathing vapors or mists. Wear protective clothing and equipment. Use only with adequate ventilation. Wash thoroughly with soap and water after handling. Keep containers closed when not in use. Keep product away from heat, sparks, flames and all other sources of ignition. Do not permit smoking in use or storage areas. Use with non-sparking tools and explosion proof equipment. Electrically bond and ground containers for transfer. Do not cut, drill, grind or weld on or near containers, even empty containers. Do not reuse containers. Empty containers retain product residues which can be hazardous. Follow all SDS precautions when handling empty containers. Refer to OSHA 1910.1028 for requirements for handling and use of benzene. Conditions for safe storage, including any incompatibilities: Store in accordance with regulations for the storage of flammable liquids. Store in a dry, well ventilated area away from heat, direct sunlight and all sources of ignition. Store away from oxidizers and other incompatible materials. Protect containers from physical damage. Page 5 of 262 Page 5 of 262 Page 5 of 262 Page 5 of 262 ---PAGE BREAK--- Jet A Fuel January 23, 2015 Page 4 of 8 SECTION 8 EXPOSURE CONTROLS and PERSONAL PROTECTION Exposure Guidelines: INGREDIENTS EXPOSURE LIMITS Kerosene 200 mg/m3, skin TWA ACGIH TLV Hydrocarbons C7-C9 None Established Benzene 1 ppm TWA, 5 ppm STEL OSHA PEL 0.5 ppm TWA, 2.5 ppm STEL ACGIH TLV Naphthalene 10 ppm TWA OSHA PEL 10 ppm, skin TWA ACGIH TLV 29 CFR 1910.1028 is the OSHA regulation on Occupational Exposure to Benzene. Assure compliance with these regulations. Appropriate engineering controls: Use with local exhaust ventilation to maintain exposures below the occupational exposure limits. Use explosion proof equipment where required Respiratory protection: If exposures are exceeded, use a NIOSH approved organic vapor respirator appropriate for the form and concentration of the contaminants should be used. Selection of respiratory protection depends on the contaminant type, form and concentration. Select in accordance with OSHA 1910.134 and good Industrial Hygiene practice. Skin protection: Impervious gloves such as nitrile recommended to prevent skin contact. Eye protection: Wear chemical safety goggles to avoid eye contact. Other: Impervious coveralls, apron and boots is required to prevent skin contact and contamination of personal clothing. A safety shower and eye wash should be available in the immediate work area. SECTION 9 PHYSICAL and CHEMICAL PROPERTIES Appearance (physical state, color, etc.): Pale yellow Odor: Aromatic hydrocarbon odor. Odor threshold: Not available pH: Not applicable Melting point/Pourpoint: Not available Boiling Point: Not available Flash point: 141.1°F (60.6°C) PMCC Evaporation rate: Not available Flammability (solid, gas): Not applicable Flammable limits: LEL: 0.6% UEL: 5% Vapor pressure: <1 mmHg Vapor density: <1 Relative density: Not available Solubility: Not available Partition coefficient: n-ctanol/water: Not available Auto-ignition temperature: >410°F (>210°C) Decomposition temperature: Not available Viscosity: 1.3-2.4 @ 104°F SECTION 10 STABILITY and REACTIVITY Reactivity: This product is not expected to be reactive. Chemical stability: The product is stable. Possibility of hazardous reactions: None known. Conditions to avoid: Keep away from heat and all sources of ignition. Incompatible materials: Avoid oxidizing agents. Hazardous decomposition products: Thermal decomposition may yield carbon oxides and other products of incomplete combustion. Page 6 of 262 Page 6 of 262 Page 6 of 262 Page 6 of 262 ---PAGE BREAK--- Jet A Fuel January 23, 2015 Page 5 of 8 SECTION 11 TOXICOLOGICAL INFORMATION Health Hazards: Inhalation: Vapors may cause respiratory irritation and central nervous system effect including headache, dizziness, headaches, giddiness, euphoria, vertigo, blurred vision, nausea, numbness, drowsiness, anesthesia, and coma. . Overexposure to benzene by inhalation may cause exhilaration, nervous excitation, and/or giddiness, followed by a period of depression, drowsiness, or fatigue, tightness of the chest, unconsciousness, tremors or death. Skin Contact: Skin contact may cause irritation, redness and defatting of the skin. Eye Contact: Eye contact may cause mild irritation with redness, tearing and pain. Ingestion: Swallowing may cause gastrointestinal irritation, nausea, vomiting, diarrhea, vertigo, drowsiness, mental confusion, staggering gait, slurred speech, convulsions, unconsciousness and death due to circulatory failure. Aspiration during swallowing or vomiting may cause lung damage. Chronic Effects of Overexposure: Prolonged occupational overexposure may cause dermatitis. Reports have associated repeated and prolonged overexposure to petroleum distillates with adverse liver, kidney and bone marrow effects and with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the product may be harmful or fatal. Repetitive direct skin application of kerosene over a two year period resulted in skin cancer in laboratory animals. Petroleum hydrocarbons of similar composition and boiling ranges have been known to product kidney damage and tumors in male rats following prolonged inhalation exposures. Benzene has been shown to cause damage to the blood forming system with anemia, leukopenia and thrombocytopenia by all routes of exposure. Mutagenicity: Benzene did not induce in vitro mutation in bacteria using standard AMES test conditions. Mammalian cell gene mutation tests carried out in various human, mouse and Chinese hamster cells resulted in mixed results. Benzene is an in vivo mutagen in mammals, especially when chromosomal aberrations and micronuclei are induced. It has been reported that benzene exposure in humans induces genotoxic effects in in vivo. Reproductive Toxicity: In a reproductive study, rats were administered 250 and 1000 mg/kg of petroleum distillates for at least 70 days prior to mating and during the 14 day mating cycle. The absence of adverse effects on in-life parameters (such as body weight, feed consumption, and clinical observations), a dosage level of 1000 mg/kg/day was considered to be the no-observed-adverse-effect level (NOAEL) for reproductive and systemic toxicity. Carcinogenicity: Kerosene is listed as a “Confirmed Animal Carcinogen with Unknown Relevance to Humans: A3 by ACGIH. Benzene is listed by IARC as “Carcinogenic to Humans” Group 1, by NTP as “Known to Be a Human Carcinogen” and as a “Confirmed Human Carcinogen”, A1 by ACGIH. Naphthalene is listed by IARC as “Possibly Carcinogenic to Humans”, Group 2B, as “Reasonably Anticipated to be a Human Carcinogen” and as a “Confirmed Animal Carcinogen with Unknown Relevance to Humans”, A3 by ACGIH. Acute Toxicity Values: Kerosene: Oral rat LD50 >5000 mg/kg, Inhalation rat LC50 >5.28 mg/L/4 hr, Dermal rabbit LD50 >2000 mg/kg Hydrocarbons C7-C9: >5000 mg/kg, Inhalation rat LC50 >5.28 mg/L/4 hr, Dermal rabbit LD50 >2000 mg/kg (structurally similar chemical) Benzene: Oral rat LD50 >2000 mg/kg, Inhalation rat LC50 41690 mg/m3/ 4 hr, Dermal rabbit LD50 > 8260 mg/kg Naphthalene: Oral rat LD50 533 mg/kg, Inhalation rat LC0 0.4 mg/L (highest attainable concentration), Dermal rat LC50 >2500 mg/kg Page 7 of 262 Page 7 of 262 Page 7 of 262 Page 7 of 262 ---PAGE BREAK--- Jet A Fuel January 23, 2015 Page 6 of 8 SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity: Kerosene: 96 hr LL50 mykiss 2.5 mg/kg, 48 hr EL50 1.4 mg/L, 72 hr EL50 Pseudokirchnerella subcapitata 1.3 mg/L Hydrocarbons C7-C9: 96 hr LL50 mykiss 2.5 mg/kg, 48 hr EL50 1.4 mg/L, 72 hr EL50 Pseudokirchnerella subcapitata 1.3 mg/L (structurally similar chemical) Benzene: 96 hr LC50 mykiss 5.3 mg/L, 48 hr EC50 daphnia magna 10 mg/L, 72 hr EC50 Pseudokirchnerella subcapitata 32 mg/L Naphthalene: 96 hr LC50 Pimephales promelas 6.08 mg/L, 48 hr EC50 daphnia magna 2.16 mg/L Persistence and degradability: Kerosene is inherently biodegradable. Bioaccumulative potential: The BCF for kerosene is 70-5000 which suggest the potential for bioconcentration is moderate to high. Mobility in soil: Some components of kerosene will display low mobility and some will be essentially immobile in soil. Other adverse effects: This product is classified as toxic to the aquatic environment with long-term adverse effects. Releases to the environment should be avoided. SECTION 13: DISPOSAL INFORMATION Waste Disposal Method: Dispose in accordance with all local, state and federal regulations. SECTION 14: TRANSPORTATION INFORMATION UN Number Proper shipping name Hazard Class Packing Group Environmental Hazard DOT UN1223 Kerosene 3 PG III No TDG UN1223 Kerosene 3 PG III No IMDG UN1223 Kerosene 3 PG III No IATA UN1223 Kerosene 3 PG III No Transport in bulk (according to Annex II of MARPOL 73/78 and the IBC Code): Not applicable. Special precautions: None known. SECTION 15: REGULATORY INFORMATION Safety, health, and environmental regulations specific for the product in question. CERCLA Hazardous Substances (Section 103)/RQ: This product has a Reportable Quantity (RQ) of 3,333 lbs. (based on the RQ for Naphthalene of 100 lbs). Releases above the RQ must be reported to the National Response Center. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. EPA SARA 311 Hazard Classification: Acute Health, Chronic Health, Fire Hazard SARA 313: This product contains the following chemicals subject to Annual Release Reporting Requirements Under SARA Title III, Section 313 (40 CFR 372): Page 8 of 262 Page 8 of 262 Page 8 of 262 Page 8 of 262 ---PAGE BREAK--- Jet A Fuel January 23, 2015 Page 7 of 8 Benzene 71-43-2 0-0.5% Naphthalene 91-20-3 0-3% CALIFORNIA PROPOSITION 65: This product contains the following chemicals known to the State of California to cause cancer or reproductive toxicity. Benzene 71-43-2 0-0.5% Cancer, developmental, male reproductive toxicity Naphthalene 91-20-3 0-3% Cancer WHMIS CLASSIFICATION: Class B, Division 3 (Combustible Liquid), Class D, Division 2A (Very Toxic Material Causing Other Toxic Effects) This product has been classified in accordance with the hazard criteria in the CPR and the MSDS contains all the information required by the CPR. Australia AICS: All of the components are listed on the Australian Inventory of Chemical Substances. Canada DSL: All of the components are listed on the Canadian Domestic Substances List. China: All the components are listed on Inventory of Existing Chemical Substances in China. European EINECS: All of the ingredients are listed on the EINECS inventory. New Zealand: All the components are listed on the New Zealand Inventory of Chemicals. Philippines: All the components are listed on the Philippine Inventory of Chemical and Chemical Substances inventory. US EPA Toxic Substances Control Act: All of the components of this product are listed on the TSCA inventory. Page 9 of 262 Page 9 of 262 Page 9 of 262 Page 9 of 262 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MATERIAL IDENTITY: +22° F Splash Windshield Washer Fluid SECTION 1 – PRODUCT IDENTIFICATION & COMPANY INFORMATION Manufacturer: SPLASH PRODUCTS, INC. Telephone: (651) 489-8211 51 East Maryland Avenue St. Paul, MN 55117-4615 Facsimile: (651) 489-8247 Transportation Emergency for immediate information about a chemical or to seek assistance from a manufacturer: 1-[PHONE REDACTED] Date Updated: January 6, 2012 SECTION 2 - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION Hazardous Component* Approximate Composition OSHA Permissible Exposure Limit** NIOSH REL ACGIH Threshold Limit Value IDLH (NIOSH) Methanol (Methyl Alcohol) -CAS 67-56-1 -UN 1230 (DOT Guide 28) <8 percent by weight 200 ppm (260 mg/m3 ) 8-Hour TWA (Skin) 200 ppm (260 mg/m3) 8-Hour TWA 250 ppm (310 mg/m3) Ceiling (Skin) 200 ppm (260 mg/m3) 8-Hour TWA 250 ppm (310 mg/m3) Short-term Exposure Limit (15-minute TWA) (Skin) 6,000 ppm (0.6 percent in air) HMIS: HEALTH: 2 FLAMMABILITY: 2 REACTIVITY: 0 SPECIAL: NONE RATING SCALE: 0=MINIMAL 1=SLIGHT 2=MODERATE 3=SERIOUS 4=SEVERE SECTION 3 – HAZARDOUS IDENTIFICATION The hazardous component listed is not a known or suspected human carcinogen as listed or determined by the National Agency for Research on Cancer, National Toxicological Program “NTP Seventh Annual Report on Carcinogens,” or International Agency for Research on Cancer (IARC) monograph reviews. In addition, it is not considered a carcinogen by the Occupational Safety and Health Administration or the National Institute for Occupational Safety and Health. Can cause eye and skin irritation. HARMFUL IF SWALLOWED. DANGER POISON. FLAMMABLE. CANNOT BE MADE NONPOISONOUS. Irritation to respiratory track. INGESTION: Can cause blindness. INHALATION: May cause headaches, dizziness, nausea, incoordination, drowsiness, visual impairment and unconsciousness EYE CONTACT: Irritating to eyes; may cause severe and permanent damage. SKIN CONTACT: Prolonged or repeated contact without rinsing with water may cause irritation. MSDS +22° F Splash Windshield Washer Fluid Page 1 of 5 Page 11 of 262 Page 11 of 262 Page 11 of 262 Page 11 of 262 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MATERIAL IDENTITY: +22° F Splash Windshield Washer Fluid SECTION 4 – FIRST AID MEASURES INGESTION: Do not give liquid if victim is unconscious or drowsy. Otherwise, give 1 or 2 glasses of water. Call doctor, hospital emergency room or poison control center for instructions to induce vomiting. When medical advice is not available, induce vomiting using syrup of ipecac according to direction. If ipecac not available, induce vomiting with finger or back of spoon by touching the back of the victim’s throat. Get medical attention. INHALATION: If exposed to excessive levels of vapors. Remove to fresh air. EYE CONTACT: Immediately flush eye with plenty of cool, running water. Remove contact lenses if applicable, and continue flushing for at least 15 minutes, holding eyelids apart to ensure thorough rinsing of the entire eye. Speed is essential to minimize injury. Call a physician immediately. SKIN CONTACT: immediately flush skin with plenty of cool running water for at least 15 minutes. Wash with soap and water. If irritation develops or persists, get medical attention. Remove contaminated clothing and shoes; wash before reuse. SECTION 5 – FIRE FIGHTING MEASURES FLASH POINT: 130°F FLAMMABLE LIMITS: In air % by volume, LEL: 6% UEL: 36% EXTINGUISHING MEDIA: Use of dry chemical, carbon dioxide, water spray, alcohol foam. SPECIAL FIRE FIGHTING PROCEDURES: Use fog or spray to prevent flooding. Be prepared to use MSHA-NIOSH self contained breathing apparatus and protecting clothing. FIRE AND EXPLOSION HAZARDS: Treat as flammable liquid. There is a chance of moderate explosion and/or dangerous fire hazard. SECTION 6 – ACCIDENTAL RELEASE MEASURES RESPONSE TO SPILLS: Eliminate all sources of ignition immediately. Mop up residue and rinse area thoroughly with water. Contain run-off with absorbent material such as sand or clay and diking. Transfer liquid and absorbent material in approved container. Flush and mop area with water allowing to air dry. Keep spill out of sewers and open bodies of water. SECTION 7 – HANDLING AND STORAGE HANDLING PRECAUTIONS: Follow directions on label. Wash after handling and before eating. STORAGE PRECAUTIONS: Store container upright. Tighten cap securely. Avoid heat, sparks, and flames. Protect container from physical damage. KEEP AWAY FROM CHILDREN MSDS +22° F Splash Windshield Washer Fluid Page 2 of 5 Page 12 of 262 Page 12 of 262 Page 12 of 262 Page 12 of 262 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MATERIAL IDENTITY: +22° F Splash Windshield Washer Fluid SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION HYGIENIC PRACTICES: Avoid breathing vapors. Use with adequate ventilation. Wash thoroughly with soap and water after handling. Follow direction on label. Do not store near food stuffs, water or feed. SKIN PROTECTION: Rubber or neoprene gloves and additional protection including impervious boots, apron, or coveralls, as needed in areas of unusual exposure. EYE PROTECTION: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area. SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear blue liquid BOILING POINT: 200°F ODOR: Mild alcohol odor FREEZE POINT: +22°F pH: 8.2 VAPOR PRESSURE (mm of Hg): 97 @20C (68F) SPECIFIC GRAVITY: (water .986 @60°F VAPOR DENSITY (Air 1.1 SOLUBILITY IN WATER: 100% EVAPORATION RATE (BuAc=1): 5.9 SECTION 10 – STABILITY AND REACTIVITY CONDITIONS TO AVOID: HEAT, SPARKS, FLAMES. No smoking when using. INCOMPATIBILITY: Strong oxidizing agents such as nitrates and sulfuric acid. HAZARDOUS DECOMPOSITION PRODUCTS: Burning can product carbon monoxide and /or carbon dioxide. Carbon monoxide is highly toxic if inhaled. Carbon dioxide in sufficient concentration can act as an HAZARDOUS POLYMERIZATION: will not occur. SECTION 11 – TOXICOLOGICAL INFORMATION CARCINOGENICITY: This product does not contain any known or anticipated carcinogens according to the criteria of the NPT annual report on carcinogens and OSHA 29 CFR 1910, Z. Methyl Alcohol (Methanol): Oral rat LD50: 5628 mg/kg: inhalation rat LC50: 64000 ppm/4H: skin rabbit LD50: 15800 mg/kg; irritation data-standard Draize test: skin, rabbit: 20mg/24hr. Moderate; eye, rabbit: 100mg/24hr. Moderate. Investigated as a mutagen, reproductive effector. METHYL ALCOHOL (67-56-1) CARCINOGEN: Known: No. Anticipated: No. MSDS +22° F Splash Windshield Washer Fluid Page 3 of 5 Page 13 of 262 Page 13 of 262 Page 13 of 262 Page 13 of 262 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MATERIAL IDENTITY: +22° F Splash Windshield Washer Fluid SECTION 12 – ECOLOGICAL INFORMATION ENVIRONMENTAL: When released into the soil, this material is expected to readily biodegrade. When released into the soil, this material is expected to leach into groundwater. When released into the soil, this material is expected to quickly evaporate. When released into water, this material is expected to have a half-life between 1 and 10 days. When released into water, this material is expected to readily biodegrade. When released into the air, this material is expected to exist in the aerosol phase with a short half-life. When released into the air, this material is expected to readily degraded by reaction with photo chemically produced hydroxyl radicals. When released into air, this material is expected to have a half-life between 10 and 30 days. When released into the air, this material is expected to be readily removed from the atmosphere by wet deposition. ENVIRONMENTAL TOXICITY: This material is expected to be toxic to aquatic life. SECTION 13 – DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: Dispose in accordance with federal, state and local regulations. SECTION 14 – TRANSPORT INFORMATION (U.S. D.O.T.) – U.S. Department of Transportation: PROPER SHIPPING NAME: Consumer Commodity ORM-D Exceptions: Per 49 CFR 173.150 (pg III, inner package not over 5.0 L) SECTION 15 – REGULATORY INFORMATION THIS PRODUCT CONTAINS COMPONENT(S) CITED ON THE FOLLOWING REGULATIONS: CHEMICAL NAME CAS NUMBER Methanol 67-56-1 U.S.FEDERAL REGULATIONS TSCA (Toxic Substance Control Act) Status – TSCA (UNITED STATES) CERCLA RQ – 40 CFR 3.2.1 Component RQ (lbs) Methyl Alcohol 5,000 MSDS +22° F Splash Windshield Washer Fluid Page 4 of 5 Page 14 of 262 Page 14 of 262 Page 14 of 262 Page 14 of 262 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET MATERIAL IDENTITY: +22° F Splash Windshield Washer Fluid SARA 302 Components – 40 CFR 355 Appendix A None Section 311/312 Hazard Class – 40CFR 370.2 Immediate Delayed Fire Reactive Sudden Release of Pressure SARA 313 Components - 40 CFR 372.65 Section 313 Components(s) CAS Number % Methanol 67-56-1 <8 INTERNATIONAL REGULATIONS Inventory Status – DSL (CANADA) The international ingredients of this are listed. WHMIS Information: B2, D1A ECL (SOUTH KOREA) The international ingredients of this product are listed. EINECS (EUROPE) The international ingredients of this product are listed. ENCS (JAPAN) The international ingredients of this product are listed. State and Local Regulations – California Proposition 65 New Jersey RTK (Right-To-Know) Label information Methyl Alcohol 67-56-1 RTK (Right-To-Know) Label information Methanol 67-56-1 Atmospheric Standards: The Clean Air Act Amendments of 1990 list methanol as a hazardous air pollutant. SECTION 16 – OTHER INFORMATION Information in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The condition or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. MSDS +22° F Splash Windshield Washer Fluid Page 5 of 5 Page 15 of 262 Page 15 of 262 Page 15 of 262 Page 15 of 262 ---PAGE BREAK--- Page 16 of 262 Page 16 of 262 Page 16 of 262 Page 16 of 262 ---PAGE BREAK--- Page 17 of 262 Page 17 of 262 Page 17 of 262 Page 17 of 262 ---PAGE BREAK--- Page 18 of 262 Page 18 of 262 Page 18 of 262 Page 18 of 262 ---PAGE BREAK--- Page 19 of 262 Page 19 of 262 Page 19 of 262 Page 19 of 262 ---PAGE BREAK--- Page 20 of 262 Page 20 of 262 Page 20 of 262 Page 20 of 262 ---PAGE BREAK--- NA AJAX CLEANER POWDER-OXYGEN BLEACH This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000222 Revision Date: 05/14/2015 1 / 10 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : AJAX CLEANER POWDER-OXYGEN BLEACH Product code : 200000017621 : B01809190000 Manufacturer or supplier's details Company : Colgate-Palmolive Co Commerical Consumer Group 191 East Hanover Avenue Morristown, NJ 07960-3151 Telephone : US: Consumer Affairs - 1-[PHONE REDACTED] Emergency telephone number : For emergencies involving spill, leak, fire, exposure or acci- dent call CHEMTREC (24hr) at (800) 424-9300 or (703) 527-3887. Medical Emergency (24HR): For MEDICAL EMERGENCIES involving this product call: (888) 489-3861 Recommended use of the chemical and restrictions on use Recommended use : A formulated multi-purpose cleaner SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Appearance powder Colour off-white GHS Classification Acute toxicity (Inhalation) : Category 4 GHS Label element Hazard pictograms : Signal word : Warning Hazard statements : H332 Harmful if inhaled. Page 21 of 262 Page 21 of 262 Page 21 of 262 Page 21 of 262 ---PAGE BREAK--- NA AJAX CLEANER POWDER-OXYGEN BLEACH This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000222 Revision Date: 05/14/2015 2 / 10 Precautionary statements : Prevention: P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P271 Use only outdoors or in a well-ventilated area. Response: P304 + P340 + P312 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. Potential Health Effects Inhalation : May be harmful if inhaled. Skin : May cause skin irritation upon prolonged contact. Eyes : Causes eye irritation on direct contact. Ingestion : May be harmful if swallowed in large quantities. Aggravated Medical Condi- tion : None known. Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by ACGIH. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Chemical Name CAS-No. Concentration LIMESTONE 1317-65-3 90 - 100 SODIUM CARBONATE 497-19-8 5 - < 10 SECTION 4. FIRST AID MEASURES If inhaled : Remove victim to fresh air. Get medical attention, if symp- toms persist. Page 22 of 262 Page 22 of 262 Page 22 of 262 Page 22 of 262 ---PAGE BREAK--- NA AJAX CLEANER POWDER-OXYGEN BLEACH This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000222 Revision Date: 05/14/2015 3 / 10 In case of skin contact : Flush skin with large amounts of water. If irritation develops and persists, get medical attention. In case of eye contact : Flush eyes with water at least 15 minutes. Get medical atten- tion if eye irritation develops or persists. If swallowed : Drink 8 ounces of clear water. Get medical attention. Most important and effects, both acute and delayed : Harmful if inhaled. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or car- bon dioxide. Hazardous combustion prod- ucts : No hazardous combustion products are known Special protective equipment for firefighters : Self-contained breathing apparatus and full protective clothing should be worn when fighting chemical fires. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- tive equipment and emer- gency procedures : Use personal protection recommended in Section 8 of the SDS. Methods and materials for containment and cleaning up : Cover with inert, absorbent material and remove to disposal container. Spill area may be slippery. Flush with plenty of wa- ter. SECTION 7. HANDLING AND STORAGE Conditions for safe storage : Store at controlled room temperature at 20-25°C (68-77°F). SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parame- ters / Permissible concentration Basis LIMESTONE 1317-65-3 TWA (Res- pirable) 5 mg/m3 NIOSH REL TWA (total) 10 mg/m3 NIOSH REL TWA (Res- pirable) 5 mg/m3 NIOSH REL Page 23 of 262 Page 23 of 262 Page 23 of 262 Page 23 of 262 ---PAGE BREAK--- NA AJAX CLEANER POWDER-OXYGEN BLEACH This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000222 Revision Date: 05/14/2015 4 / 10 TWA (total) 10 mg/m3 NIOSH REL TWA (total dust) 15 mg/m3 OSHA Z-1 TWA (respir- able fraction) 5 mg/m3 OSHA Z-1 TWA (Total dust) 15 mg/m3 OSHA P0 TWA (respir- able dust fraction) 5 mg/m3 OSHA P0 Engineering measures : In an industrial work environment, no special precautions or control measures are required. Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are un- known, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazard- ous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. Protective measures : In an industrial work environment, if a splash is likely, chemi- cal goggles may be needed. Prolonged skin contact may require protective gloves. For consumer use, no unusual precautions are necessary. Hygiene measures : In an industrial work environment, avoid eye and prolonged skin contact. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : powder Colour : off-white pH : 10.4 Flash point : No data available Density : 1.04 g/cm3 SECTION 10. STABILITY AND REACTIVITY Page 24 of 262 Page 24 of 262 Page 24 of 262 Page 24 of 262 ---PAGE BREAK--- NA AJAX CLEANER POWDER-OXYGEN BLEACH This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000222 Revision Date: 05/14/2015 5 / 10 Possibility of hazardous reac- tions : Hazardous polymerisation does not occur. Incompatible materials : Strong oxidizing agents Hazardous decomposition products : None known. SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Harmful if inhaled. Product: Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Acute inhalation toxicity : Acute toxicity estimate : 1.63 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method Components: LIMESTONE: Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 420 Acute inhalation toxicity : LC50 (Rabbit): > 3 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403 Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 402 SODIUM CARBONATE: Acute oral toxicity : LD50 (Rat): 2,800 mg/kg Acute inhalation toxicity : LC50 (Rabbit): 2.3 mg/l Exposure time: 2 h Test atmosphere: No information available. Method: No information available. Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Method: No information available. Skin corrosion/irritation Not classified based on available information. Components: LIMESTONE: Page 25 of 262 Page 25 of 262 Page 25 of 262 Page 25 of 262 ---PAGE BREAK--- NA AJAX CLEANER POWDER-OXYGEN BLEACH This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000222 Revision Date: 05/14/2015 6 / 10 Result: No skin irritation SODIUM CARBONATE: Remarks: No data available Serious eye damage/eye irritation Not classified based on available information. Components: LIMESTONE: Result: No eye irritation SODIUM CARBONATE: Result: Irritation to eyes, reversing within 21 days Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information. Components: LIMESTONE: Exposure routes: Inhalation Result: Does not cause respiratory sensitisation. Exposure routes: Dermal Result: Does not cause skin sensitisation. SODIUM CARBONATE: Exposure routes: Inhalation Remarks: No data available Exposure routes: Dermal Remarks: No data available Germ cell mutagenicity Not classified based on available information. Carcinogenicity Not classified based on available information. Reproductive toxicity Not classified based on available information. STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. Page 26 of 262 Page 26 of 262 Page 26 of 262 Page 26 of 262 ---PAGE BREAK--- NA AJAX CLEANER POWDER-OXYGEN BLEACH This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000222 Revision Date: 05/14/2015 7 / 10 Further information Product: Remarks: This product has not been tested as a whole. However, this formula was reviewed by expert toxicologists in the Product Safety Assurance Department of Colgate-Palmolive and is determined to be safe for its intended use. This review has taken into consideration available safety-related information including information on individual ingredients, similar formulas and potential ingredient interactions. This review is a component of the hazard determination used to prepare the statements in Section 3 of the SDS. SECTION 12. ECOLOGICAL INFORMATION The product has not been tested as a whole for environmental toxicity. However, environmental information on the ingredients in this product have been reviewed by the Environmental, Health and Safety group of Colgate-Palmolive and determined to have an acceptable environmental profile. This evaluation is based on available information on individual ingredients, interactions of ingredients, and similar ingredients. Biodegradability claims are supported by data on ingredients surfactants are biodegradable) or testing conducted on the final product This product is biodegradable). SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Any disposal practice must be in compliance with local, state and federal laws and regulations (contact local or state envi- ronment agency for specific rules). Do not dump in sewers, any body of water or on the ground. SECTION 14. TRANSPORT INFORMATION DOT : Not regulated. TDG : Not regulated. IATA : Not regulated. IMDG : Not regulated. International Regulation Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations SECTION 15. REGULATORY INFORMATION Page 27 of 262 Page 27 of 262 Page 27 of 262 Page 27 of 262 ---PAGE BREAK--- NA AJAX CLEANER POWDER-OXYGEN BLEACH This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000222 Revision Date: 05/14/2015 8 / 10 OSHA Hazards : Combustible dust, Moderate skin irritant, Severe eye irritant EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) SODIUM DODECYL BENZENE SULFONATE 25155-30-0 1000 * Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) SULFUR DIOXIDE 7446-09-5 500 * Calculated RQ exceeds reasonably attainable upper limit. SARA 311/312 Hazards : Acute Health Hazard SARA 302 : No chemicals in this material are subject to the reporting re- quirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). Clean Water Act The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Ta- ble 116.4A: SODIUM DODECYL BENZENE SULFONATE 25155-30-0 Sulfuric Acid SULFURIC ACID The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3: SODIUM DODECYL BENZENE SULFONATE 25155-30-0 Sulfuric Acid SULFURIC ACID This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 Massachusetts Right To Know Page 28 of 262 Page 28 of 262 Page 28 of 262 Page 28 of 262 ---PAGE BREAK--- NA AJAX CLEANER POWDER-OXYGEN BLEACH This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000222 Revision Date: 05/14/2015 9 / 10 LIMESTONE 1317-65-3 SODIUM DODECYL BENZENE SULFONATE 25155-30-0 Sulfuric Acid SULFURIC ACID SULFUR DIOXIDE 7446-09-5 Right To Know LIMESTONE 1317-65-3 SODIUM CARBONATE 497-19-8 SODIUM DODECYL BENZENE SULFONATE 25155-30-0 Sulfuric Acid SULFURIC ACID SULFUR DIOXIDE 7446-09-5 SODIUM SULFATE 7757-82-6 New Jersey Right To Know LIMESTONE 1317-65-3 SODIUM CARBONATE 497-19-8 SODIUM DODECYL BENZENE SULFONATE 25155-30-0 California Prop 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other re- productive harm. The components of this product are reported in the following inventories: TSCA : All ingredients in this product are listed on the TSCA Inventory or are not required to be listed on the TSCA Inventory. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) Page 29 of 262 Page 29 of 262 Page 29 of 262 Page 29 of 262 ---PAGE BREAK--- NA AJAX CLEANER POWDER-OXYGEN BLEACH This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000222 Revision Date: 05/14/2015 10 / 10 SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Disclaimer: The information on this sheet is limited to the material identified and is believed by the Colgate-Palmolive Company to be correct based on its knowledge and information as of the date noted. Colgate makes no representation, guarantee or warranty, expressed or im- plied, as to the accuracy, reliability or completeness of the information and assumes no re- sponsibility for injury, damage or loss resulting from the use of the material. Flammability Health Instability 2 0 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 0 0 2 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 30 of 262 Page 30 of 262 Page 30 of 262 Page 30 of 262 ---PAGE BREAK--- Dry Lub Product Code: C2015 Page 1 of 3 SAFETY DATA SHEET SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle® Dry Lub™ PRODUCT TYPE: Dry Lubricant Coating PRODUCT CODE: C2015 MANUFACTURED FOR: Castle Products, Inc. 424 St. Paul Street Rochester, NY 14605 [PHONE REDACTED] • FAX [PHONE REDACTED] EMERGENCY [PHONE REDACTED] SECTION 2 HAZARD IDENTIFICATION EMERGENCY OVERVIEW: DANGER: Gases Under Pressure, Flammable, Irritant POTENTIAL HEALTH EFFECTS: Eyes: Irritating to eyes. Skin: Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis. Inhalation: Irritating to respiratory system. Avoid breathing vapors or mists. of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting, and diarrhea. Potential for aspiration if swallowed. SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % Acetone 67-64-1 1000ppm 750ppm 750ppm 15-40% Toluene 108-88-3 200ppm 20ppm 150ppm 15-40% Propane/Isobutane/N-Butane 68476-86-8 NE NE NE 10-30% Isopropyl Alcohol 67-63-0 400ppm NE 400ppm 5-10% Molybdenum Disulfide 1317-33-5 15 mg/m3(dust) 10 mg/m3 NE 1-5% SECTION 4 FIRST AID MEASURES First Aid Procedures: Eye contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician if irritation persists. Skin contact: For skin contact flush with large amounts of water. Call a physician if irritation persists. Inhalation: Immediately remove from further exposure. Give supplemental oxygen, if breathing is difficult. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by mouth to an unconscious person. Note to physician: No information available. SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: ≥ -141°F LOWER EXPLOSIVE LIMIT: ND UPPER EXPLOSIVE LIMIT: ND EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate for surrounding fire. UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area. Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Ventilate spaces before entering. Environmental precautions: Prevent further leakage or spillage if safe to do so. Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Eliminate ignition sources including sources of electrical, static or frictional sparks. Wear appropriate protective equipment and clothing during clean-up. Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal. Page 31 of 262 Page 31 of 262 Page 31 of 262 Page 31 of 262 ---PAGE BREAK--- Dry Lub Product Code: C2015 Page 2 of 3 Large Spills: Dike far ahead of liquid spill for later disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. SECTION 7 HANDLING AND STORAGE Handling: Product is extremely flammable. Do not store near ignition sources. Avoid breathing mist. Avoid contact with skin and eyes. Wear suitable protective clothing. Wash hands after handling. Storage: Keep from freezing. Keep containers closed. Store in a cool, dry place. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established. Engineering controls: Use local exhaust ventilation. Personal protective equipment: Gloves: Not normally required. Eye/Face Protection: Eye protection not normally required but recommended. Skin Protection: Wear clothing suited to the task being performed. Respiratory Protection: Not normally required if good ventilation is maintained. SECTION 9 PHYSICAL and CHEMICAL PROPERTIES BOILING POINT: ND SPECIFIC GRAVITY (H2O=1): ND VAPOR PRESSURE: ND PERCENT VOLATILE BY VOL 64.5% VAPOR DENSITY (air=1) >1 EVAPORATION RATE (Butyl Acetate=1): ND SOLUBILITY IN WATER: ND APPEARANCE & ODOR: Black Powder / Solvent pH: NA SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable. INCOMPATIBILITY (material to avoid): Strong oxidizing agents. Strong bases. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide, Carbon Dioxide, Sulfur Oxides. HAZARDOUS POLYMERIZATION: Does not occur. SECTION 11 TOXICOLOGICAL INFORMATION Components Test Results: Acetone: Oral LD50 (rat) 5800 mg/kg Toluene: Oral LD50 (rat) 636 mg/kg; Dermal LD50 (rabbit) 8390 mg/kg; Inhalation LC50 (rat) 12.5 mg/L (4h) ISopropanol: Oral LD50 (rat) 4396 mg/kg; Dermal LD50 (rabbit) 12870 mg/kg; Inhalation LC50 (rat) 72.6 mg/L (4h) Not classified to be a carcinogen to humans. SECTION 12 ECOLOGICAL INFORMATION Component Test Results: None reported. SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Dispose according to all applicable Federal, State, and Local regulations. SECTION 14 TRANSPORT INFORMATION DOT Ground: Consumer Commodity ORM-D, or Limited Quantity. SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations. CERCLA (Superfund) reportable quantity: None SARA (Superfund Amendments and Reauthorization Act of 1986): 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Section 302 extremely hazardous substance: No Page 32 of 262 Page 32 of 262 Page 32 of 262 Page 32 of 262 ---PAGE BREAK--- Dry Lub Product Code: C2015 Page 3 of 3 Section 311/312 hazardous chemical: Acute Health Hazard: Yes; Chronic Health Hazard: Yes; Fire Hazard: Yes; Sudden Release of Pressure Hazard: No; Reactive Hazard: No.. Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR. SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.) HMIS® ratings Health: 2 Flammability: 4 Physical hazard: 2 NFPA ratings Health: 2 Flammability: 4 Instability: 0 Other: NA-Not Applicable, ND-Not Determined, NE-Not Established. Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. PREPARED: 11/29/93 UPDATED: 9/19/2013 PRODUCT C2015 Page 33 of 262 Page 33 of 262 Page 33 of 262 Page 33 of 262 ---PAGE BREAK--- Thrust Product Code: C2005 Page 1 of 3 SAFETY DATA SHEET SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle® Thrust™ PRODUCT TYPE: Penetrating Oil PRODUCT CODE: C2005 MANUFACTURED FOR: Castle Products, Inc. 424 St. Paul Street Rochester, NY 14605 [PHONE REDACTED] • FAX [PHONE REDACTED] EMERGENCY [PHONE REDACTED] SECTION 2 HAZARD IDENTIFICATION EMERGENCY OVERVIEW: DANGER: Gases Under Pressure, Flammable, Irritant POTENTIAL HEALTH EFFECTS: Eyes: May cause irritation. Skin: May cause irritation. Prolonged exposure may cause fatting dermatitis. Inhalation: May cause irritation. Propellant is a simple Ingestion: May cause headache, nausea, vomiting, and weakness. Effects of chronic exposure: Lifetime skin painting tests indicate that materials of similar composition as kerosene may have produced skin cancer in experimental animals. The relationship of these results to humans has not been fully established. SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % Petroleum Oil Blend (Mixture) 64742-52-5 5 mg/m3 NE NE 30-60% Kerosene (Petroleum) 8008-20-6 5 ppm NE NE 10-30% Propane 74-98-6 1000 ppm NE NE 7-15% Isobutane 75-28-5 1000 ppm NE NE 5-10% Ethyl acetate 141-78-6 400 ppm NE NE 1-5% SECTION 4 FIRST AID MEASURES First Aid Procedures: Eye contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician if irritation persists. Skin contact: For skin contact flush with large amounts of water. Call a physician if irritation persists. Inhalation: Immediately remove from further exposure. Give supplemental oxygen, if breathing is difficult. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by mouth to an unconscious person. Note to physician: If the product is ingested, treat the affected person SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: 25°F LOWER EXPLOSIVE LIMIT: 2.0% UPPER EXPLOSIVE LIMIT: 10.7% [Propellant: ≥-141°F EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate for surrounding fire. UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: Water from fogging nozzles may be used to cool closed containers to prevent pressure build-up if exposed to extreme temperatures. As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area. Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Ventilate spaces before entering. Environmental precautions: Prevent further leakage or spillage if safe to do so. Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Eliminate ignition sources including sources of electrical, static or frictional sparks. Wear appropriate protective equipment and clothing during clean-up. Page 34 of 262 Page 34 of 262 Page 34 of 262 Page 34 of 262 ---PAGE BREAK--- Thrust Product Code: C2005 Page 2 of 3 Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal. Large Spills: Dike far ahead of liquid spill for disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. SECTION 7 HANDLING AND STORAGE Handling: Avoid breathing mist. Avoid contact with skin and eyes. Wear suitable protective clothing. Wash hands after handling. Storage: Keep from freezing. Keep containers closed. Store in a cool, dry place. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established. Engineering controls: Use local exhaust ventilation. Personal protective equipment: General: Eye wash fountain and emergency showers are recommended. Eye/face Protection: Wear safety glasses or goggles. Skin Protection: Wear suitable protective clothing. Wear chemical resistant gloves. Respiratory Protection: When respiratory protection is required, wear a NIOSH/MSHA approved self-contained breathing apparatus with full facepiece operated in a positive-pressure mode. SECTION 9 PHYSICAL and CHEMICAL PROPERTIES BOILING POINT: 168°F (76°C) SPECIFIC GRAVITY (H2O=1): 0.88-0.89 (liquid) 0.75-0.79 (aerosol) VAPOR PRESSURE: 55-65 PERCENT VOLATILE BY VOL >95% VAPOR DENSITY (air=1) >1 EVAPORATION RATE (Butyl Acetate=1): <1 SOLUBILITY IN WATER: Negligible APPEARANCE & ODOR: Dark amber liquid / characteristic pH: NA SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (material to avoid): Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide, Carbon Dioxide, Hydrocarbon fumes and smoke where combustion is incomplete. HAZARDOUS POLYMERIZATION: Will not occur SECTION 11 TOXICOLOGICAL INFORMATION Components Test Results: No information available. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. SECTION 12 ECOLOGICAL INFORMATION Component Test Results: No information available. SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Do not puncture or incinerate containers, even when empty. Dispose according to all applicable Federal, State, and Local regulations. SECTION 14 TRANSPORT INFORMATION D.O.T. Classification: Consumer Commodity, ORM-D T.D.G. Classification: Consumer Commodity (Aerosols, UN1950, Class 2.1) SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations. CERCLA (Superfund) reportable quantity: None SARA (Superfund Amendments and Reauthorization Act of 1986): 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Page 35 of 262 Page 35 of 262 Page 35 of 262 Page 35 of 262 ---PAGE BREAK--- Thrust Product Code: C2005 Page 3 of 3 Section 302 extremely hazardous substance: No Section 311 hazardous chemical: No Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR. SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.) HMIS® ratings Health: 2 Flammability: 4 Physical hazard: 0 NFPA Code 30B: Level 3 Other: NA-Not Applicable, ND-Not Determined, NE-Not Established. Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. PREPARED: 9/25/96 UPDATED: 6/14/13 PRODUCT C2005 Page 36 of 262 Page 36 of 262 Page 36 of 262 Page 36 of 262 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Mark V Products Revision Date 12/31/05 400 El Sobrante Road Date Printed: 12/31/05 Corona, CA 92879 Product Number: Citra Clean Hand Cleaner (951) 280-9799 For Chemical Emergency, Call Chemtrec (951) 280-9393 FAX 1-[PHONE REDACTED] SECTION 1 - IDENTIFICATION Product Name: CITRA CLEAN HAND CLEANER WITH PUMICE Product Type: emulsion Description: A thick, orange colored, commercial hand cleaner with an orange fragrance. SECTION II - HAZARDOUS INGREDIENTS HAZARDOUS INGREDIENT CAS NUMBER TLV / PEL D Limonene 5989-27-5 TLV / PEL: None Est. Glycerine 56-81-5 TLV / PEL: None Est. Alkanolamine 102-71-4 TLV / PEL: Dermal LD50 2000 mg / kg Nonionic Surfactant 68081-81-2 TLV / PEL: None Est. SECTION III - PHYSICAL DATA Appearance: A thick orange liquid containing pumice Specific Gravity: 0.99 Boiling Point: > 338 o F % Volatile by volume: 92 Water Solubility 89 pH: 7 SECTION IV - FIRE AND EXPLOSION DATA Flash Point (method): > 167 o F (PMCC) Extinguishing Media: C02, dry chemical, foam, water fog, water spray. NFPA Classification: IIIB NFPA Symbol Codes: Flammability 1, Health 1, Reactivity 0 Fire Fighting Procedures: Wear approved SCBA with full facepiece operated in positive pressure demand mode. SECTION V - REACTIVITY DATA Stability: Material is Stable Hazardous Polymerization: Hazardous Polymerization is not expected to occur Incompatibility: Avoid contact with strong oxidizing agents and strong acids. Hazardous Decomposition: Combustion may produce Carbon Monoxide, CO2 and potentially irritating fumes. HEALTH HAZARD FLAMMABILITY HAZARD REACTIVITY HAZARD PERSONAL PROTECTION 1 - Slight 2 - Moderate 0 - Minimal Page 37 of 262 Page 37 of 262 Page 37 of 262 Page 37 of 262 ---PAGE BREAK--- SECTION VI - HEALTH DATA Routes of Entry: Inhalation, skin absorbtion, ingestion Listed Carcinogen: Not listed by IARC, NTP or OSHA Medical Conditions Aggrevated: Pre-existing condtions of the skin & respiratory system. Inhalation: Excessive inhalation of vapors can cause nasal and respiratory irritation. Ingestion: Can cause gastrointestinal irritation, nausea, vomiting & diarrhea. Aspiration of material into lungs may cause chemical pneumonitis. Eyes: May cause irritation, redness, tearing, blurred vision. Skin: May affect pre-existing conditions of dry skin and dermatitis. SECTION VII - FIRST AID Inhalation: Remove to fresh air. If problems develop, get medical attention. If breathing is difficult, administer oxygen. If breathing has stopped, give artificial respiration. Ingestion: Do NOT induce vomiting. If conscious, give large quantities of water. Have medical personnel determine if vomiting is necessary. Never give anything by mouth to an unconscious person. Aspiration of material into the lungs due to vomiting can cause chemical pneumonitis, which can be fatal. Eyes: Flush with large amounts of water for 15 minutes. Hold eyelids apart to ensure flushing. Get medical attention. Skin contact: Wash with soap and water. Remove contaminated clothing and wash before re-use. SECTION VIII - EMPLOYEE PROTECTION Respiratory Protection: Not usually needed. Protective Clothing: Nitrile gloves and chemical splash goggles. Addtional Measures: Do not place product in unmarked container. Keep away from children. Slippery when spilled. SECTION IX - SPILL AND DISPOSAL DATA Spill: Dike to prevent spillage into stream or storm drain system. Recover all material possible. Absorb remaining material with vermiculite or other absorbent material. Waste Disposal: Follow Federal, State and local guidelines. Handling & Storage: Store in a cool, well ventilated area. Avoid freezing or over heating. SECTION X - OTHER REGULATORY INFORMATION Shipping Name: Non Regulated UN Listing: Non Regulated Packing Group: Constituent: SECTION XI - PRECAUTIONARY STATEMENTS WARNING: This information contained in this MSDS is based on the data available to us from sources we believe to be reliable. No warranty or guaranty expressed or implied is made regarding the accuracy of this data or the results obtained from the reliance on this data. The manufacturer assumes no responsibility for injury from the use of this product. Be safe: Read this safety information and forward it to all persons who may be exposed to this product. Page 38 of 262 Page 38 of 262 Page 38 of 262 Page 38 of 262 ---PAGE BREAK--- N535 Page 1 of 2 5332 Dansher Road Illinois 60525 MATERIAL SAFETY DATA SHEET Revision Date: 12/17/2012 MSDS No. N535 Supersedes Date: 8/15/2012 Emergency Phones: [PHONE REDACTED] (NYCO) [PHONE REDACTED] (CHEMTREC) PLEASE NOTE: This MSDS is being provided to your company for the purpose of providing current health and safety information to your management and for your employees who work with this material. Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT-TO-KNOW regulations. Also make this information available to any employee who requests it. It is your obligation to comply with these regulations. SECTION I - PRODUCT IDENTITY PRODUCT NAME: Citra-Blaze 535 Cleaner Degreaser Formula: Mixture of terpene solvent, detergent, alkaline builders and water. Chemical Type: As above HMIS RATINGS Health = 1 (Slight) Flammability = 2 (Moderate) Reactivity = 0 (Minimal) Protection = B (Goggles and gloves) SECTION II - HAZARDOUS INGREDIENTS CARCINOGEN PERCENT TLV (OSHA,TP,IARC) None no SECTION III - CHEMICAL AND PHYSICAL Appearance: Orange Liquid Boiling Point: 210OF. Odor: Orange Melting Point: N/A pH: 11.0-11.8 Spec. Gravity (H20 = 1.01 Water Solubility: Complete Vapor Pressure (Mm Hg): N/A Viscosity @ 25oC: < 25 cps (Brookfield) VOC Content: 1.2% SECTION IV - FIRE AND EXPLOSION HAZARDS Flash Point (Method): 133oF. TCC Explosion Limits: Upper: 7 Lower: 1 Extinguishing Media: Water fog, CO2, halon system, foam for alcohols Special Firefighting Procedures and Hazards: Treat as a combustible liquid fire. May be ignited by heat, sparks, flame or other sources of ignition. Minimize prolonged skin and eye contact. Wear breathing, skin and eye protection if exposure is likely. SECTION V - REACTIVITY INFORMATION Stable: Unstable: Precautions: Incompatibility: Oxidizing agents. Hazardous Decomposition Products: If in a fire: CO, CO2, hydrocarbons. Hazardous Polymerization: Occurs: Does Not Occur: Page 39 of 262 Page 39 of 262 Page 39 of 262 Page 39 of 262 ---PAGE BREAK--- N535 Page 2 of 2 SECTION VI - HEALTH HAZARDS - PROTECTIVE MEASURES - FIRST AID Inhalation: Breathing of mists or vapor causes irritation. Wear approved organic mist respirator if necessary. Provide ventilation in confined spaces. Remove to fresh air. Give artificial respiration or oxygen if needed. Skin: Extended contact may cause irritation and defatting. Wear protective gloves. Flush skin thoroughly with water for 15 minutes. Remove contaminated clothing and wash before wearing again. Eyes: May cause irritation from misting. Flush with water for 15 minutes. If irritation persists consult a doctor. Ingestion: May cause mild gastric disturbances or nausea. Avoid swallowing. Drink lots of water or milk. Do not induce vomiting. If irritation persists get medical attention. Most likely routes of entry: Skin, Eyes. Other Important Medical or Precautionary Information: None SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE Spills and Leaks: Small spills can be flushed into normal drainage or into ground with copious amounts of water, or taken up with absorbent material. Do not drain to sewer without dilution. Larger spills should be contained by diking or other methods and held for disposal or reuse. Storage and Handling: Keep away from heat, sparks and open flames. Check daily for any container leaks. Waste Disposal: May be disposable in sewers if local regulations permit. Otherwise, send to licensed treatment and disposal facility for handling and disposal. Observe label precautions. Empty Containers: Rinse well before handling and disposal. Observe label precautions. Other Precautions: N/A SECTION VIII - REGULATORY INFORMATION Reportable for SARA Title III, S.313 (Form None The information herein has been compiled from sources believed to be reliable and is accurate to the best of our knowledge. However, Nyco Products cannot give any guarantees regarding information from other sources, and expressly does not make any warranties, nor assumes any liability, for its use. Page 40 of 262 Page 40 of 262 Page 40 of 262 Page 40 of 262 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 1 of 13 POWER SERVICE PRODUCTS, INC. SAFETY DATA SHEET SECTION 1 - IDENTIFICATION PRODUCT NAME: DIESEL FUEL SUPPLEMENT +CETANE BOOST Unless otherwise noted, all sections of this SDS apply to each of the following products and part numbers. PART NUMBERS: 1:400 Treatment Ratio 1016-06, 1016-09, 1025-06, 1025-09, 1025-12, 1080-06, 11016-06, 11016-09, 11025-06, 11025-12, 11080-06 1:1,000 Treatment Ratio 1000, 1128-04, 1060-01 1:1,500 Treatment Ratio 1050-02, 1055-01, 1260-01 COMPANY IDENTIFICATION: Power Service Products, Inc. P.O. Box 1089 Weatherford, TX 76086 Email: [EMAIL REDACTED] Phone: [PHONE REDACTED] or [PHONE REDACTED] Fax: [PHONE REDACTED] Emergency Phone Number: Within USA 1-[PHONE REDACTED]. Outside USA 001-[PHONE REDACTED] (Call Collect). RECOMMENDED USES: Diesel fuel additive SECTION 2 – HAZARD(S) IDENTIFICATION CLASSIFICATION UNDER 29 CFR 1910.1200(d) (NC=product does not meet classification criteria) 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Health Hazard Criteria Category Category Category Acute Toxicity, Oral: NC NC NC Acute Toxicity, Dermal: NC NC NC Acute Toxicity, Inhalation, Vapors: 3 3 3 Page 41 of 262 Page 41 of 262 Page 41 of 262 Page 41 of 262 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 2 of 13 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Health Hazard Criteria Category Category Category Skin Corrosion/Irritation: 2 2 2 Serious Eye Damage/Eye Irritation: 2 2 2 Respiratory Sensitization: NC NC NC Skin Sensitization: NC NC NC Germ Cell Mutagenicity: NC NC NC Carcinogenicity: 2 2 2 Reproductive Toxicity: NC NC NC Specific Target Organ Toxicity, Single Exposure: 3 3 3 Specific Target Organ Toxicity, Repeated or Prolonged Exposure: NC NC NC Aspiration Hazard: 1 1 1 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Physical Properties Criteria Category Category Category Explosives: NC NC NC Flammable Gases: NC NC NC Flammable Aerosols: NC NC NC Oxidizing Gases: NC NC NC Gases Under Pressure: NC NC NC Flammable Liquids: 3 3 3 Flammable Solids: NC NC NC Self-Reactive Chemicals: NC NC NC Pyrophoric Liquids: NC NC NC Pyrophoric Solids: NC NC NC Self-Heating Chemicals: NC NC NC Chemicals Which, in Contact with Water, Emit Flammable Gases: NC NC NC Oxidizing Liquids: NC NC NC Oxidizing Solids: NC NC NC Organic Peroxides: NC NC NC Corrosive to Metals: NC NC NC LABEL SIGNAL WORD, HAZARD STATEMENTS, SYMBOLS AND PRECAUTIONARY STATEMENTS UNDER 29 CFR 1910.1200(f): Please see the Note regarding product labeling in Section 16. Page 42 of 262 Page 42 of 262 Page 42 of 262 Page 42 of 262 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 3 of 13 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Signal Word Danger Danger Danger Hazard Statement(s): Flammable liquid and vapor. Toxic if inhaled. May be fatal if swallowed and enters airways. Harmful if swallowed. Causes skin and serious eye irritation. May cause respiratory irritation and drowsiness or dizziness. Symbols: The following symbols are for all treatment ratios. Precautionary Statement(s): Keep away from sparks and open flames. No smoking. Keep container closed. Use only non-sparking tools. Ground/Bond container and receiving equipment. Use explosion-proof pumps when pumping. Take precautionary measures against static discharge. Avoid breathing vapors. Use only outdoors or in a well-ventilated area. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves and eye protection. Store locked up and in cool, well ventilated place. KEEP OUT OF REACH OF CHILDREN. Hazards Not Otherwise Classified: None SECTION 3 – COMPOSITION / INFORMATION ON INGREDIENTS The specific chemical identity and exact concentration percentage has been withheld as a Trade Secret. Specific chemical information will be made available to health professionals in accordance with 29 CFR 1910.1200. INGREDIENTS CLASSIFIED AS HEALTH HAZARDS TREATMENT RATIO 1:400 Chemical Name Common Name/Synonyms CAS Number Concentration Petroleum Distillates Trade secret Trade secret 50 - 90 Hydroxy alkoxylate Trade secret Trade secret 4 - 10 Alkyl Nitrates Trade secret Trade secret 2 - 6 Naphthalene Not available 91-20-3 0.05 – 0.2 Page 43 of 262 Page 43 of 262 Page 43 of 262 Page 43 of 262 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 4 of 13 TREATMENT RATIO 1:1000 Chemical Name Common Name/Synonyms CAS Number Concentration Petroleum Distillates Trade secret Trade secret 40 - 90 Alkyl Nitrates Trade secret Trade secret 5 - 15 Aromatic Hydrocarbons Trade secret Trade secret 2 - 5 Hexan-1-ol, 2-ethyl Trade secret Trade secret 1 - 4 Naphthalene Not available 91-20-3 0.1 – 0.5 TREATMENT RATIO 1:1500 Chemical Name Common Name/Synonyms CAS Number Concentration Petroleum Distillates Trade secret Trade secret 20 - 55 Alkyl Nitrates Trade secret Trade secret 10 – 20 Aromatic Hydrocarbons Trade secret Trade secret 3 - 8 Hexan-1-ol, 2-ethyl Trade secret Trade secret 2 – 5 Naphthalene Not available 91-20-3 0.2 – 0.9 SECTION 4 - FIRST AID MEASURES As a precaution, exposure to liquids, vapors, mists and fumes should be minimized. EYE CONTACT: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice. SKIN CONTACT: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs get medical advice/attention. INHALATION: Remove person to fresh air and keep comfortable for breathing. Call a doctor. INGESTION: If swallowed, IMMEDIATELY call a doctor. Do NOT induce vomiting. SECTION 5 - FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Use water fog, alcohol-resistant foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPECIFIC HAZARDS: Vapors are heavier than air and may travel along the ground to a distant ignition source and flash back. See Section 10 for Stability and Reactivity. NOTE: EMPTY CONTAINERS CONTAIN COMBUSTIBLE VAPORS THAT CAN CAUSE FLASH FIRES OR EXPLOSIONS. CONTAINERS ARE SINGLE-TRIP CONTAINERS AND SHOULD NOT BE USED FOR ANY REASON AFTER BEING EMPTIED. DO NOT USE CUTTING TORCH Page 44 of 262 Page 44 of 262 Page 44 of 262 Page 44 of 262 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 5 of 13 EQUIPMENT OR ANY OTHER FLAME OR OTHER SOURCES OF IGNITION ON ANY EMPTY CONTAINER. PROTECTIVE EQUIPMENT AND PRECAUTIONS: Use standard protective equipment including self-contained breathing apparatus (SCBA). SECTION 6 - ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, AND EMERGENCY PROCEDURES: Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas. Eliminate all sources of ignition in the vicinity of the spill or released vapor. See Section 2 for Hazards Identification. See Section 4 for First Aid Measures. See Section 5 for Fire Fighting Information. See Section 8 for Personal Protective Equipment. SPILL CONTAINMENT AND CLEAN-UP: Eliminate potential sources of ignition. Stop leak if it can be done without risk. Dike and contain spill. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. Remove with vacuum trucks or pump to storage/salvage vessels. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly. A vapor suppressing foam may be used to reduce vapors. Local, state and federal laws and/or regulations may apply to releases and disposal of this material, as well as those materials and items employed in the clean-up releases. The user/responder will need to determine which local, state and federal laws and/or regulations are applicable. The National Response Center can be reached at 1-[PHONE REDACTED]. SECTION 7 - HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING: Avoid contact with eyes and skin. Use only with adequate ventilation. Use proper bonding and/or grounding procedures. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Keep away from ignition sources such as heat, sparks, and flames. No smoking. CONDITIONS FOR SAFE STORAGE: DO NOT USE OR STORE near heat, sparks, or flame. USE AND STORE ONLY IN A WELL-VENTILATED AREA. Handle containers with care. Keep container closed when not in use. Store locked up. STORAGE TEMPERATURE: Treatment Ratio Part Numbers: Storage Temperature: 1:400 Treatment Ratio 1016-06, 1016-09, 1025-06, 1025-12, 1080-06, 11016-06, 11016-09, 11025-06, 11025-12, 11041-04, 11080-06 -20F to 104F (-29C to 40C) 1:1,000 Treatment Ratio 1000, 1128-04, 1060-01 0F to 104F (-18C to 40C) Page 45 of 262 Page 45 of 262 Page 45 of 262 Page 45 of 262 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 6 of 13 1:1,500 Treatment Ratio 1050-02, 1055-01, 1260-01 10F to 104F (-12C to 40C) EMPTY CONTAINER WARNING: EMPTY CONTAINERS MAY CONTAIN COMBUSTIBLE VAPORS AND CAN BE DANGEROUS. SEE SECTION 5 FOR FIRE AND EXPLOSION HAZARD DATA. SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES: CAS # OSHA ACGIH NIOSH PEL TLV STEL REL STEL IDLH Note 100-41-4 100 ppm 20 ppm not est. 100 ppm 125 ppm 800 ppm (LEL) n/a Naphthalene 91-20-3 10 ppm 10 ppm not est. 10 ppm 15 ppm 250 ppm skin Petroleum Distillates n/a 500 ppm not est. not est. not est. not est. not est. n/a Cumene 98-82-8 50 ppm 50 ppm not est. 50 ppm not est. 900 ppm (LEL) Skin Toluene 108-88-3 100 ppm 20 ppm not est. 100 ppm 150 ppm 500 ppm Skin Hydroxy Alkoxylate Proprietary 50 ppm 20 ppm not est. 5 ppm not est. not est. skin ENGINEERING CONTROLS: The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Local exhaust ventilation is recommended to control exposure. PERSONAL PROTECTIVE EQUIPMENT (PPE): Eyes and Face: Eye protection such as safety glasses or chemical goggles is recommended if contact is likely. Skin: Protective chemical/oil resistant gloves are recommended. Wear additional protective clothing as appropriate. Respiratory: Wear a NIOSH/MSHA approved respirator as necessary. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Practice good housekeeping. NOTE: These precautions are for room temperature handling. Page 46 of 262 Page 46 of 262 Page 46 of 262 Page 46 of 262 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 7 of 13 SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES 1:400 Treatment Ratio 1:1000 Treatment Ratio 1:1500 Treatment Ratio Appearance Liquid, brown Liquid, brown Liquid, brown Odor Aromatic solvent Aromatic solvent Aromatic solvent Odor Threshold Not available Not available Not available pH 7 – 8 basic) 7 – 8 basic) 7 – 8 basic) Melting point/Freezing point Not available Not available Not available Initial Boiling Point and Boiling Range 300F (149C) 300F (149C) 300F (149C) Flash Point 105F (40.5C) 116F (46.6C) 121F (49.4C) Evaporation Rate Not available Not available Not available Flammability Not available Not available Not available Upper / lower Flammability or Explosive Limits Not available Not available Not available Vapor Pressure 0.2 – 0.95 0.2 – 0.95 0.2 – 0.95 Vapor Density >5.0 >5.0 >5.0 Relative Density/Specific Gravity (at 60°F) 0.910 0.912 0.896 Solubility Not available Not available Not available Partition Coefficient; n-octanol / water Not available Not available Not available Auto-ignition Temperature Not available Not available Not available Decomposition temperature Not available Not available Not available Viscosity Not available Not available Not available Pour Point -55F (-13C) -30F (1.1C) -15F (9.4C) SECTION 10 - STABILITY AND REACTIVITY REACTIVITY: see Incompatible Materials below CHEMICAL STABILITY: This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. POSSIBILITY OF HAZARDOUS REACTION: Hazardous polymerization will not occur. CONDITIONS TO AVOID: Flames, high energy ignition sources, and elevated temperatures. INCOMPATIBLE MATERIALS: May react with strong oxidizing agents, such as; chlorates, nitrates, peroxides, nitrogen oxides, sulfur oxides, etc.; alkalis; nitric acid; sulfuric acid; aluminum; brass; copper; reducing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon oxides, products of incomplete combustion. Page 47 of 262 Page 47 of 262 Page 47 of 262 Page 47 of 262 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 8 of 13 SECTION 11 - TOXICOLOGICAL INFORMATION LIKELY ROUTES OF EXPOSURE INGESTION INHALATION SKIN CONTACT EYE CONTACT SKIN ABSORPTION 1:400 Treatment Ratio X X X X 1:1000 Treatment Ratio X X X X 1:1500 Treatment Ratio X X X X RELATED TO PHYSICAL, CHEMICAL AND TOXICOLOGICAL CHARACTERISTICS: Breathing of high vapor concentrations may cause dizziness, light- headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness. The vapor or fumes from this material may cause respiratory irritation. Breathing this material at elevated concentrations causes central nervous system effects. Central nervous system effects may include headache, dizziness, nausea, vomiting, weakness, loss of coordination, blurred vision, drowsiness, confusion or disorientation. At extreme exposures, central nervous system effects may include respiratory depression, tremors, or convulsions, loss of consciousness, coma or death. DELAYED AND IMMEDIATE EFFECTS AND CHRONIC EFFECTS FROM SHORT- AND LONG-TERM EXPOSURE: Repeated skin exposure to a component of this product may cause irritation, even a burn; may cause a more severe response on covered skin, such as under clothing or gloves. Inhalation exposure to a component of this product has caused fetotoxicity in the presence of maternal toxicity in animals. NUMERICAL MEASURES OF TOXICITY Note: the information provided below are estimates; testing of the product is not available. Treatment Ratio Acute Oral Toxicity (ATEmix estimate) Acute Dermal Toxicity (ATEmix estimate) Acute Inhalation (ATEmix estimate) 1:400 Treatment Ratio Does not meet criteria Does not meet criteria 7.10 (vapors) 1:1,000 Treatment Ratio Does not meet criteria Does not meet criteria 8.56 (vapors) 1:1,500 Treatment Ratio Does not meet criteria Does not meet criteria 7.48 (vapors) SENSITIZATION: No information available. MUTAGENICITY: No information available. CARCINOGENICITY LISTINGS – the following chemicals are listed as indicated: Page 48 of 262 Page 48 of 262 Page 48 of 262 Page 48 of 262 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 9 of 13 Chemical List Cumene IARC, NTP IARC Naphthalene IARC, NTP REPODUCTIVE TOXICITY: No information available. TERATOGENICITY/EMBRYOTOXICITY: Hydroxy Alkoxylate has caused fetotoxicity with maternal toxicity. This product contains a component of a complex mixture (Xylenes (1330-20- that has been shown to cause teratogenicity and/or embryotoxicity. SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): Respiratory tract irritation, drowsiness/dizziness. SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): No information available ASPIRATION HAZARD: Aspiration hazard identified. SECTION 12 - ECOLOGICAL INFORMATION ECOTOXICITY: This material is expected to be toxic to aquatic organisms. PERSISTENCE AND DEGRADABILITY: No information available. BIOACCUMULATIVE POTENTIAL: No information available. MOBILITY IN SOIL: No information available. OTHER ADVERSE EFFECTS: No information available. SECTION 13 - DISPOSAL CONSIDERATIONS RCRA Information: Disposal of unused product may be subject to RCRA hazardous waste regulations (40 CFR Part 261). Disposal of the used product may also be regulated as hazardous waste due to resulting mixture characteristics, mixture components or product use. Such changes to the product may result in different and/or additional hazardous waste codes. Potential RCRA waste code based on the product as shipped: D001 IGNITABILITY State or local laws may impose additional regulatory requirements regarding disposal. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. EMPTY CONTAINER WARNING: EMPTY CONTAINERS MAY CONTAIN COMBUSTIBLE VAPORS AND CAN BE DANGEROUS. SEE SECTION 5 FOR FIRE AND EXPLOSION Page 49 of 262 Page 49 of 262 Page 49 of 262 Page 49 of 262 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 10 of 13 HAZARD DATA. Dispose or recycle empty containers appropriately per local, state and federal regulations. SECTION 14 - TRANSPORTATION INFORMATION The following part numbers are not regulated by DOT: 1:400 Treatment Ratio 1016-06, 1016-09, 1025-06, 1025-09, 1025-12, 1080-06, 11016-06, 11016-09, 11025-06, 11025-12, 1080-06 1:1,000 Treatment Ratio 1128-04 1:1,500 Treatment Ratio 1050-02, 1055-01 The following part numbers are regulated by DOT: 1:1,000 Treatment Ratio 1060-01 PROPER SHIPPING NAME: Combustible Liquid, N.O.S., (Petroleum Distillates) Marine Pollutant Nitrate) HAZARD CLASS: Combustible Liquid I.D. NUMBER: NA 1993 PACKING GROUP: III PLACARDING: Combustible Liquid MARINE POLLUTANT: Yes 1:1,000 Treatment Ratio 1000 PROPER SHIPPING NAME: Combustible Liquid, N.O.S., (Petroleum Distillates) Marine Pollutant Nitrate) RQ (Xylene, Naphthalene) HAZARD CLASS: Combustible Liquid I.D. NUMBER: NA 1993 PACKING GROUP: III PLACARDING: Combustible Liquid MARINE POLLUTANT: Yes PRODUCT RQ: 100 lbs. (45.45 kg) – Xylene, Naphthalene 1:1,500 Treatment Ratio 1260-01 PROPER SHIPPING NAME: Combustible Liquid, N.O.S., (Petroleum Distillates) Marine Pollutant Nitrate) HAZARD CLASS: Combustible Liquid I.D. NUMBER: NA 1993 PACKING GROUP: III PLACARDING: Combustible Liquid MARINE POLLUTANT: Yes Page 50 of 262 Page 50 of 262 Page 50 of 262 Page 50 of 262 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 11 of 13 SECTION 15 - REGULATORY INFORMATION §14(a) Consumer Product Safety Act General Certificate of Conformity Power Service Products, Inc. certifies that this product meets the statutory and regulatory requirements of the US Consumer Products Safety Act, the Federal Hazardous Substances Act, and the Poison Prevention Packaging Act of 1970, as applicable. The Power Service products are manufactured in the United States in Weatherford, Texas, unless otherwise indicated on the product label. The product manufacture lot code is stamped on the product container. This Certification is based upon a reasonable testing program conducted by Power Service Products, Inc. which includes a quality control program incorporating, as necessary, confirmation of compliance by component suppliers. Third-party testing is not required to certify compliance. Further details may be obtained by contacting the Power Service Products, Inc. EHS Manager at 1-[PHONE REDACTED]. Contents of this SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. TSCA STATUS: All chemical substances found in this product comply with the Toxic Substances Control Act inventory reporting requirements. EPA SARA TITLE III CHEMICAL LISTINGS: Section 302 Extremely Hazardous Substances: None Sections 311/ 312 Hazard Class: Acute Health Effects: Yes Sudden Release of Pressure Hazard: No Chronic Health Effects: Yes Reactivity Hazard: No Fire Hazard: Yes NFPA (NATIONAL FIRE PROTECTION ASSOCIATION) RATING: HEALTH: 2 FIRE: 2 REACTIVITY: 0 Section 313: Specific chemical information is being withheld as a Trade Secret. The following chemicals subject to the reporting requirements of EPCRA Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (40 CFR Part 372) may be present in this product at a concentration that does not exceed the specified upper weight percentage. Treatment Ratio CAS Number Chemical Name Max % 1:400 Treatment Ratio 100-41-4 24.0 NA Glycol Ether Category 8.0 Page 51 of 262 Page 51 of 262 Page 51 of 262 Page 51 of 262 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 12 of 13 Treatment Ratio CAS Number Chemical Name Max % 91-20-3 Naphthalene 1.0 98-82-8 Cumene 4.0 108-88-3 Toluene 4.0 1:1000 Treatment Ratio 100-41-4 19.0 91-20-3 Naphthalene 1.0 98-82-8 Cumene 3.5 108-88-3 Toluene 3.5 1:1,500 Treatment Ratio 100-41-4 12.0 91-20-3 Naphthalene 1.0 98-82-8 Cumene 2.0 108-88-3 Toluene 2.0 State or local laws may impose additional regulatory requirements for components of this material. It is the responsibility solely of the Employer to maintain compliance with State and Local reporting. This product contains a chemical known to the state of California to cause cancer and/or birth defects or other reproductive harm: toluene, cumene, naphthalene. SECTION 16 – OTHER INFORMATION DATE OF PREPARATION / REVISION: May 30, 2015 NOTE regarding product labeling: The OSHA Hazard Communication Standard applies to hazardous chemicals known to be present in the workplace. However, the labeling and Safety Data Sheet requirements do not apply to consumer products when they are used in the workplace for the purposes intended by the manufacturer and the use results in a duration and frequency of exposure which is not greater than the range of exposures that could reasonably be experienced by consumers when used for the intended purpose. Power Service Products intends for product packaged in 1 gallon or smaller containers to be used by consumers and has labeled those containers as required under the Consumer Product Safety Commission regulations. Power Service Products intends for product packaged in containers larger than 1 gallon to be used in the workplace and has labeled those products as required by the OSHA Hazard Communication Standard. The Consumer Product Safety Commission and OSHA Hazard Communication Standard labeling requirements are different and variations between the consumer and industrial labels may occur. It is the employer’s responsibility to purchase the appropriate product for use in the workplace. The information contained herein is offered in good faith and is believed to be accurate based on the data available to us as of the date of SDS preparation. The information in this document applies to this specific product as supplied. It may not be appropriate for this product if the product is used in combination with other materials. The information in this document is not intended to constitute product performance information. Some of the information presented and conclusions drawn herein are from sources other than direct test data on the product. No statement shall be construed as an endorsement of any product or process. The recommended Page 52 of 262 Page 52 of 262 Page 52 of 262 Page 52 of 262 ---PAGE BREAK--- Revised: May 30, 2015 Supersedes: April 1, 2015 POWER SERVICE DIESEL FUEL SUPPLEMENT +CETANE BOOST Page 13 of 13 industrial hygiene and safe handling procedures are believed to be valid in the context of the intended use as described in product labeling. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate. You are urged to obtain material safety data sheets for all products you buy, process, use or distribute, and are encouraged to advise those who may come in contact with such products of the information contained therein. Regulatory requirements are subject to change and may differ between locations. It is the buyer’s/user’s responsibility to ensure that his activities comply with all federal, state, provincial or local laws. No warranty or guarantee is expressed or implied with respect to this product, the accuracy and sufficiency of the data or recommendations herein, or the results to be obtained from the use of this product. IN NO EVENT SHALL POWER SERVICE PRODUCTS, INC. BE LIABLE FOR ANY LOSS, CLAIM, DAMAGE OR LIABILITY OF ANY KIND, WHICH MAY ARISE FROM OR IN CONNECTION WITH THE INFORMATION CONTAINED IN THIS DOCUMENT OR FROM THE USE, HANDLING OR STORAGE OF THE PRODUCT BY THE BUYER/USER, WHETHER DIRECT, INDIRECT, OR CONSEQUENTIAL, OR FOR ANY CLAIM BY ANY THIRD PARTY, BEYOND THE PURCHASE PRICE OR REPLACEMENT OF THE PRODUCT IN CONNECTION WITH WHICH SUCH LOSS, CLAIM, DAMAGE OR LIABILITY AROSE. THE FOREGOING LIMITATIONS APPLY REGARDLESS OF THE CAUSES OR CIRCUMSTANCES GIVING RISE TO SUCH LOSS, CLAIM, DAMAGE OR LIABILITY, EVEN IF SUCH LOSS, CLAIM, DAMAGE, OR LIABILITY IS BASED ON NEGLIGENCE OR OTHER TORTS OR BREACH OF CONTRACT. Page 53 of 262 Page 53 of 262 Page 53 of 262 Page 53 of 262 ---PAGE BREAK--- Revision Date: 01-May-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: DUST MOP / DUST CLOTH TREATMENT (AEROSOL) Product Number: 6099 Recommended Use: Cleaning agent Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification GHS Label Elements Signal Word: Danger Hazard Statements: Extremely flammable aerosol. Contains gas under pressure; may explode if heated Precautionary Statements: Prevention: Keep away from heat/sparks/open flames/hot surfaces. — No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Response: -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Protect from sunlight. Do not expose to temperatures exceeding 122°F (50°C) Store in a well-ventilated place Disposal: Not Applicable Hazards Not Otherwise Classified: Not Applicable Flammable Aerosols Category 1 Gases Under Pressure Page 1 / 5 Liquefied gas Symbols: Page 54 of 262 Page 54 of 262 Page 54 of 262 Page 54 of 262 ---PAGE BREAK--- 6099 - DUST MOP / DUST CLOTH TREATMENT (AEROSOL) Revision Date: 01-May-2015 Other Information: • May be harmful if swallowed. • May cause eye irritation. • May cause skin irritation. • Inhalation of vapors or mist may cause respiratory irritation. • Keep out of reach of children. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 40-70 petroleum distillates 64742-47-8 5-10 white mineral oil 8042-47-5 5-10 N-butane 106-97-8 3-7 propane 74-98-6 1-5 decaglyceryl monooleate 9007-48-1 1-5 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Water spray (fog), Foam Specific Hazards Arising from the Chemical: Extremely flammable aerosol. Exposure to high temperature may cause containers to burst. Bursting aerosol containers may be propelled from fire at high speed. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Water may be used to cool closed containers to prevent pressure build-up and possible auto ignition or explosion when exposed to extreme heat. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 7. HANDLING AND STORAGE Page 2 / 5 Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Wash thoroughly after handling. Page 55 of 262 Page 55 of 262 Page 55 of 262 Page 55 of 262 ---PAGE BREAK--- 6099 - DUST MOP / DUST CLOTH TREATMENT (AEROSOL) Revision Date: 01-May-2015 Storage Conditions: NFPA 30B Level 1 Aerosol. Do not store in direct sunlight or above 122 F° / 50 Exposure to high temperature may cause containers to burst. Keep out of the reach of children. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: . Chemical Name ACGIH TLV OSHA PEL NIOSH N-butane 106-97-8 TWA: 1000 ppm (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 TWA: 800 ppm TWA: 1900 mg/m3 propane 74-98-6 TWA: 1000 ppm TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Personal Protective Equipment Eye/Face Protection: Not required with expected use. Skin and Body Protection: Not required with expected use. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatible Materials: Strong oxidizing agents. Strong acids. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Aerosol Color: White emulsion Odor: Bland pH: 8.0-9.0 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 132 °C / 270 °F (Product without propellant) Estimated Flash Point: < -58 °C / < -72 °F (Propellant-estimated) Evaporation Rate: < 1 Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 0.95 (Product without propellant) Solubility(ies): No information available. Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 3 / 5 Decomposition Temperature: No information available. Viscosity: No information available. Page 56 of 262 Page 56 of 262 Page 56 of 262 Page 56 of 262 ---PAGE BREAK--- 6099 - DUST MOP / DUST CLOTH TREATMENT (AEROSOL) Revision Date: 01-May-2015 Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Pain and redness. -Skin Contact: Drying of the skin. -Inhalation: Nasal discomfort and coughing. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Target Organ Effects: Central nervous system. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 27233 mg/kg ATEmix (dermal): 20202 mg/kg ATEmix (inhalation-gas): 3021468 mg/l Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available petroleum distillates 64742-47-8 > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5.2 mg/L ( Rat ) 4 h white mineral oil 8042-47-5 > 5000 mg/kg ( Rat ) Not Available Not Available N-butane 106-97-8 Not Available Not Available = 658 mg/L ( Rat ) 4 h propane 74-98-6 Not Available Not Available = 658 mg/L ( Rat ) 4 h Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Microorganisms Crustacea petroleum distillates 64742-47-8 Not Available 45: 96 h Pimephales promelas mg/L LC50 flow-through 2.2: 96 h Lepomis macrochirus mg/L LC50 static 2.4: 96 h mykiss mg/L LC50 static Not Available 4720: 96 h Den-dronereides heteropoda mg/L LC50 white mineral oil 8042-47-5 Not Available 10000: 96 h Lepomis macrochirus mg/L LC50 Not Available Not Available Persistence and Degradability: No information available. Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Page 4 / 5 Contaminated Packaging: Pressurized container: Do not pierce or burn, even after use. Dispose of in accordance with federal, state and local regulations. Page 57 of 262 Page 57 of 262 Page 57 of 262 Page 57 of 262 ---PAGE BREAK--- 6099 - DUST MOP / DUST CLOTH TREATMENT (AEROSOL) Revision Date: 01-May-2015 14. TRANSPORT INFORMATION DOT: UN/ID No: UN1950 Proper Shipping Name: Aerosols Hazard Class: 2.1 Special Provisions: This product meets the exception requirements of section 49 CFR 173.306 as a limited quantity and may be shipped as a limited quantity. 15. REGULATORY INFORMATION TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product does not contain listed substances above the "de minimus" level SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: Yes Reactive Hazard: No California Proposition 65 This product does not contain any Proposition 65 chemicals 16. OTHER INFORMATION Revision Date: 01-May-2015 Reasons for Revision: No information available. Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 1 Flammability: 1 Instability: 0 Special: N/A HMIS Page 5 / 5 Health Hazards: 1 Flammability: 2 Physical Hazards: 2 Page 58 of 262 Page 58 of 262 Page 58 of 262 Page 58 of 262 ---PAGE BREAK--- Page: 1 SAFETY DATA SHEET Revision Date: 09/17/2012 Print Date: 1/13/2015 MSDS Number: R0336576 Eagle One™ ETCHING MAG WHEEL CLEANER 836604 Version: 5.1 Page 1 / 14 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Ashland Regulatory Information Number 1-[PHONE REDACTED] P.O. Box 2219 Telephone [PHONE REDACTED] Columbus, OH 43216 Emergency telephone number 1-800-ASHLAND (1-800-274- 5263) Product name Eagle One™ ETCHING MAG WHEEL CLEANER Product code 836604 2. HAZARDS IDENTIFICATION Emergency Overview Appearance: liquid, colourless DANGER! CONTAINS HYDROFLUORIC ACID. MAY BE HARMFUL. MAY CAUSE SEVERE BURNS OF RESPIRATORY AND DIGESTIVE TRACTS. MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN. CAUSES SEVERE BURNS OF THE EYES AND SKIN. Potential Health Effects Exposure routes Inhalation, Skin absorption, Skin contact, Eye Contact, Ingestion Eye contact Can cause permanent eye injury. include stinging, tearing, redness, and swelling of eyes. Can injure the cornea and cause blindness. Skin contact Can cause permanent skin damage. may include redness, burning, and swelling of skin, burns, and other skin damage. Exposure can cause severe irritation and fluoride-like burns which may not be immediately evident. Ingestion Page 59 of 262 Page 59 of 262 Page 59 of 262 Page 59 of 262 ---PAGE BREAK--- Page: 2 SAFETY DATA SHEET Revision Date: 09/17/2012 Print Date: 1/13/2015 MSDS Number: R0336576 Eagle One™ ETCHING MAG WHEEL CLEANER 836604 Version: 5.1 Page 2 / 14 Swallowing this material may be harmful or fatal. may include severe stomach and intestinal irritation (nausea, vomiting, diarrhea), abdominal pain, and vomiting of blood. Swallowing this material may cause burns and destroy tissue in the mouth, throat, and digestive tract. Low blood pressure and shock may occur as a result of severe tissue injury. Inhalation It is possible to breathe this material under certain conditions of handling and use (for example, during heating, spraying, or stirring). Breathing this material may be harmful or fatal. may include severe irritation and burns to the nose, throat, and respiratory tract. are not expected at air concentrations below the recommended exposure limits, if applicable (see Section Aggravated Medical Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, lung (for example, asthma-like conditions), Upper respiratory tract, skin, Liver, kidney, Central nervous system, bone, Exposure to this material may aggravate any preexisting condition sensitive to a decrease in available oxygen, such as chronic lung disease, coronary artery disease or anemias., Individuals with preexisting heart disorders maybe more susceptible to (irregular heartbeats) if exposed to high concentrations of this material. Signs and of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways), Cough, sneezing, choking, Headache, Difficulty in breathing, lung edema (fluid buildup in the lung tissue), damage to the mouth, throat, and/or airways Target Organs Repeated, prolonged overexposure to inorganic fluoride compounds may result in gastrointestinal disturbances, loss of weight, anemia (reduced number of red blood cells), diseases of the teeth,and skeletal fluorosis. Skeletal fluorosis is characterized by bone and joint pain, limited motion in the joints or spine, increased bone density which can cause the bones to become brittle, and hardening of ligaments., Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals:, nervous system effects, blood abnormalities, liver abnormalities, kidney damage, Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans:, damage to tooth enamel, effects on lung function, respiratory tract damage (nose, throat, and airways) Carcinogenicity Page 60 of 262 Page 60 of 262 Page 60 of 262 Page 60 of 262 ---PAGE BREAK--- Page: 3 SAFETY DATA SHEET Revision Date: 09/17/2012 Print Date: 1/13/2015 MSDS Number: R0336576 Eagle One™ ETCHING MAG WHEEL CLEANER 836604 Version: 5.1 Page 3 / 14 This product contains sulfuric acid. The International Agency for Research on Cancer (IARC) and the National Toxicology Program (NTP) have listed strong-inorganic-acid mists containing sulfuric acid as causing cancer in humans. Reproductive hazard Inhalation of sulfuric acid fumes was not harmful to the fetus in laboratory animal studies even at levels that caused some harm to the pregnant animals., This material (or a component) has been shown to cause harm to the fetus in laboratory animal studies. Harm to the fetus occurs only at exposure levels that harm the pregnant animal. The relevance of these findings to humans is uncertain. Other information Hydrofluoric acid has been shown to cause permanent changes in the DNA of insect germ cells. Changes in these cells can be passed to the next generation. The relevance of this finding to human health is uncertain. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Components CAS-No. / Trade Secret No. Concentration PHOSPHORIC ACID 7664-38-2 >=10-<15% SULFURIC ACID 7664-93-9 HYDROFLUORIC ACID 7664-39-3 ALCOHOL ETHOXYLATE SODIUM 1-OCTANESULFONATE 5324-84-5 4. FIRST AID MEASURES Eyes If material gets into the eyes, immediately flush eyes gently with water for at least 15 minutes while holding eyelids apart. If develop as a result of vapor exposure, immediately move individual away from exposure and into fresh air before flushing as recommended above. Seek immediate medical attention. Skin Page 61 of 262 Page 61 of 262 Page 61 of 262 Page 61 of 262 ---PAGE BREAK--- Page: 4 SAFETY DATA SHEET Revision Date: 09/17/2012 Print Date: 1/13/2015 MSDS Number: R0336576 Eagle One™ ETCHING MAG WHEEL CLEANER 836604 Version: 5.1 Page 4 / 14 Immediately flush contaminated skin with large quantities of cool running water for 5 minutes. Remove contaminated clothing while flushing contaminated skin. Immediately after washing, apply 2.5% calcium gluconate gel to all affected skin areas. (Note: If gel is not prepared within 5 minutes, continue flushing until gel is prepared.) The gel should be massaged into the affected skin by personnel wearing gloves to prevent skin contamination during first aid. Gel should be applied every 15 minutes and massaged continuously. Instead of calcium gluconate treatment, the affected areas may be soaked in iced 0.13% benzalkonium chloride solution (Zephiran chloride). Use ice cubes rather than shaved ice to prevent frostbite. If it is not practical to immerse affected area, towels should be soaked with iced 0.13% benzalkonium chloride solution and used as compresses for the burned area. Compresses should be changed every 2-3 minutes and continued until pain is relieved or victim is seen by a physician. If neither calcium gluconate nor benzalkonium chloride is available, use an iced saturated water solution of magnesium sulfate (Epsom salts), or if that is not available, iced 70% alcohol or ice water. Local anesthetics should be avoided since relief of pain indicates success of the treatment. ***Get medical attention as soon as possible.*** ::::NOTE::::Calcium gluconate gel can be prepared by mixing a 10 milliliter ampule of calcium gluconate with a 2-ounce tube of K-Y jelly (Johnson & Johnson). After a jar of this mixture has been opened and used, it should be discarded to prevent bacterial or chemical contamination. Ingestion Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. Inhalation If develop, immediately move individual away from exposure and into fresh air. Seek immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial respiration. If breathing is difficult, administer oxygen. Notes to physician Hazards: This product contains hydrofluoric acid (HF). Acute local effects from HF exposure are concentration-dependent. If untreated or exposure is prolonged, even dilute solutions of HF can cause delayed toxicity following penetration to subcutaneous tissue. Acute systemic toxicity is largely dependent upon the total amount of fluoride ion absorbed. Thus ingestion, skin contact or significant inhalation can cause severe systemic effects including electrolyte (calcium, magnesium, potassium) and acid-base abnormalities with resulting cardiovascular effects. Exposure of of the body surface area with any concentration of HF may predispose the patient to development of hypocalcemia. Chronic exposure to less than acutely toxic amounts of HF is a low toxicity hazard. Repeated exposure and absorption of 10-80 mg of fluoride per day may produce systemic fluorosis. Page 62 of 262 Page 62 of 262 Page 62 of 262 Page 62 of 262 ---PAGE BREAK--- Page: 5 SAFETY DATA SHEET Revision Date: 09/17/2012 Print Date: 1/13/2015 MSDS Number: R0336576 Eagle One™ ETCHING MAG WHEEL CLEANER 836604 Version: 5.1 Page 5 / 14 Treatment: No information available. 5. FIREFIGHTING MEASURES Suitable extinguishing media Dry chemical, Foam, Carbon dioxide (CO2) Hazardous combustion products Oxides of phosphorus, corrosive vapors, sulfur oxides, toxic fumes, acid vapors, Hydrogen fluoride Precautions for fire-fighting Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). Use water spray to cool fire exposed containers and structures until fire is out if it can be done with minimal risk. Avoid spreading burning material with water used for cooling purposes. NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB 6. ACCIDENTAL RELEASE MEASURES Personal precautions For personal protection see section 8. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions Prevent spreading over a wide area (e.g. by containment or oil barriers). Do not let product enter drains. Do not flush into surface water or sanitary sewer system. Methods for cleaning up Keep in suitable, closed containers for disposal. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Other information Comply with all applicable federal, state, and local regulations. Page 63 of 262 Page 63 of 262 Page 63 of 262 Page 63 of 262 ---PAGE BREAK--- Page: 6 SAFETY DATA SHEET Revision Date: 09/17/2012 Print Date: 1/13/2015 MSDS Number: R0336576 Eagle One™ ETCHING MAG WHEEL CLEANER 836604 Version: 5.1 Page 6 / 14 7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Storage Store in a cool, dry, ventilated area. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines PHOSPHORIC ACID 7664-38-2 ACGIH time weighted average 1 mg/m3 ACGIH Short term exposure limit 3 mg/m3 NIOSH Recommended exposure limit (REL): 1 mg/m3 NIOSH Short term exposure limit 3 mg/m3 OSHA Z1 Permissible exposure limit 1 mg/m3 SULFURIC ACID 7664-93-9 ACGIH time weighted average 0.2 mg/m3 Thoracic fraction. NIOSH Recommended exposure limit (REL): 1 mg/m3 OSHA Z1 Permissible exposure limit 1 mg/m3 HYDROFLUORIC ACID 7664-39-3 ACGIH time weighted average 0.5 ppm ACGIH Ceiling Limit Value: 2 ppm NIOSH Recommended exposure limit (REL): 3 ppm NIOSH Recommended exposure limit (REL): 2.5 mg/m3 NIOSH Ceiling Limit Value and Time Period (if specified): 6 ppm NIOSH Ceiling Limit Value and Time Period (if specified): 5 mg/m3 OSHA Z2 time weighted average 3 ppm General advice These recommendations provide general guidance for handling this product. Personal protective equipment should be selected for individual applications and should consider factors which affect Page 64 of 262 Page 64 of 262 Page 64 of 262 Page 64 of 262 ---PAGE BREAK--- Page: 7 SAFETY DATA SHEET Revision Date: 09/17/2012 Print Date: 1/13/2015 MSDS Number: R0336576 Eagle One™ ETCHING MAG WHEEL CLEANER 836604 Version: 5.1 Page 7 / 14 exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities. Exposure controls Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Mechanical ventilation systems used to ventilate corrosive storage or process areas must be designed with components that are corrosion resistant. Eye protection Wear chemical splash goggles and face shield when there is potential for exposure of the eyes or face to liquid, vapor or mist. Maintain eye wash station in immediate work area. Skin and body protection Wear resistant gloves (consult your safety equipment supplier). Discard gloves that show tears, pinholes, or signs of wear. Wear appropriate chemical impervious clothing and boots whenever there is potential for skin contact with product. Launder clothing before reuse. Maintain safety shower at all locations where skin contact could occur. Contact your local safety equipment supplier to assist the facility in determining proper selection of personal protective equipment for the applications/operations present at your facility. Respiratory protection A NIOSH-approved air-purifying respirator with an appropriate cartridge and/or filter may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits (if applicable) or if overexposure has otherwise been determined. Protection provided by air- purifying respirators is limited. Use a positive pressure, air-supplied respirator if there is any potential for uncontrolled release, exposure levels are not known or any other circumstances where an air- purifying respirator may not provide adequate protection. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state liquid Colour colourless Boiling point/boiling range 195.1 °F / 90.6 °C @ 1,013.33 hPa Calculated Phase Transition Liquid/Gas pH 1 Flash point > 212 °F / > 100 °C Page 65 of 262 Page 65 of 262 Page 65 of 262 Page 65 of 262 ---PAGE BREAK--- Page: 8 SAFETY DATA SHEET Revision Date: 09/17/2012 Print Date: 1/13/2015 MSDS Number: R0336576 Eagle One™ ETCHING MAG WHEEL CLEANER 836604 Version: 5.1 Page 8 / 14 Evaporation rate Ethyl Ether Vapour pressure 23.333 hPa @ 68 °F / 20 °C Calculated Vapor Pressure Density 1.1 g/cm3 9.46 lb/gal @ 60.00 °F / 15.56 °C 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid excessive heat Incompatible products Fluorine, nitromethane, Strong oxidizing agents, strong reducing agents, Sulphides, sulphites, Acids, Acid Aldehydes, Alcohols, Amines, Bases, carbide, carbonates, Combustible material, Copper, Cyanides, glycols, halogens, Nitriles, Organic materials, organic nitro compounds, Powdered metals, sulfides Hazardous decomposition products Oxides of phosphorus, corrosive vapors, Sulphur oxides, toxic fumes, acid vapors, Hydrogen fluoride Hazardous reactions Product will not undergo hazardous polymerization. 11. TOXICOLOGICAL INFORMATION Acute oral toxicity Acute oral toxicity - Product : no data available Acute oral toxicity - Components PHOSPHORIC ACID : LD 50: ca. 2,600 mg/kg Species: Rat Page 66 of 262 Page 66 of 262 Page 66 of 262 Page 66 of 262 ---PAGE BREAK--- Page: 9 SAFETY DATA SHEET Revision Date: 09/17/2012 Print Date: 1/13/2015 MSDS Number: R0336576 Eagle One™ ETCHING MAG WHEEL CLEANER 836604 Version: 5.1 Page 9 / 14 SULFURIC ACID : LD 50: 2,140 mg/kg Species: Rat ALCOHOL ETHOXYLATE : LD50: > 2,000 mg/kg Species: rat Remarks: Based on a similar product formulation. Acute inhalation toxicity Acute inhalation toxicity - Product : no data available Acute inhalation toxicity - Components PHOSPHORIC ACID : Remarks: Corrosive to respiratory system Acute dermal toxicity Acute dermal toxicity - Product : no data available Acute dermal toxicity - Components PHOSPHORIC ACID : LD 50: 2,740 mg/kg Species: Rabbit HYDROFLUORIC ACID : LD Lo: 500 mg/kg Species: Mouse ALCOHOL ETHOXYLATE : LD 50: 3,300 mg/kg Species: Rat Acute toxicity (other routes of administration) Acute toxicity (other routes of administration) : no data available 12. ECOLOGICAL INFORMATION Biodegradability Biodegradability - Product : no data available Biodegradability - Components ALCOHOL ETHOXYLATE : Remarks: Expected to be biodegradable Bioaccumulation Page 67 of 262 Page 67 of 262 Page 67 of 262 Page 67 of 262 ---PAGE BREAK--- Page: 10 SAFETY DATA SHEET Revision Date: 09/17/2012 Print Date: 1/13/2015 MSDS Number: R0336576 Eagle One™ ETCHING MAG WHEEL CLEANER 836604 Version: 5.1 Page 10 / 14 Bioaccumulation - Product : no data available Ecotoxicity effects Toxicity to fish Toxicity to fish - Product : no data available Toxicity to fish - Components SULFURIC ACID : LC 50: 42 mg/l Exposure time: 96 h Species: Western mosquitofish (Gambusia affinis) Method: Static Remarks: Mortality ALCOHOL ETHOXYLATE : 8.5 mg/l Exposure time: 96 h Species: Pimephales promelas (fathead minnow) Remarks: Based on a similar product formulation. Toxicity to daphnia and other aquatic invertebrates Toxicity to daphnia and other aquatic invertebrates - Product : no data available Toxicity to daphnia and other aquatic invertebrates - Components ALCOHOL ETHOXYLATE : 5.3 mg/l Species: Daphnia Remarks: Based on a similar product formulation. Toxicity to algae Toxicity to algae - Product : no data available Toxicity to bacteria Toxicity to bacteria - Product : no data available Page 68 of 262 Page 68 of 262 Page 68 of 262 Page 68 of 262 ---PAGE BREAK--- Page: 11 SAFETY DATA SHEET Revision Date: 09/17/2012 Print Date: 1/13/2015 MSDS Number: R0336576 Eagle One™ ETCHING MAG WHEEL CLEANER 836604 Version: 5.1 Page 11 / 14 13. DISPOSAL CONSIDERATIONS Waste disposal methods Dispose of in accordance with all applicable local, state and federal regulations. 14. TRANSPORT INFORMATION REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP MARINE POLLUTANT / LTD. QTY. U.S. DOT - ROAD 3264 LIQUIDO CORROSIVO, ACIDO, INORGANICO, N.E.P. (PHOSPHORIC ACID, SULFURIC ACID) 8 II U.S. DOT - RAIL 3264 Corrosive liquid, acidic, inorganic, n.o.s. (PHOSPHORIC ACID, SULFURIC ACID) 8 II U.S. DOT - INLAND WATERWAYS 3264 Corrosive liquid, acidic, inorganic, n.o.s. (PHOSPHORIC ACID, SULFURIC ACID) 8 II TRANSPORT CANADA - ROAD UN 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (PHOSPHORIC ACID, SULFURIC ACID) 8 II LIMITED QUANTITY TRANSPORT CANADA - RAIL Page 69 of 262 Page 69 of 262 Page 69 of 262 Page 69 of 262 ---PAGE BREAK--- Page: 12 SAFETY DATA SHEET Revision Date: 09/17/2012 Print Date: 1/13/2015 MSDS Number: R0336576 Eagle One™ ETCHING MAG WHEEL CLEANER 836604 Version: 5.1 Page 12 / 14 UN 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (PHOSPHORIC ACID, SULFURIC ACID) 8 II TRANSPORT CANADA - INLAND WATERWAYS UN 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (PHOSPHORIC ACID, SULFURIC ACID) 8 II INTERNATIONAL MARITIME DANGEROUS GOODS UN 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (PHOSPHORIC ACID, SULFURIC ACID) 8 II INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO UN ORM-D, CONSUMER COMMODITY ORM INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER UN ORM-D, CONSUMER COMMODITY ORM MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTES UN ORM-D, CONSUMER COMMODITY ORM *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. 15. REGULATORY INFORMATION Page 70 of 262 Page 70 of 262 Page 70 of 262 Page 70 of 262 ---PAGE BREAK--- Page: 13 SAFETY DATA SHEET Revision Date: 09/17/2012 Print Date: 1/13/2015 MSDS Number: R0336576 Eagle One™ ETCHING MAG WHEEL CLEANER 836604 Version: 5.1 Page 13 / 14 California Prop. 65WARNING! This product contains a chemical known to the State of California to cause cancer. SULFURIC ACID SARA Hazard Classification SARA 311/312 Classification Acute Health Hazard Chronic Health Hazard SARA 313 Component(s) SULFURIC ACID 2.35 % HYDROFLUORIC ACID 1.60 % New Jersey RTK Label Information WATER 7732-18-5 PHOSPHORIC ACID 7664-38-2 SULFURIC ACID 7664-93-9 SURFACTANT HYDROFLUORIC ACID 7664-39-3 RTK Label Information WATER 7732-18-5 PHOSPHORIC ACID 7664-38-2 SULFURIC ACID 7664-93-9 HYDROFLUORIC ACID 7664-39-3 Notification status US. Toxic Substances Control Act y (positive listing) Canada. Canadian Environmental Protection Act (CEPA). Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133) y (positive listing) Australia. Industrial Chemical (Notification and Assessment) Act y (positive listing) New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand n (Negative listing) Japan. Kashin-Hou Law List n (Negative listing) Korea. Toxic Chemical Control Law (TCCL) List y (positive listing) Philippines. The Toxic Substances and Hazardous and Nuclear Waste Control Act y (positive listing) Page 71 of 262 Page 71 of 262 Page 71 of 262 Page 71 of 262 ---PAGE BREAK--- Page: 14 SAFETY DATA SHEET Revision Date: 09/17/2012 Print Date: 1/13/2015 MSDS Number: R0336576 Eagle One™ ETCHING MAG WHEEL CLEANER 836604 Version: 5.1 Page 14 / 14 China. Inventory of Existing Chemical Substances y (positive listing) Reportable quantity - Product US. EPA CERCLA Hazardous Substances (40 CFR 302) 6250 lbs Reportable quantity-Components HYDROFLUORIC ACID 7664-39-3 100 lbs HMIS NFPA Health 3 3 Flammability 0 0 Physical hazards 0 Instability 0 Specific Hazard 16. OTHER INFORMATION The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department (1-[PHONE REDACTED]). Page 72 of 262 Page 72 of 262 Page 72 of 262 Page 72 of 262 ---PAGE BREAK--- Page: 1 SAFETY DATA SHEET Revision Date: 06/22/2013 Print Date: 8/19/2014 MSDS Number: 000000109636 Eagle One™ WAX-AS-U-DRY® SPRAY WAX E12089244 Version: 4.1 Page 1 / 11 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Ashland Regulatory Information Number 1-[PHONE REDACTED] P.O. Box 2219 Telephone [PHONE REDACTED] Columbus, OH 43216 Emergency telephone number 1-800-ASHLAND (1-[PHONE REDACTED]) Product name Eagle One™ WAX-AS-U-DRY® SPRAY WAX Product code E12089244 2. HAZARDS IDENTIFICATION Emergency Overview Appearance: liquid, white CAUTION! MAY AFFECT THE CENTRAL NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. PROLONGED OR REPEATED CONTACT MAY DRY THE SKIN AND CAUSE IRRITATION AND BURNS. Potential Health Effects Exposure routes Inhalation, Skin absorption, Skin contact, Eye Contact, Ingestion Eye contact May cause mild eye irritation. include stinging, tearing, and redness. Skin contact May cause slight skin irritation. Prolonged or repeated contact may dry the skin. may include redness, burning, and drying and cracking of skin, skin burns, and other skin damage. Ingestion Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. Inhalation It is possible to breathe this material under certain conditions of handling and use (for example, during heating, spraying, or stirring). Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. are not expected at air concentrations below the recommended exposure limits, if applicable (see Section Aggravated Medical Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, Skin Page 73 of 262 Page 73 of 262 Page 73 of 262 Page 73 of 262 ---PAGE BREAK--- Page: 2 SAFETY DATA SHEET Revision Date: 06/22/2013 Print Date: 8/19/2014 MSDS Number: 000000109636 Eagle One™ WAX-AS-U-DRY® SPRAY WAX E12089244 Version: 4.1 Page 2 / 11 Signs and of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea), central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness) Target Organs Exposure to this material (or a component) has been found to cause kidney damage in male rats. The mechanism by which this toxicity occurs is specific to the male rat and the kidney effects are not expected to occur in humans. Carcinogenicity This material is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration (OSHA).This product (or a component) is a petroleum-derived material. Similar materials and certain compounds occurring naturally in petroleum oils have been shown to cause skin cancer in laboratory animals following repeated exposure without washing or removal. Reproductive hazard There are no data available for assessing risk to the fetus from maternal exposure to this material. Other information When heated to temperatures above 150 degrees C in the presence of air, this product can form formaldehyde vapors. Formaldehyde has been identified as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) and the Occupational Safety and Health Administration (OSHA). Formaldehyde is irritating to the eyes, nose, throat, and airways, and in rare cases, can cause an allergic reaction (causes narrowing of the air passages of the lungs, sweating, flushing, hives, rapid heart rate, and lowered blood pressure). In addition, formaldehyde can cause an allergic skin reaction (delayed skin rash which may be followed by blistering, scaling and other skin effects). It is harmful if inhaled, swallowed or absorbed through skin. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Components CAS-No. / Trade Secret No. Concentration SOLVENT NAPHTHA (PETROLEUM), HEAVY ALIPHATIC 64742-96-7 DIMETHYL SILICONES AND SILOXANES 63148-62-9 4. FIRST AID MEASURES Eyes If develop, move individual away from exposure and into fresh air. Flush eyes gently with water while holding eyelids apart. If persist or there is any visual difficulty, seek medical attention. Skin Page 74 of 262 Page 74 of 262 Page 74 of 262 Page 74 of 262 ---PAGE BREAK--- Page: 3 SAFETY DATA SHEET Revision Date: 06/22/2013 Print Date: 8/19/2014 MSDS Number: 000000109636 Eagle One™ WAX-AS-U-DRY® SPRAY WAX E12089244 Version: 4.1 Page 3 / 11 Remove contaminated clothing. Wash exposed area with soap and water. If persist, seek medical attention. Launder clothing before reuse. Ingestion Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. Inhalation If develop, move individual away from exposure and into fresh air. If persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention. Notes to physician Hazards: No information available. Treatment: No information available. 5. FIREFIGHTING MEASURES Suitable extinguishing media Dry chemical, Carbon dioxide (CO2), Water spray Hazardous combustion products Aldehydes, carbon dioxide and carbon monoxide, Hydrocarbons, formaldehyde, Hydrogen, silicon oxides Precautions for fire-fighting Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). Use water spray to cool fire exposed containers and structures until fire is out if it can be done with minimal risk. Avoid spreading burning material with water used for cooling purposes. NFPA Flammable and Combustible Liquids Classification not applicable 6. ACCIDENTAL RELEASE MEASURES Personal precautions For personal protection see section 8. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions Prevent spreading over a wide area (e.g. by containment or oil barriers). Do not let product enter drains. Do not flush into surface water or sanitary sewer system. Methods for cleaning up Keep in suitable, closed containers for disposal. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Page 75 of 262 Page 75 of 262 Page 75 of 262 Page 75 of 262 ---PAGE BREAK--- Page: 4 SAFETY DATA SHEET Revision Date: 06/22/2013 Print Date: 8/19/2014 MSDS Number: 000000109636 Eagle One™ WAX-AS-U-DRY® SPRAY WAX E12089244 Version: 4.1 Page 4 / 11 Other information Comply with all applicable federal, state, and local regulations. 7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Storage Store in a cool, dry, ventilated area. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Contains no substances with occupational exposure limit values. General advice These recommendations provide general guidance for handling this product. Personal protective equipment should be selected for individual applications and should consider factors which affect exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities. Exposure controls General room ventilation should be adequate for normal conditions of use. However, if unusual operating conditions exist, provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Eye protection Not required under normal conditions of use. Wear splash-proof safety goggles if material could be misted or splashed into eyes. Skin and body protection Wear resistant gloves (consult your safety equipment supplier). Respiratory protection Respiratory protection is not required under normal conditions of use. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state liquid Colour white Boiling point/boiling range 212 °F / 100 °C @ 1,013.33 hPa Calculated Phase Transition Liquid/Gas pH 7 - 8 Page 76 of 262 Page 76 of 262 Page 76 of 262 Page 76 of 262 ---PAGE BREAK--- Page: 5 SAFETY DATA SHEET Revision Date: 06/22/2013 Print Date: 8/19/2014 MSDS Number: 000000109636 Eagle One™ WAX-AS-U-DRY® SPRAY WAX E12089244 Version: 4.1 Page 5 / 11 Flash point not applicable Lower explosion limit/Upper explosion limit 0.6 / 7 Calculated Explosive Limit Vapour pressure 23.333 hPa @ 68 °F / 20 °C Calculated Vapor Pressure 10. STABILITY AND REACTIVITY Stability Stable. Conditions to avoid None known. Incompatible products Strong oxidizing agents, strong reducing agents Hazardous decomposition products Aldehydes, carbon dioxide and carbon monoxide, Hydrocarbons, formaldehyde-like, Hydrogen, silicon oxides Hazardous reactions Product will not undergo hazardous polymerization. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation Skin absorption Skin contact Eye Contact Ingestion Product Acute oral toxicity : no data available Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Skin corrosion/irritation : no data available Serious eye damage/eye : no data available Page 77 of 262 Page 77 of 262 Page 77 of 262 Page 77 of 262 ---PAGE BREAK--- Page: 6 SAFETY DATA SHEET Revision Date: 06/22/2013 Print Date: 8/19/2014 MSDS Number: 000000109636 Eagle One™ WAX-AS-U-DRY® SPRAY WAX E12089244 Version: 4.1 Page 6 / 11 irritation Respiratory or skin sensitisation : no data available Target Organ Systemic Toxicant - Repeated exposure : Target Organs: Exposure to this material (or a component) has been found to cause kidney damage in male rats. The mechanism by which this toxicity occurs is specific to the male rat and the kidney effects are not expected to occur in humans. Components: SOLVENT NAPHTHA (PETROLEUM), HEAVY ALIPHATIC: Acute oral toxicity : LD 50 Rat: > 5 g/kg Information given is based on data obtained from similar substances. Acute inhalation toxicity : LC 50 Rat: > 5 mg/l Exposure time: 4 h Information given is based on data obtained from similar substances. Acute dermal toxicity : LD 50 Rat: > 2,000 mg/kg Information given is based on data obtained from similar substances. Aspiration toxicity : May be fatal if swallowed and enters airways. DIMETHYL SILICONES AND SILOXANES: Acute oral toxicity : LD 50 Rat: > 5 g/kg Acute inhalation toxicity : LC 50 Rat: > 695 mg/m3 Exposure time: 4 h Method: OECD Test Guideline 403 Acute dermal toxicity : LD 50 Rabbit: > 2,000 mg/kg Respiratory or skin sensitisation : Classification: Did not cause sensitisation on laboratory animals. Germ cell mutagenicity Genotoxicity in vitro : In vitro tests did not show mutagenic effects Carcinogenicity : see user defined free text Page 78 of 262 Page 78 of 262 Page 78 of 262 Page 78 of 262 ---PAGE BREAK--- Page: 7 SAFETY DATA SHEET Revision Date: 06/22/2013 Print Date: 8/19/2014 MSDS Number: 000000109636 Eagle One™ WAX-AS-U-DRY® SPRAY WAX E12089244 Version: 4.1 Page 7 / 11 Repeated dose toxicity : Note: No adverse effect has been observed in chronic toxicity tests. 12. ECOLOGICAL INFORMATION Ecotoxicity Product: no data available Components: no data available Persistence and degradability Product: no data available Components: DIMETHYL SILICONES AND SILOXANES: Biodegradability : Not readily biodegradable. Bioaccumulative potential Product: no data available Components: no data available Mobility in soil Product: no data available Components: DIMETHYL SILICONES AND SILOXANES: Page 79 of 262 Page 79 of 262 Page 79 of 262 Page 79 of 262 ---PAGE BREAK--- Page: 8 SAFETY DATA SHEET Revision Date: 06/22/2013 Print Date: 8/19/2014 MSDS Number: 000000109636 Eagle One™ WAX-AS-U-DRY® SPRAY WAX E12089244 Version: 4.1 Page 8 / 11 Surface tension : 20 mN/m 13. DISPOSAL CONSIDERATIONS Waste disposal methods Dispose of in accordance with all applicable local, state and federal regulations. 14. TRANSPORT INFORMATION REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP MARINE POLLUTANT / LTD. QTY. U.S. DOT - ROAD Not dangerous goods U.S. DOT - RAIL Not dangerous goods U.S. DOT - INLAND WATERWAYS Not dangerous goods TRANSPORT CANADA - ROAD Not dangerous goods TRANSPORT CANADA - RAIL Not dangerous goods TRANSPORT CANADA - INLAND WATERWAYS Not dangerous goods INTERNATIONAL MARITIME DANGEROUS GOODS Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER Not dangerous goods MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTES Not dangerous goods *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Page 80 of 262 Page 80 of 262 Page 80 of 262 Page 80 of 262 ---PAGE BREAK--- Page: 9 SAFETY DATA SHEET Revision Date: 06/22/2013 Print Date: 8/19/2014 MSDS Number: 000000109636 Eagle One™ WAX-AS-U-DRY® SPRAY WAX E12089244 Version: 4.1 Page 9 / 11 Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. 15. REGULATORY INFORMATION California Prop. 65 WARNING! This product contains a chemical known to the State of California to cause cancer. DIETHANOLAMINE FORMALDEHYDE ACETALDEHYDE SARA Hazard Classification SARA 311/312 Classification Acute Health Hazard SARA 313 Component(s) SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. New Jersey RTK Label Information WATER 7732-18-5 SOLVENT NAPHTHA (PETROLEUM), HEAVY ALIPHATIC 64742-96-7 DIMETHYL SILICONES AND SILOXANES 63148-62-9 RTK Label Information WATER 7732-18-5 SOLVENT NAPHTHA (PETROLEUM), HEAVY ALIPHATIC 64742-96-7 DIMETHYL SILICONES AND SILOXANES 63148-62-9 Notification status US. Toxic Substances Control Act y (positive listing) Canada. Canadian Environmental Protection Act (CEPA). Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133) y (positive listing) Australia. Industrial Chemical (Notification and Assessment) Act y (positive listing) Japan. ENCS - Existing and New Chemical Substances Inventory n (Negative listing) Korea. Toxic Chemical Control Law (TCCL) List y (positive listing) Philippines. The Toxic Substances and Hazardous and Nuclear Waste Control Act y (positive listing) China. Inventory of Existing Chemical Substances y (positive listing) Reportable quantity - Product US. EPA CERCLA Hazardous Substances (40 CFR 302) 666666 lbs Reportable quantity-Components DIETHANOLAMINE 111-42-2 100 lbs Page 81 of 262 Page 81 of 262 Page 81 of 262 Page 81 of 262 ---PAGE BREAK--- Page: 10 SAFETY DATA SHEET Revision Date: 06/22/2013 Print Date: 8/19/2014 MSDS Number: 000000109636 Eagle One™ WAX-AS-U-DRY® SPRAY WAX E12089244 Version: 4.1 Page 10 / 11 HMIS NFPA Health 1 1 Flammability 1 1 Physical hazards 0 Instability 0 Specific Hazard 16. OTHER INFORMATION The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department (1-[PHONE REDACTED]). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the “International Air Transport Association” (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the “International Civil Aviation Organization” IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act Page 82 of 262 Page 82 of 262 Page 82 of 262 Page 82 of 262 ---PAGE BREAK--- Page: 11 SAFETY DATA SHEET Revision Date: 06/22/2013 Print Date: 8/19/2014 MSDS Number: 000000109636 Eagle One™ WAX-AS-U-DRY® SPRAY WAX E12089244 Version: 4.1 Page 11 / 11 DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System Page 83 of 262 Page 83 of 262 Page 83 of 262 Page 83 of 262 ---PAGE BREAK--- Page 84 of 262 Page 84 of 262 Page 84 of 262 Page 84 of 262 ---PAGE BREAK--- Page 85 of 262 Page 85 of 262 Page 85 of 262 Page 85 of 262 ---PAGE BREAK--- Page 86 of 262 Page 86 of 262 Page 86 of 262 Page 86 of 262 ---PAGE BREAK--- Page 87 of 262 Page 87 of 262 Page 87 of 262 Page 87 of 262 ---PAGE BREAK--- 1. IDENTIFICATION Product identifier Product Name FAST ORANGE SMOOTH LOTION WITH BRUSH 15 FL.OZ Other means of identification Product Code 23113 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Hand Cleaner or Soap - Heavy Duty Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: [PHONE REDACTED] International Emergency: 00+1+ [PHONE REDACTED] Contract Number: MIS0003453 E-mail address [EMAIL REDACTED] 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label elements Emergency Overview Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Page 1 / 7 Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Revision Date 15-May-2015 SAFETY DATA SHEET Version 1 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Odor Citrus Appearance White Physical state Lotion Page 88 of 262 Page 88 of 262 Page 88 of 262 Page 88 of 262 ---PAGE BREAK--- Other Information Harmful to aquatic life. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. Unknown acute toxicity 6.4155% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret WATER 7732-18-5 60 - 100 * ETHOXYLATED C11-C16 ALCOHOL 127036-24-2 1 - 5 * D-LIMONENE 5989-27-5 0.1 - 1 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact None under normal use conditions. Inhalation None under normal use conditions. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important and effects, both acute and delayed See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Page 2 / 7 23113 - FAST ORANGE SMOOTH LOTION WITH BRUSH 15 FL.OZ Revision Date 15-May-2015 Page 89 of 262 Page 89 of 262 Page 89 of 262 Page 89 of 262 ---PAGE BREAK--- Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Avoid contact with eyes. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes. Conditions for safe storage, including any incompatibilities Storage Conditions Keep from freezing. Incompatible materials None known 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Appropriate engineering controls Engineering Controls Eyewash stations Individual protection measures, such as personal protective equipment Eye/face protection Tight sealing safety goggles. Skin and body protection None under normal use conditions. Respiratory protection None under normal use conditions. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 3 / 7 23113 - FAST ORANGE SMOOTH LOTION WITH BRUSH 15 FL.OZ Revision Date 15-May-2015 Page 90 of 262 Page 90 of 262 Page 90 of 262 Page 90 of 262 ---PAGE BREAK--- Information on basic physical and chemical properties Physical state Lotion Appearance White Odor Citrus Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content <1 Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Incompatible materials None known Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Page 4 / 7 Evaporation rate < 1 Autoignition temperature No information available Decomposition temperature No information available Butyl acetate = 1 Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values Lower flammability limit: No information available 23113 - FAST ORANGE SMOOTH LOTION WITH BRUSH 15 FL.OZ Vapor pressure No information available Boiling point / boiling range > 100 °C / 212 °F No data available Vapor density >1 Remarks • Method Air = 1 Relative density 0.96 Revision Date 15-May-2015 Flash point Water solubility Soluble in water > 95 °C / > 203 °F Solubility in other solvents No information available pH Partition coefficient No information available 6.0-8.0 Page 91 of 262 Page 91 of 262 Page 91 of 262 Page 91 of 262 ---PAGE BREAK--- Information on likely routes of exposure Inhalation None known. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 WATER 7732-18-5 > 90 mL/kg ( Rat ) - - D-LIMONENE 5989-27-5 = 4400 mg/kg ( Rat ) > 5 g/kg ( Rabbit ) - Information on toxicological effects No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA D-LIMONENE 5989-27-5 - Group 2A - X IARC (International Agency for Research on Cancer) Group 2A - Probably Carcinogenic to Humans Not classifiable as a human carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 405680 mg/kg ATEmix (dermal) 461460 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity 6.4372% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea D-LIMONENE 5989-27-5 - 35: 96 h mykiss mg/L LC50 0.619 - 0.796: 96 h Pimephales promelas mg/L LC50 flow-through - Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Other adverse effects No information available Page 5 / 7 Revision Date 15-May-2015 23113 - FAST ORANGE SMOOTH LOTION WITH BRUSH 15 FL.OZ Page 92 of 262 Page 92 of 262 Page 92 of 262 Page 92 of 262 ---PAGE BREAK--- 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status D-LIMONENE 5989-27-5 Toxic 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Not Listed. ENCS Not Listed. IECSC Complies KECL Not Listed. PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Yes Page 6 / 7 Revision Date 15-May-2015 23113 - FAST ORANGE SMOOTH LOTION WITH BRUSH 15 FL.OZ Page 93 of 262 Page 93 of 262 Page 93 of 262 Page 93 of 262 ---PAGE BREAK--- Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts LANOLIN 8006-54-0 - - X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 15-May-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 7 / 7 - Revision Date 15-May-2015 HMIS NFPA Health hazards 1 Flammability 1 Physical hazards 0 Personal protection B Health hazards 1 Flammability 1 23113 - FAST ORANGE SMOOTH LOTION WITH BRUSH 15 FL.OZ Instability 0 Page 94 of 262 Page 94 of 262 Page 94 of 262 Page 94 of 262 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 1 / 9 SAFETY DATA SHEET 1. Identification Product number [PHONE REDACTED] Product identifier GERMICIDAL CLEANER Revision date 03-23-2015 Company information Claire Manufacturing Co. 1005 S. Westgate Drive Addison, IL 60101 United States Company phone General Assistance 1-[PHONE REDACTED] Emergency telephone US 1-[PHONE REDACTED] Emergency telephone outside US 1-[PHONE REDACTED] Version # 04 Supersedes date 03-05-2015 Recommended use Cleaner Recommended restrictions None known. 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements Flammable aerosols Serious eye damage/eye irritation Not classified. Not classified. Category 1 Category 2 Signal word Danger Hazard statement Extremely flammable aerosol. Causes serious eye irritation. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash thoroughly after handling. Wear eye/face protection. Response If swallowed: Rinse mouth. Do NOT induce vomiting. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Storage Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Disposal Not available. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % 2-Butoxyethanol Butane EDTA Tertrasodium Salt 111-76-2 106-97-8 64-02-8 2.5 - 10 1 - 2.5 1 - 2.5 Other components below reportable levels 90 - 100 Page 95 of 262 Page 95 of 262 Page 95 of 262 Page 95 of 262 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 2 / 9 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Call a physician if develop or persist. Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists. Eye contact Rinse with water. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Get medical attention if occur. Most important acute and delayed Indication of immediate medical attention and special treatment needed Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. Provide general supportive measures and treat Keep victim under observation. may be delayed. General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water. Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Do not use water jet as an extinguisher, as this will spread the fire. Contents under pressure. Pressurized container may explode when exposed to heat or flame. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Use water spray to cool unopened containers. In the event of fire and/or explosion do not breathe fumes. General fire hazards Extremely flammable aerosol. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Level 1 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). Page 96 of 262 Page 96 of 262 Page 96 of 262 Page 96 of 262 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 3 / 9 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value 2-Butoxyethanol (CAS 111-76-2) US. ACGIH Threshold Limit Values PEL 240 mg/m3 50 ppm Components Type Value 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) TWA 20 ppm STEL 1000 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Biological limit values ACGIH Biological Exposure Indices TWA 24 mg/m3 5 ppm TWA 1900 mg/m3 800 ppm Components Value Determinant Specimen Sampling Time 2-Butoxyethanol (CAS 111-76-2) 200 mg/g Butoxyacetic acid (BAA), Creatinine in urine * with hydrolysis * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies 2-Butoxyethanol (CAS 111-76-2) Skin designation applies. US - Tennesse OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Hand protection Wear appropriate chemical resistant gloves. Skin protection Other Wear suitable protective clothing. Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Page 97 of 262 Page 97 of 262 Page 97 of 262 Page 97 of 262 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 4 / 9 9. Physical and chemical properties Appearance Physical state Gas. Form Aerosol. Color Not available. Odor Not available. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 212 °F (100 estimated Flash point -156.0 °F (-104.4 Propellant estimated Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Flammability limit - upper Not available. Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 55 - 75 psig @70F estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Specific gravity 0.979 estimated 10. Stability and reactivity Reactivity Reacts violently with strong acids. This product may react with oxidizing agents. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid Avoid temperatures exceeding the flash point. Do not mix with other chemicals. Contact with incompatible materials. Incompatible materials Acids. Oxidizing agents. Hazardous decomposition products No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation Prolonged inhalation may be harmful. Skin contact 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Eye contact Causes serious eye irritation. Page 98 of 262 Page 98 of 262 Page 98 of 262 Page 98 of 262 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 5 / 9 related to the physical, chemical and toxicological characteristics Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. Information on toxicological effects Acute toxicity Harmful if inhaled. Harmful if swallowed. Components Species 2-Butoxyethanol (CAS 111-76-2) Acute Dermal LD50 Guinea pig Test Results 230 ml/kg, 24 Hours 7.3 ml/kg, 4 Days Inhalation Rabbit 450 ml/kg, 24 Hours 435 mg/kg, 24 Hours 0.63 ml/kg Rat > 2000 mg/kg, 24 Hours LC50 Rabbit 400 ppm, 7 Hours Oral Rat 450 ppm, 4 Hours LD100 Rabbit 695 mg/kg LD50 Dog > 695 mg/kg Guinea pig 1200 mg/kg Rat 530 - 2800 mg/kg Butane (CAS 106-97-8) Acute Inhalation LC50 Mouse 1237 mg/l, 120 Minutes 52 120 Minutes Rat 1355 mg/l EDTA Tertrasodium Salt (CAS 64-02-8) Acute Oral LD50 Rat 1658 mg/kg * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Causes skin burns. Serious eye damage/eye irritation Respiratory or skin sensitization Causes eye burns. Risk of serious damage to eyes. Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity 2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Not classified. Page 99 of 262 Page 99 of 262 Page 99 of 262 Page 99 of 262 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 6 / 9 Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not likely, due to the form of the product. Chronic effects Prolonged inhalation may be harmful. May be harmful if absorbed through skin. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components 2-Butoxyethanol (CAS 111-76-2) Aquatic Species Test Results Fish LC50 Inland silverside (Menidia beryllina) 1250 mg/l, 96 hours EDTA Tertrasodium Salt (CAS 64-02-8) Aquatic Algae Fish IC50 LC50 Algae Bluegill (Lepomis macrochirus) 1.01 mg/L, 72 Hours 472 - 500 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) 2-Butoxyethanol 0.83 Butane 2.89 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. 14. Transport information DOT UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group UN1950 Aerosols 2.2 - 2.2 Not applicable. Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Packaging exceptions Packaging non bulk Packaging bulk 306 None None Page 100 of 262 Page 100 of 262 Page 100 of 262 Page 100 of 262 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 7 / 9 This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently. IATA UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards ERG Code UN1950 Aerosols, non-flammable 2.2 - 2.2 Not applicable. Yes 2L Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Other information Passenger and cargo aircraft Cargo aircraft only Packaging Exceptions IMDG UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards Marine pollutant EmS Allowed. Allowed. LTD QTY UN1950 AEROSOLS 2.2 - 2.2 Not applicable. Yes Not available. Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Packaging Exceptions Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT IATA; IMDG LTD QTY Not applicable. Page 101 of 262 Page 101 of 262 Page 101 of 262 Page 101 of 262 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 8 / 9 Marine pollutant 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Chemical name CAS number Reportable quantity Threshold planning quantity Threshold planning quantity, lower value Threshold planning quantity, upper value Ammonia 7664-41-7 100 500 lbs Hydrogen Peroxide 7722-84-1 1000 1000 lbs SARA 311/312 Hazardous No chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Butane (CAS 106-97-8) Safe Drinking Water Act (SDWA) US state regulations Not regulated. US. Massachusetts RTK - Substance List 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) US. New Jersey Worker and Community Right-to-Know Act 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) US. Worker and Community Right-to-Know Law 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) US. Rhode Island RTK Butane (CAS 106-97-8) Page 102 of 262 Page 102 of 262 Page 102 of 262 Page 102 of 262 ---PAGE BREAK--- Product name: GERMICIDAL CLEANER Product [PHONE REDACTED] Version 04 Revision date: 03-23-2015 Issue date: 07-28-2014 SDS US 9 / 9 US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Domestic Substances List (DSL) Canada Non-Domestic Substances List (NDSL) China Inventory of Existing Chemical Substances in China (IECSC) Europe European Inventory of Existing Commercial Chemical Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) Japan Inventory of Existing and New Chemical Substances (ENCS) Korea Existing Chemicals List (ECL) New Zealand New Zealand Inventory Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) No Yes No Yes No No Yes No No No Yes A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 07-28-2014 Revision date 03-23-2015 Version # 04 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Revision Information Product and Company Identification: Alternate Trade Names Page 103 of 262 Page 103 of 262 Page 103 of 262 Page 103 of 262 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Product number [PHONE REDACTED] Product identifier GLEME GLASS CLEANER Company information Claire Manufacturing Co. 1005 S. Westgate Drive Addison, IL 60101 United States Company phone General Assistance 1-[PHONE REDACTED] Emergency telephone US 1-[PHONE REDACTED] Emergency telephone outside US 1-[PHONE REDACTED] Version # 01 Recommended use cleaner Recommended restrictions None known. 2. Hazard(s) identification Liquefied gas Gases under pressure Physical hazards Not classified. Health hazards Not classified. Environmental hazards Not classified. OSHA defined hazards Label elements Signal word Warning Hazard statement Contains gas under pressure; may explode if heated. Precautionary statement Prevention Observe good industrial hygiene practices. Response Wash hands after handling. Storage Protect from sunlight. Store in a well-ventilated place. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number % Chemical name Common name and synonyms 111-76-2 2-Butoxyethanol 2.5 - 10 64-17-5 Ethyl Alcohol 2.5 - 10 106-97-8 Butane 1 - 2.5 74-98-6 Propane Other components below reportable levels 90 - 100 1 - 2.5 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Get medical attention if persist. 1 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 104 of 262 Page 104 of 262 Page 104 of 262 Page 104 of 262 ---PAGE BREAK--- Skin contact Get medical attention if irritation develops and persists. Eye contact Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Most important acute and delayed Direct contact with eyes may cause temporary irritation. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Contents under pressure. During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire-fighting equipment/instructions In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed to heat. Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. See Section 8 of the SDS for Personal Protective Equipment. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into waterways, sewer, basements or confined areas. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Ground and bond containers when transferring material. Do not re-use empty containers. Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Level 1 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. Keep containers closed in a dry, cool and well-ventilated place. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). 2 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 105 of 262 Page 105 of 262 Page 105 of 262 Page 105 of 262 ---PAGE BREAK--- 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Type PEL 240 mg/m3 2-Butoxyethanol (CAS 111-76-2) 50 ppm PEL 1900 mg/m3 Ethyl Alcohol (CAS 64-17-5) 1000 ppm PEL 1800 mg/m3 Propane (CAS 74-98-6) 1000 ppm US. ACGIH Threshold Limit Values Value Components Type TWA 20 ppm 2-Butoxyethanol (CAS 111-76-2) STEL 1000 ppm Butane (CAS 106-97-8) STEL 1000 ppm Ethyl Alcohol (CAS 64-17-5) US. NIOSH: Pocket Guide to Chemical Hazards Value Components Type TWA 24 mg/m3 2-Butoxyethanol (CAS 111-76-2) 5 ppm TWA 1900 mg/m3 Butane (CAS 106-97-8) 800 ppm TWA 1900 mg/m3 Ethyl Alcohol (CAS 64-17-5) 1000 ppm TWA 1800 mg/m3 Propane (CAS 74-98-6) 1000 ppm Biological limit values ACGIH Biological Exposure Indices Value Components Determinant Specimen Sampling Time 200 mg/g Butoxyacetic acid (BAA), with hydrolysis Creatinine in urine * 2-Butoxyethanol (CAS 111-76-2) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies 2-Butoxyethanol (CAS 111-76-2) Skin designation applies. US - Tennesse OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection If contact is likely, safety glasses with side shields are recommended. Hand protection For prolonged or repeated skin contact use suitable protective gloves. Skin protection Other Wear suitable protective clothing. 3 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 106 of 262 Page 106 of 262 Page 106 of 262 Page 106 of 262 ---PAGE BREAK--- Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Clear. Physical state Gas. Form Aerosol. Liquefied gas. Color Light yellow. Odor Characteristic. Odor threshold Not available. pH 9.1 - 10.1 estimated Melting point/freezing point Not available. Initial boiling point and boiling range 212 °F (100 estimated Flash point -156.0 °F (-104.4 Propellant estimated Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Not available. Flammability limit - upper Not available. Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 80 - 100 psig @70F estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Aerosol spray enclosed space Deflagration density > 2.52 g/cm3 Tested Aerosol spray ignition distance < 15 cm Tested estimated Specific gravity 0.977 - 0.997 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Hazardous polymerization does not occur. Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. 4 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 107 of 262 Page 107 of 262 Page 107 of 262 Page 107 of 262 ---PAGE BREAK--- Incompatible materials Strong oxidizing agents. Hazardous decomposition products No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation Prolonged inhalation may be harmful. Skin contact No adverse effects due to skin contact are expected. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Eye contact Direct contact with eyes may cause temporary irritation. related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity May be harmful if swallowed. May be harmful in contact with skin. May be harmful if inhaled. Expected to be a low hazard for usual industrial or commercial handling by trained personnel. Test Results Components Species 2-Butoxyethanol (CAS 111-76-2) LD50 Guinea pig Dermal Acute 230 ml/kg, 24 Hours 7.3 ml/kg, 4 Days Rabbit 450 ml/kg, 24 Hours 435 mg/kg, 24 Hours 0.63 ml/kg Rat > 2000 mg/kg, 24 Hours LC50 Rabbit Inhalation 400 ppm, 7 Hours Rat 450 ppm, 4 Hours LD100 Rabbit Oral 695 mg/kg LD50 Dog > 695 mg/kg Guinea pig 1200 mg/kg Rat 530 - 2800 mg/kg Butane (CAS 106-97-8) LC50 Mouse Inhalation Acute 1237 mg/l, 120 Minutes 52 120 Minutes Rat 1355 mg/l Ethyl Alcohol (CAS 64-17-5) LC50 Cat Inhalation Acute 85.41 mg/l, 4.5 Hours 43.68 mg/l, 6 Hours Mouse > 60000 ppm 79.43 mg/l, 134 Minutes Rat > 115.9 mg/l, 4 Hours 5 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 108 of 262 Page 108 of 262 Page 108 of 262 Page 108 of 262 ---PAGE BREAK--- Test Results Components Species 51.3 mg/l, 6 Hours LD50 Monkey Oral 6000 mg/kg Mouse 10500 ml/kg Rat 1187 - 2769 mg/kg 7800 ml/kg Propane (CAS 74-98-6) LC50 Mouse Inhalation Acute 1237 mg/l, 120 Minutes 52 120 Minutes Rat 1355 mg/l 658 mg/l/4h * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation May be irritating to the skin. Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. May be irritating to eyes. Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity 2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Not likely, due to the form of the product. Chronic effects Prolonged inhalation may be harmful. May be harmful if absorbed through skin. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. 12. Ecological information Ecotoxicity Harmful to aquatic life. Product Test Results Species GLEME GLASS CLEANER (CAS Mixture) Aquatic EC50 Crustacea 13838.1602 mg/l, 48 hours estimated Daphnia Components Test Results Species 2-Butoxyethanol (CAS 111-76-2) Aquatic LC50 Fish 1250 mg/l, 96 hours Inland silverside (Menidia beryllina) 6 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 109 of 262 Page 109 of 262 Page 109 of 262 Page 109 of 262 ---PAGE BREAK--- Components Test Results Species Ethyl Alcohol (CAS 64-17-5) Aquatic EC50 Crustacea 7700 - 11200 mg/l, 48 hours Water flea (Daphnia magna) * Estimates for product may be based on additional component data not shown. LC50 Fish > 100.1 mg/l, 96 hours Fathead minnow (Pimephales promelas) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) 2-Butoxyethanol 0.83 Butane 2.89 Ethyl Alcohol -0.31 Propane 2.36 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. 14. Transport information DOT UN1950 UN number Aerosols UN proper shipping name 2.2 Class Transport hazard class(es) - Subsidiary risk 2.2 Label(s) Not applicable. Packing group Read safety instructions, SDS and emergency procedures before handling. Special precautions for user 306 Packaging exceptions None Packaging non bulk None Packaging bulk This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently. IATA UN1950 UN number Aerosols, non-flammable UN proper shipping name 2.2 Class Transport hazard class(es) - Subsidiary risk 2.2 Label(s) Not applicable. Packing group No. Environmental hazards 2L ERG Code Read safety instructions, SDS and emergency procedures before handling. Special precautions for user 7 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 110 of 262 Page 110 of 262 Page 110 of 262 Page 110 of 262 ---PAGE BREAK--- Allowed. Passenger and cargo aircraft Other information Allowed. Cargo aircraft only LTD QTY Packaging Exceptions IMDG UN1950 UN number AEROSOLS UN proper shipping name 2.2 Class Transport hazard class(es) - Subsidiary risk 2.2 Label(s) Not applicable. Packing group No. Marine pollutant Environmental hazards Not available. EmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user LTD QTY Packaging Exceptions Not applicable. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT IATA; IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. 8 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 111 of 262 Page 111 of 262 Page 111 of 262 Page 111 of 262 ---PAGE BREAK--- Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Butane (CAS 106-97-8) Propane (CAS 74-98-6) Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. Massachusetts RTK - Substance List 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) Propane (CAS 74-98-6) US. New Jersey Worker and Community Right-to-Know Act 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) Propane (CAS 74-98-6) US. Worker and Community Right-to-Know Law 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) Propane (CAS 74-98-6) US. Rhode Island RTK Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Yes Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) Yes China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) No New Zealand New Zealand Inventory No Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) 9 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 112 of 262 Page 112 of 262 Page 112 of 262 Page 112 of 262 ---PAGE BREAK--- Country(s) or region Inventory name On inventory (yes/no)* Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 05-26-2015 Version # 01 References EPA: AQUIRE database NLM: Hazardous Substances Data Base US. IARC Monographs on Occupational Exposures to Chemical Agents Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 10 / 10 Product name: GLEME GLASS CLEANER Product [PHONE REDACTED] Version 01 Issue date: 05-26-2015 SDS US Page 113 of 262 Page 113 of 262 Page 113 of 262 Page 113 of 262 ---PAGE BREAK--- Revision Date: 04-May-2015 Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name: GS RESTROOM CLEANER Product Number: 3503 , 3533 Recommended Use: Disinfectant Uses Advised Against: For Industrial and Institutional Use Only Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA [PHONE REDACTED] (Business hours) www.spartanchemical.com 24 Hour Emergency Phone Numbers: Medical Emergency/Information: [PHONE REDACTED] Transportation/Spill/Leak: CHEMTREC [PHONE REDACTED] 2. HAZARDS IDENTIFICATION GHS Classification Serious Eye Damage/Eye Irritation: Category 2A GHS Label Elements Signal Word: Warning Hazard Statements: Causes serious eye irritation Precautionary Statements: Prevention: Wash hands and any exposed skin thoroughly after handling. Wear eye / face protection Response: -Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information. Storage: Not Applicable Disposal: Not Applicable Hazards Not Otherwise Classified: Not Applicable Other Information: • May be harmful if swallowed. • May cause skin irritation. • Inhalation of vapors or mist may cause respiratory irritation. • Keep out of reach of children. Page 1 / 5 0.30298% of the mixture consists of ingredient(s) of unknown toxicity. Symbols: Page 114 of 262 Page 114 of 262 Page 114 of 262 Page 114 of 262 ---PAGE BREAK--- 3503 - GS RESTROOM CLEANER Revision Date: 04-May-2015 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% water 7732-18-5 60-100 citric acid 77-92-9 5-10 alcohol ethoxylate 68439-46-3 1-5 xanthan gum 11138-66-2 0.1-1 Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret. 4. FIRST AID MEASURES -Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Product does not support combustion, Use extinguishing agent suitable for type of surrounding fire Specific Hazards Arising from the Chemical: Dried product is capable of burning. Combustion products are toxic. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors. Protective Equipment and Precautions for Firefighters: Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full protective gear. Cool fire-exposed containers with water spray. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). 7. HANDLING AND STORAGE Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Storage Conditions: Keep containers closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep from freezing. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: None established. Engineering Controls: Page 2 / 5 Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Personal Protective Equipment Eye/Face Protection: Wear splash goggles. Page 115 of 262 Page 115 of 262 Page 115 of 262 Page 115 of 262 ---PAGE BREAK--- 3503 - GS RESTROOM CLEANER Revision Date: 04-May-2015 Skin and Body Protection: Not required with expected use. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance. 10. STABILITY AND REACTIVITY Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Heat, flames and sparks. Incompatible Materials: Strong oxidizing agents. Strong acids. Hazardous Decomposition Products: May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. of Exposure: -Eye Contact: Pain, redness, swelling of the conjunctiva and blurred vision. -Skin Contact: Drying of the skin. -Inhalation: Nasal discomfort and coughing. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 29382 mg/kg Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Liquid Color: Clear Odor: Bland pH: 1.5-2.5 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 100 °C / 212 °F Flash Point: > 100 °C / > 212 °F Evaporation Rate: < 1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 1.03 Solubility(ies): Soluble in water Partition Coefficient: No information available. Autoignition Temperature: No information available. Page 3 / 5 Decomposition Temperature: No information available. Viscosity: No information available. Page 116 of 262 Page 116 of 262 Page 116 of 262 Page 116 of 262 ---PAGE BREAK--- 3503 - GS RESTROOM CLEANER Revision Date: 04-May-2015 water 7732-18-5 > 90 mL/kg ( Rat ) Not Available Not Available citric acid 77-92-9 = 3000 mg/kg ( Rat ) Not Available Not Available alcohol ethoxylate 68439-46-3 = 1378 mg/kg ( Rat ) > 2 g/kg ( Rabbit ) Not Available Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA. 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Microorganisms Crustacea citric acid 77-92-9 Not Available 1516: 96 h Lepomis macrochirus mg/L LC50 static Not Available 120: 72 h Daphnia magna mg/L EC50 Persistence and Degradability: No information available. Bioaccumulation: No information available. Other Adverse Effects: No information available. 13. DISPOSAL CONSIDERATIONS Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT: Not Regulated Proper Shipping Name: Non Hazardous Product Special Provisions: Shipping descriptions may vary based on mode of transport, quantities, package size, and/or origin and destination. Check with a trained hazardous materials transportation expert for information specific to your situation. 15. REGULATORY INFORMATION TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances. SARA 313 This product does not contain listed substances above the "de minimus" level SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: No Reactive Hazard: No California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 acetaldehyde - 75-07-0 Carcinogen WARNING: This product contains a chemical known to the State of California to cause cancer. Page 4 / 5 EPA Pesticide Registration Number: 5741-25 Page 117 of 262 Page 117 of 262 Page 117 of 262 Page 117 of 262 ---PAGE BREAK--- 3503 - GS RESTROOM CLEANER Revision Date: 04-May-2015 EPA Statement: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: EPA Pesticide Label: Caution. Causes moderate eye irritation. May be harmful if swallowed. Avoid contact with eyes, skin or clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, or using the toilet. 16. OTHER INFORMATION Revision Date: 04-May-2015 Reasons for Revision: No information available. Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health Hazards: 1 Flammability: 0 Instability: 0 Special: N/A HMIS Page 5 / 5 Health Hazards: 1 Flammability: 0 Physical Hazards: 0 Page 118 of 262 Page 118 of 262 Page 118 of 262 Page 118 of 262 ---PAGE BREAK--- Page 119 of 262 Page 119 of 262 Page 119 of 262 Page 119 of 262 ---PAGE BREAK--- HOSPECO HEALTH GARDS AIR FRESHENER VINEYARD, 7OZ. HMIS Minimal Slight Moderate Serious Severe 0 1 2 3 4 NFPA Insignificant Slight Moderate High Extreme March 21, 2013 NEW HOSPECO HEALTH GARDS AIR FRESHENER VINEYARD, 7OZ. Mixture packaged in pressurized aerosol spray can. 2-Propanone 67-64-1 1000 ppm 500 ppm 750 ppm STEL Liquefied Petroleum Gas 68476-86-8 Unknown 1000 ppm *Section 313 Supplier Notification - Indicates hazardous ingredients which are toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372. >100°F 0.78 – 0.81g/ml No Data 20.0% >1.00 N/A Insoluble Water white clear liquid with a characteristic odor FLAMMABLE N/A N/A Dry chemical, CO2, Alcohol-resistant foam Keep containers cool using water spray. Use proper equipment to protect personnel from bursting containers. Contents under pressure. Do not expose to temperatures exceeding 120° F as containers may vent, rupture or burst. Unstable □ Stable ■ Heat, sparks open flames; Temp. > 120°F. May Occur □ Will not Occur ■ Acids, alkalis, Reducing agents, Strong oxidizing agents CO and CO2 HOSPECO Cleveland, Ohio 44143 [PHONE REDACTED] Page 120 of 262 Page 120 of 262 Page 120 of 262 Page 120 of 262 ---PAGE BREAK--- SECTION 6 - HEALTH HAZARDS Routes of Entry Inhalation: Yes Eyes / Skin: Yes Ingestion: Unlikely Signs and of Exposure (Acute & Chronic) Eye contact: Can cause eye irritation. include stinging, tearing, redness, and swelling of eyes; Skin contact: May cause mild skin irritation. Prolonged or repeated contact may dry the skin. may include redness, burning, drying and cracking of skin, and skin burns. Passage of this material into the body through the skin is possible, but it is unlikely that this would result in harmful effects during safe handling and use. Ingestion: Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. This material can get into the lungs during swallowing or vomiting. This can result into lung inflammation and other lung injury; Inhalation: Breathing of vapor or mist is possible. Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Medical Conditions Generally Aggravated by Exposure Pre-existing skin and lung disorders Chemical Listed as Carcinogen or Potential Carcinogen National Toxicology Program Yes No   I.A.R.C. Monographs Yes No   OSHA Yes No   Emergency and First Aid Procedures 1. Inhalation Immediately move to fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention. 2. Eyes Immediately move to fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention. 3. Skin Remove contaminated clothing. Wash exposed area with soap and water. If persist, seek medical attention. Launder clothing before reuse. 4. Ingestion Seek medical attention. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. SECTION 7 – SPECIAL PROTECTION INFORMATION Respiratory Protection (Specify Type) None required for normal use. Ventilation Local Exhaust Maintain adequate ventilation. Mechanical (General) N/A Special N/A Other N/A Protective Gloves Chemical Resistant Eye Protection Safety Glasses Other Protective Clothing or Equipment Wash hands after use. SECTION 8 – SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES Precautions to be Taken Handling and Storage WARNING: FLAMMABLE. Contents under pressure. Keep away from heat, sparks and open flames. Excessive inhalation in confined areas may cause headaches or dizziness. Intentional misuse by deliberately concentrating or inhaling the contents may be harmful or fatal. Avoid contact with skin and eyes. Avoid contact with food and food handling surfaces. Avoid contact with painted, varnished or plastic surfaces. Do not store at temperatures above 120°F. Do not puncture or incinerate containers. Keep out of reach of children. Store in accordance with NFPA 30B for Level 3 Aerosols. Other Precautions Read label cautions carefully. Follow label directions to avoid injury. Steps to be Taken in Case Material is Released or Spilled Absorb spill with inert material then place in a chemical waste container. Dispose of spill material in accordance with regulations. Waste Disposal Methods Dispose of in accordance with local, state, and federal regulations. Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986: This product is not known to contain any chemicals currently listed as carcinogens or reproductive toxins under California Proposition 65 at levels which would be subject to the proposition. Transportation Info DOT Shipping Name: Aerosols, Limited Quantity Hazard Class: Class 2.1(flammable gas) UN/ID Number: UN 1950 We believe all information given is accurate. It is offered in good faith, but without guarantee. Since conditions are beyond our control, user assumes all responsibility and risk. 1254354 / 9004354 / 9004117 132103 Page 121 of 262 Page 121 of 262 Page 121 of 262 Page 121 of 262 ---PAGE BREAK--- SAFETY DATA SHEET Spectrum Group Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Hot Shot Natural Flying Insect Killer 1-[PHONE REDACTED] HG-95844 21-1082 Page 1 SDS Date: 03/11/15 Product Name: Hot Shot Natural Flying Insect Killer CAS Aerosol Product Use: Flying Insect Killer Aerosol Manufacturer: Chemsico Div. of United Industries Corp. P.O. Box 142642 St. Louis, MO 63114 This product is classified according to the Globally Harmonized System (GHS). ROUTES OF EXPOSURE Potential short term health effects: Eyes, Skin Eyes: Causes moderate eye irritation. Skin: May cause skin irritation. Inhalation: No expected reaction. Ingestion: No expected reaction. Target organs: Eyes, Skin Chronic effects: Prolonged or repeated exposure can cause drying, defatting and dermatitis. Signs and may include redness, edema, drying, defatting and cracking of the skin. Composition comments: This product is considered not hazardous under 29 CFR 1910.1200 (Hazard Communication). NOTE: No reportable quantities of hazardous ingredients are present per OSHA 29 CFR 1910.1200. No toxic chemical(s) subject to reporting requirements of Section 313 of Title III and 40 CFR 372 are present. ACTIVE COMPONENT CAS# PERCENTAGE Lemongrass Oil 8007-02-1 3.00% Carbon Dioxide 124-38-9 2.50% OTHER COMPONENT CAS# PERCENTAGE Other N/A 94.50% Note: Ingredients not identified are not hazardous. SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION SECTION 2 - HAZARDS IDENTIFICATION SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS Page 122 of 262 Page 122 of 262 Page 122 of 262 Page 122 of 262 ---PAGE BREAK--- SAFETY DATA SHEET Spectrum Group Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Hot Shot Natural Flying Insect Killer 1-[PHONE REDACTED] HG-95844 21-1082 Page 2 FIRST AID PROCEDURES Eye contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses if present after the first 5 minutes then continue rinsing eye. Contact a physician for treatment advice. Skin contact: Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum or using the toilet. Inhalation: None required Ingestion: None required Note to Physician: Skin may be delayed. General advice: If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Keep out of reach of children. Flammable properties: Pressurized Aerosol Container. SUITABLE EXTINGUISHING MEDIA Extinguishing media: Water Fog, Foam, CO2, Dry Chemical Unsuitable extinguishing media: Not Available SPECIFIC HAZARDS ARISING FROM THE CHEMICAL Protection of firefighters: Not Available Protective equipment for firefighters: Firefighters should wear full protective clothing including self-contained breathing apparatus. Hazardous combustion products: None known SENSITIVITY TO MECHANICAL IMPACT Explosion data: Not Available Sensitivity to static discharge: Not Available Personal precautions: Keep unnecessary personnel away. Do not touch or walk through spilled material. HMIS Ratings Health Hazard 1 Fire Hazard 0 Reactivity 0 Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. SECTION 4 - FIRST AID MEASURES SECTION 5 - FIRE FIGHTING MEASURES SECTION 6 - ACCIDENTAL RELEASE MEASURES Page 123 of 262 Page 123 of 262 Page 123 of 262 Page 123 of 262 ---PAGE BREAK--- SAFETY DATA SHEET Spectrum Group Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Hot Shot Natural Flying Insect Killer 1-[PHONE REDACTED] HG-95844 21-1082 Page 3 Methods for cleaning up: Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with earth, sand or absorbent material swept up and placed in suitable, covered, and labeled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills in original containers for re-use. Handling: Use good industrial hygiene practices in handling this material. Storage: Keep out of reach of children. Store in a closed container away from incompatible materials. Engineering controls: General ventilation normally adequate. EYE / FACE PROTECTION Personal protective equipment: None required Hand protection: None required Skin and body protection: None required Respiratory protection: None required General hygiene considerations: Handle in accordance with good industrial hygiene and safety practice. When using, do not eat or drink. Wash hands before breaks and immediately after handling the product. Appearance: Clear to hazy Color: Yellow Form: Aerosol Odor: Lemongrass & Wintergreen Odor threshold: Not Available Physical state: Pressurized liquid pH: 8.3 Freezing point: 32°F Boiling point: 212°F Flash point: 1300F (liquid portion) Flame Extension 0” (level 1 aerosol) Flammability limits in air, lower, % by volume: Not Available SECTION 7 - HANDLING AND STORAGE SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES Page 124 of 262 Page 124 of 262 Page 124 of 262 Page 124 of 262 ---PAGE BREAK--- SAFETY DATA SHEET Spectrum Group Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Hot Shot Natural Flying Insect Killer 1-[PHONE REDACTED] HG-95844 21-1082 Page 4 Flammability limits in air, upper, % by volume: Not Available Vapor pressure: Not Available Vapor density: Not Available Specific gravity: 0.985 Octanol/water coefficient: Not Available Auto-ignition temperature: Not Available Chemical stability: Stable under recommended storage conditions. Conditions to avoid: Do not mix with other chemicals. Incompatible materials: Avoid strong oxidizers. Hazardous decomposition products: None known. Possibility of hazardous reactions: Hazardous polymerization does not occur. EFFECTS OF ACUTE EXPOSURE Eye: Causes temporary eye injury. Skin: May cause skin irritation. Inhalation: LC50 > 2mg/L (EPA Tox category IV) Ingestion: LD50 > 5000 mg/kg Sensitization: Not a skin sensitizer. Chronic effects/ Carcinogenicity: Not Available Mutagenicity: Not Available Reproductive effects: Not Available Teratogenicity: Not Available Ecotoxicity: Not Available Environmental effects: Not Available Aquatic toxicity: Not Available Persistence / degradability: Not Available Bioaccumulation / accumulation: Not Available Partition coefficient: Not Available Mobility in environmental media: Not Available Chemical fate information: Not Available SECTION 10 - CHEMICAL STABILITY & REACTIVITY INFORMATION SECTION 11 - TOXICOLOGICAL INFORMATION SECTION 12 - ECOLOGICAL INFORMATION Page 125 of 262 Page 125 of 262 Page 125 of 262 Page 125 of 262 ---PAGE BREAK--- SAFETY DATA SHEET Spectrum Group Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Hot Shot Natural Flying Insect Killer 1-[PHONE REDACTED] HG-95844 21-1082 Page 5 Waste codes: Not Available Disposal instructions: Dispose in accordance with all applicable regulations. Waste from residues / unused products: Not Available Contaminated packaging: Not Available U.S. Department of Transportation (DOT): Aerosols, Flammable, 2.1, UN-1950, Limited Quantity U.S. Federal regulations: This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. IATA: 1950, Aerosols, Flammable, 2.1 IMDG: 1950, Aerosols, 2.1, Limited Quantity 29 CFR 1910.1200 hazardous chemical Occupational Safety and Health Administration (OSHA): No CERCLA (Superfund) reportable quantity: Not Available HAZARD CATEGORIES Superfund Amendments and Reauthorization Act of 1986 (SARA): Immediate Hazard No Delayed Hazard No Fire Hazard No Pressure Hazard No Reactivity Hazard No Section 302 extremely hazardous Substance: No Section 311 hazardous chemical: No Clean Air Act (CAA): Not Available Clean Water Act (CWA): Not Available State regulations: INVENTORY STATUS Inventory Country(s) or region name on inventory (yes/no)*: N/A, Regulated by EPA SECTION 13 - DISPOSAL CONSIDERATIONS SECTION 14 - TRANSPORTATION INFORMATION SECTION 15 - REGULATORY INFORMATION Page 126 of 262 Page 126 of 262 Page 126 of 262 Page 126 of 262 ---PAGE BREAK--- SAFETY DATA SHEET Spectrum Group Division of United Industries Corp P.O. Box 142642 St. Louis, MO 63114-0642 Product Name: Phone: Items: Formula Code: Hot Shot Natural Flying Insect Killer 1-[PHONE REDACTED] HG-95844 21-1082 Page 6 Disclaimer: Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. Issue date: 3/11/15 Prepared by: United Industries Corp. (800) 242-1166 SECTION 16 - OTHER INFORMATION Page 127 of 262 Page 127 of 262 Page 127 of 262 Page 127 of 262 ---PAGE BREAK--- Page 128 of 262 Page 128 of 262 Page 128 of 262 Page 128 of 262 ---PAGE BREAK--- Page 129 of 262 Page 129 of 262 Page 129 of 262 Page 129 of 262 ---PAGE BREAK--- Page 130 of 262 Page 130 of 262 Page 130 of 262 Page 130 of 262 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Insect Repellent Product identifier Other means of identification 14011 Product code EPA: 51147-13-55809 Registration number Insect repellent Recommended use None known. Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufactured or sold by: Company name CRC Industries, Inc. Address 885 Louis Dr. Warminster, PA 18974 US Telephone General Information [PHONE REDACTED] Technical Assistance [PHONE REDACTED] Customer Service [PHONE REDACTED] 24-Hour Emergency [PHONE REDACTED] (US) (CHEMTREC) [PHONE REDACTED] (International) Website www.crcindustries.com 2. Hazard(s) identification Category 1 Flammable aerosols Physical hazards Liquefied gas Gases under pressure Category 4 Acute toxicity, oral Health hazards Category 4 Acute toxicity, dermal Category 2 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Sensitization, skin Category 3 narcotic effects Specific target organ toxicity, single exposure Category 2 Hazardous to the aquatic environment, acute hazard Environmental hazards Category 3 Hazardous to the aquatic environment, long-term hazard Not classified. OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause drowsiness or dizziness. Toxic to aquatic life. Harmful to aquatic life with long lasting effects. 1 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 131 of 262 Page 131 of 262 Page 131 of 262 Page 131 of 262 ---PAGE BREAK--- Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not apply while equipment is energized. Pressurized container: Do not pierce or burn, even after use. Extinguish all flames, pilot lights and heaters. Vapors will accumulate readily and may ignite. Use only with adequate ventilation; maintain ventilation during use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any listed on this label, increase ventilation or leave the area. Avoid breathing mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves/protective clothing. Wear eye/face protection. Avoid release to the environment. Response If swallowed: Call a poison center/doctor if you feel unwell. Rinse mouth. If on skin: Wash with plenty of water. If skin irritation or rash occurs: Get medical attention. Take off contaminated clothing and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Exposure to high temperature may cause can to burst. Disposal Dispose of contents/container in accordance with local/regional/national regulations. Hazard(s) not otherwise classified (HNOC) Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. Supplemental information 32.11% of the mixture consists of component(s) of unknown acute oral toxicity. 32.11% of the mixture consists of component(s) of unknown acute dermal toxicity. 72.39% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment. 3. Composition/information on ingredients Mixtures CAS number % Common name and synonyms Chemical name 67-63-0 Isopropyl alcohol 30 - 40 134-62-3 N,N-Diethyl-m-toluamide (DEET) 25.1 68476-86-8 Liquefied Petroleum Gas 20 - 30 113-48-4 Dicarboximide 5 - 10 136-45-8 Dipropyl isocinchomeronate 2.5 67-64-1 Acetone 1 - 3 57-55-6 Propylene glycol 1 - 3 Specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Inhalation Remove contaminated clothing immediately and wash skin with soap and water. In case of eczema or other skin disorders: Seek medical attention and take along these instructions. Wash contaminated clothing before reuse. Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Eye contact Rinse mouth. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Get medical advice/attention if you feel unwell. Ingestion May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash. Most important acute and delayed Provide general supportive measures and treat Keep victim warm. Keep victim under observation. may be delayed. Indication of immediate medical attention and special treatment needed Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse. General information 2 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 132 of 262 Page 132 of 262 Page 132 of 262 Page 132 of 262 ---PAGE BREAK--- 5. Fire-fighting measures Alcohol resistant foam. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Unsuitable extinguishing media Contents under pressure. Pressurized container may rupture when exposed to heat or flame. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture when exposed to heat or flame. General fire hazards 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Remove all possible sources of ignition in the surrounding area. Many vapors are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. The product is immiscible with water and will spread on the water surface. Stop the flow of material, if this is without risk. Prevent product from entering drains. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. Use appropriate containment to avoid environmental contamination. Environmental precautions 7. Handling and storage Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Do not taste or swallow. When using, do not eat, drink or smoke. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Avoid release to the environment. Wash contaminated clothing before reuse. For product usage instructions, please see the product label. Precautions for safe handling Level 3 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Avoid spark promoters. These alone may be insufficient to remove static electricity. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 3 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 133 of 262 Page 133 of 262 Page 133 of 262 Page 133 of 262 ---PAGE BREAK--- 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Components Type PEL 2400 mg/m3 Acetone (CAS 67-64-1) 1000 ppm PEL 980 mg/m3 Isopropyl alcohol (CAS 67-63-0) 400 ppm US. ACGIH Threshold Limit Values Value Components Type STEL 750 ppm Acetone (CAS 67-64-1) TWA 500 ppm STEL 400 ppm Isopropyl alcohol (CAS 67-63-0) TWA 200 ppm US. NIOSH: Pocket Guide to Chemical Hazards Value Components Type TWA 590 mg/m3 Acetone (CAS 67-64-1) 250 ppm STEL 1225 mg/m3 Isopropyl alcohol (CAS 67-63-0) 500 ppm TWA 980 mg/m3 400 ppm US. AIHA Workplace Environmental Exposure Level (WEEL) Guides Value Components Form Type TWA 10 mg/m3 Aerosol. Propylene glycol (CAS 57-55-6) Biological limit values ACGIH Biological Exposure Indices Value Components Determinant Specimen Sampling Time 50 mg/l Acetone Urine * Acetone (CAS 67-64-1) 40 mg/l Acetone Urine * Isopropyl alcohol (CAS 67-63-0) * - For sampling details, please see the source document. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Appropriate engineering controls Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles). Eye/face protection Skin protection Wear protective gloves such as: Nitrile. Viton®. Hand protection Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended. Other If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels. Respiratory protection Wear appropriate thermal protective clothing, when necessary. Thermal hazards When using do not smoke. Keep away from food and drink. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace. General hygiene considerations 4 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 134 of 262 Page 134 of 262 Page 134 of 262 Page 134 of 262 ---PAGE BREAK--- 9. Physical and chemical properties Appearance Liquid. Physical state Aerosol. Form Clear. Colorless. Color Mild. Alcoholic. Odor Odor threshold Not available. pH Not available. Melting point/freezing point -138.5 °F (-94.7 estimated Initial boiling point and boiling range 132.9 °F (56.1 estimated Flash point 75 °F (23.9 Tag Closed Cup Evaporation rate Moderate. Not available. Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower 2 % estimated Flammability limit - upper 12.8 % estimated Vapor pressure 1234.3 hPa estimated Vapor density > 1 (air = 1) Relative density 0.8 estimated Solubility (water) Immiscible. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 700 °F (371.1 estimated Decomposition temperature Not available. Viscosity (kinematic) Not available. Percent volatile 67.3 % estimated 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Reactivity Material is stable under normal conditions. Chemical stability No dangerous reaction known under conditions of normal use. Possibility of hazardous reactions Heat, flames and sparks. Contact with incompatible materials. Conditions to avoid Acids. Strong oxidizing agents. Isocyanates. Chlorine. Incompatible materials Carbon oxides. Nitrogen oxides (NOx). Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Skin contact Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Eye contact Causes serious eye irritation. Ingestion Harmful if swallowed. related to the physical, chemical and toxicological characteristics Headache. May cause drowsiness and dizziness. Nausea, vomiting. Severe eye irritation. may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash. Information on toxicological effects Acute toxicity In high concentrations, vapors are anesthetic and may cause headache, fatigue, dizziness and central nervous system effects. Harmful in contact with skin. Harmful if swallowed. Narcotic effects. May cause an allergic skin reaction. 5 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 135 of 262 Page 135 of 262 Page 135 of 262 Page 135 of 262 ---PAGE BREAK--- Test Results Product Species Insect Repellent Dermal Acute LD50 Rabbit 1380 mg/kg estimated Inhalation LC50 Rat 40990 ppm, 4 hours estimated 12 mg/l, 4 Hours estimated Oral LD50 Rat 1737 mg/kg estimated * Estimates for product may be based on additional component data not shown. TDL0 Human 117 g/kg estimated Causes skin irritation. Skin corrosion/irritation Causes serious eye irritation. Serious eye damage/eye irritation Respiratory sensitization Not a respiratory sensitizer. May cause an allergic skin reaction. Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. This product is not expected to cause reproductive or developmental effects. Reproductive toxicity Specific target organ toxicity - single exposure May cause drowsiness and dizziness. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. 12. Ecological information Toxic to aquatic life. Harmful to aquatic life with long lasting effects. Ecotoxicity Product Test Results Species Insect Repellent Aquatic Acute EC50 Crustacea 171.4605 ppm, 48 hours estimated Daphnia LC50 Fish 218.1529 ppm, 96 hours estimated Fish Components Test Results Species Acetone (CAS 67-64-1) Aquatic EC50 Crustacea 10294 - 17704 mg/l, 48 hours Water flea (Daphnia magna) LC50 Fish 4740 - 6330 mg/l, 96 hours Rainbow trout,donaldson trout mykiss) Isopropyl alcohol (CAS 67-63-0) Aquatic Acute EC50 Crustacea 7550 - 13299 mg/l, 48 hours Water flea (Daphnia magna) LC50 Fish 3200 mg/l, 96 hours Fathead minnow (Pimephales promelas) N,N-Diethyl-m-toluamide (DEET) (CAS 134-62-3) Aquatic LC50 Fish 106 - 114 mg/l, 96 hours Fathead minnow (Pimephales promelas) 6 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 136 of 262 Page 136 of 262 Page 136 of 262 Page 136 of 262 ---PAGE BREAK--- Components Test Results Species Propylene glycol (CAS 57-55-6) Aquatic LC50 Fish 710 mg/l, 96 hours Fathead minnow (Pimephales promelas) * Estimates for product may be based on additional component data not shown. Acute EC50 Crustacea 4850 - 34000 mg/l, 48 hours Water flea (Daphnia magna) No data is available on the degradability of this product. Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Acetone -0.24 Isopropyl alcohol 0.05 N,N-Diethyl-m-toluamide (DEET) 2.02 Propylene glycol -0.92 No data available. Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Disposal of waste from residues / unused products D001: Waste Flammable material with a flash point <140 F Hazardous waste code Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Contaminated packaging 14. Transport information DOT UN1950 UN number Aerosols, flammable, Limited Quantity UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk 2.1 Label(s) Not applicable. Packing group Read safety instructions, SDS and emergency procedures before handling. Special precautions for user N82 Special provisions 306 Packaging exceptions None Packaging non bulk None Packaging bulk IATA UN1950 UN number Aerosols, flammable, Limited Quantity UN proper shipping name 2.1 Class Transport hazard class(es) - Subsidiary risk Not applicable. Packing group No. Environmental hazards 10L ERG Code Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Allowed. Passenger and cargo aircraft Other information Allowed. Cargo aircraft only 7 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 137 of 262 Page 137 of 262 Page 137 of 262 Page 137 of 262 ---PAGE BREAK--- IMDG UN1950 UN number AEROSOLS, LIMITED QUANTITY UN proper shipping name 2 Class Transport hazard class(es) - Subsidiary risk Not applicable. Packing group No. Marine pollutant Environmental hazards Not available. EmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. SARA 304 Emergency release notification Not regulated. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance Dipropyl isocinchomeronate (CAS 136-45-8) CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1) Listed. CERCLA Hazardous Substances: Reportable quantity Acetone (CAS 67-64-1) 5000 LBS Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center ([PHONE REDACTED]) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated. Safe Drinking Water Act (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1) 6532 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1) 35 %WV DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1) 6532 Not regulated. Food and Drug Administration (FDA) US EPA Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA) This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. FIFRA Information Warning. Signal word Harmful if swallowed. Causes substantial but temporary eye injury. This product is registered in all 50 United States and Puerto Rico. This product is not registered outside of the United States and Puerto Rico. Hazard statement 8 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 138 of 262 Page 138 of 262 Page 138 of 262 Page 138 of 262 ---PAGE BREAK--- Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Section 311/312 Hazard categories No SARA 302 Extremely hazardous substance US state regulations US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. Acetone (CAS 67-64-1) Dipropyl isocinchomeronate (CAS 136-45-8) Isopropyl alcohol (CAS 67-63-0) Liquefied Petroleum Gas (CAS 68476-86-8) US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. New Jersey Worker and Community Right-to-Know Act Acetone (CAS 67-64-1) Propylene glycol (CAS 57-55-6) Dipropyl isocinchomeronate (CAS 136-45-8) Isopropyl alcohol (CAS 67-63-0) US. Massachusetts RTK - Substance List Acetone (CAS 67-64-1) Isopropyl alcohol (CAS 67-63-0) US. Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Isopropyl alcohol (CAS 67-63-0) Propylene glycol (CAS 57-55-6) US. Rhode Island RTK Acetone (CAS 67-64-1) Dipropyl isocinchomeronate (CAS 136-45-8) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Benzene (CAS 71-43-2) Listed: February 27, 1987 Cumene (CAS 98-82-8) Listed: April 6, 2010 Dipropyl isocinchomeronate (CAS 136-45-8) Listed: May 1, 1996 Ethanal (CAS 75-07-0) Listed: April 1, 1988 US - California Proposition 65 - CRT: Listed date/Developmental toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 Toluene (CAS 108-88-3) Listed: January 1, 1991 US - California Proposition 65 - CRT: Listed date/Female reproductive toxin Toluene (CAS 108-88-3) Listed: August 7, 2009 US - California Proposition 65 - CRT: Listed date/Male reproductive toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 64.9 % Not regulated Consumer products (40 CFR 59, Subpt. C) State This product is regulated as an Insect Repellent. This product is compliant for use in all 50 states. Consumer products VOC content (CA) 64.9 % VOC content (OTC) 64.9 % 9 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 139 of 262 Page 139 of 262 Page 139 of 262 Page 139 of 262 ---PAGE BREAK--- International Inventories Country(s) or region Inventory name On inventory (yes/no)* Yes Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory No Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 05-21-2015 Issue date Allison Cho Prepared by Version # 01 CRC # 926 Further information Health: 1 Flammability: 3 Physical hazard: 0 Personal protection: B HMIS® ratings Health: 1 Flammability: 3 Instability: 0 NFPA ratings NFPA ratings 0 1 3 The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries. Disclaimer 10 / 10 Material name: Insect Repellent 14011 Version 01 Issue date: 05-21-2015 SDS US Page 140 of 262 Page 140 of 262 Page 140 of 262 Page 140 of 262 ---PAGE BREAK--- SAFETY DATA SHEET Issuing Date: 18-Feb-2015 Revision Date: 18-Feb-2015 Version 1 1. IDENTIFICATION Product Name Ivory Original Liquid Hand Soap Product ID: 97161377_RET_NG Product Type: Finished Product - Consumer (Retail) Use Only Recommended Use Personal Beauty Care Product Manufacturer The Procter & Gamble Company Sharon Woods Innovation Center 11510 Reed Hartman Highway Cincinnati OH 45241 +1 [PHONE REDACTED] E-mail Address Emergency Telephone Transportation (24 HR) CHEMTREC - 1-[PHONE REDACTED] Canada) or 1-[PHONE REDACTED] Mexico toll free in country: [PHONE REDACTED] 2. HAZARD IDENTIFICATION "Consumer Products", as defined by the US Consumer Product Safety Act and which are used as intended (typical consumer duration and frequency), are exempt from the OSHA Hazard Communication Standard (29 CFR 1910.1200). This SDS is being provided as a courtesy to help assist in the safe handling and proper use of the product. This product is classifed under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:. Eye Damage / Irritation Category 2B Signal Word WARNING Hazard Statements Causes eye irritation Hazard pictograms None Precautionary Statements - Prevention Wash hands thoroughly after handling Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention Precautionary Statements - Storage None Page 1 / 6 Precautionary Statements - None Page 141 of 262 Page 141 of 262 Page 141 of 262 Page 141 of 262 ---PAGE BREAK--- 97161377_RET_NG - Ivory Original Liquid Hand Soap Revision Date: 18-Feb-2015 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation 4. FIRST AID MEASURES First aid measures for different exposure routes Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact None under normal use. Ingestion Not an expected route of exposure. If swallowed:. Clean mouth with water and afterwards drink plenty of water. Inhalation None under normal use. Most important acute and delayed May cause eye irritation. Indication of immediate medical attention and special treatment needed, if necessary Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Water. Dry chemical. Alcohol-resistant foam. Unsuitable Extinguishing Media None. Special hazard None known. Special protective equipment for fire-fighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Specific hazards arising from the chemical None. 6. ACCIDENTAL RELEASE MEASURES Disposal Hazards not otherwise classified (HNOC) None Chemical Name Synonyms Trade Secret CAS-No Weight % Poly(oxy-1,2-ethanediyl), alpha-sulfo-omega-(dodecyloxy)-, sodium salt (1:1) - No 9004-82-4 5 - 10 Sulfuric acid monododecyl ester sodium salt (1:1) - No 151-21-3 1 - 5 1-Propanaminium, 3-amino-N-(carboxymethyl)-N,N-dimet hyl-, N-coco acyl derivs., inner salts Page 2 / 6 - No 61789-40-0 1 - 5 Page 142 of 262 Page 142 of 262 Page 142 of 262 Page 142 of 262 ---PAGE BREAK--- 97161377_RET_NG - Ivory Original Liquid Hand Soap Revision Date: 18-Feb-2015 Personal precautions, protective equipment and emergency procedures Personal precautions None under normal use conditions. Advice for emergency responders Use personal protective equipment as required. Environmental precautions Do not discharge product into natural waters without pre-treatment or adequate dilution. Methods and materials for containment and cleaning up Methods for containment Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. Methods for cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Keep container closed when not in use. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers closed in a dry, cool and well-ventilated place. Incompatible products None known. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Exposure guidelines are not relevant when product is used as intended in a household setting. Exposure controls Engineering Measures No information available Personal Protective Equipment Eye Protection Manufacturing Sites: Safety glasses with side-shields Distribution, Workplace and Household Settings: No special protective equipment required Hand Protection No special protective equipment required Skin and Body Protection No special protective equipment required Respiratory Protection No special protective equipment required 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State @20°C liquid Appearance clear blue-green Odor characteristic Odor threshold No information available Property Values Note pH value 5.8 - 7.3 Page 3 / 6 Melting/freezing point No information available Page 143 of 262 Page 143 of 262 Page 143 of 262 Page 143 of 262 ---PAGE BREAK--- 97161377_RET_NG - Ivory Original Liquid Hand Soap Revision Date: 18-Feb-2015 VOC Content Products comply with US state and federal regulations for VOC content in consumer products. 10. STABILITY AND REACTIVITY Reactivity None under normal use conditions. Stability Stable under normal conditions. Hazardous polymerization Hazardous polymerization does not occur. Hazardous Reactions None under normal processing. Conditions to Avoid None under normal processing. Materials to avoid None in particular. Hazardous Decomposition Products None under normal use. 11. TOXICOLOGICAL INFORMATION Product Information Information on likely routes of exposure Inhalation No known effect. Skin contact No known effect. Ingestion No known effect. Eye contact Avoid contact with eyes. Irritating to eyes. Delayed and immediate effects as well as chronic effects from short and long-term exposure Acute toxicity No known effect. Skin corrosion/irritation No known effect. Serious eye damage/eye irritation Irritating to eyes. Skin sensitization No known effect. Respiratory sensitization No known effect. Germ cell mutagenicity No known effect. Neurological Effects No known effect. Reproductive toxicity No known effect. Developmental toxicity No known effect. Teratogenicity No known effect. STOT - single exposure No known effect. STOT - repeated exposure No known effect. Target Organ Effects No known effect. Aspiration hazard No known effect. Carcinogenicity No known effect. Boiling point/boiling range No information available Flash point No information available Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limits in Air Upper flammability limit No information available Lower Flammability Limit No information available Vapor pressure No information available Vapor density No information available Relative density No information available Water solubility No information available Solubility in other solvents No information available Partition coefficient: n-octanol/waterNo information available Autoignition temperature No information available . Decomposition temperature No information available . Viscosity of Product No information available Page 4 / 6 Page 144 of 262 Page 144 of 262 Page 144 of 262 Page 144 of 262 ---PAGE BREAK--- 97161377_RET_NG - Ivory Original Liquid Hand Soap Revision Date: 18-Feb-2015 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not expected to be hazardous to the environment. Persistence and degradability No information available. Bioaccumulative potential No information available. Mobility No information available. Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Waste treatment Waste from Residues / Unused Products Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Codes (non-household setting) 561 14. TRANSPORT INFORMATION DOT Not regulated IMDG Not regulated IATA Not regulated 15. REGULATORY INFORMATION U.S. Federal Regulations SARA 313 Not applicable for consumer use CERCLA Not applicable for consumer use Food and Drug Administration (FDA) The product described in this Material Safety Data Sheet is regulated under the Federal Food, Drug, and Cosmetics Act and is safe to use as per directions on container, box or accompanying literature (where applicable) Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) Not applicable for consumer use Page 5 / 6 Clean Water Act Not applicable for consumer use Page 145 of 262 Page 145 of 262 Page 145 of 262 Page 145 of 262 ---PAGE BREAK--- 97161377_RET_NG - Ivory Original Liquid Hand Soap Revision Date: 18-Feb-2015 California Proposition 65 This product is not subject to warning labeling under California Proposition 65. U.S. State Regulations (RTK) Not applicable for consumer use International Inventories United States Product is a personal care product and regulated under FDA. Canada This product is in compliance with CEPA for import by P&G. Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory CEPA - Canadian Environmental Protection Act Perfumes contained with the products comply with appropriate IFRA guidance. 16. OTHER INFORMATION Issuing Date: 18-Feb-2015 Revision Date: 18-Feb-2015 Reason for revision Initial Release. Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text Page 6 / 6 End of SDS Page 146 of 262 Page 146 of 262 Page 146 of 262 Page 146 of 262 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET SECTION 1: PRODUCT AND COMPANY IDENTIFICATION MSDS 0108KD Issue Date: 6/9/2003 PRODUCT NAME: Kiwi Select All Protector Rain and Stain Protector GENERAL USE: Waterproofing aerosol. APPEARANCE: Aerosol concentrate is clear to pale straw. Distributor in USA Distributor in Canada Sara Lee Household & Body Care USA Sara Lee Household & Body Care -Canada 707 Eagleview Blvd. Cambridge, Ontario N1T1B2 Canada Exton, PA 19341-1124 USA EMERGENCY TELEPHONE NUMBER EMERGENCY TELEPHONE NUMBER: (519) 622-9800 CHEM-TEL, INC. 1- (800) 255-3924, Outside U.S.A. (813) 248-0585 SECTION 2 - HAZARDOUS INGREDIENTS HAZARDOUS CAS # % OSHA PEL ACGIH SARA SARA INGREDIENTS (By weight) TWA 302 313 ACETIC ACID, BUTYL 123864 1 TO 3 TWA 150PPM 150 ppm No No ESTER STEL 200PPM HEPTANE 142825 65 TO 72 TWA 500PPM 400 ppm No No STEL None MINERAL SPIRITS 64742887 1 TO 3 TWA None None No No STEL None ISOPROPYL ALCOHOL 67630 1 TO 3 TWA 400PPM 400 ppm No Yes STEL 500PPM PROPANE 74986 9 TO 13 TWA 1000PPM 2500 ppm No No STEL None PROPANE, 2-METHYL- 75285 12 TO 16 TWA None 800 ppm No No STEL None In Canada, Not a WHMIS Controlled Product (Consumer Commodity) SECTION 3 - HAZARDS IDENTIFICATION Ingestion: May be harmful or fatal if swallowed. This product may be aspirated into the lungs during swallowing or vomiting and cause lung damage. Eye Contact: Aerosol mist may irritate eyes; always direct spray away from face. Solvent vapors may irritate eyes; always use in well ventilated area. Direct eye contact with product may cause stinging, tearing, redness or swelling. Inhalation: Intentional misuse by deliberately concentrating and inhaling vapors can be harmful or fatal. High vapor concentrations resulting from misuse may cause irritation to the respiratory tract. Overexposure may include headaches, dizziness, and irritation to the respiratory tract. Overexposure may include headaches, dizziness, anesthetic, and include redness, burning, drying, and cracking of skin. CHRONIC: Repeated or prolonged exposure may lead to drying of skin, defatting of skin and dermatitis. SECTION 4 - FIRST AID MEASURES INHALATION Remove person to fresh air; contact a physician and/or transport to medical facility. If victim is not breathing, immediately begin artificial respiration. If breathing difficulties develop, oxygen may be given by qualified personnel. SKIN / EYE CONTACT Eye: Flush eyes with water for 15 minutes. If irritation develops, seek medical attention. Skin: Wash exposed skin with soap and water. If irritation develops, seek medical attention. INGESTION: Do not induce vomiting. Contact a poison control center or physician immediately. If victim is unconscious or drowsy, place them on their left side with head down. SECTION 5 - FIRE FIGHTING MEASURES FLASH POINT Propellant: -104 C (-156 F) Concentrate: Approximately -8 C (18 F) Product determined to be extremely flammable as per U. S. Federal Hazardous Substance Act 16 CFR 1500.45 and Canadian Hazardous Products Act. Page 1 of 4 Page 147 of 262 Page 147 of 262 Page 147 of 262 Page 147 of 262 ---PAGE BREAK--- FLAMMABLE LIMITS LEL: N.D. UEL N.D. AUTOIGNITION TEMP. N.D. NFPA AEROSOL LEVEL: 3 EXTINGUISHING MEDIA Foam, carbon dioxide, dry chemical or water fog. FIRE FIGHTING PROCEDURE : Use air supplied breathing equipment. UNUSUAL FIRE & EXPLOSION HAZARDS Water may be ineffective. Aerosol cans may explode from internal pressure build-up when exposed to extreme heat. Water may be used to cool containers and prevent explosion. HAZ. COMBUSTION PRODUCTS Combustion will yield carbon dioxide and/or carbon monoxide. SECTION 6: ENVIRONMENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED - Wear proper personal protective equipment. Remove all possible ignition sources. Provide adequate ventilation. Keep out of water supply. Mop up, wipe up, or soak up with absorbent. Place spill cleanup material in an approved container. SECTION 7: HANDLING AND STORAGE PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE - This product is classified as a Level III aerosol in accordance with the National Fire Protection Association DANGER: Keep away from heat and flame. Do not use while smoking. Do not puncture, incinerate, or store above 49 C (120 SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS Local exhaust required if using large amounts of product in a confined area. PERSONAL PROTECTION: RESPIRATORY PROTECTION (SPECIFY TYPE): Use approved cartridge respirator or supplied air if exposure limits are exceeded. PROTECTIVE GLOVES Chemical resistant gloves if sensitivity exists or if repeated or prolonged contact occurs. EYE PROTECTION: Safety glasses recommended when using any aerosol. OTHER PROTECTION: DANGER: Keep away from heat and flame. Do not use while smoking. WORK / HYGIENIC PRACTICES: Practice safe workplace habits. Minimize body contact with this as well as all chemicals in general. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES VAPOR PRESSURE (MM Hg) N.D. VAPOR DENSITY (AIR =1 ) N.D. SPECIFIC GRAVITY (WATER 0.7 EVAPORATION RATE (WATER N.D. SOLUBILITY IN WATER Slight. FREEZING POINT N.D. pH N.D. ODOR Characteristic. BOILING POINT N.D. VOLATILE ORGANIC COMPOUND (Total VOC’s) 99% SECTION 10 - STABILITY AND REACTIVITY STABILITY: Stable. CONDITIONS TO AVOID: DANGER: Keep away from heat and flame. Do not use while smoking. Do not puncture, incinerate, or store at temperatures above 49 C (120 If swallowed or if excessive inhalation occurs resulting in abnormal reactions including dizziness or nausea, contact a physician. Do not induce vomiting. If eye contact occurs, flush eyes with water for 15 minutes and contact physician. Use in a well- ventilated area. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Contains hydrocarbon propellant and petroleum distillates. Keep out of reach of children. INCOMPATIBILITY (MATERIALS TO AVOID) Strong oxidizing agents, hot surfaces, and open flames. HAZARDOUS DECOMPOSITION PRODUCTS: Combustion will yield carbon dioxide and/or carbon monoxide. Decomposition products dependent on combustion conditions. HAZARDOUS POLYMERIZATION Will not occur. Page 2 of 4 Page 148 of 262 Page 148 of 262 Page 148 of 262 Page 148 of 262 ---PAGE BREAK--- SECTION 11 -TOXICOLOGICAL INFORMATION Hazardous Ingredients % CAS # LD50 of Ingredients LC50 of Ingredients (Specify Species and Route (Specify Species and Route) ISOPROPYL ALCOHOL 1 TO 3 67630 5045 mg/kg N.AV. Rat-oral PROPANE, 2-METHYL- 12 TO 16 75285 N.AV. 57 pph/15 min. Rat-inh PROPANE 9 TO 13 74986 N.AV. N.AV. HEPTANE 65 TO 72 142825 222 mg/kg 75 g/m3 Mus-i.v. Mus-inh ACETIC ACID, BUTYL ESTER 1 TO 3 123864 13100 mg/kg 2000 ppm/4 hr Rat-oral Rat-inh MINERAL SPIRITS 1 TO 3 64742887 N.AV. N.AV. SECTION 12 -ECOLOGICAL INFORMATION None. SECTION 13 - DISPOSAL INFORMATION Dispose of product in accordance with federal, state, and local regulations. SECTION 14 - TRANSPORTATION INFORMATION aerosols, flammable UN 1950, Hazard Division 2.1 reclassed Consumer Commodity ORM-D for ground transportation SECTION 15 - REGULATORY INFORMATION TSCA (Toxic Substance Control Act): Components of this product are listed on the TSCA Inventory. SARA TITLE III (Superfund Amendments and Reauthorization Act) ,Canadian Regulations and California Prop 65: Chemical Name CAS # SARA 313 SARA 302 CANADA IDL DSL NDSL ISOPROPYL ALCOHOL 67630 Yes No Yes Yes No PROPANE, 2-METHYL- 75285 No No No Yes No PROPANE 74986 No No No Yes No HEPTANE 142825 No No Yes Yes No ACETIC ACID, BUTYL ESTER 123864 No No Yes Yes No MINERAL SPIRITS 64742887 No No No Yes No Chemical Name CAS # Prop65 Prop65 Prop65 Prop65 Cancer Developmental Female Male Reproductive Reproductive ISOPROPYL ALCOHOL 67630 No No No No PROPANE, 2-METHYL- 75285 No No No No PROPANE 74986 No No No No HEPTANE 142825 No No No No ACETIC ACID, BUTYL ESTER 123864 No No No No MINERAL SPIRITS 64742887 No No No No Page 3 of 4 Page 149 of 262 Page 149 of 262 Page 149 of 262 Page 149 of 262 ---PAGE BREAK--- SECTION 16 -OTHER INFORMATION US SKU 382-001 Canada SKU HMIS HAZARD HEALTH: 2 0 = INSIGNIFICANT 3 = HIGH FLAMMABILITY 4 1 = SLIGHT 4 = EXTREME REACTIVITY: 1 2 = MODERATE PERSONAL PROTECTION EQUIPMENT: None MSDS Prepared By: SCH SARA LEE Household and Body Care - USA Issue Date: 6/9/2003 707 Eagleview Blvd Exton, PA 19341 (610) 321-2171 THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND EXPRESSED OR IMPLIED IS MADE WITH RESPECT TO THE INFORMATION CONTAINED HEREIN. Page 4 of 4 Page 150 of 262 Page 150 of 262 Page 150 of 262 Page 150 of 262 ---PAGE BREAK--- page 1 of 6 DATE OF PREPARATION May 4, 2015 MATERIAL SAFETY DATA SHEET TT3701 06 00 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER TT3701 PRODUCT NAME KRYLON® Industrial QUIK-MARK™ Solvent-Based Inverted Marking Paint (Fluorescent), Red Orange MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY KRYLON INDUSTRIAL PRODUCTS GROUP Cleveland, OH 44115 Telephone Numbers and Websites Product Information (800) 247-3266 www.kpg-industrial.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident) Page 151 of 262 Page 151 of 262 Page 151 of 262 Page 151 of 262 ---PAGE BREAK--- TT3701 page 2 of 6 HMIS Codes Health 2* Flammability 3 Reactivity 0 SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight CAS Number Ingredient Units Vapor Pressure 14 74-98-6 Propane ACGIH TLV 1000 PPM 760 mm OSHA PEL 1000 PPM 6 106-97-8 Butane ACGIH TLV 1000 PPM 760 mm OSHA PEL 800 PPM 8 110-54-3 Hexane ACGIH TLV 50 PPM 127 mm OSHA PEL 50 PPM 4 107-83-5 ACGIH TLV Not Available 211 mm OSHA PEL Not Available 1 96-14-0 ACGIH TLV 500 PPM 211 mm OSHA PEL Not Available 1 79-29-8 ACGIH TLV Not Available 230 mm OSHA PEL Not Available 9 142-82-5 Heptane ACGIH TLV 400 PPM 50 mm ACGIH TLV 500 PPM STEL OSHA PEL 400 PPM OSHA PEL 500 PPM STEL 7 64742-89-8 Lt. Aliphatic Hydrocarbon Solvent ACGIH TLV 300 PPM 12 mm OSHA PEL 300 PPM 0.4 100-41-4 ACGIH TLV 20 PPM 7.1 mm OSHA PEL 100 PPM OSHA PEL 125 PPM STEL 2 1330-20-7 Xylene ACGIH TLV 100 PPM 5.9 mm ACGIH TLV 150 PPM STEL OSHA PEL 100 PPM OSHA PEL 150 PPM STEL 0.3 14808-60-7 Quartz ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.1 mg/m3 as Resp. Dust 27 1317-65-3 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system the reproductive system SIGNS AND OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Page 152 of 262 Page 152 of 262 Page 152 of 262 Page 152 of 262 ---PAGE BREAK--- TT3701 page 3 of 6 UEL 9.5 LEL 0.9 FLASH POINT Propellant < 0 °F SECTION 4 — FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Page 153 of 262 Page 153 of 262 Page 153 of 262 Page 153 of 262 ---PAGE BREAK--- TT3701 page 4 of 6 SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 7.36 lb/gal 881 g/l SPECIFIC GRAVITY 0.89 BOILING POINT <0 - 325 °F <-18 - 162 °C MELTING POINT Not Available VOLATILE VOLUME 78% EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available pH > 2.0, < 11.5 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 56.41% Less Water and Federally Exempt Solvents SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Prolonged and repeated exposure to Hexane may cause damage to nerve tissue of the arms and legs (peripheral neuropathy), resulting in muscular weakness and loss of sensation. This effect may be increased by the presence of Methyl Ethyl Ketone. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that causes cancer in humans. Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. Page 154 of 262 Page 154 of 262 Page 154 of 262 Page 154 of 262 ---PAGE BREAK--- TT3701 page 5 of 6 TOXICOLOGY DATA CAS No. Ingredient Name 74-98-6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106-97-8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 110-54-3 Hexane LC50 RAT 4HR Not Available LD50 RAT 28700 mg/kg 107-83-5 LC50 RAT 4HR Not Available LD50 RAT Not Available 96-14-0 LC50 RAT 4HR Not Available LD50 RAT Not Available 79-29-8 LC50 RAT 4HR Not Available LD50 RAT Not Available 142-82-5 Heptane LC50 RAT 4HR Not Available LD50 RAT Not Available 64742-89-8 Lt. Aliphatic Hydrocarbon Solvent LC50 RAT 4HR Not Available LD50 RAT Not Available 100-41-4 LC50 RAT 4HR Not Available LD50 RAT 3500 mg/kg 1330-20-7 Xylene LC50 RAT 4HR 5000 ppm LD50 RAT 4300 mg/kg 14808-60-7 Quartz LC50 RAT 4HR Not Available LD50 RAT Not Available 1317-65-3 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U IATA/ICAO UN1950, AEROSOLS, FLAMMABLE, 2.1, LIMITED QUANTITY Page 155 of 262 Page 155 of 262 Page 155 of 262 Page 155 of 262 ---PAGE BREAK--- TT3701 page 6 of 6 SECTION 15 — REGULATORY INFORMATION SARA 313 SUPPLIER NOTIFICATION (40 CFR 372.65C) CAS No. CHEMICAL/COMPOUND % by WT % Element 110-54-3 Hexane 8 100-41-4 0.3 1330-20-7 Xylene 2 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 156 of 262 Page 156 of 262 Page 156 of 262 Page 156 of 262 ---PAGE BREAK--- Date Issued: 09/15/08 MSDS Ref BULK-NA220-00A Date Revised: 07/09/12 Page 1 of 2 Manufacturer: Sun & Skin Care Research, LLC d/b/a Ocean Potion Address: 851 Greensboro Road, Cocoa FL 32926 Emergency Telephone: (CHEMTREC) (800) 424-9300 Information Telephone: (800) 715-3485 Product Name: No-Ad SPF 50 Sport Sunblock Lotion Product ID: BULK-NA220-00A Chemical/Common Name CAS Number % (w/w) Not Applicable Emergency overview: No Hazard to the skin: for external use only. Do not use in eyes. Eye contact: May cause eye irritation. Skin contact: Does not irritate skin under normal conditions. Ingestion: May cause irritation to the membranes of the mouth, throat and gastrointestinal tract. Abdominal discomfort, nausea, and diarrhea may occur. Inhalation: High vapor concentrations may cause a burning sensation in the nose and throat, and stinging and watering in the eyes. Chronic effects: Not determined. Other health hazards: Not determined. The TLV of the mixture has not been established. Eye contact: Remove contact lenses, if used. Flush eyes with water for at least 15 minutes holding eyelids open. Contact physician if irritation persists. Skin contact: Wash off skin with water. Contact physician if irritation persists. Ingestion: Give two glasses of water. Contact Poison Control Center. Inhalation: Remove to fresh air. Give artificial respiration if not breathing. Consult a physician if of respiratory discomfort persist. Flash point: >200°F Extinguishing media: Dry chemical, foam or water spray/fog Incompatibility (Materials to avoid): None known. Special Fire Fighting Procedures: Self-contained positive pressure breathing apparatus and protective clothing should be worn in fighting fires involving chemicals. The liquid will not sustain combustion. Remove product containers from fire area if possible. Do not scatter spilled materials with high pressure water streams. Unusual fire and Explosion hazards: None known. Wear protective clothing. Contain spills. Scoop or shovel material into containers. Rinse residue with water as material can cause slippery conditions. Prevent wash water from entering drinking water supplies or waterways. Report all emergency spills/leaks by phone to 911. CHEMTREC is a national center established by the Chemical Manufacturer Association (CMA) in Washington DC, to relay pertinent information concerning specific chemicals on request. CHEMTREC has a 24-hour toll-free number (800) 424-9300 STORAGE: Avoid freezing or excessive heat/open flame. HANDLING: Avoid contact with eyes. Keep out of reach of children. EYE/FACE PROTECTION: When packing or mechanically working with this product, wear safety glasses or coverall goggles. RESPIRATORS: When packing or mechanically working this product, wear NIOSH approved respiratory protection if there is potential for airborne exposures in excess of applicable limits. VENTILATION: Normal area ventilation is sufficient in most cases to keep this product within applicable limits. SKIN: Gloves may be required for certain workers who have sensitive skin or contact dermatitis OTHER: Observe good personal hygiene. MATERIAL SAFETY DATA SHEET 1. PRODUCT IDENTIFICATION 2. COMPOSITION / INGREDIENT INFORMATION 7. HANDLING AND STORAGE 8. PERSONAL PROTECTIVE EQUIPMENT (PPE) 4. FIRST AID MEASURES 5. FIRE FIGHTING MEASURES 3. HAZARDS IDENTIFICATION 6. ACCIDENTAL RELEASE PROCEDURES 5. FIRE FIGHTING MEASURES (CONT) Page 157 of 262 Page 157 of 262 Page 157 of 262 Page 157 of 262 ---PAGE BREAK--- Date Issued: 09/15/08 MSDS Ref BULK-NA220-00A Date Revised: 07/09/12 Page 2 of 2 APPEARANCE: White Lotion PHYSICAL STATE: Lotion Emulsion BOILING POINT: 100 °C SOLUBILITY IN WATER: Miscible SPECIFIC GRAVITY: 0.96 – 1.03 pH: 6.50 – 7.50 FRAGRANCE: None Stability: Stable under normal conditions. Conditions to avoid: Avoid heat/open flames. Do not freeze. Incompatibility (Materials to avoid): None known. Hazardous decomposition or products: None generated under normal storage or handling conditions. Hazardous polymerization: Will not occur. No data available. Follow all federal, state, and local regulations regarding proper disposal. Proper shipping name: Not regulated. US DOT: This product is not a Hazardous Material according to the Hazardous Materials Transportation Act and DOT regulation is 49CFR. Canadian TDG: Not regulated. UNITED STATES FEDERAL REGULATIONS DOT: Registered with the U.S Department of Transportation as required by 49 CFR Part 107, Subpart G. Information available upon request. • • OSHA: United States Occupational Safety and Health Administration www.OSHA.gov • NIOSH: National Institute of Occupational Safety & Health www.niosh.com • EPA: United States Environmental Protection Agency www.epa.gov • PHMSA: United States Department of Transportation Pipeline and Hazardous Materials Safety Administration. www.phmsa.dot.gov • http://safety.science.tamu.edu/nfpa.h • http://www.paint.org/hmis/hmis_ratings.pdf HAZARD RATINGS HMIS Classification: Health: 0 Flammability: 0 Physical Hazard: 0 Reactivity: 0 Figure 1 NFPA Ratings NFPA Classification: Health Hazard: 0 Fire Hazard Flash Points: 0 Reactivity Hazard: 0 Specific Hazards: Manufacture Disclaimer: The information presented herein has been compiled from reputable and current sources as of the date provided without any warranty, expressed or implied, regarding its correctness or accuracy. Since the use of the information and the use of the product are not within the control of SSCR, it is the user’s responsibility to determine safe conditions for use and to assume liability for loss, injury, damage, or exposure resulting from the misuse of this product. 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY DATA 13. TRANSPORATION INFORMATION 14. REGULATORY INFORMATION 11. ECOLOGICAL INFORMATION 16. OTHER INFORMATION 15. MAJOR REFERENCES 12. DISPOSAL CONSIDERATIONS Page 158 of 262 Page 158 of 262 Page 158 of 262 Page 158 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 1/12 1. PRODUCT AND COMPANY IDENTIFICATION Product information Product name : OFF!® DEEP WOODS® INSECT REPELLENT VII Recommended use : Insect Repellent Manufacturer, importer, supplier : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236 Telephone : +18005585252 Emergency telephone number : 24 Hour Medical Emergency Phone: (866)231-5406 24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300 2. HAZARDS IDENTIFICATION Classification of the substance or mixture Globally Harmonized System (GHS) Classification Hazard classification Hazard category Hazards identification Flammable liquids Category 3 Flammable liquid and vapour. Eye irritation Category 2A Causes serious eye irritation. Labelling Hazard symbols Flame Exclamation mark Signal word Warning Hazard statements Flammable liquid and vapour. Causes serious eye irritation. Precautionary statements If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. Page 159 of 262 Page 159 of 262 Page 159 of 262 Page 159 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 2/12 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. Store in a well-ventilated place. Keep cool. Dispose of contents/ container to an approved incineration plant. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container closed. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves. Wash hands thoroughly after handling. Use explosion-proof electrical/ ventilating/ lighting/ equipment. Other hazards : None identified 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No. Weight percent Ethyl alcohol 64-17-5 30.00 - 60.00 N,N-Diethyl-m-toluamide 134-62-3 10.00 - 30.00 The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. Skin contact : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If you suspect a reaction to this product, discontinue use and remove contaminated clothing. Inhalation : No special requirements. Ingestion : No special requirements Page 160 of 262 Page 160 of 262 Page 160 of 262 Page 160 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 3/12 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during firefighting : Flammable liquid. Vapors are heavier than air and may travel to a source of ignition and flash back. Liquid run-off to sewers may create fire/explosion hazard. Container may melt and leak in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses. Further information : Fight fire from maximum distance or protected area. Cool and use caution when approaching or handling fire-exposed containers. For large quantities of flammable liquids, consider containment to prevent the spread of fire. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Remove all sources of ignition. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Wear personal protective equipment. Wash thoroughly after handling. Environmental precautions : Do not flush into surface water or sanitary sewer system. Use appropriate containment to avoid environmental contamination. Outside of normal use, avoid release to the environment. Methods and materials for containment and cleaning up : Soak up with inert absorbent material. Use only non-sparking equipment. Dike large spills. Clean residue from spill site. Page 161 of 262 Page 161 of 262 Page 161 of 262 Page 161 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 4/12 7. HANDLING AND STORAGE Handling Precautions for safe handling : Avoid contact with eyes and lips. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Wash thoroughly after handling. Advice on protection against fire and explosion : Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge. Use only non-sparking tools. Use explosion-proof equipment. Ground/bond container and receiving equipment. Storage Requirements for storage areas and containers : Keep container closed when not in use. Keep away from food, drink and animal feedingstuffs. Keep closed. Store in a well-ventilated place. Keep cool. Other data : Stable under normal conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Non- standard units Basis Ethyl alcohol 64-17-5 1,900 mg/m3 1,000 ppm - OSHA TWA Ethyl alcohol 64-17-5 - 1,000 ppm - ACGIH STEL Personal protective equipment Respiratory protection : Do not spray in enclosed areas. Hand protection : No special requirements. Page 162 of 262 Page 162 of 262 Page 162 of 262 Page 162 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 5/12 Eye protection : Safety glasses with side-shields Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : liquid Color : clear Odor : pleasant Odour Threshold : No data available pH : 6.98 at (20 Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Flash point : 84 °F Method: Tag Closed Cup (TCC) Evaporation rate : No data available Flammability (solid, gas) : Sustains combustion Upper/lower flammability or explosive limits : No data available Page 163 of 262 Page 163 of 262 Page 163 of 262 Page 163 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 6/12 Vapour pressure : No data available Vapour density : No data available Relative density : 0.93 g/cm3 at 20 °C Solubility(ies) : partly miscible Partition coefficient: n- octanol/water : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity, dynamic : No data available Viscosity, kinematic : Not applicable Oxidizing properties : No data available Volatile Organic Compounds Total VOC (wt. : 34.7 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations Other information : None identified : 10. STABILITY AND REACTIVITY Possibility of hazardous reactions : If accidental mixing occurs and toxic gas is formed, exit area immediately. Do not return until well ventilated. Conditions to avoid : Heat, flames and sparks. Page 164 of 262 Page 164 of 262 Page 164 of 262 Page 164 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 7/12 Incompatible materials : Strong oxidizing agents Do not mix with bleach or any other household cleaners. Strong bases Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. 11. TOXICOLOGICAL INFORMATION Emergency Overview : Warning Acute oral toxicity : LD50 4,103 mg/kg GHS Properties Classification Routes of entry Acute toxicity No classification proposed - Skin corrosion/irritation No classification proposed - Eye irritation Category 2A - Skin sensitisation No classification proposed - Respiratory sensitisation No classification proposed - Germ cell mutagenicity No classification proposed - Carcinogenicity No classification proposed - Reproductive toxicity No classification proposed - Specific target organ toxicity - single exposure No classification proposed - Specific target organ toxicity - repeated exposure No classification proposed - Aspiration hazard No classification proposed - Page 165 of 262 Page 165 of 262 Page 165 of 262 Page 165 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 8/12 Acute inhalation toxicity : GHS LC50 (dust and mist) > 2.07 mg/l Acute dermal toxicity : LD50 > 5,000 mg/kg Aggravated Medical Condition : Do not apply to cuts or irritated skin. 12. ECOLOGICAL INFORMATION Product : The product itself has not been tested. Toxicity The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions. Toxicity to fish Ethyl alcohol flow- through test LC50 Pimephales promelas (fathead minnow) 14,200 mg/l 96 h N,N-Diethyl-m-toluamide static test LC50 mykiss (rainbow trout) 71.25 mg/l 96 h Toxicity to aquatic invertebrates Ethyl alcohol static test EC50 Daphnia magna (Water flea) 2 mg/l 48 h Components End point Species Value Exposure time Components End point Species Value Exposure time Page 166 of 262 Page 166 of 262 Page 166 of 262 Page 166 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 9/12 NOEC Daphnia magna 9.6 mg/l 9 d N,N-Diethyl-m-toluamide No data available Toxicity to aquatic plants Ethyl alcohol Static EC50 Chlorella vulgaris (Fresh water algae) 275 mg/l 72 h N,N-Diethyl-m-toluamide No data available Persistence and degradability Component Biodegradation Exposure time Summary Ethyl alcohol 97 % 28 d Readily biodegradable N,N-Diethyl-m-toluamide No data available Bioaccumulative potential Component Bioconcentration factor (BCF) Partition Coefficient n- Octanol/water (log) Ethyl alcohol 3.2 estimated -0.35 Measured N,N-Diethyl-m-toluamide No data available No data available Mobility Component End point Value Ethyl alcohol No data available N,N-Diethyl-m-toluamide No data available PBT and vPvB assessment Component Results Components End point Species Value Exposure time Page 167 of 262 Page 167 of 262 Page 167 of 262 Page 167 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 10/12 Ethyl alcohol Not fulfilling PBT and vPvB criteria N,N-Diethyl-m-toluamide Not fulfilling PBT and vPvB criteria Other adverse effects : None known. 13. DISPOSAL CONSIDERATIONS PESTICIDAL WASTE: For disposal information, please read and follow Disposal instructions on the pesticide label. Consumer may discard empty container in trash, or recycle where facilities exist. 14. TRANSPORT INFORMATION Please refer to the Bill of Lading/receiving documents for up-to-date shipping information. Land transport Sea transport Air transport UN number 1993 1993 1993 UN proper shipping name UN 1993 Flammable liquid, N.O.S. (Ethyl alcohol) UN 1993 Flammable liquid, N.O.S. (Ethyl alcohol) UN 1993 Flammable liquid, N.O.S. (Ethyl alcohol) Transport hazard class(es) 3 3 3 Packing group III III III Environmental hazards - - - Special precautions for user Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. 15. REGULATORY INFORMATION Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Page 168 of 262 Page 168 of 262 Page 168 of 262 Page 168 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 11/12 Chemical Substance Inventory. California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65. Registration # / Agency 4822-399/US/EPA 16. OTHER INFORMATION HMIS Ratings Health 2 Flammability 3 Reactivity 0 NFPA Ratings Health 2 Fire 3 Reactivity 0 Special - This information is being provided in accordance with the Occupational Safety and Health Administration (OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use. Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Page 169 of 262 Page 169 of 262 Page 169 of 262 Page 169 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000022042 12/12 Prepared by SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 170 of 262 Page 170 of 262 Page 170 of 262 Page 170 of 262 ---PAGE BREAK--- There was a PDF conversion failure for - Product Name: Orange Away CAS Number: Manufacturer: Total Solutions SDS Date: 1/8/2015 To complete your binder, please link a different SDS for this product or print the SDS manually from and add to your binder. We are currently researching solutions to this issue. Thank you for your patience. Page 171 of 262 Page 171 of 262 Page 171 of 262 Page 171 of 262 ---PAGE BREAK--- PARTS MASTER PREMIUM POWER STEERING FLUID Revision Date:18-Jan-2012 Page 1 of 6 Material Safety Data Sheet NFPA HMIS Health Hazard 0 Fire Hazard 1 Reactivity 0 Issuing Date 19-July-2010 Revision Date 18-Jan-2012 Revision Number 2 1. PRODUCT AND COMPANY IDENTIFICATION Product Name PARTS MASTER PREMIUM POWER STEERING FLUID Product Code F-79 Recommended Use Manufactured by: Omni Specialty Packaging 10399 S. Hwy 1 Shreveport, LA 71115 Phone: 1 (318) 524-1100 Emergency Telephone Number CHEMTREC 1 (800) 424-9300 2. HAZARDS IDENTIFICATION Emergency Overview Appearance Clear Liquid Physical State Liquid Odor Mild petroleum odor Potential Health Effects Principal Routes of Exposure Eye contact, Skin contact, Inhalation, Ingestion Acute Toxicity Eyes Eye contact may result in slight irritation and redness.. Skin Minimally irritating upon direct contact. Inhalation Inhalation of oil mist or fumes can cause irritation of the nose, throat and upper respiratory tract Ingestion Do not ingest. May cause nausea, vomiting/diarrhea. Chronic Effects Prolonged exposure may cause chronic effects. 1 0 0 Page 172 of 262 Page 172 of 262 Page 172 of 262 Page 172 of 262 ---PAGE BREAK--- PARTS MASTER PREMIUM POWER STEERING FLUID Revision Date:18-Jan-2012 Page 2 of 6 Aggravated Medical Conditions Personnel with pre-existing skin disorders should avoid contact with this product. Environmental Hazard See Section 12 for additional Ecological Information. 3. COMPOSITION/INFORMATION ON INGREDIENTS Formula Mixture Chemical Name CAS-No Weight % Solvent-Dewaxed Heavy Paraffinic Distillates (Petroleum) 64742-65-0 85-100 Viscosity Index Improver Lubricant Mixture 5-15 Additive Package N/A 0-10 4. FIRST AID MEASURES Eye Contact Flush with large amounts of water for 15 minutes. Get medical attention if eye irritation develops or persists. If material is hot, treat for thermal burns and take victim to the hospital immediately. Skin Contact Wash off immediately with soap and plenty of water for at least 15 minutes while removing all contaminated clothing and shoes. Get medical attention immediately if skin discoloration occurs. Inhalation If affected, remove individual to fresh air. If not breathing, give mouth-to-mouth resuscitation. Get medical attention if develop or persist. Ingestion CALL PHYSICIAN IMMEDIATELY. Never give anything by mouth to an unconscious person. Don’t induce vomiting except at the instructions of the physician. Notes to Physician Treat 5. FIRE-FIGHTING MEASURES Flammable Properties Not flammable. Flash Point 380°F Suitable Extinguishing Media Water Fog. Carbon dioxide (CO2). Foam. Dry chemical. Unsuitable Extinguishing Media Water stream may spread fire. Hazardous Combustion Products Decomposition and combustion products may include smoke, carbon dioxide, carbon monoxide, and other low molecular weight hydrocarbons. Explosion Data Sensitivity to Mechanical Impact Not sensitive. Sensitivity to Static Discharge Not sensitive. Protective Equipment and Precautions for Firefighters Wear positive pressure self-contained breathing apparatus (SCBA). Use water to cool containers exposed to flames. Structural firefighters’ protective clothing will only provide limited protection. Mist or sprays may be flammable below the product normal flash point. NFPA Health Hazard 0 Flammability 1 Reactivity 0 Physical and Chemical Hazards - Page 173 of 262 Page 173 of 262 Page 173 of 262 Page 173 of 262 ---PAGE BREAK--- PARTS MASTER PREMIUM POWER STEERING FLUID Revision Date:18-Jan-2012 Page 3 of 6 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Use personal protective equipment. Avoid contact with skin, eyes, and clothing. Ensure adequate ventilation. Methods for Containment Dike far ahead of liquid spill for later disposal. Methods for Cleaning Up Pick up free liquid for recycle and/or disposal. Residual liquid and/or solid can be absorbed on inert material. Evacuation Procedures Large Spill Consider initial downwind evacuate for at least 300 meters (1000 feet). Fire If tank, rail car or tank car is involved in a fire, isolate for 800 meters (1/2 mile) in all directions; also consider initial evacuation for 800 meters (1/2 mile) in all directions. Reporting Requirements Spills that enter a water body must be reported immediately to the USEPA’s National Response Center at (800)424-8802. Check with your local and state regulators regarding their reporting requirements. 7. HANDLING AND STORAGE Handling Do not pressure, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition; they may explode. See NFPA 30 and OSHA 1910.106 – flammable and combustible liquids. Storage Store away from heat, sparks, open flame, or strong oxidizing agents in closed and properly labeled containers. Empty containers retain product residue (liquid, and/or vapor) and can be dangerous 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Solvent-Dewaxed Heavy Paraffinic Distillates (Petroleum) 64742-65-0 5 mg/m³ mist 5 mg/m³ mist None listed Viscosity Index improver Lubricant 5 mg/m³ mist 5 mg/m³ mist None listed Engineering Measures Additional area ventilation or local exhaust may be required to maintain air concentrations below recommended limits. Personal Protective Equipment Eye/Face Protection Safety glasses or face shield where splashing is possible. Full face-shield to be worn during emergencies. Skin and Body Protection As needed to prevent repeated skin contact. Solvent resistant gloves should be used if needed. Respiratory Protection Not normally needed. During emergencies wear respirator. Hygiene Measures Remove and wash contaminated clothing before re-use. Wash hands before breaks and immediately after handling the product. Page 174 of 262 Page 174 of 262 Page 174 of 262 Page 174 of 262 ---PAGE BREAK--- PARTS MASTER PREMIUM POWER STEERING FLUID Revision Date:18-Jan-2012 Page 4 of 6 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Clear Liquid Odor Mild petroleum odor Physical State Liquid pH N/A Flash Point 380°F Autoignition Temperature 600°F Boiling Point/Range >500°F Freezing Point <-40°C Explosion Limits N/A Flammability Limits in Air N/A Specific Gravity 0.85 Solubility Negligible Evaporation Rate N/A Vapor Pressure N/A Vapor Density Not Determine Density N/A 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions. Incompatible Products Open Flame and strong oxidizing agents. Conditions to Avoid Heat, flames, and sparks. Hazardous Decomposition Products Decomposition and combustion products may include hydrogen sulfide, alkyl mercaptans, sulfides, oxides or sulfur, oxides of : phosphorous, calcium and zinc; aldehydes, carbon monoxide and carbon dioxide. Hazardous Polymerization None under normal processing. 11. TOXICOLOGICAL INFORMATION Acute Toxicity Product Information Test on similar materials show a low order of acute oral and dermal toxicity. Acute Oral Effects Test on similar materials indicates low order of acute toxicity. Acute Inhalation Effects Low acute toxicity expected on inhalation. Skin Effects Practically non-toxic if absorbed. Other similar highly refined products have not shown skin tumors in mouse skin painting studies. Eye Irritation Minimal irritation on contact. Eye irritation or practically non-irritating base on similar products. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Solvent-Dewaxed Heavy Paraffinic Distillates (Petroleum) 64742-65-0 Rat >2000 mg/kg Rabbit >2000 mg/kg Rat > 2.18 mg/L 4 hours Chronic Toxicity Chronic Toxicity Prolonged exposure may cause chronic effects. Carcinogenicity Not considered a potential carcinogen base on IP346 DMSO of less than 3.0 wt% Target Organ Effects Respiratory system, Eyes, Skin, Genotoxicity This product is considered non-mutagenic and has negative potential for tumor development based on from Modified Ames Assay, with Mutagenic Index of less than 1.0. Page 175 of 262 Page 175 of 262 Page 175 of 262 Page 175 of 262 ---PAGE BREAK--- PARTS MASTER PREMIUM POWER STEERING FLUID Revision Date:18-Jan-2012 Page 5 of 6 12. ECOLOGICAL INFORMATION Ecotoxicity This product is not toxic to fish but may coat gill structures resulting in suffocation if spilled in shallow, running water. Product may be moderately toxic to amphibians by preventing dermal respiration. This product may cause gastrointestinal distress to birds and mammals through ingestion during pelage grooming. 13. DISPOSAL CONSIDERATIONS Waste Disposal Method Dispose of in accordance with local regulations. Keep this product out of sewers and waterways. Contaminated Packaging Dispose of in accordance with local regulations. 14. TRANSPORT INFORMATION DOT Not regulated IATA Not regulated IMDG/IMO Not regulated 15. REGULATORY INFORMATION International Inventories TSCA DSL EINECS/ELINCS ENCS IECSC KECL PICCS AICS Solvent-Dewaxed Heavy Paraffinic Distillates (Petroleum) 64742-65-0 Present X 265-169-7 X X X X X U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act If spilled into navigable waters it is reportable to National Response Center, [PHONE REDACTED]. Reportable Quantity = Oil Sheen present on navigable water surface. (40 CFR 116; 401.15) Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990. CERCLA Page 176 of 262 Page 176 of 262 Page 176 of 262 Page 176 of 262 ---PAGE BREAK--- PARTS MASTER PREMIUM POWER STEERING FLUID Revision Date:18-Jan-2012 Page 6 of 6 U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. Florida No listed ingredients are present Massachusetts RTK No listed ingredients are present Minnesota RTK No listed ingredients are present New Jersey RTK Lists petroleum oil, but this product does not contain hazardous ingredients. RTK Lists petroleum oil, but this product does not contain hazardous ingredients greater than Illinois DOL TSL No listed ingredients are present International Regulations Mexico – Grade No information available. Canada Not listed on the Canadian Controlled Product Ingredient Disclosure and is compliant with Controlled Products Regulation CONEG Metals Since cadmium, chromium, lead and mercury are not detectable and it does not exceed 100ppm total in this product, it is compliant with CONEG Metals regulation. EEC (Europe) This product is not known to be a dangerous good internationally. R-Phrases R45: May Cause Cancer S-Phrases S53: Avoid Exposure S45 Hazard Label None Danger Symbol None This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class D2B Toxic materials 16. OTHER INFORMATION Prepared By Juan Parker Issuing Date 28-June-2010 Revision Date 31-Jan-2012 Revision Note Not applicable Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of MSDS Page 177 of 262 Page 177 of 262 Page 177 of 262 Page 177 of 262 ---PAGE BREAK--- Page 178 of 262 Page 178 of 262 Page 178 of 262 Page 178 of 262 ---PAGE BREAK--- Page 179 of 262 Page 179 of 262 Page 179 of 262 Page 179 of 262 ---PAGE BREAK--- Page 180 of 262 Page 180 of 262 Page 180 of 262 Page 180 of 262 ---PAGE BREAK--- Page 181 of 262 Page 181 of 262 Page 181 of 262 Page 181 of 262 ---PAGE BREAK--- Page 182 of 262 Page 182 of 262 Page 182 of 262 Page 182 of 262 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 1 Initial Preparation Date: 7/19/1999 Last Revision Date: 10/23/2014 Effective Date: 10/29/2014 MATERIAL SAFETY DATA SHEET PRODUCT IDENTITY: POLAR WINDSHIELD WASH & DEICER FLUID -30F 1. CHEMICAL PRODUCT & COMPANY INFORMATION OLD WORLD INDUSTRIES, LLC 4065 COMMERCIAL AVENUE ILLINOIS 60062 PHONE: [PHONE REDACTED] EMERGENCY PHONE: 1-[PHONE REDACTED] (CHEMTREC) 2. COMPOSITION / INFORMATION ON INGREDIENTS 8-Hour Time Weighted Vapor Pressure Material CAS# % by Wt. Avg. (TWA) mm Hg @ Temp Methanol 67-56-1 35 200 ppm (260 Mg/M3) 96.1 20 C Propylene Glycol 57-55-6 <5 Not established 0.8 20 C Additives N/A <1 N/A N/A 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Slight odor. May be fatal if swallowed. Vapors can cause eye irritation. LD50 Rat (Oral): 5,628 mg/kg (Methanol) LD50 Rabbit (Skin): 20 g/kg (Methanol) Carcinogency: No National Toxicology Program: No International Agency for Research on Cancer: No OSHA Regulated: Yes HAZARD RATING SYSTEM HMIS: HEALTH: 2 FLAMMABILITY: 2 REACTIVITY: 0 PERSONAL PROTECTION: A KEY: 0 - Minimal 1 - Slight 2 - Moderate 3 - Serious 4 - Severe A - Safety glasses POTENTIAL HEALTH EFFECTS Health Hazards (Acute and Chronic): Acute: Acute methanol intoxication is manifested initially by signs of narcosis. This is followed by a latent period Page 183 of 262 Page 183 of 262 Page 183 of 262 Page 183 of 262 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 2 in which formic acid accumulates in the body causing metabolic acidosis. Severe abdominal, leg, and back pain occur and visual degeneration can lead to blindness. 1. Humans – Ingestion of 80 to 150 mL of methanol is usually fatal to humans (HSDB 1994). One worker died from exposure to vapor ranging from 4,000 to 13,000 ppm over 12 hours (ACGIH 1991). The concentration of 4,000 ppm is roughly equivalent to a total of 1,140 mg/kg over the 12-hour period (see end note Poisoning by nonlethal doses can be described in three stages: narcotic stage similar to ethanol; latent period of 10-15 hours; visual disturbances and central nervous system lesions (Rowe and McCollister 1981). Visual disturbances can lead to blindness due to edema of the retina and atrophy of the optic nerve head (HSDB 1994). Third-stage CNS lesions include headache, dizziness, abdominal, back, and leg pain, delirium that can lead to coma, and nausea (HSDB 1994). Formic acid production causes severe metabolic acidosis (Rowe and McCollister 1981). 2. Animals – Oral LD50 values for methanol is animals are 0.4 g/kg in the mouse, 6.2 to 13 g/kg in the rat, 14.4 g/kg in the rabbit, and 2 to 7 g/kg in the monkey (Rowe and McCollister 1981). The LD50 for dermal application to rabbits is 20 mL/kg (approximately 16 g/kg) (Rowe and McCollister 1981). Dose-response data for inhalation vary with species, dose, and duration (8,800 ppm for 8 hours to 152,800 ppm for 94 minutes). of intoxication include incoordination, salivation, lethargy, narcosis, and death (Rowe and McCollister 1981). Sub-chronic/Chronic: Chronic exposure to methanol, either orally or by inhalation, causes headache, insomnia, gastrointestinal problems, and blindness in humans and hepatic and brain alterations in animals. EPA has derived an oral RfD (reference dose) (see end note 3) for methanol of 0.5 mg/kg/day, based on the absence of liver and brain effects in animals exposed by mouth to 500 mg/kg/day. 1. Humans – “Chronic” exposure to methanol vapors (no time or dose given) caused conjunctivitis, headache, giddiness, insomnia, gastric disturbances, and bilateral blindness (ACGIH 1991). Marked vision loss occurred in one worker exposed to 1,200 to 8,000 ppm vapor for 4 years (ACGIH 1991). 2. Animals – No effects were seen in rats given 1% (approximately 140 mg/kg/day) methanol in drinking water for 6 months (Rowe and McCollister 1981). Hepatic abnormalities (proteinic degeneration, altered RNA metabolism) occurred in rhesus monkeys given 3 to 6 g/kg for 3 to 20 weeks and in rats given 10, 100, or 500 mg/kg/day for one month (Rowe and McCollister 1981). Rabbits chronically fed methanol (no dose or time given) had increasing blood levels, brain and eye edema, and myelin thinning (HSDB 1994). Male and female rats were gavaged with 100, 500, or 2,500 mg/kg/day for 90 days (U.S. EPA 1994). Increased levels of SGPT and SAP as well as decreased brain weights were seen in both sexes at the highest dose; a no-observed-adverse effect level (NOAEL) for the study was 500 mg/kg/day. Based on these data, the U.S. EPA (1994) calculated a chronic RfD (see end note 4) for methanol of 0.5 mg/kg/day. No toxic effects were seen in dogs exposed by inhalation to either 10,000 ppm for 3 minutes, 3x/day, for 100 days or to 450 or 500 ppm, 8 hours/day for 379 days (Rowe and McCollister 1981). Ultrastructural changes were observed in the photoreceptor cells of rabbits exposed to 46.6 ppm for 6 months (Rowe and McCollister 1981). Rowe and McCollister (1981) concluded that the effects of combined oral and inhalation exposure appear to be additive. Rats exposed by inhalation to 16.8 ppm, 4 hours/day, for 6 months and administered 0.7 mg/kg/day orally had changes in blood morphology, oxidation-reduction processes, and liver function (Rowe and McCollister 1981). Carcinogenicity: No information was found on the carcinogenicity of methanol in the secondary sources searched. 1. Humans – No information was found in the secondary sources searched concerning the carcinogenicity of methanol to humans. 2. Animals – No information was found in the secondary sources searched concerning the carcinogenicity of methanol to animals. The NTP has assigned a project leader for methanol and the design of the study is in progress (NTP 1994). Page 184 of 262 Page 184 of 262 Page 184 of 262 Page 184 of 262 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 3 4. FIRST AID MEASURES Ensure physician has access to this MSDS. Routes of Entry: Inhalation, Skin, Ingestion Signs and of Exposure: Eye Contact: May cause eye irritation. Skin Contact: Frequent or prolonged contact may cause skin irritation experienced as burning, drying, cracking and redness. Inhalation: May cause nose and throat irritation. High concentrations may cause acute central nervous system depression characterized by headaches, dizziness, nausea and confusion. Skin Absorption Health Risks and of Exposure: Harmful quantities of Methyl Alcohol may affect eyes and central nervous system. Ingestion Health Risks and of Exposure: May cause nausea, abdominal pain, headache, shortness of breath, visual impairment and blindness. Severe poisoning can cause coma and death. Medical Conditions Generally Aggravated by Exposure: Ingestion of large amounts of Methyl Alcohol has been shown to damage organs including liver, kidney, pancreas, heart, lungs and brain. Although this rarely occurs, survivors of severe intoxication may suffer permanent neurological damage. Overexposure may aggravate pre-existing disorders of the eyes. People have died as a result of drinking large amounts of methanol. Drinking smaller, non-lethal amounts of methanol adversely affects the human nervous system. Effects range from headaches to incoordination similar to that associated with drunkenness. Delayed effects such as severe abdominal, leg, and back pain can follow the inebriation effects of methanol. Loss of vision and even blindness can also occur after exposure to amounts of methanol causing inebriation. These effects are not likely to occur at levels of methanol that are normally found in the environment. Human health effects associated with breathing or otherwise consuming smaller amounts of methanol over long periods of time are not known. Workers repeatedly exposed to methanol have experienced several adverse effects. Effects range from headaches to sleep disorders and gastrointestinal problems to optic nerve damage. Laboratory studies show that repeat exposure to large amounts of methanol in air or in drinking water cause similar adverse effects in animals. TREATMENT Eyes: Flush with large quantities of water for 15 minutes and seek medical attention. Skin: Remove contaminated clothing and wash contaminated skin with large amounts of soap and water. If irritation persists, get medical attention. Launder clothing before reuse. Inhalation: Remove to fresh air. If breathing has stopped, apply artificial respiration. If breathing is difficult, give oxygen provided a qualified operator is available. Get medical attention. Ingestion: If swallowed, Do Not induce vomiting. Drink a large amount of water, milk or sodium bicarbonate to dilute material in stomach. (Never give anything by mouth to an unconscious person.) Call Poison Control Center, hospital emergency room or physician immediately. Page 185 of 262 Page 185 of 262 Page 185 of 262 Page 185 of 262 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 4 Notes to Physician: This product contains methanol which can cause intoxication and central nervous system depression. Methanol is metabolized to formic acid and formaldehyde. These metabolites can cause metabolic acidosis, visual disturbances and blindness. Since metabolism is required for these toxic their onset may be delayed from 6 to 30 hours following ingestion. Ethanol competes for the same metabolic pathway and has been used to prevent methanol metabolism. Ethanol administration is indicated in patients or at blood hemodialysis. Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material: skin, lung (for example, asthma-like conditions), liver, kidney, central nervous system, pancreas, heart). Exposure to this material may aggravate any preexisting condition sensitive to a decrease in available oxygen, such as chronic lung disease, coronary artery disease or anemias. 5. FIRE FIGHTING MEASURES FIRE & EXPLOSION HAZARD DATA Flammable Properties: Flash Point: 86 F Method Used: ETA 1010 CC Flammability Limits: Percentage of vapor concentration at which methanol can ignite in presence of spark: LEL: 6.0% UEL: 36.0% Hazardous Combustion Products: Methanol Extinguishing Media: Foam, dry chemical, carbon dioxide or any Class B extinguishing agent. Water may be unsuitable as an extinguishing medium but helpful in keeping adjacent containers cool Fire Fighting Instructions: Use water spray to cool fire exposed containers. Water may be ineffective but may be used to cool exposed containers to prevent pressure buildup and possible auto-ignition or explosion when exposed to extreme heat. If water is used, fog nozzles are preferable. Unusual Fire and Explosion Hazards: Handle as flammable liquid. Vapors are heavier than air and may travel along the ground or may be moved by ventilation. Vapors form an explosive mixture in air between the upper and lower explosive limits which can be ignited by many sources, such as pilot lights, open flames, electrical motors and switches. Protective Equipment For Fire Fighters: Wear NIOSH approved self-contained breathing apparatus with full face piece and protective clothing to prevent contact with skin and eyes. 6. ACCIDENTAL RELEASE MEASURES Small Spill: Absorb liquid on vermiculite, floor absorbent or other absorbent material. Large Spill: Eliminate all ignition sources (flares, flames including pilot lights, electrical sparks). Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source. Prevent from entering drains, sewers, streams or other bodies of water. Prevent from spreading. If runoff occurs, notify authorities as required. Pump or vacuum transfer spilled product to clean containers for recovery. Absorb unrecoverable product. Transfer contaminated absorbent, soil and other materials to containers for disposal. Prevent run-off to sewers, streams or other bodies of water. If run-off occurs, notify proper authorities as required, that a spill has occurred. Page 186 of 262 Page 186 of 262 Page 186 of 262 Page 186 of 262 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 5 7. HANDLING AND STORAGE Do not swallow. Store in closed containers in a cool, dry, well-ventilated area. Keep away from sparks and open flame. Respiratory Protection: Use approved NIOSH respirator when TLV is exceeded. Ventilation: Provide sufficient ventilation to maintain exposure below TLV. Protective Gloves: Wear appropriate impermeable gloves. Eye Protection: Use chemical safety glasses, goggles and face shields for eye protection. Other Protective Clothing or Equipment: Long sleeves and apron are recommended. Work / Hygienic Practices: Avoid prolonged or repeated skin contact. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Eye Protection: Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Consult your safety representative. Skin Protection: Wear resistant gloves (consult your safety equipment supplier). To prevent repeated or prolonged skin contact, wear impervious clothing and boots. Respiratory Protection: If workplace exposure limit(s) of product or any component is exceeded (see exposure guidelines), a NIOSH/MSHA approved air supplied respiratory is advised in absence of proper environmental control. OSHA regulations also permit other NIOSH/MSHA respirators (negative pressure type) under specified conditions (see your industrial hygienist). Engineering or administrative controls should be implemented to reduce exposure. Engineering Controls: Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below TLV(s). Exposure Guidelines: Component: Methyl Alcohol (67-56-1) OSHA VPEL 200.000 ppm – TWA (skin) OSHA VPEL 250.000 ppm – STEL (skin) ACGIH TLV 200.000 ppm – TWA (skin) ACGIH TLV 250.000 ppm – STEL (skin) 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Range: 166 F - 194 F Specific Gravity (Water .94 @ 20 C Vapor Density (Air=1): Heavier than air Water Solubility: Soluble Appearance: Clear purple liquid Odor: Mild alcohol odor Evaporation Rate: Greater than n-butyl acetate Page 187 of 262 Page 187 of 262 Page 187 of 262 Page 187 of 262 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 6 10. STABILITY & REACTIVITY DATA Stability: Stable Conditions to Avoid: Ignition sources, such as heat, sparks and flames Incompatibility (Materials to Avoid): Strong acids and strong oxidizing agents Hazardous Decomposition Products: Burning can produce carbon monoxide and/or carbon dioxide. Carbon monoxide is highly toxic if inhaled; carbon dioxide in sufficient concentrations an act as an Hazardous Polymerization: Will not occur 11. TOXICOLOGICAL INFORMATION Mutagenicity (The Effects On Genetic Material): Genotoxicity: Methanol was negative for cell transformation in Syrian hamster embryo cells (clonal assay and viral enhanced), sister chromatid exchange in vitro, and for aneuploidy and chromosome aberrations in Neurospora crassa (GENETOX 1992). The micronucleus test and the assay for chromosome aberrations in mammalian were inconclusive (GENETOX 1992). Developmental/Reproductive Toxicity: No information was found on the developmental toxicity of methanol in humans. Methanol can cause adverse effects in the developing in rats at doses that cause overt maternal intoxication. 1. Humans – No information was found in the secondary sources searched regarding the developmental or reproductive toxicity of methanol to humans. However, one of the breakdown products of the artificial sweetener aspartame is methanol. Increased blood methanol levels did not lead to increased formic acid levels in women receiving up to 200 mg/kg aspartame (no other details reported) and no evidence of fetal risk was detected (HSDB 1994). 2. Animals – Rats were exposed by inhalation, 7 hours/day, to 5,000 or 10,000 ppm methanol on gestation days 1-19 or to 20,000 ppm on days 7-15. Maternal intoxication (unsteadiness) occurred at the highest dose and coincided with extra or rudimentary ribs and urinary or cardiovascular defects in the fetuses (ACGIH 1991). Male rats had significantly lowered testosterone levels after inhalation exposure to 200 ppm methanol for 6 weeks; at 10,000 ppm a change in luteinizing hormone was also observed (HSDB 1994). Neurotoxicity: Methanol causes central nervous system depression in humans and animals as well as degenerative changes in the brain and visual system. 1. Humans – Methanol causes narcosis similar to ethanol intoxication and nonlethal doses can lead to blindness. Autopsy of individuals after lethal doses revealed edema and hyperemia of the brain and degeneration of the ganglion cells of the retina (Rowe and McCollister 1981). 2. Animals – Acute methanol intoxication in animals causes CNS depression as observed by narcosis, incoordination, lethargy, drowsiness, and prostration (Rowe and McCollister 1981). Page 188 of 262 Page 188 of 262 Page 188 of 262 Page 188 of 262 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 7 Significant Data With Possible Relevance To Humans: Pharmacokinetics: 1. Absorption – Methanol is readily absorbed after oral, inhalation, or dermal exposure. Oral doses in humans of 71 to 84 mg/kg resulted in blood levels of 4.7 to 7.6 mg/100 mL of blood within 3 hours (Rowe and McCollister 1981). Inhalation of 500 to 1,000 ppm methanol for 3 to 4 hours gave urine concentrations of 1 to 3 mg methanol/100 mL of urine at the end of exposure (Rowe and McCollister 1981). Based on urinary methanol levels, the rate of absorption of the chemical appears to be proportional to the concentration of vapor inhaled (HSDB 1994). The rate of dermal absorption increased for 35 minutes then decreased over the next 25 minutes (no other details given) (HSDB 1994). 2. Distribution – Methanol distributes rapidly in dogs exposed to 4,000 to 15,000 ppm for 12 hours to 5 days; the highest concentrations of the chemical were found in blood, eye fluid, bile, and urine (HSDB 1994). 3. Metabolism – Methanol is oxidized in the human liver by the enzyme alcohol dehydrogenase (Rowe and McCollister 1981). Metabolic products include formaldehyde and formic acid (HSDB 1994). The rate of metabolism for methanol (25 mg/kg/hr) is much slower than for ethanol (175 mg/kg/hr) and is independent of concentrations in the blood (HSDB 1994). Formic acid is responsible for the toxic effects of methanol (ACGIH 1991). 4. Excretion – Methanol is excreted either as parent compound in the urine or expired air, or as the formic acid metabolite in urine (Rowe and McCollister 1981; HSDB 1994). The amount of formic acid excreted varies greatly with species from 1% in rabbits to 20% in dogs; humans are intermediate (HSDB 1994). In humans, the half-life of methanol elimination in expired air after oral or dermal exposure is 1.5 hours (HSDB 1994). 12. ECOLOGICAL INFORMATION ENVIRONMENTAL FATE Methanol evaporates when exposed to air. It dissolves completely when mixed with water. Most direct releases of methanol to the environment are to air. Methanol also evaporates from water and soil exposed to air. Once in air, it breaks down to other chemicals. Microorganisms that live in water and in soil can also break down methanol. Because it is a liquid that does not bind well to soil, methanol that makes it way into the ground can move through the ground and enter groundwater. Plants and animals are not likely to store methanol. Methanol by itself is not likely to cause environmental harm at levels normally found in the environment. Methanol can contribute to the formation of photochemical smog when it reacts with other volatile organic carbon substances in air. Movement & Partitioning: The miscibility of methanol in water and a low KOC indicate that the chemical will be highly mobile in soil (HSDB 1994). Volatilization half-lives from a model river and an environmental pond were estimated at 4.8 days and 51.7 days, respectively (HSDB 1994). Methanol can be removed from the atmosphere in rain water (HSDB 1994). Degradation & Transformation: 1. Air – Once in the atmosphere, methanol exists in the vapor phase with a half life of 17.8 days (HSDB 1994). The chemical reacts with photochemically produced hydroxyl radicals to produce formaldehyde (HSDB 1994). Methanol can also react with nitrogen dioxide in polluted air to form methyl nitrite (HSDB 1994). 2. Soil – Biodegradation is the major route of removal of methanol from soils. Several species of Page 189 of 262 Page 189 of 262 Page 189 of 262 Page 189 of 262 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 8 Methylobacterium and Methylomonas isolated from soils are capable of utilizing methanol as a sole carbon source (CHEMFATE 1994). 3. Water – Most methanol is removed from water by biodegradation. The degradation products of methane and carbon dioxide were detected from aqueous cultures of mixed bacteria isolated from sewage sludge (CHEMFATE 1994). Aerobic, Gram-negative bacteria (65 strains) isolated from seawater, sand, mud, and weeks of marine origin utilized methanol as a sole carbon source (CHEMFATE 1994). Aquatic hydrolysis, oxidation, and photolysis are not significant fate processes for methanol (HSDB 1994). 4. Biota – Bioaccumulation of methanol in aquatic organisms is not expected to be significant based on an estimated bioconcentration factor of 0.2 (HSDB 1994). Ecotoxicology: 1. Toxicity to Aquatic Organisms – Methanol has low acute toxicity to aquatic organisms; lethal concentrations are much greater than 100 mg/L. Ninety-six hour LC50 values for fish are 28,100 mg/L for Pimephales promelas (fathead minnow), 20,100 mg/L for mykiss (rainbow trout), and >28,000 mg/L for Alburnus alburnus (bleak) (AQUIRE 1994). Forty-eight hour LC50 values for Cyprinus carpio (common carp) and Carassius auratus (goldfish) are 28,000 mg/L and 1,700 mg/L, respectively (AWQUIRE 1994). Growth inhibition occurred for 4 strains of Anabaena (blue-green algae) over a range of EC50s of 2.57%-3.13% for 10-14 days (AQUIRE 1994). The LC50 for Artemia salina (brine shrimp) is >10,000 mg/L in 24 hours and that for Culex restuans (mosquito) is 20,000 mg/L in 18 hours (AQUIRE 1994). 2. Toxicity to Terrestrial Organisms – No information was found in the secondary sources searched regarding the toxicity of methanol to terrestrial organisms. However, based on the range of oral LD50s, 0.4 to 14.2 g/kg, for monkeys, rats, mice, and rabbits (Rowe and McCollister 1981), it is unlikely that methanol would be toxic to terrestrial animals at environmental levels. 3. Abiotic Effects – Methanol reacts with nitrogen dioxide in polluted atmospheres to produce methyl nitrite (HSDB 1994). According to the definition provided in the Federal Register (1992), methanol is a volatile organic compound (VOC) substance. As a VOC, methanol can contribute to the formation of photochemical smog in the presence of other VOCs. 13. DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION U. S. Department of Transportation: In Inner Packaging No More Than 5.0 L: Proper Shipping Name: Consumer Commodity ORM-D Per 49 CFR Part 173.10 (PG III, inner packaging no more than 5.0L) In Packaging Over 5.0 L: Proper Shipping Name: Flammable Liquid, n.o.s. (Methanol) ID UN 1993 Class: 3 Hazard Label: Flammable Liquid PG: III Page 190 of 262 Page 190 of 262 Page 190 of 262 Page 190 of 262 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 9 International Air Dangerous Good Regulations (IATA): Proper Shipping Name: Flammable Liquid, n.o.s. (Methanol) ID UN 1993 Class: 3 Hazard Label: Flammable Liquid PG: III Ltd. Qty. Packaging Instruction: Y309 (Max qty. per package 10L) Special Provision: A3 International Maritime Dangerous Goods (IMDG): Proper Shipping Name: Limited Quantities of Class 3 (This must be notated on Shipper's Declaration). 15. REGULATORY INFORMATION THIS PRODUCT CONTAINS COMPONENT(S) CITED ON THE FOLLOWING REGULATIONS: CHEMICAL NAME CAS NUMBER Methanol 67-56-1 U.S. Federal Regulations TSCA (Toxic Substances Control Act) Status – TSCA (UNITED STATES) The intentional ingredients of this product are listed. CERCLA RQ – 40 CFR 302.4(a) Component RQ (lbs) Methyl Alcohol 5,000 SARA 302 Components – 40 CFR 355 Appendix A None Section 311/312 Hazard Class – 40 CFR 370.2 Immediate Delayed Fire Reactive ( ) Sudden Release of Pressure ( ) SARA 313 Components – 40 CFR 372.65 Section 313 Component(s) CAS Number % Methanol 67-56-1 35 International Regulations Inventory Status – DSL (CANADA) The intentional ingredients of this product are listed. WHMIS Information: B2, D1A ECL (SOUTH KOREA) The intentional ingredients of this product are listed. EINECS (EUROPE) The intentional ingredients of this product are listed. ENCS (JAPAN) The intentional ingredients of this product are listed. Page 191 of 262 Page 191 of 262 Page 191 of 262 Page 191 of 262 ---PAGE BREAK--- Polar Windshield Wash & Deicer Fluid -30F 10 State and Local Regulations California Proposition 65: Methanol is on the California Proposition 65 list as a reproductive toxicant. New Jersey RTK (Right-to-Know) Label Information: Methyl Alcohol (67-56-1) RTK (Right-to-Know) Label Information: Methanol (67-56-1) Atmospheric Standards: The Clean Air Act Amendments of 1990 list methanol as a hazardous air pollutant. 16. OTHER INFORMATION Contact: Tom Cholke Phone: (847) 559-2225 Old World Industries, LLC makes no warranty, representation or guarantee as to the accuracy, sufficiency or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity and suitability of his own use, handling and disposal of this product. Since actual use by others is beyond our control, no warranty, expressed or implied, is made by Old World Industries, LLC as to the effects of such use, the results to be obtained or the safety and toxicity of this product, nor does Old World Industries, LLC assume liability arising out of the use by others of this product referred to herein. The data in this MSDS relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Page 192 of 262 Page 192 of 262 Page 192 of 262 Page 192 of 262 ---PAGE BREAK--- SAFETY DATA SHEET PRIME SOURCE® SILKY PINK HAND SOAP Version 1.4 Revision Date: 04/27/2015 MSDS Number: 31606-00005 Date of last issue: 03/19/2015 Date of first issue: 11/24/2014 1 / 12 SECTION 1. IDENTIFICATION Product name : PRIME SOURCE® SILKY PINK HAND SOAP Product code : 75004224 Manufacturer or supplier's details Company name of supplier : PRIME SOURCE, LLC Address : One City Place Drive, Suite 200 St. Louis MO 63141 Telephone : [PHONE REDACTED] Emergency telephone : [PHONE REDACTED] Recommended use of the chemical and restrictions on use Recommended use : Skin-care Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Not a hazardous substance or mixture. GHS Label element Not a hazardous substance or mixture. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous ingredients Page 193 of 262 Page 193 of 262 Page 193 of 262 Page 193 of 262 ---PAGE BREAK--- SAFETY DATA SHEET PRIME SOURCE® SILKY PINK HAND SOAP Version 1.4 Revision Date: 04/27/2015 MSDS Number: 31606-00005 Date of last issue: 03/19/2015 Date of first issue: 11/24/2014 2 / 12 Chemical Name CAS-No. Concentration Alcohols, C10-16, ethoxylated, sulfates, sodium salts 68585-34-2 1 - < 5 Cocoamidopropyl betaine 61789-40-0 1 - < 5 SECTION 4. FIRST AID MEASURES If inhaled : If inhaled, remove to fresh air. Get medical attention if occur. In case of skin contact : Wash with water and soap as a precaution. Get medical attention if occur. In case of eye contact : Flush eyes with water as a precaution. Get medical attention if irritation develops and persists. If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if occur. Rinse mouth thoroughly with water. Most important and effects, both acute and delayed : None known. Protection of first-aiders : No special precautions are necessary for first aid responders. Notes to physician : Treat and supportively. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : None known. Specific hazards during fire fighting : Exposure to combustion products may be a hazard to health. Hazardous combustion prod- ucts : Sulfur oxides Carbon oxides Metal oxides Chlorine compounds Nitrogen oxides (NOx) Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Page 194 of 262 Page 194 of 262 Page 194 of 262 Page 194 of 262 ---PAGE BREAK--- SAFETY DATA SHEET PRIME SOURCE® SILKY PINK HAND SOAP Version 1.4 Revision Date: 04/27/2015 MSDS Number: 31606-00005 Date of last issue: 03/19/2015 Date of first issue: 11/24/2014 3 / 12 Evacuate area. Special protective equipment for fire-fighters : Wear self-contained breathing apparatus for firefighting if necessary. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Follow safe handling advice and personal protective equipment recommendations. Environmental precautions : Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for containment and cleaning up : Soak up with inert absorbent material. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements. SECTION 7. HANDLING AND STORAGE Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Local/Total ventilation : Use only with adequate ventilation. Advice on safe handling : Handle in accordance with good industrial hygiene and safety practice. Take care to prevent spills, waste and minimize release to the environment. Conditions for safe storage : Keep in properly labeled containers. Store in accordance with the particular national regulations. Materials to avoid : Do not store with the following product types: Strong oxidizing agents Page 195 of 262 Page 195 of 262 Page 195 of 262 Page 195 of 262 ---PAGE BREAK--- SAFETY DATA SHEET PRIME SOURCE® SILKY PINK HAND SOAP Version 1.4 Revision Date: 04/27/2015 MSDS Number: 31606-00005 Date of last issue: 03/19/2015 Date of first issue: 11/24/2014 4 / 12 SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Contains no substances with occupational exposure limit values. Hazardous components without workplace control parameters Ingredients CAS-No. Alcohols, C10-16, ethoxylated, sulfates, sodium salts 68585-34-2 Cocoamidopropyl betaine 61789-40-0 Engineering measures : Ensure adequate ventilation, especially in confined areas. Minimize workplace exposure concentrations. Dust formation may be relevant in the processing of this product. In addition to substance-specific OELs, general limitations of concentrations of particulates in the air at workplaces have to be considered in workplace risk assessment. Relevant limits include: OSHA PEL for Particulates Not Otherwise Regulated of 15 mg/m3 - total dust, 5 mg/m3 - respirable fraction; and ACGIH TWA for Particles (insoluble or poorly soluble) Not Otherwise Specified of 3 mg/m3 - respirable particles, 10 mg/m3 - inhalable particles. Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. Hand protection Remarks : Wash hands before breaks and at the end of workday. Eye protection : Wear the following personal protective equipment: Safety glasses Skin and body protection : Skin should be washed after contact. Hygiene measures : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. Page 196 of 262 Page 196 of 262 Page 196 of 262 Page 196 of 262 ---PAGE BREAK--- SAFETY DATA SHEET PRIME SOURCE® SILKY PINK HAND SOAP Version 1.4 Revision Date: 04/27/2015 MSDS Number: 31606-00005 Date of last issue: 03/19/2015 Date of first issue: 11/24/2014 5 / 12 SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Color : opalescent, pink Odor : floral Odor Threshold : No data available pH : 4.8 - 6.2 Melting point/freezing point : No data available Solidification / Setting point 2.9 °C Initial boiling point and boiling range : 97.00 °C Flash point : > 100 °C Evaporation rate : No data available Flammability (solid, gas) : Not applicable Upper explosion limit : No data available Lower explosion limit : No data available Vapor pressure : No data available Relative vapor density : No data available Density : 1.00 g/cm3 Solubility(ies) Water solubility : soluble Partition coefficient: n- octanol/water : Not applicable Autoignition temperature : No data available Decomposition temperature : The substance or mixture is not classified self-reactive. Viscosity Viscosity, kinematic : 3,000 - 16,000 mm2/s (20 Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. Page 197 of 262 Page 197 of 262 Page 197 of 262 Page 197 of 262 ---PAGE BREAK--- SAFETY DATA SHEET PRIME SOURCE® SILKY PINK HAND SOAP Version 1.4 Revision Date: 04/27/2015 MSDS Number: 31606-00005 Date of last issue: 03/19/2015 Date of first issue: 11/24/2014 6 / 12 SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reac- tions : Can react with strong oxidizing agents. Conditions to avoid : None known. Incompatible materials : Oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Ingredients: Alcohols, C10-16, ethoxylated, sulfates, sodium salts: Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg Assessment: The substance or mixture has no acute oral toxicity Cocoamidopropyl betaine: Acute oral toxicity : LD50: > 5,000 mg/kg Method: OECD Test Guideline 401 Remarks: Based on data from similar materials Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 402 Assessment: The substance or mixture has no acute dermal toxicity Remarks: Based on data from similar materials Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation Page 198 of 262 Page 198 of 262 Page 198 of 262 Page 198 of 262 ---PAGE BREAK--- SAFETY DATA SHEET PRIME SOURCE® SILKY PINK HAND SOAP Version 1.4 Revision Date: 04/27/2015 MSDS Number: 31606-00005 Date of last issue: 03/19/2015 Date of first issue: 11/24/2014 7 / 12 Ingredients: Alcohols, C10-16, ethoxylated, sulfates, sodium salts: Result: Skin irritation Serious eye damage/eye irritation Not classified based on available information. Product: Result: No eye irritation Ingredients: Alcohols, C10-16, ethoxylated, sulfates, sodium salts: Result: Irreversible effects on the eye Cocoamidopropyl betaine: Species: Rabbit Result: Irreversible effects on the eye Method: OECD Test Guideline 405 Remarks: Based on data from similar materials Respiratory or skin sensitization Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information. Product: Assessment: Does not cause skin sensitization. Ingredients: Cocoamidopropyl betaine: Test Type: Maximization Test (GPMT) Routes of exposure: Skin contact Species: Guinea pig Result: negative Remarks: Based on data from similar materials Germ cell mutagenicity Not classified based on available information. Ingredients: Cocoamidopropyl betaine: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative Remarks: Based on data from similar materials Genotoxicity in vivo : Test Type: Mammalian micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Ingestion Result: negative Page 199 of 262 Page 199 of 262 Page 199 of 262 Page 199 of 262 ---PAGE BREAK--- SAFETY DATA SHEET PRIME SOURCE® SILKY PINK HAND SOAP Version 1.4 Revision Date: 04/27/2015 MSDS Number: 31606-00005 Date of last issue: 03/19/2015 Date of first issue: 11/24/2014 8 / 12 Remarks: Based on data from similar materials Carcinogenicity Not classified based on available information. IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. Ingredients: Cocoamidopropyl betaine: Effects on fetal development : Test Type: Embryo-fetal development Species: Rat Application Route: Ingestion Method: OECD Test Guideline 414 Result: negative Remarks: Based on data from similar materials STOT-single exposure Not classified based on available information. STOT-repeated exposure Not classified based on available information. Repeated dose toxicity Ingredients: Cocoamidopropyl betaine: Species: Rat NOAEL: 250 mg/kg Application Route: Ingestion Exposure time: 90 d Method: OECD Test Guideline 408 Remarks: Based on data from similar materials Aspiration toxicity Not classified based on available information. Page 200 of 262 Page 200 of 262 Page 200 of 262 Page 200 of 262 ---PAGE BREAK--- SAFETY DATA SHEET PRIME SOURCE® SILKY PINK HAND SOAP Version 1.4 Revision Date: 04/27/2015 MSDS Number: 31606-00005 Date of last issue: 03/19/2015 Date of first issue: 11/24/2014 9 / 12 SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Ingredients: Cocoamidopropyl betaine: Toxicity to fish : LC50: > 1 - 10 mg/l Exposure time: 96 h Method: ISO 7346/2 Remarks: Based on data from similar materials Toxicity to bacteria : EC50: > 100 mg/l Method: OECD Test Guideline 209 Remarks: Based on data from similar materials Persistence and degradability Product: Biodegradability : Result: Biodegradable Ingredients: Alcohols, C10-16, ethoxylated, sulfates, sodium salts: Biodegradability : Result: Readily biodegradable. Cocoamidopropyl betaine: Biodegradability : Result: Readily biodegradable. Biodegradation: > 60 % Exposure time: 28 d Method: OECD Test Guideline 301 Remarks: Based on data from similar materials Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Page 201 of 262 Page 201 of 262 Page 201 of 262 Page 201 of 262 ---PAGE BREAK--- SAFETY DATA SHEET PRIME SOURCE® SILKY PINK HAND SOAP Version 1.4 Revision Date: 04/27/2015 MSDS Number: 31606-00005 Date of last issue: 03/19/2015 Date of first issue: 11/24/2014 10 / 12 SECTION 14. TRANSPORT INFORMATION International Regulation Not regulated as a dangerous good IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. Domestic regulation 49 CFR Not regulated as a dangerous good SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : No SARA Hazards SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. US State Regulations Right To Know Water 7732-18-5 70 - 90 % Alcohols, C10-16, ethoxylated, sulfates, sodium salts 68585-34-2 1 - 5 % Sodium chloride 7647-14-5 1 - 5 % New Jersey Right To Know Water 7732-18-5 70 - 90 % Alcohols, C10-16, ethoxylated, sulfates, sodium salts 68585-34-2 1 - 5 % Sodium chloride 7647-14-5 1 - 5 % Cocoamidopropyl betaine 61789-40-0 1 - 5 % Page 202 of 262 Page 202 of 262 Page 202 of 262 Page 202 of 262 ---PAGE BREAK--- SAFETY DATA SHEET PRIME SOURCE® SILKY PINK HAND SOAP Version 1.4 Revision Date: 04/27/2015 MSDS Number: 31606-00005 Date of last issue: 03/19/2015 Date of first issue: 11/24/2014 11 / 12 California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: AICS : All ingredients listed or exempt. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Sources of key data used to compile the Material Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen- cy, http://echa.europa.eu/ Revision Date : 04/27/2015 Items where changes have been made to the previous version are highlighted in the body of this document by two vertical lines. The information provided in this Safety Data Sheet is correct to the best of our knowledge, in- formation and belief at the date of its publication. The information is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provid- ed relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, un- less specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, in- Flammability Health Instability 0 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 0 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page 203 of 262 Page 203 of 262 Page 203 of 262 Page 203 of 262 ---PAGE BREAK--- SAFETY DATA SHEET PRIME SOURCE® SILKY PINK HAND SOAP Version 1.4 Revision Date: 04/27/2015 MSDS Number: 31606-00005 Date of last issue: 03/19/2015 Date of first issue: 11/24/2014 12 / 12 cluding an assessment of the appropriateness of the SDS material in the user’s end product, if applicable. US / Z8 Page 204 of 262 Page 204 of 262 Page 204 of 262 Page 204 of 262 ---PAGE BREAK--- Material Safety Data Sheet U.S. Department of Labor May be used to comply with Occupational Safety and Health Administration OSHA's Hazard Communication Standard, (Non-Mandatory Form) 29 CFR 1910.1200. This Standard must be Form Approved consulted for specific requirements. OMB No. 1218-0072 IDENTITY (As Used on Label and List) PROPANE Note: Blank spaces are not permitted. If any item is not applicable, or no information is available, the space must be marked to indicate that. Section I Manufacturer's Name BernzOmatic Emergency Telephone Number [PHONE REDACTED] Address (Number, Street, City, State, and ZIP Code) Telephone Number for Information [PHONE REDACTED] 1 Bernzomatic Drive Date Prepared June 11, 2011 Medina, NY 14103 Signature of Preparer (optional) Section II - Hazard Ingredients/Identity Information Hazardous Components (Specific Chemical Identity; Common Name(s)) US OSHA PEL ACGIH TLV Other Limits Recommended % (optional) PROPANE (CAS No. 74-98-6) 1000PPM 1000PPM N/A 100 NFPA HAZARD RATINGS Health – 1 Flammability – 4 Reactivity - 0 HMIS RATINGS Health – 0 Flammability – 4 Reactivity - 0 Notes: When propane fuel is burned efficiently, the normal by-products of combustion are CO2 and H20. Inefficient burning may add CO to the by-products of combustion. Section III - Physical/Chemical Characteristics Boiling Point: -44° F Specific Gravity (H2O = Liquid @ 60° F .51 Vapor Pressure (mm Hg.): @ 100° F 197psig Melting Point: Not Applicable Vapor Density (AIR = @ 1 ATM @ 60° F 1.56 Evaporation Rate (Butyl Acetate = Not Applicable Solubility in Water: Insoluble Appearance and Odor (At Normal Conditions): Colorless – Rotten Egg Odor. Page 205 of 262 Page 205 of 262 Page 205 of 262 Page 205 of 262 ---PAGE BREAK--- 2 Section IV - Fire and Explosion Hazard Data Flash Point (Method Used): -156° F Closed Cup Flammable Limits: LEL 2.1 UEL 9.5 Extinguishing Media: Stop flow of gas or oxygen. Special Fire Fighting Procedures: Use water to cool tanks. Unusual Fire and Explosion Hazards: Auto ignition temp. 842° F. Heavier than air (vapor density 1.5). May travel a considerable distance to a source of ignition and flashback. Section V - Reactivity Data Stability: Unstable NO Conditions to Avoid: Stable X N/A Incompatibility (Materials to Avoid): N/A Hazardous Decomposition or Byproducts At temperatures above the melting point metal oxide fumes may be evolved. Hazardous Polymerization: May Occur NO Conditions to Avoid: Will Not Occur X N/A Section VI - Health Hazard Data Route(s) of Entry: Inhalation? YES Skin? YES Ingestion? NO Health Hazards (Acute and Chronic) Contact with liquid propane may cause frost burns. Carcinogenicity: NTP? Not listed as a carcinogen IARC Monographs? Not listed as a carcinogen OSHA Regulated? Not listed as a carcinogen Signs and of Exposure: High concentrations may cause headaches and drowsiness. Medical Conditions Generally Aggravated by Exposure: Not Applicable Emergency and First Aid Procedures: Remove exposed person from contaminated area. Warning: This fuel and by-products of combustion of this fuel, contain chemicals known to the State of California to cause cancer, birth defects, and other reproductive harm. Page 206 of 262 Page 206 of 262 Page 206 of 262 Page 206 of 262 ---PAGE BREAK--- 3 Section VII - Precautions for Safe Handling and Use Steps to Be Taken in Case Material is Released or Spilled: Remove ignition sources and ventilate area. Waste Disposal Method: Vent gas to atmosphere in flame free, spark free area outdoors. Precautions to Be taken in Handling and Storing: Store at temperatures below 120° F in well ventilated, spark free, flame free area. Other Precautions: None Section VIII - Control Measures Respiratory Protection (Specify Type): Not required with normal use. Ventilation: Local Exhaust – N/A Mechanical (General) – N/A Special – N/A Other – N/A Protective Gloves: Not Required Eye Protection: Not Required Other Protective Clothing or Equipment: Not Required Work/Hygienic Practices: N/A Section IX – Transportation Information WHMIS Classification: A – Compressed Gas & B1 – Flammable Gas Class: 2.1 Proper Shipping Name: Petroleum Gas, Liquefied Hazard Classification: Flammable Gas UN Number: 1075 Section X – Additional Information DISCLAIMER: Judgments as to the suitability of information herein or the purchaser’s purposes are necessarily the purchaser’s responsibility. Reasonable care has been taken in the preparation of this material, but there are NO WARRANTIES, NO REPRESENTATIONS, AND NO RESPONSIBILITY AS TO THE ACCURACY OR THE SUITABILITY OF THIS INFORMATION FOR ANY PURCHASER’S USE OR FOR ANY CONSEQUENCE TO USE. This Material Safety Data Sheet is offered solely for your information, consideration and investigation. BernzOmatic provides no warranties; either express or implied, and assumes no responsibilities for the accuracy or completeness of the data contained in this document. The data in this Material Safety Data Sheet relates only to this product and does not relate to use in combination with any other material or in any process. Page 207 of 262 Page 207 of 262 Page 207 of 262 Page 207 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 1/14 1. PRODUCT AND COMPANY IDENTIFICATION Product information Product name : RAID® WASP & HORNET KILLER 33 Recommended use : Insecticide Manufacturer, importer, supplier : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236 Telephone : +18005585252 Emergency telephone number : 24 Hour Medical Emergency Phone: (866)231-5406 24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300 2. HAZARDS IDENTIFICATION Classification of the substance or mixture Globally Harmonized System (GHS) Classification Hazard classification Hazard category Hazards identification Aerosol Category 1 Extremely flammable aerosol. Aspiration hazard Category 1 May be fatal if swallowed and enters airways. Gases under pressure Compressed gas Contains gas under pressure; may explode if heated. Labelling Hazard symbols Flame Gas cylinder Health hazard Signal word Danger Hazard statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal if swallowed and enters airways. Precautionary statements If medical advice is needed, have product container or label at hand. Page 208 of 262 Page 208 of 262 Page 208 of 262 Page 208 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 2/14 Keep out of reach of children. Read label before use. IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. Do NOT induce vomiting. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 122 Protect from sunlight. Store in a well-ventilated place. Dispose of contents/ container to an approved incineration plant. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Other hazards : None identified 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No. Weight percent Distillates (petroleum), hydrotreated light 64742-47-8 60.00 - 100.00 Carbon dioxide 124-38-9 1.00 - 5.00 Isopropanol 67-63-0 1.00 - 5.00 Cypermethrin 52315-07-8 0.0001 - 0.10 Prallethrin 23031-36-9 0.0001 - 0.10 The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Eye contact : No special requirements Skin contact : No special requirements Inhalation : No special requirements. Ingestion : IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. Do NOT induce vomiting. Page 209 of 262 Page 209 of 262 Page 209 of 262 Page 209 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 3/14 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during firefighting : Do not use a solid water stream as it may scatter and spread fire. Aerosol Product - Containers may rocket or explode in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses. Further information : Fight fire from maximum distance or protected area. Cool and use caution when approaching or handling fire-exposed containers. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. NFPA Classification : NFPA Level 3 Aerosol 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Remove all sources of ignition. Wear personal protective equipment. Wash thoroughly after handling. Environmental precautions : Do not flush into surface water or sanitary sewer system. Use appropriate containment to avoid environmental contamination. Outside of normal use, avoid release to the environment. Methods and materials for containment and cleaning up : If damage occurs to aerosol can: Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Dike large spills. Clean residue from spill site. 7. HANDLING AND STORAGE Handling Page 210 of 262 Page 210 of 262 Page 210 of 262 Page 210 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 4/14 Precautions for safe handling : Avoid contact with skin, eyes and clothing. Do not enter places where used or stored until adequately ventilated. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Pressurized container. Do not pierce or burn, even after use. Advice on protection against fire and explosion : Keep away from sources of ignition - No smoking. Do not spray on an open flame or other ignition source. Storage Requirements for storage areas and containers : Protect from sunlight. Do not expose to temperatures exceeding 50 122 Keep away from food, drink and animal feedingstuffs. Keep in a dry, cool and well-ventilated place. Store locked up. Page 211 of 262 Page 211 of 262 Page 211 of 262 Page 211 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 5/14 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Non- standard units Basis Distillates (petroleum), hydrotreated light 64742-47-8 1,200 mg/m3 152 ppm - SUPPLIER Carbon dioxide 124-38-9 9,000 mg/m3 5,000 ppm - OSHA TWA Carbon dioxide 124-38-9 - 30,000 ppm - ACGIH STEL Carbon dioxide 124-38-9 - 5,000 ppm - ACGIH TWA Isopropanol 67-63-0 980 mg/m3 400 ppm - OSHA TWA Isopropanol 67-63-0 - 400 ppm - ACGIH STEL Isopropanol 67-63-0 - 200 ppm - ACGIH TWA Personal protective equipment Respiratory protection : Do not spray in enclosed areas. Hand protection : No special requirements. Eye protection : No special requirements. Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 212 of 262 Page 212 of 262 Page 212 of 262 Page 212 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 6/14 Form : aerosol Color : clear Odor : characteristic Odour Threshold : No data available pH : Not applicable Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Flash point : 22 °C 71.6 °F Evaporation rate : No data available Flammability (solid, gas) : Sustains combustion Upper/lower flammability or explosive limits : No data available Vapour pressure : Not applicable Vapour density : No data available Relative density : 0.81 g/cm3 at 21 °CGLP: yes Solubility(ies) : negligible Partition coefficient: n- : No data available Page 213 of 262 Page 213 of 262 Page 213 of 262 Page 213 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 7/14 octanol/water Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity, dynamic : No data available Viscosity, kinematic : No data available Oxidizing properties : No data available Volatile Organic Compounds Total VOC (wt. : 3 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations Other information : None identified : 10. STABILITY AND REACTIVITY Possibility of hazardous reactions : Stable under recommended storage conditions. Conditions to avoid : Heat, flames and sparks. Incompatible materials : Strong oxidizing agents Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. 11. TOXICOLOGICAL INFORMATION Emergency Overview : Danger Page 214 of 262 Page 214 of 262 Page 214 of 262 Page 214 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 8/14 Acute oral toxicity : NA GHS LD50 estimated > 5,000 mg/kg Acute inhalation toxicity : NA GHS LC50 (dust and mist) estimated > 5.47 mg/l Acute dermal toxicity : NA GHS LD50 estimated > 5,000 mg/kg GHS Properties Classification Routes of entry Acute toxicity No classification proposed - Acute toxicity No classification proposed - Acute toxicity No classification proposed - Skin corrosion/irritation No classification proposed - Serious eye damage/eye irritation No classification proposed - Skin sensitisation No classification proposed - Respiratory sensitisation No classification proposed - Germ cell mutagenicity No classification proposed - Carcinogenicity No classification proposed - Reproductive toxicity No classification proposed - Specific target organ toxicity - single exposure No classification proposed - Specific target organ toxicity - repeated exposure No classification proposed - Aspiration hazard Category 1 - Aggravated Medical : None known. Page 215 of 262 Page 215 of 262 Page 215 of 262 Page 215 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 9/14 Condition 12. ECOLOGICAL INFORMATION Product : The product itself has not been tested. Toxicity The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions. Toxicity to fish Distillates (petroleum), hydrotreated light static test LC50 Lepomis macrochirus 2.2 mg/l 96 h Carbon dioxide No data available Isopropanol LC50 Pimephales promelas (fathead minnow) 9,640 mg/l 96 h Cypermethrin LC50 mykiss (rainbow trout) 0.00283 mg/l 96 h NOEC Pimephales promelas (fathead minnow) 0.00001 mg/l 28 d Prallethrin LC50 mykiss (rainbow trout) 0.012 mg/l 96 h Toxicity to aquatic invertebrates Distillates (petroleum), hydrotreated light No data available Components End point Species Value Exposure time Components End point Species Value Exposure time Page 216 of 262 Page 216 of 262 Page 216 of 262 Page 216 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 10/14 Carbon dioxide No data available Isopropanol EC50 Daphnia magna (Water flea) 13,299 mg/l 48 h Cypermethrin EC50 Daphnia magna (Water flea) 0.00471 mg/l 48 h NOEC Daphnia magna (Water flea) 0.00004 mg/l 21 d Prallethrin EC50 Daphnia magna (Water flea) 0.0062 mg/l 48 h Toxicity to aquatic plants Distillates (petroleum), hydrotreated light No data available Carbon dioxide No data available Isopropanol EC50 Desmodesmus subspicatus (green algae) > 1,000 mg/l 72 h Cypermethrin ErC50 No data available > 0.0033 mg/l 72 h Prallethrin No data available Pseudokirchneriella subcapitata (green algae) 2 mg/l 96 h Persistence and degradability Component Biodegradation Exposure time Summary Components End point Species Value Exposure time Page 217 of 262 Page 217 of 262 Page 217 of 262 Page 217 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 11/14 Distillates (petroleum), hydrotreated light No data available Carbon dioxide No data available Isopropanol 53 % 5 d Readily biodegradable Cypermethrin 0.6 - 1.4 % 33 d Not readily biodegradable. Prallethrin No data available Not readily biodegradable. Bioaccumulative potential Component Bioconcentration factor (BCF) Partition Coefficient n- Octanol/water (log) Distillates (petroleum), hydrotreated light 61 - 159 No data available Carbon dioxide No data available No data available Isopropanol 0.96 estimated 0.05 Cypermethrin 373.4 Measured 5.3 - 5.6 Prallethrin No data available 4.49 Mobility Component End point Value Distillates (petroleum), hydrotreated light No data available Carbon dioxide No data available Isopropanol No data available Cypermethrin Koc 80653 - 574360 Prallethrin No data available PBT and vPvB assessment Component Results Distillates (petroleum), hydrotreated light Not fulfilling PBT and vPvB criteria Isopropanol Not fulfilling PBT and vPvB criteria Page 218 of 262 Page 218 of 262 Page 218 of 262 Page 218 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 12/14 Cypermethrin Not fulfilling PBT and vPvB criteria Prallethrin Not fulfilling PBT and vPvB criteria Other adverse effects : None known. 13. DISPOSAL CONSIDERATIONS PESTICIDAL WASTE: For disposal information, please read and follow Disposal instructions on the pesticide label. Consumer may discard empty container in trash, or recycle where facilities exist. 14. TRANSPORT INFORMATION Please refer to the Bill of Lading/receiving documents for up-to-date shipping information. Land transport Sea transport Air transport UN number 1950 1950 1950 UN proper shipping name AEROSOLS, Flammable, 2.1 AEROSOLS, Flammable, 2.1 AEROSOLS, Flammable, 2.1 Transport hazard class(es) 2.1 2 2.1 Packing group - - - Environmental hazards - - - Special precautions for user Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. 15. REGULATORY INFORMATION FIFRA Labeling This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to Page 219 of 262 Page 219 of 262 Page 219 of 262 Page 219 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 13/14 certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION: CONTENTS UNDER PRESSURE. Exposure to temperatures above 130° F may cause bursting. Extremely flammable. This product is extremely toxic to fish and aquatic invertebrates. Drift and runoff may be hazardous to fish in water adjacent to treated areas. Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Registration # / Agency 4822-553/US/EPA 16. OTHER INFORMATION HMIS Ratings Health 2 Flammability 3 Reactivity 0 Page 220 of 262 Page 220 of 262 Page 220 of 262 Page 220 of 262 ---PAGE BREAK--- Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200 RAID® WASP & HORNET KILLER 33 Version 1.1 Print Date 03/04/2015 Revision Date 02/23/2015 SDS Number 350000010777 14/14 NFPA Ratings Health 2 Fire 3 Reactivity 0 Special - This information is being provided in accordance with the Occupational Safety and Health Administration (OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use. Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) Page 221 of 262 Page 221 of 262 Page 221 of 262 Page 221 of 262 ---PAGE BREAK--- ---PAGE BREAK--- ---PAGE BREAK--- ---PAGE BREAK--- TWINKLE METAL POLISH & FIBERGLASS CLEANER 90165 Industrial/Institutional: Cleaning product. 04/19/2000 04/20/2000 Material Safety Data Sheet Product Name Product Use Validation Date Print Date In Case of Emergency Section 1. Chemical Product and Company Identification Supersedes 04/13/2000. Health 1 0 0 Fire Hazard Reactivity Specific Hazard Health Fire Hazard Reactivity Protective Clothing 0 0 1 (800) 851-7145 U.S. Headquarters Hazardous Material Information System (HMIS) National Fire Protection Association (NFPA) Code MSDS# 126154001 433283 Drackett Professional A Division of S.C. Johnson Commercial Markets, Inc. 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249 Blue. Paste. See Section 9. CAUTION: May be mildly irritating to eyes. May be mildly irritating to skin. Emergency Overview None required. PMS# TWINKLE METAL POLISH & FIBERGLASS CLEANER Ammonium Hydroxide 1336-21-6 <1.0 Not available. ORAL (LD50): Acute: 350 mg/kg [Rat]. Emulsifier 68439-49-6 <1.0 Not available. ORAL (LD50): Acute: 1260 mg/kg [Rat]. Octadecanoic acid 26764-26-1 5-10 Not available. Not available. Petroleum distillates 64342-88-7 10-30 Not available. Not available. Polishing powder 1313-74-7 10-30 Not available. Not available. Water 7732-18-5 30-60 Not available. Not available. Section 2. Composition and Information on Ingredients Ingredients CAS # % by Weight Exposure Limits LC50/LD50 Inhalation. Skin contact. Eye contact. Medical Conditions Aggravated by Overexposure: None known. Section 3. Hazards Identification Routes of Entry Potential Acute Health Effects None known. May be mildly irritating to eyes. None known. May be mildly irritating to skin. Eyes Skin Inhalation Ingestion See Toxicological Information (section 11) Continued on Next Page Page: 1/4 Page 225 of 262 Page 225 of 262 Page 225 of 262 Page 225 of 262 ---PAGE BREAK--- Material Safety Data Sheet TWINKLE METAL POLISH & FIBERGLASS CLEANER No specific first aid measures are required. Flush immediately with plenty of water. Get medical attention if irritation occurs. Flush immediately with plenty of water. Get medical attention if irritation occurs. No specific first aid measures are required. Section 4. First Aid Measures Eye Contact Skin Contact Inhalation Ingestion None known. None known. Not available. Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire fighting procedure may be used. None known. Section 5. Fire Fighting Measures Flammability of the Product Flash Points Products of Combustion Fire Fighting Media and Instructions Special Remarks on Fire and Explosion Hazards In the event of major spillage: Use appropriate containment to avoid environmental contamination. Sweep or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a water rinse for final clean-up. Put on appropriate personal protective equipment (see Section Section 6. Accidental Release Measures Personal Precautions Environmental Precautions and Clean-up Methods Store in a dry, cool and well-ventilated area. Protect from freezing. KEEP OUT OF REACH OF CHILDREN. Avoid contact with skin and eyes. FOR INDUSTRIAL USE ONLY. Section 7. Handling and Storage Handling Storage No special ventilation requirements. General room ventilation is adequate. Section 8. Exposure Controls/Personal Protection Engineering Controls No special protective clothing is required. No special protective clothing is required. No special protective clothing is required. No special protective clothing is required. No special protective clothing is required. Personal Protection Eyes Hands Respiratory Feet Body 93°C (199.4°F) Solid. (Paste.) 9.5 [Basic.] 1.12 Ammoniacal. Blue. Boiling/Condensation Point Section 9. Physical and Chemical Properties Physical State and Appearance pH Specific Gravity Solubility in water Odor Color Negligible. Continued on Next Page Page: 2/4 Page 226 of 262 Page 226 of 262 Page 226 of 262 Page 226 of 262 ---PAGE BREAK--- Material Safety Data Sheet TWINKLE METAL POLISH & FIBERGLASS CLEANER The product is stable. Not available. Will not occur. When exposed to fire: Produces normal products of combustion. None known. Section 10. Stability and Reactivity Stability and Reactivity Conditions of Instability Incompatibility with Various Substances Hazardous Decomposition Products Hazardous Polymerization Section 11. Toxicological Information Effects of Chronic Exposure Other Toxic Effects None known. ORAL (LD50) Estimated to be greater than 5000 mg/kg (rat). Acute toxicity Not available. Section 12. Ecological Information Not available. No special precautions. Dispose of according to all federal, state and local regulations. Waste Information Section 13. Disposal Considerations Section 14. Transport Information DOT Classification TDG Classification Not regulated Not regulated Section 15. Regulatory Information Chemical Inventory Status US Regulations Canadian Regulations Not applicable. All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Registered Product Information This product is not subject to the reporting requirements under California's Proposition 65. Reporting in this section is based on ingredients disclosed in Section 2 WHMIS Classification WHMIS Icon Registered Product Information Not applicable. Not applicable. Continued on Next Page Page: 3/4 Page 227 of 262 Page 227 of 262 Page 227 of 262 Page 227 of 262 ---PAGE BREAK--- Material Safety Data Sheet TWINKLE METAL POLISH & FIBERGLASS CLEANER Not available. Section 16. Other Information Other Special Considerations Notice to Reader This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Version 1 Page 228 of 262 Page 228 of 262 Page 228 of 262 Page 228 of 262 ---PAGE BREAK--- UNITED 166 320 37th Avenue, St. Charles, Illinois 60174 • 214 Dolomite Drive, Downsview, Ontario M3J2N2 To Reorder Call: www.unitedlabsinc.com [PHONE REDACTED] MATERIAL SAFETY DATA SHEET 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 166 POWER UP Foaming, No Rinse Chiller Coil Cleaner March 5, 2008 HEALTH (0 = Maximum Safety) 1 REACTIVITY (0 = Maximum Safety) 0 Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 Always follow Label Directions and Cautions. 4 Extreme 3 High 2 Moderate 1 Slight 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. FLAMMABILITY (0 = Maximum Safety) 2 - 1 - Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: B 2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) Tetrasodium EDTA 64-02-8 1-5 NE NE 3030 mg/kg (Rat/oral) NE Diethylene glycol monoethyl ether 111-90-0 1-5 NE NE 1920-9050 mg/kg (Rat/oral) NE 2-Butoxyethanol 111-76-2 1-5 20 ppm 50 ppm Skin 470 mg/kg (Rat/oral) 450 ppm/4 hr (Rat/ Inhalation) Propane/n-Butane 68476-86-8 1-5 1000 ppm 1000 ppm NE NE 3. HAZARDS IDENTIFICATION Eyes: May cause irritation. Can cause burning sensation, redness, and pain. Skin: May cause irritation on prolonged contact. Inhalation: Breathing vapors and mists may cause mucous membrane and respiratory irritation. Excessive overexposure may cause headache, dizziness, drowsiness, depressed respiration and heart rate, heat irregularities, shortness of breath, unconsciousness or death. Intentional misuse by concentrating and inhaling contents may be harmful or fatal. Ingestion: Exposure by ingestion is unlikely since an aerosol, but if occurs: may cause gastrointestinal irritation, nausea, vomiting, dizziness. 4. FIRST AID MEASURES Eyes: Flush with plenty of water for at least 15 minutes while holding eyelids open. Call a physician or poison control center immediately. Skin: Wash with soap and water. If irritation persists, call a physician or poison control center. Inhalation: Remove to fresh air. If irritation persists, call a physician or poison control center. If Swallowed: DO NOT induce vomiting. Call a physician or poison control center immediately. 5. FIRE FIGHTING MEASURES Flash Point (TCC): (of Concentrate Only) >154°F/>68°C Explosive Limits: Lower (LEL): 1.8 Upper (UEL): 9.5 Flame Projection (Aerosol): Product is not required to be labeled as flammable per 16 CFR 1500.3 and 1500.45. Hazardous Products of Combustion: When strongly heated, as in a fire, may produce oxides of carbon. Fire and Explosion Hazards: Contents under pressure. Keep away from heat and open flames. Container may rupture or explode in the heat of a fire. Prolonged exposure to temperatures above 54°C/130°F may cause cans to burst. Extinguishing Media: Water spray, Foam, Carbon dioxide, Dry chemical. Fire Fighting Instructions: Wear self-contained breathing apparatus w/full protective clothing. Containers should be cooled with water fog to prevent vapor pressure build up. Use equipment or shielding, as required, to protect personnel from bursting, rupturing or venting containers. Page 229 of 262 Page 229 of 262 Page 229 of 262 Page 229 of 262 ---PAGE BREAK--- - 2 - 6. ACCIDENTAL RELEASE MEASURES Small Spills: Ventilate area. Remove all sources of ignition. Soak up spill with an inert absorbent and place into a designated disposal container. Large Spills: Wear appropriate protective clothing. Remove all sources of ignition. Soak up spill with an inert absorbent and place into a designated disposal container. 7. HANDLING AND STORAGE Store in a cool, dry area away from heat or open flame. Do not puncture or incinerate containers. Do not store at temperatures above 120°F/ 49°C. Do not expose to direct sunlight. For Industrial and Institutional use only. NFPA Code 30 B Storage Level Number 1 Aerosol. Avoid breathing vapors or spray mist. Avoid contact with eyes. Avoid prolonged contact with skin or clothing. Wash thoroughly with soap and water after handling. KEEP OUT OF REACH OF CHILDREN. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Safety glasses or safety goggles are recommended. Skin: Chemical resistant gloves are recommended if needed to avoid prolonged skin contact. Respiratory: None required if good ventilation is maintained. If exposure exceeds TLV levels, use a NIOSH/MSHA approved respirator to prevent overexposure. Engineering Controls: General ventilation is adequate under normal conditions; mechanical ventilation may be required for use in poorly ventilated areas or when large amounts are used. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: NA Specific Gravity: 0.9697 (H2O=1) Vapor Pressure: 116@130°F/ 51@70°F Melting Point: ND Vapor Density: >1 Evaporation Rate: ND Solubility in Water: Soluble pH: 12-12.5 Appearance and Odor: Aerosol; hazy, yellow spray with floral odor. 10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: When ignited or strongly heated, as in a fire this product may produce oxides of carbon. Chemical Stability: Stable Incompatibility: Avoid contact with strong oxidizing agents, acids and bases. 11. TOXICOLOGICAL INFORMATION Carcinogenicity (NTP/IARC/OSHA): None California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? Yes 12. ECOLOGICAL INFORMATION ND 13. DISPOSAL CONSIDERATIONS Consult your local, state, provincial and federal regulations for proper disposal guidelines. Do not puncture or incinerate containers. Disposal regulations may be different for each state and/or locality. 14. TRANSPORT INFORMATION DOT: Available upon request TDG: Available upon request UN: Availabale upon request 15. REGULATORY INFORMATION VOC(Volatile Organic Compounds): 8% TSCA (Toxic Substances Control Act): Listed SARA Title III Section 302 EHS: ND SARA Title III Section 311/312: ND SARA Title III Section 313 Toxic Chemicals: None WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 166 POWER UP PREPARED BY: Sandy Kopacz Page 230 of 262 Page 230 of 262 Page 230 of 262 Page 230 of 262 ---PAGE BREAK--- - 1 - UNITED 195 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 195 SMELL JEL Jellied Deodorant Spray December 22, 2012 HMIS III HEALTH (0 = Maximum Safety) 0 PHYSICAL HAZARD (0 = Maximum Safety) 0 Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 FLAMMABILITY (0 = Maximum Safety) 1 2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) Isopropyl alcohol 67-63-0 5-10 200 ppm 400 ppm 980 mg/m3 >5045 mg/kg (Rat/oral) 16000 ppm 8 hr (Rat) 1.2-propanediol 57-55-6 5-10 N/A N/A 22000-31000 Mg/kg(Rat/oral) N/A Propane/N-Butane 68476-85-7 10-30 1000 ppm 1800 mg/m3 1000 ppm 1800 mg/m3 N/A N/A 3. HAZARDS IDENTIFICATION Emergency Overview: Aerosol under pressure do not expose to high temperatures 120°F/49°C or store in direct sunlight. Routes of Entry: Eyes, Skin, Ingestion, Inhalation Eyes: May cause irritation. Skin: May cause slight irritation, possible dryness with prolonged contact. Inhalation: Intentional overexposure to mist or vapors may result in dizziness and headache. Ingestion: May cause nausea or gastric discomfort. Chronic Health Hazards: None known. Medical Conditions Generally Aggravated by Exposure: None known. Carcinogenicity (NTP/IARC/OSHA): None 4. FIRST AID MEASURES Eyes: Flush with plenty of water for 15 minutes and call a physician immediately. Skin: Wash with soap and water. If irritation persists, call a physician. If Inhaled: Remove patient to fresh air immediately. Apply artificial respiration if needed and call a physician. If Swallowed: Drink several glasses of water. Call a physician immediately. 5. FIRE FIGHTING MEASURES Flash Point (TCC): 180°F/82.2°C Explosive Limits: Lower (LEL): ND Upper (UEL): ND Flame Projection (Aerosol): Nonflammable per 16 CFR 1500.45 Hazardous Products of Combustion: When strongly heated, as in a fire, this product may produce carbon dioxide and carbon monoxide. Fire and Explosion Hazards: Do not expose aerosols to temperatures above 120°F/49°C or the container may burst, rupture or vent. Extinguishing Media: Water, foam, Carbon dioxide, Dry chemical, Fire Fighting Instructions: Wear self-contained breathing apparatus w/full protective clothing. Containers should be cooled with water to prevent vapor pressure build up. Prevent runoff from entering sewers and public waterways. 6. ACCIDENTAL RELEASE MEASURES Small Spills: Pick up small spills with rag or towel. Clean surface thoroughly to remove residual contamination. Large Spills: Remove sources of ignition and ventilate area. Soak up with an inert absorbent and place in designated disposal container. Prevent material from entering sewers or drains. Wash area thoroughly to remove residual contamination. MATERIAL SAFETY DATA SHEET 320 37th Avenue, St. Charles, Illinois 60174 To Reorder Call: www.unitedlabsinc.com . www.unitedlabsinc.ca [PHONE REDACTED] Always follow Label Directions and Cautions. * Chronic 2 Moderate 4 Severe 1 Slight 3 Serious 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: A Page 231 of 262 Page 231 of 262 Page 231 of 262 Page 231 of 262 ---PAGE BREAK--- - 2 - 7. HANDLING AND STORAGE Keep this product properly labeled and store in a cool, well-ventilated area, away from heat or other sources of ignition. Do not expose to direct sunlight or store at temperatures above 120°F/49°C. may cause bursting. Wash hands and face with soap and water after using this product. Keep out of reach of children. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Safety glasses recommended if direct contact is possible. Skin: Chemical resistant gloves recommended only for prolonged or repeated exposure. Respiratory: Not normally needed. If TLV is exceeded, an organic vapor cartridge respirator or SCBA may be needed. Engineering Controls: Ventilation not normally required and local exhaust generally adequate. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 212°F/100°C (Initial-Concentrate) Specific Gravity: 0.99 (Concentrate@77°F) Vapor Pressure: 17.5 77°F Melting Point: ND Vapor Density: >1 Evaporation Rate: <1 Solubility in Water: Soluble pH: 7.6—7.7 VOC (Volatile Organic Compounds): 24.9% Appearance and Odor: White aerosol foam in orange or mulberry scent 10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: When strongly heated, as in a fire, this product may produce carbon dioxide and carbon monoxide. Chemical Stability: Stable Conditions to Avoid (Polymerization): None Incompatibility: Avoid contact with strong oxidizers, alkalies, and acids. 11. TOXICOLOGICAL INFORMATION See section 2 12. ECOLOGICAL INFORMATION N/A 13. DISPOSAL CONSIDERATIONS Consult your local, state, provincial and federal regulations for proper disposal guidelines. Do not puncture or incinerate containers. Wrap container and place in trash collection. Disposal regulations may be different for each state and/or locality. Aerosol cans when vented to atmospheric pressure through normal use pose no disposal hazard. RCRA Hazard Class: Considered non-hazardous under RCA, however product should be fully characterized prior to disposal (40 CFR 261) 14. TRANSPORT INFORMATION US DOT: Consumer Commodity, ORM-D IMDG-Water/Ocean: UN 1950, AEROSOLS IN LIMITED QUANTITIES OF CLASS 2, 2.2, PG None IATA-Air: UN 1950, AEROSOLS IN LIMITED QUANTITIES OF CLASS 2, 2.2 PG None 15. REGULATORY INFORMATION U.S. Federal Regulations: TSCA (Toxic Substances Control Act): All Chemicals are listed or exempt CERCLA (Comprehensive Response Compensation, and Liability Act): None SARA Title III Section 302 EHS: None SARA Title III Section 311/312: None SARA Title III Section 313 Toxic Chemicals: Isopropyl Alcohol – CAS#67-63-0 State Regulations: California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? No Right-to-know acts for Rhode Island, Florida, Minnesota, Massachusetts, New Jersey, Tennessee, Connecticut hazardous material survey. Illinois toxic substances disclosure to employee act. 195WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR. California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? No 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 195 SMELL JEL PREPARED BY: Sandy Kopacz Page 232 of 262 Page 232 of 262 Page 232 of 262 Page 232 of 262 ---PAGE BREAK--- - 1 - UNITED 77 1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): [PHONE REDACTED] PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 77 BIATRON® Organic Digester and Liquid Drain Cleaner February 8, 2013 HMIS III HEALTH (0 = Maximum Safety) 3 PHYSICAL HAZARD (0 = Maximum Safety) 2 Always follow Label Directions and Cautions. Always follow Label Directions and Cautions. 4 FLAMMABILITY (0 = Maximum Safety) 0 2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) Sulfuric acid 7664-93-9 60-100 1 mg/m3 1 mg/m3 2140 mg/kg (rat/oral) 347 ppm 1 hr/rat 3. HAZARDS IDENTIFICATION Eyes: Very corrosive. Causes severe burns and blindness. Do not wear contact lenses. Skin: Very corrosive. Causes severe and painful burns. Inhalation: May cause headache, drowsiness, and central nervous system depression. Mist causes severe irritation of nose, throat and lungs. Ingestion: Very corrosive. Causes severe burns to mouth, throat, and stomach. Harmful or fatal. 4. FIRST AID MEASURES Eyes: Flood with cool water for at least 15 minutes and get medical attention immediately. DO NOT wear contact lenses. Skin: Flood with cool water for several minutes until all the product is washed away. Then cover area with moistened sodium bicarbonate. Seek medical attention immediately. Inhalation: Remove patient to fresh air immediately. If patient is not breathing, apply artificial respiration. Seek medical attention immediately. Ingestion: DO NOT induce vomiting. If conscious, immediately drink large amounts of water to reduce the concentration. Give milk of magnesia or whites of eggs beaten into water. Avoid carbonates or sulfates. Get medical attention immediately. 5. FIRE FIGHTING MEASURES Flash Point (TCC): None Explosive Limits: Lower (LEL): NA Upper (UEL): NA Flame Projection (Aerosol): NA Hazardous Products of Combustion: When strongly heated, as in a fire, this product may produce oxides of sulfur and carbon. Fire and Explosion Hazards: This product reacts violently with generation of great heat, when water is added. Temperatures may exceed 240F and may boil and splatter the mixture. May react with metals to release hydrogen gas. Extinguishing Media: Use media appropriate for surrounding material. Use water spray to cool containers exposed to fire. Do not get water inside containers. Fire Fighting Instructions: Avoid spraying water onto leaking containers. Water applied directly to sulfuric acid causes evolution of heat and splattering. Firefighters should wear full protective equipment and NIOSH approved self-contained breathing apparatus. Stay upwind if product is involved in a fire. MATERIAL SAFETY DATA SHEET 320 37th Avenue, St. Charles, Illinois 60174 To Reorder Call: www.unitedlabsinc.com . www.unitedlabsinc.ca [PHONE REDACTED] Always follow Label Directions and Cautions. * Chronic 2 Moderate 4 Severe 1 Slight 3 Serious 0 Minimal See Hazards Identification Section of this MSDS for more detailed information. Susceptible to Release of Energy. 4 May detonate-vacate area if 2 Violent chemical change materials are exposed to fire. possible-use hose stream 3 Strong shock of heat may from distance detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. Susceptibility of Material to Burning. 4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn. PERSONAL PROTECTION: p, n, o Page 233 of 262 Page 233 of 262 Page 233 of 262 Page 233 of 262 ---PAGE BREAK--- - 2 - 6. ACCIDENTAL RELEASE MEASURES Small Spills: Wear protective equipment and clothing before entering area. Ventilate area. Avoid contact with skin and eyes. Neutralize spill with soda ash. Flush area with water using care. Unneutralized acid will generate heat when mixed with water. Large Spills: Same as above. 7. HANDLING AND STORAGE Store in a secure area out of reach of children and unauthorized persons. Keep containers closed when not in use. Do not store near incompatible materials, such as strong alkalis or flammables. Store product in a well-ventilated area. Do not add water to concentrate. Wear appropriate personal protective equipment. Do not breathe sprays or mists. Do not get in eyes, on skin or on clothing. Do not ingest. Deactivating chemicals: Lime, limestone, sodium carbonate, sodium bicarbonate, diluted sodium hydroxide, dilute aqua ammonia. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Safety goggles and Face Shield are recommended. Skin: Chemical resistant gloves are recommended. Respiratory: To avoid breathing fumes, use NIOSH-approved respirator. Engineering Controls: Mechanical ventilation recommended when handling in enclosed/tight spaces. Other Protective Equipment: Coveralls, boots and or other acid resistant protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 535F/279C Specific Gravity: 1.835 (H2O=1) Vapor Pressure: 1.7 mmHg Melting Point: -31F/35C Vapor Density: >1 (air=1) Evaporation Rate: <1 (BA=1) Solubility in Water: Complete pH: 1 Appearance and Odor: viscous, clear, tan colored liquid with no scent 10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: When strongly heated, as in a fire, this product may produce toxic gases and vapors (sulfur dioxide, sulfuric acid vapors and sulfur trioxide) may be released when sulfuric acid decomposes. Chemical Stability: Stable under normal conditions, but reacts violently with water and organic materials with evolution of heat. Under fire conditions, decomposes to form sulfur oxides. Incompatibility: Do not mix this product with other cleaning chemicals, especially bases or oxidizers such as bleach. 11. TOXICOLOGICAL INFORMATION Carcinogenicity (NTP/IARC/OSHA): None California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? No 12. ECOLOGICAL INFORMATION ND 13. DISPOSAL CONSIDERATIONS Consult your local, state and federal regulations for proper disposal guidelines. Disposal regulations may be different for each state and/or locality. 14. TRANSPORT INFORMATION DOT- Land: UN 1830, Sulfuric Acid, 8, PG II TDG - Land: UN 1830, Sulphuric Acid, 8, PG II UN: Available upon request. 15. REGULATORY INFORMATION VOC Volatile Organic Compounds): None TSCA (Toxic Substances Control Act): Listed SARA Title III Section 302 EHS: Extremely hazardous substance. SARA Title III Section 311/312: Immediate health, delayed health and physical hazard. SARA Title III Section 313 Toxic Chemicals: Sulfuric acid CAS# 7664-93-9 WHMIS Classification: E, D1A This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN. UNITED 77 BIATRON® PREPARED BY: Sandy Kopacz Page 234 of 262 Page 234 of 262 Page 234 of 262 Page 234 of 262 ---PAGE BREAK--- SAFETY DATA SHEET 1. Identification Unleaded Gasoline - All Grades Product identifier Other means of identification SER20 SDS number 8950A; 8951A Product code Fuel. Recommended use None known. Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name Silver Eagle Refining Inc. Address 2355 South 1100 West Woods Cross Utah 84087 US Telephone number [PHONE REDACTED] Contact person Quality Assurance Manager Emergency telephone number CHEMTREC [PHONE REDACTED] 2. Hazard(s) identification Category 1 Flammable liquids Physical hazards Category 2 Skin corrosion/irritation Health hazards Category 1B Germ cell mutagenicity Category 1A Carcinogenicity Category 2 Reproductive toxicity Category 3 respiratory tract irritation Specific target organ toxicity, single exposure Category 3 narcotic effects Specific target organ toxicity, single exposure Category 1 (Bone Marrow, Central nervius System, Blood) Specific target organ toxicity, repeated exposure Category 1 Aspiration hazard Category 1 Hazardous to the aquatic environment, acute hazard Environmental hazards Category 1 Hazardous to the aquatic environment, long-term hazard Not classified. OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable liquid and vapor. Causes skin irritation. May cause genetic defects. May cause cancer. Suspected of damaging fertility or the unborn child. May cause respiratory irritation. May cause drowsiness or dizziness. Causes damage to organs (Central Nervous System, Blood, Bone Marrow) through prolonged or repeated exposure. May be fatal if swallowed and enters airways. Very toxic to aquatic life with long lasting effects. Unleaded Gasoline - All Grades SDS US 920117 Version 01 Revision date: - Issue date: 18-May-2015 1 / 15 Page 235 of 262 Page 235 of 262 Page 235 of 262 Page 235 of 262 ---PAGE BREAK--- Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe mist or vapor. Use only outdoors or in a well-ventilated area. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Avoid release to the environment. Response In case of fire: Use appropriate media to extinguish. If ingested: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin (or hair): Immediately remove all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before re-use. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If exposed or concerned: Get medical advice/attention. Specific treatment (see this label). Collect spillage. Storage Keep container closed. Store in a well-ventilated place. Keep cool. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) Static Accumulating Liquid. Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. 3. Composition/information on ingredients Mixtures 86290-81-5 88-100 Gasoline CAS number % Chemical name 108-88-3 5-25 Toluene 1330-20-7 5-20 Xylene 64-17-5 9-10 Ethanol 78-78-4 0-10 79-29-8 0-5 592-27-8 0-5 591-76-4 0-5 107-83-5 0-5 589-81-1 0-5 589-34-4 0-5 96-14-0 0-5 71-43-2 0-5 Benzene 106-97-8 0-5 Butane 110-82-7 0-5 Cyclohexane 100-41-4 0-5 25550-14-5 0-5 142-82-5 0-5 Heptane 111-65-9 0-5 Octane 109-66-0 0-5 Pentane 25551-13-7 0-5 110-54-3 0-5 n-Hexane All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Composition comments Unleaded Gasoline - All Grades SDS US 920117 Version 01 Revision date: - Issue date: 18-May-2015 2 / 15 Page 236 of 262 Page 236 of 262 Page 236 of 262 Page 236 of 262 ---PAGE BREAK--- 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Inhalation Immediately remove all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Get medical attention if irritation develops and persists. Eye contact Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Ingestion Irritation of eyes and mucous membranes. Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. May cause respiratory irritation. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Skin irritation. May cause redness and pain. Most important acute and delayed Provide general supportive measures and treat Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim under observation. may be delayed. Indication of immediate medical attention and special treatment needed Immediately remove all contaminated clothing. If exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse. General information 5. Fire-fighting measures Alcohol resistant foam. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Water may be an ineffective extinguishing medium. Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Unsuitable extinguishing media Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. To reduce potential for static discharge, use proper bonding and grounding procedures. This liquid may accumulate static electricity when filling properly grounded containers. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Special protective equipment and precautions for firefighters In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Specific methods Extremely flammable liquid and vapor. General fire hazards 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Transfer by mechanical means such as vacuum truck to a salvage tank or other suitable container for recovery or safe disposal. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Unleaded Gasoline - All Grades SDS US 920117 Version 01 Revision date: - Issue date: 18-May-2015 3 / 15 Page 237 of 262 Page 237 of 262 Page 237 of 262 Page 237 of 262 ---PAGE BREAK--- Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is NOT miscible in water. This material is classified as a water pollutant under the Clean Water Act and should be prevented from contaminating soil or from entering sewage and drainage systems which lead to waterways. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. Use appropriate containment to avoid environmental contamination. Environmental precautions 7. Handling and storage Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. When using do not smoke. Explosion-proof general and local exhaust ventilation. Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. For additional information on equipment bonding and grounding, refer to the American Petroleum Institute (API) Recommended Practice 2003, "Protection Against Ignitions Arising out of Static, Lightning, and Stray Currents" or National Fire Protection Association (NFPA) 77, "Recommended Practice on Static Electricity" or National Fire Protection Association (NFPA) 70, "National Electrical Code". Use only as a motor fuel. Do not siphon by mouth. Precautions for safe handling Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and equipment. These alone may be insufficient to remove static electricity. Store in a cool, dry place out of direct sunlight. Store in original closed container. Store in a well-ventilated place. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). Tank storage: Tank must be equipped with foam injection. Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Value Type Components STEL 5 ppm Benzene (CAS 71-43-2) TWA 1 ppm US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Type Components PEL 2350 mg/m3 (CAS 592-27-8) Unleaded Gasoline - All Grades SDS US 920117 Version 01 Revision date: - Issue date: 18-May-2015 4 / 15 Page 238 of 262 Page 238 of 262 Page 238 of 262 Page 238 of 262 ---PAGE BREAK--- US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Value Type Components 500 ppm PEL 2350 mg/m3 (CAS 589-81-1) 500 ppm PEL 2000 mg/m3 (CAS 589-34-4) 500 ppm PEL 1050 mg/m3 Cyclohexane (CAS 110-82-7) 300 ppm PEL 1900 mg/m3 Ethanol (CAS 64-17-5) 1000 ppm PEL 435 mg/m3 (CAS 100-41-4) 100 ppm PEL 2000 mg/m3 Heptane (CAS 142-82-5) 500 ppm PEL 1800 mg/m3 n-Hexane (CAS 110-54-3) 500 ppm PEL 2350 mg/m3 Octane (CAS 111-65-9) 500 ppm PEL 2950 mg/m3 Pentane (CAS 109-66-0) 1000 ppm PEL 435 mg/m3 Xylene (CAS 1330-20-7) 100 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) Value Type Components Ceiling 25 ppm Benzene (CAS 71-43-2) TWA 10 ppm Ceiling 300 ppm Toluene (CAS 108-88-3) TWA 200 ppm US. ACGIH Threshold Limit Values Value Type Components STEL 1000 ppm (CAS 79-29-8) TWA 500 ppm TWA 1000 ppm (CAS 78-78-4) STEL 500 ppm (CAS 591-76-4) TWA 400 ppm STEL 1000 ppm (CAS 107-83-5) TWA 500 ppm STEL 500 ppm (CAS 589-34-4) TWA 400 ppm STEL 1000 ppm (CAS 96-14-0) TWA 500 ppm STEL 2.5 ppm Benzene (CAS 71-43-2) TWA 0.5 ppm STEL 1000 ppm Butane (CAS 106-97-8) TWA 100 ppm Cyclohexane (CAS 110-82-7) Unleaded Gasoline - All Grades SDS US 920117 Version 01 Revision date: - Issue date: 18-May-2015 5 / 15 Page 239 of 262 Page 239 of 262 Page 239 of 262 Page 239 of 262 ---PAGE BREAK--- US. ACGIH Threshold Limit Values Value Type Components STEL 1000 ppm Ethanol (CAS 64-17-5) TWA 20 ppm (CAS 100-41-4) STEL 500 ppm Gasoline (CAS 86290-81-5) TWA 300 ppm STEL 500 ppm Heptane (CAS 142-82-5) TWA 400 ppm TWA 50 ppm n-Hexane (CAS 110-54-3) TWA 300 ppm Octane (CAS 111-65-9) TWA 1000 ppm Pentane (CAS 109-66-0) TWA 20 ppm Toluene (CAS 108-88-3) TWA 25 ppm (CAS 25551-13-7) STEL 150 ppm Xylene (CAS 1330-20-7) TWA 100 ppm US. NIOSH: Pocket Guide to Chemical Hazards Value Type Components Ceiling 1800 mg/m3 (CAS 79-29-8) 510 ppm TWA 350 mg/m3 100 ppm Ceiling 1800 mg/m3 (CAS 592-27-8) 385 ppm TWA 350 mg/m3 75 ppm Ceiling 1800 mg/m3 (CAS 107-83-5) 510 ppm TWA 350 mg/m3 100 ppm Ceiling 1800 mg/m3 (CAS 589-81-1) 385 ppm TWA 350 mg/m3 75 ppm Ceiling 1800 mg/m3 (CAS 589-34-4) 440 ppm TWA 350 mg/m3 85 ppm Ceiling 1800 mg/m3 (CAS 96-14-0) 510 ppm TWA 350 mg/m3 100 ppm STEL 1 ppm Benzene (CAS 71-43-2) TWA 0.1 ppm TWA 1900 mg/m3 Butane (CAS 106-97-8) 800 ppm TWA 1050 mg/m3 Cyclohexane (CAS 110-82-7) 300 ppm TWA 1900 mg/m3 Ethanol (CAS 64-17-5) 1000 ppm STEL 545 mg/m3 (CAS 100-41-4) Unleaded Gasoline - All Grades SDS US 920117 Version 01 Revision date: - Issue date: 18-May-2015 6 / 15 Page 240 of 262 Page 240 of 262 Page 240 of 262 Page 240 of 262 ---PAGE BREAK--- US. NIOSH: Pocket Guide to Chemical Hazards Value Type Components 125 ppm TWA 435 mg/m3 100 ppm Ceiling 1800 mg/m3 Heptane (CAS 142-82-5) 440 ppm TWA 350 mg/m3 85 ppm TWA 180 mg/m3 n-Hexane (CAS 110-54-3) 50 ppm Ceiling 1800 mg/m3 Octane (CAS 111-65-9) 385 ppm TWA 350 mg/m3 75 ppm Ceiling 1800 mg/m3 Pentane (CAS 109-66-0) 610 ppm TWA 350 mg/m3 120 ppm STEL 560 mg/m3 Toluene (CAS 108-88-3) 150 ppm TWA 375 mg/m3 100 ppm TWA 125 mg/m3 (CAS 25551-13-7) 25 ppm STEL 655 mg/m3 Xylene (CAS 1330-20-7) 150 ppm TWA 435 mg/m3 100 ppm Biological limit values ACGIH Biological Exposure Indices Value Sampling Time Determinant Specimen Components 25 µg/g S-Phenylmerca pturic acid Creatinine in urine * Benzene (CAS 71-43-2) 0.15 g/g Sum of mandelic acid and acid Creatinine in urine * (CAS 100-41-4) 0.4 mg/l 2,5-Hexanedio n, without hydrolysis Urine * n-Hexane (CAS 110-54-3) 0.3 mg/g o-Cresol, with hydrolysis Creatinine in urine * Toluene (CAS 108-88-3) 0.03 mg/l Toluene Urine * 0.02 mg/l Toluene Blood * 1.5 g/g acids Creatinine in urine * Xylene (CAS 1330-20-7) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation Benzene (CAS 71-43-2) Can be absorbed through the skin. n-Hexane (CAS 110-54-3) Can be absorbed through the skin. Toluene (CAS 108-88-3) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies Toluene (CAS 108-88-3) Skin designation applies. US ACGIH Threshold Limit Values: Skin designation Benzene (CAS 71-43-2) Can be absorbed through the skin. Unleaded Gasoline - All Grades SDS US 920117 Version 01 Revision date: - Issue date: 18-May-2015 7 / 15 Page 241 of 262 Page 241 of 262 Page 241 of 262 Page 241 of 262 ---PAGE BREAK--- n-Hexane (CAS 110-54-3) Can be absorbed through the skin. Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Appropriate engineering controls Individual protection measures, such as personal protective equipment Chemical respirator with organic vapor cartridge and full facepiece. Eye/face protection Skin protection Wear appropriate chemical resistant gloves. Be aware that the liquid may penetrate the gloves. Frequent change is advisable. Nitrile or neoprene gloves are recommended. Hand protection Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended. Other Chemical respirator with organic vapor cartridge and full facepiece. Respiratory protection Wear appropriate thermal protective clothing, when necessary. Thermal hazards When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Appearance Liquid. Physical state Liquid. Form Clear to bronze. Color Strong Hydrocarbon. Odor Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 85 - 437 °F (29 - 225 Flash point -45.0 °F (-43 Evaporation rate 10 - 11 (BuAc=1) Not available. Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower 1.4 Flammability limit - upper 7.6 Explosive limit - lower Not available. Explosive limit - upper Not available. Vapor pressure 200 - 450 mm Hg ( 68°F) Vapor density > 1 ( Air=1) Relative density 0.74 (H20=1) Solubility(ies) Solubility (water) Gasoline: negliglible. Ethanol: readily soluble in water Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature > 530 °F 277 Decomposition temperature Not available. Viscosity Not available. 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Reactivity Material is stable under normal conditions. Chemical stability Unleaded Gasoline - All Grades SDS US 920117 Version 01 Revision date: - Issue date: 18-May-2015 8 / 15 Page 242 of 262 Page 242 of 262 Page 242 of 262 Page 242 of 262 ---PAGE BREAK--- No dangerous reaction known under conditions of normal use. Possibility of hazardous reactions Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Conditions to avoid Strong acids. Strong oxidizing agents. Halogens. Incompatible materials No hazardous decomposition products are known. Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation Headache. Nausea, vomiting. May cause irritation to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. Skin contact Causes skin irritation. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. related to the physical, chemical and toxicological characteristics May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Irritation of eyes and mucous membranes. May cause respiratory irritation. Skin irritation. May cause redness and pain. Information on toxicological effects Acute toxicity May be fatal if swallowed and enters airways. May be harmful if inhaled. Narcotic effects. May cause respiratory irritation. Test Results Components Species (CAS 78-78-4) LC50 Mouse Inhalation Acute 1000 mg/l, 1 Hours 450 mg/l, 2 Hours Benzene (CAS 71-43-2) LD50 Rat Oral Acute 930 mg/kg Cyclohexane (CAS 110-82-7) LD50 Rat Oral Acute 12705 mg/kg Ethanol (CAS 64-17-5) LC50 Rat Inhalation Acute 30000 mg/m3 (CAS 100-41-4) LD50 Rabbit Dermal Acute 15400 mg/kg LC50 Rat Inhalation 17.4 mg/m³, 4 Hours LD50 Rat Oral 35000 - 47000 mg/kg Heptane (CAS 142-82-5) LC50 Rat Inhalation Acute 103 mg/l, 4 Hours Unleaded Gasoline - All Grades SDS US 920117 Version 01 Revision date: - Issue date: 18-May-2015 9 / 15 Page 243 of 262 Page 243 of 262 Page 243 of 262 Page 243 of 262 ---PAGE BREAK--- Test Results Components Species Toluene (CAS 108-88-3) LD50 Rabbit Dermal Acute 14.1 ml/kg LC50 Rat Inhalation 49000 mg/m³, 4 Hours LD50 Rat Oral 636 mg/kg Xylene (CAS 1330-20-7) LD50 Rabbit Dermal Acute 12126 mg/kg, 24 Hours LC50 Rat Inhalation 6350 ppm, 4 Hours LD50 Rat Oral 3523 mg/kg Causes skin irritation. Skin corrosion/irritation Direct contact with eyes may cause temporary irritation. Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not available. This product is not expected to cause skin sensitization. Skin sensitization May cause genetic defects. Germ cell mutagenicity Carcinogenicity May cause cancer. IARC Monographs. Overall Evaluation of Carcinogenicity Benzene (CAS 71-43-2) 1 Carcinogenic to humans. (CAS 100-41-4) 2B Possibly carcinogenic to humans. Gasoline (CAS 86290-81-5) 2B Possibly carcinogenic to humans. Toluene (CAS 108-88-3) 3 Not classifiable as to carcinogenicity to humans. Xylene (CAS 1330-20-7) 3 Not classifiable as to carcinogenicity to humans. NTP Report on Carcinogens Benzene (CAS 71-43-2) Known To Be Human Carcinogen. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Benzene (CAS 71-43-2) Cancer Components in this product have been shown to cause birth defects and reproductive disorders in laboratory animals. Suspected of damaging fertility or the unborn child. Reproductive toxicity Specific target organ toxicity - single exposure May cause respiratory irritation. May cause drowsiness and dizziness. Specific target organ toxicity - repeated exposure Causes damage to organs (Bone Marrow, Central nervius System, Blood) through prolonged or repeated exposure. Aspiration hazard May be fatal if swallowed and enters airways. Chronic effects Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. 12. Ecological information Very toxic to aquatic life with long lasting effects. Ecotoxicity Components Test Results Species Cyclohexane (CAS 110-82-7) Aquatic LC50 Fish 3.961 - 5.181 mg/l, 96 hours Fathead minnow (Pimephales promelas) (CAS 100-41-4) Aquatic EC50 Crustacea 1.81 mg/l, 48 hours Daphnia Unleaded Gasoline - All Grades SDS US 920117 Version 01 Revision date: - Issue date: 18-May-2015 10 / 15 Page 244 of 262 Page 244 of 262 Page 244 of 262 Page 244 of 262 ---PAGE BREAK--- Components Test Results Species LC50 Fish 32 - 88 mg/l, 96 hours Bluegill (Lepomis macrochirus) 12.1 mg/l, 96 hours Fathead minnow (Pimephales promelas) Toluene (CAS 108-88-3) Aquatic EC50 Crustacea 5.46 - 9.83 mg/l, 48 hours Water flea (Daphnia magna) LC50 Fish 6.86 - 8.48 mg/l, 96 hours Pink salmon gorbuscha) No data is available on the degradability of this product. Persistence and degradability No data available. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) (CAS 79-29-8) 3.42 (CAS 78-78-4) 2.3 (CAS 592-27-8) 5.18 (CAS 107-83-5) 3.74 (CAS 589-81-1) 5.18 (CAS 589-34-4) 4.66 (CAS 96-14-0) 3.6 Benzene (CAS 71-43-2) 2.13 Butane (CAS 106-97-8) 2.89 Cyclohexane (CAS 110-82-7) 3.44 Ethanol (CAS 64-17-5) -0.31 (CAS 100-41-4) 3.15 Heptane (CAS 142-82-5) 4.66 Octane (CAS 111-65-9) 5.18 Pentane (CAS 109-66-0) 3.39 Toluene (CAS 108-88-3) 2.73 Xylene (CAS 1330-20-7) 3.2 n-Hexane (CAS 110-54-3) 3.9 No data available. Mobility in soil Other adverse effects The product is a volatile organic compound which has a photochemical ozone creation potential. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations. Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the waste disposal company. D001: Waste Flammable material with a flash point <140 °F Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Contaminated packaging 14. Transport information DOT UN1203 UN number Gasoline UN proper shipping name 3 Class Transport hazard class(es) - Subsidiary risk 3 Label(s) II Packing group No Marine pollutant Environmental hazards Read safety instructions, SDS and emergency procedures before handling. Special precautions for user 144, 177, B1, B33, IB2, T4 Special provisions Unleaded Gasoline - All Grades SDS US 920117 Version 01 Revision date: - Issue date: 18-May-2015 11 / 15 Page 245 of 262 Page 245 of 262 Page 245 of 262 Page 245 of 262 ---PAGE BREAK--- 150 Packaging exceptions 202 Packaging non bulk 242 Packaging bulk IATA UN1203 UN number Gasoline UN proper shipping name 3 Class Transport hazard class(es) - Subsidiary risk 3 Label(s) II Packing group No Environmental hazards 3H ERG Code Read safety instructions, SDS and emergency procedures before handling. Special precautions for user IMDG UN1203 UN number GASOLINE UN proper shipping name 3 Class Transport hazard class(es) - Subsidiary risk 3 Label(s) II Packing group No Marine pollutant Environmental hazards F-E, S-E EmS Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Not applicable. However, this product is a liquid and if transported in bulk covered under MARPOL 73/78, Annex I. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. One or more components are not listed on TSCA. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Benzene (CAS 71-43-2) Cancer Central nervous system Blood Aspiration Skin Eye respiratory tract irritation Flammability CERCLA Hazardous Substance List (40 CFR 302.4) (CAS 79-29-8) LISTED (CAS 78-78-4) LISTED (CAS 592-27-8) LISTED (CAS 591-76-4) LISTED (CAS 107-83-5) LISTED (CAS 589-81-1) LISTED (CAS 589-34-4) LISTED (CAS 96-14-0) LISTED Benzene (CAS 71-43-2) LISTED Butane (CAS 106-97-8) LISTED Cyclohexane (CAS 110-82-7) LISTED Ethanol (CAS 64-17-5) LISTED (CAS 100-41-4) LISTED Gasoline (CAS 86290-81-5) LISTED Unleaded Gasoline - All Grades SDS US 920117 Version 01 Revision date: - Issue date: 18-May-2015 12 / 15 Page 246 of 262 Page 246 of 262 Page 246 of 262 Page 246 of 262 ---PAGE BREAK--- Heptane (CAS 142-82-5) LISTED n-Hexane (CAS 110-54-3) LISTED Octane (CAS 111-65-9) LISTED Pentane (CAS 109-66-0) LISTED Toluene (CAS 108-88-3) LISTED Xylene (CAS 1330-20-7) LISTED Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Hazard categories SARA 302 Extremely hazardous substance Not listed. Yes SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Chemical name CAS number % by wt. Toluene 108-88-3 5-25 Xylene 1330-20-7 5-20 Benzene 71-43-2 0-5 Cyclohexane 110-82-7 0-5 100-41-4 0-5 25551-13-7 0-5 n-Hexane 110-54-3 0-5 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Benzene (CAS 71-43-2) (CAS 100-41-4) n-Hexane (CAS 110-54-3) Toluene (CAS 108-88-3) Xylene (CAS 1330-20-7) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) (CAS 78-78-4) Butane (CAS 106-97-8) Pentane (CAS 109-66-0) Not regulated. Safe Drinking Water Act (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Toluene (CAS 108-88-3) 6594 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Toluene (CAS 108-88-3) 35 %WV DEA Exempt Chemical Mixtures Code Number Toluene (CAS 108-88-3) 594 US state regulations US. Massachusetts RTK - Substance List (CAS 79-29-8) (CAS 78-78-4) (CAS 592-27-8) (CAS 591-76-4) (CAS 107-83-5) (CAS 589-81-1) (CAS 589-34-4) (CAS 96-14-0) Benzene (CAS 71-43-2) Butane (CAS 106-97-8) Cyclohexane (CAS 110-82-7) Ethanol (CAS 64-17-5) (CAS 100-41-4) Unleaded Gasoline - All Grades SDS US 920117 Version 01 Revision date: - Issue date: 18-May-2015 13 / 15 Page 247 of 262 Page 247 of 262 Page 247 of 262 Page 247 of 262 ---PAGE BREAK--- Heptane (CAS 142-82-5) n-Hexane (CAS 110-54-3) Octane (CAS 111-65-9) Pentane (CAS 109-66-0) Toluene (CAS 108-88-3) (CAS 25551-13-7) Xylene (CAS 1330-20-7) US. New Jersey Worker and Community Right-to-Know Act (CAS 79-29-8) (CAS 78-78-4) (CAS 592-27-8) (CAS 107-83-5) (CAS 589-81-1) (CAS 589-34-4) Benzene (CAS 71-43-2) Butane (CAS 106-97-8) Cyclohexane (CAS 110-82-7) Ethanol (CAS 64-17-5) (CAS 100-41-4) (CAS 25550-14-5) Heptane (CAS 142-82-5) n-Hexane (CAS 110-54-3) Octane (CAS 111-65-9) Pentane (CAS 109-66-0) Toluene (CAS 108-88-3) (CAS 25551-13-7) Xylene (CAS 1330-20-7) US. Worker and Community Right-to-Know Law (CAS 79-29-8) (CAS 78-78-4) (CAS 591-76-4) (CAS 107-83-5) (CAS 589-34-4) (CAS 96-14-0) Benzene (CAS 71-43-2) Butane (CAS 106-97-8) Cyclohexane (CAS 110-82-7) Ethanol (CAS 64-17-5) (CAS 100-41-4) Gasoline (CAS 86290-81-5) Heptane (CAS 142-82-5) n-Hexane (CAS 110-54-3) Octane (CAS 111-65-9) Pentane (CAS 109-66-0) Toluene (CAS 108-88-3) (CAS 25551-13-7) Xylene (CAS 1330-20-7) US. Rhode Island RTK (CAS 78-78-4) Benzene (CAS 71-43-2) Butane (CAS 106-97-8) Cyclohexane (CAS 110-82-7) (CAS 100-41-4) n-Hexane (CAS 110-54-3) Pentane (CAS 109-66-0) Toluene (CAS 108-88-3) Xylene (CAS 1330-20-7) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Benzene (CAS 71-43-2) (CAS 100-41-4) Toluene (CAS 108-88-3) Unleaded Gasoline - All Grades SDS US 920117 Version 01 Revision date: - Issue date: 18-May-2015 14 / 15 Page 248 of 262 Page 248 of 262 Page 248 of 262 Page 248 of 262 ---PAGE BREAK--- International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australian Inventory of Chemical Substances (AICS) No Australia Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) No Canada Inventory of Existing Chemical Substances in China (IECSC) No China European Inventory of Existing Commercial Chemical Substances (EINECS) Yes Europe European List of Notified Chemical Substances (ELINCS) No Europe Inventory of Existing and New Chemical Substances (ENCS) No Japan Existing Chemicals List (ECL) No Korea New Zealand Inventory Yes New Zealand Philippine Inventory of Chemicals and Chemical Substances (PICCS) No Philippines *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Toxic Substances Control Act (TSCA) Inventory No United States & Puerto Rico 16. Other information, including date of preparation or last revision 18-May-2015 Issue date - Revision date Version # 01 Health: 2 Flammability: 4 Physical hazard: 0 HMIS® ratings IARC Monographs. Overall Evaluation of Carcinogenicity (Volumes 1-106) HSDB (2005) ACGIH (2007) IUCLID References The information in the sheet was written based on the best knowledge and experience currently available. Silver Eagle Refining Inc. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. Disclaimer Unleaded Gasoline - All Grades SDS US 920117 Version 01 Revision date: - Issue date: 18-May-2015 15 / 15 Page 249 of 262 Page 249 of 262 Page 249 of 262 Page 249 of 262 ---PAGE BREAK--- Material Safety Data Sheet Page 1 of 7 Section 1: Product & Company Identification Product Name: White Lithium Grease (aerosol) Product Number 14200 Product Use: lubricating grease Manufacturer / Supplier Contact Information: In United States: In Canada: CRC Industries, Inc. CRC Canada Co. 885 Louis Drive 2-1246 Lorimar Drive Warminster, PA 18974 Mississauga, Ontario L5S 1R2 www.crcindustries.com www.crc-canada.ca 1-[PHONE REDACTED] (General) 1-[PHONE REDACTED] (800) 521-3168 (Technical) (800) 272-4620 (Customer Service) 24-Hr Emergency – CHEMTREC: (800) 424-9300 or (703) 527-3887 Section 2: Hazards Identification Emergency Overview DANGER: Extremely Flammable. Harmful or Fatal if Swallowed. Contents Under Pressure. Appearance & Odor: Off-white, viscous grease with solvent odor Potential Health Effects: ACUTE EFFECTS: EYE: May cause mild irritation including stinging and redness, but does not injure eye. SKIN: Single, brief exposures may cause mild irritation. Frequent or prolonged contact may cause more severe irritation, defatting of the skin, and dermatitis. INHALATION: High vapor concentrations are irritating to the respiratory tract and may cause headaches, dizziness, anesthesia, drowsiness, unconsciousness and other central nervous system effects, including death. May cause peripheral nervous system disorder and/or damage. Heating the dispensed grease may generate irritating vapors. INGESTION: Low order of toxicity by ingestion. Main hazard is aspiration into the lungs during swallowing or vomiting. Small amounts aspirated into the respiratory system may cause bronchopneumonia or pulmonary adema, possible progressing to death. CHRONIC EFFECTS: Overexposure to n-hexane may cause progressive and potentially irreversible damage to the peripheral nervous system, particularly in the arms and legs. TARGET ORGANS: central nervous system, peripheral nervous system, respiratory system Medical Conditions Aggravated by Exposure: skin and respiratory conditions See Section 11 for toxicology and carcinogenicity information on product ingredients. Page 250 of 262 Page 250 of 262 Page 250 of 262 Page 250 of 262 ---PAGE BREAK--- Product Name: White Lithium Grease (aerosol) Product Number 14200 Page 2 of 7 Section 3: Composition/Information on Ingredients COMPONENT CAS NUMBER % by Wt. Hexane isomers 64742-49-0 / 107-83-5 40 - 50 n-Hexane 110-54-3 3.2 Heavy naphthenic petroleum distillates 64742-52-5 10 - 20 Liquefied petroleum gas 68476-86-8 35 - 45 Section 4: First Aid Measures Eye Contact: Immediately flush with plenty of water for 15 minutes. Call a physician if irritation persists. Skin Contact: Remove contaminated clothing and wash affected area with soap and water. Call a physician if irritation persists. Wash contaminated clothing prior to re-use. Inhalation: Remove person to fresh air. Keep person calm. If not breathing, give artificial respiration. If breathing is difficult give oxygen. Call a physician. Ingestion: Do NOT induce vomiting. Contact a physician immediately. Note to Physicians: Treat Gastric lavage using a cuffed endotracheal tube may be performed at your discretion. Section 5: Fire-Fighting Measures Flammable Properties: This product is extremely flammable in accordance with aerosol flammability definitions. (See 16 CFR 1500.3(c)(6) Flash Point: < 20°F / -6°C (TCC) Upper Explosive Limit: 9.0 Autoignition Temperature: 489°F / 254°C Lower Explosive Limit: 1.7 Fire and Explosion Data: Suitable Extinguishing Media: Class B fire extinguishers, dry chemical, foam or CO2 Products of Combustion: Fumes, smoke and carbon monoxide Explosion Hazards: Aerosol containers, when exposed to heat from fire, may build pressure and explode. Vapors may accumulate in a confined space and create a flammable atmosphere. Protection of Fire-Fighters: Firefighters should wear self-contained, NIOSH-approved breathing apparatus for protection against suffocation and possible toxic decomposition products. Proper eye and skin protection should be provided. Use water spray to keep fire-exposed containers cool and to knock down vapors which may result from product decomposition. Do not spray water directly on fire; product will float and could be reignited on surface of water. Section 6: Accidental Release Measures Personal Precautions: Use personal protection recommended in Section 8. Environmental Precautions: Take precautions to prevent contamination of ground and surface waters. Do not flush into sewers or storm drains. Page 251 of 262 Page 251 of 262 Page 251 of 262 Page 251 of 262 ---PAGE BREAK--- Product Name: White Lithium Grease (aerosol) Product Number 14200 Page 3 of 7 Methods for Containment & Clean-up: Dike area to contain spill. Remove all sources of ignition. Ventilate the area with fresh air. If in confined space or limited air circulation area, clean-up workers should wear appropriate respiratory protection. Recover or absorb spilled material using an absorbent designed for chemical spills. Place used absorbents into proper waste containers. Section 7: Handling and Storage Handling Procedures: Use proper grounding and bonding procedures for transferring materials. Do not use product near any source of ignition. Avoid contact with eyes and skin. Avoid breathing vapors. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. For product use instructions, please see the product label. Storage Procedures: Store in a cool dry area out of direct sunlight. Aerosol cans must be maintained below 120°F / 49°C to prevent cans from rupturing. Aerosol Storage Level: III Section 8: Exposure Controls/Personal Protection Exposure Guidelines: OSHA ACGIH OTHER COMPONENT TWA STEL TWA STEL TWA SOURCE UNIT Hexane isomers 500(v) 1000(v) 500 1000 NE ppm n-Hexane 500 NE 50(s) NE NE ppm Heavy naphthenic petroleum distillates 5 NE NE NE NE mg/m3 Liquefied petroleum gas 1000 NE 1000 NE NE ppm N.E. – Not Established – ceiling – skin – vacated Controls and Protection: Engineering Controls: Area should have ventilation to provide fresh air. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at the source, preventing dispersion into the general work area. Use mechanical means if necessary to maintain vapor levels below the exposure guidelines. If working in a confined space, follow applicable OSHA regulations. Respiratory Protection: None required for normal work where adequate ventilation is provided. If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with organic vapor cartridge. Air monitoring is needed to determine actual employee exposure levels. Use a self-contained breathing apparatus in confined spaces and for emergencies. Eye/face Protection: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear splash-proof goggles. Skin Protection: Use protective gloves such as nitrile, PVC or Viton®. Also, use full protective clothing if there is prolonged or repeated contact of liquid with skin. Section 9: Physical and Chemical Properties Page 252 of 262 Page 252 of 262 Page 252 of 262 Page 252 of 262 ---PAGE BREAK--- Product Name: White Lithium Grease (aerosol) Product Number 14200 Page 4 of 7 Physical State: semi-solid / grease Color: off-white Odor: solvent Odor Threshold: ND Specific Gravity: 0.6257 Initial Boiling Point: 140°F / 60°C Freezing Point: < -50°F / -45°C Vapor Pressure: ND Vapor Density: > 1 (air = 1) Evaporation Rate: fast Solubility: not soluble in water Coefficient of water/oil distribution: ND pH: NA Volatile Organic Compounds: wt 85 g/L: 531.8 lbs./gal: 4.43 Section 10: Stability and Reactivity Stability: Stable Conditions to Avoid: Sources of ignition, temperature extremes Incompatible Materials: Strong oxidizers Hazardous Decomposition Products: Oxides of carbon Possibility of Hazardous Reactions: No Section 11: Toxicological Information Long-term toxicological studies have not been conducted for this product. The following information is available for components of this product. Acute Toxicity: Component Oral LD50 (rat) Dermal LD50 (rabbit) Inhalation LC50 (rat) Hexane isomers > 5000 mg/kg > 2000 mg/kg No data n-Hexane 28,710 mg/kg > 3000 mg/kg 48,000 ppm/4H Heavy naphthenic petroleum distillates No data No data No data Liquefied petroleum gas No data No data No data Chronic Toxicity: Component OSHA Carcinogen IARC Carcinogen NTP Carcinogen Irritant Sensitizer Hexane isomers No No No No Unknown n-Hexane No No No Skin No Heavy naphthenic petroleum distillates No No No Eye Unknown Liquefied petroleum gas No No No No No Reproductive Toxicity: No information available Teratogenicity: No information available Mutagenicity: No information available Synergistic Effects: No information available Page 253 of 262 Page 253 of 262 Page 253 of 262 Page 253 of 262 ---PAGE BREAK--- Product Name: White Lithium Grease (aerosol) Product Number 14200 Page 5 of 7 Section 12: Ecological Information Ecological studies have not been conducted for this product. The following information is available for components of this product. Ecotoxicity: n-hexane - 48 Hr EC50 water flea: 3.87 mg/L 96 Hr LC50 Lepomis macrochirus: 4.12 mg/L Persistence / Degradability: No information available Bioaccumulation / Accumulation: No information available Mobility in Environment: No information available Section 13: Disposal Considerations Waste Classification: The packaged liquid product is a RCRA hazardous waste for the characteristic of ignitability with a waste code of D001. The dispensed grease is not a hazardous waste. (See 40 CFR Part 261.20 – 261.33). Empty aerosol containers may be recycled. All disposal activities must comply with federal, state, provincial and local regulations. Local regulations may be more stringent than state, provincial or national requirements. Section 14: Transport Information US DOT (ground): UN1950, Aerosols, flammable, 2.1, Limited Quantity** ICAO/IATA (air): UN1950, Aerosols, flammable, 2.1, Limited Quantity IMO/IMDG (water): UN1950, Aerosols, 2.1, Limited Quantity Special Provisions: **This product can be classified and labeled as ‘Consumer Commodity, ORM-D’ for domestic ground shipping until December 31, 2020. If shipping as limited quantity by ground, note that shipping papers are not required. Section 15: Regulatory Information U.S. Federal Regulations: Toxic Substances Control Act (TSCA): All ingredients are either listed on the TSCA inventory or are exempt. Comprehensive Environmental Response, Compensation and Liability Act (CERCLA): Reportable Quantities (RQ’s) exist for the following ingredients: n-hexane (5000 lbs) Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center ([PHONE REDACTED]) and to your Local Emergency Planning Committee. Superfund Amendments Reauthorization Act (SARA) Title III: Section 302 Extremely Hazardous Substances (EHS): None Section 311/312 Hazard Categories: Fire Hazard Yes Reactive Hazard No Release of Pressure Yes Acute Health Hazard Yes Chronic Health Hazard No Page 254 of 262 Page 254 of 262 Page 254 of 262 Page 254 of 262 ---PAGE BREAK--- Product Name: White Lithium Grease (aerosol) Product Number 14200 Page 6 of 7 Section 313 Toxic Chemicals: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: n-hexane Clean Air Act: Section 112 Hazardous Air Pollutants (HAPs): n-hexane Occupational Safety and Health Administration: This product is regulated by the Hazard Communications Standard. U.S. State Regulations: California Safe Drinking Water and Toxic Enforcement Act (Prop 65): This product may contain the following chemicals known to the state of California to cause cancer, birth defects or other reproductive harm: None Consumer Products VOC Regulations: This product is not regulated (semi-solid lubricant). State Right to Know: New Jersey: 75-83-2, 109-66-0, 78-78-4, 96-37-7, 110-54-3, 79-29-8, 68476-86-8 107-83-5, 75-83-2, 110-54-3, 79-29-8, 68476-86-8 Massachusetts: 107-83-5, 75-83-2, 110-54-3, 79-29-8, 68476-86-8 Rhode Island : 75-83-2, 110-54-3, 79-29-8, 68476-86-8 Canadian Regulations: Controlled Products Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. WHMIS Hazard Class: A, B5, D2A, D2B Canadian DSL Inventory: All ingredients are either listed on the DSL Inventory or are exempt. European Union Regulations: RoHS Compliance: This product is compliant with Directive 2002/95/EC of the European Parliament and of the Council of 27 January 2003. This product does not contain any of the restricted substances as listed in Article 4(1) of the RoHS Directive. Additional Regulatory Information: None Section 16: Other Information HMIS® (II) Health: 1 Flammability : 3 Reactivity: 0 PPE: B Ratings range from 0 (no hazard) to 4 (severe hazard) NFPA 3 0 1 Page 255 of 262 Page 255 of 262 Page 255 of 262 Page 255 of 262 ---PAGE BREAK--- Product Name: White Lithium Grease (aerosol) Product Number 14200 Page 7 of 7 Prepared By: Michelle Rudnick CRC 568G Revision Date: 06/09/2015 Changes since last revision: Revision Date The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this MSDS consult your supervisor, a health & safety professional, or CRC Industries. ACGIH: American Conference of Governmental Industrial Hygienists CAS: Chemical Abstract Service CFR: Code of Federal Regulations DOT: Department of Transportation DSL: Domestic Substance List g/L: grams per Liter HMIS: Hazardous Materials Identification System IARC: International Agency for Research on Cancer IATA: International Air Transport Association ICAO: International Civil Aviation Organization IMDG: International Maritime Dangerous Goods IMO: International Maritime Organization lbs./gal: pounds per gallon LC: Lethal Concentration LD: Lethal Dose NA: Not Applicable ND: Not Determined NIOSH: National Institute of Occupational Safety & Health NFPA: National Fire Protection Association NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration PMCC: Pensky-Martens Closed Cup PPE: Personal Protection Equipment ppm: Parts per Million RoHS: Restriction of Hazardous Substances STEL: Short Term Exposure Limit TCC: Tag Closed Cup TWA: Time Weighted Average WHMIS: Workplace Hazardous Materials Information System Page 256 of 262 Page 256 of 262 Page 256 of 262 Page 256 of 262 ---PAGE BREAK--- MATERIAL SAFETY DATA SHEET Product number 700-006 . 1. Product and Company Identification space Product name Xtreme Gleme All Weather Surface Degreaser space Effective date 03-Oct-2012 space Company information Claire Manufacturing Co. 1005 S. Westgate Drive Addison, IL 60101 United States space Company phone General Assistance 1-[PHONE REDACTED] space Emergency telephone US 1-[PHONE REDACTED] space Emergency telephone outside US 1-[PHONE REDACTED] space Version # 09 space Supersedes date 04-Mar-2011 space Product use Degreaser space Emergency overview Aerosol. CONTENTS UNDER PRESSURE. Harmful in contact with eyes. . 2. Hazards Identification space Routes of exposure Eye contact. Skin contact. Ingestion. Potential health effects space Eyes Contact may irritate or burn eyes. space Skin Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. space Inhalation Intentional misuse by concentrating and inhaling the product can be harmful or fatal. space Ingestion Exposure by ingestion of an aerosol is unlikely. Components of the product may be absorbed into the body by ingestion. May cause delayed lung damage. Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea. space Target organs Central nervous system. Lungs. space Chronic effects Unconsciousness. Conjunctiva. Cyanosis (blue tissue condition, nails, lips, and/or skin). May cause central nervous system disorder narcosis involving a loss of coordination, weakness, fatigue, mental confusion and blurred vision) and/or damage. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. May cause delayed lung injury. space Signs and Discomfort in the chest. Narcosis. Cyanosis (blue tissue condition, nails, lips, and/or skin). Coughing. Jaundice. Defatting of the skin. Skin irritation. space CAS # Percent 5 - 8 64-17-5 Components Ethyl Alcohol 3 - 5 112-34-5 Diethylene Glycol Monobutyl Ether 1 - 3 106-97-8 n-Butane 80 - 90 Non-hazardous and other components below reportable levels . 3. Composition / Information on Ingredients space Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. First aid procedures . 4. First Aid Measures space Skin contact Wash off with warm water and soap. Get medical attention if irritation develops and persists. space Inhalation Move to fresh air. Get medical attention if persist. space Ingestion If material is ingested, immediately contact a poison control center. space Product name: Xtreme Gleme All Weather Surface Degreaser Product 700-006 Revision date: 03-OCT-2012 Print date: 03-OCT-2012 MSDS US 1 / 5 Page 257 of 262 Page 257 of 262 Page 257 of 262 Page 257 of 262 ---PAGE BREAK--- Notes to physician Keep victim warm. Keep victim under observation. may be delayed. space Flammable properties Vapor or gas may spread to distant ignition sources and flash back. Runoff to sewer may cause fire or explosion hazard. . 5. Fire Fighting Measures space Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Extinguishing media space Protective equipment and precautions for firefighters In case of fire and/or explosion do not breathe fumes. Containers should be cooled with water to prevent vapor pressure build up. Protection of firefighters space Methods for containment Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Stop the flow of material, if this is without risk. . 6. Accidental Release Measures space Methods for cleaning up Should not be released into the environment. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. space Handling Pressurized container: Do not pierce or burn, even after use. Do not smoke while using or until sprayed surface is thoroughly dry. Do not use if spray button is missing or defective. Do not re-use empty containers. Do not get this material in contact with eyes. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with skin. . 7. Handling and Storage space Storage Contents under pressure. Do not puncture, incinerate or crush. The pressure in sealed containers can increase under the influence of heat. Do not handle or store near an open flame, heat or other sources of ignition. Avoid exposure to long periods of sunlight. Store in cool place. Keep container dry. Keep out of the reach of children. Keep away from food, drink and animal feedingstuffs. Level 1 Aerosol (NFPA 30B) space Exposure limits ACGIH Components CAS # Ethyl Alcohol 64-17-5 TWA 1000 ppm STEL 1000 ppm Ceiling Not established Diethylene Glycol Monobutyl Ether 112-34-5 20 ppm Not established Not established space n-Butane 106-97-8 1000 ppm Not established Not established . 8. Exposure Controls / Personal Protection space OSHA Components CAS # Ethyl Alcohol 64-17-5 TWA 1000 ppm STEL Not established Ceiling Not established space Diethylene Glycol Monobutyl Ether 112-34-5 100 ppm Not established Not established space Eye / face protection Do not get in eyes. Chemical goggles are recommended. Personal protective equipment space Skin protection Wear appropriate chemical resistant clothing. Chemical resistant gloves. space Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. space Appearance Cloudy. . 9. Physical & Chemical Properties space Boiling point 215.6 °F (102.2 estimated space Product name: Xtreme Gleme All Weather Surface Degreaser Product 700-006 Revision date: 03-OCT-2012 Print date: 03-OCT-2012 MSDS US 2 / 5 Page 258 of 262 Page 258 of 262 Page 258 of 262 Page 258 of 262 ---PAGE BREAK--- Color Not available space Density 0.9597 g/cm3 estimated space Flammability (HOC) 4.6332 kJ/g estimated space Flash back No space Flash point -156 °F (-104.4 Propellant space Form Aerosol. space Freezing point Not available space Odor Characteristic. space pH 9.5 - 10.5 space Physical state Liquid. space Pressure 65 - 70 psig @70F space Solubility Partially space Specific gravity 0.9598 estimated space Chemical stability Risk of ignition. . 10. Chemical Stability & Reactivity Information space Conditions to avoid Heat, flames and sparks. space Hazardous decomposition products Irritants. Toxic gas. space Acute effects Acute LD50: 55663 mg/kg estimated, Rat, Dermal . 11. Toxicological Information space Component analysis - LD50 Toxicology Data - Selected LD50s and LC50s 112-34-5 Oral LD50 Rat 3384 mg/kg; Dermal LD50 Rabbit 2700 mg/kg Diethylene Glycol Monobutyl Ether 64-17-5 Oral LD50 Rat 7060 mg/kg; Inhalation LC50 Rat 124.7 mg/L 4 h Ethyl Alcohol 106-97-8 Inhalation LC50 Rat 658 mg/L 4 h n-Butane space Carcinogenicity IARC - Group 1 (Carcinogenic to Humans) 64-17-5 Monograph 100E [in preparation] (in alcoholic beverages); Monograph 96 [2010] (in alcoholic beverages) Ethyl Alcohol space Ecotoxicity LC50 23777 mg/L, Fish, 96.00 Hours, EC50 23978 mg/L, Daphnia, 48.00 Hours, IC50 5503 mg/L, Algae, 72.00 Hours, Contains a substance which causes risk of hazardous effects to the environment. . 12. Ecological Information space Waste codes D001: Waste Flammable material with a flash point <140 F . 13. Disposal Considerations space Disposal instructions Contents under pressure. Do not puncture, incinerate or crush. Dispose of this material and its container to hazardous or special waste collection point. Do not allow this material to drain into sewers/water supplies. If discarded, this product is considered a RCRA ignitable waste, D001. space Department of Transportation (DOT) Requirements Aerosols 2.1 UN1950 Hazard class UN number Proper shipping name Basic shipping requirements: 153, N82 306 None None Special provisions Packaging exceptions Packaging non bulk Packaging bulk Additional information: . 14. Transport Information space Product name: Xtreme Gleme All Weather Surface Degreaser Product 700-006 Revision date: 03-OCT-2012 Print date: 03-OCT-2012 MSDS US 3 / 5 Page 259 of 262 Page 259 of 262 Page 259 of 262 Page 259 of 262 ---PAGE BREAK--- Further information This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2013, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/13 and may be used now in place of the "Consumer Commodity ORM-D" marking but not concurrently. space IMDG AEROSOLS 2.1 1950 Hazard class UN number Proper shipping name Basic shipping requirements: LTD QTY 5F None 2 Packaging exceptions Item Labels required Transport Category Additional information: space IATA Aerosols, flammable 2.1 1950 Hazard class UN number Proper shipping name Basic shipping requirements: LTD QTY 2.1 Packaging exceptions Labels required Additional information: space US federal regulations U.S. - CERCLA/SARA - Section 313 - Emission Reporting 112-34-5 1.0 % de minimis concentration (applies to R-(OCH2CH2)n-OR', where n = 1,2, or 3, R=alkyl C7 or less, or R = phenyl or alkyl substituted phenyl, R' = H or alkyl C7 or less, or OR' consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or sulfonate, Chemical Category N230) Diethylene Glycol Monobutyl Ether This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. . 15. Regulatory Information space 29 CFR 1910.1200 hazardous chemical Yes Occupational Safety and Health Administration (OSHA) space None CERCLA (Superfund) reportable quantity space Section 302 extremely hazardous substance No Superfund Amendments and Reauthorization Act of 1986 (SARA) space Section 311 hazardous chemical Yes space Hazard categories (311/312) Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No space Inventory status Country(s) or region Inventory name On inventory (yes/no)* No Yes No Yes No China Europe Europe Japan Korea Inventory of Existing Chemical Substances in China (IECSC) European Inventory of New and Existing Chemicals (EINECS) European List of Notified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory space Product name: Xtreme Gleme All Weather Surface Degreaser Product 700-006 Revision date: 03-OCT-2012 Print date: 03-OCT-2012 MSDS US 4 / 5 Page 260 of 262 Page 260 of 262 Page 260 of 262 Page 260 of 262 ---PAGE BREAK--- State regulations U.S. - - RTK (Right to Know) List 112-34-5 Environmental hazard Diethylene Glycol Monobutyl Ether 64-17-5 Present Ethyl Alcohol 106-97-8 Present n-Butane space Further information HMIS® is a registered trade and service mark of the NPCA. . 16. Other Information space HMIS® ratings Health: 1 Flammability: 2 Physical hazard: 0 space Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. The information in the sheet was written based on the best knowledge and experience currently available. space MSDS sections updated Product and Company Identification: Product and Company Identification Physical & Chemical Properties: Appearance Physical & Chemical Properties: Color Physical & Chemical Properties: Form Transport Information: Product Shipping Name/Packing Group Transport Information: Further information space Prepared by Regulatory Compliance space Product name: Xtreme Gleme All Weather Surface Degreaser Product 700-006 Revision date: 03-OCT-2012 Print date: 03-OCT-2012 MSDS US 5 / 5 Page 261 of 262 Page 261 of 262 Page 261 of 262 Page 261 of 262 ---PAGE BREAK--- Safety Data Sheets Maple Highway Shop Maple Highway Shop 02/29/2016 Page 262 of 262 Page 262 of 262 Page 262 of 262 Page 262 of 262